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Sample records for long-fiber injection-molded thermoplastics

  1. Injection-Molded Long-Fiber Thermoplastic Composites: From Process Modeling to Prediction of Mechanical Properties

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Ba Nghiep; Kunc, Vlastimil; Jin, Xiaoshi; Tucker III, Charles L.; Costa, Franco

    2013-12-18

    This article illustrates the predictive capabilities for long-fiber thermoplastic (LFT) composites that first simulate the injection molding of LFT structures by Autodesk® Simulation Moldflow® Insight (ASMI) to accurately predict fiber orientation and length distributions in these structures. After validating fiber orientation and length predictions against the experimental data, the predicted results are used by ASMI to compute distributions of elastic properties in the molded structures. In addition, local stress-strain responses and damage accumulation under tensile loading are predicted by an elastic-plastic damage model of EMTA-NLA, a nonlinear analysis tool implemented in ABAQUS® via user-subroutines using an incremental Eshelby-Mori-Tanaka approach. Predicted stress-strain responses up to failure and damage accumulations are compared to the experimental results to validate the model.

  2. An Integrated Approach Linking Process to Structural Modeling With Microstructural Characterization for Injections-Molded Long-Fiber Thermoplastics

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Ba Nghiep; Bapanapalli, Satish K.; Smith, Mark T.; Kunc, Vlastimil; Frame, Barbara; Norris, Robert E.; Phelps, Jay; Tucker III, Charles L.; Jin, Xiaoshi; Wang, Jin

    2008-09-01

    The objective of our work is to enable the optimum design of lightweight automotive structural components using injection-molded long fiber thermoplastics (LFTs). To this end, an integrated approach that links process modeling to structural analysis with experimental microstructural characterization and validation is developed. First, process models for LFTs are developed and implemented into processing codes (e.g. ORIENT, Moldflow) to predict the microstructure of the as-formed composite (i.e. fiber length and orientation distributions). In parallel, characterization and testing methods are developed to obtain necessary microstructural data to validate process modeling predictions. Second, the predicted LFT composite microstructure is imported into a structural finite element analysis by ABAQUS to determine the response of the as-formed composite to given boundary conditions. At this stage, constitutive models accounting for the composite microstructure are developed to predict various types of behaviors (i.e. thermoelastic, viscoelastic, elastic-plastic, damage, fatigue, and impact) of LFTs. Experimental methods are also developed to determine material parameters and to validate constitutive models. Such a process-linked-structural modeling approach allows an LFT composite structure to be designed with confidence through numerical simulations. Some recent results of our collaborative research will be illustrated to show the usefulness and applications of this integrated approach.

  3. Assessment of Current Process Modeling Approaches to Determine Their Limitations, Applicability and Developments Needed for Long-Fiber Thermoplastic Injection Molded Composites

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Ba Nghiep; Holbery, Jim; Smith, Mark T.; Kunc, Vlastimil; Norris, Robert E.; Phelps, Jay; Tucker III, Charles L.

    2006-11-30

    This report describes the status of the current process modeling approaches to predict the behavior and flow of fiber-filled thermoplastics under injection molding conditions. Previously, models have been developed to simulate the injection molding of short-fiber thermoplastics, and an as-formed composite part or component can then be predicted that contains a microstructure resulting from the constituents’ material properties and characteristics as well as the processing parameters. Our objective is to assess these models in order to determine their capabilities and limitations, and the developments needed for long-fiber injection-molded thermoplastics (LFTs). First, the concentration regimes are summarized to facilitate the understanding of different types of fiber-fiber interaction that can occur for a given fiber volume fraction. After the formulation of the fiber suspension flow problem and the simplification leading to the Hele-Shaw approach, the interaction mechanisms are discussed. Next, the establishment of the rheological constitutive equation is presented that reflects the coupled flow/orientation nature. The decoupled flow/orientation approach is also discussed which constitutes a good simplification for many applications involving flows in thin cavities. Finally, before outlining the necessary developments for LFTs, some applications of the current orientation model and the so-called modified Folgar-Tucker model are illustrated through the fiber orientation predictions for selected LFT samples.

  4. Injection molding of thermoplastic elastomers for microstructured substrates

    Science.gov (United States)

    Birkar, Smita

    Amorphous and semi-crystalline thermoplastic polymers have been widely investigated for injection molding of parts with microstructured surfaces. Microstructured surfaces injection molded from thermoplastic elastomers have emerging applications as superhydrobic surfaces and patterned adhesives, but there is a limited understanding of the factors affecting replication with these materials. This research was a continued investigation of block copolymer thermoplastic elastomers as well as the first in-depth examination of thermoplastic vulcanizates for injection molding microfeatures. The first focus of this research was the interactions between tooling aspect ratio and feature orientation (negative and positive tooling) and thermoplastic elastomer hard segment content on microfeature replication. Electroformed nickel tooling having positive and negative features with different geometries and aspect ratios of 0.02:1 to 2:1 were molded from three copolyester thermoplastic elastomers with similar chemistry and different hardness values. The tooling and part features were characterized for feature depth and height as well as feature definition using scanning electron microscopy and optical profilometry. Results were correlated with elastomer properties. In the second parts of this research, the effects of microfeature spacing on the replication of thermoplastic elastomer features was investigated using micropillars with two diameters (10 and 20 mum) and three spacing ratios (0.5:1, 1:1, and 2:1). The tooling and part features were characterized for feature depth and height as well as feature definition using scanning electron microscopy and optical profilometry. Feature spacing significantly affected the replication of micropillars using a thermoplastic elastomer. This replication was competition between cooling and pressurization of the melt. Wider spacing between smaller features allowed cooling in the tooling lands to dominate the feature filling. Higher pressures did not always produce better feature replication, suggesting that cooling effects in the tooling "holes" restricted filling. High pressures also produced surface porosity in the molded pillars. Although thermoplastic vulcanizates, thermoplastic elastomers with excellent processability and flexibility, are a widely used for over molding and automotive applications, the third section of this research was the first in-depth investigation of injection molding thermoplastic vulcanizates to create microstructured surfaces. In this study, nickel cobalt tooling was used to mold commercially-available thermoplastic vulcanizates with polypropylene/ethylene propylene diene monomer (PP/EPDM) backbones into 20-mum-diameter and 100-mum-wide features. These results were compared to those for a polypropylene homopolymer. The primary molding parameters, including melt and mold temperatures were evaluated for their effects on microfeature replication. Additionally, a two-level, three-factorial design of experiments was conducted to further evaluate the effects of key parameters (cooling time, hold pressure, and polymeric material) on the feature definition and depth ratios of the molded microfeatures. These results were compared to the properties of the thermoplastic vulcanizates.

  5. Modeling morphology evolution during injection molding of thermoplastic polymers

    Science.gov (United States)

    Pantani, R.; De Santis, F.; Speranza, V.; Titomanlio, G.

    2015-05-01

    The effect of temperature, pressure and flow on relaxation time (or spectrum), crystallization time, nucleation density and rate, spherulite growth rate, the interrelation among these quantities and the distributions of deformation rate and cooling time during the process all together determine the morphology distribution in the final object. A simple model linking all these quantities was developed to describe morphology evolution during polymer processing. The effect of flow on nucleation density and growth rate of an isotactic polypropylene (iPP) is described on the basis of a molecular stretch parameter and the stretch evolution is described by a simple nonlinear Maxwell model, whose relaxation time, in its turn, is determined by the molecular stretch and, obviously, temperature pressure and crystallinity [1]. The model is applied to the description of morphology evolution during the injection molding process of a very accurately characterized iPP as far as rheology, quiescent crystallization and effect of flow on nucleation and spherulitic growth rates. Main characteristics of final morphology are reproduced by the simulations.

  6. Modeling of the injection of loaded thermoplastic mixtures with application in metal injection molding

    International Nuclear Information System (INIS)

    The study is focussed on the modeling and numerical simulation of the loaded thermoplastic mixtures currently used in metal injection molding. Due to the fact that the mixture is highly concentrated in metallic powders, the models based on the homogenization theory and using an equivalent viscosity are no longer suitable. So a biphasic formulation has been developed to describe the flow of such mixtures. An interaction term between powder and thermoplastic fluid polymer accounts for segregation or debinding effects. In this type of the problem, the solid phase fraction is a key fields variable. The associated equations are solved separately for each phase taking into account interactions and coupling effects. A general solver in 2D and 3D has been developed that account propagation of fluid front by the extension to biphasic cases of the VOF method. For solving the velocity/pressure problem the fractional step method has been extended to the biphasic cases. Numerical simulations have been compared to the experimental results obtained by a using multiple cavity with pressure and temperature sensors. Comparisons between numerical simulation results and experiments show good agreements in terms of pressure and temperature evolutions during molding. It is also demonstrated that the numerical results are accurate and sensitive to variation of the injection molding marameters. (author)

  7. Numerical prediction of fiber orientation in injection-molded short-fiber/thermoplastic composite parts with experimental validation

    Science.gov (United States)

    Thi, Thanh Binh Nguyen; Morioka, Mizuki; Yokoyama, Atsushi; Hamanaka, Senji; Yamashita, Katsuhisa; Nonomura, Chisato

    2015-05-01

    Numerical prediction of the fiber orientation in the short-glass fiber (GF) reinforced polyamide 6 (PA6) composites with the fiber weight concentration of 30%, 50%, and 70% manufactured by the injection molding process is presented. And the fiber orientation was also directly observed and measured through X-ray computed tomography. During the injection molding process of the short-fiber/thermoplastic composite, the fiber orientation is produced by the flow states and the fiber-fiber interaction. Folgar and Tucker equation is the well known for modeling the fiber orientation in a concentrated suspension. They included into Jeffrey's equation a diffusive type of term by introducing a phenomenological coefficient to account for the fiber-fiber interaction. Our developed model for the fiber-fiber interaction was proposed by modifying the rotary diffusion term of the Folgar-Tucker equation. This model was presented in a conference paper of the 29th International Conference of the Polymer Processing Society published by AIP conference proceeding. For modeling fiber interaction, the fiber dynamic simulation was introduced in order to obtain a global fiber interaction coefficient, which is sum function of the fiber concentration, aspect ratio, and angular velocity. The fiber orientation is predicted by using the proposed fiber interaction model incorporated into a computer aided engineering simulation package C-Mold. An experimental program has been carried out in which the fiber orientation distribution has been measured in 100 x 100 x 2 mm injection-molded plate and 100 x 80 x 2 mm injection-molded weld by analyzed with a high resolution 3D X-ray computed tomography system XVA-160?, and calculated by X-ray computed tomography imaging. The numerical prediction shows a good agreement with experimental validation. And the complex fiber orientation in the injection-molded weld was investigated.

  8. Numerical prediction of fiber orientation in injection-molded short-fiber/thermoplastic composite parts with experimental validation

    Energy Technology Data Exchange (ETDEWEB)

    Thi, Thanh Binh Nguyen; Morioka, Mizuki; Yokoyama, Atsushi [Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585 (Japan); Hamanaka, Senji; Yamashita, Katsuhisa; Nonomura, Chisato [Research Center, Toyobo Co., LTD, 2-1-1 Katata, Otsu, Shiga 520-0292 (Japan)

    2015-05-22

    Numerical prediction of the fiber orientation in the short-glass fiber (GF) reinforced polyamide 6 (PA6) composites with the fiber weight concentration of 30%, 50%, and 70% manufactured by the injection molding process is presented. And the fiber orientation was also directly observed and measured through X-ray computed tomography. During the injection molding process of the short-fiber/thermoplastic composite, the fiber orientation is produced by the flow states and the fiber-fiber interaction. Folgar and Tucker equation is the well known for modeling the fiber orientation in a concentrated suspension. They included into Jeffrey’s equation a diffusive type of term by introducing a phenomenological coefficient to account for the fiber-fiber interaction. Our developed model for the fiber-fiber interaction was proposed by modifying the rotary diffusion term of the Folgar-Tucker equation. This model was presented in a conference paper of the 29{sup th} International Conference of the Polymer Processing Society published by AIP conference proceeding. For modeling fiber interaction, the fiber dynamic simulation was introduced in order to obtain a global fiber interaction coefficient, which is sum function of the fiber concentration, aspect ratio, and angular velocity. The fiber orientation is predicted by using the proposed fiber interaction model incorporated into a computer aided engineering simulation package C-Mold. An experimental program has been carried out in which the fiber orientation distribution has been measured in 100 x 100 x 2 mm injection-molded plate and 100 x 80 x 2 mm injection-molded weld by analyzed with a high resolution 3D X-ray computed tomography system XVA-160?, and calculated by X-ray computed tomography imaging. The numerical prediction shows a good agreement with experimental validation. And the complex fiber orientation in the injection-molded weld was investigated.

  9. Effect of starch types on properties of biodegradable polymer based on thermoplastic starch process by injection molding technique

    Directory of Open Access Journals (Sweden)

    Yossathorn Tanetrungroj

    2015-04-01

    Full Text Available In this study effects of different starch types on the properties of biodegradable polymer based on thermoplastic starch (TPS were investigated. Different types of starch containing different contents of amylose and amylopectin were used, i.e. cassava starch, mungbean starch, and arrowroot starch. The TPS polymers were compounded and shaped using an internal mixer and an injection molding machine, respectively. It was found that the amount of amylose and amylopectin contents on native starch influence the properties of the TPS polymer. A high amylose starch of TPMS led to higher strength, hardness, degree of crystallization than the high amylopectin starch of TPCS. In addition, function group analysis by Fourier transforms infrared spectrophotometer, water absorption, and biodegradation by soil burial test were also examined.

  10. Characterization of thermoplastic polyurethane/polylactic acid (TPU/PLA) tissue engineering scaffolds fabricated by microcellular injection molding

    Energy Technology Data Exchange (ETDEWEB)

    Mi, Hao-Yang [National Engineering Research Center of Novel Equipment for Polymer Processing, South China University of Technology, Guangzhou (China); Department of Mechanical Engineering, University of Wisconsin–Madison, WI (United States); Salick, Max R. [Department of Engineering Physics, University of Wisconsin–Madison, WI (United States); Jing, Xin [National Engineering Research Center of Novel Equipment for Polymer Processing, South China University of Technology, Guangzhou (China); Department of Mechanical Engineering, University of Wisconsin–Madison, WI (United States); Jacques, Brianna R. [Department of Biology, University of Wisconsin–River Falls, WI (United States); Crone, Wendy C. [Department of Engineering Physics, University of Wisconsin–Madison, WI (United States); Peng, Xiang-Fang, E-mail: pmxfpeng@scut.edu.cn [National Engineering Research Center of Novel Equipment for Polymer Processing, South China University of Technology, Guangzhou (China); Turng, Lih-Sheng, E-mail: turng@engr.wisc.edu [Department of Mechanical Engineering, University of Wisconsin–Madison, WI (United States)

    2013-12-01

    Polylactic acid (PLA) and thermoplastic polyurethane (TPU) are two kinds of biocompatible and biodegradable polymers that can be used in biomedical applications. PLA has rigid mechanical properties while TPU possesses flexible mechanical properties. Blended TPU/PLA tissue engineering scaffolds at different ratios for tunable properties were fabricated via twin screw extrusion and microcellular injection molding techniques for the first time. Multiple test methods were used to characterize these materials. Fourier transform infrared spectroscopy (FTIR) confirmed the existence of the two components in the blends; differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA) confirmed the immiscibility between the TPU and PLA. Scanning electron microscopy (SEM) images verified that, at the composition ratios studied, PLA was dispersed as spheres or islands inside the TPU matrix and that this phase morphology further influenced the scaffold's microstructure and surface roughness. The blends exhibited a large range of mechanical properties that covered several human tissue requirements. 3T3 fibroblast cell culture showed that the scaffolds supported cell proliferation and migration properly. Most importantly, this study demonstrated the feasibility of mass producing biocompatible PLA/TPU scaffolds with tunable microstructures, surface roughnesses, and mechanical properties that have the potential to be used as artificial scaffolds in multiple tissue engineering applications. - Highlights: • Microcellular injection molding was used to fabricate tissue engineering scaffolds. • TPU/PLA tissue engineering scaffolds with tunable properties were fabricated. • Multiple test methods were used to characterize the scaffolds. • The biocompatibility of the scaffolds was confirmed by fibroblast cell culture. • Scaffolds produced have the potential to be used in multiple tissue applications.

  11. Processing-microstructure models for short- and long-fiber thermoplastic composites

    Science.gov (United States)

    Phelps, Jay H.

    The research for this thesis has explored the important microstructural variables for injection-molded thermoplastic composites with discontinuous fiber reinforcement. Two variables, the distributions of fiber orientation and fiber length after processing, have proven to be not only important for correct material property prediction but also difficult to predict using currently available modeling and simulation techniques. In this work, we develop new models for the prediction of these two microstructural variables. Previously, the Folgar-Tucker model has been widely used to predict fiber orientation in injection molded SFT composites. This model accounts for the effects of both hydrodynamics and fiber-fiber interactions in order to give a prediction for a tensorial measure of fiber orientation. However, when applied to at least some classes of LFTs, this model does not match all components of experimental fiber orientation tensor data. In order to address this shortcoming of the model, we hypothesize that Folgar and Tucker's phenomenological treatment of the effects of fiber-fiber interactions with an isotropic rotary diffusion contribution to the rate of change of orientation is insufficient for materials with longer fibers. Instead, this work develops a fiber orientation model that incorporates anisotropic rotary diffusion (ARD). From kinetic theory we derive a general family of evolution equations for the second-order orientation tensor, correcting errors in earlier treatments, and identify a specific equation that is useful for predicting orientation in LFTs. The amount of diffusivity in this model used to approximate the effect of fiber-fiber interactions in each direction is assumed to depend on a second-order space tensor, which is taken to be a function of the orientation state and the rate of deformation. Also, concentrated fiber suspensions align more slowly with respect to strain than the Folgar-Tucker model predicts. Here, we borrow the technique of Wang et al. (2008) to incorporate this behavior in an objective fashion in this new model. Model parameters are selected by matching the experimental steady-state orientation in simple shear flow, and by requiring stable steady states and physically realizable solutions. Utilizing two separate techniques, we identify model parameters for three different materials. We then show that once a set of parameters that meets all previously established criteria has been identified, the differences in model behavior are negligible within that set of parameters. The final model with the proper parameter set is suitable for use in mold filling and other flow simulations, and does give improved predictions of fiber orientation for injection molded LFTs. Although significant fiber length degradation in LFTs has been observed both in literature and in this work, there are no quantitative fiber breakage models to predict either fiber length distributions or average fiber length measures. This work reviews the suspected causes of fiber breakage during the processing of discontinuously-reinforced thermoplastics, specifically LFTs, and introduces a phenomenological fiber breakage model based on the buckling force in a hydrodynamically loaded fiber. This breakage model is incorporated into a conservation equation for total fiber length, and a phenomenological model for the evolution of the fiber length distribution is developed. From this model, we also develop separate, approximate models for the evolution of both the number-average and weight-average fiber length measures. By applying these models to both a simple numerical example and a more complex mold-filling simulation, a qualitative agreement between experiment and prediction is observed. Although these results are promising, the breakage models have only been applied to the mold cavity in injection molding simulation. Both a literature review and our experimental data strongly suggest that the majority of fiber length degradation occurs in the earlier stages of injection molding, in the screw nozzle, runners, and gate. A be

  12. Predictive Engineering Tools for Injection-molded Long-Carbon-Fiber Thermoplastic Composites - FY 2014 Third Quarterly Report

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Ba Nghiep; Sanborn, Scott E.; Mathur, Raj N.; Sharma, Bhisham; Sangid, Michael D.; Wang, Jin; Jin, Xiaoshi; Costa, Franco; Gandhi, Umesh N.; Mori, Steven; Tucker III, Charles L.

    2014-08-15

    This report describes the technical progresses made during the third quarter of FY 2014: 1) Autodesk introduced the options for fiber inlet condition to the 3D solver. These options are already available in the mid-plane/dual domain solver. 2) Autodesk improved the accuracy of 3D fiber orientation calculation around the gate. 3) Autodesk received consultant services from Prof. C.L. Tucker at the University of Illinois on the implementation of the reduced order model for fiber length, and discussed with Prof. Tucker the methods to reduce memory usage. 4) PlastiComp delivered to PNNL center-gated and edge-fan-gated 20-wt% to 30-wt% LCF/PP and LCF/PA66 (7”x7”x1/8”) plaques molded by the in-line direct injection molding (D-LFT) process. 5) PlastiComp molded ASTM tensile, flexural and impact bars under the same D-LFT processing conditions used for plaques for Certification of Assessment and ascertaining the resultant mechanical properties. 6) Purdue developed a new polishing routine, utilizing the automated polishing machine, to reduce fiber damage during surface preparation. 7) Purdue used a marker-based watershed segmentation routine, in conjunction with a hysteresis thresholding technique, for fiber segmentation during fiber orientation measurement. 8) Purdue validated Purdue’s fiber orientation measurement method using the previous fiber orientation data obtained from the Leeds machine and manually measured data by the University of Illinois. 9) PNNL conducted ASMI mid-plane analyses for a 30wt% LCF/PP plaque and compared the predicted fiber orientations with the measured data provided by Purdue University at the selected locations on this plaque. 10) PNNL put together the DOE 2014 Annual Merit Review (AMR) presentation with the team and presented it at the AMR meetings on June 17, 2014. 11) PNNL built ASMI dual domain models for the Toyota complex part and commenced mold filling analyses of the complex part with different wall thicknesses in order to support part molding. 12) Toyota and Magna discussed with PNNL on tool modification for molding the complex part. Toyota sent the CAD files of the complex part to PNNL to build ASMI models of the part for mold filling analysis to provide guidance to tooling and part molding.

  13. Predictive engineering tools for injection-molded long-carbon-fiber thermoplastic composites - FY 2015 third quarterly report

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Ba Nghiep [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Fifield, Leonard S. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Mori, Steven [MAGNA Exteriors and Interiors Corp. Aurora, ON (Canada); Gandhi, Umesh N. [Toyota Research Institute North America, Ann Arbor, MI (United States); Wang, Jin [Autodesk, Inc., Ithaca, NY (United States); Costa, Franco [Autodesk, Inc., Ithaca, NY (United States); Wollan, Eric J. [PlastiComp, Inc., Winona, MN (United States); Tucker, III, Charles L. [Univ. of Illinois at Urbana-Champaign, Urbana, IL (United States)

    2015-07-01

    During the third quarter of FY 2015, the following technical progress has been made toward project milestones: 1) Magna oversaw the tool build and prepared the molding plan for the complex part of Phase II. 2) PlastiComp hosted a visit by Magna and Toyota on April 23rd to finalize the molding scope and schedule. The plan for molding trials including selection of molding parameters for both LFT and D-LFT for the U-shape complex part was established. 3) Toyota shipped the U-shape complex part tool to Magna on May 28th, 2015. 4) Plasticomp provided 30wt% LCF/PP and 30wt% LCF/PA66 compounded pellets to Magna for molding the complex part. 5) Magna performed preliminary molding trials on June 2nd, 2015 to validate wall thickness, fill profile, tool temperature and shot size requirements for the complex part. 6) Magna performed the first complex part run on June 16th and 17th, 2015 at Magna’s Composite Centre of Excellence in Concord, ON, Canada. Dale Roland of Plasticomp, and Umesh Gandhi of Toyota also attended the molding. 7) Magna discussed and finalized the plan with PNNL and the team for cutting samples from molded parts at selected locations for fiber orientation and length measurements. 8) Magna provided the computer-aided design (CAD) files of the complex parts with and without ribs to PNNL and Autodesk to build the corresponding ASMI models for injection molding simulations. Magna also provided the actual parameters used. 9) Plasticomp’s provided knowledge and experience of molding LCF materials essential to the successful molding of the parts including optimization of fill speed, tool temperatures, and plasticizing conditions for the 30wt% LCF/PP and 30wt% LCF/PA66 materials in both rib and non-rib versions. 10) Magna molded additional parts for evaluation of mechanical property testing including torsional stiffness on June 29th and 30th, 2015 at Magna’s Composite Center of Excellence. 11) Toyota began preparation for the torsion test of the specimens. Preparation of a computer-aided engineering (CAE) model to predict the performance is in progress. 12) Autodesk fixed an error in the implementation of the proper orthogonal decomposition (POD) calculation of fiber length that had caused the ASMI solution to crash and provided an updated build of ASMI containing the fix. 13)Autodesk reviewed and provided feedback for the complex part molding and measurement locations. 14) Autodesk provided support to set up the workflow for ASMI-ABAQUS® analysis, and provided a fix and workaround for a bug in the ASMI-ABAQUS® output command. 15) Autodesk helped build ASMI analysis models for the complex parts with and without ribs. 16) Autodesk worked on improving the orientation prediction accuracy in the shearing layer for 3D meshes based on comparison to measured data of the plaque moldings. 17) PNNL installed a new ASMI version received from Autodesk and performed comparative analyses to assess mid-plane versus 3D fiber length predictions using the full fiber length model and the reduced-order model (ROM) using POD. 18) PNNL presented the project scope, accomplishments, significant results and future plans to DOE and the USCAR Materials Tech Team on June 3rd, 2015. 19) PNNL discussed the cutting of samples from molded parts and finalized a plan with Magna and the team suggesting the sample size, locations and number of samples per location. 20) PNNL and Autodesk built ASMI models for the complex parts with and without ribs, and preliminary analyses of the part with ribs were conducted using the actual molding parameters received from Magna. 21) PNNL worked on a procedure to extract fiber orientation and length results from a 3D ASMI analysis to a 3D ABAQUS model. This procedure is essential to import ASMI fiber orientation and length to a 3D ABAQUS model of the part allowing future part structural analysis for weight reduction study.

  14. Relationship between fiber degradation and residence time distribution in the processing of long fiber reinforced thermoplastics

    Directory of Open Access Journals (Sweden)

    2008-08-01

    Full Text Available Long fiber reinforced thermoplastics (LFT were processed by in-line compounding equipment with a modified single screw extruder. A pulse stimulus response technique using PET spheres as the tracer was adopted to obtain residence time distribution (RTD of extrusion compounding. RTD curves were fitted by the model based on the supposition that extrusion compounding was the combination of plug flow and mixed flow. Characteristic parameters of RTD model including P the fraction of plug flow reactor (PFR and d the fraction of dead volume of continuous stirred tank reactor (CSTR were used to associate with fiber degradation presented by fiber length and dispersion. The effects of screw speed, mixing length and channel depth on RTD curves, and characteristic parameters of RTD models as well as their effects on the fiber degradation were investigated. The influence of shear force with different screw speeds and variable channel depth on fiber degradation was studied and the main impetus of fiber degradation was also presented. The optimal process for obtaining the balance of fiber length and dispersion was presented.

  15. Local mechanical properties of LFT injection molded parts: Numerical simulations versus experiments

    Science.gov (United States)

    Desplentere, F.; Soete, K.; Bonte, H.; Debrabandere, E.

    2014-05-01

    In predictive engineering for polymer processes, the proper prediction of material microstructure from known processing conditions and constituent material properties is a critical step forward properly predicting bulk properties in the finished composite. Operating within the context of long-fiber thermoplastics (LFT, length filled compound to compare the measured data with the numerical simulation results. In this investigation, tensile tests and 3 point bending tests are considered. To characterize the fiber length distribution of the polymer melt entering the mold (necessary for the numerical simulations), air shots were performed. For those air shots, similar homogenization conditions were used as during the injection molding tests. The fiber length distribution is characterized using automated optical method on samples for which the matrix material is burned away. Using the appropriate settings for the different experiments, good predictions of the local mechanical properties are obtained.

  16. Characterization of Injection Molded Structures

    DEFF Research Database (Denmark)

    Sun, Ling; SØgaard, Emil

    Microscopy has been widely applied to understand surface structures of solid samples. According to the instrumental methodology, there are different microscopy methods: optical microscopy, electron microscopy, and scanning probe microscopy (SPM). These microscopy methods have individual advantages and limitations. Therefore, it would be difficult to characterize complex, especially hierarchical structures by using only one method. Here we present a combined optical microscopy, scanning electron microscopy (SEM), and scanning probe microscopy study on injection molded structures. These structures are used for different applications. We show how to correlate the structures of the polymer replicas with respect to their functionalities. Furthermore, we introduce how we coordinate with all partners in the “Nanoplast” project, and how we utilize the existing facilities of each method to understand structure-properties relationship of the injection molded polymer samples. These results are very important in optimizing injection molding parameters.

  17. The Shrinkage Behavior and Surface Topographical Investigation for Micro Metal Injection Molding

    DEFF Research Database (Denmark)

    Islam, Aminul; Giannekas, Nikolaos; Marhöfer, David Maximilian; Tosello, Guido; Hansen, Hans Nørgaard

    2014-01-01

    Metal injection molding (MIM) is a near net shape manufacturing technology that can produce highly complex and dimensionally stable parts for high end engineering applications. Despite the recent growth and industrial interest, micro metal molding is yet to be the field of extensive research especially when it is compared with micro molding of thermoplastics. The current paper presents a thorough investigation on the process of metal injection molding where it systematically characterizes the ef...

  18. Surface microstructure replication in injection molding

    DEFF Research Database (Denmark)

    Theilade, Uffe Arlø; Hansen, Hans Nørgaard

    2006-01-01

    In recent years, polymer components with surface microstructures have been in rising demand for applications such as lab-on-a-chip and optical components. Injection molding has proven to be a feasible and efficient way to manufacture such components. In injection molding, the mold surface topography is transcribed onto the plastic part through complex mechanisms. This replication, however, is not perfect, and the replication quality depends on the plastic material properties, the topography itse...

  19. Injection molded self-cleaning surfaces

    DEFF Research Database (Denmark)

    Søgaard, Emil

    2014-01-01

    This PhD thesis concerns the development of superhydrophobic surfaces fabricated by injection molding. Today, injection molding is the prevalent production method for consumer plastic products. However, concerns regarding the environmental impact of a plastic production are increasing, especially because the use of potentially toxic self-cleaning coatings is used worldwide in a larger and larger scale. In this context, the work in this PhD project could be seen as a scientific effort towards red...

  20. On Optimization of Injection Molding Cooling

    OpenAIRE

    Rännar, Lars-Erik

    2008-01-01

    This thesis is devoted to analysis and optimization of the injection molding process with a focus on the mold. In the analysis, both process parameters and the design of the mold are taken in consideration. A procedure has been developed, i.e. a method and a program code, which enables optimization of different quantities, not only restricted to injection molding simulation, by altering different variables. There are many ways to interpret the word “optimization”. In this work, “optimization”...

  1. Injection Molding of High Aspect Ratio Nanostructures

    DEFF Research Database (Denmark)

    Matschuk, Maria; Larsen, Niels Bent

    We present a process for injection molding of 40 nm wide and >100 nm high pillars (pitch: 200 nm). We explored the effects of mold coatings and injection molding conditions on the replication quality of nanostructures in cyclic olefin copolymer. We found that optimization of molding parameters using native nickel molds only lead to slight improvements in replication quality. In contrast, a fluorocarbon based antistiction coating (FDTS) was found to improve the replication quality significantly.

  2. Injection Molding of High Aspect Ratio Nanostructures

    DEFF Research Database (Denmark)

    Matschuk, Maria; Larsen, Niels Bent

    2011-01-01

    We present a process for injection molding of 40 nm wide and >100 nm high pillars (pitch: 200 nm). We explored the effects of mold coatings and injection molding conditions on the replication quality of nanostructures in cyclic olefin copolymer. We found that optimization of molding parameters using native nickel molds only lead to slight improvements in replication quality. In contrast, a fluorocarbon based antistiction coating (FDTS) was found to improve the replication quality significantly.

  3. Injection Molding of High Aspect Ratio Nanostructures

    OpenAIRE

    Matschuk, Maria; Larsen, Niels Bent

    2012-01-01

    We present a process for injection molding of 40 nm wide and >100 nm high pillars (pitch: 200 nm). We explored the effects of mold coatings and injection molding conditions on the replication quality of nanostructures in cyclic olefin copolymer. We found that optimization of molding parameters using native nickel molds only lead to slight improvements in replication quality. In contrast, a fluorocarbon based antistiction coating (FDTS) was found to improve the replication qu...

  4. Nanostructuring steel for injection molding tools

    DEFF Research Database (Denmark)

    Al-Azawi, A.; Smistrup, Kristian; Kristensen, Anders

    2014-01-01

    The production of nanostructured plastic items by injection molding with ridges down to 400 nm in width, which is the smallest line width replicated from nanostructured steel shims, is presented. Here we detail a micro-fabrication method where electron beam lithography, nano-imprint lithography and ion beam etching are combined to nanostructure the planar surface of a steel wafer. Injection molded plastic parts with enhanced surface properties, like anti-reflective, superhydrophobic and structur...

  5. Progress in simulating semi-flexible glass fiber orientation in an injection molded end-gated plaque

    Science.gov (United States)

    Cieslinski, Mark J.; Meyer, Kevin J.; Baird, Donald G.

    2014-05-01

    The use of long fiber reinforced thermoplastics has gained increasing interest as a means to enhance a part's mechanical properties created through traditional melt processing techniques. Injection molding creates a complex microstructure to develop caused by flow field within the mold. Accurate predictions of fiber orientation can allow for mold design to be tailored to achieve a desired microstructure and mechanical properties. Simulations utilize the Bead-Rod orientation model adapted for concentrated suspensions to account for semi-flexible fibers by representing a fiber as two adjoined vectors that are free to rotate around the connecting point. This work uses orientation model parameters extracted from orientation data taken along the center plane at the transition between the gate and plaque. The entire mold cavity is simulated under non-isothermal conditions including the entry region to the plaque and the fountain flow behavior at the advancing front. Simulations of the semi-flexible model are compared to the Strain Reduction Factor (SRF) model developed for rigid fibers following the same simulation procedure. Predictions are compared to experimental data measured along and away from the plane of symmetry. Improvement in orientation predictions are obtained from the Bead-Rod model which greatly out performs the rigid fiber model away from the center plane.

  6. All-in-polymer injection molded device for single cell capture using multilevel silicon master fabrication

    DEFF Research Database (Denmark)

    Tanzi, S.; Larsen, S.T.; Matteucci, M.; Taboryski, R.

    2012-01-01

    This work demonstrates a novel all-in-polymer device for single cell capture applicable for biological recordings. The chip is injection molded and comprises a "cornered" (non planar) aperture. It has been demonstrated how cornered apertures are straightforward to mold in PDMS [1,2]. In this study we demonstrate cornered apertures made in a thermoplastic polymer. One of the advantages of cornered apertures is the ease of microscopy under a standard inverted optical microscope, when using transpa...

  7. Injection molded polymer chip for electrochemical and electrophysiological recordings from single cells

    DEFF Research Database (Denmark)

    Tanzi, Simone; Larsen, Simon Tylsgaard; Taboryski, Rafael J.

    2011-01-01

    We present a novel method to fabricate an all in polymer injection molded chip for electrochemical cell recordings and lateral cell trapping. The complete device is molded in thermoplastic polymer and it results from assembling two halves. We tested spin-coated conductive polymer poly(3,4-ethylenedioxythiopene) and showed that it can be used as an electrode material for detecting neurotransmitters electrochemically in biosensors.

  8. Surface microstructure replication in injection molding

    DEFF Research Database (Denmark)

    Theilade, Uffe ArlØ; Hansen, Hans NØrgaard

    2006-01-01

    In recent years, polymer components with surface microstructures have been in rising demand for applications such as lab-on-a-chip and optical components. Injection molding has proven to be a feasible and efficient way to manufacture such components. In injection molding, the mold surface topography is transcribed onto the plastic part through complex mechanisms. This replication, however, is not perfect, and the replication quality depends on the plastic material properties, the topography itself, and the process conditions. This paper describes and discusses an investigation of injection molding of surface microstructures. The fundamental problem of surface microstructure replication has been studied. The research is based on specific microstructures as found in lab-on-a-chip products and on rough surfaces generated from EDM (electro discharge machining) mold cavities. Emphasis is put on the ability to replicate surface microstructures under normal injection-molding conditions, i.e., with commodity materials within typical process windows. It was found that within typical process windows the replication quality depends significantly on several process parameters, and especially the mold temperature. For the specific microstructures, evidence suggests that step-height replication quality depends linearly on structure width in a certain range

  9. Nanostructuring steel for injection molding tools

    DEFF Research Database (Denmark)

    Al-Azawi, A.; Smistrup, Kristian

    2014-01-01

    The production of nanostructured plastic items by injection molding with ridges down to 400 nm in width, which is the smallest line width replicated from nanostructured steel shims, is presented. Here we detail a micro-fabrication method where electron beam lithography, nano-imprint lithography and ion beam etching are combined to nanostructure the planar surface of a steel wafer. Injection molded plastic parts with enhanced surface properties, like anti-reflective, superhydrophobic and structural colors can be achieved by micro-and nanostructuring the surface of the steel molds. We investigate the minimum line width that can be realized by our fabrication method and the influence of etching angle on the structure profile during the ion beam etching process. Trenches down to 400 nm in width have been successfully fabricated into a 316 type electro-polished steel wafer. Afterward a plastic replica has been produced by injection molding with good structure transfer fidelity. Thus we have demonstrated that by utilizing well-established fabrication techniques, nanostructured steel shims that are used in injection molding, a technique that allows low cost mass fabrication of plastic items, are produced.

  10. Progress in Titanium Metal Powder Injection Molding

    Directory of Open Access Journals (Sweden)

    Randall M. German

    2013-08-01

    Full Text Available Metal powder injection molding is a shaping technology that has achieved solid scientific underpinnings. It is from this science base that recent progress has occurred in titanium powder injection molding. Much of the progress awaited development of the required particles with specific characteristics of particle size, particle shape, and purity. The production of titanium components by injection molding is stabilized by a good understanding of how each process variable impacts density and impurity level. As summarized here, recent research has isolated the four critical success factors in titanium metal powder injection molding (Ti-MIM that must be simultaneously satisfied—density, purity, alloying, and microstructure. The critical role of density and impurities, and the inability to remove impurities with sintering, compels attention to starting Ti-MIM with high quality alloy powders. This article addresses the four critical success factors to rationalize Ti-MIM processing conditions to the requirements for demanding applications in aerospace and medical fields. Based on extensive research, a baseline process is identified and reported here with attention to linking mechanical properties to the four critical success factors.

  11. Injection molded self-cleaning surfaces

    DEFF Research Database (Denmark)

    SØgaard, Emil

    2014-01-01

    This PhD thesis concerns the development of superhydrophobic surfaces fabricated by injection molding. Today, injection molding is the prevalent production method for consumer plastic products. However, concerns regarding the environmental impact of a plastic production are increasing, especially because the use of potentially toxic self-cleaning coatings is used worldwide in a larger and larger scale. In this context, the work in this PhD project could be seen as a scientific effort towards reducing toxic compounds in manufactured plastic parts by developing injecting molded surfaces that are superhydrophobic based on topography rather than chemical compounds. Therefore, a novel method for fabricating superhydrophobic polymer surfaces with excellent water-repellant properties is developed. The method is based on microstructure fabrication and superposed nanostructures on silicon wafers. The nano- and microstructured silicon is electroplated with nickel and the resulting nickel shim with inverse polarity is used in an injection molding process. A versatile injection molding process capable of producing different nano- and microstructures on areas larger than 10 cm2 is developed. Variotherm mold heating is used to ensure complete filling of the mold and a mold cavity-depacking process step is introduced. The depacking step increases polymer shrinkage allowing the nano- and microstructures to be successfully demolded. A systematic wetting study on injection molded polymer surfaces is performed on periodic hierarchical structures with nanograss and holes. Water wetting tests are carried out using a pressure cell to control the water pressure. Microscopic wetting behavior of the structures is studied by optical transmission microscopy. Interestingly, it is found that the surface chemistry of the polymer changes over time causing a decrease in hydrophobicity. It is concluded that the material properties of the polymer is critical for maintaining superhydrophobicity under water exposure. A range of different structures with and without the hierarchical nanograss, pillars, micro cavities (holes), spruce like micropillars and pyramid shaped structures are examined. By employing deep ultra violet (DUV) projection lithography for mold fabrication, polymer surface feature sizes in the nanometer range could be realized over large surface areas. The superhydrophobic surfaces were fabricated from the amorphous polymer TOPAS 8007-S04 (COC) and the semi crystalline polymer PP HD601CF. An overview of the different types of structures in relation to applications is given. In particular, spruce like micropillars seems interesting. Here, the contact angles increase from 102° for unstructured polymer surfaces, to 172° for structured surfaces with a drop roll-off angle of less than 2°. Thereby, it is shown that an extremely water repellant surface can be injection molded directly with clear perspectives for more environmental and healthier plastic consumer products.

  12. Modelling and monitoring in injection molding

    DEFF Research Database (Denmark)

    Thyregod, Peter

    2001-01-01

    This thesis is concerned with the application of statistical methods in quality improvement of injection molded parts. The methods described are illustrated with data from the manufacturing of parts for a medical device. The emphasis has been on the variation between cavities in multi-cavity molds. >From analysis of quality measurements from a longer period of manufacturing, it was found that differences in cavities was that source of variation with greatest influence on the lenght of the molded...

  13. Functional nanostructures on injection molded plastic

    DEFF Research Database (Denmark)

    Johansson, Alicia Charlotte; Søgaard, Emil; Andersen, Nis Korsgaard; Sun, Ling; Taboryski, Rafael J.

    2014-01-01

    Nanotechnology can be used to make inexpensive plastic parts with functional surfaces. The plastic parts can be molded using a standard injection molding process. The nanostructures are directly transferred from the surface of the molding tool to the surface of the molded plastic part during the molding process. The main advantage with this method is that surface treatments and chemical additives are avoided, which minimizes health risks and simplifies recycling. Another advantage is that the un...

  14. Structural development of HDPE in injection molding

    OpenAIRE

    Sousa, R.A; R. L. Reis; Cunha, A. M.; Bevis, M. J.

    2003-01-01

    This study investigated some relevant structure/properties relationships in shear-controlled orientation in injection molding (SCORIM) of high-density polyethylene (HDPE). SCORIM was used to deliberately induce a strong anisotropic character in the HDPE microstructure. Three grades with different molecular weight characteristics were molded into tensile test bars, which were subsequently characterized in terms of the mechanical behavior by tensile tests and microhardness measurements. The str...

  15. Injection molding simulation with variothermal mold temperature control of highly filled polyphenylene sulfide

    Science.gov (United States)

    Birkholz, A.; Tschiersky, M.; Wortberg, J.

    2015-05-01

    For the installation of a fuel cell stack to convert chemical energy into electricity it is common to apply bipolar plates to separate and distribute reaction gases and cooling agents. For reducing manufacturing costs of bipolar plates a fully automated injection molding process is examined. The high performance thermoplastic matrix material, polyphenylene sulfide (PPS), defies against the chemical setting and the operation temperature up to 200 °C. To adjust also high electrical and thermal conductivity, PPS is highly filled with various carbon fillers up to an amount of 65 percentage by volume. In the first step two different structural plates (one-sided) with three different gate heights and molds are designed according to the characteristics of a bipolar plate. To cope with the approach that this plate should be producible on standard injection molding machines with variothermal mold temperature control, injection molding simulation is used. Additionally, the simulation should allow to formulate a quality prediction model, which is transferrable to bipolar plates. Obviously, the basis for a precise simulation output is an accurate description of the material properties and behavior of the highly filled compound. This, the design of the structural plate and mold and the optimization via simulation is presented, as well. The influence of the injection molding process parameters, e.g. injection time, cycle times, packing pressure, mold temperature, and melt temperature on the form filling have been simulated to determine optimal process conditions. With the aid of the simulation and the variothermal mold temperature control it was possible to reduce the required melt temperature below the decomposition temperature of PPS. Thereby, hazardous decomposition products as hydrogen sulfide are obviated. Thus, the health of the processor, the longevity of the injection molding machine as well as the material and product properties can be protected.

  16. Experimental Investigation into Suitable Process Conditions for Plastic Injection Molding of Thin-Sheet Parts

    Directory of Open Access Journals (Sweden)

    Dyi-Cheng Chen

    2014-04-01

    Full Text Available This study performs an experimental investigation into the effects of the process parameters on the surface quality of injection molded thin-sheet thermoplastic components. The investigations focus specifically on the shape, number and position of the mold gates, the injection pressure and the injection rate. It can be seen that the gravity force entering point improved filling of the cavity for the same forming time and injection pressure. Moreover, it shows the same injection pressure and packing time, the taper-shape gate yields a better surface appearance than the sheet-shape gate. The experimental results provide a useful source of reference in suitable the process conditions for the injection molding of thin-sheet plastic components.

  17. All-in-polymer injection molded device for single cell capture using multilevel silicon master fabrication

    DEFF Research Database (Denmark)

    Tanzi, S.; Larsen, S.T.

    2012-01-01

    This work demonstrates a novel all-in-polymer device for single cell capture applicable for biological recordings. The chip is injection molded and comprises a "cornered" (non planar) aperture. It has been demonstrated how cornered apertures are straightforward to mold in PDMS [1,2]. In this study we demonstrate cornered apertures made in a thermoplastic polymer. One of the advantages of cornered apertures is the ease of microscopy under a standard inverted optical microscope, when using transparent materials. After the part is injection molded, the sealing of the chip is performed by thermal bonding to a polymer foil, so the complete device results from only two parts. It differs from similar devices in the novel material and fabrication platform that enables high reproducibility and inexpensive mass production. Optimization of the fabrication scheme has been carried out in order to avoid defects during demolding. Capturing of single PC12 cells has been demonstrated.

  18. Birefringence characterization of injection molded microplates

    Science.gov (United States)

    Adhikari, Achyut; Asundi, Anand

    2015-03-01

    Birefringence affects the quality of image analysis in injection molded micro-plates. Depending upon their manufacturing / production processes and the type of material, different plates exhibit varying amounts of birefringence. This birefringence is attributed to residual stress generated during the molding process. Polarimeter is the standard tool for birefringence distribution visualization and quantification. Broad chemical resistance and high mechanical stability of the plates are the desirable properties that can be characterized by birefringence measurement. Birefringence, expressed in nm/cm is light retardance (nm) after passing through a sample with certain thickness (cm). Low or uniform birefringence plates provide high-resolution demonstrating higher performance, hence suitable for bio-chemical analysis.

  19. Smart plastic functionalization by nanoimprint and injection molding

    DEFF Research Database (Denmark)

    Zalkovskij, Maksim; Thamdrup, Lasse Højlund; Smistrup, Kristian; Andén, Thomas; Johansson, Alicia C.; Mikkelsen, Niels Jørgen; Madsen, Morten Hannibal; Garnæs, Jørgen; Kristiansen, Tommy Tungelund; Diemer, Mads; Døssing, Michael; Minzari, Daniel; Tang, Peter Torben; Kristensen, Anders; Taboryski, Rafael J.; Essendrop, Søren; Nielsen, Theodor; Bilenberg, Brian

    2015-01-01

    In this paper, we present a route for making smart functionalized plastic parts by injection molding with sub-micrometer surface structures. The method is based on combining planar processes well known and established within silicon micro and sub-micro fabrication with proven high resolution and high fidelity with truly freeform injection molding inserts. The link between the planar processes and the freeform shaped injection molding inserts is enabled by the use of nanoimprint with flexible mol...

  20. Multi-height structures in injection molded polymer

    DEFF Research Database (Denmark)

    Andersen, Nis Korsgaard; Taboryski, Rafael J.

    2015-01-01

    We present the fabrication process for injection molded multi-height surface structures for studies of wetting behavior. We adapt the design of super hydrophobic structures to the fabrication constrictions imposed by industrial injection molding. This is important since many super hydrophobic surfaces are challenging to realize by injection molding due to overhanging structures and very high aspect ratios. In the fabrication process, we introduce several unconventional steps for producing the de...

  1. Optomechanical details in injection-molded assemblies

    Science.gov (United States)

    Hebert, Raymond T.

    1995-12-01

    With the advent of low-cost electro-optic components such as LEDs, laser diodes and CCD imaging devices, the cost and performance demands now fall upon the optical subsystems in order to achieve realistic marketing targets for many emerging commercial and consumer products. One of the many benefits of injection-molded plastic optics is the diversity of features that are available to the design team. Once designed and incorporated into the tooling, many features are virtually free in high-volume production. These features can include mechanical details as well as optical functions. Registration features can be included for precisely positioning optical elements to one another or to other assemblies such as printed circuit boards or housings. Snaps, compression features, spring-loading elements, standoffs, self-tapping screws or ultrasonically weldable features can greatly facilitate ease of assembly.

  2. Functional nanostructures on injection molded plastic

    DEFF Research Database (Denmark)

    Johansson, Alicia Charlotte; SØgaard, Emil

    Nanotechnology can be used to make inexpensive plastic parts with functional surfaces. The plastic parts can be molded using a standard injection molding process. The nanostructures are directly transferred from the surface of the molding tool to the surface of the molded plastic part during the molding process. The main advantage with this method is that surface treatments and chemical additives are avoided, which minimizes health risks and simplifies recycling. Another advantage is that the unique technology enables nanostructuring of free form molded parts. The functional surfaces can have many different properties including anti-reflective, self-cleaning, anti-stiction or color effects. In this work we focus on the superhydrophobic and self-cleaning properties.

  3. Applications of thin carbon coatings and films in injection molding

    Science.gov (United States)

    Cabrera, Eusebio Duarte

    In this research, the technical feasibility of two novel applications of thin carbon coatings is demonstrated. The first application consists of using thin carbon coatings on molds for molding ultra-thin plastic parts (application consists of a new approach to provide electromagnetic interference (EMI) shielding for plastic parts using in mold coated nanoparticle thin films or nanopapers to create a conductive top layer. During this research, the technical feasibility of a new approach was proven which provides injection molding of ultra-thin parts at lower pressures, without the need of fast heating/fast cooling or other expensive mold modification. An in-house developed procedure by other members of our group, was employed for coating the mold surface using chemical vapor deposition (CVD) resulting in a graphene coating with carbide bonding to the mold surface. The coating resulted in a significant decrease of surface friction and consequently easiness of flow when compared to their uncoated counterparts. Thermoplastic polymers and their composites are a very attractive alternative but are hindered by the non-conductive nature of polymers. There are two general approaches used to date to achieve EMI shielding for plastic products. One is to spray a conductive metal coating onto the plastic surface forming a layer that must maintain its shielding effectiveness (SE), and its adhesion to the plastic throughout the expected life of the product. However, metal coatings add undesirable weight and tend to corrode over time. Furthermore, scratching the coating may create shielding failure; therefore, a protective topcoat may be required. The other approach is to use polymer composites filled with conductive fillers such as carbon black (CB), carbon nanofiber (CNF), and carbon nanotube (CNT). While conductive fillers may increase the electrical conductivity of polymer composites, the loading of such fillers often cannot reach a high level (plastic parts was proven using in mold coated nanoparticle thin films or nanopapers to create a conductive top layer. For many years, in-mold coating (IMC) has been commercially applied to Sheet Molding Compound (SMC) compression molded parts, as an environmentally friendly approach to improve its surface quality and provide the required conductivity for electrostatic painting using carbon black (CB). Such process can also be applied to injection molding for creating a top conductive layer. Increasing the amount of CB will increase the surface conductivity of the coated part, thus improving the paint transfer efficiency. However the CB levels needed to achieve the conductivity levels required for achieving EMI shielding would make the coating viscosity too large for proper coating. Nanopaper based composites are excellent candidates for EMI shielding because of the nanopaper's high concentration of carbon nanofibers (CNFs) (~2 wt% to 10 wt% depending on nanopaper/thermoplastic thickness and 71wt.% to 79wt.% in the nanopaper itself after resin infusion) and high conductivity of the nanopaper. Instead of premixing nanoparticles with IMC coating, nanopapers enable the use of low viscosity IMC without CB coating to impregnate the CNF network in order to reach high electrical conductivity and EMI shielding values. (Abstract shortened by UMI.).

  4. Powder Injection Molding of Ceramic Engine Components for Transportation

    Science.gov (United States)

    Lenz, Juergen; Enneti, Ravi K.; Onbattuvelli, Valmikanathan; Kate, Kunal; Martin, Renee; Atre, Sundar

    2012-03-01

    Silicon nitride has been the favored material for manufacturing high-efficiency engine components for transportation due to its high temperature stability, good wear resistance, excellent corrosion resistance, thermal shock resistance, and low density. The use of silicon nitride in engine components greatly depends on the ability to fabricate near net-shape components economically. The absence of a material database for design and simulation has further restricted the engineering community in developing parts from silicon nitride. In this paper, the design and manufacturability of silicon nitride engine rotors for unmanned aerial vehicles by the injection molding process are discussed. The feedstock material property data obtained from experiments were used to simulate the flow of the material during injection molding. The areas susceptible to the formation of defects during the injection molding process of the engine component were identified from the simulations. A test sample was successfully injection molded using the feedstock and sintered to 99% density without formation of significant observable defects.

  5. Multi-height structures in injection molded polymer

    DEFF Research Database (Denmark)

    Andersen, Nis Korsgaard; Taboryski, Rafael J.

    2015-01-01

    We present the fabrication process for injection molded multi-height surface structures for studies of wetting behavior. We adapt the design of super hydrophobic structures to the fabrication constrictions imposed by industrial injection molding. This is important since many super hydrophobic surfaces are challenging to realize by injection molding due to overhanging structures and very high aspect ratios. In the fabrication process, we introduce several unconventional steps for producing the desired shapes, using a completely random mask pattern, exploiting the diffusion limited growth rates of different geometries, and electroforming a nickel mold from a polymer foil. The injection-molded samples are characterized by contact angle hysteresis obtained by the tilting method. We find that the receding contact angle depends on the surface coverage of the random surface structure, while the advancing contact angle is practically independent of the structure. Moreover, we argue that the increase in contact angle hysteresis correlates with the concentration of pinning sites among the random surface structures.

  6. Binder Removal from Powder Injection Molded 316L Stainless Steel

    Directory of Open Access Journals (Sweden)

    M.A. Omar

    2011-01-01

    Full Text Available This study reports the results of preparation of 316L stainless steel polymer based injection molded feed stock, rheology of feed stock and injection molding. The plastic binder was extracted from molded samples. The binder extraction was carried out in two steps: by solvent and thermal techniques. The results showed that feed stock prepared was suitable for injection molding and this was confirmed by rheology data measured by using capillary rheometer. The test samples were injection molded without physical defects. Paraffin Wax (major binder was extracted by using solvent extraction for 300 min. The thermal debinding was performed four different heating rates rage 1-7C min-1. The SEM results showed that the PW was completely extracted from the test samples after 300 min.

  7. Injection molding integration of theory and modeling methods

    CERN Document Server

    Zheng, Rong; Fan, Xi-Jun

    2011-01-01

    This practical volume covers the fundamental principles and numerical methods related to modeling the injection molding process. It addresses the cutting edge of our understanding of simulation technologies, without losing sight of useful classical approaches.

  8. Mechanical behavior of injection-molded starch-based polymers

    OpenAIRE

    R. L. Reis; Cunha, A. M.; Allan, P S; Bevis, M. J.

    1996-01-01

    This work evaluates the mechanical performance of injection-molded starch-based copolymers, 60/40 (mol/mol) starch/poly(ethylene vinyl alcohol), and the possibility of improving material properties through deliberately induced anisotropy during processing. Different types of samples were produced by conventional and shear-controlled injection molding (Scorim) and tested under tensile and impact loading. The behavior of three distinct grades is discussed in terms of the respective fracture mor...

  9. Packing parameters effect on injection molding of polypropylene nanostructured surfaces

    DEFF Research Database (Denmark)

    Calaon, Matteo; Tosello, Guido; Hansen, Hans Nørgaard; Ravn, C.; Islam, Aminul

    2012-01-01

    In today´s industry, applications involving surface patterning of sub-?m to nanometer scale structures have shown a high growth potential. To investigate the injection molding capability of replicating sub-?m surface texture on a large scale area, a 30x80 mm2 tool insert with surface structures having a diameter of 500 nm was employed. The tool insert surface was produced using chemical-based-batch techniques such aluminum anodization and nickel electroplating. During the injection molding proce...

  10. Modelling and monitoring in injection molding

    DEFF Research Database (Denmark)

    Thyregod, Peter

    2001-01-01

    This thesis is concerned with the application of statistical methods in quality improvement of injection molded parts. The methods described are illustrated with data from the manufacturing of parts for a medical device. The emphasis has been on the variation between cavities in multi-cavity molds. >From analysis of quality measurements from a longer period of manufacturing, it was found that differences in cavities was that source of variation with greatest influence on the lenght of the molded parts. The other large contribution to the lenght varation was the different machine settings. Samples taken within the same machine set-point did not cause great variation compared to the two preceding sources of variation. A simple graphical approach is suggested for finding patterns in the cavity differences. Applying this method to data from a 16 cavity mold, a clear connection was found between a parts lenght and the producing cavitys position in the mold. In a designed expriment it was possible to isolate the machine parameters contributing to the variation beteeen cavities. Thus, with a proper choice of levels for the machine variables, it was possible to reduce the varation between cavities substantially. Also an alternative model for the shrinkage of parts from a multi-cavity mold is suggested. From applying the model to data from a shringage study, it seemed that the observed part differences were not only due to differences in cavity dimensions. A model for the in-control varation for a multi-cavity molding process was suggested. Based on this model, control charting proceures have been suggested for monitoring the quality of the molded parts. Moreover, a capability index for multi-cavity molds has been suggested. Furthermore an alternative method for in-line quality charting is suggested. The method is for continuous control by attributes, and it is an alternative to the batch oriented approach mostly used. The procedure is especially efficient for quality requirements of very low proportion non-conformities. For the proposed charts the ARL function is derived. It is shown that in the case where a non-conforning unit is only expected very rarely during sampling, a moving sum chart and a CUSUM chart are equivalent. Finally, the correlation structure of 21 process variables has been studied prior to monitoring the process. Is is illustrated how the process can be analysed with multivariate techniques. It was found that two principal components reflected changes in machine set-points. Thus, there seems to be great potential in monitoring the process variables using a multivariate approach.

  11. The Shrinkage Behavior and Surface Topographical Investigation for Micro Metal Injection Molding

    DEFF Research Database (Denmark)

    Islam, Aminul; Giannekas, Nikolaos

    2014-01-01

    Metal injection molding (MIM) is a near net shape manufacturing technology that can produce highly complex and dimensionally stable parts for high end engineering applications. Despite the recent growth and industrial interest, micro metal molding is yet to be the field of extensive research especially when it is compared with micro molding of thermoplastics. The current paper presents a thorough investigation on the process of metal injection molding where it systematically characterizes the effects of important process conditions on the shrinkage and surface quality of molded parts with micro features. Effects of geometrical factors like feature dimensions and distance from the gate on the replication quality are studied. The influence of process conditions on the achievable roughness for the final metal parts is discussed based on the experimental findings. The test geometry is characterized by 2½D surface structures containing thin ribs of different aspect ratios and thicknesses in the sub-mm dimensional range. The test parts were molded from Catamold 316L with a conventional injection molding machine. Afterwards, the parts were de-binded and sintered to produce the final test samples. Among the different process parameters studied, the melt temperature was the most influential parameters for better replication and dimensional stability of the final part. The results presented in the paper clearly show that the shrinkage in metal part is not uniform in the micro scale. It depends on the feature dimensions and also on the process conditions. A thin section of the part exhibits higher relative shrinkage compared with a thicker section. Based on these findings, it can be concluded that a micro part molded by MIM process will have higher relative shrinkage compared to a macro part made with the same process.

  12. The shrinkage behavior and surface topographical investigation for micro metal injection molding

    Science.gov (United States)

    Islam, A.; Giannekas, N.; Marhöfer, D. M.; Tosello, G.; Hansen, H. N.

    2015-05-01

    Metal injection molding (MIM) is a near net shape manufacturing technology that can produce highly complex and dimensionally stable parts for high end engineering applications. Despite the recent growth and industrial interest, micro metal molding is yet to be the field of extensive research especially when it is compared with micro molding of thermoplastics. The current paper presents a thorough investigation on the process of metal injection molding where it systematically characterizes the effects of important process conditions on the shrinkage and surface quality of molded parts with micro features. Effects of geometrical factors like feature dimensions and distance from the gate on the replication quality are studied. The influence of process conditions on the achievable roughness for the final metal parts is discussed based on the experimental findings. The test geometry is characterized by 2½D surface structures containing thin ribs of different aspect ratios and thicknesses in the sub-mm dimensional range. The test parts were molded from Catamold 316L with a conventional injection molding machine. Afterwards, the parts were de-binded and sintered to produce the final test samples. Among the different process parameters studied, the melt temperature was the most influential parameters for better replication and dimensional stability of the final part. The results presented in the paper clearly show that the shrinkage in metal part is not uniform in the micro scale. It depends on the feature dimensions and also on the process conditions. A thin section of the part exhibits higher relative shrinkage compared with a thicker section. Based on these findings, it can be concluded that a micro part molded by MIM process will have higher relative shrinkage compared to a macro part made with the same process.

  13. Smart plastic functionalization by nanoimprint and injection molding

    DEFF Research Database (Denmark)

    Zalkovskij, Maksim; Thamdrup, Lasse HØjlund

    2015-01-01

    In this paper, we present a route for making smart functionalized plastic parts by injection molding with sub-micrometer surface structures. The method is based on combining planar processes well known and established within silicon micro and sub-micro fabrication with proven high resolution and high fidelity with truly freeform injection molding inserts. The link between the planar processes and the freeform shaped injection molding inserts is enabled by the use of nanoimprint with flexible molds for the pattern definition combined with unidirectional sputter etching for transferring the pattern. With this approach, we demonstrate the transfer of down to 140 nm wide holes on large areas with good structure fidelity on an injection molding steel insert. The durability of the sub-micrometer structures on the inserts have been investigated by running two production series of 102,000 and 73,000 injection molded parts, respectively, on two different inserts and inspecting the inserts before and after the production series and the molded parts during the production series.

  14. Numerical approach of the injection molding process of fiber-reinforced composite with considering fiber orientation

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen Thi, T. B., E-mail: thanhbinh.skku@gmail.com, E-mail: yokoyama@kit.ac.jp; Yokoyama, A., E-mail: thanhbinh.skku@gmail.com, E-mail: yokoyama@kit.ac.jp [Department of Advanced Fibro-Science, Kyoto Institute of Technology (Japan); Ota, K., E-mail: kei-ota@toyobo.jp, E-mail: katsuhiro-kodama@toyobo.jp, E-mail: katsuhisa-yamashita@toyobo.jp, E-mail: yumiko-isogai@toyobo.jp, E-mail: kenji-furuichi@toyobo.jp, E-mail: chisato-nonomura@toyobo.jp; Kodama, K., E-mail: kei-ota@toyobo.jp, E-mail: katsuhiro-kodama@toyobo.jp, E-mail: katsuhisa-yamashita@toyobo.jp, E-mail: yumiko-isogai@toyobo.jp, E-mail: kenji-furuichi@toyobo.jp, E-mail: chisato-nonomura@toyobo.jp; Yamashita, K., E-mail: kei-ota@toyobo.jp, E-mail: katsuhiro-kodama@toyobo.jp, E-mail: katsuhisa-yamashita@toyobo.jp, E-mail: yumiko-isogai@toyobo.jp, E-mail: kenji-furuichi@toyobo.jp, E-mail: chisato-nonomura@toyobo.jp; Isogai, Y., E-mail: kei-ota@toyobo.jp, E-mail: katsuhiro-kodama@toyobo.jp, E-mail: katsuhisa-yamashita@toyobo.jp, E-mail: yumiko-isogai@toyobo.jp, E-mail: kenji-furuichi@toyobo.jp, E-mail: chisato-nonomura@toyobo.jp; Furuichi, K., E-mail: kei-ota@toyobo.jp, E-mail: katsuhiro-kodama@toyobo.jp, E-mail: katsuhisa-yamashita@toyobo.jp, E-mail: yumiko-isogai@toyobo.jp, E-mail: kenji-furuichi@toyobo.jp, E-mail: chisato-nonomura@toyobo.jp; Nonomura, C., E-mail: kei-ota@toyobo.jp, E-mail: katsuhiro-kodama@toyobo.jp, E-mail: katsuhisa-yamashita@toyobo.jp, E-mail: yumiko-isogai@toyobo.jp, E-mail: kenji-furuichi@toyobo.jp, E-mail: chisato-nonomura@toyobo.jp [Toyobo Co., LTD. Research Center (Japan)

    2014-05-15

    One of the most important challenges in the injection molding process of the short-glass fiber/thermoplastic composite parts is being able to predict the fiber orientation, since it controls the mechanical and the physical properties of the final parts. Folgar and Tucker included into the Jeffery equation a diffusive type of term, which introduces a phenomenological coefficient for modeling the randomizing effect of the mechanical interactions between the fibers, to predict the fiber orientation in concentrated suspensions. Their experiments indicated that this coefficient depends on the fiber volume fraction and aspect ratio. However, a definition of the fiber interaction coefficient, which is very necessary in the fiber orientation simulations, hasn't still been proven yet. Consequently, this study proposed a developed fiber interaction model that has been introduced a fiber dynamics simulation in order to obtain a global fiber interaction coefficient. This supposed that the coefficient is a sum function of the fiber concentration, aspect ratio, and angular velocity. The proposed model was incorporated into a computer aided engineering simulation package C-Mold. Short-glass fiber/polyamide-6 composites were produced in the injection molding with the fiber weight concentration of 30 wt.%, 50 wt.%, and 70 wt.%. The physical properties of these composites were examined, and their fiber orientation distributions were measured by micro-computed-tomography equipment ?-CT. The simulation results showed a good agreement with experiment results.

  15. The effects of process parameters on injection-molded PZT ceramics part fabrication- compounding process rheology.

    Energy Technology Data Exchange (ETDEWEB)

    Halbleib, Laura L.; Yang, Pin; Mondy, Lisa Ann; Burns, George Robert

    2005-05-01

    Solid solutions of lead-based perovskites are the backbone materials of the piezoelectric components for transducer, actuator, and resonator applications. These components, typically small in size, are fabricated from large sintered ceramic slugs using grinding and lapping processes. These operations increase manufacturing costs and produce a large hazardous waste stream, especially when component size decreases. To reduce costs and hazardous wastes associated with the production of these components, an injection molding technique is being investigated to replace the machining processes. The first step in the new technique is to compound an organic carrier with a ceramic powder. The organic carrier is a thermoplastic based system composed of a main carrier, a binder, and a surfactant. Understanding the rheology of the compounded material is necessary to minimize the creation of defects such as voids or cavities during the injection-molding process. An experiment was performed to model the effects of changes in the composition and processing of the material on the rheological behavior. Factors studied included: the surfactant of the organic carrier system, the solid loading of the compounded material, and compounding time. The effects of these factors on the viscosity of the material were investigated.

  16. CENTRAL CONVEYING & AUTO FEEDING SYSTEMS FOR AN INJECTION MOLDING SHOP

    Directory of Open Access Journals (Sweden)

    Sanjeev Kumar

    2011-08-01

    Full Text Available Nowadays injection molding is probably the most important method of Processing of consumer and industrial goods, and is performed everywhere in the world. The developing of injection molding becomes a competition from day to day. This Process now integrated with computer control make the production better in quality and Better quantity. The trends of producing a plastics product in injection molding industries are recently changing from traditional method to using the FEA analysis. For injection molding industries, time and cost is very important aspects to consider because these two aspectswill directly related to the profits at a company. The next issue toconsider, to get the best parameter for the injection molding process, plastics has been waste. Through the experiment, operator will use large amount of plastics material to get the possibly parameters to setup the machine.To produce the parts with better quality and quantity these molding defects are the major obstacles in achieving the targets with quality & quantity. Various defects like Short shot, colour streaks and low productivity rates are associated with the material mixing and feeding as molded plastics are often a blend of two or more materials. Colors (master batch and other additives are often mixed (blended with the raw plastic material prior to the molding process in molding plants. So it is very necessary to work out auto blending and auto feeding of plasticgranules to the machine hopper. This paper will cover the studyof automatic blending unit & central conveying system for plasticgranule feeding to machine & will help in optimizing the injection molding process.

  17. Dynamic of taking out molding parts at injection molding

    Directory of Open Access Journals (Sweden)

    E. Ragan

    2012-10-01

    Full Text Available Most plastic parts used in automobile production are manufactured by injection molding. Their quality depends also on taking out molding and on the manipulators for it. Task of this contribution is to theoretically describe a transport of molding at taking out after injection molding in relation on its regulation. The following quantities are derived at it: the transition characteristic of the taking out system, the blocking diagram of taking out molding regulation, the amplitude and phase characteristic and the transition characteristic of action quantity at taking out molding regulation.

  18. Process and part filling control in micro injection molding

    DEFF Research Database (Denmark)

    Tosello, Guido; Hansen, Hans NØrgaard

    2008-01-01

    The influence of process parameters on ?-injection molding (?IM) and on ?-injection molded parts has been investigated using Design of Experiments. A mold with a sensor applied at injection location was used to monitor actual injection pressure and to determine the cavity filling time. Flow markers position was measured on the polymer ?-parts to evaluate filling behavior of the polymer melt flowing through ?-features. Experimental results obtained under different processing conditions were evaluated to correlate the process parameter levels influence on the selected responses. Results showed that the injection speed in one of the most influencing process parameters on the ?IM process and on the ?-parts filling.

  19. Two component micro injection molding for MID fabrication

    DEFF Research Database (Denmark)

    Islam, Mohammad Aminul; Hansen, Hans NØrgaard

    2009-01-01

    Molded Interconnect Devices (MIDs) are plastic substrates with electrical infrastructure. The fabrication of MIDs is usually based on injection molding and different process chains may be identified from this starting point. The use of MIDs has been driven primarily by the automotive sector, but recently the medical sector seems more and more interested. In particular the possibility of miniaturization of 3D components with electrical infrastructure is attractive. The paper describes possible manufacturing routes and challenges of miniaturized MIDs based on two component micro injection molding and subsequent metallization. The technology will be demonstrated by an industrial component.

