Energy Technology Data Exchange (ETDEWEB)

EPRI research related to coal liquefaction has concentrated on the chemistry of the processes. Recent work is reviewed.

Energy Technology Data Exchange (ETDEWEB)

Research programs on coal liquefaction are presented. Major topics include: coprocessing, two-stage liquefaction, low severity liquefaction, coal/catalyst and liquefaction chemistry. Individual projects are processed separately for the data bases. (CBS)

Energy Technology Data Exchange (ETDEWEB)

Some applications of magnetic resonance in coal liquefaction research described briefly are: (1) investigation of the nature of carbon deposits on used coal-liquefaction catalysts, (2) determination of the fate of hydrogen during coal liquefaction, and (3) observation of transient free radicals during coal pyrolysis. The first two applications make use of cross-polarization /sup 13/C magnetic resonance combined with magic angle spinning, and the third application is an electron spin resonance study. (BLM)

Energy Technology Data Exchange (ETDEWEB)

This paper discusses geology, coalfields, coal quality, seams and strata, coal reserves, mining methods, production, coal liquefaction, and research on spontaneous combustion and methane explosions.

Science.gov (United States)

Results of research programs in coal liquefaction are presented. Areas of research include: desulfurization by bioprocessing; characterization of coal liquefaction processes by XAFS spectroscopy; coprocessing of coal with heavy oil and petroleum residuals; liquefaction research in pyrolysis, catalysis and coal dissolution; novel catalysts; data base development; resource evaluation; depolymerization; solvent extraction and chromatography; correlations of liquefaction yields and coal structure. Individual projects are processed separately for the data bases. (CBS)

Energy Technology Data Exchange (ETDEWEB)

Significant progress was made in the May 1990--May 1991 contract period in three primary coal liquefaction research areas: catalysis, structure-reactivity studies, and novel liquefaction processes. A brief summary of the accomplishments in the past year in each of these areas is given.

Energy Technology Data Exchange (ETDEWEB)

This is a synopsis of a paper describing Rheinbraun/Union Kraftstoff research.

Energy Technology Data Exchange (ETDEWEB)

The overall goal of the Coal Liquefaction Program of the Office of Coal Technology (OCT) is to develop the scientific and engineering knowledge base with which industry can bring economically competitive and environmentally acceptable advanced technology for manufacturing synthetic liquid fuels from coal into the marketplace when needed. The technical goal of the Coal Liquefaction Program is to seek advanced and innovative improvements over the state-of-the-art processes for coal liquefaction that can utilize all major parts of the US coal resource base. A technology description and discussion of program goals and strategy is provided in this report. 2 figs.

Energy Technology Data Exchange (ETDEWEB)

Coal liquefaction technology aims to obtain a liquid fuel from coal by cracking the coal under elevated temperature and pressure and simultaneously adding hydrogen, either directly as a gas or by way of a suitable solvent. The author describes the work being done on coal liquefaction in Japan, where this technology is being developed as part of a large-scale national project.

Energy Technology Data Exchange (ETDEWEB)

Three areas have been investigated: coal liquefaction with supercritical fluids, liquefaction by extraction with high boiling liquid solvents, and the production of resins from coal-derived hydrocarbons. The processes are described.

Energy Technology Data Exchange (ETDEWEB)

This study had two objectives: (1) To enhance the fundamental understanding of observed differences in the short contact time, donor solvent liquefaction of bituminous and subbituminous coals. (2) To determine if physical refining of subbituminous coals could be used to give a better feedstock for the first stage of two-stage liquefaction processes. Liquefaction studies using microautoclaves were carried out. Results are discussed. 11 refs., 25 figs., 29 tabs.

Energy Technology Data Exchange (ETDEWEB)

Consol R D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-fold: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

Energy Technology Data Exchange (ETDEWEB)

The paper studied a possibility of estimating characteristics of coal liquefaction residue from liquefaction conditions in the case of fixing coal kind in the NEDOL process coal liquefaction PSU. Wyoming coal was used for the study, and the already proposed simplified liquefaction reaction models were used. Among material balances explained by the models, those of asphaltene, preasphaltene, THF insoluble matters are concerned with residue composition. Ash content is separately calculated from ash balance. Reaction velocity constants of simplified liquefaction reaction models which influence the residue composition were obtained by the multiple regression method from experimental results in the past. The estimation expression of residue viscosity was introduced from residue ash/composition. When the ...

Energy Technology Data Exchange (ETDEWEB)

This paper describes a research and development project to quantify the effects of cleaning the coal feed on the yield patterns and processing rates for the Liquid Solvent Extraction (LSE) direct coal liquefaction process and to obtain information on the effect of the co-refining of coal-derived and petroleum distillates to premium transport fuels. 6 refs., 25 figs., 40 tabs.

Energy Technology Data Exchange (ETDEWEB)

The catalytic liquefaction of a Chinese bituminous coal was simulated by artificial neural network. Three liquefaction variables, catalyst loading, reaction temperature and reaction time were used as inputs and tetrohydrofuran (THF) conversion and toluene (T) conversion were used as outputs. The artificial neural network, trained by the experimental data, could represent the liquefaction process, with a mean squared deviation of less than 0.025. 7 refs.,1 fig., 3 tabs.

Energy Technology Data Exchange (ETDEWEB)

Cooperative research in coal liquefaction from Auburn University, University of Kentucky, University of Pittsburgh, West Virginia University, University of Utah, and the UK Center for Applied Energy Research, are briefly discussed. Topics covered include desulfurization, chemical reactivity, coprocessing, and catalysis. (CBS)

Science.gov (United States)

A method for analyzing the experimental results of coal liquefaction reactions which is applicable to a number of aspects of coal liquefaction research and process control, including rapid selectivity and performance screening for catalysts; correlation of laboratory results with process parameters; and optimization of product yield with plant process conditions is described here. Ternary diagrams of product/by-product distributions for the coal liquefaction using Co/Mo catalysts combined with a hyperbolic relationship for the conversion of various hydrocarbon fractions can be used for catalyst screening. A hydrogen consumption diagram used to provide a more significant selectivity test than the hyperbolic correlation is also included. (BLM)

Energy Technology Data Exchange (ETDEWEB)

A discussion of the Sasol I, II, and III coal liquefaction plants of the Republic of South Africa was presented. The technology, capacity, and economics of these projects were included in the discussion. These plants utilize the Fischer-Tropsch process of indirect coal liquefaction and produce a barrel of synthetic crude for about $55 (or about $20 above current market prices). Outlines of the differences in indirect coal liquefaction and newer direct methods were presented. It was determined that the South African dedication to coal liquefaction was made more for the political aspects of energy independence than economics.

Energy Technology Data Exchange (ETDEWEB)

British Columbia is rich in resources of coal but is deficient in resources of liquid petroleum. The overall objective of the B.C. Research Coal Liquefaction Program is to provide sufficient technical data to identify and evaluate coal conversion opportunities in the province. In this first quarterly report, liquefaction test systems are discussed and results from the testing of equipment, procedures and analytical methods using coal samples from Sukunka (N.E. coal) and Hat Creek (central interior) are presented. The proposed program to be undertaken over the next four years is outlined.

Energy Technology Data Exchange (ETDEWEB)

The DOE Coal Liquefaction Research Needs (COLIRN) Panel reviewed, developed, and assessed R and D needs for the development of coal liquefaction for the production of transportation fuels. Technical, economics, and environmental considerations were important components of the panel's deliberations. The panel examined in some depth each of the following technologies: direct liquefaction of coal, indirect liquefaction via conversion of coal-derived synthesis gas, pyrolysis, coprocessing of combined coal/oil feedstocks, and bioconversion of coal and coal-derived materials. In this assessment particular attention was given to highlighting the fundamental and applied research which has revealed new and improved liquefaction ...

Science.gov (United States)

Research is being carried out in this project in two areas which are of interest to ongoing investigations at the Pittsburgh Energy Technology Center (PETC). They are: (a) thermal behavior of slurry reactors used for indirect coal liquefaction; and (b) coal liquefaction under supercritical conditions. The current status of each of these tasks is summarized in this report. 76 refs., 23 figs., 6 tabs.

Energy Technology Data Exchange (ETDEWEB)

The aim of British coal liquefaction research is to produce premium products such as transport fuels and chemical feedstocks. Government support has been promised for two 25 tpd pilot plants. Badger estimate that the finished products would cost 25% more than petroleum products. Countries with no indigenous oil are likely to commence commercial coal liquefaction soon.

Energy Technology Data Exchange (ETDEWEB)

The National Coal Board is investigating two routes for production of oils: liquid solvent extraction and supercritical gas extraction. Both these processes are considered ready for major development to plants of the 1 t/h scale.

Science.gov (United States)

This report accounts for Task 3 of DOE Contract No. AC01-81FE-05077. It reviews the developments in indirect coal liquefaction with emphasis on slurry-phase reactors and catalysis. This report also discusses topics related to indirect coal liquefaction research, such as analytical techniques in catalysis. The subjects covered in this report were selected by DOE. This report is the third and final task report of the three major tasks in this contract. The first task, ''Direct Coal Liquefaction Catalyst Development - Program Review and Research Perspectives'', was completed in November 1982. The second task, ''Review of Direct Coal Liquefaction by Slurry-Phase Catalysis'', was completed in September 1983. 47 refs., 66 figs., 50 tabs.

Energy Technology Data Exchange (ETDEWEB)

The relationship between coal properties and liquefaction or gasification characteristics was analyzed by using the analysis and test results and liquefaction characteristics in the coal data base. On liquefaction reaction, the close relation between an oil yield and coal constituent composition or a coal rank is well-known. Various multivariable regression analyses were conducted by using 6 factors as variables such as calorific value, volatile component, O/C and H/C atomic ratios, exinite+vitrinite content and vitrinite reflectance, and liquefaction characteristics as variate. On liquefaction characteristics, the oil yield of dehydrated and deashed coals, asphaltene yield, hydrogen consumption, produced water and gas quantities, and oil+asphaltene yield were predicted. The ...

Science.gov (United States)

ERDA's coal liquefaction program is reviewed, especially the progress with several pilot plant operations. Other items involve the possible recovery of organic chemicals from coal liquids, the filtration of coal liquids, some experiments on hydrogenation and carbonization, and renovation of the Cresap materials and equipment test facility. (LTN)

Science.gov (United States)

The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of analytical chemistry to direct coal liquefaction process development. Independent analyses by well-established methods will be obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, analytical instruments and techniques which are currently underutilized for the purpose of examining coal-derived samples will be evaluated. The data obtained from this study will be used to help guide current process development and to develop an improved data base on coal and coal liquids properties. A sample bank will be established and maintained for use in this project and will be available for use by other researchers. ...

