Lean premixed combustion (LPC) of natural gas is of considerable interest in land-based gas turbines for power generation. However, modeling such combustors and adequately addressing the concerns of LPC, which include emissions of nitrogen oxides, carbon monoxide and unburned hydrocarbons, remains a significant challenge. In this paper, characteristics of published simulations of gas turbine combustion are summarised and methods of modeling turbulent combustion are reviewed. The velocity-composition PDF method is selected for implementation in a new comprehensive model that uses an unstructured-grid flow solver. Reduced mechanisms for methane combustion are evaluated in a partially stirred reactor model. Comprehensive model predictions of swirl-stabilised LPC of natural gas are compared with detailed measurements obtained in a laboratory-scale combustor. The model is also applied to industrial combustor geometries. (Author)
Most of the anthropogenic emissions of carbon dioxide result from the combustion of fossil fuels for energy production. Photosynthesis has long been recognized as a means, at least in theory, to sequester anthropogenic carbon dioxide. Aquatic microalgae have been identified as fast growing species whose carbon fixing rates are higher than those of land-based plants by one order of magnitude. Physical Sciences Inc. (PSI), Aquasearch, and the Hawaii Natural Energy Institute at the University of Hawaii are jointly developing technologies for recovery and sequestration of CO{sub 2} from stationary combustion systems by photosynthesis of microalgae. The research is aimed primarily at demonstrating the ability of selected species of microalgae to effectively fix carbon from typical power plant exhaust gases. This report covers the reporting period 1 April to 30 June 2003 in which PSI, ...
... be easily replaceable, and its compartment or container ... in a simple, efficient manner for storage or disposal. ... and enters the reactor at approximatel ...
The German-Russian project that is part of the G8 initiative on Global Partnership Against the Spread of Weapons and Materials of Mass Destruction focuses on the speedy construction of a land-based interim storage facility for nuclear submarine reactor compartments at Sayda Bay near Murmansk. This project includes the required infrastructure facilities for long-term storage of about 150 reactor compartments for a period of about 70 years. The interim storage facility is a precondition for effective activities of decommissioning and dismantlement of almost all nuclear-powered submarines of the Russian Northern Fleet. The project also includes the establishment of a computer-assisted waste monitoring system. In addition, the project involves clearing Sayda Bay of other shipwrecks of the Russian navy. On the German side the project is carried out by the Energiewerke Nord GmbH (EWN) on behalf of the Federal ...
A corrosion-testing program has been initiated in Purex and Redox storage tnnks to obtain corrosion data on carbon steel and three associated materials in neutralized process wastes. (C.W.H.)
Most of the anthropogenic emissions of carbon dioxide result from the combustion of fossil fuels for energy production. Photosynthesis has long been recognized as a means, at least in theory, to sequester anthropogenic carbon dioxide. Aquatic microalgae have been identified as fast growing species whose carbon fixing rates are higher than those of land-based plants by one order of magnitude. Physical Sciences Inc. (PSI), Aquasearch, and the Hawaii Natural Energy Institute at the University of Hawaii are jointly developing technologies for recovery and sequestration of CO{sub 2} from stationary combustion systems by photosynthesis of microalgae. The research is aimed primarily at demonstrating the ability of selected species of microalgae to effectively fix carbon from typical power plant exhaust gases. This report covers the reporting period 1 January to 31 March 2004 in which PSI, ...
Power supply to Bergen has created headaches. Many will not have the land-based high-voltage wire. But the alternatives are costly and will delay the line by many years. (AG)
... operational AUV and Unmanned Underwater Vehicle (UUV) ... by Brooks with land-based robots [BROOKS 88 ... system for a mobile land robot called ...
This paper describes the estimated the rate of carbon accumulation in the woody biomass and total carbonstorage in the forests including trees, soil and litter in Korea. The relevant data come from the Statistical Yearbook of Forestry and major results of the studies on forest biomass in Korea. Most of the forests, which has been denuded or degraded during the 2nd World War and the Korean War, were recovered through ``Reforestation Project(1973-1987)`` and natural regeneration. So, now they are mostly young secondary forests and grow rapidly. Total carbon removal by forests is estimated at 8.1 million tonnes of carbon(MtC) and the carbon emission by commercial harvesting at 0.9 MtC. therefore, the forests in Korea play an essential role as a net carbon sink. The annul net carbon removal is 7.2 MtC and accounts for about ...
A study in northeast Germany has shown that the establishment of short rotation coppices (SRC) of Robinia pseudoacacia L. may be a viable option for improving farmers income on marginal soils. The plantations produce woody biomass at a fast rate for energy use. Carbon is accumulated in the harvestable biomass, as well as in the stump and the roots. These plant compartments form a long-term carbonstorage pool because they can survive a harvest, stay vital at the site and continue to grow as the plant ages. As organic litter decomposes, additional carbon is sequestered under SRC as soil organic carbon. The carbon sequestration in SRC of R. pseudoacacia on mining sites within the Lower Lusatian region in northeast Germany was studied and the results were complemented with findings of current field studies conducted on reclaimed mine sites. The average above ground ...
In the framework of the carbonstorage two forestry methods are analyzed by the author: the standing capitalization (slowing of the crops) and the spices substitution (slow growing species by fast growing species). The construction of a model taking into account the all stage of the carbon implication (biomass, soil, forest products) offers simulation and quantitative results on these methods. (A.L.B.)
Summary of personnel, commitments, and costs ... Origin of complex land-based ecosystems (W. Friedman) ...... technology has brought about the birth of lab- ..... Baross, J.A. and S.E. Hoffman, Submarine hydrothermal vents and ...
Carbon steel is frequently used to construct concentrated sulphuric acid storage tanks. This paper discussed the corrosion performance of carbon steel tanks and outlined the underlying mechanisms responsible for major corrosion modes. Analyses of hydrogen grooving and dilute acid corrosion failure mechanisms were presented. Recent corrosion-induced leak failures were also discussed. The use of anodic protection and organic coatings as a corrosion control measure was also evaluated. The results of laboratory studies that were conducted to understand corrosion-induced failures showed that carbon steel electrodes exhibited transpassive corrosion at relatively high anodic potentials, while stainless steel electrodes exhibited transpassive corrosion at anodic potentials less than 1 V. It was concluded that corrosion-induced leaks can be prevented by using anodic protection and baked phenolic coating ...
... Areas of Consultation: All Areas About DECC Bioenergy Carbon capture & storageCarbon Reduction Commitment Climate Change Agreements CRC energy efficiency scheme Development, consents and planning reform Electricity Electricity network Emissions Emissions trading Energy markets Energy network Energy security Feed-in Tariffs Fuel poverty Funding and support Gas Governance Green Deal Hydroelectricity International climate change International energy Legislation Low-carbon Microgeneration News Nuclear Oil Renewable energy Saving energy and CO2 Site Wide Footer Smart ...
An efficient method of hydrogen storage in nano-porous carbons is its reversible sorption by electrochemical decomposition of a KOH water solution according to the following equation: C + xH{sub 2}O + xe{sup -} {yields} (CH{sub x}) + xOH{sup -} where (CH{sub x}) stands for the hydrogen inserted into the nano-porous carbon during charging and oxidized during discharging. Although various carbon materials have been investigated as hydrogen adsorbents, the information about the storage mechanism as well as the nature of the hydrogen/carbon interaction is still not sufficient. In order to extend the understanding of the process, carbon samples charged electrochemically were investigated by temperature programmed desorption (TPD). The nature of the hydrogen/carbon interaction was studied by electrochemical analysis at ...
This paper reports the estimates concerning the atmospheric carbon dioxide absorption and storage by living plants all over the world. It is necessary to decrease atmospheric carbon dioxide concentrations for avoiding global warming. As living plants absorb carbon dioxide by photosynthesis and accumulate carbon in their bodies, they can play an important role to remove atmospheric carbon dioxide. Literatures describing distribution areas, biomass values and net primary productivity (NPP) of forests, marine plants and microorganisms were collected. Examining those data, the biomass and NPP of forests, marine plants and microorganisms can be summarized as follows: (1) Forest biomass and their NPP of the world. The world's forest area is recently estimated as 4 billion hectares, and their biomass is about 400 billion tons of carbon ...
Full text of publication follows: Energy and environment are two major concerns in our modern society due to the coming shortage in fossil energy sources and the growing of greenhouse gas emissions. The challenge for the coming years is to discover new energy resources and to develop devices that are compatible with a sustainable development and generate few (or zero) emission. One of these devices is the fuel cell feed by hydrogen, whose application fields are very large. In particular, the proton exchange membrane fuel cell (PEMFC) is the most realistic device for automotive application. However, hydrogen storage remains one of the most important challenges regarding its development. Although different techniques are available for storing hydrogen, no ideal solution has been found yet. Compression needs elaborated tanks in shape for supporting high pressures, liquefaction requires an expensive hydrogen cooling and adapted tanks. Chemical ...
Full text of publication follows: Energy and environment are two major concerns in our modern society due to the coming shortage in fossil energy sources and the growing of greenhouse gas emissions. The challenge for the coming years is to discover new energy resources and to develop devices that are compatible with a sustainable development and generate few (or zero) emission. One of these devices is the fuel cell feed by hydrogen, whose application fields are very large. In particular, the proton exchange membrane fuel cell (PEMFC) is the most realistic device for automotive application. However, hydrogen storage remains one of the most important challenges regarding its development. Although different techniques are available for storing hydrogen, no ideal solution has been found yet. Compression needs elaborated tanks in shape for supporting high pressures, liquefaction requires an expensive hydrogen cooling and adapted tanks. Chemical ...
The processes controlling total carbon (C) storage and release from the terrestrial biosphere are still poorly quantified. We conclude from analysis of paleodata and climatebiome model output that terrestrial C exchanges since the last glacial maximum (LGM) were dominated by slow processes of C sequestration in soils, possibly modified by C starvation and reduced water use efficiency of trees during the LGM. In contrast, future C cycling will be dominated by human activities, not only from increasing C release with burning of fossil fuels, and but also from indirect effects which increase C storage in the terrestrial biosphere and decrease C storage in the biosphere. Comparison of the positive and negative C flux processes involved suggests that if the C sequestration processes are important, they likely will be so during the next few decades, gradually being counteracted by the C release processes. ...
PUREX high-level waste (HLW) is contained at the West Valley Demonstration Project (WVDP) in an underground carbon-steel storage tank. The HLW consists of a precipitated sludge and an alkaline supernate. This report describes the system that the WVDP has developed and implemented to resuspend and wash the HLW sludge from the tank. The report discusses Sludge Mobilization and Wash System (SMWS) equipment design, installation, and testing. The storage tank required modifications to accommodate the SMWS. These modifications are discussed as well.
As portable electronics become more advanced and alternative energy demands become more prevalent, the development of advanced energy storage technologies is becoming ever more critical in today's society. In order to develop higher power and energy density batteries, innovative electrode materials that provide increased storage capacity, greater rate capabilities, and good cyclability must be developed. Nanostructured materials are gaining increased attention because of their potential to mitigate current electrode limitations. Here we report on the use of vertically aligned multi-walled carbon nanotubes (VA-MWNTs) as the active electrode material in lithium-ion batteries. At low specific currents, these VA-MWNTs have shown high reversible specific capacities (up to 782mAhg^-^1 at 57mAg^-...
In order to investigate pitting corrosion of copper coiled tubes for air conditioning systems with an open heat storage water tank, the effect of carbon films on the inner surface of copper tubes and fine corrosion-product particles in water as environmental corrosion factor on pitting corrosion was studied by field test under real environmental conditions. As a result, pitting corrosion of copper tubes was caused by synergistic effect of fine corrosion-product particles in water and carbon films. Generation of pitting corrosion was derived from deposition of the films and particles, while considerable growth of pitting corrosion was dependent on the particles. Time variation of spontaneous electrode potential also showed the effect of the film and particle. Pitting corrosion potential was estimated to be nearly 100mV vs. SCE. The following measures against pitting corrosion were considered to be effective: (1) Removal of ...
A geologic sequestration pilot in the Thornton gas field in Northern California, USA involves injection of up to 4000 tons of CO{sub 2} into a stacked gas and saline formation reservoir. Lawrence Berkeley National Laboratory (LBNL) is leading the pilot test in collaboration with Rosetta Resources, Inc. and Calpine Corporation under the auspices of the U.S. Department of Energy and California Energy Commission's WESTCARB, Regional Carbon Sequestration Partnership. The goals of the pilot include: (1) Demonstrate the feasibility of CO{sub 2} storage in saline formations representative of major geologic sinks in California; (2) Test the feasibility of Enhanced Gas Recovery associated with the early stages of a CO{sub 2} storage project in a depleting gas field; (3) Obtain site-specific information to improve capacity estimation, risk assessment, and performance prediction; (4) Demonstrate and test methods for ...
The Earth`s oceans, forests, agricultural lands and other natural areas absorb about half of the carbon dioxide emitted from anthropogenic sources. Terrestrial carbon sequestration strategies are immediately available to bridge the gap between current terrestrial sequestration capacity and high-capacity geologic sequestration projects available in 10 to 20 years. Terrestrial carbon sequestration strategies consist of implementing land management practices aimed at decreasing CO2 emitted into the atmosphere and developing advanced measurement tools to inventory and monitor carbon processes in soils and biota. In addition to atmospheric CO2 mitigation and carbon trading advantages, terrestrial carbon sequestration produces a variety of benefits which include reclamation of degraded lands, increased soil productivity, increased land value and a more secure food ...
An efficient method of hydrogen storage in nano-porous carbons is its reversible sorption by electrochemical decomposition of a KOH water solution [1-3] according to the following equation: C + xH{sub 2}O + xe{sup -} {yields} (CH{sub x}) + xOH{sup -} where (CH{sub x}) stands for the hydrogen inserted into the nano-porous carbon during charging and oxidized during discharging. Although various carbon materials have been investigated as hydrogen adsorbents, the information about the storage mechanism as well as the nature of the hydrogen/carbon interaction is still not sufficient. In order to extend the understanding of the process, carbon samples charged electrochemically were investigated by temperature programmed desorpt(TPD). The nature of the hydrogen/carbon interaction was studied by electrochemical analysis at ...
... Carbon capture and storage Waste Prevention and Recycling EU clean air strategy Environmental liability: Applying the 'polluter pays' principle What goes around ...comes around: Recycling and climate change Behind closed doors: Air quality in buildings Keeping cool with refrigerants: The F-gas review Regions fighting climate ...
The objectives of the project were (i) to develop a combination iron oxide production and carbon sequestration plant that will use serpentine ores as the source of iron and the extraction tailings as the storage element for CO2 disposal, (ii) the identification of locations within the US where this process may be implemented and (iii) to create a standardized process to characterize the serpentine deposits in terms of carbon disposal capacity and iron and steel production capacity. The first objective was not accomplished. The research failed to identify a technique to accelerate direct aqueous mineral carbonation, the limiting step in the integration of steel production and carbon sequestration. Objective (ii) was accomplished. It was found that the sequestration potential of the ultramafic resource surfaces in the US and Puerto Rico is approximately 4,647 Gt of CO2 or over 500 ...
