International Nuclear Information System (INIS)

... argon carbon dioxide cations electric fields gases helium ion mobility molecular

International Nuclear Information System (INIS)

For pt.I see ibid., vol.516, p.426-48, 1998. Manifest N=2 supersymmetric hypermultiplet mass terms can be introduced in the projective N=2 superspace formalism. In the case of complex hypermultiplets, where the gauge covariantized spinor derivatives have an explicit representation in terms of gauge prepotentials, it is possible to interpret such masses as vacuum expectation values of an Abelian vector multiplet. The duality transformation that relates the N=2 off-shell projective description of the hypermultiplet to the on-shell description involving two N=1 chiral superfields allows us to obtain the massive propagators of the N=1 complex linear fields in the projective hypermultiplet. The N=1 massive propagators of the component superfields in the projective hypermultiplet suggest a possible ansatz for the N=2 massive ...

Energy Technology Data Exchange (ETDEWEB)

In order to establish coal NOx preventive measures, discussions were given on formation of N2 in the fixed-bed pyrolysis of low rank coals and the mechanisms thereof. Chinese ZN coal and German RB coal were used for the discussions. Both coals do not produce N2 at 600{degree}C, and the main product is volatile nitrogen. Conversion into N2 does not depend on heating rates, but increases linearly with increasing temperature, and reaches 65% to 70% at 1200{degree}C. In contrast, char nitrogen decreases linearly with the temperature. More specifically, these phenomena suggest that the char nitrogen or its precursor is the major supply source of N2. When mineral substances are removed by using hydrochloric acid, their catalytic action is lost, and conversion into N2 decreases ...

International Nuclear Information System (INIS)

Cross-sections for "8"4Sr(n, 2n)"8"3Sr, "8"6Sr(n, 2n)"8"5"mSr, "8"6Sr(n, 2n)"8"5Sr, "8"8Sr(n, 2n)"8"7"mSr, "8"4Sr(n, p)"8"4Rb, "8"6Sr(n, p)"8"6Rb, "8"8Sr(n, p)"8"8Rb and "8"8Sr(n, #alpha#)"8"5"mKr reactions have been measured at neutron energies from 13.5 to 14.6 MeV using activation technique and by means of #gamma#-ray spectrometry. The neutron flux was determined using the monitor reaction "9"3Nb(n, 2n)"9"2"mNb and the neutron energies were measured by the method of cross-section ratios for "9Zr(n, 2n)"8"9Zr to "9"3Nb (n, 2n)"9"2"mNb reactions. The results of present work are compared with data published previously.

KoreaScience (Korea)

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British Library Electronic Table of Contents (United Kingdom)

The fossil fuel consumption and pollutant emissions in a coal fired fluidized bed boiler could be reduced by biomass pyrolysis gas reburning. The influence of three kinds of biomass pyrolysis gases on the emission of N2O in a laboratory scale fluidized bed was investigated using the mechanism of GRI3.0 in this paper. The results showed that: the effect of sawdust pyrolysis gas reburning on N2O was more significant than that of rice husk and orange peel under the same conditions; the increase of initial oxygen content from 1% to 8% in flue gas would restrain the decomposition of N2O; the N2O decomposition was enhanced by increasing reaction temperature from 1073.15 K to 1323.15 K, and the decomposition rate may reach 99% at 1223.15 K.

Energy Technology Data Exchange (ETDEWEB)

Amino acids other than those that serve as ligands have been found to influence the chemical properties of transferrin iron. The catalytic ability of pyrophosphate to mediate transferrin iron release to a terminal acceptor is largely quenched by modification non-liganded histine groups on the protein. The first order rate constants of iron release for several partially histidine modified protein samples were measured. A statistical method was employed to establish that one non-liganded histidine per metal binding domain was responsible for the reduction in rate constant. These results imply that the iron mediated chelator, pyrophosphate, binds directly to a histidine residue on the protein during the iron release process. EPR spectroscopic results are consistent with this interpretation. Kinetic and amino acid sequence studies of ovotransferrin and lactoferrin, in addition to human serum transferrin, have allowed the tentative assignment of His-207 in the N-terminal domain and His-535 ...

Energy Technology Data Exchange (ETDEWEB)

The effect of combustion conditions on conversion of char nitrogen to N2 was studied in the combustion experiment of char obtained by pyrolysis of coal. Char specimen was prepared by holding ZN coal of Chinese lignite in Ar atmosphere at 1123K for one hour. A batch scale quartz-made fluidized bed reactor was used for combustion experiment. After the specimen was fluidized in reaction gas, it was rapidly heated to start combustion reaction. CO, CO2 and N2 in produced gases were online measured by gas chromatography (GC). As the experimental result, under the incomplete combustion condition where a large amount of CO was produced by consuming almost all of O2, no NOx and N2O produced from char were found, and almost all of N-containing gas was N2. At the final stage of combustion, pyridinic-N disappeared completely, and ...

International Nuclear Information System (INIS)

Short communication.

Energy Technology Data Exchange (ETDEWEB)

This dissertation is devoted to the study of the phenomenological consequences of the three-generation heterotic string models based on the Calabi-Yau compactifications and the N = 2 superconformal constructions.

International Nuclear Information System (INIS)

... kinetics chemical reactions energy dependence ion-molecule collisions milli

CERN Document Server

We study N=2 SuperVirasoro SCFT for the generic value of the central charge. The main tool is the nonstandard bosonisation suggested in \\ref\\rRoz{L. Rozansky a letter to M. Bershadsky, 1989}, \\ref\\rSeBGR{B. Gato-Rivera, A. Semikhatov Phys. Letts. B293 (1992) 72},\\ref\\rBLNW{M. Bershadsky, W. Lerche, D. Nemeshansky, N. Warner N=2 Extended superconformal structure of Gravity and W Gravity coupled to Matter HUTP-A034/92}. The free field resolutions for the irreducible representations are obtained; the characters of these representations are computed. The quantum hamiltonian reduction from the Kac-Moody $\\hat{sl}_k(2|1)$ to N=2 $SVir$ is constructed.

Energy Technology Data Exchange (ETDEWEB)

We study the relationship between tachyons in N=2 superconformal tensor product models and topology changing of the defining polynomial of corresponding algebraic varieties. We show that monomials which correspond to tachyons change the topology of the defining polynomial if they are added whereas those corresponding to massless and massive fields do not. (orig.).

British Library Electronic Table of Contents (United Kingdom)

The cyclization has been studied of N-(2-cyclopent-1-en-1-ylphenyl)benzamides into the corresponding 3,1-benzoxazines by the action of gaseous hydrogen chloride, trifluoroacetic acid, or bromine, and also under conditions of electron impact in the gas phase. A scheme is proposed for the fragmentation of the molecular ions of the products obtained.

International Nuclear Information System (INIS)

We obtain conformal invariant topological field theories with N = 2 supersymmetry by twisting Sevrin, Troost and Van Proeyen's SU(2) x SU(2) x U(1) extended N = 4 superconformal field theories. We expect that the number of physical states is finite although the original N = 4 theories have continuous spectra. It is shown that the number of physical states is actually finite when the central charge c < 6 in the corresponding N = 4 theories. The physical states inherit the structure of the chiral ring in N = 2 superconformal minimal series which is obtained by the reduction from N = 4 theories. We also show that the algebra contains the topological N = 4 superconformal algebra as subalgebra. Therefore a closed set of a finite number of physical states in the topological N = 1 superconformal algebra can also be obtained. (orig.).

International Nuclear Information System (INIS)

Measurements are made of the isomeric ratio for the (n,2n) and (#betta#,n) reactions on the neutron-deficient nuclei _9_2Mo, _9_0Zr, _8_6Sr and _7_4Se. A method is developed for calculating the isomeric ratio for a low excitation energy of the residual nucleus. The good agreement found between experimental results and calculations for the (#betta#,n) reaction confirms the choices of residual nucleus characteristics, transmission coefficients of neutrons emitted etc. used in the calculations. The results of a study of the (n,2n) reaction were used to find the spin dependences of nuclear level density in the excitation energy region approx. 14 MeV. (author).

CERN Document Server

Recently we discovered and discussed non-Abelian duality in the quark vacua of N=2 super-Yang-Mills theory with the U(N) gauge group and N_f flavors (N_f>N). Both theories from the dual pair support non-Abelian strings which confine monopoles. Now we introduce an N=2-breaking deformation, a mass term \\mu{\\mathcal A}^2 for the adjoint fields. Starting from a small deformation we eventually make it large which enforces complete decoupling of the adjoint fields. We show that the above non-Abelian duality fully survives in the limit of N=1 SQCD, albeit some technicalities change. For instance, non-Abelian strings which used to be BPS-saturated in the N=2 limit, cease to be saturated in N=1 SQCD. Our duality is a distant relative of Seiberg's duality in N=1 SQCD. Both share some common features but have drastic distinctions. This is due to the fact that ...

International Nuclear Information System (INIS)

The details and principles of an apparatus built for measurements of fluorescence quantum yields and cascade-free lifetimes of open-shell cations are reported. These rely on the detection of coincidences between energy selected photo-electrons and undispersed photons. The results of such measurements for CO"+_2,COS"+,CS"+_2 and N_2O"+ in selected vibrational levels of their excited states are presented. Non-unity fluorescence quantum yields are found for some vibronic levels of CO"+_2(B), COS"+(A), N_2O"+(A) and a non-exponential decay is observed for CS"+_2(B). The data yield the following values for the radiative lifetimes: CO"+_2(A) 124 +- 6 ns,CO"+_2(B) 140 +- 7 ns, COS"+(A) 550 +- 50 ns and N_2O"+(A) 240 +- 12 ns. (orig.).

Environmental Research Database

ObjectivesThe specific objectives of the research are to: 1. Determine the concentrations of N2O, NO and NO2 in tropical coastal waters in relation to nutrients and salinities. 2. Determine, with excess nitrate present, the potential for nitrate reduction and denitrification in sediments along tropical estuaries, and whether NO, NO2, N2O, N2 or NH4+ are significant products. 3. Establish the balance between denitrification, nitrate ammonification and anammox in tropical estuarine sediments, relative to [continued...]DescriptionThe coastal zone is extremely important in the biogeochemical processes which control the natural cycle of elements of the Earth. In particular, the coastal zone contributes significantly to the nitrogen cycle, removing nitrogen washed in from the land by rivers and so reducing its fertilizing impact on the coastal seas. However, these ...

International Nuclear Information System (INIS)

Cross sections for (n,2n) (n,p) (n,#alpha#), and (n,d*)"1 reactions have been measured on ruthenium isotopes at the neutron energies of 13.5 to 14.8 MeV using the activation technique in combination with high-resolution gamma-ray spectroscopy. Data are reported for the following reactions: "1"0"4Ru(n,2n)"1"0"3Ru, "9"8Ru(n,2n)"9"7Ru, "9"6Ru(n,2n)"9"5Ru, "9"6Ru(n,p)"9"6Tc"g, "9"6Ru(n,p)"9"6Tc"m, "1"0"4Ru(n,p)"1"0"4Tc, "1"0"2Ru(n,p)"1"0"2Tc"m, "1"0"4Ru(n,#alpha#)"1"0"1Mo, "1"0"2Ru(n,#alpha#)"9"9Mo, "9"6Ru(n,#alpha#)"9"3Mo"m, and "9"6Ru(n,d*)"9"5Tc"m. Results were discussed and compared with the previous works.

International Nuclear Information System (INIS)

The sheath plasma characteristics changing with the negative bias applied to the substrate during electron cyclotron resonance plasma nitriding are studied. The sheath characteristics obtained by a Langmuir single probe and an ion energy analyzer show that when the negative bias applied to the substrate is increasing, the most probable energy of ions in the sheath and the full width of half maximum of ions energy distribution increase, the thickness of the sheath also increases, whereas the saturation current of ion decreases. It has been found from the optical emission spectrum that there are strong lines of N_2 and N_2"+. Based on the experiment results the mechanism of plasma nitriding is discussed

Energy Technology Data Exchange (ETDEWEB)

A new hydroxyiminoamide ligand, 1-(2-nitroimidazole-1-yl)-propanhydroxyiminoamide (N2IPA) was synthesized. The biodistribution of {sup 99m}Tc-N2IPA in mice bearing S180 tumor demonstrated that the complex showed a selective accumulation in tumor and slow clearance from it. The tumor-to-tissue uptake ratios increased with time. At 4 hours after injection, the uptake ratios of tumor to muscle, blood, liver, heart, and lung reached 8.4, 1.5, 0.6, 2.9, and 2.3, respectively. Moreover, the tumor-to-liver uptake ratio steadily increased to 0.9 at 8 hours and 2.3 at 24 hours. The complex showed little uptake and quick clearance in blood, lung and other organs. Compared with other proposed hypoxia-imaging agents, this novel agent has advantages of higher tumor-to-muscle and tumor-to-blood uptake ratios and easier synthesis.