  20. Fast prototyping of injection molded polymer microfluidic chips

    International Nuclear Information System (INIS)

    We present fast prototyping of injection molding tools by the definition of microfluidic structures in a light-curable epoxy (SU-8) directly on planar nickel mold inserts. Optimized prototype mold structures could withstand injection molding of more than 300 replicas in cyclic olefin copolymer (COC) without any signs of failure or release. The key parameters to avoid mold failure are maximum adhesion strength of the epoxy to the nickel insert and minimum interfacial energy of the epoxy pattern to the molded polymer. Optimal molding of microstructures with vertical sidewalls was found for nickel inserts pre-coated by silicon oxide before applying the structured epoxy, followed by coating of the epoxy by a fluorocarbon layer prior to injection molding. Further improvements in the mold stability were observed after homogeneous coating of the patterned epoxy by a second reflowed layer of epoxy, likely due to the resulting reduction in sidewall steepness. We employed the latter method for injection molding bondable polymer microfluidic chips with integrated conducting polymer electrode arrays that permitted the culture and on-chip analysis of cell spreading by impedance spectroscopy

  1. Microstructural and mechanical characterization of injection molded 718 superalloy powders

    International Nuclear Information System (INIS)

    Highlights: •Microstructural and mechanical properties of injection molded Nickel 718 superalloy were studied. •The maximum sintered density achieved this study was 97.3% at 1290 °C for 3 hours. •Tensile strength of 1022 MPa and elongation of 5.3% were achieved for sintered-heat treated samples. -- Abstract: This study concerns with the determination of optimum production parameters for injection molding 718 superalloy parts. And at the same time, microstructural and mechanical characterization of these produced parts was also carried out. At the initial stage, 718 superalloy powders were mixed with a multi-component binder system for preparing feedstock. Then the prepared feedstock was granulated and shaped by injection molding. Following this operation, the shaped samples were subjected to the debinding process. These samples were sintered at different temperatures for various times. Samples sintered under the condition that gave way to the highest relative density (3 h at 1290 °C) were solution treated and aged respectively. Sintered, solution treated and aged samples were separately subjected to microstructural and mechanical characterization. Microstructural characterization operations such as X-ray diffraction, optical microscope (OM), scanning electron microscope (SEM), transmission electron microscope (TEM) and elemental analysis showed that using polymeric binder system led to plentiful carbide precipitates to be occurred in the injection molded samples. It is also observed that the volume fractions of the intermetallic phases (?? and ??) obtained by aging treatment were decreased due to the plentiful carbide precipitation in the samples. Mechanical characterization was performed by hardness measurements and tensile tests

  2. Microstructural and mechanical characterization of injection molded 718 superalloy powders

    Energy Technology Data Exchange (ETDEWEB)

    Özgün, Özgür [Bingol University, Faculty of Engineering and Architecture, Mechanical Eng. Dep., 12000 Bingol (Turkey); Gülsoy, H. Özkan, E-mail: ogulsoy@marmara.edu.tr [Marmara University, Technology Faculty, Metallurgy and Materials Eng. Dep., 34722 Istanbul (Turkey); Y?lmaz, Ramazan [Sakarya University, Technology Faculty, Metallurgy and Materials Eng. Dep., 54187 Sakarya (Turkey); F?nd?k, Fehim [Sakarya University, Technology Faculty, Metallurgy and Materials Eng. Dep., 54187 Sakarya (Turkey) and International University of Sarajevo, Faculty of Engineering and Natural Sciences, Department of Mechanical Engineering, 71000 Sarajevo, Bosnia and Herzegovina (Bosnia and Herzegowina)

    2013-11-05

    Highlights: •Microstructural and mechanical properties of injection molded Nickel 718 superalloy were studied. •The maximum sintered density achieved this study was 97.3% at 1290 °C for 3 hours. •Tensile strength of 1022 MPa and elongation of 5.3% were achieved for sintered-heat treated samples. -- Abstract: This study concerns with the determination of optimum production parameters for injection molding 718 superalloy parts. And at the same time, microstructural and mechanical characterization of these produced parts was also carried out. At the initial stage, 718 superalloy powders were mixed with a multi-component binder system for preparing feedstock. Then the prepared feedstock was granulated and shaped by injection molding. Following this operation, the shaped samples were subjected to the debinding process. These samples were sintered at different temperatures for various times. Samples sintered under the condition that gave way to the highest relative density (3 h at 1290 °C) were solution treated and aged respectively. Sintered, solution treated and aged samples were separately subjected to microstructural and mechanical characterization. Microstructural characterization operations such as X-ray diffraction, optical microscope (OM), scanning electron microscope (SEM), transmission electron microscope (TEM) and elemental analysis showed that using polymeric binder system led to plentiful carbide precipitates to be occurred in the injection molded samples. It is also observed that the volume fractions of the intermetallic phases (?? and ??) obtained by aging treatment were decreased due to the plentiful carbide precipitation in the samples. Mechanical characterization was performed by hardness measurements and tensile tests.

  3. Fast prototyping of injection molded polymer microfluidic chips

    DEFF Research Database (Denmark)

    Hansen, Thomas Steen; Selmeczi, David

    2010-01-01

    We present fast prototyping of injection molding tools by the definition of microfluidic structures in a light-curable epoxy (SU-8) directly on planar nickel mold inserts. Optimized prototype mold structures could withstand injection molding of more than 300 replicas in cyclic olefin copolymer (COC) without any signs of failure or release. The key parameters to avoid mold failure are maximum adhesion strength of the epoxy to the nickel insert and minimum interfacial energy of the epoxy pattern to the molded polymer. Optimal molding of microstructures with vertical sidewalls was found for nickel inserts pre-coated by silicon oxide before applying the structured epoxy, followed by coating of the epoxy by a fluorocarbon layer prior to injection molding. Further improvements in the mold stability were observed after homogeneous coating of the patterned epoxy by a second reflowed layer of epoxy, likely due to the resulting reduction in sidewall steepness. We employed the latter method for injection molding bondable polymer microfluidic chips with integrated conducting polymer electrode arrays that permitted the culture and on-chip analysis of cell spreading by impedance spectroscopy.

  4. Injection molded dielectromagnets prepared from mixture of hard magnetic powders

    International Nuclear Information System (INIS)

    Dielectromagnets are permanent magnets prepared from a hard magnetic powder bonded by binder. These permanent magnets are termed also as bonded permanent magnets. There are two ways to prepare dielectromagnets: compression molding and injection molding. Dielectromagnets prepared by injection molding, from the same hard magnetic powders, have worse magnetic properties than dielectromagnets prepared by compression molding, but they are cheaper. Isotropic dielectromagnets prepared from ferrite powder have low value of magnetic properties, but their advantage is positive value of temperature coefficient of JHc. They are low in price. Dielectromagnets prepared from melt-spun Nd-Fe-B have high values of magnetic properties.Value of temperature coefficient of JHc is their weakness. They are more expensive than ferrite dielectromagnets. Comparison of advantages and disadvantages of dielectromagnets prepared from different kinds of hard magnetic powder has produced an idea of making dielectromagnets from the mixture of these powders prepared by compression molding have magnetic and thermal properties of values between values of dielectromagnets from Nd-Fe-B and ferrite powders. It was described elsewhere. The purpose of this investigation is to prepare injection molded dielectromagnets from mixture of powders of strontium ferrite and melt-spun ribbon Nd-Fe-B and to find correlation between the composition of the mixture and magnetic properties of dielectromagnets. A result of mixture composition on magnetic properties of injection molded dielectromagnets is shown. (author)

  5. PHYSICAL PROPERTIES OF EXTRUDED AND INJECTION MOLDED CORN GLUTEN MEAL

    Science.gov (United States)

    This study was performed to investigate the compounding of corn gluten meal (CGM) and decanoic acid and to evaluate their mechanical properties. The mixture of CGM and 30% decanoic acid was compounded in a twin screw extruder, followed by injection molding. Scanning electron microscopy (SEM), tens...

  6. Residual stress distribution in injection molded parts

    Directory of Open Access Journals (Sweden)

    P. Postawa

    2006-08-01

    Full Text Available Purpose: The paper presents the results of the investigations of influence of the amorphous polystyrene (PSprocessing on the diversity of the internal stresses observed in the injection moulded piece.Design/methodology/approach: For the tests, the standardized mould piece designed for the investigations ofthe processing shrinkage of thermoplastics materials has been used. The samples have been prepared using theDesign of Experiment (DoE theory.The state of internal stresses has been analysed by means of photoelastic method (used stress viewer equipmenton the basis of the layout and size of the isochromatics (fields with the same colour, which determine the mouldpiece’s areas where the same value for the difference of main tensions. In the article the results of investigationsof influence of 5 chosen processing parameters such as injection temperature Tw, mould temperature Tf,clamping pressure pd, cooling time tch and the injection speed vw on the changes in isochromatics layout as adeterminant for diversity of internal stresses in injection moulded pieces have been presented.Findings: The performed investigations of the influence of injection conditions on the state of internal stressesreached for injection mould pieces were to determine the parameters of injection at which the achieved state ofthe stresses in the mould piece (described by the difference of main tensions will show the lowest values.Practical implications: Effects of examinations of influence of processing conditions on residual stress ininjection molded parts (presented in the article could find practical application in polymer industry, both smalland large enterprises.Originality/value: New approach to fast estimation of value of residual stresses were present in the paper.

  7. Injection molding of bushes made of tribological PEEK composites

    Directory of Open Access Journals (Sweden)

    2007-12-01

    Full Text Available Polyetheretherketone (PEEK composites have been extensively studied because of the excellent tribological behavior among plastics. However, laboratory specimens and tests are generally discussed, whereas application studies on industrial components are infrequent. In this paper, an injection molded bush made of tribological PEEK was analyzed to correlate wear behavior and molded material structure. Bushes were tested under unlubricated sliding conditions by means of a short wear test. Surface analysis, differential scanning calorimetry (DSC and optical microscopy were used to evaluate the distribution of the different composite fillers (polytetrafluoroethylene, PTFE, graphite particles and carbon microfibers and their effect on the final bush behavior. A significant lack of homogeneity was observed in the molded bush and black bands appeared on the shaft surface after testing due to the sliding. The bush geometry and the injection molding process should be optimized to allow the best tribological behavior of the molded material under working conditions.

  8. Pressureless sintering behavior of injection molded alumina ceramics

    Directory of Open Access Journals (Sweden)

    Liu W.

    2014-01-01

    Full Text Available The pressureless sintering behaviors of two widely used submicron alumina (MgOdoped and undoped with different solid loadings produced by injection molding have been studied systematically. Regardless of the sinterability of different powders depending on their inherent properties, solid loading plays a critical role on the sintering behavior of injection molded alumina, which greatly determines the densification and grain size, and leads to its full densification at low temperatures. As compared to the MgO-doped alumina powder, the undoped specimens exhibit a higher sinterability for its smaller particle size and larger surface area. While full densification could be achieved for MgO-doped powders with only a lower solid loading, due to the fact that MgO addition can reduce the detrimental effect of the large pore space on the pore-boundary separation.

  9. Packing parameters effect on injection molding of polypropylene nanostructured surfaces

    DEFF Research Database (Denmark)

    Calaon, Matteo; Tosello, Guido

    2012-01-01

    In today´s industry, applications involving surface patterning of sub-?m to nanometer scale structures have shown a high growth potential. To investigate the injection molding capability of replicating sub-?m surface texture on a large scale area, a 30x80 mm2 tool insert with surface structures having a diameter of 500 nm was employed. The tool insert surface was produced using chemical-based-batch techniques such aluminum anodization and nickel electroplating. During the injection molding process, polypropylene (PP) was employed as material and packing phase parameters (packing time, packing pressure) were investigated. The replicated surface topographies were quantitatively characterized by atomic force microscopy using specific three-dimensional surface parameters and qualitatively inspected by scanning electron microscopy. Results showed that the degree of replication from the tool to the polymer part was mainly influenced by packing pressure level and distance from the gate.

  10. Injection molding of coarse 316L stainless steel powder

    International Nuclear Information System (INIS)

    Metal injection molding (MIM) process using 316L stainless steel powder of 45 ?m was investigated. The binder system consists of a major fraction of palm stearins and minor fraction of polyethylene with a powder loading of 65 vol. %. The rheological behaviour of the feedstock was determined using Capillary Rheometer. The feedstock then injected using vertical injection molding machine into the tensile test bar. Then molded parts were de bound and sintered in vacuum at temperature of 1360 degree Celsius. The results show that the viscosity of the feedstock decreased with the temperature increased. The best sintered density achieved was about 7.5 g/cm3 with the tensile strength of more than 460 MPa. The properties of the sintered specimens could be increased with the increasing of sintering temperature. (author)

  11. FPGA-Based Multiprocessor System for Injection Molding Control

    Directory of Open Access Journals (Sweden)

    Roque A. Osornio-Rios

    2012-10-01

    Full Text Available The plastic industry is a very important manufacturing sector and injection molding is a widely used forming method in that industry. The contribution of this work is the development of a strategy to retrofit control of an injection molding machine based on an embedded system microprocessors sensor network on a field programmable gate array (FPGA device. Six types of embedded processors are included in the system: a smart-sensor processor, a micro fuzzy logic controller, a programmable logic controller, a system manager, an IO processor and a communication processor. Temperature, pressure and position are controlled by the proposed system and experimentation results show its feasibility and robustness. As validation of the present work, a particular sample was successfully injected.

  12. Evaluation of stability for monolayer injection molding tools coating

    DEFF Research Database (Denmark)

    Cech, Jiri; Taboryski, Rafael J.

    2012-01-01

    We tested and characterized molecular coating of Aluminium and Nickel prototype molds and mold inserts for polymer replication via injection molding (IM). X-Ray photoelectron spectroscopy (XPS) data, sessile drop contact angles with multiple fluids, surface energy and roughness data have been collected and used to predict coating lifetimes. Samples have been characterized immediately after coating, after 500+ IM cycles to test durability and after 7 months to test temporal stability. Sessile dro...

  13. Comparison of two setups for induction heating in injection molding

    DEFF Research Database (Denmark)

    Menotti, Stefano; Hansen, Hans Nørgaard; Bissacco, Giuliano; Guerrier, Patrick; Tang, Peter Torben

    2015-01-01

    To eliminate defects and improve the quality of molded parts, increasing the mold temperature is one of the applicable solutions. A high mold temperature can increase the path flow of the polymer inside the cavity allowing reduction of the number of injection points, reduction of part thickness, and moulding of smaller and more complex geometries. The last two aspects are very important in micro injection molding. In this paper, a new embedded induction heating system is proposed and validated a...

  14. On the Injection Molding of Nanostructured Polymer Surfaces

    DEFF Research Database (Denmark)

    Pranov, Henrik; Rasmussen, Henrik K.; Larsen, Niels Bent; Gadegaard, Nikolaj

    2006-01-01

    Well-defined nano-topographies were prepared by electron-beam lithography and electroplated to form nickelshims. The surface pattern consisted of square pillars repeated equidistantly within the plane of the surface in a perpendicular arrangement. The width and distance between the squares both ranged from 310 to 3100 rim. All the pillars were 220 nm high. The nickel-shim was used as a surface-template during injection molding of polycarbonate. Secondly, a nickel shim, with a surface pattern con...

  15. CAE for Injection Molding — Past, Present and the Future

    Science.gov (United States)

    Wang, Kuo K.

    2004-06-01

    It is well known that injection molding is the most effective process for mass-producing discrete plastic parts of complex shape to the highest precision at the lowest cost. However, due to the complex property of polymeric materials undergoing a transient non-isothermal process, it is equally well recognized that the quality of final products is often difficult to be assured. This is particularly true when a new mold or material is encountered. As a result, injection molding has often been viewed as an art than a science. During the past few decades, numerical simulation of injection molding process based on analytic models has become feasible for practical use as computers became faster and cheaper continually. A research effort was initiated at the Cornell Injection Molding Program (CIMP) in 1974 under a grant from the National Science Foundation. Over a quarter of the century, CIMP has established some scientific bases ranging from materials characterization, flow analysis, to prediction of part quality. Use of such CAE tools has become common place today in industry. Present effort has been primarily aimed at refinements of many aspects of the process. Computational efficiency and user-interface have been main thrusts by commercial software developers. Extension to 3-dimensional flow analysis for certain parts has drawn some attention. Research activities are continuing on molding of fiber-filled materials and reactive polymers. Expanded molding processes such as gas-assisted, co-injection, micro-molding and many others are continually being investigated. In the future, improvements in simulation accuracy and efficiency will continue. This will include in-depth studies on materials characterization. Intelligent on-line process control may draw more attention in order to achieve higher degree of automation. As Internet technology continues to evolve, Web-based CAE tools for design, production, remote process monitoring and control can come to path. The CAE tools will eventually be integrated into an Enterprise Resources Planning (ERP) system as the trend of enterprise globalization continues.

  16. Ion channel recordings on an injection-molded polymer chip

    DEFF Research Database (Denmark)

    Tanzi, Simone; Matteucci, Marco; Christiansen, Thomas Lehrmann; Friis, Søren; Christensen, Mette Thylstrup; Garnæs, Jørgen; Wilson, Sandra; Kutchinsky, Jonatan; Taboryski, Rafael

    2013-01-01

    In this paper, we demonstrate recordings of the ion channel activity across the cell membrane in a biological cell by employing the so-called patch clamping technique on an injection-molded polymer microfluidic device. The findings will allow direct recordings of ion channel activity to be made using the cheapest materials and production platform to date and with the potential for very high throughput. The employment of cornered apertures for cell capture allowed the fabrication of devices witho...

  17. Two component micro injection molding for MID fabrication

    DEFF Research Database (Denmark)

    Islam, Mohammad Aminul; Hansen, Hans Nørgaard; Tang, Peter Torben

    2009-01-01

    Molded Interconnect Devices (MIDs) are plastic substrates with electrical infrastructure. The fabrication of MIDs is usually based on injection molding and different process chains may be identified from this starting point. The use of MIDs has been driven primarily by the automotive sector, but recently the medical sector seems more and more interested. In particular the possibility of miniaturization of 3D components with electrical infrastructure is attractive. The paper describes possible ma...

  18. Injection molding of high aspect ratio sub-100 nm nanostructures

    DEFF Research Database (Denmark)

    Matschuk, Maria; Larsen, Niels B

    2013-01-01

    We have explored the use of mold coatings and optimized processing conditions to injection mold high aspect ratio nanostructures (height-to-width >1) in cyclic olefin copolymer (COC). Optimizing the molding parameters on uncoated nickel molds resulted in slight improvements in replication quality as described by height, width and uniformity of the nanoscopic features. Use of a mold temperature transiently above the polymer glass transition temperature (Tg) was the most important factor in increa...

  19. Stability of FDTS monolayer coating on aluminum injection molding tools

    DEFF Research Database (Denmark)

    Cech, Jiri; Taboryski, Rafael J.

    2012-01-01

    The injection molding industry often employs prototype molds and mold inserts from melt spun (rapid solidification processing [1,2]) aluminum, especially for applications in optics [3,4], photonics [5] and microfludics. Prototypes are also used for verification of mold filling. The use of aluminum tools has reduced lead time (days instead of weeks) and manufacturing cost (30% of conventional mold). Moreover, for aluminum, a surface roughness (RMS) below 5 nm can be obtained with diamond machinin...

  20. Injection molding of high aspect ratio sub-100 nm nanostructures

    DEFF Research Database (Denmark)

    Matschuk, Maria; Larsen, Niels B

    2013-01-01

    We have explored the use of mold coatings and optimized processing conditions to injection mold high aspect ratio nanostructures (height-to-width >1) in cyclic olefin copolymer (COC). Optimizing the molding parameters on uncoated nickel molds resulted in slight improvements in replication quality as described by height, width and uniformity of the nanoscopic features. Use of a mold temperature transiently above the polymer glass transition temperature (Tg) was the most important factor in increasing the replication fidelity. Surface coating of the nickel molds with a fluorocarbon-containing thin film (FDTS) greatly enhanced the quality of replicated features, in particular at transient mold temperatures above Tg. Injection molding using the latter mold temperature regime resulted in a bimodal distribution of pillar heights, corresponding to either full or very poor replication of the individual pillars. The poorly replicated structures on nickel molds with or without FDTS coatings all appeared fractured. We investigated the underlying mechanism in a macroscopic model system and found reduced wetting and strongly decreased adhesion of solidified COC droplets on nickel surfaces after coating with FDTS. Reduced adhesion forces are consistent with lowered friction that reduces the risk of fracturing the nanoscopic pillars during demolding. Optimized mold surface chemistry and associated injection molding conditions permitted the fabrication of square arrays of 40 nm wide and 107 nm high (aspect ratio >2.5) pillars on a 200 nm pitch.

  1. Ion channel recordings on an injection-molded polymer chip

    DEFF Research Database (Denmark)

    Tanzi, Simone; Matteucci, Marco

    2013-01-01

    In this paper, we demonstrate recordings of the ion channel activity across the cell membrane in a biological cell by employing the so-called patch clamping technique on an injection-molded polymer microfluidic device. The findings will allow direct recordings of ion channel activity to be made using the cheapest materials and production platform to date and with the potential for very high throughput. The employment of cornered apertures for cell capture allowed the fabrication of devices without through holes and via a scheme comprising master origination by dry etching in a silicon substrate, electroplating in nickel and injection molding of the final part. The most critical device parameters were identified as the length of the patching capillary and the very low surface roughness on the inside of the capillary. The cross-sectional shape of the orifice was found to be less critical, as both rectangular and semicircular profiles seemed to have almost the same ability to form tight seals with cells with negligible leak currents. The devices were functionally tested using human embryonic kidney cells expressing voltage-gated sodium channels (Nav1.7) and benchmarked against a commercial state-of-the-art system for automated ion channel recordings. These experiments considered current–voltage (IV) relationships for activation and inactivation of the Nav1.7 channels and their sensitivity to a local anesthetic, lidocaine. Both IVs and lidocaine dose–response curves obtained from the injection-molded polymer device were in good agreement with data obtained from the commercial system.

  2. Metal injection molding (MIM) of NdFeB magnets

    OpenAIRE

    Hartwig T.; Lopes L.; Wendhausen P.; Ünal N.

    2014-01-01

    Due to the increased and unstable prices for Rare Earth elements there are activities to develop alternative hard magnetic materials. Reducing the amount of material necessary to produce complex sintered NdFeB magnets can also help to reduce some of the supply problem. Metal Injection Molding (MIM) is able to produce near net shape parts and can reduce the amount of finishing to achieve final geometry. Although MIM of NdFeB has been patented and published fairly soon after the development of ...

  3. RECENT METHODS FOR OPTIMIZATION OF PLASTIC INJECTION MOLDING PROCESS –A RETROSPECTIVE AND LITERATURE REVIEW

    OpenAIRE

    P.K.BHARTI; M. I. Khan,; Harbinder Singh

    2010-01-01

    Injection molding has been a challenging process for many manufacturers and researchers to produce products meeting requirements at the lowest cost. Faced with global competition in injection molding industry, using the trialand- error approach to determine the process parameters for injection molding is no longer good enough. Factors that affect the quality of a molded part can be classified into four categories: part design, mold design, machineperformance and processing conditions. The par...

  4. Gate design in injection molding of microfluidic components using process simulations

    DEFF Research Database (Denmark)

    Marhöfer, D. M.; Tosello, G.; Islam, A.; Hansen, H. N.

    2015-01-01

    Just as in conventional injection molding of plastics, process simulations are an effective tool in the area of micro injection molding. They are applied in order to optimize and aid the design of the micro plastic part, the mold and the actual process. Available simulation software is actually made for macroscopic injection molding, but by means of the correct implementation and modelling strategy it can also be applied to micro plastic parts, as it is shown in the presented work. Process simul...

  5. Validation of precision powder injection molding process simulations using a spiral test geometry

    DEFF Research Database (Denmark)

    Marhöfer, Maximilian; Müller, Tobias; Tosello, Guido; Islam, Aminul; Hansen, Hans N.; Piotter, Volker

    2015-01-01

    Like in many other areas of engineering, process simulations find application in precision injection molding to assist and optimize the quality and design of precise products and the molding process. Injection molding comprises mainly the manufacturing of plastic components. However, the variant of precision powder injection molding for the production of metallic and ceramic micro parts raises more and more interest though. Consequently, in the entire field the demand for simulation tools increa...

  6. Reinforcement and structure development in injection molding of bone-analogue composites

    OpenAIRE

    Sousa, R.A; R. L. Reis; Cunha, A. M.; Bevis, M. J.

    2002-01-01

    Composites of high density polyethylene (HDPE) with hydroxyapatite (HA—the main inorganic constituent of human bone) were produced by extrusion compounding and subsequent injection molding. Shear controlled orientation in injection molding (SCORIM) was used deliberately to induce a strong anisotropic character in the composite materials. Bi-composite moldings featuring a sandwich like morphology were also produced by mono-sandwich injection molding. These composites combine ...

  7. Injection molding tools with micro/nano-meter pattern

    DEFF Research Database (Denmark)

    Kristensen, Anders Technical University of Denmark,

    The present invention relates to methods for embedded a micrometer and/or nanometer pattern into an injection molding tool. In a first main aspect, a micro/nanometer structured imprinting device is applied in, or on, an active surface so as to transfer the micro/nanometer patterned structure to the tool while the imprinting device is, at least partly, within a cavity of the injection molding tool. In a second main aspect, a base plate with a micro/nanometer structured pattern positioned on an upper part is positioned on the active surface within the tool, the lower part of the base plate facing the tool, the active surface receiving the base plate being non-planar on a macroscopic scale. Both aspects enable a simple and effective way of transferring the pattern, and the pattern may be transferred on the active working site of tool immediately prior to molding without the need for extensive preparations or remounting of the tool before performing the molding process.

  8. On the Injection Molding of Nanostructured Polymer Surfaces

    DEFF Research Database (Denmark)

    Pranov, Henrik; Rasmussen, Henrik K.

    2006-01-01

    Well-defined nano-topographies were prepared by electron-beam lithography and electroplated to form nickelshims. The surface pattern consisted of square pillars repeated equidistantly within the plane of the surface in a perpendicular arrangement. The width and distance between the squares both ranged from 310 to 3100 rim. All the pillars were 220 nm high. The nickel-shim was used as a surface-template during injection molding of polycarbonate. Secondly, a nickel shim, with a surface pattern consisted of a squared sine with a period of 700 nm and amplitude of 450 nm, was mounted on, and it was in good thermal contact with the upper plate in a hot-press. Polycarbonate/polystyrene was melted on the lower plate while the temperature of the shim was kept below the glass transition temperature. The upper plate was lowered until the shim was in contact with the melt. Experiments were carried out with a clean shim and a shim coated with a monolayer of fluorocarbonsilane. As a result of the surface coating, the amplitude of the replicated grating decreased from about 350 nm in polycarbonate and 100 nm in polystyrene to less than 10 nm. The experiments strongly suggest that the possibility to injection mold sub-micrometer surface structures in polymers mainly relates to adhesive energy between polymer and shim.

  9. Stability of FDTS monolayer coating on aluminum injection molding tools

    DEFF Research Database (Denmark)

    Cech, Jiri; Taboryski, Rafael J.

    2012-01-01

    The injection molding industry often employs prototype molds and mold inserts from melt spun (rapid solidification processing [1,2]) aluminum, especially for applications in optics [3,4], photonics [5] and microfludics. Prototypes are also used for verification of mold filling. The use of aluminum tools has reduced lead time (days instead of weeks) and manufacturing cost (30% of conventional mold). Moreover, for aluminum, a surface roughness (RMS) below 5 nm can be obtained with diamond machining [3,4,6]. Conventional mold coatings add cost and complexity, and coatings with thicknesses of a few microns can obliterate small features. The nanoimprint lithography community extensively uses functional monolayer coatings on silicon/SiO2 lithographic stamps [7–11]. This treatment dramatically reduces stiction, and improves yield and quality of replicated nanostructures. Here we report on a fluorinated trichloro-silane based coating deposited on aluminum or its alloys by molecular vapor deposition. Wehave tested the stability of this coating in challenging conditions of injection molding, an environment with high shear stress from the molten polymer, pressures up to 200 MPa, temperatures up to 250 ?C, and rapid thermal cycling.

  10. A wide variety of injection molding technologies is now applicable to small series and mass production

    Energy Technology Data Exchange (ETDEWEB)

    Bloß, P., E-mail: bloss@kuz-leipzig.de, E-mail: juettner@kuz-leipzig.de, E-mail: jacob@kuz-leipzig.de, E-mail: loeser@kuz-leipzig.de, E-mail: michaelis@kuz-leipzig.de, E-mail: krajewsky@kuz-leipzig.de; Jüttner, G., E-mail: bloss@kuz-leipzig.de, E-mail: juettner@kuz-leipzig.de, E-mail: jacob@kuz-leipzig.de, E-mail: loeser@kuz-leipzig.de, E-mail: michaelis@kuz-leipzig.de, E-mail: krajewsky@kuz-leipzig.de; Jacob, S., E-mail: bloss@kuz-leipzig.de, E-mail: juettner@kuz-leipzig.de, E-mail: jacob@kuz-leipzig.de, E-mail: loeser@kuz-leipzig.de, E-mail: michaelis@kuz-leipzig.de, E-mail: krajewsky@kuz-leipzig.de; Löser, C., E-mail: bloss@kuz-leipzig.de, E-mail: juettner@kuz-leipzig.de, E-mail: jacob@kuz-leipzig.de, E-mail: loeser@kuz-leipzig.de, E-mail: michaelis@kuz-leipzig.de, E-mail: krajewsky@kuz-leipzig.de; Michaelis, J., E-mail: bloss@kuz-leipzig.de, E-mail: juettner@kuz-leipzig.de, E-mail: jacob@kuz-leipzig.de, E-mail: loeser@kuz-leipzig.de, E-mail: michaelis@kuz-leipzig.de, E-mail: krajewsky@kuz-leipzig.de; Krajewsky, P., E-mail: bloss@kuz-leipzig.de, E-mail: juettner@kuz-leipzig.de, E-mail: jacob@kuz-leipzig.de, E-mail: loeser@kuz-leipzig.de, E-mail: michaelis@kuz-leipzig.de, E-mail: krajewsky@kuz-leipzig.de [Kunststoff-Zentrum in Leipzig gGmbH (KuZ), Leipzig (Germany)

    2014-05-15

    Micro plastic parts open new fields for application, e. g., to electronics, sensor technologies, optics, and medical engineering. Before micro parts can go to mass production, there is a strong need of having the possibility for testing different designs and materials including material combinations. Hence, flexible individual technical and technological solutions for processing are necessary. To manufacture high quality micro parts, a micro injection moulding machine named formicaPlast based on a two-step plunger injection technology was developed. Resulting from its design, the residence time and the accuracy problems for managing small shot volumes with reproducible high accuracy are uncompromisingly solved. Due to their simple geometry possessing smooth transitions and non adherent inner surfaces, the plunger units allow to process 'all' thermoplastics from polyolefines to high performance polymers, optical clear polymers, thermally sensitive bioresorbables, highly filled systems (the so-called powder injection molding PIM), and liquid silicon rubber (LSR, here with a special kit). The applied platform strategy in the 1K and 2K version allows integrating automation for assembling, handling and packaging. A perpendicular arrangement allows encapsulation of inserts, also partially, and integration of this machine into process chains. Considering a wide variety of different parts consisting of different materials, the high potential of the technology is demonstrated. Based on challenging industrial parts from electronic applications (2K micro MID and bump mat, where both are highly structured parts), the technological solutions are presented in more detail.

  11. A Recurrent Neural Network for Warpage Prediction in Injection Molding

    Scientific Electronic Library Online (English)

    A., Alvarado-Iniesta; D.J., Valles-Rosales; J.L., García-Alcaraz; A., Maldonado-Macias.

    2012-12-01

    Full Text Available La inyección de plásticos se considera como uno de los procesos de manufactura más flexibles y económicos con un gran volumen de producción de piezas de plástico. Las causas de variación durante la inyección de plásticos se relacionan con el amplio número de factores que intervienen durante un ciclo [...] de producción regular, tales variaciones impactan la calidad del producto final. Un problema común de calidad en productos terminados es la presencia de deformaciones. Así, este estudio tuvo como objetivo diseñar un sistema basado en redes neuronales recurrentes para predecir defectos de deformación en productos fabricados por medio de inyección de plásticos. Se emplean cinco parámetros del proceso por ser considerados críticos y que tienen un gran impacto en la deformación de componentes plásticos. El presente estudio hizo uso del software de análisis finito llamado Moldflow para simular el proceso de inyección de plásticos para recolectar datos con el fin de entrenar y probar la red neuronal recurrente. Redes neuronales recurrentes fueron utilizadas para entender la dinámica del proceso y debido a su capacidad de memorización, los valores de deformación pudieron ser predichos con exactitud. Los resultados muestran que la red diseñada funciona bien en términos de predicción, superando aquellas predicciones generadas por redes de propagación hacia adelante. Abstract in english Injection molding is classified as one of the most flexible and economical manufacturing processes with high volume of plastic molded parts. Causes of variations in the process are related to the vast number of factors acting during a regular production run, which directly impacts the quality of fin [...] al products. A common quality trouble in finished products is the presence of warpage. Thus, this study aimed to design a system based on recurrent neural networks to predict warpage defects in products manufactured through injection molding. Five process parameters are employed for being considered to be critical and have a great impact on the warpage of plastic components. This study used the finite element analysis software Moldflow to simulate the injection molding process to collect data in order to train and test the recurrent neural network. Recurrent neural networks were used to understand the dynamics of the process and due to their memorization ability, warpage values might be predicted accurately. Results show the designed network works well in prediction tasks, overcoming those predictions generated by feedforward neural networks.

  12. POWDER INJECTION MOLDING OF SIC FOR THERMAL MANAGEMENT V

    Directory of Open Access Journals (Sweden)

    Valmikanathan Onbattuvelli

    2012-06-01

    Full Text Available Silicon carbide (SiC exhibits many functional properties that are relevant to applications in electronics, aerospace, defense and automotive industries. However, the successful translation of these properties into final applications lies in the net-shaping of ceramics into fully dense microstructures. Increasing the packing density of the starting powders is one effective route to achieve high sintered density and dimensional precision. The present paper presents an in-depth study on the effects of nanoparticle addition on the powder injection molding process (PIM of SiC powder-polymer mixtures. In particular, bimodal mixtures of nanoscale and sub-micrometer particles are found to have significantly increased powder packing characteristics (solids loading in the powder-polymer mixtures. The influence of nanoparticle addition on the multi-step PIM process is examined. The above results provide new perspectives which could impact a wide range of materials, powder processing techniques and applications.

  13. Rapid control of mold temperature during injection molding process

    International Nuclear Information System (INIS)

    The control of mold surface temperature is an important factor that determines surface morphology and its dimension in thickness direction. It can also affect the frozen molecular orientation and the mold surface replicability in injection molded products. In this work, thin thermally active films were used to quickly control the mold surface temperature. In particular, an active high electrical conductivity carbon black loaded polyimide composites sandwiched between two insulating thin polymeric layers was used to condition the mold surface. By controlling the heating time, it was possible to control precisely the temporal variation of the mold temperature surface during the entire cycle. The surface heating rate was about 40°C/s and upon contact with the polymer the surface temperature decreased back to 40°C within about 5 s; the overall cycle time increased only slightly. The effect on cross section sample morphology of samples of iPP were analyzed and discussed on the basis of the recorded temperature evolution

  14. Rapid control of mold temperature during injection molding process

    Science.gov (United States)

    Liparoti, Sara; Hunag, Tsang Min; Sorrentino, Andrea; Titomanlio, Giuseppe; Cakmak, Mukerrem

    2015-05-01

    The control of mold surface temperature is an important factor that determines surface morphology and its dimension in thickness direction. It can also affect the frozen molecular orientation and the mold surface replicability in injection molded products. In this work, thin thermally active films were used to quickly control the mold surface temperature. In particular, an active high electrical conductivity carbon black loaded polyimide composites sandwiched between two insulating thin polymeric layers was used to condition the mold surface. By controlling the heating time, it was possible to control precisely the temporal variation of the mold temperature surface during the entire cycle. The surface heating rate was about 40°C/s and upon contact with the polymer the surface temperature decreased back to 40°C within about 5 s; the overall cycle time increased only slightly. The effect on cross section sample morphology of samples of iPP were analyzed and discussed on the basis of the recorded temperature evolution.

  15. Evaluation of stability for monolayer injection molding tools coating

    DEFF Research Database (Denmark)

    Cech, Jiri; Taboryski, Rafael J.

    2012-01-01

    We tested and characterized molecular coating of Aluminium and Nickel prototype molds and mold inserts for polymer replication via injection molding (IM). X-Ray photoelectron spectroscopy (XPS) data, sessile drop contact angles with multiple fluids, surface energy and roughness data have been collected and used to predict coating lifetimes. Samples have been characterized immediately after coating, after 500+ IM cycles to test durability and after 7 months to test temporal stability. Sessile drop contact angle was measured for multiple fluids, namely water, di-iodomethane and benzylacohol. Detectable coating presence was indicated by an increased angle on all post IM samples. To conclude, we present mold coating evaluation method, which is well suited for ultrathin, controlable, covalently bonded coating, that is reasonably durable, affordable, scalable to production, detectable on surface and especially suitable for rapid prototyping and mold geometry testing.

  16. Rapid control of mold temperature during injection molding process

    Energy Technology Data Exchange (ETDEWEB)

    Liparoti, Sara; Titomanlio, Giuseppe [Department of Industrial Engineering, University of Salerno Via Giovanni Paolo II, 132, 84084 Fisciano (Italy); Hunag, Tsang Min; Cakmak, Mukerrem [Department of Polymer Engineering, The University of Akron, Akron, OH 44325 (United States); Sorrentino, Andrea [Institute for Polymers, Composite and Biomaterials (IPCB) - CNR, P. Enrico Fermi 1, 80055 Portici (Italy)

    2015-05-22

    The control of mold surface temperature is an important factor that determines surface morphology and its dimension in thickness direction. It can also affect the frozen molecular orientation and the mold surface replicability in injection molded products. In this work, thin thermally active films were used to quickly control the mold surface temperature. In particular, an active high electrical conductivity carbon black loaded polyimide composites sandwiched between two insulating thin polymeric layers was used to condition the mold surface. By controlling the heating time, it was possible to control precisely the temporal variation of the mold temperature surface during the entire cycle. The surface heating rate was about 40°C/s and upon contact with the polymer the surface temperature decreased back to 40°C within about 5 s; the overall cycle time increased only slightly. The effect on cross section sample morphology of samples of iPP were analyzed and discussed on the basis of the recorded temperature evolution.

  17. Fiber breakage phenomena in long fiber reinforced plastic preparation

    Science.gov (United States)

    Huang, Chao-Tsai; Tseng, Huan-Chang; Vlcek, Jiri; Chang, Rong-Yeu

    2015-07-01

    Due to the high demand of smart green, the lightweight technologies have become the driving force for the development of automotives and other industries in recent years. Among those technologies, using short and long fiber-reinforced plastics (FRP) to replace some metal components can reduce the weight of an automotive significantly. However, the microstructures of fibers inside plastic matrix are too complicated to manage and control during the injection molding through the screw, the runner, the gate, and then into the cavity. This study focuses on the fiber breakage phenomena during the screw plastification. Results show that fiber breakage is strongly dependent on screw design and operation. When the screw geometry changes, the fiber breakage could be larger even with lower compression ratio.

  18. Characterization of polymeric binders for Metal Injection Molding (MIM) process

    Science.gov (United States)

    Adames, Juan M.

    The Metal Injection Molding (MIM) process is an economically attractive method of producing large amounts of small and complex metallic parts. This is achieved by combining the productivity of injection molding with the versatility of sintering of metal particulates. In MIM, the powdered metal is blended with a plastic binder to obtain the feedstock. The binder imparts flowability to the blend at injection molding conditions and strength at ambient conditions. After molding, the binder is removed in a sequence of steps that usually involves solvent-extraction and polymer burn-out. Once the binder is removed, the metal particles are sintered. In this research several topics of the MIM process were studied to understand how the polymeric binder, similar to the one used in the sponsoring company, works. This was done by examining the compounding and water debinding processes, the rheological and thermal properties, and the microstructure of the binder/metal composite at different processing stages. The factors studied included the metal contents, the composition of the binder and the processing conditions. The three binders prepared during the course of this research were blends of a polyolefin, polyoxymethylene copolymer (POM) and a water-soluble polymer (WSP). The polyolefin resins included polypropylene (PP), high-density polyethylene (HDPE) and linear low-density polyethylene (LLDPE). The powdered metal in the feedstocks was 316 L stainless steel. The compounding studies were completed in an internal mixer under different conditions of temperature, rotational speed and feedstock composition. It was found that the metal concentration was the most important factor in determining the torque evolution curves. The observation of microstructure with Scanning Electron Microscope (SEM) at different stages during compounding revealed that the metal particles neither agglomerate nor touch each other. The liquid extraction of the water-soluble polymer (WSP) from the molded parts (or water debinding) was investigated using two configurations of flow of water relative to the samples. Both permitted the reduction of the mass transfer resistance outside the parts, revealing information on the diffusion of the WSP inside the part exclusively. The debinding studies showed that a single effective diffusivity could be used to model the extraction process of the binder from molded parts. This approach is more accurate when the debinding time is above 2 hours. Steady shear and dynamic experiments were conducted on the binder and feedstocks samples containing LLDPE. The results of both experiments revealed that the feedstocks did not show yield stress even though the highest metal content was 64% by volume. Therefore, it was concluded that there were only hydrodynamic interactions between the metal particles. The thermal characterization of binders, polymers and feedstocks included differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The DSC tests were performed after preheating and quenching of the samples. The heating rate was 20°C/min. The TGA scans were conducted from room temperature to 700°C at 20°C/min. The DSC tests revealed that the melting point of the polymers depressed when blended in the binders and feedstocks. The depression was more intense for POM and the water-soluble polymer than for the polyolefins. Therefore, it was concluded that the melting point depression of POM and the water-soluble polymer was caused by their entrapment in the polyolefin matrix and in between the metal particles. The TGA scans showed that the feedstocks with higher metal concentration had higher final decomposition temperature, but similar onset temperature. The reason was that the higher the metal concentration the more difficult the diffusion of the products of the decomposition of the binder out of the samples. The morphological studies revealed that the binders were heterogeneous showing domains of the polar resins, embedded in a continuous phase composed of polyolefin. This distribution of phases was the result of th

  19. Metal Injection Molding (MIM) of NdFeB Magnets

    Science.gov (United States)

    Hartwig, T.; Lopes, L.; Wendhausen, P.; Ünal, N.

    2014-07-01

    Due to the increased and unstable prices for Rare Earth elements there are activities to develop alternative hard magnetic materials. Reducing the amount of material necessary to produce complex sintered NdFeB magnets can also help to reduce some of the supply problem. Metal Injection Molding (MIM) is able to produce near net shape parts and can reduce the amount of finishing to achieve final geometry. Although MIM of NdFeB has been patented and published fairly soon after the development of the NdFeB magnets there has never been an industrial production. This could be due to the fact that MIM was very young at that time and hardly developed. Thus, the feasibility of the process needs to be revaluated. This paper presents results of our work on determining the process parameters influencing the magnetic properties of the sintered magnets as well as the shrinkage during processing. The role of binder and powder loading on the alignment of the particles as well as on the carbon and oxygen contamination was examined.

  20. Injection molded polymeric micropatterns for bone regeneration study.

    Science.gov (United States)

    Zanchetta, Erika; Guidi, Enrica; Della Giustina, Gioia; Sorgato, Marco; Krampera, Mauro; Bassi, Giulio; Di Liddo, Rosa; Lucchetta, Giovanni; Conconi, Maria Teresa; Brusatin, Giovanna

    2015-04-01

    An industrially feasible process for the fast mass-production of molded polymeric micro-patterned substrates is here presented. Microstructured polystyrene (PS) surfaces were obtained through micro injection molding (?IM) technique on directly patterned stamps realized with a new zirconia-based hybrid spin-on system able to withstand 300 cycles at 90 °C. The use of directly patterned stamps entails a great advantage on the overall manufacturing process as it allows a fast, flexible, and simple one-step process with respect to the use of milling, laser machining, electroforming techniques, or conventional lithographic processes for stamp fabrication. Among the different obtainable geometries, we focused our attention on PS replicas reporting 2, 3, and 4 ?m diameter pillars with 8, 9, 10 ?m center-to-center distance, respectively. This enabled us to study the effect of the substrate topography on human mesenchymal stem cells behavior without any osteogenic growth factors. Our data show that microtopography affected cell behavior. In particular, calcium deposition and osteocalcin expression enhanced as diameter and interpillar distance size increases, and the 4-10 surface was the most effective to induce osteogenic differentiation. PMID:25756304

  1. Imprinted and injection-molded nano-structured optical surfaces

    DEFF Research Database (Denmark)

    Christiansen, Alexander Bruun Technical University of Denmark,

    2013-01-01

    Inspired by nature, nano-textured surfaces have attracted much attention as a method to realize optical surface functionality. The moth-eye antireflective structure and the structural colors of Morpho butterflies are wellknown examples used for inspiration for such biomimetic research. In this paper, nanostructured polymer surfaces suitable for up-scalable polymer replication methods, such as imprinting/embossing and injection-molding, are discussed. The limiting case of injection-moulding compatible designs is investigated. Anti-reflective polymer surfaces are realized by replication of Black Silicon (BSi) random nanostructure surfaces. The optical transmission at normal incidence is measured for wavelengths from 400 nm to 900 nm. For samples with optimized nanostructures, the reflectance is reduced by 50 % compared to samples with planar surfaces. The specular and diffusive reflection of light from polymer surfaces and their implication for creating structural colors is discussed. In the case of injection-moulding compatible designs, the maximum reflection of nano-scale textured surfaces cannot exceed the Fresnel reflection of a corresponding flat polymer surface, which is approx. 4 % for normal incidence. Diffraction gratings provide strong color reflection defined by the diffraction orders. However, the apperance varies strongly with viewing angles. Three different methods to address the strong angular-dependence of diffraction grating based structural color are discussed.

  2. Metal Injection Molding (MIM of NdFeB Magnets

    Directory of Open Access Journals (Sweden)

    Hartwig T.

    2014-07-01

    Full Text Available Due to the increased and unstable prices for Rare Earth elements there are activities to develop alternative hard magnetic materials. Reducing the amount of material necessary to produce complex sintered NdFeB magnets can also help to reduce some of the supply problem. Metal Injection Molding (MIM is able to produce near net shape parts and can reduce the amount of finishing to achieve final geometry. Although MIM of NdFeB has been patented and published fairly soon after the development of the NdFeB magnets there has never been an industrial production. This could be due to the fact that MIM was very young at that time and hardly developed. Thus, the feasibility of the process needs to be revaluated. This paper presents results of our work on determining the process parameters influencing the magnetic properties of the sintered magnets as well as the shrinkage during processing. The role of binder and powder loading on the alignment of the particles as well as on the carbon and oxygen contamination was examined.

  3. Flexural Properties of Injection-Molded Bamboo/pbs Composites

    Science.gov (United States)

    Ohkita, Kazuya; Takagi, Hitoshi

    In recent years, from an environmental perspective, there has been increasing interest in the change to a sustainable society. The use of natural-fiber-reinforced biodegradable composites has been proposed as one solution. Bamboo is an often used renewable bio-resource; it has an inherent advantage of rapid growth. Polybutylene succinate (PBS), used as matrix resin, has biodegradable characteristics. This paper describes flexural properties of bamboo/PBS composites prepared by injection molding. The following results were obtained. The flexural modulus was improved with increasing bamboo powder contents when the cylinder temperature of the injection molder was 140°C. However, the flexural strength showed the opposite tendency to be decreased with increasing bamboo powder contents. An SEM photomicrograph of the fracture surface for bamboo/PBS composites showed typical fracture behavior of pull-out fibers without fiber fracture. Furthermore, there was no adhesion of PBS resin on the bamboo fiber surface. Processing conditions affected mechanical properties of bamboo/PBS composites, imparting higher flexural strength and flexural modulus at high cylinder temperatures such as 180°C and 200°C.

  4. Development of Defects Free Stainless Steel Parts Using Powder Injection Molding

    Directory of Open Access Journals (Sweden)

    M.A. Omar

    2013-01-01

    Full Text Available Austenitic 316L Stainless Steel (SS is widely used in aerospace, automotive, sports and medical industries due to its mechanical properties and corrosion resistance. Defects free molding of parts depends upon the features of feedstock. In powder injection molding, feedstock preparation is critical step and any deficiency at this stage cannot be retrieve in latter steps. The objective of this research work is to optimize solid loading for defects free injection molded parts. During the present research work five formulations having solid loading 60-71 vol% were prepared by using multi component binder system. The degradation temperature of feedstocks was determined by using Thermogravimetric analysis (TGA and flow behavior through rheometer. Homogeneity of the feedstock was verified by using Scanning Electron Microscopy (SEM. Finally, injection molding was done and it was found that the feedstocks having solid loading up to 69 vol% were successfully injection molded and components were without physical defects.

  5. Design of Multimodel based MPC and IMC control schemes applied to injection molding machine

    Directory of Open Access Journals (Sweden)

    Kanaga Lakshmi

    2014-03-01

    Full Text Available Good control of plastic melt temperature for injection molding is very important in reducing operator setup time, ensuring product quality, and preventing thermal degradation of the melt. The controllability and set points of barrel temperature also depend on the precise monitoring and control of plastic melt temperature. Motivated by the practical temperature control of injection molding, this paper proposes MPC and IMC based control scheme. A robust system identification and control methodology is developed which uses canonical varieties analysis for identification and model predictive control for regulation. The injection molding process consists of three zones and the mathematical model for each of the zone is different. The control output for each zone controller is assigned a weight based on the computed probability of each model and the resulting action is the weighted average of the control moves of the individual zone controllers.   Keywords: Injection-Molding Machine (IMM, IMC Control, Temperature Control.

  6. Development of the computer-aided process planning (CAPP) system for polymer injection molds manufacturing

    OpenAIRE

    J. Tepi?; V. Todi?; Luki?, D.; Miloševi?, M.; S. Borojevi?

    2011-01-01

    Beginning of production and selling of polymer products largely depends on mold manufacturing. The costs of mold manufacturing have significant share in the final price of a product. The best way to improve and rationalize polymer injection molds production process is by doing mold design automation and manufacturing process planning automation. This paper reviews development of a dedicated process planning system for manufacturing of the mold for injection molding, which integrates computer-...

  7. Injection molded superhydrophobic surfaces based on microlithography and black silicon processing

    DEFF Research Database (Denmark)

    Søgaard, Emil; Andersen, Nis Korsgaard; Taboryski, Rafael; Smistrup, Kristian

    2012-01-01

    This work is concerned with the design, development, and testing of nanostructured polymer surfaces with self-cleaning properties that can be manufactured by injection molding. In particular, the superimposed micro- and nanometer length scales of the so-called Lotus effect were investigated in detail with an engineering perspective on choice of materials and manufacturability by injection molding. Microscope slides with superhydrophobic properties were succesfully fabricated. Preliminary results...

  8. Powder Injection Molding of Al-(Steel and Magnet) Hybrid Components

    Science.gov (United States)

    Liu, Z. Y.; Kent, D.; Schaffer, G. B.

    2009-12-01

    A powder injection molding (PIM) process was developed to prepare aluminum hybrid components incorporating low carbon steel, AlNiCo, or BaFeO magnetic inserts. The inserts were securely bound within the powder injection molded aluminum due to sintering shrinkage and physical reaction at the interface. The low sintering temperature of the aluminum alloy ensured a minimal level of interfacial reaction and limited the degradation of the properties of the inserts.

  9. An X-ray Scattering Study of Water-Conditioned Injection- Molded Starch during Isothermal Heating

    OpenAIRE

    Cagiao, M.E.; Bayer, R. K.; Rueda, D. R.; Baltá Calleja, F. J.

    2003-01-01

    The in situ structure variation of injection molded starch (as processed and after water conditioning)during heat treatment was investigated by means of wideangle X-ray scattering using synchrotron radiation. Results confirm that the crystal structure of potato starch is destroyed after injection molding, while as-processed corn starch preserves some degree of crystallinity. This residual crystallinity in corn starch is related to the crystalline Vh form,made of complexes of amylose with l...

  10. Predictive Engineering Tools for Injection-Molded Long-Carbon-Fiber Thermoplastic Composites

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Ba Nghiep; Simmons, Kevin L.

    2013-05-30

    This quarterly report summarizes the status for the project planning to complete all the legal and contract documents required for establishing the subcontracts needed and a Cooperative Research and Development Agreement (CRADA) with Autodesk, Inc., Toyota Motor Engineering and Manufacturing North America (Toyota), and Magna Exterior and Interiors Corporation (Magna). During the second quarter (1/1/2013 to 3/31/2013), all the technical and legal documents for the subcontracts to Purdue University, University of Illinois, and PlastiComp, Inc. were completed. The revised CRADA documents were sent to DOE, Autodesk, Toyota, and Magna for technical and legal reviews. PNNL Legal Services contacted project partners’ Legal counterparts for completing legal documents for the project. A non-disclosure agreement was revised and sent to all the parties for reviews.

  11. Predictive Engineering Tools for Injection-Molded Long-Carbon-Fiber Thermoplastic Composites - Quarterly Report

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Ba Nghiep; Simmons, Kevin L.

    2013-04-04

    This quarterly report summarizes the status for the project planning to initiate all the legal and contract documents required for establishing the subcontracts needed and a Cooperative Research and Development Agreement (CRADA) with Autodesk, Inc., Toyota Motor Engineering and Manufacturing North America (Toyota), and Magna Exterior and Interiors Corporation (Magna). During the first quarter (10/1/2012 to 12/31/2012), the statements of work (SOW) for the subcontracts to Purdue University, University of Illinois, and PlastiComp, Inc. were completed. A draft of the CRADA SOW was sent to Autodesk, Toyota, and Magna for technical and legal reviews. PNNL Legal Services contacted project partners’ Legal counterparts for preparing legal documents for the project. A non-disclosure agreement was drafted and sent to all the parties for reviews.

  12. RECENT METHODS FOR OPTIMIZATION OF PLASTIC INJECTION MOLDING PROCESS –A RETROSPECTIVE AND LITERATURE REVIEW

    Directory of Open Access Journals (Sweden)

    P.K. Bharti

    2010-09-01

    Full Text Available Injection molding has been a challenging process for many manufacturers and researchers to produce products meeting requirements at the lowest cost. Faced with global competition in injection molding industry, using the trialand- error approach to determine the process parameters for injection molding is no longer good enough. Factors that affect the quality of a molded part can be classified into four categories: part design, mold design, machineperformance and processing conditions. The part and mold design are assumed as established and fixed. During production, quality characteristics may deviate due to drifting or shifting of processing conditions caused by machine wear, environmental change or operator fatigue. Determining optimal process parameter settings critically influences productivity, quality, and cost of production in the plastic injection molding (PIM industry. Previously, production engineers used either trial-and-error method or Taguchi’s parameter design method to determine optimal process parameter settings for PIM. However, these methods are unsuitable in present PIM because of the increasing complexity of product design and the requirement of multi-response quality characteristics. This article aims to review the recent research in designing and determining process parameters of injection molding. A number of research works based on various approaches have been performed in the domain of the parameter setting for injection molding. These approaches, including mathematical models, Taguchi method, Artificial Neural Networks (ANN,Fuzzy logic, Case Based Reasoning (CBR, Genetic Algorithms (GA, Finite Element Method(FEM,Non Linear Modeling, Response Surface Methodology, Linear Regression Analysis ,Grey Rational Analysis and Principle Component Analysis (PCA are described in this article. The strength and theweakness of individual approaches are discussed. It is then followed by conclusions and discussions of the potential research in determining process parameters for injection molding.

  13. Electrical and dielectric properties of foam injection-molded polypropylene/multiwalled carbon nanotube composites

    International Nuclear Information System (INIS)

    A combination of high dielectric permittivity (??) and low dielectric loss (tan ?) is required for charge storage applications. In percolative systems such as conductive polymer composites, however, obtaining high ?? and low tan ? is very challenging due to the sharp insulation-conduction transition near the threshold region. Due to the particular arrangement of conductive fillers induced by both foaming and injection molding processes, they may address this issue. Therefore, this work evaluates the application of foam injection molding process in fabricating polymer nanocomposites for energy storage. Polypropylene-multiwalled carbon nanotubes (PP-MWCNT) composites were prepared by melt mixing and foamed in an injection molding process. Electrical conductivity (?), ?? and tan ? were then characterized. Also, scanning and transmission electron microscopy (SEM and TEM) was used to investigate the carbon nanotube’s arrangement as well as cellular morphology. The results showed that foam injection-molded composites exhibited highly superior dielectric properties to those of solid counterparts. For instance, foamed samples had ??=68.3 and tan ? =0.05 (at 1.25 vol.% MWCNT), as opposed to ??=17.8 and tan ?=0.04 in solid samples (at 2.56 vol.% MWCNT). The results of this work reveal that high performance dielectric nanocomposites can be developed using foam injection molding technologies for charge storage applications

  14. Electrical and dielectric properties of foam injection-molded polypropylene/multiwalled carbon nanotube composites

    Science.gov (United States)

    Ameli, A.; Nofar, M.; Saniei, M.; Hossieny, N.; Park, C. B.; Pötschke, P.

    2015-05-01

    A combination of high dielectric permittivity (?') and low dielectric loss (tan ?) is required for charge storage applications. In percolative systems such as conductive polymer composites, however, obtaining high ?' and low tan ? is very challenging due to the sharp insulation-conduction transition near the threshold region. Due to the particular arrangement of conductive fillers induced by both foaming and injection molding processes, they may address this issue. Therefore, this work evaluates the application of foam injection molding process in fabricating polymer nanocomposites for energy storage. Polypropylene-multiwalled carbon nanotubes (PP-MWCNT) composites were prepared by melt mixing and foamed in an injection molding process. Electrical conductivity (?), ?' and tan ? were then characterized. Also, scanning and transmission electron microscopy (SEM and TEM) was used to investigate the carbon nanotube's arrangement as well as cellular morphology. The results showed that foam injection-molded composites exhibited highly superior dielectric properties to those of solid counterparts. For instance, foamed samples had ?'=68.3 and tan ? =0.05 (at 1.25 vol.% MWCNT), as opposed to ?'=17.8 and tan ?=0.04 in solid samples (at 2.56 vol.% MWCNT). The results of this work reveal that high performance dielectric nanocomposites can be developed using foam injection molding technologies for charge storage applications.

  15. Electrical and dielectric properties of foam injection-molded polypropylene/multiwalled carbon nanotube composites

    Energy Technology Data Exchange (ETDEWEB)

    Ameli, A.; Nofar, M.; Saniei, M.; Hossieny, N.; Park, C. B. [Microcellular Plastics Manufacturing Laboratory, Department of Mechanical and Industrial Engineering, University of Toronto, 5 King’s College Road, Toronto, Ontario, Canada M5S 3G8 (Canada); Pötschke, P. [Leibniz-Institut für Polymerforschung Dresden e.V. (IPF), Hohe Strasse 6, D-01069 Dresden (Germany)

    2015-05-22

    A combination of high dielectric permittivity (??) and low dielectric loss (tan ?) is required for charge storage applications. In percolative systems such as conductive polymer composites, however, obtaining high ?? and low tan ? is very challenging due to the sharp insulation-conduction transition near the threshold region. Due to the particular arrangement of conductive fillers induced by both foaming and injection molding processes, they may address this issue. Therefore, this work evaluates the application of foam injection molding process in fabricating polymer nanocomposites for energy storage. Polypropylene-multiwalled carbon nanotubes (PP-MWCNT) composites were prepared by melt mixing and foamed in an injection molding process. Electrical conductivity (?), ?? and tan ? were then characterized. Also, scanning and transmission electron microscopy (SEM and TEM) was used to investigate the carbon nanotube’s arrangement as well as cellular morphology. The results showed that foam injection-molded composites exhibited highly superior dielectric properties to those of solid counterparts. For instance, foamed samples had ??=68.3 and tan ? =0.05 (at 1.25 vol.% MWCNT), as opposed to ??=17.8 and tan ?=0.04 in solid samples (at 2.56 vol.% MWCNT). The results of this work reveal that high performance dielectric nanocomposites can be developed using foam injection molding technologies for charge storage applications.

  16. Effects of mold geometry on fiber orientation of powder injection molded metal matrix composites

    Science.gov (United States)

    Ahmad, Faiz; Aslam, Muhammad; Altaf, Khurram; Shirazi, Irfan

    2015-07-01

    Fiber orientations in metal matrix composites have significant effect on improving tensile properties. Control of fiber orientations in metal injection molded metal composites is a difficult task. In this study, two mold cavities of dimensions 6x6x90 mm and 10x20x180 mm were used for comparison of fiber orientation in injection molded metal composites test parts. In both mold cavities, convergent and divergent flows were developed by modifying the sprue dimensions. Scanning electron microscope (SEM) was used to examine the fiber orientations within the test samples. The results showed highly aligned fiber in injection molded test bars developed from the convergent melt flow. Random orientation of fibers was noted in the composites test bars produced from divergent melt flow.

  17. Computer Aided Design of The Cooling System for Plastic Injection Molds

    Directory of Open Access Journals (Sweden)

    Hakan GÜRÜN

    2009-02-01

    Full Text Available The design of plastic injection molds and their cooling systems affect both the dimension, the shape, the quality of a plastic part and the cycle time of process and the cost of mold. In this study, the solid model design of a plastic injection mold and the design of cooling sysytem were possibly carried out without the designer interaction. Developed program permited the use of three types of the cooling system and the different cavity orientations and the multible plastic part placement into the mold cores. The program which was developed by using Visual LISP language and the VBA (Visual BASIC for Application modules, was applicated in the AutoCAD software domain. Trial studies were presented that the solid model design of plastic injection molds and the cooling systems increased the reliability, the flexibility and the speed of the design.

  18. Bio-inspired piezoelectric artificial hair cell sensor fabricated by powder injection molding

    Science.gov (United States)

    Han, Jun Sae; Oh, Keun Ha; Moon, Won Kyu; Kim, Kyungseop; Joh, Cheeyoung; Seo, Hee Seon; Bollina, Ravi; Park, Seong Jin

    2015-12-01

    A piezoelectric artificial hair cell sensor was fabricated by the powder injection molding process in order to make an acoustic vector hydrophone. The entire process of powder injection molding was developed and optimized for PMN–PZT ceramic powder. The artificial hair cell sensor, which consists of high aspect ratio hair cell and three rectangular mechanoreceptors, was precisely fabricated through the developed powder injection molding process. The density and the dielectric property of the fabricated sensor shows 98% of the theoretical density and 85% of reference dielectric property of PMN–PZT ceramic powder. With regard to homogeneity, three rectangular mechanoreceptors have the same dimensions, with 3 ?m of tolerance with 8% of deviation of dielectric property. Packaged vector hydrophones measure the underwater acoustic signals from 500 to 800 Hz with ?212 dB of sensitivity. Directivity of vector hydrophone was acquired at 600 Hz as analyzing phase differences of electric signals.

  19. Injection-Molded Soft Magnets Prepared from Fe-Based Metallic Glass: Mechanical and Magnetic Properties

    Science.gov (United States)

    Zhong, Tian; Huang, Ran; Huang, Jia; Ouyang, Wei

    2015-09-01

    The injection-molded metallic glass soft magnet is prepared from the powder of melt-spun ribbon of Fe36Co36B20Si4Nb4 glassy alloy and Nylon 6,6 of wt.% from 5 to 20 via the polymer injection molding technology. The product is characterized by the SEM, mechanical, and magnetic test. The results indicate that this type of materials has comparable mechanical properties and morphological feature with the conventional injection-molded NdFeB magnet and exhibits excellent soft magnetic behaviors. The magnetic properties of the injected magnets are compared with the raw metallic glass, solvent-casted resin bonding magnets, and thermal-treated magnets to confirm that the processing temperature of Nylon injection does not affect the magnetism. The injection technology is a practical processing method to be applied on the metallic glass for potential usage.

  20. Injection-Molded Soft Magnets Prepared from Fe-Based Metallic Glass: Mechanical and Magnetic Properties

    Science.gov (United States)

    Zhong, Tian; Huang, Ran; Huang, Jia; Ouyang, Wei

    2015-10-01

    The injection-molded metallic glass soft magnet is prepared from the powder of melt-spun ribbon of Fe36Co36B20Si4Nb4 glassy alloy and Nylon 6,6 of wt.% from 5 to 20 via the polymer injection molding technology. The product is characterized by the SEM, mechanical, and magnetic test. The results indicate that this type of materials has comparable mechanical properties and morphological feature with the conventional injection-molded NdFeB magnet and exhibits excellent soft magnetic behaviors. The magnetic properties of the injected magnets are compared with the raw metallic glass, solvent-casted resin bonding magnets, and thermal-treated magnets to confirm that the processing temperature of Nylon injection does not affect the magnetism. The injection technology is a practical processing method to be applied on the metallic glass for potential usage.

  1. Evaluation of hot-melt extrusion and injection molding for continuous manufacturing of immediate-release tablets.

    Science.gov (United States)

    Melocchi, Alice; Loreti, Giulia; Del Curto, Maria Dorly; Maroni, Alessandra; Gazzaniga, Andrea; Zema, Lucia

    2015-06-01

    The exploitation of hot-melt extrusion and injection molding for the manufacturing of immediate-release (IR) tablets was preliminarily investigated in view of their special suitability for continuous manufacturing, which represents a current goal of pharmaceutical production because of its possible advantages in terms of improved sustainability. Tablet-forming agents were initially screened based on processability by single-screw extruder and micromolding machine as well as disintegration/dissolution behavior of extruded/molded prototypes. Various polymers, such as low-viscosity hydroxypropylcellulose, polyvinyl alcohol, polyvinyl alcohol-polyethylene glycol graft copolymer, various sodium starch glycolate grades (e.g., Explotab(®) CLV) that could be processed with no need for technological aids, except for a plasticizer, were identified. Furthermore, the feasibility of both extruded and molded IR tablets from low-viscosity hydroxypropylcellulose or Explotab(®) CLV was assessed. Explotab(®) CLV, in particular, showed thermoplastic properties and a very good aptitude as a tablet-forming agent, starting from which disintegrating tablets were successfully obtained by either techniques. Prototypes containing a poorly soluble model drug (furosemide), based on both a simple formulation (Explotab(®) CLV and water/glycerol as plasticizers) and formulations including dissolution/disintegration adjuvants (soluble and effervescent excipients) were shown to fulfill the USP 37 dissolution requirements for furosemide tablets. PMID:25761921

  2. Development of the computer-aided process planning (CAPP system for polymer injection molds manufacturing

    Directory of Open Access Journals (Sweden)

    J. Tepi?

    2011-10-01

    Full Text Available Beginning of production and selling of polymer products largely depends on mold manufacturing. The costs of mold manufacturing have significant share in the final price of a product. The best way to improve and rationalize polymer injection molds production process is by doing mold design automation and manufacturing process planning automation. This paper reviews development of a dedicated process planning system for manufacturing of the mold for injection molding, which integrates computer-aided design (CAD, computer-aided process planning (CAPP and computer-aided manufacturing (CAM technologies.

  3. Injection molded superhydrophobic surfaces based on microlithography and black silicon processing

    DEFF Research Database (Denmark)

    SØgaard, Emil; Andersen, Nis Korsgaard

    2012-01-01

    This work is concerned with the design, development, and testing of nanostructured polymer surfaces with self-cleaning properties that can be manufactured by injection molding. In particular, the superimposed micro- and nanometer length scales of the so-called Lotus effect were investigated in detail with an engineering perspective on choice of materials and manufacturability by injection molding. Microscope slides with superhydrophobic properties were succesfully fabricated. Preliminary results indicate a contact angle increase from 95° for the unstructured polymer to a maximum 150°. The lowest drop roll off angles observed were in the range 1° to 5°.

  4. Temperature Dependence and Magnetic Properties of Injection Molding Tool Materials Used in Induction Heating

    DEFF Research Database (Denmark)

    Guerrier, Patrick; Nielsen, Kaspar Kirstein

    2015-01-01

    To analyze the heating phase of an induction heated injection molding tool precisely, the temperature-dependent magnetic properties, B–H curves, and the hysteresis loss are necessary for the molding tool materials. Hence, injection molding tool steels, core materials among other materials have, in this paper, been characterized for their temperature-dependent magnetic properties. The properties have been measured using a vibrating sample magnetometer, able to reach to 350 °C. The established material database comprises the B–H loops, from which the mean B–H curve, relative permeability versus magnetic flux density, and hysteresis loss versus magnetic flux density have been extracted and are presented.

  5. Injection molded pinched flow fractionation device for enrichment of somatic cells in cow milk

    DEFF Research Database (Denmark)

    Jensen, Marie PØdenphant; Marie, Rodolphe

    2014-01-01

    In this paper the continuous microfluidic separation technique pinched flow fractionation is applied to the enrichment of somatic cells from cow milk. Somatic cells were separated from the smallest fat particles and proteins thus better imaging and analysis of the cells can be achieved. The enrichment was performed using an all-polymer pinched flow fractionation device fabricated by injection molding. The polymer chips were bonded to a 500 lm polymer foil using UV assisted thermal bonding. The quality of the final devices was reproducible and the injection molding process combined with the use of cheap materials ensures the possibility for device mass production

  6. An easy-to-decompose binder for Ti metal injection molding: Preparation and characterization of feedstock

    Science.gov (United States)

    Hayat, Muhammad Dilawer; Wen, Guian; Cao, Peng

    2015-03-01

    Impurity control is crucial to Ti metal powder injection molding (Ti-MIM) since titanium is a universal solvent to interstitial elements such as oxygen, carbon and nitrogen. In this study, a low decomposition temperature binder system was developed; the rheological and solvent debinding assessments of the feedstock formulated from this binder were performed. Solvent mixing was employed to prepare homogeneous feedstocks. Effects of powder shape and solid loading on rheological properties were evaluated. After injection molding, a debinding profile was constructed. The debound parts were then characterized by microstructural observation.

  7. Properties of high density polyethylene – Paulownia wood flour composites via injection molding

    Science.gov (United States)

    Paulownia wood (PW) flour is evaluated as a bio-based fiber reinforcement. Composites of high density polyethylene (HDPE), 25% by weight of PW, and either 0% or 5% by weight of maleated polyethylene (MAPE) were produced by twin screw compounding followed by injection molding. Molded test composite...

  8. Development of Metal Plate with Internal Structure Utilizing the Metal Injection Molding (MIM Process

    Directory of Open Access Journals (Sweden)

    Kwangho Shin

    2013-12-01

    Full Text Available In this study, we focus on making a double-sided metal plate with an internal structure, such as honeycomb. The stainless steel powder was used in the metal injection molding (MIM process. The preliminary studies were carried out for the measurement of the viscosity of the stainless steel feedstock and for the prediction of the filling behavior through Computer Aided Engineering (CAE simulation. PE (high density polyethylene (HDPE and low density polyethylene (LDPE and polypropylene (PP resins were used to make the sacrificed insert with a honeycomb structure using a plastic injection molding process. Additionally, these sacrificed insert parts were inserted in the metal injection mold, and the metal injection molding process was carried out to build a green part with rectangular shape. Subsequently, debinding and sintering processes were adopted to remove the sacrificed polymer insert. The insert had a suitable rigidity that was able to endure the filling pressure. The core shift analysis was conducted to predict the deformation of the insert part. The 17-4PH feedstock with a low melting temperature was applied. The glass transition temperature of the sacrificed polymer insert would be of a high grade, and this insert should be maintained during the MIM process. Through these processes, a square metal plate with a honeycomb structure was made.

