Energy Technology Data Exchange (ETDEWEB)
The ability of residual biomass from the thermotolerant ethanol-producing yeast strain Kluyveromyces marxianus IMB3 to function as a biosorbent for uranium has been examined. It was found that the biomass had an observed maximum biosorption capacity of 120 mg U/g dry weight of biomass. The calculated value for the biosorption maximum, obtained by fitting the data to the Langmuir model was found to be 130 mg U/g dry weight biomass. Maximum biosorption capacities were examined at a number of temperatures and both the observed and calculated values obtained for those capacities increased with increasing temperature. Decreasing the pH of the biosorbate solution resulted in a decrease in uptake capacity. When biosorption reactions were carried out using sea-water as the diluent it was found that the maximum biosorption ...
1997-06-01
Functionally defined substates within the human embryonic stem cell compartment.
Human embryonic stem (ES) cells can undergo spontaneously differentiation in standard culture conditions, demonstrating that the undifferentiated state is relatively unstable. The heterogeneous expression of SSEA3 observed within human ES colonies, provides a means to examine undifferentiated stem cell substates. Through functional testing of single cells we have shown that undifferentiated ES cells can be segregated into functionally discrete subpopulations on the basis of SSEA3 expression: SSEA3(High), SSEA(Low) and SSEA3(Negative). Human ES subpopulations were found to be interconvertible, but they possess distinct properties when challenged to differentiate along the neural lineage. These data suggest that ES cells with pluripotent/self-renewal capacities can exhibit different responses to induction of differentiation. PMID:21763622
2011-05-11
Technology base research on zinc/air battery systems: Final report
Energy Technology Data Exchange (ETDEWEB)
The capacity extension of additives was tested in a 200 cm/sup 2/bi-cell and a Zn powder moving-bed slurry. It was found that for the Type A additives in 12 M KOH, 25 g/l of silicate provided higher capacity than stannate, titanate and aluminate additives. The optimum concentration of sorbitol (a Type B additive that stabilizes polymeric chains involving ZnO) was found to be 15 g/l in 12 M KOH. A silicate and sorbitol combination added to Zn powder slurry in 12 M KOH provided a 20% increase in discharge capacity (195 Ah/l at 200 A/cm/sup 2/) compared to the maximum capacity obtained with silicate alone. A much lower capacity (74 Ah/l) was realized with silicate as Type C additive (precipitation of ZnO away from the Zn surface, for low KOH concentrations). The mechanisms of passivation and capacity extension were discussed and a model presented. The cell voltage ...
1987-09-01
International Nuclear Information System (INIS)
The molar heat capacities (Cp,m) of a series of synthetic forsterite (Fo)-fayalite (Fa), (Mg2SiO4+Fe2SiO4), olivines have been measured between 5K and 300K on milligram-sized samples with the Physical Properties Measurement System (Quantum Design(R)). Sharp, ?-type heat capacity anomalies are observed in the Fe-rich compositions fayalite, Fo10Fa90, Fo20Fa80, Fo30Fa70, and Fo40Fa60. The corresponding Neel temperatures TN decrease linearly from 64.5K in fayalite to 32.8K in Fo40Fa60 following the relationship TN=79.02.xFa-14.07. Fo50Fa50 and Mg-richer olivines show weak broad features in the heat capacity data around 15K to 20K that decrease in magnitude with increasing forsterite content. In order to derive and separate molar electronic, magnetic and vibrational heat capacity contributions, Cel,m, Cmag,m, and Cvib,m from the experimental heat capacities (Ctot,m), ...
2007-06-01
Oxygen-induced enhancement of the adsorptive capacity of activated charcoal
Energy Technology Data Exchange (ETDEWEB)
Adsorption isotherms for phenol and o-cresol on activated charcoal at neutral pH and several dissolved oxygen concentrations were conducted at 23{degree}C. Significant improvements in capacities were observed with increasing dissolved oxygen concentrations for the two adsorbates. These statistically-significant additional capacities were not due to biological activities but merely due to surface chemical reactions. The improvement in capacity was directly related to the amount of oxygen per unit mass of GAC.
1992-02-01
Lung diffusing capacity in a hyperbaric environment: assessment by a rebreathing technique.
UK PubMed Central (United Kingdom)
A rebreathing method was developed for measuring diffusing lung capacity for carbon monoxide (DLCO) in a hyperbaric environment. Twenty two professional naval divers with normal lung function were included...Full Text Available
1992-04-01
Strain-dependent variation in collateral circulatory function in mouse hindlimb
UK PubMed Central (United Kingdom)
The extent (density and diameter) of the native (preexisting) collateral circulation in healthy tissues and the capacity of collaterals to enlarge/remodel in obstructive arterial disease are important...Full Text Available
2010-08-01
This study investigated the feasibility of using a new adsorbent prepared from coconut coir pith, CP (a coir industry-based lignocellulosic residue), for the removal of uranium [U(VI)] from aqueous solutions. The adsorbent (PGCP-COOH) having a carboxylate functional group at the chain end was synthesized by grafting poly(hydroxyethylmethacrylate) onto CP using potassium peroxydisulphate-sodium thiosulphite as a redox initiator and in the presence of N,N'-methylenebisacrylamide as a crosslinking agent. IR spectroscopy results confirm the graft copolymer formation and carboxylate functionalization. XRD studies confirm the decrease of crystallinity in PGCP-COOH compared to CP, and it favors the protrusion of the functional group into the aqueous medium. The thermal stability of the samples was studied using thermogravimetry (TG). Surface charge density of the samples as a function of pH was determined ...
2008-01-28
Energy Technology Data Exchange (ETDEWEB)
Flue gas desulfurizing capacities of active carbon fibers (ACF) made from polyacrylonitrile (PAN-ACF) were studied, the features were clarified and at the same time the factors governing the capacities were studied to get guides for better products. Desulfurization capacities of 17 kinds of ACFs were studied. Two kinds of PAN-ACF, FE-200 and FE-300, especially the latter exhibited the higher desulfurization capacity. The capacity of FE-300 was about 20 times higher than those of fibers other than PAN systems and about 4 times higher than that of active coke for desulfurization. From the influence of reacting conditions on the desulfurizating capacity and the desorption profiles of adsorbed SO {sub 2}, it was concluded that the capacity was determined by the effective adsorption capacity of ACF and SO {sub 2} was retained ...
1991-04-10
Energy Technology Data Exchange (ETDEWEB)
In this study, the biosorption of Cd(II), Ni(II) and Pb(II) on Aspergillus niger in a batch system was investigated, and optimal condition determined by means of central composite design (CCD) under response surface methodology (RSM). Biomass inactivated by heat and pretreated by alkali solution was used in the determination of optimal conditions. The effect of initial solution pH, biomass dose and initial ion concentration on the removal efficiency of metal ions by A. niger was optimized using a design of experiment (DOE) method. Experimental results indicated that the optimal conditions for biosorption were 5.22 g/L, 89.93 mg/L and 6.01 for biomass dose, initial ion concentration and solution pH, respectively. Enhancement of metal biosorption capacity of the dried biomass by pretreatment with sodium hydroxide was observed. Maximal removal efficiencies for Cd(II), Ni(III) and Pb(II) ions of 98, 80 and 99% were achieved, respectively. The ...
2009-10-15
UK PubMed Central (United Kingdom)
The murine cytomegalovirus (MCMV) M33 gene is conserved among all betaherpesviruses and encodes a homologue of seven-transmembrane receptors (7TMR) with the capacity for constitutive signaling. Previous...Full Text Available
2008-02-01
Energy Technology Data Exchange (ETDEWEB)
Amphiphilic block copolymers are synthesized by sulfonation of poly(styrene-b-methyl methacrylate) (PS-b-PMMA) using acetyl sulfate, and are blended with poly(vinylidene fluoride) (PVDF) to prepare a new proton exchange membrane, in which PMMA is miscible with PVDF. The morphology and the transport properties of the membranes are investigated as functions of the degree of sulfonation as well as the blend ratio. Notable transition of phase-separated morphology is observed as the PVDF content of the blend is increased. Both the proton conductivity and the ion-exchange capacity (IEC) of the membrane increase with increasing the degree of sulfonation of PS-b-PMMA, and they are also enhanced as the phase-separated domains of blend membrane are well-ordered. Unlike the Nafion membrane, the proton conductivity of the blend membrane increases up to 90 C, indicating the blend membrane shows better thermal stability than the Nafion ...
2009-03-01
Measurements of water vapor adsorption on the Geysers rocks
Energy Technology Data Exchange (ETDEWEB)
The ORNL high temperature isopiestic apparatus was adapted for adsorption measurements. The quantity of water retained by rock samples taken from three different wells of The Geysers was measured at 150 °C and at 200 °C as a function of pressure in the range 0.00 ≤ p/p0 ≤ 0.98, where p0 is the saturated water vapor pressure. The rocks were crushed and sieved into three fractions of different grain sizes (with different specific surface areas). Both adsorption (increasing pressure) and desorption (decreasing pressure) runs were made in order to investigate the nature and extent of the hysteresis. Additionally, BET surface area analyses were performed by Porous Materials Inc. on the same rock samples using nitrogen or krypton adsorption measurements at 77 K. Specific surface areas and pore volumes were determined. These parameters are important in estimating water retention capability of a ...
1996-01-24
Magnetocaloric and magnetoresistance studies of GdPd{sub 2}Si
Energy Technology Data Exchange (ETDEWEB)
The compound GdPd{sub 2}Si, which is reported to order antiferromagnetically at 13 K, has been investigated by heat capacity and electrical resistivity measurement in the presence of external magnetic fields. In contrast to an earlier report, the zero-field heat capacity and resistivity data indicate two magnetic transitions at 13 and 17 K. The external magnetic field substantially influences the resistivity and heat capacity of the compound around the magnetic ordering temperature. The magnetocaloric effect, which is calculated from in-field heat capacity data, is quite large around the magnetic transition temperature. The magnetoresistance is also large near the magnetic ordering temperature. The metamagnetic transition is observed for 10 kOe magnetic field both in magnetocaloric and in magnetoresistance data. The metamagnetic transition strongly influences the magnetocaloric ...
2001-01-22
Magnetocaloric and magnetoresistance studies of GdPd_2Si
International Nuclear Information System (INIS)
The compound GdPd_2Si, which is reported to order antiferromagnetically at 13 K, has been investigated by heat capacity and electrical resistivity measurement in the presence of external magnetic fields. In contrast to an earlier report, the zero-field heat capacity and resistivity data indicate two magnetic transitions at 13 and 17 K. The external magnetic field substantially influences the resistivity and heat capacity of the compound around the magnetic ordering temperature. The magnetocaloric effect, which is calculated from in-field heat capacity data, is quite large around the magnetic transition temperature. The magnetoresistance is also large near the magnetic ordering temperature. The metamagnetic transition is observed for 10 kOe magnetic field both in magnetocaloric and in magnetoresistance data. The metamagnetic transition strongly influences the magnetocaloric effect ...
2001-01-22
Heat capacities of the mixtures of ionic liquids with acetonitrile
International Nuclear Information System (INIS)
Isobaric specific heat capacities were measured for {1-hexyl-3-methylimidazolium tetrafluoroborate (HMIMBF4) + acetonitrile (MeCN)} and {1-methyl-3-octylimidazolium tetrafluoroborate (OMIMBF4) + acetonitrile} within the whole range of composition and temperatures from (283.15 to 323.15) K. The excess molar heat capacities were calculated from the experimental results and satisfactorily fitted to Redlich-Kister type polynomials for several selected temperatures. Negative deviations from the additivity of molar heat capacities were observed within the whole composition range of (HMIBMF4 + MeCN) and (OMIMBF4 + MeCN). The results obtained have been interpreted in terms of interactions between ionic liquids and acetonitrile.
2010-02-01
ALOS satellite imagery utilizations for safeguards
International Nuclear Information System (INIS)
This paper introduces examples of satellite imageries analysis and utilizations for safeguards activities. Recently, many kinds of satellite imageries are available in the world i.e., high-spatial resolution, multi- and hyper-spectral, multi-function, and multi-polarization radars. The problem is that how to obtain the required information from these digital images. The Japan Aerospace Exploration Agency (JAXA) has successfully launched the Advanced Land Observing Satellite (ALOS, the nickname is 'Daichi') on 24th January, 2006. The mission objectives are cartography, regional observation, disaster monitoring etc. ALOS has three instruments, PRISM, AVNIR-2, and PALSAR, to achieve these objectives. An overview of ALOS is provided. ALOS follows the Japanese Earth Resources Satellite- 1 (JERS-1) and the Advanced Earth Observing Satellite (ADEOS) and utilizes advanced land-observing ...
2006-10-16
The genetic basis of salinity tolerance in Arctic charr (Salvelinus alpinus).
ABSTRACT: BACKGROUND: The capacity to maintain internal ion homeostasis amidst changing conditions is particularly important for teleost fishes whose reproductive cycle is dependent upon movement from freshwater to seawater. Although the physiology of seawater osmoregulation in mitochondria-rich cells of fish gill epithelium is well understood, less is known about the underlying causes of inter- and intraspecific variation in salinity tolerance. We used a genome-scan approach in Arctic charr (Salvelinus alpinus) to map quantitative trait loci (QTL) correlated with variation in four salinity tolerance performance traits and six body size traits. Comparative genomics approaches allowed us to infer whether allelic variation at candidate gene loci (e.g., ATP1alpha1b, NKCC1, CFTR, and cldn10e) could have underlain observed variation. RESULTS: Combined parental analyses yielded genome-wide significant QTL on linkage groups 8, 14 and 20 for salinity ...
2011-09-21
Energy Technology Data Exchange (ETDEWEB)
Nanosized CaSnO{sub 3} is synthesized by a hydrothermal process and characterized by X-ray diffraction (XRD), Raman spectroscopy, and scanning electron microscopy (SEM). The SEM observation shows the sample has a porous flowerlike morphology. The electrochemical results exhibit that the stable and reversible capacity of 547 mAh g{sup -1} is obtained after 50 cycles at 60 mA g{sup -1} (0.1 C) and the corresponding charge capacity is determined to be 316 mAh g{sup -1} at the current density of 2.5 C. Cyclic voltammetry and electrochemical impedance spectroscopy data are analyzed to complement the galvanostatic results. The observed excellent performance is attributed to the porous structure and large surface area of flowerlike CaSnO{sub 3}.
2010-04-30
FEBEX II Project Final report on thermo-hydro-mechanical laboratory tests
International Nuclear Information System (INIS)
The results of the thermo-hydro-mechanical (THM) study of the FEBEX bentonite performed during FEBEX II are presented. The laboratory test program continued in part with the works carried out during FEBEX I, particularly in activities related to tests aimed to the calibration of the models, the acquisition of parameters by back-analysis and the improvement of the knowledge on the behaviour of expansive clays. But the program has also included tests on new areas: investigations about the influence of the microstructure changes in bentonite, of temperature and of the solute concentration on the behaviour of clay. Besides, several tests were proposed in order to understand the unexpected behaviour observed in the mock-up test, towards the end of year 2. Temperature effects on water retention curves in confined and unconfined conditions were determined, and swelling pressure, hydraulic conductivity and swelling and consolidation strains as a ...
As-synthesized MCM-41 silica: new adsorbent for perchlorate
British Library Electronic Table of Contents (United Kingdom)
Here we demonstrate that the as-prepared MCM-41 mesoporous silica material, which is synthesized using cetyltrimethylammonium bromide as a cationic surfactant exhibits very high capacity for perchlorate uptake from solutions. Thus we discover a new function for the as-synthesized mesoporous materials containing cationic surfactants. These materials are shown to have better capacity than the currently used activated carbon, which is preloaded with cationic surfactant. As-synthesized MCM-41 has a higher removal of perchlorate with 0.378???0.038?meq/g than the surfactant modified activated carbon sample, which removed 0.304???0.005?meq/g i.e., MCM-41 has a 24 % higher capacity than the surfactant modified activated carbon sample for perchlorate uptake because of higher surfactant content and ...
2010-01-01
Role of limited cell replicative capacity in pathological age change. A review
Energy Technology Data Exchange (ETDEWEB)
Physiological functions are carried out by differentiated cells, with finite lifespans, which age and need to be replaced. In young individuals, tissue functions are sustained at optimal levels because cellular dysfunction and cell loss are balanced by the emergence of newly differentiated cells as stem cells and their partially differentiated descendants replicate. However, with the passage of time the mitotic rates of these cells diminish. Eventually, replications occur too infrequently to offset the loss. It is at this point that the tissue begins to show structural changes and declining function which, as they become pervasive, are identified as ageing. In this paper the theory is set forth that: (1) Diminishing mitotic activity in older tissues results from limited stem cell replicative capacity. (2) All stem cells, regardless of tissue, exhibit similar replicative patterns over time, progressing ...
1982-01-01
Energy Technology Data Exchange (ETDEWEB)
The electrochemical performances of orthorhombic LiMnO{sub 2} compounds are analyzed in order to find a structural and/or morphological origin to the differences of electrochemical behaviours observed in compounds with different size of crystallites and different amounts of lattice defects. Energy capacity performances of 200 Ah/kg are reached for materials with crystallites of about 10{sup 7} Angstrom{sup 3} and with about 7% of defects, while energy capacities of only 80 Ah/kg are obtained for materials with ten times bigger crystallites. (J.S.) 3 refs.
1996-12-31
High capacity Si/DC/MWCNTs nanocomposite anode materials for lithium ion batteries
International Nuclear Information System (INIS)
Nanocomposites comprising nanocrystal silicon (Si), disordered carbon (DC), and multi-walled carbon nanotubes (MWCNTs) - denoted as Si/DC/MWCNTs - have been prepared by pyrolyzing the phenol-formaldehyde resin (PFR) mixed with Si and MWCNTs. This nanocomposite anode material showed a discharge capacity of 1216 mAh/g in the first cycle, and a charge capacity of 711 mAh/g after 20 charge-discharge, much higher than that of Si/DC composite. It can be observed that Si particles wrapped in MWCNTs were homogeneously embedded into the matrix of the DC. The improved electrochemical performance is hypothesized to be mainly attributed to the morphology stability of the composite due to the excellent resiliency and distinct electric conductivity of the MWCNTs.
2010-03-18
Cathode materials for lithium rocking chair batteries
Energy Technology Data Exchange (ETDEWEB)
Cathode materials for rechargeable rocking chair or lithium-ion batteries, are reviewed. The emphasis is placed on the comparison between specific capacities and rechargeability of lithium-containing high voltage cathode materials such as manganese oxides and LiMO{sub 2} compounds, where M is Co or Ni. It is generally found that the maximum reversible capacities for the most promising materials fall in the range 100-120 mAh/g, and decaying to around 75 mAh/g after several hundred cycles. The rechargeability is similar for the most commonly considered materials: LiMn{sub 2}O{sub 4}, LiCoO{sub 2} and LiNiO{sub 2}. No improvements in capacity or rechargeability, beyond what have been found for these materials, is observed by substitution of other elements into these compounds
1996-03-29
Heat capacity of VT1-0 commercial titanium and VT5 and VT5-1 titanium base alloys at low temperature
International Nuclear Information System (INIS)
The temperature dependences of the heat capacity of commercial titanium VT1-0 and alloys on its base, VT5 and VT5-1, have been derived in the temperature range of 4 to 290 K. For comparison, similar measurements have been conducted on pure titanium and specially prepared solid solutions on its base (Ti+3.7 at.% Al and Ti+0.82 at.% Sn). The measurement accuracy has been sufficient for comparing the results with calculation data. The obtained results are interpreted using the known concepts of the role of the mass of interstitial atoms and changes in the interatomic bond forces. It is shown that the phonon components of the molar heat capacities of solid solutions of Al in titanium have lower values in the entire temperature range, as compared to titanium. The corresponding differences are proportional to the Al concentrations. The lower molar heat capacity in the case of dissolution of Al is due to the low mass of the ...
1978-01-01
Energy Technology Data Exchange (ETDEWEB)
The performance of more than 3,000 offshore platforms in the Gulf of Mexico was observed during the passage of Hurricane Andrew in August 1992. This event provided an opportunity to test the procedures used for platform analysis and design. A global bias was inferred for overall platform capacity and loads in the Andrew Joint Industry Project (JIP) Phase 1. It was predicted that the pile foundations of several platforms should have failed, but did not. These results indicated that the biases specific to foundation failure modes may be higher than those of jacket failure modes. The biases in predictions of foundation failure modes were therefore investigated further in this study. The work included capacity analysis and calibration of predictions with the observed behavior for 3 jacket platforms and 3 caissons using Bayesian updating. Bias factors for two foundation failure modes, lateral shear and ...
1996-12-31
Functionalized multi-walled carbon nanotubes as affinity ligands
Energy Technology Data Exchange (ETDEWEB)
Functionalization of carbon nanotubes is very challenging for their applications. The paper here describes a new method to functionalize multi-walled carbon nanotubes (MWCNTs) as specific affinity adsorbents. MWCNTs were acid purified and pretreated with (3-aminopropyl)-triethoxysilane (APTES) in order to introduce abundant amino groups on the surface of MWCNTs. After the conversion of amino groups to carboxyl groups by succinic acid anhydride, MWCNTs were attached to protein A or aminodextran using 1-ethyl-3,3' (dimethylamion)-propylcarbodiimide as a biofunctional crosslinker. The incorporation of aminodextran as a spacer arm noticeably increased the binding capacity of the APTES-modified MWCNTs for protein A. The application of affinity MWCNTs for purification of immunoglobulin G was then evaluated. The affinity of MWCNTs with AMD spacer exhibited a high adsorption capacity of {approx}361 ...
2007-03-21
Regeneration of granular activated carbon using hydrothermal technology
Energy Technology Data Exchange (ETDEWEB)
The economic feasibility of using granular activated carbon (GAC) to remove organic contaminants from industrial and municipal wastewater is contingent upon its reuse during multiple adsorption-regeneration cycles. The most common process for the regeneration of GAC is the thermal method. Drawbacks associated with thermal regeneration include a 5--10% loss of carbon due to oxidation and attrition, a decrease in adsorption capacity, and high energy costs. The purpose of this study was to investigate the regeneration of GAC using hydrothermal technology. Phenol contaminated and non-contaminated GAC samples were regenerated using supercritical water (411 deg C and 26.2 MPa) with dissolved oxygen concentrations of 0 mg/L, 5 mg/L, and 100 mg/L. For comparative purposes, GAC was regenerated using subcritical water (300 deg C and 12.4 MPa) with a dissolved oxygen concentration of 5 mg/L. Regenerated GAC samples were evaluated in terms of adsorption ...
1999-05-01
User's manual of SECOM2: a computer code for seismic system reliability analysis
International Nuclear Information System (INIS)
This report is the user's manual of seismic system reliability analysis code SECOM2 (Seismic Core Melt Frequency Evaluation Code Ver.2) developed at the Japan Atomic Energy Research Institute for systems reliability analysis, which is one of the tasks of seismic probabilistic safety assessment (PSA) of nuclear power plants (NPPs). The SECOM2 code has many functions such as: Calculation of component failure probabilities based on the response factor method, Extraction of minimal cut sets (MCSs), Calculation of conditional system failure probabilities for given seismic motion levels at the site of an NPP, Calculation of accident sequence frequencies and the core damage frequency (CDF) with use of the seismic hazard curve, Importance analysis using various indicators, Uncertainty analysis, Calculation of the CDF taking into account the effect of the correlations of responses and capacities of components, and Efficient sensitivity analysis by ...
Energy Technology Data Exchange (ETDEWEB)
In an adiabatic low-pressure calorimeter, the temperature dependence of the standard molar heat capacity of paramagnetic dicarbonyl rhodium complex with o-semiquinone (CO){sub 2}Rh(SQ) has been determined in the range from T=(6 to 355)K mainly with an accuracy of about 0.3%. Over the ranges from T=(205 to 234) K, T=(266 to 315)K and T=(316 to 345)K physical transformations have been revealed and their enthalpies and entropies have been estimated. The experimental data were used to calculate the thermodynamic functions C{sub p,m}{sup o}/R,{delta}{sub 0}{sup T}H{sub m}{sup o}/(R.K),{delta}{sub 0}{sup T}S{sub m}{sup o}/R and {phi}{sub m}{sup o}={delta}{sub 0}{sup T}S{sub m}{sup o}-{delta}{sub 0}{sup T}H{sub m}{sup o}/T (where R is the universal gas constant) between T=(0 and 355)K. The fractal dimension D in the heat capacity function of the fractal variant of Debye heat capacity ...
2006-06-15
Silanization of the silica gel surface in the synthesis of silica gel polyamine composites uses (chloropropyl)-trichlorosilane (CPTCS). It is possible to substitute a molar fraction of reagent CPTCS with methyltrichlorosilane (MTCS), creating a mixed silane surface layer. Two types of silica gels were modified with a series of MTCS:CPTCS molar ratios. Solid-state CP/MAS 29Si and 13C NMR spectroscopies were used to evaluate the surface silane composition. Surface silane coverage was markedly improved for the resulting gels. When polyamines were grafted to the resultant MTCS:CPTCS silane layers, it was shown that the decrease in the number of propyl attachments to the polyamine resulted in increased quantities of ''free amines''. Optimum MTCS:CPTCS ratios were determined for three polyamines grafted onto one silica gel. A substantial free amine increase was observed for poly(allylamine) (PAA). Metal uptake studies show increases in ...
2006-09-13
Energy Technology Data Exchange (ETDEWEB)
Silanization of the silica gel surface in the synthesis of silica gel polyamine composites uses (chloropropyl)-trichlorosilane (CPTCS). It is possible to substitute a molar fraction of reagent CPTCS with methyltrichlorosilane (MTCS), creating a mixed silane surface layer. Two types of silica gels were modified with a series of MTCS:CPTCS molar ratios. Solid-state CP/MAS 29Si and 13C NMR spectroscopies were used to evaluate the surface silane composition. Surface silane coverage was markedly improved for the resulting gels. When polyamines were grafted to the resultant MTCS:CPTCS silane layers, it was shown that the decrease in the number of propyl attachments to the polyamine resulted in increased quantities of ''free amines''. Optimum MTCS:CPTCS ratios were determined for three polyamines grafted onto one silica gel. A substantial free amine increase was observed for poly(allylamine) (PAA). Metal uptake studies show increases in ...
2006-09-13
Theoretical calculation for the elastic wave velocities and thermodynamic functions of graphite
International Nuclear Information System (INIS)
Based on the generalized gradient approximation (GGA) of density functional theory (DFT) and the full-potential linearized augmented plane wave (FLAPW) at the level including all electrons, the lattice parameters of graphite are calculated and optimized. Some elastic wave velocities transmitted in graphite are deduced. Using the methods of elastic wave velocity method and the atomic displacement method, the Debye frequency of graphite is obtained. The standard heat capacity, entropy, sublimation enthalpy of graphite is deduced at 289.5 k and 1 atm. The calculated results are discussed and compared with experimental data. (authors)
2006-06-01
A phenomenological Landau theory for electromagnons in cubic spinel multiferroic CoCr_2O_4
International Nuclear Information System (INIS)
Non-anisotropic free energy is considered which under minimization yields two magnetic phases: a conical spin density wave and a low temperature conical cycloid. Using equations of motion, the excitation spectrum is studied. Knowing the nature of these excitations, the dielectric function as well as the fluctuation specific heat is computed and compared with the experimental spectrum. Due to the electromagnon going soft, the dielectric function (imaginary part) as well as the specific heat capacity show peaks at the temperature where ferroelectricity appears in the system.
2010-06-09
Light-weight free-standing carbon nanotube-silicon films for anodes of lithium ion batteries.
Silicon is an attractive alloy-type anode material because of its highest known capacity (4200 mAh/g). However, lithium insertion into and extraction from silicon are accompanied by a huge volume change, up to 300%, which induces a strong strain on silicon and causes pulverization and rapid capacity fading due to the loss of the electrical contact between part of silicon and current collector. Si nanostructures such as nanowires, which are chemically and electrically bonded to the current collector, can overcome the pulverization problem, however, the heavy metal current collectors in these systems are larger in weight than Si active material. Herein we report a novel anode structure free of heavy metal current collectors by integrating a flexible, conductive carbon nanotube (CNT) network into a Si anode. The composite film is free-standing and has a structure similar to the steel bar reinforced concrete, where the infiltrated CNT network ...
2010-07-27
Electrochemical stability of silicon/carbon composite anode for lithium ion batteries
International Nuclear Information System (INIS)
Silicon/carbon composite anode materials were prepared by pyrolyzing the phenol-formaldehyde resin (PFR) mixed with silicon and graphite powders. Scanning electron microscopic (SEM) observation showed that the morphology stability of the composite electrodes can be retained during cycling. A structure evolution mechanism is proposed to illuminate the enhancement of cycleability of the composite electrode. The composite used as anode material for lithium ion batteries possesses a reversible capacity of over 700 mAh/g.
2007-04-20
Exploring the structure of the proton through polarization observables in l p \\to jet X
We present results for a complete set of polarization observables for jet production in lepton proton collision, where the final state lepton is not observed. The calculations are carried out in collinear factorization at the level of Born diagrams. For all the observables we also provide numerical estimates for typical kinematics of a potential future Electron Ion Collider. On the basis of this numerical study, the prospects for the transverse single target spin asymmetry are particularly promising. This observable is given by a certain quark-gluon correlation function, which has a direct relation to the transverse momentum dependent Sivers parton distribution.
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
In the present work temperature dependences of heat capacity of carbosilane dendrimers with butyl terminal groups of the third and the fourth generations as well as of the fifth and the sixth generations have been determined first in the range from 6 to 340K and between 6 and 600K, respectively, by precision adiabatic vacuum and dynamic calorimetry. In the above temperature ranges the physical transformations have been detected and their thermodynamic characteristics have been estimated and analyzed. The experimental data were used to calculate standard thermodynamic functions, namely the heat capacity C{sub p}{sup o}(T), enthalpy H{sup o}(T)-H{sup o}(0), entropy S{sup o}(T)-S{sup o}(0) and Gibbs function G{sup o}(T)-H{sup o}(T), for the range from T->0 to (340-600)K. Linear dependences of changing the corresponding thermodynamic functions of the dendrimers on their molecular ...
2006-01-15
Energy Technology Data Exchange (ETDEWEB)
The use of POE solid polymer electrolytes in negative lithium electrode batteries allows to reach energy density values close to 150 Wh/kg. The functioning of Li/POE/V{sub 2}O{sub 5} elements has been studied on small capacity elementary cells (about 26 mAh) and the results obtained were confirmed using coiled elements of 1.4 to 1.8 Ah capacity. This work has been carried out for Bollore Technologies (BT) and Electricite de France (EdF) companies. (J.S.)
1996-12-31
Pickup and delivery network segmentation using contiguous geographic clustering
British Library Electronic Table of Contents (United Kingdom)
This paper addresses the problem of partitioning a local service region into nonoverlapping work areas in which pickups and deliveries are made throughout the day. For a fleet of homogeneous vehicles, a given set of customers, and expected demand for service, the objective is to find the least number of work areas or clusters that satisfy a variety of geometric and capacity constraints. Using rectangles as the basic shape, each cluster must have an aspect ratio that falls within certain bounds, as well as meet load and time requirements dictated by the capacity of a vehicle and the working hours in a day, respectively. The latter requirement presents a unique hurdle because travel times are a function of the actual routes followed by the drivers, and are not known, even in a probabilistic ...
2011-01-01
The kWh model finds the kWh outputs of each plant and reservoir capacities of hydro and pumped storage plants and minimizes the sum of fixed charges for constructing the reservoirs and generating facilities, also the fuel costs of thermal and nuclear plants. It is a linear programming problem whose constants are represented by nonlinear functions of kW running capacity of each plant. The optimal pattern of nuclear and thermal units is found by solving the linear programming problem derived for the pumped storage and hydroplants. Excluding the upper bound constraints, the number of constraint equations are few and do not increase with the number of units, although the number of variables increases. The computing time increases only in proportion to the number of groupings of generating units. Sensitivity analysis can be done easily. The detailed operational behavior of each generating unit can be taken into account.
1979-03-01
British Library Electronic Table of Contents (United Kingdom)
Soluble TWEAK is a member of the TNF-alpha family of cytokines that has been shown to predict mortality in patients with heart failure. Pulmonary artery hypertension is a devastating disease, in which right ventricular function has been shown to be the major determinant of prognosis. In this hypothesis-generating study, we sought to evaluate the potential usefulness of sTWEAK in the prediction of disease severity in patients with pulmonary artery hypertension. We therefore conducted a retrospective analysis of sTWEAK serum levels in 95 stable patients with PAH. For all patients data on hemodynamic parameters, biomarkers and functional exercise tests were available. Compared to controls, patients with PAH showed significantly decreased levels of sTWEAK [median 314?pg/ml (interquartile range...
2011-01-01
Improving functional esophageal surgery with a ?smart? bougie: endoflip
British Library Electronic Table of Contents (United Kingdom)
Background An emerging imaging tool, the functional lumen imaging probe (Endoflip; Crospon Ltd, Galway, Ireland), provides a real-time measurement of esophagogastric junction (EGJ) capacity and diameter, which would be of particular interest in functional esophageal surgery such as Heller myotomy and antireflux procedures. This study aimed to demonstrate the intraoperative use of endoflip in the treatment of achalasia and gastroesophageal reflux disease (GERD). Methods In the first case, Heller myotomy was performed under endopflip guidance, for persistent dysphagia after failed endoscopic dilatation. In the second case, the endoflip was used to calibrate a Nissen fundoplication. With the patient under general anesthesia, the endoflip catheter was inserted orally and positioned to straddle...
2011-01-01
Observational constraints in scalar tensor theory with tachyonic potential
We study the dynamics of the scalar tensor cosmological model in the presence of tachyon field. In an alternative approach, in two exponential and power law form of the scalar field functions in the model, field equations are solved by simultaneously best fitting the model parameters with the most recent observational data. This approach gives us an observationally verified interpretation of the dynamics of the universe. We then discuss the best fitted of equation of state parameter, the statefinder parameters and the reconstructed scalar field in the model.
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
Improved biosorption of uranium by Kluyveromyces marxianus IMB3 biomass was achieved by increasing the electric field strength of delivered pulses from 1.25kV/cm to 2.5kV/cm. Although this had little or no effect on the maximum biosorption capacity (q(max)), at low concentrations of uranium the amount bound to the biomass increased from 70 to 140mg uranium/g biomass. Significant increases in the maximum biosorption capacities (119-180 mg uranium/g biomass) were observed when the pulse field strength was increased from 2.5kV/cm to 3.25kV/cm. (Author).
1996-04-01
International Nuclear Information System (INIS)
The ternary rare earth compound NdRh_4B_4 has been studied by means of critical field, low temperature heat capacity, and static magnetic susceptibility measurements. Features in the upper critical field and heat capacity data at 1.31 K and 0.89 K suggest the occurrence of long-range magnetic order in the superconducting state. The temperature dependence of the static magnetic susceptibility follows a Curie-Weiss law with an effective magnetic moment #mu#sub(eff) = 3.58 +- 0.05 #mu#sub(B) and a Curie-Weiss temperature thetasub(p) = -6.2 +- 1.0 K between 20 K and room temperature. However, magnetization vs. applied magnetic field isotherms suggest the development of a ferromagnetic component in the Nd"3"+ magnetization at low temperatures. (author).
1979-01-01
Heat capacity and magnetic ordering of two cerium sulfides, CeS/sub 1. 393/ and CeS/sub 1. 457/
Energy Technology Data Exchange (ETDEWEB)
Heat-capacity (0.5--20 K) and magnetic-susceptibility (4--300 K) measurements have been made on two cerium sulfide samples having compositions as CeS/sub 1.393/ and CeS/sub 1.457/. These materials follow the Curie-Weiss law above 100 K, and become ferromagnetically ordered near 6 and 3 K, respectively. Shift of the ordering to higher temperatures under applied magnetic fields is also observed in CeS/sub 1.457/. The estimated effective magnetic moment and entropy associated with the ordering are consistent with the paramagnetic nature of Ce/sup 3 +/ (4f/sup 1/) in a crystalline environment.
1982-08-01
Capacity-coupled multidischarge for atmospheric plasma production
International Nuclear Information System (INIS)
We propose a method of plasma production by capacity-coupled multidischarge (CCMD) at atmospheric pressure. The discharge gaps in the CCMD consist of a common electrode and a number of compact electrodes (CCE) which are directly coupled with small capacitors for quenching the discharge. A simple CCE structure is provided by a cylindrical capacitor, the inner conductor of which is used as a gap electrode. A short pulse discharge is observed to appear homogeneously at each CCE. A charge transfer for the single-pulsed discharge is 10-100 times as large as that of the conventional dielectric barrier discharge. A high efficiency of ozone production has been confirmed in the CCMD using O_2 gas. A device configuration of the CCMD is quite flexible with respect to its geometrical shape and size. The CCMD could be used to produce plasmas for various kinds of industrial applications at atmospheric pressure.
2003-12-29
Biosorption of heavy metals on fungal biomass
Energy Technology Data Exchange (ETDEWEB)
A method of using fungi in removing heavy metal from wastewater was discussed. Fungi for this purpose can be obtained inexpensively, and on a constant basis from industrial fermentation processes. The biosorption of lead, cadmium and nickel on fungal stock cultures, was investigated. In these experiments, the fungal stock used was Aspergillus niger and Rhizopus stolonfier. Alkali pre-treatment of the fungal biomass improved the metal biosorptive capacity in comparison to live cells. The effect of alkali treatment, however, varied,showing highest biosorptive capacity for lead and least for nickel. Results showed that metal biosorption of metallic ions increased with an increase in pH from 3.2 to 4.0. Equilibrium times of five hours were observed for the biosorption of lead and cadmium, while the equilibrium time for nickel was three hours. 10 refs., 3 tabs., 7 figs.
1996-09-01
International Nuclear Information System (INIS)
The static thermophysical properties of the molten salt system like LiF-NaF-BeF_2 influence the design and construction of the fuel salt and coolant in the Molten Salt Reactor for the new generation. In this paper, the equation of state of the ternary system 0.15LiF-0.58NaF-0.27BeF_2, over the temperature range from 873.15K to 1073.15K at one atmosphere pressure, is described by using modified Peng-Robinson equation. The density of the ternary system is evaluated by this equation directly, and compared with the experimental data. Base on the equation of state, the other static thermophysical properties such as the enthalpy, entropy and heat capacity at constant pressure are evaluated by the fugacity coefficient and residual function methods respectively. The density calculated by Peng-Robinson equation is in highly agreement with the experimental data, and the enthalpy, entropy and heat capacity evaluated by such two ...
2008-03-01
International Nuclear Information System (INIS)
The static thermodynamic properties of the molten salt system like LiF-NaF-BeF_2 influence the design and construction of the fuel salt and coolant in the Molten Salt Reactor for the new generation. In this paper, the equation of state of the ternary system 15%LiF-58%NaF-27%BeF_2, over the temperature range of 873.15K to 1073.15K at one atmosphere pressure, is described using Peng-Robinson equation modified by us. And the density of the ternary system is evaluated by this equation directly, and compared with the experimental data. Base on the equation of state, the other static thermodynamic properties such as the enthalpy, entropy and heat capacity at constant pressure are estimated by the residual function method and the fugacity coefficient method respectively. The density calculated by Peng-Robinson equation is in highly agreement with the experimental data, and the enthalpy, entropy and heat capacity evaluated by such ...
2007-04-22
The static thermophysical properties of the molten salt system like LiF-NaF-BeF2 influence the design and construction of the fuel salt and coolant in the Molten Salt Reactor for the new generation. In this paper, the equation of state of the ternary system 0.15LiF-0.58NaF-0.27BeF2, over the temperature range from 873.15K to 1073.15K at one atmosphere pressure, is described by using modified Peng-Robinson equation. The density of the ternary system is evaluated by this equation directly, and compared with the experimental data. Base on the equation of state, the other static thermophysical properties such as the enthalpy, entropy and heat capacity at constant pressure are evaluated by the fugacity coefficient and residual function methods respectively. The density calculated by Peng-Robinson equation is in highly agreement with the experimental data, and the enthalpy, entropy and heat capacity evaluated by such two ...
2008-01-01
Energy Technology Data Exchange (ETDEWEB)
Apparent molar volumes V{sub phi} and apparent molar heat capacities C{sub p,phi} were determined for aqueous solutions of nickel(II) nitrate, copper(II) nitrate, and zinc(II) nitrate at molalities m=(0.01 to 0.5) mol {center_dot} kg{sup -1}, and at the pressure p=0.35 MPa. Solution densities obtained using a vibrating-tube densimeter at T=(278.15 to 368.15) K were used to calculate V{sub phi} values. Heat capacity measurements obtained with a twin fixed-cell, differential-output, power-compensating, temperature-scanning calorimeter at T=(278.15 to 393.15) K were used to calculate values of C{sub p,phi}. Our results were then fitted to functions of m and T and compared to literature values.
2004-05-01
Energy Technology Data Exchange (ETDEWEB)
Natural, formaldehyde-treated and copolymer-grafted orange peels were evaluated as adsorbents to remove lead ions from aqueous solutions. The optimum pH for lead adsorption was found to be pH 5. The adsorption process was fast, reaching 99% of sorbent capacity in 10 min for the natural and treated biomasses and 20 min for the grafted material. The treated biomass showed the highest sorption rate and capacity in the batch experiments, with the results fitting well to a pseudo-first order rate equation. In the continuous test with the treated biomass, the capacity at complete exhaustion was 46.61 mg g{sup -1} for an initial concentration of 150 mg L{sup -1}. Scanning electronic microscopy and energy dispersive X-ray spectroscopy indicated that the materials had a rough surface, and that the adsorption of the metal took place on the surface. Fourier transform infrared spectroscopy revealed that the ...
2009-01-30
Market survey for nuclear power. Memorandum by the Director General
International Nuclear Information System (INIS)
... Having established the required total capacity additions, the capacity available
1973-09-18
Powdering characteristics of thin film evaporator, 1. Drying and powdering of solution
Energy Technology Data Exchange (ETDEWEB)
Vertical thin film evaporators have been used to concentrate and dry solutions because their rotating swing blades prevent scale from being deposited on the heated surfaces. Powdering capacity of the vertical thin film evaporator was examined experimentally for drying applications of radioactive liquid waste generated from nuclear power plants. As a result, it was found that the powdering capacity increased with the blade rotation, changing significantly in the low ratational region and scarcely in the high rotational region. The powdering capacity in the high rotational region was restricted by the lack of heat flux which was theoretically evaluated for the concentrating process. As the critical factor in the low rotational region was not clear, a visual test apparatus was made to observe flow patterns in the evaporator, and a powdering model was obtained. This model showed that powdering process was ...
1983-01-01
Powdering characteristics of thin film evaporator, 1
International Nuclear Information System (INIS)
Vertical thin film evaporators have been used to concentrate and dry solutions because their rotating swing blades prevent scale from being deposited on the heated surfaces. Powdering capacity of the vertical thin film evaporator was examined experimentally for drying applications of radioactive liquid waste generated from nuclear power plants. As a result, it was found that the powdering capacity increased with the blade rotation, changing significantly in the low ratational region and scarcely in the high rotational region. The powdering capacity in the high rotational region was restricted by the lack of heat flux which was theoretically evaluated for the concentrating process. As the critical factor in the low rotational region was not clear, a visual test apparatus was made to observe flow patterns in the evaporator, and a powdering model was obtained. This model showed that powdering process was ...
1983-01-01
The luminosity function of cluster pulsars
We study luminosities of millisecond pulsars in globular clusters by fitting the observed luminosity distribution with single and double power laws. We use simulations to model the observed distribution as the brighter part of some parent distribution for Terzan 5 and try to find a model which simultaneously agrees with the observed diffuse radio flux, total predicted number of pulsars and observed luminosity distribution. We find that wide ranges of parameters for log-normal and power-law distributions give such good models. No clear difference between the luminosity distributions of millisecond pulsars in globular clusters and normal disk pulsars was seen.
2010-01-01
Metal work function tuning with new molecular acceptors
Energy Technology Data Exchange (ETDEWEB)
The interfaces between metal electrodes and electroactive organic materials are important for the performance of organic electronic devices. One way of optimizing the anode/organic interface is the insertion of a (sub-)monolayer of molecular acceptors. Here we present an UPS study of new electron acceptor molecules deposited on Au(111), Cu(111) and Ag(111). This study intends to improve the understanding of how the interactions of specific electron withdrawing groups with metal surfaces are correlated with observed modifications of interfacial electron density distribution, work function change ({delta}{phi}), and the energy level alignment. We find that {delta}{phi}, which is the difference between the work function ({phi}) of the clean metal surface and {phi} after formation of a molecular monolayer, is a monotonic function of initial {phi} of the metal. Two different slopes were ...
