WorldWideScience
1

High-Sensitivity Analysis of Naturally Occurring Sugar Chains, Using a Novel Fluorescent Linker Molecule  

UK PubMed Central (United Kingdom)

To analyse the binding of sugar chains to proteins, viruses and cells, the surface plasmon resonance (SPR) technique is very convenient and effective because it is a real-time, non-destructive detection...Full Text Available

2009-07-01

2

Sugar Ester Modified Lipase Catalyzed Esterification in Organic Media.  

Science.gov (United States)

The esterification reaction of a long-chain fatty acid and a fatty alcohol catalyzed by sugar ester-modified lipases in organic media was studied. The reaction activity was improved when the lipases were modified with sugar esters. Among four kinds of sugar esters and six kinds of lipases, lipase CES modified with sugar ester SE-7 showed the highest reaction activity. The pH, solvent and temperature on the reaction activity of SE-7 modified lipase CES were also studied. PMID:12142919

1999-01-01

3

Analysis by high-performance liquid chromatography of radioactively labeled carbohydrate components of proteoglycans  

Energy Technology Data Exchange (ETDEWEB)

Methods were developed for the separation of radioactively labeled carbohydrate components of proteoglycans by isocratic ion-moderated partition HPLC. Neutral sugars were separated after hydrolysis in trifluoroacetic acid with baseline separation between glucose, xylose, galactose, fucose, and mannose. N-Acetylneuraminic acid, N-acetylated hexosamines, glucose, galactose, and xylitol were likewise well separated from each other under isocratic elution conditions. Glucuronic acid, iduronic acid, and their lactones were separated after hydrolysis in formic acid and sulfuric acid. Glucosamine, galactosamine, galactosaminitol, and glucosaminitol were separated by HPLC on a cation exchanger with neutral buffer after hydrolysis in hydrochloric acid. THe separation techniques also proved useful in fractionation of exoglycosidase digests of O- and N-linked oligosaccharides. Separations of aldoses, hexosamines, and uronic acids were adapted to sensitive ...

1986-04-01

4

Nonenzymatic glycosylation of human hemoglobin at multiple sites  

International Nuclear Information System (INIS)

The most abundant minor hemoglobin component of human hemolysate is Hb A1c, which has glucose bound to the N-terminus of the beta chain by a ketoamine linkage. Hb A1c is formed slowly and continuously throughout the 120 day lifespan of the red cell. It can be synthesized in vitro by incubating purified hemoglobin with 14C-glucose. Other minor components, Hb A1a1 and Hb A1a2 are adducts of sugar phosphates at the N-terminus of the beta chain. Hb A1b contains an unidentified nonphosphorylated sugar at the beta N-terminus. In addition, a significant portion of the major hemoglobin component (Hb Ao) is also glycosylated by a glucose ketoamine linkage at other sites on the molecule, including the N-terminus of the alpha chain and the epsilon-amino group of several lysine residues on both the alpha and the beta chains. The results indicate that the interaction of ...

5

Alcohol from sugar beet. The Austrian sugar industry project  

Energy Technology Data Exchange (ETDEWEB)

The Austrian sugar industry has developed a project for the manufacture of alcohol that is geared to the conditions in that country and is based on sugar beet as raw material. An alcohol production plant could be integrated in a sugar factory and operate all the year round at a capacity of 120,000 l/d. In this factory, the fermentation raw material would be in the form of green syrup (also thick juice if the need arose) and would be supplied from other sugar factories operating without molasses. The vinasse is to be concentrated and used or burnt. The project provides new possibilities for agriculture, and the sugar industry expects an improvement in plant utilization and a diversification.

1983-12-01

6

DNA-new combination: a practical application in the sugar industry  

Energy Technology Data Exchange (ETDEWEB)

One of the first technical applications of gene technology is reported here. The DNA of E. coli cells was rearranged such that these cells produce large quantities of the enzyme ..cap alpha..-galactosidase. This enzyme is used to split the trisaccharide, raffinose, which is formed during the production of sugar from sugar beet. By this means sugar yields can be increased and the energy required for sugar crystallisation reduced.

1983-04-01

7

Waste heat recovery systems in the sugar industry: An Indian perspective  

Energy Technology Data Exchange (ETDEWEB)

This article identifies the key role of the sugar industry in the rural development of developing countries. The Indian sugar industry, already second largest among the country`s processing industries, shows even greater potential, according to the Plan Documents (shown in a table). The potential of waste heat in sugar processing plants, which produce white crystal sugar using the double sulphitation clarification process, is estimated at 5757.9 KJ/kg of sugar. Efficient waste heat recovery (WHR) systems could help arrest the trend of increasing production costs. This would help the sugar industry not only in India, but in many other countries as well. The innovative methods suggested and discussed briefly in this article include dehydration of prepared cane, bagasse drying, and juice heating using waste heat. These methods can reduce the cost of energy in ...

1996-04-01

8

DNA alterations photosensitized by tetracycline and some of its derivatives  

Energy Technology Data Exchange (ETDEWEB)

Bacteriophage M13 mp10 DNA were irradiated with near-UV light in the presence of tetracycline derivatives and primed with synthetic oligonucleotide to be used for DNA synthesis using Escherichia coli DNA polymerase. Chain terminations were observed by denaturing polyacrylamide gel electrophoresis and mapped precisely. All the synthesis stops occurred before or at the level of guanine residues, showing that the photoreaction mediated by tetracycline derivatives led to a preferential alteration of guanine residues. These lesions were demonstrated to be induced in DNA through a pathway involving singlet oxygen. Tetracycline derivatives also photoinduced the breakage of the DNA sugar-phosphate backbone monitored by the conversion of supercoiled phi X174 DNA to a relaxed form. This lesion was shown to be initiated by hydroxyl radicals. The production of this free radical has been confirmed by electron paramagnetic resonance (EPR) spin trapping ...

1986-06-01

10

Electricity usage in the sugar industry: Opportunities for reducing the demand. Proceedings. Moeglichkeiten der Elektroenergie-Einsparung in der Zuckerindustrie. VDZ-Tagungsbericht  

Energy Technology Data Exchange (ETDEWEB)

The use of thermal energy in the West German sugar industry has fallen by nearly half in the last twenty years. At the same time, automation and new technologies have led to an increase in the consumption of electric energy. In many cases, the equilibrium of combined heat and power has been upset. That equilibrium is, however, a fundamental precondition of the economical energy management of a sugar factory. Electrical engineers and sugar technologists have looked at the situation in the sugar industry form different points of view and have presented interesting ideas - in some instances already put into practice - to solve the problem. Examination of the electricity consumption of alternative processes, systems and pieces of equipment used in sugar manufacturing, from the beet yard to the sugar house, has revealed marked differences and considerable potential ...

1989-01-01

11

Sugar Efflux from Maize (Zea mays L.) Pedicel Tissue 1  

UK PubMed Central (United Kingdom)

Sugar release from the pedicel tissue of maize (Zea mays L.) kernels was studied by removing the distal portion of the kernel and the lower endosperm, followed by replacement of the...Full Text Available

1985-03-01

12

Sucrose Uptake by Sugar Beet Tap Root Tissue 1  

UK PubMed Central (United Kingdom)

Sucrose uptake by discs of mature sugar beet root tissue incubated in [14C]-sucrose exhibited nonsaturating kinetics over the concentration range of 1 to 500 millimolar. Uptake was inhibited...Full Text Available

1979-11-01

13

Regulation and Function of Escherichia coli Sugar Efflux Transporter A (SetA) during Glucose-Phosphate Stress?  

UK PubMed Central (United Kingdom)

Accumulation of certain nonmetabolizable sugar-phosphates (including α-methyl glucoside-6-phosphate) in Escherichia coli is growth inhibitory and elicits the glucose-phosphate...Full Text Available

2011-01-01

14

Metabolic Engineering of Lactobacillus plantarum for Production of l-Ribulose?  

UK PubMed Central (United Kingdom)

l-Ribulose is a rare and expensive sugar that can be used as a precursor for the production of other rare sugars of high market value such as l-ribose. In this work we describe a production...Full Text Available

2007-11-01

15

Biosynthesis, Translocation, and Accumulation of Betaine in Sugar Beet and Its Progenitors in Relation to Salinity 12  

UK PubMed Central (United Kingdom)

Like other halophytic chenopods, sugar beet (Beta vulgaris L.) can accumulate high betaine levels in shoots and roots. N,N,N-trimethylglycine impedes sucrose crystallization...Full Text Available

1982-10-01

16

Auxin-Induced Ethylene Production as Related to Auxin Metabolism in Leaf Discs of Tobacco and Sugar Beet 1  

UK PubMed Central (United Kingdom)

Exogenously supplied indole-3-acetic acid (IAA) stimulated ethylene production in tobacco (Nicotiana glauca) leaf discs but not in those of sugar beet (Beta vulgaris...Full Text Available

1983-11-01

17

Acetic Acid Bacterial Biota of the Pink Sugar Cane Mealybug, Saccharococcus sacchari, and Its Environs  

UK PubMed Central (United Kingdom)

Saccharococcus sacchari is the primary colonizer of the developing “sterile” tissue between the leaf sheath and stem of sugar cane. The honeydew secreted by the mealybugs...Full Text Available

1990-03-01

18

Abscisic Acid Inhibition of Radicle Emergence But Not Seedling Growth Is Suppressed by Sugars1  

UK PubMed Central (United Kingdom)

Low concentrations of sugars altered the sensitivity of seed germination to inhibition by exogenous abscisic acid (ABA). Germination of wild-type and ABA-insensitive (abi) Arabidopsis...Full Text Available

2000-04-01

19

Sugar uptake and starch biosynthesis by slices of developing maize endosperm  

Energy Technology Data Exchange (ETDEWEB)

{sup 14}C-Sugar uptake and incorporation into starch by slices of developing maize (Zea mays L.) endosperm were examined and compared with sugar uptake by maize endosperm-derived suspension cultures. Rates of sucrose, fructose, and D- and L-glucose uptake by slices were similar, whereas uptake rates for these sugars differed greatly in suspension cultures. Concentration dependence of sucrose, fructose, and D-glucose uptake was biphasic (consisting of linear plus saturable components) with suspension cultures but linear with slices. These and other differences suggest that endosperm slices are freely permeable to sugars. After diffusion into the slices, sugars were metabolized and incorporated into starch. Starch synthesis, but not sugar accumulation, was greatly reduced by 2.5 millimolar p-chloromercuribenzenesulfonic acid and 0.1 millimolar carbonyl cyanide ...

1990-11-01

20

Use of geothermal heat for sugar refining in Imperial County. Final report, Phase I  

Energy Technology Data Exchange (ETDEWEB)

The objective of the three-phase Holly Sugar Geothermal Project was to replace fossil fuels with geothermal energy for sugar beet processing at the Holly Sugar plant located in Brawley, California, in a technically straightforward, economically sound and environmentally acceptable manner. The first phase of the project, discussed in this final report, encompassed the design and analysis of a geothermal industrial heat system for Holly Sugar and addresses: (1) assessment of the geothermal resource; (2) development of a preliminary system design; (3) analysis and publication of an environmental analysis and monitoring report; (4) preliminary economic analyses; (5) dissemination of project related information; and (6) the development of a proposal for the follow-on phases.

1980-12-01

21

Nuclear analytical techniques in Cuban sugar industry  

Energy Technology Data Exchange (ETDEWEB)

This paper is a review concerning the application of Nuclear Analytical Techniques in the Cuban sugar industry. The most complete elemental composition of final molasses (34 elements) and natural zeolites (38) this last one employed as an auxiliary agent in sugar technological processe4s has been performed by means of instrumental Neutron Activation Analysis (INAA) and X-Ray Fluorescence Analysis (XRFA). The trace elemental sugar cane soill-plant relationship and elemental composition of different types of Cuban sugar (raw, blanco-directo and refine) were also studied. As a result, valuable information referred to the possibilities of using these products in animal and human foodstuff so as in the other applications are given. (author). 34 refs., 6 figs., 1 tab.

1997-12-01

22

Nanoelectrospray high capacity ion trap multiple stage mass spectrometry for the structural analysis of human brain gangliosides  

International Nuclear Information System (INIS)

Full text: A novel protocol based on electrospray ionization (ESI) multiple stage high capacity ion trap (HCT) mass spectrometry (MS) was developed for glycosphingolipidomic surveys. The method was optimized for detailed structural elucidation of human brain gangliosides and particularly applied to human hippocampus-associated structures. The multiple stage MS experiments allowed for a complete structural characterization of GM1 ganglioside species, which was achieved by elucidation of the oligosaccharide sequence, identification of the GM1 a structural isomer from the data upon sialic acid localization along the sugar backbone and determination of the d18:1/18:0 of fatty acid/sphingoid base composition of the ceramide moiety. The methodology developed here is of general practical applicability for glycolipids and represents a step forward in the implementation of the advanced and most modern MS methods in glycomics. Gangliosides are glycosphingolipids, which ...

2006-10-25

23

Biohydrogen production from desugared molasses (DM) using thermophilic mixed cultures immobilized on heat treated anaerobic sludge granules  

British Library Electronic Table of Contents (United Kingdom)

Hydrogen production from desugared molasses (DM) was investigated in both batch and continuous reactors using thermophilic mixed cultures enriched from digested manure by load shock (loading with DM concentration of 50.1 g-sugar/L) to suppress methanogens. H"2 gas, free of methane, was produced during batch cultivations, at different (DM) concentrations ranging from 1.5 g-sugars/L to 50.1 g-sugars/L. The highest yield of 237 ml-H"2/g-sugar was achieved during the DM batch fermentation at concentration of 2.1 g-sugars/L, whereafter the yield decreased with increasing DM concentration. The enriched hydrogen producing mixed culture achieved from the 16.7 g-sugars/L DM batch cultivation was immobilized on heat treated anaerobic sludge granules in an up-flow anaerobic sludge blanket (UASB) reac...

2011-01-01

24

A supply chain-transport supernetwork equilibrium model with the behaviour of freight carriers  

British Library Electronic Table of Contents (United Kingdom)

This paper presents a supernetwork equilibrium model integrating supply chain networks with a transport network, namely, a supply chain-transport supernetwork equilibrium model. The model takes into account the behaviour of freight carriers and transport network users to endogenously determine the transport costs generated in the supply chain networks. The interaction between transport network and supply chain networks can also be examined. Results of the numerical tests reveal that the improvement of transport network could enhance the efficiency of supply chain networks. The paper makes contributions to modelling of supply chain networks as well as to that of transport networks.

2011-01-01

25

Retrospective search on non forest energy crops  

Energy Technology Data Exchange (ETDEWEB)

This literature survey covers the period 1969 to date including sugar crops, hydrocarbon bearing arid plants, aquaculture/aquatic biomass systems, and alcohol fuels.

1981-01-01

26

If I Had - A Family Member with Metabolic Syndrome  

Medline Plus

... elevated blood sugar levels, but not full-blown diabetes. What are the keys to preventing the disease? ... been well studied, in a study called The Diabetes Prevention Program, in several thousand people with this ...

27

Apoplastic invertases  

UK PubMed Central (United Kingdom)

The mutualistic interaction of plants with arbuscular mycorrhizal (AM) fungi is characterized by an exchange of nutrients. The plant provides sugars in the form of hexoses to the heterotrophic fungus...Full Text Available

2008-05-01

28

AN ELECTROPHYSIOLOGICAL ANALYSIS OF THE ACTION OF CARBOHYDRATES ON THE SUGAR RECEPTOR OF THE BLOWFLY*  

UK PubMed Central (United Kingdom)

Measurements of the taste thresholds of blowflies for a wide variety of carbohydrates, presented individually and in combination, showed that the stimulating effects of the compounds are not always...Full Text Available

1969-01-01

29

Information security in networked supply chains: impact of network vulnerability and supply chain integration on incentives to invest  

British Library Electronic Table of Contents (United Kingdom)

Recent supply chain reengineering efforts have focused on integrating firms? production, inventory and replenishment activities with the help of communication networks. While communication networks and supply chain integration facilitate optimization of traditional supply chain functions, they also exacerbate the information security risk: communication networks propagate security breaches from one firm to another, and supply chain integration causes breach on one firm to affect other firms in the supply chain. We study the impact of network security vulnerability and supply chain integration on firms? incentives to invest in information security. We find that even though an increase in either the degree of network vulnerability or the degree of supply chain integration increases the secur...

2010-01-01

30

Interaction of antimicrobial peptides with lipid membranes  

International Nuclear Information System (INIS)

This study aims to investigate the difference in the interaction of antimicrobial peptides with two classes of zwitterionic peptides, phosphatidylethanolamines (PE) and phosphatidylcholines (PC). Further experiments were performed on model membranes prepared from specific bacterial lipids, lipopolysaccharides (LPS) isolated from Salmonella minnesota. The structure of the lipid-peptide aqueous dispersions was studied by small-and wide-angle X-ray diffraction during heating and cooling from 5 to 85 C. The lipids and peptides were mixed at lipid-to-peptide ratios 10-10000 (POPE and POPC) or 2-50 (LPS). All experiments were performed at synchrotron soft condensed matter beamline A2 in Hasylab at Desy in Hamburg, Germany. The phases were identified and the lattice parameters were calculated. Alamethicin and melittin interact in similar ways with the lipids. Pure POPC forms only lamellar phases. POPE forms lamellar phases at low temperatures that upon heating transform into a highly curved ...

31

Report on the engineering and economics of an ethanol/gasohol joint-venture project with Caldwell Sugars Co-op, Inc. at Thibodaux, Louisiana. Attachment B, Volume III. Definitive estimate. Section 1: terminal  

Energy Technology Data Exchange (ETDEWEB)

A detailed definitive cost estimate is given for an ethanol/gasohol storage and blending terminal serving a planned distillery at a Louisiana sugar factory. Included are an analysis of the accuracy of the estimate, labor rates efficiency, materials and labor escalation, as well as detailed calculations for each account of the project. (LEW)

1982-04-01

32

Cloning and expression of recombinant, functional ricin B chain.  

UK PubMed Central (United Kingdom)

The cDNA encoding the B chain of the plant toxin ricin has been cloned and expressed in monkey kidney COS-M6 cells. The recombinant B chain was detected by labeling the transfected cells with [35S]methionine...Full Text Available

1987-08-01

33

A direct role for serum albumin in the cellular uptake of long-chain fatty acids.  

UK PubMed Central (United Kingdom)

The interaction of long-chain fatty acids with cells is important for their uptake and metabolism, as well as their involvement in signalling processes. The majority of long-chain fatty acids circulating...Full Text Available

1995-05-15

34

Characteristics of sugar uptake by immature maize embryos  

Energy Technology Data Exchange (ETDEWEB)

Characteristics of sugar uptake by immature maize embryos were determined in vitro utilizing a /sup 14/C-sugar solution incubation method. Hexose uptake rates were greater than those for sucrose, however, all showed biphasic kinetics. Glucose and fructose saturable components were evidence at <50 mM and sucrose at <5 mM. Chemical inhibitors (CCCP, DNP, NaCN, and PCMBS) and low temperature reduced sugar uptake. Sucrose influx was pH dependent while glucose was not. Embryos maintained a high sucrose to hexose ratio throughout development. At 25 days after pollination sucrose levels exceeded 200 mM while hexose levels remained below 5 mM. Glucose was rapidly converted to sucrose upon transport into the embryo. These circumstantial data indicate that sugar uptake by immature maize embryos is metabolically dependent and carrier mediated. Furthermore, sucrose transport appears to occur against its ...

1986-04-01

35

Calcination of Fluorinel-sodium waste blends using sugar as a feed additive (formerly WINCO-11879)  

Energy Technology Data Exchange (ETDEWEB)

Methods were studied for using sugar as a feed additive for converting the sodium-bearing wastes stored at the Idaho Chemical Processing Plant into granular, free flowing solids by fluidized-bed calcination at 500{degrees}C. All methods studied blended sodium-bearing wastes with Fluorinel wastes but differed in the types of sugar (sucrose or dextrose) that were added to the blend. The most promising sugar additive was determined to be sucrose, since it is converted more completely to inorganic carbon than is dextrose. The effect of the feed aluminum-to-alkali metal mole ratio on calcination of these blends with sugar was also investigated. Increasing the aluminum-to-alkali metal ratio from 0.6 to 1.0 decreased the calcine product-to-fines ratio from 3.0 to 1.0 and the attrition index from 80 to 15%. Further increasing the ratio to 1.25 had no effect.

1992-06-01

36

Biosynthesis of hyaluronan: direction of chain elongation  

UK PubMed Central (United Kingdom)

The mechanism of hyaluronan biosynthesis in vertebrates had been proposed to occur at the reducing end of growing chains. This mechanism was questioned because a recombinant synthase appeared to add...Full Text Available

2006-09-15

37

Electricity production from the biomass of the sugarcane industry in Mauritius  

Energy Technology Data Exchange (ETDEWEB)

The analysis of bagasse use indicates that the production of exportable electricity from sugar cane factories in Mauritius can be increased from the current level of between 10 and 20 kWh to around 60 kWh per tonne cane crushed. If the bagasse is dried and pelletized, and cane tops and leaves (CT and L) also used, electricity production can be further increased to around 100-110 kWh per tonne of cane crushed. An economic analysis of the process shows that the cost of electricity generated within the sugar industry in Mauritius is competitive with that of electricity produced from fossil fuels. In addition, it is shown that almost twice the current annual electricity consumption, or the postulated annual electricity consumption for the year 2000, of the island can be provided by the Mauritian Sugar Industry. 10 references.

1984-01-01

38

Alcohol fermentation in olive oil extraction effluents  

Energy Technology Data Exchange (ETDEWEB)

Eight culture-collection yeast strains of various species and five newly isolated stains were tested for both growth in olive oil extraction effluents and fermentation of the sugars in the same media. The culture-collection yeast strains did not grow in an effluent containing 2.86% sugar (w/v), 8 g/litre phenolic substances, 4.58 g/litre titratable acidity and pH 4.96, whereas the newly isolated strains of Torulopsis sp. MK-1, Saccharomyces norbensis MC-1, S. oleaceus MC-2 and S. oleaginosus grew well and fermented the sugars. In the medium mentioned above, they produced alcohol in amounts of 1.63 to 1.38%, respectively. None of the yeasts grew in an olive oil extraction effluent vacuum-concentrated to over 13-14% of dry matter. The strain of T. sp. MK-1 showed a higher stability.

1989-01-01

41

Metal nanoparticle inks  

Energy Technology Data Exchange (ETDEWEB)

Stabilized silver particles comprise particles comprising silver, a short-chain capping agent adsorbed on the particles, and a long-chain capping agent adsorbed on the particles. The short-chain capping agent is a first anionic polyelectrolyte having a molecular weight (Mw) of at most 10,000, and the long-chain capping agent is a second anionic polyelectrolyte having a molecular weight (Mw) of at least 25,000. The stabilized silver particles have a solid loading of metallic silver of at least 50 wt %.

2011-04-12

45

Application of dose factors for decay chains  

International Nuclear Information System (INIS)

... dose rates inhalation iodine 134 krypton 88 nuclear decay quality factor

47

Enhancing supply chain solutions with the application of chaos theory  

British Library Electronic Table of Contents (United Kingdom)

Purpose ? The purpose of this article is to expand the base of supply chain knowledge by applying chaos theory principles to selected supply chain functions. Design/methodology/approach ? Researchers borrow chaos theory from the natural sciences, provide a basic explanation, and then examine how it may be applied to enhance supply chain management techniques. Findings ? Chaos theory principles are used to assist in the examination of forecasting, product design, and inventory management challenges currently facing supply chain practitioners. Research limitations/implications ? Application of chaos theory to various supply chain issues and key functional areas may produce an increase in the level of understanding of supply chain ambiguity and how chaos theory may provide valuable insight in...

2006-01-01

48

Effects of cell culture conditions on antibody N-linked glycosylation-what affects high mannose 5 glycoform  

British Library Electronic Table of Contents (United Kingdom)

Abstract The glycosylation profile of therapeutic antibodies is routinely analyzed throughout development to monitor the impact of process parameters and to ensure consistency, efficacy, and safety for clinical and commercial batches of therapeutic products. In this study, unusually high levels of the mannose-5 (Man5) glycoform were observed during the early development of a therapeutic antibody produced from a Chinese hamster ovary (CHO) cell line, model cell line A. Follow up studies indicated that the antibody Man5 level was increased throughout the course of cell culture production as a result of increasing cell culture medium osmolality levels and extending culture duration. With model cell line A, Man5 glycosylation increased more than twofold from 12% to 28% in the fed-batch process...

2011-01-01

49

Waste to value  

Energy Technology Data Exchange (ETDEWEB)

The basic technology behind bioethanol production is tried and tested. Alcohol is produced through the fermentation of sugar, which when processed can be used as a biofuel. Now, however, a multitude of new technologies are set to also make cellulose available as a raw material for ethanol production. (orig.)

2010-07-01

50

Uptake and utilization of nutrients by developing kernels of Zea mays L  

Energy Technology Data Exchange (ETDEWEB)

The mechanisms involved in amino acid and sugar uptake by developing maize kernels were investigated. In the pedicel region of maize kernel, the site of nutrient unloading from phloem terminals, amino acids are accumulated in considerable amounts and undergo significant interconversion. A wide spectrum of enzymatic activities involved in the metabolism of amino acids is observed in these tissues. Subsequently, amino acids are taken up by the endosperm tissue in processes which require energy and the presence of carrier proteins. Conversely, no evidence was found that energy and carriers are involved in sugar uptake. This process of sugar uptake is not inhibited by metabolic inhibitors and shows nonsaturable kinetics, but the uptake is pH-dependent. L-glucose is taken up at a significantly reduced rate in comparison to D-glucose uptake. Based on analysis of radioactivity distribution among sugar ...

1987-01-01

51

The Effects of Temperature on the Labellar Chemoreceptors of the Blowfly  

UK PubMed Central (United Kingdom)

In the labellar chemosensory hairs of the blowfly, Phormia regina Meigen, stationary amplitudes of the slow potentials induced by salt and sugar stimulations were decreased to 50–80%...Full Text Available

1972-02-01

52

Retardation of Bean Leaf Senescence by Benzyladenine and Its Influence on Phosphate Metabolism 1  

UK PubMed Central (United Kingdom)

The levels of glucose, sugar phosphates, and adenosine phosphates were determined in primary leaves of intact bean plants during normal senescence and compared to leaves in which senescence was delayed...Full Text Available

1970-10-01

53

Photosynthesis by sugar-cane leaves  

UK PubMed Central (United Kingdom)

1. Radioactive products in detached leaf segments were examined after periods of steady-state photosynthesis in 14CO2. 2. After exposure to 14CO2 for approx....Full Text Available

1966-10-01

54

Phloem loading: an integrated approach  

Energy Technology Data Exchange (ETDEWEB)

This study focuses on the regulation of sucrose transport across the plasmalemma. Initially, we re-examined the use of leaf discs to study the kinetics of phloem loading using Allium cepa leaves. All tissues exhibited the same linear plus saturable profile as Beta vulgaris, except fructose uptake into the inner parenchyma and bundle-sheath cells; in this case the response was linear. These results indicate that all tissues of the leaf retrieve exogenous sucrose such that kinetics from leaf discs cannot be taken to represent phloem loading per se. We continued our study by investigating the influence of internal sugars on sugar transport across the plasmalemma. We found that if internal sugars were manipulated by heat-girdling techniques or DCMU treatment there was no appreciable change in sucrose influx. However, longer term heat-girdling decreased sucrose uptake. These data indicate that carbohydrate partitioning among the ...

1986-01-01

55

Pathway of Sugar Transport in Germinating Wheat Seeds  

UK PubMed Central (United Kingdom)

Three homeologous genes encoding a sucrose (Suc) transporter (SUT) in hexaploid wheat (Triticum aestivum), TaSUT1A, 1B, and 1D, were...Full Text Available

2006-08-01

56

Isoenzymes of Sugar Phosphate Metabolism in Endosperm of Germinating Castor Beans 1  

UK PubMed Central (United Kingdom)

Two isoenzymes each of phosphoglucomutase, hexose phosphate isomerase, aldolase, fructose diphosphatase, phosphofructokinase, and 6-phosphogluconate dehydrogenase have been separated by DEAE-cellulose...Full Text Available

1981-06-01

57

Influence of invertase activity and glycerol synthesis and retention on fermentation of media with a high sugar concentration by Saccharomyces cerevisiae.  

UK PubMed Central (United Kingdom)

In the past, the fermentation activity of Saccharomyces cerevisiae in substrates with a high concentration of sucrose (HSuc), such as sweet bread doughs, has been linked inversely to invertase activity...Full Text Available

1997-01-01

58

Increased Ethanol Productivity in Xylose-Utilizing Saccharomyces cerevisiae via a Randomly Mutagenized Xylose Reductase?  

UK PubMed Central (United Kingdom)

Baker's yeast (Saccharomyces cerevisiae) has been genetically engineered to ferment the pentose sugar xylose present in lignocellulose biomass. One of the reactions controlling the...Full Text Available

2010-12-01

59

Genetic engineering of group 2 sigma factor SigE widely activates expressions of sugar catabolic genes in Synechocystis species PCC 6803.  

Science.gov (United States)

Metabolic engineering of photosynthetic organisms is required for utilization of light energy and for reducing carbon emissions.Control of transcriptional regulators is a powerful approach for changing cellular dynamics, because a set of genes is concomitantly regulated. Here, we show that overexpression of a group 2 ? factor, SigE, enhances the expressions of sugar catabolic genes in the unicellular cyanobacterium, Synechocystis sp. PCC 6803. Transcriptome analysis revealed that genes for the oxidative pentose phosphate pathway and glycogen catabolism are induced by overproduction of SigE. Immunoblotting showed that protein levels of sugar catabolic enzymes, such as glucose-6-phosphate dehydrogenase, 6-phosphogluconate dehydrogenase, glycogen phosphorylase, and isoamylase, are increased. Glycogen levels are reduced in the SigE-overexpressing strain grown under light. Metabolome analysis revealed that metabolite levels of the TCA cycle and ...

2011-07-11

60

Efficacy of standard glucose-based and reduced-osmolarity maltodextrin-based oral rehydration solutions: effect of sugar malabsorption.  

UK PubMed Central (United Kingdom)

Previously we reported that standard oral rehydration salts (ORS) solution is not as effective as a reduced-osmolarity glucose-based ORS for the treatment of children with acute noncholera diarrhoea:...Full Text Available

1996-01-01

61

Effect of discriminative plant-sugar feeding on the survival and fecundity of Anopheles gambiae  

UK PubMed Central (United Kingdom)

BackgroundA previous study showed for Anopheles gambiae s.s. a gradation of feeding preference on common plant species growing in a malaria holoendemic area in western...Full Text Available

62

Diversity of Microbial Sialic Acid Metabolism  

UK PubMed Central (United Kingdom)

Sialic acids are structurally unique nine-carbon keto sugars occupying the interface between the host and commensal or pathogenic microorganisms. An important function of host sialic acid is to regulate...Full Text Available

2004-03-01

63

Diversity and activity of sugar transporters in nematode-induced root syncytia  

UK PubMed Central (United Kingdom)

The plant-parasitic nematode Heterodera schachtii stimulates plant root cells to form syncytial feeding structures which synthesize all nutrients required for successful nematode development....Full Text Available

2009-07-01

64

Beverage patterns and trends among school-aged children in the US, 1989-2008  

UK PubMed Central (United Kingdom)

BackgroundHigh intake of sugar-sweetened beverages in childhood is linked to increased risk of obesity and type II diabetes later in life. Using three nationally representative surveys...Full Text Available

65

Ameliorating effects of industrial sugar residue on the Jales gold mine spoil (NE Portugal) using Holcus lanatus and Phaseolus vulgaris as indicators  

Energy Technology Data Exchange (ETDEWEB)

A residue of the sugar industry can be used in revegetation programs on metal contaminated sites. - Phytostabilisation of bare heavily contaminated substrate, such as abandoned mine sites, is considered a very appropriate technology in order to diminish erosion and dispersion of contaminants into the surroundings. In this short-term pot study, application of industrial sugar residue (ISR), a waste product of the sugar industry, proved to ameliorate spoils conditions for plant performance by elevating pH and immobilising several metals. Although arsenate concentrations were positively correlated to spoil pH and spoil treatment with ISR mobilised As, growth of both Phaseolus vulgaris and Holcus lanatus improved significantly after applications of 3.75 g ISR kg{sup -1} dry spoil. Nutrient uptake from the substrate, with the exception of potassium, was elevated by ISR. As a remediation technique ISR application could be ...

2003-09-01

66

Anaerobic fermenter-decanter for the purification of residual water from sugar refineries, with recovery of combustible methane  

Energy Technology Data Exchange (ETDEWEB)

An anaerobic fermenter-decanter for the purification of residual water from the sugar industry, with recovery of methane, consists of a tank with inclined walls, with a central agitator on a vertical shaft. A flexible cover anchored by its periphery to the walls of the tank and totally submerged forms a collecting pocket for the fermentation gases. The water to be purified is introduced, after being heated to about 35, towards the bottom of the tank near the agitator. A metal collecting bell with submerged edges and with the shaft of the agitator passing axially through it is connected by its edges to a central opening of the cover. The purification yields may exceed 90%.

1981-10-06

67

The chain mechanism in catalytic cracking. The chain mechanism in catalytic cracking  

Energy Technology Data Exchange (ETDEWEB)

The cracking of 2-methylpentane on USHY at 300, 400, 450, and 500[degrees]C is interpreted in detail in terms of a chain mechanism. The kinetic equation developed from this mechanism fits the experimental data very well. The contribution of chain processes to the overall rate of conversion depends on the kinetic chain length, which in turn depends on the surface coverage by carbenium ions and their reactivities. Kinetic parameters were obtained at all four temperatures. A detailed examination of the kinetics shows that chain processes are more important at low reaction temperatures, whereas protolytic cracking dominates at higher temperatures. The parameters also show that both competitive inhibition by products and the rate of catalyst decay increase with increasing reaction temperature. Furthermore, they show that carbenium ions formed on Broensted sites are more stable than carbonium ions. 39 refs., ...

1993-03-01

68

Supply chain planning using multi-stage stochastic programming  

British Library Electronic Table of Contents (United Kingdom)

Purpose - The purpose of this paper is to explore the functionality of multistage programming approach on network supply chain structure. Design/methodology/approach - The general supply chain structure is considered and the supply chain planning model is developed using a two stage programming approach. The same model is extended to cover the applicability and advantages of a multi-stage programming approach. Findings - A multi-period supply chain model for new product launches under uncertain demand for supply chain network structure has been developed. The model allows simultaneous determination of optimum procurement quantity, production quantity across the different plants, transportation routes and the outsourcing cost in case of shortages. The proposed multi-stage model is compared ...

2008-01-01

69

Agent Simulation of Chain Bankruptcy  

CERN Document Server

We have conducted an agent-based simulation of chain bankruptcy. The propagation of credit risk on a network, i.e., chain bankruptcy, is the key to nderstanding largesized bankruptcies. In our model, decrease of revenue by the loss of accounts payable is modeled by an interaction term, and bankruptcy is defined as a capital deficit. Model parameters were estimated using financial data for 1,077 listed Japanese firms. Simulations of chain bankruptcy on the real transaction network consisting of those 1,077 firms were made with the estimated model parameters. Given an initial bankrupt firm, a list of chain bankrupt firms was obtained. This model can be used to detect high-risk links in a transaction network, for the management of chain bankruptcy.

2007-01-01

70

Stations Maidanak2  

Science.gov (United States)

Identification of the Ranging System Reference Point (SRP) ... Daylight Filter Type : (SPECTRAL FILTER/FABRY-PEROT/etc) Dayl. Filt. ... INT/etc) Edit Criterion 1st Chain : (ITERATIVE n.n SIGMA/MANUAL/NONE/etc) Edit Criterion 2nd Chain ...

71

Stations Maidanak1  

Science.gov (United States)

Identification of the Ranging System Reference Point (SRP) ... Daylight Filter Type : (SPECTRAL FILTER/FABRY-PEROT/etc) Dayl. Filt. ... INT/etc) Edit Criterion 1st Chain : (ITERATIVE n.n SIGMA/MANUAL/NONE/etc) Edit Criterion 2nd Chain ...

72

Selection and characterization of ricin toxin A-chain mutations in Saccharomyces cerevisiae.  

UK PubMed Central (United Kingdom)

A DNA sequence encoding the A chain of ricin toxin (RTA) from the castor bean plant, Ricinus communis, was placed under GAL1 promoter control and transformed into Saccharomyces cerevisiae. Induction...Full Text Available

1989-02-01

73

Prevention of guanine modification and chain cleavage during the solid phase synthesis of oligonucleotides using phosphoramidite derivatives.  

UK PubMed Central (United Kingdom)

Phosphoramidite reagents can phosphitylate guanine bases at the O6-position during solid phase synthesis and serious chain cleavage occurs if the base phosphitylation is not eliminated before the iodine/water...Full Text Available

1986-08-26

74

Prevention of chain cleavage in the chemical synthesis of 2'-silylated oligoribonucleotides.  

UK PubMed Central (United Kingdom)

Strong aqueous ammonium hydroxide used to remove N-acyl protecting groups from synthetic oligoribonucleotides causes removal of some alkylsilyl protecting groups from 2'-hydroxyls and leads to chain...Full Text Available

1989-05-11

75

NAME=\\  

Wastenet

...Agriculture Analysis of food supply chains and linkages in relation to quality and safety assurances Dept of Primary Industries, Australia Impact of food chain quality assurance requirements on farmer adoption and competitiveness UK Research Councils Review of environmental certification through farm assurance followed by industry developmental workshop Agriculture & ...

76

Mutation analysis of the ferritin L-chain gene in age-related cataract  

UK PubMed Central (United Kingdom)

PurposeTo investigate whether acquired somatic mutations in the iron response element of the ferritin L-chain gene account for the age-related cataract.MethodsThe...Full Text Available

77

Identification and Characterization of Retinoid-Active Short-Chain Dehydrogenases/Reductases in Drosophila melanogaster  

UK PubMed Central (United Kingdom)

BackgroundIn chordates, retinoid metabolism is an important target of short-chain dehydrogenases/reductases (SDRs). It is not known whether SDRs play a role in retinoid...Full Text Available

2009-10-01

78

Human papillomavirus infection and anal carcinoma. Retrospective analysis by in situ hybridization and the polymerase chain reaction.  

UK PubMed Central (United Kingdom)

To examine the association of human papillomavirus (HPV) infection with anal squamous cell carcinoma, the authors applied the highly sensitive polymerase chain reaction (PCR) and in situ hybridization...Full Text Available

1992-06-01

79

Detection of Ockelbo virus RNA in skin biopsies by polymerase chain reaction.  

UK PubMed Central (United Kingdom)

A sensitive assay based on the polymerase chain reaction for the detection of Ockelbo virus RNA was developed. Two primer pairs from the gene coding for the E2 glycoprotein were chosen. By use of a...Full Text Available

1993-08-01

80

Detection of Chlamydia trachomatis in genital swabs: comparison of commercial and in house amplification methods with culture  

UK PubMed Central (United Kingdom)

AIMS: To evaluate the sensitivity of the Roche Cobas, Roche Amplicor plate kit, ligase chain reaction (LCR), and an in house polymerase chain reaction (PCR) by titration of purified elementary bodies...Full Text Available

1998-08-01

81

Conditions for the selective labelling of the 66 000 dalton chain of the acetylcholine receptor by the covalent non-competitive blocker 5-azido-["3H]trimethisoquin  

International Nuclear Information System (INIS)

A photoaffinity derivative of the local anesthetic trimethisoquin, 5-azido-["3H]trimethisoquin (5-A["3H]T) labelled bands of app. mol. wt 50 k and 66 k. To explain the rather paradoxical labelling by 5-A["3H]T of two polypeptide chains instead of one, three possibilities were considered: (i) The site for non-competititve blockers is not carried by the 50 k or 66 k chain; however, these chains lie in the vicinity of the binding site and become preferentially labelled since they present chemical groups with which the nitrene group of 5-A["3H]T reacts. (ii) The 50 k and 66 k chains are different but carry binding sites for non-competitive blockers with similar reactivities. (iii) The 50 k chain labelled by 5-A["3H]T derives from the 66 k chain by proteolysis. These results show that the third alternative is the correct one. Under conditions which limit proteolysis, ...

82

A Comparison of the Metabolic Fate of Fatty Acids of Different Chain Lengths in Developing Oilseeds  

UK PubMed Central (United Kingdom)

To determine if medium and long chain fatty acids can be appropriately metabolized by species that normally produce 16 and 18 carbon fatty acids, homogenates of developing Cuphea wrightii, Carthamus...Full Text Available

1989-07-01

83

Spin operator matrix elements in the quantum Ising chain: fermion approach  

CERN Document Server

Using some modification of the standard fermion technique we derive factorized formula for spin operator matrix elements (form-factors) between general eigenstates of the Hamiltonian of quantum Ising chain in a transverse field of finite length. The derivation is based on the approach recently used to derive factorized formula for Z_N-spin operator matrix elements between ground eigenstates of the Hamiltonian of the Z_N-symmetric superintegrable chiral Potts quantum chain. The obtained factorized formulas for the matrix elements of Ising chain coincide with the corresponding expressions obtained by the Separation of Variables Method.

2010-01-01

84

Measuring relative probability of Am-242 #beta#-decay  

International Nuclear Information System (INIS)

... americium 241 americium 242 beta decay chain reactions integral doses mass

85

Global Value Chains and Open Networks: The Case of Italian Industrial Districts  

British Library Electronic Table of Contents (United Kingdom)

Italian district small and medium enterprises (SMEs) developed aggressive strategies to extend their sales networks and supply chains abroad. Literature on districts offered alternative explanations about the impacts of internationalization on local manufacturing systems. The authors consider the evolution of Italian districts in the framework of global value chain approach, focusing on the role of leading firms. Based on a survey of 650 Italian SMEs and financial indicators, the paper describes the rise of a new district firm model, the open network, which becomes a key node of global value chains. The paper also analyses the relationships among internationalization, innovation strategies and performance of SMEs.

2010-01-01

87

Molecular basis of factor VIII inhibition by human antibodies. Antibodies that bind to the factor VIII light chain prevent the interaction of factor VIII with phospholipid.  

UK PubMed Central (United Kingdom)

Most antibodies to factor VIII have recently been shown to react with discrete regions of the factor VIII light chain (within the C2 domain) and/or the factor VIII heavy chain (within the amino-terminal...Full Text Available

1989-06-01

88

Device for the inspection of curved pipes in steam raising units  

Energy Technology Data Exchange (ETDEWEB)

The chain of eddy current probes and a film cassette probe, which responds to radiation from a radio-active source in one of the heat exchanger pipes is examined. The probes are moved by nylon pipes on both ends of the chain through the pipe to be examined. The nylon pipes are bent off load. In this way the probes on the chain will adjust near to the plane of bending of the pipes to be tested.

1980-01-03

89

Integration of manufacturing and distribution networks in a global car company - network models and numerical simulation  

British Library Electronic Table of Contents (United Kingdom)

Global supply chain practices and their effects have received considerable attention over the last two decades. In the recent past, the need for integration across supply chains has been identified as a key for effective and efficient operations of supply chains. This is observed with the increasing trend of collaborative partnerships among supply chain partners. This paper presents an integrated approach for manufacturing and distribution networks within the supply chain system of a global car company. The paper shows that the integration of manufacturing and distribution networks creates the environment for effective planning of many components and execution/follow-up of those plans. These components include materials, resources, operations/activities, suppliers and customers. The main f...

