British Library Electronic Table of Contents (United Kingdom)

A fully lamellar ferrite/cementite nanostructure was designed in a low C steel by using a specific thermal treatment. The strengthening of such microstructure has been investigated as a function of prestrain by rolling up to a deformation of 300%. As in usual pearlitic structure, its work-hardening shows no saturation and its elongation to fracture remains rather constant instead of decreasing drastically as conventional steels. The hardening by a similitude effect is thus not the privilege of pearlitic steels. Nevertheless, its lower initial work-hardening rate at low strain compared to an equivalent pearlitic steel and a lower hardening potential at high strain let us suspect major differences in the nature and the behaviour of ferrite channels in relation to the morphogenesis of the mic...

Energy Technology Data Exchange (ETDEWEB)

Mechanical properties of P-LDHA and V-ROL N steels of the Czech production are compared with other ultra-high strength steels produced in the world. The most important results can be summarized into following points: 1. Optimally heat treated P-LDHA steel exhibits substantially better strength characteristics then the V-ROL N steel. 2. Optimal tempering temperature of the P-LDHA steel is 300 C. 3. Basic mechanical properties of P-LDHA steel belong to the top of the UHS steels ranking and are well comparable with those of American 300 M steel. 4. In the low-cycle fatigue region, the P-LDHA steel exhibits slightly better fatigue resistance then the 300 M steel. On the other hand, the high-cycle fatigue resistance of 300 M steel is slightly ...

Energy Technology Data Exchange (ETDEWEB)

Nanocrystalline and nanostructured materials offer unique microstructure-dependent properties that are superior to coarse-grained materials. These materials have been shown to have very high hardness, strength, and wear resistance. However, most current methods of producing nanostructured materials in weapons-relevant materials create powdered metal that must be consolidated into bulk form to be useful. Conventional consolidation methods are not appropriate due to the need to maintain the nanocrystalline structure. This research investigated new ways of creating nanocrystalline material, new methods of consolidating nanocrystalline material, and an analysis of these different methods of creation and consolidation to evaluate their applicability to mesoscale weapons applications where part features are often under 100 {micro}m wide and the material's microstructure must be very small to give homogeneous properties ...

International Science & Technology Center (ISTC)

Nanostructured Materials from Impulse Plasma in Liquid: Studying of Physical-Chemical Properties, Optimization of Conditions of Obtaining

Energy Technology Data Exchange (ETDEWEB)

There are two types in quench distortion of steel parts: thermal distortion and transformation distortion. Quench distortion is caused mainly by uneven cooling rate of steel parts from Austenitising temperature. The rapid cooled side is lengthened (convex deformation); the slow cooled side is shortened (concave deformation). So, to control the quench distortion, it is necessary to regulate the cooling rate of steel parts during quenching. TWO COMPONENTS produce the quench distortion of steel parts: the thermal stress and transformation stress. Generally, the effect of the thermal stress on the quench distortion is stronger than the transformation stress. The quench distortion is caused by uneven cooling rate of the steel parts, from Austenitising temperature to Ms point and Ms-Mf range. So, to control the quench distortion, it is very important to regulate the ...

International Nuclear Information System (INIS)

Focused Ion Beam (FIB) milling is a powerful tool to produce ordered magnetic nanostructures. However, it is impossible to produce out-of-plane magnetized nanoscale structures from multilayer films by direct FIB writing. Co/Pt multilayers exhibit an out-of-plane easy axis due to strong perpendicular interface anisotropy. The interface contribution is known to be very sensitive to high energy ion irradiation. In case of 30 keV Ga ions it needs less than one ion per 100 surface atoms to destroy the perpendicular interface anisotropy. We demonstrate how this problem can be overcome by milling a Co/Pt multilayer, which has been deposited on a SiN membrane, from the rear side, through the SiN. The effect of the ions is determined as a function of applied dose utilizing the domain structure imaged by soft X-ray holography. When the magnetic material is removed we find only a very narrow range of destruction around the holes in ...

International Nuclear Information System (INIS)

The effect of the rare earth element, yttrium, on the mechanical properties of 9Cr-2WVTa low active martensite steel for fusion reactor was studied and the metallurgical behavior of yttrium in the steel was primarily analyzed. The results show that it is easy for yttrium to aggregate and form the blocky yttrium rich inclusions in the steel, which can dissever the continuity of the matrix and produce micro-cracks for fracture. The yttrium rich inclusions were distributed along the rolling direction, which made the fracture surface delaminated in the tensile and impact samples, and reduced the mechanical properties of the steel. (authors)

Science.gov (United States)

The Asarco-Mission complex (image left) is an active producer of copper and molybdenum (important in making steel and other metal alloys), ...

Energy Technology Data Exchange (ETDEWEB)

We used light confinement in optical microcavities to achieve a strong enhancement and a precise wavelength tunability of the electrical photoconductance of nanostructured porous silicon (PS). The devices consist of a periodic array of alternating PS layers, electrochemically etched to have high and low porosities - and therefore distinct dielectric functions. A central layer having a doubled thickness breaks up the symmetry of the one-dimensional photonic structure, producing a resonance in the photonic band gap that is clearly observed in the reflectance spectrum. The devices were transferred to a glass coated with a transparent SnO{sub 2} electrode, while an Al contact was evaporated on its back side. The electrical conductance was measured as a function of the photon energy. A strong enhancement of the conductance is obtained in a narrow (17nm FWHM) band peaking at the resonance. We present experimental results of the angular dependence of ...

International Nuclear Information System (INIS)

Scanning thermal microscopy (SThM) was used to map thermal conductivity images in an ultrafine-grained copper surface layer produced by surface mechanical attrition treatment (SMAT). It is found that the deformed surface layer shows different thermal conductivities that strongly depend on the grain size of the microstructure: the thermal conductivity of the nanostructured surface layer decreases obviously when compared with that of the coarse-grained matrix of the sample. The role of the grain boundaries in thermal conduction is analyzed in correlation with the heat conduction mechanism in pure metal. A theoretical approach, based on this investigation, was used to calculate the heat flow from the probe tip to the sample and then estimate the thermal conductivities at different scanning positions. Experimental results and theoretical calculation demonstrate that SThM can be used as a tool for the thermal property and microstructural analysis of ...

CERN Document Server

A total of 50 000 tonnes of low-carbon steel sheet has been ordered for the LHC main magnets. After three years of production, about 10 000 tonnes of steel sheet have been produced by Cockerill-Sambre Groupe Usinor. This paper gives a summary of the manufacturing process and improvements implemented as well as an overview of the difficulties encountered during this production. Preliminary statistics obtained for the mechanical and magnetic steel properties are presented. (6 refs).

Energy Technology Data Exchange (ETDEWEB)

Voestalpine AG (Linz, Austria) produces heavy steel for steam turbines, compressors for the promotion of oil and gas as well as for the chemical industry, mechanical engineering and for the offshore technology. A weight range between 1 and 200 tons can be covered. The author of the contribution under consideration is limited to characteristics which have to be managed by a large steel foundry within the range of the steam power plants. This is described on the basis of produced steam turbines for power stations in the highest performance segment (1,600 MW).

International Science & Technology Center (ISTC)

Multi-functional Bioactive Nano-structured Coatings for Load-Bearing Implants

Energy Technology Data Exchange (ETDEWEB)

Full text of publication follows: Energy and environment are two major concerns in our modern society due to the coming shortage in fossil energy sources and the growing of greenhouse gas emissions. The challenge for the coming years is to discover new energy resources and to develop devices that are compatible with a sustainable development and generate few (or zero) emission. One of these devices is the fuel cell feed by hydrogen, whose application fields are very large. In particular, the proton exchange membrane fuel cell (PEMFC) is the most realistic device for automotive application. However, hydrogen storage remains one of the most important challenges regarding its development. Although different techniques are available for storing hydrogen, no ideal solution has been found yet. Compression needs elaborated tanks in shape for supporting high pressures, liquefaction requires an expensive hydrogen cooling and adapted tanks. Chemical storage by hydrides imposes heavy devices. A ...

Energy Technology Data Exchange (ETDEWEB)

A number of properties in steel components are detrimentally influenced when exposed to hydrogen environments. Under these conditions, atomic hydrogen is adsorbed on the steel surface, then absorbed and preferentially transported towards tri-dimensional stressed regions in the crystal lattice and into defects such as interfaces or dislocations. The hydrogen embrittlement susceptibility is strongly influenced by various microstructural parameters including the type of inclusions, steel composition and heat treating conditions. One of the alternatives employed in minimizing hydrogen embrittlement is the use of surface barriers for hydrogen permeation. In particular, the presence of surface nitride layers in steels can be considered as an effective barrier. Nitride steel surface layers can be produced by plasma nitriding with the concomitant benefits of improved ...

International Nuclear Information System (INIS)

The critical part of the trimetallic transition joint (type 304 stainless steel/Alloy 800/2.25 Cr-1 Mo steel), the Alloy 800/2.25 Cr-1 Mo steel joint welded with Inconel 182, was subjected to thermal cycling between room temperature and 873 K. The thermal cycling test procedure used produces accelerated failures in transition joints similar to those observed in steam generators of operating power plants. On thermal cycling, precipitation at the weld/ferritic steel interface decreased on post-weld heat treatment. This precipitation increased with increased prior ageing and applied stress. The results of these tests indicated a considerable improvement in performance of the trimetallic transition joint compared to the direct (bimetallic) transition joint. (orig.).

International Nuclear Information System (INIS)

With the aim of optimizing the nitriding process parameters (temperature and gas mixture ) experimental studies of the plasma nitriding of Ck 15 steel were carried out, using a D. C. glow discharge. Nitriding treatments were performed at 450, 500 and 550 and N_2/H_2 volume ratio of 3/1, 1/1 and 1/3 for 5 hours. Nitriding treatment produces modified surface layer consisting of an outer compound layer and an inner diffusion layer.The plasma nitriding of Ck 15 produce single white layer consisting of #gamma#-(Fe_4N).

Science.gov (United States)

A novel reactor combining a flame-deposited nanostructured titanium dioxide film and a set of embedded ceramic electrodes was designed, developed and tested for degradation of methyl tert-butyl ether (MTBE) in water. On applying a voltage to the ceramic electrodes, a surface coro...

KoreaScience (Korea)

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British Library Electronic Table of Contents (United Kingdom)

Tailor die quenching in the hot stamping of quenchable steel sheets was developed to produce ultra-high strength steel formed parts having strength distribution. Local portions of the heated sheet were quenched by holding grooved tools at the bottom dead centre during the stamping. Non-contact portions were generated in the sheet by grooving the tools, and thus the strength in the contact portions is high owing to the quenching and that in the non-contact portions is low owing to the lack of the quenching. Hat-shaped products having a tensile strength of approximately 1.5GPa only at four corners were formed.

International Nuclear Information System (INIS)

Separate effect of impurities and alloying additions of phosphorus, silicon, boron, carbon, sulphur, magnesium, copper, aluminium and molybdenum on the tendency to intergranular corrosion (IGC) of quenched highly pure steel Fe-20% Cr-20Ni in boiling solution 27% HNO_3+40 g/l Cr"6"+, as well as in sulphuric and nitric acids mainly at potentials, corresponding to repassivation range, has been studied. It is shown that steel susceptibility to IGC depends on impurity nature and to a high extent is determined by the potential value independent of the way of its achieving. The most unfavourable effect on stability of grain boundaries is produced by microadditions of boron as well as by impurities of phosphorus and silicon. To ensure increased corrosion resistance of the investigated steel against IGC in highly oxidative media the pontent of phosphorus and silicon impurities unit should not exceed 0.01 and ...

Energy Technology Data Exchange (ETDEWEB)

The stress corrosion cracking (SCC) susceptibility of 13% Cr martensitic (UNS S42000) and supermartensitic (UNS S41125) steels in sodium chloride solutions in the presence of thiosulphate was evaluated by slow strain rate tests (SSRT). The tests were performed in 5% sodium chloride solutions buffered at pH 2.7, 3.5, 4.5 and 6.0 in the absence and presence of thiosulphate in a concentration range between 10{sup -6} and 10{sup -3} M, at 25 {+-} 0.1 C. The electrochemical behaviour of the two steels in the different solutions was determined by recording the anodic and cathodic polarisation curves. 13% Cr martensitic steel showed SCC in 5% sodium chloride solutions with pH {<=} 4.5 in the presence of 3 x 10{sup -6} thiosulphate. Decreasing the chloride ion concentration from 50 to 10 g/l, the critical concentration of thiosulphate to provoke SCC susceptibility increased from 3 x 10{sup -6} to 1 x 10{sup -5} M. The ...

Energy Technology Data Exchange (ETDEWEB)

In response to the Clean Coal II solicitation, Bethlehem Steel Corporation (BSC) submitted a proposal to the DOE in May 1988. The proposal submitted by BSC describes a Unique integration of commercial technologies developed by Davy/Still Otto to clean coke oven gas being produced at its Sparrows Point, Maryland steel plant. This innovative coke oven gas cleaning system combines secondary gas cooling with hydrogen sulfide and ammonia removal, hydrogen sulfide and ammonia recovery, ammonia destruction and sulfur recovery to produce a cleaner fuel gas for plant use. The primary environmental benefit associated with employing this innovative coke oven gas cleaning system is realized when the fuel gas is burned within the steel plant. Emissions of sulfur dioxide are reduced by more than 60 percent. The removal, recovery and destruction of ammonia eliminates the disposal problems ...