During this project we experimentally evaluated the below-ground biomass and carbon allocation and partitioning of four different fast- and slow-growing families of loblolly pine located in Scotland County, NC, in an effort to increase the long-term performance of the crop. The trees were subjected to optimal nutrition and control since planting in 1993. Destructive harvests in 1998 and 2000 were used for whole?plant biomass estimates and to identify possible family differences in carbon acquisition (photosynthesis) and water use efficiency. At regular intervals throughout each year we sampled tissues for carbohydrate analyses to assess differences in whole-tree carbonstorage. Mini rhizotron observation tubes were installed to monitor root system production and turnover. Stable isotope analysis was used to examine possible functional differences in water and nutrient acquisition of root systems between ...
This paper examines the role that carbon dioxide capture and storage technologies could play in reducing greenhouse gas emissions if a significant unconventional fuels industry were to develop within the United States. Specifically, the paper examines the potential emergence of a large scale domestic unconventional fuels industry based on oil shale and coal-to-liquids (CTL) technologies. For both of these domestic heavy hydrocarbon resources, this paper models the growth of domestic production to a capacity of 3 MMB/d by 2050. For the oil shale production case, we model large scale deployment of an in-situ retorting process applied to the Eocene Green River formation of Colorado, Utah, and Wyoming where approximately 75% of the high grade oil shale resources within the United States lies. For the CTL case, we examine a more geographically dispersed coal-based unconventional fuel industry. This paper examines the performance of these industries ...
...Polymer Fuel Cells Challenge Publications News Events Login Register Search Content type All Web pages Case studies Publications News Video Home ...Buildings Carbon capture & storage Combined heat & power Electricity transmission & distribution Energy storage Fuel cells Geothermal Hydroelectric Hydrogen Industry Lighting Marine Metering Nuclear Solar Transport Wind ...Home Emerging technologies Current focus areas Polymer Fuel Cell Challenge Polymer Fuel Cells Challenge The objective of the Polymer Fuel Cells Challenge is to develop,...prove and commercialise novel polymer fuel cell technologies that have the potential to deliver a step-change in overall system cost. What are ...
Basic properties and battery performances of the novel high temperature stable lithium salt (Li{sub 2}B{sub 12}F{sub 12}, Dilithium Dodecafluorododecaborate; Li{sub 2}DFB) were studied using a Mn-based cathode and anode composed of a hard carbon and graphite mixture. The effect of co-solvents (mainly linear carbonate in electrolyte formulation of PC/EC/co-solvent (5/30/65 vol% mixture)) on conductivity, viscosity, charge-discharge capacities, rate performance, temperature performance, cycle life and storage life at 60 C was investigated. Conductivity of Li{sub 2}DFB electrolyte increased with reducing its viscosity by changing co-solvent and increasing the volume of the higher dielectric solvent. Li{sub 2}DFB electrolytes showed comparable discharge capacity and columbic efficiency against LiPF{sub 6} electrolyte. Li{sub 2}DFB electrolytes improved the storage life and cycle life of a Mn-based cell at ...
Gas hydrates have impacted the oil and gas industry since 1934, when they were first found to plug pipelines. Today we know that in deep oceans and in permafrost, very substantial gas reserves are present in hydrated form. Concerns are being raised about in situ dissociation for both energy and greenhouse implications upon methane release. In Japan work is underway to consider the storage of carbon dioxide, concentrated in clathrates. This talk will deal with some basic questions. Why should we be interested in gas hydrates? What are gas hydrates? How do gas hydrates form? How might hydrates impact on the energy/environmental picture?
'Objective of this project is to develop and use Electrochemical Emission Spectroscopy (EES) and other electrochemical techniques as in situ tools for exploring corrosion mechanisms of iron and carbon steel in highly alkaline solutions and for continuously monitoring corrosion on structural materials in DOE liquid waste storage system. In particular, the author will explore the fundamental aspects of the passive behavior of pure iron since breakdown of passivity leads to localized corrosion. This report summarizes work after 1 year of a 3 year project.'
The theme of the conference was 'The paradox: today's coal technologies versus tomorrow's promise'. The sessions covered: today's technologies, tomorrow's potential; economic stability; energy security; transition to sustainable energy future; new coal power technologies leading to zero emission coal; existing power plants - improved performance through use of new technology; and carbon capture and storage R & D - challenges and opportunities. Some of the papers only consist of the viewgraphs/overheads.
The lithium storage properties of graphene nanosheet (GNS) materials as high capacity anode materials for rechargeable lithium secondary batteries (LIB) were investigated. Graphite is a practical anode material used for LIB, because of its capability for reversible lithium ion intercalation in the layered crystals, and the structural similarities of GNS to graphite may provide another type of intercalation anode compound. While the accommodation of lithium in these layered compounds is influenced by the layer spacing between the graphene nanosheets, control of the intergraphene sheet distance through interacting molecules such as carbon nanotubes (CNT) or fullerenes (C60) might be crucial for enhancement of the storage capacity. The specific capacity of GNS was found to be 540 mAh/g, which is much larger than that of graphite, and this was increased up to 730 mAh/g and 784 mAh/g, respectively, by the incorporation of ...
This proceedings volume comprises 17 papers on the following subjects: Methane hydrates, compounds of gas and water; Compressed air stroage gas turbine power plants / Scheduled application for load levelling between varying wind power production and power demand; Modern pumped storage power stations in the GW range - the PSW Goldisthal example; Lead batteries - new developments and future applications; Alkaline battery systems for hybrid electric road vehicles; Lighium systems and their applications; Zinc/air cells; Hydrogen storage - metal hydride storage, compressed gas storage, LNG storage; Carbon nanofibres for hydrogen storage; Double-layer condensers - technology, cost, perslpectives; Supercondensers in motor vehicles; Superconducting magnetic energy stores; Flywheel storage - status report; Decentralized energy ...
The world's 500 million road vehicles using internal combustion engines account for roughly half of global oil consumption and, in Italy, for about 50% of all nitrogen oxide and 90% of carbon monoxide emissions. In efforts to conserve petroleum reserves and reduce air pollution, research programs are being conducted to develop hydrogen fueled automotive engines. Hydrogen combustion products are carbon dioxide free, and when burned with a large excess of air, this fuel produces water vapour and only small amounts of nitrogen oxides. Hydrogen fueled vehicles can be made to operate in a dual fuel mode so as to allow the use of petrol or diesel fuel in travel over long distances. Currently, because technical and economic difficulties relevant to hydrogen fuel storage limit driving range and payload (there are bulk and weight problems in compressed gas and metal hydride storage systems, and cost problems in ...
In this study the greenhouse impact of the total Finnish forest sector was considered, which means that the estimated emissions and sink effects from exported forest products were also included. The forest biomass is and seems to be in the next decades the most important factor in the carbon balance of the total forest sector. The development alternatives of forest industries and waste management practices has still a remarkable influence on the greenhouse impact of the Finnish forest sector. The waste management practices in the future has an important influence on the emissions but the exact net greenhouse impact of the landfills is still uncertain. However, the methane emissions from existing landfills can be reduced essentially by gas recovery. Increased incineration and energy recovery of wood waste (and replacing fossil fuel use by it) is also a future alternative for reducing the greenhouse effects in the forest sector. The sequestration of ...
The working hypothesis of the research was that the soil of boreal forests is a large carbon store and the amount of C is still increasing in young soils, like in the forest soils of Finland, which makes these soils important sinks for atmospheric CO{sub 2}. Since the processes defining the soil C balance, primary production of plants and decomposition, are dependent on environmental factors and site properties, it was assumed that the organic carbon pool in the soil is also dependent on the same factors. The soil C store is therefore likely to change in response to climatic warming. The aim of this research was to estimate the C balance of forest soil in Finland and predict changes in the balance in response to changes in climatic conditions. To achieve the aim (1) intensive empirical experimentation on the density of C in different pools in the soil and on fluxes between the pools was done was done, (2) the effect of site fertility and ...
The technology based portion of the Advanced Turbine Systems Program (ATS) contains several subelements which address generic technology issues for land-based gas-turbine systems. One subelement is the Materials/ Manufacturing Technology Program which is coordinated by DOE Oak Ridge Operations and Oak Ridge National Laboratory (ORNL). The work in this subelement is being performed predominantly by industry with assistance from universities and the national laboratories. Projects in this sub-element are aimed toward hastening the incorporation of new materials and components in gas turbines.
The results of the 2006 investigation of contaminant sources at Navarre, Kansas, clearly demonstrate the following: {sm_bullet} Sources of carbon tetrachloride contamination were found on the Navarre Co-op property. These sources are the locations of the highest concentrations of carbon tetrachloride found in soil and groundwater at Navarre. The ongoing groundwater contamination at Navarre originates from these sources. {sm_bullet} The sources on the Co-op property are in locations where the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) never conducted grain storage operations. {sm_bullet} No definitive sources of carbon tetrachloride were identified on the portion of the current Co-op property formerly used by the CCC/USDA. {sm_bullet} The source areas on the Co-op property are consistent with the locations of the most intense Co-op operations, both historically and at ...
The present study includes thermal stability of some fatty acids as phase change materials (PCMs). The selected fatty acids were stearic, palmitic, myristic and lauric acid with melting temperatures between 40-63{sup o}C and industrial-grade with 90-95% purity. Latent heat storage capacity and phase transition temperature of the PCMs were determined by Differential Scanning Calorimetry (DSC) technique as a function of after repeated thermal cycles such as 40, 410, 700 and 910. The present work also comprises the investigation of corrosion resistance of some construction materials to the fatty acids over a long period. The containment materials tested were stainless steel (SS 304 L), carbon steel (steel C20), aluminium (Al) and copper (Cu). Gravimetric analysis as mass loss (mg/cm{sup 2}), corrosion rate (mg/day) and a microscopic or metallographic investigation were performed for corrosion tests after 910 thermal cycles. DSC measurements showed ...
This report summarizes preliminary 2-D reactive-transport simulations on the injection, storage and transport of supercritical CO{sub 2} in dolostone formations in the Ordos Basin in China. The purpose of the simulations was to evaluate the role that basin heterogeneity, permeability, CO{sub 2} flux, and geochemical reactions between the carbonate geology and the CO{sub 2} equilibrated brines have on the evolution of porosity and permeability in the storage reservoir. The 2-D simulation of CO{sub 2} injection at 10{sup 3} ton/year corresponds to CO{sub 2} injection at a rate of 3 x 10{sup 5} ton/year in a 3-D, low permeable rock. An average permeability of 10 md was used in the simulation and reflects the upper range of permeability reported for the Ordos Basin Majiagou Group. Transport and distribution of CO{sub 2} between in the gas, aqueous, and solid phases were followed during a 10-year injection phase and a 10-year ...
Geological carbon dioxide capture and storage (CCS) is currently seriously considered for addressing, in the near term, the problem of climate change. CCS technology is available today and is expected to become an increasingly affordable CO2 abatement alternative. Whereas the rapidly growing scientific literature on CCS as well as experimental and commercial practice demonstrate the technological and economic feasibility of implementing this clean fossil fuel option on a large scale, relatively little attention has been paid so far to the risks and environmental externalities of geological storage of CO2. This paper assesses the effects of including CCS damage costs in a long-term energy scenario analysis for Europe. An external cost sensitivity analysis is performed with a bottom-up energy technology model that accounts not only for CCS technologies but also for their external costs. Our main conclusion is that in a ...
In Romania, the nuclear power is an element of sustainable development, being competitive, efficient and viable in the market economy. Fuel supply is ensured as nuclear fuel is manufactured in the country out of local uranium resources available in Romania. As for the environmental protection, it is known that, unlike the thermal power plants, the nuclear power plants do not release sulfur and nitrogen oxides, carbon dioxide and do not generate slag and ashes. The operation of nuclear power units does not release pollutants and, accordingly, these stations can contribute to the limitation and the abatement of environmental pollution. After seven years of Cernavoda NPP Unit 1 operation, a facility for storing low and medium level nuclear fuel wastes was built at the plant site as well as an intermediate dry storage for spent nuclear fuel whose first modules were commissioned in July 2003. They shall provide safe storage ...
A general analysis is presented of a photon storage cavity, coupled to free-electron laser (FEL) cavity. It is shown that if the coupling between the FEL cavity and the storage cavity is unidirectional (for example, a ring resonator storage cavity) then storage is possible, but that if the coupling is bi-directional then storage is not possible. Parameters are presented for an infra-red FEL storage cavity giving an order of magnitude increase in the instantaneous photon power within the storage cavity. 4 refs., 3 figs.
Recently, it has become clear that the chemical circumstances under which long-term geological evolution occurs must be properly evaluated in order to develop effective remediation programs for contaminated soil, landfills, radioactive waste repositories, and carbon dioxide capture and storage. The issue of acidic leakage from excavated rock stuck was assessed using a hydro-geochemical simulator, TOUGHREACT. We concluded that in order to properly investigate the phenomenon of acidic leakage from excavated pyrite-containing rock stuck, it is important to obtain accurate information about the following factors: intensity of rainfall, unsaturated flow properties of the excavated rock stuck, specific surfaces for oxidation reaction of pyrite, the species and the quantity of other minerals contained in the rock, and secondary minerals produced. (author)
A controlled field pilot has been developed in Bozeman, Montana, USA, to study near surface CO2 transport and detection technologies. A slotted horizontal well divided into six zones was installed in the shallow subsurface. The scale and CO2 release rates were chosen to be relevant to developing monitoring strategies for geological carbonstorage. The field site was characterized before injection, and CO2 transport and concentrations in saturated soil and the vadose zone were modeled. Controlled releases of CO2 from the horizontal well were performed in the summers of 2007 and 2008, and collaborators from six national labs, three universities, and the U.S. Geological Survey investigated movement of CO2 through the soil, water, plants, and air with a wide range of near surface detection techniques. An overview of these results will be presented.
Precious metal (PM) dispersions on CeO{sub 2}-containing supports were examined. When dispersions were evaluated by the H{sub 2}-O{sub 2} titration method, the CeO{sub 2}-containing supports hide the true redox of PM because of the large oxygen storage-reduction capacity of the oxide, resulting in higher apparent dispersions than the exact values. When Pt dispersions on the CeO{sub 2} support were evaluated by the ordinary CO pulse method, CO was adsorbed on the CeO{sub 2} support as carbonate species accompanying the oxidation with lattice oxygen. Therefore, the dispersions estimated from the CO uptake were also higher than the exact value. Infrared spectra also clearly evidenced the presence of carbonate species after CO adsorption. To prevent the CO adsorption on CeO{sub 2} as the carbonate species, we treated Pt/CeO{sub 2} with CO{sub 2} before CO adsorption. The strong bands arising from ...