  9. THERMAL PROPERTIES OF EXTRUDED-INJECTION MOLDED POLY (LACTIC ACID) AND FIBER BLENDS

    Science.gov (United States)

    In order to determine the degree of compatibility between PLA and different bio-materials (fibers), PLA was blended with sugar beet pulp, apple, cuphea, lasquerella, and milkweed fibers. Fibers were added at 85:15 and 70:30 PLA:Fiber. The composites were dry blended, extruded and injection molded....

  10. Thermal properties of extruded/injection-molded poly(lactic acid) and biobased composites

    Science.gov (United States)

    In order to determine the degree of compatibility between PLA and different biomaterials (fibers), PLA was compounded with sugar beet pulp and apple fibers. Fibers were added at 85:15 and 70:30 PLA:Fiber. The composites were blended by extrusion followed by injection molding. Differential Scannin...

  11. Dimensional Accuracy Optimization of the Micro-plastic Injection Molding Process Using the Taguchi Design Method

    Directory of Open Access Journals (Sweden)

    Chil-Chyuan KUO

    2015-07-01

    Full Text Available Plastic injection molding is an important field in manufacturing industry because there are many plastic products that are produced by injection molding. However, the time and cost required for producing a precision mold are the most troublesome problems that limit the application at the development stage of a new product in precision machinery industry. This study presents an approach of manufacturing a hard mold with microfeatures for micro-plastic injection molding. This study also focuses on Taguchi design method for investigating the effect of injection parameters on the dimensional accuracy of Fresnel lens during plastic injection molding. It was found that the dominant factor affecting the microgroove depth of Fresnel lens is packing pressure. The optimum processing parameters are packing pressure of 80 MPa, melt temperature of 240 °C, mold temperature of 90 °C and injection speed of 50 m/s. The dimensional accuracy of Fresnel lens can be controlled within ±3 ?m using the optimum level of process parameters through the confirmation test. The research results of this study have industrial application values because electro-optical industries are able to significantly reduce a new optical element development cycle time.

  12. LCI Databases Sensitivity Analysis of the Environmental Impact of the Injection Molding Process

    Directory of Open Access Journals (Sweden)

    Ana Elduque

    2015-03-01

    Full Text Available During the last decades, society’s concern for the environment has increased. Specific tools like the Life Cycle Assessment (LCA, and software and databases to apply this method have been developed to calculate the environmental burden of products or processes. Calculating the environmental impact of plastic products is relevant as the global plastics production rose to 288 million tons in 2012. Among the different ways of processing plastics, the injection molding process is one of the most used in the industry worldwide. In this paper, a sensitivity analysis of the environmental impact of the injection molding process has been carried out. In order to perform this study, the EcoInvent database inventory for injection molding, and the data from which this database is created, have been studied. Generally, when an LCA of a product is carried out, databases such as EcoInvent, where materials, processes and transports are characterized providing average values, are used to quantify the environmental impact. This approach can be good enough in some cases but in order to assess a specific production process, like injection molding, a further level of detail is needed. This study shows how the final results of environmental impact differ for injection molding when using the PVC’s, PP’s or PET’s data. This aspect suggests the necessity of studying, in a more precise way, this process, to correctly evaluate its environmental burden. This also allows us to identify priority areas and thereby actions to develop a more sustainable way of manufacturing plastics.

  13. Influence of the polypropylene structure on the replication of nanostructures by injection molding

    Science.gov (United States)

    Vera, Julie; Brulez, Anne-Catherine; Contraires, Elise; Larochette, Mathieu; Valette, Stéphane; Benayoun, Stéphane

    2015-11-01

    In this paper, an experimental study of replication by injection molding of sub-micrometer features is presented. Two polypropylenes with different melt flow rates (MFR) were used throughout this study. The used removable mold insert was textured with a femtosecond laser. Replication of these periodic structures, called ripples, is thus investigated. Despite different MFR, we show that the viscosities of the two polymers at the investigated temperatures and injection shear rates are similar. The reproducibility of the injected molded samples and the texture of the mold were analyzed. We propose a specific methodology to quantify the reproducibility quality replicas. The latter introduces morphological parameters such as anisotropy rate, power density, etc. A difference between the two replicas was noticeable. Based on rheological analysis, the viscosity was ruled out as the origin of this difference. Other properties were identified as the source such as the chain length and the stress relaxation time. Their impact on the replication quality was investigated and found interesting.

  14. A study of magneto-crystalline alignment in sintered barium hexaferrite fabricated by powder injection molding

    Science.gov (United States)

    Zlatkov, B. S.; Nikolic, M. V.; Aleksic, O.; Danninger, H.; Halwax, E.

    2009-02-01

    Barium hexaferrite permanent magnets were produced by powder injection molding. Starting barium hexaferrite powder was prepared from a Fe 2O 3 and BaCO 3 powder mixture by calcination followed by milling. The feedstock for powder injection molding was prepared by mixing barium hexaferrite powder with a low viscosity binder. Magnetic alignment was achieved by applying a high intensity magnetic field to the melted feedstock during the injection process. Green samples (with and without magnetic alignment) were subjected to solvent debinding and subsequent thermal debinding followed by sintering. Sintering conditions were optimized in order to achieve a maximum energy product value. Magneto-crystalline aligning in barium hexaferrite was studied on both green and sintered samples using X-ray diffraction, scanning electron microscope (SEM) and magnetic measurements (hysteresisgraphs). All measurements were made both in a parallel and perpendicular direction to the aligning magnetic field. The obtained results confirmed magneto-crystalline alignment.

  15. Anisotropic injection molding of strontium ferrite powder using a PP/PEG binder system

    Science.gov (United States)

    Lee, S. H.; Jeung, W. Y.

    2001-05-01

    In this study, new binder system for anisotropic injection molding of Sr-ferrite was developed and a process for injection molding of Sr-ferrite was optimized. The developed binder system is composed of 30 vol% PP, 60 vol% PEG-20 000 and 10 vol% PEG-4000. The extraction by water was applied to remove the major binder components PEGs and the minor binder component, PP, was subsequently burned out in air. Behaviors of extraction and thermal debinding with time and debinding atmosphere and variations of the magnetic properties with sintering temperature were studied. The sintered magnets made by PIM process showed residual carbon content of 230 ppm and a maximum energy product of 4.2 MGOe.

  16. Numerical Analysis of Mold Deformation Including Plastic Melt Flow During Injection Molding

    International Nuclear Information System (INIS)

    In the present study, a numerical analysis of an injection molding process was conducted for predicting the mold deformation considering non-Newtonian flow, heat transfer, and structural behavior. The accurate prediction of mold deformation during the filling stage is important to successfully design and manufacture a precision injection mold. While the local mold deformation can be caused by various factors, a pressure induced by the polymer melt is considered to be one of the most significant ones. In this regard, the numerical simulation considering both the melt filling and the mold deformation was carried out. A mold core for a 2D axisymmetric center-gated disk was used for the demonstration of the present study. The flow behavior inside the mold cavity and temperature distribution were analyzed along with the core displacement. Also, a Taguchi method was employed to investigate the influence of the relevant parameters including flow velocity, mold core temperature, and melt temperature

  17. Two component tungsten powder injection molding – An effective mass production process

    International Nuclear Information System (INIS)

    Tungsten and tungsten-alloys are presently considered to be the most promising materials for plasma facing components for future fusion power plants. The Karlsruhe Institute of Technology (KIT) divertor design concept for the future DEMO power plant is based on modular He-cooled finger units and the development of suitable mass production methods for such parts was needed. A time and cost effective near-net-shape forming process with the advantage of shape complexity, material utilization and high final density is Powder Injection Molding (PIM). This process allows also the joining of two different materials e.g. tungsten with a doped tungsten alloy, without brazing. The complete technological process of 2-Component powder injection molding for tungsten materials and its application on producing real DEMO divertor parts, characterization results of the finished parts e.g. microstructure, hardness, density and joining zone quality are discussed in this contribution

  18. Numerical Analysis of Mold Deformation Including Plastic Melt Flow During Injection Molding

    Energy Technology Data Exchange (ETDEWEB)

    Jung, Joon Tae; Lee, Bong-Kee [Chonnam National University, Gwangju (Korea, Republic of)

    2014-07-15

    In the present study, a numerical analysis of an injection molding process was conducted for predicting the mold deformation considering non-Newtonian flow, heat transfer, and structural behavior. The accurate prediction of mold deformation during the filling stage is important to successfully design and manufacture a precision injection mold. While the local mold deformation can be caused by various factors, a pressure induced by the polymer melt is considered to be one of the most significant ones. In this regard, the numerical simulation considering both the melt filling and the mold deformation was carried out. A mold core for a 2D axisymmetric center-gated disk was used for the demonstration of the present study. The flow behavior inside the mold cavity and temperature distribution were analyzed along with the core displacement. Also, a Taguchi method was employed to investigate the influence of the relevant parameters including flow velocity, mold core temperature, and melt temperature.

  19. Injection molding of ultra-fine Si3N4 powder for gas-pressure sintering

    Science.gov (United States)

    Yang, Xian-feng; Yang, Jiang-hong; Xu, Xie-wen; Liu, Qi-cheng; Xie, Zhi-peng; Liu, Wei

    2015-06-01

    The ceramic injection molding technique was used in the gas-pressure sintering of ultra-fine Si3N4 powder. The feedstock's flowability, debinding rate, defect evolution, and microstructural evolution during production were explored. The results show that the solid volume loading of less than 50vol% and the surfactant mass fraction of 6wt% result in a perfect flowability of feedstock; this feedstock is suitable for injection molding. When the debinding time is 8 h at 40°C, approximately 50% of the wax can be solvent debinded. Defects detected during the preparation are traced to improper injection parameters, mold design, debinding parameters, residual stress, or inhomogeneous composition distribution in the green body. The bulk density, Vickers hardness, and fracture toughness of the gas-pressure-sintered Si3N4 ceramic reach 3.2 g/cm3, 16.5 GPa, and 7.2 MPa·m1/2, respectively.

  20. Orientation of Carbon Fibers in Copper matrix Produced by Powder Injection Molding

    Directory of Open Access Journals (Sweden)

    Irfan Shirazi M.

    2014-07-01

    Full Text Available Fiber orientation is a big challenge in short fiber reinforced composites. Powder injection molding (PIM process has some intrinsic fiber alignment associated with it. During PIM process fibers in skin region of moldings are aligned as these regions experience higher shear flow caused by the mold walls. Fibers in the core region remain randomly aligned as these regions are far from mold walls and experience lesser shear flow. In this study short carbon fiber (CF reinforced copper matrix composite was developed by PIM process. Two copper composite feedstock formulations were prepared having 5 vol% and 10 vol% CFs and a wax based binder system. Fiber orientation was controlled during injection molding by using a modified mold that has a diverging sprue. The sprue creates converging flow when feedstock enters into the mold cavity. Fiber orientation was analysed after molding using FESEM. The orientation of fibers can be controlled by controlling flow of feedstock into the mold.

  1. Numerical modeling of magnetic induction and heating in injection molding tools

    DEFF Research Database (Denmark)

    Guerrier, Patrick; Hattel, Jesper Henri

    2013-01-01

    Injection molding of parts with special requirements or features such as micro- or nanostructures on the surface, a good surface finish, or long and thin features results in the need of a specialized technique to ensure proper filling and acceptable cycle time. The aim of this study is to increase the temperatures as close as possible to the cavity surface, by means of an integrated induction heating system in the injection molding tool, to improve the fluidity of the polymer melt hereby ensuring that the polymer melt will continue to flow until the mold cavity is completely filled. The presented work uses numerical modeling of the induction heating in the mold to investigate how the temperature in the mold will be distributed and how it is affected by different material properties.

  2. Two component tungsten powder injection molding – An effective mass production process

    Energy Technology Data Exchange (ETDEWEB)

    Antusch, Steffen, E-mail: steffen.antusch@kit.edu; Commin, Lorelei; Mueller, Marcus; Piotter, Volker; Weingaertner, Tobias

    2014-04-01

    Tungsten and tungsten-alloys are presently considered to be the most promising materials for plasma facing components for future fusion power plants. The Karlsruhe Institute of Technology (KIT) divertor design concept for the future DEMO power plant is based on modular He-cooled finger units and the development of suitable mass production methods for such parts was needed. A time and cost effective near-net-shape forming process with the advantage of shape complexity, material utilization and high final density is Powder Injection Molding (PIM). This process allows also the joining of two different materials e.g. tungsten with a doped tungsten alloy, without brazing. The complete technological process of 2-Component powder injection molding for tungsten materials and its application on producing real DEMO divertor parts, characterization results of the finished parts e.g. microstructure, hardness, density and joining zone quality are discussed in this contribution.

  3. Investigation of process parameters for an Injection molding component for warpage and Shrinkage

    Directory of Open Access Journals (Sweden)

    Mohammad Aashiq M1 , Arun A.P1 ,Parthiban M

    2013-04-01

    Full Text Available The purpose of the research is to explore the influence of different mold temperatures on the warpage & shrinkage of the injection molded component’s. The simulation software MOLDEX 3D was used for this study, the simulations were done by varying different mold temperatures and their corresponding warpage & shrinkage were collected. It was found that the different mold wall temperature causes the asymmetrical polymer flow in the cross-section due to which the asymmetrical structure in the parts cross-section occurs and this was observed using the flow analysis software. So it is required to assurehomogeneous mold wall temperature across the entire cavityduring the production of injection molded parts. This researchfinally concludes that warpage and shrinkage decreases for increased values of mold temperature

  4. A Simulation Study of Conformal Cooling Channels in Plastic Injection Molding

    Directory of Open Access Journals (Sweden)

    Omar A. Mohamed, S.H. Masood, Abul Saifullah

    2013-09-01

    Full Text Available In injection molding process, the cooling channel performance is one of the most crucial factors because it has significant effect on both production rate and the quality of the plastic part. In order to reduce the cycle time, and control the uniform distribution of temperature, it is necessary to create conformal cooling channels, which conform to the shape of the mold cavity and core. This paper presents a simulation study of different types of cooling channels in an injection molded plastic part and compares the performance in terms of time to ejection temperature, shrinkage, temperature profile, and part warpage to determine which configuration is more appropriate to provide uniform cooling with minimum cycle time. Autodesk Moldflow Insight (AMI simulation software is used to examine the results of the cooling channels performance.

  5. Development of Metal Plate with Internal Structure Utilizing the Metal Injection Molding (MIM) Process

    OpenAIRE

    Kwangho Shin; Youngmoo Heo; Hyungpil Park; Sungho Chang; Byungohk Rhee

    2013-01-01

    In this study, we focus on making a double-sided metal plate with an internal structure, such as honeycomb. The stainless steel powder was used in the metal injection molding (MIM) process. The preliminary studies were carried out for the measurement of the viscosity of the stainless steel feedstock and for the prediction of the filling behavior through Computer Aided Engineering (CAE) simulation. PE (high density polyethylene (HDPE) and low density polyethylene (LDPE)) and polypropylene (PP)...

  6. High quality ion channels recordings on an injection molded polymer chip

    DEFF Research Database (Denmark)

    Tanzi, Simone

    2013-01-01

    In this thesis we demonstrate high quality recordings of the ion channel activity across the cell membrane in a biological cell by employing the so called patch clamping technique on an injection molded polymer microfluidic device. Such recordings are traditionally made using glass micropipettes, or in recent years using consumable microfluidic chips of high costs. The patch clamping method is widely used both in fundamental studies of electrophysiology of living cells and tissue and in drug dis...

  7. Correlation between Rheotens measurements and reinforcement of polymer nanocomposites in the injection molding compounder

    Science.gov (United States)

    Battisti, Markus G.; Friesenbichler, Walter; Duretek, Ivica; Guttmann, Peter

    2015-04-01

    The evaluation of the effectiveness of reinforcement of polymers and polymer nanocomposites(PNCs), in particular the improvement of Young's modulus, is made by performing standardized tensile tests. Structural and morphological characterizations typically are investigated using expensive techniques like transmission electron microscopy (TEM), X- ray scattering and sometimes also rheological analyses (rotational rheometry). The objective of this study is to generate faster and economically advantageous data to verify the quality of the produced PNC-compound in an on-line measurement system. Subsequently injection molded parts are processed by using the Injection Molding Compounder (PNC-IMC) “by only one plasticizing process”. In comparison to the conventional compounding process, where the compound has to be pelletized and fed into the injection molding machine for the second plasticizing process, injection molding compounding combines these two processing steps. This paper shows first results and problems with the implementation of the Rheotens equipment into the concept of the IMC. Different processing techniques and various processing conditions were compared and the occurring effects were detected both with tensile testing and extensional melt rheology. Both, the increase of the Young's modulus by using layered silicates as nanofillersis compared to the virgin polypropylene and the correlation of the level of melt strength with Rheotens measurements is shown. These results give a good overview on both the possibilities and the limitations of the material pre-tests by the use of extensional rheology in the concept of the IMC for producing PNCs. Further studies to enable a fast and efficient way of estimating the level of reinforcement in PNCs by means of Rheotens measurements will be carried out towards industrial usability. Furthermore the verification of exfoliation and intercalation of the layered silicates in the polymer matrix using small angle X- ray scattering is planned.

  8. Injection molding of nanopatterned surfaces in the sub-micrometer range with induction heating aid

    DEFF Research Database (Denmark)

    Menotti, Stefano; Hansen, Hans Nørgaard; Bissacco, Giuliano; Calaon, Matteo; Tang, Peter Torben; Ravn, Christian

    2014-01-01

    Replication of sub-micrometer structures by injection molding leads to special requirements for the mold in order to ensure proper replica and acceptable cycle time. This paper investigates the applicability of induction heating embedded into the mold for the improvement of nanopattern replication. A tool insert having a surface containing functional geometries in the sub-micrometer range was produced using aluminum anodization and nickel electroplating. In order to provide elevated mold tempera...

  9. All polymer, injection molded nanoslits, fabricated through two-level UV-LIGA processes

    DEFF Research Database (Denmark)

    Østergaard, Peter Friis; Matteucci, Marco; Marie, Rodolphe; Kristensen, Anders; Taboryski, Rafael J.

    2012-01-01

    Micro- and nanofluidic systems fabricated in silicon and glass substrates are expensive and have long production cycles. To minimize the time used by researchers to fabricate their systems, rather than using them, medium to high volume throughput of specific chips, containing fluidic channels in the micro- and nanoregime is required. To obtain this, injection molding is included in the research process for making several chips (100-1000) with the same layout. The time it takes for the individual...

  10. Experimental Study of Fiber Length and Orientation in Injection Molded Natural Fiber/Starch Acetate Composites

    DEFF Research Database (Denmark)

    Peltola, Heidi; Madsen, Bo; Joffe, Roberts; Nättinen, Kalle

    2011-01-01

    Composite compounds based on triethyl citrate plasticized starch acetate and hemp and flax fibers were prepared by melt processing. Plasticizer contents from 20 to 35 wt% and fiber contents of 10 and 40 wt% were used. The compounded composites were injection molded to tensile test specimens. The effect of processing, melt viscosity and fiber type on the fiber length was investigated. The lengths of fully processed fibers were determined by dissolving the matrix and measuring the length of the re...

  11. Experimental validation of viscous and viscoelastic simulations of micro injection molding process

    DEFF Research Database (Denmark)

    Gava, Alberto; Tosello, Guido; Lucchetta, Giovanni; Hansen, Hans Nørgaard; Schoth, Andreas

    2009-01-01

    The effects of two different rheological models used in the simulation of the micro injection molding (µIM) process are investigated. The Cross-WLF viscous model and the Giesekus viscoelastic model are selected and their performance evaluated using 3D models implemented on two different commercially available software packages. Simulation results are then compared with the experimental µIM process. Validation parameters for the comparison are the flow front position during filling of the micro c...

  12. Micro Injection Molding of Thin Walled Geometries with Induction Heating System

    DEFF Research Database (Denmark)

    Menotti, Stefano; Hansen, Hans Nørgaard; Bissacco, Giuliano; Grev, Nathaniel Ryan; Tang, Peter Torben

    2014-01-01

    To eliminate defects and improve the quality of molded parts, increasing the mold temperature is one of the applicable solutions. A high mold temperature can increase the path flow of the polymer inside the cavity allowing reduction of the number of injection points, reduction of part thickness and moulding of smaller and more complex geometries. The last two aspects are very important in micro injection molding. In this paper a new embedded induction heating system is proposed and validated. An...

  13. Forehead Augmentation with a Methyl Methacrylate Onlay Implant Using an Injection-Molding Technique

    OpenAIRE

    Dong Kwon Park; Ingook Song; Jin Hyo Lee; Young June You

    2013-01-01

    Background The forehead, which occupies about one third of the face, is one of the majordeterminants of a feminine or masculine look. Various methods have been used for the augmentationof the forehead using autologous fat grafts or alloplastic materials. Methylmethacrylate(MMA) is the most appropriate material for augmentation of the forehead, and we have usedan injection-molding technique with MMA to achieve satisfactory results.Methods Under local anesthesia with intravenous (IV) sedation, ...

  14. EFFECTS OF INJECTION TEMPERATURE ON MECHANICAL PROPERTIES OF BAGASSE/POLYPROPYLENE INJECTION MOLDING COMPOSITES

    OpenAIRE

    Shinichi Shibata; Rahman M. Bozlur; Isao Fukumoto; Yasuyuki Kanda

    2010-01-01

    Effects of injection temperature on thermal degradation and porosity of the bagasse/polypropylene injection molding composites were studied. Above 185 ºC, incomplete filling occurred. The incomplete filling increased with increase of injection temperature. It was found that the gas generated by thermal degradation of bagasse fibers was so accumulated in the injection cylinder that the injected composites ended up with incomplete filling. A modified injection method with the venting of gas inc...

  15. Injection molded chips with integrated conducting polymer electrodes for electroporation of cells

    DEFF Research Database (Denmark)

    Andresen, Kristian; Hansen, Morten; Matschuk, Maria; Jepsen, Søren Terpager; Sørensen, Henrik Schiøtt; Utko, Pawel; Selmeczi, Dávid; Hansen, Thomas Steen; Larsen, Niels Bent; Rozlosnik, Noemi; Taboryski, Rafael Jozef

    2010-01-01

    We present the design-concept for an all polymer injection molded single use microfluidic device. The fabricated devices comprise integrated conducting polymer electrodes and Luer fitting ports to allow for liquid and electrical access. A case study of low voltage electroporation of biological cells in suspension is presented. The working principle of the electroporation device is based on a focusing of the electric field by means of a constriction in the flow channel for the cells. We demonstra...

  16. Gate design in injection molding of microfluidic components using process simulations

    DEFF Research Database (Denmark)

    Marhöfer, David Maximilian; Tosello, Guido; Islam, Aminul; Hansen, Hans Nørgaard

    2015-01-01

    Process simulations are an effective design and optimization tool in conventional as well as micro injection molding (?IM). They can be applied to optimize and assist the design of the micro part, the mold, the micro cavity and the ?IM process. Available simulation software is however developed for macroscopic plastic parts. By using the correct implementation and careful modelling though, it can also be applied to micro parts. In the present work, process simulations were applied to a microflui...

  17. A Simulation Study of Conformal Cooling Channels in Plastic Injection Molding

    OpenAIRE

    Omar A. Mohamed, S.H. Masood, Abul Saifullah

    2013-01-01

    In injection molding process, the cooling channel performance is one of the most crucial factors because it has significant effect on both production rate and the quality of the plastic part. In order to reduce the cycle time, and control the uniform distribution of temperature, it is necessary to create conformal cooling channels, which conform to the shape of the mold cavity and core. This paper presents a simulation study of different types of cooling channe...

  18. The effect of mold surface topography on plastic parat in-process shrinkage in injection molding

    DEFF Research Database (Denmark)

    Arlø, Uffe Rolf; Hansen, Hans Nørgaard; Kjær, Erik Michael

    2003-01-01

    An experimental study of the effect of mold surface roughness on in-process in-flow linear part shrinkage in injection molding has been carried out. The investigation is based on an experimental two-cavity tool, where the cavities have different surface topographies, but are otherwise identical. The study has been carried out for typical commercial polystyrene and polypropylene grades. The relationship between mold surface topography and linear shrinkage has been investigated with an experimenta...

  19. Micromechanical Properties of Injection-Molded Starch–Wood Particle Composites

    OpenAIRE

    Ueberschaer, A.; Cagiao, M.E.; Bayer, R. K.; Henning, S; Baltá Calleja, F. J.

    2006-01-01

    The micromechanical properties of injection molded starch–wood particle composites were investigated as a function of particle content and humidity conditions. The composite materials were characterized by scanning electron microscopy and X-ray diffraction methods. The microhardness of the composites was shown to increase notably with the concentration of the wood particles. In addition,creep behavior under the indenter and temperature dependence were evaluated in terms of the indepe...

  20. Dimensional changes of acrylic resin denture bases: conventional versus injection-molding technique.

    Directory of Open Access Journals (Sweden)

    Jafar Gharechahi

    2014-08-01

    Full Text Available Acrylic resin denture bases undergo dimensional changes during polymerization. Injection molding techniques are reported to reduce these changes and thereby improve physical properties of denture bases. The aim of this study was to compare dimensional changes of specimens processed by conventional and injection-molding techniques.SR-Ivocap Triplex Hot resin was used for conventional pressure-packed and SR-Ivocap High Impact was used for injection-molding techniques. After processing, all the specimens were stored in distilled water at room temperature until measured. For dimensional accuracy evaluation, measurements were recorded at 24-hour, 48-hour and 12-day intervals using a digital caliper with an accuracy of 0.01 mm. Statistical analysis was carried out by SPSS (SPSS Inc., Chicago, IL, USA using t-test and repeated-measures ANOVA. Statistical significance was defined at P<0.05.After each water storage period, the acrylic specimens produced by injection exhibited less dimensional changes compared to those produced by the conventional technique. Curing shrinkage was compensated by water sorption with an increase in water storage time decreasing dimensional changes.Within the limitations of this study, dimensional changes of acrylic resin specimens were influenced by the molding technique used and SR-Ivocap injection procedure exhibited higher dimensional accuracy compared to conventional molding.

  1. The use of stereolithography rapid tools in the manufacturing of metal powder injection molding parts

    Scientific Electronic Library Online (English)

    V. E., Beal; C. H., Ahrens; P. A., Wendhausen.

    2004-03-01

    Full Text Available The utilization of stereolithography molds in the manufacture pre-series for injection molded plastic parts aims to reduce costs throughout the product life-time, but mainly during design and manufacturing phases. The use of this Rapid Tooling technique in powder metal injection molding is evaluated [...] in this work. One of the greatest differences between traditional and stereolithography tools is related to the heat conductivity of the materials employed. For example, steel molds have a heat conductivity coefficient 300 times higher than molds made with the photosensitive resin used in the stereolithography process. The discrepancy regarding the cooling rate of the molded parts during the injection cycle must be compensated with adjustments in the injection molding parameters, such as temperature, pressure and speed. The optimization of these parameters made it possible to eject green parts from the mold without causing defects which would become evident in debinding and sintering stages. The dimensional analysis performed at the end of each case study showed that the shrinking factor of the component after the sintering had the same value obtained for components using traditional metallic molds. Moreover, the dimensional error remains under 2% which can be considered low for a pre-series of components (or prototype series).

  2. Dimensional Changes of Acrylic Resin Denture Bases: Conventional Versus Injection-Molding Technique

    Science.gov (United States)

    Gharechahi, Jafar; Asadzadeh, Nafiseh; Shahabian, Foad; Gharechahi, Maryam

    2014-01-01

    Objective: Acrylic resin denture bases undergo dimensional changes during polymerization. Injection molding techniques are reported to reduce these changes and thereby improve physical properties of denture bases. The aim of this study was to compare dimensional changes of specimens processed by conventional and injection-molding techniques. Materials and Methods: SR-Ivocap Triplex Hot resin was used for conventional pressure-packed and SR-Ivocap High Impact was used for injection-molding techniques. After processing, all the specimens were stored in distilled water at room temperature until measured. For dimensional accuracy evaluation, measurements were recorded at 24-hour, 48-hour and 12-day intervals using a digital caliper with an accuracy of 0.01 mm. Statistical analysis was carried out by SPSS (SPSS Inc., Chicago, IL, USA) using t-test and repeated-measures ANOVA. Statistical significance was defined at Presin specimens were influenced by the molding technique used and SR-Ivocap injection procedure exhibited higher dimensional accuracy compared to conventional molding. PMID:25584050

  3. Characterization Of Metal Injection Molding (MIM Feedstock Based On Water Soluble Binder System

    Directory of Open Access Journals (Sweden)

    Norhamidi Muhamad

    2008-08-01

    Full Text Available Metal Injection Molding (MIM is a new manufacturing technique especially to produce small and complex precision parts. Characterization of feedstock is one of the important tasks in order to evaluate the homogeneity level of the feedstock prepared and to control the quality of the parts during injection molding process. This paper attempts to investigate the characteristics of the MIM feedstock by performing rheological test using the feedstock consisted of 316L stainless steel powder with a mean particle size of 12 micrometer and a major fraction of water soluble binder system known as polyethylene glycol (PEG. Three different weight percentage of PEG at 65, 75, and 85 respectively were used during the investigation. The viscosity of MIM feedstock at different temperatures and shear rates were measured and evaluated. Results show that increasing the PEG content would decrease the viscosity of the feedstock. The rheological properties of the feedstock showed that the proposed method of mixing is adequate to produce a homogeneous feedstock that is favorable for injection molding process.

  4. Measurement of solidification and melting behavior of resin in injection molding and detection of flaws molded parts by using ultrasonic waves

    International Nuclear Information System (INIS)

    Injection molding of thermoplastics is widely used in many industries. However, it is not so easy to design the mold and to determine the optimal injection conditions. Therefore, a number of CAR mold design software packages for simulating the injection molding process have been developed. In order to confirm the results obtained from CAE, it is necessary to compare the numerical results with the experimental ones. In practice, the filling behavior has been observed with an optical visualization technique, but the solidification behavior of melted resin filled into the cavity has not yet been observed. It has been indirectly detected by measuring the pressure in the mold cavity. On the other hand, the melting behavior of solid resin in the barrel of an infection molding machine has influence on the quality of a molded part. Therefore, it is important to observe the melting behavior of solid resin in the barrel. In this study a method for measuring the solidification behavior in the cavity and the melting behavior in the barrel have been developed by using ultrasonic waves. Moreover, a method of detecting a flaw or a different material included in the molded part has been developed by using ultrasonic waves. Especially, a flaw close to the surface of the molded part can be detected by separating the flaw echo from the surface echo of the molded part. It was determined that the thickness of the solid layer of the melted resin filled into the cavity can be measured by using ultrasonic waves. The melting behavior of the resin on the barrel surface can be observed by measuring the amplitude of the reflected echo on the interface between the barrel and resin. Moreover, the flaw close to the surface of the molded part can be detected by using the ultrasonic waves.

  5. Wall-slip of highly filled powder injection molding compounds: Effect of flow channel geometry and roughness

    Energy Technology Data Exchange (ETDEWEB)

    Hausnerova, Berenika; Sanetrnik, Daniel [Dept. of Production Engineering, Faculty of Technology, Tomas Bata University in Zlin, nám. T.G. Masaryka 5555, 760 01 Zlín, Czech Republic and Centre of Polymer Systems, University Institute, Tomas Bata University in Zlin, Nad Ovc (Czech Republic); Paravanova, Gordana [Centre of Polymer Systems, University Institute, Tomas Bata University in Zlin, Nad Ovcírnou 3685, 760 01 Zlín (Czech Republic)

    2014-05-15

    The paper deals with the rheological behavior of highly filled compounds proceeded via powder injection molding (PIM) and applied in many sectors of industry (automotive, medicine, electronic or military). Online rheometer equipped with slit dies varying in surface roughness and dimensions was applied to investigate the wall-slip as a rheological phenomenon, which can be considered as a parameter indicating the separation of compound components (polymer binder and metallic powder) during high shear rates when injection molded.

  6. Optimizing Injection Molding Processing Parameters for Enhanced Mechanical Performance of Oil Palm Empty Fruit Bunch High Density Polyethylene Composites

    OpenAIRE

    M. S. Ramli; M.R. Abdul Latif; P.S.M. Megat-Yusoff

    2011-01-01

    This study reports on the influence of injection molding processing parameters on mechanical properties of oil palm Empty Fruit Bunch (EFB) filled High Density Poly Ethylene (HDPE). The biocomposite pellets were first prepared using an extruder with 20 wt% EFB content before being processed in an injection-molding machine for specimen fabrication. Two processing parameters were varied systematically and independently during the composite sample fabrication. The holding pressure was increased ...

  7. A Novel Injection-Molded Capsular Device for Oral Pulsatile Delivery Based on Swellable/Erodible Polymers

    OpenAIRE

    Gazzaniga, Andrea; Cerea, Matteo; COZZI, ALBERTO; Foppoli, Anastasia; Maroni, Alessandra; Zema, Lucia

    2011-01-01

    The feasibility of injection molding was explored in the preparation of a novel capsular device for oral pulsatile/delayed delivery based on swellable/erodible polymers. For this purpose, a mold intended to be coupled with a bench-top injection-molding press was designed. This was expected to enable the preparation of matching capsule cap and body items within a single manufacturing cycle and the selection of differing shell thicknesses (300, 600, and 900 ?m). Hydroxypropylcellulose (Klucel® ...

  8. Forehead Augmentation with a Methyl Methacrylate Onlay Implant Using an Injection-Molding Technique

    Directory of Open Access Journals (Sweden)

    Dong Kwon Park

    2013-09-01

    Full Text Available Background The forehead, which occupies about one third of the face, is one of the majordeterminants of a feminine or masculine look. Various methods have been used for the augmentationof the forehead using autologous fat grafts or alloplastic materials. Methylmethacrylate(MMA is the most appropriate material for augmentation of the forehead, and we have usedan injection-molding technique with MMA to achieve satisfactory results.Methods Under local anesthesia with intravenous (IV sedation, an incision was made onthe scalp and a meticulous and delicate subperiosteal dissection was then performed. MMAmonomers and polymers were mixed, the dough was injected into the space created, andmanual molding was performed along with direct inspection. This surgery was indicated forpatients who wanted to correct an unattractive appearance by forehead augmentation. Everypatient in this study visited our clinics 3 months after surgery to evaluate the results. Wejudged the postoperative results in terms of re-operation rates caused by the dissatisfactionof the patients and complications.Results During a 13-year period, 516 patients underwent forehead augmentation with MMA.With the injection-molding technique, the inner surface of the MMA implant is positionedclose to the underlying frontal bone, which minimizes the gap between the implant and bone.The borders of the implant should be tapered sufficiently until no longer palpable or visible.Only 28 patients (5.4% underwent a re-operation due to an undesirable postoperative appearance.Conclusions The injection-molding technique using MMA is a simple, safe, and ideal methodfor the augmentation of the forehead.

  9. Cytocompatibility of titanium metal injection molding with various anodic oxidation post-treatments

    International Nuclear Information System (INIS)

    Metal injection molding (MIM) is a near net shape manufacturing method that allows for the production of components of small to moderate size and complex shape. MIM is a cost-effective and flexible manufacturing technique that provides a large innovative potential over existing methods for the industry of implantable devices. Commercially pure titanium (CP-Ti) samples were machined to the same shape as a composite feedstock with titanium and polyoxymethylene, and these metals were injected, debinded and sintered to assess comparative biological properties. Moreover, we treated MIM-Ti parts with BIOCOAT®, BIODIZE® and BIOCER®, three different anodic oxidation techniques that treat titanium using acid, alkaline and anion enriched electrolytes, respectively. Cytocompatibility as well as morphological and chemical features of surfaces was comparatively assessed on each sample, and the results revealed that MIM-Ti compared to CP-Ti demonstrated a specific surface topography with a higher roughness. MIM-Ti and BIOCER® samples significantly enhanced cell proliferation, cell adhesion and cell differentiation compared to CP-Ti. Interestingly, in the anodization post-treatment established in this study, we demonstrated the ability to improve osseointegration through anionic modification treatment. The excellent biological response we observed with MIM parts using the injection molding process represents a promising manufacturing method for the future implantable devices in direct contact with bones. - Highlights: ? Metal injection molding technique gives titanium a specific surface roughness. It enhances the biological response. ? Anodic oxidation method adds Ca, P, and Mg ions on the surface, promoting the cell adhesion. ? Cytocompatibility analyses show an increased cell adhesion and proliferation on MIM-Ti compared to pure titanium.

  10. Structural and magnetic properties of sintered Sr-ferrites fabricated by powder injection molding

    Science.gov (United States)

    Murillo, N.; González, J.; Guraya, C.; Gutiérrez, M.; Seco, F. J.

    1999-08-01

    Studies of microstructure (SEM and metalographic micrographs) and magnetic properties (remanent magnetisation and coercive field) have been performed on bipolar sintered Sr-ferrite permanent magnets obtained by powder injection molding (PIM) method under applied magnetic field in order to align the magnetic particles during the PIM process. Magnetic measurements on the samples were made in the parallel and perpendicular direction of the aligning magnetic field. The remanence in the direction of alignment increased sharply with the alignment field to a maximum value of 3840 Gs while the coercivity decreases to a minimum value of 3220 Oe.

  11. Electroforming of Tool Inserts for Injection Molding of Optical or Microfluidic Components

    DEFF Research Database (Denmark)

    Tang, Peter Torben; Christensen, Thomas R.

    2004-01-01

    With a rapidly increasing international interest in “Lab-on-a-chip”-systems as well as affordable polymer optics, the combination of electroforming and injection molding offers an attractive fabrication solution. Miniaturized analysis systems can be used for medical, security (anti terror monitoring) and environmental (waste water monitoring) applications. Optical components in polymer materials can be used for consumer electronics and for sensor systems. The presentation will include the complete fabrication scheme for tool inserts based on machining and electroforming. Electroforming processes for nickel and copper will be disclosed. Processing parameters for the different types of tools as well as quality control measures will be presented.

  12. Effect of rheological parameters on curing rate during NBR injection molding

    Science.gov (United States)

    Kyas, Kamil; Stanek, Michal; Manas, David; Skrobak, Adam

    2013-04-01

    In this work, non-isothermal injection molding process for NBR rubber mixture considering Isayev-Deng curing kinetic model, generalized Newtonian model with Carreau-WLF viscosity was modeled by using finite element method in order to understand the effect of volume flow rate, index of non-Newtonian behavior and relaxation time on the temperature profile and curing rate. It was found that for specific geometry and processing conditions, increase in relaxation time or in the index of non-Newtonian behavior increases the curing rate due to viscous dissipation taking place at the flow domain walls.

  13. Mechanical Properties of Injection Molded B 4C-C Ceramics

    Science.gov (United States)

    Schwetz, Karl A.; Sigl, Lorenz S.; Pfau, Lothar

    1997-10-01

    Various mechanical properties of carbon-doped boron carbide ceramics, prepared by the fabrication route, injection molding/pressureless sintering/post-hot isostatic pressing (HIP) were investigated as a function of the sintering temperature and the carbon additive level used. An optimum combination of mechanical properties (flexural stregth, fracture toughness, Young's modulus, Knoop's hardness) is thus obtained with 100% dense and very fine grained materials (mean grain size 1-4 ?m) which were sintered at temperatures from 2150 to 2175°C and post-HIPed at 2050°/200 MPa Ar, having an approximate final composition of 96 B4C-4C (wt%).

  14. Influência do desempenho térmico de moldes fabricados com compósito epóxi/alumínio nas propriedades de pp moldado por injeção / Thermal behavior of epoxy/aluminum rapid tooling composite during injection molding of polypropylene

    Scientific Electronic Library Online (English)

    Gean V., Salmoria; Carlos H., Ahrens; Felix A. Y., Villamizar; Aurélio da C., Sabino Netto.

    2008-09-01

    Full Text Available O surgimento das tecnologias de prototipagem rápida (RP) e de ferramental rápido (RT) tem despertado interesse da indústria de moldes de injeção. O vazamento de termofixos com cargas metálicas possibilita a construção de moldes usando materiais compósitos, os quais apresentam maior resistência que o [...] s utilizados por outras técnicas RT. Neste trabalho foi estudado o comportamento térmico de moldes fabricados em epóxi/alumínio durante a injeção de polipropileno através de avaliações da estrutura e de propriedades mecânicas utilizando difração de raio X e ensaios de dureza e de tração. Os corpos-de-prova injetados no molde em compósito epóxi/alumínio apresentaram pequenas diferenças no grau de cristalinidade das superfícies analisadas e propriedades mecânicas semelhantes aos corpos-de-prova injetados em molde de aço. O estudo mostrou um razoável desempenho térmico do molde compósito durante a injeção de polipropileno evidenciando a viabilidade de utilização destes moldes na produção de pequenas séries de protótipos e de produtos neste termoplástico. Abstract in english rapid prototyping (RP) and rapid tooling (RT) technologies are gaining increasing importance in the injection molding industry. Casting of resin/metal composites allows the construction of molds with greater resistance than those manufactured by other RT techniques such as Stereolithography. In this [...] work, the thermal behavior of molds manufactured in epoxy/aluminum during the injection molding of polypropylene specimens was investigated. Structural and mechanical characterization of the molded specimens included X ray analysis, hardness and tensile testing. The samples presented small differences in the degree of crystallinity and similar mechanical properties in comparison with samples injected into steel molds. This study showed a reasonable thermal performance of the epoxy/aluminum mold during the injection molding of polypropylene, thus demonstrating the viability of using these molds to produce a few number of prototypes or products with this thermoplastic.

  15. Rapid and low-cost prototyping of medical devices using 3D printed molds for liquid injection molding.

    Science.gov (United States)

    Chung, Philip; Heller, J Alex; Etemadi, Mozziyar; Ottoson, Paige E; Liu, Jonathan A; Rand, Larry; Roy, Shuvo

    2014-01-01

    Biologically inert elastomers such as silicone are favorable materials for medical device fabrication, but forming and curing these elastomers using traditional liquid injection molding processes can be an expensive process due to tooling and equipment costs. As a result, it has traditionally been impractical to use liquid injection molding for low-cost, rapid prototyping applications. We have devised a method for rapid and low-cost production of liquid elastomer injection molded devices that utilizes fused deposition modeling 3D printers for mold design and a modified desiccator as an injection system. Low costs and rapid turnaround time in this technique lower the barrier to iteratively designing and prototyping complex elastomer devices. Furthermore, CAD models developed in this process can be later adapted for metal mold tooling design, enabling an easy transition to a traditional injection molding process. We have used this technique to manufacture intravaginal probes involving complex geometries, as well as overmolding over metal parts, using tools commonly available within an academic research laboratory. However, this technique can be easily adapted to create liquid injection molded devices for many other applications. PMID:24998993

  16. Optimization of injection molding process for car fender in consideration of energy efficiency and product quality

    Directory of Open Access Journals (Sweden)

    Hong Seok Park

    2014-10-01

    Full Text Available Energy efficiency is an essential consideration in sustainable manufacturing. This study presents the car fender-based injection molding process optimization that aims to resolve the trade-off between energy consumption and product quality at the same time in which process parameters are optimized variables. The process is specially optimized by applying response surface methodology and using nondominated sorting genetic algorithm II (NSGA II in order to resolve multi-object optimization problems. To reduce computational cost and time in the problem-solving procedure, the combination of CAE-integration tools is employed. Based on the Pareto diagram, an appropriate solution is derived out to obtain optimal parameters. The optimization results show that the proposed approach can help effectively engineers in identifying optimal process parameters and achieving competitive advantages of energy consumption and product quality. In addition, the engineering analysis that can be employed to conduct holistic optimization of the injection molding process in order to increase energy efficiency and product quality was also mentioned in this paper.

  17. Initial verification of an induction heating set-up for injection molding

    DEFF Research Database (Denmark)

    Menotti, Stefano; Hansen, Hans NØrgaard

    2013-01-01

    Molding of thin and long parts by injection molding leads to special requirements for the mold in order to ensure proper filling and acceptable cycle time. This paper investigates the applicability of embedded induction heating for the improvement of the filling of thin long parts. The object selected for the investigation is a thin spiral. For the complete molding of the component, elevated mold temperatures are required. For this propose a new injection molding set-up was developed, which allows rapid heating of the cavity wall by an induction heating system. The temperature was measured by two thermocouples placed in the die insert. The system was used to heat up the cavity wall with heating rates of up to 10 °C/s. Experiments were carried out with ABS material. The lengths of the object were measured by a suitable measurement set up. The experimental result show that the use of the induction heating system process is an efficient way for improving the filling of the cavity.

  18. Optimization of injection molded parts by using ANN-PSO approach

    Directory of Open Access Journals (Sweden)

    R. Spina

    2006-02-01

    Full Text Available Purpose: The aim of the work was the optimization of injection molded product warpage by using an integrated environment.Design/methodology/approach: The approach implemented took advantages of the Finite Element (FE Analysis to simulate component fabrication and investigate the main causes of defects. A FE model was initially designed and then reinforced by integrating Artificial Neural Network to predict main filling and packing results and Particle Swarm Approach to optimize injection molding process parameters automatically.Findings: This research has confirmed that the evaluation of the FE simulation results through the Artificial Neural Network system was an efficient method for the assessment of the influence of process parameter variation on part manufacturability, suggesting possible adjustments to improve part quality.Research limitations/implications: Future researches will be addressed to the extension of analysis to large thin components and different classes of materials with the aim to improve the proposed approach.Originality/value: The originality of the work was related to the possibility of analyzing component fabrication at the design stage and use results in the manufacturing stage. In this way, design, fabrication and process control were strictly links.

  19. Effect of injection molding parameters on nanofillers dispersion in masterbatch based PP-clay nanocomposites

    Directory of Open Access Journals (Sweden)

    J. Soulestin

    2012-03-01

    Full Text Available The effect of injection molding parameters (screw rotational speed, back pressure, injec-tion flow rate and holding pressure on the nanofiller dispersion of melt-mixed PP/clay nanocomposites was investigated. The nanocomposites containing 4 wt% clay were obtained by dilution of a PP/clay masterbatch into a PP matrix. The evaluation of the dispersion degree was obtained from dynamic rheological measurements. The storage modulus and complex viscosity exhibit significant dependence on the injection molding parameters. PP/clay nanocomposite molded using more severe injection parameters (high shear and long residence time displays the highest storage modulus and complex viscosity, which illustrates the improved dispersion of clay platelets. This better dispersion leads to better mechanical properties particularly higher Young modulus, tensile strength and unnotched impact strength. A Taguchi analysis was used to identify the influence of individual process parameters. The major individual parameter is the injection flow rate, whose increase improves nanoclay dispersion. The combination of high back pressure and high screw rotational speed is also necessary to optimize the dispersion of clay nanoplatelets.

  20. Micro Machining of Injection Mold Inserts for Fluidic Channel of Polymeric Biochips

    Directory of Open Access Journals (Sweden)

    Myeong-Woo Cho

    2007-08-01

    Full Text Available Recently, the polymeric micro-fluidic biochip, often called LOC (lab-on-a-chip, has been focused as a cheap, rapid and simplified method to replace the existing biochemical laboratory works. It becomes possible to form miniaturized lab functionalities on a chip with the development of MEMS technologies. The micro-fluidic chips contain many micro-channels for the flow of sample and reagents, mixing, and detection tasks. Typical substrate materials for the chip are glass and polymers. Typical techniques for micro-fluidic chip fabrication are utilizing various micro pattern forming methods, such as wet-etching, micro-contact printing, and hot-embossing, micro injection molding, LIGA, and micro powder blasting processes, etc. In this study, to establish the basis of the micro pattern fabrication and mass production of polymeric micro-fluidic chips using injection molding process, micro machining method was applied to form micro-channels on the LOC molds. In the research, a series of machining experiments using micro end-mills were performed to determine optimum machining conditions to improve surface roughness and shape accuracy of designed simplified micro-channels. Obtained conditions were used to machine required mold inserts for micro-channels using micro end-mills. Test injection processes using machined molds and COC polymer were performed, and then the results were investigated.

  1. Simulation of shrinkage and warpage of semi-crystalline thermoplastics

    Science.gov (United States)

    Hopmann, Ch.; Borchmann, N.; Spekowius, M.; Weber, M.; Schöngart, M.

    2015-05-01

    Today, the simulation of the injection molding process is state of the art. Besides the simulation of the manufacturing process, commercial simulation tools allow a prediction of the structural properties of the final part. Especially the complex shrinkage and warpage behavior is of interest as it significantly influences the part quality. Although modern simulation tools provide qualitatively correct results for several materials and processing conditions, significant deviations from the real component's behavior can occur for semi-crystalline thermoplastics. One underlying reason is the description on the macro scale used in these simulation tools. However, in semi-crystalline materials significant effects take place on the micro scale, e.g. crystalline superstructures that cannot be neglected. As part of a research project at IKV, investigations are carried out to improve the simulation accuracy of shrinkage and warpage. To point out differences in the accuracy of commercially available simulation tools, a reference part is computed for the materials polypropylene and polyoxymethylene. The results are validated by injection molding experiments. The shrinkage and warpage behavior is characterized by optical measuring technology. In future, models for the description of the pvT behavior of semi-crystalline thermoplastics will be implemented into the software package SphäroSim which was developed at IKV. With this software, crystallization kinetics for semi-crystalline thermoplastics can be calculated on the micro scale. With the newly implemented pvT models the calculation of shrinkage and warpage for semi-crystalline thermoplastics will be enabled on the micro scale.

  2. Heat transfer at the polymer-metal interface -- A method of analysis and its application to injection molding

    Energy Technology Data Exchange (ETDEWEB)

    Quilliet, S.; Le Bot, P.; Delaunay, D.; Jarny, Y.

    1997-07-01

    Heat transfer at the polymer-metal interface constitutes a key point to interpret shrinkage and warpage during injection molding. In heat transfer, the interface conditions are modelized by a thermal contact resistance (TCR). An apparatus was built and a new method was used to determine the TCR variation and simultaneously the temperature field in the polymer, in a real situation of injection molding. The experimental device consists in an instrumented injection mold. A specific heat flux sensor has been developed in order to determine simultaneously the metal surface temperature and the heat flux crossing the interface. The polymer surface temperature is obtained by solving numerically the heat conduction equation in the polymer. The boundary conditions are the experimental heat flux densities. The initial condition is evaluated by an inverse method based on the energy conservation and the heat flux history. Two thermal models are necessary to take into account the packing and the cooling phases. Some experimental results will be shown.

  3. Localized mold heating with the aid of selective induction for injection molding of high aspect ratio micro-features

    International Nuclear Information System (INIS)

    High-frequency induction is an efficient, non-contact means of heating the surface of an injection mold through electromagnetic induction. Because the procedure allows for the rapid heating and cooling of mold surfaces, it has been recently applied to the injection molding of thin-walled parts or micro/nano-structures. The present study proposes a localized heating method involving the selective use of mold materials to enhance the heating efficiency of high-frequency induction heating. For localized induction heating, a composite injection mold of ferromagnetic material and paramagnetic material is used. The feasibility of the proposed heating method is investigated through numerical analyses in terms of its heating efficiency for localized mold surfaces and in terms of the structural safety of the composite mold. The moldability of high aspect ratio micro-features is then experimentally compared under a variety of induction heating conditions.

  4. High quality ion channels recordings on an injection molded polymer chip

    DEFF Research Database (Denmark)

    Tanzi, Simone

    2013-01-01

    In this thesis we demonstrate high quality recordings of the ion channel activity across the cell membrane in a biological cell by employing the so called patch clamping technique on an injection molded polymer microfluidic device. Such recordings are traditionally made using glass micropipettes, or in recent years using consumable microfluidic chips of high costs. The patch clamping method is widely used both in fundamental studies of electrophysiology of living cells and tissue and in drug discovery. The findings of this work will allow direct recordings of ion channel activity to be made using the cheapest materials and production platform to date, and with the potential for very high throughput. The employment of cornered apertures for cell capture allowed the fabrication of devices without through holes via a process comprising master origination by dry etching in a silicon substrate, electroplating in nickel, and injection molding of the final part. A thorough characterization of the patching orifices by means of SEM and AFM showed high replication accuracy through the fabrication process. The most critical device parameters were identified as the length of the patching capillaries and the very low surface roughness inside of the capillaries. The cross-sectional shape of the cornered apertures was found to be less critical, as apertures with different profiles were tested with cells and showed the same ability to form tight seals with cells with negligible leak currents. The ability to form high resistance seals in the GOhm range, the so called gigaseals, is demonstrated with a success rate of 15%. The devices were functionally tested with Human Embryonice Kidney (HEK) cells expressing voltage-gated sodium channels and benchmarked against a commercial state-of-the-art system for automated ion channel recordings. These experiments considered current-voltage relationships for activation and inactivation of the sodium channels and their sensitivity to a local anesthetic, lidocaine. Both IVs and lidocaine does response curves obtained from the injection molded polymer device were in excellent agreement with data obtained from the commercial system.

  5. Predictive Engineering Tools for Injection-Molded Long-Carbon-Fiber Thermoplastic Composites - Second FY 2015 Quarterly Report

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Ba Nghiep [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Fifield, Leonard S. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Kijewski, Seth A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Sangid, Michael D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Wang, Jin [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Costa, Franco [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Tucker, III, Charles L. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Mathur, Raj N. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Gandhi, Umesh N. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Mori, Steven [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-05-19

    During the second quarter of FY 2015, the following technical progress has been made toward project milestones: 1) Autodesk reviewed 3D fiber orientation distribution (FOD) comparisons and provided support on improving accuracy. 2) Autodesk reviewed fiber length distribution (FLD) data comparisons and provided suggestions, assisted PNNL in FOD and FLD parameter settings optimization, and advised PNNL on appropriate through thickness thermal conductivity for improved frozen layer effect on FOD predictions. Autodesk also participated in project review meetings including preparations and discussions towards passing the go/no-go decision point. 3) Autodesk implemented an improved FOD inlet profile specification method through the part thickness for 3D meshes and provided an updated ASMI research version to PNNL. 4) The University of Illinois (Prof. C.L. Tucker) provided Autodesk with ideas to improve fiber orientation modeling 5) Purdue University re-measured fiber orientation for the fast-fill 50wt% LCF/PA66 edge-gated plaque, and delivered the fiber orientation data for this plaque at the selected locations (named A, B, and C, Figure 1) to PNNL. Purdue also re-measured fiber orientation for locations A on the fast-fill 30wt% LCF/PP and 50wt% LCF/PA66 center-gated plaques, which exhibited anomalous fiber orientation behavior. 6) Purdue University conducted fiber length measurements and delivered the length data to PNNL for the purge materials (slow-fill 30wt% LCF/PP and 30wt% LCF/PA66 purge materials) and PlastiComp plaques selected on the go/no-go list for fiber length model validation (i.e., slow-fill edge-gated 30wt% LCF/PP and 30wt% LCF/PA66 plaques, Locations A, B, and C). 7) PNNL developed a method to recover intact carbon fibers from LCF/PA66 materials. Isolated fibers were shipped to Purdue for length distribution analysis. 8) PNNL completed ASMI mid-plane analyses for all the PlastiComp plaques defined on the go/no-go list for fiber orientation (FO) model validation and compared the predicted fiber orientations with the measured data provided by Purdue at Locations A, B, and C on these plaques. The 15% accuracy criterion based on evaluation of tensile and bending stiffness was used to assess the accuracy in fiber orientation predictions. 9) PNNL completed ASMI mid-plane analyses for all the PlastiComp plaques defined on the go/no-go list for fiber length distribution (FLD) model validation and compared the predicted length distributions with the measured data provided by Purdue at Locations A, B, and C on these plaques. The 15% accuracy criterion based on evaluation of tensile and bending stiffness was used to assess the accuracy in fiber orientation predictions. 10) PNNL tested the new ASMI version received from Autodesk in March 2015, examined and discussed 3D fiber orientation predictions for PlastiComp plaques. 11) PlastiComp, Inc. (PlastiComp), Toyota Research Institute North America (Toyota) and Magna Exteriors and Interiors Corporation (Magna) participated in discussions with team members on the go/no-go plan. Toyota continued the discussion with Magna on tool modification for molding the complex part in order to achieve the target fiber length in the part.

  6. Predictive Engineering Tools for Injection-Molded Long-Carbon-Fiber Thermoplastic Composites - FY 2015 First Quarterly Report

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Ba Nghiep [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Fifield, Leonard S. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Kijewski, Seth A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Sangid, Michael D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Wang, Jin [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Jin, Xiaoshi [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Costa, Franco [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Tucker, III, Charles L. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Mathur, Raj N. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Gandhi, Umesh N. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Mori, Steven [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-01-29

    During the first quarter of FY 2015, the following technical progress has been made toward project milestones: 1) Autodesk delivered a new research version of ASMI to PNNL. This version includes the improved 3D fiber orientation solver, and the reduced order model (ROM) for fiber length distribution using the proper orthogonal decomposition (POD) implemented in the mid-plane, dual-domain and 3D solvers. 2) Autodesk coordinated a conference paper with PNNL reporting ASMI mid-plane fiber orientation predictions compared with the measured data for two PlastiComp plaques. This paper was accepted for presentation at the 2015 Society for Plastics Engineers (SPE) ANTEC conference. 3) The University of Illinois (Prof. Tucker) assisted team members from Purdue with fiber orientation measurement techniques, including interpretation of off-axis cross sections. 4) The University of Illinois assisted Autodesk team members with software implementation of the POD approach for fiber length modeling, and with fiber orientation modeling. 5) The University of Illinois co-authored in the SPE ANTEC paper, participated with the team in discussions of plaque data and model results, and participated in the definition of go/no-go experiments and data. 6) Purdue University (Purdue) conducted fiber orientation measurements for 3 PlastiComp plaques: fast-fill 30wt% LCF/PP center-gated, fast-fill 50wt% LCF/PA66 edge-gated and fast-fill 50wt% LCF/PA66 center-gated plaques, and delivered the fiber orientation data for these plaques at the selected locations (named A, B, and C) to PNNL. However, the data for the fast-fill 50wt% LCF/PA66 edge-gated plaque exhibited unusual variations and could not be used for the model validation. Purdue will re-measure fiber orientation for this plaque. 7) Based on discussions with the University of Illinois Purdue explained the ambiguity in the measurements of the fiber orientation components. 8) PNNL discussed with team members to establish a go/no-go decision plan for the project and submitted the established plan to DOE. 9) PNNL performed ASMI mid-plane analyses for the fast-fill center-gated 30wt% LCF/PP and 50wt% LCF/PA66 plaques and compared the predicted fiber orientations with the measured data provided by Purdue at Locations A, B, and C on these plaques. 10) Based on discussions with the University of Illinois and Autodesk, PNNL proposed a procedure to adjust fiber orientation data for Location A of the center-gated plaques so that the data can be expressed and interpreted in the flow/cross-flow direction coordinate system. 11) PNNL tested the new ASMI version received from Autodesk, examined and discussed 3D fiber orientation predictions for PlastiComp plaques. 12) PlastiComp, Inc. (PlastiComp), Toyota Research Institute North America (Toyota) and Magna Exteriors and Interiors Corp. (Magna) participated in discussions with team members on the go/no-go plan and the issues related to fiber length measurements. Toyota continued the discussion with Magna on tool modification for molding the complex part in order to achieve the target fiber length in the part.

  7. Predictive Engineering Tools for Injection-Molded Long-Carbon-Fiber Thermoplastic Composites - FY 2014 First Quarterly Report

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Ba Nghiep; Sanborn, Scott E.; Simmons, Kevin L.; Mathur, Raj N.; Sangid, Michael D.; Jin, Xiaoshi; Costa, Franco; Gandhi, Umesh N.; Mori, Steven; Tucker III, Charles L.

    2014-02-19

    The CRADA between PNNL, Autodesk, Toyota and Magna has been effective since October 28th, 2013. The whole team including CRADA and subcontract partners kicked off the project technically on November 1st, 2013. This report describes work performed during the first quarter of FY 2014. The following technical progresses have been made toward project milestones: 1) The project kickoff meeting was organized at PlastiComp, Inc. in Winona on November 13th, 2013 involving all the project partners. During this meeting the research plan and Gantt chart were discussed and refined. The coordination of the research activities among the partners was also discussed to ensure that the deliverables and timeline will be met. 2) Autodesk delivered a research version of ASMI to PNNL for process modeling using this tool under the project. PNNL installed this research version on a PNNL computer and tested it. Currently, PNNL is using ASMI to prepare the models for PlastiComp plaques. 3) PlastiComp has compounded long carbon-fiber reinforced polypropylene and polyamide 6,6 compounds for rheological and thermal characterization tests by the Autodesk laboratories in Melbourne, Australia. 4) Initial mold flow analysis was carried out by PlastiComp to confirm that the 3D complex part selected by Toyota as a representative automotive part is moldable. 5) Toyota, Magna, PlastiComp and PNNL finalized the planning for molding the Toyota 3D complex part. 6) Purdue University worked with PNNL to update and specify the test matrix for characterization of fiber length/orientation. 7) Purdue University developed tools to automate the data collection and analysis of fiber length and orientation measurements. 8) Purdue University designed and specified equipment to replace the need for equipment using the technology established by the University of Leeds at General Motors.

  8. Predictive Engineering Tools for Injection-Molded Long-Carbon-Fiber Thermoplastic Composites - FY13 Third Quarterly Report

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Ba Nghiep; Simmons, Kevin L.

    2013-08-06

    This quarterly report summarizes the status for the project planning to obtain all the approvals required for a Cooperative Research and Development Agreement (CRADA) with Autodesk, Inc., Toyota Motor Engineering and Manufacturing North America (Toyota), and Magna Exterior and Interiors Corporation (Magna). The CRADA documents have been processed by PNNL Legal Services that is also coordinating the revision effort with the industrial parties to address DOE’s comments.

  9. Predictive Engineering Tools for Injection-Molded Long-Carbon-Fiber Thermoplastic Composites - FY13 Fourth Quarterly Report

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Ba Nghiep; Simmons, Kevin L.

    2013-12-02

    This quarterly report summarizes the status of the project planning to obtain all the approvals required for a Cooperative Research and Development Agreement (CRADA) with Autodesk, Inc., Toyota Motor Engineering and Manufacturing North America (Toyota), and Magna Exterior and Interiors Corporation (Magna). The final CRADA documents processed by PNNL’s Legal Services were submitted to all the parties for signatures.

  10. Qualification Methods of Al2O3 Injection Molding Raw Materials

    Science.gov (United States)

    Egész, Á.; Gömze, L. A.

    2015-04-01

    For producing ceramic arc tube parts (plugs), there are used two different major components for producing injection molding raw material (feedstock): high purity alumina powder as the main component, and an organic paraffin wax as a binder material. It is expressly important to know the material, physical and chemical properties of these components, since mainly these have effect on the homogenity of feedstock, and therefore on the quality of end product. In this research, both of the main components and the moldable raw material was investigated by visual, physical, and thermal methods. As most important and main statement, the researchers found that the dynamic viscosity of raw material depends more on the applied temperature, than on the deformation speed gradient. Applied analitycal methods were laser granulometry, sieve analysis, differential thermal analysis and rheology analysis.

  11. Study of soft magnetic iron cobalt based alloys processed by powder injection molding

    Science.gov (United States)

    Silva, Aline; Lozano, Jaime A.; Machado, Ricardo; Escobar, Jairo A.; Wendhausen, Paulo A. P.

    As a near net shape process, powder injection molding (PIM) opens new possibilities to process Fe-Co alloys for magnetic applications. Due to the fact that PIM does not involve plastic deformation of the material during processing, we envisioned the possibility of eliminating vanadium (V), which is generally added to Fe-Co alloys to improve the ductility in order to enable its further shaping by conventional processes such as forging and cold rolling. In our investigation we have found out two main futures related to the elimination of V, which lead to a cost-benefit gain in manufacturing small magnetic components where high-saturation induction is needed at low frequencies. Firstly, the elimination of V enables the achievement of much better magnetic properties when alloys are processed by PIM. Secondly, a lower sintering temperature can be used when the alloy is processed starting with elemental Fe and Co powders without the addition of V.

  12. Microstructure and magnetic properties of Fe-50%Ni alloy fabricated by powder injection molding

    Science.gov (United States)

    Ma, Jidong; Qin, Mingli; Zhang, Lin; Zhang, Ruijie; Qu, Xuanhui

    2013-03-01

    Fe-50%Ni soft magnetic alloys were produced by powder injection molding using carbonyl iron and carbonyl nickel as raw materials. The effects of sintering temperature and time on the microstructure and magnetic properties of the alloys were investigated. The results indicate that the magnetic properties are dependent on the microstructure. The densification and grain size of the alloys increase with increasing sintering temperature and time, facilitating the enhancement of permeability and saturation induction, as well as the decrease of coercive force. In the case of the sintering temperature of 1360 °C for 10 h, the relative density of 97% and grain size of 200 ?m were obtained, and the maximum permeability of 43,541, saturation induction of 1.48 T and coercive force of 6.8 A/m were achieved. Further elongation of sintering time did not bring about any increase of densification and grain size.

  13. Injection molding micro patterns with high aspect ratio using a polymeric flexible stamper

    Directory of Open Access Journals (Sweden)

    2011-11-01

    Full Text Available Poor filling occurs during the injection molding process of micro- or nano- scale patterns mainly because the hot polymer melt rapidly cools and its skin quickly solidifies upon contact with the mold surface. In this study, it is proposed to use Polyethylene terephthalate (PET film coated with patterned polyurethane acrylate (PUA as an effective thermal barrier. It can significantly hinder heat transfer into the mold during the molding process and thus may keep the melt viscosity low for longer duration. As a result, the replication would be improved not only during the filling phase but also during the packing phase. In order to verify the validity of the use of polymeric stamper, the melt-film interface temperature was evaluated by numerical simulation. Experimental results indicated that patterns possessing widths within the range of one to tens of micrometers and a height of approximately 10 µm were successfully filled and demolded.

  14. A Study on the Sensitivity and Optimization for Gate Location in Injection Mold Filling

    Energy Technology Data Exchange (ETDEWEB)

    Yoo, Yeongeun [LG Chemical Ltd., Seoul (Korea, Republic of); Tucker III, Charles L. [Univ. of Illinois at Urbana-Champaign, Illinois (United States)

    2002-11-15

    A manufacturing process design methodology is presented to optimize the gate location in injection molding. The design methodology employs polymer process modeling, design sensitivity analysis, and numerical optimization. To solve the design problem, design sensitivities are used with numerical optimization. A new method to apply inlet boundary condition is presented to locate the gate arbitrarily on the mold and the gate pressure is evaluated from the result pressure field with efficiency. The sensitivities are evaluated with respect to gate locations. During the optimization, a method to measure distance on the curved surface in the unit of element is introduced to keep the gate inside the mold. The method developed in this study is applied to some geometries of application and the optimal location is obtained effectively.

  15. INJECTION MOLDING AND STRUCTURAL ANALYSIS IN METAL TO PLASTIC CONVERSION OF BOLTED FLANGE JOINT BY CAE

    Directory of Open Access Journals (Sweden)

    Marian Blaško

    2014-12-01

    Full Text Available Many metal parts in various applications are being replaced by plastic parts. There are several reasons for that depending on actual application - minimize part cost, enhance corrosion resistance, integrating more components into one part etc. Most important steps of metal to plastic conversion are material selection and design of plastic part. Plastic part has to withstand the same load as metal part. To fulfill this requirement fiber reinforced engineering plastics are often used. Also it is convenient to substitute heavy wall sections with ribbed structure to increase load-carrying ability of part and decrease cycle time, eliminate voids, sink marks etc. Mechanical properties of such part could be highly affected by fiber orientation. Results of fiber orientation from injection molding filling analysis can be used in stress analysis for better prediction of part response to mechanical load. Such coupled analysis is performed here in this case study on bolted flange joint.

  16. Biodegradability of injection molded bioplastic pots containing polylactic acid and poultry feather fiber.

    Science.gov (United States)

    Ahn, H K; Huda, M S; Smith, M C; Mulbry, W; Schmidt, W F; Reeves, J B

    2011-04-01

    The biodegradability of three types of bioplastic pots was evaluated by measuring carbon dioxide produced from lab-scale compost reactors containing mixtures of pot fragments and compost inoculum held at 58 °C for 60 days. Biodegradability of pot type A (composed of 100% polylactic acid (PLA)) was very low (13 ± 3%) compared to literature values for other PLA materials. Near infrared spectroscopy (NIRS) results suggest that the PLA undergoes chemical structural changes during polymer extrusion and injection molding. These changes may be the basis of the low biodegradability value. Biodegradability of pot types B (containing 5% poultry feather, 80% PLA, 15% starch), and C (containing 50% poultry feather, 25% urea, 25% glycerol), were 53 ± 2% and 39 ± 3%, respectively. More than 85% of the total biodegradation of these bioplastics occurred within 38 days. NIRS results revealed that poultry feather was not degraded during composting. PMID:21320772

  17. Study of soft magnetic iron cobalt based alloys processed by powder injection molding

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Aline [Departamento de Engenharia Mecanica-Labmat, Universidade Federal de Santa Catarina, Florianopolis 88040-900 (Brazil)], E-mail: aline@emc.ufsc.br; Lozano, Jaime A. [Departamento de Engenharia Mecanica-Labmat, Universidade Federal de Santa Catarina, Florianopolis 88040-900 (Brazil); Machado, Ricardo [Steelinject Ltda, Dalton Lahm dos Reis, 201-Distrito Industrial, Caxias do Sul 95112-090 (Brazil); Escobar, Jairo A. [Universidad de Los Andes, Departamento de Ingenieria Mecanica-Bogota (Colombia); Wendhausen, Paulo A.P. [Departamento de Engenharia Mecanica-Labmat, Universidade Federal de Santa Catarina, Florianopolis 88040-900 (Brazil)

    2008-07-15

    As a near net shape process, powder injection molding (PIM) opens new possibilities to process Fe-Co alloys for magnetic applications. Due to the fact that PIM does not involve plastic deformation of the material during processing, we envisioned the possibility of eliminating vanadium (V), which is generally added to Fe-Co alloys to improve the ductility in order to enable its further shaping by conventional processes such as forging and cold rolling. In our investigation we have found out two main futures related to the elimination of V, which lead to a cost-benefit gain in manufacturing small magnetic components where high-saturation induction is needed at low frequencies. Firstly, the elimination of V enables the achievement of much better magnetic properties when alloys are processed by PIM. Secondly, a lower sintering temperature can be used when the alloy is processed starting with elemental Fe and Co powders without the addition of V.