Science.gov (United States)

In the Advance Coal Liquefaction Concept Proposal (ACLCP) carbon monoxide (CO) and water have been proposed as the primary reagents in the pretreatment process. The main objective of this project is to develop a methodology for pretreating coal under mild conditions based on a combination of existing processes which have shown great promise in liquefaction, extraction and pyrolysis studies. The aim of this pretreatment process is to partially depolymerise the coal, eliminate oxygen and diminish the propensity for retograde reactions during subsequent liquefaction. The desirable outcome of the CO pretreatment step should be: (1) enhanced liquefaction activity and/or selectivity toward products of higher quality due to chemical modification of the coal structure; (2) cleaner downstream products; (3) overall improvement in ...

Energy Technology Data Exchange (ETDEWEB)

Consol R&D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-field: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.

Energy Technology Data Exchange (ETDEWEB)

The paper discusses the status of coal as a raw material and energy source. After referring to coal preparation and the costs it involves the author deals with coal/liquid suspensions and their fueling uses. Access is given to different aspects concerning the use of coal for electric power and heat generation. They include pollution abatement measures, economic analyses and fuel engineering in the case of coal. Further sections are dedicated to upgrading procedures such as the gasification, liquefaction and coking of coal. A bibliography informs the reader about further publications available on the subject. (HAG).

Energy Technology Data Exchange (ETDEWEB)

A highly dispersed limonite catalyst was shown to have advantageous properties in a commercial liquefaction plant: it has high catalytic activity, low cost for catalyst production and abundant resources. 3 refs., 3 figs., 2 tabs.

Science.gov (United States)

The objectives of this contract are to conduct exploratory coal liquefaction research on modified solvents with slurry phase catalysts and on coal pretreatment. This report describes a review of the existing literature as well as currently on-going research in the areas of: (1) solvent quality effects on coal liquefaction; (2) role of heteroatoms in liquefaction of coal; (3) heteroatoms removal through solvent treatment, extraction and hydrogenation; (4) slurry phase catalysts in hydroprocessing of coal; and (5) effect of coal preparation and pretreatment on liquefaction. The review encompasses both technical papers and presentations as well as the patent literature. This report is comprised of two distinct parts. In Part I all the literature available on the effect of solvent ...

Energy Technology Data Exchange (ETDEWEB)

This quarterly report for the period April through June 1984 summarizes activities in Sandia National Laboratories' continuing program of coal liquefaction research. The primary goals are to: explore novel catalytic concepts and materials for conversion of coal to liquid fuels; determine the effects of process variables on catalyst deactivation; determine the effects of coal structure and solvent properties on low temperature dissolution; study the kinetics and catalysis of hydrogen transfer reactions; develop an understanding of slurry gelling phenomena; and provide a technical assessment of coal liquefaction processes. During this period, work was performed on: analysis of catalyst samples from Wilsonville Run 246; catalyst presulfiding; catalyst activity testing using pyrene as a chemical probe; catalyst deactivation using a high-pressure model ...

Energy Technology Data Exchange (ETDEWEB)

Mineral matter in coals is important in various senses for coal liquefaction. It is possible that the catalytic activity is affected by the interaction between catalyst and mineral matter. Iron-based catalyst forms pyrrhotite in the process of liquefaction, but the interaction between it and mineral matter is not known in detail. In this study, the interaction between mineral matter and catalyst and the selective reaction between them were investigated. Tanito Harum coal was used for this study. This coal contains a slight amount of siderite and jarosite besides pyrite as iron compounds. Liquefaction samples were obtained from the 1 t/d NEDOL process PSU. The solid deposits in the reactor mainly contained pyrrhotite and quartz. A slight amount of kaolinite was observed, and pyrite was little remained. It was found that the catalyst ...

Energy Technology Data Exchange (ETDEWEB)

Low-temperature catalytic pretreatment is a promising approach to the development of an improved liquefaction process- This work is a fundamental study on effects of pretreatments on coal structure and reactivity in liquefaction. The main objectives of this project are to study the coal structural changes induced by low-temperature catalytic and thermal pretreatments by using spectroscopic techniques; and to clarify the pretreatment-induced changes in reactivity or convertibility of coals in the subsequent liquefaction. This report describes the recent progress of our work. Substantial progress has been made in the spectroscopic characterization of structure and pretreatment-liquefaction reactions of a Montana subbituminous Coal (DECS-9), and thermochemical analysis of three mw and reacted bituminous ...

Energy Technology Data Exchange (ETDEWEB)

This article discusses the latest developments made in the field of technology used for coal liquefaction. Some new areas of development in research and development work are described. Particular consideration is given to low-severity processing. This has two advantages, mostly low-molecular-weight fragments are produced and the extracts are low in heteroatoms. A detailed description of low-severity processing is given. The refining of the liquids produced from coal is also covered.

Energy Technology Data Exchange (ETDEWEB)

A C.sub.5 -900.degree. F. (C.sub.5 -482.degree. C.) liquid yield greater than 50 weight percent MAF feed coal is obtained in a coal liquefaction process wherein a selected combination of higher hydrogen partial pressure, longer slurry residence time and increased recycle ash content of the feed slurry are controlled within defined ranges.

Energy Technology Data Exchange (ETDEWEB)

Some Japanese and US coal liquefaction research projects are listed.

Science.gov (United States)

This report consists of ten sections in addition to an executive summary and a glossary. Each section was abstracted and indexed separately. (EJH)

Science.gov (United States)

The investigation of various Two-Stage Liquefaction (TSL) process configurations was conducted at the Wilsonville Advanced Coal Liquefaction R D Facility between July 1982 and September 1986. The facility combines three process units. There are the liquefaction unit, either thermal (TLU) or catalytic, for the dissolution of coal, the Critical Solvent Deashing unit (CSD) for the separation of ash and undissolved coal, and a catalytic hydrogenation unit (HTR) for product upgrading and recycle process solvent replenishment. The various TSL process configurations were created by changing the process sequence of these three units and by recycling hydrotreated solvents between the units. This report presents a description of the TSL configurations investigated and an analysis of the operating and performance data from the period of study. Illinois No. 6 Burning Star ...

Science.gov (United States)

Programs in coal research by the Pittsburgh Energy Technology Center are discussed. Topics include: Coal Science and Chemistry, Coal Liquefaction, Alternative Fuels, Coal Preparation, Combustion, MHD Program, Flue Gas Cleanup, Environmental Coordination, and Technology Transfer. (CBS)

Energy Technology Data Exchange (ETDEWEB)

In order to replace industrial cobalt and nickel and molybdenum catalysts, more economical catalysts, red muds, are used. Comparative data about the chemical, structural and thermal properties of different samples of red muds, which are important for catalytic hydrogenation, are cited. The different conditions for hydrogenation of coals in a reactor are examined.

Energy Technology Data Exchange (ETDEWEB)

Recent research at the laboratory scale by a number of organizations in different countries has shown that with the use of particular types of solvents it is possible to achieve almost complete conversion of coal to liquid products under relatively mild process conditions. This work is reviewed and the conclusions to be drawn from it are summarized.

Energy Technology Data Exchange (ETDEWEB)

Since natural pyrite is easy to obtain and cheap as coal liquefaction catalyst, it is to be used for the 150 t/d scale NEDOL process bituminous coal liquefaction pilot plant. NEDO and NCOL have investigated the improvement of catalytic activity of pulverized natural pyrite for enhancing performance and economy of the NEDOL process. In this study, coal liquefaction tests were conducted using natural pyrite catalyst pulverized by dry-type bowl mill under nitrogen atmosphere. Mechanism of catalytic reaction of the natural pyrite was discussed from relations between properties of the catalyst and liquefaction product. The natural pyrite provided an activity to transfer gaseous hydrogen into the liquefaction product. It was considered that pulverized pyrite promotes the hydrogenation reaction of asphaltene because ...

Energy Technology Data Exchange (ETDEWEB)

This report presents the operating results for Run 255 at the Advanced Coal Liquefaction Research and Development Facility in Wilsonville, Alabama. This run operated in the Close Coupled Integrated Two-Stage Liquefaction mode (CC-ITSL) using Martin Lake Texas lignite. The purpose of this run was to demonstrate unit and system operability with Martin Lake lignite. Run 255 began on 20 March 1988 and continued through 9 June 1988. During this period, 204.4 MF tons of Martin Lake Texas lignite were fed in 1865.5 hours of operation. 70 figs., 21 tabs.

Energy Technology Data Exchange (ETDEWEB)

Research continued on low severity coal liquefaction. Research using high temperature infrared of cyclic olefins progressed well during this quarter. Several fluorinated solvents were found that provide a high temperature medium for isotetralin and its aromatic and aliphatic analogues.

Energy Technology Data Exchange (ETDEWEB)

Various research programs on coal liquefaction are described. Research efforts are reported from the University of Kentucky, University of Pittsburgh, West Virginia University, University of Utah, and the Center for Applied Energy Research. Research areas include depolymerization, desulfurization, coprocessing catalysis, hydrogenation, and solvent extraction. (CBS)

Energy Technology Data Exchange (ETDEWEB)

The development of a synthetic fuels industry in Australia is described in the context of overall energy policy. The national coal liquefaction research program is directed at three main routes to liquid fuels: hydroliquefaction, pyrolysis and indirect liquefaction. Australia is also contributing to technology development and assessment programs in cooperation with other countries, in particular Federal Republic of Germany and Japan.

Energy Technology Data Exchange (ETDEWEB)

This semiannual report for the period October 1983-March 1984 summarizes activities in Sandia National Laboratories' continuing program of coal liquefaction research. The primary goals are to: explore novel catalytic concepts and materials for conversion of coal to liquid fuels; determine the effects of process variables on catalyst deactivation; determine the effects of coal structure and solvent properties on low temperature dissolution; study the kinetics and catalysis of hydrogen transfer reactions; develop an understanding of slurry gelling phenomena; and provide a technical assessment of coal liquefaction processes. During this period, work was performed on: the use of pyrene as a chemical probe of catalyst activity; analysis of catalysts from Wilsonville run 242 using ESCA; atmospheric pressure model compound activity testing of regenerated ...

Science.gov (United States)

Oak Ridge National Laboratory (ORNL) has for over ten years provided materials testing and failure analysis services to various coal conversion and utilization facilities in the United States. ORNL was involved in these types of activities at all four of the major coal liquefaction pilot plants. This paper presents a summary of activities at Wilsonville over the past two and one-half years. Some details of these activities are discussed below. Failure analysis of elastomers, stainless steels, and alloys is discussed. 6 refs., 9 figs., 13 tabs.

