WorldWideScience
1

Flow visualization of liquid metal by neutron radiography  

Energy Technology Data Exchange (ETDEWEB)

Thermal hydraulics of a liquid metal is important to design the blanket of a magnetic confined fusion reactor. Since a liquid metal has high thermal and electrical conductivity, the flow characteristics are often different from those of an ordinary liquid like water especially in thermal convection and under a magnetic field. It is difficult to simulate such flows in a liquid metal cooled blanket by water. Flow visualization is a popular method to study thermal hydraulics. Since most of metals are visible by neutron rays, neutron radiography is available to the flow visualization of a liquid metal. The purpose of this study is to develop a visualization technique of the flow in a liquid metal by real-time neutron radiography using the ...

1994-12-31

2

Flow visualization of liquid metal by neutron radiography  

International Nuclear Information System (INIS)

Thermal hydraulics of a liquid metal is important to design the blanket of a magnetic confined fusion reactor. Since a liquid metal has high thermal and electrical conductivity, the flow characteristics are often different from those of an ordinary liquid like water especially in thermal convection and under a magnetic field. It is difficult to simulate such flows in a liquid metal cooled blanket by water. Flow visualization is a popular method to study thermal hydraulics. Since most of metals are visible by neutron rays, neutron radiography is available to the flow visualization of a liquid metal. The purpose of this study is to develop a visualization technique of the flow in a liquid metal by real-time neutron radiography using the ...

1994-07-01

3

Fuel cycle of reactor SVBR-100  

International Nuclear Information System (INIS)

... fast reactors fbr type reactors fuels liquid metal cooled reactors materials nuclear

4

High temperature liquid level sensor  

International Nuclear Information System (INIS)

A length of metal sheathed metal oxide cable is perforated to permit liquid access to the insulation about a pair of conductors spaced close to one another. Changes in resistance across the conductors will be a function of liquid level, since the wetted insulation will have greater electrical conductivity than that of the dry insulation above the liquid elevation.

1983-03-01

5

The transition of metallic crystals nanostructure into the nanostructure of metallic liquids  

International Nuclear Information System (INIS)

The evolution of metallic substance atomic structure is studied on temperature variation including crystal heating up to melting points, a crystal- liquid phase transition and initiation of a high-density liquid specific structure. It is marked that heat induced changes of simple metal structure can be described as changes around a natural elementary cell which is common for both a crystal and a liquid and consists of a central atom and Z_1 atoms of the first coordination sphere. On this basis the vacancy model of melting is verified. Concentrations of melting vacancies are determined by coordination numbers in the form of Z_1/(1+Z_1)"2 which are the same for both a crystal and a natural elementary cell. The size of natural elementary cells is in an agreement with that of the coordination sphere featured in the liquid and phase transition statistical theory. ...

6

Competing Shapes And Alignments In Neutron-Rich Hf Nuclei  

International Nuclear Information System (INIS)

The talk will focus on spin-dependent competition between oblate and prolate shape minima in the potential energy landscape of "1"8"0Hf (the most neutron-rich stable isotope), mediated via the alignment of valence nucleons. Results of a prompt spectroscopic study, using deep inelastic reactions with Gammasphere and CHICO, bombarding a thin "2"3"2Th target with a "1"8"0Hf beam #approx#25% above the Coulomb barrier, will be presented. Nucleon alignments in both prolate and oblate minima will be discussed, as well as the favoring of oblate collective rotation at high spins, observed through a mixing with gamma vibrations built on the prolate shape.

2008-05-12

7

LIQUID NITROGEN CRYOSTAT TO FACILITATE ISOTHERMAL ANNEALING STUDIES ON METALS AFTER HEAVY-PARTICLE BOMBARDMENT  

Science.gov (United States)

A cryostat is described that was developed for irradiating a number of small metal specimens with a high beamcurrent of heavy particles at liquid nitrogen temperature. The specimens, which are mounted on a block, are taken out of the cryostat after irradiation and subsequently annealed in a temperature bath. The progress of annealing is followed by measuring the change in electrical resistivity of the specimens in liquid helium. (auth)

1964-01-01

8

The questions of liquid metal two-phase flow modelling in the FBR core channels  

International Nuclear Information System (INIS)

The two-fluid model representation for calculations of two-phase flow characteristics in the FBR fuel pin bundles with liquid metal cooling is presented and analysed. Two conservation equations systems of the mass, momentum and energy have been written for each phase. Components accounted the mass-, momentum- and heat transfer throughout the interface occur in the macro-field equations after the averaging procedure realisation. The pattern map and correlations for two-fluid model in vertical liquid metal flows are presented. The description of processes interphase mass- and heat exchange and interphase friction is determined by the two-phase flow regime. The opportunity of the liquid metal two-phase flow regime definition is analysed. (author)

2000-06-01

9

Liquid metal flow measurement by neutron radiography  

Energy Technology Data Exchange (ETDEWEB)

Visualization of a liquid metal flow and image processing methods to measure the vector field are carried out by real-time neutron radiography. The JRR-3M real-time thermal neutron radiography facility in the Japan Atomic Energy Research Institute was used. Lead-bismuth eutectic was used as a working fluid. Particles made from a gold-cadmium intermetallic compound (AuCd{sub 3}) were used as the tracer for the visualization. The flow vector field was obtained by image processing methods. It was shown that the liquid metal flow vector field was obtainable by real-time neutron radiography when the attenuation of neutron rays due to the liquid metal was less than l/e and the particle size of the tracer was larger than one image element size digitized for the image processing. (orig.).

1996-07-21

10

Liquid metal flow measurement by neutron radiography  

International Nuclear Information System (INIS)

Visualization of a liquid metal flow and image processing methods to measure the vector field are carried out by real-time neutron radiography. The JRR-3M real-time thermal neutron radiography facility in the Japan Atomic Energy Research Institute was used. Lead-bismuth eutectic was used as a working fluid. Particles made from a gold-cadmium intermetallic compound (AuCd_3) were used as the tracer for the visualization. The flow vector field was obtained by image processing methods. It was shown that the liquid metal flow vector field was obtainable by real-time neutron radiography when the attenuation of neutron rays due to the liquid metal was less than l/e and the particle size of the tracer was larger than one image element size digitized for the image processing. (orig.).

1996-07-01

12

Visualization of a gas-liquid metal two-phase natural circulation flow by a real-time neutron radiography technique  

Energy Technology Data Exchange (ETDEWEB)

In a breeder-type nuclear power plant, liquid metal is used as a coolant due to the high heat capacity factor. Also, some proposals for fusion reactor blanket design include liquid metal as a possible coolant. In both cases the understanding of natural circulation of liquid-metal flow behavior is an integral part of the thermal hydraulic analysis, especially under two-phase flow conditions. Experimental investigations have been conducted to study a liquid metal two-phase natural circulation flow system. A lead-bismuth (PbBi) eutectic mixture is used as a working fluid in a heated metal walled natural circulation loop. Gas injection induces natural circulation through the gas-lift mechanism. A real-time neutron radiography system is used to visualize the two-phase mixture, specifically the interface and the flow regime. ...

1996-06-01

13

Visualization of a gas-liquid metal two-phase natural circulation flow by a real-time neutron radiography technique  

International Nuclear Information System (INIS)

In a breeder-type nuclear power plant, liquid metal is used as a coolant due to the high heat capacity factor. Also, some proposals for fusion reactor blanket design include liquid metal as a possible coolant. In both cases the understanding of natural circulation of liquid-metal flow behavior is an integral part of the thermal hydraulic analysis, especially under two-phase flow conditions. Experimental investigations have been conducted to study a liquid metal two-phase natural circulation flow system. A lead-bismuth (PbBi) eutectic mixture is used as a working fluid in a heated metal walled natural circulation loop. Gas injection induces natural circulation through the gas-lift mechanism. A real-time neutron radiography system is used to visualize the two-phase mixture, specifically the interface and the flow regime. ...

1996-03-10

14

Interface heat transfer of horizontal co-current liquid-liquid stratified flow  

International Nuclear Information System (INIS)

Co-current stratified flow of liquid metal and water was investigated in a horizontal rectangular channel. Position of the interface pressure drop and direct contact heat transfer between these immisci ble liquids were measured in a fully developed flow. A turbulence model was proposed to explain the experimental results considering that the turbulence is damped near the liquid-liquid interface by surface tension. The analytical results showed good agreement with the experimental ones. Main results are that (1) position of the interface mainly depends on the flow rate ratio of both liquids, that (2) the pressure drop is approximately proportional to square of the average velocity of water, and that (3) heat transfer rate at direct contact interface is several times higher than that of co-current flow separated by a thin solid plate. (author).

1980-01-01

15

Visualization of liquid metal two-phase flow by a real time neutron radiography system  

Energy Technology Data Exchange (ETDEWEB)

In order to understand the detail transient two-phase flow structure, more advanced two-phase flow instrumentation is required. One advanced technique for flow visualization is real-time neutron radiography. Reconstruction method of visualized radiographic image of liquid metal two-phase flow generated by the real-time neutron radiography system is proposed in this paper. Image processing techniques for noise reduction and image enhancement are discussed in detail. (author).

1995-11-01

16

Visualization of liquid metal two-phase flow by a real time neutron radiography system  

International Nuclear Information System (INIS)

In order to understand the detail transient two-phase flow structure, more advanced two-phase flow instrumentation is required. One advanced technique for flow visualization is real-time neutron radiography. Reconstruction method of visualized radiographic image of liquid metal two-phase flow generated by the real-time neutron radiography system is proposed in this paper. Image processing techniques for noise reduction and image enhancement are discussed in detail. (author).

1995-01-01

17

Liquid metal cooled fast breeder reactor comprising electromagnetic braking systems of the coolant flow  

International Nuclear Information System (INIS)

The liquid-metal-cooled fast breeder reactor presented includes a fuel assembly made up of several long sub-assemblies rising side by side. Each of the sub-assemblies of an external area of the fuel assembly comprises an electromagnetic braking system for regulating the flow of coolant in the sub-assembly, the magnetic fields of the braking systems being temperature sensitive.

18

Analytical determination of the dimensions and evolution with current of the ion-emitting jet in liquid-metal ion sources  

Energy Technology Data Exchange (ETDEWEB)

The apex dimensions and length are calculated as a function of current for the ion-emitting jet in liquid-metal ion sources (LMIS). The results agree well with observations. Since the final expressions are analytical, they give more insight into the fundamental mechanisms involved than do numerical calculations. Some implications of the model are discussed concerning focused ion beam (FIB) systems employing LMIS. (author).

1991-12-14

19

Chemistry of polynuclear transition-metal complexes in ionic liquids.  

Science.gov (United States)

Transition-metal chemistry in ionic liquids (IL) has achieved intrinsic fascination in the last few years. The use of an IL as environmental friendly solvent, offers many advantages over traditional materials synthesis methods. The change from molecular to ionic reaction media leads to new types of materials being accessible. Room-temperature IL have been found to be excellent media for stabilising transition-metal clusters in solution and to crystallise homo- and heteronuclear transition-metal complexes and clusters. Furthermore, the use of IL as solvent provides the option to replace high-temperature routes, such as crystallisation from the melt or gas-phase deposition, by convenient room- or low-temperature syntheses. Inorganic IL composed of alkali metal cations and polynuclear transition-metal cluster anions are also known. Each of these areas will be ...

2011-07-11

20

A superconductor to superfluid phase transition in liquid metallic hydrogen  

CERN Document Server

Although hydrogen is the simplest of atoms, it does not form the simplest of solids or liquids. Quantum effects in these phases are considerable (a consequence of the light proton mass) and they have a demonstrable and often puzzling influence on many physical properties, including spatial order. To date, the structure of dense hydrogen remains experimentally elusive. Recent studies of the melting curve of hydrogen indicate that at high (but experimentally accessible) pressures, compressed hydrogen will adopt a liquid state, even at low temperatures. In reaching this phase, hydrogen is also projected to pass through an insulator-to-metal transition. This raises the possibility of new state of matter: a near ground-state liquid metal, and its ordered states in the quantum domain. Ordered quantum fluids are traditionally categorized as superconductors or superfluids; these respective ...

2004-01-01

21

Heat-driven liquid metal cooling device for the thermal management of a computer chip  

International Nuclear Information System (INIS)

The tremendous heat generated in a computer chip or very large scale integrated circuit raises many challenging issues to be solved. Recently, liquid metal with a low melting point was established as the most conductive coolant for efficiently cooling the computer chip. Here, by making full use of the double merits of the liquid metal, i.e. superior heat transfer performance and electromagnetically drivable ability, we demonstrate for the first time the liquid-cooling concept for the thermal management of a computer chip using waste heat to power the thermoelectric generator (TEG) and thus the flow of the liquid metal. Such a device consumes no external net energy, which warrants it a self-supporting and completely silent liquid-cooling module. Experiments on devices driven by one or two stage TEGs indicate that a ...

2007-08-07

22

Influence of relaxation phenomena in liquid phase on magnetic anisotropy of metallic glasses  

International Nuclear Information System (INIS)

It if first shown, that the effective field of uniaxial magnetic anisotropy of Fe-Cr-P-C and Fe-Ni-B-Si system amorphous alloys is reduced with an increase of the source melt isothermal exposure time. The behaviour noted is conditioned by microcoherence and relaxation processes in the nonequilibrium liquid phase after crystal-liquid phase transition.

1996-12-01

23

Studies on magnetohydrodynamic flow characteristics and heat transfer of liquid metal two-phase flow cooling systems for a magnetically confined fusion reactor  

Energy Technology Data Exchange (ETDEWEB)

Liquid metal cooling for the first wall and blanket of a magnetic confinement fusion reactor has various advantages. However, it has the disadvantages of large magnetohydrodynamic pressure drops and heat transfer deterioration under a strong magnetic field. Thus, the present authors have proposed cooling with a helium-lithium annular mist flow as well as the cooling with a liquid metal boiling flow, and as fundamental studies, investigated the effect of a magnetic field on the flow characteristics and heat transfer of liquid metal two-phase systems since the 1970s. In the present paper we summarize the important findings obtained from our experimental studies for (i) an air-mercury stratified flow in a horizontal rectangular channel, (ii) a helium-lithium annular mist flow in a horizontal rectangular channel, (iii) the mercury pool boiling on a horizontal ...

1995-03-01

24

Studies on magnetohydrodynamic flow characteristics and heat transfer of liquid metal two-phase flow cooling systems for a magnetically confined fusion reactor  

International Nuclear Information System (INIS)

Liquid metal cooling for the first wall and blanket of a magnetic confinement fusion reactor has various advantages. However, it has the disadvantages of large magnetohydrodynamic pressure drops and heat transfer deterioration under a strong magnetic field. Thus, the present authors have proposed cooling with a helium-lithium annular mist flow as well as the cooling with a liquid metal boiling flow, and as fundamental studies, investigated the effect of a magnetic field on the flow characteristics and heat transfer of liquid metal two-phase systems since the 1970s. In the present paper we summarize the important findings obtained from our experimental studies for (i) an air-mercury stratified flow in a horizontal rectangular channel, (ii) a helium-lithium annular mist flow in a horizontal rectangular channel, (iii) the mercury pool boiling on a horizontal ...

25

In situ observation of axial irradiation growth in liquid-metal reactor metal fuel  

International Nuclear Information System (INIS)

Effects of the rapid early-in-life expansion of metal fuel were measured in an irradiation experiment in the Fast Flux Test Facility (FFTF). This important performance/design information was obtainable through the unique combination of a dimensionally stable FFTF oxide core and the calibrated proximity instrumentation associated with the test. These results delineate the time dependence of metal-fuel swelling and provide quantitative estimates of the magnitude of axial fuel swelling in full-length metal-fuel assemblies. Final posttest examination results will define actual fuel column growth levels.

1989-11-26

26

Solution of Bohr's collective Hamiltonian for transitional odd-mass nuclei  

International Nuclear Information System (INIS)

A numerically feasible method, based on the use of deformed phonons, is developed for the diagonalization of the collective quadrupole Hamiltonian for a system with an odd particle coupled to an anharmonic even core. Examples: the transition from prolate to oblate via #gamma#-unstable shapes and furthermore the hsub(9/2) spectra of the nuclei "1"8"7Ir and "1"9"7Tl. (Auth.).

27

COLLAPSE AND FRAGMENTATION OF MOLECULAR CLOUD CORES. X. MAGNETIC BRAKING OF PROLATE AND OBLATE CORES  

International Nuclear Information System (INIS)

The collapse and fragmentation of initially prolate and oblate, magnetic molecular clouds is calculated in three dimensions with a gravitational, radiative hydrodynamics code. The code includes magnetic field effects in an approximate manner: magnetic pressure, tension, braking, and ambipolar diffusion are all modeled. The parameters varied for both the initially prolate and oblate clouds are the initial degree of central concentration of the radial density profile, the initial angular velocity, and the efficiency of magnetic braking (represented by a factor f _m_b = 10"-"4 or 10"-"3). The oblate cores all collapse to form rings that might be susceptible to fragmentation into multiple systems. The outcome of the collapse of the prolate cores depends strongly on the initial density profile. Prolate cores with central densities 20 times higher than their boundary densities collapse and fragment into binary or quadruple ...

2009-06-01

28

Consolidation behavior of Cu- and Ni-based bulk metallic glass composites  

Energy Technology Data Exchange (ETDEWEB)

The Cu- and Ni-based bulk metallic glass matrix composites were fabricated by spark plasma sintering of a mixture of gas-atomized metallic glass powders and ductile brass powders. The brass powders added for the enhancement of plasticity are well distributed in the matrix after consolidation. The matrix of the composite materials remains as a fully amorphous phase after consolidation process. With increasing the brass content, the level of plasticity strain increased, although the level of strength decreased. The successful consolidation of metallic glass matrix composite with high density was attributed to viscous flow in the supercooled liquid state during spark plasma sintering.

2007-05-31

29

The U.S. Liquid Metal Reactor Development Program  

International Nuclear Information System (INIS)

This paper discusses how the U.S. Liquid Metal Reactor Development Program has been restructured to carry out R and D on advanced reactor technology. The program gives particular emphasis to improvements to reactor safety. The new directions are based on the technology of the integral fast reactor (IFR). Much of the basis for superior safety performance using IFR technology has been experimentally verified and aggressive programs continue in EBR-II and TREAT. Progress has been made in demonstrating both the metallic fuel and the new electrochemical processes of the IFR. The FFTF facility is converting to metallic fuel; however, FFTF also maintains a considerable U.S. program in oxide fuels. In addition, generic programs are continuing in steam generator testing, materials development, and with international cooperation, aqueous reprocessing.

1988-05-01

31

Reactor physics results from fast flux test facility operation  

International Nuclear Information System (INIS)

Criticality was first achieved with the Fast Flux Test Facility (FFTF) a little more than 10 yr ago on February 9, 1980. Although the FFTF was designed and built primarily for testing fuels, materials, and components for the liquid-metal fast breeder reactor program, it has, over its first 10 yr of operation, provided valuable information in many other areas. This paper provides a summary of the contributions to the physics of liquid-metal reactors (LMRs) obtained from operation of and testing in the FFTF, with emphasis on some of the more significant and interesting accomplishments.

1990-11-11

32

Enhanced LMR [liquid metal reactors] core cooling utilizing passive vortex devices  

International Nuclear Information System (INIS)

Several design options for improved passive circulation flow have been investigated for use in small, modular liquid metal cooled reactors (LMRs). The purpose is to enhance the transition to natural convection cooling following loss of forced circulation flow, reducing thermal transients experienced by the fuel and possibly eliminating the need for emergency pony-motor flow. Design details to minimize pressure drops may also enhance maximum equilibrium power levels possible under natural circulation only.

1988-05-01

33

An overview of FFTF [Fast Flux Test Facility] contributions to Liquid Metal Reactor Safety  

International Nuclear Information System (INIS)

The Fast Flux Test Facility has provided a very useful framework for testing the advances in Liquid Metal Reactor Safety Technology. During the licensing phase, the switch from a nonmechanistic bounding technique to the mechanistic approach was developed and implemented. During the operational phase, the consideration of new tests and core configurations led to use of the anticipated-transients-without-scram approach for beyond design basis events and the move towards passive safety. The future role of the Fast Flux Test Facility may involve additional passive safety and waste transmutation tests. 26 refs.

1990-11-11

34

Development of engineering technology basis for pyrometallurgical reprocessing: development of transport technology and pyro-process equipments  

International Nuclear Information System (INIS)

Development of the engineering technology basis of pyrometallurgical reprocessing is a key issue for industrialization. For development of the transport technologies of molten salt and liquid cadmium at around 773 K, a salt transport test rig and a metal transport test rig were newly installed in an Ar glove box. Function of the salt transport test rig was confirmed with LiCl-KCl molten salt, and the transport behaviour of molten salt was found to follow that of water. The molten salt/liquid metal contactor for Ln/An separation was newly designed and installed. The test with a single-stage contactor was successful with simulated elements, and a three-stage contactor is now under development. A large-scale electro-refiner with a function to transport molten salt and liquid cadmium were newly designed, and to be installed for demonstration test with simulated materials. (authors)

2006-09-25

35

Sodium leak detector  

International Nuclear Information System (INIS)

Purpose: To permit accurate detection of sodium leakage by distinguishing between variations in the overflow tank level due to changes in sodium temperature accompanying changes in the power level or operating state of a liquid metal sodium cooled fast breeder, and a reduction in power level due to duct leakage. Constitution: The volume of sodium in the primary cooling system is roughly estimated from the temperatures of hot and cold legs, and the duct leak preset level with respect to the sodium liquid level within an overflow tank when the plant is normal is varied according to the state of the plant. More particularly, the volume of sodium within the overflow tank is calculated on the basis of a signal representing the liquid level detected by a liquid level gauge in the overflow tank and a signal representing the temperature detected by hot leg and cold leg thermometers, thereby ...

36

Transuranic material recovery in the Integral Fast Reactor fuel cycle demonstration  

Energy Technology Data Exchange (ETDEWEB)

The Integral Fast Reactor is an innovative liquid metal reactor concept that is being developed by Argonne National Laboratory. It takes advantage of the properties of metallic fuel and liquid metal cooling to offer significant improvements in reactor safety, operation, fuel cycle economics, environmental protection, and safeguards. The plans for demonstrating the IFR fuel cycle, including its waste processing options, by processing irradiated fuel from the Experimental Breeder Reactor-II fuel in its associated Fuel Cycle Facility have been developed for the first refining series. This series has been designed to provide the data needed for the further development of the IFR program. An important piece of the data needed is the recovery of TRU material during the reprocessing and waste operations.

1993-01-01

37

Transuranic material recovery in the Integral Fast Reactor fuel cycle demonstration  

Energy Technology Data Exchange (ETDEWEB)

The Integral Fast Reactor is an innovative liquid metal reactor concept that is being developed by Argonne National Laboratory. It takes advantage of the properties of metallic fuel and liquid metal cooling to offer significant improvements in reactor safety, operation, fuel cycle economics, environmental protection, and safeguards. The plans for demonstrating the IFR fuel cycle, including its waste processing options, by processing irradiated fuel from the Experimental Breeder Reactor-II fuel in its associated Fuel Cycle Facility have been developed for the first refining series. This series has been designed to provide the data needed for the further development of the IFR program. An important piece of the data needed is the recovery of TRU material during the reprocessing and waste operations.

1993-03-01

38

Rotational velocities and central velocity dispersions for a sample of S0 galaxies  

International Nuclear Information System (INIS)

Central velocity dispersions and rotation curves to radii of approx.5 kpc have been measured for 32 galaxies, mostly field S0's. Our rotation curves confirm the result of Kormendy and Illingworth that the bulges of S0 galaxies are in rapid rotation, with enough rotational kinetic energy to account for their flattenings. The V/sigma-ellipticity relation we find for S0 bulges is compared with similar data for elliptical galaxies from Davies et al. We conclude that (1) faint SO bluges and elliptical galaxies (M/sub B/ fainter than -20.5) are both consistent with oblate rotators with isotropic velocity dispersions (although in our sample, S0 bluges are flatter, on the average, than ellipticals) and (2) bright S0 bulges, -22.0oblate models, but bright ellipticals are not. Hence a significant kinematic difference persists between S0 bulges and ellipticals. This difference suggests that disk galaxies ...

39

Pollen flora of Pakistan--LXVII: acanthaceae  

International Nuclear Information System (INIS)

Pollen morphology of 30 species of the family Acanthaceae belonging to 11 genera has been investigated using light and scanning electron microscope. Acanthaceae is a eurypalynous family. Pollen are usually radially symmetrical, isopolar, sub-prolate to prolate rarely prolate-spheroidal or sub-oblate to oblate-spheroidal, generally tricolporate or heterocolporate rarely colpate or porate. Exine ornamentation varies from medium to coarse reticulate, or often lopho-reticulate with luminae perforated to baculate or scabrate. On the basis of apertural type, exine ornamentation and colpal membrane eight distinct pollen types have been recognized viz., Pollen type-I: Barleria cristata-type, Pollen type-II: Blepharis ciliaris-type, Pollen type-III: Hygrophila polysperma - type, Pollen type-IV: Justicia adhatoda-type, Pollen type-V:Lepidagathis incurva-type, Pollen type- VI: Peristrophe paniculata-type, Pollen type-VII: Ruellia patula-type and Pollen ...

2010-12-01

40

Techniques for measurement of velocity in liquid-metal MHD flows  

Energy Technology Data Exchange (ETDEWEB)

Three instruments for measuring local velocities in liquid-metal MHD experiments for fusion blanket applications are being evaluated. The devices are used in room-temperature NaK experiments to measure three-dimensional flow field patterns anticipated in complex blanket geometries. Hot film anemometry, a standard technique in ordinary fluids, is being used, as well as two developmental devices. One is called the Liquid Metal Electromagnetic Velocity Instrument (LEVI), and performs essentially as a local dc electromagnetic flow meter. The third device, a Thermal Transient Anemometer (TTA) is a rugged, yet relatively simple device, which measures local velocity through the mechanism of convective heat transfer, in some ways similar to hot-film anemometry. Results are presented showing the kinds of data collected this far with each instrument. Measurements include both local velocity measurements and some preliminary frequency ...

1986-01-01

41

Process of making particle board from pyrophosphate treated polyisocyanates  

Energy Technology Data Exchange (ETDEWEB)

A process is disclosed for the preparation of liquid, storage-stable, polyisocyanate compositions containing a release agent formed in situ which compositions are useful, for example, as binder resins in the formation of particle boards which latter, because of the presence of the release agent, show no tendency to adhere to the face of metal platens used in their formation. The process comprises heating an organic polyisocyanate (polymethylene polyphenyl polyisocyanate preferred) with an acid phosphate (e.g. a mixture of mono-and di-alkyl acid phosphates) under conditions controlled as to time and temperature so as to yield a product which is storage stable and shows no tendency to deposit solid or to separate into two liquid phases.

1984-10-09

42

On the mechanism of the nonmonotonic relaxation processes in the metallic melts  

International Nuclear Information System (INIS)

The numerical analysis of the experimental data on viscosity change by time in the period after fast heating and crystal-liquid phase transition for the copper nonequilibrium melts and the Fe_7_0Cr_1_0P_1_3C_7 glass-forming melt near their melting temperatures is accomplished through the method of correlation functions and the Rytov-Dimentberg criterion. The observed dependences have nonmonotonic oscillating character but they do not relate to auto-oscillations. The proposed theoretical model of the properties oscillations origination by relaxation in the nonequilibrium liquids explains them as manifestation of noise-induced transitions in the metastable area near the critical temperatures (melting, structural transitions)

2000-01-01

43

Lithium-lead/water reaction experiments and analysis  

Energy Technology Data Exchange (ETDEWEB)

An experiment has been performed to investigate the chemical reaction between the liquid phases of the eutectic lithium-lead (Li/sub 17/Pb/sub 83/) and water. The reactants and products were constrained within a closed reaction vessel, allowing the extent of reaction to be determined from the partial pressure of the hydrogen reaction product. The data from the tests showed that the extent of reaction did not depend upon the water temperature. The data also indicated that the extent of reaction passed through a maximum as the initial liquid metal temperature was varied from 350 to 500 C, and a model was developed to explain this behavior. 11 refs., 3 figs.

1988-01-01

44

Application of the tracer technique to study on casting solidification  

International Nuclear Information System (INIS)

The results and techniques of radiographic study on solidification of iron and steel mould castings are described. The study was made to determine the causes of the mold castings defects. The liquid metal is either labelled in the ladle, or relabelled inside the mould in present time intervals. In the former case, the radioactive phosphorus is segregated in the last-solidifying casting locations, and in the latter, the radioactive phosphorous is distributed along the solid-liquid interface at the time of the next addition in turn. The solidification process parameters may be arrived at by the autoradiograms taken in the pipe-sensitive casting sections. Using these data it is possible to proceed to the proper modifications in the steel casting process.

45

The role of natural circulation in the FFTF [Fast Flux Test Facility] passive safety tests  

International Nuclear Information System (INIS)

A series of tests were completed at the Fast Flux Test Facility to demonstrate the passive safety characteristics of liquid metal reactors with natural circulation flow. The first test consisted of transition from forced to natural circulation flow at an initial decay power of 0.3%. The second test represented an unprotected loss-of-flow transient to natural circulation from 50% power with the control rods prevented from scramming into the core. The third test was a steady-state, natural circulation condition with core fission powers up ato about 2.3%. Core sodium data and results of single and multi-channel computer models confirmed the reliability and effectiveness of natural circulation flow for liquid metal reactor safety.

1987-12-13

46

Natural convection cooling of liquid metal systems  

International Nuclear Information System (INIS)

The recognition that natural convection offers the prospect of an important inherent safety feature for liquid metal cooled reactor systems has provided the impetus for a world-wide research effort over the past decade. Whilst this research has been based on experiment, both plant experiments and out-of-pile experiments, the enormous advances in the development of computing power in recent years have enabled complementary programmes of mathematical modelling through numerical simulation of the transport equations in three spatial dimensions. These not only offer considerable promise for the designer in projecting the behaviour from experiments and prototype plant to full scale plant, they have also proved to be of considerable value in helping us to interpret and understand the results of the experiments themselves. This paper attempts to review the progress made with the emphasis on decay heat removal by natural convection in the pool-type ...

47

Measurement of the ratio of liquid to solid phases in a continuous ingot  

International Nuclear Information System (INIS)

A radiometric method of measuring the ratio of liquid and solid phases (crust thickness) in a continuous ingot for automation of the continuous steel casting process, has been proposed. The essence of the method is, that radiation flux, bearing information on the object tested, is transformed in a succession of electric pulses, which is processed afterwords for obtaining necessary information. In this case either the flux of non-scattered radiation, passed through the object, or the flux of single-scattered radiation reflected from the object is registered. Block-diagram and specifications of a radiometric device with the Co source of 50 gxequiv. Ra activity developed for this purpose are presented. The technique for calibration ob the device and the results of its tests, are described. It is shown, that introduction of such devices for the control crust thickness at the installations of continuous steel casting of metallurgical works would permit to exercise ...

48

Heat transfer augmentation in liquid metal reactor steam generators  

International Nuclear Information System (INIS)

The use of heat transfer augmentation devices has been proposed as a means for reducing the cost of steam generators for advanced LMR designs by approximately 25%. Experimental results are presented for two types of enhancers in the form of a twisted-tape and a core-tube insert in the steam tube of a 13.1-m-long, sodium-heated single-tube test section. Test parameters were prototypical of liquid metal reactor (LMR) steam generator design for a once-through high-pressure steam cycle. Heat transfer results are compared with the no-insert case on an overall and local basis. Although both augmentations increased overall performance, the mechanisms were different.

49

Fabrication of core demonstration experiments for irradiation in FFTF [Fast Flux Test Facility  

International Nuclear Information System (INIS)

A major initiative to develop and irradiate a long-life, mixed-oxide fuel system in the Fast Flux Test Facility (FFTF) has been implemented by Westinghouse Hanford Company for the US Department of Energy. The FFTF, shown in Figures 1 and 2, is a 400 megawatt thermal, fast liquid metal reactor that tests liquid metal, space and fusion fuels and materials. The new fuel system, called the Core Demonstration Experiment (CDE) demonstrates the capability of achieving a three- to four-year life in a prototypic heterogeneous reactor environment under prototypic power and temperature conditions. This fuel system will greatly increase fuel performance and lifetime from the current standard FFTF driver fuel. New design features, fabrication development, CDE assembly fabrication, and irradiation status have been described.

1990-06-10

50

Development of liquid metal ion sources, focused ion beam and their applications  

International Nuclear Information System (INIS)

To suit the needs of development for manufacture VLSI, we started to investigate liquid metal ion sources (LMIS) and focused ion beam (FIB) in 1984. Many kinds of emitters viz. neddle type, co-axial type and capillary type of Ga and Au LMIS and three kinds of eutectic alloys LMIS (Au-Si, Au-Si-Be, Pd-Ni-Si-Be-B) have been tested. A program which can calculate focused ion guns has been written. Four kinds of foused ion guns have been operated, a fine beam with diametic 0.1 #mu#m is obtained. Using the FIB a scanning ion microscope has been constructed. Some tests of etching and self-developing of nitrocellulose are described. (author).

51

Technique for compressing light intensity ranges utilizing a specifically designed liquid crystal notch filter  

Energy Technology Data Exchange (ETDEWEB)

A pin hole camera assembly for use in viewing an object having a relatively large light intensity range, for example a crucible containing molten metal in an atomic vapor laser isotope separation (AVLIS) system is disclosed herein. The assembly includes means for optically compressing the light intensity range appearing at its input sufficient to make it receivable and decipherable by a standard video camera. To accomplish this, the assembly utilizes the combination of interference filter and a liquid crystal notch filter. The latter which preferably includes a cholesteric liquid crystal arrangement is configured to pass light at all wavelengths, except a relatively narrow wavelength band which defines the filter's notch, and includes means for causing the notch to vary to at least a limited extent with the intensity of light at its light incidence surface.

1988-01-01

52

Real-time neutron radiography for visualisation of interfacial geometry and phase distribution in two-phase flow  

International Nuclear Information System (INIS)

Results of ongoing research project at the McMaster Nuclear Reactor Facility on real-time neutron radiography for the visualization of interfacial geometry, movements and phase distributions in gas-liquid and gas-liquid-metal multi-phase flows are presented. Experiments were conducted with bubble column tubes with boiling liquid nitrogen, air-water and air-mercury mixtures. Discussions are also focused on air-water flowing within a tube containing a CANDU type 37 rod fuel bundle assembly positioned both horizontally and vertically. Computer processing using a digital image format to enhance the real-time images was used. Imaging techniques include frame averaging, background substraction, edge enhancement (spatial filtering), contrast enhancement and video densitometry. (orig.).

1989-10-01

53

Interface heat transfer of horizontal co-current liquid-liquid stratified flow. II - Entrance region  

Science.gov (United States)

Flow structures and heat transfer at the liquid-liquid interface are investigated experimentally and analytically in the entrance region of a liquid metal-water stratified flow in a horizontal rectangular channel. The two-equation model and the mixing length mode, including a damping turbulent region near the interface, are used to obtain analytical results for pressure drop, position of the interface, and heat transmission coefficients across the interface. Analytical results are compared with experimental results. Conclusions are presented and include the following: (1) vertical position of the interface increases or decreases along the stream according to the fluid flow rate of both fluids, and then approaches a constant value in the fully developed region; (2) pressure drop increases along the stream from the minimum value at the inlet; and (3) heat transmission coefficients across the interface decrease in the entrance ...

1981-06-01

54

Activation of aluminium metal to evolve hydrogen from water  

Energy Technology Data Exchange (ETDEWEB)

The method of aluminium metal activation by liquid eutectics Ga-In (70:30) and Ga-In-Sn-Zn (60:25:10:5) is developed. Subsequent dispersion of the obtained specimens up to a particle size of >0.5mm leads to the drastic interaction of aluminium powder and water with evolving hydrogen. In the present work the oxidation rate of activated aluminium and water is investigated depending on eutectic composition, reaction temperature, and powder particle size. The mechanism of the main eutectic's components influence on the reacting ability of aluminium is discussed. (author)

2008-06-15

55

Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material  

Energy Technology Data Exchange (ETDEWEB)

An alkali metal manganese oxide secondary cell is disclosed which can provide a high rate of discharge, good cycling capabilities, good stability of the cathode material, high specific energy (energy per unit of weight) and high energy density (energy per unit volume). The active material in the anode is an alkali metal and the active material in the cathode comprises an orthorhombic alkali metal manganese oxide which undergoes intercalation and deintercalation without a change in phase, resulting in a substantially linear change in voltage with change in the state of charge of the cell. The active material in the cathode is an orthorhombic structure having the formula M.sub.x Z.sub.y Mn.sub.(1-y) O.sub.2, where M is an alkali metal; Z is a metal capable of substituting for manganese in the orthorhombic structure such as iron, cobalt or titanium; x ranges from about 0.2 in the fully ...

1996-01-01

56

Novel Binders and Methods for Agglomeration of Ore  

Energy Technology Data Exchange (ETDEWEB)

Many metal extraction operations, such as leaching of copper, leaching of precious metals, and reduction of metal oxides to metal in high-temperature furnaces, require agglomeration of ore to ensure that reactive liquids or gases are evenly distributed throughout the ore being processed. Agglomeration of ore into coarse, porous masses achieves this even distribution of fluids by preventing fine particles from migrating and clogging the spaces and channels between the larger ore particles. Binders are critically necessary to produce agglomerates that will not break down during processing. However, for many important metal extraction processes there are no binders known that will work satisfactorily at a reasonable cost. A primary example of this is copper heap leaching, where there are no binders currently encountered in this acidic environment process. As a ...

2006-03-31

57

Waste treatment by dialysis. (Latest citations from Pollution abstracts). Published Search  

Energy Technology Data Exchange (ETDEWEB)

The bibliography contains citations concerning the use of dialysis in the treatment of wastewaters. Techniques for the removal of metals, ammonia, waste acids, nitrates, and phosphates are described. Special attention is given to the desalination of liquid wastes. Applications of this technology to the treatment of effluent from the agrochemical, petrochemical, tanning, and electroplating industries are discussed. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

1996-02-01

58

Instrumentation and control improvements at Experimental Breeder Reactor II  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this paper is to describe instrumentation and control (I C) system improvements at Experimental Breeder Reactor 11 (EBR-11). The improvements are focused on three objectives; to keep the reactor and balance of plant (BOP) I C systems at a high level of reliability, to provide diagnostic systems that can provide accurate information needed for analysis of fuel performance, and to provide systems that will be prototypic of I C systems of the next generation of liquid metal reactor (LMR) plants.