  18. All polymer, injection molded nanoslits, fabricated through two-level UV-LIGA processes

    DEFF Research Database (Denmark)

    Østergaard, Peter Friis; Matteucci, Marco

    2012-01-01

    Micro- and nanofluidic systems fabricated in silicon and glass substrates are expensive and have long production cycles. To minimize the time used by researchers to fabricate their systems, rather than using them, medium to high volume throughput of specific chips, containing fluidic channels in the micro- and nanoregime is required. To obtain this, injection molding is included in the research process for making several chips (100-1000) with the same layout. The time it takes for the individual chip to be fabricated in this way is much shorter than with conventional cleanroom methods, and the price is equally lower. Optimization of the final chip is explored, by looking at which aspects ratios are possible to obtain in polymer chips. Finally, signal to noise ratio of the chips used for fluorescent experiments is investigated, by an expected reduction of the excitation of fluorescent states in the polymer with the use of chips in different colors.

  19. The effect of mold surface topography on plastic parat in-process shrinkage in injection molding

    DEFF Research Database (Denmark)

    ArlØ, Uffe Rolf; Hansen, Hans NØrgaard

    2003-01-01

    An experimental study of the effect of mold surface roughness on in-process in-flow linear part shrinkage in injection molding has been carried out. The investigation is based on an experimental two-cavity tool, where the cavities have different surface topographies, but are otherwise identical. The study has been carried out for typical commercial polystyrene and polypropylene grades. The relationship between mold surface topography and linear shrinkage has been investigated with an experimental two-cavity mold producing simple rectangular parts with the nominal dimensions 1 x 25 x 50 mm (see figure 1). The cavities have different surface topographies on one side, but are otherwise identical (see discussion of other contribution factors).

  20. Multiple Performance Optimization for the Best Metal Injection Molding Green Compact

    Directory of Open Access Journals (Sweden)

    M.R. Harun

    2011-01-01

    Full Text Available This study presents and demonstrates the effectiveness of optimizing multiple quality characteristics of the injection molding of the MIM green compacts via Taguchi method-based Grey analysis. The modified algorithm adopted here was successfully used for both detraining the optimum setting of the process parameters and for combining multiple quality characteristics into one integrated numerical value called Grey relational grade. The significant molding parameters were identified as (1 Injection Pressure (2 Injection Temperature (3 Powder Loading (4 Mold Temperature (5 Holding Pressure and (6 Injection Speed. In addition, the multiple quality characteristics required are: (1 less defects (2 strong and (3 denser compact. The result concluded that the powder loading (C is very significant for the combination of the quality characteristics.

  1. Fabrication and characterization of injection molded multi level nano and microfluidic systems

    DEFF Research Database (Denmark)

    Matteucci, Marco; Christiansen, Thomas Lehrmann

    2013-01-01

    We here present a method for fabrication of multi-level all-polymer chips by means of silicon dry etching, electroplating and injection molding. This method was used for successful fabrication of microfluidic chips for applications in the fields of electrochemistry, cell trapping and DNA elongation. These chips incorporate channel depths in the range between 100nm and 100?m and depth to width aspect ratios between 1/200 and 2. Optimization of the sealing process of all-polymer COC microfluidic chips by means of thermal bonding is also presented. The latter includes comparing the bonding strength of UV-treated foils and presentation of a simple model for estimating the delamination pressure. With UV surface treatments, foils of 100?m thickness were found to withstand pressures up to 9atm in Ø4mm cylindrical inlets when thermally bonded to micropatterned substrates of 2mm thickness.

  2. Hydrogen silsesquioxane mold coatings for improved replication of nanopatterns by injection molding

    DEFF Research Database (Denmark)

    Hobæk, Thor Christian; Matschuk, Maria

    2015-01-01

    We demonstrate the replication of nanosized pillars in polymer (cyclic olefin copolymer) by injection molding using nanostructured thermally cured hydrogen silsesquioxane (HSQ) ceramic coatings on stainless steel mold inserts with mold nanostructures produced by a simple embossing process. At isothermal mold conditions, the average pillar height increases by up to 100% and a more uniform height distribution is observed compared to a traditional metal mold insert. Thermal heat transfer simulations predict that the HSQ film retards the cooling of the polymer melt during the initial stages of replication, thus allowing more time to fill the nanoscale cavities compared to standard metal molds. A monolayer of a fluorinated silane (heptadecafluorotrichlorosilane) deposited on the mold surface reduces the mold/polymer interfacial energy to support demolding of the polymer replica. The mechanical stability of thermally cured HSQ makes it a promising material for nanopattern replication on an industrial scale without the need for slow and energy intensive variotherm processes.

  3. Experimental validation of viscous and viscoelastic simulations of micro injection molding process

    DEFF Research Database (Denmark)

    Gava, Alberto; Tosello, Guido

    2009-01-01

    The effects of two different rheological models used in the simulation of the micro injection molding (µIM) process are investigated. The Cross-WLF viscous model and the Giesekus viscoelastic model are selected and their performance evaluated using 3D models implemented on two different commercially available software packages. Simulation results are then compared with the experimental µIM process. Validation parameters for the comparison are the flow front position during filling of the micro cavity. They are respectively obtained by applying the short-shots method and the flow-markers method. The µIM part is a polystyrene tensile bar test weighting 20mg and with three µ-features 300µm wide.

  4. Injection molded chips with integrated conducting polymer electrodes for electroporation of cells

    DEFF Research Database (Denmark)

    Andresen, Kristian; Hansen, Morten

    2010-01-01

    We present the design-concept for an all polymer injection molded single use microfluidic device. The fabricated devices comprise integrated conducting polymer electrodes and Luer fitting ports to allow for liquid and electrical access. A case study of low voltage electroporation of biological cells in suspension is presented. The working principle of the electroporation device is based on a focusing of the electric field by means of a constriction in the flow channel for the cells. We demonstrate the use of AC voltage for electroporation by applying a 1 kHz, +/- 50 V square pulse train to the electrodes and show delivery of polynucleotide fluorescent dye in 46% of human acute monocytic leukemia cells passing the constriction.

  5. Injection molded chips with integrated conducting polymer electrodes for electroporation of cells

    International Nuclear Information System (INIS)

    We present the design-concept for an all polymer injection molded single use microfluidic device. The fabricated devices comprise integrated conducting polymer electrodes and Luer fitting ports to allow for liquid and electrical access. A case study of low voltage electroporation of biological cells in suspension is presented. The working principle of the electroporation device is based on a focusing of the electric field by means of a constriction in the flow channel for the cells. We demonstrate the use of AC voltage for electroporation by applying a 1 kHz, ±50 V square pulse train to the electrodes and show delivery of polynucleotide fluorescent dye in 46% of human acute monocytic leukemia cells passing the constriction.

  6. Study of microcellular injection-molded polypropylene/waste ground rubber tire powder blend

    International Nuclear Information System (INIS)

    Microcellular polypropylene/waste ground rubber tire powder blend processing was performed on an injection-molding machine with a chemical foaming agent. The molded samples produced based on the design of experiments (DOE) matrices were subjected to tensile testing and scanning electron microscope (SEM) analyses. Molding conditions and waste ground rubber tire (WGRT) powder have been found to have profound effects on the cell structures and mechanical properties of polypropylene (PP) and waste ground rubber tire powder composite samples. The result shows that microcellular PP/WGRT blend samples exhibit smaller cell size and higher cell density compare with polypropylene resin. Among the molding parameters studied, chemical foaming agent weight percentage has the most significant effect on cell size, cell density, and tensile strength. The results also suggest that tensile strength of microcellular PP/WGRT composites is sensitive to weight reduction, and skin thickness.

  7. Measurements of Powder-Polymer Mixture Properties and Their Use in Powder Injection Molding Simulations for Aluminum Nitride

    Science.gov (United States)

    Kate, Kunal H.; Onbattuvelli, Valmikanathan P.; Enneti, Ravi K.; Lee, Shi W.; Park, Seong-Jin; Atre, Sundar V.

    2012-09-01

    Aluminum nitride has been favored for applications in manufacturing substrates for heat sinks due to its elevated temperature operability, high thermal conductivity, and low thermal expansion coefficient. Powder injection molding is a high-volume manufacturing technique that can translate these useful material properties into complex shapes. In order to design and fabricate components from aluminum nitride, it is important to know the injection-molding behavior at different powder-binder compositions. However, the lack of a materials database for design and simulation at different powder-polymer compositions is a significant barrier. In this paper, a database of rheological and thermal properties for aluminum nitride-polymer mixtures at various volume fractions of powder was compiled from experimental measurements. This database was used to carry out mold-filling simulations to understand the effects of powder content on the process parameters and defect evolution during the injection-molding process. The experimental techniques and simulation tools can be used to design new materials, select component geometry attributes, and optimize process parameters while eliminating expensive and time-consuming trial-and-error practices prevalent in the area of powder injection molding.

  8. CONVERSION OF WIND POWER TO HYDROGEN FUEL: DESIGN OF AN ALTERNATIVE ENERGY SYSTEM FOR AN INJECTION MOLDING FACILITY

    Science.gov (United States)

    Injection molding plants are large consumers of electricity. At its current level of operations, Harbec Plastics (Ontario, NY) uses about 2,000,000 kilowatt-hours of electricity per year. Based on the US average fuel mix, approximately 1.5 pounds of CO2

  9. Optimization of powder injection molding of feedstock based on aluminum oxide and multicomponent water-soluble polymer binder.

    Czech Academy of Sciences Publication Activity Database

    Hausnerová, B.; Marcaníková, L.; Filip, Petr; Sáha, P.

    2011-01-01

    Ro?. 51, ?. 7 (2011), s. 1376-1382. ISSN 0032-3888 R&D Projects: GA ?R GA103/08/1307 Institutional research plan: CEZ:AV0Z20600510 Keywords : powder injection mold ing * viscosity * thermogravimetric analysis Subject RIV: BK - Fluid Dynamics Impact factor: 1.302, year: 2011

  10. Short-term and long-term behavior of PP-polymer nanocomposites produced by injection molding compounding

    Science.gov (United States)

    Battisti, M. G.; Guttmann, P.; Chitu, L.; Friesenbichler, W.

    2015-05-01

    There are only few investigations considering the impact of nanoscale fillers on the mechanical und thermo-mechanical properties of polymers. Particularly there is a lack of results regarding long term creep behavior of Polypropylene-based polymer nanocomposites (PNCs). Therefore, the objective of this study is to determine the influence of nanofiller content on the mechanical and thermo-mechanical behavior of Polypropylene-based PNCs. Processing of the test specimens was carried out using the Polymer NanoComposite Injection Molding Compounder (PNC-IMC). In comparison to the conventional compounding process, in which the compound must be pelletized and fed into the injection molding machine for the second plasticizing process, injection molding compounding combines these two processing steps. Material compounding and subsequent injection molding are done directly with only one plasticizing process, using a heated melt pipe and a melt accumulator for melt transfer from the compounder to the injection molding machine. The PNCs were produced in the 3-in-1 process at the PNC-IMC, where all components (polymer, compatibilizer, nanofiller) were added simultaneously into the compounder. Furthermore, the polymer melt was treated using elongational flow generating devices for better intercalation and exfoliation of the nanofillers. Tensile tests were made to characterize the short-term-mechanical properties. Tensile creep tests show the influence of nanofillers on the long-term-creep-performance and dynamic mechanical tests (DMA) were performed to investigate the thermo-mechanical behavior. Both, the improvements in the mechanical and thermo-mechanical properties in comparison to the pure polypropylene are shown and give an excellent overview of possibilities and limitations of the PNCs. Further research will focus on the detailed understanding of the different mechanisms of property improvement of layered silicates in polymer. By using small angle X-ray scattering exfoliation and intercalation of the layered silicates in the polymer matrix will be verified.

  11. Mechanical properties of the weld line defect in micro injection molding for various nano filled polypropylene composites

    International Nuclear Information System (INIS)

    Research highlights: ? PP/CNFs and PP/TiO2 composites with relative high loading fractions (10, 20, 30 and 35 wt%) were fabricated by inner melt mixing process. Micro tensile test samples were formed by injection molding combined with variotherm process for all composites. ? The morphological properties of all nano composites were characterized by WXRD, whose results imply the adding nano fillers did not change the crystal form of PP, but the crystallites size and distance between lattices of crystals were changed with various nano fillers and loading fractions. ? DSC analysis show that due to the nucleating function of nano fillers, the peak temperature of crystallization was increased and the peak temperature of crystallization melting was decreased by adding the nanofillers. ? The flow ability of nano composites was tested by high pressure single capillary rheometer and the results demonstrate that nano fillers increased the viscosity of PP matrix. ? Based on these significant information and analysis foundation of the nano filled composites, the micro weld line samples were formed by injection molding process and characterized by tensile test method. From the achieved results, it can be found that in general, for functional nano filled polymer composites, the mechanical property of micro weld lines were obviously influenced by nano fillers' shape and loading fractions. ? The E modulus of micro weld line was increased due to loading CNFs in PP matrix, while the elongation of the micro tensile samples with weld line is considerably decreased comparing with those of unfilled PP samples. The detrimental tensile strength of micro weld lines were observed when CNFs contents increasing, except for at a 10 wt%. ? For TiO2 nano particles filled PP, due to the poor dispersion of nano particles, at low loading fraction of 10 wt%, the E modulus and tensile strength of micro weld lines were decreased by filling nano particles, but when the loading fraction is increased to 30%, the E modulus and tensile strength of micro weld line were increased again compared with the low loading level. ? Finally, an empirical prediction equation for micro injection molded weld line strength of nano PP composites was proposed for higher nano filler loading fraction than 10 wt%. - Abstract: The nano filled functional polymer materials have been widely processed with micro injection molding technology for micro electromechanical systems (MEMS) fabrication. As the unfavorable defect in micro injection molding parts, weld line brings reduced mechanical and physical properties, especially for nano filled composites. In this study, polypropylene (PP) was compounded respectively with carbon nano fibers (CNFs) and TiO2 nano particles at various weight fractions (10, 20, 30, 35 wt%) through co-screws internal mixing. The morphological, thermal and rheological properties of nano composites were characterized by wider angle X-ray diffraction (WXRD), different scanning calorimeter (DSC) and high pressure capillary rheometer. Additionally, under the constant setting of injection molding process parameters in injection molding machine, micro tensile samples with weld lines for each nano filled PP composite were produced. The tensile tests were served as the characterizing method for weld line mechanical properties. The results show that when the CNFs is filled higher than 10 wt%, the tensile strength of samples with weld lines made of nano composites become lower than neat PP. While the raising CNFs content contributes to the improved E modulus of micro injection molded weld lines. Additionally, with the increasing fraction of CNFs in PP, the weld line area's elongation percent is decreased. Whereas for case of TiO2, the 10 wt% is the threshold for micro injection molded weld line tensile strength turning from decrease trend to increase. The same as CNFs, elongation of micro weld line samples were in general lower than neat PP as well, due to the addition of TiO2 nano particles.

  12. Prediction of birefringence in plastics optical elements using 3D CAE for injection molding

    Science.gov (United States)

    Maekawa, Yoshinori; Onishi, Michihisa; Ando, Atsushi; Matsushima, Shinji; Lai, Francis

    2000-07-01

    Recent improvements of plastics optics performance and manufacturing technology of plastics lenses have resulte din rapid applicationfo plastics otical elements. On eof the factors indelyaing the applications of the plastics oticalelements is the existence of birefringence in palstics lenses. It gives us a challenge to resolve th proboem so that the plastics oticalelements can achieve much higher levels of performance. It is generally recongized that the mechanism of birefringence generation is relevant to the resin behaviors during the injection molding process. If this mechanism is fully understood by flow analysis, it may be a great contribution to the fabrication of plastics optical elements. However, convetnioanl two-dimensional flow anlaysis on onjection molding fails to graps th ephenomena of birfringence. in this paper, we have successfully indentified some phenomena on onjection molding that are closely related to the gneratioof birefringence.We anlayzed th ephenomean in detial sin filling pakcing, and colling processes durin th einjection modlin process using tthree-dimensional CAE system, called 3D TIMON. The anlayzed rsults were confirmed experimentally and theyenabled us to predict the generation of birefringence by CAE analysis.

  13. Thermal and mechanical behavior of injection molded Poly(3-hydroxybutyrate/Poly(epsilon-caprolactone blends

    Directory of Open Access Journals (Sweden)

    Marcia Adriana Tomaz Duarte

    2006-03-01

    Full Text Available Aiming the development of high-performance biodegradable polymer materials, the properties and the processing behavior of poly(3-hydroxybutyrate, P(3HB, and their blends with poly(epsilon-caprolactone, PCL, have been investigated. The P(3HB sample, obtained from sugarcane, had a molecular weight of 3.0 x 10(5 g.mol¹, a crystallinity degree of 60%, a glass transition temperature (Tg, at - 0.8 °C, and a melting temperature at 171 °C. The molecular weight of PCL was 0.8 x 10(5 g.mol-1. Specimens of 70/30 wt. (% P(3HB/PCL blends obtained by injection molding showed tensile strength of 21.9 (± 0.4 MPa, modulus of 2.2 (± 0.3 GPa, and a relatively high elongation at break, 87 (± 20%. DSC analyses of this blend showed two Tg´s, at - 10.6 °C for the P(3HB matrix, and at - 62.9 °C for the PCL domains. The significant decrease on the Tg of P(3HB evidences a partial miscibility of PCL in P(3HB. According to the Fox equation, the new Tg corresponds to a 92/8 wt. (% P(3HB/PCL composition.

  14. Reaction injection molding and direct covalent bonding of OSTE+ polymer microfluidic devices

    Science.gov (United States)

    Sandström, N.; Shafagh, R. Z.; Vastesson, A.; Carlborg, C. F.; van der Wijngaart, W.; Haraldsson, T.

    2015-07-01

    In this article, we present OSTE+RIM, a novel reaction injection molding (RIM) process that combines the merits of off-stoichiometric thiol-ene epoxy (OSTE+) thermosetting polymers with the fabrication of high quality microstructured parts. The process relies on the dual polymerization reactions of OSTE+ polymers, where the first curing step is used in OSTE+RIM for molding intermediately polymerized parts with well-defined shapes and reactive surface chemistries. In the facile back-end processing, the replicated parts are directly and covalently bonded and become fully polymerized using the second curing step, generating complete microfluidic devices. To achieve unprecedented rapid processing, high replication fidelity and low residual stress, OSTE+RIM uniquely incorporates temperature stabilization and shrinkage compensation of the OSTE+ polymerization during molding. Two different OSTE+ formulations were characterized and used for the OSTE+RIM fabrication of optically transparent, warp-free and natively hydrophilic microscopy glass slide format microfluidic demonstrator devices, featuring a storage modulus of 2.3?GPa and tolerating pressures of at least 4?bars.

  15. Experimental Study of Fiber Length and Orientation in Injection Molded Natural Fiber/Starch Acetate Composites

    DEFF Research Database (Denmark)

    Peltola, Heidi; Madsen, Bo

    2011-01-01

    Composite compounds based on triethyl citrate plasticized starch acetate and hemp and flax fibers were prepared by melt processing. Plasticizer contents from 20 to 35 wt% and fiber contents of 10 and 40 wt% were used. The compounded composites were injection molded to tensile test specimens. The effect of processing, melt viscosity and fiber type on the fiber length was investigated. The lengths of fully processed fibers were determined by dissolving the matrix and measuring the length of the remaining fibers by microscope analysis. A clear reductive effect of the processing on the fiber length was noticed. A reduction of fiber length along the increasing fiber content and the decreasing plasticizer content was also detected. This reduction originated from the increasing shear forces during compounding, which again depended on the increased viscosity of the material. Hemp fibers were shown to remain longer and fibrillate more than flax fibers, leading to higher aspect ratio. Thus, the reinforcement efficiencyof hemp fibers by the processing was improved, in contrast with flax fibers. In addition, the analysis of fiber dispersion and orientation showed a good dispersion of fibers in the matrix, and a predominant orientation of the fibers in the melt flow direction.

  16. Application of knowledge-based vision to closed-loop control of the injection molding process

    Science.gov (United States)

    Marsh, Robert; Stamp, R. J.; Hill, T. M.

    1997-10-01

    An investigation is under way to develop a control system for an industrial process which uses a vision systems as a sensor. The research is aimed at the improvement of product quality in commercial injection molding system. A significant enhancement has been achieved in the level of application of visually based inspection techniques to component quality. The aim of the research has been the investigation, and employment, of inspection methods that use knowledge based machine vision. The application of such techniques in this context is comprehensive, extending from object oriented analysis, design and programming of the inspection program, to the application of rule based reasoning, to image interpretation, vision system diagnostics, component diagnostics and molding machine control. In this way, knowledge handling methods are exploited wherever they prove to be beneficial. The vision knowledge base contains information on the procedures required to achieve successful identification of component surface defects. A collection of image processing and pattern recognition algorithms are applied selectively. Once inspection of the component has been performed, defects are related to process variables which affect the quality of the component, and another knowledge base is used to effect a control action at the molding machine. Feedback from other machine sensor is also used to direct the control procedure. Results from the knowledge based vision inspection system are encouraging. They indicate that rapid and effective fault detection and analysis is feasible, as is the verification of system integrity.

  17. An injection molded microchip for nucleic acid purification from 25 microliter samples using isotachophoresis.

    Science.gov (United States)

    Marshall, L A; Rogacs, A; Meinhart, C D; Santiago, J G

    2014-02-28

    We present a novel microchip device for purification of nucleic acids from 25?L biological samples using isotachophoresis (ITP). The device design incorporates a custom capillary barrier structure to facilitate robust sample loading. The chip uses a 2mm channel width and 0.15mm depth to reduce processing time, mitigate Joule heating, and achieve high extraction efficiency. To reduce pH changes in the device due to electrolysis, we incorporated a buffering reservoir physically separated from the sample output reservoir. To reduce dispersion of the ITP-focused zone, we used optimized turn geometries. The chip was fabricated by injection molding PMMA and COC plastics through a commercial microfluidic foundry. The extraction efficiency of nucleic acids from the device was measured using fluorescent quantification, and an average recovery efficiency of 81% was achieved for nucleic acid masses between 250pg and 250ng. The devices were also used to purify DNA from whole blood, and the extracted DNA was amplified using qPCR to show the PCR compatibility of the purified sample. PMID:24485540

  18. Optimization of plastic injection molding process parameters for manufacturing a brake booster valve body

    International Nuclear Information System (INIS)

    Highlights: • PIM process parameters have been optimized for a brake booster valve body. • The Taguchi method and computer-aided engineering have been integrated and used. • Seven key parameters of PIM process have been considered. • A nearly 12% improvement have been found by using the optimal PIM process parameters. • The efficient improvement can improve the safety performance of a vehicle. - Abstract: The plastic injection molding (PIM) process parameters have been investigated for manufacturing a brake booster valve body. The optimal PIM process parameters is determined with the application of computer-aided engineering integrating with the Taguchi method to improve the compressive property of the valve body. The parameters considered for optimization are the following: number of gates, gate size, molding temperature, resin temperature, switch over by volume filled, switch over by injection pressure, and curing time. An orthogonal array of L18 is created for the statistical design of experiments based on the Taguchi method. Then, Mold-Flow analyses are performed by using the designed process parameters based on the L18 orthogonal array. The signal-to-noise (S/N) ratio and the analysis of variance (ANOVA) are used to find the optimal PIM process parameters and to figure out the impact of the viscosity of resin, curing percentage, and compressive strength on a brake booster valve body. When compared with the average compression strength out of the 18 design experiments, the compression strength of the valve body produced using the optimal PIM process parameters showed a nearly 12% improvement

  19. Micro Injection Molding of Thin Walled Geometries with Induction Heating System

    DEFF Research Database (Denmark)

    Menotti, Stefano; Hansen, Hans NØrgaard

    2014-01-01

    To eliminate defects and improve the quality of molded parts, increasing the mold temperature is one of the applicable solutions. A high mold temperature can increase the path flow of the polymer inside the cavity allowing reduction of the number of injection points, reduction of part thickness and moulding of smaller and more complex geometries. The last two aspects are very important in micro injection molding. In this paper a new embedded induction heating system is proposed and validated. An experimental investigation was performed based on a test geometry integrating different aspect ratios of small structures. ABS was used as material and different combinations of injection velocity, pressure and mold temperature were tested. The replicated test objects were measured by means of an optical CMM machine. On the basis of the experimental investigation the efficacy of the embedded induction heating system with respect to improvement of replication quality, reduction of injection pressure and injection velocity as well as reduction of cycle time has been verified.

  20. Thermal shock behavior of tungsten based alloys manufactured via powder injection molding

    Energy Technology Data Exchange (ETDEWEB)

    Pintsuk, G., E-mail: g.pintsuk@fz-juelich.de [Forschungszentrum Jülich, EURATOM-Association, D-52425 Jülich (Germany); Blagoeva, D. [Nuclear Research and Consultancy Group, P.O. Box 25, 1755 ZG Petten (Netherlands); Opschoor, J. [ECN, Energy research Centre of the Netherlands, P.O. Box 1, 1755 ZG Petten (Netherlands)

    2013-11-15

    The focus of this work is to address mechanical strength and recrystallization resistance through thermal shock investigation of newly developed fine grained tungsten base materials (i.e., pure tungsten and two doped tungsten-grades incorporating either 1 or 5 vol%Y{sub 2}O{sub 3} produced via powder injection molding (PIM)). Therefore, repetitive ELM (edge localized mode)-like loads (n = 100) were applied by means of an electron beam at various temperatures between RT and 400 °C (673 K) with a pulse duration of 1 ms and an absorbed power density of up to 1.13 GW/m{sup 2}. The microstructural properties, e.g. grain size, and Y{sub 2}O{sub 3}-particle distribution, were correlated with crack formation at a certain temperature, the crack propagation direction towards the bulk material and the amount of plastic deformation/surface roughening at higher temperatures. Thereby, it was shown that W–1 vol%Y{sub 2}O{sub 3} outperformed all other investigated grades and reference materials from literature.

  1. Injection molding of nanopatterned surfaces in the sub-micrometer range with induction heating aid

    DEFF Research Database (Denmark)

    Menotti, Stefano; Hansen, Hans NØrgaard

    2014-01-01

    Replication of sub-micrometer structures by injection molding leads to special requirements for the mold in order to ensure proper replica and acceptable cycle time. This paper investigates the applicability of induction heating embedded into the mold for the improvement of nanopattern replication. A tool insert having a surface containing functional geometries in the sub-micrometer range was produced using aluminum anodization and nickel electroplating. In order to provide elevated mold temperatures necessary for the complete replica of the pattern, a new mold setup was developed, which allows rapid heating of the cavity wall using an induction heating system. Temperature was measured using a thermocouple placed in the mold insert. The system was used to heat up the cavity wall with heating rates of up to 10 K/s. Acrylonitrile butadiene styrene (ABS) and polycarbonate (PC) were used as materials, and heating parameters were investigated after a preliminary optimization with standard heating conditions. The replicated surfaces were quantitatively characterized by atomic force microscopy using specific three-dimensional surface amplitude parameters and qualitatively inspected by scanning electron microscopy. The experimental results show that the use of the induction heating system is an efficient way for improving nanoreplication.

  2. Injection molding of ceramic filled polypropylene: The effect of thermal conductivity and cooling rate on crystallinity

    Energy Technology Data Exchange (ETDEWEB)

    Suplicz, A.; Szabo, F.; Kovacs, J.G., E-mail: kovacs@pt.bme.hu

    2013-12-20

    Highlights: • BN, talc and TiO{sub 2} in 30 vol% were compounded with polypropylene matrix. • According to the DSC measurements, the fillers are good nucleating agents. • The thermal conductivity of the fillers influences the cooling rate of the melt. • The higher the cooling rate is, the lower the crystallinity in the polymer matrix. - Abstract: Three different nano- and micro-sized ceramic powders (boron-nitride (BN), talc and titanium-dioxide (TiO{sub 2})) in 30 vol% have been compounded with a polypropylene (PP) matrix. Scanning electron microscopy (SEM) shows that the particles are dispersed smoothly in the matrix and larger aggregates cannot be discovered. The cooling gradients and the cooling rate in the injection-molded samples were estimated with numerical simulations and finite element analysis software. It was proved with differential scanning calorimetry (DSC) measurements that the cooling rate has significant influence on the crystallinity of the compounds. At a low cooling rate BN works as a nucleating agent so the crystallinity of the compound is higher than that of unfilled PP. On the other hand, at a high cooling rate, the crystallinity of the compound is lower than that of unfilled PP because of its higher thermal conductivity. The higher the thermal conductivity is, the higher the real cooling rate in the material, which influences the crystallization kinetics significantly.

  3. Thermal shock behavior of tungsten based alloys manufactured via powder injection molding

    Energy Technology Data Exchange (ETDEWEB)

    Pintsuk, G. [Forschungszentrum Juelich, EURATOM-Association, D-52425 Juelich (Germany); Blagoeva, D. Nuclear Research and Consultancy Group NRG, PO Box 25, 1755 ZG Petten (Netherlands)); Opschoor, J. [Energy research Centre of the Netherlands ECN, P.O. Box 1, 1755 ZG Petten (Netherlands)

    2013-11-15

    The focus of this work is to address mechanical strength and recrystallization resistance through thermal shock investigation of newly developed fine grained tungsten base materials (i.e., pure tungsten and two doped tungsten-grades incorporating either 1 or 5 vol%Y2O3 produced via powder injection molding (PIM)). Therefore, repetitive ELM (edge localized mode)-like loads (n = 100) were applied by means of an electron beam at various temperatures between RT and 400C (673 K) with a pulse duration of 1 ms and an absorbed power density of up to 1.13 GW/m{sup 2}. The microstructural properties, e.g. grain size, and Y2O3-particle distribution, were correlated with crack formation at a certain temperature, the crack propagation direction towards the bulk material and the amount of plastic deformation/surface roughening at higher temperatures. Thereby, it was shown that W-1 vol%Y2O3 outperformed all other investigated grades and reference materials from literature.

  4. Optimization of Micro Metal Injection Molding By Using Grey Relational Grade

    International Nuclear Information System (INIS)

    Micro metal injection molding (?MIM) which is a variant of MIM process is a promising method towards near net-shape of metallic micro components of complex geometry. In this paper, ?MIM is applied to produce 316L stainless steel micro components. Due to highly stringent characteristic of ?MIM properties, the study has been emphasized on optimization of process parameter where Taguchi method associated with Grey Relational Analysis (GRA) will be implemented as it represents novel approach towards investigation of multiple performance characteristics. Basic idea of GRA is to find a grey relational grade (GRG) which can be used for the optimization conversion from multi objectives case which are density and strength to a single objective case. After considering the form 'the larger the better', results show that the injection time(D) is the most significant followed by injection pressure(A), holding time(E), mold temperature(C) and injection temperature(B). Analysis of variance (ANOVA) is also employed to strengthen the significant of each parameter involved in this study.

  5. Fabrication of microstructures with extreme structural heights by vacuum reaction injection molding and electroforming

    International Nuclear Information System (INIS)

    Development work has resulted in a vacuum reaction injection molding (RIM) process which allows to fabricate plastic microstructures having minimum lateral dimensions in the micrometer range and structural heights of several hundred micrometers. The plastic structures generated by this method on an electrically conductive gate plate can be used directly as templates for the production of metallic microstructures through electroforming. The mold inserts for the molding tools used in the RIM process are fabricated by synchrotron radiation lithography and electroforming on an electrically conductive base plate. Particularly stable mold inserts made of one single material with extremely plane surfaces are obtained by electrodeposition of metal such that it stands by several millimeters over the resist structures generated by lithography. The mold insert produced in this way is separated from the base plate and the resist structures are subsequently removed. The molding tests were performed at a purpose developed vacuum RIM apparatus. Methacrylate base casting resins were used with an internal mold release agent added in order to reduce the adhesion of the produced part on the mold insert. By the example of fabrication of separation nozzle structures with minimum lateral dimensions of about 3 ?m and a maximum structural height of 310 ?m it has been demonstrated that molding can be performed at 100% yield and that service lives of the mold inserts can be achieved which are adequate for mass production. (orig./HP)

  6. Enteric-coating of pulsatile-release HPC capsules prepared by injection molding.

    Science.gov (United States)

    Macchi, E; Zema, L; Maroni, A; Gazzaniga, A; Felton, L A

    2015-04-01

    Capsular devices based on hydroxypropyl cellulose (Klucel® LF) intended for pulsatile release were prepared by injection molding (IM). In the present work, the possibility of exploiting such capsules for the development of colonic delivery systems based on a time-dependent approach was evaluated. For this purpose, it was necessary to demonstrate the ability of molded cores to undergo a coating process and that coated systems yield the desired performance (gastric resistance). Although no information was available on the coating of IM substrates, some issues relevant to that of commercially-available capsules are known. Thus, preliminary studies were conducted on molded disks for screening purposes prior to the spray-coating of HPC capsular cores with Eudragit® L 30 D 55. The ability of the polymeric suspension to wet the substrate, spread, start penetrating and initiate hydration/swelling, as well as to provide a gastroresistant barrier was demonstrated. The coating of prototype HPC capsules was carried out successfully, leading to coated systems with good technological properties and able to withstand the acidic medium with no need for sealing at the cap/body joint. Such systems maintained the original pulsatile release performance after dissolution of the enteric film in pH 6.8 fluid. Therefore, they appeared potentially suitable for the development of a colon delivery platform based on a time-dependent approach. PMID:25585355

  7. Chemical vapor deposition and analysis of thermally insulating ZrO2 layers on injection molds

    International Nuclear Information System (INIS)

    High quality injection molding requires a precise control of cooling rates. Thermal barrier coating (TBC) of zirconia with a thickness of 20-40 ?m on polished stainless steel molds could provide the necessary insulating effect. This paper presents results of zirconia deposition on stainless steel substrates using chemical vapor deposition (CVD) aiming to provide the process parameters for the deposition of uniform zirconia films with such a thickness. The deposition was performed with zirconium (IV) acetylacetonate (Zr(C5H7O2)4) as precursor and synthetic air as co-reactant, which allows deposition at temperatures below 600 C. The experiments were carried out in a hot-wall reactor at pressures between 7.5 mbar and 500 mbar and in a temperature range from 450 C to 600 C. Important growth parameters were characterized and growth rates between 1 and 2.5 ?m/h were achieved. Thick and well adhering zirconia layers of 38 ?m could be produced on steel within 40 h. The transient heat transfer rate upon contact with a hot surface was also evaluated experimentally with the thickest coatings. These exhibit a good TBC performance. (copyright 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  8. Thermal and mechanical behavior of injection molded Poly(3-hydroxybutyrate)/Poly(epsilon-caprolactone) blends

    Scientific Electronic Library Online (English)

    Marcia Adriana Tomaz, Duarte; Roberson Goulart, Hugen; Eduardo Sant' Anna, Martins; Ana Paula Testa, Pezzin; Sérgio Henrique, Pezzin.

    2006-03-01

    Full Text Available Aiming the development of high-performance biodegradable polymer materials, the properties and the processing behavior of poly(3-hydroxybutyrate), P(3HB), and their blends with poly(epsilon-caprolactone), PCL, have been investigated. The P(3HB) sample, obtained from sugarcane, had a molecular weight [...] of 3.0 x 10(5) g.mol¹, a crystallinity degree of 60%, a glass transition temperature (Tg), at - 0.8 °C, and a melting temperature at 171 °C. The molecular weight of PCL was 0.8 x 10(5) g.mol-1. Specimens of 70/30 wt. (%) P(3HB)/PCL blends obtained by injection molding showed tensile strength of 21.9 (± 0.4) MPa, modulus of 2.2 (± 0.3) GPa, and a relatively high elongation at break, 87 (± 20)%. DSC analyses of this blend showed two Tg´s, at - 10.6 °C for the P(3HB) matrix, and at - 62.9 °C for the PCL domains. The significant decrease on the Tg of P(3HB) evidences a partial miscibility of PCL in P(3HB). According to the Fox equation, the new Tg corresponds to a 92/8 wt. (%) P(3HB)/PCL composition.

  9. Unique opportunities in powder injection molding of refractory and hard materials

    International Nuclear Information System (INIS)

    Powder injection molding (PIM) is a relatively new manufacturing process for the creation of complicated net-shapes outside the range usually possible via powder metallurgy technologies. This new process is now in production at more than 550 sites around the world. Although a small industry, PIM will soon pass $1 billion dollars (USA) in annual sales. This presentation overviews the PIM process, some of the new developments and some of the successes that have occurred with both refractory metals and hard metals. Example applications are seen in medical and dental devices, industrial components, wristwatches, jet engines, firearms, automotive components, and even hand tools. To help establish the novel growth opportunities, PIM is compared to other fabrication routes to better understand the design features arising with this new approach, providing a compelling case for substantial opportunities in the refractory and hard materials. Illustrations are provided of several components in production. New opportunities abound for the technology, since it eliminates the shape complexity barrier associated with die compaction and the cost of machining associated with complicated or dimensionally precise components. Further, a relative cost advantage exists for refractory and hard materials because PIM can use the same powders at the same prices as employed in alternative processes. Future successes will occur by early identification of candidate materials and designs. Early examples include tungsten heavy alloy components now reaching production rates of six million per month. (author)

  10. Materials selection and manufacturing of thermoplastic elastomer microfluidics

    Science.gov (United States)

    Sameoto, D.; Wasay, A.

    2015-03-01

    In this paper we outline some of the manufacturing advantages and challenges of working with thermoplastic elastomers as an alternative to traditional polydimethysiloxane (PDMS) for flexible and reversibly bonded microfluidic systems. Unlike PDMS, thermoplastic elastomers can be processed with many industrial polymer manufacturing technologies such as extrusion, injection molding, hot embossing and others, potentially permitting much more scalable production and cheaper costs per part. Unlike a more rigid thermoplastic, these thermoplastic elastomers are typically much easier to bond, either reversibly or permanently due to their inherent compliance and subsequent low pressures necessary to seal channels and reservoirs. Unlike PDMS however, where one material (Sylgard 184) dominates the literature, there have not been many in depth investigations into thermoplastic elastomers and their relative performance and applicability to microfabrication. We show a comparison between several categories of thermoplastic elastomer to demonstrate what issues may be encountered and to demonstrate that even for labs with minimal equipment, academic prototyping with these materials is not necessarily any more challenging than PDMS.

  11. Acoustic Emission Detection of Macro-Cracks on Engraving Tool Steel Inserts during the Injection Molding Cycle Using PZT Sensors

    Directory of Open Access Journals (Sweden)

    Aleš Han?i?

    2013-05-01

    Full Text Available This paper presents an improved monitoring system for the failure detection of engraving tool steel inserts during the injection molding cycle. This system uses acoustic emission PZT sensors mounted through acoustic waveguides on the engraving insert. We were thus able to clearly distinguish the defect through measured AE signals. Two engraving tool steel inserts were tested during the production of standard test specimens, each under the same processing conditions. By closely comparing the captured AE signals on both engraving inserts during the filling and packing stages, we were able to detect the presence of macro-cracks on one engraving insert. Gabor wavelet analysis was used for closer examination of the captured AE signals’ peak amplitudes during the filling and packing stages. The obtained results revealed that such a system could be used successfully as an improved tool for monitoring the integrity of an injection molding process.

  12. Optimizing Injection Molding Processing Parameters for Enhanced Mechanical Performance of Oil Palm Empty Fruit Bunch High Density Polyethylene Composites

    Directory of Open Access Journals (Sweden)

    M.S. Ramli

    2011-01-01

    Full Text Available This study reports on the influence of injection molding processing parameters on mechanical properties of oil palm Empty Fruit Bunch (EFB filled High Density Poly Ethylene (HDPE. The biocomposite pellets were first prepared using an extruder with 20 wt% EFB content before being processed in an injection-molding machine for specimen fabrication. Two processing parameters were varied systematically and independently during the composite sample fabrication. The holding pressure was increased from 60 to 90 bars while the injection temperature was varied from 150 to 210°C. The highest tensile strength of the composites was achieved at 70 bar holding pressure and 150°C injection temperature. However, the highest fracture strength was achieved at 80 bars whilst maintaining the injection temperature at 150°C. Flexural strength was shown to be unaffected by the varying pressure. The optimal processing parameters for highest mechanical performance were found to be at holding pressure of 80 bars and injection tempera

  13. Die-sinking electrical discharge machining of a high-strength copper-based alloy for injection molds

    OpenAIRE

    F. L. Amorim; Weingaertner, W. L.

    2004-01-01

    High-strength copper alloys are used as materials for injection molding tools or as cores and inserts in steel molds because of their high thermal conductivity, corrosion and wear resistance. Unfortunately, there is little technological knowledge on the electrical discharge machining (EDM) of copper-beryllium ASTM C17200 alloy. In this work, rough and finish machining conditions were tested using copper and tungsten-copper as materials for the electrodes. Cross-sectional micrographic and hard...

  14. Experimental Analysis for Factors Affecting the Repeatability of Plastics Injection Molding Tests on the Self-developed Apparatus

    OpenAIRE

    Yuejun Liu; Yugang Huang; Duxin Li

    2013-01-01

    To improve the repeatability of the injection molding test result, the affecting factors were investigated by means of experiments. Besides the traditional processing parameter, the factors of test conditions were also considered. In order to focus on the molding process rather than the molded part, the curve measurement of the melt pressure at the entrance to the nozzle was used as the output characteristic. Experiments for polypropylene (PP) showed that the injected volume was the key proc...

  15. Single Performance Optimization of Micro Metal Injection Molding for the Highest Green Strength by Using Taguchi Method

    OpenAIRE

    M.H.I Ibrahim; N. Muhamad; A.B Sulong; K.R. Jamaludin; S. Ahmad; N.H. M. Nor

    2010-01-01

    Micro metal injection molding is drawing attention recently as one the most cost effective processes in powder metallurgy to produce small-scale intricate part and competitive cost for mass production of micro components where it is greatly influenced by injection parameter. Thus, this paper investigated the optimization of highest green strength which plays an important characteristic in determining the successful of micro MIM. Stainless steel SS 316L was used with composite binder, which co...

  16. MECHANICAL PROPERTIES OF INJECTION-MOLDED FOAMED WHEAT STRAW FILLED HDPE BIOCOMPOSITES: THE EFFECTS OF FILLER LOADING AND COUPLING AGENT CONTENTS

    OpenAIRE

    Fatih Mengeloglu; Kadir Karaku?

    2012-01-01

    This study investigated the effect of filler loading and coupling agent contents on the densities and mechanical properties of injection-molded foamed biocomposites. Biocomposite pellets were manufactured using wheat straw flour, maleic anhydrite grafted polyethylene (MAPE), paraffin wax, and high-density polyethylene (HDPE) with an extrusion process. Pellets and the chemical foaming agent (azodicarbonamide) were dry-mixed and foamed in an injection-molding machine. Densities and mechanical p...

  17. Microstructural study of duplex stainless steels obtained by powder injection molding

    Energy Technology Data Exchange (ETDEWEB)

    Sotomayor, M.E., E-mail: msotomay@ing.uc3m.es [Materials Science and Engineering Department, Carlos III University of Madrid, Avda. Universidad 30, 28911 Leganés (Spain); Kloe, R. de, E-mail: rene.de.kloe@ametek.nl [EDAX B. V., PO Box 4144, 5004 JC Tilburg (Netherlands); Levenfeld, B., E-mail: bll@ing.uc3m.es [Materials Science and Engineering Department, Carlos III University of Madrid, Avda. Universidad 30, 28911 Leganés (Spain); Várez, A., E-mail: alvar@ing.uc3m.es [Materials Science and Engineering Department, Carlos III University of Madrid, Avda. Universidad 30, 28911 Leganés (Spain)

    2014-03-15

    Highlights: • The microstructural evolution of sintered PIM duplex stainless steels was studied. • A destabilization of austenite occurs after sintering at high temperature. • Electron backscatter diffraction (EBSD) revealed a remaining of 0.5% of austenite. • Ferrite content was also determined employing a magnetic method. -- Abstract: This experimental work is focused on the study of microstructural evolution during sintering of duplex stainless steels (DSS) obtained by powder injection molding (PIM). Ferritic 430L and austenitic 316L stainless steel powders were previously premixed in a 50/50 volume ratio and afterward they were sintered in low vacuum at different temperatures for 1 h. Microstructural analysis of sintered samples was conducted by means of scanning electron microscopy (SEM) and a compositional analysis of the alloying elements along different phases was performed by energy dispersive analysis of X-rays (EDS). Phase transformations were evaluated by X-ray diffraction (XRD) experiments, and the magnetic phase content was measured with a ferritoscope. The intensity of the main austenite diffraction peak decreases as sintering temperature increases to finally disappear in the sample sintered at 1100 °C. This destabilization of the austenite is probably related to a high Nickel diffusion detected from austenite to ferrite particles. Moreover, electron backscatter diffraction (EBSD) data were collected to quantify microstructural properties. Several EBSD pattern maps were acquired in order to define the amount of austenite phase. Due to the advantages of this technique a 0.5% of austenite could be detected after sintering at 1200 °C. After sintering process, the austenite content in sintered duplex stainless steels obtained through this processing route was lower than expected. Finally, Bain mechanism was proposed as an explanation to this phase transformation takes place. EBSD technique has been proved to be the most suitable to monitor the microstructure of sintered DSS.

  18. An Approach to Rib Design of Injection Molded Product Using Finite Element and Taguchi Method

    OpenAIRE

    Tian-Syung Lan; Min-Chie Chiu; Long-Jyi Yeh

    2008-01-01

    In this study, not only Taguchi Method but also ANSYS in providing an economical and effective advance to the optimum design of the rib for a plastic injected product are introduced. The analytical model of a rectangular thermoplastic Acrylonitrile Butadiene Styrene (ABS) plastic cover with rib of given thickness (2.8 mm) was selected and constructed based on design experiences and the dimensions as well as the width of the rib were selected as the control factors for Taguchi Method. The defl...

  19. Fabrication and characterization of injection molded poly ({epsilon}-caprolactone) and poly ({epsilon}-caprolactone)/hydroxyapatite scaffolds for tissue engineering

    Energy Technology Data Exchange (ETDEWEB)

    Cui Zhixiang [Zhengzhou University, Henan (China); Nelson, Brenton; Peng, YiYan [University of Wisconsin-Madison, Wisconsin (United States); Li Ke [South China University of Technology, Guangzhou (China); Pilla, Srikanth; Li Wanju [University of Wisconsin-Madison, Wisconsin (United States); Turng, Lih-Sheng, E-mail: turng@engr.wisc.edu [University of Wisconsin-Madison, Wisconsin (United States); South China University of Technology, Guangzhou (China); Huazhong University of Science of Technology, Wuhan (China); Shen Changyu, E-mail: shency@zzu.edu.cn [Zhengzhou University, Henan (China)

    2012-08-01

    In this study, poly({epsilon}-caprolactone) (PCL)/sodium chloride (NaCl), PCL/poly(ethylene oxide) (PEO)/NaCl and PCL/PEO/NaCl/hydroxyapatite (HA) composites were injection molded and characterized. The water soluble and sacrificial polymer, PEO, and NaCl particulates in the composites were leached by deionized water to produce porous and interconnected microstructures. The effect of leaching time on porosity, and residual contents of NaCl and NaCl/HA, as well as the effect of HA addition on mechanical properties was investigated. In addition, the biocompatibility was observed via seeding human mesenchymal stem cells (hMSCs) on PCL and PCL/HA scaffolds. The results showed that the leaching time depends on the spatial distribution of sacrificial PEO phase and NaCl particulates. The addition of HA has significantly improved the elastic (E Prime ) and loss moduli (E Double-Prime ) of PCL/HA scaffolds. Human MSCs were observed to have attached and proliferated on both PCL and PCL/HA scaffolds. Taken together, the molded PCL and PCL/HA scaffolds could be good candidates as tissue engineering scaffolds. Additionally, injection molding would be a potential and high throughput technology to fabricate tissue scaffolds. - Highlights: Black-Right-Pointing-Pointer PCL/NaCl, PCL/PEO/NaCl and PCL/PEO/NaCl/HA composites were injection molded. Black-Right-Pointing-Pointer Leaching time depends on the distribution of PEO phase and NaCl particulates. Black-Right-Pointing-Pointer The elastic and loss moduli of PCL/HA scaffolds have significantly improved. Black-Right-Pointing-Pointer Human hMSCs have attached, survived and proliferated well on PCL and PCL/HA scaffolds. Black-Right-Pointing-Pointer Molded PCL and PCL/HA scaffolds could be good candidates for tissue engineering.

  20. Fabrication and characterization of injection molded poly (?-caprolactone) and poly (?-caprolactone)/hydroxyapatite scaffolds for tissue engineering

    International Nuclear Information System (INIS)

    In this study, poly(?-caprolactone) (PCL)/sodium chloride (NaCl), PCL/poly(ethylene oxide) (PEO)/NaCl and PCL/PEO/NaCl/hydroxyapatite (HA) composites were injection molded and characterized. The water soluble and sacrificial polymer, PEO, and NaCl particulates in the composites were leached by deionized water to produce porous and interconnected microstructures. The effect of leaching time on porosity, and residual contents of NaCl and NaCl/HA, as well as the effect of HA addition on mechanical properties was investigated. In addition, the biocompatibility was observed via seeding human mesenchymal stem cells (hMSCs) on PCL and PCL/HA scaffolds. The results showed that the leaching time depends on the spatial distribution of sacrificial PEO phase and NaCl particulates. The addition of HA has significantly improved the elastic (E?) and loss moduli (E?) of PCL/HA scaffolds. Human MSCs were observed to have attached and proliferated on both PCL and PCL/HA scaffolds. Taken together, the molded PCL and PCL/HA scaffolds could be good candidates as tissue engineering scaffolds. Additionally, injection molding would be a potential and high throughput technology to fabricate tissue scaffolds. - Highlights: ?PCL/NaCl, PCL/PEO/NaCl and PCL/PEO/NaCl/HA composites were injection molded. ?Leaching time depends on the distribution of PEO phase and NaCl particulates. ?The elastic and loss moduli of PCL/HA scaffolds have significantly improved. ?Human hMSCs have attached, survived and proliferated well on PCL and PCL/HA scaffolds. ?Molded PCL and PCL/HA scaffolds could be good candidates for tissue engineering.

  1. Investigating the Influence of Different Process Parameters on Shrinkage of Injection-Molded Parts

    Directory of Open Access Journals (Sweden)

    A. R. Jafarian

    2005-01-01

    Full Text Available Different models have been proposed to investigate the effects of various process parameters on shrinkage of plastic parts, which in most cases the effect of each parameter is obtained by changing one factor at a time. In this research, a simple flat model has been used and a simulation code has been developed. Then, through this simulation code, the effects of different process parameters have been investigated. This code was run for a typical thermoplastic (polycarbonate and finally, a Design Of Experiments (DOE approach was used to study the effects of multiple variables on shrinkage simultaneously.

  2. Application of Rapid Prototyping and Wire Arc Spray to the Fabrication of Injection Mold Tools (MSFC Center Director's Discretionary Fund)

    Science.gov (United States)

    Cooper, K. G.

    2000-01-01

    Rapid prototyping (RP) is a layer-by-layer-based additive manufacturing process for constructing three-dimensional representations of a computer design from a wax, plastic, or similar material. Wire arc spray (WAS) is a metal spray forming technique, which deposits thin layers of metal onto a substrate or pattern. Marshall Space Flight Center currently has both capabilities in-house, and this project proposed merging the two processes into an innovative manufacturing technique, in which intermediate injection molding tool halves were to be fabricated with RP and WAS metal forming.

  3. Low Speed Technology for Small Turbine Development Reaction Injection Molded 7.5 Meter Wind Turbine Blade

    Energy Technology Data Exchange (ETDEWEB)

    David M. Wright; DOE Project Officer - Keith Bennett

    2007-07-31

    An optimized small turbine blade (7.5m radius) was designed and a partial section molded with the RIM (reaction-injection molded polymer) process for mass production. The intended market is for generic three-bladed wind turbines, 100 kilowatts or less, for grid-assist end users with rural and semi-rural sites, such as the farm/ranch market, having low to moderate IEC Class 3-4 wind regimes. This blade will have substantial performance improvements over, and be cheaper than, present-day 7.5m blades. This is made possible by the injection-molding process, which yields high repeatability, accurate geometry and weights, and low cost in production quantities. No wind turbine blade in the 7.5m or greater size has used this process. The blade design chosen uses a RIM skin bonded to a braided infused carbon fiber/epoxy spar. This approach is attractive to present users of wind turbine blades in the 5-10m sizes. These include rebladeing California wind farms, refurbishing used turbines for the Midwest farm market, and other manufacturers introducing new turbines in this size range.

  4. Die-sinking electrical discharge machining of a high-strength copper-based alloy for injection molds

    Scientific Electronic Library Online (English)

    F. L., Amorim; W. L., Weingaertner.

    2004-06-01

    Full Text Available High-strength copper alloys are used as materials for injection molding tools or as cores and inserts in steel molds because of their high thermal conductivity, corrosion and wear resistance. Unfortunately, there is little technological knowledge on the electrical discharge machining (EDM) of copper [...] -beryllium ASTM C17200 alloy. In this work, rough and finish machining conditions were tested using copper and tungsten-copper as materials for the electrodes. Cross-sectional micrographic and hardness examinations as well as surface roughness measurements were also carried out on workpieces after machining in order to study the thermally affected zones. Appropriate parameters settings for EDM of the investigated alloy are suggested.

  5. A Fully Coupled Simulation and Optimization Scheme for the Design of 3D Powder Injection Molding Processes

    International Nuclear Information System (INIS)

    The paper is concerned with optimization and parametric identification of Powder Injection Molding process that consists first in injection of powder mixture with polymer binder and then to the sintering of the resulting powders parts by solid state diffusion. In the first part, one describes an original methodology to optimize the injection stage based on the combination of Design Of Experiments and an adaptive Response Surface Modeling. Then the second part of the paper describes the identification strategy that one proposes for the sintering stage, using the identification of sintering parameters from dilatometer curves followed by the optimization of the sintering process. The proposed approaches are applied to the optimization for manufacturing of a ceramic femoral implant. One demonstrates that the proposed approach give satisfactory results

  6. Effect of injection molded micro-structured polystyrene surfaces on proliferation of MC3T3-E1 cells

    Directory of Open Access Journals (Sweden)

    G. Lucchetta

    2015-04-01

    Full Text Available In this work, osteoinductive micro-pillared polystyrene surfaces were mass-produced for bone replacement applications, by means of the micro injection molding process. Firstly, the molding process parameters were optimized with a two-level, three-factor central composite face-centered plan to increase the quality of polystyrene micro pillars replication and to maximize the pillars height uniformity over the molded part. Secondly, osteoblastic MC3T3-E1 cells adhesion and proliferation on the replicated substrates were assessed as a function of micro topography parameters, such as pillars diameter, aspect ratio and spacing. Cell morphology and proliferation were evaluated through MTS test after 1, 3 and 7 days from seeding. The experimental results showed that cells adhesion and proliferation is more positively promoted on micro-pillared surfaces compared to flat surfaces, but no correlations were observed between cell proliferation and pillar diameter and spacing.

  7. Influence of different process settings conditions on the accuracy of micro injection molding simulations: an experimental validation

    DEFF Research Database (Denmark)

    Tosello, Guido; Gava, Alberto

    2009-01-01

    Currently available software packages exhibit poor results accuracy when performing micro injection molding (µIM) simulations. However, with an appropriate set-up of the processing conditions, the quality of results can be improved. The effects on the simulation results of different and alternative process conditions are investigated, namely the nominal injection speed, as well as the cavity filling time and the evolution of the cavity injection pressure as experimental data. In addition, the sensitivity of the results to the quality of the rheological data is analyzed. Simulated results are compared with experiments in terms of flow front position at part and micro features levels, as well as cavity injection filling time measurements.

  8. DNA barcoding via counterstaining with AT/GC sensitive ligands in injection-molded all-polymer nanochannel devices

    DEFF Research Database (Denmark)

    Østergaard, Peter Friis; Matteucci, Marco

    2013-01-01

    Nanochannel technology, coupled with a suitable DNA labeling chemistry, is a powerful approach for performing high-throughput single-molecule mapping of genomes. Yet so far nanochannel technology has remained inaccessible to the broader research community due to high fabrication cost and/or requirement of specialized facilities/skill-sets. In this article we show that nanochannel-based mapping can be performed in all polymer chips fabricated via injection molding: a fabrication process so inexpensive that the devices can be considered disposable. Fluorescent intensity variations can be obtained from molecules extended in the polymer nanochannels via chemical counterstaining against YOYO-1. In particular, we demonstrate that the counterstaining induced fluorescent intensity variations to a large degree appear to be proportional to the theoretically computed sequence-maps of both local AT and GC variation along DNA sequences.

  9. Shear controlled alignment of short carbon fibers in copper matrix composite green samples produced by powder injection molding

    Science.gov (United States)

    Shirazi, Irfan; Ahmad, Faiz; Raza, M. Rafi; Muhsan, Ali. S.; Aslam, M.

    2015-07-01

    The tensile properties of short fiber reinforced composites are enhanced if fiber alignment in the load direction is achieved. Powder injection molding provides partial alignment of fibers in molded parts and shows a skin-core effect. The objective of this study was to align fibers completely in flow direction and reducing skin-core effect in green samples. This objective was achieved by changing the type of flow during molding by changing sprue geometry in a way that diverging flow is developed in it. This diverging flow was converted to converging flow when feedstock entered mold cavity and generated shear to align fibers. This sprue modification was helpful in aligning short fibers in flow direction and eliminating skin-core effect.

  10. Solidification behavior of high-density polyethylene (HDPE) during injection molding: Correlation between crystallization kinetics and thermal gradient field

    Science.gov (United States)

    Yang, Bin; Deng, Yan-Li; Li, Gui-Jing; Miao, Ji-Bin; Xia, Ru; Qian, Jia-Sheng; Chen, Peng; Liu, Jing-Wang

    2015-07-01

    This work mainly investigated the effect of thermal field on the crystallization kinetics of high-density polyethylene (HDPE) during injection molding (IM) process. The thickness X = 0.4 was found to be a crucial location heavily influenced by thermal conduction. The temperature decay tended to be stable, with limited variation of the crystallization rate when X > 0.4. It was observed that the crystallization rate was in good proportion to the cooling rate (?). Our experimental finding showed that the consequence of relative crystallinity (?) was in agreement with that of the secondary temperature difference (STD). This study is practically significant to the further investigation on the relationship among “processing-structure-property” of polymeric materials.

  11. Effect of low doses beta irradiation on micromechanical properties of surface layer of injection molded polypropylene composite

    Science.gov (United States)

    Manas, David; Manas, Miroslav; Gajzlerova, Lenka; Ovsik, Martin; Kratky, Petr; Senkerik, Vojt?ch; Skrobak, Adam; Danek, Michal; Manas, Martin

    2015-09-01

    The influence of beta radiation on the changes in the structure and selected properties (mechanical and thermal) was proved. Using low doses of beta radiation for 25% glass fiber filled polypropylene and its influence on the changes of micromechanical properties of surface layer has not been studied in detail so far. The specimens of 25% glass fiber filled PP were made by injection molding technology and irradiated by low doses of beta radiation (0, 15 and 33 kGy). The changes in the microstructure and micromechanical properties of surface layer were evaluated using FTIR, SEM, WAXS and instrumented microhardness test. The results of the measurements showed considerable increase in micromechanical properties (indentation hardness, indentation elastic modulus) when low doses of beta radiation are used.

  12. Effect of the coupling agent on the properties of NdFeB injection molding magnets (abstract)

    Science.gov (United States)

    Chen, L. K.; Hung, Y. C.; Ko, W. S.

    1991-04-01

    In the manufacturing of injection molded magnets made from NdFeB (MQ) powder and nylon-12, coupling agents are normally added to prevent NdFeB powders from oxidation in the period of injection processes. The reheological behavior of NdFeB pellets related to the quantities and kinds of coupling agents. The effects of coupling agents on the NdFeB injection molded magnets are seldom presented in literature1 and will be the sub-seldom presented in the literature1 and will be the subject of this work. Five coupling agents (two belong to silane series, two belong to titanate series, and one belongs to the zircoaluminate series) have been investigated and evaluated. Differential scanning calorimetry (DSC) data show that 0.5 wt. % of isopropyle tri(dioctyl)-pyrophosphate titanate has the best result for oxidation resistance. On the other hand, the compression strength and reheological behavior of the bonded magnets are dependent on the kinds of coupling agents. The zircoaluminate coupling agent induces 30% enhancement of compression strength better than other coupling agents. Titanate coupling agents have a lower injection temperature. It demonstrated that the titanate coupling agent can effectively reduce the relative viscosity of the compounds. In the meantime, we did a 100-h environmental test at 80 °C, 90% RH. Experimental results also show that the titanate coupling agents have best anticorrosion ability. Magnetic properties of bonded magnet Br=5.7 kG, Hc=4.5 kOe, iHc=8.4 kOe, and (BH)max=6.7 mGOe can be obtained. Results suggested the titanate coupling agent is the best choice in this study.

  13. Injection Molding of Titanium Alloy Implant For Biomedical Application Using Novel Binder System Based on Palm Oil Derivatives

    Directory of Open Access Journals (Sweden)

    R. Ibrahim

    2010-01-01

    Full Text Available Problem statement: Titanium alloy (Ti6Al4V has been widely used as an implant for biomedical application. In this study, the implant had been fabricated using high technology of Powder Injection Molding (PIM process due to the cost effective technique for producing small, complex and precision parts in high volume compared with conventional method through machining. Approach: Through PIM, the binder system is one of the most important criteria in order to successfully fabricate the implants. Even though, the binder system is a temporary, but failure in the selection and removal of the binder system will affect on the final properties of the sintered parts. Therefore, the binder system based on palm oil derivative which is palm stearin had been formulated and developed to replace the conventional binder system. Results: The rheological studies of the mixture between the powder and binders system had been determined properly in order to be successful during injection into injection molding machine. After molding, the binder held the particles in place. The binder system had to be removed completely through debinding step. During debinding step, solvent debinding and thermal pyrolysis had been used to remove completely of the binder system. The debound part was then sintered to give the required physical and mechanical properties. The in vitro biocompatibility also was tested using Neutral Red (NR and mouse fibroblast cell lines L-929 for the direct contact assay. Conclusion: The results showed that the properties of the final sintered parts fulfill the Standard Metal Powder Industries Federation (MPIF 35 for PIM parts except for tensile strength and elongation due to the formation of titanium carbide. The in vitro biocompatibility on the extraction using mouse fibroblast cell line L-929 by means of NR assays showed non toxic for the sintered specimen titanium alloy parts.

  14. Drying Thermoplastics

    Science.gov (United States)

    1976-01-01

    In searching for an improved method of removing water from polyester type resins without damaging the materials, Conair Inc. turned to the NASA Center at the University of Pittsburgh for assistance. Taking an organized, thorough look at existing technology before beginning research has helped many companies save significant time and money. They searched the NASA and other computerized files for microwave drying of thermoplastics. About 300 relevant citations were retrieved - eight of which were identified as directly applicable to the problem. Company estimates it saved a minimum of a full year in compiling research results assembled by the information center.

  15. Nonlinear rheology and strain recovery of short chain branched polyolefin elastomers and thermoplastic olefin blends

    Science.gov (United States)

    Patham, Bhaskar

    Polyolefin elastomers are random copolymers having a polyethylene backbone with the higher olefinic comonomer incorporated as short-chain branches. These random copolymers are widely used as polymer modifiers for thermoplastic materials such as polypropylenes, resulting in thermoplastic olefin (TPO) blends. This thesis addresses the nonlinear rheological behavior of the elastomers and then of the TPO blends. The effects of varying short chain branch density (SCB) on the melt rheology of three ethylene-octene random copolymers have been investigated. In particular, the strain-hardening behavior in extensional flow and strain recovery following nonlinear shear creep has been evaluated. The zero-shear viscosity followed trends in the backbone molecular weight closely. While the three copolymers were indistinguishable in linear viscoelastic creep and recovery, recovery following nonlinear shear creep decreased progressively with increasing SCB density. This reveals that the extent of rapid chain equilibration that occurs over Rouse time scales at higher strains was progressively lower with increasing SCB density. Strain hardening in uniaxial extensional flow was observed for all three copolymers. At strain rates below the primitive chain equilibration rates, strain hardening increases progressively with increasing SCB density. At higher rates, upon onset of primitive chain stretch, the strain hardening behavior for the three melts merges. Two thermoplastic olefin (TPO) blends were characterized in the context of injection molding; the surface morphology of injection molded tensile bars with these materials showed surface defects or flow marks to different extents. The flow marks were traced to different degrees of strain recovery in the dispersed phases of the two blends. This recovery occurred over injection molding timescales of the order of a few seconds. Strain recovery after shear creep was higher in the blend that displayed more severe flow marks in injection molding; the corresponding elastomer by itself also showed a greater extent of creep recovery. The quick strain recovery in the elastomer must be associated with elastic stresses rather than interfacial tension. A new experimental apparatus was assembled to study strain recovery after elongation of a model elastomer suspended in a less viscoelastic medium at room temperature. Small drops of well-characterized elastomers suspended in a matrix fluid of lower viscosity and elasticity, are stretched rapidly without wall effects in this setup; the stretch ratio of the drops is then recorded over time. Preliminary results confirm significant recovery over a few seconds. Exploration of the full range of parameters with this setup is left for future work.

  16. Polyethylene ionomer-based nano-composite foams prepared by a batch process and MuCell injection molding

    International Nuclear Information System (INIS)

    To understand the correlation between foamability and melt rheology of polyethylene-based ionomers having different degrees of the neutralization and corresponding nano-composites, we have conducted the foam processing via a batch process in an autoclave and microcellular foam injection molding (FIM) process using the MuCell technology. We have discussed the obtainable morphological properties in both foaming processes. All cellular structures were investigated by using field emission scanning electron microscopy. The competitive phenomenon between the cell nucleation and the cell growth including the coalescence of cell was discussed in light of the interfacial energy and the relaxation rate as revealed by the modified classical nucleation theory and rheological measurement, respectively. The FIM process led to the opposite behavior in the cell growth and coalescence of cell as compared with that of the batch process, where the ionic cross-linked structure has significant contribution to retard the cell growth and coalescence of cell. The mechanical properties of the structural foams obtained by FIM process were discussed.

  17. 2:17-type SmCo magnets prepared by powder injection molding using a water-based binder

    Science.gov (United States)

    Tian, Jianjun; Tao, Siwu; Qu, Xuanhui; Zhang, Shengen

    2:17-type SmCo permanent magnets by powder injection molding using a water-based binder have been studied. The water-based binder is methylcellulose solution, which consists of deionized water and methylcellulose. When the solution concentration is 0.5 wt%, the carbon content of the sintered magnets is below 0.1 wt% and the magnets have better magnetic properties. The magnetic properties and density of the sintered magnets can be increased through pre-sintering in vacuum (10 -3 Pa) at 1200 °C. However, the Sm content of the magnets loses obviously in pre-sintering for a long period. The appropriate pre-sintering duration is 20-40 min. The magnetic properties of the magnets are: Br=0.97 T, Hcj=871 kA/m, BH max=157 kJ/m 3. The structure of the magnet consists of the matrix phases (2:17 phases) and the precipitate phases (1:5 phases).

  18. 2:17-type SmCo magnets prepared by powder injection molding using a water-based binder

    Energy Technology Data Exchange (ETDEWEB)

    Tian Jianjun [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); State Key Laboratory for Advanced Metals and Materials, Beijing 100083 (China)], E-mail: tianjianjun@mater.ustb.edu.cn; Tao Siwu [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Qu Xuanhui [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); State Key Laboratory for Advanced Metals and Materials, Beijing 100083 (China); Zhang Shengen [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China)

    2008-09-15

    2:17-type SmCo permanent magnets by powder injection molding using a water-based binder have been studied. The water-based binder is methylcellulose solution, which consists of deionized water and methylcellulose. When the solution concentration is 0.5 wt%, the carbon content of the sintered magnets is below 0.1 wt% and the magnets have better magnetic properties. The magnetic properties and density of the sintered magnets can be increased through pre-sintering in vacuum (10{sup -3} Pa) at 1200 deg. C. However, the Sm content of the magnets loses obviously in pre-sintering for a long period. The appropriate pre-sintering duration is 20-40 min. The magnetic properties of the magnets are: Br=0.97 T, H{sub cj}=871 kA/m, BH{sub max}=157 kJ/m{sup 3}. The structure of the magnet consists of the matrix phases (2:17 phases) and the precipitate phases (1:5 phases)

  19. 2:17-type SmCo magnets prepared by powder injection molding using a water-based binder

    International Nuclear Information System (INIS)

    2:17-type SmCo permanent magnets by powder injection molding using a water-based binder have been studied. The water-based binder is methylcellulose solution, which consists of deionized water and methylcellulose. When the solution concentration is 0.5 wt%, the carbon content of the sintered magnets is below 0.1 wt% and the magnets have better magnetic properties. The magnetic properties and density of the sintered magnets can be increased through pre-sintering in vacuum (10-3 Pa) at 1200 deg. C. However, the Sm content of the magnets loses obviously in pre-sintering for a long period. The appropriate pre-sintering duration is 20-40 min. The magnetic properties of the magnets are: Br=0.97 T, Hcj=871 kA/m, BHmax=157 kJ/m3. The structure of the magnet consists of the matrix phases (2:17 phases) and the precipitate phases (1:5 phases)

  20. AKUMULASI LISTRIK STATIS PADA GELAS PLASTIK PRODUKSI MESIN INJECTION MOLDING: PENGARUH KELEMBABAN UDARA, TEMPERATUR, DAN BAHAN ADITIF

    Directory of Open Access Journals (Sweden)

    Ratnawati Ratnawati

    2014-12-01

    Full Text Available Akumulasi listrik statis pada gelas polipropilena hasil produksi mesin injection molding dapat menyebabkan gelas memiliki gaya elektrostatik dan tidak dapat turun secara gravitasi. Masalah ini menghambat aplikasi gelas pada mesin pengisian air minum dalam kemasan (AMDK. Penelitian ini bertujuan untuk mengetahui pengaruh kelembaban udara, temperatur, dan penambahan bahan aditif TiO2 terhadap potensial listrik permukaan gelas polipropilena. Hasil penelitian menunjukkan bahwa potensial listrik permukaan dipengaruhi oleh kelembaban udara ruang produksi, temperatur, dan penambahan TiO2. Potensial listrik permukaan semakin kecil dengan naiknya kelembaban udara. Setelah kelembaban mencapai 68% potensial listrik permukaan cenderung konstan. Ditinjau dari beda potensial (DV antara permukaan dua gelas, kelembaban optimum adalah 67-68%, yang ditandai dengan beda potensial yang paling rendah. Beda potensial ? 5,2 kV menyebabkan gelas cepat turun, beda potensial 5,2 kV < DV ? 6,7 kV menyebabkan gelas turun dengan lambat, dan DV ? 6,7 kV menyebabkan gelas sangat lambat turun atau menempel. Potensial listrik turun dengan naiknya temperatur. Potensial listrik statis permukaan hanya sedikit turun akibat penambahan 0,75% berat TiO2. Hasil penelitian ini juga menunjukkan bahwa penggunaan gelas dengan potensial listrik permukaan rendah dapat menaikkan kecepatan mesin pengisian AMDK menjadi 220-250 rpm dan 140-160 rpm, masing-masing untuk mesin pengisian gelas 180 ml dan 225 ml.

