British Library Electronic Table of Contents (United Kingdom)

Regional Ocean Modeling System (ROMS v 3.0), a three-dimensional numerical ocean model, was previously enhanced for shallow water applications by including wave-induced radiation stress forcing provided through coupling to wave propagation models (SWAN, REF/DIF). This enhancement made it suitable for surf zone applications as demonstrated using examples of obliquely incident waves on a planar beach and rip current formation in longshore bar trough morphology (Haas and Warner, 2009). In this contribution, we present an update to the coupled model which implements a wave roller model and also a modified method of the radiation stress term based on Mellor (2008, 2011a,b,in press) that includes a vertical distribution which better simulates non-conservative (i.e., wave breaking) processes and ...

Science.gov (United States)

We explore the impact of obliquity variations on planetary habitability in hypothetical systems with high mutual inclination. For the hypothetical systems, we restrict our exploration to systems consisting of a solar-mass star, an Earth-mass planet at 1 AU, and 1 or 2 giant planets. We verify that these systems are stable for 108 years with N-body simulations. We then calculate the obliquity variations induced by the orbital architecture on the Earth-mass planets. We find that in some cases the spin axes can rotate through 360 degrees in as little as 10,000 years (John is that right? Can you look through the systems and find the most extreme case of obliquity variation?) Next, we run energy balance models (EBM) on the terrestrial planets to assess surface temperature and ice coverage on the planets' oceans. Finally, we explore differences in the outer edge of the habitable zone for planets with rapid ...

KoreaScience (Korea)

Full Text Available

International Nuclear Information System (INIS)

Planar channeling effects are studied in such well-oriented polycrystalline layers as NiSi_2 and Pb_2Si layers formed on single crystalline Si. Crystalline perfection of such layers is discussed by using the energy- and angular dependences of the axial and planar channeling yields. It has been shown that, in suitable conditions, the energy dependence of the planar yield is more sensitive to the spread of crystallite orientations in polycrystals than that of the axial one. (Auth.).

KoreaScience (Korea)

Full Text Available

CERN Document Server

We define the Bloch spectrum of a quantum graph to be the collection of the spectra of a family of Schr\\"odinger operators parametrized by the cohomology of the quantum graph. We show that the Bloch spectrum determines the Albanese torus, the block structure and the planarity of the graph. It determines a geometric dual of a planar graph. This enables us to show that the Bloch spectrum completely determines planar 3-connected quantum graphs.

CERN Document Server

The predictions of the MSSM are discussed in the light of recent LEP and SLD precision data. The full supersymmetric one loop corrections to the effective weak mixing angle, experimentally determined in LEP and SLD experiments, are considered. It is demonstrated, both analytically and numerically, that, potentially dangerous, large logarithmic sparticle corrections are cancelled. The relative difference factor \\Delta k between the mixing angle defined as a ratio of couplings and the experimentally obtained angle is discussed. It is found that \\Delta k is dominated by the oblique corrections, while the non-oblique overall supersymmetric EW and SQCD corrections are negligible. The comparison of the MSSM with radiative electroweak symmetry breaking to the LEP precision data indicates that rather large values of the soft breaking parameter M_{1/2} in the region greater than 500 GeV are preferred.

International Nuclear Information System (INIS)

This study is concerned to the perforation phenomena of the oblique dual-plate by projectile. Experiment and simulation related to that was carried out. the variables considered in this phenomena include the electrolytic zinc coated steel sheet and carbon steel rod. In the former, the confirmation and projectile velocity possible phenomena of real phenomena is done, the latter, the effect of parameter such as time-step and grid space length is analyzed by using the three-dimensional Lagrangian explicit time-integration finite element code, HEMP. This code use the eight node hexahedral elements and in this study, Von-Mises Criteria is used as the strength model, Mie-Gruneisen is as the Equation of State. The simulation was performed by contrast with the experiment. Through the calibration of the parameter of Lagrangian code, reasonable result was approached.

UK PubMed Central (United Kingdom)

Cilia are important cellular structures that have been implicated in a variety of signaling cascades. In this review, we discuss the current evidence for and against a link between cilia and both the...Full Text Available

UK PubMed Central (United Kingdom)

This paper reviews the development of cerebral scintigraphy from its early days of planar imaging with simple technetium-99m labelled compounds to the recent revival of the technique in the form of...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Single-shot spin-echo diffusion-weighted echo-planar imaging using a phased-array multicoil was performed to distinguish between normal and cirrhotic livers. Sets of 6 images with different b-value were acquired with breath-holding. Significant differences were observed between controls and cirrhosis cases in the signal ratios when the b-value was 383 s/mm{sup 2}, and apparent diffusion coefficients. (orig.)

Energy Technology Data Exchange (ETDEWEB)

The physics of microcavities have been a subject of intense study over the past 25 years. This work stimulated a large body of experimental and theoretical work on the optimization of the light extraction properties of light-emitting diodes. Not only has this led to the current high efficiency microcavity LEDs but also to the high brightness LEDs based on other approaches, which are presently available on the market. An overview of the state of the art of planar semiconductor microcavity LEDs will be presented. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Energy Technology Data Exchange (ETDEWEB)

In the Wajima lung cancer screening program conducted under the auspices of Kanazawa University Hospital, Fuji Computed Radiography (FCR) was utilized in a new chest radiography trial. The results of the screening program are that the necessity of repeat examinations due to poor image quality are less common and the method enables detection of small pulmonary nodular shadows which are possibly candidates for surgery. Oblique chest X-ray with FCR is remarkably effective for the detection and the identification of small lesions. However, the disadvantage of slow processing and high cost must be fully satisfied if FCR is to become a new imaging modality for mass screening.

International Nuclear Information System (INIS)

Instrumental neutron activation analysis (INAA) and radionuclide X-ray fluorescence analysis (RXFA) were used for the determination of rare earth elements. For INAA, solution obtained by sample decomposition was dripped onto filter paper, enclosed and sealed into a polyethylene foil. The sample was activated in reactor WWR-S over a period of 4 to 6 hours with a neutron fluence of 10"1"3cm"-"2. Gamma radiation measurement was carried out with a planar and a coaxial HP-Ge detector in three decay periods. La, Ce, Nd, Sm, Eu, Gd, Tb, Ho, Tm, Yb and Lu were determined. The advantage of the method is its accuracy and high sensitivity, the disadvantage is the time-consuming analysis. The RXFA method was used as a rapid and operative method for the analysis of loose ore samples, aqueous and organic solutions of rare earth elements. For exciting X-ray radiation, "2"4"1Am was used and the radiation of K-lines was detected with a planar Si(Li) detector. ...

Energy Technology Data Exchange (ETDEWEB)

A three-dimensional mathematical thermo-fluid model coupling the electrochemical kinetics with fluid dynamics was developed to simulate the heat and mass transfer in planar anode-supported solid oxide fuel cell (SOFC). The internal reforming reactions and electrochemical reactions of carbon monoxide and hydrogen in the porous anode layer were analyzed. The temperature, species mole fraction, current density, overpotential loss and other performance parameters of the single cell unit were obtained by a commercial CFD code (Fluent) and external sub-routine. Results show that the current density produced by electrochemical reactions of carbon monoxide cannot be ignored, the cathode overpotential loss is the biggest one among the three overpotential losses, and that the proper decrease of the operating voltage leads to the increase of the current density, PEN structure temperature, fuel utilization factor, fuel efficiency and power output of the SOFC. (author)

British Library Electronic Table of Contents (United Kingdom)

An analytical method was proposed for calculating radiative fluxes incident on a planar circular detector from a volume multiple point chemi- or bio-luminescent source inside a coaxial cylindrical reactor. The method was designed for a cylindrical reactor when the surface reflections were neglected and when chemi- or bio-luminescence reaches a detector embedded in the same homogeneous optical medium as the point emitters of the volume multiple point source model. The radiative fluxes from arbitrarily distributed point emitters were expressed by one generalized quadruple-integral formula. Then some double- and single-integral formulas were obtained for calculating radiative fluxes from identically radiating point emitters uniformly distributed within the reactor. Selected results were compu...

British Library Electronic Table of Contents (United Kingdom)

Magnetic pulse welding is a solid state impact welding process, similar to explosive welding, which produces metallurgical bond by oblique high-speed impact between two metal bodies. This violent impact removes the metal surface oxide layers and then joins the two atomic level clean metal surfaces together by the incidental compression pressure. The impact velocity is at 200?400?m/s and the being welded metal surface undergoes severe plastic deformation with strain rate in the order of 106?107?s?1. The ultrafine-grained structure was observed on the welded interface. This article studied two types of similar material lap joint interfaces and the base metals were aluminum alloy 6061 and copper alloy 110. Nano-indentation testing shows that the welded interfaces have significantly greater ha...

Energy Technology Data Exchange (ETDEWEB)

A brief summary of the theory and experiments on electron- cyclotron heating and current drive is presented. The general relativistic formulation of wave propagation and linear absorption is considered in some detail. The O-mode and the X-mode for normal and oblique propagation are investigated and illustrated by several examples. The experimental verification of the theory in T-10 and D- III-D is briefly discussed. Quasilinear evolution of the momentum distribution and related applications as, for instance, non linear wave, damping and current drive, are also considered for special cases of wave frequencies, polarization and propagation. In the concluding section we present the general formulation of the wave damping and current drive in the absence of electron trapping for arbitrary values of the wave frequency. (Author) 13 refs.

