With conventional heating process, ultraviolet (UV) illumination, and microwave irradiation, we have successfully synthesized UV curable encapsulating adhesives with excellent gas barrier capabilities, good adhesive strength, moderate hardness, and high refractive indices. The experimental results manifest that the physical properties of lab-made encapsulating adhesives are highly dependent on their chemical structures and synthetic procedure. We also discover that the encapsulating adhesive prepared by microwave irradiation (i.e. encapsulating adhesive VI-MW) exhibits better adhesive strength and higher gas resistance than those prepared by conventional heating process and UV illumination. Furthermore, encapsulating adhesive VI-MW has also been applied for the package of organic light emi...
A procedure was developed for separating rubidium from irradiated aluminum encapsulated uranium. The separations procedure produces a final ultra-high purity RbCl product for subsequent high performance mass spectrometric analysis. The procedure involves first removing most of the macro-components and fission products by strong base anion exchange using, first, concentrated HCl, then oxalic acid media and second, selectively separating rubidium from alkaline-earth ions and other alkali-metal ions, including cesium, using Bio-Rex-40 cation-exchange resin. The resultant RbCl is then put through a final vacuum sublimation step. Ultra-pure reagents and specially clean glassware are used throughout the procedure to minimize contamination by naturally-occurring rubidium.
A procedure was developed for separating rubidium from irradiated aluminum encapsulated uranium. The separations procedure produces a final ultra-high purity RbCl product for subsequent high performance mass spectrometric analysis. The procedure involves first removing most of the macro-components and fission products by strong base anion exchange using, first, concentrated HCl, then oxalic acid media and second, selectively separating rubidium from alkaline-earth ions and other alkali-metal ions, including cesium, using Bio-Rex-40 cation-exchange resin. The resultant RbCl is then put through a final vacuum sublimation step. Ultra-pure reagents and specially clean glassware are used throughout the procedure to minimize contamination by naturally-occurring rubidium.
The feasibility of continuous production of gallium arsenide ribbon single crystals, by passage of a molten zone through boron-oxide encapsulated GaAs feedstock, is being investigated. Polycrystalline GaAs ribbons have been grown in graphite boats by passage of a wide zone through B2O3-encapsulated feed-stock, confined by a quartz cover plate. Failure to remove the encapsulant above its glass transition temperature, however, resulted in cracking of the ribbons on cooling to room temperature. In order to study the crucial zone melting step in isolation from the encapsulation steps of the continuous process, a constrained-zone melting apparatus has been constructed in which the boron oxide serves only as a sealant to suppress arsenic vaporization. Large grained polycrystalline samples have been produced with this apparatus.
Thermoplastic encapsulation has been extensively studied at Brookhaven National Laboratory`s (BNL) Environmental and Waste Technology Center (EWTC) as a waste encapsulation technology applicable to a wide range of waste types including radioactive, hazardous and mixed wastes. Encapsulation involves processing thermoplastic and waste materials into a waste form product by heating and mixing both materials into a homogeneous molten mixture. Cooling of the melt results in a solid monolithic waste form in which contaminants have been completely surrounded by a polymer matrix. Heating and mixing requirements for successful waste encapsulation can be met using proven technologies available in various types of commercial equipment. Processing techniques for thermoplastic materials, such as low density polyethylene (LDPE), are well established within the plastics ...
The process of miniemulsification allows the generation of small, homogeneous, and stable droplets containing monomer or polymer precursors and magnetite which are then transferred by polymer reactions to the final polymer latexes, keeping their particular identity without serious exchange kinetics involved. It is shown that the miniemulsion process can excellently be used for the formulation of polymer-coated magnetic nanoparticles which can further be used for biomedical applications. The use of high shear, appropriate surfactants, and the addition of a hydrophobe in order to suppress the influence of Ostwald ripening are key factors for the formation of the small and stable droplets in miniemulsion and will be discussed. Two different approaches based on miniemulsion processes for the encapsulation of magnetite into polymer particles will be presented in detail.
This paper describes the unique challenges involved in achieving compliance with the Resource Conservation and Recovery Act (Public Law 94-580) Land Disposal Restrictions (LDR) treatment standards for four types of mixed wastes generated throughout the U.S. Department of Energy (DOE) complex: (1) radioactively contaminated lead acid batteries; (2) radioactively contaminated cadmium-, mercury-, and silver-containing batteries; (3) mercury-bearing mixed wastes; and (4) radioactive lead solids. For each of these mixed waste types, the paper identifies the strategy pursued by DOE's Office of Pollution Prevention and Resource Conservation Policy and Guidance (EH-43) in coordination with other DOE elements and the U.S. Environmental Protection Agency (EPA) to meet the compliance challenge. Specifically, a regulatory interpretation was obtained from EPA agreeing that the LDR treatment standard for wastes in the D008 'Radioactive Lead Solids' sub-category applies to radioactively contaminated ...
The long-term stability of pentacene thin-film transistors (TFTs) encapsulated with a transparent SnO{sub 2} thin-film prepared by ion beam-assisted deposition (IBAD) was investigated. After encapsulationprocess, our organic thin-film transistors (OTFTs) showed somewhat degraded field-effect mobility of 0.5 cm{sup 2}/(V s) that was initially 0.62 cm{sup 2}/(V s), when a buffer layer of thermally evaporated 100 nm SnO{sub 2} film had been deposited prior to IBAD process. However, the mobility was surprisingly sustained up to 1 month and then gradually degraded down to 0.35 cm{sup 2}/(V s) which was still three times higher than that of the OTFT without any encapsulation layer after 100 days in air ambient. The encapsulated OTFTs also exhibited superior on/off current ratio of over 10{sup 5} to that of the unprotected devices ({approx}10{sup 4}) which was reduced ...
For prolonged storage and eventual disposal radioactive wastes will be solidified to reduce the problems which accompany liquid waste whilst solid wastes will be encapsulated in an immobilising matrix. In the solidification and encapsulationprocess it will be important to produce a material in a form which is chemically stable, mechanically strong and which will not react with or allow free passage of groundwater. To this end a continuous check will be required to ensure that the various wastes are chemically compatible with the solidifying and binding matrices and that the associated processes are performed against a strict Quality Programme. The Quality Programme will be extensive requiring the specification of procedures for assessing the quality and nature of the wastes, the detailed operation of the solidification and/or encapsulation, the overpack requirements for ...
This paper demonstrates that a commercial-scale facility for encapsulating krypton-85 in zeolite-5A or glass at a 2000 MTHM per year nuclear fuel reprocessing plant can be designed to contain fragments and the 340 to 850 kCi krypton-85 inventory from an assumed catastrophic failure of the high pressure vessel. The vessel failure was assumed as a worst case and was not based on a detailed design evaluation or operating experience. The process design is based on existing commercial hot isostatic pressing technology operated at up to 40 times the scale required for krypton encapsulation. From the calculated process gas inventory in the pressure vessel and vessel design, the maximum explosive energy of 8.4 kg TNT and resulting vessel plug and fragment velocities were calculated. The facility Containment Cell housing the high pressure vessel was designed to contain the gases, fragments, and the shock wave ...
Solar cells and organic electronic devices require an encapsulation to ensure sufficient lifetime. Key parameters of the encapsulation are permeation barrier, UV stability, temperature stability, optical transmission spectra and mechanical stability. The requirements depend very much on the specific application. Many work groups suggest multilayer stacks to meet the permeation requirements. In this paper the permeation barrier properties of the different constituents of such a multilayer stack are characterized. Different layer materials are compared regarding their water vapour and oxygen permeability as well as the influence of process parameters is examined. Finally temperature dependent permeation measurements are used to characterize the permeation mechanisms in the different constituents of the multilayer barrier.
In this paper it is shown that the ''third postulate'' of special relativity (i.e. the so-called ''Reinterpretation principle'' by Stueckelberg and by Faynmam) is enough to implement the law of retarded casuality for tachyons even in macro-physics, when usual macro-objects interact with micro-tachyons and macro-tachyons.
Current multi-scale computational models of ventricular electromechanics describe the full process of cardiac contraction on both the micro- and macro- scales including: the depolarization of cardiac cells, the release of calcium from intracellular stores, tension generation by cardiac myofilaments, and mechanical contraction of the whole heart. Such models are used to reveal basic mechanisms of cardiac contraction as well as the mechanisms of cardiac dysfunction in disease conditions. In this paper, we present a methodology to construct finite element electromechanical models of ventricular contraction with anatomically accurate ventricular geometry based on magnetic resonance and diffusion tensor magnetic resonance imaging of the heart. The electromechanical model couples detailed repres...
This paper describes the needs, reasoning, approaches, and technical details to establish a practical accelerated weathering test (AWT) protocol for indoor testing of the photothermal stability of encapsulation materials and encapsulated solar cells and minimodules.
Nowadays climate change is one of the environmental problems in the global policy agenda. However, in countries like United States and United Kingdom the media started to report regularly on this issue in 1988. Since then many researches have been carrying out focused on how the media influence, along with other factors, public understanding of climate change through the media construction of the problem in several countries. Given the implications of social acceptance for design and implementation of public policies on mitigation and adaptation to climate change, the overall aim of this report is to review the status of the issue from a qualitative and quantitative approach. Qualitatively, media construction of climate change is described as the result of different processes taking place at macro and micro scales. Interactions among scientists, politicians, industry, the media themselves and the social context are considered ...
The stages of processes leading to radiation damage are studied, as well as, the direct and indirect mechanics of its production. The radiation effects on nucleic acid and protein macro moleculas are treated. The physical and chemical factors that modify radiosensibility are analysed, in particular the oxygen effects, the sensibilization by analogues of nitrogen bases, post-effects, chemical protection and inherent cell factors. Consideration is given to restoration processes by excision of injured fragments, the bloching of the excision restoration processes, the restoration of lesions caused by ionizing radiations and to the restoration by genetic recombination. Referring to somatic effects of radiation, the early ones and the acute syndrome of radiation are discussed. The difference of radiosensibility observed in mammalian cells and main observable alterations in tissues and organs are commented. ...
A novel process was proposed to synthesize nano Sb-encapsulated pyrolytic polyacrylonitrile composite for anode material in lithium secondary batteries. The preparation started with the dissolution of SbCl{sub 3} and polyacrylonitrile (PAN) in dimethylformamide (DMF) solution, followed by the addition of KBH{sub 4} to reduce Sb{sup 3+} in the solution. The Sb composite was obtained by pyrolysis of the Sb/PAN mixture that precipitated out when the DMF solution was added by plentiful water. The TEM analysis showed that about 100-200 nm Sb particles were embedded by the pyrolyzed PAN, which provided a conductive matrix to relieve the morphological change of Sb during electrochemical cycling. As-prepared composite presented good cycleability for lithium storage. The proposed process paves an effective way to prepare high performance alloy based composite anode materials for high performance lithium-ion batteries. (author)
A method for encapsulating and immobilizing waste for disposal. Waste, preferably, biologically, chemically and radioactively hazardous, and especially electronic wastes, such as circuit boards, are placed in a crucible and heated by microwaves to a temperature in the range of approximately 300{degrees}C to 800{degrees}C to incinerate organic materials, then heated further to a temperature in the range of approximately 1100{degrees}C to 1400{degrees}C at which temperature glass formers present in the waste will cause it to vitrify. Glass formers, such as borosilicate glass, quartz or fiberglass can be added at the start of the process to increase the silicate concentration sufficiently for vitrification.
A major factor for the achievement of the desirable performance, efficiency and lifetime of flexible organic electronic devices is the optimization of the encapsulation layers that protect the device active layers by atmospheric gas molecule permeation. The active layers consisted of small molecule and/or polymer organic semiconductors as well as the organic conductors need to be encapsulated into a transparent medium that will provide the necessary protection and maintain their charge generation and transport characteristics. The encapsulation layers are generally consisted of inorganic thin films (silicon oxide-SiO{sub x} and aluminium oxide-AlO{sub x}) deposited onto the polymeric substrates, such as PolyEthylene Terephthalate (PET). In this work, in situ and real-time Spectroscopic Ellipsometry in the ultraviolet spectral region has been implemented in order to investigate the growth of inorganic SiO{sub x} and AlO{sub ...
The two-fluid model representation for calculations of two-phase flow characteristics in the FBR fuel pin bundles with liquid metal cooling is presented and analysed. Two conservation equations systems of the mass, momentum and energy have been written for each phase. Components accounted the mass-, momentum- and heat transfer throughout the interface occur in the macro-field equations after the averaging procedure realisation. The pattern map and correlations for two-fluid model in vertical liquid metal flows are presented. The description of processes interphase mass- and heat exchange and interphase friction is determined by the two-phase flow regime. The opportunity of the liquid metal two-phase flow regime definition is analysed. (author)
Nuclear approaches for compositional characterization has bright application prospect in forensic perspective towards assessment of nature and origin of seized material. The macro and micro physical properties of nuclear materials can be specifically associated with a process or type of nuclear activity. Under the jurisdiction of nuclear analytical chemistry as well as nuclear forensics, thrust areas of scientific endeavor like determination of radioisotopes, isotopic and mass ratios, analysis for impurity contents, arriving at chemical forms/species and physical parameters play supporting evidence in forensic investigations. The analytical methods developed for this purposes can be used in international safeguards as well for nuclear forensics. Nuclear material seized in nuclear trafficking can be identified and a profile of the nuclear material can be created
Strut lattice structures of reaction-bonded silicon infiltrated silicon carbide ceramics (RB-SiSiC) for air-fuel mixture formation and for nonstationary lean-burn under pressure applications were fabricated. The lattice design with a high porosity >80% was shaped by indirect three-dimensional printing. It was shown that pre-ignition processes in the porous reactor are much faster than in a free combustion, especially at lower temperatures. Interaction of high velocity diesel jets with cylindrical strut ligaments of the SiSiC lattice structure offers a new possibility for quick and efficient fuel distribution (multi-jet splitting) in space.
Laser consolidation (LC) developed by National Research Council???s Industrial Materials Institute (NRC-IMI-London) since mid-1990s, is a laser cladding based rapid manufacturing and material additive process that could fabricate a ???net-shape??? functional metallic shape through a ???layer-upon-layer??? deposition directly from a computer aided design model without using molds or dies. In order to evaluate the LC processability of different materials, some representative nickel-based superalloys (IN-625, IN-718, IN-738, and Waspaloy), stainless steels (austenitic SS316L and martensitic SS420), and lightweight alloys (Ti???6Al???4V titanium alloy and Al-4047 aluminum alloy) have been investigated. Like other laser cladding based processes, due to process-induced rapid directional solidifi...
To investigate the potential causes of changes to bird communities in exurban areas, we examined the relationship between bird and macro invertebrate communities in exurbanized forest. We randomly located sampling points across a gradient of exurbanization. We used point counts to quantify bird communities and sweep netting, soil cores, pitfalls, and frass collectors to quantify macro invertebrates. Bird communities had higher richness and abundance in exurban areas compared to undeveloped forests, and lost some species of conservation concern but gained others. The macro invertebrate community was slightly more abundant in exurban areas, with a slight shift in taxonomic composition. The abundance of macro invertebrates in soil cores (but not pitfalls) predicted the abundance of ground-foraging birds. The abundance of macro invertebrates in sweep nets was not associated with the ...
The {sup 176}Ybn,{gamma}{sup 177}Yb-{beta}{sup -}{yields}{sup 177}Lu process was investigated to provide no-carrier-added (nca) {sup 177}Lu. The radiochemical separation of the {sup 177}Lu from the macro-amounts of the ytterbium target based on the cementation process, i.e. the selective extraction of Yb by Na(Hg) amalgam from Cl{sup -}/CH{sub 3}COO{sup -} electrolytes, followed by a final cation exchange purification. The cementation separation process provides a decontamination factor of Yb(III) of 10{sup 4}, the cation exchange purification adding a decontamination factor of >10{sup 2}. The nca {sup 177}Lu is available in radiochemically pure form despite the chemical similarity of the lanthanides with 75{+-}5% overall separation yield within 4-5 h. It can be used to synthesise nca {sup 177}Lu labelled radiotherapeuticals.
The research for the development of flexible organic electronic devices (FEDs) is rapidly increasing worldwide, since FEDs will change radically several aspects of everyday life. Although there has been considerable progress in the area of flexible inorganic devices (a-Si or solution processed Si), there are numerous advances in the organic (semiconducting, conducting and insulating), inorganic and hybrid (organic-inorganic) materials that exhibit customized properties and stability, and in the synthesis and preparation methods, which are characterized by a significant amount of multidisciplinary efforts. Furthermore, the development and encapsulation of organic electronic devices onto flexible polymeric substrates by large-scale and low-cost roll-to-roll production processes will allow their market implementation in numerous application areas, including displays, lighting, photovoltaics, radio-frequency identification ...
Microgel-clay composite particles were prepared by one-step surfactant-free precipitation polymerization. Laponite nanoparticles present in the reaction mixture become encapsulated during the microgel formation process. Microgel-clay composites based on poly(N-vinylcaprolactam-co-acetoacetoxyethyl methacrylate) containing different amount of incorporated clay nanoparticles were synthesized. The clay content was varied from 2 wt% to 18 wt%. The extremely high incorporation efficiency of the clay nanoparticles into microgels was detected. The size of the hybrid microgels was decreased from 700 nm to 100 nm by increase of the clay concentration in the reaction mixture. Obtained hybrid microgels exhibit negative surface charge and excellent colloidal stability. Microgel-clay composite particle...
A brief overview is given of a report on Emergency Core Cooling Systems (ECCS) Recirculation Reliability Knowledge Base compiled by the International Working Group on ECCS Reliability for the OECD/NEA/CSNI. Four safety issues are identified which arise in the context of loss of coolant accidents (LOCAs) and are connected with materials and/or processes that interfere with the ECCS safety function in ways other than just strainer head loss generation. They are: the generation of missiles during a LOCA from encapsulated insulation materials used to reduce insulation debris production; clogging of BWR pressure suppression containment vent pipes by insulation jackets or metallic insulation foil pieces; strainer or sump debris ingestion and the effects of ingested debris on ECCS equipment and core cooling; miscellaneous items such as material aging and self-cleaning strainer concepts. The emphasis is mainly on BWRs but many of the considerations ...
We have studied the impact of overexpression of an intracellular signaling protein, integrin-linked kinase (ILK), on the survival and function of encapsulated islet tissue used for the treatment of type 1 diabetes. The dimensions of the encapsulated tissue can impact the stresses placed on the tissue and ILK overexpression shows the ability to extend function of dissociated cells as well as intact islets. These results suggest that lost cell-extracellular matrix interactions in cell encapsulation systems can lead to decreased insulin secretion and ILK signaling is a target to overcome this phenomenon. (communication)
The most frequent ultimate cause of death is myocardial arrest. In many cases this is due to myocardial hypoxia, generally arising from failure of the coronary macro- and microcirculation to deliver...Full Text Available
A process and apparatus for solidifying radioactive waste liquid containing dissolved and/or suspended solids is disclosed. The process includes chemically treating for pH adjustement and precipitation of solids, concentrating solids with a thin-film evaporator to provide liquid concentrate containing about 50% solids, and drying the concentrate with heated mixing apparatus. The heated mixing apparatus includes a heated wall and working means for shearing dried concentrate from internal surfaces and subdividing dry concentrate into dry, powdery particles. The working means includes a rotor and helical means for positively advancing the concentrate and resulting dry particles from inlet to outlet of the mixing apparatus. The dry particles may also be encapsulated in a matrix material. Entrained particles in the vapor stream from the evaporator and mixer are removed in an integral particle separator and the vapor is ...
Recently, the Tri-Party Agreement (TPA) among the State of Washington Department of Ecology, U.S. Department of Energy (DOE) and the US Environmental Protection Agency (EPA) for the cleanup of the Hanford Site was renegotiated. The revised agreement specifies vitrification as the encapsulation technology for low level waste (LLW). A demonstration, testing, and evaluation program underway at Westinghouse Hanford Company to identify the best overall melter-system technology available for vitrification of Hanford Site LLW to meet the TPA milestones. Phase I is a {open_quotes}proof of principle{close_quotes} test to demonstrate that a melter system can process a simulated highly alkaline, high nitrate/nitrite content aqueous LLW feed into a glass product of consistent quality. Seven melter vendors were selected for the Phase I evaluation: joule-heated melters from GTS Duratek, Incorporated (GDI); Envitco, Incorporated (EVI); Penberthy Electomelt, ...
A room-temperature process for stabilizing mineral waste streams has been developed, based on acid-base reaction between MgO and H3PO4 or acid phosphate solution. The resulting waste form sets into a hard ceramic in a few hours. In this way, various alumina industry wastes, such as red mud and treated potliner waste, can be solidified into ceramics which can be used as structural materials in waste management and construction industry. Red mud ceramics made by this process were low-porosity materials ({approx}2 vol%) with a compression strength equal to portland cement concrete (4944 psi). Bonding mechanism appears to be result of reactions of boehmite, goethite, and bayerite with the acid solution, and also encapsulation of red mud particles in Mg phosphate matrix. Possible applications include liners for ponds and thickned tailings disposal, dikes for waste ponds, and grouts. Compatability problems arising at the ...
Abstract: The clustered logrank test is a nonparametric method of significance testing for correlated survival data. Examples of its application include cluster randomized trials where groups of patients rather than individuals are randomized to either a treatment or a control intervention. We describe a SAS macro that implements the 2-sample clustered logrank test for data where the entire cluster is randomized to the same treatment group. We discuss the theory and applications behind this test as well as details of the SAS code.
A composition and method for encapsulating a photovoltaic device which minimizes discoloration of the encapsulant. The composition includes an ethylene-vinyl acetate encapsulant, a curing agent, an optional ultraviolet light stabilizer, and/or an optional antioxidant. The curing agent is preferably 1,1-di-(t-butylperoxy)-3,3,5-trimethylcyclohexane; the ultraviolet light stabilizer is bis-(N-octyloxy-tetramethyl) piperidinyl sebacate and the antioxidant is selected from the group consisting of tris (2,4-di-tert-butylphenyl) phosphite, tetrakis methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate) methane, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, and 2,2'-ethylidene bis(4,6-di-t-butylphenyl) fluorophosponite. The composition is applied to a solar cell then cured. The cured product contains a minimal concentration of curing-generated chromophores and resists UV-induced degradation.
This work showed the formation of phospholipid vesicle coating on inorganic sericite surface with characterization by combining electron microscopy of FE-SEM, TEM, AFM, and qualitatively evaluated the coated phospholipid vesicle by XPS as a function of etching time. The possibility of phospholipid vesicle mobility on the surface was restrained by the chelation effect of magnesium cation. The stabilization properties of phospholipid vesicles on sericite surface were demonstrated by the various concentration of magnesium cation. The presence of magnesium was found to have a much more pronounced influence on the lipid deposition process. The Mg cation plays an important role for attaching the phospholipids with optimum concentration of 7 mM. Totally, the phospholipid vesicles coating on inorganic powder could be useful for bio-related fields such as cosmetics and drug delivery system as the key functional compounds. We hope this basic result lead to a general and ...
This Maintenance Implementation Plan (MIP) has been developed for maintenance functions associated with the B Plant/WESF (Waste Encapsulation Storage Facility) complex. The objective of this plan is to provide baseline information for establishing and identifying WHC conformance programs and policies applicable to implementation of DOE order 4330.4B guidelines. In addition, this maintenance plan identifies the actions necessary to develop a cost-effective and efficient maintenance program at B Plant/WESF. The B Plant WESF facility complex consists of three main facilities and several support structures located in the 200 East Area of the Hanford site. B Plant is a transition facility that is required to ensure safe storage and management of WESF (operating facility) cesium and strontium capsules. B Plant/WESF also contains substantial radiological inventory from previous campaigns. There are no production activities at B Plant, but several of its operating systems ...