Energy Technology Data Exchange (ETDEWEB)

This paper reports that the co-deposition of chromium and silicon into a 2.25Cr-1.0Mo-0.15C steel, alloy 800, and type 304 stainless steel has been achieved using the pack cementation process. The ferritic coating produced on the 2.25 Cr-1.0Mo steel was approximately 225 {mu}m (9 mils) thick, whereas the inward diffusion of chromium and silicon produced a two-phase structure of ferrite and austenite for type 304. Chromium and silicon were incorporated into the austenitic solid solution upon diffusion into alloy 800. All coatings had approximately 25 to 35 wt% Cr and 2 to 3% Si at the surface. Cyclic oxidation testing in air of the coated 2.25Cr-1.0Mo steel (T = 700{degrees} C) and type 304 (T = 1035{degrees} C) showed a dramatic decrease in the oxidation kinetics compared to the original uncoated alloys. The cyclic oxidation of alloy 800 was also improved.

International Nuclear Information System (INIS)

Focused Ion Beams are an important approach for nanostructure fabrication in the semiconductor industry and material sciences. Applications in sputtering and ion induced deposition of materials are investigated. The IMSA FIB system equipped with the high resolution Orsay Physics CANION M31plus ion column with current densities up to 10 A/cm"2 including a gas injection system is applied. In this work the ion beam induced chemical vapour deposition of tungsten, wherefore tungsten hexacarbonyl as precursor gas is used for a first investigation. Conductive tungsten-nanowires with smallest cross-section upon a substrate of Si and SiO_2 are produced. The ion beam parameters of this focused ion beam system are optimized for the metal deposition. A short insight in the theory of layer nucleation and growth induced by the ion beam during the metal deposition is given. The layer quality is determined by Auger electron analysis which shows the components ...

Energy Technology Data Exchange (ETDEWEB)

The aim of this work is to describe the processes during plasma nitriding of Nb-containing, powder metallurgy prepared (PM) tool steel. PM steel was studied containing 2.5% C, 3.3% Si, 6.2% Cr, 2.2% Mo, 2.6% V, 2.6% Nb and 1.0% W, produced by melt atomization and hot isostatic pressing. The hardened and tempered steel was plasma nitrided at temperatures ranging from 470 to 530 deg. C. The nitriding time was 30-180 min. Optical microscopy, electron microscopy, XRD, EDS, WDS and hardness measurements were used to study the steel's properties, microstructure, phases and chemical composition. The nitriding temperature of 470 deg. C was found to be unsuitable for practical use because the layers prepared at this temperature were non-uniform. The compound layer formed by M{sub 2,3}(C,N) and M{sub 4}N was found after nitriding at temperatures of 500 and 530 deg. C for at least 60 ...

Energy Technology Data Exchange (ETDEWEB)

To avoid the drop in corrosion resistance of stainless steels in conventional nitriding (precipitation of CrN), low-temperature techniques like ion implantation, plasma immersion ion implantation (PIII, PI{sup 3}) and low-temperature plasma nitriding were developed. In this investigation, four stainless-steel grades (ferritic: X6Cr17, austenitic-ferritic: X2CrNiMoN22.5.3, austenitic: X8CrNiTi18.10 and X5CrNi18.10) were plasma-nitrided between 250 and 500 C. Nitrogen-enriched layers with a high nitrogen content were produced, leading to a significant increase in surface hardness. X-ray diffraction indicated that CrN did not precipitate if treatment temperatures did not exceed 400 C. 'Expanded austenite' formed in the austenitic and duplex steels and {epsilon}-nitride (Fe{sub 2}N{sub 1-x}) in the ferritic steel. The optically visible structure of the nitrided cases ...

Energy Technology Data Exchange (ETDEWEB)

Spray depositing allows the production of steels having a structure which is free of any macro-segregation, homogeneous and equiaxed. Nevertheless the spray deposition of steels shows some effects that have to be regarded as disadvantages. A porous region at the billet border and a rather coarse-grained microstructure can be noticed. As a result, in the presented work the influence of a subsequent hot rolling and a following heat treatment on microstructure and mechanical properties has been investigated. For this purpose the bearing steel SAE 52100 has been used as master material. The initial microstructure has been transformed to a homogeneous equiaxed fine-grained pearlitic microstructure without any remaining porosity. To get use of the characteristic properties of this high-strength steel an isothermal bainitic hardening has been carried out. Information about the mechanical properties of this ...

Science.gov (United States)

A proposed inhibitor for steel corrosion in hydrochloric acid consists essentially of 0.5% of an inhibitor called BA-6, 0.25-0.5% of 1-hexynol-3, and about 0.02% of potassium iodide (calculated on the amount of acid). The inhibitor DA-6 is produced by condensing benzylamine with utrotropine. 1-Hexynol-3, secondary alcohol, is obtained from butyraldehyde and acetylene in the presence of caustic potash. The increase of potassium iodide concentration from 0.02-0.1% increases the protective action of the inhibitor. Hexynol, dipropargyl ester, and potassium iodide must be introduced in HC1 before injection of the latter into the well.

British Library Electronic Table of Contents (United Kingdom)

For an ultrafine grain ferrite/cementite (UGF/C) steel, the Charpy impact energy was measured at temperatures from 373K to 4.2K, and tensile tests were carried out at temperatures between 323K and 77K. For the steel with annealed microstructure, the ductile-to-brittle transition appearance temperature (DBTT) was lower than the Charpy transition temperature (CTT). With increasing annealing time at 873K, the DBTT and the CTT increased, and the DBTT approached the CTT. The DBTT decreased with decreasing effective grain size. The effective grain size correlated to the grain size of the larger grain size peak in the distribution of grains with {100} planes. The annealed microstructures had higher yield strength for equivalent toughness (including upper shelf energy, DBTT and CTT) compared to th...

International Nuclear Information System (INIS)

The effect of surface treatment on the characteristics of the passive film on a super duplex stainless steel is addressed. Auger Electron Spectroscopy (AES) has been used to provide in-depth chemical profile analyses of the passivation film. This study showed that the constitution of the film is largely dependent on the electrolytic conditions under which it is produced or to which it is submitted. The passive films formed by polarisation in an alkaline solution (boric-borate solution) consist of two regions, an inner region rich in chromium and an outer region rich in iron, whilst the films produced in acid solution only present the chromium - rich region. The film thickness is also greatly affected by the polarisation conditions. It can vary from ca. 8 monolayers to about 20 monolayers for cathodically and anodically polarised specimens respectively. The microstructure of weldmetal is also discussed. (author)

Energy Technology Data Exchange (ETDEWEB)

The influence of surface oxides of variable composition and nonstoichiometry formed at high temperatures in air on the general corrosion resistance of ferritic chromium steel type 08H17T (Fe-17Cr-1Ti) in weak sulfuric acid has been studied. Anodic passive films formed on steel with different pretreatments have also been examined. The surface oxide of nearly stoichiometric composition formed at 300 C provides for the passive state of steel in sulfuric acid despite its depletion by chromium when compared with that for nonstoichiometric Cr-enriched oxide formed at 600 C. The dissolution and transformation of nonstoichiometric thermal surface oxide in sulfuric acid appear to take place through defect sites, {minus}Fe{sup 2+} ions, and oxygen vacancies of the n-type conductor. The passive film formed on the nonstoichiometric oxide film, which had been produced at 600 C, was found to be more susceptible to ...

International Nuclear Information System (INIS)

Results from a heavily fouled 19 tube C-E model boiler test to investigate the potential for egg crate corrosion in aggressively fouled AVT chemistry are reported. Substantial support plate and egg crate corrosion was produced in this test. Carbon steel drilled support plates exhibited extensive denting which resulted in flow hole ligament cracking. Corrosion of the carbon steel egg crate, through-wall at areas of tube contact, resulted in denting of the Alloy 600 heat transfer tubes. Corrosion performance of the 409 stainless steel egg crate was improved compared to the carbon steel egg crate although localized through-wall corrosion was noted. The results from the above test and previously reported tests were compared based on the following simplifying assumptions: maximum dent size and/or corrosion penetrations utilized, average bulk water chloride concentrations, pilling ...

International Nuclear Information System (INIS)

A low-molybdenum austenitic stainless steel (UNS S30100) has been surface implanted with molybdenum ions, using various doses of 50 keV and 140 keV ions at room temperature. It is found that in aqueous sulphate/chloride solutions similar to the constitution of sea-waters the implantation does not affect the potentiostatically-determined critical pitting potential, but does change the density and morphology of corrosion pits. Pitting initiation after the addition of chloride at a fixed potential indicates little change in the time for measurable current increase, but the rate of increase of the current is much lower for implanted material. Detailed examination using optical microscopy, scanning electron microscopy, transmission electron microscopy and selected area diffraction suggests that the pits produced in implanted material are hemispherical with smooth covers of unattacked alloy. The use of half-implanted samples demonstrates that ...

International Nuclear Information System (INIS)

The thermo-chemical treatments of steels with plasma is normally carried out in low-pressure ionized gaseous atmospheres. Among the treatments used most often are: nitruration, carburization and boronized. A plasma can also generate at atmospheric pressure. One way to produce it is with an electrochemical cell that works at a relatively high inter-electrode voltage and under conditions of heavy gas generation. This type of plasma is known as electrolytic plasma. This work studies the feasibility of using electrolytic plasma for the surface processing of steels. Two processes were selected: boronized and nitruration., for the hardening of two types of steel: one with low carbon (1020) and one with low alloy (4140). In the case of the nitruration, the 1020 steel was first aluminized. The electrolytes were aqueous solutions of borax for the boronizing and urea for the nitruration. The ...

Energy Technology Data Exchange (ETDEWEB)

The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, efforts have focused on the facility modifications for continuous hydrotreating, as well as developing improved protocols for producing synthetic pitches.

British Library Electronic Table of Contents (United Kingdom)

The physics and technology of a new class of efficient composite piezoelectrics are described. This material combines nanostructured and micropiezoelectric matrix composites. They consist of a polymer matrix, an insulating nanodimensional phase, and a microdimensional piezoelectric phase. It is shown that the nanostructuring of the near-surface region of polymer-PZT piezoelectric composites greatly improves their piezoelectric, mechanical, and electromechanical characteristics. A plausible mechanism underlying this effect is suggested.

Energy Technology Data Exchange (ETDEWEB)

A total of 10 samples disks of 2024-T3 aluminum and 4130 ferrous steel were exposed to rocket-triggered lightning currents at the Kennedy Space Center test site in Florida during the summer of 1990. The experimental configuration was arranged so that the samples were not exposed to the preliminary streamer, wire-burn, or following currents that are associated with an upward-initiated rocket-triggered flash but which are a typical of naturally initiated lightning. Return-stroke currents and continuing currents actually attaching to the sample were measured, augmented by close-up video recordings of approximately 3 feet of the channel above the sample and by 16-mm movies with 5-ms resolution. From these data it was possible to correlate individual damage spots with streamer, return-stroke, and continuing currents that produced them. Substantial penetration of 80-mil aluminum was produced by a continuing current of submedian ...

International Nuclear Information System (INIS)

As an unconventional surface alloying process, ion implantation has been utilized to improve the active-passive behavior and the pitting resistance of martensitic M50 engineering alloy. In a field simulation study, Cr-implantation only at 150 kev to a fluence of 2 x 10"1"7 ions/cm"2 prevented pitting. The best pitting resistance of the steel was obtained with multiple implantations of Cr and Mo. The intermixing effect of high fluence P-implantation into 304 stainless produced an amorphous surface alloy. The removal of the grain boundaries and the uniformity of the resulting structure had a great influence on corrosion properties. REED analysis indicated that the anodic passive films formed on P-implanted 304 stainless steel at 250 mV (SCE) in 0.5M H_2SO_4 was amorphous. Phosphorus and boron were implanted into 316 stainless steel to study the passivity of 316 stainless. Electrochemical experiments were ...

International Nuclear Information System (INIS)

Simulation irradiation experiments were carried out to investigate the formation processes and contribution to hardening of radiation-induced features in low alloy steels. Medium Cu (0.12 and 0.16%) and low Cu (0.03%) A533B steels were irradiated with 3 MeV Ni ions and 5 MeV electrons, and in KUR at 290degC. Irradiated steels were examined by three-dimensional atom probe, positron annihilation, high-resolution transmission electron microscopy and hardness measurements. Electron irradiation caused almost the same hardening as KUR irradiation in medium Cu steels under almost the same dose rate and dose conditions, whereas the formation of larger, denser and more Cu enriched clusters and smaller accumulation of single vacancies were confirmed for KUR irradiation. This indicated that cascade damage provides additional cluster nucleation sites to compensate for lower free point defect production. High dose ...

Energy Technology Data Exchange (ETDEWEB)

The microstructure of the layers produced by plasma nitriding austenitic stainless steel at different treatment temperatures (400 and 500 C) were studied by transmission electron microscopy (TEM) together with X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results show that the microstructures were composed of 'expanded austenite' ({gamma}{sub N}) and {alpha}(ferrite)+CrN following plasma nitriding at lower and higher treatment temperatures, respectively. The former contains stacking faults and deformed twin substructures, while the latter is made up of colonies displaying a lamellar structure. Kurdjumov-Sachs or Nishiyama-Wassermann orientation relationships between the {alpha} and CrN layer were observed. (orig.)

International Nuclear Information System (INIS)

The possible corrosion damage is discussed of the CrNi and CrNiMo types steels used as structural materials in WWER type nuclear power plants. It includes point and slot corrosion, corrosion cracking and corrosion fatigue as well as corrosion denting. Also discussed are test procedures that simulate operating conditions and are used for assessing the properties of metallurgical products (sheets and tubes) used in nuclear power engineering. Briefly described is a system for testing the said products in an aqueous medium while keeping the test parameters in a narrow range for a long time. Under the defined temperature, pressure and corrosion medium composition, the test specimens in this system can mechanically be loaded, both statically and dynamically or a temperature gradient can be produced at the tube-tube plate joint. (Z.M.). 1 fig., 1 tab., 10 refs.

