Energy Technology Data Exchange (ETDEWEB)

Iodine-125 labelled vinyl and aryl iodides are formed via the reaction of sodium iodide-125 with vinyl- and arylboronic acids. Good yields of isomerically pure products are obtained.

International Science & Technology Center (ISTC)

Development of the Technology to Obtain Pure Metal Scandium by Thermal Decomposition of Scandium Iodide

International Nuclear Information System (INIS)

This patent describes the producing of a refractory metal wherein a sponge refractory metal is produced as an intermediate product by the use of magnesium with the incidental production of magnesium chloride, and wherein residual magnesium is separated from the magnesium chloride and from refractory metal to a vacuum distillation step which fractionally distills the magnesium, the magnesium chloride, and the metal sub-chlorides; the steps of: recovering fractionally distilled vapors of magnesium chloride and metal sub-chlorides from a sponge refractory metal; separately condensing the vapors as separately recovered; and recycling the separately recovered magnesium at a purity of at least about 96%.

Energy Technology Data Exchange (ETDEWEB)

Recent developments on plastic forming technology of magnesium alloys are presented. Attempts have been undergoing with an aim at forming magnesium alloy parts at lower temperatures. It is believed that fine microstructure magnesium alloys usually have much higher plasticity at lower temperatures and even room temperatures. Extrusion is a method to form magnesium profile products and tube products, which is also one of the effective ways to make fine microstructure magnesium alloys. Superplasticity forming is another method to form high plasticity magnesium alloys. Hot forming of magnesium sheet parts is an important process to form magnesium products. Some developments related to above issues are discussed in the present paper. (orig.)

Energy Technology Data Exchange (ETDEWEB)

Gas and plasma nitriding processes were executed in the magnesium with modification by titanium in search for an effective surface treatment method for magnesium alloys. Magnesium-nitrogen system has completely no solid solution or solubility, so that nitride should be only formed by eutectic reaction in the liquid phase. Hence, magnesium is difficult or nearly impossible to have its surface modified by nitriding. Addition of nitride forming element into magnesium enables us to lower the onset temperature of nitriding. Magnesium-titanium alloys with 1 to 5 wt% are yielded by the bulk mechanical alloying and, subjected to gas nitriding for various process conditions. Successful co-formation of Mg{sub 3}N{sub 2} as well as TiN becomes a proof to demonstrate the possibility of gas/plasma nitriding in the solid-state magnesium with aid of ...

Energy Technology Data Exchange (ETDEWEB)

Using commercial AZ31 magnesium alloy sheets, we produced a foamable preform sheet containing titanium hydride (TiH{sub 2}) powder through diffusion-bonding and hot-rolling of four cycles. Heating the preform sheets in Ar atmosphere, we obtained closed-cell magnesium alloy foams with various porosities. The foamed specimen at 883 K showed the maximum porosities of 77%. (orig.)

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

Energy Technology Data Exchange (ETDEWEB)

The preparation and luminescence properties of crystal phosphors based on alkali metal iodide and calcium oxide substrates were studied. The highest luminescence intensities were achieved with iodide substrates at 200/sup 0/ and with the calcium oxide substrate at 800/sup 0/. The calibration graphs were linear in the thallium concentration ranges 0.03-5.0 and 0.1-2.0 mu g using sodium and potassium oxides, respectively, and in the range 0.05-5 mu g using cesium iodide and calcium oxide. A method is proposed for the determination of down to 3 x 10/sup -4/% thallium in rocks, using a crystal phosphor with sodium iodide substrate.

Energy Technology Data Exchange (ETDEWEB)

Magnesium alloys show a high specific strength and are therefore increasingly used for light-weight constructions in transportation industry.{sup [1,2]} To predict the behaviour of the material under the influence of cyclic loading it is vital to understand the fatigue behaviour of magnesium alloys. Only when understood properly, it is possible to fully apply the potential weight reduction by using magnesium alloys. A very important aspect in fatigue of magnesium alloys is the influence of a corrosive media and elevated temperatures, of which both are relevant in automotive applications. These two factors tend to have deleterious effects on magnesium alloys and therefore also have to be considered in investigations on the fatigue behaviour of magnesium alloys. (Abstract Copyright [2004], Wiley Periodicals, Inc.)

International Nuclear Information System (INIS)

A method for converting organic iodides to elemental iodine would be advantageous in improving the performance of charcoal filters for the removal of radio iodines from reactor off gases. A photochemical method has been developed. The HAVCHM code was used to establish the relevant process time scales on a complete set of rate equations describing the primary and secondary reactions occurring in a plug-flow reactor containing low levels of elemental iodine and methyl iodide in air, which is irradiated by intense u.v. light. These simulations were used to justify the contraction of the complete set of reactions to the most significant elementary processes. The contracted set of rate equations are then solved analytically to render the concentration-time profiles of methyl iodide, total inorganic iodine and total oxidized organics, consistent with the achievement of a desirable radioiodine decontamination factor. For the short ...

Energy Technology Data Exchange (ETDEWEB)

Plastic formability of cast magnesium alloy that were hot rolled after roll strip casting was investigated to ascertain the feasibility of semi-solid strip casting process of AZ31B magnesium alloy. Hot rolling and heat treatment conditions were changed to examine which conditions were appropriate for producing AZ31B wrought magnesium alloys after strip casting process. Microscopic observation of the crystals of the manufactured wrought magnesium alloys was performed. It has been found that a limiting drawing ratio of 2.7 was possible in a warm deep drawing test of the cast magnesium alloy sheets after being hot rolled. (orig.)

UK PubMed Central (United Kingdom)

OBJECTIVE--To examine the effect of a reduced sodium and increased potassium and magnesium intake on blood pressure. DESIGN--Randomised double blind placebo controlled trial. SETTING--General population...Full Text Available

Science.gov (United States)

... Both magnesium and aluminium phosphides are therefore potentially more efficient than either calcium or sodium phosphide. ...

Energy Technology Data Exchange (ETDEWEB)

Two extruded magnesium alloys, AZ31 and AZ61 were selected to evaluate the influence of process parameters on the material forgeability. The processing parameters considered for forging magnesium alloys were: compression load in the range 55 KN to 60 KN and forging temperature, in the range of ambient temperature to 300 C. Uniaxial compression tests were conducted to establish the strain-temperature relationship. The influences of process parameters on the microstructure were also evaluated. (orig.)

Energy Technology Data Exchange (ETDEWEB)

Measurements of the double-electron-capture process in which a positive ion of iodine becomes a negative ion in a single collision with a magnesium atom are reported between 20 and 90 keV. The cross section is comparable to that for the rare gases and not as large as might be expected from a two-valence-electron atom. This process is probably insignificant in the production of negative ion beams using a magnesium-vapor target.

British Library Electronic Table of Contents (United Kingdom)

Corrosion inhibition of iron in H2SO4 by polyacrylic acid (PAA) was investigated using electrochemical techniques at 30degreeC. Results obtained indicate that PAA inhibited the corrosion of iron in the acid medium. Inhibition efficiency increases with increase in PAA concentration and synergistically enhanced on addition of iodide ions. Potentiodynamic polarization results suggest that PAA functions as a modest cathodic inhibitor. The adsorption of PAA onto the iron surface followed Temkin adsorption isotherm. FTIR analysis revealed that the synergistic effect due to co-adsorption of iodide ions and PAA is co-operative in nature.

Energy Technology Data Exchange (ETDEWEB)

This paper deals with an experimental study of ultra-precision diamond cutting of magnesium alloy (AZ31). In order to investigate the machinability such as the cutting force and the surface integrity and understand the problems in a micro cutting, the experiments on the diamond cutting of magnesium alloy and pure aluminum with an ultra-precision turning machine has been carried out. The machinability of magnesium alloy was compared with that of pure aluminum and discussed. Consequently, both the thrust force component and the surface roughness obtained by cutting of magnesium alloy became larger than that of pure aluminum. It was also found that the inclusions or the defects in the work material caused to generate the scratches on the finished surface and influenced the integrity of mirror surface. (orig.)

International Nuclear Information System (INIS)

One of the most effective removing processes of iodine species is what is called ''Iodox Process'', which contains oxidation and absorption of iodine species by highly concentrated nitric acid. The result of fundamental test with bubble column in this process had been reported. Present paper describes the fundamental experiment by the use of packed column. This experiment has been carried out to clear the effect of feed gas flow rate, nitric acid flow rate, nitric acid concentration, and methyl iodide concentration on removal efficiency of methyl iodide. The following results were obtained. The decontamination factor of methyl iodide (DF) increases exponentially with nitric acid concentration, which agrees with the result obtained by using the bubble column. The factor is in inverse proportion to feed gas flow rate, and is also almost independent of nitric acid flow rate and methyl iodide concentration. ...

International Nuclear Information System (INIS)

An earlier representation of the radial distribution of dose about the path of a heavy ion in liquid water is modified and extended to include silicon, lithium fluoride, and sodium iodide. 6 refs., 5 figs., 1 tab.

International Nuclear Information System (INIS)

The ion mobilities of |"2"1"1At|At(I) in dependence on thiourea (tu) concentration, iodide concentration and a mixture of both ligands were measured by the electromigration method in free electrolytes. An equilibrium model was developed for the characterization of electromigration curves which permitted the calculation of stability constants and ion mobilities of the complexes |AtI|, |AtI_2|"-, |Attu|"+, |Attu_2|"+ and |AtItu| existing in these solutions. Ethanol and water served as solvents. The temperature was 298 K and the ionic strength was about 0.05 mol/dm"3. (author) 16 refs.; 2 figs.

Science.gov (United States)

We present a sample preparation method for measuring magnesium in individual whole lymphocytes by electron probe X-ray microanalysis. We use Burkitt's lymphoma cells in culture as the test sample and compare X-ray microanalysis of individual cells with atomic absorption analysis of pooled cell populations. We determine the magnesium peak-to-local continuum X-ray intensity ratio by electron probe X-ray microanalysis and calculate a mean cell magnesium concentration of 39 +/- 19 mmol/kg dry weight from analysis of 100 cells. We determine a mean cell magnesium concentration of 34 +/- 4 mmol/kg dry weight by atomic absorption analysis of pooled cells in three cell cultures. The mean cell magnesium concentrations determined by the two methods are not significantly different. We find a 10% coefficient of variation for both methods of analysis and a 30% coefficient of variation in ...

International Nuclear Information System (INIS)

The development of light-weight vehicle is in great demand for enhancement of fuel efficiency and dynamic performance. The vehicle weight can be reduced effectively by using lightweight materials such as magnesium alloys. However, the use of magnesium alloys in sheet forming processes is still limited because of their low formability at room temperature and the lack of understanding of the forming process of magnesium alloys at elevated temperatures. In this study, uniaxial tensile tests of the magnesium alloy AZ31B-O at various temperatures were performed to evaluate the mechanical properties of this alloy relevant for forming of magnesium sheets. To construct a FLD (forming limit diagram), a forming limit test were conducted at temperature of 100 and 200 deg. C. For the evaluation of the effects of the punch temperature on the formability of a rectangular cup drawing with AZ31B-O, ...

Energy Technology Data Exchange (ETDEWEB)

Magnesium is known to have poor formability at room temperature, mainly attributed to its hexagonal lattice structure. This paper presents the findings generated from development of warm forming to produce thin-walled magnesium components. Finite element analysis was conducted to evaluate the formability of the material and the simulated results were compared to the tensile results and product formability. Tensile tests were used to verify the formability of the sheet metal at difference temperatures. The process parameters considered in the feasibility study were forming temperature, in the range of 28 C to 300 C and magnesium sheet (AZ31B-H24) thickness, in the range of 0.4 mm to 1 mm. Magnesium hand phone covers of a thickness down to 0.4 mm have been successfully produced. The feasible forming temperature was found to be between 200 C and 250 C. Metallographic examination shows evident of ...