Different concrete waste packages have been designed by Electricite de France (EDF) for the long-term storage of radioactive Low Level Waste (LLW). Their main function is to confine radionuclides from the biosphere for three hundred years in a near-surface disposal. According to the transport regulations, a Type-B package is needed for some waste like water filters. The water filters from EDF nuclear power plants are encapsulated in mortar and placed in a concrete container. Transport regulations for these containers have required the development of a methodology for safety assessment. The reference scenario of container degradation during transport considers a 9 m drop and a 800"oC fire for 30 min. First, the different chemical and physical processes involved in the containment of radionuclides are analysed. In particular, the radionuclide transport mechanisms in cement-based materials have been reviewed. Secondly, the effects of a container ...
Biomimetic vesicle media which can selectivity extract and concentrate heavy metals (e.g., Pb{sup 2+}) from dilute solutions of 5 ppm and less have been prepared. At a concentration of only 1% 2/v, these non-covalently assembled, unilamellar, surfactant vesicles provide approximately 1,000m{sup 2} of exposed membrane surface area per liter of suspension which gives rise to very rapid rates of metal ion extraction. To facilitate the selective transport of heavy metal ions through the ion impermeable vesicle wall, the vesicles are doped with lipophilic ionophores, both natural and synthetic. In addition, the metal chelating agent, nitrolotriacetate, is encapsulated in the aqueous vesicle core to provide the driving force for metal ion uptake and concentration. Concentration factors in excess of 1000 fold have been observed. Metal-sorbing surfactant vesicles measuring approximately 100 nm in diameter are stable and have been tested in a bench-scale metal ion ...
Dutch-style fermented sausages were manufactured with 15% and 30% pork back-fat substitution by pure or commercial encapsulated fish oil, either added as such or as pre-emulsified mixture with soy protein isolate. Adding commercial encapsulated fish oil was the most important factor influencing the chemical composition. The fat content was not significantly different between products (p>0.05). The n-6/n-3 ratio decreased from 8.49 in controls to 0.90-2.47 in modified products. Lipid oxidation parameters (propanal and hexanal) showed much higher values for sausages with pure fish oil than for products with encapsulated oil. For the latter, lipid oxidation was similar to controls. Products with encapsulated or pre-emulsified oil were significantly firmer than products from other treatments i...
When a plasma becomes contaminated by foreign particles, generically referred to as dust, the result is called a dusty plasma. At the present time there is a great deal of interest in dusty plasmas because of their roles in terrestrial and extra-terrestrial processes - semiconductor processing, high temperature fusion experiments, stellar formation and the rings of Saturn. This thesis is concerned with the role of dust in processing type plasmas. In the following experiments, artificial dust is introduced into a parallel electrode plasma chamber. Ions and electrons in the plasma charge the dust particles and they become suspended in the plasma due to the balancing of electric and gravitational forces. By illuminating the suspended dust with laser light and using an extremely high speed camera fitted with a macro lens to look at the scattered light, the dust particles are observed directly. Specially ...
This article examines social stratification in individual health trajectories for multiple cohorts in the context of China’s dramatically changing macro-social environment. Using data...Full Text Available
It is answered to a previous letter by Basano, and shown that the difficulties met by that author within ''Extended relativity'' do not exist, but are due to the erroneous assumption that a certain condition for tachyons to be absorbed by a macro-object is sufficient (whilst it is only a necessary one).
A laboratory stream consisting of two stream sections interrupted by two pools was filled with a mixture of tap water and organically enriched water from rivers nearby. Bottom sediment material, Potamogeton pectinatus, macro-invertebrate organisms, as well as the mosquito fish, Aplocheilichthys johnstonii were collected from rivers around Johannesburg and introduced into the laboratory stream. After initial acclimatization, the distribution of the isotope "3"2P through this laboratory stream was followed. Absorption of this isotope by benthic algae, Potamogeton pectinatus, several macro-invertebrate organisms as well as Aplocheilichthys johnstonii was recorded.
In the present study 12 diets, each one consisting of a pool of seven day diets, composed by four meals: breakfast, lunch, dinner and snack, adequate in energy and macro nutrients according to the RDA (Recommended Daily Allowance) recommendations, were elaborated and offered to a group of 12 men (19-42 years). The diets were collected by duplicate portion technique and dried by two different processes: freeze drying and 60 deg C ventilated oven drying. In the total, 24 diets were analyzed. The content of some minerals and trace elements (Ca, Fe, Mg, Mn, Na, Se and Zn) were determined by Instrumental Neutron Activation Analysis. The validation of methodology was made by analysis of the reference materials Typical Diet (NIST SRM 1548"a), Orchard Leaves (NIST SRM 1541) and Peach Leaves (NIST SRM 1547). The results observed by two different drying processes used were statistically compared by test T of Student. It was possible ...
Impact of some heavy metals like zinc, lead, copper, chromium and cadmium were studied at four spots on the macro-invertebrate fauna of the Thaddo stream, a tributary of Malir River. This was in correlation with an earlier study on the physico-chemical aspects of water which showed a severe pollution in this stream. Present data for the qualitative and quantitative analyses of macro-invertebrates and the ranges of heavy metals (Zn 0.5-3.5, Pb 0.90-1.42, Cu 0.35-0.93, Cr 0.0-0.08 and Cd 0.003-0.01 ppm) in the water samples also indicate high level of pollution in the stream. Macro-invertebrate fauna comprises only of aquatic insects which include larvae of Chironomus spp., adults of the Notonectus sp., and nymphs of Gomphus sp. (dragon fly) belonging to the order Diptera , Hemiptera and Odonata, respectively. Quantitatively Notonectus sp. predominated and followed by Chironomus larvae. The maximum concentrations of all heavy ...
A typical form of change in runoff characteristics caused by the widespread use of hydroelectric power in Switzerland is the intermittent draining (torrent operation). It is the aim of the present work to help elucidate possible consequences of these changes in drain onto the benthobiocoenosis. The study was carried through on the Secklisbach at Oberrickenbach (in the semicanton of Nidwalden) and one of its side streamlets (800m above sea level). The macroinvertebrate coenosis was studied at four locations with similar conditions of drainage basin, population density and topography but varying in the degree of impairment to the draining. There were monthly benthos samples taken using a Surber sampling-device. Results show that the locations not only varied in drain, but also in temperature, this being a consequence of water storage by the power plant. The readings pointed out different values for the locations in daily average temperature, day amplitudes and half-yearly temperature ...
Full text: Mt Morgan was mined for copper and gold from 1882 to 1982 and subsequent tailings re-processing ceased in 1990. Direct and accidental deposition of tailings into the adjacent Dee River and acid mine drainage from the mine site continues to impact the Dee River. The Queensland Department of Natural Resources gauging and monitoring station at Kenbula (adjacent to the mine) continuously monitors pH of around 2.8. Twenty kilometres downstream of the mine the pH improves to 3.5. Elevated sediment metal concentrations have been recorded over 50 kilometres downstream in investigations conducted by CSIRO (Jones et al. 1995, 1996) and others. Biological monitoring by Mackey (1988) and subsequently by Duivendoorden (1995,1997), confirmed significant impact on the fish, macrophyte of macro invertebrate populations downstream of the mine. The current AINSE sponsored project will investigate the use of mussels (genus Allathryia) to archive the ...
The objective of the investigation was to study the feasibility of applying continuous casting steel 100Cr6 (SAE 52100) for bearing balls. It was found that two of three continuous casted steel batches have longer or at least similar rolling contact fatigue lifetimes compared to one ingot casted batch. For one of the continuous casted batches, the rolling contact fatigue lifetime was 30% less. The micro- and macrostructure and the residual stresses below the surface of the balls were comparable. There is also no obvious difference between the four batches in the metallurgical parameters like contents of oxygen, titanium and sulfur as well as in the distribution of carbides and their network. The reason for the shorter lifetime of one batch finally was found to be due not to the continuous casting process itself. There was a difference in the cross section of the different casting moulds, and by this in the speed of solidification. As a consequence an increased ...
This paper describes an approach to solve air quality problems which frequently occur during iterations of the baseline change process. From a schedule standpoint, it is desirable to perform this evaluation in as short a time as possible while budgetary pressures limit the size of the staff available to do the work. Without a method in place to deal with baseline change proposal requests the environment analysts may not be able to produce the analysis results in the time frame expected. Using a concept called the Rapid Response Air Quality Analysis System (RAAS), the problems of timing and cost become tractable. The system could be adapted to assess other atmospheric pathway impacts, e.g., acoustics or visibility. The air quality analysis system used to perform the EA analysis (EA) for the Salt Repository Project (part of the Civilian Radioactive Waste Management Program), and later to evaluate the consequences of proposed baseline changes, consists of three ...
A method for the study of conjugated polyelectrolyte (CPE) photophysics in solution at the single-molecule level is described. Extended observation times of single polymer molecules are enabled by the...Full Text Available
The DataAccessBean is similar to the Data Access Object (DAO) interface in that the DataAccessBean interface is meant to encapsulate the implementation details of the DynamicJavaBean that accesses persistent storage devices such as RDBMS, flat text file databases, etc.
BackgroundHyaluronic acid capsule plays a key role in Streptococcus pyogenes virulence. Circulation of mucoid or highly encapsulated strains has been related to...Full Text Available
BackgroundWithin the last 25 years, after the introduction of the swimbladder nematode Anguillicoloides crassus from East-Asia to Europe, a body of work has aggregated...Full Text Available
A a result of its former role as a producer of nuclear weapons components, the Rocky Flats Environmental Technology Site (RFETS), Golden, Colorado accumulated a variety of plutonium-contaminated materials. When the level of contamination exceeded a predetermined level (the economic discard limit), the materials were classified as residues rather than waste and were stored for later recovery of the plutonium. Although large quantities of residues were processed, others, primarily those more difficult to process, remain in storage at the site. It is planned for the residues with lower concentrations of plutonium to be disposed of as wastes at an appropriate disposal facility, probably the Waste Isolation Pilot Plant (WIPP). Because the plutonium concentration is too high or because the physical or chemical form would be difficult to get into a form acceptable to WIPP, it may not be possible to dispose of a portion of the residues at WIPP. The ...
Encapsulation of technetium-99m sestamibi ({sup 99m}Tc-MIBI) in polyethyleneglycol-liposomes ({sup 99m}Tc-MIBI-PEG-liposomes) could extend the duration of its circulation in blood and alter its biodistribution, enabling its concentration in tumours to be increased. An original method to encapsulate {sup 99m}Tc-MIBI in PEG-liposomes is described. The {sup 99m}Tc-MIBI-PEG-liposomes were compared with free {sup 99m}Tc-MIBI with respect to (a) tumour availability (b) ability to distinguish between chemotherapy-sensitive and -resistant cells and (c) uptake ratio in tumour imaging. PEG-liposomal systems composed of distearoylphosphatidylcholine/cholesterol/PEG{sub 2000}-distearoyl phosphatidylethanolamine and lissamine-rhodamine B-labelled liposomes were used. The encapsulation of {sup 99m}Tc-MIBI in liposomes was achieved using the K{sup +} diffusion potential method. We compared the uptake of free versus ...
Specific structure of biota community condition can used as indicator for the ecosystem stability value or the waters pollution level where the aquatic biota exist. the macro invertebrates as bio indicator organism can used to assess the upper Cisadane Sub River Basin water quality. The grouping and calculation result from family number, Ept presences (sensitive macro invertebrate), Diversity index (H"'), DO value and TOC value showed 5 criteria of water quality as reference site. This criteria is used to determine water quality level from ten branches of rivers in the upper Cisadane Sub River Basin, Cijeruk districts. The biotic index calculation for ASPT (Average Score Per Taxon) and T and T (index Trihadiningrum and Tjindronegoro) is used to asses water quality based on macro invertebrate composition indicator. Both biotic index system support and give the similar evaluation to water quality level from ten branches of ...
This study evaluates the correlation between transplanted Asiatic clam and indigenous community responses to acid mine drainage and nutrient loading in first-to-third-order streams, by comparing the toxicological endpoints of clam survival and growth with benthic macro-invertebrate community indices as community responses to both acid mine drainage and nutrient loading. Clam survival was found to be positively correlated with water column pH and negatively correlated with conductivity and metal concentrations. There was also a positive correlation with the relative abundance of the macro-invertebrate Ephemeroptera, the most sensitive taxonomic group, to acid mine drainage in this watershed. No correlation was found between clam growth and acid mine drainage inputs, but there was evidence of positive correlation with nitrate concentrations and the relative abundance of collector-filterer functional feeding groups. These results suggest that clam ...
A high power Free-Electron Laser (FEL) has lased at a wavelength of 22 #mu#m at the Japan Atomic Energy Research Institute (JAERI). The maximum power on a macro-pulse average is 1.7 kW, and it corresponds to an FEL energy of 160 #mu#J/micro-pulse. Extraction efficiency from the electron beam to the FEL radiation was measured to be 5.3% by an energy analyzer, when the maximum FEL power was coupled out. The rms wavelength spread was measured to be 4.6% at the same time. The extraction efficiency, in general, has a maximum value near the zero detuning length of an optical cavity, where (in contrast) the single-pass gain becomes smallest. A high peak current and a long macro-pulse duration are therefore indispensable for realizing high efficiency. The electron beam energy is 16.5 MeV, and the average current is 5.3 mA at a micro-pulse repetition rate of 10.4 MHz. The macro-pulse duration is 500 #mu#s (5000 micro-pulses), long ...
Successful interface engineering requires compositional and electronic material characterization as a prerequisite for understanding and intentionally generating interfaces in photovoltaic devices. The paper gives an overview with several examples, all referring to Cu(In,Ga)(S,Se){sub 2} ('CIGSSe')-based solar cells, with an emphasis on characterization using highly specialized methods, such as elastic recoil detection analysis, X-ray emission spectroscopy and photoelectron spectroscopy using synchrotron and ultraviolet light for excitation, inverse photoemission spectroscopy and Kelvin probe force microscopy. First, the determination of the depth profile of the band gap energy E{sub g} in the absorber layer is demonstrated. The modification of E{sub g} towards both interfaces is discussed in terms of beneficial electronic effects. Next, the interface between absorber and buffer layers with alternative and promising non-toxic materials is considered. Between CIGSSe ...
Two methods, a traditional emulsion technique and a high voltage electrostatically modified encapsulation system, were used to fabricate degradable chitosan/beta -tricalcium phosphate (beta-TCP) microspheres. The two distinct kinds of microspheres both exhibited good sphericity and the beta-TCP was trapped well inside the chitosan gel. The microspheres prepared by high voltage electrostatic system exhibited a rougher outer surface and narrower size distribution. These microspheres were then used as an added constituent to commercially available PMMA bone cement. Four modified cement composites that were prepared with different composition ratios of the two kinds of chitosan/beta-TCP microspheres that were made from emulsion technique (C1P1 and C2P1) and from a process by a high voltage electrostatic system (EC1P1 and EC2P1) were compared with the PMMA cement (Pure P). The characteristics of these materials indicate that with the addition of ...
The relationship between microstructure and macro properties of different cementitious materials has been investigated. This study consists of the following tasks: using NMR and IR to better characterize the amorphous and poorly crystalline phases that occur in blended cements; characterizing the microstructure of the hydration products of modified Portland cement as a function of different percentages of pozzolan replacements by ESEM, SEM, and EDS; comparing the properties of blended cement pastes with a control group of normal Portland cements; and studying the engineering aspects of blended cement that are important for identifying and characterizing fundamental phenomena that are responsible for their durability. The overall influence of the nanoscale and microscale structure of blended and Portland cement on the properties of the resultant composite will be discussed.
Wind power is a maturing technology that in a number of countries is likely to contribute a major share to fully renewable energy systems. Denmark has a comparably long history of wind power development and is planning to continue expanding the existing capacity. If a large-scale penetration of wind power is to be achieved, an integrated framework is needed that can respond to the associated challenges. This paper argues for adopting an integrated macro perspective when evaluating and building frameworks to support wind power development. This macro perspective is applied to the case of Denmark, and more specifically to concrete wind power projects in the region of Northern Jutland. The results suggest although certain elements in the legislation have been improved, the feasibility of wind power projects cannot be guaranteed, and there is a tendency to exclude smaller turbines from the development.
Most countries worldwide nowadays apply Environmental Assessment (EA) as an ex ante tool to evaluate environmental impacts of policies, plans, programmes, and projects. However, the application and performance of EA differ significantly. Scientific analysis of how EA performs mainly focuses on two levels: the micro (or project) level and the macro (or system) level. Macro level analysis usually focuses on institutions for EA and the organisation of stakeholder interaction in EA. This article proposes a more comprehensive framework for analysing EA systems that combines other approaches with a capacity approach and an explicit consideration of the context in which EA systems are developed and performed. In order to illustrate the value of our framework, we apply it to the Republic of Yemen,...
With an increased use of fiber reinforced concrete in structural applications, proper characterization techniques and development of design guides are needed. This dissertation presents a multi-scale modeling approach for fiber and fabric reinforced cement-based composites. A micromechanics-based model of the yarn pullout mechanism due to the failure of the interfacial zone is presented. The effect of mechanical anchorage of transverse yarns is simulated using nonlinear spring elements. The yarn pullout mechanism was used in a meso-scale modeling approach to simulate the yarn bridging force in the crack evolution process. The tensile stress-strain response of a tension specimen that experiences distributed cracking can be simulated using a generalized finite difference approach. The stiffness degradation, tension stiffening, crack spacing evolution, and crack width characteristics of cement composites can be derived using matrix, interface and fiber properties. The ...
Full text: Dissolution test (DT) is one of the important specifications of PFBR MOX fuel. It is a macro homogeneity test used to ascertain that the dissolution of spent fuel will be easier during reprocessing. The DT specification limit for PFBR MOX fuel is ? 1.0 wt.% residue of the whole pellet when it is dissolved in HNO3 under reflux conditions. For this test, sintered MOX pellet is dissolved in reflux condition in 60 ml of 12M HNO3 for 10 hours. This test is carried out for each batch and during complete MOX campaign a lot of MOX waste in liquid form is being generated. This liquid waste is in clean form and U and Pu is required to be recovered from the clean waste. Different methods like direct denitration, precipitation and solvent extraction are available but either the product is not of good quality for pelletization or secondary liquid wastes are generated. Microwave denitration is a faster and cleaner method which has different heat transfer mechanism and ...
This document presents our proposal to continue the activities of Boston University researchers in eight projects in high energy physics research: Colliding Beams Physics; Accelerator Design Physics; MACRO Project; Proton Decay Project; Theoretical Particle Physics; Muon G-2 Project; and Hadron Collider Physics. The scope of each of these projects is presented in detail in this paper.
Technology of plasma sputtering, structure and properties of zirconium dioxide coatings were studied. Necessity of void number increase to enhance coating heat-resistance is shown. Optimal powder particle size (20-60 #mu#m) providing optimal coating porosity was determined. Weight part of stabilizating oxide (Y_2O_3) in ZrO_2 for formation in coating of microcracks serving as barriers for macro-cracks propagation was determined.
...] gueconwpa~05-05-05 How is Macro News Transmitted to Exchange Rates? (December 2003) by Martin D. D. Evans(Georgetown University and NBER) and Richard K. Lyons(U.C. Berkeley and NBER, Haas School of Business) [Downloadable!] gueconwpa~05-05-04 A New Micro Model of Exchange Rate Dynamics (March 2004) by Martin D. D. Evans(Georgetown University and ...
Scenario analyses are described here using the Global MARKAL-Macro Trade (GMMT) model to study the economic implications of the Kyoto Protocol to the UN Convention on Climate change. Some conclusions are derived in terms of efficient implementations of the post-Kyoto extensions of the Protocol. (author) 2 figs., 5 refs.
An approach to solving the problem of managerial control quality improvement corporate information-calculating networks (CICN) is proposed. The approach is based on the concept of a flexible toolkit. A macro-model, system-science and system-engineering models of an intelligent managerial control system (IMCS) for CICN development are considered as well as its dynamics. The practical opportunity of IMCS implementation is assessed. (5 refs).
This Phase 1 final report covers the work performed by Springborn Testing and Research, Inc., for the period October 1, 1997 to June 30, 1998 under the Department of Energy Cooperative Agreement Number DE-FC36-97GO10255, entitled Development of Flame Retardant PV Module Encapsulants. While use of roof-mounted arrays has always been an attractive means of deploying PV, only within recent years have such building integrated concepts (BIPV) found renewed interest among module makers and end-users. Prior to building integrated and rooftop applications, flammability requirements for modules have not been a great industry concern. However, with growing interest in BIPV and the requirement for building code requirements for commercial and industrial structures, flammability issues have become a barrier to entry for many module constructions into this potentially huge domestic market for PV. The overall goal of the 3 phase PV BONUS two project is to develop and ...
It has been acknowledged that river morphology and hydrology have been intensively altered due to the anthropic demands in floodplain land use and management, flood protection, promotion of navigability or energy production. Rivers were transformed in water highways, having lost contact with their surrounding floodplain as well as the plethora of ecological processes and occupants once thriving in these ecotonal zones. The identification of this emerging threat of morphological and hydrological alteration on ecological integrity adds further complexity in the exploitation of hydrosystem resources. These resources are heavily coveted and guarded by different lobbies each having strategic views on future project development. Stakeholders may want to promote hydro-electricity, ecologists a natural reserve, communes may wish to have an increased flood protection and leisure promoters a nautical center. As a result, the proposition of a river development project is ...
In this work, a mixed cationic--anionic [i.e. cetyltrimethylammonium bromide-sodium octyl sulphate] surfactant system was used to synthesize the magnetite particles. The loading content of iron ions (Fe{sup 3+} and Fe{sup 2+}) into the surfactant system was varied to study its effect on the formation of magnetite, magnetic and morphological properties of the magnetite particles encapsulated by the surfactant vesicles. It has been verified that the vesicle-encapsulated magnetite particles with sizes from 100 to 200 nm were formed, which were almost independent of the loading content of iron ions. However, the morphological structure of the magnetite particles was dependent on the loading content of iron ions and there existed an optimal loading content for a full packing of the surfactant vesicles with the magnetite particles.
In this work, a mixed cationic--anionic [i.e. cetyltrimethylammonium bromide-sodium octyl sulphate] surfactant system was used to synthesize the magnetite particles. The loading content of iron ions (Fe"3"+ and Fe"2"+) into the surfactant system was varied to study its effect on the formation of magnetite, magnetic and morphological properties of the magnetite particles encapsulated by the surfactant vesicles. It has been verified that the vesicle-encapsulated magnetite particles with sizes from 100 to 200 nm were formed, which were almost independent of the loading content of iron ions. However, the morphological structure of the magnetite particles was dependent on the loading content of iron ions and there existed an optimal loading content for a full packing of the surfactant vesicles with the magnetite particles.
Encapsulation of a unique isotopic blend of krypton and xenon gas employs a special application of laser technology. The encapsulated gas is then used as the primary medium for detection and identification of failed nuclear fuel rods. The use of gas tagging as a means of detecting and identifying failed nuclear fuel rods has been successfully demonstrated and used by the Argonne National Laboratory, Experimental Breeder Reactor (EBR-2) Project, and the Westinghouse Hanford Company (WHC), Fast Flux Test Facility (FFTF) Fast Breeder Reactor Program. The Power Reactor and Nuclear Fuel Development Corporation (PNC) of Japan has selected this leak detection system for use in their MONJU Prototype Reactor fuel assemblies. The MONJU reactor is almost identical in design to the highly successful FFTF reactor, which is currently in standby status.
This paper describes the Knowledge Encapsulation Framework (KEF), a suite of tools to enable knowledge inputs (relevant, domain-specific facts) to modeling and simulation projects, as well as other domains that require effective collaborative workspaces for knowledge-based task. This framework can be used to capture evidence (e.g., trusted material such as journal articles and government reports), discover new evidence (covering both trusted and social media), enable discussions surrounding domain-specific topics and provide automatically generated semantic annotations for improved corpus investigation. The current KEF implementation is presented within a wiki environment, providing a simple but powerful collaborative space for team members to review, annotate, discuss and align evidence with their modeling frameworks. The novelty in this approach lies in the combination of automatically tagged and user-vetted resources, which increases user trust in the ...
