Energy Technology Data Exchange (ETDEWEB)

An axisymmetric unit cell model based on a regular array of second-phase particles arranged on a BCC lattice is used to study deformation mechanisms of ferrite-pearlite structural steels. Microstructural characteristics of the steels were parameterized by the pearlite volume fraction, the aspect ratio of the pearlite particles, and the neighboring factor, which represents the ratio of interparticle spacing in the longitudinal direction to that in the transverse direction. FE analyses were carried out to investigate the macroscopic and microscopic response of unit cells with morphological features based on idealizations of the microstructures of the actual steels. Tensile properties of each constituent phase were obtained experimentally and used in the analyses. As compared to traditional axisymmetric models, the BCC tell model appears to be able to capture more realistically the ...

CERN Document Server

This paper proposes the use of particle swarm optimization method (PSO) for finite element (FE) model updating. The PSO method is compared to the existing methods that use simulated annealing (SA) or genetic algorithms (GA) for FE model for model updating. The proposed method is tested on an unsymmetrical H-shaped structure. It is observed that the proposed method gives updated natural frequencies the most accurate and followed by those given by an updated model that was obtained using the GA and a full FE model. It is also observed that the proposed method gives updated mode shapes that are best correlated to the measured ones, followed by those given by an updated model that was obtained using the SA and a full FE model. Furthermore, it is observed that the ...

Energy Technology Data Exchange (ETDEWEB)

From a macroscopic point of view, corrosion of Zn alloy coated steel sheet occurs by the coating preceding corrosion mechanism; microscopically, however, the coated layer corrosion velocity in the tip of corrosion is different. In order to find the main factors of under-film corrosion of Zn and Zn-Fe alloy coatings in the salt water spray atmospheric exposure test, the correlation between point inflation-exfoliation width and chlorine penetration behavior, point adhesion, and the difference in chlorine penetration behavior due to alloy coating components were investigated. Consequently, the following results were obtained: 1. The better correlation was observed between chlorine penetration distance and point inflation-point exfoliation width. 2. The durability of coating against chlorine penetration improved by increase in point adhesion and Zn content in the coating layer. 3. Zn-Fe (10-20%) alloy coating showed better ...

International Nuclear Information System (INIS)

Favorable reaction channels are searched for in order to obtain the superheavy element "2"9"8114. The interaction energy is supposed to comply with the adiabatic hypothesis. Concerning the deformation energy, a very complete binary macroscopic-microscopic energy method is used to perform calculations. Deformed two-center shell model provides the energy level schemes for shell effects. Yukawa-plus-exponential model gives the macroscopic (liquid drop) part of the total energy. The mass tensor is obtained by the Werner-Wheeler irrotational flow hypothesis. Finally the minimization of the multidimensional action integral produces the highest penetrability values. Kr-projectile reactions provide the best pairs, although generally the presentabilities are very low. (author)

International Nuclear Information System (INIS)

We have constructed a mathematical model that describes the coherent spontaneous radiation of a macroscopically filled exciton mode. We have demonstrated qualitatively ways in which a coherent subsystem of excitons can be formed. When this occurs under the influence of an external coherent source, exciton free induction occurs, while in the case of a spontaneous transition of the excitons to a coherent state through freezing of the reservoir of intermolecular interactions superradiance occurs. We have concluded that superradiance in the system of Frenkel excitons is possible under the influence of the non-Dicke mechanisms of self-induction of correlations, when the dipole transition moments of the individual atoms are coupled into a single macroscopic effective spin through their electrostatic interaction, this being analogous to the ordering of magnetic dipole moments in a ferromagnet.

CERN Document Server

We present constraints on theoretical models of Type Ia SNe using spatially resolved ASCA X-ray spectroscopy of four galaxy clusters: Abell 496, Abell 2199, Abell 3571 & Perseus. All four clusters have central Fe abundance enhancements and an ensemble of abundance ratios are used to show that most of the Fe in the central regions of the clusters comes from SN Ia. At the center of each cluster, simultaneous analysis of spectra from all ASCA instruments shows that the Ni to Fe abundance ratio (normalized by the solar ratio) is ~ 4. We use the Ni/Fe ratio as a discriminator between SN Ia explosion models: the Ni/Fe ratio of ejecta from the "Convective Deflagration" model W7 is consistent with the observations, while those of "delayed detonation" models are not consistent at the 90% confidence level.

Science.gov (United States)

In this article, we describe an approach to model the electromechanical behavior of the skeletal muscle based on the Huxley formulation. We propose a model that complies with a well established macroscopic behavior of striated muscles where force-length, force-velocity, and Mirsky-Parmley properties are taken into account. These properties are introduced at the microscopic scale and related to a tentative explanation of the phenomena. The method used integrates behavior ranging from the microscopic to the macroscopic scale, and allows the computation of the dynamics of the output force and stiffness controlled by EMG or stimulation parameters. The model can thus be used to simulate and carry out research to develop control strategies using electrical stimulation in the context of rehabilitation. Finally, through animal experiments, we estimated model parameters ...

UK PubMed Central (United Kingdom)

Francisella tularensis requires iron (Fe) for growth, but the biologic sources of Fe for this organism are largely unknown. We found that Francisella sp. growing in...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Fuel cell vehicles have been identified as the personal transportation technology of the future because of their high efficiency and very low emissions. To achieve the goal of road-ready fuel cell vehicles, great strides must be made in the development of fuel cells, hydrogen production and hydrogen storage technologies, that includes metal-H interaction studies and safety considerations. The interaction between two-hydrogen atoms and a {gamma}-Fe structure containing a vacancy has been studied using a cluster model and a theoretical method. For the study of the sequential absorption, the hydrogen atoms were positioned in their energy minima configurations, near the vacancy. The interactions mainly involve Fe 4s-H 1s atomic orbitals. The contribution of Fe 4p and Fe 3d orbitals is much less important. The Fe-Fe bond is weakened as new Fe-H-H ...

International Nuclear Information System (INIS)

In this work, the pulse plasma nitriding process of pure iron is modelled using a kinetic model derived from the Fick's laws. This approach based on the error function model allows to simulate the growth kinetics of a biphase configuration consisting of #gamma#'-Fe_4N_1_-_x and #epsilon#-Fe_2_-_3N iron nitrides under specified conditions. By coupling the kinetics data about the diffusivities of nitrogen in #alpha#-Fe, #gamma#' and #epsilon# phases to the thermodynamic description of the Fe-N phase diagram, it is possible to evaluate the kinetic constant at each growing phase interface, the thickness of nitrided layer, and predict the nitrogen concentration profiles. The comparison between the experimental and theoretical results shows the reliability of the simulation results.

International Nuclear Information System (INIS)

"9Be-induced inelastic scattering of "6"2","6"4","6"6Fe and "6"0","6"2","6"4Cr was performed at intermediate beam energies. Excited states in "6"4Cr were measured for the first time. Energies and population patterns of excited states in these neutron-rich Fe and Cr nuclei are compared and interpreted in the framework of large-scale shell-model calculations in different model spaces. Evidence for increased collectivity and for distinct structural changes between the neighboring Fe and Cr isotopic chains near N=40 is presented.

CERN Document Server

Liquid-liquid wetting failure is investigated in a two-dimensional Couette system with two immiscible fluids of arbitrary viscosity. The problem is solved exactly using a sharp interface treatment of hydrodynamics (lubrication theory) as a function of the capillary number, viscous ratio and separation of scale, i.e. slip length versus macroscopic scale of the system. The existence of critical velocities, above which no stationary solutions are found, is analyzed in detail in terms of the relevant parameters of the system. Comparisons with existing analysis for other geometries are also carried out. A numerical method of analysis is also presented, based on diffuse interface models obtained from multiphase extensions of the lattice Boltzmann equation (LBE). Sharp interface and diffuse interface models are quantitatively compared face to face indicating the correct limit of applicability of the diffuse interface ...

International Nuclear Information System (INIS)

The determination of ratio of neutron over proton matrix elements by inelastic proton scattering, for 0"+#->#2"+ transitions, is investigated via the comparison between experimental data and theoretical calculations. Calculations into the context of a macroscopic and a microscopic description are performed for a wide mass range nuclei: "1"8O, "3"0Si, "3"2","3"4S, "4"8Ca, "8"8Sr, for which these ratios were determined previously with an independent technique. At that point the choice of the theoretical model may be very critical. It is thus the purpose of this investigation to point out the most suitable model. It is found that in general both theoretical models can be employed for the reliable determination of neutron over proton matrix element ratios.

Energy Technology Data Exchange (ETDEWEB)

Research highlights: {yields} The use of resonant photoemission in its 'core-hole clock' expression for the study of the dynamical charge transfer across hybrid organic-inorganic interfaces and for the intermolecular charge transfer in the bulk of organic thin films is reviewed. {yields} The electronic coupling to the substrate and the efficiency of charge transport across hybrid interfaces is different for individual electronic subsystems of the molecular adsorbate. {yields} The intermolecular charge transfer in the bulk of discotic liquid crystals occurs on the order of a few femtoseconds and is faster than expected from the macroscopic charge transport characteristics of the material. -- Abstract: The focus of this brief review is the use of resonant photoemission in its 'core-hole clock' expression for the study of two important problems relevant for the field of organic electronics: the dynamical charge transfer across ...

International Nuclear Information System (INIS)

The neutron-rich Fe isotopes from A=61 to 66 were studied through multinucleon transfer reactions by bombarding a "2"3"8U target with a 400 MeV "6"4Ni beam. Unambiguous identification of prompt #gamma# rays belonging to each nucleus was achieved using coincidence relationships with the ions detected in a high-acceptance magnetic spectrometer. The new data extend our knowledge of the level structure of Fe isotopes, which is discussed in terms of the systematics of the region and compared with large-scale shell-model calculations.

International Nuclear Information System (INIS)

The dependence of the carrier concentrations, of the resistivity and of the Hall coefficient of irradiated silicon on the neutron fluences has been investigated, starting from the supposition that the main phenomena induced by irradiation in the semiconductor bulk are shallow-donor removal and deep-centres creation. The free parameters of the model are initial doping of the starting material, the permitted energy level values of the radiation-induced centres in the semiconductor band gap and their introduction rates. The influence of each parameter on the calculated dependences is studied in detail, for three cases: one deep acceptor-like centre, two deep acceptors and one deep acceptor plus one deep donor-like centre. each of the three cases is discussed in correspondence with different experimental results.

Science.gov (United States)

This paper describes the anelastic strain recovery and the strain hardening of amorphous metals and presents the experimental result that creep deformation is represented by a viscoelastic model consisting of rheological elements. Materials studied were 80Pd--20Si, 80Fe--13P--7C, and 60 Cu--40 Zr. (DLC)

Science.gov (United States)

This study addresses the modeling of transdermal diffusion of drugs, to better understand the permeation of molecules through the skin, and especially the stratum corneum, which forms the main permeation barrier of the skin. In transdermal delivery of systemic drugs, the drugs diffuse from a patch placed on the skin through the epidermis to the underlying blood vessels. The epidermis is the outermost layer of the skin and can be further divided into the stratum corneum (SC) and the viable epidermis layers. The SC consists of keratinous cells (corneocytes) embedded in the lipid multi-bilayers of the intercellular space. It is widely accepted that the barrier properties of the skin mostly arises from the ordered structure of the lipid bilayers. The diffusion path, at least for lipophilic molecules, seems to be mainly through the lipid bilayers. Despite the advantages of transdermal drug delivery compared to other drug delivery routes such as oral dosing and ...

International Nuclear Information System (INIS)

Substantial roles of precipitates such as Zr-Fe-Cr type intermetallic compounds on uniform corrosion and hydrogen pickup of zirconium alloys in pure water autoclave tests were investigated from an electrochemical point of view. In the previous paper, corrosion mechanism was elucidated by the anodic protection-precipitates degradation model. This paper describes the roles on hydrogen pickup. 633 K pure water autoclave test was performed on high purity zirconium, Zr-0.2Fe, Zr-0.2Cr, and Zr-0.1Fe-0.1Cr alloys. Hydrogen analysis after the corrosion test showed that hydrogen pickup ratio of Zr-0.2Fe alloy was about 80%. It was much higher than about 30% of pure Zr and about 10% of both Zr-0.2Cr and Zr-0.1Fe-0.1Cr alloys. Larger hydrogen content was introduced into Zr-0.2Fe alloy than the other ones by the cathodic hydrogen charging under ...

British Library Electronic Table of Contents (United Kingdom)

Objective: : Evaluate expression of inducible negative regulators of JAK/STAT pathway and their target proteins during the course of ligature-induced experimental periodontal disease in rats. Design: : Rats were sacrificed 07, 15 and 30days after disease induction for histological evaluation of periodontal inflammation and macroscopic analysis of alveolar bone loss. SOCS expression and the activation status of STAT1 and STAT3 were evaluated in gingival biopsies by real time PCR and Western blot. Results: : Ligature-induced model presented significant progressive bone loss from 7 to 30days. Inflammation was evident and similar for 07 and 15days; however, a decrease on severity at the end of the experimental period was observed. There was a significant (p<0.05) increase on SOCS1 and SOCS3 ge...

International Nuclear Information System (INIS)

We present results of multiple-time-scale simulations of 5, 10 and 15 keV low temperature ion implantation of arsenic on silicon (100), followed by high temperature anneals. The simulations start with a molecular dynamics (MD) calculation of the primary state of damage after 10ps. The results are then coupled to a kinetic Monte Carlo (MC) simulation of bulk defect diffusion and clustering. Dose accumulation is achieved considering that at low temperatures the damage produced in the lattice is stable. After the desired dose is accumulated, the system is annealed at 800 degrees C for several seconds. The results provide information on the evolution for the damage microstructure over macroscopic length and time scales and affords direct comparison to experimental results. We discuss the database of inputs to the MC model and how it affects the diffusion process.

International Nuclear Information System (INIS)

Surface analytical studies of high nitrogen austenitic stainless steels exposed to deaerated 0.1M HCl have revealed that nitrogen alloying additions influence the composition of salt layers and the passive film/alloy interface. In this study the authors employ electrochemical techniques and variable angle X-ray Photoelectron Spectroscopy (XPS) to examine the passive films formed on a series of austenitic stainless steels, Fe18Cr8Ni, Fe18Cr8Ni0.2N, Fe20Cr20Ni, Fe20Cr20Ni6Mo and Fe20Cr20Ni6Mo0.2N, in acidic chloride aqueous solution. In addition, several other model alloys, Fe19Cr, Fe19Cr9Ni, Fe19Cr2.5Mo, and Fe19Cr9Ni2.5Mo, were examined before and after electrochemical surface nitriding, a technique proven to have an effect analogous to N alloying. It was shown that nitrogen, ...

International Nuclear Information System (INIS)

We investigate the effects of single-particle structure and pairing on the equilibration of positive and negative-parity level densities for the even-even nuclei "5"8","6"2","6"6Fe and "5"8Ni and the odd-A nuclei "5"9Ni and "6"5Fe. Calculations are performed using the shell model Monte Carlo method in the complete fp-gds shell-model space using a pairing+quadrupole type residual interaction. We find for the even-even nuclei that the positive-parity states dominate at low excitation energies due to strong pairing correlations. At excitation energies at which pairs are broken, single-particle structure of these nuclei is seen to play the decisive role for the energy dependence of the ratio of negative-to-positive parity level densities. We also find that equilibration energies are noticeably lower for the odd-A nuclei "5"9Ni and "6"5Fe than for the neighboring even-even nuclei "5"8Ni ...