Energy Technology Data Exchange (ETDEWEB)

A chromium-free conversion coating for magnesium alloys were described. The conversion coating could be obtained when AZ31D magnesium alloy was immersed in a solution containing a manganese salt, phosphate and an inhibitor. Corrosion resistance of the chemical conversion coating was evaluated by anodizing polarization curve and salt immersion. XRD analysis showed that the conversion coating was mainly composed of Mn{sub 3}(PO{sub 4}){sub 2}. The morphology of the coating is observed by using SEM. The effect of electrolyte pH and concentration of inhibitor on coating growth are investigated. (orig.)

Science.gov (United States)

... alloys--Lanthanum-- Magnesium--Magnasium &11oy8--Hagn*31Uft compounds--Manxganese--Manganes. alloys-- Mercury ...

International Nuclear Information System (INIS)

Magnesium alloys have been increasingly used in automotive and electronic industries because of their excellent strength to weight ratio and EMI shielding properties. However, magnesium alloys have low formability at room temperature due to their unique mechanical behavior (twinning and untwining), prompting for forming at an elevated temperature. In this study, a temperature dependent constitutive model for magnesium alloy (AZ31B) sheet is developed. A hardening law based on non linear kinematic hardening model is used to consider Bauschinger effect properly. Material parameters are determined from a series of uni-axial cyclic experiments (T-C-T or C-T-C) with the temperature ranging 150-250 deg. C. The influence of temperature on the constitutive equation is introduced by the material parameters assumed to be functions of temperature. Fitting process of the assumed model to measured data is presented and the results are ...

International Nuclear Information System (INIS)

One of the major concerns during high speed welding of magnesium alloys is the presence of porosity in the weld metal that can deteriorate mechanical properties. This study seeks to analyze the presence method and quantity of pore during hybrid laser-tungsten inert gas arc (TIG) welding of magnesium alloy AZ31B by radiography, optical microscopy and electron probe microanalysis (EMPA). At the same time, it identifies both the mechanism of pore formation and a remedy for this problem. The experimental results indicate that lacking of shielding gas for laser beam is the dominant cause of macroporosity formation during the hybrid of laser-TIG welding of magnesium Alloys AZ31B plate, and hydrogen is not main cause to form large pores. A favorable weld without porosity can be obtained by appending lateral shielding gas for laser beam.

Energy Technology Data Exchange (ETDEWEB)

In this paper, for an acceleration of utilization of magnesium alloy which is being interested in recent years, friction welding of AZ31 magnesium alloy was carried out, and the joint performance was discussed in relation to the deformation heat input in the upset stage and upset loss as a evaluation factor. Where, the deformation heat input in the upset stage is mechanical work represented by the product of upset speed and axial pressure. As a result, it was made clear that the friction welding of AZ31 magnesium alloy was easy in the atmosphere, and good welded joints without a non- adhesion area at the weld interface could de obtained. Moreover, the evaluation factors discussed were possible to evaluate to joint performance. (orig.)

British Library Electronic Table of Contents (United Kingdom)

A microanalytical characterization of cast magnesium alloys of eutectic origin based on the Mg?Al?Ca ternary matrix system has been carried out in order to investigate the influence of alloying elements on their microstructure as well as microchemistry-processing-microstructural relations using structure-sensitive techniques of electron microscopy, mechanical spectroscopy (internal friction), X-ray diffractometry, and advanced microanalytical methods including electron probe compositional analysis. Following the data obtained here there is direct correlation of microstructure with creep properties of the new experimental magnesium alloys. The creep and heat-induced properties of the multicomponent magnesium alloys containing low range of inexpensive additions of titanium (0.07?0.2%) or str...

Energy Technology Data Exchange (ETDEWEB)

Although magnesium is not attacked by hydrocarbons, it reacts vigorously with anhydrous methanol, raising concerns about the compatibility of the metal with methanol blend fuels. This paper describes the behavior of magnesium alloys in laboratory tests in static contact with methanol-containing fuels at 110/sup 0/F. Water in small concentrations (above 0.25% by weight of the methanol content) is shown to prevent the destructive attack of magnesium by these fuels. The required water content is well within the water tolerance of methanol-GTBA (gasoline grade tertiary-butyl alcohol) cosolvent fuel blends. Die cast AZ91HP shows greater resistance to methanol reaction than does AZ31B sheet.

Energy Technology Data Exchange (ETDEWEB)

A new technique was proposed in order to improve poor corrosion resistance in magnesium. That is, magnesium hydroxide film was formed on the surface of 3 N-Mg by artificial corrosion in 1% MgCl{sub 2} solution for 3.6 ks, which followed by oxidation at 673 K for 3.6 ks in air. Corrosion resistance was evaluated by salt immersion tests in 1% NaCl solution under in situ laser microscopic observations. Bubble evolution, which occurred immediately at the beginning of the immersion test in the case of non-treated specimen, was suppressed by the process. And also, formation of filiform corrosion was suppressed for about 3.6 ks, which occurred at 180 s in the non-treated specimen. (orig.)

Science.gov (United States)

In view of the effect of the acidity on the oxidation potentials of nitrous, arsenous, and arsenic acids, one should expect a complex relationship between the rate of arsenic (III) to arsenic (V) and the pH of the solution. They studied the kinetics of the reaction 2AsO/sub 2//sup -/ + O/sub 2/ ..-->.. 2AsO/sub 3//sup -/ as functions of concentrations (partial pressure) of all the components of the system NaAsO/sub 2/-HCl(HClO/sub 4/)-NaNO/sub 2/-KI-H/sub 2/O-O/sub 2/ and temperature. The study of the kinetics of arsenic(III) oxidation to arsenic(V) with oxygen in the presence of sodium nitrite and iodide ions showed that the reaction rate passes through a maximum at an acid content of 1.2-2.5 M and rises in proportion to the second exponent of the sodium nitrite concentration and to the first exponent of the iodide ion concentrations and partial oxygen pressure. A fall in the temperature facilitates intensification of the process and ...

Energy Technology Data Exchange (ETDEWEB)

Magnesium alloys and composites are potentially highly attractive materials for lightweight design in the automotive industry - if common forming technologies, i.e., deep drawing and cold extrusion, are applicable to them; so far, this is seldom the case. The authors have tested some candidate Mg alloys and discuss the results of their measurements in detail. The Figure shows a typical workpiece part obtained by a deep-drawing technique. (Abstract Copyright [2003], Wiley Periodicals, Inc.)

International Nuclear Information System (INIS)

Self-assembled monolayer (SAM) of histidine (His) was prepared on copper surface at various pH values. The effect of KI additives on corrosion protection efficiency of His SAM was also studied. The protection abilities of these films against copper corrosion in 0.5 M HCl aqueous solution were investigated using electrochemical impedance spectroscopy and polarization techniques. The results show that the film formed on the electrode is more stable at pH = 10 than that at other pH values. When the iodide ions were added into the His self-assembly solution (pH = 10), protection efficiency was further improved. The inhibition mechanism has been discussed by quantum chemical calculations.

International Nuclear Information System (INIS)

A kind of polymer-metal complex gel electrolyte is successfully prepared and is used in dye-sensitized solar cells. Raman and X-ray photoelectron spectroscopy confirm the structure of this complex and is found that the metal ion reacts with nitrogen in the polymer. This novel electrolyte shows apparent diffusion coefficient of iodide of 8.37 x 10-7 cm2 s-1 and the energy conversion efficiency of 6.10% when the amount of ZnI2 is 0.04 M. By studying the dissociation active energy of the inorganic salt in electrolytes, we find that the metal salts can dissociate more easily after reacting with polymer and as a result can provide extra free iodide ion. The cell maintains ca. 93% of its initial efficiency after 20 d without further sealing, which shows good long-time stability.

Energy Technology Data Exchange (ETDEWEB)

PVD-chromium-nitride coated samples of substrates of the magnesium alloy AZ91hp and the roller and ball bearing steel 100Cr6 were investigated regarding structure, mechanical characteristics, adhesion and internal stresses. For the coatings the parameters layer thickness and substrate BIAS voltage were varied. Both substrate materials were coated in one lad. Results of the X-ray analysis of the internal stresses show significant differences between the coated magnesium and the coated steel substrates. In the case of the variation of the substrate BIAS voltage, for the coated steel a dependency of the internal stresses to coating parameters could be obtained. For the coated magnesium no dependency was recognizable. The coating structure was examined with scanning electron microscopy. Element depth profiles of the coated samples were performed with SIMS. (orig.)

International Nuclear Information System (INIS)

Possibility for using a sodium iodide scintillator as a reference signal source is considered. Experimental data on studying the performance of a gamma thickness gage with an additional scintillator are given. Results of experimental investigations of a thickness gage dummy proved practical expediency of the principle being considered. It is established, in particular, that the device is ready to operate without warm-up with a constant sensitivity, the deviation not exceeding 0.5%, in the ambient temperature range of 15-25 deg C.

Energy Technology Data Exchange (ETDEWEB)

The results of Sandia National Laboratories' participation in the NASA Planetary Definition and Design Program are summarized. Areas reported include the characterization of large area cadmium zinc telluride spectrometers and the application of simulation techniques to the prediction of device performance. Also investigated was the response of mercuric iodide devices in the region from 1 to 100 KeV. A literature study to determine the status or radiation damage measurements in room temperature semiconductor devices is also reported.

Energy Technology Data Exchange (ETDEWEB)

A synergistic effect exists when benzotriazole (BTAH) and iodide ions are used together to prevent the corrosion of copper in sulfuric acid. The nature of this effect has been studied systematically by using electrochemical techniques and X-ray photoelectron spectroscopy. The synergistic effect is due largely to the formation of a film of Cu(IBTA) complex and is probably polymeric in nature. This new complex film greatly depresses copper dissolution.

Energy Technology Data Exchange (ETDEWEB)

Magnesium alloys are ideal candidates to benefit from equal channel angular extrusion (ECAE) because of their poor forming characteristics due to a hcp structure. In this study, ECAE processing was applied to ZK31 and AZ31 magnesium alloys under various conditions. The grain size of as-ECAE specimens decreases with decreasing the processing temperature, however, the grain size decreases slightly with increasing number of repetitive processing. Both the tensile strength and 0.2% proof stress of as-ECAE specimens are high when processed at low temperature, but the elongation is high when processed at high temperature. Crystal orientation is different in the two alloys and it also varies according to the processing temperature for the two alloys. The difference of the crystal orientation influences the tensile properties, especially 0.2% proof stress. (orig.)

Energy Technology Data Exchange (ETDEWEB)

Applications of magnesium alloys are motivated mainly by their lightweight. However, manufacturing cost should also be evaluated when considering applying them. From this point of consideration, adoption of sheet forming processes, which previously have not been heavily researched, should be an option. This paper is intended to pioneer the study of the formability of magnesium alloy AZ31 out of rolled sheets at elevated temperatures. The rolled microstructures are examined and correlated with their formability. Post-forming conditions will also be investigated. The tool employed to perform the sheet forming experiments was a punchless die-setting which used pressurized gas to press the sheet into a female die cavity. This technique applied to Mg-alloy is unconventional and warrants attention for its potential utilization in the industry. (orig.)

Energy Technology Data Exchange (ETDEWEB)

We conduct the static and dynamic loading fracture experiments on magnesium alloy (AZ31B) under the equitable and inequitable biaxial stress. We process specimens as cross type with cracks. There are different kinds of cracks defined by their crack angles. By using a hydraulic high-speed biaxial experiment machine, we put the equitable and inequitable stresses on the specimen. We analyze results using the caustic method. The experiments reveal a few important results. There is negative correlation between the fracture toughness value and the plate thickness in the magnesium alloy sheet specimen. The fracture toughness value decrease in the case the crack has the angle different from the loading direction. The fracture toughness value decreases significantly under the inequitable biaxial stress. (orig.)