In Streptococcus pneumoniae, CpsB, CpsC, and CpsD are essential for encapsulation, and mutants containing deletions of cpsB, cpsC, or cpsD...Full Text Available
The complete nucleotide sequence of the cap3A gene of Streptococcus pneumoniae, which is directly responsible for the transformation of some unencapsulated, serotype 3 mutants to the encapsulated phenotype,...Full Text Available
Accelerated aging tests have been conducted to evaluate the long-term durability of cementitious material against aggressive ions. In tests, cementitious specimens were immersed in the solutions containing concentrated aggressive ions at high temperature and it promoted diffusion of the ions in the specimen. This method would be suitable for the evaluation on the aging as the alteration of the specimen would be expected to resemble the natural behavior. This paper presents a classification of alteration mechanism in the immersion tests using MgCl{sub 2} and Na{sub 2}SO{sub 4} solution. This classification was done by relating the changes of compressive strength to microscopic and mineralogical changes.
The tips and tools in Excel Hacks include little known backdoor" adjustments for everything from reducing workbook and worksheet frustration to hacking built-in features such as pivot tables, charts, formulas and functions, and even the macro language. This resourceful, roll-up-your-sleeves guide shows you new ways to make Excel do things--from data analysis to worksheet management to import/export--that you never thought possible. Excel Hacks increases productivity with Excel and gives you hours of "hacking" enjoyment along the way. "
Purpose - The purpose of this paper is to elicit the subtle but progressive shift in organizational/institutional interaction with its rivals within a competitive framework, and thereby discusses and analyses paradigm shifts in competition and competitiveness. The paper argues that interorganizational networks and the recent concept of supply chain management may have induced a change in how competitiveness is viewed at the national, industry, and firm levels of interaction. Design/methodology/approach - The paper conceptualizes extant literature into distinct themes of (organizational and institutional) analysis - micro, macro, and meso - and based on this review the paper seeks to identify emerging logics and shifts within mainstream competitiveness literature over the last decade. Findi...
Recently Basano (Int. J. Theor. Phys.; 16:715 (1977)) in a paper entitled 'Information Flow, Causality and the Classical Theory of Tachyons' commented on earlier work by the present authors. In answer to those comments it is pointed out that although 'Extended Relativity' seems to allow one to solve any causal paradoxes with both usual particles and tachyons nevertheless a number of paradoxes are continuously proposed. It has already been shown by the authors that tachyons possibly do not imply any causality violations even in macro-physics but Basano claimed that the procedure lead to new, different paradoxes. It is here demonstrated that such presumed difficulties do not exist. (U.K.).
Gadolinium nitrate has been employed in Indian nuclear reactors for the first time as soluble neutron poison in the heavy water moderators of the 540 MWe PHWRs TAPS 3 and 4, as a fast acting secondary shut down system (SDS-2); and also for reactivity shim. For this purpose, the moderator purification system is currently equipped with special ion-exchange columns/schemes, developed by present authors. However, for gadolinium removal from moderator in the post SDS-2 scenario, the two stage ion-exchange - cation bed operation followed by mixed bed operation - results in low pH conditions persisting in the moderator for a few hours, which gives rise to certain operational problems. The present paper describes a mixed bed ion-exchange scheme employing macro-porous strong acid cation and macro-porous weak base anion resins, which has been developed to eliminate acidic conditions and gives a better pH control. The cation to anion capacity ratio in the ...
Reaction between [V^I^VO(acac)2] and the ONN donor Schiff base Hpydx-aepy (I) (Hpydx-aepy=Schiff base obtained by the condensation of pyridoxal and 2-aminoethylpyridine) resulted in the formation of a complex [V^I^VO(acac)(pydx-aepy)] (1). Addition of aqueous 30% H2O2 to 1 yields the poor stable oxidoperoxidovanadium(V) complex [V^VO(O2)(pydx-aepy)] (2). Its formation has also been demonstrated in solution by treating 1 with H2O2 in methanol. Reaction of vanadium exchanged zeolite-Y with I in methanol followed by aerial oxidation gave zeolite-Y encapsulated dioxidovanadium(V) complex, abbreviated as [V^VO2(pydx-aepy)]-Y (4). The crystal and molecular structure of 1 has been determined, confirming the ONN binding mode of the ligand. The encapsulated complex [V^VO2(pydx-aepy)]-Y (4) catalyse...
Antitumor platinum(II) complexes derived from N-alkyl-propanediamine differing in the length of their carbon chain (C8, C10, C12 and C14) were incorporated in liposomes and the cytotoxic activity of these formulations was evaluated against tumor (A{sub 549}, MDA-MB-231, B16-F1 and B16-F10) and non-tumor (BHK-21 and CHO) cell lines. Stable and monodisperse liposome suspensions incorporating the platinum complexes were obtained from the lipid composition consisting of distearoyl-sn-glycero-3-phosphocholine, cholesterol and 1,2-distearoyl-sn-glycero- 3-phosphoethanolamine-N-(methoxy(polyethylene glycol)-2000) at 5:3:0.3 molar ratio. The entrapment efficiency (EE%) of the platinum complexes in liposomes increased with the carbon chain length. EE% was higher than 80% in C12- and C14-derivatives. The effect of liposome encapsulation on the cytotoxic activity of the complexes was found to depend on the carbon chain length. These data indicate that the highest drug ...
Mixed Uranium Plutonium Carbide ((U, Pu) C), in the form of pellets encapsulated in stainless steel tubes is the fuel for Fast Breeder Test Reactor (FBTR) at Kalpakkam. For the fabrication of fuel for enlarging the core of this reactor, high burn up plutonium is used. The external exposure in these labs was significantly higher than that with low burn up Pu fuel. Dose evaluation to the organs was carried out using experimental TLDs during various operations of FBTR fuel fabrication to study the dose distribution pattern. (author)
In the context of safety assessment of radioactive waste repositories, complex radionuclide transport models covering key safety-relevant processes play a major role. In recent Swiss safety assessments, such as Kristallin-I, an important drawback was the limitation in geosphere modelling capability to account for geosphere heterogeneities. In marked contrast to this limitation in modelling capabilities, great effort has been put into investigating the heterogeneity of the geosphere as it impacts on hydrology. Structural geological methods have been used to look at the geometry of the flow paths on a small scale and the diffusion and sorption properties of different rock materials have been investigated. This huge amount of information could however be only partially applied in geosphere transport modelling. To make use of these investigations the 'PICNIC project' was established as a joint cooperation of PSI/Nagra and QuantiSci to provide a new ...
It was developed a new formulation of macro aggregates of Samarium 153 ({sup 153} Sm-MH) for the arthropaties treatment. The radio pharmaceutic was prepared by reaction of Samarium 153 chloride (SmCl{sub 3}) in aqueous environment with sodium boron hydride in NaOH 0.5 N. The microscopic analysis shown that the particles have an average size of 4% m (range 1-14 {mu} m). The velocity of sedimentation was 0.008 cm/min with high stability in vitro in human serum. The biological studies in healthy rabbits, shown that the complex is retained inside the articulation still eight days after of the administration of the radiopharmaceutical. Likewise, it is presented the data of absorbed dose in the different target organs, which was determined by thermoluminescent dosimetry (TLD) through the use of a REMCAL phantom (radiation equivalent manikin calibration). (Author)
Thin films of Ni and Ni alloy have been widely used in microelectromechanical systems (MEMS) and magnetic storage systems. As the dimensions of components in these systems decrease to the micro-scale, even the nano-scale, the interfacial phenomena significantly differ to the counterparts on the macro-scale. A better understanding of micro-/nano-tribology will benefit the fabrication of the small components. In this manuscript parallel molecular dynamics (MD) simulations have been conducted to investigate the nanoscratch behavior of nickel. The simulations are performed for two cases with different indenter shapes. Case I has a sharp indenter, while the indenter in Case II is blunt. It has been found that the indenter shape significantly influences the nanoscratch deformation. The sharp ind...
The microstructural evolution of a AZ31 Mg alloy during hot rolling has been investigated using optical microscopy and texture (macro and micro) analysis as the main characterization tools. In particular, the differences between the microstructure obtained by unidirectional rolling (UR) and cross rolling (CR) are studied. Significant twinning activity is observed in both cases. Additionally, after cross rolling, a rather heterogeneous microstructure develops, with scattered regions populated by very fine grains. The strong basal fiber texture of the as-received material remains present after both hot rolling schemes. The impossibility to obtain accurate EBSD measurements within the twinned regions suggests that significant localized deformation takes place in those areas. Thus, these regions become preferential sites for the onset of recrystallization due to the increase in the local strain energy. (orig.)
Abstract Within the framework of the CRC 799 -TRIP-Matrix-Composites- at the TU Bergakademie Freiberg new composite materials consisting of TRIP steel and zirconium dioxide ceramics are designed in a powder route and a casting route. To manufacture faultless samples basic investigations of the feeding and infiltration behaviour within macro porous ceramics such as filters were needed. The effects of bottom pouring and top pouring were investigated as well as the effects of different preheating temperatures, contents of phosphorous in the steel and flow trough rates. Bottom pouring corrupts the feeding mainly of filters with high ppi (pores per inch). Top pouring improves the feeding, but generates inhomogeneous infiltration qualities, which can affected and enhanced by a increasing preheat...
The postulate that negative-energy particles do not exist (travelling forward in time) leads automatically to the 'Reinterpretation Principle' by Stueckelberg and by Feynman. It has been already shown that such a 'principle', assumed as the Third postulate of special relativity, ensures the validity of the law of (retarded) casuality both in standard relativity and in (extended) relativity with tachyons and with Superluminal inertial frames. Our Thir postulate, moreover, allows predicting antiparticle existence in a purely relativistic context. In this paper it is shown that the Third postulate is enough to implement the law of casuality even in macrophysics, when usual macro-objects interact with micro-tachyons and macrotachyons. To that aim, some tachyon kinematics is further developed, which can be useful even in understanding elementary-particle interactions (and may be hadron structure). Many other related problems are discussed.
A series of cyclic voltammetry, chronoamperometry and electrochemical impedance experiments have been carried out in order to investigate the effect of cathode composition and porosity on the electrochemical characteristics of strontium-doped lanthanum, praseodymium and gadolinium cobaltite cathodes. The impedance responses at different electrode potentials of the half cell and symmetric single cell setups are compared and analyzed by the equivalent circuit modeling method. The deconvolution of impedance spectra for single cell cathode and anode reactions contributions based on the results of simultaneous analysis of half cells and symmetric single cells has been made by differential impedance real part vs. ac frequency plot analysis method. Noticeable influence of cathode chemical composition, meso-porosity and macro-porosity on the electrochemical activity of the oxygen electroreduction has been demonstrated. Seeming activation energy values have been calculated ...
Lupinus albus L. plants were grown from seeds and irradiated at various stages of development with acute or chronic gamma rays. All plants were greenhouse grown (pre- and post-irradiation) and allowed to proceed through their normal growth cycle. The purpose of these experiments was to establish a Plactochron Index for Lupinus albus L. and to determine the effects of acute and chronic irradiation on development at the macro and microscopic levels. A Plastochron Index was calculated and used as an indirect time scale to evaluate the effects of gamma rays from a common base line. Acute radiation treatment lasted for a period of a few days, whereas chronic treatment was initiated at the seedling stage and lasted for the entire growth season. Vegetative plants were used to study the effects of acute radiation exposure on apical meristem morphology, Plastochron Index, phyllatoxis and gross morphology.
Leafy samples often used as medicine in the Indian Ayurvedic system and vegetables were analyzed for 20 elements (As, Ba, Br, Ca, Ce, Cr, Cs, Co, Eu, Fe, K, La, Na, Rb, Sb, Sc, Sm, Sr, Th, Zn) by employing Instrumental Neutron Activation Analysis (INAA). The samples were irradiated at the 100 kW TRIGA-MAINZ nuclear reactor and the induced activities were counted by gamma ray spectrometry using an efficiency calibrated high resolution High Purity Germanium (HPGe) detector. The concentration of the elements in the medicinal and vegetable leaves and their biological effects on human beings are discussed.
The study was conducted during 2000 to determine the role of various chemical plant factors viz., total minerals, nitrogen, fat contents, carbohydrate, macro an micro nutrients in the leaves of five genotypes of sugarcane i.e., BF-162, SPSG-26, L-118, CP-43/33 and CP-72/2086 by correlating the infestation of top borer, Scirpophaga Nivella F. at tillering stage. None of the genotype was found completely resistant to the pest. CP-43/33 and BF-162 proved susceptible and resistant varieties, respectively. Total mineral, manganese and copper contents did not show significant correlation with the pest infestation, whereas nitrogen, potassium, calcium, magnesium and ferrous contents played a positive and significant role. Phosphorous, carbohydrates, fats and zinc contents played a significant and negative effect on the pest infestation at tillering stage. (author)
BACKGROUND: Calibration by inverse modelling was performed with the MACRO transport and fate model using long-term (>10 years) drainflow and isoproturon (IPU) data from western France. Two lack-of-fit (LOF) indices were used to control the inverse modelling: sum of squares (SS) and an alternative statistic called the vertical-horizontal distance integrator (VHDI), which is designed to account for offsets in observed and predicted arrival times of peak IPU concentration. With these data, SS was artificially inflated because it is limited to comparison of predicted and observed IPU concentrations that are concurrent in time. The LOFs were used along with the index of agreement (d) and the correlation coefficient (r) to ascertain the fit of the calibrated models. RESULTS: Predicted arrival ti...
The possibility of electrochemical corrosion of carbon steel at the rate of 3.25 x 10"-"5 A/cm"2 in water was examined under the conditions present during an accidental pipe rupture at the Mihama nuclear power plant: liquid conductivity, 7.5 #mu#S/cm; dissolved oxygen concentration, 5 ppb or less; pH 8.6#propor to#9.3; ferrous ion concentration, 20 ppb or less; temperature, 142 C. The corrosion rate of iron in a micro-cell with a dissolved oxygen reduction cathode was estimated to be only 1/400 of the preceding rate. On the other hand, that in a micro-cell with a hydrogen ion reduction cathode was estimated to be as high as 1/10 of the preceding rate, that is, 3.25 x 10"-"6 A/cm"2. Two important factors may have influenced the corrosion rate: the remarkable wall thinning, which must have been the direct cause of the rupture of the pipe, was located close to, and downstream from, an orifice; and, the water temperature was in the range at which carbon steel makes a transition from the ...
Fatty acids such as stearic acid (SA), palmitic acid (PA), myristic acid (MA), and lauric acid (LA) are promising phase change materials (PCMs) for latent heat thermal energy storage (LHTES) applications, but high cost is the most drawback which limits the utility area of them in thermal energy storage. The use of fatty acids as form-stable PCM will increase their feasibilities in practical LHTES applications due to reduced cost of the energy storage system. In this regard, a series of fatty acid/poly(methyl methacrylate) (PMMA) blends, SA/PMMA, PA/PMMA, MA/PMMA, and LA/PMMA were prepared as new kinds of form-stable PCMs by encapsulation of fatty acids into PMMA which acts as supporting material. The blends were prepared at different mass fractions of fatty acids (50, 60, 70, 80, and 90% w/w) to reach maximum encapsulation ratio. All blends were subjected to leakage test by heating the blends over the melting temperature of the PCM. The blends ...
The infrared spectrum of the rotovibrational band {ital v}=0{r_arrow}2 of parahydrogen has been observed in the condensed phases down to {ital T}=2 K. In the solid, phonon and roton sidebands exhibit peaks corresponding to those observed in the fundamental. Contributions arising from the reorientation of ortho-H{sub 2} impurities have been detected. The {ital Q}{sub 1}(0)+{ital S}{sub 1}(0) band has been resolved into an asymmetric doublet, and the origin of this latter is discussed. In the liquid phase the observed line shapes include strong translational contributions, and are accounted for by assuming that at short times the excited molecule is encapsulated in the cage of nearest neighbors.
Presented are the results from a laboratory test program conducted to identify and evaluate materials for converting hazardous geothermal residues to a non-hazardous and potentially usable form. Results indicate that the residues can be effectively incorporated, as a fine aggregate, into portland cement-based composites. Five geothermal residues obtained from sites in the Salton Sea area of California were evaluated. Three of these were classified as hazardous. After mixing with cement, the leach rates were all well below specified levels. Although structural-grade composites were produced, gradual reductions in properties with time up to 1 yr were noted. This indicates ongoing chemical reactions between the cement paste and the constituents of the residues. Further research is necessary before the composites could be considered for use in structural applications. 3 refs., 8 tabs.
Today, component oriented middlewares are used to design, develop and deploy easily distributed applications, by ensuring the heterogeneity, interoperability, and reuse of the software modules, and the separation between the business code encapsulated in the components and the system code managed by the containers. Several standards answer this definition such as: CCM (CORBA Component Model), EJB (Enterprise Java Beans) and .Net. However these standards offer a limited and fixed number of system services, removing any possibility to add system services or to reconfigure dynamically the middleware. Our works propose mechanisms to add and to adapt dynamically the system services, based on a reconfiguration language which is dynamically adaptable to the need of the reconfiguration, and on a tool of dynamic reconfiguration, a prototype was achieved for the OpenCCM platform, that is an implementation of the CCM specification. This work was partially financed by the ...
Nuclear power has been considered for space applications since the 1960s. Between 1955 and 1972 the US built and tested over twenty nuclear reactors/ rocket-engines in the Rover/NERVA programs. However, changes in environmental laws may make the redevelopment of the nuclear rocket more difficult. Recent advances in fuel fabrication and testing options indicate that a nuclear rocket with a fuel form significantly different from NERVA may be needed to ensure public support. The Center for Space Nuclear Research (CSNR) is pursuing development of tungsten based fuels for use in a NTR, for a surface power reactor, and to encapsulate radioisotope power sources. The CSNR Summer Fellows program has investigated the feasibility of several missions enabled by the NTR. The potential mission benefits of a nuclear rocket, historical achievements of the previous programs, and recent investigations into alternatives in design and materials for future systems will be discussed.
Abstract Entrapping inclusion complexes in liposomes has been proposed to increase the entrapment efficiency (EE) and stability of liposomes compared with conventional liposomes. In the present study, a stable honokiol-in-hydroxypropyl--cyclodextrin-in-liposome (honokiol-in-HP--CD-in-liposome) was developed as honokiol delivery system by a novel method. The final molar ratio of honokiol/HP--CD/lipid was selected as 1:2:2. The mean particle size was 123.5 nm, the zeta potential was -25.6 mV, and the EE was 91.09 2.76%. The release profile in vitro demonstrated that honokiol is released from honokiol-in-HP--CD-in-liposome with a sustained and slow speed. Crystallographic study indicated that honokiol was first bound within HP--CD and then the inclusion complex was encapsulated within liposom...
The photocytotoxic effect of hypericin (Hyp) targeted by two different delivery techniques, namely, liposomes and anti-hepatocyte specific antigen (anti-HSA) was investigated. Optical absorption and steady-state fluorescence were used to analyze the conjugation of Hyp with anti-HSA model and to evaluate the encapsulation capacity and drug release in a liposome model. Particle size and thermal analysis of the prepared liposomes were performed using laser-light scattering and differential scanning calorimetry (DSC), respectively. Viability study of HepG2 cells exposed to Hyp in the two delivery systems, in the dark and following visible light irradiation, was performed in comparison to free Hyp. The intracellular uptake and localization of Hyp in HepG2 cells were analyzed by means of spectro...
This paper investigates the phase change behavior of 65 mol% capric acid and 35 mol% lauric acid, calcium chloride hexahydrate, n-octadecane, n-hexadecane, and n-eicosane inside spherical enclosures to identify a suitable heat storage material. Analytical models are developed for solidification and melting of sphere with conduction, natural convection, and heat generation. Both the models are validated with previous experimental studies. Good agreement was found between the analytical predictions and experimental study and the deviations were lesser than 20%. Heat flux release at the wall, cumulative energy release to the external fluid, are revealed for the best PCM. The influence of the size of encapsulation, initial temperature of the PCM, the external fluid temperature on solidified and molten mass fraction, and the total phase change time are also investigated. (author)
Copper complexes of the amino acids histidine, arginine and lysine have been introduced into the supercages of zeolite Y and, for the first time, into the large intracrystalline cavities of zeolites EMT and MCM-22. The resulting host/guest compounds are characterized by X-ray powder diffraction, UV/VIS-spectroscopy in the diffuse reflectance mode and by catalytic tests in the liquid-phase oxidation of aromatic alcohols (viz. benzyl alcohol, 2- and 3-methylbenzyl alcohol and 2,5-dimethylbenzyl alcohol) with tertiary-butylhydroperoxide as oxidant. It was observed that intracrystalline copper-amino acid complexes possess remarkable catalytic activity, yielding the corresponding aromatic aldehydes and acids. (orig.)
In 2009, following approval of the European Marine Strategy Framework Directive (MSFD, 2008/56/EC), the European Commission (EC) created task groups to develop guidance for eleven quality descriptors that form the basis for evaluating ecosystem function. The objective was to provide European countries with practical guidelines for implementing the MSFD, and to produce a Commission Decision that encapsulated key points of the work in a legal framework. This paper presents a review of work carried out by the eutrophication task group, and reports our main findings to the scientific community. On the basis of an operational, management-oriented definition, we discuss the main methodologies that could be used for coastal and marine eutrophication assessment. Emphasis is placed on integrated ap...
Plutonium oxide fuel pellets for powering radioisotopic thermoelectric generators for NASA space vehicles are encapsulated in iridium which has been grain-boundary-stabilized with thorium and aluminum. After aging for 6 months at 1310/sup 0/C under vacuum, enhanced grain growth is observed in the near-surface grains of the iridium next to the PuO/sub 2/. Examination of the grain boundaries by AES and SIMS shows a depletion of thorium and aluminum. Iron, chromium, and nickel from the fuel were found to diffuse into the iridium along the grain boundaries. Enhanced grain growth appears to result from thorium depletion in the grain boundaries of the near-surface grains next to the fuel. However, in one instance grain growth was slowed by the formation of thorium oxide by oxygen diffusing up the grain boundaries.
The purpose of the Hanford Waste Management Plan (HWMP) is to provide an integrated plan for the safe storage, interim management, and disposal of existing waste sites and current and future waste streams at the Hanford Site. The emphasis of this plan is, however, on the disposal of Hanford Site waste. The plans presented in the HWMP are consistent with the preferred alternative which is based on consideration of comments received from the public and agencies on the draft Hanford Defense Waste Environmental Impact Statement (HDW-EIS). Low-level waste was not included in the draft HDW-EIS whereas it is included in this plan. The preferred alternative includes disposal of double-shell tank waste, retrievably stored and newly generated TRU waste, one pre-1970 TRU solid waste site near the Columbia River and encapsulated cesium and strontium waste.
Asphalt emulsions were evaluated as a means to immobilize radiological contaminants deposited on urban surfaces after a dirty bomb attack. Contaminated surfaces would be sprayed with thin coatings of asphalt emulsion to encapsulate the radioactive particles until the site can be safely remediated. This research investigated applications of an asphalt emulsion (Topein C, Encapco Technologies, LLC, Napa, CA) to treat (zero-valent) iron, lead, and uranium powders on various building material surfaces. Initial studies found that some of the building materials (limestone, concrete, and metal) reacted with the emulsion producing gas bubbles, which formed 0.001 to 1 cm vesicles in the cured asphalt emulsion. These vesicles, however, did not expose the building material surface, and the reaction a...
As a method to make use of a high latent heat of a liquid-solid phase change material in a confined convective heat transfer, a phase change material, lauric acid, was encapsulated in a tiny hollow sphere, and mixed with water, forming a slurry of microencapsulated phase-change material (MCPCM slurry). Four different sizes (200, 100, 50, and 25 {mu}m ID) of MCPCMs were tested in this study. Thermal characteristics of the pure lauric acid and lauric acid MCPCMs were tested by a differential scanning calorimeter. Viscosity of the slurries of water and the capsules was measured by a rotating viscometer. The slurries were also tested in a convective-heat-transfer-test apparatus. (author). 11 refs., 5 figs., 1 tab.