2011-01-01

90

Analysis of the bullwhip effect in multi-product, multi-stage supply chain systems-a simulation approach  

British Library Electronic Table of Contents (United Kingdom)

This research aims to develop a simulation approach based on system dynamics modelling (SDM) and adaptive network based fuzzy inference system (ANFIS) for quantifying and reducing the bullwhip effect in a multi-product, multi-stage supply chain. The proposed model is comprised of three groups of variables influencing the bullwhip effect, namely the structure of a supply chain network, supply chain contributions (ordering process in regular situation or when a supplier has a promotion or shortage gaming) and supply chain performances (the number of defects and ordering lead time). As a result, a two layer simulation model is developed with three generic models. The flexibility of this proposed approach is its ability to model various types of ordering policies which are basic inventory poli...

2010-01-01

91

A social network-based organizational model for improving knowledge management in supply chains  

British Library Electronic Table of Contents (United Kingdom)

Purpose - This paper seeks to provide a social network-based model for improving knowledge management in multi-level supply chains formed by small and medium-sized enterprises (SMEs). Design/methodology/approach - This approach uses social network analysis techniques to propose and represent a knowledge network for supply chains. Empirical experience from an exploratory case study in the construction sector is also presented. Findings - This proposal improves the establishment of inter-organizational relationships into networks to exchange knowledge among the companies along the supply chain and to create specific knowledge by promoting confidence and motivation. Originality/value - This proposed model is useful for academics and practitioners in supply chain management to gain a better un...

2011-01-01

92

Risk of Colon Cancer and Coffee, Tea, and Sugar-Sweetened Soft Drink Intake: Pooled Analysis of Prospective Cohort Studies  

British Library Electronic Table of Contents (United Kingdom)

Background The relationships between coffee, tea, and sugar-sweetened carbonated soft drink consumption and colon cancer risk remain unresolved. Methods We investigated prospectively the association between coffee, tea, and sugar-sweetened carbonated soft drink consumption and colon cancer risk in a pooled analysis of primary data from 13 cohort studies. Among 731 441 participants followed for up to 6-20 years, 5604 incident colon cancer case patients were identified. Study-specific relative risks (RRs) and 95% confidence intervals (CIs) were estimated using Cox proportional hazards models and then pooled using a random-effects model. All statistical tests were two-sided. Results Compared with nonconsumers, the pooled multivariable relative risks were 1.07 (95% CI = 0.89 to 1.30, Ptrend = ...

2010-01-01

93

Haiti: energy efficiency in the sugar and manufacturing industries  

Energy Technology Data Exchange (ETDEWEB)

A review of energy use in Haiti, aimed at identifying possible projects to complement current A.I.D. support for institution building and energy planning within the Ministry of Mines and Energy Resources (MMRE), is presented. Key findings are that: (1) the sugar and manufacturing industries rely heavily on biomass fuels - wood, charcoal, and bagasse (sugar cane residue); and (2) demand for commercial energy and for electricity is growing rapidly despite supply constraints. The report calls for A.I.D. to: initiate a program to reduce biomass consumption (which is causing severe soil erosion and deforestation), especially in the small distilleries called guildives; collaborate with MMRE and the World Bank to develop a detailed workplan to promote energy efficiency in the guildives, focusing on technology development; help MMRE and the private sector to project Haiti's industrial energy and electricity needs through the year 2000; and ...

1985-03-28

94

Extrusion as a thermo-mechanical pre-treatment for lignocellulosic ethanol  

Energy Technology Data Exchange (ETDEWEB)

Two physical pre-treatment methods, particle size reduction by grinding and thermo-mechanical extrusion, were evaluated as alternatives to traditional biomass pretreatments for lignocellulosic ethanol. Commonly available agricultural co-products wheat bran and soybean hull were the model substrates. Extrusion led to higher reducing sugar yields as compared to grinding for wheat bran, but not in the case of soybean hulls. The best combination of extrusion screw speed and maximum barrel temperature were 7 Hz/150 C and 3.7 Hz/110 C. The use of a solvent mixture (sodium hydroxide, urea, and thiourea) and calcium chloride solution in combination with extrusion treatment did not lead to improvement in reducing sugar yield. However, extensive washing to get rid of solvents and enzymatic inhibitors improved the conversion efficiency substantially, resulting in total reducing sugar yields of 60-73% and 25-36%, respectively, for ...

2010-12-15

95

Effect of drought and abscisic acid application on the osmotic adjustment of four wheat cultivars  

International Nuclear Information System (INIS)

The accumulation of osmolytes in leaf tissues and the abscisic acid-induced stomatal closure are well-recognized mechanisms associated with drought tolerance in crop plants. We determine the response in terms of osmotic potential and the contents of leaf proline, glycine betaine and soluble sugar at booting and grain filling stages of four wheat (Triticum aestivum L.) cultivars to drought and exogenously applied abscisic acid (ABA) in a pot study. Leaf sample were collected 3, 6 and 9 days after drought induction and at 48 and 72 h of re-watering (recovery). Marked decreases in osmotic potential associated with the accumulation of proline, glycine betaine and soluble sugars occurred under conditions of drought stress Accession 011320 was most sensitive to drought and showed the largest decrease in osmotic potential and least accumulation of proline, sugar and glycine betaine The inhibitory effects of drought stress were ...

2010-02-01

96

Dynamics of growth/mature-related substances in vegetables using specific triple labelled compound  

Energy Technology Data Exchange (ETDEWEB)

Dynamics and metabolism of sugars translocated into the fruit region were investigated in tomato using {sup 14}C-labelled compounds. The translocation substance in tomato is thought to be sucrose, but the amount of sucrose in its fruit is very small. Therefore, the degradation of sucrose in the fruit and its translocation to the fruit was investigated. The sucrose was digested into hexoses such as glucose, fructose, etc. and the degradation rate was considerably low. In the stage of thickening growth, sucrose was more extensively converted into other substances except for sugars compared with the coloring stage. Then, {sup 14}C-labelled fructose was given through its gynophore to investigate the degree of reproduction to sucrose. The fructose level in the fruit reached the platean by 48 hrs after the addition and gradually decreased. The radioactivities were detected in sugars, organic acids and other alcohol soluble ...

1998-02-01

97

Integrated production of wood fuels and pulpwood using chain-flail delimbing-debarking technology; Puupolttoaineen ja selluhakkeen integroitu tuotanto ketjukarsinta-kuorintatekniikalla  

Energy Technology Data Exchange (ETDEWEB)

The objective of the research was to develop a procurement method for small-diameter pulpwood based on chain-flail delimbing-debarking method. The study consisted of four parts: Development of the chain-flail delimbing-debarking method (based on Peterson Pacific DDC 5000 device); Combined chain-flail delimbing and drum-debarking; Processing and procurement of the chain-flail delimbing chips and; Intensifying of the timber debarking in chain-flail delimbing. The project was coordinated by Metsaeteho, and it was carried out as cooperation between Metsaeteho, the Finnish Forest Research Institute (METLA), VTT Energy, Pertti Szepaniak Oy and Enso-Gutzeit Oy. A calculation model, by which it is possible to determine the costs of pulpwood chips and fuel-rawmaterials formed beside the pulpwood chips while using different kinds of procurement methods and chains, was ...

1996-12-31

98

Genetic organization of Bungarus multicinctus protease inhibitor-like proteins.  

Science.gov (United States)

The structural organization of the genes encoding Bungarus multicinctus protease inhibitor-like proteins (PILPs), PILP-1, PILP-2 and PILP-3, are reported in this study. Unlike PILP-2 and PILP-3, recombinant PILP-1 exhibited inhibitory activity on trypsin. PILP genes and B chain genes shared identical organization with three exons interrupted by two introns in similar positions. On the contrary, intron 1 of these genes had a similar size, a notable variation with the size of intron 2 was observed. It was found that two regions at the second intron of B1 chain and B2 chain genes were absent in that of PILP genes. Noticeably, intronic insertion in the second intron of B chain genes appeared in the promoter region of PILP-1 gene, but not in that of PILP-2 and PILP-3 genes. Comparative analyses of PILP genes and B chain genes showed that the protein-coding regions of the exons are more ...

2008-03-27

99

A study of membrane protein defects and alpha hemoglobin chains of red blood cells in human beta thalassemia  

International Nuclear Information System (INIS)

The soluble pool of alpha hemoglobin chains present in blood or bone marrow cells was measured with a new affinity method using a specific probe, beta A hemoglobin chain labeled with ["3H]N-ethylmaleimide. This pool of soluble alpha chains was 0.067 #+-# 0.017% of hemoglobin in blood of normal adult, 0.11 #+-# 0.03% in heterozygous beta thalassemia and ranged from 0.26 to 1.30% in homozygous beta thalassemia intermedia. This elevated pool of soluble alpha chains observed in human beta thalassemia intermedia decreased 33-fold from a value of 10% of total hemoglobin in bone marrow cells to 0.3% in the most dense red blood cells. The amount of insoluble alpha chains was measured by using the polyacrylamide gel electrophoresis in urea and Triton X-100. In beta thalassemia intermedia the amount of insoluble alpha chains was correlated with the decreased spectrin ...

100

Stoichio-kinetic modeling and optimization of chemical synthesis: Application to the aldolic condensation of furfural on acetone  

British Library Electronic Table of Contents (United Kingdom)

The condensation reaction of furfural (F) on acetone (Ac) gives a high added value product, the 4-(2-furyl)-3-buten-2-one (FAc), used as aroma in alcohol free drinks, ice, candies, gelatines and other products of current life. This synthesis valorises the residues of sugar cane treatment since furfural is obtained by hydrolysis of sugar cane bagasse followed by vapor training extraction. In the face of numerous and complex reactions involved in this synthesis, it is very complicated to define the kinetic laws from exact stoichiometry. A solution allowing to cope the problem consists in identifying an appropriate stoichiometric model. It does not attempt to represent exactly all the reaction mechanisms, but proposes a mathematical support to integrate available knowledge on the transformati...

2008-01-01

101

Scientific challenges of bioethanol production in Brazil  

British Library Electronic Table of Contents (United Kingdom)

Bioethanol (fuel alcohol) has been produced by industrial alcoholic fermentation processes in Brazil since the beginning of the twentieth century. Currently, 432 mills and distilleries crush about 625 million tons of sugarcane per crop, producing about 27 billion liters of ethanol and 38.7 million tons of sugar. The production of bioethanol from sugarcane represents a major large-scale technology capable of producing biofuel efficiently and economically, providing viable substitutes to gasoline. The combination of immobilization of CO2 by sugarcane crops by photosynthesis into biomass together with alcoholic fermentation of this biomass has allowed production of a clean and high-quality liquid fuel that contains 93% of the original energy found in sugar. Over the last 30?years, several inn...

2011-01-01

102

Root exudation of sugars, amino acids, and organic acids by maize as affected by nitrogen, phosphorus, potassium, and iron deficiency  

British Library Electronic Table of Contents (United Kingdom)

Abstract Root exudates play a major role in the mobilization of sparingly soluble nutrients in the rhizosphere. Since the amount and composition of major metabolites in root exudates from one plant species have not yet been systematically compared under different nutrient deficiencies, relations between exudation patterns and the type of nutrient being deficient remain poorly understood. Comparing root exudates from axenically grown maize plants exposed to N, K, P, or Fe deficiency showed a higher release of glutamate, glucose, ribitol, and citrate from Fe-deficient plants, while P deficiency stimulated the release of -aminobutyric acid and carbohydrates. Potassium-starved plants released less sugars, in particular glycerol, ribitol, fructose, and maltose, while under N deficiency lower am...

2011-01-01

103

Metabolite profiling of sucrose effect on the metabolism of Melissa officinalis by gas chromatography-mass spectrometry  

British Library Electronic Table of Contents (United Kingdom)

The effect of sugar on plant metabolism, which is known to be similar to hormone-like signaling, was metabolomically studied using Melissa officinalis (lemon balm). The metabolite profiles of M. officinalis treated with sucrose were analyzed by gas chromatography-mass spectrometry (GC-MS) and principal component analysis (PCA). A total of 64 metabolites from various chemical classes including alcohols, amines, amino acids, fatty acids, inorganic acids, organic acids, phosphates, and sugars were identified by GC-MS. Three groups treated with different sucrose concentrations were clearly separated by PCA of their metabolite profiles, indicating changes in the levels of many metabolites depending on the sucrose concentration. Metabolite profiling revealed that treatment with a higher sucrose ...

2011-01-01

104

Influence of sodium chloride and sodium sulfate salinities on photosynthetic carbon assimilation in peanut  

International Nuclear Information System (INIS)

The effect of NaCl and Na_2SO_4 treatments on chlorophyll content, rate of "1"4C assimilation and products of photosynthesis in peanut (Arachish hypogaea L.) variety TMV-10 has been investigated. It was observed that chlorophyll content was affected mainly by NaCl, Na_2SO_4 treatment lowered the rate of photosynthetic "1"4CO_2 fixation. The analysis of labelled products revealed that the salts affect the carbon metabolism differently. The radioactivity was found to be accumulated in fractions of sugars and sugarphosphates in the leaves of NaCl treated plants. Na_2SO_4 treatment brought about considerable decline in labelling of sugars and an increase in labelling of amino acids and sugarphosphates. (orig.).

1980-01-01

105

Extrusion as a thermo-mechanical pre-treatment for lignocellulosic ethanol  

British Library Electronic Table of Contents (United Kingdom)

Two physical pre-treatment methods, particle size reduction by grinding and thermo-mechanical extrusion, were evaluated as alternatives to traditional biomass pretreatments for lignocellulosic ethanol. Commonly available agricultural co-products wheat bran and soybean hull were the model substrates. Extrusion led to higher reducing sugar yields as compared to grinding for wheat bran, but not in the case of soybean hulls. The best combination of extrusion screw speed and maximum barrel temperature were 7 Hz/150 ?C and 3.7 Hz/110 ?C. The use of a solvent mixture (sodium hydroxide, urea, and thiourea) and calcium chloride solution in combination with extrusion treatment did not lead to improvement in reducing sugar yield. However, extensive washing to get rid of solvents and enzymatic inhibit...

2010-01-01

106

Effect of processing of dates into date juice concentrate and appraisal of its quality characteristics  

British Library Electronic Table of Contents (United Kingdom)

Date palm (Phoenix dactylifera) is widely cultivated in Kutch district of Gujarat and the fruits are harvested at immature stage before the onset of monsoon to prevent spoilage. The immature date fruits with less commercial value were used for processing into date juice concentrate. Immature dates were crushed and treated with 0.1% pectinase enzyme for 120 min to obtain maximum juice. Date juice was found to be rich in reducing sugars (16.1%) and total sugars (18.3%). Juice was pasteurized at 85?C to inactivate the enzyme, cooled and centrifuged at 3000 rpm to get clear juice. The juice was concentrated in a thin film evaporator to a total soluble solids (TSS) of 76?Brix in 2 passes. Chemical composition of date juice during different stages of concentration was determined. Date juice conc...

2010-01-01

107

Tests for mutagencity of free radicals formed in irradiated sugars and amino acids  

International Nuclear Information System (INIS)

Radicals formed in gamma-irradiated crystals of galactose and glycine were found, upon dissolution, to cause mutagenesis of Salmonella typhimurium strains TA-98 and TA-100. Although the reproducibility of the results has not been adequately determined, they suggest the possibility of developing a test to measure the mutagenic-carcinogenic potential of radiation-induced free radicals with a microbial system.

1977-05-01

108

Sinterable powders  

International Nuclear Information System (INIS)

A description is given of sinterable powders and methods of producing sintered products using such powders. The powders consist of (a) a particulate ceramic material, e.g. SiC, having specified particle size and surface area; (b) a carbon source material, e.g. sugar or a phenol-formaldehyde resin; and (c) a residue from a solution of H3BO3, B2O3, or mixtures of these as sintering aid. (U.K.).

109

Plant biomass and stem juice of the C4 sugarcane at elevated growth CO2 and temperature  

Science.gov (United States)

Plant biomass, stem juice and stem sugar were determined for four sugarcane cultivars grown for three months at daytime [CO2] of 360 (ambient) and 720 (doubled) ppm and temperatures (T) of 1.5 (near-ambient) and 6.0C higher than outside ambient T. Leaf area and biomass, stem biomass, stem juice and ...

110

Evaluation of Dry Chemicals by Photoacoustic Imaging  

Science.gov (United States)

In this study, an apparatus suitable to photoacoustic (PA) imaging to measure blood-analysis and urinalysis is fabricated and its measurement scheme has been established for the first time. The PA imaging of urinalysis test strip, blood sugar test strip, and cholesterol test strip is performed. A calibration curve of PA measurement is obtained for a urine test strip. The detectivity is better than that obtained by an eye-measurement.

1992-10-01

111

Design and operation of a quadruple effect evaporator with concentrator  

Energy Technology Data Exchange (ETDEWEB)

For the sugar industry, a new system of multiple-effect evaporation consuming minimal steam has been designed by means of a mathematical model and its advantages and characteristics are analysed. A way is found to overcome difficulty in operation and instability of the amount of steam consumed. Statistical data obtained using the new system are compared with the old system and show an economic profit as well as confirming the validity of the model. (author)

1993-02-01

112

Crystallization and preliminary X-ray diffraction studies of two thermostable ?-galactosidases from glycoside hydrolase family 36  

UK PubMed Central (United Kingdom)

α-Galactosidases from thermophilic organisms have gained interest owing to their applications in the sugar industry. The α-galactosidases AgaA, AgaB and AgaA A355E mutant from Geobacillus...Full Text Available

113

Direct photoaffinity labeling by nucleotides of the apparent catalytic site on the heavy chains of smooth muscle and Acanthamoeba myosins  

International Nuclear Information System (INIS)

The heavy chains of Acanthamoeba myosins, IA, IB and II, turkey gizzard myosin, and rabbit skeletal muscle myosin subfragment-1 were specifically labeled by radioactive ATP, ADP, and UTP, each of which is a substrate or product of myosin ATPase activity, when irradiated with uv light at 0"0C. With UTP, as much as 0.45 mol/mol of Acanthamoeba myosin IA heavy chain and 1 mol/mol of turkey gizzard myosin heavy chain was incorporated. Evidence that the ligands were associated with the catalytic site included the observations that reaction occurred only with nucleotides that are substrates or products of the ATPase activity; that the reaction was blocked by pyrophosphate which is an inhibitor of the ATPase activity; that ATP was bound as ADP; and that label was probably restricted to a single peptide following limited subtilisin proteolysis of labeled Acanthamoeba myosin IA heavy chain and extensive cleavage ...

114

Isolation and amino acid sequence of a short-chain neurotoxin from an Australian elapid snake, Pseudechis australis.  

Science.gov (United States)

A short-chain neurotoxin Pseudechis australis a (toxin Pa a) was isolated from the venom of an Australian elapid snake Pseudechis australis (king brown snake) by sequential chromatography on CM-cellulose, Sephadex G-50 and CM-cellulose columns. Toxin Pa a has an LD50 (intravenous) value of 76 micrograms/kg body wt. in mice and consists of 62 amino acid residues. The amino acid sequence of Pa a shows considerable homology with those of short-chain neurotoxins of elapid snakes, especially of true sea snakes. PMID:4091794

1985-12-01

115

The chain of the natural gas in Colombia  

International Nuclear Information System (INIS)

The book tries about the International and national aspects, natural gas situation, production, consumption, prices, demand projection, energetic plans, norms and laws of the natural gas in Colombia

2007-01-01

117

Sentence Processing: Linking Language to Motor Chains  

UK PubMed Central (United Kingdom)

A growing body of evidence in cognitive science and neuroscience points towards the existence of a deep interconnection between cognition, perception and action. According to this embodied perspective...Full Text Available

118

SEVEN-YEAR WILKINSON MICROWAVE ANISOTROPY PROBE (WMAP - LAMBDA - NASA  

Science.gov (United States)

of the determinant of the parameter covariance matrix for each ... parameter covariance matrix, as obtained from the Markov chains. The basic set ...

119

Risk trade-off linked to temporary storage function in road transports  

British Library Electronic Table of Contents (United Kingdom)

Today?s demand on high supply chain performance requires higher awareness about supply chain risks and uncertainty. The purpose of this paper is to analyse the role of temporary storage in the transport network in a supply chain perspective. The primary research question concerns the purpose or role of temporary storage and whether management of temporary storage can contribute to reducing risks and uncertainty in the supply chain. The research is based on a system-theoretical approach, which emphasizes a holistic view instead of the characteristics of the different parts. The research method used in this paper is abductive. Existing theories are used to formulate a framework which leads to a conceptual model description of the temporary storage function. This model is then supported and v...

2011-01-01

120

Nuclear data sheets for A = 101  

Energy Technology Data Exchange (ETDEWEB)

Detailed level and decay schemes are presented for the nuclei of the A = 101 mass chain. The level properties obtained from decay and reaction experiments are shown in the drawings. Experimental methods, references, and comments are given in the text.

1985-08-01

121

Nuclear data sheets for A = 101  

International Nuclear Information System (INIS)

Detailed level and decay schemes are presented for the nuclei of the A = 101 mass chain. The level properties obtained from decay and reaction experiments are shown in the drawings. Experimental methods, references, and comments are given in the text.

122

How can supply networks increase firm value? A causal framework to structure the answer  

British Library Electronic Table of Contents (United Kingdom)

The recent literature in the field of supply chain management emphasizes the role of inter-organizational networks and the integration of vertical reproduction networks (supply chains) in particular as a key factor for value creation. However, the literature includes little empirical evidence. This situation suggests the need to appraise investments in such networks or supply chains carefully. How can a decision maker reliably assess the effect of investing in inter-organizational network arrangements on firm value? This article takes up this issue and suggests a framework consisting of five components to help answer the question. The task of the framework is to support the structuring and revelation of the causal chain between investments in the network on the one hand and the effect of t...

2009-01-01

123

Electronic properties of Nb_3Ge and Nb_3Al from self-consistent pseudopotentials. II. Bonding, electronic charge distributions, and structural transformation  

International Nuclear Information System (INIS)

Electron charge distributions are presented for Nb_3Ge, Nb_3Al, and two other hypothetical A-15 structures. Results indicate that the bonding in these materials is mainly metallic in character with some covalentlike bonding between Nb-chain atoms. We find significant coupling between neighboring chains and also between chain atoms and atoms at the cubic site. Comparison is made with various theoretical models. Investigation of the charge character of states near E/sub F/ suggests further developments in current theories on the structural transformation of A-15 compounds. The effect of chain dimerization on electronic states and charge distribution of Nb_3Ge is also investigated.

124

Electronic properties of Nb3Ge and Nb3Al from self-consistent pseudopotentials. II. Bonding, electronic charge distributions, and structural transformation  

Science.gov (United States)

Electron charge distributions are presented for Nb3Ge, Nb3Al, and two hypothetical A-15 structures. Results indicate that the bonding in these materials is mainly metallic in character with some covalentlike bonding between Nb-chain atoms. We find significant coupling between neighboring chains and also between chain atoms and atoms at the cubic site. Comparison is made with various theoretical models. Investigation of the charge character of states near EF suggests further developments in current theories on the structural transformation of A-15 compounds. The effect of chain dimerization on electronic states and charge distribution of Nb3Ge is also investigated.

1979-02-01

125

Electronic properties of Nb/sub 3/Ge and Nb/sub 3/Al from self-consistent pseudopotentials. II. Bonding, electronic charge distributions, and structural transformation  

Science.gov (United States)

Electron charge distributions are presented for Nb/sub 3/Ge, Nb/sub 3/Al, and two other hypothetical A-15 structures. Results indicate that the bonding in these materials is mainly metallic in character with some covalentlike bonding between Nb-chain atoms. We find significant coupling between neighboring chains and also between chain atoms and atoms at the cubic site. Comparison is made with various theoretical models. Investigation of the charge character of states near E/sub F/ suggests further developments in current theories on the structural transformation of A-15 compounds. The effect of chain dimerization on electronic states and charge distribution of Nb/sub 3/Ge is also investigated.

1979-02-15

126

Efficacy and Safety of a New Vaginal Contraceptive Antimicrobial Formulation Containing High Molecular Weight ...  

Science.gov (United States)

... commercial material manufactured utilizing chlorinated hydrocarbons for the sulfonation of a long chain polystyrene to produce high ... ...

127

Creating reliable pharmaceutical distribution networks and supply chains in African countries: Implications for access to medicines  

British Library Electronic Table of Contents (United Kingdom)

The presence of inefficient distribution networks and supply chains of medicines creates problems in that even if African countries can secure steep, sustainable cost-containing procurements, access to needed medicines may still be impaired. The expected health benefits from affordable pricing or subsidies on prices of medicines may not be realized. This article evaluates drug supply chains in African countries and advocates for consolidated private wholesale markets and multiplicity of retail pharmacies. Public supply chains should be shortened and supported by contracting out with private distributors, including wholesalers and retail pharmacies. Additionally, drug regulatory authorities should be allowed to charge registration fees that are proportionate to the costs of technical regula...

2009-01-01

128

Baxter Q-operator and Separation of Variables for the open SL(2,R) spin chain  

CERN Document Server

We construct the Baxter Q-operator and the representation of the Separated Variables (SoV) for the homogeneous open SL(2,R) spin chain. Applying the diagrammatical approach, we calculate Sklyanin's integration measure in the separated variables and obtain the solution to the spectral problem for the model in terms of the eigenvalues of the Q-operator. We show that the transition kernel to the SoV representation is factorized into the product of certain operators each depending on a single separated variable. As a consequence, it has a universal pyramid-like form that has been already observed for various quantum integrable models such as periodic Toda chain, closed SL(2,R) and SL(2,C) spin chains.

2003-01-01

129

Alpha-toxin of Staphylococcus aureus.  

UK PubMed Central (United Kingdom)

Alpha-toxin, the major cytotoxic agent elaborated by Staphylococcus aureus, was the first bacterial exotoxin to be identified as a pore former. The protein is secreted as a single-chain, water-soluble...Full Text Available

1991-12-01

130

Acetylcholine Receptor Binding Characteristics of Snake and ...  

Science.gov (United States)

... Naja oxiana neurotoxin 1, Bungarus multicinctus or-bungarotoxin) and short-chain group (Naja naja atra cobrotoxin, Naja oxiana neurotoxin 11. ...

2011-05-13

131

A4 business finance 2010 v1c:Layout 1  

Wastenet

Regional sector organisations providing information, networking, supply chain and business development opportunities.Available to companies in the following sectors:

132

A child with hyperferritinemia: Case report  

UK PubMed Central (United Kingdom)

Hereditary hyperferritinemia cataract syndrome (HHCS) is a rare condition caused by mutations in the gene coding for the light chain of ferritin; it does not lead to iron overload, but it is associated...Full Text Available

133

Worldwide differences in the incidence of type I diabetes are associated with amino acid variation at position 57 of the HLA-DQ beta chain.  

UK PubMed Central (United Kingdom)

The presence of an amino acid other than aspartic acid at position 57 of the HLA-DQ beta chain (non-Asp-57) is highly associated with susceptibility to insulin-dependent diabetes mellitus (IDDM), whereas...Full Text Available

1990-10-01

134

The superconducting critical temperature of radiation damaged A-15 compounds  

International Nuclear Information System (INIS)

A simple model is used to explain the decrease in superconducting critical temperature with damage observed for irradiated A-15 compounds. A truncated t-matrix approximation is used to describe the disorder along the one-dimensional transition metal chains. Three dimensionality is introduced by the inclusion of interaction between transition metal atoms on different chains. Numerical fits to experiment are discussed in the conclusion. (author).

135

Production and characterization of monoclonal antibodies recognizing the alpha-chain subunits of human ia alloantigens.  

UK PubMed Central (United Kingdom)

Two monoclonal antibodies, TAL-1B5 and TAL-3C3, specific for human Ia alpha-chain subunits have been produced by fusing P3/NSI/1-Ag4-1 mouse myeloma cells with spleen cells from a BALB/c mouse immunized...Full Text Available

1983-12-01

136

Pair formation in two-electron correlated chains  

Energy Technology Data Exchange (ETDEWEB)

We study two correlated electrons in a nearest-neighbour tight-binding chain, with both on-site and nearest-neighbour interaction. Both the cases of parallel and antiparallel spin are considered. In addition to the free electron band for two electrons, there are correlated bands with positive or negative energy, depending on whether the interaction parameters are repulsive or attractive. Electrons form bound states, with amplitudes that decay exponentially with separation. Conditions for such states to be filled at low temperatures are discussed.

2003-05-21

137

Nuclear data sheets for A = 177  

International Nuclear Information System (INIS)

Evaluated nuclear structure and decay data for all nuclei within the A=177 mass chain are presented. Significant new information is included since the previous evaluation of this mass chain. The present work supersedes the earlier one by E. Browne (1993Br06), published in Nuclear Data Sheets 68, 747 (1993).

2003-04-01

138

Discrimination of Listeria monocytogenes from other Listeria species by ligase chain reaction.  

UK PubMed Central (United Kingdom)

A ligase chain reaction assay based on a single-base-pair difference in the V9 region of the 16S rRNA gene (16S rDNA) was developed to distinguish between Listeria monocytogenes and other Listeria species....Full Text Available

1992-11-01

139

Detection of pathogenic Yersinia enterocolitica in foods and water by immunomagnetic separation, nested polymerase chain reactions, and colorimetric detection of amplified DNA.  

UK PubMed Central (United Kingdom)

A two-step polymerase chain reaction (PCR) procedure with two nested pairs of primers specific for the yadA gene of Yersinia enterocolitica was developed. The PCR assay identified all common pathogenic...Full Text Available

1993-09-01

140

Comments dataset for A=177.  

Energy Technology Data Exchange (ETDEWEB)

Evaluated nuclear structure and decay data for all nuclei within the A=177 mass chain are presented. Significant new information is included since the previous evaluation of this mass chain. The present work supersedes the earlier one by E. Browne (1993Br06), published in Nuclear Data Sheets 68, 747 (1993).

2003-04-01

141

The TSG-6/HC2-mediated transfer is a dynamic process shuffling heavy chains between glycosaminoglycans  

DEFF Research Database (Denmark)

The heavy chain (HC) subunits of the bikunin proteins are covalently attached to a single chondroitin sulfate (CS) chain originating from bikunin and can be transferred to different hyaluronan (HA) molecules by TSG-6/HC2. In the present study, we demonstrate that HCs transferred to HA may function as HC donors in subsequent transfer reactions, and we show that the CS of bikunin may serve as an HC acceptor, analogous to HA. Our data suggest that TSG-6/HC2 link HCs randomly on the CS chain of bikunin, in contrast to the ordered attachment observed during the biosynthesis. Moreover, the results show that the transfer activity is indifferent to the new HC position, and the relocated HCs are thus prone to further TSG-6/HC2-induced transfer reactions. The data suggest that HCs may be transferred directly from HA to HA without the involvement of the bikunin CS chain. The results demonstrate reversibility of ...

2010-01-01

142

Liposome encapsulation of lipophilic N-alkyl-propanediamine platinum complexes: impact on their cytotoxic activity and influence of the carbon chain length  

Energy Technology Data Exchange (ETDEWEB)

Antitumor platinum(II) complexes derived from N-alkyl-propanediamine differing in the length of their carbon chain (C8, C10, C12 and C14) were incorporated in liposomes and the cytotoxic activity of these formulations was evaluated against tumor (A{sub 549}, MDA-MB-231, B16-F1 and B16-F10) and non-tumor (BHK-21 and CHO) cell lines. Stable and monodisperse liposome suspensions incorporating the platinum complexes were obtained from the lipid composition consisting of distearoyl-sn-glycero-3-phosphocholine, cholesterol and 1,2-distearoyl-sn-glycero- 3-phosphoethanolamine-N-(methoxy(polyethylene glycol)-2000) at 5:3:0.3 molar ratio. The entrapment efficiency (EE%) of the platinum complexes in liposomes increased with the carbon chain length. EE% was higher than 80% in C12- and C14-derivatives. The effect of liposome encapsulation on the cytotoxic activity of the complexes was found to depend on the carbon chain length. These ...

2010-07-01

143

Hemoglobin of mice with radiation-induced mutations at the hemoglobin loci  

International Nuclear Information System (INIS)

Chemical analyses were done on the abnormal hemoglobins of the five (101 x SEC)F_1 offspring of X- irradiated adult SEC mice to determine which hemoglobin genes were expressed in each hemoglobin variant. Three offspring of irradiated SEC males did not express either of the two kinds of #alpha#-chains normally found in all SEC mice. The deficient #alpha#-chain synthesis caused these mice to exhibit an #alpha#-thalassemia similar to human #alpha#-thalassemia. Scanning electron microscopy was used to show that many erythrocytes of mice with #alpha#-thalassemia have bizarre shapes; e.g. many erythrocytes appeared flattened or had thorny projections (acanthocytes). One mutant with a tandem duplication of a segment of chromosome 7 (site of locus determining #beta#-chain structure) produced twice as much SEC as 101 #beta#-chain polypeptides. One mutant that probably arose by non-disjunction of chromosome 7's ...

144

First detection of lamella-gyroid-cylinder phase transition of neat polyethylene-poly(ethylene oxide) diblock copolymers on the basis of synchrotron WAXD/SAXS and infrared/Raman spectral measurements  

International Nuclear Information System (INIS)

The phase transition behaviour of polyethylene-b-poly(ethylene oxide) (PE-b-PEO) diblock copolymer with relatively short chain lengths has been studied on the basis of temperature dependent infrared and Raman spectral measurements and synchrotron WAXD/SAXS simultaneous measurements, from which the concrete structural changes were deduced successfully from the various levels of molecular chain conformation, chain packing mode and higher-order structure. The higher-order structure has been found to transform between lamella, perforated lamella, gyroid, cylinder and sphere structures. The inner structural changes occurring in the polyethylene and poly(ethylene oxide) parts have been related with these morphological changes. The morphological transition from lamella to gyroid occurs with keeping the crystalline state of polyethylene parts. This apparently curious transition can be interpreted reasonably by assuming the ...

2009-08-01

145

Assembly of Linear Nano-Chains from Iron Oxide Nanospheres with Asymmetric Surface Chemistry  

Science.gov (United States)

Besides the multifunctionality, another equally important aspect of nanoparticles is their engineerability to control the geometrical and chemical properties during fabrication. In this work, we exploited this aspect to define asymmetric surface chemistry of an iron oxide nanosphere by controlling the topology of ligand expression on its surface resulting in a particle with two faces, one displaying only amines and the other only thiols. Specifically, amine-functionalized iron oxide nanospheres were attached on a solid support via a crosslinker containing a disulfide bridge. Liberation of the nanosphere using thiolytic cleavage created thiols on the portion of the particle's surface that interacted with the solid support. Employing a solid-phase strategy and a step-by-step addition of particles, the two unique faces on the same nanosphere served as fittings to assemble them into linear nano-chains. Assembly of chains with various lengths and ...

2011-01-06

146

Turgor-regulated sugar release in sugarbeet leaves  

Energy Technology Data Exchange (ETDEWEB)

Under drought conditions, sucrose distribution (osmotic adjustment vs. export) may be regulated at the mesophyll plasmalemma/tonoplast. Leaves were given {sup 14}CO{sub 2} for a 30/30 min pulse/chase. Peeled leaf discs were put in low or high osmotic solutions to monitor release of labeled solutes. High turgor increased efflux rates double those at low turgor. About 30% and 55% of the released label was in the sugar (sucrose + hexose) fractions at low and high turgor, respectively. Response to changes in cell turgor was rapid and reversible. PCMBS had no effect on efflux. NEM and CCCP enhanced efflux at high turgor. Presence of unlabeled sucrose in the wash solutions greatly enhanced sucrose efflux in a turgor-dependent manner; suggesting the presence of a sucrose exchange system, which appeared to be at the tonoplast. Turgor-regulated efflux involved both the tonoplast and plasmalemma. However, efflux across the plasmalemma was not carrier-mediated.

1989-04-01

147

Sweet savings  

Energy Technology Data Exchange (ETDEWEB)

Ways of reducing the excessive energy consumption in the Polish sugar industry are examined. The three main areas where energy reduction measures might be taken are: reducing the process heat demand which arises from the need to evaporate excess water from the juice supplied to the crystallisers; improving the effectiveness of the thermal system by moving from the present four-effect evaporation to five-effect evaporation and using crystallisation vapours for juice heating; replacing old steam boilers with more efficient units. Most Polish sugar factories are relatively small, however, and the energy saving measures, all of which require the installation of more modern equipment, are not economically feasible in the short term. Moreover, the stringent limits on atmospheric emissions which come into effect in 1998 will require factories to use low-sulphur coal and install costly glue-gas cleaning equipment. With limited funds available this may ...

1996-12-12

148

Studies on sugar recognizing and binding protein (lectin) in marine invertebrates (physiological control of lectin); Kaiyo musekitsui dobutsu no toninshiki ketsugo tanpakushitsu (lectin) ni kansuru kenkyu (lectin no seiriteki seigyo)  

Energy Technology Data Exchange (ETDEWEB)

Lectin is a generic name of sugar binding protein in living organisms. With an objective to clarify physiological functions of lectin in marine invertebrates and utilize it as a useful material in the bio-chemical industry, studies were carried out on the chemical structure, distribution in living organisms and structural changes of lectin. Lectin is involved with such physiological actions as immunity reactions, generation and differentiation, Ca fixation and symbiosis. Lectin is one of the main components of lymph fluid in shellfish and crustacean, and is a multi-functional polymer that is related with foreign substance recognition, Ca transport, and shell formation. Lectin of a certain kind shows strong actions to accelerate cell division. Organs and cells were cultivated for lectin producing organs and lectin producing cells to verify the production thereof. Elucidation was attempted in a molecular level on such physiological functions as foreign substance ...

1993-03-01

149

Structure-activity-relationships (SAR) in pyrimidine nucleoside transport  

International Nuclear Information System (INIS)

Several series of pyrimidine nucleosides were evaluated as part of a larger program to develop non-invasive brain imaging agents. The interaction of these antitumor/antiviral nucleosides with an NBMPR-sensitive murine erythroctye nucleoside transporter was evaluated by determining their inhibitory effect (K_i) on zero-trans influx of thymidine. Within each series of compounds, which had F, Cl, Br or I as halogen substituents, an increase in size of the halogen atom or a decrease in electronegativity decreased affinity for the transporter. Partition coefficients (P) of these pyrimidine nucleosides were measured to determine their potential to diffuse across the blood-brain-barrier (BBB). Most of the pyrimidine nucleosides had lower P values (log P < 0.9), and were considered to be poor candidates for simple diffusion across the BBB, although an active BBB transport mechanism for some nucleosides could be operative. For a given series, it was found that log P correlated with log 1/K_i ...

150

Separation of the components of the binary mixture ethanol-water by steam flux in solid phase column; Separacao dos componentes da mistura binaria etanol-agua por passagem do vapor em coluna de fase solida  

Energy Technology Data Exchange (ETDEWEB)

This paper deals with the energy required to separate ethanol from an aqueous solution in a distillation column containing a solid phase. The solid phases evaluated consisted of either an amylatious (ground corn) or a cellulose (sugar cane bagasse) absorber whit particle sizes smaller than 4 mm. The water-retention capacity of each solid phase was measured by passing vapors or ethanol-water mixtures through the solid phase. When starting with initial concentrations bellow the azeotropic point, ethanol concentrations up to 99,5% (on corn) and 97,2% (on sugar cane) were achieved. The water content was evaluated potentiometrically (Karl`Fischer). Regarding the 2-4 mm ground corn solid phase column, the energy consumed was estimated to be reduced by 15,6% and 60% (by weight) ethanol-water mixture respectively. (author) 11 refs., 2 figs., 2 tabs

1987-12-31

151

Feasibility of creation of new markets for activated charcoal and its exploitation  

Energy Technology Data Exchange (ETDEWEB)

The size of the market for pulverized activated charcoal and particulate activated charcoal prepared by the Association of Inorganic Chemicals of Japan is 55,000t/y (1987) in total. Individually, some fields showed the expansion such as water purification, water treatment and gas treatment on the one hand, but on the other hand, several fields showed the decline such as sugar refining, dextrin sugar and soda glutamate. As a whole, the market showed no marked fluctuations or a very slight increase. Many of the above usages are traditional in the chemical industry and the food industry, etc., and the new usages developed in the past several years have not grown to influence the statistics as yet. Selection of raw material is the key for determining the character of activated charcoal. And the factors of determining the characteristic features are fine pore, surface area and surface activity (catalystic activity). Furthermore, the function ...

1988-10-01

152

Energy and agriculture in the Haitian economy: A computable general equilibrium model  

Energy Technology Data Exchange (ETDEWEB)

This report documents a computable general equilibrium (CGE) model of the economy of Haiti, emphasizing energy use in agriculture. CGE models compare favorably with econometric models for developing countries in terms of their ability to take advantage of available data. The model of Haiti contains ten production sectors: manufacturing, services, transportation, electricity, rice, coffee, sugar cane, sugar refining, general agriculture, and fuelwood and charcoal. All production functions use functional forms which permit factor substitution. Consumption is specified for three income categories of consumers and a government sector with a linear expenditure system (LES) of demand equations. The economy exports four categories of products and imports six. Balanced trade and capital accounts are required for equilibrium. Total sectoral allocations of land, labor and capital are constrained to equal the quantities of these inputs in the Haitian ...

1988-02-01

153

Energy analysis of biochemical conversion processes of biomass to bioethanol  

Energy Technology Data Exchange (ETDEWEB)

Bioethanol is among the most promising of biofuels that can be produced from different biomass such as agricultural products, waste and byproducts. This paper reported on a study that examined the energy conversion of different groups of biomass to bioethanol, including lignocelluloses, starches and sugar. Biochemical conversion generally involves the breakdown of biomass to simple sugars using different pretreatment methods. The energy needed for the conversion steps was calculated in order to obtain mass and energy efficiencies for the conversions. Mass conversion ratios of corn, molasses and rice straw were calculated as 0.3396, 0.2300 and 0.2296 kg of bioethanol per kg of biomass, respectively. The energy efficiency of biochemical conversion of corn, molasses and rice straw was calculated as 28.57, 28.21 and 31.33 per cent, respectively. The results demonstrated that lignocelluloses can be efficiently converted with specific microorganisms ...

2010-07-01

154

Effects of soil pH on rhizoctonia damping-off of sugar beet and disease suppression induced by soil amendment with crop residues  

British Library Electronic Table of Contents (United Kingdom)

Effects of soil pH on damping-off of sugar beet by R. solani (AG2-2) and soil suppressiveness against the disease were studied by comparing disease incidences in pasteurized versus non-pasteurized, infested soils. Soil pH was correlated neither to disease incidence in five soils ranging from pH?4.5 to 7.2 nor to indigenous disease suppressiveness, the difference in disease incidences between non-treated soil and its pasteurized counterpart. When an alkaline soil was acidified with H2SO4, disease suppression markedly declined, increasing disease incidence in the non-pasteurized soil. Inversely, disease suppression was enhanced when an acidic soil was neutralized by adding Ca(OH)2. Soil amendment with dried peanut plant residue suppressed the disease in two pasteurized, near-neutral soils, l...

2011-01-01

155

Effect of increased CO sub 2 and decreased O sub 2 on photosynthesis, and carbon allocation in source leaves  

Energy Technology Data Exchange (ETDEWEB)

The effect of raising the rate of photosynthesis on the allocation of carbon between sucrose and starch was studied by means of steady-state radiolabeling. Sugar beet source leaves on intact plants were exposed to ambient levels of CO{sub 2} and O{sub 2} for 3 hrs. Next CO{sub 2} was raised to 600 {mu}LL{sup {minus}3} for 3 hrs then O{sub 2} was decreased to 2% for 3 hrs. Rates of net carbon exchange (NCE), export, and starch and sucrose synthesis were measured. NCER increased by 30% under the combined treatments and the proportion of photosynthate allocated to starch and to sucrose did not change. When O{sub 2} concentration was lowered, NCER increased but export did not and sucrose accumulated. This observation, and our earlier conclusion that export rate usually equals sucrose synthesis rate, lead us to conclude that low O{sub 2} directly inhibited export. Low O{sub 2} treatment causes sucrose to accumulate in a sugar beet leaf which usually ...