Energy Technology Data Exchange (ETDEWEB)

Simultaneous nitriding and ageing heat treatments of precipitation hardenable tool steel was carried out inside a DC-pulsed plasma nitriding reactor. A single heat treatment cycle was done, as the plasma nitriding and age hardening processes occur approximately at the same ranges of temperatures and times. Specimens of Cr-Ni-Mo-Al age hardenable steel, in the solubilized and solubilized and aged conditions, were tested. Plasma nitriding and ageing, carried out at 500 deg. C for times ranging between 2 and 8 h, increased the surface hardness up to 1000 HV, producing case depths between 100 and 200 {mu}m. The core hardness of solubilized samples increased from 30 to 39 Rockwell C after the plasma nitriding treatment proving the possibility of nitriding and ageing at the same treatment cycle. The pre-aged samples did not show any overageing after the simultaneous plasma nitriding and ageing treatments. The corrosion resistance ...

Energy Technology Data Exchange (ETDEWEB)

In this paper, we report on a series of experiments designed to study the influence of plasma nitriding on the mechanical properties of austenitic stainless steel. Plasma nitriding experiments were conducted on AISI 304L steel in a temperature range of 375-475 C using pulsed-DC plasma with different N{sub 2}-H{sub 2} gas mixtures and treatment times. Firstly the formation and the microstructure of the modified layer will be highlighted followed by the results of hardness measurement, adhesion testing, wear resistance and fatigue life tests. The modified surface was analyzed directly after plasma nitriding as well as using a depth profiling method. The microhardness after plasma nitriding is increased up to 19 GPa, that is a factor of five higher compared to the untreated material (3.3 GPa). The adhesion is examined by Rockwell indentation and scratch test. No delamination of the treated layer could be observed. The wear rate after plasma ...

Energy Technology Data Exchange (ETDEWEB)

A fractographic and numerical approach is presented to analyze hydrogen-plasticity interactions in pearlitic steel and to elucidate the main hydrogen transport mechanism in this material under triaxial stress states produced by notches. Fractographic analysis showed that the microdamage produced by the hydrogen was clearly detectable by scanning electron microscopy (SEM), through a specific microscopic topography associated with hydrogen effects (tearing topography surface or TTS). Numerical computations obtained by using an elastic-plastic finite element program gave the progressive spreading of the plastic zone, closely associated with the movement of dislocations. In the majority of cases, the plastic zone (PZ) clearly exceeds the hydrogen affected region (TTS) and has no relation with it. In some tests, however, the hydrogen-induced micro-damage surpasses the only region in which there is dislocation movement, and in ...

Energy Technology Data Exchange (ETDEWEB)

The use of nitrogen ion implantation to increase the surface hardness of structural steels is well documented. Traditionally this involves the use of high energy nitrogen ion beams (approximately 100 keV), with a relatively low beam current density because high energy beams are necessary to produce the required penetration into the material to achieve a significant depth of hardened material. Hardening needs to occur in a region whose size is comparable with the scale of the deformation associated with the tribocontact. 100 keV nitrogen ions typically penetrate into steels only about 0.1 {mu}m and the range of possible tribological applications is thus restricted by this shallow treatment depth. In plasma nitriding processes the nitrogen ions approach the substrate with much lower energies but the ion currents are sufficiently high to cause considerable substrate heating. In this study an ion beam process has been used ...

CERN Document Server

Specification of the steel sheet for the 300 GeV magnet system

International Science & Technology Center (ISTC)

Development of the Corrosion Protection Technology for Special Steels and Alloys

Energy Technology Data Exchange (ETDEWEB)

This report discusses the current state and the future of the Dutch basic metal industry. The steel industry and the aluminium industry are discussed in detail. First their current energy use, the technology and their product markets are analysed. The competitiveness of Dutch and Western European producers is discussed. Main technological developments and other key issues (especially future CO2 policies) are analysed. Based on this analysis, scenarios are developed for the energy use in the basic metal industry for the period 2000-2020. 88 tabs., 55 figs., 143 refs.

Science.gov (United States)

In this project the influence of residual compression stresses on the stress corrosion cracking behaviour of the turbine disc steel 26 NiCrMoV 14 5 (Rp(sub 0.2) = 850 N/mm(sup 2)) was investigated. The residual compression stresses were produced by shot p...

International Nuclear Information System (INIS)

... NOU TsIPK; Obninsk (Russian Federation) 978-5-85855-125-6 208 p.

UK PubMed Central (United Kingdom)

The treatment of brain disorders is one of the greatest challenges in drug delivery because of a variety of main barriers in effective drug transport and maintaining therapeutic concentrations in the...Full Text Available

International Nuclear Information System (INIS)

In this work, the effects of the focus ion beam (FIB) milling process on the optical properties of semiconductor nanostructures were investigated. With this aim, a sensitive materials system based on InGaAs/GaAs quantum dots with well known and excellent optical properties was selected for the FIB treatment. The FIB technique was used to locally remove a metallic mask deposited on top of the quantum dot sample. The photoluminescence (PL) signal, collected from the circular openings, was used to infer the possible damage effects of the ion beam on the properties of the dots.

Energy Technology Data Exchange (ETDEWEB)

The possibilities for heat recovery in a cast iron melting furnace were studied. A cupola furnace which produces 40 tonnes steel per hour, produces 25,000 Nm/sup 3//h of flue gases which contain 16-22% CO. Taking into account the heat losses at the chimney where fumes are cooled to 200/sup 0/C the recoverable heat is about 12.4-10/sup 6/ kcal/h which mainly consists of combustion heat in CO. This study showed that the heat can be used for the production of electricity, which will be used in the plant. Recovery of 87 kWh of electricity per tonne of steel produced is possible. A steam turbine driven generator of 3.5 MW will be required. The combustion of the low calorific gas (approximately 400 kcal/Nm/sup 3/) has been studied and gave positive results: wet CO gas can be burnt without addition of methane and preheating of air is not required. The pilot plant consisting of a thermic ...

International Nuclear Information System (INIS)

Full text of publication follows: Low activation ferritic/martensitic steels are receiving a high priority in the European long term materials research. Although extensively investigated, the available experimental data do not cover all required parameter ranges and cannot unambiguously be used to produce hardening/embrittlement trend curves. Therefore, the main objective of this work is to provide a physically-based engineering model offering a rational to experimental observations. From the literature, experimental data were selected to establish a database that mainly consists of 8 to 9Cr-steels irradiated in the range of 50 to 600 deg. C up to 30 dpa and with a He-content up to 5000 appm. The database includes neutron and proton irradiations, He-implanted as well as B- and Ni-doped steels. Because of the difficulty of interpretation inherent to the Charpy impact test, only tensile data were ...

Energy Technology Data Exchange (ETDEWEB)

In the present paper the tribological behavior of the coatings are discussed. Duplex coatings were applied on cold working steel 100Cr6. Samples were plasma nitrided at different thickness of plasma surface layers. TiN was deposited with a classic BALZERS PVD equipment and subsequent ion implantation. Ion implantation was provided with N{sup 5+} ions. The other samples were produced with IBAD technology in DANFYSIK chamber. Wear resistance and exchanges of friction coefficient were measured with on-line test using special designed tribology equipment. Following the tests, the wear zone morphology and characteristics of surface layer structure as well as important properties were investigated by scanning electron microscopy (SEM) and X-ray diffraction analysis (XRD). Scratch adhesion testing was performed using commercially available equipment. Energy dispersive X-ray analysis (EDAX) of the wear-scars on pins provided essential information on ...

Energy Technology Data Exchange (ETDEWEB)

Described herein are the latest trends in rolling mill facilities toward the 21st. century and new techniques developed by Hitachi Ltd. These cover hot rolling facilities, such as two-stage twin, high crown control-roll cross mill, roll shaping machine and continuous hot rolling systems; cold rolling facilities, such as pickling line-tandem cold mill and other continuous systems; and fine steel rolling facilities, such as roll mill for very small diameter pipes and others to improve productivity and product quality. The other new techniques include systems to pursue reliability and maintainability, in which electric appliances, instruments and computers are integrated, or equipped with built-in large-capacity inverters and drivers. For hot rolling, the above techniques lead to development of a new system named Hi-HOT, which produces high-quality hot coils at a sufficient speed, while keeping rolled steel at a desired ...

Energy Technology Data Exchange (ETDEWEB)

Semiconducting properties of passive films formed on AISI 304 stainless steel grade were investigated by capacitances measurements in chloride containing aqueous solutions for different surface finishes: BA (bright annealing in hydrogen containing atmospheres) and 2B (standard annealing in oxidising atmospheres followed by pickling in acid, then water rinsing). Mott-Schottky analysis shows that for high enough electrode potential, and whatever the surface finish, the films behave like n-type semiconductors. 2B passive film appears to be more donor-doped than BA one and the density of donor states increases with chloride concentration. The electron donor levels are assumed to be generated by negatively charged cations vacancies produced by the chloride ions reaction with the outer passive film. This reaction looks easier for 2B than BA condition, which explains why BA resists better than 2B to pit nucleation.

Science.gov (United States)

The financial evaluation of capital and operating cost estimates for a dry coke quenching facility installation indicates a marginal return on investment if the evaluation is based exclusively on steam credits. However, the potential improvements in environmental emissions and reported, but unverified, blast furnace operations may justify the expenditure. The Russian and Japanese claim of 2 to 4% reduction in blast furnace coke usage with up to 4% increase in iron production has not been demonstrated in the domestic steel industry and, therefore, is not included in the financial analysis. A 2% coke reduction represents a savings of approximately $0.81 per ton of hot metal produced or an additional annual credit of $1,800,000 for dry coke quenching, exclusive of productivity gains. Additional credit of this magnitude would increase the estimated discounted cash flow return from 10% to approximately 16% for the estimated capital expenditure of ...

Energy Technology Data Exchange (ETDEWEB)

Mono-dispersed cubic CeO{sub 2} nanoparticles have been synthesized using a surfactant-assisted method with laurylamine hydrochloride and cerium alkoxide modified with acetylacetone in an aqueous solution system. The prepared cubic CeO{sub 2} nanoparticles had a highly crystallized structure at 353 K and formed rod-like structures by calcination at 673 K after freeze-drying the CeO{sub 2} gel. We discovered a clear potential to make 1D, 2D or 3D CeO{sub 2}-materials with a well-controlled characteristic length and shape by assembling cubic-shaped CeO{sub 2} nanoparticle building blocks. CeO{sub 2}-TiO{sub 2} composite nanostructures have also been synthesized by changing the mole ratio of cerium alkoxide/titanium alkoxides. By utilizing the redox characteristic of CeO{sub 2}, CeO{sub 2} nanoparticles and CeO{sub 2}-TiO{sub 2} composite nanostructures after calcination, showed reaction activity toward the oxidization of I{sup -} to I{sub 2}, due ...

Science.gov (United States)

A post-accident-heat-removal structural effects analysis for the steel liner in the FFTF concrete containment structure is presented. (JWR)

Science.gov (United States)

The Energy crisis happens to be one of the greatest challenges we are facing today. In this view, much effort has been made in developing new, cost effective, environmentally friendly energy conversion and storage devices. The performance of such devices is fundamentally related to material properties. Hence, innovative materials engineering is important in solving the energy crisis problem. One such innovation in materials engineering is porous materials for energy storage. Porous electrode materials for lithium-ion batteries (LIBs) offer a high degree of electrolyte-electrode wettability, thus enhancing the electrochemical activity within the material. Among the porous materials, mesoporous materials draw special attention, owing to shorter diffusion lengths for Li+ and electronic movement. Nanostructured mesoporous materials also offer better packing density compared to their nanostructured counterparts such as nanopowders, nanowires, ...

International Nuclear Information System (INIS)

A mass separated focused ion beam (FIB) is a very useful tool to fabricate nanostructures by writing implantation within an ion beam synthesis process. In these investigations the IMSA-OrsayPhysics FIB, equipped with a Co_3_6Nd_6_4 alloy liquid metal ion source, was applied. Si(100) and (111) wafers were implanted with 60 keV Co"+"+ ions in the dose range of 2 . 10"1"6 to 2 . 10"1"7 cm"-"2. Implantation parameters were investigated, like pixel dwell time, relaxation time (time between two cycles), dose rate as well as the pixel overlapping factor. The subsequent annealing was done in a two step process, namely 600 deg. C for 60 min and 1000 deg. C for 30 min in a N_2 ambient. The results obtained by SEM investigations in terms of continuous nanowire structures following the direction and interrupted CoSi_2 pattern in the direction show a clear dependence on the time scale as well as the scanning mode of the irradiation. Structure sizes as small as 10 nm are ...

Energy Technology Data Exchange (ETDEWEB)

This book discusses problems and topics important for the design and construction of fixed offshore platforms used for drilling and producing petroleum from beneath the sea. A general description of offshore platforms serves as an introduction to the whole problem of offshore structures. A chapter on the hydrodynamic analysis of fixed offshore platforms gives the basis for the layout and construction of such structures. A guide to soil investigation methods essential for the geotechnical analysis of foundation designs for all types of offshore structures concentrates on the instrumentation equipment actually used. Detailed information is given on pile foundations with special emphasis on steel jacket platforms. The behaviour of gravity platforms during the final construction stage is analysed. The basis for the design of subsea pipelines and their stability is treated as well as the scour protection near offshore platforms.

