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Role of Na+ in transport of Hg2+ and induction of the Tn21 mer operon.

The temperature and concentration dependence of the densities of binary CaBr_2-(Li, Na, K, Rb, Cs)Br, NaBr-(Sr, Ba)Br_2 and KBr-SrBr_2 mixtures have been measured using the method of hydrostatic weighing. With exception of the systems LiBr-CaBr_2 and NaBr-(Sr, Ba)Br_2 the calculated molar excess volumes are positiv in the investigated mixtures. (author).

1980-01-01

2

Atomic masses of "6Li,"2"3Na,"3"9","4"1K,"8"5","8"7Rb, and "1"3"3Cs

The effects of sodium ions on the uptake of Hg2+ and induction of the Tn21 mer operon were studied by using Escherichia coli HMS174 harboring the reporter plasmids pRB28 and pOS14. Plasmid pRB28 carries...Full Text Available

1994-10-01

3

Utilization of fermentation waste (Corynebacterium glutamicum) for biosorption of Reactive Black 5 from aqueous solution

The atomic masses of the alkali-metal isotopes "6Li,"2"3Na,"3"9","4"1K,"8"5","8"7Rb, and "1"3"3Cs have been obtained from measurements of cyclotron frequency ratios of pairs of ions simultaneously trapped in a Penning trap. The results, with one standard deviation uncertainty, are: M("6Li)=6.015 122 887 4(16)u,M("2"3Na)=22.989769 282 8(26)u,M("3"9K)=38.963 706 485 6(52)u,M("4"1K)=40.961 825 257 4(48)u,M("8"5Rb)=84.911 789739(9)u,M("8"7Rb)=86.909 180 535(10)u, and M("1"3"3Cs)=132.905 451 963(13)u. Our mass of "6Li yields an improved neutron separation energy for "7Li of 7251.1014(45) keV.

2010-10-01

4

The saturation vapour pressure and decomposition potential of ThCl_4 solutions in molten alkali chlorides

A fermentation waste, Corynebacterium glutamicum, was successfully employed as a biosorbent for Reactive Black 5 (RB5) from aqueous solution. This paper initially studied the effect of pretreatment on the biosorption capacity of C. glutamicum toward RB5, using several chemical agents, such as HCl, H{sub 2}SO{sub 4}, HNO{sub 3}, NaOH, Na{sub 2}CO{sub 3}, CaCl{sub 2} and NaCl. Among these reagents, 0.1 M HNO{sub 3} gave the maximum enhancement of the RB5 uptake, exhibiting 195 mg/g at pH 1 with an initial RB5 concentration of 500 mg/l. The solution pH and temperature were found to affect the biosorption capacity, and the biosorption isotherms derived at different pHs and temperatures revealed that a low pH (pH 1) and high temperature (35 deg. C) favored biosorption. The biosorption isotherm was well represented using three-parameter models ...

2007-03-06

5

Technique for generating atomic negative ion beams of the group IA elements

The partial pressures of the components (ThCl_4, MCl and MThCl_5) in the saturated vapours of ThCl_4 solutions in molten LiCl, NaCl, KCl, RbCl and CsCl are determined as a function of temperature (900 to 1200 K) and ThCl_4 concentration (2 to 50 mol% ThCl_4) by dynamic method. Thorium tetrachloride volatility is shown to exceed that of alkali chloride from the melts containing less than 98 LiCl or NaCl, 83 KCl, 67 RbCl and 48 mol% CsCl. From experimental observations the decomposition potential of the electrolytes under investigation was estimated in temperature and concentration ranges of our measurements. Under otherwise equal conditions, it increases in the series of alkali chlorides from LiCl to CsCl. (author).

1984-01-01

6

Alteration of alpha 1 Na+,K(+)-ATPase "8"6Rb"+ influx by a single amino acid substitution

A technique has been developed which enables the direct sputter generation of atomic negative ion beams of all members of the Group IA elements (Li, Na, K, Rb and Cs). The method is based on the use of sputter samples formed by pressing mixtures of the carbonates of the Group IA elements and 10% (atomic) Cu, Ag or other metal powders. The following intensities are typical of those observed from carbonate samples subjected to approx. = 3 keV cesium ion bombardment: Li/sup -/: greater than or equal to 0.5 ..mu..A; Na/sup -/: greater than or equal to 0.5 ..mu..A; K/sup -/: greater than or equal to 0.5 ..mu..A; Rb/sup -/: greater than or equal to 0.5 ..mu..A; Cs/sup -/: greater than or equal to 0.2 ..mu..A.

1989-03-15

7

Synthesis of new ternary alkali metal GICs at high pressures

The sodium- and potassium-dependent adenosine triphosphatase (Na+,K(+)-ATPase) maintains the transmembrane Na+ gradient to which is coupled all active cellular transport systems. The R and S alleles of the gene encoding the Na+,K(+)-ATPase alpha 1 subunit isoform were identified in Dahl salt-resistant (DR) and Dahl salt-sensitive (DS) rats, respectively. Characterization of the S allele-specific Na+,K(+)-ATPase alpha 1 complementary DNA identified a leucine substitution of glutamine at position 276. This mutation alters the hydropathy profile of a region in proximity to T3(Na), the trypsin-sensitive site that is only detected in the presence of Na+. This mutation causes a decrease in the rubidium-86 influx of S allele-specific sodium pumps, thus marking a domain in the Na+,K(+)-ATPase alpha subunit important for K+ transport, and supporting ...

8

Trace Elements in Human Myocardial Infarction Determined by Neutron Activation Analysis

Graphite intercalation compounds, Rb{sub x}KC{sub 8}, Cs{sub x}KC{sub 8} and Na{sub x}KC{sub 8}, x{approx equal}1-1.3, are obtained under pressures up to 80 kbar using KC{sub 8} as the initial compound. Total contents of alkali metals in these compounds correspond to the formula MC{sub 3.5-4.0}. (orig.).

1992-07-01

9

Saturation vapour pressure and decomposition potential of ThCl/sub 4/ solutions in molten alkali chlorides

By means of neutron activation analysis, injured and adjacent uninjured human heart tissue from 12 autopsy cases with myocardial infarction are investigated with respect to the concentration of 23 trace elements. The bulk elements K, Na and P are also determined. A recently developed ion-exchange technique, combined with subsequent y-spectrometry, is used. The following trace elements are determined: Ag, As, Au, Ba, Br, Ca, Cd, Ce, Co, Cr, Cs, Cu, Fe, Hg, La, Mo, Rb, Sb, Sc, Se, Sm, Zn and W. In the injured tissue compared to the uninjured, calculation on a wet weight basis showed a decrease in Co, Cs, K, Mo, P, Rb and Zn, and an increase in Br, Ca, Ce, La, Na, Sb and Sm. The differences in Ca, La, Mo, P and Zn are dependent on the age of the myocardial infarction, and the regression lines for these elements are given. The concentration of the trace elements in uninjured tissue from infarcted hearts is ...

1965-01-01

10

Production of atomic negative ion beams of the Group IA elements

The partial pressures of the components (ThCl/sub 4/, MCl and MThCl/sub 5/) in the saturated vapours of ThCl/sub 4/ solutions in molten LiCl, NaCl, KCl, RbCl and CsCl are determined as a function of temperature (900 to 1200 K) and ThCl/sub 4/ concentration (2 to 50 mol% ThCl/sub 4/) by dynamic method. Thorium tetrachloride volatility is shown to exceed that of alkali chloride from the melts containing less than 98 LiCl or NaCl, 83 KCl, 67 RbCl and 48 mol% CsCl. From experimental observations the decomposition potential of the electrolytes under investigation was estimated in temperature and concentration ranges of our measurements. Under otherwise equal conditions, it increases in the series of alkali chlorides from LiCl to CsCl.

1984-01-01

11

Experimental determination of the thermal diffusivity of molten alkali halides by the forced Rayleigh scattering method. I. Molten LiCl, NaCl, KCl, RbCl, and CsCl

A method has been developed which enables the direct sputter generation of atomic negative ion beams of all members of the Group IA elements (Li, Na, K, Rb, and Cs). The method consists of the use of sputter samples formed by pressing mixtures of the carbonates of the Group IA elements and 10% (atomic) Cu, Ag, or other metal powder. The following intensities are typical of those observed from carbonate samples subjected to /approximately/3 KeV cesium ion bombardment: Li/sup -/: greater than or equal to0.5 ..mu..A; Na/sup -/: greater than or equal to0.5 ..mu..A; K/sup -/: greater than or equal to0.5 ..mu..A; Rb/sup -/: greater than or equal to0.5 ..mu..A; Cs/sup -/: greater than or equal to0.2 ..mu..A. 7 refs., 2 figs., 1 tab.

1988-01-01

12

Proton-loaded zeolites. 2. Dehydrohalogenation versus decationization kinetics: Cation and acidity effects

As a series of experimental determinations of the thermal diffusivity of molten alkali halides, this paper describes measurements on five molten alkali metal chlorides (LiCl, NaCl, KCl, RbCl, and CsCl) in the temperature range up to 1440 K by the forced Rayleigh scattering method. K[sub 2]Cr[sub 2]O[sub 7] is employed as a dye substance to color the transparent molten salts. In comparison with the present results converted into thermal conductivity, most of the previous experimental data obtained by steady-state methods show larger values, up to about five times, which may be due to the systematic error caused by the presence of convection and radiation. It is found that the thermal conductivity of these series of molten alkali metal chlorides decreases with increasing molecular weight, and their temperature coefficients are weakly negative. 24 refs., 9 figs., 6 tabs.

1992-07-01

13

Cell volume regulation in hemoglobin CC and AA erythrocytes

The work presented in part 1 of this study established that the sorption of anhydrous HX into dehydrated Na{sub 56}Y progresses through a sequence of steps involving HX ionization and charge separation, oxygen framework protonation, formation of {alpha}-cage confined cation-anion contact ion pairs, and proton solvation by HX. A logical extension, which is the subjected of this study, concerns the effect of extraframework alkali metal cation type (M = Li{sup +}, Na{sup +}, K{sup +}, Rb{sup +}, Cs{sup +}) on the sorption process. The question of the acidity of proton-loaded zeolites compared to Broensted acid zeolites is addressed by using probe reactions with weak bases like ethane and cyclopropane. Additional insight into these systems is also obtained from a quantitative comparison of the kinetic and thermodynamic activation parameters for the dehydrohalogenation of proton-loaded zeolites exemplified by (HX){sub ...

1990-10-18

14

Determination of a various ions such as alkali metals in leaves, stems, roots and seeds of the radish and their distribution

Swelling hemoglobin CC erythrocytes stimulates a ouabain-insensitive K flux that restores original cell volume. Studies were performed with the K analog, "8"6Rb. This volume regulatory pathway was characterized for its anion dependence, sensitivity to loop diuretics, and requirement for Na. The swelling-induced K flux was eliminated if intracellular chloride was replaced by nitrate and both swelling-activated K influx and efflux were partially inhibited by 1 mM furosemide or bumetanide. K influx in swollen hemoglobin CC cells was not diminished when Na in the incubation medium was replaced with choline, indicating Na independence of the swelling-induced flux. Identical experiments with hemoglobin AA cells also demonstrated a swelling-induced increase in K flux, but the magnitude and duration of this increase were considerably less than that seen with hemoglobin CC cells. The increased K flux in ...

15

E2f binding-deficient Rb1 protein suppresses prostate tumor progression in vivo

Determination, uptake and distribution of various ions such as alkali metals in three different parts (leaf, stem and root) and seeds of radish (Kaiware daikon) were examined using flame emission spectrometry and ICP-AES. In order to examine the influence of concentration alkali metal ion concentration in the radish culture solution on the uptake and distribution of these metals, the radish was grown at pH 5.6 in solutions containing alkali metal chloride at concentrations ranging from 10{sup -5} to 10{sup -1} mol dm{sup -3}. When the radish were grown in culture solution with alkali metal ions of low concentrations (10{sup -5} and 10{sup -4} mol dm{sup -3}), Na, K, Rb and trace Li were detected in leaves, stems and roots while Cs was scarcely detected. However, the contents of Na, K, Li in these organs were the same as those in radish cultivated in pure water. An increase of Rb uptake was observed with ...

1995-05-01

16

Measurement of induced radioactivity in materials found around a neutron generator

Mutational inactivation of the RB1 tumor suppressor gene initiates retinoblastoma and other human cancers. RB1 protein (pRb) restrains cell proliferation by binding...Full Text Available

2011-01-11

17

The induced radioactivity in the construction materials of a Cockcroft-- Walton type neutron generator was measured. Major activation products (/sup 24/ Na, /sup 28/Al, /sup 56/Mn, /sup 64/Cu, /sup 65/Ni, /sup 69m/Zn, /sup 88/Rb /sup 91/Sr /sup 101/Mo, /sup 187/W/ and resulting doses are tabulated. Results show that the highest gamma activities would be observed in the fluorescent bulbs, copper pipe, aluminum lattice rod, and the aluminum pipe clamp. Thermoluminescent dosimeter readings yield the highest doses for the copper pipe tee, copper pipe, and aluminum lattice rod. Results of measuremerts of the neutron and gamma dose profiles of the facility are shown. However the indication is clearly that the tritium target, compared to other components, is the major source of radiation both during and after shutdown. (UK)

1974-01-01

18

Frequency mixing crystal

First principle calculations of alkali hydride electronic structures

In a laser system for converting infrared laser light waves to visible light comprising a source of infrared laser light waves and means of harmoic generation associated therewith for production of light waves at integral multiples of the frequency of the original wave, the improvement of said means of harmonic generation comprising a crystal having the chemical formula X.sub.2 Y(NO.sub.3).sub.5 .multidot.2 nZ.sub.2 o wherein X is selected from the group consisting of Li, Na, K, Rb, Cs, and Tl; Y is selected from the group consisting of Sc, Y, La, Ce, Nd, Pr, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Al, Ga, and In; Z is selected from the group consisting of H and D; and n ranges from 0 to 4.

1992-01-01

19

Estimation of essential and trace elements in some medicinal plants by PIXE and PIGE techniques

Electronic structure, volume optimization, bulk moduli, elastic constants, and frequencies of the transversal optical vibrations in LiH, NaH, KH, RbH, and CsH are calculated using the full potential augmented plane wave method, extended with local orbitals, and the full potential linearized augmented plane wave method. The obtained results show some common features in the electronic structure of these compounds, but also clear differences, which cannot be explained using simple empirical trends. The differences are particularly prominent in the electronic distributions and interactions in various crystallographic planes. In the light of these findings we have elaborated some selected experimental results and discussed several theoretical approaches frequently used for the description of various alkali hydride properties.

2007-10-10

20

Determination of macro, micro nutrient and trace element concentrations in Indian medicinal and vegetable leaves using instrumental neutron activation analysis

Proton induced X-ray emission (PIXE) and proton induced {gamma}-ray emission (PIGE) techniques are employed for the determination of essential and trace elements in some commonly used medicinal plants of north east India. Light elements such as Na, Mg, Al and P are determined by PIGE while medium Z elements such as K, Ca, Mn, Fe, Cu, Zn, Rb and Sr are determined by PIXE. Analysis is performed on pellets (thick targets) prepared using powders of the specimens which, in turn, are obtained following a series of processing steps. Plant based biological certified reference materials (CRMs) served as standards for quantification. These elements are found to be present in varying concentrations in the studied plants, with the contents of Mn and Zn being notably large in certain specimens. Medicinal properties possessed by these plants have been correlated with their elemental distribution.

2008-04-15

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Availability of essential trace elements in Ayurvedic Indian medicinal herbs using instrumental neutron activation analysis

Leafy samples often used as medicine in the Indian Ayurvedic system and vegetables were analyzed for 20 elements (As, Ba, Br, Ca, Ce, Cr, Cs, Co, Eu, Fe, K, La, Na, Rb, Sb, Sc, Sm, Sr, Th, Zn) by employing Instrumental Neutron Activation Analysis (INAA). The samples were irradiated at the 100 kW TRIGA-MAINZ nuclear reactor and the induced activities were counted by gamma ray spectrometry using an efficiency calibrated high resolution High Purity Germanium (HPGe) detector. The concentration of the elements in the medicinal and vegetable leaves and their biological effects on human beings are discussed.

1999-05-01

22

A PIXE/PIGE study of gold mineralisation in lateritic terrain, Tanami Desert, Australia

Specific parts of several plants (fruits, leaves, stem, bark and roots) often used as medicines in the Indian Ayurvedic system have been analysed for 20 elements (As, Ba, Br, Ca, Cl, Co, Cr, Cu, Fe, K, Mn, Mo, Na, P, Rb, Sb, Sc, Se, Sr and Zn) by employing instrumental neutron activation analysis (INAA). The samples were irradiated with thermal neutrons in a nuclear reactor and the induced activity was counted using high resolution gamma ray spectrometry. Most of the medicinal herbs have been found to be rich in one or more of the elements under study. (Author).

1997-01-01

23

NMR study of one-dimensional ionic conductor with hollandite-type structure (IV) Rb-priderite

Proton induced X-ray and {gamma}-ray emission (PIXE/PIGE) have been used to analyze major and trace elements in a suite of 140 core samples from around of the Jim`s Find South gold anomaly in the Tanami desert, located in heavily weathered terrain. Simultaneous analyses were obtained for 30 elements, ranging in atomic number from {sup 3}Li to {sup 90}Th. The method was chosen because of its speed and the wide range of determination, its flexibility, precision and low detection limits. The regolith powder samples were treated by hot aqua regia before making them into pills. The PIXE/PIGE data of the acid insoluble residue give three factor analysis clusters. The first cluster comprises the elements F, Al, K, V, Mn, Fe, Ga, Rb, W and Au and is essentially related to sericitic wallrock alteration. The second cluster consists of Ti, As, Y, Zr, and Nb and is largely related to resistant minerals. The third cluster consists of Na, Ca and Sr and is ...

1997-12-31

24

Inorganic profile of some Brazilian medicinal plants obtained from ethanolic extract and ''in natura'' samples

Conduction properties of Rb"+ ion in Rb-Al-priderite and K"+ ion and Rb"+ ion in (K,Rb)-Al-priderite, were investigated by NMR using "2"7Al in the framework as a probe. Size effect was observed remarkably in the activation energies. Frequency dependence of T_1 in Rb-Al-priderite at a low temperature indicates that the relaxation behavior of "2"7Al in Rb-Al-priderite can be described by the continuum model. Barrier height distributions and 'attempt frequencies' in both samples obtained by a curve-fitting method are discussed in comparison with those of K-Al-priderite. (orig.).

1985-08-18

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Formation of double hafnium sulfates in the systems HfO"2-H"2SO"4-Me"2SO"4-H"2O (Me-Na, K, Rb, Cs and NH"4)

The Anadenathera macrocarpa, Schinus molle, Hymenaea courbaril, Cariniana legalis, Solidago microglossa and Stryphnodendron barbatiman, were collected ''in natura'' samples (leaves, flowers, barks and seeds) from different commercial suppliers. The pharmaco-active compounds in ethanolic extracts had been made by the Mato Grosso Federal University (UFMT). The energy-dispersive x-ray fluorescence (ED-XRF) spectrometry was used for the elemental analysis in different parts of the plants and respective ethanolic extracts. The Ca, Cl, Cu, Fe, K, Mg, Mn, Na, Ni, P, Rb, S, Sr and Zn concentrations were determined by the fundamental parameters method. Some specimens showed a similar inorganic profile for ''in natura'' and ethanolic extract samples and some ones showed a distinct inorganic profile. For example, the Anadenathera macrocarpa showed a similar concentration in Mg, P, Cu, ...

2004-10-03

26

Application of neutron activation analysis method in leaves of Casearia obliqua medicinal plant; Aplicacao do metodo de analise por ativacao com neutrons na analise de folhas da planta medicinal Casearia obliqua

Influence of alkali elements on formation, composition, solubility and region of stability of complex hafnium sulfates, separated in the HfO"2-H"2SO"4-Me"2SO"4-H"2O (Me-Na, K, Rb, Cs and NH"4 group) systems is studied. In all cases hafnium forms the complex sulfates of three types differing by basicity or ratio HfO"2:SO"3 1:1, 1:1.5, 1:2. Three basic and three medium sulfates are crystallized in the systems with sodium; with rubidium, cesium and ammonium - two basic and two medium sulfates and with potassium - two basic and one medium salts. Anhydrous salts do not form in the investigated systems. Potassium salt approximately 0.3% according to HfO"2 is characterized by minimum solubility from the salts of 2HfOSO"4x(1-3)Me"2SO"4x(4-6)xH"2O while solubility of the same salts with rubidium, cesium and sodium increases from (0.25-1.0); (0.5-1.5) till (1.0-5)% according to HfO"2 correspondingly.

1982-01-01

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Influence of the Atmosphere on a Rubidium Clock's Frequency ...

The pharmacological properties of medicinal plants have been related to the presence of organic compounds, however elements are also known to have an important participation in the active compounds constitution process. In this study, instrumental neutron activation analysis (INAA) was applied to determine elements in leaves of Casearia obliqua medicinal plant collected at two different locations in the Atlantic Forest, Brazil, SP. Soil samples collected from where this plant was grown were also analyzed in order to verify if there is a correlation between the elements present in soils and plant leaves. Br, Ca, Cl, Co, Cr, Cs, Fe, K, La, Mn, Na, Rb, Sb, Sc and Zn were determined in C. obliqua leaves and the elements As, Ca, Ce, Eu, Fe, Hf, La, Lu, Nd, Rb, Sc, Sm, Tb, Th, U and Zn in soils. Soil samples collected from two different locations presented similar concentrations for most elements. Likewise, C. obliqua leaves ...

2005-07-01

28

Upgrading low molecular weight hydrocarbons

... Figure 3 shows on-orbit (ie, vacuum) frequency aging rates for Milstar rubidium (Rb) clocks, GPS Block IIR Rb clocks, and GPS Block IIA Rb clocks. ...

2007-11-01

29

Ternary oxide nanostructures and methods of making same

This patent describes a process for the conversion of low molecular weight alkanes to higher molecular weight hydrocarbons. It comprises: contacting the low molecular weight alkanes, at an elevated temperature, with oxygen and a catalyst of the formula Zn{sub a}A{sub b}M{sub c}M'{sub d}O{sub x} wherein A is Li, Na, K, or mixtures thereof; M is Al, Ga, Cr, La, Y, Sc, V, Nb, Ta, Cu or mixtures thereof; M' is Cs, Rb, Mg, Ca, Sr, Ba, Sm, Pb, Mn, Sb, P, Sn, Bi, Ti, Zr, Hf, or mixtures thereof; a if from about 1 to about 20; b is from about 0.1 to about 20; c is from about 0 to about 5 d is from about 0 to about 20, and x is a number needed to fulfill the valence requirements of the other elements; provided that at least one c and d is a t least 0.1; and when M' is Sn, c must be at least 0.1.

1989-12-12

30

Solid electrolyte and lithium battery employing it. Kotai denkaishitsu oyobi sore wo shiyo shite naru richiumu denchi

A single crystalline ternary nanostructure having the formula A.sub.xB.sub.yO.sub.z, wherein x ranges from 0.25 to 24, and y ranges from 1.5 to 40, and wherein A and B are independently selected from the group consisting of Ag, Al, As, Au, B, Ba, Br, Ca, Cd, Ce, Cl, Cm, Co, Cr, Cs, Cu, Dy, Er, Eu, F, Fe, Ga, Gd, Ge, Hf, Ho, I, In, Ir, K, La, Li, Lu, Mg, Mn, Mo, Na, Nb, Nd, Ni, Os, P, Pb, Pd, Pr, Pt, Rb, Re, Rh, Ru, S, Sb, Sc, Se, Si, Sm, Sn, Sr, Ta, Tb, Tc, Te, Ti, Tl, Tm, U, V, W, Y, Yb, and Zn, wherein the nanostructure is at least 95% free of defects and/or dislocations.

2009-09-08

31

Secondary reactions during CO hydrogenation on zeolite-supported metal catalysts: influence of alkali cations

Recently, the lithium ion-conductive solid electrolyte draws attention because there is a possibility of producing the maintenance-free battery which is characterized by having such advantages as high energy density and no possibility of electrolyte leak because of solid state structure. The invented lithium ion-conductive solid electrolyte is formed by sintering the granular electrolyte expressed in the following general formula: Li(1+(4-n)x)MxTi(2-x)(PO4)3 (M = mono- or di-valent cation, x = 0.1 - 0.5). Examples of the monovalent cation are Na[sup +], K[sup +], Rb[sup +], Cs[sup +], and Cu[sup +]. Examples of divalent cation are Mg[sup 2+], Fe[sup 2+], Be[sup 2+], Ca[sup 2+], Sr[sup 2+], Ba[sup 2+], Ra[sup 2+], Mn[sup 2+], Co[sup 2+], Cu[sup 2+], Ni[sup 2+], Zn[sup 2+], and Cd[sup 2+]. The electric conductivity of lithium ion is increased with the increase in the content of Li[sup +] in the electrolyte. 4 figs.

1993-11-12

32

Analysis of medicinal plant extracts by neutron activation method; Analise de extratos de plantas medicinais pelo metodo de ativacao com neutrons

The effect of neutralizing cations on the secondary reactions of the primary products from CO hydrogenation over ion-exchanged zeolite-supported Ru catalysts was investigated using zeolites with different alkali cations (Li/sup +/, Na/sup +/, K/sup +/, Rb/sup +/, Cs/sup +/). The transformation of olefins (propylene and butene) on the zeolites without the metal, under conditions similar to those used for CO hydrogenation, was also studied in order to understand the effect of the various constituents of the support, i.e., the Broensted acid sites generated during catalyst preparation and the alkali cations, on possible secondary reactions of the primary olefinic products. It was established that secondary acid-catalyzed reactions of these primary products can play a major role in shaping product selectivity during CO hydrogenation over zeolite-supported catalysts. Depending on the concentration and the strength of the acid sites, various ...

1987-10-01

33

Study of Nitrate Stress in Desulfovibrio vulgaris Hildenborough Using iTRAQ Proteomics

This dissertation has presented the results from analysis of medicinal plant extracts using neutron activation method. Instrumental neutron activation analysis was applied to the determination of the elements Al, Br, Ca, Ce, Cl, Cr, Cs, Fe, K, La, Mg, Mn, Na, Rb, Sb, Sc and Zn in medicinal extracts obtained from Achyrolcline satureoides DC, Casearia sylvestris, Centella asiatica, Citrus aurantium L., Solano lycocarpum, Solidago microglossa, Stryphnondedron barbatiman and Zingiber officinale R. plants. The elements Hg and Se were determined using radiochemical separation by means of retention of Se in HMD inorganic exchanger and solvent extraction of Hg by bismuth diethyl-dithiocarbamate solution. Precision and accuracy of the results have been evaluated by analysing reference materials. The therapeutic action of some elements found in plant extracts analyzed was briefly discussed 70 refs., 13 figs., 15 tabs

1995-12-31

34

Thermoluminescence of irradiated RbCl and RbCl:Sn crystals

The response of Desulfovibrio vulgaris Hildenborough (DvH),a sulphate-reducing bacterium, to nitrate stress was examined usingquantitative proteomic analysis. DvH was stressed with 105 m M sodiumnitrate(NaNO3), a level that caused a 50 percent inhibition in growth.The protein profile of stressed cells was compared with that of cellsgrown in the absence of nitrate using the iTRAQ peptide labellingstrategy and tandem liquid chromatography separation coupled with massspectrometry (quadrupoletime-of-flight) detection. A total of 737 uniqueproteins were identified by two or more peptides, representing 22 percentof the total DvH proteome and spanning every functional category. Theresults indicate that this was a mild stress, as proteins involved incentral metabolism and the sulphate reduction pathway were unperturbed.Proteins involved in the nitrate reduction pathway increased. Increasesseen in transport systems for proline, glycine^ betaineandglutamateindicate that the ...

2006-10-12

35

Production of "8"3Rb and development of a generator for the separation of sup(83m)Kr from "8"3Rb

The thermoluminescence (TL) and emission of coloured RbCl and RbCl:Sn crystals are studied in the temperature range 300 to 560 K. The glow peaks responsible for F centres and tin centres in different valence states are identified using optical bleaching studies. The glow peaks are analysed using total curve fitting method and the kinetic parameters are determined. In moderately #gamma#-irradiated tin-doped RbCl crystals, the TL emission bands observed at 4.0, 3.6, and 2.2 eV are attributed to Sn"0, Sn"+, and Sn"- centers, respectively. A comprehensive energy level diagram depicting the various TL processes in these undoped and tin-doped RbCl crystals is proposed. (author).

36

Monitoring digoxin therapy: I. Plasma concentrations and an in vitro assay of tissue response.

"8"3Rb was produced from rubidium by a (#gamma#,2n)-reaction. The specific activity in the irradiated samples of RbCl was 0.2 to 0.3mCi"8"3Rb/gRb. For the separation of the sup(83m)Kr in the liquid phase the cation exchanger Dowex-50WX12 proved to be a suitable carrier. sup(83m)Kr was eluted by bidistilled water. The yield ranged from 85-95%, at an elution time of 3 minutes. The decontamination factor was > 10"6. The separation of sup(83m)Kr in the gaseous phase was effected by floating a "8"3Rb loaded column with an elution gas. The best results were obtained with a generator containing aluminium oxide as carrier for "8"3Rb. The yield of sup(83m)Kr was 90-100%, the decontamination factor > 10"4, the time needed for the separation 20-60 seconds. All generators proved to be very safe even after long time of use. (orig.).

37

Functional Interactions between Retinoblastoma and c-MYC in a Mouse Model of Hepatocellular Carcinoma

1 An in vitro technique is described for measuring the uptake of 86Rb by human erythrocytes. 2 Fifteen patients were treated with digoxin for atrial fibrillation and other fast arrhythmias. 3 86Rb uptake...Full Text Available

1977-04-01

38

Decays of "8"8Kr and "8"8Rb

Inactivation of the RB tumor suppressor and activation of the MYC family of oncogenes are frequent events in a large spectrum of human cancers. Loss of RB function and MYC activation are thought to...Full Text Available

39

Decays of "8"8Kr and "8"8Rb

... isotopes minutes living radioisotopes nuclei odd-odd nuclei particle properties

40

Element distribution in the brain sections of rats measured by synchrotron radiation X-ray fluorescence

The #gamma# rays following the #beta# decays of "8"8Kr and "8"8Rb have been studied, using both large volume Ge(Li) detectors for singles and coincidence measurements and anti-Compton spectrometry for singles measurements. Level schemes for "8"8Rb and "8"8Sr were constructed from the data and 74 of 81 #gamma# rays observed in the decay of "8"8Kr were placed in the "8"8Rb level scheme with 23 excited states. For the decay of "8"8Rb, all of the observed 27 #gamma# rays have been placed in the (well known) level structure of "8"8Sr. Spin and parity assignments have been deduced from #beta#-decay logft values and #gamma#-ray transition patterns. Possible shell model interpretations are presented for the level schemes.

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41

ZZ DECAYREM/C, Decay Spectra Library for EXREM Calculation

The concentration of trace elements in brain sections was measured by synchrotron radiation X-ray fluorescence. The relative concentration was calculated by means of the normalization of Compton scattering intensity approximately 22 keV, after the normalization for collecting time of X-ray spectrum and the counting of the ion chamber, and subtracting the contribution of the polycarbonate film for supporting sample. Furthermore, the statistical evaluation of the element distribution in various regions of the brain sections of the 20-day-old rats was tested. For investigating the distribution of elements in the brain of iodine deficient rats, Wistar rats were fed with iodine deficient diet and deionized water (ID group). The rats were fed the same iodine deficient diet, but drank KIO_3 solution as control (CT group). The results showed that the contents of calcium (Ca) in thalamus (TH) and copper (Cu) and iron (Fe) in cerebral cortex (CX) of ID rats were significantly lower than that of ...

2004-02-27

42

Real time neutron diffraction study on the intercalation of deuterobenzene into RbC/sub 24/

Description of problem or function: Format: EXREM III; Nuclides: radioactive decay data on 252 Nuclides: 1H-3, 4Be-7, 6C-11, 6C-14, 7N-13, 8O-15, 9F-18, 11Na-22, 11Na-24, 12Mg-28, 13Al-28, 15P-32, 15P-33, 16S-35, 17Cl-36, 17Cl-38, 18A-37, 18A-39, 19K-40, 19K-42, 19K-43, 20Ca-45, 20Ca-47, 20Ca-49, 21Sc-46, 21Sc-47, 21Sc-49, 24Cr-51, 25Mn-52M, 25Mn-52, 25Mn-54, 26Fe-52, 26Fe-55, 26Fe-59, 27Co-56, 27Co-57, 27Co-58, 27Co-60, 28Ni-56, 28Ni-63, 29Cu-64, 30Zn-65, 30Zn-69M, 30Zn-69, 31Ga-67, 31Ga-68, 32Ge-77, 33As-76, 33As-77, 34Se-75, 35Br-80M, 35Br-80, 35Br-82, 35Br-83, 35Br-84, 36Kr-79, 36Kr-83M, 36Kr-85M, 36Kr-85, 36Kr-87, 36Kr-88, 37Rb-84, 37Rb-86, 37Rb-87, 37Rb-88, 37Rb-89, 37Rb-90M, 37Rb-90, 38Sr-85, 38Sr-87M, 38Sr-89, 38Sr-90, 38Sr-91, 38Sr-92, 38Sr-93, 39Y-87, 39Y-88, 39Y-90, 39Y-91M, 39Y-91, ...

43

ylx5271.PDF

Wastenet

citrate boric acid citrate acid-NaOH

44

A real time neutron diffraction study on the intercalation of deuterobenzene into RbC_2_4

The reaction of RbC/sub 24/ with C/sub 6/D/sub 6/ vapour was studied by neutron diffraction on a time scale of 5 min/spectrum. As for the reaction of KC/sub 24/, a second stage phase RbC/sub 24/(C/sub 6/D/sub 6/)sub(y) is initially formed and subsequently transformed into a first stage phase. Model calculations indicate that the benzene rings are canted against the graphite planes both in the first and in the second stage phase.

1983-11-01

45

Job Performance Measurement in the Military: A Classification ...

The reaction of RbC_2_4 with C_6D_6 vapour was studied by neutron diffraction on a time scale of 5 min/spectrum. As for the reaction of KC_2_4, a second stage phase RbC_2_4(C_6D_6)sub(y) is initially formed and subsequently transformed into a first stage phase. Model calculations indicate that the benzene rings are canted against the graphite planes both in the first and in the second stage phase. (Auth.).

1983-01-01

46

Correlation between deoxyribonucleic acid excision-repair and life-span in a number of mammalian species

... AUTHOR(S) Kavanagh, MJ; Borman, WC,; Hedge, JW; Gould, RB i3a. ... 3.5 Performance Standards, Scale Characteristics, and Scale Development ...

1987-09-01

47

UNCERTAINTY IN THE ESTIMATE OF POSITION AND ...

(Jun 1974). United States Hart, RW Setlow, RB Oak Ridge National Lab.,

48

Synthesis, crystal structure and nonlinear optical property of Rb3V5O14

... matrices were written in the form R(t) = R'(t) Mpp T V(t) = V (t) MppT (C-3) 49 Page 59. ... GW~/EE/64.-9 where ra(!L) rb(L) 0 MPPT= (C-4) [rb(L) ra(L) 0 ...

1964-06-01

49

Determination of the cross section for the fission neutron reaction "8"8Sr(n,p)"8"8Rb

The new nonlinear optical crystal Rb3V5O14 has been synthesized by solid state reaction and characterized by single-crystal X-ray diffraction, IR and thermogravimetric analysis. The crystal Rb3V5O14 crystallizes in the trigonal system with space P31m (No. 157), a=b=8.7134(12) A, c=5.2807(11) A and ?=90o, ?=90o, ?=120o, Z=1, ?=3.516 g/cm3. It is a layered structure that is very flat and strongly parallel to c. The V5O14 layer structure consists of corner-linked square and triangular pyramids. The layers are separated by Rb+ ions, which fit equally well on the V5O14 layer. The Kurtz powder SHG measurement, using 1064 nm radiation, showed that the second-harmonic generation efficiency of Rb3V5O14 is about two times that of KDP. -- Graphical abstract: The new nonlinear optical crystal Rb3V5O14 has been synthesized by solid state reaction and characterized by single-crystal X-ray ...

2010-12-01

50

A case of noble gas leakage searching and analysis in Daya Bay NPP

The cross section for the reaction "8"8Sr(n,p)"8"8Rb was found to be (0.0155 +- 0.0017) mb. This value corresponds well with those calculated by Roy, Hawton, Calamand, and Nasyrov. (author).

51

Study of the inorganic constituents in different species of Casearia medicinal plant collected in distinct regions of the Atlantic Forest, SP State, Brazil; Estudo sobre os constituintes inorganicos presentes em diferentes especies da planta medicinal do genero Casearia coletadas em regioes distintas da Mata Atlantica, SP

The author reports briefly a noble gas leakage searching process in which a person was contaminated in Daya Bay NPP, the radionuclide causing contamination was ascertained as the daughter product of "8"8Kr, the "8"8Rb; By taking air contamination sampling and measuring the "8"8Rb concentration in the room, the leakage source was predetermined and the leakage rate of primary coolant was estimated

1999-09-01

52

Luminescent unit computerization to research spectral characteristics of fine film alkali halide crystal

The use of medicinal plants in the treatment of diseases has increased significantly in the last years, as has research concerning chemical characterization of these plants. In this study, inorganic constituents were determined in leaves and in extracts from three medicinal plant species of the Casearia genus (C. sylvestris, C. decandra and C. obliqua) collected in distinct regions of the Atlantic Forest, SP. The elemental compositions of the soils in which these plants were grown were also determined. Traditionally, these plants are used due to their antiinflammatory, antiacid, antiseptic and cicatrizing properties. The antiulcer and the antitumor activities of the Casearia genus and its capacity to neutralize snake and bee venoms, have also been scientifically confirmed. The analytical methodology used was neutron activation analysis. Long and short irradiation periods of the samples and the standards were carried out at IPEN's IEA-R1 nuclear research reactor. In the leaf K ...

2006-07-01

53

A single amino acid substitution results in a retinoblastoma protein defective in phosphorylation and oncoprotein binding

The fundamental optical absorption of ion crystals characterizes the creation of different free low energetic electronic excitation (the excitons and electron-hole pairs), but their straight registration is not possible because of incommensurable big absorption factor of alkali halide monocrystals. So to registration the spectrums of alkali halide monocrystal very fine layers are necessary. We have received fine films of Nal and KCl in system of KCl-Nal-KCl, KCl-KI-KCl on the base of universal vacuum post VUP-4, VUP-5 by thermal evaporation. A unique spectral unit has been created For this on the basic the SDL-2 complex. Complex consists of radiator, systems of condensers, monochromators MDR-12 and MDR-23, receivers of radiation, controller by unit. Connect and control of monochromators by means of IBM-compatible computer has been created. Kinematics schemes of monochromators provide consequent removing on output slot of monochromatic radiation in operating range of each diffraction ...

54

Regulation of Na(+)-K+ pump activity in contracting rat muscle.

The authors have previously identified a small-cell lung cancer cell line (NCI-H209) that expresses an aberrant, underphosphorylated form of the retinoblastoma protein RB1. Molecular analysis of RB1 mRNA from this cell line revealed a single point mutation within exon 21 that resulted in a nonconservative amino acid substitution (cysteine to phenylalanine) at codon 706. Stable expression of this mutant RB1 cDNA in a human cell line lacking endogenous RB1 demonstrated that this amino acid change was sufficient to inhibit phosphorylation. In addition, this cysteine-to-phenylalanine substitution also resulted in loss of RB1 binding to the simian virus 40 large tumor and adenovirus E1A transforming proteins. These results confirm the importance of exon 21 coding sequences and suggest that the cysteine residue at codon 706 may play a role in achieving a specific protein conformation ...

55

Effects of NaCl on Proline Synthesis and Utilization in Excised Barley Leaves 1

1. In rat soleus muscle, high frequency electrical stimulation produced a rapid increase in intracellular Na+ (Na+i) content. This was considerably larger in muscles contracting without developing tension...Full Text Available

1997-09-15

56

A novel Na⁺ channel splice form contributes to the regulation of an androgen-dependent social signal

Proline accumulation in NaCl-treated excised barley (Hordeum vulgare var Larker) leaves was studied. Leaves were treated by placing the cut end in NaCl solutions and allowing the salt...Full Text Available

1983-07-01

57

Modeling of the Three-Body Effects in the Neutral Trimers in the Quartet State by ab initio Calculations. H3, Na3, and Na2B.

Na⁺ channels are often spliced but little is known about the functional consequences of splicing. We have been studying the regulation of Na⁺ current inactivation in an...Full Text Available

2008-09-10

58

Czech Academy of Sciences Repository

Full Text Available

2003-01-01

59

Rb-Sr ages and palaeomagnetic data for some Angolan alkaline intrusives

Transient diffusion, desorption, and reaction studies of cyclopropane and propylene with NaX and Eu/NaX zeolites

New Rb-Sr age measurements are reported for a number of intrusives from Angola. Data for the Njoio and Tchivira nepheline syenite bodies yield mineral isochrons indicating ages of 104,3+-0,8 Ma and 130,8+-1,4 Ma respectively. Palaeomagnetic studies on the same occurrences gave marginal and scattered results respectively. Micas from the Camafuca crater-facies kimberlite yielded and apparent age of 1 822+-151 Ma, a result that is far in excess of the Tertiary (or younger) age inferred for this pipe. Similarly conflicting data were obtained for the Nova Lisboa kimberlite. It is likely that older crustal micas incorporated in the kimberlite breccias are responsible for the anomalous ages reported on the kimberlites. Satisfactory palaeomagnetic data are reported for the Zenza and Bailundu occurrences, not dated by the Rb-Sr method. A convenient K-Ar age of 80+-0,8 Ma was obtainable for Zenza.

60

Structure-activity relationships of anthraquinone derivatives derived from bromaminic acid as inhibitors of ectonucleoside triphosphate diphosphohydrolases (E-NTPDases)

The exchange of Eu[sup 3+] for Na[sup +] cations into the sodalite cages of X zeolite (Eu[sub 25]Na[sub 11]X) leads selectively to the isomerization reaction of cyclopropane to propylene. The latter reaction is catalyzed by Broensted acid sites with an apparent activation energy of 10.6 kcal/mol. Sorption measurements of cyclopropane and propylene with Eu/NaX and NaX zeolites at 40 C support the view that Na[sup +] cations might be considered as sites for sorption of these molecules. Force fields created by Eu[sub 4]O[sup 10+] present in Eu/NaX zeolite may affect sorption. On the other hand, Broensted acid sites in Eu/NaX enhance sorption of cyclopropane and propylene at 40 C. Chemisorption of propylene on the Broensted acid sites of Eu/NaX is reversible and may occur via a propylene carbenium cation intermediate. Small ...

1992-05-01

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61

Structural studies of peptides from HPVs (Human Papiloma Viruses) 9, 16 and 30 with LxCxE anchoring in the presence or absence of pRB (RetinoBlastoma protein)

Reactive blue 2 (RB-2) had been characterized as a relatively potent ectonucleoside triphosphate diphosphohydrolase (E-NTPDase) inhibitor with some selectivity for NTPDase3. In search for the pharmacophore...Full Text Available

2009-03-01

62

Role of microRNA-23b in flow-regulation of Rb phosphorylation and endothelial cell growth

... AUREMN), Rio de Janeiro, RJ (Brazil) [vp.] APPLIED LIFE SCIENCES cpb

2004-07-27

63

Prognostic evaluation of metallothionein expression in human colorectal neoplasms.

MicroRNAs (miRs) can regulate many cellular functions, but their roles in regulating responses of vascular endothelial cells (ECs) to mechanical stimuli remain unexplored. We hypothesize that the physiological...Full Text Available

2010-02-16

64

Genetic diversity associated with in vitro and conventional bud propagation of Saccharum varieties using RAPD analysis

AIM: To investigate the role of metallothionein in colorectal tumours and the possible relation with other factors associated with tumour progression: expression of cathepsin D (CD), CD44, p53, Rb,...Full Text Available

1999-12-01

65

British Library Electronic Table of Contents (United Kingdom)

Abstract Polymorphisms in the genomic DNA of eight varieties maintained by conventional bud propagation (via rhizomes) and by in vitro shoot tip cultures were detected by RAPD analysis of sugarcane varieties. The study estimated the genetic diversity induced after in vitro multiplication of these varieties. Higher (28.9%) and lower (12%) numbers of polymorphic bands were detected in plants propagated via rhizomes; the genetic similarity estimate varying from 0.63 to 0.80. Plants of SP90-3723 and SP91-1049, or RB85-5113 and SP90-3723, varieties involving greater genetic distances may be indicated as progenitors in breeding programmes. In vitro multiplication of RB86-7515, RB85-5113, RB83-5054 and SP86-42 varieties increases genetic variability, while in vitro multiplication of SP91-1049, SP...

2008-01-01

66

Discovery of interstellar rubidium

We have discovered interstellar rubidium by observing the resonance line of Rb I at 7800 A toward zeta Oph. This is the heaviest element yet detected within the interstellar medium, and our detection of this element is important for understanding the history of nucleosynthesis in the solar neighborhood.