1993-01-01

59

Instrumentation and control improvements at Experimental Breeder Reactor II  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this paper is to describe instrumentation and control (I&C) system improvements at Experimental Breeder Reactor 11 (EBR-11). The improvements are focused on three objectives; to keep the reactor and balance of plant (BOP) I&C systems at a high level of reliability, to provide diagnostic systems that can provide accurate information needed for analysis of fuel performance, and to provide systems that will be prototypic of I&C systems of the next generation of liquid metal reactor (LMR) plants.

1993-03-01

60

HLMC Fast Reactor With Complete Natural Circulation  

Science.gov (United States)

To seek for a promising concept of a heavy liquid metal coolant (HLMC) fast reactor plant, Japan Nuclear Cycle Development Institute (JNC) and the electric utilities conducted conceptual design study on various types of plant concepts and compared these concepts based on technical feasibility and economical perspective. The Pb-Bi cooled complete natural circulation reactor concept may attain high safety level and construction cost goal (Yen 200,000/kWe) (authors)

2002-07-01

61

Fuel-related advances in science and technology. (XIII) University education. (5) Petrochemistry and coal liquefaction  

Energy Technology Data Exchange (ETDEWEB)

The author draws the connections between the work he has done over the last ten years and related research. Connections with industry are also mentioned, and future prospects are considered. Topics discussed include research into the synthesis of olefins and into liquid phase oxidation, the catalytic effects of transition metal compounds, and coal liquefaction. (35 refs.) (In Japanese)

1982-01-01

62

Contribution of the ion-energy distribution to the current-density distribution of a focused-ion beam  

Energy Technology Data Exchange (ETDEWEB)

A general expression for the current-density distribution of a focused-ion beam (FIB) in the chromatic-aberration region is set up in the form of a definite integral. With the experimentally obtained ion-energy distribution of a liquid-metal ion source, its contribution to the FIB current-density distribution is estimated. Calculated results explain the wide-exponential tail of a FIB.

1987-09-01

63

Contribution of the ion-energy distribution to the current-density distribution of a focused-ion beam  

International Nuclear Information System (INIS)

A general expression for the current-density distribution of a focused-ion beam (FIB) in the chromatic-aberration region is set up in the form of a definite integral. With the experimentally obtained ion-energy distribution of a liquid-metal ion source, its contribution to the FIB current-density distribution is estimated. Calculated results explain the wide-exponential tail of a FIB.

64

Recent progress on biosorption of Heavy metals from liquids using low cost biosorbents: characterization, biosorption parameters and mechanism studies  

Energy Technology Data Exchange (ETDEWEB)

A significant number of biosorption studies on the removal of heavy metal from aqueous solutions have been conducted worldwide. Nearly all of them have been directed towards optimizing biosorption parameters to obtain the highest removal efficiency while the rest of them are concerned with the biosorption mechanism. Combinations of FTIR, SEM-EDX, TEM as well as classical methods such as titrations are extremely useful in determining the main processes on the surfaces of biosorbents. Diverse functional groups represented by carboxyl, hydroxyl, sulfate and amino groups play significant roles in the biosorption process. Solution pH normally has a large impact on biosorption performance. In brief, ion exchange and complexation can be pointed out as the most prevalent mechanisms for the biosorption of most heavy metals. (Abstract Copyright [2008], Wiley Periodicals, Inc.)

2008-12-15

65

Reactivity from power spectral density measurements with /sup 252/Cf. [LMFBR  

Science.gov (United States)

The theory of a method of determination of the reactivity from power spectral density measurements with /sup 252/Cf and the results of experiments with a critical assembly mock-up of a liquid-metal fast breeder reactor and with uranium (93.2 wt % /sup 235/U) metal cylinders and a sphere are presented. This method of reactivity determination has an advantage over existing methods in that it determines the reactivity only from properties of the reactor at the subcritical state of interest and thus does not require a calibration near delayed criticality. In these experiments the reactivity was varied by changing the fissile loading or the amount of neutron absorber inserted; for the LMFBR mock-up, the reactivity varied to approximately 75 dollars subcritical, and for the uranium metal assemblies, to approximately 30 dollars subcritical.

1977-08-01

66

Metal ion complexation by ionizable crown ethers  

Energy Technology Data Exchange (ETDEWEB)

Research conducted since the last progress report includes the synthesis and characterization of twenty three novel proton-ionizable crown ether compounds. Metal ion complexation behavior of new and previously-synthesized proton-ionizable crown ether compounds has been probed by solvent extraction and transport across polymer-supported liquid membranes. The behavior of neutral polyether and proton-ionizable polyether ligands in polymeric membrane electrodes has been assessed. Studies of the use of proton-ionizable crown ethers for separation of lithium isotopes were initiated. Also, the thermodynamics of interactions between alkali metal cations and ionized crown ethers have been probed by titration calorimetry. 10 refs., 1 tab.

1989-09-01

67

Ceramic/polymer functionally graded material (FGM) lightweight armor system  

Energy Technology Data Exchange (ETDEWEB)

This is the final report of a two-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). Functionally graded material is an enabling technology for lightweight body armor improvements. The objective was to demonstrate the ability to produce functionally graded ceramic-polymer and ceramic-metal lightweight armor materials. This objective involved two aspects. The first and key aspect was the development of graded-porosity boron-carbide ceramic microstructures. The second aspect was the development of techniques for liquid infiltration of lightweight metals and polymers into the graded-porosity ceramic. The authors were successful in synthesizing boron-carbide ceramic microstructures with graded porosity. These graded-porosity boron-carbide hot-pressed pieces were then successfully liquid-infiltrated in vacuum with molten aluminum at 1,300 C, and ...

1998-12-31

68

The Effect of Applied Pressure During Feeding of Critical Cast Aluminum Alloy Components With Particular Reference to Fatigue Resistance  

Energy Technology Data Exchange (ETDEWEB)

the medium to long freezing range alloys of aluminum such as A356, A357, A206, 319 for example are known to exhibit dispersed porosity, which is recognized as a factor affecting ductility, fracture toughness, and fatigue resistance of light alloy castings. The local thermal environment, for example, temperature gradient and freezing from velocity, affect the mode of solidification which, along with alloy composition, heat treatment, oxide film occlusion, hydrogen content, and the extent to which the alloy contracts on solidification, combine to exert strong effects on the porosity formation in such alloys. In addition to such factors, the availability of liquid metal and its ability to flow through the partially solidified casting, which will be affect by the pressure in the liquid metal, must also be considered. The supply of molten metal will thus be controlled by the volume of ...

2003-06-30

69

Development of pyro-separation technology based on molten salt electrolysis  

International Nuclear Information System (INIS)

In order to effectively recover uranium, rotation speed of solid cathode was examined, and effect of uranium concentration and current density on electrodeposition were confirmed. And the potentiostatic and galvanostatic electrorefining experiments were conducted. Element used in the experiments were Zr, Nd, La chlorides. The reduction potentials of chlorides metals on liquid Cd cathode were measured by cyclic voltammetry experiments. The electrowinning experiments were performed in order to recover small amounts of uranium in salt. Experimental set-up for the batch type reductive extraction experiments were developed and installed. On the base of experimental results of batch type, multi-stage extraction equipment was set-up, and optimum number of stage and recover yield were measured. In the oxidative extraction study is examine selective separation behavior of the rare earth metals from alloy composed of actinide and ...

2010-10-01

70

Development of HT-9 for liquid-metal reactor components  

International Nuclear Information System (INIS)

Alloy HT-9 is being used for both duct and cladding applications in advanced liquid-metal reactor (LMR) experiments. This tempered martensitic steel was selected for use as an LMR core component material primarily because of its excellent resistance to radiation-induced swelling. Experiments conducted in the Fast Flux Test Facility (FFTF) at 410 degree C and exposures in the range of 150 to 175 displacements per atom (dpa) have shown that Ht-9 exhibits only a 0.2 to 0.3% increase in volume. Cold-worked austenitic steels exhibit volumetric increases of 20 to 30% at 410 degree C, Alloy HT-9 is being used for a series of fuel pin experiments in the FFTF, and these tests have achieved a burnup of 175 MWd/kg metal and a fluence of 25 x 10"2"2 n/cm"2 (E > 0.1 MeV) without fuel pin breach. The high confidence placed in HT-9 is based on a wide series of in- and ex-reactor experiments. Test results for these experiments are summarized in this paper.

1989-11-26

71

Quantum frustration in organic Mott insulators: from spin liquids to unconventional superconductors  

CERN Document Server

We review the interplay of frustration and strong electronic correlations in quasi-two-dimensional organic charge transfer salts, such as k-(BEDT-TTF)_2X and Et_nMe_{4-n}Pn[Pd(dmit)2]2. These two forces drive a range of exotic phases including spin liquids, valence bond crystals, pseudogapped metals, and unconventional superconductivity. Of particular interest is that in several materials there is a direct transition as a function of pressure from a spin liquid Mott insulating state to a superconducting state. Experiments on these materials raise a number of profound questions about the quantum behaviour of frustrated systems, particularly the intimate connection between spin liquids and superconductivity. Insights into these questions have come from a wide range of theoretical techniques including first principles electronic structure, quantum many-body theory and quantum field theory. In this review ...

2010-01-01

72

Materials considerations for the National Spallation Neutron Source target  

Energy Technology Data Exchange (ETDEWEB)

The National Spallation Neutron Source (NSNS), in which neutrons are generated by bombarding a liquid mercury target with 1 GeV protons, will place extraordinary demands on materials performance. The target structural material will operate in an aggressive environment, subject to intense fluxes of high energy protons, neutrons, and other particles, while exposed to liquid mercury and to water. Components that require special consideration include the Hg liquid target container and protective shroud, beam windows, support structures, moderator containers, and beam tubes. In response to these demands a materials R and D program has been developed for the NSNS that includes: selection of materials; calculations of radiation damage; irradiations, post irradiation testing, and characterization; compatibility testing and characterization; design and implementation of a plan for monitoring of materials performance in service; and ...

1997-08-01

73

Dynamics of the globular cluster M2 (NGC 7089)  

International Nuclear Information System (INIS)

We have obtained radial velocities for 69 stars in the globular cluster M2 (NGC 7089). M2's rotation axis is, within sizeable uncertainties, perpendicular to the major axis determined by the flattening. The ratio of rotational to random kinetic energy agrees with that predicted from the ellipticity assuming an oblate figure and an isotropic velocity-dispersion tensor. We have fitted King-Michie models to determine M2's mass, the exponent of an assumed power-law mass function, and the anisotropy radius. The most significant sources of uncertainty in the modeling are the velocity dispersion, the distance, and the mass-luminosity relation for the cluster stars. The models favor mass functions similar to or shallower than the Salpeter initial-mass function and a moderate amount of velocity anisotropy.

74

Separation of {sup 187,188}Pt and {sup 187,188}Ir produced in {sup 11}B{sup 4+} irradiated tantalum target  

Energy Technology Data Exchange (ETDEWEB)

Heavy ion irradiation on tantalum metal target with 57 MeV {sup 11}B{sup 4+} leads to the production of no-carrier-added radioisotopes of platinum, {sup 187,188}Pt and iridium, {sup 187,188}Ir in the matrix, which have been effectively separated from the bulk target and from each other with suitable anion exchangers employing liquid-liquid extraction (LLX). Also {sup 188,189}Pt and {sup 188,189}Ir radionuclides have been produced, from their short-lived precursors {sup 188,189}Au, in {sup 12}C{sup 6+} irradiated tantalum matrix. Gamma-spectroscopy has been utilised to determine the production, extent of separation and purity of the radiotracers at different stages of the experiment. (orig.)

2000-07-01

75

Investigation of heat transfer with boiling of cryogenic liquids on surfaces with capillary-porous coating  

Energy Technology Data Exchange (ETDEWEB)

Means of intensifying heat transfer with nucleate boiling, based on boiling under constrained conditions (in slots, on a capillary-porous surface) are the most promising since a high intensity of heat transfer is ensured. In the present work we attempt to evolve the main assumptions for the physical model of the process of vapour formation under constrained conditions and to extend them to the boiling of cryogenic liquids on surfaces with a capillary-porous deposit; also, the results are given of experimental investigations of heat transfer with the boiling of nitrogen, oxygen and hydrogen at atmospheric perssures and below on capillary-porous surfaces of various metals of different structure produced by an electric arc method of gasothermal spray coating.

1980-01-01

76

Assessment of interference in biosorption of a heavy metal  

Energy Technology Data Exchange (ETDEWEB)

Biosorption of heavy metals by various biological materials has been studied extensively in the last decade due to its potential particularly in wastewater treatment. The presence of a large number of metals in industrial metal-bearing solutions makes it necessary to investigate their effect on the final metal uptake by individual biosorbent materials. Nonliving biomass of Sargassum, a brown marine alga, is capable of binding more than 10% of its dry weight in toxic cadmium ions. Although ubiquitous iron interferes with Cd uptake, only approximately 4.5% of it is sequestered (biomass dry weight). Biosorption of both metals at pH 4.5 could be described by Langmuir-type isotherms with b, the affinity-related coefficient (Cd: b = 0.015; Fe: b = 0.027). The interference of Fe with Cd uptake, and vice versa, was assessed by deriving three-dimensional equilibrium ...

1997-05-20

77

Fragmentation mechanisms of a single molten copper jet penetrating a sodium pool. Transition from thermal to hydrodynamic fragmentation in instantaneous contract interface temperatures below its freezing point  

International Nuclear Information System (INIS)

To clarify the fragmentation mechanism of a molten metallic fuel jet in a sodium pool under high-ejection-velocity conditions that correspond to the medium- and high-burnup conditions in the metallic fuel core of liquid-metal-cooled fast breeder reactors, a series of experiments with molten copper as a metallic fuel simulant and a sodium pool was carried out. Under low-ejection-velocity conditions in the range of an ambient Weber number (Wea) a ? 200, the size of the fragments is confirmed to be almost independent of the initial superheating of the jet. Furthermore, the size of the fragments agrees well with that evaluated using the Rayleigh-Taylor instability model, in which the fragment size is assumed to be equal to half the fastest growing wavelength. This result is qualitatively consistent with the characteristics that the molten jet column with large inertia force owing to the high ejection ...

2010-03-01

78

Rotation of the bulge components of barred galaxies  

International Nuclear Information System (INIS)

Stellar rotation and velocity-dispersion measurements are presented for the bulge components of the SBO galaxies NGC 1023, 2859, 2950, 4340, 4371, and 7743. The kinematics of nine SB bulges with data available are compared with bulges of unbarred galaxies studied by Kormendy and Illingworth. All of the SB bulges are found to rotate at least as rapidly as oblate-spheroid dynamical models which are flattened by rotation. This result confirms the conclusion of Kormendy and Illingworth that bulges rotate very rapidly. Six SB bulges found by Kormendy and Koo to be triaxial rotate even more rapidly than the oblate models. In this respect, they resemble published n-body models of bars. That is, triaxial bulges are dynamically like bars and unlike elliptical galaxies, which are also believed to be triaxial, but which rotate slowly. Measured velocity anisotropies are found to be consistent with these conclusions. Two ordinary bulges whose rotation is ...

79

Temperature dependence of density and compressibility of eutectic mixtures of alkali metal chlorides near melting point  

International Nuclear Information System (INIS)

Hydrostatic weighing was used to measure the pre-melt density of crystalline eutectic mixtures of alkaline metal chlorides of the compositions (mole fractions): 0.605 LiCl + 0.395 CsCl, 0.585 LiCl + 0.415 KCl, 0.297 NaCl + 0.246 KCl + 0.457 CsCl, and 0.348 NaCl + 0.652 CsCl with melting points 598, 628, 753, 763 K, respectively, as a function of temperature. In the same temperature ranges, the compressibility and molar volume of eutectics as well as their sudden change upon melting were estimated. Unusual variations of these properties were revealed near the crystal/liquid phase transition, which were related to local disordering of particle configuration

80

TEM and ToF-SIMS studies on the corrosion behavior of vanadium and chromium containing WC-Co hard metals in alkaline solutions  

British Library Electronic Table of Contents (United Kingdom)

The corrosion behavior of hard metals with VC and Cr3C2 grain growth inhibitors was investigated in alkaline solutions by electrochemical methods. The two inhibitors have opposite effects on the corrosion behavior: Cr3C2 significantly improves the corrosion behavior, whereas VC-containing alloys show a poor resistance. Time-of-flight secondary ion mass spectrometry (ToF-SIMS) and analytical transmission electron microscopy (TEM) analyses of the distributions of Cr and V in the composite material, as well as in the surface layers formed during corrosion were employed to clarify the influence of these elements on the corrosion behavior. The measurements showed that VC is precipitated mostly along the WC/binder interface after the liquid-phase sintering process, while Cr3C2 is almost homogene...

2011-01-01

81

Performance of hydrous titanium oxide-supported catalysts in coal-liquids upgrading  

Science.gov (United States)

Experimental tests were performed in a continuous-flow hydrotreating unit at Pittsburgh Energy Technology Center to evaluate the performance of hydrous titanium-oxide supported (HTO) catalysts as hydrotreating catalysts for use in two-stage coal liquiefaction. Catalysts containing either a combination of CO, Ni, and Mo as the active metal components or Pd as the active metal componet were tested with representative hydrotreater feed stocks from the Wilsonville Advanced Coal Liquefaction Research and Development Facility. Catalyst performance evaluation was based on desulfurization and denitrogenation activity, the conversion of cyclohexane-insolbule material, and hydrogenation activity during 100-hour reactor runs. Results indicated that the HTO catalysts were comparable to a commercial Ni/Mo-alumina supported catalyst in the areas evaluated. 11 refs., 1 fig., 6 tabs.

1988-01-01

82

Overview of industrial applications of induction; L'induction au service de l'industrie: panorama des applications industrielles  

Energy Technology Data Exchange (ETDEWEB)

Because power requirements in induction heating applications are largely dependent on the physical properties of the product to be heated, inducting, heating is mainly used in steelwork applications, for the manufacture of finished or semi-finished parts. Applications here cover five main types of steelworks operation: smelting, heating prior to forming, heat treatment, surface treatment, and assembly process. At the same time, technological progress has opened up innovative applications in sectors such as chemical and agro-food industries. Other emerging applications for induction include direct forming of liquid metal, wholly or partially replacing mechanical transformations on solid metal. Techniques include electromagnetic forming, continuous cold-crucible casting, electromagnetic mixing, flow control by continuous magnetic field, and production of intense sliding fields (pumps, flow regulation). (author)

2004-05-01

83

Coir pith-a biosorbent for removal of cesium from aqueous solutions  

International Nuclear Information System (INIS)

Coir pith (CP), an abundantly available lignocellulosic agricultural waste from the local coir industry has been found to be an effective biosorbent for removal of metal ions from aqueous solutions. Transition metal hexacyanoferrates, in particular nickel hexacyano ferrate (NiHCF) also referred to as Prussian blue analogue (PBA), is known to be highly selective for removal of cesium from aqueous solutions. A novel method for the synthesis of PBA inside the porous matrix of coir pith and use of this composite material for the sorption of cesium is described in this paper. Equilibrium experiments showed that the sorption capacity of coir pith nearly doubled due to the modification. Owing to its low cost and rapid sorption kinetics, this hybrid material seems to be one of the most promising compounds for the recovery of cesium from liquid nuclear wastes. (author)

2007-01-04

84

Catalytic effect of oxides and sulfides of metallic minerals on hydrogenation of Kansk-Achinsk brown coal  

Energy Technology Data Exchange (ETDEWEB)

Discusses results of investigations into catalytic properties of various minerals during hydrogenation of Kansk-Achinsk brown coal with a view to replacing synthetic compositions based on molybdenum. Describes tests and equipment used in hydrogenation of grade B-2 Borodinsk deposit coal in tetralin (hydrogen donor). Various by-products of metallurgical processes and compounds separated from tailings containing mainly iron and sulfur and other metals were used as catalysts. States that: minerals containing iron compounds in the form of pyrites, hematites and magnetites exhibit catalytic properties when used in the hydrogenation of brown coal; pyritic catalysts enrich liquid products with hydrogen while sulfur and nitrogen content remains the same; the yield of malthenes with pyritic catalysts is no lower than with alumocobaltmolybdenum catalysts. 18 refs.

1988-05-01

85

A novel electrochemical alkylation of aniline with methanol over Zn/Cu salts modified kaolin  

British Library Electronic Table of Contents (United Kingdom)

A novel liquid phase alkylation of aniline with methanol over Zn/Cu salts modified kaolin assisted with a pair of porous carbon electrode in slurry-bed reactor under constant current intensity, room temperature and atmospheric pressure was reported. The Zn/Cu salts modified kaolin catalysts were synthesized and characterized by infrared spectrometer (IR), powder X-ray diffraction (XRD) and scanning electron microscopy (SEM), which showed that the transition metals were completely supported on kaolins structure and formed a pored one. The effect parameters, such as initial pH, electrolysis time, metal ratio with kaolin and salts composition in this electrochemical catalytic system, were studied. The procedure was inspected by ultraviolet-visible spectrum (UV-vis), and the product distributi...

2008-01-01

86

Long-life bismuth liquid metal ion source for focussed ion beam micromachining application  

International Nuclear Information System (INIS)

Liquid metal ion sources (LMISs) with Ga as ion species are widely used in focused ion beam (FIB) technology for micromachining and surface treatment on the sub-micron and nano-scale. Key features of a LMIS for investigating mechanical properties and 3D-microfabrication of materials are long life-time, high brightness, stable ion current and a highly effective milling ability for the material to be modified. In order to increase the material removal rate, heavier ions than Ga and their clusters should be applied. Bismuth (Bi) is the heaviest, non-radio-active element in the periodic table, is non-toxic and exhibits a low melting point. We have thus produced a long-life (about 1000 h) Bi LMIS with a good beam performance, applicable in any FIB system. Since Bi is the only element in this source, it is not necessary to separate it from other ions by a mass filter. Investigation of the sputtering rate of NiTi shape memory alloys using Ga and Bi ...

2008-09-15

87

Catalytic activity of hydrophobic Pt/C/PTFE catalysts of different PTFE content for hydrogen-water liquid exchange reaction  

International Nuclear Information System (INIS)

10%Pt/C catalysts were prepared by liquid reduction method. PTFE and Pt/ C catalysts were adhered to porous metal and hydrophobic Pt/C/PTFE catalysts were prepared. The structure and size of Pt crystal particles of Pt/C catalysts were analyzed by XRD, and their mean size was 3.1 nm. The dispersion state of Pt/C and PTFE was analyzed by SEM, and they had good dispersion mostly, but PTFE membrane could be observed on local parts of Pt/C/PTFE surface. Because of low hydrophobicity, Pt/C/ PTFE catalysts have low activity when the mass ratio of PTFE and Pt/C is 0.5: 1, and their catalytic activity increases markedly when the ratio is 1:1. When the ratio increases again, more Pt active sites would be covered by PTFE and interior diffusion effect would increase, which result in the decrease of catalytic activity of Pt/C/PTFE. By PTFE pretreatment of porous metal carrier, the activity of Pt/C/PTFE catalysts decreases when the mass ...

2007-09-01

88

Benchmark problem: Hydraulics and heat transfer in the model pin bundle with liquid metal coolant. UPV-EHU calculations  

International Nuclear Information System (INIS)

The Department of Nuclear Engineering and Fluid Mechanics in the University of the Basque Country (UPV-EHU), has done calculations for the proposed benchmark problem, in the frame of the 11th international meeting of the IAHR working group on advanced nuclear reactors thermal-hydraulics (Obninsk-Russian Federation, 5-9 July 2004). The purpose of the benchmark is to compare experimental and analytical results of some experiments carried out in the State Scientific Center of Russian Federation 'Institute of Physics and Power Engineering' (SSC RF IPPE). These experiments were held to research the cooling of pin bundles by liquid metals in reference to the core of Nuclear Reactors such as BREST. The analytical results have been done with the Computational Fluid Dynamics (CFD) code FLUENT. Temperature and velocity fields are the main variables considered for the comparison, and some assumptions has been made in order to simplify a complicate ...

2004-07-05

89

Enhancement of the decontamination factor for liquid radioactive waste and other radioactive materials  

International Nuclear Information System (INIS)

Decommissioning of radiological and nuclear installations is for this century the new challenge. One of the performance criteria is the reduction of total quantities of radioactive materials (liquid or solid) arising from dismantling and decontamination of radiological and nuclear installations. In this work we present a new application of the water soluble polymers used as: - flocculation agents in treatment and conditioning process within the management of radioactive liquid materials; - strippable coatings on solid materials based on the water soluble polymers. The parameters of water soluble polymers made in our Institute by radiation processing have been analysed, namely the molecular average weight, composition, and efficiency of utilization of these polymeric materials as well as the content of ash, additives, decontamination factor, consumption per surfaces/liter, corrosion aspects, compatibility with various surfaces (of ...

2003-10-20

90

Development of engineering technology basis for industrialization of pyrometallurgical reprocessing  

International Nuclear Information System (INIS)

Development of the engineering technology basis of pyrometallurgical reprocessing is a key issue for industrialization. For development of the transport technologies of molten salt and liquid cadmium at around 500 deg. C, a salt transport test rig and a metal transport test rig were installed in Ar glove box. Function of centrifugal pump and 1/2'' declined tubing were confirmed with LiCl- KCl molten salt. The transport behavior of molten salt was found to follow that of water. Function of centrifugal pump, vacuum sucking and 1/2'' declined tubing were confirmed with liquid Cd. With employing the transport technologies, industrialization applicable electro-refiner was newly designed and engineering-scale model was fabricated in Ar glove box. The electro-refiner has semi-continuous liquid Cd cathode instead of conventional one used in small-scale tests. With using actinide-simulating elements, ...

2007-09-09

91

Spray-formed tooling and aluminum strip  

Energy Technology Data Exchange (ETDEWEB)

Spray forming is an advanced materials processing technology that converts a bulk liquid metal to a near-net-shape solid by depositing atomized droplets onto a suitably shaped substrate. By combining rapid solidification processing with product shape control, spray forming can reduce manufacturing costs while improving product quality. De Laval nozzles offer an alternative method to the more conventional spray nozzle designs. Two applications are described: high-volume production of aluminum alloy strip, and the production of specialized tooling, such as injection molds and dies, for rapid prototyping.

1995-11-01

92

Production of a helium beam in a focused ion beam machine using an electron beam ion trap  

International Nuclear Information System (INIS)

Gallium liquid-metal ion sources that have been introduced in the late 1970s have allowed the development of a new class of micro- and nanofabrication tools collectively denominated as focused ion beam (FIB) machines. To investigate the potential of a helium beam in such a FIB instrument the authors have tested a room-temperature electron beam ion trap coupled with a high resolution FIB machine. In this letter they present their first results in target imaging using a helium beam with a resolution that allows to account for a beam diameter in the submicrometer range.

2007-02-19

93

Preparation of silver nanofluid by the submerged arc nanoparticle synthesis system (SANSS)  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this study is fabrication and characterization of silver nanofluid by the submerged arc nanoparticle synthesis system (SANSS). The silver metal electrodes under the electrical discharge will melt and evaporate rapidly and condense to form the nanoparticles in the lower temperature dielectric liquid and produce the suspended nanoparticle. The results showed that the spherical nanosilver particle formed in the ethylene glycol and the mean particle size is about 12.5 nm. The prepared silver nanofluid was irradiated under the 410 nm visible light, electrons could be excited from the valence band to the conduction band. The silver nanofluid more closely resembles Newtonian fluids.

2007-05-31

94

Investigation of the transportation requirements for fusion power plants  

Science.gov (United States)

This report presents a general investigation of the transport requirements associated with the construction and operation of conceptual fusion reactors. Projections of amounts of construction and operating materials requiring transportation are presented for several proposed designs. The material to be shipped is described along with the shipping containers that might be used, the transport modes and the expected impact of transporting these materials. Transportation of both radioactive and nonradioactive materials will be required. Most of these materials are routinely shipped by the transportation industry. Transportation requirements of a representative fusion reactor are also compared with Liquid Metal Fast Breeder Reactor (LMFBR) requirements.

1976-09-01

95

FFTF operating experience 1982-1984  

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) is a 400 MWt sodium-cooled fast reactor operated by Westinghouse Hanford Company for the US Department of Energy to conduct fuels and materials testing in support of the US Liquid Metal Fast Breeder Reactor programme. Early in 1982, the FFTF began its first 100 day irradiation cycle. Since that time the plant has operated very well, achieving a cycle capacity factor of 94 per cent in the most recent irradiation cycle. The authors describe the results achieved in the first three cycles of operation and carrying through to the fourth reactor cycle which began in January 1984. (author).

96

Enhanced LMR core cooling utilizing passive vortex devices  

International Nuclear Information System (INIS)

This paper reports several design options for improved passive circulation flow investigated for use in small, modular liquid metal cooled reactors (LMRs). The purpose is to enhance the transition to natural convection cooling following loss of forced circulation flow, reducing thermal transients experienced by the fuel and possibly eliminating the need for emergency pony-motor flow. Design details to minimize pressure drops may also enhance maximum equilibrium power levels possible under natural circulation only.

1988-05-01

97

Application of the GEM shutdown device to the FFTF reactor  

Energy Technology Data Exchange (ETDEWEB)

A novel device called the gas expansion model (GEM) is being developed at the Hanford Engineering Development Laboratory for testing in the 400-MW(th) fast flux test facility (FFTF) reactor. Incorporation of the GEM into liquid-metal reactor designs is intended to measurably contribute to the achievement of inherent safety, by allowing the reactor to passively shut down even in the extremely remote (hypothetical) event of an unprotected (no scram) loss-of-flow accident. The purpose of this paper is to describe the GEM and present predictive analyses of the effectiveness of the device during unprotected loss-of-flow experiments in the FFTF.

1986-01-01

98

Application of the GEM shutdown device to the FFTF reactor  

International Nuclear Information System (INIS)

A novel device called the gas expansion model (GEM) is being developed at the Hanford Engineering Development Laboratory for testing in the 400-MW(th) fast flux test facility (FFTF) reactor. Incorporation of the GEM into liquid-metal reactor designs is intended to measurably contribute to the achievement of inherent safety, by allowing the reactor to passively shut down even in the extremely remote (hypothetical) event of an unprotected (no scram) loss-of-flow accident. The purpose of this paper is to describe the GEM and present predictive analyses of the effectiveness of the device during unprotected loss-of-flow experiments in the FFTF.

1986-11-16

99

Analysis of the thermal performance of dynamic solar systems  

Energy Technology Data Exchange (ETDEWEB)

This article proposes a model for estimating the effect of the overall thermal resistance of the absorber and the coolant on a solar thermal energy system utilizing advanced heat transfer mediums. Two equations can be used to model a dynamic system: one for the maximum conversion efficiency and one to specify the constraint that, in quasi-steady state, the net energy collected must be transferred to the coolant. These two equations define a constrained optimization problem in two variables, the fluid and the absorber temperatures. The results present interesting implications for liquid metal, direct absorption, and solar evaporating systems.

1996-03-01

100

Laser-assisted solar cell metallization processing. Quarterly report, September 13-December 12, 1983  

Energy Technology Data Exchange (ETDEWEB)

The Westinghouse Electric Corporation has undertaken to investigate, develop, and characterize laser-assisted processing techniques utilized to produce the fine line, thin metal grid structures that are required to fabricate high-efficiency solar cells. Two basic techniques for metal deposition will be investigated, as follows: (1) photochemical decomposition of liquid or gas phase organometallic compounds utilizing either a focused, CW ultraviolet laser (System 1) or a mask and ultraviolet flood illumination, such as that provided by a repetitively pulsed, defocused excimer laser (System 2), for pattern definition, and (2) thermal deposition of metals from organometallic solutions or vapors utilizing a focused, CW laser beam as a local heat source to draw the metallization pattern. The purpose of this contract is to investigate the various existing laser-assisted film deposition ...

1984-01-16

101

Assessment Of Heavy Metal Contamination Of Arable Soils In Central Bekaa Plain, Lebanon  

International Nuclear Information System (INIS)

The study area is located in the Bekaa plain of Lebanon totaling about 12753 ha. It lies between the eastern foothills of Mount Lebanon chain and expands across the Litani River towards the foothills of the eastern Anti-Lebanon Mountains. Its characteristics, i.e. natural terrain, climate and socio-economy, make it vulnerable especially due to soil pollution. This paper tries to identify the nature and level of soil pollution by heavy metals. Valley slopes represent a complex landform and lithology that contributed to the formation of different soil. Agriculture in the plain is being practiced mainly with cash, field crops and vegetables. Throughout the central part of the plain, groundwater table is abundant and relatively high (<1.0 m. locally) that multiplies the vulnerability of the soil-groundwater system. There are different sources of pollution, such as industrial (tanneries, batteries, leather manufacturing), solid and liquid wastes, ...

2004-12-04

102

Liquid-metal flow in a sharp elbow in a uniform transverse magnetic field  

Science.gov (United States)

In the self-cooling blankets of the Tokamak fusion reactor, a liquid metal, namely liquid lithium, is pumped through a system of ducts to transfer heat and capture neutrons. One of the blanket designs proposed in Argonne National Laboratory's Blanket Comparison and Selection study uses a combination of poloidal and toroidal ducts in order to maximize heat transfer while minimizing net pressure drop. In the design, the poloidal and toroidal ducts meet at sharp, abrupt corners. They were modelled as two identical, straight, semi-infinite, thin-walled, rectangular ducts with 45{degree} miters and joined at a 90{degree} angle in the plane of a strong, uniform magnetic field. While in the toroidal containment vessel (i.e. the blanket), the liquid lithium is subjected to a large electromagnetic body force due to the presence of a strong magnetic field. This body force so dominates the flow as to make ...

1989-01-01

103

The US Advanced Liquid Metal Reactor and the Fast Flux Test Facility Phase IIA passive safety tests  

International Nuclear Information System (INIS)

This report discusses the safety approach of the Advanced Liquid Metal reactor program, sponsored by the US Department of Energy, which relies upon passive reactor responses to off-normal condition to limit power and temperature excursions to levels that allow safety margins. Gas expansion modules (GEM) have included in the design to provide negative reactivity to enhance these margins in the extremely unlikely event that pumping power is lost and the highly reliable scram system fails to operate. The feasibility and beneficial features of these devices were first demonstrated in the core of the Fast Flux Test Facility (FFTF) in 1986. Preapplication safety evaluations by the US Nuclear Regulatory Commission have identified areas that must be addressed if these devices are to be relied on. One of these areas is the response of the reactor when it is critical and the pumps are turned on, resulting in positive reactivity being added to the core. ...

1992-10-25

104

The U.S. Advanced Liquid Metal Reactor and the fast flux test facility phase IIA passive safety tests  

International Nuclear Information System (INIS)

The safety approach of the Advanced Liquid Metal Reactor program, sponsored by the U.S. Department of Energy, relies upon passive reactor responses to off-normal conditions to limit power and temperature excursions to levels that allow large safety margins. Gas expansion modules (GEM) have been included in the design to provide negative reactivity to enhance these margins in the extremely unlikely event that pumping power is lost and the highly reliable scram system fails to operate. The feasibility and beneficial features of these devices were first demonstrated in the core of the Fast Flux Test Facility (FFTF) in 1986. Pre-application safety evaluations by the U.S. Nuclear Regulatory Commission have identified areas that must be addressed if these devices are to be relied on. One of these areas is the response of the reactor when it is critical and the pumps are turned on, resulting in positive reactivity being added to the core. Tests to ...

105

Precious metal enrichment in the Platreef, Bushveld Complex, South Africa: evidence from homogenized magmatic sulfide melt inclusions  

Science.gov (United States)

Magmatic sulfide deposits are the most significant source of platinum-group elements (PGE) in the world. Key to understanding their genesis is determining the processes and timing of sulfide saturation, metal enrichment and crustal contamination. In this study, we have identified droplets of magmatic sulfide from the Platreef, South Africa, where droplets of sulfide have been trapped in the earliest crystallising phase, chromite. Due to their early entrapment at high temperatures, metal concentrations and ratios that they display are indicative of a very early-stage sulfide liquid in the system, as they will have cooled and fractionated within an essentially closed system, unlike interstitial blebs that crystallise in an open system as the magma cools. Analysis of these droplets in an opaque mineral like chromite by LA-ICP-MS is problematic as some of the fractionated inclusion is necessarily lost during cutting and ...

2011-06-01

106

Spectroscopic studies on the interaction of the antibiotic lasalocid A (x-537a) with technetium (V) ions in methanol  

International Nuclear Information System (INIS)

In the present study, the authors examine the interactions of pentavalent technetium ions (TcO/sup 3+/) with the basic form of the lasalocid A in pure methanol solvent and in methanol-water mixtures. There are a number of reasons for such a study. First, the interactions of technetium ions with biologically important compounds are of considerable importance owing to the widespread use of /sup 99m/Tc in diagnostic radio-imaging. Second, lasalocid A is known to transport metal ions across phospholipid bilayer membranes and between the aqueous cores of phospholipid inverse micelles. Third, lasalocid A is known to bind and solubilize metal ions in bulk organic liquid phases. Fourth, the conformation adopted by lasalocid A on interaction with TcO/sup 3+/ appears to be different than those found in most other cases and circumstances. Fifth, it may also be possible to use the competition of TcO/sup 3+/ with other, physiologically ...

107

Determination of reactivity from power spectral density measurements with /sup 252/Cf. [LMFBR  

Science.gov (United States)

The theory of a method of determination of reactivity from power spectral density measurements with /sup 252/Cf and the results of experiments with a critical assembly mockup of a liquid-metal fast breeder reactor (LMFBR) and with uranium (93.2 wt % /sup 235/U) metal cylinders and a sphere are presented. This method of reactivity determination has an advantage over existing methods in that it determines the reactivity only from properties of the reactor at the subcritical state of interest and thus does not require a calibration near delayed criticality. In these experiments, the reactivity was varied by changing the fissile loading or the amount of neutron absorber inserted; for the LMFBR mockup, the reactivity varied to approximately 75 dollars subcritical, and for the uranium metal assemblies to approximately 30 dollars subcritical. These experiments verified for the first time the predictions of theory that could be ...

1978-04-01

108

Batteries. Lithium batteries; Accumulateurs. Accumulateurs au lithium  

Energy Technology Data Exchange (ETDEWEB)

Lithium, with its strong reducing property and very low potential (-3.045 V/ENH), is one of the best material for electrodes. By combining lithium with an oxidizer, one can obtain an energy and electromotive force higher than with any other electrochemical couple. The density of lithium is low (0.534 g/cm{sup 3}) and thus, its specific capacity is higher than other classical anode materials. This article presents the technology of lithium batteries: 1 - presentation; 2 - negative electrodes: metallic lithium based, lithiated carbon based, transition metal compounds based negative electrodes; 3 - positive electrodes: 'low' voltage and 'high' voltage cathode materials; 4 - electrolytes: introduction, organic solvents and lithium salts-based electrolytes (case of the lithium anode battery, case of the lithium-ion battery), polymer electrolytes; 5 - metallic lithium anode and ...