2008-07-01
Role of minerals in carbonaceous adsorbents for removal of Pb(II) ions from aqueous solution
Energy Technology Data Exchange (ETDEWEB)
Adsorptive removal of Pb(II) ions from aqueous solution onto a non-activated charcoal (CC) of oak wood origin was studied in comparison with an activated carbon of coal origin. The adsorption capacity for Pb(II) of the non-activated charcoal increased significantly with deceasing particle diameter, whereas the activated carbon (AC) exhibited approximately constant capacity for Pb(II) adsorption as a function of particle size. Adsorption to the ashes prepared from the non-activated charcoal and the activated carbon was also investigated to examine the role of mineral ash. Although the ash from the activated carbon did not show any Pb(II) adsorption, the ash from the charcoal was very effective for Pb(II) adsorption. Furthermore, Pb(II) was hardly adsorbed when the ash was removed from the non-activated charcoal by acid treatment. Based on the results, the adsorption sites for Pb(II) are considered to be acidic surface ...
2005-11-01
Optimization of sorghum-methane production systems
Energy Technology Data Exchange (ETDEWEB)
This dissertation concerns a study of the utilization of sorghum biomass as the fuel for a methane production system. The objective of this research is to determine an optimal sorghum-methane production system based on anaerobic batch digestion technology. The system is described as the interaction of three components: estimation of available biomass, storage of biomass, and the gas production. Levelized costs are obtained for each component. The biomass supply is assumed to decay exponentially in quality with storage time. The gas production process is a batch type of digestion with an exponential production rate. Gas production is formulated for a fixed planning horizon (one year) as a function of the number of batches and the batch residence times. The cost equation is then described as a function of these gas production equations and their levelized costs. The structure of this resulting equation is exploited to obtain the minimum unit gas ...
1984-01-01
Low temperature humidification dehumidification desalination process
Energy Technology Data Exchange (ETDEWEB)
The humidification dehumidification desalination process is viewed as a promising technique for small capacity production plants. The process has several attractive features, which include operation at low temperature, ability to utilize sustainable energy sources, i.e. solar and geothermal, and requirements of low technology level. This paper evaluates the characteristics of the humidification dehumidification desalination process as a function of operating conditions. A small capacity experimental system is used to evaluate the process characteristics as a function of the flow rate of the water and air streams, the temperature of the water stream and the temperature of the cooling water stream. The experimental system includes a packed humidification column, a double pipe glass condenser, a constant temperature water circulation tank and a chiller for cooling water. The water production is found to ...
2006-03-01
Low temperature humidification dehumidification desalination process
International Nuclear Information System (INIS)
The humidification dehumidification desalination process is viewed as a promising technique for small capacity production plants. The process has several attractive features, which include operation at low temperature, ability to utilize sustainable energy sources, i.e. solar and geothermal, and requirements of low technology level. This paper evaluates the characteristics of the humidification dehumidification desalination process as a function of operating conditions. A small capacity experimental system is used to evaluate the process characteristics as a function of the flow rate of the water and air streams, the temperature of the water stream and the temperature of the cooling water stream. The experimental system includes a packed humidification column, a double pipe glass condenser, a constant temperature water circulation tank and a chiller for cooling water. The water production is found to ...
2006-03-01
Thermodynamics of potassium diclofenac salt aqueous solutions at various temperatures
British Library Electronic Table of Contents (United Kingdom)
Solution and dilution enthalpies of aqueous solutions of potassium diclofenac salt (K_DC) were measured by an isoperibolic calorimeter at 298.15 and 318.5?K. Heat capacities of the solutions with concentrations 0.002?0.09?mol?kg?1 were obtained at the temperature interval of 288.15?318.15?K using a scanning adiabatic microcalorimeter. The virial coefficients were derived from Pitzer?s model, and the excess thermodynamic functions of both the solvent and the solute of the solution were calculated. The concentration and temperature dependencies of thermodynamic characteristics of the solution were analyzed and discussed.
2011-01-01
Highly porous thermally structurized polyacrylonitrile. Pt. 2. Electrochemical studies
Energy Technology Data Exchange (ETDEWEB)
Electrochemical properties of thermally structurized polyacrylonitrile (TSPAN) have been investigated as a function of the preparation conditions. The best charge storage capacity has been found for highly porous semiconducting materials with specific surface areas of about 1000-1200 m{sup 2}/g and a specific conductivity of 0.1-0.2 S/cm. This material can be both oxidized and reduced with high reversibility, effectivity and cycle life and is suitable for application in various charge storage devices. (orig.).
1992-06-01
Two dimensional NMR and NMR relaxation studies of coal structure
Energy Technology Data Exchange (ETDEWEB)
This report covers the progress made on the title project for the project period. Four major areas of inquiry are being pursued. Advanced solid state NMR methods are being developed to assay the distribution of the various important functional groups that determine the reactivity of coals. Special attention is being paid to methods that are compatible with the very high magic angle sample spinning rates needed for operation at the high magnetic field strengths available today. Polarization inversion methods utilizing the difference in heat capacities of small groups of spins are particularly promising. Methods combining proton-proton spin diffusion with [sup 13]C CPMAS readout are being developed to determine the connectivity of functional groups in coals in a high sensitivity relay type of experiment. Additional work is aimed at delineating the role of methyl group rotation in the proton NMR relaxation behavior of coals.
1992-11-25
International Nuclear Information System (INIS)
The temperature dependences of the Grueneisen parameter, heat capacity, bulk modulus and linear thermal expansion coefficient of sixteen III-V zincblende compounds are studied by first-principles response-function calculations. The fundamental relationships among these physical parameters are explored. Negative thermal expansions at lower temperature are found in most of these III-V phases except for the nitrides and boron compounds. By analyzing the cell-volume dependences of the phonon spectrum, it is found that the phases with a negative thermal expansion show a significant acoustic phonon weakening at the X-point in their phonon dispersion, while slight weakening is only seen around the L-point for those boron phases. There is no sign of phonon weakening in the nitrides. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
2009-07-01
UK PubMed Central (United Kingdom)
In anaesthetized rats, extracellular and intracellular recordings were taken from 106 respiratory neurones in the intermediate region of the nucleus ambiguus. We observed unprovoked shortening of expiratory...Full Text Available
1994-04-01
On the function of the mammalian renal papilla and the peristalsis of the surrounding pelvis
UK PubMed Central (United Kingdom)
This is an informal personal review of the development over time of my ideas about the concentrating mechanism of the mammalian renal papilla. It had been observed that animals with a need to produce...Full Text Available
2011-07-01
UK PubMed Central (United Kingdom)
Quantitative probing of heterogeneous regions in muscle is feasible with phosphorus-31 magnetic resonance spectroscopy because of the differentiation of metabolic patterns of glycolytic and oxidative...Full Text Available
1987-12-01
Derivations are made for the mass and the mass-turnover time scale of an accretion disk as a function of the accretion rate, the observed disk radius, the non-viscous disk radius, and two parameters. These parameters depend on the effectiveness of viscosity and tidal angular momentum loss. Application is made to DQ Herculis.
1983-01-01
Studies on accumulation of uranium by fungus Lentinus sajor-caju
Energy Technology Data Exchange (ETDEWEB)
The untreated, heat- and alkali-treated Lentinus sajor-caju mycelia were used for the recovery of uranium from aqueous solutions. The effect of pH, temperature, initial concentration of UO{sub 2} {sup 2+} ions and contact time parameters were investigated in a batch system. The particles sizes of the fungal mycelia were ranging from 100 to 200 {mu}m. Biosorption equilibriums were established in about 30 min and the correlation regression coefficients show that the adsorption process can be well defined by the Freundlich equation. The alkali treated form had a high biosorption capacity (378 mg/g) than those of the untreated (268 mg/g) and heat-treated fungal mycelia (342 mg/g). Optimum biosorption was observed at pH 4.5 for all the tested fungal preparations and was independent of temperature (5-35 deg. C). In addition, the polarity and surface energy of the fungal biomass film preparations were determined by contact angle measurement. The ...
2006-08-21
Three adolescents (ages 14-17) with emotional and behavioral disorders displayed chronic disruptive behavior in their self-contained classrooms at a self-contained alternative school. A descriptive functional behavioral assessment was conducted for each student. Data from file review, structured interviews, and direct observations were used to identify the functions of their disruptive behaviors. Then, function-based interventions were systematically constructed for each student and implemented for an extended period (nearly 6 weeks) within the most problematic situation in their classrooms. The interventions improved each student's behavior and the effects maintained during follow-up and generalized to instruction in a nonintervention classroom. Social validity data comparing the interventions to baseline practices revealed the function-based intervention had moderately higher ...
2011-02-01
Space activities in the Bolivarian Republic of Venezuela
British Library Electronic Table of Contents (United Kingdom)
This paper summarizes the establishment and current development of space activities in the Bolivarian Republic of Venezuela. Space activities in Venezuela are focused on the areas of telecommunications, Earth observation and research on the physical properties of the Earth, and have as a primary goal the satisfaction of social needs. Current development of space activities started in 1999 when the new National Constitution recognized the value of outer space as the common heritage of mankind, and the key role of science and technology in promoting human welfare. The Bolivarian Agency for Space Activities (ABAE) was created in 2007. Its legal framework recognizes three key elements that drive its policy: the participation of society, capacity building and human training, and international c...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
Currently it can be observed that in the case of generator drives as well as 'mechanical drives' smaller units are demanded with a steam turbine capacity of up to 150 MW and clearly higher efficiencies. MAN TURBO is meeting the challenge through realisation of a comprehensive development project aiming at the extension of the application range of the current steam turbine series.
2008-07-01
Radial distribution functions of amorphous silicon
Energy Technology Data Exchange (ETDEWEB)
Substantial changes in the radial distribution function of amorphous Si films have been observed in neutron-diffraction studies. The spectra indicate changes in short-range order associated with an approx.11% modification in the bond-angle distribution width. The results allow the first direct comparison of structural and vibrational Raman probes of variations in local order in thin-film amorphous solids. Good agreement is obtained between the measured bond-angle variation and that based on Raman estimates.
1989-03-15
On the Field Dependent Surface Resistance Observed in Superconducting Niobium Cavities
A quantitative description is presented of the non-linear current-voltage response in superconducting niobium cavities for accelerator application. It is based on a fit for a large sample of data from cavity tests of different kind. Trial functions for the surface resistance describing this non-linear relation are established by a least square data fit. Those trial functions yielding the best fit are quantitatively explained by basic physics.
2009-01-01
Density changes in amorphous Pd{sub 80}Si{sub 20} during low temperature ion irradiation
Energy Technology Data Exchange (ETDEWEB)
Density changes in amorphous Pd{sub 80}Si{sub 20} during ion irradiation below 100K were detected by in situ HVEM measurements of the changes in specimen length as a function of ion fluence. A decrease in mass density as a function of the ion fluence was observed. The saturation value of the change in mass density was determined to be approximately -1.2%.
1994-11-01
Magnetic behavior and crystal field of Pr"3"+ in praseodymium selenate octahydrate
International Nuclear Information System (INIS)
Measurements are made on the principal magnetic susceptibilities and anisotropies of praseodymium selenate octahydrate single crystals in the temperature range 90 to 300 K. Although the effective magnetic moment is close to the free ion value, the anisotropy is quite high at room temperature. A least sequares fit of the Curie-Weiss law to the observed average susceptibility yields -36.5 K as the paramagnetic Curie temperature. An analysis of the results with a crystal field (CF) of D_4 symmetry, explains the observed results quite well. The CF and the spin-orbit interaction matrix is block diagonalized in the complete 33 dimensional basis of the "3H term in order to obtain the Stark energies and their eigenstates. Intermediate coupling effects are also considered. The ground state being a singlet, the g-factors are absent. Some predictions on the electronic heat capacity and the electronic quadrupole splitting are made in ...
1988-09-01
Growth and gas exchange response to water shortage of a maize crop on different soil types
British Library Electronic Table of Contents (United Kingdom)
The effect of water shortage on growth and gas exchange of maize grown on sandy soil (SS) and clay soil was studied. The lower soil water content in the SS during vegetative growth stages did not affect plant height, above-ground biomass, and leaf area index (LAI). LAI reduction was observed on the SS during the reproductive stage due to early leaf senescence. Canopy and leaf gas exchanges, measured by eddy correlation technique and by a portable photosynthetic system, respectively, were affected by water stress and a greater reduction in net photosynthetic rate (A N) and stomatal conductance (g s) was observed on SS. Chlorophyll and carotenoids content was not affected by water shortage in either condition. Results support two main conclusions: (1) leaf photosynthetic capacity was unaffec...
2009-01-01
Energy Technology Data Exchange (ETDEWEB)
The first study in this dissertation describes the development of a suppressed ion chromatographic (SIC) technique for the direct, simultaneous determination of the As and Se oxyanions in soil solution. Baseline resolution of 1 mg L[sup [minus]1] each of arsenite, arsenate, selenite, and selenate was achieved in the presence of 50 mg L[sup [minus]1] each of F, Cl, NO[sub 3]-N, SO[sub 4]-S, and PO[sub 4]-P. Detection limits ranged from 0.026 mg L[sup [minus]1] for selenite to 0.120 mg L[sup [minus]1] for arsenate. The accuracy of the SIC technique was verified by comparison to spectroscopic methods. The second study investigated the suitability of linear-plateau regression analysis for statistical evaluation of As adsorption data. The time required to reach the adsorption plateau depended on soil characteristics and As species. Identification of the adsorption plateau by the linear-plateau model allowed comparison of adsorption rates and maxima through analysis of covariance and least ...
1992-01-01
Energy Technology Data Exchange (ETDEWEB)
The significant and rapid reduction of greenhouse gas emissions is recognized as necessary to mitigate the potential climate effects from global warming. The postcombustion capture (PCC) and storage of carbon dioxide (CO{sub 2}) produced from the use of fossil fuels for electricity generation is a key technology needed to achieve these reductions. The most mature technology for CO{sub 2} capture is reversible chemical absorption into an aqueous amine solution. In this study the results from measurements of the CO{sub 2} absorption capacity of aqueous amine solutions for 76 different amines are presented. Measurements were made using both a novel isothermal gravimetric analysis (IGA) method and a traditional absorption apparatus. Seven amines, consisting of one primary, three secondary, and three tertiary amines, were identified as exhibiting outstanding absorption capacities. Most have a number of structural features in common including steric ...
2009-08-15
The probability distribution of cluster formation times and implied Einstein Radii
We provide a quantitative assessment of the probability distribution function of the concentration parameter of galaxy clusters. We do so by using the probability distribution function of halo formation times, calculated by means of the excursion set formalism, and a formation redshift-concentration scaling derived from results of N-body simulations. Our results suggest that the observed high concentrations of several clusters are quite unlikely in the standard Lambda CDM cosmological model, but that due to various inherent uncertainties, the statistical range of the predicted distribution may be significantly wider than commonly acknowledged. In addition, the probability distribution function of the Einstein radius of A1689 is evaluated, confirming that the observed value of ~45" +/- 5" is very improbable in the currently favoured cosmological model. If, however, a variance of ~20% ...
2008-01-01
International Nuclear Information System (INIS)
Ozone is a principal component of photochemical air pollution endogenous to numerous metropolitan areas. It is primarily formed by the oxidation of NOx in the presence of sunlight and reactive organic compounds. Ozone is a highly active oxidizing agent capable of causing injury to the lung. Lung injury may take the form of irritant effects on the respiratory tract that impair pulmonary function and result in subjective symptoms of respiratory discomfort. These symptoms include, but are not limited to, cough and shortness of breath, and they can limit exercise performance. The effects of ozone observed in humans have been primarily limited to alterations in respiratory function, and a range of respiratory physiological parameters have been measured as a function of ozone exposure in adults and children. These affects have been observed under widely varying (clinical experimental and ...
1994-07-01
Energy Technology Data Exchange (ETDEWEB)
In rat adipocyte membranes, both beta-adrenergic agonists and beta-adrenergic antagonists competed with (--)(/sup 3/H)dihydroalprenolol for high affinity (KD 2-4 nM) and low capacity binding sites. The antagonists but not the agonists competed with (--)(/sup 3/H)dihydroalprenolol for lower affinity and higher capacity sites. The present studies were performed in order to characterize the adipocyte beta-adrenergic receptor and distinguish it from low affinity, higher capacity sites which were heat-labile and not stereoselective. When isoproterenol was used to define the nonspecific binding, saturation studies showed a single binding site with a capacity of approximately 100 fmol/mg membrane protein (corresponding to approximately 50,000 sites/adipocyte). Binding was saturated by 10 nM (--)(/sup 3/H)dihydroalprenolol. Approximate KD's of 204 nM were observed. Kinetic analysis ...
1982-09-01
On the temperature dependence of the magnetic excitations
International Nuclear Information System (INIS)
We compare experimental data for temperature dependence of the magnetic order parameter and the magnetic excitations (spin waves) in materials with a quenched orbital moment and a well-defined spin quantum number. It is observed that the thermal decrease of the two quantities proceeds according to the same analytical function of the type y(T)=1-cT"#epsilon# with an identical exponent #epsilon#. This power function applies not only asymptotically for T->0 but holds over a wide temperature range. The exponent #epsilon# is universal, i.e. independent of spin order type and lattice symmetry and depends only on the dimensionality of the relevant interactions and on whether the spin quantum number is integer or half-integer. The different T"#epsilon# functions are identified as representations of stable universality classes. The fact that order parameter and magnetic excitations follow the same T"#epsilon# ...
2005-07-15
On The Parent Population of Radio Galaxies and the FRI - FRII Dichotomy
We test the hypothesis that radio galaxies are a random subset of otherwise normal elliptical galaxies. Starting with the observed optical luminosity functions for elliptical galaxies, we show that the probability of an elliptical forming a radio source is a continuous, increasing function of optical luminosity, proportional to L squared. With this probability function and the luminosity function of normal elliptical galaxies as input to Monte Carlo simulations, we reproduce the observed distribution of radio galaxies in the radio-optical luminosity plane. Our results show that radio galaxies are a luminosity-biased but otherwise random sample of elliptical galaxies. This unified view of radio-loud and radio-quiet ellipticals also explains the well known difference of ~0.5 mag in average optical luminosity between FRI and FRII radio galaxies as a simple ...
2001-01-01
An analysis of a firm?s capacity in Mazda?s Keiretsu
British Library Electronic Table of Contents (United Kingdom)
Capacity is defined as the power resulting from the specific position of a company in a network organization. This article extends the theory of network organizations to examine Mazda?s Yokokai Keiretsu, and proposes a new approach to calculating a firm?s capacity in a network. Capacity is divided into two categories, take-in capacity and take-out capacity, and the gap between them is called the capacity difference. We analyze the impact of capacity difference as a determinant of corporate performance in network organizations, thus providing a new perspective for successful corporate management.
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
A series of copolymers based on the cellulose acetate/propionate-g.co-acrylic acid system has been prepared under radiation-induced control. These copolymers have been assessed for their water-retention capacity both in an unmodified state and after ''decrystallization'' or ''neutralization'' treatments. The grafting of acrylic acid onto the cellulose acetate/propionate had little effect on the water retention power of the cellulose acetate/propionate. However, improvements to the water retentivity was obtained after ''decrystallization'' procedures had been carried out on the copolymers using selected alkali metal salts with methanol as the continuous medium. The water-retentivity of the copolymers increased with increase in the extent of grafting, though the effect is less pronounced at high graft levels. Neutralization of the ...
1990-01-01
Energy Technology Data Exchange (ETDEWEB)
The thermal energy storage performance and phase change stability of mix phase change materials consisted of stearic acid and Na{sub 2}PO{sub 4}.12H{sub 2}O are studied by means of Fourier transformation infrared spectrum analyses (FTIR) and Differential Scanning Calorimetry (DSC). The specific heat capacity of mix materials is also determined experimentally. The results show that all absorption peaks of functional groups and chemical bonds of stearic acid still exist, which suggests that these crystal materials composed of stearic acid and Na{sub 2}PO{sub 4}.12H{sub 2}O have good phase change stability and chemical compatibility. Thus, disadvantages caused by the subcooling of Na{sub 2}PO{sub 4}.H{sub 2}O and the low specific heat capacity of stearic acid can be solved, it is speculated that complement each other on the basis of organic/inorganic characteristics in itself is carried out for these two component materials of ...
2010-07-15
Multicast Capacity Scaling of Wireless Networks with Multicast Outage
Multicast transmission has several distinctive traits as opposed to more commonly studied unicast networks. Specially, these include (i) identical packets must be delivered successfully to several nodes, (ii) outage could simultaneously happen at different receivers, and (iii) the multicast rate is dominated by the receiver with the weakest link in order to minimize outage and retransmission. To capture these key traits, we utilize a Poisson cluster process consisting of a distinct Poisson point process (PPP) for the transmitters and receivers, and then define the multicast transmission capacity (MTC) as the maximum achievable multicast rate times the number of multicast clusters per unit volume, accounting for outages and retransmissions. Our main result shows that if $\\tau$ transmission attempts are allowed in a multicast cluster, the MTC is $\\Theta\\left(\\rho k^{x}\\log(k)\\right)$ where $\\rho$ and $x$ are functions of $\\tau$ depending ...
2010-01-01
Evaluation on the cooling capacity of the SMART-P CEDM cooler using CFD code
Energy Technology Data Exchange (ETDEWEB)
Ball screw bearings are used for the fine control of Control Rod Drive Mechanism (CEDM) for the SMART-P. Because the friction coefficient of the ball screw bearings suddenly increases at the limit temperature of 120 .deg. C, the surrounding temperature of the ball screw bearings should be less than the limit temperature for the functional integrity of the CEDM. The CEDM coolers are installed at the lower portion of the ball screw bearings to maintain the bearings' temperature less than the limit. In order to check the CEDM cooler satisfy the temperature limit of ball screw bearing at the possible operational conditions, the cooling capacity of the CEDM coolers, which was determined at the stage of 'conceptual design', is evaluated using the Computational Fluid Dynamics(CFD) code, Fluent. The analysis result shows that the current CEDM coolers satisfy the CEDM temperature limit of 120 .deg. C for the all the operation ...
2004-07-01
Evaluation on the cooling capacity of the SMART-P CEDM cooler using CFD code
International Nuclear Information System (INIS)
Ball screw bearings are used for the fine control of Control Rod Drive Mechanism (CEDM) for the SMART-P. Because the friction coefficient of the ball screw bearings suddenly increases at the limit temperature of 120 .deg. C, the surrounding temperature of the ball screw bearings should be less than the limit temperature for the functional integrity of the CEDM. The CEDM coolers are installed at the lower portion of the ball screw bearings to maintain the bearings' temperature less than the limit. In order to check the CEDM cooler satisfy the temperature limit of ball screw bearing at the possible operational conditions, the cooling capacity of the CEDM coolers, which was determined at the stage of 'conceptual design', is evaluated using the Computational Fluid Dynamics(CFD) code, Fluent. The analysis result shows that the current CEDM coolers satisfy the CEDM temperature limit of 120 .deg. C for the all the operation modes of the SMART-P and ...
2004-05-27
Energy Technology Data Exchange (ETDEWEB)
The biosorption of copper(II) ions from aqueous solution by Tectona grandis L.f. was studied in a batch adsorption system as a function of pH, metal ion concentration, adsorbent concentration and adsorbent size. The biosorption capacities and rates of copper(II) ions onto T. grandis L.f. were evaluated. The Langmuir, Freundlich, Redlich-Peterson and Temkin adsorption models were applied to describe the isotherms and isotherm constants. Biosorption isothermal data could be well interpreted by the Langmuir model with maximum adsorption capacity of 15.43 mg/g of copper(II) ion on T. grandis L.f. leaves powder. The kinetic experimental data properly correlated with the second-order kinetic model. Various thermodynamic parameters such as {delta}G{sup o}, {delta}H{sup o}, and {delta}S{sup o} were calculated indicating that this system was a spontaneous and exothermic process.
2006-09-21
International Nuclear Information System (INIS)
Iron is an essential micronutrient. As an integral part of hemoglobin, it is essential for the transport of oxygen in blood to the tissues. It is an important component of cytochromes and other tissue enzymes that are critical for cellular respiration and of myoglobin that helps maintain oxygen reserve in the muscle. It is also involved in the normal functioning of the immune function, and in the synthesis of steroid hormones and bile acids. There are serious functional consequences to iron deficiency and iron deficiency anemia (IDA) in the human body. The deleterious effects include increased morbidity, preterm delivery, low birth weight, delayed cognitive development, lowered cellular immunity and reduced physical work capacity. However, iron deficiency and IDA remain the world's most common deficiency disease in the 21st century. Recent estimates of people affected with iron deficiency and IDA are ...
2002-06-24
British Library Electronic Table of Contents (United Kingdom)
Objectives: Intra-operative cisplatin-based intra-peritoneal chemotherapy (IPC) may alter renal function in patients with advanced ovarian cancer. The aim of this study was to describe postoperative alteration of renal function after cisplatin-based IPC and to identify risk factors for moderate to severe acute renal failure. Study design: This prospective observational study was carried out on 77 consecutive patients who underwent cisplatin-based IPC procedures, with (n=23) or without (n=54) intra-peritoneal epinephrine, for advanced ovarian cancer. Postoperative renal function was assessed using serial serum creatinine measurements and was based on serum creatinine changes from pre-operative values, according to the risk, injury, failure, loss, end-stage kidney disease (RIFLE) classificat...
2011-01-01
On The Parent Population of Radio Galaxies and the FR I--II Dichotomy
The possibility of radio galaxies being random sample of otherwise normal elliptical galaxies is tested. Starting with the observed optical luminosity functions for elliptical galaxies, it is shown that the probability of an elliptical forming a radio source is a continuous, increasing function of optical luminosity, precisely proportional to square of the optical luminosity of the galaxy. Once the probability function is fixed, the luminosity function of normal elliptical galaxies is used as input for Monte Carlo simulations that reproduce the distribution of radio galaxies in the radio-optical luminosity plane. Our results show that radio galaxies are luminosity biased, but otherwise random sample of elliptical galaxies. This unified view of radio and non-radio ellipticals also explains the well known difference of 0.5 mag in average optical luminosity between FRI and FRII radio ...
2001-01-01
The specific heat capacity and thermal conductivity of normal liquid "3He
International Nuclear Information System (INIS)
By observing the diffusion of a heat pulse along a 10-cm column of normal liquid "3He with the aid of two vibrating wire thermometers, it has been possible to measure the heat capacity C and thermal conductivity K of the liquid in the temperature range from T /sub c/ to 10 mK and at pressures of 0.21, 4.39, 9.97, 20.01, and 29.32 bar. By using a Pt NMR thermometer, an LCMN thermometer, and a "3He melting curve thermometer calibrated using the melting curve given by Greywall in 1983, a temperature scale has been established and (1) it has been shown that this melting curve is consistent in the temperature range 5-22 mK with the Korringa law for the Pt thermometer with a Korringa constant of 29.8 +/- 0.2 sec mK, (2) departures have been observed from the Curie-Weiss law for LCMN at low temperatures, and (3) values of the superfluid transition temperature have been obtained that are about 4% lower than the Helsinki values. The ...
1986-01-01
Report on Thermo-Hydro-Mechanical Laboratory Tests Performed by CIEMAT on Febex Bentonite 2004-2008
International Nuclear Information System (INIS)
The results of the laboratory studies performed by CIEMAT with the FEBEX bentonite in the context of WP3.2 of the NF-PRO Project and of the Agreement ENRESA-CIEMAT Anexo V are presented and analysed in this report. They refer to the effect of the hydraulic gradient on the permeability of bentonite, the effect of the thermal gradient on the hydration kinetics of bentonite, and the repercussion of temperature on the hydro-mechanical properties of bentonite (swelling, permeability and water retention capacity). In all the cases the bentonite has been used compacted to densities expected in the engineered barrier of a high-level radioactive waste repository. The existence of threshold and critical hydraulic gradients has been observed, both of them dependent on bentonite density and water pressures. After more than seven years of hydration, the 40-cm high bentonite columns are far from full saturation, the thermal gradient additionally delaying the ...
Report on Thermo-Hydro-Mechanical Laboratory Tests Performed by CIEMAT on Febex Bentonite 2004-2008
Energy Technology Data Exchange (ETDEWEB)
The results of the laboratory studies performed by CIEMAT with the FEBEX bentonite in the context of WP3.2 of the NF-PRO Project and of the Agreement ENRESA-CIEMAT Anexo V are presented and analysed in this report. They refer to the effect of the hydraulic gradient on the permeability of bentonite, the effect of the thermal gradient on the hydration kinetics of bentonite, and the repercussion of temperature on the hydro-mechanical properties of bentonite (swelling, permeability and water retention capacity). In all the cases the bentonite has been used compacted to densities expected in the engineered barrier of a high-level radioactive waste repository. The existence of threshold and critical hydraulic gradients has been observed, both of them dependent on bentonite density and water pressures. After more than seven years of hydration, the 40-cm high bentonite columns are far from full saturation, the thermal gradient additionally delaying the ...
2009-11-25
Removal of phosphate by mesoporous ZrO{sub 2}
Energy Technology Data Exchange (ETDEWEB)
A type of mesoporous ZrO{sub 2} was synthesized and its phosphate removal potential was investigated in this study. The adsorption isotherm, pH effect, ionic strength effect and desorption were examined in batch experiments. The adsorption data fitted well to the Langmuir model with which the maximum P adsorption capacity was estimated to be 29.71 mg P/g. The amount of phosphate adsorbed increased rapidly in the first 5 h and slowly towards the end of the run, suggesting the possible monolayer coverage of phosphate ions on the surface of the adsorbent. The phosphate adsorption tended to increase with a decrease of pH and an increase of ionic strength. A phosphate desorbability of approximately 60% was observed with 0.5 M NaOH, which indicated a relatively strong bonding between the adsorbed PO{sub 4}{sup 3-} and the sorptive sites on the surface of the adsorbent. The immobilization of phosphate probably occurs by the mechanisms of ion exchange ...
2008-03-01
Positron emission tomography for modelling of geochemical transport processes in clay
Energy Technology Data Exchange (ETDEWEB)
Geological clay formations are investigated for use as final underground deposit for heat producing nuclear waste. Special kinds of clay (e.g. bentonite) can also be used for the construction of geotechnical barriers. For the long time safety prognosis of the nuclear waste repositories the development of geochemical transport models is indispensable. The transport of aqueous solutions in clay is a complex process. The three-layer-minerals bentonite and illite swell by the adsorption of water, if the volume is restricted a high swelling pressure develops. The excellent barrier effect of natural clay formations and geotechnical clay barriers is based on the high swelling pressure and the high adsorption capacity for radionuclides and other pollutants. The two-layer-mineral kaolinite has no swelling capacity. In contrast to sandy layers a special geochemical transport potential exists in clay besides the well known matrix potential which ...
2004-07-01
Isotope exchange reaction between tritiated water and hydrogen on SiC
Energy Technology Data Exchange (ETDEWEB)
SiC has been considered as a primary candidate material for a first wall component in future fusion reactor because it has been claimed that SiC has excellent high-temperature properties, good chemical stability and low activation. However, the behavior of tritium on SiC has not been discussed yet. In this study, tritium trapping capacity on the surface of SiC was experimentally obtained at the temperature range of 25-800 deg. C in consideration of tritium trapping to the experimental system. The capacity, which was independent of the water vapor pressure in the gas phase and the temperature, was determined as about 10{sup 6} Bq/cm{sup 2}. The isotope exchange reaction rate between tritiated water in a gas phase and hydrogen on the surface was quantified at the temperature of 25, 500 and 700 deg. C in consideration of the behavior of tritium trapping at change of experimental condition by the numerical curve fitting method applying the serial ...
2003-11-15
Isotope exchange reaction between tritiated water and hydrogen on SiC
International Nuclear Information System (INIS)
SiC has been considered as a primary candidate material for a first wall component in future fusion reactor because it has been claimed that SiC has excellent high-temperature properties, good chemical stability and low activation. However, the behavior of tritium on SiC has not been discussed yet. In this study, tritium trapping capacity on the surface of SiC was experimentally obtained at the temperature range of 25-800 deg. C in consideration of tritium trapping to the experimental system. The capacity, which was independent of the water vapor pressure in the gas phase and the temperature, was determined as about 10"6 Bq/cm"2. The isotope exchange reaction rate between tritiated water in a gas phase and hydrogen on the surface was quantified at the temperature of 25, 500 and 700 deg. C in consideration of the behavior of tritium trapping at change of experimental condition by the numerical curve fitting method applying the serial reactor ...
2003-11-15
Biosorption of {sup 241}Am by Rhizopus arrihizus: preliminary investigation and evaluation
Energy Technology Data Exchange (ETDEWEB)
The biosorption of {sup 241}Am from solution by a fungus--Rhizopus Arrihizus (R. arrihizus), and the effect of experimental conditions on the adsorption were investigated. The preliminary results showed that the biosorption of {sup 241}Am by R. arrihizus is very efficient. An average of more than 99% of the total {sup 241}Am was removed by R. arrihizus of 1.3 g/l (dry weight) from {sup 241}Am solutions of 5.6-111 MBq/l (44.3-877.2 {mu}g/l) (C{sub 0}), with adsorption capacities (W) of 4.2-79.4 MBq/g biomass (dry weight) (33.2-627.5 {mu}g/g). The biosorption equilibrium was achieved within 1 h and the optimum pH ranged from 1 to 3. No significant differences in {sup 241}Am biosorption were observed at 10-45 deg. C, or in solutions containing Au{sup 3+} or Ag{sup +}, even 2000 times above {sup 241}Am concentration. The relationship between concentrations and adsorption capacities of {sup 241}Am indicated that the {sup 241}Am ...
2002-08-01
Technology base research on the slurry-zinc/air battery system: Final report
Energy Technology Data Exchange (ETDEWEB)
The slurry-Zn/air battery system has received renewed R and D interest because it does not have the shape-change problems of batteries with Zn-plate electrodes and can sustain higher current densities and specific peak power than other metal-air battery systems. Additional advantages of the slurry-Zn/air battery include safety, low environmental impact, potential low cost, and separation of energy density from power density functions for design purposes. In this work we present results obtained at the individual cell level as a basis to estimate the performance of a secondary slurry-Zn/air battery system. The expected specific energy of such systems has been increased as a result of the use of capacity-extension additives, which has been one of the major thrusts of this work. 8 refs., 20 figs., 5 tabs.
1988-08-01
Techno-economic investigation of an air humidification-dehumidification desalination process
Energy Technology Data Exchange (ETDEWEB)
This article presents a humidification-dehumidification (H.D.) process suitable for desalination of sea- and brackish water. The work correlated performance characteristics of the combination of different components in such a loop. Water yield, energy requirement and design data are evaluated as functions of different parameters. The investigation covered water to air mass ratios ranging from 60 to 80, concentration ratios between 2 and 5, at a temperature difference of between 10 and 16 C, along the liquid for dehumidification. The results showed that 76% of energy consumed in the humidifier is recovered by condensation. Increase of the concentration ratio to 5 can reduce the make-up water and rejected brine by about 58% and 24% respectively. Cost calculations show that the H.D. process has significant potential as an alternative for small capacity desalination plants and permits to operate systems as small as 10 m[sup 3]/day in output. ...
1993-08-01
British Library Electronic Table of Contents (United Kingdom)
This paper analyzes the F-policy M/M/1/K queueing system with working vacation and an exponential startup time. The F-policy deals with the issue of controlling arrivals to a queueing system, and the server requires a startup time before allowing customers to enter the system. For the queueing systems with working vacation, the server can still provide service to customers rather than completely stop the service during a vacation period. The matrix-analytic method is applied to develop the steady-state probabilities, and then obtain several system characteristics. We construct the expected cost function and formulate an optimization problem to find the minimum cost. The direct search method and Quasi-Newton method are implemented to determine the optimal system capacity K, the optimal thre...
2010-01-01
Horizontal ground coupled heat pump: Thermal-economic modeling and optimization
Energy Technology Data Exchange (ETDEWEB)
The modeling and optimizing processes of a Ground Coupled Heat Pump (GCHP) with closed Horizontal Ground Heat eXchanger (HGHX) are presented in this paper. After thermal modeling of GCHP including HGHX, the optimum design parameters of the system were estimated by minimizing a defined objective function (total of investment and operation costs) subject to a list of constraints. This procedure was performed applying Genetic Algorithm technique. For given heating/cooling loads and various climatic conditions, the optimum values of saturated temperature/pressure of condenser and evaporator as well as inlet and outlet temperatures of the water source in cooling and heating modes were predicted. Then, for our case study, the design parameters as well as the configuration of HGHX were obtained. Furthermore, the sensitivity analysis of change in the total annual cost of the system and optimum design parameters with the climatic conditions, cooling/heating ...
2010-12-15
Gas Appliance Technology Center: Annual report, January-December 1986
Energy Technology Data Exchange (ETDEWEB)
The report reviews the activity during the fourth year of Gas Research Institute's Gas Appliance Technology Center program. Work on gas appliances involved a conceptual table-top multi-function oven, development of an indirect-fired conveyor oven, and performance comparisons of smooth cooktops. Performance-evaluation methods for commercial ovens were evaluated. Design improvements were made to a direct-fired conveyor oven and a pulse-combustion deep-fat fryer. Performance of common vents were studied, and a device was designed to allow incorporation of appliances with positive vent pressures into such systems. Standards-related work included draft-hood capacities, flexible corrugated-connector corrosion, and sediment trap efficiencies. Heating-related work comprised conceptual design of a vented baseboard heater and a centralized heat-transfer fluid system.
1987-08-01
Extrinsic allergic alveolitis induced by the yeast Debaryomyces hansenii.
A 65-yr-old female developed cough, fever and dyspnoea following repeated exposure to a home ultrasonic humidifier. High-resolution computed tomography showed ground-glass opacity in both lung fields. Arterial blood gas analysis gave an oxygen tension of 8.38 kPa (63 Torr). Pulmonary function testing revealed restrictive ventilatory impairment with a reduction in the diffusing capacity. The diagnosis of extrinsic allergic alveolitis (EAA) was confirmed by radiographic findings, pathological evidence of alveolitis and reproductive development by a provocation test to the humidifier water. The yeast Debaryomyces Hansenii was the only microorganism cultured from the water of the humidifier. The double diffusion precipitating test and lymphocyte proliferative response was positive for an extract of D. Hansenii, providing evidence to incriminate this fungus. This is the first described case of EAA caused by D. Hansenii. PMID:12449192
2002-11-01
British Library Electronic Table of Contents (United Kingdom)
Summary There are many active functional compounds in citrus peels, such as flavonoid and phenolic acid. Scientists tried to obtain more bioactive components from citrus peels by various methods. This research investigated the effects of different drying temperatures (50, 60, 70, 80, 90 and 100-C) on changes in the flavonoid, phenolic acid and antioxidative activities of citrus fruit (Citrus sinensis (L.) Osbeck) peels. The total phenolic and flavonoid contents of drying treated orange peels were decreased by lower drying temperature (50 and 60-C) and increased by higher drying temperature (70, 80, 90 and 100-C). Amounts of phenolic compounds in the 100-C treated sample extract were significantly higher than the amounts in the samples heated at other temperatures (P-50 values of orange pee...
2011-01-01
Application of FFT-based Algorithms for Large-Scale Universal Kriging Problems
British Library Electronic Table of Contents (United Kingdom)
Looking at kriging problems with huge numbers of estimation points and measurements, computational power and storage capacities often pose heavy limitations to the maximum manageable problem size. In the past, a list of FFT-based algorithms for matrix operations have been developed. They allow extremely fast convolution, superposition and inversion of covariance matrices under certain conditions. If adequately used in kriging problems, these algorithms lead to drastic speedup and reductions in storage requirements without changing the kriging estimator. However, they require second-order stationary covariance functions, estimation on regular grids, and the measurements must also form a regular grid. In this study, we show how to alleviate these rather heavy and many times unrealistic restr...
2009-01-01
Energy Technology Data Exchange (ETDEWEB)
Finland has some 10 million hectares of peatland, accounting for almost a third of its total area. Macroclimatic conditions have varied in the course of the Holocene growth and development of this peatland, and with them the habitats of the peat-forming plants. Temperatures and moisture conditions have played a significant role in determining the dominant species of mire plants growing there at any particular time, the resulting mire types and the accumulation and deposition of plant remains to form the peat. While in a natural state the mires of Finland have functioned as carbon dioxide sinks throughout the post-glacial period, but the ditching of peatland for forestry and agriculture, amounting to some 5,7 million hectares in Finland, has affected their water balance, especially over the last hundred years, and has thereby altered the quantity and species composition of the mire vegetation. The invasion of trees and woody plants to replace the typical mire plants ...
2007-07-01
Energy Technology Data Exchange (ETDEWEB)
Concerning the gamma emitters, the only analysis on soils put in evidence the presence of cesium-137 ({sup 137}Cs), that does not come from the cyclotron functioning but from past man action as the Chernobylsk accident and the nuclear weapon tests in atmosphere. Independently of the functioning of the installation, we observe an increase of the ambient gamma radiation only near radioactive waste storage. It results of the storage of the former cyclotron elements. The induced increase is moderated because at 5 meters the values do not exceed the background noise. In relation with the functioning of the installation an increase of the ambient gamma radiation is noticed. Two causes are to considered: the release of radionuclides in atmosphere with gaseous effluents and the radiance of radiation sources inside the building. After the stopping of the installation (48 h at least), no increase of gamma ...
2004-07-01
Traffic flow optimization on rural networks
Energy Technology Data Exchange (ETDEWEB)
Seasonal traffic on intercity corridors often creates severe congestion at various bottlenecks, such as land-drops and drawbridges. A Traffic Simulation And Optimization model (TSAO) has been developed in order to 1) evaluate traffic impacts (including travel time, vehicle operating costs, accidents, air pollution and fuel consumption) of a given routing pattern on a network, and 2) determine the optimal flow pattern. In its latest version, the TSAO model uses: 1) a macroscopic simulation approach to trace vehicle platoons through a network; 2) Greenshield's equation to represent volume-speed relationship on freeways and multi-lane highways, and Highway Capacity Manual method for two-lane rural highways; 3) Lighthill's shockwave function to simulate queue propagation; 4) event-scan time management for simulation; 5) variable link capacity for two-lane rural highways or to stimulate incidents; 6) AASHTO ...
1983-01-01
International Nuclear Information System (INIS)
A study of the magnetic properties and the heat capacity as functions of temperature and magnetic field of two ternary carbides RNiC_2, where R=La and Ce, confirms that LaNiC_2 becomes superconducting at T_c=2.7thinspK, and that CeNiC_2 orders antiferromagnetically below 18thinspK. LaNiC_2 is a conventional superconductor with a critical field of 900 Oe at T=2thinspK. CeNiC_2 obeys the Curie-Weiss law between 50 and 300thinspK showing the nearly full Ce"3"+ magnetic moment, p_e_f_f=2.47(1)#mu#_B, and has a negative paramagnetic Weiss temperature #THETA#_p=-18.3(8)thinspK. A low net magnetic moment in the ordered state, which is far from saturation in a magnetic field of 5thinspT, is consistent with an antiferromagnetic ground state. Below 20thinspK CeNiC_2 shows multiple-step magnetic transitions at 18, 10, and 2.4thinspK. Both LaNiC_2 (in the normal state) and CeNiC_2 have the same electronic heat capacity, ...
1998-07-01
Energy Technology Data Exchange (ETDEWEB)
In Chapter 2 the evaluation methods of input ground motions for seismic design are summarized and especially the empirical and/or stochastic Green's function method is introduced in order to calculate the broadband strong motions based on the physically reliable fault model. Then the evaluation procedure is applied to the Ulsan fault system near which Wolsung nuclear power plant is located. In chapter3, the PSHA case studies for Wolsung NPP site are performed, in which multi attenuation equations of earthquake motions are adopted. Moreover, the results of seismic hazard evaluation for eight sites in Korea are shown. In addition, the contents of two literatures on seismic hazard evaluation are introduced. In chapter 4, isolation devices for emergency diesel generator have been studied. The models for friction-pendulum system, high damping rubber bearing and natural rubber bearing are developed and implemented in the TDAP-III. Then, the rubber bearings as ...
2004-12-01
Sudden freeze-out vs continuous emission: duality in hydro-kinetic approach to A+A collisions
The problem of spectra formation in hydrodynamic approach to A+A collisions is discussed. It is analyzed in terms of the two different objects: distribution and emission functions. We show that though the process of particle liberation, described by the emission function, is, usually, continuous in time, the observable spectra can be also expressed by means of the Landau/Cooper-Frye prescription. We argue that such an approximate duality results from some symmetry properties that systems in A+A collisions reach to the end of hydrodynamic evolution and reduction of the collision rate at post hydrodynamic stage
2004-01-01
Optimization of inspection and replacement period by using Bayesian statistics
International Nuclear Information System (INIS)
This study describes the formulations to optimize the time interval of inspections and/or replacements of equipment/parts taking into account the probability density functions (PDF) for failure rates and parameters of failure distribution functions (FDF) and evaluates the optimized results of these time intervals using our formulations by comparing with those using only representative values of failure rates and the parameters of FDF instead of using these PDFs. The PDFs are obtained with Bayesian method and the representative values are obtained with likelihood estimation method. However, any significant difference is not observed between both optimized results within our preliminary calculations. (author)
2006-07-01
International Nuclear Information System (INIS)
The total and differential atomic pair-correlation functions of an icosahedral (quasicrystalline) solid were determined for the first time, directly by the differential anomalous-x-ray-scattering technique using synchrotron radiation. The observed atomic distances involving uranium atoms in icosahedral Pd/sub 58.8/U/sub 20.6/Si/sub 20.6/ suggest the presence of a quasicrystalline sublattice with vertex decoration. The pair distribution functions in the icosahedral and amorphous phases are similar up to the second-nearest neighbors, or up to 6 A-circle.