The significant and rapid reduction of greenhouse gas emissions is recognized as necessary to mitigate the potential climate effects from global warming. The postcombustion capture (PCC) and storage of carbon dioxide (CO{sub 2}) produced from the use of fossil fuels for electricity generation is a key technology needed to achieve these reductions. The most mature technology for CO{sub 2} capture is reversible chemical absorption into an aqueous amine solution. In this study the results from measurements of the CO{sub 2} absorption capacity of aqueous amine solutions for 76 different amines are presented. Measurements were made using both a novel isothermal gravimetric analysis (IGA) method and a traditional absorption apparatus. Seven amines, consisting of one primary, three secondary, and three tertiary amines, were identified as exhibiting outstanding absorption capacities. Most have a number of structural features in common including steric ...
Large scale steam storage power generation, one of the new energy storage systems for the future of inflexible electric power sources consisting of nuclear and coal power plants has been studied on the subjects of the systems to be attached to coal and nuclear power units, of the definition of storage efficiency and of the vertical steam storage vessel technology. Steam storage power generation may be hopeful for its higher efficiency similarly defined as of pumped storage plants while high temperature heat storage and the internal structure of large vertical steam storage vessel (accumulator) need to be developed.
Large scale steam storage power generation, one of the new energy storage systems for the future of inflexible electric power sources consisting of nuclear and coal power plants has been studied on the subjects of the systems to be attached to coal and nuclear power units, of the definition of storage efficiency and of the vertical steam storage vessel technology. Steam storage power generation may be hopeful for its higher efficiency similarly defined as of pumped storage plants while high temperature heat storage and the internal structure of large vertical steam storage vessel (accumulator) need to be developed. (author).
Stochastic models for the simulation of global radiation are discussed. Thermal transients in the ground are analyzed. The performance of buried-pipe storage and a space heating system with long-term storage is described.
This paper assesses the effects of including carbon dioxide capture and storage (CCS) damage costs in a long-term energy scenario analysis for Europe. An external cost sensitivity analysis is performed with a bottom-up energy technology model that accounts not only for CCS technologies but also for their external costs. Our main conclusion is that in a business-as-usual scenario (i.e. without climate change intervention or externality internalisation), CCS technologies are likely to be deployed at least to some extent, mainly in the power generation sector, given the economic benefits of opportunities such as enhanced coal bed methane, oil and gas recovery. Under a strict climate (CO{sub 2} emissions) constraint, CCS technologies are deployed massively. With the simultaneous introduction of both CO{sub 2} and CCS taxation in the power sector, designed to internalise the external atmospheric and geological effects of CO{sub 2} emissions and ...
Storage proteins are deposited into protein storage vacuoles (PSVs) during plant seed development and maturation and stably accumulate to high levels; subsequently, during germination the storage...Full Text Available
The impact of increasing atmospheric C0{sub 2} has not been fully evaluated on western coniferous forest species. Two year old seedlings of Pinusponderosa were grown in environmentally controlled chambers under increased C0{sub 2} conditions for 6 months. These trees exhibit morphological, physiological, and biochemical alterations when compared to our controls. Analysis of whole plant biomass distribution has shown no significant effect to the root to shoot ratios, however needles subjected to elevated C0{sub 2} exhibited an increased overall specific needle mass and a decreased total needle area. Morphological changes at the needle level included decreased mesophyll to vascular tissue 91 ratio and variations in starch storage in chloroplasts. The elevated CO{sub 2} increased internal CO{sub 2} concentrations and assimilation of carbon. Biochemical assays revealed that ribulose-bisphosphate carboxylase specific activities increased on per unit ...
Nuclear Reaction Analysis (NRA) with deuteron ion beams has been used to probe for ion implanted nitrogen and carbon with high sensitivity in zinc oxide and silicon single crystals. The ion implanted N was measured using 1.4 MeV deuteron ion beams and was found to be in agreement with calculated values. The limit of detection for N in ZnO is 8x1014 ions cm-2. Raman measurements of the ion implanted samples showed three additional modes at 275, 504, and 644 cm-1 compared to the un-implanted ZnO crystals. The NRA and Raman results provided information on the N concentration, depth distribution, and structural changes that occur in dependence on the nitrogen ion fluences. The deuterium induced 12C(d,p)13C reaction was used to measure the carbon impurity/dose in ion implanted silicon. It was found that the use of a large cold shield (liquid nitrogen trap) in the ion implanter chamber greatly reduces the amount of carbon ...
Plans for the disposal of radioactive liquid and solid wastes presently stored in double-shell tanks at the Hanford Site call for retrieval and processing of the waste to create forms suitable for permanent disposal. Waste will be retrieved from a tank using a submerged slurry pump in conjunction with one or more rotating slurry jet mixer pumps. Pacific Northwest Laboratory (PNL) has conducted tests using simulated waste slurries to assess the effects of a impinging slurry jet on the corrosion rate of the tank wall and floor, an action that could potentially compromise the tank's structural integrity. Corrosion processes were investigated on a laboratory scale with a simulated neutralized cladding removal waste (NCRW) slurry and in a subsequent test with simulated neutralized current acid waste (NCAW) slurry. The test slurries simulated the actual NCRW and NCAW both chemically and physically. The tests simulated those conditions expected to exist in the respective double-shell ...
Plans for the disposal of radioactive liquid and solid wastes presently stored in double-shell tanks at the Hanford Site call for retrieval and processing of the waste to create forms suitable for permanent disposal. Waste will be retrieved from a tank using a submerged slurry pump in conjunction with one or more rotating slurry jet mixer pumps. Pacific Northwest Laboratory (PNL) has conducted tests using simulated waste slurries to assess the effects of a impinging slurry jet on the corrosion rate of the tank wall and floor, an action that could potentially compromise the tank`s structural integrity. Corrosion processes were investigated on a laboratory scale with a simulated neutralized cladding removal waste (NCRW) slurry and in a subsequent test with simulated neutralized current acid waste (NCAW) slurry. The test slurries simulated the actual NCRW and NCAW both chemically and physically. The tests simulated those conditions expected to exist in the respective double-shell tanks ...
This document presents a conceptual design for a contingency interim measure (IM) for treatment of the public water supply system at Barnes, Kansas, should this become necessary. The aquifer that serves the public water supply system at Barnes has been affected by trace to low concentrations of carbon tetrachloride and its degradation product, chloroform. Investigations conducted on behalf of the CCC/USDA by Argonne National Laboratory (Argonne 2008a) have demonstrated that groundwater at the Barnes site is contaminated with carbon tetrachloride at concentrations exceeding the Kansas Tier 2 risk-based screening level (RBSL) and the EPA maximum contaminant level (MCL) of 5.0 {micro}g/L for this compound. The Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) formerly operated a grain storage facility in Barnes, approximately 800 ft east-southeast of the public water supply wells. ...
It is necessary to establish scenarios for reducing CO2 emissions and for developing CO2 emission control technologies to obtain a global consensus, using appropriate analytical models. For modification of the DNE-21 (Dynamic New Earth 21) model, it has a category designated as innovative technologies not involving CO2 emission and an optional consideration for the absorption of atmospheric CO2 by biomass. A global carbon circulation model, including vegetation in its scope, is also incorporated. Major results of the simulation are shown. When 20% reduction in CO2 emissions is required for only OECD countries after the year 2020, it has been demonstrated that CO2 concentration in the atmosphere will reach as high as about 900 ppm in 2100 due to CO2 emission by developing countries, and will not be a tolerable level. Under the condition that CO2 concentration in the atmosphere is controlled at 450 ppm in 2100, the amount of renewable source of energy from ...
This is the final report of a two-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project has examined the fundamental chemistry of plutonium that affects the integration of hydrothermal technology into nuclear materials processing operations. Chemical reactions in high temperature water allow new avenues for waste treatment and radionuclide separation.Successful implementation of hydrothermal technology offers the potential to effective treat many types of radioactive waste, reduce the storage hazards and disposal costs, and minimize the generation of secondary waste streams. The focus has been on the chemistry of plutonium(VI) in solution with carbonate since these are expected to be important species in the effluent from hydrothermal oxidation of Pu-containing organic wastes. The authors investigated the structure, solubility, and stability of the key plutonium complexes. ...
British Columbia-based Carmanah Technologies is a world leader in the design, manufacture and supply of patented solar-powered light emitting diode (LED) lighting solutions. As a leading alternative energy manufacturer, it was the first company to integrate LEDs with solar chargers and battery power storage. Carmanah products have high-end assembly, minimal size, maximized performance and field-proven reliability. The products have been used in public transit applications, roadway lighting, and for general aviation lighting solutions. In 2004, their products saved the equivalent of 6,705 metric tonnes of carbon dioxide. This annual report includes information on the company's net earnings and investor profiles. The company has large markets for its products with little competition. It has a strong management team and its funding places it in a position to capitalize on current and emerging technologies. The company's energy resource activities ...
Small economies such as New Zealand risk significant economic hardship without careful evaluation of alternatives to petroleum-based transportation due to the adverse effects of climate change and depleting international oil reserves. This paper uses an integrated multi-regional multi-fleet system dynamics model of New Zealand's energy economy to assess the primary impacts of alternative vehicle fleet technologies. Results suggest that hydrogen fuelled HICEs and FCVs may offer significantly greater economic savings than BEVs due to a much lower capital cost. Under our Base Case, 65% of the light fleet are HICEs and FCVs and 5% BEVs. Excluding hydrogen vehicles from the vehicle fleet can result in an average annual cost of US$562 per vehicle between 2015 and 2050. Co-production of hydrogen and electricity using coal gasification with carbon capture and storage is the dominant long term hydrogen production technology. (author)
In this article, we review and clarify some of the points made by previous authors regarding chemical looping combustion (CLC). While much of the recent interest in chemical looping combustion has been associated with carbon sequestration, our primary interest here is its potential to increase the thermodynamic efficiency of converting fuel chemical energy into useful work. We expand on several points about the details of CLC that we feel have not previously been sufficiently explored, and suggest alternative (and possibly more practical) approaches that exploit some of the same thermodynamic concepts. We illustrate our key points with {First} and {Second} Law analyses of ideal conceptual processes, which in addition to {CLC} also include isothermal, non-equilibrium, preheated combustion and combustion with thermochemical recuperation. Our results suggest that a significant portion of the potential efficiency benefit of CLC might be achieved without the need to ...
A growing number of pumped storage plants installed within the US brings attention to the increasing significance of pumped storage as a source of electrical generation capacity. Because of the special benefits this technology has to offer, hydroelectric pumped storage is an option that many utilities should consider for the supply of new capacity requirements. This article surveys the development and use of pumped storage in the US, and considers the potential for the future development of this technology. Although some of the problems that have occurred on recent projects highlight the role of pumped storage as a technological proving ground, the article puts forth the view that pumped storage is maturing to play a significant role in US electricity supply.
Off-grid power generation is meant to supply remote or rural area, where grid connection is almost impossible in terms of cost and geography, such as island, aborigine's villages, and areas where nature preservation is concern. Harnessing an abundance renewable energy sources using versatile hybrid power systems can offer the best, least-cost alternative solution for extending modern energy services to remote and isolated communities. The conventional method for off-grid power generation is using diesel generator with a renewable energy (RE) technology utilizing solar photovoltaic, wind, biomass, biogas and/or mini/micro hydro. A hybrid technology is a combination of multiple source of energy; such as RE and diesel generator and may also include energy storage such as battery. In our design, the concept of solar hybrid system is a combination of solar with diesel genset and battery as an energy storage. The main objective of the system are to ...
The set of activities performed by SENTECH, Inc. addressed the specific recommendations provided to the Department of Energy (DOE) by its advisors, including the Hydrogen Technical Advisory Panel and the review panel members of the DOE Annual Hydrogen Program Review. SENTECH`s efforts were conducted under five tasks: Task 1: Technology and Process Analysis; Task 2: Hydrogen Information Development and Transfer; Task 3: Educational Products; Task 4: Systems Analysis; and Task 5: Life Cycle Costs. SENTECH activities were executed in two broad areas--analysis and technology transfer. The analytical tasks undertaken in FY97 were focused on two types of analysis--systems analysis and technical/economic assessments. These analytical activities benefit DOE by providing data that allow it to define the strategic goals of the hydrogen R and D program. By collecting analysis of the energy efficiency, environmental externality, and economic competitiveness factors of hydrogen energy systems, DOE ...
The electrochemical capacitor devices described in this report were deliverables from the US Department of Energy--Idaho Operations Office (DOE-ID) Contract No. DE-AC07-92ID13404 as part of the US Department of Energy`s (DOE) High Power Energy Storage Program. The Idaho national Engineering and Environmental Laboratory (INEEL) has responsibility for technical management, testing, and evaluation of high-power batteries and electrochemical capacitors under this Program. The DOE has developed various electrochemical capacitors as candidate power assist devices for the Partnership for a New Generation of Vehicles (PNGV) fast response engine requirement. This contract with Maxwell Energy Products, Inc. (Maxwell) was intended to develop a high-energy-density, high-power-density ultracapacitor that is capable of load leveling batteries in electric vehicles. The performance criteria for this device are delivery of 5 W {center_dot} h/kg of useful energy that can be used by ...
This report describes the state of the art of electric energy storage technologies and discusses how adding intermittent renewable energy technologies (IRETs) to a utility network affects the benefits from storage dispatch. Load leveling was the mode of storage dispatch examined in the study. However, the report recommended that other modes be examined in the future for kilowatt and kilowatt-hour optimization of storage. The motivation to install storage with IRET generation can arise from two considerations: reliability and enhancement of the value of energy. Because adding storage increases cost, reliability-related storage is attractive only if the accruing benefits exceed the cost of storage installation. The study revealed that the operation of storage should not be guided by the output of the ...
The 200 Area Interim Storage Area Technical Safety Requirements define administrative controls and design features required to ensure safe operation during receipt and storage of canisters containing spent nuclear fuel. This document is based on the 200 Area Interim Storage Area, Annex D, Final Safety Analysis Report which contains information specific to the 200 Area Interim Storage Area.
Silicon is an attractive alloy-type anode material because of its highest known capacity (4200 mAh/g). However, lithium insertion into and extraction from silicon are accompanied by a huge volume change, up to 300%, which induces a strong strain on silicon and causes pulverization and rapid capacity fading due to the loss of the electrical contact between part of silicon and current collector. Si nanostructures such as nanowires, which are chemically and electrically bonded to the current collector, can overcome the pulverization problem, however, the heavy metal current collectors in these systems are larger in weight than Si active material. Herein we report a novel anode structure free of heavy metal current collectors by integrating a flexible, conductive carbon nanotube (CNT) network into a Si anode. The composite film is free-standing and has a structure similar to the steel bar reinforced concrete, where the infiltrated CNT network functions as both ...
This presentation gives the results of a research programme aimed at evaluating exhaust emissions from ships moving within confined coastal zones, as in Piraeus harbour. The level of various exhaust emissions were estimated on the basis of a mathematical model applied for each sea traffic element (ship). Hourly and daily records of all ships` movements in different parts of the harbour were compiled, covering extended periods of time and associated with different shipping operational characteristics (peaks, lows, etc). In order to correlate the exhaust emissions from shipping with the quality of the air in the area of interest, land-based measurements for the same pollutants were carried out in selected locations, near the port and in the greater Athens area. This enabled the investigation of time and spatial diffusion of exhaust emissions from shipping within the area of interest, taking into account the influence of prevailing meteorological conditions. A close ...