1990-05-01

156

Coffee and tea consumption and endometrial cancer risk in a population-based study in New Jersey  

British Library Electronic Table of Contents (United Kingdom)

We evaluated the role of tea and coffee and substances added (sugar/honey, creamers, and milk) on endometrial cancer risk in a population-based case?control study in six counties in New Jersey, including 417 cases and 395 controls. Multivariate odds ratios (OR) and 95% confidence intervals (CI) were computed using unconditional logistic regression. There was a moderate inverse association with coffee consumption, with an adjusted OR of 0.65 (95% CI: 0.36?1.17) for women who reported more than two cups/day of coffee compared to none. Tea consumption appeared to increase risk (OR: 1.93; 95% CI: 1.08?3.45), but after including the variables sugar/honey and cream/milk added to tea in the model, the risk estimate was attenuated and no longer statistically significant (OR: 1.77; 95% CI: 0.96?3.2...

2010-01-01

157

?Tasting and wasting?? behavior in non-human primates: Aberrant behavior or normal behavior in ?times of plenty??  

British Library Electronic Table of Contents (United Kingdom)

The purpose of this study was to develop a foraging model that engenders large meals. Eight free-feeding baboons were first given periodic access to a chocolate sugar-coated candy (M & Ms?) and then a jelly sugar-coated candy (Skittles?). Baboons had access to food 24?h each day, but they had to complete a two-phase operant procedure in order to eat. Responding on one lever during a 30-min appetitive phase was required before animals could start a consumption phase, where responding on another lever led to food delivery, i.e., a meal. 3?days a week for 8 or 9?weeks baboons received candy during the first meal and then food pellets were available: a 2?month interval when only pellets were available separated periods of candy access. All baboons ate as much candy in the single candy meal as ...

2006-01-01

158

Part IV. Radioactivity in plants  

International Nuclear Information System (INIS)

The results are presented of a study in radioactivity of forage (grass, alfalfa, clover), cereals (wheat, oats, rye, barley) and different agriculture products (fodder beet, sugar beet, leguminous plants, poppy, tobacco, maize, potatoes). Total beta activity, "4"0K, "9"0Sr and "1"3"7Cs activities were studied for the period 1962 to 1975 in selected localities in Slovakia. The highest values of "9"0Sr and "1"3"7Cs were measured in 1963, the lowest levels of "9"0Sr in 1975 while the lowest levels of "1"3"7Cs in 1973. (B.S.).

159

Locked nucleic acid (LNA): High affinity targeting of RNA for diagnostics and therapeutics  

DEFF Research Database (Denmark)

Locked nucleic acid (LNA) is a nucleic acid analogue containing one or more LNA nucleotide monomers with a bicyclic furanose unit locked in an RNA mimicking sugar conformation. This conformational restriction results in unprecedented hybridization affinity towards complementary single stranded RNA and thus, makes LNA uniquely suited for mimicking RNA structures and sequence specific targeting of RNA in vitro or in vivo. The focus of this paper is on LNAantisense, LNA-modified siRNA (siLNA), and detection and analysis of microRNAs by LNA-modified oligonucleotide probes.

2005-01-01

160

Latvian scientists research into chemical uses of timber  

Energy Technology Data Exchange (ETDEWEB)

Scientists of the Institute of Wood Chemistry of the Latvian Academy of Sciences have developed two highly efficient processes for producing furfural, a feedstock for varnishes, synthetic resins and plastics. It is made of production wastes, including branches and small-dimension timber. By one process, the raw material is chipped, treated first with diluted sulphuric acid and then with steam heated to 250 degrees C. The other uses concentrated sulphuric acid as a catalyst. Besides furfural, this process also yields sugar solutions used in alcohol and nutrient yeast production.

1982-03-20

161

Ionization and fragmentation of DNA, RNA bases induced by proton impact  

Energy Technology Data Exchange (ETDEWEB)

We present recent results obtained in the Toulouse's group that deal with proton to base and nucleoside interactions. We stress the weakness of the sugar part in the nucleoside, i.e. the uridine molecule under scrutiny. Since some parts of the fragmentation spectrum correspond to the fragmentation of a 'pure' uracil molecule, i.e. the RNA base, an 'additivity rule' seems to prevail for the nucleoside, something that still has to be confirmed. Moreover, some results that deal with the secondary electronic emission from uracil are also displayed.

2008-02-01

162

In vivo recovery of glycogen metabolism in hemolymph and tissues of a freshwater field crab Barytelphusa guerini on exposure to hexavalent chromium  

Energy Technology Data Exchange (ETDEWEB)

The in vivo toxic effects of hexavalent chromium (20 mg/liter) on hemolymph glucose, tissue glycogen, total free sugars, and active and total phosphorylases of an edible, freshwater crab Barytelphusa guerini were studied. In a 15-day exposure span followed by a 15-day postexposure recovery, the time-course alterations in these constituent segments of the glycogen metabolism indicate an inconsistent depletion in metabolite levels and elevated enzyme activities during exposure period as well as hyperglycemia. An insignificant recovery was observed in these parameters on the 15th day of the postexposure phase.

1990-08-01

163

Energy production on farms. Sustainability of energy crops  

International Nuclear Information System (INIS)

In this article the results of a study on sustainability of energy crops are discussed. Contribution to the reduction of the greenhouse effect and other environmental effects were investigated for the Netherlands. The study assumed that energy crops are grown on set-aside land or grain land. Generating electricity and/or heat from hemp, reed, miscanthus, poplar and willow show the best prospects. These crops are sustainable and may in the future be economically feasible. Ethanol from winter wheat shows the most favourable environmental effects, but is not economically efficient. Liquid fuels from oil seed rape and sugar beet are not very sustainable. 2 tabs., 4 refs.

1994-12-06

164

Temperature-induced fusion of small unilamellar vesicles formed from saturated long-chain lecithins and diheptanoylphosphatidylcholine  

Energy Technology Data Exchange (ETDEWEB)

Small unilamellar vesicles which form when gel-state long-chain phosphatidylcholines are mixed with micellar short-chain lecithins undergo an increase in size as the long-chain species melts to its liquid-crystalline form. Analysis of the vesicle population with quasi-elastic light scattering shows that the particle size increases from 90-A radius to greater than 5000-A radius. Resonance energy transfer experiments show total mixing of lipid probes with unlabeled vesicles only when the Tm of the long-chain phosphatidylcholine is exceeded. This implies that the large size change represents a fusion process. Aqueous compartments are also mixed during this transition. 31P NMR analysis of the vesicle mixtures above the phase transition shows a great degree of heterogeneity with large unilamellar particles coexisting with oligo- and multilamellar structures. Upon cooling the vesicles below the Tm, the ...

1989-10-03

165

Contamination profiles of short-chain polychlorinated n-alkanes in foodstuff samples from Japan  

Energy Technology Data Exchange (ETDEWEB)

Polychlorinated n-alkanes (PCAs) are group of chemicals manufactured by chlorination of liquid n-paraffin or paraffin wax that contain 30 to 70% chlorine by weight. Large amounts of PCAs are widely used as plasticizers for vinyl chloride, lubricants, paints, and flame retardants and number of other industrial applications. Annual global production of PCAs is approximately 300 kilo tones, with a majority having medium-carbon-chain (C14-C19) length. According to the investigation made by Kagaku Kogyo Nippon-Sha, the annual consumption of PCAs in Japan was about 83,000 tons in between 1986-2001. Short-carbon-chain (C10-C13) has been placed on the Priority Substance List under Canadian Environmental Protection Act and on the Environmental Protection Agency Toxic Release Inventory in the USA due to its potential to act as tumor promoters in mammals. Data on environment levels of PCAs is meager, nevertheless, PCAs have been measured at relatively ...

2004-09-15

166

B chain is a functional subunit of beta-bungarotoxin for inducing apoptotic death of human neuroblastoma SK-N-SH cells.  

Science.gov (United States)

beta-Bungarotoxin (beta-Bgt), a presynaptic phospholipase A(2) (PLA(2)) neurotoxin isolated from the venom of Bungarus multicinctus, consists of A chain and B chain. The goal of the present study is to explore the functional contribution of the two subunits to the toxicity of beta-Bgt. beta-Bgt was found to induce apoptotic death of SK-N-SH cells via elevating intracellular Ca(2+) and intracellular ROS production. Moreover, an activation of p38 MAPK was associated with the cytotoxicity of beta-Bgt. SB202190 (p38 MAPK inhibitor), N-acetylcysteine (antioxidant reagent), 1,2-bis(2-aminophenoxy)ethane-N,N,N,N-tetraacetic acid (BAPTA) (Ca(2+) chelator) and the inhibitors of Ca(2+) release from intracellular depots (ruthenium red and 2-aminoethoxydiphenyl borate) effectively attenuated the cytotoxicity of beta-Bgt. In sharp contrast to the inability of A chain, B chain was able to induce cytotoxic effects on ...

2007-10-13

167

T cell receptor beta chain from sea bream (Sparus aurata): Molecular cloning, expression and modelling of the complexes with MHC class I  

British Library Electronic Table of Contents (United Kingdom)

The T cell receptor is a fundamental mediator of the adaptive immune responses, since TR ab on T cells recognize foreign structures (peptides derived from processed antigens) bound to the major histocompatibility complex (MHC) on APC cells. In the present study, we report the cloning of six TRB chains cDNA sequences from gilthead sea bream (Sparus aurata), a fish of high economical impact in South Mediterranean aquaculture. The V-BETA domains have the canonical features of known teleost and mammalian TR V-BETA domains and have been divided in four different subgroups. A multiple alignment of the six sea bream TRB chains with other known TRB sequences was assembled and showed the conservation of the four cysteine residues involved in disulphide bonds and of some amino acids with an importan...

2008-01-01

168

Supply chain networks and service-dominant logic: suggestions for future research  

British Library Electronic Table of Contents (United Kingdom)

Purpose - The service-dominant (S-D) logic views supply chains as value co-creation networks. These networks promote knowledge growth amongst network members via resource deployment and coordination. The exchange of knowledge and utilization of operant resources among the network members leads to co-created service offerings and value proposals for the end-users, with the ultimate goal of transforming end-user experiences to perceptions of superior value-in-use. The purpose of this paper is to develop an illustration of the value co-creation concept and use this illustration as guide to examine the research gaps that are yet to be tapped in the area where supply chain networks and S-D logic intersects. Design/methodology/approach - The literature on S-D logic is reviewed and research gaps ...

2011-01-01

169

Miscibility enhancement of PP/PBT blends with a side-chain liquid crystalline ionomer  

British Library Electronic Table of Contents (United Kingdom)

Side-chain liquid crystalline ionomer (SLCI) containing sulfonic acid groups with a polymethylhydrosiloxane main-chain was used in the blends of polypropylene (PP) and polybutylene terephthalate (PBT) as a compatibilizer. The crystalline behavior, morphological, and mechanical properties of the blends were investigated in detail by differential scanning calorimetry (DSC), polarizing optical microscope (POM), Fourier transforms infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). Revealed by the shift of Tm in DSC thermogram and the shift of the absorbed peak in FTIR spectra, specific interaction led to stronger interfacial adhesion between these phases, which resulted in much finer dispersion of the minor PBT phase in PP matrix. The SLCI containing sulfonate acid groups ac...

2009-01-01

170

Magnetization of undoped 2-leg S=1/2 spin ladders in La{sub 4}Sr{sub 10}Cu{sub 24}O{sub 41}  

Energy Technology Data Exchange (ETDEWEB)

Magnetization data of single crystalline La{sub 4}Sr{sub 10}Cu{sub 24}O{sub 41} are presented. In this compound, doped spin chains and undoped spin ladders are realized. The magnetization, at low temperatures, is governed by the chain subsystem with a finite interchain coupling which leads to short range antiferromagnetic spin correlations. At higher temperatures, the response of the chains can be estimated in terms of a Curie-Weiss law. For the ladders, we apply the low temperature approximation for a S = 1/2 2-leg spin ladder.

2007-09-01

171

Fire retardant poly(ethylene terephthalate)/polycarbonate/triphenyl phosphite blends  

British Library Electronic Table of Contents (United Kingdom)

Flame retardant recycled PET blends containing PC and triphenyl phosphite (TPP) have been designed using the following sequential processing strategy: PET and PC are first melt blended with a transesterification catalyst, allowing the compatibilisation of the blend, before adding TPP. The presence of this last component was shown to stop the transesterification reaction between PET and PC, avoiding chain breaking. In addition, TPP acts as a chain extender of PET, allowing the average chain length to be increased. The optimized blends obtained present "V-0" UL94 rating due to a better thermal stability leading to low flammability and to the development of an important, stable and covering char layer, resulting in self-extinguishability and very low Heat Release Rates during combustion.

2008-01-01

172

Estimating Field Volatility of Soil Fumigants Using CHAIN_2D: Mitigation Methods and Comparison Against Chloropicrin and 1,3-Dichloropropene Field Observations  

British Library Electronic Table of Contents (United Kingdom)

Academic, government, and industrial field researchers have generated a significant database of field studies of the volatility of soil applied fumigants. However, limited work exists in validating physical models against field volatility data sets and fully exploring the volatility parametric response surface. Field studies quantifying atmospheric flux for soil fumigants 1,3-dichloropropene and chloropicrin are validated against the United States Department of Agriculture (USDA Salinity Laboratory) soil physics model CHAIN_2D that was modified specifically for agronomic uses of soil fumigants. Comparison between model predictions and field observations for six unique field trials in five different states indicate that CHAIN_2D effectively captures the magnitude and duration of fumigant em...

2010-01-01

173

Electronic properties of Nb_3Ge and Nb_3Al from self-consistent pseudopotentials. I. Band structure and density of states  

International Nuclear Information System (INIS)

The self-consistent-pseudopotential method is applied to the A-15 compounds Nb_3Ge and Nb_3Al. The Fermi energy is found to lie in a region of very flat bands having a bonding character along the Nb chains. Comparison with the band structures of the (nonexistent) A-15 materials Nb_3Nb and Nb_3/sup asterisk/ (chains only) suggest that the p states on the Ge and Al atoms are instrumental in determining the position of the Fermi level. There is little evidence for rigid-band behavior in the Nb_3Al/sub x/Ge/sub 1-x/ system. Studies of the effects of chain dimerization in Nb_3Ge suggest that states at R and M are more likely candidates to participate in structural transitions than states at GAMMA or X.

174

Therapy of Primary Breast Cancer  

UK PubMed Central (United Kingdom)

Most breast cancers are multicentric in origin. They drain into two primary lymphatic depots—the axilla and internal mammary chain of nodes. The incidence of metastasis to the internal mammary...Full Text Available

1970-04-01

175

The red-green visual pigment gene region in adrenoleukodystrophy.  

UK PubMed Central (United Kingdom)

Although recent data established that a specific very-long-chain fatty acyl-CoA synthetase is defective in X-linked adrenoleukodystrophy (ALD), the ALD gene is still unidentified. The ALD locus has...Full Text Available

1990-03-01

176

The Cell Non-Autonomous Nature of Electron Transport Chain-Mediated Longevity  

UK PubMed Central (United Kingdom)

SummaryThe life span of C. elegans can be increased via reduced function of the mitochondria; however, the extent to which mitochondrial alteration in a single,...Full Text Available

2011-01-07

177

Targeting Prostate Cancer Cells In Vivo Using a Rapidly Internalizing Novel Human Single-Chain Antibody Fragment  

UK PubMed Central (United Kingdom)

Human antibodies targeting prostate cancer cell surface epitopes may be useful for imaging and therapy. The objective of this study was to evaluate the tumor targeting of an internalizing human...Full Text Available

2010-03-01

178

Structure and Reaction Mechanism of Basil Eugenol Synthase  

UK PubMed Central (United Kingdom)

Phenylpropenes, a large group of plant volatile compounds that serve in multiple roles in defense and pollinator attraction, contain a propenyl side chain. Eugenol synthase (EGS) catalyzes the reductive...Full Text Available

179

Strategies for the uses of lanthanide NMR shift probes in the determination of protein structure in solutio. Application to the EF calcium binding site of carp parvalbumin.  

UK PubMed Central (United Kingdom)

The homologous sequences observed for many calcium binding proteins such as parvalbumin, troponin C, the myosin light chains, and calmodulin has lead to the hypothesis that these proteins have homologous...Full Text Available

1980-10-01

180

Stem Cell Therapies Benefit Alport Syndrome  

UK PubMed Central (United Kingdom)

Patients with Alport syndrome progressively lose renal function as a result of defective type IV collagen in their glomerular basement membrane. In mice lacking the α3 chain of type IV collagen...Full Text Available

2009-11-01

181

Some properties of beta-toxin produced by Clostridium perfringens type C.  

UK PubMed Central (United Kingdom)

Purified beta-toxin from Clostridium perfringens type C was found to be a single polypeptide chain protein with a molecular weight of approximately 30,000. The toxin was heat labile, with 75% of its...Full Text Available

1978-08-01

182

Solution structure of two molecular motor domains: nonclaret disjunctional and kinesin.  

UK PubMed Central (United Kingdom)

The effects of selected ligands on the structure of the truncated heavy-chain chemomechanical motor domains of Drosophila ncd and human kinesin were compared using the technique of transient electric...Full Text Available

1995-04-01

183

Site-specific modification of albumin by free radicals. Reaction with copper(II) and ascorbate.  

UK PubMed Central (United Kingdom)

Exposure of albumin to Cu(II) (10-100 microM) and ascorbate (0.1-2 mM) results in extensive molecular modifications, indicated by decreased fluorescence and chain breaks. The rate of utilization of...Full Text Available

1986-06-01

184

Rapid, sensitive detection of Mycoplasma pneumoniae in simulated clinical specimens by DNA amplification.  

UK PubMed Central (United Kingdom)

The polymerase chain reaction (PCR) was investigated as a means of diagnosing Mycoplasma pneumoniae infections. The target DNA sequence was a 375-bp segment of the P1 virulence protein. This DNA segment...Full Text Available

1992-12-01

185

ROMP from ROMP: A New Approach to Graft Copolymer Synthesis  

UK PubMed Central (United Kingdom)

A new strategy is presented for the synthesis of graft copolymers using only the ring-opening metathesis polymerization (ROMP). From a ROMP-derived main chain, pendant maleimide functional groups...Full Text Available

2009-06-23

186

Purification, characterization and binding interactions of the Chinese-cobra (Naja naja atra) serum antitoxic protein CSAP.  

UK PubMed Central (United Kingdom)

The characterization of the single-chain protein in Chinese-cobra (Naja naja atra) blood serum, which yields strong specific protection against the venom of the same snake, is reported. The protein,...Full Text Available

1993-07-15

187

Phosphorylation-dependent power output of transgenic flies: an integrated study.  

UK PubMed Central (United Kingdom)

We examine how the structure and function of indirect flight muscle (IFM) and the entire flight system of Drosophila melanogaster are affected by phosphorylation of the myosin regulatory light chain...Full Text Available

1997-12-01

188

Nuclear Data Sheets for A = 203  

International Nuclear Information System (INIS)

Evaluated nuclear structure and decay data for all nuclei within the A = 203 mass chain are presented. This work supersedes the earlier evaluation by S. Rab (1993Ra11), published in Nuclear Data Sheets 70, 173 (1993).

2005-05-01

190

Molecular Evidence of Bartonella Infection in Domestic Dogs from Algeria, North Africa, by Polymerase Chain Reaction (PCR)  

UK PubMed Central (United Kingdom)

Bartonella species are being recognized as important bacterial human and canine pathogens, and are associated with multiple arthropod vectors. Bartonella DNA extracted...Full Text Available

2010-08-05

191

Mechanism of L-glutamate transport in membrane vesicles from Bacillus stearothermophilus.  

UK PubMed Central (United Kingdom)

In the presence of electrochemical energy, several branched-chain neutral and acidic amino acids were found to accumulate in membrane vesicles of Bacillus stearothermophilus. The membrane vesicles contained...Full Text Available

1989-02-01

192

Localization of a critical restriction site on the I-A beta chain that determines susceptibility to collagen-induced arthritis in mice.  

UK PubMed Central (United Kingdom)

Type II collagen-induced arthritis (CIA) in mice is an autoimmune experimental model for rheumatoid arthritis. Susceptibility to CIA is associated with certain major histocompatibility complex class...Full Text Available

1989-12-01

193

Increased degradation of MYPT1 contributes to the development of tolerance to nitric oxide in porcine pulmonary artery  

UK PubMed Central (United Kingdom)

Myosin phosphatase target subunit 1 (MYPT1) is the regulatory subunit of myosin light chain phosphatase (MLCP). It plays a critical role in vasodilatation induced by cGMP-elevating agents such as nitric...Full Text Available

2010-07-01

194

Identification of Potential Calorie Restriction-Mimicking Yeast Mutants with Increased Mitochondrial Respiratory Chain and Nitric Oxide Levels  

UK PubMed Central (United Kingdom)

Calorie restriction (CR) induces a metabolic shift towards mitochondrial respiration; however, molecular mechanisms underlying CR remain unclear. Recent studies suggest that CR-induced mitochondrial...Full Text Available

195

HCN polymers characterized by solid state NMR: Chains and sheets formed in the neat liquid  

UK PubMed Central (United Kingdom)

Hydrogen cyanide polymerizes readily under a variety of conditions and significant prebiotic roles have been suggested for these polymers due to the abundance of HCN in universe. However, the structures...Full Text Available

2009-04-07

196

Genetic heterogeneity in human T-cell leukemia/lymphoma virus type II.  

UK PubMed Central (United Kingdom)

DNA from the peripheral blood mononuclear cells of 17 different individuals infected with human T-cell lymphoma/leukemia virus type II (HTLV-II) was successfully amplified by the polymerase chain reaction...Full Text Available

1993-03-01

197

Fragment condensation of peptides on teflon with radiationally grafted polystyrene  

Energy Technology Data Exchange (ETDEWEB)

In the synthesis of the peptidyl-polymer corresponding to the sequence (57-100) of the ..beta.. chain of human hemoglobin on Teflon with radiationally grafted polystyrene a comparative study was made of different methods of fragment condensation. It was shown that the most effective methods are azide condensation and condensation with the use of complex F.

1986-12-10

198

Fragment condensation of peptides on teflon with radiationally grafted polystyrene  

International Nuclear Information System (INIS)

In the synthesis of the peptidyl-polymer corresponding to the sequence (57-100) of the #beta# chain of human hemoglobin on Teflon with radiationally grafted polystyrene a comparative study was made of different methods of fragment condensation. It was shown that the most effective methods are azide condensation and condensation with the use of complex F.

199

Fluoride ion promoted deprotection and transesterification in nucleotide triesters.  

UK PubMed Central (United Kingdom)

Tetrabutylammonium fluoride will remove phenyl, trichloroethyl and cyanoethyl groups from nucleotides. In addition to the desired nucleotide products other results including chain cleavage, phosphofluoridates...Full Text Available

1979-10-10

200

Expression of embryonic hemoglobin genes in. cap alpha. -thalassemic and in. beta. -duplication mice  

Science.gov (United States)

The results of a study of the expression of embryonic hemoglobin genes in mice which show an imbalance of alpha and non-alpha chain synthesis are reported. (ACR)

1979-01-01

201

Existence and equilibration of global weak solutions to finitely extensible nonlinear bead-spring chain models for dilute polymers  

CERN Document Server

We show the existence of global-in-time weak solutions to a general class of coupled FENE-type bead-spring chain models that arise from the kinetic theory of dilute solutions of polymeric liquids with noninteracting polymer chains. The class of models involves the unsteady incompressible Navier-Stokes equations in a bounded domain in two or three space dimensions for the velocity and the pressure of the fluid, with an elastic extra-stress tensor appearing on the right-hand side in the momentum equation. The extra-stress tensor stems from the random movement of the polymer chains and is defined by the Kramers expression through the associated probability density function that satisfies a Fokker-Planck-type parabolic equation, a crucial feature of which is the presence of a center-of-mass diffusion term. We require no structural assumptions on the drag term in the Fokker-Planck equation; in particular, the drag term need not ...

2010-01-01

202

Evidence for proteolytic cleavage of brevican by the ADAMTSs in the dentate gyrus after excitotoxic lesion of the mouse entorhinal cortex  

UK PubMed Central (United Kingdom)

BackgroundBrevican is a member of the lectican family of aggregating extracellular matrix (ECM) proteoglycans that bear chondroitin sulfate (CS) chains. It is highly expressed in...Full Text Available

203

Evidence for nonrandom hydrophobicity structures in protein chains.  

UK PubMed Central (United Kingdom)

The question of whether proteins originate from random sequences of amino acids is addressed. A statistical analysis is performed in terms of blocked and random walk values formed by binary hydrophobic...Full Text Available

1996-09-03

204

Efficient Inventory Optimization of Multi Product, Multiple Suppliers with Lead Time using PSO  

CERN Document Server

With information revolution, increased globalization and competition, supply chain has become longer and more complicated than ever before. These developments bring supply chain management to the forefront of the managements attention. Inventories are very important in a supply chain. The total investment in inventories is enormous, and the management of inventory is crucial to avoid shortages or delivery delays for the customers and serious drain on a companys financial resources. The supply chain cost increases because of the influence of lead times for supplying the stocks as well as the raw materials. Practically, the lead times will not be same through out all the periods. Maintaining abundant stocks in order to avoid the impact of high lead time increases the holding cost. Similarly, maintaining fewer stocks because of ballpark lead time may lead to shortage of stocks. This also happens in the ...

2010-01-01

205

Effects of cefonicid and other cephalosporin antibiotics on male sexual development in rats.  

UK PubMed Central (United Kingdom)

The purpose of this study was to determine whether cefonicid, a cephalosporin antibiotic with a modified N-methylthiotetrazole (MTT) side chain, caused testicular toxicity when subcutaneously administered...Full Text Available

1987-07-01

206

Defining the Specificity of Cotranslationally Acting Chaperones by Systematic Analysis of mRNAs Associated with Ribosome-Nascent Chain Complexes  

UK PubMed Central (United Kingdom)

Polypeptides exiting the ribosome must fold and assemble in the crowded environment of the cell. Chaperones and other protein homeostasis factors interact with newly translated polypeptides to facilitate...Full Text Available

2011-07-01

207

Critical superparamagnetic/single-domain grain sizes in interacting magnetite particles: implications for magnetosome crystals  

UK PubMed Central (United Kingdom)

Magnetotactic bacteria contain chains of magnetically interacting crystals (magnetosome crystals), which they use for navigation (magnetotaxis). To improve magnetotaxis efficiency, the magnetosome crystals...Full Text Available

2009-12-06

208

Cardiac Myosin Is a Substrate for Zipper-interacting Protein Kinase (ZIPK)*  

UK PubMed Central (United Kingdom)

Zipper-interacting protein kinase (ZIPK) is a member of the death-associated protein kinase family associated with apoptosis in nonmuscle cells where it phosphorylates myosin regulatory light chain...Full Text Available

2010-02-19

209

Branched-chain amino acids, mitochondrial biogenesis, and healthspan: an evolutionary perspective  

UK PubMed Central (United Kingdom)

Malnutrition is common among older persons, with important consequences increasing frailty and morbidity and reducing health expectancy. On the contrary, calorie restriction (CR, a low-calorie dietary...Full Text Available

210

An analysis by low-angle neutron scattering of the structure of the acetylcholine receptor from Torpedo californica in detergent solution.  

UK PubMed Central (United Kingdom)

The acetylcholine receptor from the electric tissue of Torpedo californica is a large, integral membrane protein containing four different types of polypeptide chains. The structure of the purified...Full Text Available

1979-12-01

211

An Evaluation of the Value of Choice with Preschool Children  

UK PubMed Central (United Kingdom)

The current study examined the reinforcing effects of choosing among alternatives in a four-part evaluation. In the first study, initial-link responses in a concurrent-chains arrangement resulted in...Full Text Available

2006-01-01

212

Alpha-Hemoglobin-Stabilizing Protein: An Erythroid Molecular Chaperone  

UK PubMed Central (United Kingdom)

Alpha-hemoglobin-stabilizing protein (AHSP) is an erythroid-specific protein that acts as a molecular chaperone for the free α chains of hemoglobin. Evidence strongly suggests...Full Text Available

2011-01-01

213

Affinity maturation of human botulinum neurotoxin antibodies by light chain shuffling via yeast mating  

UK PubMed Central (United Kingdom)

Botulism is caused by the botulinum neurotoxins (BoNTs), the most poisonous substance known. Because of the high potency of BoNT, development of diagnostic and therapeutic antibodies for botulism requires...Full Text Available

2010-04-01

214

Adaptation of a Foot Plate for Use in an Isokinetic and Isotonic Leg Press  

UK PubMed Central (United Kingdom)

The use of isokinetic equipment and the leg press exercise have been major components of rehabilitation for the past several years when redeveloping muscular strength. Recently, closed kinetic chain...Full Text Available

1996-04-01

215

Accumulation of Long-Chain Glycosphingolipids during Aging Is Prevented by Caloric Restriction  

UK PubMed Central (United Kingdom)

BackgroundChronic kidney disease and end-stage renal disease are major causes of morbidity and mortality that are seen far more commonly in the aged population. Interestingly, kidney...Full Text Available

216

A post-labeling method for multiplexed and multicolored genotyping analysis of SSR, indel and SNP markers in single tube with bar-coded split tag (BStag)  

UK PubMed Central (United Kingdom)

BackgroundGenotyping analysis using capillary DNA sequencing with fluorescently labeled primer pairs obtained by polymerase chain reaction (PCR) is widely used, but is expensive....Full Text Available

217

A new approach to the prediction of the thermodiffusion for linear chain hydrocarbon binary mixtures  

Energy Technology Data Exchange (ETDEWEB)

Many attempts have been made to generate reliable thermodiffusion coefficient models for binary mixtures. This paper presented a simple analytical model for the prediction of thermal diffusion coefficients in linear chain hydrocarbon binary mixtures using the thermodynamics of irreversible process. More specifically, the model represented the net heat transport, or the energy of detaching a molecule from its neighbours in the region of the binary mixture minus the energy given up in that region when one molecule fills a hole, and examined its accuracy by comparing theoretical results with available experimental data for linear chain hydrocarbon binary mixtures. The new model was based on phenomenological and kinetic approaches which have been found to be the most reliable. The paper discussed the net heat of transport for each component in the binary mixtures and presented the results of the investigation. The perturbed ...

2009-07-01

218

A Point Mutation in a Domain of Gamma Interferon Receptor 1 Provokes Severe Immunodeficiency  

UK PubMed Central (United Kingdom)

Gamma interferon (IFN-γ) and the cellular responses induced by it are essential for controlling mycobacterial infections. Most patients bearing an IFN-γ receptor ligand-binding chain...Full Text Available

2001-01-01

219

A Mitochondrial Superoxide Signal Triggers Increased Longevity in Caenorhabditis elegans  

UK PubMed Central (United Kingdom)

The nuo-6 and isp-1 genes of C. elegans encode, respectively, subunits of complex I and III of the mitochondrial respiratory chain. Partial loss-of-function...Full Text Available

2010-12-01

220

Value creation through relationship closeness  

British Library Electronic Table of Contents (United Kingdom)

Globalization and technological innovation are creating dynamic networks or chains of interconnected players, often known as value delivery networks or supply chains, in which a firm, whether manufacturing or service, holds the key to creating and delivering value in the form of offerings to the customers. This idea of value creation and exchange is the foundation stone of relationship marketing and it is considered successful when closeness is said to have been established in the relationship which subsequently leads toward the achievement of objectives. In order to study and understand the creation of value through relationship closeness in a value delivery network particularly at the backward end, a literature review is conducted. A framework is further developed with the help of Interp...

2010-01-01

221

The use of Radioactive labeling in hemoglobin identification  

International Nuclear Information System (INIS)

The basic approach to radioactive labeling techniques in hemoglobin identification consists of mixing 14C labeled normal carrier globin with 3H labeled unknown globin and carrying out the subsequent separations and purifications looking at the distribution of 3H and 14C radioactivity. This technique was devised to ascertain the amino acid substitution in Hb Indianapolis and was instrumental in solving the structure of Hb Vicksburg. It was also useful in determining the purity of gamma-chains from cultures of human and baboon erythroid progenitors. Another use of this technique would be in identifying aberrant peaks of radioactivity in chain separation chromatograms, such as ''pre-peaks''.

222

Separation of variables for the quantum SL(2,R) spin chain  

CERN Document Server

We construct representation of the Separated Variables (SoV) for the quantum SL(2,R) Heisenberg closed spin chain and obtain the integral representation for the eigenfunctions of the model. We calculate explicitly the Sklyanin measure defining the scalar product in the SoV representation and demonstrate that the language of Feynman diagrams is extremely useful in establishing various properties of the model. The kernel of the unitary transformation to the SoV representation is described by the same "pyramid diagram" as appeared before in the SoV representation for the SL(2,C) spin magnet. We argue that this kernel is given by the product of the Baxter Q-operators projected onto a special reference state.

2003-01-01

223

Role of corporate memory in the global supply chain environment  

British Library Electronic Table of Contents (United Kingdom)

Critical knowledge is proliferated among different knowledge owners of a corporate system through the individuals lying inside or outside the system. Extraction of such knowledge is a very crucial requirement for all organisations. This paper presents the role of critical knowledge in the proper functioning of a system by representing it in the form of eXtensible Markup Language to develop a corporate memory. In order to demonstrate the role of corporate memory in the organisation, a real-world problem of a global supply chain is considered. The problem utilises the concept of corporate memory for the selection of potential suppliers from a set of available suppliers, and further to select the best route from a set of available alternative routes. The objective deals with the minimisation ...

2009-01-01

224

Radius of gyration and intrinsic viscosity of polyelectrolyte solutions  

Energy Technology Data Exchange (ETDEWEB)

Relatively low molecular weights polyelectrolytes (10{sup 4}-10{sup 6}) behave as worm-like chain when electrostatic repulsions are assumed to govern the excluded volume parameter. Under such conditions, predictions of chain expansion and effect of polyelectrolyte concentrations are made assuming that unperturbed dimensions could be obtained at infinite salt content. Experimental studies of an ionic polysaccharide, namely the Na-hyaluronate, were done and the values obtained for the radius of gyration as well as the intrinsic viscosity at different charge densities are in good agreement with the predictions.

1993-12-31

225

Quenched large deviations for random walk in a random environment  

CERN Document Server

We take the point of view of a particle performing random walk with bounded jumps on Z^d in a stationary and ergodic random environment. We prove the quenched large deviation principle (LDP) for the pair empirical measure of the environment Markov chain. By the contraction principle, we deduce the quenched LDP for the mean velocity of the particle and obtain a variational formula for the corresponding rate function. We propose an Ansatz for the minimizer of this formula. We verify this Ansatz for nearest-neighbor walks on Z. As a separate result, we give a probabilistic formula for the ergodic invariant density of the environment Markov chain in the case of ballistic random walk with bounded jumps on Z.

2008-01-01

226

Quantitative variations in the vaginal bacterial population associated with asymptomatic infections: a real-time polymerase chain reaction study.  

Science.gov (United States)

The real-time polymerase chain reaction (PCR) quantification of several vaginal bacterial groups in healthy women and patients developing asymptomatic bacterial vaginosis (BV) and candidiasis (CA) was performed. Statistical analysis revealed that the BV condition is characterised by a great variability among subjects and that it is associated with a significant increase of Prevotella, Atopobium, Veillonella and Gardnerella vaginalis, and a drop in Lactobacillus. On the contrary, the vaginal microflora of healthy women and patients developing CA was found to be homogeneous and stable over time. PMID:18762999

2008-09-02

227

Quantitative variations in the vaginal bacterial population associated with asymptomatic infections: a real-time polymerase chain reaction study  

British Library Electronic Table of Contents (United Kingdom)

The real-time polymerase chain reaction (PCR) quantification of several vaginal bacterial groups in healthy women and patients developing asymptomatic bacterial vaginosis (BV) and candidiasis (CA) was performed. Statistical analysis revealed that the BV condition is characterised by a great variability among subjects and that it is associated with a significant increase of Prevotella, Atopobium, Veillonella and Gardnerella vaginalis, and a drop in Lactobacillus. On the contrary, the vaginal microflora of healthy women and patients developing CA was found to be homogeneous and stable over time.

2009-01-01

228

Integrated planning problem in supply chains with time-varying delivery  

British Library Electronic Table of Contents (United Kingdom)

We consider a serial supply chain consisting of a raw material supplier, a manufacturer, a distribution centre and a retailer in the presence of time-varying delivery between manufacturer facility and the retailer warehouse. Delivery time functions are developed based on practical data analysis and the cost models for both linear and non-linear delivery time functions are derived. Analytic solution for system with linear delivery times is derived and a search algorithm for system with non-linear delivery times is established. Finally, sensitivity analysis is made to help decision makers achieve a lower total cost in practice.

2011-01-01

229

Fuzzy performance measurement of a supply chain in manufacturing companies  

British Library Electronic Table of Contents (United Kingdom)

This paper is aimed to present a fuzzy decision making approach to deal with the performance measurement in supply chain systems. In the manufacturing environment, performance measurement is based on different quantitative and qualitative factors. Some of these factors may have a larger effect on the performance measure than others. Units of measure of the quantitative factors are different such as time, money, percentage, ratio, and counts. Thus, this paper presents a performance measurement approach based on fuzzy set theory and the pair-wise comparison of Analytical Hierarchy Process (AHP), which ensures the consistency of the designer's assignments of importance of one factor over another to find the weight of each of the manufacturing activity in the departmental organization. In the ...

2011-01-01

230

Site-specific semisynthetic variant of human hemoglobin  

International Nuclear Information System (INIS)

A single round of Edman degradation was employed to remove the NH_2-terminal valine from isolated #alpha# chains of human hemoglobin. Reconstitution of normal #beta# chains with truncated or substituted #alpha# chains was used to form truncated (des-Val"1-#alpha#1) and substituted ([[1-"1"3C]Gly"1]#alpha#1) tetrameric hemoglobin analogs. Structural homology of the analogs with untreated native hemoglobin was established by using several spectroscopic and physical methods. Functional studies indicate that the reconstituted tetrameric protein containing des-Val"1-#alpha# chains has a higher affinity for oxygen, is less influenced by chloride ions or 2,3-biphosphoglycerate, and shows lower cooperativity than native hemoglobin. These results confirm the key functional role of the #alpha#-chain NH_2 terminus in mediating cooperative oxygen binding across the dimer interface. The ...

231

Green nanotechnology in Nordic Construction: Eco-innovation strategies and Dynamics in Nordic Window Value Chains  

DEFF Research Database (Denmark)

This project analyzes Nordic trends in the development and industrial uptake of green nanotechno-logy in construction. The project applies an evolutionary economic perspective in analyzing the innovation dynamics and firm strategies in the window value chains in three Nordic countries, Denmark, Finland and Sweden. Hence the project investigates two pervasive parallel market trends: The emergence of the green market and the emergence of nanotechnology. The analysis investigates how a traditional economic sector such as the construction sector reacts to such major trends. Conclusions are multiple, but among the most important are: Eco-innovation has become the perhaps most important driver for innovation in the construction sector. Search into eco-innovative business opportunities is intense among all companies along the three analyzed Nordic window chains. While we generally find a low uptake of nanotechnology in the construction sector in the ...

2010-01-01

232

Cost and CO2-Emission Reduction of Biomass Cascading. Methodological Aspects and Case Study of SRF Poplar  

Energy Technology Data Exchange (ETDEWEB)

This study presents and applies a coherent methodological framework to compare biomass cascading chains, i.e. the subsequent use of biomass for materials, recycling and energy recovery, considering land use, CO2 emission reduction and economic performance. Example cascading chains of short rotation poplar wood are compared with each other on the basis of literature data. Results for these chains vary strongly, namely, from CO2 mitigation benefits of 200 euro/Mg CO2 to CO2 mitigation costs of 2200 euro/Mg CO2, and from net CO2 emission reductions per hectare of biomass production of 28 Mg CO2/(ha yr) to net CO2 emissions of 8 Mg CO2/(ha yr). Using a present-value approach to determine CO2 emissions and costs affects the performance of long-term cascading chains significantly, i.e. cost and CO2 emission reduction are decreased. In general, cascading has the potential to improve both CO2 emission reduction ...

2005-08-01

233

Breaking the Biological barriers to Cellulosic Ethanol: A Joint Research Agenda  

Energy Technology Data Exchange (ETDEWEB)

A robust fusion of the agricultural, industrial biotechnology, and energy industries can create a new strategic national capability for energy independence and climate protection. In his State of the Union Address (Bush 2006), President George W. Bush outlined the Advanced Energy Initiative, which seeks to reduce our national dependence on imported oil by accelerating the development of domestic, renewable alternatives to gasoline and diesel fuels. The president has set a national goal of developing cleaner, cheaper, and more reliable alternative energy sources to substantially replace oil imports in the coming years. Fuels derived from cellulosic biomass - the fibrous, woody, and generally inedible portions of plant matter - offer one such alternative to conventional energy sources that can dramatically impact national economic growth, national energy security, and environmental goals. Cellulosic biomass is an attractive energy feedstock because it is an abundant, domestic, renewable ...

2006-06-01

234

Waterlogging-induced increase in sugar mobilization, fermentation, and related gene expression in the roots of mung bean (Vigna radiata)  

British Library Electronic Table of Contents (United Kingdom)

Summary The objective of this study was to examine the role of root carbohydrate levels and metabolism in the waterlogging tolerance of contrasting mung bean genotypes. An experiment was conducted with two cultivated mung bean (Vigna radiata) genotypes viz., T44 (tolerant) and Pusa Baisakhi (PB) (susceptible), and a wild Vigna species Vigna luteola under pot-culture to study the physiological and molecular mechanism of waterlogging tolerance. Waterlogging resulted in decrease in relative water content (RWC), membrane stability index (MSI) in root and leaf tissues, and chlorophyll (Chl) content in leaves, while the Chl a/b ratio increased. Waterlogging-induced decline in RWC, MSI, Chl and increase in Chl a/b ratio was greater in PB than V. luteola and T44. Waterlogging caused decline in tot...

2009-01-01

235

Translocation of labelled sucrose: A student exercise  

Energy Technology Data Exchange (ETDEWEB)

Photosynthetic carbohydrates from the leaves are exported through the phloem to growing tips, roots, flowers and fruits. If sucrose labelled with {sup 14}C is applied to the leaves of bean plants, the pathway for sugar movement may be readily observed by autoradiography. Students apply the labelled sucrose during class time and return the next day to press their plants. During the next class, the pressed and dried plants are placed against X-ray film and left in the dark for four weeks. the film is then developed, examined for presence of label and compared to the pressed plants. Source to sink movement is clearly illustrated and information about the mechanism of phloem transport and loading is gained through experimental treatments, which include blocking the phloem pathway and inhibiting energy production.

1990-05-01

236

Pectinolytic yeast isolates for cold-active polygalacturonase production  

British Library Electronic Table of Contents (United Kingdom)

Pectin rich cold stored spoiled fruits, vegetables and cold soils were screened and different pectinolytic isolates were obtained by enrichment culturing and ruthenium red plate assay. Among the primary isolates 10-15% were yeast isolates. Six isolates with higher zones of pectin hydrolysis were selected and tested for polygalacturonase (PGU) production at room temperature (25 degrees C) and at 5 degrees C. One isolate identified as Saccharomyces sp. with highest polygalacturonase activity at 5 degrees C was used for enzyme production using raw fruit pectins as substrates. The isolate was identified by preliminary cultural, morphological and sugar fermentation tests. PGU production was high in raw pectin substrates like orange peel (21 U/ml), apple peel (20 U/ml ), mango peel (19 U/ml), ...

