WorldWideScience
1

Lithology and evolution of the crust-mantle boundary region in the southwestern Basin and Range province  

Energy Technology Data Exchange (ETDEWEB)

Seismic transects in this area show a strongly reflective Moho of generally low relief, which, in the area of modern transects, consists of a thin zone (< 2 km thick) of short reflectors. The upper mantle is transparent and has a P{sub n} of 7.8-8.0 km/s similar to much of the western US. A lower crustal zone, 2-13 km thick, has variable internal reflectivity and a relatively low velocity of 6.6-6.8 km/s. Upper mantle peridotite xenoliths show both ductile and brittle deformational features and have structures and composition affected by magmatic intrusion; intrusions form complex dike systems and extensive zones of grain boundary infiltration in peridotite xenoliths. Whereas melt infiltration preceded and followed ductile deformation, brittle deformation, represented by closely spaced joint systems and faults, followed ductile deformation and is related to the youngest magmatic episodes. Lower crustal xenoliths are dominantly ...

1990-01-10

2

Periodicity of the Phanerozoic magmatism in Mongolia from potassium-argon data  

International Nuclear Information System (INIS)

An attempt was made to set the main potassium-argon (PA) boundaries in magmatism development in the territory of Mongolia. Results were correlated with the known concepts about periodicity of magmatism. Possibility of using PA analysis for separation of magmatic rocks was evaluated. Reliable correlation of significant PA boundaries of magmatism with geological periodization of tectonomagmatic events in Mesozoic era and Late Paleozoic era was established.

1989-01-01

3

Aqueous drilling fluids containing fluid loss additives  

Energy Technology Data Exchange (ETDEWEB)

This patent describes an aqueous clay containing drilling fluid having present in an amount sufficient to reduce fluid loss of the drilling fluid, a copolymer of (1) from about 80% to about 98% by weight of acrylic acid and (2) from about 2% to about 20% by weight of itaconic acid. The copolymer has a weight average molecular weight of between about 50,000 to about 1,000,000, being in its free acid or partially or completely neutralized salt form and being at least water dispersible.

1987-03-03

4

Effects of Sildenafil and Tadalafil on Intraocular Pressure in Sheep: Implications for Aqueous Humor Dynamics  

UK PubMed Central (United Kingdom)

Purpose.To determine the effects of vasodilators on intraocular pressure (IOP) and the protein content of sheep aqueous humor (AH), because the vasodilators may increase fluid leakage...Full Text Available

2010-06-01

5

Development document for proposed effluent limitations guidelines and standards for synthetic-based drilling fluids and other non-aqueous drilling fluids in the oil and gas extraction point source category  

Science.gov (United States)

The purpose of this rulemaking is to amend the effluent limitations guidelines and standards for the control of discharges of certain pollutants associated with the use of synthetic-based drilling fluids (SBFs) and other non-aqueous drilling fluids in portions of the Offshore Subcategory and Cook Inlet portion of the Coastal Subcategory of the Oil and Gas Extraction Point Source Category. These proposed limitations apply to discharges or effluent generated when oil and gas wells are drilled using SBFs or other non-aqueous drilling fluids (collectively referred to simply as SBFs) in coastal and offshore regions in locations where drilling wastes may be discharged.

1999-02-01

6

Thermally stable drilling fluid additive  

Energy Technology Data Exchange (ETDEWEB)

This invention relates to a water soluble polymer and method for its preparation. The water soluble polymer exhibits superior thermal stability characteristics when used as an additive in aqueous drilling fluids. The polymer consists of a major portion of a catechol based monomer and a dicarboxylic acid. Other monomers and materials are added to enhance the functional characteristics of the drilling fluid additive. The method of this invention includes the mixing of monomers, polymerization of that mixture and optionally the steps of hydrolysis and sulfonation.

1985-06-25

7

The stability of synthetic cutting fluids to microbe damage  

Energy Technology Data Exchange (ETDEWEB)

The resistance to microbe damages of aqueous solutions of cutting fluids (SOZh), which contain dual and more complex mixtures of known compounds, is studied. Lauric acid, myristic and tridecanic acid give microbic resistance to the compositions of synthetic cutting fluids. A complexing of the compositions as a rule does not support precisely expressed effects of synergism or antagonism.

1983-01-01

8

Adsorption Kinetics of Surfactants at Fluid-Fluid Interfaces  

CERN Document Server

We review a new theoretical approach to the kinetics of surfactant adsorption at fluid-fluid interfaces. It yields a more complete description of the kinetics both in the aqueous solution and at the interface, deriving all equations from a free-energy functional. It also provides a general method to calculate dynamic surface tensions. For non-ionic surfactants the results coincide with previous models. Common non-ionic surfactants are shown to undergo diffusion-limited adsorption, in agreement with experiments. Strong electrostatic interactions in salt-free ionic surfactant solutions are found to lead to kinetically limited adsorption. In this case the theory accounts for unusual experimental results which could not be understood using previous approaches. Added salt screens the electrostatic interactions and makes the ionic surfactant adsorption similar to the non-ionic case. The departure from the non-ionic behavior as the salt concentration ...

1997-01-01

9

Economic analysis of proposed effluent limitations guidelines and standards for synthetic-based drilling fluids and other non-aqueous drilling fluids in the oil and gas extraction point source category  

Science.gov (United States)

The Economic Analysis (EA) report is written to address the impacts of this proposed Effluent Limitation Guidelines and Standards for Synthetic-Based and Other Non-Aqueous Drilling Fluids. Currently, effluent guidelines pertaining to the discharge of drilling fluids address two specific types of fluids: Oil-based drilling fluids (OBFs) that use diesel and mineral oil, which are prohibited from being discharged; and Water-based drilling Fluids (WBFs), which can be discharged subject to meeting certain discharge requirements, including a sheen test and an aqueous toxicity test, in certain limited offshore regions. Section Two presents sources of data, Section Three presents the industry profile, Section Four discusses the regulatory costs of options under consideration for the proposed rulemaking, and Section Five discusses the impacts of the ...

1999-02-01

10

The effect of flow velocity on pitting corrosion and stress corrosion cracking of reactor materials  

International Nuclear Information System (INIS)

This paper describes two research programs which are currently underway in the author's laboratory to investigate the effect of fluid flow on the degradation of power plant materials in high temperature/high pressure aqueous environments. These programs include the design and operation of a controlled hydrodynamic corrosion testing apparatus that can be used to study the general and localized corrosion characteristics of alloys in simulated nuclear reactor environments, and a study of the effect of flow velocity on the stress corrosion cracking of ASTM A508 C1.2 steel and Type 304SS in simulated BWR heat transport fluids.

11

Test plan for Geo-Cleanse{reg_sign} demonstration (in situ destruction of dense non-aqueous phase liquid (DNAPL))  

Energy Technology Data Exchange (ETDEWEB)

Soils and groundwater beneath an abandoned process sewer line in the A/M Area of the Savannah River Site (SRS) contain elevated levels of volatile organic compounds, specifically trichloroethylene (TCE) and tetrachloroethylene (PCE), two common chlorinated solvents. These compounds have low aqueous solubilities, thus when released to the subsurface in sufficient quantity, tend to exist as immiscible fluids or nonaqueous phase liquids (NAPLs). Because chlorinated solvents are also denser than water, they are referred to by the acronym DNAPLs, or dense non-aqueous phase liquids. Technologies targeted at the efficient characterization or removal of DNAPL are not currently proven. For example, most DNAPL studies rely on traditional soil and water sampling and the fortuitous observation of immiscible solvent. Once DNAPL is identified, soil excavation (which is only applicable to small contained spill sites) is the only proven ...

1996-09-01

12

Nanoparticle arrays formed by spatial compartmentalization in a complex fluid.  

Energy Technology Data Exchange (ETDEWEB)

A mesoscopically ordered lamellar gel phase of a polymer-grafted, lipid-based complex fluid is used as a scaffolding to spatially organize inorganic nanoparticles. The complex fluid provides both a highly anisotropic environment and a segregated aqueous and organic domains in which inorganic nanoparticles can be selectively placed by tailoring their size and surface characteristics. Three types of silver nanoparticles -- underivatized, surfactant-stabilized, and dodecanthiol-derivatized -- were evaluated. Comparison of the surface plasmon resonance of the various silver particles dispersed in conventional solvents to those contained within the complex fluid was used to determine the region of spatial localization in the lamellar gel phase. Silver particles rendered hydrophobic by capping with an alkane thiol insert into the hydrocarbon bilayer region. Surfactant-stabilized and underivatized silver ...

2001-03-14

13

Chemical absorption of carbon dioxide with aqueous sodium hydroxide solution spray  

Energy Technology Data Exchange (ETDEWEB)

Measurements of local mass fluxes of liquid, local number fluxes of the drop and local drop size distributions at various locations in the test column were made for wide ranges of liquid flow rates and gas flow rates. An empirical correlation for the volume mean diameter of the drop at the nozzle exit was proposed. Measurements of the rates of absorption of carbon dioxide from carbon dioxide-air mixtures with water sprays (physical absorption) and aqueous sodium hydroxide sprays (chemical absorption) were made for wide range so fluid flow rates, feed gas concentrations, and initial alkali concentrations. The observed dimensionless rates of absorption were compared with the theoretical values by assuming penetration model with second-order irreversible reaction. 11 refs., 7 figs.

1996-12-31

14

Supercritical Fluid Immersion Deposition: A New Process for Selective Deposition of Metal Films on Silicon Substrates  

Energy Technology Data Exchange (ETDEWEB)

Supercritical CO2 is used as a new solvent for immersion deposition, a galvanic displacement process traditionally carried out in aqueous HF solutions containing metal ions, to selectively develop metal films on featured or non-featured silicon substrates. Components of supercritical fluid immersion deposition (SFID) solutions for fabricating Cu and Pd films on silicon substrates are described along with the corresponding experimental setup and procedure. Only silicon substrates exposed and reactive to SFID solutions can be coated. The highly pressurized and gas-like supercritical CO2, combined with the galvanic displacement property of immersion deposition, enables the SFID technique to selectively deposit metal films in small features. SFID may also provide a new method to fabricate palladium silicide in small features or to metallize porous silicon.

2005-01-01

15

Fundamental Chemistry And Thermodynamics Of Hydrothermal Oxidation Processes  

Science.gov (United States)

Hydrothermal oxidation (HTO) is a promising technology for the treatment of aqueous-fluid hazardous and mixed waste streams. Waste streams identified as likely candidates for treatment by this technology are primarily aqueous fluids containing hazardous organic compounds, and often containing inorganic compounds including radioisotopes (mixed wastes). These wastes are difficult and expensive to treat by conventional technologies (e.g. incineration) due to their high water content; in addition, incineration can lead to concerns related to stack releases. An especially attractive potential advantage of HTO over conventional treatment methods is the total containment of all reaction products within the overall system. The potential application of hydrothermal oxidation (HTO) technology for the treatment of DOE hazardous or mixed wastes has been uncertain due to concerns about safe and efficient operation of the technology. In ...

2001-12-31

16

Continental-scale magmatic carbon dioxide seepage recorded by dawsonite in the Bowen-Gunnedah-Sydney basin system, eastern Australia  

Energy Technology Data Exchange (ETDEWEB)

Dawsonite, NaAlCO{sub 3}(OH){sub 2}, is widespread as a cement, replacement, and cavity filling in Permo-Triassic sedimentary rocks of the Bowen-Gunnedah-Sydney basin system eastern Australia. The origin of dawsonite in these rocks was studied by petrographic and stable isotope analysis. Dawsonite {delta}{sup 13}C (PDB) values range from {minus}4.0 to +4.1{per_thousand} and are remarkably consistent throughout the Bowen-Gunnedah-Sydney basin system. These values indicate either a marine carbonate or magmatic source for carbon in the dawsonite. A magmatic carbon source is considered more likely on the basis that (1) evidence of and the cause for widespread marine carbonate dissolution in the sedimentary successions are not apparent, (2) dawsonite is widespread in both marine and nonmarine facies, (3) the region has been the site of major igneous activity, (4) other dawsonite deposits of similar carbon isotopic composition are linked to igneous ...

1995-07-03

17

Degradation of materials under conditions of the sulfur-iodine thermochemical cycle  

Energy Technology Data Exchange (ETDEWEB)

The sulfur-iodine (SI) thermochemical cycle is one of the main candidate methods to produce hydrogen from non-fossil sources like nuclear (GEN IV reactor) or solar thermal power. A major issue for the successful implementation of the SI cycle is the selection of technically viable and economic materials for construction of process components, particularly heat exchangers. Challenging conditions are encountered in each of the three sections of the SI cycle due to the corrosive chemicals present, including sulfuric acid, iodine, hydroiodic acid, sulfur dioxide, hydrogen, oxygen, and others. In Section I, aqueous, non-aqueous (liquid iodine), and gaseous multi-component phases are present at about 120 {sup o}C and 0.7 MPa. Section II involves gaseous and aqueous phases of sulfuric acid, sulfur dioxide, and oxygen at up to about 830 {sup o}C and 3.6 MPa. In Section III , aqueous, ...

2009-07-01

18

Test plan for single well injection/extraction characterization of DNAPL  

Energy Technology Data Exchange (ETDEWEB)

Soils and groundwater beneath an abandoned Process sewer line in the A/M Area of the Savannah River Site (SRS) contain elevated levels of volatile organic compounds, specifically trichloroethylene (TCE) and tetrachloroethylene (PCE), two common chlorinated solvents. These compounds have low aqueous solubilities, thus when released to the subsurface in sufficient quantity, tend to exist as immiscible fluids or nonaqueous phase liquids (NAPLs). Because chlorinated solvents are also denser than water, they are referred to by the acronym DNAPLS, or dense non aqueous Phase liquids. Technologies targeted at the efficient characterization or removal of DNAPL are not currently proven. For example, most DNAPL studies rely on traditional soil and water sampling and the fortuitous observation of immiscible solvent. Once DNAPL is identified, soil excavation (which is only applicable to small contained spill sites) is the only ...

1995-12-01

19

Imazalil-cyclomaltoheptaose (beta-cyclodextrin) inclusion complex: preparation by supercritical carbon dioxide and 13C CPMAS and 1H NMR characterization.  

Science.gov (United States)

An inclusion complex between imazalil (IMZ), a selected fungicide, and cyclomaltoheptaose (beta-cyclodextrin, betaCD) was obtained using supercritical fluid carbon dioxide. The best preparation conditions were determined, and the inclusion complex was investigated by means of 1H NMR spectroscopy in aqueous solution and 13C CPMAS NMR spectroscopy in the solid state. Information on the geometry of the betaCD/IMZ complex was obtained from ROESY spectroscopy, while the dynamics of the inclusion complex in the kilohertz range was obtained from the proton spin-lattice relaxation times in the rotating frame, T(1rho) (1H). PMID:14553984

2003-10-10

20

Experimental study of convective self-oscillations near the lateral surface of a bubble in a plane rectangular channel  

British Library Electronic Table of Contents (United Kingdom)

Experimental investigations have been performed to study solutal convection around an air bubble squeezed between the walls of a horizontal rectangular channel, filled by an aqueous solution of surfactant with vertically stratified concentration. A convective motion in the fluid develops due to the solutocapillary Marangoni forces at the bubble lateral free surface. The structure and evolution of the convective flow and the surfactant concentration fields in the channel have been investigated using interferometric technique. The tests revealed the development of self-oscillatory modes near the bubble surface, related to the interaction between solutocapillary and solutogravitational motion mechanisms. The time dependences of the oscillations period are analyzed in relation to the average c...

2008-01-01

21

Aqueous water-soluble soap lubricant concentrates and aqueous lubricants containing same  

Energy Technology Data Exchange (ETDEWEB)

The inclusion of neodecanoic acid in aqueous water-soluble soap lubricants reduces viscosity, and improves lubricity effectiveness.

1981-06-23

23

Surface Decontamination by Solution  

International Science & Technology Center (ISTC)

Development of Technology for Metal Surface Decontamination in Aqueous Solutions

24

MINEQL-PC. Chemical Equilibrium Composition of Aqueous Systems  

Energy Technology Data Exchange (ETDEWEB)

MINEQL is a subroutine package to calculate equilibrium composition of an aqueous system, accounting for mass transfer.

1986-11-21

25

The role of oxygen diffusion in the release of technetium from reducing cementitious waste forms  

Energy Technology Data Exchange (ETDEWEB)

Cementitious materials provide an ideal geochemical environment (e.g., high pH pore fluids and large surface areas for sorption) for immobilizing nuclear waste. The inclusion of reducing agents, such as blast furnace slag (BFS) can immobilize radionuclides by forming of solid sulfide phases. Thermodynamic calculations using the MINTEQ geochemical computer code indicate the elemental sulfur present in BPS reacts with the highly mobile pertechnetate anion (TcO{sub 4}{sup -}) anion to form an insoluble technetium sulfide phase (Tc{sub 2}S{sub 7(s)}). Initially, the waste form very effectively immobilizes technetium. However, as oxygen diffuses into the waste form, an outer zone of oxidized concrete and a shrinking core of reduced intact concrete develops. Oxidation of sulfur in the outer zone results in increased technetium concentrations in the pore fluid because Tc{sub 2}S{sub 7(a)} oxidizes to the mobile TcO{sub 4}{sup -} anion. The TcO{sub ...

1993-12-31

26

Analysis on uranium resource situations and metallogenic potential of Heyuan mineralization belt of Guangdong province  

International Nuclear Information System (INIS)

Heyuan mineralization belt is a structure-magmatic activities belt which is charcterized by strong plastic deformation and shearing. The squeeze (overthrust) structure is formed early. Later stretch produced slide shovel-shaped normal fault which control the red basin and uranium mineralization. Comprehensive study shows that this area is of favorable uranium metallogenic condition due to the rich uranium source and higher degree of geology work, it is a target for the new round resources exploration. (authors)

2008-03-01

27

Precious metal enrichment in the Platreef, Bushveld Complex, South Africa: evidence from homogenized magmatic sulfide melt inclusions  

Science.gov (United States)

Magmatic sulfide deposits are the most significant source of platinum-group elements (PGE) in the world. Key to understanding their genesis is determining the processes and timing of sulfide saturation, metal enrichment and crustal contamination. In this study, we have identified droplets of magmatic sulfide from the Platreef, South Africa, where droplets of sulfide have been trapped in the earliest crystallising phase, chromite. Due to their early entrapment at high temperatures, metal concentrations and ratios that they display are indicative of a very early-stage sulfide liquid in the system, as they will have cooled and fractionated within an essentially closed system, unlike interstitial blebs that crystallise in an open system as the magma cools. Analysis of these droplets in an opaque mineral like chromite by LA-ICP-MS is problematic as some of the fractionated inclusion is necessarily lost during cutting and polishing to initially ...

2011-06-01

28

Electromagnetic fluid valve  

International Nuclear Information System (INIS)

... bypasses control rod drives cylinders electromagnetic pumps fluid flow fluidic

30

The nucleation kinetics of calcium sulfate dihydrate in NaCl solutions up to 6 m and 90 C  

Energy Technology Data Exchange (ETDEWEB)

The crystallization of calcium sulfate from aqueous solutions with NaCl is both geological and industrial interest because NaCl is the dominant solute in natural brines and many industrial fluids. Induction periods for the nucleation of calcium sulfate dihydrate were experimentally determined as a function of supersaturation in NaCl solutions from 0 to 6 m at 25 C and in 3.0-m NaCl solutions at temperatures from 25 to 90 C. Using classic nucleation theory, the interfacial tension between gypsum and 3.0-m NaCl solution was estimated to be about 39 mJ/m[sup 2] at 25 C and increases with increasing temperature (to 63 mJ/m[sup 2] at 90 C). It was observed that the induction period decreases with increasing NaCl concentrations up to 3 m and then starts to increase slightly at a given temperature and saturation state. The electrolyte effect on nucleation was proportional to the enhanced solubility of calcium sulfate dihydrate in NaCl solutions. This ...

1994-02-01

31

Dihydroxybenzene/benzoquinone-containing polymers: organic redox polymers  

Energy Technology Data Exchange (ETDEWEB)

Polymers containing hydroquinone, catechol or their corresponding benzoquinones are a special class of redox polymers. Three pathways of their syntheses are possible: condensation polymerization of suitable monomers, addition polymerization of vinyl monomers containing redox moiety, and chemical attachment of redox unit onto pre-made polymeric matrix. A range of functionalized matrices have been employed such as polyethers, polyesters, polycarbonates, polyurethanes, polyamides and others. Protection of their phenolic functionality has conducted to chemically interesting redox polymer precursors. The presence of a redox moiety coupled with the extant functionalization of the polymer matrix makes the materials very valuable, of wide properties and consequently of vast applicability. For instance, in the oil field, some polymers such as carboxy-methyl-cellulose (CMC) are often applied as to bring about a viscosity improvement and therefore to facilitate the oil drilling. In this regard, ...

2000-08-01

32

Anti-cancer drug loaded iron-gold core-shell nanoparticles (Fe@Au) for magnetic drug targeting.  

Science.gov (United States)

Magnetic drug targeting, using core-shell magnetic carrier particles loaded with anti-cancer drugs, is an emerging and significant method of cancer treatment. Gold shell-iron core nanoparticles (Fe@Au) were synthesized by the reverse micelle method with aqueous reactants, surfactant, co-surfactant and oil phase. XRD, XPS, TEM and magnetic property measurements were utilized to characterize these core-shell nanoparticles. Magnetic measurements showed that the particles were superparamagnetic at room temperature and that the saturation magnetization decreased with increasing gold concentration. The anti-cancer drug doxorubicin (DOX) was loaded onto these Fe@Au nanoparticle carriers and the drug release profiles showed that upto 25% of adsorbed drug was released in 80 h. It was found that the amine (-NH2) group of DOX binds to the gold shell. An in vitro apparatus simulating the human circulatory system was used to determine the retention of these nanoparticle ...

2010-09-01

33

A hydroxide mixture as working fluid for absorption heat pumps  

Energy Technology Data Exchange (ETDEWEB)

Basic experimental investigations were carried out with an aqueous solution of a mixture of KOH and NaOH for use as an absorbent in absorption heat pumps. Due to its thermophysical properties this mixture allows temperature lifts from evaporator to absorber of more than 75 K (135 F) in a single-stage absorption chiller. Thermophysical and hydrodynamical properties of the solution were measured. Vapor-liquid-equilibrium data and specific heat capacities were determined for concentrations ranging from 35% up to 75% and temperatures up to 200 C (392 F). From these data the enthalpy of the solution was calculated. Additionally the crystallization temperatures, the density, and the viscosity of the solution were determined. The experimental equipment is described. The data are presented as polynomials and diagrams including experimental accuracy. An apparatus was constructed to measure heat and mass transfer coefficients of the absorption process with this solution. The ...

1996-11-01

34

Quantitation of microbial products and their effectiveness in enhanced oil recovery. Final report  

Energy Technology Data Exchange (ETDEWEB)

A three-dimensional, three-phase, multiple-component numerical simulator was developed to investigate transport and growth of microorganisms in porous media and the impacts of microbial activities on oil recovery. The microbial activities modeled in this study included: (1) growth, retention, chemotaxis, and end product inhibition of growth, (2) the formation of metabolic products, and (3) the consumption of nutrients. Major mechanisms for microbial enhanced oil recovery (MEOR) processes were modeled as follows: (1) improvement in sweep efficiency of a displacement process due to in situ plugging of highly-permeable production zones by cell mass or due to improved mobility control achieved by increasing the viscosity of the displacing fluid with a biopolymer, and (2) solubilization and mobilization of residual oil in porous media due to the reduction of the interfacial tension between oleic and aqueous phases by the production of a ...

1995-02-01

35

Carboxymethylation of peat in 2-propanol  

British Library Electronic Table of Contents (United Kingdom)

The effects of the time and temperature of alkaline pretreatment and the time and temperature of the carboxymethylation of peat in 2-propanol on the concentration of carboxymethyl groups and the solubility of the resulting products in water and an aqueous alkali solution were studied. The viscosity characteristics of the aqueous and aqueous alkaline solutions of peat carboxymethylation products were studied.

2011-01-01

36

SAMFT1D: Single-phase and multiphase flow and transport in 1 dimension. Version 2.0, Documentation and user`s guide  

Energy Technology Data Exchange (ETDEWEB)

This report documents a one-dimensional numerical model, SAMFT1D, developed to simulate single-phase and multiphase fluid flow and solute transport in variably saturated porous media. The formulation of the governing equations and the numerical procedures used in the code for single-phase and multiphase flow and transport are presented. The code is constructed to handle single-phase as well as two or three-phase flow conditions using two integrated sets of computational modules. The fully implicit scheme is used in the code for both single-phase and multiphase flow simulations. Either the Crank-Nicholson scheme or the fully implicit scheme may be used in the transport simulation. The single-phase modules employ the Galerkin and upstream weighted residual finite element techniques to model flow and transport of water (aqueous phase) containing dissolved single-species contaminants concurrently or sequentially, and include the treatment of ...

1991-09-01

37

Installations having pressurized fluid circuits  

International Nuclear Information System (INIS)

It is an object of the present invention to provide an improved installation having a pressurized fluid circuit incorporating fluidic brakes for restricting fluid flow through a breach of the installation. (author).

39

Proterozoic kimberlites and lamproites and a preliminary age for the Argyle lamproite pipe, Western Australia  

International Nuclear Information System (INIS)

The Argyle pipe occurring in the East Kimberley Province of Western Australia is a unique, highly-diamondiferous lamproite. Although it resembles other lamproites located in the West Kimberley Province with respect to its setting, structure, petrography and geochemistry, it is probably Proterozoic in age and hence substantially older than Tertiary occurrences of the West Kimberley Province. Rb-Sr measurements on whole rock and phlogopite samples from magmatic olivine-phlogopite lamproite, reveals a two point model age of 1126 +- 9 Ma for the Argyle pipe. This age is consistent with ages of other, similar volcanic igneous rocks occurring in several localities worldwide. The widespread occurrence of Proterozoic kimberlites and lamproites suggests that this was an important period of worldwide alkalic intrusive activity.

40

Gas-dynamic signs of explosive eruptions of volcanoes. 2. Model of homogeneous-heterogeneous nucleation. Specific features of destruction of the cavitating magma  

British Library Electronic Table of Contents (United Kingdom)

The dynamics of state of the crystallite-containing magma is studied within the framework of the gas-dynamic model of bubble cavitation. The effect of crystallites on flow evolution is considered for two cases: where the crystallites are cavitation nuclei (homogeneous-heterogeneous nucleation model) and where large clusters of crystallites are formed in the magma in the period between eruptions. In the first case, decompression jumps are demonstrated to arise as early as in the wave precursor; the intensity of these jumps turns out to be sufficient to form a series of discrete zones of nucleation ahead of the front of the main decompression wave. Results of experimental modeling of an explosive eruption with ejection of crystallite clusters (magmatic ?bombs??) suggest that a cocurrent flow...

2009-01-01

41

Evaluation of minderal resource potential, Caldera geology, and volcano-tectonic framework at and near Yucca Mountain, Task 3  

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the results of Task 3 work that was initially discussed in our monthly reports for the period October 1, 1992 through September 30, 1993, and contained in our various papers and abstracts, both published and currently in press or in review. Our work during this period was involved (a) the continuation of studies begun prior to October, 1992, focussed mainly on aspects of the caldera geology, volcanic stratigraphy, magmatic activity, hydrothermal mineralization and extensional tectonics of the western and northwestern parts of the southwestern and Nevada volcanic field (SWNVF), studies of the subsurface rocks of Yucca Mountain utilizing drill hole samples obtained in 1991 and 1992, and (b) new studies of veins and siliceous rocks cropping out in northwestern Yucca Mountain that provide evidence for previously unrecognized hydrothermal activity during the Crater Flat Tuff period of volcanism.

1993-09-30

42

A Late Holocene explosive mafic eruption of Villarrica volcano, Southern Andes: The Chaimilla deposit  

British Library Electronic Table of Contents (United Kingdom)

Villarrica (Chile) is one of the most active volcanoes in South America having erupted about 60 times in the last 460years. Although its historical eruptive activity has been mainly effusive and weakly explosive, it had strong explosive behaviour in postglacial times. Chaimilla (<3.1ka) is one of the best exposed and widely dispersed pyroclastic deposits, related to both fall and flow activity. The deposit is dispersed over an area of 250km^2 and consists of 8 units (A-H) which were grouped into four sequences. Stratigraphic data suggest that the eruption had a relatively short duration and evolved from i) an Opening phase, dispersing ash, lapilli clasts, accretionary lapilli, blocks and bombs, to ii) a Pulsatory phase, originating a series of magmatic explosions, to iii) a Collapsing phas...

2011-01-01

47

Integrated Reconfigurable Intelligent Systems (IRIS) for ...  

Science.gov (United States)

... They comprise of a power model for the representation of the electric system, a fluid model that represents the cooling fluid flow, three layers of ...

2009-10-31

48

Complex fluid analysis with the advanced distillation curve approach.  

Science.gov (United States)

An improved method for measuring distillation curves reveals the physicochemical properties of complex fluids such as fuels. PMID:20041713

2010-02-01

54

The platinum group elements and gold: analysis by radiochemical and instrumental neutron activation analysis and relevance to geological exploration and related problems  

Energy Technology Data Exchange (ETDEWEB)

This paper presents an overview of research conducted with the support of the Australian Institute of Nuclear Science and Engineering, at the University of Melbourne, School of Earth Sciences, Radiochemical Neutron Activation Laboratory. The primary objective of this research is to realize the high potential of the platinum group elements (PGE) and gold to the solution of petrogenetic problems, the study of magma generation and magmatic processes in mafic/ultramafic rock suites, as tracers in hydrothermal ore formation. The PGEs (Os, Ru, Ir, Pt, Pd and Rh) are among the least abundant of all elements on earth with unique properties such as high melting points, high electrical and thermal conductivity, high density, strength and toughness as alloys. They exhibit both siderophile and chalcophile characteristics and are valuable tools in providing information about magmatic processes, in particular S-saturation, as well as crystal fractionation ...

1996-12-31

55

STOMP Subsurface Transport Over Multiple Phases Version 1.0 Addendum: ECKEChem Equilibrium-Conservation-Kinetic Equation Chemistry and Reactive Transport  

Energy Technology Data Exchange (ETDEWEB)

Geologic sequestration is currently being practiced and scientifically evaluated as a critical component in a broad strategy, comprising new practices and technologies, for mitigating global climate change due to anthropogenic emissions of CO2. Demonstrating that geologic sequestration of CO2 is safe and effective, and gaining public acceptance of sequestration technologies are critically important in meeting these global climate change challenges. Monitored field-scale demonstrations of geologic sequestration of carbon dioxide will contribute greatly toward growing trust and confidence in the technology; however, pilot demonstrations ultimately will not be the norm for new geological sequestration deployments. Instead, scientists, engineers, regulators, and ultimately the public will rely on numerical simulations to predict the performance of geologic repositories for carbon dioxide sequestration. The U.S. Department of Energy (DOE), through the National Environmental Technology ...

2005-12-01

56

Method for detecting and diagnosing disease caused by pathological protein aggregation  

Energy Technology Data Exchange (ETDEWEB)

A method is provided for detecting pathological macromolecules in a patient. The method is comprised of the following: obtaining body fluid from the patient; pretreating the body fluid; subjecting the pretreated body fluid to size-exclusion chromatography to create an excluded fluid; and analyzing the excluded fluid to detect macromolecules having a predetermined molecular weight. The method also allows for comparing elution spectra with reference spectra of suspect pathologic proteins.

2000-05-16

57

Drilling fluid/formation interaction at simulated in situ geothermal conditions. Final report  

Energy Technology Data Exchange (ETDEWEB)

Interaction of drilling fluids with a geothermal reservoir formation can result in significant permeability impairment and therefore reduced well productivity. This interaction is studied under simulated in situ geothermal conditions of overburden stress, pore fluid pressure, temperature, and pore fluid chemistry. Permeability impairment of an East Mesa KGRA reservoir material is evaluated as a function of stagnation time, drilling fluid, and temperature. Results indicate that all of these parameters contribute significantly to the magnitude and the reversibility of the impairment.

1980-07-01

58

Destruction of Salmonellae on poultry meat with lysozyme, EDTA, x ray, microwave, and chlorine  

International Nuclear Information System (INIS)

Lysozyme, ethylenediaminetetracetic acid, chlorine, x-irradiation and microwaves were used in experimental attempts to eliminate Salmonella senftenberg 775W or Salmonella typhimurium from turkey drumsticks and whole carcasses. Turkey drumsticks or whole carcasses were artificially contaminated with S. senfenberg 775W or S. typhimurium in concentrations ranging between 5 x 10"5 to 8 x 10"5 viable cells per ml. of contaminating fluid. After each treatment, samples were cultured, plated, and tested according to standard methods to determine the susceptibility of Salmonella organisms to the particular treatment. A 0.1 percent solution of lysozyme eliminated the S. senftenberg 775W at 22"0C within three hours. A 0.5 percent solution of ethylenediaminetetracetic acid failed to destroy the test organism under the same conditions. Eighty thousand rads of X-ray eliminated the test organism on turkey drumsticks but failed to remove it from whole turkey carcasses. Microwaves ...

59

Coupled modeling of non-isothermal multiphase flow, solutetransport and reactive chemistry in porous and fractured media: 1. ModelDevelopment and Validation  

Energy Technology Data Exchange (ETDEWEB)

Coupled modeling of subsurface multiphase fluid and heat flow, solute transport and chemical reactions can be used for the assessment of acid mine drainage remediation, mineral deposition, waste disposal sites, hydrothermal convection, contaminant transport, and groundwater quality. Here they present a numerical simulation model, TOUGHREACT, which considers non-isothermal multi-component chemical transport in both liquid and gas phases. A wide range of subsurface thermo-physical-chemical processes is considered. The model can be applied to one-, two- or three-dimensional porous and fractured media with physical and chemical heterogeneity. The model can accommodate any number of chemical species present in liquid, gas and solid phases. A variety of equilibrium chemical reactions is considered, such as aqueous complexation, gas dissolution/exsolution, cation exchange, and surface complexation. Mineral dissolution/precipitation can proceed either ...

1998-09-01

60

Cytokine signalling in rat pulp interstitial fluid and transcapillary fluid exchange during lipopolysaccharide-induced acute inflammation  

UK PubMed Central (United Kingdom)

The dental pulp consists of loose connective tissue encased in rigid dentinal walls. Because of its topography the tissue has low interstitial compliance and limited capacity to expand during fluid...Full Text Available

2006-05-15

61

Changes in the surface fine structure of ependyma of the rat third ventricle following operative leakage of cerebrospinal fluid.  

UK PubMed Central (United Kingdom)

The role of the ventricular ependyma in the elaboration of cerebrospinal fluid under resting conditions is well documented. In an attempt to elucidate its response to cerebrospinal fluid leakage, male...Full Text Available

1985-01-01

62

Structural aspects of lithium ions hydration in aqueous solutions of electrolytes  

International Nuclear Information System (INIS)

Analysis of results of an investigation into the structure of lithium salt aqueous solutions is presented. An anomaly in lithium ion behaviour in solutions at the structural level is noted. 40 refs., 3 tabs.

63

Mean distance of closest approach of alkaline-earth metals ions in aqueous solutions: Experimental and theoretical calculations  

British Library Electronic Table of Contents (United Kingdom)

The estimation of numerical values of the mean distance of closest approach of ions, a, of alkaline-earth metal ion salts in aqueous solutions, determined from activity coefficients, as well as from different theoretical approaches, is presented and discussed.

2010-01-01

64

Effect of association processes on polymerization of N-[3-(dimethylamino)propyl]methacrylamide salts in aqueous solutions  

British Library Electronic Table of Contents (United Kingdom)

The effect of associative interactions of monomers and propagating macroradicals in homopolymerization of N-[3-(dimethylamino)propyl]methacrylamide salts and their copolymerization with acrylonitrile and acrylamide in aqueous solution was studied.

2010-01-01

65

Adsorption of di-2-ethylhexylphosphoric acid from toluene at interface with inorganic salt aqueous solutions  

International Nuclear Information System (INIS)

Interfacial tension at the aqueous solution of di-2-ethylhexylphosphoric acid or its copper salts/water solutions has been measured by the drop volume method.

67

Thermodynamic modeling of acidic gas solubility in aqueous solutions of MEA, MDEA and MEA-MDEA blends  

DEFF Research Database (Denmark)

The thermodynamic framework that was developed in a previous work [Vrachnos et al. Ind. Eng. Chem. Res. 2004, 43, 2798] for the description of chemical and vapor-liquid equilibria of carbon dioxide, hydrogen sulfide, and their mixtures in aqueous methyldiethanolamine (MDEA) solutions is revised and extended in this study to the absorption of carbon dioxide into aqueous monoethanolamine (MEA) solutions and aqueous MDEA-MEA blends. The results of the model are compared with experimental data taken from the literature. Very satisfactory predictions of acidic gas vapor-liquid equilibrium over MDEA, MEA, and their blends at various concentrations, acidic gas loadings, and temperatures are obtained.

2006-01-01

68

Sc"4"5 NMR of scandium(3) salt aqueous solutions  

International Nuclear Information System (INIS)

Russian (Jul 1974). USSR Buslaev, Yu.A. Petrosyants, SP Tarasov,

69

Fluid Transport Phenomena in Ocular Epithelia  

UK PubMed Central (United Kingdom)

This article discusses three largely unrecognized aspects related to fluid movement in ocular tissues; namely, a) the dynamic changes in water permeability observed in corneal and conjunctival...Full Text Available

2008-03-01

70

Dynamics of multicomponent vesicles in a viscous fluid  

UK PubMed Central (United Kingdom)

We develop and investigate numerically a thermodynamically consistent model of two-dimensional multicomponent vesicles in an incompressible viscous fluid. The model is derived using an energy...Full Text Available

2010-01-01

71

On the calculation of the electrolyte aqueous solution freezing temperature  

International Nuclear Information System (INIS)

Analytical expression of the dependence of freezing temperature of electrolyte (CdCl_2, CdSO_4, BeSO_4) aqueous solutions on their composition was found. Three different methods were suggested were suggested for calculation of water activity in multicomponent solution. It was established that sublinear extrapolation of freezing temperature of salt aqueous solutions was possible not up to -5 deg C, but up to -15 deg C, independently of their composition. 6 refs.; 2 figs.

72

Mechanism of the heterophase of polyacrylonitrile in aqueous and aqueous-alcoholic solution  

Energy Technology Data Exchange (ETDEWEB)

The kinetics of the hydrolysis of polyacrylonitrile in aqueous and aqueousalcoholic solution have been studied. The effects of the solvent on the kinetics of the hydrolysis have been demonstrated, together with the role of diffusion and adsorption of the hydrolyzing agent on the surface of the macromolecules. It has also been shown to be possible to control the extent of hydrolysis and the hydrophilicity of the product.

1985-09-01

73

Chapter 11 Aqueous Solutions  

Wastenet

...Chapter 11 Aqueous Solutions Chapter 11 Aqueous Solutions Download the entire chapter (PDF-136k) Drilling to China More water than rivers Saving the aquifer Drying with Xeriscapes Everywhere in the house Rainwater and graywater Creating urban watersheds Wastewater equals ...3851 Powered by Intrcomm Technology's SMC ...

