Energy Technology Data Exchange (ETDEWEB)

Experimentally it is found that at constant temperature the order-parameter relaxation time, tausub(..delta..), decreases with increasing power of the microwaves, coupled into a superconducting strip. If the same increase in critical current, that corresponds with a given power of the microwaves, is obtained by lowering the temperature, the decrease in tausub(..delta..) is smaller. This reflects the fact that quasiparticles are removed more efficiently from the gap edge by microwaves than by lowering the temperature in equilibrium. A modified time-dependent Ginzburg-Landau equation is shown to describe these results adequately.

International Nuclear Information System (INIS)

... aromatics barium dienes heat exchangers ion exchange ions kinetic equations

International Nuclear Information System (INIS)

Non-anisotropic free energy is considered which under minimization yields two magnetic phases: a conical spin density wave and a low temperature conical cycloid. Using equations of motion, the excitation spectrum is studied. Knowing the nature of these excitations, the dielectric function as well as the fluctuation specific heat is computed and compared with the experimental spectrum. Due to the electromagnon going soft, the dielectric function (imaginary part) as well as the specific heat capacity show peaks at the temperature where ferroelectricity appears in the system.

CERN Document Server

Two-dimensional simulations of the coarsening process of the isotropic/smectic-A phase transition are presented using a high-order Landau-de Gennes type free energy model. Defect annihilation laws for smectic disclinations, elementary dislocations, and total dislocation content are determined. The computed evolution of the orientational correlation length and disclination density is found to be in agreement with previous experimental observations showing that disclination interactions dominate the coarsening process. The mechanism of smectic disclination movement, limited by the absorption and emission of elementary dislocations, is found to be facilitated by curvature walls connecting interacting disclinations. At intermediate times in the coarsening process, split-core dislocation formation and interactions displaying an effective disclination quadrupole configuration are observed. This work provides the framework for further understanding of the formation and ...

Energy Technology Data Exchange (ETDEWEB)

The biosorption of Cu(II) from aqueous solutions by valonia tannin resin was investigated as a function of particle size, initial pH, contact time and initial metal ion concentration. The aim of this study was to understand the mechanisms that govern copper removal and find a suitable equilibrium isotherm and kinetic model for the copper removal in a batch reactor. The experimental isotherm data were analysed using the Langmuir, Freundlich and Temkin equations. The equilibrium data fit well in the Langmuir isotherm. The experimental data were analysed using four sorption kinetic models - the pseudo-first- and second-order equations, the Elovich and the intraparticle diffusion model equation - to determine the best fit equation for the biosorption of copper ions onto valonia tannin resin. Results show that the pseudo-second-order equation ...

CERN Document Server

n an early approach, we proposed a kinetic model with multiple translational temperature [K. Xu, H. Liu and J. Jiang, Phys. Fluids {\\bf 19}, 016101 (2007)], to simulate non-equilibrium flows. In this paper, instead of using three temperatures in $x-$, $y-$, and $z$-directions, we are going to further define the translational temperature as a second-order symmetric tensor. Based on a multiple stage BGK-type collision model and the Chapman-Enskog expansion, the corresponding macroscopic gas dynamics equations in three-dimensional space will be derived. The zeroth-order expansion gives the 10 moment closure equations of Levermore [C.D. Levermore, J. Stat. Phys {\\bf 83}, pp.1021 (1996)]. To the 1st-order expansion, the derived gas dynamic equations can be considered as a regularization of Levermore's 10 moments equations. The new gas dynamic equations have the ...

Energy Technology Data Exchange (ETDEWEB)

This book examines some of the basic principles behind chemical reactions kinetics. Topics considered include ab initio determination of potential energy for chemical reactions; semi-empirical potential energy surfaces; general theory of reactive scattering: different equation approach; and integral equation approach to reactive scattering.

Energy Technology Data Exchange (ETDEWEB)

A method of kinetic analysis applicable to non-isothermal oxidation processes of ceramic nanocomposites is presented using Ti-Si-C-N powder as the substrate. The nanoparticle size and phase composition were determined using high-resolution transmission electron microscopy and X-ray diffraction (XRD). Thermogravimetric measurements were carried out for powder samples in dry air in the temperature range 298-1770 K. The following heating rates were applied: 3, 5, 10, 20 K min{sup -1}. Mass spectrometry was used to analyze gaseous oxidation products and solid products were identified by the XRD technique. The Coats-Redfern equation was applied for the kinetic analysis. For each stage of the oxidation kinetic models, the best accuracy was achieved using a series of criteria, and then the A and E parameters of the Arrhenius equations were estimated. Both linear regression and artificial ...

CERN Document Server

In this paper, we discuss the large--time behavior of solution of a simple kinetic model of Boltzmann--Maxwell type, such that the temperature is time decreasing and/or time increasing. We show that, under the combined effects of the nonlinearity and of the time--monotonicity of the temperature, the kinetic model has non trivial quasi-stationary states with power law tails. In order to do this we consider a suitable asymptotic limit of the model yielding a Fokker-Planck equation for the distribution. The same idea is applied to investigate the large-time behavior of an elementary kinetic model of economy involving both exchanges between agents and increasing and/or decreasing of the mean wealth. In this last case, the large-time behavior of the solution shows a Pareto power law tail. Numerical results confirm the previous analysis.

Energy Technology Data Exchange (ETDEWEB)

The validity is given to the newly proposed two weighting {delta}f scheme (Wang et al., Research Report of National Institute for Fusion Science NIFS-588, 1999) for collisional or neoclassical transport calculations, which can solve the drift kinetic equation taking account of effects of steep plasma gradients, large radial electric field, finite banana width, and the non-standard orbit topology near the axis. The marker density functions in weight equations are successively solved by using the idea of {delta}f method and a hierarchy of equations for weight and marker density functions is obtained. These hierarchy equations are solved by choosing an appropriate source function for each marker density. Thus the validity of the two weighting {delta}f scheme is mathematically proved. (author)

Energy Technology Data Exchange (ETDEWEB)

Non-first order (FO) kinetics models are of three types; second order (SO), general order (GO) and mixed order (MO). It is shown that all three of these have constraints in their energy level schemes and their applicable parameter values. In nature such restrictions are not expected to exist. The thermoluminescence (TL) glow peaks produced by these models shift their position and change their shape as the trap occupancies change. Such characteristics are very unlike those found in samples of real materials. In these models, in general, retrapping predominates over recombination. It is shown that the quasi-equilibrium (QE) assumption implied in the derivation of the TL equation of these models is quite valid, thus disproving earlier workers' conclusion that QE cannot be held under retrapping dominant conditions. However notwithstanding their validity, they suffer from the shortcomings as stated above and have certain lacunae. For ...

Energy Technology Data Exchange (ETDEWEB)

The temperature and concentration dependence of the kinetics of uranium(VI) ions adsorption onto activated charcoal from aqueous solutions has been studied. The adsorption proceeds via a rather fast stage followed by a slower one, with activation energies of 5.41 and 17.46 kJ . mol[sup -1] respectively. The diffusion of uranium ions into the pores of the activated charcoal controls the kinetics of adsorption which follows the Langmuir isotherm equation in the concentration range studied. The adsorption equilibrium constant k[sub c] has been derived at temperatures between 283 K and 323 K as well as [Delta] G, [Delta] H and [Delta] S. The results indicate that the adsorption of uranium ions on activated charcoal is an endothermic process. (orig.)

Energy Technology Data Exchange (ETDEWEB)

Given the spectrum of a Hamiltonian, a methodology is developed which employs the Landau-Ginsburg theory for characterizing phase transitions in infinite systems to identify phase transition remnants in finite fermion systems. As a first application of our approach we discuss pairing in finite nuclei. (orig.)

International Nuclear Information System (INIS)

The field algebra of the minimal models of W-algebras is amenable to a very simple description as a polynomial algebra generated by a few elementary fields, corresponding to order parameters. Using this description, the complete Landau-Ginzburg lagrangians for these models are obtained. Perturbing these lagrangians we can explore their phase diagrams, which correspond to multicritical points with D_n symmetry. In particular, it is shown that there is a perturbation for which the phase structure is similar to that of the IRF models of Jimbo et al. (orig.).

Energy Technology Data Exchange (ETDEWEB)

A new method for the determination of the cmc using a dialysis technique which allows monometric species to diffuse through but no micelles has been applied for determining the mixed micelle composition. The method is based on determining the amount of surfactant that diffuses through at two different times which allows for the calculation of the cmc by use of the appropriate equation. This method requires the preparation of only one concentration of solution and lends itself particularly well to the determination of the composition of mixed micelles. (orig.)

Energy Technology Data Exchange (ETDEWEB)

The Schroedinger equation for nuclear quadruple surface vibrations is linearized with the consequence that a new spin degree of freedom appears in the wave function of the linearized equation. This spin is called collective spin and has a value of 3/2. The linearized Schroedinger equation for quadrupole vibrations is used for the description of certain collective aspects of even-odd {sup 187,189,191}Ir nuclei which have a spin 3/2 in their ground state. As a potential we use the {gamma}-soft collective potential of the neighboring even-even nuclei, which is inserted into the linearized Schroedinger equation via a scalar coupling. This leads to a collective spin-dependent fine structure splitting of the energy levels governed by a collective SO(5) spin-orbit coupling and a correction to the kinetic energy. Further, we consider explicitly spin-dependent potentials which effectively ...

CERN Document Server

We show the existence of global-in-time weak solutions to a general class of coupled FENE-type bead-spring chain models that arise from the kinetic theory of dilute solutions of polymeric liquids with noninteracting polymer chains. The class of models involves the unsteady incompressible Navier-Stokes equations in a bounded domain in two or three space dimensions for the velocity and the pressure of the fluid, with an elastic extra-stress tensor appearing on the right-hand side in the momentum equation. The extra-stress tensor stems from the random movement of the polymer chains and is defined by the Kramers expression through the associated probability density function that satisfies a Fokker-Planck-type parabolic equation, a crucial feature of which is the presence of a center-of-mass diffusion term. We require no structural assumptions on the drag term in the Fokker-Planck ...

CERN Document Server

We consider chemical reaction networks taken with mass action kinetics. The steady states of such a system are solutions to a system of polynomial equations. Even for small systems the task of finding the solutions is daunting. We develop an algebraic framework and procedure for linear elimination of variables. The procedure reduces the variables in the system to a set of "core" variables by eliminating variables corresponding to a set of non-interacting species. The steady states are parameterized algebraically by the core variables, and a graphical condition is given for when a steady state with positive core variables necessarily have all variables positive. Further, we characterize graphically the sets of eliminated variables that are constrained by a conservation law and show that this conservation law takes a specific form.

British Library Electronic Table of Contents (United Kingdom)

A numerical model is developed to study electrolyte dependent kinetics in fuel cells. The model is based on the Poisson-Nernst-Planck (PNP) and generalized-Frumkin-Butler-Volmer (gFBV) equations, and is used to understand how the diffuse layer and ionic transport play a role in the performance difference between acidic and alkaline systems. The laminar flow fuel cell (LFFC) is used as the model fuel cell architecture to allow for the appropriate comparison of equivalent acidic and alkaline systems. We study the overall cell performance and individual electrode polarizations of acidic and alkaline fuel cells for both balanced and unbalanced electrode kinetics as well as in the presence of transport limitations. The results predict cell behavior based on electrolyte composition that strongly...

Energy Technology Data Exchange (ETDEWEB)

The transformation from the as-quenched amorphous to the crystalline state in Fe/sub 78/B/sub 13/Si/sub 9/ alloy has been investigated using a new-type neutron diffractometer. The time resolved diffraction patterns clearly show that this alloy crystallizes into FeSi alloy and Fe/sub 2/B in that order. The time evolution of these crystalline phases can be analyzed by the Kolmogorov-Johnson-Mehl-Avrami equation with the exponent of about 2.5 over a wide temperature range. This suggests that the crystallization occurs by the diffusion-controlled growth with a constant nucleation rate. The scaling behavior in the crystallization kinetics is also discussed.

Energy Technology Data Exchange (ETDEWEB)

A bubble column absorber was used to investigate kinetics of the reaction between carbon dioxide and aqueous solutions of diisopropanolamine (DIPA), by means of gas absorption experiments. These were conducted in the temperature range of 10 to 40deg C, with DIPA concentrations from 5 to 500 mol/m{sup 3}, and CO{sub 2} partial pressures between 5 and 101 kPa. A model based on the Danckwerts' surface reneval theory was used to analyze the experimental results and to determine the rate constant. The obtained data support the assumption of a second-order overall reaction, with the rate constants being well correlated by the Arrhenius equation: k{sub 2} = 1.112 x 10{sup 10} exp(-4848/T). (orig.).