British Library Electronic Table of Contents (United Kingdom)

Three complementary impact welding technologies are described in this paper. They are explosive welding, magnetic pulse welding, and laser impact welding, which have been used to provide metallurgical bonds between both similar and dissimilar metal pairs. They share the physical principle that general impact-driven welding can be carried out by oblique impact but are used at different length scales from meters to sub-millimeter. The different length scales require different kinds of systems to drive the process, and the scales themselves can give different weld morphologies. Metallographic analysis on cross-sections shows a wavy interface morphology which is likely the result of an instability associated with jetting, which scours the surfaces clean during impact. The normalized period and...

Energy Technology Data Exchange (ETDEWEB)

This article illustrates what typical accept/reject curves might look like and discusses progress made in developing the required inspection techniques for flaw dimensioning. Consideration is given to the relative significance of blunt versus planar types of flaws, and of inherent limitations to the depths of certain types of flaws. Finally, consideration is given to the realities of implementing proposed procedures under field conditions. These are summarized in a series of technical options for implementation of program results.

Energy Technology Data Exchange (ETDEWEB)

The polarization characteristics of spontaneous radiation from relativistic electrons moving through helical and planar wiggler fields are evaluated for imperfect beam injection. Maximum coherent gain in free-electron laser systems are seen to occur in optical fields having these polarization characteristics rather than those of the wiggler magnets. Coupling coefficients for an electron beam skewed at an angle to the optical mode are presented.

CERN Document Server

Predictions and measurements of a multimode waveguide interferometer operating in a fibre coupled, ``dual-mode'' regime are reported. With a 1.32 micrometer source, a complete switching cycle of the output beam is produced by a 10.0 nanometer incremental change in the 8.0 micrometer width of the hollow planar mirror waveguide. This equates to a fringe spacing of $\\sim\\lambda /130$. This is an order of magnitude smaller than previously reported results for this form of interferometer.

International Nuclear Information System (INIS)

As a method to enhance the sensitivity (S) of an inorganic resist for focused-ion-beam (FIB), lithography, sub-0.1 #mu#m patterning properties of a columnar structural #alpha#-Se_7_5Ge_2_5 resist have been investigated using 30 keV low-energy Ga"+-FIB exposure and CF_4 reactive-ion etching (RIE). development. The Se_7_5Ge_2_5 thin films were 60 .deg. and 80 .deg. -obliquely deposited on Si substrate and parts of the films were annealed for several minutes at the glass transition temperature (T_g=#approx#220 .deg. C). Columnar structures with the angles of approximately 40 .deg. and 65 .deg. are observed in 60 .deg. and 80 .deg. -obliquely deposited films, respectively, and they disappear after annealing. Despite the disappearance of the columnar structures, a critical decrease in thickness is not observed. For the FIB exposures with a beam diameter of #approx#0.1#mu#m and around the threshold dose, the negative-type fine patterns with linewidth ...

Energy Technology Data Exchange (ETDEWEB)

The project has been developing Yttria Stabilized Zirconia (YSZ)-Alumina Composites as an electrolyte of a self-support type planar Solid Oxide Fuel Cell (SOFC) from the following points of view: a path of alumina particles with high thermal conductivity can be designed as an electrolyte sheet; there are some possibilities that the electrolyte can be enhanced in mechanical strength. As previously reported, these composite materials have higher mechanical strength and better thermal shock resistance than those of YSZ. These composites containing 0-30 wt% of Al[sub 2]O[sub 3] were measured by AC impedance method at temperatures of 250-1,000[degree]C. Electrical conductivities of 8YSZ without Al[sub 2]O[sub 3] and a composite consisting of 80 wt% YSZ and 20 wt%Al[sub 2]O[sub 3] as sintered samples were 1.2 x 10[sup -1]S/cm and 1.0 x 10[sup -1]S/cm respectively at 1,000[degree]C. The composite containing 20 wt% of Al[sub 2]O[sub 3] is the most promising candidate ...

International Nuclear Information System (INIS)

This article considers a hypothetical imaging device with a spinning slat collimator that measures parallel-planar-integral data from an object. This device rotates around the object 180 deg. and stops at N positions uniformly distributed over this 180 deg. . At each stop, the device spins on its own axis 180 deg. and acquires measurements at M positions uniformly distributed over this 180 deg. . For a fixed total imaging time, an optimal distribution of the scanning time among the data measurement locations is searched by a nonlinear programming method: Nelder-Mead's simplex method. The optimal dwell time is approximately proportional to the weighting factor in the backprojector of the reconstruction algorithm. By using an optimal dwell-time profile, the reconstruction signal-to-noise ratio has a gain of 23%-24% for the filtered backprojection algorithm and a gain of 10%-18% for the iterative algorithms, compared with the situation when a constant dwell-time ...

International Nuclear Information System (INIS)

We report, for the first time to our knowledge, on the active optical planar waveguides in Nd : YAG laser crystals fabricated by O3+ ion implantation at low doses of ?1014 ions cm-2. The reconstructed refractive index profiles based on the measured dark-mode spectroscopy show that an enhanced refractive index well is created in the near-surface region, forming a non-leaky waveguide structure. With thermal annealing treatment at 260 0C for 90 min, the propagation losses of the waveguides could be reduced to ?3 dB cm-1 at a wavelength of 632.8 nm. The micro-luminescence investigation reveals that the emission bands of Nd3+ ions are not significantly affected by the waveguide formation processing, which shows promising potentials for efficient waveguide laser operations at near-infrared wavelength bands.

CERN Document Server

Harborth [{\\it Elemente der Mathematik}, Vol. 33 (5), 116--118, 1978] proved that every set of 10 points in the plane, no three on a line, contains an empty convex pentagon. From this it follows that the number of disjoint empty convex pentagons in any set of $n$ points in the plane is least $\\lfloor\\frac{n}{10}\\rfloor$. In this paper we prove that every set of 19 points in the plane, no three on a line, contains two disjoint empty convex pentagons. We also show that any set of $2m+9$ points in the plane, where $m$ is a positive integer, can be subdivided into three disjoint convex regions, two of which contains $m$ points each, and another contains a set of 9 points containing an empty convex pentagon. Combining these two results, we obtain non-trivial lower bounds on the number of disjoint empty convex pentagons in planar points sets. We show that the number of disjoint empty convex pentagons in any set of $n$ points in the plane, no three on a line, is at ...

International Nuclear Information System (INIS)

Neutron semiconductor detectors for neutron counting and neutron radiography have an increasing importance. Simple silicon neutron detectors are combination of a planar diode with a layer of an appropriate neutron converter such as 6LiF. These devices have limited detection efficiency of not more than 5%. The detection efficiency can be increased by creating a 3D microstructure of dips, trenches or pores in the detector and filling it with a neutron converter. The first results related to the development of such devices are presented. Silicon detectors were fabricated with pyramidal dips on the surface covered with 6LiF and then irradiated by thermal neutrons. Pulse height spectra of the energy deposited in the sensitive volume were compared with simulations. The detection efficiency of these devices was about 6.3%. Samples with different column sizes were fabricated to study the electrical properties of 3D structures. Charge collection efficiencies in silicon ...

CERN Document Server

It is widely accepted that the prompt transient signal in the 10 keV - 10 GeV band from gamma-ray bursts (GRBs) arises from multiple shocks internal to the ultra-relativistic expansion. The detailed understanding of the dissipation and accompanying acceleration at these shocks is a currently topical subject. This paper explores the relationship between GRB prompt emission spectra and the electron (or ion) acceleration properties at the relativistic shocks that pertain to GRB models. The focus is on the array of possible high-energy power-law indices in accelerated populations, highlighting how spectra above 1 MeV can probe the field obliquity in GRB internal shocks, and the character of hydromagnetic turbulence in their environs. It is emphasized that diffusive shock acceleration theory generates no canonical spectrum at relativistic MHD discontinuities. This diversity is commensurate with the significant range of spectral indices discerned in prompt burst ...

Energy Technology Data Exchange (ETDEWEB)

Previous models of fault-propagation folding used kink-band geometries to approximate folding in front of propagating thrusts. However, kink-band kinematics cannot replicate the curved fold surfaces and complex strain patterns innatural and experimental fault-propagation folds, which also occur in front of steeper reverse and normal faults. Fault-propagation fold hinges tighten and converge downward, forming a triangular zone of penetrative deformation focused on the tip of the propagating fault. The downward convergence of deformation in fault-propagation folds can be modeled as triangular shear zones. Trishear, here defined as distributed, strain-compatible shear in a triangular (in profile) shear zone, provides an alternate kinematic model for fault-propagation folds. Trishear is analogous to simple shear in a tabular shear zone except that area balance in a triangular shear zone requires curved displacement oblique to the fault slip direction. Incremental ...

Energy Technology Data Exchange (ETDEWEB)

When chest radiographs are obtained using an anti-scatter grid in a mobile x-ray unit by Fuji Computed Radiography (FCR), right lung densities may differ from left lung densities owing to misalignment caused by an oblique x-ray beam. Such misalignment is considered to be caused by factors such as the shape of the bed and angle of the x-ray tube. Misalignment is especially frequent when exposure is carried out in the sitting position. Although a low-ratio grid has been reported to offer improvement, the misalignment is not completely eliminated. Therefore, we used a copper plate without a lattice feature instead of grid, and examined the results. The copper plate was found to have the ability of a grid to eliminate radiation scatter, and, furthermore, to offer the physical capabilities of a grid as determined by Carlin's new grid assessment method. Image quality was demonstrated through contrast manipulation to be equal to that obtained by grid use. ...