  1. Single Performance Optimization of Micro Metal Injection Molding for the Highest Green Strength by Using Taguchi Method

    Directory of Open Access Journals (Sweden)

    M.H.I Ibrahim

    2010-06-01

    Full Text Available Micro metal injection molding is drawing attention recently as one the most cost effective processes in powder metallurgy to produce small-scale intricate part and competitive cost for mass production of micro components where it is greatly influenced by injection parameter. Thus, this paper investigated the optimization of highest green strength which plays an important characteristic in determining the successful of micro MIM. Stainless steel SS 316L was used with composite binder, which consists of PEG and PMMA while SA works as a surfactant. Feedstock with 61.5% with several injection parameters were optimized which highly significant through screening experiment such as injection pressure(A, injection temperature(B, mold temperature(C, injection time(D and holding time(E. Besides that, interaction effects between injection pressure, injection temperature and mold temperature were also considered to optimize in the Taguchi’s orthogonal array. Analysis of variance (ANOVA in terms of signal-to-noise ratio (S/N-larger is better for green strength was also presented in this paper. Result shows that interaction between injection temperature and mold temperature (BxC give highest significant factor followed by interaction between injection pressure and injection temperature (AxB. Single factor that also contributes to significant optimization are mold temperature(C, injection time (D and injection pressure (A. Overall, this study shows that Taguchi method would be among the best method to solve the problem with minimum number of trials.

  2. Polyethylene ionomer-based nano-composite foams prepared by a batch process and MuCell injection molding

    Energy Technology Data Exchange (ETDEWEB)

    Hayashi, Hidetomo; Mori, Tomoki [Advanced Polymeric Nanostructured Materials Engineering, Graduate School of Engineering, Toyota Technological Institute, Hisakata 2-12-1, Tempaku, Nagoya 468-8511 (Japan); Okamoto, Masami, E-mail: okamoto@toyota-ti.ac.jp [Advanced Polymeric Nanostructured Materials Engineering, Graduate School of Engineering, Toyota Technological Institute, Hisakata 2-12-1, Tempaku, Nagoya 468-8511 (Japan); Yamasaki, Satoshi; Hayami, Hiroshi [Polymer Materials Technology R and D Department Electronics and Materials R and D Laboratories, Sumitomo Electric Industries, Ltd., Shimaya, Konohana-ku, 1-1-3, Osaka, 554-0024 (Japan)

    2010-01-01

    To understand the correlation between foamability and melt rheology of polyethylene-based ionomers having different degrees of the neutralization and corresponding nano-composites, we have conducted the foam processing via a batch process in an autoclave and microcellular foam injection molding (FIM) process using the MuCell technology. We have discussed the obtainable morphological properties in both foaming processes. All cellular structures were investigated by using field emission scanning electron microscopy. The competitive phenomenon between the cell nucleation and the cell growth including the coalescence of cell was discussed in light of the interfacial energy and the relaxation rate as revealed by the modified classical nucleation theory and rheological measurement, respectively. The FIM process led to the opposite behavior in the cell growth and coalescence of cell as compared with that of the batch process, where the ionic cross-linked structure has significant contribution to retard the cell growth and coalescence of cell. The mechanical properties of the structural foams obtained by FIM process were discussed.

  3. Mechanical and thermal properties of conventional and microcellular injection molded poly (lactic acid)/poly (?-caprolactone) blends.

    Science.gov (United States)

    Zhao, Haibin; Zhao, Guoqun

    2016-01-01

    In view of their complementary properties, blending polylactide (PLA) with poly (?-caprolactone) (PCL) becomes a good choice to improve PLA's properties without compromising its biodegradability. A series of blends of biodegradable PLA and PCL with different mass fraction were prepared by melt mixing. Standard tensile bars were produced by both conventional and microcellular injection molding to study their mechanical and thermal properties. With the increase in PCL content, the blend showed decreased tensile strength and modulus; however, elongation was dramatically increased. With the addition of PCL, the failure mode changed from brittle fracture of the neat PLA to ductile fracture of the blend as demonstrated by tensile test. Various theoretical models based on dispersion and interface adhesion were used to predict the Young's modulus and the results shows the experimental data are consistent with the predictions of the foam model and Kerner-Uemura-Takayangi model. The thermal behavior of the blends was investigated by DSC and TGA. The melting temperature and the degree of crystallinity of PCL in the PLA/PCL did not significantly change with the PCL content increasing in the whole range of blends composition. PMID:26313249

  4. Effect of Zr, Nb and Ti addition on injection molded 316L stainless steel for bio-applications: Mechanical, electrochemical and biocompatibility properties.

    Science.gov (United States)

    Gulsoy, H Ozkan; Pazarlioglu, Serdar; Gulsoy, Nagihan; Gundede, Busra; Mutlu, Ozal

    2015-11-01

    The research investigated the effect of Zr, Nb and Ti additions on mechanical, electrochemical properties and biocompatibility of injection molded 316L stainless steel. Addition of elemental powder is promoted to get high performance of sintered 316L stainless steels. The amount of additive powder plays a role in determining the sintered microstructure and all properties. In this study, 316L stainless steel powders used with the elemental Zr, Nb and Ti powders. A feedstock containing 62.5wt% powders loading was molded at different injection molded temperature. The binders were completely removed from molded components by solvent and thermal debinding at different temperatures. The debinded samples were sintered at 1350°C for 60min. Mechanical, electrochemical property and biocompatibility of the sintered samples were performed mechanical, electrochemical, SBF immersion tests and cell culture experiments. Results of study showed that sintered 316L and 316L with additives samples exhibited high corrosion properties and biocompatibility in a physiological environment. PMID:26275484

  5. Injection Molding Parameter Optimization of Titanium Alloy Powder Mix with Palm Stearin and Polyethylene for Multiple Performance Using Grey Relational Analysis

    Directory of Open Access Journals (Sweden)

    K.R. Jamaludin

    2011-01-01

    Full Text Available This paper outlines the optimization the process of injection molding parameters for feedstock of titanium alloy powder and palm stearin binder using grey relational analysis method. A Grey Relational Grade (GRG obtained from the Grey Relational Analysis (GRA is used to solve the injection molding operations with the multiple performance characteristic. The L27 (313 of orthogonal array of Taguchi method were performed. Defects, strength and density are important characteristics in determine the quality of the green part. Using these characteristics, the injection pressure, injection temperature, powder loading, mold temperature, holding pressure and injection speed are optimized in the study. From the analysis of variance (ANOVA, the injection temperature has the highest contribution to the quality of green part followed by injection pressure, powder loading, mold temperature, injection rate and holding pressure.

  6. A method for manufacturing a tool part for an injection molding process, a hot embossing process, a nano-imprint process, or an extrusion process

    DEFF Research Database (Denmark)

    The present invention relates to a method for manufacturing a tool part for an injection molding process, a hot embossing process, nano-imprint process or an extrusion process. First, there is provided a master structure (10) with a surface area comprising nanometre-sized protrusions (11) with a minimum density of approximately 105 protrusions/mm2, the protrusions being positioned in a non- periodic, irregular pattern, said protrusions being created by a process comprising alternating passivatio...

  7. MECHANICAL PROPERTIES OF INJECTION-MOLDED FOAMED WHEAT STRAW FILLED HDPE BIOCOMPOSITES: THE EFFECTS OF FILLER LOADING AND COUPLING AGENT CONTENTS

    Directory of Open Access Journals (Sweden)

    Fatih Mengeloglu,

    2012-06-01

    Full Text Available This study investigated the effect of filler loading and coupling agent contents on the densities and mechanical properties of injection-molded foamed biocomposites. Biocomposite pellets were manufactured using wheat straw flour, maleic anhydrite grafted polyethylene (MAPE, paraffin wax, and high-density polyethylene (HDPE with an extrusion process. Pellets and the chemical foaming agent (azodicarbonamide were dry-mixed and foamed in an injection-molding machine. Densities and mechanical properties of the foamed biocomposites samples were measured and analyzed using central composite design (CCD. The results showed that both filler loading and coupling agent contents affected the density and mechanical properties of foamed biocomposites. Densities in the range of 0.57 to 0.81 gr cm-3 were achieved. Best results were obtained when less than 20% wheat straw flour and 1% coupling agent content were used. The flexural modulus and tensile modulus of foamed biocomposites were improved with increasing filler loading. However, flexural strength, tensile strength, elongation at break, and impact strength values were diminished. The tensile strength of the biocomposites was positively affected by CA contents, but other mechanical properties were not affected by it. Overall, injection molded foamed biocomposites with moderate mechanical properties were produced.

  8. Constante de mola de molas cerâmicas injetadas a baixa pressão / Spring constant of low-pressure injection molded ceramic springs

    Scientific Electronic Library Online (English)

    R. A., Barbieri; J. E., Zorzi.

    2011-12-01

    Full Text Available A dificuldade de usinagem de peças cerâmicas já sinterizadas é muito grande, principalmente devido à dureza e fragilidade destes materiais, o que implica em altos custos de produção. Por isso, grandes esforços tem sido feitos no sentido de melhorar os processos de conformação a verde existentes, ou [...] criar novos processos que permitam a obtenção de peças cada vez mais próximas do formato final desejado. Produzir peças cerâmicas com formatos complexos, livres de defeitos, é uma tarefa que implica em grandes dificuldades. Molas cerâmicas possuem formatos extremamente difíceis de serem moldados e, conseqüentemente, atualmente são produzidas comercialmente molas cerâmicas pelo processo de usinagem, geralmente a um custo elevado. Uma alternativa para a produção de molas cerâmicas é a moldagem por injeção em baixa pressão. Para o desenvolvimento de molas cerâmicas para aplicações tecnológicas, é necessário, além de obter peças íntegras e livres de defeitos, aferir algumas de suas propriedades, como a constante de mola. Uma vez que estas molas encontram aplicação em altas temperaturas, torna-se imprescindível realizar a medida da resistência imposta pela mola à deformação elástica em diferentes temperaturas. Para tanto, este trabalho propõem a montagem de um sistema para a medição da constante de mola de molas cerâmicas injetadas a baixa pressão, tanto à temperatura ambiente como em altas temperaturas, usando o método dinâmico da excitação por impulso para medir a frequência de vibração da mola suspensa no interior de um forno. Para ilustrar a aplicação desta técnica são apresentados resultados obtidos para uma mola helicoidal de alumina, da temperatura ambiente até 1100 ºC. Abstract in english The machining of sintered ceramic parts is a difficult process, mainly due to the hardness and brittleness of these materials, which implies in high production costs. Therefore, great efforts have been made to improve the forming processes of green ceramics, or create new processes to obtain the nea [...] r net shape parts. The production of ceramic parts with complex shapes, free of defects, is a task that involves great difficulties. Ceramic springs exhibits shapes extremely difficult to be molded and therefore are currently commercially produced mainly by machining, a process which is difficult and expensive. An alternative for the production of ceramic springs is by low-pressure injection molding. For the development of ceramic springs for technological applications, it is required in addition to getting parts intact and free of defects, to measure some of its properties, including the spring constant. Since these springs are usually applied at high temperatures, it becomes important to carry out the measurement of resistance imposed by the spring to elastic deformation at different temperatures. Accordingly, in this work we describe the assembly of an experiment for the measurement of the spring constant of low-pressure injection molded ceramic springs, both at ambient temperature and at high temperatures, using the dynamic impulse excitation method to measure the frequency of vibration of a suspended spring inside a furnace. Results are presented for a helical spring of alumina from room temperature to1100 ºC to illustrate the application of this technique.

  9. Creating Drug Solubilization Compartments via Phase Separation in Multicomponent Buccal Patches Prepared by Direct Hot Melt Extrusion-Injection Molding.

    Science.gov (United States)

    Alhijjaj, Muqdad; Bouman, Jacob; Wellner, Nikolaus; Belton, Peter; Qi, Sheng

    2015-12-01

    Creating in situ phase separation in solid dispersion based formulations to allow enhanced functionality of the dosage form, such as improving dissolution of poorly soluble model drug as well as being mucoadhesive, can significantly maximize the in vitro and in vivo performance of the dosage form. This formulation strategy can benefit a wide range of solid dosage forms for oral and alternative routes of delivery. This study using buccal patches as an example created separated phases in situ of the buccal patches by selecting the excipients with different miscibility with each other and the model drug. The quaternary dispersion based buccal patches containing PEG, PEO, Tween 80, and felodipine were prepared by direct hot melt extrusion-injection molding (HME-IM). The partial miscibility between Tween 80 and semicrystalline PEG-PEO led to the phase separation after extrusion. The Tween phases acted as drug solubilization compartments, and the PEG-PEO phase had the primary function of providing mucoadhesion and carrier controlled dissolution. As felodipine was preferably solubilized in the amorphous regions of PEG-PEO, the high crystallinity of PEG-PEO resulted in an overall low drug solubilizing capacity. Tween 80 was added to improve the solubilization capacity of the system as the model drug showed good solubility in Tween. Increasing the drug loading led to the supersaturation of drug in Tween compartments and crystalline drug dispersed in PEG-PEO phases. The spatial distribution of these phase-separated compartments was mapped using X-ray micro-CT, which revealed that the domain size and heterogeneity of the phase separation increased with increasing the drug loading. The outcome of this study provides new insights into the applicability of in situ formed phase separation as a formulation strategy for the delivery of poorly soluble drugs and demonstrated the basic principle of excipient selection for such technology. PMID:26551593

  10. Effect of reprocessing cycles on the degradation of polypropylene copolymer filled with talc or montmorillonite during injection molding process

    Energy Technology Data Exchange (ETDEWEB)

    Demori, R.; Mauler, R. S., E-mail: raquel.mauler@ufrgs.br [Chemistry Institute, Federal University of Rio Grande do Sul, UFRGS, Av. Bento Gonçalves, 9500, Porto Alegre, 91501-970 (Brazil); Ashton, E.; Weschenfelder, V. F.; Cândido, L. H. A.; Kindlein, W. [Laboratory of Design LDSM, Federal University of Rio Grande do Sul, UFRGS (Brazil)

    2015-05-22

    Mechanical recycling of polymeric materials is a favorable technique resulting in economic and environmental benefits, especially in the case of polymers with a high production volume as the polypropylene copolymer (PP). However, recycling by reprocessing techniques can lead to thermal, mechanical or thermo-oxidative degradation that can affect the structure of the polymer and subsequently the material properties. PP filled with montmorillonite (MMT) or talc are widely produced and studied, however, its degradation reactions by reprocessing cycles are poorly studied so far. In this study, the effects of reprocessing cycles in the structure and in the properties of the PP/MMT and PP/Talc were evaluated. The samples were mixed with 5% talc or MMT Cloisite C15A in a twin-screw extrusion. After extrusion, this filled material was submitted to five reprocessing cycles through an injection molding process. In order to evaluate the changes induced by reprocessing techniques, the samples were characterized by DSC, FT-IR, Izod impact and tensile strength tests. The study showed that Young modulus, elongation at brake and Izod impact were not affected by reprocessing cycles, except when using talc. In this case, the elongation at brake reduced until the fourth cycle, showing rigidity increase. The DSC results showed that melting and crystallization temperature were not affected. A comparison of FT-IR spectra of the reprocessed indicated that in both samples, between the first and the fifth cycle, no noticeable change has occurred. Thus, there is no evidence of thermo oxidative degradation. In general, these results suggest that PP reprocessing cycles using MMT or talc does not change the material properties until the fifth cycle.

  11. Effect of reprocessing cycles on the degradation of polypropylene copolymer filled with talc or montmorillonite during injection molding process

    International Nuclear Information System (INIS)

    Mechanical recycling of polymeric materials is a favorable technique resulting in economic and environmental benefits, especially in the case of polymers with a high production volume as the polypropylene copolymer (PP). However, recycling by reprocessing techniques can lead to thermal, mechanical or thermo-oxidative degradation that can affect the structure of the polymer and subsequently the material properties. PP filled with montmorillonite (MMT) or talc are widely produced and studied, however, its degradation reactions by reprocessing cycles are poorly studied so far. In this study, the effects of reprocessing cycles in the structure and in the properties of the PP/MMT and PP/Talc were evaluated. The samples were mixed with 5% talc or MMT Cloisite C15A in a twin-screw extrusion. After extrusion, this filled material was submitted to five reprocessing cycles through an injection molding process. In order to evaluate the changes induced by reprocessing techniques, the samples were characterized by DSC, FT-IR, Izod impact and tensile strength tests. The study showed that Young modulus, elongation at brake and Izod impact were not affected by reprocessing cycles, except when using talc. In this case, the elongation at brake reduced until the fourth cycle, showing rigidity increase. The DSC results showed that melting and crystallization temperature were not affected. A comparison of FT-IR spectra of the reprocessed indicated that in both samples, between the first and the fifth cycle, no noticeable change has occurred. Thus, there is no evidence of thermo oxidative degradation. In general, these results suggest that PP reprocessing cycles using MMT or talc does not change the material properties until the fifth cycle

  12. Fabrication and characterization of poly(propylene fumarate) scaffolds with controlled pore structures using 3-dimensional printing and injection molding.

    Science.gov (United States)

    Lee, Kee-Won; Wang, Shanfeng; Lu, Lichun; Jabbari, Esmaiel; Currier, Bradford L; Yaszemski, Michael J

    2006-10-01

    Poly(propylene fumarate) (PPF) is an injectable, biodegradable polymer that has been used for fabricating preformed scaffolds in tissue engineering applications because of in situ crosslinking characteristics. Aiming for understanding the effects of pore structure parameters on bone tissue ingrowth, 3-dimensional (3D) PPF scaffolds with controlled pore architecture have been produced in this study from computer-aided design (CAD) models. We have created original scaffold models with 3 pore sizes (300, 600, and 900 microm) and randomly closed 0%, 10%, 20%, or 30% of total pores from the original models in 3 planes. PPF scaffolds were fabricated by a series steps involving 3D printing of support/build constructs, dissolving build materials, injecting PPF, and dissolving support materials. To investigate the effects of controlled pore size and interconnectivity on scaffolds, we compared the porosities between the models and PPF scaffolds fabricated thereby, examined pore morphologies in surface and cross-section using scanning electron microscopy, and measured permeability using the falling head conductivity test. The thermal properties of the resulting scaffolds as well as uncrosslinked PPF were determined by differential scanning calorimetry and thermogravimetric analysis. Average pore sizes and pore shapes of PPF scaffolds with 600- and 900-microm pores were similar to those of CAD models, but they depended on directions in those with 300-microm pores. Porosity and permeability of PPF scaffolds decreased as the number of closed pores in original models increased, particularly when the pore size was 300 microm as the result of low porosity and pore occlusion. These results show that 3D printing and injection molding technique can be applied to crosslinkable polymers to fabricate 3D porous scaffolds with controlled pore structures, porosity, and permeability using their CAD models. PMID:17518649

  13. Moldagem por injeção de pós cerâmicos: remoção da parafina e do polipropileno utilizados como veículo orgânico Ceramic injection molding: removal of pafafin and polypropylene used as organic binder

    Directory of Open Access Journals (Sweden)

    Ricardo V. B. Oliveira

    2004-09-01

    Full Text Available A moldagem por injeção de pós cerâmicos tem se tornado um processo altamente atrativo por aliar a versatilidade e a produtividade da moldagem por injeção convencional às propriedades inerentes aos materiais cerâmicos. A remoção do ligante, usado como veículo orgânico nesse processo, é uma das etapas críticas para a produção de peças cerâmicas sem defeitos. Neste trabalho avaliou-se a influência da geometria das peças injetadas na remoção do ligante, tanto por imersão em solvente como por decomposição térmica. Alumina em pó foi misturada fisicamente a um ligante composto por polipropileno [PP], parafina [PW] e ácido esteárico [AE]. As peças com diferentes geometrias foram mantidas imersas em hexano, secas sob vácuo e acompanhada a variação de massa devido à solubilização do PW e AE. A determinação da porosidade das peças, realizada por meio das isotermas de adsorção/desorção de nitrogênio, mostrou um aumento de porosidade de 0,5% volume para aproximadamente 20% volume após a imersão em solvente. A remoção térmica do PP remanescente produziu hidrocarbonetos alifáticos e compostos insaturados, determinados e quantificados por espectroscopia de infravermelho, que permearam a estrutura porosa da peça. A geometria das peças tem grande influência na remoção do ligante, podendo afetar não só a qualidade do produto final, mas também as etapas subseqüentes do processo.Powder injection molding [PIM] has become highly attractive as it combines the versatility and productivity of conventional injection molding processes with the intrinsic properties of metallic and ceramic materials. The removal of organic binder, used as vehicles during the process, is one of the most critical stages in the production of ceramic devices in this process. In this work, the influence from the geometry of the injected part on the removal of the organic binder was evaluated for both solvent immersion and thermal degradation processes. Alumina powder was mixed with an organic binder, comprising polypropylene [PP], paraffin wax [PW] and stearic acid [SA], and injection molded in different geometries. Immersion of ceramic parts in hexane induced the solubilization of PW and SA, confirmed by weight variation. Parts porosity, determined through nitrogen adsorption isotherm, showed an increase from 0.5 v% before immersion to ca. 20 v% after immersion. PP burnout produced aliphatic hydrocarbons and unsaturated compounds that flow through a porous structure produced in early stages of this process. Parts geometry plays an important role in binder removal, affecting the quality of the sintered part as well as the remaining stages of the process.

  14. The effect of injection molding conditions on the near-surface rubber morphology, surface chemistry, and adhesion performance of semi-crystalline and amorphous polymers

    Science.gov (United States)

    Weakley-Bollin, Shannon Christine

    This thesis investigated the effect of injection molding processing variables, resin formulation and mold material on the resulting morphology and properties of semi-crystalline and amorphous polymers in parts molded on large presses with fully developed flow. Five different polymer resins and two different coating types were investigated, and the near-surface morphology was found to be dependent on material formulation, processing parameters, and geometry. For painted TPO, changes in the near-surface rubber morphology and surface chemistry based on material and processing conditions had no significant effect on the adhesion performance. For metal plated ABS, the adhesion performance was found to be heavily dependent on the rubber surface morphology, which varied with material formulation and processing conditions. One of the most significant findings was that forged aluminum injection molding tooling had little effect on the surface morphology or adhesion performance of either polypropylene or the two TPO formulations examined, despite the five-fold increase in thermal conductivity over traditional tool steel. Surface chemistry, however, was found to be affected by cooling rate, depending on material formulation. A UV stabilizer additive was found concentrated at 2.5 atomic percent on the surface of the aluminum molded part, but not the steel molded part, demonstrating a possible opportunity for using additives and aluminum tooling to create "designer surfaces". Processing conditions were found to have a competing role in metal plated ABS, where conditions that lowered surface stress and improved adhesion by a factor of 15 also increased the amount of bulk molded-in stress by nearly 7%. Both factors were found to play an important role in adhesion performance due to the effect of surface stress on the quality of the resulting etch structure. The bulk stress must be minimized to due to the large mechanical and thermal mismatch between the polymer and metal layers. This work provides a more in-depth understanding of the effect of processing and material composition on morphology, surface chemistry, molded-in stress and adhesion. This will establish guidelines for future injection molded part designs to alleviate delamination failures and minimize warp, as well as contribute to modeling predictions of shrink and mechanical behavior.

  15. Moldagem por injeção de pós cerâmicos: remoção da parafina e do polipropileno utilizados como veículo orgânico / Ceramic injection molding: removal of pafafin and polypropylene used as organic binder

    Scientific Electronic Library Online (English)

    Ricardo V. B., Oliveira; Eduardo A., Pinheiro; Valdir, Soldi; Alfredo T. N., Pires; Márcio C., Fredel.

    2004-09-01

    Full Text Available A moldagem por injeção de pós cerâmicos tem se tornado um processo altamente atrativo por aliar a versatilidade e a produtividade da moldagem por injeção convencional às propriedades inerentes aos materiais cerâmicos. A remoção do ligante, usado como veículo orgânico nesse processo, é uma das etapas [...] críticas para a produção de peças cerâmicas sem defeitos. Neste trabalho avaliou-se a influência da geometria das peças injetadas na remoção do ligante, tanto por imersão em solvente como por decomposição térmica. Alumina em pó foi misturada fisicamente a um ligante composto por polipropileno [PP], parafina [PW] e ácido esteárico [AE]. As peças com diferentes geometrias foram mantidas imersas em hexano, secas sob vácuo e acompanhada a variação de massa devido à solubilização do PW e AE. A determinação da porosidade das peças, realizada por meio das isotermas de adsorção/desorção de nitrogênio, mostrou um aumento de porosidade de 0,5% volume para aproximadamente 20% volume após a imersão em solvente. A remoção térmica do PP remanescente produziu hidrocarbonetos alifáticos e compostos insaturados, determinados e quantificados por espectroscopia de infravermelho, que permearam a estrutura porosa da peça. A geometria das peças tem grande influência na remoção do ligante, podendo afetar não só a qualidade do produto final, mas também as etapas subseqüentes do processo. Abstract in english Powder injection molding [PIM] has become highly attractive as it combines the versatility and productivity of conventional injection molding processes with the intrinsic properties of metallic and ceramic materials. The removal of organic binder, used as vehicles during the process, is one of the m [...] ost critical stages in the production of ceramic devices in this process. In this work, the influence from the geometry of the injected part on the removal of the organic binder was evaluated for both solvent immersion and thermal degradation processes. Alumina powder was mixed with an organic binder, comprising polypropylene [PP], paraffin wax [PW] and stearic acid [SA], and injection molded in different geometries. Immersion of ceramic parts in hexane induced the solubilization of PW and SA, confirmed by weight variation. Parts porosity, determined through nitrogen adsorption isotherm, showed an increase from 0.5 v% before immersion to ca. 20 v% after immersion. PP burnout produced aliphatic hydrocarbons and unsaturated compounds that flow through a porous structure produced in early stages of this process. Parts geometry plays an important role in binder removal, affecting the quality of the sintered part as well as the remaining stages of the process.

  16. The evaluation of vacuum venting and variotherm process for improving the replication by injection molding of high aspect ratio micro features for biomedical application

    Science.gov (United States)

    Sorgato, Marco; Lucchetta, Giovanni

    2015-05-01

    The aspect ratio achievable in replicating micro features is one of the most important process characteristics and it is a major manufacturing constraint in applying injection molding in a range of micro engineering applications. Vacuum venting has been reported to be an effective technique in replicating micro features by microinjection molding. High surface-to-volume ratio and reduced dimensions of micro parts promote the instantaneous drop of melt temperature and consequently lead to incomplete filling. This study aims to investigate the effects of variotherm process, cavity evacuation and their interaction on the production of a micro fluidic filter for biomedical applications. A low-viscosity polystyrene and a cyclic olefin copolymer were molded applying a combination of mold evacuation and a rapid mold temperature variation that keeps the cavity temperature above the glass transition temperature during the injection phase. The research revealed the importance of these molding technologies in enhancing part filling and the replication quality for high aspect ratio micro features.

  17. The role of clay nanoparticles on the development of structural hierarchy in injection molding of nylon 6 and uniaxial stretching of poly(vinyl chloride)

    Science.gov (United States)

    Yalcin, Baris

    The main thrust of this dissertation is to investigate the role of nanoparticles in the structural formation processes that take place in a typical melt processing: injection molding, and in a rubbery state processing: uniaxial film stretching. For melt processing we selected the Nylon-6/clay nanoparticle system as an example and for the rubbery state processing we selected PVC/plasticizer/Clay nanoparticle systems. The effect of platelet type nanoparticles and processing conditions (mold temperature and injection speed) on the development of 'local' microstructure in injection molded nylon 6 parts was investigated. Nanoplatelets induce high levels of orientation of the polymer matrix throughout the thickness of the molded part even at high mold temperatures where nonisothermal effects are highly suppressed and confined to very close proximity of surfaces. These high chain orientation levels observed in nanoparticle filled systems are a result of the shear amplification effect that occurs in small spaces between adjacent nanoparticles of differing velocity. At low mold temperature, 50°C, the structure of unfilled nylon 6 is made up of a steep structural gradient containing oriented threads at the surface surrounding undeformed spherulites in the interior. In nanocomposite samples, on the other hand, the development of complete spherulites is interrupted by high nucleation density caused by the presence of nanoparticles and shear amplification that occurs in small spaces between these particles. The latter phenomenon was found to be prevalent even at high mold temperatures where the cooling rates are greatly suppressed. In the structure gradient, polymer/nanocomposite samples show double shear regions near the surface surrounding the core regions that contain sheaves. The origin of complex superimposed SALS patterns is explained in terms of the short and long-range spatial correlations of these preferentially oriented sheaves and their optic axes. (Abstract shortened by UMI.)

  18. A method for manufacturing a tool part for an injection molding process, a hot embossing process, a nano-imprint process, or an extrusion process

    DEFF Research Database (Denmark)

    SØgaard, Emil Technical University of Denmark,

    The present invention relates to a method for manufacturing a tool part for an injection molding process, a hot embossing process, nano-imprint process or an extrusion process. First, there is provided a master structure (10) with a surface area comprising nanometre-sized protrusions (11) with a minimum density of approximately 105 protrusions/mm2, the protrusions being positioned in a non- periodic, irregular pattern, said protrusions being created by a process comprising alternating passivation and etching into the master structure. Secondly, there is made a transfer of the master structure into a metal insert (20), the metal insert having a corresponding nanometre-sized pattern (21) from said protrusions, and thirdly, adapting the metal insert into a tool part (30) for enabling nanometre- sized patterns being formed by the tool part. The invention provides an easier and faster way of manufacturing the master structure, e.g. a black silicon wafer. It is a further advantage of the present invention that it provides an advantageous way of making tools capable of producing self-cleaning surfaces without the need for chemical coating.

  19. From cellular lysis to microarray detection, an integrated thermoplastic elastomer (TPE) point of care Lab on a Disc.

    Science.gov (United States)

    Roy, Emmanuel; Stewart, Gale; Mounier, Maxence; Malic, Lidija; Peytavi, Régis; Clime, Liviu; Madou, Marc; Bossinot, Maurice; Bergeron, Michel G; Veres, Teodor

    2015-01-21

    We present an all-thermoplastic integrated sample-to-answer centrifugal microfluidic Lab-on-Disc system (LoD) for nucleic acid analysis. The proposed CD system and engineered platform were employed for analysis of Bacillus atrophaeus subsp. globigii spores. The complete assay comprised cellular lysis, polymerase chain reaction (PCR) amplification, amplicon digestion, and microarray hybridization on a plastic support. The fluidic robustness and operating efficiency of the assay were ensured through analytical optimization of microfluidic tools enabling beneficial implementation of capillary valves and accurate control of all flow timing procedures. The assay reliability was further improved through the development of two novel microfluidic strategies for reagents mixing and flow delay on the CD platform. In order to bridge the gap between the proof-of-concept LoD and production prototype demonstration, low-cost thermoplastic elastomer (TPE) was selected as the material for CD fabrication and assembly, allowing the use of both, high quality hot-embossing and injection molding processes. Additionally, the low-temperature and pressure-free assembly and bonding properties of TPE material offer a pertinent solution for simple and efficient loading and storage of reagents and other on-board components. This feature was demonstrated through integration and conditioning of microbeads, magnetic discs, dried DNA buffer reagents and spotted DNA array inserts. Furthermore, all microfluidic functions and plastic parts were designed according to the current injection mold-making knowledge for industrialization purposes. Therefore, the current work highlights a seamless strategy that promotes a feasible path for the transfer from prototype toward realistic industrialization. This work aims to establish the full potential for TPE-based centrifugal system as a mainstream microfluidic diagnostic platform for clinical diagnosis, water and food safety, and other molecular diagnostic applications. PMID:25385141

  20. Morphology of wood species affecting wood-thermoplastic interaction: microstructure and mechanical adhesion

    Scientific Electronic Library Online (English)

    William, Gacitua; Michael, Wolcott.

    Full Text Available The main objective of the research presented here is to relate anatomical features of wood species that affect the interactions between polymeric phases and performance of wood plastic composites (WPC). These interactions are related to the probable interlocking volume and surface area for stress tr [...] ansfer in a WPC. Composites were produced from different wood species and analyzed using SEM (scanning electron microscopy). Results showed that wood species with high interfacial areas may increase mechanical interlocking, reflected in the viscous constant of the Maxwell model. A complicating factor is that the relation of cell wall thickness-lumen diameter and the interconnectivity between wood cells in a wood, affect the potential for cell collapse. When wood cells collapse, the penetration of the thermoplastic into the wood structure is almost always ceased. The collapse of wood cells during extrusion-injection molding processes reduced the potential surface for stress transfer between phases affecting the mechanical properties of composites. Undamaged wood cells may potentially be filled with HDPE thermoplastic enhancing modulus and increase the strength of WPC.

  1. Morphology of wood species affecting wood-thermoplastic interaction: microstructure and mechanical adhesion

    Directory of Open Access Journals (Sweden)

    William Gacitua

    2009-01-01

    Full Text Available The main objective of the research presented here is to relate anatomical features of wood species that affect the interactions between polymeric phases and performance of wood plastic composites (WPC. These interactions are related to the probable interlocking volume and surface area for stress transfer in a WPC. Composites were produced from different wood species and analyzed using SEM (scanning electron microscopy. Results showed that wood species with high interfacial areas may increase mechanical interlocking, reflected in the viscous constant of the Maxwell model. A complicating factor is that the relation of cell wall thickness-lumen diameter and the interconnectivity between wood cells in a wood, affect the potential for cell collapse. When wood cells collapse, the penetration of the thermoplastic into the wood structure is almost always ceased. The collapse of wood cells during extrusion-injection molding processes reduced the potential surface for stress transfer between phases affecting the mechanical properties of composites. Undamaged wood cells may potentially be filled with HDPE thermoplastic enhancing modulus and increase the strength of WPC.

  2. Research cooperation project on the development of easy injection molding control technology for engineering plastics; Engineering plastic no seikei joken kan`i settei gijutsu ni kansuru kenkyu kyoryoku jigyo seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    In order to enhance the industries which supply assembly parts to Japan`s assembly industries in Thailand, research cooperation project on the plastic parts production technology has started. For the research cooperation, the mold design is effectively conducted using simulation technique of CAE (computer aided engineering), and an international easy injection molding control system is made using the molding support software for injection molding machines. In FY 1996, actual situations of plastic parts and assembly industries in Thailand have been investigated through the cooperation with the counterpart of Thailand. Demand and supply of engineering plastics, receive and inspection of parts, and current circumstances of molding processing makers in Thailand have been grasped. Based on the results of this investigation, proposal of basic plan, time schedule, and delivery plan of molding machines and testing equipment have been discussed, to make the basic plan. 18 refs., 4 figs., 23 tabs.

  3. Using Direct Metal Deposition to Fabricate Mold Plates for an Injection Mold Machine Allowing for the Evaluation of Cost Effective Near-Sourcing Opportunities in Larger, High Volume Consumer Products

    Energy Technology Data Exchange (ETDEWEB)

    Duty, Chad E [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Groh, Bill [Radio Systems Corporation, Knoxville, TN (United States)

    2014-10-31

    ORNL collaborated with Radio Systems Corporation to investigate additive manufacturing (AM) of mold plates for plastic injection molding by direct metal deposition. The team s modelling effort identified a 100% improvement in heat transfer through use of conformal cooling lines that could be built into the mold using a revolutionary design enabled by additive manufacturing. Using the newly installed laser deposition system at the ORNL Manufacturing Demonstration Facility (MDF) a stainless steel mold core was printed.

  4. Desenvolvimento de liga sinterizada de níquel por moldagem de pós por injeção / Development of sintered nickel alloy by powder injection molding

    Scientific Electronic Library Online (English)

    Moisés Luiz, Parucker; Aloisio Nelmo, Klein; Roberto, Binder.

    2014-09-01

    Full Text Available A moldagem de pós por injeção é um processo de fabricação de elevada produtividade que possibilita obter componentes de geometria complexa, estreita precisão dimensional e boas propriedades mecânicas. Neste processo, uma mistura de uma determinada quantidade de pós e ligantes orgânicos (polímeros, c [...] eras e óleos) é obtida por meio de uma massa de injeção (feedstock) o qual tem características reológicas adequadas para promover a injeção desta massa em uma cavidade de um molde. A produção de ligas de níquel por meio deste processo é uma alternativa para produção de produtos que requerem aplicações avançadas onde se exige resistência a corrosão e oxidação, resistência mecânica a altas temperaturas e baixo coeficiente de atrito. Neste trabalho apresentamos um estudo das propriedades microestruturais e mecânicas de uma liga de níquel (Ni-Fe-Cr-P) processada via moldagem de pós por injeção, utilizando pós de níquel carbonila com e sem a presença de fase líquida durante a sinterização. Os resultados foram comparados com a mesma liga processada por compactação de pós. Os resultados demonstraram a necessidade de maior quantidade de matéria orgânica para o desenvolvimento da massa de injeção (feedstock: 15% m/m de polímero) para os tipos de pós metálicos utilizados (níquel carbonila do tipo INCO 123) se comparado ao feedstock de ligas comerciais que normalmente utilizam uma quantidade menor de matéria orgânica (feedstock: 9% m/m de polímero). A maior quantidade de matéria orgânica necessária para a preparação do feedstock deve-se a morfologia dos pós empregados (superficie rugosa - tipo spiky) que promove retenção de carbono durante o processo de extração, ocasionando a necessidade de otimização do ciclo de extração térmica e sinterização. Ciclos mais lentos e a baixa temperatura promoveram a total retirada dos ligantes. A liga de Ni-Fe-Cr-P injetada apresentou contração de aproximadamente 50%, além de elevado teor de poros quando comparado ao material compactado, o que influenciou as propriedades mecânicas e dureza aparente do material. Abstract in english The powder injection molding is a manufacturing process that allows high productivity to obtain complex geometry components, dimensional accuracy and good mechanical properties. In this process, a mixture of a quantity of powders and organic binders (polymers, waxes, oils) is obtained through inject [...] ion of a mass (feedstock) which has rheological properties suitable for promoting the injection of this mass in a cavity of a mold. The production of nickel alloy by this process is an alternative to production of products that require advanced applications, which require resistance to corrosion and oxidation, mechanical strength at high temperatures and low coefficient of friction. This paper we present the study of the microstructural and mechanical properties of a nickel alloy (Ni-Fe-Cr-P) processed by powder injection molding, using carbonyl nickel powders with and without the presence of liquid phase during sintering. The results are compared with the alloy processed by powder compaction. The results demonstrate the need for increased amount of organic matter for developing the injection mass (feedstock: 15 wt.% polymer) for the types of metallic powders used (nickel INCO type 123 carbonyl) compared to commercial alloy feedstock typically use a smaller amount of organic matter (feedstock: 9 wt.% polymer). The largest quantity of organic matter needed for the preparation of the feedstock due to the morphology of the powders used (spiky) which promoted carbon retention during the extraction process, resulting in the need to optimize the extraction cycle and thermal sintering. Slower cycles and low temperature promoted the complete extraction of the ligands. The Ni-Fe-Cr-P alloy injected showed shrinkage of approximately 50%, and high levels of pores as compared to the compacted material, which influenced the mechanical properties and apparent hardness of the material.

  5. Determinação da redução da resistência à tração em corpos de prova com Weld Line / Determination of reduction of the weld line strength in injection molded

    Scientific Electronic Library Online (English)

    R.P., Bom; A.F., Kalin.

    2008-06-01

    Full Text Available Neste trabalho objetivou-se determinar a redução da resistência à tração de corpos de prova com linhas de solda. Os corpos de prova ASTM foram moldados pelo processo de injeção com diferentes temperaturas de plastificação (180 ºC a 280 ºC). O material utilizado foi o polímero termoplástico Polystyro [...] l 158 K da Basf. Este estudo relaciona as linhas de solda em produtos moldados por injeção com a redução da resistência mecânica devido a fragilização na região da linha de solda. Para o desenvolvimento deste trabalho foi projetado e desenvolvido um molde de injeção com uma cavidade em forma de corpo de prova com canal de ataque pelas extremidades. Desta forma no momento da junção dos fluxos obtêm-se uma linha de solda no centro do corpo de prova. Os parâmetros do processo de injeção foram determinados a partir de um aplicativo comercial. A temperatura do molde e o tempo de injeção permaneceram constantes. O tempo de solidificação do material foi determinado analiticamente, considerando-se o centro do corpo de prova como referência. Foram injetados dez corpos de prova em cada uma das temperaturas. Foi observada de forma clara a existência de linhas de junção no centro da peça e as condições de processo utilizadas não permitiram a formação de linha de solda fria. Após a realização dos ensaios de tração, foi determinado que a tensão de ruptura decresce nas seguintes condições: com a diminuição da temperatura de injeção e do tempo de solidificação e com o aumento da trinca. A ruptura sempre ocorreu na linha de solda. Abstract in english In this paper, the purpose is to determine the weld line strength in injection molded samples. The ASTM standard dogbone-shaped samples were molded over a range of melt temperatures (180 ºC up to 280 ºC). The plastic used was a commercial grade of polystyrene (PS), BASF Polystyrol 158K. This study l [...] inks weld lines in parts by injection molding with mechanical strength reduction due to embrittling effect in weld-line region. A single-cavity mold double-gated was used to generate ASTM D638 Type I tensile specimens. The double-gated and runner allow the parts to be molded with weld line. The injection process parameters were determined by imputing resin, machine and geometry information into a CAE software package. The mold temperature and fill time were maintaining the same. The frozen time was determined by analytic equation, which considers the center of the thickness as reference. For each melt temperature 10 samples were tested. The weld line was clearly noted in the centre of the samples and the process condition set avoided the cold weld line. By the strength tests were possible to realize that lower the injection temperature lower the frozen time and higher the length of the crack. Then low injection temperature leads to low maximum strength. The fracture always occurs in the weld line.

  6. Investigation of the effect of nanoclay and processing parameters on the tensile strength and hardness of injection molded Acrylonitrile Butadiene Styrene–organoclay nanocomposites

    International Nuclear Information System (INIS)

    Highlights: • Development of polymer/clay nanocomposites. • Compatibility of ABS and montmorillonite nanoclay and composition capability of them. • Effect of nanoclay content and process parameters on the mechanical properties of nanocomposite. • Analyzing the distribution of nanoclay layers using XRD test. • Dependency of tensile strength and hardness to the nanoclay content and processing conditions. - Abstract: Polymer–clay nanocomposites have attracted considerable interest over recent years due to their dramatic improved mechanical properties. In the present study, compatibility of Acrylonitrile Butadiene Styrene (ABS) and organically modified montmorillonite nanoclay (Cloisite 30B) and composition capability of them are investigated. Polymethylmethacrylate (PMMA) in varying amount (0, 2, and 4 wt%) is used as the compatibilizer. In order to produce nanocomposite parts, the material is first compounded using a twin-screw extruder and then injected into a mold. The effect of the nanoclay percentage and processing parameters on the tensile strength and hardness of nanocomposite parts is also explored using Taguchi Design of Experiments method. Nanoclay content (in three levels: 0, 2 and 4 wt%), melt temperature (in three levels: 190, 200 and 210 °C), holding pressure (in three levels: 80, 105 and 130 MPa) and holding pressure time (in three levels: 1, 2.5 and 4 s) are considered as the variable parameters. Moreover, distribution of nanoclay layers is analyzed using Wide Angle X-ray Diffraction (XRD) test. XRD results displayed that with the presence of PMMA, nanoclay in ABS matrix is compounded in more exfoliated and less intercalated dispersion mode. Adding PMMA also leads to a remarkable increase in the fluidity of the melt during injection molding process. Results also illustrated that nanocomposites with medium loading level (i.e. 2%) of nanoclay have the highest tensile strength, while the highest hardness number belongs to nanocomposites with 4 wt% nanoclay. Obtained results also indicated that injection temperature has the most important effect on tensile strength and hardness of ABS–clay nanocomposites

  7. Aplicação das técnicas de planejamento e análise de experimentos no processo de injeção plástica / Application design of experiments in the injection molding process

    Scientific Electronic Library Online (English)

    Edwin V. Cardoza, Galdamez; Luiz C. Ribeiro, Carpinetti.

    2004-04-01

    Full Text Available Experimentos industriais são realizados pelas empresas com o intuito de melhorar o desempenho dos produtos e os processos de fabricação. Nesse sentido, este trabalho tem por objetivo estudar e aplicar as técnicas de planejamento e análise de experimentos na melhoria da qualidade industrial. Especifi [...] camente são aplicadas as técnicas de planejamento Fatorial Fracionado 2k-p, Metodologia de Superfície de Resposta e Análise de Variância, em um processo de moldagem por injeção plástica. Com essa pesquisa experimental foi possível identificar os níveis ótimos de regulagem e os parâmetros mais importantes da injeção plástica: temperatura da máquina e pressão de injeção. Para finalizar é avaliado o procedimento de implementação das técnicas de experimentação e as dificuldades práticas encontradas na empresa. Abstract in english Industrial experiments are made by companies in order to improve the quality characteristics of products and production processes. In this sense, the objective of this paper is to study and apply the design of experiments in the industrial quality improvement. In addition, as a part of the objective [...] , an application of the techniques of design Fractional Factorial 2k-p, Analysis of Variance and Response Surface Methodology is done. It is focused in an injection molding process applied by a company, that makes and trades plastic products for the civil construction. Using this experimental study, the most important parameters of plastic injection are identified: machine temperature and injection pressure. At the same time, the optimal levels of adjustment of these parameters are determined. From this study, it is evaluated both the implantation procedures of the designs of experiments as well as the difficulties faced. Also, this study tries to contribute to the university-company relationship.

  8. Aplicação das técnicas de planejamento e análise de experimentos no processo de injeção plástica Application design of experiments in the injection molding process

    Directory of Open Access Journals (Sweden)

    Edwin V. Cardoza Galdamez

    2004-04-01

    Full Text Available Experimentos industriais são realizados pelas empresas com o intuito de melhorar o desempenho dos produtos e os processos de fabricação. Nesse sentido, este trabalho tem por objetivo estudar e aplicar as técnicas de planejamento e análise de experimentos na melhoria da qualidade industrial. Especificamente são aplicadas as técnicas de planejamento Fatorial Fracionado 2k-p, Metodologia de Superfície de Resposta e Análise de Variância, em um processo de moldagem por injeção plástica. Com essa pesquisa experimental foi possível identificar os níveis ótimos de regulagem e os parâmetros mais importantes da injeção plástica: temperatura da máquina e pressão de injeção. Para finalizar é avaliado o procedimento de implementação das técnicas de experimentação e as dificuldades práticas encontradas na empresa.Industrial experiments are made by companies in order to improve the quality characteristics of products and production processes. In this sense, the objective of this paper is to study and apply the design of experiments in the industrial quality improvement. In addition, as a part of the objective, an application of the techniques of design Fractional Factorial 2k-p, Analysis of Variance and Response Surface Methodology is done. It is focused in an injection molding process applied by a company, that makes and trades plastic products for the civil construction. Using this experimental study, the most important parameters of plastic injection are identified: machine temperature and injection pressure. At the same time, the optimal levels of adjustment of these parameters are determined. From this study, it is evaluated both the implantation procedures of the designs of experiments as well as the difficulties faced. Also, this study tries to contribute to the university-company relationship.

  9. Confine Clay in an Alternating Multilayered Structure through Injection Molding: A Simple and Efficient Route to Improve Barrier Performance of Polymeric Materials.

    Science.gov (United States)

    Yu, Feilong; Deng, Hua; Bai, Hongwei; Zhang, Qin; Wang, Ke; Chen, Feng; Fu, Qiang

    2015-05-20

    Various methods have been devoted to trigger the formation of multilayered structure for wide range of applications. These methods are often complicated with low production efficiency or require complex equipment. Herein, we demonstrate a simple and efficient method for the fabrication of polymeric sheets containing multilayered structure with enhanced barrier property through high speed thin-wall injection molding (HSIM). To achieve this, montmorillonite (MMT) is added into PE first, then blended with PP to fabricate PE-MMT/PP ternary composites. It is demonstrated that alternating multilayer structure could be obtained in the ternary composites because of low interfacial tension and good viscosity match between different polymer components. MMT is selectively dispersed in PE phase with partial exfoliated/partial intercalated microstructure. 2D-WAXD analysis indicates that the clay tactoids in PE-MMT/PP exhibits an uniplanar-axial orientation with their surface parallel to the molded part surface, while the tactoids in binary PE-MMT composites with the same overall MMT contents illustrate less orientation. The enhanced orientation of nanoclay in PE-MMT/PP could be attributed to the confinement of alternating multilayer structure, which prohibits the tumbling and rotation of nanoplatelets. Therefore, the oxygen barrier property of PE-MMT/PP is superior to that of PE-MMT because of increased gas permeation pathway. Comparing with the results obtained for PE based composites in literature, outstanding barrier property performance (45.7% and 58.2% improvement with 1.5 and 2.5 wt % MMT content, respectively) is achieved in current study. Two issues are considered responsible for such improvement: enhanced MMT orientation caused by the confinement in layered structure, and higher local density of MMT in layered structure induced denser assembly. Finally, enhancement in barrier property by confining impermeable filler into alternating multilayer structure through such simple and efficient method could provide a novel route toward high-performance packaging materials and other functional materials require layered structure. PMID:25915444

  10. THERMOPLASTIC WAVES IN MAGNETARS

    International Nuclear Information System (INIS)

    Magnetar activity is generated by shear motions of the neutron star surface, which relieve internal magnetic stresses. An analogy with earthquakes and faults is problematic, as the crust is permeated by strong magnetic fields which greatly constrain crustal displacements. We describe a new deformation mechanism that is specific to strongly magnetized neutron stars. The magnetically stressed crust begins to move because of a thermoplastic instability, which launches a wave that shears the crust and burns its magnetic energy. The propagating wave front resembles the deflagration front in combustion physics. We describe the conditions for the instability, the front structure, and velocity, and discuss implications for observed magnetar activity

  11. Thermoplastic waves in magnetars

    CERN Document Server

    Beloborodov, Andrei M

    2014-01-01

    Magnetar activity is generated by shear motions of the neutron star surface, which relieve internal magnetic stresses. An analogy with earthquakes and faults is problematic, as the crust is permeated by strong magnetic fields, which greatly constrain crustal displacements. We describe a new deformation mechanism that is specific to strongly magnetized neutron stars. The magnetically stressed crust begins to move because of a thermoplastic instability, which launches a wave that shears the crust and burns its magnetic energy. The propagating wave front resembles the deflagration front in combustion physics. We describe the conditions for the instability, the front structure and velocity, and discuss implications for observed magnetar activity.

  12. Synthesis of APA6 thermoplastic matrices for the manufacture of greencomposites

    Science.gov (United States)

    Alfonso, A.; Andrés, J.; García-Manrique, J. A.

    2012-04-01

    The present research work assesses the manufacture of long fiber thermoplastic matrix composite materials (GreenComposites). Thermoplastic matrices are too viscous to be injected into the conventional LCM (Liquid Comopsite Molding) molds, and then epoxy, polyester o vinylester resins are used. Nevertheless, the groundbreaking anionic polymerization of ?-caprolactam allows such a synthesis of a thermoplastic APA6 matrix inside the mold. This matrix is sintered from the starting monomers, and presents high mechanical performance and recyclability. In order to do the reactive injection in a LCM mold, it is necessary to control the polymerization mechanism of such a thermoplastic matrix. Likewise, it puts special emphasis on detecting and solving all problems which arose during synthesis. For instance, moisture values were assessed for all starting reactants, since humidity keeps polymerization from occurring. It is thought that once the synthesis and the resulting material characterization are well controlled, the manufacture of GreenComposites through monomers injection and in situ polymerization, as well as addition of state-of-the-art fabrics such as basalt, can proceed successfully.

  13. Near net shaping of Nb-Al injection molded compacts using pulse current sintering process under pseudo hot isostatic pressing; Gi HIP-hoden shoketsuho ni yoru Nb-Al shashutsu seikeitai no near net shape koka gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Matsumoto, A.; Kato, K.; Kato, M. [National Industrial Research Institute of Nagoya,Nagoya (Japan)

    1999-02-22

    The consolidation of injection molded Nb-Al specimen by Pulse Current Sintering Process, that combines a very short time at high temperature with pressure application in various environments, is proposed as a novel process of near net forming(PHIP-PCS). The proposed PHIP technique using a pressure-transmitting medium of spherical graphite powder makes it possible to manufacture Nb-Al compacts with three dimensional shapes. Fine Nb{sub 3}Al powders, Nb-23at%Al, Nb-26at%Al-37at%Mo and Nb-27at%Al-31.5at%Mo-10W (hereafter at% being omitted), with A15 structure, were prepared by self-propagating high temperature synthesis method. The powders, mixed with 44 vol% organic binder, were injection molded. After debound in 100 Torr Ar atmosphere at 380 degree C, they were consolidated by PHIP-PCS process. Contraction percentage of the compacts prepared by PHIP-PCS was 36% for longitudinal (loading) direction, while 1% for transverse direction. Compressive flow stress at 1,800 degree C for Nb-23Al, Nb-26Al-37Mo and Nb-27Al-31.5Mo-10W compacts were respectively 27MPa, 65MPa and 95MPa.. (author)

  14. Effect of thermoplastic polyurethane content on properties of PC/TPU blend filled with Montmorillonite

    Directory of Open Access Journals (Sweden)

    G. M. Shashidhara

    2013-03-01

    Full Text Available The present study was taken up to investigate the effect of addition of Montmorillonite (MMT to Polycarbonate/Thermoplastic polyurethane (PC/TPU blends. A master batch of PC/MMT (70/30 was prepared using Hake Rheomixer and PC/TPU blends filled with MMT of different compositions (90/10/5, 80/20/5, 70/30/5 were prepared by melt mixing using required quantities of master batch, PC and TPU in a twin screw extruder (TSE. Blends of PC/TPU of similar compositions (without MMT were also prepared using twin screw extruder. The test specimens were prepared by injection molding. The samples were characterized in terms of mechanical (as per relevant ASTM standards, thermal and dynamic mechanical properties. It was observed that addition of 5 phb of MMT to PC/TPU system improves tensile strength by 34 %, flexural strength by 8.6 % and flexural modulus by 16.7 %, storage modulus by 25 % and Shore D hardness by 16 % in all the compositions containing MMT. Differencial Scanning Calorimetric (DSC and Dynamic Mechanical Analysis (DMA studies revealed that the Tg shift towards lower values when compared with neat PC.The heat deflection temperature (HDT of blends with MMT was found to increase with the reinforcement.

  15. Análise do desenvolvimento morfológico da blenda polimérica PBT/ABS durante as etapas de mistura por extrusão e moldagem por injeção Analysis of the morphological development of PBT/ABS blends during the extrusion and injection molding processes

    Directory of Open Access Journals (Sweden)

    Edson N. Ito

    2004-06-01

    Full Text Available O enfoque principal deste trabalho foi observar o desenvolvimento da morfologia de fases da blenda binária PBT/ABS e desta blenda compatibilizada pela adição de um copolímero acrílico reativo, durante a etapa de mistura por extrusão e de moldagem por injeção. A evolução da morfologia das blendas, durante a etapa de mistura, foi analisada através do uso de amostras coletadas de uma extrusora de rosca dupla co-rotacional, com acessório especialmente projetado para coleta in line. A morfologia observada nas amostras obtidas por injeção foi realizada utilizando amostras retiradas de corpos de prova moldados. As amostras obtidas por extrusão e por moldagem por injeção foram posteriormente preparadas através de crio-ultramicrotomia e observadas através de microscopia eletrônica de transmissão (TEM. Uma "Função Dispersão" foi desenvolvida neste trabalho para comparar as diversas morfologias sob diferentes condições de processamento e de compatibilização. A adição de compatibilizante favorece a formação de uma morfologia de domínios de ABS dispersos em PBT, ao longo do canhão da extrusora, e previne satisfatoriamente o fenômeno de coalescência destes domínios durante o processo de moldagem por injeção. A função dispersão foi utilizada principalmente para mostrar a tendência da evolução morfológica e mostrou um bom desempenho para tal.The aim of this work was to observe the development of the phase morphology of the PBT/ABS blends during their extrusion mixing and injection molding steps. The evolution of the blend morphology during the mixing stage was analyzed using a specially designed co-rotational twin-screw extruder with a collecting device located along the barrel. Blend samples were collected in-line along the length of the extruder barrel during the blending process. Blend morphology was also observed from specimens molded through injection molding. All the samples were observed by transmission electron microscopy (TEM. They were prepared by cryo-ultramicrotomy and the rubbery phase of the ABS contained in the blends was stained with osmium tetroxide (OsO4. A special function was established and is proposed to analyze the blend morphology trends through image analysis. In binary blends, the ABS phase showed better dispersion after the mixture passed through the extruder die. However, a coalescence phenomenon was observed during the next molding step. Compatibilized PBT/ABS blends showed better dispersion than binary blends, even after injection molding. The special function used to quantify the dispersion throughout the mixing and molding steps showed an excellent performance.

  16. Análise do desenvolvimento morfológico da blenda polimérica PBT/ABS durante as etapas de mistura por extrusão e moldagem por injeção / Analysis of the morphological development of PBT/ABS blends during the extrusion and injection molding processes

    Scientific Electronic Library Online (English)

    Edson N., Ito; Luiz A., Pessan; Elias, Hage Jr.; José A., Covas.

    2004-06-01

    Full Text Available O enfoque principal deste trabalho foi observar o desenvolvimento da morfologia de fases da blenda binária PBT/ABS e desta blenda compatibilizada pela adição de um copolímero acrílico reativo, durante a etapa de mistura por extrusão e de moldagem por injeção. A evolução da morfologia das blendas, du [...] rante a etapa de mistura, foi analisada através do uso de amostras coletadas de uma extrusora de rosca dupla co-rotacional, com acessório especialmente projetado para coleta in line. A morfologia observada nas amostras obtidas por injeção foi realizada utilizando amostras retiradas de corpos de prova moldados. As amostras obtidas por extrusão e por moldagem por injeção foram posteriormente preparadas através de crio-ultramicrotomia e observadas através de microscopia eletrônica de transmissão (TEM). Uma "Função Dispersão" foi desenvolvida neste trabalho para comparar as diversas morfologias sob diferentes condições de processamento e de compatibilização. A adição de compatibilizante favorece a formação de uma morfologia de domínios de ABS dispersos em PBT, ao longo do canhão da extrusora, e previne satisfatoriamente o fenômeno de coalescência destes domínios durante o processo de moldagem por injeção. A função dispersão foi utilizada principalmente para mostrar a tendência da evolução morfológica e mostrou um bom desempenho para tal. Abstract in english The aim of this work was to observe the development of the phase morphology of the PBT/ABS blends during their extrusion mixing and injection molding steps. The evolution of the blend morphology during the mixing stage was analyzed using a specially designed co-rotational twin-screw extruder with a [...] collecting device located along the barrel. Blend samples were collected in-line along the length of the extruder barrel during the blending process. Blend morphology was also observed from specimens molded through injection molding. All the samples were observed by transmission electron microscopy (TEM). They were prepared by cryo-ultramicrotomy and the rubbery phase of the ABS contained in the blends was stained with osmium tetroxide (OsO4). A special function was established and is proposed to analyze the blend morphology trends through image analysis. In binary blends, the ABS phase showed better dispersion after the mixture passed through the extruder die. However, a coalescence phenomenon was observed during the next molding step. Compatibilized PBT/ABS blends showed better dispersion than binary blends, even after injection molding. The special function used to quantify the dispersion throughout the mixing and molding steps showed an excellent performance.

  17. Aplicação de redes Neuro Fuzzy ao processamento de peças automotivas por meio de injeção de polímeros / Application of neurofuzzy networks for the processing of automotive parts by polymer injection molding

    Scientific Electronic Library Online (English)

    Carlos de Oliveira, Affonso; Renato José, Sassi.

    Full Text Available O processamento de peças automotivas por meio de injeção de polímeros envolve vários fenômenos físicos que ocorrem simultaneamente e que possuem caráter não linear e multivariável. Softwares comerciais podem ser utilizados na previsão dos parâmetros do processo, o que pode ser caro e inviável. Pode- [...] se determinar os parâmetros de forma analítica, mas o tratamento desse problema requer a aplicação de teorias clássicas dos fenômenos de transporte, de difícil equacionamento. As redes NeuroFuzzy são aplicáveis a esse problema porque reúnem a capacidade de aprender das redes neurais artificiais com a capacidade da lógica Fuzzy de transformar variáveis linguísticas em regras. Neste trabalho combinou-se uma rede neural artificial Multilayer Perceptron e uma rede neural artificial Radial Basis Function à lógica Fuzzy para construir-se um modelo de inferência que previu o tempo de ciclo de processos de injeção de polímeros. Os resultados obtidos confirmam as redes NeuroFuzzy como opção para esse tipo de problema. Abstract in english The injection molding of automotive parts is a complex process due to the many non-linear and multivariable phenomena that occur simultaneously. Commercial software applications exist for modeling the parameters of polymer injection but can be prohibitively expensive. It is possible to identify thes [...] e parameters analytically, but applying classical theories of transport phenomena requires accurate information about the injection machine, product geometry, and process parameters. However, neurofuzzy networks, which achieve a synergy by combining the learning capabilities of an artificial neural network with a fuzzy set's inference mechanism, have shown success in this field. The purpose of this paper was to use a multilayer perceptron artificial neural network and a radial basis function artificial neural network combined with fuzzy sets to produce an inference mechanism that could predict injection mold cycle times. The results confirmed neurofuzzy networks as an effective alternative to solving such problems.

  18. Aplicação de redes Neuro Fuzzy ao processamento de peças automotivas por meio de injeção de polímeros / Application of neurofuzzy networks for the processing of automotive parts by polymer injection molding

    Scientific Electronic Library Online (English)

    Carlos de Oliveira, Affonso; Renato José, Sassi.

    2015-03-01

    Full Text Available O processamento de peças automotivas por meio de injeção de polímeros envolve vários fenômenos físicos que ocorrem simultaneamente e que possuem caráter não linear e multivariável. Softwares comerciais podem ser utilizados na previsão dos parâmetros do processo, o que pode ser caro e inviável. Pode- [...] se determinar os parâmetros de forma analítica, mas o tratamento desse problema requer a aplicação de teorias clássicas dos fenômenos de transporte, de difícil equacionamento. As redes NeuroFuzzy são aplicáveis a esse problema porque reúnem a capacidade de aprender das redes neurais artificiais com a capacidade da lógica Fuzzy de transformar variáveis linguísticas em regras. Neste trabalho combinou-se uma rede neural artificial Multilayer Perceptron e uma rede neural artificial Radial Basis Function à lógica Fuzzy para construir-se um modelo de inferência que previu o tempo de ciclo de processos de injeção de polímeros. Os resultados obtidos confirmam as redes NeuroFuzzy como opção para esse tipo de problema. Abstract in english The injection molding of automotive parts is a complex process due to the many non-linear and multivariable phenomena that occur simultaneously. Commercial software applications exist for modeling the parameters of polymer injection but can be prohibitively expensive. It is possible to identify thes [...] e parameters analytically, but applying classical theories of transport phenomena requires accurate information about the injection machine, product geometry, and process parameters. However, neurofuzzy networks, which achieve a synergy by combining the learning capabilities of an artificial neural network with a fuzzy set's inference mechanism, have shown success in this field. The purpose of this paper was to use a multilayer perceptron artificial neural network and a radial basis function artificial neural network combined with fuzzy sets to produce an inference mechanism that could predict injection mold cycle times. The results confirmed neurofuzzy networks as an effective alternative to solving such problems.

  19. Thermoplastic starch materials prepared from rice starch

    International Nuclear Information System (INIS)

    Rice starch is a source still little studied for the preparation of thermoplastic materials. However, its characteristics, such as the presence of proteins, fats and fibers may turn into thermoplastics with a better performance. The present study intends the evaluation of the viability of making starch thermoplastic from rice starch and glycerol as plasticizer. The results of X-ray diffraction and scanning electronic microscopy demonstrate the thermoplastic acquisition. The increase of plasticizer content brings on more hydrophilic thermoplastics with less resistance to tension and elongation at break. (author)

  20. MODIFICATION OF JACK PINE TMP LONG FIBERS BY ALKALINE PEROXIDE – PART 1. CHEMICAL CHARACTERISTICS OF FIBERS AND SPENT LIQUOR

    Directory of Open Access Journals (Sweden)

    Ying Han

    2008-08-01

    Full Text Available The purpose of this work was to improve the quality of jack pine TMP long fibers, particularly with respect to the strength properties, by alkaline peroxide treatment. This paper reports the chemical characteristics of the treated long fibers and the spent liquors originating from various treatments. It was observed that, in comparison with hydrogen peroxide, the alkalinity of the treatment solutions had a greater influence on most fibre characteristics and spent liquor properties.

  1. Simulação do processo de injeção de polipropileno isotático (iPP) utilizando um modelo de cinética de cristalização quiescente / Simulation of injection molding process of isotactic polypropylene (iPP) using a quiescent crystallization kinetics model

    Scientific Electronic Library Online (English)

    Marcos A, d' Ávila; Carlos H, Ahrens; Rosario E. S, Bretas.

    1997-12-01

    Full Text Available Este trabalho concentrou-se na simulação das fases de preenchimento e resfriamento do processo de injeção do polipropileno isotático. Foi utilizado um modelo matemático baseado nas equações de conservação onde foi considerada a cinética de cristalização quiescente como termo fonte na equação da ener [...] gia. Os parâmetros do modelo de cinética de cristalização, assim como os do modelo de viscosidade, foram obtidos experimentalmente. Para a solução das equações governantes foi utilizado o método dos volumes finitos. Como resultados foram obtidos os campos de temperatura, pressão, velocidade, taxa de cisalhamento e cristalinidade em diferentes condições de processamento. Abstract in english This work is concerned with the simulation of the filling and cooling stages of the injection molding process of an isotactic polypropylene (iPP). A mathematical model based on the conservation equations was used. A crystallization kinetics model was considered as a source term in the energy equatio [...] n. The parameters of the crystallization kinetics model, as well as the viscosity model, were obtained by experimental techniques. For the solution of the governing equations the finite volume method was employed. Temperature, pressure, velocity, shear rate and crystalinity profiles under different processing conditions were obtained.

  2. Ultrasonic Assembly of Thermoplastic Parts

    Energy Technology Data Exchange (ETDEWEB)

    Schurman, W. R.

    1970-03-31

    Four ultrasonic methods were evaluated for assembly of experimental plastic parts for detonators: (1) welding, (2) crimping and staking, (3) insertion, and (4) reactivation of adhesives. For welding, staking and insertion, plastics with low elastic moduli, such as acrylics and polycarbonate, produced the best results. Thermosetting, hot-melt, and solution adhesives could all be activated ultrasonically to form good bonds on plastics and other materials. This evaluation indicated that thermoplastic detonator parts could be assembled ultrasonically in shorter times than by present production techniques with high bond strengths and high product acceptance rates.

  3. Implementation of New Process Models for Tailored Polymer Composite Structures into Processing Software Packages

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, Ba Nghiep; Jin, Xiaoshi; Wang, Jin; Phelps, Jay; Tucker III, Charles L.; Kunc, Vlastimil; Bapanapalli, Satish K.; Smith, Mark T.

    2010-02-23

    This report describes the work conducted under the Cooperative Research and Development Agreement (CRADA) (Nr. 260) between the Pacific Northwest National Laboratory (PNNL) and Autodesk, Inc. to develop and implement process models for injection-molded long-fiber thermoplastics (LFTs) in processing software packages. The structure of this report is organized as follows. After the Introduction Section (Section 1), Section 2 summarizes the current fiber orientation models developed for injection-molded short-fiber thermoplastics (SFTs). Section 3 provides an assessment of these models to determine their capabilities and limitations, and the developments needed for injection-molded LFTs. Section 4 then focuses on the development of a new fiber orientation model for LFTs. This model is termed the anisotropic rotary diffusion - reduced strain closure (ARD-RSC) model as it explores the concept of anisotropic rotary diffusion to capture the fiber-fiber interaction in long-fiber suspensions and uses the reduced strain closure method of Wang et al. to slow down the orientation kinetics in concentrated suspensions. In contrast to fiber orientation modeling, before this project, no standard model was developed to predict the fiber length distribution in molded fiber composites. Section 5 is therefore devoted to the development of a fiber length attrition model in the mold. Sections 6 and 7 address the implementations of the models in AMI, and the conclusions drawn from this work is presented in Section 8.

  4. Implementation of New Process Models for Tailored Polymer Composite Structures into Processing Software Packages

    International Nuclear Information System (INIS)

    This report describes the work conducted under the Cooperative Research and Development Agreement (CRADA) (Nr. 260) between the Pacific Northwest National Laboratory (PNNL) and Autodesk, Inc. to develop and implement process models for injection-molded long-fiber thermoplastics (LFTs) in processing software packages. The structure of this report is organized as follows. After the Introduction Section (Section 1), Section 2 summarizes the current fiber orientation models developed for injection-molded short-fiber thermoplastics (SFTs). Section 3 provides an assessment of these models to determine their capabilities and limitations, and the developments needed for injection-molded LFTs. Section 4 then focuses on the development of a new fiber orientation model for LFTs. This model is termed the anisotropic rotary diffusion - reduced strain closure (ARD-RSC) model as it explores the concept of anisotropic rotary diffusion to capture the fiber-fiber interaction in long-fiber suspensions and uses the reduced strain closure method of Wang et al. to slow down the orientation kinetics in concentrated suspensions. In contrast to fiber orientation modeling, before this project, no standard model was developed to predict the fiber length distribution in molded fiber composites. Section 5 is therefore devoted to the development of a fiber length attrition model in the mold. Sections 6 and 7 address the implementations of the models in AMI, and the conclusions drawn from this work is presented in Section 8.

  5. Thermoplastic film prevents proppant flowback

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen, P.D.; Weaver, J.D.; Parker, M.A.; King, D.G. [Halliburton Energy Services, Duncan, OK (United States)

    1996-02-05

    Thermoplastic film added to proppants is effective and economical for preventing proppant flowback after an hydraulic fracturing treatment. Most other methods, such as resin-coated proppant and fiber, for controlling proppant flowback have drawbacks that added to treatment costs by requiring long downtime, costly additives, or frequent equipment replacement. Thermoplastic film does not react chemically with fracturing fluids. After the proppant is placed in the fracture, the film strips intertwine with the proppant grains or at higher temperatures, the strips become adhesive and shrink forming consolidated clusters that hold open the newly created fractures and prevent proppant from flowing back. The low cost of the film means that the strips can be used throughout the fracturing job or in selected stages. The strips are compatible with fracturing fluid chemistry, including breakers and crosslinkers, and can be used in wells with a wide range of bottom hole temperatures. The end result is a well that can be brought back on-line in a short time with little proppant flowback. This paper reviews the cost benefits and performance of these proppants.