This paper demonstrates a proof-of-concept approach for encapsulating the insulin and Fe3O4 nanoparticles into size-controllable alginate microcapsules utilizing the electrostatic droplets (ESD) technique. We have established that the combination of ESD and external gelation is quite effective in producing uniform-sized polymer particles. In addition, using the external gelation technique, the droplets containing a sodium-alginate were gelled in situ by immersion in Ca2+, Ba2+, or Cu2+ ions for a few minutes. The results show that different-type divalent cations caused various surface features to appear on the microcapsules (e.g., cracking, orange peel, pitting, splitting, wrinkling, etc.). The particle size can be adjusted from a few micrometers to ca. 1,000??m by electrostatic force. The...
A electrogenerated chemiluminescence (ECL) sensor for itopride was developed based on tris(2,2-bipyridyl)ruthenium(II) (Ru(bpy)32+)-doped silica (RuDS) nanoparticles/biopolymer chitosan composites membrane modified glassy carbon electrode (GCE). The RuDS nanoparticles (52+-5nm) were prepared by a modified Stber synthesis method and were characterized by electrochemical, fluorometric and transmission electron microscopy technology. The Ru(bpy)32+ encapsulation interior of the silica nanoparticle maintains its electrochemical activities and also reduces Ru(bpy)32+ leaching from the silica matrix when immersed in water due to the electrostatic interaction. The ECL analytical performances of this ECL sensor for itopride based on its enhancement ECL emission of Ru(bpy)32+ were investigated in d...
The effect of the composition of multicomponent Zr-Ti-V-Mn-Cr-Ni alloys on their hydrogen-storage capacity and on the rate of electrosorption/desorption hydrogen was investigated under potentiodynamics as well as single-pulse and long-term galvanostatic conditions. The main characteristics of alloys and alloy electrodes were determined by their structural analysis by means of X-ray diffraction and scanning electron microscope, by specific surface area test and by determination of the hydrogen absorption/desorption isotherms in the gas/solid phase system. It was found that only the alloys with a manganese content below a threshold could be used as electrode materials for Ni-MH batteries, whereas the modification of the electrode material by micro-encapsulation of alloy particles should limit the dissolution of manganese from the electrode material in a strong alkaline solution. (orig.)
Background Photopolymerizable poly(ethylene glycol) (PEG) hydrogels offer a platform to deliver cells in vivo and support three-dimensional cell culture but should be designed to degrade in sync with neotissue development and endure the physiologic environment. Questions/purposes We asked whether (1) incorporation of degradation into PEG hydrogels facilitates tissue development comprised of essential cartilage macromolecules; (2) with early loading before pericellular matrix formation, the duration of load affects matrix production; and (3) dynamic loading in general influences macroscopic tissue development. Methods Primary bovine chondrocytes were encapsulated in hydrogels (n?=?3 for each condition). The independent variables were hydrogel degradation (nondegrading PEG and degrading olig...
Gastrointestinal patches represent a novel multiparticulate drug delivery system able to increase the intestinal absorption of drugs with poor bioavailability. The number of patches to administer is a critical issue since it is related to the surface and drug concentration at the absorption site. The objective of this article is to evaluate the effect of the number of administered patches on the final absorption of leuprolide, a peptide chosen as model drug, assuming complete adhesion of all the devices to the intestinal membrane. The same dose of leuprolide was encapsulated into 2, 4 and 6 patches; the resulting intestinal absorption profiles were measured with the Ussing chamber ex vivo experimental setup and compared between them. The results showed that varying the number of patches, t...
A mesoscopically ordered lamellar gel phase of a polymer-grafted, lipid-based complex fluid is used as a scaffolding to spatially organize inorganic nanoparticles. The complex fluid provides both a highly anisotropic environment and a segregated aqueous and organic domains in which inorganic nanoparticles can be selectively placed by tailoring their size and surface characteristics. Three types of silver nanoparticles -- underivatized, surfactant-stabilized, and dodecanthiol-derivatized -- were evaluated. Comparison of the surface plasmon resonance of the various silver particles dispersed in conventional solvents to those contained within the complex fluid was used to determine the region of spatial localization in the lamellar gel phase. Silver particles rendered hydrophobic by capping with an alkane thiol insert into the hydrocarbon bilayer region. Surfactant-stabilized and underivatized silver nanoparticles reside in the aqueous channels, with the latter particles preferentially ...
Spray depositing allows the production of steels having a structure which is free of any macro-segregation, homogeneous and equiaxed. Nevertheless the spray deposition of steels shows some effects that have to be regarded as disadvantages. A porous region at the billet border and a rather coarse-grained microstructure can be noticed. As a result, in the presented work the influence of a subsequent hot rolling and a following heat treatment on microstructure and mechanical properties has been investigated. For this purpose the bearing steel SAE 52100 has been used as master material. The initial microstructure has been transformed to a homogeneous equiaxed fine-grained pearlitic microstructure without any remaining porosity. To get use of the characteristic properties of this high-strength steel an isothermal bainitic hardening has been carried out. Information about the mechanical properties of this material has been gained by tensile and fatigue tests. For fatigue ...
This paper examines the global impacts of a policy that internalizes the external costs (related to air pollution damage, excluding climate costs) of electricity generation using a combined energy systems and macroeconomic model. Starting point are estimates of the monetary damage costs for SO{sub 2}, NO {sub X} , and PM per kWh electricity generated, taking into account the fuel type, sulfur content, removal technology, generation efficiency, and population density. Internalizing these externalities implies that clean and advanced technologies increase their share in global electricity production. Particularly, advanced coal power plants, natural gas combined cycles, natural gas fuel cells, wind and biomass technologies gain significant market shares at the expense of traditional coal- and gas-fired plants. Global carbon dioxide emissions are lowered by 3% to 5%. Sulfur dioxide emissions drop significantly below the already low level. The policy increases the costs of electricity ...
This paper examines the global impacts of a policy that internalizes the external costs (related to air pollution damage, excluding climate costs) of electricity generation using a combined energy systems and macroeconomic model. Starting point are estimates of the monetary damage costs for SO{sub 2}, NOX, and PM per kWh electricity generated, taking into account the fuel type, sulfur content, removal technology, generation efficiency, and population density. Internalizing these externalities implies that clean and advanced technologies increase their share in global electricity production. Particularly, advanced coal power plants, natural gas combined cycles, natural gas fuel cells, wind and biomass technologies gain significant market shares at the expense of traditional coal- and gas-fired plants. Global carbon dioxide emissions are lowered by 3% to 5%. Sulfur dioxide emissions drop significantly below the already low level. The policy increases the costs of electricity production ...
High-resolution sequence stratigraphy concepts are applied to Erema, a Miocene onshore field of the Niger delta. The field's production is decreasing and an up-to-date geological model is essential to monitor the production. We aim to show an approach, using subsurface data and sequence stratigraphic concepts, which results in a time-line (Maximum Flooding Surfaces) correlation scheme. This scheme is based upon a facies model and is destined to guide the study of the characterization of reservoir heterogeneities. Using the cored well as a reference point, the facies model consists of shoreface dunes (planar tabular cross-stratified sandstones) changing landward into fluvial distributary deposits (through cross-stratified sandstones) via a tide-influenced coastal plain facies. The stacking pattern of genetic units shows a seaward stepping phase at the reservoir scale (sixty metres thick) with an abrupt deepening at the top of the reservoir. The proposed geological scheme, at ...
Heterogeneous base stations (e.g. picocells, microcells, femtocells and distributed antennas) will become increasingly essential for cellular network capacity and coverage. Up until now, little basic research has been done on the fundamentals of managing so much infrastructure -- much of it unplanned -- together with the carefully planned macro-cellular network. Inter-cell coordination is in principle an effective way of ensuring different infrastructure components behave in a way that increases, rather than decreases, the key quality of service (QoS) metrics. The success of such coordination depends heavily on how the overhead is shared, and the rate and delay of the overhead sharing. We develop a novel framework to quantify overhead signaling for inter-cell coordination, which is usually ignored in traditional 1-tier networks, and assumes even more importance in multi-tier heterogeneous cellular networks (HCNs). We derive the overhead quality contour for general ...
The goal of the Fifteenmile Creek Habitat Improvement project is to improve wild winter steelhead habitat in the Fifteenmile Creek Basin. This goal was addressed under the Columbia River Basin Fish and Wildlife Program, Measure 703 (c) (1) - Action Item 4.2. Construction of fish habitat structures was completed on approximately 3.5 miles of Eightmile Creek and on approximately 8.5 miles of Fifteenmile Creek. A total of 15,435 yds of rock was placed to improve rearing and spawning habitat, and to improve water quality and reduce siltation. Riparian protection fencing was completed on 1.8 miles of Dry Creek, approximately 1.75 miles on Eightmile Creek, and 4.75 miles on Fifteenmile Creek. Approximately 10 miles of stream will receive protection from the 8 miles of new fencing installed and 6.5 miles of abandoned fence repaired. Irrigation withdrawal screens were installed at six irrigation pump withdrawals. These screens functioned satisfactorily during the irrigation season. Physical ...
Kerf geometry, kerf wall features, and cutting front characteristics of an Abrasive Waterjet (AWJ) machined Graphite/Epoxy (Gr/Ep) laminate were studied. A macroscopic analyses suggests that geometrical features associated with AWJ machining of Gr/Ep laminates are influenced by three macro regions along the cutting depth. The presence of these regions, including initial damage at jet entry, smooth cutting, and rough cutting near the jet exit, depends on the operating conditions. Design of experiments and analysis of variance were used to determine the effect of cutting parameters on kerf characteristics and to develop empirical models for kerf profile and features of the three distinct macroscopic regions. Cutting front analysis revealed that the mechanisms of material removal in AWJ machining of Gr/Ep do not change over the jet penetration depth. In general, high quality uniform cuts may be obtained by minimizing initial damage at the jet entry and by extending ...
The design of a gaging head for a portable radionuclide X-ray fluorescence analyzer is described. The gaging head is designed as a construction unit system which enables the application of lateral reflexion geometry as well as of coaxial geometry. It is designed so that adjustment from one geometry to the other is labour and time saving. The selection of characteristic radiation is performed by a couple of Ross' differential filters. These filters are prepared by a novel technique developed by our laboratory. The filter exchange is effected by the longitudinal move of the couple of filters encapsulated in a holder. The shift of the filters is controlled by means of a triggering mechanism situated in the body of the gaging head handle. This design makes is possible to handle the gaging head during measurements with one hand. A simple interchange of the absorption filter for the transmissive filter allows the operator to avoid any unwanted shift of the head during ...
Tarapur Atomic Power Station 3 and 4 is a 540 MWe Pressurized Heavy Water Reactor. It uses 37 - element natural Uranium dioxide (UO_2) fuel pellets encapsulated inside the cylindrical sheath and are welded to the end plate at each end. During an postulated accident in which part of the fuel bundle are exposed to very high temperature (no means of heat removal) and other are at lower temperature (coolant temperature) possibility of failure of end plate weld due of thermal stresses developed by these relative temperature cannot be ruled out. In this report an attempt is made to study behaviour of fuel bundle under different temperature loading. Modelling of 37 element fuel bundle was done in ANSYS FEM. System was analysed for various sets of temperature loading. The system was analysed for plasticity and creep as material nonlinearity. The total strain, creep strain and stress increase as the temperature increases in upper portion of fuel bundle and decrease with ...
Hybridization and thermal evolution of the Ni+C{sub 60} composites, deposited on Si(001) at room temperature, were studied using Scanning Electron Microscopy, {mu}-Raman spectroscopy and Rutherford Backscattering. As-deposited, the hybrid films exhibited a granular nano-structure with Ni nano-particles encapsulated in C{sub 60} polymerized rinds. The Ni and C (C{sub 60}) distributions in a top layer were found homogeneous with a stable Ni/C (C{sub 60}) ratio; in the larger depth the distributions were inhomogeneous and their ratio dramatically varied. At elevated temperatures, all structural parameters were changed. In the subsurface layer Ni- and C (C{sub 60})-rich zones were formed (due to the induced phase separation), C{sub 60}-molecules decayed and their fragments were transformed into amorphous carbon (a-C). The free volume distribution of the stressed hybrid matter was analyzed by the Hg marker that (in a form of vapors) in-diffused in to the samples. The ...
The purpose of this study is to analyze the safeties and the economics for Co-60 production from Wolsung PHWR and to verify the feasibility on the manufacturing of the final Co-60 source for industrial irradiation. The feasibility of reactor conversion was carried out with KEPCO collaboration. Through the site survey on the experience of Gentililly-2 in Canada, a feasibility of plant conversion, changes in design, equipment and tools for Co-60 production was verified. It was estimated that the reactor conversion would not impose adverse impact on plant safety. For the encapsulation of radiation source and storage of the final products, a modification of concrete hot cell at KAERI was primary concerns. The installation and improvement of facilities are needed to avoid cross contamination and extra radiation exposure. Main items for these are pressure gauge, separated HEPA filter the ceiling separation, extra-shielding and ceiling hoist system. At present, storage ...
A novel method for the determination of metoclopramide (MCP) using electrogenerated chemiluminescence (ECL) is presented. A tris(2,2prime-bipyridyl)dichlororuthenium(II) (Ru(bpy)32+)-doped silica (RuDS) nanoparticle/perfluoinated ion-exchange resin (Nafion) with nanocomposite membrane modified glassy carbon electrode (GCE) is used. The Ru(bpy)32+ encapsulation interior of the silica nanoparticle maintains its electrochemical activities and also reduces Ru(bpy)32+ leaching from the silica matrix when immersed in water due to the electrostatic interaction. The analytical performance of this ECL sensor for MCP is shown in detail. Under optimal experimental conditions, it has good linearity in the concentration range from 2x10-8mol/L to 1x10-5mol/L (R=0.9989) with a detection limit of 7x10-9mo...
We study quantized beamforming in wireless amplify-and-forward relay-interference networks with any number of transmitters, relays, and receivers. We design the quantizer of the channel state information to minimize the probability that at least one receiver incorrectly decodes its desired symbol(s). Correspondingly, we introduce a generalized diversity measure that encapsulates the conventional one as the first-order diversity. Additionally, it incorporates the second-order diversity, which is concerned with the transmitter power dependent logarithmic terms that appear in the error rate expression. First, we show that, regardless of the quantizer and the amount of feedback that is used, the relay-interference network suffers a second-order diversity loss compared to interference-free networks. Then, two different quantization schemes are studied: First, using a global quantizer, we show that a simple relay selection scheme can achieve maximal diversity. Then, ...
The magnetic separation technology using sub-microsized ferromagnetic particle is indispensable in many areas of medical biosciences. For example, ferromagnetic particles (200-500 nm) are widely used for cell sorting in stem cell research with the use of cell surface-specific antigens. Nanosized ferromagnetic particles (10-20 nm) have been suggested as more suitable in drug delivery studies given their efficiency of tissue penetration, however, the magnetic separation method for them has not been established. One of the major reasons is that magnetic force acting on the object particles decreases drastically as a particle diameter becomes small. In this study, magnetic force acting on the targets was enhanced by the combination of superconducting magnet and the filter consisting of ferromagnetic particle. By doing so, we confirmed that Fe{sub 3}O{sub 4} of 20 nm in diameter was trapped in the magnetic filter under an external magnetic field of 0.5 T. Fe{sub 3}O{sub 4} ...
The feasibility of containing genetically engineered bacteria with enhanced dehalogenating properties for in situ bioremediation was investigated. (1) An agarose matrix microbead protocol and a detection system for contained microorganisms or DNA were developed. Multiplex Polymerase Chain Reaction (PCR) allowed tracking of a consortium of encapsulated organisms or several gene targets from a single species. Gene sequences encoding the enzymes responsible for initiating the biodegradation of toluene, octane, and 2,4-D were detected by multiplex PCR and nucleic acid probes from similar to 1-10 biodegradative cells/g soil. Improved DNA extraction methods resulted in PCR reactions detecting similar to 6 cells/g soil. (2) The pcpB gene (for the broad-spectrum detoxicant pentachlorophenol (PCP) hydroxylase) isolated from Flavobacterium sp. strain ATCC 39723 was used in attempts to develop an improved dehalogenating recombinant microorganism for containment experiments.
Abstract The objective of this study was to determine the functional properties of cartilaginous tissues generated by porcine MSCs isolated from different tissue sources, and to compare these properties to those derived from chondrocytes (CCs). MSCs were isolated from bone marrow (BM) and infrapatellar fat pad (FP), while CCs were harvested from the articular surface of the femoro-patellar joint. Culture-expanded CCs and MSCs were encapsulated in agarose hydrogels and cultured in the presence of TGF3. Samples were analysed biomechanically, biochemically and histologically at days 0, 21 and 42. After 42 days in free swelling culture, mean GAG content was 1.50% w/w in CC-seeded constructs, compared to 0.95% w/w in FP- and 0.43% w/w in BM-seeded constructs. Total collagen accumulation was hig...
In Sweden, spent nuclear fuel will be encapsulated and placed in a deep geological repository. In this procedure, reliable and accurate spent fuel data such as discharge burnup, cooling time and residual heat must be available. The gamma scanning method was proposed in earlier work as a fast and reliable method for the experimental determination of such spent fuel data. This thesis is focused on the recent achievements in the development of a pilot gamma scanning system and its application in measuring spent fuel residual heat. The achievements include the development of dedicated spectroscopic data-acquisition and analysis software and the use of a specially designed calorimeter for calibrating the gamma scanning system. The pilot system is described, including an evaluation of the performance of the spectrum analysis software. Also described are the gamma-scanning measurements on 31 spent PWR fuel assemblies performed using the pilot system. The results obtained ...
In Sweden, spent nuclear fuel will be encapsulated and placed in a deep geological repository. In this procedure, reliable and accurate spent fuel data such as discharge burnup, cooling time and residual heat must be available. The gamma scanning method was proposed in earlier work as a fast and reliable method for the experimental determination of such spent fuel data. This thesis is focused on the recent achievements in the development of a pilot gamma scanning system and its application in measuring spent fuel residual heat. The achievements include the development of dedicated spectroscopic data-acquisition and analysis software and the use of a specially designed calorimeter for calibrating the gamma scanning system. The pilot system is described, including an evaluation of the performance of the spectrum analysis software. Also described are the gamma-scanning measurements on 31 spent PWR fuel assemblies performed using the pilot system. The results obtained ...
Although the current Internet Protocol known as IPv4 has served its purpose for over 20 years, its days are numbered. With IPv6 reaching a mature enough level, there is a need to evaluate the performance benefits or drawbacks that the new IPv6 protocol will have in comparison to the well established IPv4 protocol. Theoretically, the overhead between the two different protocols should be directly proportional to the difference in the packet's header size, however according to our findings, the empirical performance difference between IPv4 and IPv6, especially when the transition mechanisms are taken into consideration, is much larger than anticipated. We first examine the performance of each protocol independently. We then examined two transition mechanisms which perform the encapsulation at various points in the network: host-to-host and router-to-router (tunneling). Our experiments were conducted using two dual stack (IPv4/IPv6) routers using end nodes running ...
This work is a theoretical investigation on the physical properties of semiconductor-based two-dimensional photonic crystals, in particular for what concerns systems embedded in planar dielectric waveguides (GaAs/AlGaAs, GaInAsP/InP heterostructures, and self-standing membranes) or based on macro-porous silicon. The photonic-band structure of photonic crystals and photonic-crystal slabs is numerically computed and the associated light-line problem is discussed, which points to the issue of intrinsic out-of-lane diffraction losses for the photonic bands lying above the light line. The photonic states are then classified by the group theory formalism: each mode is related to an irreducible representation of the corresponding small point group. The optical properties are investigated by means of the scattering matrix method, which numerically implements a variable-angle-reflectance experiment; comparison with experiments is also provided. The analysis of surface ...
The assessment of greenhouse gas impacts in the US shows that against a baseline gasoline vehicle, the impact of including the full fuel cycle generally reduces the relative advantages of alternative transportation fuels. While a switch to diesel is estimated to save 30% as compared to gasoline, the savings from natural gas/LPG are (around 20%), for ethanol from corn (8%) and for battery electricity vehicles using power from coal (6%) are much smaller. This is largely due to the use of LCA rather than end-use comparisons. However, the results also show that there would be large savings from the use of ethanol from fuel cells using methanol (39%) or natural gas (50%), while ethanol from wood in a conventional engine appears to have the greatest savings (63%). In external costs of motor vehicle use, analysis results were presented for both air pollution and energy security impacts (including SPR, military expenditures, macro-economic costs and pecuniary costs) as ...
Pitting corrosion can be considered as a combination of two physical processes: the pit generation process and its depth growth process. Both processes are uncertain and can be modeled by stochastic processes. A model that combines two stochastic processes to describe pitting corrosion was developed. In this model, the pit generation process is represented by the Poisson process, and the pit depth growth process is modeled by the Markov process. The probability distribution of corrosion pit depth and the probability of time-to-failure are derived based upon the combined stochastic processes. Examples of the use of this method in dealing with experimental data also were developed.
Different aspects of overall evaluation of training programmes and processes as well as role of evaluation in the quality assurance process are considered.
The thermal stability of low-friction Me-C/a-C:H coatings is important for their potential applications in the tool and automotive industry. Recently we showed that CrC _x/a-C:H coatings prepared by unbalanced magnetron sputtering of a Cr target in Ar + CH_4 glow discharges exhibit a nanocomposite structure where metastable fcc CrC nanocrystals are encapsulated by an a-C:H phase. Here, we present the structural evolution of these nanocomposite CrC/a-C:H coatings during annealing. High-temperature X-ray diffraction in vacuum and differential scanning calorimetry (DSC) combined with thermo-gravimetric analysis in Ar atmosphere indicate decomposition of the formed metastable fcc CrC phase and subsequent formation of Cr_3C_2 and Cr_7C_3 and structural transformation of the a-C:H matrix phase towards higher sp"2 bonding contents at temperatures above 450 deg. C. Combined DSC and mass spectrometer analysis as well as elemental profiling after annealing in vacuum by ...
The water soluble, photolabile nitrene precursor, azidonaphthalene-2,7-disulfonic acid (ANDS) was encapsulated in small unilamellar, isoelectric (egg PC) or negatively charged (egg PC + dihexadecylphosphate) liposomes. The individual and combined effects of heme-proteins and UV irradiation on the fluorescence of these vesicles under aerobic conditions were studied. Consistent with the catalytic action of heme-proteins on lipid peroxidation and peroxide decomposition, addition of cytochrome c (positively charged) or catalase (negatively charged) to the vesicles elicited immediate formation of a fluorescence band at 470 nm, characteristic of Schiff bases that form from aldehyde byproducts of decomposing hydroperoxides. Ultraviolet irradiation of liposomes caused no significant changes in the fluorescence spectrum, in spite of the radiolysis of ANDS inside the vesicles with consequent formation of nitrene radicals. When isoelectric vesicles were irradiated with UV ...
Insect host/parasitoid interactions are co-evolved systems in which host defenses are balanced by parasitoid mechanisms to disable or hide from host immune effectors. Although there is a rich literature on these systems, parasitoid immune-disabling mechanisms have not been fully elucidated. Here we report on a newly discovered immune-disabling mechanism in the Pieris rapae/Pteromalus puparum host/parasitoid system. Because venom injections and parasitization suppresses host phagocytosis, we turned attention to the P. rapae scavenger receptor (Pr-SR), posing the hypothesis that P. puparum venom suppresses expression of the host Pr-SR gene. To test our hypothesis, we cloned a full-length cDNA of the Pr-SR. Multiple sequences alignment showed the deduced amino acid sequence of Pr-SR is similar to scavenger receptors of other lepidopterans. Bacterial and bead injections induced Pr-SR mRNA and protein expression, which peaked at 4h post-bead injection. Venom injection inhibited Pr-SR ...