CERN Document Server

Versions of parameterized pseudo-Newtonian gravity theories specially designed for cosmology have been introduced in recent cosmology literature. The modifications demand a zero-pressure fluid in the context of versions of modified Poisson-like equation with two different gravitational potentials. We consider such modifications in the context of relativistic gravity theories where the action is a general algebraic function of the scalar curvature, the scalar field, and the kinetic term of the field. In general it is not possible to isolate the zero-pressure fluid component simultaneously demanding a modification in the Poisson-like equation. Only in the small-scale limit we can realize some special forms of the attempted modifications. We address some loopholes in the possibility of showing non-Einstein gravity nature based on pseudo-Newtonian modifications in the cosmological context. We point out that future observations ...

CERN Document Server

In the paper we investigate a mathematical model describing the growth of tumor in the presence of immune response of a host organism. The dynamics of tumour and immune cells is based on the generic Michaelis-Menten kinetics describing interaction and competition between the tumour and the immune system. The appropriate phenomenological equation modeling cell-mediated immune surveillance against cancer is of the predator-prey form and within a given choice of parameters exhibits bistability. Under the influence of spontaneous weak fluctuations, the model may be analyzed in terms of a stochastic differential equation bearing the form of an overdamped Langevin-like dynamics in the external quasi-potential represented by a double well. We analyze properties of the system within the range of parameters for which the potential wells are of the same depth and when the additional perturbation describing a periodic treatment is ...

Energy Technology Data Exchange (ETDEWEB)

The corrosion behavior of Alloy 800 and Type 316 stainless steel in molten NaNO/sub 3/-KNO/sub 3/ was studied at temperatures from 605/degree/C to 630/degree/C. Corrosion behavior was significantly different from that previously reported in nitrate melts at temperatures up to 600/degree/C and involved a combination of oxidation, internal nitridation and sodium metallate formation. Corrosion kinetics, determined metallographically, switched from a parabolic to a linear rate equation as temperature increased. Corrosion was uniform and resulted in metal losses on the order of 100 micronsyear at 630/degree/C. Among the alloying elements, chromium was depleted from the alloy as the result of a basic fluxing process. The kinetic equations describing chromium depletion also changed from parabolic to linear with increasing temperature. The effect of the equilibrium chemistry of the melt on the corrosion ...

CERN Document Server

We show that in the Landau gauge of the SU(2) Yang-Mills theory the residual global symmetry supports existence of the topological vortices which resemble disclination defects in the nematic liquid crystals and the Alice (half-quantum) vortices in the superfluid heluim 3 in the A-phase. The theory also possesses half-integer and integer charged monopoles which are analogous to the point-like defects in the nematic crystal and in the liquid helium. We argue that the deconfinement phase transition in the Yang-Mills theory in the Landau gauge is associated with the proliferation of these vortices and/or monopoles. The disorder caused by these defects is suggested to be responsible for the confinement of quarks in the low-temperature phase.

CERN Document Server

In situ optical absorption spectroscopy was used to study the generation of E' centres in amorphous SiO_2 occurring by photo-induced breaking of Si-H groups under 4.7eV pulsed laser radiation. The dependence from laser intensity of the defect generation rate is consistent with a two-photon mechanism for Si-H rupture, while the growth and the saturation of the defects are conditioned by their concurrent annealing due to reaction with mobile hydrogen arising from the same precursor. A rate equation is proposed to model the kinetics of the defects and tested on experimental data.

CERN Document Server

The influence of motion of ions and electron temperature on nonlinear one-dimensional plasma waves with velocity close to the speed of light in vacuum investigated. It is shown that although the wavebreaking field weakly depends on mass of ions, the nonlinear relativistic wavelength essentially changes. The nonlinearity leads to the increase of the strong plasma wavelength, while the motion of ions leads to the decrease of the wavelength. Both hydrodynamic approach and kinetic one, based on Vlasov-Poisson equations, are used to investigate the relativistic strong plasma waves in a warm plasma. The existence of relativistic solitons in a thermal plasma is predicted.

Energy Technology Data Exchange (ETDEWEB)

The validity is given to the newly proposed two {delta}f method for neoclassical transport calculation, which can be solve the drift kinetic equation considering effects of steep plasma gradients, large radial electric field, finite banana width, and an orbit topology near the axis. The new method is applied to the study of ion transport with steep plasma gradients. It is found that the ion thermal diffusivity decreases as the scale length of density gradient decreases, while the ion particle flux due to ion-ion self collisions increases with increasing gradient. (author)

Energy Technology Data Exchange (ETDEWEB)

This paper describes the development of a computational multiphase fluid dynamics (CMFD) model of the Fischer Tropsch (FT) process in a Slurry Bubble Column Reactor (SBCR). The CMFD model is fundamentally based which allows it to be applied to different industrial processes and reactor geometries. The NPHASE CMFD solver [1] is used as the robust computational platform. Results from the CMFD model include gas distribution, species concentration profiles, and local temperatures within the SBCR. This type of model can provide valuable information for process design, operations and troubleshooting of FT plants. An ensemble-averaged, turbulent, multi-fluid solution algorithm for the multiphase, reacting flow with heat transfer was employed. Mechanistic models applicable to churn turbulent flow have been developed to provide a fundamentally based closure set for the equations. In this four-field model formulation, two of the fields are used to track the gas phase (i.e., ...

Energy Technology Data Exchange (ETDEWEB)

A stochastic-convective reactive (SCR) transport method is developed for one-dimensional steady transport in physically heterogeneous media with nonlinear degradation. The method is free of perturbation amplitude limitations and circumvents the difficulty of scale dependence of phenomenological parameters by avoiding volume-averaged specifications of diffusive/dispersive fluxes. The transport system is conceptualized as an ensemble of independent convective-reactive streamlines, each characterized by a randomized convective velocity (or travel time). Dispersive effects are treated as a component of the randomness in the streamline velocity ensemble, so no explicit expression for hydrodynamic dispersive flux is written in the streamline transport equation. The expected value of the transport over the stream tube ensemble is obtained as an average of solutions to the reactive convection equation according to the stream tube (travel time) ...

Energy Technology Data Exchange (ETDEWEB)

The effective fraction of delayed photoneutrons ({beta}{sup ph}) has been theoretically defined and experimentally determined in various different configurations of the LWR-PROTEUS critical facility. The peculiarity lies in the fact that the reactor has D{sub 2}O in only one of the four fuelled zones, thus D({gamma},n)H reactions take place mainly in this region. The work is divided into three parts. The first part is devoted to the description of the LWR-PROTEUS facility and to the measurements of {beta}{sup ph}. These experimental values are derived from standard inverse-kinetics analysis of neutron flux decay experiments for each of seven different configurations, with nine additional groups of neutron precursors to account for photoneutron effects. In the second part, the coupled neutron and gamma Boltzmann equations are reduced to exact point kinetics equations using the photon infinite-velocity ...

Energy Technology Data Exchange (ETDEWEB)

Hard surface finishing represents the final manufacturing step for functional areas of machine elements in state-of-the-art production. Raceways of rolling bearing rings are ground and honed to the required low roughness. Plastic deformation is restricted to a narrow edge zone of the hardened steel. Reheating of the machined components below the martensite tempering or bainite transformation temperature results in a marked decrease of the XRD line width on the surface. The investigated samples are made of through-hardened standard bearing steel 100Cr6 (international denotation: SAE 52100). On the basis of a material model that explains the effect as a complex diffusion process of dislocational carbon segregation, i.e. static strain aging, the measured kinetics of the XRD line width reduction is simulated by an Arrhenius-type equation, which describes the rate-controlling reaction step of temper carbide dissolution. The formation of a small ...

Energy Technology Data Exchange (ETDEWEB)

The ability of white-rot fungus, Pycnoporus sanguineus to adsorb copper (II) ions from aqueous solution is investigated in a batch system. The live fungus cells were immobilized into Ca-alginate gel to study the influence of pH, initial metal ions concentration, biomass loading and temperature on the biosorption capacity. The optimum uptake of Cu (II) ions was observed at pH 5 with a value of 2.76 mg/g. Biosorption equilibrium data were best described by Langmuir isotherm model followed by Redlich-Peterson and Freundlich models, respectively. The biosorption kinetics followed the pseudo-second order and intraparticle diffusion equations. The thermodynamic parameters enthalpy change (10.16 kJ/mol) and entropy change (33.78 J/mol K) were determined from the biosorption equilibrium data. The FTIR analysis showed that -OH, -NH, C-H, C=O, -COOH and C-N groups were involved in the biosorption of Cu (II) ions onto immobilized cells of P. sanguineus. ...

Energy Technology Data Exchange (ETDEWEB)

The growth power-time curves of a strain of petroleum bacteria, B-2, in various kinds of cultures containing different kinds of carbon sources, glucose, n-tetradecane, n-hexadecane and n-octadecane, and different kinds of microemulsions have been determined by using a 2277 Thermal Activity Monitor. The curves showed a single peak for cultures containing a single carbon source, glucose, and two peaks for cultures containing two kinds of carbon sources, glucose and one of the n-alkanes. The first peak indicated that bacteria grew by consuming glucose and the second peak indicated that bacteria grew by consuming n-alkane. The curves were complex when the bacterium grows in a microemulsion culture. According to a kinetic equation of bacterial growth under limited conditions, the rate constants of bacterial growth were obtained. The results showed that the microemulsion culture was more appropriate to bacteria to grow on n-alkanes.

International Nuclear Information System (INIS)

In order to evaluate postclosure off-site doses from low-level radioactive waste disposal facilities, a computer code was developed to simulate the radionuclide released from waste form, transport through vadose zone and transport in the saturated zone. This paper describes the methodology used to model these process. The radionuclide released from the waste is calculated using a model based on first order kinetics and the transport through porous media was determined using semi-analytical solution of the mass transport equation, considering the limiting case of unidirectional convective transport with three-dimensional dispersion in an isotropic medium. The results obtained in this work were compared with other codes, showing good agreement. (author)

CERN Document Server

Discussions on a form of a frequency spectrum of wind-driven sea waves just above the spectral maximum continue during the last three decades. In 1958 Phillips made a conjecture that wave breaking is the main mechanism responsible for the spectrum formation. That leads to the spectrum decay $\\sim \\omega^{-5}$, where $\\omega$ is the frequency of the waves. There is a contradiction between the numerous experimental data and this spectrum. The experiments show decay $\\sim\\omega^{-4}$. There are two general ways of the explanation of this phenomenon. The first one (proposed by Banner (1990)) takes into account the Doppler effect due to surface circular currents generated by long waves in the Phillips model. The second approach ascends to the work by Zakharov and Filonenko (1968). It is based on four-wave interactions in the kinetic equation and gives good agreement with the experimental data. In this article the contribution to the Phillips ...

British Library Electronic Table of Contents (United Kingdom)

In this context, the bulk ratio of CH4/N2 is examined as a potential alternative geochemical parameter for the assessment of thermal maturity of natural gas and compared to other previously published data. Open-system non-isothermal pyrolysis of low-mature coal from the Manjiaer sag, Tarim basin, yielded generation curves for methane and nitrogen. Analysis of the change of vitrinite reflectance indicates a two-stage process of thermal maturation with increasing temperatures. The relationship between Ro and pyrolysis temperature could be expressed by the following equations: Stage I: Ro = 0.0014T + 0.109, r = 0.9931(Ro Ro = 0.0067T -1.5855, r = 0.9996 (Ro > 0.6%). A kinetic interpretation of the characteristics of nitrogen and methane generation in humic coal during laboratory pyrolysis ind...

British Library Electronic Table of Contents (United Kingdom)

This paper describes a comprehensive model of wastewater treatment in secondary facultative ponds, which combines 3D hydrodynamics with a mechanistic water quality model. The hydrodynamics are based on the Navier-Stokes equation for incompressible fluids under shallow water and Boussinesq assumptions capturing the flow dynamics along length, breadth and depth of the pond. The water quality sub model is based on the Activated Sludge Model (ASM) concept, describing COD and nutrient removal as function of bacterial growth following Monod kinetics, except for Escherichia coli removal, which was modelled as first order decay. The model was implemented in the Delft3D software and was used to evaluate the effect of wind and the addition of baffles on the water flow pattern, temperature profiles i...

International Nuclear Information System (INIS)

A method for converting organic iodides to elemental iodine would be advantageous in improving the performance of charcoal filters for the removal of radio iodines from reactor off gases. A photochemical method has been developed. The HAVCHM code was used to establish the relevant process time scales on a complete set of rate equations describing the primary and secondary reactions occurring in a plug-flow reactor containing low levels of elemental iodine and methyl iodide in air, which is irradiated by intense u.v. light. These simulations were used to justify the contraction of the complete set of reactions to the most significant elementary processes. The contracted set of rate equations are then solved analytically to render the concentration-time profiles of methyl iodide, total inorganic iodine and total oxidized organics, consistent with the achievement of a desirable radioiodine decontamination factor. For the short contact times ...