A definition is given for the basic national economic task of developing the recovery of hydrocarbons from bitumen-containing rock and oil shales, and a description is given of the status of the mineral-raw material base. General concepts are given on bitumens and oil shale. Their elemental and group compositions are cited in detail, and a determination is made of the position they occupy in the total system of fossil fuels. An examination is made of data on the distribution and state of bitumen and oil shale resources, and a description is given of their principal deposits. An evaluation is made of gained experience and the potential of existing methods of working bituminous rock and oil shale deposits that include the use of available and utilized method of land-based, underground, and instrastratal extraction of petroleum from those deposits. A presentation is made of the technical-economic aspects of producing bituminous and shale oils. The book is intended for ...
The paper discusses the safety problems connected with the conversion to dense storage of RBMK-1000 spent fuel in reactor cooling pools and independent storage facilities. Recourse to dense storage has been made for a number of reasons, among which are the absence of spent fuel shipments from the nuclear power plant site, prolongation of storage time and a partial change in storage conditions. Increasing the storage density per unit volume of the storage facility and turning to new technical procedures (as against the basic design) call for further investigation of safety problems. The safety assessment of the dense storage mode includes: (1) Selecting a list of initiating events for design basis and unforeseeable accidents; (2) Assessing dense storage safety under normal as well as design basis ...
The question of whether storage of red blood cells (RBCs) alters their capacity to deliver oxygen and affects patient outcomes remains in a state of clinical equipoise. Studies of the changes...Full Text Available
Heat-of-fusion storage materials for low temperature latent heat storage in the temperature range 0-120 C are reviewed. Organic and inorganic heat storage materials classified as paraffins, fatty acids, inorganic salt hydrates and eutectic compounds are considered. The melting and freezing behavior of the various substances is investigated using the techniques of Thermal Analysis and Differential Scanning Calorimetry. The importance of thermal cycling tests for establishing the long-term stability of the storage materials is discussed. Finally, some data pertaining to the corrosion compatibility of heat-of-fusion substances with conventional materials of construction is presented.
The paper deals with the exploitation of the pumped storage plants for the control of the Slovak power system. For that purpose current utilization of pumped storage plants currently in operation was analyzed from the point of view of their part in the operation control of the Slovak power system. The aim of this analysis was to exploit knowledge gained so far for the future outlook up to the year 2010, including the evaluation of the need to construct pumped storage plant Ipel with a weekly storage cycle. (author).
The advantages of using heads of around 1000 m in conjunction with underground location of the lower reservoirs for pumped storage plants are described, and the possible layouts, equipment, and construction methods are discussed.
The protocols presently established for optimum seed storage do not account for the chemical composition of different seed species, the physiological status of the seed, and the physical status of water...Full Text Available
Hydrogen seems to possess all the characteristics to store the excess of electrical energy produced during off-peak periods. Hydrogen energy storage plants could be environmentally non-polluting, easy to place, not sensible to load variation, unbounded in size, efficient and safe. These last two features seem to contradict one another. An option that could give a reliable solution is the storage of hydrogen in metal hydride and the storage of oxygen as a liquid. Such a choice is probably the safest one to make and allows the achievement of efficiencies comparable to those obtainable with gaseous storage of both electrolytic products. The power consumption for H{sub 2} and O{sub 2} storage is only 3% of the total energy stored and the charging ratio approaches the values obtained with hydro-pumped storage plants. (Author)
OBJECTIVE: To determine the household prevalence of firearms in Pennsylvania, and describe the storage practices for these weapons. DESIGN: A statewide telephone survey of 3,620 Pennsylvania adults...Full Text Available
A study was undertaken to assess the effect of different storage temperatures on senescence and postharvest performance of isolated flowers of Ranunculus asiaticus L.. The main aim of the work was to develop a cost-effective storage protocol to reduce the postharvest losses and to bring out the transportation of cut flowers of R. Asiaticus. The flowers were subjected to two different storage treatments, dry storage and wet storage, and their postharvest performance was compared under laboratory conditions. For this purpose, the buds were harvested at 8:00 AM at loose bud stage (Stage II of flower development). The harvested buds were cut to a uniform size of 15 cm and processed for dry or wet storage. For dry storage, the buds were packed after wrapping them in moistened filter papers and ...
This layer represents the different food storage facilities available at backcountry campsites along the coast of Kenai Fjords National Park. Site locations ... ...
This paper reports on hydroelectric pumped storage which is the only proven and most efficient technology available for energy storage. It is used by utilities to provide peak and intermediate power and to optimize overall system performance. Because of increased environmental and regulatory constraints, few acceptable sites, long schedules, and huge financial commitments, large conventional pumped storage plants, are now virtually impossible to build. As an alternative, small modular pumped storage, with project sizes ranging from 25 MW to 200 MW, was created to overcome the difficulties of conventional projects. The modular approach involves standardizing the elements of a pumped storage plant by utilizing specialized siting techniques and optimizing design, equipment, and construction. Compared with conventional pumped storage, the modular design can reduce ...
The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, efforts have focused on the facility modifications for continuous hydrotreating, as well as developing improved protocols for producing synthetic pitches.
Scenarios are developed for spent fuel that is taken out of the nuclear reactor and stored for 20 years before reprocessing, and three storage techniques which use a water pool, dry cask or vault are compared with respect to their costs. The storage price (storage cost per kilogram of spent fuel), which is employed as the economic index, is calculated on the assumption that all the charge is paid when the spent fuel is brought in the storage facilities. Four scenarios are assumed for spent PWR and BWR fuels to be stored in at-reactor (AT) or away-from-reactor (AFR) facilities. The capital costs cover the buildings of the storage facilities, equipment, decommissioning, casks for transportation and storage (for cask storage) and casks for transportation (for water pool or vault storage). Costs for operation and maintenance ...
Scenarios are developed for spent fuel that is taken out of the nuclear reactor and stored for 20 years before reprocessing, and three storage techniques which use a water pool, dry cask or vault are compared with respect to their costs. The storage price (storage cost per kilogram of spent fuel), which is employed as the economic index, is calculated on the assumption that all the charge is paid when the spent fuel is brought in the storage facilities. Four scenarios are assumed for spent PWR and BWR fuels to be stored in at-reactor (AT) or away-from-reactor (AFR) facilities. The capital costs cover the buildings of the storage facilities, equipment, decommissioning, casks for transportation and storage (for cask storage) and casks for transportation (for water pool or vault storage). Costs for operation and maintenance ...
Geologic sequestration is currently being practiced and scientifically evaluated as a critical component in a broad strategy, comprising new practices and technologies, for mitigating global climate change due to anthropogenic emissions of CO2. Demonstrating that geologic sequestration of CO2 is safe and effective, and gaining public acceptance of sequestration technologies are critically important in meeting these global climate change challenges. Monitored field-scale demonstrations of geologic sequestration of carbon dioxide will contribute greatly toward growing trust and confidence in the technology; however, pilot demonstrations ultimately will not be the norm for new geological sequestration deployments. Instead, scientists, engineers, regulators, and ultimately the public will rely on numerical simulations to predict the performance of geologic repositories for carbon dioxide sequestration. The U.S. Department of Energy (DOE), through ...
Carbon capture and storage have been receiving increasing interest lately, mainly as an option to reduce CO{sub 2} emissions from the power sector. The concept could be adapted for production of H{sub 2} as well, which would provide a carbon free energy carrier that could be used for example as transportation fuel. In this doctoral thesis, the option to use chemical-looping technologies to produce H{sub 2} from fossil fuels with CO{sub 2} capture is explored. In chemical-looping combustion, direct contact between fuel and combustion air is avoided. Instead, a solid oxygen carrier performs the task of bringing oxygen from the air to the fuel. Thus, the resulting CO{sub 2} and H{sub 2}O are not diluted with N{sub 2}, and pure CO{sub 2} can easily be recovered by cooling and condensation. The heat of reaction is the same as for ordinary combustion. Chemical-looping reforming uses the same basic principles as chemical-looping ...
Rice (Oryza sativa) seed storage proteins (SSPs) are synthesized and deposited in storage organelles in the endosperm during seed maturation as a nitrogen source for germinating seedlings....Full Text Available
Sandia National Laboratories, New Mexico, conducts the Energy Storage Systems Program, which is sponsored by the US Department of Energy`s Office of Utility Technologies. The goal of this program is to assist industry in developing cost-effective energy storage systems as a resource option by 2000. Sandia is responsible for the engineering analyses, contracted development, and testing of energy storage systems for stationary applications. This report details the technical achievements realized during fiscal year 1996.
The concept of preliminary transmutation of minor actinides before placement to the long-term storage is considered. The purpose of such preliminary transmutation before ultimate storage is to incinerate a part of actinides and to transform another part into new actinides providing low level of radiotoxicity accumulated in the storage. Modes of transmutation in reactors of PWR, PHWR (CANDU), and Superfenix types are compared. Among power reactors, heavy-water PHWR type reactor is most acceptable for preliminary transmutation. (author)
A novel approach to the reliability analysis of a power system with both hydro and pumped storage plants is presented in this paper. The proposed method is based on the concept of peak shaving for the hydro and pumped storage units. Different values of the stored energy of the pumped storage units are employed to demonstrate their effect on the generation reliability of a power system. The proposed scheme has been applied successfully to the reliability analysis of Taiwan power system.
The carbon cycle is an important part of major biogeochemical cycles. Many techniques may be used to characterize carbon amounts and sources in the environment. Here we first review the most popular techniques for the determination of organic and inorganic carbon concentrations. Decarbonatation techniques are also reviewed in details since it is often an important part of organic carbon analysis. The second part of this paper addresses the use of carbon stable isotopes to characterize organic carbon sources and processes in the environment. An overview of general stable isotopes background and terminology is given as well as the most popular analytical techniques.
The electrolyte was brought into contact with air and potassium carbonate was measured with various contact time in order to check the defect of carbon dioxide in the air on zinc-air cell. The relationship between potassium carbonate concentration in electrolyte and battery capacity was also studied. The potassium carbonate concentration in the electrolyte. The rate of carbon dioxide absorption was mainly affected by the pore size of hydrophobic membrane. Our study showed that adapting the pore of hydrophobic membrane decreased the loss of cell discharge performance due to the presence of carbon dioxide or water vapor in the atmosphere. 7 refs., 12 figs., 1 tab.
This paper discussed issues related to the storage of electricity produced from renewable energy sources. Storage systems currently used by distribution systems were reviewed. The study showed that successful storage systems ensure high charging and discharging rates for shorter periods of time. Systems with high storage capacities must also be able to store energy for longer periods of time than traditional energy storage systems. Systems include pumped storage plants; electro-chemical accumulators; compressed air accumulators; and redox flow batteries. Hydrogen technologies for the storage of electric energy from renewable sources were reviewed. The paper also outlined energy storage and fuel cell research currently being conducted by researchers in the Czech Republic. The study concluded by stating that new energy ...
The general types of pumped-storage plants and considerations for determining their need, use, and selection are presented. A brief discussion of TVA's experience on two pumped-storage schemes is included. Pumped-storage plants have become an integral part of many hydropower systems. Most of these systems use pumped-storage plants to meet power requirements during the peak load demands. In any application, large or small, the expected load demand and supply source must be identified to select the best scheme required for the particular system.
Pumped storage plants (PSP) enable the storage of energy with rated capacities of order of GW at a single site. Reservoirs allow charging and discharging times of at least hours, sometimes days or even up to several weeks. Short ramp-up times permit the participation in the secondary reserve market as a standing reserve. For bulk energy storage, PSP reach the lowest, specific costs. In the EU27 countries, Norway and Switzerland, a total of 44 GW of pumped storage capacity is installed. The utilisation of PSP strongly correlates with the amount of conventional generation capacity, rather than with topographical options. (orig.)
This paper presents a new algorithm for the optimal long-range generation planning for a thermal system with pumped-storage plants. The algorithm is based upon the analytical production costing model developed under the assumption of Gaussian probabilistic distribution of random load fluctuations and plant outages. The optimization problem consists of the master problem to determine the annual investment, and the pumped-storage subproblem to determine the optimal pumped-storage operation. The master problem is formulated as a Hamiltonian minimization problem, and the pumped-storage subproblem is solved using the concept of peak-shaving operation on the original load curve.
This paper presents a new algorithm for the optimal long-range generation planning for a thermal system with pumped-storage plants. The algorithm is based upon the analytical production costing model developed under the assumption of Gaussian probabilistic distribution of random load fluctuations and plant outages. The optimization problem consists of the master problem to determine the annual investment, and the pumped-storage subproblem to determine the optimal pumped-storage operation. The master problem is formulated as a Hamiltonian minimization problem, and the pumped-storage subproblem is solved using the concept of peak-shaving operation on the original load curve.
The National Energy Modeling System (NEMS) developed by the U.S. Department of Energy`s Energy Information Administration is a well-recognized model that is used to project the potential impact of new electric generation technologies. The NEMS model does not presently have the capability to model energy storage on the national grid. The scope of this study was to assess the feasibility of, and make recommendations for, the modeling of battery energy storage systems in the Electricity Market of the NEMS. Incorporating storage within the NEMS will allow the national benefits of storage technologies to be evaluated.
The use of natural energy sources and their conversion to secondary forms of energy are a crucial base for the development of our society with its continuous change of requirements due to an increase in population and the broadening of the needs in our modern life. As a consequence the consumption of primary energy resources rose drastically worldwide during the last 5 decades in particular in the industrialized regions such as Europe. Parallel in time the increasing awareness of negative effects of fuel dependent pollution on the environment and the introduction of stringent emission control regulations about 3 decades ago initiated extensive development and retrofit activities resulting in the today applied high level state of the art. As an additional challenge the worldwide debate about the potential effects of the emission of the s.c green house gases on the global climate in particular carbon dioxide from the use of predominantly fossil fuels have initiated ...
Within the Annual Conference 2009 of the VGB PowerTech e.V. (Essen, Federal Republic of Germany) from 23rd to 25th May, 2009, in Lyon (France) the following lectures were held: (1) Electricity demand, consequences of the financial and economic crisis - Current overview 2020 for the EU-27 (Hans ten Berge); (2) Status and perspectives of the electricity generation mix in France (Bernard Dupraz); (3) European electricity grid - status and perspective (Dominique Maillard); (4) Technologies and acceptance in the European energy market (Gordon MacKerran); (5) EPR construction in Finland, China, France, (Claude Jaouen); (6) EPR Flamanville 3: A project on the path towards nuclear revival (Jacques Alary); (7) Worldwide nuclear Revival and acceptance (Luc Geraets); (8) An overview on the status of final disposal of radioactive wastes worldwide (Piet Zuidema); (9) Who needs pumped storage plants? PSP are partner to grid stability and renewable energies (Hans-Christoph ...