Energy Technology Data Exchange (ETDEWEB)
The total and differential atomic pair-correlation functions of an icosahedral (quasicrystalline) solid were determined for the first time, directly by the differential anomalous-x-ray-scattering technique using synchrotron radiation. The observed atomic distances involving uranium atoms in icosahedral Pd/sub 58.8/U/sub 20.6/Si/sub 20.6/ suggest the presence of a quasicrystalline sublattice with vertex decoration. The pair distribution functions in the icosahedral and amorphous phases are similar up to the second-nearest neighbors, or up to 6 A-circle.
1986-07-07
System identification is a necessity in control theory. Classical control theory usually considers processes with integer order transfer functions. Real processes are usually of fractional order as opposed to the ideal integral order models. A simple and elegant scheme is presented for approximation of such a real world fractional order process by an ideal integral order model. A population of integral order process models is generated and updated by PSO technique, the fitness function being the sum of squared deviations from the set of observations obtained from the actual fractional order process. Results show that the proposed scheme offers a high degree of accuracy.
2008-01-01
A critical study of poiseuille flow of couple stress fluid with applications to blood flow
It is shown that the method used for comparing theoretical and experimental results is erroneous and the values of the couple stress parameters obtained for blood flow are incorrect. A method for determining the couple stress parameters is presented. The computational work in the improved method is considerably less. It is observed that both the couple stress parameters are functions of concentration. An empirical relation between concentration and the stress parameters is obtained. The shear viscosity and non-dimensional axial velocity are functions of concentration. Some uses of determining the values of the couple stress parameters are suggested.
1981-01-01
Energy Technology Data Exchange (ETDEWEB)
An adaptive contingency selection process is set up which produces outage lists in order to guarantee on-line network security control. The quality index system used so far did not detect and reveal all critical variables due to observation problems in the mapping of two functions. The new process uses the results of the outage simulation computing of the system status just past for the drawing up of an up-to-date outage list. A linear correcting function transform the G{sub 2}-values of the standard quality index method - which still incorporate the observation problem effect - into improved values G. Studies which use data from realstic high-voltage networks prove that the detection of critical variables is far superior to ordinary methods. (orig.).
1990-04-23
A New Stem Taper Function for Short-rotation poplar
Energy Technology Data Exchange (ETDEWEB)
A new stem taper function was established for individual trees of two poplar hybrid clones grown on a short-rotation coppice. The model could be easily fitted and required three parameters to be estimated. It can be used to estimate both diameter at a given height and height for a given top diameter. Two of the three parameters controlled the conical and the neiloid parts of the stem. Significant differences in these parameters were observed between the two clones even if no differences were observed for diameter at breast height or total height of the stem. The model could not be integrated to calculate volumes (total volume, merchantable volume), which were estimated by numerical integration. However, use of this new model allows the optimal length of billets to be determined and thus maximizes the merchantable biomass of poplar in short-rotation coppice by minimizing the biomass of residues.
2003-07-01
Energy Technology Data Exchange (ETDEWEB)
The new generation of performing rechargeable lithium-ion batteries (``rocking-chair``-type) are penalized by important self-output phenomena linked with the use of highly oxidizing positive electrodes. In order to limit this problem in LiMn{sub 2}O{sub 4}/C batteries, two different passivation techniques were used in order to limit the surface contact between the positive electrode and the electrolyte. Thanks to these treatments, a significant reduction of the percentage of irreversible capacity losses is effectively observed. (J.S.) 3 refs.
1996-12-31
General polarization capacity of dual electric layers of anthracite in aqueous solutions
Energy Technology Data Exchange (ETDEWEB)
Investigates polarographically determined capacitative curves of Soviet anthracite (Removsk seam) in solutions of KCl, HCl, phenol, propyl, butyl, amyl and hexyl alcohols. The curves were found to be asymmetric and to raise quickly in their cathode range. Their dependence on electrolyte concentration and displacements of their zero charge points were observed. Displacement values of zero charge potential were tabulated for organic compounds. It was possible to calculate displacements taking the non-uniformity of coal structure into account. It was further possible to assess surface interactions between coal and adsorbed molecules from the viewpoint of molecular energy. Orientation of phenol and alcohol molecules on the coal surface is also pointed out. 10 refs.
1991-03-01
British Library Electronic Table of Contents (United Kingdom)
A new stem cell-scaffold construct based on poly-l-lactide (PLLA) nanofibers grafted with collagen (PLLA-COL) and cord blood-derived unrestricted somatic stem cells (USSC) were proposed to hold promising characteristics for bone tissue engineering. Fabricated nanofibers were characterized using SEM, ATR-FTIR, tensile and contact angle measurements. The capacity of PLLA, plasma-treated PLLA (PLLA-pl) and PLLA-COL scaffolds to support proliferation and osteogenic differentiation of USSC was evaluated using MTT assay and common osteogenic markers such as alkaline phosphatase (ALP) activity, calcium mineral deposition and bone-related genes. All three scaffolds showed nanofibrous and porous structure with suitable physical characteristics. Higher proliferation and viability of USSC was observe...
2011-01-01
Development of Ultra-Fast Silicon Switches for Active X-Band High Power RF Compression Systems
Energy Technology Data Exchange (ETDEWEB)
We present the recent results of our research on the high power ultra-fast silicon RF switches. This switch is composed of a group of PIN diodes on a high purity silicon wafer. The wafer is inserted into a cylindrical waveguide under TE{sub 01} mode, performing switching by injecting carriers into the bulk silicon. Our current design uses a CMOS compatible process and the device was fabricated at SNF (Stanford Nanofabrication Facility). 300 ns switching time has been observed, while the switching speed can be improved further with 3-D device structure and faster driving circuit. Power handling capacity of the switch is at the level of 10 MW. The switch was designed for active X-band RF pulse compression systems--especially for NLC, but it is also possible to be modified for other applications and other frequencies.
2006-03-06
Biosorption of uranium (VI) by immobilized Aspergillus fumigatus beads
Energy Technology Data Exchange (ETDEWEB)
Biosorption of uranium (VI) ions by immobilized Aspergillus fumigatus beads was investigated in a batch system. The influences of solution pH, biosorbent dose, U (VI) concentration, and contact time on U (VI) biosorption were studied. The results indicated that the adsorption capacity was strongly affected by the solution pH, the biosorbent dose and initial U (VI) concentration. Optimum biosorption was observed at pH 5.0, biosrobent dose (w/v) 2.5%, initial U (VI) concentration 60 mg L{sup -1}. Biosorption equilibrium was established in 120 min. The adsorption process conformed to the Freunlich and Temkin isothermal adsorption models. The dynamic adsorption model conformed to pseudo-second order model.
2010-06-15
Absorption of CO/sub 2/ in aqueous solutions of mixtures of alkanolamines
Energy Technology Data Exchange (ETDEWEB)
The bulk removal of CO/sub 2/ from industrial gases is a frequently applied process in the field of gas-treating. Usually chemical solvents are used in order to increase both the solvent-loading capacity and the absorption rate. These solvents often are aqueous solutions of alkanolamines. The loaded-liquid is regenerated at high temperatures with the aid steam. In the present study absorption rates are experimentally determined in various mixtures of amines over a wide range of concentrations. Simultaneously, a model was developed for the description of mass transfer accompanied by parallel reversible chemical reactions. The equations of this mass transfer model could not be solved analytically and therefore numerical techniques were used to obtain an exact description of this process. This model also includes the asymptotic situations of homogeneous catalysts and shuttle mechanism for which in the literature several approximate solutions have been presented. The ...
1988-01-01
Energy Technology Data Exchange (ETDEWEB)
This report covers the progress made on the title project for the project period. Four major areas of inquiry are being pursued. Advanced solid state NMR methods are being developed to assay the distribution of the various important functional groups that determine the reactivity of coals. Special attention is being paid to methods that are compatible with the very high magic angle sample spinning rates needed for operation at the high magnetic field strengths available today. Polarization inversion methods utilizing the difference in heat capacities of small groups of spins are particularly promising. Methods combining proton-proton spin diffusion with {sup 13}C CPMAS readout are being developed to determine the connectivity of functional groups in coals in a high sensitivity relay type of experiment. Additional work is aimed at delineating the role of methyl group rotation in the proton NMR relaxation behavior of coals.
1992-11-25
Human complement protein C99 is a calcium binding protein
International Nuclear Information System (INIS)
Human complement protein C9 is shown to be a metalloprotein that binds 1 mol of Ca"2"+/mol of C9 with a dissociation constant of 3 #mu#m as measured by equilibrium dialysis. Incubation with EDTA removes the bound calcium, resulting in a apoprotein with decreased thermal stability. This loss in stability leads to aggregation and, therefore, to loss of hemolytic activity upon heating to a few degrees above the physiological temperature. Heat-induced aggregation of apoC9 can be prevented by salts that stabilize proteins according to the Hofmeister series of lyotropic ions, suggesting that the ion in native C9 may ligand with more than one structural element of domain of the protein. Ligand blotting indicates that the calcium binding site is located in the amino-terminal half of the protein. Removal of calcium by inclusion of EDTA in assay mixtures has no effect on the hemolytic activity of C9, and its capacity to bind to C8 in solution, or to small unilamellar lipid ...
Zn-Al alloy as a new anode-metal of a zinc-air battery
Energy Technology Data Exchange (ETDEWEB)
Low operating power and short cycle life are 2 of the main draw-backs of zinc-air batteries, despite the fact that various attempts have been made to develop improved zinc (Zn) anodes. This study investigated the performance of a Zn anode with a substantial addition of aluminium (Al). Rolled sheets of Zn-Al alloys of varying amounts of Zn and Al were used to prepare the anodes. Results of the study showed that the cells had higher open circuit voltages (OCV) values as well as a higher specific anode capacity. It was observed that specific anode capacity increased with higher current loading. The Zn{sub 59}Al{sub 41} and Zn{sub 67}Al{sub 33} sheets showed the highest performance with high OCV values of between 1540 and 1560 mV, as well as the largest specific anode capacity of 750-800 mAh per g at a discharge current of 200 mA. The 2-phase structure of the Zn-Al sheets was considered to be useful in ...
2006-01-15
Northeast U.S. LNG project expansions : are they competing or complementary projects?
Energy Technology Data Exchange (ETDEWEB)
The Northeast Gateway Energy Bridge Deepwater Port project was commissioned in 2005 and is based on a proprietary energy bridge shipboard regasification technology. The offshore liquefied natural gas (LNG) facility will be located in federal waters 13 miles southeast of Gloucester and was designed to cope with the extreme weather of the Massachusetts Bay. A dual-buoy system will be capable of ensuring continuous delivery of natural gas. Throughput capacity will range from 400 to over 800 MMcf/d. Vessels used at the port have capacities of 138,000 m{sup 3} and 150,900 m{sup 3} with peak sendout rates of 600 MMcf/d. The vessels have the capacity to rapidly increase and decrease their delivery rates. During periods of peak demand, 2 vessels can be simultaneously accommodated at the port, which has been designed to accommodate larger vessels to maximize future throughput. This presentation presented details of the ...
2006-07-01
Are There Enough Ionizing Photons to Reionize the Universe by z=6?
An estimate for the number of ionizing photons per baryon as a function of redshift is computed based on the plausible extrapolation of the observed galaxy UV luminosity function and the latest results on the properties of the escape fraction of ionizing radiation. It is found that, if the escape fraction for low mass galaxies (Mtot<10^{11}Msun) is assumed to be negligibly small, as indicated by numerical simulations, then there are not enough ionizing photons to reionize the universe by z=6 for the cosmology favored by the WMAP 3rd year results, while the WMAP 1st year cosmology is marginally consistent with the reionization requirement. The escape fraction as a function of galaxy mass would have to be constant to within a factor of two for the whole mass range of galaxies for reionization to be possible within the WMAP 3rd year cosmology.
2007-01-01
Energy Technology Data Exchange (ETDEWEB)
The molar heat capacities (C{sub p,m}) of crystalline potassium dichromate (K{sub 2}Cr{sub 2}O{sub 7} (cr)) and aqueous K{sub 2}Cr{sub 2}O{sub 7} solution (0.1699 mol.kg{sup -1}) were measured in the temperature range from 100 to 390 K and from 80 to 370 K by an automatic adiabatic calorimeter equipped with a small cell of internal volume of 6 cm{sup 3}, respectively. No phase transition took place in the temperature range from 100 to 390 K for K{sub 2}Cr{sub 2}O{sub 7} (cr). The relationships of C{sub p,m} of K{sub 2}Cr{sub 2}O{sub 7} (cr) with respect to T were established to be C{sub p,m} 177.53 + 161.92 X - 138.14 X{sup 2} - 209.67 X{sup 3} + 160.35 X{sup 4} + 137.44 X{sup 5} - 41.291 X{sup 6} and C{sub p,m} 177.52 + 171.66 X -149.59 X{sup 2} - 246.17 X{sup 3} + 194.79 X{sup 4} + 167.30 X{sup 5} - 64.368 X{sup 6} (X=(T-245.00)/145.00) for Series 1 and Series 2 experiments, respectively. No phase transition took place for the solution from 80 to 270 K. The ...
2003-07-01
Energy Technology Data Exchange (ETDEWEB)
Nickel-titanium alloys may coexist in more than one crystalline structure. There is a high temperature phase, austenite, and a low temperature phase, martensite. The metallurgical basis for the superelasticity and the shape memory effect relies in the ability of these alloys to transform easily from one phase to another. There are three essential factors for the orthodontist to understand nickel-titanium alloys behaviour: stress; deflection; and temperature. These three factors are related to each other by the stress-deflection, stress-temperature and deflection-temperature diagrams. This work was undertaken with the objective to analyse commercial nickel-titanium alloys for orthodontics application, using the dynamical mechanical analyser - DMA. Four NiTi 0,017 X 0,025'' archwires were studied. The archwires were Copper NiTi 35 deg C (Ormco), Neo Sentalloy F200 (GAC), Nitinol Superelastic (Unitek) and NiTi (GAC). The different mechanodynamical properties such as ...
2002-07-01
Ion temperature anisotropy in high power helium neutral beam fuelling experiments in JET
Energy Technology Data Exchange (ETDEWEB)
During helium beam fuelling experiments in JET, distinctive anisotropic features have been observed in the velocity distribution function describing both fast and thermal alpha particle populations. During the initial fuelling phase the central helium ion temperature observed perpendicular to the magnetic field is higher than the central electron temperature, while the central helium ion temperature observed parallel to the magnetic field is lower than or equal to the central electron temperature. In order to verify temperature measurements of both perpendicular and parallel lines of sight, other independent methods of deducing the ion temperature are investigated: deuterium ion temperature, deuterium density, comparison with neutron rates and profiles (influence of a possible metastable population of helium). 6 refs., 7 figs.
1994-07-01
Preservation of beech and spruce wood by allyl alcohol-based copolymers
International Nuclear Information System (INIS)
Allyl alcohol (AA), acrylonitrile (AN), methyl methacrylate (MMA), monomers and monomer mixtures AA+AN, AA+MMA were used to conserve and consolidate Beech and Spruce. After impregnation, copolymerisation and polymerisation were accomplished by gamma irradiation. The fine structure of wood+polymer(copolymer) composites was investigated by Scanning Electron Microscopy (SEM). It was observed that copolymer obtained from AA+MMA monomer mixture showed the optimum compatibility. The compressional strength and Brinell Hardness Numbers determined for untreated and treated wood samples indicated that the mechanical strength of wood+copolymer composites was increased. It was found that the mechanical strength of the wood samples containing the AA+MMA copolymer was higher than the others. In the presence of P(AA/MMA), at highest conversion, the compressive strength perpendicular to the fibres in Beech and Spruce increased approximately 100 times. The water uptake ...
1999-06-01
Based on studies on the genetic and molecular basis of Shigella flexneri invasive properties, we have constructed and evaluated a double mutant of S. flexneri serotype 5 for utilization as a live attenuated oral vaccine against shigellosis. The first mutation, icsA, blocks intracellular spread of bacteria as well as cell-to-cell infection. It affects the capacity of the invasive pathogen to form large abscesses in epithelia. The second mutation, iuc, eliminates production of the siderophore aerobactin thus impairing growth of the bacterium within tissues. This double mutant, SC5700 appeared safe when administered intragastrically to macaque monkeys as three doses (5 x 10(10) c.f.u. each) at weekly intervals. Protection against a challenge by the wild type isolate (M90T) was observed 4 weeks after the last vaccine inoculation. Duration of carriage was considerably reduced as compared to the control group in which all animals had developed severe ...
1989-10-01
Spinning tachyons as particle constituents
International Nuclear Information System (INIS)
The motions of a classical free spinning point particle are extended to include the range of superluminal velocities. There is no formal change in the constraint-dependent functional relationship between observable mass and spin, i.e., trajectory, accompanying this extension. However, the theory now permits the specification, for superluminal velocities, of a linearly rising trajectory and naturally yields tachyon confinement. Therefore, unlike their subluminal counterparts, these tachyons can be considered candidates for elementary particle constituents.
Radiation-annealing hardening of vanadium
International Nuclear Information System (INIS)
A study is made of the mechanical properties of vanadium irradiated with fast neutrons up to dose 8.6.10"-"4 dpa, as a function of the temperature of post-radiation annealing. The radiation-annealing hardening (RAH) effect is observed at 300"oC, in agreement with previous studies. It is established for the first time that RAH is accompanied by fall in ductility. A phenomenological model is described which explains the dependence of RAH on radiation dose and temperature, as well as on the content of chemically active alloying impurities. (author).
Petroleum waxes in solvent systems
Energy Technology Data Exchange (ETDEWEB)
Wax appearance temperature (WAT) of three petroleum waxes in different solvent systems under varying thermal conditions has been determined. It is observed that this temperature mainly is a function of the concentration of the wax and the solubility parameter ([delta]) of the solvent taken. This dependence of WAT has been quantified in terms of these variables in the form of mathematical equation and nomographs. (orig.)
1994-01-01
Measurement of the electrical resistivity of the lithium isotopes at low temperatures
Energy Technology Data Exchange (ETDEWEB)
The electrical resistivity at low temperatures (T = 10 to 90 K) of the lithium isotopes /sup 6/Li and /sup 7/Li and of an isotopic mixture /sup 7 +6/Li has been studied. The specimens contained a small amount of chemical impurities. An appreciable difference was observed in the temperature dependence of the resistivity produced both by deformation of the phonon spectrum, related to the change in isotopic composition, and by the presence of chemical impurities making the nonequilibrium part of the electron distribution function more isotropic.
1982-03-01
Infrared stimulated luminescence-decay shape from NaCl as a function of radiation doses
Energy Technology Data Exchange (ETDEWEB)
Dose-dependent behavior of the infrared stimulated luminescence (IRSL) decay from NaCl has been studied experimentally using only one aliquot irradiated with a range of 2-200 Gy {beta}-radiation doses. It was observed that the maximum IRSL intensity has not changed by an increase in dose though the total intensity increased as expected. Considering the possible implications of our findings for dosimeter, the results were compared with the other studies and discussed.
2007-11-15
Effect of ultrasonic energy on Mn-Zn ferrite powder behavior
Energy Technology Data Exchange (ETDEWEB)
Effect of ultrasonic-wave irradiation on the Mn-Zn ferrite powder suspension prepared by solid-state reaction and alcoholic dehydration methods was investigated. Size, distribution, and morphology of the powders prepared at different temperatures were examined, as a function of irradiation time. It was observed that the powders were reduced in size by ultrasonic energy through distinct routes. 8 refs., 7 figs., 1 tab.
1999-07-01
Calculation of Compton profiles of tantalum and tungsten
International Nuclear Information System (INIS)
Calculations of the Compton profiles for the transition metals Ta and W are performed, using electron wave functions obtained from self-consistent augmented plane wave (APW) band structure calculations within the local density formalism of Hedin-Lundqvist. Relativistic effects are included except for the spin-orbit interaction. The observed structures of the Compton profiles in these metals are understood in terms of the topology of their Fermi surfaces. (author).
Energy Technology Data Exchange (ETDEWEB)
The apex dimensions and length are calculated as a function of current for the ion-emitting jet in liquid-metal ion sources (LMIS). The results agree well with observations. Since the final expressions are analytical, they give more insight into the fundamental mechanisms involved than do numerical calculations. Some implications of the model are discussed concerning focused ion beam (FIB) systems employing LMIS. (author).
1991-12-14
Energy Technology Data Exchange (ETDEWEB)
This study reports on the physical-chemical behaviour of swelling di-octahedral clays (smectites) and their interaction with aqueous solutions and bacteria (Shewanella putrefaciens). Experimental results are presented for compacted clays, hydrated under confined volume conditions, using a new type of reaction-cell (the 'wet-cell' of Warr and Hoffman, 2004) that was designed for in situ X-ray diffraction (XRD) measurement. For comparison, dispersed clay systems were studied using standard batch solutions subjected to varying degrees of agitation. The combination of time-dependent in situ XRD measurements with gravimetric measurements and calculated diffraction patterns using the CALCMIX software (Plancon and Drits, 1999) allowed to successful quantification of the dynamics of water uptake and storage. This analytical procedure combined with published water vapour adsorption data enabled determination of the abundance of structured water layers, developed in the ...
2008-01-15
International Nuclear Information System (INIS)
Full text: A novel protocol based on electrospray ionization (ESI) multiple stage high capacity ion trap (HCT) mass spectrometry (MS) was developed for glycosphingolipidomic surveys. The method was optimized for detailed structural elucidation of human brain gangliosides and particularly applied to human hippocampus-associated structures. The multiple stage MS experiments allowed for a complete structural characterization of GM1 ganglioside species, which was achieved by elucidation of the oligosaccharide sequence, identification of the GM1 a structural isomer from the data upon sialic acid localization along the sugar backbone and determination of the d18:1/18:0 of fatty acid/sphingoid base composition of the ceramide moiety. The methodology developed here is of general practical applicability for glycolipids and represents a step forward in the implementation of the advanced and most modern MS methods in glycomics. Gangliosides are glycosphingolipids, which ...
2006-10-25
Energy Technology Data Exchange (ETDEWEB)
The electrochemical intercalation of non-solvated lithium in different graphited materials has been performed in LiClO{sub 4}-ethylene carbonate (EC) medium. The irreversible capacity observed during the first output is mainly due to the formation of a passivation layer made of electrolyte reduction products. These products have been characterized for different electrode reduction potentials using transmission electron microscopy (image, diffraction) and electron energy loss spectroscopy (EELS). EC reduction on the electrode surface in presence of LiClO{sub 4} leads to the formation of Li{sub 2}CO{sub 3} for potentials close to 0.8 V vs Li{sup +}/Li. For lower potentials, the electrolyte reduction reaction goes on with the formation of different lithium alkyl-carbonates. In LiClO{sub 4}-propylene carbonate (PC) medium, the interface phenomena are different. The reduction of a graphite electrode is characterized by the exfoliation phenomenon ...
1996-12-31
Energy Technology Data Exchange (ETDEWEB)
The authors hypothesized that acute respiratory responsiveness to ozone predicts chronic lung injury from repeated exposure to ozone-containing air pollution. They tested this hypothesis in 164 middle-aged nonsmoking residents of an ozone-polluted community who underwent lung-function measurements during 1986 and 1987 (i.e., time 3). The time-3 study was a follow up of more comprehensive studies conducted in 1977--1978 (time 1) and in 1982--1983 (time 2). In contrast to the apparent rapid (i.e., {approx} 60 ml/y) decline in lung-function measurements between times 1 and 2, their subjects showed little change in forced vital capacity (FVC) or forced expired volume in 1 s (FEV{sub 1.0}) between times 2 and 3, and they experienced a normal decline between times 1 and 3. A subgroup (n = 45) underwent 2-h laboratory ozone exposures to 0.4 ppm ozone, accompanied by intermittent exercise, and they experienced mild acute reductions ...
1998-09-01
Energy Technology Data Exchange (ETDEWEB)
We describe the synthesis and characterization of superparamagnetic iron oxide nanoparticle based heavy metal sorbents with various surface chemistries that demonstrate an excellent affinity for the separation of heavy metals in contaminated water systems (i.e. spiked Columbia river water). The magnetic nanoparticle sorbents are prepared from an easy to synthesize iron oxide precursor, followed by a simple, one-step ligand exchange technique to introduce the organic surface functionality of interest chosen to target either specific or broader classes of heavy metals. Functionalized superparamagnetic nanoparticles are excellent sorbent materials for the extraction of heavy metal contaminants from environmental and clinical samples since they are easily removed from the media once bound to the contaminant by simply applying a magnetic field. These engineered magnetic nanoparticle sorbents have an inherently high active surface area (often > ...
2010-06-01
Mesoporous Silicon-Based Anodes for High Capacity, High - NASA
Aug 6, 2010 ... A new high capacity anode composite based on mesoporous silicon is proposed. By virtue of a structure that resembles a pseudo ...
Industrial-process control valves Part2 : Flow capacity Section Four : Inherent flow characteristics and rangeability
1989-01-01
Activation of stem cells in hepatic diseases
UK PubMed Central (United Kingdom)
The liver has enormous regenerative capacity. Following acute liver injury, hepatocyte division regenerates the parenchyma but, if this capacity is overwhelmed during massive or chronic liver...Full Text Available
2008-01-01
In longitudinal and spatial studies, observations often demonstrate strong correlations that are stationary in time or distance lags, and the times or locations of these data being sampled may not be homogeneous. We propose a nonparametric estimator of the correlation function in such data, using kernel methods. We develop a pointwise asymptotic normal distribution for the proposed estimator, when the number of subjects is fixed and the number of vectors or functions within each subject goes to infinity. Based on the asymptotic theory, we propose a weighted block bootstrapping method for making inferences about the correlation function, where the weights account for the inhomogeneity of the distribution of the times or locations. The method is applied to a data set from a colon carcinogenesis study, in which colonic crypts were sampled from a piece of colon segment from each of the 12 rats in the ...
2007-01-01
Fiscal year 1996 U.S. Department of Energy, Richland Operations Office Site summary baseline
International Nuclear Information System (INIS)
The technical baseline is a hierarchical description of the Hanford Site cleanup mission. This technical baseline does not address the science, technology, or economic transition missions. It begins with a definition of the existing conditions at the Hanford Site, provides a description of the end product or mission accomplishments at completion, presents a statement of the major requirements and constraints that must be observed during the performance of the mission, and provides a statement of the top-level strategic approach to accomplish the mission. Mission-level interfaces are also described. This information is further defined hierarchically in increasing levels of detail. This definition is composed of the following major elements: functions that are key task descriptions; requirements that are the measurable standards to which the functions must be performed; architectures which are specific engineering solutions ...
2009-06-01
Cosmic evolution of the atomic and molecular gas content of galaxies
We study the evolution of the cold gas content of galaxies by splitting the interstellar medium into its atomic and molecular hydrogen components, using the galaxy formation model GALFORM in the LCDM framework. We calculate the molecular-to-atomic hydrogen mass ratio, H2/HI, in each galaxy using two different approaches; the pressure-based empirical relation of Blitz & Rosolowsky and the theoretical model of Krumholz, McKeee & Tumlinson, and apply them to consistently calculate the star formation rates of galaxies. We find that the model based on the Blitz & Rosolowsky law predicts an HI mass function, CO(1-0) luminosity function, correlations between the H2/HI ratio and stellar and cold gas mass, and infrared-CO luminosity relation in good agreement with local and high redshift observations. The HI mass function evolves weakly with redshift, with the number density of high mass galaxies ...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
A flow microcalorimeter of the Picker design has been used to measure molar excess enthalpies at 298.15 K of the seven binary liquid mixtures 1-chloronaphthalene + n-hexane, + n-heptane, + n-octane, + n-decane, + n-dodecane, + n-pentadecane, and + n-hexadecane. Experiments were performed in the discontinuous mode, covering essentially the whole composition range. The overall imprecision of the measurements is characterized by standard deviations from Redlich-Kister type smoothing equations of generally less than +- 1 per cent of the maximum value Hsub(max)sup(E) of the excess enthalpy (with respect to mole fraction). The most striking feature is that for 6 <= n <= 16 (n denotes the number of C-atoms of the n-alkane) Hsub(max)sup(E) decreases with increasing n, the correlation being approximately linear. - For the mixtures 1-chloronaphthalene + n-hexane, + n-heptane, + n-octane, + n-dodecane, + n-pentadecane, and + n-hexadecane molar excess volumes Vsup(E) at 298.15 K were ...
1981-09-01
International Nuclear Information System (INIS)
The experimental has been performed with a view to studying complete and incomplete fusion in "1"4N + "1"6"3D_y system below 7 MeV/nucleon. The excitation functions for several reactions have been measured using the activation technique and compared with the theoretical predictions based on statistical models. The codes ALICE-91 and CASCADE used earlier for the analysis of excitation functions in case of "1"2C + "1"6"5H_0 system have been used here also with the same set of input parameters. It has been observed that the theoretical calculations do not match with the experimental excitation functions well but the overall shape of the excitation function is reproduced satisfactorily. The composite nucleus ("1"7"7T_a) formed in this ("1"4N + "1"6"3D_y) case is the same as the one formed in "1"2C + "1"6"5H_0 system studied earlier. Measured excitation functions for ...
2002-10-01
Energy Technology Data Exchange (ETDEWEB)
Apparent molar heat capacities for KI[sub 3](aq) were determined from flow-microcalorimetric measurements of KI(aq) solutions containing dissolved iodine. From these, the conventional partial molar heat capacity C[sub p,2][sup [infinity
1993-05-01
Combustion of Crop Production Wastes
International Science & Technology Center (ISTC)
Development, Investigation and Improvement of a System of Incinerating Crop Production Wastes in Small Capacity Boilers
High resolution scanning electron microscopy of plasmodesmata.
Symplastic transport occurs between neighbouring plant cells through functionally and structurally dynamic channels called plasmodesmata (PD). Relatively little is known about the composition of PD or the mechanisms that facilitate molecular transport into neighbouring cells. While transmission electron microscopy (TEM) provides 2-dimensional information about the structural components of PD, 3-dimensional information is difficult to extract from ultrathin sections. This study has exploited high-resolution scanning electron microscopy (HRSEM) to reveal the 3-dimensional morphology of PD in the cell walls of algae, ferns and higher plants. Varied patterns of PD were observed in the walls, ranging from uniformly distributed individual PD to discrete clusters. Occasionally the thick walls of the giant alga Chara were fractured, revealing the surface morphology of PD within. External structures such as spokes, spirals and mesh were ...
2011-05-28
Cavitation during hot-torsion testing of Ti-6Al-4V
Hot-torsion testing was used to establish the cavitation behavior of a typical alpha/beta titanium alloy, Ti-6Al-4V, with a colony microstructure, during simple-shear deformation. For this purpose, sections of deformed specimens were examined by optical metallography, and by scanning and orientation-imaging microscopy (OIM). It was found that cavity nucleation occurred along prior beta boundaries as well as at triple points; in particular, most cavities nucleated along boundaries perpendicular to the axial direction of the specimen. Extensive growth was observed for cavities surrounded by both hard and soft orientations, with the soft colonies accommodating more of the imposed strain. At high degrees of deformation, dynamic globularization of the colony microstructure adjacent to the cavities was also observed. In addition, the metallographic observations revealed that the cavities did not grow in an equiaxed mode, but in ...
2005-12-01
International Nuclear Information System (INIS)
Our purpose in this work was to develop an automatic boundary detection method for mammographic masses and to rigorously test this method via statistical analysis. The segmentation method utilized a steepest change analysis technique for determining the mass boundaries based on a composed probability density cost function. Previous investigators have shown that this function can be utilized to determine the border of the mass body. We have further analyzed this method and have discovered that the steepest changes in this function can produce mass delineations that include extended projections. The method was tested on 124 digitized mammograms selected from the University of South Florida's Digital Database for Screening Mammography (DDSM). The segmentation results were validated using overlap, accuracy, sensitivity, and specificity statistics, where the gold standards were manual traces provided by two expert radiologists. ...
2004-10-01
The thorny path linking cellular senescence to organismalaging
Energy Technology Data Exchange (ETDEWEB)
Half a century is fast approaching since Hayflick and colleagues formally described the limited ability of normal human cells to proliferate in culture (Hayflick and Moorhead, 1961). This finding--that normal somatic cells, in contrast to cancer cells, cannot divide indefinitely--challenged the prevailing idea that cells from mortal multicellular organisms were intrinsically ''immortal'' (Carrell, 1912). It also spawned two hypotheses, essential elements of which persist today. The first held that the restricted proliferation of normal cells, now termed cellular senescence, suppresses cancer (Hayflick, 1965; Sager, 1991; Campisi, 2001). The second hypothesis, as explained in the article by Lorenzini et al., suggested that the limited proliferation of cells in culture recapitulated aspects of organismal aging (Hayflick, 1965; Martin, 1993). How well have these hypotheses weathered the ensuing decades? Before answering this question, we first consider ...
2005-08-09
Removal of basic dye by modified Unye bentonite, Turkey
Energy Technology Data Exchange (ETDEWEB)
The adsorption behavior of crystal violet (CV{sup +}) from aqueous solution onto raw (RB) and manganese oxide-modified (MMB) bentonite samples was investigated as a function of parameters such as initial CV{sup +} concentration, contact time and temperature. The Langmuir, Freundlich and Dubinin-Radushkevich (D-R) adsorption models were applied to describe the equilibrium isotherms. The Langmuir monolayer adsorption capacities of RB and MMB were estimated as 0.32 and 1.12 mmol/g, respectively. The mean adsorption energy derived from D-R isotherm for MMB showed that the type of adsorption of dye molecules on this material may be defined as chemical adsorption. The adsorption rate was fast and more than half of the adsorbed-CV{sup +} was removed in the first 55 min for RB and 5 min for MMB at the room temperature. The pseudo-first-order, pseudo-second-order kinetic and the intraparticle diffusion models were used to describe the kinetic data and ...
2009-03-15
Energy Technology Data Exchange (ETDEWEB)
Analyses of process system properties were continued for important chemical materials involved in the several processes under consideration for semiconductor and solar cell grade silicon production. Major activities were devoted to physical, thermodynamic and transport property data for silicon. Property data are reported for vapor pressure heat of vaporization, heat of sublimation, liquid heat capacity and solid heat capacity as a function of temperature to permit rapid usage in engineering. Chemical engineering analysis of the HSC process (Hemlock Semiconductor Corporation) for production of silicon was initiated. The process is based on hydrogen reduction of dichlorosilane (DCS) to produce the polysilicon. The chemical vapor deposition reaction for DCS is faster in rate than the conventional process route which utilizes trichlorosilane (TCS) as the silicon raw material. Status and progress are reported for primary ...
1980-03-01
DEFF Research Database (Denmark)
The coupling between cerebral metabolic rate of oxygen (CMRO2) and blood flow (CBF) in response to visual stimulation was evaluated by means of a model of oxygen delivery. The model predicted a nonlinear relationship between stimulus-evoked changes of oxygen consumption and blood flow. The magnitude of the CMRO2/CBF ratio index (IO2) was used to indicate the degree of flow-metabolism coupling prevailing in specific areas of the brain during physiological stimulation. Therefore, the index provided a measure of the blood oxygenation level dependent (BOLD) magnetic resonance contrast. To evaluate the changes of IO2 in response to visual stimulation, the model was applied to the effect of a changing flicker rate of a visual stimulus on the magnitudes of CBF, CMRO2, and oxygen diffusion capacity, in the human brain. Positron emission tomography (PET) was used to measure the CBF and the CMRO2 in 12 healthy volunteers who viewed a cross-hair (baseline) or a yellow-blue ...
2000-01-01
Energy Technology Data Exchange (ETDEWEB)
Puffer gas circuit breaker used widely in interrupters with from middle capacity to large capacity does not keep away from reacting force of the puffer with high functions in principle and there is a limit in low operation. In this study, aiming at low operation of the interrupters, in order to clarify the basic motions of hybrid circuit interrupter that is the combination of thermal puffer gas circuit breaker and vacuum circuit breaker, the interrupting ability of simple thermal puffer gas breaker and the voltage sharing characteristics in the cases of series connection with the vacuum circuit breaker are studied. The results of the study are as follows. In comparing terminal short circuit accident interrupting ability of single flow typed thermal puffer gas breaker with that of double flow typed thermal puffer gas breaker, the interrupting ability of the double flow typed thermal puffer gas breaker may be improved. It is ...
1993-12-20
Energy Technology Data Exchange (ETDEWEB)
In 1986, following comprehensive preliminary studies, a 17 MW battery energy storage plant was set up in the insular power supply system of Berlin (West) for the purpose of frequency and output control and provision of immediate reserve capacities. The present paper reports on the initial task, and the dimensioning and construction of this large-scale demonstration as well as the costs entailed in this. It also relates the experiences gained with the operation of the battery energy storage plant in its function as a fast-responding control unit and gives an account of its economic efficiency. Recent studies on the economic efficiency of the plant in conditions as they exist in the present interconnected power supply system are presented. Finally the author reports on the experiences gained with individual plant components, i.e., battery, battery periphery, and power converter and quantifies the cost of plant operation, maintenance, and ...
1996-12-31
Energy Technology Data Exchange (ETDEWEB)
This paper proposes a novel and efficient algorithm to obtain optimal generation dispatch reflecting the operator's intention in power system rescheduling. In optimal system operation, various objectives, such as economy, quality and transmission security, need to be achieved simultaneously. However, these objectives are often contradictory and in a trade-off relationship with respect to each other thus making it difficult to handle this class of problem by conventional approaches. In the proposed algorithm, optimal generation dispatch is formulated as a multi-objective optimization problem. A fuzzy coordination technique based on fuzzy set theory is used to obtain an optimal solution. Evaluation indices composed of fuel cost, transmission line overload and AFC regulation capacity margin are measured by the membership functions, and multi-objective optimization is solved by maximizing the composite performance index, namely, the fuzzy ...
1992-10-01
British Library Electronic Table of Contents (United Kingdom)
Abstract We address the fundamental question of matching the rest-frame K-band luminosity function (LF) of galaxies over the Hubble time using semi-analytic models after modification of the stellar population modelling. We include the Maraston evolutionary synthesis models, which feature a higher contribution by the thermally pulsating asymptotic giant branch (TP-AGB) stellar phase, into three different semi-analytic models, namely the De Lucia and Blaizot version of the Munich model, morgana and the Menci model. We leave all other input physics and parameters unchanged. We find that the modification of the stellar population emission can solve the mismatch between models and the observed rest-frame K-band luminosity from the brightest galaxies derived from UKIRT Infrared Deep Sky Survey d...
2011-01-01
Split anterior tibial tendon transfer for varus equinus spastic foot deformity
British Library Electronic Table of Contents (United Kingdom)
Spastic equinovarus foot deformity commonly occurs after stroke or head trauma. Management by split anterior tibial tendon transfer to the lateral border of the foot was chosen by the authors. The purpose of that work was to assess the reliability of this method to improve patient's functional autonomy and investigate the relationship between the initial clinical examination findings and the quality of the functional results. 84 feet, operated in 82 patients out of 130, of mean age 46 years, were reviewed at a mean follow-up of 65 months. Very few complications were observed. Toe deformities remain a commonly associated problem. 80 patients were able to walk barefoot, 74 reported an increase in their walking distance, and 73 could regularly wear normal shoes. There is a strong relationship...
2011-01-01
Phonon spectra of A-15 compounds and ternary molybdenum chalcogenides
International Nuclear Information System (INIS)
A survey is given on studies of the phonon spectra of several A-15 compounds by inelastic neutron scattering on polycrystalline samples. Comparison of the results for V_3Si, V_3Ge, N_3Ga, Nb_3Sn and Nb_3Al at 297 K lead to the conclusion that the interatomic forces are to a good approximation the same for all compounds with 4.75 valence electrons but are reduced by about 20% for those with 4.5 valence electrons. For all compounds investigated a softening of the phonon frequencies on cooling is observed which is most pronounced for those materials with the highest T/sub c/ values. From a comparison of the results with the experimentally determined Eliashberg function of Nb_3Sn information is derived about the energy dependence of the electron-phonon coupling function #alpha#"2.
P03-378 - Erectile dysfunction in psychiatric patients
British Library Electronic Table of Contents (United Kingdom)
Introduction: Erectile dysfunction (ED) is defined as the inability to achieve or maintain an erection sufficient for sexual activity. Objectives: ED is a common condition in psychiatric patients, which can modify their quality of life. Aims: The aim of this study is to assess the prevalence and the severity of ED in psychiatric patients. Methods: This naturalistic, observational study was conducted during a six months period. The International Index of Erectile Function (IIEF) 15-item questionnaire was used to assess 144 male inpatients with different psychiatric disorders. IIEF is a brief, cross-culturally valid, self-administered scale for detecting treatment-related changes in patients with erectile dysfunction and addresses the relevant domains of male sexual function: erectile functi...
2011-01-01
Experimental measurements were made of the production cross sections and energy distributions of gamma rays emitted when the stable targets /sup 88/Sr, /sup 89/Y and /sup 90/Zr are exposed to protons in the energy range 3 to 8 MeV. The data are being analyzed using a recent version of the Uhl statistical model code. One conclusion is that while the gamma-ray strength functions employed reproduce the proton capture cross sections, they do not achieve the same degree of hardness observed in the measured spectra. To do so, their lower energy regions must be modified; such changes, however, do not affect the capture cross sections. 7 references.
1978-09-01
Matrix models as CFT: Genus expansion
International Nuclear Information System (INIS)
We show how the formulation of the matrix models as conformal field theories on a Riemann surfaces can be used to compute the genus expansion of the observables. Here we consider the simplest example of the Hermitian matrix model, where the classical solution is described by a hyperelliptic Riemann surface. To each branch point of the Riemann surface we associate an operator which represents a twist field dressed by the modes of the twisted boson. The partition function of the matrix model is computed as a correlation function of such dressed twist fields. The perturbative construction of the dressing operators yields a set of Feynman rules for the genus expansion, which involve vertices, propagators and tadpoles. The vertices are universal, the propagators and the tadpoles depend on the Riemann surface. As a demonstration we evaluate the genus-two free energy using the Feynman rules.
2010-10-01
British Library Electronic Table of Contents (United Kingdom)
Shallow-water zooplanktivorous fish rely on their vision for foraging. In shallow water, feeding efficiency decreases in dim light and thus the fish cease foraging at crepuscular hours. Creatures living in the lower parts of their depth ranges are expected to be exposed to limited light levels for longer hours. However, observations of the zooplanktivore Dascyllus marginatus showed little change in foraging duration down to 40m deep. We asked whether the visual system's functionality changes with depth along the depth range of this damselfish; we examined eye and retina anatomy for changes in visual acuity and light sensitivity and used the optomotor response to test for spatial and temporal light summation. We found only minor changes in the anatomy of the eye that are not expected to aff...
2010-01-01
Bonding and microstructural stability in Ni55Ti45 studied by experimental and theoretical methods
Energy Technology Data Exchange (ETDEWEB)
Spiral orbit tribometry friction tests performed on Ni-rich Ni55Ti45 titanium ball bearings indicate that this alloy is a promising candidate for future aerospace bearing applications. Microstructural characterization of the bearing specimens was performed using transmission electron microscopy and energy dispersive spectroscopy, with NiTi, Ni4Ti3, Ni3Ti, and Ni2Ti4Ox phases identified within the microstructure of the alloy. Density functional theory was applied to predict the electronic structure of the NixTiy phases, including the band structure and site projected density of states. Ultraviolet photoemission spectroscopy was used to verify the density of states results from the density functional theory calculations, with good agreement observed between experiment and theory.
2010-11-25
An animal model of social instability stress in adolescence and risk for drugs of abuse
British Library Electronic Table of Contents (United Kingdom)
There is increasing evidence that adolescence, like early life, is a sensitive period in which ongoing brain development can be influenced by environmental factors. This review describes our use of social instability as a model of mild adolescent social stress, its effects on social interactions and on hypothalamic?pituitary?adrenal function over the course of the procedure and in response to new stressors. The effects of social instability are sex-specific, with qualitative differences between the sexes on HPA function over the course of the stressor procedure, and with greater effects in males on behaviour observed during the social instability and greater effects in females on behavioural responses to drugs of abuse into adulthood, long after the stress exposure. The results from invest...
2010-01-01
Adsorption and Dissociation of Molecular Hydrogen on the (0001) Surface of DHCP Americium
Hydrogen molecule adsorption on the (0001) surface of double hexagonal closed packed americium has been studied in detail within the framework of density functional theory. Weak molecular hydrogen adsorptions were observed. The most stable configuration corresponded to a Hor2 approach molecular adsorption at the one-fold top site where the molecule's approach is perpendicular to a lattice vector. Adsorption energies and adsorption geometries for different adsorption sites will be discussed. The change in work functions, magnetic moments, partial charges inside muffin-tins, difference charge density distributions and density of states for the bare Am slab and the Am slab after adsorption of the hydrogen molecule will be discussed. Reaction barrier for the dissociation of hydrogen molecule will be presented. The implications of adsorption on Am 5f electron localization-delocalization will be summarized.