2005-10-01

109

Cryogenic liquid transfer termination apparatus  

International Nuclear Information System (INIS)

Apparatus for termination of cryogenic liquid transfer from a liquid supply container to a storage-dispensing container is disclosed.

110

Multiphase reacting flow modeling of singlet oxygen generators for chemical oxygen iodine lasers.  

Energy Technology Data Exchange (ETDEWEB)

Singlet oxygen generators are multiphase flow chemical reactors used to generate energetic oxygen to be used as a fuel for chemical oxygen iodine lasers. In this paper, a theoretical model of the generator is presented along with its solutions over ranges of parameter space and oxygen maximizing optimizations. The singlet oxygen generator (SOG) is a low-pressure, multiphase flow chemical reactor that is used to produce molecular oxygen in an electronically excited state, i.e. singlet delta oxygen. The primary product of the reactor, the energetic oxygen, is used in a stage immediately succeeding the SOG to dissociate and energize iodine. The gas mixture including the iodine is accelerated to a supersonic speed and lased. Thus the SOG is the fuel generator for the chemical oxygen iodine laser (COIL). The COIL has important application for both military purposes--it was developed by the US Air Force in the 1970s--and, as the infrared beam is readily absorbed by ...

2008-08-01

111

Nonaqueous synthesis of metal oxide nanoparticles: Short review and doped titanium dioxide as case study for the preparation of transition metal-doped oxide nanoparticles  

Science.gov (United States)

The liquid-phase synthesis of metal oxide nanoparticles in organic solvents under exclusion of water is nowadays a well-established alternative to aqueous sol-gel chemistry. In this article, we highlight some of the advantages of these routes based on selected examples. The first part reviews some recent developments in the synthesis of ternary metal oxide nanoparticles by surfactant-free nonaqueous sol-gel routes, followed by the discussion of the morphology-controlled synthesis of lanthanum hydroxide nanoparticles, and the presentation of structural peculiarities of manganese oxide nanoparticles with an ordered Mn vacancy superstructure. These examples show that nonaqueous systems, on the one hand, allow the preparation of compositionally complex oxides, and, on the other hand, make use of the organic components (initially present or formed in situ) in the reaction mixture to tailor the morphology. Furthermore, obviously ...

2008-07-15

112

Metal Nanoparticles Preparation In Supercritical Carbon Dioxide Solutions  

Energy Technology Data Exchange (ETDEWEB)

The novel optical, electronic, and/or magnetic properties of metal and semiconductor nanoparticles have resulted in extensive research on new methods for their preparation. An ideal preparation method would allow the particle size, size distribution, crystallinity, and particle shape to be easily controlled, and would be applicable to a wide variety of material systems. Numerous preparation methods have been reported, each with its inherent advantages and disadvantages; however, an ideal method has yet to emerge. The most widely applied methods for nanoparticle preparation include the sonochemical reduction of organometallic reagents,(1&2) the solvothermal method of Alivisatos,(3) reactions in microemulsions,(4-6) the polyol method (reduction by alcohols),(7-9) and the use of polymer and solgel materials as hosts.(10-13) In addition to these methods, there are a variety of methods that take advantage of the unique properties of a supercritical fluid.(14&15) ...

2004-04-01

113

Solid/liquid lubrication of ceramics at elevated temperatures  

Energy Technology Data Exchange (ETDEWEB)

This study investigates the effect of solid and liquid lubrication on friction and wear performance of silicon nitride (Si{sub 3}N{sub 4}) and cast iron. The solid lubricant was a thin silver film ({approx}2 {mu}m thick) produced on Si{sub 3}N{sub 4} by ion-beam-assisted deposition. A high-temperature polyol-ester-base synthetic oil served as the liquid lubricant. Friction and wear tests were performed with pin-on-disk and oscillating-slider wear test machines at temperatures up to 300{degrees}C. Without the silver films, the friction coefficients of Si{sub 3}N{sub 4}/Si{sub 3}N{sub 4} test pairs were 0.05 to 0.14, and the average wear rates of Si{sub 3}N{sub 4} pins were {approx}5 x 10{sup -8} mm{sup 3} N{sup -1}. The friction coefficients of Si{sub 3}N{sub 4}/cast iron test pairs ranged from 0.08 to 0.11, depending on test temperature. The average specific wear rates of cast iron pins were {approx}3 x 10{sup -7} mm{sup 3} N{sup -1} m{sup -1}. ...

1996-04-01

114

Chamber technology concepts for inertial fusion energy: Three recent examples  

Energy Technology Data Exchange (ETDEWEB)

The most serious challenges in the design of chambers for inertial fusion energy (IFE) are 1) protecting the first wall from fusion energy pulses on the order of several hundred megajoules released in the form of x rays, target debris, and high energy neutrons, and 2) operating the chamber at a pulse repetition rate of 5-10 Hz (i.e., re-establishing, the wall protection and chamber conditions needed for beam propagation to the target between pulses). In meeting these challenges, designers have capitalized on the ability to separate the fusion burn physics from the geometry and environment of the fusion chamber. Most recent conceptual designs use gases or flowing liquids inside the chamber. Thin liquid layers of molten salt or metal and low pressure, high-Z gases can protect the first wall from x rays and target debris, while thick liquid layers have the added benefit of protecting structures from fusion ...

1997-02-27

115

Subsurface Injection of Liquid Waste  

Science.gov (United States)

... Other Sources Toxics Intranet Subsurface Injection of Liquid Waste -- Florida Surface features of a typical...

116

Liquid Radioactive Wastes Processing  

International Science & Technology Center (ISTC)

Methods of Decontamination, Utilization, and Deactivation of Liquid Radioactive Wastes

118

Visualization and measurement of heat transfer phenomenon  

Energy Technology Data Exchange (ETDEWEB)

This research aims at elucidating thermal hydraulic phenomena by carrying out their visualization and measurement which are difficult by conventional method, utilizing the excellent properties of real time neutron radiography and showing the usefulness of neutron radiography. The experiments were carried out on the visualization and measurement of liquid metal flow and mixed phase flow and the visualization and diagnosis of mixed phase flow equipment. As the achievement in this fiscal year, the image-processing method for visualizing quantitatively the distribution of void fraction in gas-liquid two-phase flow has been devised, therefore, its method and results are reported. For the analysis of multi-dimensional two-phase flow, in order to prepare the model and determine the constitution equation, the data on the multi-dimensional distribution of void fraction are required. Void fraction is defined. The method of image ...

1995-03-01

119

Tribological coatings for liquid metal and irradiation environments  

International Nuclear Information System (INIS)

Several metallurgical coatings have been developed that provide good tribological performances in high-temperature liquid sodium and that are relatively unaffected by neutron fluences to 6 X 10/sup 22/ n/cm/sup 2/ (E > 0.1 MeV). The coatings that have consistently provided the best tribological performance have been the nickel aluminide diffusion coatings created by the pack cementation process, chromium carbide or Tribaloy 700 trade mark (a nickel-base hardfacing alloy) applied by the detonation-gun process, and chromium carbide and other hardfacing alloy) applied by the detonation-gun process, and chromium carbide and other hardfacing materials applied by the electro-spark deposition process. The latter process is a relatively recent development for nuclear applications and is expected to find wide usage. Other coating processes, such as plasma-spray coating, sputtering, and chemical vapor deposition, were candidates for use on various components, but the ...

120

Surface modification/alloying using intense pulsed electron beam as a tool for improving the corrosion resistance of steels exposed to heavy liquid metals  

British Library Electronic Table of Contents (United Kingdom)

The alloying of steel surface with aluminum (Al) using Microsecond-pulsed Intense Electron Beams (MIEB-Al) was developed and optimized in order to be used for improving the corrosion resistance of the 316, 1.4970 and T91 steels, exposed to liquid Pb and Pb-Bi-eutectic. The procedure consists in two steps: (i) coating the steel surface with Al or an Al-containing alloy layer and (ii) melting the coating layer and the steel surface layer using intense pulsed electron beam. In order to cover the steel surface with an homogeneous and crack-free Al-alloyed layer, the following experimental conditions are required: Al coating thickness range 5-10mm, electron kinetic energy 120keV; pulse duration 30ms; energy density 40-45J/cm2; number of pulses 2-3. Using the mentioned procedure, the corrosion r...

2011-01-01

121

Start-up control system and vessel for LMFBR  

Energy Technology Data Exchange (ETDEWEB)

A reflux condensing start-up system includes a steam generator, a start-up vessel connected parallel to the steam generator, a main steam line connecting steam outlets of the steam generator and start-up vessel to a steam turbine, a condenser connected to an outlet of the turbine and a feedwater return line connected between the condenser and inlets of the steam generator and start-up vessel. The start-up vessel has one or more heaters at the bottom thereof for heating feedwater which is supplied over a start-up line to the start-up vessel. Steam is thus generated to pressurize the steam generator before the steam generator is supplied with a heat transfer medium, for example liquid sodium, in the case of a liquid metal fast breeder reactor. The start-up vessel includes upper and lower bulbs with a smaller diameter mid-section to act as water and steam reservoirs. The start-up vessel can thus be used not only in a start-up ...

1987-01-01

122

Separation of "1"8"7","1"8"8Pt and "1"8"7","1"8"8Ir produced in "1"1B"4"+ irradiated tantalum target  

International Nuclear Information System (INIS)

Heavy ion irradiation on tantalum metal target with 57 MeV "1"1B"4"+ leads to the production of no-carrier-added radioisotopes of platinum, "1"8"7","1"8"8Pt and iridium, "1"8"7","1"8"8Ir in the matrix, which have been effectively separated from the bulk target and from each other with suitable anion exchangers employing liquid-liquid extraction (LLX). Also "1"8"8","1"8"9Pt and "1"8"8","1"8"9Ir radionuclides have been produced, from their short-lived precursors "1"8"8","1"8"9Au, in "1"2C"6"+ irradiated tantalum matrix. Gamma-spectroscopy has been utilised to determine the production, extent of separation and purity of the radiotracers at different stages of the experiment. (orig.)

123

Preparation, characterization and electrical properties of SnO{sub 2} based liquid petroleum gas sensor  

Energy Technology Data Exchange (ETDEWEB)

The present investigation deals with the fabrication of liquid petroleum gas (LPG) sensor based on semiconducting oxide SnO{sub 2}. The gas sensor elements have been prepared by conventional solid state route. Addition of noble metal sensitizer, palladium and grain growth inhibitor, aluminum silicate to the base material SnO{sub 2}, not only improved the sensitivity towards LPG but also the selectivity in the presence of CO and CH{sub 4} gases. Out of various sensor compositions, SnO{sub 2}:Al{sub 2}Si{sub 2}O{sub 7} (35 wt.%):Pd (1.5 wt.%) sintered at 800 C for 5 h has shown high sensitivity (0.97) towards LPG at an operating temperature of 350 C. Different characterization techniques have been employed, such as differential thermal analysis (DTA), surface area analyzer, X-ray diffraction (XRD), to study the formation of SnO{sub 2}, surface area and crystallite size, respectively. The results suggested the possibility of utilizing the sensor ...

1999-03-25

124

Physical properties of Ti/sub 50/Be/sub 40/Zr/sub 10/ glass  

Science.gov (United States)

Continuous metallic glass ribbons were produced by mejans of liquid-quenching at rates >10/sup 50/C/s. The ribbons, typically 30 ..mu..m thick and 1 to 2 mm wide, were determined to be glassy by X-ray diffraction (XRD) employing CuK..cap alpha.. and MoK..cap alpha.. radiation. Mechanical properties of the as-quenched product were determined by measurements of hardness, tensile strength and Young's modulus. The Vicker's diamond pyramid microhardness (H/sub V/) was measured on epoxy mounted samples using a Lietz Miniload instrument with a 100 g load. Tensile tests were conducted in an Instron machine using specimens which were hand-polished to produce smooth, parallel sides. Young's modulus (E) is given by the relationship rho V/sub E/sup 2//. V/sub E/, the velocity of extensional mode waves, was measured by the pulse-echo technique using a Panametrics Intervalometer and glass density, rho, was obtained by the ...

1977-09-01

125

Numerical simulations of industrial processes involving fluid dynamics, combustion and radiation  

Energy Technology Data Exchange (ETDEWEB)

Moving out of the scientific community research laboratories, computational fluid dynamics (CFD) software packages are now allowing industrials to analyse and optimize industrial processes involving the use of gases, liquids and even some two-phase fluids. Their attractiveness and their impact stems out from the opportunity they offer to bring insight into an existing unit, or even at the design stage, by displaying the spatial distribution of process relevant variables such as temperature, concentration. The filling of the spacing in between a two-layer window is a simple example. This new opportunity of visualisation is at times an unique way, when the process environment is an opaque one, such as liquid metal flowing into a tundish or when measurements of flows may be a long and tedious work, such as flows within water treatment basins. This environment we are to investigate in order to optimize can also be a harsh one, ...

1997-12-31

126

Evaluation of value for hydrogen release from high-level liquid waste. 4. Hydrogen release rate for {gamma}-ray radiolysis of simulated purex waste solutions  

Energy Technology Data Exchange (ETDEWEB)

The rates of hydrogen release from simulated high-level liquid waste (SHLLW) during irradiation of {sup 60}Co {gamma}-rays have been studied using a laboratory-scale apparatus. The SHLLW used was made up of 28 different metal elements, the concentrations of which were determined from a computed data (ORIGEN-2) for a Purex spent fuel (burn-up of 4.5 GWd/t, cooling time of 4 years) except for those of corrosion products (Fe, Cr and Ni) and of chemical process additive (P). The nitrate ion concentration of the SHLLW was 4.97 M. The G-value of hydrogen release was 0.0164 for stirred conditions, but for nonstirred conditions with dose rate : 2.8 kGy/h and with the SHLLW solution height more than 8 cm, the following relation was found between the G-value and the solution height (d cm); G(H{sub 2}) = 0.100 d{sup -1.6}. The G-values of oxygen and nitrogen releases were also determined. (author)

1997-12-01

127

Evaluation of value for hydrogen release from high-level liquid waste. 4. Hydrogen release rate for #gamma#-ray radiolysis of simulated purex waste solutions  

International Nuclear Information System (INIS)

The rates of hydrogen release from simulated high-level liquid waste (SHLLW) during irradiation of "6"0Co #gamma#-rays have been studied using a laboratory-scale apparatus. The SHLLW used was made up of 28 different metal elements, the concentrations of which were determined from a computed data (ORIGEN-2) for a Purex spent fuel (burn-up of 4.5 GWd/t, cooling time of 4 years) except for those of corrosion products (Fe, Cr and Ni) and of chemical process additive (P). The nitrate ion concentration of the SHLLW was 4.97 M. The G-value of hydrogen release was 0.0164 for stirred conditions, but for nonstirred conditions with dose rate : 2.8 kGy/h and with the SHLLW solution height more than 8 cm, the following relation was found between the G-value and the solution height (d cm); G(H_2) = 0.100 d"-"1"."6. The G-values of oxygen and nitrogen releases were also determined. (author).

1997-01-01

128

Development of pyrometallurgical partitioning of transuranium elements from high-level liquid waste. Improvement to pyrometallurgical partitioning process and process demonstration  

Energy Technology Data Exchange (ETDEWEB)

The partitioning of transuranium elements (TRUs) from high-level liquid waste (HLLW) through the use of pyrometallurgical technology has been underway since 1986, for the purpose of the improving the safety and public acceptance of the disposal of high-level vitrified waste. Prior to the pyrometallurgical partitioning process, the alkali metals can be separated at the denitration process for oxide conversion of HLLW, chlorination in a chloride salt bath can be used to effectively convert oxides to chlorides, and evaporated chlorides can be captured with high efficiency in another adopted chloride salt bath. The higher separation factors between actinides and rare earths are obtained in a LiCl-KCl/Bi system than in a LiCl-KCl/Cd system. Based on the results, we propose a practical process flow for partitioning TRUs from HLLW by pyrometallurgical technology. This process was demonstrated successfully using simulated purex waste. Each element of ...

1998-10-01

129

Conceptual design for accelerator-driven sodium-cooled sub-critical transmutation reactors using scale laws  

Energy Technology Data Exchange (ETDEWEB)

The feasibility study on conceptual design methodology for accelerator-driven sodium-cooled sub-critical transmutation reactors has been conducted to optimize the design parameters from the scale laws and validates the reactor performance with the integrated code system. A 1000 MWth sodium-cooled sub-critical transmutation reactor has been scaled and verified through the methodology in this paper, which is referred to Advanced Liquid Metal Reactor (ALMR). A Pb-Bi target material and a partitioned fuel are the liquid phases, and they are cooled by the circulation of secondary Pb-Bi coolant and by primary sodium coolant, respectively. Overall key design parameters are generated from the scale laws and they are improved and validated by the integrated code system. Integrated Code System (ICS) consists of LAHET, HMCNP, ORIGEN2, and COMMIX codes and some files. Through ICS the target region, the core region, and ...

1998-12-31

130

Microbial remediation of soil pollution from ore mining. Part 3: Cyanide removal and biosorption of heavy metals in mining and processing water; Untersuchungen zur mikrobiellen Sicherung von Erzbergbaualtlasten. Teilvorhaben 3: Cyanidabbau und Biosorption von Schwermetallen in Abwaessern aus Erzbergbau- und Aufbereitungsbetrieben. Abschlussbericht  

Energy Technology Data Exchange (ETDEWEB)

1. Cyanide degradation: Of the cyanide- and thiocyanate-degrading bacteria, Burkholderia cepacia and Pseudomonas spec. were the most effective. 2. Biosorption: Of the isolates suited for biosorption of heavy metals, 597-A (non-identifiable) and 597-A2 (Aspergillus fumigatis) had the biggest potential. The sorption capacity of the fungi for metals varied with the C source used for their growth: apple juice > molasses > glucose. The fungi are not cyanide-sensitive and can even degrade cyanide. Living biomass had better metal sorption efficiencies than dead mycelium. The biosorption rates in waste water were usually higher than in broth. Depending on the metal composition and concentrations and on the exposure time and volume of the mycelia, up to 85 % of the initial concentration was removed from the liquid phase. The capacity of different biomasses for the sorption of ...

1999-12-01

131

Behavior of Aqueous Electrolytes in Steam Cycles - The Final Report on the Solubility and Volatility of copper(I) and Copper(II) Oxides  

Energy Technology Data Exchange (ETDEWEB)

Measurements were completed on the solubility of cupric and cuprous oxides in liquid water and steam at controlled pH conditions from 25 to 400 C (77 to 752 F). The results of this study have been combined with those reported from this laboratory in two previous EPRI reports to provide a complete description of the solubility of these oxides and the speciation of copper dissolved in liquid water and steam as a function of oxidation state, temperature, pH, and in the case of steam, pressure. These constitute the first set of reliable data for cuprous oxide solubility over this range of conditions. For the more intensively studied CuO case, agreement was found between our results and those of previous studies of its solubility in steam, whereas only partial agreement was evident for its solubility in liquid water. For both oxides this disagreement often amounted to orders of magnitude. The solubility of cuprous oxide is ...

2004-05-01

132

Theoretical analysis of the DC electromagnetic flow coupler  

Energy Technology Data Exchange (ETDEWEB)

A descriptive model and design procedure for the DC electromagnetic flow coupler is developed based on a quasi-one-dimensional analysis previously developed for the DC electromagnetic pump. It is shown that for a particular flow coupler geometry, the total efficiency and the pressure gradients through the pump and generator depend on two parameters - the Hartmann number and the ratio of the pump flow rate to generator flow rate. Thus, for a fixed Hartmann number the efficiency depends only on the flow ratio. However, for a fixed pressure rise through the pump it is shown that the efficiency depends only on the Hartmann number. Nomographs showing the operating characteristics and critical design points are presented. Example calculations for a full-size unit, suitable for use in a liquid-metal cooled fast breeder reactor, are also discussed using the design nomographs.

1983-03-01

133

The surface chemistry of iron Fischer-Tropsch catalysts  

Energy Technology Data Exchange (ETDEWEB)

The indirect conversion of coal to liquid hydrocarbons via steam gasification followed by synthesis gas (CO/H/sub 2/) chemistry has been the subject of intensive study for a number of decades. A key technological challenge facing researchers in this area is control over the product distribution during the hydrocarbon synthesis step. In the case of iron Fischer-Tropsch catalysts, it has been known that the addition of alkali to the metal catalyst has a significant impact on the product distribution. Iron catalysts treated with alkali produce less methane more alkenes and higher molecular weight products. In spite of numerous investigations, the details of this promotional effect are not understood on a molecular level. To explore the role of alkali in the surface chemistry of iron catalysts, the authors have carried out a combined surface science and catalytic kinetic study of a model iron catalyst with and without surface alkali.

1986-04-01

134

Superconductivity in cage doped fullerenes. Final report  

Energy Technology Data Exchange (ETDEWEB)

Motivated by the discovery of superconductivity in alkali and alkaline earth fullerides, this program was undertaken both to understand the nature of and expand the range of materials demonstrating superconductivity. The first approach involved attempts to modify the fullerene cage by incorporating heteroatoms in the structure and the preparation and photophysical properties of nitrogen and sulfur doped fullerenes were studied in detail. The second approach involved examining the stoichiometry and effect of preparative conditions on the behavior of alkali, alkaline earth, lanthanide and mixed ion fullerides. In particular, the authors have elaborated on a technique for making such salts using liquid ammonia or aliphatic amines as solvents. Thirdly, modeling studies were undertaken to predict the properties of heterohedral fullerines and metal - C60 complexes, and theoretical guidelines were developed for understanding the reactivity of the ...

1996-08-26

135

Status and progress in sludge washing: A pivotal pretreatment method  

Energy Technology Data Exchange (ETDEWEB)

Separation of the bulk soluble chemical salts from the insoluble metal hydroxides and radionuclides is central to the strategy of disposing Hanford tank waste. Sludge washing and caustic leaching have been selected as the primary methods for processing the 230 million L (61,000,000 gal) of Hanford tank waste. These processes are very similar to those selected for processing waste at the West Valley Site in New York and the Savannah River Site in South Carolina. The purpose of sludge washing is to dissolve and remove the soluble salts in the waste. Leaching of the insoluble solids with caustic will be used to dissolve aluminum hydroxide and chromium hydroxide, and convert insoluble bismuth phosphate to soluble phosphate. The waste will be separated into a high-level solids fraction and a liquid fraction that can be disposed of as low-level waste after cesium removal. The washing and leaching operations involve batchwise mixing, settling, and ...

1995-01-01

136

Safety philosophy and concepts for large liquid metal breeder reactor power plants  

International Nuclear Information System (INIS)

This paper addresses the unique related aspects of the LMFBR concept which are of significance to containment design and structural analysis. Topics covered include: Primary boundary integrity assurance; Effects of sodium spills on integrity of structures; Provisions being considered for containment of melted cores; Fuel handling accidents. Specific reference is made to the FFTF and the Clinch River Breeder Reactor Project designs and methods of treatment of the above problems. In particular, the part played by tests, such as those carried out on a simulated FFTF model, and the planned structural reliability and related programs are considered. Where practicable, these topics are addressed in a manner which places FFTF and CRBR in context with other LMFBR's and point to a possible direction for future American LMFBR designs. (Auth.).

137

Safety philosophy and concepts for large liquid metal breeder reactor power plants  

International Nuclear Information System (INIS)

This paper will adress the unique safety related aspects of the LMFBR concept which are of significance to containment design and structural analyses. Topics to be covered will include: primary boundary integrity assurance; effects of sodium spills on integrity of structures; provisions being considered for containment of melted cores; and fuel handling accidents. Specific reference will be made to the FFTF and the Clinch River Breeder Reactor Project designs and methods of treatment of the above problems. In particular, the part played by tests, such as those carried out on a simulated FFTF model, and the planned structural reliability and related programs will be considered. Where practicable, these topics will be addressed in a manner which places FFTF and CRBR in context with other LMFBR's, and will point to a possible direction for future American LMFBR designs.

1975-09-01

138

Results of the 1986 FFTF inherent safety tests  

International Nuclear Information System (INIS)

A series of tests was recently completed at the 400-MW (thermal) Fast Flux Test Facility (FFTF) to further demonstrate the passive safety characteristics of liquid-metal-cooled fast reactors. Earlier FFTF testing of decay heat removal by sodium natural circulation was reported in 1981. The main purpose of the 1986 test series was to demonstrate passive reactor shutdown during a loss-of-flow event when several inherent shutdown devices called gas expansion modules (GEMs) were installed in the reactor. However, these tests also provide further data on the natural circulation performance of the primary system, in particular the reactor core, and thus add to the data base available for checking the validity of available analytical tools.

1987-06-07

139

Recent developments in the CONTAIN-LMR code  

International Nuclear Information System (INIS)

Through an international collaborative effort, a special version of the CONTAIN code is being developed for integrated mechanistic analysis of the conditions in liquid metal reactor (LMR) containments during severe accidents. The capabilities of the most recent code version, CONTAIN LMR/1B-Mod.1, are discussed. These include new models for the treatment of two condensables, sodium condensation on aerosols, chemical reactions, hygroscopic aerosols, and concrete outgassing. This code version also incorporates all of the previously released LMR model enhancements. The results of an integral demonstration calculation of a sever core-melt accident scenario are given to illustrate the features of this code version. 11 refs., 7 figs., 1 tab.

1990-08-12

140

Real-time neutron radiography applications in dynamic fluid flow studies  

Energy Technology Data Exchange (ETDEWEB)

Real-time neutron radiography (RTNR) is now proving to be a valuable research tool in the study of hydrogenous fluid flow. One of the most significant advantages of neutron radiography is the ability to image hydrogenous substances (such as lubricants, coolants, and fuels) inside metallic materials such as aluminum and titanium engines. By using RTNR, one can then study dynamic events such as the movement of liquids inside these solids. The Phoenix Memorial Laboratory (PML) at the University of Michigan has recently developed and installed a facility dedicated to RTNR. The work at PML has shown that RTNR of dynamic events can provide information enabling the researcher to follow dynamic events that were previously impossible or impractical. This paper will show the variety of uses of RTNR presently being pursued at PML.

1986-01-01

141

Real-time neutron radiography applications in dynamic fluid flow studies  

International Nuclear Information System (INIS)

Real-time neutron radiography (RTNR) is now proving to be a valuable research tool in the study of hydrogenous fluid flow. One of the most significant advantages of neutron radiography is the ability to image hydrogenous substances (such as lubricants, coolants, and fuels) inside metallic materials such as aluminum and titanium engines. By using RTNR, one can then study dynamic events such as the movement of liquids inside these solids. The Phoenix Memorial Laboratory (PML) at the University of Michigan has recently developed and installed a facility dedicated to RTNR. The work at PML has shown that RTNR of dynamic events can provide information enabling the researcher to follow dynamic events that were previously impossible or impractical. This paper will show the variety of uses of RTNR presently being pursued at PML.

1986-11-16

142

Radiological operating experience at FFTF [Fast Flux Test Facility  

International Nuclear Information System (INIS)

The Fast Flux Test Facility has been in operation for approximately five years, including about one thousand days of full power operation of the Fast Test Reactor. During that time the collective dose equivalents received by operating personnel have been about two orders of magnitude lower than those typically received at commercial light water reactors. No major contamination problems have been encountered in operating and maintaining the plant, and release of radioactive gas to the environment has been minimal and well below acceptable limits. All shields have performed satisfactorily. Experience to date indicates an apparent radiological superiority of liquid metal reactor systems over current light water plants.

1987-04-22

143

Precise measurement of a focused ion beam profile  

Energy Technology Data Exchange (ETDEWEB)

The profile of focused boron ion beam (FIB) from a liquid metal ion source was determined by MOS device characteristics and resist exposure experiments. A focused boron ion beam was line-scanned into the middle of the channel region along the source to drain direction of a MOSFET, and the effective channel width is determined from electrical measurements. PMMA resist was also exposed by a line-scanned boron FIB and the developed contour was observed by a SEM. The profile of the focused boron ion beam with a diameter of around 0.2 ..mu..m was determined by these two methods and it was found to have about a 1 ..mu..m wide tail at around three orders of magnitude below the peak current density region. The profile difference between the two measurements are attributed to the boron diffusion in silicon by subsequent heat-treatments during device fabrication.

1987-06-01

144

Point-contact Andreev spectroscopy on thin Ni_2MnIn Heusler films  

International Nuclear Information System (INIS)

Heusler films with L2_1 and B2 structure are deposited simultaneously on amorphous carbon films, Si(100) surfaces, and in situ cleaved InAs(110) surfaces by coevaporation of Ni and the alloy MnIn. Morphology, structure, and stoichiometry are investigated with transmission-electron microscopy, electron diffraction, and X-ray spectroscopy. The almost perfect lattice match supports highly oriented growth of Ni_2MnIn on InAs, which is proven by electron diffraction under grazing incidence. The electrical resistivity of thin films on Si show metallic behavior. At temperatures of liquid helium point-contact Andreev reflection spectroscopy is performed on films grown on Si(100) and in situ cleaved InAs(110) surfaces yielding spin polarizations comparable to the ones of Fe, Ni, Co, and permalloy (Ni_8_0Fe_2_0).

2007-09-01

145

Orbital ordering, ferroelasticity, and the large pressure induced volume collapse in PbCrO3  

CERN Document Server

We report a new tetragonal ground-state for perovskite-structured PbCrO3 from DFT+U calculations, and explain its anomalously large volume. The new structure is stabilized due to orbital ordering of Cr-d in the presence of a large tetragonal crystal field, mainly due to off-centering of the Pb atom. At higher pressures (smaller volumes) there is a first-order transition to a cubic phase where the Cr-d orbitals are orbitally liquid. This phase-transition is accompanied by a ~11.5% volume collapse, one of the largest known for transition-metal oxides. The large ferroelasticity and its strong coupling to the orbital degrees of freedom could be exploited to form potentially useful magnetostrictive materials

2011-01-01

146

NONLINEAR OPTICAL PHENOMENA: Nonlinear optical properties of colloidal silver nanoparticles produced by laser ablation in liquids  

Science.gov (United States)

The optical and nonlinear optical properties of colloidal solutions of silver obtained by laser ablation in water and ethanol are studied. It is shown that freshly prepared colloids experience a full or partial sedimentation by changing their nonlinear optical properties. Aqueous colloids undergo a partial sedimentation and their nonlinear optical absorption changes to nonlinear optical transmission. The obtained results are interpreted using the Drude model for metal particles taking the particle size into account and can be explained by the sedimentation of larger silver particles accompanied by the formation of a stable colloid containing silver nanoparticles with a tentatively silver oxide shell. The characteristic size of particles forming such a stable colloid is determined and its optical nonlinearity is estimated.

2004-07-01

147

Multi-Dimensional Analysis for Sodium Hot Pool using MARS-LMR in Steady State  

International Nuclear Information System (INIS)

DBEs (Design Basis Event) of KALIMER-600 (Korea Advanced Liquid Metal Reactor) were analyzed in one dimension by KAERI (Korea Atomic Energy Research Institute). KALIMER-600 is the pool type SFR (Sodium cooled Fast Reactor), thereby the sodium of primary system is prohibited movement to out of a reactor vessel. There are many contacting and including compositions in the sodium hot pool, such as IHX (Intermediate Heat eXchanger), DHX (Decay Heat eXchanger), Pump, UIS (Upper Internal Structure), and core. Moreover, the complex phenomena are occurred in sodium hot pool during steady and transient states. Therefore, the one dimensional analysis is modified to the multi-dimensional analysis through modification of sodium hot pool from one to three dimensions

2010-10-01

148

Liquid metal reactor cover gas purification and analysis in the USA  

International Nuclear Information System (INIS)

Two sodium cooled reactors are currently being operated in the United States of America for the US Department of Energy. These are Experimental Breeder Reactor 11, EBR-11, and the Fast Flux Test Facility, FFTF. EBR-11 is located near Idaho Falls, Idaho, and the FFTF is near Richland, Washington. These reactors are currently engaged in a wide range of testing including fuels and materials tests, and plant system performance and safety development. The US DOE program also includes designs of a next generation sodium cooled power reactor. The FFTF and EBR-11 communities are providing input to these designs. This paper discusses the efforts to develop and operate cover gas systems for the sodium cooled nuclear reactor program in the USA.

1986-09-24

149

Laser-generated PuO_2--UO_2 condensation aerosols  

International Nuclear Information System (INIS)

A 340-watt CO_2 laser is being used to generate PuO_2-UO_2 condensation aerosol from the surface of a Liquid Metal Fast Breeder Reactor (LMFBR) fuel pellet. A wide range of concentrations is achieved by varying the laser power, pulse width, and/or pulse period. The resulting aerosol is composed of branch chain-like aggregates, with the primary particle size ranging between 0.005 and 0.15 #mu#m. X-ray diffraction analyses show that these aerosols condense into a face-centered cubic crystal structure. The activity mean aerodynamic diameter (AMAD), for most power levels, is approximately 0.85 #mu#m with a geometric standard deviation of 1.5.

1977-05-01

150

Instabilities in Focused Ion Beam-patterned Au nanowires  

British Library Electronic Table of Contents (United Kingdom)

Focused Ion Beam (FIB) technology has become an indispensable enabling tool for micro nano fabrications. One important application is to use FIB for patterning conducting nanowires of metals down to a few tens of nanometre for applications such as interconnects, heaters and temperature nanosensors. A series of experiments on Au nanowires fabricated by FIB on SixNy membrane show that nanowires with width 50nm have structural instabilities. These are liquid like and first show-up as undulations in nanowire width with clearly defined wave lengths. For smaller widths (20nm) the instabilities grow and the wires eventually break-up into spherical balls. Further experiments show that the nanowires can be made stable to smaller widths by the use of a Cr underlayer to enhance surface wetting. The o...

2011-01-01

151

Hydrogen energy storage: hydrogen and oxygen storage subsystems  

Energy Technology Data Exchange (ETDEWEB)

Hydrogen seems to possess all the characteristics to store the excess of electrical energy produced during off-peak periods. Hydrogen energy storage plants could be environmentally non-polluting, easy to place, not sensible to load variation, unbounded in size, efficient and safe. These last two features seem to contradict one another. An option that could give a reliable solution is the storage of hydrogen in metal hydride and the storage of oxygen as a liquid. Such a choice is probably the safest one to make and allows the achievement of efficiencies comparable to those obtainable with gaseous storage of both electrolytic products. The power consumption for H{sub 2} and O{sub 2} storage is only 3% of the total energy stored and the charging ratio approaches the values obtained with hydro-pumped storage plants. (Author)

1997-12-31

152

Focused ion beam preparation of inclined planes in semiconductor materials  

International Nuclear Information System (INIS)

Focused ion beam (FIB) micromachining has been used to produce inclined planes on semiconductor surfaces. A 10 keV FIB system, utilising a Ga"+ liquid metal ion source (LMIS), was employed. The ramped surfaces were prepared by digitally deflecting the ion beam in a serpentine fashion over a rectangular area and incrementing the time the beam spends at a pixel, dwell time, line by line. For the conditions used, control in micromachining the inclination of the ramps to the starting horizontal surface is of the order of 1 arc s per scan of the FIB over the area of interest. The possibility of using such surfaces prepared by FIB, along with vacuum growth techniques such as molecular beam epitaxy (MBE), for application to strain relief structures and lateral device production is discussed. (author).

153

Five years operating experience at the Fast Flux Test Facility  

Energy Technology Data Exchange (ETDEWEB)

The Fast Flux Test Facility (FFTF) is a 400 Mw(t), loop-type, sodium-cooled, fast neutron reactor. It is operated by the Westinghouse Hanford Company for the United States Department of Energy at Richland, Washington. The FFTF is a multipurpose test reactor used to irradiate fuels and materials for programs such as Liquid Metal Reactor (LMR) research, fusion research, space power systems, isotope production and international research. FFTF is also used for testing concepts to be used in Advanced Reactors which will be designed to maximize passive safety features and not require complex shutdown systems to assure safe shutdown and heat removal. The FFTF also provides experience in the operation and maintenance of a reactor having prototypic components and systems typical of large LMR (LMFBR) power plants. The 5 year operational performance of the FFTF reactor is discussed in this report. 6 refs., 10 figs., 2 tabs.

1987-04-01

154

Five years operating experience at the Fast Flux Test Facility  

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) is a 400 Mw(t), loop-type, sodium-cooled, fast neutron reactor. It is operated by the Westinghouse Hanford Company for the United States Department of Energy at Richland, Washington. The FFTF is a multipurpose test reactor used to irradiate fuels and materials for programs such as Liquid Metal Reactor (LMR) research, fusion research, space power systems, isotope production and international research. FFTF is also used for testing concepts to be used in Advanced Reactors which will be designed to maximize passive safety features and not require complex shutdown systems to assure safe shutdown and heat removal. The FFTF also provides experience in the operation and maintenance of a reactor having prototypic components and systems typical of large LMR (LMFBR) power plants. The 5 year operational performance of the FFTF reactor is discussed in this report. 6 refs., 10 figs., 2 tabs.

1987-09-13

155

FFTF operating experience, 1982-1984  

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) is a 400 Mwt sodium-cooled fast reactor operating at the Hanford Engineering Development Laboratory, Richland, Washington, to conduct fuels and materials testing in support of the US Liquid Metal Fast Breeder Reactor (LMFBR) program. Startup and initial power testing included a comprehensive series of nonnuclear and nuclear tests to verify the thermal, hydraulic, and neutronic characteristics of the plant. A specially designed series of natural circulation tests were then performed to demonstrate the inherent safety features of the plant. Early in 1982, the FFTF began its first 100-day irradiation cycle. Since that time the plant has operated very well, achieving a cycle capacity factor of 94% in the most recent irradiation cycle. Seventy-five specific test assemblies and 25,000 individual fuel pins have been irradiated, some in excess of 80 MWd/Kg.

1984-04-09

156

FFTF criteria for run-to-cladding-breach experiments  

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) is a liquid-metal-cooled fast reactor, which is designed to test a variety of different structural and fuel materials. A safety analysis is performed for each experiment that is irradiated in FFTF. The FFTF final safety analysis report (FSAR) assumed that all driver fuel assemblies would maintain cladding integrity during normal operations and all design transients. Maintenance of cladding integrity retains three barriers to any fission gas release to the public and also prevents any potential contact between the fuel and coolant. Experiments are, in general, expected to meet the same criterion. Selected experiments can, however, be classified as run-to-cladding-breach experiments (RTCB). The purpose of this paper is to describe alternative acceptance criteria for RTCB experiments that they feel provide protection equivalent to the maintenance of cladding integrity.