CERN Document Server

In order to reduce the activation temperature of the TiZrV alloy, thin films of various compositions were produced by three-cathode magnetron sputtering on stainless-steel substrates. For the characterisation of the activation behaviour the surface chemical composition has been monitored by Auger electron spectroscopy during specific in situ thermal cycles. The volume elemental composition of the film has been measured by energy dispersive X-ray spectroscopy and the morphology (crystal structure and size of the crystallites) has been investigated by X-ray diffraction. The criteria indicating the sample quality and its dependence on film structure and chemical composition are presented and discussed. (13 refs).

British Library Electronic Table of Contents (United Kingdom)

A test bench was designed and assembled to carry out impact tests on samples and components. The system allows simple and rapid adjustment of the test parameters, such as the shot size and air pressure, with good repeatability of the results. Tests on steel and light alloys were carried out under both as-produced condition and on thin hard-coated samples. Significant reductions in dimple dimensions were seen after coating. FE models simulating the experiments overestimated the dimple depths, although the parameter trend was satisfactorily captured. The residual stresses from coating and shot peening determined numerically are believed to have been proven effective against fatigue.

British Library Electronic Table of Contents (United Kingdom)

Background, aim, and scope Semi-trailers with load boxes are the most important mode of grain transport by land in the world. Load boxes can be produced with different materials such as: wood, steel, and synthetic material. They are responsible for effectiveness retention and quality of grains during the transport. Among the main aspects to be considered and valued when selecting materials for load boxes are the final mass of the semi-trailer, loss of grains, and mechanical properties. Environmental performance is another important aspect to be taken into account for developing and selecting new materials in this kind of application. This study presents a comparative environmental evaluation of load boxes built from two different materials (a wood panel and a three-layer synthetic (TLS) pa...

International Nuclear Information System (INIS)

This report discusses the work done on EPRI program S149-1. In this program the feasibility of cleaning steam generators off line with organic chelants as a means of arresting denting corrosion was investigated. The rationale behind this program is to make use of those periods during which nuclear steam generators are in cold shutdown or wet layup to carry out a low-temperature soak with a combined chelant-inhibitor solution in order to dissolve some of the magnetite which has built up in crevices and to concomitantly remove entrained corrodents such as chloride ion. It was hoped that these soaks would be effective in reducing carbon steel support plate corrosion which produces tube denting.

International Nuclear Information System (INIS)

The evolution of metallic substance atomic structure is studied on temperature variation including crystal heating up to melting points, a crystal- liquid phase transition and initiation of a high-density liquid specific structure. It is marked that heat induced changes of simple metal structure can be described as changes around a natural elementary cell which is common for both a crystal and a liquid and consists of a central atom and Z_1 atoms of the first coordination sphere. On this basis the vacancy model of melting is verified. Concentrations of melting vacancies are determined by coordination numbers in the form of Z_1/(1+Z_1)"2 which are the same for both a crystal and a natural elementary cell. The size of natural elementary cells is in an agreement with that of the coordination sphere featured in the liquid and phase transition statistical theory. Calculated data are given for a number of metals, Cs, Eu, Ni, V included

British Library Electronic Table of Contents (United Kingdom)

Modifications of the structure and mechanical properties in LiF crystals irradiated with MeV-energy Au ions have been studied using nanoindentation, atomic force microscopy and optical spectroscopy. The nanostructuring of crystals under a high-fluence irradiation (above 1013 ions/cm2)?was?observed. Nanoindentation tests show a strong ion-induced increase of hardness (up?to 150?200%), which is related to the high volume concentration of complex color centers, defect aggregates, dislocation loops and grain boundaries acting as strong barriers for dislocations. From the?depth profiling of the hardness and energy loss it follows that both nuclear and electronic stopping mechanisms of MeV Au ions contribute to the creation of damage and hardening. Whereas the electronic stopping is dominating i...

British Library Electronic Table of Contents (United Kingdom)

The aim of this study was to develop a nanostructured Nb2O5-natural hydroxyapatite bulk composite to serve as an alternative biocompatible bulk material for implants. A set of samples of hydroxyapatite from fish bones with different concentrations of Nb2O5 were designed. They were prepared through a milling process, compacted under different pressures (350, 450, 550 and 650MPa) and sintered in air atmosphere at 1000^oC for 1h. The results revealed that the prepared composites presented strong interactions between the two elements and showed improvement in the sinterability with significant densification and microstructure changes, suggesting that they are promising for implants meant to replace bone tissues.

Energy Technology Data Exchange (ETDEWEB)

Austenitic stainless steels (304-type) have been implanted with nitrogen ions in order to investigate the effects of implanted nitrogen on their electrochemical behaviour and on the nature of the passive film formed on the steels in acid (0.5M H{sub 2}SO{sub 4}). Alloys with two nitrogen doses have been prepared (2.5x10{sup 16} and 2x10{sup 17} N atoms/cm{sup 2}). The implanted alloys have been characterized by {sup 15}N-NRA (nuclear reaction analysis) and XPS (X-ray photoelectron spectroscopy). Alloy surfaces with well-defined N concentrations were prepared, prior to the electrochemical measurements, by argon-ion sputtering of the implanted material for a fixed time in order to reach a well-defined point on the nitrogen depth profile. The samples were then transferred without exposure to air to an electrochemical cell mounted in an inert gas glove box. The implanted nitrogen modifies the electrochemical behaviour of the alloy. The anodic ...

Energy Technology Data Exchange (ETDEWEB)

The influence of high C martensite on the strength and impact behavior of C-Mn-Nb-Al steels has been determined for two distributions: films surrounding the ferrite grains and distinct colonies. In the former case, the impact behavior markedly deteriorated, this deterioration increasing with martensite level. The changes in impact behavior could be explained by regarding the films of martensite as being similar to the brittle grain boundary carbides that are present in ferrite-pearlite steels. These films readily crack, yet are always thick enough to produce a sufficient wide crack to render crack propagation easy. The critical event in fracture then becomes the ability to propagate the cracks through the grain boundaries. The greater the grain boundary coverage by these films, the easier this becomes and the worse is the impact behavior. When the martensite is present as colonies, again the impact performance is seriously ...

Energy Technology Data Exchange (ETDEWEB)

The first part of a systematic investigation is presented of surface treatments affecting the fatigue behavior of smooth and notched quenched and tempered (Q and T) specimens made of a B-Mn SS2131 ({approx}AISI 15B21H) steel. In this part, the effects of plasma nitriding (nitriding temperature=480 C, time=24 h) on the fatigue strength and notch sensitivity were investigated. Constant stress amplitude plane reversed bending fatigue tests (R=-1) at 47 Hz were conducted using cylindrical plasma nitriding (PN) and Q and T steel specimens with K{sub t}=1.05 and 1.7. The compound layer was found to consists of {epsilon}-phase and {gamma}`-phase. S-N curves show that plasma nitriding improves the fatigue limit by 53 and 115% of Q and T smooth and notched specimens, respectively. The fatigue strength of smooth specimens is improved through the whole fatigue life but only for long fatigue lives for notched specimens. Plasma nitriding reverses the low ...

Energy Technology Data Exchange (ETDEWEB)

Two mechanical design requirements are defined for the SSC Collider beam tube. First, the vacuum requirement (luminosity lifetime = 150 hrs). It requires the design of a pressure boundary within the cold mass vessel to provide a vacuum tunnel for the proton beam and to minimize the synchrotron radiation gas desorbtion with a suitable material. The Collider beam tube design is under an intensive activity to search for a material that will meet the luminosity requirement without a distributed pump or liner. Second is the tube wall`s resistivity requirement ({sigma}*t = 2E5 {Omega}{sup {minus}1}). For a 4.2 K beam tube the Cu thickness is 100 {mu}m (RRR=30,6.7 T, {sigma}=2E9{Omega}{sup {minus}1}m{sup {minus}1}). The copper yield strength is relatively low in comparison to steel and, therefore, the design of the steel layer is governed by the copper layer yield stress limit. A beam tube subjected to eddy current load in a quenching dipole requires ...

Energy Technology Data Exchange (ETDEWEB)

The Partnership for a New Generation of Vehicles (PNGV) program intends to develop new designs for automobiles that will reduce fuel consumption by two thirds but otherwise have price, comfort, safety, and other measures of performance similar to the typical automobile now on the market. PNGV vehicle designs are expected to substitute lightweight materials, such as aluminum, magnesium, carbon-reinforced polymer composites, glass-reinforced polymer composites, and ultra- light steel, for heavier materials such as steel and iron in automobile components. The target mass of a PNGV vehicle is 1,960 pounds, as compared to the average current vehicle that weights 3,240 pounds. Other changes could include the use of different ferrous alloys, engineering changes, or incorporation of advanced ceramic components. Widespread adoption of these vehicle designs would affect materials markets and require concurrent development and adoption of supporting ...

Energy Technology Data Exchange (ETDEWEB)

The automotive industry desires to optimize safety and lightweight construction for the production of cars and trucks. The resulting task for steel suppliers is to make steel grades available that can fulfil these requirements. Different projects have shown optimistic outlooks for optimization of safety and reduction of the weight of automobile bodies by using different high strength and ultra high strength steels. In the last group the dual phase steels play the lead. In recent years different steel grades have been developed and optimized for these applications. On one hand developing the mechanical properties as well as joining and forming of dual phase steels is one of the first steps. On the other hand different coated surfaces for various applications of dual phase steels is another step. Starting with characteristic production ...

UK PubMed Central (United Kingdom)

After slow progress in the efforts to develop phase plates for electron microscopes, functional phase plate using thin carbon film has been reported recently. It permits collecting high-contrast images...Full Text Available

International Nuclear Information System (INIS)

Nanocrystalline materials can exhibit properties which are considerably different from their coarse-grained counterparts, making them unique for basic or applied research and also very promising for potential applications. The topics which are addressed in the present paper are magnetic properties and magnetic correlations on the nanometer scale, mechanical properties, in particular the influence of grain boundaries on the elastic and plastic behaviour, and vibration models of grain boundary atoms in nanostructured materials. (author)

British Library Electronic Table of Contents (United Kingdom)

Deposition of CN-based films by a novel version of active screen plasma nitriding, aiming at surface modification of polymers, is reported. The approach relies on the use of pure graphite as the grid material, which was found to act both as an active screen and as a dry source of carbon atoms for the synthesis of thin films consisting mainly of a stoichiometric CN layer with columnar-type structure and dome-like nanostructured morphology.

International Nuclear Information System (INIS)

A variety of advanced controlled rolling techniques have been developed to improve toughness, strength and weldability of niobium-steels. To achieve optimum properties, control of prior stage rolling conditions and accelerated cooling are needed. In low carbon steel, the addition of niobium results in a greater increase in tensile strength than that of vanadium without a loss of toughness. At the same strength level, niobium-steel has less susceptibility to weld cracking and good toughness in the HAZ of its weldments than similar vanadium steels. Separation and formability of niobium steels are also discussed.

Energy Technology Data Exchange (ETDEWEB)

Microalloyed or high strength low alloy (HSLA) steels are carbon-manganese steels containing small amounts of Nb, V or Ti. The excellent mechanical properties of these alloys, particularly high yield strength, usually obviate the need for expensive quench and tempering operations. Furthermore, the presence of a significant amount of nitride-forming elements in some microalloyed steels has generated interest in the applicability of these alloys as a new generation of nitriding steels. In this paper, a study of the plasma nitriding behaviour of a commercially available microalloyed steel MAXIMA{sup TM} is reported. A comparison is made with a traditional quenched and tempered nitriding steel (En19), plasma nitrided under similar conditions. Optical and scanning electron microscopy in conjunction with microhardness measurements and X-ray diffraction were utilized ...

International Science & Technology Center (ISTC)

Corrosion- and Wear Resistant Silicon Containing Chromium-Manganese and Nickel-Chromium-Manganese Nonmagnetic Steels with Increased Strength and Toughness for Reliable Work at Normal and Cryogenic Temperatures

International Nuclear Information System (INIS)

The ion nitriding treatment is a process widely used in steel alloys to improve the material's properties; such as surface hardness, resistance to wear, fatigue life and resistance to corrosion. But geometric changes in the components can produce during the nitriding process different effects on the behavior of the plasma, such as local variations in the electric field, an empty cathode effect, etc. These in turn can affect among other factors the local temperature and therefore the kinetics of the process, generating variations in the compound layer thicknesses and zone of diffusion, and micro-hardness profile. These heterogeneities limit the effectiveness of the plasma nitriding process, where control and duplication of the surface modification are most important. This work aims to study the effect of the geometry of the pieces treated with ionic nitriding, especially the effect of the orifices. An understanding of the operating mechanisms is ...

International Nuclear Information System (INIS)

Radiation hardening in austenitic stainless steels is shown to modify deformation characteristics and correlate well with an increased susceptibility to intergranular stress corrosion cracking (IGSCC). Available data on neutron-irradiated materials have been analyzed and correlations developed between fluence, yield strength and cracking susceptibility in high-temperature water environments. Large heat-to-heat differences in the critical fluence (0.2 to 2.5 x10"2"1 n/cm"2) for IGSCC are documented. In many cases, this variability is consistent with yield strength differences among irradiated materials. IGSCC correlates better to yield strength than to fluence for most heats suggesting a possible role of radiation-induced hardening and microstructure on cracking. Microstructural evolution during proton and heavy-ion irradiation has been characterized in low-carbon 304SSs. Hardening results from a dispersion of dislocation loops in the matrix which increase in ...