74

Geothermal energy in Italy and abroad; La geotermia in Italia e all'estero  

Energy Technology Data Exchange (ETDEWEB)

Geothermal systems and fields are analysed giving particular evidence to the value of the geothermal source as an important natural source of energy. The paper analyses hydrothermal systems and describes the international experimental studies on the use of geothermal reservoirs in hot rocks with geopressured and magmatic systems. Experts are optimistic as far as the use of this innovative source of energy is possible in the medium-short term. [Italian] Si analizzano i sistemi e i campi geotermici, sottolineando il valore della fonte geotermica come risorsa naturale ragguardevole d'energia. Vengono descritti i sistemi idrotermali e gli esperimenti condotti a livello internazionale sull'utilizzo di serbatoi geotermici in rocce calde con sistemi geopressurizzati e magmatici. L'ottimismo degli esperti sull'utilizzo di questa innovativa sorgente d'energia in tempi medio-brevi.

2001-04-01

75

Geological evolution of the center-southern portion of the Guyana shield based on the geochemical, geochronological and isotopic studies of paleoproterozoic granitoids from southeastern Roraima, Brazil; Evolucao geologica da porcao centro-sul do escudo das Guianas com base no estudo geoquimico, geocronologico e isotopico dos granitoides paleoproterozoicos do sudeste de Roraima, Brasil  

Energy Technology Data Exchange (ETDEWEB)

This study focuses the granitoids of center-southern portion of Guyana Shield, southeastern Roraima, Brazil. The region is characterized by two tectonic-stratigraphic domains, named as Central Guyana (GCD) and Uatuma-Anaua (UAD) and located probably in the limits of geochronological provinces (e.g. Ventuari-Tapajos or Tapajos-Parima, Central Amazonian and Maroni-Itacaiunas or Transamazon). The aim this doctoral thesis is to provide new petrological and lithostratigraphic constraints on the granitoid rocks and contribute to a better understanding of the origin and geo dynamic evolution of Guyana Shield. The GCD is only locally studied near to the UAD boundary, and new geological data and two single zircon Pb-evaporation ages in mylonitic biotite granodiorite (1.89 Ga) and foliated hastingsite-biotite granite (1.72 Ga) are presented. These ages of the protholiths contrast with the lithostratigraphic picture in the other areas of Cd (1.96-1.93 Ga). Regional mapping, petrography, ...

2006-07-01

76

Early cretaceous age of orthogneiss from the Charleston Metamorphic Group, New Zealand  

International Nuclear Information System (INIS)

Discordant U-Pb zircon isotopic data from amphibolite facies orthogneisses of the Charleston Metamorphic Group, western South Island, New Zealand, define a lower intercept age of 114#+-#18 m.y. that is interpreted as the crystallization age of the orthogneiss magmas. The upper intercept age of 1026#+-#97 m.y. reflects inherited components of Precambrian zircon derived from the source region of the magmas. The age, and whole rock chemical characteristics, indicate that the orthogneisses are part of the same phase of Early cretaceous magmatic activity that produced voluminous arc-related calc-alkaline plutonic rocks throughout western South Island. Previously published K-Ar and Rb-Sr mineral ages indicate uplift and cooling of the Charleston Metamorphic Group to less than 400deg C by 110-90 m.y. This uplift occurred as a consequence of low-angle normal faulting related to the Late Cretaceous breakup of Gondwana, and suggests that regional continental lithospheric ...

77

Uranium-lead zircon ages from the Median Tectonic Zone, New Zealand  

International Nuclear Information System (INIS)

The Median Tectonic Zone (MTZ) of New Zealand is a generally north trending belt of Mesozoic subduction related I-type plutonic, volcanic, and sedimentary rocks in South Island and Stewart Island that separates Permian strata of the Eastern Province Brook Street Terrane from lower to mid Gondwana margin assemblages of the Western Province. High precision isotope dilution U/Pb ages of zircons from 30 rocks are reported. Pre-digestion leaching of zircon in hydrofluoric acid yielded significantly more concordant residues by removing common Pb and dissolving more soluble high-U domains that have been more affected by relatively recent Pb loss. The results show that MTZ magmatism ranges in age from at least Early Triassic to Early Cretaceous (247-131 Ma), with a pronounced gap in the Middle Jurassic. Triassic plutons tend to occur on the eastern side of the MTZ, and they intrude volcanic/sedimentary sequences of the MTZ in Nelson and eastern Fiordland. These sequences ...

78

Cryo-irradiation as a terminal method for the sterilization of drug aqueous solutions  

British Library Electronic Table of Contents (United Kingdom)

The aim of this study is to evaluate the specificities of the irradiation of drugs in frozen aqueous solution. The structures of the degradation products were determined to gain insight into the radiolysis mechanisms occurring in frozen aqueous solutions. Metoclopramide hydrochloride and metoprolol tartrate were chosen as models. The frozen solutions were irradiated at dry ice temperature by high energy electrons at various doses. The drug purity (chemical potency) and the radiolysis products were quantified by HPLC-DAD. Characterization of the degradation products was performed by LC-APCI-MS-MS. The structures of the radiolysis products detected in irradiated frozen aqueous solutions were compared to those detected in solid-state and aqueous solutions (previous studies). For both metoclop...

2008-01-01

81

Techniques and tools for condition monitoring and life prediction of fluid power controls used in fuel handling systems of PHWRs  

International Nuclear Information System (INIS)

Various diagnostics techniques for condition monitoring and life prediction of fluid power components and system are discussed. Though some of the techniques are very promising but may not be accepted because of increase in the instrumentation, it is planned to implement these techniques on various circuits of Fluid Power Lab for further improving and developing these for direct implementation in various fluid power circuits of power reactors. (author). 6 figs.

84

Power transmitting fluids containing esters of hydrocarbyl succinic acid or anhydride with thio-bis-alkanols  

Energy Technology Data Exchange (ETDEWEB)

Mineral oil based power transmitting fluids, such as automatic transmission fluids, are disclosed which contain 0.05 to 2.0 weight percent of an ester of a thio-bis alkanol and a C/sub 12/-C/sub 50/ hydrocarbon succinic acid or anhydride, the ester being a multifunctional additive providing the properties of friction modification, corrosion inhibition, anti-wear, oxidation inhibition and extreme pressure properties to the fluids.

1987-10-27

90

Flow deflector for nuclear fuel element assemblies  

International Nuclear Information System (INIS)

... coolants departure nucleate boiling fluid flow fluidic control devices fuel

94

On the solid-fluid transition zone in welding analysis  

Energy Technology Data Exchange (ETDEWEB)

Equilibrium and energy equations have been developed in describing the solid-fluid transition zone during the melting and solidification of the binary alloys. Due to the existence of the transition region exhibited both solid and fluid phases at the same material point from continuum point of view, mixture theory was utilized to analyze the region. Unlike the Stefan problem, the latent heat due to the phase change appears as a source term in the heat equation. The molten fluid is treated as a thermoviscous and incompressible fluid, whereas the solid is thermoviscoplastic described by the Bodner-Partom/Walker type of constitutive equations. Thermal mechanical behaviors of the solid and the fluid phases are determined separately because of insignificant mechanical interactions between them. Volume fractions of the phases are obtained according to the equilibrium phase diagram. The ...

1993-01-01

95

Condensing curves for a number of mixed-hydrocarbon working fluids  

Energy Technology Data Exchange (ETDEWEB)

Condensing curves are presented for a number of two-component mixed hydrocarbon working fluids which are potentially usable in binary geothermal cycles. Performance of geothermal thermodynamic cycles incorporating these fluids has been evaluated under separate cover; two figures summarizing the results of those evaluations have been included here for continuity. The purpose of this report is: first, to document the condensing curves which were used in the mixed fluid cycle analyses, and second, to provide background useful in the preliminary evaluation of heat rejection systems for advanced geothermal electric power plants utilizing mixed hydrocarbon working fluids. Some concluding remarks are presented.

1981-07-01

96

Geologic and geomorphologic controls of the kaolin deposits of Campo Alegre basin (SC-Brazil); Controles geologicos e geomorfologicos dos depositos de caulim da Bacia de Campo Alegre, SC  

Energy Technology Data Exchange (ETDEWEB)

The most important kaolin deposits from Campo Alegre region (S C) were formed by the conjunction of at least one hydrothermal phase followed by many others weathering, supergenic, phases. Possibly deposits formed by only one of these processes exist, but these deposits shall be small and smaller than those mined today. Besides kaolinization, illitization/muscovitization and silicification, hydrothermalism also generated pyritized and propilitized zones, with quartz + chlorite. Together, hipogenic alterations related to kaolin deposits are very similar to alterations of high sulfidation epigenetic volcanogenic gold deposits. Most part of the biggest kaolin mines from the southern part of Campo Alegre Basin are distributed along a 13 Km long and 0,5 Km width bent zone that is parallel to structural alignments that point out the eastern Basin border. This zone was originated by deformation that has inclined and broken rocks, generating a fault system alongside and parallel to structural ...

2001-03-01

97

Mass transfer model for two-layer TBP oxidation reactions: Revision 1  

Energy Technology Data Exchange (ETDEWEB)

To prove that two-layer, TBP-nitric acid mixtures can be safely stored in the Canyon evaporators, it must be demonstrated that a runaway reaction between TBP and nitric acid will not occur. Previous bench-scale experiments showed that, at typical evaporator temperatures, this reaction is endothermic and therefore cannot run away, due to the loss of heat from evaporation of water in the organic layer. However, the reaction would be exothermic and could run away if the small amount of water in the organic layer evaporates before the nitric acid in this layer is consumed by the reaction. Provided that there is enough water in the aqueous layer, this would occur if the organic layer is sufficiently thick so that the rate of loss of water by evaporation exceeds the rate of replenishment due to mixing with the aqueous layer. Bubbles containing reaction products enhance the rate of transfer of water from the aqueous layer to the ...

1994-11-04

98

Field-controllable electro- and magneto-rheological fluid dampers in flow mode using Herschel-Bulkley theory  

Science.gov (United States)

The Bingham plastic constitutive model has been widely used to predict the post-yield behavior of electro- and magneto- rheological fluids (ER and MR fluids). However, if these fluids experience shear thinning or shear thickening, the Bingham plastic model may not be an accurate predictor of behavior, since the post-yield plastic viscosity is assumed to be constant. In a recent study, it was theoretically and experimentally demonstrated that the Herschel-Bulkley fluid model can be successfully employed when evaluating non- Newtonian post-yield behavior of ER and MR fluids. In this paper, the Herschel-Bulkley model is employed to include a detailed analysis of ER and MR fluid dynamics through pipes and parallel plates. Simplified explicit expressions for the exact formulation are also developed. It is shown that the proposed simplified model of the ...

2000-04-01

99

New crystallization of fatty acids from aqueous ethanol solution combined with liquid-liquid extraction  

Energy Technology Data Exchange (ETDEWEB)

A new separation process of saturated fatty acids (lauric acid-myristic acid) using crystallization from an aqueous ethanol solution has been examined. There were two vessels in this separation process: an extraction vessel and a crystallization vessel. The fatty acids in the aqueous phase were first extracted from their organic phase (melt) in the extraction vessel. The fatty acids in the aqueous phase were continuously introduced to the crystallization vessel, and then the fatty acids were crystallized there. The crystals of the fatty acids were collected continuously above the aqueous phase in the crystallization vessel. In this process, the yield and the purity of the crystals over time were measured, and it was found that the purity of lauric acid increased unsteadily up to 0.98 mole fraction of lauric acid with an increase in the yield of the low yield range. The mole fraction of ethanol in the ...

1999-06-01

100

Effect of pH on the phase separation in the ternary aqueous system containing the hydrophilic ionic liquid 1-butyl-3-methylimidazolium bromide and the kosmotropic salt potassium citrate at T=298.15K  

British Library Electronic Table of Contents (United Kingdom)

The goal of this work is to study the effect of the aqueous medium pH on the two-phase equilibrium behaviour of the aqueous {1-butyl-3-methylimidazolium bromide ([C4mim]Br)+potassium citrate} system in order to obtain further information about the salting-out effect produced by the addition of a kosmotropic salt to an aqueous solution of a hydrophilic ionic liquid (IL). For this purpose the phase diagrams and the liquid-liquid equilibrium (LLE) data of the {[C4mim]Br+potassium citrate} aqueous two-phase system (ATPS) were determined experimentally at different pH values. Four medium pH values (5.00, 6.00, 7.00 and 8.00) were assayed at T=298.15K. The effect of pH on the ATPS-promoting capability of citrate anions in the aqueous [C4mim]Br solutions was explained based on the structural hydr...

2011-01-01

101

Desorption of CO{sub 2} from MDEA and activated MDEA solutions  

Energy Technology Data Exchange (ETDEWEB)

A packed column was used for investigating the desorption rate of CO{sub 2} from aqueous methyldiethanolamine (MDEA) and activated MDEA solutions. Experiments were conducted within the temperature range 30--70 C, the concentration of MDEA was 4.28 kmol/m{sup 3}, and the concentration of piperazine (PZ) was 0.10 kmol/m{sup 3} for aqueous activated MDEA solutions. Experimental data confirmed that the kinetics model of absorption CO{sub 2} into aqueous MDEA and activated MDEA solutions can be applicable to the situations in which desorption occurs, and the desorption rate of model predictions agree well with that of experimental determination.

1995-03-01

102

A comparative study on the carbon dioxide capture power between 30 wt% 2-amino-2-methyl-1-propanol and 30 wt% methyldiethanol amine aqueous solutions  

Energy Technology Data Exchange (ETDEWEB)

A comparative study has been performed to compare the 30 wt% of 2-amino-2-methyl-1-propanol (AMP) aqueous solution and 30 wt% of methyldiethanol amine (MDEA) aqueous solution to capture carbon dioxide contained in the flue gas stream. The equilibrium constants for each electrolyte reactions have been used to estimate the carbon dioxide absorption process. Henry's constants for each binary pairs between solute gases and solvent have been used to estimate solubility of the gas components.

2009-05-15

103

The inertial dynamics of thin film flow of non-Newtonian fluids  

CERN Document Server

Consider the flow of a thin layer of non-Newtonian fluid over a solid surface. I model the case of a viscosity that depends nonlinearly on the shear-rate; power law fluids are an important example, but the analysis here is for general nonlinear dependence. The modelling allows for large changes in film thickness provided the changes occur over a large enough lateral length scale. Modifying the surface boundary condition for tangential stress forms an accessible base for the analysis where flow with constant shear is a neutral critical mode, in addition to a mode representing conservation of fluid. Perturbatively removing the modification then constructs a model for the coupled dynamics of the fluid depth and the lateral momentum. For example, the results model the dynamics of gravity currents of non-Newtonian fluids even when the flow is not very slow.

2007-01-01

104

Relating Complex Fluid Composition and Thermophysical Properties with the Advanced Distillation Curve Approach  

British Library Electronic Table of Contents (United Kingdom)

Complex fluids have long posed a significant challenge in our ability to characterize and model fluid properties. Here, we consider complex fluids to be mixtures with many components that can differ significantly in polarity and polarizability. The penultimate complex fluid is crude oil, although many other fluids such as finished fuels are also highly complex. We have recently introduced a measurement strategy that can simplify these efforts and provides the added potential of linking chemical composition (i.e. analytical) information with physical property information. In addition to chemical characterization, the approach provides the ability to calculate thermodynamic and transport properties for such complex heterogeneous streams. The technique is based on the advanced distillation cu...

2010-01-01

105

On the anatomy of the adsorption heat versus loading as a function of temperature and adsorbate for a graphitic surface  

British Library Electronic Table of Contents (United Kingdom)

In this paper we review and classify the various patterns of isosteric heat versus loading for adsorption of gases on graphitised thermal carbon black at temperatures ranging from below the 3D triple point to temperatures above it, but less than the 3D critical point. We have identified the features of heat curve and highlighted the microscopic origin of these features. The patterns vary with temperature and with the relative strength of the fluid-fluid interaction and solid-fluid interaction. For simple adsorptives (by simple we meant there is no strong association between fluid particles), the heat curve is typified by fluid-fluid attraction and layering phenomena. For adsorptives showing strong association such as water, ammonia and methanol, the heat curve essentially begins below the ...

2008-01-01

106

The effect of aqueous composition on diffusion coefficient in bentonite  

International Nuclear Information System (INIS)

The diffusion coefficients (De) in bentonite were measured to understand and quantify the influence of groundwater chemistry such as ionic strength and to quantify the alteration of smectite mineralogical transformations. (author)

2009-12-01

107

Small Regulatory RNA and Legionella pneumophila  

UK PubMed Central (United Kingdom)

Legionella pneumophila is a gram-negative bacterial species that is ubiquitous in almost any aqueous environment. It is the agent of Legionnaires’ disease, an acute and often...Full Text Available

108

Radiosterilization of drugs in aqueous solutions may be achieved by the use of radioprotective excipients  

British Library Electronic Table of Contents (United Kingdom)

The aim of this study was to assess the feasibility of radiosterilization of drugs aqueous solutions and to evaluate the effects of some additives, such as mannitol, nicotinamide and pyridoxine, which might protect the drug from degradation. Metoclopramide was selected as a model drug. The structures of the degradation products were determined to gain insight on the radiolysis mechanisms in aqueous solution in order to design strategies to lower the drug degradation.Metoclopramide hydrochloride aqueous solutions with and without excipients were irradiated either with gamma rays or high-energy electrons. HPLC-DAD was used to measure the loss of chemical potency and to quantify the degradation products which were also characterized by LC-APCI-MS-MS. Metoclopramide recovery for gamma and elec...

2008-01-01

109

Production of tetrazolium salts under conditions of phase-transfer catalysis  

Energy Technology Data Exchange (ETDEWEB)

Recently the authors showed that tetrazolium salts can be obtained during the oxidation of substituted 1,3,5-triarylformazans with potassium permanganate in a two-phase organic solvent-water system. The role of phase-transfer catalyst in this reaction is played by the tetrazolium salt, which is formed in a small amount as the result of oxidation of the formazan at the phase boundary. The method is distinguished by its extreme simplicity. However, the yield of the tetrazolium salts fluctuates within wide limits and does not exceed 62%. This is due to the fact that as the reaction proceeds the pH of the aqueous phase increases from 6 to 12. At the same time it is known that tetrazolium salts are unstable in aqueous alkaline solutions. They found that if the aqueous phase is replaced by aqueous hydrochloric acid (5 wt. %) the yields of the tetrazolium salts (Ia-g) are increased to 70-87%. For convenience ...

1988-06-20

111

/sup 109/Ag NMR spectra of aqueous silver ions coordinated with nitroxide radical. Silver-TANOL complex and TANOL as a doping agent  

Energy Technology Data Exchange (ETDEWEB)

The effects of TANOL radical have been examined on chemical shifts and relaxation rates of /sup 109/Ag NMR in aqueous solution of silver salts. The silver ion in aqueous solution is found to coordinate with TANOL radical. A small amount of TANOL is added as a doping agent(0.020M), since /sup 109/Ag signals are obtained for (1.0M) silver ion within 30 minutes. The /sup 109/Ag chemical shifts of silver salt in aqueous solutions were found within the range of 0 to -1000 ppm relative to that of 1.0M AgNo/sub 3/.

1982-09-01

112

The Bidimensional Stefan Problem with Convection: The Time-Dependent Case.  

Science.gov (United States)

This paper considers the time dependent Stefan problem with convection in the fluid phase governed by the Stokes equation, and with adherence of the fluid on the lateral boundaries. The existence of a weak solution is obtained via the introduction of a te...

1982-01-01

113

Mid-trimester diagnosis of bladder neck obstruction by ultrasound and paracentesis.  

UK PubMed Central (United Kingdom)

A bladder neck obstruction was suspected after ultrasound investigation at 16 weeks' gestation. Evaluation of protein content in the amniotic fluid, fetal ascites, and fluid from the overdistended bladder...Full Text Available

1983-06-01

114

Magnetic resonance imaging and computational fluid dynamics (CFD) simulations of rabbit nasal airflows for the development of hybrid CFD/PBPK models  

UK PubMed Central (United Kingdom)

The percentages of total airflows over the nasal respiratory and olfactory epithelium of female rabbits were calculated from computational fluid dynamics (CFD) simulations of steady-state inhalation....Full Text Available

2009-05-01

115

Intrauterine tracheal obstruction, a new treatment for congenital diaphragmatic hernia, decreases amniotic fluid sodium and chloride concentrations in the fetal lamb.  

UK PubMed Central (United Kingdom)

OBJECTIVE: To evaluate the effect of fetal tracheal occlusion on sodium and chloride concentrations in amniotic and tracheal fluid. SUMMARY BACKGROUND DATA: Intrauterine tracheal occlusion has been...Full Text Available

1997-12-01

116

Improvements in or relating to fluid operated devices for moving articles  

International Nuclear Information System (INIS)

The patent relates to fluid operated devices for moving articles. The machine may be used in filling a nuclear fuel canister with fuel pellets where there is a tendency for out of squareness of pellets to produce a jam condition readily cleared by a modest force. (U.K.).

1984-09-27

117

Hydrodynamics in an external field  

CERN Document Server

The methods of statistical dynamics are applied to a fluid with 5 conserved fields (the mass, the energy, and the three components of momentum) moving in a given external potential. When the potential is zero, we recover a previously derived system of parabolic differential equations, called "corrections to fluid dynamics".

2002-01-01

118

Hydrodynamic thickening of lubricating fluid layer beneath sliding mesothelial tissues  

UK PubMed Central (United Kingdom)

The delicate mesothelial surfaces of the pleural space and other serosal cavities slide relative to each, lubricated by pleural fluid. In the absence of breathing motion, differences between...Full Text Available

2008-01-01

119

Gingival crevicular fluid levels of clindamycin compared with its minimal inhibitory concentrations for periodontal bacteria.  

UK PubMed Central (United Kingdom)

Clindamycin concentrations in gingival crevicular fluid and in blood were determined over a 7-h period and were related to the minimal inhibitory concentrations of this agent for 340 bacterial strains...Full Text Available

1981-05-01

120

Density separation of materials by using magnetic fluids  

Energy Technology Data Exchange (ETDEWEB)

The magnetic fluid is a colloidal suspension of magnetite in kerosene, prepared by a low-cost process. Separation is accomplished in an open trough filled with magnetic fluid. A magnetic field is established in the fluid, by energizing an electromagnet having poles on each side of the trough. Due to the design of the magnet poles and air gaps, the magnetic field is strongest at the bottom, about 10,000 oersteds, and uniformly decreases in strength to about 2000 oersteds at the top of the fluid. Therefore, the magnetic field gradient increases with depth. The magnetic force attracts the entire separation medium (magnetic fluid) creating a reaction force of equal magnitude and acting in the opposite direction. This reaction created within a magnetic fluid/magnetic field combination is called a magnetic levitation force. It increases with the field strength. In ...

1980-03-01

121

Computer Simulation of Geothermal Reservoirs.  

Science.gov (United States)

General balance laws and constitutive relations are developed for convective hydrothermal geothermal reservoirs. A fully interacting rock-fluid system is considered; typical rock-fluid interactions involve momentum and energy transfer, and the dependence ...

1975-01-01

122

Changes in Gingival Crevicular Fluid Inflammatory Mediator Levels during the Induction and Resolution of Experimental Gingivitis in Humans  

UK PubMed Central (United Kingdom)

AimThe goal of this study is to characterize the changes in 33 biomarkers within the gingival crevicular fluid during the 3-week induction and 4-week resolution of...Full Text Available

2010-04-01

123

Cerebrospinal Fluid Steroidomics: Are Bioactive Bile Acids Present in Brain?*  

UK PubMed Central (United Kingdom)

In this study we have profiled the free sterol content of cerebrospinal fluid by a combination of charge tagging and liquid chromatography-tandem mass spectrometry. Surprisingly, the most abundant cholesterol...Full Text Available

2010-02-12

124

Centrifugal potential energy : an astounding renewable energy concept  

Energy Technology Data Exchange (ETDEWEB)

A new energy concept known as centrifugal potential energy was discussed. This new energy concept is capable of increasing the pressure, temperature and enthalpy of a fluid, without having to apply work or heat transfer to the fluid. It occurs through a change in the centrifugal potential energy of the flowing fluid in a rotating frame of reference or a centrifugal force field, where work is performed internally by the centrifugal weight of the fluid. This energy concept has resulted in new energy equations, such as the Rotational Frame Bernoulli's Equation for liquids and the Rotational Frame Steady-Flow Energy Equation for gases. Applications of these equations have been incorporated into the design of centrifugal field pumps and compressors. Rather than compressing a fluid with a physical load transfer, these devices can compress a fluid via the ...

2010-07-01

125

Appearance of beta-endorphin-like immunoreactivity in human ventricular cerebrospinal fluid upon analgesic electrical stimulation.  

UK PubMed Central (United Kingdom)

beta-Endorphin-like immunoreactivity in human ventricular cerebrospinal fluid was measured with a specific radioimmunoassay. The subjects were undergoing a surgical procedure for relief of chronic intractable...Full Text Available

1978-10-01

126

An evaluation of cerebrospinal fluid oligoclonal banding confirmed by immunofixation on agarose gel.  

UK PubMed Central (United Kingdom)

The cerebrospinal fluid (CSF) from 115 consecutive patients undergoing diagnostic lumbar puncture or myelography was examined to determine the usefulness of immunofixation, following agarose gel electrophoresis,...Full Text Available

1983-06-01

127

A novel enzyme-based acidizing system: Matrix acidizing and drilling fluid damage removal  

Energy Technology Data Exchange (ETDEWEB)

A novel acidizing process is used to increase the permeability of carbonate rock cores in the laboratory and to remove drilling fluid damage from cores and wafers. Field results show the benefits of the technology as applied both to injector and producer wells.

1995-12-31

128

Two-fluid spray atomisation and pneumatic nozzles for fluid bed coating/agglomeration purposes: A review  

DEFF Research Database (Denmark)

In fluid bed processing in the chemical, food or pharmaceutical industries, pneumatic nozzles are typically used to convert binder or coating liquids into droplets. Producing fine droplets from liquids in a gas phase is termed atomisation, and it involves complex phenomena which are not yet fully understood. This paper provides a systematic and up-to-date review of two-fluid nozzle designs and principles together with a presentation of nozzle fundamentals introducing basic nozzle theory and thermodynamics. Correlations for the prediction of mean droplet diameters are reviewed, compared and accompanied by a discussion of their use.

2008-01-01

129

Origins of acid fluids in geothermal reservoirs  

International Nuclear Information System (INIS)

Acid fluids in geothermal reservoirs are rare. Their occurrence in geothermal systems associated with recent volcanism (Tatun Sumikawa, Miravalles) probably indicates that the geotherml reservoir fluid was derived from volcanic fluid incompletely neutralized by reaction with feldspars and micas. Superheated steam containing HCl (Larderello, The Geysers) forms acid where it condenses or mixes with liquid at moderate temperatures (325 deg. C). Cryptoacidity occurs at Los Humeros where HCl acidity is formed and neutralized without reaching the surface. (author). 28 refs, 9 figs, 2 tabs.

1992-03-01

130

Orbital storage and supply of subcritical liquid nitrogen  

Science.gov (United States)

Subcritical cryogenic fluid management has long been recognized as an enabling technology for key

1990-01-01

131

Modeling Cavitation in Cryogenic Fluids: Validation for Liquid Nitrogen, Hydrogen, and Oxygen  

Science.gov (United States)

This viewgraph presentation provides an overview of research designed to provide a numerical

2003-01-01

132

Low temperature solar-to-electric power conversion system  

Science.gov (United States)

An electric power generating apparatus is described, including: a solar collector; a primary thermal loop including primary thermal fluid; a cavity receiver to receive reflected solar energy from the solar reflector, convert the solar energy into thermal energy, and transmit the thermal energy to the primary thermal fluid by heating the primary thermal fluid not to exceed a given temperature, the given temperature being substantially equal to 700 F; a Stirling engine receiving the primary thermal fluid heated by the cavity receiver, including means to generate mechanical power and means to generate electrical power from the means to generate mechanical power.

1993-07-20

133

JPRS Report, Science & Technology, China, High-Power ...  

Science.gov (United States)

... KDP crystal. ... The KDP crystal has a high nonlinear the degree of matching between the fluid and the window coefficient. ...

1991-10-18

134

Intensifying bactericidal effect of biocides in cutting fluids  

Energy Technology Data Exchange (ETDEWEB)

A study is presented of the influence of ethylenediamine-tetraacetic acid (EDTAA) on the antimicrobial properties of a number of bactericidal additives for cutting fluids. During the testing both the microbiological and primary physical-chemical properties of the cutting fluids were determined. The duration of protective action of the additives vazin, vazin FD, formacide-13, kamcide-5 and furacylin was determined with and without EDTAA in Ukrinol-1 cutting fluid. Though EDTAA itself did not show great duration of antibacterial effect, when combined with the other additives it lengthened their time of protection by a factor of 2.2 to 2.7. 10 references.

1983-06-01

135

Heating of magneto-rheological fluid dampers: a theoretical study  

Science.gov (United States)

This paper focuses on a theoretical model that predicts the temperature increase of Magneto-rheological (MR) fluid dampers experiencing a sinusoidal input motion. A theoretical model is developed to estimate the temperature rise based on the non-linear behavior of the MR fluid damper. This model is solved numerically, and the numerical solution is compared with a known linear solution and experimental result in order to validate the accuracy of the model. Also, a non-dimensional form of the governing equations are developed to examine the key parameters. The non-dimensional terms show the effect of external and internal parameters on the trends of heat dissipation as well as heat generation within the MR fluid damper.

1999-05-01

136

Fluidic-controlled automatic rabbit system  

International Nuclear Information System (INIS)

... v. 15(10) p. 445-449. automation control equipment fluid flow fluidic control

137

Fluidic shut-down system for a nuclear reactor  

International Nuclear Information System (INIS)

... fluid poison control fluidic control devices reactors scram scram rods control

139

Flow Control  

Science.gov (United States)

... 65th AGARD Fluid Dynamics Symposium, Madrid, Spain, October ... of research programs on flow control ... separation, and delta wing flows formed the ...

1991-04-30

140

Feynman-Wiener path integral representation for scalar advected diffusion  

Energy Technology Data Exchange (ETDEWEB)

We write a path-integral expression for the Green function of a advected scalar on a fluid flux. (author)

2000-07-01

141

Evaluation of the fluid force in main feed water control valve for APWRs  

International Nuclear Information System (INIS)

... 2432 v. 43(1) SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS

2006-01-01

142

Computer simulation of interface potentials: Towards a first principle description of complex interfaces?  

British Library Electronic Table of Contents (United Kingdom)

We discuss the feasibility of a hierarchical protocol whereby the description and prediction of adsorbed fluids in confined systems at the mesoscopic scale is achieved by use of interface potentials that are obtained from raw molecular simulation data. Starting from a microscopic description of a fluid?s interface on a flat substrate, we attempt to extract the minimum information that is required in order to predict the behavior of that fluid at larger length scales from coarse grained surface Hamiltonians. A critical assessment of this procedure hinges on controversial aspects of wetting behavior and more generally on the meaning of metastability and instability of thermodynamic systems.

2011-01-01

143

Well preflush fluid  

Energy Technology Data Exchange (ETDEWEB)

This patent describes a preflush fluid for preventing lost circulation during the cementing of a well, the fluid consisting essentially of: (a) water; (b) about 10 to about 30 percent by weight of water (% BWOW) cement; (c) about 5 to about 30% BWOW calcium sulfate selected from the group consisting of calcium sulfate hemihydrate, calcium sulfate dihydrate, and mixtures thereof; and (d) an alkali metal-containing quick-hardening accelerator.

1992-01-21

144

Sloshing of fluid in horizontal steam generator generated by horizontal and vertical seismic motions  

International Nuclear Information System (INIS)

The nuclear power plants with WWER type reactors are characterized by horizontally situated steam generators (SG). During seismic event the horizontal and vertical ground accelerations induce fluid motion in directions of longitudinal and transversal axis. Resulting dynamic forces act on the SG attachment and could cause the failure of screws. In obvious PSA scenarios, these phenomena are classified as a indirect induced LOCA. In this paper the effects of transversal sloshing of fluid are analyzed.

1989-08-14

145

Self-filling and self-purging apparatus for detecting spontaneous radiation from substances in fluids  

Energy Technology Data Exchange (ETDEWEB)

Disclosed herein is a radiation detector providing for the in situ automatic sampling of fluids containing substances emitting radiation, especially Cerenkov radiation. The detector permits sampling within well casings and is self-purging such that no additional provisions must be established for the storage and disposal of contaminated fluids.

1993-01-01

146

Radionuclide demonstration of ventriculoatrial shunt-cutaneous fistula with cerebrospinal fluid leak  

International Nuclear Information System (INIS)

Radionuclide techniques have commonly been used to assess ventriculovenous shunt function, cerebrospinal fluid dynamics, and for the diagnosis of cerebrospinal fluid leaks. All of these techniques were utilized in this unusual case of retrograde migration of a ventriculoatrial catheter into the neck, with cutaneous fistulization and CSF leak. (orig.).

147

Leak location in fluid filled cables using the PFT method  

Energy Technology Data Exchange (ETDEWEB)

A new method of pinpointing dielectric fluid leaks on pipe-type and self-contained cables using perfluorocarbon tracer (PFT) is presented. The method has successfully been used on the Con Edison transmission system to locate leaks of dielectric fluid on both types of cables. Application of the PFT technique does not require feeder deenergization and provides major advantages over the conventional method of freeze and pressure testing. Description of the method and results of field application are presented in the paper.

1999-01-01

148

CT-guided percutaneous aspiration and drainage of postoperative abdominal fluid collections  

International Nuclear Information System (INIS)

The authors report the personal techniques and the results of CT-guided percutaneous drainage of postoperative abdominal fluid collections. CT-guided percutaneous drainage offers many advantages over surgery: it is less invasive, can be repeated and requires no anesthesia, there are not surgery-related risks and lower morbidity and mortality rates. Moreover, subsequent hospitalization is shorter and costs are consequently reduced. The authors conclude that CT-guided percutaneous drainage is the method of choice in the treatment of postoperative abdominal fluid collections.

1999-03-01

149

Peculiarity of counterion - polyion interactions in aqueous solutions of copolymers of acrylamide with cadmium acrylate  

Energy Technology Data Exchange (ETDEWEB)

Binding of Cd/sup 2 +/ ions in aqueous solutions of statistical copolymers of acrylamide with cadmium acrylate with different content of ionogenic groups in copolymers was investigated by polarography, conductometry, viscometry and dialysis. It is shown that the degree of binding of Cd/sup 2 +/ ions increases with increasing of the content of ionogenic groups in the copolymer and with decreasing of ionic strength of the solution. The values of the degree of binding of Cd/sup 2 +/ ions obtained by polarography and dialysis show satisfactory agreement.

1984-02-01

150

Non-aqueous electrode research. Interim technical report, 1 October 1978-25 October 1979  

Energy Technology Data Exchange (ETDEWEB)

This report describes work carried out in the second 13 months of a 33 month contract to characterize the passive films formed on anodes commonly used in non-aqueous battery cells, and to identify cell reaction products formed at the carbon cathode commonly used in these cells.

1980-03-01

151

Molar extinction coefficients in aqueous solutions of some alkaline earth chlorides  

International Nuclear Information System (INIS)

Molar extinction coefficients for the solid solutes in aqueous solutions of some alkaline earth chlorides such as MgCl_2.6H_2O, CaCl_2, SrCl_2.6H_2O and BaCl_2.2H_2O have been determined at 81, 356, 511, 662, 1173 and 1332 keV energies in different concentration using the narrow beam transmission methods. (author)

1999-12-21

152

LC-MS analysis in the e-beam and gamma radiolysis of metoprolol tartrate in aqueous solution: Structure elucidation and formation mechanism of radiolytic products  

British Library Electronic Table of Contents (United Kingdom)

E-beam and gamma products from the radiolysis of aqueous solutions of (+-)-metoprolol tartrate, saturated in nitrogen, are analyzed by HPLC with on-line mass and UV detectors. The structures of 10 radiolytic products common to e-beam and gamma irradiations are elucidated by comparing their fragmentation pattern to that of (+-)-metoprolol. Two of the radiolytic products are also metabolites. Different routes for the formation of the radiolytic products are proposed.

2006-01-01

153

Flue gas desulfurization/denitrification using metal-chelate additives  

Science.gov (United States)

A method of simultaneously removing SO.sub.2 and NO from oxygen-containing flue gases resulting from the combustion of carbonaceous material by contacting the flue gas with an aqueous scrubber solution containing an aqueous sulfur dioxide sorbent and an active metal chelating agent which promotes a reaction between dissolved SO.sub.2 and dissolved NO to form hydroxylamine N-sulfonates. The hydroxylamine sulfonates are then separated from the scrubber solution which is recycled.

1986-01-01

154

Estimation of the mean distance of closest approach of some heavy metal ions in aqueous solutions: some experimental and theoretical calculations  

British Library Electronic Table of Contents (United Kingdom)

The estimation of numerical values of the mean distance of closest approach of ions, a, of heavy metal ion salts in aqueous solutions, determined from activity coefficients, as well as from different theoretical approaches, is presented and discussed.

2011-01-01

155

Design of absorption columns in the presence of surfactants  

Energy Technology Data Exchange (ETDEWEB)

An equation is described to estimate the value of the liquid-phase mass-transfer coefficient of aqueous solutions of surfactants from its value for pure water. The form of the equation is obtained from Levich's theory, and it is adjusted to experiments of absorption of CO/sub 2/ in aqueous solutions of five pure surfactants. The reduction of the absorption rate is correlated with the interfacial pressure of the solution.

1986-01-01

156

DEFINITIVE SOX CONTROL PROCESS EVALUATIONS: AQUEOUS CARBONATE AND WELLMAN-LORD (ACID, ALLIED CHEMICAL, AND RESOX) FGD (FLUE GAS DESULFURIZATION) TECHNOLOGIES  

Science.gov (United States)

The report gives results of economic evaluations of two processes: the Rockwell International aqueous carbonate process (ACP) and the Wellman-Lord process, the latter applied to a sulfuric acid plant, the Foster Wheeler Resox process, and the Allied Chemical coal reduction proces...

157

Corrosion resistance of zinc coatings on depleted uranium and uranium alloys  

Energy Technology Data Exchange (ETDEWEB)

Simulated atmospheric corrosion studies were performed to determine the corrosion protection provided by galvanized zinc coatings on depleted uranium, U-0.75 Ti alloy, and U-6 Nb alloys. The accelerated ASTM tests consisted of exposing the galvanized samples to aqueous and aqueous chloride environments. The test results showed that anodic protection was provided by the electronegative zinc coatings on uranium and uranium alloys. Treating zinc with chromate conversion coatings also provided more protection.

1985-01-27

158

Aqueous liquid scintillation counting with fluor-containing nanosuspensions  

Energy Technology Data Exchange (ETDEWEB)

A microemulsion comprised of water, Brij 78, pentanol and styrene into which PPO and bis-MSB had been dissolved was prepared. Polymerization of the styrene resulted in a suspension of fluor-containing polystyrene nanoparticles (<100 nm). After a concentration step, the aqueous nanosuspension was able to detect {sup 14}C with counting efficiencies over 50% of those of a commercially available scintillation cocktail. Monte Carlo calculations demonstrated that the size and concentration of the nanoparticles were appropriate for optimum detection efficiency.