International Nuclear Information System (INIS)

... halogenation ionizing radiations kinetics radiations reaction kinetics

Energy Technology Data Exchange (ETDEWEB)

Trichloroethene (TCE), a common groundwater contaminant, can be degraded under certain conditions by microorganisms that occur naturally in the subsurface. TCE can be degraded under anaerobic conditions to less chlorinated compounds and ultimately into the non-chlorinated, non-hazardous end product, ethene, via anaerobic reductive dechlorination (ARD). ARD is widely recognized as a TCE degradation mechanism, and occurs in active groundwater remediation and can occur during monitored natural attenuation (MNA). MNA relies on natural processes, such as dispersion and degradation, to reduce contaminant concentrations to acceptable levels without active human intervention other than monitoring. TCE can also be biodegraded under aerobic conditions via cometabolism, in which microbial enzymes produced for other purposes fortuitously also react with TCE. In cometabolism, TCE is oxidized directly to non-hazardous products. Cometabolism as a TCE-degrading process under aerobic conditions is less ...

Science.gov (United States)

It is shown that the extended softening in k space of the [111] transverse acoustic phonon in Nb3Sn seen recently by neutron measurements is in agreement with the predictions of a phenomenological Landau description of the structural phase transition in the A-15 compounds. This indicates the feasibility of a calculation of the partial phonon density of states of modes directly coupled to the order parameter driving the structural transition, as a function of temperature.

International Nuclear Information System (INIS)

The structural instability in high temperature A-15 superconductors is examined from a phenomenological, Landau theoretic point of view, based on the picture of an electronically driven lattice instability. emphasis is given to lattice properties--in particular, the extended softening of phonons in k-pace and phonon linewidth. Implications of the extended softening on the microscopic picture of the transition, and the interplay between structural and superconducting instabilities in the A-15 compounds are discussed.

International Nuclear Information System (INIS)

The study of tropospheric kinetics underlies global change because key greenhouse gases are photochemically active. Modeling of tropospheric chemistry on a global scale is essential because some indirect greenhouse gases are short-lived and interact in a non-linear fashion. It is also extremely challenging, however; the global change grid is extensive in both the physical and temporal domains, and critical lower atmospheric species include the organics and their oxidized derivatives, which are numerous. Several types of optimization may be incorporated into kinetics modules to enhance their ability to simulate the complete lower atmospheric gas phase chemical system. (1) The photochemical integrator can be accelerated by avoiding matrix and iterative solutions and by establishing families. Accuracy and mass conservation are sacrificed in the absence of iteration, but atom balancing is restorable post hoc. (2) Chemistry can be arranged upon the ...

Energy Technology Data Exchange (ETDEWEB)

Abstract not provided

International Nuclear Information System (INIS)

... atp-ase azido compounds biochemical reaction kinetics endoplasmic reticulum

International Nuclear Information System (INIS)

We theoretically model a nuclear-state preparation scheme that increases the coherence time of a two-spin qubit in a double quantum dot. The two-electron system is tuned repeatedly across a singlet-triplet level-anticrossing with alternating slow and rapid sweeps of an external bias voltage. Using a Landau-Zener-Stueckelberg model, we find that in addition to a small nuclear polarization that weakly affects the electron spin coherence, the slow sweeps are only partially adiabatic and lead to a weak nuclear spin measurement and a nuclear-state narrowing which prolongs the electron spin coherence. This resolves some open problems brought up by a recent experiment. We also show that the electronic two-spin states singlet and triplet T_+ are promising candidates for the implementation of a qubit in GaAs double quantum dots (DQD). A coherent superposition of the two-spin states is obtained by finite time Landau-Zener-Stueckelberg interferometry and ...

British Library Electronic Table of Contents (United Kingdom)

Supercritical fluid extraction from dried banana peel (Musa spp., subgroup Prata, genomic group AAB, popularly known in Brazil as Enxerto) was studied. The aspects investigated were: overall extraction curve (OEC), mass transfer modeling of the yield curves, economical analysis of the process and phase equilibrium data for the pseudo-ternary system of banana peel extract, carbon dioxide and ethanol. The extraction operating conditions evaluated were: pressure ranging from 100bar to 300bar, temperature from 40 to 50^oC and constant solvent flow rate of 5.0gCO2/min. Experimental extraction data were correlated using three kinetic models based on mass transfer equations (logistic, diffusion and Esquivel models). Phase equilibrium measurements were performed using pressure from 64.9bar to 239....

Energy Technology Data Exchange (ETDEWEB)

The pozzolanic behaviour of compound-activated red mud-coal gangue has been investigated through TG, DTA, XRD, FTIR and {sup 27}Al MAS NMR. From viewpoint of reaction kinetics, it is found that the pozzolanic reaction mechanism of the compound-activated red mud-coal gangue-lime system is clearly consistent with diffusion control up to 14 days, and the reaction rate constant calculated from Jander equation decreases with the increase of CaO addition in the system. The hydration products formed in the red mud coal gangue-lime systems at ambient temperature are essentially aluminous C-S-H and Ca{sub 3}Al{sub 2}O{sub 6} center dot xH{sub 2}O. From TG analysis results, it is thought that the high amount of Ca(OH){sub 2} in the pastes of studied system is not conducive to the continual increase of non-evaporable water content of the hydration products. Of particular interest. {sup 27}Al MAS NMR proved to be an effective technique to obtain valuable ...

Energy Technology Data Exchange (ETDEWEB)

A class II atomistic force field with Lennard-Jones 6-9 nonbond interactions is used to investigate equations of state (EOS) for important high explosive detonation products N{sub 2} and H{sub 2}O in the temperature range 700-2500 K and pressure range 0.1-10 GPa. A standard 6th order parameter-mixing scheme is then employed to study a 2:1 (molar) H{sub 2}O:N{sub 2} mixture, to investigate in particular the possibility of phase-separation under detonation conditions. The simulations demonstrate several important results, including: (1) the accuracy of computed EOS for both N{sub 2} and H{sub 2}O over the entire range of temperature and pressure considered; (2) accurate mixing-demixing phase boundary as compared to experimental data; and (3) the departure of mixing free energy from that predicted by ideal mixing law. The results provide comparison and guidance to state-of-the-art chemical kinetic models.

CERN Document Server

The term ``dynamo'' means different things to the laboratory fusion plasma and astrophysical plasma communities. To alleviate the resulting confusion and to facilitate interdisciplinary progress, we pinpoint conceptual differences and similarities between laboratory plasma dynamos and astrophysical dynamos. We can divide dynamos into three types: 1. magnetically dominated helical dynamos which sustain a large scale magnetic field against resistive decay and drive the magnetic geometry toward the lowest energy state, 2. flow-driven helical dynamos which amplify or sustain large scale magnetic fields in an otherwise turbulent flow, and 3. flow-driven nonhelical dynamos which amplify fields on scales at or below the driving turbulence. We discuss how all three types occur in astrophysics whereas plasma confinement device dynamos are of the first type. Type 3 dynamos requires no magnetic or kinetic helicity of any kind. Focusing on type 1 and 2 dynamos, we show how ...

International Nuclear Information System (INIS)

The carbon transfer has been analyzed in the Alloy 800/sodium/stainless steel system by determining the carbon-uptake of Alloy 800 foils, which were exposed in liquid sodium of known carburizing potential. Under equilibrium condistions between 650 and 550_0C the measured total carbon concentrations in the Alloy 800 tabs were found to be roughly related to the carbon activities of the sodium environment by the equation already stated for the 18 Cr-8/10 Ni stainless steels, extrapolated to the chemical composition of the Ni-rich austenitic alloy. However the Alloy 800 was not found to undergo any decarburization in low-carbon activity environments. The carbon diffusion kinetics was determined as a function of temperature, it was found to be similar to that reported for the AISI-304 type of steel. The effects of sodium exposure on microstructural and mechanical properties of several Alloy 800 heats were examined at 550_0C as a function of the ...

Science.gov (United States)

The current status of a computational aeroacoustics (CAA) approach to simulate broadband noise is reviewed. The method rests on the use of steady Reynolds averaged Navier-Stokes (RANS) simulation to describe the time-averaged motion of turbulent flow. By means of synthetic turbulence the steady one-point statistics (e.g. turbulence kinetic energy) and turbulent length- and time-scales of RANS are translated into fluctuations having statistics that very accurately reproduce the initial RANS target-setting. The synthetic fluctuations are used to prescribe sound sources which drive linear perturbation equations. The whole approach represents a methodology to solve statistical noise theory with state-of-the-art CAA tools in the time-domain. A brief overview of the synthetic turbulence model and its numerical discretization in terms of the random particle-mesh (RPM) and fast random particle-mesh (FRPM) method is given. Results are presented for ...

Energy Technology Data Exchange (ETDEWEB)

The purpose of this research is to develop a technically and economically feasible process for biologically producing H(sub 2) from synthesis gas while, at the same time, removing harmful sulfur gas compounds. Six major tasks are being studied: 1. Culture development, where the best cultures are selected and conditions optimized for simultaneous hydrogen production and sulfur gas removal; 2. Mass transfer and kinetic studies in which equations necessary for process design are developed; 3. Bioreactor design studies, where the cultures chosen in Task 1 are utilized in continuous reaction vessels to demonstrate process feasibility and define operating conditions; 4. Evaluation of biological synthetic gas conversion under limiting conditions in preparation for industrial demonstration studies; 5. Process scale-up where laboratory data are scaled to larger-size units in preparation for process demonstration in a pilot-scale unit; and 6. Economic ...

CERN Document Server

Nine extrasolar planets with masses between 110 and 430M are known to transit their star. The knowledge of their masses and radii allows an estimate of their composition, but uncertainties on equations of state, opacities and possible missing energy sources imply that only inaccurate constraints can be derived when considering each planet separately. Aims: We seek to better understand the composition of transiting extrasolar planets by considering them as an ensemble, and by comparing the obtained planetary properties to that of the parent stars. Methods: We use evolution models and constraints on the stellar ages to derive the mass of heavy elements present in the planets. Possible additional energy sources like tidal dissipation due to an inclined orbit or to downward kinetic energy transport are considered. Results: We show that the nine transiting planets discovered so far belong to a quite homogeneous ensemble that is characterized by a ...

Energy Technology Data Exchange (ETDEWEB)

Ion diamagnetic effects on the m=1 (poloidal mode number) and n=1 (toroidal mode number) kinetic internal kink mode are studied numerically by the three-field gyro-reduced-MHD code in the cylindrical coordinates, GRM3F-CY. In the derivation of the gryo-reduced-MHD model including the ion diamagnetic effects, finite gyroradius effects of ions are added to the gyrokinetic Poisson equation (quasi-neutral condition) and the convection term of the conservation law of the ion density. It is found that the long wavelength approximation, ksub(perpendicular) {rho}{sub ti} << 1, where ksub(perpendicular) is the wavenumber perpendicular to the magnetic field and {rho}{sub ti} is the thermal ion gyroradius, fails to reproduce the correct dispersion relation; the formulation valid even for ksub(perpendicular) {rho}{sub ti} >> 1 is necessary. The results of numerical calculation coincide with the theory for |{omega}{sub ...

Energy Technology Data Exchange (ETDEWEB)

The aim of the thesis is to validate concepts used in hydrocarbon generation and migration models; the model considered is the Temispack model developed by IFP, and the validation is based on the investigation of the thermal and hydraulic evolution in various sedimentary basins. It is shown that, in general, the thermal history of sediments is influenced by external processes (sedimentation rates, lithology, climate changes, regional-scale groundwater circulations) which frequently overprint internal processes (variations of crustal/mantle heat flow). It is found that external processes can frequently explain past thermal events that were erroneously attributed to internal causes (tectonic-thermal events). The origin of over-pressures in young basins with high sedimentation rates is shown to be generally related to compaction disequilibrium. Shale permeability values calibrated against overpressure profiles are consistent with experimental constraints. Compaction models predict ...

Science.gov (United States)

An x-ray diffraction approach has been developed for determination of the kinetics of growth of Pd/sub 2/Si layers. Epitaxial Pd/sub 2/Si films were grown on Si(111) substrates over a temperature range of 160-222/sup 0/C by a solid-state reaction between the substrates and the Pd overlayers. The parabolic rate equation was verified and rate constants showed Arrhenius behavior with an activation energy E/sub a/ = 1.06 eV and prefactor k/sub 0/ = 7 x 10/sup -4/ cm/sup 2//s. The low value of E/sub a/ suggests a short-circuit diffusion mechanism. It is reasonable to expect that impurities and microstructure may play important roles in the growth process. Impurity levels in the specimens were evaluated by analytic techniques suited to thin-film study: Rutherford backscattering spectrometry, secondary ion mass spectrometry, and Auger electron spectrometry. No impurities were present at concentrations approaching 1 at. %. Some O, C, and F were ...