The 24 papers presented at the conference on Neutralisation des eaux de drainage dans l'environnement minier (NEDEM) (Mine Environment Neutral Drainage (MEND)) 2000 symposium on research on innovative methods to control acid mine drainage, covered eight sessions with both technical and general interest papers. The technical papers covered the topics of acid mine drainage and remediation measures, such as flooding, soil cover with various materials, encapsulation, and others. Other topics discussed included the freeze-thaw cycle and its effect on the performance of soil covers. The environmental impacts of acid mine drainage were also described. Some case studies were included to further illustrate the environmental impacts of acid mine drainage and to demonstrate the effectiveness of remedial actions in specific situations. Most of the cases studied were mines located in Quebec and Northern Ontario, with some in British Columbia. The general interest ...
Brachytherapy refers to short distance treatment of cancer with radiation from small, encapsulated radionuclide sources. This type of treatment is given by placing sources directly into or near the volume to be treated. The dose is then delivered continuously, either over a short period of time (temporary implants) or over the lifetime of the source to a complete decay (permanent implants). This technique is extensively used in the treatments of gynecological, breast, prostate, head and neck, and other soft tissue cancers. The clinical outcomes of this treatment depend on accurate dosimetry and dose delivery. The patient is generally considered to be water equivalent. So the treatment planning system software generally is based on measured or calculated dose distributions in homogenous water medium. In real situation, the treatment volume is not homogenous water medium, but it is a heterogeneous medium consisting of bone, soft tissue, lung, air etc. For better ...
The mining complex Eustis-Capelton, located in the Estrie, was created in 1860, just as the demand and the prices for copper were beginning to rise. It survived the economic crash that followed the end of the American Civil War and continued its activities. Mine Albert was closed in 1907, and the Capelton chemical complex in 1924. As for the Eustis Mine, it continued to operate until 1939. The various mining companies operating in the region were able to maintain their presence throughout the difficult periods due to their flexibility, their capacity to innovate and their good management practices. It was the lack of minerals and several other factors that finally contributed to the demise of the mining industry in the Estrie region. The waste rock piles and tailings at the Eustis, Albert, Capel, and Hartford Mines all display acid mine drainage potential. The tailings are located along the Eustis and Capel streams, which follow a steep course toward the Massawippi River, and tailings ...
The proposed design for a final repository for spent fuel and other long-lived residues in Sweden is based on the multi-barrier principle. The waste will be encapsulated in sealed cylindrical canisters, which will then be placed in granite bedrock and surrounded by compacted bentonite clay. The canister design is based on a thick cast inner container fitted inside a corrosion-resistant copper canister. During fabrication of the outer copper canisters there will be some unavoidable grain growth in the welded areas. As grains grow they will tend to concentrate impurities within the copper at the new grain boundaries. The work described in this report was undertaken to determine whether there is any possibility of enhanced corrosion at grain boundaries within the copper canister. The potential for grain boundary corrosion was investigated by exposing copper specimens, which had undergone different heat treatments and hence had different grain sizes, to aerated ...
Objective: Solid pseudopapillary tumor of the pancreas (SPTP tumor) is a rare pancreatic neoplasm with low malignant potential, which usually affects female patients in the second or third decades of life. It is a non-functional, slow-growing neoplasm that very often reaches considerable size before the first symptoms appear. Symptomatology is frequently related to tumor size. Surgical excision is usually curative in most cases. Infrequently the tumor can appear in male patients or in aged women, which can make the diagnosis more difficult. Some patients develop liver metastases in the follow-up that can be resected. Our purpose is to review the radiological and pathological findings of SPTP with emphasis on these infrequent cases. Subjects and methods: The medical records and radiological findings of patients who underwent surgery for SPTP between 2000 and 2005 were retrospectively reviewed. Study eligibility required that patients had undergone surgical resection and that a SPTP had ...
Objective: Solid pseudopapillary tumor of the pancreas (SPTP tumor) is a rare pancreatic neoplasm with low malignant potential, which usually affects female patients in the second or third decades of life. It is a non-functional, slow-growing neoplasm that very often reaches considerable size before the first symptoms appear. Symptomatology is frequently related to tumor size. Surgical excision is usually curative in most cases. Infrequently the tumor can appear in male patients or in aged women, which can make the diagnosis more difficult. Some patients develop liver metastases in the follow-up that can be resected. Our purpose is to review the radiological and pathological findings of SPTP with emphasis on these infrequent cases. Subjects and methods: The medical records and radiological findings of patients who underwent surgery for SPTP between 2000 and 2005 were retrospectively reviewed. Study eligibility required that patients had undergone surgical resection and that a SPTP had ...
This paper deals with preparation of PE clay nano composite specimen for transmission electron microscopy (TEM) and studying the difference between dispersion of clay in low density polyethylene using poly(hydrogen methyl siloxane) (PHMS) as coupling agent and untreated one. Argon ion milling is the conventional means by which film sections are thinned to electron transparency for TEM analysis, but this technique exhibits significant problems. In particular, selective thinning and imaging of sub-micrometer inclusions during sample milling are highly problematic. We have achieved successful results using the focused ion beam (FIB) lift-out technique, which utilizes a 30 kV Ga"+ ion beam to extract electron transparent specimens with nanometer scale precision. Using this procedure, we have prepared a number of thin film materials representing a range of structures and compositions for TEM analysis. We believe that FIB milling will create major new opportunities in the field of thin film ...
In the early 1980s, AECL built a Waste Treatment Centre (WTC) for managing low-level solid and aqueous liquid wastes for converting CANDU wastes. At present, two liquid waste streams are being treated at the WTC. The liquid waste streams are volume-reduced by a combination of continuous crossflow microfiltration (MF), spiral wound reverse osmosis (SWRO) and tubular reverse osmosis (TRO) membrane technologies. The concentrate produced from the TRO system and the volume-reduced MF backwash solutions are evaporated while simultaneously adding bitumen in a thin-film evaporator. A water-free product of chemical and radiochemical salts and bitumen is removed in 200-L galvanized steel drums for storage. The radiation field of product drums on contact typically has a value of 0.5 to 3 R/h depending upon the feed concentration of radioactivity to the evaporator. The total solids content in the 200-L drum ranges from 25 to 35%. Encapsulated in the bitumen matrix are a ...
This paper introduces the JNM Special Issue on the development of a first wall for the reaction chamber in a laser fusion power plant. In this approach to fusion energy a spherical target is injected into a large chamber and heated to fusion burn by an array of lasers. The target emissions are absorbed by the wall and encapsulating blanket, and the resulting heat converted into electricity. The bulk of the energy deposited in the first wall is in the form of X-rays (1.0-100 keV) and ions (0.1-4 MeV). In order to have a practical power plant, the first wall must be resistant to these emissions and suffer virtually no erosion on each shot. A wall candidate based on tungsten armor bonded to a low activation ferritic steel substrate has been chosen as the initial system to be studied. The choice was based on the vast experience with these materials in a nuclear environment and the ability to address most of the key remaining issues with existing facilities. This ...
... and facilities; the physical processing of materials into products; and processes associated with ... area of bulk silicon prod! uction as wafer material has been omitted, in keeping with current ...
In a process for separating insoluble red mud from Bayer process streams the improvement is described which comprises contacting and mixing a Bayer process stream with a tertiary polyamine having a molecular weight of at least about 10,000 in an amount effective to reduce the iron content thereof.
Adaptive image processing is one of the most important techniques in visual information processing, especially in early vision such as image restoration, filtering, enhancement, and segmentation. This work focuses on applications of advanced CI techniques in image processing applications
Mg-3%Al-1%Zn (AZ31) alloy was subjected to ECAE processing at 523 and 573 K. Microstructure observation and texture analysis were carried out using optical microscope and SEM-EBSD technique in order to investigate the process of microstructural changes including texture development during ECAE processing. Grain refinement during ECAE processing is enhanced by dynamic continuous recrystallization. The texture of the ECAE-processed AZ31 alloy specimens change with ECAE processing temperature, and the textural changes relate to deformation mechanisms that change with ECAE processing temperature. (orig.)
Makeup water is distilled internally in an amine gas treating unit by adding it to the reclaimer used to process a slipstream of lean amine from the stripper.
... Abstract : The beater additive process for manufacturing combustible cartridge cases is superior to the solvent resin, post-impregnation process. ...
Atomization of liquid fuel in aircraft engines requires application of airblast atomizers, where the kerosene is supplied into the shear layer between two swirling airstreams. The transfer of this functional principle towards gaseous fuel, as illustrated in Fig. 1, yielded a strong influence of the swirl arrangement of the airflows on flame stability and homogeneity of the fuel/air-mixture. Compared to the co-swirl configuration the flow field of the counter-swirl arrangement exhibits a marked increase of the mass flow recirculated in the internal recirculation zone and a reduction of its length in axial direction. This is attributed to the faster decay of tangential velocity maxima in case of counter-rotating airflows. This generates a stronger positive axial pressure gradient dp/dx, thus enhancing the internal recirculation zone. Analysis of local turbulence quantities yields a restriction of turbulent exchange to smaller radial sections and lower maximum values in the jet dominated ...
Magnetic resonance (MR) imaging and histopathology were used to diagnose an articular process synovial myxoma in a dog. On MR images, the tumor was characterized by distortion of the left L1-L2 articular process, widening of the articular process joint, and the presence of a mass contiguous with the synovium of the articular process that displaced the spinal cord. The tumor was T2-hyperintense, T1-hypointense, relative to muscle, and had mild contrast enhancement. The MR features of articular process synovial myxoma may be distinct from other diseases of the articular process joint.
In the presented case study CRS processing was able to improve the overall data quality of the processed lines in terms of signal-to-noise ratio and imaging. The complex geology is causing serious problems in conventional NMO/DMO processing that were solved by CRS processing. Even a depth processing with velocities calculated from CRS attributes gives good results similar to those from PreSDM in terms of the velocity field. Data quality of poststack depth migrated CRS stacks is even better than the image from PreSDM. (orig.)
The report gives results of economic evaluations of two processes: the Rockwell International aqueous carbonate process (ACP) and the Wellman-Lord process, the latter applied to a sulfuric acid plant, the Foster Wheeler Resox process, and the Allied Chemical coal reduction proces...
Consol R D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-fold: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.
Consol R D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-field: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.
This book deals specifically with the development of new processes of converting coal into useful chemical feedstocks. The major topic in this volume is the generation of syngas and its catalytic conversion to chemicals via the Fischer-Tropsch synthesis. Describes processes involved in conversion, recent catalytic developments, and the commercially important Sasol process. Also includes chapters on the carbide process and potential of future developments in the field.
Contemporary high dimensional biological assays, such as mRNA expression microarrays, regularly involve multiple data processing steps, such as experimental processing, computational processing, sample...Full Text Available
It is shown that a natural consequence of the binary pulsar's evolution is a neutron star collision. Such a collision is expected to eject neutron-rich matter of an r-process character. Taking reasonable estimates for the number of such events over the history of the galaxy, it may be that they account for all of the r-process nuclei.
Laser assisted solar cell metallization processing which is a one step process is examined. The potential advantages of laser disposition techniques for photovoltaic systems are: a high resolution, no photolithography, clean and contamination free, in-situ sintering, and low contact resistance.
As part of its program to provide technology for reducing undesirable environmental impacts of mineral processing operations, the Bureau of Mines developed the citrate process for desulfurizing industrial stack gases that contain from 0.1 to 2 vol pct SO2...
Autism is a pervasive developmental condition, characterized by impairments in non-verbal communication, social relationships and stereotypical patterns of behavior. A large body of evidence suggests that several aspects of face processing are impaired in autism, including anomalies in gaze processing, memory for facial identity and recognition of facial expressions of emotion. In search of neural markers of anomalous face processing in autism, much interest has focused on a network of brain regions that are implicated in social cognition and face processing. In this review, we will focus on three such regions, namely the STS for its role in processing gaze and facial movements, the FFA in face detection and identification and the amygdala in processing facial expressions of emotion. Much evidence suggests that a better understanding of the normal development of ...
The control of gas activity and process technology has developed tremendously over the past two decades. While once considered to be primitive control systems using simple PID loops with thermocouples that were suspect and unable to perform repeatedly and consistently during the arduous process of plasma nitriding and processing, developments in recent years have elevated the control of the process into what might be considered one of the most controllable processes of the latter part of this century. The advent of plasma processing technology has improved control methods by observing and harnessing each of the various process parameters into many different combinations of control systems. Some of these control systems can control the complete function of the process, thus freeing the operator entirely for other duties, ...
In order to reduce the length and to increase the effectiveness of processing, the proposed method for acetic processing of an electric centrifugal well pump calls for covering the pressure line during the curing and periodically starting the pump.
Gasification and hydrogenation are the two basic routes for coal processing. Accounts are given of various low-temperature processes in coal gasification route A: air separation, removal of sour gas by the Rectisol process, liquid nitrogen washing, the material balance and utility consumption of these processes, plus low-temperature gas separation, partial condensation and methane washing. There are also accounts of the low-temperature processes involved in gasification route B: i.e., in the indirect coal liquefaction and direct liquefaction carried out in the Sasol II and III processes. (3 refs.) (In Japanese)
Computation and information processing are among the most fundamental notions in cognitive science. They are also among the most imprecisely discussed. Many cognitive scientists take it for granted that cognition involves computation, information processing, or both ? although others disagree vehemently. Yet different cognitive scientists use ?computation? and ?information processing? to mean different things, sometimes without realizing that they do. In addition, computation and information processing are surrounded by several myths; first and foremost, that they are the same thing. In this paper, we address this unsatisfactory state of affairs by presenting a general and theory-neutral account of computation and information processing. We also apply our framework by analyzing the relatio...
Focussed ion beam (FIB) technology has the advantage of being a maskless process compatible with UHV processing. This makes it attractive for use in in situ processing and has been applied to the fabrication of various mesoscopic structures. The present paper reviews these results whilst putting emphasis on in situ processing by a combined FIB and molecular beam epitaxy system. The typical performance of present FIB systems is also presented. In order to utilize the potential advantages of FIB processing, reduction of damage and improvement of throughput are important, and much effort has been devoted to developing processing techniques which require a reduced dose. The importance of low-energy FIB is discussed. (author).
Focussed ion beam (FIB) technology has the advantage of being a maskless process compatible with UHV processing. This makes it attractive for use in in situ processing and has been applied to the fabrication of various mesoscopic structures. The present paper reviews these results whilst putting emphasis on in situ processing by a combined FIB and molecular beam epitaxy system. The typical performance of present FIB systems is also presented. In order to utilize the potential advantages of FIB processing, reduction of damage and improvement of throughput are important, and much effort has been devoted to developing processing techniques which require a reduced dose. The importance of low-energy FIB is discussed. (author).
The article focusses on operational experience gained with the following items: scrubbing system with oxidation, regenerative gas preheater, blower/fan, aerosol filter, and product processing. (orig./PW).
For a process intimately connected to an immense range of physiological processes, the molecular understanding of macroautophagy remains far from complete. Recent large-scale studies, including...Full Text Available
Project methodology, analysis of the occupational and training situation, task analysis process, design process for a systematic training plan specific to the job position are described.
The objective of this project was to develop new photocatalytic or other innovative process chemistry for the treatment of pink water and related contaminated water.
... ge aircraft engines (geae) has taken to development an induction plasma deposition (ipd) processing method for the fabrication of ti6242/sic mmc ...
The study design included an in vivo laboratory study. The objective of the study is to quantify the kinematics of the lumbar spinous processes in asymptomatic patients during un-restricted functional...Full Text Available
... coordinates to allow for multisensor fusion, trajectory ... of an image processing toolkit (iPTK ... effectiveness of data-driven registration processing, spatial ...
Objective:This paper describes the Lamar Soutter Library's process and costs associated with digitizing 300 doctoral dissertations for a newly implemented institutional repository...Full Text Available
A process has been proposed to increase the efficiency of an ideal Otto cycle via a quantum heat engine that has no cooler reservoir. We show that such a process is not feasible.
...Continued) FEDERAL RAILROAD ADMINISTRATION, DEPARTMENT OF TRANSPORTATION QUALIFICATION AND CERTIFICATION OF LOCOMOTIVE ENGINEERS Dispute Resolution Procedures § 240.405 Processing qualification review petitions. (a)...
This report describes accomplishment of simulations of Pyrochemical Process Operation by using virtual engineering models. The pyrochemical process using molten salt electrorefining would introduce new technologies for new fuels of particle oxide, particle nitride and metallic fuels. This system is a batch treatment system of reprocessing and re-fabrication, which transports products of solid form from a process to next process. As a results, this system needs automated transport system for process operations by robotics. In this study, a simulation code system has been prepared, which provides virtual engineering environment to evaluate the pyrochemical process operation of a batch treatment system using handling robots. And the simulation study has been conducted to evaluate the required system functions, which are the function of handling robots, the ...
This 4.5-year project consisted of routine analytical support to DOE`s direct liquefaction process development effort (the Base Program), and an extensive effort to develop, demonstate, and apply new analytical methods for the characterization of liquefaction process streams (the Participants Program). The objective of the Base Program was to support the on-going DOE direct coal liquefaction process development program. Feed, process, and product samples were used to assess process operations, product quality, and the effects of process variables, and to direct future testing. The primary objective of the Participants Program was to identify and demonstrate analytical methods for use in support of liquefaction process develpment, and in so doing, provide a bridge between process design, development, and operation and ...
A review is presented of the work being carried out around the world on the vitrification of high-level waste. A description is given of the French AVM process, West Germany's research on the Vera, Fips and Pamela processes and the United Kingdom Harvest process. Mention is also made of the Lotes process being developed by Belguim, and of the inactive vitrification plant in Italy, Ivet 1. (U.K.).
Thermodynamic consideration and process calculations at equilibrium conditions showed that processes for separating gas mixtures by partial condensation at low temperatures using turboexpanders have got less energy losses than processes with quasi isobar partial condensation. Compared to the low-pressure parts of condensing steam turbines in turboexpanders less erosion problems are to expected for such separating processes. Separation of liquid in the machine, however, is more difficult withouf additional measures. (orig.).
Two extruded magnesium alloys, AZ31 and AZ61 were selected to evaluate the influence of process parameters on the material forgeability. The processing parameters considered for forging magnesium alloys were: compression load in the range 55 KN to 60 KN and forging temperature, in the range of ambient temperature to 300 C. Uniaxial compression tests were conducted to establish the strain-temperature relationship. The influences of process parameters on the microstructure were also evaluated. (orig.)
The application of photopolymerisation (UV) and electron beams (EB) technologies in radiation rapid cure (PRC) processing is discussed. The chemistry associated with such reactions and the mechanisms of the processes are treated. The occurrence of concurrent grafting to substrate with radiation curing of films is shown to be an advantage in enhancing the properties of certain finished products. The parameters influencing the optimum grafting yield in such PRC processes are discussed. In many applications, the chemistry of such processes combined with the machine, specially for EB is shown. (author).
The application of various signal processing methods to extract energy storage information from plasma diamagnetism sensors occurring during physics experiments on the Tandom Mirror Experiment-Upgrade (TMX-U) is discussed. We show how these processing techniques can be used to decrease the uncertainty in the corresponding sensor measurements. The algorithms suggested are implemented using SIG, an interactive signal processing package developed at LLNL.
The image processing system for the dynamic neutron radiography has been developed. It is based on the hardware subset, composed by the method of the pipe-line and use of algorithm of local statistics. The processing speed per one pixel is shorter than 100 n sec and video-rate processing can be executed on it. Some image processes for improving the quality of the real-time neutron image, noise reduction and contrast stretching would be attempted by the use of this system. (author).
Processes were developed that use lasers as manufacturing tools. These processes were stripping of insulation from cables and wires, machining of quartz, microdrilling and welding of reflective metals, and precision alignment of curved surfaces before machining. A technological basis also was formed which resulted in a process for automatic surface inspection of parts and aided development of machining processes for Kevlar parts.
The Synthoil process for producing heavy desulfurized fuel oil from coal has been under development at Pittsburgh Energy Research Center since 1969. The status of development and technical feasibility of the process are reviewed. This is part of an engineering and economic evaluation based on the conceptual design of a 100,000-bbl/day commercial Synthoil facility. Experimental data are discussed with regard to their adequacy for the formulation of a basis for the process design of such a facility. Potential engineering and equipment problems are analyzed.
Data Qualification (DQ) is a formal, technical process whose objective is to affirm that experimental data are suitable for their intended use. Although it is not possible to develop a fixed recipe for the DQ process to cover all test situations, these general guidelines have been developed for the Nuclear Engineering Section to establish a framework for qualifying data from steady-state processing. These guidelines outline the role of the DQ team providing insight into the planning and conducting of the DQ process.
Contents include: introduction; river systems; physical processes; chemical processes; estuaries and coastal zone; introduction; physical processes; chemical processes; the role of sediments; introduction; the anoxic layer; major-element chemistry; minor-element chemistry; the oxic-anoxic interface; assessment; introduction; analysis of sediments; modelling.
... Author: Radev, Dragomir R. Subjects: natural language processing DeweyClass: 764 Resource type: document Natural Language Processing Research Group Research Group based in the Department of Computer Science, University of Sheffield. Conducts research into natural language analysis topics including data mining/information extraction, dialogue, and semantics. Author: Department of Computer Science, University of Sheffield Subjects: natural language processing DeweyClass: 764 Resource ...
We report Sr, Pd and Ag abundances for a sample of metal-poor field giants and analyze a larger sample of Y, Zr, and Ba abundances. The [Y/Zr] and [Pd/Ag] abundance ratios are similar to those measured for the r-process-rich stars CS 22892-052 and CS 31082-001. The [Pd/Ag] ratio is larger than predicted from the solar-system r-process abundances. The constant[Y/Zr] and [Sr/Y] values in the field stars places strong limits on the contributions of the weak s-process and the main s-process to the light neutron-capture elements. Stars in the globular cluster M 15 possess lower [Y/Zr] values than the field stars. There is a large dispersion in [Y/Ba]. Because the r-process is responsible for the production of the heavy elements in the early Galaxy, these dispersions require varying light-to-heavy ratios in r-process yields.
A process combining dark fermentation and photofermentation for production of hydrogen is interesting due to its potential of producing hydrogen at a high yields. In this study, the hydrogen process is compared to a 2nd generation ethanol process with respect to cost and with the aim of increasing our understanding of the pros and cons and giving a clear picture of the present status of the two processes. The hydrogen production cost was found to be about 20 times higher than the ethanol production cost, 421.7&z.euro;/GJ compared to 19.5&z.euro;/GJ. The main drawbacks of the hydrogen process are its low productivity, low energy efficiency, and the high cost of buffer and base required to control the pH.
Microwave-hydrothermal processing was compared with conventional hydrothermal processing in the crystallization of hematite from 1M ferric nitrate and hydroxyapatite from calcium oxide and phosphoric acid. Microwave-hydrothermal processing led to the crystallization of hematite while convention-hydrothermal process led to the crystallization of a mixture of goethite and hematite under the same temperature conditions. Thus the crystallization of hematite which is the stable iron oxide phase at high temperatures has been catalyzed by microwaves. Microwave-hydrothermal processing also led to highly crystalline hydroxyapatite powders compared to the conventional hydrothermal processing which also points to the catalytic role of microwaves. The microwave induced effects may be attributed to the generation of localized high temperatures at the reaction sites which ...
In this paper a novel method is presented, based on the use of plasma processing, to suppress the transient enhanced diffusion of boron implanted in silicon. We found for silicon samples processed with plasma and subsequently boron implanted that the anomalous diffusion of the dopant atoms at the beginning of the annealing process is almost completely suppressed. This phenomenon is interpreted in terms of capture of the ion beam generated interstitials by the dislocations induced by the plasma processing. At room temperature the dislocations are observed to grow in size after the boron implant, attesting their efficiency as trapping centres for interstitials. Moreover, varying the plasma process conditions we can establish a general relation between the presence of the trapping centres induced by the plasma processing and the suppression of the transient ...