1986-06-15

157

Electron beam induced reactions in metal/Si systems  

Energy Technology Data Exchange (ETDEWEB)

Thin Pt, Pd, Pt/sub 2/Si, PtSi, Pd/sub 2/Si, Ni, Mo, W, Nb, Ti, V films deposited on Si single crystal were treated by using electron beam pulses of 60 ns duration in the 0.4-4 J/cm/sup 2/ energy density range. Irradiation of these structures produces at the same time many phases. Post-thermal annealing of the reacted layer induces the formation of a stable phase, the same obtained by only thermal treatment in a conventional furnace. A linear relationship between the energy density range and the lowest eutectic temperature of the compounds formed has been found. Further SEM observations seem to identify a liquid layer from which the phases are forming by subsequent fast cooling.

1982-01-01

158

Electron beam induced reactions in metal/Si systems  

International Nuclear Information System (INIS)

Thin Pt, Pd, Pt_2Si, PtSi, Pd_2Si, Ni, Mo, W, Nb, Ti, V films deposited on Si single crystal were treated by using electron beam pulses of 60 ns duration in the 0.4-4 J/cm"2 energy density range. Irradiation of these structures produces at the same time many phases. Post-thermal annealing of the reacted layer induces the formation of a stable phase, the same obtained by only thermal treatment in a conventional furnace. A linear relationship between the energy density range and the lowest eutectic temperature of the compounds formed has been found. Further SEM observations seem to identify a liquid layer from which the phases are forming by subsequent fast cooling. (author).

159

Direct strip casting of magnesium  

Energy Technology Data Exchange (ETDEWEB)

A new interest in magnesium alloys has arisen since light-weight constructions have become more and more attractive. Products that are currently available are mostly cast, forged, and extruded. A cost-effective production of sheet metals will render new perspectives in the design of light-weight constructions. The development of new casting technologies like thin slab casting or strip casting with an in-line rolling process is expected to result in a shorter processing time featuring a high potential of saving energy, time, and cost. Particular attention is paid to the casting process parameters such as casting speed and solidification speed. This article deals with some aspects of a magnesium-adapted single-belt caster. Results of casting experiments and material examination are shown as well as some advices given concerning safety and handling of liquid magnesium. (orig.)

2004-12-01

160

Corrosion experiments and materials developed for the Japanese HLM systems  

British Library Electronic Table of Contents (United Kingdom)

The static corrosion tests in lead-bismuth eutectic (LBE) were conducted from 450degreeC to 600degreeC to understand corrosion behavior and develop corrosion resistant materials for heavy liquid metal systems. While increase of Cr content in steels enhances corrosion resistance in LBE, the effect approaches a constant value above 12wt% of Cr. Corrosion depth in LBE increases with increasing temperature and corrosion attack becomes severe above 550degreeC even under the condition of high oxygen concentration. Nickel dissolution and Pb-Bi penetration occur in 316SS and JPCA above 550degreeC under the condition of high oxygen concentration. When oxygen concentration decreases below the level of Fe oxide formation, corrosion attack on these steels also becomes violent due to dissolution of var...

2011-01-01

161

Correlation effects in partially ionized mass asymmetric electron-hole plasmas  

CERN Document Server

The effects of strong Coulomb correlations in dense three-dimensional electron-hole plasmas are studied by means of unbiased direct path integral Monte Carlo simulations. The formation and dissociation of bound states, such as excitons and bi-excitons is analyzed and the density-temperature region of their appearance is identified. At high density, the Mott transition to the fully ionized metallic state (electron-hole liquid) is detected. Particular attention is paid to the influence of the hole to electron mass ratio $M$ on the properties of the plasma. Above a critical value of about M=80 formation of a hole Coulomb crystal was recently verified [Phys. Rev. Lett. {\\bf 95}, 235006 (2005)] which is supported by additional results. Results are related to the excitonic phase diagram of intermediate valent Tm[Se,Te], where large values of $M$ have been observed experimentally.

2007-01-01

162

Coal-liquefaction-process research quarterly report, January 1 - March 31, 1982  

Science.gov (United States)

Objectives of the program are to understand the mechanisms of coal liquefaction, to determine the role of catalysts in the direct conversion of coal to liquids, to determine the mechanism of catalyst deactivation and to explore slurry phase catalyst systems. Specific projects include: short-contact time coal liquefaction, mineral matter effects and catalyst studies. During this period, work was performed on: (1) the stability, at reaction temperature, of a recycle solvent obtained from the Lummus Two Stage Liquefaction facility, (2) reactions of preasphaltenes and asphaltenes prepared under various reaction severities, (3) the evaluation of the catalyst level detector installed at the H-Coal facility, (4) the characterization of oil soluble metal compounds with respect to hydrogenation activity, and (5) characterization, deactivation and regeneration of catalysts obtained from both the H-Coal and Lummus facilities.

1982-10-01

163

Bloch-Boltzmann analysis of electrical transport in intermetallic compounds: ReO[sub 3], BaPbO[sub 3], CoSi[sub 2], and Pd[sub 2]Si  

Energy Technology Data Exchange (ETDEWEB)

The shape and magnitude of the electrical resistivity [rho]([ital T]) is analyzed for four intermetallic compounds, and electron-phonon coupling constants [lambda] are extracted. ReO[sub 3] is particularly interesting because a sharp departure from the Bloch-Grueneisen shape can be attributed to high-frequency optical vibrations. The [lambda] values for the oxide metals seem too large to be consistent with the absence of superconductivity, but the results generally agree well with a conventional Fermi-liquid interpretation. The Hall coefficient [ital R][sub [ital H

1993-06-01

164

Application of mass spectrometry to fuels and materials testing at FFTF  

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) is a 400 MW(th) sodium cooled reactor and is the largest test reactor of its type in the world. It was designed and is being operated to serve two purposes: gaining liquid metal system experience and serving as a test bed for fuels and materials. During test operations it is possible that cladding breaches and escape of fission gas to the reactor cover gas region can occur. To identify the source of such a leak all 78 fuel pin assemblies contain ''gas tag'' with a unique ''tag'' mixture in each assembly. The mass spectrometric identification of tag isotope ratios makes possible rapid location and thus faster removal (if required) of breached test pins.

165

Analyses of eigenvalue bias and control rod worths in FFTF [Fast Flux Test Facility  

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) core loading during its ninth operating cycle was significantly different from that of previous cycles because of the presence of the Core Demonstration Experiment (CDE). The CDE consists of a number of axially blanketed fuel assemblies and internal blankets prototypic of advanced oxide cores in Liquid Metal Reactors (LMR). In preparation for the Cycle 9 reload design effort, a careful assessment of control rod worth and reactivity calculations for Cycles 1 through 8 was made. The goal of this study was to establish calculational biases and reduce uncertainties factored into the reload design calculations. These analyses helped assure that the operational objectives for Cycle 9 were met.

1987-09-13

166

Analyses of eigenvalue bias and control rod worths in FFTF (Fast Flux Test Facility)  

Energy Technology Data Exchange (ETDEWEB)

The Fast Flux Test Facility (FFTF) core loading during its ninth operating cycle was significantly different from that of previous cycles because of the presence of the Core Demonstration Experiment (CDE). The CDE consists of a number of axially blanketed fuel assemblies and internal blankets prototypic of advanced oxide cores in Liquid Metal Reactors (LMR). In preparation for the Cycle 9 reload design effort, a careful assessment of control rod worth and reactivity calculations for Cycles 1 through 8 was made. The goal of this study was to establish calculational biases and reduce uncertainties factored into the reload design calculations. These analyses helped assure that the operational objectives for Cycle 9 were met.

1987-01-01

167

Absorption studies for selection of low cost materials for management of low level radioactive liquid waste  

International Nuclear Information System (INIS)

Natural minerals and some industrial wastes are used as low cost sorbents for removal of metal ions from effluent streams. Apatite as natural mineral and red mud as an industrial waste have been tested for their sorption properties with respect to two important fission products "1"3"7Cs and "9"0Sr. Their ion exchanging capacity was tested after every 4 hours till 24 hours. The material gets saturated after 4-8 hours. Hence these materials can be considered for treating in treating LLW before discharge, industrial waste treatment and as backfill or admixture material for shallow land repository. (author)

2010-03-01

168

A method for producing a filtering material for organic substances  

Energy Technology Data Exchange (ETDEWEB)

A method is proposed for making a filtering material (FM) through applying bitumen or tar to a porous substance and subsequent roasting. Blast furnace slag, pumice and other inorganic substances are used as the porous substance. The method makes it possible to acquire an inexpensive filtering material with a developed surface (Pv), which replaces activated charcoal. Example. Blast furnace slag is heated to 200 to 300 degrees and with mixing is impregnated by 5 to 15 percent bitumen or tar. The impregnated slag is roasted at 800 to 1,000 degrees until full carbonization of the bitumen or tar, acquiring in this way a filtering material, which is characterized by a specific surface of 700 to 1,000 square centimeters per gram and suitable as a replacement for activated charcoal for removing organic components and heavy metals from gaseous and liquid phases. The cost of the filtering material is one eighth to one tenth of that of activated charcoal.

1981-06-27

169

High Throughput Screening for the Discovery of More Efficient Catalysts for Emissions Control  

Energy Technology Data Exchange (ETDEWEB)

High-throughput synthesis and screening methods have been developed for the discovery of highly active catalysts for the control of emissions from stationary and mobile sources. Low temperature CO oxidation, CO methanation, NOx abatement and the destruction of Volatile Organic Compounds (VOCs) will be discussed. The discovery libraries for primary screening consisted of both 11x11 and 16x16 catalyst arrays on 3 inch and 4 inch quartz wafers, respectively. Catalysts were prepared by robotic liquid dispensing techniques and screened for catalytic activity in Symyx's Scanning Mass Spectrometer. The screening protocols encompassed mixed metal oxides, perovskites and supported base and noble metals. Active hits were further optimized in focus libraries using shallower compositional gradients. The ScanMS is a fast serial screening tool that uses flat wafer catalyst surfaces, local laser heating, a scanning/sniffing ...

2004-03-31

170

Characterization of the surface film growth during the electrochemical process: Part 2 (90 % copper-10 % nickel system)  

Energy Technology Data Exchange (ETDEWEB)

In order to understand the resistance of passive films formed during corrosion processes, an analytical technique using x-ray diffraction was developed to examine the structure of metal in closest proximity to the metal/liquid interface. The in-situ structure at the metal liquid interface was examined for 90 % copper and 10 % nickel (90-10 Cu-Ni) in KOH solution at room temperature and at four different potentistatically controlled potentials ({minus}0.5 V, {minus}0.1 V, +0.5 V and +0.10 V versus Ni/NiO). The chemical changes at the metal interface were studied over a period of 48 hours. It was found that the integrity of the 90-10 Cu-Ni foil in KOH was lost after a continued application of the potential over 48 hours. The x-ray diffraction results indicated that the structure of both the inner and the outer passive layers, at {minus}0.5V and {minus}0.1 V (versus Ni/NiO), is ...

1998-06-01

171

Application of the Center for Air Toxic Metals (CATM) database  

Energy Technology Data Exchange (ETDEWEB)

A relational database capable of storing and manipulating the large volumes of data on air toxic metals has been developed for the Center for Air Toxic Metals at the Energy and Environmental Research Center (EERC) of the University of North Dakota. The database provides information to researchers, managers, and operations personnel to aid in their decision making and long-term planning of issues related to air toxic metals. A personal computer-based graphical user interface is used to access the data located on a UNIX workstation at the EERC. With security codes and software issued by the EERC and an Internet service provider in place, the database can be accessed externally through the Internet. Currently the database contains over 3000 analytical measurements from nine full-scale systems and several bench-scale operations. Data are available on gas, solid, and liquid stream samples as well as relevant ...

1996-12-31

172

Partial discharge in liquid nitrogen  

Science.gov (United States)

Results are presented of experiments on partial discharge in liquid nitrogen, including insulation breakdown characteristics of liquid nitrogen, partial discharge characteristics of composite insulation systems, lifetime of polymer films, impulse breakdown of polymer films in liquid nitrogen, etc. The partial discharge characteristics of liquid nitrogen are examined with increasing liquid-nitrogen pressure. It is concluded that a composite insulation structure of polymer film and liquid nitrogen can be used as effective electrical insulators at cryogenic temperatures.

1976-01-01

173

Cryogenic trick for enhanced cooling using liquid nitrogen  

International Nuclear Information System (INIS)

The thermal transpiration method has been employed to replace the temperature of liquid nitrogen by #approx#12 K. This is done by bubbling He (g) through the liquid nitrogen.

1993-01-01

174

Raman Under Nitrogen. The High-Resolution Raman Spectroscopy of Crystalline Uranocene, Thorocene, and Ferrocene  

Science.gov (United States)

The utility of recording Raman spectroscopy under liquid nitrogen, a technique we call Raman Under Nitrogen (RUN), is demonstrated for ferrocene, uranocene and thorocene. Using RUN, low temperature (liquid nitrogen cooled) Raman spectra for these compounds exhibit higher resolution than previous studies and new vibrational features are reported. The first Raman spectra of crystalline uranocene at 77 K are reported using excitation from argon (5145 ) and krypton (6764 ) ion lasers. The spectra obtained showed bands corresponding to vibrational transitions at 212, 236, 259, 379, 753, 897, 1500, and 3042 cm-1 , assigned to ring-metal-ring stretching, ring-metal tilting, out-of-plane CCC bending, in-plane CCC bending, ring-breathing, C-H bending, CC stretching and CH stretching, respectively. The assigned vibrational bands are compared to those of uranocene in THF and thorocene. All vibrational frequencies ...

2004-02-08

175

Raman Under Nitrogen. The High-Resolution Raman Spectroscopy of Crystalline Uranocene, Thorocene, and Ferrocene  

International Nuclear Information System (INIS)

The utility of recording Raman spectroscopy under liquid nitrogen, a technique we call Raman Under Nitrogen (RUN), is demonstrated for ferrocene, uranocene and thorocene. Using RUN, low temperature (liquid nitrogen cooled) Raman spectra for these compounds exhibit higher resolution than previous studies and new vibrational features are reported. The first Raman spectra of crystalline uranocene at 77 K are reported using excitation from argon (5145 ) and krypton (6764 ) ion lasers. The spectra obtained showed bands corresponding to vibrational transitions at 212, 236, 259, 379, 753, 897, 1500, and 3042 cm-1 , assigned to ring-metal-ring stretching, ring-metal tilting, out-of-plane CCC bending, in-plane CCC bending, ring-breathing, C-H bending, CC stretching and CH stretching, respectively. The assigned vibrational bands are compared to those of uranocene in THF and thorocene. All vibrational frequencies ...

2004-02-08

176

FFTF operational results: startup to 100 MWd/kg  

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) is a 400-MW(t) sodium-cooled fast reactor operating at the Hanford Engineering Development Laboratory in Richland, Washington, to conduct fuels and materials testing in support of the US liquid-metal fast breeder reactor program. Startup and initial power testing included a comprehensive series of nuclear and nonnuclear tests to verify the thermal and neutronic characteristics of the plant and to demonstrate its inherent safety features. Extensive reactor core characterization measurements were completed to provide the neutron and gamma spectra, fission rates, and other physics data needed to design and evaluate tests irradiated in the FFTF. A specially designed series of natural-circulation tests was performed to demonstrate the inherent safety features of the plant. Early in 1982 the FFTF began its first 100-d irradiation cycle. Since that time the plant has operated beyond expectations; it achieved a cycle capacity factor of ...

177

DEEP DESULFURIZATION OF DIESEL FUELS BY A NOVEL INTEGRATED APPROACH  

Energy Technology Data Exchange (ETDEWEB)

Due to the increasingly stricter regulations for deep reduction of fuel sulfur content, development of new deep desulfurization processes for liquid transport fuels has become one of the major challenges to the refining industry and to the production of hydrocarbon fuels for fuel cell applications. The sulfur compounds in the current transport fuels corresponding to the S level of 350-500 ppm account for only about 0.12-0.25 wt % of the fuel. The conventional hydrotreating approaches will need to increase catalyst bed volume at high-temperature and high-pressure conditions for treating 100 % of the whole fuel in order to convert the fuel mass of less than 0.25 wt %. In the present study, we are exploring a novel adsorption process for desulfurization at low temperatures, which can effectively reduce the sulfur content in gasoline, jet fuel and diesel fuel at low investment and operating cost to meet the needs for ultra-clean transportation fuels and for fuel cell ...

2001-09-01

178

Application of neutron radiography systems in JRR-3M to nuclear engineering  

Energy Technology Data Exchange (ETDEWEB)

Initial major applications of neutron radiography (NR) to nuclear engineering were nondestructive inspections of nuclear fuel, control rods, reactor materials and some other components. Increase in the available neutron flux over 10{sup 8} n/cm{sup 2}s at the JRR-3M thermal neutron radiography facility (TNRF) in 1991 has expanded the application field to the dynamic but clear imaging of moving objects and fluid phenomena. The JRR-3M TNRF is facilitated with three major imaging systems, being characterized by spatial and/or temporal resolutions: 1. Static neutron radiography (SNR), 2. real-time neutron radiography (RNR) with an imaging rate of 30 frames/s and 3. High-frame-rate neutron radiography (HFRNR). SNR has been used for three-dimensional visualization of air-water two-phase flows in a simulated rod bundle. Three-dimensional computed tomography clearly illustrated average void fraction distributions around tie spacers. RNR has been used for visualization and quantitative ...

1999-07-01

179

Diffusion and adsorption of methane confined in nanoporous carbon aerogel: a combined quasi-elastic and small-angle neutron scattering study  

Energy Technology Data Exchange (ETDEWEB)

The diffusion of methane confined in nano-porous carbon aerogel with the average pore size 48 {angstrom} and porosity 60% was investigated as a function of pressure at T = 298 K using quasi-elastic neutron scattering (QENS). The diffusivity of methane shows a clear effect of confinement: it is about two orders of magnitude lower than in bulk at the same thermodynamic conditions and is close to the diffusivity of liquid methane at 100 K (i.e. {approx} 90 K below the liquid-gas critical temperature T{sub C} {approx} 191 K). The diffusion coefficient (D) of methane initially increases with pressure by a factor of {approx}2.5 from 3.47 {+-} 0.41 x 10{sup -10} m{sup 2} s{sup -1} at 0.482 MPa to D = 8.55 {+-} 0.33 x 10{sup -10} m{sup 2} s{sup -1} at 2.75 MPa and starts to decrease at higher pressures. An explanation of the observed non-monotonic behavior of the diffusivity in the confined fluid is based on the results of small-angle neutron ...

2010-04-01

180

DOE indirect liquefaction program  

Science.gov (United States)

Processes for the hydrogenation of carbon monoxide have had commercial importance since about 1920, when the commercial production of methanol and higher alcohols on oxide catalysts began. Soon thereafter Fischer and Tropsch discovered that liquid hydrocarbons could be synthesized from carbon monoxide and hydrogen over Group VIII metal catalysts. Following extensive catalyst and process development efforts, this technology provided Germany with a source of liquid fuels during World War II. The period following the war saw an acceleration in research and development on the Fischer-Tropsch process, but the only commercial application that was to emerge was the SASOL process in the Union of South Africa. The oil crises of the 1970s have rekindled worldwide interest in indirect liquefaction technologies for the production of clean, high-quality motor fuels from coal. The development of more efficient coal gasification processes ...

1985-01-01

181

A pilot-scale jet bubbling reactor for wet flue gas desulfurization with pyrolusite.  

Science.gov (United States)

MnO2 in pyrolusite can react with SO2 in flue gas and obtain by-product MnSO4 x H2O. A pilot scale jet bubbling reactor was applied in this work. Different factors affecting both SO2 absorption efficiency and Mn2+ extraction rate have been investigated, these factors include temperature of inlet gas flue, ration of liquid/solid mass flow rate (L/S), pyrolusite grade, and SO2 concentration in the inlet flue gas. In the meantime, the procedure of purification of absorption liquid was also discussed. Experiment results indicated that the increase of temperature from 30 to 70 K caused the increase of SO2 absorption efficiency from 81.4% to 91.2%. And when SO2 concentration in the inlet flue gas increased from 500 to 3000 ppm, SO2 absorption efficiency and Mn2+ extraction rate decreased from 98.1% to 82.2% and from 82.8% to 61.7%, respectively. The content of MnO2 in pyrolusite had a neglectable effect on SO2 absorption efficiency. Low L/S was good ...

2005-01-01

186

STRUCTURE OF LIQUID NITROGEN,  

Science.gov (United States)

... Accession Number : AD0618975. Title : STRUCTURE OF LIQUID NITROGEN,. Corporate Author : CALIFORNIA INST OF TECH PASADENA. ...

1962-03-27

187

Operational Characteristics of a Liquid Nitrogen Powered ...  

Science.gov (United States)

... Accession Number : ADA350829. Title : Operational Characteristics of a Liquid Nitrogen Powered Automobile. Descriptive Note : Master's thesis. ...

1998-08-04

188

Nanostructured Materials from Impulse Plasma in Liquid  

International Science & Technology Center (ISTC)

Nanostructured Materials from Impulse Plasma in Liquid: Studying of Physical-Chemical Properties, Optimization of Conditions of Obtaining

189

MAGMA: A Liquid Software Approach to Fault Tolerance ...  

Science.gov (United States)

... MAGMA © : A LIQUID SOFTWARE APPROACH TO FAULT TOLERANCE, COMPUTER NETWORK SECURITY, AND SURVIVABLE NETWORKING ...

2001-12-01

190

Liquid hydrocarbon fuel composition  

Energy Technology Data Exchange (ETDEWEB)

A fuel composition comprising a liquid hydrocarbon fuel and a detergent amount of the product of reaction between a polyamine and a stearic acid is described.

1983-07-19

191

Freeze protection valve and system  

Energy Technology Data Exchange (ETDEWEB)

The present invention is a device for a solar heating system having a solar collector, a storage tank connected to the solar collector, a pump for circulating liquid from the tank to the solar collector, a supply of liquid at a temperature above freezing and a connection from the supply of liquid to the solar collector for replacing any liquid lost from said solar collector. The device comprises a sensor for sensing the temperature of liquid in the solar collector, and a valve for bleeding liquid from the solar collector when the sensed temperature falls below a predetermined minimum whereby cool liquid in the solar collector is automatically replaced by liquid at a temperature above freezing.

1985-12-10

192

Development of a stable cobalt-ruthenium Fischer-Tropsch catalyst. Technical progress report No. 12, July 1, 1992--September 30, 1992  

Energy Technology Data Exchange (ETDEWEB)

The fixed bed pilot plant, the catalyst testing procedure, and the calculations for conversion and selectivities were previously described in the technical progress report covering the period of 3/16/88 to 6/16/88 for Contract DE-AC22-87PC79812. Conversions and hydrocarbon selectivities were calculated using data from an on-line gas chromatography (GC) analyzer. Alcohol selectivities were calculated using data from an on-line boiling point GC analyzer which analyzed the liquid product. The catalysts were prepared via the steps of impregnation, calcination, and reduction on a special Y-zeolite-derived support. The impregnation step consisted of evaporation of metal salts on to the support from an aqueous solution. For one catalyst (No. 6531-188) the metal salts were evaporated on to the support from a reverse micelle solution containing the metal salts. All the catalysts were calcined for four hours at ...

1992-12-31

193

Degradation of materials under conditions of the sulfur-iodine thermochemical cycle  

Energy Technology Data Exchange (ETDEWEB)

The sulfur-iodine (SI) thermochemical cycle is one of the main candidate methods to produce hydrogen from non-fossil sources like nuclear (GEN IV reactor) or solar thermal power. A major issue for the successful implementation of the SI cycle is the selection of technically viable and economic materials for construction of process components, particularly heat exchangers. Challenging conditions are encountered in each of the three sections of the SI cycle due to the corrosive chemicals present, including sulfuric acid, iodine, hydroiodic acid, sulfur dioxide, hydrogen, oxygen, and others. In Section I, aqueous, non-aqueous (liquid iodine), and gaseous multi-component phases are present at about 120 {sup o}C and 0.7 MPa. Section II involves gaseous and aqueous phases of sulfuric acid, sulfur dioxide, and oxygen at up to about 830 {sup o}C and 3.6 MPa. In Section III , aqueous, non-aqueous, and gaseous phases, at up to 310 {sup o}C and 2.2 MPa, containing iodine, ...

2009-07-01

194

Nano-Materials in Metal-Matrix Composites  

International Science & Technology Center (ISTC)

Metal Matrix Composites on the Basis of Nano-Materials

196

The use of foam to improve liquid lifting from low-pressure gas wells  

Energy Technology Data Exchange (ETDEWEB)

Gas well load up is the loss of available reservoir energy due to the accumulation of liquids in the wellbore over time, and these liquids arise from liquids (hydrocarbons and water) condensed from the gas. Accumulation of these liquids near the wellbore can cause severe reduction to complete loss of available transport energy. A systematic experimental approach was undertaken to evaluate the performance of foam in removing liquids from the bottom of wells. The objectives of the research were: (1) to determine the efficiency of liquid lifting with foam; and (2) to compare the effects of surfactant type and concentration on liquid lifting. A flowloop successfully simulated the effects of completions with and without packer for low-pressure gas well with liquid production. In the base-case runs (air and water flow), the ...

1999-07-01

197

Electromagnetic structure of decuplet baryons towards the chiral regime  

Science.gov (United States)

The electromagnetic properties of the baryon decuplet are calculated in quenched QCD on a 20{sup 3}x40 lattice with a lattice spacing of 0.128 fm using the fat-link irrelevant clover fermion action with quark masses providing a pion mass as low as 300 MeV. Magnetic moments and charge radii are extracted from the electric and magnetic form factors for each individual quark sector. From these, the corresponding baryon properties are constructed. We present results for the higher-order moments of the spin-3/2 baryons, including the electric-quadrupole moment E2 and the magnetic-octupole moment M3. The world's first determination of a nonzero M3 form factor for the {delta} baryon is presented. With these results we provide a conclusive analysis which shows that decuplet baryons are deformed. We compare the decuplet-baryon results from a similar lattice calculation of the octet baryons. We establish that the environment sensitivity is far less pronounced for the decuplet baryons ...

2009-09-01

198

TRITEX. A ferritic steel loop with Pb-15.8Li. Facility and operation  

Energy Technology Data Exchange (ETDEWEB)

TRITEX was a pumped loop with Pb-15.8Li, fabricated from steel 1.4922. In contact with the molten eutectic were also molybdenum, vanadium and armco-iron. The loop was originally designed to investigate tritium extraction using solid getter metals. Over the years the goal changed to the study of metals, corrosion products and purification of the eutectic mixture. Therefore many modifications were done. The first part of this report describes TRITEX. All parts were enclosed in thermoboxes for a homogeneous temperature. One test section was in an argon glove box and could be opened during operation. Other special equipment`s were: permeation membranes and liquid-metal-covergas-interfaces to study the transport of H{sub 2}, D{sub 2} and {sup 3}H, different purification devices, a quartz observation window to see the liquid metal surface, 4 different kinds of flow measurements, level ...

1999-05-01

199

Laboratory Directed Research and Development (LDRD) on Mono-uranium Nitride Fuel Development for SSTAR and Space Applications  

Energy Technology Data Exchange (ETDEWEB)

The US National Energy Policy of 2001 advocated the development of advanced fuel and fuel cycle technologies that are cleaner, more efficient, less waste-intensive, and more proliferation resistant. The need for advanced fuel development is emphasized in on-going DOE-supported programs, e.g., Global Nuclear Energy Initiative (GNEI), Advanced Fuel Cycle Initiative (AFCI), and GEN-IV Technology Development. The Directorates of Energy & Environment (E&E) and Chemistry & Material Sciences (C&MS) at Lawrence Livermore National Laboratory (LLNL) are interested in advanced fuel research and manufacturing using its multi-disciplinary capability and facilities to support a design concept of a small, secure, transportable, and autonomous reactor (SSTAR). The E&E and C&MS Directorates co-sponsored this Laboratory Directed Research & Development (LDRD) Project on Mono-Uranium Nitride Fuel Development for SSTAR and Space Applications. In fact, three out ...

2006-02-09

200

Ultratrace determination in high-purity molybdenum and tungsten with ion chromatographic trace-matrix-separation. Pt. 1; Selection and optimization of the separation step. Ultraspurenanalytik in hochreinem Molybdaen und Wolfram mit ionenchromatographischer Spuren-Matrix-Trennung. Tl. 1; Auswahl und Optimierung des Trennschritts  

Energy Technology Data Exchange (ETDEWEB)

Known trace-matrix-separation and enrichment procedures for the refractory metals Mo and W use very time-consuming batch-techniques. This paper presents the application of a quasicontinuous liquid chromatographic (LC) technique as a step towards automated ultratrace separation. The anionic peroxo complexes from Mo(VI) and W(VI) are used for the trace-matrix-separation. Optimization of the peroxide concentration permits a complete removal of all cationic analyte traces on the HPLC-suitable cation exchanger Nucleosil SA. The high chromato-graphic efficiency also allows a direct ion chromatographic separation of the removed traces. This leads to conclusions about the contribution of the analyte traces on the trace-matrix-separation column and the limits of determination. (author). 13 refs.; 12 figs.; 5 tabs.

1991-11-20

201

Testing of the SpinTek Rotary Microfilter Using Actual Waste  

Energy Technology Data Exchange (ETDEWEB)

The Department of Energy selected caustic-side solvent extraction (CSSX) as the preferred cesium-removal technology for SRS high-level waste. In the pretreatment step of the CSSX flowsheet, the incoming salt solution, which contains entrained sludge, is contacted with MST to adsorb strontium and selected actinides. An alternative approach replaces MST with the addition of sodium permanganate, strontium nitrate, and hydrogen peroxide. The pretreatment operation then filters the resulting slurry to remove the sludge and MST or manganese oxide and strontium carbonate solids. The filtrate receives further treatment in the solvent extraction system. SRTC personnel coordinated tests using a SpinTek rotary microfilter at the vendor location in FY01. These tests demonstrated a significant improvement - 2.5 to 6 times increase - in performance relative to the conventional cross-flow filter units. Rotary microfilter testing used a filter disk with nominal pore size of either 0.1-micron or 0. ...

2004-02-13

202

Subsurface contaminants focus area  

Energy Technology Data Exchange (ETDEWEB)

The US Department of Enregy (DOE) Subsurface Contaminants Focus Area is developing technologies to address environmental problems associated with hazardous and radioactive contaminants in soil and groundwater that exist throughout the DOE complex, including radionuclides, heavy metals; and dense non-aqueous phase liquids (DNAPLs). More than 5,700 known DOE groundwater plumes have contaminated over 600 billion gallons of water and 200 million cubic meters of soil. Migration of these plumes threatens local and regional water sources, and in some cases has already adversely impacted off-site rsources. In addition, the Subsurface Contaminants Focus Area is responsible for supplying technologies for the remediation of numerous landfills at DOE facilities. These landfills are estimated to contain over 3 million cubic meters of radioactive and hazardous buried Technology developed within this specialty area will provide efective methods to contain ...

1996-08-01

203

Study on pyrolysing behavior of NiO-SDC composite particles prepared by spray pyrolysis technique  

Energy Technology Data Exchange (ETDEWEB)

The NiO-samaria doped ceria (SDC) composite powders were prepared by spray pyrolysis technique at temperatures between 400 and 1000 C. The variation of the particle structure was investigated by X-ray diffraction (XRD), X-ray absorption fine structure (XAFS), scanning electron microscope (SEM), and transmission electron microscope (TEM)-energy-dispersive X-ray spectroscopy (EDS). The thermal analysis of raw materials was also carried out. The following facts became clear in this study. Ceria and nickel have been already separated at 400 C. Samaria is amorphous phase below 600 C, and is dissolved in ceria at 600 C or higher. Samaria is distributed uniformly inside the particles before dissolving in ceria. The thermal decomposition temperatures of metal nitrate are: cerium < nickel < samarium. The results of these analyses were explained without contradiction. It was found that it is important to optimize the state of liquid drop ...

2007-03-15

204

State-in-the-art of applications of shock wave research and its future; Shogekiha no oyo gijutsu no genjo to shorai  

Energy Technology Data Exchange (ETDEWEB)

A shock wave appears when the release of accumulated energy is instantaneous. For instance, it accompanies gunpowder explosion, electric discharge, laser beam convergence, collision of high-speed objects, release of high-pressure gas, and supersonic flight. The shock wave research center of Institute of Fluid Science, Tohoku University, is engaged in researches to elucidate the basics of various shock wave phenomena and to apply the fruit to engineering, science, and medicine. In this report, some examples of recent application studies at the center are described, and the trend of shock wave researches in the future is introduced. The ultimate state of the stagnation point of a nozzle flow simulating a reentry into the atmosphere is produced by shock wave compression in a free piston shock tube which is a ground-borne experimental apparatus. Los Alamos National Laboratory, U.S., succeeded in generating metallic hydrogen of a crystalline structure by subjecting ...

1999-03-15

205

SEM and TEM investigations of recovery and recrystallization in technically pure molybdenum; REM- und TEM-Untersuchungen von Erholung und Rekristallisation in technisch reinem Molybdaen  

Energy Technology Data Exchange (ETDEWEB)

Beside traditional applications of refractory metals, e.g. in high temperature furnace construction, lighting or glass industry, one of the most important molybdenum products nowadays are large plates which are frequently used as targets for the sputtering of molybdenum layers in thin-film transistor liquid crystal displays. For the hot rolling of the sintered pre-material, the control over the recovery and recrystallization behavior is of particular importance. Molybdenum tends to a very recovery controlled behavior during hot deformation, at which the dislocations arrange into subcell boundaries instantaneously. These pronounced recovery processes seem to consume a large amount of the stored deformation energy for the actual recrystallization. On the other hand, recovery provides the future recrystallization nuclei. For a comprehensive characterization of these microstructural processes, electron microscopy appears to be the most proper ...

2011-07-15

206

Recent trends in heavy-fermion physics  

Energy Technology Data Exchange (ETDEWEB)

We discuss recent results obtained for the heavy-fermion metals UPd{sub 2}Al{sub 3} and YbRh{sub 2}Si{sub 2}. UPd{sub 2}Al{sub 3} is the first among all superconductors for which tunneling and inelastic neutron-scattering data highlight a non-phononic, i.e., magnetic-exciton mediated, pair state. YbRh{sub 2}Si{sub 2} represents a model system exhibiting pronounced non-Fermi liquid effects above a weak antiferromagnetic phase transition at T{sub N}=70 mK. Upon approaching the quantum critical point (T{sub N}{yields}0), by low doping with Ge, one observes for T<0.3 K disparate behavior in the temperature dependences of both the electrical resistivity and the electronic specific heat as well as a Curie-Weiss law in the uniform magnetic susceptibility, implying uncompensated large 4f moments. These observations indicate a break up of the composite quasiparticles into their local f-spin and itinerant conduction-electron parts.

2003-05-01

207

Recent developments in the design of conceptual fusion reactors  

International Nuclear Information System (INIS)

Since the first round of conceptual fusion reactor designs in 1973 - 1974, there has been considerable progress in design improvement. Two recent tokamak designs of the Wisconsin and Culham groups, with increased plasma beta and wall loading (power density), lead to more compact reactors with easier maintenance. The Reference Theta-Pinch Reactor has undergone considerable upgrading in the design of the first wall insulator and blanket. In addition, a conceptual homopolar energy storage and transfer system has been designed. In the case of the mirror reactor, there are design changes toward improved modular construction and ease of handling, as well as improved direct converters. Conceptual designs of toroidal-multiple-mirror, liner-compression, and reverse-field pinch reactors are also discussed. A design is presented of a toroidal multiple-mirror reactor that combines the advantages of steady-state operation and high-aspect ratio. The liner-compression reactor eliminates a major ...

208

Post-column reaction detector for platinum(II) antieoplastic agents  

Energy Technology Data Exchange (ETDEWEB)

The development and evaluation of a post-column reaction detector sensitive to platinum(II) complexes is presented in which sodium bisulfite is used as the derivatizing agent with potassium dichromate as an activating agent. The influences of mobile phase changes (i.e., pH, organic modifiers, electrolytes), oxygen, metal ions, and order of reagent addition on reaction kinetics and product yield are defined and used in optimization of detector response. Detection at lambda/sub max/ 290 nm results in an on-line post-column sensitivity of 40-60 ng/mL for selected cis-dichloroplatinum complexes and a sensitivity of 300-1200 ng/mL for four (substituted)-malonato-platinum complexes. The reaction detector is used to monitor the kinetics of aquation of cisplatin (CDDP) and to quantitate CDDP degradation in plasma. As the sensitivity for CDDP in plasma is comparable to that achieved from high pressure liquid chromatography (HPLC) effluent ...

1984-03-01

209

Irradiation-induced electrical conductivity of AlN and Al{sub 2}O{sub 3} at 450 C  

Energy Technology Data Exchange (ETDEWEB)

The electrical conductivity of Vitox-alumina (99.2%), Wesgo-alumina (99.9%) and AlN (99.6%) has been measured during and after irradiation with an experimental set-up which allows fusion relevant loading conditions. All irradiations were performed in high vacuum at 450 C using a 104 MeV {alpha}-particle beam with an applied DC electric field of 100 kV/m. In the high purity Vitox-alumina the in-situ and postirradiation bulk conductivities {sigma} and {sigma}{sub 0} show the highest irradiation induced electrical breakdown ever observed. The saturation level near 4 x 10{sup -2} ({Omega}m){sup -1}, reached already after 0.015 dpa (O-sublattice), is already above the critical value necessary to avoid MHD pressure drop with 10 {mu}m coatings in flowing liquid metal coolants. Under the same conditions no radiation induced electrical degradation at all has been found in Wesgo-alumina and AlN. (orig.).

1995-12-31

210

Heat transfer and hydraulics of liquid metal-gas two-phase magnetohydrodynamic flow  

International Nuclear Information System (INIS)

Local properties and heat transfer have been investigated in a NaK-nitrogen two-phase flow in a vertical tube under transverse magnetic field. An objective two-phase flow regime identification was also carried out systematically, using the probability distribution function of two-phase electromagnetic flowmeter signals. The application of a magnetic field was bound to bring about a drastic change in the void fraction profile, i.e., asymmetric profile perpendicular to the field direction. This effect was more remarkably observed in bubbly flows. The magnetic field was also observed to decrease the number of bubbles, by promoting the agglomeration of small bubbles into larger ones and also break-up of large slugs, and, thus, to shift the flow regime boundaries. It has been also shown that the two-phase Nusselt number increases in bubbly flows, while it decreases in slug flows. This trend however reduces in the presence of a magnetic field.