International Nuclear Information System (INIS)

Luminescence and reflection spectra as well as luminescence kinetics of the 1 mol% Sm3+-doped crystalline lanthanum magnesium meta borate (LaMgB5O10) and gadolinium magnesium meta borate (GdMgB5O10) were analyzed. Materials were synthesized by conventional solid state route and showed bright orange-red emission under UV excitation. Emission spectra contain sharp and well resolved Sm3+4G5/2#->#6HJ transitions indicating a strong crystal-field effect. In case of gadolinium compound energy transfer between Gd3+ and Sm3+ was detected. The luminescent kinetics of the Sm3+ in analyzed powders is characterized by single exponential decay and experimental values vary in the range 2.2-2.4 ms. - Research highlights: ? Phosphorescence of samarium-doped lanthanide magnesium meta borates. ? Bright and well resolved orange-red emission of Sm3+ under UV excitation. ? Energy transfer from Gd3+ to Sm3+ in gadolinium ...

Energy Technology Data Exchange (ETDEWEB)

The aim of this study as to determine the mechanisms involved in using ammonium fluoborate as a reducing atmosphere when preheating a high magnesium content aluminium alloy. Rutherford Backscattering (RBS) has been the major technique used in the analysis of samples, it revealed significant reduction in both the diffusion of magnesium to the surface and the calculated oxide thickness in the presence of NH{sub 4}BF{sub 4}. At temperatures above 500 deg C in air, SEM images revealed depressions and voids due to incipient melting at various stages, around the grain boundaries. Grain boundaries effectively acted as pipes aiding the diffusion of magnesium to the surface. These results have been verified through compositional analysis with both RBS and auger electron spectroscopy (AES). Results from NH{sub 4}BF{sub 4} atmosphere preheat conditions showed significant improvements. It was verified experimentally that above 500 deg ...

Science.gov (United States)

The catalytic effects of copper-aluminium-magnesium oxides in the oxidative coupling of phenylethyne is described. The importance of surface properties as a redox site are discussed.

UK PubMed Central (United Kingdom)

A novel therapeutic compound was found to induce bladder tumors in male rats. Given the location of the tumors and the increased amounts of calcium- and magnesium-containing solids found in the urine...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The possibility of improving the cold formability of wrought magnesium alloys is considered in light of their good hot forming characteristics. Magnesium alloy AZ31B sheet is selected as a model system. Parameters affecting formability, such as strain hardening rate, strain rate sensitivity, and the degree of anisotropy are examined systematically by conducting tensile tests over a range of temperatures (room temperature to 250 C) and strain rates (1 x 10{sup -5} to 0.1 s{sup -1}). The plastic anisotropy and deformation texture evolution are examined in samples aligned with the sheet rolling and transverse directions. Polycrystal plasticity simulations using a viscoplastic self-consistent (VPSC) formulation are used to model the observed anisotropy and texture evolution. The adjustable parameters in the model are the relative critical resolved shear stresses of the dislocation mechanisms known to operate within magnesium. ...

International Nuclear Information System (INIS)

Chemical and phase homogeneity of titanium-niobium sponge, produced by a combined magnesium-thermic reduction of niobium pentachloride and titanium tetrachloride mixtures, is investigated. It is ascertained that a sponge consists of spherical shape particles and has a large number of pores. Particle sizes are reduced with niobium being substituted for titanium from 50-500 #mu#m for titanium sponge to 1-40 #mu#m for niobium one, which testifies to the bormation in a titanium-niobium sponge of an alloy and not a mechanical mixture. A number of solid solutions is detected by X-ray phase analysis. Lattice parameters are determined.

British Library Electronic Table of Contents (United Kingdom)

A new coumarin-based sensor molecule (L1) has been synthesized and this was found to bind calcium and magnesium ions more effectively as compared to other alkali/alkaline earth/lanthanide and certain transition metal ions. A significant enhancement in fluorescence intensity was observed on binding to Ca2+ and Mg2+ ions; while a minor quenching was observed for weakly bound Hg2+, Ni2+, Fe3+, and Co2+ ions. PET process, coupled with the ICT process, is proposed to explain the observed spectral response.

Energy Technology Data Exchange (ETDEWEB)

Optimum conditions for microstructural control in industrial hot working of cast and homogenized AZ31 magnesium alloys are evaluated by using a processing map. The recommended window for bulk metal working of this alloy is the domain in the temperature range 300-450 C and strain rate range 1-10 s{sup -1}, and the optimum processing parameters are 400 C and 10 s{sup -1}, where grain-boundary self diffusion is the rate-controlling mechanism. (Abstract Copyright [2009], Wiley Periodicals, Inc.)

Energy Technology Data Exchange (ETDEWEB)

The superplastic characteristics and diffusion bonding behaviors were investigated in commercial 7475 aluminum alloy and AZ31 magnesium alloy sheets. In this study, the presently used materials behaved in a superplastic manner at {proportional_to} 773 K (7475Al) and {proportional_to} 523 K (AZ31). Then, by the theoretical relationship between pressure and time, these materials were successfully diffusion bonded at the superplastic temperatures. The bonding strength was more than 65 MPa. The experimental bonding conditions in high quality joining, times and pressures, were good agreed with prediction analysis. (orig.)

International Nuclear Information System (INIS)

The fabrication and complete evaluation are described of a dihydropyridine in equilibrium pyridinium salt type redox system for the delivery of radioiodinated agents to the brain. The pivotal intermediate, N-succinimidyl (1-methylpyridinium iodide)-3-carboxylate was prepared by condensation of nicotinic acid and N-hydroxysuccinimide in the presence of dicyclohexylcarbodimide, followed by quaternization of III with methyl iodide. Tissue distribution studies of "1"2"5I-labeled 4-iodoaniline and the redox agents were performed in rats. ["1"2"5I]Iodoaniline initially showed moderate (0.58% dose/gm) brain uptake with subsequent release of the radioactivity from the brain. ["1"2"5I]Iodoaniline, when coupled to a dihydropyridine carrier showed higher uptake and retention in the brain. The ["1"2"5I]iodophenylethyl analogue showed uptake and retention in the brain to be very similar. Apparently the lipophilic agents cross the blood-brain barrier and are ...

Energy Technology Data Exchange (ETDEWEB)

A solid electrolyte cell comprises an alkali metal anode, e.g. lithium, a halogen-containing organic polymer cathode and a solid elecrolyte between the anode and the cathode. The cathode comprises iodine-containing vacuum-cyclised polyacrylonitrile, and the solid electrolyte is preferably lithium iodide and halogen-free vacuum-cyclised polyacrylonitrile. This patent also discloses the use of isotactic polyacrylonitrile, a method of making a cathode comprising iodine-containing vacuum-cyclised polyacrylonitrile, and novel methods of making the solid elecrolyte cells described.

Energy Technology Data Exchange (ETDEWEB)

This patent describes a process for preparing poly(aryl ether ketones) by nucleophilic displacement polymerization in the presence of at least one alkali metal base selected from potassium, rubidium or cesium, and fluoride ions, which comprises adding to the polymerization: (a) an effective amount of at least one metal salt selected from lithium, sodium, alkaline earth or lanthanide chloride, bromide, iodide, sulfate, alkyl or aryl carboxylate, cyanide, borate or phosphate to slow or stop advancement of molecular weight and (b) an end-capping agent.

International Nuclear Information System (INIS)

This work showed the formation of phospholipid vesicle coating on inorganic sericite surface with characterization by combining electron microscopy of FE-SEM, TEM, AFM, and qualitatively evaluated the coated phospholipid vesicle by XPS as a function of etching time. The possibility of phospholipid vesicle mobility on the surface was restrained by the chelation effect of magnesium cation. The stabilization properties of phospholipid vesicles on sericite surface were demonstrated by the various concentration of magnesium cation. The presence of magnesium was found to have a much more pronounced influence on the lipid deposition process. The Mg cation plays an important role for attaching the phospholipids with optimum concentration of 7 mM. Totally, the phospholipid vesicles coating on inorganic powder could be useful for bio-related fields such as cosmetics and drug delivery system as the key functional compounds. We hope ...

International Nuclear Information System (INIS)

In the present work the hydrogen desorption properties of nanostructured magnesium hydride (MgH2) synthesized by controlled reactive mechanical milling (CRMM) of elemental Mg powder under hydrogen are investigated. A profound effect of the particle size of synthesized MgH2 hydride on its hydrogen desorption characteristics measured by differential scanning calorimetery (DSC) has been found. All synthesized MgH2 powders are characterized by a double hydrogen desorption peak. Furthermore, below a certain threshold particle size the DSC desorption temperature of the peak doublet starts decreasing rapidly with decreasing of the mean hydride powder particle size (expressed as equivalent circle diameter-ECD). In contrast, the nanograin (crystallite) size of MgH2 does not seem to have apparent effect on the DSC desorption temperature. It is also observed that for powder particles smaller than some threshold value, X-ray diffraction shows the presence of two polymorphic ...

International Nuclear Information System (INIS)

In situ spectroscopic ellipsometry was employed to investigate the initial regime of rare earth metal (REM) conversion coatings formation on AZ31 magnesium alloy. Three REM salts solutions, 0.05 mol.dm"-"3 Ce(NO_3)_3, La(NO)_3 and Sm(NO)_3 solutions, were used for REM conversion coatings preparation. By deconvoluting the ellipsometric data, the surface of the fresh well-polished AZ31 magnesium alloy was found to be covered with 15.80 nm thick native (hydr)oxide film; the refractive indices and the thickness of Ce, La and Sm conversion coatings were obtained. The formation kinetics of three REM coatings follows different exponential functions and the coatings exhibit different optical properties. La conversion coating has the largest n values and the lowest k values while Sm conversion coating is just opposite. Moreover, the pH variation of the bulk conversion solutions upon the coatings formation was recorded. It is confirmed that the reduction ...

Energy Technology Data Exchange (ETDEWEB)

A press formability of magnesium alloy sheet cannot be evaluated by only general characteristics in tensile test; tensile strength, elongation n-value and r-value. For example, AZ31-alloy elongates about 20% in room temperature but breaks easily at shallow stage in deep drawing, which is caused by little local elongation (local necking). Crystallographic restriction of slip deformation in this alloy produces high strength, which almost equal to macroscopic fracture strength. In press forming, the bending under high tension requires a large deformability. A great difference in the deformability between AZ31 magnesium alloy and a strain hardened A1100 Aluminum (only 5% in elongation) is shown by static bending test with V-notch. In a rolled plate of AZ31, a crack is produced by stress concentration and propagates with reduced load at all testing temperature up to 453 K. In contrast, the point of notch in A1100 is dulled by local plastic ...

International Nuclear Information System (INIS)

Research highlights: ? Reports a high protection system for the alloy in corrosive environment. ? Describes an interfacial process with self-healing properties. ? Reports the influence of substrate pre-treatment in the coating performance. - Abstract: In this paper the interface of poly(vinylidene fluoride) coatings prepared by the dip coating method and HF-treated AZ31 magnesium alloy was evaluated. The best performance of this system in corrosion tests compared to ground, as-received and acetic acid cleaned substrates is related to an acid-base interaction at the interface and to interfacial reactions which resulted in a self-healing process. The protectiveness of the samples was investigated using impedance and immersion tests while the coating morphology and interface stability were investigated by scanning electron microscopy, X-ray photoelectron spectroscopy and adhesion tests.

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AZ31 magnesium alloy was friction-welded to AM60 and the microstructures and the friction welding process were studied. The microstructures changed near the weld interface. The AZ31 was refined to a grain size of several {mu}m near the weld interface. The nucleation occurred in the shear bands that were introduced during the welding process. On the other hand, the eutectic structure was deformed and the lamellar structure which was composed of {alpha}-Mg and Mg{sub 17}Al{sub 12} was formed near the weld interface in AM60 alloy. In the friction process, the adhesion and peel off occurred alternately between AZ31 and AM60. Eventually, bonding was completed during upset process. (orig.)