Science.gov (United States)

As a result of the large limestone deposits available in Poland, the low cost of reagent acquisition for the largescale technological use and relatively well-documented processes of flue gas desulfurization (FGD) technologies based on limestone sorbent slurry, wet scrubbing desulfurization is a method of choice in Poland for flue gas treatment in energy production facilities, including power plants and industrial systems. The efficiency of FGD using the above method depends on several technological and kinetic parameters, particularly on the pH value of the sorbent (i.e., ground limestone suspended in water). Consequently, many studies in Poland and abroad address the impact of various parameters on the pH value of the sorbent suspension, such as the average diameter of sorbent particles (related to the limestone pulverization degree), sorbent quality (in terms of pure calcium carbonate [CaCO3] content of the sorbent material), stoichiometric surfeit of CaCO3 in ...

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The quaternionic formalism for subluminal field equations (Maxwell's equations) and its interrelationship with complex superluminal Lorentz transformations have been given and it has been shown that the quaternionic forms of relativistic equations describe tachyons.

International Nuclear Information System (INIS)

High-energy ionizing radiation is a prominent modality for the treatment of many cancers. The approaches to electron dose calculation can be categorized into semi-empirical models (e.g. Fermi-Eyges, convolution-superposition) and probabilistic methods (e.g. Monte Carlo). A third approach to dose calculation has only recently attracted attention in the medical physics community. This approach is based on the deterministic kinetic equations of radiative transfer. We derive a macroscopic partial differential equation model for electron transport in tissue. This model involves an angular closure in the phase space. It is exact for the free streaming and the isotropic regime. We solve it numerically by a newly developed HLLC scheme based on Berthon et al (2007 J. Sci. Comput. 31 347-89) that exactly preserves the key properties of the analytical solution on the discrete level. We discuss several test cases taken from the medical ...

International Nuclear Information System (INIS)

... kinetics chemical reactions energy dependence ion-molecule collisions milli

International Nuclear Information System (INIS)

A one-dimensional tachyon Klein-Gordon equation is reduced to a nonrelativistic-tachyon equation of motion. The interpretation of this reduced equation leads to the following conclusions: 1) tachyons can be localized in time instead of in space as compared with bradyons, 2) space representation and momentum representation of bradyonic quantum equation of motion are replaced by time representation and energy representation in tachyon quantum equation of motion and 3) with the aid of these results, it has been found that the solutions of the tachyon Klein-Gordon equation of motion form a complete set. (author).

International Nuclear Information System (INIS)

We consider a SQUID ring inductively coupled to an electromagnetic field mode, both treated quantum mechanically. We demonstrate a method for creating a maximally entangled state between the ring and the field mode. Our method utilises a non-adiabatic external magnetic flux pulse to move into and out of a transition region. Hence, our approach is fundamentally different to techniques based on Landau-Zener tunnelling that can also be used to achieve similar results. Our analysis is extended to include the effects of coupling the system to a dissipative environment. With this model we show that although such an environment makes a noticeable difference to the time evolution of the system, it need not destroy the entanglement of this coupled system over time scales required for quantum technologies.

CERN Document Server

It is a pity that the real state of matter in pulsar-like stars is still not determined confidently because of the uncertainty about cold matter at supranuclear density, even 40 years after the discovery of pulsar. Nuclear matter (related to neutron stars) is one of the speculations for the inner constitution of pulsars even from the Landau's time more than 70 years ago, but quark matter (related to quark stars) is an alternative due to the fact of asymptotic freedom of interaction between quarks as the standard model of particle physics develops since 1960s. Therefore, one has to focus on astrophysical observations in order to answer what the nature of pulsars is. In this presentation, I would like to summarize possible observational evidence/hints that pulsar-like stars could be quark stars, and to address achievable clear evidence for quark stars in the future experiments.

International Nuclear Information System (INIS)

In this paper, 0.75Pb(Fe2/3W1/3)O3-0.25PbTiO3-0.15 wt% MnO (0.75PFW-0.25PT-0.15 wt% MnO) ceramics are synthesized by two different methods, the conventional direct oxide synthesized (DS) method and two-step indirect synthesized (IS) method. The low-field dielectric responses are investigated by using the empirical law, the Curie-Weiss law, the modified-Landau theory and the spin-glass model. Due to the IS method, the lattice structure and the grain structure of the samples are changed. Furthermore, the dielectric properties are evidently modified. It is suggested that the ordering degree of B-site cations is enhanced by using the IS synthesized method.

CERN Document Server

The optical birefringence of rod-like nematogens (7CB, 8CB), imbibed in parallel silica channels with 10 nm diameter and 300 micrometer length, is measured and compared to the thermotropic bulk behavior. The orientational order of the confined liquid crystals, quantified by the uniaxial nematic ordering parameter, evolves continuously between paranematic and nematic states, in contrast to the discontinuous isotropic-to-nematic bulk phase transitions. A Landau-de Gennes model reveals that the strength of the orientational ordering fields, imposed by the silica walls, is beyond a critical threshold, that separates discontinuous from continuous paranematic-to-nematic behavior. Quenched disorder effects, attributable to wall irregularities, leave the transition temperatures affected only marginally, despite the strong ordering fields in the channels.

Energy Technology Data Exchange (ETDEWEB)

A classical model is presented for magnetic field-induced Wigner crystallization in electron systems confined within two-dimensional quantum dots. In contrast to other classical models, this one does not treat an electron as a point charge; the electron density is assumed to take a Gaussian form corresponding to the lowest Landau level. Using a Monte Carlo method we have determined the equilibrium configurations as functions of the magnetic field. We have found a classical counterpart of the quantum maximum density droplet (MDD) and studied the breakdown of the MDD into a Wigner molecule as well as the transformations of the Wigner molecule shape induced by the external magnetic field. The phase diagram for the classical Wigner molecules has been presented and its qualitative agreement with previous quantum mechanical calculations has been shown.

Energy Technology Data Exchange (ETDEWEB)

The oxidation of boron carbide in steam or air was recently extensively studied especially in Forschungszentrum Karlsruhe, Institut fuer Materialforschung. An important data set is available for the interaction modelling. An oxygen diffusion model through the superficial liquid boron oxide formed on the boron carbide external surface associated to a superficial reaction between the liquid boron oxide and steam is proposed to simulate the experimental kinetics from BOX rig and thermogravimetric tests on the interaction between steam and boron carbide at a temperature range 800 C to 1400 C. The oxygen diffusion model will be also useful to simulate interaction between boron carbide and Ar+O2 (air simulation) atmosphere when the steam pressure becomes zero. From the analysis of BOX rig experimental kinetics of non-condensable (H2, CO2, CO and CH4) gases we propose an oxygen diffusion model through the liquid boron oxide and a ...

International Nuclear Information System (INIS)

... compounds plants radiation effects radioisotopes reaction kinetics trees

Science.gov (United States)

We obtain the radial Dirac equations for the Plebanski metric and transform these equations into one-dimensional wave equations. Finally we conclude with the result that the electron and the neutrino fields are not superradiant.

CERN Document Server

We study the well-posedness of the initial value problem for a wide class of singular evolution equations. We prove a general well-posedness theorem under three assumptions easy to check: the first controls the singular part of the equation, the second the behavior of the nonlinearities, and the third one assumes that an energy estimate can be found for the linearized system. We allow losses of derivatives in this energy estimate and therefore construct a solution by a Nash-Moser iterative scheme. As an application to this general theorem, we prove the well-posedness of the Serre and Green-Naghdi equation and discuss the problem of their validity as asymptotic models for the water-waves equations.

Energy Technology Data Exchange (ETDEWEB)

Large-eddy-simulations are performed for the heat transfer and the wake flow of a thin rotating disk subjected to an outer parallel passing stream of air. Above a critical value for the angular velocity of the disk, heat transfer augmentation sets on. This is strongly related to a flow instability that leads to a periodic vortex generation at the counter-moving disk side. The resulting phenomena are captured by the classical Landau model. For higher angular velocities the wake becomes fully turbulent, and here the transition to turbulence seems to be very abrupt. In this regime, a periodic vortex generation is observable at the co-moving disk side, too. (orig.) [German] Grobstruktur-Simulationen werden fuer die Waermeuebertragung und die Nachlaufstroemung fuer eine duenne rotierende Scheibe in einem aeusseren parallelen Luftstrom durchgefuehrt. Oberhalb eines kritischen Wertes fuer die Rotationsgeschwindigkeit setzt eine Verstaerkung der Waermeuebertragung ein. ...

Energy Technology Data Exchange (ETDEWEB)

The high frequency, low mode number toroidicity-induced Alfven eigenmodes (TAE) are shown to be driven unstable by the circulating and/or trapped {alpha}-particles through the wave-particle resonances. Satisfying the resonance condition requires that the {alpha}-particle birth speed v{sub {alpha}} {ge} v{sub A}/2{vert bar}m-nq{vert bar}, where v{sub A} is the Alfven speed, m is the poloidal model number, and n is the toroidal mode number. To destabilize the TAE modes, the inverse Landau damping associated with the {alpha}-particle pressure gradient free energy must overcome the velocity space Landau damping due to both the {alpha}-particles and the core electrons and ions. The growth rate was studied analytically with a perturbative formula derived from the quadratic dispersion relation, and numerically with the aid of the NOVA-K code. Stability criteria in terms of the {alpha}-particle beta {beta}{sub {alpha}}, {alpha}-particle pressure ...

International Nuclear Information System (INIS)

The Yang-Mills equations are formulated in the form of generalized Maurer-Cartan equations, such that the corresponding algebraic operations are shown to satisfy the defining relations of homotopy Lie superalgebra.

Energy Technology Data Exchange (ETDEWEB)

Constructed wetlands may be used for removal of high nutrient loads in greenhouse wastewater prior to discharge into the environment. Temperature affects both the physical and biological activities in wetland systems. Since nitrification and denitrification are temperature-dependent processes, effluent nitrate concentrations will fluctuate due to changes in air and wetland temperature. In a cold climate, constructed wetlands can function in a temperature-controlled, greenhouse environment year-round. This work evaluates four temperature treatments on nitrate removal rates in five planted and five unplanted laboratory-scale wetlands. Wetlands were supplied with a nutrient solution similar to the fertigation runoff solution (100 PPM nitrate-N) used in greenhouse crop production. A first-order kinetic model was used to describe experimental nitrate depletion data and to predict nitrate removal rate constants (k) in the wetlands planted with Iris pseudocoras. The ...

Science.gov (United States)

The objective of the study was the kinetic modeling of the effect of storage temperature on the quality and shelf life of chilled fish, modified atmosphere-packed (MAP), and osmotically pretreated with the addition of nisin as antimicrobial agent. Fresh gilthead seabream (Sparus aurata) fillets were osmotically treated with 50% high dextrose equivalent maltodextrin (DE 47) plus 5% NaCl. Water loss, solid gain, salt content, and water activity were monitored throughout treatment and treatment conditions were selected for the shelf life study. Untreated and osmotically pretreated slices with and without nisin (2 x 10(4) IU/100 g osmotic solution), packed in air or modified atmosphere (50% CO(2)-50% air), and stored at controlled isothermal conditions (0, 5, 10, and 15 degrees C) were studied. Quality assessment and modeling were based on growth of several microbial indices, total volatile nitrogen, trimethylamine nitrogen, lipid oxidation (TBARS), and sensory ...

Energy Technology Data Exchange (ETDEWEB)

Coupled modeling of subsurface multiphase fluid and heat flow, solute transport and chemical reactions can be used for the assessment of acid mine drainage remediation, mineral deposition, waste disposal sites, hydrothermal convection, contaminant transport, and groundwater quality. Here they present a numerical simulation model, TOUGHREACT, which considers non-isothermal multi-component chemical transport in both liquid and gas phases. A wide range of subsurface thermo-physical-chemical processes is considered. The model can be applied to one-, two- or three-dimensional porous and fractured media with physical and chemical heterogeneity. The model can accommodate any number of chemical species present in liquid, gas and solid phases. A variety of equilibrium chemical reactions is considered, such as aqueous complexation, gas dissolution/exsolution, cation exchange, and surface complexation. Mineral dissolution/precipitation can proceed either subject to local equilibrium or ...

Energy Technology Data Exchange (ETDEWEB)

Monte Carlo neutron transport methods can be used to verify the applicability of point kinetics for safety analysis of nuclear reactors. KENO-NR was used to obtain the transfer function of the Advanced Neutron Source reactor and the time delay between the core power production and the external detectors, a parameter of interest to the safety systems design. The good agreement between the Monte Carlo generated transfer function and the point kinetics transfer function validates that the uncommon ANS geometry does not preclude the use of point kinetics in the frequency range that was investigated. Various features of the power spectral densities also demonstrated the applicability of point kinetics. The time delay was obtained from the cross-power spectral density (CPSD) and is {approximately}15 ms. These analyses show that frequency analysis can be used experimentally to investigate the validity of the ...