1981-12-01

67

A first for Samarinda

Synthesis and characterization of Rosebengal/folicacid-functionalized multiwall carbon nanotubes

Gas-fired combined cycle plant may be the norm when it comes to new plant but it comes in a variety of shapes and sizes. Samarinda uses aero-derivatives with the famous Rolls-Royce RB211 gas generator. (author)

1996-10-01

68

British Library Electronic Table of Contents (United Kingdom)

Multiwall carbon nanotubes (MWCNTs) were functionalized with a photosensitizer, rosebengal (RB), and folicacid (FA), an anti-cancer drug simultaneously and individually, which was characterized with various analytical instruments like Fourier Transform Iinfrared (FTIR) spectroscopy, UV?Vis spectroscopy, Thermogravimetric analysis (TGA), Photoluminescence (PL) spectroscopy, X-ray photoelectron spectroscopy (XPS), and Transmission electron microscopy (TEM). FTIR spectra confirmed the chemical modification of MWCNT. The chemical functionalization of MWCNT with RB was further supported by UV?Vis and PL spectra.

2011-01-01

69

Rb-Sr age of the Sundsta granite in the Western Pregothian tectonic mega-unit, south-western Sweden

Multielement XRF-analysis of blood from patients with dilated cardiomyopathy

The Sundsta granite is a reddish, acidic granite, situated in the Western Pregothian mega-unit in Vaermland, south-western Sweden. Its Rb-Sr whole-rock age is 1566+-39 Ma with an initial ratio 0f 0.705 +-0.003. The region is dominated by grey, migmatized granitoids presumably belonging to the Aamaal-I group which has ages of 1650-1700 Ma. The marked difference in degree of migmatization between these two rock-units may indicate that the intrusion of the Sundsta granite post-dates the main migmatization phase of the Aamaal-I granitoid in this region.

1982-10-25

70

Volume regulation in Mycoplasma gallisepticum: evidence that Na+ is extruded via a primary Na+ pump.

Radionuclide x-ray fluorescence analysis was used for the determination of Fe, Zn, Br and Rb levels in whole blood from dilated cardiomyopathy patients and from a control group. The XRF-system consisted of a radionuclide source "1"0"9Cd, a semiconductor Si/Li detector connected to a multichannel analyzer. Fe content in blood of patients was significantly lower than that of the control. Zn content showed no deviation from normal range. Values for Br and Rb in patients highly exceed the range reported for them. (author) 4 tabs.; 9 refs.

1991-03-01

71

Use of Eu"3"+ as an oxygen environment probe in alkali-alkaline earth-lanthanide phosphates with the #beta#-K_2SO_4 structure

The primary extrusion of Na+ from Mycoplasma gallisepticum cells was demonstrated by showing that when Na+-loaded cells were incubated with both glucose (10 mM) and the uncoupler SF6847 (0.4 microM),...Full Text Available

1989-08-01

72

The Role of Na-Montmorillonite on Thermal Characteristics and Morphology of Electrospun PAN Nanofibers

The use of europium as a local structural probe allows the various phases appearing in the NaCaPO_4-Na_3Eu(PO_4)_2 and NaSrPO_4-Na_3Eu(PO_4)_2 systems to be detected. The broadening of the europium emission lines in going from the calcium to the strontium phases illustrates the ease of displacement of the PO_4 groups. (Auth.).

1983-09-01

73

Morphology and Properties of Polyacrylonitrile/Na-MMT Nanocomposites Prepared via in-situ Polymerization with Macroazoinitiator

Full Text Available

2010-08-01

74

Ion Exchange of Synthetic Na-fluor-tetrasilicic Mica(I)

Full Text Available

2006-06-01

75

Expression of Na(+)-H+ exchange and ATP-dependent proton extrusion in growing rat IMCD cells

Full Text Available

1984-03-01

76

Effects of thyroxine on hyperkalemia and renal cortical Na+, K+ - ATPase activity induced by cyclosporin A.

As the last step of urinary acidification, the inner medullary collecting duct (IMCD) is thought to secrete protons into the tubular lumens by means of a H(+)-translocating adenosinetriphosphatase (H(+)-ATPase). However, recent studies have also shown the existence of Na(+)-H+ exchange activity in IMCD cells. Although the physiological function of the antiporter in IMCD cells is unknown, activation of Na(+)-H+ exchange in other cell-culture systems has been suggested to be closely associated with the process of cell growth. Thus presence of Na(+)-H+ exchange may relate to the growth phase of these cells. To examine intracellular pH (pHi) regulation in growing IMCD cells, we studied proton transport by Na(+)-dependent and Na(+)-independent mechanisms by microfluorimetry using the pHi-sensitive dye 2',7'-bis(carboxyethyl)-5,6-carboxyfluorescein acetoxymethyl ester ...

1990-03-01

77

Comparison of Premixed NaHCO3 and Lidocaine on Rocuronium Injection Pain

Full Text Available

2002-10-01

78

Extracellular ATP4- promotes cation fluxes in the J774 mouse macrophage cell line

Full Text Available

2005-05-01

79

Effect of fluoride ion on the pitting corrosion of type 304 stainless steel in neutral NaCl solution. Chusei NaCl suiyoekichu ni okeru SUS 304 ko no koshoku ni oyobosu F[sup -] no eikyo

Extracellular ATP stimulates transmembrane ion fluxes in the mouse macrophage cell line J774. In the presence of Mg2+, nonhydrolyzable ATP analogs and other purine and pyrimidine nucleotides do not elicit this response, suggesting the presence of a specific receptor for ATP on the macrophage plasma membrane. One candidate for such a receptor is the ecto-ATPase expressed on these cells. We, therefore, investigated the role of this enzyme in ATP-induced /sup 86/Rb+ efflux in J774 cells. The ecto-ATPase had a broad nucleotide specificity and did not hydrolyze extracellular ATP in the absence of divalent cations. /sup 86/Rb+ efflux was not blocked by inhibition of the ecto-ATPase and did not require Ca2+ or Mg2+. In fact, ATP-stimulated /sup 86/Rb+ efflux was inhibited by Mg2+ and correlated with the availability of ATP4- in the medium. In the absence of divalent cations, the slowly hydrolyzable ATP analogs adenosine ...

1987-03-05

80

IRSL characteristics of NaCl and KCl relative to dosimeter

Anode polarization measurement is performed in mixed solution of NaCl and NaF using SUS 304 steel to investigate whether F[sup -] promotes or inhibits pitting corrosion. Pitting corrosion does not occur in the solution of NaF only, but passive state is broken above a certain critical potential, resulting in overall dissolution. When anode polarization measurement is made in a solution of fixed concentration NaCl added with NaF, pitting corrosion is inhibited at a certain critical concentration. F[sup -] has no effect on corrosion potential in the solution up to this critical concentration. Overall dissolution occurs in the solution with higher concentration than the critical concentration, the current value at that time agrees with that in the solution of NaF alone, and no effect of Cl[sup -] is shown. The concentration range where pitting corrosion occurs and ...

1994-05-15

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81

ZZ MCB-JEF2.2, MCB Continuous-Energy Neutron Cross Section Libraries for Temperatures from 300 to 1800 K

The aim of this work is to determine and compare the dosimetric properties of NaCl and KCl samples using infrared-stimulated luminescence (IRSL) technique. For a material to be used as dosimeter, both the IRSL temperature dependence and the radiation dose response have critical importance. In this work the IRSL characteristics from NaCl and KCl samples were experimentally investigated as a function of temperature and laboratory radiation doses. Dosimetric properties of NaCl and KCl samples were found significantly different. The IRSL signals displayed by NaCl were found to be more stable, reliable and agreeable than those of KCl.

2007-01-15

82

Removal of Cr(III) from aqueous solutions using zeolite NaY prepared from rice husk ash

1 - Description of program or function: MCB-JEF2.2 is a continuous-energy cross section libraries in ACE Format suitable for the MCB-1C and MCNP codes. Libraries for various materials were generated at six different Temperatures, and cover the energy range up to 20 MeV. Format: ACE. Number of groups: Continuous energy. Nuclides: H-1, H-2, H-3, He-3, He-4, Li-6, Li-7, Be-9, B-10, B-11, C-nat., N-14, N-15, O-16, O-17, Na-23, F-19, Mg-nat., Al-27, Si-nat., P-31, S-32, S-33, S-34, S-36, Cl-nat, K-nat, Ca-nat., Ti-nat, V-nat, Cr-50, Cr-52, Cr-53, Cr-54, Mn-55, Fe-54, Fe-56, Fe-57, Fe-58, Co-59, Ni-58, Ni-59, Ni-60, Ni-61, Ni-62, Ni-64, Cu-nat, Ga-nat, Ge-72, Ge-73, Ge-74, Ge-76, As-75, Se-74, Se-76, Se-77, Se-78, Se-80, Se-82, Br-79, Br-81, Kr-78, Kr-80, Kr-82, Kr-83, Kr-84, Kr-85, Kr-86, Rb-85, Rb-86, Rb-87, Sr-84, Sr-86, Sr-87, Sr-88, Sr-89, Sr-90, Y-89, Y-90, Y-91, Zr-nat, Zr-90, Zr-91, Zr-92, Zr-93, ...

83

Influence of sodium chloride and sodium sulfate salinities on photosynthetic carbon assimilation in peanut

The efficiency of the synthesized zeolite NaY from rice husk ash (RHA) in the removal of Cr(III) from aqueous solution was studied. Zeolite NaY was synthesized from RHA via seeding technique and the identification of its structure was done by X-ray Diffraction (XRD) technique and the elemental analysis was carried out by X-ray Fluorescence (XRF). The physicochemical properties which were related to the use of the zeolite NaY as a sorbent was also investigated. The synthesized zeolite NaY has higher cation exchange capacity (CEC) than the commercial zeolite NaY due to the higher amount of sodium content in the synthesized as well as the lower ratio of silica to alumina. The synthesized zeolite NaY together with the commercial one as comparison was used in the sorption of the Cr(III) in aqueous solution by batch sorption experiments. The kinetic study showed that ...

2007-01-01

84

Inactivation of several strains of Listeria monocytogenes attached to the surface of packaging material by Na-Chlorophyllin-based photosensitization

The effect of NaCl and Na_2SO_4 treatments on chlorophyll content, rate of "1"4C assimilation and products of photosynthesis in peanut (Arachish hypogaea L.) variety TMV-10 has been investigated. It was observed that chlorophyll content was affected mainly by NaCl, Na_2SO_4 treatment lowered the rate of photosynthetic "1"4CO_2 fixation. The analysis of labelled products revealed that the salts affect the carbon metabolism differently. The radioactivity was found to be accumulated in fractions of sugars and sugarphosphates in the leaves of NaCl treated plants. Na_2SO_4 treatment brought about considerable decline in labelling of sugars and an increase in labelling of amino acids and sugarphosphates. (orig.).

1980-01-01

85

British Library Electronic Table of Contents (United Kingdom)

This study was focused on the possibility to inactivate thermosensitive Listeria monocytogenes ATCL3C 7644 and thermoresistant 56 Ly strain by Na-Chlorophyllin (Na-Chl)-based photosensitization in vitro and on the surface of packaging. Comparative analysis of antimicrobial efficiency of photosensitization with conventional surface cleaning was performed. Data indicate that both Listeria strains, after incubation with Na-Chl and following illumination (l=400nm, 20mWcm-2), were inactivated by 7 log in vitro. This treatment cleaned both Listeria strains from packaging surfaces. Comparative analysis indicates that washing with water diminishes pathogens by less than 1 log, 200ppm Na-hypochlorite by 1.7 log, Na-Chl-based photosensitization by 4.5 log. Listeria biofilms were totally removed from...

2010-01-01

86

Transport and deamination of amino acids by a gram-positive, monensin-sensitive ruminal bacterium.

The nucleation kinetics of calcium sulfate dihydrate in NaCl solutions up to 6 m and 90 C

Strain F, a recently isolated ruminal bacterium, grew rapidly with glutamate or glutamine as an energy source in the presence but not the absence of Na. Monensin, a Na+/H+ antiporter, completely inhibited...Full Text Available

1990-07-01

87

The experiment NA59: The "Quarter Wave Plate" is a "110" silicon crystal of 5 cm diameter and 10 cm long

The crystallization of calcium sulfate from aqueous solutions with NaCl is both geological and industrial interest because NaCl is the dominant solute in natural brines and many industrial fluids. Induction periods for the nucleation of calcium sulfate dihydrate were experimentally determined as a function of supersaturation in NaCl solutions from 0 to 6 m at 25 C and in 3.0-m NaCl solutions at temperatures from 25 to 90 C. Using classic nucleation theory, the interfacial tension between gypsum and 3.0-m NaCl solution was estimated to be about 39 mJ/m[sup 2] at 25 C and increases with increasing temperature (to 63 mJ/m[sup 2] at 90 C). It was observed that the induction period decreases with increasing NaCl concentrations up to 3 m and then starts to increase slightly at a given temperature and saturation state. The electrolyte effect on nucleation was ...

1994-02-01

88

CERN Multimedia

The experiment NA59: The "Quarter Wave Plate" is a "110" silicon crystal of 5 cm diameter and 10 cm long

1999-01-01

89

Sodium oxonitridometallates(VI) of molybdenum and tungsten, Na[sub 4]MO[sub 2]N[sub 2] (M = Mo, W). Natriumoxonitridometallate(VI) von Molybdaen und Wolfram, Na[sub 4]MO[sub 2]N[sub 2] (M = Mo, W)

Reduced PCR Sensitivity Due to Impaired DNA Recovery with the MagNA Pure LC Total Nucleic Acid Isolation Kit

MoO[sub 3] as well as WO[sub 3] react with an excess of NaNH[sub 2] in autoclaves at temperatures ranging from 250 C to 750 C to yield - in contrast to Ta[sub 2]O[sub 5] backslash lbrackvertical stroke 1 backslash rbrackvertical stroke - oxonitridometallates of general composition Na[sub 4]MX[sub 4] and other products like Na[sub 5]WO[sub 4]N backslash lbrackvertical stroke 2 backslash rbrackvertical stroke . The compounds decompose in moist air within minutes to Na[sub 2]WO[sub 4], Na[sub 2]MoO[sub 4] and Na[sub 2]MoO[sub 4].xH[sub 2]O, respectively. (orig.)

1993-07-01

90

Pitting corrosion of Alloy 690 in thiosulfate-containing chloride solutions

The increasing demand for molecular diagnostics in clinical microbiology laboratories necessitates automated sample processing. In the present study, we evaluated the performance of the MagNA Pure LC...Full Text Available

2005-09-01

91

Mechanism of Na(+)-dependent citrate transport in Klebsiella pneumoniae.

The effects of thiosulfate ion and solution pH on pitting corrosion of Alloy 690 in chloride solution were explored. Potentiodynamic polarization measurements were conducted to evaluate pitting corrosion susceptibility of Alloy 690 in these environments. The results showed that pitting corrosion occurred in the mill-annealed (1050 deg. C/5min) Alloy 690 in 1 wt% NaCl solution but not in 0.1 M Na{sub 2}S{sub 2}O{sub 3} solution. The value of pitting nucleation potential (E{sub np}) determined in 1 wt% NaCl solution (without Na{sub 2}S{sub 2}O{sub 3} ) increased with increasing solution pH value in the range of 2-10. The addition of Na{sub 2}S{sub 2}O{sub 3} to 1 wt% NaCl solution greatly affected the pitting corrosion behavior, which was dependent on concentration. The preformed nickel sulfide surface film due to the presence of Na{sub ...

2000-02-01

92

Increased rigidity of the chiral centre of tocainide favours stereoselectivity and use-dependent block of skeletal muscle Na⁺ channels enhancing the antimyotonic activity in vivo

Citrate transport via CitS of Klebsiella pneumoniae has been shown to depend on the presence of Na+. This transport system has been expressed in Escherichia coli, and uptake of citrate in E. coli membrane...Full Text Available

1992-08-01

93

Effects of PKA phosphorylation on the conformation of the Na,K-ATPase regulatory protein FXYD1

Searching for the structural requirements improving the potency and the stereoselectivity of Na⁺ channel blockers as antimyotonic agents, new...Full Text Available

2001-12-01

94

Effect of oxygen and oxidizing ions on denting corrosion

FXYD1 (phospholemman) is a member of an evolutionarily conserved family of membrane proteins that regulate the function of the Na,K-ATPase enzyme complex in specific tissues and specific physiological...Full Text Available

2009-11-01

95

Crystal structure of ball-milled mixture of sodium chloride and magnesium chloride-ethanol adduct

Information is presented concerning solute concentration in a porous layer; solute concentration in a packed crevice; corrosion of a packed carbon steel crevice in NaCl-O"2 solutions; and effect of copper on corrosion in NaCl-O"2 solutions.

1983-01-01

96

Photoluminescence, optically stimulated luminescence, and thermoluminescence study of RbMgF3:Eu2+

NaCl doped MgCl_2.nEtOH adducts were prepared by ball-milling MgCl_2.2.5EtOH with NaCl. Both the ball-milled MgCl_2.nEtOH/NaCl mixture and pure MgCl_2.2.5EtOH adducts were analyzed by X-ray diffraction (XRD), transmission electron microscope (TEM), thermogravimetry (TG) and differencial scanning calorimetry (DSC). A simple MgCl_2.nEtOH/NaCl mixture without ball-milling treatment was also studied for comparison. Two kinds of mixed crystals, Na_2MgCl_4 and NaMgCl_3, were found to be formed in a ball-milled mixture that contained 16 mol.% NaCl. TG and DSC analysis of the samples also provided indirect evidences supporting the presence of the mixed crystals in the ball-milled mixture. Adding certain amounts of NaCl in MgCl_2.2.5EtOH adduct, either by co-milling or by simple mixing, greatly increased the thermal stability of ...

2008-02-05

97

Cross-section measurements for (n, 2a) (n, p) and (n, #alpha#) reactions on strontium isotopes at the neutron energy about 14 MeV

Optically stimulated luminescence (OSL) and thermoluminescence are observed in polycrystalline RbMgF3:Eu2+ after x-ray, ?-ray, or ? irradiation. The main electron traps are F-centers but there are other unidentified traps. The main hole traps at room temperature are probably Eu3+ and thermal or optical stimulation leads to electron-hole recombination at the Eu3+ site and Eu2+ emissions arising from 6PJ to 8S7/2 and 4f5d(Eg) to 8S7/2 transitions. We find that some of the electron traps can be emptied by infrared stimulation and all of the electron traps can be emptied by white light stimulation. The OSL dark decay is long and exceeds 5 days for traps that are emptied by white light stimulation after initial infrared bleaching. Our results show that this compound can be used as a radiation dosimeter for intermediate dose levels where the 87Rb self-dose does not significantly affect the dose reading.

2009-01-15

98

Use of Eu/sup 3 +/ as an oxygen environment probe in alkali-alkaline earth-lanthanide phosphates with the. beta. -K/sub 2/SO/sub 4/ structure

Cross-sections for "8"4Sr(n, 2n)"8"3Sr, "8"6Sr(n, 2n)"8"5"mSr, "8"6Sr(n, 2n)"8"5Sr, "8"8Sr(n, 2n)"8"7"mSr, "8"4Sr(n, p)"8"4Rb, "8"6Sr(n, p)"8"6Rb, "8"8Sr(n, p)"8"8Rb and "8"8Sr(n, #alpha#)"8"5"mKr reactions have been measured at neutron energies from 13.5 to 14.6 MeV using activation technique and by means of #gamma#-ray spectrometry. The neutron flux was determined using the monitor reaction "9"3Nb(n, 2n)"9"2"mNb and the neutron energies were measured by the method of cross-section ratios for "9Zr(n, 2n)"8"9Zr to "9"3Nb (n, 2n)"9"2"mNb reactions. The results of present work are compared with data published previously.

2006-01-01

99

Study of volatility of toxic elements from samples on the basis of phenol-formaldehyde resin

The use of europium as a local structural probe allows the various phases appearing in the NaCaPO/sub 4/-Na/sub 3/Eu(PO/sub 4/)/sub 2/ and NaSrPO/sub 4/-Na/sub 3/Eu(PO/sub 4/)/sub 2/ systems to be detected. The broadening of the europium emission lines in going from the calcium to the strontium phases illustrates the ease of displacement of the PO/sub 4/ groups.

1983-09-15

100

Effect of water on the formation of HSO/sub 3//sup -/ ions upon SO/sub 2/ adsorption onto faujasite-type zeolites

Russian 1977. USSR Dubinskaya, NA Kolomijtsev, MA Dundua, V.Yu.

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

101

Synthesis, crystal structures and spectroscopic properties of RbBaTaS{sub 4} and K{sub 2}BaTa{sub 2}S{sub 11}

SO/sub 2/ adsorption onto faujasite-type zeolites (Na-X, Na-Y) was investigated by combined UV and IR spectroscopy. Formation of chemisorbed HSO/sub 3//sup -/ species, indicated by a UV band around 215 nm and a low-frequency IR band at 1240 cm/sup -1/, was shown to depend significantly upon the presence of water. Differences in the behavior of Na-X and Na-Y were discussed in terms of different site populations.

1987-01-01

102

Transmutations in fusion test facilities

Single crystals of RbBaTaS{sub 4} (1) and K{sub 2}BaTa{sub 2}S{sub 11} (2) were obtained from the reactions of Ta, with in situ formed fluxes of A{sub 2}S{sub 3} (A = K, Rb), BaS, and S at 500 C. Compound 1 crystallizes in the orthorhombic space group Pnma with a = 9.3286(5), b = 7.0391(4), c = 12.4365(7) A, V = 816.6(1) A{sup 3}, Z = 4. Compound 2 crystallizes in the monoclinic space group P2{sub 1}/c with a = 14.5280(10), b = 12.6347(7), c = 17.5148(12) A, {beta} = 94.744(8) , V = 3203.9(4) A{sup 3}, Z = 4. The structure of RbBaTaS{sub 4} (1) consists of isolated tetrahedral [TaS{sub 4}]{sup 3-} anions and Rb{sup +} and Ba{sup 2+} cations. The Ba{sup 2+} cations are surrounded by nine sulfur atoms forming distorted tricapped trigonal prisms, whereas the Rb{sup +} cations are in an irregular environment of ten sulfur atoms. The structure of K{sub 2}BaTa{sub 2}S{sub 11} (2) consists ...

2010-10-15

103

Structure-activity relationships of anthraquinone derivatives derived from bromaminic acid as inhibitors of ectonucleoside triphosphate diphosphohydrolases (E-NTPDases)

Using an expanded nuclear data base, the transmutation of PCA, AMCR33 (a reduced activation austenitic steel), HT-9, Rafer2 (a reduced activation ferritic steel), V-15%Cr-5%Ti alloy, and SiAlON (a ceramic) were calculated for two positions in the Fast Flux Test Facility (FFTF), three positions in the High Flux Isotope Reactor (HFIR), and the first wall position of both the STARFIRE and MARS conceptual fusion reactors. The peripheral test (PTP) position, and to a lesser extent the radial beryllium (RB) position, of HFIR show significant transmutations which are often in the opposite direction to the transmutations in the fusion conceptual designs. The positions in FFTF, as well as the hafnium covered location in the HFIR RB position show relative minor transmutations.

1986-04-01

104

British Library Electronic Table of Contents (United Kingdom)

Reactive blue 2 (RB-2) had been characterized as a relatively potent ectonucleoside triphosphate diphosphohydrolase (E-NTPDase) inhibitor with some selectivity for NTPDase3. In search for the pharmacophore and to analyze structure-activity relationships we synthesized a series of truncated derivatives and analogs of RB-2, including 1-amino-2-sulfo-4-ar(alk)ylaminoanthraquinones, 1-amino-2-methyl-4-arylaminoanthraquinones, 1-amino-4-bromoanthraquinone 2-sulfonic acid esters and sulfonamides, and bis-(1-amino-4-bromoanthraquinone) sulfonamides, and investigated them in preparations of rat NTPDase1, 2, and 3 using a capillary electrophoresis assay. Several 1-amino-2-sulfo-4-ar(alk)ylaminoanthraquinone derivatives inhibited E-NTPDases in a concentration-dependent manner. The 2-sulfonate group ...

2009-01-01

105

Separation of rubidium from irradiated aluminum-encapsulated uranium

Separation of rubidium from irradiated aluminum-encapsulated uranium

A procedure was developed for separating rubidium from irradiated aluminum encapsulated uranium. The separations procedure produces a final ultra-high purity RbCl product for subsequent high performance mass spectrometric analysis. The procedure involves first removing most of the macro-components and fission products by strong base anion exchange using, first, concentrated HCl, then oxalic acid media and second, selectively separating rubidium from alkaline-earth ions and other alkali-metal ions, including cesium, using Bio-Rex-40 cation-exchange resin. The resultant RbCl is then put through a final vacuum sublimation step. Ultra-pure reagents and specially clean glassware are used throughout the procedure to minimize contamination by naturally-occurring rubidium.

1993-05-01

106

Resource-loaded planning for ALICE

A procedure was developed for separating rubidium from irradiated aluminum encapsulated uranium. The separations procedure produces a final ultra-high purity RbCl product for subsequent high performance mass spectrometric analysis. The procedure involves first removing most of the macro-components and fission products by strong base anion exchange using, first, concentrated HCl, then oxalic acid media and second, selectively separating rubidium from alkaline-earth ions and other alkali-metal ions, including cesium, using Bio-Rex-40 cation-exchange resin. The resultant RbCl is then put through a final vacuum sublimation step. Ultra-pure reagents and specially clean glassware are used throughout the procedure to minimize contamination by naturally-occurring rubidium.

1982-01-01

107

Petrography, geochemistry and regional significance of crystalline klippen in the Garhwal Lesser Himalaya, India

The ALICE experimental area management team faces various challenges when it comes to sharing scarce resources, indispensable to any efficient installation in a category one worksite. Space, cranes, jigs, and personnel with key competences have to be carefully allocated to activities so as to avoid slowing down work progress. To this intent, a resource loaded planning has been developed that allows highlighting coactivities and prioritizing critical tasks. It uses the built-in capabilities of Microsoft Project. The use of this scheduling tool leads to a more efficient use of time and a safer work environment. The installation sequence resulting from this schedule is presented in this paper. The first part of the sequence focuses on the revision of the coils in the SX2 building. The dipole has then to be installed in the RB26 side of the UX25 cavern. This complex and resource intensive activity has to be performed in parallel with the services installation inside ...

2005-01-01

108

British Library Electronic Table of Contents (United Kingdom)

Uphalda gneisses (UG) is a crystalline klippe located near Srinagar in Garhwal Himalaya. These gneisses are compared with Debguru porphyroids (DP) (?Ramgarh group) of Garhwal?Kumaun Himalaya and Baragaon mylonitic gneisses (BMG) of Himachal Himalaya. Petrographic study reveals that the deformation of UG was initiated at higher temperature (above 350?C) and continued till lowering of temperature and deformation led to the mylonitization. Geochemically, these granitic gneisses (UG, DP and BMG) exhibit similar composition. Features such as high molecular A/CNK value (>1), presence of normative corundum and absence of normative diopside, enhanced Rb/Sr, Rb/Zr ratios, enrichment of Th and containing rounded zircons support their crustally-derived S-type granitic nature. The linear plot in major...

2011-01-01

109

Gamow-Teller #beta#-transition from the 2"- ground state of "8"8Rb to the 3"- excited state of "8"8Sr

Formation of complex Langmuir and Langmuir-Blodgett films of water soluble rosebengal

The Gamow-Teller #beta#-transition from the ground state 2"- of "8"8Rb to the 3"- level at 2.734 MeV of "8"8Sr is studied. The nuclear matrix element and the log ft value are calculated using complete nuclear wave functions for the initial and final states. It is shown that, contrary to the normal assumption, the component of the final state does give a very important contribution to due to the presence of strong cancellation effects. Although our calculations favour a wave function for the 3"- level "8"8Sr where neutron 1h-1p configurations are not included, there are still some facts which make that our results cannot be taken as conclusive. (orig.).

110

British Library Electronic Table of Contents (United Kingdom)

This communication reports the formation of complex Langmuir monolayer at the air-water interface by charge transfer types of interaction with the water soluble N-cetyl Formula Not Shown -trimethyl ammonium bromide (CTAB) molecules doped with rosebengal (RB), with the stearic acid (SA) molecules of a preformed SA Langmuir monolayer. The reaction kinetics of the formation of RB-CTAB-SA complex monolayer was monitored by observing the increase in surface pressure with time while the barrier was kept fixed. Completion of interaction kinetics was confirmed by FTIR study. This complex Langmuir films at the air-water interface was transferred onto solid substrates at a desired surface pressure to form multilayered Langmuir-Blodgett films. Spectroscopic characterizations reveal some molecular lev...

2007-01-01

111

$sup 86$ $sup 88$Sr(d,$sup 3$He)$sup 85$ $sup 87$Rb reactions and a possible Z = 38 magic number

Resurgent Na^+ current: A new avenue to neuronal excitability control

The /sup 86,88/Sr(d, /sup 3/He)/sup 85,87/Rb reactions were studied at energy of 28 MeV and angular distributions were obtained for all observed states. Spectroseopic factors were extracted from distorted-wave Born-approximation calculations of the cross sections. These spectroacopic factors, and those from the /sup 86,88/Sr(/sup 3/He, d)/sup 87,89/ Y reactions, mixing in the ground state of /sup 88/Sr is inferred. The two g/sub (9/2) neutro n ton orbital populations in /sup 86/Sr. (auth)

1973-10-01

112

British Library Electronic Table of Contents (United Kingdom)

Integrative and firing properties are important characteristics of neuronal circuits and these responses are determined in large part by the repertoire of ion channels they express, which can vary considerably between cell types. Recently, a new mode of operation of voltage dependent sodium channels has been described that generates a so-called resurgent Na^+ current. Accumulating evidence suggests resurgent Na current participates in the generation of sub-threshold inward Na^+ current causing membrane depolarization which provides the necessary drive to fire high-frequency action potentials. Recent studies indicate that resurgent Na^+ current could be a more widespread feature than previously thought.

2011-01-01

113

Removal of radioactive ions from nuclear waste solutions by electrodialysis

Effect of Na/sub 3/Zn- and Na/sub 3/Ca DTPA on the behaviour and biological effect of /sup 239/Pu in rats

Removal of radioactive ions was studied from low and medium level radioactive waste solutions by electrodialysis using ion exchange membranes. The test solutions contained "1"3"7Cs"+, "1"0"6Ru"3"+ or fission products (F.P.) as active ions and NaCl, Na_2SO_4 or Ca(NO_3)_2 as inactive coexisting salts. The decontamination factor of the active ions was in the order: "1"3"7Cs"+ (greater than 99%) > "9"0Sr"2"+ > F.P. > "1"0"6Ru"3"+. The dialysis time required to attain the saturation was the shortest for monovalent cations K"+, Cs"+ and Na"+, intermediate for divalent cation Sr"2"+, and the longest for trivalent cation Ru"3"+. The ratio of the decontamination factor of an active ion eta sub( a) to the desalination factor of an inactive ion eta sub( b) was nearly equal to unity for "2"4Na, "4"2K, "1"3"7Cs and "9"0Sr. On the other hand, the apparent selective permeability of an active ion (A"+) ...

114

A biomass-supported Na2CO3 sorbent for flue gas desulfurization.

The effect of a complexon therapy scheme including early (in 1 h) administration of Na/sub 3/Ca DTPA and subsequent administration of Na/sub 3/Zn DTPA or Na/sub 3/Ca DTPA at a dose of 25 ..mu..Cimol/kg/day by three 2-week courses (5 times a week) with 2-week interruptions was studied in experiments on 541 male rats after intraperitoneal administration of /sup 239/Pu citrate complex (95 kBq/kg). The treatment resulted in a 3-fold lessening of the content of /sup 239/Pu and absorbed doses in the skeleton, a significant prolongation of the mean survival time (MST) from 452 to 593 days (Na/sub 3/Zn DTPA) and 643 days (Na/sub 3/Ca DTPA), and in a decrease of the osteosarcoma incidence from 76.4 to 32.6-41.2%. The ratio of osteosarcomas per 1 Gy retained in rats (0.076-0.083 %) did not differ from that in untreated animals.

1985-02-01

115

miR-34a and miR-15a/16 are co-regulated in non-small cell lung cancer and control cell cycle progression in a synergistic and Rb-dependent manner

A novel sorbent for SO2 removal has been investigated. The sorbent is obtained by conventional incipient wetness impregnation of abandoned biomaterials (straw or dried leaves) with an aqueous solution of Na2CO3. A material with the composition 80 wt % Na2CO3/straw shows a desulfurization activity which is both higher and faster than that of the reference sample Na2CO3/gamma-Al2O3. The breakthrough and stoichiometric SO2 adsorption efficiencies for 80 wt % Na2CO3/straw reach 48.9% and 80.6%, respectively, at a temperature of 80 degrees C. The adsorption efficiencies are almost constant in the temperature range 70 to 300 degrees C. According to IR and XPS analysis the main products observed on the spent sorbent are sulfite below 150 degrees C and sulfate at 300 degrees C. The Na2CO3 in 80 wt % Na2CO3/straw can potentially be recycled by the oxidation of the straw ...

2003-06-01

116

Rubidium 5"2P fine-structure transitions induced by collisions with potassium and caesium atoms

BackgroundmicroRNAs (miRNAs) are small non-coding RNAs that are frequently involved in carcinogenesis. Although many miRNAs form part of integrated networks, little information is...Full Text Available

117

Removal of basic dye by modified Unye bentonite, Turkey

A diode-laser fluorescence experiment was performed in order to study fine-structure transitions between 5"2P states of rubidium atoms colliding with ground-state potassium or caesium atoms. The Rb(5"2P_3_/_2) state was optically excited and the intensity ratio of sensitized to direct fluorescence was measured. (author).

118

Intrinsic and extrinsic crossluminescence in ionic crystals

The adsorption behavior of crystal violet (CV{sup +}) from aqueous solution onto raw (RB) and manganese oxide-modified (MMB) bentonite samples was investigated as a function of parameters such as initial CV{sup +} concentration, contact time and temperature. The Langmuir, Freundlich and Dubinin-Radushkevich (D-R) adsorption models were applied to describe the equilibrium isotherms. The Langmuir monolayer adsorption capacities of RB and MMB were estimated as 0.32 and 1.12 mmol/g, respectively. The mean adsorption energy derived from D-R isotherm for MMB showed that the type of adsorption of dye molecules on this material may be defined as chemical adsorption. The adsorption rate was fast and more than half of the adsorbed-CV{sup +} was removed in the first 55 min for RB and 5 min for MMB at the room temperature. The pseudo-first-order, pseudo-second-order kinetic and the intraparticle diffusion models were used to describe ...

2009-03-15

119

Intrinsic and extrinsic crossluminescence in ionic crystals

Intrinsic crossluminescence (CRL) of CsBr, CsCl, and of BaF{sub 2} was investigated with electron-beam and synchrotron radiation excitation. From the CRL spectra, the excitation spectra and the reflectivity, energy level schemes were deduced. Extrinsic CRL was observed changing either the initial (CsCl:Br{sup -}) or the final (RbCl:Cs{sup +}; KCl:Cs{sup +}) state of CRL by doping. (author).

1991-01-01

120

Intestinal circulation during inhalation anesthesia

Intrinsic crossluminescence (CRL) of CsBr, CsCl, and of BaF_2 was investigated with electron-beam and synchrotron radiation excitation. From the CRL spectra, the excitation spectra and the reflectivity, energy level schemes were deduced. Extrinsic CRL was observed changing either the initial (CsCl:Br"-) or the final (RbCl:Cs"+; KCl:Cs"+) state of CRL by doping. (author).

1990-09-03

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

121

Intestinal circulation during inhalation anesthesia

This study was designed to evaluate the influence of inhalational agents on the intestinal circulation in an isolated loop preparation. Sixty dogs were studied, using three intestinal segments from each dog. Selected intestinal segments were pumped with aortic blood at a constant pressure of 100 mmHg. A mixture of /sub 86/Rb and 9-microns spheres labeled with /sup 141/Ce was injected into the arterial cannula supplying the intestinal loop, while mesenteric venous blood was collected for activity counting. A very strong and significant correlation was found between rubidium clearance and microsphere entrapment (r = 0.97, P less than 0.0001). Nitrous oxide anesthesia was accompanied by a higher vascular resistance (VR), lower flow (F), rubidium clearance (Cl-Rb), and microspheres entrapment (Cl-Sph) than pentobarbital anesthesia, indicating that the vascular bed in the intestinal segment was constricted and flow (total and nutritive) decreased. ...

1985-04-01

122

Identification and determination of elements in Taraxacum officinale plant from different Bratislava localities

This study was designed to evaluate the influence of inhalational agents on the intestinal circulation in an isolated loop preparation. Sixty dogs were studied, using three intestinal segments from each dog. Selected intestinal segments were pumped with aortic blood at a constant pressure of 100 mmHg. A mixture of _8_6Rb and 9-microns spheres labeled with "1"4"1Ce was injected into the arterial cannula supplying the intestinal loop, while mesenteric venous blood was collected for activity counting. A very strong and significant correlation was found between rubidium clearance and microsphere entrapment (r = 0.97, P less than 0.0001). Nitrous oxide anesthesia was accompanied by a higher vascular resistance (VR), lower flow (F), rubidium clearance (Cl-Rb), and microspheres entrapment (Cl-Sph) than pentobarbital anesthesia, indicating that the vascular bed in the intestinal segment was constricted and flow (total and nutritive) decreased. ...

123

Identification and determination of elements in Taraxacum officinale plant from different Bratislava localities

Elements Ti, Mn, Fe, Ni, Cu, Zn, Pb, Br, Rb and Sr were determined by the method of radionuclide X-ray fluorescence analysis with semiconductor detection in samples of Taraxacum officinale from various localities of Bratislava. The dependence of their content on the source and the degree of the air pollution was found out.

1983-01-01

124

Heavy metals and some other elements in medicinal plants. Determined by X-ray fluorescence analysis

Elements Ti, Mn, Fe, Ni, Cu, Zn, Pb, Br, Rb and Sr were determined by the method of radionuclide X-ray fluorescence analysis with semiconductor detection in samples of Taraxacum officinale from various localities of Bratislava. The dependence of their content on the source and the degree of the air pollution was found out. (author).

1983-01-01

125

First results of preoperative localisation of parathyroid glands adenomas by means of subtraction scintigraphy with technetium-99m and thallium-201

Determination of Mn, Fe, Cu, Zn, Hg, Pb, Br, Se, Rb, Sr and Cd in the medicinal plants by radionuclide X-ray fluorescence analysis (using "2"3"8Pu, "2"4"1Am/Ag and "1"2"5I) is described. (author). 12 refs., 2 tabs.

1995-01-01

126

Enhancement of efficacy of process water monitors in detecting heavy water leak in steam generator blow down lines

Eight patients with primary hyperparathyroidism were examined preoperative to locate the affected parathyroid glands. The localisation was done with technetium 99m and thallium 201. This new method seems to be of great value to locate preoperative the affected parathyroid glands. (R.B.).

127

Effect of Lanthanum on Ion Absorption in Corn Roots ¹

The Steam Generator (SG) serves as an interface between primary and secondary cycle in Pressurized Heavy Water Reactor (PHWR). Failure of steam generator tubes result in leaking of active heavy water in the secondary closed loop. In Tarapur Atomic Power Station-3 and 4 (TAPS- 3 and 4), Scintillator detectors are provided to detect on line heavy water leakages in SG and moderator heat exchangers by monitoring Nitrogen-16 (16N) and Oxygen-19 (19O) activities. Efficacy of detection of these activities at designed detector position on SG blow down line in presence of background radiation field is analysed theoretically. The count rate of 19O and 16N estimated at the detector position inside Reactor Building (RB) shows that detectors only respond to very high leak rates due to presence of high ambient radiation level even though sensitivity is appreciably good. For detector position in RB in the accessible areas and out side the RE containment, the ...

2006-11-13

128

Comparative Uptake and Interaction of Several Radionuclides in the Trophic Levels Surrounding the Los Alamos Meson Physics Facility (LAMPF) Waste Water Ponds.

Short term (10 min) influx of ⁸⁶Rb-labeled potassium into corn (Zea mays L. WF9 × M14) root segments was inhibited by La (NO₃)₃ or LaCl₃....Full Text Available

1975-03-01

129

Environmental, health, and safety issues of sodium-sulfur batteries for electric and hybrid vehicles. Volume 1, Cell and battery safety

A study was undertaken to examine the uptake, distribution, and interaction of five activation products (Co-57, Be-7, Cs-134, Rb-83, and Mn-54) within the biotic and abiotic components surrounding the waste treatment lagoons of the Los Alamos Meson Physic...

1989-01-01

130

Environmental, health, and safety issues of sodium-sulfur batteries for electric and hybrid vehicles

This report is the first of four volumes that identify and assess the environmental, health, and safety issues involved in using sodium-sulfur (Na/S) battery technology as the energy source in electric and hybrid vehicles that may affect the commercialization of Na/S batteries. This and the other reports on recycling, shipping, and vehicle safety are intended to help the Electric and Hybrid Propulsion Division of the Office of Transportation Technologies in the US Department of Energy (DOE/EHP) determine the direction of its research, development, and demonstration (RD&D) program for Na/S battery technology. The reports review the status of Na/S battery RD&D and identify potential hazards and risks that may require additional research or that may affect the design and use of Na/S batteries. This volume covers cell design and engineering as the basis of safety for ...

1992-09-01

131

Insulin affects the sodium affinity of the rat adipocyte (Na ,K )-ATPase

This report is the first of four volumes that identify and assess the environmental, health, and safety issues involved in using sodium-sulfur (Na/S) battery technology as the energy source in electric and hybrid vehicles that may affect the commercialization of Na/S batteries. This and the other reports on recycling, shipping, and vehicle safety are intended to help the Electric and Hybrid Propulsion Division of the Office of Transportation Technologies in the US Department of Energy (DOE/EHP) determine the direction of its research, development, and demonstration (RD D) program for Na/S battery technology. The reports review the status of Na/S battery RD D and identify potential hazards and risks that may require additional research or that may affect the design and use of Na/S batteries. This volume covers cell design and engineering as the basis of safety for ...

1992-09-01

132

x - NASA Technical Reports Server

The K0.5 for intracellular sodium of the two forms of (Na ,K )-ATPase which exist in rat adipocytes has been determined by incubating the cells in the absence of potassium in buffers of varying sodium concentration; these conditions shut off the Na pump and allow sodium to equilibrate into the cell. The activity of (Na ,K )-ATPase was then monitored with YWRb /K pumping which was initiated by adding isotope and KCl to 5 mM, followed by a 3-min uptake period. Atomic absorption and SSNa tracer equilibration were used to determine the actual intracellular (Na ) under the different conditions. The K0.5 values thus obtained were 17 mM for alpha and 52 mM for alpha(+). Insulin treatment of rat adipocytes had no effect on the intracellular (Na+) nor on the Vmax of YWRb /K pumping, but did produce a shift in the sodium ion K0.5 values to 14 mM for alpha and 33 mM for alpha(+). This change ...

1985-08-25

133

Variation of ion Eu III concentration incorporated in yttrium-aluminium matrix; Variacao da concentracao do ion Eu III incorporado na matriz de itrio-aluminio

analysis of NaMBT in ethylene glycol-water solutions with high accuracy. It reduces analysis time, requires smaller samples, and is able to detect extremely ...

134

Sorption of long-lived radionuclides from model radioactive wastes on {alpha}-crystalline polyantimonic acid; Sorpcja radionuklidow dlugozyciowych z modelowych odpadow promieniotworczych na {alpha}-krystalicznym kwasie poliantymonowym

No abstract prepared.

2005-07-01

135

Novel approach to decontaminate food-packaging from pathogens in non-thermal and not chemical way: Chlorophyllin-based photosensitization

No abstract prepared

1998-12-31

136

British Library Electronic Table of Contents (United Kingdom)

This study was focused on the possibility to inactivate main food pathogens, their spores and biofilms on the surface of packaging material polyolefine by Na-chlorophyllin (Na-Chl)-based photosensitization and to compare efficiency of this treatment with conventional antimicrobials. Data indicate that Bacillus cereus and Listeria monocytogenes were effectively inactivated (7 log) by Na-Chl (7.5x10-7M)-based photosensitization in vitro and on the surface of packaging. Meanwhile to achieve adequate inactivation of thermo-resistant strains, spores or biofilms the higher Na-Chl concentration and longer illumination times had to be used. Comparison of different surface decontamination treatments reveal that photosensitization is much more effective against B. cereus and L. monocytogenes attache...

2011-01-01

137

Neuroradiologic and Neurophysiologic Findings of Neuralgic Amyotrophy

NASA TECH BRIEF - NASA Technical Report Server (NTRS)

ObjectiveNeuralgic amyotrophy (NA) is a distinct clinical syndrome that is characterized by the acute onset of shoulder and arm pain, weakness, and sensory loss. The purpose of this...Full Text Available

2010-11-01

138

Mathematical analysis of inhibition effect of natural products in labelling of blood elements: preliminary studies; Analise matematica do efeito de produtos naturais na marcacao de elementos sanguineos: estudos preliminares

(NaMBT) inhibitor in ethylene glycol-water solutions. The improved method must be faster and more accur- ate than wet chemical techniques. ...

139

Instrumental-activation analysis of Mo, Al, Ca, Mn, Cl, Na, and K in soil-plant samples

No abstract prepared.