  6. Joining of thermoplastic substrates by microwaves

    Science.gov (United States)

    Paulauskas, Felix L. (Oak Ridge, TN); Meek, Thomas T. (Knoxville, TN)

    1997-01-01

    A method for joining two or more items having surfaces of thermoplastic material includes the steps of depositing an electrically-conductive material upon the thermoplastic surface of at least one of the items, and then placing the other of the two items adjacent the one item so that the deposited material is in intimate contact with the surfaces of both the one and the other items. The deposited material and the thermoplastic surfaces contacted thereby are then exposed to microwave radiation so that the thermoplastic surfaces in contact with the deposited material melt, and then pressure is applied to the two items so that the melted thermoplastic surfaces fuse to one another. Upon discontinuance of the exposure to the microwave energy, and after permitting the thermoplastic surfaces to cool from the melted condition, the two items are joined together by the fused thermoplastic surfaces. The deposited material has a thickness which is preferably no greater than a skin depth, .delta..sub.s, which is related to the frequency of the microwave radiation and characteristics of the deposited material in accordance with an equation.

  7. Influência da cera de carnaúba no comportamento reológico de misturas usadas na moldagem por injeção em baixa pressão / Influence of carnauba wax in the feedstock rheology used in low-pressure injection molding

    Scientific Electronic Library Online (English)

    P. A., Ourique; R. C. D., Cruz; J. E., Zorzi.

    2015-03-01

    Full Text Available A moldagem por injeção em baixa pressão (MIBP) tem algumas vantagens sobre outros métodos de conformação de peças cerâmicas com formas complexas. Dentre as vantagens estão os menores custos na produção de lotes pequenos e médios e o menor desgaste de moldes e equipamento. Neste trabalho, foi estudad [...] o o efeito de um dos aditivos orgânicos usados na MIBP, a cera de carnaúba, no comportamento reológico da mistura (feedstock). O pó cerâmico utilizado foi uma alumina, com tamanho de partícula em torno de 0,4 ?m. Com adições de 5% e 10% em peso de cera de carnaúba no veículo orgânico a viscosidade diminui significativamente, sendo bem mais acentuada com 10%, enquanto que, acima deste valor (15%), a viscosidade diminui, mas esta redução é menos pronunciada. Em contrapartida, em feedstocks sem a cera de carnaúba (0%), a viscosidade é tão elevada que praticamente inviabiliza a injeção em baixas pressões. Abstract in english The low-pressure injection molding (LPIM) has some advantages over other methods of forming ceramic parts with complex shapes. Among the advantages are the lower costs in the production of small and medium lots and less wear of molds and equipment. In this work, the effect of an organic additive use [...] d in LPIM been studied, carnauba wax, on the rheology of the mixture (feedstock). The ceramic powder used was alumina with particle size of about 0.4 micrometers. With additions of 5wt% and 10wt% of carnauba wax in the organic vehicle, viscosity decreases significantly, being much more pronounced at 10%, while above this value (15%), the viscosity decrease, but this reduction is less pronounced. In contrast, in feedstock without carnauba wax (0%), the viscosity is so high that the injection almost impossible at low pressures.

  8. Avaliação do comportamento térmico por DSC na região da pele e do núcleo de amostras injetadas de nanocompósitos de poliamida 6/argila organofílica / Polyamide 6/organoclay nanocomposites: evaluation of thermal behavior of injection molded samples by DSC

    Scientific Electronic Library Online (English)

    Renê A. da, Paz; Amanda M. D., Leite; Edcleide M., Araújo; Tomas J. A., Melo; Luiz A., Pessan.

    Full Text Available Nanocompósitos de poliamida 6/argila organofílica foram preparados pelo método de intercalação por fusão. A argila foi tratada com o sal quaternário de amônio (Cetremide) visando-se à obtenção da argila organofílica (OMMT). Esta foi caracterizada por fluorescência de raio X (FRX), Espectroscopia no [...] Infravermelho (FTIR) e Difração de Raio X (DRX). Os resultados dessas análises evidenciaram incorporação do sal entre as camadas da argila, tornando-a organofílica. Os nanocompósitos foram obtidos em extrusora de rosca dupla corrotacional, com 3% em peso de argila, e estes foram posteriormente injetados. A caracterização dos nanocompósitos por DRX mostrou uma estrutura esfoliada e/ou parcialmente esfoliada. As análises por Calorimetria Exploratória Diferencial (DSC) foram realizadas nas regiões da pele (superfície) e do núcleo (centro) dos corpos de prova e, mostraram as fases cristalinas ? e ? na pele e apenas a fase ? no núcleo e que o grau de cristalinidade na pele foi menor do que no núcleo. Abstract in english Polyamide 6/organoclay nanocomposites were prepared using the melt intercalation technique. The clay was treated with a quaternary ammonium salt (Cetremide) to obtain the organoclay (OMMT), which was characterized with X ray fluorescence (XRF), Infrared Spectroscopy (FTIR) and X ray diffraction (XRD [...] ). The results of these analyses showed the incorporation of the salt in the clay structure, confirming the organophilization. The nanocomposites were obtained in a co-rotational twin screw extruder with 3 wt. (%) of clay, and then the pellets were injection molded. The characterization by XRD of the nanocomposites showed an exfoliated and/or partially exfoliated structure. The analysis by DSC were made in the skin and core regions of the samples, showing the ? and ?-crystalline forms in the skin and only the ?-form in the core region. The degree of crystallinity in the skin was lower than in the core.

  9. Avaliação do comportamento térmico por DSC na região da pele e do núcleo de amostras injetadas de nanocompósitos de poliamida 6/argila organofílica Polyamide 6/organoclay nanocomposites: evaluation of thermal behavior of injection molded samples by DSC

    Directory of Open Access Journals (Sweden)

    Renê A. da Paz

    2010-01-01

    Full Text Available Nanocompósitos de poliamida 6/argila organofílica foram preparados pelo método de intercalação por fusão. A argila foi tratada com o sal quaternário de amônio (Cetremide visando-se à obtenção da argila organofílica (OMMT. Esta foi caracterizada por fluorescência de raio X (FRX, Espectroscopia no Infravermelho (FTIR e Difração de Raio X (DRX. Os resultados dessas análises evidenciaram incorporação do sal entre as camadas da argila, tornando-a organofílica. Os nanocompósitos foram obtidos em extrusora de rosca dupla corrotacional, com 3% em peso de argila, e estes foram posteriormente injetados. A caracterização dos nanocompósitos por DRX mostrou uma estrutura esfoliada e/ou parcialmente esfoliada. As análises por Calorimetria Exploratória Diferencial (DSC foram realizadas nas regiões da pele (superfície e do núcleo (centro dos corpos de prova e, mostraram as fases cristalinas ? e ? na pele e apenas a fase ? no núcleo e que o grau de cristalinidade na pele foi menor do que no núcleo.Polyamide 6/organoclay nanocomposites were prepared using the melt intercalation technique. The clay was treated with a quaternary ammonium salt (Cetremide to obtain the organoclay (OMMT, which was characterized with X ray fluorescence (XRF, Infrared Spectroscopy (FTIR and X ray diffraction (XRD. The results of these analyses showed the incorporation of the salt in the clay structure, confirming the organophilization. The nanocomposites were obtained in a co-rotational twin screw extruder with 3 wt. (% of clay, and then the pellets were injection molded. The characterization by XRD of the nanocomposites showed an exfoliated and/or partially exfoliated structure. The analysis by DSC were made in the skin and core regions of the samples, showing the ? and ?-crystalline forms in the skin and only the ?-form in the core region. The degree of crystallinity in the skin was lower than in the core.

  10. Highly stabilized optical frequency comb interferometer with a long fiber-based reference path towards arbitrary distance measurement.

    Science.gov (United States)

    Nakajima, Yoshiaki; Minoshima, Kaoru

    2015-10-01

    An optical frequency comb interferometer with a 342-m-long fiber-based optical reference path was developed. The long fiber-based reference path was stabilized to 10-12-order stability by using a fiber noise cancellation technique, and small temperature changes on the millikelvin order were detected by measuring an interferometric phase signal. Pulse number differences of 30 and 61 between the measurement and reference paths were determined precisely, with slight tuning of the 53.4 MHz repetition frequency. Moreover, with pulse number difference of 61, a 6.4-m-wide scanning for the relative pulse position is possible only by 1 MHz repetition frequency tuning, which makes pulses overlapped for arbitrary distance. Such wide-range high-precision delay length scanning can be used to measure arbitrary distances by using a highly stabilized long fiber-based reference path. PMID:26480113

  11. Vector rectangular-shape laser based on reduced graphene oxide interacting with long fiber taper

    CERN Document Server

    Gao, Lei; Zeng, Jing; Huang, Wei; Liu, Min

    2014-01-01

    A vector dual-wavelength rectangular-shape laser (RSL) based on a long fiber taper deposited with reduced graphene oxide is proposed, where the nonlinearity is enhanced due to large evanescent-field-interacting length and strong field confinement of a 8 mm fiber taper with a waist diameter of 4 micronmeters. Graphene flakes are deposited uniformly on the taper waist with light pressure effect, so this structure guarantees both excellent saturable absorption and high nonlinearity. The RSL with a repetition rate of 7.9 MHz exhibits fast polarization switching in two orthogonal polarization directions, and the temporal and spectral characteristics are investigated. The results suggest that the long taper-based graphene structure is an efficient choice for nonlinear devices.

  12. Thermoplastic blow molding of metals

    Directory of Open Access Journals (Sweden)

    Jan Schroers

    2011-01-01

    Full Text Available While plastics have revolutionized industrial design due to their versatile processability, their relatively low strength has hampered their use in structural components. On the other hand, while metals are the basis for strong structural components, the geometries into which they can be processed are rather limited. The “ideal” material would offer a desirable combination of superior structural properties and the ability to be precision (net shaped into complex geometries. Here we show that bulk metallic glasses (BMGs, which have superior mechanical properties, can be blow molded like plastics. The key to the enhanced processability of BMG formers is their amenability to thermoplastic forming. This allows complex BMG structures, some of which cannot be produced using any other metal process, to be net shaped precisely.

  13. Thermoplastic matrix composite processing model

    Science.gov (United States)

    Dara, P. H.; Loos, A. C.

    1985-01-01

    The effects the processing parameters pressure, temperature, and time have on the quality of continuous graphite fiber reinforced thermoplastic matrix composites were quantitatively accessed by defining the extent to which intimate contact and bond formation has occurred at successive ply interfaces. Two models are presented predicting the extents to which the ply interfaces have achieved intimate contact and cohesive strength. The models are based on experimental observation of compression molded laminates and neat resin conditions, respectively. Identified as the mechanism explaining the phenomenon by which the plies bond to themselves is the theory of autohesion (or self diffusion). Theoretical predictions from the Reptation Theory between autohesive strength and contact time are used to explain the effects of the processing parameters on the observed experimental strengths. The application of a time-temperature relationship for autohesive strength predictions is evaluated. A viscoelastic compression molding model of a tow was developed to explain the phenomenon by which the prepreg ply interfaces develop intimate contact.

  14. Comparison between Palm Oil Derivative and Commercial Thermo-Plastic Binder System on the Properties of the Stainless Steel 316L Sintered Parts

    Science.gov (United States)

    Ibrahim, R.; Azmirruddin, M.; Wei, G. C.; Fong, L. K.; Abdullah, N. I.; Omar, K.; Muhamad, M.; Muhamad, S.

    2010-03-01

    Binder system is one of the most important criteria for the powder injection molding (PIM) process. Failure in the selection of the binder system will affect on the final properties of the sintered parts. The objectives of this studied is to develop a novel binder system based on the local natural resources and environmental friendly binder system from palm oil derivative which is easily available and cheap in our country of Malaysia. The novel binder that has been developed will be replaced the commercial thermo-plastic binder system or as an alternative binder system. The results show that the physical and mechanical properties of the final sintered parts fulfill the Metal Powder Industries Federation (MPIF) standard 35 for PIM parts. The biocompatibility test using cell osteosarcoma (MG63) and vero fibroblastic also shows that the cell was successfully growth on the sintered stainless steel 316L parts indicate that the novel binder was not toxic. Therefore, the novel binder system based on palm oil derivative that has been developed as a binder system fulfills the important criteria for the binder system in PIM process.

  15. Efeito do processamento em misturas de alumina/ligantes orgânicos usadas na moldagem por injeção em baixa pressão Effect of processing variables in alumina/organic binders mixtures used in low-pressure injection molding

    Directory of Open Access Journals (Sweden)

    P . A. Ourique

    2013-03-01

    Full Text Available A moldagem por injeção em baixa pressão (MIBP é uma técnica que já vem sendo empregada na produção de peças cerâmicas com formas e geometrias complexas. A homogeneidade da mistura de ligantes orgânicos e pós cerâmicos é um fator determinante que deve ser controlado para minimizar a formação de imperfeições no processamento de feedstocks para MIBP. Defeitos típicos de processamento por MIBP, como bolhas de ar e aglomerados, geram gradientes de densidade nas misturas que, após conformação, possuem poucas possibilidades de remoção. Essas imperfeições comprometem o desempenho dos produtos obtidos por essa técnica. Este trabalho está focado na avaliação dessas heterogeneidades e como elas podem ser correlacionadas com a variação da densidade aparente e com o comportamento reológico dessas misturas. Para tanto, aluminas submicrométricas, como recebida e desaglomerada, foram adicionadas a uma mistura fundida de ligantes a base de parafinas, ceras e aditivos e processada em dois tipos diferentes de misturadores, com e sem o auxílio de vácuo. Foi observada a presença de aglomerados existentes na alumina como recebida, possivelmente gerados durante a etapa de calcinação. Também foi observado que o tipo de misturador e a aplicação ou não de vácuo durante a etapa final do processamento têm grande influência no tempo de mistura necessário para reduzir a viscosidade do feedstock para a injeção.The low-pressure injection molding (LPIM is a technique already being used in the production of ceramic parts with complex shapes and geometries. The homogeneity of the mixture of organic binder and ceramic powder is a determining factor which must be controlled to minimize defects formation while feedstock processing to LPIM. Typical defects of LPIM processing, such as air bubbles and agglomerates, generate density gradients in the mixtures, which, after shaping, have little possibility of removal. These imperfections compromise the performance of the products obtained by this technique. This work is focused on the evaluation of these inhomogeneities and how they can be correlated with density variation and the rheological behavior of these mixtures. Therefore, submicrometer aluminas, as received and deagglomerated, were added to a molten mixture of paraffin based binders, waxes and additives and processed in two different mixers, with and without vacuum. The presence of alumina agglomerates was observed in the powder as received, possibly generated during the calcination step. It was also observed that the type of mixer and vacuum application or not during the final processing step, has a major influence on the mixing time required to reduce the viscosity of the feedstock for injection.

  16. Efeito do processamento em misturas de alumina/ligantes orgânicos usadas na moldagem por injeção em baixa pressão / Effect of processing variables in alumina/organic binders mixtures used in low-pressure injection molding

    Scientific Electronic Library Online (English)

    P . A., Ourique; A., Susin Neto; S. G., Echeverrigaray; R. C. D., Cruz; J. E., Zorzi.

    2013-03-01

    Full Text Available A moldagem por injeção em baixa pressão (MIBP) é uma técnica que já vem sendo empregada na produção de peças cerâmicas com formas e geometrias complexas. A homogeneidade da mistura de ligantes orgânicos e pós cerâmicos é um fator determinante que deve ser controlado para minimizar a formação de impe [...] rfeições no processamento de feedstocks para MIBP. Defeitos típicos de processamento por MIBP, como bolhas de ar e aglomerados, geram gradientes de densidade nas misturas que, após conformação, possuem poucas possibilidades de remoção. Essas imperfeições comprometem o desempenho dos produtos obtidos por essa técnica. Este trabalho está focado na avaliação dessas heterogeneidades e como elas podem ser correlacionadas com a variação da densidade aparente e com o comportamento reológico dessas misturas. Para tanto, aluminas submicrométricas, como recebida e desaglomerada, foram adicionadas a uma mistura fundida de ligantes a base de parafinas, ceras e aditivos e processada em dois tipos diferentes de misturadores, com e sem o auxílio de vácuo. Foi observada a presença de aglomerados existentes na alumina como recebida, possivelmente gerados durante a etapa de calcinação. Também foi observado que o tipo de misturador e a aplicação ou não de vácuo durante a etapa final do processamento têm grande influência no tempo de mistura necessário para reduzir a viscosidade do feedstock para a injeção. Abstract in english The low-pressure injection molding (LPIM) is a technique already being used in the production of ceramic parts with complex shapes and geometries. The homogeneity of the mixture of organic binder and ceramic powder is a determining factor which must be controlled to minimize defects formation while [...] feedstock processing to LPIM. Typical defects of LPIM processing, such as air bubbles and agglomerates, generate density gradients in the mixtures, which, after shaping, have little possibility of removal. These imperfections compromise the performance of the products obtained by this technique. This work is focused on the evaluation of these inhomogeneities and how they can be correlated with density variation and the rheological behavior of these mixtures. Therefore, submicrometer aluminas, as received and deagglomerated, were added to a molten mixture of paraffin based binders, waxes and additives and processed in two different mixers, with and without vacuum. The presence of alumina agglomerates was observed in the powder as received, possibly generated during the calcination step. It was also observed that the type of mixer and vacuum application or not during the final processing step, has a major influence on the mixing time required to reduce the viscosity of the feedstock for injection.

  17. Os efeitos no empacotamento de peças injetadas para diferentes espessuras de canais de ataque (gate) tipo filme / The effects of injection molding packing for different thickness of film type gates

    Scientific Electronic Library Online (English)

    Altair Carlos da, Cruz; Ricardo Pedro, Bom.

    Full Text Available Este trabalho tem como objetivo determinar a variação da massa de corpos de prova fabricados pelo processo de moldagem por injeção. A partir de equações que tratam da solidificação de placas, foi correlacionado o tempo de solidificação do canal de ataque com o tempo de início de estabilização da mas [...] sa do corpo de prova obtido na cavidade do molde de injeção. Para o desenvolvimento experimental foi utilizado o copolímero estireno-acrilonitrila (SAN). Para a realização dos corpos de prova, foi necessário secar o material, fixar alguns parâmetros de processo, tais como pressão de injeção, tempo de injeção, temperatura nos diferentes estágios e temperatura do molde. Os parâmetros variáveis foram o tempo e a pressão de recalque. Com os corpos de prova prontos, suas massas foram determinadas, inicialmente, para o conjunto corpo de prova e canais de distribuição; em seguida, para o corpo de prova individualmente, sendo este previamente separado dos canais de distribuição. A variação da massa dos corpos de prova para as diferentes pressões de recalque e seus respectivos desvios-padrão foram representadas graficamente em função da variação do tempo de recalque. A massa do corpo de prova começou a estabilizar a partir de um certo tempo. Este tempo foi determinado graficamente e ficou coerente com os resultados dos tempos calculados a partir de equações que tratam do resfriamento de placas. Abstract in english The aim of his study is to determine the model test bulk used by the injection molding process. The mathematical model governing by the plate solidification will indicate the solidification time of the gate together with the beginning of the stabilization of the cavity bulk. In this test a styrene-a [...] crylonitrile copolymer (SAN) will be used. In order to develop the model tests, the material had to be dried to establish some parameters like: injection pressure, injection time, temperature of the different stages as well as moulding temperature. The variable parameters were the time and the discharge pressure. As the model tests were fully develoved, bulks were determined, first for the mould cavity and branches and next for the single cavity which was separated from the branches. The variation of the cavity bulk for the different discharge pressures and the standard deviation were graphically represented due to the time deviation of the discharge. The results showed that the time the bulk cavity begins to stabilize matches the calculated time, for the non-flow temperature, as well as the glass part temperature, the discharge pressure.

  18. Moldagem por injeção em baixa pressão de peças complexas de cerâmicas avançadas produzidas com pós submicrométricos / Low-pressure injection molding of complex parts of advanced ceramic produced with fine powder

    Scientific Electronic Library Online (English)

    J. E., Zorzi; C. A., Perottoni; J. A. H. da, Jornada.

    2004-09-01

    Full Text Available A moldagem por injeção em baixa pressão (MIBP) tem constituído, nos últimos anos, uma excelente alternativa para a produção de pequenos lotes de peças cerâmicas diversificadas e com formas complexas. Esta técnica de conformação é relativamente simples e barata, mas apresenta diversos problemas na et [...] apa de extração dos ligantes, principalmente quando o pó cerâmico é muito fino e as peças possuem grande seção transversal. Neste trabalho é descrita uma metodologia específica para a produção de peças cerâmicas por moldagem por injeção a baixa pressão de alumina submicrométrica (0,4 mim), incluindo a formulação da mistura para injeção, bem como detalhes do processo de extração dos ligantes orgânicos utilizados na moldagem. Para o desenvolvimento deste processo fez-se necessário (i) entender melhor o processo de MIBP, (ii) desenvolver a formulação da mistura de pó cerâmico e aditivos orgânicos, (iii) confeccionar moldes adequados para a injeção a baixas pressões e (iv) otimizar os parâmetros de injeção. A metodologia desenvolvida neste trabalho, possibilita a confecção de peças cerâmicas complexas, com seção transversal relativamente grande, permitindo uma produção robusta de pequenos lotes de peças cerâmicas diversificadas com ótima qualidade e excelente reprodutibilidade. Abstract in english In the past years, low-pressure injection molding (LPIM) has been a good alternative for the production of small batches of diversified complex shapes ceramic parts. This molding technique is relatively simple and cheap, but presents several problems related to debinding, especially for fine ceramic [...] particle, and large cross-section ceramic pieces. In this work, we present a metodology for the production of ceramic parts based on the LPIM of submicrometer-sized alumina powder (0.4 mum). The binder formulation is described, as well as the details of the debinding stage. For the development of this process it was necessary (i) to achieve a better understanding of the LPIM process, (ii) develop the binder formulation and to find the better proportion for the binder plus ceramic powder mixture, (iii) to prepare molds suitable for LPIM and (iv) to optimize the injection parameters. The procedure here reported makes it possible to produce complex shape ceramic parts, with relatively large cross-section, allowing the robust production of small batches of diversified ceramic parts, with high quality and excellent reproducibility.

  19. Laser beam welding of thermoplastics

    Science.gov (United States)

    Russek, Ulrich A.; Palmen, A.; Staub, H.; Poehler, J.; Wenzlau, C.; Otto, G.; Poggel, M.; Koeppe, A.; Kind, H.

    2003-07-01

    Current product development showing an ever shrinking physical volume is asking for new, reliable joining technologies. Laser beam technologies conceal innovative solutions to overcome limitations of conventional joining technologies. Laser beam welding of thermoplastics offers several process technical advantages. The joining energy is fed contact-less into the joining area, avoiding mechanical stress and thermal load to the joining partners. The energy is supplied spatially (seam width on the order of 100 ?m) and timely (interaction time on the order of ms) very well defined. Different process strategies are possible leading to flexibility, product adapted irradiation, short process times and high quality weld seams as well as to high integration abilities and automation potentials. During the joining process no vibration, no thermal stress, no particle release takes place. Therefore, destruction of mechanically and electronically highly sensitive components, such as microelectronics, is avoided. The work place pollution is neglectable compared to other joining technologies, such as gluing (fume) or ultrasonic welding (noise, pieces of fluff). Not only micro-components can be welded in a reproducible way but also macro-components while obtaining a hermetic sealing with good optical appearance. In this publication firstly, an overview concerning process technical basis, aspects and challenges is given. Next, results concerning laser penetration welding of polymers using high power diode lasers are presented, while comparing contour and simultaneous welding by experimental results and the on-line process monitoring.

  20. Development of Lignin-Based Polyurethane Thermoplastics

    Energy Technology Data Exchange (ETDEWEB)

    Saito, Tomonori [ORNL; Perkins, Joshua H [ORNL; Jackson, Daniel C [ORNL; Trammell, Neil E [ORNL; Hunt, Marcus A [ORNL; Naskar, Amit K [ORNL

    2013-01-01

    In our continued effort to develop value-added thermoplastics from lignin, here we report utilizing a tailored feedstock to synthesize mechanically robust thermoplastic polyurethanes at very high lignin contents (75 65 wt %). The molecular weight and glass transition temperature (Tg) of lignin were altered through cross-linking with formaldehyde. The cross-linked lignin was coupled with diisocyanate-based telechelic polybutadiene as a network-forming soft segment. The appearance of two Tg s, around 35 and 154 C, for the polyurethanes indicates the existence of two-phase morphology, a characteristic of thermoplastic copolymers. A calculated Flory-Huggins interaction parameter of 7.71 also suggests phase immiscibility in the synthesized lignin polyurethanes. An increase in lignin loading increased the modulus, and an increase in crosslink-density increased the modulus in the rubbery plateau region of the thermoplastic. This path for synthesis of novel lignin-based polyurethane thermoplastics provides a design tool for high performance lignin-based biopolymers.

  1. Assembly injection moulding joins metal and thermoplastics; Montagespritzgiessen verbindet Metall und Thermoplast

    Energy Technology Data Exchange (ETDEWEB)

    Drummer, Dietmar; Meister, Steve [Erlangen-Nuernberg Univ., Erlangen (Germany). Lehrstuhl fuer Kunststofftechnik; Reichart, Marc [HBW Gubesch Kunststoff Engineering GmbH, Wilhelmsdorf (Germany)

    2010-03-08

    Automotive safety restraint system components increasingly use flexible styrenic and olefinic TPEs. With continued evolution in automotive interior design and performance requirements, demands on material technology are concomitantly rising. A growing trend towards molded in color solutions with low gloss aesthetics require TPE materials with ery low gloss, improved scratch resistance, and low temperature ductility. Innovations utilizing Teknor Apex's compounding technology have enabled the development of low gloss styrenic elastomers for airbag door applications that provide an optimized combination of low temperature performance, surface aesthetics (low gloss and improved scratch resistance), and ease of processing. This paper highlights the salient features of these new compounds and the effect of injection molding condition on the gloss at the surface of the cover.

  2. Evolução da morfologia de fases de blendas PA6/AES em extrusora de dupla rosca e moldagem por injeção / Evolution of phase morphology of PA6/AES blends during the twin screw extrusion and injection molding processes

    Scientific Electronic Library Online (English)

    Adriane, Bassani; Elias, Hage Jr; Luiz A., Pessan; Ana V, Machado; José A., Covas.

    2005-07-01

    Full Text Available A evolução da morfologia de fases em blendas não reativas e reativas de poliamida-6 com copolímero de acrilonitrila/EPDM/estireno (AES) em uma extrusora de rosca dupla co-rotacional foi investigada. A evolução da morfologia de fases ao longo da extrusora de rosca dupla foi monitorada através da cole [...] ta de pequenas amostras em válvulas no barril da extrusora e caracterização por microscopia eletrônica de transmissão (MET). Foram utilizados como compatibilizantes reativos os copolímeros metacrilato de metila-co-anidrido maleico (MMA-MA) e metacrilato de metila-co-metacrilato de glicidila (MMA-GMA). Os grupos anidrido maleico e epóxi nos copolímeros podem reagir com os grupos finais de cadeia da poliamida durante o processamento no estado fundido e melhorar a interação na interfase do sistema PA6/AES. A blenda PA6/AES não compatibilizada apresentou uma morfologia grosseira de fases onde a fase AES não está bem dispersa na matriz de PA6 devido à falta de interações adequadas entre os componentes da blenda. A adição do compatibilizante MMA-GMA não proporcionou boa dispersão de fases e não melhorou as propriedades mecânicas da blenda, provavelmente porque as possíveis reações no sistema são lentas e podem não ocorrer na extrusora. Por outro lado, a blenda compatibilizada com o copolímero MMA-MA apresentou uma excelente resistência ao impacto à temperatura ambiente e uma diminuição na temperatura de transição dúctil-frágil. As partículas de AES apresentam-se muito mais refinadas e sofrem uma redução significativa em seu tamanho já no início do processo de extrusão. A morfologia observada nas amostras injetadas apresentou uma boa correlação com as propriedades mecânicas obtidas. Abstract in english The evolution of phase morphology in non-reactive vs reactive blends with polyamide and ethylene-propylene-diene elastomer grafted with styrene-acrylonitrile copolymer (AES) in a co-rotating twin-screw extruder was investigated. The morphological evolution of these blends along a twin-screw extruder [...] was monitored by quickly collecting small samples from the melt at specific extruder barrel locations and characterizing them with a transmission electron microscope (TEM). The copolymers methyl methacrylate-co-maleic anhydride (MMA-MA) and methyl methacrylate-co-glycidyl methacrylate (MMA-GMA) were used as compatibilizing agents. The maleic anhydride and the epoxy groups of the copolymers can react with the polyamide end groups during melt processing and improve the interphase interaction in the PA6/AES system. The uncompatibilized blends showed a coarse phase morphology where the AES phase is not well dispersed in the PA6 matrix due to lack of adequate interaction between the components. The addition of MMA-GMA compatibilizer neither promoted good phase dispersion or improved the mechanical properties of the blends, probably because the possible reactions are very slow and may not occur inside the extruder. On the other hand, the addition of the MMA-MA copolymer promotes better impact strength and good phase dispersion in the blend. The AES particles undergo significant reduction in the first stages of the mixture inside the extruder. The morphology observed for the injection molded specimens was correlated with the mechanical properties.

  3. Evolução da morfologia de fases de blendas PA6/AES em extrusora de dupla rosca e moldagem por injeção Evolution of phase morphology of PA6/AES blends during the twin screw extrusion and injection molding processes

    Directory of Open Access Journals (Sweden)

    Adriane Bassani

    2005-07-01

    Full Text Available A evolução da morfologia de fases em blendas não reativas e reativas de poliamida-6 com copolímero de acrilonitrila/EPDM/estireno (AES em uma extrusora de rosca dupla co-rotacional foi investigada. A evolução da morfologia de fases ao longo da extrusora de rosca dupla foi monitorada através da coleta de pequenas amostras em válvulas no barril da extrusora e caracterização por microscopia eletrônica de transmissão (MET. Foram utilizados como compatibilizantes reativos os copolímeros metacrilato de metila-co-anidrido maleico (MMA-MA e metacrilato de metila-co-metacrilato de glicidila (MMA-GMA. Os grupos anidrido maleico e epóxi nos copolímeros podem reagir com os grupos finais de cadeia da poliamida durante o processamento no estado fundido e melhorar a interação na interfase do sistema PA6/AES. A blenda PA6/AES não compatibilizada apresentou uma morfologia grosseira de fases onde a fase AES não está bem dispersa na matriz de PA6 devido à falta de interações adequadas entre os componentes da blenda. A adição do compatibilizante MMA-GMA não proporcionou boa dispersão de fases e não melhorou as propriedades mecânicas da blenda, provavelmente porque as possíveis reações no sistema são lentas e podem não ocorrer na extrusora. Por outro lado, a blenda compatibilizada com o copolímero MMA-MA apresentou uma excelente resistência ao impacto à temperatura ambiente e uma diminuição na temperatura de transição dúctil-frágil. As partículas de AES apresentam-se muito mais refinadas e sofrem uma redução significativa em seu tamanho já no início do processo de extrusão. A morfologia observada nas amostras injetadas apresentou uma boa correlação com as propriedades mecânicas obtidas.The evolution of phase morphology in non-reactive vs reactive blends with polyamide and ethylene-propylene-diene elastomer grafted with styrene-acrylonitrile copolymer (AES in a co-rotating twin-screw extruder was investigated. The morphological evolution of these blends along a twin-screw extruder was monitored by quickly collecting small samples from the melt at specific extruder barrel locations and characterizing them with a transmission electron microscope (TEM. The copolymers methyl methacrylate-co-maleic anhydride (MMA-MA and methyl methacrylate-co-glycidyl methacrylate (MMA-GMA were used as compatibilizing agents. The maleic anhydride and the epoxy groups of the copolymers can react with the polyamide end groups during melt processing and improve the interphase interaction in the PA6/AES system. The uncompatibilized blends showed a coarse phase morphology where the AES phase is not well dispersed in the PA6 matrix due to lack of adequate interaction between the components. The addition of MMA-GMA compatibilizer neither promoted good phase dispersion or improved the mechanical properties of the blends, probably because the possible reactions are very slow and may not occur inside the extruder. On the other hand, the addition of the MMA-MA copolymer promotes better impact strength and good phase dispersion in the blend. The AES particles undergo significant reduction in the first stages of the mixture inside the extruder. The morphology observed for the injection molded specimens was correlated with the mechanical properties.

  4. Ultrasonic Welding of Graphite/Thermoplastic Composite

    Science.gov (United States)

    Hardy, S. S.; Page, D. B.

    1982-01-01

    Ultrasonic welding of graphite/thermoplastic composite materials eliminates need for fasteners (which require drilling or punching, add weight, and degrade stiffness) and can be totally automated in beam fabrication and assembly jigs. Feasibility of technique has been demonstrated in laboratory tests which show that neither angular orientation nor vacuum affect weld quality.

  5. Attribute based selection of thermoplastic resin for vacuum infusion process

    DEFF Research Database (Denmark)

    Prabhakaran, R.T. Durai; Lystrup, Aage; Løgstrup Andersen, Tom

    2011-01-01

    The composite industry looks toward a new material system (resins) based on thermoplastic polymers for the vacuum infusion process, similar to the infusion process using thermosetting polymers. A large number of thermoplastics are available in the market with a variety of properties suitable for different engineering applications, and few of those are available in a not yet polymerised form suitable for resin infusion. The proper selection of a new resin system among these thermoplastic polymers...

  6. Thermoplastic microcantilevers fabricated by nanoimprint lithography

    DEFF Research Database (Denmark)

    Greve, Anders; Keller, Stephan Urs; Vig, Asger Laurberg; Kristensen, Anders; Larsson, David; Yvind, Kresten; Hvam, Jørn Märcher; Cerruti, Marta; Majumdar, Arunava; Boisen, Anja

    2010-01-01

    Nanoimprint lithography has been exploited to fabricate micrometre-sized cantilevers in thermoplastic. This technique allows for very well defined microcantilevers and gives the possibility of embedding structures into the cantilever surface. The microcantilevers are fabricated in TOPAS and are up to 500 ?m long, 100 ?m wide, and 4.5 ?m thick. Some of the cantilevers have built-in ripple surface structures with heights of 800 nm and pitches of 4 ?m. The yield for the cantilever fabrication is 95...

  7. Glass transition temperature of thermoplastic starches

    Directory of Open Access Journals (Sweden)

    M. Mitrus

    2005-09-01

    Full Text Available Thermoplastic starch was produced by mixing potato starch and glycerol in a single screw extruder. The glass transition temperatures of the materials obtained were measured by differential scanning calorimetry (DSC. Both the influence of extruder parameters and material parameters, such as moisture and glycerol content and amyloses/amylopectine ratio were investigated. Repeated extrusion cycles affect the glass transition temperature only to a very small extent.

  8. Glass transition temperature of thermoplastic starches

    OpenAIRE

    M. Mitrus

    2005-01-01

    Thermoplastic starch was produced by mixing potato starch and glycerol in a single screw extruder. The glass transition temperatures of the materials obtained were measured by differential scanning calorimetry (DSC). Both the influence of extruder parameters and material parameters, such as moisture and glycerol content and amyloses/amylopectine ratio were investigated. Repeated extrusion cycles affect the glass transition temperature only to a very small extent.

  9. Continuous welding modeling of thermoplastic matrix composites

    OpenAIRE

    Nicodeau, Célia

    2005-01-01

    The automated two placement process developed in the aircraft industry is an emerging technique for manufacturing continuous fiber-reinforced thermoplastic parts. Our objective is to understand the physical mechanisms taking place in the APC-2 (carbon/PEEK) welding phenomenon in order to model and improve the process. The originality of the study was to develop a process thermal model at a macroscopic scale and simultaneously to deeply study phenomenon at a macromolecular scale. The 2D therma...

  10. Silane Crosslinked Wood-Thermoplastic Composites

    OpenAIRE

    Bengtsson, Magnus

    2005-01-01

    Wood-thermoplastic composites are a more environmental friendly alternative for pressure-treated lumber but can also replace engineering plastic products. These composites have been on the market for more than ten years now and have mainly been used in building and automotive applications. The use of these materials has shown that long-term properties, durability, and toughness are the main problems. The aim of this study was to investigate if silane crosslinking could be one way of...

  11. An afterloading brachytherapy device utilizing thermoplastic material

    International Nuclear Information System (INIS)

    An afterloading brachytherapy device for treatment of residual cancer in an enucleated orbit with two cesium-137 sources was designed using a thermoplastic material, Aquaplast. The device consists of a face-mask support held in place with elastic bands around the head and an acrylic afterloading applicator. The device is very easy to make, holds the sources firmly in place, allows full mobility of the patient, and gives excellent dose distribution to the target area. It was easily tolerated by a 7-year-old child during the 50 h of treatment. (author). 3 refs.; 4 figs

  12. Radiation effects on carbon fiber reinforced thermoplastics

    International Nuclear Information System (INIS)

    Polyether-ether-ketone (PEEK) and a newly developed thermoplastic polyimide ''new-TPI'' were applied to carbon fiber reinforced plastic (CFRP) as a matrix resin. PEEK and new-TPI showed excellent resistance over 50 MGy to electron irradiation and the crosslinking proceeded predominantly by irradiation. The changes in mechanical properties induced by electron irradiation of the CFRP with the two resins were examined at various temperatures. The flexural strength and modulus measured at -196 and 25 degree C were scarcely affected up to 120 MGy and both the values measured at high temperature were increased with dose

  13. Supportability evaluation of thermoplastic and thermoset composites

    Science.gov (United States)

    Chanani, G. R.; Boldi, D.; Cramer, S. G.; Heimerdinger, M. W.

    1990-01-01

    Nearly 300 advanced composite components manufactured by Northrop Corporation are flying on U.S. Air Force and U.S. Navy supersonic aircraft as part of a three-year Air Force/Navy/Northrop supportability evaluation. Both thermoplastic and high-temperature thermoset composites were evaluated for their in-service performance on 48 USAF and Navy F-5E fighter and USAFT-38 trainer aircraft in the first large-scale, long-term maintenance evaluation of these advanced materials. Northrop manufactured four types of doors for the project-avionics bay access, oil fill, inlet duct inspection, and a main landing gear door. The doors are made of PEEK (polyetheretherketone) thermoplastic, which is tougher and potentially less expensive to manufacture than conventional composites; and 5250-3 BMI (bismaleimide) thermoset, which is manufactured like a conventional epoxy composite but can withstand higher service temperatures. Results obtained so far indicate that both the BMI and PEEK are durable with PEEK being somewhat better than BMI.

  14. Polyether Based Thermoplastic Polyurethane Melt Blown Nonwovens

    Directory of Open Access Journals (Sweden)

    Terezie Zapletalova

    2006-08-01

    Full Text Available A series of melt blown samples were produced from three hardness grades of ether based thermoplastic polyurethane elastomers (TPU. The fabrics were tested to investigate their structure-property relationship in a melt blown process. Solution viscosities of the web were only 20-26% of there original values indicating a large loss in polymer molecular weight during melt blowing. Fiber diameter distributions measured on melt blown samples were found comparable to those made with more conventional polymers. The fiber orientation distribution functions (ODF suggest slight fiber orientation in machine direction. Tensile and elongation properties depended on die-to-collector distance (DCD, polymer hardness and fiber ODF. A strong relationship between the tensile strength and die-to-collector distance was identified and attributed to reduced interfiber adhesion in the web with increasing DCD. The reduction in adhesion was attributed to greater extents of solidification before reaching the forming belt for longer DCDs. This paper is the first in a series relating the influence of the melt blowing process parameters on the polymer properties and the nonwoven fabric properties for block thermoplastic elastomers.

  15. Thermoplastic microcantilevers fabricated by nanoimprint lithography

    International Nuclear Information System (INIS)

    Nanoimprint lithography has been exploited to fabricate micrometre-sized cantilevers in thermoplastic. This technique allows for very well defined microcantilevers and gives the possibility of embedding structures into the cantilever surface. The microcantilevers are fabricated in TOPAS and are up to 500 µm long, 100 µm wide, and 4.5 µm thick. Some of the cantilevers have built-in ripple surface structures with heights of 800 nm and pitches of 4 µm. The yield for the cantilever fabrication is 95% and the initial out-of-plane bending is below 10 µm. The stiffness of the cantilevers is measured by deflecting the cantilever with a well-characterized AFM probe. An average stiffness of 61.3 mN m?1 is found. Preliminary tests with water vapour indicate that the microcantilevers can be used directly for vapour sensing applications and illustrate the influence of surface structuring of the cantilevers

  16. Thermoplastic starch films reinforced with talc nanoparticles.

    Science.gov (United States)

    Castillo, Luciana; López, Olivia; López, Cintia; Zaritzky, Noemí; García, M Alejandra; Barbosa, Silvia; Villar, Marcelo

    2013-06-20

    Nanocomposite films of thermoplastic corn starch (TPS) with talc particles were obtained by thermo-compression in order to study the effect of filler on structure, optical, and thermal properties. Talc increased the films rigid phase, thus their cross-sections resulted more irregular. Talc preferential orientation within matrix and good compatibility between particles and TPS was observed by SEM. Slight crystalline structure changes in TPS matrix were measured by XRD and DSC, due to talc nucleating effect. Randomly dispersed talc nanoagglomerates and individual platelets were assessed by TEM. Laminar morphology and nano-sized particles allowed that nanocomposite films were optically transparent. TPS-talc films resulted heterogeneous materials, presenting domains rich in glycerol and others rich in starch. Talc incorporation higher than 3%, w/w increased softening resistance of the nanocomposites as stated by DMA. Relaxation temperatures of glycerol-rich phase shifted to higher values since talc reduces the mobility of starch chains. PMID:23648028

  17. Monitoring impact damaging of thermoplastic composites

    Science.gov (United States)

    Boccardi, S.; Carlomagno, G. M.; Meola, C.; Russo, P.; Simeoli, G.

    2015-11-01

    Thermoplastic composites are becoming ever more attractive also to the aeronautical sector. The main advantage lies in the possibility to modify the interface strength of polypropylene based laminates by adjusting the composition of the matrix. Understanding these aspects is of great importance to establish a possible link between the material toughness and the matrix ingredients. The aim of the present work is to ascertain the ability of an infrared imaging device to visualize any change, in the material behaviour to low energy impact, induced by changes in the matrix composition. Attention is given to image processing algorithms; in particular, an original procedure to measure the extension of the impact-affected area is proposed.

  18. Thermoplastic Ribbon-Ply Bonding Model

    Science.gov (United States)

    Hinkley, Jeffrey A.; Marchello, Joseph M.; Messier, Bernadette C.

    1996-01-01

    The aim of the present work was to identify key variables in rapid weldbonding of thermoplastic tow (ribbon) and their relationship to matrix polymer properties and to ribbon microstructure. Theoretical models for viscosity, establishment of ply-ply contact, instantaneous (Velcro) bonding, molecular interdiffusion (healing), void growth suppression, and gap filling were reviewed and synthesized. Consideration of the theoretical bonding mechanisms and length scales and of the experimental weld/peel data allow the prediction of such quantities as the time and pressure required to achieve good contact between a ribbon and a flat substrate, the time dependence of bond strength, pressures needed to prevent void growth from dissolved moisture and conditions for filling gaps and smoothing overlaps.

  19. Ultrasonic Assisted Consolidation of Commingled Thermoplastic/Glass Fiber Rovings

    OpenAIRE

    Lionetto, Francesca; Dell’Anna, Riccardo; Montagna, Francesco; Maffezzoli, Alfonso

    2015-01-01

    Thermoplastic matrix composites are finding new applications in different industrial area, thanks to their intrinsic advantages related to environmental compatibility and processability. The approach presented in this work consists in the development of a technology for the simultaneous deposition and consolidation of commingled thermoplastic rovings through to the application of high energy ultrasound. An experimental equipment, integrating both fiber impregnation and ply consolidation in a ...

  20. Properties and performance of flax yarn/thermoplastic polyester composites

    DEFF Research Database (Denmark)

    Madsen, Bo; Mehmood, Shahid

    2012-01-01

    Aiming at demonstrating the potential of unidirectional natural fiber-reinforced thermoplastic composites in structural applications, textile flax yarn/thermoplastic polyester composites with variable fiber volume fractions have been manufactured by a filament-winding process followed by a vacuum-assisted compression molding process. The microstructure of the composites shows that the flax fiber yarns are well impregnated by the polyester matrix, and this supports the measured low porosity conte...

  1. Synthesis and characterization of energetic thermoplastic elastomers for propellant formulations

    OpenAIRE

    Aparecida M. Kawamoto; José Irineu S.Oliveira; Rita de Cássia L. Dutra; Luis Claudio Rezende; Thomas Keicher; Horst Krause

    2009-01-01

    Synthesis and characterization of energetic ABA-type thermoplastic elastomers for propellant formulations has been carried out. Following the working plan elaborated, the synthesis and characterization of Poly 3- bromomethyl-3-methyl oxetane (PolyBrMMO), Poly 3- azidomethyl-3-methyl oxetane (PolyAMMO), Poly 3,3-bis-azidomethyl oxetane (PolyBAMO) and Copolymer PolyBAMO/AMMO (by TDI end capping) has been successfully performed. The thermoplastic elastomers (TPEs) were synthesized using the chai...

  2. Crosslinking of thermoplastics by gamma-irradiation in industrial conditions

    International Nuclear Information System (INIS)

    The material properties of thermoplastics can be improved by irradiation-induced crosslinking. Polyethylene crosslinked by radiation exhibits higher resistance to chemicals and low susceptibility to stress cracking, cold flow and sub-zero impact damage. Mechanical properties at elevated temperatures and heat distortion temperatures are increased. Using the shape-memory effect, it is also possible to produce heat-shrunk products from crosslinked thermoplastics. (Author)

  3. Characteristics and utilization of thermoplastic elastomers (TPE)-an overview

    Energy Technology Data Exchange (ETDEWEB)

    Roestamsjah [R and D Center for Applied Chemistry, Indonesian Inst. of Sciences (Indonesia)

    1998-10-01

    The unique feature of thermoplastic elastomer, the combining of processing characteristics of thermoplastics with the physical properties of vulcanized rubber is reviewed. Highlights of TPE and its characteristics is aimed to generate interest in TPE, where SANS technique will be utilized for its characterization. The topics discussed include rubber elasticity, state of aggregation of polymers, microseparation in block copolymer system, application of TPE, and finally some notes in developing interest in TPE and SANS in Indonesia. (author)

  4. Construction of a holographic deblurring filter using a thermoplastic film

    Science.gov (United States)

    Minemoto, T.; Takahashi, T.

    1981-08-01

    A holographic filter for the restoration of images blurred by linear motion was recorded on a thermoplastic film using an electron beam recording device. In the recording device, a microprocessor was used to make the filter by compensating for the nonlinearity of the thermoplastic film, and the development of the film was correctly controlled by using the light diffracted from it. The diffraction efficiency of the realized filter agreed well with the theoretical function of the filter.

  5. Study on resistance welding of glass fiber reinforced thermoplastic composites

    International Nuclear Information System (INIS)

    Highlights: ? A Taguchi technique was used to design the experimental plan. ? TPC were joined by Resistance welding setup. ? TPC joints were characterized by mechanical and metallurgical study. ? Statistical method was used for parameter optimization of TPC joining. -- Abstract: Thermoplastic polymer industry has expanded a new impact with the introduction of Eco-friendly thermoplastic matrix composites (TPCs), which finds applications in medical, aerospace, electronic and automotive areas. Joints of non-conductive thermoplastic composite materials are processed by Resistance Welding (RW) by incorporating a conductive corrosion resistive conductive material, as an interlayer. Glass fiber reinforced polypropylene thermoplastic composite sheets were used for this study. The experimental set-up for resistance welding was fabricated. Welding current, clamping pressure and welding duration (Time) are the control parameters. The joining trials on composites were carried out using Taguchi method to reduce time and cost effective experimental studies. The effect of parameters which govern the quality of resistance welding of thermoplastic composites is also emphasized in this work. The purpose of this study is to determine the optimum process parameters for RW. The joints obtained were analyzed microscopically; it revealed the good integration of thermoplastic composite with the interlayer material. The mechanical strength of the joints is tested through lap shear strength testing.

  6. Novel polymer blends with thermoplastic starch

    Science.gov (United States)

    Taghizadeh, Ata

    A new class of polymers known as "bioplastics" has emerged and is expanding rapidly. This class consists of polymers that are either bio-based or biodegradable, or both. Among these, polysaccharides, namely starch, are of great interest for several reasons. By gelatinizing starch via plasticizers, it can be processed in the same way as thermoplastic polymers with conventional processing equipment. Hence, these bio-based and biodegradable plastics, with their low source and refinery costs, as well as relatively easy processability, have made them ideal candidates for incorporation into various current plastic products. Four different plasticizers have been chosen here for gelatinization of thermoplastic starch (TPS): glycerol, sorbitol, diglycerol and polyglycerol, with the latter two being used for the first time in such a process. Two methodological categories are used. The first involves a calorimetric method (Differential Scanning Calorimetry) as well as optical microscopy; these are "static" methods where no shear is applied A wide range of starch/water/plasticizer compositions were prepared to explore the gelatinization regime for each plasticizer. The onset and conclusion gelatinization temperatures for sorbitol and glycerol were found to be in the same vicinity, while diglycerol and polyglycerol showed significantly higher transition temperatures. The higher molecular weight and viscosity of polyglycerol allow this transition to occur at an even higher temperature than with diglycerol. This is due to the increase in molecular weight and viscosity of the two new plasticizers, as well as their significant decrease in water solubility. It is demonstrated that the water/plasticizer ratio has a pronounced effect on gelatinization temperatures. When plasticizer content was held constant and water content was increased, it was found that the gelatinization temperature decreased for all the plasticizers. Meanwhile, when the water content was held constant and the plasticizer content was increased, the gelatinization temperature increased for glycerol, sorbitol and diglycerol, but it moved in the opposite direction in the case of polyglycerol. The gelatinization temperature variation for glycerol, sorbitol and diglycerol caused by changing water and plasticizer content indicates that water is the primary agent causing granular swell and plasticization in the gelatinization process. Due to the high molecular weight and viscosity, as well as the low hydroxyl group density (~ one --OH per two carbon) and borderline solubility of polyglycerol in water, it is believed that water-aided penetration of the plasticizer among the crystalline structure of starch molecules is significantly decelerated. So it is proposed that in the case of low-water solubility of the plasticizers, gelatinization temperature is determined more by the total amount of the plasticizer and water, rather than the water/plasticizer ratio. Increasing the miscibility of polyglycerol in water by increasing the temperature of the initial slurry, results in a return of the system to the typical thermal dependence of gelatinization with plasticizer/water ratio. Secondly, the gelatinization of starch under "dynamic conditions" was studied. In this case, a constant shear is applied to the slurry, along with a temperature ramp to induce gelatinization. This is, in fact, a rheological technique that heats up the slurry, while a mechanical shear is applied throughout. The reason for using this method is that in the plastic industry, thermoplastic starch is produced via processes involving shear such as extrusion, but, to date, there has not yet been a thorough study on the effect of pure shear on the gelatinization process. Glycerol, diglycerol and sorbitol were subjected to different dynamic gelatinization treatments in a couette flow system, and the results were compared with static gelatinization. Applying shear showed virtually no effect on the onset gelatinization temperature. However, the conclusion temperature was remarkably reduced

  7. Applications of lasers in metallization of thermoplastic and thermosetting polymers

    Directory of Open Access Journals (Sweden)

    P. Rytlewski

    2013-04-01

    Full Text Available Purpose: This work focuses on the studies of chemical and physical changes induced by ArF-laser irradiation leading to formation of surfaces catalytically highly active and fully prepared for the direct electroless metallization for the case of thermoplastic and thermosetting polymer composites. The only pretreatment method for surface to be activated was laser irradiation. There are compared two polymer composites: thermoplastic and thermosetting with the same qualitative and quantitative contents of the selected copper compounds. Additionally, there is presented wide context of laser applications in electroless metallization of polymeric materials.Design/methodology/approach: The composites contained the same amount of copper(II oxide (CuO and copper(II acetoacetate Cu(acac2, while varied with the type of polymer matrix. There were chosen polyamide 6 as thermoplastic and polyurethane resin as thermosetting polymer matrixes. The composites were irradiated with various numbers of ArF excimer laser pulses (? = 193 nm at constant fluence of 100 mJ/cm2. The metallization procedure of the laser-irradiated samples was performed by use of a commercial metallization bath and formaldehyde as a reducing agent. The samples were examined using FTIR, contact angle measurement and SEM techniques.Findings: It was found that laser irradiation induce catalytic properties in the studied composites. However, better catalytic properties were achieved for the thermoplastic than thermosetting polymer composites.Research limitations/implications: In order to better understand the differences in laser interactions between thermoplastic and thermosetting composites more examples of various polymer matrixes should be investigated.Practical implications: Suitable condition for laser irradiation of the composites associated with the best catalytic properties were proposes. Better catalytic properties were achieved for thermoplastic than thermosetting composite.Originality/value: Comparison of new thermoplastic and thermosetting polymer composites intended for laser direct electroless metallization is firstly reported in this article.

  8. Improved Thermoplastic/Iron-Particle Transformer Cores

    Science.gov (United States)

    Wincheski, Russell A.; Bryant, Robert G.; Namkung, Min

    2004-01-01

    A method of fabricating improved transformer cores from composites of thermoplastic matrices and iron-particles has been invented. Relative to commercially available laminated-iron-alloy transformer cores, the cores fabricated by this method weigh less and are less expensive. Relative to prior polymer-matrix/ iron-particle composite-material transformer cores, the cores fabricated by this method can be made mechanically stronger and more magnetically permeable. In addition, whereas some prior cores have exhibited significant eddy-current losses, the cores fabricated by this method exhibit very small eddy-current losses. The cores made by this method can be expected to be attractive for use in diverse applications, including high-signal-to-noise transformers, stepping motors, and high-frequency ignition coils. The present method is a product of an experimental study of the relationships among fabrication conditions, final densities of iron particles, and mechanical and electromagnetic properties of fabricated cores. Among the fabrication conditions investigated were molding pressures (83, 104, and 131 MPa), and molding temperatures (250, 300, and 350 C). Each block of core material was made by uniaxial-compression molding, at the applicable pressure/temperature combination, of a mixture of 2 weight percent of LaRC (or equivalent high-temperature soluble thermoplastic adhesive) with 98 weight percent of approximately spherical iron particles having diameters in the micron range. Each molded block was cut into square cross-section rods that were used as core specimens in mechanical and electromagnetic tests. Some of the core specimens were annealed at 900 C and cooled slowly before testing. For comparison, a low-carbon-steel core was also tested. The results of the tests showed that density, hardness, and rupture strength generally increased with molding pressure and temperature, though the correlation was rather weak. The weakness of the correlation was attributed to the pores in the specimens. The maximum relative permeabilities of cores made without annealing ranged from 30 to 110, while those of cores made with annealing ranged from 900 to 1,400. However, the greater permeabilities of the annealed specimens were not associated with noticeably greater densities. The major practical result of the investigation was the discovery of an optimum distribution of iron-particle sizes: It was found that eddy-current losses in the molded cores were minimized by using 100 mesh (corresponding to particles with diameters less than or equal to 100 m) iron particles. The effect of optimization of particle sizes on eddy-current losses is depicted in the figure.

  9. Method for bonding a thermoplastic polymer to a thermosetting polymer component:

    OpenAIRE

    van Tooren, M. J. L.

    2012-01-01

    The invention relates to a method for bonding a thermoplastic polymer to a thermosetting polymer component, the thermoplastic polymer having a melting temperature that exceeds the curing temperature of the thermosetting polymer. The method comprises the steps of providing a cured thermosetting polymer component comprising an implant of a thermoplastic polymer at least at the part of the thermosetting polymer component to be bonded, locating a thermoplastic polymer in contact with at least the...

  10. Bioinspired design and macroscopic assembly of poly(vinyl alcohol)-coated graphene into kilometers-long fibers

    Science.gov (United States)

    Kou, Liang; Gao, Chao

    2013-05-01

    Nacre is characterized by its excellent mechanical performance due to the well-recognized ``brick and mortar'' structure. Many efforts have been applied to make nacre-mimicking materials, but it is still a big challenge to realize their continuous production. Here, we prepared sandwich-like building blocks of poly(vinyl alcohol) (PVA)-coated graphene, and achieved high-nanofiller-content kilometers-long fibers by continuous wet-spinning assembly technology. The fibers have a strict ``brick and mortar'' layered structure, with graphene sheet as rigid brick and PVA as soft mortar. The mortar thickness can be precisely tuned from 2.01 to 3.31 nm by the weight feed ratio of PVA to graphene, as demonstrated by both atomic force microscopy and X-ray diffraction measurements. The mechanical strength of the nacre-mimicking fibers increases with increasing the content of PVA, and it rises gradually from 81 MPa for the fiber with 53.1 wt% PVA to 161 MPa for the fiber with 65.8 wt% PVA. The mechanical performance of our fibers was independent of the molecular weight (MW) of PVA in the wide range of 2-100 kDa, indicating that low MW polymers can also be used to make strong nanocomposites. The tensile stress of fibers immersed in PVA 5 wt% solution reached ca. 200 MPa, surpassing the values of nacre and most of other nacre-mimicking materials. The nacre-mimicking fibers are highly electrically conductive (~350 S m-1) after immersing in hydroiodic acid, enabling them to connect a circuit to illuminate an LED lamp.Nacre is characterized by its excellent mechanical performance due to the well-recognized ``brick and mortar'' structure. Many efforts have been applied to make nacre-mimicking materials, but it is still a big challenge to realize their continuous production. Here, we prepared sandwich-like building blocks of poly(vinyl alcohol) (PVA)-coated graphene, and achieved high-nanofiller-content kilometers-long fibers by continuous wet-spinning assembly technology. The fibers have a strict ``brick and mortar'' layered structure, with graphene sheet as rigid brick and PVA as soft mortar. The mortar thickness can be precisely tuned from 2.01 to 3.31 nm by the weight feed ratio of PVA to graphene, as demonstrated by both atomic force microscopy and X-ray diffraction measurements. The mechanical strength of the nacre-mimicking fibers increases with increasing the content of PVA, and it rises gradually from 81 MPa for the fiber with 53.1 wt% PVA to 161 MPa for the fiber with 65.8 wt% PVA. The mechanical performance of our fibers was independent of the molecular weight (MW) of PVA in the wide range of 2-100 kDa, indicating that low MW polymers can also be used to make strong nanocomposites. The tensile stress of fibers immersed in PVA 5 wt% solution reached ca. 200 MPa, surpassing the values of nacre and most of other nacre-mimicking materials. The nacre-mimicking fibers are highly electrically conductive (~350 S m-1) after immersing in hydroiodic acid, enabling them to connect a circuit to illuminate an LED lamp. Electronic supplementary information (ESI) available: More AFM and SEM images and electrical conductivities of CRG@PVA with different feed ratios, FTIR spectra, Raman and XPS results of GO, CRG and CRG@PVA, SEM images of CRG@PVA fibers with different diameters, SEM images and conductivity of CRG@PVA fibers with different MW of PVA, the tensile curve of CRG@PVA paper, and videos of graphene knot and spring. See DOI: 10.1039/c3nr00455d

  11. Development and testing of thermoplastic structural components for modular prostheses.

    Science.gov (United States)

    Coombes, A G; MacCoughlan, J

    1988-04-01

    The wider use of thermoplastic structural components in modular artificial limbs would enable their general properties of low density, corrosion resistance and mouldability and more specific properties of certain thermoplastics such as shock absorption, fatigue and wear resistance to be used to the advantage of patients and manufacturers. They provide an alternative to metal and carbon fibre reinforced resin systems. Emphasis has been placed on the development of rotationally moulded Nylon 11 shank sections, using Philadelphia recommended load levels as the design criteria for structural integrity. Laboratory testing underlined the importance of fatigue testing of thermoplastic components since structural deterioration due to creep--a time dependent mechanical property of thermoplastics--can be ascertained in fatigue testing but would not be evident on the shorter timescale of the static test. Experimental below-knee prostheses incorporating suitably designed plastic shanks and alignment devices can withstand high static loads and exhibit long fatigue lifetimes in excess of 2 million cycles. The shank design offered an opportunity for testing under service conditions the validity of the Philadelphia Static Load level (2.5 kN) since shank failure loads are around this figure. Patient trials of experimental prostheses based on various combinations of plastic shanks and alignment devices and conducted over 33 months indicate that the Static Load Level along with fatigue testing is a satisfactory test criterion for general service use of thermoplastic prosthetic components. PMID:3399367

  12. Optimization of injection molding process parameters by a hybrid of artificial neural network and artificial bee colony algorithm / Optimización de los parámetros del proceso de inyección de plásticos a través de un híbrido de redes neuronales artificiales y el algoritmo de la colonia artificial de abejas

    Scientific Electronic Library Online (English)

    Alejandro, Alvarado Iniesta; Jorge L., García Alcaraz; ManuelIván, Rodríguez Borbón.

    2013-06-01

    Full Text Available Este estudio presenta un híbrido de redes neuronales artificiales con el algoritmo de la colonia artificial de abejas para optimizar los parámetros del proceso de inyección de plásticos con el objetivo de minimizar la deformación en productos plásticos. Una red neuronal de propagación hacia adelante [...] es empleada para obtener una relación matemática entre los parámetros del proceso y el objetivo a optimizar. El algoritmo de la colonia artificial de abejas es usado para encontrar el conjunto óptimo de valores de los parámetros que resultarían en la solución óptima. Un caso experimental es presentado acoplando simulaciones de Moldflow junto con los esquemas mencionados con el fin de validar el enfoque propuesto. La temperatura del plástico, temperatura del molde, presión de empaque, tiempo de empaque, y tiempo de enfriamiento son consideradas como las variables de diseño. Los resultados revelan que el enfoque propuesto puede eficientemente apoyar a ingenieros a determinar los parámetros óptimos y alcanzar ventajas competitivas en términos de calidad y costos. Abstract in english This paper presents a hybrid of artificial neural networks and artificial bee colony algorithm to optimize the process parameters in injection molding with the aim of minimize warpage of plastic products. A feedforward neural network is employed to obtain a mathematical relationship between the proc [...] ess parameters and the optimization goal. Artificial bee colony algorithm is used to find the optimal set of process parameters values that would result in the optimal solution. An experimental case is presented by coupling Moldflow simulations along with the intelligent schemes in order to validate the proposed approach. Melt temperature, mold temperature, packing pressure, packing time, and cooling time are considered as the design variables. Results revealed the proposed approach can efficiently support engineers to determine the optimal process parameters and achieve competitive advantages in terms of quality and costs.

  13. Nanocellular thermoplastic foam and process for making the same

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Lingbo; Costeux, Stephane; Patankar, Kshitish A.; Moore, Jonathan D.

    2015-09-29

    Prepare a thermoplastic polymer foam having a porosity of 70% or more and at least one of: (i) an average cell size of 200 nanometers or less; and (ii) a nucleation density of at least 1.times.1015 effective nucleation sites per cubic centimeter of foamable polymer composition not including blowing agent using a foamable polymer composition containing a thermoplastic polymer selected from styrenic polymer and (meth)acrylic polymers, a blowing agent comprising at least 20 mole-percent carbon dioxide based on moles of blowing agent and an additive having a Total Hansen Solubility Parameter that differs from that of carbon dioxide by less than 2 and that is present at a concentration of 0.01 to 1.5 weight parts per hundred weight parts thermoplastic polymer.

  14. Comprehensive Welding of Thermoplastics by a Diode Laser

    Science.gov (United States)

    Sato, Kimitoshi; Saito, Takushi; Kurosaki, Yasuo

    This paper deals with a development of “comprehensive" laser welding of thermoplastics with versatility in color and shape of products. Overlap welding of thermoplastics is one of the features of application of diode lasers. Most of thermoplastics are transparent to diode lasers; therefore it is need to weld plastic article with colorant. The influence of absorptance and transmittance of overlapping colored plastics were studied. Various colored plastics with infrared-transparent pigments were tested as the welding material. The appropriate absorptance and transmittance of overlapping colored plastic were examined. The feasibility of the technique of welding of transparent plastics using infrared-absorbing layer was also investigated. The temperature distribution within the plastics was calculated by numerical simulation in order to estimate the validity of the proposing experimental systems. It was confirmed by the experiments that the 35?m film, which shows only 10% in absorptance is enough to weld a pair of transparent articles as infrared-absorbing layer.

  15. Evaluation of wetting transitions on injected molded hierarchical moss structures

    OpenAIRE

    Bor?vka, Martin; Janeba, Martin

    2013-01-01

    Bio-inspired hierarchical surfaces demonstrate a potential for a variety of green technologies. The design of those surfaces remains a challenging scientific and technological task. The diversity of plant surface structures, evolved over 460 million years, has led to a large variety of highly adapted functional structures. The plant cuticle provides structural, chemical and physical modifications for surface wetting, ranging from superhydrophilic to superhydrophobic. Understanding the physica...

  16. Validation of three-dimensional micro injection molding simulation accuracy

    DEFF Research Database (Denmark)

    Tosello, Guido Technical University of Denmark,

    2011-01-01

    Data analysis and simulations on micro-molding experiments have been conducted. Micro molding simulations have been executed taking into account actual processing conditions implementation in the software. Various aspects of the simulation set-up have been considered in order to improve the simulation accuracy (i.e. decrease deviations from experimental values): injection speed profile, cavity injection pressure, melt and mold temperatures, three-dimensional mesh parameters, and material rheological characterization. Quality factors investigated for the quantitative comparisons were: short shot length, injection pressure profile, molding mass and flow pattern. The importance of calibrated micro molding process monitoring for an accurate implementation strategy of the simulation and its validation has been demonstrated. In fact, inconsistencies and uncertainties in the experimental data must be minimized to avoid introducing uncertainties in the simulation calculations. Simulations of bulky sub-100 milligrams micro molded parts have been validated and a methodology for accurate micro molding simulations was established.

  17. Preparation, morphology and rheology of thermoplastic starch/polycaprolactone blends.

    Czech Academy of Sciences Publication Activity Database

    Šlouf, Miroslav; Ostafinska, Aleksandra; Nevoralová, Martina; Michálková, Danuše; Horák, Pavel; Kredatusová, Jana

    Budapest : Department of Pharmacology, Institute of Experimental Medicine , Hungarian Academy of Sciences, 2015. s. 574-576. [Multinational Congress on Microscopy /12./. 23.08.2015-28.08.2015, Eger] R&D Projects: GA ?R(CZ) GA14-17921S Institutional support: RVO:61389013 Keywords : biodegradable polymers * thermoplastic starch * blends Subject RIV: JJ - Other Materials

  18. Attribute Based Selection of Thermoplastic Resin for Vacuum Infusion Process: A Decision Making Methodology

    DEFF Research Database (Denmark)

    Raghavalu Thirumalai, Durai Prabhakaran; Lystrup, Aage; Løgstrup Andersen, Tom

    2012-01-01

    The composite industry looks toward a new material system (resins) based on thermoplastic polymers for the vacuum infusion process, similar to the infusion process using thermosetting polymers. A large number of thermoplastics are available in the market with a variety of properties suitable for different engineering applications, and few of those are available in a not yet polymerised form suitable for resin infusion. The proper selection of a new resin system among these thermoplastic polymers...

  19. Toroid Joining Gun. [thermoplastic welding system using induction heating

    Science.gov (United States)

    Buckley, J. D.; Fox, R. L.; Swaim, R J.

    1985-01-01

    The Toroid Joining Gun is a low cost, self-contained, portable low powered (100-400 watts) thermoplastic welding system developed at Langley Research Center for joining plastic and composite parts using an induction heating technique. The device developed for use in the fabrication of large space sructures (LSST Program) can be used in any atmosphere or in a vacuum. Components can be joined in situ, whether on earth or on a space platform. The expanded application of this welding gun is in the joining of thermoplastic composites, thermosetting composites, metals, and combinations of these materials. Its low-power requirements, light weight, rapid response, low cost, portability, and effective joining make it a candidate for solving many varied and unique bonding tasks.

  20. Modification of thermoplastic polymers by radiation chemical methods

    International Nuclear Information System (INIS)

    The general conditions under which radiation chemical reactions can compete with conventional chemical reactions are first discussed, along with the advantages and shortcomings of electron accelerators which are commonly used as radiation sources for treatment of polymers. After a review of the reactions which occur on irradiation of thermoplastics, the practical application of degradatin and above all cross-linking by radiation (especially in polyethylene) is outlined. Finally, the different methods of grafting by radiation and their technical realization are discussed

  1. Multiple-length-scale deformation analysis in a thermoplastic polyurethane

    OpenAIRE

    Sui, Tan; Baimpas, Nikolaos; Dolbnya, Igor P.; Prisacariu, Cristina; Korsunsky, Alexander M.

    2015-01-01

    Thermoplastic polyurethane elastomers enjoy an exceptionally wide range of applications due to their remarkable versatility. These block co-polymers are used here as an example of a structurally inhomogeneous composite containing nano-scale gradients, whose internal strain differs depending on the length scale of consideration. Here we present a combined experimental and modelling approach to the hierarchical characterization of block co-polymer deformation. Synchrotron-based small- and wide-...

  2. Thermoplastic Polyurethane Elastomer Nanocomposites: Morphology, Thermophysical, and Flammability Properties

    OpenAIRE

    Ezekoye, Ofodike A; Joseph H. Koo; Wai K. Ho

    2010-01-01

    Novel materials based on nanotechnology creating nontraditional ablators are rapidly changing the technology base for thermal protection systems. Formulations with the addition of nanoclays and carbon nanofibers in a neat thermoplastic polyurethane elastomer (TPU) were melt-compounded using twin-screw extrusion. The TPU nanocomposites (TPUNs) are proposed to replace Kevlar-filled ethylene-propylene-diene-monomer rubber, the current state-of-the-art solid rocket motor internal insulation. Scan...

  3. Microstructure-property relationships in discontinuous fiber reinforced thermoplastic composites

    Energy Technology Data Exchange (ETDEWEB)

    Vyakarnam, M.N.; Drzal, L.T. [Michigan State Univ., East Lansing, MI (United States)

    1996-12-31

    A novel Aligned Discontinuous Fiber (ADF) composite process has been developed to optimize performance and processability of discontinuous fiber thermoplastic composites. The principle feature of this process is the alignment of the fibers using electric fields in air. The successful control of the orientation state of the fibers using the ADF process led to the fabrication of micro-structure controlled discontinuous fiber composites and the subsequent investigation into the microstructure-property relationships of these materials.