CERN Document Server

In this paper, we study the existence and uniqueness of periodic solutions of the differential equation of the form . Here, we obtain some sufficient conditions which guarantee the existence of periodic solutions. This equation is a quite general third- order nonlinear vector differential equation, and one example is given for illustration of the subject.

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The hierarchy of integrable nonlinear equations associated with the quadratic bundle is considered. The expressions for the solution of linearization of these equations and their conservation law in the terms of solutions of corresponding Lax pairs are found. It is shown for the first member of the hierarchy that the conservation law is connected with the solution of linearized equation due to the Noether's theorem. The local hierarchy and three nonlocal ones of the infinitesimal symmetries and conservation laws explicitly expressed through the variables of the nonlinear equations are derived. (author)

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No abstract prepared.

Energy Technology Data Exchange (ETDEWEB)

This two-volume reference uses many equations to provide detailed information on atomic and nuclear decay phenomena.

International Nuclear Information System (INIS)

The problem in perturbation theory in general relativity is finding a natural gauge which simplifies the equations considerably. We solved the first and second order perturbation equations in the ''Lorentz gauge'' using the two-timing method. The equations were deduced from the equations of Einstein in the presence of a matter energy-momentum tensor of a perfect fluid with equation of state p = (#gamma#-1) rho. It is found that the 0--0 component of the first order equations together with the gauge conditions are consistent with the Bianchi type V model, without axial symmetry. It represents a ''ground state'' situation of the Bianchi type IX model (Mixmaster model.) The second order equations, describing the reaction back of the gravitational waves on the slowly varying background, give rise to rotation and will disturb the isotropization ...

UK PubMed Central (United Kingdom)

The kinetic parameters of single bonds between neural cell adhesion molecules were determined from atomic force microscope measurements of the forced dissociation of the homophilic protein-protein bonds....Full Text Available

UK PubMed Central (United Kingdom)

The kinetics of the degradation of trichloroethylene (TCE) and seven other chlorinated aliphatic hydrocarbons by Methylosinus trichosporium OB3b were studied. All experiments were performed with cells...Full Text Available

UK PubMed Central (United Kingdom)

We have characterized the kinetic response of gene targets throughout the murine genome to transcriptional modulation by the glucocorticoid receptor (GR). In contrast to a model in which multiple genes...Full Text Available

UK PubMed Central (United Kingdom)

The mechanism by which mechanical force regulates the kinetics of a chemical reaction is unknown. Here, we use single-molecule force–clamp spectroscopy and protein engineering to study the effect...Full Text Available

UK PubMed Central (United Kingdom)

We modified an existing enzyme-linked immunosorbent assay (ELISA) to be able to use new spectrophotometers which can measure the rate of color development in microtiter wells. This new kinetic-based...Full Text Available

UK PubMed Central (United Kingdom)

We present the formulation and testing of a mathematical model for the kinetics of homotypic cellular aggregation. The model considers cellular aggregation under no-flow conditions as a two-step process....Full Text Available

Energy Technology Data Exchange (ETDEWEB)

This work deals with kinetic description of carbothermic reduction of iron oxides using microwaves as power source. Previous researches show that it is possible to conduct this kind of process successfully, but real kinetic comparisons between conventional and microwaves procedure have been presented partially. The aim of this work is to describe reduction kinetics, taking into account how the iron oxide is reduced by microwaves compared with conventional energy supply. In this study the authors used iron ore in pellet shape and dust. They found that both, pellet and dust reduction stops when it reaches approximately 40%, even at whole power.

Energy Technology Data Exchange (ETDEWEB)

Studies dialysis kinetics of zinc dialkyldithiophosphates, detergent-dispersing agents, alkyl-phenols and base oils. It was established that diffusion kinetics of oil hydrocarbons through membrane of individual compounds and narrow fractions is described by Brinzinger's formula, which is identical to the kinetic reaction formula of the 1st order. It was shown that dialysis can be utilized to determine the content of the ''active substance'' only in sulphonate and alkylsalycilate additives. Increasing temperature from 20 to 40/sup 0/ results in an increased dialysis constant for all studied products by 1.4-1.9 times.

CERN Document Server

We carry out a Lie group analysis of the Sachs equations for a time-dependent axisymmetric non-rotating space-time in which the Ricci tensor vanishes. These equations, which are the first two members of the set of Newman-Penrose equations, define the characteristic initial-value problem for the space-time. We find a particular form for the initial data such that these equations admit a Lie symmetry, and so defines a geometrically special class of such spacetimes. These should additionally be of particular physical interest because of this special geometric feature.

Energy Technology Data Exchange (ETDEWEB)

Classical molecular dynamics simulations are carried out to investigate the salvation shell exchange kinetics of potassium ion in bulk water, chloroform, and carbon tetrachloride. The reactive flux method is used to compute the dissociation rates. The influence of the solvent on the reaction rates and kinetic properties of this exchange process will be discussed. Comparison will be also be made to the prediction of the Grote-Hynes theory.

International Nuclear Information System (INIS)

The kinetics of lead distribution was studied in suckling and adult rats 8 days after a single intraperitoneal injection of "2"0"3Pb. Marked differences were observed in the kinetics of lead retention and distribution in suckling as compared to adult rats. The rate of "2"0"3Pb disappearance was lower in the whole body, blood and kidneys, but higher in the liver, while the deposition processes predominated in the brain, femur and teeth of sucklings as compared to adult animals. (auth).

Energy Technology Data Exchange (ETDEWEB)

Thermodynamic analysis of dissolution processes of tungsten minerals in citric acid solutions in the absence and in the presence of hydrochloric acid has been carried out by means of calculation of Gibbs energy of the chemical reactions. Kinetic characteristics, such as specific dissolution rates and activation energies, are determined. It is established that the dissolution reactions studied take place in kinetic region. A possibility of scheelite selective dissolution in the presence of other tungsten minerals is shown.

CERN Document Server

We present here the effective theory of inflation `a la Ginsburg-Landau in which the inflaton potential is a polynomial. The slow-roll expansion becomes a systematic 1/N expansion where N ~ 60. The spectral index and the ratio of tensor/scalar fluctuations are n_s - 1 = O(1/N), r = O(1/N) while the running turns to be d n_s/d \\ln k = O(1/N^2) and can be neglected. The energy scale of inflation M ~ 0.7 10^{16} GeV is completely determined by the amplitude of the scalar adiabatic fluctuations. A complete analytic study plus the Monte Carlo Markov Chains (MCMC) analysis of the available CMB+LSS data showed: (a) the spontaneous breaking of the phi -> - phi symmetry of the inflaton potential. (b) a lower bound for r: r > 0.023 (95% CL) and r > 0.046 (68% CL). (c) The preferred inflation potential is a double well, even function of the field with a moderate quartic coupling yielding as most probable values: n_s = 0.964, r = 0.051. This value for r is within ...

Science.gov (United States)

Four-enzyme section of the shikimate pathway (Aro B, D, E, and K) of Streptococcus pneumoniae has been studied. Kinetic properties of the individual enzymes and three- and four-enzyme linked reactions have been characterized in vitro. On the basis of the data measured in spectrophotometric and LC-MS experiments, kinetic mechanisms of the enzymes have been suggested and all kinetic parameters have been identified. Kinetic models for these three- and four-enzyme sections of the shikimate pathway have been constructed and validated. The model of the four-enzyme section of shikimate pathway has been employed to design an inhibition-sensitive reconstituted pathway for a high-throughput screening effort on the shikimate pathway. It was demonstrated that using the model it was possible to optimize this reconstituted pathway in such a way to provide equal sensitivity of the enzymes to inhibition. PMID:16921527

International Nuclear Information System (INIS)

In this work, the pulse plasma nitriding process of pure iron is modelled using a kinetic model derived from the Fick's laws. This approach based on the error function model allows to simulate the growth kinetics of a biphase configuration consisting of #gamma#'-Fe_4N_1_-_x and #epsilon#-Fe_2_-_3N iron nitrides under specified conditions. By coupling the kinetics data about the diffusivities of nitrogen in #alpha#-Fe, #gamma#' and #epsilon# phases to the thermodynamic description of the Fe-N phase diagram, it is possible to evaluate the kinetic constant at each growing phase interface, the thickness of nitrided layer, and predict the nitrogen concentration profiles. The comparison between the experimental and theoretical results shows the reliability of the simulation results.

Energy Technology Data Exchange (ETDEWEB)

A detailed chemical kinetic reaction mechanism is developed to describe incineration of the chemical warfare nerve agent sarin (GB), based on commonly used principles of bond additivity and hierarchical reaction mechanisms. The mechanism is based on previous kinetic models of organophosphorus compounds such as TMP, DMMP and DIMP that are often used as surrogates to predict incineration of GB. Kinetic models of the three surrogates and GB are then used to predict their consumption in a perfectly stirred reactor fueled by natural gas to simulate incineration of these chemicals. Computed results indicate that DIMP is the only one of these surrogates that adequately describes combustion of GB under comparable conditions. The kinetic pathways responsible for these differences in reactivity are identified and discussed. The most important reaction in GB and DIMP that makes them more reactive than TMP or DMMP ...

Energy Technology Data Exchange (ETDEWEB)

An efficient method of hydrogen storage in nano-porous carbons is its reversible sorption by electrochemical decomposition of a KOH water solution according to the following equation: C + xH{sub 2}O + xe{sup -} {yields} (CH{sub x}) + xOH{sup -} where (CH{sub x}) stands for the hydrogen inserted into the nano-porous carbon during charging and oxidized during discharging. Although various carbon materials have been investigated as hydrogen adsorbents, the information about the storage mechanism as well as the nature of the hydrogen/carbon interaction is still not sufficient. In order to extend the understanding of the process, carbon samples charged electrochemically were investigated by temperature programmed desorption (TPD). The nature of the hydrogen/carbon interaction was studied by electrochemical analysis at different temperatures. The TPD experiments consist of heating the samples from room temperature to 950 C and of quantitative analysis by On-line mass ...

International Nuclear Information System (INIS)

To develop the advanced subchannel analysis code, the dominant factors that influence the boiling transitional process must be taken into account in the mechanistic constitutive equations based on the flow geometries and the fluid properties. The dominant factors that influence the boiling transitional processes are (1) the gas-liquid re-distribution by cross flow, (2) the liquid film dryout, (3) the two-phase flow regime transition, (4) the droplet deposition, and (5) the spacer-droplet interaction. At first, we indicated the strategy for the development of the constitutive equations for the five dominant factors based on the experimental database by the latest measurement technique and the latest computational fluid dynamics method. Then, the problems of the present constitutive equations and the improvement plan of the constitutive equations were indicated. Finally, the layered structure for the ...

International Nuclear Information System (INIS)

The static thermophysical properties of the molten salt system like LiF-NaF-BeF_2 influence the design and construction of the fuel salt and coolant in the Molten Salt Reactor for the new generation. In this paper, the equation of state of the ternary system 0.15LiF-0.58NaF-0.27BeF_2, over the temperature range from 873.15K to 1073.15K at one atmosphere pressure, is described by using modified Peng-Robinson equation. The density of the ternary system is evaluated by this equation directly, and compared with the experimental data. Base on the equation of state, the other static thermophysical properties such as the enthalpy, entropy and heat capacity at constant pressure are evaluated by the fugacity coefficient and residual function methods respectively. The density calculated by Peng-Robinson equation is in highly agreement with the experimental data, and the enthalpy, entropy and ...

Science.gov (United States)

The static thermophysical properties of the molten salt system like LiF-NaF-BeF2 influence the design and construction of the fuel salt and coolant in the Molten Salt Reactor for the new generation. In this paper, the equation of state of the ternary system 0.15LiF-0.58NaF-0.27BeF2, over the temperature range from 873.15K to 1073.15K at one atmosphere pressure, is described by using modified Peng-Robinson equation. The density of the ternary system is evaluated by this equation directly, and compared with the experimental data. Base on the equation of state, the other static thermophysical properties such as the enthalpy, entropy and heat capacity at constant pressure are evaluated by the fugacity coefficient and residual function methods respectively. The density calculated by Peng-Robinson equation is in highly agreement with the experimental data, and the enthalpy, entropy and ...

British Library Electronic Table of Contents (United Kingdom)

An elliptic equation in a rectangle with coefficients depending on a fast variable and with its period being a small parameter is considered. An asymptotic expansion of the solution up to an arbitrary degree of the small parameter is constructed and substantiated by applying the two-scale expansion method.