Energy Technology Data Exchange (ETDEWEB)

In the present dissertation, a hierarchical multiscale approach for modeling FePt nanoparticles by atomistic computer simulations is developed. By describing the interatomic interactions on different levels of sophistication, various time and length scales can be accessed. Methods range from static quantum-mechanic total-energy calculations of small periodic systems to simulations of whole particles over an extended time by using simple lattice Hamiltonians. By employing these methods, the energetic and thermodynamic stability of non-crystalline multiply twinned FePt nanoparticles is investigated. Subsequently, the thermodynamics of the order-disorder transition in FePt nanoparticles is analyzed, including the influence of particle size, composition and modified surface energies by different chemical surroundings. In order to identify processes that reduce or enhance the rate of transformation from the ...

Energy Technology Data Exchange (ETDEWEB)

The possibility of improving the cold formability of wrought magnesium alloys is considered in light of their good hot forming characteristics. Magnesium alloy AZ31B sheet is selected as a model system. Parameters affecting formability, such as strain hardening rate, strain rate sensitivity, and the degree of anisotropy are examined systematically by conducting tensile tests over a range of temperatures (room temperature to 250 C) and strain rates (1 x 10{sup -5} to 0.1 s{sup -1}). The plastic anisotropy and deformation texture evolution are examined in samples aligned with the sheet rolling and transverse directions. Polycrystal plasticity simulations using a viscoplastic self-consistent (VPSC) formulation are used to model the observed anisotropy and texture evolution. The adjustable parameters in the model are the relative critical resolved shear stresses of the dislocation mechanisms known to operate within magnesium. ...

Energy Technology Data Exchange (ETDEWEB)

XVTa and XXTa nuclei were oriented at low temperature as dilute impurities in Fe. The magnetic hyperfine splitting frequencies = B sub(HF)/Ih of the XVTa and XXTa ground states have been measured to be 320.45(11) and 317.552(55) MHz by using the technique of NMR-ON. Taking the known hyperfine field of Y Ta in Fe, the magnetic moments have been deduced: ( XVTa, 7/2 ) =2.270(45) and ( XXTa, 7/2 ) =2.250(45) sub(N). These values of the magnetic moments are discussed in the framework of the rotational model.

Energy Technology Data Exchange (ETDEWEB)

Differential cross sections for 201.5 MeV proton scattering form /sup 88/Sr were measured. From the analysis of the elastic data, no unique optical-model potential could be obtained, but the radial moments are well determined. In a macroscopic analysis of the collective states it turns out that if the optical potential and transition potential are chosen consistently, unambiguous potential deformation lengths can be obtained even though the optical potential is not unique. Taking into account the range and density dependence of the underlying effective interaction reliable neutron deformation lengths can be obtained. For inelastic transitions of various character microscopic distorted-wave calculations with a density-dependent interaction based on the Paris potential were performed. The nuclear structure was taken from one broken-pair calculations in a large model space, calibrated by (e,e') data. In general a good ...

CERN Document Server

n an early approach, we proposed a kinetic model with multiple translational temperature [K. Xu, H. Liu and J. Jiang, Phys. Fluids {\\bf 19}, 016101 (2007)], to simulate non-equilibrium flows. In this paper, instead of using three temperatures in $x-$, $y-$, and $z$-directions, we are going to further define the translational temperature as a second-order symmetric tensor. Based on a multiple stage BGK-type collision model and the Chapman-Enskog expansion, the corresponding macroscopic gas dynamics equations in three-dimensional space will be derived. The zeroth-order expansion gives the 10 moment closure equations of Levermore [C.D. Levermore, J. Stat. Phys {\\bf 83}, pp.1021 (1996)]. To the 1st-order expansion, the derived gas dynamic equations can be considered as a regularization of Levermore's 10 moments equations. The new gas dynamic equations have the same structure as the Navier-Stokes equations, but the stress ...

CERN Document Server

Galactic open clusters are since long recognized as one of the best tools for investigating the radial distribution of iron and other metals. We employed FLAMES at VLT to collect UVES spectra of bright giant stars in a large sample of open clusters, spanning a wide range of Galactocentric distances, ages, and metallicities. We present here the results for four clusters: Berkeley 20 and Berkeley 29, the two most distant clusters in the sample; Collinder 261, the oldest and the one with the minimum Galactocentric distance; Melotte 66. Equivalent width analysis was carried out using the spectral code MOOG and Kurucz model atmospheres to derive abundances of Fe, Al, Mg, Si, Ca, Ti, Cr, Ni, Ba; non-LTE Na abundances were derived by direct line-profile fitting. We obtain subsolar metallicities for the two anticenter clusters Be 20 ([Fe/H]=-0.30, rms=0.02) and Be 29 ([Fe/H]=-0.31, rms=0.03), and for Mel 66 ...

International Nuclear Information System (INIS)

A spectroscopic study is performed for high spin states of "5"5Fe, "5"5Co and "5"7Ni. To populate the investigated residues with a relevant cross section, the fusion evaporation reactions of "3"0Si("2"8Si, 2pn)"5"5Fe, "3"0Si("2"8Si, 2pn)"5"5Co and "4He("5"4Fe, n)"5"7Ni were chosen. To identify the new #gamma# transitions and to build the energy level schemes, #gamma#-#gamma# coincidence techniques together with excitation functions were employed. Angular distributions and #gamma#-#gamma# angular correlations allowed us to assign the spin values of the nuclear states. The previous level scheme of "5"5Fe is extended into the region between 6.5-11 MeV of excitation energy, up to spin 27/2, while the yrast decay pathos of "5"7Ni and "5"5Co are reported here for the first time. Experimental data are fairly well reproduced by Glaudemans' shell model calculations. (orig.).

UK PubMed Central (United Kingdom)

The authors describe the development of a four-dimensional atlas and reference system that includes both macroscopic and microscopic information on structure and function of the human brain in persons...Full Text Available

CERN Document Server

The detailed formulation for loop quantum cosmology (LQC) in the Bianchi I model with a scalar massless field has been constructed. In this paper, its effective dynamics is studied in two improved strategies for implementing the LQC discreteness corrections. Both schemes show that the big bang is replaced by the big bounces, which take place up to three times, once in each diagonal direction, when the area or volume scale factor approaches the critical values in the Planck regime measured by the reference of the scalar field momentum. These two strategies give different evolutions: In one scheme, the effective dynamics is independent of the choice of the finite sized cell prescribed to make Hamiltonian finite; in the other, the effective dynamics reacts to the macroscopic scales introduced by the boundary conditions. Both schemes reveal interesting symmetries of scaling, which are reminiscent of the relational interpretation of quantum ...

Energy Technology Data Exchange (ETDEWEB)

The macroscopic behavior of magnetostrictive materials results from domain evolutions occurring at a microscopic scale. The author shows how to compute magnetization and magnetostriction curves by appraising the behavior of the underlying microstructures. The method hinges on an averaging device (Young measures), which allows one to pass from the microscopic to the macroscopic scale. He takes into account the kinematical constraints on the accommodation of elastic effects, and he highlights the role of material symmetry in the selection of energetically optimal microstructures.

International Nuclear Information System (INIS)

We investigate the dynamics of an 11-dimensional homogeneous cosmological model. We assume that the t = const hypersurfaces are products of a 3-dimensional Bianchi type-IX space and a 7-dimensional torus. Most results of our investigation hold when the 7-dimensional torus is replaced by an m-dimensional torus T/sup m/. We show that for a large class of vacuum solutions the physical space expands while the microspace contracts providing a natural mechanism of dimensional reduction. Matter satisfying a simple barotropic equation of state always breaks the process of dynamical dimensional reduction. With special attention we study the behavior of our model close to the initial singularity. In contrast with the 4-dimensional Bianchi type-IX cosmological model the Kasner solution always describes an approach to the initial singularity. We study the transition from the Kasner regime to the oscillatory regime. We show that matter ...

International Nuclear Information System (INIS)

The purpose of this paper is to demonstrate how recent experimental results of "1"5"1Eu and "5"7Fe high pressure Moessbauer studies in 4f and 3d metallic magnetic systems can contribute to a deeper understanding of the nature of local moment (4f) and itinerant (3d) magnetism in these systems. Special emphasis is given on the comparison of the experimental results with related theoretical models. (orig.).

CERN Document Server

We study spectroscopically determined iron abundances of 642 solar-type stars to search for the signature of accreted iron-rich material. We find that the metallicity [Fe/H] of a subset of 466 main sequence stars, when plotted as a function of stellar mass, mimics the pattern seen in lithium abundances in open clusters. Using Monte Carlo models we find that, on average, these stars have accreted about 0.4 Earth masses of iron while on the main sequence. A much smaller sample of 19 stars in the Hertzsprung gap, which are slightly evolved and whose convection zones are significantly more massive, have lower average [Fe/H], and their metallicity shows no clear variation with stellar mass. These findings suggest that terrestrial-type material is common around solar type stars.

International Nuclear Information System (INIS)

"1"7"5Ta and "1"7"7Ta nuclei were oriented at low temperature as dilute impurities in Fe. The magnetic hyperfine splitting frequencies #nu#="+#mu#B sub(HF)/Ih"+ of the "1"7"5Ta and "1"7"7Ta ground states have been measured to be 320.45(11) and 317.552(55) MHz by using the technique of NMR-ON. Taking the known hyperfine field of "1"8"1Ta in Fe, the magneticmoments have been deduced: "+#mu#("1"7"5Ta, 7/2"+)"+=2.270(45) and "+#mu#("1"7"7Ta, 7/2"+)"+=2.250(45)#mu# sub(N). These values of the magnetic moments are discussed in the framework of the rotational model. (author).

Energy Technology Data Exchange (ETDEWEB)

Passive films formed on Alloy 690 in different pH solutions at high temperatures were studied by potentiodynamic polarization, Auger electron spectroscopy, thermodynamic diagrams and the Mott-Schottky relation. The chemical compositions and electronic structures of the passive films were found to be strongly pH-dependent. In alkaline solutions, a secondary passivation was clearly observed on potentiodynamic polarization curves. The passive films were a mixture of Cr{sub 2}O{sub 3} and FeCr{sub 2}O{sub 4} below the flat band potential of nickel oxide and were NiFe{sub 2}O{sub 4} above this potential. Electronic structure models, describing the electrochemical properties of the passive films, are proposed and discussed.

Energy Technology Data Exchange (ETDEWEB)

The use of chemically selective laser ionization combined with {beta} -delayed neutron counting at CERN/ISOLDE has permitted identification and half-life measurements for 623-ms {sup 61}Mn up through 14-ms {sup 69}Mn . The measured half-lives are found to be significantly longer near N=40 than the values calculated with a quasiparticle random-phase-approximation shell model. Gamma-ray singles and coincidence spectroscopy has been performed for {sup 64,66}Mn decays to levels of {sup 64,66}Fe , revealing a significant drop in the energy of the first 2{sup +} state in these nuclides that suggests an unanticipated increase in collectivity near N=40 . {copyright} {ital 1999} {ital The American Physical Society }

Energy Technology Data Exchange (ETDEWEB)

Seasonal traffic on intercity corridors often creates severe congestion at various bottlenecks, such as land-drops and drawbridges. A Traffic Simulation And Optimization model (TSAO) has been developed in order to 1) evaluate traffic impacts (including travel time, vehicle operating costs, accidents, air pollution and fuel consumption) of a given routing pattern on a network, and 2) determine the optimal flow pattern. In its latest version, the TSAO model uses: 1) a macroscopic simulation approach to trace vehicle platoons through a network; 2) Greenshield's equation to represent volume-speed relationship on freeways and multi-lane highways, and Highway Capacity Manual method for two-lane rural highways; 3) Lighthill's shockwave function to simulate queue propagation; 4) event-scan time management for simulation; 5) variable link capacity for two-lane rural highways or to stimulate incidents; 6) AASHTO ...

International Nuclear Information System (INIS)

Minor M (M = Fe, Mn, Cr) additions are widely added to enhance the corrosion resistance of commercial cupronickel alloys. The present paper aims at optimizing the amounts of M in Cu_7_0(Ni,Fe,Mn,Cr)_3_0 (at.%) alloys using a cluster-plus-glue-atom model for stable solid solutions. By this model, it assumed that 1 M atom and 12 Ni atoms formed an M-centered and Ni-surrounded cube-octahedron cluster and the isolated M_1Ni_1_2 clusters are embedded in a Cu matrix, conforming to a cluster formula [M_1Ni_1_2]Cu_3_0_._3 = [M_1_/_1_3Ni_1_2_/_1_3]_3_0Cu_7_0. A structure of this kind satisfies ideally the nearest neighbor requirement, i.e. only M-Ni and Ni-Cu neighbors are allowed and the unfavorable Cu-M pairs are avoided, and hence it describes a stable solid solution structure with good thermal stability. Electrochemical corrosion measurements indicated that ...

International Nuclear Information System (INIS)

Fe-Cu binary alloys are often used to mimic the behaviour of reactor pressure vessel steels. Their study allows identifying some of the defects responsible for irradiation-induced hardening. But recently the influence of manganese and nickel in low-Cu steels has been found to be important as well. In contrast with existing models found in the literature, which predict that hardening saturates after a certain dose, Fe alloys containing nickel and manganese irradiated in a material test reactor (BR2) show a continuous increase of hardening, up to doses equivalent to about 40 years of operation. Considerations based on positron annihilation spectroscopy analyses suggest that the main objects causing hardening in Cu-free alloys are most probably self-interstitial clusters decorated with manganese. In low-Cu reactor pressure vessel steels and in Fe-CuMnNi alloys, the main effect is still due to Cu-rich ...

Energy Technology Data Exchange (ETDEWEB)

Complementary electrochemical, spectrophotometric and electron microsopic investigations were made in addition to the conversion electron Moessbauer spectroscopic (CEMS) measurements to learn more about the mechanism of corrosion of low carbon steel samples in aqueous sulfate and sulfite containing sulfate solutions (pH 3.5, 6.5 and 8.5). Passivation of iron in pure sulfate solution was studied in detail in earlier papers. In the present work, we used a solution containing both sulfate and sulfite anions to obtain more information about the effect of acid rain on low carbon steel samples. The compositions and thicknesses of the passive films formed due to the electrochemical treatments were determined from the CEM spectra. [gamma]-FeOOH was found in each case on the surface of the samples; nevertheless, at pH 3.5 the sextet belonging to Fe[sub 3]C appears in the CEM spectra, and also FeSO[sub 4] . H[sub 2]O was detected in ...

British Library Electronic Table of Contents (United Kingdom)

In this research, the interactive effect of grain and specimen sizes on the flow stress of sheet metal in microforming is investigated via the tensile test of pure copper and numerical modeling. Models based on different assumptions are proposed to analyze the size effect phenomenon. It is found that the flow stress decreases linearly with the decrease of the ratio of specimen to grain sizes. The grain boundary thickness decreases and its volume fraction increases with the decrease of grain size. The variation of grain boundary thickness is not proportional to the variation of grain size. Furthermore, the fraction of grain boundary increases with the strain and the ratio of specimen to grain sizes. Based on the FE simulation, it is found that the simulated flow stress, which is modeled bas...