2004-06-01

159

Adsorption of di-2-ethylhexylphosphoric acid from toluene the interface with inorganic salt aqueous solutions  

International Nuclear Information System (INIS)

Interfacial tension in the system toluene solution of di-2-ethylhexylphosphoric acid HDEHP-aqueous solutions of inorganic salts has been measured by the drop volume method. The ion-exchange constants in the monolayers formed by HDEHP and alkaline-earth metals have been measured.

160

A method for making a drilling mud  

Energy Technology Data Exchange (ETDEWEB)

A method is proposed for making a drilling mud, which includes mixing of an aqueous solution of a water soluble acrylic polymer with clay. It is distinguished by the fact that in order to reduce the corrosion activity of the clay solution, the dry clay is slaked in an aqueous solution of partially hydrolized polyacrylonitrile with the following component relationship (in percent by mass): clay, 3 to 10; hydrolized polyacrylonitrile, 3 to 5 and water, the remainder.

1983-01-01

161

Enthalpy changes upon partial evaporation of aqueous solutions containing ammonia and carbon dioxide  

Energy Technology Data Exchange (ETDEWEB)

The thermodynamic properties of aqueous solutions containing ammonia and sour gases such as carbon dioxide, sulfur dioxide, or hydrogen sulfide must be known in many applications. A typical example is the cleaning of raw gases in power stations. The enthalpy changes upon partial evaporation of aqueous solutions containing ammonia and of aqueous solutions containing ammonia and carbon dioxide were measured at temperatures from 313 to 393 K with a thin film evaporator flow calorimeter. The molalities of ammonia and carbon dioxide entering the calorimeter ranged up to 12 and 6 mol/kg, respectively. The physicochemical model originally developed by Edwards et al. (1978) and further modified and extended by Kurz et al. (1995) to describe phase equilibria in aqueous systems containing ammonia and carbon dioxide is used to derive a predictive enthalpy model for this complex, chemical reactive system. ...

1998-08-01

162

The onset of convection in a couple stress fluid saturated porous layer using a thermal non-equilibrium model  

International Nuclear Information System (INIS)

The stability of a couple stress fluid saturated horizontal porous layer heated from below and cooled from above when the fluid and solid phases are not in local thermal equilibrium is investigated. The Darcy model is used for the momentum equation and a two-field model is used for energy equation each representing the solid and fluid phases separately. The linear stability theory is employed to obtain the condition for the onset of convection. The effect of thermal non-equilibrium on the onset of convection is discussed. It is shown that the results of the thermal non-equilibrium Darcy model for the Newtonian fluid case can be recovered in the limit as couple stress parameter C?0. We also present asymptotic analysis for both small and large values of the inter phase heat transfer coefficient H. We found an excellent agreement between the exact solutions and asymptotic solutions when H is very small.

2009-02-16

163

Solar energy conversion system  

Energy Technology Data Exchange (ETDEWEB)

A solar energy collection and conversion system is disclosed in which a cassegrain mirror system is rotated about a diurnal axis, which axis is adjusted for seasonal variations in the incidence of the sun's rays on the earth's surface. A black body absorption cavity filled with translucent or transparent fluid material is used for direct absorption of the sun's rays. The incident solar energy is absorbed directly by the fluid medium. The fluid within the cavity may be maintained under extremely high pressures and temperatures in order to utilize this fluid as a heat storage medium. Such heat storage is facilitated by apparatus which permits a change in the volume of the reflective cavity in response to the temperature or pressure of the fluid within the cavity.

1981-09-01

164

Numerical and experimental investigation of shellside characteristics for RODbaffle heat exchanger  

Energy Technology Data Exchange (ETDEWEB)

RODbaffle heat exchanger is a kind of shell-and-tube heat exchanger with eminent performance. Because of the characteristics of tube bundle support structure, fluid flow on shellside is longitudinal and periodical, and fluid flow is of symmetry in landscape orientation. According to the fluid flow characteristics on shellside and ignoring the impact of inlet, outlet and shell wall, a periodic flow unit duct was taken as the simplified model of the shellside to perform numerical simulation by using CFD code, FLUENT. It was found that the both errors in magnitude of the main fluid velocities and heat transfer coefficients between results of simulation and that of experiment or correlations are less than 10%, and the errors of pressure drop between simulation and correlation are no more than 20%. The detailed characteristics and relation of fluid flow and heat transfer on shellside of ...

2008-05-15

165

Control rod drives  

International Nuclear Information System (INIS)

Purpose: To secure the reactor operation safety by the provision of a fluid pressure detecting section for control rod driving fluid and a control rod interlock at the midway of the flow pass for supplying driving fluid to the control rod drives. Constitution: Between a driving line and a direction control valve are provided a pressure detecting portion, an alarm generating device, and a control rod inhibition interlock. The driving fluid from a driving fluid source is discharged by way of a pump and a manual valve into the reactor in which the control rods and reactor fuels are contained. In addition, when the direction control valve is switched and the control rods are inserted and extracted by the control rod drives, the pressure in the driving line is always detected by the pressure detection section, whereby if abnormal pressure is resulted, the alarm generating device is ...

166

Approximate method for the determination of the response frequency of pipe whip. [With fluid flowing in the pipe at different velocities  

Energy Technology Data Exchange (ETDEWEB)

An approximate analysis based on the virtual work technique, which was used to determine the effect of fluid velocity on the response frequency of a simply supported pipe, resulted in the following conclusions: (1) the critical fluid velocity at which the system becomes statically unstable is 129.5 ft/s; (2) the natural frequency of the pipe decreases as the fluid velocity increases; (3) higher flow rates increase the dynamic coupling of the system, making it much more susceptible to external excitation; (4) as the critical frequency approaches zero and the fluid velocity approaches the critical value, the amplitude becomes greater (though in an actual pipe, damping effects will limit the amplitude somewhat); and (5) the virtual work technique is a convenient method for approximating solutions to most non-linear vibration problems, giving results that are satisfactory for engineering-design purposes.

1980-05-01

167

Application of multi-fluid model in dryout prediction  

International Nuclear Information System (INIS)

Dryout predictions using a multi-flood model for the annular two-phase flow regime are compared against dryout data obtained for BWR condition. The multifluid model treats two-phase flow as composed of distinct fluid regions (fluids) and individual conservation equations are applied to each fluid. Dryout is assumed to occur when flow rate of one of the liquid films becomes zero. The factor is extended to cover dryout data for very short boiling lengths. The present study involves wide ranges in geometries, heat flux distributions, and fluid concentrations. The accuracy of dryout power prediction is found to be as good as that of empirical correlations. It is confirmed that within a single analytical framework, the model can handle various classes of dryout analyses whereas the existing equilibrium models cannot.

1983-01-01

168

Thermal and tectonic history of the Ordos Basin, China: Evidence from apatite fission track analysis, vitrinite reflectance, and K-Ar dating  

Energy Technology Data Exchange (ETDEWEB)

Apatite fission track analysis, vitrinite reflectance data, and K-Ar dating of Permian-Carboniferous and Mesozoic core samples have been successfully integrated to reconstruct the thermal and tectonic history of the Ordos basin, China. Apatite fission track ages of Carboniferous-Jurassic sedimentary rocks range between 3 and 137 Ma, and are significantly younger than the stratigraphic ages. Confined fission track lengths demonstrate exclusively mixed length distribution, indicating complex thermal history. The data suggest that the samples must have all experienced higher paleotemperatures in the past. Mean virtinite reflectance values (R{sub o}) of the Triassic rocks range from 0.61 to 1.06%, giving a high coalification gradient of 0.36%/km and suggesting a high paleothermal gradient of 57{degrees}C/km. Permian-Carboniferous rocks have R{sub o} values on the order of 1.0-3.0%, and locally up to 4.0-6.0%. Some high R{sub o} values coincide with positive gravity and magnetic anomalies. ...

1996-07-01

169

Granitoid formation is ineffective in isotopically homogenizing continental crust: Evidence from archean rocks of the Wind River Mountains, Wyoming  

Energy Technology Data Exchange (ETDEWEB)

The Archean core of the Laramide Wind River uplift records evidence of at least three major granitoid-forming episodes. The oldest, the Dry Creek gneiss (DCG), was emplaced by 2.8 Ga and occupies the northeastern part of the range. Mafic, pelitic and ultramafic inclusions occur in the DCG. Elsewhere in the Wind River Mountains there is evidence for crustal components as old as 3.8 Ga. The Bridger batholith (BB), intruded at 2.67 Ga, is found in the west-central Wind River Mountains. The Wind River batholith (WRB) refers to the youngest Late Archean granodiorites and granites which are found throughout the range and includes granitoids previously name the Louis Lake, Bears Ears, Popo Agie, and Middle Mountain intrusions. Although granitoids of the Wind River batholith have been dated at 2.63 and 2.55 Ga, they are considered together here because there is a complete gradation in rock type and because definite intrusive contacts are scarce. The DCG, BB, and WRB each span the ...

1992-01-01

170

Geochemistry of basalts from the Dumisseau formation, southern Haiti: Implications for the origin of the Caribbean Sea crust  

Energy Technology Data Exchange (ETDEWEB)

Basalt and diabase from the Cretaceous Dumisseau Formation, southern Haiti have Mg-numbers of 43-63, TiO/sub 2/ contents of 1.6-3.9% and La abundances of 3.6-15.3 ppm. LaTa ratios average 10, and indicate that the basalts are oceanic in character, distinct from the arc associations forming the northern part of Haiti. Oldest lavas have low TiO/sub 2/, (1.6%) and are LREE-depleted, similar to N-MORBs, whereas overlying lavas have higher TiO/sub 2/ (2-3.9%) and are LREE-enriched, similar to E-MORBs or hotspot basalts. /sup 87/Sr/sup 86/Sr ratios vary from 0.70280 to 0.70316, /sup 143/Nd/sup 144/Nd from 0.512929 to 0.513121, and /sup 206/Pb/sup 204/Pb from 19.00 to 19.27 LREE-depleted lavas have high /sup 143/Nd/sup 144/Nd (0.51309-0.51310) typical of MORBs, whereas /sup 143/Nd/sup 144/Nd in the LREE-enriched lavas varies widely (0.512929-0.513121). Chemical features of the Dumisseau basalts are equivalent to those of Caribbean seafloor basalts recovered on DSDP Leg 15, and support the ...

1988-03-01

171

Correlated variations and periodicity of global CO{sub 2}, biological mass extinctions and extra-terrestrial bolide impacts over the past 250 million years and possible geodynamical implications  

Energy Technology Data Exchange (ETDEWEB)

Earth`s history has been witness to recurrently alternating phases of catastrophic evolution and dominant tectonic deformations, contractions and extension of rifting and spreading leading to quasi-cyclic changes in sedimentary environment and various earth processes. Recent studies have shown quasi-periodicities of 32{+-}2 Million years (Myr) in various endogenic (geomagnetic reversals, magmatic events, mantle convection, various tectonic activities, climate change and biological extinctions) and exogenic (impact catering) processes indicating a remarkable kinship. A time series analysis is presented of the available CO{sub 2} record over the past 250 Myr decoded from global CaCO{sub 3} accumulation rates in sedimentary environment. The time series analysis reveals an intriguing evidence of a dominant periodicity of 33{+-}2 Myr which matches closely with a `common catastrophic periodicity` of 32 Myr identified in various terrestrial and extra-terrestrial records. ...

1998-12-31

172

On the anatomy of the adsorption heat versus loading as a function of temperature and adsorbate for a graphitic surface.  

Science.gov (United States)

In this paper we review and classify the various patterns of isosteric heat versus loading for adsorption of gases on graphitised thermal carbon black at temperatures ranging from below the 3D triple point to temperatures above it, but less than the 3D critical point. We have identified the features of heat curve and highlighted the microscopic origin of these features. The patterns vary with temperature and with the relative strength of the fluid-fluid interaction and solid-fluid interaction. For simple adsorptives (by simple we meant there is no strong association between fluid particles), the heat curve is typified by fluid-fluid attraction and layering phenomena. For adsorptives showing strong association such as water, ammonia and methanol, the heat curve essentially begins below the condensation heat and then approaches it as loading is increased. This is mainly due to the strong hydrogen bonding ...

2008-05-24

173

Void fraction estimation within rod bundles based on three-fluid model and comparison with X-ray CT void data  

Energy Technology Data Exchange (ETDEWEB)

An interfacial shear stress equation in the dispersed-annular two-phase flow regime has been developed, which is based on a three-fluid model consisting of a liquid film on a rod, vapor and entrained liquid associated with a vapor flow. It is an extension of J.G.M. Andersen's procedure that provides a two-fluid interfacial shear stress equation using the drift flux parameters C{sub 0} and V{sub gj}. This interfacial shear stress equation can take into account a phase and velocity distribution through an equivalence between the drift flux parameters and the interfacial shear stress. Using the three-fluid subchannel analysis code TEMPO with the three-fluid interfacial shear stress model the capability of a three-fluid calculation using the drift flux parameters C{sub 0} and V{sub gj} that reproduce a measured void fraction is demonstrated. A comparison was made with advanced ...

1990-06-01

174

Mass transfer model for two-layer TBP oxidation reactions  

Energy Technology Data Exchange (ETDEWEB)

To prove that two-layer, TBP-nitric acid mixtures can be safely stored in the canyon evaporators, it must be demonstrated that a runaway reaction between TBP and nitric acid will not occur. Previous bench-scale experiments showed that, at typical evaporator temperatures, this reaction is endothermic and therefore cannot run away, due to the loss of heat from evaporation of water in the organic layer. However, the reaction would be exothermic and could run away if the small amount of water in the organic layer evaporates before the nitric acid in this layer is consumed by the reaction. Provided that there is enough water in the aqueous layer, this would occur if the organic layer is sufficiently thick so that the rate of loss of water by evaporation exceeds the rate of replenishment due to mixing with the aqueous layer. This report presents measurements of mass transfer rates for the mixing of water and butanol in two-layer, ...

1994-09-28

175

Sulfonaphtholazoresorcinol as reagent for tungsten  

International Nuclear Information System (INIS)

Interaction of W(6) with sulphonaphtholazoresorcinol (SNAR) in aqueous solution has been studied. Tungsten is determined in the form of sulphonaphtholazoresorcinate by extraction with higher alcohols. The optimum conditions for the formation of a complex of W with SNAR in aqueous solution are as follows: a 10-fold excess of SNAR, concentration of HCl 1-1.5N, ethanol content 5-10 vol.%, time of formation of the complex 30 min. A component ratio for the complex has been established in the case of aqueous solution and extract; molar extinction coefficients are 0.9x10"4 and 1.7x10"4, respectively. The formation constant for the complex being extracted is 2.2x10"2"3. A method has been developed for determination of microgram quantities of W in a vanadium specimen.

1977-01-01

176

Spectroscopic properties of the f-elements in compounds and solutions. [79 references  

Energy Technology Data Exchange (ETDEWEB)

In this systematic examination of some of the spectroscopic properties of the f-elements we deal with both the trivalent lanthanides and actinides. We summarize the present status of our energy level calculations in single crystal matrices and in aqueous solution, and compare the predicted crystal-field structure in certain low-symmetry sites with that observed. Some interesting new structural insights are thereby gained. The state eigenvectors from these calculations are then used in part in reassessing and interpreting the intensities of transitions in aqueous solution via the Judd-Ofelt theory. The parameters of this theory derived from fitting experimental data are compared with those computed from model considerations. Finally, we discuss some recent contributions to the interpretation of excited state relaxation processes in aqueous solution. 79 references, 23 figures, 17 tables.

1982-01-01

177

Irradiation of human insulin in aqueous solution, first step towards radiosterilization  

British Library Electronic Table of Contents (United Kingdom)

The degradation of irradiated human insulin in aqueous solutions was investigated in order to protect the protein against ionizing radiation. The influence of the drug concentration, excipients and irradiation temperature were studied.Aqueous solutions at pH 2 were irradiated by gamma rays or by accelerated electrons. Two different high-performance liquid chromatography (HPLC) methods were used: reverse-phase high-performance liquid chromatography (RP-HPLC)/UV and size exclusion liquid chromatography (SEC/UV) to investigate both the fragmentation and the formation of higher molecular weight proteins.In solution without excipients irradiated at ambient temperature at 10kGy, the loss of human insulin is almost complete. Addition of radio-protecting excipients (free radicals scavengers) and c...

2007-01-01

178

Green synthesis of iron nanoparticles and their application as a Fenton-like catalyst for the degradation of aqueous cationic and anionic dyes  

British Library Electronic Table of Contents (United Kingdom)

Iron nanoparticles were produced using extracts of green tea leaves (GT-Fe NPs). The materials were characterized using TEM, SEM/EDX, XPS, XRD, and FTIR techniques and were shown to contain mainly iron oxide and iron oxohydroxide. The obtained nanoparticles were then utilized as a Fenton-like catalyst for decolorization of aqueous solutions containing methylene blue (MB) and methyl orange (MO) dyes. The related experiments investigated the removal kinetics and the effect of concentration for both MB and MO. The concentrations of dyes in aqueous solution were monitored using ultraviolet-visible (UV-vis) spectroscopy. The results indicated fast removal of the dyes with the kinetic data of MB following a second order removal rate, while those of MO were closer to a first order removal rate. T...

2011-01-01

179

First-order kinetics-controlled multiple species reactive transport of dissolved organic compounds in groundwater: Development and application of a numerical model  

Energy Technology Data Exchange (ETDEWEB)

Reactive chemical transport models developed over the past decade have generally relied on the assumption that local thermodynamic equilibrium is achieved at all times between aqueous species in a given system. Consequently, homogeneous aqueous systems characterized by a number of kinetically slow reactions, particularly problems involving organic species, cannot be satisfactorily modeled. In this study, we present a prototype computer model, KINETRAN, which is designed to handle kinetically-controlled homogeneous reactions in the aqueous phase, along with the transport of the various species involved, through geologic media. 31 refs., 53 figs., 10 tabs.

1990-05-01

180

Ferrihydrite phase transformation in the presence of aqueous sulfide and supercritical CO2  

British Library Electronic Table of Contents (United Kingdom)

The transformation of ferrihydrite to siderite (FeCO3) in the presence of supercritical CO2 (scCO2) and aqueous sulfide has been investigated by in situ attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) and ex situ X-ray diffraction (XRD). The chemical transformation of iron-bearing minerals to form iron carbonates may play a role in the chemistry related to the geological sequestration of carbon dioxide in the Earth's (sub)surface. The iron oxyhydroxide ferrihydrite in an aqueous solution containing sodium sulfide in contact with scCO2 at 100^oC reacts within 24h to form siderite and elemental sulfur. In situ studies of this reaction with ATR-FTIR show that ferrihydrite exists with an adsorbed layer of carbonate. However, the presence of the carbonate adsorbat...

2010-01-01

181

Extraction of hafnium by 1-phenyl-3-methyl-4-benzoyl-5-pyralozone from aqueous-alcoholic solutions  

International Nuclear Information System (INIS)

Extraction of hafnium by 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone (HL) in benzene, toluene, chloroform and tetrachloromethane from aqueous-alcoholic solutions of the formal acidity of 2M-HClO_4 was studied. Methyl, ethyl, n- and isopropyl, tert-butyl and allyl alcohol as well as ethylene glycol monomethyl ether and propylene glycol were used as organic components of the mixed aqueous-organic phase. Their presence in some cases resulted in a synergic increase in the distribution ratio of hafnium. The increase is interpreted using the results of a slope analysis and measurements of the alcohol distribution and the relative permittivity of the organic phase. It is suggested that HfL_4 molecules were solvated by alcohol molecules in the organic phase. At high alcohol concentration synergism changed into antagonism. This was caused by changes in the distribution of HL and its interaction with the alcohol in the organic phase. (author).

182

Extraction of americium of different oxidation states in two-phase aqueous system based on polyethylene glycol  

International Nuclear Information System (INIS)

Americium extraction in different oxidation states in two-phase aqueous system based on polyethylene glycol is investigated. Conditions for quantitative extraction of americium (3) and americium (5) from ammonium sulfate solutions within pH=3-5 interval in the presence of arsenazo 3 are found. Composition of the produced americium complexes with reagent is determined; americium (3) interacts with arsenazo 3 in ammonium sulfate solutions with the formation of MeR and Me_2R composition complexes. Absorption spectrum characteristics of americium (3) and- (5) complexes with arsenazo 3 in ammonium sulfate solutions and extracts based polyethylene glycol aqueous solutions are given. Molar extinction coefficients of americium complexes with arsenazo (3) in these solutions are determined.

1987-01-01

183

Dietary plant materials reduce acrylamide formation in cookie and starch-based model systems  

British Library Electronic Table of Contents (United Kingdom)

Abstract BACKGROUND: Dietary plant materials have attracted much attention because of their health benefits to humans. Acrylamide is found in various heated carbohydrate-rich foods. Our previous results showed that crude aqueous extracts from diverse dietary plants and some phenolic compounds could mitigate acrylamide formation in an asparagine-glucose model system. Based on our previous study, several plant materials were selected to further investigate their inhibitory effects on acrylamide formation in cookies and starch-based model systems. RESULTS: Addition of raw powders from selected dietary plants and their crude aqueous extracts could considerably reduce acrylamide formation in both cookie and potato starch-based models. Aqueous extracts of clove at 4% caused the largest reduction...

2011-01-01

184

Coir pith-a biosorbent for removal of cesium from aqueous solutions  

International Nuclear Information System (INIS)

Coir pith (CP), an abundantly available lignocellulosic agricultural waste from the local coir industry has been found to be an effective biosorbent for removal of metal ions from aqueous solutions. Transition metal hexacyanoferrates, in particular nickel hexacyano ferrate (NiHCF) also referred to as Prussian blue analogue (PBA), is known to be highly selective for removal of cesium from aqueous solutions. A novel method for the synthesis of PBA inside the porous matrix of coir pith and use of this composite material for the sorption of cesium is described in this paper. Equilibrium experiments showed that the sorption capacity of coir pith nearly doubled due to the modification. Owing to its low cost and rapid sorption kinetics, this hybrid material seems to be one of the most promising compounds for the recovery of cesium from liquid nuclear wastes. (author)

2007-01-04

185

Absorption of carbonyl sulfide in aqueous methyldiethanolamine  

Energy Technology Data Exchange (ETDEWEB)

The absorption of carbonyl sulfide in aqueous methyldiethanolamine (MDEA) was studied over a range of temperatures and MDEA concentrations. MDEA is commonly used for selective absorption of hydrogen sulfide in the presence of carbon dioxide. However, sulfur in the form of COS may also be present and it is necessary that estimates of absorption rates of this compound be made. The objective of this study is to determine the physiochemical properties needed to predict COS absorption rates in aqueous MDEA. Free gas solubility and the diffusivity of COS in MDEA solutions were measured over the temperature range 15 to 40{sup 0}C for MDEA concentrations up to 30 weight per cent using the nitrous oxide analogy method. Solubilities were measured volumetrically in an equilibrium cell and diffusivities were measured using a laminar liquid jet absorber. The kinetics of the reaction between COS and MDEA were studied by measuring absorption rates in a single ...

1988-01-01

186

Transport of sorbing solutes in randomly heterogeneous formations: Spatial moments, macrodispersion, and parameter uncertainty  

Energy Technology Data Exchange (ETDEWEB)

Expressions for the spatial moments and macrodispersion tensor for sorbing solutes in heterogeneous formations were presented using a probabilistic model of a fluid residence time coupled with the particle position analysis. The fluid residence time was defined as a fraction of the actual time during which the particle stayed in the mobile fluid phase of the aquifer. The fluid residence time is a random variable whose variability comes as a result of the non-equilibrium sorption properties. The sorbing solute was assumed to be governed with first-order linear kinetics. The closed-form expressions were based on the stationarity in the kinetic process and on the first-order approximation in the hydraulic conductivity field and in the fluid residence time. The non-equilibrium effects were presented as a function of the spatial variability in hydraulic conductivity and temporal ...

1993-06-01

187

Integrated numerical modeling of surface-subsurface-coupled, 2-phase fluid/heat flow in limnological system 1. New type of modeling and experimental study; Shizen suirikei no ryutai{center_dot}netsu ido togo moderingu no kokoromi 1. Ryutai{center_dot}netsu ido no atarashii teishikika to jikkenteki kento  

Energy Technology Data Exchange (ETDEWEB)

This paper describes the comprehensive modeling method of fluid and heat flows in the hydrological system. Based upon the concept that the hydrological system is composed of the air-water 2-phase fluids, and the rock phase, various natural processes are modeled including surface/subsurface 2-phase mass transfer, heat exchanges between fluid phases, between fluid and solid phases, and sensible/latent heat exchanges on the ground surface. A field-oriented numerical simulator is developed, in which a set of governing equations is solved for different variables on the surface and in subsurface regions, respectively. Results of an experimental study are presented, in which transient formulation of heat exchange between fluid/solid phases is examined through matching of the observation and calculated performances. (author)

1999-08-31

188

Integrated numerical modeling of surface-subsurface-coupled, 2-phase fluid/heat flow in limnological system 1. New type of modeling and experimental study. Shizen suirikei no ryutai[center dot]netsu ido togo moderingu no kokoromi 1. Ryutai[center dot]netsu ido no atarashii teishikika to jikkenteki kento  

Energy Technology Data Exchange (ETDEWEB)

This paper describes the comprehensive modeling method of fluid and heat flows in the hydrological system. Based upon the concept that the hydrological system is composed of the air-water 2-phase fluids, and the rock phase, various natural processes are modeled including surface/subsurface 2-phase mass transfer, heat exchanges between fluid phases, between fluid and solid phases, and sensible/latent heat exchanges on the ground surface. A field-oriented numerical simulator is developed, in which a set of governing equations is solved for different variables on the surface and in subsurface regions, respectively. Results of an experimental study are presented, in which transient formulation of heat exchange between fluid/solid phases is examined through matching of the observation and calculated performances. (author)

1999-08-31

189

Fluid flow visualization with neutron radiography. [Using collimated beam of neutrons  

Energy Technology Data Exchange (ETDEWEB)

A technique was developed that permits fluid flow to be visualized even where the flow is completely shrouded by metal. The technique employs real-time neutron radiography, which is similar to x-ray radiography except a collimated beam of neutrons is used. Various combinations of neutron-opaque tracer materials were tested with neutron-transparent fluid. Neutron opaque tracers, such as solid particles, fluid droplets, and streaklines were imaged through metal walls as they convected in neutron-transparent ambient fluid. Visualization of bubbles/voids were evaluated for possible future applications. Surface-flow patterns were also imaged by using neutron-opaque tufts. These techniques were evaluated for image contrast, resolution, and the ability to accurately track fluid flow fields. The techniques were also modeled to optimize contrast in various flow configurations. Imaging ...

1991-01-01

190

Fluid flow visualization with neutron radiography  

International Nuclear Information System (INIS)

A technique was developed that permits fluid flow to be visualized even where the flow is completely shrouded by metal. The technique employs real-time neutron radiography, which is similar to x-ray radiography except a collimated beam of neutrons is used. Various combinations of neutron-opaque tracer materials were tested with neutron-transparent fluid. Neutron opaque tracers, such as solid particles, fluid droplets, and streaklines were imaged through metal walls as they convected in neutron-transparent ambient fluid. Visualization of bubbles/voids were evaluated for possible future applications. Surface-flow patterns were also imaged by using neutron-opaque tufts. These techniques were evaluated for image contrast, resolution, and the ability to accurately track fluid flow fields. The techniques were also modeled to optimize contrast in various flow configurations. Imaging ...

1764-01-01

191

Effects of transverse magnetic field, Prandtl number and Reynolds number on non-Darcy mixed convective flow of an incompressible viscous fluid past a porous vertical flat plate in a saturated porous medium  

Energy Technology Data Exchange (ETDEWEB)

The effect of transverse magnetic field parameter (Hartmann number, Ha) Reynolds number (Re) and Prandtl number (Pr) on the mixed convection flow past a semi-infinite vertical porous plate in a non-Darcian porous medium with variable viscosity and porosity, viscous dissipation and fluid-solid thermal conductivity ratio in the presence of plate transpiration (lateral mass flux) is investigated theoretically and numerically using Keller`s implicit finite difference scheme. It is shown that the Harmann number acts as a retarding force and increases the momentum boundary layer thickness, analogous to the flow against a positive pressure gradient, simultaneously decreasing local skin friction (shear stress). The heat transfer rate is however enhanced by the magnetic field (for positive values of the Eckert number) since the fluid is heated and temperature gradients become reduced between the fluid and the plate, with important ...

1997-01-01

192

A computational fluid dynamics investigation of fluid flow in a dense medium plasma reactor  

International Nuclear Information System (INIS)

Computational fluid dynamics are applied to the study of three-dimensional fluid flow in a dense medium plasma reactor (DMPR) under different operating conditions. Reaction mechanisms and rates for the removal of methyl t-butyl ether (MTBE) in a DMPR are developed from experimental data to determine the plasma volume, the rate of interphase mass transfer and the photolysis rate of MTBE via UV emission from the plasma. The simulations utilize the plasma volume determined from the kinetic data to show that the volume of fluid in contact with the plasma in the DMPR only constitutes a maximum of approximately 10% of the fluid intended to be cycled through the plasma tubules. The simulations also predict appreciable pressure gradients on the surface of the pin electrodes, resulting in a small discharge area located away from the region in which the electric field strength is a maximum. This result has been ...

2007-01-21

193

The Differential Expression of Aqueous Soluble Proteins in Breast Normal and Cancerous Tissues in Relation to Stage and Grade of Patients  

UK PubMed Central (United Kingdom)

Breast cancer is a leading cause of female deaths worldwide. In Malaysia, it is the most common form of female cancer while Infiltrating ductal carcinoma (IDC) is the most common form of breast cancer....Full Text Available

2010-01-01

194

Process and apparatus for chemically removing ash from coal  

Science.gov (United States)

Finely divided ash-containing coal is immersed in an aqueous solution of hydrochloric acid or citric acid, and acidic ammonium fluoride to cause the ash to react with the acid and the acidic ammonium fluoride, and the deashed coal is thereafter separated from the solution.

1984-01-03

195

Prevention of chain cleavage in the chemical synthesis of 2'-silylated oligoribonucleotides.  

UK PubMed Central (United Kingdom)

Strong aqueous ammonium hydroxide used to remove N-acyl protecting groups from synthetic oligoribonucleotides causes removal of some alkylsilyl protecting groups from 2'-hydroxyls and leads to chain...Full Text Available

1989-05-11

196

Osmotically Induced Removal of Water from Fungal Cells as Determined by a Spin Probe Technique 1  

UK PubMed Central (United Kingdom)

Effects of physical environment on plasma membrane semipermeability and osmotic induction of changes in aqueous cytoplasmic volume were studied in vegetative and spore cells of a plant pathogenic fungus,...Full Text Available

1978-11-01

197

Membrane nanotubes induced by aqueous phase separation and stabilized by spontaneous curvature  

UK PubMed Central (United Kingdom)

Tubular membrane structures are widespread in eukaryotic cells, but the mechanisms underlying their formation and stability are not well understood. Previous work has focused on tube extrusion from...Full Text Available

2011-03-22

198

Ion clustering in aqueous solutions probed with vibrational energy transfer  

UK PubMed Central (United Kingdom)

Despite prolonged scientific efforts to unravel the hydration structures of ions in water, many open questions remain, in particular concerning the existences and structures of ion clusters in 1∶1...Full Text Available

2011-03-22

201

IgE antibodies to D. pteronyssinus in atopic patients.  

UK PubMed Central (United Kingdom)

An aqueous house dust mite extract was separated by SDS-PAGE and transferred to nitrocellulose membranes by Western Blotting. Two major allergens, Der pI and Der pII associated with the mite faeces...Full Text Available

1988-06-01

202

Foam Filled Muzzle Blast Reducing Device.  

Science.gov (United States)

A device for reducing the muzzle blast and flash from large caliber guns is disclosed. A container having a plurality of internal chambers and baffle plates filled with an aqueous foam is mounted to the muzzle of the gun barrel. The foam and chambers co-o...

1982-01-01

203

Flocculation Equipment on Environmental Expert  

Wastenet

... Optimisation of reactive dye removal by sequential electrocoagulation-flocculation... The removal of Reactive Black 5 dye in an aqueous solution by electrocoagulation (EC) as well... »Read more By M. Mohsen Nourouzi, T. G. Chuah, Thomas S....

204

Felting Process for Making Combustible Cartridge Cases.  

Science.gov (United States)

A cartridge case is made by making up an aqueous slurry of cellulosic fibers, forming the fibers into a mat and molding the mat or preform into final shape by use of a die at up to 165 degrees F.

1965-01-01

205

Electron Spin Resonance Studies of Ionic Permeability Properties of Thylakoid Membranes of Beta vulgaris and Avicennia germinans1  

UK PubMed Central (United Kingdom)

Measurement of intrathylakoid aqueous volumes by electron spin resonance spectroscopy was used to study ionic permeability properties of thylakoid membranes isolated from Beta vulgaris...Full Text Available

1985-05-01

206

Differential stain for mycobacteria that does not require heat.  

UK PubMed Central (United Kingdom)

A stain of 0.1% toluidine blue in a 1.0% aqueous solution of triethylene glycol followed by decolorization with acid-alcohol resulted in mycobacteria retaining the stain (violet), whereas non-acid-fast...Full Text Available

1981-01-01

207

Conformational stability of alternating d (CG) oligomers in high salt solution.  

UK PubMed Central (United Kingdom)

The conformation of d (CG)n oligomers with n = 2,3 has been studied in aqueous solution in the presence of high salt concentration. A minimum n value of three is necessary to obtain a left-handed Z-helix....Full Text Available

1981-05-11

208

Altering high temperature subterranean formation permeability  

Energy Technology Data Exchange (ETDEWEB)

This patent describes a delayed acrylamide containing polymer crosslinker having stability in an aqueous solution at high temperatures. It comprises: a combination of an aldehyde and a salicylic acid derivative selected from salicylamide and acetysalicylic acid.

1991-02-19

209

Adverse Effect of Ammonium Salts on the Antibacterial Activity of Paraformaldehyde Solutions  

UK PubMed Central (United Kingdom)

The antibacterial activity of aqueous solutions of paraformaldehyde in concentrations from 0.1 to 0.4% (w/v) is bacteriostatic rather than bactericidal in the presence or absence of ammonium chloride....Full Text Available

1963-07-01

210

Adhesion of DOPA-Functionalized Model Membranes to Hard and Soft Surfaces  

UK PubMed Central (United Kingdom)

The adhesive proteins secreted by marine mussels form a natural glue that cures rapidly to form strong and durable bonds in aqueous environments. These mussel adhesive proteins contain an unusual...Full Text Available

2009-01-01

211

3G279: the interaction of reagent-demulsifiers and oil components  

Energy Technology Data Exchange (ETDEWEB)

The adsorption interaction of different types of demulsifiers and the oils of Western Siberia is covered. The high adsorption capacity of Separol-5084 and disolvan-4490 reagents is established. The positive role of this phenomen in breaking aqueous oil emulsifiers is theoretically substantiated and experimentally confined.

1981-01-01

212

Thermodynamics &  

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... Thermodynamics & Fluid - EA BOOKS About us | My EA Books | Contact us | Authors Home page Currently ...Electronics Environmental Management Mechanical Multi-disciplinary Quality Railways Structural Water CATEGORIES Books Mechanical Thermodynamics & Fluid Thermodynamics & Fluid Display: 10 results ... Display product Add to shopping basket Engineering Thermodynamics: A Computer Approach, 3rd Edition AU$99.09 ex-GST Terms and Conditions A ...textbook for applied or engineering thermodynamics, or as a reference for practicing engineers, the book uses extensive in-text, solved examples and ...

213

The effect of the shear rate-dependent thermal conductivity of non-Newtonian fluids on the heat transfer in a pipe flow  

Science.gov (United States)

The present study investigates the effect of the shear rate-dependent thermal conductivity of non-Newtonian fluids on the heat transfer enhancement in a pipe flow. The constant heat flux as thermal boundary condition was adopted in the thermally developed region. The present analytical results show the heat transfer enhancement over those of a shear rate-independent thermal conductivity fluid. The heat transfer coefficient ratio (h/h{sub 0}) linearly increase with the non-dimensional average velocity difference which is the product of the shear rate-dependence of the thermal conductivity and wall-shear rate.

1996-09-01

214

Heat rejection system  

Energy Technology Data Exchange (ETDEWEB)

A cooling system for rejecting waste heat consists of a cooling tower incorporating a plurality of coolant tubes provided with cooling fins and each having a plurality of cooling channels therein, means for directing a heat exchange fluid from the power plant through less than the total number of cooling channels to cool the heat exchange fluid under normal ambient temperature conditions, means for directing water through the remaining cooling channels whenever the ambient temperature rises above the temperature at which dry cooling of the heat exchange fluid is sufficient and means for cooling the water. 5 figs.

1980-01-22

215

Electron paramagnetic resonance of nitroxide-doped magnetic fluids  

Energy Technology Data Exchange (ETDEWEB)

Electron paramagnetic resonance was used to investigate surface-coated magnetite-based magnetic fluids doped with TEMPOL. Two magnetic fluid samples, having magnetite nanoparticles with average diameter of 94 A and coated with different coating layers (lauric acid plus ethoxylated polyalcohol in one case and oleoylsarcosine in the other case), were doped with TEMPOL (6 mM and pH 7.4) and investigated as a function of the nanoparticle concentration. The resonance field and the resonance linewidth both scale linearly with the nanoparticle concentration.

2002-11-01

216

Buoyancy effects in double-diffusive and mixed convection flows  

Science.gov (United States)

When induced by bottom heating in a horizontal fluid layer which is characterized by forced motion or solute stratification, buoyancy-driven flows may assume a variety of forms. The flows, which are examples of mixed or double-diffusive convection, can strongly influence heat tranfer or the entrainment of stratified fluid. General aspects of each form of convection are reviewed, and emphasis is placed on mixed convection in a horizontal rectangular channel and on double-diffusive convection due to thermally driven mixed-layer development in a solutally stratified fluids. Flow conditions are described, and experimental and theoretical results are presented for related heat-transfer and entrainment parameters.

1986-01-01

217

A multilayered acoustic hyperlens with acoustic metamaterials  

British Library Electronic Table of Contents (United Kingdom)

The acoustic hyperlens can be realized by an alternating layered structure of water and fluid with negative mass density. Based on this alternating layered principle, we propose that an acoustic metamaterial consisting of three layers in water background can be designed to replace the fluid with negative mass density. The effective mass density and bulk modulus of the system which is composed of acoustic metamaterial and water are functions of the frequency. The effective mass density of such a system is close to the negative mass density of the fluid at a specific frequency; thus an acoustic metamaterial hyperlens can be achieved.

2011-01-01

218

Thermodynamics of potassium diclofenac salt aqueous solutions at various temperatures  

British Library Electronic Table of Contents (United Kingdom)

Solution and dilution enthalpies of aqueous solutions of potassium diclofenac salt (K_DC) were measured by an isoperibolic calorimeter at 298.15 and 318.5?K. Heat capacities of the solutions with concentrations 0.002?0.09?mol?kg?1 were obtained at the temperature interval of 288.15?318.15?K using a scanning adiabatic microcalorimeter. The virial coefficients were derived from Pitzer?s model, and the excess thermodynamic functions of both the solvent and the solute of the solution were calculated. The concentration and temperature dependencies of thermodynamic characteristics of the solution were analyzed and discussed.