2009-03-01
The effect of ductile connectors on the behaviour of timber-concrete composite beams
British Library Electronic Table of Contents (United Kingdom)
The load-carrying capacity and ultimate deformation capacity of timber-concrete composite systems can be significantly influenced by the ductility of the connection between the two materials. The use of more ductile connections can increase the load-carrying capacity of the composite system as well as its ultimate deformation capacity. In this work, the potential increase that might be expected for these two parameters due to the use of ductile connections will be assessed through numerical simulations, taking the non-linear behaviour of the connections into account. Furthermore, the connection ductility required to achieve the maximum load capacity depends on the mechanical properties of the connection as well as on the geometric and mechanical properties of the composite system. There ar...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
The control of piece size in ruptured rocks in coal sections is important as part of the general problem of increasing efficiency in the technology of open-pit mining operations. An attempt is made in this paper to estimate the rupture capacity of exposed rocks in coal sections based on a set of physicomechanical property indicators, using the methods of multidimensional statistical analysis. It was established that all the parameters for the physiocomechanical properties of the exposed rocks are highly correlated. The method proposed for determining criteria for explosive capacity is of interest in developing criteria for the destruction capacity (drillability, excavation capacity, etc.) in the exposed rocks of coal sections which are characterized by high variation in physical and mechanical properties.
1988-03-01
Energy Technology Data Exchange (ETDEWEB)
Thermal and mechanical properties for geothermal formations are tabulated for a range of temperatures and stress conditions. Data was obtained from the technical literature and direct contacts with industry. Thermal properties include heat capacity, conductivity, and diffusivity. Undisturbed geothermal profiles are also presented. Mechanical properties include Youngs modulus and Poisson ratio. GEOTEMP thermal simulations of drilling, production and injection are reported for two geothermal regions, the hot dry rock area near Los Alamos and the East Mesa field in the Imperial Valley. Actual drilling, production, and injection histories are simulated. Results are documented in the form of printed GEOTEMP output and plots of temperatures versus depth, radius, and time. Discussion and interpretation of the results are presented for drilling and well completion design to determine: wellbore temperatures during drilling as a function of depth; bit ...
1981-07-01
Energy Technology Data Exchange (ETDEWEB)
The simultaneous biosorption of Cr(VI) and Cu(II) on free Rhizopus arrhizus in a packed column operated in the continuous mode was investigated and compared to the single metal ion situation. The breakthrough curves were measured as a function of feed flow rate, feed pH, and different combinations of metal ion concentrations in the feed solutions. Column competitive biosorption data were evaluated in terms of the maximum (equilibrium) capacity in the column, the amount of metal loading on the R. arrhizus surface, the adsorption yield, and the total adsorption yield. In the single-ion situation the adsorption isotherms were developed for optimum conditions, and it was seen that the adsorption equilibrium data fit the noncompetitive Freundlich model. For the multicomponent adsorption equilibrium the competitive adsorption isotherms were also developed. The competitive Freundlich model for binary metal mixtures represented most the column ...
1999-12-01
Simulation for transient stability study of the Taiwan power system - a nuclear majority system
Energy Technology Data Exchange (ETDEWEB)
A transient stability program was developed for the Taiwan Power Company, which has a high proportion of nuclear generation in its power system. This program offers a new territory to investigate nuclear plant effects on the power system transient stability. This program also provides a high speed tool for the Taipower system operational planning. A generalized procedure of synchronous machine modeling for a large-scale stability study is presented. The merits and weaknesses of machine modeling can be comprehended through each item of this procedure. Three types of nonlinear synchronous machine modeling implemented into this stability program are derived by following this procedure. A robust subroutine was derived to perform the fourth order Runge-Kutta integration method, making the software programming neat and systematical. For simulating the nuclear plant influence on the system, this program implemented an additional four functions: load-limit operation ...
1984-01-01
Simulation for transient stability study of the Taiwan power system - a nuclear majority system
International Nuclear Information System (INIS)
A transient stability program was developed for the Taiwan Power Company, which has a high proportion of nuclear generation in its power system. This program offers a new territory to investigate nuclear plant effects on the power system transient stability. This program also provides a high speed tool for the Taipower system operational planning. A generalized procedure of synchronous machine modeling for a large-scale stability study is presented. The merits and weaknesses of machine modeling can be comprehended through each item of this procedure. Three types of nonlinear synchronous machine modeling implemented into this stability program are derived by following this procedure. A robust subroutine was derived to perform the fourth order Runge-Kutta integration method, making the software programming neat and systematical. For simulating the nuclear plant influence on the system, this program implemented an additional four functions: load-limit operation ...
Scaling Laws and Design Principles for Multi-Cellular Wireless OFDMA Systems
In this paper, we consider the downlink of large-scale multi-cellular OFDMA-based networks and study performance bounds of the system as a function of the number of users $K$, the number of base-stations $B$, and the number of resource-blocks $N$. Here, a resource block is a collection of subcarriers such that all such collections, that are disjoint have associated independently fading channels. We derive novel upper and lower bounds on the sum-utility for a general spatial geometry of base stations, a truncated path loss model, and a variety of fading models (Rayleigh, Nakagami-$m$, Weibull, and LogNormal). We also establish the associated scaling laws and show that, in the special case of fixed number of resource blocks, a grid-based network of base stations, and Rayleigh-fading channels, the sum information capacity of the system scales as $\\Theta(B \\log\\log K/B)$ for extended networks, and as $O(B \\log\\log K)$ and $\\Omega(\\log \\log ...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
The hydro-generators suffer during its operative useful life a combination of stresses of nature thermal, electric, mechanics and environmental. With the time, they are going losing the capacity to support those stresses and the power plants suffer, more and more frequently, undesirable stops for repair services and maintenance. In function of the high costs incurred with these stopped, the operation of the power plant can be economically impracticable. That unavailability of the generation for the electric system, it results in reduction of the reliability, burdening the politics of load ruling. The re-potentiation is a proposal that seeks to extend the useful life of hydro-generators, at the same time that it try to rescue the reliability and the readiness of the plant, with larger power. The power increase is usually made possible, or for the surplus of the hydro resources in excess, or for the reduction of the losses of all the components ...
1996-07-01
Probabilistic power generation planning with environmental consideration for Lebanon
International Nuclear Information System (INIS)
Full text.This paper describes a software tool for generation expansion planning based on dynamic programming, probabilistic production simulation, and environmental assessment. The aim is to determine the units needed to expand a given system in order to minimize either the cost or the environmental impact or some weighed function of the two. The problem of generation expansion planning is solved in stages using Tunnel Dynamic Programming (TDP) with Heuristic rules to limit the number of options analyzed. The production costing methodology is based on combining a probabilistic generation model known as the capacity outage table (COT) with the load duration curve (LDC) of the system to deduce a risk model from which the expected energy not supplied (EENS) is estimated. The generation model is built recursively using an efficient numerical convolution procedure and is combined at each step with the LDC to calculate the expected energy produced ...
2000-11-23
Preparation of activated carbon assembly by using glass fabrics and its SO{sub 2} adsorption
Energy Technology Data Exchange (ETDEWEB)
Inexpensive activated carbon assembly(ACA) was prepared with glass fabrics coated by 10 wt%, 25 wt%, 50 wt% phenolic resin solution, followed by activation at 700{sup o} C under N{sub 2} atmosphere and subsequent surface modification with N{sub 2}, NH{sub 3}, CO{sub 2} gas, respectively. The conversion chemistry of resin to carbon was analyzed by using FT-IR, TGA, SEM, XPS, and the SO{sub 2} adsorption characteristics of the ACA were compared to that of commercial activated carbon fabrics(ACF). The ACA modified by NH{sub 3} showed the best SO{sub 2} adsorption behavior due to the presence of basic functional groups such as amine on the surface, confirmed by XPS. The ACA modified by NH{sub 3} displayed relatively high adsorption capacity of 116.5 mg/g carbon, which is corresponding to 75% adsorption of the commercial ACF(153.4 mg/g) treated with the same method. 14 refs., 6 figs., 2 tabs.
1999-07-01
International Nuclear Information System (INIS)
Sulfonated poly(ether ether ketone) (SPEEK) membranes with various degrees of sulfonation (DS) have been prepared as a potential membrane material for proton exchange membrane by sulfonation process using mixtures of (15-30% concentration) fuming sulfuric acid and (95-98%) concentrated sulfuric acid as the sulfonating agent. The sulfonation process was conducted at room temperature by varying the acid ratio and reaction time. The produced membranes were then characterized by evaluating the ion exchange capacity (IEC), water uptake, thermal stability, proton conductivity and methanol permeability as a function of degree of sulfonation. The proton conductivity of the sulfonated PEEK membranes with various DS was within the magnitude of 10"-"3 and 10"-"2 S cm"-"1 at room temperature and the methanol permeability was in the range of 3.45 x 10"-"7 to 2.73 x 10"-"6 cm"2 s"-"1. The overall membrane performance of the SPEEK membrane with 80% DS was six ...
2007-07-15
Experimental parametric equation for the prediction of valve coefficient (C_v) for choke valve trims
International Nuclear Information System (INIS)
The calculation of nominal choke valve size determines the effective capacity for an oil and gas production system. The degree of restriction for the controlling area in the valve is a function of the surrounding geometry. In an orifice plate this is known as the 'velocity of approach' and can be used to determine the meter coefficient (C_m). This paper presents a technique for choke valves, based on the meter velocity of approach parameter, which can be used to predict the Valve Coefficient (C_v) for new trim designs. The prediction method uses a data trend based on a number of flow tests conducted on various trim characteristics. The resultant parametric equation is used to predict the C_v of a new trim geometry. The method relies on experimental data determined per IEC 60534-2-3, with calculations per IEC 60534-2-1. This paper further investigates the effect of varying upstream geometry on C_v for a 4'' nominal valve.
Effect of natural rubber processing sludge on the degradation of crude oil hydrocarbons in soil
Energy Technology Data Exchange (ETDEWEB)
Crude oil-polluted soil (five parts of weathered crude oil per 100 parts of soil; equivalent to 50,000 mg oil kg{sup -}1 soil) samples were slurried in deionised water (300% of the water retention capacity of the soil) and treated with various amounts of natural-rubber processing sludge (nitrogen content 62.15 mgkg{sup -1} and phosphorus contents 8.75 mgkg{sup -1}) in a well-stirred, continuously-aerated tank at 29{sup o}C. Changes in the total hydrocarbon content of the soil sample were determined, using a spectrophotometric technique, as a function of time. The extent of crude oil degradation was markedly higher (by up to 100%) in the sludge-treated soil than in the untreated soil sample. The efficiency of biodegradation of the crude oil hydrocarbons using the slurry-phase technique was compared with that of solid-phase technique. (author)
2002-03-01
Carbon coatings with olive oil, soybean oil and butter on nano-LiFePO{sub 4}
Energy Technology Data Exchange (ETDEWEB)
Kitchen oils (olive, soybean and butter) are selected for carbon coatings on LiFePO{sub 4}. The surface properties of LiFePO{sub 4} are unknown or vary depending on synthetic methods. The multi-functional groups of fatty acids in the oils can orient properly to cope with the variable surface properties of LiFePO{sub 4}, which can lead to dense carbon coatings. The low price and low toxicity of kitchen oils are other advantages of the coating process. LiFePO{sub 4} (D{sub 50} = 121 nm)combined with the carbon coating enhances the rate capability. Capacities at the 2C rate reach 150 mAh g{sup -1} or higher. The charge retention values of 2.0C/0.2C are between 94.4 and 98.9%. (author)
2007-05-15
Automation in a material processing/storage facility
Energy Technology Data Exchange (ETDEWEB)
The Savannah River Site (SRS) is currently developing a new facility, the Actinide Packaging and Storage Facility (APSF), to process and store legacy materials from the United States nuclear stockpile. A variety of materials, with a variety of properties, packaging and handling/storage requirements, will be processed and stored at the facility. Since these materials are hazardous and radioactive, automation will be used to minimize worker exposure. Other benefits derived from automation of the facility include increased throughput capacity and enhanced security. The diversity of materials and packaging geometries to be handled poses challenges to the automation of facility processes. In addition, the nature of the materials to be processed underscores the need for safety, reliability and serviceability. The application of automation in this facility must, therefore, be accomplished in a rational and disciplined manner to satisfy the strict operational requirements ...
1997-05-01
Energy Technology Data Exchange (ETDEWEB)
The thermal-hydraulic performance in periodic frosting conditions is experimentally studied for the parallel-flow parallel-fin heat exchanger, henceforth referred to as a PF{sup 2} heat exchanger, a new style of heat exchanger that uses louvered bent fins on flat tubes to enhance water drainage when the flat tubes are horizontal. Typically, it takes a few frosting/defrosting cycles to come to repeatable conditions. The criterion for the initiation of defrost and a sufficiently long defrost period are determined for the test PF{sup 2} heat exchanger and test condition. The effects of blower operation on the pressure drop, frost accumulation, water retention, and capacity in time are compared under the conditions of 15 sequential frosting cycles. Pressure drop across the heat exchanger and overall heat transfer coefficient are quantified under frost conditions as functions of the air humidity and air face velocity. The performances of two types ...
2010-09-15
Aggregation of silica nanoparticles directed by adsorption of lysozyme.
The interaction of the globular protein lysozyme with silica nanoparticles of diameter 20 nm was studied in a pH range between the isoelectric points (IEPs) of silica and the protein (pH 3-11). The adsorption affinity and capacity of lysozyme on the silica particles is increasing progressively with pH, and the adsorbed protein induces bridging aggregation of the silica particles. Structural properties of the aggregates were studied as a function of pH at a fixed protein-to-silica concentration ratio which corresponds to a surface concentration of protein well below a complete monolayer in the complete-binding regime at pH > 6. Sedimentation studies indicate the presence of compact aggregates at pH 4-6 and a loose flocculated network at pH 7-9, followed by a sharp decrease of aggregate size near the IEP of lysozyme. The structure of the bridged silica aggregates was studied by cryo-transmission electron microscopy (cryo-TEM) and small-angle ...
2011-07-20
International Nuclear Information System (INIS)
Thermodynamic data has been selected for solids and aqueous species of technetium. Equilibrium constants have been calculated in the temperature range 0 to 300 deg C at a pressure of 1 bar for T<100 deg C and at the steam saturated pressure at higher temperatures. For aqueous species, the revised Helgeson-Kirkham-Flowers model is used for temperature extrapolations. The data base contains a large amount of estimated data, and the methods used for these estimations are described in detail. A new equation is presented that allows the estimation of #DELTA#_rCdeg_p_m values for mononuclear hydrolysis reactions. The formation constants for chloro complexes of Tc(V) and Tc(IV), whose existence is well established, have been estimated. The majority of entropy and heat capacity values in the data base have also been estimated, and therefore temperature extrapolations are largely based on estimations. The uncertainties derived from these calculations are described. Using ...
Spin-polarized Auger-electron diffraction study of the magnetic poisoning of Fe(001) by sulfur
International Nuclear Information System (INIS)
Spin-polarized angle-resolved sulfur L_2_,_3VV Auger-electron spectra have been recorded for the c(2x2)S/Fe(001) system. The data show the modulation of the sulfur Auger spin polarization as a function of emission angle, which represents an observation of spin-polarized Auger-electron diffraction (SPAED), a potentially powerful tool for the study of local magnetic structure at surfaces, interfaces, and thin films. Theoretical modeling of the SPAED data indicates a large decrease in the magnetization of the top iron layer, suggesting a magnetic poisoning induced by the sulfur overlayer. These findings are independently supported by the observation of a large decrease of secondary electron spin polarization upon sulfur adsorption.
Properties of low residual stress silicon oxynitrides used as a sacrificial layer
Energy Technology Data Exchange (ETDEWEB)
Low residual stress silicon oxynitride thin films are investigated for use as a replacement for silicon dioxide (SiO{sub 2}) as sacrificial layer in surface micromachined microelectrical-mechanical systems (MEMS). It is observed that the level of residual stress in oxynitrides is a function of the nitrogen content in the film. MEMS film stacks are prepared using both SiO{sub 2} and oxynitride sacrificial layers. Wafer bow measurements indicate that wafers processed with oxynitride release layers are significantly flatter. Polycrystalline Si (poly-Si) cantilevers fabricated under the same conditions are observed to be flatter when processed with oxynitride rather than SiO{sub 2} sacrificial layers. These results are attributed to the lower post-processing residual stress of oxynitride compared to SiO{sub 2} and reduced thermal mismatch to poly-Si.
2000-01-04
Observation of strain-enhanced electron-spin polarization in photoemission from InGaAs
International Nuclear Information System (INIS)
Electron-spin polarization in excess of 70% has been observed in photoemission from a 0.1-#mu#m-thick epitaxial layer of In_xGa_1_-_xAs with x#approx#0.13 grown on a GaAs substrate. Under these conditions, the epitaxial layer is expected to be highly strained by the 0.9% lattice mismatch. The electron polarization and the quantum efficiency have been measured as a function of the excitation photon energy from 1.25 to 2.0 eV. A significant enhancement of the electron polarization occurs in the vicinity of 1.33 eV where the expected strain-induced level splitting permits optical excitation of a single-band transition.
Grid cells generate an analog error-correcting code for singularly precise neural computation
British Library Electronic Table of Contents (United Kingdom)
Entorhinal grid cells in mammals fire as a function of animal location, with spatially periodic response patterns. This nonlocal periodic representation of location, a local variable, is unlike other neural codes. There is no theoretical explanation for why such a code should exist. We examined how accurately the grid code with noisy neurons allows an ideal observer to estimate location and found this code to be a previously unknown type of population code with unprecedented robustness to noise. In particular, the representational accuracy attained by grid cells over the coding range was in a qualitatively different class from what is possible with observed sensory and motor population codes. We found that a simple neural network can effectively correct the grid code. To the best of our kn...
2011-01-01
Electron stimulated desorption of anions from adsorbed and condensed CFCl_3 and CF_2Cl_2
International Nuclear Information System (INIS)
Electron simulated desorption of anions from CFCl_3 and CF_2Cl_2 condensed on an Au substrate is studied in the energy range 0-15 eV. The negative fragments are recorded mass spectro metrically as the function of the incident electron energy. Below 10 eV we observe anion desorption via pronounced resonance profiles which are characteristic for dissociative electron attachment (DA) while the continuous rise of the signal at higher energies accounts for dipolar dissociation (DD) and processes involving secondary electrons from the metallic substrate. For both compounds F"- and Cl"- are the only fragment anions we could observe. (author).
1994-03-20
Effects of Valproic Acid on Organic Acid Metabolism in Children: A Metabolic Profiling Study
British Library Electronic Table of Contents (United Kingdom)
Young children are at increased risk for valproic acid (VPA) hepatotoxicity. Urinary organic acid profiles, as a surrogate of mitochondrial function, were obtained in children 1.9 to 17.3 years of age (n = 52) who were undergoing treatment with VPA for seizure disorders. Age-matched patients receiving treatment with carbamazepine (CBZ; n = 50) and healthy children not undergoing treatment (n = 22) served as controls. Age-related changes in organic acid profiles were observed in all three groups. Although the untreated and CBZ control groups were indistinguishable from each other with respect to the principal-component analysis (PCA) score plots of the subjects, a distinct boundary was apparent between the VPA and each of the control groups. Interindividual variability was observed in the V...
2011-01-01
Coherent Smith-Purcell radiation in the far-infrared region from a short-bunched electron beam
International Nuclear Information System (INIS)
Coherent Smith-Purcell radiation, emitted from short-bunched electrons passing by a lamellar-type grating of aluminum, has been observed in the millimeter wave region. The energy of the electrons is either 42 MeV when they are accelerated by an L-band linear accelerator or 150 MeV accelerated by an S-band one. The intensity of the radiation is proportional to the square of the beam current. The radiation is linearly polarized, and the electric vector of the radiation is in the plane defined by the observing point and the beam trajectory. The intensity decreases with the beam height, i.e. the distance of the beam from the surface of the grating, in accordance with the modified Bessel function of zeroth order. copyright 1996 American Institute of Physics.
1995-09-28
System identification refers to estimation of process parameters and is a necessity in control theory. Physical systems usually have varying parameters. For such processes, accurate identification is particularly important. Online identification schemes are also needed for designing adaptive controllers. Real processes are usually of fractional order as opposed to the ideal integral order models. In this paper, we propose a simple and elegant scheme of estimating the parameters for such a fractional order process. A population of process models is generated and updated by particle swarm optimization (PSO) technique, the fitness function being the sum of squared deviations from the actual set of observations. Results show that the proposed scheme offers a high degree of accuracy even when the observations are corrupted to a significant degree. Additional schemes to improve the accuracy still further are also proposed and ...
2008-01-01
"Advanced" data reduction for the AMBER instrument
The amdlib AMBER data reduction software is meant to produce AMBER data products from the raw data files that are sent to the PIs of different proposals or that can be found in the ESO data archive. The way defined by ESO to calibrate the data is to calibrate one science data file with a calibration one, observed as close in time as possible. Therefore, this scheme does not take into account instrumental drifts, atmospheric variations or visibility-loss corrections, in the current AMBER data processing software, amdlib. In this article, we present our approach to complement this default calibration scheme, to perform the final steps of data reduction, and to produce fully calibrated AMBER data products. These additional steps include: an overnight view of the data structure and data quality, the production of night transfer functions from the calibration stars observed during the night, the correction of additional effects ...
2008-01-01
Energy Technology Data Exchange (ETDEWEB)
A fermentation waste, Corynebacterium glutamicum, was successfully employed as a biosorbent for Reactive Black 5 (RB5) from aqueous solution. This paper initially studied the effect of pretreatment on the biosorption capacity of C. glutamicum toward RB5, using several chemical agents, such as HCl, H{sub 2}SO{sub 4}, HNO{sub 3}, NaOH, Na{sub 2}CO{sub 3}, CaCl{sub 2} and NaCl. Among these reagents, 0.1 M HNO{sub 3} gave the maximum enhancement of the RB5 uptake, exhibiting 195 mg/g at pH 1 with an initial RB5 concentration of 500 mg/l. The solution pH and temperature were found to affect the biosorption capacity, and the biosorption isotherms derived at different pHs and temperatures revealed that a low pH (pH 1) and high temperature (35 deg. C) favored biosorption. The biosorption isotherm was well represented using three-parameter models (Redlich-Peterson and Sips) compared to two-parameter models (Langmuir and Freundlich models). As a result, ...
2007-03-06
Energy Technology Data Exchange (ETDEWEB)
This is the first time that the adsorption of binary mixtures of polycyclic aromatic hydrocarbons (PAHs) has been studied. This study was carried out at laboratory scale in an experimental apparatus specially designed for this aim: with gas-phase fluorescence, a new detection procedure was used. Experimental conditions, mainly in terms of temperature (150C) and contaminant concentration (approximately 1 ppmv), close to the ones observed in energy generation systems, were applied. The PAH adsorption process interpretation was carried out by recording the experimentally obtained breakthrough curves. After the detection parameter optimization, the influence of adsorbate characteristics in the hot gas cleaning of PAH was studied. In this system, the adsorption of 10 binary mixtures of five PAH (naphthalene (Np), fluorene (Fu), phenanthrene (Phe), fluoranthene (Fl), and pyrene (Py)) on an activated carbon was investigated. It was found that the adsorbent efficiency is ...
2003-06-01
MnO powder as anode active materials for lithium ion batteries
Energy Technology Data Exchange (ETDEWEB)
MnO powder materials are investigated as anode active materials for Li-ion batteries. Lithium is stored reversibly in MnO through conversion reaction and interfacial charging mechanism, according to the results of ex situ XRD, TEM and galvanostatic intermittent titration technique. A layer of the solid electrolyte interphase with a thickness of 20-60 nm is covered on MnO particles after full insertion. MnO powder materials show reversible capacity of 650 mAh g{sup -1} with average charging voltage of 1.2 V. It can deliver 400 mAh g{sup -1} at a rate of 400 mA g{sup -1}. The cyclic performance of MnO is improved significantly after decreasing particle size and coating with a layer of carbon. Among observed transition metal oxides, MnO shows relatively lower voltage hysteresis (<0.7 V) between the discharging and the charging curves at 0.05 C. In addition to its environmental benign feature and high density (5.43 g cm{sup -3}), MnO seems a ...
2010-05-15
Ionizing radiation-induced mutation of human cells with different DNA repair capacities
Energy Technology Data Exchange (ETDEWEB)
We have observed significant differences in the response to ionizing radiation of two closely related human cell lines, and now compare the effects on these lines of both low and intermediate LET radiation. Compared to TK6, WTK1 has an enhanced X-ray survival, and is also more resistant to cell killing by {alpha}-particles. The hprt locus is more mutable in WTK1 than in TK6 by both X-rays and {alpha}-particles. WTK1 is also more mutable by {alpha}-particles than by X-rays at the hprt locus. X-ray-induced mutation at the heterozygous tk locus in WTK1 is about 25 fold higher than in TK6, while {alpha}-particle-induced mutation is nearly 50 fold higher at this locus. Also, the slowly growing tk- mutants, which comprise the majority of spontaneous and X-ray-induced tk- mutants of TK6, were not induced significantly by {alpha}-particles. Previously, we showed that TK6 has a reduced capacity for recombination compared with WTK1, and therefore, these ...
1994-12-31
Energy Technology Data Exchange (ETDEWEB)
Effects of the addition of precious metals (PM; Pt, Rh) on CeO{sub 2}/Al{sub 2}O{sub 3} and CeO{sub 2}/La{sub 2}O{sub 3}/Al{sub 2}O{sub 3} were confirmed to enhance the oxygen storage capacities (OSC). Increments in the OSC of the added CeO{sub 2}/La{sub 2}O{sub 3}/Al{sub 2}O{sub 3} catalysts were much greater than those in the OSC of the PM added CeO{sub 2}/Al{sub 2}O{sub 3}. The enhanced OSC is ascribed to the interaction between PM and a CeO{sub 2}-La{sub 2}O{sub 3} solid solution formed during the catalyst preparation. No enhancements in the OSC were observed on physical mixing of CeO{sub 2}/La{sub 2}O{sub 3}/Al{sub 2}O{sub 3} and Pt-Rh/Al{sub 2}O{sub 3}, although the composition ratio of PM:CeO{sub 2}:La{sub 2}O{sub 3} is the same as that in the PM added CeO{sub 2}/La{sub 2}O{sub 3}/Al{sub 2}O{sub 3}. This indicates that the intimate contacts between the precious metals and CeO{sub 2} particles dispersed on Al{sub 2}O{sub 3} are essential ...
1990-08-09
Energy Technology Data Exchange (ETDEWEB)
The effect of 10 wk endurance swim training on 3-O-methylglucose (3-MG) uptake (at 40 mM 3-MG) in skeletal muscle was studied in the perfused rat hindquarter. Training resulted in an increase of approximately 33% for maximum insulin-stimulated 3-MG transport in fast-twitch red fibers and an increase of approximately 33% for contraction-stimulated transport in slow-twitch red fibers compared with nonexercised sedentary muscle. A fully additive effect of insulin and contractions was observed both in trained and untrained muscle. Compared with transport in control rats subjected to an almost exhaustive single exercise session the day before experiment both maximum insulin- and contraction-stimulated transport rates were increased in all muscle types in trained rats. Accordingly, the increased glucose transport capacity in trained muscle was not due to a residual effect of the last training session. Half-times for reversal of contraction-induced ...
1990-12-01
Biosorption of americium-241 by Candida sp.
Energy Technology Data Exchange (ETDEWEB)
As an important radioisotope in nuclear industry and other fields, americium-241 is one of the most serious contamination concerns duo to its high toxicity and long half-life. In this experiment, the biosorption of {sup 241}Am from solution by Candida sp., and the effects of various experimental conditions on the adsorption were investigated. The preliminary results showed that the adsorption of {sup 241}Am by Candida sp. was efficient. {sup 241}Am could be removed by Candida sp. of 0.82 g/L (dry weight) from {sup 241}Am solutions of 5.6-111 MBq/L (44.3-877.2 {mu}g/L)(C{sub 0}), with maximum adsorption rate (R) of 98% and maximum adsorption capacities (W) of 63.5 MBq/g biomass (dry weight) (501.8 {mu}g/g). The biosorption equilibrium was achieved within 4 hour and the optimum pH was pH = 2. No significant differences on {sup 241}Am adsorption were observed at 10 C-45 C, or in solutions containing Au{sup 3+} or Ag{sup +}, even 1500 times or 4500 ...
2003-07-01
The construction of earthquake damage estimation system for city gas supply system
Energy Technology Data Exchange (ETDEWEB)
The regular occurrence of large-scale earthquakes in Japan necessitates the use of earthquake disaster prevention systems that focus on gathering damage information on gas supply facilities immediately after an earthquake strikes and minimizing the damage. This paper discussed the development of an earthquake damage estimation system for city gas pipelines that can show damage information in real-time by using earthquake records obtained from densely deployed earthquake observation networks and the most advanced telecommunication and information technologies. The paper summarized the earthquake damage estimation system (EDES) and Toho Gas disaster prevention measures. Specific topics that were discussed included the Toho Gas supply method; earthquake countermeasures; construction of computer systems; normal and emergency operation of EDES; and verification of functions in actual earthquakes. It was concluded that when there is an emergency, the ...
2010-07-01
Energy Technology Data Exchange (ETDEWEB)
With an objective to learn reactivity of coal at its surface, surfaces of oxidized coal samples were investigated. Miike coal was oxidized by using {sup 18}O2 in a closed loop system. As the reaction progresses, proportion of CO2 including isotopes increased rapidly as a result of oxidation of CO sites existing in the coal and the newly generated C{sup 18}O sites. The oxidizing reaction progressed via oxygen adsorbing sites generated near the surface, and oxygen containing groups. An FT-IR analysis estimated the depth of the oxidized layer to be 10{mu}m or less from particle surface. The oxidized coal was pulverized to see its surface condition. Functional groups introduced by the oxidation enter into the vicinity of the surface in a form to desorb as CO. CO2 is trapped in inner pores. The coal surface was observed by using an atomic force microscope. No observable openings in the pore structure were discerned on the ...
1996-10-28
Testosterone has bipotential effects on male fitness; that is, it both suppresses immune function and maintains characteristics important for reproductive success. Presumably, these effects of testosterone may be more pronounced among polygynous species because testosterone concentrations are generally higher among polygynous than monogamous males. The present study examined sex and species differences in cell-mediated immunity among four arvicoline rodents. The role of mating system and sex steroids in sex differences in immune function was examined in individually housed polygynous meadow (Microtus pennsylvanicus) and montane (M. montanus) voles and monogamous prairie (M. ochrogaster) and pine (M. pinetorum) voles in Experiment 1. No sex differences in splenocyte proliferation were observed among the four species and circulating testosterone concentrations did not correlate with immune function of ...
1997-08-01
Thermal energy storage system using stearic acid as a phase change material
Energy Technology Data Exchange (ETDEWEB)
The thermal performance and phase change stability of stearic acid as a latent heat energy storage material has been studied experimentally. The thermal performance and heat transfer characteristics of the stearic acid were tested and compared with other studies given in the literature. In the present study, parameters such as transition times, temperature range and propagation of the solid-liquid interface as well as the effect of heat flow rate on the phase change stability of stearic acid as a phase change material (PCM) were studied. The experimental results showed that the melting stability of the PCM is better in the radial direction than in the axial direction. The variation in the melting and solidification parameters of the PCM with the change of inlet water temperature is also studied. We observed that while the heat exchanger tube is in the horizontal position, the PCM has more effective and steady phase change characteristics than in the vertical ...
2001-07-01
Energy Technology Data Exchange (ETDEWEB)
Ice jamming, known to cause high water levels at even moderate river flows, is described as both the main and least understood source of ice-related bridge damages. This paper describes a joint study by the New Brunswick Department of Transportation, the Department of the Environment, local governments, and the National Water Research Institute, designed to address problems associated with the interaction of ice jams and bridges. The study consists of collecting information at each of four sites in New Brunswick including: historical data on ice jam locations, causes, and water levels; channel bathymetry, width and slope within each study centred at the respective bridge; and documentation of ice conditions throughout the ice season, including measurement of ice cover thickness, observation of breakup mechanisms, times, causes, characteristics and possible impacts of ice jam release. Data analysis will include determination of high stages due to ice jams or surges ...
2000-12-01
Psychoanalysis and psychosomatics: a new synthesis.
The usefulness of psychoanalysis to psychosomatic medicine has been limited by the longstanding assumption that the psychological disorder in psychosomatic patients resembles the conflict-based psychopathology that Freud identified in psychoneurotic patients. Recent investigations of the alexithymia construct, and the discovery that social relationships can influence health over the entire life span, have challenged this assumption and created an opportunity for a new and active involvement of psychoanalysis with psychosomatic medicine. In this contribution, I offer a synthesis of contemporary psychoanalytic observations and theories with concepts and research findings from developmental psychology, developmental biology, and the biomedical sciences. The proposed synthesis is consistent with the view that living organisms are self-regulating cybernetic systems; it also extends an evolving new psychosomatic model that conceptualizes illnesses and diseases as ...
1992-01-01
Energy Technology Data Exchange (ETDEWEB)
Reductive quenching of two photoexcited ruthenium(II) complexes by an anionic electron donor, 2,2{prime}-azinobis(3-ethyl-benzothiazoline-6-sulfonate) (ABTS{sup 2{minus}}), in aqueous solution was examined by laser flash photolysis before and after adding positively charged colloidal (250-{angstrom} diameter) alumina-coated silica particles. The kinetics and quantum yields of electron transfer with an anionic sensitizer, RuL{sub 3}{sup 4{minus}} (L = bathophenanthroline disulfonate), and a cationic one, Ru(bpy){sub 3}{sup 2+} (bpy = 2,2{prime}-bipyridine), were compared. Coadsorption of ABTS{sup 2{minus}} and RuL{sub 3}{sup 4{minus}} by the particles greatly enhanced the rate of quenching such that only the reaction occurring on the surfaces of the particles was observed. Electron transfer from ABTS{sup 2{minus}} to RuL{sub 3}{sup 4-*} occurred by a static (nondiffusional) process, and the quenching efficiency was maximal when there was close to monolayer coverage ...
1989-02-23
High-performance hybrid pervaporation membranes with superior hydrothermal and acid stability
Energy Technology Data Exchange (ETDEWEB)
A new organic-inorganic hybrid membrane has been prepared with exceptional performance in dewatering applications. The only precursor used in the sol-gel synthesis of the selective layer was organically linked 1,2-bis(triethoxysilyl)ethane (BTESE). The microporous structure of this layer enables selective molecular sieving of small molecules from larger ones. In the dehydration of n-butanol with 5% of water, the membrane shows a high separation factor of over 4000 and ultra-fast water transport at a rate of more than 20 kg m{sup -2} h{sup -1} at 150C. This can be related to the high adsorption capacity of the material and the sub-micron thickness of the selective layer. The selectivity has now remained constant over almost one and a half years under continuous process testing conditions. Apart from the hydrothermal stability, the membrane exhibits a high tolerance for acid contamination. A slow performance decline in flux and separation factor is only ...
2009-05-15
Desorption of polycyclic aromatic hydrocarbons from carbon nanomaterials in water
Energy Technology Data Exchange (ETDEWEB)
Desorption behavior of pyrene, phenanthrene and naphthalene from fullerene, single-walled carbon nanotubes (SWCNTs) and multi-walled carbon nanotubes (MWCNTs) was examined. Available adsorption space of carbon nanotubes (CNTs) was found to be the cylindrical external surface, neither the inner cavities nor inter-wall spaces due to impurities in the CNTs and restricted spaces (0.335 nm) of the MWCNTs, respectively. Desorption hysteresis was observed for fullerene but not for CNTs. Deformation-rearrangement was proposed to explain the hysteresis of polycyclic aromatic hydrocarbons (PAHs) for fullerene, due to the formation of closed interstitial spaces in spherical fullerene aggregates. However, long, cylindrical carbon nanotubes could not form such closed interstitial spaces in their aggregates due to their length, thus showing no significant hysteresis. High adsorption capacity and reversible adsorption of PAHs on CNTs imply the potential ...
2007-01-15
Energy Technology Data Exchange (ETDEWEB)
Pulsed laser deposition (PLD) is known for its capacity to reproduce a target composition on a substrate. The authors have used this deposition technique to produce thin films of transition metal chalcogenides. However, the deposits were always deficient in Te relative to the starting material (composed by a refractory metal (niobium) and a chalcogene (tellurium)). Variations of the interreticular distances have been observed with respect to fluence and substrate temperature. The authors show that spatial composition of the films is determined by a degree of crystallinity of deposit and by the reaction of formation of Te{sub 2} molecule within laser induced plume. Two kinds of deposits have been obtained: Nb{sub 5}Te{sub 4}-type thin films which have a one-dimensional structure and NbTe{sub 2}-type thin films which have a two-dimensional structure. While NbTe{sub 2} films have been realized by sputtering, it is the first time that Nb{sub ...
1996-12-31
Energy Technology Data Exchange (ETDEWEB)
The ability of white-rot fungus, Pycnoporus sanguineus to adsorb copper (II) ions from aqueous solution is investigated in a batch system. The live fungus cells were immobilized into Ca-alginate gel to study the influence of pH, initial metal ions concentration, biomass loading and temperature on the biosorption capacity. The optimum uptake of Cu (II) ions was observed at pH 5 with a value of 2.76 mg/g. Biosorption equilibrium data were best described by Langmuir isotherm model followed by Redlich-Peterson and Freundlich models, respectively. The biosorption kinetics followed the pseudo-second order and intraparticle diffusion equations. The thermodynamic parameters enthalpy change (10.16 kJ/mol) and entropy change (33.78 J/mol K) were determined from the biosorption equilibrium data. The FTIR analysis showed that -OH, -NH, C-H, C=O, -COOH and C-N groups were involved in the biosorption of Cu (II) ions onto immobilized cells of P. sanguineus. ...
2009-01-15
[HBsAG in feces, urine and saliva].
After some observations about the tests of the research exposed in the literature, authors illustrate the tests for 142 patients divided into 5 groups: a) patients affected with acute viral hepatitis; b) patients affected with praegressa acute viral hepatitis; c) relatives of patients with acute viral hepatitis; d) volunteers; e) patients affected with chronic uraemia under dialisis periodic treatment. After the testing control, authors, conclude with an hipotesis: a possible epidemic function of faeces, urine saliva, in the passage of the acute viral hepatitis. PMID:488577
Superconductivity in irradiated A-15 compounds at low fluences. I. Neutron-irradiated V_3Si
International Nuclear Information System (INIS)
The behavior of the superconducting transition temperature T/sub c/ of single-crystal and polycrystalline V_3Si was investigated as a function of low-fluence neutron irradiation. It is found that the initial degradation of T/sub c/ is sample-dependent, some specimens showing no degradation in T/sub c/ up to a fluence of 2 x 10"1"8 n/cm"2. This and many other earlier observations on low-fluence behavior are explained in terms of a recently proposed model of radiation damage in A-15 compounds.
Simulation of DNA electrophoresis through microstructures
British Library Electronic Table of Contents (United Kingdom)
The dependence of the mobility of DNA molecules through an hexagonal array of micropillars on their length and the applied electric field was investigated and it was found that mobility is a nonmonotonic function of their length. Results also revealed that the size dependence of the DNA mobility depends on the applied electric field and there is a crossover around E 25 V/cm for the mobility of l-DNA and T4-DNA. These observations are explained in terms of the diffusion process inside the structure affected by the solvent and are modeled using the Langevin and its corresponding Fokker-Planck equations. The phenomenon is generalized under three regimes in a phase diagram relating the electric field and the DNA lengths. The model and the associated phase diagram described here provide an expl...
2007-01-01
International Nuclear Information System (INIS)
The 2nd periodical inspection was carried out on the asphalt solidification facility and the incinerator in Unit 2 of the Sendai Nuclear Power Station from November 5 to 28, 1985. Inspection was made in radiation control facility and disposal facility. By external appearance, disassembly, function and performance tests there were observed no abnormalities. The personnel exposure doses during the inspection were below the permissible level. In the inspection, improvement etc. works were not done. (Mori, K.).
1986-01-01
Energy Technology Data Exchange (ETDEWEB)
The form factor for excitation of the 1/sup +/ state at 3.48 MeV in /sup 88/Sr by inelastic electron scattering has been measured for momentum transfers q = 0.24-0.62 fm/sup -1/. Neither its magnitude nor shape can be described employing the best available nuclear wave functions. We demonstrate with a schematic model that the observed reduction of the form factor may be understood by taking into account a renormalization of the M1-operator due to virtual ..delta..-hole excitations.
1982-04-01
International Nuclear Information System (INIS)
The form factor for excitation of the 1"+ state at 3.48 MeV in "8"8Sr by inelastic electron scattering has been measured for momentum transfers q = 0.24-0.62 fm"-"1. Neither its magnitude nor shape can be described employing the best available nuclear wave functions. We demonstrate with a schematic model that the observed reduction of the form factor may be understood by taking into account a renormalization of the M1-operator due to virtual #DELTA#-hole excitations. (orig.).
Phase diagram and effective shape of semi-flexible colloidal rods and biopolymers
We study suspensions of semi-flexible colloidal rods and biopolymers using an Onsager-type second-virial functional for a segmented-chain model. For suspensions of thin and thick fd virus particles we calculate phase diagrams in quantitative agreement with experimental observations, and we find their effective state-point dependent shape to be much shorter and thicker than the actual shape. We also calculate the stretching of worm-like micelles in a host fd virus solution, again finding agreement with experiments. For both systems, our results show that the fd virus stiffness can play a key role in system behavior.
2011-01-01
On the mechanism of the nonmonotonic relaxation processes in the metallic melts
International Nuclear Information System (INIS)
The numerical analysis of the experimental data on viscosity change by time in the period after fast heating and crystal-liquid phase transition for the copper nonequilibrium melts and the Fe_7_0Cr_1_0P_1_3C_7 glass-forming melt near their melting temperatures is accomplished through the method of correlation functions and the Rytov-Dimentberg criterion. The observed dependences have nonmonotonic oscillating character but they do not relate to auto-oscillations. The proposed theoretical model of the properties oscillations origination by relaxation in the nonequilibrium liquids explains them as manifestation of noise-induced transitions in the metastable area near the critical temperatures (melting, structural transitions)
2000-01-01
Neutron irradiation effects in austenitic alloys
International Nuclear Information System (INIS)
The post (neutron) -irradiation high-temperature tensile and creep-rupture properties, deformation and fracture characteristics of austenitic alloys, particularly solution annealed Type 316 steel, are surveyed and correlated with the damage structures developed as a function of irradiation temperature (and dose). The mechanisms proposed to explain the irradiation-induced changes in properties and behaviour are summarised. The factors responsible for the observed differences in the post-irradiation and 'in-reactor' creep-rupture properties and behaviour of an austenitic steel are discussed in terms of the helium gas and stress driven growth of small intergranular bubbles and the atom plating associated with their growth and coalescence. (author).
1980-03-01
Knock limitations of methane-air mixtures in a turbocharged dual-fuel engine
Energy Technology Data Exchange (ETDEWEB)
Knock limitations are investigated using natural gas, with diesel pilot ignition, as a fuel for the 3406 DI-TA Caterpillar diesel engine. Thermodynamic properties at TDC are generated by computer and compared with experimental results. Exhaust emissions are analyzed. A comparison is made of dual-fuel operation relative to diesel. Observations are made to determine the onset of knock. The onset of knock is characterized as a function of engine speed, load, inlet manifold temperature, and air-fuel ratio (A/F). The conditions at the inset of knock are determined using cylinder pressure data. The most efficient operating range is determined with knock avoidance as a prime parameter.
1987-01-01
Excitation of 1/sup +/ states in /sup 88/Sr by proton inelastic scattering
Energy Technology Data Exchange (ETDEWEB)
In a (p,p') study of /sup 88/Sr at Esub(p) = 201 MeV both a large resonance centered at 9.4 MeV excitation energy and the known 1/sup +/ state at 3.486 MeV are excited. Several discrete states are observed in the resonance. The cross section of the whole resonance is 27% of a simple particle-hole prediction. The strength of the low-lying 1/sup +/ state is only about 15% of that calculated from a wave function including core-polarization contributions, whereas (e,e') scattering finds about 50%.
1985-06-10
Excitation of 1"+ states in "8"8Sr by proton inelastic scattering
International Nuclear Information System (INIS)
In a (p,p') study of "8"8Sr at Esub(p) = 201 MeV both a large resonance centered at 9.4 MeV excitation energy and the known 1"+ state at 3.486 MeV are excited. Several discrete states are observed in the resonance. The cross section of the whole resonance is 27% of a simple particle-hole prediction. The strength of the low-lying 1"+ state is only about 15% of that calculated from a wave function including core-polarization contributions, whereas (e,e') scattering finds about 50%. (orig.).
International Nuclear Information System (INIS)
Hitherto in this laboratory, ionization coefficients alpha and attachment coefficients #eta# have been determined from Townsend's discharge experiments by a curve-fitting method. However, the method proved to be laborious, Formulae have been derived in this paper to give value of alpha and #eta# as a function of Isubo, Isub1 and Isub2 where Isubo is the photoelectric current at a gap setting d and Isub2 the current at another gap setting 2 d. The values of alpha and #eta# obtained give currents in agreement to within 3% in the best cases with the observed currents.