Energy Technology Data Exchange (ETDEWEB)

A dipole magnet based on the common coil design, using prereacted Nb{sub 3}Sn superconductor, is under development at Fermilab, for a future Very Large Hadron Collider. This magnet has some innovative design and technological features such as single layer coils, a 22 mm wide 60-strand Rutherford type cable and stainless steel collars reinforced by horizontal bridges inserted between coil blocks. Both left and right coils are wound simultaneously into the collar structure and then impregnated with epoxy. In order to optimize the design and fabrication techniques an R&D program is underway. The production of cables with the required characteristics was shown possible. Collar laminations were produced, assembled and tested in order to check the effectiveness of the bridges and the validity of the mechanical design. A mechanical model consisting of a 165 mm long section of the magnet straight section was assembled and tested. This paper ...

International Nuclear Information System (INIS)

A series of experiments have been conducted on AISI 5140 low alloy steel using a hollow cathode discharge-assisted plasma nitriding apparatus with the aim of elucidating the role of substrate bias voltages in plasma nitriding process. For comparison, some samples were nitrided with applied substrate bias (-50 V) while other samples were nitrided at floating potential. Treatments were carried out in NH_3 atmosphere of 150 Pa at temperatures ranging from 450 "oC to 550 "oC for 2 h, 4 h, and 6 h. The nitrided samples were characterized by optical microscopy, X-ray diffraction and micro-hardness measurement. The corrosion behaviors were evaluated using anodic polarization tests in 3.5% NaCl solution. The results showed that the microstructure and phase constituents of the nitride layers were strongly influenced by the bias voltages. It was also demonstrated that the better corrosion resistance with a thicker nitrided layer was obtained on the biased sample.

International Nuclear Information System (INIS)

Liquid radioactive raffinates from nuclear fuel reprocessing at the Idaho National Engineering and Environmental Laboratory were solidified, or calcines, in a fluidized bed reactor at approximately 500 C to form a dry granular material. This calcine has been provisionally stored near-surface in concrete-encased stainless steel bins at the Idaho Nuclear Technology Engineering Center. Research addressing the permanent immobilization of radioactive waste has been ongoing. One option is to separate the radioactive constituents from the calcine, thereby reducing the radioactive waste volume to be ultimately stored at a national nuclear waste repository. Nitric acid dissolution of the calcine is a key front-end unit operation in the separations option. In order to design calcine dissolution equipment, quantification of dissolution reaction rate parameters is required. A pilot-plant-produced, non-radioactive calcine was utilized to study the ...

Energy Technology Data Exchange (ETDEWEB)

A new material has been developed for welded low-pressure shafts in steam turbines. Nine test welds were examined in order to confirm the chemical analysis. A shaft disc with an optimized composition was produced and destructively tested. The new material demonstrates, both in a total forging and also in a joint weld examined, excellent strength and toughness characteristics as well as excellent resistance to corrosion. Accordingly, all the requirements for welded low-pressure shafts in steam turbines are fulfilled. (orig.) [Deutsch] Fuer geschweisste Niederdruckwellen in Dampfturbinen wurde ein neuer Werkstoff entwickelt. Zur Festlegung der chemischen Analyse wurden 9 Versuchsschmelzen untersucht. Mit optimierter Zusammensetzung wurde eine Wellenscheibe hergestellt und zerstoerend untersucht. Der neue Werkstoff zeigt sowohl im gesamten Schmiedestueck als auch in einer untersuchten Verbindungsschweissung gute Festigkeits- und Zaehigkeitseigenschaften sowie gute ...

Energy Technology Data Exchange (ETDEWEB)

This paper evaluates abrasive jet wear tests, carried out on the ZUK-3M abrasion apparatus according to the GOSF 23.201-78 industrial standard. As abrasive material, brown coal coke dust, brown coal dust, power plant fly ash and quartz sand (for the purpose of comparison) were employed. Seventeen types of materials were blasted with abrasive jets, including a selection of steels, glass, rubber, SYS-pur plastics, cast basalt, Kawenit and vitroceramics. The test apparatus produced abrasive jet velocities between 12 and 130 ms/SUP/-/SUP/1 at rotor revolutions of 1,000 to 10,000 min/SUP/-/SUP/1. Blasted material samples were arranged at angles between 15 and 90 degrees. Various tables and graphs present abrasivity results. These results were employed for technical modifications of dedusting equipment in briquetting and coking plants, which led to a threefold increase in service life of abrasion endangered equipment parts. (8 refs.) (In German)

Science.gov (United States)

... Title : THE INFLUENCE OF GRAIN BOUNDARY CARBIDE DENSITY ON THE BRITTLE FRACTURE OF FERRITE PEARLITE STEELS. ...

Science.gov (United States)

Not Available

KoreaScience (Korea)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Short communication

International Nuclear Information System (INIS)

... Engineering, Kitakyushu, Fukuoka (Japan) Hattanda, Takumi NTT Advanced

Energy Technology Data Exchange (ETDEWEB)

The investigated hybrid nanocomposite consists of a porous silicon template with electrochemically embedded Ni or Co nanostructures and offers magnetic characteristics which can be tailored by the electrochemical process parameters during fabrication. A twofold magnetic behaviour can be observed, a first one due to the spinmagnetism at magnetic fields below the saturation magnetization of the deposited metals and a second non-saturating term at higher fields (>1 T up to 7 T) above the saturation magnetization. In case of Ni deposited within the pores this non-saturating term shows a paramagnetic characteristic and follows exactly the Curie-Weiss law, whereas for Co/porous silicon samples the temperature dependent magnetization shows some deviations from the Curie Weiss law. In this high field region a difference in the temperature dependence between Ni and Co is observed whereas the non-saturating term does not depend on the geometry of the embedded ...

International Nuclear Information System (INIS)

Spherical nanostructured Si/C composite was prepared by spray drying technique, followed by heat treatment, in which nanosized silicon and fine graphite particles were homogeneously embedded in carbon matrix pyrolyzed by phenol formaldehyde resin. Cyclic voltammetry tests showed two pairs of redox peaks corresponding to lithiation and delithiation of Si/C composite. The Si/C composite exhibited a reversible capacity of 635 mAh g"-"1 and good cycle performance used in lithium ion batteries. To improve cycle performance of this Si/C composite further, the carbon-coated Si/C composite was synthesized by the second spray drying and heat treatment processing. The cycle performance of carbon-coated Si/C composite was improved significantly, which was attributed to the formation of stable SEI passivation layers on the outer surface of carbon shell which protected the bared silicon from exposing to electrolyte directly.

International Nuclear Information System (INIS)

In the present work the hydrogen desorption properties of nanostructured magnesium hydride (MgH2) synthesized by controlled reactive mechanical milling (CRMM) of elemental Mg powder under hydrogen are investigated. A profound effect of the particle size of synthesized MgH2 hydride on its hydrogen desorption characteristics measured by differential scanning calorimetery (DSC) has been found. All synthesized MgH2 powders are characterized by a double hydrogen desorption peak. Furthermore, below a certain threshold particle size the DSC desorption temperature of the peak doublet starts decreasing rapidly with decreasing of the mean hydride powder particle size (expressed as equivalent circle diameter-ECD). In contrast, the nanograin (crystallite) size of MgH2 does not seem to have apparent effect on the DSC desorption temperature. It is also observed that for powder particles smaller than some threshold value, X-ray diffraction shows the presence of two polymorphic ...

International Nuclear Information System (INIS)

In the present paper it is assumed that above a limiting value of fission fluency (burn-up) a more intensive process of irradiation introduced chemical interaction occurs. A significant part of fission gas product is thus expected to be chemically bounded in the matrix of UO_2 fuel. The fission gas atoms substituting, for example, uranium atoms in the crystallographic lattice can form weak facets. At a certain saturation condition, division of the grains can occur at the weak facets and the increase in fission-gas products release may be expected. The fact that the process of grain division for high burn-ups (70-80 MWd/kgU) forms an extremely fine structure up to the temperature as high as 1100 "oC and simultaneously the observed decreases in fission gas concentration in the fuel supports this concept. The analysis of fission gas concentration change due to the formation of nanostructures in UO_2 fuel at high burn-ups in terms of total surface area change in a ...

Energy Technology Data Exchange (ETDEWEB)

Previously we have used atomic force anodisation lithography, with a self-assembled monolayer of hexadecyltrichlorosilane as a resist, to pattern silicon oxide nanostructures onto a p-type silicon (1 0 0) substrate. A condensation reaction was used to immobilise carbon nanotubes with high carboxylic acid functionality directly to the silicon oxide. A further condensation reaction using this surface attached the molecule ferrocenemethanol to the bound nanotubes. These new nanostructures were used as electrodes to observe the oxidation and reduction of ferrocene. However, because the small currents measured are near the detection limits of the electrochemical system used, important electrode kinetics could not to be obtained. A scribing approach made larger regions of oxidised silicon leading to the creation of larger scale patterned arrangements of carbon nanotubes allowing measurement of important electrochemical parameters such as electrode ...

International Nuclear Information System (INIS)

Both the price of nickel and the allergic reaction that it can cause to human beings make it desirable to develop and use nickel-free austenitic stainless steels. The steels should be austenitic so as to avoid ferro-magnetism, a condition which has to be fulfilled for a number of requirements, including its use as implants in the human body, for wrist watch cases and many others. The paper presents the development of a nickel-free steel containing 11 percent manganese, 17 percent chromium, 4 percent molybdenum, and 0.9 percent nitrogen. This austenitic stainless steel has exceptional strength and corrosion resistance. These properties could result in numerous applications of the steel. A limitation, however, is that the steel is not weldable.

Energy Technology Data Exchange (ETDEWEB)

In this book over 250 alloys are organized by AISI number into 10 major sections: Irons, Carbon Steels, Alloy Steels, Low Alloy Constructional Steels, Ultra High Strength Steels, Tool Steels, Maraging Steels, Wrought Stainless Steels, Heat Resistnat Casting Alloys, and Iron Based Rought Superalloys. Each alloy record lists the designation, specifications, UNS number, composition, product forms and a comment on the high-temperature properties and applications. Referenced data is then given for physical properties such as density, specific heat, thermal conductivity, thermal expansion, electrical conductivity, Poisson's ratio, moduli of elasticity and rigidity, etc. Mechanical properties follow, and include tensile properties, shearing and bearing properties, impact properties, creep, stress rupture and stress relaxation and fatigue ...

International Nuclear Information System (INIS)

We explore the relation of nanostructures with the appearance of giant magnetoresistance (GMR) in melt-spun CuCo ribbons. We find by energy-filtered transmission electron microscopy that the ribbons are composed of a periodic distribution of Co within the Cu, as in spinodal decomposition. The lamellar structure should thus be associated with GMR, as only a small percentage of the Co is present in the form of grains. This is counterintuitive, for no clear interfaces are present as required by standard models, and the period of the composition oscillation (43-52 nm) is an order of magnitude larger than the mean free paths for electrons. Upon annealing, a secondary spinodal decomposition appears following the same direction as the original.

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We demonstrate the rapid optical characterization of large numbers of individual metal nanoparticles freely diffusing in colloidal solution by confocal laser spectroscopy. We find that hollow gold nanospheres and solid silver nanoparticles linked with a bifunctional ligand, both designed nanostructures, exhibit significantly higher monodispersity in their Rayleigh and Raman scattering response than randomly aggregated gold and silver nanoparticles. We show that measurements of rotational diffusion timescales allow sizing of particles significantly more reliably than can be obtained using translational diffusion timescales.

International Nuclear Information System (INIS)

Formation of the soft magnetic nanostructure in amorphous Fe_1_4Ni_4_0Zr_7B_1_2 alloy due to heat treatment is studied by the Moessbauer, differential scanning calorimetry, and X-ray diffraction techniques. Annealing at temperatures 520-580 "oC leads to the formation of extremely soft nanocrystalline alloy as revealed by the rf-Moessbauer measurements. The superparamagnetic behaviour was observed for the alloy annealed at 620-640 "oC. At higher annealing temperatures good soft magnetic properties deteriorate. (author)

International Nuclear Information System (INIS)

Several recent experiments on micro- (or nano-) structured samples of ferromagnetic materials are introduced. Magnetization reversal phenomena are investigated on submicron wire samples of trilayer structure using the giant magnetoresistance effect. Domain wall movements are sensitively monitored by resistivity measurements and the velocity of propagation is determined. The contribution of domain wall to the resistivity is argued from the results on artificially designed samples of a spring-magnet system. In circular dots of permalloy, the existence of vortex magnetization is confirmed and the reversal of the vortex core magnetization is studied from magnetic force microscopy measurements. (author)

Energy Technology Data Exchange (ETDEWEB)

Nanoparticles represent versatile building blocks in material science and nanotechnology. Thereby, the defined assembly of nanostructures (13 and 56 nm in diameter, respectively) is of significant importance. Short DNA sequences can be bound to the nanoparticle surface thus enabling highly specific DNA hybridization-driven events that direct the formation of nanoparticle constructs.In this paper, examples for the defined formation of gold nanoparticle constructs are demonstrated. In addition, gold-silver core-shell nanoparticles are introduced as further building blocks for the hybridization-controlled formation of nanoparticle constructs.

International Nuclear Information System (INIS)

Growing competitiveness of alternative manufacturing routes requires cost minimization in the production of drop forged components. The authors analyse the potential of medium carbon, vanadium microalloyed steels for drop forging. Laboratory and industrial experiments have been carried out emphasizing deformation and temperature cycles, strain rates and dwell times showing a typical processing path, associated mechanical properties and corresponding microstructures. The steels the required levels of mechanical properties on cooling after forging, eliminating subsequent heat treatment. The machinability of V-microalloyed steels is also improved when compared with plain medium carbon steels. (author)

International Nuclear Information System (INIS)

Recent data on resistance of modern corrosion-resistant austenitic-ferritic steels to different types of corrosion are generalized. It is shown that these steels are characterized by high resistance to general corrosion in acid, alkali, chloride and other solutions, are not inclined to intercrystalline, pitting and crevice corrosion and are noted for high resistance to corrosion cracking and corrosion fatigue. All this is combined with technological and economical effectiveness. It is advisible to use these steels instead of highly-alloyed and expensive steels and alloys in chemical, power and other industries. 59 refs.; 2 tabs.