Science.gov (United States)

The objective of the current research in coal liquefaction is to produce a synthetic crude from coal at a cost lower than $30.00 per barrel (Task A). A second objective is to produce a fuel which is low in aromatics, yet of sufficiently high octane number for use in the gasoline-burning transportation vehicles of today. To meet this second objective, research was proposed for conversion of the highly-aromatic liquid product from coal conversion to a product high in isoparaffins, which compounds in the gasoline range exhibit a high octane number (Task B). Experimental coal liquefaction studies conducted in a batch microreactor in the laboratory have demonstrated potential for high conversions of coal to liquids with low yields of hydrocarbon (HC) gases, hence small consumption of hydrogen in the primary liquefaction step. ...

Science.gov (United States)

Because hydrogenation of coal to liquid products (oils) is accompanied by distributions of complex by-product mixtures (IOM, preasphaltenes, asphaltenes and gases) which change as a function of reaction variables (time, temperature and pressure) and reactor configuration, the determination of selectivity relationships for coal liquefaction catalysts has been a difficult and time-consuming task involving numerous experiments to adequately describe catalyst performance over a range of conditions. This paper describes a method for analyzing the experimental results of coal liquefaction reactions which may be applied to a number of aspects of coal liquefaction research and process control, including: rapid selectivity and performance screening for catalysts; correlation of laboratory results with process parameters; and optimization of product ...

Energy Technology Data Exchange (ETDEWEB)

Several kinds of catalysts for coal liquefaction were analysed by means of high pressure differential thermal analysis (DTA). The activity order is as follows: Fe(OH)/sub 3/.Ni(OH)/sub 2/ > 3665 > Fe(OH)/sub 3/.MoO/sub 3/ > Jin Chuan Mineral > concentrated pyrite > Japan red-mud approx. equal to Fe(OH)/sub 3/.CuO approx. equal to no catalyst. If the catalysts are promoted by sulphur., the activity order is 3665 + S > Fe(OH)/sub 3/.Ni(OH)/sub 2/ + S > Fe(OH)O/sub 33/ + S > Japan red mud + S > Fe(OH)O/sub 3/.CuO + S > no catalyst. The kinetic parameters of three catalysts commonly used in the liquefaction of coal were determined.

Energy Technology Data Exchange (ETDEWEB)

The Consortium for Fossil Fuel Liquefaction Science (CFFLS) is a research consortium that includes five universities and a state energy laboratory. The membership is comprised of Auburn University, the University of Kentucky, the University of Pittsburgh, the University of Utah, West Virginia University, and the Kentucky Energy Cabinet Laboratory. The Consortium was formed in 1984 in response to the concern of the faculty and scientists at these institutions over the decline of coal liquefaction research in the United States, particularly long-range, basic research. Significant progress towards these goals was made in the current contract period. Major research accomplishments are presented on coal desulfurization, coprocessing, pyrolysis, enhanced reactivity, characterization, resource evaluation and database development. 108 refs., 90 figs., 38 tabs.

Science.gov (United States)

A phase 2 study has been initiated to investigate surfactant-assisted coal liquefaction, with the objective of quantifying the enhancement in liquid yields and product quality. This report covers the second quarter of work. The major accomplishments were: completion of coal liquefaction autoclave reactor runs with Illinois number 6 coal at processing temperatures of 300, 325, and 350 C, and pressures of 1800 psig; analysis of the filter cake and the filtrate obtained from the treated slurry in each run; and correlation of the coal conversions and the liquid yield quality to the surfactant concentration. An increase in coal conversions and upgrading of the liquid product quality due to surfactant addition was observed for all runs.

Energy Technology Data Exchange (ETDEWEB)

Process solvent was hydrogenated in the brown coal liquefaction, to investigate the influence of it on the prethermal treatment and liquefaction. Consequently, it was found that the n-hexane soluble (HS) yield was improved. In this study, capacity of hydrogen transfer from solvent during prethermal treatment and effects of catalyst were investigated. Since prethermal treatment in oil was effective for improving the oil yield in the presence of hydrogen/catalyst or high hydrogen-donor solvent, influence of hydrogen-donor performance of solvent or addition of catalyst on the hydrogenation behavior of coal and the characteristics of products during prethermal treatment were investigated in relation to successive liquefaction results. As a result, it was found that the increase of HS yield was due to the acceleration of conversion of THF-insoluble using high hydrogen-donor solvent ...

Energy Technology Data Exchange (ETDEWEB)

The Nova Scotia Research Foundation Corporation was established in 1946 by the Province of Nova Scotia to use science and technology to assist in the economic development of Nova Scotia. Within the Applied Science Division of the Corporation, research and development programs in the area of coal and mineral technology have been undertaken. A brief description of two projects -- coal liquefaction and coal-water fuels, are reported.

Science.gov (United States)

The overall objective of this project was to develop a new approach for the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrated coal selection, pretreatment, coal swelling with catalyst impregnation, liquefaction, product recovery with characterization, alternate bottoms processing, and a technical assessment including an economic evaluation. Heterofunctional solvents were the most effective in swelling coals. Also solvent blends such as isopropanol/water were more effective than pure solvents alone. Impregnating slurry catalysts simultaneously during coal swelling showed that better uptake was achieved with nonswelling solvent and higher impregnation temperature. Some enhancement in initial coal conversion was seen liquefying ...

Energy Technology Data Exchange (ETDEWEB)

Product control procedures, the development of new technologies, and the extension of the applications of solid fuels are described. Hydrogasification and high-temperature Winkler gasification are discussed. The design and function of a continuous, semi-industrial plant for hydrogenating liquefaction in the sump phase are gone into. (MOS).

Science.gov (United States)

DOE is supporting the development of several conversion processes that are currently in the pilot plant stage. Each of these processes is described briefly and information given as to contractor, contract, funding, site and current progress. Several support projects are treated similarly. (LTN)

Energy Technology Data Exchange (ETDEWEB)

The Sunshine Project of Japan was inaugurated in 1974. Since 1980 it has been promoting priority projects such as coal liquefaction. Japan is now promoting the basic and applied research that underpins this development and is increasing the efficiency of technical development. With regard to risk dispersion, the expansion of international cooperation such as the IEA is being promoted.

Energy Technology Data Exchange (ETDEWEB)

A summary of the 1983 Critical Solvent Deashing unit performance at the Wilsonville Advanced Coal Liquefaction R and D Facility is presented. All periods of on feed operation, unscheduled shutdowns, and scheduled shutdowns are accounted for and tabulated. Causes of unscheduled shutdowns are identified and discussed. Details of repeated, major maintenance problems with various pieces of equipment are presented. Where applicable, solutions are discussed. Historical operations and maintenance data are presented and used for comparison purposes in order to better indicate areas of improvement in the unit. 4 references, 7 figures, 3 tables.

Energy Technology Data Exchange (ETDEWEB)

The status of commercial technology for indirect liquefaction, as exemplified by SASOL facilities in South Africa, is reviewed. The impact of substituting more advanced gasifiers and synthesis systems is then investigated. Slagging BGC/Lurgi, Texaco and Shell-Koppers gasifiers were substituted for the Dry Ash Lurgi units used at SASOL. SASOL SYNTHOL synthesis units were replaced by slurry phase Fischer-Tropsch units employing technology pioneered by Kolbel. The advanced systems were found to have a highly favorable impact on plant efficiency, product distribution and gasoline cost. If all the projected technical improvements can be realized for indirect liquefaction, the yields of refined transportation fuels per ton of coal will approach those anticipated for direct liquefaction processes.

Energy Technology Data Exchange (ETDEWEB)

Brown coal resources of the Latrobe Valley in Australia total 140 billion tons to a depth of 975 feet, while economically recoverable reserves have been calculated to total 57 billion tons. Although the coal provides only a very low heating value, about 3300 Btu/lb with 60% moisture content, the enormous seam thicknesses with little overburden allow large scale, open cut mining operations. The low cost and high reactivity of the coal is attracting extensive coal liquefaction research. Research into dewatering processes for the high moisture content brown coal is being conducted. The dried brown coal could be used both domestically and internationally for electricity generation and as an industrial fuel.

Energy Technology Data Exchange (ETDEWEB)

Special CoMo/Al{sub 2}O{sub 3} catalysts were prepared for testing in coal liquefaction: a conventional CoMo/Al{sub 2}O{sub 3} catalyst, one containing Zn as a second promoter and one having the alumina acidified with fluorine. Their activities were compared with that of red mud. The experiments were conducted in a stirred autoclave with a subbituminous coal and solvent (tetralin, anthracene oil or creosote oil) at 425{degree}C and 17 MPa. The liquefaction products were fractionated into oils, asphaltenes and preasphaltenes with pentane, toluene and THF. The Co(Zn)Mo/Al{sub 2}O{sub 3} catalysts have far higher activities than red mud. Zn and fluorine have beneficial effects on the catalyst activity. Coal tar distillates give higher conversions and oil + gas yields than tetralin when the prepared catalysts are used. 17 refs., 7 tabs.

Energy Technology Data Exchange (ETDEWEB)

The US DOE is calling on the nations' industries and academic institutions to develop a new approach for converting coal into liquid fuels at costs that can be competitive with imported oil. Based on a number of innovations, the department is looking for new approaches that can substantially reduce the cost of liquids from coal, essentially capping the price of imported oil. If successful, the new process will define the next generation of coal liquefaction technology and represent a dramatic improvement over the current state-of-the-art integrated two-stage process. 1 fig.

Science.gov (United States)

The US Department of Energy is carrying out a program of research and development to establish the capability to produce synthetic liquid fuels from coal. According to the National Energy Policy Plan IV, the Assistant Secretary of Fossil Energy is charged with carrying out a program to foster an adequate supply of energy at reasonable cost through innovative, long-term R and D. The payoff for this kind of research is potentially high if the country should need the capability on short notice. However, the research is also high risk in terms of the expectation of process for synthetic fuels to turn a profit for a private sector company. As the date when commercial quantities of synfuels will be needed has retreated before lower real prices of petroleum, the US DOE program for coal liquefaction has evolved to give increasing support to longer range, more exploratory technologies, rather than those nearly developed to the point ...

Science.gov (United States)

DOE's program for the conversion of coal to liquid fuels was begun by two of DOE's predecessor agencies: Office of Coal Research (OCR) in 1962, and Bureau of Mines, US Department of the Interior, in the 1930's. Current work is aimed at improved process configurations for both catalytic and non-catalytic processes to provide more attractive processing economics and lower capital investment. The advantage of coal liquefaction is that the entire range of liquid products, especially boiler fuel, distillate fuel oil, and gasoline, can be produced from coal by varying the type of process and operating conditions used in the process. Furthermore, coal-derived liquids have the potential for use as chemical feedstocks. To provide efficient and practical means of utilizing coal resources, DOE is supporting the development ...