1986-08-01

211

GaAs Blocked-Impurity-Band Detectors for Far-Infrared Astronomy  

Energy Technology Data Exchange (ETDEWEB)

High-purity and doped GaAs films have been grown by Liquid-phase epitaxy (LPE) for development of a blocked impurity band (BIB) detector for far-infrared radiation. The film growth process developed has resulted in the capability to grow GaAs with a net active impurity concentration below 1 x 10{sup 13} cm{sup -3}, ideal for the blocking layer of the BIB detector. The growth of n-type LPE GaAs films with donor concentrations below the metal-insulator transition, as required for the absorbing layer of a BIB detector, has been achieved. The control of the donor concentration, however, was found to be insufficient for detector production. The growth by LPE of a high-purity film onto a commercially grown vapor-phase epitaxial (VPE) n-type GaAs doped absorbing layer resulted in a BIB device that showed a significant reduction in the low-temperature dark current compared to the absorbing layer only. Extended optical response was not detected, most ...

2004-12-21

212

Fuels and materials testing capabilities in Fast Flux Test Facility  

Energy Technology Data Exchange (ETDEWEB)

The Fast Flux Test Facility (FFTF) reactor, which started operating in 1982, is a 400 MWt sodium-cooled fast neutron reactor located in Hanford, Washington State, and operated by Westinghouse Hanford Co. under contract with U.S. Department of Energy. The reactor has a wide variety of functions for irradiation tests and special tests, and its major purpose is the irradiation of fuel and material for liquid metal reactor, nuclear reactor and space reactor projects. The review first describes major technical specifications and current conditions of the FFTF reactor. Then the plan for irradiation testing is outlined focusing on general features, fuel pin/assembly irradiation tests, and absorber irradiation tests. Assemblies for special tests include the material open test assembly (MOTA), fuel open test assembly (FOTA), closed loop in-reactor assembly (CLIRA), and other special fuel assemblies. An interim examination and maintenance cell (FFTF/IEM ...

1989-07-01

213

Fuels and materials testing capabilities in Fast Flux Test Facility  

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) reactor, which started operating in 1982, is a 400 MWt sodium-cooled fast neutron reactor located in Hanford, Washington State, and operated by Westinghouse Hanford Co. under contract with U.S. Department of Energy. The reactor has a wide variety of functions for irradiation tests and special tests, and its major purpose is the irradiation of fuel and material for liquid metal reactor, nuclear reactor and space reactor projects. The review first describes major technical specifications and current conditions of the FFTF reactor. Then the plan for irradiation testing is outlined focusing on general features, fuel pin/assembly irradiation tests, and absorber irradiation tests. Assemblies for special tests include the material open test assembly (MOTA), fuel open test assembly (FOTA), closed loop in-reactor assembly (CLIRA), and other special fuel assemblies. An interim examination and maintenance cell (FFTF/IEM ...

214

Focused ion beam processes for high-T/sub c/ superconductors  

International Nuclear Information System (INIS)

Focused ion beam (FIB) processes have been developed for Y--Ba--Cu--O superconductor films. A Y--Cu liquid metal ion source has been fabricated, using a Y_6_7 --Cu_3_3 eutectic alloy as the ion source. As-sputtered Y--Ba--Cu--O film etch rate ratios to GaAs(100) and Si(100) substrates are 0.28 and 1.4 for 130-keV Au"+ FIB ion etching, respectively. Y--Ba--Cu--O submicron patterns have been demonstrated by using FIB lithography and Cl_2 reactive ion beam etching. Moreover, a Y--Ba--Cu--O superconducting line with 4-#mu#m linewidth has been fabricated by annealing an as-sputtered Y--Ba--Cu--O line pattern. T/sub c/ control of Y--Ba--Cu--O film has been achieved by 200-keV Ne"+, using conventional ion implantation and 300 keV Si"+"+ FIB ion implantation.

215

FFTF operations: initial operator training simulator program  

International Nuclear Information System (INIS)

This paper describes the Fast Flux Test Facility (FFTF) Operations initial training program utilizing the Operator Training Simulator (OTS). The OTS is a computer-driven system that provides real time response of essential FFTF plant functions to a control room mockup. The FFTF, a 400 Megawatt, three-loop, sodium-cooled fast test reactor will test fuels, materials and equipment for the U.S. Liquid Metal Fast Breeder Reactor Program. Construction is expected to be completed in August 1978. Initial criticality is expected in early 1979. This schedule will require FFTF control room operators to be fully qualified to operate the facility by late 1979. Because FFTF is like no other U.S. nuclear reactor, existing U.S. utility plants could not be depended on to provide highly experienced people to operate FFTF. Therefore, an Operator Training Simulator has been built. The OTS will play a vital role in the formal operator qualification program.

216

FFTF fission gas monitor computer system  

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) is a liquid-metal-cooled test reactor located on the Hanford site. A dual computer system has been developed to monitor the reactor cover gas to detect and characterize any fuel or test pin fission gas releases. The system acquires gamma spectra data, identifies isotopes, calculates specific isotope and overall cover gas activity, presents control room alarms and displays, and records and prints data and analysis reports. The fission gas monitor system makes extensive use of commercially available hardware and software, providing a reliable and easily maintained system. The design provides extensive automation of previous manual operations, reducing the need for operator training and minimizing the potential for operator error. The dual nature of the system allows one monitor to be taken out of service for periodic tests or maintenance without interrupting the overall system functions. A built-in calibrated gamma source can be ...

217

FFTF [Fast Flux Test Facility] fuel handling experience (1979--1986)  

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF)is a 400 MW (th) sodium-cooled fast flux test reactor located on the Hanford Site in southeastern Washington State. The FFTF is operated by the Westinghouse Hanford Company for the United States Department of Energy. The FFTF is a three loop plant designed primarily for the purpose of testing full-scale core components in an environment prototypic of future liquid metal reactors. The plant design emphasizes features to enhance this test capability, especially in the area of the core, reactor vessel, and refueling system. Eight special test positions are provided in the vessel head to permit contact instrumented experiments to be installed and irradiated. These test positions effectively divide the core into three sectors. Each sector requires its own In-Vessel Handling Machine (IVHM) to access all the core positions. Since the core and the in-vessel refueling components are submerged under sodium, all handling ...

1987-09-01

218

FFTF [Fast Flux Test Facility] cesium trap design, installation, and operating experience  

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) is a 400-MWt, sodium-cooled reactor located on the Hanford Site near Richland, Washington, USA. The FFTF is owned by the U.S. Department of Energy and is operated by the Westinghouse Hanford Company. The FFTF was designed to test fuels and materials for use in liquid metal reactors. Since initial operation in 1982, anticipated breaches of experimental fuel pins have released fission products, including cesium, into the primary sodium. Because of its high volatility, cesium vaporizes into the cover gas space, where it condenses on components and equipment and is transported into the cover gas outlet. Because of the long half-life of "1"3"7Cs, these deposits result in long-term, local radiation levels that make contact maintenance difficult. Thus, a cesium trap was installed in FFTF to reduce the cesium level in the sodium. The trap could also permit a Run Beyond Cladding Breach (RBCB) program without ...

1988-10-17

219

FFTF [Fast Flux Test Facility] Integrated Leak Rate Test Computer System  

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) is a liquid-metal-cooled test reactor located on the Hanford Site. The FFTF is the only reactor of this type designed and operated with the intent of meeting the licensing requirements of the Nuclear Regulatory Commission (NRC). Unique characteristics of the FFTF that present special challenges related to leak rate testing include thin wall containment vessel construction, cover gas systems that penetrate containment, and a low-pressure design basis accident. The successful completion in 1986 of the third FFTF Integrated Leak Rate Test (ILRT) five days ahead of schedule and 10% under budget was a major achievement for the Westinghouse Hanford Company. The success of this operational safety test was due in large part to a special local area network (LAN) of three IBM PC/XT computers that monitored the sensor data, calculated the containment vessel leak rate, and displayed test results. The multiple computer configuration allowed ...

220

Environmental impacts of nuclear and coal-fired power plants  

International Nuclear Information System (INIS)

The current situation in the development of nuclear power in the world and in Czechoslovakia is briefly outlined and the possibilities are discussed of alternative energy resources. The environmental impact is described of conventional power plants firing coal; sulphur and nitrogen oxides are mentioned and their environmental impacts shown. Their quantities and the quantities of other gaseous, liquid and soid wastes produced by coal power plants are given. Annual estimates are presented of radioactive material emissions; trace amount emissions of toxic metals and their ecological risks are shown. Concern over the increasing concentration of CO_2 in the atmosphere is voiced. For nuclear power plants, the amount of radionuclides in stack emission and of those released into water flows is tabulated. Their effect on the aqueous ecosystem is characterized as is thermal pollution of water flows and the environmental impact of cooling towers. Other ...

1984-01-01

221

Electrospun porous SnO{sub 2} nanotubes as high capacity anode materials for lithium ion batteries  

Energy Technology Data Exchange (ETDEWEB)

Porous SnO{sub 2} nanotubes were prepared via electrospinning followed by calcination in air. As anode materials for lithium ion batteries, the porous nanotubes delivered a high discharge capacity of 807 mAh g{sup -1} after 50 cycles. Even after cycled at high rates, the electrode still retained a high fraction of its theoretical capacity. Such excellent performances of porous SnO{sub 2} nanotubes could be attributed to the porous and hollow structure which facilitated liquid electrolyte diffusion into the bulk materials and buffered large volume changes during lithium ions insertion/extraction. Furthermore, the nanoparticles of nanotubes provided the shorter diffusion length for lithium ions insertion which benefited in retaining the structural stability and good rate performance. Our results demonstrated that this simple method could be extended for the synthesis of porous metal oxide nanotubes with high performances in the applications of ...

2010-10-15

222

Development of a new technology for preparing samples for transmission electron microscopy (TEM) on the basis of ion fine beam processing; Entwicklung einer neuen Technologie zur Probenpraeparation fuer die Transmissions-Elektronenmikroskopie (TEM) auf der Basis der Ionenfeinstrahlbearbeitung  

Energy Technology Data Exchange (ETDEWEB)

The goal of this project was to develop a new technology for preparing samples for transmission electron microscopy (TEM) on the basis of ion fine beam processing. For this purpose processes of ion-beam-assisted removal (sputtering), separation, sample handling and ion-beam-assisted chemical etching as well of system-inherent components were examined. As an alternative to a Ga-source a liquid-metal ion source based on a AuGeSi alloy was developed, characterised and used in the FIB 4400. [German] Aufgabe des Projektes war die Entwicklung einer neuen Technologie zur Probenpraeparation fuer die Transmissions-Elektronenmikroskopie (TEM) auf der Basis der Ionenfeinstrahlbearbeitung. Dazu wurden Prozesse der ionenstrahlgestuetzten Abtragung (Sputtern), der Abscheidung, des Probenhandling, des ionenstrahlgestuetzten chemischen Aetzens sowie systemeigener Komponenten untersucht. Als Alternative zur Ga-Quelle wurde eine Fluessigmetall-Ionenquelle auf der Basis einer AuGeSi ...

2001-08-01

223

Development and Application of Subchannel Analysis Code Technology for Advanced Reactor Systems  

Energy Technology Data Exchange (ETDEWEB)

A study has been performed for the development and assessment of a subchannel analysis code which is purposed to be used for the analysis of advanced reactor conditions with various configurations of reactor core and several kinds of reactor coolant fluids. The subchannel analysis code was developed on the basis of MATRA code which is being developed at KAERI. A GUI (Graphic User Interface) system was adopted in order to reduce input error and to enhance user convenience. The subchannel code was complemented in the property calculation modules by including various fluids such as heavy liquid metal, gas, refrigerant,and supercritical water. The subchannel code was applied to calculate the local thermal hydraulic conditions inside the non-square test bundles which was employed for the analysis of CHF. The applicability of the subchannel code was evaluated for a high temperature gas cooled reactor condition and supercritical pressure conditions ...

2006-01-15

224

Construction of a open-quotes black neutron detectorclose quotes at the University of Massachusetts-Lowell Accelerator Laboratory  

International Nuclear Information System (INIS)

In many experiments involving fast neutrons generated in nuclear reactions initiated by accelerator produced charged particle beams, it is important to be able to determine accurately the neutron yield from the target. A detector suitable for such applications should have: a constant efficiency over a large energy range; a fast time response; and the ability to discriminate between gamma rays and neutrons. The authors have constructed a open-quotes black neutron detectorclose quotes based on the design of Poenitz that has these characteristics. At the Lowell Van de Graaff accelerator laboratory neutrons are produced via the "7Li(p,n)"7Be reaction using a pulsed proton beam which impinges on metallic lithium targets. The pulsed beam enables the detector to be used in a time-of-flight spectrometer. Use of BC501 liquid scintillator permits neutron-gamma discrimination. The scintillator is viewed by five RCA 48796 photo tubes. The detector is ...

1992-03-16

225

Conceptual design of a medium scale lead-bismuth cooled fast reactor  

International Nuclear Information System (INIS)

To seek for a promising concept of a heavy liquid metal coolant (HLMC) fast reactor plant, Japan Nuclear Cycle Development Institute and the electric utilities conducted conceptual design study on various types of plant concepts and compared these concepts based on technical feasibility and economical perspective. A comparative design study is performed on Lead-Bismuth cooled reactors with forced and natural convection cooling. Eliminating an intermediate cooling system makes the heat transport system simple and can decrease the amount of the weight of NSSS. Based on the estimation of the amount materials, the plant internal load etc., a construction cost of these plants are evaluated approximately 2/3 times of that of LWRs at present. And, the nitride fuel makes breeding ratio of 1.2 with 150 GWd/t of burnup. The results of unprotected event analyses such as UTOP and ULOF show that both of concepts have possible features to withstand ...

2003-09-15

226

Comparison of the SASSYS/SAS4A radial core expansion reactivity feedback model and the empirical correlation for the FFTF  

International Nuclear Information System (INIS)

The present emphasis on inherent safety for liquid-metal reactor designs has resulted in a need to represent the various reactivity feedback mechanisms as accurately as possible. The dominant negative reactivity feedback has been found to result from radial expansion of the core for most postulated anticipated transient without scram events. For this reasons, a more detailed model for calculating the reactivity feedback from radial core expansion, including subassembly bowing has been recently developed for use with the SASSYS/SAS4A code system. The purpose of this summary is to present an extension to the model so that it is more suitable for handling a core restraint design as used in the Fast Flux Test Facility (FFTF), and to compare the SASSYS/SAS4A results using this model to the empirical correlation presently being used to account for radial core expansion reactivity feedback in the FFTF.

1987-11-15

227

CoSi_2 nanostructures by writing FIB ion beam synthesis  

International Nuclear Information System (INIS)

A mass separated focused ion beam (FIB) is a very useful tool to fabricate nanostructures by writing implantation within an ion beam synthesis process. In these investigations the IMSA-OrsayPhysics FIB, equipped with a Co_3_6Nd_6_4 alloy liquid metal ion source, was applied. Si(100) and (111) wafers were implanted with 60 keV Co"+"+ ions in the dose range of 2 . 10"1"6 to 2 . 10"1"7 cm"-"2. Implantation parameters were investigated, like pixel dwell time, relaxation time (time between two cycles), dose rate as well as the pixel overlapping factor. The subsequent annealing was done in a two step process, namely 600 deg. C for 60 min and 1000 deg. C for 30 min in a N_2 ambient. The results obtained by SEM investigations in terms of continuous nanowire structures following the direction and interrupted CoSi_2 pattern in the direction show a clear dependence on the time scale as well as the scanning mode of the irradiation. Structure sizes as ...

2006-07-01

228

CFD code fluent turbulence models application. Ansaldo's prototype modeling  

International Nuclear Information System (INIS)

Among others, one of the main activities in the Nuclear Engineering and Fluid Mechanics Department of the Engineering School in Bilbao, is the study of liquid metals behavior. And for this purpose the CFD code FLUENT is being used. Currently, the code is being applied to the use of Lead-Bismuth eutectic (LBE) as the coolant of an accelerator driven system (ADS) and also as the target for a neutron source. In this paper, ANSALDO's Energy Amplifier Demonstration Facility is simulated, paying attention only on the coolant. As it will be later explained, natural convection is a very important issue, because the philosophy for safety systems in nuclear devices tends to consider passive technologies. The purpose is to avoid electrical machines like pumps, so the core should remain coolable, even if there is a blackout. To get this natural circulation, heat transfer plays a main role, and as turbulence enhances the heat transfer, it is important to ...

2001-12-04

229

Breached fuel location in FFTF by delayed neutron monitor triangulation  

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) features a three-loop, sodium-cooled 400 MWt mixed oxide fueled reactor designed for the irradiation testing of fuels and materials for use in liquid metal cooled fast reactors. To establish the ultimate capability of a particular fuel design and thereby generate information that will lead to improvements, many of the fuel irradiations are continued until a loss of cladding integrity (failure) occurs. When the cladding fails, fission gas escapes from the fuel pin and enters the reactor cover gas system. If the cladding failure permits the primary sodium to come in contact with the fuel, recoil fission products can enter the sodium. The presence of recoil fission products in the sodium can be detected by monitoring for the presence of delayed neutrons in the coolant. It is the present philosophy to not operate FFTF when a failure has occurred that permits fission fragments to enter the sodium. Thus, it is ...

1985-11-10

230

A design study of reactor core optimization for direct nuclear heat-to-electricity conversion in a space power reactor  

Energy Technology Data Exchange (ETDEWEB)

To propose a new design concept of a nuclear reactor used in the space, research has been conducted on the conceptual design of a new nuclear reactor on the basis of the following three main concepts: (1) Thermionic generation by thermionic fuel elements (TFE), (2) reactivity control by rotary reflector, and (3) reactor cooling by liquid metal. The outcomes of the research are: (1) A calculation algorithm was derived for obtaining convergent conditions by repeating nuclear characteristic calculation and thermal flow characteristic calculation for the space nuclear reactor. (2) Use of this algorithm and the parametric study established that a space nuclear reactor using 97% enriched uranium nitride as the fuel and lithium as the coolant and having a core with a radius of about 25 cm, a height of about 50 cm and a generation efficiency of about 7% can probably be operated continuously for at least more than ten years at 100 kW only by reactivity ...

1998-01-01

231

Quantification of order in the liquid at a solid-liquid interface by High-Resolution Transmission Electron Microscopy (HRTEM)  

Energy Technology Data Exchange (ETDEWEB)

A number of different theoretical approaches have been used to model to atomic structure and properties of solid-liquid interfaces. Most calculations indicate that ordering occurs in the first several layers of the liquid, adjacent to the crystal surface. In contrast to the numerous theoretical investigations, there have been no direct experimental observations of the atomic structure of a solid-liquid interface for comparison. Saka et al. examined solid-liquid interfaces in In and In-Sb at lattice-fringe resolution in the TEM, but their data do not reveal information about the atomic structure of the liquid phase. The purpose of this study is to determine the atomic structure of a solid-liquid interface using a highly viscous supercooled liquid, i.e., a crystal-amorphous interface.

1996-12-31

232

Preparation of AgX (X = Cl, I) nanoparticles using ionic liquids  

Energy Technology Data Exchange (ETDEWEB)

Nanoparticles of silver halides have been prepared by mixing silver halide powder with a single liquid phase consisting of an ionic liquid, isooctane, n-decanol and water. Much higher nanoparticle concentrations may be formed with ionic liquids using this new simple method than are found with conventionally applied surfactants. This method also emphasizes the applicability of ionic liquids as versatile components in microemulsions and as solvents for the synthesis of nanomaterials. The effect on the nanoparticles of changing the composition of the liquid mixtures and the nature of the ionic liquid is analysed. High nanoparticle concentrations were only found with chloride based ionic liquids, indicating the importance of the ionic liquid anion in the mechanism of the reaction.

2008-03-12

233

Ultra-fast charge transfer in organic electronic materials and at hybrid interfaces studied using the core-hole clock technique  

Energy Technology Data Exchange (ETDEWEB)

Research highlights: {yields} The use of resonant photoemission in its 'core-hole clock' expression for the study of the dynamical charge transfer across hybrid organic-inorganic interfaces and for the intermolecular charge transfer in the bulk of organic thin films is reviewed. {yields} The electronic coupling to the substrate and the efficiency of charge transport across hybrid interfaces is different for individual electronic subsystems of the molecular adsorbate. {yields} The intermolecular charge transfer in the bulk of discotic liquid crystals occurs on the order of a few femtoseconds and is faster than expected from the macroscopic charge transport characteristics of the material. -- Abstract: The focus of this brief review is the use of resonant photoemission in its 'core-hole clock' expression for the study of two important problems relevant for the field of organic electronics: the dynamical charge transfer across ...

2011-01-15

234

Performance and capacity fade of V{sub 2}O{sub 5}-lithium polymer batteries at a moderate-low temperature  

Energy Technology Data Exchange (ETDEWEB)

Lithium metal-polymer electrolyte batteries with improved utilisation of the active material at a moderate-low temperature (65degC) were realised. Low molecular weight poly(ethylene glycol) (PEG, MW=2000) was used as the lithium-ion conductive matrix in the composite cathode. The cathode active material was crystalline V{sub 2}O{sub 5}. A blend of poly(ethylene oxide) (PEO, MW=4x10{sup 6}) and PEG was used as a solid polymer electrolyte (SPE). The transport properties of the SPE were evaluated at various temperatures. A specific conductivity as high as 1.0x10{sup -4} S cm{sup -1} was calculated at 45degC. The temperature dependence of the interfacial resistances between lithium/SPE and cathode material/PEG was evaluated. The lithium/SPE interfacial resistance decreases linearly with the temperature. The charge transfer resistance between cathode material and PEG reaches a minimum at 60degC and it does not decrease with a further temperature increase. The data ...

2001-07-01

235

International Clean Energy System Using Hydrogen Conversion (WE-NET). subtask 5. Development of hydrogen transport/storage technology (development of tanker for liquid hydrogen); Suiso riyo kokusai clean energy system gijutsu (WE-NET). subtask 5. Suiso yuso chozo gijutsu no kaihatsu (ekitai suiso yuso tanker no kaihatsu)  

Energy Technology Data Exchange (ETDEWEB)

As a part of the WE-NET project, the tanker for liquid hydrogen transport was studied. In fiscal 1996, some experiments and numerical analyses were proposed which are necessary to solve technological issues extracted in fiscal 1995 for heat insulation structure. The issue was roughly classified into vacuum and non-vacuum insulation, and their basic functions and required performance were arranged. Boil-off rate of 0.2-0.4%/d was targeted. The insulation system which applies polyurethane form (PUF) to tank surfaces and injects atmospheric N2 gas into the surrounding hold space, could achieve the targeted insulation performance by PUF of 1m in thickness. The system of vacuum panel insulation and atmospheric N2 gas injection into a hold space required the panel of 500mm in thickness because of the large effect of metallic outer panel material. The system of vacuum hold and PUF panels was faced with the essential issue for realizing and maintaining ...

1997-03-01

236

Differential rod worth profile affected by axial blankets in FFTF [Fast Flux Test Facility  

International Nuclear Information System (INIS)

The central feature of the Fast Flux Test Facility (FFTF) is the fast test reactor (FTR), which is a liquid-sodium-cooled fast reactor providing high fast-neutron flux for irradiation testing of fuels and materials. The FTR also provides a means to develop breeder reactor core components and to gain reactor systems operating experience for future liquid-metal fast breeder reactors (LMFBRs). In the FTR core, there are 82 incore positions (within rows 1 through 6) available for driver fuel assemblies and/or test assemblies. In addition, there are three safety rods and six control rods located in rows 3 and 5, respectively, in the three symmetric core sectors. The FFTF has been successfully and continuously operated for more than 11 reactor cycles. For the first 8 cycles, the core loadings were composed of the mixed-oxide driver fuel assemblies and some test assemblies. These assemblies have an active core section of 91.5 cm with 15.2-cm upper and ...

1990-06-10

237

Andreev reflection and order parameter symmetry in heavy-fermion superconductors: the case of CeCoIn5  

International Nuclear Information System (INIS)

We review the current status of Andreev reflection spectroscopy on the heavy fermions, mostly focusing on the case of CeCoIn5, a heavy-fermion superconductor with a critical temperature of 2.3 K. This is a well-established technique to investigate superconducting order parameters via measurements of the differential conductance from nanoscale metallic junctions. Andreev reflection is clearly observed in CeCoIn5 as in other heavy-fermion superconductors. Considering the large mismatch in Fermi velocities, this observation seemingly appears to disagree with the Blonder-Tinkham-Klapwijk (BTK) theory. The measured Andreev signal is highly reduced to the order of maximum ?13% compared to the theoretically predicted value (100%). The background conductance exhibits a systematic evolution in its asymmetry over a wide temperature range from above the heavy-fermion coherence temperature down to well below the superconducting transition temperature. Analysis of the ...

2009-03-11

238

[The indicators of biological age and accelerated aging in liquidators of the consequences of radiation emergency].  

Science.gov (United States)

The biological age (BA) of the majority of the liquidators of the consequences of the radiation accidents in the Navy and of the liquidators of the Chernobyl' APS accident exceeds the medium standard and the DBA (due BA). The index of the BA can be a characteristic of the influence of the social-hygienic factors on the health condition of the Special Risk Subunit--the liquidators of the consequences of the radiation accidents. It was established, that the radiation influence concerns to the factors dramatically increasing the BA and the rate of senescence of the liquidators of the consequences of the radiation accidents. PMID:21809627

2011-01-01

239

Physical Properties of Liquid Crystals  

CERN Document Server

This handbook is a unique compendium of knowledge on all aspects of the physics of liquid crystals. In over 500 pages it provides detailed information on the physical properties of liquid crystals as well as the recent theories and results on phase transitions, defects and textures of different types of liquid crystals. An in-depth understanding of the physical fundamentals is a prerequisite for everyone working in the field of liquid crystal research. With this book the experts as well as graduate students entering the field get all the information they need.

1999-01-01

240

Theoretical and practical considerations on the problem of metal--metal interaction.  

UK PubMed Central (United Kingdom)

The interaction between two metals, which can be either synergistic or antagonistic, implies that the behavior of one is changed by the presence of the other. Possible mechanisms of these interactions,...Full Text Available

1978-08-01

241

Metal phthalocyanine catalysts  

Energy Technology Data Exchange (ETDEWEB)

As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

1994-01-01

242

Theoretical study on device efficiency of pulsed liquid jet pump  

International Nuclear Information System (INIS)

The influence of the main factors on device efficiency of pulsed liquid jet pump with gas-liquid piston is analysed, the theoretical equation and its time-averaged solution of pulsed liquid jet pump device efficiency are derived. The theoretical and experimental results show that the efficiency of transmission of energy and mass to use pulsed jet is greatly raised, compared with steady jet, in the same device of liquid jet pump. The calculating results of time-averaged efficiency of pulsed liquid jet pump are approximately in agreement with the experimental results in our and foreign countries

2001-03-01

243

Solubility and rate of dissolution for Miscanthus in hydrophilic ionic liquids  

British Library Electronic Table of Contents (United Kingdom)

Miscanthus is a potential feedstock for the production of biofuels. Lignocellulosic biomass is not soluble in conventional solvents, but Miscanthus and other lignocellulosic biomass have reasonable solubilities in some ionic liquids. The solubility of Miscanthus in a variety of hydrophilic ionic liquids was measured as a function of particle size, temperature and time for dissolution. In addition to temperature and time, the ionic liquid anion has a significant effect on solubility and rate of dissolution. The moisture content of Miscanthus lowers its solubility in certain ionic liquids. Chloride, acetate, and phosphate-based ionic liquids favor solubility. A tentative correlation for the solubility of Miscanthus is proposed in terms of Abraham solvation parameters obtained from quantum-ch...

2011-01-01

244

Global Molecular Characterization of the Chromate Stress Response in Shewanella oneidensis MR-1: Identification of a Putative DNA-Binding Response Regulator and Azoreductase Involved in Cr(VI) Detoxification  

Energy Technology Data Exchange (ETDEWEB)

Shewanella oneidensis MR-1 is a model environmental organism that possesses diverse respiratory capacities, including the ability to reduce soluble Cr(VI) to sparingly soluble, less toxic Cr(III). Effective bioremediation of Cr-contaminated sites requires knowledge of the molecular mechanisms and regulation of heavy metal resistance and biotransformation by dissimilatory metal-reducing bacteria. Towards this goal, our ERSP-funded work is focused on the identification and functional analysis of genes/proteins comprising the response pathways for chromate detoxification and/or reduction. Previous transcriptomic profiling and whole-cell proteomic analyses implicated the involvement of a functionally undefined DNA-binding response regulator (SO2426) and a putative azoreductase (SO3585) in the chromate stress response of MR-1. Here we describe a detailed functional analysis of SO2426 and SO3585 in order to begin to understand the role of these ...

2006-04-05

245

Wear Rate and Friction Coefficient in Liquid Nitrogen and ...  

Science.gov (United States)

... Title : Wear Rate and Friction Coefficient in Liquid Nitrogen and Hydrogen of Steel Sliding on Polymer Laminates (Various Fabrics and Polymers. ...

1968-04-01

246

Quantitation of Antibiotics by High-Pressure Liquid Chromatography: Cephalothin  

UK PubMed Central (United Kingdom)

A technique for quantitative determination of cephalothin and desacetylcephalothin in serum using a method based on high-pressure liquid chromatography is described. Both compounds were quantitatively...Full Text Available

1978-02-01

247

NASA - NASA Selects Pennsylvania Firm to Build Liquid Nitrogen Plant  

Science.gov (United States)

Sep 21, 2006 ... NASA has selected Air Products and Chemicals, Inc., Allentown, Pa., to design, furnish and install a plant to produce liquid nitrogen for ...

248

Liquid Nitrogen Dewar Loading at KSC for STS-71 Flight  

Science.gov (United States)

Liquid nitrogen dewar loading at Kennedy Space Center for STS-71 flight with Stan Koszelak (right),

1995-01-01

251

Surface Decontamination by Solution  

International Science & Technology Center (ISTC)

Development of Technology for Metal Surface Decontamination in Aqueous Solutions

256

Thermodynamic Stable Metal Compositions  

International Science & Technology Center (ISTC)

Thermodynamic Stable Metal Compositions for Improvement of an Operational Safety of Constructional Materials under Conditions of Multifactor Loadings of an Aggressive Environment

257

Superconducting properties of metallic superlattices  

Energy Technology Data Exchange (ETDEWEB)

The preparation by sputtering of artificial metallic superlattices is described, as are the results of x-ray structural determinations. Tunneling and resistivity measurements on these materials are reported.

1987-01-01

258

Separator Plates with Metal Felt Insertions  

International Science & Technology Center (ISTC)

Development of Bipolar Separator Plates with Porous Insertions of Metal Felt as Bearing Surfaces for Fuel Cell Electrodes

259

Metals and alloys : atmospheric corrosion testing : General requirements for field tests  

CERN Document Server

Metals and alloys : atmospheric corrosion testing : General requirements for field tests

1992-01-01

260

Heavy Metals Effect on Animal Cells  

International Science & Technology Center (ISTC)

Studies of the Superheavy-metal Effect as a Stress-factor on Protein Biosynthesis and Cytoskeleton Integrity in Animal Cells

261

Compressive and Shear Buckling Analysis of Metal Matrix ...  

Science.gov (United States)

... Title : Compressive and Shear Buckling Analysis of Metal Matrix Composite Sandwich Panels Under Different Thermal Environments. ...

262

Combustible Metallic Igniter Casing for Tank Guns  

Science.gov (United States)

... TANK GUNS, GUNS, CHAMBERS, IGNITERS, INTERIOR BALLISTICS, INTERNAL PRESSURE, COMBUSTIBLE CARTRIDGE CASES, METALS. ...

1991-11-01

263

A NEW FORM OF SOLID STATE SOLAR GENERATOR  

Science.gov (United States)

... nent to the design and construction of metal-semiconductor solar cells, in that both the photovoltage and the efficiency of metal-semiconductor cells ...

1962-01-01

265

Use of evaporation for the treatment of liquids in the nuclear industry  

International Nuclear Information System (INIS)

... The results show that a system decontamination factor of 10^ to 10* can be

1994-07-25

267

Transportation of liquids by pipeline. testing highly volatile liquid pipelines  

Science.gov (United States)

In order to reduce the potential for severe liquid pipeline accidents, the U.S. Materials Transportation Bureau (MTB) proposes to require a hydrostatic test on all onshore pipelines carrying highly volatile liquids which have not been previously tested to at least 1.25 times their maximum operating pressure for at least 24 hr. Comments should be received by the MTB by 2/15/79. Late filed comments will be considered as far as practicable.

1978-11-13

269

Reactions of carbon acids and 1,3-dipoles in the presence of ionic liquids  

International Nuclear Information System (INIS)

The review is devoted to the use of ionic liquids as solvents, immobilized organocatalysts and reagents in reactions involving carbon acids and 1,3-dipoles, which are widely used to prepare practically valuable organic compounds of various classes. The characteristic features of processes in the presence of ionic liquids, the effects of the structure of cations and anions on the regio-, stereo- and enantioselectivities of reactions and methods of recovery of ionic liquids are considered.

2010-09-14

270

Method of removing entrained particles from flue gas and composition of matter  

Energy Technology Data Exchange (ETDEWEB)

A composition of matter to treat particles entrained in flue gas, is described comprising: a caustic liquid used to adjust resistivity of the entrained particles; and inert particulate matter supporting the caustic liquid for inhibiting chemical action of the caustic liquid until used to adjust the resistivity of the entrained particles, the inert particulate matter supporting sufficient caustic liquid to adjust the resistivity of the entrained particles.

1988-04-19

271

Localized Rayleigh Instability in Evaporation Fronts  

CERN Document Server

A qualitatively different manifestation of the Rayleigh instability is demonstrated, where, instead of the usual extended undulations and breakup of the liquid into many droplets, the instability is localized, leading to an isolated narrowing of the liquid filament. The localized instability, caused by a nonuniform curvature of the liquid domain, plays a key role in the evaporation of thin liquid films off solid surfaces.

2009-01-01

272

Explosive acceleration of liquid from a cylindrical container using the implosive technique  

British Library Electronic Table of Contents (United Kingdom)

Tthe acceleration of a liquid from a cylindrical container by the products of instantaneous detonation of a superimposed explosive charge (implosion method) is studies numerically in a two-dimensional formulation. Analytical formulas for the asymptotic velocities of liquid expansion and acceleration of the container body were obtained using numerical calculations in a one-dimensional approximation. The effect of the fracture of the body on the velocity of liquid expansion was studied in a two-dimensional formulation.

2011-01-01

274

AUTOMATIC LIQUID NITROGEN PUMPING SYSTEM FOR PARTICLE ACCELERATORS  

Science.gov (United States)

A description is given of an automatic liquid nitrogen pumping system. Pamping of liquid nitrogen iato cooling traps up to a predetermined level is achieved by an automatically controlled compressed air system. An impontant feature of the equipment is the ability to switch automatically from an empty liquid nitrogen reservoir to a full one. This allows for a much more flexible operation than in conventional systems where the reservoir has to be replaced manually when empty. (auth)

1963-04-16

275

Instabilities during liquid migration into superheated hydrothermal systems  

Energy Technology Data Exchange (ETDEWEB)

Hydrothermal systems typically consist of hot permeable rock which contains either liquid or liquid and saturated steam within the voids. These systems vent fluids at the surface through hot springs, fumaroles, mud pools, steaming ground and geysers. They are simultaneously recharged as meteoric water percolates through the surrounding rock or through the active injection of water at various geothermal reservoirs. In a number of geothermal reservoirs from which significant amounts of hot fluid have been extracted and passed through turbines, superheated regions of vapor have developed. As liquid migrates through a superheated region of a hydrothermal system, some of the liquid vaporizes at a migrating liquid-vapor interface. Using simple physical arguments, and analogue laboratory experiments we show that, under the influence of gravity, the liquid-vapor ...

1995-01-26

276

Development of polarizable chloroform potential and its applications to chloroform-water liquid-liquid interface  

Energy Technology Data Exchange (ETDEWEB)

An all-atom polarizable chloroform (CHCl{sub 3}) potential model has been developed using the classical molecular dynamics techniques. This potential is shown to reproduce reasonably well the structural, dynamical, and thermodynamic properties of bulk liquid CHCl{sub 3} at various temperatures and pressures. With this potential, we carried out computer simulations to investigate the CHCl{sub 3}-H{sub 2}O liquid/liquid interface. Detailed structural and electrical properties at the interface will be analyzed via the density profile, radial distribution functions, molecular orientation, hydrogen bonding, and the z-dependent dipole distributions. Comparison will also be made to the results of the CCl{sub 4}-H{sub 2}O liquid/liquid interface.

1996-10-01

277

Atomic mechanism of glass-to-liquid transition in simple monatomic glasses  

British Library Electronic Table of Contents (United Kingdom)

The atomic mechanism of a glass-to-liquid transition in a monatomic Lennard-Jones (LJ) glass was studied using the molecular dynamics (MD) method. Glassy models were heated up from low temperature at two different heating rates and a glass-to-liquid transition found to occur at the higher heating rate. The temperature dependence of the potential energy, mean-squared-displacements (MSD) of the atoms and the self-intermediate scattering function indicate clearly that a glass transition occurs in the system. The atomic mechanism of the glass-to-liquid transition was investigated by analyzing the spatio-temporal arrangement of liquid-like atoms in the system upon heating. Liquid-like atoms were detected using the Lindemann-melting-like criterion. Upon heating, liquid-like atoms occur at temper...

2011-01-01

278

Alkali metal and alkali metal hydroxide intercalates of the layered transition metal disulfides  

International Nuclear Information System (INIS)

The intercalation reaction of some layered transition metal disulfides with alkali metals, alkali metal hydroxides, and tetraalkylammonium hydroxides were investigated. The alkali metal intercalates were prepared in the respective metal-hexamethylphosphoric triamide solutions in vaccuo, and the hydroxide intercalates in aqueous hydroxide solutions. According to the intercalation reaction, the c-lattice parameter was increased, and the increase indicated the expansion of the interlayer distance. In the case of alkali metal intercalates, the expansion of the interlayer distance increased continuously, corresponding to the atomic radius of the alkali metal. On the other hand, the hydroxide intercalates showed discrete expansion corresponding to the effective ionic radius of the intercalated cation. All intercalates of TaS_2 amd NbS_2 were ...