International Nuclear Information System (INIS)

Using the activitation method (n,2n) excitation-functions were measured for "5"4Fe, "7"0Ge, "7"4Se, "8"5Rb, sup(86,88)Sr, "8"9Y, "9"2Mo, and "2"0"4Hg in the neutron-energy region 13-18 MeV. The results are checked for consistency by means of a systematic of (n,2n) cross-sections as a function of the nuclear neutron excess (N-Z)/A. Furthermore the data are compared with results from the statistical nuclear reactions theory which were calculated using optical model absorption cross-sections and the Fermi-gas-model formula for the nuclear level density. In the case of "2"0"4Hg the influence of preequilibrium nucleon emission was taken into account. (orig.).

International Nuclear Information System (INIS)

Quantitative structure activity relationship (QSAR) analysis of the correlations between initial brain uptake and structure parameters, for example lipophilicity F_r, molar refractivity MR and electronic parameters #sigma#_1 of the "9"9Tc"m-N_2S_2 complexes have been studied with multiple regression analysis method. The main structural factors which affect the initial brain uptake of this kind of brain imaging agents have been discussed. The results may give some theoretical information for designing new brain imaging agents

International Nuclear Information System (INIS)

We describe the analysis of forward mutations induced in the tetracycline resistance gene of the plasmid pBR322 by directing the reaction of the carcinogen N-acetoxy-N-2-acetylaminofluorene (N-AcO-AAF) to a small restriction fragment (BamHI, SalI) that is located in the proximal part of the antibiotic-resistance gene. Mutant plasmids obtained both in wild type and excision repair deficient (uvrA) bacterial cells are compared. Preliminary data showing the distribution of the -AAF adducts along this restriction fragments are discussed in relation to the observed spectrum of mutations. 20 references, 4 figures.

British Library Electronic Table of Contents (United Kingdom)

The effect of a series of complexing and reducing agents on the extraction-chemical behavior of technetium as applied to extraction splitting of uranium and plutonium in the Purex process was examined. Kinetic parameters of the catalytic decomposition of N2H5NO3 under the action of Tc in the presence of these agents were evaluated. Variation of the ratio of the oxidized and reduced Tc species in the course of the process and in the hydrazine-free systems was determined. Reagents preventing oxidation of the reduced technetium and decomposition of N2H5NO3 in nitric acid solutions (acetohydroxamic acid, hydroxylamine, ascorbic acid, etc.), inhibiting the reduction of Tc with hydrazine nitrate (H2O2, HN3, etc.), and known as complexing agents toward quadrivalent actinides but indifferent to Tc...

British Library Electronic Table of Contents (United Kingdom)

Amino-rich polymeric coatings are widely used in biomedical applications, since they promote adsorption of diverse biomolecules or facilitate cell growth. As a consequence, there is a growing interest in fabrication of such coatings that is focused predominantly on the optimization of the deposition process in terms of high density of primary amino groups. In addition, the nature of biomedical applications requires also sufficient stability of the films in aqueous environments. This aspect is investigated in this contribution. In particular, the effect of water and phosphate buffer saline on the coatings prepared by RF magnetron sputtering of Nylon 6,6 in Ar/N2 and N2/H2 gas mixtures is evaluated. The samples exposed to liquids are characterized by various diagnostic methods and their prop...

British Library Electronic Table of Contents (United Kingdom)

In this context, the bulk ratio of CH4/N2 is examined as a potential alternative geochemical parameter for the assessment of thermal maturity of natural gas and compared to other previously published data. Open-system non-isothermal pyrolysis of low-mature coal from the Manjiaer sag, Tarim basin, yielded generation curves for methane and nitrogen. Analysis of the change of vitrinite reflectance indicates a two-stage process of thermal maturation with increasing temperatures. The relationship between Ro and pyrolysis temperature could be expressed by the following equations: Stage I: Ro = 0.0014T + 0.109, r = 0.9931(Ro Ro = 0.0067T -1.5855, r = 0.9996 (Ro > 0.6%). A kinetic interpretation of the characteristics of nitrogen and methane generation in humic coal during laboratory pyrolysis ind...

CERN Document Server

In this paper we establish a fundamental structural result for formal series encoding the total non-archimedean masses of quadratic lattices of varying determinant squareclasses, but with fixed rank $n$ and signature over any fixed number field. We conclude with some local computations for $n=2$, and use these to derive an analytic class number formula for CM extensions.

International Nuclear Information System (INIS)

The nanocrystallization process of amorphous Fe_7_3_._5Si_1_3_._5B_9Nb_3Cu_1 was investigated by active screen plasma nitriding (ASPN) treatment at temperatures ranging from 410 "oC to 560 "oC for 3 h in two gas mixtures of 75% N_2-25% H_2 and 25% N_2-75% H_2 at 5 mbar atmosphere. The amorphous ribbons were then annealed under vacuum at the same time and temperatures mentioned above. The structure of the samples was analyzed using various techniques such as X-ray diffraction (XRD), atomic force microscopy (AFM) and differential scanning calorimetry (DSC). Microhardness measurements, electrical resistivity and Vibrating Sample Magnetometer (VSM) were used to study mechanical, electrical and magnetic properties of the samples, respectively. It was observed that the ASPN treatment leads to finer grain size and higher crystalline volume fraction and modifies the structural features of Fe(Si) phase. The ...

British Library Electronic Table of Contents (United Kingdom)

Biased above threshold (VT), pulsed photocurrent (u) measurements on windowed silicon Pd gate MOS capacitors are shifted (DV) negatively by H2/N2, whereas Au gates shift positively under NO2/air. Below VT, the shifts are reversed by adjustments of interface state population. Minor temperature increases may coax the device from inversion to depletion, inducing sign reversal of the chemical response.

International Nuclear Information System (INIS)

The use of environmental monitoring as a technique to identify activities related to the nuclear fuel cycle has been proposed by international safeguards organizations. The elements specific for each kind of nuclear activity, or 'nuclear signatures', inserted in the ecosystem can be intercepted by different live organisms. This work demonstrates the technical viability of using pine needles as bioindicators of nuclear signatures associated with uranium enrichment activities. Additionally, it proposes the use of HR-ICP-MS to identify the signature corresponding to that kind of activities in the ecosystem. Nitric acid solutions, used to wash pine needles sampled near nuclear facilities and containing only 0.1 #mu#g x kg"-"1 of uranium, exhibit a n("2"3"5U)/n("2"3"8U) isotopic abundance ratio of 0.0092#+-#0.0002, while solutions originated from samples collected at places located more than 200 km far from ...

International Nuclear Information System (INIS)

Thermo-reactive diffusion chromizing followed by pulsed plasma nitriding were carried out on AISI 52100 and 8620 bearing steels. The chromized samples were pulse-plasma nitrided for 5 h at 500 deg. C in various N_2-H_2 gas mixtures. The coated steels were characterized using scanning electron microscopy, X-ray diffraction and microhardness testing. The unlubricated wear behaviors of only chromized and duplex treated steels were investigated in ball-on-disc system tests at room temperature. X-ray diffraction patterns of the duplex treated samples containing H_2 indicated the formation of dominant CrN and Cr_2N nitrides as well as the formation of Cr_3C_2 and Cr_7C_3 carbides. Gas mixtures in the plasma nitriding, which was performed after chromizing, have a significant influence on the wear rate of the duplex treated steels. The wear and friction tests showed that the lowest friction coefficient and wear rates were observed for the samples ...

International Nuclear Information System (INIS)

The main purpose of this work is to evaluate the role of CT in identifying other morphological signs of met static lymph node involvement from non small cell bronchogenic carcinoma. This is done to improve N staging, a critical step in this disease. In fact, since diameter is the only criterion used to distinguish normal form abnormal lymph nodes, mediastinal CT only has 80% diagnostic accuracy. 137 patients with known or suspected lung cancer were examined with Helical CT during early and late arterial phases (2 min. delay, 3 mm thickness, 5 mm inter slice gap) to depict node characteristics. Mediastinal lymph nodes, located according to the American Thoracic Society mapping, were considered normal when they were not visible or, if visible, less than 1 cm in diameter and of homogeneous density; lymph nodes over 1 cm in diameter and homogenous density were considered reactive. A lymph node was considered metastatic when, independent of size, the following signs were found: central hypo ...

CERN Document Server

Site measurements were collected at Mount John University Observatory in 2005 and 2007 using a purpose-built scintillation detection and ranging system. $C_n^2(h)$ profiling indicates a weak layer located at 12 - 14 km above sea level and strong low altitude turbulence extending up to 5 km. During calm weather conditions, an additional layer was detected at 6 - 8 km above sea level. $V(h)$ profiling suggests that tropopause layer velocities are nominally 12 - 30 m/s, and near-ground velocities range between 2 -- 20 m/s, dependent on weather. Little seasonal variation was detected in either $C_n^2(h)$ and $V(h)$ profiles. The average coherence length, $r_0$, was found to be $7 \\pm 1$ cm for the full profile at a wavelength of 589 nm. The average isoplanatic angle, $\\theta_0$, was $1.0 \\pm 0.1$ arcsec. The mean turbulence altitude, $\\bar{h_0}$, was found to be $2.0\\pm0.7$ km above sea level. No ...

Energy Technology Data Exchange (ETDEWEB)

The metal dependence of mesoporous activated carbons with various metal acetylacetonate (acac) particles prepared from Morwell coal was studied. In experiment, the mixture of Morwell coal and acac metal complexes were dissipated into tetrahydrofuran, and after agitation in Ar atmosphere, the solvent was removed by vacuum distillation. Coal specimens with Fe(acac)3, Ni(acac)2 and Co(acac)2 as acac complexes were activated by exchanging flow gas with water vapor after heat treatment in N2 gas flow at 900{degree}C. The pore sizes of the specimens were obtained from N2 adsorption isotherms by BET method and BJH method. Conditions of pores and metals in the specimens were examined by XRD measurement and TEM observation. The relation between the above conditions and pore characteristics obtained from adsorption experiment was also examined. As a result, the difference in mesopore ratio between the specimens ...

International Nuclear Information System (INIS)

The usually low wear resistance of titanium materials can be increased by the thermochemical surface treatment nitriding. In result of comparative investigations of gas and plasma nitriding it will be shown that it is possible to obtain a specific variation of the properties in the highly stressed case by means of these both technologies on example of the (#alpha#+#beta#) alloy Ti-6Al-4V. Gas and plasma nitriding was carried out in the temperature range from 650 to 800 C over 4 to 48 h in different gas atmospheres, i.e. 100% NH_3 (gas), 100% N_2 (gas and plasma), 20% H_2 + 80% N_2 and 20% Ar + 20% H_2 (plasma). The temperature range was fixed in the middle of (#alpha#+#beta#) region, because the core properties are influenced negative in the field of #beta#-transustemperature. The relations between the applied nitriding technologies, the layer structure (chemical, phases, geometrical) and selected layer ...

International Nuclear Information System (INIS)

This paper reports measurements of absolute differential cross sections for the direct scattering of oxygen atoms by He, Ne, Ar, Kr, Xe, H_2, N_2, O_2, CO, CO_2, H_2O, SO_2, NH_3, CH_4, CF_4, and SF_6 targets. The measured cross sections include contributions from all elastic and inelastic processes that result in a fast neutral oxygen atom product. Cross sections are presented for 0.5- and 1.5-keV projectile energies over the laboratory angular range 0.2 degree endash 5 degree. When compared in the center-of-mass reference frame, these cross sections exhibit a high degree of similarity in both amplitude and angular dependence. The cross sections for N_2, CO, CO_2, and H_2O are inverted using a partial-wave analysis to yield empirical interaction potentials, which can then be used to extrapolate the measurements down to lower energies. Using these potentials, cross sections are evaluated at 0.1 keV. ...

Energy Technology Data Exchange (ETDEWEB)

Electrochemical corrosion rate probes were constructed and tested along with mass loss coupons in a N2/O2/CO2 plus water vapor environment. Temperatures ranged from 450 to 600 C. Corrosion rates for ash-covered mild steel, 304L SS, and 316L SS probes using electrochemical techniques were a function of time, temperature, and process environment. Correlation between electrochemical and mass loss corrosion rates was good.