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The development of a twinned microstructure in hexagonal close-packed rolled magnesium compressed in the in-plane direction has been monitored in situ with neutron diffraction. The continuous conversion of the parent to daughter microstructure is tracked through the variation of diffraction peak intensities corresponding to each. Approximately 80% of the parent microstructure twins by 8% compression. Elastic lattice strain measurements indicate that the stress in the newly formed twins (daughters) is relaxed relative to the stress field in the surrounding matrix. However, since the daughters are in a plastically 'hard' deformation orientation, they quickly accumulate elastic strain as surrounding grains deform plastically. Polycrystal modeling of the deformation process provides insight about the crystallographic deformation mechanism involved.

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Grain refinement in AZ31 magnesium alloy has been attempted by hot-rolling and annealing process. Specimens were solution heat treated at 673 K for 36 ks, then hot-rolled at 423-773 K with total reduction of 20-80% by multi pass process. The rolled specimens were annealed at 473-673 K for 3.6 ks. Grain sizes after the solution heat treatment were about 20 to 150 {mu}m. After hot-rolling at 573 K and annealing at 473 K, grain sizes decreased into about 5 to 10 {mu}m. Suppression of grain growth by pinning due to precipitates was observed by transmission electron microscopic observations. (orig.)

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The thermochemical calculations performed with a large number of elements to describe the chemical system in a Phebus FP test allow the following conclusions: The metallic absorber materials play a significant role in fission product speciation. At around 1000 C and above, silver iodide is the dominant iodine carrier in a full steam atmosphere in both FPT0 and FPT1. At lower temperatures, cadmium iodide takes over. In a reduced environment, indium iodide becomes important. Caesium iodide does certainly appear; at certain test conditions it becomes the major iodine transporting vehicle. But its role is not greater than that of the other iodides. It has more chances in FPT1 than in FPT0. Chlorine, which was present in FPT0 as a contaminant in relatively large amounts, does not prevent the iodine from forming Csl. Both share the caesium like partners. The evolution of caesium chloride ...

UK PubMed Central (United Kingdom)

Vacuolar ion channels in guard cells play important roles during stomatal movement and are regulated by many factors including Ca²⁺, calmodulin, protein kinases, and phosphatases....Full Text Available

UK PubMed Central (United Kingdom)

Background: Diet plays a key role in the development of type 2 diabetes (T2D), but little is known about the contributions of specific nutrients in populations in which dietary patterns...Full Text Available

International Nuclear Information System (INIS)

After being pre-plated a zinc layer, an amorphous Al-Mn alloy coating was applied onto the surface of AZ31B magnesium alloy with a bath of molten salts. Then the corrosion performance of the coated magnesium alloy was examined in 3.5% NaCl solution by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The results showed that the single Zn layer was active in the test solution with a high corrosion rate while the Al-Mn alloy coating could effectively protect AZ31B magnesium alloy from corrosion in the solution. The high corrosion resistance of Al-Mn alloy coating was ascribed to an intact and stable passive film formed on the coating. The performances of the passive film on Al-Mn alloy were further investigated by Mott-Schottky curve and X-ray photoelectron spectroscopy (XPS) analysis. It was confirmed that the passive film exhibited n-type semiconducting behavior in 3.5% NaCl solution with a ...

Science.gov (United States)

A laser spectrometer for the ethylenediaminetetra-acetic acid (EDTA) titration of magnesium or calcium ions that is designed around a handheld laser pointer as the source and a photoresistor as the detector is developed. Findings show that the use of the spectrometer reduces the degree of uncertainty and error in one part of the EDTA titrations, however overall standard deviations depend on the skill of the student and their willingness to be careful and precise.

International Nuclear Information System (INIS)

"2"0"3Pb, an ideal radionuclide for toxicological studies, can be artificially produced by bombardment of a thallium target but due to the extreme toxicity of thallium the lead has to be separated completely from the thallium. A single step method is here described consisting of removing the thallium from a dilute acid chloride solution using a continuous ethyl ether extraction. Essentially all of the thallium and almost none of the lead is removed in a 3-hr extraction. Because the ether is recycled, only about 30 ml are needed. If other contaminants are introduced from the bombardment and its subsequent manipulations, an additional step is used in which the lead is extracted from an iodide solution with methyl isopropyl keton. (U.K.).

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We have developed a method for the synthesis of C-11 iodoantipyrine. Carbon-11-labeled methyl iodide, prepared from /sup 11/CO2, was used to methylate 3-methyl-1-phenyl-2-pyrazolin-5-one to form C-11 antipyrine. Following silica-gel column chromatography and iodination, radiochemical purity of the C-11 iodoantipyrine was more than 99.5%, with a 10% yield and a specific activity of 30 mCi/mumol. Preliminary animal studies showed complete cerebral extraction and local cerebral blood-flow values that were within 4.6% of those obtained using C-14 iodoantipyrine. The C-11 analog, with positron emission tomography, will facilitate local cerebral blood-flow studies in human subjects.

British Library Electronic Table of Contents (United Kingdom)

Background and purpose: The aims of this study were to investigate the anti-cancer activity of SZ-685C, an anthracycline analogue isolated from marine-derived mangrove endophytic fungi, and to explore the molecular mechanisms underlying such activity. Experimental approach: The effect of SZ-685C on the viability of cancer cell lines was investigated using the 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl tetrazolium bromide (MTT) assay. SZ-685C-induced apoptosis was assessed by Annexin V-fluorescein isothiocyanate/propidium iodide staining, terminal deoxynucleotidyl transferase-mediated dUTP nick end labelling assay and analysis of caspase activation. The effect of SZ-685C on the Akt/FOXO pathway was studied using Western blotting analysis, and the in vivo anti-tumour efficacy was examined in ...

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Recently the authors showed that tetrazolium salts can be obtained during the oxidation of substituted 1,3,5-triarylformazans with potassium permanganate in a two-phase organic solvent-water system. The role of phase-transfer catalyst in this reaction is played by the tetrazolium salt, which is formed in a small amount as the result of oxidation of the formazan at the phase boundary. The method is distinguished by its extreme simplicity. However, the yield of the tetrazolium salts fluctuates within wide limits and does not exceed 62%. This is due to the fact that as the reaction proceeds the pH of the aqueous phase increases from 6 to 12. At the same time it is known that tetrazolium salts are unstable in aqueous alkaline solutions. They found that if the aqueous phase is replaced by aqueous hydrochloric acid (5 wt. %) the yields of the tetrazolium salts (Ia-g) are increased to 70-87%. For convenience of isolation the readily water-soluble tetrazolium chlorides were converted into the ...

International Nuclear Information System (INIS)

Ultrathin solid polymer electrolyte membranes containing sulfonic ester groups were prepared by polymerization of methyl benzenesulfonate and octamethylcyclotetrasiloxane in a glow discharge plasma. The sulfonic ester groups of the plasma polymer were transformed to lithium sulfonate groups by treatment with lithium iodide. Hybridization of this plasma polymer containing the lithium sulfonate groups with poly(ethylene oxide) (average Mw 300) resulted in the formation of a single lithium ion conductive film. The hybrid polymer electrolyte films were about 1 #mu#m thick, pinhole-free, adherent to various substrates, and showed ionic conductivities at 60 degrees C of the order of 10"- "6 S cm"- "1 (10"2 #OMEGA# cm"2 resistance per unit area of as-prepared solid polymer electrolyte). This material shows promise for electrochemical applications such as all solid-state lithium batteries, sensors, and electrochemical display devices.

British Library Electronic Table of Contents (United Kingdom)

The comprehensive theoretical and experimental study of the adsorption of water and methanol molecules on active sites (carboxyl and phenol hydroxyl groups) on the graphitized thermal carbon black is performed. It is shown that microclusters formed upon the adsorption of these molecules on such sites are characterized by the cyclic structure comprising 4?5 molecules similar to that whose existence was revealed previously in liquid water and on the surface of silver iodide. The analysis of the studied adsorption clusters demonstrated that the formation of such cycles is governed primarily by the hydrogen bonding; however, a definite role is played also by energy effects associated with the changes in the state of molecular motion during adsorption. It is shown that the generalized Langmuir ...

British Library Electronic Table of Contents (United Kingdom)

Sales of iodized table salt (household use, bulk containers) have been flat in Germany since 1996/1997. Nevertheless, the amount of iodide excreted with the urine has been steadily increasing in the German population since 1993. We investigated the beverage iodine levels as possible source of the increased input of iodine into the food chain. No systematic studies on this topic have yet been carried out in Germany. A total of 510 samples were drawn from large grocery discounters who supply all German states with their products (35% fruit and vegetable juices, 35% beers, 10% pooled milk and yoghurt drinks, 10% mineral water, 10% soda). (1) Water-based beverage samples are prepared by solid-phase extraction and iodine concentration is determined by HPLC and electrochemical detection, (2) the...

International Nuclear Information System (INIS)

Full text: Production: This radio iodine produced by three methods: 1) Wet method: The irradiated tellurium is dissolved in an oxidizing mixture which also converts iodine in to iodide. This is a chemical method and iodine that it produced with this method has low purity and efficiency. 2). Dry Method: The irradiated tellurium is dissolved in furnace (750 deg. C) with sublimation method and iodine absorbed in sodium solution . In this case we have more than 99.5 % purity and 80 % efficiency. We are using this type in Iran. 3) Fission fragment method: In this case the iodine separated from fission fragment directly and we have high purity (career free) and specific activity of iodine. Application: Iodine is a versatile tracer element. It is used to determine thyroid cancer metastases, and size, shape and activity of the thyroid gland. Critical organ of iodine is thyroid gland. One of the common diagnostic procedures for determining thyroid function therefore, is to ...

Energy Technology Data Exchange (ETDEWEB)

The kinetics of the oxidative addition of CH/sub 3/I to platinum(II) complexes in aqueous solutions of K/sub 2/PtCl/sub 4/ and KPtCl/sub 3/(C/sub 2/H/sub 4/) have been studied by PMR and GLC. The second-order rate constants for the PtCl/sub 3/(H/sub 2/O)/sup -/ and PtCl/sub 4//sup 2 -/ particles are equal to 400 exp(-2.7 x 10/sup 3//T) and 3.18 x 10/sup 10/ exp(-9.2 x 10/sup 3//T) mole/sup -1/ x liter x sec/sup -1/, respectively. The introduction of a ..pi..-acceptor ligand, viz. ethylene, into the coordination sphere of platinum(II) results in a sharp drop in the rate, probably due to a decrease in the electron density on the platinum atom. According to the PMR data, the product of the oxidative addition of CH/sub 3/I to Zeise's salt is a methyl complex of platinum(IV), is identical to the complex obtained by reacting methyl iodide with K/sub 2/PtCL/sub 4/, and does not contain an olefin.

International Nuclear Information System (INIS)

7,959 patients were examined by radionuclide in-vivo methods within one year, 1,228 of them by application of "1"3"1I-iodide (radioiodine test and scintigraphy of the thyroid gland). In compliance with the ICRP publications 26 and 27 the somatically effective equivalent dose H/sub s,eff/ was ascertained for several examining methods, derived from it the collective dose S/sub s,eff/ and considering a part of manifestation resulting from the age distribution of patients, the somatic risk regarding radiation-induced malignoma with fatal termination. For the patients examined by "1"3"1I-iodide the collective dose was 79.9 man x Sv and the mean somatic risk 30 x 10"-"5 with a part of manifestation of 0.39 accordig to 0.37 radiation-induced malignomas with fatal termination. For all patients examined by other radiopharmaceuticals the collective dose was 14.07 man x Sv, the mean somatic risk 1.7 x 10"-"5 according to 0.11 malignomas. The average ...