279

The Stefan problem of evaporation of a volatile component from a binary liquid mixture  

Science.gov (United States)

The study is concerned with the Stefan problem of evaporation of a volatile component from its solution with a virtually non-volatile material. The analysis provides an analytical solution to the problem based on mass-transfer fundamentals. Results yield the evaporation rate, interfacial mole fractions, concentration profiles in the gas and liquid phases, and the location of the evaporation front. The analysis can be used to provide the binary liquid diffusion coefficient of the volatile component based on experimental data for the liquid gas interface position as a function of time. The requirements for such a measurement are discussed in terms of the volatility of the evaporating component and its initial concentration in the liquid mixture.[Figure not available: see fulltext.

2006-01-01

280

Negative charges in liquid hydrogen and deuterium  

Energy Technology Data Exchange (ETDEWEB)

The temperature and pressure dependence of the mobilities of negative charges injected into liquid hydrogen and deuterium have been measured. The authors propose the existence of two types of charge carriers in liquid parahydrogen. One is a bubble with an electron inside while the other has higher mobility. Relaxation of the current through liquid hydrogen was observed. It is suggested that in liquid and solid hydrogen under {beta}-irradiation neutral complexes are created which can trap the negative charges and have a lifetime of about 10 hours. 6 refs., 5 figs.

1992-11-01

281

Sandia National Laboratories support of the Iraq Nuclear Facility Dismantlement and Disposal Program.  

Energy Technology Data Exchange (ETDEWEB)

Because of past military operations, lack of upkeep and looting there are now enormous radioactive waste problems in Iraq. These waste problems include destroyed nuclear facilities, uncharacterized radioactive wastes, liquid radioactive waste in underground tanks, wastes related to the production of yellow cake, sealed radioactive sources, activated metals and contaminated metals that must be constantly guarded. Iraq currently lacks the trained personnel, regulatory and physical infrastructure to safely and securely manage these facilities and wastes. In 2005 the International Atomic Energy Agency (IAEA) agreed to organize an international cooperative program to assist Iraq with these issues. Soon after, the Iraq Nuclear Facility Dismantlement and Disposal Program (the NDs Program) was initiated by the U.S. Department of State (DOS) to support the IAEA and assist the Government of Iraq (GOI) in eliminating the threats from ...

2009-03-01

282

Final Report for "Investigation of reaction networks and active sites in bio-ethanol steam reforming over Co-based catalysts" with all publications attached.  

Energy Technology Data Exchange (ETDEWEB)

This was a university-based research project in support of distributed reforming production technologies for hydrogen. Our objective was to examine the steam reforming of bio-ethanol and other related bio-derived liquids over non-precious metal catalyst systems to enable small-scale distributed hydrogen production technologies from renewable sources. The study targeted development of a catalytic system that does not rely on precious metals and that can be active in the 350-550 C temperature range, with high selectivity and high stability. To this end, we adopted a multi-prong research strategy, that included catalyst formulation and synthesis, detailed catalyst characterization, reaction kinetics and reaction engineering, molecular modeling and economic analysis studies. Our approach was an iterative one, where the knowledge gained in one aspect of the study was utilized to modify and fine-tune catalyst development. The ...

2011-03-31

283

Space effect on liquid film flow in a BWR fuel bundle  

Science.gov (United States)

Critical power at boiling transition is an important factor in a boiling water reactor (BWR) fuel bundle design. Boiling transition under high quality accounts for dryout as the result of the complete disappearance of film flow on a fuel rod. This liquid film vanishing process can be calculated by the liquid film model, which takes into account the evaporation due to heat from the rod surface, liquid film entrainment by steam flow, and liquid droplet deposition. It is known that spacers affect liquid film entrainment and liquid droplet deposition, so the detailed study of spacer effects on hydrodynamic characteristics is necessary for critical power prediction based on the film flow model. Many studies have been conducted to examine spacer effects on liquid film flow. However, most of them are restricted to simple test sections such as a ...

1991-01-01

284

The effect of metal ceramic restoration framework design on tooth color  

British Library Electronic Table of Contents (United Kingdom)

Statement of problem The opacity of the metal framework in metal ceramic restorations results in reduced light transmission through the tooth that diminishes the esthetics of the tooth. Purpose The purpose of this study was to investigate the color change that occurs apically to a metal ceramic restoration as a result of altering the metal framework design. Material and methods Color change relative to the unprepared tooth (DE) between various metal ceramic restorations was determined using computer imaging and CIELAB coordinates and compared to previously determined levels of clinical acceptability. Color change was evaluated by examining 2 conditions (the metal copings and the completed metal ceramic restorations), 4 framework designs (metal collar and porcelain margins with 0-mm, 1-mm, ...

2008-01-01

285

Fracture Resistance of Metal Ceramic Restorations with Two Different Margin Designs After Exposure to Masticatory Simulation  

British Library Electronic Table of Contents (United Kingdom)

Statement of problem Although the esthetic outcome of a collarless metal ceramic restoration is superior to that of a restoration with a metal margin, its mechanical strength has not been evaluated. Purpose The purpose of this study was to evaluate and compare the fracture resistance of metal ceramic restorations with metal margins to that of metal ceramic restorations with circumferential porcelain margins, after exposure to masticatory simulation. Material and methods Twenty-four metal ceramic restorations were fabricated and paired with 24 cobalt-chrome tooth analogs. Twelve of the specimens had metal margins, while the remainder had circumferential porcelain margins. The restorations were cemented on the metal tooth analogs with a resin-modified glass ionomer luting agent (FujiCEM). Al...

2009-01-01

286

Are Stars with Planets Polluted?  

CERN Document Server

We compare the metallicities of stars with radial velocity planets to the metallicity of a sample of field dwarfs. We confirm recent work indicating that the stars-with-planet sample as a whole is iron rich. However, the lowest mass stars tend to be iron poor, with several having [Fe/H]0.48) that contributes to but does not explain the mass-metallicity trend in the stars-with-planets sample. We use Monte Carlo models to show that adding an average of 6.5 Earth masses of iron to each star can explain both the mass-metallicity and the age-metallicity relations of the stars-with-planets sample. However, for at least one star, HD 38529, there is good evidence that the bulk metallicity is high. We conclude that the observed metallicities and metallicity trends are the result of the interaction of three effects; accretion of ...

2002-01-01

287

Modification of surface properties of copper-refractory metal alloys  

Energy Technology Data Exchange (ETDEWEB)

The surface properties of copper-refractory metal (CU-RF) alloy bodies are modified by heat treatments which cause the refractory metal to form a coating on the exterior surfaces of the alloy body. The alloys have a copper matrix with particles or dendrites of the refractory metal dispersed therein, which may be niobium, vanadium, tantalum, chromium, molybdenum, or tungsten. The surface properties of the bodies are changed from those of copper to that of the refractory metal.

1993-10-12

288

Models for the rate of benzene sulfonation in heterogeneous systems  

Science.gov (United States)

Macrokinetics of benzene sulfonation in liquid-liquid and gas-liquid systems has been studied in continuous mixed reactors. It has been shown that the rate of sulfonation of benzene at 25/sup 0/C in two liquid phases using concentrated sulfuric acid is kinetically controlled. Whereas the rate of the latter reaction by gaseous sulfur trioxide at the same temperature is largely affected by the diffusional phenomena. At this temperature, the rate of reaction in gas-liquid system was described by a model assuming a fast reaction in the liquid phase. However, by increasing the temperature, the fast reaction region gradually changed to instantaneous reaction regime. A model, describing such a regime has also been developed and verified experimentally.

1986-09-01

289

Method of reducing volume of radioactive liquid waste  

International Nuclear Information System (INIS)

Purpose: To enable the solidification of liquid waste containing radioactive substance in a free shape with large volume reduction ratio without a pulverizing step by producing solute in the liquid waste as a slurry in a predetermined organic solvent and forming it into a cake by mechanical exfoliation. Method: Liquid waste containing suitably concentrated radioactive substances is supplied to a centrifugal thin film evaporator together with an organic agent having a higher boiling point than water and a non aqueous solution to evaporate the water content, the solute in the waste is produced as a slurry in the organic solvent, and removed as cake-state solute slightly residued with the organic solvent by the mechanical exfoliation such as centrifugal exfoliation or settling exfoliation from the slurry-state liquid. Accordingly, it can be increased in size as compared with the powder reduced in volume of ...

1981-08-01

290

Is cold better ? - exploring the feasibility of liquid-helium-cooled optics.  

Energy Technology Data Exchange (ETDEWEB)

Both simulations and recent experiments conducted at the Advanced Photon Source showed that the performance of liquid-nitrogen-cooled single-silicon crystal monochromators can degrade in a very rapid nonlinear fashion as the power and for power density is increased. As a further step towards improving the performance of silicon optics, we propose cooling with liquid helium, which dramatically improves the thermal properties of silicon beyond that of liquid nitrogen and brings the performance of single silicon-crystal-based synchrotrons radiation optics up to the ultimate limit. The benefits of liquid helium cooling as well as some of the associated technical challenges will be discussed, and results of thermal and structural finite elements simulations comparing the performance of silicon monochromators cooled with liquid nitrogen and helium will be given.

1999-09-30

291

Selection study of self actuated shutdown system for a large scale FBR  

International Nuclear Information System (INIS)

The Self Actuated Shutdown System (SASS) is now under development for use in a large scale FBR, in order to establish the passive shutdown capability against the postulated ATWS events, i.e. ULOF, UTOP and ULOHS. The function of SASS makes use of the safety characteristics of a liquid metal cooled FBRs such as a large subcooling and low pressure system. The insertion of the control rods insertion is assured even in the most conservative seismic design condition by employing articulate rods and the SASS will be installed into the detaching mechanism employing a curie point the magnet alloy. ULOF analysis of the present FBR shows that coolant boiling inception is prevented if a control rod of the SASS is detached at the uppermost temperature of 680degC for the Curie point magnet, and after the reactor shutdown the coolant temperature is kept below 600degC by the pony motor flow. Therefore the SASS will establish passive shutdown capability ...

1995-04-23

292

Review of high-level waste form properties. [146 bibliographies  

Energy Technology Data Exchange (ETDEWEB)

This report is a review of waste form options for the immobilization of high-level-liquid wastes from the nuclear fuel cycle. This review covers the status of international research and development on waste forms as of May 1979. Although the emphasis in this report is on waste form properties, process parameters are discussed where they may affect final waste form properties. A summary table is provided listing properties of various nuclear waste form options. It is concluded that proposed waste forms have properties falling within a relatively narrow range. In regard to crystalline versus glass waste forms, the conclusion is that either glass of crystalline materials can be shown to have some advantage when a single property is considered; however, at this date no single waste form offers optimum properties over the entire range of characteristics investigated. A long-term effort has been applied to the development of glass and calcine waste forms. Several ...

1980-12-01

293

Reactivity surveillance experiments with the engineering mock-up core of the fast flux test facility reactor  

International Nuclear Information System (INIS)

An experiment was performed with a mock-up of the core of the Fast Flux Test Facility (FFTF) reactor to evaluate three reactivity measurement methods for application to liquid-metal fast breeder reactors (LMFBR): modified source multiplication measurements with the low-level flux monitor for refueling (35 dollars subcritical) of FFTF, noise analysis to 35 dollars subcritical, and inverse kinetics rod drop to 12 dollars subcritical. To investigate the spatial dependence of these measurement methods and to resolve discrepancies previously reported, detectors were placed in the core, reflector, and radial shield, and experimental data were collected with the reactivity at near delayed criticality to 35 dollars subcritical. Conclusions from this experiment are the following. Low-level flux monitors in the shield of the FFTF will be adequate for reactivity surveillance during refueling, using the modified source multiplication method calibrated near critical by an ...

294

Material flows of mobile phones and accessories in Nigeria: Environmental implications and sound end-of-life management options  

International Nuclear Information System (INIS)

Presently, Nigeria is one of the fastest growing Telecom markets in the world. The country's teledensity increased from a mere 0.4 in 1999 to 10 in 2005 following the liberalization of the Telecom sector in 2001. More than 25 million new digital mobile lines have been connected by June 2006. Large quantities of mobile phones and accessories including secondhand and remanufactured products are being imported to meet the pent-up demand. This improvement in mobile telecom services resulted in the preference of mobile telecom services to fixed lines. Consequently, the contribution of fixed lines decreased from about 95% in year 2000 to less than 10% in March 2005. This phenomenal progress in information technology has resulted in the generation of large quantities of electronic waste (e-waste) in the country. Abandoned fixed line telephone sets estimated at 120,000 units are either disposed or stockpiled. Increasing quantities of waste mobile phones estimated at 8 million units by 2007, ...

2008-02-01

295

K and L x-ray production cross sections excited by 14.00--34.16 MeV #alpha#-particle beams  

International Nuclear Information System (INIS)

K and L-shell x-ray production cross sections were measured using #alpha#-particle beams of 14.00 to 34.16 MeV. The K-shell measurements ranged from Z = 20 to Z = 50 and included Ca, Sc, Ti, V, Fe, Ni, Cu, Zn, Ga, Br, Rb, Sr, Y, Mo, Ag, In, and Sn while the L-shell measurements ranged from Z = 55 to Z = 92 and included Cs, Ba, Ce, Gd, Tm, Lu, Au, Pb, Th, and U. Thin metallic foils were used for the measurements and corrections for self-attenuation were negligible. A liquid nitrogen cooled Si(Li) detector and associated pulsed optical electronics were used in detecting x-rays. Absolute cross sections with an uncertainty of +-10 percent are presented for the elements measured. Also smoothed cross sections are presented which were generated by a three term polynomial fit of the experimental data points. By use of available fluorescence yields the K-shell data were converted to ionization cross sections and compared to various theoretical models. ...

296

FFTF [Fast Flux Test Facility] Fission Gas Monitor Computer System  

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) is a liquid-metal-cooled, fast neutron test reactor located on the Hanford Site. A dual computer system has been developed to monitor the reactor cover gas to detect and characterize any fuel or test pin fission gas releases. The system acquires gamma spectra data, identifies isotopes, calculates specific isotope and overall cover gas activity, presents control room alarms and displays, and records and prints data and analysis reports. The Fission Gas Monitor System (FGMS) integrates commercially available hardware and software, providing a reliable and easily maintained system. The design provides extensive automation of previous manual operations, reducing the need for operator training and minimizing the potential for operator error. The dual nature of the system allows either system A or B to be taken out of service for periodic tests or maintenance without interrupting the overall system performance. A control room color ...

297

Dose reduction by chemical decontamination  

International Nuclear Information System (INIS)

At the Borssele Nuclear Power Station, which has been in operation since 1973, a comprehensive program of modifications, one of the most extensive of its kind worldwide, was conducted in 1997 within the framework of an integral safety evaluation carried out at ten-year intervals, especially in the nuclear section. The collective dose associated with this activity was greatly reduced by Alara measures, one of which was chemical decontamination of part of the emergency and residual heat removal systems. An average decontamination factor (DF) of 17 was achieved by using the Siemens Cord UV process. Two decontamination cycles were required. The decontamination program took three days to be completed. The planned collective dose was reduced from 1029 mSv (without decontamination) to 335 mSv (on the basis of a DF of 8). Based on the DF of 17 achieved, the planned dose was corrected downward to 270 mSv. The dose finally achieved was 118 mSv. A total of 13.7 kg of metal ...

1998-10-01

298

Design of a closed 4 MW spallation target module with heat removal system for an ADS system  

International Nuclear Information System (INIS)

At the Forschungszentrum Karlsruhe the HGF Strategy Fund project entitled 'Innovative Technology to Reduce Radiotoxicity' is performed which delivers an essential scientific contribution to the application oriented fundamental research for Accelerator Driven Systems (ADS). The addressed topics are in the areas of heavy liquid metal technology, thermalhydraulics and materials / corrosion. An ADS consists of three main components: an proton accelerator, a spallation target and a subcritical blanket. The strategic objective of an ADS is the transmutation of long-lived radioactive waste (plutonium, minor actinides and long-lived fission products) into short-lived isotopes or stable elements, thus closing the fuel cycle. The objective of one task of the HGF Strategy Fund Project is the numerical calculation of a closed spallation target module. In a consequent next step such a spallation target can be experimentally investigated at IKET and the ...

299

Changes in the flexural strength of engineering ceramics after high temperature sodium corrosion test. Influence after sodium exposure for 1000 hours  

International Nuclear Information System (INIS)

Engineering ceramics have excellent properties such as high strength, high hardness and high heat resistance compared with metallic materials. To apply the ceramic in fast reactor environment, it is necessary to evaluate the sodium compatibility and the influence of sodium on the mechanical properties of ceramics. In this study, the influence of high temperature sodium on the mechanical properties of sintered ceramics of conventional and high purity Al_2O_3, SiC, SiAlON, AlN and unidirectional solidified ceramics of Al_2O_3/YAG eutectic composite were investigated by means of flexure tests. Test specimens were exposed in liquid sodium at 823K and 923K for 3.6Ms. There were no changes in the flexural strength of the conventional and high purity Al_2O_3, AlN and Al_2O_3/YAG eutectic composite after the sodium exposure at 823K. On the contrary, the decrease in the flexural strength was observed in SiC and SiAlON. After the sodium exposure at 923K, ...

300

Analysis of ZPPR experiments supporting production of "6"0Co in FFTF  

International Nuclear Information System (INIS)

An effort to expand the irradiation mission of the Fast Flux Test Facility (FFTF) beyond testing fuels and materials for the liquid-metal reactor (LMR) program included a study of the feasibility of producing commercial quantities of "6"0Co. The "6"0Co would be produced by neutron capture in assemblies containing an array of natural cobalt pins and hydrogen-bearing moderator pins located at the periphery of the FFTF core. Adding hydrogenous material to the assemblies enhances "6"0Co production by slowing neutrons into energy ranges where the "5"9Co capture cross section is higher. Some of the moderated neutrons leak from the moderated region to adjacent fuel regions, increasing local fission rates. In order to validate calculated fission rates and establish calculational biases and uncertainties, experiments were conducted in the zero-power plutonium reactor (ZPPR) to measure fission rates in fuel regions adjacent to a mock-up of a cobalt production assembly. The ...

1987-06-07

301

Activities performed within the program of Nuclear Safety Research on structural and cladding materials for innovative reactor systems able to transmute nuclear waste  

International Nuclear Information System (INIS)

Full text: The transmutation of nuclear waste to reduce the burden on a geological repository is a relevant topic within the Program of Nuclear Safety Research of the Research Centre Karlsruhe. Several studies have confirmed that a high efficiency of transmutation of actinides is reached in fast neutron spectrum reactor system. Therefore, an important effort is dedicated to the study of transmutation strategies with different fast reactors and their associated technologies. Moreover, in international contexts as Generation IV International Forum (GIF) and Sustainable Nuclear Energy Technology Platform (SNETP), fast reactors are considered in the frame of sustainable development of nuclear energy and reduction of waste. The systems that are currently under investigation, in the frame of the different fuel cycle scenarios, are liquid metal cooled and gas cooled fast reactors as well as Accelerator Driven Sub-critical Transmutation devices (ADS). ...

2009-10-05

302

Achievement report for fiscal 1998. Research and development on a new manufacturing method for functional thin films suitable for recycling, and their application to colored glasses (the second year); 1998 nendo seika hokokusho. Recycle ni tekishita kinosei usumaku no shinki seizoho to chakushoku glass eno oyo ni kansuru kenkyu kaihatsu (dai 2 nendo)  

Energy Technology Data Exchange (ETDEWEB)

A new thin film manufacturing method is established to add a function to glass material surface, as a new material technology which harmonizes with global environment, and is suitable for resource re-utilization and energy conservation. It is intended to develop a leading technology to promote recycling of colored glasses by applying this technical method to colored glasses. Fiscal 1998 has implemented subsequently to fiscal 1997 the following subjects in the three research items composed of a new manufacturing method of functional thin films, application of the functional thin films to colored glasses, and the comprehensive investigative studies: establishment of an industrial manufacturing method for color coating liquid and evaluation of basic characteristics of the colored functional thin films, optimization of element technology for photo-sensitive gel films by means of chemically modifying metallic alkoxide, tests of forming films on ...

1999-03-01

303

Regulatory Framework for Advanced Fuel Cycle Facility Using Pyroprocess in Korea  

International Nuclear Information System (INIS)

Nuclear power plants of 20 units of in Korea are generating about 700 MTU of spent fuels annually. The inventory of spent fuels in Korea were estimated about 10,087.07 MTU at end of 2008, and the storage space of spent fuels won't be available any more at 2016 due to the saturation of the spent fuel pools in the plants. In addition, in order to reduce carbon emission and correspond to the enormous electricity demand in Korea, 8 units of nuclear power plants are under construction and several more plants are under planning. The 100,000 MTU of spent fuel inventory are expected by the year of 2095 in Korea. Therefore, short term and long term of spent fuel management plans are under discussion and implementation in Korea. As a short term of spent fuel management strategy for the target year of 2016, central or local spent fuel dry interim storage options are mostly under discussion. As a long term of management plan, fast reactor and advanced fuel cycle R and D plan were approved by 255th ...

2010-10-01

304

Hydrogen in metals  

International Nuclear Information System (INIS)

An important application of metal hydrides is as a moderator material in nuclear reactors. The fundamental properties of hydrides are illustrated and an impression given of the current research into hydrogen in transition metals. Phase diagrams, magnetic properties, temperature dependence of the diffusion coefficient, energy level schemes and superconductivity are considered. (C.F.).

305

Fatigue and creep crack growth behaviour at high temperatures for weld metals of Alloy 800 and Alloy 617  

International Nuclear Information System (INIS)

High temperature fatigue crack growth (FCG) and creep crack growth (CCG) experiments have been conducted in air on weld metal, heat affected zone (HAZ) and base metal of the austenitic Alloy 800 and the nickel base Alloy 617. Tests were performed on specimens machined from pipes, in the temperature range 550-900 deg. C. The crack propagation mode was examined. At all temperatures and for both materials, FCG of base metal was found to be the highest, whereas the weld metal exhibited the lowest FCG rate. The FCG rate in the HAZ was found to lie in between of those observed for base and weld metal. The crack propagation mode remained transgranular in base metal and transdendritic in weld metal at all temperatures. CCG behaviour could be described using the energy rate integral C*. Base metal and weld ...

1993-08-15

306

Biosorption of heavy metals by free and immobilised biomass  

Energy Technology Data Exchange (ETDEWEB)

A review of the research activities carried out by the authors on biosorption of heavy metals is reported in this work. In particular, biomass characterisation, biosorption equilibrium with single metal system, biomass immobilisation in polymeric matrix and related kinetics, biosorption in membrane reactor systems are the main aspects reported in the paper. (orig.)

2000-07-01

307

Application of ?- and ?-Isomerism of Octahedral Metal Complexes for Inducing Chiral Nematic Phases  

UK PubMed Central (United Kingdom)

The Δ- and Λ-isomerism of octahedral metal complexes is employed as a source of chirality for inducing chiral nematic phases. By applying a wide range of chiral metal complexes as a...Full Text Available

308

Rapid and continuous hydrothermal crystallization of metal oxide particles in supercritical water  

Energy Technology Data Exchange (ETDEWEB)

This paper reports on hydrolysis of 10 metal salt aqueous solutions of 6 metal oxides that was conducted in supercritical water. Continuous and rapid production of metal oxide fine particles was achieved by mixing a metal salt aqueous solution with preheated water fed from another line. The reaction time required was less than 2 min. Particle size, morphology, and crystal structure of the obtained metal (hydrous) oxides were examined. Particle size (20 to 600 nm) was different among the system but the size range was relatively narrow in all the cases.

1992-04-01

309

Two-Phase Stefan Problem with Interfacial Energy and Entropy.  

Science.gov (United States)

The classical Stefan theory for the melting of a solid or the freezing of a liquid is too simplistic to describe phenomena such as supercooling, in which a liquid supports temperatures below its freezing point, or superheating, the analog for solids, or d...

1985-01-01

310

Technology application for processing highly viscous liquid in polymer plants  

Energy Technology Data Exchange (ETDEWEB)

This paper introduces recent instances of polymerizers for highly viscous liquid needed in the field of synthetic resin and synthetic fiber. A horizontal twin-shaft type polymerizer has two horizontally rotating shafts with stirring blades of spectacle-shaped type, which are arranged at a 90 [degree] phase difference. As they rotate, they scrape highly viscous liquid sticking to the surface inside the polymerizer and on the rotating shafts. This polymerizer is capable of processing highly viscous liquid up to about 2000 Pa[center dot]s. A lattice-type twisting blade polymerizer is a vertical-type reactor and features a special stirring blade capable of stirring highly viscous liquid up to 5000 Pa[center dot]s This polymerizer has no central rotating shaft so that highly viscous liquid does not stick on it. A sloped blade-type thin-film evaporator has spiral blades in the ...

1993-01-01

311

Molar and excess volumes of liquid In-Sb, Mg-Sb, and Pb-Sb alloys  

Energy Technology Data Exchange (ETDEWEB)

By a direct Archimedes' technique, volumetric data were obtained for liquid In, Mg, Pb, and Sb and mixtures of In-Sb, Mg-Sb, and Pb-Sb. In this paper the excess volumes for the alloys studied are presented and discussed.

1990-04-01

312

Methylprednisolone acetate induced release of cartilage proteoglycans: determination by high performance liquid chromatography.  

UK PubMed Central (United Kingdom)

A high performance liquid chromatography (HPLC) procedure suitable for the simultaneous determination of the molecular size and concentration of macromolecular hyaluronate and proteoglycans in synovial...Full Text Available

1992-02-01

313

Ionic liquids for post combustion CO{sub 2} absorption  

Energy Technology Data Exchange (ETDEWEB)

The use of ionic liquids for post combustion capture was discussed. Compared to other solvents, ionic liquids can be used in higher concentrations. Other advantages include the large variation in physical and chemical properties and the non measurable vapor pressure. In this study, 78 different ionic liquids were synthesized and the carbon dioxide absorption rate was measured. The most promising ionic liquids were produced and various tests were made to identify the most suitable absorption solvent. The vapor-liquid equilibrium curve was measured between 40 and 110 degrees C. Pilot plant tests with MEA and one selected ionic liquid test with 30 per cent MEA at the pilot plant at the EVNs Duernrohr Power Station in Lower Austria are running successfully with a capture performance of approximately 87 per cent. The experiments will provide a direct comparison of ...

2009-07-01

314

Ion transport properties of lithium ionic liquids and their ion gels  

International Nuclear Information System (INIS)

A new series of lithium ionic liquids were prepared by introducing of two electron-withdrawing trifluoroacetyl groups in borate salts containing two methoxy-oligo(ethylene oxide) groups in the structures. Successive substitution reactions of oligo-ethylene glycol monomethyl ether and trifluroacetic acid from LiBH_4 yielded the lithium salts, which were clear and colorless liquids at room temperature. The fundamental physicochemical properties, such as density, thermal property, viscosity, ionic conductivity, self-diffusion coefficients, and electrochemical stability, were measured. The lithium ionic liquids had self-dissociation ability and conducted ions even in the absence of organic solvents. New polymer electrolytes, named 'ion gels', were prepared by radical cross-linking reactions of a poly(ethylene oxide-co-propylene oxide)tri-acrylate macromonomer in the presence the lithium ionic liquid. An ...

2005-06-30

315

Investigation of enzymatic biodiesel production using ionic liquid as a co-solvent  

Energy Technology Data Exchange (ETDEWEB)

Ionic liquids can enhance the activity, selectivity, and stability of enzyme catalysts. Enzymes and ionic liquids as catalysts are seen as a more environmentally friendly technology than the use of traditional catalyst materials in biofuels production. This study investigated the lipase catalyzed esterification reaction for biodiesel production in the presence of the ionic liquid BMIM PF{sub 6}. Methyl acetate was used as the acyl acceptor. A titremetric assay was conducted to measure the activity of the lipase with various amounts of ionic liquid. Reaction parameters were investigated in order to determine their effects on biodiesel conversion. An 80 per cent overall methyl oleate biodiesel yield was successfully produced in the presence of the ionic liquid. The ionic liquid improved lipase activity as well as overall biodiesel yield. Results also showed that ...

2010-04-15

316

Determination of Salirasib (S-trans, trans-farnesylthiosalicylic acid) in human plasma using liquid chromatography-tandem mass spectrometry  

UK PubMed Central (United Kingdom)

A liquid chromatography/tandem mass spectrometric (LC/MS/MS) assay was developed for the quantitative determination of salirasib (S-trans, trans-farnesylthiosalicylic acid,...Full Text Available

2008-06-15

317

Detection and Identification of Ciprofloxacin-Resistant Yersinia pestis by Denaturing High-Performance Liquid Chromatography  

UK PubMed Central (United Kingdom)

Denaturing high-performance liquid chromatography (DHPLC) has been used extensively to detect genetic variation. We used this method to detect and identify Yersinia pestis KIM5 ciprofloxacin-resistant...Full Text Available

2003-07-01

318

Anion-exchange extraction of cephapirin, cefotaxime, and cefoxitin from serum for liquid chromatography.  

UK PubMed Central (United Kingdom)

An anion-exchange column technique for extraction of antibiotics from serum proteins has been developed for use in the assay of cephapirin, cefotaxime, and cefoxitin by high-pressure liquid chromatography....Full Text Available

1982-04-01

319

Toxicity and Bioavailability of Metals in the Missouri River ...  

Science.gov (United States)

contaminated groundwater from the ASARCO metals refining facility ... ditch or creek crossing the ASARCO property at its northern end) and one at its ...

320

Temperature Histories of Small Metallic Fragments Trapped in ...  

Science.gov (United States)

... Abstract : Small metallic fragments can be trapped in combustible cartridge cases during manufacture and released into the interior-ballistic flow ...

1990-10-01

321

NASA TM X-52248 - NASA Technical Report Server (NTRS)  

Science.gov (United States)

Magnetic Forming (10). - Forming of metals (the metal needs only to be an electrical conductor) is achieved without physical contact ...

322

Metals and kidney autoimmunity.  

UK PubMed Central (United Kingdom)

The causes of autoimmune responses leading to human kidney pathology remain unknown. However, environmental agents such as microorganisms and/or xenobiotics are good candidates for that role. Metals,...Full Text Available

1999-10-01

323

Laser-assisted solar cell metallization processing - NASA ...  

Science.gov (United States)

Oct 15, 1985 ... Title: Laser-assisted solar cell metallization processing. No Digital Version Available: Go to Tips on Ordering ...

324

Immobilization of waste material  

International Nuclear Information System (INIS)

A method is described for immobilizing or solidifying waste material, which includes blending the waste material with powdered metal and subjecting the mixture of waste material and powdered metal to high pressure. (author).

325

DISTORTION OF A MAGNETIC FIELD BY THE MOTION OF A ...  

Science.gov (United States)

... No. 52. Metal Complexew-I. Preparation and Physical Properties of Transition Metal Complexes of 6-Mercaptopurine and ,-Mercapto-6, 7-Diphenyl ...

1965-06-01

327

AN EVALUATION OF AN IMPORTANT ADVANCE IN ...  

Science.gov (United States)

... No. 52. Metal Complexes-I. Preparation and Physical Properties of Transition Metal Complexes of 6-Mercaptopurine and 4-Mercapto-6, 7-Diphenyl ...

1965-03-01

328

Theory of melting and crystallization  

Energy Technology Data Exchange (ETDEWEB)

A consistent statistical theory of the crystal-liquid phase transition is developed, being based on a method which takes into account liquidlike fluctuations in crystals and solidlike clusters in liquids. It is shown that degenerate fluidlike droplets have a finite number density at zero temperature, while nondegenerate fluctuations disappear when the temperature goes to zero. The existence of a melting point is proved. This method, which takes into consideration the heterophase fluctuations, provides the possibility of describing metastable states such as a supercooled liquid or an overheated crystal. Conditions for the existence of metastable states are found. The liquid-glass transition can also be described by the method presented here.

1985-07-01

329

The design of an irradiator for the continuous processing of liquid latex  

International Nuclear Information System (INIS)

This paper presents anew design concept for a gamma irradiation plant for the continuous processing of pumpable liquids. Typical applications of such a plant include: the irradiation vulcanisation of natural latex rubber; disinfection of municipal sewage sludge for agricultural use; sterilisation of liquids in the pharmaceutical and cosmetics industries; industrial processing of bulk liquids The authors describe the design and operation of the latex irradiator now operating on a small production scale in Malaysia and proposed developments. The design allows irradiation processing to be carried out under an inert or other gaseous environment. State-of-the-art computer control system ensures the fully automatic processing operation needed by industrial computers.

1998-06-01

330

Search for an instability on a quenched-liquid interface  

Energy Technology Data Exchange (ETDEWEB)

We searched for signs of an instability on the interface between the two phases of a binary-liquid mixture, isobutyric acid and water, after the mixture was quenched further into the two-phase region. Such an instability would be the liquid-liquid analog of the Mullins-Sekerka instability seen in quenched alloys. Never is any dramatic growth observed, but under conditions of small dimensionless quench depth (theta<1.5 x 10/sup -3/), the intensity of light scattered from the interface grows for small values of the momentum transfer k.

1987-04-15

331

Relation of the One-Phase Stefan Problem to the Seepage of ...  

Science.gov (United States)

... Accession Number : ADA079641. Title : Relation of the One-Phase Stefan Problem to the Seepage of Liquids and Electrochemical Machining,. ...

1979-12-01

332

Orbital storage and supply of subcritical liquid nitrogen  

Science.gov (United States)

Subcritical cryogenic fluid management has long been recognized as an enabling technology for key

1990-01-01

333

Modeling Cavitation in Cryogenic Fluids: Validation for Liquid Nitrogen, Hydrogen, and Oxygen  

Science.gov (United States)

This viewgraph presentation provides an overview of research designed to provide a numerical

2003-01-01

334

Measurement of liquid xenon scintillation from heavy ions using a silicon photodiode  

Energy Technology Data Exchange (ETDEWEB)

Scintillation light in liquid xenon excited by 100 MeV/n Al ions was detected with a home-made silicon photodiode. The diameter of the photodiode was 2 inch. The effective quantum efficiency was observed to be 22% for the wavelength of liquid xenon scintillation light (170 nm), while the effective quantum efficiency for 5.486 MeV alpha-particle excitation was 44%. An energy resolution of 0.5% rms was achieved for the energy deposition of 2.5 GeV in liquid xenon using a fast preamplifier ({approx equal} 20 ns). (orig.).

1991-11-15

335

Mathematical Modeling and Optimization Studies on ...  

Science.gov (United States)

... 1]. Results and Discussion A cross section of liquid feed direct borohydride fuel cell model was created and studied. The ...

2010-05-12

336

Liquid nitrogen dewar for protein crystal growth  

Science.gov (United States)

Gaseous Nitrogen Dewar apparatus developed by Dr. Alex McPherson of the University of California,

2001-01-01

337

Iodine decontamination factor for liquid radioactive waste volume reduction system  

International Nuclear Information System (INIS)

(Jun 1976). United States Tokerud, LD Garcia, R. Aerojet Energy Conversion

1976-06-13

338

Battery Thermal Management System Design Modeling  

Energy Technology Data Exchange (ETDEWEB)

Looks at the impact of cooling strategies with air and both direct and indirect liquid cooling for battery thermal management.

2006-11-01

339

A thermal hydraulic investigation on ADSR liquid lead target  

Energy Technology Data Exchange (ETDEWEB)

Computational fluid dynamics(CFD) code FLUENT was used to simulate the thermal hydraulic processes occurring in conceptual design of the accelerator-driven subcritical reactor(ADSR) liquid lead target. The purpose of the analysis is to investigate the thermal hydraulic characteristics of liquid lead as ADSR target material with various target geometries and injection locations of proton beam. In the calculation analysis, the local temperature of the liquid lead target rises to the boiling temperature very rapidly. When the proton beam is injected from the bottom of the target system, the duration time to reach the boiling temperature is longer and the temperature distribution is flatter than other cases.

1998-05-01

340

The separation and determination of trace elements in iron ore  

International Nuclear Information System (INIS)

The separation, concentration, and determination of trace elements in iron ores are described. After the sample has been dissolved, the iron is separated by liquid-liquid extraction with a liquid cation-exchanger, di-(2-ethylhexyl) phosphoric acid. The trace elements aluminium, cadmium, calcium, chromium, cobalt, copper, lead, magnesium, manganese, mercury, potassium, sodium, vanadium, and zinc are determined in the aqueous phase by atomic-absorption spectrophotometry.

2008-05-01

341

Rayleigh Scattering in Rare Gas Liquids  

CERN Document Server

The Rayleigh scattering length has been calculated for rare-gas liquids in the ultraviolet for the frequencies at which they luminesce. The calculations are based on the measured dielectric constants in the gas phase, except in the case of xenon for which measurements are available in the liquid. The scattering length mayplace constraints on the design of some large-scale detectors, using uv luminescence, being proposed to observe solar neutrinos and dark matter. Rayleigh scattering in mixtures of rare-gas mixtures is also discussed.

2002-01-01

342

Quantitative determination of atmospheric hydroperoxyl radical  

Energy Technology Data Exchange (ETDEWEB)

A method for the quantitative determination of atmospheric hydroperoxyl radical comprising: (a) contacting a liquid phase atmospheric sample with a chemiluminescent compound which luminesces on contact with hydroperoxyl radical; (b) determining luminescence intensity from the liquid phase atmospheric sample; and (c) comparing said luminescence intensity from the liquid phase atmospheric sample to a standard luminescence intensity for hydroperoxyl radical. An apparatus for automating the method is also included.

2007-10-23

343

Interphase mass transfer in the separation of isotopes in countercurrent columns (liquid-solid systems)  

International Nuclear Information System (INIS)

The results of calculated and experimental investigation of interphase isotopic exchange efficiency in countercurrent columns are given when separation processes of isotope mixtures are taken place with use of liquid-solid systems. Effect of liquid phase flow on transfer unit height in ion exchange separation of boron, lithium, nitrogen isotopes is considered. 40 refs.; 5 figs.

344

Comparison of the charge injection barrier at realistic and ideal metal/organic interfaces: metals become faceless  

Energy Technology Data Exchange (ETDEWEB)

Most of the organic electronic devices are nowadays fabricated under poor vacuum conditions. In this regard, there is only little knowledge about the impact of contamination of the metal electrode on the charge injection barrier in this kind of electronic devices. In our study we have performed X-ray and ultra violet photoemission spectroscopy (XPS, UPS) on interfaces between the organic semiconductor -sexithiophene and sputter cleaned (ideal) metals as well as contaminated (realistic) metals. As metal substrates we have used silver, gold, palladium, and platinum. These metals provide us a wide range of metal work functions from 4.2 eV for silver up to 5.5 eV for platinum. For all interfaces of -sexithiophene and contaminated metals we have observed a reduction of the interface dipole and the hole injection barrier. The charge injection ...