International Nuclear Information System (INIS)

The experimental study on #beta#-delayed proton decays near the proton drip line published by our group over the last 8 years were reviewed and summarized briefly, including first observation of 9 precursors in the rare-earth region and new measurements of 5 nuclei in the mass-90 region near N-Z line with the aid of the 'p-#gamma#' coincidence in combination with a He-jet tape transport system. Systematically comparing the experimental data with the current nuclear-model predictions, following points were represented. (1) the experimental half-lives for "8"5Mo and "9"2Rh as well as the predicted 'waiting point' nuclei "8"9Ru and "9"3Pd are 5-10 times longer than the macroscopic-microscopic model predictions given by Moeller et al. It considerably influences the prediction of mass abundances of the nuclides produced in rp-process. (2) The current-model predictions are not consistent with the experimental ...

CERN Document Server

We model the transport of cosmic ray nuclei in the Galaxy by means of a new numerical code. Differently from previous numerical models we account for a generic spatial distribution of the diffusion coefficient. We found that in the case of radially uniform diffusion, the main secondary/primary ratios (B/C, N/O and sub-Fe/Fe) and the modulated antiproton spectrum match consistently the available observations. Convection and re-acceleration do not seem to be required in the energy range we consider: $1 \\le E \\le 10^3$ GeV/nucleon. We generalize these results accounting for radial dependence of the diffusion coefficient, which is assumed to trace that of supernova remnants. While this does not affect the prediction of secondary/primary ratios, the simulated longitude profile of the diffuse $\\gamma$-ray emission is significantly different from the uniform case and may agree with EGRET measurements without invoking {\\it ad ...

International Nuclear Information System (INIS)

11-MeV neutrons were elastically and inelastically scattered from eight single-closed-shell nuclei: three proton-vibrational nuclei with N = 50 ("8"8Sr, "9"0Zr, "9"2Mo) and five even-even neutron-vibrational nuclei ("1"1"6"-"1"2"4Sn) with Z = 50. Detection methods involving electronic discrimination against #gamma# rays, and time-of-flight techniques were used to measure the energy of the scattered neutrons. Data were taken from 15"0 to 150"0 in 5"0 intervals. Measured differential cross sections were normalized to the zero-degree neutron flux and corrected. An optical model (OM) analysis was used to fit the elastic data with the code GENOA, and potential parameters were obtained for each nucleus. The observed low-lying electric quadrupole (2"+) and octupole (3"-) states were collective in nature; the macroscopic or collective model for inelastic scattering was used to generate the differential cross-section angular ...

International Nuclear Information System (INIS)

In this thesis the rate constants for a number of radical reactions in aqueous solution have been studied in a wide temperature range. The reactions of H with H_2O_2, OH and HO_2 and the reactions of HO_2 with OH, Fe"2"+ and Cu"2"+ have been studied. For each reaction rate constants have been determined as a function of temperature using the technique of high temperature, high pressure (HTP) pulse radiolysis. The rate constants were obtained by fitting a kinetic computer model to the experimental data. From an Arrhenius plot the activation energy of each reaction was determined. The data determined in this way are important for modeling of radiolysis in nuclear light water reactors. A previously developed model for calculation of the effect of water radiolysis products on oxidation and dissolution of spent nuclear fuel has been improved. In the new model, called TraRaMo, ...

UK PubMed Central (United Kingdom)

Secreted human bronchial mucins, directly collected from macroscopically healthy bronchial mucosa, were prepared in the presence of six proteinase inhibitors, and analysed by electron microscopy. These...Full Text Available

International Nuclear Information System (INIS)

Using the activitation method (n,2n) excitation-functions were measured for "5"4Fe, "7"0Ge, "7"4Se, "8"5Rb, sup(86,88)Sr, "8"9Y, "9"2Mo, and "2"0"4Hg in the neutron-energy region 13-18 MeV. The results are checked for consistency by means of a systematic of (n,2n) cross-sections as a function of the nuclear neutron excess (N-Z)/A. Furthermore the data are compared with results from the statistical nuclear reactions theory which were calculated using optical model absorption cross-sections and the Fermi-gas-model formula for the nuclear level density. In the case of "2"0"4Hg the influence of preequilibrium nucleon emission was taken into account. (orig.).

British Library Electronic Table of Contents (United Kingdom)

Abstract Simon Saunders and David Wallace have proposed an attractive semantics for interpreting linguistic communities embedded in an Everettian multiverse. It provides a charitable interpretation of our ordinary talk about the future, and allows us to retain a principle of bivalence for propositions and to retain the law of excluded middle in the logic of propositions about the future. But difficulties arise when it comes to providing an appropriate account of the metaphysics of macroscopic objects and events. I evaluate various metaphysical frameworks which might be combined with the Saunders-Wallace semantics. I conclude that the most appropriate metaphysics to underwrite the semantics renders Everettian quantum mechanics a theory of non-overlapping worlds.

International Nuclear Information System (INIS)

"1"7"5Ta and "1"7"7Ta nuclei as dilute impurities in Fe were oriented at low temperatures. Using the technique of NMR/ON the magnetic moments have been measured: "+#mu#("1"7"5Ta, 7/2"+,"+=2.270(45) #mu# sub(N) and "+#mu#("1"7"5Ta, 7/2"+)"+=2.250(45) #mu# sub(N). These values are discussed in the framework of the rotational model. (author).

Energy Technology Data Exchange (ETDEWEB)

Angular distributions for the elastic and inelastic scattering of /sup 12/C at 80 MeV by /sup 88/Sr and of /sup 7/Li at 36, 42 and 48 MeV by /sup 54/Fe have been analysed. The optical potentials of /sup 12/C and /sup 7/Li ions are calculated in terms of the alpha-particle and triton optical potentials. Coupled-channels calculations using these potentials are performed. Good fits to the experimental data and the phenomenological calculations are obtained for /sup 12/C projectiles.

Energy Technology Data Exchange (ETDEWEB)

Gas nitridation has shown excellent promise to form dense, electrically conductive and corrosion-resistant Cr-nitride surface layers on Ni-Cr base alloys for use as proton exchange membrane fuel cell (PEMFC) bipolar plates. Due to the high cost of nickel, Fe-base bipolar plate alloys are needed to meet the cost targets for many PEMFC applications. Unfortunately, nitridation of Fe-base stainless steel alloys typically leads to internal Cr-nitride precipitation rather than the desired protective surface nitride layer formation, due to the high permeability of nitrogen in these alloys. This paper reports the finding that it is possible to form a continuous, protective Cr-nitride (CrN and Cr{sub 2}N) surface layer through nitridation of Fe-base stainless steel alloys. The key to form a protective Cr-nitride surface layer was found to be the initial formation of oxide during nitridation, which prevented the internal nitridation ...

International Nuclear Information System (INIS)

The EXAFS-study (Fe, Sn and Ge K-edges) of disordered by mechanical activation binary supersaturated nanocrystalline solid solutions Fe-Al, Fe-Ge, Fe-Sn and Fe-Si is presented. The EXAFS-spectra are processed by solving the inverse binary problem, using the EXAFS-spectrum of the Fe K-edge only or combining the EXAFS-spectra on two K-edges, Fe and Ge or Fe and Sn. The parameters of partial correlation functions indicate chemical short-range ordering, high local static distortions in the lattice, increasing with metalloid content. The macrostructure of other type is forming through an initial, 'local' stage within the bcc lattice.

Energy Technology Data Exchange (ETDEWEB)

The Recycler ring magnet will be made of Strontium ferrite permanent magnets. A strontium ferrite permanent magnet without compensation has a temperature coefficient of -0.2 % in dB/dT. To compensate this effect, we are utilizing 30 % Ni 70 % Fe alloy, a temperature compensation ferromagnetic material with a low Curie point. To search for optimum commercially available material and optimum condition, we made a couple of simple model magnets, and tested with several different compensating material. The test results are reported and its optimal conditions are shown. Several different configurations were tested including a possible 2 kG magnet configuration.

Energy Technology Data Exchange (ETDEWEB)

This study has confirmed large seasonal and daily variations of Rn in soil gas, developed models for the effects of temperature and moisture on air-water Rn partition, inhibited Rn diffusion from wet soil into sparse large air-filled pores and effects of diffusion into bedrock, demonstrated that organic matter is a major host for 226Ra in soils and that organic-bound Ra largely determines the proportion of 222Rn emanated to pore space, shown that in contrast 220Rn is emanated mainly from 224Ra in Fe-oxides, detected significant disequilibrium between 226Ra and 238U in organic matter and in some recent glacial soils, demonstrated by computer models that air convection driven by temperature differences is expected in moderately permeable soils on hillsides.

International Nuclear Information System (INIS)

An Fe-15Cr-20Ni ternary model alloy and a Type 316 stainless steel were irradiated by dual-ions at 1 to 50 appm of He/dpa ratios, to investigate the helium effects on microstructural development in austenitic alloys under irradiation. Quantitative analysis on resultant microstructures revealed that the Frank loop nucleation rate and the network dislocation density positively correlate and Frank loop growth rate negatively correlate with the He/dpa ratio, while the cavity growth rate has its peak at an intermediate helium injection rate. Although He/dpa dependence of various microstructural features were similar for the model alloy and the 316SS, the rates of their development and the mechanism which had assisted cavity growth were significantly different in these two materials. (orig.).

CERN Document Server

The transition region between the straight part and the ends of the coils of the LHC model and prototype dipole magnets are often identified as the origin of training quenches. In order to study how the discontinuities in the material properties of these regions affect coil pre-stress and possibly gain more insight in the quench behavior, a program was set up at CERN to analyze by 3D-FEM these particular regions. The ACCEL team, who performed a similar analysis for the main quadrupoles of the Superconducting Supercollider SSC, is entrusted with this program. In this paper we report on the results of 3D-modeling and analysis of the coil return end region, including the complete coil mass, of a 1-m single bore model magnet. This magnet represents all relevant features of the "two-in-one" LHC main dipole design concerning the winding configuration, the collar pack, the yoke, and the outer shell representing the He-vessel. The ...

Energy Technology Data Exchange (ETDEWEB)

Systematic studies of the NdFeAsOF superconducting energy gap using point-contact Andreev-reflection (PCAR) spectroscopy are presented. At low temperatures the PCAR conductance spectra show a pair of gap-like peaks at about {+-} (4-7) mV and in most cases also a pair of humps at around {+-} 10 mV. Fits to the s-wave two-gap model of the PCAR conductance allowed to determine two superconducting energy gaps in the system. However, the energy-gap features disappear at T* = 15-20 K, much below the particular T{sub c} of the junction under study. At T* a zero-bias conductance (ZBC) peak emerges, which at higher temperatures usually overwhelms the spectrum with an intensity significantly higher than the conductance signal at lower temperatures. Possible causes of this unexpected temperature effect are discussed. In some cases the conductance spectra show just a reduced conductance around the zero-bias voltage, the effect persisting well above the ...

Energy Technology Data Exchange (ETDEWEB)

A process model was used to better understand the controls on the chemical evolution of drainage in a historic mining district. At the Pecos Mine Operable Unit, New Mexico, drainage near the waste rock pile is acidic (pH varies from 3.0--5.0) and carries high concentrations of Zn, Al, Cu and Pb. As drainage flows toward the Pecos River, pH increases to greater than 7 and heavy metal content decreases. A process model of natural attenuation in this drainage shows the main controls on pH are reaction with a local bedrock that contains limestone, and concurrent mixing with tributary streams. Models that account for both calcite dissolution and mixing reproduce the observed decrease in aqueous metal concentrations with increasing pH. Contaminant concentrations attenuate primarily via two distinct pathways: Al, Cu, Fe and Pb precipitate directly from solution, whereas Zn, Mg, Mn and SO{sub 4} concentrations ...

International Nuclear Information System (INIS)

Nano indentation analysis and transmission electron microscopy observation were performed to investigate a microstructural evolution and its influence on the hardening behavior in Fe-Cr alloys after an irradiation with 8 MeV Fe4+ ions at room temperature. Nano indentation analysis shows that an irradiation induced hardening is generated more considerably in the Fe-15Cr alloy than in the Fe-5Cr alloy by the ion irradiation. TEM observation reveals a significant population of the a0 dislocation loops in the Fe-15Cr alloy and an agglomeration of the 1/2a0 dislocation loops in the Fe-5Cr alloy. The results indicate that the a0 dislocation loops will act as stronger obstacles to a dislocation motion than 1/2a0 dislocation loops.

International Nuclear Information System (INIS)

Nanocrystalline samples of Fe_8_0Mo_2_0 and Fe_5_0Mo_5_0 alloys were prepared by the mechanical milling method. The structure, lattice parameters, and crystallite size were determined by the X-ray diffraction. The magnetic properties of the milled products were determined by the Moessbauer spectroscopy. It was observed that in the case of the Fe_8_0Mo_2_0 alloy a solid solution of Mo in Fe was formed with the lattice parameters of the Fe increasing from 0.28659 nm to 0.29240 nm and the crystallite size decreasing from 250 nm to 20 nm. In the case of the Fe_5_0Mo_5_0 alloy there were no clear changes in values of the lattice parameters of Fe and Mo during the milling process, but the crystallite size decreased from 200 to 15 nm. Moessbauer spectra revealed different magnetic phases in the machanosynthesized Fe_Mo samples. ...

Energy Technology Data Exchange (ETDEWEB)

It is hypothesized that the good performance of Alloy 800 in steam generator service is due to its relative immunity to two distinct mechanisms of stress corrosion cracking; the argument also applies to intergranular corrosion. One mechanism operates in the high-nickel region (Alloy 600 and nearby model alloys) and is due to internal intergranular oxidation. The other operates in the low-nickel (stainless steel) region and is due to de-alloying of Fe and/or Cr. This latter mechanism may, under special conditions, operate in high-Ni, high-Cr alloys such as 690. Some essential features of the de-alloying mechanism are demonstrated using strong caustic solutions, and the prospect of extending this approach to dilute high-temperature environments is discussed. (author)

Energy Technology Data Exchange (ETDEWEB)

Using carbon-paste-CuFeS{sub 2} electrodes and a cyclic voltammetric technique, it was found that a large number of intermediate electrochemical oxidation reactions were associated with the dissolution of chalcopyrite in presence and absence of bacteria. The effects of concentrations of copper, ferrous and ferric ions, as well as of agitation on the peaks of cyclic voltammograms were measured. It was established that chalcopyrite oxidation was solid-state controlled as suggested by the data of chronopotentiometric and chronoamperometric measurements. The activation energy of solid state diffusion of chalcopyrite leaching was determined by the Sand's method to be {triangle}E{sub a} = 20.5 kJ. The leaching mechanism is discussed in terms of solid-state properties (energy bonding) of the n-type semiconductor chalcopyrite and energy density states of redox systems of acidic bacterial leach media. A generalized model for the mechanism of ...

International Nuclear Information System (INIS)

Passive films formed on Alloy 690 in high-temperature alkaline environments were investigated by potentiodynamic polarization, X-ray photoelectron spectroscopy, transmission electron microscopy and Mott-Schottky approach. Passive current density and donor density of the passive films increase with increasing temperature, due to increased diffusion rates of metallic ions and dehydration of hydroxide phases. The passive films show a duplex structure including an inner layer of fine-grained Cr oxide or spinel oxide and an outer layer of Ni-Fe spinel oxide and Ni hydroxide. A growth model of the passive films on Alloy 690 in high-temperature alkaline environments is proposed and discussed.