2011-01-01

237

Kundur [Benincasa hispida (Thunb.) Cogn.]: A potential source for valuable nutrients and functional foods  

British Library Electronic Table of Contents (United Kingdom)

Kundur [Benincasa hispida (Thunb.) Cogn.], a member of the family Cucurbitaceae, is one of the famous crops that are grown primarily for its fruits and usually recognized with its nutritional and medicinal properties especially in Asian countries. Kundur fruit has been valued as a nutritious vegetable as it provides a good source for natural sugars, amino acids, organic acids, mineral elements and vitamins. A number of medicinal properties such as anti-diarrheal, anti-obesity, anti-ulcer, and antioxidant and diuretic have been ascribed to this fruit of high economic value. As a rich source of functionally important bioactives and therapeutics such as triterpenes, phenolics, sterols, and glycosides, the fruit has been widely used for the treatment of epilepsy, ulcer, and other nervous disor...

2011-01-01

238

Influence of gamma-irradiation, growth retardants and coatings on the shelf life of winter guava fruits (Psidium guajava L.)  

British Library Electronic Table of Contents (United Kingdom)

Experiment was conducted to study the effect of gamma irradiation, growth retardants and coatings (coconut oil, mustard oil and liquid paraffin) on shelf life of winter guava fruits during storage. The results revealed that the superiority of coconut oil coating over other post harvest treatments. Physiological loss in weight (7.1%), marketable fruits retained over control (86.7%), total soluble solid (16.1%), ascorbic acid (195 mg/100 g pulp) and total sugar (10%) of fruit were positively influenced by coconut oil coating up to 12 days of storage. The treatment was found significantly effective in increasing the post harvest life of fruits for 12 days over control without adversely affecting the fruit quality. Coconut oil coating gave highest consumer acceptability while, maintaining suff...

2010-01-01

239

Enzymatic activity of the cellulolytic complex produced by Trichoderma reesei. Enzymatic hydrolysis of cellulose; Actividad enzimatica del complejo celulolitico producido por Trichoderma reesei. Hidrolisis enzimatica de la celulosa  

Energy Technology Data Exchange (ETDEWEB)

The enzymatic activity characterization of the cellulolytic complex obtained from Trichoderma reesei QM 9414 and the influence of the enzymatic hydrolysis conditions on the hydrolysis yield are studied. Pure cellulose and native or alkali pretreated biomass Onopordum nervosum have been used as substrates. The values of pH, temperature, substrate concentration and enzyme-substrate ratio for the optimum activity of that complex, evaluated as glucose and reducing sugars production, have been selected. Previous studies on enzymatic hydrolysis of 0. nervosum have shown a remarkable effect of the alkaline pretreatments on the final hydrolysis yield. (Author) 10 refs.

1986-07-01

240

Biological treatment of wine of distilleries  

International Nuclear Information System (INIS)

The potential of the yeast Candida tropicalis and Candida guillermondii was evaluated and an isolated partnership of microorganisms of waters of the Medellin River, conformed by two bacteria and one leavening, to degrade the content of organic matter present in wine produced by the factory of Licores and Alcoholes de Antioquia (FLA) in aerobic process with biomass production. For each one of the microorganisms in study this capacity of removal in units of chemical demand of oxygen was quantified (CDO); in addition, parameters were analyzed such as yield of the biomass in relation to the removed CDO and to total reducing sugars (TRS) consumed, time of fermentation and speed of growth different dilutions from wine. Also the possible inhibition was analyzed that the present phenolic compounds in this wine can cause in the biological process of degradation.

241

Biochemical monitoring of black raspberry (Rubus coreanus Miquel) fruits according to maturation stage by ^1H NMR using multiple solvent systems  

British Library Electronic Table of Contents (United Kingdom)

Nuclear magnetic resonance (NMR) techniques coupled with multivariate data analysis were used to conduct monitoring of biochemical changes of black raspberry fruits at different stages of maturation and under various extraction and NMR dissolution solvent conditions: extraction with 50% methanol and D"2O as an NMR dissolution solvent, extraction with 50% methanol and 50% methanol-d"4 as an NMR dissolution solvent, and extraction with 100% ethyl acetate and 100% methanol-d"4 as an NMR dissolution solvent. Partial least-squares discriminant analysis reliably distinguished black raspberry fruits according to the maturation stage, whereby the relative levels of various compounds such as amino acids, organic acids, sugars and phenolic compounds were compared using analysis of variance. Sucrose ...

2011-01-01

242

A study on the pretreatment of a sugarcane bagasse sample with dilute sulfuric acid  

British Library Electronic Table of Contents (United Kingdom)

Experiments based on a 23 central composite full factorial design were carried out in 200-ml stainless-steel containers to study the pretreatment, with dilute sulfuric acid, of a sugarcane bagasse sample obtained from a local sugar?alcohol mill. The independent variables selected for study were temperature, varied from 112.5?C to 157.5?C, residence time, varied from 5.0 to 35.0 min, and sulfuric acid concentration, varied from 0.0% to 3.0% (w/v). Bagasse loading of 15% (w/w) was used in all experiments. Statistical analysis of the experimental results showed that all three independent variables significantly influenced the response variables, namely the bagasse solubilization, efficiency of xylose recovery in the hemicellulosic hydrolysate, efficiency of cellulose enzymatic saccharificatio...

2011-01-01

243

Translocation of /sup 14/C-sucrose from mesophyll to vein and stem bark in mulberry plant  

Energy Technology Data Exchange (ETDEWEB)

One-year-old seedlings of mulberry, the variety of Shinichinose, were used to fix /sup 14/CO/sub 2/ for 10 minutes under light of 18,000 lux at 28 deg C. Photosynthesis was continued after that in the air not containing /sup 14/CO/sub 2/. The specimens were collected immediately after and 10 and 30 minutes after the /sup 14/CO/sub 2/ fixation, divided into mesophyll, vein and stem bark, frozen in liquid N/sub 2/, and the contents of sucrose, glucose and fructose and their radioactivity were measured. The ratio of the radioactivity incorporated into sucrose to the total radioactivity incorporated into each tissue was very large, and the incorporation into glucose or fructose was very little. The content of sucrose was also larger than that of the other sugars in all the tissues. These findings showed that the photosynthates were translocated mainly in the form of sucrose. The ratio of specific radioactivity (dpm/mg sugar) in the mesophyll to ...

1982-12-01

244

Effective atomic numbers and electron densities of some biologically important compounds containing H, C, N and O in the energy range 145-1330 keV  

International Nuclear Information System (INIS)

A semi-empirical relation which can be used to determine the total attenuation cross sections of samples containing H, C, N and O in the energy range 145-1332 keV has been derived based on the total attenuation cross sections of several sugars, amino acids and fatty acids. The cross sections have been measured by performing transmission experiments in a narrow beam good geometry set-up by employing a high-resolution hyperpure germanium detector at seven energies of biological importance such as 145.4 keV, 279.2 keV, 514 keV, 661.6 keV, 1115.5 keV, 1173.2 keV and 1332.1 keV. The semi-empirical relation can reproduce the experimental values within 1-2%. The total attenuation cross sections of five elements carbon, aluminium, titanium, copper and zirconium measured in the same experimental set-up at the energies mentioned above have been used in a new matrix method to evaluate the effective atomic numbers and the effective electron densities of samples such as ...

2006-09-28

245

Effect of some physical treatments on anti nutritional factors and fatty acids composition of Vicia faba L. seeds  

International Nuclear Information System (INIS)

This study was carried out to evaluate the effects of irradiation (gamma irradiation at dose levels of 0.0, 2.5, 5.0, 10.0 or 20.0 kGy, He-Ne and their combination) on nutritive characteristics of Vicia faba L. seeds (Giza 843). Analyses included levels of anti-nutrients (total phenolic compounds, tannins, phytic acid, trypsin inhibitor and vicine), chemical composition (sugars, crude proteins, fat, dry matter and ash) and fatty acids profile. All treatments caused significant (P<0.05) decreases in the antinutrational factors under investigation. The reduction in the content of tannins and phenolic compounds were more pronounced with He-Ne alone or He-Ne in combination with gamma irradiation. At dose levels 10.0 and 20.0 kGy without or with combination of He-Ne were more efficiency in the reduction of phytic acid content by 24.3, 32.8, 34.5 and 45.5 %, respectively. Also, for trypsin inhibitor activity, the maximum inhibition was observed with the treatment of ...

246

(/sup 14/C)sucrose uptake and labeling of starch in developing grains of normal segl barley  

Energy Technology Data Exchange (ETDEWEB)

Previous work showed that the segl mutant of barley (Hordeum vulgare o Betzes) did not differ from normal Betzes in plant growth, photosynthesis, or fertility, but it produced only shrunken seeds regardless of pollen source. To determine whether defects in sucrose uptake or starch synthesis resulted in the shrunken condition, developing grains of Betzes and segl were cultured in (/sup 14/C)sucrose solutions after slicing transversely to expose the endosperm cavity and free space. In both young grains (before genotypes differed in dry weight) and older grains (17 days after anthesis, when segl grains were smaller than Betzes), sucrose uptake and starch synthesis were similar in both genotypes on a dry weight basis. To determine if sucrose was hydrolyzed during uptake, spikes of Betzes and segl were allowed to take up (fructose-U-/sup 14/C)sucrose 14 days after anthesis and the radioactivity of endosperm sugars was examined during 3 hours of incubation. Whereas less ...

1984-01-01

247

Tertiary structure prediction of C-peptide of ribonuclease A by multicanonical algorithm  

CERN Document Server

We have performed multicanonical Monte Carlo simulations of C-peptide of ribonuclease A. It is known by CD and NMR experiments that this peptide has high alpha-helix content in aqueous solution and that the side-chain charges of residues Glu-2$^-$ and His-12$^+$ play an important role in the stability of the alpha-helix. In order to confirm these experimental implications, we have used two analogues of the peptide with charged and neutral side chains of Glu-2 and His-12. Two dielectric functions, distance-dependent and constant, are considered to study the effects of solvent contributions. All the simulations were started from random initial conformations. Various thermodynamic quantities such as average helicity as a function of residue number and average distance between two side chains as a function of temperature are calculated. The results are found to be in accord with the implications of CD and NMR experiments. The ...

1998-01-01

248

On nonlinear Markov chain Monte Carlo  

CERN Document Server

Let $\\mathscr{P}(E)$ be the space of probability measures on a measurable space $(E,\\mathcal{E})$. In this paper we introduce a class of nonlinear Markov chain Monte Carlo (MCMC) methods for simulating from a probability measure $\\pi\\in\\mathscr{P}(E)$. Nonlinear Markov kernels (see [Feynman--Kac Formulae: Genealogical and Interacting Particle Systems with Applications (2004) Springer]) $K:\\mathscr{P}(E)\\times E\\rightarrow\\mathscr{P}(E)$ can be constructed to, in some sense, improve over MCMC methods. However, such nonlinear kernels cannot be simulated exactly, so approximations of the nonlinear kernels are constructed using auxiliary or potentially self-interacting chains. Several nonlinear kernels are presented and it is demonstrated that, under some conditions, the associated approximations exhibit a strong law of large numbers; our proof technique is via the Poisson equation and Foster--Lyapunov conditions. We investigate the ...

2011-01-01

249

Novel platinum(II) complexes of long chain aliphatic diamine ligands with oxalato as the leaving group: Comparative cytotoxic activity relative to chloride precursors  

Energy Technology Data Exchange (ETDEWEB)

Platinum complexes play an important role in the development of anticancer drugs. Their cytotoxicity can be influenced by the nature of the leaving ligands, due to the hydrolysis reaction that occurs prior to the binding of the platinum complex to DNA. Also, non-leaving groups such as lipophilic diamines may affect cellular uptake. In this work, we describe the synthesis of platinum(II) complexes having oxalato and long chain aliphatic N-alkyl ethylenediamines as ligands. The products were characterized by elemental analyses, infrared spectroscopy and {sup 1}H, {sup 13}C and {sup 195}Pt NMR spectroscopy. Biological activity was assessed against tumor cell lines (A{sub 549}, B16-F1, B16-F10, MDA-MB-231) and non-tumor cell lines (BHK-21 and CHO). The length of the carbon chain affects the cytotoxicity and the oxalato complexes were less cytotoxic than the respective chloride-containing analogues. (author)

2010-07-01

250

Mechanism of ageing in irradiated polymers  

Energy Technology Data Exchange (ETDEWEB)

Samples of ultra-high molecular weight polyethylene (UHMWPE) and nylon 66, of grades suitable for use in medical prostheses, were subjected to irradiation using a /sup 60/Co source. The effects of a 10 Mrad dose on percentage crystallinity, tensile behaviour and dynamic mechanical response were established 3 days after irradiation at intervals over a one year period. Crystallinity in UHMWPE was found to increase progressively during this period with consequent changes in mechanical behaviour. It is proposed that the observed ageing process arises from the breakdown of metastable groups in the polymer, which are formed on irradiation, with consequent release of long inter-lamella tie chains. This removes an inhibition to crystal perfection processes, which can occur at room temperature in polyethylene. Infra-red spectroscopic evidence supports the proposal that the metastable species is peroxy or hydroperoxy and that this decomposes on ageing to a carbonyl group, ...

1988-01-01

251

Linear chain tensioning of moored production vessels  

Energy Technology Data Exchange (ETDEWEB)

As need for development of marginal and deepwater oil fields grows, demand increases for floating production vessels (FPVs) such as floating production, storage and offloading (FPSO) units; spread-moored production semi-submersibles; and turret-moored production vessels. The FPV may be purpose-built; or an existing vessel such as an exploration drilling semi-sub or ship-shape vessel may be modified to suit the purpose. In either case, requirements for tensioning systems for the mooring lines on the FPV are quite unique, and are not without the potential for problems when traditional chain windlasses or wire rope systems are employed. This two-part article discusses the range of available technologies and systems for tensioning mooring lines on FPVs. It examines problems of size, weight and safety associated with some available designs; and it considers in detail a specific family of new units. Part 1, presented here, discusses the FPV market, worldwide potential ...

1993-04-01

252

Improving the decontamination of ruthenium with short chain hydroxamic ACTD as complexing agent  

International Nuclear Information System (INIS)

The ruthenium decontamination factor in Purex process falls quickly with recycles of TBP. So it is necessary to change the chemical states of RuNO complexes in order to improve DF_R_u in the uranium purification cycle. The retention of RuNO complexes in TBP-kerosenelaurohydroxamic acid is observed to be quite large in our previous work. Therefore, water-soluble short chain hydroxamic acid is used as complexing agent to decrease the distribution coefficient of Ru. Hydroxamic acid can transform RuNO complexes into in-extractable species by TBP-kerosene in certain conditions. The result of cascade experiment indicates that the ruthenium decontamination can be increased by a factor of 40-50. Acidity has more influence on the effect of pretreatment. The higher acidity is, the worse the effect will be. The pretreatment is first carried out in low acidic solution, then extractive acidity is increased. In this way, the distribution of Ru can be decreased obviously. After ...

253

Continuous and Discrete (Classical) Heisenberg Spin Chain revised  

CERN Document Server

The Hamiltonian structure of the Classical Heisenberg Spin Chain (CHSC) has been extensively studied by a number of authors. First of all, we mention Faddeev and Thaktadjan that, in their fundamental monograph "Hamiltonian Methods in the Theory of Soliton", elucidate the main properties of both continuous and (semi-)discrete models. An analysis of the su(2) continuous model in the context of the reduction theory for Poisson Nijenhuis manifolds was performed by Magri et al in1985, while through a similar approach a few years later Ragnisco and Santini analyzed the discrete case. In the meantime, among the condensed matter community there was some renewed interest on Potts models, sort of generalized spin chains where the relevant field variable is allowed to take values at the $N^{th}$ roots of unity. The proper theoretical setting for such models, at least at the classical level, would have been the extension to NxN matrices of the approach ...

2006-01-01

254

A non-linear approach to the structure-mobility relationship in protein main chains  

Energy Technology Data Exchange (ETDEWEB)

A correlation investigation was carried out on the series of atomic coordinates (MPV) and temperature factor (T {sub f}), respectively for human hemoglobin and HIV-1 protease protein main chains. The MPV series revealed resemblances to the corresponding T {sub f} series. Each minor or major peak in a series had a corresponding peak in the related series. This brings a qualitative evidence for the connection of the two parameters. The series were further subjected to spectral and detrended fluctuation analysis which all revealed long-range correlation properties. This combined analysis revealed that the data were controlled both by the correlation of stationary fluctuation and trends or non-stationary contribution to correlation. The correlation of all MPV series was found to be much less sensitive to ligand binding than the corresponding T {sub f} series. Thus the long-range correlation properties of the protein main chain structure and ...

2007-05-15

255

A non-linear approach to the structure-mobility relationship in protein main chains  

International Nuclear Information System (INIS)

A correlation investigation was carried out on the series of atomic coordinates (MPV) and temperature factor (T _f), respectively for human hemoglobin and HIV-1 protease protein main chains. The MPV series revealed resemblances to the corresponding T _f series. Each minor or major peak in a series had a corresponding peak in the related series. This brings a qualitative evidence for the connection of the two parameters. The series were further subjected to spectral and detrended fluctuation analysis which all revealed long-range correlation properties. This combined analysis revealed that the data were controlled both by the correlation of stationary fluctuation and trends or non-stationary contribution to correlation. The correlation of all MPV series was found to be much less sensitive to ligand binding than the corresponding T _f series. Thus the long-range correlation properties of the protein main chain structure and mobility revealed two ...

2007-05-01

256

A CD33-specific single-chain immunotoxin mediates potent apoptosis of cultured human myeloid leukaemia cells.  

Science.gov (United States)

A novel single-chain immunotoxin was constructed by combining a CD33-specific single chain Fv (scFv) antibody fragment with an engineered variant of Pseudomonas exotoxin A (ETA). The variant toxin carries the KDEL peptide at its C-terminus, a cellular peptide mediating improved retrograde transport to the endoplasmic reticulum. The purified recombinant fusion protein induced potent apoptosis of the human myeloid cell lines U937, HL-60 and THP-1. Up to 98% of U937 cells were eliminated after treatment for 72 h with a single dose of 500 ng/ml (c. 7 nmol/l). Killing was antigen-specific and occurred by apoptosis. A control protein, consisting of a CD19-specific scFv antibody fragment fused to the ETA-KDEL toxin, failed to induce death of the CD19-negative cell lines U937, HL-60 and THP-1. The CD33-ETA toxin also mediated apoptosis of fresh patient-derived acute myeloid leukaemia cells from bone marrow and peripheral blood. The pronounced ...

2006-04-01

257

Variational method for estimating the rate of convergence of Markov Chain Monte Carlo algorithms  

CERN Document Server

We demonstrate the use of a variational method to determine a quantitative lower bound on the rate of convergence of Markov Chain Monte Carlo (MCMC) algorithms as a function of the target density and proposal density. The bound relies on approximating the second largest eigenvalue in the spectrum of the MCMC operator using a variational principle and the approach is applicable to problems with continuous state spaces. We apply the method to one dimensional examples with Gaussian and quartic target densities, and we contrast the performance of the basic Metropolis-Hastings algorithms with a ``smart'' variant that incorporates gradient information into the trial moves. We find that the variational method agrees quite closely with numerical simulations. We also see that the smart MCMC algorithm often fails to converge geometrically in the tails of the target density except in the simplest case we examine, and even then care must be taken to choose the appropriate ...

2006-01-01

258

The role of RFID in agriculture: Applications, limitations and challenges  

British Library Electronic Table of Contents (United Kingdom)

The recent advances in RFID offer vast opportunities for research, development and innovation in agriculture. The aim of this paper is to give readers a comprehensive view of current applications and new possibilities, but also explain the limitations and challenges of this technology. RFID has been used for years in animal identification and tracking, being a common practice in many farms. Also it has been used in the food chain for traceability control. The implementation of sensors in tags, make possible to monitor the cold chain of perishable food products and the development of new applications in fields like environmental monitoring, irrigation, specialty crops and farm machinery. However, it is not all advantages. There are also challenges and limitations that should be faced in the...

2011-01-01

259

Superheavy elements with the Berkeley gas-filled separator  

Energy Technology Data Exchange (ETDEWEB)

In April and May of 1999 the Berkeley Gas-filled Separator was used to search for the production and decay of element 118 from the {sup 86}Kr + {sup 208}Pb reaction, according to Smolanczuk's predictions of relatively large production rates. Three decay chains, each consisting of an implanted heavy ion, followed by a rapid (ms) succession of high-energy (>10 MeV) alpha-particle decays were detected. These chains are consistent with the production and decay of element 118 with mass number 293. These results a) show experimental evidence for the existence of shell-stabilized superheavy elements, b) provide experimental values for refinement of nuclear mass models in the superheavy element region, and, most importantly, c) present a new' reaction pathway for the production of superheavy elements. (author)

2000-03-01

260

Sodium monocarboxylates as inhibitors of AZ31 alloy corrosion in a synthetic cooling water  

Energy Technology Data Exchange (ETDEWEB)

This research investigated the inhibiting effects that sodium salts of linear monocarboxylic acids displayed towards the corrosion process of AZ31 Mg alloy in ASTM D 1387 saline solution (a synthetic industrial cooling water). The length of the aliphatic chain of the acids ranged between 7 and 15 carbon atoms. The inhibiting action of these salts can be related to the precipitation of an insoluble magnesium salt, which mainly affected the anodic reaction. The aliphatic chain length controlled the anion solubility and the reaction rate of magnesium carboxylate formation. For all the salts, an optimum concentration was experienced: 10{sup -2} M for sodium decanoate (caprate), 10{sup -3} M for sodium dodecanoate (laurate), 10{sup -4} M for sodium tetradecanoate (myristate); when this concentration was exceeded, a diminution (even a disappearance) in the inhibiting action was found. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

2009-03-15

261

Security of mobile agents: a new concept of the integrity protection  

CERN Document Server

The recent developments in the mobile technology (mobile phones, middleware) created a need for new methods of protecting the code transmitted through the network. The proposed mechanisms not only secure the compiled program, but also the data, that can be gathered during its "journey". The oldest and the simplest methods are more concentrated on integrity of the code itself and on the detection of unauthorized manipulation. Other, more advanced proposals protect not only the code but also the execution state and the collected data. The paper is divided into two parts. The first one is mostly devoted to different methods of securing the code and protecting its integrity; starting from watermarking and fingerprinting, up to methods designed specially for mobile agent systems: encrypted function, cryptographic traces, time limited black-box security, chained-MAC protocol, publicly-verifiable chained digital signatures The second part presents new ...

2005-01-01

262

SAXS studies on added-salt species dependence of conformation of fully-charged poly(L-glutamate) in aqueous solutions  

Energy Technology Data Exchange (ETDEWEB)

The effect of counter-ion species on the local conformation of fully-charged poly(L-glutamate) in added-salt aqueous solutions were studied by small-angle X-ray scattering(SAXS). In the case of presence of monovalent counter-ion, the scattering behaviour could be explained by taking into consideration the excluded volume effect and intermolecular-interface interaction on the scattering function of wormlike chain. On the other hand, since SAXS profile of the solution in the presence of divalent counter-ion well fitted to the scattering function of dendrimer, it suggested that the conformation of polymer chain in such solution would be more compact conformation than that of presence of monovalent ion.

2010-10-01

263

Phylogeography of rabies virus isolated from dogs in Brazil between 1985 and 2006  

British Library Electronic Table of Contents (United Kingdom)

To establish the phylogeographic relationships in rabies viruses in Brazil, we studied a dataset retrieved from GenBank consisting of 71 genetic sequences from the coding region of the N gene of rabies viruses isolated in dogs over a period of 22?years. The Bayesian Markov chain Monte Carlo method available in the BEAST package was used with the GTR+G+?4 evolutionary model in conjunction with the relaxed uncorrelated lognormal molecular clock model and an exponential growth tree prior. A discrete phylogeographic diffusion model was also analyzed using a standard continuous-time Markov chain viewed with Google Earth to provide a spatial projection of the diffusion of genetic lineages based on their phylogeographic relationships. The topology of the time and substitution phylogenetic trees a...

2011-01-01

264

Oilseed crop with promise  

Energy Technology Data Exchange (ETDEWEB)

Cuphea, a relatively unknown plant outside the scientific community, might someday provide valuable oils for manufacturing soaps, detergents, surfactants, and lubricants, and may have medical, nutritional and dietetic applications as well. Unique properties of oils found in its seed make cuphea a potentially valuable new crop for the USA. Its seeds contain large quantities of medium-chain fatty acids such as lauric acid, which is used in manufacturing soaps and detergents. Other medium-chain fatty acids in cuphea can be used for clinical treatment of rare human ailments associated with fat absorption. New uses for the fatty acids in the seed may be developed and economic conditions may change, making the crop more or less valuable.

1986-02-01

265

Mitochondrial DNA background modulates the assembly kinetics of OXPHOS complexes in a cellular model of mitochondrial disease  

British Library Electronic Table of Contents (United Kingdom)

Lebers hereditary optic neuropathy (LHON), the most frequent mitochondrial disorder, is mostly due to three mitochondrial DNA (mtDNA) mutations in respiratory chain complex I subunit genes: 3460/ND1, 11778/ND4 and 14484/ND6. Despite considerable clinical evidences, a genetic modifying role of the mtDNA haplogroup background in the clinical expression of LHON remains experimentally unproven. We investigated the effect of mtDNA haplogroups on the assembly of oxidative phosphorylation (OXPHOS) complexes in transmitochondrial hybrids (cybrids) harboring the three common LHON mutations. The steady-state levels of respiratory chain complexes appeared normal in mutant cybrids. However, an accumulation of low molecular weight subcomplexes suggested a complex I assembly/stability defect, which was ...

2008-01-01

266

Intramolecular Form Factor in Dense Polymer Systems: Systematic Deviations from the Debye formula  

CERN Document Server

We discuss theoretically and numerically the intramolecular form factor $F(q)$ in dense polymer systems. Following Flory's ideality hypothesis, chains in the melt adopt Gaussian configurations and their form factor is supposed to be given by Debye's formula. At striking variance to this, we obtain noticeable (up to 20%) non-monotonic deviations which can be traced back to the incompressibility of dense polymer solutions beyond a local scale. The Kratky plot ($q^2F(q)$ {\\it vs.} wavevector $q$) does not exhibit the plateau expected for Gaussian chains in the intermediate $q$-range. One rather finds a significant decrease according to the correction $\\delta(F^{-1}(q)) = q^3/32\\rho$ that only depends on the concentration $\\rho$ of the solution, but neither on the persistence length or the interaction strength.

2007-01-01

267

Improvements on burnup chain model and group cross section library in the SRAC system  

Energy Technology Data Exchange (ETDEWEB)

Data and functions of the cell burnup calculation of the SRAC system were revised to improve mainly the accuracy of the burnup calculation of high conversion light water reactors (HCLWRs). New burnup chain models were developed in order to treat fission products (FPs) and actinide nuclides in detail. Group cross section library, SRACLIB-JENDL2, was generated based on JENDL-2 nuclear data file. In generating this library, emphasis was placed on FPs and actinides. Also revised were the data such as the average energy release per fission for various actinides. These improved data were verified by performing the burnup analysis of PWR spent fuels. Some new functions were added to the SRAC system for the convenience to yield macroscopic cross sections used in the core burnup process. (author).

1992-01-01

268

Identification of pork derivatives in food products by species-specific polymerase chain reaction (PCR) for halal verification  

British Library Electronic Table of Contents (United Kingdom)

Pork identification in four types of food products, which are sausages and the casings, bread and biscuits, using species-specific polymerase chain reaction (PCR) detection of a conserved region in the mitochondrial (mt) 12S ribosomal RNA (rRNA) gene was developed. Genomic DNA of the food products were successfully extracted except for the casing samples, where no genomic DNA was detected. The extracted genomic DNA was then subjected to PCR amplification targeting the specific regions of the 12S rRNA gene. The genomic DNA from the food products were found to be of good quality and produced clear PCR products on the amplification of 12S rRNA gene of 387 base pairs (bp) from pork species. The species-specific PCR identification yielded excellent results for identification of pork derivatives...

2007-01-01

269

Identification and characterization of retinoid-active short-chain dehydrogenases/reductases in Drosophila melanogaster  

British Library Electronic Table of Contents (United Kingdom)

Background In chordates, retinoid metabolism is an important target of short-chain dehydrogenases/reductases (SDRs). It is not known whether SDRs play a role in retinoid metabolism of protostomes, such as Drosophila melanogaster. Methods Drosophila genome was searched for genes encoding proteins with ?50% identity to human retinol dehydrogenase 12 (RDH12). The corresponding proteins were expressed in Sf9 cells and biochemically characterized. Their phylogenetic relationships were analyzed using PHYLIP software. Results A total of six Drosophila SDR genes were identified. Five of these genes are clustered on chromosome 2 and one is located on chromosome X. The deduced proteins are 300 to 406 amino acids long and are associated with microsomal membranes. They recognize all-trans-retinaldehyd...

2009-01-01

270

Greenhouse gas emission inventory based on full energy chain analysis  

International Nuclear Information System (INIS)

Methodology, characteristics, features and results obtained for greenhouse gases within the recent Swiss LCA study 'Environmental Life-Cycle Inventories of Energy Systems' are presented. The focus of the study is on existing average Full Energy Chains (FENCHs) in the electricity generation mixes in Europe and in Switzerland. The systems, including coal (hard coal and lignite), oil, natural gas, nuclear and hydro, are discussed one by one as well as part of the electricity mixes. Photovoltaic systems are covered separately since they are not included in the electricity mixes. A sensitivity analysis on methane leakage during long-range transport via pipeline is shown. Whilst within the current study emissions are not attributed to specific countries, the main sectors contributing to the total GHGs emissions calculated for the various FENCHs are specified. (author). 10 refs, 10 figs, 9 tabs.

1996-07-01

271

Fragile granular jamming  

Energy Technology Data Exchange (ETDEWEB)

We demonstrate experimentally that the route to a jammed state for a set of bi-dispersed frictional disks, subjected to uni-axial compression from a random initial unjammed state, consists of a consolidation state, a fragile jammed state, and finally a rigid jammed state. In the consolidation regime, the pressure on the sides increases very slowly with the packing fraction {phi} and there are no detectable stress chains. In the fragile jammed state, stress chains are visible, the pressure increases exponentially with {phi}, and the fraction of moving disks drops exponentially. Eventually, a final regime where particle displacements are below our resolution and the pressure varies approximately linearly with {phi} is reached. We argue that this scenario is generic for ather mal frictional compressed particles.

2009-01-01

272

Embodied energy and emergy evaluation of a typical biodiesel production chain in China  

British Library Electronic Table of Contents (United Kingdom)

Biodiesel from non-grain feedstock has been considered as one of the proper substitutes for fossil fuels associated with a series of activities emerging in China in order to meet the resource shortage and develop the energy crops. This paper presents an ecological accounting framework based on embodied energy, emergy, and CO2 emission for the whole production chain of biodiesel made from Jatropha curcas L. (JCL) oil. The energy and materials invested in and CO2 emission from the whole process, including cropping, transportation, extraction, and production, are accounted and calculated. Also, EmCO2, the ratio of real CO2 released to the emergy-based sustainability indicator per joule biodiesel, is proposed in this paper to present a new goal function for low-carbon system optimization. Fina...

2011-01-01

273

Chain radiation-chemical cross-linking of polyethylene under high pressures. [Gamma radiation  

Energy Technology Data Exchange (ETDEWEB)

Regularities in the radiation cross-linking of low-density polyethylene under various conditions of ..gamma..-irradiation were studied. It is shown that at the 0.5 GPa pressure and 450 K the gel formation is initiated at doses of about 1 kGy, i.e. at doses 10 times as low as compared to normal conditions. Abnormally high rate of radiation cross-linking at high temperature and high pressure is an evidence of changes in the mechanism of polyethylene, radiation cross-linking, i.e. of the process transition from nonchain to chain conditions. Decrease in the potential barriers of macroradical reactions with macromolecules is the most probable reason of change in the polymer cross-linking nature.

1984-01-01

274

Bifurcation and chaos of a pest-control food chain model with impulsive effects  

Energy Technology Data Exchange (ETDEWEB)

According to biological and chemical control strategy for pest control, we investigate the dynamics of a predator-prey food chain with impulsive effect, periodic releasing natural enemies and spraying pesticide at different fixed times, by using impulsive differential equation. Choose pest birth rate r{sub 2} as control parameter, we show that there exists a stable pest-eradication periodic solution when r{sub 2} is less than some critical value r{sub 2}* and the system is permanence when r{sub 2} is larger than the critical value r{sub 2}*. By use of standard techniques of bifurcation theory, we prove that above this threshold there are periodic oscillations in prey, middle-predator and top predator. Furthermore, bifurcation diagrams have shown that there exists complexity for the pulsed system including periodic doubling cascade.

2009-02-28

275

Bacteriophage P22 capsid size determination: Roles for the coat protein telokin-like domain and the scaffolding protein amino-terminus  

British Library Electronic Table of Contents (United Kingdom)

Assembly of icosahedral capsids of proper size and symmetry is not understood. Residue F170 in bacteriophage P22 coat protein is critical for conformational switching during assembly. Substitutions at this site cause assembly of tubes of hexamerically arranged coat protein. Intragenic suppressors of the ts phenotype of F170A and F170K coat protein mutants were isolated. Suppressors were repeatedly found in the coat protein telokin-like domain at position 285, which caused coat protein to assemble into petite procapsids and capsids. Petite capsid assembly strongly correlated to the side chain volume of the substituted amino acid. We hypothesize that larger side chains at position 285 torque the telokin-like domain, changing flexibility of the subunit and intercapsomer contacts. Thus, a sing...

2011-01-01

276

X-point model for magnetic susceptibility of A-15 compounds  

Science.gov (United States)

The X-point linear chain model for electronic structure of A-15 compounds is shown to lead to a weakly temperature dependent magnetic susceptibility ?(T) = 3micro2?N(0) tanh (?~ / T) is serious disagreement with experiment. Supported in part by NSF-DMR76-20641; AROD-DAHCO4-75-G-0052; and FRAP-CUNY 11453.

1977-11-01

277

Uranium phosphates  

International Nuclear Information System (INIS)

Methods of preparation, stability in solutions and in the solid phase, composition of orthophosphate crystallohydrates and condensed uranyl- and uranium (4) phosphates, are considered. Structures of these compounds are discussed; it is shown that they are steric polymers with an uranylphosphate framework. The problem of phosphate-anion polymerization in the process of thermal decomposition is discussed. It is established that condensed uranyl polyphosphates are not stable during storage, capable of degradation, its degree increasing with the phosphate chain length and uranium content.

279

Structure of a mycobacterial polysaccharide-fatty acyl-CoA complex: nuclear magnetic resonance studies.  

UK PubMed Central (United Kingdom)

MMP, a linear alpha 1 leads to 4 linked polymer of 3-O-methylmannose, regulates the fatty acid synthetase from Mycobacterium smegmatis by forming stoichiometric complexes with the long-chain acyl-CoA...Full Text Available

1980-05-01

280

Single-mode 30 MW CO/sub 2/ laser system for 16. mu. m Raman scattering in parahydrogen  

Energy Technology Data Exchange (ETDEWEB)

A CO/sub 2/ laser chain able to supply approx.=30 MW on a single mode TEM/sub 00/ is described. The coupling of a modified Lumonics 101 module with a low-pressure cell constitues the oscillator and two further Lumonics 103 stages two amplifiers. The final pulse achieves the energy of 4.0 J with 90% of this energy in a peak of 100 ns FWHM.

1983-01-11

281

Side chain SAR of bicyclic [beta]-lactamase inhibitors (BLIs). 1. Discovery of a class C BLI for combination with imipinem  

Energy Technology Data Exchange (ETDEWEB)

Bridged monobactam {beta}-lactamase inhibitors were prepared and evaluated as potential partners for combination with imipenem to overcome class C {beta}-lactamase mediated resistance. The (S)-azepine analog 2 was found to be effective in both in vitro and in vivo assays and was selected for preclinical development.

2010-09-17

282

Rotational modes of oscillation of rodlike dust grains in a plasma  

CERN Document Server

Three dimensional rotatory modes of oscillations in a one-dimensional chain of rodlike charged particles or dust grains in a plasma are investigated. The dispersion characteristics of the modes are analyzed. The stability of different equilibrium orientations of the rods, phase transitions between the different equilibria, and a critical dependence on the relative strength of the confining potential are analyzed. The relations of these processes with liquid crystals, nanotubing, and plasma coating are discussed.

2003-01-01

283

Rayleigh scattering of Moessbauer radiation in hyaluronate oriented fibres  

Energy Technology Data Exchange (ETDEWEB)

The Rayleigh scattering of Moessbauer radiation has been measured on highly oriented fibres of Na-hyaluronate at different hydration levels. The elastic- and-inelastic-scattering intensities, measured as a function of the scattering vector Q, have provided information on the dynamic structuring of the water molecules to the polysaccharidic chains.

1996-02-01

284

Platelet receptor recognition domain on the. gamma. chain of human fibrinogen and its synthetic peptide analogues  

Energy Technology Data Exchange (ETDEWEB)

The authors have shown previously that the domain recognizing receptors on activated human platelets is located on the human fibrinogen {gamma} chain between residues 400 and 411. To study the correlation between the structure of this segment of the {gamma} chain and its reactivity toward receptors on ADP-activated human platelets, they designed a series of analogues containing replacements at 9 out of 12 positions. A double substitution of the normal His{sup 400}-His{sup 401} sequence by Ala-Ala reduced the inhibitory potency of the dodecapeptide 3-fold. When Lys{sup 406} was replaced by Arg, the inhibitory potency of the dodecapeptide decreased 15 times. On the other hand, substitution of Ala{sup 408} with Arg increased the inhibitory potency of the dodecapeptide 6-fold. A drastic decrease in the reactivity of the dodecapeptide toward platelet receptors was observed when Val{sup 411} was replaced by leucine or cysteine or tyrosine. A 3-fold ...

1989-04-04

285

On a new model for deep inelastic lepton-nuclei scatterings. I  

International Nuclear Information System (INIS)

An approach to high energy nuclear reactions (relativistic nuclear physics) is developed on the basis of the quark-parton-flucton concept. The main assumptions underlying the known parton chain model are briefly reformulated, modified and generalized to the flucton case. This new model is used to investigate electron-nuclei and muon-nuclei inclusive reactions within the framework of quantum electrodynamics. The theoretical results are fitted well with existing data. (Auth.).

286

Morphology-controlled synthesis and novel microwave electromagnetic properties of hollow urchin-like chain Fe-doped MnO2 under 10 T high magnetic field  

International Nuclear Information System (INIS)

Fe-doped MnO2 with a hollow sea urchin-like ball chain shape was first synthesized under a high magnetic field of 10 T. The formation mechanism was investigated and discussed in detail. The synthesized samples were characterized by XRD, SEM, TEM, EMPA, and vector network analysis. By doping MnO2 with Fe, the relative complex permittivity of MnO2 and its corresponding loss tangent clearly decreases, but its relative complex permeability and its corresponding loss tangent markedly increases. Moreover, the theoretically calculated values of reflection loss show that with increasing the Fe content, the as-prepared Fe-doped MnO2 exhibits good microwave absorption capability. -- Graphical Abstract: Fe-doped MnO2 with a hollow sea urchin-like ball chain shape was first synthesized in a high magnetic field of 10 T via a simple chemical process. Display Omitted Highlights: ? Fe-doped MnO2 with a hollow sea urchin-like ball chain ...

2011-05-01

287

Molecular methods  

Energy Technology Data Exchange (ETDEWEB)

Chapter 5, describes some of the most important molecular methods used in the study of chromosome structure and function. The methods discussed include fragmentation of DNA, cloning, flow cytometry and chromosome sorting, is situ hybridization, polymerase chain reaction (PCR), and yeast artificial chromosomes (YACs). 18 refs., 3 figs., 1 tab.

1993-12-31

288

Moderate deviations for stationary sequences of Hilbert valued bounded random variables  

CERN Document Server

In this paper, we derive the moderate deviation principle for stationary sequences of bounded random variables with values in a Hilbert space. The conditions obtained are expressed in terms of martingale-type conditions. The main tools are martingale approximations and a new Hoeffding inequality for non adpated sequences of Hilbert-valued random variables. Applications to Cramer-Von Mises statistics, functions of linear processes and stable Markov chains are given.

2008-01-01

289

Medium-chain fatty acid binding to albumin and transfer to phospholipid bilayers.  

UK PubMed Central (United Kingdom)

Temperature-dependent (5-42 degrees C) 13C NMR spectra of albumin complexes with 90% isotopically substituted [1-13C]decanoic acids (3 mol of fatty acid per mol of albumin) showed a single peak at greater...Full Text Available

1989-04-01

290

Inflammatory mediators promote production of shed LRP1/CD91, which regulates cell signaling and cytokine expression by macrophages  

UK PubMed Central (United Kingdom)

LRP1 is a type-1 transmembrane receptor that mediates the endocytosis of diverse ligands. LRP1 β-chain proteolysis results in release of sLRP1 that is present in human plasma. In this study,...Full Text Available

2010-10-01

291

Incorporation of "1"4C-linoleic acid in cerebrosides of psoriatic and normal human skin  

International Nuclear Information System (INIS)

It was shown that the incorporation of "1"4C-linoleic acid in cerebrosides of normal and psoriatic human skin is different. In psoriatic epidermis and corium the turnover of this fatty acid is significantly elevated. It is suggested that in psoriasis the epidermal cell is not able to build up a regular carbohydrate sequences of lipids because the false carbohydrate chain activates the degradation of glycolipids and in compensating for the increased degradation raises the synthesis rate of glycolipids. (orig./MG).

292

Improving the Quality of Life  

Wastenet

...and supply ensuring better food quality for the consumer developing safer and more flexible food production processes and technologies raw materials for food production; production and processing systems; by-products and wastes from fisheries and agro-industry; new food sources; packaging systems; quality monitoring; traceability Food contamination detecting and eliminating infectious and toxic agents throughout the food chain establishing the hazards and origins of food contaminants producing food more safely rapid ...

293

Fouling Study of Silicon Oxide Pores Exposed to Tap Water  

Energy Technology Data Exchange (ETDEWEB)

We report on the fouling of Focused Ion Beam (FIB)-fabricated silicon oxide nanopores after exposure to tap water for two weeks. Pore clogging was monitored by Scanning Electron Microscopy (SEM) on both bare silicon oxide and chemically functionalized nanopores. While fouling occurred on hydrophilic silicon oxide pore walls, the hydrophobic nature of alkane chains prevented clogging on the chemically functionalized pore walls. These results have implications for nanopore sensing platform design.

2007-07-12

294

Flow improvers for crude and residual-containing fuel oils  

Science.gov (United States)

Copolymers of a 1,2 epoxy alkane and a cyclic carboxylate compound of the class consisting of dicarboxylic acid anhydrides, preferably maleic anhydride or a hydrocarbyl substituted succinic anhydride and a beta lactone, said copolymers having C/sub 10/ to C/sub 50/, preferably C/sub 20/ to C/sub 40/, linear, pendant hydrocarbon chains are flow improvers in residual and crude oils.