Science.gov (United States)

This report summarizes the 1981 operating and test data obtained at the six ton per day Advanced Coal Liquefaction Research and Development Facility in Wilsonville, Alabama. Special emphasis is placed on data accumulated during the fourth quarter of 1981. The Wilsonville R and D Facility was in operation 71% of 1981 (70% of the fourth quarter) with scheduled shutdowns accounting for 23% of the downtime (28% during the fourth quarter). Kentucky 9 coal from the Fies mine was processed in all runs conducted during 1981 (Runs 222 through 235). The hydrotreater (HTR) unit was brought on stream successfully in May 1981. The three process units of the Wilsonville facility were operated in a non-integrated mode during the second half of 1981. Significant data was obtained and is summarized.

Science.gov (United States)

During this reporting period the experimental apparatus was completed after substantial delays by the manufacturer. The equipment has been fully tested to familiarize the staff with its operating and safety procedures. An initial liquefaction study has begun on samples of Utah coal (60 microns or less) using 50 grams of iron-titanium alloy, 500 ml of tetralin, and 150 grams of powdered coal at 500/sup 0/F and 500 psig. Results will be available in the next quarterly report. A new researcher has been added to the project to address the hydrogen absorption of new and recycled alloy samples. 2 figs.

Science.gov (United States)

The Advanced Coal Liquefaction Research and Development Facility in Wilsonville, Alabama, is funded by the US Department of Energy (DOE), the Electric Power Research Institute (EPRI), and Amoco Corporation. On behalf of these organizations, Southern Company Services manages and Southern Clean Fuels Division of Southern Electric International operates the Wilsonville facility. Oak Ridge National Laboratory (ORNL) receives funding from DOE to provide materials technical support to the Wilsonville operators. For the period July 1987 through November 1990 the plant was operated with two reactors a thermal reactor and a catalytic reactor in a close-coupled integrated two-stage liquefaction mode. Coal processed was obtained from several seams including Ohio No. 6, Illinois No. 6, and Pittsburgh No. 8, as well as Texas lignite and several subbituminous coals. Corrosion samples which were ...

Energy Technology Data Exchange (ETDEWEB)

The first part of the conference dealt with environmental effects of using coal. Papers dealt with the use of fly ash in agriculture and its effect on plant growth; the effect of airborne emissions on fish and wildlife resources, on watersheds, and on airsheds; the effects of surface mining on the ecology; blast effects; and health hazards associated with coal. The session on policy studies addressed the issue of cost of synthetic fuels and discussed the state and federal pollution regulations on burning coal and waste disposal. The session on combustion presented papers on atmospheric and pressurized fluidized-bed combustion for industrial and utility boilers. It also included papers on MHD power plants, coal-oil and coal-water mixtures, emission characterization and control, and catalytic combustors. The design of gasification plants, reaction kinetics, specific heats of ...

Science.gov (United States)

Prior to 1978, the Wilsonville Advanced Coal Liquefaction facility material balance surrounded only the thermal liquefaction unit and involved analyses of only the slurry stream and individual gas streams. The distillate solvent yield was determined by difference. Subsequently, several modifications and additional process units were introduced to this single unit system. With the inclusion of the deashing unit in 1978 and the catalytic hydrogenation unit in 1981, the process has evolved into a sophisticated two-stage coal liquefaction process and has the potential for various modes of integration. This report presents an elemental balancing procedure and a simplified presentation format that is sufficiently flexible to meet current and future needs. The development of the elemental balancing technique and the relevant computer programs to handle the calculations have been addressed. ...

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Previous laboratory tests of elastomer O-rings in coal liquefaction solvents conducted at L'Garde, Inc., indicated that certain ethylenepropylenediene monomer (EPDM) compounds provided the best performance when a backup ring was used to limit swelling. Before service testing in a pump at the Wilsonville, Alabama, Advanced Coal Liquefaction Research and Development Facility, tests of six selected elastomers in the appropriate Wilsonville-produced solvent were conducted at Oak Ridge National Laboratory (ORNL). The ORNL tests measured the elastomers' changes in cross section, weight, density, and relative flexibility. Although two perfluoroelastomers showed less degradation of most properties during these tests, it was decided to proceed with service testing of two EPDM elastomers because of their much lower cost. 5 refs., 14 figs., 7 tabs.

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The liquefaction reaction system of an NEDOL process coal liquefaction 1t/d PSU was opened and checked to investigate the cause of the rise of differential pressure between liquefaction reactors of the PSU. The liquefaction test at a coal concentration of 50 wt% using Tanito Harum coal was conducted, and it was found that the differential pressure between reactors was on the increase. By the two-phase flow pressure loss method, deposition thickness of deposit in pipelines was estimated at 4.4mm at the time of end operation, which agreed with a measuring value obtained from a {gamma} ray. The rise of differential pressure was caused by deposit formation in pipelines connecting reactors. The main component of the deposit is calcite (CaCO3 60-70%) and is the same as the usual one. It is also the same type as the deposit on the reactor wall. Ca ...

Science.gov (United States)

This report presents the operating results for Run 244 at the Advanced Coal Liquefaction R and D Facility in Wilsonville, Alabama. This run was made in an all-distillate Integrated Two-Stage Liquefaction (ITSL) mode using Illinois 6 coal from the Burning Star mine. The primary objective was to demonstrate the effects of temperature programming an aged catalyst batch on the ITSL product slate, especially on the net C/sub 1/-C/sub 5/ gas production and hydrogen consumption. Other objectives were to demonstrate the effect of fresh catalyst addition and to age the catalyst batch for an extended run with catalyst addition and withdrawal. Run 244 began on 4 July 1983 and continued through 27 September 1983. During this period, 182.9 tons of coal was fed in 1872 hours of operation. Seven special product workup material balances and two hydrotreater balances were defined, and the results ...

Science.gov (United States)

This topical report presents data and results obtained from the hydrogen microautoclave. The autoclave has been used to test for the quality of hydrotreater residue product and hydrotreater catalyst activity. Data obtained from Run 242 and the first part of Run 243 is presented in a convenient format and conclusions based upon this data are summarized. Some of the topics discussed in this report are the following: development and description of procedures for the catalyst and hydrotreater residue, the significance of test results and their meaning, and the relationship of test results to process performance. 7 references, 13 tables, 22 figures.

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The effect of method of sulfur addition on the hydrocracking activity of coal liquefaction catalysts was investigated using a high-pressure differential thermal analyser. The three methods of sulfur addition were: 1) physical mixing of 10 wt% elemental sulfur with red mud; 2) pre-sulfidation of red mud with hydrogen sulfide; 3) use of reagent grade pyrite. The pre-sulfided catalyst was slightly less active than the catalyst prepared by physical mixing, and both of these were changed to pyrrhotite in the course of use. Although the pyrite catalyst exhibited activity at markedly lower temperatures than those required for the other two catalysts, conversions were lower than had been expected. This is thought to be due to a different catalytic mechanism being involved. 13 references.

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For developing coal liquefaction processes, it is an important problem to improve the light oil yield with increased oil yield. It was previously reported that distillate mainly containing lighter fraction can be produced with high oil yield by reducing the iron/sulfur catalyst addition in slurry, by recycling gas in the process operation, by utilizing these effects, and by using heavy oil as recycling solvent. In this study, the maximum distillate yield of Victorian brown coal was investigated through continuous liquefaction using a bench scale unit. In addition, operation conditions for obtaining sufficient oil yield were investigated under the reduced catalyst addition into one-third. Consequently, it was confirmed that the maximum content of lighter fraction in distillate product was obtained with reduced catalyst addition by using heavy oil as recycling solvent, by adopting new catalyst, and by ...

Science.gov (United States)

Research continued on the synthesis of model compounds for coal liquefaction research. This report covers the actual laboratory investigation performed during the reporting period in order to attain the stated objective of the project, viz, the synthesis of a model compound containing tetrahydronaphthalene, naphthalene and phenyl moieties linked by methylene, ethylene and ether bonds. The overall synthetic approach aimed at obtaining the end product has been broken down into three major steps that involve the synthesis of three key reactive intermediates. These are: (1) 3,5-dimethyl-5-bromobenzyl chloride, (2) 1-chloromethylene-2-hydroxytetralin and (3) 2-chloromethylene-1-hydroxynaphthalene.

Science.gov (United States)

This report presents an overview of research activity currently being funded by the US Department of Energy (DOE) on solid wastes from coal gasification, coal liquefaction, and oil shale technologies, Projects conducted in the DOE energy technology centers and national laboratories, and in cooperative projects with other government agencies, private industry, and universities are developing the basic and applied technology and data on which present and future fuel-conversion and utilization processes depend. The report identifies data gaps and recommends research needs where warranted.

Energy Technology Data Exchange (ETDEWEB)

The Project was started August 1, 1992. During these first two months, the Project Management plan was issued and approved during discussions at the Pittsburgh Energy and Technology Centre. Feed materials for the experimental work (with the exception of the second solvent) have been received. The analytical work up of these feed materials has been completed, and autoclave stability tests with the solvent and solvent fraction have been performed and analyzed. The Project is proceeding on schedule.

Science.gov (United States)

Recent fuel cost increases coupled with energy shortages have resulted in an awareness of the need to conserve energy and to expand the United States domestic energy base. Increase in coal conversion and utilization are major objectives of the research and development activities in the US Department of Energy. Several alternate processing schemes are being developed to convert coal to environmentally acceptable liquid fuels. A few of these technologies are approaching the commercialization stage and scale-up is being carried forward on the most promising processes. The various coal liquefaction processes are discussed by dividing them into four general classifications. Processes for converting various types of coal to synthetic liquid fuels are being improved so that clean fuels can be produced commercially. Emphasis is on the production of fuels suitable for firing industrial and ...

Energy Technology Data Exchange (ETDEWEB)

This report describes progress on the Advanced Coal Liquefaction project by the Gulf Research and Development Company's Merriam Laboratory during the months of January through March 1983. The liquefaction behavior of Illinois No. 6 coal beneficiated in various ways was studied in both single-stage recycle (SRC II) and short contact time (SCT) modes of operation. The distillate yield increased as the iron level in the feed slurry increased in both modes of operation. In the SCT mode, the conversion increased at greater depths of cleaning. In the SRC II mode, the distillate yield and conversion were much higher with deep cleaning and add-back of pyrite than with conventional cleaning. Pyrite addition resulted in a significant increase in short contact time conversion of subbituminous Belle Ayr coal in both high and low quality solvents. Solvent quality itself, however, had ...

Science.gov (United States)

There are five tasks within this project on thermally stable coal-based jet fuels. Progress on each of the tasks is described. Task 1, Investigation of the quantitative degradation chemistry of fuels, has 5 subtasks which are described: Literature review on thermal stability of jet fuels; Pyrolytic and catalytic reactions of potential endothermic fuels: cis- and trans-decalin; Use of site specific {sup 13}C-labeling to examine the thermal stressing of 1-phenylhexane: A case study for the determination of reaction kinetics in complex fuel mixtures versus model compound studies; Estimation of critical temperatures of jet fuels; and Surface effects on deposit formation in a flow reactor system. Under Task 2, Investigation of incipient deposition, the subtask reported is Uncertainty analysis on growth and deposition of particles during heating of coal-derived aviation gas turbine fuels; under Task 3, Characterization of solid gums, sediments, and ...