International Nuclear Information System (INIS)

To aid in the study of lower hybrid current drive as a means of current profile control, the radial profile and velocity distribution of the fast current-carrying electrons and their time evolution must be known. As part of the recent effort to understand this fast electron transport, a diagnostic has been installed on PBX-M to measure the electron cyclotron emission from the fast electrons. An oblique horizontal view of upshifted cyclotron emission in the midplane can give radial as well as velocity space information about the fast electrons. Emission in X mode frequencies refracted by the right-hand cutoff is radially localized. The observed emission at a specific frequency comes only from the radial region r_t_u_r_n=#0. Emission measured by this new diagnostic has been found to be radially localized as predicted. It is also expected that localized moments of the distribution function may be obtained from these data. A superheterodyne receiver at 60--90 GHz has ...

Energy Technology Data Exchange (ETDEWEB)

In this experiment, a beam incident from an oblique direction is reflected by a spherical lens toward the direction of incidence. When the surface of a matter is vibrated by elastic waves, the spherical lens comes into a translation motion that accompanies the vibration. It follows accordingly that the vibration on the surface of the matter may be detected by sensing the spherical lens travelling speed. Three components of the vibration may be determined if beams are focused at one spot from three directions. Detection of the S-wave component by LDV (laser Doppler vibrometer) discloses the complicated wave field in a heterogeneous material, and this physical model experiment may be utilized in various fields of study. For instance, information about problems that may surface in the field work may be collected beforehand in a physical model experiment for developing an S-wave-aided probing method. For the study of seismic wave propagation in a complicated ...

Energy Technology Data Exchange (ETDEWEB)

Objective. The aim of this study was to assess the capability of high-resolution images obtained with a commercially available pelvic phased-array surface coil to demonstrate normal hip anatomy. Design. We retrospectively analyzed the oblique coronal magnetic resonance (MR) images of hips of 36 consecutive patients acquired on a 1.5-T clinical imager using a pelvic phased-array coil as a receiver, a 16-20 cm field of view, and 5 mm slice thickness. Patients. Thirty-six patients were studied, age 15-81 years. There were 20 males and 16 females. Results and conclusions. The articular cartilage, cortex, superior labrum, and iliofemoral ligament were well visualized on proton density weighted fat saturation (PDF) images. The femoral and obturator vessels, obturator nerve, and various muscles were easily seen on T1-weighted images. High-resolution imaging of the hip is achievable in a reasonable amount of time using newer phased-array surface coils and may play an ...

Science.gov (United States)

The aim of the present study focuses on experimentally demonstrating the efficacy of using angularly-variable fiber geometry to achieve the desired tissue-layer selection and probing depths with the further objective of enhancing the sensitivity and specificity of spectral diagnosis in stratified architectures that resemble human cervical epithelia. The morphological and biochemical features of epithelial tissue vary in accordance with tissue depths; consequently, the accuracy of spectroscopic diagnosis of epithelial dysplasia may be enhanced by probing the optical properties of this tissue. When correlated to cellular dysplasia, layer-specific changes in tissue optical properties may be deciphered by reflectance spectroscopy coupled with angularly-variable fiber geometry. This study addresses the utility of using such angularly-variable fiber geometry for resolving spatially-specific spectral signatures of tissue pathology. This is accomplished by interpreting and analyzing the ...

International Nuclear Information System (INIS)

Aim: To create nomograms for renal size as measured from DMSA renal studies, and to test the nomograms for their ability to separate normal from abnormal kidneys. Method: Renal length was measured from posterior oblique views and renal area from posterior views. Results from 253 patients with bilateral normal kidneys were used to create nomograms for renal size relative to patient age, body height, weight or body surface area (BSA). The nomograms enclosed 95% of the normal kidneys, thus indicating the range for 95% confidence limits, and hence the specificity. Each nomogram was then tested against 46 hypertrophied kidneys and 46 damaged kidneys. Results: The results from nomograms of renal length and renal area, compared to age, body height, body weight and BSA are presented. For each nomogram, the range is presented as a fraction of the mean value, and the number of abnormal kidneys (hypertrophied or damaged) outside the normal range is presented as a percentage ...

CERN Document Server

The combination of large thickness ($>3$ $\\mu$m), large--area uniformity (75 mm diameter), high growth rate (up to 0.4 $\\mu$m/min) in assemblies of complex--shaped nanowires on lithographically defined patterns has been achieved for the first time. The nanoscale and the microscale have thus been blended together in sculptured thin films with transverse architectures. SiO$_x$ ($x\\approx 2$) nanowires were grown by electron--beam evaporation onto silicon substrates both with and without photoresist lines (1--D arrays) and checkerboard (2--D arrays) patterns. Atomic self--shadowing due to oblique--angle deposition enables the nanowires to grow continuously, to change direction abruptly, and to maintain constant cross--sectional diameter. The selective growth of nanowire assemblies on the top surfaces of both 1--D and 2--D arrays can be understood and predicted using simple geometrical shadowing equations.

Energy Technology Data Exchange (ETDEWEB)

The authors report a novel configuration for a zinc-particle, packed-bed anode in which an open structure of high hydraulic permeability is maintained indefinitely in a cell with closely spaced walls by the formation of particle bridges and associated gaps. The configuration minimizes electrolyte pumping costs, allows rapid refueling and partial recharge, and provides for 100% zinc consumption. This approach benefits zinc/air fuel batteries by allowing nearly continuous operation and fuel recycle without commercial infrastructure; it benefits Zn/[Fe(CN){sub 6}]{sup {minus}3} batteries by eliminating shape-change and polarization problems found with planar anodes.

International Nuclear Information System (INIS)

This work reports on the use of three state-of-the-art Monte Carlo codes (MCNPX, PENELOPE, FLUKA) in the efficiency calibration of a Broad-Energy Germanium (BEGe) detector. Initial discrepancies found between the experimental and computational efficiency values are related to the poor knowledge of some physical parameters of the detector (dead-layers, crystal dimensions, etc.). As a consequence, a sensitivity analysis was carried out. Each parameter was systematically analyzed, and an accurate model of the detector was determined. The obtained results are consistent, allowing this model to be used in computational efficiency calibrations of the equipment at stake.

Science.gov (United States)

Self-magnetically insulated, high-voltage transmission lines are used in inertial confinement fusion particle accelerators in order to transmit power from the vacuum insulator to the diode. This paper describes a time-dependent 2-D code (MITL) for calculating (for planar or triplate geometries) the motion of test electrons through the tapered input or output convolutes of such lines. MITL results show that the electron canonical momentum in the direction of the flow changes as the electron passes through the convoluted geometry; it is suggested that these electrons lead to losses observed in long self-magnetically insulated lines.

Energy Technology Data Exchange (ETDEWEB)

We consider the radiation of particles (electrons and positrons) undergoing planar channeling in a single crystal of small thickness L. We show that for Lapprox...pi..b/theta/sub L/, where b is the lattice constant and theta/sub L/ is the Lindhard angle, in addition to the principal maxima of spontaneous radiation of channeled particles in the spectrum there are additional interference maxima, and the positions of all maxima of the radiation intensity depend on L. We discuss the dependence of the intensity of radiation at various frequencies on the crystal thickness.

Energy Technology Data Exchange (ETDEWEB)

A variety of engineering and experimental applications require primary support structures which are self-centering. High mechanical strength, low-density, carbon fiber/epoxy matrix composite springs are used in unique planar, cylindrical, conical, and spherical configurations to self-center components. The sinusoidal and triangular-shaped composite springs are readily manufactured and assembled into component hardware. Design considerations, flexural strength properties, load bearing and centering data plus procedures for the manufacture of composite springs are presented.

Energy Technology Data Exchange (ETDEWEB)

The purpose of this paper is to investigate the influence of diabetic myocardial damage (suspected myocardial damage; SMD) diagnosed by [sup 201]Tl-SPECT and diabetic cardiac autonomic neuropathy (AN) on myocardial MIBG uptake in patients with NIDDM. Eighty-seven diabetic patients divided into four subgroups: 23 with SMD (+) AN (+); 19 with SMD (+) AN (-); 27 with SMD (-) AN (+); 18 with SMD (-) AN (-), and 10 controls were studied. Both planar and SPECT images were taken at 30 minutes (early) and 3 hours (delayed) after [sup 123]I-MIBG injection. The heart to mediastinum uptake ratio (H/M) and washout ratio of [sup 123]I-MIBG (WR) were obtained from both planar images. Similarly, the difference between the [sup 201]Tl image and the [sup 123]I-MIBG image in the total uptake score (TUS) was taken as the difference in the total uptake score ([Delta]TUS) representing cardiac sympathetic denervation without SMD. On both early and delayed ...

Science.gov (United States)

The influence of material configuration and impact parameters on the damage tolerance characteristics of sandwich composites comprised of carbon-epoxy woven fabric facesheets and Nomex honeycomb cores was investigated using empirically based response surfaces. A series of carefully selected tests were used to isolate the coupled influence of various combinations of the number of facesheet plies, core density, core thickness, impact energy, impactor diameter, and impact velocity on the damage formation and residual strength degradation due to normal impact. The ranges of selected material parameters were typical of those found in common aircraft applications. The diameter of the planar damage area associated with Through Transmission Ultrasonic C-scan measurements and the peak residual facesheet indentation depth were used to describe the extent of internal and detectable surface damage, respectively. Standard analysis of variance techniques were used to assess the ...

Energy Technology Data Exchange (ETDEWEB)

This paper describes a new time-resolved three-dimensional, three-component (3D-3C) measurement technique called wall-PIV. It was developed to assess near wall flow fields and shear rates near non-planar surfaces. The method is based on light absorption according to Beer-Lambert's law. The fluid containing a molecular dye and seeded with buoyant particles is illuminated by a monochromatic, diffuse light. Due to the dye, the depth of view is limited to the near wall layer. The three-dimensional particle positions can be reconstructed by the intensities of the particle's projection on an image sensor. The flow estimation is performed by a new algorithm, based on learned particle trajectories. Possible sources of measurement errors related to the wall-PIV technique are analyzed. The accuracy analysis was based on single particle experiments and a three-dimensional artificial data set simulating a rotating sphere. (orig.)