A computer modelling has been developed for the calculation of mass balance of monazite ore break-down by alkali process at Rare Earth Research and Development Center. The process includes the following units : ore digestion by concentrate NaOH, dissolution of digested ore by HCl, uranium and thorium precipitation and crystallization of Na3PO4 which is by-product from this process. The model named RRDCMBP was prepared in Visual Basic language. The modelling program can be run on personal computer and it is interactive and easy to use. User is able to choose any equipment in each unit process and input data to get output of mass balance results. The model could be helpful in the process analysis for the further process adjustment and development.
Magnesium alloys are ideal candidates to benefit from equal channel angular extrusion (ECAE) because of their poor forming characteristics due to a hcp structure. In this study, ECAE processing was applied to ZK31 and AZ31 magnesium alloys under various conditions. The grain size of as-ECAE specimens decreases with decreasing the processing temperature, however, the grain size decreases slightly with increasing number of repetitive processing. Both the tensile strength and 0.2% proof stress of as-ECAE specimens are high when processed at low temperature, but the elongation is high when processed at high temperature. Crystal orientation is different in the two alloys and it also varies according to the processing temperature for the two alloys. The difference of the crystal orientation influences the tensile properties, especially 0.2% proof stress. (orig.)
An ion processing element employing composite media disposed in a porous substrate, for facilitating removal of selected chemical species from a fluid stream. The ion processing element includes a porous fibrous glass substrate impregnated by composite media having one or more active components supported by a matrix material of polyacrylonitrile. The active components are effective in removing, by various mechanisms, one or more constituents from a fluid stream passing through the ion processing element. Due to the porosity and large surface area of both the composite medium and the substrate in which it is disposed, a high degree of contact is achieved between the active component and the fluid stream being processed. Further, the porosity of the matrix material and the substrate facilitates use of the ion processing element in high volume applications where it is desired to ...
The papers collected in this volume were presented at the 4th Colloquium on Process Simulation held at Helsinki University of Technology, Espoo, Finland, June 11-13, 1997. In the more developed industrial nations, the processes for producing chemicals, energy, and materials encounter environmental concern and laws which challenge engineers to develop the processes towards more efficient, economical and safe operation. This necessitates more thorough understanding of the processes and phenomena involved. Formerly, the development of the processes was largely based on trial and error, whereas today, the development of computer performance together with the diversification of modelling software enables simulation of the processes. The increased capacity and possibilities for modelling the processes brought by the improved hardware and software, ...
Appendices to this summary consist of twelve individual status reports that will be available through the National Technical Information Service (NTIS) in the United States and of course limited copies will be available through NATO. The twelve report titles which are appendices to the summary are: (A) Status Report on the Limestone/Sludge Flue Gas Desulfurization Process; (B) Status Report on the Lime/Sludge Flue Gas Desulfurization Process; (C) Status Report on the Double Alkali/Sludge Flue Gas Desulfurization Process; (D) Status Report on the Sea Water Scrubbing Flue Gas Desulfurization Process; (E) Status Report on the Limestone/Gypsum Flue Gas Desulfurization Process; (F) Status Report on the Lime/Gypsum Flue Gas Desulfurization Process; (G) Status Report on the Double Alkali/Gypsum Flue Gas Desulfurization Process; (H) Status Report on ...
This paper presents anew design concept for a gamma irradiation plant for the continuous processing of pumpable liquids. Typical applications of such a plant include: the irradiation vulcanisation of natural latex rubber; disinfection of municipal sewage sludge for agricultural use; sterilisation of liquids in the pharmaceutical and cosmetics industries; industrial processing of bulk liquids The authors describe the design and operation of the latex irradiator now operating on a small production scale in Malaysia and proposed developments. The design allows irradiation processing to be carried out under an inert or other gaseous environment. State-of-the-art computer control system ensures the fully automatic processing operation needed by industrial computers.
The author outlines the special features of several coal liquefaction processes and describes their present stage of development. The following processes are reviewed: the SRC, EDS and H-Coal processes, the new IG process, and the BCL and NEDOL processes. The type of products resulting from coal liquefaction are discussed and explanations given of their yields. Finally, the characteristics of coal liquids are compared with those of petroleum-derived products, and the author outlines the nature of a chemical industry based on coal liquids as feedstocks. 9 references, 4 figures, 6 tables.
This volume contains the papers presented at the 1st International Workshop on "Decentralized Coordination of Distributed Processes", DCDP 2010, held in Amsterdam, The Netherlands on June 10th, 2010 in conjunction with the 5th International Federated Conferences on Distributed Computing Techniques, DisCoTec 2010. The central theme of the workshop is the decentralized coordination of distributed processes. Decentralized: there is no single authority in the network that everything is vulnerable to. Coordinated: processes need to cooperate to achieve meaningful results, potentially in the face of mutual suspicion. Distributed: processes are separated by a potentially unreliable network.
A fundamental and very well studied region of the Erd\\"os-R\\'enyi process is the phase transition at n/2 edges in which a giant component suddenly appears. We examine the process beginning with an initial graph. We further examine the Bohman-Frieze process in which edges between isolated vertices are more likely. While the positions of the phase transitions vary, the three processes belong, roughly speaking, to the same universality class. In particular, the growth of the giant component in the barely supercritical region is linear in all cases.
We show that a stationary IDp process (i.e., an infinitely divisible stationary process without Gaussian part) can be written as the independent sum of four stationary IDp processes, each of them belonging to a different class characterized by its L\\'{e}vy measure. The ergodic properties of each class are, respectively, nonergodicity, weak mixing, mixing of all order and Bernoullicity. To obtain these results, we use the representation of an IDp process as an integral with respect to a Poisson measure, which, more generally, has led us to study basic ergodic properties of these objects.
The heavy crude fraction processing is performed under very high vacuum to minimize thermal cracking which cause coke deposition and damage the equipment. The current tendency is to process heavier oil leading to higher process temperatures and consequently to greater fouling. This situation demands better knowledge fouling process by carbonization. This problem is pronounced in the residual gasoil region of a vacuum distillation unit because it obstructs the recirculation circuits and the spray system with serious environmental and economics implications. This paper review the main correlated published work related to coke generation and fouling and presents a discussion about the works. (author)
Consol R&D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-field: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.
Consol R&D is conducting a three-year program to characterize process and product streams from direct coal liquefaction process development projects. The program objectives are two-fold: (1) to obtain and provide appropriate samples of coal liquids for the evaluation of analytical methodology, and (2) to support ongoing DOE-sponsored coal liquefaction process development efforts. The two broad objectives have considerable overlap and together serve to provide a bridge between process development and analytical chemistry.
System identification is a necessity in control theory. Classical control theory usually considers processes with integer order transfer functions. Real processes are usually of fractional order as opposed to the ideal integral order models. A simple and elegant scheme is presented for approximation of such a real world fractional order process by an ideal integral order model. A population of integral order process models is generated and updated by PSO technique, the fitness function being the sum of squared deviations from the set of observations obtained from the actual fractional order process. Results show that the proposed scheme offers a high degree of accuracy.
The exergy method is used to compare different production processes and various methods for emission abatement with respect to their overall environmental impact. Some ammonium nitrate production processes are studied as examples, because the pollutants (ammonia and ammonium nitrate), emitted from these processes into the air and/or into the water, are really a feedstock and a product from the production process. Therefore, the essential result of the waste flows treatment is the recycling of the pollutants (ammonia and ammonium nitrate) back into the production process, decreasing simultaneously the exergy input and cumulative exergy consumption. (author)
We study a percolation process on the planted binary tree, where clusters freeze as soon as they become larger than some fixed parameter N. We show that as N goes to infinity, the process converges in some sense to the frozen percolation process introduced by Aldous. In particular, our results show that the asymptotic behaviour differs substantially from that on the square lattice, on which a similar process has been studied recently by van den Berg, de Lima and Nolin.
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The operation of industrial facilities has generally resulted in contamination of the surrounding soils and ground water. A variety of methods have been proposed for the remediation of contaminated sites. This paper presents new process technology that is capable of performing treatment on ground water or soil washing leachates. The process is targeted to treat low levels of radioactivity, organics and heavy metals present in the aqueous solutions, to be easily transported and provide simple operation on-site and provide an effluent that meets the specified discharge quality. The purification process involves sequential chemical treatment and filtration. The paper will describe the development of the technology and review the current progress in its use to remediate contaminated sites at Chalk River. The application of the process technology has demonstrated that the ambitious goal of setting the ...
The operation of industrial facilities has generally resulted in contamination of the surrounding soils and ground water. A variety of methods have been proposed for the remediation of contaminated sites. This paper presents new process technology that is capable of performing treatment on ground water or soil washing leachates. The process is targeted to treat low levels of radioactivity, organics and heavy metals present in the aqueous solutions, to be easily transported and provide simple operation on-site and provide an effluent that meets the specified discharge quality. The purification process involves sequential chemical treatment and filtration. The paper will describe the development of the technology and review the current progress in its use to remediate contaminated sites at Chalk River. The application of the process technology has demonstrated that the ambitious goal of setting the ...
Utilization of microwaves for heating purposes began in the 1940`s. This new form of energy transfer offers many distinct advantages over conventional heating, such as volumetric, fast, direct, selective, instantaneous, and controllable heating. Studies of microwave processing of polymeric materials in the early 1960`s led to a successful industrial application in the rubber industry. Since the mid-1980`s, there has been a great deal of interest in microwave processing of polymeric materials. Technical issues, such as temperature uniformity and control of thermal runaway during processing, were investigated and many successful laboratory scale results were obtained from both fundamental and processing studies. This paper presents a historical perspective of microwave heating in the processing of polymer composites and discusses possible future directions for technology ...
Process residues are generated at both the Rocky Flats Plant (RFP) and the Savannah River Plant (SRP) during aqueous chemical and pyrochemical operations. Frequently, process operations will result in either impure products or produce residues sufficiently contaminated with transuranics to be nondiscardable as waste. Purification and recovery flowsheets for process residues have been developed to generate solutions compatible with subsequent Purex operations and either solid or liquid waste suitable for disposal. The ''scrub alloy'' and the ''anode heel alloy'' are examples of materials generated at RFP which have been processed at SRP using the developed recovery flowsheets. Examples of process residues being generated at SRP for which flowsheets are under development include LECO crucibles and ...
A large portion of the work performed at nuclear power plants follows standardized flow paths. For example, although components on which the maintenance crew works differ from one assignment to the next, all assignments basically follow the same process: requesting, reviewing, planning, scheduling, executing, testing, and documenting the work. In general, the term open-quotes work processclose quotes is used to refer to a standardized sequence of tasks designed within the operational environment of an organization to achieve a specific goal. The predictable nature of work processes suggests that a systematic analysis can be conducted to identify the desirable design of the process and to develop performance measures with respect to the strengths and weaknesses in the process. Furthermore, because of the close relationship of the work process to plant performance and plant safety, it ...
Coal may be used to generate electrical energy by any of several processes, most of which involve combustion or gasification. Combustion in a coal-fired boiler and power generation using a steam-cycle is the conventional conversion method; however total energy conversion efficiencies for this type of process are only slightly over 30%. Integration of a gas-cycle in the process (combined cycle) may increase the total conversion efficiency to 40%. Conversion processes based on gasification offer efficiencies above 50%. H{sub 2}S is the predominant gaseous contaminant in raw coal gas. This process is concerned with the removal of H{sub 2} from coal gas through an electrochemical membrane technology.
An exergy analysis method is presented of the solar multi-effect humidification?dehumidification desalination (HDD) process. Pinch technology is used in the humidification process to determine the maximum possible saturated air temperature and the temperature of water rejected from the unit, and then the dehumidification process to determine the temperature of water leaving from the heat exchanger. The formulae to calculate the exergy of water and saturated air are given. The solar plane collector is used. From exergy analysis, the solar collector has the lowest exergy efficiency; the HDD process has a lower exergy efficiency, and the water rejected has also a large exergy loss. The energy and exergy recovery rate of the desalination process is also lower. The solar multi-effect HDD proces...
The unconventional technologies, currently applied at a certain category of materials, difficult to be processed through usual techniques, have undergone during the last 60 years all the stages, since their discovery to their use on a large scale. They are based on elementary mechanisms which run the processing through classic methods, yet, they use in addition the interconnections of these methods. This leads to a plus in performance by increasing the outcomes precision, reducing the processing time, increasing the quality of the finite product, etc. This performance can be much increased by using the computer and a software product in assisting the human operator in the processing by an unconventional method such as; the electric or electro-chemical erosion, the complex electric-electro-chemical erosion, the processing by a laser fascicle and so on. The present work presents such ...
Electromagnetic forming (EMF) is a forming process that relies on the inductive electromagnetic force to deform metallic workpiece at high speed. Calculation of the electromagnetic force is essential to understand the EMF process. However, accurate calculation requires complex numerical solution, in which the coupling between the electromagnetic process and the deformation of workpiece needs be considered. In this paper, an appropriate formula has been developed to calculate the electromagnetic force in metal work-piece in the sheet EMF process. The effects of the geometric size of coil, the material properties, and the parameters of discharge circuit on electromagnetic force are taken into consideration. Through the formula, the electromagnetic force at different time and in different positions of the workpiece can be predicted. The calculated electromagnetic force and magnetic field are in good ...
This paper presents a hybrid solar desalination process of the multi-effect humidification dehumidification and the basin-type unit. The sketch of the hybrid solar desalination process is given. The solar vacuated tube collector is employed in the desalination system, multi-effect humidification dehumidification desalination (HDD) process is plotted according to pinch technology, and then the water rejected from multi-effect HDD process is reused to desalinate in a basin-type unit further. The gain output ratio (GOR) of this system will rise by 2?3 at least through reusing the rejected water. The research proves that the multi-effect HDD has much room to be improved. A hybrid solar desalination process of the multi-effect humidification dehumidification and the basin-type unit should be no...
System identification refers to estimation of process parameters and is a necessity in control theory. Physical systems usually have varying parameters. For such processes, accurate identification is particularly important. Online identification schemes are also needed for designing adaptive controllers. Real processes are usually of fractional order as opposed to the ideal integral order models. In this paper, we propose a simple and elegant scheme of estimating the parameters for such a fractional order process. A population of process models is generated and updated by particle swarm optimization (PSO) technique, the fitness function being the sum of squared deviations from the actual set of observations. Results show that the proposed scheme offers a high degree of accuracy even when the observations are corrupted to a significant degree. Additional schemes to improve the ...
In the early sixties it was decided to investigate salt formations on its suitability to host heat generating radioactive waste in Germany. In the reference repository concept consequently the emplacement of vitrified waste canisters in deep vertical boreholes inside a salt mine was considered whereas spent fuel should be disposed of in self shielding casks (type POLLUX) in horizontal drifts. The POLLUX casks, 65 t heavy carbon steel casks, will be laid down on the floor of a horizontal drift in one of the disposal zones to be constructed in the salt dome at the 870 m level. The space between casks and drift walls will be backfilled with crushed salt. The transport, the handling und the emplacement of POLLUX casks were subject of successfully performed demonstration and in situ tests in the nineties and resulted in an adjustment of the atomic law. The borehole disposal concept comprises the emplacement of unshielded canisters with vitrified HLW in boreholes with a diameter of 60 cm and ...
Statistical design of experiments is widely used among scientists and engineers to understand influential factors in a laboratory or manufacturing process. One of the underlying principles of...Full Text Available
This document demonstrates the commercial status of the process units to be used in the Tri-State Synfuels Project at Henderson, Kentucky. The basic design philosophy as established in October, 1979, was to use the commercial SASOL II/III plants as a basis. This was changed in January 1982 to a plant configuration to produce gasoline via a methanol and methanol to gasoline process. To accomplish this change the Synthol, Oil workup and Chemical Workup Units were eliminated and replaced by Methanol Synthesis and Methanol to Gasoline Units. Certain other changes to optimize the Lurgi liquids processing eliminated the Tar Distillation and Naphtha Hydrotreater Units which were replaced by the Partial Oxidation Unit. The coals to be gasified are moderately caking which necessitates the installation of stirring mechanism in the Lurgi Dry Bottom gasifier. This work is in the demonstration phase. Process ...
This document demonstrates the commercial status of the process units to be used in the Tri-State Synfuels Project at Henderson, Kentucky. The basic design philosophy as established in October, 1979, was to use the commercial SASOL II/III plants as a basis. This was changed in January 1982 to a plant configuration to produce gasoline via a methanol and methanol to gasoline process. To accomplish this change the Synthol, Oil workup and Chemical Workup Units were eliminated and replaced by Methanol Synthesis and Methanol to Gasoline Units. Certain other changes to optimize the Lurgi liquids processing eliminated the Tar Distillation and Naphtha Hydrotreater Units which were replaced by the Partial Oxidation Unit. The coals to be gasified are moderately caking which necessitates the installation of stirring mechanism in the Lurgi Dry Bottom gasifier. This work is in the demonstration phase. Process ...
BackgroundProcessing of multimodal information is a critical capacity of the human brain, with classic studies showing bimodal stimulation either facilitating or interfering in perceptual...Full Text Available
The interactions between biochemical processes and mechanical signaling play important roles during various cellular processes such as wound healing, embryogenesis, metastasis, and cell migration. While...Full Text Available
Three flocks raised for broiler or roaster performance tests were studied to determine the incidence and sources of salmonellae during the growing period, transport and processing and to relate these...Full Text Available
This Mini-Computer-Assisted Nursing Management System allows nursing to control staffing costs and more effectively relate staffing to patient care requirements. Nursing resources are prospectively...Full Text Available
The Bureau of Mines performed chemical research to elaborate details of sulfur chemistry pertaining to the citrate flue gas desulfurization process in which sulfur dioxide (SO2), absorbed (as bisulfite ion) in a buffered sodium citrate solution, is reduce...
Instructional systems design is a process for assessing learning needs, creating instructional programs, and evaluating effectiveness of learning. We discuss the benefits of including instructional systems design theory and practice in the curriculum, with an emphasis on making the process relevant for student nurse anesthetists. PMID:10488275
A catalytic process for the oxidation of sulfur-containing gases , E.G., sulfur dioxide and simultaneous production of sulfuric acid wherein a sulfur-containing gas is reacted with an oxygencontaining gas in the presence of a catalyst comprising an iron group metal on a solid support comprising a zeolite in a silicaalumina matrix.
The melting unit, consisting of a water-cooled cupola furnace, afterburner, heat exchanger, air preheater, consumes most of the supplied energy in the rockwool process. The report maps the energy flows and defines factors of merit according to thermodynam...
Coordinated Research Project (CRP) was initiated in 2002 by IAEA to enable Member States in developing methodologies for reducing radio-toxic discharge to the environment from nuclear fuel cycle activities and in paving the way for sustainability of nuclear energy. In the past three Research Coordination Meetings (RCM), the following areas of research were examined upon: (1)Basic studies to compare dry partitioning process with aqueous partitioning process; (2)Defining proliferation resistance attributes of partitioning processes; (3) Advanced characterization methods for actinides for measuring the possible material holdup;( 4)Minimization of actinides losses in the waste fraction from the partitioning process;(5)Establishment of separation criteria of partitioning process to minimize environmental impact; and (6)Defining environmental impact associated with partitioning ...
Cultural monitoring was used to study the incidence and sources of salmonellae in a 4160 bird broiler flock during the growing period, transport and processing in a commercial plant. No salmonellae...Full Text Available
Since fuel oil meeting the requirements of current petroleum products can be produced by SASOL F-T synthetic process, the manufacturing process of hydrocarbon fuel oil from the coal-derived synthesis gas, downstream processes are being successively investigated. Mobile M-gasoline, MTG, process which produces gasoline from the natural gas-derived synthesis gas through methanol went into commercial operation in New Zealand in 1986. Although the gasoline suffices the quality of commercial gasoline by both fixed bed and fluidized bed systems, the price and service life of catalyst and control of by-product durene must be improved. Any STG processes have not been completed yet and the yield and quality of gasoline are inferior to those of gasoline produced by the MTG process. Applying two-stage process, the STG process will ...
Papers are presented in the areas of: Medical Technologies; Non-Destructive Evaluation; Applications of Signal/Image Processing; Laser Guide Star and Adaptive Optics; Computational Electromagnetic, Acoustics and Optics; Micro-Impulse Radar Processing; Optical Applications; TANGO Space Shuttle.
Limestone slurry needs to move efficiently through a complex process, meaning that selecting the right pumps and valves is critical. The article discusses factors to consider in selecting pumps and values for flue gas desulfurization process in coal-fired power plants. 2 photos.
A schematic diagram of the decision making process for air pollution control equipment for the conversion of a fossil-fired generating unit from oil to coal is presented and explained.
Administrative procedure connecting for licensing new materials or consumer products appropriated to radiosterilization have been performed and explained. Also the organization of irradiation process for attaining the proper result have been described in detail. 4 refs, 1 tab.
BackgroundThe evidence that red and processed meat influences colorectal carcinogenesis was judged convincing in the 2007 World Cancer Research Fund/American Institute of Cancer...Full Text Available
We have demonstrated that the SSSE pulverization process can convert multicomponent plastic waste into a powder with very promising properties. A variety of mixed color plastic chips have been pulverized.
This Process Waste Assessment was conducted to evaluate the two largest hazardous waste streams generated on-site at Sandia National Laboratory (SNL)/California -- ``Other Inorganic Solid Waste`` and ``Empty Containers <30 Gallons.``
Plasma nitriding as a diffusion process is the oldest plasma-assisted process for the surface treatment of metals. Although the use of this process in industry is already well developed and established there are still several scientific questions in the basic understanding of the process and consequently some problems and limits concerning its upscaling for industrial use. Therefore it is necessary to get reproducible results for different geometries of workpieces and for different workload sizes. Correlations between different plasma and treatment parameters, especially in big plants, have to be considered. To understand the process handling using some simple but impressive models the difficulties of treating single parts or mixed workloads are explained. For profitable applications of plasma nitriding plants, some guidelines for the use and selection of a suitable ...
BackgroundLittle is known about the role European patient organisations play in the process of deciding on reimbursement for medicines. Therefore we explore the...Full Text Available
Accomplishments for the quarter are presented for the following areas of research: oil shale, tar sand, coal, advanced exploratory process technology, and jointly sponsored research. Oil shale research includes; oil shale process studies, environmental base studies for oil shale, and miscellaneous basic concept studies. Tar sand research covers process development. Coal research includes; underground coal gasification, coal combustion, integrated coal processing concepts, and solid waste management. Advanced exploratory process technology includes; advanced process concepts, advanced mitigation concepts, and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO[sub 2] ...
Myelination is an important process in brain development, and delays or abnormalities in this process have been associated with a number of conditions including autism, developmental delay,...Full Text Available
Commercial development of oil shale resources will produce vast quantities of processed shale waste. The presence of potentially toxic trace elements, inorganic salts, and potentially toxic residual organic constitutents make the disposal of vast quantities of processed shale a potential environmental problem. To be environmentally acceptable, processed shale disposal must: result in a physically stable structure, prevent or minimize release of potentially toxic compounds, and provide an economically acceptable post-land use. Water is the common element underlying all factors important to the environmental stability of disposed solid waste. The leaching and transport of solubles by water in processed shale embankments may result in degradation of local surface and groundwater quality. The major purpose of this research is to physically model, study, and describe the redistribution and movement of water ...
BackgroundModeling of a complex biological process can explain the results of experimental studies and help predict its characteristics. Among such processes is transcription in...Full Text Available
A process for the recovery of nitrilotriacetic acid values from solutions containing polyvalent metal complexes of nitrilotriacetic and the decomposition products thereof is described, the process being characterized by the addition to such solutions of sufficient strong acid to dissociate the complex under conditions to precipitate the nitrilotriacetic acid.
Method for inhibiting the formation of foulants on petrochemical equipment which involves adding to the petrochemical, during processing, a composition comprising a thiodipropionate and either a dialkyl acid phosphate ester or a dialkyl acid phosphite ester.
A process is described for covering methane to a higher order hydrocarbon comprising contacting a gaseous reactant consisting of methane with a phosphate-containing catalyst for a sufficient period of time and at an effective temperature to provide the phosphate-containing catalyst consisting essentially of the higher order hydrocarbon. The catalyst is represented by a formula.