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Stearic acid gel is employed to study the phase evolution of MgTiO{sub 3} nanoparticles by thermal gravimetric analysis, X-ray diffraction, and Fourier transform infrared. During the preparation of stearic acid gel, tetrabutyl titanate easily absorbed moisture to hydrolyze into Ti(OH){sub 4} firstly, and then reacts with stearic acid and magnesium stearate to form magnesium-titanium oxide network polymer gel, meanwhile n-butanol is generated. When stearic acid gel is calcined in air, a series of oxidation and combustion reactions occur, meanwhile apparent heat is given off. The results show that a metastable intermediate phase Mg{sub 2}TiO{sub 4} is generated at 450 {sup o}C and nearly disappeared at 550 {sup o}C. Simultaneously, a new solid phase of MgTiO{sub 3} appears. The metastable intermediate phase Mg{sub 2}TiO{sub 4} is successfully identified in the current work.

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In this study, isothermal torsion tests were carried out on magnesium AZ31B alloy under constant strain rate conditions, in the range of 250 to 400 C at 0.01, 0.1, and 1.0 s{sup -1}. Alloy flow stress dependence on strain rate and temperature can be described by a power law with activation energy of 130 kJ/mol. Microstructural examination of hot deformed samples shows very fine recrystallized grains decorating grain boundaries of larger gains in the form of a necklace. These fine grains are produced by dynamic recrystallization at the grain boundaries of original grains. Microstructure evolution, based on samples quenched at different strain levels, indicates that increasing deformation strain has little effect on recrystallized grain size but widens the recrystallized region, with full recrystallization achieved at a certain high strain level. Recrystallized grain size increases with increasing deformation temperature and strain rate. The latter suggests ...

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The tensile and compressive properties as well as LCF and HCF performance of the extruded magnesium alloys AZ31 and AZ80 were determined in extrusion (L) and long-transverse (T) directions. Owing to marked crystallographic textures, both alloys showed pronounced directional mechanical properties in monotonic as well as cyclic loading with strength values in L-direction being significantly superior to those in T-direction. Thermomechanical treatments such as pressing, swaging and rolling were found to increase yield stresses and HCF strengths and to alter the directionality in properties due to textural modifications. To further improve HCF strengths, mechanical surface treatments such as shot peening, roller-burnishing and deep rolling were utilized. The results indicate marked improvements provided that suitable process parameters are used. The improvement of the HCF strengths is explained by the process-induced changes in near-surface dislocation densities and ...

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Three kinds of thin AZ31 wrought magnesium alloys sheets were used in order to investigate the influence of the second phase particles on fracture toughness. From the theoretical model, the ratio of {lambda}{sub p}/d{sub p} would be estimated 5 {proportional_to} 6. On the other hand, from the microstructural observation, average particle spacing on each material was sample A: 13.1 {mu}m, sample B: 14.1, and sample C: 12 {mu}. In addition, average particle size on each sample was sample A: 2.1, sample B: 1.9, and sample C: 2.3 {mu}m. Therefore, the ratio of {lambda}{sub p}/d{sub p} calculated from fracture surface observation would be predicted 6 {proportional_to} 7. In comparison with the result of the prediction by theoretical analysis was in good agreement with the result of fracture toughness observation. It was found that the variation in plane-strain fracture toughness on AZ31 were affected by both of particle spacing and particle size. (orig.)

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The deformation behavior and structure changes of magnesium alloy AZ31 were studied in compression at temperatures ranging from 523 K to 673 K and at a strain rate of 3 x 10{sup -3} s{sup -1}. They depend sensitively on deformation temperature. At high temperatures, grain fragmentation takes place due to frequent formation of kink bands initially at corrugated grain boundaries and then in grain interiors, followed by full development of new grains in high strain. At lower temperatures, in contrast, twinning takes place in rather coarse grains and kink bands are formed mainly in finer original ones in low strain. It is concluded that new grain evolution can be controlled by a deformation-induced continuous reaction resulting in grain fragmentation by kink bands, i.e. continuous dynamic recrystallization (cDRX). The latter is discussed comparing with conventional, i.e. discontinuous, DRX. (orig.)

British Library Electronic Table of Contents (United Kingdom)

The effect of ammonia treatment in field natural rubber (NR) latex with different storage period time on the properties of concentrated NR latex and stability of skim latex was investigated. Fresh NR latex was treated with various ammonia contents such as 0.35, 0.60 and 0.80% w/w, and then they were centrifuged to get the concentrated NR latex with 60% dry rubber content (DRC) containing 0.16, 0.18 and 0.25% w/w, respectively and skim NR latex with roughly 5% DRC containing 0.42, 0.60 and 0.80% w/w, respectively. The effect of storage times with ?0, 15, 30 and 45 days for concentrated NR latex with different ammonia contents on their properties such as alkalinity, magnesium content and viscosity was observed. It was found that generally, magnesium content in field NR latex and latex...

Energy Technology Data Exchange (ETDEWEB)

The mechanical behaviour of wrought magnesium alloy AZ31 has been characterised by tensile testing at room temperature. Tests were carried out at various strain rates between 0.00003 s{sup -1} and 0.01 s{sup -1} on material which had been extruded to a bar of approximately 6 mm thick, and 80 mm wide. Specimens were machined from three orientations relative to the extrusion direction: parallel, perpendicular, and 45 from the extrusion direction. Significant variations of the properties were observed depending on the extrusion orientation and strain rate. At all strain rates the yield stress declined as the test orientation was rotated away from the extrusion direction. Parallel to the extrusion direction, the yield stress was found to increases markedly with increasing strain rate, whereas at 45 and 90 a lesser influence of strain rate was observed. The work hardening exponent was also influenced by the test orientation. Metallographic studies revealed a ...

International Nuclear Information System (INIS)

Multi-cation #alpha#-Sialon ceramics were prepared using mixtures of samarium with calcium, magnesium, yttrium and ytterbium, and compared with a pure Sm-Sialon of equivalent total stabilising cation composition. A ratio of 80eq% samarium to 20eq% of the second stabilising additive was used. Samples were fired at 1820 deg C and subsequently heat treated at 1450 deg C. XRD phase analysis showed that all additives resulted in greater #alpha#-Sialon stability, and that calcium was the most effective additive for the stabilisation of the #alpha#-Sialon phase. Copyright (1998) Australasian Ceramic Society

International Nuclear Information System (INIS)

The description is presented of binary phase diagrams of titanium alloyed with the following elements: silver, aluminium, arsenic, gold, boron, barium, beryllium, bismuth, carbon, calcium, cadmium, cobalt, chromium, copper, iron, gallium, germanium, hydrogen, hafnium, indium, iridium, potassium, lithium, magnesium, manganese, molybdenum, nitrogen, sodium, niobium, nickel, oxygen, osmium, phosphorus, lead, palladium, platinum, plutonium, rhenium, lanthanium, cerium, preseodymium, neodymium, gadolinium, erbium, terbium, thulium, lutetium, rhodium, ruthenium, scandium, silicon, tin, strontium, tantalum, technetium, thorium, uranium, vanadium, tungsten, yttrium, ytterbium, zinc and zirconium.

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This specification establishes requirements for design, testing, and quality assurance for electric heaters that will be used to maintain primary Sodium temperature in the Fast Test Facility (FFTF) reactor vessel. The Test Specification (WHC-SD-FF-SDS-003) has been revised to Rev. 1. This change modifies the fabrication of approximately 25 feet of the subject heater using ceramic insulators over the heater lead wire rather than compressed magnesium oxide. Also, 304 or 316 stainless steel can be used for the heater sheath. This change should simplify fabrication and improve the heater operational reliability.

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The theoretical principles underlying the formation of oxide and, in particular, anodic oxide coatings on metals produced by chemical oxidation, anodizing in solutions, and anodizing in cold plasmas are reviewed. The mechanisms and conditions of anodic oxidation are described, and the structure of anodic oxide coatings on aluminum, magnesium, beryllium, zinc, cadmium, iron, cobalt, nickel, titanium, zirconium, tantalum, and chromium alloys is examined. Attention is also given to various applictins of anodized coatings. 54 references.

International Nuclear Information System (INIS)

The adsorption properties of four samples of the #alpha#-modification of boron nitride (#alpha#-BN) were investigated by the gas-chromatographic method. According to the electron microscopy data, the #alpha#-BN particles possess the shape of thin plates. An #alpha#-BN sample prepared from magnesium polyboride, is the most uniform adsorbent. For a series of n-alkanes, benzene, and alkyl benzenes, by testing the #alpha#-BN samples one has obtained the retained volumes (Henry constants) and the values of the differential adsorption heat, which are close to those of the surface zero filling. These thermodynamic characteristics of adsorption have shown that the #alpha#-BN, line the graphitized thermal carbon black, is not a specific adsorbent.

Science.gov (United States)

INTRODUCTION. We searched for a pathophysiologically based feature of major water electrolytes, which may define water quality better than the water hardness, respecting urinary calculus formation. MATERIALS AND METHODS. Utilizing a multistage stratified sampling, 2310 patients were diagnosed in the imaging centers of the provincial capitals in Iran between 2007 and 2008. These were composed of 1755 patients who were settled residents of 24 provincial capitals. Data on the regional drinking water composition, obtained from an accredited registry, and their relationships with the region's incidence of urinary calculi were evaluated by metaregression models. The stone risk index (defined as the ratio of calcium to magnesium-bicarbonate product in drinking water) was used to assess the risk of calculus formation. RESULTS. No correlation was found between the urinary calculus incidence and the amount of calcium, bicarbonate, or the total hardness of the drinking water. ...

International Nuclear Information System (INIS)

The synthesis of ["1"1C]phenobarbital, ["1"1C]pentobarbital and["1"1C]amobarbital labelled in the 5-[1-"1"1C]ethyl position is reported. The malonic esters R- CH(CO_2Et)_2 [R phenyl-, 1-methylbutyl-, and 3- methylbutyl- were alkylated with [1-"1"1C]ethyl iodide prepared from ["1"1C]carbon dioxide. Ring closure of the 2-[1-"1"1C]ethyl-labelled malonic esters with urea afforded 5-[1-"1"1C]ethyl-phenobarbital,-phenobarbital, -pentobarbital and -amobarbital synthesis times of 42-47 min, counted from ["1"1C] carbon dioxide. In typical syntheses starting with 3 GBq pentobarbitol and (81 mCi) ["1"1C]carbon dioxide, 150-215 MBq (4-6 mCi) were produced in 25-30% decay corrected -amobarbital radiochemical yields with radiochemical purities greater than 98%. (author).

CERN Document Server

High pressure xenon ionization chamber detectors are possible alternatives to traditional thallium doped sodium iodide (NaI(Tl)) and hyperpure germanium as gamma spectrometers in certain applications. Xenon detectors incorporating a Frisch grid exhibit energy resolutions comparable to cadmium/zinc/telluride (CZT) (e.g. 2% (at) 662keV) but with far greater sensitive volumes. The Frisch grid reduces the position dependence of the anode pulse risetimes, but it also increases the detector vibration sensitivity, anode capacitance, voltage requirements and mechanical complexity. We have been investigating the possibility of eliminating the grid electrode in high-pressure xenon detectors and preserving the high energy resolution using electronic risetime compensation methods. A two-electrode cylindrical high pressure xenon gamma detector coupled to time-to-amplitude conversion electronics was used to characterize the pulse rise time of deposited gamma photons. Time ...

Science.gov (United States)

An extraction of molybdenum is described that provides a more predictable separation over a significantly wider acidity range than previously determined. The extraction of Mo appeared to be a function of HCl normality, with virtually complete separation above 3.6 N. A test was conducted to determine if the extraction was a function of just HCl concentration or of overall acidity. When the aqueous phases of the test sequence were all prepared at 1 N H/sub 2/SO/sub 4/ in addition to the HCl in each, the resulting extraction curves were essentially identical. Another test was performed to determine if Mo was being extracted as an iodide complex. Three aqueous solutions, which were 4 N in HCl and 26% (w/v) ascorbic acid, were prepared in culture tubes. When 25 ..mu..g of Mo was extracted from these solutions of 5 mL of organic phase, the KCl gave only a 16% extraction, the KBr gave only a 22% extraction, and the KI provided an essentially total extraction. 4 ...