International Nuclear Information System (INIS)

Experimental studied of deep-inelastic scattering of neutrino, antineutrino, #mu#-mesons, electron reactions on He, D, Al, Fe, Au, Be, C, Ca, Ag, N nuclei conducted in recent years at different laboratories the world for consideration of modern status of the problems of R(x, Q"2) = #sigma#sub(L)/#sigma#sub(T) parameter variation and for study on nuclear effects in structural functions of nucleons are described in the review. Experimental information on measurements of the R parameter by data on EMS and SLAK groups is analyzed. It is noted that experimental data on measuring R contain essential errors that hampers unambiguous interpretation of data on nucleon structure. Present experimental data and predictions for explanation of the EMS effect are analyzed from the view point of quark and flucton models of a nucleus.

CERN Document Server

We compare the metallicities of stars with radial velocity planets to the metallicity of a sample of field dwarfs. We confirm recent work indicating that the stars-with-planet sample as a whole is iron rich. However, the lowest mass stars tend to be iron poor, with several having [Fe/H]0.48) that contributes to but does not explain the mass-metallicity trend in the stars-with-planets sample. We use Monte Carlo models to show that adding an average of 6.5 Earth masses of iron to each star can explain both the mass-metallicity and the age-metallicity relations of the stars-with-planets sample. However, for at least one star, HD 38529, there is good evidence that the bulk metallicity is high. We conclude that the observed metallicities and metallicity trends are the result of the interaction of three effects; accretion of about 6 Earth masses of iron rich material, selection effects, and in some cases, high intrinsic metallicity.

Science.gov (United States)

The aim of present study was to evaluate antioxidant property of Glycyrrhiza glabra root extracts using in vitro models. The dose-dependent aqueous and ethanolic extracts demonstrated the scavenging activity against nitric oxide (concentration that caused 50% inhibition of nitric oxide radicals [IC(50)]=72 and 62.1 microg/ml, respectively), superoxide (IC(50)=64.2 and 38.4 microg/ml, respectively), hydroxyl (IC(50)=81.9 and 63 microg/ml, respectively), DPPH (IC(50)=43.6 and 28.3 microg/ml, respectively) and ABTS(*+) (IC(50)=77.3 and 57.2 microg/ml, respectively) radicals. Further, both extracts showed strong reducing power and iron-chelating capacities. In the Fe(2+)/ascorbate system, both extracts were found to inhibit mitochondrial fraction lipid peroxidation. In copper-catalyzed human serum and low-density lipoprotein oxidation models, both extracts significantly (P<0.05) lengthened the lag phase along with a decline ...

British Library Electronic Table of Contents (United Kingdom)

Abstract We present the first numerical,-N-body, hydrodynamical, chemical simulations of cosmic structure formation in the framework of non-Gaussian models. We study the impact of primordial non-Gaussianities on early chemistry (e-, H, H+, H-, He, He+, He++, H2, H+2, D, D+, HD, HeH+), molecular and atomic gas cooling, star formation, metal (C, O, Si, Fe, Mg, S) enrichment, Population-III (popIII) and Population-II-I (popII) transition and on the evolution of -visible- objects. We find that non-Gaussianities can have some consequences on baryonic structure formation at very early epochs, but the subsequent evolution at later times washes out any difference among the various models. When assuming reasonable values for primordial non-Gaussian perturbations, it turns out that they are responsi...

British Library Electronic Table of Contents (United Kingdom)

An operator of FE-closure is introduced on the set of functions of a multivalued logic based on the systems of functional equations. It is proved that, for every k ? 2, the FE-closure operator generates a finite classification on the set P k of functions of k-valued logic. The least class in this classification is shown to be the class H k of all homogeneous functions. Also a series of corollaries are obtained concerning the finite FE-generating sets in the FE-closed classes.

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

KoreaScience (Korea)

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KoreaScience (Korea)

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KoreaScience (Korea)

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Energy Technology Data Exchange (ETDEWEB)

A model system, described by the consistent Vlasov-Poisson equations under periodical boundary conditions, has been studied numerically near the point of a marginal stability. The power laws, typical for a system, undergoing a second-order phase transition, hold in a vicinity of the critical point: (i) A {proportional_to} -{theta}{sup {beta}}, {beta}=1.907{+-}0.006 for {theta} {<=} 0, where A is the saturated amplitude of the marginally-stable mode; (ii) {chi} {proportional_to} {theta}{sup -{gamma}} as {theta} {yields} 0, {gamma}={gamma}{sub -}=1.020{+-}0.008 for {theta} < 0, and {gamma}={gamma}{sub +}=0.995{+-}0.020 for {theta} > 0, where {chi}={partial_derivative}A/{partial_derivative}F{sub 1} at F{sub 1} {yields} 0 is the susceptibility to external drive of the strain F{sub 1}; (iii) at {theta}=0 the system responds to external drive as A {proportional_to} F{sub 1}{sup 1/{delta}}, and {delta}=1.544{+-}0.002. {theta}=(<v{sup ...

Science.gov (United States)

An island of isomers have recently been observed on both sides of the N=40 shell below the Ni isotopes. Isomeric states in the 65Fe and 67Fe allow the knowledge of the single particle structure around the {nu}g9/2 shell. Moreover, the excitation energy of the first 2+ and 4+ states in the 68Fe have been established by {beta}-{gamma} correlation. The evolution of the structure of the Fe isotopes going far away from the valley of stability is, for the first time, given for N>40.

Energy Technology Data Exchange (ETDEWEB)

Single Fe impurities were implanted in an Er single crystal and found to occupy both substitutional and interstitial sites, below a temperature of 200 K. The local susceptibility of Fe on both sites follows a Curie-Weiss law and exhibits a positive local Curie constant, indicating an antiferromagnetic coupling between the Fe and the surrounding Er moments. The corresponding nuclear spin relaxation rates follow a Korringa law as a function of temperature, confirming the dominance of local magnetism and the formation of local moments on each of the sites occupied by Fe.

International Nuclear Information System (INIS)

Fe_5_0Pt_5_0 nanodots dispersed in a SiO_2 film (Fe_5_0Pt_5_0 nanodot film) were formed by a self-assembled nanodot deposition (SAND) method in which Fe_5_0Pt_5_0 and SiO_2 are cosputtered in a high vacuum rf magnetron sputtering equipment. Fe_5_0Pt_5_0 pellets are laid on a SiO_2 target in a sputtering chamber to form the Fe_5_0Pt_5_0 nanodot film in the SAND method. The size and density of Fe_5_0Pt_5_0 nanodot were controlled by changing the ratio of the total area of Fe_5_0Pt_5_0 pellets to that of SiO_2 target. The Fe_5_0Pt_5_0 nanodot size decreases and its density increases when the ratio decreases. As-deposited Fe_5_0Pt_5_0 nanodots self-assembled to a face-centered-cubic phase of single-crystal structure. The Fe_5_0Pt_5_0 nanodot films were annealed to evaluate the ...

Energy Technology Data Exchange (ETDEWEB)

The relativistic motion of an electron is numerically analyzed in a tokamak having macroscopic magnetic turbulence. Stochasticity induced by the relativistic motion overwhelms the phase averaging effect, which provides a tokamak with an effective loss mechanism for the avoidance/suppression of runaway electron generation at a major disruption. On the other hand, electrons in the KAM (Kolmogorov-Arnold-Moser) region will be observed as a runaway snake. (author)

Energy Technology Data Exchange (ETDEWEB)

The paper presents results of studies on the effect of heat treatment on strength and pattern of 40Kh steel impact failure. Loading levels corresponding to macroscopic spalling microdamage initiation in the material are determined for three initial states. Metallographic study on the spalling failure pattern for 40Kh steel in different initial states and data on microhardness measurement are presented.

Energy Technology Data Exchange (ETDEWEB)

This report focuses on a better understanding of the physical phenomenon related to the enhancement of boiling and non-boiling heat transfer by applying ultrasonic waves. Experimental results obtained both in a pool of water and in a vertically upward water flow proved clearly that macroscopic acoustic stream induced by ultrasonics is a major contribution to heat transfer augmentation. (author).

Energy Technology Data Exchange (ETDEWEB)

In the hypothetical event of a severe accident in a Light Water Reactor, scenarios in which the reactor pressure vessel (RPV) fails and the core melt mixture (called corium) relocates into the reactor cavity, cannot be excluded. The viscosity (in fact, corium rheological behaviour) plays a major role in many phenomena such as core melt down, discharge from reactor pressure vessel, interaction with structural materials (concrete,...) and spreading in a core-catcher. For these reasons, it is important to be able to predict the rheological behaviour of corium melts of different compositions (essentially based on UO{sub 2}, ZrO{sub 2}, Fe{sub x}O{sub y} and Fe for in-vessel scenarios, plus SiO{sub 2} and CaO for ex-vessel scenarios) at temperatures above solidus temperature. In the case of corium-concrete mixtures, the increase of viscosity depends not only on the increase of particles in the melts but also on the increase of the residual liquid ...

International Nuclear Information System (INIS)

Production of Fe_2O_3, Y_2O_3, YFeO_3, Y_3Fe_5O_1_2 powders using the alkoxomethod - during hydrolysis by yttrium and iron alcohol solutions, is studied. It is stated that production of the powders of Y_2O_3-Fe_2O_3 system oxides using alkoxomethod permits to decrease essentially the reaction volumes, number of operations, their duration as compared to the cooxidation of oxide hydrates from inorganic salt aqueous solutions. During heat treatment of iron (3) alcohol hydrolysis products #gamma#-Fe_2O_3 is first crystallized by contrast to #alpha#-FeOOH, usually produced by deposition from solutions. Further heat treatment of #gamma#-Fe_2O_3 results in production of #alpha#-Fe_2O_3. Conditions for crystallization of Y_3Fe_5O_1_2 and YFeO_3 phases, prepared by both methods, and their crystallite mean sizes are close, but the ...

British Library Electronic Table of Contents (United Kingdom)

A magnetic core/shell Fe3O4/FeMnOx catalyst was prepared by a simple oxidation-precipitation method. The catalyst was characterized by X-ray diffraction, transmission electron microscope, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, thermogravimetric analysis and cyclic voltammetry. The characterization studies verified that Fe3O4 core was coated with a layer of Fe-Mn oxide. The Fe3O4/FeMnOx was found to be an effective and stable heterogeneous catalyst for the discoloration of methylene blue (MB) in aqueous solution by H2O2. The high catalytic activity is due to the FeMnOx shell, which not only increased the surface hydroxyl groups, but also enhanced the interfacial electron transfer. The discoloration of MB could be due to the decomposition of H2O2 into ?OH ...

Science.gov (United States)

In order to model transport of dissolved ions in subsurface environments, one should understand how these ions interact with solid phase adsorbents. Our primary goal has been investigating the reaction mechanisms which affect microcontaminant partitioning between aqueous solutions and solid phase adsorbents, using goethite ({alpha}-FeOOH) as a model adsorbent. Cylindrical internal reflection -- Fourier transform infrared (CIR-FTIR) spectroscopy has been developed as the primary technique for this study. Wet chemical adsorption studies, acoustophoresis and electrophoretic mobility have been used to obtain supporting information as needed. Phenol and o-nitrophenol did not adsorb to goethite. Benzoate, phthalate and p-hydroxybenzoate all adsorbed via a bidentate mechanism to two adjacent iron atoms, while salicylate and 2,4-dihydroxybenzoate formed a chelate complex to single iron atoms. Phosphate adsorption was predominately ...

British Library Electronic Table of Contents (United Kingdom)

We synthesized Fe3O4Gg nanocomposites through a combination of solvothermal, hydrothermal, and chemical redox reactions. Characterization of the resulting samples by X-ray diffraction, Fourier-transform infrared spectroscopy, field-emission scanning and transmission electron microscopy, and magnetic measurement is reported. Compared to Fe3O4g nanocomposites, the Fe3O4Gg nanocomposites showed enhanced antibacterial activity. The Fe3O4Gg nanocomposites were able to almost entirely prevent growth of Escherichia coli when the concentration of Ag nanoparticles was 10mg/mL. Antibacterial activity of the Fe3O4Gg nanocomposites was maintained for more than 40h at 37^oC. The intermediate carbon layer not only protects magnetic core, but also improves the dispersion and antibacterial activity of the...

British Library Electronic Table of Contents (United Kingdom)

Microanalytical methods suitable for the determination of Fe, Cu in HT-29 (human colon adenocarcinoma) cells treated with different iron compounds (Fe(II) sulfate, Fe(III) chloride, Fe(III) citrate and Fe(III) transferrin) and cultured in medium supplemented or not with 10% (v/v) fetal calf serum (FCS) by total reflection X-ray fluorescence spectrometry (TXRF) and simultaneous graphite furnace atomic absorption spectrometry (GF-AAS) were developed. The developed TXRF method was also suitable for Zn determination in the samples. The main advantage of the proposed methods is the execution of all sample preparation steps following incubation and prior to the elemental analysis in the same Eppendorf tubes. Sample preparation was performed at microscale (115mL sample volume) with 65% nitric aci...

Energy Technology Data Exchange (ETDEWEB)

By ab-initio calculation we show that the (Ga,Fe)N ground state may be changed from anti-ferromagnetic to ferromagnetic by acceptor defect like Ga vacancies. The electronic structures are calculated by using the Korringa-Kohn-Rostoker (KKR) method combined with coherent potential approximation (CPA). We show that we can increase the magnetic moment of Fe in p-type GaN by oxygen co-doping. Mechanism of exchange interactions between magnetic ions in p-type (Ga,Fe)N is also studied. The effect of external magnetic field on the electronic structure of (Ga, Fe)N and p-type (Ga, Fe)N is investigated.

Energy Technology Data Exchange (ETDEWEB)

Physico-chemical characterizations performed on samples of 100Cr6 steel implanted both with boron and nitrogen revealed the formation of boron nitride along with the following new phases: Fe{sub 1-x}(B, N), Fe{sub 2-x}(B, N) and Fe{sub 3-x}(B, N). A thorough analysis of boron NITRIDE (5BN) indicates that a low ion current density (3 {mu}A.cm{sup -2}) in the case of the boron plus nitrogen sequence favours the formation of sp{sup 2} bonds (hexagonal-BN) while a higher ion current density (6{mu}A.cm{sup -2}) promotes sp{sup 3} bonds (cubic-BN) in the opposite sequence. Tribological tests carried out on these samples revealed that nitrogen and boron implantations do not lead to any significant improvement of friction and wear at variance with the results obtained by others authors. However, on a set samples accidentally contaminated with carbon during implantation, we noticed a considerable improvement of these tribological ...

International Nuclear Information System (INIS)

A new iron phosphate (NH4)4Fe3(OH)2F2[H3(PO4)4] has been synthesized hydrothermally at HF concentrations from 0.5 to 1.2 mL. Single-crystal X-ray diffraction analysis reveals its three-dimensional open-framework structure (monoclinic, space group P21/n (No. 14), a=6.2614(13) A, b=9.844(2) A, c=14.271(3) A, ?=92.11(1)o, V=879.0(3) A3). This structure is built from isolated linear trimers of corner-sharing Fe(III) octahedra, which are linked by (PO4) groups to form ten-membered-ring channels along [1 0 0]. This isolated, linear trimer of corner-sharing Fe(III) octahedra, [(FeO4)3(OH)2F2], is new and adds to the diverse linkages of Fe polyhedra as secondary building units in iron phosphates. The trivalent iron at octahedral sites for the title compound has been confirmed by synchrotron Fe K-edge XANES spectra and magnetic measurements. Magnetic measurements also ...