1979-01-23

295

Effect of the electron-electron coupling parameters on the superconducting transition temperature in the compounds with the A-15 structure  

International Nuclear Information System (INIS)

The electron structure of the A-15 compounds is studied by accounting for the Hubbard energy as the highest energy parameter. The conditions for the Cooper instability origination are obtained. The superconducting transition temperature dependence on the degree of filling the d- and p-shells of the transition and nontransition elements is determined. The relationship between the transition temperature and the energy jumpover along the chains, which allows comparison with the experiment, is established. Qualitative explanation of the Mattias empiric rules is presented

2000-09-01

296

Density of states of ordered and disordered A-15 phase  

International Nuclear Information System (INIS)

Within the tight binding framework, a study is made of how the disorder affects the electronic properties of A-15 compounds. In particular it is shown that for compounds of two transition metals in the A-15 structure, the vacancy formation affects the density of states only in the low energy region or in the high energy region, in opposition with the isolated chain model of Labbe and Friedel. It is concluded that interchain interactions are important. (U.K.).

297

Convergenomics Strategic Innovation in the Convergence Era  

CERN Document Server

Convergenomics is about the megatrends that are shaping how people behave and organizations work. In this insightful analysis, Sang Lee and David Olson describe how globalization, digitization, changing demographics, changing industry mix, deregulation and privatization, commoditization of processes, new value chains, emerging new economies, deteriorating environment, and cultural conflicts have led to what they define as a convergence revolution.Lee and Olson discuss this convergence revolution from the perspectives of technology, industry, knowledge, open-source networking and bio-artificial

2010-01-01

298

Contribution of calcium ions and hydrogen ions to the signal transduction chain in phytochrome-mediated spore germination. [Onoclea sensibilis L  

Energy Technology Data Exchange (ETDEWEB)

Red light stimulates germination in the spores of Onoclea sensibilis L. Phytochrome is confirmed to be the photoreceptor pigment in the germination response by demonstrating red-far-red photoreversibility. External Ca/sup 2 +/ is required for this response with a threshold at a submicromolar concentration. Red light stimulates an increase in the total concentration of intracellular calcium in the spores as determined by atomic absorption spectroscopy. Subsequent exposure to far-red light inhibits the red light-induced increase in intracellular calcium. The majority of the increase occurs 5 minutes after the onset of irradiation. The calcium-antagonist, La/sup 3 +/ inhibits both germination and the red light-induced increase in intracellular calcium. Using /sup 31/P-nuclear magnetic resonance spectroscopy, the author tested the hypothesis that a sustained increase in intracellular pH contributes to the signal transduction chain. He never detected a red light-induced ...

1985-01-01

299

Basic consideration on high power free-electron lasers  

Energy Technology Data Exchange (ETDEWEB)

An FEL amplifier to generate a laser power of the order of TW at 4 {mu}m wavelength is investigated for a {gamma}-{gamma} collider. A concept of an amplifier chain consisting of a phase-displacement deceleration FELs is proposed to increase the FEL efficiency and to mitigate the requirement for the beam energy spread. The feasibility of the driving linac for the FEL system is also discussed. ((orig.)).

1995-02-01

300

Basic consideration on high power free-electron lasers  

International Nuclear Information System (INIS)

An FEL amplifier to generate a laser power of the order of TW at 4 #mu#m wavelength is investigated for a #gamma#-#gamma# collider. A concept of an amplifier chain consisting of a phase-displacement deceleration FELs is proposed to increase the FEL efficiency and to mitigate the requirement for the beam energy spread. The feasibility of the driving linac for the FEL system is also discussed. ((orig.)).

301

A real time neutron diffraction study on the reaction of AsF_5 with deuterated polyparaphenylene  

International Nuclear Information System (INIS)

The doping of deuterated polyparaphenylene [C_6D_4]sub(n) with AsF_5 has been investigated by real time neutron diffractometry at 100, 400 and 820 mbar AsF_5 pressure. The reaction appears to be diffusion controlled. Evidence for one doped phase with partial crystalline order was obtained. Structural considerations suggest two polymer chains plus one dopant ''string'' as the repetitive unit. (Auth.).

1982-01-01

302

A novel amphiphilic pincer palladium complex: design, preparation and self-assembling behavior.  

Science.gov (United States)

Amphiphilic pincer palladium complexes bearing hydrophilic and hydrophobic side chains on the planar NCN palladium pincer backbone were designed and prepared via the ligand introduction route. The complexes self-assembled under aqueous conditions to form vesicles with bilayer membranes containing palladium species. The catalytic activity of the vesicles in the Miyaura-Michael reaction in water was investigated. PMID:21837316

2011-08-11

303

31P NMR study of improvement in oxidative phosphorylation by vitamins K3 and C in a patient with a defect in electron transport at complex III in skeletal muscle.  

UK PubMed Central (United Kingdom)

The bioenergetic capacity of skeletal muscle in a 17-year-old patient with a severe defect in complex III of the electron transport chain has been examined by 31P NMR measurements of the molar ratio...Full Text Available

1984-06-01

304

(-)-Epigallocatechin Gallate Regulates CD3-mediated T Cell Receptor Signaling in Leukemia through the Inhibition of ZAP-70 Kinase*  

UK PubMed Central (United Kingdom)

The ζ chain-associated 70-kDa protein (ZAP-70) of tyrosine kinase plays a critical role in T cell receptor-mediated signal transduction and the immune response. A high level of ZAP-70 expression...Full Text Available

2008-10-17

305

The behavior of waste rock piles; Le comportement des haldes de steriles  

Energy Technology Data Exchange (ETDEWEB)

Under the auspices of the Mine Environment Neutral Drainage (MEND) Program, several waste rock piles were monitored and characterized. Acid rock drainage (ARD) became a mechanism better understood based on the data acquired during these projects. Numerical simulation was used to better comprehend the quantitative issues associated with the characterization of three specific sites for the purpose of this study. The sites selected were the south waste rock pile of the Doyon Mine in Quebec, the Northdale of the mining district of Ronnenberg in Germany, and the waste rock pile of the Sugar Shack South of the Questa mine in New Mexico. The observed and simulated conditions were very distinct from one mine to another, even if the same mechanisms were involved. The dominant oxygen and heat transfer mechanisms displayed the most varied behavior between the sites. ARD control or site rehabilitation decisions were based on the quantitative understanding gained from the ...

2000-07-01

306

The Structure of Sucrose Phosphate Synthase from Halothermothrix orenii Reveals Its Mechanism of Action and Binding Mode  

Energy Technology Data Exchange (ETDEWEB)

Sucrose phosphate synthase (SPS) catalyzes the transfer of a glycosyl group from an activated donor sugar, such as uridine diphosphate glucose (UDP-Glc), to a saccharide acceptor D-fructose 6-phosphate (F6P), resulting in the formation of UDP and D-sucrose-6'-phosphate (S6P). This is a central regulatory process in the production of sucrose in plants, cyanobacteria, and proteobacteria. Here, we report the crystal structure of SPS from the nonphotosynthetic bacterium Halothermothrix orenii and its complexes with the substrate F6P and the product S6P. SPS has two distinct Rossmann-fold domains with a large substrate binding cleft at the interdomain interface. Structures of two complexes show that both the substrate F6P and the product S6P bind to the A-domain of SPS. Based on comparative analysis of the SPS structure with other related enzymes, the donor substrate, nucleotide diphosphate glucose, binds to the B-domain of SPS. Furthermore, we propose a ...

2008-01-01

307

Sucrose transport into stalk tissue of sugarcane  

Energy Technology Data Exchange (ETDEWEB)

The productivity of higher plants is, in part, dependent on transport of photosynthate from source to sink (in sugarcane, stalk) and upon its assimilation in cells of the sink tissue. In sugarcane, sucrose has been reported to undergo hydrolysis in the apoplast before uptake into the storage parenchyma, whereas recently, sucrose was reported to be taken up intact. This work was based on lack of randomization of ({sup 14}C)fructosyl sucrose accumulated after feeding tissue slices with this sugar. In this report, we present evidence from slices of stalk tissue that sucrose is taken up intact via a carrier-mediated, energy-dependent process. The evidence includes: (1) uptake of fluorosucrose, an analog of sucrose not subject to hydrolysis by invertase; (2) little or no randomization of ({sup 14}C) fructosyl sucrose taken up; (3) the presence of a saturable as well as a linear component of sucrose uptake; and (4) inhibition of both the saturable and linear components ...

1990-05-01

308

Rubidium uptake by mouse pancreatic islets exposed to 6-hydroxydopamine, ninhydrin, or other generators of hydroxyl radicals  

International Nuclear Information System (INIS)

The purpose was to study the toxicity of drugs known to generate free radicals on isolated pancreatic islets. The accumulattion of "8"6Rb"+ by mouse pancreatic islets was measured in vitro. Exposing the islets to 6-hydroxydopamine, minhydrin, or phenazine methosulphate + NADH inhibited the Rb"+ uptake, whereas paraquat or acetylphenylhydrazine had no effect. This effect of 6-hydroxydopamine was prevented by either of the hydroxyl radical scavengers, sodium benzoate and mannitol, but not by the non-scavenger,urea; ninhydrin was partially protected against by mannitol but not by benzoate. Protection against 6-hydroxydopamine was also afforded by D-glucose but not by L-glucose or 3-O-methyl-D-glucose; none of the sugars protected against ninhydrin. In damaging islet beta-cells and in being protected against by D-glucose, 6-hydroxydopamine closely resembles the diabetogenic drug, alloxan. It is suggested that protection against alloxan may involve both glucose ...

309

Relaxant effects of hexosamines on isolated small human placental arteries  

DEFF Research Database (Denmark)

Wharton's jelly contains large amounts of hyaluronic acid, and glucosamine is an important constituent of this macromolecule. In order to evaluate the placental vascular effects of this aminosugar, small chorionic and stem villous arteries were dissected from placental specimens obtained at normal term vaginal deliveries (n = 15). Ring preparations were mounted in organ baths, and isometric wall tensions were measured. Glucosamine and its epimer galactosamine (5 X 10(-4) to 10(-2) M) produced marked relaxation of contractions induced by PGF2 alpha (10(-5) M) in both chorionic and stem villous arteries. The effect was unchanged after pretreatment with atropin, propranolol and indomethacin. The relaxant effect of the neutral sugar mannose was less pronounced compared with that of the hexosamines. Total tissue concentrations of placental hexosamines have been reported within the range needed to produce placental vascular relaxation in the present study. However, the ...

1987-01-01

310

Purification and analysis of RNA polymerase II transcription factors by using wheat germ agglutinin affinity chromatography.  

Science.gov (United States)

We recently found that many RNA polymerase II transcription factors are modified with N-acetylglucosamine residues. These sugar moieties confer upon transcription factors an ability to bind the lectin wheat germ agglutinin. We have taken advantage of this interaction to devise a purification procedure for the "GC-box" binding transcription factor Sp1. Crude nuclear extracts are first subjected to wheat germ agglutinin affinity chromatography and then subjected to sequence-specific DNA affinity chromatography. The Sp1 protein purified by this procedure is at least 95% pure, and the overall recovery is greater than 80%. In addition to yielding larger quantities of Sp1 than conventional schemes, the new purification procedure is also simpler and more rapid. We show that wheat germ agglutinin affinity chromatography can also be used to purify the glycosylated forms of the CCAAT-binding transcription factor. Thus, wheat germ agglutinin affinity chromatography may aid ...

1989-03-01

311

Proteomic analysis of the shistosome tegument and its surface membranes  

Scientific Electronic Library Online (English)

Abstract in english The tegument surface of the adult schistosome, bounded by a normal plasma membrane overlain by a secreted membranocalyx, holds the key to understanding how schistosomes evade host immune responses. Recent advances in mass spectrometry (MS), and the sequencing of the Schistosoma mansoni transcriptome/genome, have facilitated schistosome proteomics. We detached the tegument from the worm body and enriched its surface membranes by differential extraction, before subjecting t (more) he preparation to liquid chromatography-based proteomics to identify its constituents. The most exposed proteins on live worms were labelled with impearmeant biotinylation reagents, and we also developed methods to isolate the membranocalyx for analysis. We identified transporters for sugars, amino acids, inorganic ions and water, which confirm the importance of the tegument plasma membrane in nutrient acquisition and solute balance. Enzymes, including phosphohydrolases, ...

2006-10-01

312

Preliminary investigation into the pressing process of sweet pearl millet and sweet sorghum biomass for ethanol production  

Energy Technology Data Exchange (ETDEWEB)

Corn is the main source for biofuel production in North America. However, both sweet pearl millet and sweet sorghum crops represent an interesting alternative to corn for ethanol production because of their high biomass yield under a wide range of environmental conditions and high concentration of readily fermentable sugars. Coproducts such as pressing residues can be also be utilized so that nothing is lost in the process. However, in order to improve the extraction of juice for ethanol production, the pressing process of this biomass must be optimized. Preliminary experiments were therefore conducted to optimize the juice extraction from sweet pearl millet and sweet sorghum using 2 different presses, notably a screw press and a manually operated hydraulic press. Both types of biomass were either chopped finely or coarsely and were exposed to various pressures with the hydraulic press. The volume of juice extracted from both crops increased linearly with ...

2010-07-01

313

Partitioning and transport of the translocates mannitol and sucrose in the light and dark in celery (Apium Graveolens L. )  

Energy Technology Data Exchange (ETDEWEB)

Sucrose and mannitol are major photosynthetic products and translocates in celery. Assimilate partitioning and transport were studied by pulse-labeling leaves with /sup 14/CO/sub 2/ followed by different length chases in ambient air. After a 2 h chase in the light there was more /sup 14/C in sucrose than mannitol in source leaves and their petioles. In contrast after a 2 h dark chase leaves contained more /sup 14/C in mannitol than sucrose but petioles had more /sup 14/C in sucrose than mannitol. After a 15 h chase (6 h light; 9 h dark) labeled sucrose was higher in source petiole vascular bundles than in adjacent parenchyma tissue but label in glucose and fructose was higher in the parenchyma tissue. After the 15 h chase most of the /sup 14/C remaining in developing sink leaves and their petioles was in mannitol. Although in the light mannitol:sucrose ratios are the same in leaf and petiole tissues, in the dark sucrose is initially the major translocate with mannitol becoming more ...

1987-04-01

314

Molar extinction coefficients of some carbohydrates in aqueous solutions  

Science.gov (United States)

Molar extinction coefficients of some carbohydrates viz. L-arabinose (C5H10O5), D-glucose (C6H12O6), D-mannose (C6H12O6), D-galactose (C6H12O6), D(-) fructose (C6H12O6) and maltose (C12H24O12) in aqueous solutions have been determined at 81, 356, 511, 662, 1173 and 1332 keV by gamma ray transmission method in a narrow beam good geometry set-up. These coefficients have been found to depend upon the photon energy following a 4-parameter polynomial. These extinction coefficients for different sugars having the same molecular formula have same values varying within experimental uncertainty. Within concentration ranges studied, Beer--Lambert law is obeyed very well.

2002-03-01

315

Induction of mutation in Trichoderma viride for conversion of natural cellulose into glucose  

Energy Technology Data Exchange (ETDEWEB)

The production of cellulolytic enzymes from fungi has been extensively studied. Several mutants of Trichoderma reesei were selected. Most of the studies were carried out on T. reesei, T. viride, T. harzianum, Penicillium funiculosum, Altemaria alternata. Aspergillus phoenicis, A. ustus, A. tamarii, A. japonicus, and A. niger. T. koningii is one of the most active producers of the so-called C, factor, which is indispensable for the rapid and extensive attack on crystal-line cellulose. However, Trichodenna is known to excrete only small amounts of {beta}-glucosidase. Therefore, Trichoderma is supplemented with {beta}-glucosidase from Aspergillus to increase the saccharification rate of cellulose to glucose as the main sugar. Induction of mutations in Trichodenna spp. rather than T. viride as a tool for the enhancement of {beta}-glucosidase activity was reported. Unfortunately, T. reesei is a poor producer of {beta}-glucosidase. On the other hand, T. harzianum M{sub ...

1991-12-31

316

Images of very high energy cosmic ray sources in the Galaxy: I. A source towards the galactic centre  

Energy Technology Data Exchange (ETDEWEB)

Recent analyses of the anisotropy of cosmic rays at 10{sup 18} eV (the AGASA and SUGAR data) show significant excesses from regions close to the galactic centre and Cygnus. Our aim is to check whether such anisotropies can be caused by single sources of charged particles. We investigate propagation of protons in two models of the galactic regular magnetic field (with the irregular component included) assuming that the particles are injected by a short-lived discrete source lying in the direction of the galactic centre. We show that apart from a prompt image of the source, the regular magnetic field may cause delayed images at quite large angular distances from the actual source direction. The image is strongly dependent on the time elapsed after ejection of particles and it is also very sensitive to their energy. For the most favourable conditions for particle acceleration by a young pulsar, the predicted fluxes are two to four orders of magnitude higher than those ...

2002-08-01

317

Homo-d-lactic acid production from mixed sugars using xylose-assimilating operon-integrated Lactobacillus plantarum  

British Library Electronic Table of Contents (United Kingdom)

In order to achieve efficient d-lactic acid fermentation from a mixture of xylose and glucose, the xylose-assimilating xylAB operon from Lactobacillus pentosus (PXylAB) was introduced into an l-lactate dehydrogenase gene (ldhL1)-deficient Lactobacillus plantarum (?ldhL1-xpk1::tkt-?xpk2) strain in which the phosphoketolase 1 gene (xpk1) was replaced with the transketolase gene (tkt) from Lactococcus lactis, and the phosphoketolase 2 (xpk2) gene was deleted. Two copies of xylAB introduced into the genome significantly improved the xylose fermentation ability, raising it to the same level as that of ?ldhL1-xpk1::tkt-?xpk2 harboring a xylAB operon-expressing plasmid. Using the two-copy xylAB integrated strain, successful homo-d-lactic acid production was achieved from a mixture of 25?g/l xylos...

2011-01-01

318

Food and chemical industry. Soy sauce and chemical engineering; Shokuhinn to kagaku kogaku. Shoyu to kagaku kogaku  

Energy Technology Data Exchange (ETDEWEB)

The buckwheat soup is a mixture of seasonings such as soy sauce, sweet sake, sugar and the like and stock of dried bonito. This paper describes an analysis of the stock manufacturing step, an important step in the manufacture of buckwheat soup, and the setting of stock extraction conditions on the basis of this analysis. If the rate of infiltration of water into the dried bonito is found, it is a very effective finding for setting the thickness of flakes of dried bonito and the extraction time to prepare buckwheat soup industrially. To obtain such knowledge, the time taken for the water to pass through flakes of dried bonito of various thicknesses, to vaporize and to remove latent heat till the temperature of the surfaces of flakes lowers was measured. The thickness of flakes of dried bonito and extraction time were set on the basis of the data thus obtained. Dired bonito was then supplied to a bench scale flow extraction apparatus filled with hot water, and the ...

1997-05-05

319

Effects of an acute dose of gamma radiation exposure on stem diameter growth, carbon gain, and biomass partitioning in Helianthus annuus  

Energy Technology Data Exchange (ETDEWEB)

Nineteen-day-old dwarf sunflower plants (Helianthus annuus, variety NK894) received a variable dose (0-40 Gy) from a cobalt-60 gamma source. A very sensitive stem monitoring device, developed at Battelle's Pacific Northwest Laboratories, Richland, Washington was used to measure real-time changes in stem diameter. Exposure of plants caused a significant reduction in stem growth and root biomass. Doses as low as 5 Gy resulted in a significant increase in leaf density, suggesting that nonreversible morphological growth changes could be induced by very low doses of radiation. Carbohydrate analysis of 40-Gy irradiated plants demonstrated significantly more starch content in leaves and significantly less starch content in stems 18 days after exposure than did control plants. In contrast, the carbohydrate content in roots of 40-Gy irradiated plants were not significantly different from unirradiated plants 18 days after exposure. These results indicate that radiation either decreased ...

1988-05-25

320

Development and application of microbial selective plugging processes  

Energy Technology Data Exchange (ETDEWEB)

Phillips Petroleum Company recently completed a microbial selective plugging (MSP) pilot at the North Burbank Unit (NBU), Shidler, Oklahoma. Nutrients were selected for the pilot that could stimulate indigenous microflora in the reservoir brine to grow and produce exopolymer. It was found that soluble corn starch polymers (e.g., maltodextrins) stimulated the indigenous bacteria to produce exopolymer, whereas simple sugars (e.g., glucose and sucrose), as well as complex media (e.g., molasses and Nutrient Broth), did not. Injection of maltodextrin into rock cores in the presence of indigenous NBU bacteria resulted in stable permeability reductions (> 90%) across the entire length, while injection of glucose resulted only in face plugging. In addition, it was found that organic phosphate esters (OPE) served as a preferable source of phosphorus for the indigenous bacteria, since orthophosphates and condensed phosphates precipitated in NBU brine at reservoir ...

1995-12-31

321

Continuous fermentative hydrogen production in different process conditions  

Energy Technology Data Exchange (ETDEWEB)

This paper reported on a study in which hydrogen was produced by fermentation of biomass. A continuous process using a non-sterile substrate with a readily available mixed microflora was used on heat treated digested sewage sludge from a wastewater treatment plant. Hydrogen was produced from waste sugar at a pH of 5.2 and a temperature of 37 degrees C. An experimental setup of three 5.5 L working volume continuously stirred tank reactors (CSTR) in different stirring speeds were constructed and operated at 7 different hydraulic retention times (HRTs) and different organic loading rates (OLR). Dissolved organic carbon was examined. The results showed that the stirring speed of 135 rpm had a beneficial effect on hydrogen fermentation. The best performance was obtained in 135 rpm and 8 h of HRT. The amount of gas varied with different OLRs, but could be stabilized on a high level. Methane was not detected when the HRT was less than 16 h. The study identified the ...

2010-07-01

322

Chemical Composition and Nutritional Value of Unripe Banana Flour (Musa acuminata, var. Nanic?o)  

British Library Electronic Table of Contents (United Kingdom)

Banana flour obtained from unripe banana (Musa acuminata, var. Nanic?o) under specific drying conditions was evaluated regarding its chemical composition and nutritional value. Results are expressed in dry weight (dw). The unripe banana flour (UBF) presented a high amount of total dietary fiber (DF) (56.24?g/100?g), which consisted of resistant starch (RS) (48.99?g/100?g), fructans (0.05?g/100?g) and DF without RS or fructans (7.2?g/100?g). The contents of available starch (AS) (27.78?g/100?g) and soluble sugars (1.81?g/100?g) were low. The main phytosterols found were campesterol (4.1?mg/100?g), stigmasterol (2.5?mg/100?g) and ?-sitosterol (6.2?mg/100?g). The total polyphenol content was 50.65?mg GAE/100?g. Antioxidant activity, by the FRAP and ORAC methods, was moderated, being 358.67 an...

2011-01-01

323

Assessment of energy potential from biomass in Louisiana. Final report  

Energy Technology Data Exchange (ETDEWEB)

The objective of this project is to identify feasible Louisiana-grown biomass crops and residues, to combine these with technically and economically feasible conversion processes, and to provide integrated biomass energy production systems in Louisiana. Among the recommended integrated systems are: cotton gin trash and rice hull processing residues used for either direct combustion or methane or ethanol production. Steam generation via direct combustion is recommended. Hardwood chips are economically feasible despite considerable price and supply instability, while high sugar or starch content crops are easily converted to ethanol but limited by price. Possible breakthroughs in biomass production or in the hydrolysis of starch or cellulose substrates may decrease processing costs. Recommended areas for future study dealing with production include: (1) increase biomass availability and density; (2) increase harvesting, transportation and storage technologies; (3) ...

1983-12-01

324

Anaerobic digestion of olive mill wastewaters  

Energy Technology Data Exchange (ETDEWEB)

Anaerobic treatment of olive oil mill wastewaters (COD up to 220 kg/cubic m) is feasible, and the most promising results were obtained on UASB reactors, both at laboratory and pilot scale (tank capacity 15 litres and 5 cubic m), fed on diluted waste (COD = 13-18 kg/cubic m). Volumetric loading rates ranging from 16-21.5 kg COD/cubic m/day and 70% removal efficiencies were obtained with these digesters. Start-up of UASB reactors fed on olive oil mill waste is a delicate step which still has to be fully controlled and optimized. The best results were obtained by starting with very diluted waste (COD = 5 kg/cubic m). Granulation of the sludge, as achieved in Dutch UASB digesters fed on sugar beet wastewaters, was not obtained, but, even so, the settleability of the sludge was very good. 22 references.

1984-01-01

325

Adaptation of oral streptococci to low pH.  

Science.gov (United States)

The strategies employed by oral streptococci to resist the inimical influences of acidification reflect the diverse and dynamic niches of the human mouth. All of the oral streptococci are capable of rapid degradation of sugar to acidic end-products. As a result, the pH value of their immediate environment can plummet to levels where glycolysis and growth cease. At this point, the approaches for survival in acid separate the organisms. Streptococcus mutans, for example, relies on its F-ATPase, to protect itself from acidification by pumping protons out of the cells. S. salivarius responds by degrading urea to ammonia and S. sanguis produces ammonia by arginolysis. The mechanisms by which these organisms regulate their particular escape route are now being explored experimentally. The picture that emerges is that the acid-adaptive regulatory mechanisms of the oral streptococci differ markedly from those employed by Gram-negative bacteria. What remains to be ...

2000-01-01

326

A procedure for batch separation of sup 14 C-hexose from sup 14 C-sucrose  

Energy Technology Data Exchange (ETDEWEB)

This presentation describes a method for separating {sup 14}C-hexose from {sup 14}C-sucrose in extracts of plant tissue. Portions of ethanol extracts are treated with activated charcoal in microcentrifuge tubes. Aliquots are removed, ethanol evaporated and replaced with reaction mixture that phosphorylates hexose (HEPPS, K{sub 2}HPO{sub 4}, Mg(C{sub 2}H{sub 3}O{sub 2}){sub 2}, ovalbumen, Na{sub 2}ATP, yeast hexokinase). After a time course, the hexokinase reaction is stopped (slowed considerably) to minimize effects of contamination enzyme activities. The stopping agent used is lyxose, a nonphosphorylable analogue of glucose. The strong anionic charge of phosphate introduced through the hexokinase action results in binding (> 95%) of hexose-phosphate to anion-exchange resin. Sucrose remains unbound (> 95%) in solution. This batch ion-exchange is performed in microcentrifuge tubes to allow many samples to be processed simultaneously. Recovery of radiolabel in extracts is complete ...

1991-05-01

327

A marvel of colors and ingredients. The story of urine test strip.  

Science.gov (United States)

The history of the urinary test papers does not being in the post-war period. As early as the 1880's some practitioners and pharmacists tried to replace the complicated wet-chemical procedures and apparatus by "dry chemistry." The first popular test paper for sugar and albumin originated in England in 1883. Dry reagents for proving hematuria have been available since the beginning of this century. Until the 1930s a wide palette of commercial urine tests with "modern" brand names was established. A methodological breakthrough was created by the spot test chemistry inaugurated by the Austrian, Fritz Feigl, about 1920. Using the capillary properties of filter paper in enhancing color reactions he founded a new area of analytical chemistry. Many of the pioneers were recruited from Jewish scientists. In this lecture is proposed that their emigration and banishment as well as the Second World War have stopped the development of urinary diagnostics on the European ...

1994-11-01

328

A fluorescent aminolipid from a green photosynthetic bacterium  

Energy Technology Data Exchange (ETDEWEB)

A preliminary chemical characterization is presented of phosphate-free aminolipids isolation from Chlorobium limicola f. thiosulfatophilum. The lipid contains no phosphorus, glycerol, sugar, ornithine, or lysine. Ultraviolet absorption and fluorescence spectra indicate that the amino moiety of the lipid is an aromatic heterocyclic compound. Infrared spectra indicate that the lipid is a secondary or tertiary amide, and gas chromatograhic analysis of the hydrolyzed lipid shows that for each 1100 g of lipid, 1 mol of myristic acid (C/sub 14:0/) is linked in an amide bond. Acid hydrolysis of the lipid yields two fluorescent substances, A (ninhydrine positive) and B (negative), in addition to myristic acid. Proton nuclear magnetic resonance (NMR) studies indicate that substance A contains a butyl groups attached to a conjugated ring carbon, two equivalent ethyl groups attached to one or two nitrogen atoms, and two downfield protons (8.4 ppm), perhaps attached to a ring ...

1983-04-12

329

A New and Sound Technology for Biogas from Solid Waste and Biomass  

International Nuclear Information System (INIS)

Organic waste, as a main constituent of municipal solid waste, has as well as solid biomass a high potential for biogas generation. Despite the importance of biogas generation from these materials, the availability of large-scale biogas processes lacks behind the demand. A newly developed double-stage solid-liquid biogas process, consisting of an open hydrolysis stage and a fixed-bed methane reactor, allows the biogas production from almost all biodegradable solid waste and renewable resources like maize, grass, sugar cane, etc. Furthermore, residues from industrial processes, like the glycerine waste water from biodiesel production, can also be converted into biogas successfully. Due to the strong separation of hydrolysis and methanation, the process is extremely stable. No malfunction has been detected so far. The open hydrolysis releases CO_2 and allows oxidation of sulfur. Consequently, the biogas has a high methane (>72%) and low H_2S concentration (<100 ...

2009-04-01

330

A Blueprint for Telerehabilitation Guidelines?October 2010  

British Library Electronic Table of Contents (United Kingdom)

Committee Members Co-Chairs David Brennan, M.B.E., Senior Research Engineer, National Rehabilitation Hospital, Washington, District of Columbia. Lyn Tindall, Ph.D., Speech-Language Pathologist, Department of Veterans Affairs Medical Center, Lexington, Kentucky. Writing Committee Janet Brown, M.A., CCC-SLP, Director, Health Care Services, American Speech-Language-Hearing Association, Rockville, Maryland. Mike Campbell, M.S., M.B.A., CCC-SLP, Director of the Speech and Hearing Program, The University of North Carolina at Greensboro, Browns Summit, North Carolina. Jana Cason, D.H.S., OTR/L, Assistant Professor, Auerbach School of Occupational Therapy, Louisville, Kentucky. Diana Christiana, M.A.T., CCC-SLP, President/CEO, Clinical Communications, Sugar Land, TX. Alan Lee, Ph.D., P.T., D.P.T.,...

2011-01-01

331

Simulating physiological conditions to evaluate nanoparticles for magnetic fluid hyperthermia (MFH) therapy applications  

Energy Technology Data Exchange (ETDEWEB)

Magnetite nanoparticles with high self-heating capacity and low toxicity characteristics are a promising candidate for cancer hyperthermia treatment. In order to achieve minimum dosage to a patient, magnetic nanoparticles with high heating capacity are needed. In addition, the influence of physiological factors on the heat capacity of a material should be investigated in order to determine the feasibility. In this study, magnetite nanoparticles coated with lauric acid were prepared by co-precipitation of Fe{sup 3+}:Fe{sup 2+} in a ratio of 2:1, 5:3, 3:2, and 4:3, and the pH was controlled using NaOH. Structural and magnetization characterization by means of X-ray diffractometry (XRD) and a superconducting quantum interference device (SQUID) revealed that the main species was Fe{sub 3}O{sub 4} and further showed that most of the nanoparticles exhibited superparamagnetic properties. All of the magnetic nanoparticles showed a specific absorption rate (SAR) increase that was linear with ...

2010-01-15

332

Unsymmetrically substituted n-type perylene bisimides with liquid crystalline properties  

Energy Technology Data Exchange (ETDEWEB)

Perylene bisimides (PBIs) represent an important class of organic n-type semiconductors exhibiting a relatively high electron affinity among large-band-gap materials. Herein synthesis and characterization of several unsymmetrical N-substituted PBI dyes is presented and the thermotropic behavior, which is strongly affected by the respective N-substituents was investigated. Two different series of highly soluble and fluorescent derivatives have been synthesized: (1) PBIs bearing swallow-tailed alkyl chains, different in size or (2) one swallow-tailed alkyl chain and one branched oligoethylenglycolether. Synthesis of these PBIs is generally feasible by two distinct divergent synthesis approaches. Thermotropic behavior was studied by DSC, POM and XRD measurements. Inherent {pi}-{pi} interactions between cofacially orientated perylene molecules and the elliptic shape of the molecule favor the ordering in columns and self-organized architectures. ...

2009-07-01

333

Transbilayer and interbilayer phospholipid exchange in dimyristoylphosphatidylcholine/dimyristoylphosphatidylethanolamine large unilamellar vesicles  

International Nuclear Information System (INIS)

The rates of spontaneous interbilayer and transbilayer exchange of ["3H]dimyristoylphosphatidylcholine (["3H]DMPC) were examined in the DMPC and DMPC/dimyristoylphosphatidylethanolamine (DMPE) large unilamellar vesicles in the liquid-crystalline-, gel-, and mixed-phase states. DMPC desorption rates from either gel or liquid-crystalline phases containing DMPE are very similar to the corresponding rates from pure DMPC gel or liquid-crystalline phases. The authors proposed that the DMPC/DSPC behavior results from packing defects in gel phases composed of both DMPC and DSPC molecules because of the four-carbon difference in the acyl chain lengths of the two species. The present results strongly support this hypothesis because no such anomalous behavior is observed in DMPC/DMPE, which is similar to DMPC/DSPC in phase behavior but does not have the chain length difference. These results are not consistent with lipid headgroup dehydration as the major ...

334

The superspin approach to a disordered quantum wire in the chiral-unitary symmetry class with an arbitrary number of channels  

CERN Document Server

We use a superspin Hamiltonian defined on an infinite-dimensional Fock space with positive definite scalar product to study localization and delocalization of noninteracting spinless quasiparticles in quasi-one-dimensional quantum wires perturbed by weak quenched disorder. Past works using this approach have considered a single chain. Here, we extend the formalism to treat a quasi-one-dimensional system: a quantum wire with an arbitrary number of channels coupled by random hopping amplitudes. The computations are carried out explicitly for the case of a chiral quasi-one-dimensional wire with broken time-reversal symmetry (chiral-unitary symmetry class). By treating the space direction along the chains as imaginary time, the effects of the disorder are encoded in the time evolution induced by a single site superspin (non-Hermitian) Hamiltonian. We obtain the density of states near the band center of an infinitely long quantum wire. Our results ...

2009-01-01

335

The carbon balance and greenhouse effects of the Finnish forest sector at present, in the past and future  

Energy Technology Data Exchange (ETDEWEB)

In this study the greenhouse impact of the total Finnish forest sector was considered, which means that the estimated emissions and sink effects from exported forest products were also included. The forest biomass is and seems to be in the next decades the most important factor in the carbon balance of the total forest sector. The development alternatives of forest industries and waste management practices has still a remarkable influence on the greenhouse impact of the Finnish forest sector. The waste management practices in the future has an important influence on the emissions but the exact net greenhouse impact of the landfills is still uncertain. However, the methane emissions from existing landfills can be reduced essentially by gas recovery. Increased incineration and energy recovery of wood waste (and replacing fossil fuel use by it) is also a future alternative for reducing the greenhouse effects in the forest sector. The sequestration of carbon by increasing the storages of ...

1996-12-31

336

Smooth muscle myosin heavy chain locus (MYH11) maps to 16p13. 13-p13. 12 and establishes a new region of conserved synteny between human 16p and mouse 16  

Energy Technology Data Exchange (ETDEWEB)

The human smooth muscle myosin heavy chain locus (MYH11) was mapped by fluorescence in situ hybridization to the middle of the p arm of chromosome 16 using a genomic cosmid clone containing coding sequences of the gene as probe. Probe from coding sequence, when applied to Southern blots of a panel of hybrids containing different portions of human chromosome 16, localized the gene to 16p13.13-13.12. Coding sequence PCR primers, when used on the DNA from a CHO-mouse hybrid clone mapping panel informative for mouse chromosomes, showed that the gene was located on mouse chromosome 16. These results correct a recent assignment of MYH11 from 16q12.2 to the region of the 16p-arm inversion breakpoint seen in acute myelomonocytic leukemia (AMML) M4Eo and demonstrate that the conflicting data do not result from the presence of additional MYH genes on the q arm of the chromosome. Also, a new region of conserved synteny between human 16p and mouse 16 is established. 10 refs., ...

1993-10-01

337

Reactions of 3-methylpentane and 2,3-dimethylbutane on aluminosilicate catalysts  

Science.gov (United States)

Catalytic reactions of 3-methylpentane and 2,3-dimethylbutane on HY, amorphous silica-alumina, and HZSM-5 have been studied at 500{degree}C. Both kinetic phenomena and product selectivities have been reported. Cracking reactions an HZSM-5 can be attributed to initiation through protonation occurring at Bronsted sites. Bimolecular processes leading to chain reaction via hydride transfer are restricted within the narrow pore pentasil zeolite. On HY and amorphous silica-alumina, initiation of cracking also occurs at Bronsted sited. No direct evidence was found for participation of Lewis acid sites on the catalyst framework itself. Following initiation, reactions on these catalysts are accelerated through a chain process occurring at Lewis sites generated by adsorption of product olefins at Bronsted sites. The resulting change in the dominant cracking mechanism is reflected in the product selectivity, illustrated here by a falling off in formation ...

1990-12-01

338

Radiation-induced mutations at mouse hemoglobin loci  

International Nuclear Information System (INIS)

In experiments designed to detect new mutations affecting hemoglobin, we irradiated the male or female parent in reciprocal crosses of two mouse strains that differ in alleles at the hemoglobin (Hba, Hbb) loci as well as at five other specific loci. Offspring were analyzed for hemoglobin properties (electrophoretic pattern, solubility, crystal pattern), serum albumin differences, erythrocyte lysis, reticulocyte count, and external appearance. Five hemoglobin variants were found among the mutants. In three, the genetic contribution from the irradiated father was not expressed with regard to the #alpha#-chain; one carried a tandem duplication (the first known case in the mouse) involving Hbb; and one probably resulted from double nondisjunction of chromosome 7. The finding that major chromosome aberratios can mimic hemoglobin mutations indicates the need, in similar experiments, to follow F_1 screening with thorough cytogenetic analysis. The variants in which there ...

339

Quantitation of acyl migration during lipase-catalyzed acidolysis, and of the regioisomers of structured triacylglycerols formed  

DEFF Research Database (Denmark)

Various MLM-type (M, medium-chain fatty acids; L, long-chain fatty acids) structured triacylglycerols were produced in pilot- or small-scale packed-bed reactors by lipase-catalyzed acidolysis. The incorporation and acyl migration of octanoic acid were measured by gas chromatography and Grignard degradation, and ranged from 39.0 to 48.7% and 0.6 to 9.3%, respectively. Quantitation of triacylglycerol molecular species was performed by ammonia negative ion chemical ionization (NICI) mass spectrometry (MS). The proportion of ACN (acyl carbon number) 34 species that contained one C-18 fatty acid and two C-8:0, in samples analyzed, varied from 12.5 to 23.2%. The selected regioisomers MLM and MML within the ACN 34 species group were quantified by NICI tandem MS (MS/MS) and were in the range of 97.1 to 98.4% and 1.6 to 2.9%, respectively. There was no correlation between the level of acyl migration during lipase-catalyzed esterification and the level ...

2001-01-01

340

Neutron diffraction study of quasi-one-dimensional spin-chain compounds Ca3Co2-xFexO6  

International Nuclear Information System (INIS)

We report the results of the DC magnetization, neutron powder diffraction and neutron depolarization studies on the spin-chain compounds Ca3Co2-xFexO6 (x = 0, 0.1, 0.2 and 0.4). Rietveld refinement of neutron powder diffraction patterns at room temperature confirms the single-phase formation for all the compounds in rhombohedral structure with space group R3-barc. Rietveld refinement also confirms that Fe was doped at the trigonal prism site, 6a (0, 0, 1/4) of Co. The high temperature magnetic susceptibility obeys the Curie-Weiss law; the value of the paramagnetic Curie temperature (?p) decreases as the concentration of iron increases and it becomes negative for x = 0.4. No extra Bragg peak as well as no observable enhancement in the intensity of the fundamental (nuclear) Bragg peaks has been observed in the neutron diffraction patterns down to 30 K. No depolarization of neutron beam has been observed down to 3 K confirming the absence of ferro- or ...

2008-11-01

341

Highly specific antiserum for arginine vasopressin  

International Nuclear Information System (INIS)

A high sensitivity (titer 60-150,000) radioimmunoassay for arginine vasopressin (AVP) has been developed using synthetic AVP as antigen and standard. The specificity of the antiserum has been characterized in detail by measuring the relative binding affinities of 29 analogs and fragments of AVP. In general, single amino acid substitution or deletion in the AVP molecule caused a reduction in binding to the antiserum; binding was further impaired for analogs which had multiple substitutions. ''Ring'' and ''tail'' fragments of the neurohypophysial hormones did not bind to the antiserum, and the only analog which the antiserum could not differentiate from AVP was deamino-AVP. More specifically, the antiserum exhibited the following properties: position 1, no requirement for a position charge at "1/_2 Cys; positions 2 and 3, requirements for #pi#-#pi# interacting pair of aromatic side chains and for Tyr at position 2; position 4, requirement for Gln (>Thr > Val); ...

342

High resolution Computed Tomography in the study of temporal bone trauma  

International Nuclear Information System (INIS)

Thirty-five patients with temporal bone fractures were examined; the fractures were sometimes associated with dislocation of the assicular chain caused by road fatalities. Computed Tomography (CT) was performed either because of the presence of clinical symptoms associated with trauma of the temporal bone, because of a hemotympanum discovered during a CT scan of the brain. Thirty-three fractures were detected: 19 longitudinal, 6 transverse, and 8 complex. An incudostapedial dislocation was also detected, together with a displacement of a stapedial prosthesis from the lenticular process of incus, and 3 incus-malleus dislocation associated with fractures. High resolution CT allows the precise definition of the course of the fractures, of the associated dislocation of the ossicular chain, and of facial nerve lesion, thus allowing a more accurate surgical intervention. In the examination of the temporal bone, high resolution CT is preferible to ...

1988-01-01

343

Ground-state properties of exotic nuclei near Z=40 in the relativistic mean-field theory  

International Nuclear Information System (INIS)

Study of the ground-state properties of Kr, Sr and Zr isotopes has been performed in the framework of the relativistic mean-field (RMF) theory using the recently proposed relativistic parameter set NL-SH. It is shown that the RMF theory provides an unified and excellent description of the binding energies, isotope shifts and deformation properties of nuclei over a large range of isospin in the Z=40 region. It is observed that the RMF theory with the force NL-SH is able to describe the anomalous kinks in isotope shifts in Kr and Sr nuclei, the problem which has hitherto remained unresolved. This is in contrast with the density-dependent Skyrme-Hartree-Fock approach which does not reproduce the behaviour of the isotope shifts about shell closure. On the Zr chain we predict that the isotope shifts exhibit a trend similar to that of the Kr and Sr nuclei. The RMF theory also predicts shape coexistence in heavy Sr isotopes. Several dramatic shape transitions in the ...

344

Expression of fully functional tetrameric human hemoglobin in Escherichia coli  

International Nuclear Information System (INIS)

Synthesis genes encoding the human #alpha#- and #beta#-globin polypeptides have been expressed from a single operon in Escherichia coli. The #alpha#- and #beta#-globin polypeptides associate into soluble tetramers, incorporate heme, and accumulate to >5% of the total cellular protein. Purified recombinant hemoglobin has the correct stoichiometry of #alpha#- and #beta#-globin chains and contains a full complement of heme. Each globin chain also contains an additional methionine as an extension to the amino terminus. The recombinant hemoglobin has a C_4 reversed-phase HPLC profile essentially identical to that of human hemoglobin A_0 and comigrates with hemoglobin A_0 on SDS/PAGE. The visible spectrum and oxygen affinity are similar to that of native human hemoglobin A_0. The authors have also expressed the #alpha#- and #beta#-globin genes separately and found that the expression of the #alpha#-globin gene alone results in a marked decrease in ...