2011-01-01

219

Stress corrosion cracking and pitting corrosion relation for zircaloy-4 in chloride-containing hydro-alcoholic media  

International Nuclear Information System (INIS)

A study of stress corrosion cracking susceptibility of Zircaloy-4 in chloride-containing aqueous methanolic media is presented. The influence of water content is investigated in the 5-100 vol. % water range. The dependence of stress corrosion cracking on potential is evidenced. A close correlation is established with pitting susceptibility determined by a statistical analysis of induction times. A correlation with the repassivation potential is observed in the water-rich solutions. In the low water content solutions, two repassivation curves are determined according to the experimental technique. Pit morphology and fractography show a transition from aqueous to organic media. (author).

220

Removal of boron from aqueous solution by using neutralized red mud  

International Nuclear Information System (INIS)

The adsorptive removal of boron from aqueous solution by using the neutralized red mud was studied in batch equilibration technique. The effects of pH, adsorbent dosage, initial boron concentration and contact time on the adsorption were investigated. The experiments demonstrated that boron removal was of a little fluctuation in pH range of 2-7 and it takes 20 min to attain equilibrium. The adsorption data was analyzed using the Langmuir and the Freundlich isotherm models and it was found that the Freundlich isotherm model represented the measured sorption data well.

2007-04-02

221

Rapid and continuous hydrothermal crystallization of metal oxide particles in supercritical water  

Energy Technology Data Exchange (ETDEWEB)

This paper reports on hydrolysis of 10 metal salt aqueous solutions of 6 metal oxides that was conducted in supercritical water. Continuous and rapid production of metal oxide fine particles was achieved by mixing a metal salt aqueous solution with preheated water fed from another line. The reaction time required was less than 2 min. Particle size, morphology, and crystal structure of the obtained metal (hydrous) oxides were examined. Particle size (20 to 600 nm) was different among the system but the size range was relatively narrow in all the cases.

1992-04-01

222

Radiolysis of neutron irradiated lithium solutions  

International Nuclear Information System (INIS)

In the Aqueous Self-Cooled Blanket (ASCB) concept, an aqueous "6Li solution in a metallic structure is used as a shielding-breeding blanket for fusion reactors. The experimental results of this study indicate that the radiolytic gas production in an ASCB will be proportional to the absorbed radiation energy. The observed radiation chemical yields allow the preliminary estimation of the radiolysis effects for a specific ASCB design. Contrary to the theoretical predictions, the use of hydrogen as a cover gas at up to 1 MPa had no measurable effect on the radiolytic gas production. Probably it will thus not be possible to suppress the radiolytic decomposition of a low-pressure ASCB by the addition of hydrogen. Catalytic recombination will be required. (orig.).

223

Process for the chemical removal of ash from coal and device for carrying out this process. Verfahren zur chemischen Entfernung der Asche aus Kohle sowie Vorrichtungen zur Durchfuehrung dieses Verfahrens  

Energy Technology Data Exchange (ETDEWEB)

In order to remove ash from coal, it is introduced into an aqueous ash removal solution, which contains nitric acid or citric acid and ammonium hydrogen fluoride. The coal without ash is then separated from the aqueous solution. According to the process, either finely ground coal is introduced into the ash removel solution or the coal with the solution is ground in a wet pulveriser.

1981-03-13

224

Polythermal study of the M(ClO_4)_2-H_2O systems, where M"2 = Mg"2"+, Ca"2"+, Sr"2"+, Ba"2"+  

International Nuclear Information System (INIS)

Crystallization points of aqueous solution of the systems M(ClO_4)_2-H_2O (M"2 = Mg"2"+, Ca"2"+, Sr"2"+, Ba"2"+), depending on the salt concentration, were identified by visual-polythermal method. Relying on model notions on the structure of the electrolyte solutions, specific features of strontium perchlorate solubility polytherm and concentration dependence of the relative dynamic viscosity of the salt aqueous solutions are discussed

2005-03-01

225

Molecular dynamics simulations of aqueous ionic clusters using polarizable water  

Energy Technology Data Exchange (ETDEWEB)

The solvation properties of a chlorine ion in small water clusters are investigated using state-of-the-art statistical mechanics. The simulations employ the polarizable water model developed recently by Dang [J. Chem. Phys. [bold 97], 2659 (1992)]. The ion--water interaction potentials are defined such that the successive binding energies for the ionic clusters, and the solvation enthalpy, bulk vertical binding energy, and structural properties of the aqueous solution agree with the best available results obtained from experiments. Simulated vertical electron binding energies of the ionic clusters Cl[sup [minus

1993-11-01

226

Modeling of (vapor + liquid) equilibrium and enthalpy of solution of carbon dioxide (CO{sub 2}) in aqueous methyldiethanolamine (MDEA) solutions  

Energy Technology Data Exchange (ETDEWEB)

A thermodynamic model was used to estimate enthalpy of solution of carbon dioxide (CO{sub 2}) in methyldiethanolamine (MDEA) aqueous solutions. The model was based on a set of equations for chemical equilibria, phase equilibria, charge, and mass balances. Non-ideality in the liquid phase was taken into account by interaction parameters fitted to (vapor + liquid) equilibrium data. The enthalpies of solution of CO{sub 2} were derived from the model using classical thermodynamic relations and were compared to experimental values obtained in previous works.

2009-06-15

227

Modeling of (vapor + liquid) equilibrium and enthalpy of solution of carbon dioxide (CO_2) in aqueous methyldiethanolamine (MDEA) solutions  

International Nuclear Information System (INIS)

A thermodynamic model was used to estimate enthalpy of solution of carbon dioxide (CO_2) in methyldiethanolamine (MDEA) aqueous solutions. The model was based on a set of equations for chemical equilibria, phase equilibria, charge, and mass balances. Non-ideality in the liquid phase was taken into account by interaction parameters fitted to (vapor + liquid) equilibrium data. The enthalpies of solution of CO_2 were derived from the model using classical thermodynamic relations and were compared to experimental values obtained in previous works.

2009-06-01

228

Modeling and Experimental Study of Carbon Dioxide Absorption in a Membrane Contactor  

Energy Technology Data Exchange (ETDEWEB)

This dissertation deals with membrane gas absorption in the application of CO{sub 2} removal by aqueous alkanolamines, using microporous PTFE hollow fiber membranes. A new lab-scale apparatus was constructed and an extensive experimental study executed to determine the performance of the membrane gas absorber, with aqueous solutions of monoethanolamine (MEA) and methyldiethanolamine (MDEA) as absorbents. The important operation parameters CO{sub 2} partial pressure, gas velocity, liquid velocity, temperature and liquid CO{sub 2} loading were systematically varied within the range typically experienced in a process for exhaust gas CO{sub 2}-removal

2003-03-15

229

Investigation of chloro, sulfato and oxalato-complexes of protactinium (V) by solvent extraction technique  

International Nuclear Information System (INIS)

The stability constant values of Pa(V) with some complexing ligands (chloride, sulfate and oxalate) are graphically determined using solvent extraction data. The organic phase was at constant composition of HTTA in benzene while the aqueous phase was held at constant hydrogen ion concentration and ionic strength of 3. The curve-fitting method was adopted throughout this investigation, giving the following values. The stability constants obtained are used to calculate the distribution of the different Pa (V) species in the corresponding aqueous phase (expressed in mole fraction) as a function of ligand ion concentration.

230

Coordination compounds of oxovanadium(4), nickel(2) and copper(2) with bis-(salicyliden)-thiocarbazide  

International Nuclear Information System (INIS)

A reaction of aqueous-methanol solutions of thiocarbazide and salycilic aldehyde, taken in a molal ratio of 1:2 on the matrix of oxovanadium(VO) in the presence of aqueous ammonium results in a coordination compound of the VC_1_5H_1_2N_4O_3S composition. Similar compounds are obtained with salts of nickel(2) and copper(2). Complexes of oxovanadium(4) and copper(2) have effective magnetic moments normal for systems with a spin of 1/2. The compound with nickel is diamagnetic. These data agree with the configuration of the coordination compounds obtained.

231

Chronoamperometric study of mild steel pitting in sodium sulfide aqueous solution  

Science.gov (United States)

Mild steel samples were studied by chronoamperometry in sodium sulfide (Na[sub 2]S) aqueous solution. Pit nucleation and growth also were monitored by optical microscopy. The influence of variables such as temperature, polarization potential, surface roughness, the presence of electrochemically generated oxide layers, and the simultaneous presence of potassium hydroxide (KOH) was studied. The influence of each parameter on pit shape and growth was reviewed. Different reactions and competitive processes were proposed based on the experimental results.

1994-08-01

232

Aqueous radioactive waste bituminization  

International Nuclear Information System (INIS)

The bituminzation of decontamination and ion exchange resin stripping wastes with four grades of asphalt was investigated to determine the effects of asphalt type on the properties of the final products. All waste forms deformed readily under light loads indicating they would flow if not restrained. It was observed in all cases that product leaching rates increased as the hardness of the asphalt used to treat the waste increased. If bituminization is adopted for any Ontario Hydro aqueous radioactive wastes they should be treated with soft asphalt to obtain optimum leaching resistance and mechanical stability during interim storage should be provided by a corrosion resistant container.

5049-01-01

233

Adsorption of phosphate from aqueous solution using activated red mud  

Energy Technology Data Exchange (ETDEWEB)

Adsorption of phosphate (PO{sub 4}{sup 3{minus}}) from aqueous solution on activated red mud (ARM) was studied as a function of time, pH, temperature, concentration of adsorbent and adsorbate in acetic acid-sodium acetate buffer medium. The adsorption of phosphate follows Langmuir as well as Freundlich adsorption isotherms. The process efficiency was found to be 80--90% at room temperature. This can be extended to the treatment of industrial effluents containing phosphates like that from phosphatic fertilizer plants.

1998-08-01

234

Unsteady MHD micro polar flow and heat transfer over a vertical porous moving plate with variable suction  

Energy Technology Data Exchange (ETDEWEB)

The unsteady two-dimensional laminar flow of a viscous incompressible electrically conducting micro polar fluid via a porous medium past a semi-infinite vertical porous moving plate in the presence of a transverse magnetic field is studied. A uniform magnetic field acts perpendicularly to the porous surface in which absorbs the micro polar fluid with a suction velocity varying with time. The effects of material parameters on the velocity and temperature fields across the boundary layer are investigated. The method of solution can be applied for small perturbation approximation. Numerical results of velocity and temperature distributions of micro polar fluids are compared with the corresponding flow problems for a Newtonian fluid. (author)

2001-07-01

235

Thoracoscopy in Children: Is a Chest Tube Necessary?  

UK PubMed Central (United Kingdom)

PurposeHistorically, a chest tube or drain has been left following a thoracic operation to allow drainage of air or fluid in the postoperative period. However, in...Full Text Available

2009-04-01

236

Thermal Performance of Low Layer Density Multilayer Insu1ation Using Liquid Nitrogen  

Science.gov (United States)

In order to support long duration cryogenic propellant storage, the Cryogenic Fluid Management (CFM)

2011-01-01

237

The use of tracers to analyze the effects of reinjection into fractured geothermal reservoirs  

Science.gov (United States)

This paper discusses the use of tracers as a reservoir engineering tool in fractured geothermal reservoirs. The principle concern in injecting cooler spent fluids into a fractured reservoir is that the fluids may move through high permeability channels and return to the production wells after contacting a relatively small volume of rock. As a consequence of this rapid transport, the fluids will be only partially reheated and after a short period time will effectively mine the heat from the limited volume of rock. The production wells will then experience a rapid and premature reduction in thermal output. Tracers can be used to infer the existence of high mobility conduits between injection and production wells and to monitor chemical changes of an injected fluid. Since tracer arrival precedes thermal breakthrough, tracer tests are a very useful forecasting tool.

1987-01-01

238

The N-terminal domain of a-dystroglycan, released as a 38kDa protein, is increased in cerebrospinal fluid in patients with Lyme neuroborreliosis  

British Library Electronic Table of Contents (United Kingdom)

a-Dystroglycan is an extracellular adhesion protein that is known to interact with different ligands. The interaction is thought to stabilize the integrity of the plasma membrane. The N-terminal part of a-dystroglycan may be proteolytically processed to generate a small 38kDa protein (a-DG-N). The physiological significance of a-DG-N is unclear but has been suggested to be involved in nerve regeneration and myelination and to function as a potential biomarker for neurodegenerative and neuromuscular diseases. In this report we show that a-DG-N is released into different body fluids, such as lachrimal fluid, cerebrospinal fluid (CSF), urine and plasma. To investigate the significance of a-DG-N in CSF we examined the levels of a-DG-N and known neurodegenerative markers in CSF from patients di...

2011-01-01

239

Sunflower i condenser-subcooler topical re- port, jun. 1960 - aug. 1962  

Science.gov (United States)

Fluid dynamic design criteria for mercury condenser-subcooler component for sunflower power conversion system

1964-01-01

240

Study of ebullated bed fluid dynamics for H-Coal. Quarterly progress report No. 2, December 1, 1977--February 28, 1978  

Science.gov (United States)

The H-Coal ebullated bed reactor contains at least four discrete components: gas, liquid, catalyst, and unconverted coal and ash. Because of the complexity created by these four components, it is desirable to understand the fluid dynamics of the system. The objective of this program is to establish the dependence of the ebullated bed fluid dynamics on process parameters. This will permit improved control of the ebullated bed reactor. Progress has been made in the study undertaken for defining the hydrodynamic properties of gas/liquid/solid systems as related to the H-Coal process. The literature search was completed, and a report will be issued shortly. Design and construction of the fluid dynamics unit proceeded as planned. Unit completion is scheduled for May 1, 1978.

1978-03-01

241

Study of Contemporary Electronic Components under a Fluid ...  

Science.gov (United States)

... The effects of these voids were more noticeable for tantalum and aluminum electrolytic capacitors, which usually exhibited severe case deformation ...

1973-03-01

242

Soret and Dufour effect on double diffusion mixed convection from a vertical surface in a porous medium saturated with a non-Newtonian fluid  

British Library Electronic Table of Contents (United Kingdom)

A non-similar boundary layer analysis is presented to study the flow, heat and mass transfer characteristics of non-Darcian mixed convection of a non-Newtonian fluid from a vertical isothermal plate embedded in a homogeneous porous medium with the effect of Soret and Dufour and in the presence of either surface injection or suction. The value of the mixed-convection parameter lies between 0 and 1. In addition, the power-law model is used for non-Newtonian fluids with exponent n1 for dilatant fluids. Furthermore, the coordinates and dependent variables are transformed to yield computationally efficient numerical solutions that are valid over the entire range of mixed convection, from the pure forced-convection limit to the pure free-conve...

2010-01-01

243

STUDY OF METHODS FOR IMPROVING SYNTHETIC ...  

Science.gov (United States)

... At no time must any solution or water temper- atures exceed 72°F, with all fluids maintained as close as possible to 700F. ...

1963-05-15

244

Properties of molecular solids and fluids at high pressure and temperatures  

Energy Technology Data Exchange (ETDEWEB)

This renewal request for DOE grant DE-FG02-86ER45238, is dedicated to providing a complete thermodynamic profile of solids fluids, and fluid mixtures, over a wide range of temperatures and pressures. We are partially motivated by technological interest in detonation, combustion, superhard high pressure materials, and high temperature superconductors, which are important components of interest of various DOE laboratories. Our work on fluids and solids, composed of simple molecules, involves the determination of structures, phase transitions, pressure-volume relations, phonon, vibron, and libron modes of excitation, sound velocities, specific heats, thermal expansion, virial coefficients, sublimation energies, and orientational translational, and magnetic correlations. We hope that the study of these systems under extreme thermodynamic conditions will lead to exotic new materials of value, as well as enhanced fundamental ...

1992-03-01

245

Pharmacological optimization of tissue perfusion  

UK PubMed Central (United Kingdom)

After fluid resuscitation, vasoactive drug treatment represents the major cornerstone for correcting any major impairment of the circulation. However, debate still rages as to the choice of agent, dose,...Full Text Available

2009-07-01

246

Perfect and Incompressible Fluid Flow in Turbomachines.  

Science.gov (United States)

A method for calculating flow through an airfoil cascade drawn on a surface of revolution is discussed. The three-dimensional flow was assumed to be represented by part-channels of varying width. The basic equations are the equation of continuity and the ...

1974-01-01

247

PROCEEDINGS OF THE 1966 HEAT TRANSFER AND FLUID ...  

Science.gov (United States)

... mass of gray gas by thermal radiation; An experimental study of the turbulent wake behind a cone at M = 5; Heat transfer augmentation by steady ...

248

Novel Magnetic Fluids for Breast Cancer Therapy  

Science.gov (United States)

... metal-oleate complexes. At this point, this method has been reported only for iron nanoparticles [15]. We have demonstrated ...

2008-01-01

249

Locally invasive lymphangiosarcoma in a young domestic shorthair  

British Library Electronic Table of Contents (United Kingdom)

A 2-year-old, female spayed, domestic shorthair cat presented to the University of Missouri-Veterinary Medical Teaching Hospital (UMC-VMTH) with an approximately 11-month history of fluid-draining pockets along her ventral thorax and axillae. The skin in these regions was erythematous, and multiple areas drained a serous to serosanguinous fluid. Fluid-filled, nodules formed along the ventrum, but these nodules disappeared as fluid drained spontaneously. Histologic assessment of skin biopsies revealed areas of vascular proliferation extending along the deep margin of the section and rare instances of invasion into the superficial dermis. These vascular channels were devoid of cells, lined by variably pleomorphic endothelial cells which had a low mitotic index. Based on the mild to moderate ...

2011-01-01

250

Identification and application of black-box model for a self-sensing damping system using a magneto-rheological fluid damper  

British Library Electronic Table of Contents (United Kingdom)

In vibration control field, magneto-rheological (MR) fluid dampers are semi-active control devices that have recently begun to receive more attention. This paper presents a black-box model (BBM) for identification of a MR fluid damper and its application to vibrating control systems using that damper with self-sensing behavior. A model named ''black-box'' is a simple direct modeling method which is designed for a typical MR fluid damper using the self-tuning fuzzy technique. The characteristics of the researched damper are directly estimated through a fuzzy mapping system. In order to improve the accuracy of the proposed model, the back propagation algorithm and gradient descent method were used to train the fuzzy parameters to minimize the model error function. Consequently, the BBM with ...

2010-01-01

251

Geometry of elastic hydrofracturing by injection of an over pressured non-Newtonian Fluid  

CERN Document Server

The nucleation and propagation of hydrofractures by injection of over pressured fluids in an elastic and isotropic medium are studied experimentally. Non-Newtonian fluids are injected inside a gelatine whose mechanical properties are assumed isotropic at the experimental strain rates. Linear elastic theory predicts that plastic deformation associated to breakage of gelatin bonds is limited to a small zone ahead of the tip of the propagating fracture and that propagation will be maintained while the fluid pressure exceeds the normal stress to the fracture walls (Ch\\'avez-\\'Alvarez,2008) (i.e., the minimum compressive stress), resulting in a single mode I fracture geometry. However, we observed the propagation of fractures type II and III as well as nucleation of secondary fractures, with oblique to perpendicular trajectories with respect to the initial fracture. In the Video (http://hdl.handle.net/1813/14122) experimental ...

2009-01-01

253

Evaluation of CFD to Determine Two-Dimensional Airfoil ...  

Science.gov (United States)

rotor flow field in which the main rotor operates. The majority of ..... early separation predicted by their CFD code was ...... Airfoil, AGARD Fluid Dynamics Panel ...

254

Design and Operation of a Novel Capillary Pumped Two-Loop System for Cooling of Electronic Devices  

British Library Electronic Table of Contents (United Kingdom)

Heat pipes, loop heat pipes (LHP), and capillary pumped loops (CPL) have already proven their potential to remove high heat fluxes from a small electronic device and transport the heat to a heat sink that is large enough to transfer it into the ambient air. We introduce a novel two-loop system similar in design to CPLs but with an additional buoyancy-driven fluid loop. Non-degassed methanol is used as a working fluid. Key benefits compared to LHPs and CPLs are easy filling procedure, easy startup, and the tolerance toward noncondensable gases in the fluid. The amount of fluid in the system can be varied over a broad range without affecting the heat transfer performance. Three different inverted-meniscus-type evaporators have been employed in this study. A maximum evaporator heat transfer r...

2012-01-01

255

Bibliography of Documents Related to the Theory, Operation ...  

Science.gov (United States)

... 28, No. 12B, December 1986, pp. 1931-1942. Dattner, A. and Eninger, J., "Studies of a Coaxial Plasma Gun," The Physics of Fluids, Vol. 7, No. ...

1990-11-01

256

Analysis of the omnium-g receiver  

Energy Technology Data Exchange (ETDEWEB)

A thermal analysis of the Omnium-G receiver is presented and the technique is shown to be generally applicable to solar thermal receivers utilizing a directly heated thermal mass. The thermal loss coefficient, including reradiation losses, is calculated and shown to agree quite well with the experimentally measured thermal loss coefficient. The rate of heat transfer to the working fluid is also analyzed and the analysis is used to show that the Omnium-G receiver is well matched to the water/steam working fluid because the steam outlet temperature is almost the same as the receiver temperature. A general procedure for calculating receiver performance is presented. With this procedure, the energy delivery to any working fluid, the delivered temperature of the working fluid, and the pressure drop through the receiver can be determined. An example of the calculation is also presented.

1980-03-01

257

Advanced distillation curve measurements for corrosive fluids: Application to two crude oils  

British Library Electronic Table of Contents (United Kingdom)

We have recently introduced several important improvements in the measurement of distillation curves for complex fluids. The modifications include a composition-explicit data channel for each distillate fraction (for both qualitative and quantitative analysis) and corrosivity assessment of each distillate fraction. The composition-explicit information is achieved with a new sampling approach that allows precise qualitative as well as quantitative analyses of each fraction, on the fly. We have applied the new method to a variety of fluids, including simple n-alkanes, rocket propellant, gasoline, jet fuels, and a hydrocarbon fluid made corrosive with dissolved hydrogen sulfide. In the current contribution, we present the application of the advanced distillation curve method to two samples of...

2008-01-01

258

Active Dynamic Flow Control Studies on Rotor Blades  

Science.gov (United States)

... of the cycle shows that the separation area ea. ... with suitable flow solvers based on the Reynolds ... AGARD 75th Fluid Dynamics Panel Meeting and ...

2001-06-01

259

Wind instability of a foam layer sandwiched between the atmosphere and the ocean  

CERN Document Server

Kelvin-Helmholtz instability of short gravity waves is examined in order to explain the recent findings of the decrease in momentum transfer from hurricane winds to sea waves. A three-fluid configuration of a foam layer between the atmosphere and the ocean is suggested to provide signifficant stabilization of the system and shifting the marginal critical wavelength to the shortwave part of the spectrum. It is conjectured that such stabilization leads to the observed drag reduction. The high contrasts in three fluid densities provide a universal mechanism for stabilizing surface perturbations.

2007-01-01

260

Themis solar receiver  

Energy Technology Data Exchange (ETDEWEB)

The conception of a solar receiver intended to equip a tower power-station has to combine multiple requirements: very highly concentrated solar flux, unsteady in time and space; necessity to obtain a high efficiency; respect of the physical limits of the materials and of the fluid. The description of Themis solar receiver and of its operation is preceded by considerations which have led to the choice of the cavity, of the fluid and of its circulation.

1982-01-01

261

Power fluidics and the environment  

International Nuclear Information System (INIS)

This paper reviews power fluidics technology in the nuclear industry giving emphasis also on its potential uses in chemical plants and in flood and irrigation control. This is a technology of controlling process fluids by purely hydrodynamic methods, which should increase system reliability by eliminating valves, pumps and other fluid control devices that are often causes of failure. This review indicates that the hydrodynamics of fluidic components are not satisfactorily understood at present and may be more complex than similar theory in electronics.

262

Physical therapy applications of MR fluids and intelligent control  

Science.gov (United States)

Resistance exercise has been widely reported to have positive rehabilitation effects for patients with neuromuscular and orthopaedic conditions. This paper presents an optimal design of magneto-rheological fluid dampers for variable resistance exercise devices. Adaptive controls for regulating the resistive force or torque of the device as well as the joint motion are presented. The device provides both isometric and isokinetic strength training for various human joints.

2005-05-01

263

Oil well drilling clay conditioners and method of their preparation  

Energy Technology Data Exchange (ETDEWEB)

Drilling fluid additives are prepared by oxidation of sulfonated lignin-containing materials with manganese dioxide under highly acidic conditions to make manganese lignosulfonates. Additional improvements in the rheological properties of the additives may be obtained by complexing the manganese lignosulfonate so obtained with a heavy metal cation (preferably iron or copper), by, for example, addition of ferrous sulfate or ferric sulfate to the manganese lignosulfonate. These products show the requisite combination of rheological properties for a satisfactory drilling fluid additive or conditioner.

1984-05-08

264

Heterogeneous mechanism of nucleation in a superheated cryogenic fluid flow  

Energy Technology Data Exchange (ETDEWEB)

A model of heterogeneous mechanism of nucleation on impurity particles in a fluid volume is proposed. The particle spectrum is reproduced by solving the ''inverse'' problems on stationary outflow of a boiling parahydrogen with the use of experimental data of authors. A relation for a closure of the equation system describing a non-equilibrium outflow is obtained. It is shown that within the investigated parameter range one manages to calculate the characteristics of a stationary outflow with a satisfactory accuracy.

1984-03-01

265

Heat transfer from magneto-rheological fluid dampers  

Science.gov (United States)

This paper presents a theoretical study of heat transfer from magneto-rheological fluid (MRF) dampers. A lumped system model is developed which is capable of predicting the temperature rise for any size MRF damper. As a case study example, finned and unfinned dampers are compared for automotive-size MRF dampers. The results demonstrate that heat transfer from these devices can be enhanced considerably with the use of fins.

2000-04-01

266

Dimension reduction in fluid dynamics equations  

British Library Electronic Table of Contents (United Kingdom)

A method for transforming the Euler and Navier-Stokes equations and a complete system of fluid dynamics equations in three dimensions to a closed system on any moving surface is proposed. As a result, for an arbitrary geometric configuration, the dimension of the equations is reduced by one, which makes them convenient for numerical simulation. The general principles of the method are described, and verifying examples are presented.

2011-01-01

267

Depth of origin of the gas content in thermal waters  

Energy Technology Data Exchange (ETDEWEB)

The gas composition of recent thermal waters is in perfect conformity with their geologic-tectonic positions. The composition of gas-liquid inclusions in the basic-hyperbasic xenoliths of basaltoid lavas depends on the depth from which xenoliths are supplied. (The depth is determined by using the methods of geological thermobarometers). By comparing available data the conclusion was drawn that the gas compositions of thermal waters reflect the depth of generation of deep fluid which heats them and depends on the penetration depth of the fluid-conducting fissure zones.

1980-01-01

268

Density Currents  

Science.gov (United States)

In this activity, students will make a turbidity current. They will discover how fluids of differing densities interact with one another, learn some ways the densities of fluids can be changed and observe how density currents transport and deposit tremendous amounts of sediment in lakes and in the ocean. Additional options allow students to create and observe different kinds of density currents.

269

Thermomechanical vibration analysis of a functionally graded shell with flowing fluid  

Energy Technology Data Exchange (ETDEWEB)

This paper reports the results of an investigation into the vibration of functionally graded cylindrical shells with flowing fluid, embedded in an elastic medium, under mechanical and thermal loads. By considering rotary inertia, the first-order shear deformation theory (FSDT) and the fluid velocity potential, the dynamic equation of functionally graded cylindrical shells with flowing fluid is derived. Here, heat conduction equation along the thickness of the shell is applied to determine the temperature distribution and material properties are assumed to be graded distribution along the thickness direction according to a power-law in terms of the volume fractions of the constituents. The equations of eigenvalue problem are obtained by using a modal expansion method. In numerical examples, effects of material composition, thermal loading, static axial loading, flow velocity, medium stiffness and shell geometry parameters on ...

2008-11-15

270

The onset of convection in a couple stress fluid saturated porous layer using a thermal non-equilibrium model  

Energy Technology Data Exchange (ETDEWEB)

The stability of a couple stress fluid saturated horizontal porous layer heated from below and cooled from above when the fluid and solid phases are not in local thermal equilibrium is investigated. The Darcy model is used for the momentum equation and a two-field model is used for energy equation each representing the solid and fluid phases separately. The linear stability theory is employed to obtain the condition for the onset of convection. The effect of thermal non-equilibrium on the onset of convection is discussed. It is shown that the results of the thermal non-equilibrium Darcy model for the Newtonian fluid case can be recovered in the limit as couple stress parameter C{yields}0. We also present asymptotic analysis for both small and large values of the inter phase heat transfer coefficient H. We found an excellent agreement between the exact solutions and asymptotic solutions when H is very ...

2009-02-16

271

The condition monitoring of fluid-filled taped cables employed in underground transmission through dissolved gas analysis  

Energy Technology Data Exchange (ETDEWEB)

There is an urgent need to monitor the condition of fluid-filled taped (FFT) cables. The Dissolved-Gas Analysis (DGA) technique that has been successfully applied to power transformers holds great potential for the preventive maintenance of FFT cables. However, before this emerging technique can be properly applied to cables, a suitable fluid sampling and subsequent gas analysis method had to be developed, including the generation of both laboratory and field data to aid in data interpretation. Data on gas saturation levels in various cable fluids have been presented. This paper describes a novel method developed specifically for FFT cables and discusses field results so obtained. The type, distribution and concentration of gases from fluid alone and paper alone under electrical stress has been presented, including the differences between normal and not-so-normal cable systems as demonstrated by DGA. ...

1994-12-31

272

Novel reduced pressure-balance syringe for chromatographic analysis.  

Science.gov (United States)

When withdrawing a fluid sample (for additional chromatographic analyses) from an apparatus operated at a reduced pressure, a typical syringe proves to be ineffective (even if it is equipped with a gas tight plunger). It simply does not create enough pressure differential to remove a fluid sample from a reduced pressure environment. We encountered such a situation as part of efforts to extend the operation of the advanced distillation curve protocol to reduced pressures. The problem was solved by the development of a pressure balance syringe that allows reliable and precise sampling from an apparatus operating at sub-ambient pressures. This new device uses an external vacuum source to evacuate a syringe barrel, allowing a user to withdraw fluid samples from environments with pressures as low as 0.5kPa. To demonstrate the operation of the newly developed device, distillate analyses were performed on two ...

2010-09-19

273

Nevada Nuclear Waste Storage Investigations: Exploratory Shaft Facility fluids and materials evaluation  

Energy Technology Data Exchange (ETDEWEB)

The objective of this study was to determine if any fluids or materials used in the Exploratory Shaft Facility (ESF) of Yucca Mountain will make the mountain unsuitable for future construction of a nuclear waste repository. Yucca Mountain, an area on and adjacent to the Nevada Test Site in southern Nevada, USA, is a candidate site for permanent disposal of high-level radioactive waste from commercial nuclear power and defense nuclear activities. To properly characterize Yucca Mountain, it will be necessary to construct an underground test facility, in which in situ site characterization tests can be conducted. The candidate repository horizon at Yucca Mountain, however, could potentially be compromised by fluids and materials used in the site characterization tests. To minimize this possibility, Los Alamos National Laboratory was directed to evaluate the kinds of fluids and materials that will be used and their potential ...

1988-11-01

274

Modeling and field studies of radon-222 in geothermal reservoirs  

Science.gov (United States)

Radon-222 was shown to be useful in-situ tracer for studying thermodynamic, geologic, and transport properties of geothermal reservoirs. The relationships to reservoir properties are based on steady-state and non-steady-state models which incorporate the thermodynamic state and relative mobility of the fluids, and partitioning between the fluid phases. The steady-state thermodynamic models assume equilibrium between radon emanation from the reservoir rock and the geofluid concentration. The non-steady-state model solves the partial differential equations describing radon transport under transient two-phase geothermal flow conditions. Radon concentrations of fluids from nine geothermal reservoirs showed strong correlations to the specific volume of the reservoir fluid. Lowest values were associated with all-liquid wells at Cerro Prieto, Wairakei, and Los Azufres reservoirs, and the highest values for ...

1986-01-01

275

Catalytic hydrothermal gasification of biomass for the production of synthetic natural gas[Dissertation 17100  

Energy Technology Data Exchange (ETDEWEB)

Energy from biomass is a CO{sub 2} neutral, sustainable form of energy. Anaerobic digestion is an established technology for converting biomass to biogas, which contains around 60% methane, besides CO{sub 2} and various contaminants. Most types of biomass contain material that cannot be digested; in woody biomass, this portion is particularly high. Therefore, conventional anaerobic digestion is not suited for the production of biogas from woody biomass. While wood is already being converted to energy by conventional thermal methods (gasification with subsequent methanation), dung, manure, and sewage sludge represent types of biomass whose energy potential remains largely untapped (present energetic use of manure in Switzerland: 0.4%). Conventional gas phase processes suffer from a low efficiency due to the high water content of the feed (enthalpy of vaporization). An alternative technology is the hydrothermal gasification: the water contained within the biomass serves as reaction ...

2007-07-01

276

Analytical study on integrity of BWR reactor internal structures against water hammer under RIA conditions  

Energy Technology Data Exchange (ETDEWEB)

The integrity of the RPV head and reactor internals was assessed by means of fluid-structural analyses using a coupled method to evaluate the water hammer phenomenon arising from high burnup fuel failure under RIA conditions. The fluid viscosity effect on the water column burst as well as the complex three-dimensional flow paths caused by a core shroud and standpipes were considered in this study. The three analysis scenarios were designed to investigate the above mentioned influential factors separately. In the first scenario, a two-dimensional axisymmetric reactor vessel model without any reactor internals was modeled to assess the influence of the fluid dynamics in the NSC RIA regulatory evaluation. This model has an actual RPV geometry and can be simply separated from other influential factors in order to concentrate only on investigation of the fluid viscosity effect. In the second scenario, a ...

2003-07-01

277

Diverter/bop system and method for a bottom supported offshore drilling rig  

Energy Technology Data Exchange (ETDEWEB)

A system is described adapted for alternative use as a diverter or a blowout preventer for a bottom supported drilling rig and adapted for connection to a permanent housing attached to rig structural members beneath a drilling rig rotary table, the permanent housing having an outlet connectable to a rig fluid system flow line. The system consists of: a fluid flow controller having a controller housing with a lower cylindrical opening and an upper cylindrical opening and a vertical path therebetween and a first outlet passage and a second outlet passage provided in its wall, a packing element disposed within the controller housing, and annular piston means adapted for moving from a first position to a second position, whereby in the first position the piston means wall prevents interior fluid from communicating with the outlet passages in the controller housing wall and in the second position the piston means wall allows ...

1986-07-01

278

Adsorption of argon on homogeneous graphitized thermal carbon black and heterogeneous carbon surface.  

Science.gov (United States)

In this paper we investigate the effects of surface mediation on the adsorption behavior of argon at different temperatures on homogeneous graphitized thermal carbon black and on heterogeneous nongraphitized carbon black surface. The grand canonical Monte Carlo (GCMC) simulation is used to study the adsorption, and its performance is tested against a number of experimental data on graphitized thermal carbon black (which is known to be highly homogeneous) that are available in the literature. The surface-mediation effect is shown to be essential in the correct description of the adsorption isotherm because without accounting for that effect the GCMC simulation results are always greater than the experimental data in the region where the monolayer is being completed. This is due to the overestimation of the fluid-fluid interaction between particles in the first layer close to the solid surface. It is the surface mediation that reduces this ...

2005-07-15

279

Removal of Cr(III) from aqueous solutions using zeolite NaY prepared from rice husk ash  

International Nuclear Information System (INIS)

The efficiency of the synthesized zeolite NaY from rice husk ash (RHA) in the removal of Cr(III) from aqueous solution was studied. Zeolite NaY was synthesized from RHA via seeding technique and the identification of its structure was done by X-ray Diffraction (XRD) technique and the elemental analysis was carried out by X-ray Fluorescence (XRF). The physicochemical properties which were related to the use of the zeolite NaY as a sorbent was also investigated. The synthesized zeolite NaY has higher cation exchange capacity (CEC) than the commercial zeolite NaY due to the higher amount of sodium content in the synthesized as well as the lower ratio of silica to alumina. The synthesized zeolite NaY together with the commercial one as comparison was used in the sorption of the Cr(III) in aqueous solution by batch sorption experiments. The kinetic study showed that the Cr(III) uptake by both zeolites were based on the pseudo second order model. ...

2007-01-01

280

Molar extinction coefficients in aqueous solutions of some amino acids  

International Nuclear Information System (INIS)

Mass attenuation coefficients of amino acids viz. glycerine (C_2H_5NO_2), 1-Serine (C_3H_7NO_3), 1-Theronine (C_4H_9NO_3), 1-Proline (C_5H_9NO_2), 1-Valine (C_5H_1_1NO_2) and 1-Phenylalanine (C_9H_1_1NO_2) in aqueous solutions have been determined at 81, 356, 511, 662, 1173 and 1332 keV by the gamma-ray transmission method in a narrow beam good geometry setup. Precisely measured densities of these solutions were used for the determination of these coefficients which varied systematically with the corresponding changes in the concentrations (g/cm"3) of the solutions. Molar extinction coefficients of amino acids were then obtained at these energies and were found to be in good agreement with the theoretical results. In addition, total interaction cross sections of amino acids in aqueous solutions were also calculated. (author)

2002-09-01

281

Magnetic nanoparticle (Fe3O4) impregnated onto tea waste for the removal of nickel(II) from aqueous solution  

British Library Electronic Table of Contents (United Kingdom)

The removal of Ni(II) from aqueous solution by magnetic nanoparticles prepared and impregnated onto tea waste (Fe3O4-TW) from agriculture biomass was investigated. Magnetic nanoparticles (Fe3O4) were prepared by chemical precipitation of a Fe^2^+ and Fe^3^+ salts from aqueous solution by ammonia solution. These magnetic nanoparticles of the adsorbent Fe3O4 were characterized by surface area (BET), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM) and Fourier Transform-Infrared Spectroscopy (FT-IR). The effects of various parameters, such as contact time, pH, concentration, adsorbent dosage and temperature were studied. The kinetics followed is first order in nature, and the value of rate constant was found to be 1.90x10^-^2min^-^1 at 100mgL^-^1 and 303K. Removal ef...

2011-01-01

282

Effect of water activity on the lipase catalyzed esterification of geraniol in ionic liquid [bmim]PF6.  

Science.gov (United States)

Enzymatic reactions in non-aqueous media have been shown to be effective in carrying out chemical transformation where the reactants are insoluble in water or water is a byproduct limiting conversion. Ionic liquids, liquid organic salts with infinitesimal vapor pressure, are potentially useful alternatives to organic solvents. It is known that the thermodynamic water activity is an important variable affecting the activity of enzymes in non-aqueous solvents. This study investigated the influence of water activity on the esterification of geraniol with acetic acid in ionic liquid [bmim]PF6 catalyzed by immobilized Candida antarctica lipase B. The conversion of geraniol in [bmim]PF6 was significant although the reaction rate was slower than in organic solvents. The profile of initial reaction rate-water activity was determined experimentally, and differed from the data reported for other non-aqueous solvents. A maximum in the ...