The paper demonstrates several ways that medical language processing can be combined with emerging display technologies to facilitate the extraction of data from free-text patient documents. The techniques...Full Text Available
To perform the localization project of WOLSUNG reactor fuel, mass-production system of irradiation-stable and sound fuel pellet must be established. The following subjects have been carried out to set up CANDU fuel fabrication process for continuous produ...
Two manufacturing processes have been developed for fabricating PLZT bonded lens assemblies (BLA's) for the USAF EEU-2/P Thermal/Flash Protective Goggle. One process utilizes thin Sylgard spacers which remain in the BLA to establish bond thickness between...
Ten subjects balanced their own body or a mechanically equivalent unstable inverted pendulum by hand, through a compliant spring linkage. Their balancing process was always characterized by repeated...Full Text Available
Laser-assisted processing techniques for producing high-quality solar cell metallization patterns are being investigated, developed, and characterized. The tasks comprising these investigations are outlined.
Processing of food with ionizing radiation is a method suitable to enhance shelf-life and hygienic quality. Up to a dose of 10 kGy the method is considered wholesome. In many countries the practical use of food irradiation is increasing, however, in the Federal Republic of Germany the process is strictly forbidden. Applications and methods for radiation processing of food are compiled, limits and prospects are explained, and advantages and disadvantages are compared with traditional methods. Identification of irradiated foods and dosimetry and process control for radiation processing of food are areas where further research is needed. Continuous processing of particulate foods in bulk is an application where electron accelerators might be profitable. Beam parameters and velocity distribution of food particles in the treatment area can be matched for an effective ...
The ability to determine the interval and duration of sensory events is fundamental to most forms of sensory processing, including speech and music perception. Recent experimental data support the notion...Full Text Available
Research programs, presented at the contractor's review meeting on indirect liquefaction, are presented on the following topics: oxygenates (methanol) synthesis; Fischer-Tropsch synthesis; product upgrading; and process support engineering evaluations. A total of 18 reports are included. Individual projects are processed separately for the data bases. (CBS)
An analysis is made of the manner in which the process of primordial black-hole formation and the subsequent accretion of gas depend on the equation of state. On the assumption that the process is spherically symmetric, the problem is solved numerically.
SummaryObjective:Formalizing clinical practice guidelines (CPGs) for a subsequent computer-supported processing is a challenging, but burdensome and...Full Text Available
The compromised abilities to localize sounds and to understand speech are two hallmark deficits in aged individuals. The auditory cortex is necessary for these processes, yet we know little...Full Text Available
An approach to the calculation of the quantity of heat consumed in the process of coal formation is presented. The variability of this parameter in a coalification series is analyzed using coals from the Kuznetsk and Tunguska Basins as an example.
A system and method for generating global asynchronous signals in a computing structure. Particularly, a global interrupt and barrier network is implemented that implements logic for generating global interrupt and barrier signals for controlling global asynchronous operations performed by processing elements at selected processing nodes of a computing structure in accordance with a processing algorithm; and includes the physical interconnecting of the processing nodes for communicating the global interrupt and barrier signals to the elements via low-latency paths. The global asynchronous signals respectively initiate interrupt and barrier operations at the processing nodes at times selected for optimizing performance of the processing algorithms. In one embodiment, the global interrupt and barrier network is implemented in a scalable, massively parallel ...
The author demonstrates through a specific example that it is possible to extract rotational energy from a Kerr source (in principle, of arbitrary size but not turned black) through a reversible process by suitably injecting tachyons. (Auth.).
The notes describe in detail primary and secondary galvanic cells, fuel cells, electrochemical synthesis and electroplating processes, corrosion: measurments, inhibitors, cathodic and anodic protection, details of metal dissolution reactions, Pourbaix diagrams and purification of waste water from galvanic industries.
The aim of this study is to develop an Automatic Post-processing Tool for four-dimensional (4D) treatment planning (APT4D) that enables the user to perform some necessary procedures related...Full Text Available
Liquid Phase Catalytic Exchange (LPCE)- Cryogenic Distillation(CD) process was studied which could be available for an optimal tritium removal process of pressurized heavy water reactor system at Wolsung nuclear power plant in the near future. Based upon ...
Proteins that metabolize or bind the nucleotide second messenger cyclic diguanylate regulate a wide variety of important processes in bacteria. These processes include motility, biofilm formation, cell...Full Text Available
This article describes the processes for the treatment of plastic waste: sampling, sorting, comminution. The requirements for the different processes for waste treatment (as recycling, utilization as raw material, energy recovery, combustion) are listed. (SR)
Quantitative metallography is often used to confirm the proper processing of aerospace metallic materials. A microstructural feature of great importance for titanium alloys processed in the alpha-beta phase field is the volume fraction of primary alpha. S...
The beater additive process for manufacturing combustible cartridge cases is superior to the solvent resin, post-impregnation process. However, the current beater additive resins do not produce as good a product as the solvent-resin system. The objective ...
DOE is supporting the development of several conversion processes that are currently in the pilot plant stage. Each of these processes is described briefly and information given as to contractor, contract, funding, site and current progress. Several support projects are treated similarly. (LTN)
At the St. Joe Minerals Corp.'s zinc smelter powerplant, an SO2 emission control program evolved into a cooperative program with the Bureau of Mines for installation and initial operation of a citrate process flue gas desulfurization demonstration plant. ...
Stomatal movements depend on both ion influx and efflux; attainment of steady state apertures reflects modulation of either or both processes. The role of Ca2+ in those two processes was...Full Text Available
BackgroundThe implementation of high throughput sequencing for exploring biodiversity poses high demands on bioinformatics applications for automated data processing. Here we introduce...Full Text Available
BackgroundAdipose tissue lipid storage and processing capacity can be a key factor for obesity-related metabolic disorders such as insulin resistance and diabetes. Lipid uptake is...Full Text Available
This article describes process evaluation methods for the Pool Cool Diffusion Trial across four years. Pool Cool is a skin cancer prevention program that was...Full Text Available
Pestiviruses are positive-strand RNA viruses closely related to human hepatitis C virus. Gene expression of these viruses occurs via translation of a polyprotein, which is further processed by cellular...Full Text Available
...that use the cellulose ether process to manufacture a particular cellulose ether. Cellulose food casing means a cellulose casing, which is manufactured using the viscose process, used in forming meat products (e.g., hot dogs,...
... The Effect of the Temperature to Which the Material is Heated on the Process of Formation of Intermetallic Compounds in Magnetic Pulse Welding,. ...
A process for the production of transportation fuels from heavy hydrocarbonaceous feedstock is provided comprising a two-stage, close-coupled process, wherein the first stage comprises a hydrothermal zone into which is introduced a mixture comprising a feedstock and red mud having coke-suppressing and demetalizing activity, and hydrogen; and the second, close-coupled stage comprises a hydrocatalytic zone into which substantially all the effluent from the first stage is directly passed and processed under hydrocracking conditions.
The production of oil by retorting shale and other hydrocarbonaceous and lignocellulosic solid materials is facilitated by retorting in the presence of steam and acetic acid.
In this article, a continuous stabilization process was used to make flame resistant fibers from polyacrylonitrile (PAN) fibers. The effect of the stabilization time and the stretching process during the stabilization process on the physical properties and flammability of the resultant flame resistant fibers was studied. Increased drawing of PAN fibers during the continuous stabilization process was found to decrease the diameter and increase the tensile strength in the resultant flame resistant fibers. These fibers also had higher density. There were no absolute relationships seen between flame-resistance and the formation of stable ladder polymers, density, and oxygen content. ((orig.))
... the application of an acousto- optical tunable filter ... Couplers for Large Switch-Array Applications ... Symmetric Integrated Optic X Junction," Electronics ...
A process for the production of transportation fuels from heavy hydrocarbonaceous feedstock is provided comprising a two-stage, close-coupled process, wherein the first stage comprises a hydrothermal zone into which is introduced a mixture comprising a feedstock and metals-impregnated red mud having coke-suppressing and demetalizing activity, and hydrogen; and the second, close-coupled stage comprises a hydrocatalytic zone into which substantially all the effluent from the first stage is directly passed and processed under hydrocatalytic conditions. The preferred metals for impregnation include transition metals, in particular, nickel and molybdenum.
Typical receiver processing, targeting always the best achievable bit error rate performance, can result in a waste of resources, especially, when the transmission conditions are such that the best performance is orders of magnitude better than the required. In this work, a processing framework is proposed which allows adjusting the processing requirements to the transmission conditions and the required bit error rate. It applies a-posteriori probability receivers operating over multiple-input multiple-output channels. It is demonstrated that significant complexity savings can be achieved both at the soft, sphere-decoder based detector and the channel decoder with only minor modifications.
... The task consisted of determination of the most economical composition of the charge of the cupola furnace of the foundry. 21s was no simple task. ...
... in the processes of production and, partic- ularly, product distribution and also by the increase in directive and disciplinary methods of intervention ...
Pittston Coal Company recognized the potential economic benefit of improving process efficiency with increased capacity at it`s U.K. No. 1 Coal Preparation Plant. Accordingly, extensive research, both domestically and internationally, was conducted to select the appropriate technologies to achieve the desired circuit in the most cost effective manner while, at the same time, sacrificing neither structural integrity nor process performance. Large diameter heavy media cyclone technology was combined with highly efficient banana type screens and improved high intensity magnetic separators to create a coordinated process circuit that provided high efficiency at very high capacities in an economically attractive package.
... in the Vicinity of Terminal Areas," Ph. ... WORDS Operations Research Stochastic processes Mathematical ... theory Aut',matic control Queueing theory ...
Low-dust flue gases can be washed efficiently of SO/sub 2/, and the flue gas heat can be utilized. The residual heat fraction still required by the process is characterized by a temperature of 15/sup 0/K above the temperature of the purified flue gas. Marketable crystalline ammonium sulfate is produced. The high efficiency and low heat consumption are achieved by combining all process stages in a single, fully integrated cycle process free of heat and materials losses. The process is characterized by high efficiency, low investment and operating costs, recovery of thermal energy, and production of an ammonium sulfate fertilizer.
The cathodic electrode process of Y(3+) ions on the Mo electrode in the LICl-KCl molten salt with YCl3(3wt%) in the temperature range of 450 - 530 deg. C has been investigated using cyclic voltammetry and chronopotentiometry. The convolution technique has been applied to the treatment of cyclic voltammogram. The results show that the reduction mechanism of Y(3+) ion is Y(3+) + 3e = Y, a simple one-step process. The cathodic process is very close to a reversible process under lower scanning rates, and is diffusion-controlled. The cathodic product is an insoluble product.
An alkaline-side solvent extraction process was developed for cesium removal from Savannah River Site (SRS) tank waste. The process was invented at Oak Ridge National Laboratory and developed and tested at Argonne National Laboratory using singlestage and multistage tests in a laboratory-scale centrifugal contactor. The dispersion number, hydraulic performance, stage efficiency, and general operability of the process flowsheet were determined. Based on these tests, further solvent development work was done. The final solvent formulation appears to be an excellent candidate for removing cesium from SRS tank waste.
... This work was based upon previously successful development of combustible cartridge cases, at Illinois Institute of Technology Research Institute ...
Surface quality is one of the most important criteria for establishing the optimum cutting parameters needed to perform a machining process. Usually, the evaluation of the degree of the surface finishing requires to apply metrological techniques which involve times out in the production. As a consequence of this, a loss in both the economy of the process and the fiability of the tests reproducibility can be produced. In this work a relation between cutting force and surface roughness has been studied for the turning process of an Al-Cu alloy. From this relation, the surface quality of the machined samples can be evaluated by using the cutting forces values acquired during the cutting process. (Author) 8 refs.
Computer processing was adopted to pick up significant signals from the undefined Moessbauer spectra. A program, by which smoothing and curve fitting was made possible, was devised and applied to the analysis of the Moessbauer spectra of "5"7Fe enriched iron and other specimens. Although this processing sometimes distorted the absorption peaks, it was quite effective for elimination of noise and finding of exact positions of absorption peaks. Availability of the processing was demonstrated by several examples obtained for "5"7Fe enriched iron, natural iron, calcined ferric oxyhydroxides, red mud residue and its calcined product. (auth.).
Development of a Comprehensive Decontamination Database and an Absorption-Electrochemical Metal Surface Decontamination Technique Combining Chemical and Electrochemical Process
The humidification?dehumidification process is an interesting technique that has been adapted for water desalination. Previous works experimentally investigated desalination processes in the shell and tube columns, where the humidification and dehumidification were thermally coupled and simultaneously performed at the tube and shell sides, respectively. In this work, a comprehensive steady-state mathematical model was developed for such a humidification?dehumidification desalination process by taking into account the heat and mass balances on both sides of the desalting column, the mass transfer rate at the humidification side, and the heat transfer rate between the dehumidification side and humidification side. Meanwhile, the mass transfer coefficient at the humidification side and the to...
... fields, materials can be subjected to energy densities exceeding those realized in high explosives, a fact which forms the basis for magnetic forming ...
A tissue culture process, organogenesis, is described which involves the stepwise production of a shoot apex, which grows to have leaves and stem and finally roots, culminating in the production of a complete plant. The production and subsequent development of numerous adventitious shoots, preferably from adult tree tissues offers the greatest potential for commercial cloned plantlet production. The process describes these steps for Pinus taeda, the loblolly pine. (Refs. 25).
Results of researches on nitriding process of EJ961 steel are presented in this work. This steel was subjected to nitriding both on the cathode and on the isolated from cathode and anode substrate, that is at so called potential of glow discharged plasma. Nitriding processes were performed using device for glow discharge treatments with cooled anode. (author)
The harmful effect of phosphate in yellow cake on the TBP purification process and its removal methods are dealed with. The reason of more uranium loss in residue was analyzed. The harmful effect of phosphate on TBP extraction efficiency and operaton of extraction column was discussed. The limit value of uranium concentration in digestion solution was presented. For TBP purification process, the presence of phosphate in yellow cake does more harm than good. (authors)
The need is substantiated for using remote control of technological processes on blowout dangerous beds. A method is proposed for this control based on recording with the help of AGZ apparatus for gas release into the roadway. Distinguishing features are indicated for the change in methane concentration in the roadway with normal occurrence of the process and in the case of blowout of coal and gas.
The principle for working out the time-temperature schedule of the carbonization was determined through the investigation on the carbonization process of the green body and the phenol formaldehyde resin. During the carbonization process, the crack at lower temperatures is due to strain inhomogeneity produced in press. But the crack at higher temperatures results from the improper increasing rate of temperature. The application of the autoclave-carbonization process can increase the mechanical properties of the spherical fuel elements.
Design process of steam generator and condenser at Russian nuclear power plant type WWER-1000 is identified. The four chapter of the books are organized as nuclear power plant, types of steam generators specially horizontal steam generator, process of steam generator design and the description of condenser and its process design.
A CMOS programmable picture processor with its own photodiode array is presented. The circuit is novel in that it includes an instruction set that permits most low-level picture processing operations. The chip is a parallel machine with a processing unit for each picture element. Images are binarized and are processed line by line. An experimental chip has been designed and is under fabrication. 2 references.
A borohydride, for instance sodium borohydride, is added to the radioactive effluent, with eventually a carrier such as Cu{sup +}, to give a precipitate containing ruthenium. The processing can be combined to Sr and Cs precipitation be know processes giving barium sulfate and nickel ferrocyamide precipitates. Influence of borohydride concentration on decontamination factor is given.
The author is exploring the efficiency of pulsed plasma processing in the removal of nitrogen dioxide, nitrogen oxide, and other pollutants. This process uses an electrical discharge to create chemical radicals from air molecules. These radicals can react with pollutants and form harmless compounds. Additives such as hydrocarbons are also used to improve the efficiency of the removal. The efficient removal of nitrogen dioxide has required the presence of dilute aqueous solution of ammonia.
The objective of Phase IV of the contract is to design a conceptual flue gas treating unit based on the fluidized-bed Copper Oxide (FBCO) process for a new coal-fired 500 MW(e) power plant. A technical and economic evaluation of the FBCO process, based on the conceptual design, will also be completed. Progress is described.
We report an observation of a delayed all-optical routing/switching phenomenon based on ultraslow group velocity of light via nondegenerate four-wave mixing processes in a defected solid medium. Unlike previous demonstrations of enhanced four-wave mixing processes using the slow light effects, the present observation demonstrates a direct retrieval of the resonant Raman-pulse excited spin coherence into photon coherence through coherence conversion processes.
A range of lessons have been identified from previous attempts to implement long term radioactive waste management policy in the UK and internationally. Many of these relate to the way the decision-making process is undertaken and the fact that there needs to be an open, transparent process that enables continuous stakeholder involvement. Nirex believes that using the SEA and EIA frameworks will help to incorporate the lessons learned into the future decision-making process relating to long-term radioactive waste management.
The Multiple Address Processing Unit (MAPU) of the AN/TGC-26 tape relay center was originally designed to process ACP 127 message format. With the advent of JANAP 128 as a standardized message format a pressing need was felt for a MAPU modification to all...
The bibliography contains citations concerning industrial uses and design of microwave heating equipment. Included are heating and drying of paper, industrial process heat, vulcanization, textile processing, metallurgical heat for sintering and ceramic manufacturing, food processing, and curing of polymers.(Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)
Epidemiological studies will not solve the shape of the dose effect curve for stochastic effects in the low dose range. Unicellular processes are necessary for the primary processes so that no threshold dose exists. This is evident for somatic and genetic mutations. Not clearly solved is this question for the complex carcinogenesis. These processes develop with manifold interacting molecular and cellular steps. (orig.).
The Tank Waste Remediation System (TWRS) Information Systems Definition architecture evaluated information Management (IM) processes in several key organizations. The intent of the study is to identify improvements in TWRS IM processes that will enable better support to the TWRS mission, and accommodate changes in TWRS business environment. The ultimate goals of the study are to reduce IM costs, Manage the configuration of TWRS IM elements, and improve IM-related process performance.
A diverse set of digital image-processing applications exists at the Lawrence Livermore National Laboratory. While many of these include some sort of image analysis or restoration, virtually all of them require image-enhancement procedures. In this paper we describe the principal image-processing facility at the Laboratory, followed by a discussion of several of the major image-processing application areas.
A tobermorite/hydroxyapatite composite was prepared by hydrothermal treatment using diatomaceous earth, ?-tricalcium phosphate and slaked lime starting materials. The XRD patterns of the composite confirmed that tobermorite and hydroxyapatite were formed after the hydrothermal process. The bending strength of the composite reached a level higher than 9?MPa after the hydrothermal process. The development of the bending strength was due to the formation of tobermorite and hydroxyapatite during the hydrothermal process. The composite had a high specific surface area due to these newly formed crystals.
This article examines the impact of mist-eliminator (ME) design and reliability on the performance of flue gas desulfurization (FGD) processes. ME failures are the second most common cause of FGD system outages. ME design also affects the chemistry of the FGD processes. The author considers the ME the linchpin of the whole FGD process system.
These guidelines discuss in more detail the radiological design review process used by the Project Hanford Management Contractors as described in HNF-PRO-1622, Radiological Design Review Process. They are intended to supplement the procedure by providing background information on the design review process and providing a ready source of information to design reviewers. The guidelines are not intended to contain all the information in the procedure, but at points, in order to maintain continuity, they contain some of the same information.
The report gives results of a comparison of results from a recent forced-oxidation limestone flue gas desulfurization (FGD) process evaluation and those from a conceptual design and economic evaluation of a sodium/limestone double-alkali FGD process, based on recent EPA-sponsored...
In connection with the ERP project 'Dynamic modelling of staged gasification processes' a gasification simulator has been constructed. The simulator consists of: a mathematical model of the gasification process developed at Technical University of Denmark, a user interface programme, IGSS, and a communication interface between the two programmes. (BA)
Digital optical processing (DOP) was conceived to encompass the advantages of both electronic and optical processors, which are parallelism, flexibility, and high accuracy. The authors discuss the concept of parallelism, how it applies to DOP differently than to electronic parallel processing, and other potential advantages in using DOP. A PLZT memory device is described which can perform a series of logic or memory operations. From several of these PLZT devices a DOP is constructed to illustrate some of its programmability features.
This paper describes the research and development activities in three areas of radiation processing, namely: food irradiation, medical product sterilization and wood plastic combination. Plans and efforts exerted to acquire a larger gamma source to augment our present 5,000 curie source are discussed. Cost estimates for a radiation facility are presented on the basis of the market potential of food irradiation and medical product sterilization. Existing local industries that can benefit from the adaptation of irradiation technology in their processing requirements are described.
For the first time in China, Daya Bay Nuclear Power Station applied the advanced technology of worldwide commercial pressurized reactors to the in-core detectors, the leading excore six-chamber instrumentation for precise axial power distribution, and the related data processing. Described in this article are the neutron flux measurement in Daya Bay Nuclear Power Station, and the detailed data processing.
This 4.5-year project consisted of routine analytical support to DOE`s direct liquefaction process development effort (the Base Program), and an extensive effort to develop, demonstrate, and apply new analytical methods for the characterization of liquefaction process streams (the Participants Program). The objective of the Base Program was to support the on-going DOE direct coal liquefaction process development program. Feed, process, and product samples were used to assess process operations, product quality, and the effects of process variables, and to direct future testing. The primary objective of the Participants Program was to identify and demonstrate analytical methods for use in support of liquefaction process development, and in so doing, provide a bridge between process design, and development, and operation ...
A new technology called a self-aligned metal-silicide process is described in the fabrication of silicon detectors. It has been found that this technology improves both detector yield and leakage current. The use of a metal silicide also gives a lower contact resistance and, depending on the thermal process, a controllable junction depth, which may be essential in the integration of detectors and their electronics.
An industrial EB processing line is started to produce cement-bound /CB/ chipboard with radiation cured acrylic coating. The basic features of this line are presented here. The main technological parameters of coating such as: effect of oligomer- and monomer reactivity, monomer functionality, dose-rate and inerting atmosphere on the progress of curing have been discussed. The EB processed CB board is an advanced composite material for the modern lightweight architecture.
We identify emission lines of post-iron peak elements in very high signal-to-noise spectra of a sample of planetary nebulae. Analysis of lines from ions of Kr and Xe reveals enhancements in most of the PNe, in agreement with the theories of s-process in AGB star. Surprisingly, we did not detect lines from Br even though s-process calculations indicate that it should be produced with Kr at detectable levels.
This paper discusses the economics of legumes irradiation such as Chickpea,Lupin,Kidny Bean and broad and the effect of various parameters on unit processing costs. It provides a model for calculating specific unit processing costs by correlating known capital costs with annual operation cost an annual throughputs. We analysed the cost-benefit of the proposed grain irradiation facility. We took into account the cost of the capital investment, operation and other additional parameters and then estimated the unit processing cost. The investment criteria utilized for commercial evaluation were internal rate of return (I.I.R), pay back period (P.B.P), and average rate of return (A.R.R). The irradiation cost and the additional income are also discussed. The results of this analysis showed that the installation of an irradiation unit for legumes processing in Egypt would be economically feasible.
A real-time two-dimensional void fraction distribution measurement of gas-liquid two-phase flow was carried out by real-time neutron radiography and real-time image processing. The JRR-3M real-time thermal neutron radiography system and a Musashi dynamic image processing system were used. Image processing methods to calculate two-dimensional and cross-sectional void fraction distributions were proposed. The void fraction distribution was calculated by non-linear processing of the neutron radiography image and displayed by pseudo-color in real-time. A simple gas-liquid two-phase flow induced by injecting gas through needles at the bottom of water pool in a rectangular vessel was tested. (orig.).