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AIM: To define the value of digital radiography with a clinical flat panel detector system for evaluation of wrist fractures in comparison with state of the art storage phosphor radiography. MATERIAL AND METHODS: Hard copy images of 26 fractured wrist specimens were acquired with the same exposure dose on a state of the art storage phosphor radiography system and a clinical flat panel detector. Image features like cortical bone surface, trabecular bone, soft tissues and fracture delineation were independently analysed by 4 observers using a standardised protocol. Image quality ratings were evaluated with an analysis of variance (ANOVA). RESULTS: Flat panel detector radiographs were rated superior with respect to cortical and trabecular bone representation as well as fracture evaluation, while storage phosphor radiographs produced better soft tissue detail. CONCLUSION: In some of the observed image quality aspects, the performance of caesium iodide/amorphous silicon ...

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Magnetic coupling between two or more metal centers is an important facet of d- and f-block transition metal chemistry due to its implications in chemical bonding. With respect to actinide metals, magnetic coupling between polymetallic actinide centers is less well-known. Of the few documented examples, only one bimetallic uranium(V) complex, [(MeC{sub 5}H{sub 4}){sub 2}U]{sub 2}[{mu}-1,4-N{sub 2}C{sub 6}H{sub 4}] (1), has unequivocally demonstrated antiferromagnetic coupling. This complex employs a {pi}-conjugated 1,4-phenylenedimide ligand system which bridges the two f{sup 1}-metal centers and enables antiferromagentic coupling between unpaired f-e1ectrons residing in a {pi}-symmetry orbital. In this communication, we report the synthesis of a dimeric bis(imido) uranium(V) iodide complex and demonstrate with magnetic susceptibility measurements and density functional theory (DFT) calculations that the f{sup 1}-uranium centers display antiferromagnetic coupling ...

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The literature of radiation damage measurements on cadmium zinc telluride (CZT), cadmium telluride (CT), and mercuric iodide (HgI{sub 2}) is reviewed and in the case of CZT supplemented by new alpha particle data. CZT strip detectors exposed to intermediate energy (1.3 MeV) proton fluences exhibit increased interstrip leakage after 10{sup 10} p/cm{sup 2} and significant bulk leakage after 10{sup 12} p/cm{sup 2}. CZT exposed to 200 MeV protons shows a two-fold loss in energy resolution after a fluence of 5 {times} 10{sup 9} p/cm{sup 2} in thick (3 mm) planar devices but little effect in 2 mm devices. No energy resolution effects were noted from moderated fission spectrum of neutrons after fluences up to 10{sup 10} n/cm{sup 2}, although activation was evident. Exposures of CZT to 5 MeV alpha particle at fluences up to 1.5 {times} 10{sup 10} {alpha}/cm{sup 2} produced a near linear decrease in peak position with fluence and increases in FWHM beginning at about 7.5 ...

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Extruded and hot-rolled 200 C {proportional_to} 500 C AZ31B plates were studied their texture using ODFs analysis. The as-extruded specimen has the strongest intensity of (0001)-ND fiber and 300 C and 400 C hot-rolled ones have the next, but the 200 C hot-rolled one has the lowest intensity. Compared with the corresponding tensile properties, this feature evidents that a pronounced (0001) basal texture will reduce ductility of AZ31B alloy. The ODFs results also indicate that (05 anti 52)- and (01 anti 10)-ND fibers are related to the ductility of AZ31B alloy. (orig.)

Energy Technology Data Exchange (ETDEWEB)

Pilot plant tests have been conducted to evaluate sodium thiosulfate as an oxidation inhibition additive in five lime/limestone slurry flue gas desulfurization processes. It was found that the oxidation rate of absorbed sulfur dioxide (SO)/sub 2/ was reduced by more than 50 percent in the presence of 100 to 200 ppm of thiosulfate ion in the scrubbing slurry. Calcium sulfate dihydrate (gypsum) scaling was eliminated and the unsaturated (with respect to gypsum) operation mode was maintained by the addition of sodium thiosulfate. Other benefits of sodium thiosulfate addition observed at the pilot plant included improvement in solids dewatering properties for limestone processes and improvement in SO/sub 2/ removal efficiency for magnesium-enhanced lime/limestone processes.

Energy Technology Data Exchange (ETDEWEB)

The article gives results of pilot-plant tests to evaluate sodium thiosulfate as an oxidation-inhibition additive in five lime/limestone slurry flue-gas desulfurization processes. It was found that the oxidation rate of absorbed SO/sub 2/ was reduced by more than 50% in the presence of 100-200 ppm of thiosulfate ion in the scrubbing slurry. Calcium sulfate dihydrate (gypsum) scaling was eliminated and the unsaturated (with respect to gypsum) operation mode was maintained by the addition of sodium thiosulfate. Other benefits of sodium thiosulfate addition observed at the pilot plant included improvement in solids dewatering properties for limestone processes and improvements in SO/sub 2/ removal efficiency for magnesium-enhanced lime/limestone processes.

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Counter-current regeneration of 2-stage sodium zeolite softeners has been employed in reducing hardness leakage level of steamflooding water to less than 1 ppm when raw water contains as much as 5,000 ppm of the total dissolved solids. Hardness leakage is caused by sodium displacement of calcium and magnesium from the bottom of the exchanger bed. This study presents nomographs providing for rapid calculations to be made, for which a convenient operational mode does not already exist. The nomographs relate the hardness leakage as a function of salt quality and influent water quality and present solutions for predicting the leakage level, salt quality requirement or the treatability of raw water required for steamflooding projects.

International Nuclear Information System (INIS)

Microstructure and properties of a Mg AZ31B laser beam weld without filler are studied using electron microscopy, X-ray diffraction and mechanical tests. The microstructure of the weld is characterized by a narrow heat affected zone, columnar grains and precipitate coarsening in the fusion zone. Texture in the fusion zone is significantly different from the texture of the base material. The residual stress distribution observed is similar at the top and the bottom of the weld, maximum tensile residual stress values are observed in the fusion zone. Tensile tests reveal differences in the mechanical behavior of the fusion zone and the parent material, which can be related to the differences of texture and the resulting deformation mechanisms.

British Library Electronic Table of Contents (United Kingdom)

Normally, concrete technologists attribute salt weathering, salt crystallization or physical attack to the deterioration of concrete that is partially exposed to sulfate environment. However, there are few convincing evidences supporting this view. The purpose of this paper is to check by means of extensive micro-analysis if traces of sulfate crystals are present in the paste. This would enable to verify in a direct way whether salt weathering really causes cement paste damage or not.In this research, cement paste and cement?fly ash paste specimens were partially exposed to sodium sulfate and magnesium sulfates solution under a constant storage condition (20 ? 2 ?C, and 60 ? 5% RH) and a sharply fluctuating environment (40 ? 2 ?C and 35 ? 5% RH for 24 h, then 10 ? 1 ?C and 85 ? 5% RH, also...

International Nuclear Information System (INIS)

This study concerns the Souss upstream basin. The objective is to investigate the characteristics of surface water and groundwater, to assess the impact of artificial recharge as reinforcement of the natural replenishment and assess the renewal of groundwater under semi-arid area. Two major water types are observed: (i) surface waters and upstream springs (least mineralized) and (ii) all groundwater samples (prevailing calcium and magnesium bicarbonate water type). Water isotopes show a low evaporation of precipitations during infiltration. Impoverishment in heavy isotopes is the characteristic of mountain rainfalls, or of a climate colder and wetter than present. Carbon-14 activities (34-94 pmc) indicate a long residence time. The artificial recharge is low compared to the reservoir volume, due to which the renewal rate is also low.

International Nuclear Information System (INIS)

Corrosion tests of titanium alloys VTI-0, OT4, VT5-1 and steel Kh18N1OT in 10% and 18% HCl with additions of carnallite at 40 deg C have been carried out. It has been established that titanium alloys in 10% and 18% HCl containing 5 and 10% carnallite are sufficiently corrosion resistant in the presence of 0.1-1% FeCl or HNO_3 and can be used for manufacturing the equipment of recirculation gas scrubbers. Steel Kh18N10T is unstable in all the media tested. It is subjected to intensive pitting. Specimens of steel Kh18N10T have also revealed edge cracking.

British Library Electronic Table of Contents (United Kingdom)

Commercial rolled magnesium sheets of alloys AZ31 (Mg-3 mass%Al-1 mass%Zn) and ZE10 (Mg-1 mass% Zn-<1 mass% Rare Earths) in O-temper condition were used for blanking experiments near room temperature. A serrated fracture surface can be observed in case of AZ31 but not in case of ZE10. During the shearing process of the AZ31 sheet, many micro cracks parallel to the sheet plane are generated in the shearing zone. These micro cracks lead to the formation of loose particles during the shearing operation, which interfere with further processing of the part and incur additional costs by increasing the scrap rate. It is found that the strong basal texture of this alloy is an important reason for the generation of such serrated cracks. In this paper a new method of selective texture modification i...

International Nuclear Information System (INIS)

Fractionation of isotopes of the alkali metals and the alkaline earth metals in ion exchange chromatography of their chlorides was studied. The heavier isotopes of potassium and rubidium were found to be preferentially fractionated into the ion exchanger phase while the lighter isotopes of lithium, magnesium, calcium and strontium were enriched in the exchanger phase. This can be interpreted as a resultant of the relative significance of isotope effect upon dehydration and isotope effect accompanying the phase change of the hydrated metal ion. Found was no evidence of anomalous isotope effect attributable to the odd-even difference in mass number of isotopes. Based on the spectroscopic and solution chemical data (experimental and theoretical), the isotopic reduced partition function ratios of the hydrated alkaline metal ions and stretching force constants of metal ion-hydrating water bonds were estimated. (author).

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The structure and catalytic properties of 2 wt.-% Pd/SiO/sub 2/ catalysts promoted with 2 wt.-% MgO and 0.2-5 wt.-% iron have been investigated. Catalysts were characterized by TPR, hydrogen chemisorption, and Moessbauer spectroscopy and their catalytic performance in methanol formation was also measured. At 16 at.-% iron a sharp maximum was observed in the activity which can be interpreted as being due to simultaneous promotion with iron and MgO. Independent mechanisms of promotion were found for the two modifiers: iron influenced the metallic component by forming bimetallic PdFe particles while MgO changed the properties of silica in a favourable way. 6 figs., 29 refs., 1 tab.

International Nuclear Information System (INIS)

The synthesis, characterization, and some analytical applications of a new triazine resin are described. Separation of group IB, IIB, VIB, and VIIB metal ions from group VIII metal ions is achieved by this PDT-4 resin. Calcium(II) and magnesium(II) are taken up at pH = 6, 0.1 M acetate and are eluted at pH = 6, 0.1 M sodium nitrate. Copper(II) is retained at pH = 6, 0.1 M acetate and pH = 1 hydrochloric acid and is eluted subsequently by 5 M perchloric acid. Molybdenum(VI) is sorbed selectively from 0.1 N sulfuric acid or hydrochloric acid and is eluted in a tight band by 0.1 N sodium hydroxide. Numerous rapid column chromatographic separations are reported using this new resin, including analysis of NBS standard samples.

Energy Technology Data Exchange (ETDEWEB)

Effects of ions of Group IA, IIA, IIIB, and VIIB elements on the cathodic deposition of a molybdenum were investigated in a KCl-LiCl (eutectic)-MoCl/sub 3/ molten salt at 773 K (500/degree/C). The results can be summarized as follows: The addition of potassium, rubidium, cesium, and barium cations and fluorine anions to the KCl-LiCl (eutectic)-MoCl/sub 3/ molten salt is effective in depressing the cathodic deposition of the molybdenum subchloride, which hinders the smooth, flat electrodeposition of molybdenum. The addition of lithium, sodium, magnesium, calcium, strontium, and aluminum cations and bromine and iodine anions promotes the undesirable cathodic deposition of the molybdenum subchloride.