Effects of avalanche hole injection in fluorinated SiO[sub 2] MOS capacitors
Energy Technology Data Exchange (ETDEWEB)
Significantly improved immunity to hot-hole damage of the SiO[sub 2]/Si structure is achieved by a shallow fluorine implantation into the poly-Si gate of MOS capacitors followed by a drive-in process. Compared to the nonfluorinated control, the fluorinated samples exhibit a dramatic reduction of both hole trapping probability and interface-trap generation under avalanche hole injection conditions. The degree of such an improvement increases monotonically as a function of the F implantation dose (up to 10[sup 16]/cm[sup 2]). Significant decrease of the hole detrapping rate is also observed in fluorinated samples. Possible mechanisms are discussed.
1993-04-01
Effective Constraints for Quantum Systems
An effective formalism for quantum constrained systems is presented which allows manageable derivations of solutions and observables, including a treatment of physical reality conditions without requiring full knowledge of the physical inner product. Instead of a state equation from a constraint operator, an infinite system of constraint functions on the quantum phase space of expectation values and moments of states is used. The examples of linear constraints as well as the free non-relativistic particle in parameterized form illustrate how standard problems of constrained systems can be dealt with in this framework.
2008-01-01
International Nuclear Information System (INIS)
Polymer composites are used in numerous applications. In spite of this fact, new developments are still under way to explore in other field of application of these materials and to tailor their properties for more extreme condition. A particular emphasis is focused on fillers content is summarized. Some steps towards the functionally graded materials are illustrated. The FT-IR spectroscopic studies revealed the information about curing of epoxy with fillers. It was observed that mechanical properties like tensile strength, hardness etc get enhanced up with filler contents. The effect of the different formulations were investigated and discussed for optimum process condition. (author)
1398-01-01
International Nuclear Information System (INIS)
Nano-indentation has been used to assess the hardness of equiaxed grains of #alpha#-Ti as a function of orientation. Surface normals of these grains in metallographic sections were assessed using orientation imaging microscopy. Thin membranes of material from below a series of nano-indentations were excised by use of a dual-beam focused ion beam instrument. In this way, the dislocation substructures beneath individual indentations were characterized using transmission electron microscopy, permitting an identification of both statistically stored and geometrically necessary dislocations.
2005-07-25
Dielectric behavior of Ba{sub 0.95}Sr{sub 0.05}TiO{sub 3} ceramics sintered by microwave
Energy Technology Data Exchange (ETDEWEB)
Here we report detailed dielectric studies carried out on a Barium strontium titanate (BST) (95:5) composition. The material was synthesized by conventional ceramic method and microwave processing, and the later technique resulted in material with high density, improved microstructure and dielectric properties. The dielectric properties were studied as a function of frequency and temperature and well-defined ferroelectric behavior of first order transition was observed. It follows Curie-Weiss law above transition temperature (paraelectric region). Curie temperature is slightly higher for microwave sintered (MS) material.
2002-12-01
Computer model of high-latitude scintillation. [WBMOD program
Energy Technology Data Exchange (ETDEWEB)
The DNA Wideband satellite experiment provided extensive data on scintillation produced in high-altitude structured plasmas. A computer program, WBMOD, is being developed to summarize those data in an applications-oriented way. The program contains the phase-screen scattering theory of Rino and a morphological description of ionospheric irregularities (thus far only at auroral latitudes) based on Wideband observations. It permits a user to compute scintillation indices for both phase and intensity as a function of system operating parameters and solar-ionospheric disturbance level. Correction is made for multiple scatter, and the user may choose either one-way (communication) or two-way (radar) propagation.
1982-01-01
Computer model of high-latitude scintillation
International Nuclear Information System (INIS)
The DNA Wideband satellite experiment provided extensive data on scintillation produced in high-altitude structured plasmas. A computer program, WBMOD, is being developed to summarize those data in an applications-oriented way. The program contains the phase-screen scattering theory of Rino and a morphological description of ionospheric irregularities (thus far only at auroral latitudes) based on Wideband observations. It permits a user to compute scintillation indices for both phase and intensity as a function of system operating parameters and solar-ionospheric disturbance level. Correction is made for multiple scatter, and the user may choose either one-way (communication) or two-way (radar) propagation.
Automatic interpretation of Schlumberger soundings
Energy Technology Data Exchange (ETDEWEB)
The automatic interpretation of apparent resistivity curves from horizontally layered earth models is carried out by the curve-fitting method in three steps: (1) the observed VES data are interpolated at equidistant points of electrode separations on the logarithmic scale by using the cubic spline function, (2) the layer parameters which are resistivities and depths are predicted from the sampled apparent resistivity values by SALS system program and (3) the theoretical VES curves from the models are calculated by Ghosh's linear filter method using the Zhody's computer program. Two soundings taken over Takenoyu geothermal area were chosen to test the procedures of the automatic interpretation.
1980-09-01
British Library Electronic Table of Contents (United Kingdom)
We have measured the frequency-dependent dielectric function of semi-crystalline polybutylene terephthalate (PBT) in the terahertz region between 100?GHz and approximately 2.8?THz. A characteristic band is observed around 2.38?THz. The intensity of this band is a good indicator of the degree of crystallinity of the different samples. A potential assignment of this band is proposed, based on the comparison with spectroscopic data of the structurally very similar polyethylene terephtalate (PET). Furthermore, the frequency-dependent index of refraction of PBT reveals more insight about the morphology and different thermal history of the samples under investigation.
2011-01-01
Analysis of the beam bunching produced by a free electron laser
International Nuclear Information System (INIS)
A high-power microwave Free Electron Laser (FEL) experiment has been performed to study the inherent electron beam bunching that occurs in the FEL interaction. An induction linac delivered a 1 kA, 2.2 MeV electron beam to a FEL amplifier. In the process of amplifying the input signal of frequency 35 GHz to power levels of the order of 10 MW, the electron beam was bunched by the ponderomotive force. In this paper we describe the FEL experiment and the optical technique that was used to observe the bunches. Their properties as functions of the basic FEL parameters are discussed. copyright 1996 American Institute of Physics.
International Nuclear Information System (INIS)
Structural and functional responses of a benthic macroinvertebrate assemblage to pulses of the insecticide imidacloprid were assessed in outdoor stream mesocosms. Imidacloprid pulses reduced invertebrate abundance and community diversity in imidacloprid-dosed streams compared to control streams. These results correlated well with effects of imidacloprid on leaf litter decomposition and feeding rates of Pteronarcys comstocki, a stonefly, in artificial streams. Reductions in oxygen consumption of stoneflies exposed to imidacloprid were also observed in laboratory experiments. Our findings suggest that leaf litter degradation and single species responses can be sensitive ecotoxicological endpoints that can be used as early warning indicators and biomonitoring tools for pesticide contamination. The data generated illustrates the value of mesocosm experiments in environmental assessment and how the consideration of functional ...
Holomorphic wave function of the Universe
Energy Technology Data Exchange (ETDEWEB)
The quantum behavior of the vacuum Bianchi type-IX universe with the cosmological constant is investigated in terms of the Ashtekar variables. An exact solution to the quantum Hamiltonian constraint in the holomorphic representation is given. This solution reduces to the Hartle-Hawking wave function in the spatially isotropic sector and extends in the triad representation to the classically forbidden region where the determinant of the spatial metric becomes negative. The analysis of the quantum Robertson-Walker universe indicates that if the superspace is extended to such a classically forbidden region, the holomorphic representation picks up some restricted class of solutions in general. This observation leads to a new ansatz on the boundary condition of the Universe. In particular, the behavior of the Lorentzian and Euclidean WKB orbits corresponding to the solution suggests a new picture on the semiclassical behavior of the quantum ...
1990-10-15
Holomorphic wave function of the Universe
International Nuclear Information System (INIS)
The quantum behavior of the vacuum Bianchi type-IX universe with the cosmological constant is investigated in terms of the Ashtekar variables. An exact solution to the quantum Hamiltonian constraint in the holomorphic representation is given. This solution reduces to the Hartle-Hawking wave function in the spatially isotropic sector and extends in the triad representation to the classically forbidden region where the determinant of the spatial metric becomes negative. The analysis of the quantum Robertson-Walker universe indicates that if the superspace is extended to such a classically forbidden region, the holomorphic representation picks up some restricted class of solutions in general. This observation leads to a new ansatz on the boundary condition of the Universe. In particular, the behavior of the Lorentzian and Euclidean WKB orbits corresponding to the solution suggests a new picture on the semiclassical behavior of the quantum ...
Density functional calculations of 15N chemical shifts in solvated dipeptides
International Nuclear Information System (INIS)
We performed density functional calculations to examine the effects of solvation, hydrogen bonding, backbone conformation, and the side chain on 15N chemical shielding in proteins. We used N-methylacetamide (NMA) and N-formyl-alanyl-X (with X being one of the 19 naturally occurring amino acids excluding proline) as model systems. In addition, calculations were performed for selected fragments from protein GB3. The conducting polarizable continuum model was employed to include the effect of solvent in the density functional calculations. Our calculations for NMA show that the augmentation of the polarizable continuum model with the explicit water molecules in the first solvation shell has a significant influence on isotropic 15N chemical shift but not as much on the chemical shift anisotropy. The difference in the isotropic chemical shift between the standard ?-sheet and ?-helical conformations ranges from 0.8 to 6.2 ppm depending on the residue ...
2008-06-01
Energy Technology Data Exchange (ETDEWEB)
A beta microprobe was successfully applied to monitor arterial input function for quantification of regional cerebral blood flow (rCBF) in the monkey brain with {sup 15}O-water and positron emission tomography (PET). The sensitivity of the probe was approximately 0.83 to 1.67 cps/kBq/ml depending on the studies. A preliminary study was performed to find a suitable use and to evaluate the performance of the system and data analysis procedure. The results showed that dispersion correction of measured input function was unnecessary if microprobes were connected directly to the arterial catheter. Then multiple CBF measurements were done in three monkeys under anesthesia. Identical regions of interest were placed with the aid of magnetic resonance imaging (MRI) of each monkey and rCBF values were estimated. Estimated rCBFs were reproducible for several measurements. The mean CBF value for a pentobarbital anesthetized monkey was 46.0 ml/min/100 g ...
1998-02-01
Energy Technology Data Exchange (ETDEWEB)
Shewanella oneidensis MR-1 is a model environmental organism that possesses diverse respiratory capacities, including the ability to reduce soluble Cr(VI) to sparingly soluble, less toxic Cr(III). Effective bioremediation of Cr-contaminated sites requires knowledge of the molecular mechanisms and regulation of heavy metal resistance and biotransformation by dissimilatory metal-reducing bacteria. Towards this goal, our ERSP-funded work is focused on the identification and functional analysis of genes/proteins comprising the response pathways for chromate detoxification and/or reduction. Previous transcriptomic profiling and whole-cell proteomic analyses implicated the involvement of a functionally undefined DNA-binding response regulator (SO2426) and a putative azoreductase (SO3585) in the chromate stress response of MR-1. Here we describe a detailed functional analysis of SO2426 and SO3585 in order to ...
2006-04-05
Energy Technology Data Exchange (ETDEWEB)
We report the results of ab initio calculations of cross sections and molecular-frame photoelectron angular distributions for C 1s ionization of CO2, and propose a mechanism for the recently observed asymmetry of those angular distributions with respect to the CO^+and O^+ions produced by subsequent Auger decay. The fixed-nuclei, photoionization amplitudes were constructed using variationally obtained electron-molecular ion scattering wave functions. We have also carried out electronic structure calculations which identify a dissociative state of the CO2^++ dication that is likely populated following Auger decay and which leads to O^+ + CO^+ fragment ions. We show that a proper accounting of vibrational motion in the computation of the photoelectron angular distributions, along with reasonable assumptions about the nuclear dissociation dynamics, gives results in good agreement with recent experimental observations. We also ...
2009-02-18
Strain enhanced electron spin polarization observed in photoemission from InGaAs
International Nuclear Information System (INIS)
Electron spin polarization in excess of 70% has been observed in photoemission from a 0.1 #mu#m-thick epitaxial layer of In_xGa_1_-_xAs with x #approx# 0.13 grown on a GaAs substrate. Under these conditions, the epitaxial layer is expected to be highly strained by the 0.9% lattice mismatch, as confirmed by x-ray diffractometer measurements of the lattice parameter. The electron polarization and the quantum efficiency have been measured as a function of the excitation photon energy from 1.25 to 2.0 eV. A significant enhancement of the electron polarization occurs in the vicinity of 1.33 eV where the expected strain-induced level splitting permits optical excitation of a single band transition. Measurements made on a control sample of 1.14 #mu#m thickness, significantly larger than the critical thickness for pseudomorphic strain, show no polarization enhancement. These measurements represent the first observation of ...
1991-05-06
The data obtained by the recent modern sky surveys enable detailed studies of the stellar distribution in the multi-dimensional space spanned by spatial coordinates, velocity and metallicity, from the solar neighborhood all the way out to the outer Milky Way halo. While these results represent exciting observational breakthroughs, their interpretation is not simple. For example, traditional decomposition of the thin and thick disks predicts a strong correlation in metallicity and kinematics at $\\sim$1 kpc from the Galactic plane; however, recent SDSS--based work has demonstrated an absence of this correlation for disk stars. Instead, the variation of the metallicity and rotational velocity distributions can be modeled using non--Gaussian functions that retain their shapes and only shift as the distance from the mid--plane increases. To fully contextualize these recent observational results, a detailed comparison with ...
2008-01-01
Pairing effects in nucleon transfer reactions in the system sup 144 Sm+ sup 88 Sr at 4. 7 MeV/u
Energy Technology Data Exchange (ETDEWEB)
Proton and neutron transfer populating low-lying states have been studied in the system {sup 144}Sm+{sup 88}Sr at an energy below the Coulomb barrier. The experimental cross sections for the single proton transfer are well reproduced by DWBA-calculations using spectroscopic information from light ion reactions. The two-proton transfer appears enhanced relative to the uncorrelated sequential transfer of single protons. The same holds for the transfer of proton pairs, the enhancement is kept for the second pair. This is interpreted as a supercurrent between two superfluid nuclear proton-pair wave functions: More mass and charge is transported per time unit in pairs than by single nucleons. Neutron transfer is observed with large cross sections and is found to contribute to the energy loss observed in the transfer reactions. For mixed proton-neutron transfers the sequential nature of the transfer reactions is established in a ...
1990-05-01
Pairing effects in nucleon transfer reactions in the system "1"4"4Sm+"8"8Sr at 4.7 MeV/u
International Nuclear Information System (INIS)
Proton and neutron transfer populating low-lying states have been studied in the system "1"4"4Sm+"8"8Sr at an energy below the Coulomb barrier. The experimental cross sections for the single proton transfer are well reproduced by DWBA-calculations using spectroscopic information from light ion reactions. The two-proton transfer appears enhanced relative to the uncorrelated sequential transfer of single protons. The same holds for the transfer of proton pairs, the enhancement is kept for the second pair. This is interpreted as a supercurrent between two superfluid nuclear proton-pair wave functions: More mass and charge is transported per time unit in pairs than by single nucleons. Neutron transfer is observed with large cross sections and is found to contribute to the energy loss observed in the transfer reactions. For mixed proton-neutron transfers the sequential nature of the transfer reactions is established in a similar ...
Locally Optimally-emitting Clouds and the Narrow Emission Lines in Seyfert Galaxies
The narrow emission line spectra of active galactic nuclei are not accurately described by simple photoionization models of single clouds. Recent Hubble Space Telescope images of Seyfert 2 galaxies show that these objects are rich with ionization cones, knots, filaments, and strands of ionized gas. Here we extend to the narrow line region the ``locally optimally emitting cloud'' (LOC) model, in which the observed spectra are predominantly determined by powerful selection effects. We present a large grid of photoionization models covering a wide range of physical conditions and show the optimal conditions for producing many of the strongest emission lines. We show that the integrated narrow line spectrum can be predicted by an integration of an ensemble of clouds, and we present these results in the form of diagnostic line ratio diagrams making comparisons with observations. We also predict key diagnostic line ratios as a ...
1997-01-01
Local therapies to heal the penis: fact or fiction?
Penile rehabilitation has been an area of intense study and debate over the last decade. Interest in this topic was stimulated by the observation that erectile dysfunction remained a significant problem after radical prostatectomy despite meticulous nerve-sparing technique. Smooth muscle alterations and fibrotic changes in the penis were identified as the underlying causes of penile atrophy, veno-occlusive dysfunction, and Peyronie's-like changes that were observed after surgery. Initial observations that intracavernous injection therapies used on a regular basis postoperatively resulted in improvements in the return of spontaneous erectile function led to the development of penile rehabilitation protocols. Chronic dosing of oral type V phosphodiesterase inhibitors is now commonly used by urologists after radical prostatectomy despite a lack of convincing evidence from randomized, placebo-controlled ...
2008-11-20
Focused ion-beam line profiles: A study of some factors affecting beam broadening
Energy Technology Data Exchange (ETDEWEB)
The current--density profile of a focused ion beam (FIB) has a central peak accompanied by broader ``wings`` that, while unimportant in lithographic applications, can lead to unwanted effects during an implantation operation. The origin of the wings, and hence the best way to minimize them, is not clear and needs further study. We have measured the line profiles of several of the ions available in our FIB machine as a function of a number of variables, under ultrahigh vacuum (UHV) conditions. No effects are observed from changes in emission current or deliberate defocusing of the objective lens. There are some changes with beam aperture and/or current, but the biggest differences seem to be associated with a change of source type and hence, possibly, with a change in the source/extractor configuration or in the alloy and the emission process. The wing amplitudes are appreciably lower than many previously observed, and their ...
1995-11-01
Focused ion-beam line profiles: A study of some factors affecting beam broadening
International Nuclear Information System (INIS)
The current--density profile of a focused ion beam (FIB) has a central peak accompanied by broader ''wings'' that, while unimportant in lithographic applications, can lead to unwanted effects during an implantation operation. The origin of the wings, and hence the best way to minimize them, is not clear and needs further study. We have measured the line profiles of several of the ions available in our FIB machine as a function of a number of variables, under ultrahigh vacuum (UHV) conditions. No effects are observed from changes in emission current or deliberate defocusing of the objective lens. There are some changes with beam aperture and/or current, but the biggest differences seem to be associated with a change of source type and hence, possibly, with a change in the source/extractor configuration or in the alloy and the emission process. The wing amplitudes are appreciably lower than many previously observed, and their ...
International Nuclear Information System (INIS)
The purpose of this research is to investigate the micro-mechanism of deformation behavior of metallic glasses. We report the results of direct observations of short-range and medium-range structural change during tensile deformation of metallic glasses by high energy X-ray diffraction method. Cu50Zr50 and Ni30Zr70 metallic glass samples in the ribbon shape (1.5 mm width and 25 ?m) were made by using rapid quenching method. Tensile deformation added to the sample was made by using special equipment adopted for measuring the high energy X-ray diffraction. The peaks in pair distribution function g(r) for Cu50Zr50 and N30iZr70 metallic glasses move zigzag into front and into rear during tensile deformation. These results of direct observation on atomic distribution change for Cu50Zr50 and Ni30Zr70 metallic glass ribbons during tensile deformation suggest that the micro-relaxations occur.
2009-08-26
Direct observation of ordered orbital of YTiO_3 by the X-ray magnetic diffraction technique
International Nuclear Information System (INIS)
X-ray magnetic diffraction (XMD) technique was applied to an orbital ordering compound of ferromagnetic YTiO_3 for the first time. The orbital-magnetic form factor #mu# _L(k) and the spin-magnetic form factor #mu# _S(k) were independently measured by utilizing the LS separation ability of the XMD. The #mu# _L(k) was measured for ten reciprocal-lattice points. No significant values of the #mu# _L(k) were observed for most of the reciprocal-lattice points within the estimated statistical errors, which suggested quenching of the orbital moment. The #mu# _S(k) was measured for 22 reciprocal-lattice points. Fourier synthesis of the #mu# _S(k) gave the spin density distribution m _S(r) in the real space. The obtained m _S(r) map shows the characteristic feature of the electron distribution of 3d electron in the t_2_g state of a Ti atom coordinated by O"2"- ions, in which the electrons are distributed away from the negative O"2"- ions. It is concluded that the electron ...
2005-08-01
An adaptive filter to approximate the Bayesian strategy for sonographic beamforming.
A first-principles task-based approach to the design of medical ultrasonic imaging systems for breast lesion discrimination is described. This study explores a new approximation to the ideal Bayesian observer strategy that allows for object heterogeneity. The new method, called iterative Wiener filtering, is implemented using echo data simulations and a phantom study. We studied five lesion features closely associated with visual discrimination for clinical diagnosis. A series of human observer measurements for the same image data allowed us to quantitatively compare alternative beamforming strategies through measurements of visual discrimination efficiency. Employing the Smith-Wagner model observer, we were able to breakdown efficiency estimates and identify the processing stage at which performance losses occur. The methods were implemented using a commercial scanner and a cyst phantom to explore development of spatial ...
2010-07-19
International Nuclear Information System (INIS)
The molar heat capacities of chloroform, dichloromethane, methanol, acetonitrile, acetone, dimethyl sulfoxide, benzene, dimethylformamide, toluene, and cyclohexane, as well as their deuterated isotopologues, were measured using a multi-channel heat conduction TAM (Thermal Activity Monitor) III microcalorimeter. In addition, the apparent molar heat capacities of some of the associated dilute aqueous solutions (0.0039 i < 0.0210) were also measured. A temperature drop method from (298.15 to 297.15) K at 0.1 MPa was employed. The corresponding heat capacities were determined from the integration of the measured heat flow. The heat capacity results are shown to be in good to very good agreement with the available literature values. In addition, good correlations were obtained for the effect of isotopic substitution on both molar heat capacity and apparent molar heat ...
2008-11-01
New sets of cross sections for the production of krypton isotopes from targets of Rb, Sr, Y, and Zr were constructed primarily on the bases of experimental excitation functions for Kr production from Y. These cross sections were used to calculate galactic-cosmic-ray and solar-proton production rates for Kr isotopes in the moon. Spallation Kr data obtained from ilmenite separates of rocks 10017 and 10047 are reported. Production rates and isotopic ratios for cosmogenic Kr observed in ten well-documented lunar samples and in ilmenite separates and bulk samples from several lunar rocks with long but unknown irradiation histories were compared with predicted rates and ratios. The agreements were generally quite good. Erosion of rock surfaces affected rates or ratios for only near-surface samples, where solar-proton production is important. There were considerable spreads in predicted-to-observed production rates of /sup 83/Kr, ...
1979-01-01
Energy Technology Data Exchange (ETDEWEB)
The present study includes thermal stability of some fatty acids as phase change materials (PCMs). The selected fatty acids were stearic, palmitic, myristic and lauric acid with melting temperatures between 40-63{sup o}C and industrial-grade with 90-95% purity. Latent heat storage capacity and phase transition temperature of the PCMs were determined by Differential Scanning Calorimetry (DSC) technique as a function of after repeated thermal cycles such as 40, 410, 700 and 910. The present work also comprises the investigation of corrosion resistance of some construction materials to the fatty acids over a long period. The containment materials tested were stainless steel (SS 304 L), carbon steel (steel C20), aluminium (Al) and copper (Cu). Gravimetric analysis as mass loss (mg/cm{sup 2}), corrosion rate (mg/day) and a microscopic or metallographic investigation were performed for corrosion tests after 910 thermal cycles. DSC measurements showed ...
2003-05-01
On the cells of origin of radiogenic thyroid cancer: New studies based on an old idea
Energy Technology Data Exchange (ETDEWEB)
We have presented evidence that the functional thyroid follicles (follicular units, FU) which are formed in grafts of monodispersed rat thyroid cells, and hence the thyroid tumors which later develop in such grafts, are clonal in origin. Recent studies have been designed to investigate: whether cell number-dependent inhibition of promotion-progression is mediated by remote hormonal feed-back, local cell-cell interactions, or both; the cell population kinetics of the clonogen subpopulation during goitrogenesis and goiter involution; and the effect of prolonged exposure to high levels of TSH (thyrotropin) on the capacity of the clonogens to give rise to functional FU. The results indicate that local cell-cell interactions play an important role in the cell number-dependent suppression of neoplastic promotion-progression. They also show that if sufficient thyroid cells are grafted, the thyroid-pituitary axis can be ...
1990-01-01
Liquid Water from First Principles: Validation of Different Sampling Approaches
Energy Technology Data Exchange (ETDEWEB)
A series of first principles molecular dynamics and Monte Carlo simulations were carried out for liquid water to assess the validity and reproducibility of different sampling approaches. These simulations include Car-Parrinello molecular dynamics simulations using the program CPMD with different values of the fictitious electron mass in the microcanonical and canonical ensembles, Born-Oppenheimer molecular dynamics using the programs CPMD and CP2K in the microcanonical ensemble, and Metropolis Monte Carlo using CP2K in the canonical ensemble. With the exception of one simulation for 128 water molecules, all other simulations were carried out for systems consisting of 64 molecules. It is found that the structural and thermodynamic properties of these simulations are in excellent agreement with each other as long as adiabatic sampling is maintained in the Car-Parrinello molecular dynamics simulations either by choosing a sufficiently small fictitious mass in the microcanonical ensemble ...
2004-05-20
Energy Technology Data Exchange (ETDEWEB)
Inverter introduced in this paper is intended for use in medium-capacity photovoltaic power generation systems designed for industries in general. Interconnection is carried out at a low-voltage 210V point receiving from a commercial 3 phase-3 cable 6.6kV high voltage incoming panel. So as to ensure stable extraction of power in the maximum degree from a photovoltaic power generation system that is naturally unstable, this inverter monitors voltage and power, and behaves in a fully automated way. A maximum power point tracking (MPPT) control function is provided, which measures the power level at the current operating voltage point A, changes the operating voltage to a voltage value B which is lower than the point A voltage by 3V and to a voltage value C which is higher than the point A voltage by 3V, and measures the power level at each point. Comparison is then made between the values measured at the said points on a PV profile, and the ...
1997-10-30
The effect of exercise training prior to acute myocardial infarction (AMI) on left ventricular (LV) remodeling is poorly understood. This study investigated the protective effect of 3 weeks of swimming exercise training prior to AMI on cardiac morphology and function. Male Sprague-Dawley rats (n = 35) were randomly assigned to 3 groups: swimming training (n = 14, 90 min, 5 days/wk, 3 wk), sedentary (n =14), and controls (n = 7, no exercise, no MI). At the end of the training/sedentary period, rats were subjected to AMI (ExMI and SedMI) induced by surgical ligation of the left coronary artery. Thereafter, the rats remained sedentary for a 4-wk recovery period. Trans-thoracic echocardiography was performed in each group at the end of the exercise/sedentary period (pre-AMI), 24 hr after AMI, and following recovery (4 wk after AMI). No differences were observed in LV dimensions and function pre-AMI among the 3 groups; however, ...
2005-01-01
International Nuclear Information System (INIS)
The International Atomic Energy Agency has initiated a co-ordinated research programme on implementation of base-isolation for nuclear structures. This paper discusses two areas relevant to modelling elastomeric base-isolators. These are the use of simplified models to predict the response of isolated structures to earthquake inputs and finite element analysis for calculating the stress distributions within the isolators. In the former, a curvilinear hysteretic model of the high damping natural rubber able to accommodate the stiffening of the rubber at large shear deflections is presented. Its predictions of structural accelerations and bearing displacement produced by design earthquakes and those above the design level are compared with those using a linear spring and dashpot model. A comparison has been made between two finite element analyses using MARC and ABAQUS of the force-deformation behaviour of a single disc of rubber bonded on both sides. The disc was loaded both in ...
1996-05-27
Surge Capacity for Response to Bioterrorism in Hospital Clinical Microbiology Laboratories
UK PubMed Central (United Kingdom)
Surge capacity is the ability to rapidly mobilize to meet an increased demand. While large amounts of federal funding have been allocated to public health laboratories, little federal funding has been...Full Text Available
2003-12-01
Superior energy capacity of graphene nanosheets for a nonaqueous lithium-oxygen battery.
Graphene nanosheets (GNSs) were synthesized and used as cathode active materials in a nonaqueous lithium-oxygen battery. The GNSs electrode delivered an extremely high discharge capacity in comparison to carbon powders, which is attributed to its unique morphology and structure. PMID:21779551
2011-07-21
Sexual Dimorphism in Primate Aerobic Capacity: A Phylogenetic Test
UK PubMed Central (United Kingdom)
Male intrasexual competition should favour increased male physical prowess. This should in turn result in greater aerobic capacity in males than in females (i.e., sexual dimorphism), and a correlation...Full Text Available
2010-06-01
Only Slight Impact of Predicted Replicative Capacity for Therapy Response Prediction
UK PubMed Central (United Kingdom)
BackgroundReplication capacity (RC) of specific HIV isolates is occasionally blamed for unexpected treatment responses. However, the role of viral RC in response to antiretroviral...Full Text Available
UK PubMed Central (United Kingdom)
Isometric/isokinetic muscle strength and isokinetic endurance of the lower extremities as well as aerobic capacity were evaluated in 67 patients (43 female, 24 male; mean age 53 years, range 23-65)...Full Text Available
1992-01-01
Maximum capacity of steam turbine units
International Nuclear Information System (INIS)
The author investigates the question of the maximum capacity of steam turbines in nuclear power plants when towards the end of the nineties turbo-generator units of 3,000 MW and more will be necessary as a result of increased energy demand. (TK).
Global Soil Water Holding Capacity Dataset from UNEP ... - GCMD - NASA
Global Soil Water Holding Capacity Dataset from UNEP/GRID. Entry ID: GNV0025 ... Dao at unep.org. Contact Address: Head of Metadata & Socio-Economics Unit ...
UK PubMed Central (United Kingdom)
AIMS:This study aimed to determine the effect of 50 days of forced swimming stress on fertilization capacity of rat and subsequent offspring quality.SETTING...Full Text Available
2010-01-01
Energy Technology Data Exchange (ETDEWEB)
The experimental has been performed with a view to studying complete and incomplete fusion in {sup 14}N + {sup 163}D{sub y} system below 7 MeV/nucleon. The excitation functions for several reactions have been measured using the activation technique and compared with the theoretical predictions based on statistical models. The codes ALICE-91 and CASCADE used earlier for the analysis of excitation functions in case of {sup 12}C + {sup 165}H{sub 0} system have been used here also with the same set of input parameters. It has been observed that the theoretical calculations do not match with the experimental excitation functions well but the overall shape of the excitation function is reproduced satisfactorily. The composite nucleus ({sup 177}T{sub a}) formed in this ({sup 14}N + {sup 163}D{sub y}) case is the same as the one formed in {sup 12}C + {sup 165}H{sub 0} system studied ...
2002-10-01
This paper explores how an aid-funded Ph.D.-programme in mathematics education instituted in some Southern African Development Community countries measures up to issues related to research capacity development projects. The research capacity development programme is described and reflected against mutual benefit, relevance, sustainability and prioritization of the location of project funding expenditure--some of the constructs in the discourse on research capacity development initiatives. It is found that the benefits of the programme are indeed mutual; the outcomes regarding relevance and sustainability are more uncertain and the location of expenditure of the funding is not overtly in favour of the donor country.
2005-11-01
Abstracts by Mission Directorate - NASA
A new high capacity anode composite based on mesoporous silicon is proposed. By virtue of a structure that resembles a pseudo one-dimensional phase, ...
Silicon nanopowder as active material for hybrid electrodes of lithium-ion batteries
British Library Electronic Table of Contents (United Kingdom)
Cycling parameters (reversible specific capacity, first-cycle coulombic efficiency, accumulated irreversible capacity, and reversible capacity retention) of hybrid electrodes based on mechanical mixtures of a silicon nanopowder with KS6 and MAG-20 synthetic graphites and binders of varied nature were subjected to an integrated analysis in comparison with graphite electrodes.
2011-01-01
Effects of human serum on bacterial competition with neutrophils for molecular oxygen.
A dialyzable factor(s) in human serum is known to stimulate gonococcal oxygen consumption. Its effect on other human pathogens was investigated. A 10% serum solution increased peak O2 consumption for Escherichia coli and Staphylococcus aureus to 157% (P less than 0.05) and 199% (P less than 0.02), respectively, of their O2 consumption when suspended in Hanks balanced salt solution, compared with a 356% increase for Neisseria gonorrhoeae with serum. Dialyzed serum lacked stimulatory capacity. Bacteria, serum, and neutrophils are often incubated to evaluate neutrophil bactericidal activity. Samples of 10(8) N. gonorrhoeae, S. aureus, and E. coli turned resazurin colorless (anaerobic conditions, Eh less than -42 mV) after 7.4, 13.3, and 15.1 min, respectively. Because neutrophil formation of reactive oxygen intermediates requires ambient O2, the effect of live bacteria and serum on this process was explored. After 5 min of incubation of 10(8) N. gonorrhoeae or S. ...
1986-06-01
Asymptotic functions and multiplication of distributions
International Nuclear Information System (INIS)
Considered is a new type of generalized asymptotic functions, which are not functionals on some space of test functions as the Schwartz distributions. The definition of the generalized asymptotic functions is given. It is pointed out that in future the particular asymptotic functions will be used for solving some topics of quantum mechanics and quantum theory.
1976-01-26
Simulation of natural convection cooling phenomena for research reactors using the code PARET
International Nuclear Information System (INIS)
This study deals with testing the capacity of the code PARET to simulate natural circulation phenomena under different boundary conditions in addition to assessment of some new options related to simulation of control rod movement and the reactivity effect of thermal expansion fuel elements. the experiments of the simple thermal hydraulic loop of Missouri University about natural circulation phenomena in narrow parallel channel were used to validate the code. The results indicate good agreements regarding the evolution of coolant velocity and clad temperature. In particular the heat transfer coefficient of natural convection has been calculated in good agreement with the experiment. On the other hand, the core of MNSR reactor has been modelled to stimulate the reactor dynamic behaviour under natural circulation condition for different initial power level. The observed oscillations during the initial phase vanish gradually with passing time. In ...
Energy Technology Data Exchange (ETDEWEB)
The objective of this project is to develop a pellet formulation which is capable of achieving low sulfur partial pressures and a high capacity for sulfur, loaded from a hot fuel gas and which is readily regenerable. Furthermore the pellet must be strong for potential use in a fluidized bed and regenerable over many cycles of loading and regeneration. Regeneration should be in air or oxygen-depleted air to produce a high-concentration sulfur dioxide. Fixed-bed tests were conducted with several formulations of manganese sesquioxide and titania, and alumina They were subject to a simplified fuel gas of the oxygen-blown Shell type spiked with a 30,000ppmv concentration of H{sub 2}S. Pellet crush strengths for 4 and 2mm diameter pellets was typically 12 lbs per pellet and 4 lbs per pellet, respectively. For the most favorable of the formulations tested and under the criteria of break-through at less than 100ppmv H2S and loading temperatures of 500{degrees}C and an ...
1996-06-12
Isocapnic hyperventilation with cold air (IHCA) is a reliable technique for assessing indirect bronchial hyperresponsiveness in patients with asthma. Impedance measurement of the respiratory system by the forced pseudorandom noise oscillation technique is a sensitive technique to assess changes in bronchial tone after IHCA. The aim of this study was to evaluate the effect of 6 weeks of treatment with beclomethasone dipropionate, 1,000 microg x day-1, on IHCA in asthmatic patients, measured with both forced oscillation technique and flow-volume recordings. Forty patients with mild asthma were included in this double-blind, placebo-controlled parallel-group study. Stratification on the basis of sex was performed to overcome differences in airway diameter. At entry and every 2 weeks during the treatment period, IHCA was performed and patient diaries were evaluated. Characteristic changes in forced oscillation parameters after IHCA were observed in all patients. After ...
1997-03-01
A high-sensitivity small animal SPECT system
International Nuclear Information System (INIS)
Medical imaging using single gamma-ray-emitting radionuclides typically makes use of parallel hole collimators or pinholes in order to achieve good spatial resolution. However, a tradeoff in sensitivity is inherent in the use of a collimator, and modern preclinical single photon emission computed tomography (SPECT) systems detect a very small fraction of emitted gamma rays, often less than 0.1%. A system for small animal SPECT imaging which uses no collimators could potentially achieve very high sensitivity-several tens of percent-with reasonably sized detectors. This would allow two significant improvements in preclinical studies: images could be obtained more rapidly, allowing higher throughput for screening applications, or for dynamic processes to be observed with very good time resolution; and images could be obtained with less radioactive tracer, making possible the in vivo imaging of low-capacity receptor systems, aiding research into ...
2009-03-07
International Nuclear Information System (INIS)
In the report the results of the estimations of radiological risk of various stages of decommissioning of nuclear submarines are presented. At occurrence on nuclear submarine the heavy failure, relating to the class hypotetical volume of acting of radionuclides in atmosphere can reach 1.6E(15) Bq. Results of estimations probable doses on an axis of a trace of a radioactive loop show, that at distribution of radionuclides during atmospheric carry to 'agreed' settlement (500-1000 m) the maximum doses on its territory can make: about 6.0E(-3) Sv (for the whole body); 3.0E(-3) Gy for the leather (basal layer); 6.3E(-2) Gy for the lungs (acute exposure) and up to 1.8 Gy for the thyroid gland. Hypotetical failure for the estimation of the greatest possible radioecological consequences for hydrobiocenosis is considering, connected with single discharge of liquid radioactive waste (LRW) in water area. At navigating failure of the tanker with LRW in water area can arrive 300 M3 of LRW with the ...
2000-05-01
The three-point function as a probe of models for large-scale structure
Energy Technology Data Exchange (ETDEWEB)
The authors analyze the consequences of models of structure formation for higher-order (n-point) galaxy correlation functions in the mildly non-linear regime. Several variations of the standard {Omega} = 1 cold dark matter model with scale-invariant primordial perturbations have recently been introduced to obtain more power on large scales, R{sub p} {approximately}20 h{sup {minus}1} Mpc, e.g., low-matter-density (non-zero cosmological constant) models, {open_quote}tilted{close_quote} primordial spectra, and scenarios with a mixture of cold and hot dark matter. They also include models with an effective scale-dependent bias, such as the cooperative galaxy formation scenario of Bower, et al. The authors show that higher-order (n-point) galaxy correlation functions can provide a useful test of such models and can discriminate between models with true large-scale power in the density field and those where the galaxy power arises from ...
1993-06-19
Energy Technology Data Exchange (ETDEWEB)
ABSTRACT-Here we identify release of annexin A2 into the culture medium in response to low dose X-ray radiation exposure and establish functional linkages to an established paracrine factor-mediated anchorage-independent growth response. Using a standard bicameral coculture model, we observe that annexin A2 levels associated with non-irradiated neighboring cells seeded in the lower chamber (annexin A2 silenced [shRNA] JB6 cells) are increased upon coculture with irradiated (10-50 cGy) JB6 cells seeded in the upper chamber, relative to coculture with sham exposed JB6 cells seeded in the upper chamber, suggesting that annexin A2 released into the medium is capable of communicating in a paracrine fashion. Using a previously established coculture model, we observed that the paracrine factor-mediated anchorage-independent growth response to low dose X-ray radiation is markedly reduced when irradiated annexin A2 silenced (shRNA) ...
2009-07-13
International Nuclear Information System (INIS)
Full text: As you know, thin films which generate anomalous big photovoltage (APhV) , as film photo resistive structures made of the combinations of A_2B_6 respond to X-ray and #gamma#- radiations. In this work the influence of X-ray and #gamma#-radiations on the quantity of APhV in the system APhV-film-photoresistor was investigated. Earlier polycrystal films with anomalous photo voltage properties were received only on the clean and flat surface with high isolation property (R>10"1"4 #OMEGA#). We worked out the technology of receiving APhV films CdTe on the surface of the photosensitive film CdS. The main condition under which this effect may be observed is that the lining must be slant concerning to the direction of the motion of evaporated substance's molecular bunch during the growing of the film, i.e. received film must have a dendritic structure. That is why photosensitive film CdS was received with thermo vacuum slanting pulverization (#alpha#=30-60 ...
2004-08-23
The static indentation behavior of composite sandwich panels with thin quasi-isotropic skins
The quasi-static normal indentation of sandwich panels with quasi-isotropic laminated composite skins and honeycomb or foam cores, by spherical indentors, has been investigated using experiments and finite element analysis. The experimental program emphasized the effects of indentor size on the resulting load indentation responses, failure mechanisms in the skin and the core, and the measurement of contact areas between indentor and the target. The sandwich panels were indented up to the initiation of skin fracture and the resulting contact data was used to characterize contact power laws. A non-linear finite element model was developed based on the experimental observations to systematically explore the indentation behavior of diverse sandwich configurations and to investigate the contact pressure distributions. The finite element model was used as an experimental tool in the development of a simple non-dimensional semi-empirical model that was based on the ...
2001-01-01
DISSIPATION AND EXTRA LIGHT IN GALACTIC NUCLEI. II. 'CUSP' ELLIPTICALS
International Nuclear Information System (INIS)
We study the origin and properties of 'extra' or 'excess' central light in the surface brightness profiles of cusp or power-law elliptical galaxies. Dissipational mergers give rise to two-component profiles: an outer profile established by violent relaxation acting on stars already present in the progenitor galaxies prior to the final stages of the merger, and an inner stellar population comprising the extra light, formed in a compact central starburst. By combining a large set of hydrodynamical simulations with data that span a broad range of profiles at various masses, we show that observed cusp ellipticals appear consistent with the predicted 'extra light' structure, and we use our simulations to motivate a two-component description of the observations that allows us to examine how the properties and mass of this component scale with, e.g., the mass, gas content, and other properties of the galaxies. We show how to robustly separate the ...
2009-03-01
Lithium intercalation in porous carbon electrodes
Energy Technology Data Exchange (ETDEWEB)
Carbons derived from the phase separation of polyacrylonitrile/solvent mixtures were investigated as lithium intercalation anodes for rechargeable lithium-ion batteries. The carbon electrodes have a bulk density of 0.35-0.5 g/cm{sup 3}, relatively low surface areas (< 10 m{sup 2}/g), and micron-size cells. Pyrolysis temperature influences the reversible lithium intercalation and the irreversible capacity (associated with the formation of the passivating layer). Carbon electrodes pyrolyzed at 600{degrees}C have first-cycle capacity as high as 550 mAh/g as well as large irreversible capacity, 440 mAh/g. Electrodes prepared at 1050{degrees}C have reversible capacities around 270 mAh/g with relatively lower capacity losses (120 mAh/g). Doping the organic precursors with phosphoric acid, prior to pyrolysis at 1050{degrees}C, leads to carbon electrodes with reversible ...
1995-04-01
Energy Technology Data Exchange (ETDEWEB)
This paper describes effects of methods to calculate and analyze bearing capacities and transformation of pile foundations in the limit state design method. Different pile bearing capacity estimating expressions including criteria used in other countries were applied to the case of steel piles driven into the `diatomaceous mudstone ground` in Noto Peninsula, Ishikawa Prefecture where detailed ground and soil surveys have been made, and the case of piles driven in place into the `sandy and clayish soil alternating ground layers` at the Tennoji area in Osaka Prefecture. The results were compared with those of static loading tests. As a result, the estimated bearing capacity limit was found to agree relatively well with the measured values where uniaxial compression strength was used according to the reference architectural formula. The estimated bearing capacity limit using the N-value as the soil ...
1994-09-01
Carbon nanotube coating silicon doped with Cr as a high capacity anode
Energy Technology Data Exchange (ETDEWEB)
Effects of dopant and coating carbon nanotube on anodic performance of Si were studied for metallic anode Li ion rechargeable battery with large capacity. Although the large Li intercalation capacity higher than 1500mAhg{sup -1} is exhibited on pure Si, it decreased drastically with increasing cycle number. Increasing the electrical conductivity by doping Cr or B is effective for increasing the initial capacity and the cycle stability of Si for Li intercalation. Coating semiconductive Si with the carbon nanotube by decomposition of hydrocarbon is effective for increasing the cycle stability, though the initial Li intercalation capacity slightly decreased. Conducting binder is also important for increasing the cycle stability and it was found that Li intercalation capacity higher than 1500mAhg{sup -1} can be sustained by using poly vinyliden fruolide. Consequently, reversible Li ...
2005-08-26
Water diffusion profile measurements in epoxy using neutron radiography
International Nuclear Information System (INIS)
The diffusion characteristics of water in polymer materials have been studied for a few decades. Several methods have been developed to provide water diffusion characteristics as a function of time, temperature, pressure, or thickness of polymer. Unfortunately, most of these methods give the amount of water absorbed as a function of weight versus time at given environmental conditions. Concentration profiles of the water diffusion through the polymer have been unobtainable by these established methods. Neutron radiography is a method of non-destructive testing that has grown rapidly over the past ten years and is capable of giving these concentration profiles. Epoxy is one of the most commonly used polymers for which water diffusion information is important. In the automotive industry, epoxy is used both as a sealant and a bonder to prevent water from getting inside structures and causing corrosion. To prevent this corrosion, it is important to ...