Energy Technology Data Exchange (ETDEWEB)

Recent work on [ital N]=2 supersymmetric Bianchi type IX cosmologies coupled to a scalar field is extended to a general treatment of homogeneous quantum cosmologies with explicitly solvable momentum constraints, i.e., Bianchi types I, II, VII, VIII in addition to the Bianchi type IX, and special cases, namely, the Freidmann universes, the Kantowski-Sachs space, and Taub-NUT space. In addition to the earlier explicit solution of the Wheeler-DeWitt equation for Bianchi type IX, describing a virtual wormhole fluctuation, an additional explicit solution is given and identified with the no-boundary state.''

International Nuclear Information System (INIS)

The "2H(#alpha#,p#alpha#)n reaction was investigated in a kinematically complete experiment with a #alpha#-beam at energy 27.2 MeV.The "5He excited state was observed and its parameters were determinate.Coincidence spectra were fitted by contribution of sequential decay through the "5He ground and excited states.The best agreement with the data was obtained assuming the following "5He excited state parameters: E_a_n=2.8 MeV #GAMMA#=2.5 MeV.

Energy Technology Data Exchange (ETDEWEB)

The present invention provides a compound of the formula (Cat).sup.+.sub.z[M.sup.++(5-nitro-1H-tetrazolato-N2).sup.-.sub.x(H.sub.2- O).sub.y] where x is 3 or 4, y is 2 or 3, x+y is 6, z is 1 or 2, and M.sup.++ is selected from the group consisting of iron, cobalt, nickel, copper, zinc, chromium, and manganese, and (Cat).sup.+ is selected from the group consisting of ammonium, sodium, potassium, rubidium and cesium. A method of preparing the compound of that formula is also disclosed.

International Nuclear Information System (INIS)

With the aim of optimizing the nitriding process parameters (temperature and gas mixture ) experimental studies of the plasma nitriding of Ck 15 steel were carried out, using a D. C. glow discharge. Nitriding treatments were performed at 450, 500 and 550 and N_2/H_2 volume ratio of 3/1, 1/1 and 1/3 for 5 hours. Nitriding treatment produces modified surface layer consisting of an outer compound layer and an inner diffusion layer.The plasma nitriding of Ck 15 produce single white layer consisting of #gamma#-(Fe_4N).

International Nuclear Information System (INIS)

A mixture of powders of silica and aluminum nitride is subjected to high-energy ball milling for different milling times. This material is subsequently compacted by uniaxial pressing and sintered at 1450 deg. C. The resulting pellets are crushed and analysed by X-ray diffraction. For short milling times, the amount of phase transformation is minimal and the resulting material mostly consists of cristobalite and aluminum nitride. For long milling times, nanocrystalline #beta#-SiAl_2O_2N_2 is mainly produced.

International Nuclear Information System (INIS)

In this study, Multi-Walled Carbon Nanotubes (MWCNTs) / Hydroxylapatite (HAp) composites were made to improve mechanical properties by using Spark Plasma Sintering (SPS) method. Slurry 6 mol of CaHPO4#centre dot#2H2O (DCPD), 4 mol calcium hydroxide and MWCNTs were mixed and sintered by using SPS at 5-120 MPa pressure, 1200-1250 deg. C and in vacuum or N2 atmosphere. The fracture toughness of sintered MWCNTs/HAp composites was increased.

International Nuclear Information System (INIS)

This report describes recent extensions to the energy-systems GMM (Global Multiregional MARKAL) model undertaken by the Energy Economics Group (EEG) of the Paul Scherrer Institute (PSI) in Switzerland (hereon referred to as PSI-EEG) in the context of the SAPIENTIA project sponsored by the European Commission (DG Research) and the Swiss National Centre for Competence in Research on Climate (NCCR-Climate). GMM is a multi-regional 'bottom-up' energy-systems optimization model that endogenizes technology learning. The model has been developed and is used at PSI-EEG. The main extensions undertaken here concern the incorporation of a clusters approach to technology learning, the introduction of an improved representation of the transportation sector with emphasis on the passenger sub-sector and the implementation of marginal abatement curves for CH4 and N2O, two main non-CO2 greenhouse gases. Also, a linear representation of the atmospheric ...

Science.gov (United States)

One-electron reduction of the square-planar nickel precursor (PNP)NiCl ( 1) (PNP (-) = N[2-P(CHMe 2) 2-4-methylphenyl] 2) with KC 8 effects ligand reorganization of the pincer ligand to assemble a Ni(I) dimer, [Ni(mu 2-PNP)] 2 ( 2), containing a Ni 2N 2 core structure, as inferred by its solid-state X-ray structure. Solution magnetization measurements are consistent with a paramagnetic Ni(I) system likely undergoing a monomer dimer equilibrium. The room-temperature and 4 K solid-state X-band electron paramagnetic resonance (EPR) spectra display anisotropic signals. Low-temperature solid-state X-band EPR data at 4 K reveal rhombic values g z = 1.980(4), g x = 2. 380(4), and g y = 2.225(4), as well as a forbidden signal at g = 4.24 for the Delta M S = 2 half field transition, in accord with 2 having two weakly interacting metal centers. Utilizing an S = 1 model, full spin Hamiltonian simulation of the ...

International Nuclear Information System (INIS)

Aqueous deoxyhemoglobin solutions (2 mg/ml) were gamma-irradiated by a "6"0Co source in the presence of methanol, ethanol, 1-butanol and t-butanol under N_2O or argon. The effects of the interaction of the particular alcohol radical species with hemoglobin were determined according to the detected spectral alterations in the visible range. The amounts of stable final products in the form of methemoglobin (MetHb) and the sum of hemichromes and cholehemichromes (Hemichr) were estimated in irradiated preparations. For preparations irradiated under N_2O, the radiation yield for MetHb formation was three-fold lower in the presence of ethanol and 1-butanol [G(MetHb) = 0.33[ compared with preparations irradiated in the presence of t-butanol or without alcohol [G(MetHb) = 1.00[. The yield of hemichromes and cholehemichromes in preparations irradiated under N_2O ...

International Nuclear Information System (INIS)

Full text: In the upper layers of the Earth's atmosphere, molecular nitrogen absorbs the extreme ultraviolet (XUV) solar radiation. The absorption is associated with dipole-allowed excitation of states of singlet ungerade symmetry ("1#SIGMA#"+_u and "1#PI#_u), which are known to undergo predissociation due to coupling with a mainfold of "1#PI#_u states. We determined new N_2 isotopic lifetimes of many "1#SIGMA#"+_u and "1#PI#_u states via line broadening measurements in the frequency domain. Ultrahigh resolution XUV + UV ionization spectra were recorded (bandwidth #approx# 250 MHz, resolving power 10"7), from which the natural linewidth, i.e. lifetime, was determined. These lifetimes provide new information about the predissociation of the singlet ungerade states in N_2. Tunable narrowband XUV radiation was produced by successively pulsed amplification of cw dye laser radiation, frequency doubling the ...

International Nuclear Information System (INIS)

1 - Description of program or function: The COOLOD-N2 code provides a capability for the analyses of the steady-state thermal-hydraulics of research reactors. This code is a revised version of the COOLOD-N code, and is applicable not only for research reactors in which plate-type fuel is adopted, but also for research reactors in which rod-type fuel is adopted. In the code, subroutines to calculate temperature distribution in rod-type fuel have been newly added to the COOLOD-N code. The COOLOD-N2 code can calculate fuel temperatures under both forced convection cooling mode and natural convection cooling mode. A 'Heat Transfer package' is used for calculating heat transfer coefficient, DNB heat flux etc. The 'Heat Transfer package' is a subroutine program and is especially developed for research reactors in which plate-type fuel is adopted. In case of rod-type fuel, DNB heat flux is calculated by both ...

British Library Electronic Table of Contents (United Kingdom)

Fe-doped TiO2 hollow spheres (Fe-THs) were synthesized by sol?gel process using carbon spheres as templates. The prepared samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), UV?vis diffuse reflectance spectrum (DRS), N2 adsorption?desorption isotherms, Electron paramagnetic resonance (EPR) spectroscopy and Photoluminescence emission spectroscopy (PL). UV?vis spectra showed that Fe3+ doping could extend the absorption edge to the visible region. EPR spectra showed that Fe3+ was incorporated into the crystal lattice of TiO2, which could inhibit the recombination of photo-induced electron?hole pairs and improve the photocatalytic activity. The photocatalytic activities of the prepared samples were evaluated for the degradation of dye Reactive Brillia...

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The 6n-dimensional phase space of the planetary (1+n)-body problem (after the classical reduction of the total linear momentum) is shown to be foliated by symplectic leaves of dimension (6n?2) invariant for the planetary Hamiltonian Formula Not Shown . Such foliation is described by means of a new global set of Darboux coordinates related to a symplectic (partial) reduction of rotations. On each symplectic leaf Formula Not Shown has the same form and it is shown to preserve classical symmetries. Further sets of Darboux coordinates may be introduced on the symplectic leaves so as to achieve a complete (total) reduction of rotations. Next, by explicit computations, it is shown that, in the reduced settings, certain degeneracies are removed. In particular, full torsion is checked both in the ...

International Nuclear Information System (INIS)

Three new phases with compositions, LaSr_2FeTiO_7, NdSr_2FeTiO_7 and GdSr_2FeTiO_7, were prepared by the traditional ceramic method. Lazy-Pulverix analysis of the X-ray diffraction data suggests that the phases crystallize in the RP-type (n = 2) structure in the space group, I4/mmm. The cell dimensions along the c-axis decrease with decrease in size of the rare earth ions. Electrical resistivity, as a function of temperature, shows that the materials are insulators and the resistivity decreases with decrease in the size of the rare earth ion, which is attributed to increase in the three-dimensional character. (author)

International Nuclear Information System (INIS)

Ion desorption from a condensed gas solid Ne impacted by singly- and multiply-charged Ar"q"+ ions (q = 1-7) has been investigated. Various secondary ions such as cluster ions, Ne"+_n (n = 2-20) as well as atomic ions are observed. Mass spectral patterns, thickness dependence of the yields, and kinetic energy distributions of the desorbed Ne"+_n (n = 1,2) depend strongly on the projectile charge state. These results indicate that the dissipation of the projectile potential energy on the surface leads to the desorption of the monomer and small cluster ions by a Coulomb repulsion between adjacent target ions.

International Nuclear Information System (INIS)

A simple and rapid procedure was developed for the purification of cyclotron-produced "2"0"3Pb via the "2"0"3Tl(d,2n) "2"0"3Pb reaction. A Pb(II) selective ion-exchange resin, with commercial name Pb Resin from Eichrom Technologies, Inc., was used to purify "2"0"3Pb from the cyclotron-irradiated Tl target with excellent recovery of the enriched Tl target material. The purified "2"0"3Pb was used to radiolabel the monoclonal antibody Herceptin. The in vitro and in vivo properties of the "2"0"3Pb radioimmunoconjugate were evaluated.

International Nuclear Information System (INIS)

The recent acceleration of effort to elucidate and explore the coordination chemistry of technetium has been prompted mainly by the need for a new generation of radiotracers in nuclear medicine, preferentially for tomograhic studies. Current approaches and their limitations in designing "9"9"mTc complexes capable of penetrating cell membranes of the target organs, and remaining there sufficiently long, are reviewed. With the predominance of Tc(V) oxo compounds, especially for brain imaging agents, new N4 and N2S2 coordinate complexes have been developed by shifting from bidentate to tetradentate ligands with a variable side chain or other adjustable reactivity. The search for myocardial imaging agents has focused on a variety of mixed ligand complexes of Tc(III) and most promising [Tc(CNR)_6]"+ complexes of Tc(I). 64 refs. (author).

British Library Electronic Table of Contents (United Kingdom)

We demonstrate a novel cross-sectional deformation, called the radial corrugation, of multi-walled carbon nanotubes (MWNTs) under hydrostatic pressure. Theoretical analyses based on the continuum elastic approximation have revealed that MWNTs consisting of more than ten concentric walls undergo elastic deformations at critical pressure Formula Not Shown , above which the circular shape of the cross-section becomes radially corrugated. Various corrugation modes have been observed by tuning the innermost tube diameter and the number of constituent walls, which is a direct consequence of the core-shell structure of MWNTs. Cross-sectional views of MWNT under high hydrostatic pressure: elliptic deformation with the mode index n = 2 (left), and radial corrugations with n = 5 (center), and n = 6 ...