345

Development of radiological emergency preparedness and biological dosimetry technology  

Energy Technology Data Exchange (ETDEWEB)

Large-scale field tracer experiments have been conducted on Ulchin and Wolsung nuclear sites for the purpose of validating FADAS and of analyzing the environmental characteristics around the nuclear site. The most influential factor in atmospheric dispersion is the meteorological condition. During the experiment, meteorological data were measured on the release point and the selected positions among sampling points. Once radioactive materials are released to the atmosphere, members of public may be exposed through the environmental media such as air, soil and foods. Therefore, to protect the public, adequate countermeasures should be taken at due time for those exposure pathways. Both processes of justification and optimization are applied to a countermeasure simultaneously for decision-making. The work scope of biological research for the radiation protection had contained the search of biological microanalytic methods for the assessment of health effect by radiation and toxic agents, ...

1999-04-01

346

Crystalline and Liquid Crystalline Organic-Inorganic Hybrid Salts with Cation-Sensitized Hexanuclear Molybdenum Cluster Complex Anion Luminescence  

British Library Electronic Table of Contents (United Kingdom)

Abstract The salts [Cnmim]2[Mo6Cl14] (mim = methylimidazolium; n = 4, 6, 12, 16, 18) have been obtained by reaction of CnmimCl with MoCl2. Thermal analysis shows the melting point decreases with increasing alkyl chain length of the cation. The imidazolium chloromolybdates(II) with n = 6-18 decompose above 340 C; [C18mim]2[Mo6Cl14] is thermally stable up to 390 C. All compounds are insensititve to the constituents of the atmosphere. Of the higher melting salts [Cnmim]2[Mo6Cl14] (n = 4, 6), high-quality single crystals could be obtained. Single-crystal X-ray structural analyses clearly show that the cluster complex anion [Mo6Cl14]2- has an electron-precise octahedral {Mo6} cluster. For [C4mim]2[Mo6Cl14], two polymorphs differing in the cation alkyl-side-chain conformation were obtained. The ...

2011-01-01

347

Brain imaging agents: synthesis and characterization of (N-piperidinylethyl) hexamethyl diaminodithiolate oxo technetium(V) complexes  

Energy Technology Data Exchange (ETDEWEB)

Two sup(99m)Tc complexes of (N-piperidinylethyl) hexamethyl diaminodithiol (NEP-DADT) have shown high brain uptake in rodents and lower primates. One of these sup(99m)Tc complexes has given positive images of the brain in man which are qualitatively related to regional brain blood flow (rCBF). In order to determine the structure of these sup(99m)Tc products, the corresponding /sup 99/Tc(NEP-DADT) complexes were prepared and characterized by HPLC, TLC, fast-atom-bombardment mass spectrometry (FAB MS) and other analytical techniques. These results indicate that the two /sup 99/Tc (NEP-DADT) complexes are syn and anti isomers (i.e. one isomer has the N-piperdinylethyl side chain located syn to the technetium oxo core while the other has this side chain located anti to the technetium oxo core).

1987-01-01

348

Brain imaging agents: synthesis and characterization of (N-piperidinylethyl) hexamethyl diaminodithiolate oxo technetium(V) complexes  

International Nuclear Information System (INIS)

Two sup(99m)Tc complexes of (N-piperidinylethyl) hexamethyl diaminodithiol (NEP-DADT) have shown high brain uptake in rodents and lower primates. One of these sup(99m)Tc complexes has given positive images of the brain in man which are qualitatively related to regional brain blood flow (rCBF). In order to determine the structure of these sup(99m)Tc products, the corresponding "9"9Tc(NEP-DADT) complexes were prepared and characterized by HPLC, TLC, fast-atom-bombardment mass spectrometry (FAB MS) and other analytical techniques. These results indicate that the two "9"9Tc (NEP-DADT) complexes are syn and anti isomers (i.e. one isomer has the N-piperdinylethyl side chain located syn to the technetium oxo core while the other has this side chain located anti to the technetium oxo core). (author).

349

Allosteric Tuning of the Intra-Cavity Binding Properties of a Calix[6]arene through External Binding to a ZnII Center Coordinated to Amino Side Chains  

British Library Electronic Table of Contents (United Kingdom)

Molecular recognition by calix[6]arene-based receptors bearing three primary alkylamino side chain arms (1) is described. Complexation of ZnII ion provides the dinuclear m-hydroxo complex ${{\\bf 2}{{{\\rm OH}\\hfill \\atop {\\rm G}\\hfill}}}$, XRD characterization of which, together with solution studies, provided evidence of its hosting of neutral polar organic guests G. Treatment of this complex with a carboxylic acid or a sulfonamide (XH) results in the formation of mononuclear species ${{\\bf 3}{{{\\rm X}\\hfill \\atop {\\rm G}\\hfill}}}$, one of which (X = Cl) has been characterized by XRD. A dicationic complex ${{\\bf 3}{{{\\rm RNH}{_{2}}\\hfill \\atop {\\rm G}\\hfill}}}$ is obtained upon treatment of ${{\\bf 2}{{{\\rm OH}\\hfill \\atop {\\rm G}\\hfill}}}$ with a mixture of an alkylamine and a strong acid....

2007-01-01

350

Aging mechanism of Sulfonated poly(aryl ether ketone) (sPAEK) in an hydroperoxide solution and in fuel cell  

Energy Technology Data Exchange (ETDEWEB)

Ex situ and in situ fuel cell degradation of a sPAEK membrane were investigated. Post-mortem analyses of the aged membrane and of the degradation products eluted in water were carried out by NMR, IR, SEC and EDX. Ex situ agings were performed in a low concentration H{sub 2}O{sub 2} solution (0.07%) without any metallic catalyst. We exemplify that ex situ accelerated aging tests in such hydrogen peroxide solution are relevant to the chemical degradation in fuel cell. We have shown that a 500 h fuel cell test at moderate temperature (60 C) induces significant modifications on the macromolecules such as a 40% molecular weight reduction. Degradation appears heterogeneous and limited to the cathode side. The model compound approach developed in the previous article (Perrot et al.) has allowed the identification of the aging path in fuel cell. Phenolic and carboxylic acid chain ends have been identified as the main products resulting from polymer ...

2010-01-15

351

Adhesive carrier particles for rapidly hydrated sorbent for moderate-temperature dry flue gas desulfurization.  

Science.gov (United States)

A rapidly hydrated sorbent for moderate-temperature dry flue gas desulfurization was prepared by rapidly hydrating adhesive carrier particles and lime. The circulation ash from a circulating fluidized bed boiler and chain boiler ash, both of which have rough surfaces with large specific surface areas and specific pore volumes, can improve the adhesion, abrasion resistance, and desulfurization characteristics of rapidly hydrated sorbent when used as the adhesive carrier particles. The adhesion ability of sorbent made from circulation ash is 67.4% higher than that of the existing rapidly hydrated sorbent made from fly ash, the abrasion ratio is 76.2% lower, and desulfurization ability is 14.1% higher. For sorbent made from chain boiler ash, the adhesion ability is increased by 74.7%, the desulfurization ability is increased by 30.3%, and abrasion ratio is decreased by 52.4%. The abrasion ratios of the sorbent made from circulation ash having ...

2010-06-15

352

A fixed cations and low Tg polymer: the poly(4-vinyl-pyridine) quaternized by poly(ethylene oxide) links. Conductivity study; Un electrolyte polymere a cations fixes et bas Tg: les poly(4-vinylpyridine) quaternisees par des chainons de poly(oxyde d`ethylene). Etude de la conductivite  

Energy Technology Data Exchange (ETDEWEB)

The spontaneous ionic polymerization of 4-vinyl-pyridine in presence of mono-tosylated or bromated short chains of poly(ethylene oxide)-(PEO) is used to prepare amorphous comb-like poly-cations with low Tg. The polymer electrolyte properties of these new structures have been studied without any addition of salts. The ionic conductivity of these fixed cation poly-electrolytes depends on the length of the grafted PEO and varies from 10{sup -7} to 10{sup -4} S/cm between 25 and 80 deg. C. It is only weakly dependent on the nature of the cation but it is controlled by the movements of the pyridinium cation which are facilitated by the plastifying effect of the POE chains which do not directly participate to the ionic transport. (J.S.) 17 refs.

1996-12-31

353

Transmutation of {sup 241}Am in a high thermal neutron flux  

Science.gov (United States)

Amongst the minor actinides issued from the spent nuclear fuel, {sup 241}Am is present in high concentration and contributes significantly to the long-term radiotoxicity of nuclear waste. A major uncertainty was present in the transmutation chain of {sup 241}Am when irradiated by a high intensity thermal neutron flux. This uncertainty was brought about by the poor knowledge of the {sup 242gs}Am neutron capture cross section. A dedicated experiment has been performed at the Institut Laue-Langevin in Grenoble, which gives a definitive experimental answer to this problem.

1998-10-26

354

Transmutation of "2"4"1Am in a high thermal neutron flux  

International Nuclear Information System (INIS)

Amongst the minor actinides issued from the spent nuclear fuel, "2"4"1Am is present in high concentration and contributes significantly to the long-term radiotoxicity of nuclear waste. A major uncertainty was present in the transmutation chain of "2"4"1Am when irradiated by a high intensity thermal neutron flux. This uncertainty was brought about by the poor knowledge of the "2"4"2"g"sAm neutron capture cross section. A dedicated experiment has been performed at the Institut Laue-Langevin in Grenoble, which gives a definitive experimental answer to this problem.

1998-10-26

355

Total mercury and its distribution in blue crab and deep water pink shrimp from Alexandria coast.  

Science.gov (United States)

Total mercury content and its distribution in muscles and viscera of male and female blue crab (Callinectes sapidus Rothbum) and deep water pink shrimp (Parapenacus longirostris) collected from the 3 main fishing grounds near the Alexandria coast in the Mediterranean sea was estimated. The results indicate that the mercury content in the muscles of both species differ according to fishing areas, size, sex, and species. More than 75% of total mercury were accumulated in the viscera of both species which indicates that the mercury entered in these organisms via the feed chain. PMID:3696196

1987-01-01

356

The river Elbe. A case study for the ecological and economical chain of sediments  

Energy Technology Data Exchange (ETDEWEB)

Industrial activities in the river basin of the Elbe have a very long tradition, and have been resulting in the contamination of sediments for centuries. Contamination lasted until the fall of the iron curtain; since then, the situation has improved significantly. In the transition zone between freshwater systems and the marine environment, ports like Hamburg still have to bear this burden of history. An overall (contaminated) management strategy should be developed in the context of the European Water Framework Directive with the emphasis on source control. (orig.)

2002-07-01

357

Synthesis and Biophysical Characterization of Chlorambucil Anticancer Ether Lipid Prodrugs  

DEFF Research Database (Denmark)

The synthesis and biophysical characterization of four prodrug ether phospholipid conjugates are described. The lipids are prepared from the anticancer drug chlorambucil and have C16 and C18 ether chains with phosphatidylcholine or phosphatidylglycerol headgroups. All four prodrugs have the ability to form unilamellar liposomes (86-125 nm) and are hydrolyzed by phospholipase A2, resulting in chlorambucil release. Liposomal formulations of prodrug lipids displayed cytotoxicity toward HT-29, MT-3, and ES-2 cancer cell lines in the presence of phospholipase A2, with IC50 values in the 8-36 ?M range.

2009-01-01

358

Solid-phase synthesis and pharmacological evaluation of novel nucleoside-tethered dinuclear platinum(II) complexes  

British Library Electronic Table of Contents (United Kingdom)

Three novel inosine-based dinuclear platinum complexes have been synthesized via a solid-phase strategy. In these compounds, the metal is linked both to the N-7 of the purine nucleus and to the terminal amine group of a hexylamine side chain installed on N-1. Cis- or trans- diamine as well as ethylenediamine ligands are coordinated to platinum along with a chloride. The synthesised complexes were tested against four different human tumor cell lines. One of these complexes proved to be more cytotoxic than cisplatin against the MCF7 cancer cell line in a short-term exposure assay.

2011-01-01

359

Robust computationally efficient control of cooperative closed-chain manipulators with uncertain dynamics  

British Library Electronic Table of Contents (United Kingdom)

This article presents a decentralized control scheme for the complex problem of simultaneous position and internal force control in cooperative multiple manipulator systems. The proposed controller is composed of a sliding mode control term and a force robustifying term to simultaneously control the payloads position/orientation as well as the internal forces induced in the system. This is accomplished independently of the manipulators dynamics. Unlike most controllers that do not require prior knowledge of the manipulators dynamics, the suggested controller does not use fuzzy logic inferencing and is computationally inexpensive. Using a Lyapunov stability approach, the controller is proven to be robust in the face of varying systems dynamics. The payloads position/orientation and the inte...

2007-01-01

360

Reliable dates for the last 50.000 years; Des dates fiables pour les 50 000 dernieres annees  

Energy Technology Data Exchange (ETDEWEB)

The accuracy of the carbon 14 dating method is dependent on the fluctuations of carbon 14 in the atmosphere over long periods of time. Fossil corals that are dated by both carbon 14 and uranium-thorium methods allows the setting of calibration curves for the carbon 14 method for the last 50.000 years. The uranium-thorium method is based on the measurement of the ratio of 2 isotopes: thorium 230 and uranium 234 that are both present in the decay chain of uranium 238. (A.C.)

2004-03-01

361

Relationship between copper speciation and cyanobacterial distribution in harbors and other coastal environments. Final report, 1 July 1993--1 November 1998  

Energy Technology Data Exchange (ETDEWEB)

The long term goal is to determine the ecological importance of specific toxic metals (copper and zinc) in harbors, through an understanding of their chemistry and biological effects at the base of marine food chains. This work provides information on potential problems with Zn and Cu, which may help to foresee problems in the future. Anthropogenic inputs of both metals are increasing; they are derived from diverse sources and are a simple function of population growth in coastal regions.

1998-11-01

362

Real time neutron diffraction study on the reaction of AsF/sub 5/ with deuterated polyparaphenylene  

Energy Technology Data Exchange (ETDEWEB)

The doping of deuterated polyparaphenylene (C/sub 6/D/sub 4/)sub(n) with AsF/sub 5/ has been investigated by real time neutron diffractometry at 100, 400 and 820 mbar AsF/sub 5/ pressure. The reaction appears to be diffusion controlled. Evidence for one doped phase with partial crystalline order was obtained. Structural considerations suggest two polymer chains plus one dopant ''string'' as the repetitive unit.

1982-07-01

363

Procedures manual for the Evaluated Nuclear Structure Data File  

International Nuclear Information System (INIS)

This manual is a collection of various notes, memoranda and instructions on procedures for the evaluation of data in the Evaluated Nuclear Structure Data File (ENSDF). They were distributed at different times over the past few years to the evaluators of nuclear structure data and some of them were not readily avaialble. Hence, they have been collected in this manual for ease of reference by the evaluators of the international Nuclear Structure and Decay Data (NSDD) network contribute mass-chains to the ENSDF. Some new articles were written specifically for this manual and others are reivsions of earlier versions.

1999-04-01

364

Phase diagram and effective shape of semi-flexible colloidal rods and biopolymers  

CERN Document Server

We study suspensions of semi-flexible colloidal rods and biopolymers using an Onsager-type second-virial functional for a segmented-chain model. For suspensions of thin and thick fd virus particles we calculate phase diagrams in quantitative agreement with experimental observations, and we find their effective state-point dependent shape to be much shorter and thicker than the actual shape. We also calculate the stretching of worm-like micelles in a host fd virus solution, again finding agreement with experiments. For both systems, our results show that the fd virus stiffness can play a key role in system behavior.

2011-01-01

365

Nuclear Data Sheets for A = 177  

Energy Technology Data Exchange (ETDEWEB)

Evaluated spectroscopic data for all nuclei with mass number A = 177 and corresponding level schemes from radioactive decay and reaction studies are presented. Most of the new information since the previous evaluation of this mass chain consists of the decay of the recently discovered isotope [sup 177]Tm, and the level structure of [sup 177]Ir, [sup 177]Os, and [sup 177]Pt. The present evaluation supersedes the earlier one by Y. A. Ellis and B. Harmatz (75E107) published in Nuclear Data Sheets 16, 135 (1975).

1993-03-01

366

Nuclear Data Sheets for A = 177  

International Nuclear Information System (INIS)

Evaluated spectroscopic data for all nuclei with mass number A = 177 and corresponding level schemes from radioactive decay and reaction studies are presented. Most of the new information since the previous evaluation of this mass chain consists of the decay of the recently discovered isotope "1"7"7Tm, and the level structure of "1"7"7Ir, "1"7"7Os, and "1"7"7Pt. The present evaluation supersedes the earlier one by Y. A. Ellis and B. Harmatz (75E107) published in Nuclear Data Sheets 16, 135 (1975).

367

Nanostructure of thin gold films investigated by means of atomic force microscopy and X-ray reflectometry methods  

International Nuclear Information System (INIS)

A study of the thin gold film growth, during the deposition on glass substrate under UHV conditions at low temperatures, is presented. The complementary methods, the atomic force microscopy and grazing incidence x-ray reflectometry, are used for the research. It is shown that due to variation of the time of deposition from 2 to 50 min different kinds of thin Au films nanostructures are obtained: from discontinuous films consisting of isolated islands, via formation of the chains of islands, up to continuous films. (author)

2001-09-23

368

Mass distribution of fission products in the 28.5 MeV alpha particle induced fission of "2"3"2Th  

International Nuclear Information System (INIS)

Mass distribution in 28.5 MeV alpha particle induced fission of "2"3"2Th has been determined using gamma spectrometric technique. The chain yields of 24 different fission products covering both symmetric and asymmetric mass divisions were determined. The mass distribution was found to be asymmetric with peak positions at mass numbers 96 and 136 respectively while the peak to valley ratio was 3.86. The results are compared with the available literature on 14 MeV neutron induced fission of "2"3"5U. (orig.).

369

Mass distribution of fission products in the 28. 5 MeV alpha particle induced fission of sup 232 Th  

Energy Technology Data Exchange (ETDEWEB)

Mass distribution in 28.5 MeV alpha particle induced fission of {sup 232}Th has been determined using gamma spectrometric technique. The chain yields of 24 different fission products covering both symmetric and asymmetric mass divisions were determined. The mass distribution was found to be asymmetric with peak positions at mass numbers 96 and 136 respectively while the peak to valley ratio was 3.86. The results are compared with the available literature on 14 MeV neutron induced fission of {sup 235}U. (orig.).

1989-01-01

370

Injection and extraction magnets: septa  

CERN Document Server

An accelerator has limited dynamic range: a chain of accelerators is required to reach high energy. A combination of septa and kicker magnets is frequently used to inject and extract beam from each stage. The kicker magnets typically produce rectangular field pulses with fast rise- and/or fall-times, however the field strength is relatively low. To compensate for their relatively low field strength, the kicker magnets are generally combined with electromagnetic septa. The septa provide relatively strong field strength but are either DC or slow pulsed. This paper discusses injection and extraction systems with particular emphasis on the hardware required for the septa.

2010-01-01

371

IAEA Coordinated Research Project: Updated decay data library for actinides  

Energy Technology Data Exchange (ETDEWEB)

Recommended nuclear decay data for specific actinides are important in fuel-cycle studies for thermal and fast reactors and inventory studies for safeguards. Therefore, a programme of work was initiated in 2005 to improve the actinide decay data library of the International Atomic Energy Agency through the efforts of a Coordinated Research Project (CRP). The proposed contents of the new database are described, including the agreement to include additional actinides and a significant number of natural decay chain radionuclides. This work is on-going, and is estimated for completion in 2009/10.

2008-06-15

372

Fractal dimensionality of polymer networks formed by photopolymerization in a liquid crystal medium  

Energy Technology Data Exchange (ETDEWEB)

Fractal dimensional analysis was employed to obtain a quantitative measure of the morphology of polymer networks formed by UV irradiation induced polymerization of photo-reactive mesogenic monomers dissolved in a liquid crystal host medium. The fractal dimensions obtained, may be interpreted by polymer network growth following a percolation-like model for monomer concentrations well below the solubility limit. On passing the solubility limit, the polymerization process changes from a (radical chain) solution polymerization to a dispersion polymerization, with fractal dimensions decreasing and suggesting a cluster-cluster aggregation process for monomer concentrations above the solubility limit, similar to the aggregation of colloidal particles.

2002-10-21

373

Evaluation of the residual radiation field in the proton accelerator facility of the Proton Engineering Frontier Project (PEFP) in Korea  

British Library Electronic Table of Contents (United Kingdom)

In Korea, the Proton Engineering Frontier Project (PEFP) is building a proton linear accelerator facility with energy up to 100MeV and a beam current of 20mA. In this study, a radiation field after shutdown in the accelerator facility of the PEFP was evaluated for the purpose of the radiation shielding by using MCNPX code. A facility modeling was performed for the accelerator tunnel building, accelerator chain, target rooms and beam experiment hall. And radiation source terms were evaluated in the facility. With this facility, model and radiation source terms, the concentration of 41Ar was evaluated and the cooling time satisfying regulation in Korea was calculated.

2007-01-01

374

Entanglement of systems of dipolar coupled nuclear spins at the adiabatic demagnetization  

CERN Document Server

We consider the adiabatic demagnetization in the rotating reference frame (ADRF) of a system of dipolar coupled nuclear spins $s=1/2$ in the external magnetic field. The demagnetization starts with the offset of the external magnetic field (in frequency units) from the Larmor frequency being several times greater than the local dipolar field. For different subsystem sizes, we have found from numerical simulations the temperatures at which subsystems of a one-dimensional nine-spin chain and a plane nine-spin cluster become entangled. These temperatures are of the order of microkelvins and are almost independent of the subsystem size. There is a weak dependence of the temperature on the space dimension of the system.

2008-01-01

375

Emerging logics of competition: paradigm shift, fantasy, or reality check?  

British Library Electronic Table of Contents (United Kingdom)

Purpose - The purpose of this paper is to elicit the subtle but progressive shift in organizational/institutional interaction with its rivals within a competitive framework, and thereby discusses and analyses paradigm shifts in competition and competitiveness. The paper argues that interorganizational networks and the recent concept of supply chain management may have induced a change in how competitiveness is viewed at the national, industry, and firm levels of interaction. Design/methodology/approach - The paper conceptualizes extant literature into distinct themes of (organizational and institutional) analysis - micro, macro, and meso - and based on this review the paper seeks to identify emerging logics and shifts within mainstream competitiveness literature over the last decade. Findi...

2010-01-01

376

Electronic structure of clusters of A-15 compounds with radiation induced defects  

Energy Technology Data Exchange (ETDEWEB)

The electronic structure of the clusters (V/sub 3/Si/sub 4/)/sup 12 -/, (Nb/sub 3/Sn/sub 4/)/sup 12 -/(Mo/sub 3/Ge/sub 4/)/sup 15 -/ in crystalline V/sub 3/Si, Nb/sub 3/Sn, Mo/sub 3/Ge compounds is calculated by the Extended Hueckel method. The influence of different types of radiation induced defects on the density of states at the Fermi level (the anti-site defects, the displacement of atoms in linear chains, the vacancy-interstitial type defects) is considered.

1981-05-01

377

Electronic structure of clusters of A-15 compounds with radiation induced defects  

International Nuclear Information System (INIS)

The electronic structure of the clusters [V_3Si_4]"1"2"-, [Nb_3Sn_4]"1"2"-[Mo_3Ge_4]"1"5"- in crystalline V_3Si, Nb_3Sn, Mo_3Ge compounds is calculated by the Extended Hueckel method. The influence of different types of radiation induced defects on the density of states at the Fermi level (the anti-site defects, the displacement of atoms in linear chains, the vacancy-interstitial type defects) is considered. (author).

378

Current situation of steel industry and coking coal industry and expectations for Canadian coal  

Energy Technology Data Exchange (ETDEWEB)

The world steel industry and market and the current status and prospects for the Japanese steel industry are discussed with particular reference to China, Europe, and the US. Trends in coking coal supply from Australia, Canada, and Mongolia and changes in demand for hard and semi-soft coking coals are considered. Canadian coal plays a significant role in the hard coking coal and PCI coal markets. This is expected to continue. Emerging concerns include the strong Canadian dollar and increases in fuel and materials costs. Canadian suppliers are asked to improve efficiencies, be competitive in the overall coal chain, and diversify their PCI coal reserves. 14 figs.

2006-07-01

379

Collectivity at N=40 in neutron-rich "6"4Cr  

International Nuclear Information System (INIS)

"9Be-induced inelastic scattering of "6"2","6"4","6"6Fe and "6"0","6"2","6"4Cr was performed at intermediate beam energies. Excited states in "6"4Cr were measured for the first time. Energies and population patterns of excited states in these neutron-rich Fe and Cr nuclei are compared and interpreted in the framework of large-scale shell-model calculations in different model spaces. Evidence for increased collectivity and for distinct structural changes between the neighboring Fe and Cr isotopic chains near N=40 is presented.

2010-05-01

380

Collective charge excitation of Sr_1_4_-_xCa_xCu_2_4O_4_1. A fingerprint of novel charge ordered state?  

International Nuclear Information System (INIS)

We review recent progress on experimental studies of collective charge excitations in hole-doped spin ladder system Sr_1_4_-_xCa_xCu_2_4O_4_1, focusing on anomalous features of phase excitation. We also discuss possible candidates for related charge ordered state, together with a controversial issue of the hole density transferred from spin chain layers to spin ladder layers. (author)

2007-04-01

381

A combinatorial spanning tree model for knot Floer homology  

CERN Document Server

We iterate Manolescu's unoriented skein exact triangle in knot Floer homology with coefficients in the fraction field of the group ring (Z/2Z)[Z]. The result is a spectral sequence which converges to a stabilized version of delta-graded knot Floer homology. The (E_2,d_2) page of this spectral sequence is an algorithmically computable chain complex expressed in terms of spanning trees, and we show that there are no higher differentials. This gives the first combinatorial spanning tree model for knot Floer homology.

2011-01-01

382

Natural radiation exposure occurring at handling, storage and disposal of natural radioactive materials; Strahlenbelastung bei Umgang, Lagerung und Abfallhaltung von natuerlicher Radioaktivitaet in Rohstoffen  

Energy Technology Data Exchange (ETDEWEB)

Processing certain raw materials containing natural radioactive isotopes (e.g. U-238, Th-232 or K- 40) into products such as glas, abrasives, grinding materials or electrodes used for gasshielded tungsten-arc welding also leads to certain concentrations of industrial waste containing natural radioactive materials. Such industrial waste does not necessarily contain natural radioactive substances in concentrations exceeding the highest possible levels but nevertheless in significantly measurable quantities. This, however, frequently leads to confusion bordering on irritation by entities processing such substances as well as the general public, since they tend to believe natural radioactive substances in unobjectable concentration to cause similar or identical - health - consequences as man made radioactive substances in detrimental concentration. Radioactive materials may be incorporated intentionally or unintentionally into the product as main or additional ingredients. The recent ...

2009-07-01

383

Natural radiation exposure occurring at handling, storage and disposal of natural radioactive materials  

International Nuclear Information System (INIS)

Processing certain raw materials containing natural radioactive isotopes (e.g. U-238, Th-232 or K- 40) into products such as glas, abrasives, grinding materials or electrodes used for gasshielded tungsten-arc welding also leads to certain concentrations of industrial waste containing natural radioactive materials. Such industrial waste does not necessarily contain natural radioactive substances in concentrations exceeding the highest possible levels but nevertheless in significantly measurable quantities. This, however, frequently leads to confusion bordering on irritation by entities processing such substances as well as the general public, since they tend to believe natural radioactive substances in unobjectable concentration to cause similar or identical - health - consequences as man made radioactive substances in detrimental concentration. Radioactive materials may be incorporated intentionally or unintentionally into the product as main or additional ingredients. The recent ...

2009-09-21

384

Hot atom labeling of myoglobin and hemoglobin and biophysical studies of oxygen and CO binding to carp hemoglobin  

International Nuclear Information System (INIS)

Human Hb, the monomeric Hb of Glycera dibranchiata and horse Mb were modified by replacement of the protoheme with 2,4-dibromodeuteroheme. Following neutron capture by "7"9Br and "8"1Br, the locations of radioactive Br were determined. Although human Hb had approximately four times the mass and volume of the other proteins, about 9% of the activated Br was inserted into each of the three globins. These results suggest that the insertion is short-range (within 15 angstrom) and that this method could be used to label target sites in various proteins and other biological structures. Carp Hb's containing proto-, meso-, deutero- and dibromoheme were prepared. Kinetic and thermodynamic parameters for oxygen and CO binding were determined at Ph 6 (+IHP) (T-state, low-affinity protein) and Ph 9 (R-state, high-affinity protein). Parameters for the binding of oxygen and CO were related to the properties of the four hemes to estimate the inductive and steric factors in the ligation process. The ...

385

Heavy chain of Acanthamoeba myosine IB is a fusion of myosin-like and non-myosin-like sequences  

Energy Technology Data Exchange (ETDEWEB)

Acanthamoeba castellanii myosins IA and IB demonstrate the catalytic properties of a myosin and can support analogues of contractile and motile activity in vitro, but their single, low molecular weight heavy chains, roughly globular shapes, and inabilities to self-assemble into filaments make them structurally atypical myosins. The authors present the complete amino acid sequence of the 128-kDa myosin IB heavy chain, which they deduced from the nucleotide sequence of the gene and which reveals that the polypeptide is a fusion of myosin-like and non-myosin-like sequences. Specifically, the amino-terminal approx. 76 kDa of amino acid sequence is highly similar to the globular head sequences of conventional myosins. By contrast, the remaining approx. 51 kDa of sequence shows no similarity to any portion of conventional myosin sequences, contains regions that are rich in glycine, proline, and alanine residues, and lacks the distinctive sequence ...

1987-10-01

386

Heavy chain of Acanthamoeba myosine IB is a fusion of myosin-like and non-myosin-like sequences  

International Nuclear Information System (INIS)

Acanthamoeba castellanii myosins IA and IB demonstrate the catalytic properties of a myosin and can support analogues of contractile and motile activity in vitro, but their single, low molecular weight heavy chains, roughly globular shapes, and inabilities to self-assemble into filaments make them structurally atypical myosins. The authors present the complete amino acid sequence of the 128-kDa myosin IB heavy chain, which they deduced from the nucleotide sequence of the gene and which reveals that the polypeptide is a fusion of myosin-like and non-myosin-like sequences. Specifically, the amino-terminal #approx# 76 kDa of amino acid sequence is highly similar to the globular head sequences of conventional myosins. By contrast, the remaining #approx# 51 kDa of sequence shows no similarity to any portion of conventional myosin sequences, contains regions that are rich in glycine, proline, and alanine residues, and lacks the distinctive sequence ...

387

Formation of silk fibroin nanoparticles in water-miscible organic solvent and their characterization  

Energy Technology Data Exchange (ETDEWEB)

When Silk fibre derived from Bombyx mori, a native biopolymer, was dissolved in highly concentrated neutral salts such as CaCl{sub 2}, the regenerated liquid silk, a gradually degraded peptide mixture of silk fibroin, could be obtained. The silk fibroin nanoparticles were prepared rapidly from the liquid silk by using water-miscible protonic and polar aprotonic organic solvents. The nanoparticles are insoluble but well dispersed and stable in aqueous solution and are globular particles with a range of 35-125 nm in diameter by means of TEM, SEM, AFM and laser sizer. Over one half of the {epsilon}-amino groups exist around the protein nanoparticles by using a trinitrobenzenesulfonic acid (TNBS) method. Raman spectra shows the tyrosine residues on the surface of the globules are more exposed than those on native silk fibers. The crystalline polymorph and conformation transition of the silk nanoparticles from random-coil and {alpha}-helix form (Silk I) into anti-parallel {beta}-sheet form ...

2007-10-15

388

Electron-beam induced RAFT-graft polymerization of poly(acrylic acid) onto PVDF  

Energy Technology Data Exchange (ETDEWEB)

This paper explores for the first time the post-radiation-induced-graft polymerization on solid substrate using reversible addition-fragmentation transfer (RAFT) mechanism. Radiation-induced graft polymerization onto polymers is a potentially interesting technique to create easily new materials from highly resistant polymers, e.g. surface graft polymerization of acrylic acid (AA) onto poly(vinylidene difluoride) (PVDF) improves its surface properties without losing its excellent mechanical properties. As a consequence of the radical nature of the polymerization processes it is difficult to control molecular weight of grafted chains, and therefore design and standardize the properties of the final product. RAFT polymerization is a suitable method to obtain monodisperse polymers. The ability of the RAFT agents to control the polymer chain length could be an interesting approach to improve the grafted polymers obtained by ...

2005-07-01

389

Development of wood fuel delivery logistics; Puupolttoaineiden hankintalogistiikan kehittaeminen  

Energy Technology Data Exchange (ETDEWEB)

The main aim of the project is to model the energy wood business and total logistics in a certain large region. First, wood utilisation locations inside this area are examined; the most important ones are the wood processing factories, and the heating- and power plants. After that, wood potentials in the forests of the area are evaluated in sub-areas suitable in size and sufficiently detailed for further evaluations. For that purpose, the most valuable source data are forest management plans, up to ten years forward, on which basis the wood fuel potentials can be evaluated following sustainable development. In Finland there are extensive and detailed data bases storing forest information and it is possible to collect necessary data for a data base applicable to our calculations. In logistical sense it is important to know, by which delivery chains the economically best and desired results are achieved. The software prototype based on data base is modelled and ...

1996-12-31

390

Wind tunnel tests of biodegradable fugitive dust suppressants being considered to reduce soil erosion by wind at radioactive waste construction sites  

International Nuclear Information System (INIS)

Wind tunnel tests were performed of three fugitive dust control agents derived from potato and sugar beet products. These materials are being considered for use as dust suppressants to reduce the potential for transport of radioactive materials by wind from radioactive waste construction and remediation sites. Soil and dust control agent type, solution concentrations, application quantities, aging (or drying) conditions, surface disturbance, and wind and saltating sand eolian erosive stresses were selected and controlled to simulate application and exposure of excavated soil surfaces in the field. A description of the tests, results, conclusions, and recommendations are presented in this report. The results of this study indicate that all three dust control agents can protect exposed soil surfaces from extreme eolian stresses. It is also clear that the interaction and performance of each agent with various soil types may differ dramatically. Thus, soils similar to ...

1993-01-01

391

Total interaction cross sections and effective atomic numbers of some biologically important compounds containing H, C, N and O in the energy range 6.4-136 keV  

International Nuclear Information System (INIS)

The total interaction cross sections (#sigma#_t) of some sugars and amino acids and five elements: lithium, carbon, oxygen, aluminium and calcium have been measured for 6.4 keV, 13.95 keV, 14.4 keV, 17.74 keV, 24.14 keV, 30.8 keV, 35 keV, 59.54 keV, 81 keV, 122 keV and 136 keV photons in a narrow beam good geometry set up, by using high resolution detectors such as a Si-PIN diode detector and a high purity germanium detector. The #sigma#_t values have been used in a matrix method to evaluate the effective atomic numbers Z_e_f_f of the samples from their effective atomic cross sections #sigma#_a. The effective atomic cross section of a sample #sigma#_a is the total interaction cross section divided by the total number of atoms of all types in it. Further, a quantity called the effective atomic weight A_e_f_f of a sample was defined as the ratio of the molecular weight A to the total number of atoms of all types in it. The variation of Z_e_f_f was systematically ...

2007-09-28

392

The weak force and SETH: The search for Extra-Terrestrial Homochirality  

Energy Technology Data Exchange (ETDEWEB)

We propose that a search for extra-terrestrial life can be approached as a Search for Extra-Terrestrial Homochirality{emdash}SETH. Homochirality is probably a pre-condition for life, so a chiral influence may be required to get life started. We explain how the weak force mediated by the {ital Z}{sup 0} boson gives rise to a small parity-violating energy difference (PVED) between enantiomers, and discuss how the resulting small excess of the more stable enantiomer may be amplified to homochirality. Titan and comets are good places to test for emerging pre-biotic homochirality, while on Mars there may be traces of homochirality as a relic of extinct life. Our calculations of the PVED show that the natural L-amino acids are indeed more stable than their enantiomers, as are several key D-sugars and right-hand helical DNA. Thiosubstituted DNA analogues show particularly large PVEDs. L-quartz is also more stable than D-quartz, and we believe that further crystal counts ...

1996-07-01

393

The effects of climatic change on crop production. Results of a five-year research project  

Energy Technology Data Exchange (ETDEWEB)

The aim of this research project, funded jointly by SILMU and by the Agricultural Research Centre of Finland, was to evaluate the possible effects of changes in climate and carbon dioxide concentration on the growth, development and yield of field crops and on crop pests and diseases in Finland. The study focused on two cereal crops (spring wheat and spring barley), a grass species (meadow fescue), some common pathogens of cereals and potato, insect pests of small fruits and nematode risk of potato and sugar beet. The results of this study indicate the following effects on crop production of the `best guess` climate change anticipated for Finland by 2050: A lengthening of the potential growing season of 3-5 weeks. A northward expansion of about 250-500 km in suitability for cereal production. Increased yields of adapted spring cereals. New, longer-season cultivars would benefit from both higher temperatures and elevated CO{sub 2}. Improved potential for the ...

1996-12-31

394

Survey report for fiscal 1998. Survey of the current state and tasks of research and development of technologies for effectively utilizing CO{sub 2} fixation by higher vegetation; 1998 nendo chosa hokokusho. Koto shokubutsu ni okeru nisanka tanso koteika yuko riyo gijutsu no kenkyu kaihatsu no genjo to kadai ni kansuru chosa  

Energy Technology Data Exchange (ETDEWEB)

Investigations and studies are conducted seeking for a CO2 fixation method improved by utilizing the photosynthesizing function of higher vegetation. Details of higher vegetation genes are being disclosed thanks to the rapid progress of studies making use of molecular biological techniques, and the application of the genetic mechanism to scientific and technological fields is becoming increasingly feasible. In particular, the role of the CO2 fixation enzyme RuBisCO has been elucidated almost completely. It has been learned that, in terms of photosynthesizing capability, the C{sub 4} plants (corn etc.) are 2-3 times higher than the C{sub 3} plants (rice, wheat, etc.), and 5-10 times higher than the CAM plants (cactuses etc.). Studies are also under way about the rice genome so that a photosynthesizing capability so high as that of the C{sub 4} plants may be endowed the rice plant. The metabolism and control of useful substances produced in the CO2 fixation process etc. in the higher ...

1999-03-01

395

Response of photosynthesis, starch and sucrose synthesis to increased CO sub 2 and lowered O sub 2  

Energy Technology Data Exchange (ETDEWEB)

Increasing photosynthesis rate by raising CO{sub 2} and lowering O{sub 2} usually results in measured rates lower than those expected from the kinetics of rubisco. The failure of leaves to utilize the increased efficiency of rubisco has been attributed to limitations in rates of either starch or sucrose synthesis, which lead to a lowering of Pi and a reduction in the rate of ATP synthesis. In sugar beet leaves, increasing CO{sub 2} from 350 to 600 {mu}L L{sup {minus}1} usually increased photosynthesis only about 10%, compared to the 45% expected, and lowering O{sub 2} from 2 to 21% increased photosynthesis only an additional 20%, compared to the additional 40% expected. In some cases, raising CO{sub 2} increased photosynthesis the full 30% with no further increase occurring upon lowering O{sub 2}. In all cases, rates of starch and sucrose synthesis consistently increased in proportion to increasing photosynthesis rate. Metabolites that are predominantly cytosolic ...

1990-05-01

396

Regulation of sucrose synthesis in water stressed leaves  

Energy Technology Data Exchange (ETDEWEB)

Alteration in carbon metabolism and carbohydrate partitioning occur in drought stressed plants. Some species accumulate large quantities of starch in the chloroplast, which may be used to support sucrose synthesis under conditions of limited carbon supply. The authors monitored chemical partitioning of carbon between sugars and starch and the activity of sucrose phosphate synthase (SPS) and fructose 1,6 bisphosphatase (FBPase) in the source leaves of water stressed tomatoes. Plants were stressed by withdrawing water for 10 days and rewatered for recovery. Water potential dropped from {minus}0.8 to {minus}2.2MPA in 10 days, but recovered to control level 2 days after rewatering. Photosynthetic rates as measured by the activity of Rubisco followed similar patterns to those of water potential. After 10 days, leaf starch levels decreased to less than 50% of control. Sucrose levels did not increase significantly, but hexose levels increased 3-4 fold during the stress ...

1991-05-01

397

Projected change in climate thresholds in the Northeastern U.S.: implications for crops, pests, livestock, and farmers  

Energy Technology Data Exchange (ETDEWEB)

Most prior climate change assessments for U.S. agriculture have focused on major world food crops such as wheat and maize. While useful from a national and global perspective, these results are not particularly relevant to the Northeastern U.S. agriculture economy, which is dominated by dairy milk production, and high-value horticultural crops such as apples (Malus domestica), grapes (vitis vinifera), sweet corn (Zea mays var. rugosa), cabbage (Brassica oleracea var. capitata), and maple syrup (sugar maple, Acer saccharum). We used statistically downscaled climate projections generated by the HadCM3 atmosphere-ocean general circulation model, run with Intergovernmental Panel on Climate Change future emissions scenarios Alfi (higher) and B1 (lower), to evaluate several climate thresholds of direct relevance to agriculture in the region. A longer (frostfree) growing season could create new opportunities for farmers with enough capital to take risks on new crops ...

2008-07-01

398

Pre-treatment and ethanol fermentation potential of olive pulp at different dry matter concentrations  

Energy Technology Data Exchange (ETDEWEB)

Renewable energy sources have received increased interest from the international community with biomass being one of the oldest and the most promising ones. In the concept of exploitation of agro-industrial residues, the present study investigates the pre-treatment and ethanol fermentation potential of the olive pulp, which is the semi solid residue generated from the two-phase processing of the olives for olive oil production. Wet oxidation and enzymatic hydrolysis have been applied aiming at the enhancement of carbohydrates' bioavailability. Different concentrations of enzymes and enzymatic durations have been tested. Both wet oxidation and enzymic treatment were evaluated based on the ethanol obtained in a subsequent fermentation step by Saccharomyces cerevisiae and Thermoanaerobacter mathranii. It was found that a four-day hydrolysis time was adequate for a satisfactory release of glucose and xylose. The combination of wet oxidation and enzymatic hydrolysis resulted in the ...

2009-11-15

399

Isotope aided studies of the bioavailability of iron from human diets consumed in Peru  

International Nuclear Information System (INIS)

Iron deficiency anaemia is an important health problem in Peru, which affects approximately 25% of the population. The most vulnerable groups are children below 5 years of age and pregnant women, of whom 64% and 53% respectively are anemic. The main reason for this deficiency is inadequate iron intake. Heme iron consumption is very low, and non-heme iron is virtually the only source of iron in the diet. Despite regional differences in food consumption, wheat, salt and sugar are widely consumed in all areas. Wheat is likely to be the most suitable food vehicle for iron fortification due to the processing required. Based on the recent food consumption surveys conducted in Lima by the IIN, we selected examples of typical main meals and measured iron bioavailability in the diet using an extrinsic tag method with 1.5 #mu#Ci of "5"9Fe and 5 #mu#Ci of "5"5Fe as markers. Coffee with bread and butter for breakfast, noodle soup with vegetables, rice with seasoned tripe ...