1998-07-01

140

Environmental, health, and safety issues of sodium-sulfur batteries for electric and hybrid vehicles

... activation analysis aluminium 28 calcium 49 chlorine 38 cotton plants li-drifted

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

141

Corrosion behavior of sputter-deposited W-Nb alloys in NaCl and NaOH solutions

Recycling and disposal of spent sodium-sulfur (Na/S) batteries are important issues that must be addressed as part of the commercialization process of Na/S battery-powered electric vehicles. The use of Na/S batteries in electric vehicles will result in significant environmental benefits, and the disposal of spent batteries should not detract from those benefits. In the United States, waste disposal is regulated under the Resource Conservation and Recovery Act (RCRA). Understanding these regulations will help in selecting recycling and disposal processes for Na/S batteries that are environmentally acceptable and cost effective. Treatment processes for spent Na/S battery wastes are in the beginning stages of development, so a final evaluation of the impact of RCRA regulations on these treatment processes is not possible. The objectives of tills report on battery recycling and disposal ...

1992-09-01

142

A Response Surface Model Based on Absorbance Data for the Growth Rates of Salmonella enterica Serovar Typhimurium as a Function of Temperature, NaCl, and pH

The corrosion behavior of the sputter-deposited amorphous or nanocrystalline W-Nb alloys is studied in 10% NaCl, 0.1 and 1 M NaOH solutions at 24 deg. C, open to air using immersion tests and electrochemical measurements. Niobium metal acts synergistically with tungsten in enhancing the corrosion resistance of the W-Nb alloys so as to show lower corrosion rates than the corrosion rates of the alloy-constituting elements in almost all examined solutions. Corrosion rates of W-Nb alloys are about more than one order of magnitude less than that of the sputter-deposited tungsten and even lower than that of sputter-deposited niobium. The stability of the anodic passive films formed on the W-Nb alloys increase with niobium content.

2008-05-29

143

8862 - NASA Technical Reports Server

Full Text Available

2007-04-01

144

Two-nucleon multiplets near mass A = 88 and the implication for the residual nucleon-nucleon interaction

Mar 1, 2011 ... analysis of NaMBT in ethylene glycol-water solutions with high accuracy. It reduces analysis time, requires smaller samples, and is able to ...

145

Two-nucleon multiplets near mass A = 88 and the implication for the residual nucleon-nucleon interaction

The low excitation energy spectroscopy of /sup 86/Sr, /sup 88/Sr, /sup 89/Sr, /sup 86/Rb, and /sup 87/Rb nuclear systems was studied via one-nucleon transfer reactions. The strontium isotopes, /sup 87/Sr and /sup 88/Sr, were used as targets in this study. Spectroscopic strengths were extracted from the measured transfer reaction cross sections and the distorted wave Born approximation (DWBA) analysis. Efforts have been made to accomplish a complete detection of spectroscopic strengths through the excitation energy region where levels can be resolved and identified. A shell model sum rule analysis is then made. Diagonal matrix elements for the effective two-nucleon interaction were deduced from empirical energy centroid. Matrix elements normalized by their empirical monopole energy was plotted against the semiclassical angle between two spins. They were compared with various analytical function forms of the effective two-nucleon interaction ...

1987-01-01

146

Rubidium uptake by mouse pancreatic islets exposed to 6-hydroxydopamine, ninhydrin, or other generators of hydroxyl radicals

The low excitation energy spectroscopy of "8"6Sr, "8"8Sr, "8"9Sr, "8"6Rb, and "8"7Rb nuclear systems was studied via one-nucleon transfer reactions. The strontium isotopes, "8"7Sr and "8"8Sr, were used as targets in this study. Spectroscopic strengths were extracted from the measured transfer reaction cross sections and the distorted wave Born approximation (DWBA) analysis. Efforts have been made to accomplish a complete detection of spectroscopic strengths through the excitation energy region where levels can be resolved and identified. A shell model sum rule analysis is then made. Diagonal matrix elements for the effective two-nucleon interaction were deduced from empirical energy centroid. Matrix elements normalized by their empirical monopole energy was plotted against the semiclassical angle between two spins. They were compared with various analytical function forms of the effective two-nucleon interaction depending on their spins, ...

147

Determination of trace elements in Syrian medicinal plants and their infusions by energy dispersive X-ray fluorescence and total reflection X-ray fluorescence spectrometry

The purpose was to study the toxicity of drugs known to generate free radicals on isolated pancreatic islets. The accumulattion of "8"6Rb"+ by mouse pancreatic islets was measured in vitro. Exposing the islets to 6-hydroxydopamine, minhydrin, or phenazine methosulphate + NADH inhibited the Rb"+ uptake, whereas paraquat or acetylphenylhydrazine had no effect. This effect of 6-hydroxydopamine was prevented by either of the hydroxyl radical scavengers, sodium benzoate and mannitol, but not by the non-scavenger,urea; ninhydrin was partially protected against by mannitol but not by benzoate. Protection against 6-hydroxydopamine was also afforded by D-glucose but not by L-glucose or 3-O-methyl-D-glucose; none of the sugars protected against ninhydrin. In damaging islet beta-cells and in being protected against by D-glucose, 6-hydroxydopamine closely resembles the diabetogenic drug, alloxan. It is suggested that protection against alloxan may involve ...

148

Decolorization of reactive dyes by mixed cultures isolated from textile effluent under anaerobic conditions

X-ray fluorescence (XRF) and total-reflection X-ray fluorescence (TXRF) techniques suited well for a multi-element determination of K, Ca, Mn, Fe, Cu, Zn, Rb, and Sr in some Syrian medicinal plant species. The accuracy and the precision of both techniques were verified by analyzing the Standard Reference Materials (SRM) peach-1547 and apple leaves-1515. A good agreement between the measured concentrations of the previously mentioned elements and the certified values were obtained with errors less than 10.7% for TXRF and 15.8% for XRF. The determination of Br was acceptable only by XRF with an error less than 24%. Furthermore, the XRF method showed a very good applicability for the determination of K, Ca, Mn, Fe, Cu, Zn, Rb, Sr, and Br in infusions of different Syrian medicinal plant species, namely anise (Anisum vulgare), licorice root (Glycyrrhiza glabra), and white wormwood (Artemisia herba-alba)

2009-07-15

149

British Library Electronic Table of Contents (United Kingdom)

In the present study mixed cultures that could grew in the molasses media were isolated from textile dye effluent and its decolorization activity was studied in a batch system under anaerobic conditions, in order to determine the optimal conditions required for the highest decolorization activity. The optimum pH value for decolorization was determined as 8 for all the dyes tested. In the experiment with pH 8 dye decolorizations by mixed cultures were investigated at about 96.2-1031.3mgl-1 initial dye concentrations. The highest dye removal rates of mixed cultures were 94.9% for Reactive Red RB, 91.0% for Reactive Black B and 63.6% for Remazol Blue at 953.2, 864.9 and 1031.3mgl-1 initial dye concentrations respectively within 24h incubation period. When the Reactive Red RB was used, approxi...

2006-01-01

150

Changes of the surface-to-volume ratio and diffusion coefficient of fission gas in fuel pellets during irradiation

Application of radionuclide X-ray fluorescence analysis to the monitoring of the quality of air

Short-lived fission gas release from fuel pellets during irradiation was investigated based on the experimental results of the gas-flow rigs irradiated in the Halden Heavy Water Reactor (HBWR). The release-to-birth (R/B) rates of short-lived fission gas were measured by means of gas-flow measurement during the irradiation experiments. Surface-to-volume (S/V) ratios of fuel pellets and diffusion coefficients of short-lived fission gas release were evaluated from the obtained (R/B) values. The increase of (S/V) ratio agreed well with the point where the fuel temperature exceeded the threshold of 1% fission gas release. This indicates that the interlinkage of fission gas bubbles occurred there. The evaluated diffusion coefficients scattered in the range between 10"-"2"3 and 10"-"1"7 m"2/s, and the effects of fuel type (UO_2 or MOX) were not clearly observed. In addition, it is likely that the restructuring effect of fuel pellet on the diffusion ...

2010-07-31

151

(n,2n) excitation functions for "5"4Fe, "7"0Ge, "7"4Se, "8"5Rb, sup(86,88)Sr, "8"9Y, "9"2Mo, and "2"0"4Hg in the neutron energy region 13-18 MeV

An X-ray fluorometric train was set up for analyzing gravitational fallout, and tested on standard reference samples of fly ashes from conventional power plants. Analysis of thin layers proved inappropriate, and therefore pelletization of the samples, either alone or together with the X-ray MIX binder, was applied. Sample grinding in an agate mortar was found sufficient to suppress the particle size effect. The optimum pressure was 20 MPa. The optimum geometry was sought for "1"0"9Cd source, and limits of detection of 2.78-0.47 #mu#g were achieved for Cr-Zr elements. Tominaga's method was employed for matrix effect correction. Ti, Fe, Cu, Zn, As, Rb, Sr, Zr and Pb were determined in the SRM's; the relative errors ranged from units per cent (for Zn, Rb, Sr and Zr present in concentrations about 100 ppm and for Fe in concentrations of units per cent) up to 45% (for Ti present in a concentration of 0.67%). The method developed was applied to the ...

1990-10-01

152

Some structural factors affecting the critical temperatures of superconductors

Using the activitation method (n,2n) excitation-functions were measured for "5"4Fe, "7"0Ge, "7"4Se, "8"5Rb, sup(86,88)Sr, "8"9Y, "9"2Mo, and "2"0"4Hg in the neutron-energy region 13-18 MeV. The results are checked for consistency by means of a systematic of (n,2n) cross-sections as a function of the nuclear neutron excess (N-Z)/A. Furthermore the data are compared with results from the statistical nuclear reactions theory which were calculated using optical model absorption cross-sections and the Fermi-gas-model formula for the nuclear level density. In the case of "2"0"4Hg the influence of preequilibrium nucleon emission was taken into account. (orig.).

153

Real-time neutron diffraction measurements of the kinetics of first-order phase transitions

A new empirical expression is presented for the T/sub c/ of A-15 compounds, T/sub c/ = 210 2R/sub A/-d/sub 0//R/sub B/..sqrt..M/sub A/ x R/sup 3//sub A/g-barZ-bary/sub B//RB/R/sup 3//sub B/n-baray/sub A//R/sub A/, from which the effects of some structural factors on T/sub c/ for high-T/sub c/ superconductors are obvious.

1981-07-01

154

Radio frequency He/sup -/ source and a source of negative ions by cesium sputtering

The wide-angle neutron diffractometer recently installed at the HFIR has the capability of performing time-resolved or time-slicing measurements. One of the interesting problem areas the authors have explored using this time-slicing function of the diffractometer is the kinetics of structural changes occurring after a temperature jump across a value at which a first-order phase transition occurs. Two measurements of this sort have been carried out: the phase III to II transition in RbNO_3 and the transition between the alpha and beta phases in Sn.

1985-03-01

155

Production of superheavy elements in cold fusion reactions

Two sources of negative ions are described. An rf source produces up to 14 ..mu..A beams of He/sup -/ by charge exchange in Rb vapor. The other Source of Negative Ions by Cesium Sputtering (SNICS) produces a wide variety of negative ion beams in the ..mu..A range. Two important features of SNICS are its simple, compact construction and its very good beam emittance (2 to 4..pi..mm mrad MeV/sup 1/2/). Both sources have lifetimes >200 hours and they are used extensively on the Wisconsin EN tandem.

1981-04-01

156

Interpretation of neutron activation cross-sections with pre-equilibrium consideration

The cold fusion reactions leading to superheavy elements with Z=104-116 has been discussed in our model recently [5]. Presently we shortly discuss our model and extend our consideration to fusion reactions ("8"6Kr, "8"7Rb, "8"8Sr)+"2"0"8Pb and "8"6Kr+"2"0"9Bi leading to elements with Z=118-120. The available experimental cross-section data for the reactions are well described.

2001-04-19

157

Identification of elements in plant drugs and their water infusion using X-ray fluorescence analysis

The aim of the present is to consider the influence of pr equilibrium processes on the activation cross-sections of "2"7 Al(n,p) "2"7 Mg, "5"1 V(n,p) "5"1"m Ti, "8"8 Sr(n,p) "8"8"m Rb, "9"4 Zr(n,p) "9"4"m Y and "9"7"Mo(n,p) "9"7"m Nb in the neutron energy range 13 to 15 MeV. Comparison with recent measurements is given for all considered isotopes. 2 figs., 1 tab.

158

Theoretical studies of metal-phosphate interactions: interaction of Li+, Na+, K+, Be++, Mg++, and Ca++ with H2PO4- and (CH3O)2PO2-: implications for nucleic acid solvation.

The present work gives preliminary results of analysis of drug mixtures (NEPHROSAL tea bag) and its water infusion. In a sample of dried drugs the elements K, Ca, Mn, Fe, Ni, Cu, Zn, Br, Rb, Sr, Pb were identified, whereas in their water infusion only Ca, Mn, Zn and Sr were found. The method applied was radionuclide X-ray fluorescence analysis using a radionuclide source "1"0"9Cd, a Si/Li semiconductor detector and a multichannel analyzer Canberra 8100. (author) 6 refs.; 3 figs.

8100-01-01

159

The Na⁺/H⁺ Exchanger NHE6 in the Endosomal Recycling System Is Involved in the Development of Apical Bile Canalicular Surface Domains in HepG2 Cells

Model phosphate-metal solvation complexes have been studied by ab-initio self-consistent-field techniques. The complexes studied include (RO)2PO2-(R = H or CH3) with Li+, Na+, K+, Be++, Mg++, Ca++,...Full Text Available

1975-10-01

160

Spectrophotometric technique quantitatively determines NaMBT inhibitor in ethylene glycol-water solutions

Polarized epithelial cells develop and maintain distinct apical and basolateral surface domains despite a continuous flux of membranes between these domains. The Na⁺/H⁺exchanger...Full Text Available

2010-04-01

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161

Spectral D line of Na-like multicharged ions and phenomenological inclusion of the Lamb shift in the many-electron systems

Spectrophotometric method, using a ratio-recording ultraviolet-absorption spectrophotometer, permits analysis of NaMBT in ethylene glycol-water solutions with high accuracy. It reduces analysis time, requires smaller samples, and is able to detect extremely small concentrations of mercaptobenzothiazole.

1967-01-01

162

Methanol to gasoline over zeolite H-ZSM-5: Improved catalyst performance by treatment with NaOH

Phenomenological accountancy of quanta-electrodynamic corrections by means of introduction into multielectron theory of short-term potential, the parameters whereof are calibrated in such a way that provides for correct reproduction of the Lamb shift of the 1s-orbital energy for a correspondingly selected effective charge is developed by example of d-line of Na-like multicharged ions.

163

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Wastenet

... There are common woodland birds in spring and turtle doves in spring and summer. Havergate Island This small island in the River ...for its breeding avocets and terns, which can be seen throughout the spring and summer. Access is by boat only and the trip ... Visit in spring to hear a symphony of birdsong, especially the nightingales which breed here, and to see bluebells and primroses ... Spring is also an excellent time to visit. Loch na Muilne Loch na Muilne is a fantastic place to see a variety ...

164

British Library Electronic Table of Contents (United Kingdom)

The catalytic performance of alkaline-treated zeolite H-ZSM-5 in the conversion of methanol to gasoline has been studied. After treatment with 0.20M NaOH, the total conversion capacity increased by a factor of 3.3, and the selectivity towards the gasoline fraction increased by a factor of 1.7. Physical characterization indicated the formation of mesopores and improved crystallinity.

2008-01-01

165

Infrared stimulated luminescence-decay shape from NaCl as a function of radiation doses

Gamma-ray spectra from neutron capture on /sup 87/Sr

Dose-dependent behavior of the infrared stimulated luminescence (IRSL) decay from NaCl has been studied experimentally using only one aliquot irradiated with a range of 2-200 Gy {beta}-radiation doses. It was observed that the maximum IRSL intensity has not changed by an increase in dose though the total intensity increased as expected. Considering the possible implications of our findings for dosimeter, the results were compared with the other studies and discussed.

2007-11-15

166

Evidence for Na⁺ Influx via the NtpJ Protein of the KtrII K⁺ Uptake System in Enterococcus hirae

The gamma-ray spectrum following neutron capture on /sup 87/Sr was measured at 3 neutron energies: E/sub n/ = thermal, 2 keV, and 24 keV. Gamma rays were detected in a three-crystal Ge(Li)-NaI-NaI pair spectrometer. Gamma-ray intensities deduced from these spectra by spectral unfolding are presented.

1981-07-01

167

Effects of pseudomonas toxin A, diphtheria toxin, and cholera toxin on electrical characteristics of turtle bladder.

The ntpJ gene, a cistron located at the tail end of the vacuolar-type Na⁺-ATPase (ntp) operon of Enterococcus hirae, encodes a transporter...Full Text Available

2000-05-01

168

Effect of modification on catalytic properties of NaY zeolites

Rapidly developing changes in the short-circuiting current (Isc), conductance (G), and potential (PD) of turtle bladders in Na-rich or Na-free media are seen after the mucosal addition, at 10 nM, of...Full Text Available

1979-07-01

169

Corrosion resistance of metals in hot hydroxide solutions

The effect of treatment with hydrogen, hydrogen sulfide, and steam on the catalytic properties of NaY zeolites has been studied. A mechanism has been proposed for activation of the zeolites, which explains the appearance of Broensted acid centers on modified samples. The influence of modification temperature and the degree of decationization of the zeolites on the promoting capacity of the latter in the cumene cracking reaction has been studied.

1988-04-01

170

Corrosion Behavior of Titanium Grade 7 in Fluoride-Containing NaCl Brines.

Effect of hydroxide nature, concentration and temperature on corrosion resistance of domestic steels and alloys to hot NaOH, KOH, LiOH solutions is considered. It is ascertained that by corrosion growth in relation to stainless steels and nickel alloys, the hydroxides are placed in the following sequence: LiOHNaOH. Hydroxide solution concentration and temperature regions in which stainless steel and nickel alloy tendency to cracking is manifested, are determined. 12 refs., 12 figs.

171

Comparative study on tea chemical analysis; Estudo comparativo na analise quimica de chas

The effects of fluoride on the corrosion behavior of Titanium Grade 7 (0.12-0.25% Pd) have been investigated. Up to 0.1 mol/L fluoride was added to the NaCl brines at 95oC, and three pH values of 4, 8, and 11 were selected for studying pH dependence of fl...

2004-01-01

172

Syntheses and crystal structures of the compounds In_3_._7Mo_1_5S_1_9, In_1_._6Rb_2Mo_1_5S_1_9, In_2_._2CsMo_1_5S_1_9 and ScTl_2Mo_1_5S_1_9 containing Mo_6 and Mo_9 clusters

This paper describes the application of the instrumental analytical methods: neutron activation techniques, atomic absorption spectroscopy and flame emission spectroscopy, used to analyse some home-made teas, determining Na, K and Cl and comparing the results. This study verify whether the home-made teas used for rehydration of the children reach the composition recommended by WHO (World Health Organization). (author). 6 refs., 6 tabs.

1995-12-31

173

Rb-Sr isotope systematics of granitic soil chronosequence: The importance of biotite weathering

The new compounds In_3_._7Mo_1_5S_1_9, In_1_._6Rb_2Mo_1_5S_1_9, In_2_._2CsMo_1_5S_1_9, and ScTl_2Mo_1_5S_1_9 have been synthesized by solid-state reaction in sealed molybdenum crucible at about 1250 deg. C. Their crystal structures were solved and refined from X-ray single-crystal data in the hexagonal space group P63/m. Their Mo-S framework consists of an equal mixture of Mo_6S_8S_6 and Mo_9S_1_1S_6 cluster units interconnected through Mo-S bonds. In In_3_._7Mo_1_5S_1_9, the In atoms occupy crystallographically different positions depending on their formal oxidation states of +1 or +3. This was confirmed by replacing partially or totally the monovalent indium by another monovalent cation such as the rubidium, cesium or thallium and the trivalent indium by the scandium to get the new In_1_._6Rb_2Mo_1_5S_1_9, In_2_._2CsMo_1_5S_1_9, and ScTl_2Mo_1_5S_1_9 compounds, respectively.

2004-11-30

174

Photooxidation of different organic dyes (RB, MO, TB, and BG) using Fe(III)-doped TiO{sub 2} nanophotocatalyst prepared by novel chemical method

The Rb-Sr isotope systematics of bedrock, soil digests, and the cation exchange fraction of soils from a granitic glacial soil chronosequence in the Wind River Mountains, Wyoming, USA, were investigated. Six soil profiles ranging in age from 0.4 to {approximately}300 kyr were studied and revealed that the {sup 87}Sr/{sup 86}Sr ratio of exchangeable strontium in the B-horizons decreased from 0.7947 to 0.7114 with increasing soil age. Soil digests of the same samples showed much smaller variation in {sup 87}Sr/{sup 86}Sr from 0.7272 to 0.7103 and also generally decreased with increasing soil age. Elevation of the {sup 87}Sr/{sup 86}Sr ratios of Sr released by weathering over the soil digest and bedrock values results from the rapid weathering of biotite to form hydrobiotite and vermiculite in the younger soils. Biotite is estimated to weather at approximately eight times the rate of plagioclase (per gram of mineral) in the youngest soil profile and decreases to a ...

1997-08-01

175

Emplacement ages of Jurassic-Cretaceous South African kimberlites by the Rb-Sr method on phlogopite and whole-rock samples

The nano-structured Fe(III)-doped TiO{sub 2} photocatalysts with anatase phase have been developed for the oxidation of non-biodegradable different organic dyes like methyl orange (MO), rhodamine B (RB), thymol blue (TB) and bromocresol green (BG) using UV-Hg-lamp. The different compositions of Fe{sub x}Ti{sub 1-x}O{sub 2} (x = 0.005, 0.01, 0.05, and 0.1) nanocatalysts synthesized by chemical method (CM), have been characterized by X-ray diffraction (XRD), UV-vis diffuse reflectance spectra, specific surface area (BET), transmission electronic microscopy (TEM) analysis, XPS, ESR and zeta potential. From XRD analysis, the results indicate that all the compositions of Fe(III) doped in TiO{sub 2} catalysts gives only anatase phase not rutile phase. For complete degradation of all the solutions of the dyes (MO, RB, TB, and BG), the composition with x = 0.005 is more photoactive compared all other compositions of Fe{sub x}Ti{sub 1-x}O{sub 2}, and ...

2008-09-15

176

Analysis of efficacy of process water monitors in detecting heavy water leak in steam generator blow down lines

Rb-Sr phlogopite age determinations, interpreted as emplacement ages, are reported for 15 southern African kimberlites. Jagersfontein and Rietfontein (85 and 95 Ma) have ages typical of the majority of well-known Cretaceous kimberlites, whereas somewhat older ages of about 118 to 125 Ma have been obtained for localities in the Postmasburg, Barkly West and Boshoff districts. Previous zircon ages of 90Ma for Finsch and Roberts Victor are believed to be incorrect. Two other localities in the Barkly West area have significantly younger emplacement ages of about 114 Ma relative to most Barkly West occurrences. Two off-craton kimberlites, Uintjiesberg and Mzongwana, are 100 and 150 Ma in age respectively. Swartruggens and Elandskloof have ages of 150-160 and 165 Ma respectively. A Barkly West occurrence, Klipfontein, also has an apparent age of 160 Ma, but this result cannot be considered reliable. The emplacement ages and initial "8"7Sr/"8"6Sr ratios of southern African ...

177

3D-nuclear heat generation in PCC-charcoal filter in TAPP-3 and 4

The Steam Generator (SG) serves as an interface between primary and secondary cycle in Pressurized Heavy Water Reactor (PHWR). Failure of steam generator tubes result in leaking of active heavy water in the secondary closed loop. In Tarapur Atomic Power Station-3 and 4 (TAPS- 3 and 4), Scintillator detectors are provided to detect on line heavy water leakages in SG and moderator heat exchangers by monitoring Nitrogen-16 ("1"6N) and Oxygen-19 ("1"90) activities. Efficacy of detection of these activities at designed detector position on SG blow down line in presence of background radiation field is analysed theoretically. The count rate of "1"9O and "1"6N estimated at the detector position inside Reactor Building (RB) shows that detectors only respond to very high leak rates due to presence of high background even though sensitivity is appreciably good. For detector position out side the RB containment, the travel time for the feed water becomes ...

2005-11-23

178

X-ray diffraction analysis of corrosion products of Fe-Ni-Cr alloys formed in molten nitrate salts

This paper deals with the calculations of 3D nuclear heat generation profile in the charcoal filter and subsequently the commencement time of Primary Containment Cleanup (PCC) system of 540MWe Pressurized Heavy Water Reactor (PHWR). Fuel failure is predicted due to overheating of the fuel under loss of Coolant Accident (LOCA) without Emergency Core Cooling System (LOCA without ECCS). Subsequently fission product gasses along with water vapours are released to Reactor Building (RB) atmosphere. Plate-out and water trapping mechanism stabilizes the concentration of significant fission products i.e. radioiodines in about 4 hours before being circulated through charcoal filters of Containment Cleanup system. After cleaning up the RB atmosphere, it is discharged to outside atmosphere through stack. The isotopes of radioiodine emit beta and gamma radiations. Gamma radiations are partly stopped within the charcoal and heat is generated. The part of ...

2006-11-13

179

The influence of yttrium (Y) on the corrosion of Mg-Y binary alloys

Chemical phase identifications of complex, multilayered corrosion products formed on Fe-Ni-Cr alloys immersed in molten NaNO/sub 3/-KNO/sub 3/ and LiNO/sub 3/-NaNO/sub 3/-KNO/sub 3/ were obtained by X-ray diffraction analysis. Diffraction analyses performed after successive material removal steps provided depth profiles of corrosion products and identified the dominant phases as NaFeO/sub 2/, Fe/sub 3/O/sub 4/, and Cr/sub 2/O/sub 3/ for Alloy 800 and 316SS after immersion in NaNO/sub 3/-KNO/sub 3/. In LiNO/sub 3/-NaNO/sub 3/-KNO/sub 3/, the major corrosion products identified on Alloy 800 were LiFeO/sub 2/, Fe/sub 3/O/sub 4/, and Cr/sub 2/O/sub 3/. X-ray diffraction results were supplemented by electron microprobe analyses that revealed the solid solution nature of several of the oxide phases.

1984-08-01

180

Investigation of texturization for crystalline silicon solar cells with sodium carbonate solutions

Research highlights: #-># The Y-intermetallic can accelerate corrosion and Y can increase the protectiveness of the surface layer. #-># In 0.1 M NaCl, the corrosion rate of Mg-Y alloys increased with increasing Y due to the Y intermetallic. #-># In 0.1 M NaCl, there was filiform corrosion. #-># In 0.1 M Na_2SO_4, the corrosion rate of Mg-Y alloys decreased with increasing Y in the range 3-7%Y. #-># Hydrogen evolution was observed from particular parts of the alloy surface. - Abstract: Corrosion of Mg-Y alloys was studied using electrochemical evaluations, immersion tests and direct observations. There were two important effects. In 0.1 M NaCl, the corrosion rate increased with increasing Y content due to increasing amounts of the Y-containing intermetallic. In 0.1 M Na_2SO_4, the corrosion rate decreased with increasing Y content above 3%, attributed to a more ...

2010-11-01

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181

Comparative study of seed germination and growth of Kochia prostrata and Kochia scoparia (Chenopodiaceae) under salinity

We investigate a new texturization technique for crystalline silicon solar cells with sodium carbonate (Na{sub 2}CO{sub 3}) solutions. We show the dependence of the hemispherical surface reflectance on solution temperature, the etching time and the Na{sub 2}CO{sub 3} concentration. Furthermore, we investigate what element in Na{sub 2}CO{sub 3} solution influences the texturing for reducing the texturing time. As a result of experiments, we find it possible to get low reflectance in a shorter texturing time by the addition of NaHCO{sub 3}. The size of texture becomes smaller by the addition of NaHCO{sub 3} but the etching rate does not change. We conclude carbonic ion and/or its compound seems to play an important role as the initiator of pyramidal structure. This texturing method is cost effective because there is no need of expensive IPA, and the surface reflectance is reduced ...

2000-04-01

182

British Library Electronic Table of Contents (United Kingdom)

Soils of arid regions of Central Asia contain salts of different types that may differentially affect seed germination and plant development. We studied effect of NaCl, Na2SO4, 2NaCl + KCl + CaCl2 and 2Na2SO4+K2SO4+MgSO4 on germination of Kochia prostrata and Kochia scoparia seeds under a range of concentrations from 0.5 to 5% and at two constant temperature regimes +22 degrees C and +6 degrees C. The observed salt tolerance limit of germination at constant temperature +22 degrees C for both species was 5-6%, while at low temperature (+6 degrees C) this limit was 2%. The salt tolerance of young plants (before flowering) was 3% for NaCl. Low concentrations of sulfuric and mixed salts had a stimulating effect on seed germination in K. prostrata. Despite similarity of salt-tolerance limits...

2011-01-01

183

Active packaging of ground beef patties by edible zein films incorporated with partially purified lysozyme and Na2EDTA

British Library Electronic Table of Contents (United Kingdom)

Summary In this study, antimicrobial activity of zein films incorporated with partially purified lysozyme and disodium ethylenediaminetetraacetic acid (Na2EDTA) has been tested on selected pathogenic bacteria and refrigerated ground beef patties. The developed films containing 700-g-cm-2 lysozyme and 300-g-cm-2 Na2EDTA showed antimicrobial activity on Listeria monocytogenes, Escherichia coli O157:H7, and Salmonella typhimurium. The application of lysozyme and Na2EDTA incorporated zein films on beef patties significantly decreased total viable counts (TVC) and total coliform counts after 5-days of storage compared to those of control patties (P-2EDTA or Na2EDTA alone significantly slowed down the oxidative changes in patties during storage (P-P-2EDTA for active packaging of refrigerated mea...

2011-01-01

184

X-ray photoelectron spectroscopy and x-ray excited Auger spectroscopy studies of manganese thiophosphate intercalated with sodium ions

Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB5O9

Polycrystalline powders of Na{sub 2x}Mn{sub 1-x}PS{sub 3} have been synthesized from layered MnPS{sub 3} material by successive ion-exchange intercalation of potassium and sodium ions. Their x-ray photoelectron spectroscopy (XPS) and x-ray excited Auger spectroscopy spectra have been measured at room temperature using Mg K{alpha} (1253.6 eV) x-ray source. In particular, the Mn, P, and S 2p and Na 1s and 2p core-level regions and the Na Auger KL{sub 23}L{sub 23} transition have been investigated. All the analyzed XPS core-level spectra display a single-peak structure, suggesting the absence of nonequivalent atoms of Na, Mn, P, and S. The manganese XPS spectrum shows, as observed in MnPS{sub 3} and in its cesium and potassium intercalation compounds, typical shake-up satellites, suggesting that the Mn-S bond is yet mainly ionic in nature. The comparison with the XPS spectra relative to MnPS{sub 3} and its ...

2008-12-15

185

The basic experiment on the high-temperature chemical reaction between sodium compound and iron-base material. Pt. 2. Structure observations

A novel sodium lead pentaborate, NaPbB5O9, has been successfully synthesized by standard solid-state reaction. The single-crystal X-ray structural analysis showed that NaPbB5O9 crystallizes in the monoclinic space group P21/c with a=6.5324(10) A, b=13.0234(2) A, c=8.5838(10) A, ?=104.971(10)o, and Z=4. The crystal structure is composed of double ring [B5O9]3- units, [PbO7] and [NaO7] polyhedra. [B5O9]3- groups connect with each other forming two-dimensional infinite ?[B5O9]3- layers, while [PbO7] and [NaO7] polyhedra are located between the layers. [PbO7] polyhedra linked together via corner-sharing O atom forming novel infinite ?[PbO6] chains along the c axis. The thermal behavior, IR spectrum and the optical diffuse reflectance spectrum of NaPbB5O9 were reported. -- Graphical abstract: A new phase, NaPbB5O9, has been discovered in the ternary M2O-PbO-B2O3 ...

2011-04-01

186

Survival of-Escherichia coli-O157:H7 in Meat Product Brines Containing Antimicrobials

This experiment is carried out in the series of the investigation on the damage mechanism of carbon steel. In this paper, the damage situation is considered by structure observations. The test were carried out in 600degC-1200degC temperature range, in blowing an argon gas. The reagents are Na{sub 2}O, Na{sub 2}O{sub 2} and NaOH. From structure observations, the holes are observed on the surface of iron-base material in some test conditions. This result is indicated that the selective reaction occurs. The selective reaction is more obvious as the time exposed to the high temperature is longer. It is considered that the selective reaction occurs after the chemical reaction between iron-base material and sodium compound. The areas, in which Mn-concentration is higher, are observed in products on the surface of specimen. (author)

1997-07-01

187

British Library Electronic Table of Contents (United Kingdom)

Abstract:- Brine solution injection of beef contaminated with-Escherichia coli-O157:H7 on its surface may lead to internalization of pathogen cells and/or cross-contamination of the brine, which when recirculated, may serve as a source of new product contamination. This study evaluated survival of-E. coli-O157:H7 in brines formulated without or with antimicrobials. The brines were formulated in sterile distilled water (simulating the composition of freshly prepared brines) or in a nonsterile 3% meat homogenate (simulating the composition of recirculating brines) at concentrations used to moisture-enhance meat to 110% of initial weight, as follows: sodium chloride (NaCl, 5.5%) + sodium tripolyphosphate (STP, 2.75%), NaCl + sodium pyrophosphate (2.75%), or NaCl + STP combined with potassium ...

2011-01-01

188

Selenium fractions in selenate-fertilized field soils of Finland

British Library Electronic Table of Contents (United Kingdom)

Depending on the soil environment, selenium (Se) can exist as several species differing greatly in bioavailability. Characterization of soil Se reserves is thus necessary in assessing the nutritional supply of this essential element. In low-Se areas, Se fertilization is an option for securing adequate Se nutrition. Fertilization is, however, challenged by the unknown fate of the residual Se. In this study, we aimed to clarify the Se status of selenate-fertilized field soils by fractionating soil Se into five pools: salt-soluble (KCl), adsorbed (KH2PO4/K2HPO4), organically associated (NaOH), elemental (Na2SO3) and recalcitrant Se (NaOCl). Changes induced in these fractions by repeated application of low selenate doses were examined by comparing samples collected from the same locations in 1...

2011-01-01

189

Pretreatment of empty palm fruit bunch for production of chemicals via catalytic pyrolysis

British Library Electronic Table of Contents (United Kingdom)

The effect of chemical pretreatments using NaOH, H2O2, and Ca(OH)2 on Empty Palm Fruit Bunches (EPFB) to degrade EPFB lignin before pyrolyis was investigated. Spectrophotometer analysis proved consecutive addition of NaOH and H2O2 decomposed almost 100% of EPFB lignin compared to 44% for the Ca(OH)2, H2O2 system while NaOH and Ca(OH)2 used exclusively could not alter lignin much. Next, the pretreated EPFB was catalytically pyrolyzed. Experimental results indicated the phenolic yields over Al-MCM-41 and HZSM-5 catalysts were 90wt% and 80wt%, respectively compared to 67wt% yield for the untreated sample under the same set of conditions. Meanwhile, the experiments with HY zeolite yielded 70wt% phenols.

2009-01-01

190

Ocular Burn: Rinsing and Healing with Ionic Marine Solutions and Vegetable Oils

British Library Electronic Table of Contents (United Kingdom)

Abstract Purpose: We investigated the effects of various rinsing and healing protocols on corneal wound repair and inflammation following alkali burn in rabbits. Methods: We conducted in vitro, in vivo and ex vivo studies. First, different rinse solutions were tested in vitro after incubation of ocular cells with methanol or NaOH. Cell viability was then assessed using the neutral red test (cytofluorometry). Second, NaOH was applied to rabbit corneas and associations of rinse solutions (NaCl 0.9% or controlled ionization marine solutions) with N-acetylcysteine or vegetable oils (from Calophyllum inophyllum and Aleurites moluccana) were tested in vivo. The regeneration of the corneal epithelium and the infiltration of inflammatory cells were evaluated using in vivo confocal microscopy and e...

2009-01-01

191

Inhibition effects on fermentation of hardwood extracted hemicelluloses by acetic acid and sodium

British Library Electronic Table of Contents (United Kingdom)

Extraction of hemicellulose from hardwood chips prior to pulping is a possible method for producing ethanol and acetic acid in an integrated forest bio-refinery, adding value to wood components normally relegated to boiler fuel. Hemicellulose was extracted from hardwood chips using green liquor, a pulping liquor intermediate consisting of aqueous NaOH, Na2CO3, and Na2S, at 160degreeC, held for 110min in a 20L rocking digester. The extracted liquor contained 3.7% solids and had a pH of 5.6. The organic content of the extracts was mainly xylo-oligosaccharides and acetic acid. Because it was dilute, the hemicellulose extract was concentrated by evaporation in a thin film evaporator. Concentrates from the evaporator reached levels of up to 10% solids. Inhibitors such as acetic acid and sodium ...

2010-01-01

192

Experimental study on simultaneous desulfurization and denitrification from flue gas with composite absorbent

British Library Electronic Table of Contents (United Kingdom)

Abstract The characteristics of desulfurization and denitrification with composite absorbent were researched through aqueous absorption experiments. The removal efficiencies of SO2 and NO were up to 100 and 95%, respectively. The composite absorbent included NaClO2 and component M. Existence of component M in the solution could reduce the absorbent cost compared with using sodium chlorite alone. Chlorine dioxide, as main reaction intermediate product, participated in oxidation reaction. The optimal experimental conditions involved NaClO2 concentration of1.13 mmol/L, solution pH of 5.5, molar ratio (M/NaClO2) of 4.1, reaction temperature of 323 K. The optimal solution pH and reaction temperature were both in the required ranges of limestone-gypsum wet flue gas desulfurization (FGD) process....

2011-01-01

193

Estimation of thermodynamic properties of the ternary molten salt system, LiF-NaF-BeF2, by the modified Peng-Robinson equation

British Library Electronic Table of Contents (United Kingdom)

The molten salt reactor (MSR), which is one of the generation IV reactors, can meet the demand of transmutation and breeding. The thermodynamic properties of the molten salt system like LiF-NaF-BeF2 influence the design and construction of the fuel salt and coolant in the MSR for the new generation. In this paper, the equation of state of the ternary system 15%LiF-58%NaF-27%BeF2, over the temperature range from 873.15 to 1 073.15 K at one atmosphere pressure, is described using a modified Peng-Robinson (PR) equation. The densities of the ternary system and its components are estimated by this equation directly, and compared with the experimental data. Based on the equation of state, the other thermodynamic properties such as the enthalpy, entropy and heat capacity at constant pressure are ...

2007-01-01

194

Determination of Ca, Cr, Cu, Fe, K, Mg, Na and Zn in Brazilian medicinal plants by neutron activation and atomic absorption; Determinacao de Ca, Cr, Cu, Fe, K, Mg, Na e Zn em plantas medicinais brasileiras por ativacao neutronica e absorcao atomica

Towards hyperpolarized ¹³C-succinate imaging of brain cancer

Medicinal plants are available in the markets in Belo Horizonte, Minas Gerais. The objective of this work is to investigate the Ca, Cr, Cu, Fe, K, Mg, Na e Zn concentrations in two lots of usually known diuretics plants (azeitona do mato, cabelo de milho, cavalinha, cervejinha do campo, chapeu de couro, congonha de bugre, marmelinho do campo and quebra pedra) bought with an interval of time - six months - between the purchases. The elemental concentrations were determined applying k{sub 0} instrumental neutron activation analysis and atomic absorption spectrophotometry analysis. (author)

2002-07-01

195

The seeded growth of calcium sulfate dihydrate crystals in NaCl solutions up to 6 m and 90 C

We describe a novel ¹³C enriched precursor molecule, sodium 1-¹³C acetylenedicarboxylate, which after hydrogenation by PASADE-NA (Parahydrogen and Synthesis Allows Dramatically...Full Text Available

2007-05-01

196

The Complex Interstellar Na I Absorption toward h and Chi Persei

The kinetics of calcium sulfate crystal growth is of importance in various fields, such as geochemistry, desalination technology, petroleum industry, and water and wastewater treatment. The seeded crystal growth rate of calcium sulfate dihydrate was measured as a function of supersaturation in NaCl electrolyte solutions from 0 to 6 m at temperatures of 25, 50, 70, and 90 C. The growth followed a second-order parabolic rate law with activation energies greater than 53 kJ/mol which suggested the surface reaction as the rate-limiting step. It was observed that the rate constant and the activation energy are solution composition dependent. The rate constant increases with NaCl concentration up to 3 molal and then begins to fall slightly. The activation energy dropped from 61 kJ/mol in the pure Ca-SO[sub 4]H[sub 2]O system to 53 kJ/mol in 3.0 m NaCl solutions. The electrolyte effect was similar to the crystal solubility behavior ...

1994-03-15

197

Synthesis of (Bi0.5Na0.5)TiO3 (BNT) and Pr doped BNT using the soft combustion technique and its properties

Recent high spatial and spectral resolution investigations of the diffuse interstellar medium (ISM) have found significant evidence for small-scale variations in the interstellar gas on scales less than or equal to 1 pc. To better understand the nature of small-scale variations in the ISM, we have used the KPNO WIYN Hydra multi-object spectrograph, which has a mapping advantage over the single-axis, single-scale limitations of studies using high proper motion stars and binary stars, to obtain moderate resolution (~12 km/s) interstellar Na I D absorption spectra of 172 stars toward the double open cluster h and Chi Persei. All of the sightlines toward the 150 stars with spectra that reveal absorption from the Perseus spiral arm show different interstellar Na I D absorption profiles in the Perseus arm gas. Additionally, we have utilized the KPNO Coude Feed spectrograph to obtain high-resolution (~3 km/s) interstellar Na I D ...

2004-01-01

198

British Library Electronic Table of Contents (United Kingdom)

In this work, bismuth sodium titanate (Bi0.5Na0.5)TiO3 (BNT) and praseodymium (Pr)-doped BNT were successfully produced using the soft combustion technique. The effects of Pr doping on stoichiometry, microstructure, density and dielectric properties were studied. Pure Pr-doped BNT was obtained in all samples containing 5, 10 and 20mol% Pr after calcination at 800^oC for 3h. The produced powders were then pressed into pellets and sintered at 1100^oC for 3h. The very similar ionic radii of Pr^3^+ with Bi^3^+ and Na^+ made it possible to substitute both Bi and Na. The crystallite size and grain size decreased with increasing Pr amount because Pr acted as grain growth inhibitor, both for calcined powders and for sintered pellets. Maximum density was obtained in 5mol% Pr-doped BNT, beyond which...

2011-01-01

199

Study on performance of colloidal mixtures consisted of stearic acid and Na{sub 2}HPO{sub 4}.12H{sub 2}O for use as phase change materials of thermal energy storage

Stress corrosion cracking in high-purity water of 3-31/2% NiCrMoV low-alloy steels for steam turbine disks and rotors. Pt. 1

The thermal energy storage performance and phase change stability of mix phase change materials consisted of stearic acid and Na{sub 2}PO{sub 4}.12H{sub 2}O are studied by means of Fourier transformation infrared spectrum analyses (FTIR) and Differential Scanning Calorimetry (DSC). The specific heat capacity of mix materials is also determined experimentally. The results show that all absorption peaks of functional groups and chemical bonds of stearic acid still exist, which suggests that these crystal materials composed of stearic acid and Na{sub 2}PO{sub 4}.12H{sub 2}O have good phase change stability and chemical compatibility. Thus, disadvantages caused by the subcooling of Na{sub 2}PO{sub 4}.H{sub 2}O and the low specific heat capacity of stearic acid can be solved, it is speculated that complement each other on the basis of organic/inorganic characteristics in itself is carried out for these two component materials of ...

2010-07-15

200

Polyphenols in the active fraction of needle-prick (Dasyphyllum brasiliense, Asteraceae), a medicinal plant with antiinflammatory activity; Polifenois na fracao ativa de espinho-agulha (Dasyphyllum brasiliense, Asteraceae), uma planta medicinal com atividade antiinflamatoria

In recent years intergranular stress corrosion cracking has occurred world-wide in the shrink-fitted discs of low pressure turbine rotors made of low alloy steels. Only in a few cases steam impurities such as NaOH, Na_2CO_3, Na_2SO_4, H_2S or NaCl, which initiate SCC, could be found. To clarify the SCC-behaviour experiments on turbine disc steels with different chemical compositions and yield strength were performed in high purity water. The results show, that chemical composition has no effect on the crack initiation. Under high purity water conditions no crack initiation due to stress corrosion cracking is observed on the steel with a yield strength of 850 N/mm"2. On the steel with a yield strength of 1250 N/mm"2 which is not used in service, crack initiation occurs in pure water. But if sharp cracks already exist, crack propagation occurs in both cases. The investigations showed, that stress ...

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201

Micropolarities of lipid bilayers and micelles. 3. Effect of monovalent ions on the dielectric constant of the water-membrane interface of unilamellar phosphatidylcholine vesicles

No abstract prepared.

2008-07-01

202

Measurement of a continuous curve for alpha particles stopping power in aluminium at the Bragg peak region; Medida de uma curva continua do poder de freamento de particulas alfa em Al na regiao do pico de Bragg

A study was undertaken of the effect of monovalent cations (Li/sup +/, Na/sup +/, K/sup +/) on the dielectric constant (epsilon) of the water-lipid interface of unilamellar phosphatidylcholine (PC) vesicles, i.e., the ester carbonyl oxygen region of the PC molecules or the neighborhood of the oxygen atoms of the phosphorylcholine moiety. epsilon was determined by reacting the free radical 1,1-diphenyl-2-picrylhydrazyl with ..cap alpha..-tocopherol incorporated in the lipid vesicles. The results are consistent with a decrease of epsilon (LiCl: 35.5 to 29.5; NaCl: 34 to 29; KCl: 33 to 29) as the concentration of the salts in the solvent media increases from 0.025 to 0.5 M. These effects can be rationalized in terms of dielectric saturation at the water-lipid interface brought about by ion-induced local electric fields. In the unilamellar PC vesicles the effect of the ions on epsilon follows the sequence K/sup +/ > Na/sup ...