Within the Annual Conference 2009 of the VGB PowerTech e.V. (Essen, Federal Republic of Germany) from 23rd to 25th May, 2009, in Lyon (France) the following lectures were held: (1) Electricity demand, consequences of the financial and economic crisis - Current overview 2020 for the EU-27 (Hans ten Berge); (2) Status and perspectives of the electricity generation mix in France (Bernard Dupraz); (3) European electricity grid - status and perspective (Dominique Maillard); (4) Technologies and acceptance in the European energy market (Gordon MacKerran); (5) EPR construction in Finland, China, France, (Claude Jaouen); (6) EPR Flamanville 3: A project on the path towards nuclear revival (Jacques Alary); (7) Worldwide nuclear Revival and acceptance (Luc Geraets); (8) An overview on the status of final disposal of radioactive wastes worldwide (Piet Zuidema); (9) Who needs pumped storage plants? PSP are partner to grid stability and renewable energies (Hans-Christoph ...
Leakage of CO{sub 2} and displaced brine from geologic carbon sequestration (GCS) sites into potable groundwater or to the near-surface environment is a primary concern for safety and effectiveness of GCS. The focus of this study is on the estimation of the probability of CO{sub 2} leakage along conduits such as faults and fractures. This probability is controlled by (1) the probability that the CO{sub 2} plume encounters a conductive fault that could serve as a conduit for CO{sub 2} to leak through the sealing formation, and (2) the probability that the conductive fault(s) intersected by the CO{sub 2} plume are connected to other conductive faults in such a way that a connected flow path is formed to allow CO{sub 2} to leak to environmental resources that may be impacted by leakage. This work is designed to fit into the certification framework for geological CO{sub 2} storage, which represents vulnerable resources such as potable groundwater, ...
Carbon supported catalysts can lose their activity over a period of time due to the sintering of the nanometer-sized catalyst particles. The sintering of metal clusters on carbon supports can occur due to the weak interaction between the metal and the support and also due to the corrosion of carbon, especially in fuel cell electrocatalysts. The sintering may be reduced by increasing the interaction between the metal and the support and also by increasing the corrosion resistance of carbon supports. In an effort to mitigate the growth of the nanoparticles, carbon-substituted boron defects were introduced in the carbon lattice. The interaction between the Pt nanoparticles on the pure and boron-doped carbon supports was examined using X-ray photoelectron spectroscopy (XPS). The results indicate that the interaction between the Pt nanoparticles ...
Mineral carbonation is based on the reaction of carbon dioxide with metal-oxide bearing minerals, usually containing magnesium or calcium silicate, to form hardly soluble carbonates and other solid byproducts. The concept is based on acceleration of the naturally occurring rock weathering process. In the present work the calcium silicate is present in the mineral, wollastonite. To accelerate the process and make it potentially useful for practical applications, mineral carbonation is conducted here using an indirect two-step route in which the reactive component (Ca^2^+ ions in considered case) is first extracted from the mineral matrix and afterwards carbonated. Two solid byproducts are formed in this process: silica in the extraction step and calcium carbonate in the carbonation step. In...
Carbon-14 was analysed by direct absorption of carbon dioxide on the mixture of organic amine compound and scintillation cocktail then counted by low level liquid scintillation counter. This method can be applied for radiocarbon dating. In this study, the effects of carbon dioxide absorption, and counting efficiency were investigated using various commercial available cocktail. It was found that permafluor V and Ready Gel showed the highest carbon dioxide absorption whereas the Permafluor V showed the highest counting efficiency
The principle for working out the time-temperature schedule of the carbonization was determined through the investigation on the carbonization process of the green body and the phenol formaldehyde resin. During the carbonization process, the crack at lower temperatures is due to strain inhomogeneity produced in press. But the crack at higher temperatures results from the improper increasing rate of temperature. The application of the autoclave-carbonization process can increase the mechanical properties of the spherical fuel elements.
Wetlands can potentially sequester vast amounts of carbon. However, over 50% of wetlands globally have been degraded or lost. Restoration of wetland systems may therefore result in increased sequestration of carbon. Preliminary results of our investigations into atmospheric carbon sequestration by restored coastal wetlands indicate that carbon can be sequestered in substantial quantities in the first 2-50 years after restoration of natural hydrology and sediment accretion processes.
This critical review with 28 references examines absorption and emission in the v2 band of the carbon dioxide molecule at around the 15micron wavelength. The argument for additional infrared absorption, the enhanced greenhouse effect due to increased carbon dioxide concentrations, and radiation transport and increased emissions are discussed. Experiments studying the transmission spectra of pure carbon dioxide and carbon dioxide in nitrogen, and comparing them with the results of climate modelling using the HITRAN and GEISA databases, are described.
Over the past 40 years, cavern storage of LPG's, petrochemicals, such as ethylene and propylene, and other petroleum products has increased dramatically. In 1991, the Gas Processors Association (GPA) lists the total U.S. underground storage capacity for LPG's and related products of approximately 519 million barrels (82.5 million cubic meters) in 1,122 separate caverns. Of this total, 70 are hard rock caverns and the remaining 1,052 are caverns in salt deposits. However, along the eastern seaboard of the U.S. and the Pacific northwest, salt deposits are not available and therefore, storage in hard rocks is required. Limited demand and high cost has prevented the construction of hard rock caverns in this country for a number of years. The storage of natural gas in mined caverns may prove technically feasible if the geology of the targeted market area is suitable; and economically ...
The Cambro-Ordovician platform was formed along the margin of the old super-continent of Laurentia approximately 470 million years ago, and is a prolific producer of hydrocarbons. This presentation provided a geological review of the region as well as estimates of the amounts of oil in place. A simplified geological cross-section of the formation was presented, as well as a chart of the Anticosti Basin of western Newfoundland. Details of exploration wells targeting the Cambro-Ordovician carbonate platform and current west coast land holdings were provided. An outline of the area's petroleum system included details of source rock, reservoirs, traps and seals and migration and timing. Offshore prospects for the platform were estimated to be in the region of 100 to 200 million barrels. Onshore prospects were estimated to be in the region of 30 million to 150 million barrels. It was noted that limited coverage by onshore seismic data may mean that larger ...
Peatlands are an important long-term sink for atmospheric carbon dioxide (CO{sub 2}). The storage function of peatland ecosystems is significantly impacted by drainage and extraction processes, which can result in the release of significant amounts of CO{sub 2}. This paper investigated the net ecosystem CO{sub 2} exchange of a newly developed extraction-restoration technique that preserved the acrotelm and replaced it directly on the cut surface of the peatlands. The technique used a modified block-cut method with a back-hoe to create a drainage ditch. Actrotelm and surface vegetation were removed and placed to one side, and the peat was mechanically removed. The acrotelm was then transplanted over the older and more decomposed catotelm peat to create a trench topography in which the natural peatland was higher than the extracted zone. Air temperatures, water table levels, and volumetric moisture content levels were measured throughout the ...
The effect of liquefied natural gas on pollutant emissions was evaluated experimentally with used and new appliances in the laboratory and with appliances installed in residences, targeting information gaps from previous studies. Burner selection targeted available technologies that are projected to comprise the majority of installed appliances over the next decade. Experiments were conducted on 13 cooktop sets, 12 ovens, 5 broiler burners, 5 storage water heaters, 4 forced air furnaces, 1 wall furnace, and 6 tankless water heaters. Air-free concentrations and fuel-based emission factors were determined for carbon monoxide, nitrogen oxides, nitrogen dioxide, and the number of (predominantly ultrafine) particles over complete burns?including transient effects (device warm-up and intermittent firing of burners) following ignition--and during more stable end-of-burn conditions. Formaldehyde was measured over multi-burn cycles. The baseline fuel ...
ICP emission analyses are prone to errors due to changes in power level, nebulization rate, plasma temperature, and sample matrix. As a result, accurate analyses of complex samples often require frequent bracketing with matrix matched standards. Information needed to track and correct the matrix errors is contained in the emission spectrum. But most commercial software packages use only the analyte line emission to determine concentrations. Changes in plasma temperature and the nebulization rate are reflected by changes in the hydrogen line widths, the oxygen emission, and neutral ion line ratios. Argon and off-line emissions provide a measure to correct the power level and the background scattering occurring in the polychromator. The authors` studies indicated that changes in the intensity of the Ar 404.4 nm line readily flag most matrix and plasma condition modifications. Carbon lines can be used to monitor the impact of organics on the analyses and calcium and ...
The Materials & Fuel Complex (MFC) facilities 799 Sodium Processing Facility (a single building consisting of two areas: the Sodium Process Area (SPA) and the Carbonate Process Area (CPA), 799A Caustic Storage Area, and 770C Nuclear Calibration Laboratory have been declared excess to future Department of Energy mission requirements. Transfer of these facilities from Nuclear Energy to Environmental Management, and an associated schedule for doing so, have been agreed upon by the two offices. The prerequisites for this transfer to occur are the removal of nonexcess materials and chemical inventory, deinventory of the calibration source in MFC-770C, and the rerouting and/or isolation of utility and service systems. This report provides a description of the current physical condition and any hazards (material, chemical, nuclear or occupational) that may be associated with past operations of these facilities. This information will document ...
A study was conducted to determine the feasibility and the opportunity of photochemical pretreatment on the biodegradation and detoxification of Methyl Tert Butyl Ether (MTBE), Ethyl Tert Butyl Ether (ETBE) and Tert Amyl Methyl Ether (TAME), the most common oxygenates used as octane enhancers in unleaded gasoline. The production, storage, uses and disposal of oxygenates result in an unknown amount of groundwater pollution. Because of their high solubility, MTBE, ETBE and TAME are detected in large portions in saturated zones of aquifers. The biodegradation of these oxygenates is difficult and slow, and information regarding their biodegradability is scarce. Photo-decomposition of oxidants under appropriate UV radiation has been shown to be very effective because the hydroxyl radicals produced possess high oxidation potential. In this study, the H{sub 2}O{sub 2}/UV process was used to generate hydroxyl radicals. Maximal oxygenates transformation was obtained in a ...
A study was conducted to determine the feasibility and the opportunity of photochemical pretreatment on the biodegradation and detoxification of Methyl Tert Butyl Ether (MTBE), Ethyl Tert Butyl Ether (ETBE) and Tert Amyl Methyl Ether (TAME), the most common oxygenates used as octane enhancers in unleaded gasoline. The production, storage, uses and disposal of oxygenates result in an unknown amount of groundwater pollution. Because of their high solubility, MTBE, ETBE and TAME are detected in large portions in saturated zones of aquifers. The biodegradation of these oxygenates is difficult and slow, and information regarding their biodegradability is scarce. Photo-decomposition of oxidants under appropriate UV radiation has been shown to be very effective because the hydroxyl radicals produced possess high oxidation potential. In this study, the H_2O_2/UV process was used to generate hydroxyl radicals. Maximal oxygenates transformation was obtained in a few minutes. ...
The carbon-isotope ratio recently obtained for the carbon found in the Murchison meteorite, which has been shown (by the racemic nature of twelve component amino acids) to be free of terrestrial contamination,...Full Text Available
This patent describes a process for removing carbon dioxide from a feed stream of natural gas having at least methane, ethane and heavier. It comprises: first, separating the feed stream in a first separator to form a first stream having substantially all of the propane and heavier hydrocarbons and carbon dioxide and ethane and a second stream, having methane, carbon dioxide and ethane; separating the second stream in a second separator into a stream of carbon dioxide product and a third stream having ethane, methane and carbon dioxide: mixing at least a portion of the third stream with a polar compound; stream after the mixing in an absorber; separating the vapor and liquid of the third stream after the mixing in an absorber; absorbing the remaining unabsorbed carbon dioxide in a lean portion of the polar compound in the absorber, the absorber ...
Carbon dioxide is a waste product of aerobic cellular respiration in all aerobic life forms. PaCO2 represents the balance between the carbon dioxide produced and that eliminated. Hypocapnia...Full Text Available
This study is one element of a larger engineering study effort by WHC to examine the feasibility of irradiated fuel and sludge consolidation in the KW Basin in response to TPA Milestone (target date) M-34-00-T03. The study concludes that up to 11,500 fuel storage canisters could be accommodated in the KW Basin with modifications. These modifications would include provisions for multi-tiered canister storage involving the fabrication and installation of new storage racks and installation of additional decay heat removal systems for control of basin water temperature. The ability of existing systems to control radionuclide concentrations in the basin water is examined. The study discusses requirements for spent nuclear fuel inventory given the proposed multi-tiered storage arrangement, the impact of the consolidated mass on the KW Basin structure, and criticality issues associated with multi-tiered ...
This paper introduces the method of seismic stability analysis for the increase of fuel storage capacity of wet storage stacks by one or two more stack floor at Wolsung Nuclear Unit 2,3,4, which had been originally licensed assuming 16 tray stack-o-storage. As a basic procedure, tipping and sliding stability of the structure is checked at first thru seismic analysis and the resultant load from dynamic analysis is applied for static stress analysis, and the result of which is reviewed for compatability with applicable standard. As a result, sliding and overturning are not expected under design basis earthquakes for increased storage cases of 17 tray and 18 tray stacks. And it is anticipated the result of stress analysis will be acceptable.
This paper introduces the method of seismic stability analysis for the increase of fuel storage capacity of wet storage stacks by one or two more stack floor at Wolsung Nuclear Unit 2,3,4, which had been originally licensed assuming 16 tray stack-o-storage. As a basic procedure, tipping and sliding stability of the structure is checked at first thru seismic analysis and the resultant load from dynamic analysis is applied for static stress analysis, and the result of which is reviewed for compatability with applicable standard. As a result, sliding and overturning are not expected under design basis earthquakes for increased storage cases of 17 tray and 18 tray stacks. And it is anticipated the result of stress analysis will be acceptable.
The Electric Power Research Institute has published a report for planners, designers, owners, and operators of hydroelectric pumped-storage plants that records the operation and maintenance knowledge of 35 domestic and foreign pumped-storage projects. The report provides a comprehensive record of practices that have reduced forced outages and shortened scheduled repairs. As time passes and experienced staff retire at pumped-storage plants, many O M lessons are lost. To remedy that situation, EPRI commissioned Morrison-Knudsen Engineers Inc. to prepare a special report. The 348-page publication records the accumulated civil, geotechnical, mechanical, and electrical O M knowledge and experiences of pumped-storage plant staff. It also includes recommendations to planners and designers of future pumped-storage plants and concludes with descriptions of O M experiences reported by plant ...
A method of making high strength coke briquettes suitable for use as blast furnace coke comprising, (A) providing coal, (B) heating the coal at a temperature at or above the softening point of the coal to form partially carbonized char, (C) cooling the partially carbonized char below the softening point of the coal, (D) mixing the cooled partially carbonized char and tar to form a mixture of tar and partially carbonized char, (E) briquetting the mixture of tar and partially carbonized char to form briquettes of tar and partially carbonized char, (F) calcinating the briquettes to form high strength briquettes.
The compressive and torsional buckling behavior of carbon nanotube bundles at room temperature is examined with classical molecular dynamics simulation. The critical compressive load and stiffness of a single carbon nanotube in the bundle are found to be similar to those of individual carbon nanotubes. However, the critical torsional moment and stiffness of a single carbon nanotube in the bundle are found to be higher than those of individual carbon nanotubes. In addition, this study demonstrates that van der Waals interactions between the nanotubes in the bundle significantly affect the critical compressive load of the nanotube bundle.