Science.gov (United States)

... However, the solution of the Stefan problem in this context becomes abruptly complicated, since within each zone, the differential equations ...

Science.gov (United States)

... analyze importance sampling schemes for stochastic networks ... an interesting mixed open/closed queueing network ... with a suitable terminal condition ...

CERN Document Server

P. Galenko et al. proposed a modified Cahn-Hilliard equation to model rapid spinodal decomposition in non-equilibrium phase separation processes. This equation contains an inertial term which causes the loss of any regularizing effect on the solutions. Here we consider an initial and boundary value problem for this equation in a two-dimensional bounded domain. We prove a number of results related to well-posedness and large time behavior of solutions. In particular, we analyze the existence of bounded absorbing sets in two different phase spaces and, correspondingly, we establish the existence of the global attractor. We also demonstrate the existence of an exponential attractor.

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the progressive simplification of composite sandwich panels. The equations ... The thermal and structural behavior of composite sandwich panels with a ...

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... Following the application of the error covariance update equation, we apply the following operation to the parameter covariance matrix P+: ...

CERN Document Server

In this Letter the bound states of (2+1) Dirac equation with the cylindrically symmetric $\\delta (r-r_{0})$-potential are discussed. It is surprisingly found that the relation between the radial functions at two sides of $r_{0}$ can be established by an SO(2) transformation. We obtain a transcendental equation for calculating the energy of the bound state from the matching condition in the configuration space. The condition for existence of bound states is determined by the Sturm-Liouville theorem.

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Sandia National Laboratories maintains several libraries of equation of state tables, in a modified Sesame format, for use in hydrocode calculations and other applications. This report discusses one of those libraries, the seslan file, which contains 78 tables from the Los Alamos equation of state library. Minor changes have been made to these tables, making them more convenient for code users and reducing numerical difficulties that occasionally arise in hydrocode calculations.

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We report on the calculation of multi-loop Feynman integrals for single-scale problems by means of difference equations in Mellin space. The solution to these difference equations in terms of harmonic sums can be constructed algorithmically over difference fields, the so-called {pi}{sigma}{sup *}-fields. We test the implementation of the Mathematica package Sigma on examples from recent higher order perturbative calculations in Quantum Chromodynamics. (orig.)

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An overview is provided of an evolving atomistic and kinetic model of semiconductor growth that unifies the main features of strain relaxation in low and high lattice misfit heteroepitaxy. The model reveals a kinetic pathway for dislocation formation during growth with little or no energy cost at low misfits, thus providing a way out of the longstanding dilemma of too high dislocation nucleation energies predicted by classical theories of the equilibrium behavior of a fixed number of particles at low misfits. The essential kinetic process underlying the model are identified on the basis of comparison of the predictions of kinetic Monte-Carlo simulations of growth with real-time or in-situ data obtained in such experiments as reflection high-energy electron diffraction (RHEED) and scanning probe microscopy (SPM). Relative significance of these atomistic kinetic processes is shown to ...

International Nuclear Information System (INIS)

Kinetics of decomposition of gallium and alkali metal intermetallic compounds in the systems LiGa-LiOH, LiGa-NaOH and LiGa-KON was studied in the temperature range of 40-80 deg C. It was ascertained that increase in temperature gives rise to increase in decomposition rate, whereas increase in hydroxide concentration involves the reaction deceleration. An assumption was made that the decomposition occurs with superimposing of two mechanisms, i.e. chemical and electrochemical decomposition. Basic kinetic characteristics of the process were determined - decomposition rate constant and current density

UK PubMed Central (United Kingdom)

The objective of this study was to evaluate how the vehicles of choice affect the pharmacokinetics of orally administered Fluoranthene [FLA] in rats. Fluoranthene is a member of the family of...Full Text Available

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... determination of the molar extinction coefficients, e, were measured by the Lowry method with native a-toxin as a standard. Binding Kinetics. ...

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Data on the reactions of thiocyanogen and thiocyanogen halides with unsaturated compounds are systematised. The kinetic and stereo- and regiochemical regularities of these reactions are analysed. The bibliography includes 81 references.

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The mutual influence between the PP/PS polymer blend components during UV photodegradation was studied. Polypropylene (PP) and polystyrene (PS) have different photodegradation mechanisms, due to the larger UV absorption of polystyrene and formation of more stable tertiary carbon radicals. To compare the stabilities the kinetics of carbonyl formation was measured in different blend compositions. The results show that polystyrene presented a faster carbonyl formation than polypropylene, while the blends display faster kinetics than the isolated components. The kinetics of carbonyl formation of the blends was a function of polypropylene content. This result is unexpected if one considers the behaviour of each component alone. The kinetics and mechanism of UV degradation can be only explained ...

British Library Electronic Table of Contents (United Kingdom)

This study examined kinetics and mass transfer in the biosorption of heavy metals onto Caulerpa lentillifera. The sorption capacity of Cu^2^+, Pb^2^+ and Cd^2^+ from aqueous solution increased with initial metal concentration and decreased with biosorbent dose. Kinetic data were well described using the pseudo-second-order model. Results showed that both external mass transfer and intraparticle diffusion were rate limiting steps in the biosorption process. Activation energy of biosorption kinetics fell in the range of 3-13kJ/mol. The biosorption of Cu^2^+, Cd^2^+ and Pb^2^+ on the biomass correlated well with the Langmuir isotherm (R^2>0.99) with maximum sorption capacities at 293K of 0.169, 0.085 and 0.177mol/kg for Cu^2^+, Cd^2^+ and Pb^2^+ ions, respectively. Thermodynamic studies demon...

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X-ray diffraction offers a unique combination of advantages for kinetic study which include the non-destructive nature of the measurement, the use of bulk crystals, and the convenience of the experimental arrangements. These attributes and the availability of position-sensitive detectors and high-flux synchrotron radiation sources make this technique most useful for in situ, dynamical investigations. When using diffraction techniques to determine a diffusion coefficient, the principle of analysis entails a scattering theory and a kinetic model. The former allows the kinetic parameter(s) to be extracted from measured intensity, while the latter relates the kinetic parameter(s) to the diffusion coefficient(s). Three examples are demonstrated: (1) Palladium Silicide (Pd{sub 2}Si) Layer Growth on Silicon, (2) Decomposition of an Ni-12.5at%Si Superalloy, and (3) Short-range Ordering in Cu-Au Solid Solutions.

UK PubMed Central (United Kingdom)

Background:To determine nutrient requirements by the carbon oxidation techniques, it is necessary to know the fraction of carbon dioxide produced during the oxidative...Full Text Available

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Mar 1, 2011... properties to a complex model demanding full combustion kinetics, transport properties, and poppet valve flow characteristics. ...

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The linearized collective Schroedinger equation for nuclear quadrupole surface vibrations incorporates a new spin degree of freeedom with a spin value of 3/2. We use this equation to describe the low energy spectrum of certain even-odd Ir nuclei which have a spin 3/2 in their ground state. For that purpose we explicitly introduce collective spin-dependent potentials which simulate the interaction of the valence nucleon with the core. The linearized Schroedinger equation is transformed into an effective Schroedinger equation with collective spin-dependent potentials. Already collective spin-orbit couplings of SO(3) and SO(5) type are sufficient to reproduce the lowest excited states of even-odd Ir nuclei. (orig.).

British Library Electronic Table of Contents (United Kingdom)

Abstract The importance of evaluating greenhouse gas (GHG) emissions from dairy cows within the whole farm setting is being realized as more important than evaluating these emissions in isolation. Current whole farm models aimed at evaluating GHG emissions make use of simple regression equations to predict enteric methane (CH4) production. The objective of the current paper is to evaluate the performance of nine CH4 prediction equations that are currently being used in whole farm GHG models. Data used to evaluate the prediction equations came from a collection of individual (IND) and treatment averaged (TRT) data. Equations were compared based on mean square prediction error (MSPE) and concordance correlation coefficient (CCC) analysis. In general, predictions were poor, with root MSPE (as...

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In this paper, a complete solution of the steady-state Newton-Euler equations describing the motion of the balls in high speed thrust bill bearings is presented. Kinematic equations are derived and used as ancillary equations to obtain the numerical solution of the Newton-Euler equations. This differs from previously reported work where extraneous assumptions (instead of kinematic analysis) are used to allow solutions of these equations. It is shown that the no-slip condition for the ball motion reported in the literature is based on an unnecessary assumption. The correct form of the condition is developed and used in the analysis of the ball motion. The analysis shows the importance of contact angle on both ball motion and contact force. An approximate theory is then developed for determining the optimum contact angle that would result in minimum contact force in high speed ball ...

International Nuclear Information System (INIS)

The interfacial area transport equation dynamically models the two-phase flow regime transitions and predicts continuous change of the interfacial area concentration along the flow field. Hence, when employed in the numerical thermal-hydraulic system analysis codes, it eliminates artificial bifurcations stemming from the use of the static flow regime transition criteria. Accounting for the substantial differences in the transport phenomena of various sizes of bubbles, the two-group interfacial area transport equations have been developed. The group 1 equation describes the transport of small-dispersed bubbles that are either distorted or spherical in shapes, and the group 2 equation describes the transport of large cap, slug or churn-turbulent bubbles. The source and sink terms in the right-hand-side of the transport equations have been established by mechanistically modeling the ...

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An efficient method of hydrogen storage in nano-porous carbons is its reversible sorption by electrochemical decomposition of a KOH water solution [1-3] according to the following equation: C + xH{sub 2}O + xe{sup -} {yields} (CH{sub x}) + xOH{sup -} where (CH{sub x}) stands for the hydrogen inserted into the nano-porous carbon during charging and oxidized during discharging. Although various carbon materials have been investigated as hydrogen adsorbents, the information about the storage mechanism as well as the nature of the hydrogen/carbon interaction is still not sufficient. In order to extend the understanding of the process, carbon samples charged electrochemically were investigated by temperature programmed desorpt(TPD). The nature of the hydrogen/carbon interaction was studied by electrochemical analysis at different temperatures. The TPD experiments consist of heating the samples from room temperature to 950 C and of quantitative analysis by on-line mass ...

UK PubMed Central (United Kingdom)

To clarify the kinetic characteristics and ionic requirements of the tonoplast H⁺-translocating inorganic pyrophosphatase (H⁺-PPiase), PPi hydrolysis and PPi-dependent H⁺...Full Text Available

UK PubMed Central (United Kingdom)

NH₄⁺ inhibition kinetics for CH₄ oxidation were examined at near-atmospheric CH₄ concentrations in three upland forest soils. Whether NH₄⁺-independent...Full Text Available

UK PubMed Central (United Kingdom)

The kinetics of the urea-induced dissociation of human plasma alpha 2-macroglobulin into two half-molecular fragments was investigated at 21.0 degrees C by using small-angle neutron scattering. The...Full Text Available

UK PubMed Central (United Kingdom)

The multidrug efflux transporter AcrAB-TolC is known to pump out a diverse range of antibiotics, including β-lactams. However, the kinetic constants of the efflux process, needed for the quantitative...Full Text Available

CERN Document Server

Spain was a scientifically backward country in the early 19th-century. Thecauses were various political events, the War of Independence, and the reign ofFernando VII. The introduction of contemporary physics into textbooks wastherefore a slow process. An analysis of the contents of 19th-century Spanishtextbooks is here presented, centred on imponderable fluids, the concept ofenergy, the mechanical theory of heat, and the kinetic theory of gases.

International Nuclear Information System (INIS)

A simple model is described to simulate kinetic processes in dielectric barrier discharges for O_2/NO_x mixtures. A threshold of ozone production found experimentally is confirmed by the calculations of this modeling, and the underlying chemical reaction mechanisms are discussed. It is also found that the effects of diffusion processes in the period of the lifetime of O atoms are not important to micro-discharge channels with a large radius, i.e. larger than 150 #mu#m

International Nuclear Information System (INIS)

Combining the approaches given by Baldwin [Baldwin D et al. Symbolic computation of exact solutions expressible in hyperbolic and elliptic functions for nonlinear PDEs. J Symbol Comput 2004;37:669-705], Peng [Peng YZ. A polynomial expansion method and new general solitary wave solutions to KS equation. Comm Theor Phys 2003;39:641-2] and by Schuermann [Schuermann HW, Serov VS. Weierstrass' solutions to certain nonlinear wave and evolution equations. Proc progress electromagnetics research symposium, 28-31 March 2004, Pisa. p. 651-4; Schuermann HW. Traveling-wave solutions to the cubic-quintic nonlinear Schroedinger equation. Phys Rev E 1996;54:4312-20] leads to a method for finding exact travelling wave solutions of nonlinear wave and evolution equations (NLWEE). The first idea is to generalize ansaetze given by Baldwin and Peng to find elliptic solutions of NLWEEs. Secondly, conditions used by ...