Regulation of NMDA and AMPA receptors during the maturation phase of chicken brain development
International Nuclear Information System (INIS)
Full text: The maturation of chicken forebrain is protracted and occurs well after synapse formation providing a good model for studying mechanisms of brain maturation. Using microslices from immature (10 day) and adult chicken forebrain prepared after decapitation, we have examined functional properties of NMDA and AMPA receptors by measuring agonist-induced uptake of "4"5Ca"2"+ . The rate and extent of NMDA induced "4"5Ca"2"+ accumulation decreased during maturation with no change in EC_5_0. The rate and extent of the AMPA induced response also decreased with a 60-fold increase in EC_5_0. However, the total NMDA receptor content did not change as indicated by 3 H-MK801 binding and NR1 immunoreactivity in P2 fractions. Similarly, there was no change in the B_m_a_x of "3H-AMPA, though there was a two-fold increase in K_D, and little or no change in the immunoreactivity in GluR1, 2, 2/3 or 4. These results suggest that it is the regulation of receptors, their ...
2002-02-04
The delayed detonation model describes the observational properties of the majority of type Ia supernovae very well. Using numerical data from a three-dimensional deflagration model for type Ia supernovae, the intermittency of the turbulent velocity field and its implications on the probability of a deflagration-to-detonation (DDT) transition are investigated. From structure functions of the turbulent velocity fluctuations, we determine intermittency parameters based on the log-normal and the log-Poisson models. On the other hand, the analysis of the turbulent velocity fluctuations in the vicinity of the flame front by Roepke suggests a much higher probability of large velocity fluctuations on the grid scale in comparison to the log-normal intermittency model. Following Pan et al., we computed probability density functions for a DDT for the different distributions. Assuming that a DDT can occur in the stirred flame regime, ...
2009-01-01
Toxic effects of lead on neuronal development and function
Energy Technology Data Exchange (ETDEWEB)
The effects of lead on the development of the nervous system are of immediate concern to human health. While it is clear that lead can affect neuronal development at levels of exposure within the range found in the environment, the particular mechanism of the disruption is not readily ascertained. The goal of the authors research is to develop a model system in which the effects of lead on central nervous system development can be demonstrated. To study neuronal development in a system that minimizes such difficulties, the authors have grafted discrete brain regions derived from rat fetuses into the anterior chamber of the eye of adult hosts. The brain pieces continue organotypic development in the eye, but are isolated from possible secondary changes due to alterations in the development of the endocrine and other somatic systems because the adult host has these systems already fully developed. Using this system, they have discovered that lead induces a hypernoradrenergic innervation ...
1990-11-01
We develop a 3-D model to simulate the synthetic aperture radar (SAR) image formation process of an undulated vegetation canopy such as corn grown in fields with large periodic drainage reliefs. We explain how the simulated SAR image of undulated vegetation medium is obtained by the convolution of a 2-D slice of the 3-D simulated SAR system point spread function [(PSF), emulating the SAR beam modeled by a cosine modulated Gaussian], with the 2-D projection of the observed undulated vegetation canopy (modeled with scatterers randomly distributed in 3-D undulated space) followed by the extraction of each look envelope, the summation of looks, and sampling in azimuthal and range directions. Our model is useful to study the parameters involved in the formation and the analysis of SAR images of undulated vegetation medium. Validation of simulations made with actual SAR images shows that undulated corn crop canopies are well characterized by the mean ...
2001-10-01
Studies on radiation induced changes in bovine hemoglobin type A
International Nuclear Information System (INIS)
In this paper the structural and functional changes of gamma irradiated bovine hemoglobin are presented. Aqueous solutions/1%/of HbO_2 were irradiated in air with doses ranging from 1 to 4 Mrad. Isoelectric focusing indicated change of the charge of irradiated hemoglobin. The isoelectric point of hemoglobin was displaced towards more acid values with increasing doses, up from 1 Mrad. Fingerprint analysis and peptide column chromatography of irradiated hemoglobin demonstrated disturbances increasing with the dose. These changes were confirmed by amino acid analysis which showed that Cys, Met, Trp, His, Pro and Tyr residues were destroyed or modified following irradiation. At doses exceeding 1 Mrad the irradiated solutions of hemoglobin showed a decrease of heme-heme interaction and an increase of affinity for oxygen. Differences observed in oxygen-dissociation curves seem to be correlated with the radiation induced destruction of amino acid ...
Energy Technology Data Exchange (ETDEWEB)
Pretreatment of brown coal in oil was conducted using 1-methyl naphthalene or mixture of tetralin and 1-methyl naphthalene as solvent at temperatures ranging from 300 to 430{degree}C under nitrogen atmosphere. Effects of the solvent properties on the structural change of oxygen-functional groups (OFG) and coal liquefaction were investigated by means of quantitative analysis of OFG and solid state {sup 13}C-NMR measurement. When hydrogen transfer from solvent was insufficient, it was suggested that brown coal molecules loose their hydrogen to be aromatized. While, at lower temperatures ranging from 300 to 350{degree}C, hydrogen contained in brown coal molecules was consumed for the stabilization of pyrolytic radicals, and the deterioration of liquefaction was not observed. When hydrogen transfer from solvent was insufficient at higher temperatures above 400{degree}C in nitrogen atmosphere during pretreatment in oil, crosslinking like benzofuran ...
1996-10-28
Sol-gel coatings with phosphonate functionalities for surface modification of magnesium alloys
International Nuclear Information System (INIS)
Hybrid organic-inorganic coatings with phosphonate functionalities have been synthesized and evaluated as prospective surface treatments for magnesium materials. These coatings have been processed via a sol-gel route by hydrolysis and condensation of a mixture of diethylphosphonatoethyltriethoxy-silane and tetraethoxy-silane with variable molar ratios. The coatings morphology and the surface chemistry at the coating/substrate interface have been characterized using scanning electron microscopy, X-ray photoelectron spectroscopy, "3"1P nuclear magnetic resonance spectroscopy, and time-of-flight secondary ion mass spectrometry. The corrosion protection performance of the coatings deposited on magnesium alloy AZ31B has been examined by a group of electrochemical techniques including potentiodynamic polarization and electrochemical impedance spectroscopy. In addition, a scanning Kelvin probe technique has been used to investigate interfacial properties of the coatings. ...
2006-08-30
Separation of Minor Actinides and Lanthanides with Carbon Nano-materials
Energy Technology Data Exchange (ETDEWEB)
Recently we have found that carbon nano-materials have ability to recognize softer actinides(III). In this presentation, separation of americium(III) from lanthanides(III) by chromatography with carbon nano-materials, such as carbon nano-tubes and graphite, has been investigated by batch adsorption experiments and chromatography. The separation factor (SF) between americium(III) and lanthanide(III) was about 2 in the range of pH from 1 to 4 by using carbon nano-tube, graphite and activated charcoal. The separation factor depended on the diameter of carbon nano-tubes. Smaller one, 3-20 nm diameter, showed the best selectivity for americium(III), which separation factor was about 2.0, although larger one, 40-70 nm, showed almost no selectivity. The same behavior has been observed by using graphite powder and activated charcoal although acid- or alkali pretreated activated charcoal which generally has acidic functional group on the edge of carbon ...
2009-06-15
Properties of superconducting Cu-rich composites containing V_3Si or V_3Ga
International Nuclear Information System (INIS)
Superconducting Cu-rich composites containing the A-15 compounds V_3Si or V_3Ga were made by the ''Tsuei'' process (melting into ingots followed by cold working and heat treatment). Superconducting transition temperatures of the composites were measured. X-ray diffraction analyses were performed. Microstructures were studied using both the optical metallograph and the scanning electron microscope. For some composites containing V_3Ga, the critical current densities as functions of transverse magnetic field up to 60 kG, and as functions of temperature from 4.2 to 12"0K were measured. It was found that the Tsuei process does not work for the composites containing V_3Si, but works satisfactorily for V_3Ga; reasons are discussed. Relations between measured properties and various metallurgical factors such as alloy compositions, cross-section reduction ratios, and heat treatment are discussed. The mechanism for the observed ...
Molecular studies of the uncoupling protein
Energy Technology Data Exchange (ETDEWEB)
The uncoupling protein (UCP) is a proton/anion transporter found in the inner mitochondrial membrane of brown adipocyte. Although UCP has nor been detected in mitochondria from any other tissue, it shares structural and catalytic properties with several other mitochondrial carrier proteins. Although UCP was discovered only recently it is one of the most extensively studied mitochondrial carrier proteins.More recently, the mouse, rat, and human genes encoding for UCP have been isolated and sequenced. The availability of these various tools has led to several significant observations. UCP gene expression is strongly controlled at the level of transcription by signals that are activated after the stimulation of brown adipocytes by norepinephrine. The comparison of UCP gene with the genes encoding the adenine nucleotide translocator revealed the existence of structural and evolutionary homologies. Moreover, in humans the UCP gene and one form of adenine nucleotide ...
1991-06-01
Modelling 18O2 and 16O2 unidirectional fluxes in plants: I. Regulation of pre-industrial atmosphere
British Library Electronic Table of Contents (United Kingdom)
In closed systems, the O2 compensation point (?O) was previously defined as the upper limit of O2 level, at a given CO2 level, above which plants cannot have positive carbon balance and survive. Studies with 18O2 measure the actual O2 uptake by photorespiration due to the dual function of Rubisco, the enzyme that fixes CO2 and takes O2 as an alternative substrate. One-step modelling of CO2 and O2 uptakes allows calculating a plant specificity factor (Sp) as the sum of the biochemical specificity of Rubisco and a biophysical specificity, function of the resistance to CO2 transfer from the atmosphere to Rubisco. The crossing points (Cx, Ox) are defined as CO2 and O2 concentrations for which O2 and CO2 uptakes are equal. It is observed that: (1) under the preindustrial atmosphere, photorespir...
2011-01-01
Modeling the Galactic CV Distribution for the ChaMPlane Survey
For purposes of designing targeted cataclysmic variable (CV) detection surveys and interpreting results of other projects with many CV detections such as the ChaMPlane Survey, we have created a model of the CV distribution in the Galaxy. It is modeled as a warped, flared exponential disk with a gaussian vertical distribution. Extinction is based on a detailed Galactic dust and gas model. A luminosity function for CVs is also incorporated, based on a smoothed version of published data. We calculate predicted field detection rates as a function of the limiting magnitude expected for the detecting system (i.e. WIYN/Hydra or NOAO 4m/Mosaic). Monte-Carlo techniques are used to assess statistical fluctuations in these rates. We have created maps of the expected CV distribution for the full non-bulge Galactic plane (20 2007-01-01
Measurement and analysis of alpha particle induced reactions on praseodymium
International Nuclear Information System (INIS)
Excitation functions (EFs) for the reaction "1"4"1Pr(#alpha#, n)"1"4"4Pm and "1"4"1Pr(#alpha#, 2n)"1"4"3Pm have been measured using "1"4"1Pr as a target up to 50 MeV #alpha#-particle energy. Stacked foil activation technique and #gamma#-ray spectroscopy using 100 cm"3 Ge (Li) detector, has been used. Excitation functions are also calculated theoretically using Blann's geometry dependent hybrid (GDH) model code ALICE-91, with and without inclusion of pre-equilibrium particle emission. It has been observed that high-energy tails of the EFs are dominated by pre-equilibrium reaction mechanism. With the accepted set of input parameter, initial exciton number n_0=4 (2p + 2n + 0h), a good qualitative agreement is found. However, quantitative agreement for this magic nucleus"1"4"1Pr is also good when theoretical calculations are normalized by a multiple factor of 0.5. (author)
2005-04-01
MTF analysis of the MURR real-time neutron radiography facility
International Nuclear Information System (INIS)
In neutron radiography, as in other forms of NDE, it is sometimes desirable to observe dynamic events. This need has generated increased interest in real-time neutron radiography systems. As in other forms of radiography, a standard method for measuring the image forming capability of real-time systems is necessary in order to compare the various methods and systems used. A technique which has been used extensively in general photography and has been applied in the characterization of several screen-film combinations used in conventional neutron radiography is to determine the imaging system's modulation transfer function (MTF). This gives a graphical representation of the system's spatial resolution capabilities and was therefore chosen as the method for evaluation of the real-time neutron radiography facility at the University of Missouri Research Reactor (MURR). The method used was to image a knife-edge, differentiate the edge gradient to ...
1982-04-01
Expression of fully functional tetrameric human hemoglobin in Escherichia coli
International Nuclear Information System (INIS)
Synthesis genes encoding the human #alpha#- and #beta#-globin polypeptides have been expressed from a single operon in Escherichia coli. The #alpha#- and #beta#-globin polypeptides associate into soluble tetramers, incorporate heme, and accumulate to >5% of the total cellular protein. Purified recombinant hemoglobin has the correct stoichiometry of #alpha#- and #beta#-globin chains and contains a full complement of heme. Each globin chain also contains an additional methionine as an extension to the amino terminus. The recombinant hemoglobin has a C_4 reversed-phase HPLC profile essentially identical to that of human hemoglobin A_0 and comigrates with hemoglobin A_0 on SDS/PAGE. The visible spectrum and oxygen affinity are similar to that of native human hemoglobin A_0. The authors have also expressed the #alpha#- and #beta#-globin genes separately and found that the expression of the #alpha#-globin gene alone results in a marked decrease in the accumulation of #alpha#-globin in the ...
Enhanced photoconductivity and fine response tuning in nanostructured porous silicon microcavities
Energy Technology Data Exchange (ETDEWEB)
We used light confinement in optical microcavities to achieve a strong enhancement and a precise wavelength tunability of the electrical photoconductance of nanostructured porous silicon (PS). The devices consist of a periodic array of alternating PS layers, electrochemically etched to have high and low porosities - and therefore distinct dielectric functions. A central layer having a doubled thickness breaks up the symmetry of the one-dimensional photonic structure, producing a resonance in the photonic band gap that is clearly observed in the reflectance spectrum. The devices were transferred to a glass coated with a transparent SnO{sub 2} electrode, while an Al contact was evaporated on its back side. The electrical conductance was measured as a function of the photon energy. A strong enhancement of the conductance is obtained in a narrow (17nm FWHM) band peaking at the resonance. We present experimental results of the ...
2009-05-01
Dependence of proton beam polarization on ion source transition configurations
Energy Technology Data Exchange (ETDEWEB)
The polarization of extracted SATURNE II proton beam as a function of different ion source configurations was studied. Two distinct experiments were necessary for this purpose. In the first one, the left-right instrumental asymmetry of the beam polarimeter was determined using an unpolarized beam. In the second one this correction factor was applied to asymmetries measured with the beam from the polarized ion source in all polarization states. The measurements were carried out at the proton beam kinetic energy 0.80 GeV, where the pp-elastic scattering analyzing power is near its maximum. The results confirmed that the two so-called ``unpolarized states`` of the source were polarized to several percent, whereas the absolute values of the beam polarizations in the so-called ``polarized states`` were equal and opposite. It was observed that the hexapole lens of the ion source produced beam polarization in the absence of any transition. The beam ...
1997-11-11
International Nuclear Information System (INIS)
We report a study of the physical characteristics of the pillars of C, Pt and W grown by 10-30 keV Ga focused ion beam (FIB) as a function of Ga ion flux, and present a quantitative analysis of the elements using energy-dispersive analysis of X-rays (EDAX). All the FIB grown pillars exhibit a rough morphology with whisker like protrusions on the cylindrical surface and broadening of the base as compared to the nominal size. For a constant fluence, the height of the pillar initially increases and then reduces after going through a maximum as a function of ion flux in all the cases. The compositional analysis shows good metallic quality for Pt structures but reveals significant contamination of Ga in C and Ga and C in W structures at higher ion fluxes. Explanation to all these observations has been sought in the light of secondary ion and electron effects and the different processes involved which lead to the FIB induced ...
2008-04-01
Energy Technology Data Exchange (ETDEWEB)
During this project we experimentally evaluated the below-ground biomass and carbon allocation and partitioning of four different fast- and slow-growing families of loblolly pine located in Scotland County, NC, in an effort to increase the long-term performance of the crop. The trees were subjected to optimal nutrition and control since planting in 1993. Destructive harvests in 1998 and 2000 were used for whole?plant biomass estimates and to identify possible family differences in carbon acquisition (photosynthesis) and water use efficiency. At regular intervals throughout each year we sampled tissues for carbohydrate analyses to assess differences in whole-tree carbon storage. Mini rhizotron observation tubes were installed to monitor root system production and turnover. Stable isotope analysis was used to examine possible functional differences in water and nutrient acquisition of root systems between the various families. A genetic ...
2001-03-01
Algebraic Principles of Quantum Field Theory II: Quantum Coordinates and WDVV Equation
This paper is about algebro-geometrical structures on a moduli space $\\CM$ of anomaly-free BV QFTs with finite number of inequivalent observables or in a finite superselection sector. We show that $\\CM$ has the structure of F-manifold -- a linear pencil of torsion-free flat connection with unity on the tangent space, in quantum coordinates. We study the notion of quantum coordinates for the family of QFTs, which determines the connection 1-form as well as every quantum correlation function of the family in terms of the 1-point functions of the initial theory. We then define free energy for an unital BV QFT and show that it is another avatar of morphism of QFT algebra. These results are consequences of the solvability of refined quantum master equation of the theory. We also introduce the notion of a QFT integral and study some properties of BV QFT equipped with a QFT integral. We show that BV QFT with a non-degenerate QFT ...
2011-01-01
The strong associations between organism characteristics and network architecture
Understanding the dependence and interplay between architecture and function in biological networks has great relevance to disease progression, biological fabrication and biological systems in general. Recent research in complex systems and networks, presents methods to properly mine the architectural interdependence in networks. Guided by such work, we propose methods to associate organism characteristics with network topology by analyzing a large number of architectural patterns. We adopt an automated approach using 11 topological metrics from complex networks to characterize a collection of various kinds of biological networks. Principal component analysis and clustering allow us to extract the indispensable, independent and informative metrics. Using hierarchical linear modeling, we observe that organism characteristics associate with these metrics, surprisingly well. This work can serve as a stepping stone to cataloging biologically ...
2009-01-01
International Nuclear Information System (INIS)
The partial pressures of the components (ThCl_4, MCl and MThCl_5) in the saturated vapours of ThCl_4 solutions in molten LiCl, NaCl, KCl, RbCl and CsCl are determined as a function of temperature (900 to 1200 K) and ThCl_4 concentration (2 to 50 mol% ThCl_4) by dynamic method. Thorium tetrachloride volatility is shown to exceed that of alkali chloride from the melts containing less than 98 LiCl or NaCl, 83 KCl, 67 RbCl and 48 mol% CsCl. From experimental observations the decomposition potential of the electrolytes under investigation was estimated in temperature and concentration ranges of our measurements. Under otherwise equal conditions, it increases in the series of alkali chlorides from LiCl to CsCl. (author).
1984-01-01
The Galactic Exoplanet Survey Telescope (GEST)
The Galactic Exoplanet Survey Telescope (GEST) will observe a 2 square degree field in the Galactic bulge to search for extra-solar planets using a gravitational lensing technique. This gravitational lensing technique is the only method employing currently available technology that can detect Earth-mass planets at high signal-to-noise, and can measure the frequency of terrestrial planets as a function of Galactic position. GEST's sensitivity extends down to the mass of Mars, and it can detect hundreds of terrestrial planets with semi-major axes ranging from 0.7 AU to infinity. GEST will be the first truly comprehensive survey of the Galaxy for planets like those in our own Solar System.
2002-01-01
International Nuclear Information System (INIS)
Bisaminoethanethiol (BAT) ligands with various gem-dimethyl and amide groups were prepared, and the corresponding neutral Tc-99m complexes were prepared and evaluated for their relative stabilities by ligand-exchange reactions. It was demonstrated that technetium complexes containing gem-dimethyl substituents have higher lipophilicities, whereas those with an amide group possess greater stability, which enhances ligand-exchange reaction. The most interesting observation was that the brain uptake in rats is not determined only by lipophilicity. Apparently, Tc-99m complexes with an amide functional group display lower brain uptakes in rats compared to those without an amide group. The brain uptake was strongly influenced by substituents on the BAT ligand. These factors are critically important and should be taken into consideration when designing Tc-99m-labeled agents for CNS receptor imaging.
1998-02-01
Response variability in balanced cortical networks
DEFF Research Database (Denmark)
We study the spike statistics of neurons in a network with dynamically balanced excitation and inhibition. Our model, intended to represent a generic cortical column, comprises randomly connected excitatory and inhibitory leaky integrate-and-fire neurons, driven by excitatory input from an external population. The high connectivity permits a mean field description in which synaptic currents can be treated as gaussian noise, the mean and autocorrelation function of which are calculated self-consistently from the firing statistics of single model neurons. Within this description, a wide range of Fano factors is possible. We find that the irregularity of spike trains is controlled mainly by the strength of the synapses relative to the difference between the firing threshold and the postfiring reset level of the membrane potential. For moderately strong synapses, we find spike statistics very similar to those observed in primary visual cortex.
2006-01-01
Real-time neutron scattering investigations of biological signal transduction dynamics
Energy Technology Data Exchange (ETDEWEB)
During their catalytic cycle, proteins involved in biological signal transduction undergo unexpectedly large conformational changes, which are at the core of their biological functioning. Until now it has been extremely difficult to obtain experimental insight into the nature of these conformational changes. Mathematical modeling and time-resolved X-ray crystallography have resulted in probable routes along which these conformational changes may take place, but so far this fundamental biological phenomenon has hardly been tackled experimentally. Here, we report on an attempt to observe structural changes in Photoactive Yellow Protein with time-resolved small-angle neutron scattering using diffractometer D22 at the high-flux reactor of the Institut Laue-Langevin, Grenoble, France.
2005-07-01
Real-time neutron scattering investigations of biological signal transduction dynamics
International Nuclear Information System (INIS)
During their catalytic cycle, proteins involved in biological signal transduction undergo unexpectedly large conformational changes, which are at the core of their biological functioning. Until now it has been extremely difficult to obtain experimental insight into the nature of these conformational changes. Mathematical modeling and time-resolved X-ray crystallography have resulted in probable routes along which these conformational changes may take place, but so far this fundamental biological phenomenon has hardly been tackled experimentally. Here, we report on an attempt to observe structural changes in Photoactive Yellow Protein with time-resolved small-angle neutron scattering using diffractometer D22 at the high-flux reactor of the Institut Laue-Langevin, Grenoble, France
2005-04-11
Prospective observation of CAD/CAM titanium ceramic single crowns: A three-year follow up
British Library Electronic Table of Contents (United Kingdom)
Statement of problem Computer-aided design/computer-aided manufacturing (CAD/CAM) titanium ceramic restorations were developed with the potential for replacing expensive, high noble metal ceramic restorations. However, there is a lack of information about the clinical performance of CAD/CAM titanium ceramic single crowns. Purpose The purpose of this study was to evaluate CAD/CAM titanium ceramic single crowns after 3 years in function. Material and methods A total of 41 crowns were fabricated for 21 patients. The titanium copings were CAD/CAM milled (Everest CAD/CAM system) with an even thickness of 0.5 mm, and low-fusing veneering porcelain (Vita Titanium Porcelain) was added incrementally. The crowns were cemented using zinc phosphate cement after confirming that there were no mechanical...
2009-01-01
Properties and physiological effects of thermal carbon black.
Studies have been carried out to determine the possible physiological effects of contact with carbon black made by the thermal process. Contact was made by ingestion, skin application and/or inhalation. Ingestion and/or skin application do not appear to lead to any changes from the normal. Inhalation exposures do not produce pulmonary function changes (antemortem or postmortem studies) but may lead to moderate to severe "perifocal" emphysema in Rhesus monkeys (not observed in guinea pigs). Inhalation studies also suggest right ventricular septal and to a degree, left ventricular hypertrophy in Rhesus monkeys as an effect. Additional studies are necessary to support these finding and consideration must be given to the variability among exposed subjects as compared to controls. PMID:136503
1976-11-01
Prediction of drug particle size and content uniformity in low-dose solid dosage forms
British Library Electronic Table of Contents (United Kingdom)
Drug particle size distribution has a profound impact to the content uniformity in low-dose solid drug products. We derived theoretically the skewness of potency distribution as a function of particle size distribution and target dose. It was demonstrated that both skewness and coefficient of variation diverge simultaneously with inverse square root of the target dose. This scaling relation was observed in recent experiment and was verified by Monte Carlo (MC) simulation, which was employed for the first time to solve for the full potency distribution from a random retrieving model. When tested against the criteria from USP uniformity of dosage units, MC simulation showed a striking anisotropic distribution of the data. This suggests a full-scale consideration of the potency distribu...
2010-01-01
Predictability, complexity and learning
We define {\\em predictive information} $I_{\\rm pred} (T)$ as the mutual information between the past and the future of a time series. Three qualitatively different behaviors are found in the limit of large observation times $T$: $I_{\\rm pred} (T)$ can remain finite, grow logarithmically, or grow as a fractional power law. If the time series allows us to learn a model with a finite number of parameters, then $I_{\\rm pred} (T)$ grows logarithmically with a coefficient that counts the dimensionality of the model space. While logarithmic growth of related information theoretic quantities has been found in previous work on learning, power law growth has not been seen in this context. We find that it is associated, for example, with the learning of infinite parameter (or nonparametric) models such as continuous functions with smoothness constraints. There are connections between the predictive information and measures of complexity that have been ...
2000-01-01
Polarity of prismatic facets delimiting WC grains in WC-Co alloys
British Library Electronic Table of Contents (United Kingdom)
This study reports a determination of the polarity of WC facets in WC-Co alloys sintered at the liquid state. In these alloys, WC grains are delimited by basal facets and two sets of {101 0} prismatic facets, one set of facets being much more developed than the other. A variation of the shape is observed as a function of the composition of the alloy. High resolution transmission electron microscopy is used to investigate the polarity of the prismatic facets owing to the typical triangular patterns appearing on the images. The effect of the composition is investigated using two alloys with different carbon potentials and one containing VC and Cr3C2 as grain growth inhibitors. The interpretation of the images shows that in all cases, the same set of prismatic planes is favoured.
2010-01-01
Phase Behavior and Interactions of the Membrane-Protein Bacteriorhodopsin
Energy Technology Data Exchange (ETDEWEB)
We present a synchrotron x-ray diffraction study of melting in stacks of two-dimensional crystalline arrays of the membrane protein bacteriorhodopsin. Two distinct regimes have been found as a function of the intermembrane distance d . In the {open_quotes}coupled{close_quotes} regime for d{lt}250 {Angstrom} the temperature (T{sub m}) of the melting transition decreases with increasing d , demonstrating the effect of the repulsive membrane interactions on the intramembrane protein ordering. For d{gt}250 {Angstrom} a {open_quotes}decoupled{close_quotes} regime is found with higher T{sup *}{sub m} independent of d . Below T{sup *}{sub m} a solid-liquid-solid reentrant behavior is observed as d is increased. {copyright} {ital 1999} {ital The American Physical Society}
1999-04-01
Penile rehabilitation therapy following radical prostatectomy is a much debated topic. Erectile dysfunction is still a significant contributor to postoperative morbidity following radical prostatectomy, despite meticulous nerve-sparing technique. Secondary smooth muscle changes in the penis have been identified as the underlying causes of penile atrophy, veno-occlusive dysfunction, and fibrosis. Initial observations that intracavernous injection therapies used on a regular basis postoperatively resulted in improvements in the return of spontaneous erectile function led to the development of penile rehabilitation protocols. Chronic dosing of PDE-V inhibitors is now commonly used by urologists after radical prostatectomy. Despite the current enthusiasm of penile rehabilitation therapy, current scientific evidence with clinical trials is still limited. PMID:19255627
2009-01-25
Energy Technology Data Exchange (ETDEWEB)
The flow of current inside a conductor leads to its overheating. This conductor is also submitted to other climatic phenomena, such as wind, sun light and ambient temperature. The knowledge of this overheating is important to ensure a functioning temperature compatible with the materials used for the conductor manufacturing and with the dip of overhead power lines above the ground and buildings. On the other hand, according to the Laplace works, the flow of current inside parallel conductors induces electromagnetic forces inside them, proportional to the product of currents in both conductors. In the case of short-circuit between aerial power lines or between flexible cables, electrodynamical stresses (traction and flexion) are applied to insulators and holders and important swinging of the lines can be observed. These stresses can be extremely important and must be considered in the design of overhead lines. These two phenomena are analyzed in ...
1997-05-01
On cosmologically designed modified gravity theories
Versions of parameterized pseudo-Newtonian gravity theories specially designed for cosmology have been introduced in recent cosmology literature. The modifications demand a zero-pressure fluid in the context of versions of modified Poisson-like equation with two different gravitational potentials. We consider such modifications in the context of relativistic gravity theories where the action is a general algebraic function of the scalar curvature, the scalar field, and the kinetic term of the field. In general it is not possible to isolate the zero-pressure fluid component simultaneously demanding a modification in the Poisson-like equation. Only in the small-scale limit we can realize some special forms of the attempted modifications. We address some loopholes in the possibility of showing non-Einstein gravity nature based on pseudo-Newtonian modifications in the cosmological context. We point out that future observations of gravitational weak ...
2010-01-01
Energy Technology Data Exchange (ETDEWEB)
This document reproduces the final project of David San Fabian Ayuso, presented on May 26, 2005, for the obtention of the engineer degree of the Carlos III University of Madrid. A single-phase, isothermal model, including both electron and proton transport, is introduced for the simulation of polymer electrolyte fuel cells (PEM). The model is implemented in the commercial code Fluent 6.0, through the use of UDFs (User Defined Functions). In order to validate the model, a single canal of a PEM monocell is simulated in three dimensions. The obtained result are qualitatively satisfactory. It is observed that it is not essential to solve the current collectors when a monocell is considered (and not a stack). in the present study, the number of nodes is the computational grid appears to be too low in the membrane zone in order to make a complete validation of the model. (Author) 20 refs.
2005-07-01
Non-Fermi-liquid scaling in UCu_5_-_xPd_x (x=1, 1.5): a phenomenological description
International Nuclear Information System (INIS)
We present a unified description of the imaginary part of the dynamical magnetic susceptibility #chi#"'"'(#omega#.T) and measurements of the static susceptibility #chi#(T) and electrical resistivity #rho#(T) in the uranium intermetallics UCu_5_-_xPd_x (x = 1.1.5). For temperatures T and excitation energies #omega# in the range 12 K < #omega#, T < 150 K, our analysis demonstrates that the dynamics of isolated uranium ions are responsible for the observed temperature and frequency scaling, although interion interactions may become important at lower temperatures and frequencies. We derive a strict criterion for single-ion scaling in the form of a universal scaling function, providing a model-independent description of the compiled experimental data. (orig.).
Nickel induced structural and functional alterations in mouse Leydig cells in vitro
British Library Electronic Table of Contents (United Kingdom)
The present study was aimed at investigating effects of nickel (NiCl2) on secretion of testosterone (T), cell viability, ultrastructure and apoptosis in mouse Leydig cells. Testosterone release was measured after 48h of culture with 15.67, 31.25, 62.5, 125, 250, 500 and 1000mmol/L NiCl2 or without NiCl2 using radioimmunoassay. Cell viability was assessed by a MTT (metabolic activity assay). Quantification of apoptotic cells was performed using TUNEL assay and the ultrastructural changes were analyzed using transmission electron microscopy. The viability was decreased after addition of >=250mmol/L NiCl2. A concentration-dependent depression of T production was observed. The percentage of apoptotic cells was significantly increased only after addition of 125, 250 and 1000mmol/L NiCl2. After ...
2011-01-01
We present here a study based on the migration of protoplanets in an accretion disc of a forming star, as the mainly proposed scenario for the formation of planetary systems. Attention is here focused on the mutual interactions between two protoplanets, both embedded in the accretion disc, as a function of the protoplanets masses, their relative positions, the dynamic properties of the accretion disc particles. The study is performed through a 2D SPH code and preliminary results show an oscillation of the distance between the two protoplanets, together with a slow migration of the two planets towards the central star when two Jupiter-like planets are considered. Less correlated behaviour is observed when at least one of the two protoplanets has an Earth-like mass. The role played by the disc particles initial angular momentum is discussed.
2010-01-01
Monosodium titanate particle characterization
Energy Technology Data Exchange (ETDEWEB)
A characterization study was performed on monosodium titanate (MST) particles to determine the effect of high shear forces expected from the In-Tank Precipitation (ITP) process pumps on the particle size distribution. The particles were characterized using particle size analysis and scanning electron microscopy (SEM). No significant changes in particle size distributions were observed between as-received MST and after 2--4 hours of shearing. Both as-received and sheared MST particles contained a large percentage of porosity with pore sizes on the order of 500 to 2,000 Angstroms. Because of the large percentage of porosity, the overall surface area of the MST is dominated by the internal surfaces. The uranium and plutonium species present in the waste solution will have access to both interior and exterior surfaces. Therefore, uranium and plutonium loading should not be a strong function of MST particle size.
1993-01-12
British Library Electronic Table of Contents (United Kingdom)
All-atom molecular dynamics simulations were used to study the morphology of polymer/inorganic composite particles prepared by heterocoagulation. The results were also compared to those of our previous study of the preparation of TiO2/poly(acrylic acid-co-methyl methacrylate) and Fe3O4/polystyrene composite particles. In the simulation system, polymer or inorganic particles were simulated by surface-charge-modified C60 or Na atoms. Through a combination of analysis of the radial distribution functions of charged atoms and snapshots of the equilibrated structure, three kinds of particle distributions were observed under different conditions. When the polymer and inorganic particles had opposite surface charges and their sizes were very different, the composite morphology showed a core-shell...
2010-01-01
Molecular biology of the renin-angiotensin system
Energy Technology Data Exchange (ETDEWEB)
This paper reviews the molecular biology of the renin-angiotensin system. The renin gene structure is analyzed in detail, including an examination of the putative regulatory regions. The combined action of these regulatory sequences would result in the complex, tissue-specific expression and regulation observed in vivo. The expression of the tissue renin-angiotensin systems, which may have important physiological functions, is also described. In addition, the pathway of renin biosynthesis and secretion is reviewed. This includes speculation on the fate of circulating prorenin and the physiological role of multiple renin forms and secretory pathways. The molecular approaches described in this paper have greatly advanced our knowledge of the biology of the renin-angiotensin system. Future studies using these and other approaches should provide further insight into this complex system.
1988-10-01
Energy Technology Data Exchange (ETDEWEB)
Excitation of low temperature helium or helium/water plasma and subsequent exposure to air of polyacrylonitrile (PAN) ultrafiltration membranes was used to hydrophilize the surface of these materials. We analyzed the effectiveness of this approach as a function of plasma operating variables including gas phase composition, plasma power, treatment time and system pressure. Following the changes in physical and chemical composition of the PAN surface resulting from these modifications was a major aspect of this work. Techniques such as the captive bubble contact angle method, ellipsometry, ESCA, and FTIR-ATR were all used. In addition, the formation and life-time of peroxides during these processes were determined. At low powers (<25W) and short treatment periods ({<=}30 sec), the main chemical conversion of PAN surfaces was simultaneous hydrophilization and stabilization via PAN cyclization. Relatively small water permeability changes were ...
1995-12-01
Laser-processed thin-film transistors fabricated from sputtered amorphous-silicon films
Energy Technology Data Exchange (ETDEWEB)
Low-temperature polysilicon thin-film transistors (TFT's) have been fabricated from sputtered silicon films and characterized as a function of as-deposited hydrogen (H) content and laser crystallization fluence. A general trend is observed where TFT performance improves as the H content is lowered. Devices made from {approximately}0% H sputtered films perform similar to those made from low-pressure chemical-vapor deposition processes (LPCVD), but are fabricated at a much lower process temperature (300 C). The best sputtered TFT's had mobilities of {approximately}200 cm{sup 2}/Vs, and on/off current ratios of more than 10{sup 8}.
2000-01-01
We report electronic and magnetic structure of arsenic-doped manganese clusters from density-functional theory using generalized gradient approximation for the exchange-correlation energy. We find that arsenic stabilizes manganese clusters, though the ferromagnetic coupling between Mn atoms are found only in Mn$_2$As and Mn$_4$As clusters with magnetic moments 9 $\\mu_B$ and 17 $\\mu_B$, respectively. For all other sizes, $x=$ 3, 5-10, Mn$_x$As clusters show ferrimagnetic coupling. It is suggested that, if grown during the low temperature MBE, the giant magnetic moments due to ferromagnetic coupling in Mn$_2$As and Mn$_4$As clusters could play a role on the ferromagnetism and on the variation observed in the Curie temperature of Mn-doped III-V semiconductors.
2005-01-01
British Library Electronic Table of Contents (United Kingdom)
The interlayer exchange coupling between Co/Pt perpendicular-to-plane magnetized layers across a thin IrMn spacer layer was experimentally studied. In contrast to earlier studies on interlayer coupling through antiferromagnetic NiO, which revealed an oscillatory coupling behavior as a function of NiO thickness, a ferromagnetic coupling was observed here in the range of IrMn thickness between 0.6 and 1.5nm and antiferromagnetic between 1.5 and 2.5nm. The antiferromagnetic coupling is attributed to an orange peel magnetostatic mechanism whereas the ferromagnetic coupling is attributed to an out-of-plane polarization of the antiferromagnetic IrMn layer induced by the interfacial exchange interaction with the adjacent out-of-plane ferromagnetic layers. Measurements of hysteresis loops versus t...
2011-01-01
Integrated Analysis of Environment-driven Operational Effects in Sensor Networks
Energy Technology Data Exchange (ETDEWEB)
There is a rapidly growing need to evaluate sensor network functionality and performance in the context of the larger environment of infrastructure and applications in which the sensor network is organically embedded. This need, which is motivated by complex applications related to national security operations, leads to a paradigm fundamentally different from that of traditional data networks. In the sensor networks of interest to us, the network dynamics depend strongly on sensor activity, which in turn is triggered by events in the environment. Because the behavior of sensor networks is sensitive to these driving phenomena, the integrity of the sensed observations, measurements and resource usage by the network can widely vary. It is therefore imperative to accurately capture the environmental phenomena, and drive the simulation of the sensor network operation by accounting fully for the environment effects. In this paper, we illustrate the ...
2007-07-01
In-medium reduction of the \\eta' mass in \\sqrt{s_NN} = 200 GeV Au+Au collisions
A reduction of the mass of the \\eta'(958) meson may indicate the restoration of the UA(1) symmetry in a hot and dense hadronic matter, corresponding to the return of the 9th, "prodigal" Goldstone boson. We report on an analysis of a combined PHENIX and STAR data set on the intercept parameter of the two-pion Bose-Einstein correlation functions, as measuremed in \\sqrt{s_NN} = 200 GeV Au+Au collisions at RHIC. To describe this combined PHENIX and STAR dataset, an in-medium \\eta' mass reduction of at least 200 MeV is needed, at the 99.9 % confidence level in a broad model class of resonance multiplicities. Energy, system size and centrality dependence of the observed effect is also discussed.
2011-01-01
Glutathione peroxidase activity in the selenium-treated alga Scenedesmus quadricauda
British Library Electronic Table of Contents (United Kingdom)
The function of selenium in an organism is mediated mostly by selenoproteins including glutathione peroxidase. Glutathione peroxidase is a potent anti-oxidative enzyme, scavenging a variety of peroxides. The green alga Scenedesmus quadricauda was used to investigate the relationship between the toxicity of selenium and the glutathione peroxidase activity. Selenium resistant strains SeIV and SeVI were synchronized and grown in high concentrations of Se (selenite or selenate). As a measure of selenium toxicity the EC50 values were determined. During growth of the untreated wild type, glutathione peroxidase activity increased slightly and then declined gradually until the end of the cell cycle. A similar pattern was observed in untreated resistant strains and when resistant strains were grown...
2011-01-01
Gluino-Squark Production at the LHC: The Threshold
An analysis of the cross section for hadronic production of gluino-squark pairs close to threshold is presented. Within the framework of non-relativistic QCD a significant enhancement compared to fixed order perturbation theory is observed which originates from the characteristic remnants of the gluino-squark resonances below the nominal pair threshold. The analysis includes all colour configurations of S-wave gluino-squark pairs, i.e. triplet, sextet and 15 representation. Matching coefficients at leading order are separately evaluated for all colour configurations. The dominant QCD corrections, arising from initial- and final-state radiation are included. The non-relativistic dynamics of the gluino pair is solved by calculating the Green's function in Next-to-Leading Order (NLO). The results are applied to benchmark scenarios, based on Snowmass Points and Slopes (SPS). As a consequence of the large decay rate of at least one of the ...
2011-01-01
Geospatial tools for assessing land degradation in Budgam district, Kashmir Himalaya, India
British Library Electronic Table of Contents (United Kingdom)
Land degradation reduces the ability of the land to perform many biophysical and chemical functions. The main aim of this study was to determine the status of land degradation in the Budgam area of Kashmir Himalaya using remote sensing and geographic information system. The satellite data together with other geospatial datasets were used to quantify different categories of land degradation. The results were validated in the field and an accuracy of 85% was observed. Land use/land cover of the study area was determined in order to know the effect of land use on the rate of land degradation. Normalized differential vegetation index (NDVI) and slope of the area were determined using LANDSAT-enhanced thematic mapper plus (ETM+) data, advanced space borne thermal emission and reflection radiome...
2011-01-01
British Library Electronic Table of Contents (United Kingdom)
Children with attention-deficit/hyperactivity disorder (ADHD) often have poor relationships with peers. However, research on this topic has predominantly focused on boys. This study considered child gender, ADHD status, and dimensionally assessed conduct problems as predictors of peer relationship difficulties. Participants were 125 children (ages 6-10; 67% male), 63 with clinical diagnoses of ADHD and 62 non-ADHD comparison youth. Conduct problems were reported by teachers and observed in a lab playgroup. Peer relationships were assessed by parent report, teacher report, and peer sociometric nominations in the playgroup. Results suggested that children with ADHD, as well as those with high conduct problems, displayed more impaired peer relationships than did comparison children and those ...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
This grant has focused on the study of several aspects of electron kinetics in low pressure plasmas. Entirely new effects arise from the fact that the electron kinetics is governed by non-local effects, in which the electron distribution function is not equilibrium with the local electric field but is governed by spatial transport effects. In this grant, we were able to demonstrate several previously un-studied effects which are a direct result of the nonlocal transport. These are: (1) The existence of a ''convective cell' in electron phase space. The phenomenon was observed and studied in CW plasma conditions. (2) The occurrence of non-collisional cooling of electrons through an effect known as ''diffusive cooling''.
2004-12-13
Fast generation shedding equipment based on the observation of swings of generators
Energy Technology Data Exchange (ETDEWEB)
This paper presents a new method and newly developed stabilizing equipment to prevent the loss of synchronism of generators in pumped-storage plants from spreading. The proposed method includes functions to estimate the swing of each generator by using on-line generator output sampled at a rate of 600 times per second after an occurrence of disturbance such as fault, faulty equipment and so on, to predict generator swing 200-300 milliseconds ahead and loss of synchronism between generators in pumped-storage plants and those in thermal and nuclear plants, and to decide the number of generators that must be shed to maintain stability. Tokyo Electric Power Co. (TEPCO) installed the newly developed stabilizing equipment based on this method in the power system in June, 1986.
1988-05-01
Fast generation shedding equipment based on the observation of swings of generators
International Nuclear Information System (INIS)
This paper presents a new method and newly developed stabilizing equipment to prevent the loss of synchronism of generators in pumped-storage plants from spreading. The proposed method includes functions to estimate the swing of each generator by using on-line generator output sampled at a rate of 600 times per second after an occurrence of disturbance such as fault, faulty equipment and so on, to predict generator swing 200-300 milliseconds ahead and loss of synchronism between generators in pumped-storage plants and those in thermal and nuclear plants, and to decide the number of generators that must be shed to maintain stability. Tokyo Electric Power Co. (TEPCO) installed the newly developed stabilizing equipment based on this method in the power system in June, 1986.
1988-01-01
Facesheet debonding criteria for composite sandwich panels under in-plane compression
A method for determining the critical debond size between the facesheet and the core in composite sandwich panels under in-plane compression is described. The approach uses fracture mechanics together with a buckling criterion for a debonded faceskin. The technique yields predictions for the critical in-plane compressive load for debond propagation as a function of core-to-faceskin debond size, faceskin thickness, lay-up, composite material properties, and honeycomb properties and geometry. A computer program, developed in this work, calculates the critical buckling load and facesheet deformed shape by solving an eigenvalue problem. The output predicts, for several cases, critical initial debond lengths comparable to those that have been observed on tests on sandwich panels.
1992-07-01
Explosive performance on the non-proliferation experiment
Energy Technology Data Exchange (ETDEWEB)
The non-proliferation experiment, originally called the chemical kiloton experiment, was planned and executed by Lawrence Livermore National Laboratory to investigate the seismic yield relationship and distinguishing seismic signals between a nuclear event and a large mass conventional explosion. The Los Alamos National Laboratory planned and conducted experiments to further their studies of the source function for signals observed seismically. Since all investigations were contingent on the performance of the emplaced chemical explosive, an array of diagnostic measurements was fielded in the emplaced explosive. The CORRTEX system was used to investigate the explosive initiation and to determine the detonation velocities in multiple levels and in numerous directions. A description of the CORRTEX experiments fielded, a review of the data obtained and some interpretations of the data are reported.