2006-02-01

283

ELECTROLYTIC MEMBRANE DIALYSIS FOR TREATING WASTEWATER STREAMS  

Energy Technology Data Exchange (ETDEWEB)

This project will determine whether electrolytic dialysis has promise in the separation of charged particles in an aqueous solution. The ability to selectively move ions from one aqueous solution to another through a semipermeable membrane will be studied as a function of emf, amperage, and particle electrical charge. The ions selected for the study are Cl{sup -} and SO{sub 4}{sup 2-}. These ions are of particular interest because of their electrical conduction properties in aqueous solution resulting with their association with the corrosive action of metals. The studies will be performed with commercial membranes on solutions prepared in the laboratory from reagent salts. pH adjustments will be made with dilute reagent acid and base. Specific objectives of the project include testing a selected membrane currently available for electrolytic dialysis, membrane resistance to extreme pH conditions, the effectiveness of ...

2000-04-01

284

Biosorption of copper (II) onto immobilized cells of Pycnoporus sanguineus from aqueous solution: Equilibrium and kinetic studies  

Energy Technology Data Exchange (ETDEWEB)

The ability of white-rot fungus, Pycnoporus sanguineus to adsorb copper (II) ions from aqueous solution is investigated in a batch system. The live fungus cells were immobilized into Ca-alginate gel to study the influence of pH, initial metal ions concentration, biomass loading and temperature on the biosorption capacity. The optimum uptake of Cu (II) ions was observed at pH 5 with a value of 2.76 mg/g. Biosorption equilibrium data were best described by Langmuir isotherm model followed by Redlich-Peterson and Freundlich models, respectively. The biosorption kinetics followed the pseudo-second order and intraparticle diffusion equations. The thermodynamic parameters enthalpy change (10.16 kJ/mol) and entropy change (33.78 J/mol K) were determined from the biosorption equilibrium data. The FTIR analysis showed that -OH, -NH, C-H, C=O, -COOH and C-N groups were involved in the biosorption of Cu (II) ions onto immobilized cells of P. sanguineus. The immobilized cells ...

2009-01-15

285

Benz(a)pyrene levels in medicinal plants and the possibility of contamination of drugs of plant origin  

Energy Technology Data Exchange (ETDEWEB)

Benz(a)pyrene (BP) levels in extracts and solvent cake obtained by alcoholic and aqueous extraction of specimens of 20 different medicinal plants were measured to explore into the possibility of its passage from these plants to drugs. Seventy percent alcoholic extracts were found to contain 40-60% of BP passed from raw material, while aqueous extracts--2-3% (in some cases 10-14%). Maximal concentrations of BP in alcoholic extracts were 0.6-0.7 micrograms/1 and 0.03-0.04 micrograms/1--in aqueous ones. A significant correlation between BP level in extracts and its content in plants was established. BP pathways in the course of solasodine manufacturing from nightshade (Solanum lacinatum) were studied. As little as 1% of BP passed to extract after primary extraction in 2%--sulfuric acid. Solasodine contained about 3 micrograms/kg of BP.

1983-01-01

286

Basic design of alpha aqueous waste treatment process in NUCEF  

Energy Technology Data Exchange (ETDEWEB)

This paper described the basic design of Alpha Aqueous Waste Treatment Process in NUCEF. Since various experiments using the TRU (transuranium) elements are carried out in NUCEF, wastes containing TRU elements arise. The liquid wastes in NUCEF are categorized into three types. Decontamination and volume reduction of the liquid waste mainly of recovery water from acid recovery process which has lowest radioactive concentration is the most important task, because the arising rate of the waste is large. The major function of the Alpha Aqueous Waste Treatment Process is to decontaminate the radioactive concentration below the level which is allowed to discharge into sea. Prior the process design of this facility, the followings are evaluated:property and arising rate of the liquid waste, room space to install and licensing condition. Considering varieties of liquid wastes and their large volume, the very high decontamination factor was proposed by ...

1996-11-01

287

Thermal-fluid flow analysis and demonstration test of a spent fuel storage system  

Energy Technology Data Exchange (ETDEWEB)

Thermal-fluid flow analysis and demonstration test were performed for a spent fuel storage system. The commercial computational fluid dynamics (CFD) code, FLUENT was used for the numerical analysis. Effective thermal conductivities of a spent fuel assembly and a fuel basket were derived to optimize a thermal analysis model. Also, a porous model, which can simplify a complex configuration of a fuel assembly, was used in the thermal analysis. Demonstration test were performed to verify the thermal analysis method and procedure using a half scaled-down model and an electrically heated dummy fuel. The numerical analysis results were compared with the experimental data. Thermal analyses of the storage system were carried out for normal and off-normal conditions by using the verified analysis method.

2009-03-15

288

The structure of an active acoustic metamaterial with tunable effective density  

Energy Technology Data Exchange (ETDEWEB)

A new class of one-dimensional active acoustic metamaterials (AAMMs) with programmable effective densities is presented. The proposed AAMM is capable of producing densities that are orders of magnitudes lower or higher than the ambient fluid. Such characteristics are achieved by using an array of fluid cavities separated by piezoelectric diaphragms that are controlled to generate constant densities over wide frequency bands. The piezodiaphragms are augmented with passive electrical components to broaden the operating frequency bandwidth and enable densities higher than the fluid medium to be generated. The use of these components is shown to be essential to maintain the closed-loop compliance of the piezodiaphragm away from the zone of elastic instabilities. The values of the passive components are selected on a rational basis in order to ensure a balance between the frequency bandwidth and control voltage. With this unique ...

2009-12-15

289

The effects of temperature dependent viscosity and thermal conductivity on unsteady MHD convective heat transfer past a semi-infinite vertical porous moving plate with variable suction  

British Library Electronic Table of Contents (United Kingdom)

In this article, we studied the effects of variable viscosity and thermal conductivity on an unsteady two-dimensional laminar flow of a viscous incompressible conducting fluid past a semi-infinite vertical porous moving plate taking into account the effect of a magnetic field in the presence of variable suction. The fluid viscosity is assumed to vary as an inverse linear function of temperature but the thermal conductivity is assumed to vary as a linear function of temperature. It is assumed that the porous plate moves with a constant velocity in the direction of fluid flow, and the free stream velocity follows the exponentially increasing small perturbation law. The governing equations for the flow are transformed into a system of nonlinear ordinary differential equations by perturbation ...

2007-01-01

290

The composition-explicit distillation curve technique: Relating chemical analysis and physical properties of complex fluids  

British Library Electronic Table of Contents (United Kingdom)

The analysis of complex fluids such as crude oils, fuels, vegetable oils and mixed waste streams poses significant challenges arising primarily from the multiplicity of components, the different properties of the components (polarity, polarizability, etc.) and matrix properties. We have recently introduced an analytical strategy that simplifies many of these analyses, and provides the added potential of linking compositional information with physical property information. This aspect can be used to facilitate equation of state development for the complex fluids. In addition to chemical characterization, the approach provides the ability to calculate thermodynamic properties for such complex heterogeneous streams. The technique is based on the advanced distillation curve (ADC) metrology, wh...

2010-01-01

291

THE EFFECT OF VARIABLE THERMAL CONDUCTIVITY ON MICRO-POLAR FLUID FLOW BY CHEBYSHEV COLLOCATION METHOD  

British Library Electronic Table of Contents (United Kingdom)

In this article, the authors analyzed the effect of thermal conductivity on unsteady magnetohydrodynamic (MHD) free convection in a micro-polar fluid past a semi-infinite vertical porous plate. The fluid thermal conductivity is assumed to vary as a linear function of temperature. By using the Chebyshev collocation method in the spatial direction and the Crank-Nicolson method in the time direction, the boundary layer equations are transformed into a linear algebraic system. There are several material parameters whose affect on the flow have been studied, for instance, thermal conductivity, radiation, magnetic, micro-polar, suction (or injection) parameters, and Prandtl number. Boundary layer and Boussineq approximations have been introduced together to describe the flow field. The domain of...

2010-01-01

292

Novel reduced pressure-balance syringe for chromatographic analysis  

British Library Electronic Table of Contents (United Kingdom)

When withdrawing a fluid sample (for additional chromatographic analyses) from an apparatus operated at a reduced pressure, a typical syringe proves to be ineffective (even if it is equipped with a gas tight plunger). It simply does not create enough pressure differential to remove a fluid sample from a reduced pressure environment. We encountered such a situation as part of efforts to extend the operation of the advanced distillation curve protocol to reduced pressures. The problem was solved by the development of a pressure balance syringe that allows reliable and precise sampling from an apparatus operating at sub-ambient pressures. This new device uses an external vacuum source to evacuate a syringe barrel, allowing a user to withdraw fluid samples from environments with pressures as l...

2010-01-01

293

Nonlinear black-box models and force-sensorless damping control for damping systems using magneto-rheological fluid dampers  

British Library Electronic Table of Contents (United Kingdom)

In vibration control field, magneto-rheological (MR) fluid dampers are semi-active control devices that have recently begun to receive more attention. This paper presents a nonlinear black-box model (BBM) and an inverse black-box model (IBBM) for the identification of a MR fluid damper and their application to design a novel force-sensorless control method for any damping system using that damper. The nonlinear model named 'black-box' is a simple direct modeling method which was designed based on fuzzy-neural technique. Characteristics of the damper in study are directly estimated through a fuzzy mapping system. In order to improve the model accuracy, neural network technique including back-propagation and gradient descent method were used to train the fuzzy parameters to minimize the mode...

2011-01-01

294

Neurotoxicity and bony diseases caused by the continuous contamination with aluminum of solutions of renal dialysis  

International Nuclear Information System (INIS)

This article reviews the principal evidences about aluminum neurotoxicity in vitro, and some evidences in brain tissues of Alzheimer patients; and also show some studies realized with human that suffer renal deficiencies, dealing whit the principal osteodystrophy. The problem of analyzing low aluminum concentration in human fluids is overcome with very sensitive analytical methods as electrothermal atomic absorption spectrometry (ETAS) and voltammetric methods as Anodic Striping Voltammetry with complexing agents that easing adsorption over solid electrodes or mercury hanging drops. Is a vital question to know with accuracy the aluminum concentration in water used in hemodialysis or in fluids used in ambulatory peritoneal dialysis, as a first stage to prevent contamination by aluminum. So the prevention of contamination during sapling storage and analysis of biological fluids should be the first need and the sources of ...

2001-01-01

295

Ion processing element with composite media  

Energy Technology Data Exchange (ETDEWEB)

An ion processing element employing composite media disposed in a porous substrate, for facilitating removal of selected chemical species from a fluid stream. The ion processing element includes a porous fibrous glass substrate impregnated by composite media having one or more active components supported by a matrix material of polyacrylonitrile. The active components are effective in removing, by various mechanisms, one or more constituents from a fluid stream passing through the ion processing element. Due to the porosity and large surface area of both the composite medium and the substrate in which it is disposed, a high degree of contact is achieved between the active component and the fluid stream being processed. Further, the porosity of the matrix material and the substrate facilitates use of the ion processing element in high volume applications where it is desired to effectively process a high volume flows.

2009-03-24

296

Intrinsic fluorescence of the amniotic fluid  

International Nuclear Information System (INIS)

The intrinsic fluorescence of clear amniotic fluid from third-trimester pregnancy is reported. The fluorescence intensity peaked at 405 nm when excited by ultraviolet light in the range of 310 to 360 nm. All of the 33 samples tested fluoresced, and their emission spectrum had the same shape, varying only in magnitude. Changing sample temperature (20 to 50 C) and sample pH (7.2 to 7.7) had little effect on the emission spectrum. The same fluorescence, with higher intensity, was observed when some newborn urine was tested. The fluorescence of amniotic fluid may provide a new tool to determine fetal age, fetal organ maturation, and fetal distress. (author).

1981-01-01

297

In situ Raman spectroscopy investigation of bioactive glass reactivity: Simulated body fluid solution vs TRIS-buffered solution  

British Library Electronic Table of Contents (United Kingdom)

In the present contribution, the innovative in situ Raman micro-spectroscopy was applied to investigate the in vitro reactivity of various bioactive glasses. All the investigated glasses belonged to the Na2O\\K2O-CaO-P2O5-SiO2 system, but contained sensibly different percentages of network modifiers. The glasses were immersed for increasing times, up to 96h, in simulated body fluid (SBF) and in tris-buffered (TRIS) solution. In this way, two fundamental items were addressed, i.e. the effect of the glass composition and the nature of the soaking fluid on the overall reactivity. As regards the SBF, all the glasses were able to promote the formation of a hydroxyl-carbonate apatite (HCA) surface layer in very short times. The reaction rate was particularly quick for the 45S5 Bioglass and for it...

2011-01-01

298

Improvements in SCR systems  

Energy Technology Data Exchange (ETDEWEB)

Selective catalytic reduction (SCR) is a method of reducing the emissions of nitrogen oxides into the atmosphere. Peerless Manufacturing Co. specialises in designing and building SCR systems. The company uses fluid flow modelling to design systems, creating physical and/or numerical flow models to normalise the flow and eliminate potential problems. Computational fluid dynamics (CFD) is used to visualise fluid flow within SCR units and other types of equipment involving phase separators, air intake systems etc. An example is given of use of the commercial CFD code FLUENT to create a full-scale model of an SCR unit so its design could be modified for optimum performance. 1 fig., 1 photo.

2000-12-01

299

Electrorheological RayleighTaylor instability at the interface between a porous layer and thin shell with poorly conducting couple stress fluid  

British Library Electronic Table of Contents (United Kingdom)

This paper is concerned with the study of the Electrorheological RayleighTaylor instability (ERTI) at the interface between a densely packed saturated poorly conducting couple stress porous layer accelerated by a lighter poorly conducting couple stress fluid in a thin shell in the presence of a transverse electric field and laser radiation. A simple theory based on fully developed flow approximations is used to derive the dispersion relation for the growth rate of ERTI. The cutoff and the maximum wave numbers and the corresponding maximum frequencies are obtained. It is shown that the effects of couple stress parameter and the electric field reduce the growth rate considerably compared to a non-conducting fluid in the absence of an electric field. These are favorable to control the surface...

2011-01-01

300

Electrochemical characterization and CFD simulation of flow-assisted corrosion of aluminum alloy in ethylene glycol-water solution  

British Library Electronic Table of Contents (United Kingdom)

An impingement jet system was used to study flow-assisted corrosion (FAC) of 3003 aluminum (Al) alloy in ethylene glycol-water solutions that simulates the automotive coolant by corrosion potential and electrochemical impedance spectroscopy (EIS) measurements as well as computational fluid dynamics (CFD) simulation. The effects of solution pH and fluid impact angle on Al FAC were determined. An increase of solution pH enhances the activity of Al due to dissolution of Al oxide film in alkaline environment. Moreover, Al activity decreases with the increasing fluid impact angle to the specimen. A CFD simulation shows that, with the increase of impact angle, the electrode area under high-velocity flow field decreases and that under low-velocity flow field increases. Consequently, the shear str...

2008-01-01

301

Couple stress fluid improve rub-impact rotor-bearing system - Nonlinear dynamic analysis  

British Library Electronic Table of Contents (United Kingdom)

This study performs a dynamic analysis of the rub-impact rotor supported by two couple stress fluid film journal bearings. The strong nonlinear couple stress fluid film force, nonlinear rub-impact force and nonlinear suspension (hard spring) are presented and coupled together in this study. The displacements in the horizontal and vertical directions are considered for various non-dimensional speed ratios. The numerical results show that the dynamic behaviors of the system vary with the dimensionless speed ratios, the dimensionless unbalance parameters and the dimensionless parameter, l*. Inclusive of the periodic, sub-harmonic, quasi-periodic and chaotic motions are found in this analysis. The results of this study contribute to a further understanding of the nonlinear dynamics of a rotor-...

2010-01-01

302

Computerized pressure monitoring and control of Hydro-Quebec`s fluid-filled high-voltage underground cable network in Montreal  

Energy Technology Data Exchange (ETDEWEB)

The development and installation, by Hydro-Quebec, of a computerized pressure monitoring and control system on its fluid-filled high voltage underground cable network in Montreal, was described. The average age of these underground fluid-filled cables is more than 30 years and the cost to replace the circuits is estimated to be 230 million dollars. It is, therefore, crucial to maintain at all times and under all operating conditions a positive oil pressure in order to maintain the dielectric strength of paper insulation, and to prevent air and moisture from entering the cables and accessories. The monitoring and control system is reliable, flexible, user friendly and easy to upgrade. It reduces intervention time on the cables and ensures the protection of the cable network by remotely operating valves to connect oil reserve banks and by providing efficient maintenance management tools. 1 ref., 1 tab., 4 figs.

1996-08-01

303

Comparison of fluid-dynamic modeling of flow with velocity-encoded MR imaging  

International Nuclear Information System (INIS)

This paper develops a fluid dynamic model using finite difference methods characterizing flow in phantoms simulating in vivo conditions and to compare those results with velocity encoded MR images. The phantom consisted of 1-inch (2.5-cm) tubing with semicircular insert and fluid with viscosity, T1, and T2 comparable to blood. Numeric solutions to Navier-Stokes equations for this system were obtained using finite difference methods, with velocity input function of zero at walls and parabolic at both ends. In resulting color raster (CR) images, color temperature represented velocity value. In velocity-encoded MR images acquired under the same flow conditions, phase is proportional to average velocity during application of flow-encoding gradients. Because these gradients are applied along one direction per acquisition, magnitude and direction of velocity are obtained.

1990-11-25

304

Analysis of cerebrospinal fluid from chronic fatigue syndrome patients for multiple human ubiquitous viruses and xenotropic murine leukemia-related virus  

British Library Electronic Table of Contents (United Kingdom)

Abstract Recent reports showed many patients with chronic fatigue syndrome (CFS) harbor a retrovirus, xenotropic murine leukemia-related virus (XMRV), in blood; other studies could not replicate this finding. A useful next step would be to examine cerebrospinal fluid, because in some patients CFS is thought to be a brain disorder. Finding a microbe in the central nervous system would have greater significance than in blood because of the integrity of the blood-brain barrier. We examined cerebrospinal fluid from 43 CFS patients using polymerase chain reaction techniques, but did not find XMRV or multiple other common viruses, suggesting that exploration of other causes or pathogenetic mechanisms is warranted. Ann Neurol 2011;

2011-01-01

305

User's guide to PROTOCOL, a numerical simulator for the dissolution reactions of inorganic solids in aqueous solutions  

Energy Technology Data Exchange (ETDEWEB)

This report provides a user's manual for PROTOCOL, a comprehensive coupled kinetic/equilibrium computer program for analyzing the dissolution reactions of solids with aqueous solutions, specifically applied to the potential corrosion of vitrified nuclear waste by groundwater. The capabilities and available options are summarized as well as instructions for setting up and running problems. Also described in this report and included in the PROTOCOL software package are MASTER, a master file of species thermodynamic data, MANEQL, a preprocessor program and POSTP, a postprocessor. POSTP provides offline plotting using the CRAY-1 DISSPLA 9.0 graphics library. PROTOCOL is operational on the CDC-7600 and CRAY-1 computers at the Lawrence Livermore National Laboratory. 7 references, 10 figures, 2 tables.

1984-10-01

306

Thermodynamics of aqueous magnesium chloride, calcium chloride, and strontium chloride at elevated temperatures  

International Nuclear Information System (INIS)

Heat capacities and densities of aqueous MgCl/sub 2/, CaCl/sub 2/, and SrCl/sub 2/ from the accompanying paper are combined with literature data up to 473 K to yield temperature-dependent equations by using the ion-interaction model of Pitzer. These heat capacity equations have been integrated to yield the enthalpy and the Gibbs energy. The enthalpy parameters for 298 K are evaluated in separate calculations using published high-temperature osmotic data as well as heats of dilution, while the Gibbs energy parameters for 298 K are taken from the literature. The range of validity of the final equations is described.

1987-01-01

307

The effect of ion implantation of Ar on the aqueous corrosion resistance of Zr-4 alloy  

International Nuclear Information System (INIS)

The effect of ion implantation on the aqueous corrosion resistance of Zr-4 in deaerated 1N H_2SO_4 was studied with the potentiokinetic technique. The Zr-4 alloy was bombarded with 5x10"1"4-2x10"1"6 Ar/cm"2 of 190 keV. It was found that the passive current density of Zr-4 decreases with increasing implantation dose. Photoelectrochemical results show that the ion implantation of Ar in Zr-4 raises the flatband potential of its passive film. AES was employed to analyze the surface of the passive film of Zr-4. The decrease in passive current density may be attributed to a thickening oxide layer on Zr-4 and a decrease in concentration of oxygen vacancies in its passive film. ((orig.)).

308

Statistical design of experiments as a tool for optimizing the batch conditions to methylene blue biosorption on yellow passion fruit and mandarin peels  

British Library Electronic Table of Contents (United Kingdom)

In order to reduce the total number of experiments for achieving the highest removal of methylene blue (MB) from aqueous solutions using yellow passion fruit peel (Passiflora edullis, F. flavicarpa) and mandarin peel (Citrus reticulata) as biosorbents two independent sets of full 23 factorial designs with two central points (10 experiments) were experimented. In order to continue the optimization of the system a new full 22 factorial design with two central points (six experiments) and a central composite surface analysis (13 experiments, divided into four cube points, five centre points, and four axial points) were employed for yellow passion fruit peel (PFP) and mandarin peel (MP), respectively. Using these statistical tools, the best conditions for MB removal from aqueous solution were ...

2007-01-01

309

Sorption of Brilliant Red HE-3B Reactive Dye from Aqueous Solution onto Seashells Waste: Equilibrium and Kinetic Studies  

British Library Electronic Table of Contents (United Kingdom)

The potential of waste seashells powder, as a new adsorbent for Brilliant Red HE-3B reactive dye removal from aqueous solutions, was examined by the batch technique. The Freundlich, Langmuir, and Dubinin-Radushkevich adsorption models were applied to describe the equilibrium sorption data and to determine the corresponding isotherm constants. The values of the thermodynamic parameters, ?G, ?H, and ?S, indicate that the sorption of reactive dye is a spontaneous and endothermic process. The kinetic data evaluated by pseudo-first order, pseudo-second order, and intraparticle diffusion kinetic models suggested that the sorption of reactive dye onto seashell is a complex process and both surface sorption and intraparticle diffusion contributes to the rate limiting step.

2011-01-01

310

SUCCESSES AND EMERGING ISSUES IN SIMULATING THE MIXING BEHAVIOR OF LIQUID-PARTICLE NUCLEAR WASTE SLURRIES AT THE SAVANNAH RIVER SITE - 211B  

Energy Technology Data Exchange (ETDEWEB)

Aqueous radioactive high-level waste slurries are combined during processing steps that ultimately produce a stable borosilicate glass waste form. Chemically treated waste slurries are combined with each other and with glass frit-water slurries to produce the melter feed. Understanding the evolution of the rheological properties of the slurries is an important aspect of removing and treating the stored waste. To a first approximation, combinations of colloidal waste slurry with {approx}0.1-mm mean diameter glass frit or glass beads act in an analogous matter to slurries of spherical beads in Newtonian liquids. The non-Newtonian rheological properties of the waste slurries without frit, however, add complexity to the hydrodynamic analysis. The use of shear rate dependent apparent viscosities with the modified Einstein equation was used to model the rheological properties of aqueous frit-waste slurries.

2009-09-02

311

SAXS studies on added-salt species dependence of conformation of fully-charged poly(L-glutamate) in aqueous solutions  

Energy Technology Data Exchange (ETDEWEB)

The effect of counter-ion species on the local conformation of fully-charged poly(L-glutamate) in added-salt aqueous solutions were studied by small-angle X-ray scattering(SAXS). In the case of presence of monovalent counter-ion, the scattering behaviour could be explained by taking into consideration the excluded volume effect and intermolecular-interface interaction on the scattering function of wormlike chain. On the other hand, since SAXS profile of the solution in the presence of divalent counter-ion well fitted to the scattering function of dendrimer, it suggested that the conformation of polymer chain in such solution would be more compact conformation than that of presence of monovalent ion.

2010-10-01

312

Removal of reactive dye Brilliant Red HE-3B from aqueous solutions by industrial lignin: Equilibrium and kinetics modeling  

British Library Electronic Table of Contents (United Kingdom)

The lignin, one of the main by-products of the pulp industry, can be used to remove dyes from textile wastewaters. The potential of the lignin for Brilliant Red HE-3B reactive dye removal from aqueous solutions at pH=1.5 was examined by the batch technique as a function of dye concentration, solution temperature and contact time. The Freundlich, Langmuir, Dubinin-Radushkevich and Tempkin adsorption isotherms were used to describe the data of sorption equilibrium and to determine its corresponding isotherm constants. The thermodynamic parameters DG, DH and DS were also determined; the obtained values show that the sorption of reactive dye on lignin is a spontaneous, endothermic and entropy-driven process. The kinetic of reactive dye sorption was analyzed using the pseudo-first order and pse...

2010-01-01

313

Removal of methylene blue dye from aqueous solutions by adsorption using yellow passion fruit peel as adsorbent  

British Library Electronic Table of Contents (United Kingdom)

The removal of color from aquatic systems caused by presence of synthetic dyes is extremely important from the environmental viewpoint because most of these dyes are toxic, mutagenic and carcinogenic. In this present study, the yellow passion fruit (Passiflora edulis Sims. f. flavicarpa Degener) peel a powdered solid waste, was tested as an alternative low-cost adsorbent for the removal of a basic dye, methylene blue (MB), from aqueous solutions. Adsorption of MB onto this natural adsorbent was studied by batch adsorption isotherms at room temperature. The effects of shaking time and pH on adsorption capacity were studied. An alkaline pH was favorable for the adsorption of MB. The contact time required to obtain the maximum adsorption was 56h at 25degreeC. Yellow passion fruit peel may be ...

2008-01-01

314

Remazol Black B removal from aqueous solutions and wastewater using weakly basic anion exchange resins  

British Library Electronic Table of Contents (United Kingdom)

In this study, the use of the weakly basic anion exchange resins of phenol-formaldehyde (Amberlyst A 23), polyacrylate (Amberlite IRA 67) and polystyrene (Lewatit MonoPlus MP 62) matrices for removal of the reactive dye Remazol Black B (RBB) from aqueous solution and wastewater were investigated. RBB sorption on the anion exchangers was a time dependent process. Color reduction percentiles of 75.2, 33.9 and 25.1% in wastewater treatment were found after 216 h of phase contact time with Lewatit MonoPlus MP 62, Amberlyst A 23 and Amberlite IRA 67, respectively. Inorganic salts and anionic surfactant action influenced RBB uptake by the anion exchangers. The amounts of dye retained by the anion exchangers increased with a rise in temperature. The maximum sorption capacities calculated from the...

2011-01-01

315

Recovery of transplutonium elements from aqueous and water-ethanol solutions of sulfuric acid and their separation from other actinides  

Energy Technology Data Exchange (ETDEWEB)

The behavior of Am, Cm, Bk, Cf, Es, and other actinides, as well as Zr, on anion and cation exchangers in aqueous and water-ethanol solutions of sulfuric acid as a function of the various components of the solution has been investigated. It has been discovered that the presence of ethanol in sulfuric acid solutions causes an increase in the distribution coefficients both on cation exchangers and on anion exchangers. The possibility of the use of ion exchangers for the preconcentration and separation of transplutonium elements from U, Np, Pu, Zr, and other elements which form strong complexes with sulfate ions over a broad range of concentrations of sulfuric acid has been demonstrated.

1988-05-01

316

Radiation oxidation of phenol in petrochemical waste water. II  

International Nuclear Information System (INIS)

The rate was studied of radiation destruction of phenol aqueous solutions at a concentration range of 1 to 100 ppm. Irradiated were model solutions containing additions of some organic and inorganic substances typical of the petrochemical industry. In view of the fact that the radiation destruction kinetics is determined by the amount of dissolved oxygen in the sample and by the phenol concentration, relatively low doses were used. Thus, a sufficient amount of oxygen in the sample and therefore the oxidation mechanism of radiolysis were ensured. The dose-response relationships for phenol destruction were studied using doses of 50, 100, 200 and 400 J.kg"-"1; the limit dose was 500 J.kg"-"1. From the results obtained, a kinetic model was constructed of radiation phenol oxidation in aqueous solutions in the presence of various organic and inorganic additions. (B.S.).

1981-01-01

317

Preparation of tetravalent praseodymium in potassium phosphotungstate aqueous solutions  

International Nuclear Information System (INIS)

The possibility has been studied of oxidizing Prsup((3)) to Prsup((4)) when Prsup((3)) is added to an aqueous weakly-acid solution containing K_1_0[P_2W_1_7O_6_1H_2O] x H_2O. A sharp change in the solution colouring has been observed as a result of Prsup((3)) oxidation to Prsup((4)). The absorption spectra of solution of Prsup((4)) have been recorded and the values of the molar extinction coefficients have been determined. On storage of the solution, Prsup((4))reduces to Prsup((3)) with a half-reduction period of 0.2-0.5 hour.

1977-01-01

318

Photodestruction of explosives in process water  

Energy Technology Data Exchange (ETDEWEB)

Photodestruction has received much attention in recent years. In particular, titanium dioxide (TiO{sub 2}) and ozonolysis have attained a position of prominence. These technologies hold promise for the destruction of trace amounts of aqueous high explosives that are generated by load and pack operations, as well as demilitarization activities. Currently this water is treated by passing through a bed of activated carbon. The carbon is then steam regenerated and reused, thus creating a second waste stream which must be disposed of, or the carbon is burned directly. Recent trends in environmental regulation have shown that this may not be a viable option for process water remediation in the future. This talk will discuss efforts to employ alternate aqueous treatment techniques that not only remove the explosives compounds but are able to transform the parent compound into carbon dioxide and water. Titanium dioxide photocatalysis as well as ...

1995-12-31

319

Photodegradation of flupentixol in aqueous solution under irradiation at 254nm: Identification of the photoproducts generated  

British Library Electronic Table of Contents (United Kingdom)

After irradiation at 254nm of aqueous solutions of the antipsychotic drug flupentixol, the structures of the photodegradation products were determined by ultra high performance liquid-chromatography linked to mass spectrometry. Fragmentation patterns of the parent ions were established on a hybrid linear ion trap-orbitrap mass spectrometer allowing accurate mass measurements of both parent and daughter ions. This allowed to propose plausible structures for the main photolysis products of flupentixol. A total of nine photoproducts were detected after irradiation of the drug. The main photoproduct is generated following the addition of a hydroxyl group on the double bond adjacent to the thioxanthene ring. Secondary photoproducts were also observed.

2010-01-01

320

Phase-Separation Kinetics and Mechanism in a Methylcellulose/Salt Aqueous Solution Studied by Time-Resolved Small-Angle Light Scattering (SALS)  

British Library Electronic Table of Contents (United Kingdom)

Abstract Phase-separation dynamics are investigated by SALS in aqueous MC solutions in the presence of 5% NaCl, promoted by a quench temperature. The observed scattering peak indicates that the phase separation occurs by the SD mechanism, leading to a bicontinuous structure. A semilog plot of I(q) against time in the early stage of SD gives a straight line, but the position of qmax varies; also, a Cahn-Hilliard plot indicates that diffusive processes dominate and the data can be described by linear CHC theory. Dapp shows a kinetic dependency on the quench temperature. The spinodal temperature of the sample is 41-C. In the late stages, S(q,t) collapses into a universally time-independent curve.

2011-01-01

321

Non-Aqueous Preparation of High-Crystallinity Hierarchical TiO2 Hollow Spheres with Excellent Photocatalytic Efficiency  

British Library Electronic Table of Contents (United Kingdom)

Abstract High-crystallinity hierarchical anatase TiO2 hollow spheres were prepared by a high-temperature (350 C) and non-aqueous solvothermal method in the absence of water, templates, or additives. The hollow structures were assembled from highly crystallized TiO2 nanoparticles and exhibit superior photocatalytic properties relative to those of Degussa P25 TiO2 under irradiation with UV light. The influence of reaction temperature on the crystallinity, morphology, crystallite shape and size, band gap, specific surface area, and pore size distribution of TiO2 has been studied in detail. It is evident that reaction temperature is the most important factor to increase the crystallinity of TiO2 in order to improve its charge transfer and transport properties, which are important in photocatal...

2011-01-01

322

Laser surface modification for aqueous corrosion resistance  

International Nuclear Information System (INIS)

Laser surface modification can lead to formation of a novel microstructure on the surface of a material resulting in improved surface properties. During the past one and half decades, a number of investigations have been reported on laser surface modification techniques for improving the corrosion resistance of various materials. This paper reviews various work reported on utilising laser modification techniques for enhancing the aqueous corrosion resistance of materials. The laser surface modification work carried out on materials like stainless steels, C-steels, low alloy steels and non-ferrous materials such as Zr, Zn, Al, Ni, Mg and their alloys has been covered in the review. General features observed in improving the corrosion resistance after laser processing have been discussed and scope for future investigations in this field has been highlighted. (author). 97 refs., 15 figs., 5 tabs.

323

Kinetics of uranium (VI) ions adsorption on activated charcoal from aqueous solutions  

Energy Technology Data Exchange (ETDEWEB)

The temperature and concentration dependence of the kinetics of uranium(VI) ions adsorption onto activated charcoal from aqueous solutions has been studied. The adsorption proceeds via a rather fast stage followed by a slower one, with activation energies of 5.41 and 17.46 kJ . mol[sup -1] respectively. The diffusion of uranium ions into the pores of the activated charcoal controls the kinetics of adsorption which follows the Langmuir isotherm equation in the concentration range studied. The adsorption equilibrium constant k[sub c] has been derived at temperatures between 283 K and 323 K as well as [Delta] G, [Delta] H and [Delta] S. The results indicate that the adsorption of uranium ions on activated charcoal is an endothermic process. (orig.)

1994-01-01

324

Kinetics of the methylparathion hydrolysis in aqueous medium; Cinetica de la hidrolisis del metilparation en medio acuoso  

Energy Technology Data Exchange (ETDEWEB)

The kinetics of alkaline hydrolysis of methylparathion was studied at different temperatures (0-50 Centigrade) in the p H range of 8-12 by ultraviolet-visible absorption spectroscopy. Optimum p H and wavelength conditions were defined to carry out the simultaneous determination of methylparathion and one of its hydrolysis product, paranitrophenol, in buffered aqueous medium. Based on the experimental data and the mathematical equation of the kinetics, a rate constant (k) of first-order and an activation energy (Ea) of 9.2 Kcal/mol, were estimated. (Author) activation energy (Ea) of 9.2 Kcal/mol, were estimated. (Author)

1997-12-31

325

Kinetics of carbon dioxide absorption in aqueous solutions of diisopropanolamine  

Energy Technology Data Exchange (ETDEWEB)

A bubble column absorber was used to investigate kinetics of the reaction between carbon dioxide and aqueous solutions of diisopropanolamine (DIPA), by means of gas absorption experiments. These were conducted in the temperature range of 10 to 40deg C, with DIPA concentrations from 5 to 500 mol/m{sup 3}, and CO{sub 2} partial pressures between 5 and 101 kPa. A model based on the Danckwerts' surface reneval theory was used to analyze the experimental results and to determine the rate constant. The obtained data support the assumption of a second-order overall reaction, with the rate constants being well correlated by the Arrhenius equation: k{sub 2} = 1.112 x 10{sup 10} exp(-4848/T). (orig.).

1992-04-01

326

Interaction of periodic and iodic acids with propyoneamide in aqueous solutions  

International Nuclear Information System (INIS)

Interaction of periodic and iodic acids with propyoneamide in aqueous solutions at 25 deg C has been studied. In the system iodic acid-propyoneamide-water formation of two compounds of the composition 6C_2H_5CONH_2#centre dot#HIO_3 and C_5H_5CONH_2#centre dot#HIO_3 is ascertained, for which concentrational boundaries of formation, density, melting points are determined. The system periodic acid-propyoneamide-water is referred to the simple eutonic type. By the method of IR spectroscopy it has been shown that oxygen atom of amide carbonyl group is the centre of propyoneamide protonation by iodic acid.

327

Hydrogen-atom attack on methyl viologen in aqueous solution studied by pulse radiolysis  

International Nuclear Information System (INIS)

Using hydrogen at high pressures of up to 150 bar as an OH scavenger in aqueous MV"2"+ solutions (pH 1) it is possible to differentiate between two kinds of transient formed simultaneously by H-atom attack on methyl viologen. One of them is assigned to an H adduct on the N atom, MV"+H"+, with absorption bands identical to those of the radical cation, MV"+. The MV"+H"+ species deprotonates forming the long-lived radical cation, MV"+. The second type of transient produced is attributed to an H-adduct on the ring carbon, MV"2"+H, decaying by second-order kinetics. The formation of MV"+ by electron transfer from the propan-2-ol radical has been reinvestigated (pH 0 to 7); its absorption spectrum does not change in this pH range. Rate constants and molar extinction coefficients are presented. (U.K.).

1984-01-01

328

Distributions of /sup 35/S-sulfate and /sup 3/H-glucosamine in the angular region of the hamster: light and electron microscopic autoradiography  

Energy Technology Data Exchange (ETDEWEB)

The distribution of /sup 35/S-sulfate and /sup 3/H-glucosamine in the angular region of the hamster was studied by light and electron microscopic autoradiography following intraperitoneal injection of these compounds to hamsters. Exposed silver grains of /sup 35/S-sulfate were concentrated in the trabecular meshwork, sclera, and cornea, and grains of /sup 3/H-glucosamine were localized in the trabecular region. The radioactivity of both isotopes was observed in the Golgi apparatuses of the endothelial cells of the angular aqueous plexus and the trabecular meshwork. The grains were noted over the entire cytoplasm, except for the nucleus, and then were incorporated into the amorphous substance and collagen fibers in the region adjacent to the angular aqueous sinus. These results suggest that endothelial cells in the angular region synthesize and secrete the sulfated glycosaminoglycans and hyaluronic acid.

1983-06-01

329

Development of a waterjet system for direct delivery of granular iron and activated carbon to remediate contaminated aqueous sediments  

British Library Electronic Table of Contents (United Kingdom)

Abstract While the techniques and technologies associated with contaminated sediment remediation are relatively mature, there are several issues associated with these practices that make them unattractive. The inability of currently used mechanical mixing implements to place amendments in aqueous environments and their intrusive behavior toward benthic communities are just two examples of a necessity for an improved delivery method. Waterjets may be a viable option for placement of particulate remediation amendments, such as activated carbon and granular iron, at depth. A custom waterjet nozzle and injection system has been fabricated by the authors to examine this delivery concept. The developed injection system's performance was tested by characterizing the waterjet-delivered amendment (...