Science.gov (United States)

Natural bone consists of hard nanostructured hydroxyapatite (HA) in a nanostructured protein-based soft hydrogel template (ie, mostly collagen). For this reason, nanostructured HA has been an intriguing coating material on traditionally used titanium for improving orthopedic applications. In addition, helical rosette nanotubes (HRNs), newly developed materials which form through the self-assembly process of DNA base pair building blocks in body solutions, are soft nanotubes with a helical architecture that mimics natural collagen. Thus, the objective of this in vitro study was for the first time to combine the promising attributes of HRNs and nanocrystalline HA on titanium and assess osteoblast (bone-forming cell) functions. Different sizes of nanocrystalline HA were synthesized in this study through a wet chemical precipitation process following either hydrothermal treatment or sintering. Transmission electron microscopy ...

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This paper describes the test results on high-temperature strength properties of fire resistant steel(FR steel) for building, the formulation, and the examples of application to member tests and actual buildings. Because of its components and manufacturing method, FR steel excels in strength at elevated temperature due to precipitation and dispersion strengthening. Tests on high temperature properties of FR steel showed that every property such as strength, stress-strain curve, elastic modulus, and creep performance at high temperature was superior to those of conventional steels. Then, it was confirmed in the tensile tests at room temperature and high temperature after heat history that FR steel could be reused after fire. It was also found in the member tests that columns and beams of FR steel could support loadings equivalent to long-term ...

International Nuclear Information System (INIS)

68 replaced carbon steel piping in secondary system of pressurized water reactor (PWR) has been investigated by visual examination for checking thinning conditions. It is well known that the flow-accelerated corrosion (FAC) was inhibited by traces of Cr in steel. Therefore, the chemical compositions of those steels have been measured. In addition, the micro structure and hardness of those steels have been investigated. And the relationship between those material variables and FAC rate was considered. As the results, (1) The Cr contents in those steels were below 0.1 wt% except one sample. Minute quantities of chromium increase the resistance against FAC. But the water velocity was thought to be the dominant factor rather than chemical composition in steel, at least such as below 0.1%Cr. (2) Hardness of all piping has been satisfied the specifications of each ...

International Nuclear Information System (INIS)

In the early 1980s, AECL built a Waste Treatment Centre (WTC) for managing low-level solid and aqueous liquid wastes for converting CANDU wastes. At present, two liquid waste streams are being treated at the WTC. The liquid waste streams are volume-reduced by a combination of continuous crossflow microfiltration (MF), spiral wound reverse osmosis (SWRO) and tubular reverse osmosis (TRO) membrane technologies. The concentrate produced from the TRO system and the volume-reduced MF backwash solutions are evaporated while simultaneously adding bitumen in a thin-film evaporator. A water-free product of chemical and radiochemical salts and bitumen is removed in 200-L galvanized steel drums for storage. The radiation field of product drums on contact typically has a value of 0.5 to 3 R/h depending upon the feed concentration of radioactivity to the evaporator. The total solids content in the 200-L drum ranges from 25 to 35%. Encapsulated in the ...

Energy Technology Data Exchange (ETDEWEB)

Four commercial stainless steels (mat. Nos. 1.4539, 1.4586, 1.4571 and 1.4462) were tested in 96% and 90% sulfuric acid of 80/sup 0/C as to their corrosion fatigue strength by subjecting notched round bars to the rotary bending test. At the same time, the efficiency of anodic protection was examined. With all four steels, the alternating bending strength obtained in the air is essentially reduced. The semiaustenitic steel Nr. 1.4462 shows a lower corrosion fatigue strength than the three austenitic steels. Although making the corrosion fatigue strength of steels better calculable, anodic protection proves insufficient to completely prevent notched round bars from corrosion fatigue in concentrated sulfuric acid.

Wastenet

...3 MtC, with 78% of these emissions from integrated steel making (26.9 MtC) and the rest (22%)...6 MtC, with 71% of these emissions from integrated steel making (21.9 MtC) and the rest (29%)...1 million ton of carbon (MtC) in 1994 (3.9 MtC from integrated steel making, and 2.2 MtC from secondary ...7 MtC in 2002 (3.7 MtC from integrated steel making, and 2.0 MtC from secondary steel making), corresponding ...

Energy Technology Data Exchange (ETDEWEB)

Sprayforming offers the possibility to produce a variety of preforms in a single step directly from the melt. Numerous processing parameters ensure high flexibility but require detailed knowledge concerning the microstructure of sprayformed material depending on chemical composition and processing parameters. Within the current study fundamental investigations using unalloyed and low alloy steel grades (C15, C105, 100Cr6) for sprayforming of plates and billets have been performed concerning the influence of chromium and carbon content and selected processing parameters. Sprayformed preforms revealed austenite grain sizes up to 500 {mu}m depending on the development of porosity. Different types of porosity have been detected which can be associated with incomplete densification due to high cooling rates, solidification shrinkage and entrapped nitrogen. Atomisation gas pressure and carbon content are parameters of primary importance. (Abstract ...

Science.gov (United States)

This study deals with the torsional response of Ti-8823 and 18Ni (200) maraging steel. The effect of different heat treatments and the subsequent change in microstructure are investigated. In the case of the Ti-8823, a comparison was made between the solu...

UK PubMed Central (United Kingdom)

OBJECTIVE: To study cause specific mortality and cancer morbidity in workers exposed to the dust of grinding materials, grinding agents, and stainless steel, especially with regard to a possibly increased...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared

Energy Technology Data Exchange (ETDEWEB)

Steel is one of the most versatile materials known to mankind. It is used in a variety of applications. In many of these applications, it is exposed to the atmosphere, leading to rust formation, which weakens structures made using steel. Hence, protection is important. The popular methods to prevent corrosion are painting, galvanizing, electroplating etc. The widely used Chrome etching process is very effective in corrosion inhibition as well as in hardening the steel. But, Chromium and its compounds are highly placed among the toxic chemicals listed under pollution prevention initiatives of the EPA. Hence, it was decided to find alternatives to this process.

Energy Technology Data Exchange (ETDEWEB)

In recent years, the phase stability of austenitic stainless steels, and its effect on the mechanical properties of stainless steels, have been the subject of much interest. With the availability of new experimental techniques, new theoretical methods, and new computational procedures, significant advances have been made in understanding, and being able to predict, phase stability and mechanical properties of stainless steel welds. This paper reviews some of these developments, with an emphasis on recent work that has been done at Oak Ridge National Laboratory.

International Nuclear Information System (INIS)

Mixed microstructures have been studied in low- carbon microalloyed steels suitable for automotive applications, after continuous cooling from the hot-rolled condition. Microstructural features such as polygonal ferrite, bainitic and acicular ferrite and microphase constituent are identified using transmission electron microscopy. The influence of these mixed structures on the tensile strength, impact toughness and fracture behaviour is examined. It is found that improvements in impact toughness as compared with microalloyed medium- carbon ferrite/pearlite steels can be achieved from these predominantly acicular structures developed by controlling alloy composition and continuous cooling of these lower carbon steels. (orig.).

International Nuclear Information System (INIS)

A study is made into microhardness and structure of coatings on various system steels (37G2S, 25Kh5M, R6M5), obtained by ion nitriding in a low pressure (10"-"1 Pa) arc discharge plasma. A comparison of properties is accomplished for steels nitrided in an arc gas discharge and in a furnace. It is stated that ion-plasma nitriding in an arc gas plasma generator is an efficient method of alloy steels hardening which allows changing the structure and increasing the hardness of a surface layer up to rather great depth

International Nuclear Information System (INIS)

The influence of microalloying vanadium or titanium on improving the corrosion resistance of mild steel in saturated calcium hydroxide solution was investigated. Potential-time, potentiodynamic polarization, and impedance measurement techniques were employed. The corrosion products have been examined by infrared and X-ray diffraction analysis and by scanning electron microscopy. It has been shown that the grain refining, due to microalloying, plays an important role in enhancing the corrosion resistance of steel. Scales of calcite and iron oxides on top of a protective oxide are formed on the investigated steels.

Energy Technology Data Exchange (ETDEWEB)

Short communication

International Nuclear Information System (INIS)

... Industry, Material Science Research Laboratory, Yokosuka, Kanagawa (Japan)

International Nuclear Information System (INIS)

... Yoshiaki Toshiba Corp., Nuclear Power Division, Yokohama, Kanagawa (Japan)

Science.gov (United States)

No abstract available.

Energy Technology Data Exchange (ETDEWEB)

Stress-rupture strength tests were made of metal steam pipe (12Kh1MF steel) in various conditions, the original, after aging under laboratory conditions (580{degrees}C, 10,000 h), and after long service. It was shown that the more the steel is hardened by heat treatment or cold plastic working in the original condition, the less it hardens in creep. It was established that softening in creep of steel with a moderate yield strength is caused primarily by aging and with a high yield strength by pore formation.

Energy Technology Data Exchange (ETDEWEB)

By magnetron sputtering model steel films with specific properties can be prepared for purposive surveys. By changing the deposition parameters certain properties of these films can be influenced. For this thesis steel films with 18% Cr and 8% Ni have been prepared in order to study specific parameters on the corrosion resistance of bulk stainless steel. Chemical composition, microstructure, and surface morphology of these films have been characterized. In comparison to bulk steel sheets with the same chemical composition they have a smaller grain size and a ferritic structure. In contrast to bulk steel sheets they don`t contain any nonmetallic inclusions like Mn-sulfides. The influence of these structural differences on the corrosion resistance has been studied. For this purpose the electrochemical properties of the sputter-deposited steels have been compared ...

International Nuclear Information System (INIS)

Structure of ferrite in drawn pearlitic steel containing 0.9 mass% C was investigated with X-ray diffraction technique using synchrotron radiation. In the detailed analysis of diffraction peaks of ferrite during the drawing process, it was experimentally revealed that the transformation of ferrite from bcc to bct due to the supersaturation of carbon in ferrite of heavily drawn pearlitic steel.

International Nuclear Information System (INIS)

Azobenzene dyes are effective inhibitors for austenitic 304 L and 316 L stainless steel corrosion in high acidic medium up to 7N. A good efficiency is obtained from weight loss and electrochemical Rsub(p) measurements in hydrochloric acid, while no inhibition is observed in sulfuric solutions. Transformation from the primarily azobenzene to other compounds give rise to enhanced protection of steel samples, and probable structures of the inhibiting species are proposed in view of our results.

International Nuclear Information System (INIS)

The pitting corrosion resistance of three different types of stainless steel implanted with silicon is investigated using the potentiokinetic polarization technique. The specimens are tested in 3% NaCl and 0.1 N HCl solutions. Silicon ion implantation inhibits pitting corrosion of the steels in both aqueous media. The corrosion resistance depends on the silicon dose. Post implantation annealing only slightly alters the localized corrosion. (author).

International Nuclear Information System (INIS)

Mutual influence of phosphorus and carbon on the tendency to integranular corrosion (IGC) of tempered austenitic stainless steels in boiling solutions of 65% HNO_3 and 27% of HNO_3+40 g/l Cr"6"+ was investigated. It is ascertained that under the action of carbon additions susceptibility of phosphorus-containing steels to IGC increases considerably in pure nitric acid and decreases in nitric acid containing the oxidant. Possible reasons for the effects observed are discussed.

Energy Technology Data Exchange (ETDEWEB)

One of the effective methods of deep modification of the surface of steels and alloys is the combination of ion implantation and plasma nitriding. In this work, the long-range effect is demonstrated in the case of combination of the effect of high- and low-energy ions of nitrogen on a martensitic steel for each ion implantation is usually not effective, and a titanium alloy used widely in industry.

Energy Technology Data Exchange (ETDEWEB)

Discussion is presented of world crude steel production, the Japanese steel industry and its expectations of the Canadian coal industry. It is concluded that the Canadian coal industry should pay attention to the trend in customer's requirements regarding coal quality, maintain price competitiveness in the international market place, and remain flexible with regard to the market trend.

International Nuclear Information System (INIS)

Effect of hydroxide nature, concentration and temperature on corrosion resistance of domestic steels and alloys to hot NaOH, KOH, LiOH solutions is considered. It is ascertained that by corrosion growth in relation to stainless steels and nickel alloys, the hydroxides are placed in the following sequence: LiOHsteel and nickel alloy tendency to cracking is manifested, are determined. 12 refs., 12 figs.

British Library Electronic Table of Contents (United Kingdom)

The thermal stability of nanoscale grains in cryomilled aluminum powders containing 1% diamantane was investigated. Diamantane is a diamondoid molecule consisting of 14 carbon atoms in a diamond cubic structure that is terminated by hydrogen atoms. The nanostructures of the resulting cryomilled powders were characterized using both transmission electron microscopy (TEM) and X-ray diffraction (XRD) techniques. The average grain size was found to be on the order of 22?nm, a value similar to that obtained for cryomilled Al without diamantane. To determine thermal stability, the powders were heated in an inert gas atmosphere at constant temperatures between 423 and 773?K (0.51T m to 0.83T m) for exposure times of up to 10?h. The average grain size for all powders containing diamantane was obse...