  4. The mechanical behaviour of nano-particle modified thermoplastics

    OpenAIRE

    Zuo, Koucheng

    2010-01-01

    Hybrids made up of polymers and nano-particles have received great interest both in academia and industry. The uniformly dispersed nano-sized particles create a large interfacial area per unit volume and could result in a remarkable improvement in thermal and mechanical properties when compared with virgin polymer or conventional micron-sized particle modified composites. This thesis presents and discusses the effects of adding rigid nano-sized ZnO particles into four thermoplastic systems at...

  5. Synthesis of biodegradable thermoplastic elastomers (BTPE based on ?-caprolactone

    Directory of Open Access Journals (Sweden)

    2010-01-01

    Full Text Available Aiming to mimic blood vessels, biodegradable thermoplastic elastomer (BTPE is designed to be elastic, flexible and tough. A series of biodegradable triblock copolymers and poly(ester-urethanes (PEU based on ?-caprolactone have been synthesized and studied. The crystallinity of the poly(?-caprolactone used as soft segment has been disrupted by incorporating either L-lactide (L-LA units or trimethylene carbonate (TMC units. Our studies suggest that soft segment composition does affect the mechanical properties significantly.

  6. Thermoplastic polymers surfaces for Dip-Pen Nanolithography of oligonucleotides

    International Nuclear Information System (INIS)

    Different thermoplastic polymers were spin-coated to prepare smooth surfaces for the direct deposition of end-group modified oligonucleotides by Dip-Pen Nanolithography. A study of the diffusion process was done in order to investigate the dependence of calibration coefficient and quality of deposited features on environmental parameters (temperature, relative humidity) and ink's molecular weight and functionality. The optimization of the process parameters led to the realization of high quality and density nanoarrays on plastics.

  7. Thermoplastic polymers surfaces for Dip-Pen Nanolithography of oligonucleotides

    Energy Technology Data Exchange (ETDEWEB)

    Suriano, Raffaella [Dipartimento di Chimica, Materiali e Ingegneria Chimica “Giulio Natta”, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milano (Italy); Biella, Serena, E-mail: serena.biella@polimi.it [Dipartimento di Chimica, Materiali e Ingegneria Chimica “Giulio Natta”, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milano (Italy); Cesura, Federico; Levi, Marinella; Turri, Stefano [Dipartimento di Chimica, Materiali e Ingegneria Chimica “Giulio Natta”, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milano (Italy)

    2013-05-15

    Different thermoplastic polymers were spin-coated to prepare smooth surfaces for the direct deposition of end-group modified oligonucleotides by Dip-Pen Nanolithography. A study of the diffusion process was done in order to investigate the dependence of calibration coefficient and quality of deposited features on environmental parameters (temperature, relative humidity) and ink's molecular weight and functionality. The optimization of the process parameters led to the realization of high quality and density nanoarrays on plastics.

  8. Distribution of oil in olefinic thermoplastic elastomer blends

    OpenAIRE

    Sengers, WGF; Wübbenhorst, Michael; Picken, SJ; Gotsis, AD

    2005-01-01

    The distribution of processing oil in two olefinic thermoplastic elastomer (OTPE) blends was determined using dielectric spectroscopy. The OPTE blends are blends of dynamically vulcanised EPDM with polypropylene (PP), TPVs, and blends of PP with SEBS. Both blend types contain paraffinic oil, which is present in both the PP and in the elastomer phase. The determination of the actual oil concentration by measuring the reduction in the glass transition temperatures (T-g) is inaccurate using DSC ...

  9. Distribution of Oil in a PP/EPDM Thermoplastic Elastomer

    Science.gov (United States)

    Kikuchi, Yutaka; Okada, Tetsuo; Inoue, Takashi

    Distribution of oil in a commercial PP(polypropylene)/EPDM(ethylene-propyrene-diene rubber) thermoplastic elastomer was analyzed by light scattering. It was shown that the oil preferentially stays in EPDM particles at low temperatures and it migrates to PP matrix at high temperatures. That is, the oil is expected to play a dual role; softener at ambient temperature and plasticizer at processing temperature. The temperature dependence of oil distribution was nicely interpreted by a thermodynamic discussion.

  10. Novel thermoplastic bonding using a bulk metallic glass solder

    International Nuclear Information System (INIS)

    A novel thermoplastic bonding concept is demonstrated based on the unique rheological behavior and pattern-replicating ability of bulk metallic glass (BMG)-forming liquids. In this approach, the BMG is heated above Tg to the 'supercooled liquid' region while a small normal force is applied to the joint. This results in liquid reflow, wetting and a strong bond. Complete wetting between copper substrates and a layer of platinum-based BMG leads to an atomistically intimate void-free interface

  11. Elasto-plastic Thermal Stress Analysis in Symmetric Thermoplastic Laminates

    OpenAIRE

    Çallio?lu, Hasan; Sayman, Onur; Ataberk, Necati

    2005-01-01

    Abstract In this study, a thermal elastic–plastic stress analysis is carried out in steel fiber-reinforced symmetric thermoplastic laminated plates. The material is assumed to be strain-hardening. The orientation angles are chosen as, (0°/90°)s, (30°/30°)s, (45°/45°)s, (60°/60°)s, (15°/0°)s, (30°/0°)s, (45°/0°)s, (60°/0°)s, (75°/0°)s. The Tsai–Hill th...

  12. Mechanical properties of carbon fibre reinforced thermoplastics for cryogenic applications

    International Nuclear Information System (INIS)

    The high specific strength, the high specific stiffness and the excellent fatigue behaviour favours carbon fibre reinforced plastics (CFRP) as a supplement to metals for low temperature applications. The weakest link in the composite is the polymeric matrix, which is preloaded by thermal tensile strains and becomes brittle at low temperatures. Tough thermoplastic polymers show a higher cryogenic fracture strain than commonly used epoxy-matrix systems. Two carbon fibre reinforced tough thermoplastics (PEEK, PC) were tested at 293 K, 77 K and 5 K by tensile, bending and fatigue loading. It has been found, that the toughness of the matrices generally improves the static strength at low temperatures. In bidirectionally reinforced thermoplastics, transversal cracks appear in the matrix or in the boundary layer at composite strains below 0,2%, originated by the thermal preloading. The formation and development of the cracks depend on the fibre-matrix-bond and on the thickness of the composite layers. Fibre-misalignment results in a poor tension-tension fatigue endurance limit of less than 50% of the static strength. Further developments in the manufacturing process are necessary to improve the homogeneity of the composite structure in order to increase the long term fatigue behaviour. (orig.)

  13. Material, process, and product design of thermoplastic composite materials

    Science.gov (United States)

    Dai, Heming

    Thermoplastic composites made of polypropylene (PP) and E-glass fibers were investigated experimentally as well as theoretically for two new classes of product designs. The first application was for reinforcement of wood. Commingled PP/glass yarn was consolidated and bonded on wood panel using a tie layer. The processing parameters, including temperature, pressure, heating time, cooling time, bonding strength, and bending strength were tested experimentally and evaluated analytically. The thermoplastic adhesive interface was investigated with environmental scanning electron microscopy. The wood/composite structural design was optimized and evaluated using a Graphic Method. In the second application, we evaluated use of thermoplastic composites for explosion containment in an arrester. PP/glass yarn was fabricated in a sleeve form and wrapped around the arrester. After consolidation, the flexible composite sleeve forms a solid composite shell. The composite shell acts as a protection layer in a surge test to contain the fragments of the arrester. The manufacturing process for forming the composite shell was designed. Woven, knitted, and braided textile composite shells made of commingled PP/glass yarn were tested and evaluated. Mechanical performance of the woven, knitted, and braided composite shells was examined analytically. The theoretical predictions were used to verify the experimental results.

  14. Flexible thermoplastic composite of Polyvinyl Butyral (PVB) and waste of rigid Polyurethane foam

    Scientific Electronic Library Online (English)

    Marilia, Sônego; Lidiane Cristina, Costa; José Donato, Ambrósio.

    2015-04-01

    Full Text Available This study reports the preparation and characterization of composites with recycled poly(vinyl butyral) (PVB) and residue of rigid polyurethane foam (PUr), with PUr contents of 20, 35 and 50 wt %, using an extruder equipped with a Maillefer single screw and injection molding. The components of the c [...] omposites were thermally characterized using differential scanning calorimetry (DSC) and thermogravimetry. The composites were evaluated by melt flow index (MFI), tensile and hardness mechanical tests and scanning electron microscopy (SEM). Tg determined by DSC of PVB sample (53 °C) indicated the presence of plasticizer (Tg of pure PVB is 70 °C). MFI of the composites indicated a viscosity increase with the PUr content and, as the shear rate was held constant during injection molding, higher viscosities promoted higher shear stresses in the composites, thereby causing breaking or tearing of the PUr particles. The SEM micrographs showed low adhesion between PVB and PUr and the presence of voids, both inherent in the rigid foam and in the interphase PVB-PUr. The SEM micrographs also showed that PVB/PUr (50/50) composite exhibited the smallest particle size and a more homogeneous and compact structure with fewer voids in the interface. The stiffness of the composites increases with addition of the PUr particles, as evidenced in the mechanical tests.

  15. 40 CFR Table 6 to Subpart Jjj of... - Known Organic HAP Emitted From the Production of Thermoplastic Products

    Science.gov (United States)

    2010-07-01

    ...Organic HAP Emitted From the Production of Thermoplastic Products...Organic HAP Emitted From the Production of Thermoplastic Products... ? ? ABS using a batch emulsion process ? ? ? ABS... ABS using a continuous emulsion process ? ? ?...

  16. Use of Melt Flow Rate Test in Reliability Study of Thermoplastic Encapsulation Materials in Photovoltaic Modules

    Energy Technology Data Exchange (ETDEWEB)

    Moseley, J.; Miller, D.; Shah, Q.-U.-A. S. J.; Sakurai, K.; Kempe, M.; Tamizhmani, G.; Kurtz, S.

    2011-10-01

    Use of thermoplastic materials as encapsulants in photovoltaic (PV) modules presents a potential concern in terms of high temperature creep, which should be evaluated before thermoplastics are qualified for use in the field. Historically, the issue of creep has been avoided by using thermosetting polymers as encapsulants, such as crosslinked ethylene-co-vinyl acetate (EVA). Because they lack crosslinked networks, however, thermoplastics may be subject to phase transitions and visco-elastic flow at the temperatures and mechanical stresses encountered by modules in the field, creating the potential for a number of reliability and safety issues. Thermoplastic materials investigated in this study include PV-grade uncured-EVA (without curing agents and therefore not crosslinked); polyvinyl butyral (PVB); thermoplastic polyurethane (TPU); and three polyolefins (PO), which have been proposed for use as PV encapsulation. Two approaches were used to evaluate the performance of these materials as encapsulants: module-level testing and a material-level testing.

  17. Thermal study of the coking behaviour of thermoplastic coals

    Energy Technology Data Exchange (ETDEWEB)

    Vladimir Strezov; Anthony Morrison; Peter Nelson [Macquarie University (Australia)

    2007-12-15

    A novel thermoanalytical technique Computer Aided Thermal Analysis was applied for thermal evaluation of specific heat, heats of reactions, thermal conductivity and diffusivity of the coals during their pyrolysis. Volatiles liberated during pyrolysis of the coals were evaluated using a micro gas chromatograph, while the tars were condensed at room temperature and characterised with matrix-assisted laser desorption/ionisation mass spectrometer (MALDI). Thermogravimetric analysis was employed to measure volatile matter release with temperature during pyrolysis. A small coking reactor was designed to prepare coke samples under laboratory bench-scale conditions. The initial thermal conductivity and diffusivity measured at 100{sup o}C were found to correlate to volatile matter of the coal. When temperatures reached thermoplastic range, the thermal conductivities and diffusivities increased rapidly with the change dependent on the fluidity of the coal. Laboratory produced cokes exhibited a linear relationship between their strength and coke density. The properties of laboratory produced cokes, however, differed from the corresponding coke properties produced under research coke oven conditions. This is most likely because of differences in secondary reactions for the small and large-scale coking conditions. The thermal analysis data showed strong correlations with the properties of the coke produced under research coke oven conditions. The specific heat and corresponding heats of reactions of coals in the temperature range when coals undergo thermoplastic transformation were found to correspond well with the coke quality tests. A linear relationship was found between the thermoplastic range correlation and the coke strength after reactivity with CO{sub 2} for the cokes. An empirical equation was derived from this relationship which can potentially be applied to predict CSR values using a simple thermoanalytical test.

  18. Use of polymer conductors for welding thermoplastic materials

    International Nuclear Information System (INIS)

    Although some polymer conductors of electricity (ex. Polyanilines) are materials known for more than 100 years, only recently have the interesting chemical, electrical and optic properties of their insulating and conducting forms been recognized. Advances made in the chemistry of polymer conductors have also led to improvements in processing them. This work studies a practical application of these materials: the use of polymer conductors for the remote welding of insulating thermoplastic polymers, using energy from microwaves for the local heating of the union. Many thermoplastics (for ex. Polyethylene) do not absorb, or absorb very little, energy from microwaves. Different conductor materials (conductor polymers, carbon nanotubes), however, heavily absorb energy from microwaves with the resulting heating. In this way the welding zone can be heated without affecting the rest of the piece. Conductor polymers (polyanilines) were synthesized chemically and they were characterized by infrared spectroscopy. Polyanilines and other materials (carbon nanotubes) were also modified by reaction with diazone salts. Tests were carried out using different types of coupling: in powder, with material in suspension with wax, with material in suspension with Vaseline, with painted soluble material and with in-situ synthesized polymer on both surfaces to be joined. Different exposure times were tested in a 700 W microwave oven; the 10 mm bars made with different thermoplastic materials, particularly high density polyethylene (HDPE) and polypropylene (PP), were welded. These welded unions were then mechanically tested. The tests on the mechanical properties of the unions yielded an interesting repetition of results when samples welded by microwaves were examined under the same conditions. It was shown that splices can be achieved with reasonably acceptable mechanical resistance in a reduced processing time (CW)

  19. Development of thermoplastic solidification process for urban solid radioactive wastes

    International Nuclear Information System (INIS)

    Urban radioactive solid wastes come mainly from laboratories and hospitals using nuclear technology and radioisotope. Most of them is combustible and they are treated by incineration into ash which is dispersive and may easily contaminated the environment. For this reason the immobilization of the ash is required. Spent ion exchange resins are also dispersive and they need to be converted into stable waste forms. This paper describes the technological process and operation conditions for polymerization of the incineration ash and spent ion exchange resins with the thermoplastic solidification unit. (author). 1 fig., 6 tabs

  20. Induction Consolidation of Thermoplastic Composites Using Smart Susceptors

    Energy Technology Data Exchange (ETDEWEB)

    Matsen, Marc R

    2012-06-14

    This project has focused on the area of energy efficient consolidation and molding of fiber reinforced thermoplastic composite components as an energy efficient alternative to the conventional processing methods such as autoclave processing. The expanding application of composite materials in wind energy, automotive, and aerospace provides an attractive energy efficiency target for process development. The intent is to have this efficient processing along with the recyclable thermoplastic materials ready for large scale application before these high production volume levels are reached. Therefore, the process can be implemented in a timely manner to realize the maximum economic, energy, and environmental efficiencies. Under this project an increased understanding of the use of induction heating with smart susceptors applied to consolidation of thermoplastic has been achieved. This was done by the establishment of processing equipment and tooling and the subsequent demonstration of this fabrication technology by consolidating/molding of entry level components for each of the participating industrial segments, wind energy, aerospace, and automotive. This understanding adds to the nation's capability to affordably manufacture high quality lightweight high performance components from advanced recyclable composite materials in a lean and energy efficient manner. The use of induction heating with smart susceptors is a precisely controlled low energy method for the consolidation and molding of thermoplastic composites. The smart susceptor provides intrinsic thermal control based on the interaction with the magnetic field from the induction coil thereby producing highly repeatable processing. The low energy usage is enabled by the fact that only the smart susceptor surface of the tool is heated, not the entire tool. Therefore much less mass is heated resulting in significantly less required energy to consolidate/mold the desired composite components. This energy efficiency results in potential energy savings of {approx}75% as compared to autoclave processing in aerospace, {approx}63% as compared to compression molding in automotive, and {approx}42% energy savings as compared to convectively heated tools in wind energy. The ability to make parts in a rapid and controlled manner provides significant economic advantages for each of the industrial segments. These attributes were demonstrated during the processing of the demonstration components on this project.

  1. Sustainable green composites of thermoplastic starch and cellulose fibers

    Directory of Open Access Journals (Sweden)

    Amnuay Wattanakornsiri

    2014-04-01

    Full Text Available Green composites have gained renewed interest as environmental friendly materials and as biodegradable renewable resources for a sustainable development. This review provides an overview of recent advances in green composites based on thermoplastic starch (TPS and cellulose fibers. It includes information about compositions, preparations, and properties of starch, cellulose fibers, TPS, and green composites based on TPS and cellulose fibers. Introduction and production of these recyclable composites into the material market would be important for environmental sustainability as their use can decrease the volume of petroleum derived plastic waste dumps. Green composites are comparable cheap and abundant, but further research and development is needed for a broader utilization.

  2. Nanoimprint technology nanotransfer for thermoplastic and photocurable polymers

    CERN Document Server

    Taniguchi, Jun; Mizuno, Jun; Saito, Takushi

    2013-01-01

    Nanoscale pattern transfer technology using molds is a rapidly advancing area and one that has seen much recent attention due to its potential for use in nanotechnology industries and applications. However, because of these rapid advances, it can be difficult to keep up with the technological trends and the latest cutting-edge methods. In order to fully understand these pioneering technologies, a comprehensive understanding of the basic science and an overview of the techniques are required. Nanoimprint Technology: Nanotransfer for Thermoplastic and Photocurable Polymers covers

  3. Computational modelling of a thermoforming process for thermoplastic starch

    Science.gov (United States)

    Szegda, D.; Song, J.; Warby, M. K.; Whiteman, J. R.

    2007-05-01

    Plastic packaging waste currently forms a significant part of municipal solid waste and as such is causing increasing environmental concerns. Such packaging is largely non-biodegradable and is particularly difficult to recycle or to reuse due to its complex composition. Apart from limited recycling of some easily identifiable packaging wastes, such as bottles, most packaging waste ends up in landfill sites. In recent years, in an attempt to address this problem in the case of plastic packaging, the development of packaging materials from renewable plant resources has received increasing attention and a wide range of bioplastic materials based on starch are now available. Environmentally these bioplastic materials also reduce reliance on oil resources and have the advantage that they are biodegradable and can be composted upon disposal to reduce the environmental impact. Many food packaging containers are produced by thermoforming processes in which thin sheets are inflated under pressure into moulds to produce the required thin wall structures. Hitherto these thin sheets have almost exclusively been made of oil-based polymers and it is for these that computational models of thermoforming processes have been developed. Recently, in the context of bioplastics, commercial thermoplastic starch sheet materials have been developed. The behaviour of such materials is influenced both by temperature and, because of the inherent hydrophilic characteristics of the materials, by moisture content. Both of these aspects affect the behaviour of bioplastic sheets during the thermoforming process. This paper describes experimental work and work on the computational modelling of thermoforming processes for thermoplastic starch sheets in an attempt to address the combined effects of temperature and moisture content. After a discussion of the background of packaging and biomaterials, a mathematical model for the deformation of a membrane into a mould is presented, together with its finite element discretisation. This model depends on material parameters of the thermoplastic and details of tests undertaken to determine these and the results produced are given. Finally the computational model is applied for a thin sheet of commercially available thermoplastic starch material which is thermoformed into a specific mould. Numerical results of thickness and shape for this problem are given.

  4. Dynamic dielectric characterization of thermosets and thermoplastics using intrinsic variables

    Science.gov (United States)

    Kranbuehl, D. E.; Delos, S. E.; Jue, P. K.; Jarvie, T. P.; Williams, S. A.

    1984-01-01

    Dynamic dielectric analysis has been used to study curing polymer systems and thermoplastics. Measurements have been made over a frequency range of six decades. The data are analyzed in terms of capacitance, conductance, dissipation, complex permittivity, and conductivity (sigma). Complex permittivity and sigma are properties which are characteristic of the cure state of the material and independent of the size of the sample. LARC-160, PMR-15, NARMCO 5208, Epon and UDEL-P1700 have been studied. The experimental results suggest that when ionic processes dominate the dielectric response, the intensive property sigma is a good monitor of the resin's viscosity.

  5. Novel thermoplastic bonding using a bulk metallic glass solder

    Energy Technology Data Exchange (ETDEWEB)

    Suh, Jin-Yoo [Keck Laboratory of Engineering Materials, California Institute of Technology, MC 138-78, 1200 E. California Boulevard, Pasadena, CA 91125 (United States)], E-mail: jinyoo@caltech.edu; Lohwongwatana, Boonrat [Metallurgical Engineering Department, Chulalongkorn University, Bangkok 10330 (Thailand); Garland, Carol M. [Keck Laboratory of Engineering Materials, California Institute of Technology, MC 138-78, 1200 E. California Boulevard, Pasadena, CA 91125 (United States); Conner, R. Dale [Department of Manufacturing Systems Engineering and Management, California State University Northridge, Northridge, CA 91330 (United States); Johnson, William L. [Keck Laboratory of Engineering Materials, California Institute of Technology, MC 138-78, 1200 E. California Boulevard, Pasadena, CA 91125 (United States); Suh, Daewoong [Components Research, Intel Corporation, Chandler, AZ 85226 (United States)

    2008-10-15

    A novel thermoplastic bonding concept is demonstrated based on the unique rheological behavior and pattern-replicating ability of bulk metallic glass (BMG)-forming liquids. In this approach, the BMG is heated above T{sub g} to the 'supercooled liquid' region while a small normal force is applied to the joint. This results in liquid reflow, wetting and a strong bond. Complete wetting between copper substrates and a layer of platinum-based BMG leads to an atomistically intimate void-free interface.

  6. Solid particle erosion and viscoelastic properties of thermoplastic polyurethanes

    Directory of Open Access Journals (Sweden)

    G. Arena

    2015-03-01

    Full Text Available The wear resistance of several thermoplastic polyurethanes (TPUs having different chemical nature and micronscale arrangement of the hard and soft segments has been investigated by means of erosion and abrasion tests. The goal was correlating the erosion performances of the materials to their macroscopic mechanical properties. Unlike conventional tests, such as hardness and tensile measurements, viscoelastic analysis proved to be a valuable tool to study the erosion resistance of TPUs. In particular, a strict correlation was found between the erosion rate and the high-frequency (~107 Hz loss modulus. The latter reflects the actual ability of TPU to dissipate the impact energy of the erodent particles.

  7. Thermoplastic starch materials prepared from rice starch; Preparacao e caracterizacao de materiais termoplasticos preparados a partir de amido de arroz

    Energy Technology Data Exchange (ETDEWEB)

    Pontes, Barbara R.B.; Curvelo, Antonio A.S., E-mail: barbarapont@gmail.co [Universidade de Sao Paulo (IQSC/USP), Sao Carlos, SP (Brazil). Inst. de Quimica

    2009-07-01

    Rice starch is a source still little studied for the preparation of thermoplastic materials. However, its characteristics, such as the presence of proteins, fats and fibers may turn into thermoplastics with a better performance. The present study intends the evaluation of the viability of making starch thermoplastic from rice starch and glycerol as plasticizer. The results of X-ray diffraction and scanning electronic microscopy demonstrate the thermoplastic acquisition. The increase of plasticizer content brings on more hydrophilic thermoplastics with less resistance to tension and elongation at break. (author)

  8. Processability of Pultrusion Using Natural Fiber and Thermoplastic Matrix

    Directory of Open Access Journals (Sweden)

    Günter Mennig

    2007-10-01

    Full Text Available Fundamental mechanisms of the pultrusion process using commingled yarns of polypropylene matrix and discontinuous flax fiber to produce thermoplastic profiles were investigated in numerical and experimental manners. Essential issue is the fact that all natural fibers are discontinuous by nature, which may negatively influence the processability. The pultrusion process will be only successful if the pulling force exerted on the solidified pultrudates can be transmitted to the regions of unmelted commingled yarns by “bridging over” those melted regions within the die. This can be realized by applying a sufficient number of small yarn bundles of high compactness rather than a thicker single bundle of lower compactness as the raw material. Furthermore, the possibility of adding extra melt into the yarn bundles by side-fed extrusion has been investigated showing that the impregnation can be improved only for the outer layers of yarns, which is owed to the high viscosity of the thermoplastic melt and the limited length of the die.

  9. Interlaminate Deformation in Thermoplastic Composite Laminates: Experimental-Numerical Correlation

    Directory of Open Access Journals (Sweden)

    Fang Y.

    2010-06-01

    Full Text Available The interlaminar deformation behaviors of thermoplastic AS4/PEEK composite laminates subjected to static tensile loading are investigated by means of microscopic moiré interferometry with high spatial resolution. The fully threedimensional orthotropic elastic-plastic analysis of interlaminar deformation for the thermoplastic laminates is developed in this paper, and used to simulate the stress-strain curves of tensile experiment for its angle-ply laminates. Under uniaxial tensile loading, the 3D orthotropic elastic-plastic FE analysis and microscopic moiré interferometry of interlaminar deformations are carried out for the [±25]S4 laminates. The quantitative local-filed experimental results of interlaminar shear strain and displacements at freeedge surface of the laminate are compared with corresponding numerical results of the orthotropic elastic-plastic FE model. It is indicated that the numerical tensile stressstrain curves of angle-ply laminates computed with 3D orthotropic elastic-plastic model are agree with experimental results. The numerical interlaminar displacement U and shear strain ?xz are also consistent with the experimental results obtained by moiré interferometry. It is expected the elastic-plastic interlaminar stresses and deformations analysis for the optimal design and application of AS4/PEEK laminates and its structures.

  10. Biodeterioration studies of thermoplastics in nature using indigenous bacterial consortium

    Scientific Electronic Library Online (English)

    Mohd. Shahbaz, Anwar; Harshita, Negi; Mohd. Ghulam Haider, Zaidi; Sanjay, Gupta; Reeta, Goel.

    2013-06-01

    Full Text Available Thermoplastics, poly vinyl chloride and low-density polyethylene were treated in the presence of indigenously developed bacterial consortium in laboratory and natural conditions. The consortium was developed using four bacteria, selected on the basis of utilization of PVC as primary carbon source, n [...] amely P. otitidis, B. aerius, B. cereus and A. pedis isolated from the plastic waste disposal sites in Northern India. The comparative in-vitro treatment studies as revealed by the spectral and thermal data, illustrated the relatively better biodegradation potential of developed consortium for PVC than the LDPE. Further, the progressive treatments of both the thermoplastics were conducted for three months under natural conditions. For this purpose, bioformulation of consortium was prepared and characterized for the viability up to 70 days of storage at 25±1ºC. The consortium treated polymer samples were monitored through SEM and FT-IR spectroscopy. Analytical data revealed the biodeterioration potential of the developed consortium for PVC and LDPE, which could help in disposing the plastic waste.

  11. Biodeterioration studies of thermoplastics in nature using indigenous bacterial consortium

    Directory of Open Access Journals (Sweden)

    Mohd. Shahbaz Anwar

    2013-06-01

    Full Text Available Thermoplastics, poly vinyl chloride and low-density polyethylene were treated in the presence of indigenously developed bacterial consortium in laboratory and natural conditions. The consortium was developed using four bacteria, selected on the basis of utilization of PVC as primary carbon source, namely P. otitidis, B. aerius, B. cereus and A. pedis isolated from the plastic waste disposal sites in Northern India. The comparative in-vitro treatment studies as revealed by the spectral and thermal data, illustrated the relatively better biodegradation potential of developed consortium for PVC than the LDPE. Further, the progressive treatments of both the thermoplastics were conducted for three months under natural conditions. For this purpose, bioformulation of consortium was prepared and characterized for the viability up to 70 days of storage at 25±1ºC. The consortium treated polymer samples were monitored through SEM and FT-IR spectroscopy. Analytical data revealed the biodeterioration potential of the developed consortium for PVC and LDPE, which could help in disposing the plastic waste.

  12. Development of thermo-plastic heating and compaction facility

    International Nuclear Information System (INIS)

    Low- and intermediate-level radioactive wastes consist of spent resin, spent filter, concentrated waste and dry active waste(DAW) and they are solidified or packaged into drums or high integrated containers(HICs). DAWs occupy 50 percent of all low- and intermediate-level radioactive wastes generated from nuclear power plants in Korea. Incinerable wastes in the DAWs are about 60 percent. Therefore, it is very important for us to reduce the volume of incinerable wastes in DAWs. Experience of supercompaction turned out that thermo-plastic wastes have a swelling effect after supercompaction process due to their repulsive power. And the thermo-plastic heating and compaction facility has been developed by KEPCO. In conclusion, heating and compaction facility can reduce the volume of DAWs as well as upgrade the quality of treated wastes, because the swelling effect by repulsive power after compaction is removed, final wastes form the shape of block and they have no free-standing water in the wastes. Plan for practical use is that this facility will be installed in other nuclear power plants in Korea in 1999. (Cho, G. S.). 1 tab., 2 figs

  13. Fly ash reinforced thermoplastic vulcanizates obtained from waste tire powder.

    Science.gov (United States)

    Sridhar, V; Xiu, Zhang Zhen; Xu, Deng; Lee, Sung Hyo; Kim, Jin Kuk; Kang, Dong Jin; Bang, Dae-Suk

    2009-03-01

    Novel thermoplastic composites made from two major industrial and consumer wastes, fly ash and waste tire powder, have been developed. The effect of increasing fly ash loadings on performance characteristics such as tensile strength, thermal, dynamic mechanical and magnetic properties has been investigated. The morphology of the blends shows that fly ash particles have more affinity and adhesion towards the rubbery phase when compared to the plastic phase. The fracture surface of the composites shows extensive debonding of fly ash particles. Thermal analysis of the composites shows a progressive increase in activation energy with increase in fly ash loadings. Additionally, morphological studies of the ash residue after 90% thermal degradation shows extensive changes occurring in both the polymer and filler phases. The processing ability of the thermoplastics has been carried out in a Monsanto processability testing machine as a function of shear rate and temperature. Shear thinning behavior, typical of particulate polymer systems, has been observed irrespective of the testing temperatures. Magnetic properties and percolation behavior of the composites have also been evaluated. PMID:18838261

  14. Advanced Laser Transmission Welding Strategies for Fibre Reinforced Thermoplastics

    Science.gov (United States)

    Wippo, V.; Jaeschke, P.; Brueggmann, M.; Suttmann, O.; Overmeyer, L.

    Laser transmission welding can be used to join endless fibre reinforced thermoplastics. The welding temperature is affected by the heat conduction along carbon fibresand depends on the local orientation of the fibres in the weld seam and the laser welding technique itself. In these investigations the heat development during the welding with quasi-static temperature fields, which is a combination of two laser welding techniques, is evaluated and compared to welding with a homogenized intensity distribution. In order to optimize the temperature distribution over the weld seam width for both linear and curved weld seams, different scanning structures have beenadapted. The experiments were conducted with a diode laser emitting at a wavelength of 940 nm and the process was monitored by aninfrared camera. The used thermoplastics consist of laminates based on unidirectional carbon fibre reinforced polyphenylenesulfide. With the developed scanning structures, a near-homogeneous temperature distribution was generated over the width of the weld seam for curved weld seams, which is not possible by welding with a homogenized laser radiation intensity distribution.

  15. Synthesis and characterization of energetic thermoplastic elastomers for propellant formulations

    Directory of Open Access Journals (Sweden)

    Aparecida M. Kawamoto

    2009-01-01

    Full Text Available Synthesis and characterization of energetic ABA-type thermoplastic elastomers for propellant formulations has been carried out. Following the working plan elaborated, the synthesis and characterization of Poly 3- bromomethyl-3-methyl oxetane (PolyBrMMO, Poly 3- azidomethyl-3-methyl oxetane (PolyAMMO, Poly 3,3-bis-azidomethyl oxetane (PolyBAMO and Copolymer PolyBAMO/AMMO (by TDI end capping has been successfully performed. The thermoplastic elastomers (TPEs were synthesized using the chain elongation process PolyAMMO, GAP and PolyBAMO by diisocyanates. In this method 2.4-toluene diisocyanate (TDI is used to link block A (hard and mono- functional to B (soft and di-functional. For the hard A-block we used PolyBAMO and for the soft B-block we used PolyAMMO or GAP.This is a joint project set up, some years ago, between the Chemistry Division of the Institute of Aeronautics and Space (IAE - subordinated to the Brazilian Ministry of Defense - and the Fraunhofer Institut Chemische Technologie (ICT, in Germany. The products were characterized by different techniques as IR- and (1H,13CNMR spectroscopies, elemental and thermal analyses. New methodologies based on FT-IR analysis have been developed as an alternative for the determination of the molecular weight and CHNO content of the energetic polymers.

  16. Interrelation between blend ratio and heating rate on thermoplasticity of coal blends

    Energy Technology Data Exchange (ETDEWEB)

    Takanohashi, T.; Masaki, K.; Yoshida, T.; Hanaoka, K.; Dobashi, A. [National Institute of Advanced Industrial Science & Technology, Ibaraki (Japan)

    2004-09-01

    Thermoplasticity for coal blends of a high-caking Goonyella coal and a slightly-caking Witbank coal was evaluated by a dynamic viscoelastic technique using a temperature-variable rheometer. At several blend ratios, effect of heating rate on the thermoplasticity for blends was investigated. At a heating rate of 3{degree}C/min, for the coal blends containing 50% Witbank coal, the thermoplasticity was almost the same as Witbank coal alone, suggesting that Witbank coal has any negative effect for thermoplasticity of the blends with Goonyella coal. In contrast, in the cases of less than 30% Witbank coal contained, a sufficient thermoplasticity to produce metallurgical cokes was observed. On the other hand, when the heating rate was increased to 10{degree}C/min, even for the blend containing 70% Witbank coal, a high thermoplasticity was obtained. This result indicates that the slight increase in heating rate greatly affected the thermoplasticity of coal blends. In addition, it is suggested the coal blend containing 70% slightly-caking Witbank coal can be used for cokemaking, when the heating rate is increased to 10{degree}C/min during heating.

  17. Manufacturing of a REBCO racetrack coil using thermoplastic resin aiming at Maglev application

    Science.gov (United States)

    Mizuno, Katsutoshi; Ogata, Masafumi; Hasegawa, Hitoshi

    2015-11-01

    The REBCO coated conductor is a promising technology for the Maglev application in terms of its high critical temperature. The operating temperature of the on-board magnets can be around 40-50 K with the coated conductor. The REBCO coils are cooled by cryocoolers directly, and hence the thermal design of the REBCO coils significantly changes from that of LTS coils. We have developed a novel REBCO coil structure using thermoplastic resin. The coil is not impregnated and the thermoplastic resin is used to bond the coil winding and the heat transfer members, e.g. copper and aluminum plates. The viscosity of the thermoplastic resin is high enough for the thermoplastic resin not to permeate between the turns in the coil. Therefore, the thermal stress does not occur and the risk of degradation is removed. This paper contains the following three topics. First, the thermal resistance of the thermoplastic resin was measured at cryogenic temperature. Then, a small round REBCO coil was experimentally produced. It has been confirmed that the thermoplastic resin does not cause the degradation and, the adhesion between the coil winding and copper plates withstands the thermal stress. Finally, we successfully produced a full-scale racetrack REBCO coil applying the coil structure with the thermoplastic resin.

  18. Thermoplastic Elastomers via polyolefin/Layered Silicate Nanocomposites

    Science.gov (United States)

    Kalluru, Sri; Cochran, Eric

    2013-03-01

    Here we report the synthesis of fully exfoliated polyolefin nanocomposites via Surface-Initiated Ring Opening Metathesis Polymerization (SI-ROMP). Montmorillonite (MMT) clay platelets were rendered hydrophobic through ion exchange with alkyl-ammonium surfactants terminated with norbornene. We were then able to form block copolymer brushes of (substituted) norbornenes and cyclopentene via SI-ROMP. Subsequent hydrogenation yielded highly crystalline polyethylene and rubbery saturated polynorbornenes, thus giving a thermoplastic elastomer. Nanocomposites were prepared with different nanofiller percentages and were characterized for morphological (XRD, TEM), thermal (TGA, DSC), and mechanical (DMA, Rheology) properties. Complete exfoliation of nanocomposites was confirmed by XRD and TEM. A fraction of the polymer brushes were subsequently removed from their substrate by reverse ion exchange and characterized in parallel with their corresponding nanocomposite analogs. In this way we were able to directly assess the role of the filler particle in the thermal properties, melt rheology, morphology, and tensile properties.

  19. Nanoscale pattern fidelity and transfer of hierarchically patterned thermoplastics films

    Science.gov (United States)

    Chen, Ying; Kulkarni, Manish; Marshall, Allan; Douglas, Jack; Karim, Alamgir; the university of akron Team

    2015-03-01

    We demonstrate a versatile and inexpensive method for controlling the surface relief structure of both flexible elastomeric and glassy polymer films over large areas through a two-step imprinting process. First, nanoscale patterns were formed by nanoimprinting polymer films with a pattern on a DVD disk, obtained originally by nanoimprinting from a lithographically etched master pattern on a silicon wafer; micron-scale patterns were then superimposed on the nanoimprinted films by exposing them to ultraviolet radiation in oxygen (UVO) through a TEM grid mask having variable micron-scale patterning. This simple two-stage imprinting method allows for facile fabrication of hierarchically structured elastomer and thermoplastic polymer films. Besides, the thermodynamic properties of dewetting phenomenon of polystyrene film under the confinement of hierarchically patterned PDMS is studied.

  20. Multiple-length-scale deformation analysis in a thermoplastic polyurethane

    Science.gov (United States)

    Sui, Tan; Baimpas, Nikolaos; Dolbnya, Igor P.; Prisacariu, Cristina; Korsunsky, Alexander M.

    2015-03-01

    Thermoplastic polyurethane elastomers enjoy an exceptionally wide range of applications due to their remarkable versatility. These block co-polymers are used here as an example of a structurally inhomogeneous composite containing nano-scale gradients, whose internal strain differs depending on the length scale of consideration. Here we present a combined experimental and modelling approach to the hierarchical characterization of block co-polymer deformation. Synchrotron-based small- and wide-angle X-ray scattering and radiography are used for strain evaluation across the scales. Transmission electron microscopy image-based finite element modelling and fast Fourier transform analysis are used to develop a multi-phase numerical model that achieves agreement with the combined experimental data using a minimal number of adjustable structural parameters. The results highlight the importance of fuzzy interfaces, that is, regions of nanometre-scale structure and property gradients, in determining the mechanical properties of hierarchical composites across the scales.

  1. Development and testing of pesticide formulations with thermoplastic polymers

    International Nuclear Information System (INIS)

    Thermoplastic polymers, mainly ethylene-vinyl acetate co-polymers (EVA), were used to prepare controlled release formulations of pesticides. EVA films with the incorporated herbicides desmetryn and atrazine successfully suppressed weed growth in field trials with white cabbage and sweet corn, respectively, at amounts of application comparable or even lower than those necessary with conventional techniques. The transfer of desmetryn from polymer films into the vapour phase was determined in the laboratory and found to be negligible compared with the release into water coming into contact with the films. Other examples of experimental applications of EVA formulations were control of aquatic weeds with the herbicides terbutryn and simetryn, root zone application of carbofuran in rice and cotton cultivation and the combined attraction and elimination of tsetse flies. (author). 7 refs, 4 figs, 2 tabs

  2. Study of Time-Dependent Properties of Thermoplastics

    Directory of Open Access Journals (Sweden)

    Bolchoun A.

    2010-06-01

    Full Text Available Simple tests carried out with a common tension/compression testing machine are used to obtain timedependent properties of non-reinforced thermoplastics. These tests include ramp loadings as well as relaxation and creep tests. Two materials (PBT Celanex 2002-2 and POM Hostaform C9021, Ticona GmbH, Kelsterbach were taken for the experiments. The experiments show that an adequate description of the long-term material properties can be obtained from the short-time tests, namely from tests with constant traverse speed $L^.$. Below a model for the time-dependent mechanical behavior is presented and fitted to the obtained measured data. For the evaluation of the fitting quality long-term tests are used. Especially creep and relaxation tests with ”jumps”, i.e. rapid change of loading, are important for this purpose.

  3. Thermoplastic Polyurethane Elastomer Nanocomposites: Morphology, Thermophysical, and Flammability Properties

    Directory of Open Access Journals (Sweden)

    Ofodike A. Ezekoye

    2010-01-01

    Full Text Available Novel materials based on nanotechnology creating nontraditional ablators are rapidly changing the technology base for thermal protection systems. Formulations with the addition of nanoclays and carbon nanofibers in a neat thermoplastic polyurethane elastomer (TPU were melt-compounded using twin-screw extrusion. The TPU nanocomposites (TPUNs are proposed to replace Kevlar-filled ethylene-propylene-diene-monomer rubber, the current state-of-the-art solid rocket motor internal insulation. Scanning electron microscopy analysis was conducted to study the char characteristics of the TPUNs at elevated temperatures. Specimens were examined to analyze the morphological microstructure during the pyrolysis reaction and in fully charred states. Thermophysical properties of density, specific heat capacity, thermal diffusivity, and thermal conductivity of the different TPUN compositions were determined. To identify dual usage of these novel materials, cone calorimetry was employed to study the flammability properties of these TPUNs.

  4. Aluminium nitride fibers from a thermoplastic organoaluminum precursor

    International Nuclear Information System (INIS)

    The high thermal conductivity of aluminum nitride (AlN) and its close thermal expansion match to silicon make it a potentially important material for use in microelectronic packaging. Recent AlN research has focused on forming monolithic bodies for replacing alumina and beryllium oxide substrates. However, the authors recently reported alumina fiber-polymer composites which favorably combine the thermal properties of ceramics with the dielectric and processing advantages of polymers. They predicted that by incorporating AlN fibers in such composites, properties could be tailored to give in-plane thermal conductivity exceeding alumina, in-plane thermal expansion close to silicon, and out-of-plane dielectric constant typical of glass-epoxy. The author's AlN fibers are prepared from a thermoplastic organoaluminum preceramic polymer. The polymer is melt spun, cured and pyrolyzed in ammonia, and sintered at high temperature. The authors report properties of the fibers relevant to electronic applications

  5. Machining Accuracy and Stability During Drilling of Thermoplastics

    Directory of Open Access Journals (Sweden)

    Firas M. Al Quran

    2007-01-01

    Full Text Available This study is an attempt to present experimentally the effect of poor thermal conductivity of thermoplastic on machining accuracy. In this case the machined surface roughness, maximum temperature generated during cutting and the dimensional accuracy of the drilled specimens were determined. The executed study shows that, the temperature generated increases by increasing the tool feed, cutting speed and hole depth. The use of large drill diameter leads to insignificantly increase the cutting temperature. The cutting speed during drilling teflon without cooling should not exceed 100 m min-1, if the temperature of the machined material is taken into account. At cooling with pressurized air, the drilling operation may be carried at speed up to 200 m min-1, since in this case the temperature generated in the cutting zone decreases approximately to 30-40°C. It is possible to drill holes with length equals twice the diameter at high speed and attain the desired accuracy.

  6. Production and properties of micro-cellulose reinforced thermoplastic starch

    Science.gov (United States)

    Kmetty, Á.; Karger-Kocsis, J.; Czigány, T.

    2015-02-01

    Thermoplastic starch (TPS)/micro-fibrillated cellulose (MFC) composites were prepared from maize starch with different amount of distilled water, glycerol and cellulose reinforcement. The components were homogenized by kneader and twin roll technique. The produced TPS and TPS-based polymer composites were qualified by static and dynamic mechanical tests and their morphology was analysed by microscopic techniques. The results showed that the amount of water and the order of the production steps control the properties of both the TPS and its MFC reinforced version. With increasing content of MFC the stiffness and strength of the TPS matrix increased, as expected. Microscopic inspection revealed that the TPS has a homogenous structure and the MFC is well dispersed therein when suitable preparation conditions were selected.

  7. Electrospun Thermoplastic Polyurethane Mats Containing Naproxen– Cyclodextrin Inclusion Complex

    Directory of Open Access Journals (Sweden)

    Akduman Çi?dem

    2014-12-01

    Full Text Available Incorporation of cyclodextrins (CDs into electrospun nanofibrous materials can be considered as potential candidates for functional medical textile applications. Naproxen (NAP is a type of non-steroidal anti-inflammatory drug commonly administered for the treatment of pain, inflammation and fever. Drug-inclusion complex formation with CDs is an approach to improve the aqueous solubility via molecular encapsulation of the drug within the cavity of the more soluble CD molecule. In this study, NAP or different NAP-CD inclusion complexes loaded nanofibres were successfully produced through electrospinning and characterised. The inclusion complex loaded mats exhibited significantly faster release profiles than NAP-loaded thermoplastic polyurethane (TPU mats. Overall, NAP-inclusion complex loaded TPU electrospun nanofibres could be used as drug delivery systems for acute pain treatments since they possess a highly porous structure that can release the drug immediately.

  8. Creep of thermoplastic polyurethane reinforced with ozone functionalized carbon nanotubes

    Directory of Open Access Journals (Sweden)

    Z. Zhang

    2012-09-01

    Full Text Available This work focused on the mechanical behavior, especially creep resistance, of thermoplastic polyurethane (TPU filled with ozone-treated multi-walled carbon nanotubes (MWCNTs. It was found that the ozone functionalization of MWCNTs could improve their dispersion and interfacial adhesion to the TPU matrix as proved by scanning electron microscope and Raman spectrometer. It finally contributed to the enhancement of Young’s modulus and yield strength of TPU/MWCNT composites. Moreover, the creep resistance and recovery of MWCNT/TPU composites revealed a significant improvement by incorporating ozone functionalized MWCNTs. The strong interaction between the modified MWCNTs and TPU matrix would enhance the interfacial bonding and facilitate the load transfer, resulting in low creep strain and unrecovered strain.

  9. Attribute based selection of thermoplastic resin for vacuum infusion process : A decision making methodology

    DEFF Research Database (Denmark)

    Prabhakaran, R.T. Durai; Lystrup, Aage

    2011-01-01

    The composite industry looks toward a new material system (resins) based on thermoplastic polymers for the vacuum infusion process, similar to the infusion process using thermosetting polymers. A large number of thermoplastics are available in the market with a variety of properties suitable for different engineering applications, and few of those are available in a not yet polymerised form suitable for resin infusion. The proper selection of a new resin system among these thermoplastic polymers is a concern for manufactures in the current scenario and a special mathematical tool would be beneficial. In this paper, the authors introduce a new decision making tool for resin selection based on significant attributes. This article provides a broad overview of suitable thermoplastic material systems for vacuum infusion process available in today’s market. An illustrative example—resin selection for vacuum infused of a wind turbine blade—is shown to demonstrate the intricacies involved in the proposed methodology for resin selection.

  10. Attribute Based Selection of Thermoplastic Resin for Vacuum Infusion Process: A Decision Making Methodology

    DEFF Research Database (Denmark)

    Raghavalu Thirumalai, Durai Prabhakaran; Lystrup, Aage

    2012-01-01

    The composite industry looks toward a new material system (resins) based on thermoplastic polymers for the vacuum infusion process, similar to the infusion process using thermosetting polymers. A large number of thermoplastics are available in the market with a variety of properties suitable for different engineering applications, and few of those are available in a not yet polymerised form suitable for resin infusion. The proper selection of a new resin system among these thermoplastic polymers is a concern for manufactures in the current scenario and a special mathematical tool would be beneficial. In this paper, the authors introduce a new decision making tool for resin selection based on significant attributes. This article provides a broad overview of suitable thermoplastic material systems for vacuum infusion process available in today’s market. An illustrative example—resin selection for vacuum infused of a wind turbine blade—is shown to demonstrate the intricacies involved in the proposed methodology for resin selection.

  11. Properties and performance of flax yarn/thermoplastic polyester composites

    DEFF Research Database (Denmark)

    Madsen, Bo; Mehmood, Shahid

    2012-01-01

    Aiming at demonstrating the potential of unidirectional natural fiber-reinforced thermoplastic composites in structural applications, textile flax yarn/thermoplastic polyester composites with variable fiber volume fractions have been manufactured by a filament-winding process followed by a vacuum-assisted compression molding process. The microstructure of the composites shows that the flax fiber yarns are well impregnated by the polyester matrix, and this supports the measured low porosity content of the composites. The experimental tensile modulus and ultimate tensile stress of the composites in the axial and transverse directions are well simulated by rule of mixtures models. In the axial direction, at a fiber volume fraction of 0.50, the experimental tensile modulus and ultimate tensile stress are 32 GPa and 350 MPa, respectively. In comparison, for glass fiber composites at a fiber volume fraction of 0.50, the tensile modulus and ultimate tensile stress are calculated to be 38 GPa and 1800 MPa, respectively. The flax yarn composites show better specific tensile modulus than the glass fiber composites with values of 23 GPa/g/cm3 and 20 GPa/g/cm3, respectively. An analysis of data from previous studies of unidirectional natural fibre composites demonstrates comparatively good reinforcement efficiency of the flax yarn fibers with an effective tensile modulus and ultimate tensile stress of the fibers in the area of 70 GPa and 800 MPa, respectively. Altogether, it is demonstrated that composites with high-quality textile flax yarn are well suited for structural applications when stiffness and weight saving are the central selection criteria.

  12. Synthesis of thermoplastic poly(ester-olefin elastomers

    Directory of Open Access Journals (Sweden)

    Tanasijevi? Branka

    2004-01-01

    Full Text Available A series of thermoplastic poly(ester-olefin elastomers, based on poly(ethylene-stat-butylene, HO-PEB-OH, as the soft segment and poly (butylene terephthalate, PBT, as the hard segment, were synthesized by a catalyzed transesterification reaction in solution. The incorporation of soft hydrogenated poly(butadiene segments into the copolyester backbone was accomplished by the polycondensation of ?, ?-dihydroxyl telechelic HO-PEB-OH, (PEB Mn = 3092 g/mol with 1,4-butanediol (BD and dimethyl terephthalate (DMT in the presence of a 50 wt-% high boiling solvent i.e., 1,2,4-trichlorobenzene. The molar ratio of the starting comonomers was selected to result in a constant hard to soft weight ratio of 60:40. The synthesis was optimized in terms of both the concentration of catalyst, tetra-n-butyl-titanate (Ti(OBu4, and stabilizer, N,N'-diphenyl-p-phenylenediamine (DPPD, as well as the reaction time. It was found that the optimal catalyst concentration (Ti(OBu4 for the synthesis of these thermoplastic elastomers was 1.0 mmol/mol ester and the optimal DPPD concentration was 1.0 wt-%. The extent of the reaction was followed by measuring the inherent viscosity of the reaction mixture. The effectiveness of the incorporation of the soft segments into the copolymer chains was proved by Soxhlet extraction with chloroform. The molecular structures, composition and the size of the synthesized poly(ester-butylenes were verified by 1H NMR spectroscopy, viscometry of dilute solutions and the complex dynamic melt viscosity. The thermal properties of poly(ester-olefins were investigated by differential scanning calorimetry (DSC. The degree of crystallinity was also determined by DSC. The thermal and thermo-oxidative stability were investigated by thermogravimetric analysis (TGA. The rheological properties of poly(ester-olefins were investigated by dynamic mechanical spectroscopy in the melt and solid state.

  13. Photoinitiated grafting of porous polymer monoliths and thermoplastic polymers for microfluidic devices

    Science.gov (United States)

    Frechet, Jean M. J. (Oakland, CA); Svec, Frantisek (Alameda, CA); Rohr, Thomas (Leiden, NL)

    2008-10-07

    A microfluidic device preferably made of a thermoplastic polymer that includes a channel or a multiplicity of channels whose surfaces are modified by photografting. The device further includes a porous polymer monolith prepared via UV initiated polymerization within the channel, and functionalization of the pore surface of the monolith using photografting. Processes for making such surface modifications of thermoplastic polymers and porous polymer monoliths are set forth.

  14. The crystallization of tough thermoplastic resins in the presence of carbon fibers

    Science.gov (United States)

    Theil, M. H.

    1986-01-01

    The crystallization kinetics of the thermoplastic resins poly(phenylene sulfide) (PPS) and poly(aryl-ether-ether-ketone) (PEEK) in the presence and in the abscence of carbon fibers was studied. How carbon fiber surfaces in composites affect the crystallization of tough thermoplastic polymers that may serve as matrix resins were determined. The crystallization kinetics of such substances can provide useful information about the crystallization mechanisms and, thus, indicate if the presence of carbon fibers cause any changes in such mechanisms.

  15. Application of Taguchi method in the optimisation of filament winding of thermoplastic composites

    OpenAIRE

    Silva, J. F; J. Domaga?a; L. A. Dobrza?ski

    2007-01-01

    Purpose: Purpose of this paper was to find the optimum parameters to produce Twintex® tubes by filament winding.Design/methodology/approach: Taguchi approach was used for this design. The experiments were done with varying fibers temperature, winding speed, number of layers and roving. Thermoplastic composite rings were manufactured in the thermoplastic filament winding process at selected conditions. The glass and polypropylene fibers (Twintex®) were used to produce tubes. T...

  16. Production of thermoplastic matrix towpregs for higly demanding and cost - effective commercial applications

    OpenAIRE

    Nunes, J. P.; Silva, J. F

    2011-01-01

    This work reviews the work made in last years to produce thermoplastic matrix towpregs to highly demanding and more cost-effective commercial applications using a powder coating technology developed in Portugal by Minho and Porto Universities. Different thermoplastic matrices and continuous fibre reinforcements were used in the towpregs produced for highly demanding markets (e.g., carbon fibre reinforced Primospire towpreg) and for more commercial applications (e.g., glass fibre reinforce...

  17. Recycling and Fibre Reinforcement of Thermoplastic Wastes to Produce Composites for Construction Works

    OpenAIRE

    P.M. Wambua; A.N. Mayaka; E.O.V. Odhong

    2012-01-01

    Thermoplastics are among polymers that biodegrades very slowly over a very long period and can be regarded as nonbiodegradable despite their rapid accumulation in the environment. The use of plant natural fibres as reinforcement for thermoplastics to produce composites is an important area for research. In this study, composites of high density polyethylene wastes reinforced with wood flour, rice husks and bagasse fibers were prepared. The fibers were heated to reduce their moisture content a...

  18. Polypropylene and Natural Rubber based Thermoplastic Vulcanizates by Electron Induced Reactive Processing

    OpenAIRE

    Mondal, Manas

    2013-01-01

    Thermoplastic Vulcanizates (TPVs) are itself a commercially high valued group of polymer blend. They render technological properties of conventional vulcanized elastomers with the ease of thermoplastic melt (re)processability. With ever growing market, TPVs have got plenty of applications among various fields. Here, the technological properties of these TPVs were tailored according to the purpose by interplaying physical parameters of polymers and advanced high energy electron technology. E...

  19. Additive free thermoplastic vulcanizates based on natural rubber

    Energy Technology Data Exchange (ETDEWEB)

    Mondal, Manas, E-mail: mondal@ipfdd.de [Leibniz-Institut für Polymerforschung Dresden e.V., Institut für Polymerwerkstoffe, Hohe Straße 6, 01069 Dresden (Germany); Technische Universität Dresden, Institut für Werkstoffwissenschaft, 01069 Dresden (Germany); Gohs, Uwe, E-mail: gohs@ipfdd.de [Leibniz-Institut für Polymerforschung Dresden e.V., Institut für Polymerwerkstoffe, Hohe Straße 6, 01069 Dresden (Germany); Wagenknecht, Udo [Leibniz-Institut für Polymerforschung Dresden e.V., Institut für Polymerwerkstoffe, Hohe Straße 6, 01069 Dresden (Germany); Heinrich, Gert [Leibniz-Institut für Polymerforschung Dresden e.V., Institut für Polymerwerkstoffe, Hohe Straße 6, 01069 Dresden (Germany); Technische Universität Dresden, Institut für Werkstoffwissenschaft, 01069 Dresden (Germany)

    2013-12-16

    Electron induced reactive processing (EIReP) is an eco-friendly and sustainable reactive processing method based on the use of high energy electrons. It was used to cross-link the elastomeric domain phase during melt mixing in order to prepare natural rubber (NR) and polypropylene (PP) based thermoplastic vulcanizates (TPVs). The electron treatment with various values of absorbed dose showed a prominent effect on mechanical, rheological, and morphological characteristics of the PP/NR TPVs. SEM and TEM studies confirmed that these TPVs can exists across the co-continuous or discrete phase morphology. The maximum set of mechanical properties (tensile strength of 15 MPa and elongation at break of more than 500%) were obtained at an absorbed dose of 100 kGy for a 50/50 blend ratio of NR and PP without addition of any compatibilizer or chemicals. At higher values of absorbed dose the degradation of polypropylene showed a negative impact on the properties of the TPVs. Depending on the morphology and the evaluation of mechanical properties a structure–property co-relationship is drawn on the basis of common phenomenological understanding of the TPVs. - Highlights: • Dynamic vulcanization of 50:50 PP/NR blend by high energy electron beam. • PP/NR TPVs show rubber like behavior with melt processability. • High tensile strength of 15 MPa and large extensibility beyond 500%. • Complete phase inversed morphology from NR to PP matrix. • Vulcanized natural rubber particle size of 1–3 ?m.

  20. Rheological behaviour of thermoplastic poly(ester-siloxanes

    Directory of Open Access Journals (Sweden)

    Anti? Vesna V.

    2010-01-01

    Full Text Available Two series of thermoplastic elastomers (TPES based on poly(dimethylsiloxane, (PDMS as the soft segment and poly(butylene terephthalate (PBT as the hard segment, were analyzed by dynamic mechanical spectroscopy. In the first TPES series the lengths of both hard and soft segments were varied while the mass ratio of the hard to soft segments was nearly constant (about 60 mass%. In the second series, the mass ratio of hard and soft segments was varied in the range from 60/40 to 40/60, with a constant length of soft PDMS segments. The influence of the structure and composition of TPESs on the rheological properties, such as complex dynamic viscosity, ?*, the storage, G’, and loss, G”, shear modulus as well as the microphase separation transition temperature, TMST, was examined. The obtained results showed that the storage modulus of the TPESs increased in a rubbery plateau region with increasing degree of crystallinity. The rheological measurements of TPESs also showed that a microphase reorganization occurred during the melting process. The microphase separation transition temperatures were in the range from 220 to 234 °C. In the isotropic molten state, the complex dynamic viscosity increased with increasing both the content and lenght of hard PBT segments.

  1. 3-D stamp forming of thermoplastic matrix composites

    Science.gov (United States)

    Hou, M.; Friedrich, K.

    1994-03-01

    In this investigation a mould with hemispherical cavity and 80 kN hydraulic press, allowing variable stamping speeds, are employed for experimentally studying of the 3-D stamp forming process of continuous fiber reinforced thermoplastic laminates. In particular, glass fiber (GF) reinforced polyetherimide (PEI) woven fabric made of sheath surrounded, polymer powder impregnated fiber bundles manufactured by Enichem, Italy, is used. Pre-consolidated laminates are heated by contact heating in an external heater up to about 120°C above the glass transition temperature ( T g) of the polymer matrix; they are then stamp formed in a cold matched metal tool. Typical cycle times (including preheating time of the preconsolidated laminates) are in the range of 3 min. Useful processing conditions, such as stamping temperature, stamping velocity and hold-down pressure required for stamp forming of this composite are determined. In addition the effect of die geometries (deformation radian) and original laminate dimensions are studied. The results describe the correlations between processing parameters and fiber buckling. Finally the thickness distribution in stamped parts are investigated in relation to different directions of fiber orientation.

  2. Biosynthesis of novel thermoplastic polythioesters by engineered Escherichia coli

    Science.gov (United States)

    Lütke-Eversloh, Tina; Fischer, Andreas; Remminghorst, Uwe; Kawada, Jumpei; Marchessault, Robert H.; Bögershausen, Ansgar; Kalwei, Martin; Eckert, Hellmut; Reichelt, Rudolf; Liu, Shuang-Jiang; Steinbüchel, Alexander

    2002-12-01

    The development of non-petrochemical sources for the plastics industry continues to progress as large multinationals focus on renewable resources to replace fossil carbon. Many bacteria are known to accumulate polyoxoesters as water-insoluble granules in the cytoplasm. The thermoplastic and/or elastomeric behaviour of these biodegradable polymers holds promise for the development of various technological applications. Here, we report the synthesis and characterization of microbial polythioesters (PTEs), a novel class of biopolymers of general technological relevance. Biosynthesis of PTE homopolymers was achieved using a recombinant strain of Escherichia coli that expressed a non-natural pathway consisting of a butyrate kinase, a phosphotransbutyrylase, and a PHA synthase. Different homopolymers were produced, consisting of either 3-mercaptopropionate, 3-mercaptobutyrate, or 3-mercaptovalerate repeating units, if the respective mercaptoalkanoic acids were provided as precursor substrates to the fermentative process. The PTEs contributed up to 30% (w/w) of the cellular dry weight and were identified as hydrophobic inclusions in the cytoplasm. The chemical and stereochemical homogeneity of the purified PTEs were identified by different methods, and the estimated physical properties were compared to the oxypolyester equivalents, revealing low crystalline order and, for the poly(3-mercaptopropionate) improved thermal stability. The ability to produce PTEs through a biosynthetic route opens up new avenues in the field of biomaterials.

  3. Thermoplastic microchannel fabrication using carbon dioxide laser ablation.

    Science.gov (United States)

    Wang, Shau-Chun; Lee, Chia-Yu; Chen, Hsiao-Ping

    2006-04-14

    We report the procedures of machining microchannels on Vivak co-polyester thermoplastic substrates using a simple industrial CO(2) laser marker. To avoid overheating the substrates, we develop low-power marking techniques in nearly anaerobic environment. These procedures are able to machine microchannels at various aspect ratios. Either straight or serpent channel can be easily marked. Like the wire-embossed channel walls, the ablated channel surfaces become charged after alkaline hydrolysis treatment. Stable electroosmotic flow in the charged conduit is observed to be of the same order of magnitude as that in fused silica capillary. Typical dynamic coating protocols to alter the conduit surface properties are transferable to the ablated channels. The effects of buffer acidity on electroosmotic mobility in both bare and coated channels are similar to those in fused silica capillaries. Using video microscopy we also demonstrate that this device is useful in distinguishing the electrophoretic mobility of bare and latex particles from that of functionalized ones. PMID:16288768

  4. Performance of polymeric films based thermoplastic starch and organophilic clay

    International Nuclear Information System (INIS)

    The aim of this work was the development and investigation of the properties of flat films of LDPE/corn thermoplastic starch (TPS). A bentonite clay (Argel) was organophilized and characterized by XRD. This clay (1%) in both pristine and organophilic forms was added to the matrix (LDPE) and to LDPE/TPS systems with TPS contents varying from 5-20% w/w. The films manufactured (LDPE, LDPE/Clay, LDPE/TPS, LDPE/TPS/Clay) were characterized. Results indicate that water vapor permeability is dependent and increases with TPS content which was attributed to the higher affinity of water by TPS. TPS and Clay addition to LDPE led to significant changes in film properties with respect to the neat LDPE. In general,tensile and perforation forces increased with clay and TPS contents; the strength of thermo sealed films lowered with natural clay addition and increased with TPS and organoclay incorporation and, in general, dynamic friction coefficient decrease with organoclay and TPS addition. Best overall properties were obtained for the systems containing the organoclay and optimal properties were achieved for the 5%TPS10 LDPE1% ANO system. (author)

  5. Thermoplastic encapsulation of waste surrogates by high-shear mixing

    International Nuclear Information System (INIS)

    Brookhaven National Laboratory (BNL) has developed a robust, extrusion-based polyethylene encapsulation process applicable to a wide range of solid and aqueous low-level radioactive, hazardous and mixed wastes. However, due to the broad range of physical and chemical properties of waste materials, pretreatment of these wastes is often required to make them amenable to processing with polyethylene. As part of the scope of work identified in FY95 open-quotes Removal and Encapsulation of Heavy Metals from Ground Water,close quotes EPA SERDP No. 387, that specifies a review of potential thermoplastic processing techniques, and in order to investigate possible pretreatment alternatives, BNL conducted a vendor test of the Draiswerke Gelimat (thermokinetic) mixer on April 25, 1995 at their test facility in Mahwah, NJ. The Gelimat is a batch operated, high-shear, high-intensity fluxing mixer that is often used for mixing various materials and specifically in the plastics industry for compounding additives such as stabilizers and/or colorants with polymers

  6. Two-dimensional Stamp Forming Analysis for Thermoplastic Composites

    Directory of Open Access Journals (Sweden)

    Chih-Min Ma

    2013-01-01

    Full Text Available Fiber-reinforced thermoplastics have been gaining popularity for many of the weight critical components in the aerospace and automotive industries. They offer the potential advantage because they are molded in mass-production more easily than are reinforced thermosets. In this study, the main purpose is focused on the two-dimensional stamp forming process for the manufacturing of carbon fiber reinforced polyamide-6. Two different mold angles (90°, 120° are discussed. The experiments are conducted based on five factors (two levels each split-plot design with Taguchi L16 orthogonal array. The processing conditions, e.g., the thermoforming temperature, mold temperature, pressure and time, required to give high-quality parts are established. By the results of the analysis of variance (ANOVA, this study derives the best set of the parameters and their estimated equations under different mold angle, respectively. The results have described the correlations between processing parameters and shear stress. Furthermore, for verifying the prediction ability of the estimated equations, the confirmation experiments are conducted. The confirmatory test results, 48.67 and 48.16 kg mm-2, fall in their confidence interval, respectively. It shows that both of the prediction ability of estimated equation and the repetition of the experimental results have confirmed and accepted by the tests.

  7. Optimization of Stamp Forming Process for Thermoplastic Composites

    Directory of Open Access Journals (Sweden)

    Chih-Min Ma

    2014-02-01

    Full Text Available The present study is focused on the development of a two-dimensional stamping method for the manufacturing of fiber reinforced composites with thermoplastic matrix resins. Materials investigated are carbon fiber reinforced polyamide-6. Taguchi L16 orthogonal array is used in split-plot designs. The processing conditions include thermoforming temperature, mold temperature, pressure and time, required to establish high-quality parts. From the experimental results, we derive a set of best combination, A1 (90°, B2 (263?C, C1 (105?C, D1 (33 kg/cm2 and E2 (48 sec and carry out an estimated equation for the short-beam shear strength. The results have described the correlations between processing parameters and shear stress. Finally, for verifying the prediction ability of the estimated equation, the confirmation experiments are conducted. The confirmation test result is 48.67 kg/mm2, fall in the confidence interval. It shows that the prediction ability of estimated equation and the repetition of the experimental results has confirmed and accepted by the tests.

  8. Thermoplastic polyurethane synthesis using POSS as a chain modifier

    Scientific Electronic Library Online (English)

    Gabriel Hoyer, Lopes; Janaína, Junges; Rudinei, Fiorio; Mara, Zeni; Ademir José, Zattera.

    2012-08-01

    Full Text Available In this study, thermoplastic polyurethanes (TPUs) were synthesized using the one-shot process in solution. To obtain the samples n-phenylaminopropyl polyhedric oligomeric silsesquioxane (POSS) was added as a chain modifier during the synthesis in four different amounts. The samples were characterize [...] d by infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and capillary rheometry. FTIR confirm the TPU attainment due the absence of the band at ~2253 cm-1 suggesting a complete conversion of the isocyanate terminations. The TGA showed that incorporation of POSS decreased the rate of mass loss of TPU under isothermal conditions. The flexible phase showed an enhanced stability to temperature, probably due to increased phase separation between the rigid and flexible domains. The DSC showed that incorporation of 0.4 wt. (%) of POSS increased the glass transition temperature of the flexible phase. Moreover, addition of POSS modified the melting behaviour, providing samples with a higher melting enthalpy compared to neat TPU as a consequence of the formation of larger crystals. The capillary rheometry analysis revels that the POSS addition showed a clear tendency toward higher intrinsic viscosities as the amount of POSS was increased.

  9. Microstructure and thermomechanical properties relationship of segmented thermoplastic polyurethane (TPU)

    Energy Technology Data Exchange (ETDEWEB)

    Frick, Achim, E-mail: achim.frick@htw-aalen.de; Borm, Michael, E-mail: achim.frick@htw-aalen.de; Kaoud, Nouran, E-mail: achim.frick@htw-aalen.de; Kolodziej, Jan, E-mail: achim.frick@htw-aalen.de; Neudeck, Jens, E-mail: achim.frick@htw-aalen.de [Institute of Polymer Science and Processing (iPSP), HTW Aalen (Germany)

    2014-05-15

    Thermoplastic polyurethanes (TPU) are important polymeric materials for seals. In competition with Acrylonitrile butadiene rubbers (NBR), TPU exhibits higher strength and a considerable better abrasion resistance. The advantage of NBR over TPU is a smaller compression set but however TPU excels in its much shorter processing cycle times. Generally a TPU is a block copolymer composed of hard and soft segments, which plays an important role in determining the material properties. TPU can be processed either to ready moulded parts or can be incorporated by multi component moulding, in both cases it shows decent mechanical properties. In the present work, the relationship between melt-process induced TPU morphology and resultant thermo mechanical properties were examined and determined by means of quasi-static tensile test, creep experiment, tension test and dynamical mechanical analysis (DMA). Scanning electron beam microscope (SEM) and differential scanning calorimeter (DSC) were used to study the morphology of the samples. A significant mathematical description of the stress-strain behaviour of TPU was found using a 3 term approach. Moreover it became evident that processing conditions such as processing temperature have crucial influence on morphology as well as short and long-term performance. To be more precise, samples processed at higher temperatures showed a lack of large hard segment agglomerates, a smaller strength for strains up to 250% and higher creep compliance.

  10. Thermoplastic polymeric adhesive for structural bonding applications for orthopaedic devices

    International Nuclear Information System (INIS)

    The orthopaedics industry has witnessed tremendous growth in recent years primarily due to the introduction of high performance, porous coated implants. These devices have eliminated the need for the use of bone cement for in vivo implant fixation, replacing it with the ingrowth of bone into the porous surfaces. The metallurgical bonding processes used for attaching the porous to the implant body introduce some undesirable effect i.e., the reduction of the fatigue strength of the implant due to the ''notches'' created and also due to the high temperature exposure during the sintering operations. This paper describes the development of a thermoplastic polymeric adhesive based structural bonding technique. The high performance polymeric adhesive is fully characterized with respect to its intended application. The design of the porous layer is optimized to achieve a reliable bond to the implant. A thermal heating/cooling process was developed to control the final polymer morphology. Static and fatigue tests were conducted to fully characterize the adhesive bond strength. A ring shear test method was developed to determine the shear strength of the bond interface. Besides the characterization of the adhesive bond, the joints will be analyzed using finite element models. The correlation between the analytical models and the

  11. Improved construction materials for polar regions using microcellular thermoplastic foams

    Science.gov (United States)

    Cunningham, Daniel J.