1994-03-01
Effects of antipsychotics and amphetamine on social behaviors in spontaneously hypertensive rats
British Library Electronic Table of Contents (United Kingdom)
We have recently reported that spontaneously hypertensive rats (SHRs) exhibit a deficit in contextual fear conditioning that is specifically reversed by antipsychotic and potentiated by psychostimulants and other manipulations thought to produce schizophrenia-like states in rodents. Based on these findings, we suggested that this deficit in fear conditioning could be used as an experimental model of emotional processing impairments observed in schizophrenia. This strain has also been suggested as a model by which to study attention deficit/hyperactivity disorder (ADHD). Considering that schizophrenia and ADHD are both characterized by poor social function, this study aimed to investigate possible behavioral deficits of SHRs in a social context. Furthermore, we sought to examine the effects...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
The thermal stability and deformability of Mn-Al-C alloys containing 0.6 pct C are investigated experimentally as a function of excess phase content. It is shown that an increase in Mn content from 68.9 to 73.5 pct leads to increased stability of the high-temperature epsilon phase. The enrichment of the system Mn-Al-Cu in Mn and Al above the optimum composition leads to the formation of nonmagnetic excess phases, eta and beta, which reduce the magnetization of the alloy. In addition, a decrease in thermal stability is observed in the alloy with 73.5 pct Mn due to the decomposition of the ferromagnetic phase. 7 references.
1988-01-01
Energy Technology Data Exchange (ETDEWEB)
An array of sonic transducers, useful for medical ultrasonic imaging, has individual sections thereof separately coupled for forming separate beams of sonic energy which converge, respectively, to separate foci along a common axis of the beams. The ratio of the diameter of the radiating aperture of the array relative to a wavelength of the sonic energy is chosen to provide a moderate degree of focusing so that the depth of field at one focus blends with the depth of field of the next focus. Thereby, there is formed a continuous region of substantially uniform intensity of sonic radiation along the common beam axis. Circuitry is provided for selecting one or more specific foci dependent on the bounds of a selected region to be insonified. Upon reception of sonic energy, circuitry is provided for selecting one or more specific foci as a function of the time of travel of an echo from a subject being observed to approximate a continuously varying ...
1981-07-07
Determination of radon and thoron permeability through some plastics by track technique
Energy Technology Data Exchange (ETDEWEB)
Experiments have been performed to study the usefulness of several types of plastic foils as filter to separate radon and thoron. Time-integrated alpha-activity measurements have been carried out by using the so-called ''can-technique'' equipped with both LR-115 and CR-39 track detectors. The track density observed on the detectors, taken as a measure of radon activity concentration, has been determined as a function of the thickness of filter foils. The radon permeability and the thoron separation factors have been determined. It is shown that various plastic foils exhibit considerable differences in radon diffusion coefficient owing to their different chemical structures. Among the plastic foils investigated the polyethylene proved to have the highest gas diffusion coefficient.
1986-01-01
British Library Electronic Table of Contents (United Kingdom)
b-carotene, a natural antioxidant, beneficial form human health prospective. In this study we had examined the recovery of b-carotene form mesoporous carbon coated monolith (MCCM) by batch process. Desorption kinetics and isotherm studies were carried out by using n-hexane as an eluent. Isotherm studies showed better applicability of Langmuir model. The first-order two-compartment three-parameter kinetics model as a function of initial loading concentration and reaction temperature was applied. It was observed that b-carotene desorption process is controlled by both rapid and slow desorption. Results showed that the slow desorption fraction increases from 0.8446 to 0.9007 with increase in initial loading concentration from 10.83 to 39.72mg/g while, the slow desorption fraction decreases fr...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
The deterioration of AA2024, AA6061 and AA7475 anodised in an environmentally-compliant tartaric acid/sulphuric acid electrolyte has been examined as a function of the immersion time in the electrolyte after termination of anodising. By transmission electron microscopy and scanning electron microscopy, degradation of the porous oxide film was qualitatively observed on AA2024. Electrochemical impedance spectroscopy revealed that AA2024 and AA7075 were more sensitive to prolonged immersion in the anodising electrolyte compared with AA6061, due to increased barrier layer thinning rates and increased susceptibility to localized corrosion. Salt spray tests confirmed the previous, indicating decay of anticorrosion performance for AA2024 and AA7075.
2010-07-15
D-branes in a big bang/big crunch universe: Misner space
Energy Technology Data Exchange (ETDEWEB)
We study D-branes in a two-dimensional lorentzian orbifold R{sup 1,1}/{gamma} with a discrete boost {gamma}. This space is known as Misner or Milne space, and includes big crunch/big bang singularity. In this space, there are D0-branes in spiral orbits and D1-branes with or without flux on them. In particular, we observe imaginary parts of partition functions, and interpret them as the rates of open string pair creation for D0-branes and emission of winding closed strings for D1-branes. These phenomena occur due to the time-dependence of the background. Open string 2{yields}2 scattering amplitude on a D1-brane is also computed and found to be less singular than closed string case.
2005-09-01
Cosmological parameter estimation using Particle Swarm Optimization (PSO)
Obtaining the set of cosmological parameters consistent with observational data is an important exercise in current cosmological research. It involves finding the global maximum of the likelihood function in the multi-dimensional parameter space. Currently sampling based methods, which are in general stochastic in nature, like Markov-Chain Monte Carlo(MCMC), are being commonly used for parameter estimation. The beauty of stochastic methods is that the computational cost grows, at the most, linearly in place of exponentially (as in grid based approaches) with the dimensionality of the search space. MCMC methods sample the full joint probability distribution (posterior) from which one and two dimensional probability distributions, best fit (average) values of parameters and then error bars can be computed. In the present work we demonstrate the application of another stochastic method, named Particle Swarm Optimization (PSO), that is widely used ...
2011-01-01
Corrosion mode diagrams for alloy 690 TT and alloy 800
Energy Technology Data Exchange (ETDEWEB)
Due to the well-establish corrosion problems of Alloy 600 as a steam-generator material and the subsequent focus on thermally treated (TT) Alloy 690 and Alloy 800 as alternative materials, a systematic analysis of the corrosion behavior of these two latter alloys is warranted. Corrosion test results for Alloys 690 TT and 800 were collected and organized in the form of corrosion mode diagrams. Selected data for mill annealed (MA) Alloy 600 were also included for reference. The corrosion mode diagrams correlate the modes of corrosion degradation observed in tests as functions of the environment pH and electrochemical potential (ECP). The diagrams confirm that Alloys 690TT shows some susceptibility in caustic environments, and Alloy 800 shows susceptibility in both caustic and highly acidic environments. (authors). 6 figs., 5 refs.
1994-12-31
Corrosion mode diagrams for alloy 690 TT and alloy 800
International Nuclear Information System (INIS)
Due to the well-establish corrosion problems of Alloy 600 as a steam-generator material and the subsequent focus on thermally treated (TT) Alloy 690 and Alloy 800 as alternative materials, a systematic analysis of the corrosion behavior of these two latter alloys is warranted. Corrosion test results for Alloys 690 TT and 800 were collected and organized in the form of corrosion mode diagrams. Selected data for mill annealed (MA) Alloy 600 were also included for reference. The corrosion mode diagrams correlate the modes of corrosion degradation observed in tests as functions of the environment pH and electrochemical potential (ECP). The diagrams confirm that Alloys 690TT shows some susceptibility in caustic environments, and Alloy 800 shows susceptibility in both caustic and highly acidic environments. (authors). 6 figs., 5 refs.
Core-shell polymer nanorods by a two-step template wetting process
International Nuclear Information System (INIS)
One-dimensional core-shell polymer nanowires offer many advantages and great potential for many different applications. In this paper we introduce a highly versatile two-step template wetting process to fabricate two-component core-shell polymer nanowires with controllable shell thickness. PLLA and PMMA were chosen as model polymers to demonstrate the feasibility of this process. Solution wetting with different concentrations of polymer solutions was used to fabricate the shell layer and melt wetting was used to fill the shell with the core polymer. The shell thickness was analyzed as a function of the polymer solution concentration and viscosity, and the core-shell morphology was observed with TEM. This paper demonstrates the feasibility of fabricating polymer core-shell nanostructures using our two-step template wetting process and opens the arena for optimization and future experiments with polymers that are desirable for specific ...
2009-07-22
Contribution to 3D-operational geodesy. Pt. 3
Energy Technology Data Exchange (ETDEWEB)
Whereas in part 1 and 2 the detailed observation equations of terrestrial type for an integrated geodetic model are presented this paper will outline how the theory is transferred in an operational program. The main lines of functions of the FORTRAN IV program are discussed. Since the input specifications as well as the data requirements are described in detail and illustrated by example of input and output part 3 can serve as an user-guide for OPERA. OPERA is an acronym for operational adjustment. Besides the integrated determination of 3D-geocentric coordinates and the gravity disturbing potential the program can handle all cases of traditional geodesy (in total 13 variants of solution are provided) equivalent also with adjustments in ellipsoidal coordinates B, L or H, as well as constrained adjustments, pure prediction of the gravity disturbing field, etc.
1983-01-01
Contribution of climatic and anthropogenic effects to the hydric deficit of peatlands
British Library Electronic Table of Contents (United Kingdom)
Abstract The present study makes use of a detailed water balance to investigate the hydrological status of a peatland with a basal clay-rich layer overlying an aquifer exploited for drinking water. The aim is to determine the influence of climate and groundwater extraction on the water balance and water levels in the peatland. During the two-year period of monitoring, the hydrological functioning of the wetland showed a hydric deficit, associated with a permanent unsaturated layer and a deep water table. At the same time, a stream was observed serving as a recharge inflow instead of draining the peatland, as usually described in natural systems. Such conditions are not favourable for peat accumulation. Field investigations show that the clay layer has a high hydraulic conductivity (from 11...
2011-01-01
Chemical isomeric effects on propanol glassy structures
Energy Technology Data Exchange (ETDEWEB)
We have studied the structure of both propanol isomers in their glassy and crystalline states by neutron diffraction. The glass-transition temperatures of 1- and 2-propanol are about 98 and 115 K, respectively and, surprisingly, even larger differences are observed for the melting temperatures of the stable crystals, which are 148 and 185 K, respectively. Their supercooled liquid phases show rather different relaxation spectra, 1-propanol manifesting strong deviations from Debye behavior, whereas 2-propanol shows a far weaker effect. We discuss the spectra obtained for the static structure factor and the static pair correlation function D(r). There is a noticeable difference in the position of the first sharp diffraction peak, which clearly indicates a density change, well correlated with the period of the intermolecular oscillations shown by D(r). (orig.)
2002-07-01
Chemical isomeric effects on propanol glassy structures
International Nuclear Information System (INIS)
We have studied the structure of both propanol isomers in their glassy and crystalline states by neutron diffraction. The glass-transition temperatures of 1- and 2-propanol are about 98 and 115 K, respectively and, surprisingly, even larger differences are observed for the melting temperatures of the stable crystals, which are 148 and 185 K, respectively. Their supercooled liquid phases show rather different relaxation spectra, 1-propanol manifesting strong deviations from Debye behavior, whereas 2-propanol shows a far weaker effect. We discuss the spectra obtained for the static structure factor and the static pair correlation function D(r). There is a noticeable difference in the position of the first sharp diffraction peak, which clearly indicates a density change, well correlated with the period of the intermolecular oscillations shown by D(r). (orig.)
Characteristics of infrared-stimulated luminescence from a feldspar at low temperatures
International Nuclear Information System (INIS)
The characteristics of infrared-stimulated luminescence (IRSL) from a sample of potassium feldspar at low temperatures are presented. These studies extend the previous work from this laboratory on the optical bleaching characteristics and emission spectra of feldspars at room temperature and recent measurements of the stimulated spectrum for a sample of potassium feldspar at room temperature. Stimulation spectra have been measured at 290, 160 and 145 K. By fitting Gaussian functions to the spectra, the peak position is shown to shift to higher photon energies at lower temperatures and the full-width half-maximum of the peak to reduce with decreasing temperature. The variation of IRSL intensity with temperature for several stimulating wavelengths has been determined and the form of the IRSL decay curve measured at 290 and 160 K. No substantial differences were observed in the form of the decay curves at each temperature. (author).
1993-07-01
Bandgap properties of the indium sulfide thin-films grown by co-evaporation
British Library Electronic Table of Contents (United Kingdom)
In the present study the optical properties of co-evaporated indium sulfide thin films are investigated. Before being optically characterized, the composition as well as the crystalline properties of the film have been checked with the help of energy dispersive spectroscopy (EDX) and X-Ray diffraction (XRD) analyses. The optical absorption coefficient ? of this indium sulfide film has been deduced from reflectivity R(?) and transmission T(?) measurements. The fit of the curve representing ?(h?) suggests that the ?-In2S3 has an indirect bandgap of 2.01?eV. Density functional theory (DFT) calculations are performed on this indium sulfide compound, using TB-LMTO code. Through these band structure investigations, an indirect bandgap is predicted as observed experimentally. The top of the valen...
2009-01-01
Assessing potential impacts of climatic change on subalpine forests on the eastern Tibetan Plateau
British Library Electronic Table of Contents (United Kingdom)
Forest gap models have been used widely in the study of forest dynamics, including predicting long-term succession patterns and assessing the potential impacts of climate change on forest structure and composition. However, little effort is devoted to predict forest dynamics in the high elevation areas, although they have the sensitive response to global climate change. In the present study, based on a modified height-diameter function, we developed a new version (FAREAST-GFSM) of the forest patch model, FAREAST for simulating the changes of subalpine forests. The observed data from the Gongga Mt. Alpine Station were also used to test model precision. With the improved performance of FAREAST-GFSM, we explored the impact of three warming scenarios on subalpine forest on the eastern Tibetan ...
2011-01-01
A polarized neutron reflectometry study of the spin glass freezing in a 29 nm thick AuFe film
Energy Technology Data Exchange (ETDEWEB)
We performed polarized neutron reflectometry (PNR) experiments on a 29 nm thick Au{sub 93}Fe{sub 7} film in a temperature range from 295 K down to 2 K in a vertical magnetic field up to 6 T. These high-field experiments were performed on the C5 spectrometer in Chalk River, Canada, using a split-pair cryomagnet. The magnetization as determined by PNR can be described with a Brillouin function from 295 K down to 50 K assuming the magnetic moment of isolated Fe atoms, i.e. 4{mu}{sub B} per Fe atom. Below 50 K the onset of the spin-glass freezing is observed as a strong deviation from this Brillouin type behavior of isolated atoms.
2007-07-15
A new method of determining the inclination angle in interacting binaries
We describe a method of determining the system parameters in non-eclipsing interacting binaries. We find that the extent to which an observer sees the shape of the Roche-lobe of the secondary star governs the amount of distortion of the absorption line profiles. The width and degree of asymmetry of the phase-resolved absorption line profiles show a characteristic shape, which depends primarily on the binary inclination and gravity darkening exponent. We show that, in principle, by obtaining high spectral and time resolution spectra of quiescent cataclysmic variables or low mass X-ray binaries in which the mass-losing star is visible, fitting the shape of absorption line profiles will allow one to determine not only the mass function of the binary, but also the binary inclination and hence the mass of the binary components.
1998-01-01
This contribution deals with identification of fractional-order dynamical systems. System identification, which refers to estimation of process parameters, is a necessity in control theory. Real processes are usually of fractional order as opposed to the ideal integral order models. A simple and elegant scheme of estimating the parameters for such a fractional order process is proposed. This method employs fractional calculus theory to find equations relating the parameters that are to be estimated, and then estimates the process parameters after solving the simultaneous equations. The said simultaneous equations are generated and updated using particle swarm optimization (PSO) technique, the fitness function being the sum of squared deviations from the actual set of observations. The data used for the calculations are intentionally corrupted to simulate real-life conditions. Results show that the proposed scheme offers a very high degree of ...
2008-01-01
A Bayesian approach to analyze energy balance data from lactating dairy cows
British Library Electronic Table of Contents (United Kingdom)
The objective of the present investigation was to develop a Bayesian framework for updating and integrating covariate information into key parameters of metabolizable energy (ME) systems for dairy cows. The study addressed specifically the effects of genetic improvements and feed quality on key parameters in current ME systems. These are net and metabolizable energy for maintenance (NEM and MEM, respectively), efficiency of utilization of ME for milk production (kL) and growth (kG), and efficiency of utilization of body stores for milk production (kT). Data were collated from 38 studies, yielding 701 individual cow observations on milk energy, ME intake, and tissue gain and loss. A function based on a linear relationship between milk energy and ME intake and correcting for tissue energy lo...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
Molar excess volumes, V{sup E}, molar excess enthalpies, H{sup E}, and speeds of sound data, u, of chloroform (i) + aniline or o-toluidine (j) binary mixtures have been measured as a function of composition at 308.15 K. Isentropic compressibility changes of mixing, {kappa}{sub S}{sup E} have been determined by employing speed of sound data. Topological investigations of V{sup E} data reveals that aniline, chloroform and o-toluidine are associated entities and these (i + j) mixtures contain a 1:1 molecular complex. The IR studies lend further support to the nature and extent of interaction for the proposed molecular entity in the mixtures. H{sup E} and {kappa}{sub S}{sup E} values have also been calculated by employing Moelwyn-Huggins concept [Polymer 12 (1971) 387] taking topology of the constituents of the mixtures. It has been observed that calculated H{sup E} and {kappa}{sub S}{sup E} values compare well with their corresponding experimental ...
2008-05-30
International Nuclear Information System (INIS)
Molar excess volumes, VE, molar excess enthalpies, HE, and speeds of sound data, u, of chloroform (i) + aniline or o-toluidine (j) binary mixtures have been measured as a function of composition at 308.15 K. Isentropic compressibility changes of mixing, ?SE have been determined by employing speed of sound data. Topological investigations of VE data reveals that aniline, chloroform and o-toluidine are associated entities and these (i + j) mixtures contain a 1:1 molecular complex. The IR studies lend further support to the nature and extent of interaction for the proposed molecular entity in the mixtures. HE and ?SE values have also been calculated by employing Moelwyn-Huggins concept [Polymer 12 (1971) 387] taking topology of the constituents of the mixtures. It has been observed that calculated HE and ?SE values compare well with their corresponding experimental values. The observed VE, HE and ?SE data have also been ...
2008-05-30
Energy Technology Data Exchange (ETDEWEB)
An ASTER (advanced spaceborne thermal emission and reflection radiometer) is one of the image sensors. It is to be installed in an earth survey polar orbit platform satellite, EOS-AM1, which is to be launched in 1998, and it is going to start its operation. Data observed by the thermal infrared remote sensing of ASTER include the spectral emissivity, and the spectral emission reflectivity which is expressed by the function of temperature. It is required to overcome technical problems how to extract the spectral emissivity from the observed data. The spectral emissivity extracted from the remote sensing data by the MMD method, measured for samples collected in Cuprite area, Nevada, and/or measured at sampled points were compared to each other and discussed. The hemisphere spectral reflectivity, which is indirect spectral emissivity, agreed well with the direct spectral emissivity. Data suggesting the establishment of ...
1996-10-01
Molecular dynamics simulations have been used to study the differences between two DNA and RNA 14-mer quadruplexes of analogous sequences. Their structures present a completely different fold: DNA forms a bimolecular quadruplex containing antiparallel strands and diagonal loops; RNA forms an intrastrand parallel quadruplex containing a G-tetrad and an hexad, which dimerizes by hexad stacking. We used a multiscale computational approach combining classical Molecular dynamics simulations and density functional theory calculations to elucidate the difference in stability of the 2-folds and their ability in coordinating cations. The presence of 2'-OH groups in the RNA promotes the formation of a large number of intramolecular hydrogen bonds that account for the difference in fold and stability of the two 14-mers. We observe that the adenines in the RNA quadruplex play a key role in conserving the geometry of the hexad. We predict the cation ...
2008-09-03
Energy Technology Data Exchange (ETDEWEB)
Research and development has been performed on photochromic materials expected to be used in ultra-high density recording, high resolution indication and photoswitches. With regard to molecular orientation in the ternary system mixed LB film, the result of structural analysis by XPM spectrum revealed that the acceptor constituent in the LB film is so structured that it is separated and laminated with two other constituents, and that the sensitizer constituent and the donor constituent are not recognized of being separated definitely. Regarding the electron movement reaction in the solid phase system, a photo-current measuring experiment was carried out on the laminated film which is vacuum-deposited with the ternary system comprising of the donor, sensitizer, and acceptor. It was concluded that the observed photo-current reflects the electron movement reaction in the solid phase as it is. For the photo-current in the LB film, increase in the photo-current was ...
1990-03-01
Protons and glucose metabolism in shock
Energy Technology Data Exchange (ETDEWEB)
When oxygen is limiting, animals can ferment glucose via several metabolic pathways varying in energetic efficiency and leading to various end products (such as lactate, succinate, or propionate). Because the pH dependence of H/sup +/ production by fermentation is opposite to that by hydrolysis of adenosine triphosphate formed in the fermentation, the total number of moles of protons generated is always two per mole of fermentable substrate. However, two and three times more adenosine triphosphate can be turned over per mole of protons produced in succinate and propionate fermentations, respectively, than in lactate fermentation. At its limit, this advantage would achieve the same balance between H/sup +/ production and H/sup +/ consumption during ATP cycling that is observed in aerobic metabolism, a situation observed in certain alcohol fermentations. Since proton balance during anaerobiosis is clearly adaptable, we consider possible impact ...
1983-01-01
Observations of toroidal and poloidal rotation in the high-beta tokamak Torus II
The macroscopic rotation of plasma in a toroidal containment device is an important feature of the equilibrium. Toroidal and polidal rotation in the high-beta tokamak Torus II is measured experimentally by examining the Doppler shift of the 4685.75 A He II line emitted from the plasma. The toroidal flow at an average velocity of 1.6 x 10/sup 6/ cm/sec, a small fraction of the ion thermal speed, moves in the same direction as the toroidal-plasma current. The poloidal flow follows the ion diamagnetic current direction, also at an average speed of 1.6 x 10/sup 6/ cm/sec. In view of certain ordering parameters, the toroidal flow is compared with predictions from neoclassical theory in the collisional, Pfirsch-Schluter regime. The poloidal motion, however, results from an E x B drift in a positive radial electric field, approaching a stable ambipolar state. This radial electric field is determined from theory by using the measured poloidal velocity. Mechanisms for the time evolution of ...
1983-01-01
Observations of toroidal and poloidal rotation in the high beta tokamak Torus II
The macroscopic rotation of plasma in a toroidal containment device is an important feature of the equilibrium. Toroidal and poloidal rotation in the high beta tokamak Torus II is measured experimentally by examining the Doppler shift of the 4685.75 A He II line emitted from the plasma. The toroidal flow at an average velocity of 1.6 x 10/sup 6/ cm/sec, a small fraction of the ion thermal speed, moves in the same direction as the toroidal plasma current. The poloidal flow follows the ion diamagnetic current direction, also at an average speed of 1.6 x 10/sup 6/ cm/sec. In view of certain ordering parameters, the toroidal flow is compared with predictions from neoclassical theory in the collosional, Pfirsch-Schluter regime. The poloidal motion, however results from an E x B drift in a positive radial electric field, approaching a stable ambipolar state. This radial electric field is determined from theory by using the measured poloidal velocity. Mechanisms for the time evolution of ...
1983-01-01
New short-range electromagnetic current in the deuteron
International Nuclear Information System (INIS)
A new model for short-range isoscalar current in the deuteron and NN system is developed and tested on a variety of isoscalar magnetic observables such as the deuteron magnetic moment, magnetic form factor, and the circular polarization of photons at n"#->#p radiative capture at thermal neutron energies. The model for electromagnetic two-nucleon current proposed in the paper is based on generation of an intermediate dibaryon in the short-range NN interaction. This intermediate dibaryon, in turn, is treated within the new model for intermediate and short-range NN interaction recently proposed by the present authors. The transition current model developed here satisfies the current conservation relation by the construction. Our calculations have demonstrated that the new current model, using only one parameter (with a clear physical meaning), is able to describe, in very good agreement with the experimental data, three basic deuteron ...
2007-02-01
N-body Models of Extended Clusters
We use direct N-body simulations to investigate the evolution of star clusters with large size-scales with the particular goal of understanding the so-called extended clusters observed in various Local Group galaxies, including M31 and NGC6822. The N-body models incorporate a stellar mass function, stellar evolution and the tidal field of a host galaxy. We find that extended clusters can arise naturally within a weak tidal field provided that the tidal radius is filled at the start of the evolution. Differences in the initial tidal filling-factor can produce marked differences in the subsequent evolution of clusters and the size-scales that would be observed. These differences are more marked than any produced by internal evolution processes linked to the properties of cluster binary stars or the action of an intermediate-mass black hole, based on models performed in this work and previous work to date. Models evolved in a ...
2010-01-01
Microstructural evaluation of as-solidified and heat-treated [gamma]-TiAl based powders
Energy Technology Data Exchange (ETDEWEB)
Powders with nominal compositions (in atomic percent) Ti-48Al and Ti-48Al-2Nb-2Cr were prepared by the plasma rotating electrode process (PREP) and gas atomization (GA) techniques. As-solidified and heat-treated (1000degC per 3 h) powder samples were examined by metallography, scanning electron microscopy, X-ray diffraction and transmission electron microscopy. The microstructures of the powders were characterized as a function of atomization technique, alloy content, powder particle size (solidification rate) and thermal history. All of the as-solidified powders were comprised of disordered [alpha], and ordered [alpha][sub 2]-Ti[sub 3]Al and [gamma]-TiAl. For both alloys, a larger volume fraction of [alpha] and [alpha][sub 2] was observed in the PREP powders relative to GA powders of comparable size. Additionally, for both alloys and both atomization techniques, the volume fraction of [alpha][sub 2] was observed to ...
1992-05-15
Microlens Parallax Measurements with a Warm Spitzer
Because Spitzer is an Earth-trailing orbit, losing about 0.1 AU/yr, it is excellently located to perform microlens parallax observations toward the Magellanic Clouds (LMC/SMC) and the Galactic bulge. These yield the so-called ``projected velocity'' of the lens, which can distinguish statistically among different populations. A few such measurements toward the LMC/SMC would reveal the nature of the lenses being detected in this direction (dark halo objects, or ordinary LMC/SMC stars). Cool Spitzer has already made one such measurement of a (rare) bright red-clump source, but warm (presumably less oversubscribed) Spitzer could devote the extra time required to obtain microlens parallaxes for the more common, but fainter, turnoff sources. Warm Spitzer could observe bulge microlenses for 38 days per year, which would permit up to 24 microlens parallaxes per year. This would yield interesting information on the disk mass ...
2007-01-01
Energy Technology Data Exchange (ETDEWEB)
Rhodopseudomonas viridis was grown in liquid culture at 30 degrees C anaerobically in light (generation time, 13 h) and under microaerophilic growth conditions in the dark (generation time, 24 h). The bacterium could be cloned at the same temperature anaerobically in light (1 week) and aerobically in the dark (3 to 4 weeks) if oxygen was limited to 0.1%. Oxygen could not be replaced by dimethyl sulfoxide, potassium nitrate, or sodium nitrite as a terminal electron acceptor. No growth was observed anaerobically in darkness or in the light when air was present. A variety of additional carbon sources were used to supplement the standard succinate medium, but enhanced stationary-phase cell density was observed only with glucose. Conditions for induction of the photosynthetic reaction center upon the change from microaerophilic to phototrophic growth conditions were investigated and optimized for a mutant functionally defective ...
1989-05-01
Measurement of unpolarized semi-inclusive pi+ electroproduction off the proton
Semi-inclusive pi+ electroproduction on protons has been measured with the CLAS detector at Jefferson Lab. The measurement was performed on a liquid-hydrogen target using a 5.75 GeV electron beam. The complete five-fold differential cross sections were measured over a wide kinematic range in Q2, x, z, and pT and over the complete range of azimuthal angles, phi, enabling us to separate the different structure functions, H2+eps*H1, H3 and H4. Our measurements of H2 at low-x were found to be in fairly good agreement with pQCD calculations, suggesting a precocious factorization of the process. Indeed, the conventional f(x)*D(z) term can account for almost all of the observed cross section, even at small z. The measured xF-distributions are in qualitative agreement with high energy data, which suggests a surprising numerical similarity between the spectator diquark fragmentation in the present reaction and the anti-quark fragmentation measured in ...
2008-01-01
Heat transfer and hydraulics of liquid metal-gas two-phase magnetohydrodynamic flow
International Nuclear Information System (INIS)
Local properties and heat transfer have been investigated in a NaK-nitrogen two-phase flow in a vertical tube under transverse magnetic field. An objective two-phase flow regime identification was also carried out systematically, using the probability distribution function of two-phase electromagnetic flowmeter signals. The application of a magnetic field was bound to bring about a drastic change in the void fraction profile, i.e., asymmetric profile perpendicular to the field direction. This effect was more remarkably observed in bubbly flows. The magnetic field was also observed to decrease the number of bubbles, by promoting the agglomeration of small bubbles into larger ones and also break-up of large slugs, and, thus, to shift the flow regime boundaries. It has been also shown that the two-phase Nusselt number increases in bubbly flows, while it decreases in slug flows. This trend however reduces in the presence of a ...
1986-08-01
Forecasting neutrino masses from combining KATRIN and the CMB: Frequentist and Bayesian analyses
We present a showcase for deriving bounds on the neutrino masses from laboratory experiments and cosmological observations. We compare the frequentist and Bayesian bounds on the effective electron neutrino mass m_beta which the KATRIN neutrino mass experiment is expected to obtain, using both an analytical likelihood function and Monte Carlo simulations of KATRIN. Assuming a uniform prior in m_beta, we find that a null result yields an upper bound of about 0.17 eV at 90% confidence in the Bayesian analysis, to be compared with the frequentist KATRIN reference value of 0.20 eV. This is a significant difference when judged relative to the systematic and statistical uncertainties of the experiment. On the other hand, an input m_beta=0.35 eV, which is the KATRIN 5sigma detection threshold, would be detected at virtually the same level. Finally, we combine the simulated KATRIN results with cosmological data in the form of present (post-WMAP) and ...
2007-01-01
Exploring the 2D to 3D dimensionality crossover in thin iron films
Energy Technology Data Exchange (ETDEWEB)
The temperature dependence of the spontaneous magnetization of epitaxial iron films with a thickness ranging from d=20 to 200nm has been measured. The films are grown on GaAs (100) substrates which are covered by a 150nm thick silver (100) buffer layer. For three-dimensional BCC iron it was observed already in 1929 that saturation of the spontaneous magnetization for T->0 is perfectly described by a T{sup 2} power law. On the other hand, for thin two-dimensional (2D) iron films a T{sup 3/2} law has been established in many recent experimental investigations. In our iron films grown on diamagnetic silver, this dimensionality change occurs at a thickness between d=100 and 200nm. Comparison of the here-observed T{sup 3/2} coefficients with those on iron films grown on paramagnetic tungsten (110) shows that the 2D interactions are {approx}20 times larger in the films on tungsten. Recent results on Fe films which are grown directly on GaAs ...
2006-05-15
International Nuclear Information System (INIS)
The structural, morphological and optical properties of vacuum-evaporated CdTe thin films were investigated as a function of substrate temperature and post-deposition annealing without and with CdCl2/treatment at 400 C for 30 min. Diffraction patterns are almost the same exhibiting higher preferential orientation corresponding to (111) plane of the cubic phase. The intensity of the (111) peak increased with the CdCl2/annealing treatment. The microstructure observed for all films following the CdCl2/annealing treatment are granular, regardless of the as-deposited microstructure. The grain sizes are increased after the CdCl2/annealing treatment but now contain voids around the grain boundaries. The optical band gaps, Eg, were found to be 1.50, 1.50 and 1.48 eV for films deposited at 200 K and annealed without and with CdCl2/treatment at 400 C for 30 min respectively. A progressive sharpening of the absorption edge upon heat treatment particularly ...
2007-09-01
Energy Technology Data Exchange (ETDEWEB)
The real-time neutron radiography system of the Kyoto University Reactor (KUR) has been practically applied to penetrating the side plates containing boron burnable poison to test MTR type reactor fuels and to investigation of moving objects. Compared with the image obtained by the direct film method, however, the image from the TV system is in low-contrast and poor-resolution. This paper presents some digital processing approaches to improve the image quality and the neutron TV system is successfully applied to neutron computed tomography (NCT). The frame summing technique is effective to increase the quality of the radiographic image. By using the NTV system in NCT, the projection data are able to be acquired in a single measurement as observing the projection image on a CRT monitor. Two weighting functions based on the Fourier-convolution algorithm are employed to obtain the reconstructed image. The image quality could be satisfactory to ...
1984-09-01
International Nuclear Information System (INIS)
The real-time neutron radiography system of the Kyoto University Reactor (KUR) has been practically applied to penetrating the side plates containing boron burnable poison to test MTR type reactor fuels and to investigation of moving objects. Compared with the image obtained by the direct film method, however, the image from the TV system is in low-contrast and poor-resolution. This paper presents some digital processing approaches to improve the image quality and the neutron TV system is successfully applied to neutron computed tomography (NCT). The frame summing technique is effective to increase the quality of the radiographic image. By using the NTV system in NCT, the projection data are able to be acquired in a single measurement as observing the projection image on a CRT monitor. Two weighting functions based on the Fourier-convolution algorithm are employed to obtain the reconstructed image. The image quality could be satisfactory to ...
1984-01-01
Energy Technology Data Exchange (ETDEWEB)
Most of the organic electronic devices are nowadays fabricated under poor vacuum conditions. In this regard, there is only little knowledge about the impact of contamination of the metal electrode on the charge injection barrier in this kind of electronic devices. In our study we have performed X-ray and ultra violet photoemission spectroscopy (XPS, UPS) on interfaces between the organic semiconductor -sexithiophene and sputter cleaned (ideal) metals as well as contaminated (realistic) metals. As metal substrates we have used silver, gold, palladium, and platinum. These metals provide us a wide range of metal work functions from 4.2 eV for silver up to 5.5 eV for platinum. For all interfaces of -sexithiophene and contaminated metals we have observed a reduction of the interface dipole and the hole injection barrier. The charge injection barrier in all four cases is almost independent of the underlying metal (within an error of 0.2 eV) and the ...
2007-07-01
TIGER integral-field spectrography and HST/WFPC2 imaging of the E3 galaxy NGC 2974 are used to derive the kinematics of the stellar and ionized gas components in its central 500 pc. We derive a numerical two-integral distribution function from a MGE mass model using the HQ formalism. The TIGER as well as published long-slit stellar kinematics are well fitted with this self-consistent model, requiring neither the addition of a significant mass contribution from a hidden disc structure, nor the presence of a central dark mass. The data reveal the presence of a striking, highly contrasted, two-arm gaseous spiral structure within a radius of ~200 pc, corresponding to a total mass of 6.8x10^4 Msun of ionized gas. We use a deconvolved TIGER datacube to probe its kinematics at a resolution of about 0.35 arcsec. Strong departures from circular motions are observed, as well as high velocity dispersion values on the inner side of the arms. We interpret ...
2003-01-01
DEFF Research Database (Denmark)
The aim of the present study was to test a mathematical model of the biochemical processes in the parathyroid glands responsible for the secretion of parathyroid hormone resulting from extracellular calcium reduction. A double exponential curve described the parathyroid hormone secretion induced by rapid lowering of blood-ionized calcium in humans with normal as well as abnormal parathyroid tissue. Our data show that it was possible to establish a simple mathematical model of the parathyroid hormone response to blood-ionized calcium lowering, sufficient to fit experimental data obtained from patients with abnormal and normal parathyroid tissue. The fitted parameters showed no significant differences between patients with insulin-dependent diabetes mellitus and controls. In primary hyperparathyroidism, the parathyroid hormone production and steady-state transport across the cell membrane were increased, probably due to the larger amount of parathyroid tissue in these patients. These ...
1997-01-01
A MODEL OF THE SPECTRAL EVOLUTION OF PULSAR WIND NEBULAE
International Nuclear Information System (INIS)
We study the spectral evolution of pulsar wind nebulae (PWNe) taking into account the energy injected when they are young. We model the evolution of the magnetic field inside a uniformly expanding PWN. Considering time-dependent injection from the pulsar and coolings by radiative and adiabatic losses, we solve the evolution of the particle distribution function. The model is calibrated by fitting the calculated spectrum to the observations of the Crab Nebula at an age of a thousand years. The spectral evolution of the Crab Nebula in our model shows that the flux ratio of TeV #gamma#-rays to X-rays increases with time, which implies that old PWNe are faint in X-rays, but not in TeV #gamma#-rays. The increase of this ratio is because the magnetic field decreases with time and is not because the X-ray emitting particles are cooled more rapidly than the TeV #gamma#-ray emitting particles. Our spectral evolution model matches the ...
2010-06-01
Multi-functional Biocompatible Coatings
International Science & Technology Center (ISTC)
Multi-functional Bioactive Nano-structured Coatings for Load-Bearing Implants
Energy Technology Data Exchange (ETDEWEB)
The dry deposition of pollutants can be calculated from the concentration of pollutants in the atmosphere and deposition velocity. To calculate deposition velocity, turbulence parameters such as friction velocity and Monin-Obukhov length are used. However, due to the difficulties in observation of turbulence parameters, usually mean values of wind speed and temperature observed using conventional meteorological instruments are used to estimate the dry deposition. The dry deposition velocity is the function of aerodynamic resistance (R{sub a}), sublayer resistance (R{sub b}), surface resistance (R{sub c}). R{sub a} and R{sub b} are calculated from turbulence parameters and R{sub c} is related to surface characteristics. The purpose of the present study is to compare the dry deposition obtained using the data sets of mean values and turbulence parameters measured by sonic anemometer-thermometer. The field ...
1996-12-31
International Nuclear Information System (INIS)
The 177 underground storage tanks at the DOE's Hanford Site contain an estimated 180 million tons of high-level radioactive wastes. It is desirable to remove and concentrate the highly radioactive fraction of the tank wastes for vitrification. Resorcinol-formaldehyde (R-F) resin, an organic ion-exchange resin with high selectivity and capacity for the cesium ion, which is a candidate ion-exchange material for use in remediation of tank wastes. The report includes information on the structure/function analysis of R-F resin and the synthetic factors that affect performance of the resin. CS-100, a commercially available phenol-formaldehyde (P-F) resin, and currently the baseline ion-exchanger for removal of cesium ion at Hanford, is compared with the R-F resin. The primary structural unit of the R-F resin was determined to consist of a 1,2,3,4-tetrasubstituted resorcinol ring unit while CS-100, was composed mainly of a 1,2,4-trisubstituted ring. ...
2004-09-10
Success in geothermal development
International Nuclear Information System (INIS)
Success in geothermal development can be defined as the ability to produce geothermal energy at compatible energy prices to other energy sources. Drilling comprises usually the largest cost in geothermal development, and the results of drilling is largely influencing the final price of geothermal energy. For 20 geothermal fields with operating power plants, the ratio between installed capacity and the total number of well in the field is 1.9 MWe/well. The drilling history in 30 geothermal fields are analyzed by plotting the average cumulative well outputs as function of the number of wells drilled in the field. The range of the average well output is 1-10 MWe/well with the mean value 4.2 MWe/well for the 30 geothermal fields studied. A leaning curve is defined as the number of wells drilled in each field before the average output per well reaches a fairly constant value, which is characteristic for the geothermal reservoir. The range for this ...
Radiation inactivation target size of rat adipocyte glucose transporter
Energy Technology Data Exchange (ETDEWEB)
In situ assembly states of rat adipocyte glucose transport protein in plasma membrane (PM) and in microsomal pool (MM) were assessed by measuring target size (TS) of D glucose-sensitive, cytochalasin B binding activity. High energy radiation inactivated the binding in both PM and MM by reducing the total capacity of the binding (B/sub T/) without affecting the dissociation constant (K/sub D/). The reduction in B/sub T/ as a function of radiation dose was analyzed based on classical target theory, from which TS was calculated. TS in the PM of insulin-treated adipocytes was 58 KDa. TS in the MM of noninsulin-treated and insulin-treated adipocytes were 112 and 109 KDa, respectively. With MM, however, inactivation data showed anomalously low radiation sensitivities at low radiation doses showing a shoulder in the semilog plots, which may be due to an interaction with a radiation sensitive inhibitor. With these results, they propose the following ...
1987-05-01
Energy Technology Data Exchange (ETDEWEB)
In coke-oven operations flue-gas valves are used to switch the regenerator function from rich gas firing to lean gas firing. Compared with the simple geometry of the other parts of the flow path, which comprise flues and regenerators, the narrow and winding passages of the flue-gas valves give rise to relatively high losses in pressure. Without the construction of high (and therefore expensive) chimneys, this means that operating problems may well arise due the inadequate suction capacity. The project focused on the theoretical and experimental analysis of a coke-oven flue-gas valve. The primary aim was to reduce the pressure drop through the valve without modifying its external geomerty. The internal flow characteristics created by different valve geometries under a variety of operating conditions were simulated using the commercial CFD code Fluent/UNS, which provided velocity and pressure distributions. A half-scale model valve was ...
1999-06-01
Oil/electric hybrid heating experiment and demonstration. [Executive summary is a separate volume
Energy Technology Data Exchange (ETDEWEB)
Oil/electric heating systems and energy measuring instrumentation were installed in 50 houses in Deep River, Ontario. These were operated and monitored for two heating seasons to demonstrate their performance and determine the percentage oil placement as a function of heater capacity and control system. All experimental data was stored and processed by computer. It was found that oil furnace utilization efficiency varied from 48 to 59% for an average of 53.5%. Oil displacement ranged from 49 to 83% for 2.5 and 5.0 kW electric heaters controlled by two-stage indoor thermostats. Fuel costs for oil/electric hybrid heating, with 5.0 kW plenum heaters and indoor two-stage thermostats, were 20% less than for oil heating, based on average furnace efficency and 1983 January retail fuel prices. Annual load factors above 37% were achieved for plenum heaters compared to 11.9% for all-electric systems. Space heating requirements were proportional to ...
1983-07-01
International Nuclear Information System (INIS)
On the basis of soil losses records during 10 years, three levels of water erosion were established for two soil (Typical Hapludox and Oxic Dystropept) located on high and medium terraces of alluvial flat plain of piedmont in the Eastern Plains in La Libertad Research Center of CORPOICA. Eighteen 3 x 10 m"2 run-off plots were fitted out on a nonrandom arrangement of nine plots by landscape and three soil use and management treatments: zero grazing Brachiaria decumbens pasture for six years, up land rice, soybean and maize rotations for six years and bare soil for 10 years. Soil losses under these treatments allowed to define three degrees of erosion: slight (N_3 moderate (N_2) and severe (N_3) respectively. From each plot soil samples were taken at two depths for physical analyses. infiltration and resistance to cone penetration were measured in the field. Without exception water erosion produced a detrimental effect on soil physical properties and the hydrological ...
1999-12-01
High power battery test methods for hybrid vehicle applications
Energy Technology Data Exchange (ETDEWEB)
Commonly used EV battery tests are not very suitable for testing hybrid vehicle batteries, which may be primarily intended to supply vehicle acceleration power. The capacity of hybrid vehicle batteries will be relatively small, they will typically operate over a restricted range of states-of-charge, and they may seldom if ever be fully recharged. Further, hybrid propulsion system designs will commonly impose a higher regeneration content than is typical for electric vehicles. New test methods have been developed for use in characterizing battery performance and life for hybrid vehicle use. The procedures described in this paper were developed from the requirements of the government-industry cooperative Partnership for A New Generation of Vehicles (PNGV) program; however, they are expected to have broad application to the testing of energy storage devices for hybrid vehicles. The most important performance measure for a high power battery is its pulse power ...
1997-11-01
Energy Technology Data Exchange (ETDEWEB)
For most cells there exists an optimum cooling rate. Both supraoptimal rates and suboptimal rates can be very damaging. The optimal rate varies enormously from less than or equal to 1/sup 0/C/min for mammalian preimplantation embryos to greater than or equal to 800/sup 0/C/min for the human red cell. Death at supraoptimal rates is the result of the formation of intracellular ice and its recrystallization during warming. Intracellular ice occurs when cells are cooled too rapidly to allow them to equilibrate by the osmotic withdrawal of intracellular water. The definition of too rapid depends chiefly on the size of the cell and its permeability to water. Death at suboptimal rates is a consequence of the major alterations in aqueous solutions produced by ice formation. The chief effects are a major reduction in the fraction of the solution remaining unfrozen at a given temperature and a major increase in the solute concentration of that fraction. Presumably, slow freezing injury is a ...
1980-01-01
Functional Characterization of Melanocyte Stem Cells in Hair Follicles.
In mice, coat pigmentation requires a stem cell (SC) system in which the survival, proliferation, and differentiation of melanocytes (MCs) are regulated by microenvironments in hair follicles (HFs). In vitro systems are required to analyze the behavior of single melanocyte stem cells (MCSCs) and their potential to form SC systems in vivo. We describe here an experimental system for the isolation, self-renewal, and differentiation of MCSCs, as well as an in vivo reconstitution assay for assessing their potential. Using Dct(tm1(Cre)Bee)/CAG-CAT-GFP mice, we show that, in the presence of stem cell factor and basic fibroblast growth factor and the XB2 feeder cell line, purified MCSCs can undergo clonogenic proliferation, resulting in c-Kit(low) side scatter(low) cells. In culture, these cells maintain their capacity to differentiate and reconstitute an MCSC system in HFs. As these cells are present in the upper part of the HF near the bulge region, express only low ...