Energy Technology Data Exchange (ETDEWEB)

The generation of acidic mine drainage is based on the oxidation dissolution of sulfide minerals due to the contact of ores with the natural water and the air. Namely, the sulfuric acid promotes the dissolution of sulfide minerals and gangue minerals, and Fe{sup 2+} is further oxidized to turn into Fe{sup 3+}, which acts as an oxidizer for other sulfide minerals and promotes the dissolution of the same. This paper roughly describes a mine drainage treatment focusing on an Fe{sup 2+} neutralization method and an iron bacteria oxidation method. The iron bacteria oxidation method is a method of oxidizing Fe{sup 2+} into Fe{sup 3+} by using iron bacteria, and then removing Fe{sup 3+} with calcium carbonate. This method has been used for treating the drainage in the Sakuhara Mine and the former Matsuo Mine, with good results. The paper finally introduces, as ...

UK PubMed Central (United Kingdom)

Under anaerobic conditions, several species of green algae perform a light-dependent hydrogen production catalyzed by a special group of [FeFe] hydrogenases termed HydA. Although highly interesting...Full Text Available

International Nuclear Information System (INIS)

The hardening and embrittlement of reactor pressure vessel (RPV) steels is of great concern in the actual nuclear power plant life assessment. This embrittlement is caused by irradiation-induced damage, like vacancies, interstitials, solutes and their clusters. The current procedure to estimate material properties for the irradiated pressure vessels is based on Charpy-V tests of identical material located at the inner shell of the reactor. But the reason for the embrittlement of the materials is not yet totally known. The real nature of the irradiation damage should thus be examined as well as its evolution in time. Fe-Cu binary alloys are often used to mimic the behaviour of such steels. Their study allows. Identifying some of the defects responsible of the hardening, especially when compared to pure iron or C-micro-alloyed iron. More recently the influence of manganese and nickel in low-Cu RPV steels has become a significant topic. Thus in contrast with the ...

KoreaScience (Korea)

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KoreaScience (Korea)

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KoreaScience (Korea)

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Energy Technology Data Exchange (ETDEWEB)

An intermetallic compound Sm[sub 2]Fe[sub 17]N[sub x] was synthesized by plasma nitriding of Sm[sub 2]Fe[sub 17] in a stream of N[sub 2]-H[sub 2] mixed gas. The reaction proceeded at a lower temperature (around 423 K) than that of the conventional thermal technique, but not at room temperature. This is discussed on the basis of the difference between the reaction mechanisms of plasma and thermal nitridings. (orig.)

International Nuclear Information System (INIS)

We studied the epitaxial growth of iron silicide (#epsilon#-FeSi,#beta#-FeSi_2, and #alpha#-FeSi_2) nanodots on Si (111) substrates by Fe deposition on Si nanodots on Si (111) substrates with ultrathin Si oxide films using reflection high-energy electron diffraction, scanning tunneling microscopy, and transmission electron microscope (TEM). We formed almost single phase iron silicide nanodots by controlling the Fe deposition conditions; growth temperature, deposition rate, and amount. The #epsilon#-FeSi or #alpha#-FeSi_2 nanodots were epitaxially grown in a dome shape with an average size of #approx#5 nm and an ultrahigh density (>10"1"2 cm"-"2) on the surface. We formed #approx#2-nm high and #approx#8-nm wide #beta#-FeSi_2 nanodots in a dome shape with a density of #approx#5x10"1"1 cm"-"2 on the surface. Cross-sectional TEM images ...

International Nuclear Information System (INIS)

We consider a Bose-Einstein condensate (BEC) of N atoms of repulsive interaction #approx# U_0, in an elliptical trap, axially pierced by a Gaussian-intensity laser beam, forming an effective (quasi-2D) toroidal trap with minimum at radial distance #rho# = #rho#_p. The macroscopic angular momentum states #PSI#_l(#rho#,#theta#) #approx# #sq root#N#PHI#_l(#rho#)e"i"l"#theta# for integer l spread up to #rho# > #rho#_p. The spreading lowers rotational energies, so estimated low metastability barriers can support large l < or approx. l_m_a_x #approx# (NU_0)"1"/"4, < or approx. 10 for typical parameters. The l-dependent density profile module #PHI#_l(#rho#)"2 -#PHI#_0(#rho#)"2 is a signature of BEC rotation. Results are insensitive to off-axis laser displacements #rho#_0, for #rho#_0 #rho#_m_a_x << 1. (author).

CERN Document Server

We demonstrate that a massive asymptotic giant branch (AGB) star is a good candidate as the main source of short-lived radionuclides in the early solar system. Recent identification of massive (4-8 solar masses) AGB stars in the Galaxy, which are both lithium- and rubidium-rich, demonstrates that these stars experience proton captures at the base of the convective envelope (hot bottom burning), together with high-neutron density nucleosynthesis with 22Ne as a neutron source in the He shell and efficient dredge-up of the processed material. A model of a 6.5 solar masses star of solar metallicity can simultaneously match the abundances of 26Al, 41Ca, 60Fe, and 107Pd inferred to have been present in the solar nebula by using a dilution factor of 1 part of AGB material per 300 parts of original solar nebula material, and taking into account a time interval between injection of the short-lived nuclides and consolidation of the first meteorites equal ...

Energy Technology Data Exchange (ETDEWEB)

The phenomenology of wire chamber aging is discussed and fundamentals of proportional counters are presented. Free-radical polymerization and plasma polymerization are discussed. The chemistry of wire aging is reviewed. Similarities between wire chamber plasma (>1 atm dc-discharge) and low-pressure rf-discharge plasmas, which have been more widely studied, are suggested. Construction and use of a system to allow study of the plasma reactions occurring in wire chambers is reported. A proportional tube irradiated by an {sup 55}Fe source is used as a model wire chamber. Condensable species in the proportional tube effluent are concentrated in a cryotrap and analyzed by gas chromatography/mass spectrometry. Several different wire chamber gases (methane, argon/methane, ethane, argon/ethane, propane, argon/isobutane) are tested and their reaction products qualitatively identified. For all gases tested except those containing methane, use of ...

International Nuclear Information System (INIS)

An attempt to classify experimental data and to present new approach for the problem of cumulative production of particles and high-transverse momentum particles (#pi#"#+-#, k"#+-#, p, p-bar, d) on Li"6, Be, Mg, Si, "5"4","5"6","5"8Fe, "5"8","6"1","6"4Ni, Cu, "6"4Zn, "1"1"2","1"1"8","1"2"4Sn, "1"4"4","1"5"4Sm, "1"8"2","1"8"6W, U nuclei is made in the review. Particle cumulative production, quark-parton structure function, A dependence of particle production on nuclei and in nuclear collisions and A dependence of inclusive cross sections of particle cumulative production are discussed. Reactions with dissociation on nucleons of deuteron, helium and compound nuclei are considered. Possibility of unified description of different processes is discussed in terms of nucleus flucton model. 35 refs.; 22 figs.

Energy Technology Data Exchange (ETDEWEB)

The sequence of nitride formation during the early stages of plasma nitriding of pure iron was studied by optical microscopy, SEM, TEM and x-ray diffraction. Plasma nitriding at {approximately}490 C in a 25 vol.%H{sub 2} + 75 vol.%N{sub 2} mixture starts with the formation of {gamma}{prime}-Fe{sub 4}N after 40s. Once {gamma}{prime} nucleates, it mainly spreads laterally due to diffusion shortcuts in the discontinuous surface nitride layer. Before {gamma}{prime} is continuous on the surface, {epsilon} nucleates on top of it shortly after 40S. Epsilon is then observed to grow, both inwardly and laterally along with {gamma}{prime}. A compact {gamma}{prime}/{epsilon} bilayer forms on the surface at around 100s. The kinetics of nucleation, growth and compactation of the nitrides observed in the present work was significantly more rapid than in any of the nitriding process reported in the literature, including plasma nitriding. The acceleration of the nitriding kinetics ...

CERN Document Server

We study quantum Darwinism -- the redundant recording of information about a decohering system by its environment -- in zero-temperature quantum Brownian motion. An initially nonlocal quantum state leaves a record whose redundancy increases rapidly with its spatial extent. Significant delocalization (e.g., a Schroedinger's Cat state) causes high redundancy: many observers can measure the system's position without perturbing it. This explains the objective (i.e. classical) existence of einselected, decoherence-resistant pointer states of macroscopic objects.

Energy Technology Data Exchange (ETDEWEB)

This paper presents fundamental researches based on the electronic structure calculations and X absorption spectroscopy, allowing the knowledge on nuclear fuels at an atomic scale. They bring a better understanding of these material behavior to accurate the macroscopic simulation. The calculation methods, the experimental techniques of validation and the ab initio calculations results are detailed. (A.L.B.)

Energy Technology Data Exchange (ETDEWEB)

Carbon nano tubes are easily produced in macroscopic quantities, however their characterisation and possible applications are still rather limited. We have developed a new method to make aligned nano tube films which open new opportunities, not only for basic research but also for eventual applications. With this method the tubes can be aligned either parallel or perpendicular to the surface. We give a short review of the microscopic properties of single tubes and the bulk properties of the aligned films. (author). 24 refs., 6 figs.

British Library Electronic Table of Contents (United Kingdom)

Fe-doped TiO2 hollow spheres (Fe-THs) were synthesized by sol?gel process using carbon spheres as templates. The prepared samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), UV?vis diffuse reflectance spectrum (DRS), N2 adsorption?desorption isotherms, Electron paramagnetic resonance (EPR) spectroscopy and Photoluminescence emission spectroscopy (PL). UV?vis spectra showed that Fe3+ doping could extend the absorption edge to the visible region. EPR spectra showed that Fe3+ was incorporated into the crystal lattice of TiO2, which could inhibit the recombination of photo-induced electron?hole pairs and improve the photocatalytic activity. The photocatalytic activities of the prepared samples were evaluated for the degradation of dye Reactive Brillia...

Energy Technology Data Exchange (ETDEWEB)

This paper attempts to explain the peculiarities of the radial-distribution function of metal glasses without involving ideas of the amorphous structure. On a computer, the radial atomic density for a spherical eutectic single crystal of the composition Fe/sub 84/C/sub 16/ of radius 15 A formed by alternating small crystals of e-Fe and Fe/sub 3/C of cubic form with the edge of the cube ca 10 A. For the sake of clarity, the diagram of such a quasisingle crystal is shown and has been given a cubic boundary. The change in the relationship between the heights of the subpeaks of the second maximum of the radial distribution function of atoms in the Fe-B glasses with a change in the concentration of boron can be explained by the change in the space group of the Fe/sub 3/B metastable boride which is formed in this system.

Energy Technology Data Exchange (ETDEWEB)

FeAl, which has high oxidation and sulfidation resistance, was shown to be thermodynamically compatible with WC. Calculations indicate that soly. of WC in liq. Fe-40at.%Al at 1450 C is about 2 at.%. Since liquid FeAl wets WC very well, the WC/FeAl system lends itself to liquid-phase sintering, resulting in close to theoretical densities. Almost fully dense cermets with 20.6 wt% FeAl binder were produced. With one-step infiltration, 98% dense cermets with only 7 wt% FeAl binder were fabricated. RT bend strengths and fracture toughness for WC-20.6 wt% FeAl reached 1680 MPa and 22 MPa{center_dot}m{sup 1/2}. Ductile binder fracture was observed on the fracture surfaces. Pores containing oxide inclusions were found, suggesting that improvements in processing are likely to further improve the mechanical properties. Insufficient process control may ...

Energy Technology Data Exchange (ETDEWEB)

The effect of the nitrogen uptake in {alpha}-iron upon spark erosion in gaseous and liquid ammonia, plasma nitriding, and plasma immersion ion implantation is studied. The resulting phases and hyperfine parameters, measured by the Moessbauer spectroscopy, are discussed from the point of view of initial conditions of their preparation and subsequent heat and/or mechanical treatment. Spark erosion in the ammonia gas produces fine particles with the dominating ferromagnetic {alpha}-Fe phase (50%). The 20% of specimen volume form {alpha}'-Fe and {alpha}''-Fe{sub 16}N{sub 2} phases. The last 30% occupy the {gamma}'-Fe{sub 4}N, ferro- and paramagnetic {epsilon} phases, and {gamma}-Fe(N). Nitriding in the liquid ammonia allows to incorporate the higher content of nitrogen into {alpha}-iron particles which results in the formation of paramagnetic ...

Energy Technology Data Exchange (ETDEWEB)

The purpose of this study is to prevent the deactivation of catalysts recycled in the 0.1 t/d bench scale unit (BSU). Catalysts recovered during reactions in the BSU and after reactions in the 5-liter autoclave were analyzed, to investigate the influences of the reaction condition on the property and activity of catalysts. Were used {gamma}-iron oxyhydroxide ({gamma}-FeOOH), {alpha}-iron oxyhydroxide ({alpha}-FeOOH), and natural pyrite (FeS2) as catalysts. At the S/Fe atomic ration of 1.2 under the BSU reaction condition, troilite was more easily formed from {gamma}-FeOOH compared with pyrite and {alpha}-FeOOH. As the reaction proceeded through the first, second, and third reactors, the crystal size increased, the pyrrhotite content decreased, and the troilite content increased. Deactivation due to the formation of troilite was irreversible. At the ...

Energy Technology Data Exchange (ETDEWEB)

As surface treated steel sheets, steel sheets with Zn-Fe coatings as well as double-layer steel sheets with Fe-P alloy coatings on Zn-Fe alloy coatings are often used practically. Two treatment methods, which are used to dissolve only alloy layers without dissolving steel sheets in order to find amount and composition of alloy layersr have already been reported. This report investigates the mechanisms of these methods, particularly the mechanisms to control dissolution of steel sheets. In the alkali-dissolution method, Zn-Fe alloy coatings are dissolved in a strong alkaline solution(NaOH-triethanolamine (TEA)-H{sub 2}O{sub 2}). In this case, steel sheets are insoluble because passive films are formed on the surface. In the cathodic polarization electrolysis method, alloy layers are electrolyzed({minus}l.2V) and dissolved in an ammonium nitrate-0-phen electrolyte. At this potential, dissolution of steel ...

International Nuclear Information System (INIS)

The molar heat capacities (Cp,m) of a series of synthetic forsterite (Fo)-fayalite (Fa), (Mg2SiO4+Fe2SiO4), olivines have been measured between 5K and 300K on milligram-sized samples with the Physical Properties Measurement System (Quantum Design(R)). Sharp, ?-type heat capacity anomalies are observed in the Fe-rich compositions fayalite, Fo10Fa90, Fo20Fa80, Fo30Fa70, and Fo40Fa60. The corresponding Neel temperatures TN decrease linearly from 64.5K in fayalite to 32.8K in Fo40Fa60 following the relationship TN=79.02.xFa-14.07. Fo50Fa50 and Mg-richer olivines show weak broad features in the heat capacity data around 15K to 20K that decrease in magnitude with increasing forsterite content. In order to derive and separate molar electronic, magnetic and vibrational heat capacity contributions, Cel,m, Cmag,m, and Cvib,m from the experimental heat capacities (Ctot,m), we used a single-parametric phonon dispersion model to ...