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Formulation is introduced for discretizing a boundary integral equation into an indirect boundary element method for the solution of 3-dimensional topographic problems. Yokoi and Takenaka propose an analytical solution-capable reference solution (solution for the half space elastic body with flat free surface) to problems of topographic response to seismic motion in a 2-dimensional in-plane field. That is to say, they propose a boundary integral equation capable of effectively suppressing the non-physical waves that emerge in the result of computation in the wake of the truncation of the discretized ground surface making use of the wave field in a semi-infinite elastic body with flat free surface. They apply the proposed boundary integral equation discretized into the indirect boundary element method to solve some examples, and succeed in proving its validity. In this report, the equation is expanded to ...

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Solving a coupled set of differential equations formed by a Fokker-Planck equation and a set of master equations, we can calculate the number of 'prefission' particles (n,p,a), which are emitted from a hot, rotating compound nucleus. Furthermore we get their energy spectrum and their angular momentum distribution. Our results depend sensitively on the friction parameter {gamma}, the inertia M and the fission potential. Comparing the results with experimental data, we may learn something about these quantities. The investigations have been made for {sup 187}Ir and {sup 185}Os. (orig.).

CERN Document Server

Constrained quantum dynamics is used to propose a nonlinear dynamical equation for pure states of a generalized coarse-grained system. The relevant constraint is given either by the generalized purity or by the generalized invariant fluctuation, and the coarse-grained pure states correspond to the generalized coherent i.e. generalized nonentangled states. Open system model of the coarse-graining is discussed. It is shown that in this model and in the weak coupling limit the constrained dynamical equations coincide with an equation for pointer states, based on Hilbert-Schmidt distance, that was previously suggested in the context of the decoherence theory.

CERN Document Server

Big Bang nucleosynthesis requires a fine balance between equations of state for photons and relativistic fermions. Several corrections to equation of state parameters arise from classical and quantum physics, which are derived here from a canonical perspective. In particular, loop quantum gravity allows one to compute quantum gravity corrections for Maxwell and Dirac fields. Although the classical actions are very different, quantum corrections to the equation of state are remarkably similar. To lowest order, these corrections take the form of an overall expansion-dependent multiplicative factor in the total density. We use these results, along with the predictions of Big Bang nucleosynthesis, to place bounds on these corrections.

British Library Electronic Table of Contents (United Kingdom)

Pippenger (2011) recently proposed a solution to the longstanding forward-bias puzzle. He argues that the puzzling estimates obtained using the standard equation for the efficient markets hypothesis are due to omitted variable bias. He identifies the missing variables as the future change in the forward exchange rate and the future interest differential. When these are added to the standard equation, he finds a one-to-one relationship between the future change in the spot rate and the forward premium. However, we argue that his equation can only test covered interest parity and offers no insight into the forward-bias puzzle.

International Nuclear Information System (INIS)

A formalism for the dynamical treatment of the molecular orbitals of valence nucleons in nucleus-nucleus collisions is developed with the use of the coupled-reaction-channel (CRC) method. The Coriolis coupling effects as well as the finite mass effects of the nucleon are taken into account in this model, of rotating molecular orbitals, RMO. First, the validity of the concept is examined from the viewpoint of the multi-step processes in a standard CRC calculation for systems containing two identical [core] nuclei. The calculations show strong CRC effects particularly in the case where the mixing of different l-parity orbitals - called hybridization in atomic physics - occurs. Then, the RMO representation for active nucleons is applied to the same systems and compared to the CRC results. Its validity is investigated with respect to the radial motion (adiabaticity) and the rotation of the molecular axis (radial and rotational coupling). Characteristic molecular orbitals of covalent ...

Science.gov (United States)

pletely new PW fuel cell model had to be developed for CINDA. Several ...... following linear equation, which is used in the SINDA fuel cell model: ...

CERN Document Server

Within the framework of a modified Balitsky-Kovchegov equation, we calculated and provide estimates of non-linear saturation effects expected in the LHC range of energies.

International Nuclear Information System (INIS)

In this paper, research on pass schedule of tandem cold mill (TCM) is carried out. According to load (reduction, rolling force, motor power) balance, non-linear equations set with variables of inter-stand thickness is constructed. The pass schedule optimization is carried out by solving the non-linear equations set. As the traditional method, the Newton-Raphson method is used for solving the non-linear equations set. In this paper a new simple method is brought up. On basis of the monotone relations between thickness and load, the inter-stands thickness is adjusted dynamically. The solution of non-linear equations set can be converged by iterative calculation. This method can avoid the derivative calculation used by traditional method. So, this method is simple and calculation speed is high. It is suitable for on-line control. (author)

International Nuclear Information System (INIS)

Electrodynamic properties of processes involving charged tachyons are considered in connection with the real superluminal Lorentz transformations. These transformations are interpreted without making use of a tachon corridor and so that the interaction of tachyons from subluminal sources with ordinary matter is Lorentz invariant. Transformations of the electromagnetic fields are deduced from the extended principle of relativity. They are necessary in order to obtain the field equations that are satisfied by fields obeying Maxwell equations relative to superluminal inertial frames with respect to subluminal inertial frames. The field equations allow one to get the dependence of the field energy density and its current on the field strengths. The resulting equations are applied in a discussion of plane electromegnetic waves, sent out by a superluminal source. The obtained electrodynamics allows the ...

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a large number of polycrystalline materials, has the fot_ of the. Manson-Coffin- Basquin equation, wherein the exponents of the two power law terms are given ...

UK PubMed Central (United Kingdom)

The solution of the continuity equation in practical applications is examined, and the values needed for approximate solutions are indicated. Models are adequate for investigating what could happen,...Full Text Available

International Nuclear Information System (INIS)

The objective of this research is to replace the current flow regime dependent interfacial area correlations in the thermal-hydraulic system analysis codes with an interfacial area transport equation, which dynamically models two-phase flow regime transitions. The interfacial area transport equation applicable to bubbly flows has been developed based on mechanistic modeling of bubble interaction. Detailed experiments have been performed for bubbly conditions in 2.54, 5.08 and 10.16-cm ID pipes to benchmark the model. This new approach predicts the continuous changes of the interfacial area and will eliminate artificial bifurcations stemming from the use of the static flow regime transition criteria. This paper presents the preliminary results of incorporating the one-group transport equation into the USNRC consolidated code, currently under development. The framework for the two-group transport equation ...

CERN Document Server

A well-known diffuse interface model consists of the Navier-Stokes equations nonlinearly coupled with a convective Cahn-Hilliard type equation. This system describes the evolution of an incompressible isothermal mixture of binary-fluids and it has been investigated by many authors. Here we consider a variant of this model where the standard Cahn-Hilliard equation is replaced by its nonlocal version. More precisely, the gradient term in the free energy functional is replaced by a spatial con- volution operator acting on the order parameter phi. Therefore the coupling with the Navier-Stokes equations is difficult to handle even in two spatial dimensions because of the lack of regularity of phi. We establish the global existence of a weak solution.

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... 2.5.6 Development of Observation Equations . . . . . 25 2.6 Inertial Navigation Error Model . . . . . ... 2 , as expected. 2.6 Inertial Navigation Error Model ...

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... Abstract : The purpose of this paper is to introduce strapdown inertial navigation error equations based on a quaternion relation between body-fixed ...

CSIR Research Space (South Africa)

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In Randall-Sundrum-type brane-world cosmologies, the dynamical equations on the three-brane differ from the general relativity equations by terms that carry the effects of imbedding and of the free gravitational field in the five-dimensional bulk. Instead of starting from an ansatz for the metric, we derive the covariant nonlinear dynamical equations for the gravitational and matter fields on the brane. The local energy-momentum corrections are significant only at very high energies, and in this regime we show that fluid world-lines have a non-gravitational acceleration off the brane. The imprint on the brane of the nonlocal gravitational field in the bulk is more subtle, and we provide a careful decomposition of this effect. The nonlocal energy density determines the tidal acceleration in the off-brane direction, and can oppose singularity formation via the generalized Raychaudhuri equation. Unlike the ...

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The interaction of thermal radiation with conduction and convection in thermally developing absorbing, emitting, non-gray gas particulate turbulent suspension flow through a circular tube is investigated. The contribution of thermal radiation is obtained through evaluation of the total hemispherical emittance of the particulate cloud and through evaluation of single band absorptances for molecular gases, modified to account for the interaction with the particles. The governing differential equation is derived as a (nonlinear) energy equation, coupled with integral equations to find the thermal radiation contributions. The energy equation is solved numerically by an implicit finite difference with its iterative procedure. Qualitative results for Nusselt numbers are shown for a variety and range of parameters, such as optical thickness of particulates and single molecular gas bands, relative gas band ...

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The solution of the governing steady transport equations for momentum, heat and mass transfer in flowing fluids can be very difficult. These difficulties arise from the nonlinear, coupled, nonsymmetric nature of the system of algebraic equations that results from spatial discretization of the PDEs. In this manuscript the authors focus on evaluating a proposed nonlinear solution method based on an inexact Newton method with backtracking. In this context they use a particular spatial discretization based on a pressure stabilized Petrov-Galerkin finite element formulation of the low Mach number Navier-Stokes equations with heat and mass transport. The discussion considers computational efficiency, robustness and some implementation issues related to the proposed nonlinear solution scheme. Computational results are presented for several challenging CFD benchmark problems as well as two large scale 3D flow simulations.

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We consider particle evaporation and fission of an ensemble of hot, rotating compound nuclei as a stochastic process. We derive a set of coupled differential equations formed by a Fokker-Planck equation describing fission, and master equations for calculating particle evaporation. From these equations, we are able to determine multiplicities of prefission neutrons, protons and {alpha}-particles, their energy spectra and their angular momentum distributions. A comparison of our results with experimental data provides us with information regarding the reduced friction coefficient {beta}, the fission barrier height and the level density parameter. For different iridium isotopes, ({sup 181,185,187}Ir), {sup 185}Os and {sup 158}Er, we obtain as an upper limit {beta}{<=}8.0x10{sup 21} s{sup -1}. (orig.).

CERN Document Server

A set of mode-coupled excitation equations for the slowly-growing amplitudes of dielectric waveguide eigenmodes is derived as a description of the electromagnetic signal field of a high-gain free-electron laser, or FEL, including the effects of longitudinal space-charge. This approach to describing the field basis set has notable advantages for FEL analysis in providing an efficient characterization of such eigenmodes, and in allowing a clear connection to free-space propagation of the input (seeding) and output radiation. A simple transformation converts the coupled differential excitation equations into a set of coupled algebraic equations and yields a matrix determinant equation for the FEL eigenmodes. A quadratic index medium is used as a model dielectric waveguide to obtain an expression for the predicted spot size of the dominant eigenmode, in the approximation that it consists of a single ...

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This document is the final report for Cooperative Agreement DE-FC26-04NT42314, 'Kinetics Study of Mercury Reactions in FGD Liquors'. The project was co-funded by the U.S. DOE National Energy Technology Laboratory and EPRI. The objective of the project has been to determine the mechanisms and kinetics of the aqueous reactions of mercury absorbed by wet flue gas desulfurization (FGD) systems, and develop a kinetics model to predict mercury reactions in wet FGD systems. The model may be used to determine optimum wet FGD design and operating conditions to maximize mercury capture in wet FGD systems. Initially, a series of bench-top, liquid-phase reactor tests were conducted and mercury species concentrations were measured by UV/visible light spectroscopy to determine reactant and byproduct concentrations over time. Other measurement methods, such as atomic absorption, were used to measure concentrations of ...

International Nuclear Information System (INIS)

Studies at Commissariat a l'Energie Atomique (CEA) have been under way for three years in an attempt to find methods for preventing and stopping denting. Tests have been performed in 28 model boilers (Ajax with U tubes and Clarinette with straight tubes). In these boilers, with continous injection and blowdown, and heat flux is about 40 W X cm"-"2 (126900 Btu/ft"2 X h). The kinetics of denting has been studied with different levels of faulting. Some high-temperature electrochemical measurements established the mechanism of denting in the boiler tests. Denting kinetics can be rationalized in terms of three main parameters: faulting level, heat flux, and relative mechanical strength of the tube compared to the support plate.

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Among the several chemical processes conducted for the removal of organic matter present in wastewaters coming from some agro-industrial plants (wine distilleries, olive oil mills, etc), the oxidation by ozone has shown a great effectiveness in the destruction of specially refractory pollutants: it is demonstrated that the biodegradability of those wastewaters increases aflcer an ozonation pretreatment. Their great pollutant character is imputed to the presence of some organic compounds, like phenols and polyphenols, which are toxic and inhibit the latter biological treatments. In this research, a competitive kinetic procedure reported by Clurol and Nekouinaini is applied to determine the degradation rate constants by ozone of several phenolic acids which are present in the wastewaters from the olive oil obtaining process. The resulting kinetic expressions for the ozonation reactions are useful for the successful design and operation of ozone ...