British Library Electronic Table of Contents (United Kingdom)

Glass ceramics are commonly used as sealing materials for planar solid oxide fuel cells (SOFCs). The major requirements of stack and module builders for these materials are the stability of the coefficient of thermal expansion (CTE), excellent bonding (sticking) behaviour and the absence of volatile ingredients, which can lead to changes of the material properties and the sealing ability. SCHOTT Electronic Packaging has developed special glasses and glass-ceramics for various solid oxide fuel cell designs and operating temperatures. The glass compositions are based on the system MgO-Al2O3-BaO-SiO2-B2O3. In this study the evaluation of the developed materials was done by high temperature aging tests for up to 1000h, high temperature XRD-studies and Rietveld calculations, combined with scann...

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the work performed by Honeywell during the October 2001 to December 2001 reporting period under Cooperative Agreement DE-FC26-01NT40779 for the U. S. Department of Energy, National Energy Technology Laboratory (DOE/NETL) entitled ''Solid Oxide Fuel Cell Hybrid System for Distributed Power Generation''. The main objective of this project is to develop and demonstrate the feasibility of a highly efficient hybrid system integrating a planar Solid Oxide Fuel Cell (SOFC) and a turbogenerator. The conceptual and demonstration system designs were proposed and analyzed, and these systems have been modeled in Aspen Plus. Work has also started on the assembly of dynamic component models and the development of the top-level controls requirements for the system. SOFC stacks have been fabricated and performance mapping initiated.

International Nuclear Information System (INIS)

We describe a position sensitive photon counting microchannel plate based detector with an improved quadrant anode (QA) readout system. The technique relies on a combination of the four planar elements pattern and an additional fifth electrode. The charge cloud induced by single particle detection is split between the electrodes. The measured charge values uniquely define the position of the initial event. QA has been first published in 1976 by Lampton and Malina. This anode configuration was undeservedly forgotten and its potential has been hardly underestimated. The presented approach extends the operating spatial range to the whole sensitive area of the microchannel plate surface and demonstrates good linearity over the field of view. Therefore, the novel image sensor results in spatial resolution better then 50?m and count rates up to one million events per second.

International Nuclear Information System (INIS)

This paper is concerned with the real time automatic discriminating of flaws from two categories; i. cracks (planar defect) and ii. Non-cracks (volumetric defect such as cluster porosity and slag) using pulse-echo ultrasound. The raw ultrasonic flaws signal were collected from a computerized robotic plane scanning system over the whole of each reflector as the primary source of data. The signal is then filtered and the analysis in both time and frequency domain were executed to obtain the selected feature. The real time feature analysis techniques measured the number of peaks, maximum index, pulse duration, rise time and fall time. The obtained features could be used to distinguish between quantitatively classified flaws by using various tools in artificial intelligence such as neural networks. The proposed algorithm and complete system were implemented in a computer software developed using Microsoft Visual BASIC 6.0 (author)

British Library Electronic Table of Contents (United Kingdom)

Properties of photoconductive ultraviolet detectors fabricated on ZnO films were presented. Highly c-axis oriented ZnO films were grown on glass substrates by pulsed laser deposition. Ultraviolet photodetectors were fabricated based on metal-semiconductor-metal planar structures. The photoresponsivity and the quantum efficiency are much higher in the ultraviolet range than in the visible range, and the peak values are around 360nm. Photocurrent transients show that the detector has a large photocurrent with the peak value of 2.8mA, and a slow photoresponse with a rise time of 5min and a decay time of 7min. The response curve of the detector is fitted well with exponential curve. The large photocurrent should result from the both effects of the accumulation of conduction electrons and the d...

Energy Technology Data Exchange (ETDEWEB)

A new method for analysis and design of smoothing reactances utilising two-dimensional planar models is presented in this paper. Inductance and magnetic flux density are calculated, and their results compared with those measured experimentally. The results obtained are good if compared with those measured once the machine have been built. Moreover, the method herein developed is applied to the calculation of air gap lengths in terms of the desired current and inductance. The kind of reactances studied presents windings in both limbs and air gaps in the four corners (joint of limbs and yokes). The main contribution of this paper is the presentation of a method of industrial application, to be easily developed, with a very important reduction in the time of machine calculation (due to the decrease in the number of nodes and elements compared with the three-dimensional model) for the determination of the air gap length in smoothing reactances. (orig.)

International Nuclear Information System (INIS)

An instrumental neutron activation technique of determining molybdenum in ores is based on measuring gamma-activity of the "9"9Mo isotope with the use of planar and coaxial semiconductor spectrometers. A lot consisting of 50 portions, 0.5 g each, is being irradiated for 10 hours by a flow of neutrons with the density of 10"1"2 n/cm"2xsec. On the lot being allowed to stay for 3-4 days, its activity is measured during 1-5 minutes. Monoethalons based upon phenol-formaldehyde resin are used as standards. The sensitivity of the technique is 10"-"4%, reproducibility error being not higher than 10%, efficiency up to 50 portions for a working shift.

Energy Technology Data Exchange (ETDEWEB)

The tests reported were part of the DOE Geothermal Reservoir Well Stimulation Program. This East Mesa (Imperial Valley, CA) well was successfully stimulated with two fracture treatments, a dendritic fracture and a planar fracture. The natural flow production of the well increased 114 percent, to 197,900 lb/hr. These tests were among the few successful attempts of this program to increase flow from geothermal production wells. The general belief is that these tests worked OK primarily because the formation was sedimentary rock (similar to rock in most oil and gas wells that have been stimulated successfully. Similar tests in geothermal hard rock reservoirs did not work very well. (DJE 2005)

International Nuclear Information System (INIS)

Most surface-acoustic-wave and thin-film optical devices are made by the planar fabrication process. The exposure of the pattern in the polymer film is the first and most crucial step in ensuring desired device geometry, dimensional control, and freedom from pattern distortion. The methods of exposing the polymer film include: optical projection, conventional contact printing, conformable photomask contact printing, holographic recording, scanning electron beam lithography, projection electron lithography, and x-ray lithography. In this paper scanning electron beam lithography, conformable photomask contact printing, holographic recording, and x-ray lithography are discussed. In the last section, ion beam etching of relief structures is discussed.

Energy Technology Data Exchange (ETDEWEB)

Micro-batteries are one of the key components that restrict the application of autonomous Microsystems. However little efforts were made to solve the problem. We have proposed a new planar zinc/air micro-battery, suitable for autonomous microsystem applications. The micro-battery has a layered structure of zinc electrode/alkaline electrolyte/air cathode. A 3D zinc electrode with a high density of posts was designed to obtain a high porosity, hence to offer a best performance. A model of the micro-battery is developed and the device performances were simulated and discussed. A four-mask process was developed to fabricate the prototype micro-batteries. The preliminary testing results showed the micro-batteries is able to deliver a maximum power up to 5 mW, and with an average power of 100 {mu}W at a steady period for up to 2hrs. Fabrication process is still under optimization for further improvement.

Energy Technology Data Exchange (ETDEWEB)

A scheme for controlling multimanipulator systems is presented. The control objective is to coordinate the manipulators to perform parts-matching tasks such as screwing a nut onto a bolt. The task of moving a rigid object can be treated as a special case. Two secondary control objectives internal force control and load distribution can be accomplished within the structure of the control law. The internal force control mechanism keeps the internal forces on the object being manipulated at a desirable level. The load distribution mechanism distributes control effort to each manipulator according to a weighting factor. It is also shown that the control algorithm has a modular structure which facilitates its implementation on a multiprocessor computer. The scheme was tested on a planar scara type dual-manipulator system. A series of experimental results is included to demonstrate the system performance under various conditions.

Energy Technology Data Exchange (ETDEWEB)

This project is concerned with the kinetics and mechanisms of aromatic oxidation and soot and fullerenes formation in flames. The objective of the aromatics oxidation work is to identify and measure the concentration of important intermediates and products in benzene oxidation, and to determine reaction mechanisms and kinetics properties consistent with the behavior seen in flames. The research on soot formation is concerned primarily with the particle inception stages, but the work includes study of soot structure at all stages of growth in order to obtain mechanistic information from evidence of growth steps recorded in the structure of the particles. The ultimate objective is to understand how nascent soot particles are formed from high molecular weight compounds, including the roles of planar and curved PAH and the relationship between soot and fullerenes. The objective of the proposed research on fullerenes is to develop a more comprehensive understanding of ...

CERN Document Server

Mono-layers of stearic and behenic acids deposited with the Langmuir-Blodgett technique, were used as aligning films in nematic liquid crystal cells. During the filling process the liquid crystal adopts a deformed quasi-planar alignment with splay-bend deformation and preferred orientation along the filling direction. This state is metastable and transforms with time into homeotropic once the flow has ceased. The transition is accompanied by formation of disclination lines which nucleate at the edges of the cell. The lifetime of the metastable splay-bend state was found to depend on the cell thickness. On heating, anchoring transition from quasi-homeotropic to degenerate tilted alignment in form of circular domains takes place near the transition to the isotropic phase. The anchoring transition is reversible with a small hysteresis.