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The Partnership for a New Generation of Vehicles (PNGV) program intends to develop new designs for automobiles that will reduce fuel consumption by two thirds but otherwise have price, comfort, safety, and other measures of performance similar to the typical automobile now on the market. PNGV vehicle designs are expected to substitute lightweight materials, such as aluminum, magnesium, carbon-reinforced polymer composites, glass-reinforced polymer composites, and ultra- light steel, for heavier materials such as steel and iron in automobile components. The target mass of a PNGV vehicle is 1,960 pounds, as compared to the average current vehicle that weights 3,240 pounds. Other changes could include the use of different ferrous alloys, engineering changes, or incorporation of advanced ceramic components. Widespread adoption of these vehicle designs would affect materials markets and require concurrent development and adoption of supporting technologies to supply the ...

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3-Quinuclidinyl benzilate (QNB) is a potent muscarinic antagonist that binds to muscarinic acetylcholine receptors. Iodination of QNB is difficult because it contains rings that are deactivated, while phenol rings are activated. The purpose of this research is to develop an appropriate method for the iodination of QNB at no-carrier-added concentrations of /sup 125/I/NaI. Phenol was chose as the test compound for direct iodination by adding chloramine T and nonradioactive sodium iodide to the phenol in a phosphate buffer and methanol system. A simple method to radioiodinate QNB at several concentrations was developed in situ in the presence of QNB, thallic trifluoroacetate /sup 125/I/NaI, /sup 127/I/NaI, and aluminium chloride. Using milligram amounts of QNB (7.12 x 10/sup -6/ moles), three reaction steps were involved: QNB was reacted with thallic trifluoroacetate at 60/sup 0/C for 24 hours, then radioactive /sup 125/I/NaI and aluminium chloride were added to the ...

International Nuclear Information System (INIS)

The purpose of this work was to develop a high specific activity radioiodinated cell membrane probe for tracking lymphocytes in-vivo to replace the nucleus localizing, cytotoxic lipophilic chelates (In-111 oxine and Tc-99m HMPAO) currently used. Alkylation of parent dye 4-[2-[-N,N-didecylamino]phenyl]ethenyl pyridine with E-1-tributylstannyl-3-tosylpropene (prepared form E-1-tributylstannyl-1-propene-3-ol), gave a tributyltin precursor 1. Radiolabeled 3-[4-[2-[4-(N,N-didecylamino)phenyl]ethenyl]pyridino] E-[I-125]-1-iodopropene (2), was prepared from 1 using peracetic acid in acetonitrile/water. Labeling yields and specific activities achieved were 26% (#approx#2170 Ci/mmol), 40% (1220 Ci/mmol), and 55% (200 Ci/mmol) for nca, 0.4, and 2 nanomole carrier iodide runs respectively. Canine mixed leukocytes (0.5-1.0 x 10"8 cells) were labeled with 2 (67% and 42% yields for 200 Ci/mol and 1220 Ci/mmol preparations) and showed blood clearance similar to In 111 oxine. ...

International Nuclear Information System (INIS)

There is significant interest in using computed tomography (CT) for in vivo imaging applications in mouse models of disease. Most commercially available mouse x-ray CT scanners utilize a charge-coupled device (CCD) detector coupled via fibre optic taper to a phosphor screen. However, there has been little research to determine if this is the optimum detector for the specific task of in vivo mouse imaging. To investigate this issue, we have evaluated four detectors, including an amorphous selenium (a-Se) detector, an amorphous silicon (a-Si) detector with a gadolinium oxysulphide (GOS) screen, a CCD with a 3:1 fibre taper and a GOS screen, and a CCD with a 2:1 fibre taper and both GOS and thallium-doped caesium iodide (CsI:Tl) screens. The detectors were evaluated by measuring the modulation transfer function (MTF), noise power spectrum (NPS), detective quantum efficiency (DQE), stability over multiple exposures, and noise in reconstructed CT images. The a-Se ...

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Coal ash is a substance that has been mixed into minerals in the earth`s crust during their coalification process. Estimation was made on what kinds of mineral composition have been mixed into coals. Noted first was the kinds of compounds contained in the ash, wherein the ratios of mass in the compounds and minerals were correlated, and selection was made on minerals which are thought correlated. The selection criterion was based on minerals containing silica, alumina, iron oxide, lime and magnesium as compounds. Then, a phase equilibrium line diagram was used to estimate compositions and melting points of minerals which are thought to have been produced from these compounds. By comparing the estimation with the measured melting points of the ashes, mineral compositions thought reasonable were all selected. Assumption was possible on minerals that are thought to have been transferred into coal ash. Compound indications of ashes from 29 kinds of the world`s typical ...

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Adsorptive removal of Pb(II) ions from aqueous solution onto a non-activated charcoal (CC) of oak wood origin was studied in comparison with an activated carbon of coal origin. The adsorption capacity for Pb(II) of the non-activated charcoal increased significantly with deceasing particle diameter, whereas the activated carbon (AC) exhibited approximately constant capacity for Pb(II) adsorption as a function of particle size. Adsorption to the ashes prepared from the non-activated charcoal and the activated carbon was also investigated to examine the role of mineral ash. Although the ash from the activated carbon did not show any Pb(II) adsorption, the ash from the charcoal was very effective for Pb(II) adsorption. Furthermore, Pb(II) was hardly adsorbed when the ash was removed from the non-activated charcoal by acid treatment. Based on the results, the adsorption sites for Pb(II) are considered to be acidic surface functional groups on the external and internal surfaces for the ...

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Theoretical investigations on the phase change materials (PCMs) used as the heat storage media for box-type solar cookers have been conducted in this study. The selected PCMs are magnesium nitrate hexahydrate, stearic acid, acetamide, acetanilide and erythritol. For a two-dimensional simulation model based on the enthalpy approach, calculations have been made for the melt fraction with conduction only. Different materials such as glass, stainless steel, tin, aluminum mixed, aluminum and copper are used as the heat exchanger container materials in the numerical calculations. The large value of thermal conductivity of heat exchanger container material did not make a significant contribution on the melt fraction except for at very low thermal conductivities. Based on the theoretical results, stearic acid and acetamide are found to be good compatibility with latent heat storage system. It is also found that the initial temperature of PCM does not have very important ...

Science.gov (United States)

As with mammalian enzymes, green crab (Scylla serrata) alkaline phosphatase can be activated by Mg2+ through a time-dependent course. The activation is mainly a Vmax effect. Tsou's method was used to study the kinetic course of activation. The results show that the enzyme was activated by a complexing scheme that had not been previously identified: the enzyme first reversibly and quickly binds Mg2+ and then undergoes a slow reversible course to activation, with a relatively high activation energy (78 +/- 4 kJ/mol) and a slow conformational change. The activation reaction is a single molecule reaction, and the apparent activation rate constant is independent of Mg2+ concentration if the concentration is sufficiently high. The microscopic rate constants of activation and the association constant were determined from the measurements. The proposed scheme may also be applied to the Mg2+ activation mechanism for mammalian enzyme, to explain why the activation rate is time-dependent and not ...

Science.gov (United States)

Appendices to this summary consist of twelve individual status reports that will be available through the National Technical Information Service (NTIS) in the United States and of course limited copies will be available through NATO. The twelve report titles which are appendices to the summary are: (A) Status Report on the Limestone/Sludge Flue Gas Desulfurization Process; (B) Status Report on the Lime/Sludge Flue Gas Desulfurization Process; (C) Status Report on the Double Alkali/Sludge Flue Gas Desulfurization Process; (D) Status Report on the Sea Water Scrubbing Flue Gas Desulfurization Process; (E) Status Report on the Limestone/Gypsum Flue Gas Desulfurization Process; (F) Status Report on the Lime/Gypsum Flue Gas Desulfurization Process; (G) Status Report on the Double Alkali/Gypsum Flue Gas Desulfurization Process; (H) Status Report on Flue Gas Desulfurization by Scrubbing with Dilute Sulfuric Acid; (I) Status Report on the Magnesium Oxide Flue Gas ...

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The effect of concentration on the corrosion behavior of Mg-based alloy AZ91D was investigated in ethylene glycol-water solutions using electrochemical techniques i.e. potentiodynamic polarization, electrochemical impedance measurements (EIS) and surface examination via scanning electron microscope (SEM) technique. This can provide a basis for developing new coolants for magnesium alloy engine blocks. Corrosion behavior of AZ91D alloy by coolant is important in the automotive industry. It was found that the corrosion rate of AZ91D alloy decreased with increasing concentration of ethylene glycol. For AZ91D alloy in chloride >0.05 M or fluoride <0.05 M containing 30% ethylene glycol solution, they are more corrosive than the blank (30% ethylene glycol-70% water). However, at concentrations <0.05 for chloride or >0.05 M for fluoride containing ethylene glycol solution, some inhibition effect has been observed. The corrosion of AZ91D alloy ...

British Library Electronic Table of Contents (United Kingdom)

The effects of anthropogenic (nitrogen fertilization) and natural [soil texture, pH content of humus, ammonium nitrogen (N-NH4), and the available forms of phosphorus (P), potassium (K), magnesium (Mg)] factors on nitrate nitrogen (NO3-N) content and distribution were shown. The dependencies between these factors and the content of NO3-N in soil were estimated in three soil layers: 0-30 cm; 31-60 cm; 61-90 cm. The research was carried out in 2004-2006, and the soil samples were taken from 411 places throughout eastern Poland in two seasons: spring and autumn. The concentration of NO3-N significantly depended on the year of investigation, season of the year, and depth of sampling. Distribution of NO3-N in the soil profile indicates possibility of NO3 leaching during winter and early spring....

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The cost of transporting biogas digestate can be decreased by reducing its water content. However, the digestate emits volatile compounds during drying. This study investigated the drying behaviour and the change of digestate composition. Drying took place in a hybrid solar/waste-heat dryer that used solar energy as well as waste heat from a combined heat and power unit (CHP) and the exhaust air of a microturbine. The experiment involved the use of 60 t of liquid digestate. Climatic conditions were measured inside and outside the drying hall. Dry matter (DM) and organic dry matter (ODM) were also measured on a daily basis. In addition, the energy consumption of waste and solar heat were recorded and related to the quantity of dried feedstock. The total nitrogen, ammonium, phosphate, potassium oxide, magnesium oxide and calcium oxide in the digestate were subjected to chemical analysis before and after the drying process. Losses of nitrogen were calculated. Specific ...

International Nuclear Information System (INIS)

The difference of NH_4"+-N/NO_3"--N nutrition between hybrid and conventional rice varieties at the late growth stage was studied by using "1"5N-tracer technique. The results showed that the nitrate fertilizer utilization efficiency by the hybrid rice after anthesis was 7.8% higher than that by the ordinary rice variety, and the nitrate fertilizer recovery fraction by the former was 13.2% greater than that by the latter. The varietal difference in NO_3"--N uptake and utilization was almost twice as that in NH_4"+-N. It was also showed that "1"5N distribution in ear of the hybrid rice was about 20% greater than that of the conventional variety, but there were no obvious differences between NO_3"--N and NH_4"+-N. However, "1"5N distribution in the lower node leaves and root was found to be significant higher with NO_3"--N than that with NH_4"+-N in both rice varieties, particularly in the hybrid rice. Compared with NH_4"+-N, NO_3"--N top-dressing before anthesis was observed to have much ...

International Nuclear Information System (INIS)

Aim: There has been a great demand for developments of the radioligands to visualize the N-methyl-D-aspartate (NMDA) receptors by PET/SPECT. We have recently synthesized two C-11 labeled antagonists for the glycine-binding site on NMDA receptors. The aim of this work is to examine for their in vitro and in vivo binding characteristics, and to evaluate their potentials as PET radioligands for the NMDA receptors. Materials and methods: Two C-11 labeled 4-hydroxy-2-quinolones (1 and 2) were synthesized by conventional methylation of the corresponding phenols with ["1"1C]methyl iodide. In vitro and ex vivo quantitative autoradiographs with imaging plate, as well as animal PET, were employed in order to evaluate their in vitro and in vivo binding to the NMDA receptors. Results: The compound 1 showed the specific binding to rat brain slices with higher localization in the hippocampus and cerebral cortex than in the cerebellum. Both glycine antagonists and agonists ...