Energy Technology Data Exchange (ETDEWEB)

Chemical phase identifications of complex, multilayered corrosion products formed on Fe-Ni-Cr alloys immersed in molten NaNO/sub 3/-KNO/sub 3/ and LiNO/sub 3/-NaNO/sub 3/-KNO/sub 3/ were obtained by X-ray diffraction analysis. Diffraction analyses performed after successive material removal steps provided depth profiles of corrosion products and identified the dominant phases as NaFeO/sub 2/, Fe/sub 3/O/sub 4/, and Cr/sub 2/O/sub 3/ for Alloy 800 and 316SS after immersion in NaNO/sub 3/-KNO/sub 3/. In LiNO/sub 3/-NaNO/sub 3/-KNO/sub 3/, the major corrosion products identified on Alloy 800 were LiFeO/sub 2/, Fe/sub 3/O/sub 4/, and Cr/sub 2/O/sub 3/. X-ray diffraction results were supplemented by electron microprobe analyses that revealed the solid solution nature of several of the oxide phases.

International Nuclear Information System (INIS)

For optimizing the microstructure of the (#alpha# + #beta#)-titanium alloy TiAl5Fe2.5 the content of the two alloying elements aluminium and iron in the #alpha#- and #beta#-phase was determined by microprobe analysis. The alloys with the composition of the #alpha#- and of the #beta#-phase at 850 degC TiAl6Fe0.5 (#alpha#-phase) and TiAl3.5Fe6.5 (#beta#-phase) were prepared by arc melting and rolling at 850 degC. The mechanical properties of the '#alpha#'- and of the '#beta#'-phase-alloy are compared with the properties of the (#alpha# + #beta#)-alloy TiAl5Fe2.5 in the as rolled and swaged condition and after an additional aging at 550 degC. By this optimizing process it was possible to achieve a tensile strength of Rsub(m) = 1012 N/mm"2, an yield strength of Rsub(p0.2) 954 N/mm"2 and an elongation at fracture A = 14.5% in the TiAl5Fe2.5-alloy, although the degree of hot deformation ...

Energy Technology Data Exchange (ETDEWEB)

Nine coals from Spanish, British, German and American mining basins were hydrogenated using Fe catalyst precursors (red mud and FeSO{sub 4}), without solvent at 300, 350, and 400 {degree}C and 10 MPa of H{sub 2}. Overall conversion and product distribution are related to the textural characteristics of the original coals and are studies throughout the distinct hydrogenation processes. Results reveal that with FeSO{sub 4} as a catalyst precursor, conversions increase with coal surface area. However, when red mud (RM) is used, conversions are independent of coal textural characteristics. Higher conversions are obtained with FeSO{sub 4} than with RM at 300 and 350 {degree}C whereas at 400 {degree}C higher conversions are obtained with RM. This different catalytic activity is also reflected in the changes of the textural characteristics observed in each case. Up to 350 {degree}C, the residues from ...

International Nuclear Information System (INIS)

Substantial roles of precipitates such as Zr-Fe-Cr type intermetallic compounds on uniform corrosion and hydrogen pickup of zirconium alloys in pure water autoclave tests were investigated from an electrochemical point of view. This paper describes the roles on corrosion. A corrosion test on precipitate-containing and precipitate-free materials made from pure zirconium and a small quantity of iron and chromium, rest potential measurements on an intermetallic compound of Zr(FeCr)_2 and zirconium matrix, and a galvanic coupling test of those were performed. Results showed that corrosion behavior of zirconium alloys could be attributed to the electrochemical properties of intermetallic compounds precipitated in each alloy. Namely, the cathodic and anodic polarization characteristics were associated with anodic protection provided by the precipitates on the alloys and the precipitates degradation in the oxide films, respectively. The mechanism was ...

Energy Technology Data Exchange (ETDEWEB)

The oxidation of Cr(III) hydroxides, mixed Fe(III)-Cr(III) hydroxides, and specimens of spinel phases NiCr2O4 and Fe(Cr,Fe)2O4 have been investigated in alkaline suspensions under the action of air and pure oxygen (1-3 atm). The rate of reaction increases with increasing alkali concentration, temperature, and oxygen pressure. Pu(IV) fixed on chromium hydroxides is not oxidized by oxygen under these conditions but is retained in the precipitate.

International Nuclear Information System (INIS)

The crystal field splitting of the "3H_4 ground state of the Pr ion in PrFeO_3 and PrGaO_3 has been investigated by inelastic scattering of the thermal neutrons. At several temperatures the transitions have been measured by TAS and TOF methods for polycrystalline PrFeO_3 and by the TOF method for polycrystalline PrGaO_3. Energy level schemes which are different for these materials are given. (author).

Science.gov (United States)

... the effective lifetime of the excited states against spontaneous radiation is only a fe- times the natural lifetime and collisional destruction by ...

Science.gov (United States)

... Accession Number : ADD109273. Title : THERMAL STABILITY OF ALPHA-BETA TITANIUM ALLOY Ti-5Al-2Cr-1Fe,. Corporate Author : ...

KoreaScience (Korea)

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International Nuclear Information System (INIS)

The transformation from the as-quenched amorphous to the crystalline state in Fe_7_8B_1_3Si_9 alloy has been investigated using a new-type neutron diffractometer. The time resolved diffraction patterns clearly show that this alloy crystallizes into FeSi alloy and Fe_2B in that order. The time evolution of these crystalline phases can be analyzed by the Kolmogorov-Johnson-Mehl-Avrami equation with the exponent of about 2.5 over a wide temperature range. This suggests that the crystallization occurs by the diffusion-controlled growth with a constant nucleation rate. The scaling behavior in the crystallization kinetics is also discussed. (author).

Energy Technology Data Exchange (ETDEWEB)

This study was the analyse the relationship between properties of ion nitrided Fe sintered material and parameters of plasma nitriding process. Pure fe sintered materials (relative density : 92%) were fabricated by hot-pressing and nitrided under pulsed DC plasma for 4 hours. The large number of parameters in plasma diffusion treatment allows close control of the process so that surface layers with defined microstructures and properties can be obtained. The number of micropores in nitriding layer can be reduced in pulsed DC plasma by reducing the plasma power and by varying the gas mixture. The phase constitution of compound layer of nitrided Fe sintered material were influenced by gas mixture (N{sub 2} : H{sub 2}) and pulsed ratio (pulse on/off time ratio)

International Nuclear Information System (INIS)

Fe-doped MnO2 with a hollow sea urchin-like ball chain shape was first synthesized under a high magnetic field of 10 T. The formation mechanism was investigated and discussed in detail. The synthesized samples were characterized by XRD, SEM, TEM, EMPA, and vector network analysis. By doping MnO2 with Fe, the relative complex permittivity of MnO2 and its corresponding loss tangent clearly decreases, but its relative complex permeability and its corresponding loss tangent markedly increases. Moreover, the theoretically calculated values of reflection loss show that with increasing the Fe content, the as-prepared Fe-doped MnO2 exhibits good microwave absorption capability. -- Graphical Abstract: Fe-doped MnO2 with a hollow sea urchin-like ball chain shape was first synthesized in a high magnetic field of 10 T via a simple chemical process. Display Omitted Highlights: ? ...

Energy Technology Data Exchange (ETDEWEB)

Fe{sub x}Zn{sub 1-x} alloys were electrochemically deposited on aluminum substrates from a sulfate bath. The K{beta}/K{alpha} x-ray intensity ratios of Zn and Fe in Fe{sub x}Zn{sub 1-x} thin films have been experimentally studied. The energy dispersive x-ray fluorescence (EDXRF) technique was used to measure K x-ray photons. Samples were excited by using 59.5 keV photons emitted by a 50 mCi {sup 241}Am radioactive source. The emitted K x-rays were detected by an Ultra-LEGe detector having a resolution of 150 eV at 5.9 keV. In addition, the effect of bath composition on the phase structure was investigated by x-ray diffraction (XRD) analysis. The composition of the thin films was analyzed by atomic absorption spectrometry analysis. Iron content was shown to strongly affect the structure of Zn-Fe alloys. It was found that the K-shell x-ray intensity ratio changed in Fe{sub x}Zn{sub ...

International Nuclear Information System (INIS)

Half-Heusler phases XYZ (Pearson symbol cF12) are chemically versatile and rich in physical properties. The half-Heusler phase in the Fe-Zn-Sb ternary system was reported in the year 2000. In this work, two new ternary phases are identified in the vicinity of the equiatomic composition FeZnSb in the same system: Fe1-xZnSb (tetragonal, space group P4/nmm, Pearson symbol tP6-?, Z=2: a=4.1113(6) A, c=6.0127(12) A for x=0.08 (1), and a=4.1274(6) A, c=6.0068(12) A for x=0.12 (2)); and Fe7.87Zn6.72Sb8 (Fe0.98Zn0.84Sb) (3) (cubic, space group Fm-3m, Pearson symbol cF96-?, Z=4, a=11.690(13) A). 1 and 2 crystallize in the PbFCl-type structure, and 3 adopts a unique 2x2x2 supercell of a normal half-Heusler structure. The structures of both the tetragonal and cubic phases can be described as assemblies of half-Heusler structure related subunits. Electrical resistivity measurement on the pure ...

British Library Electronic Table of Contents (United Kingdom)

Two transition metal ions (Cu^2^+ and Co^2^+) and two rare earth metal ions (Ce^3^+ and La^3^+) were used as the assisted metal ions, respectively to prepare the transition metal and rare metal assisted Fe bimetallic amidoximated polyacrylonitrile (AO-PAN) fiber complexes. And their coordination configuration and visible light adsorption properties were examined by coordination number determination and UV-vis-DRS. Then the catalytic performance of these complexes was evaluated as the heterogeneous Fenton catalysts in Rhodamine B degradation by changing the nature and dosage of the assisted ions added. The results indicated that the incorporation of the assisted metal ions led to Fe bimetallic AO-PAN complexes with the more unsaturated configurations than Fe monometallic AO-PAN complex due ...

Science.gov (United States)

... Abstract : The electric resistance in weak (diluted) solid solutions of the Pd-Ag and Fe-W systems, as wellAS THE Hall effect in a Pd-Ag system ...

Energy Technology Data Exchange (ETDEWEB)

Two isothermal sections were prepared at 1000 and 1150 C showing the low-Zr phases of the system Fe-Al-Zr. The phase equilibria were determined by means of X-ray powder diffractometry and electron beam microanalysis. For initial characterisation of mechanical properties, hardness values are determined and added to the tabulated data. (orig./MM) [German] Es werden am Fe-Al-Zr-System zwei isotherme Schnitte durch den zirkoniumarmen Teil des Systems bei 1000 und 1150 C erstellt. Die auftretenden Phasengleichgewichte werden mit Hilfe der Roentgenpulverdiffraktometrie und Elektronenstrahlmikroanalyse aufgeklaert. Zusaetzlich werden zur ersten Charakterisierung der mechanischen Eigenschaften Haertewerte bestimmt.

British Library Electronic Table of Contents (United Kingdom)

We have developed efficient spectrally selective infrared (IR) emitters that can be utilized for thermophotovoltaic (TPV) power generation by using stainless steel (SUS304) substrates coated with b- FeSi2 thin films. To develop spectrally selective emitters, we theoretically propose antireflection (AR) coatings consisting of a single layer of a dielectric material having a high refractive index (~5) and are appropriate for use with metals such as stainless steels in the IR region. This type of AR coating is fabricated by sputtering a b- FeSi2 thin film on a polished SUS304 substrate. The reflectance in the IR region is successfully reduced to less than 10%. In addition, the AR properties are stable even at 700 K in air. Therefore, metals with AR coatings of b- FeSi2 can be applied to IR em...

KoreaScience (Korea)

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Science.gov (United States)

We consider a unified model of Fe ion acceleration in the solar corona. The model comprises charge-changing processes, Coulomb energy losses, and both regular and stochastic acceleration. At a given acceleration scenario, the type of acceleration is found to have a minor effect on the mean charge states, but the shapes of the charge-state distributions produced by regular acceleration and by stochastic acceleration are different. During a continual acceleration at coronal temperatures, iron ions typically follow rising trajectories on the charge-energy plane. These trajectories are situated below the mean equilibrium charge curve defined from the balance of ionization and recombination at fixed energy. During stopping, the iron ions cross the equilibrium charge curve and run through a series of charge states above the mean equilibrium charge at current energy, because the Coulomb deceleration rate significantly exceeds the ...

Energy Technology Data Exchange (ETDEWEB)

The goal of this project is to provide materials engineers, chemical engineers and plant operators with a software tool that will enable them to predict localized corrosion of process equipment including fabricated components as well as base alloys. For design and revamp purposes, the software predicts the occurrence of localized corrosion as a function of environment chemistry and assists the user in selecting the optimum alloy for a given environment. For the operation of existing plants, the software enables the users to predict the remaining life of equipment and help in scheduling maintenance activities. This project combined fundamental understanding of mechanisms of corrosion with focused experimental results to predict the corrosion of advanced, base or fabricated, alloys in real-world environments encountered in the chemical industry. At the heart of this approach is the development of models that predict the fundamental parameters that control the ...

CERN Document Server

Upcoming high-intensity laser systems will be able to probe the quantum-induced nonlinear regime of electrodynamics. So far unobserved QED phenomena such as the discovery of a nonlinear response of the quantum vacuum to macroscopic electromagnetic fields can become accessible. In addition, such laser systems provide for a flexible tool for investigating fundamental physics. Primary goals consist in verifying so far unobserved QED phenomena. Moreover, strong-field experiments can search for new light but weakly interacting degrees of freedom and are thus complementary to accelerator-driven experiments. I review recent developments in this field, focusing on photon experiments in strong electromagnetic fields. The interaction of particle-physics candidates with photons and external fields can be parameterized by low-energy effective actions and typically predict characteristic optical signatures. I perform first estimates of the accessible new-physics parameter space ...

CERN Document Server

A macroscopic realization of the strange virtual particles is presented. The classical Helmholtz and the quantum mechanical Schr\\"odinger equations are analogous differential equations. Their imaginary solutions are called evanescent modes in the case of elastic and electromagnetic fields. In the case of non-relativistic quantum mechanical fields they are called tunneling solutions. The imaginary solutions of this differential equation point to strange consequences: They are non local, they are not observable, and they described as virtual particles. During the last two decades QED calculations of the imaginary solutions have been experimentally confirmed for phonons, photons, and for electrons. The experimental proofs of the predictions of the non-relativistic quantum mechanics and of the Wigner phase time approach for the elastic, the electromagnetic and the Schr\\"odinger fields will be presented in this article. The results are zero tunneling time and an ...

British Library Electronic Table of Contents (United Kingdom)

Abstract Introduction: Laparoscopic subtotal adrenalectomy (LSA) has emerged as a treatment option in the management of certain adrenal pathologies. After LSA, a satisfactory blood supply to the adrenal remnant is vital to preserve steroid function. The aim of this study was to review the adrenal blood supply with relevance to LSA. Materials and Methods: The adrenal blood supply was examined in three ways: 1) a review of six previous cadaver studies looking at adrenal blood supply; 2) a review of our 164 consecutive laparoscopic adrenalectomies (LAs) (January 1999?January 2009); the details of the main adrenal veins and variants had been prospectively recorded; and 3) dissection of 4 cadaver specimens (macroscopic and histologic examination was performed). Results: The six cadaver studies ...