This report presents a brief description of the fabrication and advantages of a composite, carbon-metal fiber material which does not require lubrication.
We prepared cathodes with various types of activated carbon and measured the cathodes' electrochemical performance according to the kind of activated carbon. Activated carbon supplies airflow channels and reaction sites in the cathode of zinc air batteries. When we use activated carbon with a high specific surface area as the cathode's catalyst substrate, we expect high electrochemical performance because this type of carbon provides more air flow channels and reaction sites. We focused on investigating the relationship between the cathode's pore structure and its electrochemical characterizations. We also studied the effects of the various activated carbon materials on the zinc air batteries' performance. Increasing the macropores or mesopores in the activated carbon resulted in achieving more power from ...
... rate on the tensile properties of SA-106 carbon steel pipe, in support of analysis and experimental modeling of postulated pipe whip in nuclear ...
... The fuel proposed was a medium-thermal carbon black-liquid JP-i1 mixture. JP-iO or exo-tetrahydrodi (cyclopentadieue) is a pure hydrocarbon with ...
Background:To determine nutrient requirements by the carbon oxidation techniques, it is necessary to know the fraction of carbon dioxide produced during the oxidative...Full Text Available
Ab initio planewave pseudopotential method is used to study carbon diffusion and pairing in crystalline silicon. The calculation is performed with a 40 Ry planewave cutoff and 2x2x2 special k-point sampling with a supercell of 64 atoms. It is found that substitutional carbon attracts interstitial Si forming a <001> C interstitial with a large binding energy of 1.45 eV. The interstitial carbon is mobile and can migrate with a migration energy of 0.5 eV. The interstitial carbon can bind further to another substitutional carbon forming a substitutional carbon-interstitutional carbon pair with a binding energy of 1.0 eV. This model is used to understand the effect of high C concentration on the transient enhanced diffusion in Si.
A process is described for removing carbon dioxide from a feed stream of natural gas, having at least methane, ethane and heavier hydrocarbon, comprising: separating the feed stream in a first separator to form a first stream, having substantially all of the propane and heavier hydrocarbons and carbon dioxide and ethane, and a second stream, having methane, carbon dioxide and ethane; mixing the second stream with a polar compound to form a third stream; separating the vapor and liquid of the third stream in the bottom portion of an absorber; absorbing carbon dioxide and ethane from the separated vapor of Step C in a lean portion of the polar compound in the absorber, the absorber carbon dioxide and ethane forming a fourth stream; separating the ethane from the polar compound and carbon dioxide in a separator; separating the first stream in a third separator to ...
This guide has been written to introduce growers of Short Rotation Coppice (SRC) to the principles and need for cold storage of planting material. The main types of cold store are described. It also provides assistance in the selection of suitable stores and how these are located nationally. (author)
A HydroSele S seal from James Walker has provided more than two years maintenance-free service at the large Entracque pumped-storage hydroelectric scheme in Italy.
This guide describes an acceptable method of complying with the Commission's regulations with regard to the quality assurance requirements for the packaging, shipping, receiving, storage, and handling of items for water-cooled nuclear power plants.
When any new accelerator or storage ring is built that advances the state of the art, the diagnostic system becomes extremely important in tuning the facility to full specification. This paper will discuss the various diagnostic devices planned or under construction for the PSR and their connection into the control system.
The article describes control and monitoring concepts in which the delegation of responsibility is becoming more decisive than ever (automation hierarchy), and which are capable of optimized, automatic control of process events in pumped storage plants. 8 refs.
Jul 16, 2005 ... The purpose of this capability portfolio is to develop a roadmap for NASA to exploit .... 1.2.4-2: Some applications of nanotechnology to advanced EVA suits. ..... Power/Energy Storage: Materials and devices for energy storage and .... to 80 %), manufacturing costs (up to 50%) and enhancements in durability. ...
Pumped storage plants 20 are a relatively common type.They use a dam to create an upper reservoir ...Some pumped storage plants use the same water turbine and electric generator for both operating periods.That is,
Pumped storage plants are a relatively common type.They use a dam to create an upper reservoir ...Some pumped storage plants use the same water turbine and electric generator for both operating periods.
The heat storage material consists of a mixture of oleic and stearic acids in which stearic acid is present to the extent of 30 percent to 90 percent by weight. In addition to this binary system, the invention is also directed to a ternary system in which diphenyl ether is present along with the stearic and oleic acids.
This paper describes the advent of energy pumped storage plants in France, in connection with nuclear power reactors development and gives detailed specifications of different components (pump turbines, alternators, valves ...). 5 figs., 3 tabs.
IntroductionIn critically ill patients the relationship between the storage age of red blood cells (RBCs) transfused and outcomes are controversial. To determine if duration of RBC...Full Text Available
IntroductionTransfusion is a common treatment in pediatric intensive care units (PICUs). Studies in adults suggest that prolonged storage of red blood cell units is associated with...Full Text Available
The device is designed for automatic testing of the degree of discharge of tractive storage batteries (AB) for electric loaders, electric cars and electric ore locomotives. The basic electrical schematic of the device is cited.
BackgroundStorage of RBCs is necessary for an adequate blood supply. However, reports have identified potential negative sequelae of transfusing stored RBCs. An animal...Full Text Available
...capacity, and ownership of all planned and existing onshore pipelines, storage facilities, refineries, petrochemical...will be served by the port, including: (i) Onshore pipelines; (ii) Storage facilities; (iii)...
The summertime tropical cyclogenesis rate per unit area in the eastern Pacific ocean is arguably higher than in any other location in the world. Many if not most of these cyclones form from African easterly waves which cross Central America into the Pacific. Of order 25% of these waves intensify into cyclones. A significant fraction of east Pacific tropical cyclones undergoes landfall on the Mexican coast. Those which do not, generally dissipate over cold ocean waters north of the east Pacific intertropical convergence zone, often not far from land. The layer of warm ocean water which supports the development of east Pacific cyclones is unusually shallow and is structured by anticyclonic vortices which form by various processes and propagate slowly to the west. These vortices locally deepen the oceanic mixed layer and support stronger convection than their surroundings, possibly promoting cyclogenesis and cyclone intensification. Cyclones in turn have an unusually large effect on ...
Recent investigations have identified elevated concentrations of polychlorinated dibenzo-p-dioxins (dioxins) in marine sediments and wildlife of Queensland, Australia. While it has been demonstrated that the contamination is widespread and predominantly land-based, limited information exists on the pathways and fate of these compounds within the near-shore marine system. This environment supports unique and threatened species including green sea turtles (Chelonia mydas). Adult green turtles are predominantly herbivorous, feeding on seagrass and algae. Apart from initial migration to feeding grounds (at {proportional_to}10 years of age) and intermittent migrations to breeding grounds (at {proportional_to}30-50 years and thereafter), green turtles remain and feed within relatively small home ranges. Long life-span (50 years or more), near-shore feeding grounds and highly specialized food requirements render green turtles potentially vulnerable to contaminant ...
The Canadian Soldier Information Requirements Technology Demonstration (SIREQ TD) soldier modernization research and development program has conducted experiments to help determine the types and amount of information needed to support wayfinding across a range of terrain environments, the most effective display modality for providing the information (visual, auditory or tactile) that will minimize conflict with other infantry tasks, and to optimize interface design. In this study, seven different visual helmet-mounted display (HMD) designs were developed based on soldier feedback from previous studies. The displays and an in-service compass condition were contrasted to investigate how the visual HMD interfaces influenced navigation performance. Displays varied with respect to their information content, frame of reference, point of view, and display features. Twelve male infantry soldiers used all eight experimental conditions to locate bearings to waypoints. From a constant location, ...
In cold countries, the design of transmission lines and communication networks requires the knowledge of ice loads on conductors. Atmospheric icing is a stochastic phenomenon and therefore probabilistic design is used more and more for structure icing analysis. For strength and reliability assessments, a data base on atmospheric icing is needed to characterize the distributions of ice load and corresponding meteorological parameters. A test site where icing is frequent is used to obtain field data on atmospheric icing. This test site is located on the Mt. Valin, near Chicoutimi, Quebec, Canada. The experimental installation is mainly composed of various instrumented but non-energized test cables, meteorological instruments, a data acquisition system, and a video recorder. Several types of icing events can produce large ice accretions dangerous for land-based structures. They are rime due to in-cloud icing, glaze caused by freezing rain, wet snow, and mixtures of ...
Due to changed operational conditions and because of the increasing age of several hydro power plant components, there is an increasing risk of damages and the control of degradation mechanisms is of increasing significance. Therefore lifetime considerations for safety relevant components in pumped-storage plants become more and more important. The development of a lifetime management system, in conjunction with monitoring systems and specific surveillance for a group of pumped-storage power plants of different ages and in a wide range of power output is presented. The special focus is on the impact of fatigue strength considerations within this framework. The applied procedure will be described for typical mechanical components in pumped-storage plants exemplarily. (orig.)
A prototype hydride storage bed, using LaNi{sub 4.25}Al{sub 0.75} as the storage material, was fitted with strain gages to measure strains occurring in the stainless steel bed vessel caused by expansion of the storage powder upon uptake of hydrogen. The strain remained low in the bed as hydrogen was added, up to a bed loading of about 0.5 hydrogen to metal atom ratio (H/M). The strain then increased with increasing hydrogen loading ({approximately} 0.8 H/M). Different locations exhibited greatly different levels of maximum strain. In no case was the design stress of the vessel exceeded.
Innovative new ideas for the construction of homes are described. A thermal energy storage system fireplace and a geothermal heat pump for homes are described.
... Treatment of electrical systems for pumped storage plants is not covered in the manual, although much of the information is applicable to pumped ...
One of the concerns with locating radioactive waste storage sites in salt deposits is how to permanently seal the underground storage areas once they have reached their storage capacity. The compaction of salt using explosives has been identified as a potential method of producing permanent seals in both entryways and shafts to storage areas. This paper describes the test procedure and results of a preliminary investigation to determine the feasibility of utilizing explosives in the compaction of salt. Three simple tests were carried out to measure the degree to which loose salt could be compacted.
The SmartStore model was developed to determine the optimum design of borehole heat stores as a function of different design parameters. The optimum design is defined as the design that achieves the storage task with a minimum annual storage cost. The annual storage cost is the sum of annual costs of investment, operation, maintenance and heat loss. The PC-model has a user-friendly lay-out and gives a fast pre-design of borehole heat stores. In this article the model is briefly described. It is also shown that the technical design of the store is influenced by varying technical properties of the storage volume, but also by the cost of heat. (orig.)
Sandia National Laboratories, New Mexico, conducts the Utility Battery Storage Systems Program, which is sponsored by the US Department of Energy`s Office of Energy Management. The goal of this program is to assist industry in developing cost-effective battery systems as a utility resource option by 2000. Sandia is responsible for the engineering analyses, contracted development, and testing of rechargeable batteries and systems for utility energy storage applications. This report details the technical achievements realized during fiscal year 1994.
Sandia National Laboratories, New Mexico, conducts the Utility Battery Storage Systems Program, which is sponsored by the US Department of Energy`s Office of Energy Management. In this capacity, Sandia is responsible for the engineering analyses, contract development, and testing of rechargeable batteries and systems for utility-energy-storage applications. This report details the technical achievements realized during fiscal year 1993.
The Sodium Storage Facility Project Quality Assurance Plan delineates the quality assurance requirements for construction of a new facility, modifications to the sodium storage tanks, and tie-ins to the FFTF Plant. This plan provides direction for the types of verifications necessary to satisfy the functional requirements within the project scope and applicable regulatory requirements determined in the Project Functional Design Criteria (FDC), WHC-SD-FF-FDC-009.
Several of the issues of the workshop are addressed from the perspective of a potential Space Station developer and energy wheel user. Systems considerations are emphasized rather than component technology. The potential of energy storage wheel (ESW) concept is discussed. The current status of the technology base is described. Justification for advanced technology development is also discussed. The study concludes that energy storage in wheels is an attractive concept for immediate technology development and future Space Station application.
Experience and technical innovations in power plant engineering have resulted in continuous improvements of operation control, availability and safety of pumped storage plants. Process control is constantly improved as new developments are made in equipment and systems engineering. Plant control concepts with increasingly complex automation hierarchy are described by which pumped storage processes can be controlled optimally, reliably, and automatically.
A decision must be made regarding whether the United State`s stockpile of neptunium should be discarded into the waste stream or kept for the production of Pu-238. Although the cost of long term storage is not inconsequential, to dispose of the material means the closing of our option to maintain control over our Pu-238 stockpile. Within the Fuels and Materials Examination Facility at Hanford there exists a remotely operated facility that can be converted for neptunium storage. This paper describes the facility and the anticipated handling requirements.
These ten chapters present an overview of floating production, storage and offloading (FPSO) vessels, and examines deep water developments; hydrostatic stability; production, storage and offloading systems; the configuration and structure of flexible risers and umbilicals; the structural and global dynamic analysis of flexible riser and umbilicals; verification of FPSO structural integrity; vessel global loading and rigid body response; environmental loading and vessel response; and mooring systems. (UK)
The properties of capacitors are reviewed in general, including dielectrics, induced polarization, and permanent polarization. Then capacitance characteristics are discussed and modelled. These include temperature range, voltage, equivalent series resistance, capacitive reactance, impedance, dissipation factor, humidity and frequency effects, storage temperature and time, and lifetime. Applications of energy storage capacitors are then discussed. (LEW)
Electro Energy, Inc. conducted a research project to develop an energy efficient and environmentally friendly bipolar Ni-MH battery for distributed energy storage applications. Rechargeable batteries with long life and low cost potentially play a significant role by reducing electricity cost and pollution. A rechargeable battery functions as a reservoir for storage for electrical energy, carries energy for portable applications, or can provide peaking energy when a demand for electrical power exceeds primary generating capabilities.
The two favourable dry storage concepts being under consideration in the Federal Republic of Germany are presented and the physical behaviour or natural convection cooling with air is explained. With the three examples cask store, vault storage horizontally and vertically arranged the main thermodynamical design parameters and their influence on the efficiency of the cooling system and on the temperature distribution inside the store and of the stored material are discussed. Moreover, the importance of the fulfilment and the harmony of all safety criteria and the difficulties while to do so are carried out especially with the vault store.
A valuation methodology for commodity storage facilities is proposed. This model utilizes traded instruments to replicate the fundamental derivative components of commodity storage facilities. The methodology is robust to different commodities, physical characteristics, and markets for valuing these types of assets. Two examples using the U. S. natural gas markets are presented.
Carbon Black and activated carbon materials providing high surface areas and a distinct pore distribution are prime materials for supercapacitor applications at frequencies < 0.5 Hz. A number of these materials were tested for their specific capacitance, surface and pore size distribution. High capacitance electrodes were manufactured on the laboratory scale with attention to ease of processability. (author) 1 fig., 1 ref.