1992-11-16

400

Isolation and characterization of a novel lectin from the mushroom Armillaria luteo-virens  

Science.gov (United States)

From the dried fruiting bodies of the mushroom Armillaria luteo-virens, a dimeric lectin with a molecular mass of 29.4 kDa has been isolated. The purification procedure involved (NH{sub 4}){sub 2}SO{sub 4} precipitation, ion exchange chromatography on DEAE-cellulose, CM-cellulose, and Q-Sepharose, and gel filtration by fast protein liquid chromatography on Superdex 75. The hemagglutinating activity of the lectin could not be inhibited by simple sugars but was inhibited by the polysaccharide inulin. The activity was stable up to 70 {sup o}C but was acid- and alkali-labile. Salts including FeCl{sub 3}, AlCl{sub 3}, and ZnCl{sub 2} inhibited the activity whereas MgCl{sub 2}, MnCl{sub 2}, and CaCl{sub 2} did not. The lectin stimulated mitogenic response of mouse splenocytes with the maximal response achieved by 1 {mu}M lectin. Proliferation of tumor cells including MBL2 cells, HeLa cells, and L1210 cells was inhibited by the lectin with an IC{sub 5} of 2.5, 5, and 10 ...

2006-07-14

401

Green chemistry at work  

Energy Technology Data Exchange (ETDEWEB)

The 1.7 billion pounds of benzene produced each year in the US provide one measure of its utility. At the same time, there are a number of environmental reasons for avoiding the use of benzene in chemical manufacture. Perhaps most compelling: benzene is a potent carcinogen. Scrutiny of many of the chemicals derived from benzene reveals that each molecule contains at least one oxygen atom while benzene completely lacks oxygen atoms. Introduction of oxygen to make up for this lack can require processes that are environmentally problematic. One of the steps used to introduce oxygen atoms during manufacture of adipic acid, a component of Nylon 66, is responsible for 10% of the annual global increase in atmospheric nitrous oxide. This by-product is a causative agent of atmospheric ozone depletion and has been implicated in global warming. With support from EPA and the National Science Foundation, alternative manufacturing processes are being explored. By these new methods, chemicals usually ...

1994-12-31

402

Ethanol production and a case study of ethanol produced from sweet sorghum stalks via solid state fermentation  

Energy Technology Data Exchange (ETDEWEB)

Ethanol has excellent fuel properties, such as high octane, high heat of vaporization and low photochemical reactivity in the atmosphere. It is less volatile than gasoline and there is lower smog formation from evaporative emissions of pure ethanol compared to gasoline. As such, ethanol has emerged as an important alternative energy source that is sustainable, efficient, cost effective, convenient and safe. In 2006, global production of ethanol reached 13.5 billion gallons, up from 12.1 billion gallons in 2005. However, in light of the current debate of food versus fuel, the industry must shift to non-food feedstocks. This paper described an emerging technology to cost-effectively produce ethanol from sweet sorghum stalks, the most promising alternative feedstock to corn, via solid state fermentation (SSF). Experiments of advanced solid state fermentation (ASSF) for ethanol production from sweet sorghum by Saccharomyces cerevisiae were conducted in laboratory and pilot scales studies. ...

2008-07-01

403

Effect of safe environmental pre and post harvest treatments and irradiation on handling of some fruits  

International Nuclear Information System (INIS)

The present study was carried out during two successive seasons of 2005 and 2006 seasons on"Montakhab El-Kanater"guavas and"Hachiya"persimmons.two different experiments were studied, the first one for pre harvest and second post harvest. Regarding pre harvest experiment,hand or chemical flower thinning by urea or ethrel and date of fruit picking (maturity) were evaluated on both guavas and persimmons.All flower thinning treatments increased fruit set,total yield,average fruit weight and decreased fruit abscission.However,a great effect on fruit quality and chemical compositions were also found with flower thinning treatments. Chemical flower thinning was more effective than hand thinning in improving yield and quality in "Montakhab El-Kanater"guavas and "Hachiya"persimmons. However,early maturation(120 and 150 days for guava and persimmon respect.) produced poor fruit quality.Whereas, medium maturity(130 and 180 days for guava and persimmon respect.) produced fruit with high ...

404

Effect of phlorizin on sugar uptake by broadbean leaf discs. [Vica faba L  

Energy Technology Data Exchange (ETDEWEB)

Phlorizin is a competitive inhibitor of Na/sup +//glucose symport in animal cells and of H/sup +//3-O-methylglucose (3-O-MeG) symport in liverworts. The effects of this compound on the uptake of (U-/sup 14/C) sucrose and of (/sup 14/C) 3-O-MeG by broadbean (Vicia faba L.) leaf discs were studied. Leaf discs without lower epidermis were preincubated in the dark for 30 min (fresh discs) or for 12 h (aged discs) on a medium buffered at pH 5.0 containing mannitol as an osmoticum. They were then incubated for 30 min in the light on a similar solution added with 1 mM (/sup 14/C) sucrose or (/sup 14/C) 3-O-MeG and 5 mM phlorizin. Phlorizin inhibited uptake of 3-O-MeG by 37 and 50% respectively in fresh and aged discs. Sucrose uptake was more sensitive to the inhibitor than 3-O-MeG uptake and was also more inhibited in aged than in fresh discs (76% inhibition vs 54%). Kinetic studies showed that the inhibition exerted by phlorizin in fresh material is of competitive type both for sucrose and ...

1986-04-01

405

Digitonin abolishes free 2-deoxy-D-glucose accumulation in isolated rat adipocytes  

Energy Technology Data Exchange (ETDEWEB)

The hypothesis that accumulation against sizable chemical gradients of free (non-phosphorylated) 2-deoxy-D-glucose (2dGlc) in isolated rat adipocytes results from an intracellular compartmentation of free hexose was investigated. Cells exposed to 20 ..mu..g/ml digitonin for 10' demonstrated an increased plasma membrane permeability indexed by increased L-glucose entry rates and cellular (presumably cytosolic) protein and K/sup +/ loss. Functional integrity of intracellular organelles was indicated by the ability of the cells to support ATP-driven /sup 45/Ca/sup 2 +/-uptake. Equilibrium 3-O-methylglucose (3-O-MG, a non-accumulated hexose) levels were unaffected. These data suggest a specific permeabilizing action of digitonin at the plasma membrane having no effect on intracellular organelles or passively distributed solutes. Upon addition of digitonin, free 2dGlc fell from 66.5 +/- 8.9 to 7.4 +/- 2.3 pmol/10/sup 5/ cells, a value not significantly different from 3-O-MG levels. ...

1986-03-05

406

Cucumber nitrogen utilization as affected by compost levels and nitrogen rates using "1"5N technique  

International Nuclear Information System (INIS)

The beneficial effect of compost application to the sandy soil on dry matter production of shoots and fruits as well as its effect on l5N-uptake and nitrogen utilization percent of cucumber plant (Cucumis sativus L.) were studied under field conditions. Two types of natural compost (i.e. sugar cane bagasse (SC) and beet compost (BC)) with three levels (2, 4, 6 ton/fed) in addition to check treatment for each kind of compost (sheep manure with rate of 20 in/fed) combined with three rates of nitrogen fertilizer rates (50, 75, 100% from the recommended rate, i.e. 75 kg /fed) were used. The bagasse compost in both seasons gave a significantly higher response than the beet compost. There was a greet reduction in cucumber dry weight, N yield, Ndff%, FN yield and N utilization % of shoots and fruits as the level of compost application decreased. However, cucumber plants grown on high compost application level (6 ton/fed) were similar in their responses to plants grown on ...

407

Characterization of hyaluronate binding proteins isolated from 3T3 and murine sarcoma virus transformed 3T3 cells  

Energy Technology Data Exchange (ETDEWEB)

A hyaluronic acid binding fraction was purified from the supernatant media of both 3T3 and murine sarcoma virus (MSV) transformed 3T3 cultures by hyaluronate and immunoaffinity chromatography. Sodium dodecyl sulfate-polyacrylamide gel electrophoresis resolved the hyaluronate affinity-purified fraction into three major protein bands of estimated molecular weight (M/sub r,e/) 70K, 66K, and 56K which contained hyaluronate binding activity and which were termed hyaluronate binding proteins (HABP). Hyaluronate affinity chromatography combined with immunoaffinity chromatography, using antibody directed against the larger HABP, allowed a 20-fold purification of HABP. Fractions isolated from 3T3 supernatant medium also contained additional binding molecules in the molecular weight range of 20K. This material was present in vanishingly small amounts and was not detected with a silver stain or with (/sup 35/S)methionine label. The three protein species isolated by hyaluronate affinity ...

1987-06-02

408

Changes in soil N fractions and utilization of recently immobilized fertilizer N by wheat as influenced by application of some organic chemicals in rice-wheat sequence  

International Nuclear Information System (INIS)

Effect of two organic chemicals viz., 2,4-dinitrophenyl hydrazone (C_1) and naphthyl ethylene diamine (C_2) was studied by their application alone and together (Csub(1+2) at the rate of 10 ppm by growing wheat on a loamy soil (Typic ustochrept) containing recently immobilized fertilizes N of "1"5N - urea applied at 60, 120 and 180 ppm N to preceding rice under greenhouse conditions of a rice-wheat sequence. The application of C_1 and C_2 alone; and their combined application (Csub(1+2) produced 12, 15 and 18 per cent higher wheat grain yield over no-chemical application i.e. Co (3.50 g/pot). The chemicals also showed their beneficial effect on utilization of recently immobilized fertilizer N, as was evidenced by significantly higher "1"5N recovery values in wheat with C_1, C_2 and Csub(1+2)(2.84, 3.63 and 3.54 per cent, respectively) than that of Co (2.29 per cent). The soil N fractions were affected by chemical application during wheat as total hydrolyzable N, hydrolyzable ...

409

Assimilation of /sup 14/CO/sub 2/ and /sup 14/C sucrose by citrus fruit tissues  

Energy Technology Data Exchange (ETDEWEB)

Assimilation and metabolism of /sup 14/CO/sub 2/ was compared to that of (U-/sup 14/C) sucrose in young grapefruit (ca 25 mm diameter) to determine their respective roles in fruit growth. Fixation of /sup 14/CO/sub 2/ by isolated fruit tissues during 10 min in light exceeded that in dark by 2- to 30-fold depending on tissue content of chlorophyll. Greatest apparent photosynthesis occurred in outer green peel, but green juice tissues assimilated more than did adjoining inner peel tissue. In the dark, juice tissues incorporated 2.5-fold more /sup 14/CO/sub 2/ than any other tissue. Neutral sugars accounted for a smaller proportion and organic acids, a greater proportion, of the /sup 14/C-assimilates in interior peel and juice tissues. These data suggest more extensive production of organic acids from /sup 14/CO/sub 2/ in tissues isolated from the fruit interior. In contrast, little difference among tissues was evident in extent of organic- and amino-acid production ...

1987-04-01

410

Agricultural ecosystem modelling. The basis for assessing the impact of possible land-use and climate changes. Final report; Agrooekosystemmodellierung. Grundlage fuer die Abschaetzung von Auswirkungen moeglicher Landnutzungs- und Klimaaenderungen. Abschlussbericht  

Energy Technology Data Exchange (ETDEWEB)

This report presents the results of the BMBF-sponsored project Fundamentals and models for assessing the effect of climate changes on soil, plant development and the crops of an economically significant range of farm products. Its aim was to study, by means of the results obtained for winter wheat, the dependence of plant growth on temperature, radiation and water as well as nutrient supply for other economically important crop types. Building on this, process-oriented, climate-sensitive agricultural ecosystem models for winter rye, winter barley, sugar-beet and winter intercrops were developed, verified and, in some sites, validated. First scenario calculations served to demonstrate the climate sensitivity of these models. (orig./KW) [Deutsch] Im vorliegenden Bericht werden die Ergebnisse des BMBF - Vorhabens `Grundlagen und Modelle zur Abschaetzung von Klimaaenderungen auf den Boden, die Pflanzenentwicklung sowie den verwertbaren Ernteertrag einer wirtschaftlich ...

1995-12-31

411

Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB5O9  

International Nuclear Information System (INIS)

A novel sodium lead pentaborate, NaPbB5O9, has been successfully synthesized by standard solid-state reaction. The single-crystal X-ray structural analysis showed that NaPbB5O9 crystallizes in the monoclinic space group P21/c with a=6.5324(10) A, b=13.0234(2) A, c=8.5838(10) A, ?=104.971(10)o, and Z=4. The crystal structure is composed of double ring [B5O9]3- units, [PbO7] and [NaO7] polyhedra. [B5O9]3- groups connect with each other forming two-dimensional infinite ?[B5O9]3- layers, while [PbO7] and [NaO7] polyhedra are located between the layers. [PbO7] polyhedra linked together via corner-sharing O atom forming novel infinite ?[PbO6] chains along the c axis. The thermal behavior, IR spectrum and the optical diffuse reflectance spectrum of NaPbB5O9 were reported. -- Graphical abstract: A new phase, NaPbB5O9, has been discovered in the ternary M2O-PbO-B2O3 (M=alkali-metal) system. The crystal structure consists of a novel infinite ?[PbO6] ...

2011-04-01

412

Phase diagram of SrO-InO1.5-CoOx and a new compound Sr3In0.9Co1.1O6  

International Nuclear Information System (INIS)

Sr3In0.9Co1.1O6, isostructural to Ca3Co2O6, is revealed by the study of the phase relations in the system SrO-InO1.5-CoOx (1000 oC). The structure of Sr3In0.9Co1.1O6 is refined by the combination of powder X-ray and neutron diffraction. Sr3In0.9Co1.1O6 crystallizes in a trigonal lattice with the cell parameters a=b=9.59438(3) A, c=11.02172(4) A with the space group R-3c. Its structure possesses 1D (In/Co)O3 chains running along the c-axis constructed by alternating face-sharing CoO6 octahedra and (In0.9Co0.1)O6 trigonal prisms. The co-occupation of In3+ and Co3+ at the trigonal prismatic site is evidenced by elementary analysis and determined by the structure refinement. Sr3In0.9Co1.1O6 is paramagnetic, and the susceptibility is consistent with the occupation of Co3+ at 10% of the trigonal prismatic positions in a high spin state (HS, S=2). The HS Co3+ is well separated by diamagnetic CoO6 octahedra and InO6 trigonal prisms and shows a g factor of 2.0 in the ...

2011-04-01

413

Varying-G Cosmology with Type Ia Supernovae  

CERN Document Server

The observation that Type Ia supernovae are fainter than expected given their red shifts has led to the conclusion that the expansion of the universe is accelerating. The widely accepted hypothesis is that this acceleration is caused by a cosmological constant or, more generally, some dark energy field that pervades the universe. This hypothesis presents a challenge to physics so severe that one is motivated to explore alternative explanations. In this paper, we explore whether the data from Type Ia supernovae can be explained with an idea that is almost as old as that of the cosmological constant, namely, that the strength of gravity varies on a cosmic timescale. This topic is an ideal one for investigation by an undergraduate physics major because the entire chain of reasoning from models to data analysis is well within the mathematical and conceptual sophistication of a motivated undergraduate.

2009-01-01

414

Thermal neutron capture gamma-rays  

Energy Technology Data Exchange (ETDEWEB)

The energy and intensity of gamma rays as seen in thermal neutron capture are presented. Only those (n,..cap alpha..), E = thermal, reactions for which the residual nucleus mass number is greater than or equal to 45 are included. These correspond to evaluations published in Nuclear Data Sheets. The publication source data are contained in the Evaluated Nuclear Structure Data File (ENSDF). The data presented here do not involve any additional evaluation. Appendix I lists all the residual nuclides for which the data are included here. Appendix II gives a cumulated index to A-chain evaluations including the year of publication. The capture gamma ray data are given in two tables - the Table 1 is the list of all gamma rays seen in (n,..gamma..) reaction given in the order of increasing energy; the Table II lists the gamma rays according to the nuclide.

1983-01-01

415

The anti-snake venom properties of Tamarindus indica (leguminosae) seed extract  

British Library Electronic Table of Contents (United Kingdom)

In Indian traditional medicine, various plants have been used widely as a remedy for treating snakebites. The aim of this study was to evaluate the effect of Tamarindus indica seed extract on the pharmacological as well as the enzymatic effects induced by V. russelli venom. Tamarind seed extract inhibited the PLA2, protease, hyaluronidase, L-amino acid oxidase and 5prime-nucleotidase enzyme activities of venom in a dose-dependent manner. These are the major hydrolytic enzymes responsible for the early effects of envenomation, such as local tissue damage, inflammation and hypotension. Furthermore, the extract neutralized the degradation of the Bb chain of human fibrinogen and indirect hemolysis caused by venom. It was also observed that the extract exerted a moderate effect on the clotting ...

2006-01-01

416

Synthesis of reversible fluorescent organogel containing 2-(2prime-hydroxyphenyl)benzoxazole: fluorescence enhancement upon gelation and detecting property for nerve gas simulant  

British Library Electronic Table of Contents (United Kingdom)

A new low molecular mass organogelator 1 containing 2-(2prime-hydroxyphenyl)benzoxazole (HPB) group with long alkyl chain was synthesized by the reaction with 5-amino-2-(2prime-hydroxy-4prime-methylphenyl)benzoxazole and dodecyl isocyanate in THF at room temperature. The reversible gelation ability of 1 was investigated using a heating-cooling method in various organic solvents. The stable organogel was formed from carbon tetrachloride or from cyclohexane at the concentration as low as 0.9%. The self-assembled supramolecular gel structure formed by non-covalent bonding was confirmed with field emission-scanning electron microscope (FE-SEM) exhibiting fibril- or ribbon-shaped structure depending on the solvent used. Regarding the aggregation-induced emission enhancement (AIEE) phenomenon, t...

2010-01-01

417

Synthesis by plasma and characterization of semiconductor compounds derived of polyacetylene; Sintesis por plasma y caracterizacion de compuestos semiconductores derivados del poliacetileno  

Energy Technology Data Exchange (ETDEWEB)

In this work it is made a study of the structure and electric properties of chlorate polyethylene (PE-CI) with double and simple bonds obtained by continuous plasma with resistive coupling to 13.5 MHz. The synthesis conditions are power between 10 and 14 W and pressure of (6-7) x 10{sup -2} Torr. The synthesized PE-Cl in that way is soluble in acetone what indicates that probably is formed of short chains and not it shows the generalized inter crossing that is presented in some syntheses by plasma and that it can degrade the electric properties of these polymers. The IR and XPS analysis show the vibration of the C-C, C=C and C-CI bonds. The morphology of the polymer after being dissolved shows a compact and flat configuration. The electric conductivity has an approximately lineal behavior in an interval of 35 to 90% of relative humidity. (Author)

2003-07-01

418

Synthesis and properties of macromer-grafted polymers for noncovalent functionalization of multiwalled carbon nanotubes  

British Library Electronic Table of Contents (United Kingdom)

We prepared macromer-grafted polymers (MGPs) containing suitable polymer side chains for improving solubility and pyrene units for improving adsorption on multiwalled carbon nanotube (MWCNT) surfaces, and demonstrated that these MGPs act as MWCNT solubilizers that improve solubility of MWCNTs in typically poor solvents such as alkanes and that improve flowability of polymer/MWCNT composites. The polydimethylsiloxane (PDMS)-MGPs, synthesized using PDMS macromers and pyrene-containing monomers, improved solubility of MWCNTs not only in chloroform but also in hexane, which is a poor solvent for MWCNTs. Moreover, the addition of PDMS-MGP-adsorbed MWCNTs (MWCNT/PDMS-MGPs) to epoxy resin monomers or polybutylene terephthalate (PBT) drastically reduced the viscosity of the obtained epoxy resin mo...

2009-01-01

419

Synthesis and investigation of #pi#-conjugated azomethine self-assembled multilayers by layer-by-layer growth  

International Nuclear Information System (INIS)

Layer-by-layer formation for #pi#-conjugated azomethine multilayers bonded on substrates was investigated. The multilayers were synthesized using ethanol (EtOH) and dichloromethane (DCM) as reaction solvents. The multilayer characteristics were analyzed using UV-vis absorption spectroscopy, ellipsometric thickness, and atomic force microscopy. The absorption spectra and ellipsometric thicknesses of multilayers formed using EtOH and DCM were compared. The results indicate that EtOH is more suitable than DCM for such layer-by-layer formation. In addition, bandgaps estimated from the absorption edge of multilayers were investigated. The results indicate that the bandgap decreases as the number of benzene rings contained in the molecular chain of the multilayer increases. Also, a multilayer with four benzene rings bonded on a substrate had a bandgap close to that of a polymer with a similar chemical structure.

2010-07-01

420

Survey of the marine benthic infauna collected from the United States radioactive waste disposal sites off the Farallon Islands, California. Final report  

International Nuclear Information System (INIS)

Benthic biological samples were taken in 1977 from the vicinity of the Farallon Islands radioactive waste disposal sites for characterization of the infaunal macroinvertebrates and foraminifera. A total of 120 invertebrate species were collected, of which 75 species (63 percent) were polychaetes. Forty-three of these polychaete species have not previously been reported from depths greater than 1000m. A total of 1044 macroinvertebrate specimens were collected of which 54 percent were polychates. Only the nematods were present at all six benthic stations, but the community structure was dominated by the polychaetes Tauberia gracilis, Allia pulchra, Chaetozone setosa, and Cossura candida. Living and dead foraminifera were reported. The possible role of polychaetes in bioturbation and in the marine food chain is briefly discussed with respect to the various polychaete feeding mechanisms.

421

Subspace estimation and prediction methods for hidden Markov models  

CERN Document Server

Hidden Markov models (HMMs) are probabilistic functions of finite Markov chains, or, put in other words, state space models with finite state space. In this paper we examine subspace estimation methods for HMMs whose output lies a finite set as well. In particular we study the geometric structure arising from the non-minimality of the linear state space representation of HMMs, and consistency of a subspace algorithm arising from a certain factorisation of the singular value decomposition of the estimated linear prediction matrix. For this algorithm we show that the estimates of the transition and emission probability matrices are consistent up to a similarity transformation, and that the m-step linear predictor computed from the estimated system matrices is consistent, i.e. converges to the true optimal linear m-step predictor.

2009-01-01

422

Strategy and development means of the energy efficiency and renewable energies sources in France; Strategie et moyens de developpement de l'efficacite energetique et des sources d'energies renouvelables en France  

Energy Technology Data Exchange (ETDEWEB)

In the framework of the renewable energies development policy and the energy mastership wanted by the Government, a document has been asked by the Prime Minister. It evaluates the development prospects at long and medium dated, of the main chains of renewable energies production taking into account the national developable deposits size, the technologies assessment, the environmental impacts and the competition facing the traditional energies. It evaluates the measures leading to an increasing efficiency. Measures concerning the regulations, the budget, and the fiscality are also discussed. From these analysis, a national strategy for actions in favor the renewable energies, are proposed. (A.L.B.)

2000-09-01

423

Sterically stabilized water based magnetic fluids: Synthesis, structure and properties  

Energy Technology Data Exchange (ETDEWEB)

Magnetic fluids (MFs), prepared by chemical co-precipitation followed by double layer steric and electrostatic (combined) stabilization of magnetite nanoparticles dispersed in water, are presented. Several combinations of surfactants with different chain lengths (lauric acid (LA), myristic acid (MA), oleic acid (OA) and dodecyl-benzene-sulphonic acid (DBS)) were used, such as LA+LA, MA+MA, LA+DBS, MA+DBS, OA+DBS, OA+OA and DBS+DBS. Static light scattering, transmission electron microscopy, small angle neutron scattering, magnetic and magneto-rheological measurements revealed that MFs with MA+MA or LA+LA biocompatible double layer covered magnetite nanoparticles are the most stable colloidal systems among the investigated samples, and thus suitable for biomedical applications.

2007-04-15

424

Spectral investigation of primary uranyl orthophosphate  

International Nuclear Information System (INIS)

By methods of vibrational (infrared, Raman) and PMR spectroscopy, crystallohydrate forms of monosubstituted uranyl orthophosphate have been examined. The vibrational frequencies of the groupings from the compounds were identified. The existence of non-equivalent H_2PO_4"--groups in the substances under investigation was ascertained. It has been suggested that one of them is a bridged group, and the other is the end group. A fragment of the VO_2(H_2PO_4)_2 hydrate structure is given, its main constituents being uranylphosphate chains. The analysis of water vibrations assumes coordination of one mole of H_2O in VO_2(H_2PO_4)_2:3H_2O to uranium, while two other molecules are only hydrogen-bonded with phosphate anions. Absorption within the region of 2100-2550 cm"-"1 is assigned to vibrations of O...H...O groupings.

425

Solvothermal Synthesis of a New Photochromic Azo Polymer and its Self-assembly Behavior  

British Library Electronic Table of Contents (United Kingdom)

An amphiphilic azobenzene diblock copolymer {2-[4-(4-methoxy phenyl azo)phenoxy]hexyl acrylate co-acrylic acid} was synthesized via reversible addition-fragmentation chain transfer polymerization in a hydrothermal reactor. The products were characterized by 1H-NMR, DSC, GPC and UV-Vis spectroscopy. Different self-assembly behaviors of this amphiphilic diblock copolymer in different organic solvent with different water content were investigated. In THF/H2O solution, the diblock copolymer self-assembled into spheres and the spheres would then change to vesicles with smaller size by increasing the volume of H2O. However, in DMSO/H2O solution, the sizes and morphologies of the self-assembled spheres would not change significantly with an enhanced amount of H2O. Photochromic behaviors of the am...

2010-01-01

426

Self-organization and electrical properties of Head-to-Tail poly(3-hexylthiophene) in Langmuir-Blodgett films  

Energy Technology Data Exchange (ETDEWEB)

The conductive ultra thin films were fabricated from mixed monolayers containing stearic acid and Head-to-Tail poly(3-alkylthiophene). These films exhibited well-defined layered structures as determined by optical absorption and X-ray diffraction measurements. The UV-Vis absorption spectra of these films showed lower energy absorption shifts of 48 nm from that of the random poly(3-alkylthiophene)/stearic acid LB films. The blue shift of absorption maximum of the LB film is attributed to the increase of {pi}-conjugation length caused by no steric hindrance of alkyl side chains. The conductivity of the Head-to-Tail poly(3-hexylthiophene)/stearic acid LB films was greatly improved in the range of 67-100 S/cm. (orig.)

1997-01-01

427

Selective downregulation of retinoic acid-inducible gene I within the intestinal epithelial compartment in crohn's disease  

British Library Electronic Table of Contents (United Kingdom)

AbstractBackground: A defective innate immune response may contribute to the pathogenesis of Crohn's disease (CD) and ulcerative colitis (UC). Employing a global gene expression analysis, this study was aimed at identifying specifically regulated genes within the epithelial compartment in inflammatory bowel disease (IBD). Methods: The epithelial fraction of human ileal mucosa samples from surgical specimens was obtained by laser microdissection. Gene expression was examined by global expression profiling (n = 18, Affymetrix), quantitative reverse-transcription polymerase chain reaction (RT-PCR) (n = 35), immunoblot analysis (n = 9), and immunohistochemistry (n = 25). Results: Global expression profiling revealed a pronounced downregulation of the retinoic acid-inducible gene I (RIG-I) with...

2011-01-01

428

Selective changes of retroelement expression in human prostate cancer  

British Library Electronic Table of Contents (United Kingdom)

Retroelements constitute a large part of the human genome. These sequences are mostly silenced in normal cells, but genome-wide DNA hypomethylation in cancers might lead to their re-expression. Whether this re-expression really occurs in human cancers is largely unkown. We therefore investigated expression and DNA methylation of several classes of retroelements in human prostate cancer tissues and cell lines by quantitative reverse transcription-polymerase chain reaction and pyrosequencing, respectively. The most striking finding was strong and generalized increased expression of the HERV-K_22q11.23 provirus in cancers, including de novo expression of a spliced accessory Np9 transcript in some tumors. In parallel, DNA methylation in the long terminal repeat (LTR) decreased. Conversely, HER...

2011-01-01

429

Research of time-domain equivalent circuit method in solving dispersion of coupled-cavity traveling-wave tube  

International Nuclear Information System (INIS)

In this paper, a time-domain equivalent circuit method is applied to solve dispersion of coupled-cavity travelling-wave tube (CCTWT). First, the time-domain circuit equations of CCTWT coupled-cavity chain are deduced from the equivalent circuit model. Then, the equations are solved numerically by fourth-order Runge-Kutta method and a program CTTDCP is developed using MATLAB. Last, a L-band CCTWT is calculated using CTTDCP and the cavity pass-band of this tube is computed to be 1.08-1.48 GHz, which is consistent with the experimental results and the simulation results of electromagnetic code and demonstrates the validity of the time-domain equivalent circuit method. In addition, a new design method which uses the equivalent circuit method and electromagnetic simulation together to optimize the cold cavity characteristics of CCTWT is proposed. (authors)

2008-09-01

430

RXTE observations of Cas A  

International Nuclear Information System (INIS)

Rossi X-ray Timing Explorer (RXTE) observations of the bright supernova remnant Cas A have revealed a hard power law component above 10 keV in addition to two thermal components inferred from ASCA measurements of the many line centroids from low-Z elements. The power law can be shown to be consistent with synchrotron emission from radio to hard x-rays by electrons of up to 4 x 10"1"3 eV. Measurement of the 1157 keV line by CGRO from "4"4Sc in the chain of decay of "4"4Ti predicts that the two "4"4Ti lines at 68 and 78 keV should appear at the CGRO intensity. RXTE has placed upper limits on such lines that are marginally consistent with the CGRO measurement. Implications of these results on sites for cosmic ray acceleration and nucleosynthesis are discussed.

1999-01-01

431

Progress and problems in the chemistry of technetium-99m tracers  

International Nuclear Information System (INIS)

The recent acceleration of effort to elucidate and explore the coordination chemistry of technetium has been prompted mainly by the need for a new generation of radiotracers in nuclear medicine, preferentially for tomograhic studies. Current approaches and their limitations in designing "9"9"mTc complexes capable of penetrating cell membranes of the target organs, and remaining there sufficiently long, are reviewed. With the predominance of Tc(V) oxo compounds, especially for brain imaging agents, new N4 and N2S2 coordinate complexes have been developed by shifting from bidentate to tetradentate ligands with a variable side chain or other adjustable reactivity. The search for myocardial imaging agents has focused on a variety of mixed ligand complexes of Tc(III) and most promising [Tc(CNR)_6]"+ complexes of Tc(I). 64 refs. (author).

432

Preparation and evaluation of a novel glass-ionomer cement with antibacterial functions  

British Library Electronic Table of Contents (United Kingdom)

Objective.The objective of this study was to use the newly synthesized poly(quaternary ammonium salt) (PQAS)-containing polyacid to formulate the light-curable glass-ionomer cements and study the effect of the PQAS on the compressive strength and antibacterial activity of the formed cements.Materials and methods.The functional QAS and their constructed PQAS were synthesized, characterized and formulated into the experimental high-strength cements. Compressive strength (CS) and Streptococcus mutans viability were used to evaluate the mechanical strength and antibacterial activity of the cements. Fuji II LC cement was used as control. The specimens were conditioned in distilled water at 37 degrees C for 24 h prior to testing. The effects of the substitute chain length, loading as well as gra...

2011-01-01

433

Potential of production of biodiesel starting from the chicken oil in the cooperatives of the West of Parana, Brazil; Potencial de producao de biodiesel a partir do oleo de frango nas cooperativas do oeste do Parana  

Energy Technology Data Exchange (ETDEWEB)

Brazil occupies a prominence place in the development and use of sources renovate of energy, due to its great territorial extension, climate and several alternatives. One of these it is the bio diesel,o production which can substitute the oil diesel, decreasing the impacts to the environment. In the productive chain of chicken meat a residue, chicken oil, is generated with potential for biodiesel production. In this work they were certain characteristics physical chemistries, that can influence in the reactions of transesterification of the chicken oil. It was lifted up the potential of production of chicken oil in the cooperatives of the area west of the state of Parana and yield in biodiesel. The bio diesel production by cooperatives could be of 19.525.209,0 kg/year of bio diesel and the yield of 95%. (author)

2006-07-01

434

Population studies of 16 bovine STR loci for forensic purposes  

British Library Electronic Table of Contents (United Kingdom)

As a consequence of the close integration of cattle into the food chain of humans, forensically relevant cases involving cattle (Bos taurus) DNA analysis are common. However, scientific publications reporting the information content of the commonly used bovine short tandem repeat (STR) loci remains scarce. Population studies were performed for 16 polymorphic STR loci (BM1818, BM1824, BM2113, CSRM60, CSSM66, ETH3, ETH10, ETH225, HAUT27, ILSTS006, INRA023, SPS115, TGLA53, TGLA122, TGLA126, and TGLA227) including 4,162 randomly selected cattle representing 20 distinct breeds. The power of parental exclusion, expected and observed heterozygosity, probability of identity, and non-amplifying (?null?) allele frequencies were calculated. Major differences existed in the information content between...

2011-01-01

435

Pd adsorption on Si(1 1 3) surface: STM and XPS study  

Energy Technology Data Exchange (ETDEWEB)

Pd-induced surface structures on Si(1 1 3) have been studied by scanning tunneling microscopy (STM) and X-ray photoelectron spectroscopy (XPS). In the initial process of the Pd adsorption below 0.10 ML, Pd silicide (Pd{sub 2}Si) clusters are observed to form randomly on the surface. By increasing the Pd coverage to 0.10 ML, the clusters cover the entire surface, and an amorphous layer is formed. After annealing the Si(1 1 3)-Pd surface at 600 deg. C, various types of islands and chain protrusions appears. The agglomeration, coalescence and crystallization of these islands are observed by using high temperature (HT-) STM. It is also found by XPS that the islands correspond to Pd{sub 2}Si structure. On the basis of these results, evolution of Pd-induced structures at high temperatures is in detail discussed.

2008-09-30

436

Oxidation of polycaprolactone to induce compatibility with other degradable polyesters  

British Library Electronic Table of Contents (United Kingdom)

Chemical modification of poly(?-caprolactone) PCL by oxidation with potassium permanganate in solution was investigated. According to the data obtained from Fourier transform infrared spectroscopy (FT-IR) and nuclear magnetic resonance 1H NMR, after the oxidation reactions the PCL chains exhibited new functional groups (vinyl and hydroxyl) and possible intermolecular recombination, producing an oxidized-polycaprolactone (PCL-OX). Solution viscometry indicated that degradation also occurred during the oxidation reactions (30% drop in viscosity average molecular weight was detected). Differential scanning calorimetry (DSC) also indicated that PCL was chemically modified and degraded. The successive self-nucleation/annealing (SSA) treatment confirmed that a reduction (or interruption) in line...

2007-01-01

437

Optimal boarding method for airline passengers  

Energy Technology Data Exchange (ETDEWEB)

Using a Markov Chain Monte Carlo optimization algorithm and a computer simulation, I find the passenger ordering which minimizes the time required to board the passengers onto an airplane. The model that I employ assumes that the time that a passenger requires to load his or her luggage is the dominant contribution to the time needed to completely fill the aircraft. The optimal boarding strategy may reduce the time required to board and airplane by over a factor of four and possibly more depending upon the dimensions of the aircraft. I explore some features of the optimal boarding method and discuss practical modifications to the optimal. Finally, I mention some of the benefits that could come from implementing an improved passenger boarding scheme.

2008-02-01

438

New derivation of the Marshalek-Okubo realization of the shell-model algebra SO(2. nu. +1) for even and odd systems with. nu. single-particle levels  

Energy Technology Data Exchange (ETDEWEB)

In recent years, the method for unitarizing nonunitary Dyson boson realizations of shell-model algebras has been both generalized and substantially simplified through the introduction of overtly group-theoretical methods. In this paper, these methods are applied to the boson-odd-particle realization of the algebra SO(2..nu..+1) for ..nu.. single-particle levels, adapted to the group chain SO(2..nu..+1) contains SO(2..nu..) contains U(..nu..), which Marshalek first derived by brute force summation of a Taylor expansion and later Okubo by a largely algebraic technique.

1988-04-01

439

New b-amino-a-trifluoromethyl alcohols and their exploration in the synthesis of trifluoromethylated imidazole derivatives  

British Library Electronic Table of Contents (United Kingdom)

Racemic and enantiomerically pure b-amino-a-trifluoromethyl alcohols were obtained via sequential nucleophilic trifluoromethylation of selected a-imino ketones, derived from arylglyoxals, and subsequent removal of the MeO or Ph(Me)CH substituent, respectively, located at the N-atom. The obtained products, containing a primary amino group, were used for the synthesis of imidazole N-oxides bearing a trifluoromethyl group as a part of the N(1)-alkyl chain. Imidazole N-oxides with an electron-withdrawing ester group at C(4) underwent spontaneous isomerization under the reaction conditions, and the corresponding imidazol-2-ones derivatives were isolated as final products.

2011-01-01

440

Natural Convection Analysis with Various Turbulent Models Using FLUENT  

Energy Technology Data Exchange (ETDEWEB)

The buoyancy driven convective flow fields are steady circulatory flows which were made between surfaces maintained at two fixed temperatures. They are ubiquitous in nature and play an important role in many engineering applications. Especially, in last decades, natural convection in a close loop or cavity becomes the main issue in the molecular biology for the polymerase chain reaction (PCR). Application of a natural convection can reduce the costs and efforts remarkably. This paper focuses on the sensitivity study of turbulence analysis using CFD for a natural convection in a closed rectangular cavity. Using commercial CFD code, FLUENT, various turbulent models were applied to the turbulent flow. Results from each CFD model will be compared each other in the viewpoints of flow characteristics. This work will suggest the best turbulent model of CFD for analyzing turbulent flows of the natural convection in an enclosure system.

2007-07-01

441

Natural Convection Analysis with Various Turbulent Models Using FLUENT  

International Nuclear Information System (INIS)

The buoyancy driven convective flow fields are steady circulatory flows which were made between surfaces maintained at two fixed temperatures. They are ubiquitous in nature and play an important role in many engineering applications. Especially, in last decades, natural convection in a close loop or cavity becomes the main issue in the molecular biology for the polymerase chain reaction (PCR). Application of a natural convection can reduce the costs and efforts remarkably. This paper focuses on the sensitivity study of turbulence analysis using CFD for a natural convection in a closed rectangular cavity. Using commercial CFD code, FLUENT, various turbulent models were applied to the turbulent flow. Results from each CFD model will be compared each other in the viewpoints of flow characteristics. This work will suggest the best turbulent model of CFD for analyzing turbulent flows of the natural convection in an enclosure system.

2007-05-10

442

Mutations at the cysteine codons of the recA gene of Escherichia coli  

International Nuclear Information System (INIS)

Each of the three cysteine residues in the Escherichia coli RecA protein was replaced with a number of other amino acids. To do this, each cysteine codon was first converted to a chain-terminating amber codon by oligonucleotide-directed mutagenesis. These amber mutants were then either assayed for function in different suppressor strains or reverted by a second round of mutagenesis with oligonucleotides that had random sequences at the amber codon. Thirty-three different amino acid substitutions were obtained. Mutants were tested for three functions of RecA: survival following UV irradiation, homologous recombination, and induction of the SOS response. It was found that although none of the cysteines is essential for activity, mutations at each of these positions can affect one or more of the activities of RecA, depending on the particular amino acid substitution. In addition, the cysteine at position 116 appears to be involved in the RecA-promoted cleavage of the ...

443

Molecular analysis of polymerase gamma gene and mitochondrial polymorphism in fertile and subfertile men  

British Library Electronic Table of Contents (United Kingdom)

Summary CAG trinucleotide repeat length in the nuclear polymerase gamma gene (POLg) has been shown to be associated with men with reduced fertility. The present study investigated the frequency of CAG repeat length genotypes and three exonuclease motifs of the POLg in relation to the frequency of mitochondrial nucleotide substitutions. DNA from semen samples of 93 normozoospermic men and 192 non-normozoospermic men was isolated and the specific regions of the genes were amplified by polymerase chain reactions (PCR) and sequenced to identify mutations. The genotypic frequencies of pooled POLg CAG repeat lengths, =10/!=10 heterozygotes and !=10/!=10 homozygotes, were significantly different between normozoospermic and non-normozoospermic men (p p POLg genotype. Of the 17 men with non-synonym...

2006-01-01

444

Model for risk and reliability analysis of complex production systems: Application to FPSO/flow-Riser system  

British Library Electronic Table of Contents (United Kingdom)

A model for risk and reliability analysis of complex multifunctional production process systems is presented. The model employs Monte-Carlo and Markov Chain algorithms that uses a weighted index to train and simulate the fuzzy hazard data sets which represents failure outcomes of risk component transient and non-transient systems. Early simulation results shows that hazard rates and the risk of containment loss from typical floating production and storage offloading (FPSO)-Riser system for the risk components in parallel or series increases exponentially with time and decreases as safety ratings fraction increases. The reliability value decreases with time and safety fraction (SFAC) for all fuzzy hazard classifications. The results of the computed mean time before repair (MTBR) show that t...

2009-01-01

445

Mitochondrial NADH:ubiquinone oxidoreductase (complex I) in eukaryotes: A highly conserved subunit composition highlighted by mining of protein databases  

British Library Electronic Table of Contents (United Kingdom)

Complex I (NADH:ubiquinone oxidoreductase) is the largest enzyme of the mitochondrial respiratory chain. Compared to its bacterial counterpart which encompasses 14-17 subunits, mitochondrial complex I has almost tripled its subunit composition during evolution of eukaryotes, by recruitment of so-called accessory subunits, part of them being specific to distinct evolutionary lineages. The increasing availability of numerous broadly sampled eukaryotic genomes now enables the reconstruction of the evolutionary history of this large protein complex. Here, a combination of profile-based sequence comparisons and basic structural properties analyses at the protein level enabled to pinpoint homology relationships between complex I subunits from fungi, mammals or green plants, previously identified...

2011-01-01

446

Mismatch measurement and correction tools for the PS-SPS transfer of the 26GeV/C LHC beam  

CERN Document Server

TRANSVERSE EMITTANCE PRESERVATION IS A MAJOR CONCERN OF THE LHC INJECTOR CHAIN. MINIMISATION OF THE BLOW-UP DUE TO MISMATCH AT INJECTION INTO THE SPS IS THEREFORE MANDATORY. WHILE THE TRANSVERSE POSITIONN OF THE BEAM IN THE SPS INJECTION LINE IS MONITORED BUNCH BY BUNCH BY AN OTR (OPTICAL TRANSITION RADIATION) SCREEN AND A FAST CCD (CHARGED COUPLED DEVICE) CAMERA, THE PHASE SPACE MATCHING AT INJECTION IS MONITORED BY AN OTR BASED MISMATCH MONITOR IN THE SPS RING. ORTHOGONAL TUNING KNOBS WERE DEVELOPED TO TUNE INDEPENDENTLY TWISS PARAMETERS, DISPERSION AND DISPERSION DERIVATIVE. IN THIS PAPER WE DESCRIBE THE MISMATCH CORRECTION MECHANISM AS WELL AS THE TWO MONITORING SYSTEMS. WE REPORT ON FIRST MEASUREMENTS WHICH WERE CARRIED OUT DURING THE 1998 SPS RUN.

1999-01-01

447

Mechanical behavior of self-assembled carbon nanotube reinforced nylon 6,6 fibers  

British Library Electronic Table of Contents (United Kingdom)

The versatile electrospinning technique was used to successfully align and disperse multiwalled carbon nanotubes (MWCNT) in nylon 6,6 matrix to obtain composite fibers. The morphology of the composite fibers and the dispersion of the CNTs within the fibers were analyzed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM), respectively. TEM analysis revealed that the CNTs were well-dispersed, separated and aligned along the fiber axis. The thermal and mechanical properties of the composite fibers were characterized as a function of weight fraction of the CNTs. Incorporation of the CNTs in the fibers resulted in an increase in glass-transition temperature (Tg) by 7degreeC, indicating that the addition of CNTs has restricted the mobility of the polymer chains a...