Energy Technology Data Exchange (ETDEWEB)

The effect of two iron catalysts, red mud and CGS S-G, as well as Co-Mo/Al/sub 2/O/sub 3/ and Ni-Mo/Al/sub 2/O/sub 3/ commercial catalysts on the composition of oil derived from the liquefaction of Japanese subbituminous coal have been investigated comparatively by conventional autoclave experiments at 440 and 450C under initial hydrogen pressure of 85kg/cm/sup 2/ . G with tetralin to coal weight ratio of 3. From the results obtained at 450C, total conversion and the yield of gas revealed almost same level with four catalysts, but the oil product from molybdenum catalysts showed higher yield than that from iron catalysts. CGS S-G catalyst also showed higher yield of oil product than red mud catalyst. Reaction behavior of two iron catalysts were also tested by solvent recycle mode experiments.

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This report describes studies made during the fourth quarter of 1986 using the revised microautoclave experimental technique. Studies were made of the effect of reaction time on conversion using Kemmerer coal. Results that, at least during the first 30 minutes, conversion is a monotonically increasing function of reaction time and temperature. A study was also made of the effect of temperature on conversion. In general, conversion increased with temperature. The reactivity of coal appears to be unaffected by exposure to Certigrav fluid, if the exposed coal is subjected to two acetone washings under a nitrogen blanket. Work was started on using SCR-II process solvent in place of tetralin. Results indicate that SRC-II process solvent is a satisfactory solvent donor for high reactivity, high ash bituminous coals, but slightly less effective for low ash, subbituminous coals. Some tests ...

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This report presents the results of work which included extensive modifications to HRI`s existing 3 ton per day Process Development Unit (PDU) and completion of the first PDU run. The 58-day Run 1 demonstrated scale-up of the Catalytic Two-Stage Liquefaction (CTSL Process) on Illinois No. 6 coal to produce distillate liquid products at a rate of up to 5 barrels per to of moisture-ash-free coal. The Kerr McGee Rose-SR unit from Wilsonville was redesigned and installed next to the US Filter installation to allow a comparison of the two solids removal systems. Also included was a new enclosed reactor tower, upgraded computer controls and a data acquisition system, an alternate power supply, a newly refurbished reactor, an in-line hydrotreater, interstage sampling system, coal handling unit, a new ebullating pump, load cells and improved controls and remodeled preheaters. Distillate liquid yields of 5 ...

Energy Technology Data Exchange (ETDEWEB)

Coal was treated at high temperature under high pressure in the binary system mixed solvent of water and organic solvent, and the solvent treated coal was liquefied. When the treated coal was treated again by the explosive method in which high temperature and pressure were released immediately, the oil yield was higher than that by the normal method in which high temperature and pressure were reduced gradually to room temperature and atmospheric pressure. In this study, an explosive treatment unit with increased scale of sample amount was newly fabricated. Illinois No.6 coal was treated by the explosive method in a mixed solvent of water and cyclohexanol using this unit. Changes in shape on the surface, specific surface area, and functional groups were analyzed. The explosively treated coal contained more amount of low boiling point components than the normally treated ...

Energy Technology Data Exchange (ETDEWEB)

Research over a three year time span involved the study of multiphase flow useful to understanding the scaleup of coal liquefaction reactors. We attempted to establish the flow patterns and their boundaries in which a direct coal liquefaction, large diameter, bubble column operates. A flow map has been proposed in which coal slurry properties can be input to determine the flow pattern boundaries at reactor operating conditions. Gas holdup and bubble diameters have been measured under different conditions of gas and liquid flow rate. These have been used to determine interfacial area in bubble columns. An equation for the estimation of interfacial area in the bubble-slug flow pattern has been proposed. It has also been established that gas holdup and thus interfacial area depends strongly on the gas distribution in the column. Porous plate gas distributors can yield gas holdups twice ...

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This document describes the geology and hydrogeology at the former Advanced Coal Liquefaction Research and Development (ACLR&D) facility in Wilsonville, Alabama. The work was conducted by personnel from the Oak Ridge National Laboratory Grand Junction office (ORNL/GJ) for the U.S. Department of Energy (DOE) Pittsburgh Energy Technology Center (PETC). Characterization information was requested by PETC to provide baseline environmental information for use in evaluating needs and in subsequent decision-making for further actions associated with the closeout of facility operations. The hydrogeologic conceptual model presented in this report provides significant insight regarding the potential for contaminant migration from the ACLR&D facility and may be useful during other characterization work in the region. The ACLR&D facility is no longer operational and has been dismantled. The site was characterized in three phases: the first two ...

Energy Technology Data Exchange (ETDEWEB)

Room-temperature phosphorescence (RTP) has generated considerable interest over the past several years. Several materials have been used to induce RTP from a variety of compounds. However, there is still a need to test additional materials and experimental conditions for RTP so the maximum sensitivity and selectivity can be obtained. In this work, three solid surfaces and several experimental conditions were tested for RTP of nitrogen heterocycles and aromatic amines. Nitrogen heterocycles and aromatic amines are an important class of compounds as shown by work in areas such as environmental research and coal liquefaction research. 18 references.

British Library Electronic Table of Contents (United Kingdom)

Methods of X-ray diffraction and transmission electron microscopy were used to study the microstructure of dispersion-strengthened Cu-Al2O3 nanocomposites obtained by the method of simultaneous deposition of Cu and Al2O3 from the vapor phase. The effect of the size of particles of the oxide (Al2O3) and of their content on the electrical resistance of the composite has been considered. The results obtained make it possible to suppose that the main structural factor that determines the electrical resistance of the composite are nanodispersed particles of Al2O3 with a size of less than 20 nm.

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

Energy Technology Data Exchange (ETDEWEB)

Among the items of the Sunshine Project in fiscal 1981 for development of a solvent extraction and liquefaction plant, this paper describes the achievements in developing secondary hydrogenation. A small continuous hydrogenation device equipped with three reaction columns that can be filled with catalyst of 50 cc, and a dedicated testing room were designed, and orders were placed with manufacturers. The fabrication, assembly, delivery, installation, piping and wiring were all completed. The device passed a completion inspection based on the high-pressure gas safety assurance law in December 1981. After leakage due to gas and material oil was checked, a trial operation was performed, and verified of normal operation. A screening test was carried out on three kinds of commercially available and prototype catalysts before testing the SRC containing material for studying the secondary hydrogenation. The circulating solvent having a boiling point from 180 to 430 degree ...

Energy Technology Data Exchange (ETDEWEB)

Over the past 25 years there have been a large number of long runout flowslides from Rocky Mountain coal mine waste dumps. The waste dumps are constructed as end-dumped fills with an angle of repose of 38{degrees}. Dump heights range between 100 and 400 m. The dumps are normally founded on mountain slopes that are covered with a thin veneer of granular colluvial and dense stony fill materials. Conventional stability analyses carried out for these dumps using friction angles equal to the angle of repose for the waste rock and typical values ranging from 30 to 32{degree} for the foundation materials indicate that many should be stable. The flowslides occur rapidly and display surprisingly long runouts of up to 2 km in some cases. Detailed studies of three of these events indicate that static collapse of saturated or nearly saturated sandy gravel layers within the dumps may be responsible for the initial failure and the generation of high pore pressures which result ...

Energy Technology Data Exchange (ETDEWEB)

Coal liquefaction investigations required the availability of model compounds for mechanistic investigations. Towards this end, IITRI was funded to develop an approach for the synthesis of one of the target compound. This study was carried out in several phases as outlined here. Initial synthetic investigations on obtaining 2-tetrolol was carried out using high pressure and temperature reduction with Raney nickel catalyst. The next step consisted in incorporation of a hydroxymethyelene group at the C-3 position. This was successfully carried out utilizing 2-tetrolol, formaldehyde, and calcium oxide. An alternate improved method was developed using 3-carboxyl-2-naphthol. This required less time, gave a cheer product in higher yield. Efforts at the introduction of a chloromethylene group only yielded polymeric material or starting material in spite of protection the phenolic group by various groups. They synthesis of 3, 5-dimethyl-6- bromobenzyl ...

Science.gov (United States)

Processes for the hydrogenation of carbon monoxide have had commercial importance since about 1920, when the commercial production of methanol and higher alcohols on oxide catalysts began. Soon thereafter Fischer and Tropsch discovered that liquid hydrocarbons could be synthesized from carbon monoxide and hydrogen over Group VIII metal catalysts. Following extensive catalyst and process development efforts, this technology provided Germany with a source of liquid fuels during World War II. The period following the war saw an acceleration in research and development on the Fischer-Tropsch process, but the only commercial application that was to emerge was the SASOL process in the Union of South Africa. The oil crises of the 1970s have rekindled worldwide interest in indirect liquefaction technologies for the production of clean, high-quality motor fuels from coal. The development of more efficient coal gasification processes ...

Science.gov (United States)

Separate comprehensive final reports on the status of the SRC-II Demonstration Plant Design and on operating experiences at the Ft. Lewis and P-99 SRC pilot plants were prepared after the termination of those projects. However, time constraints made it impossible to consolidate all of the pilot plant data and operating experiences and relate these to the Demonstration Plant or future plant design. Most of the experimental programs during the later stages of pilot plant operation were in direct support of specific technical uncertainties identified in design work. The results of these programs would have been of substantial use in verifying or modifying design philosophy had the project proceeded. This technical data analysis project was undertaken to consolidate the pilot plant results presented in numerous reports under DOE Contract DE-AC01-79ET10104 for operation of the pilot plants, and to relate these results to specific Demonstration Plant uncertainties. The needs for and ...

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It is thought that iron-based catalysts for coal liquefaction exercise their catalytic activity by forming pyrrhotite (Fe(1-x)S). However, there are still a lot of unknown problems remained concerning the formation and agglomeration behaviors of pyrrhotite. These make a difficulty for improving the activity of iron-based catalysts. In this study, sulfiding behaviors of {alpha}-iron oxyhydroxide ({alpha}-FeOOH) and {gamma}-iron oxyhydroxide ({gamma}-FeOOH) were investigated to reveal the formation and agglomeration behaviors of pyrrhotite. It was found that pyrrhotite was easily converted from ferric oxyhydroxide catalysts having large specific surface areas at the sulfiding temperature below 250{degree}C, and fine crystallites of pyrrhotite were formed at the initial stage of sulfiding. Crystal growth of pyrrhotite at the sulfiding temperature over 350{degree}C depended on the catalyst forms. It was also found that smaller crystallites of ...