1986-02-27

203

Intelligent techniques applied in identifying fraudsters industrial consumers of electricity; Tecnicas inteligentes aplicadas na identificacao de consumidores industriais fraudadores de energia eletrica

No abstract prepared.

2008-07-01

204

Influence of tensile relief heat treatment on soldering metals crack strength obtained by tube wire soldering; Influencia do tratamento termico de alivio de tensoes na tenacidade a fratura de metais de solda obtidos por soldagem com arame tubular

The development of a computational intelligent tools based on neural network to identify commercial losses or fraud (theft energy), considering information from a database electric utility, is presented.

2009-07-01

205

Identification of triterpene saponine separated from Potentilla erecta (L.) rhizome on the base of {sup 13}C NMR spectra analysis; Identyfikacjie saponin triterpenowych wyizolowanych z klacza Potentilla Erecta (L.) na podstawie analizy {sup 13}C - NMR

Short communication

1993-12-31

206

Effects of the purple cashew tree lectin on the Tc-99 m labelled adipocyte cells; Efeito da lectina da entrecasca do cajueiro roxo na marcacao de celulas adipocitas com tecnecio-99m

No abstract prepared

1995-12-31

207

Effects of ouabain on isolated cerebral and femoral arteries of the cat: a functional and biochemical study.

No abstract prepared.

1999-07-01

208

Effect of gamma-rays on spirochaetes of the species Borrelia anserina, Sakharoff, 1891. Part 2. Changes in the antigenic structure

1. This study analyzes the mechanisms involved in the responses to ouabain in cat cerebral and femoral arteries and characterizes the electrogenic Na+ pump present in these vessels. The latter was accomplished...Full Text Available

1988-01-01

209

Dimeric subunit stoichiometry of the human voltage-dependent proton channel Hv1

Bulgarian ... Orig. Title Vliyanie na gama-lychite vyrkhu spirokheti ot vida Borrelia anserina, Sakharoff, 1891. Chast 2. Promeni v antigenniya stroezh.

210

Cyclopropane isomerization over Eu[sup 3+]NaX zeolites

In voltage-gated Na⁺, K⁺, and Ca²⁺ channels, four voltage-sensor domains operate on a central pore domain in response to membrane voltage. In contrast, the voltage-gated...Full Text Available

2008-06-03

211

Comparison of LaBr_3:Ce and NaI(Tl) Scintillators for Radio-Isotope Identification Devices

Cyclopropane isomerization to propylene over various Eu[sup 3+] loadings in NaX zeolite have been studied by measurements of steady-state and transient kinetics and by Fourier transform infrared spectroscopy. As Eu[sup 3+] loading increases, the rate of deactivation increases, the conversion increases, apparent activation energies are lowered, and Bronsted acid site strength and amounts increase. Apparent activation energies of 13-15 kcal/mol for propylene formation have been observed for these systems, consistent with literature reports for other metal supported heterogeneous catalyst systems. Deactivation studies have shown that activity can be restored by heating in He at 380[degrees]C between various temperature runs, and that gases desorbed during regeneration are predominantly propylene. Poisoning studies of Bronsted sites with Na vapor lead to deactivation of these catalysts. A reaction mechanism scheme based on [pi] allyl intermediates ...

1992-11-01

212

Catabolite Repression of the Citrate Fermentation Genes in Klebsiella pneumoniae: Evidence for Involvement of the Cyclic AMP Receptor Protein

Lanthanum halide (LaBr_3:Ce) scintillators offer significantly better resolution (< 3% at 662 keV) relative to NaI(Tl) and have recently become commercially available in sizes large enough for the handheld, Radio-Isotope Identification Device (RIID) market. Drawbacks to lanthanum halide detectors, however, include internal radioactivity contributing to spectral counts, and a low-energy response which can cause detector resolution to be worse than that of NaI(Tl) below 100 keV. To study the potential of this new material for RIIDs we performed a series of measurements comparing a 1.5 x 1.5-inch LaBr_3:Ce detector with an Exploranium GR-135 RIID, which contains a 1.5 x 2.2-inch NaI(Tl) detector. Measurements were taken for short timeframes, as typifies RIID usage. Measurements included examples of naturally occurring radioactive material (NORM), typically found in cargo, and special nuclear materials. Some measurements ...

2005-10-23

213

An analytic representation of the radial distribution of dose from energetic heavy ions in water, Si, LiF, and NaI

Klebsiella pneumoniae is able to grow anaerobically with citrate as a sole carbon and energy source by a fermentative pathway involving the Na⁺-dependent citrate...Full Text Available

2001-09-01

214

Performance of the gas bubble column in molten salt systems

An earlier representation of the radial distribution of dose about the path of a heavy ion in liquid water is modified and extended to include silicon, lithium fluoride, and sodium iodide. 6 refs., 5 figs., 1 tab.

1989-09-01

215

27na4

Wastenet

by American scientists, ecosystems containing a greater number of plant species, produce more biomass.This result ...to meet the increasing demand for land for farmland planted with monocultures, buildings and roads.For ...have hypothesized that greater ecological diversity (diversity of plant and animal species) leads to a greater

216

Electric power production from the biogas resulting of the sewer treatment: pilot project of the Sewer Treatment Station (ETE) in the Barueri city in the Great Sao Paulo; Producao de energia eletrica a partir do biogas resultante do tratamento de esgoto: projeto piloto na E.T.E. de Barueri na Grande Sao Paulo

Experimental data on the gas holdup and the mean bubble size in a bubble column with a single nozzle was obtained for gas-molten salt systems of a eutectic mixture of LiCl (58 mol %)-KCl (42 mol %) and molten NaNO/sub 3/. The liquid-phase mass transfer coefficient K /SUB L/ was evaluated from the specific surface area a and the volumetric coefficient K /SUB L/ a data for oxygen and carbon dioxide absorption into molten NaNO/sub 3/. The dimensionless correlations of the performance of bubble columns for aqueous solutions can be extended to the gas-molten salt systems.

1984-01-01

217

The interaction of Np(V), Pu(VI) and Tc(VII) with metal in alkaline solutions

This paper describes a system for biogas conversion to electric power and heat by using a micro turbine and three Otto cycle engines. The benefit of the energy from a treatment process residue aims the improvement of the global performance of the system, reducing the the emission of the greenhouse gases and contributing to the global energetic efficiency of the sewage treatment station and the basic sanitation in Brazil.

2002-07-01

218

Radioiodination of 3-quinuclidinyl benzilate using a no-carrier-added concentration of iodine-125/sodium-iodine

The interaction of Np(V), Pu(VI) and Tc(VII) with metal reductants Zn, Cr, Sn and their alloys was investigated in 0.5-4 mol l"-"1 NaOH solutions in static and dynamic conditions (by filtration of solutions through the column filled with grains of metal). In this paper, it was found that the reduction and succeeding precipitation hydroxides of these elements, on the surface of metal grains from 0.5 to 4 mol l"-"1 NaOH solutions, gives a decontamination factor (DF) from 1.1 to 67. The best result was achieved for Pu (DF=67) on Cr grains after 2.5 h contact at 60 C with 0.5 mol l"-"1 NaOH solution containing Pu(VI). Increasing the NaOH concentration, and the addition of chromate ions and complex-forming agents to alkaline solution results in a decrease of the decontamination factor (DF). A better result for Np sorption from 1 mol l"-"1 NaOH solutions was achieved after longer contact, ...

1998-06-12

219

Rb-Sr isotopic studies on granodioritic rocks from the Mecsek mountains, Hungary

3-Quinuclidinyl benzilate (QNB) is a potent muscarinic antagonist that binds to muscarinic acetylcholine receptors. Iodination of QNB is difficult because it contains rings that are deactivated, while phenol rings are activated. The purpose of this research is to develop an appropriate method for the iodination of QNB at no-carrier-added concentrations of /sup 125/I/NaI. Phenol was chose as the test compound for direct iodination by adding chloramine T and nonradioactive sodium iodide to the phenol in a phosphate buffer and methanol system. A simple method to radioiodinate QNB at several concentrations was developed in situ in the presence of QNB, thallic trifluoroacetate /sup 125/I/NaI, /sup 127/I/NaI, and aluminium chloride. Using milligram amounts of QNB (7.12 x 10/sup -6/ moles), three reaction steps were involved: QNB was reacted with thallic trifluoroacetate at 60/sup 0/C for 24 hours, then radioactive /sup ...

1986-01-01

220

Rapid and cost-effective assessment of connectivity among assemblages of Choerodon rubescens (Labridae), using laser ablation ICP-MS of sagittal otoliths

New isotopic age determinations carried out with the rubidium-strontium method on granodioritic basement rocks from the Mecsek Mountains in Southeastern Transdanubia give further support to assumptions on a polyphase development of the Mecsek crystalline. As shown by initial Sr isotopic ratios, the protolith of the granodioritic assemblage of polymetamorphic-anatectic origin must have been strongly basic in its composition. The scatter of individual model ages obtained on total rock samples reflects the polymetamorphic-polytectonized character of the basement, and suggests that following a primary granitization process secondary events might have led to the total or partial recrystallization of the rocks in question. The tectonic development of the basement crystalline as reflected in the isotopic age data closed at about 270+-20 million years ago, with processes causing retrograde changes in the crystalline as a whole but leading to the development of dyke rocks in the tectonically ...

1981-01-01

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221

British Library Electronic Table of Contents (United Kingdom)

A rapid and cost-effective assessment was required to provide advice to management on the connectivity between juvenile and adult life cycle stages of Baldchin Groper Choerodon rubescens, a labrid endemic to the west coast of Australia, which has high social value, but relatively low commercial fishery importance. To minimise costs we used laser ablation ICP-MS to analyse levels of a small suite of elements (Ca, Mg, Mn, Cu, Zn, Sr, Rb, Ba and Pb) at the margin (adult phase) and core (juvenile phase) of the same otoliths of adult C. rubescens, collected at ten locations in five management zones. The elemental composition of both otolith margins and cores differed significantly among management zones and in some cases among locations within zones. Similarity of the pattern of among-zone elem...

2011-01-01

222

Proterozoic kimberlites and lamproites and a preliminary age for the Argyle lamproite pipe, Western Australia

Production of plutonium, yttrium and strontium tracers for using in environmental research

The Argyle pipe occurring in the East Kimberley Province of Western Australia is a unique, highly-diamondiferous lamproite. Although it resembles other lamproites located in the West Kimberley Province with respect to its setting, structure, petrography and geochemistry, it is probably Proterozoic in age and hence substantially older than Tertiary occurrences of the West Kimberley Province. Rb-Sr measurements on whole rock and phlogopite samples from magmatic olivine-phlogopite lamproite, reveals a two point model age of 1126 +- 9 Ma for the Argyle pipe. This age is consistent with ages of other, similar volcanic igneous rocks occurring in several localities worldwide. The widespread occurrence of Proterozoic kimberlites and lamproites suggests that this was an important period of worldwide alkalic intrusive activity.

223

Macro-Cellular Silicon carbide Reactors for Nonstationary Combustion Under Piston Engine-Like Conditions

Summary of cyclotron production methods of "2"3"7Pu (45,2 d), "8"8Y (106,65 d) and "8"5Sr (64,84 d) tracers via nuclear reactions with protons and alphas on "2"3"5U, "8"8Sr and "8"5Rb targets in wide energy range is given. Chemical methods of separation and purification of the tracers from the irradiated uranium, strontium and rubidium targets are described. The tracers were used for determination of Pu (239-240), Sr-90 and Am-241 in the samples (soil, plants, underground waters) from Semipalatinsk Test Site. Obtained results are discussed.

2001-12-12

224

British Library Electronic Table of Contents (United Kingdom)

Strut lattice structures of reaction-bonded silicon infiltrated silicon carbide ceramics (RB-SiSiC) for air-fuel mixture formation and for nonstationary lean-burn under pressure applications were fabricated. The lattice design with a high porosity >80% was shaped by indirect three-dimensional printing. It was shown that pre-ignition processes in the porous reactor are much faster than in a free combustion, especially at lower temperatures. Interaction of high velocity diesel jets with cylindrical strut ligaments of the SiSiC lattice structure offers a new possibility for quick and efficient fuel distribution (multi-jet splitting) in space.

2011-01-01

225

K-shell x-ray production cross sections of selected elements from Ti to Y for 0.5- to 2.5-MeV alpha-particle bombardment

Determination of ratios of emission probabilities of Auger electrons and K-L-shell radiative vacancy transfer probabilities for 17 elements from Mn to Mo at 59.5keV

K-shell x-ray production cross sections and K#beta#/K#alpha# ratios have been measured for thin targets of Ti, V, Cr, Fe, Ni, Cu, Zn, Ga, As, Se, Rb, Sr, and Y for 0.5- to 2.5-MeV alpha particles. The experimental values are compared to the nonrelativistic plane-wave Born approximation (PWBA), the binary-encounter approximation, and the PWBA with binding energy and Coulomb deflection corrections. The PWBA with corrections provides the best agreement with the experimental cross sections.

226

Demonstrating coherent control in 85Rb2 using ultrafast laser pulses: a theoretical outline of two experiments

The measurements of the K X-ray intensity ratio I(K{sub {beta}})/I(K{sub {alpha}}) for the 17 elements Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Se, Br, Rb, Sr, Y, Zr, Nb and Mo have been done following ionization by 59.5keV {gamma}-rays from a {sup 241}Am point source. Ratios of emission probabilities of Auger electrons and the vacancy transfer coefficients have been extracted in terms of the intensity ratios. It is found that the present results agree well with earlier fitted values and the semi-empirical values.

2006-01-15

227

Cytoplasmic p63 immunohistochemistry is a useful marker for muscle differentiation: an immunohistochemical and immunoelectron microscopic study

Calculations relating to two experiments that demonstrate coherent control of preformed rubidium-85 molecules in a magneto-optical trap using ultrafast laser pulses are presented. In the first experiment, it is shown that pre-associated molecules in an incoherent mixture of states can be made to oscillate coherently using a single ultrafast pulse. A novel mechanism that can transfer molecular population to more deeply bound vibrational levels is used in the second. Optimal parameters of the control pulse are presented for the application of the mechanism to molecules in a magneto-optical trap. The calculations make use of an experimental determination of the initial state of molecules photoassociated by the trapping lasers in the magneto-optical trap and use shaped pulses consistent with a standard ultrafast laser system.

2009-01-01

228

British Library Electronic Table of Contents (United Kingdom)

TP63, a member of the TP53 gene family, is a nuclear marker of myoepithelial cells. Antibody against p63 is frequently used to aid in the diagnosis of prostate carcinoma, as well as in the identification of myoepithelial cells in other tissues including the breast. p63 is also a marker for squamous cell carcinoma. Recently, it was found that all p53 family members are involved in regulating the process of muscle differentiation through the retinoblastoma (RB) protein. Ablation of these p53 family functions blocks the differentiation program and promotes malignant transformation by enabling cooperating oncogenes to transform myoblasts. We therefore studied p63 expression in a number of neoplasms with myogenic differentiation. Immunohistochemical staining for p63 was performed on paraffin se...

2011-01-01

229

The comparative uptake and interaction of several radionuclides in the trophic levels surrounding the Los Alamos Meson Physics Facility (LAMPF) waste water ponds

The comparative uptake and interaction of several radionuclides in the trophic levels surrounding the Los Alamos Meson Physics Facility (LAMPF) waste water ponds

A study was undertaken to examine the uptake, distribution, and interaction of five activation products (Co-57, Be-7, Cs-134, Rb-83, and Mn-54) within the biotic and abiotic components surrounding the waste treatment lagoons of the Los Alamos Meson Physics Facility (LAMPF). The study attempted to ascertain where, and what specific interactions were taking place among the isotopes and the biotic/abiotic components. A statistical approach, utilizing Multivariate Analysis of Variance (MANOVA), was conducted testing the radioisotopic concentrations by (1) the trophic levels (TROPLVL) in each position sampled on the grid, (2) where sampled on the grid (TRAN), (3) where sampled with-in each grid line (PLOT), and (4) the side with which sampled (SIDE). This provided both the dependent and independent variables that would be tested. The Null Hypothesis (Ho) tested the difference in the mean values of the isotopes within/between each of the four independent variables. The ...

1983-05-01

230

Wetland treatment of oil and gas well wastewaters. Quarterly technical report, May 25, 1993-August 24, 1993

A study was undertaken to examine the uptake, distribution, and interaction of five activation products (Co-57, Be-7, Cs-134, Rb-83, and Mn-54) within the biotic and abiotic components surrounding the waste treatment lagoons of the Los Alamos Meson Physics Facility (LAMPF). The study attempted to ascertain where, and what specific interactions were taking place among the isotopes and the biotic/abiotic components. A statistical approach, utilizing Multivariate Analysis of Variance (MANOVA), was conducted testing the radioisotopic concentrations by (1) the trophic levels (TROPLVL) in each position sampled on the grid, (2) where sampled on the grid (TRAN), (3) where sampled with-in each grid line (PLOT), and (4) the side with which sampled (SIDE). This provided both the dependent and independent variables that would be tested. The Null Hypothesis (Ho) tested the difference in the mean values of the isotopes within/between each of the four independent variables. The ...

1989-08-01

231

Internalized insulin-receptor complexes are unidirectionally translocated to chloroquine-sensitive degradative sites. Dependence on metabolic energy

In the third quarterly report adsorption of heavy metals ions such as Cu(II) and Cr(VI) onto soils drawn from the laboratory-type wetland was shown to be weak. Secondly, it was shown that modified-clays did adsorb Cr(VI) ions strongly at pH 4.5. Further, studies on the pH dependence of the adsorption of {beta}-naphthoic acid, (NA), a well-documented contaminant in many oil and gas well waste waters onto modified-clays were undertaken and it was shown that uptake of NA by modified-clays was of the high affinity type at pH 4.5 and 7.0, but weak at pH 9.0. Adsorption of heavy metal ions, Cu{sup 2+}, and Cr(VI) onto algae, a proposed wetland amendment, was carried out and the results were presented and discussed in the fourth quarterly report. Uptake of NA by the soil component of the laboratory-type wetland was monitored as a function of pH. This quarterly report presents results from studies on the uptake of phenol and ...

1993-10-04

232

Enhanced Activity of Nanocrystalline Zeolites for Selective Catalytic Reduction of NOx

Insulin receptors on the surface of isolated rat adipocytes were photoaffinity labeled at 12 degrees C with the iodinated photoreactive insulin analogue, 125I-B2 (2-nitro-4-azidophenylacetyl)-des-PheB1-insulin, and the pathways in the intracellular processing of the labeled receptors were studied at 37 degrees C. During 37 degrees C incubations, the labeled 440-kDa insulin receptors were continuously internalized (as assessed by trypsin inaccessibility) and degraded such that up to 50% of the initially labeled receptors were lost by 120 min. Metabolic poisons (0.125-0.75 mM 2,4-dinitrophenol (DNP) and 1-10 mM NaF), which led to dose-dependent depletion of adipocyte ATP pools, inhibited receptor loss, and caused up to 3-fold increase in intracellular receptor accumulation. This effect was due to inhibition of intracellular receptor degradation, and there was no apparent effect of the metabolic poisons on initial internalization of the receptors. Following maximal ...

1988-04-25

233

Effect of chlorides on the corrosion behaviour of mild steel

Nanocrystalline zeolites with discrete crystal sizes of less than 100 nm have different properties relative to zeolites with larger crystal sizes. Nanocrystalline zeolites have improved mass transfer properties and very large internal and external surface areas that can be exploited for many different applications. The additional external surface active sites and the improved mass transfer properties of nanocrystalline zeolites offer significant advantages for selective catalytic reduction (SCR) catalysis with ammonia as a reductant in coal-fired power plants relative to current zeolite based SCR catalysts. Nanocrystalline NaY was synthesized with a crystal size of 15-20 nm and was thoroughly characterized using x-ray diffraction, electron paramagnetic resonance spectroscopy, nitrogen adsorption isotherms and Fourier Transform Infrared (FT-IR) spectroscopy. Copper ions were exchanged into nanocrystalline NaY to increase the catalytic activity. ...

2006-12-31

234

Dual radiotracer measurement of zoobenthos-mediated solute and particle transport in freshwater sediments

In PWR's steam generators, ''denting'' resulted from corrosion of support plate material, carbon steel is an important problem. The role of chlorides in corrosion acceleration of mild steel was studied. Corrosion tests were conducted at temperature from 100"0C to 280"0C in deaerated solutions of NaCl and MgCl_2 which are main content of sea water. 1) Solution of MgCl_2 was more corrosive than that of NaCl. The more increased in concentration of each chloride solution, the more corrosive in MgCl_2 soln. but the less corrosive in NaCl soln. 2) The rate of corrosion in the mixed solution of NaCl and MgCl_2 was governed by the concentration of MgCl_2 soln. The corrosion behaviour in sea water was suggested to be not controlled by NaCl but by MgCl_2. 3) Acidification of MgCl_2 soln. could be evaluated by experiment at 100"0C, the degree of acidification increased with increasing the ...

235

Dose and temporary characteristics of the changes in the amount of nucleic acids in leucocytes of irradiated rats

#gamma# spectroscopy methods have been applied to determine the effects of two freshwater benthic macroinvertebrates, on reworking of sediments and the transfer of solutes across the sediment-water interface. Natural lake sediments and overlying water were contained in temperature-regulated rectangular plastic cells. After addition of Stylodrilus (oligochaete worms) and Pontoporeia (crustacean amphipods) to these microcosms, the vertical distribution of Cs-137 (a tracer of particle transport) and Na-22 (a tracer of solute transport) were determined. In cells with Stylodrilus, the Cs-137 layer moved downward at a rate that decreased exponentially with time. In cells with Pontoporeia, Cs-137 activity was smeared downward in time owing to eddy diffusive mixing of sediments over a small range (1-2 cm). In cells without worms, the veneer of Cs active material remained at the interface while the penetration of Na-22 into sediments was consistent with ...

236

T=(5/2) "2"7Na from "1"4C+"1"4C, and the N=16 shell gap

An attempt was made for early quantitative assessment of the severety of an injury, using the nuclear acids (NA) content as a biochemical indicator. Sexually mature male rats with body mass 160-180 g were irradiated with doses 0.5, 1, 2, 4 and 8 Gy of "1"3"7Cs source. Uneven irradiation was achieved by shielding the abdominal-lumbar area with lead rings, measuring 2,5/50 mm. A 28-30% fall of the dose beneath the shielded zone was thus provided. Dose-dependent quantitative changes in Na content were determined on hours 24 and 72 within the range from 0.5 to 8 Gy and followed up until day 30 after irradiation with nonlethal (2 Gy) and lethal (8 Gy) doses. The total NA content in the leucocytes was determined by the method of Kritski and Aleksandrov. The uneven irradiation of rats within the 0,5-8 Gy range induced early dose-dependent changes in NA content. The nature of their post-irradiation dynamics ...

237

Support effects on CO hydrogenation over Ru/zeolite catalysts

For the first time a comprehensive level and decay scheme has been obtained for a T=(5/2) nucleus in the s-d shell ("2"7Na) by using a radioactive beam and target. Particle-#gamma# and p-#gamma#-#gamma# coincidences were measured following the "1"4C("1"4C,p#gamma#)"2"7Na reaction at E_l_a_b=22 MeV. The results do not support an inversion of the 2s_1_/_2 and 1d_5_/_2 orbitals, as previously proposed for T_z#>=#3, but they do suggest an increased N=16 gap between the 2s_1_/_2 and 1d_3_/_2 orbitals due to the neutron excess. A consistent interpretation of the level scheme in terms of the s-d shell model using the USD Hamiltonian is possible below 4 MeV, but differences increase at higher excitation energies. Another interpretation is that the influences of both the p_1_/_2 and f_7_/_2 intruder orbitals increase simultaneously with increasing T, an effect not included in the USD Hamiltonian.

2002-05-01

238

Relaxor or classical ferroelectric behaviour in ceramics with composition Ba{sub 1-x}Na{sub x}Ti{sub 1-x}Nb{sub x}O{sub 3}

Hydrogenation of carbon monoxide at 101.3 kPa has been studied over a series of ion-exchanged Ru catalysts supported on NaX, NaY, KL, Na mordenite, and HY zeolites. The type of zeolite had pronounced effects on the activity and selectivity of the Ru. The specific activity would appear to be related to the dispersion of reduced ruthenium in the zeolite. Methane selectivity, however, seems to be strongly influenced by the type and concentration of alkali cations remaining in the ion-exchanged zeolite. These cations appear to promote chain growth much as traditional alkali promoters would, though perhaps more indirectly. Due to bifunctional properties of the zeolite-supported catalysts, a significant fraction of C/sub 4/ was in the form of isobutane. Formation of isobutane seems to be related to either the Si/Al ratio in the zeolites or the concentration of the remaining alkali cations, but not to the OH concentration. In ...

1984-02-01

239

Piezoelectric Properties of (1-x)(Na0.5K0.5)NbO3-xAgSbO3 Lead-Free Ceramics

Ceramics with composition Ba{sub 1-x}Na{sub x}Ti{sub 1-x}Nb{sub x}O{sub 3} are of either classical ferroelectric (for 0{<=}x<0.075) and ferro- or antiferroelectric (for 0.55<x{<=}1) or relaxor ferroelectric type (for 0.075{<=}x{<=}0.55), the transition at T{sub c} being only diffuse without any frequency dispersion for this last region. All the corresponding dielectric characteristics, i.e. diffusivity of the ferroelectric-paraelectric transition, frequency dispersion of {epsilon}{sub r}', shift of T{sub m} with frequency deviation from the Curie-Weiss law, are determined. The relaxor behaviour is more relaxor the more the composition deviates from BaTiO{sub 3} and NaNbO{sub 3}. This study is in the field of preparation of relaxor ceramics free from lead in the interest of the environment, which present a transition temperature close to room temperature. (author)

2000-07-10

240

British Library Electronic Table of Contents (United Kingdom)

(1-x)(Na0.5K0.5)NbO3-xAgSbO3 lead-free piezoelectric ceramics were prepared by normal sintering. The effects of the AgSbO3 on the phase structure and piezoelectric properties of the ceramics were systematically studied. These results show that the AgSbO3-modified (K0.50Na0.50)NbO3 lead-free piezoelectric ceramics form stable solution with orthorhombic structure, and the Curie temperature and the polymorphic phase transition of the ceramics decreased with increasing AgSbO3. The result shows that the piezoelectric properties of the ceramics strongly depend on the AgSbO3. The ceramics with x=0.05 possess optimum properties (d33=192 pC/N, kp=43%, Tc=348degreeC, To-t=145degreeC, ?r632, and tan d3.5%). These results indicate that the ceramic is a promising candidate material for lead-free piezoe...

2009-01-01

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241

Optical properties of rare earth sodium double molybdates Na[sub 5]RE(MoO[sub 4])[sub 4], RE=Pr, Nd, Eu

Evaluation of static thermophysical properties of the ternary molten salt system Li, Na and Be/F based on the modified Peng-Robinson equation

Absorption and emission measurements at liquid-helium temperature, liquid-nitrogen temperature and room temperature have been performed on tetragonal scheelite-type rare earth sodium double molybdates Na[sub 5]RE(MoO[sub 4])[sub 4] and on RE-doped Na[sub 5]Gd(MoO[sub 4])[sub 4] samples. The rare earth occupies one single crystallographic position with S[sub 4] as point symmetry. The spectra were analysed according to the crystal field theory. From the experimental data, nearly complete energy level schemes of the Pr[sup 3+] and Nd[sup 3+], on the 4f [sup 2] and 4f [sup 3] configurations were derived. Very good correlation was obtained between the experimental and simulated energy level schemes, first for the approximated D[sub 2d] and then for the true S[sub 4] symmetries. The crystal field parameters vary smoothly with the atomic number of the rare earth, when compared with those determined previously for Eu[sup 3+] in the same matrix. ...

1994-06-01

242

Evaluation of static thermodynamic properties of the ternary molten salt system Li,Na,Be/F, based on the modified Peng-Robinson equation

The static thermophysical properties of the molten salt system like LiF-NaF-BeF_2 influence the design and construction of the fuel salt and coolant in the Molten Salt Reactor for the new generation. In this paper, the equation of state of the ternary system 0.15LiF-0.58NaF-0.27BeF_2, over the temperature range from 873.15K to 1073.15K at one atmosphere pressure, is described by using modified Peng-Robinson equation. The density of the ternary system is evaluated by this equation directly, and compared with the experimental data. Base on the equation of state, the other static thermophysical properties such as the enthalpy, entropy and heat capacity at constant pressure are evaluated by the fugacity coefficient and residual function methods respectively. The density calculated by Peng-Robinson equation is in highly agreement with the experimental data, and the enthalpy, entropy and heat capacity evaluated by such two different methods are ...

2008-03-01

243

Evaluation of Static Thermophysical Properties of the Ternary Molten Salt System Li, Na and Be/F Based on the Modified Peng-Robinson Equation

The static thermodynamic properties of the molten salt system like LiF-NaF-BeF_2 influence the design and construction of the fuel salt and coolant in the Molten Salt Reactor for the new generation. In this paper, the equation of state of the ternary system 15%LiF-58%NaF-27%BeF_2, over the temperature range of 873.15K to 1073.15K at one atmosphere pressure, is described using Peng-Robinson equation modified by us. And the density of the ternary system is evaluated by this equation directly, and compared with the experimental data. Base on the equation of state, the other static thermodynamic properties such as the enthalpy, entropy and heat capacity at constant pressure are estimated by the residual function method and the fugacity coefficient method respectively. The density calculated by Peng-Robinson equation is in highly agreement with the experimental data, and the enthalpy, entropy and heat capacity evaluated by such two different methods ...

2007-04-22

244

Electrochemical corrosion behavior of alloy 400: Intergranular corrosion in acidic Na_2SO_4 solutions

The static thermophysical properties of the molten salt system like LiF-NaF-BeF2 influence the design and construction of the fuel salt and coolant in the Molten Salt Reactor for the new generation. In this paper, the equation of state of the ternary system 0.15LiF-0.58NaF-0.27BeF2, over the temperature range from 873.15K to 1073.15K at one atmosphere pressure, is described by using modified Peng-Robinson equation. The density of the ternary system is evaluated by this equation directly, and compared with the experimental data. Base on the equation of state, the other static thermophysical properties such as the enthalpy, entropy and heat capacity at constant pressure are evaluated by the fugacity coefficient and residual function methods respectively. The density calculated by Peng-Robinson equation is in highly agreement with the experimental data, and the enthalpy, entropy and heat capacity evaluated by such two different methods are ...

2008-01-01

245

Effects of the. cap alpha. -adrenoceptor antagonists phentolamine, phenoxybenzamine, and Idazoxan on sympathetic blood flow control in the periodontal ligament of the cat

The influence of heat treatments on the anodic polarization behavior of alloy 400 in acidic Na_2SO_4 solutions with different pH values and chloride contents has been studied. Alloy 400 is susceptible to intergranular corrosion (IGC) in 0.5 N Na_2SO_4 solution (pH 3) containing 0.2% CuCl_2. For the same heat treatment (soaking for one hour at 900 C), the extent of IGC appears to be significantly affected by the cooling rate, which is greater for faster cooling (e.g., water quenching). Aging the water-quenched alloy at 500 C enhances IGC susceptibility, and aging at higher temperatures imparts resistance to IGC. Note that addition of small amounts of hafnium has a beneficial effect on the resistance to IGC of alloy 400 under similar exposure conditions. An attempt has been made to rationalize the observations in terms of segregation of sulfur and phosphorus to the grain boundaries.

246

Dodecanuclear rhenium cluster complexes with an interstitial carbon atom: Synthesis, structures and properties of two new compounds K6[Re12CS17(OH)6]?4H2O and Na12Re12CS17(SO3)6?48.5H2O

Blood flow changes in the periodontal ligament (PDL) were measured indirectly by monitoring the local clearance of /sup 125/I/sup -/ during electric sympathetic nerve stimulation or close intra-arterial infusions of either noradrenaline (NA) or adrenaline (ADR) before and after administration of phentolamine (PA), phenoxybenzamine (PBZ) or Idazoxan (RX). At the doses used in the present study, PA was the only antagonist that significantly reduced the blood flow decrease seen on activation of sympathetic fibers, although PBZ also reduced this response. Idazoxan, however, did not induce the consistent effect on blood flow decreases seen on sympathetic activation. All three ..cap alpha..-adrenoceptor antagonists almost abolished the effects of exogenously administered NA and ADR. The results suggest the presence of functional post-junctional adrenoceptors of both the ..cap alpha.. 1 and ..cap alpha.. 2 subtypes in the sympathetic regulation of the ...

1988-01-01

247

British Library Electronic Table of Contents (United Kingdom)

The dodecanuclear rhenium anionic complex with terminal hydroxo ligands [Re12CS17(OH)6]6? was obtained by the reaction of K6[Re12CS17(CN)6]?20H2O with molten KOH at 300 ?C. The cluster complex was crystallized as a potassium salt from aqueous solution. The reaction between K6[Re12CS17(OH)6]?4H2O and Na2S2O4 in water under reflux results in the formation of the complex Na12[Re12CS17(SO3)6]?48.5H2O. Both new compounds were characterized by single-crystal X-ray diffraction, elemental analyses and IR spectroscopy. The electronic structure of [Re12CS17(OH)6]6? was also elucidated by DFT calculation

2010-01-01

248

Basic study on high performance secondary battery for electric load-leveling & electric vehicle

Zeolite-supported Ni and Mo catalysts for hydrotreatments. 2. HRTEM observations

Na/S battery can have the higher energy density and higher power density than that of existing high performance secondary battery. This battery is expected to use for electric load leveling and electric vehicle. Ni/MH battery was developed in advanced countries, but it is one of the advanced technologies which are preserved in their own country. In the study on Na/S battery, properties of B{sup -}alumina electrolyte was investigated. Also the construction technologies of this test cell was established by combining tube type of B{sup -}alumina solid electrolyte with Na-, S- electrode etc. Especially of this cell, charge/discharge performance and open circuit voltage was examined. Mi/MH battery sample were tested with SBT500 system for self-discharge rate at room temp, was measured. It was found that the electrolyte and separator can be optimized to minimize the self-discharge rate. (author). refs., figs., tabs.

1993-12-01

249

Use of post-consumer waste plastics in cement-based composites

Calcined and sulfided Ni-Mo catalysts supported on ultrastable Y zeolite (USY), NaY zeolite, mordenite, and ZSM-5 were studied by high-resolution electron transmission microscopy (HRTEM) with selected-area electron diffraction (SAED) and energy-dispersive spectroscopy (EDS). Ni and Mo oxide aggregates were rarely observed in the USY-supported Ni-Mo catalyst, indicating that most of Ni and Mo may be incorporated into USY, e.g., supercavities and possibly sodalite cages. However, there were a large number of {alpha}-NiMoO{sub 4} aggregates of different particle sizes in NaY-, mordenite-, and ZSM-5-supported catalysts, and the mordenite-supported catalyst also contained MoO{sub 3} crystals. The {alpha}-NiMoO{sub 4} may be attached to the surface of substrates as individual particles or needle aggregates, it may be disseminated into mordenite particles, or it may even form an isolated sphere (in Ni-Mo/NaY) or a needle (in ...

2000-01-25

250

Thermally stimulated luminescence of NaAlSi_3O_8 and its analysis

This paper describes an innovative use of post-consumer waste HDPE plastic in concrete as a soft filler. A reference concrete was proportioned to have the 28-day compressive strength of 5000 psi (35 MPa). A high-density plastic was shredded into small particles for use in the concrete. These particles were subjected to three chemical treatments (water, bleach, bleach + NaOH) to improve their bonding with the cementitious matrix. The plastic particles were added to the concrete in the range of 0--5% of total mixture by weight. Compressive strengths were measured for each test mixture. The results showed that chemical treatment has a significant effect on performance of the plastic filler in concrete. Of the three treatments used on the plastic, the best performance was observed with the alkaline bleach treatment (bleach + NaOH) with respect to compressive strength of concrete.

1996-10-01

251

Temperature dependence of density and compressibility of eutectic mixtures of alkali metal chlorides near melting point

The complex thermally stimulated luminescence (TSL) pattern of NaAlSi_3O_8 has been analyzed on transparent and opaque varieties of natural crystals and synthetic pure powder. The existence of seven additional peaks in the range 20 to 450 "0C following X-irradiation at room temperature (RT) is reported, also evaluated by the curve fitting method. The validity of the analysis is discussed in the light of detailed trap analysis of KAlSi_3O_8. An attempt has been made to probe the excistence of high temperature peaks beyond 450 "0C using UV stimulation at RT. All the TSL peaks analyzed follow a second-order kinetic process.

252

Surface modification on magnesium alloys by coating with magnesium fluorides

Hydrostatic weighing was used to measure the pre-melt density of crystalline eutectic mixtures of alkaline metal chlorides of the compositions (mole fractions): 0.605 LiCl + 0.395 CsCl, 0.585 LiCl + 0.415 KCl, 0.297 NaCl + 0.246 KCl + 0.457 CsCl, and 0.348 NaCl + 0.652 CsCl with melting points 598, 628, 753, 763 K, respectively, as a function of temperature. In the same temperature ranges, the compressibility and molar volume of eutectics as well as their sudden change upon melting were estimated. Unusual variations of these properties were revealed near the crystal/liquid phase transition, which were related to local disordering of particle configuration

253

Solubility of Sn(IV) oxide in dilute NaClO{sub 4} solution at ambient temperature

A new technique has been developed for improving corrosion resistance on magnesium alloys. Specimens of AZ31 magnesium alloy were dipped into molten salt of NaBF{sub 4} at 723 K for various times, and then cooled, rinsed with water, and dried in air. Corrosion resistance in the surface treated specimens was evaluated by salt immersion test using 1% NaCl solution as a time for occurring filiform corrosion. On an un-treated AZ31 alloy, the time for starting the filiform corrosion was about 1.2 ks, while on the surface treated specimen, the time was prolonged into about 1300 ks. Moreover, the surface treated specimen showed corrosion resistance in low pH solutions, such as 1% HNO{sub 3} and HCl solutions. (orig.)

2005-07-01

254

Solubility of Sn(IV) oxide in dilute NaClO_4 solution at ambient temperature

The solubility of Sn(IV) oxide was determined in a dilute NaClO{sub 4} solution with pH 2 through 12 at ambient temperature. Both oversaturation and undersaturation experiments were carried out in an inert gas glovebox where the concentration of the oxygen and carbon dioxide were less than 1 ppm. The solubility of Sn(IV) oxide was 3 {times} 10{sup {minus}8} mol/l at neutral pH, and increased at pH > 7.5. Equilibrium constants of soluble reactions were calculated from the experimental data, using curve fitting method. The study suggests that the solubility of Sn(IV) oxide would be higher than that provisionally used in current safety assessments of HLW disposal sites.

1997-12-31

255

Sodium-driven motor of the polar flagellum in marine bacteria Vibrio

The solubility of Sn(IV) oxide was determined in a dilute NaClO_4 solution with pH 2 through 12 at ambient temperature. Both oversaturation and undersaturation experiments were carried out in an inert gas glovebox where the concentration of the oxygen and carbon dioxide were less than 1 ppm. The solubility of Sn(IV) oxide was 3 x 10"-"8 mol/l at neutral pH, and increased at pH > 7.5. Equilibrium constants of soluble reactions were calculated from the experimental data, using curve fitting method. The study suggests that the solubility of Sn(IV) oxide would be higher than that provisionally used in current safety assessments of HLW disposal sites.

1996-12-02

256

British Library Electronic Table of Contents (United Kingdom)

The Na+-driven bacterial flagellar motor is a molecular machine powered by an electrochemical potential gradient of sodium ions across the cytoplasmic membrane. The marine bacterium Vibrio alginolyticus has a single polar flagellum that enables it to swim in liquid. The flagellar motor contains a basal body and a stator complexes, which are composed of several proteins. PomA, PomB, MotX, and MotY are thought to be essential components of the stator that are required to generate the torque of the rotation. Several mutations have been investigated to understand the characteristics and function of the ion channel in the stator and the mechanism of its assembly around the rotor to complete the motor. In this review, we summarize recent results of the Na+-driven motor in the polar flagellum of ...

2011-01-01

257

Physiological and antioxidant responses of Mentha pulegium (Pennyroyal) to salt stress

British Library Electronic Table of Contents (United Kingdom)

Mentha pulegium L. is a medicinal and aromatic plant belonging to the Labiatae family present in the humid to the arid bioclimatic regions of Tunisia. We studied the effect of different salt concentrations on plant growth, mineral composition and antioxidant responses. Physiological and biochemical parameters were assessed in the plant organs after 2?weeks of salt treatment with 25, 50, 75 and 100?mM NaCl. Results showed that, growth was reduced even by 25?mM, and salt effect was more pronounced in shoots (leaves and stems) than in roots. This growth decrease was accompanied by a restriction in tissue hydration and K+ uptake, as well as an increase in Na+ levels in all organs. Considering the response of antioxidant enzymes to salt, leaves and roots reacted differently to saline conditions...

2010-01-01

258

Phenotyping in the archaea: optimization of growth parameters and analysis of mutants of Haloferax volcanii

British Library Electronic Table of Contents (United Kingdom)

Abstract A method to grow the halophilic archaeon Haloferax volcanii in microtiter plates has been optimized and now allows the parallel generation of very reproducible growth curves. The doubling time in a synthetic medium with glucose is around 6-h. The method was used to optimize glucose and casamino acid concentrations, to clarify carbon source usage and to analyze vitamin dependence. The characterization of osmotolerance revealed that after a lag phase of 24-h, H. volcanii is able to grow at salt concentrations as low as 0.7-M NaCl, much lower than the 1.4-M NaCl described as the lowest concentration until now. The application of oxidative stresses showed that H. volcanii exhibits a reaction to paraquat that is delayed by about 10-h. Surprisingly, only one of two amino acid auxotrophi...

2011-01-01

259

Optimization of alkaline hydrolysis of paddy straw for ferulic acid extraction

British Library Electronic Table of Contents (United Kingdom)

Response Surface Methodology (RSM) via Central Composite Design (CCD) was used to optimize the alkaline hydrolysis of paddy straw to improve ferulic acid extraction. The parameters involved, namely temperature (^oC), concentration of NaOH (M) and duration of extraction (h) are screened by Full Factorial Studies (FFD). The result obtained from FFD was 0.518% (5.18mg/g). The interactions between each parameters involved were studied using Central Composite Design (CCD). Upon optimization, the percentage of ferulic acid improved from 0.518% to 0.817% (8.17mg/g). The optimum conditions obtained from this study are 125^oC, 3.90M, 2.30h for temperature, concentration of NaOH and extraction time, respectively. This result shows a significant improvement than the previous published work. Details o...

2011-01-01

260

On character of organic additives effect on pitting corrosion rate of steel-Kh25T at various potentials

Morphology and properties of silane-modified montmorillonite clays and clay/PBT composites

The dependence of the inhibiting action of some surface active organic substances (SAOS) on the pitting- formation potential epsilonsub(p) has been investigated for the steel Kh25T. The study has been performed by potentiostatic method using the H_2SO_4 0.1-n-solution doped by NaCl, Na_2SO_4, in the presence of SAOS of different classes. As epsilonsub(p) shifts in positive direction from +0.6 to +1.1 V, the inhibiting action of the SAOS series (o-oxyquinoline) increases gradually till some critical potential above which SAOS favour pitting destruction of steel. This phenomenon should be considered in anodic protection in SAOS-doped solutions.

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261

British Library Electronic Table of Contents (United Kingdom)

Commercially available organoclay (Closite 30B) was modified by using 3-aminopropyltriethoxysilane (APS) via a silylation reaction. Sodium clay (Closite Na) was treated by APS directly as a control. Such modified clays were further melt-compounded with polybutylene terephthalate (PBT). The morphology and properties of the modified organoclays were characterized with X-ray diffraction (XRD), transmission electrical microscopy (TEM), Infra-red spectroscopy, contact angle measurement, and thermogravimetric analysis (TGA). The effects of modified clays on the crystallization behavior of PBT were characterized by differential scanning calorimetry. The basal spacing of Closite Na was enlarged from 1.01 to 1.41 nm after APS treatment, indicating that the APS was intercalated into the clay interga...

2008-01-01

262

Modelling Of Monazite Ore Break-Down By Alkali Process Spectrometry

High-resolution NMR on /sup 29/Si nuclei in acidic zeolites

A computer modelling has been developed for the calculation of mass balance of monazite ore break-down by alkali process at Rare Earth Research and Development Center. The process includes the following units : ore digestion by concentrate NaOH, dissolution of digested ore by HCl, uranium and thorium precipitation and crystallization of Na3PO4 which is by-product from this process. The model named RRDCMBP was prepared in Visual Basic language. The modelling program can be run on personal computer and it is interactive and easy to use. User is able to choose any equipment in each unit process and input data to get output of mass balance results. The model could be helpful in the process analysis for the further process adjustment and development.