International Nuclear Information System (INIS)

The positive-energy unitary irreducible representations of the q-deformed conformal algebra #delta#C_q = U_q(su(2,2)) are obtained by appropriate deformation of the classical ones. When the deformation parameter q is N -th root of unity, all these unitary representations become finite-dimensional. For his case we discuss in some detail the massless representations, which are also irreducible representations of the q-deformed Poincare subalgebra of #delta#C_q. Generically, their dimensions are smaller than the corresponding finite-dimensional non-unitary representation of su(2,2), except when N = 2 modul h + 1, where h is the helicity of the representations. The latter cases include the fundamental representations with h = #+-#1/2. (author). 10 refs.

Energy Technology Data Exchange (ETDEWEB)

To evaluate the effectiveness of percutaneous mechanical declotting. Using a 7-F Desilets-Hoffman sheath and the crossed-catheter technique, we aspirated the intragraft clot and pushed the residual clot into the central circulation with balloon catheters. The success rate, procedure time, complications and patency rates were evaluated. Technical success was achieved in 24 of 32 cases, with a procedure time of 30-240 (average, 111) minutes. In five of eight cases in which technical failure occurred, the guide wire failed to reach the stenotic site and in the other three, there was insufficient luminal dilatation. Complications included vein ruptures (n=2), arterial emboli (n=1) and arterial dissection (1), but there was no evidence of clinical symptoms of pulmonary embolism. The six-month patency rate was 67.8%. Mechanical declotting of thrombosed dialysis graft using a balloon catheter is relatively inexpensive, safe and fast, and is well ...

International Nuclear Information System (INIS)

An accurate neutronics calculation of a local thermal environment within a fast reactor presents a major challenge. A method was previously described that used Monte Carlo techniques within a macrocell to make accurate and reasonably efficient design calculations for such an environment. This method is now being further optimized for the calculation of "2"3"8Pu production in the Fast Flux Test Facility (FFTF). Here, it is not only important to determine the "2"3"8Pu production from neutron capture in "2"3"7Np, but also to calculate the production of the contamination isotope "2"3"6Pu from high-energy (n,2n) and (#gamma#,n) reactions. The power of the Monte Carlo method to automatically include geometry and energy self-shielding is retained by optimization using fission neutron source biasing in both space and energy.

International Nuclear Information System (INIS)

We describe in detail the space of the two Kaehler parameters of the Calabi-Yau manifold P_4"("1","1","1","6","9")[D. R. Morrison, 1993] by exploiting mirror symmetry. The large complex structure limit of the mirror, which corresponds to the classical large radius limit, is found by studying the monodromy of the periods about the discriminant locus, the boundary of the moduli space corresponding to singular Calabi-Yau manifolds. A symplectic basis of periods is found and the action of the Sp(6, Z) generators of the modular group is determined. From the mirror map we compute the instanton expansion of the Yukawa couplings and the generalized N=2 index, arriving at the numbers of instantons of genus zero and genus one of each bidegree. We find that these numbers can be negative, even in genus zero. We also investigate an SL(2, Z) symmetry that acts on a boundary of the moduli space. ((orig.)).

International Nuclear Information System (INIS)

With the assistance of mechanical activation, yttrium-stabilized #alpha#-SiAlON was prepared by combustion synthesis in air, instead of high-pressure N_2 atmosphere for the first time. The reaction activity of metallic particles was remarkably enhanced by mechanical activation, which conduced the reduction of grain size, increased the total surface area and formation of fresh surface. The formation of #alpha#-SiAlON by combustion synthesis in air was explained by a kinetically induced reaction mechanism, in which both initial formation of #alpha#-SiAlON and following avoidance of oxidation were fulfilled by the retardation of O_2 infiltration owing to the short reaction period and fast cooling rate.

British Library Electronic Table of Contents (United Kingdom)

In this study structural and magnetic character of the expanded austenite phase (gN) layer formed on a medical grade CoCrMo alloy by a low-pressure Radio-Frequency plasma nitriding process was investigated. The formation of the expanded austenite phase is facilitated at a substrate temperature near 400^oC for 1, 2, 4, 6 and 20h under a gas mixture of 60% N2-40% H2. The magnetic state of the gN layers was determined by a surface sensitive technique, magneto-optic Kerr effect (MOKE), and with a scanning probe microscope in magnetic force mode (MFM). Strong evidence for the ferromagnetic nature of the gN-(Co,Cr,Mo) phase is provided by the observation of stripe domain structures and the hysteresis loops. The ferromagnetic state for the gN phase observed here is mainly linked to large lattice ...

International Nuclear Information System (INIS)

Nano structured carbon nitride thin films were deposited at different RF powers in the range of 50 W to 225 W and constant gas ratio of (argon: nitrogen) Ar:N_2 by RF magnetron sputtering. The atomic percentage of Nitrogen: Carbon (N/C) content and impedance of the films increased from 14.36% to 22.31% and 9 x 10"-"1 #OMEGA# to 7 x 10"5 #OMEGA# respectively with increase in RF power. The hardness of the deposited films increased from 3.12 GPa to 13.12 GPa. The increase in sp"3 hybridized C-N sites and decrease of grain size with increase in RF power is responsible for such variation of observed mechanical and electrical properties.

International Nuclear Information System (INIS)

Neutron cross sections for Pu-239 and Am-241, -242m, -243 have been analyzed with the aid of theoretical models. A deformed optical potential that fits total, elastic and inelastic differential cross section data and neutron strength functions for Pu-239 and Am-241 have been used. In case of Pu-239 the consistency of absolute fission data and (n, 2n) cross section is investigated. Because of the strong discrepancies in Am fission cross section data a consistent set of calculated cross section values for the chain of Am nuclei is proposed. The present state of knowledge concerning first chance fission cross section allows to analyze fission cross section data of Am-241, -242m, -243, up to 20 MeV. The results thus obtained are compared with ENDF/B-V and JENDL-3 libraries. (orig.).

International Nuclear Information System (INIS)

The radioactive isotopes of lead are reviewed with respect to their choice for in vitro tracer studies. The #gamma#-photon energy and absence of particle emission in the decay of "2"0"3Pb makes it particularly suitable for these applications. Reaction yields of "2"0"3Pb using "2"0"3Tl targets and proton, deuteron, "3He and "4He beams are listed. Using the preferred reaction "2"0"3Tl (d, 2n)"2"0"3Pb with a 15 MeV deuteron beam, yields of about 75 #mu#Ci #mu#Ahr"-"1, after chemical separation, are reported. Details of target design and chemical separation are given. (U.K.).

British Library Electronic Table of Contents (United Kingdom)

In this article a methodology is presented for studying the influence of the biomass moisture content and the biomass/air ratio on the producer gas composition and on the chemiluminescent emissions during the combustion process. Firstly, a mathematical model based on the thermo-chemical processes inside the gasifier is used to predict the composition of the producer gas as a mixture of CO, CO2, H2, N2, CH4 and H2O gases. Secondly, the predicted composition is introduced into a constant volume combustion bomb (CVCB), which simulates the typical conditions inside the combustion chamber of an internal combustion engine, in order to characterize its combustion under gasoline-type conditions through the instantaneous pressure and the detection of the spontaneous luminous radiation (chemilumines...

British Library Electronic Table of Contents (United Kingdom)

Abstract: We have performed petrographic and spectroscopic studies of brown diamonds from an eclogite xenolith from the Udachnaya pipe (Yakutia, Russia). Brown diamonds are randomly intermixed with colorless ones in the rock and often located at the grain boundaries of clinopyroxene and garnet. Brown diamonds can be characterized by a set of defects (H4, N2D and a line at 490.7nm) which are absent in colorless diamonds. This set of defects is typical for plastically deformed diamonds and indicates that diamonds were likely annealed for a relatively short period after deformation had occurred. Excitation of brown colored zones with a 632.8nm He-Ne laser produced the typical diamond band plus two additional bands at 1730cm^-^1 and 3350cm^-^1. These spectral features are not genuine Raman ban...

Energy Technology Data Exchange (ETDEWEB)

The excitation function of ({alpha},{ital xn}) reactions on {sup 191}Ir (abundance 37.3%) and on {sup 193}Ir (abundance 62.7%) has been measured for the 17--55 MeV alpha-particle bombarding energy range. The stacked foil activation technique and {gamma}-ray spectroscopy were used to determine the cross sections. The experimental data were compared with calculated values obtained by means of a geometry-dependent hybrid model. The initial exciton number {ital n}{sub 0}=4 with {ital n}=2, {ital p}=2, and {ital h}=0 gives the best agreements with the presently measured results. To calculate the excitation function theoretically a computer code was used. This set of excitation functions provides a data basis for probing the validity of combined equilibrium and preequilibrium reaction models in a considerable energy range.

International Nuclear Information System (INIS)

Anion-exchange chromatography of element 105, dubnium (Db), produced in the "2"4"8Cm("1"9F, 5n)"2"6"2Db reaction is investigated together with the homologues Nb and Ta, and the pseudo-homologue Pa in 13.9 M hydrofluoric acid (HF) solution. The distribution coefficient (K_d) of Db on an anion-exchange resin is successfully determined by running cycles of 1702 chromatographic column separations. The result clearly indicates that the adsorption of Db on the resin is significantly different from that of the homologues and that the adsorption of anionic fluoro complexes of these elements decreases in the sequence of Ta#approx#Nb>Db#>=#Pa. (orig.)

International Nuclear Information System (INIS)

The effects of O and C ion implantation with different implantation doses on the yellow luminescence (YL) from unintentional doped n-type GaN have been studied by the photoluminescence (PL) spectra. O and C ions were implanted in the GaN samples with different doses from 1.0 x l013 to 1.0 x l017cm-2. Post-annealing was done in a quartz open-tube furnace under flowing N2 gas for 30 min at 950 degree C. By comparing with N ion implanted samples, it is assumed that different deep-level centers involving in the YL were produced in GaN after O and C ion implantation. In addition, with a dose of 1017 cm-2, the concentration of deep C centers involving in the YL was enhanced markedly. (authors)

CERN Document Server

Computing the topology of an algebraic plane curve $\\mathcal{C}$ means to compute a combinatorial graph that is isotopic to $\\mathcal{C}$ and thus represents its topology in $\\mathbb{R}^2$. We prove that, for a polynomial of degree $n$ with coefficients bounded by $2^\\rho$, the topology of the induced curve can be computed with $\\tilde{O}(n^8(n+\\rho^2))$ bit operations deterministically, and with $\\tilde{O}(n^8\\rho^2)$ bit operations with a randomized algorithm in expectation. Our analysis improves previous best known complexity bounds by a factor of $n^2$. The improvement is based on new techniques to compute and refine isolating intervals for the real roots of polynomials, and by the consequent amortized analysis of the critical fibers of the algebraic curve.

Energy Technology Data Exchange (ETDEWEB)

To investigate the problems of the Hanaro stent (Solco Intermed, Seoul, Korea) when used in the palliative treatment of patients with inoperable malignant biliary obstruction. Between January 2000 and May 2001, the treatment of 46 patients with malignant biliary obstruction involved percutaneous placement of the Hanaro stent. Five patients encountered problems during removal of the stent's introduction system. The causes of obstruction were pancreatic carcinoma (n=2), cholangiocarcinoma (n=2), and gastric carcinoma with biliary invasion (n=1). In one patient, percutaneous transhepatic cholangiography and stent insertion were performed as a one-step procedure, while the others underwent conventional percutaneous transhepatic biliary drainage for at least two days prior to stent insertion. A self-expandable Hanaro stent, 8-10 mm in deameter and 50-100 mm in lengh, and made from a strand of ...

International Nuclear Information System (INIS)

Carbothermal reduction-nitridation (CRN) of talc (Mg_3(Si_2O_5)_2(OH)_2) and halloysite (Al_2Si_2O_5(OH)_4) clay provides a useful route for preparing low-cost Mg-#alpha# sialon powder. In this study, the chosen molecular ratios of talc to halloysite were 0.1:1, 0.2:1, 1.5:1.0 and 2.0:1. The CRN reaction was conducted at 1450 to 1520 deg C and 2 to 6h holding time using carbon black as a reducing agent in flowing N_2 (gas). The results showed the synthesized powder was composed of #alpha#-sialon, #beta#-sialon and small amounts of SiC, 15R and AlN phases that greatly depended on the ratio of talc to halloysite, the reaction temperature and holding time. The highest content of Mg-#alpha# sialon, as much as 90wt%, was achieved at 1480 deg C for a holding time of 4h at a talc to halloysite ratio of 1.5:1.0. SiC was considered as an intermediate compound. We also discuss the evaporation loss of Mg caused by talc decomposing into ...