Energy Technology Data Exchange (ETDEWEB)

The hydration behavior of a number of square planar Pt(II) bis(cyano) complexes has been examined, and the limiting stoichiometries are related to the steric requirements of the dinitrogen bidentate ligands coordinated to the metal center. In particular, the IR, UV/vis, and [sup 1]H, [sup 13]C, and [sup 195]Pt NMR spectroscopic data for the compound Pt[sup II]dtbipy(CN)[sub 2] [dtbipy = 4,4[prime]-[l brace]C(CH[sub 3])[sub 3][r brace][sub 2]-2,2[prime]-bpy] have been determined and show that, at relative humidities (rh) above [approximately]40%, this complex sorbs five water molecules at room temperature. The sorption process consists of a rapid step in which one H[sub 2]O adds to the complex and which appears to be independent of rh, followed by a slower, rh-dependent step leading to the final stoichiometry. In contrast, the analogous 2,2[prime]-bpy complex sorbs no water under these conditions, while the 4,4[prime]-(CH[sub 3])[sub 2]-2,2[prime]-bpy complex sorbs ...

Science.gov (United States)

An increased compendium of drugs useful in ocular motor system dysfunction has expanded our capacity to treat selected ocular motility disorders. Adjunctive therapeutic modes (e.g., Fresnel prisms and orthoptic exercises) can also be beneficial. PAN and see-saw nystagmus can be treated with baclofen. Downbeat nystagmus may respond to clonazepam therapy, and prisms may help if the nystagmus can be modified with convergence. Congenital nystagmus may respond minimally to drugs (e.g., baclofen), but prisms or surgical procedures, or both, are still the primary treatment modalities. Innovar may be helpful in patients with severe, incapacitating vestibular disorders, and scopolamine alone or in combination with promethazine may be beneficial in patients with milder ambulatory acute peripheral vestibular disorders. Benign positional vertigo is best treated initially with positional exercises before drug therapy is instituted. Opsoclonus and ocular flutter have been treated successfully with ...

Energy Technology Data Exchange (ETDEWEB)

In this work, thermoluminescent dosimeters have been used to measure entrance surface doses (ESDs) of patients undergoing mammographic screening at the University College Hospital, Ibadan, Oyo state. The mean glandular doses (MGDs) were also calculated using the measured ESDs. The results showed that the ESDs ranged from 0.26 mGy to 21.26 mGy for the mediolateral oblique (MLO) views and 0.08 mGy to 5.36 mGy for the craniocaudal (CC) views. The calculated MGD ranged from 0.07 mGy to 3.57 mGy for the MLO views and 0.02 mGy to 0.98 mGy for the CC views. The possible reasons for the large variations in the individual ESD values and MGD values for both views are discussed using patients' data, equipment specific data and the technical parameters used for the examinations. Comparison showed that the mean ESD values and MGD values reported in this work are below published values. The mean of the calculated MGD values is also found to be lower than the recommended ...

Energy Technology Data Exchange (ETDEWEB)

Currently, x-ray mammography is the method of choice in breast cancer screening programmes. As the mammography technology moves from 2D imaging modalities to 3D, conventional computational phantoms do not have sufficient detail to support the studies of these advanced imaging systems. Studies of these 3D imaging systems call for a realistic and sophisticated computational model of the breast. DeBRa (Detailed Breast model for Radiological studies) is the most advanced, detailed, 3D computational model of the breast developed recently for breast imaging studies. A DeBRa phantom can be constructed to model a compressed breast, as in film/screen, digital mammography and digital breast tomosynthesis studies, or a non-compressed breast as in positron emission mammography and breast CT studies. Both the cranial-caudal and mediolateral oblique views can be modelled. The anatomical details inside the phantom include the lactiferous duct system, the Cooper ligaments and the ...

Energy Technology Data Exchange (ETDEWEB)

This paper reported on a new cutting mechanism that cuts fresh wood into small pieces instead of wood chips in order to avoid the problem of fermentation that occurs in storage. The prototype cutting device performs a gradual and oblique cut. It consists of a large auger in which a knife is inserted on the outer edge of the helicoid. Tree trunks up to 20 cm in diameter are fed perpendicularly into the machine and are pushed along the axis where slices are cut off against a fixed sharp-edged counter blade. The cylinder enclosing the auger is the main frame of the machine, and is closed at one end, where a heavy flywheel delivers the energy coming from the tractor's power take-off (PTO). The wood pieces ranging in length from 4 to 19 cm exit through the opposite end. The auger is 700 mm in diameter with a 300 mm pitch spacing. The logs are pushed into the machine by counter-rotating rollers placed in the feed funnel. Tests were conducted to determine the ...

Science.gov (United States)

New tetradentate N(2)O(2) donor Schiff bases and their mononuclear Co(II), Ni(II), Cu(II), and Pd(II) complexes were synthesized and characterized extensively by IR, (1)H-, (13)C-NMR, mass, ESR, conductivity measurements, elemental and thermal analysis. Specifically the magnetic and electronic spectral measurements demonstrate the octahedral structures of cobalt(II), nickel(II) complexes and square planar geometries of copper(II), palladium(II) complexes. All the ligands and complexes were screened for their in vitro antibacterial activity against two gram-positive bacteria (Bacillus subtilis, Staphylococcus aureus) and two gram-negative bacteria (Escherichia coli, Klebsiella pneumonia). In this study, Pd(II) complexes exhibited potent antibacterial activity against B. subtilis, S. aureus whereas other metal complexes also exerted good activity towards all tested strains even than standard drugs streptomycin and ampicillin. PMID:21297294

British Library Electronic Table of Contents (United Kingdom)

New Schiff base derivatives (L1 and L2) were prepared by the condensation of 2-hydroxy-3-methoxybenzaldehyde (o-vanillin) and 3-hydroxy-4-methoxybenzaldehyde (iso-vanillin) with 5-methylfurfurylamine. Two new complexes [Ni(L1)2] and [Cu(L1)2] have been synthesized with bidentate NO donor Schiff base ligand (L1). The Ni(II) and Cu(II) atoms in each complex are four coordinated in a square planar geometry. Schiff bases (L1 and L2) and complexes [Ni(L1)2] and [Cu(L1)2] were characterized by elemental analyses, FT-IR, UV-vis, mass and 1H, 13C NMR spectroscopies. The crystal structures of the ligand (L2) and complexes [Ni(L1)2] and [Cu(L1)2] have also been determined by using X-ray crystallographic technique.

Energy Technology Data Exchange (ETDEWEB)

A comparison of the loss mechanisms in screen-printed solar cells relative to buried contact cells and cells with photolithography-defined contacts is presented in this paper. Model calculations show that emitter recombination accounts for about 0.5% absolute efficiency loss in conventional screen-printed cells with low-sheet-resistance emitters. Ohmic contact to high-sheet-resistance emitters by screen-printing has been investigated to regain this efficiency loss. Our work shows that good quality ohmic contacts to high sheet-resistance emitters can be achieved if the glass frit chemistry and Ag particle size are carefully tailored. The melting characteristics of the glass frit determine the firing scheme suitable for low contact resistance and high fill factors. In addition, small to regular Ag particles were found to help achieve a higher open-circuit voltage and maintain a low contact resistance. This work has resulted in cells with high fill factors (0.782) on high sheet-resistance ...

Energy Technology Data Exchange (ETDEWEB)

Sandia National Laboratories is currently involved in the optimization of a Plane Shock Generator Explosive Lens (PSGEL). The PSGEL component consists of a detonator, explosive, brass cone and tamper housing. The purpose of the PSGEL component is to transmit a plane shock wave through the 4340 steel bulkhead (wave separator) which has a ferro-electric (PZT)ceramic disk attached to the opposite surface of the steel bulkhead. The planar shock wave depolarizes the PZT 65/35 ferro-electric ceramic to produce an electrical output. One aspect of the optimization program involves the possible replacement of 4340 steel with PH13-8Mo steel for the bulkhead. These materials, as well as the PZT 65/35 ferro-electric ceramic and the brass for the cone, required the stock characterization with respect to Hugoniot parameters. The work presented here gives the shock Hugoniot values for these four materials and documents their measurements.

Energy Technology Data Exchange (ETDEWEB)

Properties of photoconductive ultraviolet detectors fabricated on ZnO films were presented. Highly c-axis oriented ZnO films were grown on glass substrates by pulsed laser deposition. Ultraviolet photodetectors were fabricated based on metal-semiconductor-metal planar structures. The photoresponsivity and the quantum efficiency are much higher in the ultraviolet range than in the visible range, and the peak values are around 360 nm. Photocurrent transients show that the detector has a large photocurrent with the peak value of 2.8 mA, and a slow photoresponse with a rise time of 5 min and a decay time of 7 min. The response curve of the detector is fitted well with exponential curve. The large photocurrent should result from the both effects of the accumulation of conduction electrons and the decrease of the barrier height between crystallites. The relaxation time constant {tau} obtained from the curve fitting represents the time accumulation during the process. The ...

British Library Electronic Table of Contents (United Kingdom)

New palladium(II) and platinum(II) complexes of saccharinate (sac), trans-[Pd(py)"2(sac)"2] (1), cis-[Pt(py)"2(sac)"2] (2), trans-[Pd(3-acpy)"2(sac)"2] (3) and cis-[Pt(3-acpy)"2(sac)"2] (4) (py=pyridine and 3-acpy=3-acetylpyridine) have been synthesized. Elemental analysis, UV-Vis, IR, NMR and TG/DTA characterizations have been carried out. The structures of 1-4 were determined by X-ray diffraction. The palladium(II) and platinum(II) ions are coordinated by two N-bonded sac ligands, and two nitrogen atoms of py or 3-acpy, forming a distorted square-planar geometry. The palladium(II) complexes (1 and 3) are trans isomers, while the platinum(II) complexes (2 and 4) are cis isomers. The mononuclear species in the solid state are connected by weak intermolecular C-H...O hydrogen bonds, C-H...@...