2011-01-01

330

Corrosion resistance characteristic of aluminium bronze containing chromium and zirconium  

International Nuclear Information System (INIS)

There are reported the results of corrosion resistance investigation of aluminium bronzes, containing about 8 and 10% of aluminium and modifying quantities of zirconium. The tests of corrosion resistance were carried out in synthetic seawater, in 3% NaCl aqueous solution and in 10% H_2SO_4 aqueous solution, with reference to industrial bronze BA93 (CuAl9Fe3). The bronzes were tested in an annealed, hardened, tempered state and after plastic hot working. The conclusion is that corrosion resistance of aluminium bronzes, especially against selective corrosion, depends more on material structure, resulted form heat treatment, than on chemical composition. (author). 6 refs, 8 figs, 6 tabs.

331

Corrosion behaviour of Alloy 800 in high temperature aqueous solutions: Electrochemical studies  

International Nuclear Information System (INIS)

The anodic behaviour and passivity breakdown of Alloy 800 in aqueous solutions of sodium chloride, sodium sulphate and sodium bicarbonate were studied by electrochemical techniques in the temperature range from 60 C to 280 C. The pitting resistance and pitting morphology of the alloy in chloride plus sulphate and chloride plus bicarbonate mixtures, at 60 C and 280 C, were also examined. Increasing bicarbonate or sulphate additions to chloride solutions shift the characteristic pitting potential of Alloy 800 to higher values, both at low and high temperatures. Changes in pitting morphology were observed in sulphate containing solutions while the morphology of the attack found in bicarbonate containing solutions was similar to that in pure chloride solutions. Finally, no localized or substantial generalized corrosion was detected in pure sulphate or bicarbonate solutions at any temperature. (orig.).

332

Biosorption of reactive dye by waste biomass of Nostoc linckia  

British Library Electronic Table of Contents (United Kingdom)

Potential of spent biomass of a cyanobacterium, Nostoc linckia HA 46, from a hydrogen bioreactor was studied for biosorption of a textile dye, reactive red 198. The waste biomass was immobilized in calcium alginate and used for biosorption of the dye from aqueous solution using response surface methodology (RSM). Kinetics of the dye in aqueous solution was studied in batch mode. Interactive effects of initial dye concentration (100-500mg/L), pH (2-6) and temperature (25-45^oC) on dye removal were examined using Box-Behnken design. Maximum adsorption capacity of the immobilized biomass was 93.5mg/g at pH 2.0, initial concentration of 100mg/L and 35^oC temperature, when 94% of the dye was removed. Fourier transform infrared (FT-IR) studies revealed that biosorption was mainly mediated by fun...

2011-01-01

333

Biosorption of Acid Blue 25 by unmodified and CPC-modified biomass of Penicillium YW01: Kinetic study, equilibrium isotherm and FTIR analysis  

British Library Electronic Table of Contents (United Kingdom)

The main objective of this work was to investigate the biosorption performance of unmodified and Cetylpyridinium chloride (CPC)-modified biomass of Penicillium YW 01 for Acid Blue 25 (AB 25). Maximum biosorption capacity of AB 25 onto CPC-modified biosorbent was 118.48mgg^-^1 under phosphoric-phosphate buffer with initial dye concentration of 200mgL^-^1 at 30^oC. The biosorption pattern of AB 25 onto unmodified biosorbent in aqueous solution and phosphoric-phosphate buffer was well fitted with both Langmuir and Freundlich isotherm models. While the equilibrium data of CPC-modified biosorbent in aqueous solution and phosphoric-phosphate buffer failed to fit the Freundlich isotherm model, indicating the monolayer biosorption formed onto CPC-modified biosorbent. The values of initial biosorpt...

2011-01-01

334

Biosorption behavior and mechanism of beryllium from aqueous solution by aerobic granule  

British Library Electronic Table of Contents (United Kingdom)

The treatment of Be-contaminated wastewater has been paid little attention, although beryllium (Be) and its compounds are of high toxicity. In this research, aerobic granule was for the first time introduced to remove Be from aqueous solution. Influencing factors including reaction time, initial Be concentration, pH, biosorbent dosage, and coexistent metal ions (Cd, Cu, and Fe) were investigated in batch experiments. The aerobic granule, characterized by element analysis and CLSM, was abundant in carboxyl, phosphoryl, amine and hydroxyl groups. Potentiometric titration experiment demonstrated that the pH effect on biosorption depended on the surface charge of granule (pHzpc=2.4) and the species of Be (Be^2^+, Be(OH)^+, and Be(OH)2) in solution. The coexistent metal ions would either inhibi...

2011-01-01

335

Alkaline treatment of biomass fly ash for reactive dye removal from aqueous solution  

British Library Electronic Table of Contents (United Kingdom)

Biomass fly ash was treated with alkaline solution to enhance its adsorption capacity of Reactive Black 5 dye. The results revealed that the alkaline concentration, solution to fly ash ratio, treatment temperature and treatment time had a positive effect on the dye adsorption capacity of the treated fly ash (TFA), due to dissolving SiO2 and increasing the proportion of unburned carbon. In addition, the dye adsorption behavior of the TFA in aqueous solution was investigated. The effects of various experimental parameters (initial pH, initial dye concentration and contact time) were determined spectrophotometrically. The dye adsorption capacity of the TFA was maximized at an alkaline pH (8.2-10.4). The adsorption capacity of dye by the TFA increased with increasing initial dye concentration....

2010-01-01

336

Adsorption of hexavalent chromium from aqueous solution by using activated red mud  

Energy Technology Data Exchange (ETDEWEB)

Adsorption by activated red mud (ARM) is investigated as a possible alternative to the conventional methods of Cr(VI) removal from aqueous synthetic solutions and industrial effluents. Adsorption characteristics suggest the heterogenous nature of the adsorbent surface sites with respect to the energy of adsorption. Various factors such as pH, contact time, Cr(VI) concentration, amount of adsorbent, and temperature are taken into account, and promising results are obtained. The applicability of the Langmuir as well as Freundlich adsorption isotherms for the present system is tested. The loading factor (i.e., milligrams Cr(VI) adsorbed per gram of ARM) increased with initial Cr(VI) concentration, whereas a negative trend was observed with increasing temperature. The influence of the addition of anions on the adsorption of Cr(VI) depends on the relative affinity of the anions for the surface and the relative concentrations of the anions.

1999-09-01

337

Adsorption of Pb^2^+ and Zn^2^+ from aqueous solutions by sulfured orange peel  

British Library Electronic Table of Contents (United Kingdom)

In this study, sulfured orange peel (MOP) was used as adsorbent to investigate its adsorption behaviors of Pb^2^+ and Zn^2^+ from aqueous solutions. The effects of solution pH, adsorption time and metal ion concentration on adsorption were studied in batch experiments. Both adsorption kinetics of Pb^2^+ and Zn^2^+ proceeded rapidly and could be well described by pesudo-second-order equation. The maximum Langmuir adsorption capacities for Pb^2^+ and Zn^2^+ removal by MOP were evaluated as 164 and 80mg/g, respectively. A binary mixture of Pb^2^+ and Zn^2^+ was studied by using a packed column, suggesting that effective mutual separation and pre-concentration of Pb^2^+ away from Zn^2^+ using MOP could be satisfactory achieved. The results indicate that MOP could be employed as an effective lo...

2011-01-01

338

Acid gas absorption in aqueous solutions of mixed amines  

Energy Technology Data Exchange (ETDEWEB)

A mass transfer model has been developed to describe the rate of absorption (or desorption) of H{sub 2}S and CO{sub 2} in aqueous blends of a tertiary and a secondary or a primary amine. The model is based on penetration theory, and all significant chemical reactions are incorporated in the model. The reactions are taken to be reversible, with reactions involving only a proton transfer considered to be at equilibrium. The particular amines studied in this research were methyldiethanolamine (MDEA), a tertiary amine, and diethanolamine (DEA), a secondary amine. Key physicochemical data needed in the model, such as diffusion coefficients, kinetic rate constants, and gas solubilities, were measured. Experimental absorption rates of CO{sub 2} and H{sub 2}S were measured in a model gas-liquid contacting device and were compared with model predictions. Experiments were carried out for single amine solutions (both MDEA and DEA) and for amine blends.

1996-12-31

339

Absorption of carbon dioxide at high partial pressures in 1-amino-2-propanol aqueous solution. Considerations of thermal effects  

Energy Technology Data Exchange (ETDEWEB)

In the present work, the process of carbon dioxide absorption is analyzed at high partial pressures, in aqueous solutions of 1-amino-2-propanol (monoisopropanolamine (MIPA)), in relation to the thermal effects involved. All experiments were made in a stirred-tank reactor with a plane unbroken gas-liquid interface. The variables considered were the MIPA concentration within the range 0.1--2.0 M and the temperature within the interval 288--308 K. From the results, the authors deduce that the absorption process takes place in the nonisothermal instantaneous regime and propose an equation which not only relates the experimental results of flow density with the initial concentration of amine but at the same time enables the evaluation of the rise in temperature in the gas-liquid interface.

1997-10-01

340

Absorption of CO/sub 2/ in aqueous solutions of mixtures of alkanolamines  

Energy Technology Data Exchange (ETDEWEB)

The bulk removal of CO/sub 2/ from industrial gases is a frequently applied process in the field of gas-treating. Usually chemical solvents are used in order to increase both the solvent-loading capacity and the absorption rate. These solvents often are aqueous solutions of alkanolamines. The loaded-liquid is regenerated at high temperatures with the aid steam. In the present study absorption rates are experimentally determined in various mixtures of amines over a wide range of concentrations. Simultaneously, a model was developed for the description of mass transfer accompanied by parallel reversible chemical reactions. The equations of this mass transfer model could not be solved analytically and therefore numerical techniques were used to obtain an exact description of this process. This model also includes the asymptotic situations of homogeneous catalysts and shuttle mechanism for which in the literature several approximate solutions have been presented. The ...

1988-01-01

341

ASPEN simulation of environmental control processes: Final report  

Energy Technology Data Exchange (ETDEWEB)

The United States Department of Energy (DOE) at the Morgantown Energy Technology Center (METC) contracted with P.S. Lowell and Co. Inc. (Lowell and Co.) and Jay S. Dweck, Consultant, Inc., (JSD) to enhance the capability of ASPEN in simulating coal gasification and oil shale processing plants. Of particular concern was the capability to predict the distribution of environmentally significant components among the various aqueous and organic liquids and gas streams within or leaving the process. The project was divided into major task areas. The first was to develop and implement the calculational routines necessary for predicting aqueous electrolyte chemical reactions. Part of this effort also was to select a species list and collect and/or regress data for the necessary parameters. The second task was to develop and implement a multi-phase flash capability (including precipitated solids) and unit operations models for a venturi and a ...

1988-04-01

342

A novel graphene nanosheets coated stainless steel fiber for microwave assisted headspace solid phase microextraction of organochlorine pesticides in aqueous samples followed by gas chromatography with electron capture detection  

British Library Electronic Table of Contents (United Kingdom)

In this study, a novel graphene nanosheets (GNSs) coated solid phase microextraction (SPME) fiber was prepared by immobilizing microwave synthesized GNSs on a stainless steel wire. Microwave synthesized GNSs were verified by X-ray diffraction, field emission-scanning electron microscopy (FE-SEM) and transmission electron microscope (TEM). GNS-SPME fiber was characterized using FE-SEM and the results showed the GNS coating was homogeneous, porous, and highly adherent to the surface of the stainless steel fiber. The performance and feasibility of the GNS-SPME fiber was evaluated under one-step microwave assisted (MA) headspace (HS) SPME followed by gas chromatography with electron capture detection for five organochlorine pesticides (OCPs) in aqueous samples. Parameters influencing the extra...

2011-01-01

343

A new approach of the understanding of sulfur dioxide reduction in non-aqueous solvent; Une nouvelle approche de la comprehension de la reduction du dioxyde de soufre en solvant non aqueux  

Energy Technology Data Exchange (ETDEWEB)

The study of SO{sub 2} reduction in non-aqueous solvent can help to understand the functioning of Li/SO{sub 2} batteries and to find a simpler way for the synthesis of Li{sub 2}S{sub 2}O{sub 4} dithionite. This paper presents the results of electrochemical studies (cycle volt-amperometry in semi-infinite and thin film diffusion conditions, visible spectro-electrochemistry) and spectroscopic studies (UV, visible and RPE) performed on SO{sub 2} solutions. A mechanism of SO{sub 2} reduction is proposed and discussed. (J.S.) 18 refs.

1996-12-31

344

A Computer Simulation of the Electronic Structure of Leucine in Aqueous Solution  

British Library Electronic Table of Contents (United Kingdom)

In order to obtain the electronic structure of leucine (Leu) in aqueous solution, we studied three systems: Leu+7H2O, Leu+8H2O and Leu+9H2O. The results indicated that the system Leu+8H2O was the only choice which was both acceptable and doable: its computational effort was affordable, and it could simulate a main part of the solvent effect on the electronic structure of Leu in solution. Based on the system Leu+8H2O, all-electron, ab initio calculations were performed to construct an equivalent potential of water for the electronic structure of Leu with dipoles. The results showed that the main effect of water on the electronic structure of Leu was raising the occupied states about 0.0824 Ry on average, and broadening the energy gap by 11%. The water effect on the electronic structure of L...

2011-01-01

345

Tumor vascular permeability factor stimulates endothelial cell growth and angiogenesis.  

UK PubMed Central (United Kingdom)

Vascular permeability factor (VPF) is an Mr 40-kD protein that has been purified from the conditioned medium of guinea pig line 10 tumor cells grown in vitro, and increases fluid permeability from blood...Full Text Available

1989-11-01

346

Transmural distribution of extracellular purines in isolated guinea pig heart.  

UK PubMed Central (United Kingdom)

The purine adenosine appears to be involved in regulation of coronary vascular tone. Little is known concerning the levels and distribution of adenosine and related purines in the extracellular fluid...Full Text Available

1991-01-15

347

Time-dependent, finite, rotating universes  

International Nuclear Information System (INIS)

Three new classes of finite, homogeneous and nonsingular solutions of Einstein's equations which have time-dependent expansion, shear and rotation are presented. The t-constant sections are of Bianchi type IX. The source of these geometries is a fluid which has not been thermalized. (Author).

348

Time-dependent, Bianchi II, rotating universe  

International Nuclear Information System (INIS)

An exact cosmological solution of Einstein's equations which has time-dependent rotation is presented. The t-constant sections are of Bianchi type II. The source of this geometry is a fluid which has not been thermalized. (Author).

2006-11-03

349

Three-dimensional mise-a-la-masse modeling using horizontal well; Suihei kosei wo mochiita ryuden den`iho no sanjigen modeling  

Energy Technology Data Exchange (ETDEWEB)

The 3-D model program was developed to apply a mise-a-la-masse method to linear current sources with optional shapes. Mise-a-la-masse method is a bipolar mapping survey method using current sources installed in wells, and recently has been widely used for direct exploration of geothermal reservoirs. This method is also used for monitoring underground fluid as electrode arrangement of fluid flow tomography for surveying underground fluid (geothermal fluid, underground water, petroleum). In the geothermal reservoir exploration, the casing pipes of wells are used as linear current sources, and measured data are processed as those based on vertical current source. In the largely inclined well, the inclination of current sources should be considered. The 3-D modeling program was developed by difference calculus using the theoretical potential equation and apparent resistivity based on linear current sources ...

1996-10-01

350

The Effect of Age on the Gingival Crevicular Fluid Composition During Experimental Gingivitis. A Pilot Study  

UK PubMed Central (United Kingdom)

Background:Cytokines have been proposed as potentially useful diagnostic or prognostic markers of periodontal inflammation related alterations during the experimental gingivitis...Full Text Available

351

The Correlation and Accuracy of Glucose Levels between Interstitial Fluid and Venous Plasma by Continuous Glucose Monitoring System  

UK PubMed Central (United Kingdom)

BackgroundClinical experience with the continuous glucose monitoring systems (CGMS) is limited in Korea. The objective of this study is to evaluate the accuracy of the CGMS and the...Full Text Available

2010-12-01

352

Surfactant protein A, an innate immune factor, is expressed in the vaginal mucosa and is present in vaginal lavage fluid  

UK PubMed Central (United Kingdom)

Surfactant protein A (SP-A), first identified as a component of the lung surfactant system, is now recognized to be an important contributor to host defence mechanisms. SP-A can facilitate phagocytosis...Full Text Available

2004-01-01

353

Sulfate Reduction by a Desulfovibrio Species Isolated from Sheep Rumen1  

UK PubMed Central (United Kingdom)

Several dissimilatory, sulfate-reducing bacteria were isolated from the rumen fluid of sheep fed purified diets containing sulfate. One isolate, strain D, was selected for characterization. This organism...Full Text Available

1974-09-01

354

Structure of lipid bilayers  

UK PubMed Central (United Kingdom)

The quantitative experimental uncertainty in the structure of fully hydrated, biologically relevant, fluid (Lα) phase lipid bilayers has been too large to...Full Text Available

2000-11-10

355

Specificity of the anticollagenase action of tetracyclines: relevance to their anti-inflammatory potential.  

UK PubMed Central (United Kingdom)

The concentrations of doxycycline and 4-de-dimethylaminotetracycline required to inhibit 50% of collagenase activity were found to be 15 to 30 microM for human neutrophil and gingival crevicular fluid...Full Text Available

1992-01-01

356

Reinfusion of ascites during hemodialysis as a treatment of massive refractory ascites and acute renal failure  

UK PubMed Central (United Kingdom)

Refractory ascites can occur in patients with various conditions. Although several procedures based on the reinfusion of ascitic fluid have been reported after the failure of bed rest, salt and water...Full Text Available

357

Regulation of hyaluronan secretion into rabbit synovial joints in vivo by protein kinase C  

UK PubMed Central (United Kingdom)

Hyaluronan (HA) is important for joint cavitation, lubrication, volume regulation and synovial fluid drainage but little is known about the regulation of joint HA synthesis/secretion in vivo....Full Text Available

2003-07-15

358

Rapid aneuploidy detection with multiplex ligation-dependent probe amplification: a prospective study of 4000 amniotic fluid samples  

UK PubMed Central (United Kingdom)

The introduction of prenatal screening requires rapid high-throughput diagnosis of common aneuploidies. Multiplex ligation-dependent probe amplification (MLPA) allows for quick, easily automated multiplex...Full Text Available

2009-01-01

359

Prediction of critical properties of mixtures from the PRSV-2 equation of state: A correction for predicted critical volumes  

Energy Technology Data Exchange (ETDEWEB)

Critical properties of a fluid or fluid mixtures are important for describing fluid phase behavior, predicting physical properties, developing equations of state, and designing supercritical-fluid extraction processes, and compression and refrigeration units. The predictive capability of the Peng-Robinson-Styjek-Vera (PRSV-2) equation of state (1986) for critical properties of binary mixtures was investigated. The procedure adopted by Heidemann and Khalil (1980) and discussed by Abu-Eishah et al. (1998) was followed. An optimized value for the binary interaction parameter based on minimization of error between experimental and predicted critical temperatures was used. The standard and the average of the absolute relative deviations in critical properties are included. The predicted critical temperature and pressure for several nonpolar and polar systems agree well with experimental data and are always ...

1999-09-01

360

Poisonous snakebite in central Texas. Possible indicators for antivenin treatment.  

UK PubMed Central (United Kingdom)

Sixty-seven patients hospitalized for poisonous snakebite between 1975 and 1990 were managed by elevation, tetanus prophylaxis, intravenous fluids and antibiotics, and often by a limited excision of...Full Text Available

1991-05-01

361

Plasma Treatment within Dielectric Fluids.  

Science.gov (United States)

A dielectric liquid having entrained bubbles of gas or vapor is subjected to an electric field applied between spaced electrodes (112, 116) which generates microdischarges (and thus plasma) within the bubbles, allowing modification of the properties of th...

2003-01-01

362

Numerical simulations of industrial processes involving fluid dynamics, combustion and radiation  

Energy Technology Data Exchange (ETDEWEB)

Moving out of the scientific community research laboratories, computational fluid dynamics (CFD) software packages are now allowing industrials to analyse and optimize industrial processes involving the use of gases, liquids and even some two-phase fluids. Their attractiveness and their impact stems out from the opportunity they offer to bring insight into an existing unit, or even at the design stage, by displaying the spatial distribution of process relevant variables such as temperature, concentration. The filling of the spacing in between a two-layer window is a simple example. This new opportunity of visualisation is at times an unique way, when the process environment is an opaque one, such as liquid metal flowing into a tundish or when measurements of flows may be a long and tedious work, such as flows within water treatment basins. This environment we are to investigate in order to optimize can also be a harsh one, due to its high ...

1997-12-31

363

Numerical modeling of slug flow initiation in a horizontal channels using a two-fluid model  

International Nuclear Information System (INIS)

This paper presents a methodology for modeling slug initiation and growth in horizontal ducts. Transient two-fluid equations are solved numerically using a class of high-resolution shock capturing methods. The advantage of this method is that slug formation and growth in a stratified regime can be calculated directly from the solutions to the flow field differential equations. In addition, by using high-resolution shock capturing methods that do not contain numerical diffusion, the discontinuity generated by slugging in the flow field can be modeled with good accuracy. The two-fluid model is shown to be well-posed mathematically only under certain conditions. Under these circumstances, the two-fluid model is capable of correctly predicting and modeling the flow physics. When ill-posed, an unbounded instability occurs in the flow field solution, and the instability amplitude increases exponentially with decreasing mesh ...

2011-02-01

364

MULTITARGETED THERAPY OF CANCER BY GREEN TEA POLYPHENOLS  

UK PubMed Central (United Kingdom)

Tea ranks second only to water as a major component of fluid intake worldwide and has been considered a health-promoting beverage since ancient times. For the past two decades, we and others...Full Text Available

2008-10-08

365

Legionella tucsonensis sp. nov. isolated from a renal transplant recipient.  

UK PubMed Central (United Kingdom)

A Legionella-like organism (strain 1087-AZ-H) was isolated from a pleural-fluid specimen from a renal transplant patient undergoing immunosuppressive therapy. Growth characteristics and gas-liquid chromatography...Full Text Available

1989-08-01

366

Interactive Cytokine Regulation of Synoviocyte Lubricant Secretion  

UK PubMed Central (United Kingdom)

Cytokine regulation of synovial fluid (SF) lubricants, hyaluronan (HA), and proteoglycan 4 (PRG4) is important in health, injury, and disease of synovial joints, and may also provide powerful regulation...Full Text Available

2010-04-01

367

In-vivo coronary flow profiling based on biplane angiograms: influence of geometric simplifications on the three-dimensional reconstruction and wall shear stress calculation  

UK PubMed Central (United Kingdom)

BackgroundClinical studies suggest that local wall shear stress (WSS) patterns modulate the site and the progression of atherosclerotic lesions. Computational fluid dynamics (CFD)...Full Text Available

368

Immunoradiometric measurement of the factor VIII procoagulant antigen.  

UK PubMed Central (United Kingdom)

A fluid-phase immunoradiometric assay has been developed which identifies an antigen on the Factor VIII (antihemophilic factor) procoagulant protein. This sensitive and quantitative assay is not influenced...Full Text Available

1978-11-01

369

Hyperoxia enhances VEGF release from A549 cells via post-transcriptional processes  

UK PubMed Central (United Kingdom)

Exposure of animals to hyperoxia decreases lung VEGF mRNA expression concomitant with an acute increase in VEGF protein within the epithelial lining fluid (ELF). The VEGF concentration in ELF...Full Text Available

2007-09-01

370

Hydrodynamic studies of post dryout two-phase downflow in narrow channels  

Energy Technology Data Exchange (ETDEWEB)

An experimental study of the hydrodynamics of a narrow channel was performed in order to obtain the heat transfer mechanisms and influences contributing to the flow regime transition from inverted annular to inverted slug flows for post dryout downflow. The experimental series consisted of both adiabatic and diabatic visualization tests over a wide range of fluid and thermal parameters. The system inlet gas velocities ranged from 0 to 14 meters per second while the inlet fluid velocities ranged from 1 to 3 meters per second. Full extent visualization of the flow regime was possible due to a quartz tube in tube construction with a clear heating fluid. Constant temperature heating of the freon was accomplished at bulk fluid temperatures above the critical heat flux temperature. For each hydrodynamic flow condition, one to three minuets of VHS-video filming was performed to acquire both flow regime and ...

1995-07-01

371

High Shear Stress at the Surface of Enhancing Plaque in the Systolic Phase is Related to the Symptom Presentation of Severe M1 Stenosis  

UK PubMed Central (United Kingdom)

The computational fluid dynamics methods for the limited flow rate and the small dimensions of an intracranial artery stenosis may help demonstrate the stroke mechanism in intracranial atherosclerosis....Full Text Available

2011-07-01

372

Functional properties of membrane cofactor protein of complement.  

UK PubMed Central (United Kingdom)

Membrane cofactor protein (MCP or gp45-70) of the complement system is a cofactor for factor I-mediated cleavage of fluid-phase C3b and C3b-like C3, which opens the thioester bond. In the present study...Full Text Available

1989-12-01

373

Experimental evaluation of a non-azeotropic working fluid for geothermal heat pump system  

Energy Technology Data Exchange (ETDEWEB)

Geothermal energy resources are found in many countries. A reasonable and efficient utilization of these resources has been a worldwide concern. The application of geothermal heat pump systems (GHPS) can help increase the efficiency of using geothermal energy and reduce the thermal pollution to the earth surface. However, this is only possible with a proper working fluid. In this paper, a non-azeotropic working fluid (R290/R600a/R123) is presented for a GHPS where geothermal water at 40-45{sup o}C and heating network water at 70-80{sup o}C serve as the low and high temperature heat sources. Experimental results show that the coefficient of performance (COP) of a GHPS using the working fluid is above 3.5 with the condensation temperature above 80{sup o}C and the condensation pressure below 18 bar, while the temperature of the geothermal water is reduced from 40-46{sup o}C to 31-36{sup o}C. (author)

2004-06-01

374

Experimental evaluation of a non-azeotropic working fluid for geothermal heat pump system  

International Nuclear Information System (INIS)

Geothermal energy resources are found in many countries. A reasonable and efficient utilization of these resources has been a worldwide concern. The application of geothermal heat pump systems (GHPS) can help increase the efficiency of using geothermal energy and reduce the thermal pollution to the earth surface. However, this is only possible with a proper working fluid. In this paper, a non-azeotropic working fluid (R290/R600a/R123) is presented for a GHPS where geothermal water at 40-45 deg. C and heating network water at 70-80 deg. C serve as the low and high temperature heat sources. Experimental results show that the coefficient of performance (COP) of a GHPS using the working fluid is above 3.5 with the condensation temperature above 80 deg. C and the condensation pressure below 18 bar, while the temperature of the geothermal water is reduced from 40-46 deg. C to 31-36 deg. C.

2004-06-01

375

Endothelin-1 Is Increased in Cerebrospinal Fluid and Associated with Unfavorable Outcomes in Children after Severe Traumatic Brain Injury  

UK PubMed Central (United Kingdom)

AbstractSevere pediatric traumatic brain injury (TBI) is associated with unfavorable outcomes secondary to injury from activation of the inflammatory cascade, the release of excitotoxic...Full Text Available

2010-10-01

376

Effects of cyclooxygenase inhibitors on the alterations in lung mechanics caused by endotoxemia in the unanesthetized sheep.  

UK PubMed Central (United Kingdom)

The effects of Escherichia coli endotoxin on lung mechanics, hemodynamics, gas exchange, and lung fluid and solute exchange were studied in 12 chronically instrumented unanesthetized sheep. A possible...Full Text Available

1983-07-01

377

Effect of surface-perturbed intermolecular interaction on adsorption of simple gases on a graphitized carbon surface.  

Science.gov (United States)

In this paper, we investigate the effect of the solid surface on the fluid-fluid intermolecular potential energy. This modified fluid-fluid interaction energy due to the inducement of a solid surface is used in the grand canonical Monte Carlo (GCMC) simulation of various noble gases, nitrogen, and methane on graphitized thermal carbon black. This effect is such that the effective interaction potential energy between two particles close to surface is less than the potential energy if the solid substrate is not present. With this modification the GCMC simulation results agree extremely well with the experimental data over a wide range of pressures while the simulation results with the unmodified potential energy give rise to a shoulder near the neighborhood of monolayer coverage and the significant overprediction of the second and higher layer coverages. In particular the unmodified GCMC results exhibit very sharp change in those higher layers ...

2004-08-31

378

Dosing Recommendations for Continuous Venovenous Hemodiafiltration with AN69 Filter Membranes and Prismaflex Dialyzers  

UK PubMed Central (United Kingdom)

Background:Continuous renal replacement therapy is used to manage fluid and solute imbalances in critically ill patients but may affect the clearance of concurrently administered...Full Text Available

2009-11-01

379

Differential expression of Haemophilus parasuis genes in response to iron restriction and cerebrospinal fluid  

UK PubMed Central (United Kingdom)

Haemophilus parasuis is an important opportunistic pathogen in swine of high health status, but to date no proven virulence factors have been described. As virulence factors are known...Full Text Available

2007-07-01

380

Detection of Sub-Clinical CWD Infection in Conventional Test-Negative Deer Long after Oral Exposure to Urine and Feces from CWD+ Deer  

UK PubMed Central (United Kingdom)

BackgroundChronic wasting disease (CWD) of cervids is a prion disease distinguished by high levels of transmissibility, wherein bodily fluids and excretions are thought to play an...Full Text Available

381

Consistency in potency assay of tetanus toxoid in mice  

UK PubMed Central (United Kingdom)

The use of mice for the assay of tetanus toxoids would offer considerable advantages over the use of guinea-pigs, but mice cannot readily be immunized with the fluid tetanus toxoid at present designated...Full Text Available

1959-01-01

382

Chemical refining of coal (Report on ECSC contract 7220-EC/816)  

Energy Technology Data Exchange (ETDEWEB)

Three areas have been investigated: coal liquefaction with supercritical fluids, liquefaction by extraction with high boiling liquid solvents, and the production of resins from coal-derived hydrocarbons. The processes are described.

1983-01-01

383

Changes in inflammatory mediators in experimental periodontitis in the rhesus monkey.  

UK PubMed Central (United Kingdom)

Ligature-induced periodontitis was monitored for 6 months in eight Macaca mulatta monkeys to examine clinical status, radiographic bone level, and crevicular fluid (CF) levels of prostaglandin E2 (PGE2),...Full Text Available

1993-04-01

384

Cerebrospinal fluid zinc concentrations in febrile convulsions.  

UK PubMed Central (United Kingdom)

Zinc modulates the activity of glutamic acid decarboxylase, the rate limiting enzyme in the synthesis of gamma-aminobutyric acid (GABA), which is a major inhibitory neurotransmitter. Low cerebrospinal...Full Text Available

1995-10-01

385

CXCL12-Mediated Guidance of Migrating Embryonic Stem Cell-Derived Neural Progenitors Transplanted into the Hippocampus  

UK PubMed Central (United Kingdom)

Stem cell therapies for neurodegenerative disorders require accurate delivery of the transplanted cells to the sites of damage. Numerous studies have established that fluid injections to the hippocampus...Full Text Available

386

Biopersistence of nonfibrous mineral particles in the respiratory tracts of subjects following occupational exposure.  

UK PubMed Central (United Kingdom)

Transmission electron microscopy analysis (TEMA) was used to analyze the bronchoalveolar lavage fluid (BALF) of 262 subjects occupationally exposed (OE) to nonfibrous mineral particles (NFMP) and 42...Full Text Available

1994-10-01

387

Analyses of mixed-hydrocarbon binary thermodynamic cycles for moderate-temperature geothermal resources using regeneration techniques  

Energy Technology Data Exchange (ETDEWEB)

Studies of basic binary geothermal cycles utilizing mixtures of hydrocarbons have shown better performance than for pure fluids for a moderate temperature (360/sup 0/F) resource. However, a loss is net geofluid effectiveness (watt-hours net plant output/1bm geofluid) results when the geofluid outlet temperature is limited to temperatures in excess of 160/sup 0/F to alleviate a silica precipitation problem. This study examined three working fluids consisting of binary mixtures of hydrocarbons to see if use of regenerative preheating techniques such as turbine exhaust recupation and/or turbine bleed could recover the loss in geofluid effectiveness for a 160/sup 0/F geofluid outlet temperature. Results showed that with the most promising of the three working fluids a turbine exhaust recuperator alone is sufficient to recover all the lost effectiveness while maintaining the geofluid outlet temperature at 160/sup 0/F. A brief ...

1981-12-01

388

Analyses of mixed-hydrocarbon binary thermodynamic cycles for moderate-temperature geothermal resources  

Energy Technology Data Exchange (ETDEWEB)

A number of binary geothermal cycles utilizing mixed hydrocarbon working fluids were analyzed with the overall objective of finding a working fluid which can produce low-cost electrical energy using a moderately-low temperature geothermal resource. Both boiling and supercritical shell-and-tube cycles were considered. The performance of a dual-boiling isobutane cycle supplied by a 280/sup 0/F hydrothermal resource (corresponding to the 5 MW pilot plant at the Raft River site in Idaho) was selected as a reference. To investigate the effect of resource temperature on the choice of working fluid, several analyses were conducted for a 360/sup 0/F hydrothermal resource, which is representative of the Heber resource in California. The hydrocarbon working fluids analyzed included methane, ethane, propane, isobutane, isopentane, hexane, heptane, and mixtures of those pure hydrocarbons. For comparison, two ...

1981-02-01

389

Analyses of mixed hydrocarbon binary thermodynamic cycles for moderate temperature geothermal resources using regeneration techniques  

Energy Technology Data Exchange (ETDEWEB)

Studies have shown that binary geothermal cycles utilizing mixed-hydrocarbon working fluids can result in better performance than those utilizing pure fluids for moderate temperature (360F) resources. However, a loss in net geofluid effectiveness results when the geofluid outlet is limited to temperatures in excess of 160F to alleviate potential silica precipitation. This study examined three mixed-hydrocarbon working fluids to see if use of regenerative preheating techniques such as turbine exhaust recuperation and/or turbine bleed could recover this loss. Results showed that with the most promising of the three working fluids, a turbine-exhaust recuperator alone is sufficient to recover all the lost effectiveness while maintaining the geofluid outlet temperature at 160F. A brief study to investigate cold weather operation with the recuperator showed no major detrimental response of the system; ...

1982-08-01

390

Activation of peripheral blood mononuclear cells in bronchoalveolar lavage fluid from patients with sarcoidosis: visualisation of single cell activation products.  

UK PubMed Central (United Kingdom)

BACKGROUND--Interstitial lung diseases are characterised by the recruitment of mononuclear cells to disease sites where maturation occurs and activation products, including lysozyme (LZM), are released....Full Text Available

1994-11-01

391

A study of light hydrocarbons (C{sub 4}-C{sub 1}3) in source rocks and petroleum fluid  

Energy Technology Data Exchange (ETDEWEB)

This thesis consists of an introduction and five included papers. Of these, four papers are published in international journals and the fifth was submitted for review in April 2000. Emphasis has been placed on both naturally and artificially generated light hydrocarbons in petroleum fluids and their proposed source rocks as well as direct application of light hydrocarbons to oil/source rock correlations. Collectively, these papers describe a strategy for interpreting the source of the light hydrocarbons in original oils and condensates as well as the source of the asphaltene fractions from the reservoir fluids. The influence of maturity on light hydrocarbon composition has also been evaluated. The papers include (1) compositional data on the light hydrocarbons from thermal extracts and kerogen pyrolysates of sediment samples, (2) light hydrocarbon data of oils and condensates as well as the pyrolysis products of the asphaltenes from these ...

2000-07-01

392

A non-invasive technique for standing surgical repair of urinary bladder rupture in a post-partum mare: a case report  

UK PubMed Central (United Kingdom)

An 11-year-old mare presented 36 hours after foaling with a ruptured bladder. Uroperitoneum was diagnosed on ultrasound and from the creatinine concentration of the peritoneal fluid. Bladder endoscopy...Full Text Available

393

4 - NASA Technical Reports Server  

Science.gov (United States)

Mar 1, 2011 ... The movement of hydrothermal fluids and/or fumarolic vapors through local rocks prior ... The Solar Energetic Particle Event of December 14, 2006 .... for measurement of non-precipitating cloud hydrometeors and aerosols, ...

394

Use of the K88 antigen for in vivo bacterial competition with porcine strains of enteropathogenic Escherichia coli.  

Science.gov (United States)

Infant mice were used to measure the amount of fluid accumulation (enterosorption) in the intestinal tract after oral inoculation of a porcine strain of enteropathogenic Escherichia coli (K88-+, Ent-+). Significant reduction in the amount of fluid found in the intestinal tract was observed if the mice were first inoculated with a K88-possessing, non-enterotoxigenic strain of E. coli. The protection provided is thought to be due to specific competition for attachment sites on cells of the small intestine. PMID:1095492

1975-07-01

395

Simulation of Pulsed Neutron Activation using a CFD code  

International Nuclear Information System (INIS)

Tests for the applicability of a CFD (Computational Fluid Dynamics) code for simulating activity transport in PNA (Pulsed Neutron Activation) fluid measurements have been performed. The CFD code was combined with a Monte Carlo code used for the calculation of the initial activity distribution. The results from the calculations show that it is possible to use CFD for calculation of the activity distribution in PNA. The mainly qualitative results in this work are encouraging and suggest further work. In the continuation of this work a response function for the gamma detector will be calculated so that a PNA time spectrum can be simulated. A more accurate comparison with experimental data can then be performed

2008-09-14

396

Report of the Fluid Dynamics Panel Working Group 10 on calculation of 3D separate turbulent flows in boundary layer limit  

Science.gov (United States)

The results of a study conducted by Working Group 10 of the AGARD Fluid Dynamics Panel to investigate the limits of boundary layer methods, both the integral and field type formulations, for calculating three-dimensional turbulent separated flow are presented. Test cases used to assess the boundary layer calculations included the DFLVR prolate spheroid at angle of attack and the NASA-Ames Wing C. Comparisons between boundary layer calculations and experimental data are presented for these test cases along with observations, conclusions, and recommendations.

1990-05-01

397

Peristaltic flow of a couple stress fluid under the effect of induced magnetic field in an asymmetric channel  

Energy Technology Data Exchange (ETDEWEB)

The present paper investigates the peristaltic transport of a couple stress fluid in an asymmetric channel with the effect of the induced magnetic field. The exact solutions of momentum and the magnetic field equations have been calculated under the assumptions of long wave length and low but finite Reynolds number. The expression for pressure rise has been computed numerically using mathematics software Mathematica. The graphical results have been presented to discuss the physical behavior of various physical parameters of interest. Finally, the trapping phenomena have been discussed for various physical parameters. (orig.)

2011-01-15

398

Peristaltic flow of a couple stress fluid under the effect of induced magnetic field in an asymmetric channel  

British Library Electronic Table of Contents (United Kingdom)

The present paper investigates the peristaltic transport of a couple stress fluid in an asymmetric channel with the effect of the induced magnetic field. The exact solutions of momentum and the magnetic field equations have been calculated under the assumptions of long wave length and low but finite Reynolds number. The expression for pressure rise has been computed numerically using mathematics software Mathematica. The graphical results have been presented to discuss the physical behavior of various physical parameters of interest. Finally, the trapping phenomena have been discussed for various physical parameters.