International Nuclear Information System (INIS)

On the basis of soil losses records during 10 years, three levels of water erosion were established for two soil (Typical Hapludox and Oxic Dystropept) located on high and medium terraces of alluvial flat plain of piedmont in the Eastern Plains in La Libertad Research Center of CORPOICA. Eighteen 3 x 10 m"2 run-off plots were fitted out on a nonrandom arrangement of nine plots by landscape and three soil use and management treatments: zero grazing Brachiaria decumbens pasture for six years, up land rice, soybean and maize rotations for six years and bare soil for 10 years. Soil losses under these treatments allowed to define three degrees of erosion: slight (N_3 moderate (N_2) and severe (N_3) respectively. From each plot soil samples were taken at two depths for physical analyses. infiltration and resistance to cone penetration were measured in the field. Without exception water erosion produced a detrimental effect on soil physical properties ...

DEFF Research Database (Denmark)

Purpose To investigate the sensitivity and accuracy of endobronchial ultrasound-guided transbronchial needle aspiration (EBUS-TBNA) for restaging the mediastinum after induction chemotherapy in patients with non-small-cell lung cancer (NSCLC). Patients and Methods One hundred twenty-four consecutive patients with tissue-proven stage IIIA-N2 disease who were treated with induction chemotherapy and who had undergone mediastinal restaging by EBUS-TBNA were reviewed. On the basis of computed tomography, 58 patients were classified as having stable disease and 66 were judged to have had a partial response. All patients subsequently underwent thoracotomy with attempted curative resection and a lymph node dissection regardless of EBUS-TBNA findings. Results Persistent nodal metastases were detected by using EBUS-TBNA in 89 patients (72%). Of the 35 patients in whom no metastases were assessed by EBUS-TBNA, 28 were found to have residual stage ...

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In relation to coal gasification and combustion under high pressure as highly efficient coal utilization, the effect of total pressure and sintering on the SO2 capture ability of Ca-ion exchanged coal and other desulfurizing agents were studied. In experiment, specimens were filled into a small pressurized reactor to heat them under high-pressure N2 atmosphere. After the completion of combustion reaction of char at 850{degree}C, SO2, CO2 and CO gases were measured at an outlet while flowing SO2/N2. As the experimental result, all of the S content in Ca-ion exchanged coal was not absorbed by Ca content in coal during pyrolysis and combustion, resulting in discharge of 36% of the S content. Since Ca-ion exchanged coal is fast in combustion reaction, most of the S content was desulfurized by coal ash. The ash content yielded from Ca-ion exchanged coal was more excellent in SO2 capture ability than ...

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The main purpose of this work is to evaluate the role of CT in identifying other morphological signs of met static lymph node involvement from non small cell bronchogenic carcinoma. This is done to improve N staging, a critical step in this disease. In fact, since diameter is the only criterion used to distinguish normal form abnormal lymph nodes, mediastinal CT only has 80% diagnostic accuracy. 137 patients with known or suspected lung cancer were examined with Helical CT during early and late arterial phases (2 min. delay, 3 mm thickness, 5 mm inter slice gap) to depict node characteristics. Mediastinal lymph nodes, located according to the American Thoracic Society mapping, were considered normal when they were not visible or, if visible, less than 1 cm in diameter and of homogeneous density; lymph nodes over 1 cm in diameter and homogenous density were considered reactive. A lymph node was considered metastatic when, independent of size, the following signs were found: central hypo ...

CERN Document Server

In this paper, we prove a uniqueness result in the inverse problem of determining several non-constant coefficients of one-dimensional reaction-diffusion equations. Such reaction-diffusion equations include the classical model of Kolmogorov, Petrovsky and Piskunov as well as more sophisticated models from biology. When the reaction term contains an unknown polynomial part of degree $N,$ with non-constant coefficients $\\mu_k(x),$ our result gives a sufficient condition for the uniqueness of the determination of this polynomial part. This sufficient condition only involves pointwise measurements of the solution $u$ of the reaction-diffusion equation and of its spatial derivative $\\partial u / \\partial x$ at a single point $x_0,$ during a time interval $(0,\\epsilon).$ In addition to this uniqueness result, we give several counter-examples to uniqueness, which emphasize the optimality of our assumptions. Finally, in the particular cases N=2 and ...

British Library Electronic Table of Contents (United Kingdom)

One of the main causes of hip prostheses failure is the premature wear of its components. Wear of metal-on-metal joints is a concern due to the toxicity and biological reaction of wear debris and metallic corrosion. The main aim of the present study was to investigate the tribological and corrosion behavior of surface engineering CoCrMo alloy. Different surface conditions were obtained on surgical grade wrought CoCrMo alloy: plasma nitrided (520^oC by 7h at gas mixture of 10% N2+90% H2), PVD coated (monolayer CrN and multilayer (TiN/CrN)x3) and modified using duplex surface engineering technology (a combination of the two previous approaches: plasma nitriding followed by plasma assisted PVD). Surfaces were characterized using scanning electron microscopy, nanoindentation, AFM and scratch t...

International Nuclear Information System (INIS)

This work presents a comparative study of low-alloy steel nitriding for different possible techniques. Active screen plasma nitriding (ASPN) is a successful surface modification method that has many advantages over the conventional DC plasma nitriding (CPN). The corrosion behavior of 30CrNiMo8 low-alloy steel has been examined using anodic polarization tests in 3.5% NaCl solution under varying conditions of ASPN and CPN processes. The process variables included active screen setup parameters, treatment temperature (550 and 580 deg. C), gas mixture (25/75 and 75/25 of N_2/H_2) and treatment time (5 and 10 h) in 500 Pa pressure. The structure and phases composition of the compound layer was studied by X-ray diffraction (XRD), microhardness tests, optical microscopy and scanning electron microscopy (SEM). It was observed that ASPN treated samples surface enhanced corrosion resistance while the temperature and/or hole size of screen setup ...

CERN Document Server

We present here the effective theory of inflation `a la Ginsburg-Landau in which the inflaton potential is a polynomial. The slow-roll expansion becomes a systematic 1/N expansion where N ~ 60. The spectral index and the ratio of tensor/scalar fluctuations are n_s - 1 = O(1/N), r = O(1/N) while the running turns to be d n_s/d \\ln k = O(1/N^2) and can be neglected. The energy scale of inflation M ~ 0.7 10^{16} GeV is completely determined by the amplitude of the scalar adiabatic fluctuations. A complete analytic study plus the Monte Carlo Markov Chains (MCMC) analysis of the available CMB+LSS data showed: (a) the spontaneous breaking of the phi -> - phi symmetry of the inflaton potential. (b) a lower bound for r: r > 0.023 (95% CL) and r > 0.046 (68% CL). (c) The preferred inflation potential is a double well, even function of the field with a moderate quartic coupling yielding as most probable values: n_s = 0.964, r = 0.051. This ...

International Nuclear Information System (INIS)

Polypeptides, copolymers of #alpha#-amino acids and #alpha#-hydroxy acids, could prove to be a valuable new class of synthetic biodegradable polymers. In this paper. steps in synthesis of poly (dl-lactide-co-3, 6-dimethylmorpholine-2,5-dione) from dl-lactide and dl-3,6-dimethylmorpholine-2,5-dione was explained. dl-Lactide was synthesized from lactic acid. In the reaction of 2-bromopropionyl chloride and dl-alanine, N-(2-bromopropionyl)-dl-alanine was prepared and this material was converted to its salt and finally this salt was converted to 3,6-dimethylmorpholine-2,5-dione in a sublime r. These two monomers, that is d l-lactide and dl-3,6-dimethylmorpholine-2,5-dione was polymerized by ring-opening polymerization. F T-IR, "1H NMR, "1"3C NMR Spectra were used for structure elucidation of all intermediate compounds and final product.

International Nuclear Information System (INIS)

The Ti-6Al-4V alloy was treated by inductively coupled rf plasma nitriding. The effects of plasma-processing time in the range of 5-35 min on the microstructure and the mechanical properties of the plasma-nitrided Ti-6Al-4V samples were studied. The plasma power input was adjusted at 450 W and pure N_2 gas was introduced to establish a treatment pressure of 8.0-8.4 x 10"-"2 mbar. The characteristics of the nitrided layers have been investigated by microhardness testing, surface roughness measurements, optical microscopy, and x-ray diffraction. The results show that the surface microhardness increases as the plasma-processing time increases to reach 2000 HV0.1 at a plasma-processing time of 35 min. A high nitriding rate of 2.81 #mu#m"2 s"-"1 at a plasma-processing time of 25 min was achieved. The formation of the hard phases TiN, Ti_2N, and Ti(N) in the Ti-6Al-4V surfaces are found to be the reason for the increased microhardness. Surface ...

International Nuclear Information System (INIS)

Somatostatin receptor expression has been demonstrated on a number of plasma cell lines. Therefore, we questioned whether somatostatin receptor scintigraphy (SRS) can be used to demonstrate in vivo multiple myeloma (MM) activity. SRS was performed in newly diagnosed (n = 9) or relapsing (n = 18) MM patients or in patients with localized plasmacytoma (n = 2). The results were compared with radiographic findings. A positive SRS was demonstrated in 44% of the newly diagnosed patients, in 83% of the relapsed patients and in both patients with plasmacytoma. The SRS findings corresponded with radiographic abnormalities in 40% of the patients. However, in relapsed patients 60% demonstrated increased SRS uptake in areas without new radiographic abnormalities. The positive SRS corresponded with histologically proven disease activity and responded upon treatment. Moreover, immunohistochemical staining of MM material demonstrated concordant somatostatin ...

Energy Technology Data Exchange (ETDEWEB)

In the Institute for Atomic Energy, Rikkyo University, just after the TRIGA-2 research reactor of 100 kW has attained the criticality, the cylindrical box for neutron radiography (NR) irradiation was made in the attached pool, and the research on NR was started in 1961. Thereafter in 1985, the vertical irradiation pipe was installed in the reactor tank, and the experiment for collecting the basic data was begun. In 1986, based on the obtained data, the NR irradiation facility on full scale was installed in No. 2 tangential horizontal experimental hole. As the main NR irradiation facilities, the vertical neutron irradiation pipe, the use of which is stopped now, the NR facility using the horizontal experimental hole (RUR/N2), the irradiation facility and ancillary facilities such as beam shutter, beam catcher and hoist are described. As the main equipments for NR, the imaging apparatuses of cooled type CCD, SIT and superhigh sensitivity, the ...

Energy Technology Data Exchange (ETDEWEB)

A method to control charge transfer reaction in DNA using hybrid nanometer-sized TiO{sub 2} nanoparticles was developed. In this system extended charge separation reflects the sequence of DNA and was measured using metallic silver deposition or by photocurrent response. Light-induced extended charge separation in these systems was found to be dependent on the DNA-bridge length and sequence. The yield of photocatalytic deposition of silver was studied in systems having GG accepting sites imbedded in AT runs at varying distances from the TiO{sub 2} nanoparticle surface. Weak distance dependence of charge separation indicative of a hole hopping through mediating adenine (A) sites was found. The quantum yield of silver deposition in the system having a GG accepting site placed 8.5 {angstrom} from the nanoparticle surface was found to be {Phi} = 0.70 (70%) and {Phi} = 0.56 (56%) for (A){sub n} and (AT){sub n/2} bridge, respectively. Hole injection ...

International Nuclear Information System (INIS)

The credibility of the model proposed by Ghosh in predicting the refractive indices of mixed semiconductor crystals of technological importance within their miscibility range as a function of band gap is demonstrated. The high-frequency refractive indices of four quaternary alloys Al_xGa_1_-_x_-_yIn_yP (y = 0.49, 0 #<=# x #<=# 0.51), InSb_xAs_1_-_x_-_yP_y (y = 2.2x, 0 #<=# x #<=# 0.313, 0 #<=# y #<=# 0.638), Cd_xZn_1_-_x_-_yHg_ySe (x + y = 1, 0.153 #<=# x #<=# 0.684, 0.316 #<=# y #<=# 0.847), and CdS_1_-_x_-_ySe_xTe_y (x + y = 1, 0.15 #<=# x #<=# 0.93, 0.07 #<=# y #<=# 0.85) are calculated according to the relation n"2-1 = A/(E_g + B)"2 where A is an energy gap dependent constant and B is a constant depending on crystal ionicity. The calculated values show excellent agreement with the experimental data thus justifying the validity of the model.

Energy Technology Data Exchange (ETDEWEB)

Excitation functions ({alpha},3n) and ({alpha},4n) for {sup 209}Bi have been measured up to 60 MeV {alpha}-particle energy. The excitation functions are measured at 15{alpha}-particle energies by a stack foil technique in two steps. Excitation functions for the above two reactions have been reported for the first time in the energy range from 40 to 60 MeV. The measured experimental values are compared with the geometry-dependent hybrid (GDH) model in which the emission of particles prior to the equilibrium decay is taken into account whenever the interaction of projectile with the target nucleus is considered. It is found that the compound nucleus decay mechanism alone is unable to explain the experimental trend of our data. The initial exciton number 4 with different configurations has been tested and it is concluded that the configuration (2n + 2p + 0h) gives the best fit to the experimental data. (author).