Energy Technology Data Exchange (ETDEWEB)

In developing new Tc-99m brain perfusion imaging agents for SPECT, a series of BAT (bis-aminoethanethiol) derivatives was prepared. These N/sub 2/S/sub 2/ ligands formed stable and neutral complexes with reduced Tc-99m, either by Sn(II)-PPi or sodium borohydride reduction. The purity of the Tc-99m complexes was >95% (HPLC reverse-phase column, acetonitrile: pH 7.0 buffer, 85:15). The biodistribution in rats was evaluated using I-125 iodoantipyrine (IAP), a free diffusible tracer, as the internal reference. Compounds with a free hydroxyl group (I and IV) showed lower brain uptake, inspite of high P.C.; this may be related to in vivo instability of the complexes. High initial brain uptake was observed for three compounds (II, III and V), however, only compound V (P.C.=384) showed significant brain retention. Planar imaging with compound V in a monkey demonstrated that the compound localized in brain and the retention time was T/sub 1/2/=35 min. Compounds of this ...

Energy Technology Data Exchange (ETDEWEB)

Many problems in physics necessitate the solution of equations which develop sharp gradients, such as shocks. These include atmospheric shocks near the earth's surface, plasma physics phenomena, both in the laboratory and in space, combustion, petroleum reservoir modelling, and light propagation in glass fibers. To deal with this situation, methods are needed which place a high density of nodes in the neighborhoods of the steep gradients. One of the most promising of these methods is the moving finite element method which was first invented by Miller. This approach, in which the nodes are moved so as to minimize the residual error, has been used successfully by Gelinas, Doss, and co-workers to study several different one-dimensional problems and shows great promise as well in dealing with two dimensions. A paper describing the one-dimensional results has already been published, and a paper describing the two-dimensional results is in preparation. The remainder of this report ...

Energy Technology Data Exchange (ETDEWEB)

Large area, single-element Si(Li) detectors have been fabricated using a novel geometry which yields detectors with reduced capacitance and hence reduced noise at short amplifier pulse-processing times. A typical device employing the new geometry with a thickness of 6 mm and an active area of 175 mm 2 has a capacitance of only 0.5 pf, compared to 2.9 pf for a conventional planar device with equivalent dimensions. These new low capacitance detectors, used in conjunction with low capacitance field effect transistors, will result in x-ray spectrometers capable of operating at very high count rates while still maintaining excellent energy resolution. The spectral response of the low capacitance detectors to a wide range of x-ray energies at 80 K is comparable to typical state-of-the-art conventional Si(Li) devices. In addition to their low capacitance, the new devices offer other advantages over conventional detectors. Detector fabrication procedures, I-V and C-V ...

Science.gov (United States)

We have calculated the on-axis spectrum of spontaneous radiation emitted by an electron moving along a planar undulator that has a magnetic profile along the axis that approximates a square wave. (This could be obtained in practice by driving a ferromagnetic undulator into saturation by excessive current in the windings.) We find considerable enhancement of the harmonic radiation spectrum. We compare the harmonic power emitted by an electron moving through an undulator having a sine-wave field profile with the radiation emitted from an undulator having a square-wave profile; the latter is approximated by the first three Fourier components of the undulator magnetic field profile along the axial direction. Examples are computed for 40MeV electrons taking K < 1, for spontaneous radiation emitted along the axis of the system. The emission at harmonics f > 1 is greatly enhanced for the approximate square-wave magnetic profile: the ratio of the power emitted at f=5 ...

CERN Document Server

The production of X-ray radiation with a high degree of circular polarization constitutes an important goal at XFEL facilities. A simple scheme to obtain circular polarization control with crossed undulators has been proposed so far. In its simplest configuration the crossed undulators consist of pair of short planar undulators in crossed position separated by an electromagnetic phase shifter. An advantage of this configuration is a fast helicity switching. A drawback is that a high degree of circular polarization (over 90%) can only be achieved for lengths of the insertion devices significantly shorter than the gain length, i.e. at output power significantly lower than the saturation power level. The obvious and technically possible extension considered in this paper, is to use a setup with two or more crossed undulators separated by phase shifters. This cascade crossed undulator scheme is distinguished, in performance, by a fast helicity switching, a high degree ...

Energy Technology Data Exchange (ETDEWEB)

A series of cyclic strain controlled tests have been carried out at 600/sup 0/C on three high temperature austenitic iron-based alloys, AISI type 316 stainless steel, Alloy 800 H and Sandvik 253 MA. The tests were carried out under constant total strain control using a constant strain rate of 0.005 s/sup -1/. By considering the changes in modulus throughout the life of each specimen it was found that damage evolution could be successfully predicted as a function of plastic strain range despite the fact that each alloy had been chosen because of a different stress response at 600/sup 0/C. Although each alloy accumulated fatigue damage in a similar manner the longer lives of Sandvik 253 MA and Alloy 800 H at a given total strain range were due to a smaller plastic strain component and a reduced stage I crack propagation rate. In the 253 MA alloy, slip was predominantly planar with some cells occasionally forming at high strain ranges. Slip was localized in Alloy 800 ...

Energy Technology Data Exchange (ETDEWEB)

Pre-stacking depth migration treatment is studied for the estimation of the fold configuration from seismic survey cross sections. The estimation of a velocity structure is necessary for the execution of such treatment, and the utilization of structural-geological knowledge is required for its interpretation. The concept of balanced cross section in relation to the fault-bend fold constructs a stratum structure model under conditions that the deformation during fold and fault formation is a planar strain, that there is no change in volume due to deformation, and that a fold is a parallel fold. In addition to the above geometric and kinetic approach, there is another fold formation process simulation model using a Newtonian fluid for study from the viewpoint of dynamics. This simulation stands on the presumption that the boundary contains a ramp that had been in presence before fold formation and that an incompressible viscous matter is mounted on the top surface. ...

Energy Technology Data Exchange (ETDEWEB)

Although ultrasonic testing inspection technology and tools have improved significantly, there is still a need for more reliable detection, monitoring, and accurate sizing of crack-like and planar defects, complex corrosion damage, and detection of secondary features within deformed pipe. Ultrasonic two dimensional (2D) matrix phased array technology offers some unique advantages that make the technology promising for improving detection and sizing of pipeline flaws resulting from welding or from in-service damage. Ultrasonic modeling and simulation has been conducted to evaluate the detection and sizing capabilities of 2D matrix arrays for various pipeline inspection concepts. Simulations have been performed using both flexible and rigid array probes. Inspection concepts using rigid probes were evaluated for inspections from both the outside and inside pipe surfaces, while flexible probes were evaluated primarily for inspection from the outside surface when dents ...

British Library Electronic Table of Contents (United Kingdom)

In the MnIII complex of the title compound, [MnIII(C18H12N4O2)(H2O)2]ClO4, the MnIII atom is coordinated by four N atoms from the bpb2- [1,2-bis(pyridine-2-carboxamido)benzene] ligand located in the equatorial plane and two O atoms of water molecules at axial positions, yielding a distorted MnN4O2 octahedral coordination geometry. The bpb2- ligand is nearly planar, with a maximum deviation of 0.2311 (3) A from the mean plane. The MnIII complex cation and the perchlorate anion, both of which are located on twofold rotation axes, are connected by O-H...O and C-H...O hydrogen bonds into a three-dimensional supramolecular network structure.

International Nuclear Information System (INIS)

The Compton backscatter technique has been applied to lap-joint in aircraft structure in order to determine mass loss due to exfoliative corrosion of the aluminum alloy sheet skin. The mass loss of each layer has been estimated from Compton backscatter A-scan including the aluminum sheet, the corrosion layer, and the sealant. A Compton backscattering imaging system has been also developed to obtain a cross-sectional profile of corroded lap-splices of aging aircraft using a specially designed slit-type camera. The camera is to focus on a small scattering volume inside the material from which the backscattered photons are collected by a collimated scintillator detector for interpretation of material characteristics. The cross section of the layered structure is scanned by moving the scattering volume through the thickness direction of the specimen. The theoretical model of the Compton scattering based on Boltzmann transport theory is presented for quantitative characterization of ...

International Nuclear Information System (INIS)

At 650"0C, the low-cycle fatigue life was essentially the same for the two alloys on the basis of strain amplitude, but Alloy 800H had a longer life on the basis of stress amplitude. A 500"0C, Alloy 800 and 800H exhibited longer fatigue lifetime than at 650"0C, with Alloy 800 exhibiting a 2-3 times longer life than Alloy 800H when compared on the basis of plastic strain range, whereas the difference was less pronounced when compared on the basis of stress amplitude. When a creep effect was introduced either by way of a hold time or a reduced frequency, Alloy 800 exhibited a greater reduction in life than did Alloy 800H. The dislocation structure changed from planar to cellular with increase in strain range, and extensive precipitation of M_2_3C_6 was noted within the grains for Alloy 800H and along grain boundaries for both alloys. (Auth.).

Energy Technology Data Exchange (ETDEWEB)

Aim: The purpose of this prospective study was to evaluate the value of immunoscintigraphy (ISG) with anti-225.28S in clinically suspected ocular melanoma. Methods: For this purpose standardized ISG was performed in 36 patients using both planar acquisition and emission computed tomography (ECT). Ocular melanoma was present in 31 patients. In 21 patients therapy was enucleation of the eye. These specimens were evaluated by histology and immunohistochemistry in 11 of 21 patients. Results: Regarding the clinical diagnosis, ISG was positive only in 15 of 31 patients with ocular melanoma, regarding histology in 11 of 21 and regarding immunohistochemistry in 5 of 6 patients with a positive immunoreaction. 5 patients showed no immunoreactivity, their ISG was negative. Conclusion: Thus a good correlation between ISG and immunohistochemistry was observed. However ISG using the cutaneous melanoma antibody 225.28S cannot be recommended for the diagnostic work-up of an ocular ...