Layered carbon fiber mats have been prepared by layer-by-layer (LBL) electrospinning of polyacrylonitrile onto thin natural cellulose paper and subsequent carbonization. The layered carbon fiber mat has been proved to be a promising microbial fuel cell anode for high density layered biofilm propagation and high bioelectrocatalytic anodic current density.
The carbon content of silicon single crystals and polycrystals has been measured by charged particle activation analysis (CPAA) and infrared absorption. The authors obtained a linear relationship between the absorption coefficient at 605 cm/sup -1/ and the carbon content obtained by CPAA. They obtained a conversion factor of (1.00 +- 0.03) 10/sup 17//cm/sup 2/ for a 100% substitutional carbon.
The metabolism of organic matter in the coastal regions of the ocean may significantly affect the oceanic carbon budget. This paper describes the high percentage (30%) of oceanic oxidation that occurs in coastal areas and the impact of this metabolism on the carbon cycle and climate of earth. Organic metabolism in the ocean appears to be a source of carbon dioxide release into the atmosphere. Oxidation in the coastal zone is of special interest, as it is likely influenced by anthropogenic activity. Recommendations for future research on this topic are proposed. 129 refs., 2 figs., 6 tabs.
Nuclear power plants of 20 units of in Korea are generating about 700 MTU of spent fuels annually. The inventory of spent fuels in Korea were estimated about 10,087.07 MTU at end of 2008, and the storage space of spent fuels won't be available any more at 2016 due to the saturation of the spent fuel pools in the plants. In addition, in order to reduce carbon emission and correspond to the enormous electricity demand in Korea, 8 units of nuclear power plants are under construction and several more plants are under planning. The 100,000 MTU of spent fuel inventory are expected by the year of 2095 in Korea. Therefore, short term and long term of spent fuel management plans are under discussion and implementation in Korea. As a short term of spent fuel management strategy for the target year of 2016, central or local spent fuel dry interim storage options are mostly under discussion. As a long term of management plan, fast ...
The effect of sodium on the partial oxidation of methane over MoO{sub 3}-SiO{sub 2} in the presence of molecular oxygen has been investigated. As in the sodium-free case, the major products are formaldehyde, carbon monoxide, carbon dioxide, and water. Kinetic analysis indicates that methane is directly oxidized to formaldehyde and carbon dioxide. Formaldehyde is oxidized to carbon monoxide, which is itself further oxidized, providing an alternative route to carbon dioxide. The kinetic model shows that sodium poisons the direct oxidation of methane to formaldehyde and carbon dioxide, but promotes the oxidation of formaldehyde and carbon monoxide. Model predictions of rates and selectivities are in good agreement with the experimental data. A mechanism that explains both the poisoning and promotion effects of sodium on MoO{sub 3}-SiO{sub 2} is ...
In order to apply chemical-looping combustion to a practical power plant, carbon deposition on the solid particle is one of the key problems to be overcome. Six kinds of solid particles were examined to clarify the kinetic behavior of carbon deposition. The effects of the solid composition, feed gas composition, and reaction temperature on carbon deposition were investigated by thermogravimetrical reactor on the basis of NiO/YSZ particle. From the viewpoints of both reactivity and resistance against carbon deposition, the particle of NiO mixed with YSZ (i.e., yttria-stabilized zirconia) was found to be a good candidate for chemical-looping combustion. It has been observed that carbon deposition could be completely avoided with very low concentration of water vapor. By means of a proposed model, the condition that carbon deposition would be avoided was ...
In this work, a comprehensive model has been developed for the absorption of carbon dioxide into promoted hot potassium carbonate solution. The model, which is based on penetration theory, incorporates an extensive set of important reactions and takes into account the coupling between mass transfer and chemical kinetics. The penetration theory provides an appropriate absorption rate and enhancement factor for the chemical absorption. Operating data for carbon dioxide absorption into DEA-hot potassium carbonate solution has been compared with model predictions. The impact of parameters such inlet temperature of lean solution, promoter concentration, liquid split fraction, hot feed location and type of promoter on the performance of a split-flow absorber have been examined. The use of other promoters is an efficient way to enhance the carbon dioxide absorption, which has been ...
Air flow rates and carbon dioxide concentrations of air entering and exiting eight H-Area waste tanks were monitored for a period of one year. The average instanteous concentration of carbon dioxide in air is within the range reported offsite, and therefore is not affect by operation of the coal-fired power plant adjacent to the tank farm. Waste solutions in each of the tanks were observed to be continuously absorbing carbon dioxide. The rate of absorption of carbon dioxide decreased linearly with the pH of the solution. Personnel exposure associated with the routine sampling and analysis of radioactive wastes stored at SRP to determine the levels of corrosion inhibitors in solution could be reduced by monitoring the absorption of carbon dioxide and using the relationship between pH and carbon dioxide absorption to determine the free hydroxide concentration in ...
A solar thermophotovoltaic (STPV) system has both terrestrial and space applications because thermal energy storage can be utilized. Excellent properties (heat of fusion=1800 j/gm and melting temperature=1680 K) make silicon the ideal thermal storage material for an STPV system. Using a one dimensional model with tapering of the silicon storage material, it was found that several hours of running time with modest lengths ({approximately}15 cm) of silicon are possible. Calculated steady-state efficiencies for an STPV system using an Er-YAG selective emitter and ideal photovoltaic (PV) cell model are in the range of 15{percent}{endash}17{percent}. Increasing the taper of the storage material improves both efficiency and power output. {copyright} {ital 1996 American Institute of Physics.}
Today?s demand on high supply chain performance requires higher awareness about supply chain risks and uncertainty. The purpose of this paper is to analyse the role of temporary storage in the transport network in a supply chain perspective. The primary research question concerns the purpose or role of temporary storage and whether management of temporary storage can contribute to reducing risks and uncertainty in the supply chain. The research is based on a system-theoretical approach, which emphasizes a holistic view instead of the characteristics of the different parts. The research method used in this paper is abductive. Existing theories are used to formulate a framework which leads to a conceptual model description of the temporary storage function. This model is then supported and v...
Tata Electric Companies (TEC) are engaged in the generation of hydro and thermal energy. TEC, to minimise backing down of its thermal units in off peak hours and also to at least partially meet the growing deficit in the supply during peak hours is moving to install pumped storage plants (PSPs) utilising off-peak surplus energy for pumping the water from lower pond to the upper pond for subsequent utilisation for power generation during peak hours. In view of some of the infra structural facilities such as storage ponds, water conductor system, transmission lines, etc. being already available, at the existing hydro power stations owned by TEC, the pumped storage units are being proposed within the environs of existing hydro stations, i.e. a 150 MW pumped storage unit at Bhira and a 90 MW pumped storage unit at Bhivpuri. The projects are described and cost estimates is given. ...
A dry interim storage facility has been constructed at the Wolsung power plant in Korea. This dry storage facility has seven separated modules. There are 40 long slender cylinders in one module. In one cylinder, ten baskets where sixty CANDU spent fuel bundles are loaded are stacked and stored. For this dry storage facility, analyses and tests for hypothetical accident conditions that might occur while moving and storing the baskets into a cylinder were performed. In a demonstration test, one of test basket models did not satisfy one of the safety-related requirements. Thus, the revised basket designs were generated using a structural evaluation based on finite element analyses and specimen tests. Among these revised designs, one design was chosen as a final revised basket design. The fina...
This paper develops optimal bidding strategies for a pumped-storage plant in a pool-based electricity market. In the competitive regime, when compared to simple hydroelectric generator, profit of the pumped-storage plant is maximized by operating it as a generator when market clearing price is high and as a pump when the price is low. Based on forecasted hourly market clearing price, a multistage looping algorithm to maximize the profit of a pumped-storage plant is developed, considering both the spinning and non-spinning reserve bids and meeting the technical operating constraints of the plant. The proposed model is adaptive for the nonlinear three-dimensional relationship between the power produced, the energy stored, and the head of the associated reservoir. Different operating cycles for a realistic pumped-storage plant are considered and simulation results are reported and compared. (author)
The number of spent fuel storage facilities in the world continues to increase because of "Wait and See" policies and delay of a permanent disposal plan. The temporary spent fuel storage concept is changing to a pre-disposal storage concept. Strengthened safety concepts are required for expanded spent fuel storage facilities and sites. The Korea Hydro and Nuclear Power Company is planning to construct a reinforced concrete MACSTOR-400 facility at Wolsung. In concrete dry spent fuel storage structures, cracks can occur due to radiant heat and environmental chloride. The likelihood of cracking increases over time. Research on changes in shielding performance from one collinear crack in the surface of a concrete facility has been carried out. However there is no research about public radiolog...
The emergence of new power electronics and improved battery technology has created renewed interest in Battery Energy Storage Systems (BESS). These new systems provide electric utilities with alternatives to conventional storage technologies, such as pumped hydro. BESs has the potential to provide substantial benefits in terms of energy management, improved voltage, spinning reserve and protection from interruptions when compared to large centralized storage. This paper describes a commercial, economically justified, application of the new Battery Energy Storage Systems which is presently under construction in the Metlakatla Power and Light system. The paper outlines the system performance requirements which lead to consideration of BESS as an option; the economic factors which provided the justification for BESS as an economic alternative; and the overall BES system design and performance.
A high-voltage cathode initiates an electron emission, resulting in a reduction in the carbon dioxide concentration in exhaust gas from the burning of hydrocarbon fuel. Assuming that the observed carbon dioxide reduction is originated from the molecular decomposition, the energy needed for the endothermic reaction of this carbon dioxide reduction may stem primarily from the internal energy reduction in the exhaust gas in accordance of the first law of the thermodynamics. An oxygen increase due to the reduction in carbon dioxide in a discharge gas was observed in real time.
An analytical electron microscope study is presented on carbonaceous material in two chondritic porous aggregates, W7029* A and W7010* A2, from the Johnson Space Center Cosmic Dust Collection. The finding of well-ordered carbon-2H (lonsdaleite) in the two aggregates suggests that a record of hydrocarbon carbonization may be preserved in these materials. This carbon is a metastable phase resulting from hydrous pyrolysis below 300-350"0C and may be a precursor to poorly graphitized carbons in primitive extra terrestrial materials. (UK).
The interest of irradiation by carbon ions is in the fact that the carbon ions leave all their energy to a determined depth. ( phenomenon known under the name of Bragg peak)This high diffusion in tissue gives an RBE particularly high. The indications of this therapy are chordomas, and chondrosarcomas of the skull base, some cyst adenoid carcinomas, pulmonary cancer, sarcomas, hepato carcinomas, melanomas. In the light of results in term of efficiency, the place of irradiation by carbon ions should widen. (N.C.)
Carbon dioxide is receiving renewed interest as an efficient and environmentally safe refrigerant in a number of applications, including mobile air conditioning and heat pump systems, and hot water heat pumps. Compact heat exchangers for CO{sub 2} systems are designed with small-diameter tubing. The purpose of this study is therefore to provide a better basis for understanding and predicting heat transfer and pressure drop during flow vaporization of CO{sub 2} in microchannels. The ''unusual'' properties of carbon dioxide give heat transfer and two-phase flow characteristics that are very different from those of conventional refrigerants. Examples of these differences are the much higher pressure, the resulting high vapour density, a very low surface tension, and a low liquid viscosity. High pressure and low surface tension has a major effect on nucleate boiling characteristics, and earlier test data have ...
The behavior of melter feed (a mixture of nuclear waste and glass-forming additives) during waste-glass processing has a significant impact on the rate of the vitrification process. We studied the effects of silica particle size and sucrose addition on the volumetric expansion (foaming) of a high-alumina feed and the rate of dissolution of silica particles in feed samples heated at 5 C/min up to 1200 C. The initial size of quartz particles in feed ranged from 5 to 195 {micro}m. The fraction of the sucrose added ranged from 0 to 0.20 g per g glass. Extensive foaming occurred only in feeds with 5-{micro}m quartz particles; particles {ge}150 {micro}m formed clusters. Particles of 5 {micro}m completely dissolved by 900 C whereas particles {ge}150 {micro}m did not fully dissolve even when the temperature reached 1200 C. Sucrose addition had virtually zero impact on both foaming and the dissolution of silica particles. Over 100 sites in the United States are currently tasked with the ...
Lithium ion batteries use an oxide as a positive electrode and a carbon material as a negative electrode. The performances of carbon electrodes have rapidly evolved during the last years thanks to the substitution of soft carbons of Conoco or MCMB-2510 type by graphites (F-399, MCMB-2528) and then by hard carbons. These high capacity carbons (700 mAh/g) have higher service life and volume capacity than graphites but their irreversible losses are greater (>20%). In this work, materials with similar electrochemical performances are prepared by mechanical crushing. Mechanical crushing allows to obtain a wide range of carbon materials with various morphologies, specific surfaces and levels of disorder. The formation of the passivation film is directly linked with the surface of materials. A reaction scheme of the reversible and irreversible capacities has been ...
Tensile properties of reduced-activation 10Cr-30Mn austenitic steels with carbon levels from 0.003 to 0.55% were investigated over the temperature range from room temperature to 873 K after neutron irradiation in the Japan Materials Testing Reactor at 573 K to 8.5x10"2"2 n/m"2. Irradiation-induced increase in yield stress increased significantly with carbon concentration up to about 0.1% and it was constant above 0.1% carbon. A high density of dislocation loops with small (below 10 nm) and large (20-30 nm) sizes formed during irradiation. The high density, small loops caused a large irradiation hardening, while the large loops contributed only slightly to irradiation hardening. It was considered that carbon atoms formed the small loops together with irradiation defects. The deformation channeling was observed in the irradiated high carbon steels, 0.11 and 0.55% ...
Due to the cyclical human life, utility loads appear to be cyclical too. During daytime when most factories are in operation, the electricity demand is very high. On the contrary, when most people are sleeping from midnight to daybreak, the electric load is very low, usually only half of the peak load amount. To meet this large gap between peak load and light load, utilities must idle many generation plants during light load period while operating all generation plants during peak load period no matter how expensive they are. This low utilization factor of generation plants and uneconomical operation have sparked utilities to invest in energy storage devices such as pumped storage plants, compressed air energy storage plants, battery energy storage systems (BES) and superconducting magnetic energy storage systems (SMES) etc. Among these, pumped storage is ...
Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric ...
Limited demand and high cost has prevented the construction of hard rock caverns in this country for a number of years. The storage of natural gas in mined caverns may prove technically feasible if the geology of the targeted market area is suitable; and economically feasible if the cost and convenience of service is competitive with alternative available storage methods for peak supply requirements. It is believed that mined cavern storage can provide the advantages of high delivery rates and multiple fill-withdrawal cycles in areas where salt cavern storage is not possible. In this research project, PB-KBB merged advanced mining technologies and gas refrigeration techniques to develop conceptual designs and cost estimates to demonstrate the commercialization potential of the storage of refrigerated natural gas in hard rock caverns. Five regions of the U.S.A. were studied for ...