International Nuclear Information System (INIS)

The oxygen vacancies distribution in the rigid lattice and the thermally activated motion of oxygen atoms are studied in La1-xSrxGa1-xMgxO3-x (x=0.00; 0.05; 0.10; 0.15 and 0.20) compounds. For that 71Ga, 25Mg and 17O NMR was performed from 100 K up to 670 K, and ion conductivity measurements were carried out up to 1273 K. The comparison of the electric field gradients at the Ga- and Mg-sites evidences that oxygen vacancies appear exclusively near gallium cations as a species trapped below room temperature in local clusters, GaO5/2-#square#-GaO5/2. These clusters decay at higher temperature into mobile constituents of the structural octahedra Ga(O5/6#square#1/6)6/2. At the same time, the nearest octahedral oxygen environment of magnesium cations persists at different doping levels. The case of two adjacent vacant anion sites is found highly unlikely within the studied doping range. The thermally activated oxygen motion starts to develop above room temperature as is ...

International Nuclear Information System (INIS)

The first Russian reprocessing facility, known as RT-1 (located at PA-Mayak in Ural region) was started on the radiochemical plant base in 1977. Nowadays RT-1 is the sole operating reprocessing plant in Russia. The main features of RT-1 is its broad spectrum of reprocessing spent nuclear fuels (SNF). The following spent fuel types are reprocessed: -) SNF from PWR reactors (WWER-440) and FB reactor (BN-600); -) SNF of transport ship reactors; -) production reactors SNF; -) research reactor spent nuclear fuel. The world-known technological processes are used at RT-1, but there are the following distinctive features. First, the universality of the three technological lines which allows not only the reprocessing of various SNF kinds, but also to implement the combined reprocessing of some types of them. Secondly, extraction of neptunium during SNF reprocessing which is used to implement its separate storage and for radioisotope production. Thirdly, target enrichment of recycled uranium is ...

Energy Technology Data Exchange (ETDEWEB)

From the crystal field analysis of optical absorption spectra on monoclinic S.G. P2{sub 1}/c MgNd(BO{sub 2}){sub 5}, where Nd{sup 3+} occupies a single crystallographic position with no symmetry elements, energy level schemes and an expression of the associated wavefunctions for the 4f{sup 3} configuration of Nd{sup 3+} have been derived, considering approximate C{sub 2v} and C{sub s} (C{sub 2}) symmetries. Despite of the low symmetry of Nd{sup 3+}, resulting rms deviations between calculated and experimental levels are very satisfactory. The composition of the crystal field wavefunctions from both sets of phenomenological free-ion and crystal field parameters has been checked through a calculation of the thermal evolution of the paramagnetic susceptibility {chi}, according to the Van Vleck formula. The same simulation was performed with crystal field parameters (CFPs) resulting from the ab initio simple overlap model (SOM), considering the Nd{sup 3+} real point symmetry, C{sub 1}. ...

Science.gov (United States)

It is well known that one of the main advantages of the high speed forming (HSF) processes is the improvement in the forming limits of the used materials.Using the Electromagnetic Forming (EMF) technology two materials have been tested with different mechanical and physical properties: the AA5754 aluminium and the AZ31B magnesium alloys.The EMF process principle can be described as follows: A significant amount of electrical energy is stored in a bank of capacitors which are suddenly discharged releasing all the stored energy. This electric discharge runs through a coil which generates an intense transient magnetic field. At the same time transient Eddy currents are induced in the electrically conductive part placed some millimetres far from the coil. Another intense magnetic field is generated due to those Eddy currents but on the opposite direction as the one generated by the coil. A big magnetic repulsion force is created between the part and the coil. This ...

Energy Technology Data Exchange (ETDEWEB)

Lithium-ion batteries are becoming more and more important not only for portable electronic devices, but also in prevision of high power electric vehicles. In such an optic, deep studies regarding all the components of a secondary battery are in development. In this study, high voltage cathode materials have been selected. Crystals with spinel structure have a 3D vacancy pathway suitable for Li-ions transport. The material under study was LiNi{sub 0.5}Mn{sub 1.5}O{sub 4} doped with magnesium replacing the nickel. Various samples were synthesized via three different routes: a solid-state method, a modified sol-gel method and a xerogel method. The structure and morphology of the powders were analyzed with HRTEM and XRD. Electrochemical tests were also performed. A wide range of particle sizes (from micro to nanosize) was the result of the different synthesis routes. Unfortunately pure materials were not always obtained. The electrochemical tests showed improvement of ...

International Nuclear Information System (INIS)

The effects of catalytic metal additives on the hydrogen desorption properties of the submicrocrystalline magnesium hydride (#beta#-MgH_2) formed after hydrogenation of the Mg + 10 wt.%X (X = V, Y, Zr) mechanically (ball) milled composites were studied. The composites with catalytic metals were processed by controlled mechanical milling (CMM) in the magneto-mill Uni Ball Mill 5 under protective Ar atmosphere. X-ray diffraction of the milled powders revealed the formation of Mg nanograins (50-60 nm range) interdispersed with the nanograined metal additives within the powder particles. Scanning electron microscopy showed particle size reduction after milling. After activation and hydrogenation in a Sieverts-type apparatus under about 2 MPa pressure of hydrogen, the tetragonal #beta#-MgH_2 hydride co-exists with the small amount of retained unreacted Mg phase and the small amount of MgO in all three composites. The #beta#-MgH_2 phase after hydrogenation is ...

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Polycrystalline Al2O3, magnesium aluminate spinel (MgAl2O4), MgO, Si3N4, and SiC were irradiated with various ions at 200-450 K, and microstructures were examined following irradiation using cross-section TEM. Amorphization was not observed in any of the irradiated oxide ceramics, despsite damage energy densities up to {similar_to}7 keV/atom (70 displacements per atom). On the other hand, SiC readily amorphized after damage levels of {similar_to}0.4 dpa at room temperature (RT). Si3N4 exhibited intermediate behavior; irradiation with Fe{sup 2+} ions at RT produced amorphization in the implanted ion region after damage levels of {similar_to}1 dpa. However, irradiated regions outside the implanted ion region did not amorphize even after damage levels > 5 dpa. The amorphous layer in the Fe-implanted region of Si3N4 did not appear if the specimen was simultaneoulsy irradiated with 1-MeV He{sup +} ions at RT. By comparison with published results, it is concluded that ...

International Nuclear Information System (INIS)

Quantitative ecological risk assessment (ERA) is a means whereby the risk posed by a toxicant in any system can be evaluated by comparing the distribution of its measured or modelled concentrations (water quality data (WQD)) with available information on the range of concentrations that are known to adversely affect biota within that, or similar, habitats (dose-response data (DRD)). Initially, the WQD are compared with regulatory criteria (e.g. ANZECC and ARMCANZ, 2000). If they fail this test, then, on the assumption that both data sets comprise subsets of the entire range of concentrations, probability density functions are derived assuming a standard distribution form a typically log-normal. In this paper, AQUARISK has been used to estimate the risk posed by copper in effluent from the Rum Jungle mine site, pre- and post-remediation, and the proportion of taxa likely to be affected in the East Branch (EB) of the Finniss River downstream of the mine. In addition, the average ...

Energy Technology Data Exchange (ETDEWEB)

To study the fatigue life of extruded AZ31 (3%Al, 1%Zn, 0.3%Mn, Mg - the rest), AM50 (5%Al, 0.4%Mn, Mg - the rest) and ZK60 (5%Zn, 0.5%Zr, Mg - the rest) Mg alloys in air and NaCl-based solutions, corrosion fatigue tests were carried out using a rotating beam type fatigue machine. For the analysis of the corrosion fatigue behavior of Mg alloys in different environments, fitted N{sub sol}/N{sub air} ratio considered as a relative corrosion fatigue life is used. Here N{sub sol} and N{sub air} are the numbers of cycles to failure in the solution and in air, respectively. An extruded ZK60 alloy shows very high fatigue and corrosion fatigue properties in comparison with other alloys. However, ZK60 shows the lowest values of the relative fatigue life (N{sub sol}/N{sub air} {proportional_to}10{sup -3}-10{sup -2}) compared to that for AM50 and AZ31 alloys (N{sub sol}/N{sub air} {proportional_to}10{sup -2} - 10{sup -1}). Generally, extruded alloys in comparison to earlier studied die-cast ...

Energy Technology Data Exchange (ETDEWEB)

Cretaceous Sunniland Formation rudistid reservoir facies buried at 3,520 meters (92 C) between evaporite units contain marginally mature algal sapropelic carbonate source rock hydrocarbons. The closed system aids in identification of porosity redistribution related to hydrocarbon emplacement. Multiple dissolution and cementation events associated with hydrocarbon migration pulses are particularly evident along stylolites. Corrosion usually predates typically interparticle first generation saddle dolomite, and corroded saddle dolomite may be observed with two generations of optically continuous limpid overgrowths separated by a corrosive boundary. Dissolution or dedolomitization may provide a magnesium source for subsequent dolomite cements. Carbonic and organic acids are probable primary corrosive agents. Moldic, stylolite and fracture porosity, often reduced by dolomite cements, was generated. Moldic pores may develop from peloids by dissolution of peripheral ...

Energy Technology Data Exchange (ETDEWEB)

Various methods for storing hydrogen have been examined in an effort to find ways to store hydrogen in increasingly smaller volumes with decreasing weight of the whole hydrogen storage system. Metal hydrides, in which hydrogen is chemically bound to a metal atom, are considered to be very promising candidates for hydrogen storage because they have high gravimetric and volumetric storage capacities. This study investigated the effect of different magnesium (Mg) and aluminium (Al) ratios on the absorption and desorption properties of thin films. Neutron reflectometry (NR) was used in this study to better understand the absorption and desorption properties of commercially promising hydrogen storage materials. The large negative scattering length of hydrogen atoms changes the reflectivity curve substantially, so that NR can determine the total amount of stored hydrogen as well as the hydrogen distribution along the film normal, with nanometer resolution. In order to ...

International Nuclear Information System (INIS)

Selenium (Se), zinc (Zn), magnesium (Mg), molybdenum (Mo) and vanadium (V) in 28 types of Egyptian common foodstuffs as well as drinking and irrigation water samples were determined using neutron activation analysis (NAA) and atomic absorption spectrometry (AAS). The samples were collected from 74 sites over 13 governorates as well as the Nile river, wells and tap water in the regions of the Nile Delta, Sinai, the east and west desert, and north and south Egypt. These trace elements were chosen according to international references, which show the close relationship of their deficiencies to immunity-related diseases. Calculation values of daily uptake per capita were made with the results of analysis. The results, as calculated per 100 g dry weight, showed that some Egyptian foods are rich in Se including such fish (0.94 #mu#g), sesame (0.88 #mu#g), beef meat (0.48 #mu#g), instant tea (0.42 #mu#g), mushroom (0.34 #mu#g) and eggs (0.3 #mu#g), whereas the vegetables ...

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the research conducted during Budget Period One on the project ''Improved Natural Gas Storage Well Remediation''. The project team consisted of Furness-Newburge, Inc., the technology developer; TechSavants, Inc., the technology validator; and Nicor Technologies, Inc., the technology user. The overall objectives for the project were: (1) To develop, fabricate and test prototype laboratory devices using sonication and underwater plasma to remove scale from natural gas storage well piping and perforations; (2) To modify the laboratory devices into units capable of being used downhole; (3) To test the capability of the downhole units to remove scale in an observation well at a natural gas storage field; (4) To modify (if necessary) and field harden the units and then test the units in two pressurized injection/withdrawal gas storage wells; and (5) To prepare the project's final report. This report covers activities ...