2011-07-14
First North American longwall in pitching seams proven feasible. [Colorado
Energy Technology Data Exchange (ETDEWEB)
There are 1.4 Gt (1.5 billion st) of recoverable coal under less than 914 m (3,000 ft) of cover in Colorado in pitching seams. Snowmass Coal Co., in cooperation with the US Department of Energy, introduced the longwall mining method in pitching seams to North America. This venture is a coal mining research program directed toward the profitable production of coal under difficult mining conditions as found in pitching seams of the western US. Snowmass Coal classifies pitching seams into the following categories for longwall on the strike in seams 3 m (10 ft) or less thick: Flat = 0 to 10/sup 0/: Normal continuous mines and shuttle cars work efficiently. Slight = 10/sup 0/ to 22/sup 0/: The maximum pitch that rubber tired equipment will function. Moderate = 22/sup 0/ to 40/sup 0/: The angle of repose of mined coal. Steep = 40/sup 0/ to 60/sup 0/: The limit of safe use of this roof support. Vertical = over 60/sup 0/. The longwall roof support covered here will work in ...
1983-12-01
Farm & Ranch Business Management. Second Edition.
This practical guide for the agribusiness manager (the farmer, rancher, and other agribusiness people who work with agricultural commodities, supplies, and services) gives a basic understanding of modern management practices. It provides guidelines that can help them make practical business decisions. Chapter 1 is an introduction that highlights farm management efficiency, decision making, and goals and objectives. The following 11 chapters discuss recordkeeping (importance and purposes of keeping records, types of systems, record book components), financial analysis (cash flow, net worth, income statements and their ratios; whole farm and enterprise analysis; relationships of various analyses), budget analysis (introduction to types and uses of budgets, how to use and analyze a partial budget, enterprise budget and whole farm budget, production principles, cost components), cash flow analysis (projections and analysis, repayment capacity, credit needs, credit ...
1986-12-01
Energy Technology Data Exchange (ETDEWEB)
The feasibility study was conducted on a model project in Vietnam, aimed at solving the environmental pollution problems resulting from use of coal by demonstrating and disseminating the Japan's environmental technologies in the Southeast Asian countries. The feasibility study was conducted for the Cua Ong Coal Preparation Enterprise, which has the largest coal preparation capacity in Vietnam and port facilities. It is treating raw coal from 10 coal mines for classification and preparation, and shipping coal of various types that meet the standards for domestic use and export. The survey results point out that unrecovered coal remains in waste water discharged from the coal preparation plants to pollute the sea area, and that quantity of the refuse increases because of the unrecovered coal it contains. The environmental technologies needed to introduce include modification to variable wave pattern type jigging separator, refuse height measuring instrument ...
2001-06-01
Evaluation of cobalt mobility in soils from the Nevada Test Site
Energy Technology Data Exchange (ETDEWEB)
Nuclear testing at and around the Nevada Test Site (NTS) resulted in widespread contamination from transuranic and other radionuclides, as well as from other toxic inorganic and organic contaminants. The type of contamination, including spatial distribution and type of radionuclides present, depends on the type of testing performed. Remediation of the contaminated areas is currently under way. The optimum in situ or ex situ remediation technology depends on the degree of interaction between the particular radionuclide, or contaminant in general, and the soil matrix, among other factors. The objective of this project was to evaluate the sorption affinity of NTS soils for common non-transuranic radionuclides. The sorption of cobalt (Co) on soils from two different areas of the NTS, namely the Little Feller and Cabriolet event sites, was studied. Experiments were conducted as a function of pH, solid concentration, total Co concentration, ionic strength, and particle ...
1996-09-01
Energy Technology Data Exchange (ETDEWEB)
A molybdenum (Mo) adsorbent called PZC (Poly Zirconium Compound) with high efficiency of Mo adsorption has been developed in order to generate {sup 99m}Tc from {sup 99}Mo produced from natural Mo by (n, gamma) method. The {sup 99m}Tc generator using PZC has cleared mostly the technical subjects. By the results of many experiments, cold and hot test with {sup 99}Mo activity from low level (10{sup 5} Bq) to high level (10{sup 10} Bq), it has been confirmed that the PZC method can be practically applied for the (n, gamma) {sup 99}Mo-{sup 99m}Tc generator. From the reasons that PZC has the ability and many merits such as high adsorption capacity (>250 mg-Mo/g-PZC) of Mo, high elution yield (av. 80%) of {sup 99m}Tc, the low breakthrough (<0.05 kBq-{sup 99m}Mo/MBq-{sup 99m}Tc) of {sup 99}Mo and others, the current (n, fission) {sup 99m}Tc generator utilizing {sup 99}Mo produced from enriched uranium will be taken the place by PZC method. In this paper, the ...
2003-03-01
Carbon dioxide absorption with aqueous potassium carbonate promoted by piperazine
Energy Technology Data Exchange (ETDEWEB)
This paper presents thermodynamic and kinetic data collected for aqueous blends of piperazine (PZ), an ethylamine, and potassium carbonate (K{sub 2}CO{sub 3}). Mixtures of K{sup +} and PZ have been investigated in a wetted-wall column at 40 to 80{sup o}C, typical conditions for an industrial absorber. The addition of 0.6 m PZ to 20 wt% (3.6 m) K{sub 2}CO{sub 3} increases the rate of CO{sub 2} absorption by a factor of ten from the value in unpromoted solutions at 60{sup o}C. The addition of PZ increases the heat of absorption from 4 kcal/mol in 3.6 m K{sup +} to 10 kcal/mol when 0.6 m PZ is added. The capacity, ranging from 0.4 to 0.7 mol-CO{sub 2}/kg-H{sub 2}O, approaches that of monoethanolamine (MEA) solutions and seems to be a strong function of K{sup +} concentration. Speciation of the solution was obtained using proton nuclear magnetic reasonance (NMR), verifying and quantifying the presence of three PZ species. An equilibrium model and a ...
2003-07-01
Biosorption of Pb(II) and Cd(II) from aqueous solution using green alga (Ulva lactuca) biomass
Energy Technology Data Exchange (ETDEWEB)
The biosorption characteristics of Pb(II) and Cd(II) ions from aqueous solution using the green alga (Ulva lactuca) biomass were investigated as a function of pH, biomass dosage, contact time, and temperature. Langmuir, Freundlich and Dubinin-Radushkevich (D-R) models were applied to describe the biosorption isotherm of the metal ions by U. lactuca biomass. Langmuir model fitted the equilibrium data better than the Freundlich isotherm. The monolayer biosorption capacity of U. lactuca biomass for Pb(II) and Cd(II) ions was found to be 34.7 mg/g and 29.2 mg/g, respectively. From the D-R isotherm model, the mean free energy was calculated as 10.4 kJ/mol for Pb(II) biosorption and 9.6 kJ/mol for Cd(II) biosorption, indicating that the biosorption of both metal ions was taken place by chemisorption. The calculated thermodynamic parameters ({delta}G{sup o}, {delta}H{sup o} and {delta}S{sup o}) showed that the biosorption of Pb(II) and Cd(II) ions ...
2008-03-21
A wirelessly powered and controlled device for optical neural control of freely-behaving animals.
Optogenetics, the ability to use light to activate and silence specific neuron types within neural networks in vivo and in vitro, is revolutionizing neuroscientists' capacity to understand how defined neural circuit elements contribute to normal and pathological brain functions. Typically, awake behaving experiments are conducted by inserting an optical fiber into the brain, tethered to a remote laser, or by utilizing an implanted light-emitting diode (LED), tethered to a remote power source. A fully wireless system would enable chronic or longitudinal experiments where long duration tethering is impractical, and would also support high-throughput experimentation. However, the high power requirements of light sources (LEDs, lasers), especially in the context of the extended illumination periods often desired in experiments, precludes battery-powered approaches from being widely applicable. We have developed a headborne device weighing 2 g ...
2011-06-23
Energy Technology Data Exchange (ETDEWEB)
A new generation of quasimonochromatic high-flux X-ray sources, based on the X-ray radiation produced through Compton scattering between an electron beam and a laser beam, is under development. One of the possible applications of this source is inline phase contrast mammography, based on the observation of the edge-enhancement effect that can be observed at the border of structures inside the breast in images produced using a partially or totally coherent X-ray beam. In this work we present the results of a set of simulations of inline phase contrast mammography using typical inverse Compton scattering sources parameters. The simulated sample was a tumour-like mass having spherical shape, diameter between 200 {mu}m and 5 mm, placed inside a breast-like matrix, 4 cm thick, and a standard composition of 50% glandular tissue and 50% adipose tissue. We discuss the minimum requirements for mammography using inverse Compton scattering sources and we ...
2009-09-01
Thermal release of volatile fission products from irradiated nuclear fuel
International Nuclear Information System (INIS)
An effective procedure for removing _3H, Xe and Kr from irradiated fuels was demonstrated using Shippingport UO"2 fuel. The release characteristics of _3H, Kr, Xe, and I from irradiated nuclear fuel have been determined as a function of temperature and gaseous environment. Vacuum outgassing and a flowing gas stream have been used to vary the gaseous environment. Vacuum outgassing released about 99% of the _3H and 20% of both Kr and Xe within a 3 h at 1500_0C. Similar results were obtained using a carrier gas of He containing 6% H"2. However, a carrier gas containing only He resulted in the release of approximately 80% of the _3H and 99% of both Kr and Xe. These results indicate that the release of these volatile fission products from irradiated nuclear fuel is a function of the chemical composition of the gaseous environment. The rate of tritium release increased with increasing temperature (1100 to 1500_0C) and with the addition of hydrogen to ...
Energy Technology Data Exchange (ETDEWEB)
The wavefunction of a particle extends into the classically forbidden barrier region of the potential energy surface. The consequence of this partial delocalisation is the phenomenon of quantum tunnelling, an effect which enables a particle to penetrate a potential barrier of magnitude greater than the energy of the particle. The tunnelling probability is an exponential function of the particle mass. The effect is therefore an important contribution to the behaviour of light atoms, in particular the proton. The hydrogen bond has long been appreciated to be an essential component of many biological and chemical systems, and the proton transfer reaction in the hydrogen bond is fundamental to many of these processes. The proton behaviour in the hydrogen bonds of benzoic acid, acetylacetone and calix-4-arene has been studied. A variety of techniques, both experimental and computational, were adopted for the study of the three hydrogen bonded systems. The complementary ...
2002-07-01
Grid-Search Location Methods for Ground-Truth Collection from Local and Regional Seismic Networks
Energy Technology Data Exchange (ETDEWEB)
The objective of this project is to develop improved seismic event location techniques that can be used to generate more and better quality reference events using data from local and regional seismic networks. Their approach is to extend existing methods of multiple-event location with more general models of the errors affecting seismic arrival time data, including picking errors and errors in model-based travel-times (path corrections). Toward this end, they are integrating a grid-search based algorithm for multiple-event location (GMEL) with a new parameterization of travel-time corrections and new kriging method for estimating the correction parameters from observed travel-time residuals. Like several other multiple-event location algorithms, GMEL currently assumes event-independent path corrections and is thus restricted to small event clusters. The new parameterization assumes that travel-time corrections are a function of both the event ...
2003-07-24
International Nuclear Information System (INIS)
The effect of measurement geometry on the determination of the activity of solutions containing "1"2"5I for use in brachytherapy applications has been investigated for 5 mL plastic syringes and 2 mL conical glass dose vials as a function of filling mass. New dial settings for the syringes over a filling mass range of 1 to 3 g have been determined to be 497#+-#8 and 469#+-#8 (expanded, k=2, uncertainties) for the NIST Capintec CRC-12 and Capintec CRC-35R, respectively, with any effect due to the filling mass lying within the uncertainty in the activity calibration. A filling mass effect was observed in the dose vials, causing a 10.5% reduction in the chamber response from a 2 g filling mass to 1 g. Dial settings at 2 g were experimentally found to be 143#+-#2 and 135#+-#2 (expanded uncertainties) for the NIST Capintec CRC-12 and Capintec CRC-35R, respectively. The appropriate dial settings for the same vials with a 1 g filling mass were found to ...
2002-07-01
Dielectric dispersion study of Mn-doped PLZT (8/65/35)
International Nuclear Information System (INIS)
Mn-modified Pb0.92La0.08(Zr0.65Ti0.35)O3 (PLZT) was prepared chemically by a coprecipitate method using their respective nitrate salts and isopropoxides. Differential thermal analysis (DTA) and X-ray analysis clearly show the formation of PLZT single rhombohedral phase for samples calcined beyond 750 C. Uniform grain distribution was observed from scanning electron microscopic (SEM) studies and grain size was found to increase with Mn doping up to x=0.08 and then decreased. Dielectric measurement shows the decrease in peak transition temperature (TC) with Mn doping up to x=0.12 and then increase along with a sharp rise in dielectric maxima. A diffuse dielectric dispersion is observed in all the compositions. A detailed dispersion study was carried out using the Vogel-Fulcher empirical relation, a universal relaxation law and the Havriliak-Negami function. The Vogel-Fulcher relation fitting parameters of activation energy ...
2009-07-01
Energy Technology Data Exchange (ETDEWEB)
In this experiments, we established long-termed culture methods of bone marrow stromal cells for proliferation and differentiation of stem cells. And we selected some extracts which support maximal proliferation of stromal cells with this method. We conformed the synergic effects of herbal mixture extracts for stromal cell growth. The proliferation of stromal cells was increased rather by the addition of mixture extracts than by addition of single strain extract. In the previous and cooperative experiments, we selected complex extracts (Him-I, Him-II) which increased the number of nonadherent mononuclear cells. Different cytokine expression patterns were observed stromal cells cultured in the presence or absence of mixture extracts which support differentiation of nonadherent cells. Some fractions of Him-I and Him-II increased the proliferation of bone marrow cells irradiated {gamma}-ray(4Gray). Stimulation of macrophage cell line with herval extracts with the ...
2000-04-01
Stacking the Deck: Idling and Reactivation of Capacity in Offshore Drilling
British Library Electronic Table of Contents (United Kingdom)
Independent drilling contractors own all offshore drilling rigs, which they lease to oil and gas companies for use in their pursuit of their exploration and development plans. Oil and gas companies' demand for these rigs can vary quickly and dramatically in response to changes in the world market for oil and natural gas. As a result, drilling contractors often try to manage excess capacity by idling rigs (known in the industry as "stacking" a rig), reactivating them when demand recovers. This paper examines these decisions over the course of a price cycle in 1998-2000 to investigate the role of firm and rig heterogeneity in determining drillers' decisions about idling and reactivating capacity.
2008-01-01
Energy Technology Data Exchange (ETDEWEB)
In order to ensure a power balance in an electrical network a spinning reserve has to be capable of activation within seconds. However, because of the need to vary the fuel flow in the steam generator, the run-up of output takes minutes. The required capacity response is therefore achieved by storage of steam from the steam generator. In this process the turbine control valves come into action in a specific manner. The paper describes the importance of the initial reserve for unit capacity control. (orig.).
1989-09-01
Pumped storage plants. Status and perspectives
Energy Technology Data Exchange (ETDEWEB)
Pumped storage plants (PSP) enable the storage of energy with rated capacities of order of GW at a single site. Reservoirs allow charging and discharging times of at least hours, sometimes days or even up to several weeks. Short ramp-up times permit the participation in the secondary reserve market as a standing reserve. For bulk energy storage, PSP reach the lowest, specific costs. In the EU27 countries, Norway and Switzerland, a total of 44 GW of pumped storage capacity is installed. The utilisation of PSP strongly correlates with the amount of conventional generation capacity, rather than with topographical options. (orig.)
2011-07-01
High capacity heavy media processing
Energy Technology Data Exchange (ETDEWEB)
Pittston Coal Company recognized the potential economic benefit of improving process efficiency with increased capacity at it`s U.K. No. 1 Coal Preparation Plant. Accordingly, extensive research, both domestically and internationally, was conducted to select the appropriate technologies to achieve the desired circuit in the most cost effective manner while, at the same time, sacrificing neither structural integrity nor process performance. Large diameter heavy media cyclone technology was combined with highly efficient banana type screens and improved high intensity magnetic separators to create a coordinated process circuit that provided high efficiency at very high capacities in an economically attractive package.
1996-12-31
High capacity anode materials for rechargeable sodium-ion batteries
Energy Technology Data Exchange (ETDEWEB)
Electrochemical techniques have been used to study the reversible insertion of sodium into hard-carbon host structures at room temperature. In this paper the authors compare these results with those for lithium insertion in the same materials and demonstrate the presence of similar alkali metal insertion mechanisms in both cases. Despite the gravimetric capacities being lower for sodium than lithium insertion, the authors achieved a reversible sodium capacity of 300 mAh/g, close to that for lithium insertion in graphitic carbon anode materials. Such materials may therefore be useful as anodes in rechargeable sodium-ion batteries.
2000-04-01
Heat capacity measurement of some breeder materials
International Nuclear Information System (INIS)
Isobaric molar heat capacities of powder and microsphere form of Li2TiO3 (s) and powder form of LiAlO2 (s) and Li2ZrO3 (s) were measured using a heat flux type differential scanning calorimeter in the temperature range 320 - 870 K. Specific heat capacities of LiAlO2 (s) was found to be much larger compared to those of Li2TiO3 (s) and Li2ZrO3 (s). (author)
2009-01-07
We analyse the capacity of a simultaneous quantum secure direct communication scheme between the central party and other M parties via M+1-particle GHZ states and swapping quantum entanglement. It is shown that the encoding scheme should be secret if other M parties wants to transmit M+1 bit classical messages to the centre party secretly. However, when the encoding scheme is announced publicly, we prove that the capacity of the scheme in transmitting the secret messages is 2 bits, no matter how large M is.
2006-10-01
Energy Technology Data Exchange (ETDEWEB)
We wanted to evaluate the usefulness of a new type of a complex expandable nitinol stent that was designed to reduce the stent's propensity to migration during the treatment of malignant gastroduodenal obstructions. Two types of expandable nitinol stent were constructed by weaving a single thread of 0.2mm nitinol wire in a tubular configuration: an uncovered stent 18mm in diameter and a covered stent 16mm in diameter. Both ends of the covered stent were fabricated by coaxially inserting the covered stent into the tubular uncovered stent and then attaching the two stents together with using nylon monofilament. Under fluoroscopic guidance, the stent was placed in 29 consecutive patients (20 men and 9 women, mean age: 65 years) who were suffering with malignant gastric outlet obstruction (n=20), duodenal obstruction (n=6) or combined obstruction (n=3). Clinical improvement was assessed by comparing the food intake capacity before and after the procedure. The ...
2005-12-15
The removal and recovery of Cr(VI) by Li/Al layered double hydroxide (LDH)
Energy Technology Data Exchange (ETDEWEB)
Hexavalent Cr has been identified as one of the toxic metals commonly present in industrial effluents. Among the treatment techniques developed for removing Cr(VI) from waste waters, sorption is most commonly applied, due to its simplicity and efficiency. However, few adsorbents can be recycled and reused cost-effectively. In this study, the removal and recovery of Cr(VI) from water using Li/Al LDH was investigated. The removal of Cr(VI) by Li/Al LDH was evaluated in a batch mode. The results demonstrated that Cr(VI) adsorption onto Li/Al LDH occurs by replacing the Cl{sup -} that originally exists in the interlayer of the adsorbent. The degree of Cr(VI) adsorption observed for Li/Al LDH was relatively high and the process occurred rapidly; however, a portion of adsorbed Cr(VI) was gradually desorbed, due to the Li de-intercalation of Li/Al LDH. Lithium de-intercalation from Li/Al LDH with interlayer Cl{sup -} and interlayer Cr(VI) follows the first order kinetics ...
2007-04-02
Energy Technology Data Exchange (ETDEWEB)
V{sub 2}O{sub 5} based compounds are interesting low potential materials for rechargeable cathodes of lithium electrochemical generators. However, the ionic conductivity and the reversibility of electrochemical cycling of V{sub 2}O{sub 5} are limited by the possibilities of lithium insertion. This work shows that the doping of vanadium pentoxide by a M{sup 3+} trivalent transition element (M Fe, Al, Cr or La) allows to intercalate a more important amount of lithium and to improve the behaviour of the material during cycling. These materials of M{sub 0.11}V{sub 2}O{sub 5.16} formula are obtained by sol-gel synthesis. the electrochemical study of the Fe compound has shown that it is a mixed oxide with a behaviour similar to V{sub 2}O{sub 5}. The maximum capacity is of about 2 F/mole in the case of Fe, Al and Cr compounds and of about 1.7 F/mole in the case of La. The structural evolution of the Fe compound has been followed during the chemical insertion of Li and the ...
1996-12-31
Energy Technology Data Exchange (ETDEWEB)
Several recent improved methods for the EGFM are introduced in order to avoid artificial holes seen in the synthetic acceleration spectrum. Furthermore evaluation of input ground motions at Wolsung NPP are performed by varying the source parameters that may control the high-frequency wave radiation and the deviation of the synthetic motions are revealed. The PSHA case studies for four NPP sites (Wolsung, Kori, Uljin, Younggwang) are performed. In the analysis, site-specific attenuation equations developed for Korean NPP sites are employed, and the seismic hazards for the target sites are evaluated in the case where the four kind of seismic source models are considered. Moreover, the PSHA for Wolsung and Younggwang are conducted by using the site-specific attenuation equation with the index of response spectra and the uniform hazard spectra are evaluated for the two sites. The supporting tool for seismic response analysis and the evaluation tool for evaluating annual probability of ...
2005-12-15
Energy Technology Data Exchange (ETDEWEB)
High voltage cathode materials Li-excess layered oxide compounds Li[Ni{sub x}Li{sub 1/3-2x/3}Mn{sub 2/3-x/3}]O{sub 2} (0 < x < 1/2) are investigated in a joint study combining both computational and experimental methods. The bulk and surface structures of pristine and cycled samples of Li[Ni{sub 1/5}Li{sub 1/5}Mn{sub 3/5}]O{sub 2} are characterized by synchrotron X-Ray diffraction together with aberration corrected Scanning Transmission Electron Microscopy (a-S/TEM). Electron Energy Loss Spectroscopy (EELS) is carried out to investigate the surface changes of the samples before/after electrochemical cycling. Combining first principles computational investigation with our experimental observations, a detailed lithium de-intercalation mechanism is proposed for this family of Li-excess layered oxides. The most striking characteristics in these high voltage high energy density cathode materials are (1) formation of tetrahedral lithium ions at voltage less ...
2011-09-06
Growth of Pinus radiada in soil containing solid waste from the kraft pulp industry
Energy Technology Data Exchange (ETDEWEB)
The germination and growth of Pinus radials Don. plantlets in solid residues deriving from a Kraft pulp industry was evaluated. Plant conditions were monitored by histological studies of roots and shoot-tips, as well as by plant analyses of several essential and non essential elements. The solids employed consisted of ashes, fly-ashes, dregs, grits, primary sludge, brown stock screening rejects and various mixtures of them. Their addition, in a range of combinations to sandy/metamorphic or marine terrace/clay soils, resulted in effective and sustained growth under greenhouse conditions. Low proportions of wastes favored growth in most cases, indicating that they may act as fertilisers. In some experiments, especially in those where waste was added in proportions ranging from 50% to 60%, germination and/or development were slightly affected. Two-year old field experiments have confirmed that in spite of the high pH values, Na ion content or elevated water retention ...
2000-06-01
Energy Technology Data Exchange (ETDEWEB)
The operation of Diesel engines on gaseous fuels, commonly known as dual fuel engines, uses Diesel fuel as the pilot fuel and gaseous fuel (methane and sometimes propane in the present work) as the main fuel. The gaseous fuel was inducted in the intake manifold to mix with the intake air. The investigation was conducted on a high speed indirect injection (Ricardo-E6) dual fuel engine and was concerned with the effects of exhaust gas recirculation (EGR) on the dual fuel engine combustion and emissions, in particular, the effects of intake air temperature and diluent admissions (N{sub 2} and CO{sub 2}) on combustion and emissions. The use of diluents to displace oxygen (O{sub 2}) in the intake air resulted in a reduction in the O{sub 2} supplied to the engine, increased the inlet charge thermal capacity (thermal effect) and, potentially, CO{sub 2} and N{sub 2} participated in the combustion process (chemical effect). In a separate series of tests, the temperature of ...
2001-05-01
Determination of dispersion of precious metals on CeO{sub 2}-containing supports
Energy Technology Data Exchange (ETDEWEB)
Precious metal (PM) dispersions on CeO{sub 2}-containing supports were examined. When dispersions were evaluated by the H{sub 2}-O{sub 2} titration method, the CeO{sub 2}-containing supports hide the true redox of PM because of the large oxygen storage-reduction capacity of the oxide, resulting in higher apparent dispersions than the exact values. When Pt dispersions on the CeO{sub 2} support were evaluated by the ordinary CO pulse method, CO was adsorbed on the CeO{sub 2} support as carbonate species accompanying the oxidation with lattice oxygen. Therefore, the dispersions estimated from the CO uptake were also higher than the exact value. Infrared spectra also clearly evidenced the presence of carbonate species after CO adsorption. To prevent the CO adsorption on CeO{sub 2} as the carbonate species, we treated Pt/CeO{sub 2} with CO{sub 2} before CO adsorption. The strong bands arising from carbonate species on CeO{sub 2} were observed in the ...
2005-09-28
Design and performance of the solar-powered floor heating system in a green building
Energy Technology Data Exchange (ETDEWEB)
In the green building of Shanghai Research Institute of Building Science, the evacuated tubular solar collectors with a total area of 150 m{sup 2} were installed to provide heating for the covered area of 460 m{sup 2}. The floor heating coil pipes were made of high-quality pure copper with the dimension of {phi} 12 x 0.7 mm. Under typical weather condition of Shanghai, the average heating capacity was 25.04 kW during the working hours from 9:00 to 17:00, which was sufficient to keep indoor thermal environment. The average electric COP of the floor heating system was 19.76 during the system operation. Compared with the widely used air-source heat pump heating systems with the electric COP of 3.5 in Shanghai, the solar-powered floor heating system shows great potential in energy conservation in winter. With respect to the whole heating period, the solar fraction was 56%. According to the performance analysis of the system with ambient parameters, it was ...
2009-07-15
Energy Technology Data Exchange (ETDEWEB)
Biosorption using activated sludge biomass (ASB) as a potentially sustainable technology for the treatment of wastewater containing different metal ions (Cd(II), Pb(II) and Zn(II)) was investigated. ASB metal uptake clearly competed with protons consumed by microbial biomass compared with control tests with non-activated sludge biomass. Biosorption tests confirmed maximum exchange between metal ions and protons at pH 2.0-4.5. It was revealed by the study that the amount of metal ions released from the biomass increased with biomass sludge concentration. The result showed that maximum absorption of metal ions was observed for Cd(II) at pH 3.5, Pb(II) at pH 4.0, and pH 4.5 for Zn(II) ions. The maximum absorption capacities of ASB for Cd(II), Pb(II) and Zn(II) were determined to be 59.3, 68.5 and 86.5%, respectively. The biosorption of heavy metals was directly proportional to ASB stabilization corresponding to a reduction in heavy metals in the ...
2010-02-15
Biosorption of Acid Blue 290 (AB 290) and Acid Blue 324 (AB 324) dyes on Spirogyra rhizopus
Energy Technology Data Exchange (ETDEWEB)
In this study, the biosorption of Acid Blue 290 and Acid Blue 324 on Spirogyra rhizopus, a green algae growing on fresh water, was studied with respect to initial pH, temperature, initial dye concentration and biosorbent concentration. The optimum initial pH and temperature values for AB 290 and AB 324 biosorption were found to be 2.0, 30 deg. C and 3.0, 25 deg. C, respectively. It was observed that the adsorbed AB 290 and AB 324 amounts increased with increasing the initial dye concentration up to 1500 and 750 mg/L, respectively. The Langmuir, Freundlich, Redlich-Peterson and Koble-Corrigan isotherm models were applied to the experimental equilibrium data and the isotherm constants were determined by using Polymath 4.1 software. The monolayer coverage capacities of S. rhizopus for AB 290 and AB 324 dyes were found as 1356.6 mg/g and 367.0 mg/g, respectively. The intraparticle diffusion model and the pseudo-second order kinetic model were ...
2006-07-31
International Nuclear Information System (INIS)
A community greenhouse gas emission and energy inventory is an important tool to help local governments plan, implement and monitor climate change mitigation strategies and sustainable energy systems. Inventories can also facilitate a number of other local priorities such as air quality management; integrated land-use and transportation planning; infrastructure optimization and planning; and community economic development planning. The British Columbia government's community energy and emissions inventory initiative (CEEI) intends to collect and centralize high-quality geocoded data to generate high-value community inventories for the province's 185 local governments. This report presented strategic guidance for a comprehensive community emissions inventory system based on a high level review of international best practices. The report described the project objective and scope; guiding principles; research methodology; and inventory limitations. The report provided ...
International Nuclear Information System (INIS)
... um. Water retention capacity is in the range from 40 to 46 %. Dowex
2009-06-14
Regulatory T cells in human disease and their potential for therapeutic manipulation
UK PubMed Central (United Kingdom)
Regulatory T cells are proposed to play a central role in the maintenance of immunological tolerance in the periphery, and studies in many animal models demonstrate their capacity to inhibit inflammatory...Full Text Available
2006-05-01
Hydrogen adsorption by activated charcoal at low pressure and 20/sup 0/K
Energy Technology Data Exchange (ETDEWEB)
Measurements of hydrogen adsorption capacity by activated charcoal has been made at a pressure minus than 10/sup -4/ Pa and at 18 K.
1984-04-01
Energy Technology Data Exchange (ETDEWEB)
Recent developments in rechargeable Li-ion battery technology include the use of lithium-carbon compounds instead of metallic anodes. Non-graphitizable carbons offer high capacity as the anode material but it's large irreversible capacity must be solved. The ultimate goals of the present work are to understand the origin of the high capacity and large irreversible capacity in conjunction with the structural change due to Li intercalation and thus to establish a scientific basis for optimizing their performance in real batteries. 'House of cards' model is considered and emphasis is given to find out the size of the pores present in the carbon fibers prepared from an isotropic petroleum pitch and heat treated at 1200degC. Small angle neutron scattering and wide angle neutron scattering results provide enlargement of pores and d-spacing of grapheme layers after Li intercalation. ...
2001-03-01
Energy Technology Data Exchange (ETDEWEB)
In this paper, the moisture buffering capacity of spruce plywood is measured by recording the change in mass of a test specimen when the air relative humidity (RH) is changed between 33% RH and 75% RH. The aim is to represent diurnal cycles in indoor humidity with 33% RH maintained for 16 h and 75% RH maintained for 8 h. Measurements are taken using two different apparatuses, which provide different convective transfer coefficients between the air and the plywood, and the results are compared to a numerical model for validation. The validated numerical model is then used to investigate the effect of initial conditions, boundary conditions and thickness on the moisture buffering capacity of plywood. The results show that the buffering capacity of plywood depends on the initial conditions and thickness of the plywood as well as the surface film coefficient and humidity cycle. (author)
2006-07-01
International Nuclear Information System (INIS)
(1976). USSR Lupin, VM Ramazanov, PE Tomskij Gosudarstvennyj Univ.
1976-01-01
Chris Kemp is Named NASA CTO for IT
Jun 23, 2010 ... Recently, NASA CIO Linda Cureton tapped Chris Kemp as the Agency's new Chief Technology Officer for IT. In this new capacity, he will work ...
Building drought management capacity in the Mekong River basin
British Library Electronic Table of Contents (United Kingdom)
Over the past decades the Mekong River basin has experienced several droughts, the most recent of which occurred in the hydrological year 2004/2005. Impacts extended across agriculture, forestry, water resources, supply, industry, transport and the environment. In early 2006, the Mekong River Commission Secretariat initiated close consultations with the MRC member states Cambodia, Lao PDR, Thailand and Vietnam, aiming at the formulation of a common Drought Management Programme, which would enhance the existing drought management capacity and ensure effective support. This paper draws attention to the programme formulation process. It shows how national capacity needs were assessed and synthesized into a basin-wide capacity development programme. The paper concludes that in the context of i...
2008-01-01
Alkaline treatment of biomass fly ash for reactive dye removal from aqueous solution
British Library Electronic Table of Contents (United Kingdom)
Biomass fly ash was treated with alkaline solution to enhance its adsorption capacity of Reactive Black 5 dye. The results revealed that the alkaline concentration, solution to fly ash ratio, treatment temperature and treatment time had a positive effect on the dye adsorption capacity of the treated fly ash (TFA), due to dissolving SiO2 and increasing the proportion of unburned carbon. In addition, the dye adsorption behavior of the TFA in aqueous solution was investigated. The effects of various experimental parameters (initial pH, initial dye concentration and contact time) were determined spectrophotometrically. The dye adsorption capacity of the TFA was maximized at an alkaline pH (8.2-10.4). The adsorption capacity of dye by the TFA increased with increasing initial dye concentration....
2010-01-01
A nanosized silicon thin film as high capacity anode material for Li-ion rechargeable batteries
Energy Technology Data Exchange (ETDEWEB)
Silicon thin film with thickness in range 1000-5300 A deposited on rough Cu foil by a radio frequency magnetron sputtering is used as anode materials for Li-ion rechargeable batteries. The SEM, XRD and TEM analysis reveals that the Si thin film has a floccular nano-sized multi-crystalline structure. Li ions insertion/extraction evaluation is performed mainly with constant current charge/discharge cycling and cyclic voltammetry (CV) at room temperature. The cycleability and reversible discharge capacity are found to depend on the film thickness, and thinner films give larger accommodation capacity. A 3120 A Si film provides a reversible specific capacity over 3500 mA hg{sup -1} with excellent cycleability under 0.5 C charge/discharge rate.
2006-07-15
This report describes the design of, and image reconstruction capacity of a Hadamard Raman Microscopic imager. Microscopy of benzoic acid and graphite electrodes, as well as electrophoretic blotting, are described. (CBS)
1990-01-01
Asymptotic numbers, asymptotic functions and distributions
International Nuclear Information System (INIS)
The asymptotic functions are a new type of generalized functions. But they are not functionals on some space of test-functions as the distributions of Schwartz. They are mappings of the set denoted by A into A, where A is the set of the asymptotic numbers introduced by Christov. On its part A is a totally-ordered set of generalized numbers including the system of real numbers R as well as infinitesimals and infinitely large numbers. Every two asymptotic functions can be multiplied. On the other hand, the distributions have realizations as asymptotic functions in a certain sense. (author).
2007-05-18
Energy Technology Data Exchange (ETDEWEB)
These studies were undertaken to assess the effects of increased galactose (v increased glucose) metabolism via the polyol pathway on vascular filtration function in the kidneys, eyes, nerves, and aorta. Quantitative radiolabeled tracer techniques were used to assess glomerular filtration rate (GFR) and regional tissue vascular clearance of plasma 131I-bovine serum albumin (BSA) in five groups of male Sprague-Dawley rats: nondiabetic controls, streptozotocin-diabetic rats, nondiabetic rats fed a 50% galactose diet, diabetic rats treated with sorbinil (an aldose reductase inhibitor), and galactose-fed rats treated with sorbinil. Sorbinil was added to the diet to provide a daily dose of approximately .2 mmol/kg body weight. After 2 months of diabetes or galactose ingestion, albumin clearance was increased twofold to fourfold in the eye (anterior uvea, choroid, and retina), sciatic nerve, aorta, and kidney; GFR was increased approximately twofold and urinary excretion ...
1990-07-01
The aggregation of climate change damages. A welfare theoretic approach
International Nuclear Information System (INIS)
The economic value of environmental goods is commonly determined using the concepts of willingness to pay (WTP) or willingness to accept (WTA). However, the WTP/WTA observed in different countries (or between individuals) will differ according to socio-economic characteristics, in particular income. This notion of differentiated values for otherwise identical goods (say, a given reduction in mortality risk) has been criticized as unethical, most recently in the context of the 'social cost' chapter of the IPCC Second Assessment Report. These critics argue that, being a function of income, WTP/WTA estimates reflect the unfairness in the current income distribution, and for equity reasons uniform per-unit values should therefore be applied across individuals and countries. This paper analyses the role of equity in the aggregation of climate change damage estimates, using basic tools of welfare economics. It shows one way of how WTP/WTA estimates ...
1997-01-01
Energy Technology Data Exchange (ETDEWEB)
Eukaryotic genomes encode a zinc finger protein (ZPR1) with tandem ZPR1 domains. In response to growth stimuli, ZPR1 assembles into complexes with eukaryotic translation elongation factor 1A (eEF1A) and the survival motor neurons protein. To gain insight into the structural mechanisms underlying the essential function of ZPR1 in diverse organisms, we determined the crystal structure of a ZPR1 domain tandem and characterized the interaction with eEF1A. The ZPR1 domain consists of an elongation initiation factor 2-like zinc finger and a double-stranded {beta} helix with a helical hairpin insertion. ZPR1 binds preferentially to GDP-bound eEF1A but does not directly influence the kinetics of nucleotide exchange or GTP hydrolysis. However, ZPR1 efficiently displaces the exchange factor eEF1B from preformed nucleotide-free complexes, suggesting that it may function as a negative regulator of eEF1A activation. Structure-based mutational and ...
2007-01-01
International Nuclear Information System (INIS)
The synthesis, characterization of M"vO([CH_3CH_2N(CH_2CH_2S)_2](p-S-Ph-COOCH_2-CH_3)) (M:"9"9"mTc: I, Re: II) is presented in this work, where a pendant ester function is attached to the monothiolate ligand. Chemical structure of I is established after chromatographic comparison with II, synthesized in macroscopic amounts. Complex II is fully characterized by classical methods of analysis showing that the compound adopts a distorted trigonal bipyramidal configuration around the metal. The two sulfur atoms of the tridentate ligand and the oxo group form the basal plane, while the remaining nitrogen atom of the tridentate ligand and the sulfur atom of the monothiolate ligand occupy the apices of the bipyramid. In vitro challenge experiments with glutathione (GSH) in neutral aqueous medium demonstrate, that I suffers nucleophilic attack by GSH and thereby transformation to a more hydrophilic daughter metal compound. Formation of the latter depends on time and GSH ...
1998-08-01
Excitation function of the {sup 64}Ni({alpha},p){sup 67}Cu reaction for production of {sup 67}Cu
Energy Technology Data Exchange (ETDEWEB)
The excitation function of the {sup 64}Ni({alpha},p){sup 67}Cu reaction was measured from threshold up to 24 MeV in order to investigate the possibility of production of the {beta}{sup -}-emitting therapeutic radioisotope {sup 67}Cu (T{sub 1/2}=61.9 h). Two stacks of thin metallic self-supporting foils of {sup 64}Ni (enrichment 77.8%) prepared by electrolytic deposition were irradiated by {alpha}-particle beams. The radioactivity was determined via HPGe detector {gamma}-ray spectrometry. Some {sup 67}Ga activity (which emits the same {gamma}-rays as {sup 67}Cu), formed via the {sup nat}Cu({alpha},x){sup 67}Ga process on trace copper impurity in the Ni foils, was also observed. Corrections were done for {sup 67}Ga activity contribution and for the {sup 67}Cu activity escape fraction from the thin Ni-foil. The maximum cross section of the {sup 64}Ni({alpha},p){sup 67}Cu reaction amounts to 34 mb at 22 MeV. The experimental results were compared ...
2004-01-01
International Nuclear Information System (INIS)
The spike (S) protein of severe acute respiratory syndrome coronavirus (SARS-CoV) has two major functions: interacting with the receptor to mediate virus entry and inducing protective immunity. Coincidently, the receptor-binding domain (RBD, residues 318-510) of SAR-CoV S protein is a major antigenic site to induce neutralizing antibodies. Here, we used RBD-Fc, a fusion protein containing the RBD and human IgG1 Fc, as a model in the studies and found that a single amino acid substitution in the RBD (R441A) could abolish the immunogenicity of RBD to induce neutralizing antibodies in immunized mice and rabbits. With a panel of anti-RBD mAbs as probes, we observed that R441A substitution was able to disrupt the majority of neutralizing epitopes in the RBD, suggesting that this residue is critical for the antigenic structure responsible for inducing protective immune responses. We also demonstrated that the RBD-Fc bearing R441A mutation could not ...
2006-05-26
THE STATE OF STAR FORMATION AND THE INTERGALACTIC MEDIUM AT z #approx# 6
International Nuclear Information System (INIS)
In the context of stellar reionization in the standard cold dark matter model, we analyze observations at z #approx# 6 and are able to draw three significant conclusions with respect to star formation and the state of the intergalactic medium (IGM) at z #approx# 6. (1) An initial stellar mass function (IMF) more efficient, by a factor of 10-20, in producing ionizing photons than the standard Salpeter IMF is required at z #approx# 6. This may be achieved by having either (a) a metal-enriched IMF with a lower mass cutoff of #>=#30 M_s_u_n or (b) 2%-4% of stellar mass being Population III massive metal-free stars at z #approx# 6. While there is no compelling physical reason or observational evidence to support (a), (b) could plausibly be fulfilled by continued existence of some pockets of uncontaminated, metal-free gas for star formation. (2) The volume-weighted neutral fraction of the IGM of
2010-12-10
Laser flash effects on chromatic discrimination in monkeys. Final report, April 1986-June 1987
Energy Technology Data Exchange (ETDEWEB)
Detecting a camouflaged target in a visually noisy background depends on the ability of the observer to discriminate the target from the surrounding terrain. Visible laser irradiation at less than damage levels can act as a masking source by compromising or reducing the observer's ability to resolve differences in the visual scene. Previous research has examined this concept by investigating laser flash effects on: acuity (size discrimination); tracking (motion discrimination); visual sensitivity (color); and contrast sensitivity functions (luminance contrast). In all cases, flashes from continuous-wave (CW) sources have proven more effective visually than pulsed (Q-switched) sources, when compared on peak-energy criteria (i.e., MPE), even though Q-switched lasers induce damage at lower energy doses. Additionally, the inherent safety of ultra-short laser pulses has been questioned. Past animal research has shown ...
1987-10-01
Direct observation of ordered orbital of YTiO{sub 3} by the X-ray magnetic diffraction technique
Energy Technology Data Exchange (ETDEWEB)
X-ray magnetic diffraction (XMD) technique was applied to an orbital ordering compound of ferromagnetic YTiO{sub 3} for the first time. The orbital-magnetic form factor {mu} {sub L}(k) and the spin-magnetic form factor {mu} {sub S}(k) were independently measured by utilizing the LS separation ability of the XMD. The {mu} {sub L}(k) was measured for ten reciprocal-lattice points. No significant values of the {mu} {sub L}(k) were observed for most of the reciprocal-lattice points within the estimated statistical errors, which suggested quenching of the orbital moment. The {mu} {sub S}(k) was measured for 22 reciprocal-lattice points. Fourier synthesis of the {mu} {sub S}(k) gave the spin density distribution m {sub S}(r) in the real space. The obtained m {sub S}(r) map shows the characteristic feature of the electron distribution of 3d electron in the t{sub 2g} state of a Ti atom coordinated by O{sup 2-} ions, in which the electrons are distributed away from the ...
2005-08-15
Energy Technology Data Exchange (ETDEWEB)
Spin-polarized liquid helium-3 is prepared by laser optical pumping in low magnetic field and at room temperature, prior to fast liquefaction of the polarized sample. The use of a new helium-3 cryostat enabled us to obtain liquid helium-3 with polarization rates up to 25 % at well-stabilized temperatures (around 0.5 K). We could thereby study the effect of nuclear polarization on liquid-vapour equilibrium, and particularly on the saturated vapour pressure. Very sensitive capacitive gauges were developed. We estimated (to first order in M{sup 2}) the expected effects when the polarization M is suddenly destroyed. These effects were experimentally observed in helium-3/helium-4 mixtures, in pure helium-3, only a transient increase in pressure has been recorded. We then describe in a third part a preliminary experiment which aimed at determining the longitudinal relaxation time T1 in mixtures. Relaxation on the walls is efficiently reduced by a cesium coating and T1s ...
1999-07-15
Energy Technology Data Exchange (ETDEWEB)
Some hypo-stoichiometric Zr-based Laves phase alloys were prepared and studied from a viewpoint of discharge capacity for electrochemical application. After careful alloy design of ZrMn{sub 2}-based hydrogen storage alloys through changing their stoichiometry while substituting or adding some alloying elements, the Zr(Mn{sub 0.2}V{sub 0.2}Ni{sub 0.6}){sub 1.8} alloy reveals relatively good properties with regard to hydrogen storage capacity, hydrogen equilibrium pressure and electrochemical discharge capacity. In order to improve the discharge capacity and rate-capability, Zr is partially replaced by Ti. The discharge capacity of Zr{sub 1-x}Ti{sub x}(Mn{sub 0.2}V{sub 0.2}Ni{sub 0.6}){sub 1.8} (x=0.0, 0.2, 0.3, 0.4, 0.6) alloy electrodes at 30 C reaches a maximum value and decreases as the Ti fraction increases. In view of electrochemical and thermodynamic characteristics, the ...
2000-08-10
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