International Nuclear Information System (INIS)

Certain postulated faults during refuelling of AGRs may give rise to compacted fuel and graphite sleeve debris. This debris must be maintained below some safe limiting temperature. As part of a programme to assess the benefits of natural convection in cooling such debris in a region experiencing no forced cooling, a simple geometry incorporating typical debris has been studied both experimentally and by prediction. The experiment comprised an array of electrically heated fuel rods mounted co-axially in a closed cylindrical vessel and surrounded by fragments of graphite. The vessel was cooled on its cylindrical surface, the ends being insulated. Rods and vessel wall were thermocoupled. Tests covered a range of temperature and pressures in both CO_2 and N_2. Significant natural convection heat removal was demonstrated, particularly at high pressure. Predictions utilising the PHOENICS code agreed well with measured temperatures over a wide range ...

International Nuclear Information System (INIS)

Ternary R_2TSi_3 intermetallic compounds (R=Rare Earth, T=Transition Metal) with hexagonal AlB_2-type crystallographic structure are known because of their interesting physical properties. Pr_2PdSi_3 single crystals were grown by a vertical floating zone method. The compound exhibits congruent melting behavior at a liquidus temperature of about 1770 C. Single crystalline samples show a huge anisotropy at low temperatures due to the crystal electric field effect and order antiferromagnetically below the Neel temperature T_N=2.17 K. This value approximately obeys the linear de Gennes scaling for this class of compounds. The [001] orientation was identified as the magnetic easy axis at room temperature. At lower temperature (#approx#20 K) magnetic easy and hard axes interchange with each other. Two additional magnetic phase transitions were observed at temperatures below 1 K.

Energy Technology Data Exchange (ETDEWEB)

A set of computer codes have been developed to produce spectral line shapes of highly stripped ions for a number of transitions in Hydrogenic, Helium-like and Lithium-like species. The choice of the transitions has been dictated largely by the laser compression experiments. The transitions of Hydrogenic species are: Lyman ..cap alpha..; Lyman ..beta..; Lyman ..gamma..; Lyman delta; Balmer ..cap alpha..; and Balmer ..beta... The transitions of Helium-like species are: 1s/sup 2/(/sup 1/S/sub 0/)-1s2p(/sup 1/P); 1s/sup 2/(/sup 1/S/sub 0/)-1s3p(/sup 1/P); 1s/sup 2/(/sup 1/S/sub 0/)-1s4p(/sup 1/P) and the associated dipole-forbidden components. The transitions of Lithium-like species are the entire n = 2 to n = 3 and n = 4 complexes.

International Nuclear Information System (INIS)

Obtained experimental data on integral cross sections (ICS) of inelastic scattering of 50.5 MeV #alpha# particles with the excitation of "6","7Li, "9Be, "1"2","1"3C, "1"4C, "1"4N, "2"0Ne, "2"4Mg, "2"8Si nucleus low-lying energy levels are discussed. Regularities, detected in the behaviour of ICS forward scattering for 20-90 deg angles and backscattering for 90-160 deg angles for the target-nucleus under investigation are considered. Effect of reaction open channel number on #alpha#-particle scattering ICS where n,p,d- and #alpha#-channels were considered as the main channels for all the target-nuclei, is discussed. Dependence of #alpha#-particle scattering ICS on the target-nucleus level excitation energy and dependences of reaction open channel number on the channel spin, calculated for 50.5 MeV #alpha# particles and different target nuclei are shown in the diagrams. It is noted that the observed regularities in the #alpha#-particle inelastic ...

International Nuclear Information System (INIS)

A hydrogen combustion and exhaust emissions in a supercharged gas engine ignited with micro pilot diesel fuel was discussed in this presentation. A schematic diagram of the experimental study was first presented. The single cylinder, water-cooled, supercharged test engine was illustrated. Results were presented for the following: fuel energy and energy share (hydrogen and diesel fuel); pressure history and rate of heat release; engine performance and exhaust emissions; effect of nitrogen dilution on heat value per cycle; effect of N_2 dilution on pressure history and rate of heat release; and engine performance and exhaust emissions. This presentation demonstrated that smooth and knock-free engine operation results from the use of hydrogen in a supercharged dual-fuel engine for leaner fuel-air equivalence ratios maintaining high thermal efficiency. It was possible to attain mor3 than 90 per cent hydrogen-energy substitution to the diesel fuel ...

International Nuclear Information System (INIS)

The atomic structures of calcium sialons Ca_xSi_1_2_-_mAl_mN_1_6 (m = 0.5, 1, 2, 4) with the #alpha#- or #beta#-Si_3N_4-type structure were calculated, using the ab initio DFT approach, including relaxations of both lattice parameters and positions of the atoms. For all m values the #alpha#-Si_3N_4-type structure has a lower energy than the #beta#-type. For m = 1, 2 and 4 the #alpha#-type structure is also stable against decomposition into the metal nitrides, in agreement with experimental data. For m = 0.5 stability becomes uncertain. Al ions prefer positions close to Ca. Rather strong structural relaxations occur around the Ca ion.

International Nuclear Information System (INIS)

Nitrogen doped Diamond-like carbon thin films were deposited on n-Si and SiO_2 substrates by rf magnetron sputtering using pure graphite (99.999%) as the target material and mixtures of Ar, N_2 and H_2 for plasma generation. The dependence of structural and optical properties on nitrogen content was investigated using XPS, Raman spectroscopy, FT-IR spectroscopy, and Ellipsometry studies. It was found that as the nitrogen content was increased in the plasma, sp"2 bonding favored. Also it was observed that oxygen contamination increased with nitrogen content. Typical C-H stretching modes connected with diamond-like carbon could be seen in FT-IR spectra. The I_D and I_G bands were well defined and it was observed that as nitrogen content increased I_G band was enhanced. Ellipsometry studies revealed that the optical constants like refractive index (n) and extinction co-efficient (k) increased with increase in nitrogen content as well as substrate ...

British Library Electronic Table of Contents (United Kingdom)

Synthesis of highly anisotropic rod-like b-Si3N4 particles with different morphological characteristics was accomplished using commercial a-Si3N4. A number of powder mixtures were prepared with additions of various oxides (Al2O3+RE2O3, being RE=Y, La or Yb) that were subsequently heat treated in a loose powder state in the temperature range of 1750-1950degreeC and dwell times from 10 to 180min under high pressure of N2 (60MPa) in a hot isostatic press. The obtained aggregated porous bodies were lightly crushed by hand using an alumina mortar and pestle and subsequently subjected to sequential chemical treatments to eliminate the glassy phases and possible residual crystalline compounds, and to separate the synthesized b-Si3N4 particles. Resulting b-Si3N4 particles were characterized by X-r...

International Nuclear Information System (INIS)

Plasma nitriding is a powerful technique for modifying the phase-structure of the material surface layers, which affect the mechanical, physical and chemical properties of material. The effect of plasma nitriding on the surface properties of three types of steel (low carbon, AISI-304 and H13 (hardened)) has been investigated. The steel samples were plasma nitrided in vacuum of 10"-"1Pa with gas mixture of (N_2, H_2) at 530 Centigrade degree for a duration of 14 hours. Vickers microhardness measurements and XRD phase analysis of the treated and untreated samples were carried out. The diffraction patterns of treated steels revealed that new phases of #gamma#-Fe_4N, #epsilon#-Fe_3N and (Fe,Cr)_2N were formed. The maximum treated depths were about 5, 6 and 45 #mu#m for low carbon, AISI-304 and H13 (hardened) nitrided steel respectively. The microhardness was increased by about 150%, 200% and 140% for low carbon, AISI-304 and H13 nitrided samples ...

International Nuclear Information System (INIS)

A mass separated focused ion beam (FIB) is a very useful tool to fabricate nanostructures by writing implantation within an ion beam synthesis process. In these investigations the IMSA-OrsayPhysics FIB, equipped with a Co_3_6Nd_6_4 alloy liquid metal ion source, was applied. Si(100) and (111) wafers were implanted with 60 keV Co"+"+ ions in the dose range of 2 . 10"1"6 to 2 . 10"1"7 cm"-"2. Implantation parameters were investigated, like pixel dwell time, relaxation time (time between two cycles), dose rate as well as the pixel overlapping factor. The subsequent annealing was done in a two step process, namely 600 deg. C for 60 min and 1000 deg. C for 30 min in a N_2 ambient. The results obtained by SEM investigations in terms of continuous nanowire structures following the direction and interrupted CoSi_2 pattern in the direction show a clear dependence on the time scale as well as the scanning mode of the irradiation. Structure sizes as ...

International Nuclear Information System (INIS)

The nanosized luminescent Tb-MCM-41 (1:10) is synthesized by means of sol-gel-assisted self-assembly under basic conditions at room temperature. The results of "2"9Si-MAS NMR and XRD prove that Tb"3"+ doped Si-O framework. The HRTEM image shows that the regular uniform particles with a diameter of 10 nm possess ultralarge pore with diameter 2.0 nm, which is consistent with the result of N_2 adsorption. The BET surface area and porosity of Tb-MCM-41 (1:10) are 1127 m"2/g and 0.84 cm"3/g, respectively. The patterns of selected-area electron diffraction and XRD of Tb-MCM-41 (1:10) show an Fm3m space group in the cubic. FT-IR results show that the peaks near 970 cm"-"1 are assigned to the deformation vibration of silanol group. The as-products are calcined at 800 deg. C and the mesoporous materials possess enormous specific areas and large porosity, it shows that the mesoporous materials are ultrastable.

British Library Electronic Table of Contents (United Kingdom)

Cobalt supported on Beta zeolite catalysts were prepared by impregnation of metal salts in aqueous solution and were tested for the Fischer Tropsch reaction. The support consisted of a Beta zeolite composed by crystallites of nanometric dimensions and a SiO2/Al2O3 molar ratio of about 50. This support was impregnated with Co(NO3)2 aqueous solution using different metal loads of 7.5, 10, 15 and 20wt% Co. These materials were characterized by X-ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM), N2 adsorption (BET), thermal programmed reduction (TPR) and FTIR of adsorbed pyridine (i.e., surface acid sites distribution). All the catalysts showed a significant catalytic activity for the F-T reaction from synthesis gas (CO+2H2), in a continuous fixed bed reactor sys...

International Nuclear Information System (INIS)

Atomic oxygen is measured in a pulsed dielectric barrier discharge (DBD) using two-photon absorption laser-induced fluorescence (TALIF). The ground-level atomic oxygen is excited to the 3p "3P state by two-photon absorption at 226 nm. Negative (-40 kV) or positive (+30 kV) pulsed DBD occurs in an O_2-N_2 mixture at atmospheric pressure. The pulse width of the DBD current is approximately 50 ns. The TALIF experiment shows that the decay rate of atomic oxygen increases linearly with O_2 concentration. This result proves that atomic oxygen decays mainly by the third-body reaction, O + O_2 + M #-># O_3 + M. The rate coefficient of the third-body reaction is estimated to be 2.2 x 10"-"3"4 cm"6 s"-"1 in the negative DBD and 0.89 x 10"-"3"4 cm"6 s"-"1 in the positive DBD. It is shown that the decay rate of atomic oxygen increases linearly with humidity. This can explain the well-known fact that ozone production in DBD is suppressed by increasing ...

British Library Electronic Table of Contents (United Kingdom)

Platinum Group Element (PGE) concentrations in garnet pyroxenite xenoliths from Oahu, Hawaii, are significantly lower than those in mantle peridotites and show fractionated patterns (e.g. PdN/OsN=2-10, PdN/IrN=4-24; N=chondrite normalized) and very high ReN/OsN ratios (9-248). Mass balance calculations show that the bulk rock pyroxenite PGE inventory is controlled by the presence of sulfide phases. The 187Os/188Os ratios of these pyroxenites vary from subchondritic to suprachondritic (0.123-0.164); and the 187Os/188Os ratios show good correlations with bulk rock and clinopyroxene major and trace element compositions, and bulk rock PGE and sulfur abundances. These observations suggest that the Os isotope compositions in these pyroxenites largely reflect primary processes in the oceanic mant...