2011-01-01

399

Peristaltic flow of a couple stress fluid in an annulus: Application of an endoscope  

Science.gov (United States)

This paper discusses the influence of an endoscope on the peristaltic flow of a couple stress fluid in an annulus under a zero Reynolds number and long wavelength approximation. The inner tube is uniform, rigid, while the outer tube has a sinusoidal wave traveling down its wall. Analytical expressions for the axial velocity, stream function and axial pressure gradient are established. The flow is investigated in a wave frame of reference moving with the velocity of the wave. Numerical calculations are carried out for the pressure rise, frictional forces and trapping. The features of the flow characteristics are analyzed by plotting graphs and discussed in detail.

2008-04-01

400

Organometallic Polymer Coatings for Geothermal-Fluid-Sprayed Air-Cooled Condensers: Preprint  

Energy Technology Data Exchange (ETDEWEB)

Researchers are developing polymer-based coating systems to reduce scaling and corrosion of air-cooled condensers that use a geothermal fluid spray for heat transfer augmentation. These coating systems act as barriers to corrosion to protect aluminum fins and steel tubing; they are formulated to resist the strong attachment of scale. Field tests have been done to determine the corrosion and scaling issues related to brine spraying and a promising organometallic polymer has been evaluated in salt spray tests.

2002-08-01

401

Modeling of feed water check valves using RELAP5; Modellierung von Speisewasserrueckschlagventilen in RELAP5  

Energy Technology Data Exchange (ETDEWEB)

Westinghouse Electric Germany GmbH has developed fluid dynamic models for medium-actuated armatures using the thermal hydraulic code RELAP5 in order to reach a more realistic description of the armature behavior including fluid-structure interactions in case of transient flow conditions in piping systems. The contribution is concerned with the modeling of damped check valves. The model allows the description of the behavior during opening and closure of a check armature. The calculated results show good agreement with the available measured data.

2009-07-01

402

Magneto thermal convection in a compressible couple-stress fluid  

Energy Technology Data Exchange (ETDEWEB)

The problem of thermal instability of compressible, electrically conducting couple-stress fluids in the presence of a uniform magnetic field is considered. Following the linearized stability theory and normal mode analysis, the dispersion relation is obtained. For stationary convection, the compressibility, couple-stress, and magnetic field postpone the onset of convection. Graphs have been plotted by giving numerical values of the parameters to depict the stability characteristics. The principle of exchange of stabilities is found to be satisfied. The magnetic field introduces oscillatory modes in the system that were non-existent in its absence. The case of overstability is also studied wherein a sufficient condition for the non-existence of overstability is obtained. (orig.)

2010-03-15

403

Industrial processing of complex fluids: Formulation and modeling  

Energy Technology Data Exchange (ETDEWEB)

The production of many important commercial materials involves the evolution of a complex fluid through a cooling phase into a hardened product. Textile fibers, high-strength fibers(KEVLAR, VECTRAN), plastics, chopped-fiber compounds, and fiber optical cable are such materials. Industry desires to replace experiments with on-line, real time models of these processes. Solutions to the problems are not just a matter of technology transfer, but require a fundamental description and simulation of the processes. Goals of the project are to develop models that can be used to optimize macroscopic properties of the solid product, to identify sources of undesirable defects, and to seek boundary-temperature and flow-and-material controls to optimize desired properties.

1997-08-01

404

Heat generation of magneto-rheological fluid dampers  

Science.gov (United States)

This study presents a theoretical analysis of heat generation and dissipation of field-controllable magneto-rheological fluid (MRF) shock absorbers. Since MRF dampers are energy- dissipating devices, the issues of heat generation and dissipation are important in predicting their performance. A theoretical model is developed based on Bingham plastic model to estimate temperature history of the MRF dampers. The governing equation includes the MRF viscosity as a function of the temperature. The numerical solutions are compared with experimental results in order to validate the accuracy of the model, and excellent agreements are obtained.

2000-04-01

405

Experimental study on fuzzy logic vibration control of a bridge using fail-safe magnetorheological fluid dampers  

Science.gov (United States)

This study presents a semi-active vibration control of a scaled two-span bridge structure. Magneto-rheological fluid dampers are utilized as the semi-active energy absorbing devices, and a bridge vibration control system is developed. Closed-loop control system based on fuzzy logic is used to suppress the bridge deck motion under random excitation. It is demonstrated that this fuzzy logic control system can significantly reduce the relative deck displacement using about 60% less power compared to passive on state, while the absolute deck acceleration remains practically unchanged.

2001-07-01

406

Core preservation with a laminated, heat-sealed package  

Energy Technology Data Exchange (ETDEWEB)

A core preservation package was developed to maintain the reservoir characteristics of core samples and consequently to improve the quality of data obtained through laboratory core analyses. The package is a heat-sealable plastic-aluminum laminate similar to those common in the food-packaging industry. The laminated core preservation package acts as an impermeable barrier to water vapor and gases, and is resistant to chemical alteration and degradation by core fluids. These performance characteristics result in effective core preservation by maintaining the fluid content of the core. Other advantages of the laminated package are that it is fast and simple to use and eliminates the cumbersome dip-coat step used in some core preservation methods.

1988-12-01

407

Convection in the cavity between two rollers: The effect of thermal boundary conditions  

Energy Technology Data Exchange (ETDEWEB)

In this study the authors examine the convective cooling provided by fluid trapped in the cavity between two consecutive rollers in a roller bearing. In order to calculate the steady-state temperature of the roller, the designer must know nor only the rolling-contact heat input received by the roller but also the convection cooling effect of the surrounding fluid. Until recently, this lateral convection cooling effect was modeled by assuming a certain (constant) heat transfer coefficient h at the roller surface, and then calculating the steady-state temperature distribution around the roller.

1991-02-01

408

An investigation of turbulent convection heat transfer performance in spiral spring coil inserted tubes  

International Nuclear Information System (INIS)

This paper presents the results of the experimental investigation on heat transfer and fluid friction characteristics of a class of spiral spring coil used as a tube side forced convection heat transfer augmentation devices. Based on a lot of experimental data, the heat transfer correlation and fluid friction correlation revised by temperature were reached in terms of linear regression. At the same time, proper criteria were used to evaluate the economic performance of the spiral spring inserted tube according to the demand of practical application and some probing analysis were made.

1996-01-01

409

State-of-the-art review of computational fluid dynamics modeling for fluid-solids systems  

Energy Technology Data Exchange (ETDEWEB)

As the result of 15 years of research (50 staff years of effort) Argonne National Laboratory (ANL), through its involvement in fluidized-bed combustion, magnetohydrodynamics, and a variety of environmental programs, has produced extensive computational fluid dynamics (CFD) software and models to predict the multiphase hydrodynamic and reactive behavior of fluid-solids motions and interactions in complex fluidized-bed reactors (FBRS) and slurry systems. This has resulted in the FLUFIX, IRF, and SLUFIX computer programs. These programs are based on fluid-solids hydrodynamic models and can predict information important to the designer of atmospheric or pressurized bubbling and circulating FBR, fluid catalytic cracking (FCC) and slurry units to guarantee optimum efficiency with minimum release of pollutants into the environment. This latter issue will become of paramount importance with the enactment of the ...

1994-05-12

410

Metal Nanoparticles Preparation In Supercritical Carbon Dioxide Solutions  

Energy Technology Data Exchange (ETDEWEB)

The novel optical, electronic, and/or magnetic properties of metal and semiconductor nanoparticles have resulted in extensive research on new methods for their preparation. An ideal preparation method would allow the particle size, size distribution, crystallinity, and particle shape to be easily controlled, and would be applicable to a wide variety of material systems. Numerous preparation methods have been reported, each with its inherent advantages and disadvantages; however, an ideal method has yet to emerge. The most widely applied methods for nanoparticle preparation include the sonochemical reduction of organometallic reagents,(1&2) the solvothermal method of Alivisatos,(3) reactions in microemulsions,(4-6) the polyol method (reduction by alcohols),(7-9) and the use of polymer and solgel materials as hosts.(10-13) In addition to these methods, there are a variety of methods that take advantage of the unique properties of a supercritical fluid.(14&15) ...

2004-04-01

411

Comparative adequacy of conventional radiography, ultrasonography and Computed Tomography in twenty-six consecutive patients with acute superior mesenteric ischemia  

International Nuclear Information System (INIS)

Ischemic bowel disease is a rare disorder whose incidence is increasing as the mean age of the population increases. Diagnosis by clinical, laboratory and radiologic means is often difficult, and delay in definitive therapy results in substantial morbidity and mortality. A series of 26 consecutive patients, with proved acute superior mesenteric ischemia, was retrospectively reviewed: the authors reports the diagnostic methods performed preoperatively, the site and the cause of infarction and the time passed between the first radiograph and surgery. Plain abdominal radiographs were performed in 25 of 26 patients, screening abdominal US in 23 cases and CT in 19 cases. All radiological examinations were retrospectively reviewed by the three authors, independently, to recognize the different signs of infarction. On plain abdominal films, the findings warranting a presumptive diagnosis of bowel infarction were air-fluid levels (84% of cases), dilated bowel loops (48%), ...

1997-01-01

412

Analyses of mixed hydrocarbon binary thermodynamic cycles for moderate temperature geothermal resources  

Energy Technology Data Exchange (ETDEWEB)

A number of binary geothermal cycles utilizing mixed hydrocarbon working fluids were analyzed with the overall objective of finding a working fluid which can produce low-cost electrical energy using a moderately low temperature geothermal resource. Both boiling and supercritical shell-and-tube cycles were considered. The performance of a dual-boiling isobutane cycle supplied by a 280/sup 0/F hydrothermal resource (corresponding to the 5MW pilot plant at the Raft River site in Idaho) was selected as a reference. To investigate the effect of resource temperature on the choice of working fluid, several analyses were conducted for a 360/sup 0/F hydrothermal resource, which is representative of the Heber resource in California. The hydrocarbon working fluids analyzed included methane, ethane, propane, isobutane, isopentane, hexane, heptane, and mixtures of those pure hydrocarbons. For comparison, two ...

1981-01-01

413

The state of surface layers on lithium in modified non-aqueous media  

Energy Technology Data Exchange (ETDEWEB)

The state of lithium electrode surface after contact with triethylamine-modified propylene carbonate solutions of lithium perchlorate was studied using the pulse galvanostatic technique as well as methods of SIMS and electron microscopy. It was shown that amine added into the solutions stabilizes the state of lithium and prevents the formation of a secondary porous passive film on the lithium surface. Chemical composition of the primary film remains unchanged. Certain properties of passive films formed in electrolyte solutions studied were evaluated.

1995-04-01

414

The separation and determination of trace elements in iron ore  

International Nuclear Information System (INIS)

The separation, concentration, and determination of trace elements in iron ores are described. After the sample has been dissolved, the iron is separated by liquid-liquid extraction with a liquid cation-exchanger, di-(2-ethylhexyl) phosphoric acid. The trace elements aluminium, cadmium, calcium, chromium, cobalt, copper, lead, magnesium, manganese, mercury, potassium, sodium, vanadium, and zinc are determined in the aqueous phase by atomic-absorption spectrophotometry.

2008-05-01

415

The Fenton oxidation mechanism: reactivities of biologically relevant substrates with two oxidizing intermediates differ from those predicted for the hydroxyl radical.  

UK PubMed Central (United Kingdom)

The application of kinetic probes that allow one to determine relative reactivities of biologically relevant substrates with oxidizing intermediates in the Fenton reagent (H2O2 plus Fe2+ in acidic aqueous...Full Text Available

1994-07-05

416

The ANL electrochemical program for DOE on electric vehicle R&D. Quarterly progress report, January--March 1991  

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the objectives, background, technical progress, and status of ANL electric vehicle battery R&D tasks for DOE-EHP during the period of January 1 through March 31, 1991. The work is organized into the following six task areas: Project management; battery systems technology; lithium/sulfide batteries; advanced sodium/metal chloride battery; aqueous batteries; and EV Battery performance/life evaluation.

1991-12-31

417

The ANL electrochemical program for DOE on electric vehicle R D  

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the objectives, background, technical progress, and status of ANL electric vehicle battery R D tasks for DOE-EHP during the period of January 1 through March 31, 1991. The work is organized into the following six task areas: Project management; battery systems technology; lithium/sulfide batteries; advanced sodium/metal chloride battery; aqueous batteries; and EV Battery performance/life evaluation.

1991-01-01

418

Sunlight-induced efficient and selective photocatalytic benzene oxidation on TiO(2)-supported gold nanoparticles under CO(2) atmosphere.  

Science.gov (United States)

The sunlight-induced photocatalytic oxidation of aqueous benzene on TiO(2)-supported gold nanoparticles was considerably improved when the reaction was conducted under a CO(2) atmosphere. 13% yield and 89% selectivity of phenol was obtained on P25-supported gold nanoparticles under 230 kPa of CO(2). PMID:21952312

2011-09-26

419

Stress Corrosion Cracking Susceptibility of Beta Titanium Alloy 38-6-44: Candidate Alloy for Scout Torsion Bar.  

Science.gov (United States)

The threshold stress itensities for stress corrosion crack propagation in beta titanium alloy 38-6-44, Ti-3Al-8V-6Cr-4Mo-4Zr, has been determined in salt water and methanolic solutions. The alloy was immune to stress corrosion cracking in aqueous sodium c...

1974-01-01

420

Stable halogen complexes of astatine cations in aqueous solutions  

International Nuclear Information System (INIS)

Halide complexes of astatine cations At"+ and AtO"+ were prepared and their rate of migration was measured. The complexes are of the type AtX_2"- and AtOX_2"- (X = Cl"-, Br"-, I"-). The bromo complexes, AtBr_2"- and AtOBr_2"-, have a higher stability than the chloro complexes. The hydrolysis in weakly alkaline solution of AtX_2"- resulted At"-, and that of AtOX_2"- AtO_2"-. (author).

421

Slurry explosives  

Energy Technology Data Exchange (ETDEWEB)

In a slurry explosive, the fine droplets of the aqueous phase are dispersed in a continuous oily phase which comprises a thin film surrounding each droplet, the latter being less than one micron in size. The authors present these commercial explosives in three different forms, indicate their explosive properties and discuss their advantages from the safety viewpoint. They also report on tests undertaken with slurry explosives in quarries possessing different types of rock and using deep vertical shotholes.

1984-12-01

422

Room temperature synthesis of tri-, tetrasubstituted imidazoles and bis-analogues by mercaptopropylsilica (MPS) in aqueous methanol: application to the synthesis of the drug trifenagrel  

British Library Electronic Table of Contents (United Kingdom)

The heterogeneous solid catalyst, mercaptopropylsilica (MPS), has been prepared by a modified procedure in water and its structure confirmed by solid state carbon-13 CP-MAS NMR spectrum. This catalyst has been efficiently utilized for the synthesis of a wide variety of tri-, tetrasubstituted imidazoles and their bis-analogues at room temperature. The protocol was further explored for the synthesis of the drug trifenagrel.

2010-01-01

423

Review of the corrosion resistance properties of Alloy 800 in high-temperature steam  

International Nuclear Information System (INIS)

The investigations carried out on Alloy 800 in aqueous high-temperature environments in France as well as in other countries are reviewed. These studies are mainly concerned with nuclear industry where Alloy 800 can be used as structural material for steam generators of PWR, breeders or HTR. As results referred to in the literature on cracking in caustic environmens do not always agree, a discussion is presented on the matter. The behaviour of Alloy 800 in superheated steam is examined. (Auth.).

424

Quartz ceramics alloying  

International Nuclear Information System (INIS)

The following methods of quartz ceramics alloying were considered: alloying of initial quartz glass; introduction of alloying additive into water slip of quartz glass; porous materials impregnation with salt aqueous solutions and subsequent salt thermal decomposition with formation of stable oxides in pores of ceramics. Oxygen free compounds BN, SiB_4, SiC, Si_3N_4, REM oxides and transition metal oxides were used as alloying additives. Main properties of the materials and compositions obtained are presented.

425

Purification of bidentate organophosphorous extractants  

Energy Technology Data Exchange (ETDEWEB)

Crude N,N-dialkylcarbamoylmethylphosphonates and phosphine oxide extractants, and particularly crude dihexyl N,N-diethylcarbamoylmethylphosphonate and octylphenyl N,N-diisobutylcarbamoyl phosphine oxide, are purified by distilling the crude materials in a thin film evaporator. Preferably, the crude materials are reacted with concentrated hydrochloric acid and then with aqueous sodium hydroxide prior to distillation in the thin film evaporator to hydrolyze impurities contained in them. The purified extractants are useful for extracting actinides and lanthanides from liquid waste streams. (author).

1990-12-19

426

Purification of bidentate organophosphorous extractants  

International Nuclear Information System (INIS)

Crude N,N-dialkylcarbamoylmethylphosphonates and phosphine oxide extractants, and particularly crude dihexyl N,N-diethylcarbamoylmethylphosphonate and octylphenyl N,N-diisobutylcarbamoyl phosphine oxide, are purified by distilling the crude materials in a thin film evaporator. Preferably, the crude materials are reacted with concentrated hydrochloric acid and then with aqueous sodium hydroxide prior to distillation in the thin film evaporator to hydrolyze impurities contained in them. The purified extractants are useful for extracting actinides and lanthanides from liquid waste streams. (author).

1990-05-16

427

Pulsed plasma processing of effluent pollutants and toxic chemicals  

International Nuclear Information System (INIS)

The author is exploring the efficiency of pulsed plasma processing in the removal of nitrogen dioxide, nitrogen oxide, and other pollutants. This process uses an electrical discharge to create chemical radicals from air molecules. These radicals can react with pollutants and form harmless compounds. Additives such as hydrocarbons are also used to improve the efficiency of the removal. The efficient removal of nitrogen dioxide has required the presence of dilute aqueous solution of ammonia.

1994-05-01

428

Pitting corrosion resistance of silicon-implanted stainless steels  

International Nuclear Information System (INIS)

The pitting corrosion resistance of three different types of stainless steel implanted with silicon is investigated using the potentiokinetic polarization technique. The specimens are tested in 3% NaCl and 0.1 N HCl solutions. Silicon ion implantation inhibits pitting corrosion of the steels in both aqueous media. The corrosion resistance depends on the silicon dose. Post implantation annealing only slightly alters the localized corrosion. (author).

429

Overview of the activity of a Brucella abortus preparation, Bru-Pel.  

Science.gov (United States)

The properties of a nonviable, aqueous ether-extracted Brucela abortus preparation, Bru-Pel, are described. In addition to inducing a "virus-type" interferon response and protecting mice against challenge with otherwise lethal doses of Semliki Forest virus, Bru-Pel is demonstrated to have potent antitumor properties in mice. These antitumor effects appear to be mediated by an increase in nonspecific resistance similar to that seen with other experimental antitumor agents. PMID:728911

1978-11-01

430

Metallic aggregate synthesis by radiolysis of simple or complex salt aqueous solutions. Study by electron microscope of aggregate grafting on carbon membranes  

International Nuclear Information System (INIS)

French ... Title Synthese d'agregats metalliques par radiolyse de solutions aqueuses de sels simples ou complexes. Etude par M. E. du greffage des agregats sur membranes de carbone.

1987-05-20

431

Kinetics of carbon dioxide absorption in solutions of methyldiethanolamine  

Energy Technology Data Exchange (ETDEWEB)

The kinetics of the reaction of carbon dioxide in MDEA solutions were studied both experimentally and theoretically. It is concluded that MDEA acts as a homogeneous catalyst for CO/sub 2/ hydrolysis, and as a result the rate of absorption in aqueous MDEA solutions is significantly larger than one would calculate by simply taking into account the alkalinity of the reaction. A possible zwitterion mechanism is proposed for this reaction. The minor effect of ionic strength were also studied with the presence of other ions. 19 references, 6 figures.

1985-01-01

432

Induction of Porphyrin Synthesis in Etiolated Bean Leaves by Chelators of Iron 12  

UK PubMed Central (United Kingdom)

Primary leaves of 7- to 9-day-old etiolated seedlings of Phaseolus vulgaris L. var. Red Kidney infiltrated in darkness with aqueous solutions of α, α′-dipyridyl,...Full Text Available

1974-02-01

433

Heat capacities and densities of electrolyte mixtures in aqueous solution - application to the determination of apparent molar heat capacities and volumes for potassium triiodide and dioxoneptunium(V) perchlorate  

Energy Technology Data Exchange (ETDEWEB)

Apparent molar heat capacities for KI[sub 3](aq) were determined from flow-microcalorimetric measurements of KI(aq) solutions containing dissolved iodine. From these, the conventional partial molar heat capacity C[sub p,2][sup [infinity

1993-05-01

434

Formation and stabilization of anionic metal complexes in concentrated aqueous quaternary ammonium salt solutions  

Energy Technology Data Exchange (ETDEWEB)

Anionic complexes of transition metals were stabilized in aqueous solutions containing high concentrations of various short-chain quaternary ammonium salts. Compounds with longer paraffin chains were effective in much less concentrated solution. Complex ions were detected spectrophotometrically. FeCl/sub 4//sup -/, which is usually formed in concentrated HCl, was the predominant Fe(III) complex in 30 m choline chloride containing only 0.12 M HCl. A yellow transitory Tc(VII) chloro-addition intermediate, formed in the reduction of TcO/sub 4//sup -/ by concentrated HCl, was stabilized when the solution also contained 25 m choline chloride. Its spectrum, as well as the isolation of an already known Tc(VII) bipyridyl complex, is reported. Concentrated organic electrolytes also stabilized Tc(V) oxide halides against disproportionation and Tc(IV) hexahalides against hydrolysis. Halochromates of Cr(VI) were formed and stabilized in dilute acid containing quaternary ...

1985-02-04

435

Formation and stability of astatide-mercury complexes  

International Nuclear Information System (INIS)

The formation of astatide-mercury complexes was investigated in aqueous solutions.The obtained complexes were examined by paper electrophoresis. It was found that Hg(OH)At and Hg(OH)I complexes were formed in neutral solution. The stability constants of the obtained complexes were determined by ion-exchange. The preliminary results indicate that the complex of mercury with astatide is much more stable than similar complexes with iodide. (author)

2006-04-01

436

Effect of environmental variables on localized corrosion of high-performance container materials  

Energy Technology Data Exchange (ETDEWEB)

Electrochemical cyclic potentiodynamic polarization (CPP) experiments were performed on several candidate high-performance waste package container materials to evaluate their susceptibility to localized corrosion in aqueous environments relevant to the potential underground high-level nuclear waste repository. This paper presents the results of this study showing the effects of chloride ion (Cl) concentrations, pH, temperature, and electrochemical potential scan rate on the pitting corrosion behavior of these materials.

1997-01-01

437

Effect of decontamination factor on core neutronic design of light water reactors using recovered uranium reprocessed by advanced aqueous method  

International Nuclear Information System (INIS)

In the case where uranium recovered by an advanced aqueous reprocessing is utilized in light water reactors (LWRs) with the thermal neutron spectrum, the effects of the decontamination factor (DF) of the reprocessing on core neutronic characteristics were examined. The amounts of transuranium (TRU) elements and fission products (FPs) contained in the recovered uranium depend on the DF of reprocessing, and also "2"3"6U is generated by neutron capture of "2"3"5U during a reactor operation. These all act as poisons in the fuel. Therefore, in this paper, the additional "2"3"5U enrichment necessary to compensate for the produced TRU elements, FPs, and "2"3"6U was evaluated for three representative DF values: 10"2, 10"3, and infinity. The low value of 10"2 corresponds to the advanced aqueous reprocessing investigated here. An APWR core with a discharge burnup of 49 GWd/t when the initial "2"3"5U enrichment is 4.6% was considered as the reference ...

2009-05-01

438

Discovery and investigation of properties of new inorganic and organic compounds of astatine  

International Nuclear Information System (INIS)

Short review of works on astatine chemistry carried out by authors for the last thirty years are done. Discovery of single-charged cation stable in aqueous solutions is predominant attainment of authors in the branch of inorganic chemistry. The first successful synthesis of heptavalent astatine compounds is a new and significant result of the last years. New direction in the chemistry of the fifth halogen is organic chemistry of astatine

439

Coumarin-4 laser efficiency up to 0. 14% under coaxial flash-lamp pumping  

Energy Technology Data Exchange (ETDEWEB)

Under coaxial flash lamp pumping the laser efficiency of coumarin-4 in slightly basic ethyl alcohol solution as an active medium has reached a value of 0.14%. That is three times higher than that in the basic aqueous solution. Its tunable wavelength range of laser output has extended from 440 to 510 nm with the maximum at 460 nm.

1987-02-01

440

Conformational transitions of alternating purine-pyrimidine DNAs in perchlorate ethanol solutions.  

UK PubMed Central (United Kingdom)

Conformational transitions of poly(dA-dC).poly(dG-dT), poly(dA-dT).poly(dA-dT), and other alternating purine-pyrimidine DNAs were studied in aqueous ethanol solutions containing molar concentrations...Full Text Available

1995-11-01

441

Complex formation of At(I) with halogenides in alcoholic solutions  

International Nuclear Information System (INIS)

The stability constants of [AtX_2]"- with X = Cl, Br and I in ethanol and methanol as well as their ion mobilities at a temperature of 298 K and an ionic strength of 0.05 were determined by horizontal zone electromigration in homogeneous electrolyte solution. The results are compared with existing data from aqueous electrolyte systems. (author).

442

Biological solubilization of coal in aqueous and nonaqueous media  

Energy Technology Data Exchange (ETDEWEB)

Current investigations into the biological solubilization of coal with microorganisms focus on the production of solubilizing activity in fungi. Test organisms for this work include a species of the yeast Candida previously isolated from a lignite outcrop, and P. chrysosporium, a filamentous higher fungus which has played a major role in lignin biodegradation research. The studies described are primarily exploratory in nature, and are fundamental to the design of more sophisticated inquiries into the physiology of fungal coal solubilization.

1987-01-01

443

A novel amphiphilic pincer palladium complex: design, preparation and self-assembling behavior.  

Science.gov (United States)

Amphiphilic pincer palladium complexes bearing hydrophilic and hydrophobic side chains on the planar NCN palladium pincer backbone were designed and prepared via the ligand introduction route. The complexes self-assembled under aqueous conditions to form vesicles with bilayer membranes containing palladium species. The catalytic activity of the vesicles in the Miyaura-Michael reaction in water was investigated. PMID:21837316

2011-08-11

444

A method of producing a stabilizer of wash drilling muds  

Energy Technology Data Exchange (ETDEWEB)

A method is proposed for producing a stabilizer of wash drilling muds; by hydrolysis of polyacrylonitrile in an aqueous solution of alkaline agent with heating. To raise the heat resistance of the stabilizer, as the alkaline agent is used monosilicate of sodium, while the hydrolysis is done at a molar ratio of polyacrylonitrile, sodium monosilicate and water equal to 1.0:0.7-2.5:100, to a degree of hydrolysis of 25-40.

1981-01-01

445

A Monte Carlo model for predicting water quality in mine pit lakes  

Energy Technology Data Exchange (ETDEWEB)

A model has been developed to predict the chemical composition of lakes that form in pyrite-bearing open-pit mines. Pyrite oxidation in wall rock releases sulfuric acid and metals, which mix with ground waters in the lake. Aqueous metal concentrations are calculated using MINTEQA2.

1995-12-01

446

The properties and transport phenomena in oxide films on iron, nickel, chromium and their alloys in aqueous environments  

International Nuclear Information System (INIS)

The construction materials used in coolant systems in nuclear power plants become covered with oxide films as a result of exposure to the aqueous environment. The susceptibility of the materials to different forms of corrosion, as well as the extent of the incorporation of radioactive species on the surfaces of the primary circuit, are greatly influenced by the physical and chemical properties of these oxide films. The composition and characteristics of the oxide films in turn depend on the applied water chemistry. This work was undertaken in order to collect and evaluate the present views on the structure and behaviour of oxide films formed on iron- and nickel-based materials in aqueous environments. This survey should serve to recognise the areas in which more understanding and research effort is needed. The review begins with a discussion on the bulk oxides of iron, nickel and chromium, as well as their mixed oxides. In addition to bulk ...

2010-03-01

447

Advanced Binary Geothermal Power Plancts Working Fluid Property Determination and Heat Exchanger Design  

Energy Technology Data Exchange (ETDEWEB)

The performance of binary geothermal power plants can be improved through the proper choice of a working fluid, and optimization of component designs and operating conditions. This paper reviews the investigations at the Idaho National Engineering Laboratory (INEL) which are examining binary cycle performance improvements: for moderate temperature (350 to 400 F) resources with emphasis on how the improvements may be integrated into design of binary cycles. These investigations are examining performance improvements resulting from the supercritical vaporization of mixed hydrocarbon working fluids and achieving countercurrent integral condensation with these fluids, as well as the modification of the turbine inlet state points to achieve supersaturated turbine vapor expansions. For resources where the brine outlet temperature is restricted, the use of turbine exhaust recuperators is examined. The baseline plant used to ...

1989-03-21

448

A Scheme of 3-D Breakdown-whip Analysis Methodology for High Energy Piping  

Energy Technology Data Exchange (ETDEWEB)

High energy piping systems are operated with either or both conditions of maximum operating temperature exceeding 200 .deg. F(93.3 .deg. C) or maximum operating pressure exceeding 275 psig(19.3kg/cm{sup 2}) during normal operating conditions in nuclear power plants. A high energy pipe failure is postulated in branches or piping that runs larger than one inch nominal diameter. The resultant consequences of these postulated pipe breaks must be analyzed for the effect on maintenance of plant safe shutdown capability, containment integrity. And the analyzed results must be applied to the system design so that a pipe failure can not damage essential systems to an extent of impairing design function nor affect necessary component operability. The considerable effects of pipe break are as follows; dynamic effects such as pipe whip, jet impingement and environmental impact by release of system contents. Two types of forces are occurred by the pipe whip. The one is pipe whip impact force that ...

2007-10-15

449

Ultra fine grinding of low-rank coal. Progress report, April-June 1986  

Energy Technology Data Exchange (ETDEWEB)

The lignite used for Phase I of the project was a Texas lignite from the Martin Lake mine obtained from the stockpile for the Martin Lake Power Plant of the Texas Utilities Generating Company. The power requirements for the fluid-energy mill were determined from the measured steam (or air) temperatures, pressures and pressure drops and the lignite flow rate. The instrument locations for the tests are shown on Figure 1. All of the instruments were connected to a microcomputer via an analog input interface board. Data were recorded on disks periodically throughout the tests. Appropriate calibration procedures were followed to assure that reliable data were being obtained. The combined grinding/drying tests were conducted in Vicksbuth, MS at Ergon, Inc.'s fluid-energy-mill facility. both steam and air were used as grinding fluids. With steam, tests were used as grinding fluids. With steam, tests ...

1986-07-01

450

The composition-explicit distillation curve technique: Relating chemical analysis and physical properties of complex fluids.  

Science.gov (United States)

The analysis of complex fluids such as crude oils, fuels, vegetable oils and mixed waste streams poses significant challenges arising primarily from the multiplicity of components, the different properties of the components (polarity, polarizability, etc.) and matrix properties. We have recently introduced an analytical strategy that simplifies many of these analyses, and provides the added potential of linking compositional information with physical property information. This aspect can be used to facilitate equation of state development for the complex fluids. In addition to chemical characterization, the approach provides the ability to calculate thermodynamic properties for such complex heterogeneous streams. The technique is based on the advanced distillation curve (ADC) metrology, which separates a complex fluid by distillation into fractions that are sampled, and for which thermodynamically consistent temperatures ...

2009-11-17

451

Numerical study on the heat transfer to CO_2 flowing upward in a heated vertical tube at supercritical pressure  

International Nuclear Information System (INIS)

Full text of publication follows: As the coolant experiences no phase change in the core, SCWRs, unlike LWRs, cannot use design criteria based on the critical heat flux concept. The commonly accepted practice in SCWRs is to specify cladding temperature limits that must be met during transient and accident events. Therefore for the design of the SCWR, it is very important to predict the heat transfer coefficient to the supercritical water coolant with great accuracy. Our recent study focuses on the critical issue of measuring heat transfer to supercritical water at prototypical SCWR conditions and to develop the tools to predict the SCWR thermal behavior. A heat transfer test loop using a surrogate fluids, CO_2, is under construction. The reason of using CO_2 instead of water is that (i) valuable insight of the physical phenomena can be obtained with this fluid, and (ii) some existing facilities already used surrogate ...

2005-10-02

452

A nonmolecular derivation of Maxwell's thermal-creep boundary condition in gases and liquids via application of the LeChatelier-Braun principle to Maxwell's thermal stress  

Science.gov (United States)

According to the LeChatelier-Braun principle, when a closed quiescent system initially in an equilibrium or unstressed steady state is subjected to an externally imposed ``stress'' it responds in a manner tending to alleviate that stress. Use of this entropically based qualitative rule, in combination with the notion of Maxwell thermal stresses existing in nonisothermal gases and liquids, enables one to (i) derive Maxwell's thermal-creep boundary condition prevailing at the boundary between a solid and a fluid (either gas or liquid) and (ii) rationalize the phenomenon of thermophoresis in liquids, for which, in contrast with the case of gases, an elementary explanation is currently lacking. These two objectives are achieved by quantitatively interpreting the heretofore qualitative LeChatelier-Braun notion of stress in the present context as being the fluid's stress tensor, the latter including Maxwell's thermal stress. In effect, thermophoretic ...

2009-05-01

453

Wireline well logging an underutilized technique in reservoir evaluation  

Energy Technology Data Exchange (ETDEWEB)

Wireline well logs have three general uses in geothermal exploration and reservoir evaluation: reservoir parameter analysis, lithologic column determination, and reservoir size resolution. Reservoir flow testing data are acquired to understand the flow rate, life, and production potential of the geothermal reservoir. These data are a coarse subsurface measurement of the geothermal prospect. Wireline logs acquired from wells in a geothermal prospect are used to define in detail, or estimate the reservoir parameters of temperature, thickness, lateral size, amount of fracture and intergranular pore space, and the quantity and quality of fluid that might be produced. Laboratory measurements can be made on core samples and drill cuttings samples to define the intrinsic behavior of the materials and fluid that compose the geotheraml reservoir. Wireline log measurements are needed to correlate and link the reservoir testing and core analysis, reduce ...

1981-01-01

454

Vibration test report on the instrumented capsule for fuel irradiation test  

Energy Technology Data Exchange (ETDEWEB)

The fluid-induced vibration level of instrumented capsule, which was manufactured for fuel irradiation test at the reactor core of HANARO, was investigated. For this purpose, the instrumented capsule was loaded at the OR site of the HANARO design verification test facility that could simulate identical flow condition as the HANARO core. Then, vibration signals of the instrumented capsule subjected to various flow conditions were measured by using vibration sensors. In time domain analysis, maximum amplitudes and RMS values of the measured acceleration and displacement signals were obtained. By using frequency domain analysis, frequency components of the fluid-induced vibration were analyzed. In addition, natural frequencies of the instrumented capsule were obtained by performing modal test. The frequency analysis results showed that the natural frequency components near 7.5Hz and 17.5Hz were dominant in the fluid-induced ...

2003-01-01

455

Two-fluid modeling of condensation in the presence of noncondensables in two-phase channel flows  

Energy Technology Data Exchange (ETDEWEB)

Condensing two-phase channel flow occurs in many industrial applications, including heating and refrigeration systems. It can also occur in certain nuclear reactor accidents. For example, during a small-break loss-of-coolant accident in a pressurized water reactor, following the partial depletion of the primary coolant, condensation of steam on the primary side of the steam generator tubes can provide a heat sink for disposal of the decay heat generated in the reactor core. Condensing two-phase flow can also play an important role in the operation of the passive emergency cooling system in the advanced simplified boiling water reactor. Here, steady-state condensation in the presence of a noncondensable in a concurrent two-phase channel flow is analyzed using a two-fluid model. The effect of noncondensables on the combined heat transfer at the liquid-gas mixture interphase is accounted for by using the stagnant film model, and closure relations relevant to the ...

1995-01-01

456

Three-dimensional multispecies current density simulation of molten-salt electrorefining  

Energy Technology Data Exchange (ETDEWEB)

This study presents three-dimensional simulation results of multispecies and multi-reaction electrorefining for spent nuclear waste treatment. Fluid-dynamic behavior of electrorefining is analyzed by commercial computational fluid-dynamics code. The results of local fluid dynamics are coupled with one-dimensional electrochemical reaction analysis code in order to predict local current density distribution. The new approach shows current distribution patterns over the cathode surface in LiCl-KCl molten-salt electrolyte. The current density distribution patterns are analyzed for various electrode rotational speeds and diverse applied currents and the results show a good agreement with general principle of mass transfer observations. Spatially periodic and vertically striped pattern of current density is predicted at the cathode side due to mass transfer depression at separation points. These slow mass transfer regions are ...

2010-07-30

457

TheU-Tube: A Novel System for Acquiring Borehole Fluid Samplesfrom a Deep Geologic CO2 Sequestration Experiment  

Energy Technology Data Exchange (ETDEWEB)

A novel system has been deployed to obtain geochemical samples of water and gas, at in situ pressure, during a geologic CO2 sequestration experiment conducted in the Frio brine aquifer in Liberty County, Texas. Project goals required high-frequency recovery of representative and uncontaminated aliquots of a rapidly changing two-phase (supercritical CO2-brine) fluid from 1.5 km depth. The datasets collected, using both the liquid and gas portions of the downhole samples, provide insights into the coupled hydro-geochemical issues affecting CO2 sequestration in brine-filled formations. While the basic premise underlying the U-Tube sampler is not new, the system is unique because careful consideration was given to the processing of the recovered two-phase fluids. In particular, strain gauges mounted beneath the high-pressure surface sample cylinders measured the ratio of recovered brine to supercritical CO2. A quadrupole mass spectrometer provided ...

2005-03-17

458

Study of structural, thermodynamical and dynamical properties of molecular liquids confined in nano-porous materials  

International Nuclear Information System (INIS)

When liquids are confined in nano-scopic dimensions, their properties differ from the corresponding bulk liquid, due to their reduced dimensionality and surface effects. Phase transition temperatures and pressures are often shifted from the bulk values and new phases can appear due to the strong interactions of the molecules with the confining walls. We have studied the structural and dynamical properties of aromatic liquids such as benzene, toluene, and ortho-terphenyl confined in nano-porous materials, MCM-41 and SBA-15, synthesized and characterized in our laboratory. A non-trivial dependence of the glass transition temperature, Tg, on the pore size and surface treatment of nano-porous materials is confirmed and interpreted as resulting from a competition between the fluid-wall and fluid-fluid intermolecular interactions. An increase of Tg is observed for small pore sizes and attractive surface while Tg decreases for non attractive surface, ...

2006-01-01

459

Release of zinc from disposable coils during hemodialysis  

Energy Technology Data Exchange (ETDEWEB)

In a prior study, we demonstrated that certain disposable coils are contaminated with zinc and release substantial quantities of Zn during hemodialysis, producing high post-dialysis plasma Zn concentrations. The present investigation was designed to monitor plasma and dialysis fluid Zn and copper throughout dialysis and to estimate patient Zn and Cu uptake. Venous plasma, arterial plasma and coil chamber fluid were sampled periodically throughout dialysis; trace metal concentrations were determined by flame atomic absorption spectrophotometry. Release of considerable quantities of Zn from the coils into the dialysis fluid, with uptake into the patient's plasma, was found. Approximately one-half of the plasma Zn uptake occurred in the first 45 minutes. Coils from different lots released significantly different quantities of Zn. Patient uptake of Zn ranged from 3.2 mg-23.0 mg, with a mean of 15.0 +- 6.1 mg. Copper ...