2005-10-18

263

Evaluation of the evaporation behavior of Pd, Mo, Te, and Sb in simulated low level radioactive liquid waste

The effect of treatment of Na-forms of zeolites with HCl solutions and of heat treatment of their NH/sub 4/-forms on the stability of aluminum-oxygen tetrahedra has been studied in this work by high-resolution NMR on /sup 29/Si nuclei, using the synthetic zeolites X, Y, and M (mordenite) as the objects of the study. The exchange capacity with respect to Na/sup +/ ions was determined by analyzing the equilibrium solutions after contact of the samples with 0.5 NH/sub 4/Cl solution on a flame photometer. The high-resolution /sup 29/Si NMR spectra of polycrystalline samples were recorded on an SKhR-200 spectrometer with a superconducting solenoid at a frequency of 39.75 MHz with ultrafast mechanical rotation (3 kHz) of the sample at the magic angle to the external magnetic field. The results obtained are given.

1986-12-01

264

Evaluation of Chemical Interactions of Maleic Acid with Sodium Hypochlorite and Chlorhexidine Gluconate

To sophisticate the nuclear fuel recycling processes, the transfer percentages for Pd, Mo, Te, and Sb should be determined. Each element solution containing NaNO_3 or HNO_3 was fed consistently into the thin film evaporator regulated in vac and at 50 deg C. The analyte percentages in the inside of the lid, in the condenser, and in the distillate were 10"-"1%/m"2, 10"-"3%/m"2, and 10"-"3% (DF = 10"5), respectively. The Mo percentage in the condenser was lower by a factor of 10 than those of other elements investigated. The NO_3"- percentages were nearly constant despite increasing HNO_3 concentrations, however, the ratios decreased with increasing NaNO_3 concentrations. (author)

2003-02-01

265

British Library Electronic Table of Contents (United Kingdom)

IntroductionThe elimination of microorganisms from the root canal system necessitates the use of combination of irrigating solutions to enhance their antimicrobial property. The combination of irrigants and their interaction sometimes could be detrimental to the outcome of the root canal therapy. The purposes of this study were (1) to evaluate the interaction between 7% maleic acid (MA) and 2% chlorhexidine gluconate solution (CHX) and to find out the availability of individual irrigant and (2) to determine the free available chlorine content when 7% MA was mixed with 2.5% sodium hypochlorite (NaOCl) solution. MethodsInteraction between MA and CHX was assessed by high-performance liquid chromatography. Available chlorine content in NaOCl was evaluated by the standard iodine/thiosulfate tit...

2011-01-01

266

Enhancement of bioleaching of a spent Ni/Mo hydroprocessing catalyst by Penicillium simplicissimum

British Library Electronic Table of Contents (United Kingdom)

Statistically based experimental designs were applied to screen and optimize the bioleaching of spent hydrocracking catalyst by Penicillium simplicissimum. Eleven factors were examined for their significance on bioleaching using a Plackett-Burman factorial design. Four significant variables (pulp density, sucrose, NaNO"3, and yeast extract concentrations) were selected for the optimization studies. The combined effect of these variables on metal bioleaching was studied using a central composite design (CCD). Second-order polynomials were established to identify the relationship between the recovery percent of the metals and the four significant variables. The optimal values of the variables for maximum metals bioleaching were as follows: pulp density (4.0%, w/v), sucrose (90g/L), NaNO"3 (2...

2011-01-01

267

Electrosynthesis of adherent poly(3-amino-1,2,4-triazole) films on brass prepared in nonaqueous solvents

Electrosynthesis of adherent poly(3-amino-1,2,4-triazole) films on brass prepared in nonaqueous solvents

The kinetics of the electropolymerization of 3-amino-1,2,4-triazole on a brass substrate in alkaline solution containing methanol was investigated using cyclic polarization, chronoamperometry, electrochemical impedance techniques and scanning electronic microscopy. The polymeric film was prepared by successive cycles of potential of a 60Cu-Zn electrode between 0 and 1.6 V. During the second cycle, the oxidation peak of the monomer disappears indicating the formation of the insulating film. We have also shown that the monomer oxidation reaction is essentially irreversible and controlled by a diffusion process. The protective effect of the film formed on brass has been studied in a 3%NaCl and 3%NaCl + S{sup 2-} solution. The results showed important inhibition efficiency, about 96% for 4 h of testing time.

2008-06-15

268

British Library Electronic Table of Contents (United Kingdom)

The kinetics of the electropolymerization of 3-amino-1,2,4-triazole on a brass substrate in alkaline solution containing methanol was investigated using cyclic polarization, chronoamperometry, electrochemical impedance techniques and scanning electronic microscopy. The polymeric film was prepared by successive cycles of potential of a 60Cu-Zn electrode between 0 and 1.6V. During the second cycle, the oxidation peak of the monomer disappears indicating the formation of the insulating film. We have also shown that the monomer oxidation reaction is essentially irreversible and controlled by a diffusion process. The protective effect of the film formed on brass has been studied in a 3%NaCl and 3%NaCl+S2- solution. The results showed important inhibition efficiency, about 96% for 4h of testing ...

2008-01-01

269

Detection of glycoproteins in the Acanthamoeba plasma membrane

Corrosion resistance in magnesium alloys and deposition coated magnesium alloy

In the present study the authors have shown that glycoproteins are present in the plasma membrane of Acanthamoeba castellanii by utilizing different radioactive labeling techniques. Plasma membrane proteins in the amoeba were iodinated by "1"2"5I-lactoperoxidase labeling and the solubilized radiolabeled glycoproteins were separated by lectin-Sepharose affinity chromatography followed by polyacrylamide gel electrophoresis. The periodate/NaB"3H_4 and galactose oxidase/NaB"3H_4 labeling techniques were used for labeling of surface carbohydrates in the amoeba. Several surface-labeled glycoproteins were observed in addition to a diffusely labeled region with M_r of 55,000-75,000 seen on electrophoresis, which could represent glycolipids. The presence of glycoproteins in the plasma membrane of Acanthamoeba castellanii was confirmed by metabolic labeling with ["3"5S]methionine followed by lectin-Sepharose affinity chromatography and polyacrylamide gel ...

270

Calcium phosphate glass-ceramics for bioactive coating on a #beta#-titanium alloy

Corrosion behavior of deposition coated specimens prepared by the technique proposed by the authors is investigated in salt immersion tests, and also those of pure magnesium, 3N, 4N and 6N grades, and magnesium alloys, AZ31 and AZ91E, are investigated for comparison. Inhomogeneous corrosion occurs in AZ31 and AZ91E alloys when buffered solutions with pH values of 6.5 and 9.0 including 1% NaCl and a conventional 3% NaCl solution are used for immersion tests, while 6N-Mg shows homogeneous corrosion in such solutions. Corrosion behavior of the deposition coated specimen resembles that of 6N-Mg. Purification process included in the deposition coating technique provides homogeneity in microstructural and electrochemical terms, which results in improving corrosion resistance. (orig.)

2003-07-01

271

The centers of early-type galaxies with HST; 2, empirical models and structural parameters

The formation of a porous coating is the decisive feature for the bio-compatibility of silica-free calcium phosphate glass ceramics on alloy surfaces like the #beta#-Ti structured Ti-29Nb-13Ta-4.6Zr used in this work. The ceramic composition is highly important: 50CaO-40P_2O_5-7Na_2O-3TiO_2 glass powder produces a pore-free coating unable to bind hydroxyapatite, whereas 60CaO-30P_2O_5-7Na_2O-3TiO_2 glass incorporates pores from which a crystalline hydroxyapatite phase can grow over the surface from simulated body fluid (see Figure). (Abstract Copyright [2003], Wiley Periodicals, Inc.)

2003-07-01

272

Formation of N2 in the fixed-bed pyrolysis of low rank coals and the mechanisms; Koteisho netsubunkai ni okeru teitankatan kara no N2 no sisei

We present a set of structural parameters for the central parts of 57 early-type galaxies observed with the Planetary Camera of the Hubble Space Telescope. These parameters are based on a new empirical law that successfully characterizes the centers of early type galaxies. This empirical law assumes that the surface brightness profile is a combination of two power laws with different slopes gamma and beta for the inner and outer regions. Conventional structural parameters such as core radius and central surface brightness are replaced by break radius r_b, where the transition between power-law slopes takes place, and surface brightness mu_b at that radius. An additional parameter alpha describes the sharpness of the break. The structural parameters are derived using a chi-squared minimization process applied to the mean surface brightness profiles. The resulting model profiles generally give very good agreement to the observed profiles out to the radius of 10 ...

1996-01-01

273

Estimation of trace elements in some anti-diabetic medicinal plants using PIXE technique

In order to establish coal NOx preventive measures, discussions were given on formation of N2 in the fixed-bed pyrolysis of low rank coals and the mechanisms thereof. Chinese ZN coal and German RB coal were used for the discussions. Both coals do not produce N2 at 600{degree}C, and the main product is volatile nitrogen. Conversion into N2 does not depend on heating rates, but increases linearly with increasing temperature, and reaches 65% to 70% at 1200{degree}C. In contrast, char nitrogen decreases linearly with the temperature. More specifically, these phenomena suggest that the char nitrogen or its precursor is the major supply source of N2. When mineral substances are removed by using hydrochloric acid, their catalytic action is lost, and conversion into N2 decreases remarkably. Iron existing in ion-exchanged condition in low-rank coal is reduced and finely diffused into metallic iron particles. The particles react with heterocyclic nitrogen compounds and turn ...

1996-10-28

274

Early cretaceous age of orthogneiss from the Charleston Metamorphic Group, New Zealand

Trace elemental analysis was carried out in various parts of some anti-diabetic medicinal plants using PIXE technique. A 3 MeV proton beam was used to excite the samples. The elements Cl, K, Ca, Ti, Cr, Mn, Fe, Ni, Cu, Zn, Br, Rb and Sr were identified and their concentrations were estimated. The results of the present study provide justification for the usage of these medicinal plants in the treatment of diabetes mellitus (DM) since they are found to contain appreciable amounts of the elements K, Ca, Cr, Mn, Cu, and Zn, which are responsible for potentiating insulin action. Our results show that the analyzed medicinal plants can be considered as potential sources for providing a reasonable amount of the required elements other than diet to the patients of DM. Moreover, these results can be used to set new standards for prescribing the dosage of the herbal drugs prepared from these plant materials.

2006-08-15

275

Dating techniques in fault investigations

Discordant U-Pb zircon isotopic data from amphibolite facies orthogneisses of the Charleston Metamorphic Group, western South Island, New Zealand, define a lower intercept age of 114#+-#18 m.y. that is interpreted as the crystallization age of the orthogneiss magmas. The upper intercept age of 1026#+-#97 m.y. reflects inherited components of Precambrian zircon derived from the source region of the magmas. The age, and whole rock chemical characteristics, indicate that the orthogneisses are part of the same phase of Early cretaceous magmatic activity that produced voluminous arc-related calc-alkaline plutonic rocks throughout western South Island. Previously published K-Ar and Rb-Sr mineral ages indicate uplift and cooling of the Charleston Metamorphic Group to less than 400deg C by 110-90 m.y. This uplift occurred as a consequence of low-angle normal faulting related to the Late Cretaceous breakup of Gondwana, and suggests that regional continental lithospheric ...

276

Predicted versus observed cosmic-ray-produced noble gases in lunar samples: improved Kr production ratios. [From excitation functions for proton spallation of Rb, Sr, Y, Zr at 10 MeV to 10 GeV

Determining the time of most recent fault movement is an important part of assessing a possible site for a nuclear power plant. The purpose of this paper is not to present research information but to provide a practical guide to some of the dating techniques available to the engineering geologist working on nuclear power plant siting. Emphasis is placed on the practical aspects, such as usable minerals, conditions necessary for them to yield correct dates, degree of accuracy, sample collection, sample size, and sample packaging. In this paper, the usual geologic field techniques are taken for granted (such as those used in stratigraphy, paleontology, and structural analysis) for assessing fault history. Laboratory techniques used in conjunction with or supplemental to field methods are discussed. The specific radiometric methods discussed are "1"4C(carbon-14), fission track, K-Ar (potassium-argon), thermoluminescense, Rb-Sr (rubidium-strontium), and U-Th ...

277

New sets of cross sections for the production of krypton isotopes from targets of Rb, Sr, Y, and Zr were constructed primarily on the bases of experimental excitation functions for Kr production from Y. These cross sections were used to calculate galactic-cosmic-ray and solar-proton production rates for Kr isotopes in the moon. Spallation Kr data obtained from ilmenite separates of rocks 10017 and 10047 are reported. Production rates and isotopic ratios for cosmogenic Kr observed in ten well-documented lunar samples and in ilmenite separates and bulk samples from several lunar rocks with long but unknown irradiation histories were compared with predicted rates and ratios. The agreements were generally quite good. Erosion of rock surfaces affected rates or ratios for only near-surface samples, where solar-proton production is important. There were considerable spreads in predicted-to-observed production rates of /sup 83/Kr, due at least in part to uncertainties in ...

1979-01-01

278

tgz Document (18304k)

[Chemical properties of litter in dark coniferous forest of Sejila Mountains in Tibet].

N F Q k q V N h l b hs x j p bN t gX Y I r bN X U Y Fff c o t dA A p A DA2 AC7LAR A Ak VAwt A jA A A A t A bNA A A dZA A A A A A X A A M A LA A E A A wA V A A A A oA V A A oA M A...

2011-02-17

279

WASTE DISPOSAL IN SALT. I. THE HNO$sub 3$-NaCl REACTION

The storage and chemical properties of the forest litter in dark coniferous forest of Sejila Mountain were studied. The results showed that the existing storage was 5.863 t.hm-2 and the annual litter fall was 0.3205 t.hm-2. It implied that the forest litter decomposed slowly and accumulated quickly, and the turnover of nutrient circles was slow. The contents of N, Ca, Na, and Mn nutrient elements in litter layer were in the order of un-decomposed layer (U layer) > semi-decomposed layer (S layer) > decomposed layer (D layer), those of K, Fe, and Mg were in the order of D layer > S layer > U layer, and P element content was in the order of U layer > D layer > S layer. The pool of elements was 78.483 kg.hm-2 N, 3.843 kg.hm-2 P, 48.205 kg.hm-2 K, 23.115 kg.hm-2 Ca, 13.157 kg.hm-2 Na, 30.554 kg.hm-2 Fe, 2.113 kg.hm-2 Mn and 27.513 kg.hm-2 Mg. The turnover of forest litter was the total of nutrient release accumulation. K, Fe, and ...

2004-01-01

280

Unique Bell-shaped Voltage-dependent Modulation of Na⁺ Channel Gating by Novel Insect-selective Toxins from the Spider Agelena orientalis*

The chemical reaction between nitric acid and sodium chloride was investigated in onder to provide preliminary information for subsequent studies on the interaction between simulated Purex waste solution and salt. The reaction is characterized by the production of chlorine and nitrosyl chloride and can be considered to be the same as the aqua regia reaction. Within the limits of the conditions imposed by the projected field studies, the acid concentration and temperature are the two parameters which control the extent of the interaction. (auth)

1960-10-01

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

281

Thermogalvanic effects on the pitting corrosion of water-cooled heat exchangers

Spider venoms provide a highly valuable source of peptide toxins that act on a wide diversity of membrane-bound receptors and ion channels. In this work, we report isolation, biochemical analysis, and...Full Text Available

2010-06-11

282

Study on the natural gas utilization in the ceramic industry; Estudo sobre a utilizacao do gas natural na industria ceramica

Thermogalvanic corrosion of St3 steel in a temperature range from 25 to 50{degrees}C with a 3.84{degrees}C/cm gradient was studied in a neutral media flow. It is shown that the thermogalvanic effect on the pitting corrosion of water-cooled heat exchangers is decisive but dual. Depending on the composition of the cooling medium, thermogalvanic corrosion may either enhance (0.5 M NaCl) or inhibit (tap water) pitting corrosion.

1995-05-01

283

Structural and optical investigations of sodium europium carbonate Na{sub 3}Eu(CO{sub 3}){sub 3}

The production, principal applications, characteristics and properties, advantages of the gas natural is showed. A sectorial overview of the ceramic industry and the utilization of the natural gas in the ceramic industry is presented. The expectations are systematized and the impact of the natural gas utilization in the ceramic industry is evaluated. Some conclusions are withdrawn and recommendations suggested.

1998-07-01

284

Selective epoxidation of allylic alcohols with a titania-silica aerogel

The crystal structure and the luminescence properties of a new carbonate, Na{sub 3}Eu(CO{sub 3}){sub 3}, are presented. Na{sub 3}Eu(CO{sub 3}){sub 3} is orthorhombic, acentric, Ama2, Z = 4; a = 9.942(2) {angstrom}, b = 11.024(3) {angstrom}, c = 7.147(2) {angstrom}; R = 0.019, R{sub w} = 0.051, 2374 unique reflections. The anionic subnetwork is built up from the stacking of {open_quotes}standing on edge{close_quotes} and {open_quotes}flat lying{close_quotes} carbonate layers into which Na{sup +} and Eu{sup 3+} ions are inserted. The symmetry of the EuO{sub 9} polyhedra is C{sub s}. The Eu{sup 3+} ions are inserted. The symmetry of the EuO{sub 9} polyhedra is C{sub s}. The Eu{sup 3+} luminescence technique confirms the presence of a unique low symmetry site for the rare earth atom. The electrostatic crystal field (cf) effects on the {sup 7}F multiplet are evaluated on the basis of the phenomenological cf theory. The ...

1997-08-01

285

Rayleigh scattering of Moessbauer radiation in hyaluronate oriented fibres

An amorphous mesoporous titania-silica aerogel (20 wt%TiO{sub 2} - 80 wt% SiO{sub 2}) and tert.-butylhydroperoxide (TBHP) have been used for the epoxidation of various allylic alcohols. Allylic alcohols possessing an internal double bond were more reactive than those with a terminal C=C bond. Epoxide selectivities could be improved by addition of (basic) zeolite 4 A and NaHCO{sub 3} to the reaction mixture. (orig.)

1998-12-31

286

Radial distribution functions of liquid Na and Cs

The Rayleigh scattering of Moessbauer radiation has been measured on highly oriented fibres of Na-hyaluronate at different hydration levels. The elastic- and-inelastic-scattering intensities, measured as a function of the scattering vector Q, have provided information on the dynamic structuring of the water molecules to the polysaccharidic chains.

1996-02-01

287

Power system stabilizer from accelerating power for Itauba power plant: Design and implementation; Projeto e implantacao de estabilizador de sistema de potencia derivado da potencia de aceleracao na Usina de Itauba

Radial distribution functions of liquid sodium and caesium at 100"0C have been calculated by the method of molecular dynamics with interionic pair potentials derived from Heine-Abarenkov-Shaw type model potential. The results were found to be in good agreement with recent experimental data. (Auth.).

1978-01-01

288

Pore properties and pharmacological features of the P2X receptor channel in airway ciliated cells

This work presents the project and relates the implementation of a power system stabilizer in Itauba hydroelectric power plant, Brazil. Some forecasts and field experiments are also presented. 10 refs., 19 figs.

1992-12-31

289

Pitting corrosion resistance of silicon-implanted stainless steels

Airway ciliated cells express an ATP-gated P2X receptor channel of unknown subunit composition (P2X_cilia) which is modulated by Na⁺ and by long exposures to ATP. P2X_cilia...Full Text Available

2006-03-15

290

Pd-Na/F double exploding foil photoionization experiment

The pitting corrosion resistance of three different types of stainless steel implanted with silicon is investigated using the potentiokinetic polarization technique. The specimens are tested in 3% NaCl and 0.1 N HCl solutions. Silicon ion implantation inhibits pitting corrosion of the steels in both aqueous media. The corrosion resistance depends on the silicon dose. Post implantation annealing only slightly alters the localized corrosion. (author).

291

Nuclear magnetic resonance and the question of 5f electron localization in the actinides

The achievement of inner-shell photoionization of Zn-like Pd by means of two exploding foils is described. This resulted in the soft X-ray transition 3d94s2-3d104p at 46 A. It is shown that the photoionization of inner shell electrons in highly stripped ions can lead to X-ray transitions which may be candidates for X-ray lasers under 50 A.

1990-03-01

292

Nuclear magnetic resonance and the question of 5F electron localization in the actinides

Nuclear magnetic resonance results are presented for a number of NaCl-type compounds and cubic Laves-phase type compounds of uranium, neptunium, and plutonium. Special emphasis is placed on the Knight shift and spin-lattice relaxation time measurements and their interpretation in terms of localized or itinerant pictures of the 5f electrons. (author).

293

Novel inorganic hydrogen-bonded crystals with nonlinear optical properties

Nuclear magnetic resonance results are presented for a number of NaCl-type compounds and cubic Laves-phase type compounds of uranium, neptunium, and plutonium. Special emphasis is placed on the Knight shift and spin-lattice relaxation time measurements and their interpretation in terms of localized or itinerant pictures of the 5Line integral electrons.

1976-01-01

294

Nondestructive determination of airborne lead particulates by the radionuclide X-ray fluorescence analysis

Four inorganic hydrogen-bonded crystals with second-order nonlinear properties have been discovered: K_4LiH_3(SO_4)_4, Na_2SeO_4#centre dot#H_2SeO_3#centre dot#H_2O, Cs_1_,_5Li_1_,_5H(SO_4)_2 and NH_4HSeO_4. (author)

2000-01-01

295

New molten salt systems for high temperature molten salt batteries: Ternary and quaternary molten salt systems based on LiF-LiCl, LiF-LiBr, and LiCl-LiBr

Airborne lead particulates collected on a membrane filter were determined by the nondestructive X-ray fluorescence method. The gamma/X radionuclide source "2"4"1Am/Ag and a scintillation detector with a NaI/Tl crystal were used for the excitation and detection, respectively, of L X-rays of Pb. One can say, with reference to the obtained results, that the sensitivity and accuracy of the measurement is more than adequate for monitoring the Pb level in air. (author).

1980-01-01

296

British Library Electronic Table of Contents (United Kingdom)

Using a new simulative technique developed by us, we systematically investigated new ternary or quaternary molten salt systems, which are based on LiF-LiCl, LiF-LiBr, and LiCl-LiBr binary systems, for use as electrolytes in thermal batteries, and evaluated their ionic conductivities and melting points experimentally. It was confirmed experimentally that LiF-LiBr-KF (melting point: 425^oC, ionic conductivity at 500^oC: 2.52Scm^-^1), LiCl-LiBr-KF (405^oC, 2.56Scm^-^1), LiCl-LiBr-NaF-KF (425^oC, 3.11Scm^-^1), LiCl-LiBr-NaCl-KCl (420^oC, 2.73Scm^-^1), and LiCl-LiBr-NaBr-KBr (420^oC, 2.76Scm^-^1) meet our targets for both melting point (350-430^oC) and ionic conductivity (2.0Scm^-^1 and higher at 500^oC). A single cell using the newly developed LiCl-LiBr-NaCl-KCl molten salt as an electrolyte w...

2011-01-01

297

NHE8 is an intracellular cation/H⁺ exchanger in renal tubules of the yellow fever mosquito Aedes aegypti

Mechanism of denting corrosion

The goal of this study was to identify and characterize the hypothesized apical cation/H⁺ exchanger responsible for K⁺ and/or Na⁺ secretion in...Full Text Available

2009-04-01

298

Kinetics and FTIR studies of hydrocarbon synthesis on Pd/ZSM5 catalysts. Final report

The rapid corrosion of carbon steels in high temperature, acid chloride solutions is shown to be rate limited by the anodic reaction, 3Fe + 4H_2O = Fe_3O_4 + 8H"+ + 8e"-, based on experiments which find that the corrosion rate in 0.1M NiCl_2 solution has an activation energy of 60 kJ/ mole and is unaffected by adding NaCl or by replacing NiCl_2 with PtCl_4. (author).

299

Incidental orbital calcifications on computed tomography scans; Calcificacoes orbitarias incidentais na tomografia computadorizada

Hydrocarbon synthesis during CO hydrogenation over Pd/M-ZSM5 (M=H,Na,La) and Pd/SiO/sub 2/ has been investigated. Overall activity depended on the cation-exchanged form of the support and decreased in the order Pd/La-ZSM5 = Pd/Na-ZSM5 > Pd/H-ZSM5 > Pd/SiO/sub 2/. The zeolite-supported catalysts showed high selectivity towards saturated C/sub 2/-C/sub 6/ hydrocarbons, whereas Pd/SiO/sub 2/ favored methanol production. Increasing temperature and H/sub 2//CO feed ratio led to higher reaction rates, lower yields of C/sub 2/-C/sub 6/ products, and increased lighter hydrocarbons. A mechanical mixture of Pd/SiO/sub 2/ and Na-ZSM5 showed similar product distribution as Pd/Na-ZSM5. Infrared spectra of the catalysts under reaction conditions indicate the presence of adsorbed oxygenates on the zeolite. Changes in the IR bands during the initial stages of the reaction suggest that surface species on the ...

1986-10-15

300

In situ corrosion studies on selected high level waste packaging materials under simulated disposal conditions in rock salt formations

We retrospectively studied the computed tomography scans of the orbit in 75 patients in order to identify the presence of incidental calcifications (scleral and trochlear apparatus calcifications.). These imaging findings should integrate the vast list of differential diagnosis of orbital calcifications, as they may help radiologists to distinguish these calcifications from orbital foreign bodies. (author)

2001-02-01

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301

Evidence for the nature of true Lewis sites in faujasite-type zeolites

This paper reports about in-situ corrosion studies on selected materials for long-term resistant high-level waste (HLW) packagings acting as a barrier in a rock salt repository. The materials (Ti 99.8-Pd, Hastelloy C4 and five iron-base materials) were investigated in heated boreholes in the Asse salt mine under simulated HLW disposal conditions prevailing in normal operation of repository and in certain accident scenarios. The experiments under normal operating conditions were performed at temperatures of 120 deg. C to 210 deg. C (vertical temperature profile in the boreholes) without and with gamma irradiation (3#centre dot#10"2 Gy/h, Co-60 source) within the framework of the German/US Brine Migration Test. In these experiments only small amounts of migrated brine inclusions (NaCl-rich) from the rock salt were present as corrosion medium. In the experiments carried out under simulated accident conditions with intrusion of larger amounts of ...

1993-02-01

302

Evaluation of High Solids Alkaline Pretreatment of Rice Straw

An IR spectroscopic study of the reduction of copper-exchanged Linde Na-Y zeolite with hydrogen or carbon monoxide and oxidation with oxygen or oxygen-18 showed that copper(I) and AlO(+1) are formed during reduction, and that oxidation generates copper(II) ions but does not change the aluminum species. Trigonally coordinated aluminum was not detected.

1979-05-03

303

Enrichment of trace cadmium by soybean protein for the analysis by atomic absorption method

Fresh-harvested, air-dried rice straw was pretreated at a water content of 5 g H₂O/g straw using sodium hydroxide (NaOH) and compared to pretreatment at 10 g H₂O/g...Full Text Available

2010-11-01

304

Energy consumption scenarios for the fertilizer industry; Cenarios e consumo de energia na industria de fertilizantes

A method for enrichment of the ppb level of cadmium in water by using the coagulation of soybean protein by adding acids or its complex-forming character with heavy metal ions was investigated. After adding fixed amounts of soybean milk and 2% sodium diethyldithiocarbamate(DDTC) aqueous solution and a suitable amount of delta-gluconic lactone (delta-GL) to a sample solution, the mixture was heated to boiling in order to coagulate the protein. The coagulum(soybean curd) was separated from the suspension by centrifugation and burned to ashes with a low temperature plasma asher. Then the cadmium enriched in it was determined by atomic absorption spectrometry. Various factors such as the pH of the sample solution, the amounts of soybean milk and the collection additives, and the concentration of NaCl in the sample solution on the recovery of cadmium were examined systematically. The best recovery was obtained under the following conditions: To a certain amount of ...

1975-01-01

305

Effect of aging on the pitting corrosion behavior in Al-Li alloys

This paper shows the characteristics of the fertilizer production park of the State of Minas Gerais, Brazil, mainly in the aspects of energy consumption and energy sources used in the production process of the various kinds of fertilizers and by-products. A scenario including the fertilizer production evolution was made, relating this future production with the future energy consumption of this sector. 7 figs., 2 tabs.

1991-12-31

306

Differentiation associated regulation of microRNA expression in vivo in human CD8⁺T cell subsets

In the present work, electrochemical measurements and corrosion tests in NaCl solutions were carried out to study the effect of aging treatments on pitting corrosion behavior in a 8090 alloy and its high purity Al-Li binary alloy analogue. The pitting corrosion characteristics and corrosion resistance of the 8090 alloy have been determined in relation to precipitation microstructures. (orig.).

1990-06-01

307

Diagnosis of early human myocardial ischemic damage with electron probe microanalysis

BackgroundThe differentiation of CD8⁺T lymphocytes following priming of naïve cells is central in the establishment of the adaptive immune response. Yet, the...Full Text Available

308

Determination of sodium in biological samples by instrumental neutron activation analysis

We determined the Na/K x-ray intensity ratio in frozen sections of myocardial tissues obtained at autopsy from patients who died from various causes, using electron probe analysis. We have been able to distinguish between the ischemically injured and normal cells. The method is simple, fast, and dependable even when the duration of ischemia is only 30 minutes.

1983-03-01

309

Crystal field analysis of the energy level structure of Cs{sub 2}NaAlF{sub 6}:Cr{sup 3+}

Sodium is one of the most essential elements needed for metabolic processes amongst human beings. It is consumed in the form of sodium chloride but it is also present in edible plant leaves. Sodium is mostly analyzed by flame photometric method, a destructive and time consuming technique. Sodium has been determined in some green leave vegetables samples-palak, radish, khatta palak (ambat chuka), chaulai leaves, chauli bean covers and its seeds by instrumental neutron activation analysis. The method involves irradiation of samples with thermal neutrons from "2"4"1Am-Be source and counting "2"4Na activity (half life 15 hr) from the reaction "2"3Na(n,#gamma#) "2"4Na. Activity due to 1.37 MeV photopeak was counted with a NaI(Tl) crystal coupled to gamma ray spectrometer. Green leaves of the vegetables were thoroughly washed, dried at constant temperature and powdered. Bowen's Kale powder was used as ...

1981-05-01

310

Crystal field analysis of the energy level structure of Cs2NaAlF6:Cr3+

An analysis of the energy level structure of Cr{sup 3+} ions in Cs{sub 2}NaAlF{sub 6} crystal is performed using the exchange charge model (ECM) together with the crystal field analysis/microscopic spin Hamiltonian (CFA/MSH) computer package. Utilizing the crystal structure data, our approach enables modelling of the crystal field parameters (CFPs) and thus the energy level structure for Cr{sup 3+} ions at the two crystallographically inequivalent sites in Cs{sub 2}NaAlF{sub 6}. Using the ECM initial adjustment procedure, the CFPs are calculated in the crystallographic axis system centred at the Cr{sup 3+} ion at each site. Additionally the CFPs are also calculated using the superposition model (SPM). The ECM and SPM predicted CFP values match very well. Consideration of the symmetry aspects for the so-obtained CFP datasets reveals that the latter axis system matches the symmetry-adapted axis system related directly to the six Cr-F bonds well. ...

2006-06-07

311

Corrosion of materials. A tabular survey. Korrosionsverhalten von Werkstoffen. Eine tabellarische Uebersicht

An analysis of the energy level structure of Cr3+ ions in Cs2NaAlF6 crystal is performed using the exchange charge model (ECM) together with the crystal field analysis/microscopic spin Hamiltonian (CFA/MSH) computer package. Utilizing the crystal structure data, our approach enables modelling of the crystal field parameters (CFPs) and thus the energy level structure for Cr3+ ions at the two crystallographically inequivalent sites in Cs2NaAlF6. Using the ECM initial adjustment procedure, the CFPs are calculated in the crystallographic axis system centred at the Cr3+ ion at each site. Additionally the CFPs are also calculated using the superposition model (SPM). The ECM and SPM predicted CFP values match very well. Consideration of the symmetry aspects for the so-obtained CFP datasets reveals that the latter axis system matches the symmetry-adapted axis system related directly to the six Cr-F bonds well. Using the ECM predicted CFPs as an input ...

2006-06-07

312

Corrosion of aluminum and copper thin films under simulated atmospheric conditions in laboratory tests

This compact book of tables attempts to give practicians a survey of the corrosion behaviour of common structural and coating materials. Corrosion resistances are presented for steels, alloys, plastics, elastomers, graphite, glasses, and stoneware in environments of NaOH, HNO{sub 3}, SO{sub 2}, ZnCl{sub 2}, NH{sub 3}, H{sub 2}O{sub 2}, ethyl chloride, sodium acetate, and many others. (MM).

1990-01-01

313

Correlation of Fe levels determined by ferritin and through human skin in vivo measurement using X-ray fluorescence (XRF); Correlacao entre os niveis de Fe determinados pela ferritina e pela medida in vivo na pele humana atraves da metodologia de fluorescencia de raios X (XRF)

Corrosion characteristics of Al and Cu thin films have been studied in cyclic fog tests using tap water fog and fog created with 0.1% NaCl solution in tap water. Likewise, their corrosion features have been analyzed in continuous immersion testing in the laboratory in distilled water, tap water, in 0.1% NaCl and 3.5% NaCl solutions in distilled water. The corrosion potentials and the corrosion currents of these thin films change and reach steady state values after some time. However, steady state is not realized in 3.5% NaCl solutions. The corrosion current density data have been used to calculate lifetime of 1 {mu}m thick thin films of Al and Cu in the various tests, and assuming that the fog test data would hold under normal exposure conditions, life spans for these thin film sensor elements in actual exterior exposure have also been calculated. According to estimates, an Al-TF of about 1 {mu}m would ...

1998-12-31

314

Characterization of Fatty Acid Biosynthesis in Isolated Pea Root Plastids ¹

No abstract prepared.

2007-07-01

315

Anomalous solvent extraction behavior of astatine

Fatty acid biosynthesis from Na[1-¹⁴C]acetate was characterized in plastids isolated from primary roots of 7-day-old germinating pea (Pisum sativum L.) seeds. Fatty acid...Full Text Available

1991-06-01

316

An improved synthesis of [5'-"3H]-3'-azido-3'-deoxythymidine, tritiated Zidovudine

We studied the solvent extraction behavior of astatine and found the anomalous behavior of this element similar to radioiodine. Astatine was extracted into CS_2 from acidic solution over a wide range of carrier iodine concentration. The distribution ratios of astatine were determined by measuring the #gamma#-ray from 210 At with a NaI(Tl) detector. A drastic change was observed around at 10"-"4 mol/l as in the case of 131 l. This tendency is well explained by the kinematics of the chemical reactions concerned. (author).

317

A new type of scorpion Na⁺-channel-toxin-like polypeptide active on K⁺ channels

[5'-"3H]-3'-Azido-3'-deoxythymidine (3) was prepared at a specific activity of 14.0 Ci/mmol by a two-step synthetic sequence involving controlled oxidation of the unlabelled compound (1) to the 5'-aldehyde (2) followed by reduction with ["3H]-NaBH_4. Purification was performed by preparative TLC. The radiochemical purity was 99.2%. (author).

318

A detailed comparison of the 5'-end of the ovalbumin gene cloned from chicken oviduct and erythrocyte DNA.

We have purified and characterized two peptides, named KAaH1 and KAaH2 (AaH polypeptides 1 and 2 active on K⁺ channels, where AaH stands for Androctonus australis Hector),...Full Text Available

2005-06-01

319

Use of the parmbsc0 force field and trajectory analysis to study the binding of netropsin to the DNA fragment (5'CCAATTGG)2 in the presence of excess NaCl salt in aqueous solution

We have examined homologous fragments of DNA cloned from two different tissues for changes in the dNA sequence which might be related to tissue specific gene expression. The 5' end of the chicken ovalbumin...Full Text Available

1980-10-10

320

British Library Electronic Table of Contents (United Kingdom)

The parmbsc0 force field was applied to study in detail the binding of netropsin, at a salt concentration of 0.28M Na^+, to the minor groove of an 8-mer (5'CCAATTGG)2 DNA duplex forming a netropsin.DNA complex which previously has been characterized by X-ray crystallography, albeit with the use of closely related DNA duplexes. The X-ray structure revealed that the terminal guanidinium and amidinium groups of netropsin interact with the extreme ends of the palindromic AATT sequence of the receptor DNA. The parmbsc0 parameters of B-DNA and AMBER v9 parameters of netropsin generated a stable 6ns molecular dynamics (MD) trajectory for a 1:1 class I binding motif of this complex. Trajectory analysis for the salt and hydration effects on the binding of netropsin to the 8-mer DNA duplex revealed ...

2011-01-01

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

321

Transcriptome analysis reveals salt-stress-regulated biological processes and key pathways in roots of cotton (Gossypium hirsutum L.).

Thermoluminescence studies in cerium doped NaCl crystals

High salinity is one of the main factors limiting cotton growth and productivity. The genes that regulate salt stress in TM-1 upland cotton were monitored using microarray and real-time PCR (RT-PCR) with samples taken from roots. Microarray analysis showed that 1503 probe sets were up-regulated and 1490 probe sets were down-regulated in plants exposed for 3h to 100mM NaCl, and RT-PCR analysis validated 42 relevant/related genes. The distribution of enriched gene ontology terms showed such important processes as the response to water stress and pathways of hormone metabolism and signal transduction were induced by the NaCl treatment. Some key regulatory gene families involved in abiotic and biotic sources of stress such as WRKY, ERF, and JAZ were differentially expressed. Our transcriptome analysis might provide some useful insights into salt-mediated signal transduction pathways in cotton and offer a number of candidate genes as potential ...

2011-04-30

322

Thermal-resistant radiation sensing system using optical fiber for monitoring progress of chemical decontamination

Cerium is known to enter substitutionally in trivalent state when doped in alkali halides. Cerium doped NaCl crystals exhibit greatly enhanced thermoluminescence output upon X-irradiation at RT, the intensity of emission being about 10 times that in undoped crystals for similar dosage of irradiation. The cerium doped crystals give upon X-irradiation a very intense glow peak at 145degC with shoulders at 120degC and 210degC. Upon partially bleaching the crystal with F-light, the peak at 120degC becomes prominent probably due to faster bleaching of the glow at 145degC. From further optical bleaching studies, it is concluded that the glow peak at around 120degC is due to cerium centres in the irradiated crystal and the 145degC peak due to F centres. This F centre emission occurs at lower temperature, compared to that in the undoped crystals where it occurs at around 180degC. The spectral emission in the Ce doped crystals is in the blue-green region as compared to the ...

323

The requirement for sodium as a micronutrient by species having the c(4) dicarboxylic photosynthetic pathway.

A thermal-resistant radiation sensing system using optical fiber has been developed. The system is for monitoring progress of chemical decontamination and able to measure the gamma-ray level in a hot solution of decontamination chemicals in situ. Our sensor head makes use of thermal-resistant NaI (T1) and it is connected to an optical fiber bundle. Scintillation photons pass from the NaI (T1) into the end of the bundle. This part of the system can withstand temperatures of over 100degC. At the far end of the optical fiber bundle, the scintillation photons are converted into fluorescent photons using a wavelength-shifting fiber. These photons are transferred to a distant photomultiplier tube through two thin transparent optical fibers. Furthermore, we propose a self-compensation technique for the dependence of scintillator sensitivity on. This compensation method is based on the correlation between temperature, sensitivity, and scintillation ...

1999-07-01

324

The effect of temperature on the passive film properties and pitting behaviour of a Fe-Cr-Ni alloy

Six species having characteristics of plants with the C(4) dicarboxylic photosynthetic pathway, Echinochloa utilis L. Ohwi et Yabuno (Japanese millet), Cynodon dactylon L. (Bermuda grass), Kyllinga brevifolia Rottb., Amaranthus tricolor L. cv. Early splendour, Kochia childsii Hort., and Portulaca grandiflora Hook (rose moss), responded decisively to 0.1 milliequivalent per liter NaCl supplied to their culture solutions initially containing less than 0.08 microequivalent per liter Na. Chlorosis and necrosis occurred in leaves of plants not receiving sodium. Portulaca failed to set flower in the sodium-deficient cultures. Under similar conditions Poa pratensis L. (Kentucky blue grass) having characteristics of the C(3) photosynthetic pathway made normal growth and did not respond to the addition of sodium. It is concluded from these results and previously reported work that sodium is generally essential for species having the C(4) pathway but not ...

1972-05-01

325

The Requirement for Sodium as a Micronutrient by Species Having the C4 Dicarboxylic Photosynthetic Pathway

The effect of temperature (60-280{sup o}C) on the properties of the oxide films formed on Alloy 800 in 0.1 M NaCl and 0.1 M Na{sub 2}SO{sub 4} aqueous solutions was studied by in situ AC impedance spectroscopy and polarization in the Fe(CN{sub 6}){sup -3}/Fe(CN){sub 6}{sup -4} redox system. The anodic behavior under the same experimental conditions was examined by potentiodynamic polarization techniques. In both solutions the passive film was found to become more porous, and hence less protective, with increasing temperature. However, at temperatures above 150{sup o}C, the loss of film protectiveness is more pronounced in chloride solutions, in which pitting occurs. Pitting morphology was found to be strongly temperature dependent: isolated and deep pits were found up to 200{sup o}C whereas at higher temperatures a broad, shallow and more generalized type of attack was detected. No effect of temperature on the defect structure of the ...

1996-06-01

326

The Effect of Heat Treatment and Mechanical Polishing on Nitinol Stent

Six species having characteristics of plants with the C4 dicarboxylic photosynthetic pathway, Echinochloa utilis L. Ohwi et Yabuno (Japanese millet), Cynodon dactylon L. (Bermuda grass), Kyllinga brevifolia Rottb., Amaranthus tricolor L. cv. Early splendour, Kochia childsii Hort., and Portulaca grandiflora Hook (rose moss), responded decisively to 0.1 milliequivalent per liter NaCl supplied to their culture solutions initially containing less than 0.08 microequivalent per liter Na. Chlorosis and necrosis occurred in leaves of plants not receiving sodium. Portulaca failed to set flower in the sodium-deficient cultures. Under similar conditions Poa pratensis L. (Kentucky blue grass) having characteristics of the C3 photosynthetic pathway made normal growth and did not respond to the addition of sodium. It is concluded from these results and previously reported work that sodium is generally essential for species having the C4 pathway but not for ...

1972-01-01

327

The E = mc{sup 2} exhibition

To understand the effect of heat treatment and mechanical polishing of a Nitinol wire on the chemical composition and physical morphology of the wire surface. Stents with a diameter of 1.0 cm, length of 8-10 cm, and composed of a Nitinol wire, were heat-treated at 500 .deg. C for 30 minutes, and mechanically polished with walnut shell granules. The wire surface morphology was studied with both an optical and a scanning electron microscope (SEM). In addition, an elemental analysis was performed by Energy Dispersive X-ray spectroscopy (EDX). Long microcracks along the wire direction and short microcracks across the wire were observed by SEM from the raw Nitinol wire. Upon heat treatment, the color of the wire turned blue, and Na, K, Cl, Si, Al atoms were seen from the EDX of the heat treated wire, which were absent in the original wire. The microcracks disappeared with the mechanical polishing, and the Na, K, Cl, Si, Al atoms all disappeared ...

2009-09-15

328

Studies of the involvement of metal ions with several medicinal agents

The goal of this DOE-supported exhibition is to demystify Einstein`s formula E = mc{sup 2} by illustrating the interchangeability of matter (m) and energy (E), c{sup 2} being the exchange rate. The exhibition has two major parts, {open_quotes}matter into energy{close_quotes} and {open_quotes}energy into matter{close_quotes}, plus a video to connect them. {open_quotes}Matter into energy{close_quotes} has now been completed and has been placed on the museum floor. Positrons from a {sup 22}Na source are annihilated to produce gamma rays that are caught in NaI detectors. The viewer can alter the alignment of the detectors and observe the consequences for the rates of single and coincident counts. The viewer can also observe the effects of placing absorbers in front of the counters. Prototype explanatory graphics were placed around the exhibit and those will probably be changed after we have some experience with their effectiveness. The connecting ...

1995-08-01

329

Sequential Voltammetric Determination of Ultratrace Osmium, Ruthenium and Iridium. Application to Superficial Water

NMR and CD studies indicate that Mg/sup 2 +/ and Ca/sup 2 +/ are able to change the conformation of tetracycline in DMSO solution. This may affect the in vivo effect of tetracycline. Using /sup 23/Na NMR, the formation constant of NaLAS (LAS represents the anion of lasalocid A) was found to be 80 M/sup -1/ which is much smaller than that in less polar solvents. Spin-lattice relaxation measurements were made to study the binding sites of Gd/sup 3 +/ on Las in ChCl/sub 3/-DMF mixed solvent system. No intermediate conformation (between cyclic and open-chain) was found. LAS was found to be a good second-sphere ligand to inert transition-metal amines. NMR studies suggest that LAS is in cyclic conformation when bound to these metal amines. A new method for the synthesis of spin-labeled anticancer Pt(II) complexes was developed. It is very simple and gives high yield of pure spin-labeled Pt(II) complexes.

1985-01-01

330

British Library Electronic Table of Contents (United Kingdom)

Abstract The present work, regarding the determination of ultratrace Os(VIII), Ru(III) and Ir(III) in superficial waters is an interesting example of the possibility to simultaneously, or better sequentially determine each single element in real samples by voltammetry. The method is based on the catalytic current of the Os(VIII)- and Ru(III)-bromate systems by square wave voltammetry and on the Ir(III) determination by square wave catalytic adsorptive stripping voltammetry. 0.5-mol-L-1 acetate buffer pH-4.9+7.710-2-mol-L-1 NaBrO3 and 0.5-mol-L-1 acetate buffer pH-4.9+7.710-2-mol-L-1 NaBrO3+2.310-5-mol-L-1 cetyltrimethylammonium bromide (CTAB) +0.2-mol-L-1 KCl were employed as the supporting electrolytes. The analytical procedure was verified by the analysis of the standard reference materi...