Energy Technology Data Exchange (ETDEWEB)

Until now the assumption has been that synthesis gas - mixtures of carbon monoxide and hydrogen - would be the principal source for many of the chemicals and fuels to be made via C/sub 1/ chemistry. Efforts to make cheap synthesis gas continue. But the pressure to circumvent the stranglehold that OPEC has on petroleum has caused other avenues to be explored. The current oversupply of natural gas offers an interim solution to the problem of nonpetroleum alternate source materials for C/sub 1/ chemicals production. The paper discusses the constraints and advantages of four processes: conventional steam reforming, steam reforming with oxygen secondary, partial oxidation, and catalytic partial oxidation. The end product in all cases is methanol. Direct use of methanol as a fuel has encountered numerous difficulties. conversion of methanol is, thus, of more immediate interest in C/sub 1/ chemistry. The Mobil MTG process and its second-generation modifications, both producing high-grade ...

Science.gov (United States)

Having recently discovered that polynuclear heteroaromatic nitrogen compounds can be selectively reduced only at the nitrogen containing ring, we have now turned our attention towards the cleavage of the carbon nitrogen bonds in this reduced ring. Highlights for this reporting period are: (1) Studies with the 50% nickel oxide catalyst clearly show that 1,2,3,4-tetrahydroquinoline(THQ) provides approximately 20% more liquid product that does quinoline. Thus a first step selective hydrogenation to 1,2,3,4-THQ would enhance the overall HDN reaction to provide a more substantial conversion to substituted benzene and aniline derivatives. (2) The dramatic effect of the nitrogen atom is to inhibit aromatic ring hydrogenation and, to some extent, carbon-carbon bond hydrogenolysis reactivity. This is shown with proplybenzene as the substrate, where only methane gas is produced in the HDN reaction with the 50% nickel oxide catalyst. (3) The HDN reaction of cyclohexylamine only provides benzene ...

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Research programs, presented at the contractor's review meeting on indirect liquefaction, are presented on the following topics: oxygenates (methanol) synthesis; Fischer-Tropsch synthesis; product upgrading; and process support engineering evaluations. A total of 18 reports are included. Individual projects are processed separately for the data bases. (CBS)

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A total of nine papers were presented at the course with the following titles: peat accumulation and coal basins; coal composition; coal quality; sedimentary environments of coal; generation, storage and migration of natural gas in coal bed reservoirs; geophysical log interpretation; the Ardley coal zone of central Alberta; stratigraphy and sedimentary environment of the Coalspur Formation; and the coal-bearing Luscar Group of western Alberta. All of these papers have been abstracted separately.

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An investigation of the effect of blending of two different coals in various ratios on the hydrogenation reaction was carried out using a red mud-sulphur catalyst. Three Japanese coals and an Australian brown coal were used in the study. The conversion of the blended coals was compared with that obtained with each of the coals alone. A blend of the Yallourn brown coal and Shin-Yubari coal showed a synergism: it is considered that hydroaromatics from the Japanese coal promote the hydrogenation of the Yallourn coal. (The tables and captions in this paper are in English).

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Performance of various catalysts for hydrogenation of recycle solvent was evaluated for the operation of NEDOL process 1 t/d process supporting unit (PSU). Distillate between 220 and 538{degree}C derived from the liquefaction of Tanito Harum coal was used as recycle solvent. Deactivation behaviors of catalysts were compared using a prediction equation of catalyst life, by which aromatic carbon index (fa) after hydrogenation can be determined from the fa of recycle oil before hydrogenation, reaction temperature, and total hydrogenation time. Total hydrogenation time satisfying the {Delta}fa, 0.05 before and after hydrogenation were 8,000, 4,000, and 2,000 hours for NiMo-based catalysts C, A, and B, respectively. Catalyst C showed the longest life. Used catalysts were also characterized. The catalyst C showed larger mean pore size than those of the others, which resulted in the longer life due to the delay of pore blockage. From measurements by ...

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The use of low rank coal leads to a reduction of the coke strength because of the reduction of the caking property of coking coal. The authors have tried to understand this mechanism by extracting and analyzing the caking component of low rank coal and coking coal. It was found that the caking component is decreased by radical attack from the low rank coal, and thus the caking property is reduced. 11 figs., 3 tabs.

British Library Electronic Table of Contents (United Kingdom)

This paper seeks to investigate the liquefaction of clayey soils, a phenomenon that has been the trigger for many natural disasters in the last few decades, including landslides. Research was conducted on artificial clay?sand mixtures and natural clayey soils collected from the sliding surfaces of earthquake-induced landslides. The undrained response of normally consolidated clayey soils to cyclic loading was studied by means of a ring-shear apparatus. For the artificial clay?sand mixtures, it was found that the presence of a small amount of bentonite (?7%) would cause rapid liquefaction, while a further increase in bentonite content (?11%) produced the opposite effect of raising soil resistance to liquefaction by a significant degree. It was demonstrated that the bentonite?sand mixture wa...

Science.gov (United States)

Blast furnace coke containing low grade coal in a high blending ratio is manufactured by a method which comprises blending not less than 60% of a blended coal having an adjusted total moisture content of not more than 4% with not more than 40% of briquettes and carbonizing the resultant mixture. The blended coal consists essentially of not less than 80% of coking coal and not more than 20% of low grade coal. When coking coal of a kind which has its coking property segregated according to its grain size distribution is pulverized and classified by sifting and the portion of fine particles is used as mixed with the coking coal, the blending ratio of the low grade coal in the blended coal can be increased to up to 35%. The briquettes consist essentially of not less than 10% of coking ...

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This article puts the case for coal fired combined cycle gas turbine (CCGT) power plants. The need to gasify the coal for the CCGT, use of fluidised bed combustors or gasification systems, the difference in prices of coal and natural gas, and coal and natural gas reserves are discussed. (UK)

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The dispersion mechanism of highly loaded coal-water mixture (CWM) in the presence of a polyelectrolyte additive was investigated. Two important factors have been found: the ability of the additive to apply a sufficient electric repulsive force to the coal particles, and an appropriate affinity of the additive to the coal surface.

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Combustion performance trials were conducted on a commercial sample of Coal Valley coal from the Coalspur coalfield in the foothills region of Alberta. The project included an analytical investigation of the coal and coal ash properties as well as combustion studies in the CCRL pilot-scale, pulverized coal-fired boiler, under conditions representative of those in large steam boilers. This report gives the objectives of the project, the analyses of the coals, and describes the facilities and operational procedures. An evaluation of the experimental results and the conclusions are presented.

Science.gov (United States)

... ENERGY CONSERVATION, ENERGY CONSUMPTION, ELECTRIC POWER DISTRIBUTION, FOSSIL FUELS, COAL, BRAYTON CYCLE. ...

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Stability concerns of the Par Pond Dam, an embankment structure in the Savannah River Site complex, resulted in a comprehensive evaluation of the state of its integrity. Specifically, excessive seepage through the embankment, slope failure due to an earthquake event as well as liquefaction potential of the embankment and the foundation are addressed and the potential of failure is evaluated. Lastly, remedial benefits of the addition of a berm structure are also assessed.

Energy Technology Data Exchange (ETDEWEB)

Recent earthquake disasters have revealed the importance of countermeasures against soil Liquefaction in seismic design. In particular, the 1995 Hyogoken Nanbu earthquake caused several types of severe damages to pile foundations. This paper describes an analysis method for soil liquefaction using simple parameters such as SPT-N values and seismic response analyses for the pile-supported structure to consider soil-structure interaction effects and soil non-linearity using a modified Penzien model. It is important to find a way to determine the region of surrounding soil whose behavior is identical to that of piles. This paper adopts the thin layer element method to systematically determine the volume of the surrounding soil. The responses of pile-supported structure are similar, whether soil liquefaction and nonlinearity of pile are considered or not. However, the bending moment of pile become large as to soil ...

Science.gov (United States)

During 1978 the Engineering Board of SRC granted Specially Promoted Program status to the Coal Technology program. This recognized that coal would increase in importance as the cost of liquid and gaseous hydrocarbons rises with the decreasing availability of petroleum related sources. It was, therefore, considered necessary to anticipate and improve, through SRC supported research, the technologies required to win, transport, convert to liquid and gaseous fuels and utilize coal and coal based substances. In view of the interest in the program, and also in the hope of reaching a still wider audience the reports of the two meetings have been combined in this single booklet. The reports indicate specific problems of importance in coal winning and coal conversion but, naturally, do not cover all of the program priorities.

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The objectives of the Upgraded Coal Interest Group (UCIG) are as follows: Review and update the status of various coal upgrading technologies and developments and critically assess the results. Perform engineering screening analyses on various coal upgrading approaches. Perform commercialization analyses that will promote the availability and use of upgraded coal products by quantifying the benefits of using them. Identify market opportunities for introduction of upgraded coals. Perform critical analyses on a variety of coals and technologies in areas important to users but not readily available. Perform critical experiments which will show the differences between technologies.

Energy Technology Data Exchange (ETDEWEB)

Discusses Czechoslovak regulations for determining moisture content in brown coal. Standard formulae for determining total moisture content and residual water content are described. Factors that influence accuracy in determining moisture content under laboratory conditions are analyzed: brown coal type, season of the year, air humidity, method and duration of coal sample drying, number of coal samples simultaneously dried in 1 dryer, ash content of coal. On the basis of analysis recommendations for a modified method of determining moisture content in brown coal are made. 5 refs.

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The coal rank, coal distribution, and coalbed methane of four major coal zones in the Hinton and Grande Cache areas of Alberta were investigated. Coal rank in the study area ranges from subbituminous and high volatile C bituminous at surface for the Upper Cretaceous/Tertiary coal measures and semianthracite for the Lower Cretaceous Luscar Group in the Alberta Syncline. In the Rocky Mountain Foothills, maximum cumulative coal thicknesses occur in the Smoky River, Cadomin-Luscar, and Coal Valley coalfields. Cumulative coal thicknesses generally decrease east of the deformed belt; however, coal isopach maps indicate local cumulative coal thicknesses in excess of 25 m. A regional coalbed methane assessment for strata east of the deformed belt shows favorable coalbed methane ...

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Three typical Japanese coals of non-coking coal, coking coal and anthracite were heat-treated with KOH, and change in their pore structure was examined by absorption of N2, X-ray diffraction and TEM observation. In addition, the relation between a coal rank and pore structure was also studied by absorption experiment of N2. In experiment, the mixture of coal and KOH in a nickel holder was heat-treated in N2 gas flow at heating rate of 2{degree}C/min, and held at a fixed temperature for one hour. To clarify the pore structure, N2 absorption isotherms were measured at -196{degree}C under nearly 76cmHg using a commercially available full-automatic absorption measurement equipment. Based on the X-ray diffraction and TEM observation results on activated coals, the relation between the N2 absorption and pore structure was studied. The results are summarized as ...