British Library Electronic Table of Contents (United Kingdom)

SnO2/graphene nanocomposites have been fabricated by a simple chemical method. In the fabrication process, the control of surface charge causes echinoid-like SnO2 nanoparticles to be formed and uniformly decorated on the graphene. The electrostatic attraction between a graphene nanosheet (GNS) and the echinoid-like SnO2 particles under controlled pH creates a unique nanostructure in which extremely small SnO2 particles are uniformly dispersed on the GNS. The SnO2/graphene nanocomposite has been shown to perform as a high capacity anode with good cycling behavior in lithium rechargeable batteries. The anode retained a reversible capacity of 634 mA?h?g?1 with a coulombic efficiency of 98% after 50 cycles. The high reversibility can be attributed to the mechanical buffering by the GNS against...

Energy Technology Data Exchange (ETDEWEB)

Thin films of sodium montmorillonite clay and cationic polyacrylamide were grown on a polyethylene terephthalate film using layer-by-layer assembly. After 30 clay-polymer layers are deposited, with a thickness of 571 nm, the resulting transparent film has an oxygen transmission rate (OTR) below the detection limit of commercial instrumentation (< 0.005 cc/m{sup 2}/day/atm). This low OTR, which is unprecedented for a clay-filled polymer composite, is believed to be due to a brick wall nanostructure comprised of completely exfoliated clay in polymeric mortar. With an optical transparency greater than 90% and potential for microwaveability, this thin composite is a good candidate for foil replacement in food packaging and may also be useful for flexible electronics packaging.

CERN Document Server

The controlled growth of nanowires (NWs) with dimensions comparable to the Fermi wavelengths of the charge carriers allows fundamental investigations of quantum confinement phenomena. Here, we present studies of proximity-induced superconductivity in undoped Ge/Si core/shell NW heterostructures contacted by superconducting leads. By using a top gate electrode to modulate the carrier density in the NW, the critical supercurrent can be tuned from zero to greater than 100 nA. Furthermore, discrete sub-bands form in the NW due to confinement in the radial direction, which results in stepwise increases in the critical current as a function of gate voltage. Transport measurements on these superconductor-NW-superconductor devices reveal high-order (n = 25) resonant multiple Andreev reflections, indicating that the NW channel is smooth and the charge transport is highly coherent. The ability to create and control coherent superconducting ordered states in semiconductor-superconductor hybrid ...

British Library Electronic Table of Contents (United Kingdom)

To improve the friction and wear behavior of carbon fabric reinforced polymer composites (CFRP), nano-SiO2 was deposited on the fabric surface. The friction and wear behavior of the resulting composites were investigated on a model ring-on-block test rig. Experimental results revealed that fiber surface treatment contributed to largely improve the tribological properties of the CFRP composites. Scanning electron microscope (SEM) investigation showed that the worn surface of the surface modified CFRP composite was smoother under given load and sliding rate. Field emission scanning electron microscopy (FESEM), FTIR and X-ray photoelectron spectroscopy (XPS) studies of the carbon fiber surface showed that nanostructured Sio2 thin film can be obtained by SiO2 sols deposition, which improved th...

International Nuclear Information System (INIS)

One-dimensional core-shell polymer nanowires offer many advantages and great potential for many different applications. In this paper we introduce a highly versatile two-step template wetting process to fabricate two-component core-shell polymer nanowires with controllable shell thickness. PLLA and PMMA were chosen as model polymers to demonstrate the feasibility of this process. Solution wetting with different concentrations of polymer solutions was used to fabricate the shell layer and melt wetting was used to fill the shell with the core polymer. The shell thickness was analyzed as a function of the polymer solution concentration and viscosity, and the core-shell morphology was observed with TEM. This paper demonstrates the feasibility of fabricating polymer core-shell nanostructures using our two-step template wetting process and opens the arena for optimization and future experiments with polymers that are desirable for specific applications.

International Nuclear Information System (INIS)

Test Blanket Modules (TBM) will be tested in ITER to verify the capability of tritium breeding and recovery and the extraction of thermal energy suitable for the production of electricity. A Helium Cooled Solid Breeder (HCSB) TBM has been developed in Korea to accomplish these goals. Reduced Activation Ferritic/Martensitic (RAFM) steel has been chosen as the primary candidate structural material for Korean TBM. Due to the complexity of the First wall (FW) and Side wall (SW), it is necessary to develop various joining technologies, such as Hot Isostatic Pressing (HIP), Electron Beam Welding (EBW) and Tungsten Inert Gas (TIG) welding, for the successful fabrication of TBM. In this study, the mechanical properties of TIG welded RAFM steel were investigated. Various mechanical tests of TIG-welded RAFM steel were performed to obtain the optimized TIG welding process for RAFM steel

Energy Technology Data Exchange (ETDEWEB)

The goal of this project was to increase the high-temperature strength of the H-Series of cast austenitic stainless steels by 50% and the upper use temperature by 86 to 140 degrees fahrenheit (30 to 60 degrees celsius). Meeting this goal is expected to result in energy savings of 35 trillion Btu/year by 2020 and energy cost savings of approximately $230 million/year. The higher-strength H-Series cast stainless steels (HK and HP type) have applications for the production of ethylene in the chemical industry, for radiant burner tubes and transfer rolls for secondary processing of steel in the steel industry, and for many applications in the heat treating industry, including radiant burner tubes. The project was led by Duraloy Technologies, Inc., with research participation by Oak Ridge National Laboratory (ORNL) and industrial participation by a diverse group of companies.

Energy Technology Data Exchange (ETDEWEB)

In an effort to minimize the distortion of bearing steel rings during the production process, 100Cr6 steel billets are spray formed with a unique cooling control system to control the cooling and solidification behavior of the deposits. Effects of heating around the deposits, gas cooling at the substrate bottom and the gas flow over the deposits are investigated both by numerical simulation and experiment. Porosity profiles and microstructures of spray formed bearing steel are examined and evaluated. The investigation results show that the thermal boundary conditions of the deposits play important roles on the cooling and solidification behavior of the deposits, especially at the deposit periphery. Porosity in the 100Cr6 bearing steel deposit can be reduced significantly with the special cooling control system.

Energy Technology Data Exchange (ETDEWEB)

Nitrogen has been added to stainless steels to improve mechanical strength and corrosion resistance. High nitrogen steel production is limited by high gas pressure requirements and low nitrogen solubility in the melt. One way to overcome this limitation is the addition of nitrogen in solid state because of its higher solubility in austenite. However, gas and salt bath nitriding have been done at temperatures around 550 C, where nitrogen solubility in the steel is still very low. High temperature nitriding has been, thus proposed to increase nitrogen contents in the steel but the presence of oxide layers on top of the steel is a barrier to nitrogen intake. In this paper a modified plasma nitriding process is proposed. The first step of this process is a hydrogen plasma sputtering for oxide removal, exposing active steel surface improving nitrogen pickup. This is ...

Science.gov (United States)

After each archwire was ligated into a bracket with a 0.010-in stainless steel wire, both stainless steel and beta-titanium archwires (0.017- x 0.025-in) were slid through commercially pure titanium brackets (0.018-in slot size) at 34 degrees C in both the dry and wet conditions. As controls, stainless steel archwire versus stainless steel bracket couples were used with comparable dimensions. The drawing forces were measured at 5 angulations (0 degrees, 3 degrees, 7 degrees, 9 degrees, and 11 degrees ) for 5 normal forces (nominally 0.2, 0.4, 0.6, 0.8, and 1.0 kg). Regression lines were determined for each frictional couple (P <.05). In the passive configuration, the kinetic frictional coefficients of control and test couples in the dry condition were comparable to previously reported values at 0.11 +/- 0.01 for stainless steel versus stainless steel, 0.12 ...

International Nuclear Information System (INIS)

Rapid corrosion of PWR steam generator carbon steel support structures and consequential denting of steam generator tubes led to investigation of alternative support designs and materials. In recent designs of steam generators the carbon steel drilled hole tube support plate has been replaced by one of quatrefoil or trefoil shape to minimize the contact area. These plates are now made of more corrosion resistant chromium steel (approx. 12%Cr) to ensure that they are less vulnerable to attack in the event of adverse boiler water chemistry. This study was initiated to examine the corrosion behavior of a range of chromium steels in the acid chloride environments characteristic of tube/support plate crevices under adverse boiler water conditions. Objectives of the study were to: 1) determine the relative susceptibility of candidate tube support plate steels to acid chloride corrosion; ...

International Nuclear Information System (INIS)

Ferritic/martensitic steel, modified 9Cr-1Mo steels have been used most extensively in the power generation industry throughout the world due to having superior high temperature properties such as high strength, creep resistance, and good microstructure stability. These steels are also the primary candidate for the RPVs(Reactor Pressure Vessels) of High Temperature Gas-Cooled Reactors. Currently, many studies has been conducted in laboratory-scale for mod. 9Cr-1Mo steels. However, there is a lack of the study on forged thick- section for RPVs. The differences in characteristics including the through thickness microstructure and mechanical properties between internal and external locations may occur during cooling after austenitization, because the thickness of RPVs is over about 200mm. Therefore, in order to use ferritic/martensitic steel as RPVs, a detailed assessment of the ...

Energy Technology Data Exchange (ETDEWEB)

There is presently considerable interest in wear resistant coatings produced using closed field unbalanced magnetron sputtering technology. For example, layered films of diamond-like carbon (DLC) with tungsten or titanium additions have been widely reported. The benefit is that the mechanical properties are enhanced (e.g. giving greater toughness); also it is possible to control the stress state and enhance adhesion. Here we report the further development of this concept by the addition of TiN, TiCN and TiC layers in DLC-based composites, utilizing an additional source of electrons in the vicinity of substrate to enhance ionisation of the plasma and increase coating density. Composite coatings of ceramics TiN, TiC{sub x}N{sub y}, TiC, CrN, TiCrN, TiCrCN, TiCrC, metal doped Ti{sub x%}-DLC and their combinations were deposited on 316 stainless steel substrates. The mass flow of reactive gases into the chamber was controlled using plasma optical ...

Energy Technology Data Exchange (ETDEWEB)

The availability of polysilicon feedstock has become a major issue for the photovoltaic (PV) industry in recent years. Most of the current polysilicon feedstock is derived from rejected material from the semiconductor industry. However, the reject material can become scarce and more expensive during periods of expansion in the integrated-circuit industry. Continued rapid expansion of the PV crystalline-silicon industry will eventually require a dedicated supply of polysilicon feedstock to produce solar cells at lower costs. The photovoltaic industry can accept a lower purity polysilicon feedstock (solar-grade) compared to the semiconductor industry. The purity requirements and potential production techniques for solar-grade polysilicon have been reviewed. One interesting process from previous research involves reactive gas blowing of the molten silicon charge. As an example, Dosaj et all reported a reduction of metal and boron impurities from silicon melts using ...

International Nuclear Information System (INIS)

A two module electron beam source operating over a wide range of output parameters has been designed and fabricated to be used in conjunction with a pair of electron beam sustained CO_2 lasers. Each module comprised a grid-controlled thermionic electron beam gun including a compact grid pulser for control of the electron beam, a 250 kV thyratron switched modulator for acceleration of the electron beam, a 1 kHz filament heater and a complex computerized control system. The system was designed to reliably produce 45 #mu#s wide electron pulses of 150-200 keV energy, operate at repetition rates of 1-10 pps and current densities of 5-20 mA/cm"2. Additional parameters are listed. The high voltage cathode assembly employs 132 thoriated tungsten filaments distributed over the area of the 250 cm x 10 cm output window. The cathode assembly including the control grids is supported by two high voltage ceramic bushings in a stainless steel vacuum chamber. ...

International Nuclear Information System (INIS)

For the lifetime evaluation of plasma facing materials in fusion experimental machines, it is essential to investigate their surface behavior and their temperature responses during an off-normal event such as the plasma disruptions. An infrared thermometer with a sampling speed as fast as 1x10"-"6 s/data, namely, the high-speed infrared thermometer (HSIR), has been developed by the National Research Laboratory of Metrology in Japan. To evaluate an applicability of the newly developed HSIR on the surface temperature measurement of plasma facing materials, high heat flux beam irradiation experiments have been performed with three different materials under the surface heat fluxes up to 170 MW/m"2 for 0.04 s in a hydrogen ion beam test facility at the Japan Atomic Energy Research Institute. As for the results, HSIR can be applicable for measuring the surface temperature responses of the armor tile materials with a little modification. It is also confirmed that surface temperatures measured ...

International Nuclear Information System (INIS)

Full text: The transmutation of nuclear waste to reduce the burden on a geological repository is a relevant topic within the Program of Nuclear Safety Research of the Research Centre Karlsruhe. Several studies have confirmed that a high efficiency of transmutation of actinides is reached in fast neutron spectrum reactor system. Therefore, an important effort is dedicated to the study of transmutation strategies with different fast reactors and their associated technologies. Moreover, in international contexts as Generation IV International Forum (GIF) and Sustainable Nuclear Energy Technology Platform (SNETP), fast reactors are considered in the frame of sustainable development of nuclear energy and reduction of waste. The systems that are currently under investigation, in the frame of the different fuel cycle scenarios, are liquid metal cooled and gas cooled fast reactors as well as Accelerator Driven Sub-critical Transmutation devices (ADS). These innovative reactor systems, call for ...

International Nuclear Information System (INIS)

As part of a study into the properties of ferroelectric single crystals at nanoscale dimensions, the effects that focused ion beam (FIB) processing can have, in terms of structural damage and ion implantation, on perovskite oxide materials has been examined, and a post-processing procedure developed to remove such effects. Single crystal material of the perovskite ferroelectric barium titanate (BaTiO_3) has been patterned into thin film lamellae structures using a FIB microscope. Previous work had shown that FIB patterning induced gallium impregnation and associated creation of amorphous layers in a surface region of the single crystal material some 20 nm thick, but that both recrystallization and expulsion of gallium could be achieved through thermal annealing in air. Here we confirm this observation, but find that thermally induced gallium expulsion is associated with the formation of gallium-rich platelets on the surface of the annealed material. These platelets are thought to be ...