2011-01-01

331

Separation of trace radionuclides by ion exchange in the presence of competing ions

Reclaiming silver from silver zeolite

The performance of larger than bench scale ion exchange systems is evaluated by using solutions containing trace amounts of "1"3"7Cs, "8"5Kr, and "1"3"1I, and large amounts of either NaCl or Na_2HPO_4, H_3BO_3, and LiOH. The significant finding in this study is that the empirical rules of ionic selectivity of strong acid cation and strong base anion resins were followed by all ionic species, even though concentrations of some macrocomponents were nearly 10"6 times those of trace components. Other results of possible importance are the correlation between the instantaneous decontamination factor (DF) and the efficiency of column exchange capacity utilization, and the concept of time average decontamination factor (anti DF). The plot of anti DF vs. feed throughput will serve as a guide in determining when the feed should be discontinued in order to achieve a desired anti DF. Both of these correlations are derived from the breakthrough curves.

332

Radioactive-electrophoretic assay of adenosine 5'-triphosphate sulfurylase activity in crude extracts with sulfate or selenate as a substrate

Silver zeolite is used to capture radioiodines from air cleaning systems in some nuclear facilities at the Idaho National Engineering Laboratory. It may become radioactively contaminated and/or poisoned by hydrocarbon vapors, which diminishes its capacity for iodine. Silver zeolite contains up to 38 wt% silver. A pyrometallurgical process was developed to reclaim the silver before disposing of the unserviceable zeolite as a radioactive waste. A flux was formulated to convert the refractory aluminosilicate zeolite structure into a low-melting fluid slag, with Na{sub 2}O added as NAOH instead of Na{sub 2}CO{sub 3} to avoid severe foaming due to CO{sub 2} evolution. A propane-fired furnace was built to smelt 45 kg charges at 1300C in a carbon-bonded silicon carbide crucible. A total of 218 kg (7000 tr oz) of silver was reclaimed from 1050 kg of unserviceable zeolite. Silver recoveries of 97% were achieved, and the radioisotopes were fixed as ...

1991-10-01

333

Polypropylene obtained through zeolite supported catalysts

An assay method for ATP sulfurylase is presented which employs Na/sub 2/(35)SO/sub 4/ as a substrate and measures the production of labeled adenosine 5'-phosphosulfate and 3'-phosphoadenosine 5'-phosphosulfate by low-voltage, hanging paper strip electrophoresis. The method is applicable to crude bacterial or mammalian extracts and accurately measures picomole amounts of product(s). Na/sub 2/(/sup 75/)SeO/sub 4/ can also be employed as a substrate, if the unstable radioactive product, adenosine 5'-phosphoselenate, is converted to elemental /sup 75/Se degrees by inclusion of reduced glutathione in the reaction mixture. The same paper strip electrophoretic technique can then be used to separate /sup 75/Se degrees from the radiolabeled substrate. The method also has utility for measuring any direct reduction by crude microbial extracts of radioactive selenate to selenite, independent of ATP sulfurylase.

1989-02-01

334

Polypropylene obtained through zeolite supported catalysts

Propylene polymerizations were carried out with {phi}{sub 2}C(Flu)(Cp)ZrCl{sub 2} and SiMe{sub 2}(Ind)2ZrCl{sub 2} catalysts supported on silica, zeolite sodic mordenite (NaM) and acid mordenite (HM). The polymerizations were performed at different temperatures and varying aluminium/zirconium molar ratios ([Al]/[Zr]). The effect of these reaction parameters on the catalyst activity was investigated using a proposed statistical experimental planning. In the case of f{sub 2}C(Flu)(Cp)ZrCl{sub 2}, SiO{sub 2} and NaM were used as support and the catalyst performance evaluated using toluene and pentane as polymerization solvent. The molecular weight, molecular weight distribution, melting point and crystallinity of the polymers were examined. The results indicate very high activities for the syndiospecific heterogeneous system. Also, the polymers obtained had superior Mw and stereo regularity. (author)

2004-07-01

335

Piezoelectric properties and thermal stability of (Na0.53K0.47-xAgx)Nb1-xSbxO3 ceramics

Propylene polymerizations were carried out with #phi#_2C(Flu)(Cp)ZrCl_2 and SiMe_2(Ind)2ZrCl_2 catalysts supported on silica, zeolite sodic mordenite (NaM) and acid mordenite (HM). The polymerizations were performed at different temperatures and varying aluminium/zirconium molar ratios ([Al]/[Zr]). The effect of these reaction parameters on the catalyst activity was investigated using a proposed statistical experimental planning. In the case of f_2C(Flu)(Cp)ZrCl_2, SiO_2 and NaM were used as support and the catalyst performance evaluated using toluene and pentane as polymerization solvent. The molecular weight, molecular weight distribution, melting point and crystallinity of the polymers were examined. The results indicate very high activities for the syndiospecific heterogeneous system. Also, the polymers obtained had superior Mw and stereo regularity. (author)

2004-01-01

336

British Library Electronic Table of Contents (United Kingdom)

Abstract Many (K1-xNax)NbO3 (KNN)-based ceramics with high piezoelectric performance exhibit undesirable strong temperature dependence due to the orthorhombic-tetragonal polymorphic phase transition near room temperature. In order to improve the temperature stability of the ceramics, many additives have been added into the KNN-based ceramics to shift TO-T down to below room temperature. Contrary to the previous approach (Na0.53K0.47-xAgx)Nb1-xSbxO3 (NKANS) ceramics with TO-T well above room temperature have been prepared by a conventional solid-state reaction method. The density and the electrical properties are effectively improved by the addition of AgSbO3, and optimum piezoelectric properties are found in the ceramics with 0.05---x---0.07, with maximum kp---0.46 for NKANS5 and maximum d...

2011-01-01

337

Oxidation of trivalent arsenic to pentavalent arsenic with oxygen in the presence of nitrite and iodide ions

Oxidation and chromium depletion of Alloy 800 and 316SS by molten NaNO/sub 3/-KNO/sub 3/ at temperatures above 600/degree/C

In view of the effect of the acidity on the oxidation potentials of nitrous, arsenous, and arsenic acids, one should expect a complex relationship between the rate of arsenic (III) to arsenic (V) and the pH of the solution. They studied the kinetics of the reaction 2AsO/sub 2//sup -/ + O/sub 2/ ..-->.. 2AsO/sub 3//sup -/ as functions of concentrations (partial pressure) of all the components of the system NaAsO/sub 2/-HCl(HClO/sub 4/)-NaNO/sub 2/-KI-H/sub 2/O-O/sub 2/ and temperature. The study of the kinetics of arsenic(III) oxidation to arsenic(V) with oxygen in the presence of sodium nitrite and iodide ions showed that the reaction rate passes through a maximum at an acid content of 1.2-2.5 M and rises in proportion to the second exponent of the sodium nitrite concentration and to the first exponent of the iodide ion concentrations and partial oxygen pressure. A fall in the temperature facilitates intensification of the process and ...

1986-10-20

338

Osmoregulation in the Avena coleoptile: control of solute uptake in peeled sections

The corrosion behavior of Alloy 800 and Type 316 stainless steel in molten NaNO/sub 3/-KNO/sub 3/ was studied at temperatures from 605/degree/C to 630/degree/C. Corrosion behavior was significantly different from that previously reported in nitrate melts at temperatures up to 600/degree/C and involved a combination of oxidation, internal nitridation and sodium metallate formation. Corrosion kinetics, determined metallographically, switched from a parabolic to a linear rate equation as temperature increased. Corrosion was uniform and resulted in metal losses on the order of 100 micronsyear at 630/degree/C. Among the alloying elements, chromium was depleted from the alloy as the result of a basic fluxing process. The kinetic equations describing chromium depletion also changed from parabolic to linear with increasing temperature. The effect of the equilibrium chemistry of the melt on the corrosion behavior of the alloys is analyzed and possible corrosion mechanisms ...

1987-01-01

339

Near infrared to red and yellow to blue upconversion emissions from Pr"3"+: ZrF_4-BaF_2-LaF_3-YF_3-AlF_3-NaF glasses

Peeled Avena sativa coleoptile sections have been used to study the control of solute uptake under conditions where the uptake is not limited by the cuticular barrier. In the presence of 2% sucrose, auxin enhances the rate at which the total osmotic solutes increase, but this appears to be a response to the increased growth rate, inasmuch as the auxin effect is eliminated when growth is inhibited osmotically. When sections are incubated in sucrose or in 10 millimolar NaCl, the osmotic concentration increases until a plateau is reached after 8 to 24 hours. Auxin has no effect on the initial rate of increase in osmotic concentration. This difference in steady-state osmotic concentration is, in part, a response to auxin itself, as it persists when auxin-induced growth is inhibited osmotically. The upper limit for osmotic concentration does not appear to be determined by the turgor pressure, inasmuch as a combination of sucrose and NaCl gave a ...

1982-01-01

340

Ion movements in cell death: from protection to execution

This paper describes the development and a detailed analysis carried out on the luminescence characteristics of Pr"3"+ doped ZrF_4-BaF_2-LaF_3-YF_3-AlF_3-NaF glasses. In the present work our objectives are to elucidate the possible mechanisms that are responsible for NIR to red upconversion process and yellow to blue upconversion emission in terms of energy level schemes from the praseodymium containing fibre optical glass composition. We have studied their different physical and optical properties. Besides our investigation on the upconversion emission of these glasses, normal fluorescence studies have also been undertaken in explaining the mechanisms in demonstrating bright red and blue emissions upon excitations at visible and UV wavelengths. Besides these measurements works, a bright blue colour emission was observed under an UV source (202 nm) and upconverted prominent red emissions were observed with a laser diode (LD of 980 nm). Similarly under a yellow ...

2004-04-15

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

341

Scientific Electronic Library Online (English)

Abstract in english Cell death is preceded by severe disruption of inorganic ion homeostasis. Seconds to minutes after an injury, calcium, protons, sodium, potassium and chloride are exchanged between the cell and its environment. Simultaneously, ions are shifted between membrane compartments inside the cell, whereby mitochondria and endoplasmic reticulum play a crucial role. Depending of the type and severity of injury, two mutually exclusive metastable states can be reached, which predict (more) the final outcome. Cells characterized by large increases in cytosolic [Ca2+], [Na+]; and [Mg2+] swell and die by necrosis; alternatively, cells characterized by high [H+]and low [K+], with normal [Na+] and normal to moderate [Ca2+] increases die by apoptosis. The levels of these ions represent central determinants in signaling events leading to cell death. Their movements are explained mechanistically by specific modulation of membrane transport ...

2002-01-01

342

Interactions of metal cations with anionic groups on the cell Wall of the macroalga vaucheria sp.

Influence of some processing factors on susceptibility to caustic stress corrosion cracking of modified alloy 800

The aim of this article was to investigate the interactions of metal cations in aqueous solutions with the biomass of the freshwater macroalga Vaucheria sp. This problem is important when elaborating new applications of biosorption, e.g. the production of mineral feed additives for livestock from the biomass of algae enriched with microelement ions. Potentiometric titration was applied as a quick and cheap screening test to search for new efficient biosorbents. It revealed a variety of functional groups capable of cation exchange on the macroalgal surface, including carboxyl, phosphate, hydroxyl or amino groups. Fourier transform infrared spectroscopy on natural and chromium-loaded Vaucheria sp. confirmed that carboxyl groups played a dominant role in the biosorption. The study also showed that Ca(II), Na(I), K(I), and Mg(II) ions were released from the biomass after biosorption of Cu(II), Mn(II), Zn(II), and Co(II) ions, indicating that ion exchange was a key ...

2010-06-15

343

Influence of sewage sludge compost applications on uptake of element by cultivated crops in a brown forest soil. Measurement by neutron activation analysis

The influence of some processing factors such as cold work and heat treatment on the susceptibility to caustic stress corrosion cracking (SCC) of modified alloy 800, referred to alloy 800 M, in a boiling solution of 50%NaOH + 0.3%SiO_2+0.3%Na_2S_2O_3 was investigated by means of microstructure examination, tensile test, stress analysis, SCC test of C-rings, Auger electron spectroscopy (AES) and corrosion mode. Cold work led to lengthening of grains, decrease in ductility, increase in strength, residential stress and susceptibility to SCC. With increasing temperature of heat treatment on alloy 800 M after cold work, grains became bigger, ductility increased but strength, residential stress and susceptibility to SCC decreased. SCC cracks on C-ring specimens initiated from pitting and propagated along grain boundaries. AES analysis indicates that the surface films on alloy 800M are enriched in nickel and depleted in iron and chromium. (authors)

2005-07-01

344

Impedance analysis of hydrogen adsorption on palladium in 0. 1 M NaOH solution

A field study was conducted to investigate the absorption of various elements into oats and carrots cultivated in brown forest soil after three years' applications of chemical fertilizer and two types of sewage sludge compost mixed with sawdust (SD compost) or rice husk (RH compost). The results obtained in this study are summarized as follows. 1) The application of SD compost led to a significant increase on the concentrations of Mn, Zn, Ag and Ba in oat root, of Zn and Br in oat shoot, of Cl and Zn in oat ears, of Mg, Sc, Mn, Zn, Br, Ba and La in carrot peel, of Mn, Fe, Co and Zn in carrot edible portion and of Na, Sc, Mn, Fe, Co and Sm in carrot shoot. 2) The application of RH compost increased the concentrations of Mn, Zn, and Ag in oat root, of K, Cr, Mn, Zn and Br in oat shoot, of Zn and Br in oat ears, of Mg, Mn and Br in carrot peel, of Cl, Mn, Zn and Br in carrot edible portion and of Na, Mn, Zn, Br and Sm in carrot shoot. (author)

2006-03-01

345

Formation of colloidal silver nanoparticles stabilized by Na+-poly(gamma-glutamic acid)-silver nitrate complex via chemical reduction process.

The behaviour of hydrogen adsorption on palladium has been investigated by a.c. impedance measurements in 0.1 M NaOH solution of pH 13 at 298 K. The electrode impedance has been measured by superimposing an a.c. voltage of 5 mV amplitude ranging between 10{sup -1} and 10{sup 4} Hz on a d.c. potential range from -0.76 to 0.44 V (standard hydrogen electrode (SHE)). The equivalent circuit representing the hydrogen adsorption reaction is proposed from the analysis of the frequency dependence of electrode admittance. The capacitance, arising from the adsorbed hydrogen, has been determined as a function of applied potential by complex non-linear least-squares curve fitting method based on the proposed equivalent circuit. As the cathodic applied potential increased from -0.36 to -0.76 V (SHE), the adsorption capacitance considerably increased owing to the enhanced coverage of hydrogen adsorbed on the palladium surface. In the applied potential range from -0.36 to 0.24 V ...

1991-10-21

346

Electrochemical and conversion electron Moessbauer study of corrosion induced by acid rain

Macromolecular and polyanionic Na(+)-poly(gamma-glutamic acid) (PGA) silver nitrate complex acted as both a metal ion provider and a particle protector to fabricate nanosized silver colloids under chemical reduction by dextrose. The formation and size of particles have been characterized from transmission electron microscopy (TEM), dynamic light scattering analysis and UV-vis spectrophotometer. The results showed that the average particle size was 17.2+/-3.4 to 37.3+/-5.5 nm, apparently depending on the complex concentration. It was found that the rate constant and conversion of silver nanoparticles were proportional to the concentration of PGA. The growth mechanism of nanosized silver colloid was fully discussed. In addition, the in vitro cytotoxicity evaluated by L929 fibroblasts proliferation and antibacterial activity against Gram-positive strain (methicillin-resistant S. aureus (MRSA)) and Gram-negative strain (P. aeruginosa) bacteria have been assessed. ...

2007-05-18

347

Effect of surface treatemnts on stress corrosion cracking of alloy 800 in alkaline solutions. Alloy 800 no alkaline yoekichu no ouryoku fushoku ware ni oyobosu hyomenkako no eikyo

The passivation of low carbon steel was studied in aqueous solution of 0.5M Na[sub 2]SO[sub 4]+0.001M NaHSO[sub 3] (pH 3.5, 6.5 and 8.5) which can be considered as a model of acid rain. The used conversion electron Moessbauer spectroscopy (CEMS) with the complementary electrochemical investigations proved that the sulfite ions induce pitting corrosion at pH 3.5 and 6.5, while the measurements showed much weaker pitting at pH 8.5. The compositions and thicknesses of the passive films formed during the electrochemical treatments are determined from the CEM spectra. Only [gamma]-FeOOH was found on the surface of the samples at pH 6.5 and 8.5. Nevertheless, at pH 3.5 the sextet belonging to Fe[sub 3]C appears in the spectra, and also FeSO[sub 4].H[sub 2]O could be detected in low concentration. (orig.).

1993-04-01

348

Diminished osmotic fragility of human erythrocytes following the membrane insertion of oxygenated sterol compounds

Effect of the coverage of shot peening, the surface roughness and shot shape, etc. on the stress corrosion cracking (SCC) of Alloy 800 in alkaline solutions was studied. Alloy 800 specimens were cracked in boiling alkaline solutions at the potntial range of {minus} 100 to 0mV in the boiling 50%NaOH+0.3%SiO {sub 2} solution. U bend specimens were tested under the polarized condition at the controlled potential to 0mV, showing that shot peened specimens cracked more easily. Tests of specimens with the same hardness showed that specimens hardened by cold working showed the higher susceptivity than that of surface hardened specimens. In these connections, U bend specimens of higher shot peened coverage were cracked at conditions of 593K and 10%NaOH solution. O-ring specimens of smaller stress level did not show any cracks independent of surface treatments. 8 refs., 9 figs., 5 tabs.

1990-03-15

349

Determination of the hydrolysis constants of Europium (III), in ion strength media 4, 5 and 6 M NaClO{sub 4} at 303 K; Determinacion de las constantes de hidrolisis del Europio (III), en medios de fuerza ionica 4, 5 y 6 M de NaClO{sub 4} a 303 K

Oxygenated sterol compounds (OSC), when incubated for 1 hr with human erythrocytes in lipoprotein-depleted medium at concentrations of 0.625-5 x 10/sup -5/M, are inserted into the cell membrane and remain there despite subsequent washing of the cells. The insertion results in expansion of the surface area of the red cell ghost membrane, an increase in critical hemolytic volume, and as a consequence, in dimished osmotic fragility of the erythrocytes. This effect is seen with echinocyte-forming as well as with non-echinocyte-forming OSC. Erythrocytes treated with OSC do not differ from control cells with respect to their mean cell volume (MCV) in isotonic solution, water content, ion fluxes, and filterability through polycarbonate filters. The shift of the osmotic fragility curve toward lower NaCl concentrations is proportional to the amount of OSC inserted into the red cell membrane. 7BETA-Hydroxycholesterol, 22-ketocholesterol, and 20 ..cap ...

1981-08-01

350

Corrosion of high-level waste packaging materials in disposal relevant brines

This work was made with the purpose to complete information about the hydrolysis constants of Europium (III) in high ion strength media. So it was determined at a ion forces media 4, 5 and 6 M of sodium perchlorate at 303 K. The method used was the potentiometric with the aid of the Super quad computer program. In high ion strength media, the measurements of p H do not correspond directly to negative logarithm of the concentration of hydrogen ions, by this it is necessary to calibrate the electrode in these conditions. The Europium was hydrolized at pC{sub H} values greater 6 in all cases. The potentiometric method used under the described experimental conditions is adequate to determine the hydrolysis constants of Europium (III). According to the results and diagrams of chemical species of Europium obtained we can conclude that the hydrolysis constants, differ by its distribution but not in its identity. (Author)

1999-07-01

351

Comparative investigation of corrosion resistance of steel reinforcement in alinite and Portland cement mortars

Previous corrosion studies identified the materials Hastelloy C4, Ti 99.8-Pd, and carbon steels as promising for the manufacture of long-lived high-level waste containers that could act as an engineered barrier in a rock-salt repository. Here, the efficiency of the corrosion-resistant concept using surface-welded Hastelloy C4 as corrosion protection of carbon steel containers is compared with the corrosion-allowance concept using unalloyed or low-alloyed steels. The materials are examined in three disposal relevant brines (two rich in MgCl_2, one rich in NaCl) at 150 C. The results indicate that welded Hastelloy C4 is highly resistant to corrosion in the NaCl-rich brine. In the presence of sulfides or MgCl_2-rich brines, however, severe pitting corrosion occurs. The three steels investigated are resistant to pitting corrosion in all brines, and their general corrosion rates imply corrosion allowances acceptable for thick-walled containers. In ...

352

Clinical study of p-aminobenzoic acid-N-xyloside Na in advanced cancer patients

The corrosion resistance of steel-reinforced mortar specimens made from alinite cement was investigated using ordinary Portland cement (OPC) specimens as reference. The specimens were prepared and exposed in three different environments: continuous exposure in tap water, interrupted exposure in tap water, and interrupted exposure in 3.5% NaCl solution. The steel weight loss and the half cell potential were measured vs. exposure time, up to the age of 12 months. Pore solution extraction and analysis and porosity determination were also performed. In continuous exposure in tap water, alinite cement provided adequate protection against corrosion. In interrupted exposure in tap water, a higher corrosion was observed for alinite cement compared to OPC. In the case of interrupted exposure in 3.5% NaCl solution, the simultaneous action of free chlorides and oxygen resulted in the depassivation of steel reinforcing bars in alinite and Portland cement ...

1998-07-01

353

Batch test equilibration studies examining the removal of Cs, Sr, and Tc from supernatants from ORNL underground storage tanks by selected ion exchangers

Therapeutic effect of p-aminobenzoic acid-N-xyloside Na (K-247) were studied. Eleven patients with a variety of solid tumors were treated with K-247 alone. K-247 was given orally 800 mg daily for 4 weeks. As for side effect of the drug, only mild gastritis was observed in a few patients. Partial response (over 25% reduction of tumor size) with a median duration of two months was observed in 3 patients. These cases were metastatic tumor of lung from the carcinoma of thyroid, metastatic tumors of lung from the carcinoma of kidney, and mediastinal tumor. In eight patients the response was classified as no change and in one patient there was progressive disease. Thus K-247 has some therapeutic activity in patients with solid tumor. Combination therapy of irradiation and administration of K-247 were also studied. In the twelve patients receiving the combination therapy, partial response was observed in 7 patients with complete response in 3 patients. In some patients it ...

1982-02-01

354

Atmospheric emissions as a tool in evaluation of sustainability research in oil industry; Emissao atmosferica como uma ferramenta na avaliacao do desenvolvimento sustentavel na industria do petroleo

Bench-scale batch equilibration tests have been conducted with supernatants from two underground tanks at the Melton Valley Storage Tank (MVST) Facility at Oak Ridge National Laboratory (ORNL) to determine the effectiveness of selected ion exchangers in removing cesium, strontium, and technetium. Seven sorbents were evaluated for cesium removal, nine for strontium removal, and four for technetium removal. The results indicate that granular potassium cobalt hexacyanoferrate was the most effective of the exchangers evaluated for removing cesium from the supernatants. The powdered forms of sodium titanate (NaTiO) and cystalline silicotitanate (CST) were superior in removing the strontium; however, for the sorbents of suitable particle size for column use, titanium monohydrogen phosphate (TiHP {phi}), sodium titanate/polyacrylonitrile (NaTiO-PAN), and titanium monohydrogen phosphate/polyacrylonitrile (TiP-PAN) gave the best results and were about ...

1995-06-01

355

{ital J}/{ital {psi}} Suppression in Pb-Pb Collisions: A Hint of Quark-Gluon Plasma Production?

This work is directly to analysis of atmosphere surrounding Ipiranga Refinery; witch is located in the city of Rio Grande, in estate of Rio Grande do Sul. The refinery is surrounded by neighborhood, witch are impacted by atmospheric emissions of refinery. The objective of this work is correlating the refinery to the inhabitants that lives near the refinery, using an environmental sustainability index. This work will be achieve by analysis of Polycyclic Aromatic Hydrocarbons (PAH) bounded in particulate matter with diameter of 100 {mu}m (PTS), the acquisition of health data on the city hospitals and correlation of this data with PAH concentrations in Particulate Matter. The Samples were obtain by FEPAM, witch have three samples sites in the center of city. The samples was obtained by a High Volume Sampler equipped with quartz fiber filters. The meteorological data important to this work, like wind direction and speed, will be obtain in Meteorological Station on FURG. The results expect ...

2008-07-01

356

Zinc determination in medicinal powders by radionuclide X-ray fluorescence analysis

The NA50 Collaboration has recently observed a strong suppression of {ital J}/{psi} production in Pb-Pb collisions at 158GeV/nucleon. We show that this recent observation finds a quantitative explanation in a model which relates the suppression mechanism to the local energy density, whose value is higher in Pb-Pb collisions than in any other system studied previously. The sensitivity of the phenomenon to small changes in the energy density could be suggestive of quark-gluon plasma formation. {copyright} {ital 1996 The American Physical Society.}

1996-08-01

357

Theoretical study of the phonon properties of SrS

X-ray fluorescence analysis was used to determine the zinc content of the ''Perilacin'' powder and the ZnO content of the ''Epiderman-pix'' powder. The characteristic Ksub(#alpha#) line of zinc was excited using a "1"4"7Pm/Mo source (10"7 s"-"1) and the molybdenum Ksub(#alpha#) line (17.47 keV). 4 to 5% Zn and 45 to 49% ZnO were determined with a NaI(Tl) scintillation detector. The radiation intensity was found to decrease with particle size. (M.K.).

1977-01-01

358

Synthesis and Structural Characterization of a Novel Indium Mercapto Derivative (Clln(SCH2(CO) O)2)2-((4-MepyH)2)2+.

Using an ab initio pseudopotential method within a generalized gradient approximation of the density functional theory, the structural, electronic, and phonon properties of SrS in the B1 (NaCl) and B2 (CsCl) structures have been studied. The calculated lattice constants, static bulk modulus, and first-order pressure derivative of the bulk modulus are reported for both the B1 and B2 structures and compared with previous experimental and theoretical calculations. Electronic band structures and densities of states have been derived for SrS. Subsequently, a linear-response approach to the density functional theory is used to derive the phonon frequencies and densities of states.

2009-05-25

359

Shielded and unshielded geometries in the search for orphan sources

The synthesis and structural characterization of a novel In(III) complex is described. The reaction between InCl3 with sodium mercapto-acetic acid, (NaSCH2(CO)OH) in 4-methylpyridine, (CH3(C5H5N), (4-Mepy)) at 25 C affords (ClIn(SCH2(CO)O)2)2- ((4-MepyH)2...

2004-01-01

360

Shielded and unshielded geometries in the search for orphan sources

A car-borne NaI(Tl) spectrometric system was used together with a {sup 137}Cs source to obtain realistic data in the search for unshielded and semi-shielded orphan sources. The potassium-stripped counts (PSC) method was used to estimate the influence by the shielding on the detection ability. A reduction of about 5% in the critical distance was obtained for the semi-shielded source. A curve fitting method was also developed and evaluated. Results from the curve fitting method showed inferior ability to find the source compared to the PSC method. However, it can be a useful complementary tool, for characterisation of the source shielding, and estimation of the distance from the road.

2006-05-15

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

361

Removal of "2"3"9Pu from the rat with an orally administered chelon

A car-borne NaI(Tl) spectrometric system was used together with a "1"3"7Cs source to obtain realistic data in the search for unshielded and semi-shielded orphan sources. The potassium-stripped counts (PSC) method was used to estimate the influence by the shielding on the detection ability. A reduction of about 5% in the critical distance was obtained for the semi-shielded source. A curve fitting method was also developed and evaluated. Results from the curve fitting method showed inferior ability to find the source compared to the PSC method. However, it can be a useful complementary tool, for characterisation of the source shielding, and estimation of the distance from the road.

2006-05-01

362

Radius of gyration and intrinsic viscosity of polyelectrolyte solutions

The oral administration of 2,3-dihydroxybenzoic acid (DHB) to rats injected intravenously 1 hr previously with "2"3"9Pu citrate caused an increase in urinary excretion of Pu about 8 times that of animals treated with 0.9% NaCl (controls). Liver retention of Pu was decreased from 18% at 2 days in the control animals to 11% in DHB-treated rats. The skeletal retention was similarly reduced from 56% in the control group to 40% in the DHB-treated animals.

1977-05-01

363

Project scheduling with resources constraints: application in the equipment production for the oil industry; Scheduling de projetos com restricao de recursos: aplicacao na producao de equipamentos para a industria de petroleo

Relatively low molecular weights polyelectrolytes (10{sup 4}-10{sup 6}) behave as worm-like chain when electrostatic repulsions are assumed to govern the excluded volume parameter. Under such conditions, predictions of chain expansion and effect of polyelectrolyte concentrations are made assuming that unperturbed dimensions could be obtained at infinite salt content. Experimental studies of an ionic polysaccharide, namely the Na-hyaluronate, were done and the values obtained for the radius of gyration as well as the intrinsic viscosity at different charge densities are in good agreement with the predictions.

1993-12-31

364

Production of Group IIA atomic and molecular negative ion beams in a cesium-sputter negative ion source

One of the essential steps in the main scope Project Management is the Time Management made by the planning and control of the project schedule. In this work is presented the resource constrained scheduling problem beyond its mathematical formulation and a review of papers about this issue. In sequence is presented a practical example of this model considering a simplified model of an engineering project schedule of oil production equipment. The results obtained with the model application are shown and the conclusions about the work with resource constrained scheduling problems. (author)

2008-07-01

365

Production of Group IIA atomic and molecular negative ion beams in a cesium-sputter negative ion source

The results of an investigation on the production of Group IIA atomic and molecular negative ion beams formed in a cesium-sputter negative ion source are presented. The sputtering material was formed by pressing pellets of stoichiometric mixtures of the Group IIA element carbonates and 10% copper powder. Negative ions of several alkaline-earth elements and their oxides have been observed. Beam intensities as high as 180 pA have been observed for Sr{sup -}and 20 nA for SrO{sup -}. (orig.).

1996-09-11

366

Primary standardization of {sup 242} Am radioactive sources

The results of an investigation on the production of Group IIA atomic and molecular negative ion beams formed in a cesium-sputter negative ion source are presented. The sputtering material was formed by pressing pellets of stoichiometric mixtures of the Group IIA element carbonates and 10% copper powder. Negative ions of several alkaline-earth elements and their oxides have been observed. Beam intensities as high as 180 pA have been observed for Sr"-and 20 nA for SrO"-. (orig.).

1996-09-01

367

Pitting corrosion of steel pipeline in oil-water-gas multiphase flow system

The procedure followed by the Laboratorio de Metrologia Nuclear in Sao Paulo, Brazil, for the standardization of {sup 242g} Am is described. The calibration system was composed of a 4 {pi} gas-flow proportional counter coupled to a pair of NaI(Tl) crystals operating in coincidence. The samples were produced by irradiating dried aliquots of {sup 241} Am with thermal and epithermal neutrons at the IEA-R1 research reactor. The efficiency tracer technique has been applied using {sup 60} Co as tracer. The beta detection efficiency was changed by external absorbers and extrapolated to unity by linear least square fitting applying covariance methodology. (author)

2001-07-01

368

Pitting corrosion of nickel base alloys in halide media

Severe pitting corrosion occurred in a horizontal steel pipeline used to transport multiphase fluid, including water, oil, and natural gas, after 2 months of service. The pitting corrosion rate was up to 42 mm/year. Chemical analysis, X-ray diffractometry, and EDAX showed that the corrosion products mainly consisted of Fe9S8, FeCO3, and NaCl. Calcium containing inclusions were also found in the matrix of the steel, which may accelerate corrosion. The early failure was attributed to the high proportion of water, the slow flow velocity, and the use of unqualified material. (Author)

2000-07-01

369

Photography using in the petroleum industry; A fotografia na industria petrolifera

A computerized corrosion measuring system (EG and G model 350 A) was used to study the influence of Cr, Mo, Ti, Nb and W on the pitting corrosion of nickel base alloys in 3% NaCl at 90"0C. The electrochemical parameters under investigation are the corrosion potential E_c_o_r_r, pitting potential E_p and protection potential E_p_p. The corrosion behaviour of nickel base alloys were studied by using pitting scan and potentiostatic techniques. Values of corrosion potential, pitting potential and protection potential were used for a ranking of alloys for corrosion resistance.

1988-03-06

370

Photoassisted hydrogen generation by integrated electroactive SPE membrane system

The subject of this paper is based on necessity to register occurrence in petroleum industry. Specifically we are making reference about Exploration and Production at petroleum industry, using a photography as job instrument. The PETROBRAS - Petroleo Brasileiro S.A., apply the photography resources in almost all service. The Campos basin Exploration and Production, responsible for 70% Brazil's petroleum production, utilizes photographies in many solutions. This paper is based on the following premises: the photography as register way; the information facility; the technical applies; the use of this register in the academic, scientific and operational ways. (author)

1998-07-01

371

Performance before and after installation of a Power System Stabilizer (PSS). Gedrag voor en na toevoeging PSS

Incorporation of TiO{sub 2}, into perfluoroionomer membrane by treatment with TiC1{sub 4}-methanol has been described. Platinum was used as an electrocatalyst. In order to make the system electronically as well as ionically conducting, the electrode was modified with polypyrrole (PPy). Photopolymerisation of pyrrole was accomplished by immersing TiO{sub 2}-Pt-NaF in pyrrole solution. UV-visible and FT-IR Spectroscopic studies were preformed with regards to the formation of the TiO{sub 2}, Pt and PPy within Nafion matrix. We report the construction and evaluation of this integrated system and establish the feasibility of hydrogen generation thereof. (Author)

2000-04-01

372

Overview of future evolution of the specific consumption of electric energy in the primary aluminium Brazilian industry; Perspectivas de evolucao futura do consumo especifico de energia eletrica na industria brasileira de aluminio primario

The damping of unwanted oscillations in the generator units after a failure can be realized by installing a stabilizer between f.e. the revs of the generator and an input of the voltage regulator. The tuning of a Power System Stabilizer (PSS) is investigated using bode plots. Eigenvalue analysis shows an enlarged system stability margin. The method was tested on an advanced analogue power system simulator. As a result of these tests it appears to be useful to consider the stability as well as the optimal tuning. 5 figs., 6 refs.

1992-10-01

373

Observation of high-lying weak autoionizing resonances of Ne, and Mg atoms by charge-separated photoion-yield method

This article introduces the actual artistic state in energy performance terns of the primary aluminium production in Brazil and in the world. Besides, it is evaluated the future evolution perspectives of the electrical specific consumption in the industrial sector, due to the technological innovation and determined capacity eventual expansions in the productive process. 6 refs., 2 figs, 4 tabs

1996-12-31

374

Observation of high-lying weak autoionizing resonances of Ne, and Mg atoms by charge-separated photoion-yield method

Doubly-excited 2s{sup -1}2p{sup -1}3pnp autoionizing resonance series of Ne atom as well as autoionizing resonances in the 2s region of Na and Mg atoms have been studied with monochromatized synchrotron radiation. Use of charge-separated photoion-yield method allowed us to detect these weak resonances in a clarified way in the yield curves of doubly-charged ions. The observed resonance states have been interpreted with the help of MCDF calculations, and the decay processes of these resonance states are discussed briefly.

2007-03-01

375

Nondestructive analysis for "2"3"2U and decay progeny in animal tissues

Doubly-excited 2s-12p-13pnp autoionizing resonance series of Ne atom as well as autoionizing resonances in the 2s region of Na and Mg atoms have been studied with monochromatized synchrotron radiation. Use of charge-separated photoion-yield method allowed us to detect these weak resonances in a clarified way in the yield curves of doubly-charged ions. The observed resonance states have been interpreted with the help of MCDF calculations, and the decay processes of these resonance states are discussed briefly.

2007-03-01

376

NMR use in structural determination of natural products from Brazilian northeast plants; Uso de RMN na determinacao estrutural de produtos naturais de plantas nordestinas

Direct determination of "2"3"2U and its decay products in animal tissues appears to be feasible using an intrinsic Ge(Li) diode detector (for energies of 5-100 keV) and a NaI(Tl) anticoincidence-shielded Ge(Li) diode for higher-energy gamma photons. The detection sensitivity for "2"3"2U and "2"2"8Th is 0.03 and 0.01 nCi, respectively, using a 300-min counting time.

1977-05-01

377

Macro and micro observations on mortar alternation mechanism under the various solution conditions

This work has carried out a molecular structure characterization of two Brazilian plants, Harpalyce brasiliana Benth and Bredemeyera floribunda Wild, using {sup 1} H and {sup 13} C NMR spectroscopy. NMR spectra were presented and analysed, then several structures have been proposed based on spectral data, and finally the structural determination was done 3 refs., 4 figs., 1 tab.

1995-12-31

378

Lithium isotopes: differential effects in animals

Accelerated aging tests have been conducted to evaluate the long-term durability of cementitious material against aggressive ions. In tests, cementitious specimens were immersed in the solutions containing concentrated aggressive ions at high temperature and it promoted diffusion of the ions in the specimen. This method would be suitable for the evaluation on the aging as the alteration of the specimen would be expected to resemble the natural behavior. This paper presents a classification of alteration mechanism in the immersion tests using MgCl{sub 2} and Na{sub 2}SO{sub 4} solution. This classification was done by relating the changes of compressive strength to microscopic and mineralogical changes.

1995-12-31

379

Kinetic studies of alkali metal gallide decomposition in aqueous hydroxide solutions

Differences in the biological disposition and in the effects of the stable lithium isotopes, Li-6 and Li-7, in animals were characterized. A somewhat higher toxicity was associated with WLiCl compared to XLiCl with NLiCl intermediate. All lithium treatments increased water intake and resulted in weight gain. Peak plasma concentration was slightly high for 6Li than 7LiCl suppressed action potential amplitudes during tetanic stimulation more than NaCl when added to Renger solution bathing ganglia.

1984-04-01

380

Influence of the reductive preparation conditions on the morphology and on the electrochemical performance of Sn/SnSb

Kinetics of decomposition of gallium and alkali metal intermetallic compounds in the systems LiGa-LiOH, LiGa-NaOH and LiGa-KON was studied in the temperature range of 40-80 deg C. It was ascertained that increase in temperature gives rise to increase in decomposition rate, whereas increase in hydroxide concentration involves the reaction deceleration. An assumption was made that the decomposition occurs with superimposing of two mechanisms, i.e. chemical and electrochemical decomposition. Basic kinetic characteristics of the process were determined - decomposition rate constant and current density

2002-01-01

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

381

Fluoride induced changes in protein metabolism in the tissues of freshwater crab Barytelphusa guerini.

Lithium storage metals and alloys can be suitable high-capacity anode materials for lithium-ion batteries, when the morphology is specifically designed. Here, we compare three different Sn/SnSb multiphase anode materials in powder form, which have been prepared in aqueous and organic solution by chemical precipitation using NaBH{sub 4} or Zn as reductive agents. The obtained morphologies, chemical compositions, and the electrochemical performance will be comparatively discussed. The variety of synthesis parameters which have an effect on the morphology of the obtained anode materials will be particularly highlighted.

2004-03-15

382

Examination of electrochemical behavior and structure of oxide films on Ni/sub 60/Nb/sub 40/ alloy in amorphous and crystalline states

Exposure of the freshwater field crab Barytelphusa guerini to a sublethal concentration of NaF (30 mg litre(-1)) caused significant alterations in protein metabolism. After an exposure time of 15 days, the crab was found to have a marked depletion of total protein and free amino acid content. A significant elevation in transaminases, Aspartate aminotransferase (AAT) and Alanine aminotransferase (ALAT), and Glutamate dehydrogenase (GDH) activities was reflected in the free amino acid levels of the tissues. PMID:15092215

1990-01-01

383

Estimative of relative stiffness of the exudate gum polysaccharides

Experiments were conducted which established that the higher passivating capacity of Ni/sub 60/Nb/sub 40/ alloys in the amorphous state and higher efficiency of the anodic process of generation of chlorine (2 N NaCl + HCl to pH = 0) in comparison with the crystalline state are determined by higher homogeneity and density of the passive films formed on the amorphous alloy and by higher electron conduction which depends directly on the difference in the structure of the passive films formed on the alloys in the amorphous and crystalline states.

1988-05-01

384

Effect of pH on the pitting corrosion of austenitic stainless steel in chloride solution

The Smidsrod empirical stiffness parameter (B) of A. occidentale and A. lebbeck gum were determined using the correlation of intrinsic viscosity [#eta#] with ionic strength. The B value of 0.204 and 0.193 found respectively for A. occidentale and A. lebbeck suggests a flexible the molecule. The ionic strength has a greater influence on the [#eta#]. The decrease of [#eta#] increase of I, from 0.01 M to 0.1 M of NaCl, is higher for A. lebbeck (89%) than for A. occidentale (19%). (author)

2001-11-11

385

Effect of ionizing radiation and chemical mutagens on vegetatively reproducing plants. Deistvie ioniziruyushchikh izluchenii i khimicheskikh mutagenov na vegetativno razmnozhaemye rasteniya

This paper deals with the pitting corrosion of evaporators in the liquid - radwaste system of nuclear power stations. Corrosion testrs were conducted by the anodic polalization of specimen in the chloride solution. (1) The initiation of the pitting in SUS 304, SUS 316 stainless steels was inhibited by addition of NaOH and H_3BO_3, however, these addition had no effect on the pitting propagation. (2) Inconel 625 had the resitivity against the pitting initiation superior to that of stainless steels, but this was not necessarily in the case of the pitting propagation. (3) It is noticed for pitting prevention that the environmental and material effect on the pitting initiation differed from that on the pitting propagation. (author).

386

ESR study of X-ray irradiated rare earth (Ln) ion-doped glaserite and Ln ion-doped langbeinite

A study is made of plant sensitivity to mutagens during the processing of seeds. An examination is made of problems concerned with modification mutability, the nature of plant restoration following irradiation. Particular attention is given to mutation changes. A presentation is made of several features of mutant changes initially selected by separate indicators. An examination is made of the possible study of mutant indicator genetics. General data on the forms and varieties produced by the mutagenesis method are given. The book is designed for breeding specialists and geneticists engaged in the study of mutagenesis. 439 references, 27 figures, 66 table.

1981-01-01

387

Determination of constituent elements in some Nigerian medicinal plants by thermal-neutron activation analysis

X-ray irradiation-induced paramagnetic radicals in rare earth (Ln) ion-doped glaserite and Ln ion-doped langbeinite were studied by means of ESR technique, aiming at developing the highly sensitive sensor for an ESR dosimetry. The samples were prepared by two kinds of procedures as follows. In one process, the glaserite (K{sub 3}Na(SO{sub 4}){sub 2}) matrix or the langbeinite (K{sub 2}Mg{sub 2}(SO{sub 4}){sub 3}) matrix were synthesized by heating the mixture of K{sub 2}SO{sub 4} and Na{sub 2}SO{sub 4} or the mixture of K{sub 2}SO{sub 4} and MgSO{sub 4} at 1023 K for 1 hour in He flow. The matrices obtained were mixed well with a fixed amount of Ln{sub 2}(SO{sub 4}){sub 3} (Ln=La, Eu, Gd, Lu) powder and heated at 1023 K for 1 hour in He flow. In the other process, the homogeneous mixture of a fixed amount of K{sub 2}SO{sub 4}, Na{sub 2}SO{sub 4} and Ln{sub 2}(SO{sub 4}){sub 3} powders or a fixed amount of K{sub 2}SO{sub 4}, ...

1992-06-01

388

Coordination lanthanide compounds with thiosemicarbazide diacetic acid

This study of the inorganic chemical composition of 10 different Nigerian medicinal plant species, using the technique of instrumental neutron activation analysis (INAA), resulted in the determination of the concentrations of 18 major, minor, and trace elements: Al, Ba, Br, Ca, Cl, Eu, Fe, Ga, K, La, Mn, Na, Sb, Sc, Si, Sm, V, and Zn. The parts of the plants used were roots, leaves, and bark. The NBS SRM 1571 Orchard Leaves was also analyzed to assess the accuracy of the procedures used. 21 refs., 4 tables.

1984-04-02

389

Coordination lanthanide compounds with thiosemicarbazide diacetic acid

A study was made on complex formation of thiosemicarbazide diacetic acid (H/sub 2/L) with neodymium (3), holmium (3) and erbium (3) in solutions and formation of complexes of metal: ligand=4:1 composition was revealed. Synthesis conditions were developed and products of LnLClxnH/sub 2/O, LnLOHxnH/sub 2/O, Na(LnL/sub 2/)xnH/sub 2/O composition were separated in crystalline state. It was shown, that H/sub 2/L behaves in these compounds as tripod ligand with O, O, N, N donor atoms.

1983-02-01

390

Comparative study of passive films of different stainless steels developed on alkaline medium

A study was made on complex formation of thiosemicarbazide diacetic acid (H_2L) with neodymium (3), holmium (3) and erbium (3) in solutions and formation of complexes of metal: ligand=4:1 composition was revealed. Synthesis conditions were developed and products of LnLClxnH_2O, LnLOHxnH_2O, Na[LnL_2]xnH_2O composition were separated in crystalline state. It was shown, that H_2L behaves in these compounds as tripod ligand with O, O, N, N donor atoms.