International Nuclear Information System (INIS)

Shadow effect was used for investigating damage of uranium dioxide monocrystal. The dependence of shadow minimum parameters on fluence of "2"2Ne ions with 172 MeV energy was followed when detecting fission fragments. Ion dose responsible for sufficient microdamage of lattice structure, included into the classification of heavy ion damage effect on monocrystals was determined. The problem of radiation intensity effect on the character of occurred damages was studied. It was established that macroscopic sample failure, caused by generation of considerable mechanical stresses in monocrystal under beam effect could be observed along with microdamages of lattice structure at ion flux density >10"1"2 cm"-"2Xs"-"1.

International Nuclear Information System (INIS)

Contrast agent-enhanced CT scans in nine male patients with histologically proved benign lymphoepithelial lesions of the perotid gland were reviewed. All scans showed cystic-appearing masses with peripheral rim enhancement corresponding to the macroscopic appearance of the lesion. Five patients were seropositive for human immunodeficiency virus (HIV) infection or had infections seen in acquired immunodeficiency syndrome. Three patients were members of high-risk groups. Only one patient had symptoms of the SICCA syndrome. Once a rare cause of parotid gland enlargement, benign lymphoepithelial lesions have recently been seen with increasing frequency in patients with HIV infection. Although the CT appearance is not pathognomic, correlation results of aspiration cytology and with clinical history can lead to a preoperative diagnosis of a benign lymphoepithelial lesion.

British Library Electronic Table of Contents (United Kingdom)

Magnesium fructose-1,6-diphosphate is a novel agent of antimyocardial ischaemia. In the present study, the subchronic toxicity of magnesium fructose-1,6-diphosphate was investigated after 13-week repeated intravenous administration in beagle dogs. The animals received doses of 0, 75, 150 and 300 mg/kg/day (three males and three females for each dose). During the study period, clinical signs, mortality, body weights, food consumption, electrocardiogram, urinalysis, haematology, clinical biochemistry, macroscopic findings, organ weights and histopathology were examined. The administration of magnesium fructose-1,6-diphosphate resulted in increased incidence of clinical signs, including salivation and emesis. These effects were transient and were noted in almost all dogs given 300 mg/kg/day a...

Energy Technology Data Exchange (ETDEWEB)

The quantitative measurement of carbon concentration-distance curves serves as fundamental prerequisite for the evaluation of rim zone properties connected with decarburisation processes in material science. This was shown in part 1 of the present work with two samples from through-hardenable rolling bearing steel 100Cr6 (SAE 52100) austenitised in different oxidising atmospheres by position dependent determination of hardness, residual stresses, and X-ray line broadening ({l_brace}211{r_brace} {alpha}'-Fe diffraction line). In practice, it is important to predict carbon concentration-distance curves under prevailing heat treatment conditions or to conclude conversely from profile measurements. Based on a refined kinetics model of a diffusion-controlled process, part 2 therefore presents a simulation tool developed by means of the finite element method (FEM). Apart from the concentration dependence of the diffusion coefficient, it also ...

Energy Technology Data Exchange (ETDEWEB)

K{beta}-to-K{alpha} X-ray intensity ratios of Ti, Cr, Fe and Co in pure metals and in Cr{sub 0.26}Fe{sub 0.74}, Cr{sub 0.80}Co{sub 0.20} and Ti{sub 0.80}Cr{sub 0.20} alloys have been measured following excitation by 59.54 keV {gamma}-rays from a 7400 MBq (200 mCi) {sup 241}Am point-source. The valence electronic structure of Ti, Cr, Fe and Co in the samples have been evaluated by the comparison of the measured K{beta}-to-K{alpha} intensity ratios with the results of multiconfiguration Dirac-Fock calculations performed for various electronic configurations of these metals. The 3d-electron populations obtained for pure metallic Ti, Cr, Fe and Co agree well with the results of band structure calculations of Papaconstantopoulos (Handbook of band structure of elemental solids, Plenum Press, New York, 1986). Our analysis indicates significant increase of 3d-electron population of Ti, Cr and ...

Energy Technology Data Exchange (ETDEWEB)

Reasons were revealed for the fresh water resistance of sediments of hydrolyzed polyacrylonitrile obtained from interaction of it with Fe/sup 3 +/, Ca/sup 2 +/ and Cu/sup 2 +/ cations which are in the saline solutions of these metals.

Energy Technology Data Exchange (ETDEWEB)

An Fe-19Cr-8Al-0.5Hf alloy has been roll bonded to Alloy 800 to form a protective clad material suitable for use in coal conversion atmospheres. The commercial producibility of both the Fe-19Cr-8Al-0.5Hf alloy and the clad composite has been demonstrated. The clad composite has been shown to exhibit resistance to sulfidation in high sulfur, coal gasification atmospheres low Btu for 2000 hrs at 1800/sup 0/F (1255K). The FeCrAlHf alloy must be preoxidized in the absence of sulfur to form fully protective alumina scales on all surfaces. Useful life of the composite at temperatures of 1400 to 2000/sup 0/F (1033 to 1366K) is governed by reactions at the FeCrAlHf clad alloy 800 interface. The rate of interdiffusion decreases with increasing Ni content and a high Ni alloy such as RA333 appears to be a better substrate than Alloy 800 for a FeCrAlHf composite. The mechanical properties of ...

UK PubMed Central (United Kingdom)

The alternative low-spin states of Fe³⁺ and Fe²⁺ cytochrome c induced by SDS or AOT/hexane reverse micelles exhibited the heme group in a less...Full Text Available

International Nuclear Information System (INIS)

Radiometric X-ray fluorescence analysis was used for the determination of Mn, Fe, Cu, Zn and Pb in wastewater and sludges from three wastewater treatment plants in Bratislava (SR). Metals were determined in wastewaters after preconcentration by 8-hydroxyquinoline and in sludges by drying and pressing to pellets. "2"3"8Pu and "1"0"9Cd was used for excitation of fluorescence radiation. (author).

Energy Technology Data Exchange (ETDEWEB)

The nano-structured Fe(III)-doped TiO{sub 2} photocatalysts with anatase phase have been developed for the oxidation of non-biodegradable different organic dyes like methyl orange (MO), rhodamine B (RB), thymol blue (TB) and bromocresol green (BG) using UV-Hg-lamp. The different compositions of Fe{sub x}Ti{sub 1-x}O{sub 2} (x = 0.005, 0.01, 0.05, and 0.1) nanocatalysts synthesized by chemical method (CM), have been characterized by X-ray diffraction (XRD), UV-vis diffuse reflectance spectra, specific surface area (BET), transmission electronic microscopy (TEM) analysis, XPS, ESR and zeta potential. From XRD analysis, the results indicate that all the compositions of Fe(III) doped in TiO{sub 2} catalysts gives only anatase phase not rutile phase. For complete degradation of all the solutions of the dyes (MO, RB, TB, and BG), the composition with x = 0.005 is more photoactive compared all other compositions of ...

International Nuclear Information System (INIS)

In the present paper the progress of optimization of soft magnetic properties have been studied by applying different experimental techniques (magnetic measurements, electric measurements, X-ray analysis, and high-resolution electron microscopy observation). It has been shown that an increase in magnetic permeability after optimization annealing can be mainly attributed to annealing out of microvoids. (author)

Energy Technology Data Exchange (ETDEWEB)

A method for bistable storage of binary optical information includes an antiferroelectric (AFE) lead lanthanum zirconate titanate (PLZT) layer having a stable antiferroelectric first phase and a ferroelectric (FE) second phase obtained by applying a switching electric field across the surface of the device. Optical information is stored by illuminating selected portions of the layer to photoactivate an FE to AFE transition in those portions. Erasure of the stored information is obtained by reapplying the switching field.

Energy Technology Data Exchange (ETDEWEB)

Results of experimental researches of impurity level crystals Fe1-xCoxSi are presented in this article. Magnetic properties in a temperature range up to T {<=} 1000 K are analyzed. It was established that with Co impurities increasing origin of magnetic ordering exists at low temperatures. At high temperatures a high temperature maximum of susceptibility of nominally pure iron monosilicide crystal is observed.

Energy Technology Data Exchange (ETDEWEB)

Energy spectra of the Bragg reflection of the Moessbauer ..gamma..-radiation from the /sup 57/Fe/sub 3/BO/sub 6/ weakly ferromagnetic monocrystal are studied. A strong effect of the interference transitions in iron nuclei, being in non-equivalent positions, on the spectra form is revealed. The measurement results are compared with theoretical calculations.

Energy Technology Data Exchange (ETDEWEB)

In this work, the ability of a number of Zr-containing intermetallic compounds with the Zr{sub 2}Me stoichiometry, including Zr{sub 2}Fe, Zr{sub 2}Ni, Zr{sub 2}Co and Zr{sub 4}Fe{sub 2}O{sub 0.6}, to participate in the Hydrogenation-Disproportionation-Desorption-Recombination process was investigated, revealing for the first time that the HDDR route can be employed successfully for all these compounds. 24 refs.

Energy Technology Data Exchange (ETDEWEB)

The structure and pore morphology, the isothermal and continuous time-temperature conversion characteristics and the effects of heat treatment on the mechanical properties and microstructural processes were investigated in 4 copper-free recycleable PM steels Fe4Ni0,5Mo+0,5%C ({rho}=7,12 g/cm{sup 3}, HT-sintered), Fe4N0,5Mo+0,7%C ({rho}=7,12 g/cm{sup 3}, sinter-hardened), Fe1,5Mo+0,5%C and Fe1,5Mo+0,5%C+0,5%CEP ({rho}=7,3 resp. 7,32 g/cm{sup 3}, HT-sintered). [German] In dieser Arbeit wurden an den vier kupferfreien rezyklierfaehigen PM-Staehlen Fe4Ni0,5Mo+0,5%C ({rho}=7,21 g/cm{sup 3}, hochtemperaturgesintert), Fe4Ni0,5Mo+0,7%C ({rho}=7,12 g/cm{sup 3}, sintergehaertet), Fe1,5Mo+0,5%C und Fe1,5Mo+0,5%C+0,5%CEP ({rho}=7,3 bzw. 7,32 g/cm{sup 3}, hochtemperaturgesintert) die Gefuege und die Porenmorphologie, das isotherme ...

International Nuclear Information System (INIS)

Radionuclide X-ray fluorescence method was used for the determination of Fe and Zn in healing plants (Sage, Peppermint, Stinging, Common Agrimony, Milfoil, Ribwort, Tansy, White Dead-Nettle). "2"3"8Pu exciting source and Si/Li semiconductor detector were used for the determination. (author)

International Nuclear Information System (INIS)

The reactions of alpha particles on natural abundance chromium have been studied between 40 and 110 MeV, in order to produce "5"2Fe for medical use. The yield of the reaction "5"2Cr(#alpha#,4n)"5"2Fe for Esub(#alpha#) = 85 #-># 53 MeV is only 30 #mu#Ci/#mu#Ah. (orig.).

Energy Technology Data Exchange (ETDEWEB)

Superparamagnetic MFe{sub 2}{sup 3+}O{sub 4} (M=Mn{sup 2+}, Fe{sup 2+} and Co{sup 2+}) inverse spinel ferrite (ISF) nanoparticles with narrow size distribution having average diameters of 6-8 nm were synthesized by a diol reduction of organic metals and the surface was modified to be hydrophilic by coating with succimer. Magnetic resonance imaging (MRI) contrast enhancement by dipolar coupling defined interactions between the synthesized ISFs and protons in the bulk water was investigated with initial susceptibility, magnetization and anisotropy of the succimer-coated ISFs. The relaxivity ratios, r{sub 2}/r{sub 1}, for MnFe{sub 2}O{sub 4}, Fe{sub 3}O{sub 4} and CoFe{sub 2}O{sub 4} were measured to be 12.2, 23.1 and 62.3, respectively, which demonstrate the potential usefulness of these magnetic nanoparticles as T{sub 2} contrast agents for MRI.

International Nuclear Information System (INIS)

Electrodeposition of semiconducting iron oxide (Fe_2O_3) thin film was carried out from an alkaline sulphate bath. A 0.1 M ferrous sulphate (FeSO_4#centre dot#7H_2O) was complexed with 0.1 M citric acid. By addition of 1 N NaOH, pH of the solution was made alkaline (pH=9) and deposition of iron oxide (Fe_2O_3) thin films was carried out potentiostatically at room temperature (300 K). From cyclic voltametry (CV), electrochemical studies were carried out for deposition of iron oxide thin films. The XRD studies reveal that Fe_2O_3 with epsilon (#epsilon#) phase having monoclinic crystal structure is formed. By observing scanning electron microscope (SEM), it is seen that iron oxide films were homogeneous, uniform and well covered to surface of the substrate. Grain size was found to be in nanometers range from XRD analysis. The optical band gap of Fe_2O_3 thin film was estimated to be ...

Energy Technology Data Exchange (ETDEWEB)

It is thought that iron-based catalysts for coal liquefaction exercise their catalytic activity by forming pyrrhotite (Fe(1-x)S). However, there are still a lot of unknown problems remained concerning the formation and agglomeration behaviors of pyrrhotite. These make a difficulty for improving the activity of iron-based catalysts. In this study, sulfiding behaviors of {alpha}-iron oxyhydroxide ({alpha}-FeOOH) and {gamma}-iron oxyhydroxide ({gamma}-FeOOH) were investigated to reveal the formation and agglomeration behaviors of pyrrhotite. It was found that pyrrhotite was easily converted from ferric oxyhydroxide catalysts having large specific surface areas at the sulfiding temperature below 250{degree}C, and fine crystallites of pyrrhotite were formed at the initial stage of sulfiding. Crystal growth of pyrrhotite at the sulfiding temperature over 350{degree}C depended on the catalyst forms. It was also found that smaller ...

International Nuclear Information System (INIS)

An analysis of the passive films formed on amorphous alloys of the system Fe-10% Cr-5% Mo-P-metalloid and Fe-10% Cr-5% Mo-B-Si revealed that they are more markedly enriched with chromium in silicon-free alloys. In silicon-containing amorphous alloys the passive films were highly enriched with silicon, which occurred in these films in the form of a corrosion product close to SiO_2. As shown by the investigations of a study of the anodic behavior of Fe_4_0Ni_4_0P_1_4B_6 and Fe_4_0Ni_3_8Mo_4B_1_8, phosphorus facilitates the passivation of amorphous alloys by reducing the solution current in the active state and enriching the surface layers of the metal in the form of a black prepassivation film which also contains nickel and iron. The behavior of Fe-Ni amorphous alloys containing only boron as metalloid additive differs little from that of crystalline alloys of similar composition but ...

International Nuclear Information System (INIS)

Laser glazing, using a KrF excimer laser (> = 248 nm, >a = 22 ns), has been used to improve the corrosion resistance properties of crystallized Fe_4_0Ni_3_8Mo_4B_1_8 (Metglas 2826 MB) and the permanent magnet material Nd_1_5Fe_7_7B_8. The formation of an amorphous layer was confirmed by conversion-electron Mossbauer Spectroscopy (CEMS), and the thickness of the amorphous layer was determined from the attenuation of the x-rays diffracted from the underlying crystalline material. The variation with laser fluence of the amorphous layer thickness on the Metglas were measured. The corrosion properties of the original, crystalline and laser glazed Metglas were measured potentiodynamically in acid electrolyte. Similar voltametric characteristics were obtained for the laser glazed surface and original Metglas, both showing a lower current in the passive region than the crystalline material. Laser glazing of the ...