International Nuclear Information System (INIS)

Neuron differentiation is a complex process involving various cell-cell interactions, and multiple signaling pathways. We showed previously that CD40 is expressed and functional on mouse and human neurons. In neurons, ligation of CD40 protects against serum withdrawal-induced injury and plays a role in survival and differentiation. CD40 deficient mice display neuron dysfunction, aberrant neuron morphologic changes, and associated gross brain abnormalities. Previous studies by Tone and colleagues suggested that five isoforms of CD40 exist with two predominant isoforms expressed in humans: signal-transducible CD40 type I and a C-terminal truncated, non-signal-transducible CD40 type II. We hypothesized that differential expression of CD40 isoform type I and type II in neurons may modulate neuron differentiation. Results show that adult wild-type, and CD40"-"/"- deficient mice predominantly express CD40 type I and II isoforms. Whereas adult wild-type mice express mostly CD40 type I in ...

International Nuclear Information System (INIS)

In 1999, the plasma parameters of reversed shear (RS) plasmas had been extended in 1) DT-equivalent fusion power gain Q_D_T"e"q - 0.5 (n_D(0)#tau#_ET_i(0) - 4x10"2"0 m"-"3#centre dot#keV#centre dot#s) for 0.8 s and 2) full non-inductive current drive with 80% of the bootstrap current fraction. Physics of the internal transport barriers (ITBs) in RS plasmas, including the energy transport and the formation of ITB, were extensively studied. A nearly full current drive (92% non-inductively) was obtained with negative ion based neutral beam (NNB) injection (360 keV, 3.4 MW) in a high #beta#_p H-mode plasma (I_p=1.5 MA, B_T=3.7 T, q_9_5=4.2) with high plasma performance (#beta#_N=2.4 and H_8_9=2.56). Rise in the central electron temperature (T_e - 9 keV) resulted in the current drive efficiency #eta#_C_D of NNB reached 1.3x10"1"9 A/W/m"2, the highest for the neutral beam current drive. As for the H-mode plasmas, decrease in the pedestal ion ...

Science.gov (United States)

Under different sintering temperatures(340 degrees C, 440 degrees C, 540 degrees C, 640 degrees C), four TiO2 particles were prepared. The crystal types of all four samples were found to possess anatase structures by XRD. It was obtained by N2 experimental adsorption at low temperature (77K) that their surface areas and average pore size were between 79 and 124 m2/g, 56.8 and 254.8 A respectively. The pore structure of TiO2 particles was characterized by scanning electron microscope (SEM). The tests of adsorption dynamics for FGD and the performance of SO2 removal were investigated in a fixed-bed system for different samples. The results show that SG540 sample which made at 540 degrees C sintering temperature had the most quality among the four samples. It can adsorb SO2 of 38.9 mg for one gram SG540 sample. Different operating conditions for SG540 such as adsorption temperature, SO2 concentration in flue gas and the superficial velocity of ...

International Nuclear Information System (INIS)

An experimental investigation of the 70.5 keV #gamma#-ray transition from the 55/22"+[402] state to the 77/22"+[404] ground state in "1"7"7Ta was made. The half-life and magnetic moment of the initial state were found to be 73+-5 ns and 4.7+-0.5 #mu#sub(N) respectively. The E2/M1 mixing ratio of the transition was determined to be -0.10+-0.04. The reduced transition probabilities, B(E2) and B(M1), were found to be 2.9+-2.3e"2.fm"4 and (1.1+-0.1)x10"-"4#mu#sub(N)"2, respectively, and the M1 penetration parameter was determined to be 6+-2. The Coriolis mixing amplitude of the 75/22"+[402] state in the 77/22"+[404] ground state was determined from the B(E2) value to be -0.011+-0.004. It was found that the experimental value of the Coriolis matrix element <5/2"+/j-/7/2"+>sub(exp) was one-tenth of that calculated using the Nilsson wave function. The coefficient k_2, introduced by Wahlborn et al., was re-analyzed using the present experimental ...

British Library Electronic Table of Contents (United Kingdom)

Varying coordination modes of the Schiff base ligand H"2L [5-methyl-1-H-pyrazole-3-carboxylic acid (1-pyridin-2-yl-ethylidene)-hydrazide] towards different metal centers are reported with the syntheses and characterization of four mononuclear Mn(II), Co(II), Cd(II) and Zn(II) complexes, [Mn(H"2L)(H"2O)"2](ClO"4)"2(MeOH) (1), [Co(H"2L)(NCS)"2] (2), [Cd(H"2L)(H"2O)"2](ClO"4)"2 (3) and [Zn(H"2L)(H"2O)"2](ClO"4)"2 (4), and a binuclear Cu(II) complex, [Cu"2(L)"2](ClO"4)"2 (5). In the complexes 1-4 the neutral ligand serves as a 3N,2O donor where the pyridine ring N, two azomethine N and two carbohydrazine oxygen atoms are coordinatively active, leaving the pyrazole-N atoms inactive. In the case of complex 5, each ligand molecule behaves as a 4N,O donor utilizing the pyridine N, one azomethine N...

International Nuclear Information System (INIS)

In this paper, we report on a comparative study of active screen plasma nitriding (ASPN) and conventional dc plasma nitriding (CPN) behavior of 30CrNiMo8 low-alloy steel that has been examined under various process conditions. The process variables included active screen setup parameters (screen and iron plate top lids placed on the screen setup with 8 mm of hole size), treatment temperature (550 and 580 deg. C), gas mixture (75/25 and 25/75 of N_2/H_2) and treatment time (5 and 10 h) in 500 Pa pressure. The structure and phases composition of the diffusion zone and compound layer were studied by X-ray diffraction (XRD), microhardness tests, light optical microscopy and scanning electron microscopy (SEM). It was observed that treated sample surfaces in both CPN and ASPN methods consist of #gamma#' and #epsilon# phases, and while the nitriding time and/or temperature increases, the intensity of #epsilon# phase in the compound layer will increase ...

Energy Technology Data Exchange (ETDEWEB)

This study focuses on a series of Pt{sup II}(L-L{prime})(dppm){sup n+} complexes, where dppm is bis(diphenylphosphino)methane and L-L{prime} are C(caret)C{prime} (n = 0), C(caret)N (n = 1), and N(caret)N{prime} (n = 2) aromatic ligands. Structural characteristics are reported. Structural features indicate that the Pt-C bond distance is shorter than the Pt-N bond distance in symmetrical complexes and that the Pt-P bond distance trans to N is shorter than the Pt-P bond trans to C. This is consistent with the {sup 31}P NMR spectra where the chemical shift of the P trans to C is {approximately}10 ppm less than found for P trans to N. The energy maxima of the metal-to-ligand charge-transfer band for the complexes containing various L-L{prime} ligands occur in the near-UV region of the spectrum and fall into the energy series bpy > bph > phen > 2-phpy > 2-ptpy > 2-phq > 7,9-bzq, where bpy is ...

International Nuclear Information System (INIS)

''Magnetic braking'' of the plasma toroidal rotation in the high confinement H mode by applied resonant, low m,n=1 static error fields is used in DIII-D [Nucl. Fusion 31, 875 (1991)] as an independent control to evaluate the E_rxB stabilization of microturbulence in the plasma core. In the core (#rho# approx-lt 0.9) of a tokamak, the radial electric field and its shear are dominated by toroidal rotation. The fundamental quantity for shear stabilization of microturbulence is shear in the velocity of the fluctuations v_p_e_r_p_e_n_d_i_c_u_l_a_r#approx#E_rxB/B#centre dot#B which in the core is v_p_e_r_p_e_n_d_i_c_u_l_a_r#approx#v_#phi#B_#theta#/ B_#phi#. With magnetic braking greatly decreasing the toroidal rotation and thus reducing the core radial electric field and shear, far infrared (FIR) measurements of density microturbulence show downshifting in frequency near #rho##approx#0.8 as a result of the reduced Doppler shift (#omega##approx#k_#theta#E_r/B_#phi#) and a factor of 2 increase ...

International Nuclear Information System (INIS)

The model compounds, 8-methoxypsoralen-CH_2O(CH_2)_n-adenine (MOPCH_2OC_nAd, n=2,3,5,6,8, and 10) in which 5 position of 8-methoxypsoralen (8-MOP) is linked by various lengths of polymethylene bridge to N"9 of adenine. UV absorption spectra are identical with the sum of MOPCH_2OC3 and adenine absorption spectra. Solvent effect on the UV absorption and fluorescence emission spectra indicate that the lowest excited singlet state is the (#pi##->##pi#"*) state. The spectral characteristics of the fluorescence of MOPCH_2OC_nAd are strongly dependent upon the nature of the solvents. The fluorescence emission spectra in aprotic solvents are broad and structrueless due to the excimer formation through the folded conformation accelerated by hydrophobic #pi#-#pi# stacking interaction. Increasing polarity of the protic solvents leads to higher population of unfolded conformation stabilized through favorable solvation and H-bonding, and consequently to ...

International Nuclear Information System (INIS)

We outline basic principles of a canonical formalism for the Nambu mechanics - a generalization of Hamiltonian mechanics proposed by Yoichiro Nambu in 1973. It is based on the notion of a Nambu bracket, which generalizes the Poisson bracket - a 'binary'' operation on classical observables on the phase space - to the 'multiple' operation of higher order n#>=#3. Nambu dynamics is described by the phase flow given by Nambu-Hamilton equations of motion - a system of ODE's which involves n-1 'Hamiltonians'. We introduce the fundamental identity for the Nambu bracket - a generalization of the Jacobi identity - as a consistency condition for the dynamics. We show that Nambu bracket structure defines a hierarchy of infinite families of 'subordinated' structures of lower order, including Poisson bracket structure, which satisfy certain matching conditions. The notion of Nambu bracket enables us to define Nambu-Poisson manifolds - phase spaces for the Nambu mechanics, which turn out to be ...

International Nuclear Information System (INIS)

Radiopharmaceuticals for brain imaging are used for the detection of ischemia, tumours and dementia associatied with disorders of the blood flow in the brain. The current radiopharmaceuticals for brain imaging have various limitations: 2-(F-18)fluoro-2-deoxyglucose (F-18-FDG) has a very short half-life. The physical properties of di-#beta#-(piperidinoethyl)-(Se-75)selenide (Se-75-PIPSE) and di-#beta#-(morpholinoethyl)-(Se-75)-selenide (Se-75-MOSE) are not ideal. Thallium-201 diethyldithricarbamate (T1-201-DDC) has unfavourable nuclidic characteristics, limited availability, a long half-life and high cost. I-123 in N-isopropyl-p-iodoamphetamine (I-123-IMP) and N,N,N'-trimethyl-N'-(2-hydroxy-3-methyl-5-iodobenzyl)-1,3-propanediamine (I-123-HIPDM) are not freely available and are expensive. N-13-labelled ammonia has a very short half-life. Technetium-99m hexamethylpropyleneamineoxime (Tc-99m-HM-PAO) is unstable both in vitro and in vivo and has a ...

Energy Technology Data Exchange (ETDEWEB)

We report the performance of a commercial recuperated micro gas turbine on biomass producer gas and mixtures of biomass producer gas with natural gas. The biomass producer gas, obtained by gasification at 850{sup o}C with air at atmospheric pressure, contains about 7% H2, 17% CO, 15% CO2, 4% CH4, 2% other hydrocarbons, 2% H2O, and a balance of N2 and Ar from air. It has a net heating value of about 6 MJ/(Nm{sup 3}). The micro gas turbine delivers full power (30 kW{sub e}) on gas mixtures with a net heating value of at least 15 MJ/(Nm{sup 3}). For gas of lower heating value, the maximum fuel gas flow allowed by the fuel control unit limits the attainable power. At reduced power, the lower limit for stable operation is a net heating value of about 8 MJ/(Nm{sup 3}). The gross efficiency of the micro gas turbine depends on the output power but not on the gas heating value, within our estimated measurement accuracy of about 2%. Above 70% of full ...

International Nuclear Information System (INIS)

We succeeded in synthesizing a new cubic intermetallic compound PrCu_4Ag in a fcc structure. Measurements of X-ray diffraction, magnetic susceptibility, magnetization, specific heat, electrical resistivity, thermal expansion, and elastic constants have been performed on single crystals of PrCu_4Ag. A maximum value of #chi#(T) with a corresponding peak in C(T) suggests that an antiferromagnetic phase transition occurs at T_N=2.4 K, where a sudden decrease in #rho#_4_f(T) and a sharp peak in the thermal expansion coefficient #alpha#(T) were observed. Characteristic Curie-type softening was observed in the temperature dependence of the transverse mode for (C_1_1 - C_1_2)/2 and C_4_4 from 70 K down to T_N, which implies that the crystalline electric field (CEF) ground state is the magnetic triplet #GAMMA#_5. The anisotropic properties in M(T,H) and C(T,H) are studied when the external magnetic field is applied in the <100>, <110>, and ...