Energy Technology Data Exchange (ETDEWEB)

An add-on multileaf collimator for electrons (eMLC) has been developed that provides computer-controlled beam collimation and isocentric dose delivery. The design parameters result from the design study by Gauer et al (2006 Phys. Med. Biol. 51 5987-6003) and were configured such that a compact and light-weight eMLC with motorized leaves can be industrially manufactured and stably mounted on a conventional linear accelerator. In the present study, the efficiency of an initial computer-controlled prototype was examined according to the design goals and the performance of energy- and intensity-modulated treatment techniques. This study concentrates on the attachment and gantry stability as well as the dosimetric characteristics of central-axis and off-axis dose, field size dependence, collimator scatter, field abutment, radiation leakage and the setting of the accelerator jaws. To provide isocentric irradiation, the eMLC can be placed either 16 or 28 cm above the isocentre through ...

Energy Technology Data Exchange (ETDEWEB)

The palladium(II) and platinum(II)complexes(where, (M(L){sub 2}X{sub 2}), M=Pd(II), Pt(II); L=isoxazole (isox), 3, 5-dimethylisoxazole(3, 5-diMeisox), 3-methyl, 5-phenylisoxazole(3-Me, 5-Ph-isox), and 4-amino-3, 5-di-methylisoxazole (4-ADI); X=Cl, Br) with isoxazole and its derivatives were investigated on antitumor activity by MM2 and EHMO calculation. Because for all the complexes the {sigma}MO energy level (E{sub {sigma}}{sub (M-X)} between d{sub x}{sup 2}{sub -y}{sup 2} orbital of central metal and p{sub x} orbital of halogen atom is less than {sigma}MO energy level E{sub {sigma}}{sub (M-N)} between d{sub x}{sup 2}{sub -y}{sup 2} orbital of central metal and p{sub x} orbital of N atom, without exception. And judging, from the lower E{sub {sigma}}{sub (M-X)} value in trans, the bonding strength was found to be weaker in trans isomer than in cis. For the Pd(II) and Pt(II) complexes which have planar ligands, it was shown that for all the complexes dissociation of ...

Energy Technology Data Exchange (ETDEWEB)

There are currently no accepted industry standards for the tensile strain limits of girth welds. This paper investigated the behavior of girth welds with buried defects subjected to high longitudinal strains caused by soil movement. A strain design methodology based on a crack driving method was used to examine the factors influencing stain limits along with a constraint-sensitive fracture mechanics approach. No strength undermatching was used in the welds, and the defect location had no influence on crack driving force. The weld joint was assumed to have uniform tensile properties. A 3D finite element (FE) model was used to simulate pipe behavior. Symmetric boundary conditions were imposed on the symmetry planes, and uniform remote axial displacement was applied as the primary loading. Automated data processing routines were developed to extract and analyze the data. The crack driving force was computed directly from a crack tip deformation profile at the deepest point of the defect ...

Energy Technology Data Exchange (ETDEWEB)

The ortho-metalated Pt(II) complexes Pt(ppy)(CO)Cl (1), Pt(ptpy)(CO)Cl (2), and Pt(ppy)(Hppy)Cl (3) (where ppy and ptpy are respectively the ortho-C-deprotonated forms of 2-phenylpyridine and 2-p-tolylpyridine and Hppy is 2-phenylpyridine) have been prepared. The CO ligand is coordinated trans to the nitrogen atom of the ortho-metalated ligand and exerts a strong trans effect resulting in a relatively long Pt-N bond [2.114(19) {angstrom}]. This structure shows both the bidentate ppy ligand and the monodentate Hppy with the nitrogens of these ligands trans to each other. The UV/vis electronic absorption spectra of 1-3 have intense bands in the near-UV region ({approximately}375 nm) which have been assigned as metal to ligand charge transfer (MLCT) transitions, and higher energy bands were assigned as ligand-centered transitions. Each complex exhibits relatively long-lived structured emissions in the solid state at ambient temperature and at 77 K and 77 K glassy toluene solutions. These ...

Energy Technology Data Exchange (ETDEWEB)

The symmetrical complexes [{sup 99m}Tc][TcN(R{sub 2}PS{sub 2}){sub 2}] [R = CH{sub 3}, CH{sub 2}CH{sub 3}, CH{sub 2}CH{sub 2}CH{sub 3}, CH{sub 2}(CH{sub 3}){sub 2}], and the unsymmetrical complex [{sup 99m}Tc][TcN(Me{sub 2}PS{sub 2})(Et{sub 2}PS{sub 2})] have been prepared, at tracer level, through a two-step procedure involving the preliminary formation of a prereduced technetium nitrido intermediate followed by substitution reaction onto this species by the appropriate dithiophosphinate ligand [R{sub 2}PS{sub 2}]Na. The chemical identity of the resulting complexes have been established by comparison with the corresponding {sup 99}Tc-analogs prepared, at macroscopic level, by reacting the complex [{sup 99}TcNCl{sub 4}] [n-Bu{sub 4}N] (n-Bu = n-butyl) with an excess of ligand in methanol, and characterized by elemental analyses and spectroscopic techniques. The complexes are neutral and lipophilic, and possess a square pyramidal geometry, with an apical Tc N group and two ...

International Nuclear Information System (INIS)

Polymer sealing parts are widely used in various branches of engineering as detachable joints that operate at normal and cryogenic temperatures. They are also used in nuclear-power engineering to seal pumps, pipelines, etc., where they operate at 600-650 K under a neutron fluence of around 10"1"6 cm"-"2 (E #>=# 0.18 MeV) and concomitant #gamma#-irradiation of about 10"6 R. The fluoroplastic-based materials currently used degrade when irradiated in water at 320-360 K with a neutron fluence of 10"1"5 cm"-"2 (thermal neutrons) or 10"1"4 cm"-"2 (fast neutrons), and a concomitant #gamma#-irradiation dose of 2 x 10"6 R. The strength of these fluoroplastics decreases markedly after #gamma#-irradiation (from a cobalt source) at room temperature at doses above 10"6 R. For this reason, flexible and swelling graphites are finding ever increasing application. Graflex foils made of extra-pure natural graphite were found to be radiation-resistant and suitable for use as seals and ...

Energy Technology Data Exchange (ETDEWEB)

Quantitative digital imaging, using planar laser light scattering techniques is being developed for the analysis of turbulent and reacting flows. Quantitative image data, implying both a direct relation to flowfield variables as well as sufficient signal and spatial dynamic range, can be readily processed to yield two-dimensional distributions of flowfield scalars and in turn two-dimensional images of gradients and turbulence scales. Much of the development of imaging techniques to date has concentrated on understanding the requisite molecular spectroscopy and collision dynamics to be able to determine how flowfield variable information is encoded into the measured signal. From this standpoint the image is seen as a collection of single point measurements. The present effort aims at realizing necessary improvements in signal and spatial dynamic range, signal-to-noise ratio and spatial resolution in the imaging system as well as developing excitation/detection ...

Energy Technology Data Exchange (ETDEWEB)

This work is a theoretical investigation on the physical properties of semiconductor-based two-dimensional photonic crystals, in particular for what concerns systems embedded in planar dielectric waveguides (GaAs/AlGaAs, GaInAsP/InP heterostructures, and self-standing membranes) or based on macro-porous silicon. The photonic-band structure of photonic crystals and photonic-crystal slabs is numerically computed and the associated light-line problem is discussed, which points to the issue of intrinsic out-of-lane diffraction losses for the photonic bands lying above the light line. The photonic states are then classified by the group theory formalism: each mode is related to an irreducible representation of the corresponding small point group. The optical properties are investigated by means of the scattering matrix method, which numerically implements a variable-angle-reflectance experiment; comparison with experiments is also provided. The analysis of surface ...

Energy Technology Data Exchange (ETDEWEB)

The shock-induced {alpha}(bcc){r_arrow}{var_epsilon}(hcp) transition in iron begins at 13 GPa on the Hugoniot. In the two-phase region above 13 GPa, the Hugoniot lies well above the equilibrium surface defined by G{sub {alpha}}=G{sub {var_epsilon}}, with G the Gibbs free energy. Also, the phase transition relaxation time {tau} is uncertain, with estimates ranging from {lt}50 ns to {approx}180 ns. Here we present an extensive study of these important aspects, metastability and dynamics, of the {alpha}-{var_epsilon} transition in iron. Our primary theoretical tools are (a) accurate theoretically based free energies for {alpha} and {var_epsilon} phases of iron and (b) accurate calculations of the wave evolution following planar impacts. We define metastable surfaces for forward and reverse transitions by the condition that the thermodynamic driving force G{sub {alpha}}{minus}G{sub {var_epsilon}} is just balanced by an opposing force resulting from elastic stresses, ...

International Nuclear Information System (INIS)

Objectives: To minimize movement artifacts during tracer imaging studies, the animals are generally sedated. Although many reports describe the effect of barbiturates on brain function, less is published about the general impact on the extracerebral metabolism and tracer biodistribution. This report describes the influence of pentobarbital on tumor uptake of ["1"2"3I]-2-iodo-L-phenylalanine (["1"2"3I]-2I-L-PA) using dissection and nuclear imaging. Methods: R1M tumor-bearing athymic mice were divided into two populations: untreated and pentobarbital-treated. Each group was subjected to dynamic and static planar imaging and organ dissection after ["1"2"3I]-2I-L-PA injection. Two-compartment blood modeling was performed. Analysis of variance (ANOVA), t test and clustered boxplot analyses were used to compare the results between the treatment groups and between the data acquisition methods. Results: Two-compartment blood modeling demonstrated that pentobarbital ...