391

Chronoamperometric study of mild steel pitting in sodium sulfide aqueous solution

Evolution of the passive films formed on AISI 304L and duplex stainless steel SAF 2205 in NaOH 0.1 M was investigated using cyclic voltammetry, electrochemical impedance spectroscopy (EIS) and X-ray photoelectron spectroscopy (XPS). Special attention is paid to the effect of Mo in the generation of the films. Results point out to the stabilising effect of the molybdates on the surface of the film, enhancing the formation of a thin layer on the SAF 2205 with a higher Cr/Fe ratio.

2004-07-30

392

Application of self-adaptive procedure to the thermal problems analysis under steady-state and transient regimens; Aplicacao de procedimento auto-adaptativo na analise de problemas termicos no regime permanente e transiente

Mild steel samples were studied by chronoamperometry in sodium sulfide (Na[sub 2]S) aqueous solution. Pit nucleation and growth also were monitored by optical microscopy. The influence of variables such as temperature, polarization potential, surface roughness, the presence of electrochemically generated oxide layers, and the simultaneous presence of potassium hydroxide (KOH) was studied. The influence of each parameter on pit shape and growth was reviewed. Different reactions and competitive processes were proposed based on the experimental results.

1994-08-01

393

Anodic oxide coatings on metals and anodic protection /2nd revised and enlarged edition/. Anodnye oksidnye pokrytiia na metallakh i anodnaia zashchita /2nd revised and enlarged edition/

This work describes a procedure for the adaptive time dependent Finite Element Method using an automatic mesh refinement (H-Version) that efficiently reduces estimated errors ( a posteriori) below pre-assigned limits. Classical model problem for steady-state heat transfer are investigated, and the results are compared with the analytical solution. Then some typical time-dependent problem are qualitatively analysed. (author) 10 refs., 7 figs.

1990-12-31

394

Aerosol composition, chemistry, and source characterization during the 2008 VOCALS Experiment

The theoretical principles underlying the formation of oxide and, in particular, anodic oxide coatings on metals produced by chemical oxidation, anodizing in solutions, and anodizing in cold plasmas are reviewed. The mechanisms and conditions of anodic oxidation are described, and the structure of anodic oxide coatings on aluminum, magnesium, beryllium, zinc, cadmium, iron, cobalt, nickel, titanium, zirconium, tantalum, and chromium alloys is examined. Attention is also given to various applictins of anodized coatings. 54 references.

1985-01-01

395

A correlation between electrochemical parameters and stress corrosion cracking of alloy 600 in high temperature caustic solution

Chemical composition of fine aerosol particles over the northern Chilean coastal waters was determined onboard the U.S. DOE G-1 aircraft during the VOCALS (VAMOS Ocean-Cloud-Atmosphere-Land Study) field campaign between October 16 and November 15, 2008. SO42-, NO3-, NH4+, and total organics (Org) were determined using an Aerodyne Aerosol Mass Spectrometer, and SO42-, NO3-, NH4+, Na+, Cl-, CH3SO3-, Mg2+, Ca2+, and K+ were determined using a particle-into-liquid sampler-ion chromatography technique. The results show the marine boundary layer (MBL) aerosol mass was dominated by non- sea-salt SO42- followed by Na+, Cl-, Org, NO3-, and NH4+, in decreasing importance; CH3SO3-, Ca2+, and K+ rarely exceeded their respective limits of detection. The SO42- aerosols were strongly acidic as the equivalent NH4+ to SO42- ratio was only ~0.25 on average. NaCl particles, presumably of sea-salt origin, showed chloride deficits but retained ...

2010-03-15

396

[Determination of sulfite in flue gas desulfurization with seawater by ion chromatography].

The properties of the passive films formed on Alloy 600 at different applied potentials in 10% NaOH solution at 315 .deg. C was studied using in situ AC impedance and polarization measurements. The results were correlated with the stress corrosion cracking (SCC) behavior obtained from the C-ring tests in the same conditions. The change of the semiconductive property and the peak of relaxation time were observed at 0.2 V where the SCC rate showed a maximum. These results were also consistent with the prediction parameter for SCC obtained from fast and slow polarization scans.

2001-10-01

397

Phase 2 report on the evaluation of polyacrylonitrile (PAN) as a binding polymer for absorbers used to treat liquid radioactive wastes

The technology for flue gas desulfurization (FGD) with seawater is widely adopted by coal-fired power plants in coastal areas. SO2 in the flue gas is absorbed by alkaline seawater and transfered in aqueous phase as sulfite (SO3(2-)), and most SO3(2-) is transformed to sulfate (SO4(2-)) after an aeration process. The remaining SO3(2-) in the seawater discharged to sea area may be harmful to marine organism because of its biological toxicity, thus it is necessary to determine the concentration of SO3(2-) in the seawater for desulfurization. In this study, the method of determination of SO3(2-) in the seawater by ion chromatography was investigated. The separation was achieved on an IonPac AS14A column with 14 mmol/L NaOH-12 mmol/L Na2 CO3 solution as the mobile phase at a flow rate of 1.2 mL/min, and the detection was performed by a pulsed amperometric detector. Formaldehyde was added as a protective agent when sampling because the SO3(2-) is ...

2009-11-01

398

Passivity behavior of melt-spun Mg-Y Alloys

The performance of PAN-based composite absorbers was evaluated in dynamic experiments at flow rates ranging from 25--100 bed volumes (BV) per hour. Composite absorbers with active components of ammonium molybdophosphate (AMP) PAN and K-Co ferrocyanide (KCoFC) PAN were used for separating Cs from a 1 M HNO{sub 3} + 1 M NaNO{sub 3} + 2 {times} 10{sup {minus}5} M CsCl acidic simulant solution. KCoFC-PAN and two other FC-based composite absorbers were tested for separating Cs from alkaline simulant solutions containing 0.01 M to 1 M NaOH and 1 M NaNO{sub 3} + x {times} 10{sup {minus}4} M CsCl. The efficiency of the Cs sorption on the AMP-PAN absorber from acidic simulant solutions was negatively influenced by the dissolution of the AMP active component. At flow rates of 50 BV/hr, the decontamination factor of about 10{sup 3} could be maintained for treatment of 380 BV of the feed. With the KCoFC-PAN absorber, the ...

1996-05-01

399

Passivity behavior of melt-spun Mg-Y Alloys

Several Mg-Y binary ribbons with Y content up to {approx}17.9 at.% were fabricated by melt-spinning. X-ray diffraction (XRD) revealed that the phase structure changes with increasing Y content from extended solid solution to partially amorphous, and then fully intermetallic Mg{sub 24}Y{sub 5}. Anodic potentiodynamic polarization performed in 0.01 M NaCl electrolyte (pH=12) revealed improved anodic passivity behavior compared to pure Mg for all the Mg-Y alloys. X-ray photoelectron spectroscopy (XPS) revealed that the improved passivity of Mg-Y was more related to the elemental oxidation state rather than the concentration of the surface components. To study the effect of Cl{sup -} ion on the passivity behavior, anodic potentiodynamic and potentiostatic polarization were performed on Mg-17.9 at.% Y in alkaline (pH=12) NaCl electrolytes containing Cl{sup -} ion in the concentration range from 0.00 to 0.50 M. The passive films formed in 0.01 M ...

2003-12-15

400

Minerals and trace elements determination in diets by neutron activation analysis

Several Mg-Y binary ribbons with Y content up to #approx#17.9 at.% were fabricated by melt-spinning. X-ray diffraction (XRD) revealed that the phase structure changes with increasing Y content from extended solid solution to partially amorphous, and then fully intermetallic Mg_2_4Y_5. Anodic potentiodynamic polarization performed in 0.01 M NaCl electrolyte (pH=12) revealed improved anodic passivity behavior compared to pure Mg for all the Mg-Y alloys. X-ray photoelectron spectroscopy (XPS) revealed that the improved passivity of Mg-Y was more related to the elemental oxidation state rather than the concentration of the surface components. To study the effect of Cl"- ion on the passivity behavior, anodic potentiodynamic and potentiostatic polarization were performed on Mg-17.9 at.% Y in alkaline (pH=12) NaCl electrolytes containing Cl"- ion in the concentration range from 0.00 to 0.50 M. The passive films formed in 0.01 M ...

2003-12-15

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

401

Magnetic and transport properties of Ba_2Co_9O_1_4 and Ba_1_._9A_0_._1Co_9O_1_4 (A=La or Na)

In the present study 12 diets, each one consisting of a pool of seven day diets, composed by four meals: breakfast, lunch, dinner and snack, adequate in energy and macro nutrients according to the RDA (Recommended Daily Allowance) recommendations, were elaborated and offered to a group of 12 men (19-42 years). The diets were collected by duplicate portion technique and dried by two different processes: freeze drying and 60 deg C ventilated oven drying. In the total, 24 diets were analyzed. The content of some minerals and trace elements (Ca, Fe, Mg, Mn, Na, Se and Zn) were determined by Instrumental Neutron Activation Analysis. The validation of methodology was made by analysis of the reference materials Typical Diet (NIST SRM 1548"a), Orchard Leaves (NIST SRM 1541) and Peach Leaves (NIST SRM 1547). The results observed by two different drying processes used were statistically compared by test T of Student. It was possible to conclude that the concentration means ...

2002-08-11

402

Electrochemistry and passivity of a Ti-15Mo-3Nb-3Al beta-titanium alloy in ambient temperature aqueous chloride solutions

The valence and spin-state distributions of Co ions and the complex structure of antiferromagnetic Ba_2Co_9O_1_4 have led to the suggestion that doped Ba_2Co_9O_1_4 compounds may be good thermoelectric materials. We have checked this suggestion by measuring the magnetic properties as well as the transport properties of nominal Ba_1_._9A_0_._1Co_9O_1_4 (A=La or Na). We show that although all compounds are indicated to be single phase by powder X-ray diffraction analysis, they are all p-type polaronic conductors with low mobile-hole concentrations. Magnetic-susceptibility data of the parent and La-doped compounds give evidence of a second magnetic phase with ferromagnetic order setting in below 215 K; but this second phase is not seen in the Na-doped sample. We conclude that the structure is stabilized by oxidation and that cation exolution from the Ba_2Co_9O_1_4 structure creates cation vacancies that oxidize the high-spin (HS) Co(II) to the ...

2010-11-01

403

Electrochemical behavior of Ti-Cr alloys in artificial saliva

To understand the effect of Mo-Nb additions on the electrochemical behavior of #beta#-titanium alloys in ambient temperature chloride solutions, characterization of the electrochemistry and passivity of a Ti-15Mo-3Al alloy (#beta#-21S) was undertaken. Both solution heat-treated (SHT) and peak-aged (PA) alloys exhibited passive anodic behavior in aerated and deaerated 0.6M NaCl, aerated and deaerated 0.6M NaCl adjusted to pH 1 with HCl, as well as aerated 5M HCl. X-ray photoelectron spectroscopy (XPS) performed after exposure to neutral 0.6M NaCl indicated that both PA and SHT #beta#-21S formed a predominantly TiO_2 film. Auger electron spectroscopy (AES) and cathodic kinetics suggest that the Mo and Nb alloying additions are incorporated into the oxide in amounts less than that found in the alloys. The predominance of the passivating TiO_2 may explain the similarity of the electrochemical behavior observed. However, in ...

404

Electrochemical behavior of Ti-Cr alloys in artificial saliva

In this study, the corrosion behavior of commercially pure titanium (c.p. Ti), Ti-6Al-4V and five new experimental Ti-Cr alloys was evaluated through open-circuit potential (OCP) and potentiodynamic polarization measurement in an artificial saliva containing fluoride. Electron spectroscopy for chemical analysis (ESCA) was used to characterize the composition of the passive films on the alloy after potentiodynamic polarization measurement. It was found that in standard artificial saliva the OCP increases with higher Cr content in Ti-Cr alloys. In 0.5% NaF artificial saliva, the OCP decreases with decreasing Cr in Ti-Cr alloys, and all but Ti-5Cr remain consistently higher than those of c.p Ti and Ti-6Al-4V. Linear polarization results show that artificial saliva and artificial saliva containing 0.5% NaF result in different corrosion behavior in Ti-Cr alloys, c.p.Ti and Ti-6Al-4V. The Ti-Cr alloys had greater resistance to corrosion in the ...

2009-11-13

405

Dielectric and piezoelectric properties of K0.5Na0.5NbO3-AgSbO3 lead-free ceramics

In this study, the corrosion behavior of commercially pure titanium (c.p. Ti), Ti-6Al-4V and five new experimental Ti-Cr alloys was evaluated through open-circuit potential (OCP) and potentiodynamic polarization measurement in an artificial saliva containing fluoride. Electron spectroscopy for chemical analysis (ESCA) was used to characterize the composition of the passive films on the alloy after potentiodynamic polarization measurement. It was found that in standard artificial saliva the OCP increases with higher Cr content in Ti-Cr alloys. In 0.5% NaF artificial saliva, the OCP decreases with decreasing Cr in Ti-Cr alloys, and all but Ti-5Cr remain consistently higher than those of c.p Ti and Ti-6Al-4V. Linear polarization results show that artificial saliva and artificial saliva containing 0.5% NaF result in different corrosion behavior in Ti-Cr alloys, c.p.Ti and Ti-6Al-4V. The Ti-Cr alloys had greater resistance to corrosion in the ...

2009-11-13

406

Comparative behavior of Alloys 600, 690 and 800 in caustic environments

Lead-free piezoelectric ceramics (1-x)K0.5Na0.5NbO3-xAgSbO3+0.75 mol % MnO2 were prepared by a conventional solid-state sintering technique, and the piezoelectric and dielectric properties of the ceramics were studied. The results of x-ray diffraction suggest that AgSbO3 diffuses into the K0.5Na0.5NbO3 lattices to form a new solid solution with a single-phase orthorhombic perovskite structure. After the addition of AgSbO3, the paraelectric cubic-ferroelectric tetragonal phase transition temperature (TC) and the ferroelectric tetragonal-ferroelectric orthorhombic phase transition temperature (TO-T) decrease, and the ceramics become ``softened,'' resulting in significant improvements in the ferroelectric and piezoelectric properties. The ceramics with x=0.03-0.10 exhibit excellent piezoelectric properties: d33=130-216 pC/N, kp=0.44-0.51, and kt=0.40-0.52. The ceramics also exhibit a good thermal stability up to high TO-T, suggesting that the ...

2009-08-01

407

An investigation on the effect of bleaching environment on pitting corrosion and trans-passive dissolution of 316 stainless steel

Since 1991, secondary side cracking has become a major concern in EDF steam generators. At 350 C, IGSCC of Alloy 600 was found in pure NaOH solutions from 4 to 500 g/l, with a maximum at 100 g/l. From the present results and available data, IGSCC of Alloy 690 occurred in pure NaOH solutions from 40 to 500 g/l, but the greatest sensitivity was observed at 100 g/l. TG/IGSCC of Alloy 800 became more severe with increasing NaOH solutions, from 10 to 500 g/l. On the whole, the ranking for SCC-resistance was Alloy 600 < Alloy 800 < Alloy 690. A significant improvement was still obtained with 690TT with intergranular carbides (industrial tubes) and perhaps with Alloy 800 NG (nuclear grade), but both alloys cracked at the highest stresses. IGSCC susceptibility of Alloy 600 MA was higher for the tubes with the lowest values of the yield stress. The depth of IGA in the case of Alloy 600 was higher than for Alloy 690; for this ...

1995-12-31

408

An example of alkalization of SiO{sub 2} in a blast furnace coke

Pitting corrosion and trans-passive dissolution of 316 stainless steel in solution containing five percent of commercial bleaching liquid was investigated by employing potentiodynamic polarization method and recording corrosion potential during immersion. Today commercial bleaching liquids are widely used as cleaner additives, therefore, those house appliances made from stainless steels are in contact with aqueous solution containing bleaching liquid. This may cause sever localized corrosion and trans-passive dissolution. In order to investigate the possibility of trans-passive dissolution of stainless steel by bleaching liquid, potentiodynamic polarization and recording variation of corrosion potential of specimens were carried out in 0.2 M Na{sub 2}SO{sub 4} solution containing 5 %wt. commercial bleaching liquid. A 500 mV drop in trans-passive potential and also instantaneously ennobling corrosion potential revealed the possibility of trans-passive dissolution ...

2004-07-01

409

Alteration of leached glass surface

Scanning electron microscopy and an electron-microprobe analysis of a sample of blast furnace (BF) coke have revealed alkalization (5.64 wt % Na{sub 2}O + K{sub 2}O) and Al saturation (17.28 wt % Al{sub 2}O{sub 3}) of SiO{sub 2} by BF gases. The K/Na{sub at} value of 1.15 in the new phase (alteration zone) reflects close atomic proportions of the elements and suggests that the abilities to incorporate K and Na during the process are almost equal. This Al saturation and alkalization of SiO{sub 2} indicates an active role for Al along with alkali metals in BF gases. The average width of the altered area in the SiO{sub 2} grain is about 10 m, which suggests that SiO{sub 2} particles of that size can be transformed fully to the new phase, provided that at least one of their faces is open to an external pore (surface of the coke) or internal pore with circulating BF gases. The grains that exceed 10 {mu}m can only be partly ...

2007-09-15

410

Shell-model calculations for the energy levels of the N=50 isotones with A=80--87

The leached glass is subject to leachant attack and results in surface layer alteration which greatly affects the corrosion progress of glass forms. This work studied the composition change, precipitation, pitting corrosion as well as surface layer break and spallation of the leached glass forms. 6 conclusions can be made: 1. The extent of surface layer alteration is related to many factors such as temperature, pH, leachant chemistry, flow rate and leach duration, etc. 2. The alkali element Na is seriously depleted and the elements like U.Ti,Fe, Ca and Mg are enriched in the surface layer. The influence of media has such order: Fe{sub 2}O{sub 3} > Na-bentonite > Zeolite. 3. The precipitate formed in leach test for 56 days at 90 {infinity}C is mostly amorphous, but after 91 days has crystallized. There is K - Ca - Al - Si crystal,the amount of Al, K and Si is increasing, but the amount of Ca is decreasing along with leaching time. ...

1997-07-01

411

Shell-model calculations for the energy levels of the /ital N/=50 isotones with /ital A/=80--87

The detailed features of the calculated energy-level schemes and of the single-particle, orbit-occupancy properties of the low-lying levels of the N=50 isotones "8"0Zn, "8"1Ga, "8"2Ge, "8"3As, "8"4Se, "8"5Br, "8"6Kr, and "8"7Rb are presented and discussed. These results are obtained with a new effective Hamiltonian operator obtained empirically from an iterative fit to experimental energies taken from all experimentally studied (A=82--96) N=50 nuclei. The model space for the calculations consists of active 0f/sub 5/2/, 1p/sub 3/2/, 1p/sub 1/2/, and 0g/sub 9/2/ proton orbits relative to a nominal "7"8Ni core. This space is truncated internally by restricting the number of particles excited from the negative-parity orbits into the g/sub 9/2/ orbit to be no greater than four. The typical structures predicted for these lighter N=50 isotones are found to be dominated by well-mixed combinations of fp-orbit configurations, with the g/sub 9/2/ orbit playing a minor role in ...

9110-01-01

412

Monte Carlo simulations of precise timekeeping in the Milstar communication satellite system

The detailed features of the calculated energy-level schemes and of thesingle-particle, orbit-occupancy properties of the low-lying levels of the/ital N/=50 isotones /sup 80/Zn, /sup 81/Ga,/sup 82/Ge, /sup 83/As, /sup 84/Se,/sup 85/Br, /sup 86/Kr, and /sup 87/Rb arepresented and discussed. These results are obtained with a new effectiveHamiltonian operator obtained empirically from an iterative fit to experimentalenergies taken from all experimentally studied (/ital A/=82--96)/ital N/=50 nuclei. The model space for the calculations consists ofactive 0/ital f//sub 5/2/, 1/ital p//sub 3/2/,1/ital p//sub 1/2/, and 0/ital g//sub 9/2/ proton orbits relativeto a nominal /sup 78/Ni core. This space is truncated internally byrestricting the number of particles excited from the negative-parity orbitsinto the /ital g//sub 9/2/ orbit to be no greater than four. The typicalstructures predicted for these lighter /ital N/=50 isotones are found tobe dominated by well-mixed ...

1989-07-01

413

Mercury and other trace elements in a pelagic Arctic marine food web (Northwater Polynya, Baffin Bay)

The Milstar communications satellite system will provide secure antijam communication capabilities for DOD operations into the next century. In order to accomplish this task, the Milstar system will employ precise timekeeping on its satellites and at its ground control stations. The constellation will consist of four satellites in geosynchronous orbit, each carrying a set of four rubidium (Rb) atomic clocks. Several times a day, during normal operation, the Mission Control Element (MCE) will collect timing information from the constellation, and after several days use this information to update the time and frequency of the satellite clocks. The MCE will maintain precise time with a cesium (Cs) atomic clock, synchronized to UTC(USNO) via a GPS receiver. We have developed a Monte Carlo simulation of Milstar's space segment timekeeping. The simulation includes the effects of: uplink/downlink time transfer noise; satellite crosslink time transfer noise; satellite ...

1995-05-01

414

Mercury and other trace elements in a pelagic Arctic marine food web (Northwater Polynya, Baffin Bay)

Total mercury (THg), methylmercury (MeHg) and 22 other trace elements were measured in ice algae, three species of zooplankton, mixed zooplankton samples, Arctic cod (Boreogadus saida), ringed seals (Phoca hispida) and eight species of seabirds to examine the trophodynamics of these metals in an Arctic marine food web. All samples were collected in 1998 in the Northwater Polynya (NOW) located between Ellesmere Island and Greenland in Baffin Bay. THg and MeHg were found to biomagnify through the NOW food web, based on significant positive relationships between log THg and log MeHg concentrations vs. {delta} {sup 15}N muscle and liver . The slope of these relationships for muscle THg and MeHg concentrations (slope = 0.197 and 0.223, respectively) were similar to those reported for other aquatic food webs. The food web behavior of THg and {delta} {sup 15}N appears constant, regardless of trophic state (eutrophic vs. oligotrophic), latitude (Arctic vs. tropical) or salinity (marine vs. ...

2005-12-01

415

M shell x-ray emission in Pb, Th and U due to L_3 to M sub shell transfer of vacancies

Total mercury (THg), methylmercury (MeHg) and 22 other trace elements were measured in ice algae, three species of zooplankton, mixed zooplankton samples, Arctic cod (Boreogadus saida), ringed seals (Phoca hispida) and eight species of seabirds to examine the trophodynamics of these metals in an Arctic marine food web. All samples were collected in 1998 in the Northwater Polynya (NOW) located between Ellesmere Island and Greenland in Baffin Bay. THg and MeHg were found to biomagnify through the NOW food web, based on significant positive relationships between log THg and log MeHg concentrations vs. #delta# "1"5N muscle and liver . The slope of these relationships for muscle THg and MeHg concentrations (slope = 0.197 and 0.223, respectively) were similar to those reported for other aquatic food webs. The food web behavior of THg and #delta# "1"5N appears constant, regardless of trophic state (eutrophic vs. oligotrophic), latitude (Arctic vs. tropical) or salinity (marine vs. freshwater) ...

2005-12-01

416

Large turbine, central power generation on offshore production facilities

M shell x-ray production cross sections in thick targets of Pb, Th and U by K x-rays of Rb, Nb and Mo respectively have been measured. As the incident K x-ray energies are above the L_3 edge but below L_2 edge energies of the respective target elements under reference, the M x-rays are produced not only due to direct interaction of incident photons with M shell electrons but also due to the shift of the L_3 subshell vacancies to the M shell. The experiment has been performed using a double reflection geometrical setup with a 1 Curie"2"4"1Am gamma ray source and a Si (Li) x-ray spectrometer. The measured values have been compared with those calculated using known values of M and L_3 subshell photoionisation cross sections and fluorescence yields etc., wherever possible. The component of the percentage contribution due to shift of L_3 subshell vacancies to M shell to the total M shell x-ray emission were evaluated and it is seen that the shift of vacancies from L_3 ...

417

K and L x-ray production cross sections excited by 14.00--34.16 MeV #alpha#-particle beams

A case study of a hypothetical offshore production fixed leg platform facility is presented. The purpose of the case study is to demonstrate the advantages offered by modern, fuel efficient large gas turbines in central power generation service for offshore production. The case study was presented using the Rolls- Royce RB211 large gas turbine with facility production of approximately 240,000 BPD of oil and 540 MMSCFD of associated gas. The gas was subjected to three stages of separation for removal of hydrocarbon liquids and water. The liquids, natural gas, and crude oil were exported from the production platform to an onshore receiving terminal. Gas compression is the service that requires the greatest amount of power for any given production facility. For this case study, gas compression represented approximately 70 per cent of the power load with the remainder represented by the liquid export pumps (16 per cent), and by general utilities (14 per cent). The case ...

2005-07-01

418

Hybrid apparatus for Bose-Einstein condensation and cavity quantum electrodynamics: Single atom detection in quantum degenerate gases

K and L-shell x-ray production cross sections were measured using #alpha#-particle beams of 14.00 to 34.16 MeV. The K-shell measurements ranged from Z = 20 to Z = 50 and included Ca, Sc, Ti, V, Fe, Ni, Cu, Zn, Ga, Br, Rb, Sr, Y, Mo, Ag, In, and Sn while the L-shell measurements ranged from Z = 55 to Z = 92 and included Cs, Ba, Ce, Gd, Tm, Lu, Au, Pb, Th, and U. Thin metallic foils were used for the measurements and corrections for self-attenuation were negligible. A liquid nitrogen cooled Si(Li) detector and associated pulsed optical electronics were used in detecting x-rays. Absolute cross sections with an uncertainty of +-10 percent are presented for the elements measured. Also smoothed cross sections are presented which were generated by a three term polynomial fit of the experimental data points. By use of available fluorescence yields the K-shell data were converted to ionization cross sections and compared to various theoretical models. The data suggest the ...

419

Fluxes of H+ and K+ in corn roots

We present and characterize an experimental system in which we achieve the integration of an ultrahigh finesse optical cavity with a Bose-Einstein condensate (BEC). The conceptually novel design of the apparatus for the production of BECs features nested vacuum chambers and an in vacuo magnetic transport configuration. It grants large scale spatial access to the BEC for samples and probes via a modular and exchangeable ''science platform.'' We are able to produce 87Rb condensates of 5x106 atoms and to output couple continuous atom lasers. The cavity is mounted on the science platform on top of a vibration isolation system. The optical cavity works in the strong coupling regime of cavity quantum electrodynamics and serves as a quantum optical detector for single atoms. This system enables us to study atom optics on a single particle level and to further develop the field of quantum atom optics. We describe the technological modules and the operation of the combined ...

2006-06-01

420

Fission product and actinide release from the debris bed test Phebus FPT4: synthesis of the post test analyses and of the revaporisation testing of the plenum samples

We report here on an experimental system that utilizes ion-selective microelectrodes to measure the electrochemical potential gradients for H"+ and K"+ ions within the unstirred layer near the root surface of both tact 4-day-old corn seedlings and corn root segments. Analysis of the steady state H"+ and K"+ electrochemical potential gradients provided a simultaneous measure of the fluxes crossing a localized region of the root surface. Net K"+ influx values obtained by this method were compared with unidirectional K"+ ("8"6Rb"+) influx kinetic data; at any particular K"+ concentration, similar values were obtained by either technique. The ion-specific microelectrode system was then used to investigate the association between net H"+ efflux and net K"+ influx. Although the computed H"+K"+ stoichiometry is dependent upon the choice of diffusion coefficients, the values obtained were extremely variable, and net K"+ influx rarely appeared to be charge-balanced by H"+ ...

1987-01-01

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

421

Evidence for the presence of two supracrustal sequences in the central Wind River Mountain, Wyoming

The Phebus FP project in an international reactor safety project. Its main objective is to study the release, transport and retention of fission products in a severe accident of a Light Water Reactor (LWR). The FPT4 test was performed with a fuel debris bed geometry, to look at late phase core degradation and the releases of low volatile fission products and actinides. Post Test Analyses results indicate that releases of noble gases (Xe, Kr) and high-volatile fission products (Cs, I) were nearly complete and comparable to those obtained during Phebus tests performed with a fuel bundle geometry (FPT1, FPT2). Volatile fission products such as Mo, Te, Rb, Sb were released significantly as in previous tests. Ba integral release was greater than that observed during FPT1. Release of Ru was comparable to that observed during FPT1 and FPT2. As in other Phebus tests, the Ru distribution suggests Ru volatilization followed by fast redeposition in the fuelled section. The ...

2006-03-01

422

DNA rearrangements from #gamma#-irradiated normal human fibroblasts preferentially occur in transcribed regions of the genome

Supracrustal rocks, although volumetrically minor, are found throughout the Archean basement of the central and northern Wind River Mountains. Detailed mapping in the Medina Mountain area suggests that at least two discrete sedimentation events are preserved. The older sequence occurs as melanosomes in a multiple deformed migmatitic gneiss. Rock types include mafic rocks (metavolcanics.), calc-silicates, iron formation and rare pelites. Although retrogression is widespread, small patches with granulite mineralogies are found preserved. The younger supracrustal sequence consists of banded amphibolites, calc-silicates, semipelitic and pelitic gneiss. These rocks form synformal structures that are up to 4 km in length. The coherent nature of these rocks and the lack of the aforementioned porphyritic dikes strongly suggests that this sequence, the Medina Mountain. Supracrustals (MMS) is considerably younger than the supracrustal rocks found in the migmatites. The authors propose that the ...

1985-01-01

423

Cellular dosimetry: Absorbed fractions for monoenergetic electron and alpha particle sources and S-values for radionuclides uniformly distributed in different cell compartments

Full text: DNA rearrangement events leading to chromosomal aberrations are central to ionizing radiation-induced cell death. Although DNA double-strand breaks are probably the lesion that initiates formation of chromosomal aberrations, little is understood about the molecular mechanisms that generate and modulate DNA rearrangement. Examination of the sequences that flank sites of DNA rearrangement may provide information regarding the processes and enzymes involved in rearrangement events. Accordingly, we developed a method using inverse PCR that allows the detection and sequencing of putative radiation-induced DNA rearrangements in defined regions of the human genome. The method can detect single copies of a rearrangement event that has occurred in a particular region of the genome and, therefore, DNA rearrangement detection does not require survival and continued multiplication of the affected cell. Ionizing radiation-induced DNA rearrangements were detected in several different ...

2003-08-17

424

Uptake of radiolabeled ions in normal and ischemia-damaged brain

The importance of cellular dosimetry in both diagnostic and therapeutic nuclear medicine is becoming increasingly recognized. Experimental range-energy relations for electrons and alpha particles, along with derived geometric reduction factors, are used to calculate cellular absorbed fractions for these radiations. The resulting absorbed fractions are employed to calculate cellular S-values for several radionuclides. Cellular absorbed fractions for monoenergetic electron sources with energies ranging from 0.1 keV to 1 MeV, distributed uniformly in the source region, are calculated for several target {l_arrow} source combinations including cell{l_arrow}cell, cell{l_arrow}cell surface, nucleus{l_arrow}nucleus, nucleus {l_arrow}cytoplasm and nucleus {l_arrow}cell surface. Similar data are also provided for monoenergetic alpha particle sources with energies ranging from 3 to 10 MeV. S-values are also conveniently tabulated for {sup 32}P, {sup 35}S, {sup 86}Rb, {sup ...

1994-02-01

425

Measurement and analysis of neutron production cross sections and determination of some reaction rates for nuclear astrophysical calculations

The regional concentrations of nine radiochemicals were measured in rat brain after induction of cerebral ischemia to identify tracers concentrated by brain undergoing selective neuronal necrosis. Transient (30 minute) forebrain ischemia was produced in the rat; 24 hours after cerebral recirculation the radiochemicals were injected intravenously and allowed to circulate for 5 hours. The brain concentrations of the radiochemicals in dissected regions were determined by scintillation counting. Forebrain ischemia of this nature will produce extensive injury to striatal neurons but will spare the great majority of neocortical neurons at 24 hours. The regional concentrations of these radiochemicals varied considerably in both control and ischemic animals. In postischemic animals, 4 radionuclides (/sup 63/Ni, /sup 99/TcO/sub 4/, /sup 22/Na, and (/sup 3/H)tetracycline) were concentrated in the irreversibly damaged striatum in amounts ranging from 1.4 to 2.4 times greater ...

1986-05-01

426

310 nm irradiation of atmospherically relevant concentrated aqueous nitrate solutions: nitrite production and quantum yields.

The absolute cross sections of "2"3Na(p,n)"2"3Mg, "2"7Al(p,n)"2"7Si and "3"0Si(#alpha#,n)"3"3S reactions were measured in the incident energy range of 5.05 to 5.80, 5.80 to 6.25 and 3.975 to 6.235 MeV respectively using a spherically shaped 4#pi# neutron detector. In the energy range 5.80 to 7.80 and 6.235 to 11.30 MeV the absolute cross sections of "2"3Na(p,n)"2"3Mg and "3"0Si-(#alpha#,n)"3"3S reactions were determined by optical model calculations. The cross sections of the inverse reactions "2"3Mg(n,p)"2"3Na and "3"3S(n,#alpha#)"3"0Si were also calculated by the same method for the neutron energy range of 10 keV to 7.50 MeV for each reaction. The cross section of the latter reaction in the neutron energy range of 10 keV to 840 keV was also determined from its inverse reaction "3"0Si(#alpha#,n)"3"3S by the application of the detailed balance theorem. The reactions for which the cross sections were determined are of ...

427

WASTE TREATMENT AND DISPOSAL PROGRESS REPORT FOR JUNE AND JULY 1962

The heterogeneous processing of atmospheric aerosols by reaction with nitrogen oxides results in the formation of particulate and adsorbed nitrates. The water content of these hygroscopic nitrate aerosols and consequently the nitrate ion concentration depend on relative humidity, which can impact the physicochemical properties of these aerosols. This report focuses on the 310 nm photolysis of aqueous sodium and calcium nitrate solutions at pH 4 over a wide concentration range of nitrate ion concentrations representative of atmospheric aerosols. In particular, the quantum yield (phi) of nitrite formation was measured and found to significantly decrease at high concentrations of nitrate for Ca(NO(3))(2). In particular, phi for Ca(NO(3))(2) was found to have a maximum value of (7.8 +/- 0.1) x 10(-3) for nitrate ion solution concentrations near one molal, with the smallest quantum yield for the highest concentration solution above 14 m nitrate ion, phi = (2.3 +/- 2.0) x 10(-4). The effect ...

2008-12-25

428

The phosphate complexation of neptunium(V)

9 9 simulated Purex waste oxides was investigated as a function of Na/sub 2/O, CaO and P/sub 2/O/sub 5/ content. All compositions lost some sulfate at 50 to 100 deg C above the softening point. In generai the volatility decreased with increase of either Na/ sub 2/O or CaO relative to P/sub 2/O/sub 5/, but no simple correlation Was indicated. Softening temperatures were lowered by inc ease in Na/sub 2/O vs CaO. Ceramic solids were obtained but no true glasses. Attempts to produce glasses by addition of varying combinations of Al/sub 2/O/sub 3/, PbO, BaO, and B/sub 2/O/ sub 3/ to simulated Pure x waste plus phosphite were unsuccessful. The use of 0.005 M Na/sub 2/C/O/sub 3/ to precipitate calcium from wastes containing up to 3 ppm of phosphate was demonstrated in four pilot plant runs and produced a decrease in the hardness of the waste leaving the clarifier. An inadvertent ...

1962-12-19

429

Systematic evaluation of pre-HPLC sample processing methods on total and individual isoflavones in soybeans and soy products

The phosphate complexation of Np(V) is investigated in the pH range from 6.4 to 10.0 in 0.1 M NaClO_4 at 22#+-#2 C by absorption spectroscopy. The formation of two phosphate complexes is confirmed by spectroscopic speciation: NpO_2HPO"-_4 at 988.8 nm and NpO_2PO"2"-_4 at 993.6 nm with molar extinction coefficients of 251#+-#8 and 201#+-#11 1/mol cm, respectively. The complexation constants are determined to be log #beta# = 2.54#+-#0.02 for NpO_2HPO"-_4 and log #beta# = 6.33#+-#0.08 for NpO_2PO"2"-_4. The competition of the phosphate complexation with the carbonate complexation is demonstrated by speciation calculation under different geochemical conditions. (orig.).

1996-01-01

430

British Library Electronic Table of Contents (United Kingdom)

There are mainly two protocols in isoflavone analysis, one that involves hydrolysis prior to HPLC analysis and the other direct HPLC analysis. In this study, three different hydrolysis methods were systematically re-evaluated, and compared with direct HPLC analysis. Acidic hydrolysis (1.2-3M HCl in ethanol at 80^oC) showed a maximum conversion of ca. 92% from glucosides to aglycones in 2h; however, longer reaction caused degradation of genistein. Alkaline hydrolysis using 2M NaOH converted acetylglucosides and malonylglucosides to their respective glucosides within 10min. Glucuronidase from H. pomatia effectively converted isoflavone glucosides and acetylglucosides to aglycones. Quantification of the total isoflavones in various soy food products showed no significant difference among dire...

2011-01-01

431

Synthesis of I-125 labeled photoaffinity rapamycin analogs

Study of protein-protein interactions in under saturated and supersaturated lysozyme solutions in heavy water as a function of temperature; Etude des interactions proteine-proteine en solutions sous-saturees et sursaturees de lysozyme dans l`eau lourde en fonction de la temperature

Two no-carrier-added "1"2"5I-labelled photoaffinity rapamycin analogs were prepared: 7-demethoxy-7-(4-azido-3-"1"2"5I-benzyloxy) rapamycin and its C_2_8-C_2_9 seco analog. The key reactions of the synthesis were substitution of the C_7 methoxyl of rapamycin with 4-azido-3-tributylstannylbenzyloxy group, exchange of tributyltin with "1"2"5I using Na"1"2"5I and Chloramine-T, and a ZnCl_2 mediated retro-Aldol cleavage of the C_2_8-C_2_9 bond of rapamycin. (author).

432

Studies on the separation of Ag(I) during the recovery of Pu by ammonium plutonium(III) oxalate precipitation methodology

We have studied freshly prepared lysozyme solutions in heavy water for two NaCl concentrations as a function of temperature. Lysozyme solubilities in this solvent are determined by static light scattering. By small angle neutron scattering, we evidence that interactions between lysozyme molecules are characterized by a second virial coefficient A{sub 2} whether the solution is under-saturated or supersaturated. From the variation of A{sub 2} as a function of temperature we have evaluated the enthalpy corresponding to the interaction between lysozyme molecules. We show that the interactions between protein molecules are higher in heavy water than in light water. (authors). 13 refs., 3 figs.

1996-04-01

433

Structure of Mgn and Mg n + clusters up to n = 30

Studies on the separation of Ag(I) during the recovery of Pu from analytical waste generated during potentiometric determination of Pu using AgO as oxidant, by precipitation of Pu as ammonium plutonium (III) oxalate have shown that most of the Ag(I) is separated during the reduction of Pu to Pu(III) state by ascorbic acid. A decontamination factor of 54 was obtained. Additional a decontamination factor of 5.8 was obtained during the precipitation of Pu as ammonium plutonium (III) oxalate. The Ag content was determined by gamma spectrometry, using "1"1"1Ag as a tracer (T_1_/_2 7.45 d, #gamma# 342.1 keV) and HPGe as detector. The studies indicate that Ag is preferentially separated almost quantitatively during the recovery of plutonium, when acidity adjustment is done with NaOH instead of NH_3. (author)

2007-02-14

434

British Library Electronic Table of Contents (United Kingdom)

We present structure calculations of neutral and singly ionized Mg clusters of up to 30 atoms, as well as Na clusters of up to 10 atoms. The calculations have been performed using density functional theory (DFT) within the local (spin-)density approximation, ion cores are described by pseudopotentials. We have utilized a new algorithm for solving the Kohn-Sham equations that is formulated entirely in coordinate space and, thus, permits straightforward control of the spatial resolution. Our numerical method is particularly suitable for modern parallel computer architectures; we have thus been able to combine an unrestricted simulated annealing procedure with electronic structure calculations of high spatial resolution, corresponding to a plane-wave cutoff of 954 eV for Mg. We report the geo...

2011-01-01

435

Structure and antimicrobial activity relationship of quaternary N-alkyl chitosan derivatives against some plant pathogens

British Library Electronic Table of Contents (United Kingdom)

In the present work, quaternary chitosans as water-soluble compounds were prepared based on three-step process. Schiff bases were firstly synthesized by the reaction between the amino groups of chitosan with aliphatic aldehydes followed by a reduction with sodium borohydride (NaBH4) to form N-(alkyl) chitosans. N,N,N-(dimethyl alkyl) chitosans were then obtained by a reaction of chitosan containing N-butyl, N-pentyl, N-hexyl, N-heptyl, and N-octyl substituents with methyl iodide. The compounds were characterized using IR and NMR spectroscopy. Subsequent experiments were conducted to test their antimicrobial activities against the most economic plant pathogenic bacteria of crown gall disease Agrobacterium tumefaciens, soft mold disease Erwinia carotovora, fungi of grey mold Botrytis cinerea...

2010-01-01

436

Solubility of AmOHCO{sub 3} in aqueous solution under atmospheric conditions

Sodium hideout studies in steam generator crevices

Modeling calculations on the solubility of americium have indicated that basic americium carbonate, and not americium trihydroxide, is the solubility-controlling solid in the pH range from 6 to 10 under the influence of atmospheric CO{sub 2}. The solubility of crystalline {sup 243}AmOHCO{sup 3} has been investigated in batch experiments in near-neutral and basic solutions as a function of dissolution time in 0.1 M NaClO{sup 4} at room temperature under oxic conditions. After the solutions reached steady-state conditions, the influence of dissolved solids on the americium concentration in the supernatant solution was studied by utilizing several experimental methods to separate the solution phase from the solid. The solids were characterized by X-ray powder diffraction analysis.

1987-12-01

437

Simplified electrostatic model for band-gap underestimates in the local-density approximation

The steam generator availability is one of the important problems encountered during the pressurized water nuclear plant operation. Various kinds of corrosion phenomena were observed in the past. These phenomena result from the concentration of impurities mainly in three locations in the steam generators: the tubesheet crevices, the tube support plate crevices, and the sludge pile. Corrections were made in the design and the materials used but a number of steam generators suffer or will suffer from corrosion processes inducing in many cases forcing their replacement. In order to prevent or to retard the corrosions several laboratories have performed experiments to reproduce and to study the corrosion processes. The first step of the degradation is the concentration of chemical species. A method using /sup 24/Na as a radioactive tracer was used to establish the concentration kinetics of caustic which was identified as the major cause of the intergranular attack ...

438

Shifts in soil organic matter composition following treatment with sodium hypochlorite and hydrofluoric acid

An estimate of the undercounted electrostatic energy terms in local-density-functional total-energy calculations for nonmetallic systems with separated electron-hole pairs is used to derive a simplified correction to density-functional - theory band gaps. The correction is evaluated for Ne, Ar, Kr, LiF, NaCl, CsCl, MgO, CaS, BaS, C, AlP, and Si. The band-gap errors are reduced from 40-50% to 10-15% for most of the systems studied. Conduction-band corrections are shown to be nearly as large as valence-band corrections in free-electron-like semiconductors. 28 references, 1 figure.

1985-04-15

439

British Library Electronic Table of Contents (United Kingdom)

A renewed interest in chemical fractionation of soil organic matter (SOM) originates from the premise that it enables to isolate labile SOM from SOM protected through mineral binding and recalcitrant SOM. Both selective removal of labile non-bound SOM through oxidation or hydrolysis as well as selective removal of minerals and attached SOM are often applied. Molecular-level SOM characterization by means of temperature resolved Pyrolysis-Field Ionization Mass Spectroscopy analysis (Py-FIMS) was used here as an approach to obtain insight into the fate of SOM upon wet chemical treatment with regard to composition and thermal stability. The applied sequential chemical treatment with 6% NaOCl and 10% HF yielded similar sizes in stable SOM fractions between sandy semi-native heathland and cultiv...

2009-01-01

440

Removal of short range order minerals prior to grain size analysis of volcanic ash soils

British Library Electronic Table of Contents (United Kingdom)

Abstract Incomplete dispersion of aggregates is a well known difficulty when analyzing soil texture of Andosols, particularly if no fresh soil material is available. To facilitate such investigations, several dispersion procedures were carried out on air dried samples rich in short range order minerals, originating from selected Andosol profiles (S Mexico). As a result, we propose an improved method based on a sequential chemical treatment with K oxalate, NH4 oxalate, and oxalic acid that reliably removes cementing agents and allows for a stable dispersion of soil particles after addition of Na pyrophosphate. This method was proved to be well reproducible and highly reliable for routine grain size determinations. The potential error caused by the inherent risk of dissolving primary mineral...

2010-01-01

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441

Relationship between the electronic structure of passive films and the susceptibility to pitting corrosion of stainless steels; Relations entre la structure electronique des films de passivation formes sur les aciers inoxydables et la susceptibilite de ces derniers a la corrosion par piqures

Reference materials to evaluate measurement systems for the nutrient composition of foods: results from USDA?s National Food and Nutrient Analysis Program (NFNAP)

The passive films formed on 316L stainless steel in various NaCl solutions have been investigated by capacitance measurements (Mott-Schottky). Pitting parameters have been determined using the galvano-kinetic polarisation method. The obtained results reveal the existence of a shallow and a deep donor level localised in the band gap of the semiconducting oxide film. These energy levels are due to iron ions in the tetrahedral and octahedral positions. It also appears that the participation of the deep donor level effects the electric field. The study developed allows us to compare characteristic parameters of the electronic structure of the passive film to those related to pitting susceptibility. (authors) 25 refs.