Energy Technology Data Exchange (ETDEWEB)

The effects of Fe and B{sub 4}C on the sintering behavior and mechanical properties of TiB{sub 2} ceramics have been studied. Sintering was performed in an Ar atmosphere at 2000{degrees}C using attrition-milled TiB{sub 2} powder. When a small amount of Fe (0.5 wt%) was added, abnormal grain growth occurred and the sintered density was low. In the case of B{sub 4}C added along with 0.5 wt% Fe, however, abnormal grain growth was remarkably suppressed, and the sintered density was increased up to 95% of theoretical. But with excess Fe addition (5 wt%), B{sub 4}C grains did not act as a grain growth inhibitor, and B{sub 4}C grains were frequently trapped in large TiB{sub 2} grains. The best mechanical properties were obtained for the TiB{sub 2}-10 wt% B{sub 4}C-0.5 wt% Fe ceramics, which exhibited a three-point bending strength of 400 MPa and a fracture toughness of 5.5 MPa {center dot} ...

Energy Technology Data Exchange (ETDEWEB)

Corrosion of several materials including pure metals Fe, Ni, Cr and also Fe-Cr, Fe-Ni-Cr alloys, has been studied in anisothermal Pb17Li (Tmax = 500 deg C; {Delta}T = 60 deg C). The corrosion rate of pure nickel is two orders of magnitude higher than the chromium one and about three orders of magnitude higher than the iron one. Fe-Cr alloys (1.4914) suffers a dissolution rate equal to the one of its major constituent, iron. With regard to the three austenitic materials (316L and NS20 steels, alloy 800), they exhibit a porous corrosion layer mainly constituted of ferrite but containing also a small amount of {sigma} phase in the case of the alloys with higher Ni content, NS30 steel and alloy 800. Mechanism of formation of this layer is discussed.

Energy Technology Data Exchange (ETDEWEB)

The study of passive films formed on a nickel base alloy type Inconel 600 is performed by capacitance measurements (Mott-Schottky approach). This research is supported by the passivation study of the alloying elements Ni, Cr, Fe and high purity alloys Ni-Cr, Ni-Fe, Ni-Cr-Fe. The results obtained show that the capacitive behaviour of the Inconel 600 in the passive state is similar to that on a p-n heterojunction to which a barrier zone of nickel oxide is added. The individual or combined action of alloying elements on the development of this kind of electronic structure is discussed. (authors). 5 refs., 6 figs.

Energy Technology Data Exchange (ETDEWEB)

We report the experimental and theoretical results on the anisotropies in the magnetic properties and x-ray absorption spectra of single-crystal LiFePO4. A mean-field theory is developed to explain the observed strong anisotropies in Lande g-factor, paramagnetic Curie temperature, and effective moment for LiFePO4 single crystals. The values of the in-plane nearest- and next-nearest-neighbor spin exchange (J1 and J2), interplane spin exchange (J{perpendicular}), and single-ion anisotropy (D), obtained recently from neutron scattering measurements, are used for calculating the Curie temperatures with the formulas derived from the mean-field Hamiltonian. It is found that the calculated Curie temperatures match well with that obtained by fitting the magnetic susceptibility curves to the modified Curie-Weiss law. For the polarized Fe K-edge x-ray absorption spectra of single-crystal LiFePO4, a different ...

International Nuclear Information System (INIS)

We present an abundance analysis based on high-resolution spectra of 10 stars selected to span the full range in metallicity in the Ursa Minor (UMi) dwarf spheroidal (dSph) galaxy. We find that [Fe/H] for the sample stars ranges from -1.35 to -3.10 dex. Combining our sample with previously published work for a total of 16 luminous UMi giants, we establish the trends of abundance ratios [X/Fe] as functions of [Fe/H] for 15 elements. In key cases, particularly for the #alpha#-elements, these trends resemble those for stars in the outer part of the Galactic halo, especially at the lowest metallicities probed. The neutron-capture elements show an r-process distribution over the full range of Fe metallicity reached in this dSph galaxy. This suggests that the duration of star formation in the UMi dSph was shorter than in other dSph galaxies. The derived ages for a larger sample of UMi stars with more ...

Energy Technology Data Exchange (ETDEWEB)

Non-uniform radionuclide distribution in tumours will lead to a non-uniform absorbed dose. The aim of this study was to investigate how tumour control probability (TCP) depends on the radionuclide distribution in the tumour, both macroscopically and at the subcellular level. The absorbed dose in the cell nuclei of tumours was calculated for {sup 90}Y, {sup 177}Lu, {sup 103m}Rh and {sup 211}At. The radionuclides were uniformly distributed within the subcellular compartment and they were uniformly, normally or log-normally distributed among the cells in the tumour. When all cells contain the same amount of activity, the cumulated activities required for TCP = 0.99 (A-tilde{sub TCP=0.99}) were 1.5-2 and 2-3 times higher when the activity was distributed on the cell membrane compared to in the cell nucleus for {sup 103m}Rh and {sup 211}At, respectively. TCP for {sup 90}Y was not affected by different radionuclide distributions, whereas for {sup 177}Lu, it was slightly ...

International Nuclear Information System (INIS)

The Wendelstein 7-X (W7-X) modular stellarator is under construction at the Max-Planck-Institut fuer Plasmaphysik in Greifswald, Germany. The W7-X magnet system contains 70 coils made up from helium cooled superconducting cables in aluminium alloy (EN AW-6063) jackets. Several hundred connections of the jacket to the cable joints are made by aluminium-to-aluminium welds. Due to geometrical and thermal boundary conditions these welds cannot be accomplished free from defects. Microscopic analyses of the welds show that a variety of small flaws such as cracks and pores develop during welding. The welds have thus to be dimensioned accordingly, and appropriate weld qualification, investigation and testing has to be done in order not to jeopardise the structural integrity and leak tightness. The weld is mechanically loaded during cool-down due to the difference in thermal contractions between the GRP insulation and the aluminium, and during operation by bending moments from electromagnetic ...

Energy Technology Data Exchange (ETDEWEB)

The first study in this dissertation describes the development of a suppressed ion chromatographic (SIC) technique for the direct, simultaneous determination of the As and Se oxyanions in soil solution. Baseline resolution of 1 mg L[sup [minus]1] each of arsenite, arsenate, selenite, and selenate was achieved in the presence of 50 mg L[sup [minus]1] each of F, Cl, NO[sub 3]-N, SO[sub 4]-S, and PO[sub 4]-P. Detection limits ranged from 0.026 mg L[sup [minus]1] for selenite to 0.120 mg L[sup [minus]1] for arsenate. The accuracy of the SIC technique was verified by comparison to spectroscopic methods. The second study investigated the suitability of linear-plateau regression analysis for statistical evaluation of As adsorption data. The time required to reach the adsorption plateau depended on soil characteristics and As species. Identification of the adsorption plateau by the linear-plateau model allowed comparison of adsorption rates and maxima through analysis of ...

International Nuclear Information System (INIS)

The DNA double-strand break (DSB) damage response induced by high energy charged particles on lung fibroblast cells embedded in a 3-dimensional (3-D) collagen tissue equivalents was investigated using antibodies to the DNA damage response proteins gamma-histone 2AX (#gamma#-H2AX) and phosphorylated DNA-PKcs (p-DNA-PKcs). 3-D tissue equivalents were irradiated in positions across the linear distribution of the Bragg curve profiles of 307.7 MeV/nucleon, 556.9 MeV/nucleon, or 967.0 MeV/nucleon "5"6Fe ions at a dose of 0.30 Gy. Patterns of discrete DNA damage streaks across nuclei or saturated nuclear damage were observed, with saturated nuclear damage being more predominant as samples were positioned closer to the physical Bragg peak. Quantification of the DNA damage signal intensities at each distance for each of the examined energies revealed a biological Bragg curve profile with a pattern of DNA damage intensity similar to the physical Bragg curve for the ...

Energy Technology Data Exchange (ETDEWEB)

Carbon capture and storage have been receiving increasing interest lately, mainly as an option to reduce CO{sub 2} emissions from the power sector. The concept could be adapted for production of H{sub 2} as well, which would provide a carbon free energy carrier that could be used for example as transportation fuel. In this doctoral thesis, the option to use chemical-looping technologies to produce H{sub 2} from fossil fuels with CO{sub 2} capture is explored. In chemical-looping combustion, direct contact between fuel and combustion air is avoided. Instead, a solid oxygen carrier performs the task of bringing oxygen from the air to the fuel. Thus, the resulting CO{sub 2} and H{sub 2}O are not diluted with N{sub 2}, and pure CO{sub 2} can easily be recovered by cooling and condensation. The heat of reaction is the same as for ordinary combustion. Chemical-looping reforming uses the same basic principles as chemical-looping combustion, but operates at under stoichiometric conditions. ...

Energy Technology Data Exchange (ETDEWEB)

Biosorption of heavy metals by various biological materials has been studied extensively in the last decade due to its potential particularly in wastewater treatment. The presence of a large number of metals in industrial metal-bearing solutions makes it necessary to investigate their effect on the final metal uptake by individual biosorbent materials. Nonliving biomass of Sargassum, a brown marine alga, is capable of binding more than 10% of its dry weight in toxic cadmium ions. Although ubiquitous iron interferes with Cd uptake, only approximately 4.5% of it is sequestered (biomass dry weight). Biosorption of both metals at pH 4.5 could be described by Langmuir-type isotherms with b, the affinity-related coefficient (Cd: b = 0.015; Fe: b = 0.027). The interference of Fe with Cd uptake, and vice versa, was assessed by deriving three-dimensional equilibrium two-metal sorption isotherm surfaces, smoothed and cut to reveal the inhibition effect ...

International Nuclear Information System (INIS)

Alloying elements such as Fe and Cr are generally considered to be effective even in small quantities for corrosion resistance of Zircaloy-4. The maximum total solubility of Fe + Cr in a Zr-Sn matrix has been reported to be very low. Therefore, most of these elements are observed in the form of ternary Zr-Fe-Cr-type precipitates. To clarify the effects of precipitates on corrosion property, Zr-1.3 Sn-(Fe,Cr) alloys containing Fe + Cr from 45 up to 180 ppm (the Fe to Cr ratio is about 2) were melted from pure zirconium (X-bar Zr and EB-Zr) and pure alloying elements. They were subjected to corrosion testing in 633 K water and microstructural analysis. It was found that precipitate-free materials showed much larger weight gains than precipitate-containing materials even at the same alloy compositions. Subsequently, a corrosion test on the precipitate-free material ...

International Nuclear Information System (INIS)

Photoelectrochemical current response of passive film was investigated for pure Cr and Fe-xCr (x = 8, 14, 18) alloys polarised potentiostatically in 0.1 kmol m"-"3 H_2SO_4 solution. Photoelectrochemical action spectrum could be separated into two or three constituents. These components were considered to be derived from Cr_2O_3 (E_g"o"p"t#propor to#3.6 eV) and Cr(OH)_3 (E_g"o"p"t#propor to#2.5 eV), and possibly CrO OH. The optical band gap, E_g"o"p"t, of each component was almost constant for various applied potentials, polarisation periods, and substrate materials. Flat band potential E_j_b at which the polarity of photocurrent changes from negative to positive with increasing potential was determined for each phase. E_j_b for Cr(OH)_3 on Cr and Fe-Cr alloys was about 250 mV_A_g_/_A_g_C_l. E_j_b for Cr_2O_3 was about 700 mV for Cr and about 500 mV for Fe-Cr alloys. E_j_b of Cr_2O_3 for Fe-Cr alloys ...

British Library Electronic Table of Contents (United Kingdom)

Two analytical methods were proposed in this research, coupled electro-thermal finite element (FE) analysis and thermal-mechanical FE analysis, to analyze the mechanical behavior of bonding wire of power module under cyclic power loads, and the International Electrotechnical Commission standard is adopted in conducting a power cycling test. The exterior temperature distribution was measured by an infrared thermometer. Moreover, the junction temperature is calculated from the given thermal impedance of the semiconductor chip, chip power loss, and case temperature. Subsequently, the simulated temperature distribution via electro-thermal FE analysis is compared with experimental results to validate the methodology used in the aforementioned analysis. The analysis shows compressive stress at t...

Energy Technology Data Exchange (ETDEWEB)

Fatigue tests were accomplished with a series of specimens doped with trace elements of a hardened Fe-Ni-Cr alloy, cast and hardened with intermetallic phases for determining the influence of these elements on the high temperature strength properties. The results of extensive fatigue tests show that even small contents of Te, Bi, Se, Pb, Tl and Zn considerably influence the life and creep processes especially after longer running periods, when added individually or combinedly. In contrast to this, the fatigue ductility is reduced by trace element additions even with short running periods. The order in which the metallic trace elements influence the fatigue properties nearly correlates with earlier work concerning Ni- and Co-superalloys. (orig.)

British Library Electronic Table of Contents (United Kingdom)

Under changing redox conditions some plants create plaques at their root surface, which may affect the mobility and uptake of As and heavy metals but it is unknown to what extent this also holds true for willows in contaminated floodplain soils. Therefore, willow roots were sampled from a phytoremediation trial in the contaminated floodplain of the river Elbe (Germany), cryofixed, freeze-dried, and cross sections were mapped for the distribution of As, Ca, Cu, Fe, K, Mn, Ni, S and Zn by synchrotron based X-ray fluorescence spectroscopy. The elements Ca, Cu, Ni, S and Zn were concentrated in the aerenchymatic tissue, and not associated with Fe and Mn. Mixed Fe-Mn plaques covered the surface of the willow roots and As was accumulated in these plaques. The observed association pattern between...

British Library Electronic Table of Contents (United Kingdom)

Gas nitridation has shown excellent promise to form dense, electrically conductive and corrosion-resistant Cr-nitride surface layers on Ni-Cr base alloys for use as proton exchange membrane fuel cell (PEMFC) bipolar plates. Due to the high cost of nickel, Fe-base bipolar plate alloys are needed to meet the cost targets for many PEMFC applications. Unfortunately, nitridation of Fe-base stainless steel alloys typically leads to internal Cr-nitride precipitation rather than the desired protective surface nitride layer formation, due to the high permeability of nitrogen in these alloys. This paper reports the finding that it is possible to form a continuous, protective Cr-nitride (CrN and Cr2N) surface layer through nitridation of Fe-base stainless steel alloys. The key to form a protective Cr...

Energy Technology Data Exchange (ETDEWEB)

Moessbauer spectra of the imitative ancient Jun porcelain indicate that the glaze and body materials contain Fe{sub 2}O{sub 3}, Fe{sub 3}O{sub 4} and structural iron. It is clear that during the firing process, the glaze undergoes dehydration, dehydroxylation, vitrification and recrystallization. The Fe{sup 2+} quadrupole splitting value of the paramagnetic peak of the body material is high even at low firing temperatures. For the body material, the distinction between dehydration and dehydroxylation is not clear. The changes of magnetism of the glaze and body materials in the firing process and the coloring mechanism of the sky-blue Jun porcelain are analyzed in the present paper. (orig.)

Energy Technology Data Exchange (ETDEWEB)

The magnetic properties of diluted spinels Zn{sub 1-x}M{sub x}Fe{sub 2}O{sub 4} (M = Mg, Ni) systems have been studied by mean field theory, probability law and high-temperature series expansions method in the range 0 {<=} x {<=} 1. The exchange interactions are calculated by the first and second theory, respectively. The magnetic phase diagrams of Zn{sub 1-x}M{sub x}Fe{sub 2}O{sub 4} (M = Mg, Ni) are calculated by the high-temperature series expansions, combined with the Pade approximants method. The critical exponent associated with the magnetic susceptibility ({gamma}) is deduced.