1981-06-01

460

Power-cycle studies for a geothermal electric plant for MX operating bases  

Energy Technology Data Exchange (ETDEWEB)

Binary geothermal plants were investigated for providing electrical power for MX missile bases. A number of pure hydrocarbons and hydrocarbon mixtures were evaluated as working fluids for geothermal resource temperatures of 365, 400, and 450/sup 0/F. Cycle thermodynamic analyses were conducted for pure geothermal plants and for two types of coal-geothermal hybrid plants. Cycle performance results were presented as net geofluid effectiveness (net plant output in watts per geofluid flow in 1 bm/hr) and cooling water makeup effectiveness (net plant output in watts per makeup water flow in 1 bm/hr). A working fluid containing 90% (mass) isobutane/10% hexane was selected, and plant statepoints and energy balances were determined for 20MW(e) geothermal plants at each of the three resource temperatures. Working fluid heaters and condensers were sized for these plants. It is concluded that for the advanced plants investigated, ...

1981-11-01

461

Nonlinear dynamics of a flexible rotor supported by turbulent journal bearings with couple stress fluid  

Energy Technology Data Exchange (ETDEWEB)

This study presents a dynamic analysis of a rotor supported by two turbulent flow model journal bearings and lubricated with couple stress fluid under nonlinear suspension. The dynamics of the rotor center and bearing center is studied. The dynamic equations are solved using the Runge-Kutta method. The analysis methods employed in this study is inclusive of the dynamic trajectories of the rotor center and bearing center, power spectra, Poincare maps and bifurcation diagrams. The maximum Lyapunov exponent analysis is also used to identify the onset of chaotic motion. The results show that the values of dimensionless parameters l* strongly influence dynamic motions of bearing and rotor centre. It is found that couple stress fluid improve the stability of the system when l* > 0.4 even if the flow of this system is turbulent. We also demonstrated that the dimensionless rotational speed ratios s and the dimensionless unbalance parameter ...

2008-08-15

462

Nonlinear dynamics of a flexible rotor supported by turbulent journal bearings with couple stress fluid  

International Nuclear Information System (INIS)

This study presents a dynamic analysis of a rotor supported by two turbulent flow model journal bearings and lubricated with couple stress fluid under nonlinear suspension. The dynamics of the rotor center and bearing center is studied. The dynamic equations are solved using the Runge-Kutta method. The analysis methods employed in this study is inclusive of the dynamic trajectories of the rotor center and bearing center, power spectra, Poincare maps and bifurcation diagrams. The maximum Lyapunov exponent analysis is also used to identify the onset of chaotic motion. The results show that the values of dimensionless parameters l* strongly influence dynamic motions of bearing and rotor centre. It is found that couple stress fluid improve the stability of the system when l* > 0.4 even if the flow of this system is turbulent. We also demonstrated that the dimensionless rotational speed ratios s and the dimensionless unbalance parameter #beta# ...

2008-08-01

463

Matter and dynamics in closed cosmologies  

International Nuclear Information System (INIS)

To systematically analyze the dynamical implications of the matter content in cosmology, we generalize earlier dynamical systems approaches so that perfect fluids with a general barotropic equation of state can be treated. We focus on locally rotationally symmetric Bianchi type IX and Kantowski-Sachs orthogonal perfect fluid models, since such models exhibit a particularly rich dynamical structure and also illustrate typical features of more general cases. For these models, we recast Einstein's field equations into a regular system on a compact state space, which is the basis for our analysis. We prove that models expand from a singularity and recollapse to a singularity when the perfect fluid satisfies the strong energy condition. When the matter source admits Einstein's static model, we present a comprehensive dynamical description, which includes the qualitative asymptotic behavior, of models in the neighborhood of the ...

2005-04-15

464

Investigation and improvement of ejector refrigeration system using computational fluid dynamics technique  

Energy Technology Data Exchange (ETDEWEB)

Ejector refrigeration systems are usually designed to utilize low grade energy for driving the cycle. They also have low maintenance cost because they operate without a compressor. Mainly, the ejector performance directly affects the refrigerating performance. Therefore, an investigation on the characteristics and an efficient design of the ejector are important to improve ejector refrigeration systems. In this study, the computational fluid dynamics (CFD) code, FLUENT, is employed to predict the flow phenomena and performance of CPM and CMA steam ejectors. The ejector refrigeration system, using water as the working fluid, is operated at 120-140 C boiler temperature and 5-15 C evaporator temperature. CFD can predict ejector performance very well and reveal the effect of operating conditions on an effective area that is directly related to its performance. Besides, it is found that the flow pattern does not depend much on the suction zone ...

2007-09-15

465

Feasibility of an antiproton catalyzed fission fragment rocket  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this project was to investigate the feasibility of an antiproton catalyzed fission fragment rocket (FFR). The FFR is characterized by the extraction of fission fragments from the fissile fuel, and the utilization of their kinetic energy for thrust generation. A significant drawback to previous FFR designs was the requirement to maintain a critical nuclear pile as the fission fragment source. The author examined the possibility of replacing the critical pile with a sub-critical pile driven by antiprotons. Recent experiments have revealed that antiprotons stimulate highly energetic fissions in {sup 238}U, with a neutron multiplicity of 13.7 neutrons per fission. This interaction was used as a throttled neutron source. The pile consisted of layers of fissile coated fibers which are designed to allow fission fragments to escape them, where the fragments collide with a fluid. The heated fluid is then ejected from the rocket to provide ...

1992-03-01

466

Evaluation of advanced technologies for power transformers. Final report  

Energy Technology Data Exchange (ETDEWEB)

The high insulating strength of certain gases, such as sulfur hexafluoride, when used at high pressure, suggests that there may be advantages to compressed gases as the insulating fluid in power transformers. However, simply exchanging the oil for compressed gas in an otherwise conventional transformer design will not yield a significant overall advantage. Compressed gases present the engineer with properties which are quite different from mineral oil. If gases are to be used as the major insulating fluid in power transformers, then virtually all aspects of the insulation and cooling of the apparatus must be reconsidered, affording an opportunity to introduce new design concepts, new materials, and new construction techniques. In this program, the feasibility of using the following principal design concepts has been explored: sheet conductors for the windings; a system of sealed, self-contained, annular cooling ducts containing circulating ...

1981-01-01

467

Diverter/bop system and method for a bottom supported offshore drilling rig  

Energy Technology Data Exchange (ETDEWEB)

This patent describes a system adapted for alternative use as a diverter or a blowout preventer for a bottom supported drilling rig and adapted for positioning beneath a rotary table of the drilling rig, the system comprising: a fluid flow controller having a controller housing with a lower opening and an upper opening and a vertical flow path therebetween and an outlet passage provided in its housing wall, and at least two bases. A method is described for installing a system adapted for alternative connection as a diverter or a blowout preventer for a bottom supported drilling rig positioned beneath a rotary table of the drilling rig after structural casing has been set in a borehole. The method comprises: positioning a first telescoping spool having a lower end and an upper end below the rotary table, the first spool having a first base disposed at its upper end, the first base having a port disposed in its wall; aligning a fluid flow ...

1987-03-03

468

Diverter bop system and method for a bottom supported offshore drilling rig  

Energy Technology Data Exchange (ETDEWEB)

A system and method for installing a fluid flow controller and telescoping spools beneath an offshore bottom supported drilling rig rotary table is disclosed. Upper and lower telescoping spools are provided for initially connecting a Diverter/BOP convertible fluid flow controller between structural casing in the well and a permanent housing beneath the drilling rig rotary table. Clamp means are provided for clamping the rig vent line to an opening in the housing wall of the fluid flow controller during drilling of the borehole through the structural casing in preparation for setting and cementing the conductor casing. In that mode, the system is adapted as a diverter system. After the well is drilled for the conductor casing and the conductor casing is cemented and cut off at its top, a mandrel is fitted at the top of the conductor casing to which the lower end of the lower spool may be connected. The system may be used in ...

1985-06-25

469

Corrosion in drilling and well stimulation  

Energy Technology Data Exchange (ETDEWEB)

Corrosion in drilling and well stimulation is described in relation to acid corrosion inhibition, acid inhibitors, acetylenic inhibitors, synergistic blends, metallurgy, wellbore tubulars, coiled tubing, and high alloy tubular materials. Acidizing is a procedure for stimulating oil and gas wells. Factors that have an important influence on the reaction rate and the way in which acid reacts with rock include temperature, acid concentration, acid volume, injection velocity, acid viscosity, and fluid loss properties of the formation. The cost of drill pipe failures are $1 per fot of hole drilled, which is a significant fraction of the drilling cost. Steps in a test procedure are listed, as well as factors which determine the extent of acid corrosion in a given situation including acid type and strength, metal type, temperature, contact time; pressure, and volume/surface area ratio. Underbalanced drilling is a method for completing oil and gas wells that minimizes the ...

1999-07-01

470

Conceptual fusion power monitor based on the "1"6O(n,p)"1"6N reaction  

International Nuclear Information System (INIS)

The feasibility of developing a fusion power monitor based on a fluid activation detector is considered here. The activation fluid may be either a liquid or a gas and its composition can be selected from a number of candidate materials to provide desired activation and decay characterisitcs. Performance calculations indicate that ordinary water would be a nearly ideal activation fluid. The "1"6O(n,p)"1"6N reaction has a threshold at about 10 MeV and a cross section energy dependence giving it a predominant response for unmoderated D-T fusion neutrons. Adequate activation can be obtained at moderate flow rates for remote counting away from the high radiation area of the reactor. The 7.16 sec half-life of "1"6N is ideal for remote counting with subsequent decay in a small hold-up tank to eliminate activity build-up in the recycled water.

1981-07-01

471

Chaos and bifurcation of a flexible rotor supported by porous squeeze couple stress fluid film journal bearings with non-linear suspension  

Energy Technology Data Exchange (ETDEWEB)

This study presents a dynamic analysis of a flexible rotor supported by two porous squeeze couple stress fluid film journal bearings with non-linear suspension. The dynamics of the rotor center and bearing center are studied. The analysis of the rotor-bearing system is investigated under the assumptions of non-Newtonian fluid and a short bearing approximation. The spatial displacements in the horizontal and vertical directions are considered for various non-dimensional speed ratios. The dynamic equations are solved using the Runge-Kutta method. The analysis methods employed in this study is inclusive of the dynamic trajectories of the rotor center and bearing center, power spectra, Poincare maps and bifurcation diagrams. The maximum Lyapunov exponent analysis is also used to identify the onset of chaotic motion. The numerical results show that the stability of the system varies with the non-dimensional speed ratios, the non-dimensional ...

2008-01-15

472

Chaos and bifurcation of a flexible rotor supported by porous squeeze couple stress fluid film journal bearings with non-linear suspension  

International Nuclear Information System (INIS)

This study presents a dynamic analysis of a flexible rotor supported by two porous squeeze couple stress fluid film journal bearings with non-linear suspension. The dynamics of the rotor center and bearing center are studied. The analysis of the rotor-bearing system is investigated under the assumptions of non-Newtonian fluid and a short bearing approximation. The spatial displacements in the horizontal and vertical directions are considered for various non-dimensional speed ratios. The dynamic equations are solved using the Runge-Kutta method. The analysis methods employed in this study is inclusive of the dynamic trajectories of the rotor center and bearing center, power spectra, Poincare maps and bifurcation diagrams. The maximum Lyapunov exponent analysis is also used to identify the onset of chaotic motion. The numerical results show that the stability of the system varies with the non-dimensional speed ratios, the non-dimensional ...

2008-01-01

473

CFD simulation of flow distribution in the header of plate-fin heat exchangers  

Energy Technology Data Exchange (ETDEWEB)

The flow distribution through a plate-fin heat exchanger is studied by using a computational fluid dynamics (CFD) code, FLUENT. The flow distribution through any heat exchanger affects its performance. In designing a heat exchanger, it is assumed that the fluid is uniformly distributed through the heat exchanger core. In practice, however, it is impossible to distribute fluid uniformly, because of an improper inlet configuration, imperfect design, and a complex heat transfer process. The CFD simulation of the flow distribution in the header of a conventional plate-fin heat exchanger is presented. It is found that the flow maldistribution is very serious in the y-direction of the header. A modified header is proposed and simulated using CFD. The modified header configuration has a more uniform flow distribution than the conventional header configuration. Hence, the efficiency of the modified heat exchanger is seen to be ...

2007-10-15

474

Augmentation of heat transfer in heat conductive medium by electro-hydrodynamic effect  

Energy Technology Data Exchange (ETDEWEB)

A method of augmenting heat transfer in the interior of a fluid or from the interface of a solid in contact to a fluid by utilizing electro hydrodynamic (EHD) phenomena has the following advantages: the heat transfer can be effected by using a relatively small, light-weight high voltage source and some simple structural members; no vibration and noise are generated; the method has a control function to control heat transfer by adjustment of field and voltage; and this method is effective in cost-saving. It is mass transfer by the electric force caused by interaction between true charges or polarized charges in a fluid and external electric filed that plays an important role in most of such heat transfer augmentation methods by EHD. Examples of heat transfer augmentation by EHD phenomena include electricaly induced convection, contribution of EHD effect to heat transfer accompanied with boiling, heat transfer by corona wind ...

1988-04-20

475

Analysis of flow-induced vibration by improvement of design in UCN 5,6 steam generator  

Energy Technology Data Exchange (ETDEWEB)

Youngkwang Unit 3,4 and Ulchin Unit 3 and 4 have had problem of the KSNP Steam Generator due to a severe fretting wear on the tube. In particular, the wears were localized and concentrated in the upper part of U-bend of the Central Cavity region. At the upper tube bundle Central Cavity, the fluid flow velocities and void fraction are very high, because the steam is made by high heat transfer at secondary region. Also, this region is affected easily by fretting wear due to it's unsupported span is longer than another regions. The fretting wear is assumed to be result of Flow-Induced Vibration (F. I. V), which can occur by many mechanisms. EFDP was added to UCN 5,6 for prevent fretting wear by the SEC LCC and DSHIC, a company of design and manufacture of the steam generator, respectively. In order to evaluate the efficacy of EFDP, ANSYS and ATHOS-3 Code were used. From sensitivity analysis and calculation results, Density and Velocity into the Central Cavity ...

2001-10-01

476

Analysis of flow-induced vibration by improvement of design in UCN 5,6 steam generator  

International Nuclear Information System (INIS)

Youngkwang Unit 3,4 and Ulchin Unit 3 and 4 have had problem of the KSNP Steam Generator due to a severe fretting wear on the tube. In particular, the wears were localized and concentrated in the upper part of U-bend of the Central Cavity region. At the upper tube bundle Central Cavity, the fluid flow velocities and void fraction are very high, because the steam is made by high heat transfer at secondary region. Also, this region is affected easily by fretting wear due to it's unsupported span is longer than another regions. The fretting wear is assumed to be result of Flow-Induced Vibration (F. I. V), which can occur by many mechanisms. EFDP was added to UCN 5,6 for prevent fretting wear by the SEC LCC and DSHIC, a company of design and manufacture of the steam generator, respectively. In order to evaluate the efficacy of EFDP, ANSYS and ATHOS-3 Code were used. From sensitivity analysis and calculation results, Density and Velocity into the Central Cavity are ...

2001-10-01

477

Waste treatment process for removal of contaminants from aqueous, mixed-waste solutions using sequential chemical treatment and crossflow microfiltration, followed by dewatering  

Energy Technology Data Exchange (ETDEWEB)

In processes of this invention aqueous waste solutions containing a variety of mixed waste contaminants are treated to remove the contaminants by a sequential addition of chemicals and adsorption/ion exchange powdered materials to remove the contaminants including lead, cadmium, uranium, cesium-137, strontium-85/90, trichloroethylene and benzene, and impurities including iron and calcium. Staged conditioning of the waste solution produces a polydisperse system of size enlarged complexes of the contaminants in three distinct configurations: water-soluble metal complexes, insoluble metal precipitation complexes, and contaminant-bearing particles of ion exchange and adsorbent materials. The volume of the waste is reduced by separation of the polydisperse system by cross-flow microfiltration, followed by low-temperature evaporation and/or filter pressing. The water produced as filtrate is discharged if it meets a specified target water quality, or else the filtrate is ...

1994-01-01

478

Waste treatment process for removal of contaminants from aqueous, mixed-waste solutions using sequential chemical treatment and crossflow microfiltration, followed by dewatering  

Energy Technology Data Exchange (ETDEWEB)

In processes of this invention aqueous waste solutions containing a variety of mixed waste contaminants are treated to remove the contaminants by a sequential addition of chemicals and adsorption/ion exchange powdered materials to remove the contaminants including lead, cadmium, uranium, cesium-137, strontium-85/90, trichloroethylene and benzene, and impurities including iron and calcium. Staged conditioning of the waste solution produces a polydisperse system of size enlarged complexes of the contaminants in three distinct configurations: water-soluble metal complexes, insoluble metal precipitation complexes, and contaminant-bearing particles of ion exchange and adsorbent materials. The volume of the waste is reduced by separation of the polydisperse system by cross-flow microfiltration, followed by low-temperature evaporation and/or filter pressing. The water produced as filtrate is discharged if it meets a specified target water quality, or else the filtrate is ...

1994-11-22

479

Sulfur and carbon cycling in a flue gas desulfurization sludge disposal site.  

Science.gov (United States)

Products of a power plant flue gas desulfurization scrubber are discharged into a pond as sludge consisting of calcite (initial delta13C 3.2-3.8 per thousand), gypsum (initial delta34S 7.6-8.6 per thousand), and aqueous solution. Reducing conditions exist below a boundary that appears to move vertically as a function of changes in pond water level. Under reducing conditions, bacteria partially reduce aqueous sulfate to low-delta34S sulfide, consuming organic carbon and generating low-delta13C bicarbonate. Under oxidizing conditions, sulfide is converted to sulfate, leading to calcite dissolution, gypsum precipitation, and isotopic re-equilibration of remaining calcite with dissolved bicarbonate near the pond surface. The gypsum has delta34S near 6 per thousand, and calcite has delta13C as low as -1.7 per thousand; the changes from initial values correspond to predictions based on isotopic balance and reaction stoichiometry. The pond largely ...

2003-04-01

480

Single-Electrode Capacitance and Charged State in Interfacial Region within Nano-Porous Carbon Electrode for Electric Double Layer Capacitor; Kasseitan denki 2jyuso kyapasita no tankyoku seiden yoryo to koeki kaimen chikuden jyotai  

Energy Technology Data Exchange (ETDEWEB)

The single-electrode capacitance of a nano-porous carbon electrode used as an electric double layer capacitor was measured. The charged state of the electrolyte ion was discussed from the results. Single-electrode capacitance was not proportional to the specific surface area of the electrode. This implies that the whole surface of the electrode is not effective for the formation of an electric double layer. It is considered that edge orientation of the carbon structure would give a dominant contribution to capacitance. For measurements with aqueous solutions of various electrolytes, capacitance was about the same value for each salt compound. For aqueous acid solution, on the other hand, capacitance was twice to three times as large as that for salt compounds. This difference, however, became negligibly small if the concentration of electrolyte solution was lowered. Taking account of the hydrated ionic radius of each ion, it was considered that ...

1997-07-10

481

Role of minerals in carbonaceous adsorbents for removal of Pb(II) ions from aqueous solution  

Energy Technology Data Exchange (ETDEWEB)

Adsorptive removal of Pb(II) ions from aqueous solution onto a non-activated charcoal (CC) of oak wood origin was studied in comparison with an activated carbon of coal origin. The adsorption capacity for Pb(II) of the non-activated charcoal increased significantly with deceasing particle diameter, whereas the activated carbon (AC) exhibited approximately constant capacity for Pb(II) adsorption as a function of particle size. Adsorption to the ashes prepared from the non-activated charcoal and the activated carbon was also investigated to examine the role of mineral ash. Although the ash from the activated carbon did not show any Pb(II) adsorption, the ash from the charcoal was very effective for Pb(II) adsorption. Furthermore, Pb(II) was hardly adsorbed when the ash was removed from the non-activated charcoal by acid treatment. Based on the results, the adsorption sites for Pb(II) are considered to be acidic surface functional groups on the external and internal ...

2005-11-01

482

Radiation-induced reduction of ditetrazolium salt in aqueous solutions  

Energy Technology Data Exchange (ETDEWEB)

Color formation in aqueous solutions of the ditetrazolium salt blue tetrazolium (BT{sup 2+}) in the absence or presence of oxygen is a complex radiation chemical reaction. The final stable product is the poorly soluble diformazan violet to blue pigment having a broad spectral absorption band ({lambda}{sub max}=552 nm). The reaction of BT{sup 2+} with the hydrated electron proceeds by rapid reduction of BT{sup 2+} followed by protonation at the nitrogen closest to the unsubstituted phenyl group, via the two intermediate tetrazolinyl radicals shared by the ditetrazole ring nitrogens. The effect of solution pH, N{sub 2}O saturation, and the presence of the reducing agent dextrose are examined. The system serves as a radiochromic sensor and a dosimeter of ionizing radiations. Solutions of 5 mmol l{sup -1} BT{sup 2+} at pH 7.3 serve as dosimeters over an absorbed-dose range of approximately 0.2-6 kGy (dearated, with a range of 1-8 mmol l{sup -1} dextrose) and of about ...

2002-04-01

483

Radiation Chemistry of Aqueous Solutions Related to Nuclear Reactor Systems and Spent Fuel Management  

International Nuclear Information System (INIS)

In this thesis the rate constants for a number of radical reactions in aqueous solution have been studied in a wide temperature range. The reactions of H with H_2O_2, OH and HO_2 and the reactions of HO_2 with OH, Fe"2"+ and Cu"2"+ have been studied. For each reaction rate constants have been determined as a function of temperature using the technique of high temperature, high pressure (HTP) pulse radiolysis. The rate constants were obtained by fitting a kinetic computer model to the experimental data. From an Arrhenius plot the activation energy of each reaction was determined. The data determined in this way are important for modeling of radiolysis in nuclear light water reactors. A previously developed model for calculation of the effect of water radiolysis products on oxidation and dissolution of spent nuclear fuel has been improved. In the new model, called TraRaMo, simultaneous transport by diffusion and chemical reactions induced by radiolysis can be ...

2003-01-01

484

On the formation and extent of uptake of silver nanoparticles by live plants  

Energy Technology Data Exchange (ETDEWEB)

In this work we investigate the limits of uptake of metallic silver by two common metallophytes, Brassica juncea (BJ) and Medicago sativa (MS) and assess the form and distribution of the metal once sequestered by the plants. BJ accumulated up to 12.4 wt.% silver when exposed to an aqueous substrate containing 1,000 ppm AgNO{sub 3} for 72 h, however silver uptake was largely independent of exposure time and substrate silver concentration. MS accumulated up to 13.6 wt.% silver when exposed to an aqueous substrate containing 10,000 ppm AgNO{sub 3} for 24 h. In contrast to BJ there was a general trend for MS showing an increase in metal uptake with a corresponding increase in the substrate metal concentration and exposure time. In both cases the silver was stored as discrete nanoparticles, with a mean size of {approx}50 nm. According to the hyperaccumulation definition of Brooks et al. (Brooks RR, Chambers MF, Nicks LJ, Robinson BH (1998) ...

2008-04-15

485

Kinetics and mechanism of superoxide radical reactions with some biologically important compounds in aqueous solutions. Pulse radiolysis  

International Nuclear Information System (INIS)

Microsecond pulse radiolysis of oxygenated aqueous solutions containing 0.02 mol dm"-"3 sodium formate and 2 mmol dm"-"3 phosphate buffer at pH 7 was used to generate superoxide anion radicals. The influence of some biologically important compounds upon the rate of O_2"."-"b"a"r decay as monitored spectrophotometrically in the range of 245-300 nm. Hematoporphyrin (HP), hemin C (HC), catalase (Cat), cobalt sulfophthalocyanine (CoTSPc) were studied. Among the investigated compounds only Cat was found to show a high catalytic efficiency towards the self-decay of O_2"."-"b"a"r. A red shift of 0_2"."-"b"a"r absorption band and slowing down of its decay were observed to take place by adding HP or CoTSPc to the solutions containing formate ions in excess. This effect is associated with the formation of a transient superoxo-complex. An appearance of an intermediate species with absorption maxima at 350 nm and half-life of about 2 s was observed to accompany the ...

486

Integrated microelectrode arrays for trace-metal analysis of aqueous solutions  

Energy Technology Data Exchange (ETDEWEB)

Stripping Voltammetry (SV) at microelectrodes has gained increased interest in the analysis of aqueous solutions due to its ability to analyze low concentrations (ppb) of electroactive metallic species in solution. Existing integrated circuit (IC) technology allows the inexpensive fabrication of microelectrodes with dimensions on the order of microns and with a high degree of uniformity and reproducibility. Additional circuitry, both multiplexing and signal conditioning, can be placed directly onto the sensor offering increased sensitivity and flexibility. Multi-element electrochemical sensors containing arrays of Pt, Au, and Ag electrodes and capable of individual measurement through built-in multiplexing or simultaneous measurement at the appropriate potential ranges for each individual electrode were fabricated using existing 2 micron IC technology. Results of simultaneous measurements of low concentrations of Cd, Pb, Cu, As, and Hg in solution indicate that ...

1995-12-31

487

Extraction of molybdenum with a multielement liquid organic extraction system  

Science.gov (United States)

An extraction of molybdenum is described that provides a more predictable separation over a significantly wider acidity range than previously determined. The extraction of Mo appeared to be a function of HCl normality, with virtually complete separation above 3.6 N. A test was conducted to determine if the extraction was a function of just HCl concentration or of overall acidity. When the aqueous phases of the test sequence were all prepared at 1 N H/sub 2/SO/sub 4/ in addition to the HCl in each, the resulting extraction curves were essentially identical. Another test was performed to determine if Mo was being extracted as an iodide complex. Three aqueous solutions, which were 4 N in HCl and 26% (w/v) ascorbic acid, were prepared in culture tubes. When 25 ..mu..g of Mo was extracted from these solutions of 5 mL of organic phase, the KCl gave only a 16% extraction, the KBr gave only a 22% extraction, and the KI provided an essentially total ...

1985-10-01

488

Evaluation of small-angle neutron scattering curves of unilamellar phosphatidylcholine liposomes using a multi shell model of bilayer neutron scattering length density  

International Nuclear Information System (INIS)

Computer simulated small-angle neutron scattering curves of spherical poly disperse extruded unilamellar liposomes from saturated 1,2-diacylphosphatidylcholines in the aqueous phase are evaluated by using a multi shell model, which divides the lipid bilayer of liposomes into the polar head group region, and the nonpolar hydrocarbon region consisting of the chains of methylene groups and of the region of methyl groups. In the each of these regions, the coherent neutron scattering length density is supposed to by homogeneous. The evaluation is based on obtaining of radius of gyration from Kratky-Porod plot of small-angle neutron scattering data in the Guinier region of small scattering vector values. From radii of gyration obtained at several different molar fractions N_D_2_O/(N_D-2_O + N_H_2_O) in the aqueous phase (contrasts) and independent volumetric data, the lipid surface area A_L (or the bilayer thickness d_L) and the number of water ...

2000-12-15

489

Equilibrium, thermodynamic and kinetic studies for the biosorption of aqueous lead(II) ions onto the seed husk of Calophyllum inophyllum  

British Library Electronic Table of Contents (United Kingdom)

Biosorption of lead(II) ions from aqueous solution onto the seed husk of Calophyllum inophyllum was investigated in a batch system. Equilibrium, thermodynamics and kinetic studies were conducted by considering the effects of pH, initial metal ion concentration, contact time, and temperature. The results showed that the uptake of the metal ions increased with increase in initial metal ion concentration. The pH for optimum adsorption was 4 for the Pb(II) ions (q=4.86mg/g and 97.2% adsorption). Langmuir isotherm described the biosorption of Pb(II) ions onto the biomass (R^2=0.9531) better than the Freundlich model (R^2=0.7984), and the Temkin model (R^2=0.8761). Biosorption kinetics data obtained for the metal ions sorption were fitted using pseudo-first-order and pseudo-second-order. It was ...

2010-01-01

490

Enhancement of N-nitrosamine formation on granular-activated carbon from N-methylaniline and nitrite  

Energy Technology Data Exchange (ETDEWEB)

Sterile aqueous N-methylaniline solutions were allowed to equilibrate at various nitrite, F-400 granular-activated carbon, and pH levels for 1 week. The aqueous and activated carbon phases were extracted and analyzed for nitrosamines relative to an added internal standard. Selected ion monitoring GC/MS, utilizing continuous monitoring of the NO/sup +/ ion (m/z 29.9980) characteristic of nitrosamines, at medium resolution (R = 2500-3000) was applied to quantitatively measure nitrosamines at picograms per microliter concentrations. This method selected for nitrosamine products only and eliminated interferences from non-nitrosamine reaction products. Results indicate that the pressure of granular-activated carbon significantly enhanced the formation of nitrosamine from N-methyl-aniline (F = 145, P< 0.0001). The amount of N-nitrosomethylaniline formed in the presence of activated carbon was 75 times more than that formed in the absence of ...

1986-10-01

491

Electron spin resonance study of the equilibrium between tetrahalogeno- and pentahalogeno-nitridotechnetate (VI) ions in solution  

Energy Technology Data Exchange (ETDEWEB)

The e.s.r. spectra of (AsPh/sub 4/)(TcNCl/sub 4/), Cs/sub 2/(TcNCl/sub 5/), (AsPh/sub 4/)(TcNBr/sub 4/), and Cs/sub 2/(TcNBr/sub 5/) have been studied in non-aqueous and concentrated aqueous acid solutions. None of the spectra shows evidence for the co-ordination of a fifth halide ligand in the trans position, even under circumstances such as a 2 000-fold excess of halide ion, which would be expected to favour the formation of the pentahalogenonitridotechnetate ion. The predominant species in solution is the tetrahalogenonitridotechnetate ion, where the trans position may be vacant or occupied by a solvent molecule in the case of the non-aqeuous solvents and by a water molecule in the case of HCl and HBr solutions. This conclusion may be contrasted with the behaviour of a number of tetra- and penta-halogeno-oxometal complexes, where the equilibrium (MOX/sub 4/)sup(n-) + X/sup -/< - - > (MOX/sub 5/)sup(n + 1)/sup -/ is clearly established.

1987-07-01

492

Easy access to 6-membered iminoalditols - important glycosidase inhibitors  

DEFF Research Database (Denmark)

Stereoselective methods for synthesising iminoalditols are still needed, as this class of compounds is known to contain strong glycosidase inhibitors. We have for some time investigated (1) the possibilities for using 2-amino-6-bromo-2,6-dideoxy-aldonolactones as starting materials for such compounds, since a substitution at C-6 by the 2-amino group should lead to the target molecules. We have found that treatment of mentioned 2-aminolacones with aqueous base gave 5- or 6-membered iminoalditols depending of the stereochemistry of the lactone, while under non aqueous conditions only formation of 6-membered iminoalditols were observed. The use of triethylamine in methanol thus gave methylesters of 6-membered iminouronic acids. Reduction of the ester group with sodium borohydride gave the target compounds. The mechanisms of the reactions will be discussed as well as specific results obtained. (1) Lundt, I. Top. Curr. Chem. 1997, 187, 117-156

493

Direct liquefication of coal  

Energy Technology Data Exchange (ETDEWEB)

A patent is claimed for a direct coal liquefication process which is carried out by interaction with a paste, consisting of small-fragment coal, oil and catalysts, with H/sub 2/ at increased temperatures and pressures. The catalyst is a mixture of 1 part per weight of Fe-ore that's been activated by aqueous treatment, and 0.1-1.0 powder-form S. The Fe-ore can be magnetite, limonite, hematite, pyrite, ferrous sand or ''red mud'' (byproduct of the Bayer process), with the ''red mud'' and limonite, having a particle size of about 100 mesh is preferable. Activation of Fe-ore includes aqueous treatment in boiling water for 30-120 min with subsequent drying; annealing at a temp. of 300-700/sup 0/C for 10-120 min; submerging into cold water and final drying. The catalyst is added to the paste in the amount of 0.03-0.3 parts per weight to one part of fine coal. This ...

1982-06-22

494

Catalytic behavior of Co/(Nanob-Zeolite) bifunctional catalysts for Fischer-Tropsch reactions  

British Library Electronic Table of Contents (United Kingdom)

Cobalt supported on Beta zeolite catalysts were prepared by impregnation of metal salts in aqueous solution and were tested for the Fischer Tropsch reaction. The support consisted of a Beta zeolite composed by crystallites of nanometric dimensions and a SiO2/Al2O3 molar ratio of about 50. This support was impregnated with Co(NO3)2 aqueous solution using different metal loads of 7.5, 10, 15 and 20wt% Co. These materials were characterized by X-ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM), N2 adsorption (BET), thermal programmed reduction (TPR) and FTIR of adsorbed pyridine (i.e., surface acid sites distribution). All the catalysts showed a significant catalytic activity for the F-T reaction from synthesis gas (CO+2H2), in a continuous fixed bed reactor sys...

2011-01-01

495

Binary copper(II) and uranyl(VI) complexes of glycocyamine, taurine and pyridoxal and ternary complexes involving 2,2'-bipyridine, 1,10-phenanthroline or nitrilotriacetic acid  

International Nuclear Information System (INIS)

Chelating tendencies of several biologically important compounds viz. glycocyamine (GCN: N-amidino-aminoethanoic acid) taurine (TRN: 2-aminoethanesulphonic acid) and pyridoxal [PDL: 3-hydroxy-5-(hydroxymethyl)-2-methyl-pyridine-4-carbaldehyde] have been examined by pH-metric titration technique in their binary complex formation with copper(II) and uranyl(VI) ions. The work has further been extended to investigating the ternary complex formation involving 2.2'-bipyridine. 1,10-phenanthroline or nitrilotriacetic acid as a primary and TRN and PDL as secondary ligands. All the experiments were carried out at 25"0C and at an ionic strength of 0.1M (NaCl0_4) in aqueous or 50% (v/v) aqueous-ethanol medium according to the suitability of the experimental conditions. Stabilities of ternary complexes as compared to those of the corresponding binary complexes of the secondary ligands have also been discussed. (author).

496

Behavior of tritium in the Purex process  

Energy Technology Data Exchange (ETDEWEB)

The tri-n-butyl phosphate(TBP) extraction behavior of tritium was studied to support the evaluation of tritium confinement in the Purex process. The tritium distribution ratio in the system of U - 30% TBP/n-dodecane(nDD) - HNO[sub 3] [minus]H[sub 2]O was measured in batch-wise experiments. The tritium decontamination factor in a tritium scrubbing step was measured in chemical flow sheet experiments using a 6 stage mixer-settler having an internal recycle system of aqueous solution in each stage. Tritium was mainly extracted in the forms of water and nitric acid in the system. Less than 1% of the amount of tritium in the organic phase was fixed in the degradation products of the solvent. A tritium decontamination factor of about 500 in the tritium scrubbing step was obtained under the conditions of about 85 g-U/dm[sup 3] of uranium concentration in the irradiated solvent(30% TBP/nDD), 3 M nitric acid in the tritium scrubbing solution and an organic: ...

1995-01-01

497

Assessment and influence of operational parameters on the TiO_2 photocatalytic degradation of sodium benzene sulfonate under highly concentrated solar light illumination  

International Nuclear Information System (INIS)

Sodium benzene sulfonate (BS) was decomposed in aqueous TiO_2 dispersions under highly concentrated solar light illumination to examine the photocatalytic characteristics of a parabolic round concentrator (PRC) reactor to degrade the pollutant without visible light absorption. The effects of such operational parameters as initial concentration, volume of the aqueous BS solution, oxygen purging, and TiO_2 loading on the kinetics of decomposition of BS were investigated. An effective photodegradation necessitates a suitable combination of initial volume and concentration of BS solution. Relative to atmospheric air, oxygen purging significantly accelerates the degradation process at high initial concentrations of BS (0.40 mM or 1.0 mM). Optimal TiO_2 loading was 9 gl "-"1, greater than previously reported. Elimination of TOC (total organic carbon) followed pseudo first-order kinetics in the initial stages of the photodegradation process. The ...

498

Analgesic activity of the aqueous fraction from the ethanolic extract of Chrysanthemum indicum in mice.  

Science.gov (United States)

The aqueous fraction (AF) of an ethanolic extract from Chrysanthemum indicum was evaluated for analgesic activity in mice using chemical and thermal models of nociception. Given orally, AF at doses of 300 and 600 mg/kg produced significant inhibitions on chemical nociception induced by intraperitoneal acetic acid, subplantar formalin/capsaicin injections and on thermal nociception in the tail-flick test and in the hot plate test. In the pentobarbital sodium-induced sleeping time test and the open-field test, AF neither significantly enhanced the pentobarbital sodium-induced sleeping time nor impaired the motor performance, indicating that the observed analgesic activity was unlikely due to sedation or motor abnormality. In a measurement of core body temperature, AF did not affect temperature within 80 min. Moreover, the effective dose (600 mg/kg) also showed no toxicity within 7 days. These results suggested further that AF produced analgesic activity possibly ...

2011-07-01

499

An electron spin resonance study of the equilibrium between tetrahalogeno- and pentahalogeno-nitridotechnetate (VI) ions in solution  

International Nuclear Information System (INIS)

The e.s.r. spectra of [AsPh_4][TcNCl_4], Cs_2[TcNCl_5], [AsPh_4][TcNBr_4], and Cs_2[TcNBr_5] have been studied in non-aqueous and concentrated aqueous acid solutions. None of the spectra shows evidence for the co-ordination of a fifth halide ligand in the trans position, even under circumstances such as a 2 000-fold excess of halide ion, which would be expected to favour the formation of the pentahalogenonitridotechnetate ion. The predominant species in solution is the tetrahalogenonitridotechnetate ion, where the trans position may be vacant or occupied by a solvent molecule in the case of the non-aqeuous solvents and by a water molecule in the case of HCl and HBr solutions. This conclusion may be contrasted with the behaviour of a number of tetra- and penta-halogeno-oxometal complexes, where the equilibrium [MOX_4]sup(n-) + X"-< - - > [MOX_5]sup(n + 1)"- is clearly established. (author).

500

A study on the photocatalytic decomposition reactions of organics dissolved in water (II)  

Energy Technology Data Exchange (ETDEWEB)

Experiments on aqueous TiO{sup 2} photocatalytic reaction characteristics of 4 nitrogen-containing and 12 aromatic organic compounds were carried out. Based on the values calculated for the distribution of ionic species and atomic charge, the characteristics of their photocatalytic decomposition were estimated. It was shown that the dependence of decomposition of the N-containing compounds were linearly proportional to their nitrogen atomic charge values, while that of the aromatic compounds were inversely proportional. The effects of aqueous pH, oxygen content and concentration on the TiO{sup 2} photocatalytic characteristics of EDTA-Cu(II) and EDTA-Fe(III) were experimentally investigated. All EDTA systems were decomposed better in the pH range of 2.5{approx}3.0 and with more dissolved oxygen. These results could be applied to a unit process for removal of organic impurities dissolved in a source water of the system water, and for treatment ...

2001-01-01