2007-07-01

345

The thermal conductivity jump at crystal-liquid phase transition in CHCl3, C6H6, and CCl4: the action of rotational molecular motions  

International Nuclear Information System (INIS)

The thermal conductivity of liquid CHCl3, C6H6, and CCl4 is measured by a steady-state method under saturated vapor pressure in the temperature regions corresponding to pre-crystallization temperatures. The experimental results obtained are used to investigate the isobaric thermal conductivity jump ? ?p at the crystal-liquid phase transition in CHCl3, C6H6, and CCl4. The contributions of the phonon-phonon and phonon-rotational interaction to the total thermal resistance in solid and liquid state are specified using a modified method of reduced coordinates. The decrease in the thermal conductivity at the crystal-liquid phase transition, ? ?p, is explained by a combined effect of variations in positional distribution of molecules and in the form of rotational molecular motion.

2009-04-01

346

The thermal conductivity jump at crystal-liquid phase transition in CHCl3, C6H6, and CCl4: the action of rotational molecular motion  

Science.gov (United States)

The thermal conductivity of liquid CHCl3, C6H6, and CCl4 is measured by a steady-state method under saturated vapor pressure in the temperature regions corresponding to pre-crystallization temperatures. The experimental results obtained are used to investigate the isobaric thermal conductivity jump ??p at the crystal-liquid phase transition in CHCl3, C6H6, and CCl4. The contributions of the phonon-phonon and phonon-rotational interaction to the total thermal resistance in solid and liquid state are specified using a modified method of reduced coordinates. The decrease in the thermal conductivity at the crystal-liquid phase transition, ??p, is explained by a combined effect of variations in positional distribution of molecules and in the form of rotational molecular motion.

2009-04-01

347

Process for treatment of detergent-containing radioactive liquid wastes  

Energy Technology Data Exchange (ETDEWEB)

A detergent-containing radioactive liquid waste originating from atomic power plants is concentrated to have about 10 wt. % detergent concentration, then dried in a thin film evaporator, and converted into powder. Powdered activated carbon is added to the radioactive waste in advance to prevent the liquid waste from foaming in the evaporator by the action of surface active agents contained in the detergent. The activated carbon is added in accordance with the COD concentration of the radioactive liquid waste to be treated, and usually at a concentration 2-4 times as large as the COD concentration of the liquid waste to be treated. A powdery product having a moisture content of not more than 15 wt. % is obtained from the evaporator, and pelletized and then packed into drums to be stored for a predetermined period.

1984-02-21

348

Process for treatment of detergent-containing radioactive liquid wastes  

International Nuclear Information System (INIS)

A detergent-containing radioactive liquid waste originating from atomic power plants is concentrated to have about 10 wt. % detergent concentration, then dried in a thin film evaporator, and converted into powder. Powdered activated carbon is added to the radioactive waste in advance to prevent the liquid waste from foaming in the evaporator by the action of surface active agents contained in the detergent. The activated carbon is added in accordance with the COD concentration of the radioactive liquid waste to be treated, and usually at a concentration 2-4 times as large as the COD concentration of the liquid waste to be treated. A powdery product having a moisture content of not more than 15 wt. % is obtained from the evaporator, and pelletized and then packed into drums to be stored for a predetermined period.

1984-02-01

349

Measurement of liquid nitrogen level by radiation  

Energy Technology Data Exchange (ETDEWEB)

The measurement of level in the liquid nitrogen vessel has been carried out by the weight conversion method using weigher or by putting directly a stick in the vessel. On a large CE tank, the pressure difference was read by manometer. These methods can not be used when the vessel does not put on the weigher or the pipe for manometer is stopped. We noticed the interaction between radiation ({gamma}-ray) and substance and applied it to determine the liquid nitrogen level. The results proved it the easy method for measurement of the level in the large CE tank. Cesium 137 ({gamma}-ray energy: 662 keV) was used as the radiation source. {gamma}-ray transmission dose was determined by GM survey meter. The liquid nitrogen level could be determined by using the change of the transmission dose with amount of liquid nitrogen. (S.Y.)

1995-07-01

350

Liquid level control system of fast reactor secondary cooling system  

International Nuclear Information System (INIS)

Object: To minimize the range of the liquid level variation of the cooling system and reduce the time required for the liquid level control by sealing the gas of a cover gas respiration system which acts upon an evaporator and pump overflow column. Structure: In liquid level control by the cover gas pressure of a high-speed reactor secondary cooling system, upon occurrence of a sudden change in the rate of flow of the recirculated liquid, automatic check valves provided in an evaporator and pump overflow column cover gas respiration system are completely or substantially closed, while at the same time the recirculation cooling medium is sucked up and an automatic check valve provided in the overflow system is closed. (Kamimura, M.).

351

Improvement on Liquid Radioactive Waste Treatment System of Nuclear Power Plant By Applying Ion Exchange Method  

International Nuclear Information System (INIS)

Liquid radioactive waste treatment method of using evaporator was widely used from Kori 1 to Uljin 3 and 4, but a liquid radioactive waste treatment equipment that uses an ion exchange method instead of an evaporator was adopted aiming to minimize amount of radioactive waste and radiation exposure. However, the same equipment was introduced and applied for the first time in Korea and had experienced difficulties in securing credibility for the equipment and handling of liquid radioactive waste with inadequate data about performance and experience in operation and maintenance. In this study, examination, application and effect analysis was performed on the optimization measure for handling liquid radioactive waste of Yonggwang Nuclear Power Unit 5 and 6(YGN 5 and 6) that applies an ion exchange method

2010-10-01

352

High-Throughput Screening of Drugs of Abuse in Urine by Supported Liquid?Liquid Extraction and UHPLC Coupled to Tandem MS  

British Library Electronic Table of Contents (United Kingdom)

A qualitative method, involving supported liquid?liquid extraction (SLE) and ultra high pressure liquid chromatography coupled to tandem mass spectrometry (UHPLC-MS?MS), was developed for the rapid tentative identification of various drugs of abuse in urine. In this study, 28 drugs and metabolites were covered by the screening procedure. Before analysis, urine samples were extracted by SLE and good extraction recoveries were obtained for most investigated compounds. The UHPLC strategy was then selected for the rapid separation of amphetamines, cocaine, opiates and related compounds in urine. Using columns packed with sub-2??m particles, analysis time was reduced down to 2?min, while maintaining acceptable performance. Finally, the detection was by tandem MS operating in the single reaction...

2009-01-01

353

Evaporation in forced convection of an Ostwaldian permanent laminar film flowing over an isothermal inclined plane surface; Evaporation en convection forcee d'un film liquide mince ostwaldien ruisselant en regime laminaire permanent sur une surface plane isotherme et inclinee  

Energy Technology Data Exchange (ETDEWEB)

The authors study, in forced convection, the evaporation of an Ostwaldian film flowing over an isothermal inclined plane surface to determine the influence of the behaviour index of the liquid on the dynamic and thermal characteristics of liquid-air system. The liquid flow is considered partially two-dimensional whereas for the air it is two-dimensional. The coupled equations with the interfacial conditions are solved using a fully implicit finite differences method. From the study, it appears that the behaviour index influences considerably the transfers which are more important for pseudo-plastic liquids than for dilatant ones. (authors)

2003-12-01

354

THE RECYCLING OF MIXTURES OF HEAVY METALS FROM WASTE USING ELECTRO- DEPOSITION  

Environmental Research Database

ObjectivesObjectives Not AvailableDescriptionWe will study the electrodeposition of metals from solutions containing a~%~ mixture of metal cations, in order to discover the conditions which lead to the separation of the metals. Measurements will be made both using small glass cells and using a more realistic size (10 cm x 10 cm electrodes) of electrodeposition cell.~%~

1996-01-31

355

THE APPLICATION OF STEEP PULSE CURRENTS TO THE ...  

Science.gov (United States)

... Title : THE APPLICATION OF STEEP PULSE CURRENTS TO THE ELECTROHYDRAULIC AND MAGNETIC FORMING OF METALS. ...

1966-04-01

360

Pure Scandium Production  

International Science & Technology Center (ISTC)

Development of the Technology to Obtain Pure Metal Scandium by Thermal Decomposition of Scandium Iodide

363

Pitting corrosion of metals: A review of the critical factors  

Energy Technology Data Exchange (ETDEWEB)

Pitting corrosion is localized accelerated dissolution of metal that occurs as a result of a breakdown of the otherwise protective passive film on the metal surface. This paper provides an overview of the critical factors influencing the pitting corrosion of metals. The phenomenology of pitting corrosion is discussed, including the effects of alloy composition, environment, potential, and temperature. A summary is then given of studies that have focused on various stages of the pitting process, including breakdown of the passive film, metastable pitting, and pit growth. 120 refs.

1998-06-01

366

Joined ceramic product  

Energy Technology Data Exchange (ETDEWEB)

According to the present invention, a joined product is at least two ceramic parts, specifically bi-element carbide parts with a bond joint therebetween, wherein the bond joint has a metal silicon phase. The bi-element carbide refers to compounds of MC, M.sub.2 C, M.sub.4 C and combinations thereof, where M is a first element and C is carbon. The metal silicon phase may be a metal silicon carbide ternary phase, or a metal silicide.

2001-01-01

373

Dioxins in the Baltic sea  

Wastenet

for municipal waste iron ore sinter plants incinerators for clinical waste facilities of the non-ferrous metal

376

Combined protection of metals by cathodic polarization and inhibitors  

Energy Technology Data Exchange (ETDEWEB)

A decrease of inhibitor concentration in a medium is always desirable even if the inhibitor is not toxic. In this connection, a sharp increase in the protective effect of certain corrosion inhibitors when cathodic polarization was applied to the metal is reviewed. The importance of a simultaneous account of the chemical structure of inhibitor and the nature of the metal corrosion under cathodic polarization is outlined. Some examples of applying this combined protection of metals are discussed.

1996-12-01

379

1993 - NASA  

Science.gov (United States)

... BUCKLING ANALYSIS OF METAL MATRIX COMPOSITE SANDWICH PANELS UNDER DIFFERENT THERMAL ENVIRONMENTS , Technical Memorandum ...

380

Technology for safe treatment of radioisotope organic wastes  

Energy Technology Data Exchange (ETDEWEB)

An examination of chemical and radiological characteristics of RI organic liquid waste, wet oxidation by Fenton reaction and decomposition liquid waste treatment process were studied. These items will be applied to develop the equipment of wet oxidation and decomposition liquid waste treatment mixed processes for the safe treatment of RI organic liquid waste which is consisted of organic solvents such as toluene, alcohol and acetone. Two types of toluene solutions were selected as a candidate decomposition material. As for the first type, the concentration of toluene was above 20 vol percent. As for the second type, the solubility of toluene was considered. The decomposition ration by Fenton reaction was above 95 percent for both of them. From the adsorption equilibrium tests, a -Na{sup +} substituted/acid treated activated carbon and Zeocarbon mixed adsorbent was selected for the fixed adsorption ...

1999-12-01

381

TPC magnet cryogenic system  

Energy Technology Data Exchange (ETDEWEB)

The Time Projection Chamber (TPC) magnet at LBL and its compensation solenoids are adiabatically stable superconducting solenoid magnets. The cryogenic system developed for the TPC magnet is discussed. This system uses forced two-phase tubular cooling with the two cryogens in the system. The liquid helium and liquid nitrogen are delivered through the cooled load by forced tubular flow. The only reservoirs of liquid cryogen exist in the control dewar (for liquid helium) and the conditioner dewar (for liquid nitrogen). The operation o these systems during virtually all phases of system operation are described. Photographs and diagrams of various system components are shown, and cryogenic system data are presented in the following sections: (1) heat leaks into the TPC coil package and the compensation solenoids; (2) heat leaks to various components of the TPC magnet cryogenics system ...

1980-03-01

382

Purification of radioactive decontamination liquids from NPP Paks with reactive adsorption and ion-exchange process  

International Nuclear Information System (INIS)

In nuclear power plant Paks, Hungary, alkaline oxidative (NaOH, KMnO_4, H_2O) and acidic reductive (citric- and oxalic acid, water) liquids are using for the decontamination of primary circuit equipment (main liquid circulating pumps, steam generators, pipelines etc). The above mentioned decontamination liquids are containing "1"1"0"mAg, "9"5Nb, "5"4Mn, "5"8 Co, "6"0Co, "5"1 Cr, "1"2"4 Sb radioisotopes, summarized radioactivity is between 10"3-8x10"4 kBq/dm"3 liquid. The decontamination liquid can be cleaned with reactive adsorption (active carbon) and ion-exchange process at elevated temperature (333-368 K) in multilayered columns. After purification the summarized radioactivity for "5"4Mn, "6"0Co, and "1"1"0"mAg are in the outlet liquid below 1 kBq/dm"3. Decontamination factor DF#approx =#10"3-10"4, volumetric reduction factor VRF#approx =#50-500.

1999-11-04

383

Separation of magnesium from magnesium chloride and zirconium and/or hafnium subchlorides in the production of zirconium and/or hafnium sponge metal  

International Nuclear Information System (INIS)

This patent describes the producing of a refractory metal wherein a sponge refractory metal is produced as an intermediate product by the use of magnesium with the incidental production of magnesium chloride, and wherein residual magnesium is separated from the magnesium chloride and from refractory metal to a vacuum distillation step which fractionally distills the magnesium, the magnesium chloride, and the metal sub-chlorides; the steps of: recovering fractionally distilled vapors of magnesium chloride and metal sub-chlorides from a sponge refractory metal; separately condensing the vapors as separately recovered; and recycling the separately recovered magnesium at a purity of at least about 96%.

1990-09-21

384

Fractionation of isotopes of alkali metals and alkaline earth metals in ion exchange chromatography  

International Nuclear Information System (INIS)

Fractionation of isotopes of the alkali metals and the alkaline earth metals in ion exchange chromatography of their chlorides was studied. The heavier isotopes of potassium and rubidium were found to be preferentially fractionated into the ion exchanger phase while the lighter isotopes of lithium, magnesium, calcium and strontium were enriched in the exchanger phase. This can be interpreted as a resultant of the relative significance of isotope effect upon dehydration and isotope effect accompanying the phase change of the hydrated metal ion. Found was no evidence of anomalous isotope effect attributable to the odd-even difference in mass number of isotopes. Based on the spectroscopic and solution chemical data (experimental and theoretical), the isotopic reduced partition function ratios of the hydrated alkaline metal ions and stretching force constants of metal ion-hydrating ...

385

Filler metal development for Hastelloy alloy XR. Filler metal for hastelloy alloy XR structure with thick wall  

Energy Technology Data Exchange (ETDEWEB)

In order to develop the filler metal for Hastelloy alloy XR structure with thick wall, the weldability and high temperature strength properties of Hastelloy alloy XR weldment were investigated using the filler metals, which were alloy-designed on the basis of multiple regression analysis. The former was examined through the chemical analysis in the deposited metal, bend test, FISCO cracking test, optical microscopy and hardness measurement. The latter was investigated by means of tensile and creep test. It was found from these results that the crack susceptibility in the weldment was apparent to be lowered without degrading the high temperature strength properties. Therefore, it is concluded that these filler metals possess excellent performance as the filler metal for Hastelloy alloy XR structure with thick wall. (author).

1991-11-01

386

Enhanced catalytic activity of Fe bimetallic modified PAN fiber complexes prepared with different assisted metal ions for degradation of organic dye  

British Library Electronic Table of Contents (United Kingdom)

Two transition metal ions (Cu^2^+ and Co^2^+) and two rare earth metal ions (Ce^3^+ and La^3^+) were used as the assisted metal ions, respectively to prepare the transition metal and rare metal assisted Fe bimetallic amidoximated polyacrylonitrile (AO-PAN) fiber complexes. And their coordination configuration and visible light adsorption properties were examined by coordination number determination and UV-vis-DRS. Then the catalytic performance of these complexes was evaluated as the heterogeneous Fenton catalysts in Rhodamine B degradation by changing the nature and dosage of the assisted ions added. The results indicated that the incorporation of the assisted metal ions led to Fe bimetallic AO-PAN complexes with the more unsaturated configurations than Fe monometallic AO-PAN complex due ...

2011-01-01

387

Effect of metal selection and porcelain firing on the marginal accuracy of titanium-based metal ceramic restorations  

British Library Electronic Table of Contents (United Kingdom)

Statement of problem Titanium is the most biocompatible metal used for dental casting; however, there is concern about its marginal accuracy after porcelain application since this aspect has direct influence on marginal fit. Purpose The purpose of this study was to determine the effect that metal selection and the porcelain firing procedure have on the marginal accuracy of metal ceramic prostheses. Material and methods Cast CP Ti, milled CP Ti, cast Ti-6Al-7Nb, and cast Ni-Cr copings (n=5) were fired with compatible porcelains (Triceram for titanium-based metals and VITA VMK 95 for Ni-Cr alloy). The Ni-Cr alloy fired with its porcelain served as the control. Photographs of metal copings placed on a master die were made. Marginal discrepancy was determined on the photographs using an image ...

2010-01-01

388

Color change during the surface preparation stages of metal ceramic alloys  

British Library Electronic Table of Contents (United Kingdom)

Statement of problem Even though metal ceramic restorations (MCRs) are widely used by clinicians, the influence of the metal on the color of overlaying porcelain is unknown. Purpose The purpose of this study was to analyze the color alterations of different types of metal ceramic alloys during several stages of metal surface preparation and to determine the effect of those changes on the resulting color of opaque porcelain (OP). Material and Methods Seven different types of alloys (3 base metal, 3 noble, and 1 high noble) were used to prepare disk-shaped specimens (1 mm x 10 mm, n=3), followed by OP application (0.1 mm). Lab values of specimens were recorded after different stages of metal surface preparation (ingot, after casting, after oxidation, and after the OP application) in addition...

2011-01-01

389

Trace metal concentrations in estuaries and coastal regions  

Energy Technology Data Exchange (ETDEWEB)

Estuaries and coastal regions are highly variable in the physical and hydrographic conditions. As a result of heavy urbanization and industrialization of the head waters of most estuaries, there are substantial localized inputs of contaminants to the estuary. These factors combined with the flushing characteristics of individual estuaries to create relatively unique features that result in variation in the typical levels of trace metals for these systems. This makes intercomparison of the estuaries difficult. Comparability among estuaries becomes even more difficult when metals analyses are conducted without proper control of field and laboratory contamination, now firmly established in the trace metal analytical literature as a prerequisite for reliable marine trace metals analysis. This paper compares the concentrations of selected trace metal (Ag, Cd, Cu, Ni, Pb, and Zn) ...

1994-12-31

390

Sodium to sodium carbonate conversion process  

Energy Technology Data Exchange (ETDEWEB)

A method is described for converting radioactive alkali metal into a low level disposable solid waste material. The radioactive alkali metal is atomized and introduced into an aqueous caustic solution having caustic present in the range of from about 20 wt % to about 70 wt % to convert the radioactive alkali metal to a radioactive alkali metal hydroxide. The aqueous caustic containing radioactive alkali metal hydroxide and CO{sub 2} are introduced into a thin film evaporator with the CO{sub 2} present in an amount greater than required to convert the alkali metal hydroxide to a radioactive alkali metal carbonate, and thereafter the radioactive alkali metal carbonate is separated from the thin film evaporator as a dry powder. Hydroxide solutions containing toxic metal hydroxide including one or more ...

1997-10-14

391

Hydrous oxide activated charcoal  

Energy Technology Data Exchange (ETDEWEB)

This patent describes a process for preparing of an ion exchanger, comprising: treating an ionically inert activated charcoal porous support with an aqueous solution of metal oxychloride selected from the group consisting of zirconium and titanium oxychlorides so as to impregnate the pores of the support with the solution; separating the treated support from excess metal oxychloride solution; converting the metal oxychloride to a hydrous metal oxide precipitate in the pores of the support at a pH above 8 and above the pH whereat the hydrous metal oxide and activated charcoal support have opposite zeta potentials and sufficient to hydrolyze the metal oxychloride. It also describes a process for preparing an ion exchanger comprising: treating granulated activated charcoal with a concentrated solution of a metal oxychloride from the group ...

1987-09-08

392

Exploring multi-metal biosorption by indigenous metal-hyperresistant Enterobacter sp. J1 using experimental design methodologies  

Energy Technology Data Exchange (ETDEWEB)

A novel experimental design, combining mixture design and response surface methodology (RSM), was developed to investigate the competitive adsorption behavior of lead, copper and cadmium by an indigenous isolate Enterobacter sp. J1 able to tolerate high concentrations of a variety of heavy metals. Using the proposed combinative experimental design, two different experiment designs in a ternary metal biosorption system can be integrated to a succinct experiment and the number of experimental trials was markedly reduced from 38 to 26 by reusing the mutual experimental data. Triangular contour diagrams and triangular three-dimensional surface plots were generated to describe the ternary metal biosorption equilibrium data in mixture design systems. The results show that the preference of metal sorption of Enterobacter sp. J1 decreased in the order of Pb{sup 2+} > Cu{sup 2+} > Cd{sup 2+}. The ...

2008-05-01

393

Effects of a chelating resin on metal bioavailability and toxicity to estuarine invertebrates: Divergent results of field and laboratory tests  

International Nuclear Information System (INIS)

Benthic invertebrates can uptake metals through diffusion of free ion solutes, or ingestion of sediment-bound forms. This study investigated the efficacy of the metal chelating resin SIR 300TM in adsorbing porewater metals and isolating pathways of metal exposure. A field experiment (Botany Bay, Sydney, Australia) and a laboratory toxicity test each manipulated the availability of porewater metals within contaminated and uncontaminated sediments. It was predicted that within contaminated sediments, the resin would adsorb porewater metals and reduce toxicity to invertebrates, but in uncontaminated sediments, the resin would not significantly affect these variables. Whereas in the laboratory, the resin produced the predicted results, in the field the resin increased porewater metal concentrations of contaminated sediments for at least 34 days ...

2010-05-01

394

Detritiation of solid waste using superheated steam  

International Nuclear Information System (INIS)

Full text: During JET operations, tritium contaminated waste is generated principally but not exclusively from 'intervention' work and from removing or replacing redundant items. It is essential for JET and for any future fusion plant to have available a route for managing each waste stream however large or small, both during operation and decommissioning of the plant. The long term outcome is to have for each tritiated waste stream from JET a route for its management leading to its eventual disposal or recycling (and thus to be available for similar waste streams which will be produced by ITER operations). Since several years SCK#centre dot#CEN has been developing techniques for the treatment of tritiated waste. Amongst them, technologies for water detritiation, for the treatment of tritiated organic liquids and for the decontamination of several types of solid tritiated waste. Our R and D focuses on the development of a system to decontaminate surface ...

2005-10-12

395

Analytical methods for heavy metals in herbal medicines  

British Library Electronic Table of Contents (United Kingdom)

Abstract Introduction - It is estimated that about 70-80% of the world's population relies on non-conventional medicine, mainly of herbal origin. However, owing to the nature and sources of herbal medicines, they are sometimes contaminated with toxic heavy metals such as lead, arsenic, mercury and cadmium, which impose serious health risks to consumers. It is critical to analyse source materials for heavy metals in order to ensure that their concentrations meet the related standards or regulations limiting their concentrations in herbal medicines. In this review, different analytical methods for analysis of heavy metals in herbal medicines are discussed. Objective - To provide a comprehensive review of the current state of the art in analytical methods used to detect heavy metals in herbal...

2011-01-01

396

Sulfur behavior in chemical looping combustion with NiO/Al{sub 2}O{sub 3} oxygen carrier  

Energy Technology Data Exchange (ETDEWEB)

Chemical looping combustion (CLC) is a novel technology where CO{sub 2} is inherently separated during combustion. Due to the existence of sulfur contaminants in the fossil fuels, the gaseous products of sulfur species and the interaction of sulfur contaminants with oxygen carrier are a big concern in the CLC practice. The reactivity of NiO/Al{sub 2}O{sub 3} oxygen carrier reduction with a gas mixture of CO/H{sub 2} and H{sub 2}S is investigated by means of a thermogravimetric analyzer (TGA) and Fourier Transform Infrared spectrum analyzer in this study. An X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and scanning electron microscope (SEM) are used to evaluate the phase characterization of reacted oxygen carrier, and the formation mechanisms of the gaseous products of sulfur species are elucidated in the process of chemical looping combustion with a gaseous fuel containing hydrogen sulfide. The results show that the rate of NiO reduction with H{sub 2}S is higher than ...

2010-05-15

397

Characterisation of thin films on rough steel substrates by FTIR microscopy and imaging  

International Nuclear Information System (INIS)

Complete text of publication follows. According to the new European regulations (Restrictions of Hazardous Substance Directive), there is an emerging demand for environmental friendly metal treatments instead on formerly used chromate conversion coating technique. The aim of the present investigations was to characterise and compare silicon containing protective thin layers on roughened galvanized steel surfaces (with average roughness of 0.7 microns), using FTIR microscopy and imaging techniques. The silicon containing coatings were produced either by Chemical Vapour Deposition (CVD) or by wet chemical treatment using liquid silane. FTIR techniques offer new possibilities in the characterisations and chemical mapping of differently coated thin films, besides SEM+EDS, AFM, nanoindentation, XPS measurements (P. Nemeth et al., Materials Science Forum, 589 (2008) 433-438). All measurements were carried out by a Varian FTS-7000 spectrometer with a ...

398

Dynamic response of a liquid-vapor interface during flow film boiling from a sphere  

Energy Technology Data Exchange (ETDEWEB)

Film boiling is the mode if boiling during which the hot surface is separated from the vaporizing liquid by a nearly continuous film vapor. Film boiling is usually considered a very undesirable boiling regime since it is a relatively quiet and inefficient mode of heat transfer, particularly as compared to nucleate boiling. It is customary to analyze the two-phase flow regime of laminar flow film boiling by assuming the two-phase flow regime of laminar flow film boiling by assuming an idealized vapor film flow characterized by a smooth liquid-vapor interface. However, during stable flow film boiling, the wavy nature of the liquid-vapor interface and its role in local heat and mass transport have been largely ignored. The vapor interface is rarely stationary. Interfacial waves may substantially augment the heat transfer rates throughout the layer. The present analysis treats stagnation point flow film boiling on a sphere ...

1987-11-01

399

Survey for Transiting Extrasolar Planets in Stellar Systems. II. Spectrophotometry and Metallicities of Open Clusters  

CERN Document Server

We present metallicity estimates for seven open clusters based on spectrophotometric indices from moderate-resolution spectroscopy. Observations of field giants of known metallicity provide a correlation between the spectroscopic indices and the metallicity of open cluster giants. We use \\chi^2 analysis to fit the relation of spectrophotometric indices to metallicity in field giants. The resulting function allows an estimate of the target-cluster giants' metallicities with an error in the method of \\pm0.08 dex. We derive the following metallicities for the seven open clusters: NGC 1245, [m/H]=-0.14\\pm0.04; NGC 2099, [m/H]=+0.05\\pm0.05; NGC 2324, [m/H]=-0.06\\pm0.04; NGC 2539, [m/H]=-0.04\\pm0.03; NGC 2682 (M67), [m/H]=-0.05\\pm0.02; NGC 6705, [m/H]=+0.14\\pm0.08; NGC 6819, [m/H]=-0.07\\pm0.12. These metallicity estimates will be useful ...

2005-01-01

400

Sequential extraction of heavy metals in river sediments of an abandoned pyrite mining area: pollution detection and affinity series  

Energy Technology Data Exchange (ETDEWEB)

In this paper heavy metal pollution at an abandoned Italian pyrite mine has been investigated by comparing total concentrations and speciation of heavy metals (Fe, Cu, Mn, Zn, Pb and As) in a red mud sample and a river sediment. Acid digestions show that all the investigated heavy metals present larger concentrations in the sediment than in the tailing. A modified Tessier's procedure has been used to discriminate heavy metal bound to organic fraction from those originally present in the mineral sulphide matrix and to detect a possible trend of metal mobilisation from red mud to river sediment. Sequential extractions on bulk and size fractionated samples denote that sediment samples present larger percent concentrations of the investigated heavy metals in the first extractive steps (I-IV) especially in lower dimension size fractionated samples suggesting ...

2004-11-01

401

Sequential extraction of heavy metals in river sediments of an abandoned pyrite mining area: pollution detection and affinity series  

International Nuclear Information System (INIS)

In this paper heavy metal pollution at an abandoned Italian pyrite mine has been investigated by comparing total concentrations and speciation of heavy metals (Fe, Cu, Mn, Zn, Pb and As) in a red mud sample and a river sediment. Acid digestions show that all the investigated heavy metals present larger concentrations in the sediment than in the tailing. A modified Tessier's procedure has been used to discriminate heavy metal bound to organic fraction from those originally present in the mineral sulphide matrix and to detect a possible trend of metal mobilisation from red mud to river sediment. Sequential extractions on bulk and size fractionated samples denote that sediment samples present larger percent concentrations of the investigated heavy metals in the first extractive steps (I-IV) especially in lower dimension size fractionated samples suggesting that ...

2004-11-01

402

Heavy metals in Semarang`s urban streams: Spatial distribution and bioindication using the guppy (Lepistes reticulatus)  

Energy Technology Data Exchange (ETDEWEB)

A field survey on cadmium, lead, copper, and zinc was performed in Semarang, the fifth largest city in Indonesia. Water, sediment, and fish samples were collected from 101 grids of 2 x 2 km. The objectives of the study were (1) to identify the spatial distribution of metals in the sediments of the greater Semarang area, (2) to estimate the background concentrations of the metals present in Semarang, (3) to provide a simple tool for deriving standards for metals in the sediment, and (4) to explore the potential use of the guppy (Lebistes reticulatus) as a bioindicator of urban metal pollution. To map the spatial distribution of the metals, concentrations of each metal in sediment were plotted against the corresponding city coordinate. On the basis of these plots, background concentrations of the metals were estimated. A combined pollution ...

1996-12-31

403

Biomimetic metal-sorbing vesicles for continuous extraction of heavy metal ions from dilute solution  

Energy Technology Data Exchange (ETDEWEB)

Biomimetic vesicle media which can selectivity extract and concentrate heavy metals (e.g., Pb{sup 2+}) from dilute solutions of 5 ppm and less have been prepared. At a concentration of only 1% 2/v, these non-covalently assembled, unilamellar, surfactant vesicles provide approximately 1,000m{sup 2} of exposed membrane surface area per liter of suspension which gives rise to very rapid rates of metal ion extraction. To facilitate the selective transport of heavy metal ions through the ion impermeable vesicle wall, the vesicles are doped with lipophilic ionophores, both natural and synthetic. In addition, the metal chelating agent, nitrolotriacetate, is encapsulated in the aqueous vesicle core to provide the driving force for metal ion uptake and concentration. Concentration factors in excess of 1000 fold have been observed. Metal-sorbing surfactant vesicles ...

1993-12-31

404

Apoferritin Templated Synthesis of Metal Phosphate Nanoparticle Labels for Electrochemical Immunoassay  

Energy Technology Data Exchange (ETDEWEB)

W have introduced template-synthesized metal phosphate nanoparticle labels for electrochemical immunoassay. Such use of an apoferritin template offers a simple and convenient route to prepare metallic nanoparticle labels for electrochemical immunoassays and avoid the complicated and time-consuming nanoparticle synthesis process (QD synthesis). Releasing metal ions from metal phosphate in an acetate buffer (pH 4.6) eliminates the harsh condition in the traditional metallic nanoparticle dissolution (e.g., strong acid dissolution of QDs and gold nanoparticles). This method is ultrasensitive and its DL is low to 77fM. The simultaneous detection of multiple protein targets is easily performed by using different metal phosphate nanoparticle labels (cadmium phosphate and lead phosphate). This approach can be extended to prepare multiple metal (such ...

2006-08-29

405

Impact characteristic analysis of ceramic/metal FGM  

Energy Technology Data Exchange (ETDEWEB)

The ceramic composite armor has been lucubrated in the past 40 years. Ceramic can provide the same protection as metal, but it has lighter weight than metal. Ceramic has excellent ability of resisting kinetic energy projectile, because it can transfer energy to a large range by its fragmented cone and has higher ability of eroding the projectile than metal. But the researches indicated the full potential of the ceramic hard face has not been achieved because the significant interface between ceramic and metal has the unfavorable impedance effects and would induce tensile failure. FGM is a new type composite with continuous transition from ceramic to metal; it has no significant discrete materials interfaces between ceramic and metal. This paper deals with the impact response of Ceramic/FGM/Metal armor by numerical and theoretical methods. ...

2003-07-01

406

Study of structural, thermodynamical and dynamical properties of molecular liquids confined in nano-porous materials  

International Nuclear Information System (INIS)

When liquids are confined in nano-scopic dimensions, their properties differ from the corresponding bulk liquid, due to their reduced dimensionality and surface effects. Phase transition temperatures and pressures are often shifted from the bulk values and new phases can appear due to the strong interactions of the molecules with the confining walls. We have studied the structural and dynamical properties of aromatic liquids such as benzene, toluene, and ortho-terphenyl confined in nano-porous materials, MCM-41 and SBA-15, synthesized and characterized in our laboratory. A non-trivial dependence of the glass transition temperature, Tg, on the pore size and surface treatment of nano-porous materials is confirmed and interpreted as resulting from a competition between the fluid-wall and fluid-fluid intermolecular interactions. An increase of Tg is observed for small pore sizes and attractive surface while Tg decreases for non ...

2006-01-01

407

Method for controlling the liquid level of a steam generator for a sodium-cooled fast breeder reactor  

International Nuclear Information System (INIS)

Object: To control the average liquid level of each steam generator at a constant level irrespective of the flow rate of sodium thereby to decrease change in the retained amount of sodium and at the same time to improve the load response characteristic. Construction: A method for decreasing to as large an extent as possible a change in the amount of sodium retained in a steam generator due to change in the flow rate, which comprises the steps of detecting the main recirculating flow rate of liquid sodium by the use of a sodium flow rate detector, amplifying the detected flow rate signal depending upon the ratio between the flow rates respectively in a super-heater and a re-heater (distribution ratio), delivering the amplified signal to a function generator which generates a liquid level setting signal for maintaining the respective average liquid levels of the super-heater and the re-heater at constant ...

408

Horizontal liquid film mist two-phase flow, 2. Droplet deposition and entrainment rates  

Energy Technology Data Exchange (ETDEWEB)

In the region of annular liquid film-mist flow, the behavior of the droplets formed from the liquid film and the rate of formation are the subjects to be clarified in connection with the forecast of dry-out point, which becomes a problem in the region of high dryness such as reactor cooling system and steam generators. Many researches have been performed on such problem in vertical tubes, but the characteristics in horizontal flow have not yet been sufficiently clarified. This series of research is to clarify various characteristics, such as the velocity of vapor phase, the flow rate distribution of droplets, the formation and adhesion of droplets and the structure of liquid film, in the region of liquid film-mist flow, where liquid film exists on the bottom of a horizontal rectangular channel, and vapor flow is accompanied by droplets. In this study, by the measurement of the flow ...

1984-06-01

409

Horizontal liquid film mist two-phase flow, 2  

International Nuclear Information System (INIS)

In the region of annular liquid film-mist flow, the behavior of the droplets formed from the liquid film and the rate of formation are the subjects to be clarified in connection with the forecast of dry-out point, which becomes a problem in the region of high dryness such as reactor cooling system and steam generators. Many researches have been performed on such problem in vertical tubes, but the characteristics in horizontal flow have not yet been sufficiently clarified. This series of research is to clarify various characteristics, such as the velocity of vapor phase, the flow rate distribution of droplets, the formation and adhesion of droplets and the structure of liquid film, in the region of liquid film-mist flow, where liquid film exists on the bottom of a horizontal rectangular channel, and vapor flow is accompanied by droplets. In this study, by the measurement of the flow ...

1984-01-01

410

G3 model of gas and liquid migration from grout containing radioactive waste  

Energy Technology Data Exchange (ETDEWEB)

Grout has been evaluated as a means of containing low-level radioactive waste for long-term disposal. Concerns about hydrogen and reactive gas generation in the Hanford Site grout disposal facility lead to the development of the G3 model, which has predicted buildup of radiolytically formed gases in the grout region and their migration to air-filled regions. The G3 model is a one-dimensional code that couples models of gas diffusion with two-phase gas and liquid flow. It was coupled to a compartment diffusion model and these models predicted the concentrations of hydrogen I nitrous oxide, and other gases in air-filled regions of the grout disposal facility. The results have served as the technical basis for safety studies. A unique finding of the G3 model was that a liquid return, or expulsion of unbound liquid from the grout region, could occur. This liquid return is driven by displacement caused by ...

1994-11-01

411

Elastic Properties of Nematic Liquid Crystals Formed by Living and Migrating Cells  

CERN Document Server

In culture migrating and interacting amoeboid cells can form nematic liquid crystal phases. A polar nematic liquid crystal is formed if the interaction has a polar symmetry. One type of white blood cells (granulocytes) form clusters where the cells are oriented towards the center. The core of such an orientational defect (disclination) is either a granulocyte forced to be in an isotropic state or another cell type like a monocyte. An apolar nematic liquid crystal is formed if the interaction has an apolar symmetry. Different cell types like human melanocytes (=pigment cells of the skin), human fibroblasts (=connective tissue cells), human osteoblasts (=bone cells), human adipocytes (= fat cells) etc., form an apolar nematic liquid crystal. The orientational elastic energy is derived and the orientational defects (disclination) of nematic liquid crystals are investigated. The ...

1998-01-01

412

Ultraviolet detectors based on ZnO films by thermal oxidation of Zn metallic films  

British Library Electronic Table of Contents (United Kingdom)

Metallic Zn films were deposited on glass substrates by electron-beam evaporation. ZnO films were synthesized by thermal oxidation of Zn metallic films in air. At the annealing temperature of 550 ?C, ZnO nanowires appeared on the surface, which mainly result from the decrease of oxidation rate. A ZnO ultraviolet photodetector was fabricated based on a metal-semiconductor-metal planar structure. The detector showed a large UV photoresponse with an increase of two orders of magnitude. It is concluded that promising UV detectors can be obtained on ZnO films by thermal oxidation of Zn metallic films. The ways of performing spectral response measurements for polycrystalline ZnO films are also discussed.

2008-01-01

413

Structures and properties of functional metal iodates  

British Library Electronic Table of Contents (United Kingdom)

Metal iodates with a lone-pair containing I(V) that is in an asymmetric coordination geometry can form a diversity of unusual structures and many of them are promising new second homonic generation (SHG) materials. They exhibit wide transparency wavelength regions, large SHG coefficients and high optical-damage thresholds as well as moderately high thermal stability. In this paper, the structures and properties of the metal iodates are reviewed. The combination of d0 transition-metal cations with the iodate groups afforded a large number of metal iodates, with cations covering alkali metal, alkaline earth and lanthanide elements. Many of them are noncentrosymmetric (NCS) and display excellent SHG properties due to the additive effects of polarizations from both types of the asymmetric unit...