1998-04-01

442

British Library Electronic Table of Contents (United Kingdom)

Over a 6.5-year period a total of 2554 values were reported by nine laboratories for 259 certified or reference nutrient concentrations in 26 certified reference materials (CRM) submitted to contract laboratories, blinded, as part of the qualifying process for analytical contracts and in the routine sample stream as part of the National Food and Nutrient Analysis Program. Each value was converted to a Z?-score, reflecting the difference from the assigned value related to the combined expected analytical uncertainty plus the uncertainty in the CRM value. Z?-scores >|3.0| were considered unacceptable. For some nutrients (Na, folate, dietary fiber, pantothenic acid, thiamin, tocopherols, carotenoids, monounsaturated, and polyunsaturated fatty acids), >20% of Z?-scores were >|3.0|. For total f...

2007-01-01

443

Rapamycin (sirolimus) protects against hypoxic damage in primary heart cultures via Na^+/Ca^2^+ exchanger activation

British Library Electronic Table of Contents (United Kingdom)

Aims: Rapamycin (sirolimus) is an antibiotic that inhibits protein synthesis through mammalian targeting of rapamycin (mTOR) signaling, and is used as an immunosuppressant in the treatment of organ rejection in transplant recipients. Rapamycin confers preconditioning-like protection against ischemic-reperfusion injury in isolated mouse heart cultures. Our aim was to further define the role of rapamycin in intracellular Ca^2^+ homeostasis and to investigate the mechanism by which rapamycin protects cardiomyocytes from hypoxic damage. Main methods: We demonstrate here that rapamycin protects rat heart cultures from hypoxic-reoxygenation (H/R) damage, as revealed by assays of lactate dehydrogenase (LDH) and creatine kinase (CK) leakage to the medium, by MTT (3-[4,5-dimethylthiazol-2-yl]-2,5-d...

2011-01-01

444

RHEED, AES and XPS studies of the passive films formed on ion implanted stainless steel

RHEED, AES and XPS studies of the passive films formed on ion implanted stainless steel

P-implantation (10"1"7 ions cm"-"2, 40 KeV) into 304 stainless steel (ss) has been carried out, and an amorphous surface alloy was formed. Polarization studies in deaerated 1N H_2SO_4+ 2% NaCl showed that P-implantation improved both the general and localized corrosion resistance of 304 ss. A comparative study has been carried out between the implanted and unimplanted steel to determine what influence P-implantation has upon the properties of the passive film formed 1N H_2SO_4. The influence of Cl ions on pre-formed passive films was also studied. RHEED, XPS and AES were used to evaluate the nature of the passive films formed in these studies.

2005-05-26

445

Preparation of cost-effective Pt-Co electrodes by pulse electrodeposition for PEMFC electrocatalysts

P-implantation (10/sup 17/ ions cm/sup -2/, 40 KeV) into 304 stainless steel (ss) has been carried out, and an amorphous surface alloy was formed. Polarization studies in deaerated 1N H/sub 2/SO/sub 4/+ 2% NaCl showed that P-implantation improved both the general and localized corrosion resistance of 304 ss. A comparative study has been carried out between the implanted and unimplanted steel to determine what influence P-implantation has upon the properties of the passive film formed 1N H/sub 2/SO/sub 4/. The influence of Cl ions on pre-formed passive films was also studied. RHEED, XPS and AES were used to evaluate the nature of the passive films formed in these studies.

1981-12-01

446

Preparation and dosimetry of radiotherapeutic particles for arthropaties; Preparacion y dosimetria de particulas radioterapeuticas para artropatias

Graphical abstract: - Abstract: Low loading platinum-cobalt (Pt-Co) cathode catalyst on a Nafion(Na+)-bonded carbon layer is fabricated by using galvanostatic pulse technique to show the advantage of electrodeposition for high utilization of catalyst in proton exchange membrane fuel cell (PEMFC). We observed that Pt-Co catalysts evenly exist on the surface of carbon electrode and its thickness is about 5.8 ?m, which is four times thinner than conventional Pt/C. Improved single cell power performance of Pt-Co cathode catalysts with a ratio of 3.2:1 compared with Pt/C is clearly presented.

2011-03-01

447

Plasma Free Myristic Acid Proportion Is a Predictor of Nonalcoholic Steatohepatitis

It was developed a new formulation of macro aggregates of Samarium 153 ({sup 153} Sm-MH) for the arthropaties treatment. The radio pharmaceutic was prepared by reaction of Samarium 153 chloride (SmCl{sub 3}) in aqueous environment with sodium boron hydride in NaOH 0.5 N. The microscopic analysis shown that the particles have an average size of 4% m (range 1-14 {mu} m). The velocity of sedimentation was 0.008 cm/min with high stability in vitro in human serum. The biological studies in healthy rabbits, shown that the complex is retained inside the articulation still eight days after of the administration of the radiopharmaceutical. Likewise, it is presented the data of absorbed dose in the different target organs, which was determined by thermoluminescent dosimetry (TLD) through the use of a REMCAL phantom (radiation equivalent manikin calibration). (Author)

1999-07-01

448

British Library Electronic Table of Contents (United Kingdom)

Background/Aims Serum free fatty acid (FFA) composition and abnormal fatty acid metabolism have been implicated in the pathogenesis of nonalcoholic steatohepatitis (NASH). Therefore, we determined if the serum FFA composition can provide accurate diagnosis of NASH. Methods We compared fasting serum FFA compositions in 20 patients with simple steatosis to those in 77 patients with NASH, including 65 patients with early-stage NASH. Results By univariate analysis, the proportions of serum free myristic acid (P?=?0.002) and palmitoleic acid (P?=?0.033) and the stearoyl CoA desaturase (SCD)-1 index (P?=?0.047) were significantly elevated in NASH patients in comparison to patients with simple steatosis. Only the serum free myristic acid proportion was significantly elevated in the early-stage NA...

2011-01-01

449

Physicochemical investigation of the behavior of elements in chloride melts in the presence of solid phases based on phosphates of polyvalent elements. II. Behavior of strontium and barium

Phase-Separation Kinetics and Mechanism in a Methylcellulose/Salt Aqueous Solution Studied by Time-Resolved Small-Angle Light Scattering (SALS)

The distribution of the alkaline earth elements strontium and barium between the solid phases of phosphates of transition elements of group 4 and chloride melts was studied. The distribution coefficients of strontium and barium were found at T = 700-800/sup 0/C. Phosphates of the type NaM/sub 2//sup (IV)/(PO/sub 4/)/sub 3/, where M/sub (IV)/ represents titanium, zirconium, and hafnium, were used as the solid phases. It was established that there is an enrichment of the precipitates with the distributed components. The distribution coefficient depends on the nature of the solid phase and the temperature. It was suggested that M/sup (II)/ x M/sub 4//sup (IV)/(PO/sub 4/)/sub 6/ is formed in processes of distribution, where M/sup (II)/ represents Sr, Ba.

1987-07-01

450

British Library Electronic Table of Contents (United Kingdom)

Abstract Phase-separation dynamics are investigated by SALS in aqueous MC solutions in the presence of 5% NaCl, promoted by a quench temperature. The observed scattering peak indicates that the phase separation occurs by the SD mechanism, leading to a bicontinuous structure. A semilog plot of I(q) against time in the early stage of SD gives a straight line, but the position of qmax varies; also, a Cahn-Hilliard plot indicates that diffusive processes dominate and the data can be described by linear CHC theory. Dapp shows a kinetic dependency on the quench temperature. The spinodal temperature of the sample is 41-C. In the late stages, S(q,t) collapses into a universally time-independent curve.

2011-01-01

451

Oxidative desulphurization study of gasoline and kerosene

British Library Electronic Table of Contents (United Kingdom)

Desulphurization of gasoline and kerosene was carried out using organic and inorganic oxidants. Among the organic oxidants used were hydrogen peroxide in combination with acetic acid, formic acid, benzoic acid and butyric acid, while inorganic oxidants used included potassium permanganate and sodium perchlorate. The oxidation of each petroleum oil was carried out in two steps; the first step consisted of oxidation of the feed at moderate temperature and atmospheric pressure while in the second step, the oxidized mixture was extracted with azeotropic mixture of acetonitrile-water. A maximum desulphurization has occurred with NaClO4 and hydrogen peroxide and acetic acid, which are 68% and 61%, respectively in case of gasoline and 66% and 63%, respectively in case of kerosene oil. The FTIR st...

2010-01-01

452

Nitrilotriacetate complex of univalent astatine

Nitrilotriacetate complex of univalent astatine

Formation of the complex of the univalent astatine cation with nitrilotriacetic acid (AtL)[sup 2-] and its stability constant (lgK[sub 1]=8.97(4), 25degC, [mu]=0.1) have been found experimentally for the first time. The complex is stable in perchlorate solutions in presence of 5 . 10[sup -3] mol . l[sup -1] of the oxidizer Na[sub 2]S[sub 2]O[sub 8] in the interval 4[<=]pH[<=]8.5. The complex is supposed to be destroyed in weak alkaline solutions by reduction of astatine to astatide. The deprotonation constant of hypoastatic acid pK[sub dp]=5.23(9) was found to be lower than determined previously. The investigation was carried out by the method of ion electrophoresis in free electrolyte solutions. (orig.).

1992-01-01

453

Molecular marks for epigenetic identification of developmental and cancer stem cells

Formation of the complex of the univalent astatine cation with nitrilotriacetic acid (AtL)"2"- and its stability constant (lgK_1=8.97(4), 25degC, #mu#=0.1) have been found experimentally for the first time. The complex is stable in perchlorate solutions in presence of 5 . 10"-"3 mol . l"-"1 of the oxidizer Na_2S_2O_8 in the interval 4#<=#pH#<=#8.5. The complex is supposed to be destroyed in weak alkaline solutions by reduction of astatine to astatide. The deprotonation constant of hypoastatic acid pK_d_p=5.23(9) was found to be lower than determined previously. The investigation was carried out by the method of ion electrophoresis in free electrolyte solutions. (orig.).

454

British Library Electronic Table of Contents (United Kingdom)

Epigenetic regulations of genes by reversible methylation of DNA (at the carbon-5 of cytosine) and numerous reversible modifications of histones play important roles in normal physiology and development, and epigenetic deregulations are associated with developmental disorders and various disease states, including cancer. Stem cells have the capacity to self-renew indefinitely. Similar to stem cells, some malignant cells have the capacity to divide indefinitely and are referred to as cancer stem cells. In recent times, direct correlation between epigenetic modifications and reprogramming of stem cell and cancer stem cell is emerging. Major discoveries were made with investigations on reprogramming gene products, also known as master regulators of totipotency and inducer of pluoripotency, na...

2011-01-01

455

Lysis of Escherichia coli cells by lysozyme: Discrimination between adsorption and enzyme action

British Library Electronic Table of Contents (United Kingdom)

The key factors of enzymatic lysis of cells are the interaction between the enzyme and the cell - catalytic and non-catalytic adsorption of enzyme on cell surface. Here, the studies of lysis of intact Escherichia coli cells by chicken egg white lysozyme were performed. It was found that the ionic strength has a dual effect onto the system. On the one hand, the desorption constant of the enzyme increases with the increase of the solution ionic strength, which results in a better enzyme performance. On the other hand, due to the higher osmosis, the cell lysis rate decreases with the increasing of ionic strength of the system. It was found that pH 8.6 and 30mM NaCl are optimal conditions for lysis of E. coli cells by lysozyme.

2011-01-01

456

Local mass transfer (heat transfer) between wall and fluid in a thin-film evaporator

Load conditions and corrosion fatigue crack propagation behavior of high performance steel under seawater environment

The measurement of local heat transfer coefficients is necessary to record the basic phenomena of heat transfer in thin-film apparatuses. For this reason the so-called electrochemical analogy method was developed and used for this application. The electrochemical method implies a specifically composed electrolyte which substitutes the fluid to be evaporated in the thin-film apparatus. Using the redox electrolyte (0,025 kmol/m/sup 3/ K/sub 4/Fe(CN)/sub 6/ resp. k/sub 4/Fe(CN)/sub 6/ and 2nNaOH) the viscosity was, for the first time, thickened until 0.4 Pa s by the help of hydroxyethyl-cellulose.

1983-03-01

457

Laser Raman microscopic studies of passive films formed on type 316LN stainless steels during pitting in chloride solution

An effect of load conditions on Corrosion Fatigue Crack Propagation (CFCP) behavior of High Performance Steel (HPS) under seawater environment was investigated. Fatigue crack propagation tests under several load conditions including stress ratio and load frequency were conducted in air and 3.5% NaCl solution environments. Corrosion/fatigue ratio factor, C/F, particularly was defined to analyze the effect of such conditions. As shown in the results, a decrease of load ratio and frequency leads to an increase of C/F factor. Consequently, under lower loading frequency and stress ratio, the seawater condition causes much more significant effect on CFCP behavior of HPS.

2009-07-01

458

Laser Raman microscopic studies of passive films formed on type 316LN stainless steels during pitting in chloride solution

The surface films formed on type 316LN stainless steels (SS) with different nitrogen contents, during potentiodynamic polarization in acidified 1 M NaCl solution, were characterized by Laser Raman Spectroscopy (LRS). LRS confirmed the presence of oxides and oxychlorides of iron and chromium, hydrated chlorides and nitrates in the film. Raman mapping showed increasing nitrate content in the film with increasing nitrogen content. The film on the uncorroded material showed the presence of chromium and molybdenum oxides. The improvement in pitting corrosion resistance of type 316LN SS with increasing nitrogen content was attributed to increased amount of nitrates in the passive film.

2010-06-15

459

LITHIUM ABUNDANCES IN RED GIANTS OF M4: EVIDENCE FOR ASYMPTOTIC GIANT BRANCH STAR POLLUTION IN GLOBULAR CLUSTERS?

The surface films formed on type 316LN stainless steels (SS) with different nitrogen contents, during potentiodynamic polarization in acidified 1 M NaCl solution, were characterized by Laser Raman Spectroscopy (LRS). LRS confirmed the presence of oxides and oxychlorides of iron and chromium, hydrated chlorides and nitrates in the film. Raman mapping showed increasing nitrate content in the film with increasing nitrogen content. The film on the uncorroded material showed the presence of chromium and molybdenum oxides. The improvement in pitting corrosion resistance of type 316LN SS with increasing nitrogen content was attributed to increased amount of nitrates in the passive film.

2010-06-01

460

Involvement of a putative response regulator Brrg-1 in the regulation of sporulation, sensitivity to fungicides, and osmotic stress in Botrytis cinerea

The determination of Li and proton-capture element abundances in globular cluster (GC) giants allows us to constrain several key questions on the multiple population scenarios in GCs, from formation and early evolution to pollution and dilution mechanisms. In this Letter, we present our results on Li abundances for a large sample of giants in the intermediate-metallicity GC NGC 6121 (M4), for which Na and O have been already determined by Marino et al. The stars analyzed are both below and above the red giant branch bump luminosity. We found that the first and second generation stars share the same Li content, suggesting that a Li production must have occurred. This provides strong observational evidence supporting the scenario in which asymptotic giant branch stars are GC polluters.

2010-06-20

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461

British Library Electronic Table of Contents (United Kingdom)

The response regulator protein is a core element of two-component signaling pathway. In this study, we investigated functions of BRRG-1 of Botrytis cinerea, a gene that encodes a putative response regulator protein, which is homologous to Rrg-1 in Neurospora crassa. The BRRG-1 gene deletion mutant ?Brrg1-62 was unable to produce conidia. The mutant showed increased sensitivity to osmotic stress mediated by NaCl and KCl, and to oxidative stress generated by H2O2. Additionally, the mutant was more sensitive to the fungicides iprodione, fludioxonil, and triadimefon than the parental strain. Western-blot analysis showed that the Bos-2 protein, the putative downstream component of Brrg-1, was not phosphorylated in the ?Brrg1-62. Real-time polymerase chain reaction assays showed that expression ...

2011-01-01

462

Inhibition of the heterotetrameric K++ channel KCNQ1/KCNE1 by the AMP-activated protein kinase

British Library Electronic Table of Contents (United Kingdom)

Abstract The heterotetrameric K++-channel KCNQ1/KCNE1 is expressed in heart, skeletal muscle, liver and several epithelia including the renal proximal tubule. In the heart, it contributes to the repolarization of cardiomyocytes. The repolarization is impaired in ischemia. Ischemia stimulates the AMP-activated protein kinase (AMPK), a serine/threonine kinase, sensing energy depletion and stimulating several cellular mechanisms to enhance energy production and to limit energy utilization. AMPK has previously been shown to downregulate the epithelial Na++ channel ENaC, an effect mediated by the ubiquitin ligase Nedd4-2. The present study explored whether AMPK regulates KCNQ1/KCNE1. To this end, cRNA encoding KCNQ1/KCNE1 was injected into Xenopus oocytes with and without additional injection o...

2011-01-01

463

Influence of pH, temperature and thermal treatment on site corrosion of SAE 304 steel in chlorinated solutions

Influence of carbon and nitrogen on corrosion resistance of high purity Fe-50mass% Cr alloys

The electrochemical behaviour and fracture morphology of homogenized and sensitized type SAE 304 stainless steel U bent specimens, in 3% NaCl solution, at pH=2.0 and pH=7.0 both at room temperature and 100"0C was studied. Polarization curves, galvanostatic and potentiostatic experiments were run. It could be observed that high temperature and low pH favour transgranular cracking and longer sensitization times lower fracture time and tend to give rise to intergranular fracture. Light sensitization can produce transgranular cracking even at room temperature, when the homogenized alloy does not present stress-corrosion cracking for the same condition. (Author).

464

In situ composite coating of titania-hydroxyapatite on titanium substrate by micro-arc oxidation coupled with electrophoretic deposition processing

High purity Fe-50mass%Cr alloys containing (C+N) in the range of 30 to 500 mass ppm were prepared and their corrosion resistance was investigated. Pitting potential in a 3.5mass%NaCl solution at 343K rose with reducing (C+N) content. Alloys containing (C+N) at less than 100 mass ppm did not sustain pitting corrosion. However, alloys containing 500 mass ppm (C+N) corroded severely in 6%FeCl_3+1/20N HCl solutions. Heat treatment at 923K was recognized as influencing corrosion resistance due to precipitation of carbonitrides only in the case of the alloy containing 500 mass ppm (C+N). (orig.).

465

British Library Electronic Table of Contents (United Kingdom)

In situ composite coating of hydroxyapatite (HA)/TiO2 were produced on titanium (Ti) substrate by micro-arc oxidation coupled with electrophoretic deposition (MAO&EPD) technique with different concentrations of HA particles in the 0.2M NaOH electrolyte solution. The surface morphology and chemical composition of the hybrid coating were effected by HA concentration. The amount of HA particles incorporated into coating layer increased with increasing HA concentration used in the electrolyte solution. The corrosion behavior of the coating layer in simulated body fluids (SBF) was evaluated using a potentiodynamic polarization test. The corrosion resistance of the coated sample was increased compared to the untreated Ti sample. The in vitro bioactivity assessment showed that the MAO&EPD treated...

2011-01-01

466

In situ Raman spectroscopy investigation of bioactive glass reactivity: Simulated body fluid solution vs TRIS-buffered solution

British Library Electronic Table of Contents (United Kingdom)

In the present contribution, the innovative in situ Raman micro-spectroscopy was applied to investigate the in vitro reactivity of various bioactive glasses. All the investigated glasses belonged to the Na2O\\K2O-CaO-P2O5-SiO2 system, but contained sensibly different percentages of network modifiers. The glasses were immersed for increasing times, up to 96h, in simulated body fluid (SBF) and in tris-buffered (TRIS) solution. In this way, two fundamental items were addressed, i.e. the effect of the glass composition and the nature of the soaking fluid on the overall reactivity. As regards the SBF, all the glasses were able to promote the formation of a hydroxyl-carbonate apatite (HCA) surface layer in very short times. The reaction rate was particularly quick for the 45S5 Bioglass and for it...

2011-01-01

467

Impacts of membrane properties on reactive dye removal from dye/salt mixtures by asymmetric cellulose acetate and composite polyamide nanofiltration membranes

British Library Electronic Table of Contents (United Kingdom)

This paper aims to study fundamentally the impacts of membrane properties on the reactive dye removal from dye/salt mixtures by nanofiltration membranes. To begin with, two types of nanofiltration membranes of similar pore size, namely asymmetric cellulose acetate membrane and thin-film composite polyamide membrane were fabricated, and their key physical, chemical and performance properties were characterized. After that, these resultant membranes were employed to perform dye removal experiments with aqueous solutions of reactive black 5 and NaCl under different operational parameters. The dye removal rate and steady permeate flux were determined and correlated with the measured membrane properties. It was found that there were significant differences between the dye removal performances o...

2010-01-01

468

Idaho Explosives Detection System

Genetic factors for resistance to diet-induced obesity and associated metabolic traits on mouse chromosome 17

The Idaho Explosives Detection System was developed at the Idaho National Laboratory (INL) to respond to threats imposed by delivery trucks potentially carrying explosives into military bases. A full-scale prototype system has been built and is currently undergoing testing. The system consists of two racks, one on each side of a subject vehicle. Each rack includes a neutron generator and an array of NaI detectors. The two neutron generators are pulsed and synchronized. A laptop computer controls the entire system. The control software is easily operable by minimally trained staff. The system was developed to detect explosives in a medium size truck within a 5-min measurement time. System performance was successfully demonstrated with explosives at the INL in June 2004 and at Andrews Air Force Base in July 2004.

2005-12-01

469

British Library Electronic Table of Contents (United Kingdom)

Obesity is associated with increased susceptibility to dyslipidemia, insulin resistance, and hypertension, a combination of traits that comprise the traditional definition of the metabolic syndrome. Recent evidence suggests that obesity is also associated with the development of nonalcoholic fatty liver disease (NAFLD). Despite the high prevalence of obesity and its related conditions, their etiologies and pathophysiology remains unknown. Both genetic and environmental factors contribute to the development of obesity and NAFLD. Previous genetic analysis of high-fat, diet-induced obesity in C57BL/6J (B6) and A/J male mice using a panel of B6-ChrA/J/NaJ chromosome substitution strains (CSSs) demonstrated that 17 CSSs conferred resistance to high-fat, diet-induced obesity. One of these CSS st...

2009-01-01

470

Ge/Si nanowire mesoscopic Josephson junctions

Formation conditions, chloride content, and stability of passive films on an iron-chromium alloy

The controlled growth of nanowires (NWs) with dimensions comparable to the Fermi wavelengths of the charge carriers allows fundamental investigations of quantum confinement phenomena. Here, we present studies of proximity-induced superconductivity in undoped Ge/Si core/shell NW heterostructures contacted by superconducting leads. By using a top gate electrode to modulate the carrier density in the NW, the critical supercurrent can be tuned from zero to greater than 100 nA. Furthermore, discrete sub-bands form in the NW due to confinement in the radial direction, which results in stepwise increases in the critical current as a function of gate voltage. Transport measurements on these superconductor-NW-superconductor devices reveal high-order (n = 25) resonant multiple Andreev reflections, indicating that the NW channel is smooth and the charge transport is highly coherent. The ability to create and control coherent superconducting ordered states in ...

2006-01-01

471

Evidence for valence transitions in neutron capture gamma-ray spectra in /sup 88/Sr

Passive films were formed on a high purity Fe-23 Cr alloy in acid sulfate solutions in the presence and absence of chloride ion. The resulting film composition was investigated by Auger depth profiling. The passivated samples were exposed to a 1M NaCl solution at a constant potential slightly above the critical pitting potential, and the current-time transient was measured in order to compare the relative stability of the different films. The results obtained suggest that the formation conditions influence the chloride content of the passive film and the breakdown behavior. Passive films formed in the presence of chloride contain and are slightly less stable towards breakdown. No chloride was found in films formed in sulfate and subsequently exposed to chloride well below the pitting potential.

1993-07-01

472

Evidence for valence transitions in neutron capture gamma-ray spectra in /sup 88/Sr

Neutron capture ..gamma..-ray spectra have been measured at 11 average neutron energies from 10 to 530 keV in /sup 88/Sr using a 20 x 15 cm NaI detector with time-of-flight discrimination of background events. The partial radiation widths and the calculated partial valence widths are compared for the strong p-wave resonances at 287 and 321 keV and found to be highly correlated. At these energies, the spectra are dominated by strong transitions to low-lying single particle states, in confirmation of the role of valence capture in the 3p region. However, the data do not support this mechanism at <508> keV.

1985-01-15

473

Electrochemical deposition of indium sulfide thin films using two-step pulse biasing

Neutron capture #gamma#-ray spectra have been measured at 11 average neutron energies from 10 to 530 keV in /sup 88/Sr using a 20 x 15 cm NaI detector with time-of-flight discrimination of background events. The partial radiation widths and the calculated partial valence widths are compared for the strong p-wave resonances at 287 and 321 keV and found to be highly correlated. At these energies, the spectra are dominated by strong transitions to low-lying single particle states, in confirmation of the role of valence capture in the 3p region. However, the data do not support this mechanism at <508> keV.

1984-09-10

474

British Library Electronic Table of Contents (United Kingdom)

Indium sulfide thin films were deposited onto indium-tin-oxide coated glass substrate by electrochemical deposition from an aqueous solution containing In2 (SO4) 3 and Na2S2O3. The deposition conditions were optimized on the basis of data obtained by scanning electron microscope, Auger electron spectroscopy and optical transmission measurements. Furthermore, the photosensitivity of the films was observed by means of photoelectrochemical measurements, which confirmed that the indium sulfide showed n-type conduction. The X-ray diffraction and Raman studies revealed that the as-grown films were amorphous or nanocrystalline in nature and became polycrystalline In2S3 after annealing.

2008-01-01

475

Dewatering press liquor derived from orange production by forward osmosis

British Library Electronic Table of Contents (United Kingdom)

In this investigation, a forward osmosis (FO) dewatering process is evaluated as an alternative for dewatering orange peel press liquor. The press liquor is concentrated by removing water via osmosis into a concentrated ''draw solution'' across a polymeric cellulose acetate membrane. For this investigation, the draw solution consisted of sodium chloride at two different concentrations (2M and 4M). These draw solutions were used to concentrate synthetic press liquor. Concentration factors up to 3.7 resulted when using a 4M NaCl draw solution and the synthetic press liquor. Also during this investigation, fouling behavior was observed and the mechanisms of fouling elucidated through a systematic approach. This approach identified the key components of the press liquor that were primarily res...

2011-01-01

476

Desulphurisation of fumes as a potential source of prime materials

Design and fabrication of large ultra-thin PIN detector with membrane stress deviation

A survey is given by the authors of methods of removing the sulphur dioxide content of fumes which can be linked together with producing useful final products. From these technologies those suppling well utilizable gypsum, the Walther process, producing ammonium sulphate, the Wellman-Lord and Bergbau-Forschung processes, respectively adapted to produce sulphuric acid or sulphur, may be of interest. Also in the method of fumes desulphurisation by catalysis by manganese, developed in KBFI, utilizable final products are given. Background of the work of developing this method. Detailed description of the manganese catalytic method based on the use of a red mud desulphurizing agent. By this process, in addition to desulphurizing fumes, enriched red mud with reduced Na/sub 2/O content is produced, which as an iron carrier, is to be reckoned with, or to be used in the cement industry for replacing imported calcined pyrites.

1986-01-01

477

Delayed Afterdepolarization in Intact Canine Sinoatrial Node as a Novel Mechanism for Atrial Arrhythmia

In this paper, the design of large thin PIN detector with a membrane stress avoidance configuration is proposed, and the related device fabrication process is developed. Ultra-thin PIN detector {approx} 1.13 cm{sup 2} in area is fabricated on a thin ( {approx} 35{mu}m) silicon membrane, and characterized. Detector performance improvement has been successfully demonstrated. With the membrane stress avoidance design, the improved detector exhibits a leakage of 6nA, which is at least 5 times lower than that of detector of identical junction area. The new detector features a full depleted capacitance of 110 pF, and a FWHM of 40.86 keV energy resolution for 5.486 MeV alpha particle spectrography.

2010-09-15

478

British Library Electronic Table of Contents (United Kingdom)

Delayed Afterdepolarization in Sinoatrial Node. Introduction: Recent evidence indicates that spontaneous sarcoplasmic reticulum Ca release and Na-Ca exchanger current activation contribute to the sinoatrial node (SAN) automaticity. These findings suggest that SAN activity may share mechanisms that underlie both automaticity and triggered activity. The aim of this study is to test the hypothesis that spontaneous, nonvoltage gated, intracellular Ca (Cai) elevation may induce delayed afterdepolarization (DAD) in intact SAN during isoproterenol infusion. Methods and Results: We simultaneously mapped Cai and membrane potential in 31 isolated Langendorff-perfused canine right atriums (RA). Isoproterenol increased heart rate and late diastolic Cai elevation (LDCAE) of the superior SAN, leading to...

2011-01-01

479

Cyclosporine metabolic side effects: association with the WNK4 system

British Library Electronic Table of Contents (United Kingdom)

Abstract Background- Cyclosporine is used for treatment of transplanted patients and for immune-mediated diseases. Cyclosporine is known to cause a combination of metabolic side effects including hypertension, hyperkalemia, hypercalciuria and hypomagnesemia. These side effects except for hypomagnesemia are the cardinal features of familial hyperkalemia and hypertension (FHHt), also called pseudohypoaldosteronism type II (PHA II). FHHt is caused by mutations in the kinases WNK1 and WNK4 resulting in an increase in renal Na-Cl cotransporter (NCC) apical distribution and function. Therefore, we studied whether cyclosporine-s metabolic side effects are mediated by WNK4 and NCC. Design- Sprague-Dawley (SD) rats were treated by cyclosporine 25-mg-kg-1 subcutaneously for 14-days. Blood pressure, ...

2011-01-01

480

Covalent modification of fused silica capillaries with quaternized polyamines to achieve robust and stable anodic electroosmotic flow

British Library Electronic Table of Contents (United Kingdom)

Synthetic chemistry originally developed for the manufacture of chemically stable silica polyamine composites was adapted for the modification of fused silica capillaries for application in CE. Polyethyleneimine (PEI) and polyallylamine (PAA) were covalently bonded to the interior surface of fused silica capillaries utilizing 3-chloropropyltrichlorosilane (CPTCS) or 3-glycidoxypropyl-trimethoxysilane (GPTMS) to anchor the polymers to the surface. The surface-bound polymers were subsequently quaternized using methyl iodide (MeI). The resulting modified capillaries were studied using CE, and were shown to provide reproducible, stable, and robust anodic EOF throughout the pH range of 2-10. Surface modifications utilizing CPTCS could be rinsed with up to 6 M HCL or 1 M NaOH without significant...

2009-01-01

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481

Corrosion resistance characteristic of aluminium bronze containing chromium and zirconium

Corrosion problems and resistance to corrosion of materials for production of steam generators for light water reactor power plants. [Alloys I-600, I-800, I-690

There are reported the results of corrosion resistance investigation of aluminium bronzes, containing about 8 and 10% of aluminium and modifying quantities of zirconium. The tests of corrosion resistance were carried out in synthetic seawater, in 3% NaCl aqueous solution and in 10% H_2SO_4 aqueous solution, with reference to industrial bronze BA93 (CuAl9Fe3). The bronzes were tested in an annealed, hardened, tempered state and after plastic hot working. The conclusion is that corrosion resistance of aluminium bronzes, especially against selective corrosion, depends more on material structure, resulted form heat treatment, than on chemical composition. (author). 6 refs, 8 figs, 6 tabs.

482

Complexation of vanadium (v) with alanine in different ionic strength

Briefly described is knowledge of crevice corrosion, corrosion cracking and denting. In evaluating the corrosion resistance of steam generator materials it is necessary to distinguish corrosion problems caused by the primary coolant side and by the secondary circuit side. At present tubes are manufactured of 7 austenitic alloys of a different chemical composition, and available information shows that views on their corrosion resistance differ. Greatest attention has been devoted to corrosion cracking in the presence of NaOH. Findings related to I-600, I-800, I-690 and AISI 316 are given. Corrodibility by sulfur-containing products is now being studied, namely the intercrystalline corrosion cracking caused by the presence of H/sub 2/S/sub 4/O/sub 6/. Knowledge gained in this respect is summed up.

1984-07-01

483

Cloud-point measurement for (sulphate salts + polyethylene glycol 15000 + water) systems by the particle counting method

The formation constants of species formed in the system H"+"+alanine and VO_"2"+alanine have be determined in aqueous solution for 1.0NaCIO_4,using a combination of pramiracetam and spectrophotometric techniques. The compositions of the formed complexes and their stability constants were determined ny curve fitting method and it was shown that di oxovanadium(V) forms two mononuclear 1:1 and 1:2 species with alanine of the type VO_2L and VO_2L_2 The protonation constant of the amino group of alanine has been determined using a computer program which employ a least-squares method. The defence of the protonation of alanine and the stability constant of the species on ionic strength are described by a Debby-huckel type equation.

2002-04-10

484

Chemical and microbial properties of mahyaveh, a traditional Iranian fish sauce

The phase separation of (water + salt + polyethylene glycol 15000) systems was studied by cloud-point measurements using the particle counting method. The effect of three kinds of sulphate salt (Na2SO4, K2SO4, (NH4)2SO4) concentration, polyethylene glycol 15000 concentration, mass ratio of polymer to salt on the cloud-point temperature of these systems have been investigated. The results obtained indicate that the cloud-point temperatures decrease linearly with increase in polyethylene glycol concentrations for different salts. Also, the cloud points decrease with an increase in mass ratio of salt to polymer.

2009-07-01

485

British Library Electronic Table of Contents (United Kingdom)

To the best of our knowledge, this is the first report on the chemical and microbial properties of traditional Iranian fish sauce, mahyaveh. Fish sauce samples used in this study originated from five different locations in the Southern part of Iran. The pH of mahyaveh samples from different locations was in the range of 4.89-7.55 and NaCl concentration was in the range of 7.48-17.1%. The overall mean of TVB-N in all the samples tested was 3098 mg/kg. Histamine, with the overall mean of 2662 mg/kg, was found to be the main biogenic amine in the Iranian fish sauce. The high histamine content can be related to the high levels of bacterial count especially enterobacteriaceae (overall mean of 3.41 log cfu/g) and lactic acid bacteria (overall mean of 4.13 log cfu/g) in this product. Spermidine w...

2012-01-01

486

Catalyzed oxidative degradation of methylene blue by in situ generated cobalt (II)-bicarbonate complexes with hydrogen peroxide

British Library Electronic Table of Contents (United Kingdom)

Oxidative degradation of methylene blue (MB) by Co^2^+-HCO3^- system with H2O2 in aqueous solution was studied. Nearly complete decolorization of the dye was obtained in less than 50min in diluted NaHCO3 solution (25mM) in the presence of only 20mM Co^2^+ ions. Meanwhile, the conjugated structure and phenyl rings of the MB molecule were destroyed or even broken down into small organic acids and inorganic ions, as indicated by FT-IR spectra and ion-chromatography. Photoluminescence probing and radical scavenging technologies suggested that the reaction of MB degradation in this system mainly involved the generation and participation of hydroxyl radicals. Furthermore, by cyclovoltammetric measurements, the in situ formed different complexes between Co^2^+ and HCO3^- were observed at differen...

2011-01-01

487

Calculation of neutron and gamma-ray emission spectra produced by p +2''2'Al reactions

Basic study on heat transfer characteristics of liquid Na in a decay-heat removal system of LMFBR

As a contribution to the US/Japan cooperative program in fusion neutronics, we have prepared a library of multigroup neutron cross sections, scattering matrices, and covariances (uncertainties and their correlations). This 74-group library, called COVFILS-2, is being used at Los Alamos and at the University of California at Los Angeles in the sensitivity and uncertainty analysis of the Li_2O integral experiment recently performed at the Fast Neutron Source (FNS) in Japan. Another intended use of this library is in the estimation of the uncertainty in key performance parameters (such as breeding ratio) of conceptual fusion reactors. The 14 materials included in the first version of COVFILS-2 are H, "6Li, "7Li, Be, C, N, O, Na, Al, Si, Cr, Fe, Ni, and Pb.

1985-01-01

488

Assessing the acid properties of desilicated ZSM-5 by FTIR using CO and 2,4,6-trimethylpyridine (collidine) as molecular probes

A numerical analysis is performed to clarify the heat transfer characteristics of combined convection around the tubes which form a single row perpendicularly arranged to a forced flow in the direction of gravity. A boundary-fitted coordinate transformation technique is adopted to solve the governing equations numerically. It is found in the case of liquid sodium that gravity-induced flow gives no substantial effect to heat transfer augmentation in a low Reynolds number region while it can be sufficiently expected in the ordinary fluids in the same Reynolds number region. This means that such heat transfer augmentation as expected in ordinary fluids can not be realized when crossflow-type heat exchangers installed for decay-heat removal operates in a low Reynolds number region.

1988-02-01

489

British Library Electronic Table of Contents (United Kingdom)

A series of desilicated ZSM-5 catalysts previously shown to have improved catalytic performance in the MTG (methanol-to-gasoline) reaction [M. Bjorgen, F. Joensen, M.S. Holm, U. Olsbye, K.-P. Lillerud, S. Svelle, Appl. Catal. A 345 (2008) 43] was subjected to thorough examination using FTIR. Clearly, defects represented by internal Si-OH sites are removed upon NaOH treatment. In a parallel manner, free Si-OH sites increase in concentration and the results point to a selective mechanism for formation of mesopores as the framework dissolution preferentially takes place at defective sites in the crystallites. The acid properties of the desilicated materials were investigated by applying CO and collidine (2,4,6-trimethylpyridine) as molecular probes. Monitoring the induced frequency shifts upo...

2009-01-01

490

Application of photoelectrochemistry and impedance measurements to the study of passive films on AISI 304 stainless steel

Antimicrobial silver-montmorillonite nanoparticles to prolong the shelf life of fresh fruit salad

In this work passive films formed in AISI 304 stainless steel were envisaged as semiconductors and studied by means of photoelectrochemistry and Mott-Schottky plots. The passive films were potentiostatically formed at different potentials (0.2-0.8V) in a basic borate/boric acid solution without and with addition of NaCl (0.5 and 1g/l) and at various temperatures in the range 8-60"oC. The influence of these parameters on the photocurrent, quantum efficiency, bandgap energy and density of charge carriers was determined. The results show that the experimental conditions at which the films are formed influence the semiconductive properties of the film, which seem to be related to the higher or lower stability of the film. An Arrhenius type of relationship was also found between the density of charge carriers and temperature, leading to the determination of an activation energy. (author) 13 refs., 7 figs.

1988-07-01

491

British Library Electronic Table of Contents (United Kingdom)

In this work, silver-montmorillonite (Ag-MMT) antimicrobial nanoparticles have been obtained by allowing silver ions from nitrate solutions to replace the Na^+ of natural montmorillonite and then to be reduced by a thermal treatment. Ag-MMT were used as active antimicrobial compounds to improve the shelf life of fresh fruit salad. In order to assess their influence on product shelf life, sensorial and microbiological quality has been monitored during the storage. The microbiological quality was determined by monitoring the principal spoilage microorganisms (mesophilic and psychrotrophic bacteria, coliforms, lactic acid bacteria, yeasts and molds). Additionally, the evolution of sensorial quality was assessed by monitoring color, odor, firmness and product overall quality. The Ag-MMT nanopa...

2011-01-01

492

Annihilation of antiprotons in light nuclei

Angular momentum dependence in 22 MeV alpha-particle elastic scattering by light nuclei

CR-39 detectors have been exposed to a 5.9-MeV antiproton beam using the low energy antiproton ring (LEAR) facility at CERN. At this energy, tracks of antiprotons appear in a CR-39 detector after 135 min of etching in 6 M NaOH at 70C. Fluence of the antiproton beam has been determined using track density. We have also found tracks in the etched CR-39 detector at different depths (250-500 mum). These tracks have resulted from the annihilation of antiprotons with the constituents (H, C and O) of the CR-39 detector. The goal of the experiment is to develop a simple and low-cost method to study properties of antiparticles and those formed after annihilation of these particles with the target matter.

2006-01-01

493

Analysis of organic acids in the pyrohydrolysis distillate of (U,Pu) mixed carbide fuel by ion chromatography

Elastic scattering of 22 MeV alpha particles by "2"3Na, sup(24-25-26)Mg, "2"7Al and "2"8Si has been measured between 24"0 and 174"0 lab. Partial angular distributions, from 120"0 to 174"0, were also measured at incident energies of 18.4 and 20.7 MeV for "2"4Mg, and 18.9 and 20.5 MeV for "2"8Si. The most striking feature of the data is the large angle behaviour: spin-zero nuclei display more pronounced backward oscillations and the cross section rises more steeply towards 180"0 for 4n nuclei than for the others. (Z.M.).

494

Amorphization of Zr_6_0Al_1_5Ni_2_5 surface layers by laser processing for corrosion resistance

The study reports the identification of different organic acids that are formed during the pyrohydrolysis of mixed carbide of uranium and plutonium using ion chromatography (IC). The identification of organic acids present in the pyrohydrolysis distillate is required to carry out interference free analysis of Cl and F. The study describes three stage isocratic separations with NaOH eluents having concentrations 2 mM, 10 mM and 50 mM respectively in order to separate and identify both aliphatic and aromatic acids. The present investigation identified formic, acetic, propionic, butyric, tartaric and oxalic acids in the distillate, however, aromatic acids could not be identified. (author)

2011-02-22

495

A protocol for the evaluation of genotoxicity in bile of carp (Cyprinus carpio) exposed to lake water treated with different disinfectants

It is generally known that a number of metallic glasses have excellent corrosion resistance in a variety of chemically hostile environments. Consequently, the use of laser cladding to coat a massive crystalline material such as aluminium with a layer of a metallic glass has obvious advantages. In this paper, the authors will show that the formation of a predominantly amorphous layer of Zr_6_0Al_1_5NI_2_5 alloy by laser processing is possible, if the obstacles to amorphization are overcome. In addition, evidence of the excellent corrosion resistance of this alloy in a NaCl solution will be given. A comparative study of the corrosion behavior of this amorphous alloy with pure aluminium and Al-Cr alloy will be done, in order to complete previous studies of laser processed coatings of aluminum substrates.

496

British Library Electronic Table of Contents (United Kingdom)

A sensitive and rapid method to evaluate toxic and genotoxic properties of drinking water supplied from Lake Trasimeno (Umbria, Central Italy) was worked out analysing bile in Cyprinus carpio exposed for 20d to lake water treated with 3 different disinfectants, sodium hypochlorite (NaClO), chlorine dioxide (ClO2) and peracetic acid (PAA). Fish were sacrificed at 0, 10 and 20d in order to investigate the time course of these endpoints. An aliquot of bile samples was fractionated by adsorption on C18 silica cartridges and the genotoxic potential of whole bile and of bile fractions was evaluated by the single-cell microgel-electrophoresis (comet) assay on human colonic adenocarcinoma cells (Caco-2). Bile (both whole and fractionated) from specimens exposed to the three disinfectants always sh...

2011-01-01

497

A phase II trial of sorafenib in first-line metastatic urothelial cancer: a study of the PMH Phase II Consortium

British Library Electronic Table of Contents (United Kingdom)

Summary Background Sorafenib is an oral multikinase inhibitor that blocks cell proliferation via the ERK pathway and angiogenesis via the VEGF pathway. This phase II trial was conducted to determine the efficacy and tolerability of sorafenib for the treatment of patients with metastatic urothelial cancer (UC) who had not had prior chemotherapy for advanced disease. Patients and Methods Seventeen chemo-na?ve UC patients with adequate performance status and organ function were treated with sorafenib 400?mg twice daily on a continuous basis until progression or unacceptable toxicity. The primary endpoint was objective tumor response rate as measured by RECIST criteria. Secondary endpoints included rate of prolonged stable disease (>3?months), time to progression, median and 1?yr survival and ...

2011-01-01

498

A mobile gamma scanning system for detecting radiation anomalies

A mobile gamma scanning system for detecting radiation anomalies

A mobile gamma-ray scanning system has been developed by Oak Ridge National Laboratory for use in the U.S. Department of Energy's remedial action survey programs. The unit consists of NaI(Tl) detectors housed in a specially equipped van. The system is operator controlled through an on-board minicomputer with data output provided on the computer video screen, strip chart recorders, and an on-line printer. Data storage is provided on floppy disk. Multichannel analysis capabilities are included for qualitative radionuclide identification. A /sup 226/Ra-specific algorithm is currently employed to identify locations containing residual radium-bearing materials.

1983-09-01

499

A basic study on heat transfer characteristics of liquid Na in a decay-heat removal system of LMFBR

A mobile gamma-ray scanning system has been developed by Oak Ridge National Laboratory for use in the U.S. Department of Energy's remedial action survey programs. The unit consists of NaI(Tl) detectors housed in a specially equipped van. The system is operator controlled through an on-board minicomputer with data output provided on the computer video screen, strip chart recorders, and an on-line printer. Data storage is provided on floppy disk. Multichannel analysis capabilities are included for qualitative radionuclide identification. A "2"2"6Ra-specific algorithm is currently employed to identify locations containing residual radium-bearing materials.

500