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This paper discusses organizational models of planning technology development in coal mining. The following 4 planning systems are analyzed: all-union national system coordinated by the Ministry of Coal Mining of the USSR, all-union associations of coal mine associations (in the Ukrainian SSR the plan is developed by the Ministry of Coal Industry of the Republic), associations of coal mines, coal mines or groups of coal mines. Methods for developing programs for technology development at 4 levels are reviewed. The following planning periods are used: 10 years or more (from 1980 to 1990), a 5 year period and a 1 year period. System for technology development in the Soviet coal industry from 1981 to 1985 is evaluated: research and development programs (20 comprehensive state programs, 36 branch programs). (In Russian)

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The nature and relationship of methane to coal mines is discussed and sources of information are outlined. Methods of gas analysis in general and methods for the detection of methane in use in coal mines are described. Methods of remote detection of gases and those that have application for use in underground coal mining operations are discussed. The report represents recommendations on remote methane detection systems that may find application in underground coal mines. (20 refs.)

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This paper reports a recent feasibility study of a scheme to transport thermal coal as a coal-water slurry by pipeline from Coalspur, Alberta to the west coast of Canada. The base case is for the transport of 10.2 million tons of coal annually, and an expanded case of 18.2 million tons is also considered. Coal would be drawn from 5 mines within a 16 km radius of Coalspur. Several different terminal layouts were considered.

Science.gov (United States)

In addition to an executive summary and glossary, the following sections are included: Clean Boiler Fuel Demonstration Plant; Development of Coal Feeders for Coal Gasification Operations; Development of a Continuous Dry Coal Screw Feeder; Coal Feeder Development Program; Engineering and Technical Support; and Technical Assistance Services. (EJH)

Science.gov (United States)

Finely divided ash-containing coal is immersed in an aqueous solution of hydrochloric acid or citric acid, and acidic ammonium fluoride to cause the ash to react with the acid and the acidic ammonium fluoride, and the deashed coal is thereafter separated from the solution.

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The overall objective of this project was to use molecular genetics to develop strains of bacteria with enhanced ability to remove sulfur from coal, and to obtain data that will allow the performance and economics of a coal biodesulfurization process to be predicted. (VC)

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The article reviews the Rothschild First Interim Report on the future of the British Coal Industry and British Coal Corporation. The report incorporates work undertaken by the Joint Working Groups set up with British Coal. The article points out various errors in the report and criticizes its conclusions.

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The increasing price differential between natural gas and coal will create a demand for technology that can allow the displacement of natural gas with coal in power plants. Coal gasification is the standard approach suggested to allow coal to displace natural gas. However, the relatively high capital investment required for coal gasification will require fuel cost differentials higher than those anticipated in the near term before coal gasification replaces natural gas. One way of achieving shorter term displacement of natural gas by coal would be to develop technology that would allow coal to be used as the heat source for the endothermic reforming of natural gas. In a natural gas-fired combined cycle power plant, the endothermic heat of reforming, which would be provided by coal combustion, is ...

Science.gov (United States)

The Eighth Indirect Liquefaction Contractors' Review Meeting was held November 15-17, 1988 at the Pittsburgh Hyatt Hotel. Twenty-eight presentations were made by contractors, invited speakers, and Pittsburgh Energy Technology Center R and D personnel. Six areas of research were covered: synthesis gas conversion to oxygenates; light hydrocarbon gas conversion; slurry reactor hydrodynamics; production, clean-up and conversion to hydrocarbon fuels; Fischer-Tropsch products upgrading; and, synthesis gas bioconversion. The meetings also included a panel discussion on direct methane conversion research. Individual projects are processed separately for the data bases.

Energy Technology Data Exchange (ETDEWEB)

Examines thermal coal demand in Japan covering: trends in energy demand; long-term outlook for energy supply and demand; coal-fired power development plan and the outlook for steam coal demand; and the prospects for Asian steam coal demand and coal procurement. Total energy consumption is expected to increase by 1.0% per annum to 2000 and thereafter 0.9% per annum until 2010. This is based on the assumption that measures to encourage energy conservation and improve energy efficiency are implemented. 3 figs., 2 tabs.

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A study is made of the metamorphism of coals in Kuznetsk Basin. To interpret the stages of coalification, measurements were used of the indicators of vitrinite along the hinges of folds, graphic plottings of isometamorphism of coals, analysis of interrelationships of the isolines of coal metamorphism with isopachites covering their deposits. The elevation of the coal mass of Kuzbass in the post-inversion time was accompanied by the formation of steep linear folds and longitudinal bending of their hinges. As a consequence of this, the hinges of the folds in beds of the same name occurred at different depths from the modern surface, however coal metamorphism along the hinges has not changed. In the Kuznetsk Basin there are no traces of post-inversion coalification.

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Coal slurry pH values can be used to characterize coals. pH values depend on the coal, time since slurry preparation, contact with gas atmosphere, particle size, and stirring. Measured values reflect a sequence of reactions including: carbon dioxide absorption by water from the air, wetting of the coal (pH may be affected by the elemental composition of the mineral matter), and further equilibration with species in the water. The pH initially drops as carbon dioxide is absorbed, then rapidly increases as the coal is wetted, and then slowly decreases as some reactions with species in the water take place.

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Traditional methane drainage methods, including conventional ventilation and boreholes drilled in the coal seam, are widely used in modern coal mining operation in China. However, it is often noted that the gas drainage presents low efficiency in most coal mines due to low permeability of the coal seam, which not only affects the safety, but also the productivity of the coal mine. This paper describes the development and application of the waterjet cutting system, which is used to create artificial fractures and increase the permeability of coal seam for the improvement of methane drainage in underground coal mines in China. According to underground monitoring, a significant improvement of methane drainage efficiency of up to 3 to 6 times over the traditional methods has been achieved. (author)

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New York State Electric and Gas Co. (NYSEG) has developed a tool called Coal Quality Engineering Analysis (CQEA) to evaluate the cost impacts of coal quality on its power plants. CQEA allows quantification of the effect of coal quality on plant operating costs and has become an important factor in coal purchasing. The article describes the development of the analysis method, including a logic diagram of CQEA relationships. The results of CQEA calculations on the impact of one coal on overall production costs of different units, the impact of different coals on overall production costs of one unit, and production cost vs. coal quality, are presented and discussed. The use of the CQEA system within NYSEG is described.

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A workshop on radioactivity in coal use was held on September 15 through 17, 1981, under the auspices of the US Department of Energy, Office of Environmental Programs, and the Los Alamos National Laboratory. The purpose of the workshop was to identify research issues associated with radioactivity resulting from the use of coal for electric power generation. The concensus of the 10 scientists participating in the workshop was that a moderate to strong need exists for research in solubility of fly ash in different fluids and for determination of radioactivity in construction materials. Several additional research issues were identified but were given a lower priority. Summaries of each presentation are included. Titles are: some effects of coal combustion on the radiation environment; radionuclides in western coal at Mound; low-level radiation in coals utilized and ashes produced at ...

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Continually rising energy prices in global markets highlights a serious concern about the need to improve energy efficiency and the efficiency in the energy sector in many countries. China, as one of the fastest growing countries in the world and the largest coal producer, has high coal consumption but a low recovery rate of coal utilization. Coal efficiency and the efficiency in coal industry have therefore attracted a great deal of attention from Chinese policy makers, coal companies and academics. This study attempts to compare the relative technical efficiency performance of listed coal mining companies in China and the US using CCR and BCC models in advanced data envelopment analysis (DEA) linear programming. The results show that the level of relative efficiency in Chinese coal mining enterprises, regardless of ...

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The DOE Working Group for an Assessment of Coal-Gasification Research Needs (COGARN - coal gasification advanced research needs) has reviewed and evaluated US programs dealing with coal gasification for a variety of applications. Cost evaluations and environmental-impact assessments formed important components of the deliberations. We have examined in some depth each of the following technologies: coal gasification for electricity generation in combined-cycle systems, coal gasification for the production of synthetic natural gas, coal gasifiers for direct electricity generation in fuel cells, and coal gasification for the production of synthesis gas as a first step in the manufacture of a wide variety of chemicals and fuels. Both catalytic and non-catalytic conversion processes were considered. In addition, we have constructed an orderly, ...

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The object of briquetting coal fines is to convert a low grade fuel into one of superior quality coal. Briquetting techniques make coal an attractive substitute fuel by converting it into a compact, stable and inexpensive fuel. The briquetting of coal fines and char fines from coal and lignite, coke breeze, charcoal fines and similar materials is an important process for producing shaped fuel for a number of uses. Formed-coke made from non-caking coal for use in a blast furnace or in a cupola furnace involves the briquetting of treated char fines and further processing of the briquettes by means of carbonizing and curing. Briquettes may be made with or without binders, brown coal is particularly suitable for briquetting without a binder. Heat treatment may enable a higher rank coal to be briquetted without a binder, but ...

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The coal bed methane (CBM) potential of five coal zones (the Kootenay, Gething, Gates, Brazeau, and Coalspur) in the Alberta foothills and mountains is re-evaluated. For evaluation, the coal zones are divided into shallow (200 to 2500 m depth) and deep (over 2500 m depth). The total gas content is estimated. Recommendations on how to obtain more reliable resource data and about producibility are included. 41 refs., 12 figs., 3 tabs., 2 apps.

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This document contains the outline and viewgraphs used in the speech. Topics covered are: conventional oil and gas recovery; unconventional oil and gas sources; oil shale resources; conventional coal combustion; advanced fossil power systems; fluidized bed combustion; coal/oil or coal/water mixtures; and gaseous and liquid fuels from coal. (DMC)

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The paper discusses clean coal technology developments in India. 2 photos.

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Discussion is presented of world crude steel production, the Japanese steel industry and its expectations of the Canadian coal industry. It is concluded that the Canadian coal industry should pay attention to the trend in customer's requirements regarding coal quality, maintain price competitiveness in the international market place, and remain flexible with regard to the market trend.

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This book presents the papers given at a symposium on occupational safety in coal mines. Topics considered at the symposium included human factors, causes and prevention of personal injuries, remote sensing for ground control, respirable dust generation by continuous miners, accident analysis, hazard analysis of mining equipment, coal mine blasting accidents, coal mine respirable dust sampling, and noise in the mining industry.

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Past and current development of coal utilization technology in the Japanese steel industry is reviewed and some projects currently under research and development briefly described. These include DIOS, an iron making process which directly utilizes both iron ore and coal without a sintering plant or a coke oven; and the development of a new generation coke oven. 15 figs.

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This report attempts to bring together available information on the coal deposits of Antarctica and discuss factors that would be involved if these deposits were to be explored and mined. Most of the reported principal coal deposits in Antarctica lie generally within the Transantarctic Mountains: the majority are of Permian age and are present in the Victoria Group of the Beacon Supergroup. Several other deposits have been recorded in East Antarctica and in the Antarctic Peninsula, including minor occurrences of Mesozoic and Tertiary coal and carbonaceous shale.