Energy Technology Data Exchange (ETDEWEB)

The performance of two-cell planar solid oxide fuel cell stacks using coal syngas, with and without hydrogen sulfide (H{sub 2}S), was studied. All cells were tested at 850 C with a constant current load of 15.2 A (current density of 0.22 A cm{sup -2} per cell) and 30% fuel utilization. The H{sub 2}S injection immediately and significantly affected the power degradation of the stack system regardless of the carrier fuel. Results for the test with only H{sub 2} and N{sub 2} in the presence of H{sub 2}S (119-120 ppm) indicated that the power decay and area-specific resistance (ASR) degradation values were lower than those for the tests where simulated syngas containing CO and increased water content was used. The results indicate that contact points in the stack contributed to the power degradation of the system. Other factors, including contamination from the upstream fuel gas tubing, may have contributed to the higher degradation under simulated syngas conditions. ...

International Nuclear Information System (INIS)

The radical cations from aziridine and azetidine have been characterized by ESR spectroscopy following their generation in the solid state by #gamma# irradiation of dilute solutions of the parent compounds in the CFCl_3 matrix at 77 K. The ESR parameters of the azetidine radical cation are typical of those for nitrogen-centered amine radical cations such as Me_2NH*"+. On the other hand, the radical cation formed from aziridine has very different ESR parameters that compare closely to those for the isoelectronic C...C ring-opened form of the oxirane radical cation and the allyl radical. The radical cation formed from azetidine is therefore assigned a ring-closed structure with the unpaired electron in a 2p/sub z/ orbital on nitrogen perpendicular to the ring plane, whereas the cation from aziridine is an allylic C...C ring-opened planar isomer with the unpaired electron in a nonbonding #pi# orbital centered mainly on the two end carbon atoms. The neutral ...

Energy Technology Data Exchange (ETDEWEB)

A unique beam of pulsed electrons has been developed using the 19-MeV, 700-kA Hermes-III accelerator. The extended planar-anode diode is used to extract at large radius an annular electron beam from the accelerator and inject the resulting beam at small angle into a low-pressure gas cell, where the beam is rapidly charge neutralized and almost current neutralized. Under these conditions, the beam propagates nearly ballistically to a focus downstream of injection, where objects can be placed for irradiation and study. For a focal length of 78 cm, measurements with a segmented calorimeter show that this configuration can deliver an energy deposition of 200 J/g [20 Mrad] over a useful area of 70 cm{sup 2} and a 4-cm depth in graphite in 25 ns. Increasing the injection angle by reducing the AK gap permits higher doses over smaller areas to be achieved. Such beams are of interest for the study of material property changes from short-pulse high-energy depositions and for ...

Energy Technology Data Exchange (ETDEWEB)

The characterization of monoammine(nitroimidazole)platinum(II) complexes of structure (PtCl{sub 2}(NH{sub 3})(NO{sub 2}Im)) (NO{sub 2}Im = 1-((((2-hydroxyethyl)amino)carbonyl)methyl)-2-nitroimidazole, Etanidazole (I), 1-(2-nitro-1-imidazolyl)-3-methoxy2-propanol, Misonidazole (II), and 1-(2-hydroxyethyl)-2-methyl-5-nitroimidazole, Metronidazole (III)) is reported. Both is cis and trans isomers may be isolated for II and III. The crystal structure of cis-amminedichloro(1-((((2-hydroxyethyl)amino)carbonyl)methyl)-2-nitroimidazole)platinum(II) has been determined by X-ray diffraction. The crystals are orthorhombic, space group Pnab with cell dimensions a = 14.867 (7) {angstrom}, b = 9.915 (5) {angstrom}, c = 19.015 (9) {angstrom}, and Z = 8. The structure was refined to R = 0.062 and R{sub w} = 0.052. Platinum has the expected square-planar coordination. The Pt-Cl bond trans to the nitroimidazole ligand is shorter (2.269 (3) {angstrom}) than normal. The dihedral angle ...

Energy Technology Data Exchange (ETDEWEB)

Rectus sheath hematomas are a frequent but sometimes misdiagnosed disease in patients under anticoagulative drugs, hemodialysis, or simply in the elderly. The most frequent localization is in the lower part of the abdomen: the explanation lies in the anatomy of the abdominal wall, especially in the arcuate line of the rectus sheath. Aim of this work is to explain the reason of the almost constant location correlating the anatomy with the CT features. The rectus abdominis muscle lies between the aponeuroses of the transverse and oblique muscles which form the so called rectus sheath. This arrangement is found from the costal arch to a level approximately between the umbilicus and the pubic symphisis, where the rear layer of the rectus sheath ends with a curved edge, called the arcuate or semicircular line of Douglas. Beneath this line the aponeuroses of the three muscles pass in front of the rectus which is separated from the peritoneum only by the fascia ...

Energy Technology Data Exchange (ETDEWEB)

The literature of radiation damage measurements on cadmium zinc telluride (CZT), cadmium telluride (CT), and mercuric iodide (HgI{sub 2}) is reviewed and in the case of CZT supplemented by new alpha particle data. CZT strip detectors exposed to intermediate energy (1.3 MeV) proton fluences exhibit increased interstrip leakage after 10{sup 10} p/cm{sup 2} and significant bulk leakage after 10{sup 12} p/cm{sup 2}. CZT exposed to 200 MeV protons shows a two-fold loss in energy resolution after a fluence of 5 {times} 10{sup 9} p/cm{sup 2} in thick (3 mm) planar devices but little effect in 2 mm devices. No energy resolution effects were noted from moderated fission spectrum of neutrons after fluences up to 10{sup 10} n/cm{sup 2}, although activation was evident. Exposures of CZT to 5 MeV alpha particle at fluences up to 1.5 {times} 10{sup 10} {alpha}/cm{sup 2} produced a near linear decrease in peak position with fluence and increases in FWHM beginning at about 7.5 ...

Energy Technology Data Exchange (ETDEWEB)

Purpose: To evaluated artifacts of unexpended stents and to determine their exact position for MR-guided percutaneous transluminal angioplasty using real-time sequences. Materials and Methods: By using an in vitro model, 11 unexpended stents - 9 nitinol, 1 stainless steel, and 1 cobalt alloy - were investigated by MR. Each stent was studied in a vessel-phantom filled with saline solution. Imaging was performed using five different realtime sequences: fast low angle shot (Flash 2D), fast imaging with steady precession (true FISP, FISP, interactive true FISP) and segmented echo planar imaging (seg. EPI). Artifacts of the introducer system and the stent were calculated by four blinded radiologists (scale: 1 - artifacts, making an excellent contribution to visualization; 2 - artifacts, making mainly a contribution to visualization; 3 - artifacts, making no contribution to visualization). Furthermore, an evaluation of the visibility of the tip of the stent-catheter and ...

Energy Technology Data Exchange (ETDEWEB)

By means of a global mode analysis of ideal MHD modes for Mercier-unstable equilibria in a planar axis L=2/M=10 heliotron/torsatron system with an inherently large Shafranov shift, the conjecture from local mode analysis for Mercier-unstable equilibria given in [N. Nakajima, Phys. Plasmas 3, 4556 (1996)] has been confirmed and the properties of pressure-driven modes, namely, ballooning modes and interchange modes, inherent to such three-dimensional systems have been clarified. The change of the local magnetic shear due to the Shafranov shift, which is related to toroidicity, reduces the field line bending stabilizing effects on ballooning modes. According to the degree of the reduction of the local magnetic shear by the Shafranov shift, the Mercier-unstable equilibria are categorized into toroidicity-dominant (strong reduction) and helicity-dominant (weak reduction) Mercier-unstable equilibria. Since the local magnetic curvature due to helicity has the same period ...

Science.gov (United States)

One-electron reduction of the square-planar nickel precursor (PNP)NiCl ( 1) (PNP (-) = N[2-P(CHMe 2) 2-4-methylphenyl] 2) with KC 8 effects ligand reorganization of the pincer ligand to assemble a Ni(I) dimer, [Ni(mu 2-PNP)] 2 ( 2), containing a Ni 2N 2 core structure, as inferred by its solid-state X-ray structure. Solution magnetization measurements are consistent with a paramagnetic Ni(I) system likely undergoing a monomer dimer equilibrium. The room-temperature and 4 K solid-state X-band electron paramagnetic resonance (EPR) spectra display anisotropic signals. Low-temperature solid-state X-band EPR data at 4 K reveal rhombic values g z = 1.980(4), g x = 2. 380(4), and g y = 2.225(4), as well as a forbidden signal at g = 4.24 for the Delta M S = 2 half field transition, in accord with 2 having two weakly interacting metal centers. Utilizing an S = 1 model, full spin Hamiltonian simulation of the low-temperature EPR spectrum on the solid sample was achieved by ...

Energy Technology Data Exchange (ETDEWEB)

In the context of safety assessment of radioactive waste repositories, complex radionuclide transport models covering key safety-relevant processes play a major role. In recent Swiss safety assessments, such as Kristallin-I, an important drawback was the limitation in geosphere modelling capability to account for geosphere heterogeneities. In marked contrast to this limitation in modelling capabilities, great effort has been put into investigating the heterogeneity of the geosphere as it impacts on hydrology. Structural geological methods have been used to look at the geometry of the flow paths on a small scale and the diffusion and sorption properties of different rock materials have been investigated. This huge amount of information could however be only partially applied in geosphere transport modelling. To make use of these investigations the 'PICNIC project' was established as a joint cooperation of PSI/Nagra and QuantiSci to provide a new geosphere transport ...