International Nuclear Information System (INIS)

The #beta#-CEZ alloy : Ti-5%Al-2%Sn-4%Zr-4%Mo-2%Cr-1%Fe is a near #beta# titanium alloy. Since its processing routes include heat treatment (consisting of solution treatment and ageing), it has been decided to study the influence of the #beta# phase stability on #alpha# phase precipitation and hardening kinetics. Small sized specimens, coming from industrial heats, have been heat treated above and below the #beta# transus, and then water quenched. Therefore, several degree of #beta# stability are obtained. When it is increased (i.e. the solution treatment temperature is lowered), #alpha# or #omega# phases precipitations are delayed, as well as the hardening phenomena. Moreover, the #omega# stability domain is reduced. The mechanisms of #alpha# or #omega# precipitation are discussed, and related to the hardening kinetics. (orig.).

Science.gov (United States)

The kinetic rate constants for the cracking, isomerization, and disproportionation of n-heptane over a CrHNaY (32% chromium exchanged) zeolite catalyst at 400, 450, and 470/sup 0/C have been calculated. The interaction of n-heptane with a model Lewis acid such as BF/sub 3/ and progress along the reaction coordinate have been studied by means of molecular orbital calculations. From the kinetic results, i.e., activation energies and frequency factors, and the theoretical calculations, it can be concluded that the controlling step in these reactions is not the formation of the carbonium ion, but the subsequent transformation of this carbonium ion. In addition, the theoretical calculations show that the attack of a Lewis acid is more likely to occur on a carbon atom than on a C-H bond.

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Reactive chemical transport models developed over the past decade have generally relied on the assumption that local thermodynamic equilibrium is achieved at all times between aqueous species in a given system. Consequently, homogeneous aqueous systems characterized by a number of kinetically slow reactions, particularly problems involving organic species, cannot be satisfactorily modeled. In this study, we present a prototype computer model, KINETRAN, which is designed to handle kinetically-controlled homogeneous reactions in the aqueous phase, along with the transport of the various species involved, through geologic media. 31 refs., 53 figs., 10 tabs.

British Library Electronic Table of Contents (United Kingdom)

b-carotene, a natural antioxidant, beneficial form human health prospective. In this study we had examined the recovery of b-carotene form mesoporous carbon coated monolith (MCCM) by batch process. Desorption kinetics and isotherm studies were carried out by using n-hexane as an eluent. Isotherm studies showed better applicability of Langmuir model. The first-order two-compartment three-parameter kinetics model as a function of initial loading concentration and reaction temperature was applied. It was observed that b-carotene desorption process is controlled by both rapid and slow desorption. Results showed that the slow desorption fraction increases from 0.8446 to 0.9007 with increase in initial loading concentration from 10.83 to 39.72mg/g while, the slow desorption fraction decreases fr...

International Nuclear Information System (INIS)

The kinetics of the reactions between mixed powders of BaCO_3 and CuO, as well as BaCO_3 and Y_2O_3, have been studied using DXRD techniques as a function of particle size, temperature, and CO_2 pressure. Except for initial nucleation phenomena, the reaction rates are governed by shrinking core behavior for BaCO_3 particle sizes between 6 and 33 #mu#m. During the initial stages of the reactions, the surface reaction kinetics are governing, whereas the diffusion of CuO, Y_2O_3, and CO_2 are limiting factors at later stages in the reactions. Quantitative conversion data were used to determine the values of the activation energies and the pertinent diffusivities in these systems.

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This project is concerned with the kinetics and mechanisms of aromatic oxidation and soot and fullerenes formation in flames. The objective of the aromatics oxidation work is to identify and measure the concentration of important intermediates and products in benzene oxidation, and to determine reaction mechanisms and kinetics properties consistent with the behavior seen in flames. The research on soot formation is concerned primarily with the particle inception stages, but the work includes study of soot structure at all stages of growth in order to obtain mechanistic information from evidence of growth steps recorded in the structure of the particles. The ultimate objective is to understand how nascent soot particles are formed from high molecular weight compounds, including the roles of planar and curved PAH and the relationship between soot and fullerenes. The objective of the proposed research on fullerenes is to develop a more ...

Science.gov (United States)

The pressure of a 6:12 fluid is obtained from the Percus-Yevick theory at the temperature kT/? = 1.35. The energy equation results are in excellent agreement with machine calculation results in contrast to the pressure and compressibility equation results. Present address: Diffusion Research Unit, The Australian National University, Canberra, ACT, Australia.

International Nuclear Information System (INIS)

An explicite PN solution of the multi-dimensional homogeneous neutron transport equation is given by expanding the angular flux into a series of geometry-independent spherical harmonics operators. An algorithm is developed for representing the spherical harmonic operators in orthogonal curvilinear coordinates. The general formulae are applied to two-dimensional spherical geometry; detailed P3 formulae are given. (orig.).

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The wave equation of a spinless tachyon is studied in Schwarzschild space-time. In contrast to earlier approaches to the problem, it is shown that tachyonic static solutions satisfy a simple second-order linear differential equation regardless of the mass of the black hole and the mass parameter of the tachyon. Physical implication of the present approach is discussed. Using Langer modification of the WKB (Wentzel-Kramers-Brillouin) boundary condition an expression similar to the Bohr-Sommerfeld quantization condition is derived.

International Nuclear Information System (INIS)

To simulate the effects of the breakup channel on rearrangement amplitudes, the conventional coupled-reaction-channel (CRC) expansion is augmented by pseudoreaction channels. The construction of the projector for the extended CRC space is discussed, and transition-operator equations on this space are given. By solving the full and post-approximation forms of the CRC equations for a model three-particle problem, the crucial role played by the nonorthogonality terms is demonstrated.

British Library Electronic Table of Contents (United Kingdom)

Diffraction by an impermeable scatterer in ?3 with a Dirichlet boundary condition is considered. It is shown that the null field equation is equivalent to the original diffraction problem. The general theoretical constructions are illustrated by analyzing the excitation of a sphere by a point source. The evolution of the residual of the null field equation as the scatterer surface is approached by an auxiliary surface is estimated.

International Nuclear Information System (INIS)

1 - Description of program or function: This program solves an eigenvalue problem zBx=Ax where A and B are real block tri-diagonal matrices. This eigenvalue problem is derived from a reduced set of linear resistive MHD equations which is often employed to study tokamak plasma stability problem. 2 - Method of solution: Both the determinant and inverse iteration methods are employed. 3 - Restrictions on the complexity of the problem: The eigenvalue z must be real

British Library Electronic Table of Contents (United Kingdom)

By a variant version of Fountain Theorem due to Zou [W. Zou, Variant fountain theorems and their applications, Manuscripta Math. 104 (2001) 343-358], the existence of infinitely many solutions is obtained for a class of biharmonic equations where the nonlinearity involves a combination of superlinear and asymptotically linear terms.

Energy Technology Data Exchange (ETDEWEB)

Zanker has recently presented nomographs for determining particle settling velocities in solid-liquid systems. These nomographs were based on the general correlations developed by Barnea and Mizrahi and Barnea and Mednick. This work presents an equation directly computing particle settling velocities, eliminating the uncertainty associated with nomographs.

Energy Technology Data Exchange (ETDEWEB)

The interfacial area transport equation dynamically models the two-phase flow regime transitions and predicts continuous change of the interfacial area concentration along the flow field. Hence, when employed in the numerical thermal-hydraulic system analysis codes, it eliminates artificial bifurcations stemming from the use of the static flow regime transition criteria. Accounting for the substantial differences in the transport phenomena of various sizes of bubbles, the two-group interfacial area transport equations have been developed. The group 1 equation describes the transport of small-dispersed bubbles that are either distorted or spherical in shapes, and the group 2 equation describes the transport of large cap, slug or churn-turbulent bubbles. The source and sink terms in the right-hand-side of the transport equations have been established by mechanistically modeling the ...

Energy Technology Data Exchange (ETDEWEB)

This demonstration project uses modern simulation techniques to illustrate the important technologies and design variables that an auto-designer would consider in production a high efficiency, low emissions vehicle. Simulation and modeling techniques use the idea of capturing the relationships between real components of the systems with mathematical equations. These equations are then solved on a computer to simulate the behavior or performance of the system under various conditions. In the current demonstration project, we focus on many variations of a hydrogen-powered vehicle.

British Library Electronic Table of Contents (United Kingdom)

Four solutions of the Cauchy problem for Mathieu?s equation away from parametric resonance domains are analytically constructed using an asymptotic averaging method in the fourth approximation. Three solutions occur near fractional parameter values at which slow combination phases exist. The fourth solution occurs in the absence of slow phases away from parametric resonance domains and the fractional parameter values.

International Nuclear Information System (INIS)

To calculate the energy band structures in semiconductors using the relativistic augmented plane wave method, atomic potential and charge density are needed, which are calculated by self-consistent method. Wave function for one electron is determined by solving the Dirac equation with the Hartree-Fock equation based on the slater's exchange potential. The results of calculation for Cu"+"1 are given. (Author).

Energy Technology Data Exchange (ETDEWEB)

The effect of finite gyroradius on the current diffusive ballooning mode is examined. Starting from the reduced MHD equations including turbulent transports, coupling with drift motion and finite gyroradius effect of ions, we derive a ballooning mode equation with complex transport coefficients. The eigenfrequency, saturation level and thermal diffusivity are evaluated numerically from the marginal stability condition. Preliminary results of their parameter dependence is presented. (author)

International Nuclear Information System (INIS)

A formula for calculating the Dirac S-matrix for central Lorentz scalar and vector potentials is derived by use of a new amplitude-phase method. The derivation also makes use of certain invariants of the reduced 2-spinor radial Dirac equations.

Energy Technology Data Exchange (ETDEWEB)

We consider the problem of rotation in a homogeneous Bianchi type IX cosmological model. Studying the Wheeler-De Witt equation corresponding to this minisuperspace, and adopting a particular choice of the factor ordering, we are able to find a particular solution which is strongly peaked about isotropy. This result confirms all the previous investigations in this field, and suggests the conclusion that the machian nature of our universe is the natural, i.e. most likely, outcome of the Planck epoch. (orig.).

Energy Technology Data Exchange (ETDEWEB)

Numerical simulations of compressible flows are commonly based on the Euler equations when effects of viscosity are thought to be negligible. These equations admit singular solutions, even in cases where the initial and boundary conditions are smooth. So-called ''Euler solvers'' rely on numerical dissipation, explicitly or implicitly present in the scheme, to regularize the problem, such that physical solutions are selected.

Science.gov (United States)

The properties and kinetics of x-ray stars in globular clusters are described. Locations, configurations, star evolution, massive close binary systems, various mechanisms, and the x-ray burster properties are included. (JFP)

Energy Technology Data Exchange (ETDEWEB)

This book examines some of the basic principles behind chemical reaction kinetics. Topics considered include the classical trajectory approach to reactive scattering; periodic orbits and theory of reactive scattering; and semiclassical reactive scattering.

Energy Technology Data Exchange (ETDEWEB)

Orujillo, sometimes called wood matter from pressed oil-stone (WPOS) is a residue from the olive oil mill industry. The generation of this biomass residue is concentrated in small areas allowing its use as fuel for medium size gasification and combustion plants. Rates of gasification of WPOS char were measured in a TGA at various temperatures (800-850-875-900-950{sup o}C), CO{sub 2} partial pressures (0.20-0.35-0.50 bar) and CO partial pressures (0.0-0.20 bar). The experiments were carried out with a monolayer bed of very fine particles well exposed to the gas so as to minimise mass and heat transfer resistances. Two kinetic models, the nth order model and Langmuir-Hinshelwood model, have been used to fit with the reactivity data. For pure CO{sub 2} experiments the kinetic parameters of nth order model were E=133 kJ/mol and n=0.43. The Langmuir-Hinshelwood kinetic model clearly describes the observed CO inhibition effect on ...

UK PubMed Central (United Kingdom)

During embryonic development, cells are instructed which position to occupy, they interpret these cues as differentiation programmes, and expand these patterns by growth. Sonic hedgehog...Full Text Available

Science.gov (United States)

Radiation Measurement in Crew Compartment. DTO 805: .... spacecraft and aircraft propulsion, and hazardous waste disposal. ...... combustion reactions in a turbulent chemical kinetic flow reactor using laser induced fluorescence and ...

UK PubMed Central (United Kingdom)

The gelation kinetics of an in situ gelable hydrogel formulated from oxidized dextran (Odex) and N-carboxyethyl chitosan (CEC) were investigated rheologically. Both Schiff base...Full Text Available