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Energy consumption of black coal mines in Poland and methods for energy conservation are evaluated. Organizational models of energy management in underground coal mining are discussed. Tasks for dispatcher service for energy consumption control in a coal mine are analyzed: control of energy supplies, control of energy consumption, evaluation of electrical failures and reliability of protection systems, recording accidents and analyzing their causes, optimization of power systems in underground mines. Problems associated with control of energy consumption in a coal mine with mechanized systems for coal mining and use of computerized control systems are discussed. Recommendations for reucing energy consumption in underground coal mining are made. 4 references.

Energy Technology Data Exchange (ETDEWEB)

Electrostatic beneficiation of dry coal has received significant attention in the last decade. In this process the coal is ground and then charged, either by corona charging or by triboelectrification (friction charging). Coal and minerals receive different levels of charge -- often opposite polarities in the case of triboelectrification -- and can then be separated based on differences in electrical mobility. Problems associated with the techniques include rapid deposition of particles on the electrodes, thus, effecting further separation. The goal of this project is to optimize the electrostatic coal cleaning process to remove pyrites and inorganic materials through studies of the electrostatic properties of powdered coal, in-situ measurements of the electrodynamics of coal and mineral particles inside the separator, and development of self-cleaning collector ...

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This paper describes an outline of solid fuel production process from brown coal and the investigation results of its elemental techniques. Dried coal is produced by this process which consists of a dewatering of crushed brown coal in oil-based solvent, a solid and liquid separation of slurry, and a remained oil recovery by heating. This process is characterized by the higher thermal efficiency compared with usual drying and the restraint of spontaneous combustion of product coal. It was revealed that solid fuel with low moisture, low ash, low sulfur, and suppressed spontaneous combustion property can be produced from Australian brown coal through this process. From the comparison between kerosene and fuel oil A, it was confirmed that the oil content during dewatering was smaller and the oil recovery by heating was easier by using a solvent with lower boiling point. It was also ...

Energy Technology Data Exchange (ETDEWEB)

Studies are made on coal in terms of its effective utilization, coal cleaning, fluidization and production of new fuel, and issues globally raised. Coal is abundant in reserves and high in supply stability and economic efficiency. However, it is much in CO2 emission per calorific value. To control as much CO2 emission as possible, effective utilization such as increasing of power generation efficiency has been proceeded with. In addition to ultra supercritical pressure and fluidized bed combustion, cited are coal gasification combined cycle power generation and high temperature type fuel cell. Coal has 5-20% ash and impurities like sulfur/nitrogen. Coal should be used clean by pollution abatement measures such as dust collecting, desulfurization and denitrification. Japan is at a world top level of these technologies. Coal is solid, and ...

Energy Technology Data Exchange (ETDEWEB)

In the course of the research project 'Investigations of trace element concentrations in coal seams with different mineral groups', 31 seam coals of the Ruhr Carboniferous were analysed in order to determine the bending of 14 coal-relevant trace elements to the mineral groups and/or minerals of the coals. Products with different ash content were produced by fluctuation of the seam coals in a laboratory cell. The raw coals and fluctuation component products were analyzed chemically and mineralogically in order to get a quantitative raw material characterisation of the sampled material. Particular interest is taken in the chemical and non-ecological composition of the mineral as ash carrier in the coal and the fluctuation component products, as well as in trace element control. (orig./EF).

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An investigation was given on the relationship between methanol adsorbing behavior of reformed coal surface and oxygen containing functional groups in coal. Akabira bituminous coal was air-oxidized or Yallourn brown coal was decarbonated in oil as a reformation treatment. Both of the treated and untreated coals showed an adsorption heat curve of the Langmuir type. The Akabira coal had its oxygen content and the adsorption heat increased as a result of the air oxidizing reformation treatment. The Yallourn coal had its oxygen content and adsorption heat decreased as a result decarbonation reformation treatment. Oxygen containing functional groups act as strong adsorption sites for methanol, and the maximum adsorption amount depends on oxygen content in the coals. Since the coal surface is non-uniform ...

Science.gov (United States)

In recent years the feedstock base of the coking plants in the South has been significantly degraded: the charges contain an increased quantity of gas coal and coal from coalfields in the East are being included. Certain plants in the Ukraine receive coal from the Kuznetsk, Pechora and Karaganda coalfields. Addition of these coal types in the charges of plants in the South is expected to continue in the future. Their efficient utilization requires careful investigation of the new charges in order to determine the optimal composition and to produce blast furnace coke meeting modern specifications.

Energy Technology Data Exchange (ETDEWEB)

In order to remove ash from coal, it is introduced into an aqueous ash removal solution, which contains nitric acid or citric acid and ammonium hydrogen fluoride. The coal without ash is then separated from the aqueous solution. According to the process, either finely ground coal is introduced into the ash removel solution or the coal with the solution is ground in a wet pulveriser.

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Technical Development Document supporting proposed water discharge regulations for the Coal Mining Industry authorized by the Clean Water Act. Proposed regulations include revised best practicable technology limitations, best available technology limitations and new source performance standards for the Coal Mining Industry. Industry operations include: coal preparation and amillary operations, active mining, F bituminous, anthracite and lignite coal, and the reclamation phase of mining.

Energy Technology Data Exchange (ETDEWEB)

The presence of water in export coals increases transport and handling costs. Coarse (+0.5 mm) coal constitutes the majority of the product, and small changes in its final moisture content will have a significant effect on overall product moisture. An on-line moisture monitor was installed on a product belt immediately after a coarse coal centrifuge to continuously measure the moisture content of the coal from a single centrifuge. Basic studies were also conducted with a laboratory centrifuge specifically designed to characterize various coarse coal samples in terms of their water retention capacity. The moisture of the coarse coal (typically 6 to 9%) was found to vary by at least 1% at a particular plant, and by a number of percentage points between plants. An empirical model has been developed which can explain about 80% of the moisture variation from the 25 ...

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This document summarizes work done at the Astronautics Technology Center of the Astronautics Corporation of America (ACA) in Phase 1 of a four phase program leading to the development of a magnetic liquefier for hydrogen. The project involves the design, fabrication, installation, and operation of a hydrogen liquefier providing significantly reduced capital and operating costs, compared to present liquefiers. To achieve this goal, magnetic refrigeration, a recently developed, highly efficient refrigeration technology, will be used for the liquefaction process. Phase 1 project tasks included liquefier conceptual design and analysis, preliminary design of promising configurations, design selection, and detailed design of the selected design. Fabrication drawings and vendor specifications for the selected design were completed during detailed design. The design of a subscale, demonstration magnetic hydrogen liquefier represents a significant advance in ...

Energy Technology Data Exchange (ETDEWEB)

In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR (formerly Kellogg Brown & Root) Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results gasification operation with Illinois Basin bituminous coal in PSDF test campaign TC17. The test campaign was completed from October 25, 2004, to November 18, 2004. System startup and initial operation was accomplished with Powder River Basin (PRB) subbituminous coal, and then the system was ...

Energy Technology Data Exchange (ETDEWEB)

In the wide range from brown coal to anthracite, an investigation was made of effects of heat treatment on physical/chemical properties and of coal rank dependence. For the experiment, 12 kinds of coal samples were used, and for heat treatment, the fluidized bed heated by the electric furnace and the infrared-ray gold image furnace were used. To examine characteristics of the heat-treated coal char, conducted were oxygen gasification, TPD measurement, XRD measurement, alkali metal measurement, and pore distribution measurement. The following were obtained from the experiment. The gasification reaction rate of the char heat-treated in the temperature range between 900{degree}C to 1700{degree}C decreases with a rise of the temperature of heat treatment, and the degree of decrease in the rate depends on coal rank. The order of gasification rate between coal ranks ...

Science.gov (United States)

A method of producing blast furnace coke from bituminous coals, particularly coals having poor coking capacities in which the coal to be carbonized is ground, predried or preheated, mixed with binders, compressed or formed into briquets having small mechanical resistances and charged into oven chambers, is characterized by fine coals or fine coal mixtures having a swelling index in mixture according to DIN 51741, smaller than 7, and preferably, below 6, and comprising more than 50% of poorly or non-baking coal having a content of volatile matter in excess of 30% or less than 20% which coals or coal mixtures are ground up to attain a surface per unit mass, according to DIN 66145, of from 400 cm/sup 2/ to 1200 cm/sup 2/ per gram, with from 3% to 8% by weight of organic binders, compressing the mixture to form it into a ...

Science.gov (United States)

The production of any form of coke is determined mainly by the raw material costs. Consequently for the production of special coke, of which the demand is satisfied at the present time by small size fractions of beehive coke or even blast furnace coke, it is necessary to use not only the plentiful coals but also the brown coals of the Kansk-Achinsk coalfield where mining is being expanded. The large reserves of the Kansk-Achinsk brown coals and the favorable geological conditions for recovery by the open-cast method make it possible to increase coal extraction from 31.6.10/sup 6/ tons in 1978 to 350.10/sup 6/ tons/yr in the next 15 to 20 years. In order to explain the high reactivity of heat treated brown coals we shall compare their properties with bituminous coal coke. During the heating of bituminous coals (with a high voltatile matter ...

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A geological and geotechnical framework was provided in order to facilitate understanding of the damage to structures resulting from soil conditions during the earthquake of January 17, 1995 at Hyogo-ken Nanbu (Kobe), Japan. Special attention was paid to the large scale failures of the quay walls in the port of Kobe, resulting from liquefaction. The performance of structures in improved and unimproved ground were compared. It was observed that locations with some previous site improvements through densification behaved satisfactorily, despite unanticipated high levels of ground motion. Soil-structure interaction problems, such as pile foundations, bridge piers, lifelines, and an underground subway station were also described. Reference was made to the significance of these failures for the seismic design in the Fraser Delta in British Columbia in view of the area`s proneness to liquefaction during a major earthquake. 31 refs., 5 tabs., 45 figs.

Energy Technology Data Exchange (ETDEWEB)

Concepts involving combined gas-turbine/steam-turbine power-generation plants, in which the fuel gas for the gas turbine is produced via the gasification of coal, are now extremely advanced. This technology already permits efficiencies of around 50% current development targets view 65% as achievable. In conventional technology, efficiencies are tied to conditions, such as air and cooling-water temperatures, at the particular location. In combined-cycle power plants, the properties of the fuel coal also play an important part. There are, in face, coals which can be more advantageously used in a combined-cycle power plant than in a conventional one. These differences, combined with advantageous concepts for coal-fired combined-cycle power-generating plants, are presented and analyzed. Particular attention is devoted to individual losses occurring at coal conversion, thermodynamic ...