Based on the Weinberg-Salam theory, the competition of the Neutrino Energy Loss (NEL) rates due to the pair, photo- and plasma process are canvassed. The ratio factor C1, C2 and C3 which correspond the different contributions of the pair, photo- and plasma neutrino process to those of the total NEL rates are accurately taken into account. The ratio factors are very sensitive to the temperature and density. The ratio factor C2 always is lower than the ratio factor C1 and C3. The pair NEL process is the dominant contribution before the crossed point O(C1=C3=0.45) and the plasma NEL process will be the main dominant contribution after the crossed point O. With increasing temperature, the crossed point O will move to the direction of higher density. (authors)
Identity is one of the most important matters in social theory, especially in recent decades. Identity is a fluid phenomenon which forms in the process of every day activities. Individuals get practical knowledge of society to do intentional practices. They operate actively in identitizing process. Gender identity is one of important dimensions of individual identities constituting in social relations to others. Different socio-economic classes experience different social relations and engage in different identity processes. This research studies the formation process of feminine identity in the process of marriage (in contrast with the concept of virginity) in lower socio-economic classes of Bam. Body as site of identity and focus of close contact between agency and structure becomes the ...
This document reports on the work done by the Separations Science and Technology Programs of the Chemical Technology Division, Argonne National Laboratory, in the period April-September 1992. This effort is mainly concerned with developing the TRUEX process for removing and concentrating actinides from acidic waste streams contaminated with transuranic (TRU) elements. The objectives of TRUEX processing are to recover valuable TRU elements and to lower disposal costs for the nonTRU waste product of the process. Two other projects are underway with the objective of developing (1) a membrane-assisted solvent extraction method for treating natural and process waters contaminated by volatile organic compounds and (2) evaporation technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process.
Feasibility of using fixed bed column of conventional ion exchangers/sorbent and chemical precipitation based processes have been examined for the effective removal of the very low levels of 106Ru activity from NH4NO3 effluent generated during wet processing of rejected sintered depleted uranium fuel pellets. Based on the results, a simple process involving precipitation of cobalt sulphide along with ferric hydroxide was selected and further optimization of process variables was carried out. The optimized process has been found to be highly efficient in reducing 106Ru activity down to extremely low levels.
The present article will review recent advances in focused ion beam (FIB) technology. With increasing demands for scale of integration, microfabrication technology is becoming more important and various new microfabrication tools and processing techniques are desired. FIB is one of the promising tools for future microfabrication technology. This provides maskless patterning capability, which is of importance for process simplification, nanofabrication and in the development of in situ vacuum processing. In situ vacuum processing systems are being developed by combining FIB and a molecular beam epitaxy system. Radiation damage may limit applications of FIB. However, it was demonstrated that low energy FIB (<1 keV) with very high brightness was reached and promising results for low damage processing have been obtained. (orig.).
Electron beam (EB) processing involves using electrons to initiate polymerization or cross-linking reactions in suitable substrates, thereby enhancing specific physical and chemical properties. A relatively new use of EB processing is now emerging: the production of fibre-reinforced composites. EB curing at ambient temperature has the potential to reduce the residual stresses in an advanced composite, a result of expansion during thermal curing, and to significantly increase the overall cure speed and process throughput. Wood fibres are used as a filler material for various thermoplastics such as polypropylene. EB treatment, combined with selected EB-curable coupling agents, significantly increases the adhesion between the wood fibres and the thermoplastic polymer, resulting in improved material properties. Work to develop both products and processes for the EB curing of fibre-reinforced composites is ...
Actinide recycling by partitioning and transmutation is considered as one of the most promising strategies to reduce the inventory of radioactive waste, thus contributing to make nuclear energy sustainable. To make advances beyond the current state of the art in pyrochemical separations processes, the Domain 2 (DM2) of ACSEPT has been built on considering a process approach based on system studied. Four work packages that represent the main steps of a process block diagram have been identified: head-end steps, core process development, and salt treatment for recycling and waste conditioning. The results obtained in this domain will be integrated in DM 3 (Process) in order to orientate the R and D studies of DM2 and to propose and validate flowsheets at the end of the project. The state of the art on pyrochemical separation within the European Community and the working program of ...
We report on the improvement of Critical Dimension (CD) linearity on a photomask by applying the concept of process proximity correction to a laser lithographic process used for fabrication of photomasks. Rule-based Laser Process proximity Correction (LPC) was performed using an automated optical proximity correction tool and we obtained dramatic improvement of CD linearity on a photomask. A study on model-based LPC was executed using a two-Gaussian kernel function and we extracted model parameters for the laser lithographic process by fitting the model-predicted CD linearity data with measured ones. Model-predicted bias values of isolated space (I/S), Arrayed Contact (A/C) and Isolated Contact (I/C) were in good agreement with those obtained by the nonlinear curve-fitting method used for the rule-based LPC.
We report on the improvement of Critical Dimension (CD) linearity on a photomask by applying the concept of process proximity correction to a laser lithographic process used for fabrication of photomasks. Rule-based Laser Process proximity Correction (LPC) was performed using an automated optical proximity correction tool and we obtained dramatic improvement of CD linearity on a photomask. A study on model-based LPC was executed using a two-Gaussian kernel function and we extracted model parameters for the laser lithographic process by fitting the model-predicted CD linearity data with measured ones. Model-predicted bias values of isolated space (I/S), Arrayed Contact (A/C) and Isolated Contact (I/C) were in good agreement with those obtained by the nonlinear curve-fitting method used for the rule-based LPC.
The conventional Calzination-Reduction-Carburization (CRC) process offers the potential to manufacture commercial WC powders with median SEM grain sizes below 0.5 pm (ultra fine grades). Strict process control and a high degree of automation have led to increased powder uniformity and high lot-to-lot reliability. The high potential and flexibility of the CRC process is shown by the development of tailor made WC powders with regard to subsequent alloy manufacturing. R and D powders have successfully been processed in full-scale units exhibiting SEM grain sizes of 0.15 - 0.20 pm. This paper discusses the powder characteristics of various ultra fine WC powder grades, stemming from the conventional CRC process. Analytical characterization include also field-emission SEM, bright field TEM, EDX analysis and XRD-line broadening. (author)
Before electroless plating, polymer surfaces must be sensitized and/or activated by using either the conventional two-step or one-step process. The latter stage is a compulsory one to make such surfaces catalytic, e.g., for Ni-P deposition. These processes are performed here using O{sub 2}, NH{sub 3}, or N{sub 2} plasma pretreatments. Reaction mechanisms are proposed for each of the processes and for each type of surface considered (oxygenated or both oxygenated and nitrogenated by the plasma treatment). Direct palladium chemisorption onto nitrogenated groups is highlighted. This allows one to simplify the process making the surface catalytic via elimination of the use of SnCl{sub 2} and to extend the method to any polymer. An additional interest of the plasma treatments, besides their high efficiency in grafting chemical functions, is to perform this grafting at will on selected areas which results in ...
Nowadays, mixing is one of the most powerful tools for the process and products optimization in chemical process industries. The available technology can help in achieving almost any desired outcomes related to the process-side of the systems. This paper presents a practical methodology to improve existing agitation systems in order to overcome the constraints previously identified in the process. Well succeed real cases using this methodology in a petrochemical plant (Nitriflex S.A.) are presented. (author) 13 refs., 1 figs., 2 tabs.
This paper describes a state-of-the-art online monitoring system using multivariate statistical technologies for continuous steel casting process, which was commissioned at Dofasco's No. 2 caster to provide consistent indication of process health for caster's start-up, continuous production and transitional operations. The paper particularly focuses on development of a novel scheme to synchronize process trajectories for monitoring specific transitional operations such as equipment or steel product grade changes. The proposed scheme is demonstrated by several industrial examples with the results showing good detectability of various process abnormalities. With the aid of this fully integrated, innovative monitoring system, Dofasco has generated significant value through improved productivi...
Odor purification process using bio-function, which is technologically called bio-deodorizing process, utilizes the function of microorganism to convert mal-odor substances to non-odor substances. It attracts attention because the operation cost of a facility is low due to non-use of chemicals and energy, and because it is environmentally friendly without the possibility of generating secondary pollution. It is being used in deodorizing at sewage treatment facilities, fertilizer plants, coating plants, and foundries in Japan, and is more widely used in Europe. The conventional deodorizing technology in Japan mostly focuses on processes of physical chemistry such as activated carbon treatment, chemical scrubbing, combustion, and masking, but bio-deodorizing process tends to replace the conventional processes. This paper explains (1) relation of mal-odor and microorganism, (2) ...
A proposed metallization system for large area silicon solar cells with shallow junctions is outlined, and its desirable features are discussed. A baseline process sequence for the nickel palladium metallization system (NPMS) is delineated. This baseline process sequence is serving as the starting point from which process variations are being performed. The eventual goal is optimization of the NPMS process and determination of the control ranges for NPMS process variables. Initial studies of palladium displacement and electroless chemical plating solutions used in the baseline NPMS have begun and progress is reported. In support of this work, an annotated bibliography (45 citations) dealing primarily with palladium plating and palladium-silicon contact formation has been prepared (and will be subject to updating in the future reports).
A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale ...
A model is presented to account for the effects of ion-induced defects during implantation processing of Si. It will be shown that processing is quite generally affected by the presence of defect excesses rather than the total number of defects. a defect is considered excess if it represents a surplus locally of one defect type over its compliment. Processing spanning a wide range of implantation conditions will be presented to demonstrate that the majority of the total defects played little or no role in the process. This is a direct result of the ease with which the spatially correlated Frenkel pairs recombine either dynamically or during a post-implantation annealing. Based upon this model, a method will be demonstrated for manipulating or engineering the excess defects to modify their effects. In particular high-energy, self-ions are shown to inject vacancies into a boron implanted region resulting ...
We consider the exact path sampling of the squared Bessel process and some other continuous-time Markov processes, such as the CIR model, constant elasticity of variance diffusion model, and hypergeometric diffusions, which can all be obtained from a squared Bessel process by using a change of variable, time and scale transformation, and/or change of measure. All these diffusions are broadly used in mathematical finance for modelling asset prices, market indices, and interest rates. We show how the probability distributions of a squared Bessel bridge and a squared Bessel process with or without absorption at zero are reduced to randomized gamma distributions. Moreover, for absorbing stochastic processes, we develop a new bridge sampling technique based on conditioning on the first hitting time at zero. Such an approach allows us to simplify simulation schemes. New methods are ...
Part 1 of the Electric Utility Engineer`s Flue Gas Desulfurization (FGD) Manual emphasizes the chemical and physical processes that form the basis for design and operation of lime- and limestone-based FGD systems applied to coal- or oil-fired steam electric generating stations. The objectives of Part 1 are: to provide a description of the chemical and physical design basis for lime- and limestone-based wet FGD systems; to identify and discuss the various process design parameters and process options that must be considered in developing a specification for a new FGD system; and to provide utility engineers with process knowledge useful for operating and optimizing a lime- or limestone-based wet FGD system.
Continuing high rates of acidic deposition in the eastern United States may lead to long-term effects on stream communities, because sensitive catchments are continuing to lose anions and cations. A two-year study of the effects of pH and associated water chemistry variables on detrital processing in three streams with different bedrock geology in the Monongahela National Forest, West Virginia were investigated. Leaf pack processing rates and macroinvertebrate colonization and microbial biomass (ATP concentration) on the packs in the three stream were compared. It was found that macroinvertebrate and microbial communities differed both among streams that differed in their capacity to buffer the effects of acidic precipitation and among years in the same stream; these differences in biotic communities were not large enough to affect rates of leaf processing between the two years of the study, but they did significantly ...
In this paper, the multisource geoscientific data, such as TM data, NOAA data, the data of Bouguer gravity anomaly and aeromagnetic anomaly, the multisource geophysical processing methods, such as upward continuations, vertical derivative and gradient image, and synthetic image processing method - remote sensing image processing and geophysical image processing under I{sup 2}S600, are used to study the reverse faults or thrusts in the southern margin of Ordos basin, China. On the basis of these results and with geological investigation in the field, the authors have determined three thrust compression systems, named EW thrust compression system, NE thrust compression system and NW thrust compression system. These three systems reveal the regularity of geological structural evolution in the southern margin of Ordos basis and in the north side of Qinling Orogenic Belt.
The contribution of exchange processes (heavy stripping and substitution) into the amplitude of the 25-30 MeV #alpha#-particle elastic scattering by "1"2C and "4"0Ca nuclei is examined taking into account the distortion of plane waves of initial and finite particles. The eikonal approximation is used for accounting for distortions. The matrix elements of exchange processes are calculated. The results of calculations show that the Wronskian cutoff radii are close to those which have been obtained for calculation of exchange processes in the plane-wave approximation. The moduli of the values defining the contribution of exchange processes to the total S matrix are plotted. Also presented are Argand diagrams and angular distributions for both reactions. It has been established that the account for exchange processes improves the agreement of theoretical curves with the experiment in ...
A process for separation of actinides and technetium from reprocessing high level liquid waste has been developed, the CTH-process. The main parts are three consecutive solvent extraction cycles followed by an optional step for sorption on inorganic ion exchangers. The first extraction cycle removes and recovers uranium, neptunium, and plutonium by extraction with HDEHP. The second extraction cycle separates technetium and nitric acid from the waste using TBP. In the third extraction cycle Am and Cm are separated from the waste using HDEHP. The actinide free waste is then passed through inorganic ion exchangers to remove most of remaining radionuclides. The process has been tested on an authenic HLLW solution. A decontamination factor > 10/sup 5/ for alpha emitters was measured for the solvent extraction process and the sorption on inorganic ion exchangers gave a decontamination factor > 3x10/sup ...
A multivariate bioprocess control approach, capable of tracking a pre-set process trajectory correlated to the biomass or product concentration in the bioprocess is described. The trajectory was either a latent variable derived from multivariate statistical process monitoring (MSPC) based on partial least squares (PLS) modeling, or the absolute value of the process variable. In the control algorithm the substrate feed pump rate was calculated from on-line analyzer data. The only parameters needed were the substrate feed concentration and the substrate yield of the growth-limiting substrate. On-line near-infrared spectroscopy data were used to demonstrate the performance of the control algorithm on an Escherichia coli fed-batch cultivation for tryptophan production. The controller showed good ability to track a defined biomass trajectory during varying process dynamics. The robustness of the control was ...
Readout integrated circuits (ROICs) for focal plane arrays (FPAs) have become increasingly complex to meet the needs of modern infrared systems. BAE Systems has pioneered a number of advanced signal processing architectures for FPA ROICs. Demonstrated signal processing capabilities of BAE Systems FPAs include analog-to-digital conversion, offset subtraction, individual pixel automatic gain compensation, transient noise suppression, on-FPA defect deselection, reconfigurable pixels, spatial neural network processing and subframe noise averaging. BAE Systems FPA advanced signal processing is not just for demonstrations, but is used in many of their deliverable FPAs, improving real system performance.
A computerised gamma scanning facilities for on-line investigation of industrial process columns and vessels has been developed by the Malaysian Nuclear Agency (Nuclear Malaysia). The technology, based on the principle of gamma-ray absorption, has been successfully applied for real-time troubleshooting, process investigation and predictive maintenance of a number of distillation columns and process vessels in petroleum refineries, gas processing plants and chemical plants in the country and the surrounding region. This paper outlines basic characteristics of the system and describes the inspection procedures, and in addition, presents a number of case studies. The case studies are purposely chosen to illustrate the versatility of the technology, and furthermore to demonstrate the economic benefits which can be realised from the application of this technology. (Author)
A concept for the optimization of manufacturing processes of composite material components with regard to product's quality and cost is introduced and applied for the case of thermoplastic composite helicopter canopies produced by `Cold' Diaphragm Forming (CDF) process. The proposed methodology relies on the consideration of the processes thermal cycle as decisive for the component's quality and cost. Quality and cost sensitivity analyses were made to derive material dependent Quality Functions (QFs) and process dependent Cost Estimation Relationships (CERs). QFs and CERs are exploited to derive iteratively the optimal thermal cycle. The processes thermal cycle is numerically simulated to allow for its virtual application on the material. To perform the optimization procedure a new softwar...
As coal becomes more and more important as a power plant fuel in this time of energy shortage and the combustion of high-sulfur coals that would impair air quality, efforts have been made to devise efficient processes to control sulfur dioxide emission. Besides desulfurization before combustion, flue gas desulfurization is considered the most promising method that could also be applicable to all other fossil fuels. In this article, the flue gas desulfurization processes are briefly reviewed, and processes with highest use and with high potential for future use are compared from technical and economical points of view. In the selection of a desulfurization process, it is very important to consider the capacity of the plant, fuel type and fuel-to-sulfur ratio, availability and price of the reagent to be used, type, price, and market of side products, disposal problems of wastes, and environmental factors.
The advancement of bioprocess monitoring will play a crucial role to meet the future requirements of bioprocess technology. Major issues are the acceleration of process development to reduce the time to the market and to ensure optimal exploitation of the cell factory and further to cope with the requirements of the Process Analytical Technology initiative. Due to the enormous complexity of cellular systems and lack of appropriate sensor systems microbial production processes are still poorly understood. This holds generally true for the most microbial production processes, in particular for the recombinant protein production due to strong interaction between recombinant gene expression and host cell metabolism. Therefore, it is necessary to scrutinise the role of the different cellular compartments in the biosynthesis process in order to develop comprehensive ...
A post-irradiation annealing study was conducted with use of reactor pressure vessel(RPV) steel A533B C1.1 base metal irradiated to a dose of 4.84x10"1"8 n/cm"2 at about 380 deg C. Microhardness and positron annihilation (PA) methods were used to obtain better understanding of the recovery of radiation hardening. Isochronal anneal experiments indicated that two recovery processes occur during annealing of irradiated specimens. The first recovery process occurs in the temperature of 280-305 deg C. The variations of Ip, Iw and R parameters indicated that the formation of vacancy clusters by vacancy aggromeration and the annihilation parameters measured indicated that the dissolution of carbon atoms decorated around vacancy-type defects and possible precipitates, and the annihilation of monovacancies give rise to the second recovery process. It was further indicated that radiation anneal hardening (RAH) in the range of 305-405 ...
In many facilities, energy management is simply a matter of managing the energy required for lighting and space conditioning. In many others, however, energy management is much more complex and involves large motors and controls, industrial insulation, complex combustion monitoring, unique steam distribution problems, significant amounts of waste heat, etc. Typical facilities offering large energy management opportunities include industrial facilities, large office and commercial operations, government institutions such as schools, hospitals and prisons. Such facilities generally have specialized industrial, commercial or institutional processes that incorporate many of the concepts covered in other chapters. These processes require thorough analytical evaluations to determine the appropriate energy-saving measures. This chapter provides some examples. In this chapter the authors present a suggested procedure for process ...
The overall goal of this work is to design and optimize a biodiesel production process from soybean oil. To achieve this goal, several inter-connected activities were undertaken. First, an initial flowsheet for the process was synthesized. The performance of this flowsheet along with the key design and operating criteria were identified by conducting computer-aided simulation using ASPEN Plus. Various scenarios were simulated to provide sufficient understanding and insights and to select a base-case flowsheet. Next, mass and energy integration studies were performed to reduce the consumption of material and energy utilities, improve environmental impact, and enhance profitability. Capital cost estimation was carried out using the ICARUS Process Evaluator computer-aided tool linked to the results of the ASPEN Plus simulation. The operating cost of the process was estimated using the key information on ...
Hydrocarbon Research, Inc. (HRI) has been actively involved in the development of a low-severity two-stage coal liquefaction process. Since inception of the concept of low-temperature, first-stage hydrogenation followed by a higher temperature second-stage hydrocracking operation, in 1982, efforts have been concentrated on this process. This final report covers development efforts under both contracts from October 1983 to March 1988. The major objective was to reduce process severity and improve economics. Studies were conducted on Illinois No. 6 and Ohio No. 5/6 bitumen coals and included several process variable experiments, catalyst testing, use of cleaned coal and evaluation process recycle options. The total effort included 277 days onstream of continuous bench-scale operations, and data analysis and process modeling, and engineering design and economic ...
Natural sunlight induces a genotoxic response in cultured CHO cells pre-treated with shale oil retort process water. Near ultraviolet light (NUV) component of the solar spectrum is the apparent radiation responsible for photoactivation. Cultured human skin fibroblasts are acutely sensitive to the genotoxic effects of photoactivated process water. The mutagenic potential of photoactivated process water in human cells is the same as that witnessed for an equivalent killing dose of the potent skin carcinogen FUV. DNA repair processes are involved in modulating genotoxic effects of this photo-induced process. The exact magnitude of the potential health-related and environmental risks resulting from photoactivation of retort process waters and other oil shale by-products is unassessed at this time. Our demonstration that a significant rate of mutation occurs in ...
The partitioning of transuranium elements (TRUs) from high-level liquid waste (HLLW) through the use of pyrometallurgical technology has been underway since 1986, for the purpose of the improving the safety and public acceptance of the disposal of high-level vitrified waste. Prior to the pyrometallurgical partitioning process, the alkali metals can be separated at the denitration process for oxide conversion of HLLW, chlorination in a chloride salt bath can be used to effectively convert oxides to chlorides, and evaporated chlorides can be captured with high efficiency in another adopted chloride salt bath. The higher separation factors between actinides and rare earths are obtained in a LiCl-KCl/Bi system than in a LiCl-KCl/Cd system. Based on the results, we propose a practical process flow for partitioning TRUs from HLLW by pyrometallurgical technology. This process was demonstrated successfully ...
The localized Pt deposition on Si by 30 keV Ga"+ focused ion beam (FIB), 10 keV electron beam (EB) or dual beams (FIB and EB) using precursor gas has been compared by analysis using a 300 keV Be"2"+ microprobe with a beam spot size of 80 nm. The distribution of deposited Pt, Ga from the ion beam itself, and C from the precursor gas was obtained at and nearby the deposited areas by micro-RBS spectra and RBS mapping. All of the beam processed areas showed a uniform Pt distribution at the deposited areas. The amount of Pt atoms increased with the increase in ion or electron dose due to the decomposition of precursor gas. The thickness of Pt layer by EB is considerably less than that by FIB due to the reduced deposition rate. Ga atoms from the center of processed areas partly redeposited at and nearby the FIB processed areas within #approx#3 #mu#m. The Ga incorporation by dual beam processing was reduced ...
The Savannah River Site (SRS) is currently developing a new facility, the Actinide Packaging and Storage Facility (APSF), to process and store legacy materials from the United States nuclear stockpile. A variety of materials, with a variety of properties, packaging and handling/storage requirements, will be processed and stored at the facility. Since these materials are hazardous and radioactive, automation will be used to minimize worker exposure. Other benefits derived from automation of the facility include increased throughput capacity and enhanced security. The diversity of materials and packaging geometries to be handled poses challenges to the automation of facility processes. In addition, the nature of the materials to be processed underscores the need for safety, reliability and serviceability. The application of automation in this facility must, therefore, be accomplished in a rational and ...
This paper investigated the effect of hydrogen (H{sub 2}) addition on the combustion process of a heavy-duty diesel engine. The addition of a small amount of H{sub 2} was shown to have a mild effect on the cylinder pressure and combustion process. When operated at high load, the addition of a relatively large amount of H{sub 2} substantially increased the peak cylinder pressure and the peak heat release rate. Compared to the two-stage combustion process of diesel engines, a featured three-stage combustion process of the H{sub 2}-diesel dual fuel engine was observed. The extremely high peak heat release rate represented a combination of diesel diffusion combustion and the premixed combustion of H{sub 2} consumed by multiple turbulent flames, which substantially enhanced the combustion process of H{sub 2}-diesel dual fuel engine. However, the addition of a relatively large amount of ...
This report summarizes the work that was completed in FY 1992 on the program {open_quotes}Technology Development for Concentrating Process Streams.{close_quotes} The purpose of this program is to evaluate and develop evaporator technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process. Concentrating these streams and minimizing the volume of waste generated can significantly reduce disposal costs; however, equipment to concentrate the streams and recycle the decontaminated condensates must be installed. LICON, Inc., is developing an evaporator that shows a great deal of potential for this application. In this report, concepts that need to be incorporated into the design of an evaporator operated in a radioactive environment are discussed. These concepts include criticality safety, remote operation and maintenance, and materials of construction. Both solubility and vapor-liquid equilibrium ...