International Nuclear Information System (INIS)

Purpose: To identify results and prognostic factors on long-term survival and local control following treatment of localized Ewing's sarcoma. Patients and Methods: Between 1979 and 2004, a total of 60 children and young adults with Ewing's sarcoma were treated. Patients with distant metastases at presentation (n = 6) and recurrent cases (n = 2) were excluded from this analysis. Patients were exclusively treated within ongoing national and international protocols CESS-81, CESS-86, EICESS-92, EURO-EWING-99. All patients received local irradiation with a total dose of 45-60 Gy; in addition, 41 (79%) of the patients had local surgical procedures, 27 (52%) of them with clear margins. Results: Overall survival rates at 5 and 10 years were 56% and 45%, respectively. Patients #<=# 14 years at diagnosis had overall survival rates of 66% and 61% at 5 and 10 years compared to older patients with corresponding survival rates of 47% and 31%, respectively ...

International Nuclear Information System (INIS)

The Phebus FP project in an international reactor safety project. Its main objective is to study the release, transport and retention of fission products in a severe accident of a Light Water Reactor (LWR). The FPT4 test was performed with a fuel debris bed geometry, to look at late phase core degradation and the releases of low volatile fission products and actinides. Post Test Analyses results indicate that releases of noble gases (Xe, Kr) and high-volatile fission products (Cs, I) were nearly complete and comparable to those obtained during Phebus tests performed with a fuel bundle geometry (FPT1, FPT2). Volatile fission products such as Mo, Te, Rb, Sb were released significantly as in previous tests. Ba integral release was greater than that observed during FPT1. Release of Ru was comparable to that observed during FPT1 and FPT2. As in other Phebus tests, the Ru distribution suggests Ru volatilization followed by fast redeposition in the fuelled section. The similar release ...

International Nuclear Information System (INIS)

Fourier transform infrared absorption spectroscopy has been used for the determination of the line strengths of 41 CO and CO_2 absorption lines at temperatures between 295 and 1250 K. The CO vibrational-rotational lines were from the P branch of the fundamental absorption band (2150--1950 cm"-"1) while the CO_2 vibrational-rotational lines were from the far wing of the R branch of the #nu#_3 fundamental band (2395--2380 cm"-"1). The intensities of the lines were measured from absorption spectra recorded in a high-temperature gas cell containing known concentrations of CO/CO_2/N_2 gas mixtures at atmospheric pressure. Absorption spectra were recorded through the cell with the use of a moderate-resolution Fourier transform infrared spectrometer. The absorption spectra were mathematically corrected for distortions resulting from the finite resolution of the spectrometer and for peak overlap. Line strength measurements were made from the corrected ...

International Nuclear Information System (INIS)

We report the results of a theoretical study of the electronic and structural properties of the hexagonal beryllium nitride, using first principle pseudopotential plane wave (PP-PW) as well as full potential linearized augmented plane wave (FP-LAPW) methods within density functional theory. In the case of PP-PW we generated the pseudopotential by the highly optimized Q_c-tuning method and used the local density approximation and generalized gradient approximation (GGA) for the exchange-correlation potential. We applied pressure on the unit cell by the Wentzcovitch and traditional methods. In the FP-LAPW approach only the GGA was used for the exchange-correlation potential. Our calculated values for structural properties, based on both approaches are in reasonable agreement with experimental and other theoretical (Hartree Fock) results. By applying the above two approaches and also the Tight Binding Linear Muffin Thin Orbital method, the ground state Kohn-Sham eigenvalues were ...

Energy Technology Data Exchange (ETDEWEB)

This description of work (DOW) details the field activities associated with the sampling of the vadose zone soils beneath the 1301-N and 1325-N cribs and trenches and will serve as a field guide for those performing the work. These activities are undertaken pursuant to the Hanford Federal Facility Agreement and Consent Order (Ecology et al., 1994a) Milestone M-16-94-01H-Tl and the June 30, 1994 Milestone Change Request M-16-94-02 (Ecology et al., 1994b). Three vadose zone borings, 1301-N-1, 1301-N-2, and 1325-N-1, will be constructed to investigate the vertical and horizontal distribution of radionuclide contamination in sediments beneath the cribs and trenches. The boreholes are also intended to intersect subsurface areas that may have been contaminated by dangerous wastes, i.e., metals, in effluent disposed during past operation of the facilities. This limited field investigation will provide data for the evaluation of remedial alternatives. ...

Energy Technology Data Exchange (ETDEWEB)

Results of an experimental study of the interaction of 140 MeV alpha particles with /sup 90/Zr nuclei resulting in fragmentation of the alpha particle are reported. The experimental observations of the study are analyzed and are found to show that alpha particle breakup reactions leading to at least 4-body final states, composed of two charged alpha particle fragments, contribute significantly to the singles yield of charged fragments observed at a fixed forward angle. The conclusions are based on coincidence measurements where one charged fragment is detected at a small forward angle which remains fixed, while the second charged fragment is detected at a series of coplanar secondary angles. The largest coincidence charged particle yield for the multiparticle final state events results from /sup 90/Zr(..cap alpha..,pp)X reactions, where both of the measured protons have energy distributions similar to the proton singles energy distributions. The second largest observed coincidence ...

International Nuclear Information System (INIS)

Constant pull rate tests were conducted on tensile specimens of Inconel Alloy 600, Incoloy Alloy 800, and Type 304 stainless steel in deaerated 10% NaOH solution at 288 C (550 F) with a cover gas of 5% H_2 in N_2. The pull rate used for most experiments was 3.3 x 10"-"6 cm/s, which corresponds to an initial strain rate of 3 x 10"-"6 s"-"1. The electrical potential of the specimens was controlled by a potentiostat using a nickel wire as a hydrogen reference electrode. Under open circuit conditions, Type 304 stainless steel specimens cracked rapidly, but Alloys 600 and 800 specimens exhibited only ductile fracture. However, cracks readily formed in Alloy 800 specimens at potentials in the +50 to +300 mV range and in Alloy 600 specimens at potentials in the +150 to +250 mV range. Scanning electron microscope (SEM) photographs of some of the cracked specimen surfaces showed the transition from ductile to brittle fracture as a consequence of changes ...

Energy Technology Data Exchange (ETDEWEB)

To establish the optimum barium-based reduced-laxative tagging regimen prior to CT colonography (CTC). Ninety-five subjects underwent reduced-laxative (13 g senna/18 g magnesium citrate) CTC prior to same-day colonoscopy and were randomised to one of four tagging regimens using 20 ml 40%w/v barium sulphate: regimen A: four doses, B: three doses, C: three doses plus 220 ml 2.1% barium sulphate, or D: three doses plus 15 ml diatriazoate megluamine. Patient experience was assessed immediately after CTC and 1 week later. Two radiologists graded residual stool (1: none/scattered to 4: >50% circumference) and tagging efficacy for stool (1: untagged to 5: 100% tagged) and fluid (1: untagged, 2: layered, 3: tagged), noting the HU of tagged fluid. Preparation was good (76-94% segments graded 1), although best for regimen D (P = 0.02). Across all regimens, stool tagging quality was high (mean 3.7-4.5) and not significantly different among regimens. The HU of layered tagged fluid was ...

Science.gov (United States)

A way to synthesize the transient zwitterionic silylene L'Si: 8 {L'=CH[(C=CH(2))CMe(N(tBu))(2)]} and achieve its facile dimerization to the remarkable N-heterobicyclic disilane 8(2) is described. At first, employing the beta-diketiminate ligand L [L=CH(CMeN(tBu))(2)], both starting materials LH (2) and its N-lithium salt LLi (3) can react with SiBr(4) to yield the silylene precursor L'SiBr(2) (4) by silicon-induced C-H activation at an exocyclic methyl group on the backbone of the ligand. Compound 4 reacts with SiBr(4) above room temperature to afford the unexpected terminal CH(SiBr(3))-substituted dibromosilane 6 along with the unique tricyclic trisilane 7. Reduction of 4 with KC(8) at 0 degrees C furnishes the novel N-heterobicyclic disilane 8(2), which is a formal dimer of the desired zwitterionic silylene L'Si: (8). It has been reasoned that compound 8(2) may results from [4+1] cycloaddition of two molecules of 8 to give the transient dimer 8(2)', which subsequently undergoes ...

International Nuclear Information System (INIS)

We have observed the CH_3OH J = 2-1, SiO J = 2-1, C"3"4S J = 2-1, H"1"3CO"+ J = 1-0, HN"1"3C J = 1-0, CCH N = 1-0, OCS J = 8-7, and SO J_N = 2_2-1_1 lines toward 20 massive clumps, including Midcourse Space Experiment (MSX) 8 #mu#m dark sources (infrared dark clouds) and MSX 8 #mu#m sources, by using the Nobeyama Radio Observatory 45 m telescope. We have found that the velocity widths of the CH_3OH and C"3"4S lines are broader than those of the H"1"3CO"+ line in the MSX dark sources. On the other hand, they are comparable to the velocity width of the H"1"3CO"+ line in the MSX sources. In addition, the [SiO]/[H"1"3CO"+] abundance ratio is found to be enhanced in the MSX dark sources in comparison with the MSX sources. These results suggest that shocks caused by interaction between an outflow and an ambient dense gas would have substantial impact on the chemical composition of the MSX dark sources. The velocity widths of the CH_3OH and C"3"4S ...

Energy Technology Data Exchange (ETDEWEB)

Objective: To compare the histopathology of nodular fasciitis (NF) with the magnetic resonance imaging (MRI) findings in order to evaluate the basis of the MR signal characteristics. Design and patients: Ten patients with NF, nine females and 1 male, with an age ranging from 13 to 58 years (mean 26.8 years) were studied. MRI findings, available in all 10 patients, were compared with the histopathology in nine patients, and an area-to-area comparative study of the whole specimen section histopathology and MRI was performed in two patients. Results: On the basis of an excisional biopsy or resection specimen, the nine lesions were classified into myxoid (n=4), cellular (n=3) and fibrous (n=2) subtypes. Four myxoid lesions with a subcutaneous location showed a homogeneous SI comparable with muscle on T1-weighted images, high SI on T2-weighted images, and had homogeneous enhancement. One cellular lesion presented with homogeneous, slightly higher SI ...

International Nuclear Information System (INIS)

Purpose: To assess the prognostic value of biologic (p53, Ki-67) and clinical factors in squamous cell carcinoma of the oropharynx after radical surgery and postoperative radiotherapy (RT). Methods and Materials: Between 1985 and 1995, a total of 102 patients with 104 tumor sites were entered onto the study. Fifty-five primary tumors (53%) involved the tonsils, 26 (25%) the soft palate, and 23 (22%) the base of the tongue. Median age was 53 years (range 36-80 years). The clinical T- and N-categories (UICC 1997) were: T1 (30), T2 (47), T3 (22), T4 (5), N0 (33), N1 (28), N2 (42), and N3 (1). Histologically-clear margins were achieved in all patients by initial surgery. Postoperative RT to the primary and regional lymphatics was given, to a total of 60 Gy in 6 weeks, and single daily fractions of 2 Gy. The expression of the nuclear p53- and Ki-67-labeling index (LI) was investigated by immunostaining using the monoclonal antibodies DO-7 and MIB 1. ...

International Nuclear Information System (INIS)

The crystal structure, electronic structure, and photoluminescence properties of EuxSi6-zAlz-xOz+xN8-z-x (x=0-0.1, 0xMySi6-zAlz-x-yOz+x+yN8-z-x-y (M=2Li, Mg, Ca, Sr, Ba) have been studied. Single-phase EuxSi6-zAlz-xOz+xN8-z-x can be obtained in very narrow ranges of x?0.06 (z=0.15) and z2+ ions can be incorporated into nitrogen-rich Si6-zAlzOzN8-z. The Eu2+ ion is found to occupy the 2b site in a hexagonal unit cell (P63/m) and directly connected by six adjacent nitrogen/oxygen atoms ranging 2.4850-2.5089 A. The calculated host band gaps by the relativistic DV-X? method are about 5.55 and 5.45 eV (without Eu2+ 4f5d levels) for x=0 and 0.013 in EuxSi6-zAlz-xOz+xN8-z-x (z=0.15), in which the top of the 5d orbitals overlap with the Si-3s3p and N-2p orbitals within the bottom of the conduction band of the host. EuxSi6-zAlz-xOz+xN8-z-x shows a strong green emission with a broad Eu2+ band centered at about 530 nm under UV to near-UV excitation range. ...