    1994-01-01

    Microcellular polymer foams (MCF) are thermoplastic foams with very small cell diameters, less than 10 microns, and very large cell densities, 10(exp 9) to 10(exp 15) cells per cubic centimeter of unfoamed material. The concept of foaming polymers with microcellular voids was conceived to reduce the amount of material used for mass-produced items without compromising the mechanical properties. The reasoning behind this concept was that if voids smaller than the critical flaw size pre-existing in polymers were introduced into the matrix, they would not affect the overall strength of the product. MCF polycarbonate (PC), polystyrene (PS), and polyvinyl chloride (PVC) were examined to determine the effects of the microstructure towards the mechanical properties of the materials at room and arctic temperatures. Batch process parameters were discovered for these materials and foamed samples of three densities were produced for each material. To quantify the toughness and strength of these polymers, the tensile yield strength, tensile toughness, and impact resistance were measured at room and arctic temperatures. The feasibility of MCF polymers has been demonstrated by the consistent and repeatable MCF microstructures formed, but the improvements in the mechanical properties were not conclusive. Therefore the usefulness of the MCF polymers to replace other materials in arctic environments is questionable.

  12. Multi-scale thermal stability of a hard thermoplastic protein-based material

    Science.gov (United States)

    Latza, Victoria; Guerette, Paul A.; Ding, Dawei; Amini, Shahrouz; Kumar, Akshita; Schmidt, Ingo; Keating, Steven; Oxman, Neri; Weaver, James C.; Fratzl, Peter; Miserez, Ali; Masic, Admir

    2015-09-01

    Although thermoplastic materials are mostly derived from petro-chemicals, it would be highly desirable, from a sustainability perspective, to produce them instead from renewable biopolymers. Unfortunately, biopolymers exhibiting thermoplastic behaviour and which preserve their mechanical properties post processing are essentially non-existent. The robust sucker ring teeth (SRT) from squid and cuttlefish are one notable exception of thermoplastic biopolymers. Here we describe thermoplastic processing of squid SRT via hot extrusion of fibres, demonstrating the potential suitability of these materials for large-scale thermal forming. Using high-resolution in situ X-ray diffraction and vibrational spectroscopy, we elucidate the molecular and nanoscale features responsible for this behaviour and show that SRT consist of semi-crystalline polymers, whereby heat-resistant, nanocrystalline ?-sheets embedded within an amorphous matrix are organized into a hexagonally packed nanofibrillar lattice. This study provides key insights for the molecular design of biomimetic protein- and peptide-based thermoplastic structural biopolymers with potential biomedical and 3D printing applications.

  13. Multi-scale thermal stability of a hard thermoplastic protein-based material

    Science.gov (United States)

    Latza, Victoria; Guerette, Paul A.; Ding, Dawei; Amini, Shahrouz; Kumar, Akshita; Schmidt, Ingo; Keating, Steven; Oxman, Neri; Weaver, James C.; Fratzl, Peter; Miserez, Ali; Masic, Admir

    2015-01-01

    Although thermoplastic materials are mostly derived from petro-chemicals, it would be highly desirable, from a sustainability perspective, to produce them instead from renewable biopolymers. Unfortunately, biopolymers exhibiting thermoplastic behaviour and which preserve their mechanical properties post processing are essentially non-existent. The robust sucker ring teeth (SRT) from squid and cuttlefish are one notable exception of thermoplastic biopolymers. Here we describe thermoplastic processing of squid SRT via hot extrusion of fibres, demonstrating the potential suitability of these materials for large-scale thermal forming. Using high-resolution in situ X-ray diffraction and vibrational spectroscopy, we elucidate the molecular and nanoscale features responsible for this behaviour and show that SRT consist of semi-crystalline polymers, whereby heat-resistant, nanocrystalline ?-sheets embedded within an amorphous matrix are organized into a hexagonally packed nanofibrillar lattice. This study provides key insights for the molecular design of biomimetic protein- and peptide-based thermoplastic structural biopolymers with potential biomedical and 3D printing applications. PMID:26387704

  14. Thermal Degradation, Mechanical Properties and Morphology of Wheat Straw Flour Filled Recycled Thermoplastic Composites

    Directory of Open Access Journals (Sweden)

    Kadir Karakus

    2008-01-01

    Full Text Available Thermal behaviors of wheat straw flour (WF filled thermoplastic compositeswere measured applying the thermogravimetric analysis and differential scanningcalorimetry. Morphology and mechanical properties were also studied using scanningelectron microscope and universal testing machine, respectively. Presence of WF inthermoplastic matrix reduced the degradation temperature of the composites. One for WFand one for thermoplastics, two main decomposition peaks were observed. Morphologicalstudy showed that addition of coupling agent improved the compatibility between WFs andthermoplastic. WFs were embedded into the thermoplastic matrix indicating improvedadhesion. However, the bonding was not perfect because some debonding can also be seenon the interface of WFs and thermoplastic matrix. In the case of mechanical properties ofWF filled recycled thermoplastic, HDPE and PP based composites provided similar tensileand flexural properties. The addition of coupling agents improved the properties ofthermoplastic composites. MAPE coupling agents performed better in HDPE while MAPPcoupling agents were superior in PP based composites. The composites produced with thecombination of 50-percent mixture of recycled HDPE and PP performed similar with theuse of both coupling agents. All produced composites provided flexural properties requiredby the ASTM standard for polyolefin-based plastic lumber decking boards.

  15. Multi-scale thermal stability of a hard thermoplastic protein-based material.

    Science.gov (United States)

    Latza, Victoria; Guerette, Paul A; Ding, Dawei; Amini, Shahrouz; Kumar, Akshita; Schmidt, Ingo; Keating, Steven; Oxman, Neri; Weaver, James C; Fratzl, Peter; Miserez, Ali; Masic, Admir

    2015-01-01

    Although thermoplastic materials are mostly derived from petro-chemicals, it would be highly desirable, from a sustainability perspective, to produce them instead from renewable biopolymers. Unfortunately, biopolymers exhibiting thermoplastic behaviour and which preserve their mechanical properties post processing are essentially non-existent. The robust sucker ring teeth (SRT) from squid and cuttlefish are one notable exception of thermoplastic biopolymers. Here we describe thermoplastic processing of squid SRT via hot extrusion of fibres, demonstrating the potential suitability of these materials for large-scale thermal forming. Using high-resolution in situ X-ray diffraction and vibrational spectroscopy, we elucidate the molecular and nanoscale features responsible for this behaviour and show that SRT consist of semi-crystalline polymers, whereby heat-resistant, nanocrystalline ?-sheets embedded within an amorphous matrix are organized into a hexagonally packed nanofibrillar lattice. This study provides key insights for the molecular design of biomimetic protein- and peptide-based thermoplastic structural biopolymers with potential biomedical and 3D printing applications. PMID:26387704

  16. Training programme impact on thermoplastic immobilization for head and neck radiation therapy

    International Nuclear Information System (INIS)

    Purpose: To determine whether uniform guidelines and training in the stabilization and formation of thermoplastic shells can improve the reproducibility of set-up for Head and Neck cancer patients. Methods and materials: Image based measurements of the planning and treatment positions for 35 head and neck cancer patients undergoing radical radiotherapy were analysed to provide a baseline of the reproducibility of thermoplastic immobilization. Radiation therapists (RT) were surveyed to establish a perception of their confidence in thermoplastic procedures. An evidence based staff training programme was created and implemented. Set-up reproduction and staff perception were reviewed to measure the impact of the training programme. Results: The mean (SD) 3D vectors of anatomical displacement, measured on the patient images, improved from 4.64 (2.03) for the baseline group compared to 3.02 (1.65) following training (p < 0.01). The proportion of 3D displacements of patient data exceeding 5 mm 3D vector was decreased from 37.1% to 5.7% (p < 0.001) and the 3 mm vector from 85.7% to 42.9% (p < 0.001). The post-training survey scores demonstrated improved confidence in reproducibility of set-up for head and neck patients. Conclusion: The Thermoplastic Shells Training Program has been found to improve the treatment reproducibility for head and neck radiation therapy patients. Uniform guidelines have increased RT confidence in thermoplastic procedures.

  17. Application of electrically conductive thermoplastic adhesive film for design and manufacturing of smart structures

    Science.gov (United States)

    Javidinejad, Amir; Joshi, Shiv P.; Shiakolas, Panayiotis S.

    1999-06-01

    The ongoing research and development of cost effective technology for remotely queried sensors for health and usage monitoring of composite structures has lead to the application of electrically conductive thermoplastic adhesive films. This paper intends to provide an in depth overview of a newly developed technology for the design and manufacturing of smart structures by introducing the application of electrically conductive thermoplastic adhesive films. The current technology is discussed and compared with this newly developed technology. It is shown that the structural aspects of this new technology are advantageous to smart structures' concept as a whole. Fabrication and manufacturing techniques for this new technology is discussed including the suitability of the process for automation. Specifically, standard tensile testing of the manufactured composite coupons with embedded thermoplastic conductive adhesive films has been performed and compared to the test results from copper embedded coupons. The effect of embedded thermoplastic stripes on stiffness as well as strength of the parent laminated- structure is evaluated and discussed. Further, fatigue testing has been done at various ultimate failure strength percentiles to determine some degree of the fatigue life of the composite and the embedded conductive and insulting films. The conductive thermoplastic films are found to be structurally superior to copper when embedded in a composite structure but the electrical conductivity is not as good as copper or other metallic conductors.

  18. Design and structural testing of smart composite structures with embedded conductive thermoplastic film

    Science.gov (United States)

    Javidinejad, Amir; Joshi, Shiv P.

    1999-10-01

    The ongoing research and development of cost effective technology for remotely queried sensors for health and usage monitoring of composite structures has lead to the application of electrically conductive thermoplastic adhesive films. This paper intends to provide an in depth overview of a newly developed technology for the design and manufacturing of smart structures by introducing the application of electrically conductive thermoplastic adhesive films. The current technology is discussed and compared with this newly developed technology. It is shown that the structural aspects of this new technology are advantageous to the concept of smart structures as a whole. Fabrication and manufacturing techniques for this new technology is discussed, including the suitability of the process for automation. Specifically, standard tensile testing of the manufactured composite coupons with embedded thermoplastic conductive adhesive films have performed and compared to the test results from copper embedded coupons. The effect of embedded thermoplastic stripes on stiffness as well as strength of the parent laminated structure is evaluated and discussed. Furthermore, fatigue testing was performed at various ultimate failure strength percentiles to determine some degree of the fatigue life of the composite and the embedded conductive and insulting films. The conductive thermoplastic films are found to be structurally superior to copper when embedded in a composite structure, but the electrical conductivity is not as good as copper or other metallic conductors.

  19. Processing and properties of natural fibers reinforced thermoplastic and thermosseting composites

    OpenAIRE

    Silva, J. F; Nunes, J. P.; Duro, A. C.; Castro, B. F.

    2013-01-01

    In this work, three different natural fibers were studied and characterized, using optical and SEM microscopy. Woven fabrics of those reinforcement fibers were used to reinforce polyester and epoxy matrices and produce composite plates by vacum lay-up. Also, using an experimental piston blender equipment, long fiber reinforced PLA (LFT) composites were manufactured by hot compression molding. All different obtained composite plates were submitted to mechanical testing in order to determin...

  20. Multiblock thermoplastic polyurethanes for biomedical and shape memory applications

    Science.gov (United States)

    Gu, Xinzhu

    Polyurethanes are a class of polymers that are capable of tailoring the overall polymer structure and thus final properties by many factors. The great potential in tailoring polymer structures imparts PUs unique mechanical properties and good cytocompatibility, which make them good candidates for many biomedical devices. In this dissertation, three families of multiblock thermoplastic polyurethanes are synthesized and characterized for biomedical and shape memory applications. In the first case described in Chapters 2, 3 and 4, a novel family of multiblock thermoplastic polyurethanes consisting of poly(?-caprolactone) (PCL) and poly(ethylene glycol) (PEG) are presented. These materials were discovered to be very durable, with strain-to-break higher than 1200%. Heat-triggered reversible plasticity shape memory (RPSM) was observed, where the highly deformed samples completely recovered their as-cast shape within one minute when heating above the transition temperature. Instead of conventional "hard" blocks, entanglements, which result from high molecular weight, served as the physical crosslinks in this system, engendering shape recovery and preventing flow. Moreover, water-triggered shape memory effect of PCL-PEG TPUs is explored, wherein water permeated into the initially oriented PEG domains, causing rapid shape recovery toward the equilibrium shape upon contact with liquid water. The recovery behavior is found to be dependent on PEG weight percentage in the copolymers. By changing the material from bulk film to electrospun fibrous mat, recovery speed was greatly accelerated. The rate of water recovery was manipulated through structural variables, including thickness of bulk film and diameter of e-spun webs. A new, yet simple shape memory cycle, "wet-fixing" is also reported, where both the fixing and recovery ratios can be greatly improved. A detailed microstructural study on one particular composition is presented, revealing the evolution of microphase morphology during the shape memory cycle. Then, in Chapter 5, the role of Polyhedral oligosilsesquioxane (POSS) in suppressing enzymatic degradation of PCL-PEG TPUs is investigated. In vitro enzymatic hydrolytic biodegradation revealed that POSS incorporation significantly suppressed degradation of PCL-PEG TPUs. All TPUs were surface-eroded by enzymatic attack in which the chemical composition and the bulk mechanical properties exhibited little changes. A surface passivation mechanism is proposed to explain the protection of POSS-containing TPUs from enzymatic degradation. Finally, Chapter 6 presents another POSS-based TPUs system with PLA-based polyol as the glassy soft block. Manipulation of the final thermal and mechanical properties is discussed in terms of different polyols and POSS used. The free recovery and the constrained recovery responses of the polymer films were demonstrated as a function of the prior "fixing" deformation temperature. In addition, this family of materials was capable of memorizing their T g., where optimal recovery breadth and recovery stress were achieved when pre-deformation occurred right at Tg.

  1. Long-term in vitro hydrolytic stability of thermoplastic polyurethanes.

    Science.gov (United States)

    Mishra, Abhinay; Seethamraju, Kasyap; Delaney, Joseph; Willoughby, Patrick; Faust, Rudolf

    2015-12-01

    Long-term in vitro stability of thermoplastic polyurethanes (TPUs) was studied for up to 52 weeks in phosphate buffer solution at 37, 55, and 80°C. Water uptake, molecular weights, and tensile properties were measured at regular intervals of 4, 8, 16, 32, and 52 weeks. The rate of molecular weight reduction increased with increasing temperature, and after 52 weeks at 80°C, all commercial polycarbonate (Bionate-55D, Quadrathane-80A, and Chronoflex-80A), poly(dimethylsiloxane) (ElastEon-2A) and polyether (Elasthane-55D) TPUs showed significant (43-51%) molecular weight (Mn ) reduction. The polyisobutylene (PIB)-based TPU exhibited a significantly lower decrease in Mn (26%) after 52 weeks at 80°C. For Bionate-55D and ElastEon-2A, at 80°C in dry nitrogen atmosphere substantial thermal degradation was observed, while for the other TPUs the effect of thermal degradation is small. The temperature dependent reduction of molecular weight was interpreted by simple second order kinetics. From the approximately linear Arrhenius plots the activation energies were calculated, which were highest for PIB-PU-020 and lowest for ElastEon-2A. For Elasthane-55D the in vitro molecular weight reduction was compared with that of explanted leads. The molecular weight reduction in vivo was much smaller than that predicted from in vitro data, which may suggest that the in vitro model does not adequately describe the hydrolysis in vivo. In the absence of validation for the other TPUs that in vitro methods closely reproduce in vivo degradation, it is unknown how these results correlate with in vivo performance. © 2015 Wiley Periodicals, Inc. J Biomed Mater Res Part A: 103A: 3798-3806, 2015. PMID:26097127

  2. Dielectric relaxation spectroscopy of thermoplastic polymers and blends

    International Nuclear Information System (INIS)

    The basic theory of dielectric relaxation spectroscopy (DRS) as it applies to condensed polymeric materials is briefly covered in this review. This involves the origin of dielectric relaxation and mathematical modelling of the resultant data in both the frequency and time domains. Issues associated with molecular mobility such as coupling theory which relates relaxation spectra to intermolecular interactions between polymer chains are covered. The mechanism and temperature dependence of primary and secondary relaxations of amorphous polymers is also discussed. In semi crystalline polymers information on the nature and environment of polymer chains in the interfacial region between crystalline and amorphous zones (rigid-amorphous phase) can be elucidated by monitoring their dielectric mobility. Experimental aspects of DRS are also briefly mentioned. To demonstrate the application of DRS, a literature review of its use in the analysis of thermoplastic blends is presented. As well as allowing determination of the existence of one or more phases in a polymer blend, a range of dielectric parameters can be determined which give information about the state of a blend on a micro-level. In miscible polymer blends, for example, the broadness of the ? - relaxation loss spectra is indicative of the range of molecular environments, concentration fluctuations and the degree of coupling between different macromolecular chains. In semicrystalline miscible blend materials, dielectric spectra can yield information about the nature of the crystalline interface in blends, addressing issues such as whether this region consists only of chains of the semi crystalline phase or whether it is phase mixed. In immiscible systems, interfacial polarisation can also influence the dielectric spectra and lead to a greater understanding of phase morphology. 204 refs., 2 tabs., 18 figs

  3. Final Report: Interphase Analysis and Control in Fiber Reinforced Thermoplastic Composites

    Energy Technology Data Exchange (ETDEWEB)

    Jon J. Kellar; William M. Cross; Lidvin Kjerengtroen

    2009-03-14

    This research program builds upon a multi-disciplinary effort in interphase analysis and control in thermoplastic matrix polymer matrix composites (PMC). The research investigates model systems deemed of interest by members of the Automotive Composites Consortium (ACC) as well as samples at the forefront of PMC process development (DRIFT and P4 technologies). Finally, the research investigates, based upon the fundamental understanding of the interphases created during the fabrication of thermoplastic PMCs, the role the interphase play in key bulk properties of interest to the automotive industry.

  4. Characterization of elastic-viscoplastic properties of an AS4/PEEK thermoplastic composite

    Science.gov (United States)

    Yoon, K. J.; Sun, C. T.

    1991-01-01

    The elastic-viscoplastic properties of an AS4/PEEK (APC-2) thermoplastic composite were characterized at 24 C (75 F) and 121 C (250 F) by using a one-parameter viscoplasticity model. To determine the strain-rate effects, uniaxial tension tests were performed on unidirectional off-axis coupon specimens with different monotonic strain rates. A modified Bodner and Partom's model was also used to describe the viscoplasticity of the thermoplastic composite. The experimental results showed that viscoplastic behavior can be characterized quite well using the one-parameter overstress viscoplasticity model.

  5. Lignin-derived thermoplastic co-polymers and methods of preparation

    Energy Technology Data Exchange (ETDEWEB)

    Naskar, Amit K.; Saito, Tomonori; Pickel, Joseph M.; Baker, Frederick S.; Eberle, Claude Clifford; Norris, Robert E.; Mielenz, Jonathan Richard

    2014-06-10

    The present invention relates to a crosslinked lignin comprising a lignin structure having methylene or ethylene linking groups therein crosslinking between phenyl ring carbon atoms, wherein said crosslinked lignin is crosslinked to an extent that it has a number-average molecular weight of at least 10,000 g/mol, is melt-processible, and has either a glass transition temperature of at least 100.degree. C., or is substantially soluble in a polar organic solvent or aqueous alkaline solution. Thermoplastic copolymers containing the crosslinked lignin are also described. Methods for producing the crosslinked lignin and thermoplastic copolymers are also described.

  6. Rapid, controllable and environmentally benign fabrication of thermoplastic nanofibers and applications

    Science.gov (United States)

    Wang, Dong

    In situ fibrillar and lamellar hybrid morphology was found in various immiscible polymer blends prepared by melt ram extrusion of cellulose acetate butyrate (CAB)/Thermoplastics at a weight ratio of 80 to 20. The formation process was analyzed and proposed. The presence of the elongational flow field determines the formation of the fibrils, and the improvement of the mixing efficiency can significantly reduce the dimensions of formed fibrils into the submicro- or nano-scale. With above results, continuous and uniform yarns of thermoplastic nanofibers were prepared via direct melt twin-screw extrusion, providing better mixing efficiency of immiscible blends of thermoplastic polymers with cellulose acetate butyrate (CAB), and subsequent extraction removal of CAB matrix. The thermoplastics which can be made into nanofibers include polyesters, polyolefins, thermoplastic polyurethane and functional copolymers, such as PE-co-GMA (Poly(Ethylene-co-Glycidyl Methacrylate)), PVA-co-PE (Poly(Vinyl Alcohol-co-Ethylene)). Ratios of thermoplastics to sacrificial CAB matrix, melt viscosity, and interfacial tensions affect formation of the nanofibers. Moreover, the crystal structures of isotactic polypropylene (iPP) nanofiber prepared were characterized with DSC and WAXD. To further demonstrate the size and shape controllability of the thermoplastic nanomaterials, polyethylene materials were selected and prepared into micro- or submicrospheres or nanofibers with different diameters and shapes by varying the composition ratio and modifying the interface properties via melt blending or extrusion of cellulose acetate butyrate (CAB)/LDPE melt blends and subsequent removal of the CAB. The surface structures of the LDPE micro- or submicrospheres and nanofibers were analyzed using SEM, FTIR-ATR spectroscopy, DSC and torque rheometer. The biotechnological applications of the thermoplastic nanofibers are also exploited. Poly(ethylene-co-glycidyl methacrylate) (PE-co-GMA) nanofibers with abundant active epoxy groups on surfaces were fabricated through above technique. The prepared PE-co-GMA nanofibers were aminated by reacting the epoxy groups with 1,3-diaminopropane. The resulting aminated PE-co-GMA nanofibers were subsequently biotinylated and then successfully applied to immobilize streptavidin-horseradish peroxidase (HRP) conjugate via specific, strong and rapid binding of biotin and streptavidin. The high activity, efficiency, sensitivity as well as good reusability of the streptavidin-HRP immobilized PE-co-GMA nanofibers demonstrated that PE-co-GMA nanofibers could be a promising candidate as solid support materials for potential biosensor applications.

  7. Thermoplastic nanoclay-modified vulcanizates based on polypropylene and nitrile-butadiene rubber

    Science.gov (United States)

    Volfson, Svetoslav I.; Okhotina, Natalya A.; Nigmatullina, Alina I.; Panfilova, Olga A.

    2014-05-01

    Thermoplastic vulcanizates based on polypropylene and nitrile-butadiene rubber, containing modified organoclay were developed. It was shown that composites containing 1 to 5 pbw of Cloisite 15A montmorillonite added to rubber show improved physical-mechanical characteristics. Their swelling degree in AI-92 and motor oil was determined. The swelling degree of composites in petrol and motor oil decreases substantially, by 20-63%, due to the introduction of Cloisite 15A montmorillonite. Modification of thermoplastic vulcanizates using layered silicates raised the degradation onset temperature and decreases weight loss upon high temperature heating.

  8. Sensitivity analysis for the process integrated online polarization of piezoceramic modules in thermoplastic composites

    Science.gov (United States)

    Hufenbach, W.; Gude, M.; Modler, N.; Heber, T.; Tyczynski, T.

    2010-10-01

    The use of active composite structures in high-volume applications requires novel robust manufacturing processes as well as specially adapted functional modules. The paper presents actual research results with regard to the process-immanent polarization of novel thermoplastic-compatible piezoceramic modules (TPM) during the consolidation process of active fibre-reinforced thermoplastic composite structures. In particular the influence of varying manufacture process parameters of a hot-press process on the polarization behaviour is investigated. The main principal objective is the purposeful utilization of process parameters for polarization support.

  9. Computer-based manufacturing cost analysis for the fabrication of thermoplastic composite structures

    Science.gov (United States)

    Foley, Michael; Bernardon, Edward

    1990-01-01

    Advanced composite structures are very expensive to manufacture. Cost estimation techniques are useful as tools for increasing cost effectiveness in part design, in selecting materials, and in the design of automated systems and manufacturing processes. A computer-based cost estimation model has been developed for analyzing the manufacturing costs involved in the fabrication of thermoplastic composite structures. The model, described in detail in this paper, evaluates existing manual and automated techniques for manufacturing a thermoplastic composite skin. Cost analysis results and their relevance to increasing cost effectiveness are discussed.

  10. Recycling of ligno-cellulosic and polyethylene wastes from agricultural operations in thermoplastic composites

    Science.gov (United States)

    In the US, wood plastic composites (WPC) represent one of the successful markets for natural fiber-filled thermoplastic composites. In the past several years, the availability of good quality wood fiber has been diminishing and prices of wood and plastic have been increasing. Therefore, the vast qua...

  11. EFFECT OF MALEIC ANHYDRIDE ON KENAF DUST FILLED POLYCAPROLACTONE/THERMOPLASTIC SAGO STARCH COMPOSITES

    Directory of Open Access Journals (Sweden)

    Siang Yee Chang,

    2012-02-01

    Full Text Available The utilization of biodegradable polymers for various applications has been restricted mainly by its high cost. This report aims to study the water absorption and mechanical properties of kenaf dust-filled polycaprolactone/thermoplastic sago starch biodegradable composites as a function of filler loading and treatment with maleic anhydride. While water absorption in untreated biocomposites increased as a function of filler loading, treated biocomposites resulted in weight loss, whereby low molecular weight substances were dissolved into the aging medium. The kenaf dust imparts reinforcing effects on the biocomposites, resulting in improved mechanical properties. This is further attested by morphological studies in which kenaf dust was well dispersed in the polycaprolactone/ thermoplastic sago starch blend matrix. The addition of maleic anhydride into the polycaprolactone/thermoplastic sago starch blend resulted in a homogeneous mixture. At low filler loading, strain at break of the maleated polycaprolactone/thermoplastic sago starch blend increased at the expense of tensile strength and modulus. This is most likely due to the excessive dicumyl peroxide content, which caused chain scission of the polycaprolactone backbone. Tensile strength and modulus improved only when high filler loading was employed.

  12. ELASTO-PLASTIC STRESS ANALYSIS OF THERMOPLASTIC MATRIX COMPOSITE LAMINATED PLATES UNDER IN-PLANE LOADING

    Directory of Open Access Journals (Sweden)

    Ahmet YAPICI

    1999-02-01

    Full Text Available Thermoplastic matrix reinforced with metal fiber, composite laminated plates were anufactured by using moulds. The symmetric and antisymmetric laminated plates were loaded by in-plane forces. An elastic-plastic numerical solution has been carried out by finite element technique (FEM for some load steps. Residual stresses and expansion of plastic zone have been illustrated in tables and figures.

  13. Novel segmented thermoplastic polyurethanes elastomers based on tetrahydrofuran ethylene oxide copolyethers as high energetic propellant binders

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Fu-Tai; Duo, Ying-Quan; Luo, Shan-Guo; Luo, Yun-Jun; Tan, Hui-Min [School of Chemical Engineering and Materials Science, Beijing Institute of Technology, Beijing 100081 (China)

    2003-02-01

    Novel thermoplastic polyurethane (TPU) elastomers based on copolyether (tetrahydrofuran ethylene oxide) as soft segments, isophorone diisocyanate and 1,4-butanediol as hard segments were synthesized for the purpose of using as propellant binders. In order to increase the miscibility of thermoplastic polyurethane elastomers with nitrate ester, polyethylene glycol (PEG) is incorporated in the co-polyether (tetrahydrofuran ethylene oxide) as soft segment. When the molecular weight and content of polyethylene glycol are controlled to 4000 and 6% of soft segments, respectively, the properties of thermoplastic polyurethane elastomers are most perfect. If plasticizing ratio of nitrate ester to thermoplastic polyurethane elastomers exceeds 4 no crystallinities are determined at room temperature. The propellant samples were prepared by a conventional absorption-rolling extrusion process and the mechanical and combustion properties evaluated afterwards. The maximum impulse reaches up to 265{proportional_to}270 s which is a little bit higher than that of a HTPB propellant. The measured results reveal a promising TPE propellant candidate which shows good processing temperature (<393 K) and excellent mechanical properties. An attracting feature which can be pointed out is that the burning rate pressure exponent reaches as low as 0.36 without the addition of burning rate catalysts. This enables an easy control of propellant combustion. (Abstract Copyright [2003], Wiley Periodicals, Inc.)

  14. [Laboratory assessment of deformational features in thermoplastic materials for removable dentures].

    Science.gov (United States)

    Poiurovskaia, I Ia; Sutugina, T F; Babaev, S A; Ron, O S

    2014-01-01

    The paper presents the results of laboratory tests of base thermoplastic materials Acry F711 and Flexi N512 in comparison with the traditional acrylic base material Ftoracs to study their deformational properties when loaded by repetitive forces close to the functional chewing loads. PMID:25588331

  15. Studies on the structure and properties of thermoplastic starch/luffa fiber composites

    International Nuclear Information System (INIS)

    Highlights: ? Thermoplastic starch/luffa fiber composites were prepared using compression molding. ? The tensile strengths of the composites were higher than for thermoplastic starch. ? Degradation temperatures of the composites were higher than for thermoplastic starch. ? Luffa fiber decreases the water absorption of TPS. -- Abstract: Thermoplastic starch (TPS)/luffa fiber composites were prepared using compression molding. The luffa fiber contents ranged from 0 wt.% to 20 wt.%. The tensile strength of the TPS/luffa fiber composite with 10 wt.% of luffa fiber had a twofold increase compared to TPS. The temperature values of maximum weight loss of the TPS/luffa fiber composites were higher than for TPS. The water absorption of the TPS/luffa fiber composites decreased significantly when the luffa fiber contents increased. The strength of adhesion between the luffa fiber and the TPS matrix was clearly demonstrated by their compatibility presumably due to their similar chemical structures as shown by scanning electron microscope (SEM) micrographs and Fourier transform infrared (FTIR) spectra.

  16. Mechanical Properties of Thermoplastic Polyurethanes Laminated Glass Treated by Acid Etching Combined with Cold Plasma

    International Nuclear Information System (INIS)

    To overcome the problem of interlaminar delamination of thermoplastic polyurethane laminated glass, silicate glass was etched with hydrofluoric acid and thermoplastic polyurethane was then treated with cold plasma. Compared with the untreated samples, the interlaminar shear strength of acid etching samples, cold plasma-treated samples and acid etching combined with cold plasma-treated samples increased by 97%, 84% and 341%, respectively. Acid etching combined with cold plasma-treated samples exhibited a higher flexural strength and strain as compared with the untreated samples. The impact energy of acid etching samples, cold plasma-treated samples and acid etching combined with cold plasma-treated samples increased by 8.7%, 8.1% and 11.6%, respectively, in comparison with the untreated samples. FT-IR analysis showed that a large number of –C=O, –CO–N and –CO–O–C– groups appeared on the surface of cold plasma-treated thermoplastic polyurethane, which resulted in the formation of hydrogen bonds. SEM results showed that some pittings formed on the surface of the silicate glass treated by acid etching, which resulted in the formation of a three-dimensional interface structure between the silicate glass and polyurethane. Hydrogen bonds combined with the three-dimensional interface between silicate glass and polyurethanes co-improved the mechanical properties of thermoplastic polyurethanes laminated glass. (plasma technology)

  17. Impact of thermoplastic mask on X-ray surface dose calculated with Monte Carlo code

    International Nuclear Information System (INIS)

    Objective: To calculate the effects of thermoplastic mask on X-ray surface dose. Methods: The BEAMnrc Monte Carlo Code system, designed especially for computer simulation of radioactive sources, was performed to evaluate the effects of thermoplastic mask on X-ray surface dose.Thermoplastic mask came from our center with a material density of 1.12 g/cm2. The masks without holes, with holes size of 0.1 cm x 0.1 cm, and with holes size of 0. 1 cm x 0.2 cm, and masks with different depth (0.12 cm and 0.24 cm) were evaluated separately. For those with holes, the material width between adjacent holes was 0.1 cm. Virtual masks with a material density of 1.38 g/cm3 without holes with two different depths were also evaluated. Results: Thermoplastic mask affected X-rays surface dose. When using a thermoplastic mask with the depth of 0.24 cm without holes, the surface dose was 74. 9% and 57.0% for those with the density of 1.38 g/cm3 and 1.12 g/cm3 respectively. When focusing on the masks with the density of 1.12 g/cm3, the surface dose was 41.2% for those with 0.12 cm depth without holes; 57.0% for those with 0. 24 cm depth without holes; 44.5% for those with 0.24 cm depth with holes size of 0.1 cm x 0.2 cm;and 54.1% for those with 0.24 cm depths with holes size of 0.1 cm x 0.1 cm.Conclusions: Using thermoplastic mask during the radiation increases patient surface dose. The severity is relative to the hole size and the depth of thermoplastic mask. The surface dose change should be considered in radiation planning to avoid severe skin reaction. (authors)

  18. Reinforcing of thermoplastic polycarbonate and polysulfone with carbon fibers: Production and characteristics of UD-compound objects

    Science.gov (United States)

    Fitzer, E.; Jaeger, H.

    1988-01-01

    The production and characteristics of the carbon fiber reinforced thermoplastics polycarbonate and polysulfone are described. The production of prepregs from defined polymer solutions is emphasized along with methods of optimizing the production of compounds. The characteristics of unidirectionally reinforced thermoplastics, such as shear strength, bending strength, and impact resistance are compared with regard to fracture behavior, the influence of intermediate layers, and the behavior under cryogenic conditions and under slightly elevated temperatures. The problem of adhesion between high strength carbon fibers and thermoplastics is examined, taking into account the effect of moisture on the shear strength and the impact resistance.

  19. Turning Renewable Resources into Recyclable Polymer: Development of Lignin-Based Thermoplastic

    Energy Technology Data Exchange (ETDEWEB)

    Saito, Tomonori [ORNL; Brown, Rebecca H [ORNL; Hunt, Marcus A [ORNL; Pickel, Deanna L [ORNL; Pickel, Joseph M [ORNL; Messman, Jamie M [ORNL; Baker, Frederick S [ORNL; Keller, Martin [ORNL; Naskar, Amit K [ORNL

    2012-01-01

    Productive uses of lignin, the third most abundant natural polymer, have been sought for decades. One especially attractive possibility is that of developing value-added products including thermoplastics based on lignin. This possibility warrants special attention due to growth of the modern biofuel industries. However, the polydisperse molecular weight and hyper-branched structure of lignin has hindered the creation of high-performance biopolymers. Here, we report the preparation and characterization of novel lignin-based, partially carbon-neutral thermoplastics. We first altered the molecular weight of lignin, either by fractionation with methanol, or by formaldehyde crosslinking. A crosslinking of lignin increases the molecular weight, exhibiting Mn = 31000 g/mol, whereas that of native lignin is 1840 g/mol. Tuning the molecular weight of lignin enabled successful preparation of novel lignin-derived thermoplastics, when coupled with telechelic polybutadiene soft-segments at proper feed ratios. Characteristic to thermoplastic rubbers, free-standing films of the resulting copolymers exhibit two-phase morphology and associated relaxations in the dynamic mechanical loss spectrum. To our knowledge this article is the first report to demonstrate phase immiscibility, melt-processibility, and biphasic morphology of soft and hard segments in a lignin-based copolymer for all feed ratios of two macromolecular components. The use of higher molecular weight lignin enhanced the resulting shear modulus due to efficient network formation of telechelic polybutadiene bridges. The storage modulus in the rubbery plateau region increased with increasing lignin content. The successful synthesis of novel lignin-based thermoplastics will open a new pathway to biomass utilization and will help conserve petrochemicals.

  20. Review of potential processing techniques for the encapsulation of wastes in thermoplastic polymers

    International Nuclear Information System (INIS)

    Thermoplastic encapsulation has been extensively studied at Brookhaven National Laboratory's (BNL) Environmental and Waste Technology Center (EWTC) as a waste encapsulation technology applicable to a wide range of waste types including radioactive, hazardous and mixed wastes. Encapsulation involves processing thermoplastic and waste materials into a waste form product by heating and mixing both materials into a homogeneous molten mixture. Cooling of the melt results in a solid monolithic waste form in which contaminants have been completely surrounded by a polymer matrix. Heating and mixing requirements for successful waste encapsulation can be met using proven technologies available in various types of commercial equipment. Processing techniques for thermoplastic materials, such as low density polyethylene (LDPE), are well established within the plastics industry. The majority of commercial polymer processing is accomplished using extruders, mixers or a combination of these technologies. Extruders and mixers are available in a broad range of designs and are used during the manufacture of consumer and commercial products as well as for compounding applications. Compounding which refers to mixing additives such as stabilizers and/or colorants with polymers, is analogous to thermoplastic encapsulation. Several processing technologies were investigated for their potential application in encapsulating residual sorbent waste in selected thermoplastic polymers, including single-screw extruders, twin-screw extruders, continuous mixers, batch mixers as well as other less conventional devices. Each was evaluated based on operational ease, quality control, waste handling capabilities as well as degree of waste pretreatment required. Based on literature review, this report provides a description of polymer processing technologies, a discussion of the merits and limitations of each and an evaluation of their applicability to the encapsulation of sorbent wastes

  1. Generating Autoclave-Level Mechanical Properties with Out-of-Autoclave Thermoplastic Placement of Large Composite Aerospace Structures Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Out-of-autoclave thermoplastic tape/tow placement (TP-ATP) is nearing commercialization but suffers a moderate gap in mechanical properties compared with laminates...

  2. Thermoplastic Polymer Nanocomposites Based on Inorganic Fullerene-like Nanoparticles and Inorganic Nanotubes

    Directory of Open Access Journals (Sweden)

    Mohammed Naffakh

    2014-06-01

    Full Text Available Using inorganic fullerene-like (IF nanoparticles and inorganic nanotubes (INT in organic-inorganic hybrid composite, materials provide the potential for improving thermal, mechanical, and tribological properties of conventional composites. The processing of such high-performance hybrid thermoplastic polymer nanocomposites is achieved via melt-blending without the aid of any modifier or compatibilizing agent. The incorporation of small quantities (0.1–4 wt.% of IF/INTs (tungsten disulfide, IF-WS2 or molybdenum disulfide, MoS2 generates notable performance enhancements through reinforcement effects and excellent lubricating ability in comparison with promising carbon nanotubes or other inorganic nanoscale fillers. It was shown that these IF/INT nanocomposites can provide an effective balance between performance, cost effectiveness, and processability, which is of significant importance for extending the practical applications of diverse hierarchical thermoplastic-based composites.

  3. Coefficient of Friction Measurements for Thermoplastics and Fibre Composites Under Low Sliding Velocity and High Pressure

    DEFF Research Database (Denmark)

    Poulios, Konstantinos; Svendsen, Gustav Winther

    2013-01-01

    Friction materials for typical brake applications are normally designed considering thermal stability as the major performance criterion. There are, however, brake applications with very limited sliding velocities, where the generated heat is insignificant. In such cases it is possible that friction materials which are untypical for brake applications, like thermoplastics and fibre composites, can offer superior performance in terms of braking torque, wear resistance and cost than typical brake linings. In this paper coefficient of friction measurements for various thermoplastic and fibre composite materials running against a steel surface are presented. All tests were carried out on a pinon-disc test-rig in reciprocating operation at a fixed sliding speed and various pressure levels for both dry and grease lubricated conditions. Moreover, a generic theoretical framework is introduced in order to interpret the changes of friction observed during the running-in phase.

  4. Evolution of umbilicals in Brazil: optimizing deepwater umbilical applications with thermoplastic hoses and steel tubes

    Energy Technology Data Exchange (ETDEWEB)

    Guerra Neto, Mauro Del [DuPont do Brasil S.A., Barueri, SP (Brazil)

    2008-07-01

    Subsea umbilicals in the past 25 years have evolved in parallel with other subsea oil and gas technologies, as the search for hydrocarbons needed to drive the global economy has led offshore exploration and development companies to seek reserves ever-farther from shore in water thousands of meters deep. Relegated to little more than afterthought status before the push into deep water, modern umbilicals have now become crucial components linking deep water producers to their subsea wells, controlling subsea production systems through hydraulic and electrical power and injecting production chemicals for corrosion-, scale-, and hydrate-inhibition at subsea well heads. Particularly in subsea developments involving several deep water wells, umbilicals today are integral to both the production-system design and the chosen operating strategy. Failure of an umbilical linking a subsea well head in deep water to a host production facility can inflict severe economic consequences upon an operator by impairing production operations or halting production altogether. The additional cost of repairing or replacing a failed umbilical can run into the millions of dollars. As offshore oil and gas production has moved into ever-deeper water, umbilical manufacturers have begun introducing new stronger materials to handle the inherently higher pressures and temperatures. Today, two types of construction are used for fluid conduits in umbilical systems deployed in deep water: thermoplastic hoses and steel tubes. Steel tubes are generally more expensive than thermoplastic hoses, relatively stiff and considered to have high tensile strength, while thermoplastic hoses are extremely flexible and exhibit lower tensile strength. This lower tensile strength of the hoses may be compensated by including steel wire armoring in the umbilical. This also provides the added benefits of additional mechanical protection compared with the equivalent unarmored steel-tubes umbilicals. When either thermoplastic-hoses or steel-tubes umbilicals will handle expected operating pressures and temperatures and neither option offers a clear-cut economic advantage, other umbilical performance characteristics or logistical factors take on greater importance. As with many other types of oil field technology, some deep water operators have developed considerable expertise working with one umbilical technology or the other and, thus, tend to prefer either thermoplastic-hose or steel tube-based umbilical systems. For example, Shell and Chevron have chosen to use steel tubes umbilicals. Meanwhile, PETROBRAS has successfully deployed thermoplastic-hoses umbilicals for subsea wells in as much as 2200 meters of water depth for the past 25 years. In addition to advances in subsea umbilical technology achieved by umbilical manufacturers, deep water oil and gas producers have strived to better understand the forces acting upon umbilicals deployed in deep water and have developed and are continuing to develop application strategies for overcoming limitations of thermoplastic-hose umbilicals in extremely deep water. Offshore oil and gas development is moving into unprecedented water depths and deep water producers are beginning to target geologic formations 7,500 m or more beneath the surface. The more challenging high-pressure, high-temperature (HP-HT) environments encountered on the world's deep water and ultra-deep water frontiers have resulted in increasing use of steel-tube umbilicals. This phenomenon has special implications for deep water oil and gas development offshore Brazil, where thermoplastic-hose umbilicals have been used almost exclusively until the past few years. (author)

  5. Coefficient of Friction Measurements for Thermoplastics and Fiber Composites under Low Sliding Velocity and High Pressure

    DEFF Research Database (Denmark)

    Poulios, Konstantinos; Svendsen, G.

    2012-01-01

    Friction materials for typical brake applications are normally designed considering thermal stability as the major performance criterion. There are however brake applications with very limited sliding velocities, where the generated heat is insignificant. In such cases it is possible that friction materials which are untypical for brake applications, like thermoplastics and fiber composites, can offer superior performance in terms of braking torque, wear resistance and cost than typical brake linings. In this paper coefficient of friction measurements for various thermoplastic and fiber composite materials running against a steel surface are presented. All tests were carried out on a pin-on-disc test-rig at a fixed sliding speed and various pressure levels for both dry and grease lubricated conditions.

  6. Compilation of radiation damage test data. Pt. 2. Thermoset and thermoplastic resins, composite materials

    International Nuclear Information System (INIS)

    This catalogue summarizes radiation damage test data on thermoplastic and thermoset resins and composites. Most of them are epoxy resins used as insulator for magnet coils. Many results are also given for new engineering thermoplastics which can be used either for their electrical properties or for their mechanical properties. The materials have been irradiated either in a 60Co source, up to integrated absorbed doses between 200 kGy and a few megagrays, at dose rates of the order of 1 Gy/s, or in a nuclear reactor at dose rates of the order of 50 Gy/s, up to doses of 100 MGy. The flexural strength, the deformation and the modulus of elasticity have been measured on irradiated and non-irradiated samples, according to the recommendations of the International Electrotechnical Commissions. The results are presented in the form of tables and graphs to show the effect of the absorbed dose on the measured properties. (orig.)

  7. Reinforcing of thermoplastics with recycled CRP; Verstaerken von Thermoplasten mit CFK-Recyclat

    Energy Technology Data Exchange (ETDEWEB)

    Schiebisch, J.; Ehrenstein, G.W.

    1994-12-31

    It is a well-known fact that thermoplastics reinforced with short carbon fibres - CRP - exhibit excellent mechanical properties and good electrical conductivity. Using the example of polyamide 6 which was compounded with specially prepared recycled CRP, the authors show that the material obtained has similar properties. This opens up new fields of application for the recycling of monograde CRP waste. (orig.) [Deutsch] Bekanntlich weisen Thermoplaste, die mit kurzen Kohlenstoffasern verstaerkt sind, ausgezeichnete mechanische Eigenschaften sowie eine gute elektrische Leitfaehigkeit auf. Am Beispiel von Polyamid 6, das mit speziell aufbereitetem CFK-Recyclat aus einem Hochleistungsverbundwerkstoff mit ausgehaerteter EP-Harz-Matrix compoundiert wurde, zeigen die Autoren, dass das so gewonnene Material aehnliche Eigenschaften hat. Damit eroeffnen sich fuer die Verwertung von sortenreinen CFG-Abfaellen neue Anwendungsfelder. (orig.)

  8. Evaluation of the thermoplasticity of different gutta-percha cones and the TC system

    Scientific Electronic Library Online (English)

    Mário, Tanomaru-Filho; Carlos Alexandre Souza, Bier; Juliane Maria Guerreiro, Tanomaru; Danilo Barbosa, Barros.

    2007-04-01

    Full Text Available OBJECTIVE: The aim of this study was to evaluate the thermoplasticity of three commercial brands of gutta-percha (Tanari, Dentsply 0.06, and Roeko), and of the TC system. MATERIALS AND METHODS: Standardized specimens were fabricated from the materials to be evaluated. Specimens were placed in water [...] at 70ºC for 60 seconds. Following that, they were positioned between two glass slabs and each set was compressed by a 5kg weight. Images of the specimens before and after compression were digitized and analyzed by the Image Tool software. The flow capacity of each material was confirmed by the difference between the initial and final areas of each sample. RESULTS: The resulting data were analyzed by ANOVA. The TC system presented the greatest thermoplasticity values (p

  9. Issues related to processability during the manufacture of thermoplastic composites using on-line consolidation techniques

    Science.gov (United States)

    Ghasemi Nejhad, M. N.

    1993-04-01

    The on-line consolidation of thermoplastic composites is a relatively new technology that can be used to manufacture composite parts with complex geometries. The localized melting/solidification technique employed in this process can reduce the residual stresses and allow for improved dimensional stability and performance. An additional advantage of this technique is the elimination of the curing steps which are necessary in the processing of thermoset-matrix composites. This article presents the effects of processing parameters on processability in on-line consolidation of thermoplastic composites for tape-laying and filament-winding processes employing anisotropic thermal analyses. The results show that the heater size, preheating conditions, and tow thickness can significantly affect the processing window which, in turn, affects the production rate and the quality of the parts.

  10. Active bilayer films of thermoplastic starch and polycaprolactone obtained by compression molding.

    Science.gov (United States)

    Ortega-Toro, Rodrigo; Morey, Iris; Talens, Pau; Chiralt, Amparo

    2015-08-20

    Bilayer films consisting of one layer of PCL with either one of thermoplastic starch (S) or one of thermoplastic starch with 5% PCL (S95) were obtained by compression molding. Before compression, aqueous solutions of ascorbic acid or potassium sorbate were sprayed onto the S or S95 layers in order to plasticize them and favor layer adhesion. S95 films formed bilayers with PCL with very good adhesion and good mechanical performance, especially when potassium sorbate was added at the interface. All bilayers enhanced their barrier properties to water vapour (up to 96% compared to net starch films) and oxygen (up to 99% compared to PCL pure). Bilayers consisting of PCL and starch containing 5% PCL, with potassium sorbate at the interface, showed the best mechanical and barrier properties and interfacial adhesion while having active properties, associated with the antimicrobial action of potassium sorbate. PMID:25965485

  11. Development of ACP reinforced thermoplastic composites as an alternative to open mold processing

    Science.gov (United States)

    O'Neill, Michael A.

    1992-01-01

    Thermoplastic/foam/glass composite technology provides a method of producing large structural parts without styrene or volatile organic compounds (VOCs). High-quality parts can be molded at a low cost by combining vacuum forming technology with a low-pressure urethane reinforcement technique. This process eliminates atomization of paint or gelcoats, styrene emissions from FRP, and associated solvents and chemicals required in the normal processing of fiberglass. Secondary operations also can be streamlined by parts consolidation in the reinforcement process.

  12. Structural, thermal and surface characterization of thermoplastic polyurethanes based on poly(dimethylsiloxane)

    OpenAIRE

    Pergal Marija V.; Stefanovi? Ivan S.; Go?evac Dejan; Anti? Vesna V.; Mila?i? Vesna; Ostoji? Sanja; Rogan Jelena; ?onlagi? Jasna

    2014-01-01

    In this study, the synthesis, structure and physical properties of two series of thermoplastic polyurethanes based on hydroxypropyl terminated poly(dimethylsiloxane) (HP-PDMS) or hydroxyethoxy propyl terminated poly(dimethylsiloxane) (EO-PDMS) as a soft segment, and 4,4’-methylenediphenyl diisocyanate and 1,4-butanediol as a hard segment were investigated. Each series is composed of samples prepared with a different soft segment. The polyurethanes were synt...

  13. Introduction of a new pair of thermoplastic materials for precision manufacturing of moulded interconnect devices

    DEFF Research Database (Denmark)

    Islam, Mohammad Aminul; Hansen, Hans Nørgaard; Tang, Peter Torben

    2008-01-01

    One of the main process chains for manufacturing of MIDs is two component injection moulding, in which the two different thermoplastic materials involved should meet the requirements for selective metallization along with the requirements imposed from process and service conditions. It is a real challenge to find a suitable pair of polymers that meet so many diversified requirements at a time. This paper presents a new pair of commercial polymer materials (ULTEM PEI1000-Noryl GTX810) that fulfil...

  14. Preparation of aqueous dispersion of thermoplastic sizing agent for carbon fiber by emulsion/solvent evaporation

    OpenAIRE

    Giraud, Isabelle; Franceschi-Messant, Sophie; Perez, Emile; Lacabanne, Colette; Dantras, Eric

    2013-01-01

    In this work, different sizing agent aqueous dispersions based on polyetherimide (PEI) were elaborated in order to improve the interface between carbon fibers and a thermoplastic matrix (PEEK). The dispersions were obtained by the emulsion/solvent evaporation technique. To optimize the stability and the film formation on the fibers, two surfactants were tested at different concentrations, with different concentrations of PEI. The dispersions obtained were characterized by dynamic light scatte...

  15. Compression properties of novel thermoplastic carbon fibre and poly-ethylene terephthalate fibre composite lattice structures

    OpenAIRE

    Schneider, Christof; Velea, Marian Nicolae; Kazemahvazi, S.; Zenkert, Dan

    2015-01-01

    A novel manufacturing route to efficiently produce fibre composite lattice structures has been developed. By using thermoplastic composite materials, flat sheets have been continuously folded, cut into a lattice shape and joined into a sandwich structure. Carbon fibre reinforced poly-ethylene terephthalate (CPET) and poly-ethylene terephthalate fibre reinforced poly-ethylene terephthalate (SrPET) materials have been used to explore two different core options; a carbon fibre option which gives...

  16. Hybrid joining technology - A new method for joining thermoplastic-metal-mixed components

    Science.gov (United States)

    Friedrich, S.; Georgi, W.; Gehde, M.; Mayer, P.

    2014-05-01

    This article deals with the clinching and hot-melt adhesive bonding of thermoplastic-metal mixed joints. Specimens made of the PA6-GF15 plastic and the DC04 steel were joined not only with the single methods but also in the combination of methods. Their mechanical properties were investigated afterwards by means of peel and tensile shear tests. It is demonstrated that a suitable combination of both joining methods can achieve an increase in strength compared to the single methods.

  17. Thermal, mechanical and morphological behavior of starch thermoplastic (TPS) and polycaprolactone (PCL)

    International Nuclear Information System (INIS)

    Thermal, mechanical and morphological properties of thermoplastic starch (TPS) and polycaprolactone (PCL) blend obtained by extrusion was studied. The results showed that TPS/PCL blends are immiscible, however it is suggested some interaction in the interphase between TPS and PCL as observed by crystallinity decrease of the blend. The PCL addition in the TPS improves the properties and decreases the cost of the blend. (author)

  18. Behaviour of thermoplastic polymers during explosive decompressions in a petroleum environment

    OpenAIRE

    Dewimille, B.; MARTIN, J; Jarrin, J.

    1993-01-01

    Thermoplastic polymers are used in the field of petroleum where they may encounter very severe conditions. So we are induced to study the ageing behaviour and the effect of rapid decompressions in a gaseous environment. In the latter case our aim is to define the limits of use and to identify the parameters influencing degradations. Such damaging is essentially of two types : (1) local in the form of blisters and (2) under extreme conditions, more homogeneous microscopic damage of the "foamin...

  19. Initiation of shape-memory effect by inductive heating of magnetic nanoparticles in thermoplastic polymers

    OpenAIRE

    Mohr, R; K. Kratz; Weigel, T.; Lucka-Gabor, M.; Moneke, M.; Lendlein, A

    2006-01-01

    In shape-memory polymers, changes in shape are mostly induced by heating, and exceeding a specific switching temperature, Tswitch. If polymers cannot be warmed up by heat transfer using a hot liquid or gaseous medium, noncontact triggering will be required. In this article, the magnetically induced shape-memory effect of composites from magnetic nanoparticles and thermoplastic shape-memory polymers is introduced. A polyetherurethane (TFX) and a biodegradable multiblock copolymer (PDC) with po...

  20. Damage detection in laminar thermoplastic composite materials by means of embedded optical fibers

    OpenAIRE

    Kojovi? Aleksandar M.; Živkovi? Irena D.; Brajovi? Ljiljana M.; Mitrakovi? Dragan; Aleksi? Radoslav R.

    2006-01-01

    This paper investigates the possibility of applying optical fibers as sensors for investigating low energy impact damage in laminar thermoplastic composite materials, in real time. Impact toughness testing by a Charpy impact pendulum with different loads was conducted in order to determine the method for comparative measurement of the resulting damage in the material. For that purpose intensity-based optical fibers were built in to specimens of composite materials with Kevlar 129 (the DuPont ...

  1. Coefficient of Friction Measurements for Thermoplastics and Fibre Composites Under Low Sliding Velocity and High Pressure

    DEFF Research Database (Denmark)

    Poulios, Konstantinos; Svendsen, Gustav Winther; Hiller, Jochen; Klit, Peder

    2013-01-01

    Friction materials for typical brake applications are normally designed considering thermal stability as the major performance criterion. There are, however, brake applications with very limited sliding velocities, where the generated heat is insignificant. In such cases it is possible that friction materials which are untypical for brake applications, like thermoplastics and fibre composites, can offer superior performance in terms of braking torque, wear resistance and cost than typical brake ...

  2. Coefficient of Friction Measurements for Thermoplastics and Fiber Composites under Low Sliding Velocity and High Pressure

    DEFF Research Database (Denmark)

    Poulios, Konstantinos; Svendsen, G.; Hiller, Jochen; Klit, Peder

    2012-01-01

    Friction materials for typical brake applications are normally designed considering thermal stability as the major performance criterion. There are however brake applications with very limited sliding velocities, where the generated heat is insignificant. In such cases it is possible that friction materials which are untypical for brake applications, like thermoplastics and fiber composites, can offer superior performance in terms of braking torque, wear resistance and cost than typical brake li...

  3. Local viscoelastic properties of a thermoplastic/carbon laminate as an indicator of fatigue damage.

    Czech Academy of Sciences Publication Activity Database

    Minster, Ji?í; Šperl, Martin; Lukeš, J.

    Vol. 606. Durnten-Zurich : Trans Tech Publications, 2014 - (Haušild, P.), s. 237-240 ISBN 978-3-03835-062-0. ISSN 1013-9826. [Local Mechanical Properties /10./. Kutná Hora (CZ), 06.11.2013-08.11.2013] R&D Projects: GA TA ?R(CZ) TA03010209 Institutional support: RVO:68378297 Keywords : thermoplastic laminate * fatigue * damage accumulation * microindentation Subject RIV: JI - Composite Materials http://www.scientific.net/KEM.606.237

  4. Investigation of a thermoplastic-powder metallurgy process for the fabrication of porous niobium rods

    International Nuclear Information System (INIS)

    The feasibility of using a thermoplastic-powder metallurgy technique for the fabrication of porous niobium rods was investigated. Some early problems were overcome to successfully extrude the polymer coated niobium powder into long lengths. The effects of certain process variables were investigated. Residual porosity and extrusion pressure were found to be regulated by the polymer fraction. The procedures for taking the extruded polystyrene--niobium rods through the heat treatments to the final, tin infiltrated stage are explained

  5. An investigation on the strain distribution of resistance welded thermoplastic composite joints:

    OpenAIRE

    Shi, H.; Fernandez-Villegas, I.; Bersee, H.E.N.

    2012-01-01

    In order to better understand the usefulness of single lap shear testing for the characterization of resistance welded thermoplastic composite joints, finite element method (FEM) and digital image correlation measurements (DIC) were combined to investigate the strain distributions of the joints during testing. Glass fibre reinforced Polyphenylene Sulfide (GF/PPS) was resistance welded in aid of a metal mesh. Shear and peel strain distributions were investigated at the joint overlap area. The ...

  6. Micro injection moulding process validation for high precision manufacture of thermoplastic elastomer micro suspension rings

    DEFF Research Database (Denmark)

    Calaon, M.; Tosello, G.; Elsborg Hansen, R.; Hansen, H. N.

    2015-01-01

    Micro injection moulding (?IM) is one of the most suitable micro manufacturing processes for flexible mass-production of multi-material functional micro components. The technology was employed in this research used to produce thermoplastic elastomer (TPE) micro suspension rings identified as critical component in micro acoustic applications (e.g. phono cartridges, see Figure 1a). The suspension ring holds in place the preassembled aluminium cantilever, magnet and diamond tip seen (see Figure 1b ...

  7. Recycling of Ground Tyre Rubber and Polyolefin Wastes by Producing Thermoplastic Elastomers

    OpenAIRE

    Lievana, Emiliano Julian

    2005-01-01

    This thesis deals with the development of thermoplastic polyolefin elastomers using recycled polyolefins and ground tyre rubber (GTR). The disposal of worn tyres and their economic recycling mean a great challenge nowadays. Material recycling is a preferred way in Europa owing to legislative actions and ecological arguments. This first step with worn tyres is already done in this direc-tion as GTR is available in different fractions in guaranteed quality. As the traditional applications of GT...

  8. Rheology/Morphology Relationship of Immiscible EPDM/PP Based Thermoplastic Elastomer Blends

    Science.gov (United States)

    Shahbikian, S.; Carreau, P. J.; Heuzey, M. C.; Ellul, M. D.; Nadella, H. P.; Cheng, J.; Shirodkar, P.

    2008-07-01

    The rheological and morphological properties of non-plasticized/plasticized EPDM/PP based thermoplastic elastomers (TPEs) have been investigated. The addition of a plasticizer reduced the rheological properties of both components and their blends and increased their deformability. Complex morphological features (e.g., specific interfacial area and its orientation) of these blends have been analyzed after multiple start-up experiments using atomic force microscopy.

  9. Investigation of Mechanical Properties of Thermoplastics with Implementations of LS-DYNA Material Models.

    OpenAIRE

    Appelsved, Peter

    2012-01-01

    The increased use of thermoplastics in load carrying components, especially in the automotive industry, drives the needs for a better understanding of its complex mechanical properties. In this thesis work for a master degree in solid mechanics, the mechanical properties of a PA 6/66 resin with and without reinforcement of glass fibers experimentally been investigated. Topics of interest have been the dependency of fiber orientation, residual strains at unloading and compression relative tens...

  10. Hemocompatibility of Inorganic Physical Vapor Deposition (PVD) Coatings on Thermoplastic Polyurethane Polymers

    OpenAIRE

    Daniel Heim; Martin Wiesinger; Marek Sanak; Roman Major; Marianne Weidenhaupt; Franz Bruckert; Paul Hartmann; Wolfgang Waldhauser; Lackner, Juergen M.

    2012-01-01

    Biocompatibility improvements for blood contacting materials are of increasing interest for implanted devices and interventional tools. The current study focuses on inorganic (titanium, titanium nitride, titanium oxide) as well as diamond-like carbon (DLC) coating materials on polymer surfaces (thermoplastic polyurethane), deposited by magnetron sputtering und pulsed laser deposition at room temperature. DLC was used pure (a-C:H) as well as doped with silicon, titanium, and nitrogen + titaniu...

  11. Green composites of thermoplastic corn starch and recycled paper cellulose fibers

    Directory of Open Access Journals (Sweden)

    Amnuay Wattanakornsiri

    2011-08-01

    Full Text Available Ecological concerns have resulted in a renewed interest in environmental-friendly composites issues for sustainabledevelopment as a biodegradable renewable resource. In this work we used cellulose fibers from recycled newspaper as reinforcementfor thermoplastic starch in order to improve its mechanical, thermal and water resistance properties. The compositeswere prepared from corn starch plasticized by glycerol (30% wt/wt of glycerol to starch as matrix that was reinforcedwith micro-cellulose fibers, obtained from used newspaper, with fiber content ranging from 0 to 8% (wt/wt of fibers to matrix.Physical properties of composites were determined by mechanical tensile tests, differential scanning calorimetry, thermogravimetricanalysis, water absorption measurement and scanning electron microscopy. The results showed that higherfibers content raised the tensile strength and elastic modulus up to 175% and 292%, respectively, when compared to thenon-reinforced thermoplastic starch. The addition of the fibers improved the thermal resistance and decreased the waterabsorption up to 63%. Besides, scanning electron microscopy illustrated a good adhesion between matrix and fibers. Theseresults indicated that thermoplastic starch reinforced with recycled newspaper cellulose fibers could be fruitfully used ascommodity plastics being strong, cheap, abundant and recyclable.

  12. Biopolymer-based thermoplastic mixture for producing solid biodegradable shaped bodies and its photo degradation stability

    Science.gov (United States)

    Sulong, Nurulsaidatulsyida; Rus, Anika Zafiah M.

    2013-12-01

    In recent years, biopolymers with controllable lifetimes have become increasingly important for many applications in the areas of agriculture, biomedical implants and drug release, forestry, wild life conservation and waste management. Natural oils are considered to be the most important class of renewable sources. They can be obtained from naturally occurring plants, such as sunflower, cotton, linseed and palm oil. In Malaysia, palm oil is an inexpensive and commodity material. Biopolymer produced from palm oil (Bio-VOP) is a naturally occurring biodegradable polymer and readily available from agriculture. For packaging use however, Bio-VOP is not thermoplastic and its granular form is unsuitable for most uses in the plastics industry, mainly due to processing difficulties during extrusion or injection moulding. Thus, research workers have developed several methods to blend Bio-VOP appropriately for industrial uses. In particular, injections moulding processes, graft copolymerisation, and preparation of blends with thermoplastic polymers have been studied to produce solid biodegradable shaped bodies. HDPE was chosen as commercial thermoplastic materials and was added with 10% Bio-VOP for the preparation of solid biodegradable shaped bodies named as HD-VOP. The UV light exposure of HD-VOP at 12 minutes upon gives the highest strength of this material that is 17.6 MPa. The morphological structure of HD-VOP shows dwi structure surface fracture which is brittle and ductile properties.

  13. Mechanical behaviour of textile-reinforced thermoplastics with integrated sensor network components

    International Nuclear Information System (INIS)

    Highlights: ? Consideration of two types of integrated bus systems for textile-reinforced thermoplastics with embedded sensor networks. ? Specimens with bus systems made of flexible printed circuit boards show good mechanical performance compared to the reference. ? Inhomogeneous interface and reduced stiffnesses and strengths for specimens with bus systems basing on single copper wires. -- Abstract: The embedding of sensor networks into textile-reinforced thermoplastics enables the design of function-integrative lightweight components suitable for high volume production. In order to investigate the mechanical behaviour of such functionalised composites, two types of bus systems are selected as exemplary components of sensor networks. These elements are embedded into glass fibre-reinforced polypropylene (GF/PP) during the layup process of unconsolidated weft-knitted GF/PP-preforms. Two fibre orientations are considered and orthotropic composite plates are manufactured by hot pressing technology. Micrograph investigations and computer tomography analyses show different interface qualities between the thermoplastic composite and the two types of bus systems. Mechanical tests under tensile and flexural loading indicate a significant influence of the embedded bus system elements on the structural stiffness and strength.

  14. EFFECT OF FIBER LOADING ON PROPERTIES OF THERMOPLASTIC SAGO STARCH/KENAF CORE FIBER BIOCOMPOSITES

    Directory of Open Access Journals (Sweden)

    Norshahida Sarifuddin,

    2012-07-01

    Full Text Available Growing attention has been paid to the innovation of ecological products, prompted by rising environmental concerns. As a natural polymer, thermoplastic sago starch has been regarded as an alternative material to petroleum-based plastic owing to its availability, cost, and biodegradability. In order to produce thermoplastic starch materials with enhanced structural and functional stability during use, kenaf fibers were incorporated as the reinforcing filler. In this work, thermoplastic sago starch (TPSS/kenaf core fiber (KF biocomposites were prepared at different fiber loadings (0 to 35 wt.%, and the effects of fiber loading were analyzed by mechanical tests, TGA, FTIR, SEM, and water absorption behavior. The tensile analysis showed a linear increase in strength and modulus upon increasing fiber content until it reached an optimum at 30 wt.% fiber loading. The thermal stability of biocomposites was improved slightly by the incorporation of kenaf fibers into TPSS matrices. FTIR results indicated a change in the functional group of the biocomposites. Moreover, the interfacial adhesion properties of biocomposites were evident from morphological studies of tensile fracture surfaces. It is interesting to note that water absorbed by the biocomposites was reduced by the addition of fiber, and it seems that the hydrophilic character was decreased especially for the glycerol-plasticized sample. The results obtained clearly illustrate the potential use of these fiber and biopolymers to establish their suitability as alternative biocomposite materials.

  15. Nanocomposites Based on Thermoplastic Polymers and Functional Nanofiller for Sensor Applications

    Directory of Open Access Journals (Sweden)

    Serena Coiai

    2015-06-01

    Full Text Available Thermoplastic polymers like polyolefins, polyesters, polyamide, and styrene polymers are the most representative commodity plastics thanks to their cost-efficient manufacturing processes, excellent thermomechanical properties and their good environmental compatibility, including easy recycling. In the last few decades much effort has been devoted worldwide to extend the applications of such materials by conferring on them new properties through mixing and blending with different additives. In this latter context, nanocomposites have recently offered new exciting possibilities. This review discusses the successful use of nanostructured dispersed substrates in designing new stimuli-responsive nanocomposites; in particular, it provides an updated description of the synthetic routes to prepare nanostructured systems having the typical properties of thermoplastic polymers (continuous matrix, but showing enhanced optical, conductive, and thermal features dependent on the dispersion topology. The controlled nanodispersion of functional labeled clays, noble metal nanoparticles and carbon nanotubes is here evidenced to play a key role in producing hybrid thermoplastic materials that have been used in the design of devices, such as NLO devices, chemiresistors, temperature and deformation sensors.

  16. Multiple-objective optimization in precision laser cutting of different thermoplastics

    Science.gov (United States)

    Tamrin, K. F.; Nukman, Y.; Choudhury, I. A.; Shirley, S.

    2015-04-01

    Thermoplastics are increasingly being used in biomedical, automotive and electronics industries due to their excellent physical and chemical properties. Due to the localized and non-contact process, use of lasers for cutting could result in precise cut with small heat-affected zone (HAZ). Precision laser cutting involving various materials is important in high-volume manufacturing processes to minimize operational cost, error reduction and improve product quality. This study uses grey relational analysis to determine a single optimized set of cutting parameters for three different thermoplastics. The set of the optimized processing parameters is determined based on the highest relational grade and was found at low laser power (200 W), high cutting speed (0.4 m/min) and low compressed air pressure (2.5 bar). The result matches with the objective set in the present study. Analysis of variance (ANOVA) is then carried out to ascertain the relative influence of process parameters on the cutting characteristics. It was found that the laser power has dominant effect on HAZ for all thermoplastics.

  17. LFI-PUR {sup trademark} machinery and equipment technology; LFI-PUR {sup trademark} Maschinen- und Anlagentechnik

    Energy Technology Data Exchange (ETDEWEB)

    Soechtig, W. [Krauss-Maffei Kunststofftechnik GmbH, Muenchen (Germany). Produktbereich Polyurethan-Technik

    2000-07-01

    Large glass fiber-reinforced PUR parts are manufactured by means of long fiber injection molding (LIF-PUR). The machinery and the processing steps are presented and evaluated: mixing head; glass chopper; lay of the roving; purging the mixing head; metering unit; process control; robots; plant technologies.

  18. Transcription of Small Surface Structures in Injection Molding - an Experimental Study

    DEFF Research Database (Denmark)

    Arlø, Uffe Rolf; Kjær, Erik Michael

    2001-01-01

    The ability to replicate the surface roughness from mold wall to the plastic part in injection moldning has many functional and cosmetic important implications from medical use to designer products. Generally the understanding of surface transcription i.e the the replication of the surface structure from the mould to plastic part, also relates to micro injection moulding and moulding of parts with specific micro structures on the surface such as optical parts. The present study concerns transcri...

  19. The Elastic Mold Deformation During the Filling and Packing Stage of the Injection Molding Process

    OpenAIRE

    Stefan Kleindel; Roland Eder; Herwig Schretter; Christoph Hochenauer

    2014-01-01

    The accurate numerical prediction of the mold filling process of long and thin walled parts is dependent on numerous factors. This paper investigates the effect of various influencing variables on the filling pattern by means of simulation and experimental validation. It was found that mold temperature, process settings and venting conditions have little effect on the predicted filling pattern. However, in the actual case study, the filling behavior observed during the experiments was signifi...

  20. MELT AND THERMAL PROPERTIES OF INJECTION MOLDED MILK-PROTEIN-BASED BIOPOLYMERS

    Science.gov (United States)

    The need to reduce the use of petroleum products has focused research efforts on using agricultural materials as substitutes for petroleum based plastics. Dairy proteins, such as whey and casein, offer significant property advantages over other agricultural materials and are compatible with biosynt...