2011-01-01

414

Relationship between the lability of sediment-bound metals (Cd, Cu, Zn) and their bioaccumulation in benthic invertebrates  

British Library Electronic Table of Contents (United Kingdom)

The present study has investigated metal contamination at nine sites (10 sampling stations) from the English Channel to the Mediterranean Sea, including low level and highly contaminated sediments. Both total and labile concentrations of metals were determined in superficial sediments. The influence of different pHs was tested and metal lability at pHs encountered in the gut of invertebrates (the ragworm Nereis diversicolor, the blue mussel Mytilus edulis, the Japanese oyster Crassostrea gigas) was compared with the distribution of metals in various operationally defined geochemical fractions. Cd showed the highest lability and Cu the lowest, whereas Zn lability was intermediate. Metal concentrations were determined in bivalves at six sites and in worms at three sites. Cd in living organis...

2007-01-01

415

Long-distance transport, vacuolar sequestration, tolerance, and transcriptional responses induced by cadmium and arsenic  

British Library Electronic Table of Contents (United Kingdom)

Iron, zinc, copper and manganese are essential metals for cellular enzyme functions while cadmium, mercury and the metalloid arsenic lack any biological function. Both, essential metals, at high concentrations, and non-essential metals and metalloids are extremely reactive and toxic. Therefore, plants have acquired specialized mechanisms to sense, transport and maintain essential metals within physiological concentrations and to detoxify non-essential metals and metalloids. This review focuses on the recent identification of transporters that sequester cadmium and arsenic in vacuoles and the mechanisms mediating the partitioning of these metal(loid)s between roots and shoots. We further discuss recent models of phloem-mediated long-distance transport, seed accumulation of Cd and As and rec...

2011-01-01

416

A metal matrix for heat transfer enhancement during phase-change processes  

Energy Technology Data Exchange (ETDEWEB)

A metal matrix is inserted into a phase-change material to enhance the heat transfer during phase-change processes. The metal matrix tends to act like a heat transfer fin from the heated or cooled surface and to increase the effective thermal conductivity of the phase-change fluid. The scope of the study involves numerically modeling the heat transfer to and from constant-temperature cylindrical tubes surrounded by water during the freezing and melting processes. Comparisons of heat transfer with and without the metal matrix are made, with different porosities and densities of the metal matrix being examined. The results of this study are discussed in terms of the effectiveness of the metal matrix as a heat transfer enhancement device.

1994-12-31

417

The Bevatron liquid nitrogen circulation system  

Science.gov (United States)

A nitrogen liquefier and computer controlled valving system have been added to the Bevatron cryoliner vacuum system to cut operating costs by reducing liquid nitrogen consumption. The computer and interface electronic systems, which control the temperatures of twenty-eight liquid nitrogen circuits, have been chosen and designed to operate in the Bevatron's pulsating magnetic field. The nitrogen exhaust is routed back to a liquefier, of about five kilowatt capacity, liquefied, and rerouted through the cooling circuits. A description of the system and operating results are presented.

1987-03-01

418

Striped instability of a holographic Fermi-like liquid  

CERN Document Server

We consider a holographic description of a system of strongly-coupled fermions in 2+1 dimensions based on a D7-brane probe in the background of D3-branes. The black hole embedding represents a Fermi-like liquid. We study the excitations of the Fermi liquid system. Above a critical density which depends on the temperature, the system becomes unstable towards an inhomogeneous modulated phase which is similar to a charge density and spin wave state. The essence of this instability can be effectively described by a Maxwell-axion theory with a background electric field. We also consider the fate of zero sound at non-zero temperature.

2011-01-01

419

New coal liquids R D to begin  

Energy Technology Data Exchange (ETDEWEB)

The US DOE is calling on the nations' industries and academic institutions to develop a new approach for converting coal into liquid fuels at costs that can be competitive with imported oil. Based on a number of innovations, the department is looking for new approaches that can substantially reduce the cost of liquids from coal, essentially capping the price of imported oil. If successful, the new process will define the next generation of coal liquefaction technology and represent a dramatic improvement over the current state-of-the-art integrated two-stage process. 1 fig.

1989-12-01

420

Modeling of (vapor + liquid) equilibrium and enthalpy of solution of carbon dioxide (CO{sub 2}) in aqueous methyldiethanolamine (MDEA) solutions  

Energy Technology Data Exchange (ETDEWEB)

A thermodynamic model was used to estimate enthalpy of solution of carbon dioxide (CO{sub 2}) in methyldiethanolamine (MDEA) aqueous solutions. The model was based on a set of equations for chemical equilibria, phase equilibria, charge, and mass balances. Non-ideality in the liquid phase was taken into account by interaction parameters fitted to (vapor + liquid) equilibrium data. The enthalpies of solution of CO{sub 2} were derived from the model using classical thermodynamic relations and were compared to experimental values obtained in previous works.

2009-06-15

421

Modeling of (vapor + liquid) equilibrium and enthalpy of solution of carbon dioxide (CO_2) in aqueous methyldiethanolamine (MDEA) solutions  

International Nuclear Information System (INIS)

A thermodynamic model was used to estimate enthalpy of solution of carbon dioxide (CO_2) in methyldiethanolamine (MDEA) aqueous solutions. The model was based on a set of equations for chemical equilibria, phase equilibria, charge, and mass balances. Non-ideality in the liquid phase was taken into account by interaction parameters fitted to (vapor + liquid) equilibrium data. The enthalpies of solution of CO_2 were derived from the model using classical thermodynamic relations and were compared to experimental values obtained in previous works.

2009-06-01

422

Microwave heating type evaporator  

Energy Technology Data Exchange (ETDEWEB)

Purpose: To prevent evaporization stills against corrosion due to radioactive liquid wastes. Constitution: Microwaves are supplied from a microwave generator by way of a wave guide tube and through a microwave permeation window to the inside of an evaporatization still. A matching device is attached to the wave guide tube for transmitting the microwaves in order to match the impedance. When the microwaves are supplied to the inside of the evaporization still, radioactive liquid wastes supplied from a liquid feed port by way of a spray tower to the inside of the evaporization still is heated and evaporated by the induction heating of the microwaves. (Seki, T.).

1987-01-22

423

Liquid crystal defects and confinement in Yang-Mills theory  

CERN Document Server

We show that in the Landau gauge of the SU(2) Yang-Mills theory the residual global symmetry supports existence of the topological vortices which resemble disclination defects in the nematic liquid crystals and the Alice (half-quantum) vortices in the superfluid heluim 3 in the A-phase. The theory also possesses half-integer and integer charged monopoles which are analogous to the point-like defects in the nematic crystal and in the liquid helium. We argue that the deconfinement phase transition in the Yang-Mills theory in the Landau gauge is associated with the proliferation of these vortices and/or monopoles. The disorder caused by these defects is suggested to be responsible for the confinement of quarks in the low-temperature phase.

2005-01-01

424

Heat storage composition  

Energy Technology Data Exchange (ETDEWEB)

A heat storage compostion comprises sodium sulfate decahydrate as main component, a supercooling inhibitor, and a solid-liquid separation inhibitor. The composition is characterized in that hydraulic calcium sulfate and/or calcium sulfate dihydrate is contained as the solid-liquid separation inhibitor in an amount of 2-15 wt% base on the whole weight of the composition, whereby the solid-liquid separation, i.e. the sedimentation of the anhydrous sodium sulfate during the phase transition, is effectively prevented and the long-term stability is improved. The long-term stabilty of the composition can be more improved by addition of a silcia series of thickener.

1987-05-05

425

Evaluation of wastewater treatment requirements for thermochemical biomass liquefaction  

Science.gov (United States)

Biomass can provide a substantial energy source. Liquids are preferred for use as transportation fuels because of their high energy density and handling ease and safety. Liquid fuel production from biomass can be accomplished by any of several different processes including hydrolysis and fermentation of the carbohydrates to alcohol fuels, thermal gasification and synthesis of alcohol or hydrocarbon fuels, direct extraction of biologically produced hydrocarbons such as seed oils or algae lipids, or direct thermochemical conversion of the biomass to liquids and catalytic upgrading to hydrocarbon fuels. This report discusses direct thermochemical conversion to achieve biomass liquefaction and the requirements for wastewater treatment inherent in such processing. 21 refs.

1992-04-01

426

ENGINEERING DEVELOPMENT OF CERAMIC MEMBRANE REACTOR SYSTEM FOR CONVERTING NATURAL GAS TO HYDROGEN AND SYNTHESIS GAS FOR LIQUID TRANSPORTATION FUELS  

Energy Technology Data Exchange (ETDEWEB)

The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through February 1999.

1999-03-01

427

ENGINEERING DEVELOPMENT OF CERAMIC MEMBRANE REACTOR SYSTEM FOR CONVERTING NATURAL GAS TO HYDROGEN AND SYNTHESIS GAS FOR LIQUID TRANSPORTATION FUELS  

Energy Technology Data Exchange (ETDEWEB)

The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through September 1999.

1999-10-01

428

Catalytic effect on the hydrogenolysis reactions of a mixture of coal liquid and deashed liquefaction residue  

Energy Technology Data Exchange (ETDEWEB)

Hydrogenolysis reactions of a mixture of coal liquid and coal liquefaction residue were carried out using red mud - sulfur or Co-Mo/Al{sub 2}O{sub 3} catalyst. The effect of deashing treatment of coal liquefaction residue were also investigated. Notable synergistic effects such as the increase of n-hexane soluble and the decrease of dichloromethane insoluble were observed only with the hydrogenolysis of the basic fraction of coal liquid and nondeashed coal liquefaction residue using red mud-sulfur catalyst. 4 refs., 2 figs., 2 tabs.

1994-12-31

429

Asset Prices, Liquidity, and Monetary Policy in an Exchange Economy  

British Library Electronic Table of Contents (United Kingdom)

I formulate a model in which money coexists with equity shares on a risky aggregate endowment. Agents can use equity as a means of payment, so shocks to equity prices translate into aggregate liquidity shocks that disrupt the mechanism of exchange. I characterize a family of optimal monetary policies and find that the resulting equity prices are independent of monetary considerations. I also study a perturbation of the family of optimal policies that targets a positive constant nominal interest rate and find that in this case the real equity return includes a liquidity return that depends on monetary considerations.

2011-01-01

430

Annealing, lattice disorder and non-Fermi liquid behavior in UCu4Pd  

Energy Technology Data Exchange (ETDEWEB)

The magnetic and electronic properties of non-Fermi liquid UCu{sub 4Pd} depend on annealing conditions. Local structural changes due to this annealing are reported from UL{sub III}- and Pd K-edge x-ray absorption fine-structure measurements. In particular, annealing decreases the fraction of Pd atoms on nominally Cu 16e sites and the U-Cu pair-distance distribution width. This study provides quantitative information on the amount of disorder in UCu{sub 4Pd} and allows an assessment of its possible importance to the observed non-Fermi liquid behavior.

2002-07-30

431

Acoustic wave device using plate modes with surface-parallel displacement  

Energy Technology Data Exchange (ETDEWEB)

Solid-state acoustic sensors for monitoring conditions at a surface immersed in a liquid and for monitoring concentrations of species in a liquid and for monitoring electrical properties of a liquid are formed by placing interdigital input and output transducers on a piezoelectric substrate and propagating acoustic plate modes therebetween. The deposition or removal of material on or from, respectively, a thin film in contact with the surface, or changes in the mechanical properties of a thin film in contact with the surface, or changes in the electrical characteristics of the solution, create perturbations in the velocity and attenuation of the acoustic plate modes as a function of these properties or changes in them.

1992-01-01

432

A new method for sealing containers with liquid samples for radioactivity measurements  

International Nuclear Information System (INIS)

It is imperative to use a leak-proof container for counting liquid sample to prevent contamination of costly gamma detectors. A sealant that ensures no leak is reported. It is a vinyl adhesive sealant used for household purposes, marketed by Gloucester Co., Inc, Franklin, MA under the trade name of Phenoseal (translucent variety). This sealant was superior to other sealants studied because it cures quickly, peels off easily after counting, and contains no detectable radioactivity. This sealant has been thoroughly tested and successfully employed it in the routine analysis of environmental liquid samples. (author)

2002-08-01

433

Wavelength shift of lasing from a dye-doped asymmetrically deformed liquid jet  

International Nuclear Information System (INIS)

We examined the spectral behaviors of lasing from a asymmetrically deformed liquid jet (a ? 14 ?m) which is induced by a laterally flowing gas. Th liquid sample was methanols which contains DCM dye. When n distortion is induced, the lasing spectrum appears as two periodic peaks which are corresponding to the resonance modes of cylindrical cavity. As the distortion parameter exceeds about 4%, the lasing spectrum shifts continuously to short wavelength. When the distortion parameter reaches ? 10%, the amount of blue shift was ? 30 nm. The blue shift can be explained as the shift of optimum wavelength of threshold curves. From the absorption and fluorescence curve of liquid sample, we estimated the spoiled Q with the distortion parameter.

1997-11-01

434

UK coal liquefaction  

Energy Technology Data Exchange (ETDEWEB)

The National Coal Board is investigating two routes for production of oils: liquid solvent extraction and supercritical gas extraction. Both these processes are considered ready for major development to plants of the 1 t/h scale.

1980-06-01

435

Thermal Performance of Low Layer Density Multilayer Insu1ation Using Liquid Nitrogen  

Science.gov (United States)

In order to support long duration cryogenic propellant storage, the Cryogenic Fluid Management (CFM)

2011-01-01

436

Theory of the crystal-liquid phase transition  

Science.gov (United States)

The SCF approximation is used in a statistical theory of melting based on equality of the chemical potentials. The results for the melting points of the inert gases are close to the observed values.

1967-02-01

437

Test and Evaluation of Liquid Polymers for Use in Army ...  

Science.gov (United States)

... The addition of 0.5 pphr of fine thermal carbon black to the polymers gave good resistance to 500 hours of ultraviolet (UV) xposure in a Weather ...

1972-10-01

438

Surface modification and characterization for dispersion stability of inorganic nanometer-scaled particles in liquid media  

International Nuclear Information System (INIS)

Inorganic nanoparticles are indispensable for science and technology as materials, pigments and cosmetics products. Improving the dispersion stability of nanoparticles in various liquids is essential for those applications. In this review, we discuss why it is difficult to control the stability of nanoparticles in liquids. We also overview the role of surface interaction between nanoparticles in their dispersion and characterization, e.g. by colloid probe atomic force microscopy (CP-AFM). Two types of surface modification concepts, post-synthesis and in situ modification, were investigated in many previous studies. Here, we focus on post-synthesis modification using adsorption of various kinds of polymer dispersants and surfactants on the particle surface, as well as surface chemical reactions of silane coupling agents. We discuss CP-AFM as a technique to analyze the surface interaction between nanoparticles and the effect of surface ...

2010-08-01

439

Sensitivity of Shallow Land Burial to neutron environment and activation cross sections in IFE thick-liquid concepts  

International Nuclear Information System (INIS)

A comprehensive assessment on the eligibility of reduced activation (RA) steels as structural chamber material in Inertial Fusion Energy thick-liquid concepts is performed. As far as alloying elements, it is shown that the activation of tungsten is a question to discuss. Regarding impurity elements, it is analyzed if they could question the possibility of obtaining real RA steels for shallow land burial (SLB). The effect of the thickness of the liquid wall on the SLB response of alloying and impurity elements is computed. It seems that a reasonable liquid thickness of about 80 cm is allowable to obtain SLB acceptability of real RA steels. And above all, we have estimated the impact of cross section uncertainties when addressing the former questions, and we identify those to be improved. The necessary improvement of some tungsten and niobium cross sections is justified. (authors)

2006-06-01

440

Science and Technology Centers  

Science.gov (United States)

... MPS) Advanced Liquid Crystalline Optical Materials Superconductivity Computation and Visualization ... Cement-Based Materials Synthesis, Growth, and Analysis of Electronic Materials Photoinduced Charge ...

441

Rapid determination of granisetron in human plasma by liquid chromatography coupled to tandem mass spectrometry and its application to bioequivalence study  

British Library Electronic Table of Contents (United Kingdom)

A simple, sensitive and rapid method for analysis of granisetron in human plasma, utilizing liquid chromatography tandem mass spectrometry (LC-MS/MS), has been developed and validated to satisfy FDA guidelines for bioanalytical methods. The analyte and internal standard (IS) were isolated from 100ml plasma samples by liquid-liquid extraction (LLE). A Varian 1200l tandem mass spectrometer equipped with an electrospray ionization source was operated in selected reaction monitoring (SRM) mode with the precursor-to-product ion transitions m/z 313.4/138 for granisetron and m/z 270/201 for the IS used for quantitation. The assay exhibited a linear dynamic range of 0.02-20ng/ml for granisetron in human plasma. The lower limit of quantification (LLOQ) was 0.02ng/ml with a relative standard deviati...

2006-01-01

442

Production of Jet Fuels from Coal-Derived Liquids. Volume 12. ...  

Science.gov (United States)

... The phenol and cresylic acid stream is flashed in a thin film evaporator over a concentrated sulfuric acid mixture to remove pyridine type substances ...

1989-12-01

443

Production of Amylase in Liquid Culture by a Strain of Aspergillus oryzae  

UK PubMed Central (United Kingdom)

The effect of different media and pH on the formation of amylase by Aspergillus oryzae EI 212 is described. Depending upon the composition of the medium and growth...Full Text Available

1970-04-01

445

Liquid nitrogen temperature operation of a switching power converter  

Science.gov (United States)

The performance of a 42/28 V, 175 W, 50 kHz pulse-width modulated buck dc/dc switching power

1995-01-01

446

Gutteral Pouch Mycosis and Mycotic Encephalitis in a Horse  

UK PubMed Central (United Kingdom)

A case of mycotic encephalitis in a horse with guttural pouch mycosis is described. A liquid pellet feed binder contaminated with Aspergillus sp. and erroneously mixed in a feed concentrate...Full Text Available

1986-03-01

447

Gas-liquid two-phase flow patterns in parallel channels for fuel cells  

Energy Technology Data Exchange (ETDEWEB)

Two-phase flow in horizontal parallel channels has been experimentally investigated under fuel cell related operating conditions. Pronounced hysteresis is observed in the pressure drop versus flow characteristic curve when starting from either flooded or dry conditions. When gas is introduced into channels initially filled with water (flooded initial condition), both gas and liquid tend to flow predominantly in one channel at low gas or liquid flow velocities. As the gas flow velocity increases, even distribution of gas and liquid flow in both channels is observed, accompanied with a sudden decrease in the pressure drop. On the other hand, even gas and liquid flow distribution between both channels is found at comparatively lower gas flow velocities when starting with dry-gas flow conditions with liquid introduced into channels filled with gas (stratified flow regime). The flow ...

2008-09-01

448

Fundamental research on explosives  

Energy Technology Data Exchange (ETDEWEB)

The nitric oxide molecule is being studied in order to understand the energetics and chemistry of initiation and detonation in liquid NO at the molecular level. An overview is presented of the work being done. (DLC)

1983-01-01

449

Fuel conversion apparatus and method  

Energy Technology Data Exchange (ETDEWEB)

Apparatus and method are described for the vaporization of liquid fuel oils to produce a gaseous mixture suitable for burning in a burner normally designed for operation utilizing natural gas.

1981-11-24

450

Flame Temperatures and Internal Pressures of Pyrotechnic ...  

Science.gov (United States)

... K. E. T,-us, "Clo:ei Chamber Burning Characteristics of Selected Liquid Monopropellants," 14th JANAP Combustion Meeting, CPIA Publication No. ...

1982-03-01

451

Fermi liquid and non-Fermi liquid in M-channel N fold degenerate anderson lattice  

Energy Technology Data Exchange (ETDEWEB)

We investigate Fermi liquid in the single-channel U-infinite N fold degenerate Anderson lattice with use of the expansion from the large limit of the spin-orbital degeneracy N. By collecting all diagrams up to O(N{sup -2}) of the imaginary part of the self-energy of the conduction electrons, the sum of those is shown to be given by a form proportional to {omega}{sup 2} + {pi}{sup 2}T{sup 2} up to O(N{sup -2}) in the single-channel model. On the other hand, the imaginary part of the self-energy of O(N{sup -1}) in the multichannel model has more singular frequency-/temperature-dependence, so the system is regarded as non-Fermi liquid. (author)

1999-02-28

452

Experimental Evaluation of a Carbon Slurry Droplet ...  

Science.gov (United States)

... The fuel proposed was a medium-thermal carbon black-liquid JP-i1 mixture. JP-iO or exo-tetrahydrodi (cyclopentadieue) is a pure hydrocarbon with ...

1981-12-14

453

Electrogenerated Chemiluminescence Sensor Based on Tris(2,2prime-bipyridine)ruthenium(II)-Immobilized Natural Clay and Ionic Liquid  

British Library Electronic Table of Contents (United Kingdom)

A novel electrogenerated chemiluminescence (ECL) sensor based on natural clay and ionic liquid was fabricated. Tris(2,2prime-bipyridine)ruthenium(II) (Ru(bpy)32+) was immobilized on natural clay surface through simple adsorption. An ECL sensor was prepared by mixing Ru(bpy)32+-incorporated clay, graphite powder and an ionic liquid (1-butyl-3-methylimidazolium hexafluorophosphate) as the binder. The electrochemical behavior and ECL of the immobilized Ru(bpy)32+ was investigated. It was observed that the ECL of immobilized Ru(bpy)32+ was activated by the ionic liquid. The proposed ECL sensor showed high sensitivity to tri-n-propylamine (TPrA) and the detection limit was found to be 20 pM. In addition, the ECL sensor displayed good stability for TPrA detection and long-term storage stability.

2010-01-01

454

Effects of confinement on the permanent electric-dipole moment of Xe atoms in liquid Xe  

CERN Document Server

Searches for permanent electric-dipole moments (EDM) of atoms provide important constraints on competing extensions to the standard model of elementary particles. Recently proposed experiment with liquid $^{129}$Xe [M.V. Romalis and M.P. Ledbetter, Phys. Rev. Lett. \\textbf{87}, 067601 (2001)] may significantly improve present limits on the EDMs. To interpret experimental data in terms of CP-violating sources, one must relate measured atomic EDM to various model interactions via electronic-structure calculations. Here we study density dependence of atomic EDMs. The analysis is carried out in the framework of the cell model of the liquid coupled with relativistic atomic-structure calculations. We find that compared to an isolated atom, the EDM of an atom of liquid Xe is suppressed by about 40%.

2004-01-01

455

Effect of radiation on certain animal viruses in liquid swine manure  

International Nuclear Information System (INIS)

The virucidal effect of _6_0Co gamma radiation was studied in cell culture medium and in liquid swine manure involving the most important porcine viruses that can be spread by liquid manure. The radiation doses (20 kGy and 30 kGy) were determined in preliminary experiments employing a porcine enterovirus from the serogroup 1 (Teschen group). In the main experiment, the following viruses were employed: swine vesicular disease (SVD) virus, type C foot-and-mouth disease (FMD) virus, a field strain of Aujeszky's disease (AD) virus, transmissible gastroenteritis (TGE) virus, as well as bovine viral diarrhoea (BVD) virus. The latter strain served as a model for hog cholera virus. The results of the experiments indicate that safe disinfection of the virus infected liquid swine manure by ionizing radiation requires a radiation dose of 30 kGy. (author).

1983-01-01

456

Cost effective use of liquid nitrogen in cryogenic wind tunnels  

Science.gov (United States)

A method of reliquefying from 12 to 19% of the nitrogen exhaust gas from a cryogenic wind tunnel has

1987-01-01

457

Comparison of methods to determine accurate dose calibrator activity measurements  

UK PubMed Central (United Kingdom)

BackgroundIn nuclear medicine, liquid radiopharmaceuticals for diagnostic or therapeutic purposes are administered to patients by using various types of syringes with different volumes....Full Text Available

459

Apoptosis at Inflection Point in Liquid Culture of Budding Yeasts  

UK PubMed Central (United Kingdom)

Budding yeasts are highly suitable for aging studies, because the number of bud scars (stage) proportionally correlates with age. Its maximum stages are known ...Full Text Available

460

Anesthetic stimulation of insect water receptors.  

UK PubMed Central (United Kingdom)

Halothane, chloroform, and carbon tetrachloride, in the vapor and liquid phases, stimulate the water receptor of the blowfly Phormia regina. There are three successive phases of response to long-lasting...Full Text Available

1976-09-01

461

An efficient in vitro plantlet regeneration of Cryptocoryne wendtii and Cryptocoryne becketti through shoot tip culture  

British Library Electronic Table of Contents (United Kingdom)

An efficient micropropagation protocol was established for Cryptocoryne wendtii and Cryptocoryne becketti using shoot tips explants. Multiple shoots were induced from shoot tip explants of both species cultured on agar-gelled as well as liquid MS medium supplemented with 0.5?mg/L BA and 0.2?mg/L IBA (proliferation medium). The multiple shoots of both the species formed on agar-gelled as well as liquid medium were vigorously growing with well-developed roots and leaves after 4?weeks of culture. Highest number of multiple shoots was obtained from shoot tip explants of both the species cultured in liquid proliferation medium after 4?weeks of culture. The shoot tip explants of C. wendtii and C. becketti, that were cultured in liquid proliferation medium (2?weeks) followed by culturing on agar-...

2011-01-01

462

ADDITION AND SUBSTITUTION PRODUCTS OF OXYGEN ...  

Science.gov (United States)

... 5.9-585/T; thermal stability; solubility in liquid nitrogen, oxygen and Freons; molar extinction coefficients in the visible range and EPR spectrum. ...

1965-01-05

463

0100127 - Liquid nitrogen dewar for protein crystal growth - NASA  

Science.gov (United States)

Gaseous Nitrogen Dewar apparatus developed by Dr. Alex McPherson of the University of California, Irvine for use aboard Mir and the International Space ...

464

The mechanism of metal nanoparticle formation in plants: limits on accumulation  

Energy Technology Data Exchange (ETDEWEB)

Metal nanoparticles have many potential technological applications. Biological routes to the synthesis of these particles have been proposed including production by vascular plants, known as phytoextraction. While many studies have looked at metal uptake by plants, particularly with regard to phytoremediation and hyperaccumulation, few have distinguished between metal deposition and metal salt accumulation. This work describes the uptake of AgNO{sub 3}, Na{sub 3}Ag(S{sub 2}O{sub 3}){sub 2}, and Ag(NH{sub 3}){sub 2}NO{sub 3} solutions by hydroponically grown Brassica juncea and the quantitative measurement of the conversion of these salts to silver metal nanoparticles. Using X-ray absorption near edge spectroscopy (XANES) to determine the metal speciation within the plants, combined with atomic absorption spectroscopy (AAS) for total Ag, the quantity of reduction ...

2009-08-15

465

Assimilation of cadmium, chromium, and zinc by the green mussel Perna viridis and the clam Ruditapes philippinarum  

Energy Technology Data Exchange (ETDEWEB)

The green mussel Perna viridis and the clam Ruditapes philippinarum have been frequently used as biomonitors of coastal contamination in subtropical and tropical waters, yet the physiological processes controlling metal uptake in these bivalves are unknown. Assimilation efficiency (AE) is an important physiological parameter quantifying metal bioavailability from ingested food. The authors determined the AEs of Cd, CR, and Zn in these bivalves feeding on five species of phytoplankton and one natural section. The influences of the cytoplasmic distribution of metals in the algal cells and the digestive physiology of bivalves on metal AEs were also examined. Among the three metals, Zn was generally assimilated at the highest efficiency, i.e., 21 to 36% in the mussels and 29 to 59% in the clams. Cr was the least assimilated metal, with AEs being 10 to 16% in the ...

2000-06-01

466

Whole-mount specimens in the analysis of en bloc samples obtained from revisions of resurfacing hip implants  

UK PubMed Central (United Kingdom)

BackgroundModern metal-on-metal hip resurfacing implants are being increasingly used for young and active patients, although the long-term outcome and failure mechanisms of these...Full Text Available

2010-06-01

467

The preparation of a `metal-free' nappy and its application to metabolic balances in children  

UK PubMed Central (United Kingdom)

Disposable nappies (diapers) have been satisfactorily demineralized and used for the collection of excreta from infants and young children during mineral and trace metal balances. It was possible to...Full Text Available

1972-11-01

468

The association between metal allergy, total hip arthroplasty, and revision  

UK PubMed Central (United Kingdom)

Background and purpose It has been speculated that the prevalence of metal allergy may be higher in patients with implant failure. We compared the prevalence and cause of revisions following...Full Text Available

2009-12-04

469

The Nature of Arsenic-Phytochelatin Complexes in Holcus lanatus and Pteris cretica1  

UK PubMed Central (United Kingdom)

We have developed a method to extract and separate phytochelatins (PCs)—metal(loid) complexes using parallel metal(loid)-specific (inductively coupled plasma-mass spectrometry) and organic-specific...Full Text Available

2004-03-01

470

Temperature Histories of Small Metallic Fragments Trapped in Propelling Charges.  

Science.gov (United States)

Small metallic fragments can be trapped in combustible cartridge cases during manufacture and released into the interior-ballistic flow upon combustion of the case. Such particles may survive the interior-ballistic cycle and pose an ignition threat to the...

1990-01-01

471

Superconductivity in transition-metal germanium systems  

International Nuclear Information System (INIS)

The variation in the superconducting properties of various binary alloys of transition metal-germanium systems was surveyed by studying sputter deposited samples prepared under various conditions. The primary interest has been to study the formation of the stoichiometric A-15 compounds T_3Ge.

472

Structural, chemical and biological aspects of antioxidants for strategies against metal and metalloid exposure  

UK PubMed Central (United Kingdom)

Oxidative stress contributes to the pathophysiology of exposure to heavy metals/metalloid. Beneficial renal effects of some medications, such as chelation therapy depend at least partially on the ability...Full Text Available

2009-09-01

473

Short-Term Metal/Organic Interface Stability Investigations of Organic Photovoltaic Devices: Preprint  

Energy Technology Data Exchange (ETDEWEB)

This paper addresses one source of degradation in OPV devices: the metal/organic interface. The basic approach was to study the completed device stability vs. the stability of the organic film itself as shown in subsequent devices fabricated from the films.

2008-05-01

474

Rhizosphere Acidification by Iron Deficient Bean Plants: The Role of Trace Amounts of Divalent Metal Ions  

UK PubMed Central (United Kingdom)

Rhizosphere acidification by Fe-deficient bean (Phaseolus vulgaris L.) plants was induced by trace amounts of divalent metal ions (Zn, Mn). The induction of this Fe-efficiency reaction...Full Text Available

1989-05-01

475

Removal of metallic tracheobronchial stents in lung transplantation with flexible bronchoscopy  

UK PubMed Central (United Kingdom)

BackgroundAirway complications are among the most challenging problems after lung transplantation, and Self-Expandable Metallic Stents (SEMS) are used to treat airway complications...Full Text Available

476

Palliation of malignant esophageal obstruction and fistulas with self expandable metallic stents  

UK PubMed Central (United Kingdom)

AIM: To evaluate the efficacy of self expandable metallic stents (SEMS) in patients with malignant esophageal obstruction and fistulas.METHODS: SEMS were implanted in the presence of fluoroscopic...Full Text Available

2010-12-07

477

Morphological and metabolic responses to starvation by the dissimilatory metal-reducing bacterium Shewanella alga BrY.  

UK PubMed Central (United Kingdom)

The response of the dissimilatory metal-reducing bacterium Shewanella alga BrY to carbon and nitrogen starvation was examined. Starvation resulted in a gradual decrease in the mean cell volume from...Full Text Available

1996-12-01

478

Metallic seals offer improved resilience  

International Nuclear Information System (INIS)

Metallic O-ring or Helicoflex seals can prevent relaxation and provide greater resilience than composite seals, helping to keep joints leaktight. Their characteristics and applications in the nuclear industry are outlined. (Author).

479

Metal atom diffusion in amorphous silica and at the silica surface. Progress report, December 1, 1982-December 1, 1983  

Energy Technology Data Exchange (ETDEWEB)

Objective is to study the effects of local structure, interatomic forces, and atom size on the mobility of metal atoms in amorphous silica and at the silica surface. EXAFS studies of Zn and Pt in silica are reported. (DLC)

1983-01-01

480

Metal Ions-Stimulated Iron Oxidation in Hydroxylases Facilitates Stabilization of HIF-1? Protein  

UK PubMed Central (United Kingdom)

The exposure of cells to several metal ions stabilizes HIF-1α protein. However, the molecular mechanisms are not completely understood. They may involve inhibition of hydroxylation by either...Full Text Available

2009-02-01

481

Mean distance of closest approach of alkaline-earth metals ions in aqueous solutions: Experimental and theoretical calculations  

British Library Electronic Table of Contents (United Kingdom)

The estimation of numerical values of the mean distance of closest approach of ions, a, of alkaline-earth metal ion salts in aqueous solutions, determined from activity coefficients, as well as from different theoretical approaches, is presented and discussed.

2010-01-01

482

Laser-assisted solar-cell metallization processing  

Energy Technology Data Exchange (ETDEWEB)

Laser assisted solar cell metallization processing which is a one step process is examined. The potential advantages of laser disposition techniques for photovoltaic systems are: a high resolution, no photolithography, clean and contamination free, in-situ sintering, and low contact resistance.

1984-03-01

483

Laser-assisted solar cell metallization processing. Quarterly Report, December 1984-February 1985  

Energy Technology Data Exchange (ETDEWEB)

Laser-assisted processing techniques for producing high-quality solar cell metallization patterns are being investigated, developed, and characterized. The tasks comprising these investigations are outlined.

1985-04-01

484

L edge-absorption systematics of some transition-metal (Pd, Ag), main-group-metal (Sn, In), and ionic (CsI) systems  

Energy Technology Data Exchange (ETDEWEB)

The L edge absorption of Pd, Ag, Sn, In, and CsI was measured in order to study the density of states and the unoccupied d states. 4 figures. (DLC)

1982-01-01

485

Identification and validation of heavy metal and radionuclide hyperaccumulating terrestrial plant species. Quarterly technical progress report, March 20, 1995--June 20, 1995  

Energy Technology Data Exchange (ETDEWEB)

The biological accumulation of heavy metals and cesium, strontium, and uranium in plants is discussed. The role of nutrient deficiencies and foliar treatments of manganese and iron compounds is described.

1995-12-01

486

High Efficiency Solar Cell on Low Cost Metal Foil Substrate  

Science.gov (United States)

During Phase II multi-junction solar cell will be grown on the large grain thin film produced during Phase I on flexible/low cost metal foil substrate. ...

487

Heavy metal concentrations in plants and different harvestable parts: A soil-plant equilibrium model  

International Nuclear Information System (INIS)

A mathematical interaction model, validated by experimental results, was developed to modeling the metal uptake by plants and induced growth decrease, by knowing metal in soils. The model relates the dynamics of the uptake of metals from soil to plants. Also, two types of relationships are tested: total and available metal content. The model successfully fitted the experimental data and made it possible to predict the threshold values of total mortality with a satisfactory approach. Data are taken from soils treated with Cd and Ni for ryegrass (Lolium perenne, L.) and oats (Avena sativa L.), respectively. Concentrations are measured in the aboveground biomass of plants. In the latter case, the concentration of metals in different parts of the plants (tillering, shooting and earing) is also modeled. At low concentrations, the effects of metals are moderate, and ...

2010-08-01

488

Enhanced tube inner surface heat transfer device and method  

Science.gov (United States)

An inner surface substrate of metal tubes is provided with a single layer of randomly distributed metal bodies bonded to the substrate, spaced from each other, and substantially surrounded by the substrate to form body void space.

1979-05-15

489

Electrolysis of halide-containing solutions with platinum based amorphous metal alloy anodes  

Energy Technology Data Exchange (ETDEWEB)

A process for the generation of halogens from halide-containing solutions includes the step of conducting electrolysis of the solutions in an electrolytic cell having a platinum based amorphous metal alloy anode.

1985-12-24

490

Drug-Eluting Stents versus Bare Metal Stents in Unprotected Left Main Coronary Artery Stenosis: a Meta-Analysis  

UK PubMed Central (United Kingdom)

ObjectivesWe undertook a meta-analysis to assess outcomes for drug-eluting (DES) and bare metal stents (BMS) in percutaneous coronary intervention (PCI) for unprotected...Full Text Available

2010-06-01

491

Cost-Effectiveness Analysis of Proposed Effluent Limitations Guidelines and Standards for the Metal Products and Machinery Industry (Phase 1).  

Science.gov (United States)

This cost-effectiveness analysis supports the proposed effluent limitations guidelines and standards for the Metal Products and Machinery Industry (MP and M) Phase I Industry. The report assesses the cost-effectiveness of five regulatory options for indir...

1995-01-01

492

Cadmium, Lead, and Other Metals in Relation to Semen Quality: Human Evidence for Molybdenum as a Male Reproductive Toxicant  

UK PubMed Central (United Kingdom)

BackgroundEvidence on human semen quality as it relates to exposure to various metals, both essential (e.g., zinc, copper) and nonessential (e.g., cadmium, lead), is inconsistent....Full Text Available

2008-11-01

493

Analysis of control methods: mercury and cadmium pollution.  

UK PubMed Central (United Kingdom)

Physical system conceptual models are developed to illustrate the various interconnecting pathways of metal flow. Economic use of mercury and cadmium, as representative toxic heavy metals, is inventoried,...Full Text Available

1975-12-01

494

Acidizing subterranean well formations containing deposits of metal compounds  

Science.gov (United States)

Methods of acidizing a subterranean well formation, acidizing compositions, and sequestering additives for preventing the precipitation of metal compounds in the formation are described. Use of the methods and chemicals described should lead to improved formation permeability as compared to use of previous methods and chemicals. 12 claims.

1979-04-24

495

46 CFR 160.171-17 - Approval testing for adult size immersion suit.  

Science.gov (United States)

...visible damage. (k) Corrosion resistance. Each metal part of a...evidence of salt-spray corrosion resistance equal to or greater than...sample of test metal must show corrosion resistance equal to or better than...

2010-10-01

497

CAPACITOR DISCHARGE METAL FORMING  

Science.gov (United States)

... Report Date : JUL 1961. Pagination or Media Count : 39. Abstract : Open-ende Terms: Electrohydraulic forming, Magnetic forming. ...

1961-07-01

498

An investigation of the decoupling effects in a magnetic forming beryllium coil assembly.  

Science.gov (United States)

Decoupling force exerted by magnetic forming Be coil assembly on metallic plate during forming

1968-01-01