Energy Technology Data Exchange (ETDEWEB)

Chromium nitride/Cr coating has been deposited on surface of 316L stainless steel to improve conductivity and corrosion resistance by physical vapor deposition (PVD) technology. Electrochemical behaviors of the chromium nitride/Cr coated 316L stainless steel are investigated in 0.05 M H{sub 2}SO{sub 4}+2 ppm F{sup -} simulating proton exchange membrane fuel cell (PEMFC) environments, and interfacial contact resistance (ICR) are measured before and after potentiostatic polarization at anodic and cathodic operation potentials for PEMFC. The chromium nitride/Cr coated 316L stainless steel exhibits improved corrosion resistance and better stability of passive film either in the simulated anodic or cathodic environment. In comparison to 316L stainless steel with air-formed oxide film, the ICR between the chromium nitride/Cr coated 316L stainless steel and carbon paper is about 30 ...

Energy Technology Data Exchange (ETDEWEB)

The effect of accelerated thermal cycling on a joint between modified 9Cr-1Mo steel (Grade 91) and Alloy 800 welded with Inconel 82 and 182 filler material is discussed. This is part of a trimetallic transition joint involving Grade 91-Alloy 800-316LN austenitic stainless steel for steam generator application. It has been shown that, during thermal cycling following the typical post-weld tempering treatment at 760 deg. C for 2 h, no carbon diffusion occurs from the ferritic steel towards the weld metal. There is, in fact, a hardness increase at the ferritic steel/weld metal interface which is probably a result of work hardening. Carbon migration sets in only after unusually long post-weld heat treatments for 20 and 50 h at 760 deg. C followed by thermal cycling. Significantly, even under the most severe thermal cycling test conditions imposed, no cracking or oxide notching could be detected, thus ...

British Library Electronic Table of Contents (United Kingdom)

The alloying of steel surface with aluminum (Al) using Microsecond-pulsed Intense Electron Beams (MIEB-Al) was developed and optimized in order to be used for improving the corrosion resistance of the 316, 1.4970 and T91 steels, exposed to liquid Pb and Pb-Bi-eutectic. The procedure consists in two steps: (i) coating the steel surface with Al or an Al-containing alloy layer and (ii) melting the coating layer and the steel surface layer using intense pulsed electron beam. In order to cover the steel surface with an homogeneous and crack-free Al-alloyed layer, the following experimental conditions are required: Al coating thickness range 5-10mm, electron kinetic energy 120keV; pulse duration 30ms; energy density 40-45J/cm2; number of pulses 2-3. Using the mentioned procedure, the corrosion r...

International Nuclear Information System (INIS)

Because of their austenitic-ferritic microstructures, duplex stainless steels offer a good combination of mechanical and corrosion resistance properties. However, heat treatments can lower the mechanical strength of these stainless steels as well as render them susceptible to intergranular corrosion (IGC) and pitting corrosion. In this study, a low-carbon (0.02%) duplex stainless steel is subjected to various heat treatments at 450 to 950 C for 30 min to 10 h. The heat-treated samples than undergo ASTM IGC and pitting corrosion tests, and the results are correlated with the microstructures obtained after each heat treatment. In the absence of Cr_2_3C_6 precipitation, #sigma#-phase precipitates render this duplex stainless steel susceptible to IGC and pitting corrosion. Even submicroscopic #sigma#-phase precipitates are deleterious for IGC resistance. Longer-duration heat treatments (at 750 to 850 C) ...

International Nuclear Information System (INIS)

Previous corrosion studies identified the materials Hastelloy C4, Ti 99.8-Pd, and carbon steels as promising for the manufacture of long-lived high-level waste containers that could act as an engineered barrier in a rock-salt repository. Here, the efficiency of the corrosion-resistant concept using surface-welded Hastelloy C4 as corrosion protection of carbon steel containers is compared with the corrosion-allowance concept using unalloyed or low-alloyed steels. The materials are examined in three disposal relevant brines (two rich in MgCl_2, one rich in NaCl) at 150 C. The results indicate that welded Hastelloy C4 is highly resistant to corrosion in the NaCl-rich brine. In the presence of sulfides or MgCl_2-rich brines, however, severe pitting corrosion occurs. The three steels investigated are resistant to pitting corrosion in all brines, and their general corrosion rates imply corrosion allowances ...

Science.gov (United States)

PMID:21900358

J-STORE (Japan)

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International Nuclear Information System (INIS)

A computational procedure is proposed to perform uncertainty analysis for the calculation of the isotopic inventory and radiological quantities obtained as a linear function of it, due to uncertainties in the activation cross sections. The method is applied to determine the uncertainty of the calculated shallow burial index (SBI) from activated type 304 stainless steel (SS) in the most neutron-exposed zone of the HYLIFE-II vessel structure. Results are obtained by means of an element-by-element study. Some other types of steel are also investigated for comparison purposes. The SS304 is confirmed to be the most promising steel option. 16 refs., 2 tabs.

DEFF Research Database (Denmark)

It is shown that multipole dislocation configurations can arise during power-law creep of certain austenitic stainless steels. These multipoles have been analysed in some detail for two particular steels (Alloy 800 and a modified AISI 316L) and it is suggested that they arise either during instantaneous loading or during the primary creep stage. Trace analysis has shown that the multipoles are confined to {1 1 1} planes during primary creep but are not necessarily confined to these planes during steady-state creep unless they are pinned by interstitials.

Energy Technology Data Exchange (ETDEWEB)

Severe pitting corrosion occurred in a horizontal steel pipeline used to transport multiphase fluid, including water, oil, and natural gas, after 2 months of service. The pitting corrosion rate was up to 42 mm/year. Chemical analysis, X-ray diffractometry, and EDAX showed that the corrosion products mainly consisted of Fe9S8, FeCO3, and NaCl. Calcium containing inclusions were also found in the matrix of the steel, which may accelerate corrosion. The early failure was attributed to the high proportion of water, the slow flow velocity, and the use of unqualified material. (Author)

Energy Technology Data Exchange (ETDEWEB)

Long crack fatigue threshold ({delta} K{sub th}) and crack closure behaviour of two thermomechanically processed microalloyed (MA) ferrite-pearlite steels are reported. {delta} K{sub th} and crack closure were measured using a dynamic compliance measurement technique. Crack closure was observed at low load ratios (R < 0.5) and the fatigue thresholds decreased with increasing load ratio. In both steels, the closure-free intrinsic threshold ({delta} K{sub eff} {sub th}) was found to be independent of the load ratio. (orig.)

International Nuclear Information System (INIS)

This paper deals with the pitting corrosion of evaporators in the liquid - radwaste system of nuclear power stations. Corrosion testrs were conducted by the anodic polalization of specimen in the chloride solution. (1) The initiation of the pitting in SUS 304, SUS 316 stainless steels was inhibited by addition of NaOH and H_3BO_3, however, these addition had no effect on the pitting propagation. (2) Inconel 625 had the resitivity against the pitting initiation superior to that of stainless steels, but this was not necessarily in the case of the pitting propagation. (3) It is noticed for pitting prevention that the environmental and material effect on the pitting initiation differed from that on the pitting propagation. (author).

Energy Technology Data Exchange (ETDEWEB)

The effect of aging on the microstructure and tensile properties of a type 316LN stainless steel/Alloy 800 joint, welded with 16-8-2 stainless steel consumable, has been studied to characterize and evaluate the joint for long-term elevated temperature service. The joint was subjected to accelerated againg heat treatments at 873 K up to 5000 h to simulate long-term service exposures. Analysis of the results from this investigation shows that this joint has adequate stability of microstructure and tensile properties even after prolonged exposure at elevated temperatures. (orig.)

Science.gov (United States)

Three bonding agents were evaluated to determine which were most effective in enhancing the bond of resin composite to stainless steel. A light-activated resin composite was bonded to a total of 60 stainless steel specimens using Panavia, Cover-Up, or Silicoating. Tensile bond strength measurements revealed that all three agents provide a satisfactory means of increasing adherence of the esthetic veneer without decreasing bonding through thermocycling of the specimens. Panavia and Cover-Up were significantly more effective than Silicoating and appear to be easier to use. PMID:8297460

J-STORE (Japan)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The current status and prospects for Japan`s economy and steel industry, forecast for demand and supply of coking coal, directions in steel making technology, and Japan`s expectations for Canadian coal are discussed. The PCI system, the Coal Moisture Control System (CMC) to increase coke density before it is fed into coke ovens, a feeder that allows use of lower quality coke on the outskirts of blast furnaces, the Direct Iron Ore Smelting (DIOS) Process, and the `Next Generation Coke Oven`, where coke is heated rapidly and coked at 700-800{degree}C are considered. By 2000, semi-soft coking coals are expected to account for over half of total coal consumption by Japanese steel mills.

International Nuclear Information System (INIS)

1974. 20 p. United States Anon. American Society of Mechanical

Energy Technology Data Exchange (ETDEWEB)

Carbon steel is frequently used to construct concentrated sulphuric acid storage tanks. This paper discussed the corrosion performance of carbon steel tanks and outlined the underlying mechanisms responsible for major corrosion modes. Analyses of hydrogen grooving and dilute acid corrosion failure mechanisms were presented. Recent corrosion-induced leak failures were also discussed. The use of anodic protection and organic coatings as a corrosion control measure was also evaluated. The results of laboratory studies that were conducted to understand corrosion-induced failures showed that carbon steel electrodes exhibited transpassive corrosion at relatively high anodic potentials, while stainless steel electrodes exhibited transpassive corrosion at anodic potentials less than 1 V. It was concluded that corrosion-induced leaks can be prevented by using anodic protection and baked phenolic coating ...

International Nuclear Information System (INIS)

... Fuel Limited, Reprocessing Business Division, Rokkasho, Aomori (Japan)

International Nuclear Information System (INIS)

Methods of automated control of 18-10-type steel inclination to IGC are developed and a corresponding automated testing complex (ATS) is created. 08Kh18N10T steel samples had two variants of thermal treatment: 1) 1200 deg (5 h), 600 deg (50 h); 2) 1200 deg (5 h). Methods of non-destructive automated control of 18-10-type steel inclination to IGC are developed on the basis of potentiodynamic reactivation (PR) principle. Automated testing complex is developed, which has undergone experimental running and demonstrated a high confidence of results, reliability and easy operation.

British Library Electronic Table of Contents (United Kingdom)

A mathematical model for heat transfer during solidification in continuous casting of automobile steel, was established on researching under the influence of the solidifying process of bloom quality of CCM in the EAF steelmaking shop, at Shijiazhuang Iron and Steel Co. Ltd. Several steel grades were chosen to research, such as, 40Cr and 42CrMo. According to the results of the high temperature mechanical property tests of blooms, the respective temperature curves for controlling the solidification of different steels were acquired, and a simulating software was developed. The model was verified using two methods, which were bloom pinshooting and surface strand temperature measuring experiments. The model provided references for research on the solidifying process and optimization of a secon...

International Nuclear Information System (INIS)

Russian (Mar 1977). USSR Makarov, VA Zarubin, PI Mironov, Yu.M.

Energy Technology Data Exchange (ETDEWEB)

This paper investigates steels 12Kh18N10T, 10Kh17N13M2T, 08Kh22N6T, and 08Kh21N6M2T. In corrosion of stainless steels in sulfuric acid solutions, dissolved sulfur dioxide acts as a cathodic depolarizer, capable of being reduced to elemental sulfur or forming sulfides with the metal. Depending on the conditions, this is associated with some increase in potential and greater or lesser increase in corrosion or facilitation of passivation of active steel. After passivation the influence of SO/sub 2/ is negligible. The results of this investigation were used as initial data for developing systems of anodic protection for shell-and-tube heat exchangers for sulfuric acid.

International Nuclear Information System (INIS)

... Energy Agency, Quantum Beam Science Directorate, Sayo, Hyogo (Japan)

Energy Technology Data Exchange (ETDEWEB)

First French manufacturer of steel boilers, Geminox proposes the THRi series, composed of condensation gas boilers whose four mural for the propane model. (O.M.)

Energy Technology Data Exchange (ETDEWEB)

This report summarizes some experiences gathered when using the semi-empirical temperature model that forms the heart of the steel casting advisory system `TUNDTEMP` in simulating the casting process. The model estimates the evolution of the liquid steel temperature in a tundish of a continuous casting machine through a temperature prediction at a couple of central time instants during the casting process. The results are compared with corresponding actual observations during the castings - measured steel temperatures and recorded casting difficulties and interruptions. Explanations for the possible discrepancies are suggested. Starting from a heuristically chosen set of model parameter values, some developing steps have been tested to reduce the simulation errors. The study concentrates mainly on temperature predictions for single heat castings. At the end of the report, some simulations of sequence castings are also ...

British Library Electronic Table of Contents (United Kingdom)

Flue gas desulfurization systems (FGDs) are operated in severely corrosive environments that cause sulfuric acid dew-point corrosion. The corrosion behavior of low-alloy steels was tested using electrochemical techniques (electrochemical impedance spectroscopy, potentiodynamic tests, potentiostatic tests), and the corrosion products were analyzed by scanning electron microscopy and X-ray photoelectron spectroscopy. The electrochemical results showed that alloying W with small amounts of Sb, Cu, and Co improves the corrosion resistance of steels. The results of surface analyses showed that the surface of the steels alloyed with W consisted of W oxides and higher amounts of Sb and Cu oxides. This suggests that the addition of W promotes the formation of a protective WO3 film, in addition to ...