2010-01-01

448

Mass distribution of fission products from moderately excited sup 236 U compound nucleus  

Energy Technology Data Exchange (ETDEWEB)

The chain yields of 30 fission products were determined in 38 MeV {alpha}-particle induced fission of {sup 232}Th. The mass yield curve was found to be primarily asymmtric with a peak to valley (p/v) ratio of 3.5. A small peak has also been observed in the symmetric region. The observed p/v ratio has been resolved into the p/v ratios of the individual mass distributions of the possible fissioning isotopes of uranium formed as a result of multichance fission. An attempt has been made to explain the p/v ratios thus obtained in the light of the available excitation energy in the system. (orig.).

1990-01-01

449

Mapping of the human cone transducin {alpha}-subunit (GNAT2) gene to 1p13 and negative mutation analysis in patients with Stargardt disease  

Energy Technology Data Exchange (ETDEWEB)

We report localization of the human cone transducin (GNAT2) gene using fluorescence in situ hybridization on chromosome 1 in band p13. The recent assignment of a gene for Stargardt disease to the same chromosomal region by linkage analysis prompted us to investigate the possible role of GNAT2 in the pathogenesis of this disease. We investigated 66 unrelated patients for mutations in the coding region of the GNAT2 gene using polymerase chain reaction-single strand conformation polymorphism analysis (SSCP) and direct sequencing. No disease-specific mutations were found, indicating that GNAT2 is probably not involved in the pathogenesis of most cases of Stargardt disease. 19 refs., 1 fig., 1 tab.

1995-01-01

450

Many-particle confinement by constructed disorder and quantum computing  

Energy Technology Data Exchange (ETDEWEB)

Many-particle confinement (localization) is studied for a 1D system of spinless fermions with nearest-neighbour hopping and interaction, or equivalently, for an anisotropic Heisenberg spin-1/2 chain. This system is frequently used to model quantum computers with perpetually coupled qubits. We construct a bounded sequence of site energies that leads to strong single-particle confinement of all states on individual sites. We show that this sequence also leads to a confinement of all many-particle states in an infinite system for a time that scales as a high power of the reciprocal hopping integral. The confinement is achieved for strong interaction between the particles while keeping the overall bandwidth of site energies comparatively small. The results show the viability of quantum computing with time-independent qubit coupling.

2005-10-01

451

Linearized augmented-plane-wave method for quasi-unidimensional systems: Carbyne and nanotube (Sc@C{sub 20})  

Energy Technology Data Exchange (ETDEWEB)

The advent of carbon nanotubes, which are graphite layers convoluted in cylinders several nanometers in diameter and several micrometers in length, as well as the experiments on implanting metal atoms in such tubes open the way to producing nanoconductors and other materials with unique properties. For theorists, the basic challenge is interpreting and predicting the structure and properties of these systems. The linearized augmented-plane-wave method (LAPW) is one of the most accurate methods in the theory of the electronic structure of solids. A generalization of this method for quasi-two-dimensional systems, surface electronic states, and layered crystals is known. The LAPW theory for quasi-unidimensional systems, which exhibit translational symmetry in one direction, has been absent thus far. In this paper, the authors suggest a version of such a theory and use this method to calculate the electronic structure of carbyne (a linear chain of carbon atoms) and ...

1995-10-01

452

Laser-generated PuO_2--UO_2 condensation aerosols  

International Nuclear Information System (INIS)

A 340-watt CO_2 laser is being used to generate PuO_2-UO_2 condensation aerosol from the surface of a Liquid Metal Fast Breeder Reactor (LMFBR) fuel pellet. A wide range of concentrations is achieved by varying the laser power, pulse width, and/or pulse period. The resulting aerosol is composed of branch chain-like aggregates, with the primary particle size ranging between 0.005 and 0.15 #mu#m. X-ray diffraction analyses show that these aerosols condense into a face-centered cubic crystal structure. The activity mean aerodynamic diameter (AMAD), for most power levels, is approximately 0.85 #mu#m with a geometric standard deviation of 1.5.

1977-05-01

453

KMeyeDB: a graphical database of mutations in genes that cause eye diseases  

British Library Electronic Table of Contents (United Kingdom)

KMeyeDB () is a database of human gene mutations that cause eye diseases. We have substantially enriched the amount of data in the database, which now contains information about the mutations of 167 human genes causing eye-related diseases including retinitis pigmentosa, cone-rod dystrophy, night blindness, Oguchi disease, Stargardt disease, macular degeneration, Leber congenital amaurosis, corneal dystrophy, cataract, glaucoma, retinoblastoma, Bardet-Biedl syndrome, and Usher syndrome. KMeyeDB is operated using the database software MutationView, which deals with various characters of mutations, gene structure, protein functional domains, and polymerase chain reaction (PCR) primers, as well as clinical data for each case. Users can access the database using an ordinary Internet browser wi...

2010-01-01

454

Isolation of antibodies specific to sickle hemoglobin by affinity chromatography using a synthetic peptide  

International Nuclear Information System (INIS)

Antibodies to hemoglobin have been studied with a radioimmunoassay which employs ["1"4C]carbamylated (= carbamoylated) hemoglobin S. An antiserum raised against hemoglobin S, which initially discriminated poorly between hemoglobins S and A, was fractionated by absorption to a column of Sepharose to which a synthetic peptide corresponding to the first 13 amino-acid residues of the #beta# chain of sickle hemoglobin had been covalently bound. A subpopulation of the antiserum was eluted from this column with 4 M guanidine . HCl. These antibodies showed binding to hemoglobin S but not to hemoglobin A and this interaction could be inhibited by the synthetic peptide. These antibodies, of demonstrated fine structural specificity, may be useful in the detection of sickle hemoglobin and in the study of its structure in solution.

455

Ionic conduction in polyether-based lithium arylfluorosulfonimide ionic melt electrolytes  

Energy Technology Data Exchange (ETDEWEB)

We report synthesis, characterization and ion transport in polyether-based ionic melt electrolytes consisting of Li salts of low-basicity anions covalently attached to polyether oligomers. Purity of the materials was investigated by HPLC analysis and electrospray ionization mass spectrometry. The highest ionic conductivity of 7.1 x 10{sup -6} S/cm at 30 deg. C was obtained for the sample consisting of a lithium salt of an arylfluorosulfonimide anion attached to a polyether oligomer with an ethyleneoxide (EO) to lithium ratio of 12. The conductivity order of various ionic melts having different polyether chain lengths suggests that at higher EO:Li ratios the conductivity of the electrolytes at room temperature is determined in part by the amount of crystallization of the polyether portion of the ionic melt.

2009-10-01

456

Ionic conduction in polyether-based lithium arylfluorosulfonimide ionic melt electrolytes  

International Nuclear Information System (INIS)

We report synthesis, characterization and ion transport in polyether-based ionic melt electrolytes consisting of Li salts of low-basicity anions covalently attached to polyether oligomers. Purity of the materials was investigated by HPLC analysis and electrospray ionization mass spectrometry. The highest ionic conductivity of 7.1 x 10-6 S/cm at 30 deg. C was obtained for the sample consisting of a lithium salt of an arylfluorosulfonimide anion attached to a polyether oligomer with an ethyleneoxide (EO) to lithium ratio of 12. The conductivity order of various ionic melts having different polyether chain lengths suggests that at higher EO:Li ratios the conductivity of the electrolytes at room temperature is determined in part by the amount of crystallization of the polyether portion of the ionic melt.

2009-10-01

457

Involvement of a putative response regulator Brrg-1 in the regulation of sporulation, sensitivity to fungicides, and osmotic stress in Botrytis cinerea  

British Library Electronic Table of Contents (United Kingdom)

The response regulator protein is a core element of two-component signaling pathway. In this study, we investigated functions of BRRG-1 of Botrytis cinerea, a gene that encodes a putative response regulator protein, which is homologous to Rrg-1 in Neurospora crassa. The BRRG-1 gene deletion mutant ?Brrg1-62 was unable to produce conidia. The mutant showed increased sensitivity to osmotic stress mediated by NaCl and KCl, and to oxidative stress generated by H2O2. Additionally, the mutant was more sensitive to the fungicides iprodione, fludioxonil, and triadimefon than the parental strain. Western-blot analysis showed that the Bos-2 protein, the putative downstream component of Brrg-1, was not phosphorylated in the ?Brrg1-62. Real-time polymerase chain reaction assays showed that expression ...

2011-01-01

458

Intravascular pressure augments cerebral arterial constriction by inducing voltage insensitive Ca2+ waves  

British Library Electronic Table of Contents (United Kingdom)

This study examined whether elevated intravascular pressure stimulates asynchronous Ca2+ waves in cerebral arterial smooth muscle cells and if their generation contributes to myogenic tone development. The endothelium was removed from rat cerebral arteries, which were then mounted in an arteriograph, pressurized (20 100 mmHg) and examined under a variety of experimental conditions. Diameter and membrane potential (VM) were monitored using conventional techniques; Ca2+ wave generation and myosin light chain (MLC20)/MYPT1 (myosin phosphatase targeting subunit) phosphorylation were assessed by confocal microscopy and Western blot analysis, respectively. Elevating intravascular pressure increased the proportion of smooth muscle cells firing asynchronous Ca2+ waves as well as event frequency. C...

2010-01-01

459

Interlattice displacements and elastic constants of the A-15 compounds V_3Si, V_3Ge and Nb_3Sn  

International Nuclear Information System (INIS)

General expressions for the interlattice displacements of the A-15 structure compounds are obtained in terms of the strain components making use of the deformation theory. The nature of the interlattice displacements of all the 8 atoms in the unit cell is discussed. It is found that the interlattice displacements occur in such a way that the pair of atoms along any linear chain move in opposite directions with equal magnitudes. Expression for the strain energy of these compounds is developed using deformation theory and this is compared with the strain energy expression from continuum theory to obtain the elastic constants. The theoretical values of the elastic constants fairly agree with the experimental values for V_3Si, V_3Ge and Nb_3Sn. (author).

460

Interlattice displacements and elastic constants of the A-15 compounds V3Si, V3Ge and Nb3Sn  

Science.gov (United States)

General expressions for the interlattice displacements of the A-15 structure compounds are obtained in terms of the strain components making use of the deformation theory. The nature of the interlattice displacements of all the 8 atoms in the unit cell is discussed. It is found that the interlattice displacements occur in such a way that the pair of atoms along any linear chain move in opposite directions with equal magnitudes. Expression for the strain energy of these compounds is developed using deformation theory and this is compared with the strain energy expression from continuum theory to obtain the elastic constants. The theoretical values of the elastic constants fairly agree with the experimental values for V3Si, V3Ge and Nb3Sn.

1978-03-01

461

Impaired mitochondrial energy metabolism and kinetic properties of cytochrome oxidase following acute aluminium phosphide exposure in rat liver  

British Library Electronic Table of Contents (United Kingdom)

The present study was designed with an aim to analyze the effect of acute aluminium phosphide (ALP) exposure (10mg/kg b.wt, intragastrically) on the kinetic characteristics of cytochrome oxidase and energy metabolism in male Wistar rat liver mitochondria. Liver mitochondrial preparations from ALP-treated rats exhibited significant decrease (66%) in the activity of cytochrome oxidase suggesting that there was a decrease in the catalytic efficiency of the active oxidase molecules on ALP treatment. The decreased activity of cytochrome oxidase with altered NADH and succinic dehydrogenase activities might have contributed towards a significant decline in state 3 and state 4 respiration as observed. These alterations in the electron transport chain complexes in turn adversely affected the ATP sy...

2010-01-01

462

Human and rat mast cell high-affinity immunoglobulin E receptors: Characterization of putative. alpha. -chain gene products  

Energy Technology Data Exchange (ETDEWEB)

The authors have cloned and determined the entire nucleotide sequence of cDNAs corresponding to the putative {alpha} subunits of the human and rat mast cell high-affinity IgE receptors. Both human and rat cDNAs encode an NH{sub 2}-terminal signal peptide, two immunoglobulin-like extracellular domains (encoded by discrete exons), a hydrophobic transmembrane region, and a positively charged cytoplasmic tail. The human and rat {alpha} subunits share an overall homology with one another and the immunoglobulin gene family, suggesting that they arose from a common ancestral gene and continue to share structural homology with their ligands. In addition, the rat gene is transcribed into at least three distinct forms, each of which yields a somewhat different coding sequence.

1988-03-01

463

Flexible Session Management in a Distributed Environment  

CERN Document Server

Many secure communication libraries used by distributed systems, such as SSL, TLS, and Kerberos, fail to make a clear distinction between the authentication, session, and communication layers. In this paper we introduce CEDAR, the secure communication library used by the Condor High Throughput Computing software, and present the advantages to a distributed computing system resulting from CEDAR's separation of these layers. Regardless of the authentication method used, CEDAR establishes a secure session key, which has the flexibility to be used for multiple capabilities. We demonstrate how a layered approach to security sessions can avoid round-trips and latency inherent in network authentication. The creation of a distinct session management layer allows for optimizations to improve scalability by way of delegating sessions to other components in the system. This session delegation creates a chain of trust that reduces the overhead of establishing secure ...

2010-01-01

464

First measurement of ADS parameters using B- -> D0K- decays in hadron collisions  

CERN Document Server

Measurements of branching fractions and CP-asymmetries of B^{-} \\rightarrow D^{0}K^{-} modes allow a theoretically-clean extraction of the CKM angle \\gamma. The method proposed by Atwood, Dunietz and Soni (ADS) makes use of a decay chain where color and Cabibbo suppression interfere, which produces large CP-violating asymmetries. The CDF experiment reports the first measurement at a hadron collider of branching fractions and CP-asymmetries of suppressed B^{-} \\rightarrow D^{0}h^{-} signals, where h is \\pi or K. Using 5.0 fb^{-1} of data we found a combined significance exceeding 5\\sigma and we determined the ADS parameters with accuracy comparable with B-factories.

2011-01-01

465

Fast neutron nuclear data: Pu-239 revision and Am status  

International Nuclear Information System (INIS)

Neutron cross sections for Pu-239 and Am-241, -242m, -243 have been analyzed with the aid of theoretical models. A deformed optical potential that fits total, elastic and inelastic differential cross section data and neutron strength functions for Pu-239 and Am-241 have been used. In case of Pu-239 the consistency of absolute fission data and (n, 2n) cross section is investigated. Because of the strong discrepancies in Am fission cross section data a consistent set of calculated cross section values for the chain of Am nuclei is proposed. The present state of knowledge concerning first chance fission cross section allows to analyze fission cross section data of Am-241, -242m, -243, up to 20 MeV. The results thus obtained are compared with ENDF/B-V and JENDL-3 libraries. (orig.).

466

Evaluation of the addition of various surfactant-suspended carbon nanotubes in MEEKC with an in situ-synthesized surfactant system  

British Library Electronic Table of Contents (United Kingdom)

Abstract Dispersions of single-walled carbon nanotubes (SWNTs) in various surfactant solutions have been systematically evaluated as additives in MEEKC. The compounds examined were catechins, phenolic acids, and flavonoids. Compared with zwitterionic and neutral surfactants, the addition of anionic dispersion seemed to be better at separating the three types of analytes in microemulsion system. In order to achieve low operating currents, an in situ-synthesized surfactant system based on the combination of a long-chain alkyl acid with an organic base was used in MEEKC. The optimized buffer contained 0.5% (57-mM) ethyl acetate, 0.6% (30-mM) lauric acid, 4.0% (666-mM) propanol, 50-mM Tris solution, and 4.5-mg/L the dispersion of SWNTs. Under optimized conditions, the established method was ap...

2011-01-01

467

Ensuring GRID resource availability with the SAM framework in LHCb  

CERN Document Server

The LHCb experiment has chosen to use the SAM framework (Service Availability Monitoring Environment from EGEE-II) [1] make extensive tests of the LHCb environment at all the accessible grid resources. The availability and the proper definition of the local Computing and Storage Elements, user interfaces as well as the WLCG software environment are checked. The SAM framework is also used to pre-install the LHCb applications in the shared software area provided by each site. The deployment of the LHCb applications is based on a python tool developed inside the experiment. It is used for software management including incremental installation of interdependent packages and clean package removal. After the application software is installed a validation test of the whole MC chain is run. According to the results of the experiment specific SAM tests, the sites are (re)integrated into the LHCb production system managed by DIRAC [2]. The possibility of automated dynamic ...

2008-01-01

468

Efficient Queue-based CSMA with Collisions  

CERN Document Server

Recently there has been considerable interest in the design of efficient carrier sense multiple access(CSMA) protocol for wireless network. The basic assumption underlying recent results is availability of perfect carrier sense information. This allows for design of continuous time algorithm under which collisions are avoided. The primary purpose of this note is to show how these results can be extended in the case when carrier sense information may not be perfect, or equivalently delayed. Specifically, an adaptation of algorithm in Rajagopalan, Shah, Shin (2009) is presented here for time slotted setup with carrier sense information available only at the end of the time slot. To establish its throughput optimality, in additon to method developed in Rajagopalan, Shah, Shin (2009), understanding properties of stationary distribution of a certain non-reversible Markov chain as well as bound on its mixing time is essential. This note presents these key results. A ...

2010-01-01

469

Effect of season on contractile and metabolic properties of desert camel muscle (Camelus dromedarius)  

British Library Electronic Table of Contents (United Kingdom)

Thirty fattened one humped desert camels were used to examine the effect of season on contractile and metabolic properties of Longissimus thoracis (LT) muscle. Ten camels were slaughtered according to seasons of the year (winter, summer and autumn). Season significantly influenced muscle chemical composition, ultimate pH (pHu) and color. Activities of metabolic enzymes were higher during autumn season compared to summer and winter for phosphofructokinase (+64% compared to both seasons) and for isocitrate dehydrogenase (+35% and +145% in autumn vs. summer and winter, respectively). Quantification of muscle myosin heavy chain isoforms by SDS-PAGE electrophoresis showed only presence of type I and type IIa MyHC in camel muscle and indicated high proportion in winter for type I and in autumn f...

2012-01-01

470

Digital Audio Sampling for Film and Video.  

Science.gov (United States)

Digital audio sampling is explained, and some of its implications in digital sound applications are discussed. Digital sound equipment is rapidly replacing analog recording devices as the state-of-the-art in audio technology. The philosophy of digital recording involves doing away with the continuously variable analog waveforms and turning the patterns into numbers. A digital recording device rapidly samples the incoming sounds, quantifying the signal into a series of numerical values (binary codes). Although digital sound eliminates many of the traditional analog problems, digital signal processing presents key problems in sampling rates and synchronization. Careful control is necessary to check signals through each step in the audio chain. The advantages of digital audio processing include increased signal-to-noise ratio, no flutter, transparent generation of copies, and sound manipulation. These benefits come with increased quality control requirements. One ...

1993-03-01

471

Dielectric behaviour of emeraldine base polymer?ZnO nanocomposite film in the low to medium frequency  

British Library Electronic Table of Contents (United Kingdom)

Emeraldine base (EB) polymer?ZnO nanoparticles composite films has been synthesized by solution casting technique on ITO-coated glass substrate and characterized by XRD, FTIR and TEM for their structure and morphology. Dielectric behaviour of these composite films has been investigated in the very low frequency region to medium frequency region (1?kHz?1?MHz). The dielectric constant of the composite with 30% nanoparticles is almost one-tenth of the pure EB. The dielectric value becomes constant in the frequency region greater than 400?kHz. The change in dielectric behaviour of the composite is explained on the basis of multilayered interface formed between the ZnO nanoparticles and emeraldine chains. Nanoparticles have high energy surface which is responsible for the decrease of free volum...

2011-01-01

472

Diagnostic and Prognostic Utility of t(14;18) in Follicular Lymphoma  

British Library Electronic Table of Contents (United Kingdom)

Abstract Background: Follicular lymphoma (FL) is one of the most common non-Hodgkin's lymphomas of B cells, being closely associated with a t(14;18) translocation. Detection of t(14;18), which is present in 70-95% of FL, might aid in FL diagnosis. Objective: To compare the efficacy of routine polymerase chain reaction (PCR) and fluorescence in situ hybridization (FISH) techniques in detecting t(14;18) in paraffin-embedded tissue samples of FL patients at different stages. Combined with other immunophenotypic biological determinants, detection of t(14;18) might help to determine patients at increased risk according to the FL International Prognostic Index (FLIPI) and therefore facilitate appropriate treatment. Design and Methods: This study was mainly based on a retrospective examination of...

2007-01-01

473

Degradation of organophosphorus pesticides in wheat during cookie processing  

British Library Electronic Table of Contents (United Kingdom)

For investigating carryover of some organophosphorus pesticide residues in the cereal food chain from grain to consumer, a study was set up on wheat bran, flour and cookies, with and without bran. Special emphasis was given to malathion and chlorpyrifos-methyl residues in cookies for better protection of consumers. Pesticide-free wheat was placed in a small-scale model of a commercial storage vessel and treated with these pesticides. The residue levels of insecticides were determined in wheat, as well as in bran, flour and cookies produced from stored wheat at various time intervals during storage. A multiresidue analysis was performed using GC-NPD and GC-MS. Malathion and chlorpyrifos-methyl residue levels were higher than the maximum residue limits (MRLs) in wheat after 240days of storag...

2009-01-01

474

Degradation of leucine zipper-positive isoform of MYPT1 may contribute to development of nitrate tolerance  

British Library Electronic Table of Contents (United Kingdom)

Aims A depressed cGMP-dependent protein kinase (PKG) activity is implicated in nitrate tolerance. The present study determines whether the leucine zipper-positive (LZ+) isoform of myosin phosphatase target subunit 1 (MYPT1), a key target protein for PKG actions, is involved in the development of nitrate tolerance. Methods and results Nitrate tolerance in in vitro preparations was obtained by a 24 h incubation with nitroglycerin (NTG). Nitrate tolerance in in vivo preparations was obtained by subcutaneous injection of mice with NTG, and the aortas were used. Protein levels of total MYPT1, MYPT1 (LZ+), PP1Cd, myosin light chain (MLC), and phosphorylated MLC were determined by Western blot analysis. Isometric vessel tension was determined by an organ chamber technique. Protein levels of MYPT1...

2010-01-01

475

Cytokine-induced impairment of short-chain fatty acid oxidation and viability in human colonic epithelial cells  

DEFF Research Database (Denmark)

Pro-inflammatory cytokines may directly influence the viability and metabolic function of colonic epithelial cells (CEC) as an early event in the development of inflammatory bowel disease. We report here that TNF-alpha+IFN-gamma induced a synergistic, concentration-dependent decline in butyrate oxidation, an essential energy supply, in HT-29 and DLD-1 cells. TNF-alpha+IFN-gamma induced a parallel profound decline in cell viability in HT-29 cells, but not in DLD-1 cells, where impairment of butyrate oxidation seemed to precede later occurrence of cell damage. TNF-alpha+INF-gamma induced CEC damage was independent on NO formation and involved the IFN-gamma signalling pathway as well as induction of apoptosis. If cytokines have similar effects in vivo, these may lead to energy deficiency and thus contribute to CEC damage and disturbance of the epithelial integrity.

2000-01-01

476

Cosmological parameter estimation using Particle Swarm Optimization (PSO)  

CERN Document Server

Obtaining the set of cosmological parameters consistent with observational data is an important exercise in current cosmological research. It involves finding the global maximum of the likelihood function in the multi-dimensional parameter space. Currently sampling based methods, which are in general stochastic in nature, like Markov-Chain Monte Carlo(MCMC), are being commonly used for parameter estimation. The beauty of stochastic methods is that the computational cost grows, at the most, linearly in place of exponentially (as in grid based approaches) with the dimensionality of the search space. MCMC methods sample the full joint probability distribution (posterior) from which one and two dimensional probability distributions, best fit (average) values of parameters and then error bars can be computed. In the present work we demonstrate the application of another stochastic method, named Particle Swarm Optimization (PSO), that is widely used in the field of ...

2011-01-01

477

Convergent Flows: Humanities Scholars and Their Interactions with Electronic Texts  

Science.gov (United States)

This article reports research findings related to converging formats, media, practices, and ideas in the process of academics' interaction with electronic texts during a research project. The findings are part of the results of a study that explored interactions of scholars in literary and historical studies with electronic texts as primary materials. Electronic texts were perceived by the study participants as fluid entities because the electronic environment promotes seamless interactions with a variety of media and formats. Working with electronic texts combines some traditional information and research practices into new patterns of information behavior. The practice called "netchaining" combines aspects of networking with information-seeking practices to establish and shape online information chains, which link sources and people. Different forms of exploration of participants' research questions were enabled by interactions with electronic texts.

2008-07-01

478

Consuming for production - Procurement for power production at Cernavoda NPP - Nuclear Sector  

International Nuclear Information System (INIS)

The paper presents some aspects relating to the importance of a good communication and cooperation between all factors involved in procurement process at Societatea Nationala 'Nuclearelectrica', SNN. In order to comply with the internal and international rules related to safety in nuclear field and public procurement requirements and for maintaining a high standard of operational performance of Cernavoda NPP, adequate procurement systems were developed by SNN SA. The importance of human factor and the training activities for all personnel from this chain of procurement process is the main key issue to maintain high quality of their activities considering that procurement documents are reviewed and approved before to be issued by all departments involved in procurement process. The specialized department for public acquisition is supervising that the procurement processes initiated at the level of branches, in accordance with their needs and with respect to the ...

2009-10-12

479

Construction and Analytical Application of Internal Amplification Controls (IAC) for Detection of Food Supply Chain-Relevant Viruses by Real-Time PCR-Based Assays  

British Library Electronic Table of Contents (United Kingdom)

Internal amplification controls (IACs) were constructed for incorporation into real-time nucleic acid amplification assays for bovine polyomavirus, hepatitis A virus, hepatitis E virus, human adenovirus, human norovirus genogroup I, human norovirus genogroup II, murine norovirus and porcine adenovirus. The addition of optimised amounts of IAC into the assays did not affect the limits of detection for each specific target virus. A poorly performed extraction of viral nucleic acids was simulated, and the effectiveness of IACs in identifying failed assays was demonstrated. The IACs constructed in this study can be reliably used in their specific assays to provide a robust control that can be routinely applied in the analysis of foods for viruses.

2011-01-01

480

Collaborative e-product development and product innovation in a demand-driven network: the moderating role of eCRM  

British Library Electronic Table of Contents (United Kingdom)

Customer relationships, product development, data integration and demand-driven supply chains are key concepts for companies that wish to remain competitive in today?s global economy. To address this important information management issue, the present study examines how, within a demand-driven network context, an eCRM can influence the interorganizational product development process between a manufacturer and its key customers. The theoretical model, built on research related to a technology assimilation model based on Fichman?s (2000) work, was tested on data from 104 manufacturers in the wireless equipment sector. The results show that the adoption of an eCRM does not moderate the relationship between collaborative e-product development involving a manufacturer and its key customers and ...

2009-01-01

481

Chromosomal localization and structure of the human type II IMP dehydrogenase gene  

Energy Technology Data Exchange (ETDEWEB)

We determined the chromosomal localization and structure of the gene encoding human type II inosine 5{prime}-monophosphate dehydrogenase (IMPDH, EC 1.1.1.205), an enzyme associated with cellular proliferation, malignant transformation, and differentiation. Using polymerase chain reaction (PCR) primers specific for type II IMPDH, we screened a panel of human-Chinese hamster cell somatic hybrids and a separate deletion panel of chromosome 3 hybrids and localized the gene to 3p21.1{yields}p24.2. Two overlapping yeast artificial chromosome clones containing the full gene for type II IMPDH were isolated and a physical map of 117 kb of human genomic DNA in this region of chromosome 3 was constructed. The gene for type II IMPDH was localized and oriented on this map and found to span no more than 12.5 kb.

1994-05-01

482

Chemistry and technology of radiation processed composite materials  

International Nuclear Information System (INIS)

Composite materials of synthetics (based on monomers, oligomers and thermoplastics) and of natural polymers (wood and other fibrous cellulosics) prepared by radiation processing, offer valuable structural materials with enhanced coupling forces between the components. The applied polymer chemistry of such composites shows several common features with that of radiation grafting. E.g. the polymerization rate of oligomer-monomer mixtures in wood remains in most cases proportional to the square-root of the initiating dose-rate, just as in the simultaneous grafting, demonstrating that the chain termination kinetics remain regularly bimolecular in the corresponding dose-rate ranges. In the processing experiences of such composites, low dose requirement, easy process-control, and good technical feasibility have been found for composites of wood with oligomer-monomer mixtures, for coconut fibres with unsaturated polyesters and for pretreated wood fibre with polypropylene.

1984-10-01

483

Chemistry and technology of radiation processed composite materials  

International Nuclear Information System (INIS)

Composite materials of synthetics (based on monomers, oligomers and thermoplastics) and of natural polymers (wood and other fibrous cellulosics) prepared by radiation processing, offer valuable structural materials with enhanced coupling forces between the components. The applied polymer chemistry of such composites shows several common features with that of radiation grafting, e.g. the polymerization rate of oligomer-monomer mixtures in wood remains in most cases proportional to the square-root of the initiating dose-rate, just as in the simultaneous grafting, demonstrating that the chain termination kinetics remain regularly bimolecular in the corresponding dose-rate ranges. In the processing experiences of such composites, low dose requirement, easy process-control, and good technical feasibility have been found for composites of wood with oligomer-monomer mixtures, for coconut fibres with unsaturated polyesters and for pretreated wood fibre with polypropylene. ...

1984-10-01

484

Chemical versus solvent extraction treatment: Comparison and influence on polyester based bio-composite mechanical properties  

British Library Electronic Table of Contents (United Kingdom)

The influence of chemical and solvent extraction compatibilising techniques on the mechanical properties of poly-lactic acid (PLA) and MaterBi-polyester (PEM) based bio-composites are compared. First, fibres were chemically grafted with two fatty chains: stearic anhydride and octadecylisocyanate. Grafted fibres were characterised by FTIR and elemental analyses. Contact angle measurements show the hydrophobisation of the fibres in spite of very low surface grafting. Extracted and non-grafted fibres were prepared to be used as references. PEM and PLA-based composites with 30% w/w were prepared by compression moulding. Their mechanical properties were studied. It was found that chemical and solvent treatment of the fibres improved the reinforcement effect in the case of a PEM matrix and the Y...

2010-01-01

485

Care programmes and integrated care pathways  

British Library Electronic Table of Contents (United Kingdom)

Purpose - The article discusses how care programmes and integrated care pathways can be linked, finding ways to improve healthcare process professional and logistical quality from a supply chain and a network point-of-view. Design/methodology/approach - The authors argue that owing to cost containment goals and increasing healthcare demand, healthcare services systems are challenged to improve service quality, whilst at the same time finding ways to improve delivery processes. It explores if the combination of two instruments, care programmes and integrated care pathways, can meet both goals. This combination is illustrated by an example from the Institute of Mental Health Care Eindhoven en de Kempen. Findings - Analysis suggests that care programmes can be combined with integrated care pa...

2008-01-01

486

CSSX Radiolytic H2 Generation ("Thermolysis") -- Final Report  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this work was to determine the radiolytic hydrogen gas yield of irradiated CSSX solvent at several temperatures. The active ingredient of this solvent is calix[4]arene-bis-(t-octylbenzo) crown-6, a calixarene crown ether used for cesium complexation. The solvent also contains 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol, a fluorinated alcoholic solvent modifer used to improve the solubility of the calixarene and its cesium complex in the Isopar L diluent. Isopar L is a branch-chain alkane and comprises most of the mixture. Samples of this solution were irradiated to various absorbed ?-ray doses in gas-tight sample containers, which were then sampled for hydrogen gas content. The methods are described below.

2009-01-01

487

CO2 maritime transportation  

British Library Electronic Table of Contents (United Kingdom)

The objective of this study is to describe the complete transport chain of CO2 between capture and storage including a ship transport. This last one is composed by the following steps:Shore terminal including the liquefaction, temporary storage and CO2 loading. Ship with a capacity of 30,000m^3. On or off shore terminal including an unloading system, temporary storage and export towards the final storage. Between all the possible thermodynamic states, the liquid one is most relevant two options are compared in the study (-50^oC, 7bar) and (-30^oC, 15bar). The ship has an autonomy of 6 days, is able to cover 1000km with a cargo of 2.5Mt/year. Several scenarios are studied varying the geographical position of the CO2 source, the number of harbours and the way the CO2 is finally stored. Depen...

2010-01-01

488

Beverage iodine levels in Germany  

British Library Electronic Table of Contents (United Kingdom)

Sales of iodized table salt (household use, bulk containers) have been flat in Germany since 1996/1997. Nevertheless, the amount of iodide excreted with the urine has been steadily increasing in the German population since 1993. We investigated the beverage iodine levels as possible source of the increased input of iodine into the food chain. No systematic studies on this topic have yet been carried out in Germany. A total of 510 samples were drawn from large grocery discounters who supply all German states with their products (35% fruit and vegetable juices, 35% beers, 10% pooled milk and yoghurt drinks, 10% mineral water, 10% soda). (1) Water-based beverage samples are prepared by solid-phase extraction and iodine concentration is determined by HPLC and electrochemical detection, (2) the...

2009-01-01

489

Anomalous properties of the local dynamics in polymer glasses  

CERN Document Server

The emergence of nanoscience has increased the importance of experiments able to probe the very local structure of materials, especially for disordered and heterogeneous systems. This is technologically important; for example, the nanoscale structure of glassy polymers has a direct correlation with their macroscopic physical properties. We have discovered how a local, high frequency dynamic process can be used to monitor and even predict macroscopic behavior in glassy polymers. Polyvinylethylenes vitrified by different chemical and thermodynamic pathways exhibit different densities in the glassy state. We find that the rate and amplitude of a high frequency relaxation mode (the Johari-Goldstein process involving local motion of segments of the chain backbone) can either correlate or anti-correlate with the density. This implies that neither the unoccupied (free) volume nor the configurational entropy governs the local dynamics in any general sense. Rather it is the ...

2008-01-01

490

Analysis of cerebrospinal fluid from chronic fatigue syndrome patients for multiple human ubiquitous viruses and xenotropic murine leukemia-related virus  

British Library Electronic Table of Contents (United Kingdom)

Abstract Recent reports showed many patients with chronic fatigue syndrome (CFS) harbor a retrovirus, xenotropic murine leukemia-related virus (XMRV), in blood; other studies could not replicate this finding. A useful next step would be to examine cerebrospinal fluid, because in some patients CFS is thought to be a brain disorder. Finding a microbe in the central nervous system would have greater significance than in blood because of the integrity of the blood-brain barrier. We examined cerebrospinal fluid from 43 CFS patients using polymerase chain reaction techniques, but did not find XMRV or multiple other common viruses, suggesting that exploration of other causes or pathogenetic mechanisms is warranted. Ann Neurol 2011;

2011-01-01

491

Analyses of uranium in some phosphate commercial products  

International Nuclear Information System (INIS)

The raw materials used in manufacturing of phosphate fertilizer products were derived from rocks. Rocks contain a remarkable of natural radioactivity. Uranium and phosphorous were originally initiated at the same time of the initiated rocks. The purpose of this research is to investigate solubility of uranium phosphate species at the phosphate fertilizer samples, samples including; raw phosphate material, single super phosphates (SSP) granules and powdered, triple super phosphates (TSP) and phosphogypsum samples were obtained from Abu-Zabal factory in Egypt. Solubility of uranium phosphate species was estimated. It was found that, less than half of the uranium phosphate species are soluble in water. The soluble uranium may be enter into the food chains by plant. Therefore, restriction should be done in order to limit contamination of land and the public.

2004-02-24

492

An new derivation of the Marshalek-Okubo realization of the shell-model algebra SO(2#nu#+1) for even and odd systems with #nu# single-particle levels  

International Nuclear Information System (INIS)

In recent years, the method for unitarizing nonunitary Dyson boson realizations of shell-model algebras has been both generalized and substantially simplified through the introduction of overtly group-theoretical methods. In this paper, these methods are applied to the boson-odd-particle realization of the algebra SO(2#nu#+1) for #nu# single-particle levels, adapted to the group chain SO(2#nu#+1) contains SO(2#nu#) contains U(#nu#), which Marshalek first derived by brute force summation of a Taylor expansion and later Okubo by a largely algebraic technique. (orig.).

493

An integrated oil and chemicals chain  

International Nuclear Information System (INIS)

Last year, 1991, was a difficult one for Finland's oil and chemicals company, Neste Corporation. The sharp fall in the international price of chemicals products had a significant impact on the corporation's overall result. Neste was, however, able to improve its competitive position, move ahead with numerous investments, and develop new businesses. This was particularly evident in two areas that have received significant emphasis within Neste in recent years: oil exploration and the Baltic region where a network of modern service stations in Neste livery and stretching from Vyborg on the Finnish-Russian border, through St. Petersburg, Tallinn, and the Baltic countries to Warsaw, is currently taking shape. The majority of the western-style stations in this network will be located along the route of the M12 highway, which has been dubbed the Via Baltica.

494

A new heuristic method for distribution networks considering service level constraint and coverage radius  

British Library Electronic Table of Contents (United Kingdom)

This paper presents a new mathematical model for designing distribution networks in a supply chain system considering service level constraint optimizing strategic decisions (location), tactical decisions (inventory), and assigning decisions. In real-world cases, demand, traveling time or any parameters in classical models may change over the period of time. So, considering uncertainty yields more flexibility for the results and the proposed model. In our study, environmental uncertainty is described by discrete scenarios. In this model, we have service level constraint in order to prevent inventory lost in distribution centers (DCs). Also, we assume that customer's demand is stochastic with Poisson distribution function and DCs have coverage radius constraints thus any DC cannot service a...

2009-01-01

495

Mucociliary transport and upper airway disease  

International Nuclear Information System (INIS)

Mucociliary transport so critical in nasal, paranasal sinus, and middle ear physiology is impaired in chronic sinsusitis and otitis media by factors such as increased mucus viscoelasticity, decreased ciliary area, and primary or secondary ciliary immotility. We reviewed the pathophysiology of primary ciliary dyskinesia, otitis media with effusion, chronic sinusitis, and allergic rhinitis in terms of mucociliary transport. Subjects with primary ciliary dyskinesia may experience recurrent middle ear infection, chronic airway infection, predominantly lower-lobe bronchiectasis, male sterility, or situs inversus. Primary ciliary dyskinesia is sometimes difficult to diagnose in cases without situs inversus. Nasal nitric oxide concentration in such patients decreases, although why is unclear. Mutations may involve dynein arm intermediate chain 1 (DNAI1) or dynein arm heavy chain 5 (DNAH5). Mucociliary clearance decreases more in those with otitis ...

2010-05-01

496

MHC-like molecules in some nonmammalian vertebrates can be detected by some cross-reactive xenoantisera.  

DEFF Research Database (Denmark)

Rabbit antisera raised to human and chicken MHC molecules were used to immunoprecipitate cross-reactive molecules from biosynthetically and cell surface-labeled spleen and/or blood cells of representative vertebrate species. Five major points emerged: 1) There were many nonspecific cross-reactions using these techniques, so various criteria were developed to distinguish these from true MHC-like molecules. 2) Only very small subpopulations of immunogen-specific antibodies cross-reacted with MHC-like molecules in other nonmammalian species. These subpopulations were different for each species and even within a species, sometimes being so limited as to behave like alloantisera. This led to a very scattered pattern of true cross-reactions that sometimes failed to reflect the properties of the bulk antibody population. 3) Antisera containing antibodies to class II beta- and class I alpha-chains cross-reacted better and more widely than those to B-G, class II alpha and, ...

1990-01-01

497

Life-cycle assessment of straw use in bio-ethanol production: A case study based on biophysical modelling  

Energy Technology Data Exchange (ETDEWEB)

Cereal straw, a by-product in the production of agricultural crops, is considered as a potentially large source of energy supply with an estimated value of 47 x 10{sup 18} J worldwide. However, there is some debate regarding the actual amounts of straw which could be removed from arable soils without jeopardizing their quality, as well as the potential trade-offs in the overall straw-to-energy chain compared to the use of fossil energy sources. Here, we used a deterministic model of C and N dynamics in soil-crop systems to simulate the effect of straw removal under various sets of soil, climate and crop management conditions in northeastern France. Model results in terms of nitrate leaching, soil C variations, nitrous oxide and ammonia emissions were subsequently inputted into the life-cycle assessment (LCA) of a particular bio-energy chain in which straw was used to generate heat and power in a plant producing bio-ethanol from wheat grains. ...

2008-05-15

498

Formation and stabilization of anionic metal complexes in concentrated aqueous quaternary ammonium salt solutions  

Energy Technology Data Exchange (ETDEWEB)

Anionic complexes of transition metals were stabilized in aqueous solutions containing high concentrations of various short-chain quaternary ammonium salts. Compounds with longer paraffin chains were effective in much less concentrated solution. Complex ions were detected spectrophotometrically. FeCl/sub 4//sup -/, which is usually formed in concentrated HCl, was the predominant Fe(III) complex in 30 m choline chloride containing only 0.12 M HCl. A yellow transitory Tc(VII) chloro-addition intermediate, formed in the reduction of TcO/sub 4//sup -/ by concentrated HCl, was stabilized when the solution also contained 25 m choline chloride. Its spectrum, as well as the isolation of an already known Tc(VII) bipyridyl complex, is reported. Concentrated organic electrolytes also stabilized Tc(V) oxide halides against disproportionation and Tc(IV) hexahalides against hydrolysis. Halochromates of Cr(VI) were formed and stabilized in dilute acid ...

1985-02-04

499

Energy and CO{sub 2eq} analysis of the agricultural phase in the sunflower biodiesel chain  

Energy Technology Data Exchange (ETDEWEB)

The suitability of the sunflower for biodiesel production was discussed in terms of the reference values on carbon dioxide equivalents (CO{sub 2eq}) emissions for every phase of the biofuels chain as indicated in the European Union (EU) Directive on renewable energies. A life cycle analysis performed on the agricultural phase of the sunflower showed that CO{sub 2eq} emissions from the cultivation phase exceeded the EU reference value. This paper highlighted the relevance of allocation methods to spread out energy consumption and CO{sub 2eq} emissions among sunflower biodiesel and oilcake. Allocation was made according to the principles of mass content, energy content and the economic value of co-products. The CO{sub 2eq} reductions obtained with the 3 methods were approximately 60, 50 and 25 per cent, respectively when compared to a case without allocation. Since these methods did not distinguish the different functionality of co-products in relation to their real ...

2010-07-01

500

Chlorophyll assembled electrode for photovoltaic conversion device  

Energy Technology Data Exchange (ETDEWEB)

Chlorophyll-a (Chl-a) assembled in hydrophobic domain by fatty acid with long alkyl hydrocarbon chain such as myristic acid (Myr), stearic acid (Ste) and cholic acid (Cho) modified onto nanocrystalline TiO{sub 2} electrode is prepared and the photovoltaic properties of the nanocrystalline TiO{sub 2} film by Chl-a are studied. Incident photon to current efficiency (IPCE) value at 660 nm in photocurrent action spectrum of Chl-a/Ste-TiO{sub 2}, Chl-a/Myr-TiO{sub 2} and Chl-a/Cho-TiO{sub 2} electrodes are 5.0%, 4.1% and 4.1%, respectively. Thus, the IPCE is maximum using Chl-a/Ste-TiO{sub 2} electrode. From the results of photocurrent responses with light intensity of 100 mW cm{sup -2} irradiation or monochromatic light with 660 nm, generated photocurrent increases using Chl-a/Ste-TiO{sub 2} electrode compared with the other Chl-a assembled TiO{sub 2} electrodes. These results show that the hydrophobic domain formed by stearic acid with long alkyl hydrocarbon ...

2007-11-20