Treatment of coal or coconut shell activated carbons with either phosgene or chlorine at 180{degree}C followed by washing with methanol or water results in chlorinated carbons with very similar pore structures to their precursors. Water adsorption experiments show that the modified materials are relatively hydrophobic, presumably as a result of replacement of oxygen-containing surface groups by chlorine. Adsorption of the model hydrophobic vapour chloropicrin from humid air is usually better for the modified carbons which, unlike the controls, do not appear to be subject to degradation in performance on ageing in a humid atmosphere. The stability of the modified carbons is probably a consequence of the chlorination of those sites on the control carbons that are prone to ready oxidation or hydroxylation. 1 tab., 2 figs., 17 refs.
This issue of Carbon Market Perspectives on 'Pathways for implementing REDD+: Experience from carbon markets and communities' discusses the role of carbon markets in scaling up investments for REDD+ in developing countries. Nine articles authored by experienced negotiators on REDD+, carbon market actors, project developers and other leading experts share experiences and make suggestions on the key elements of a future international REDD+ regime: Architecture and underlying principles, measuring, reporting and verification (MRV), private-sector involvement, the rights of indigenous people and local communities, biodiversity conservation and environmental integrity. The articles are grouped under three main topics: the lessons of existing REDD+ projects; the future REDD+ regime and the role of carbon markets; and experiences and ideas about the involvement of ...
Comparatively evaluates methods for removal of carbon dioxide from waste gases emitted from industrial plants. The evaluations concentrate on carbon dioxide absorption by water solutions of alkalis and amines. The Hindered Amines Process, developed by Exxon in the USA, is analyzed. Chemical reactions of carbon dioxide absorption in solutions with hindered amines are evaluated. The following US patents which protect processes for carbon dioxide absorption by means of hindered amines are evaluated: No. 4,112,052, No. 4,101,633, No. 4,112,051, No. 4,100,257, No. 4,112,050, No. 4,094,957. Efficiency of carbon dioxide removal by each of the processes is pointed out. 12 refs.
Carbon black is widely used as an active filler in the rubber industry to improve the physical properties of rubber. The surface energy of carbon black is high compared to that of various elastomers like styrene?butadiene rubber (SBR), butadiene rubber (BR) and ethylene?propylene?diene rubber (EPDM). The work aims at reducing the surface energy of carbon black by modifying its surface for application especially in rubber blends. The present paper looks into the possibility of using plasma polymerisation of acetylene as a surface modification technique for carbon black in comparison with silica. Thermogravimetric analysis, wetting behaviour with various liquids of known surface tension and time of flight secondary ion mass spectrometry (ToF-SIMS) were used to characterise the carbon black b...
Polyacrylonitrile (PAN)-based carbon fabric (CF) was modified with strong HNO3 oxidation and then introduced into polyimide (PI) composites. The friction and wear properties of the carbon fabric reinforced polyimide composites (CFRP), sliding against GCr15 stainless steel rings, were investigated on an M-2000 model ring-on-block test rig under dry sliding. Experimental results revealed that the carbon fiber surface treatment largely reduced the friction and wear of the CFRP. Compared with the untreated ones, the surface-modified CF can enhance the tribological properties of CFRP efficiently due to the improved adhesion between the CF and the PI matrix. Scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS) study of the carbon fiber surface showed that the fiber surfa...
Methane and carbon dioxide are the two main constituents of biogas. Biogas also contains traces of nitrogen, hydrogen, oxygen and hydrogen sulphide. When diesel engine runs on biogas, the combustion is poor as compared to diesel fuel. One of the reasons of poor combustion is the presence of carbon dioxide in the biogas. Percentage of methane and carbon dioxide in biogas varies with maturities of feed stock, temperature, water content, loading rate of raw material and bacterial actions. This paper examines the effect of variations of carbon dioxide in biogas on the performance of the engine to simulate the performance of the engine running with biogas from different sources (varying proportion of methane and carbon dioxide). (Author)
A decontamination washer for working dresses using liquid and supercritical carbon dioxide were designed and manufactured. The size of reactor for decontamination and solidification is about 16 liter. The system is a closed one with recycling ability of carbon dioxide. The efficiency of recycling of carbon dioxide and that of separation of solutes in carbon dioxide were checked. They met all the design goals. A remote control system of the carbon dioxide flow was set in a control panel. The manufactured decontamination washer was brought to Wolsung nuclear power plants, and installed to check the efficiency of decontamination and the feasibility of usage in nuclear power plants. The elimination of radioactive oil from the contaminated dresses were very high. However, the decontamination factor was lower than the design goal value. It's due to the low removal rate of ...
The moment analysis of pulse responses was applied to a biological activated carbon (BAC) bed to evaluate the microbial activity. Glucose and activated carbon fiber (ACF) were employed in experiments as a model tracer and an activated carbon respectively. No significant difference in biodegradation rates of glucose by microorganisms attached on different solid supports such as activated carbon inactivated carbon and glass fibers was observed. However, higher microbial activity was obtained from microorganisms supported on the ACF in terms of the apparent degradation of total organic including metabolic byproducts by microorganisms, since part of the metabolic byproducts was irreversibly deposited onto the ACF. 11 refs., 6 figs.
The adsorption of CO2 on a number of activated carbons, thermal carbon black, and oxide materials at 195 K was studied using static and dynamic techniques. The landing surface areas ?(CO2) ? 0.19 nm2 on thermal carbon black and the absolute values of sorption for P/P 0 < 0.4 were determined. The density of adsorbed CO2 in the micropore volume was estimated at ?(CO2) = 0.91 g/cm3. It was demonstrated that the previously found effect of a weakening of the sorption interaction of nitrogen molecules with thin-walled materials (which manifested itself in an analysis of sorption isotherms by a comparative method) was pronounced to a lesser degree for the sorption of CO2. At the same time, the presence of supermicropores in activated carbon samples resulted in overestimated values of surface area...
To apply the CO{sub 2} absorber at about 1000{sup o}C for integrated coal gasification combined cycle (IGCC) furnace, the reactions of calcium oxide and CO{sub 2} at high temperatures was examined. Calcium carbonate reacts with sodium hydrogen carbonate below 200{sup o}C and forms sodium-calcium complex carbonate. The sodium-calcium complex carbonate melts at 813{sup o}C, and the carbon dioxide absorption and discharge reversible reactions of calcium-oxide takes place via liquid at around 1000{sup o}C. Sintering of calcium oxide at high temperature has been successfully avoided by the addition of sodium.
Preliminary observations on the isothermal carbon transfer in low-carbon Alloy-800 exposed in sodium with AISI-304 type of steel at 550_0 are reported. The alloy was found to undergo a carburization comparable or slightly lower than that observed for the AISI-304 stainless steel for carbon activities above 6 x 10 /sup -3/ at 550_0C, but was not found to decarburize below such a carbon activity value. In the examined range the chemical composition of the alloys does not affect the process out of the experimental uncertainty of measure. Conclusions concerning the effective diffusion for carbon in the alloy are formulated. Preliminary relationships were found for an empirical evaluation of the carburization of the Alloy-800 in sodium of known carbon activity.
Recent advances in thin film solar photovoltaic converters (PV's) can furnish multimegawatt power levels during lunar daylight periods with only modest mass requirements. The extended duration of lunar night (ca. 354 hr) and the high specific mass of earth-imported energy storage systems (regenerative fuel cells, batteries, etc.) render PV plus import storage power systems non-competitive with nuclear power plants for lunar bases. However, power storage or generation methods which can be constructed using primarily lunar materials, used either alone or with lightweight PV's, can be attractive alternatives to nuclear power. Three separate generic systems which can provide favorable low import mass goals have been identified and studied. These are: gravitational energy generation using lunar soil, thermal energy storage using basalt rock or glass, and electrochemical storage using ...
France has a wide variety of experimental spent fuels different from LWR spent fuel discharged from commercial reactors. Reprocessing such fuels would thus require the development and construction of special facilities. The French Atomic Energy Commission (CEA) has consequently opted for long-term interim storage of these spent fuels over a period of 50 years. Comparative studies of different storage concepts have been conducted on the basis of safety (mainly containment barriers and cooling), economic, modular design and operating flexibility criteria. These studies have shown that dry storage in a concrete vault cooled by natural convection is the best solution. A research and development program including theoretical investigations and mock-up tests confirmed the feasibility of cooling by natural convection and the validity of design rules applied for fuel storage. A facility called CASCAD was built ...
A variety of special regulations exist in Costa Rica for registration and transport of hazardous substances; these set the requirements for entry into the country and the security of transport units. However, the regulations mentioned no specific rules for storing hazardous substances. Tax deposits have been the initial place where are stored the substances that enter the country.The creation of basic rules that would be regulating the storage of hazardous substances has taken place through the analysis of regulations and national and international laws governing hazardous substances. The regulatory domain that currently exists will be established with a field research in fiscal deposits in the metropolitan area. The storage and security measures that have been used by the personnel handling the substances will be identified to be putting the reality with that the hazardous substances have been handled in tax deposits. A rule base for the ...
The European gas market is continuing to expand due to increased industrial, domestic and power generation demand. As a result of this demand, and the trend toward liberalization of the market, the need for storage of gas is also increasing. One key segment of the large scale storage of gas is underground storage, either in partially depleted gas or oil fields, naturally occurring caverns, aquifers and salt cavities. In most cases the gas produced after storage requires conditioning to meet the water of hydrocarbon dew point specification of the gas transmission system. For that reason export gas from storage will require gas conditioning in order to meet pipeline specifications. Adsorption as a feasible and reliable process will be presented in detail and especially in regards to hydrocarbon dew-pointing compared with other process options. (author)
Microbial population and moisture content of traditional herbal medicines contaminated with 3 kinds of aerobic microbes, packed in 5 kinds of plastic packaging materials, followed by irradiation at minimum dose of 5 kGy and stored for 6 months were investigated. The highest reduction of microbial counts during storage was observed on samples packed in polyethylene bags. All of packaging materials used were found to be impermeable to microbes and water vapour. Radiation and packaging materials used acted synergistically to inactivate microbes durind storage. The microbial counts decreased as much as 2 to 4 log cycles during storage. (author).
The product of several advanced physical coal cleaning processes is a dry, ultrafine coal (DUC), in the order of 10 microns mean mass diameter. To utilize this fuel commercially, cost-effective, environmentally safe systems must be provided for the storage, transport, and handling of this finely divided form of fuel. The objective of the project described herein is the development of total logistics systems for DUC, including experimental verification of key features. The systems to be developed will provide for safe, economic, and environmentally protective storage and delivery of DUC for residential, commercial, and industrial uses. 20 figs.
Originally designed exclusively for peak load covering, pumped storage plants are now faced with new challenges brought about by the deregulation of the electricity market and the substantial growth of wind power capacity. Today's pumped storage plants are started more frequently and often for shorter periods of time. The grid controlling tasks have increased the importance of the role played by this type of power plant and improved sales considerably. But the operational demands have grown substantially as well. This paper discusses the ensuing adaptation of power plant operation as well as options available to power plant operators. (orig.)
HFH Herbst has designed and built a unique machine for storage of spent highly radioactive nuclear fuel rods within two years for the Swedish SKB. The vehicle (total weight 98 t) can be operated underground without a driver. Herbst was able to bring to this project almost 30 years of experience in the complementation of vehicle projects for the nuclear industry. The Procyon 1 already proved its efficiency impressively in several hundred storage processes and operates with absolute reliability. (orig.)
All power plant engineers face the problem of peak power demands. Pumped storage plants are used to generate peak load power by pumping up water utilizing off-peak energy of hydrothermal and thermonuclear plants. This is a reference to cover hydroelectric power generation with emphasis on engineering to meet peak power demands by means of pumped storage plants, tidal power plants, and low head power generation. Text covers hydrology, mechanical and electrical equipment, accessories such as penstocks and valves, and civil engineering considerations. Contains descriptions of several existing plants. Includes 200 diagrams and 50 photographs.
The purpose of the chapter is to explain briefly the various considerations that enter into determining the general layout or arrangement of typical hydroelectric powerplants, pumping plants, and pumped-storage plants. Some of the important factors that affect or determine the location, type, and layout of the plant and the selection of the major items of equipment included in the installation are outlined in this chapter. The first consideration in the design of a powerplant, pumping plant, or pumped-storage plant is that it adequately perform its function and be structurally safe. The structure is also designed to give a pleasing architectural appearance.
The Michigan Electric Coordination Center (MEPCC), operated by Consumers Power and Detroit Edison Companies, has the responsibility for scheduling the Ludington pumped storage plant. Ludington has an extremely large economic effect on the Consumers Power and Detroit Edison Companies' system due to its size (over 1800 MW net demonstrated generating capability). This paper presents a dynamic programming algorithm for scheduling large pumped storage plants and shows how this method can be coordinated with the commitment of the thermal units of the system.
In this study the technical and economical possibilities of burning carbon monoxide (CO) of the flue gas and utilizing of the released heat in hot air cupola furnace used for melting have been studied. As basis for examining was burning of cleaned furnace...
This study was designed to evaluate the suitability of a novel bioabsorbable material in treating bone defects. A poly(desaminotyrosyl-tyrosine-ethyl ester carbonate) (PDTE carbonate) membrane (thickness...Full Text Available
The present invention relates to a method of recycling polymeric waste products into monomers and high value forms of carbon by pyrolytic conversion using an induction coupled RF plasma heated reactor.
Porous carbon with high surface area and pore volume was prepared by a reverse replication process and its toluene equilibrium adsorption behavior was investigated. The preparation process of the porous carbon was composed of following sub-processes in series: synthesis and template preparation of silica gel, impregnation and polymerization of DVB monomer in silica template, carbonization of DVB polymer in a silica-polymer composite, and HF-assisted selective etching of silica in carbon-silica composite, The prepared porous carbon was nano porous and had ultrahigh specific surface area (2007 m{sup 2}/g) and large pore volume (3.07cm{sup 3}/g). The nanoporous carbon showed rapid toluene adsorption rate and good toluene adsorption capacity, compared with a commercial Y-type zeolite, In the present study, a reverse replication process to prepare nanoporous ...
Recently we have found that carbon nano-materials have ability to recognize softer actinides(III). In this presentation, separation of americium(III) from lanthanides(III) by chromatography with carbon nano-materials, such as carbon nano-tubes and graphite, has been investigated by batch adsorption experiments and chromatography. The separation factor (SF) between americium(III) and lanthanide(III) was about 2 in the range of pH from 1 to 4 by using carbon nano-tube, graphite and activated charcoal. The separation factor depended on the diameter of carbon nano-tubes. Smaller one, 3-20 nm diameter, showed the best selectivity for americium(III), which separation factor was about 2.0, although larger one, 40-70 nm, showed almost no selectivity. The same behavior has been observed by using graphite powder and activated charcoal although acid- or alkali pretreated activated charcoal ...
Carbon nanotubes (CNTs) are considered one of the most promising materials in nanotechnology, with attractive properties for many technologic applications. The different synthesis, purification, and...Full Text Available
BackgroundThe precision in carbon ion radiotherapy depends on the calibration of Hounsfield units (HU) as measured with computed tomography (CT) to water equivalence. This calibration...Full Text Available
The acetogenic bacterium Clostridium thermoaceticum ATCC 39073 grew at the expense of the two-carbon substrates oxalate and glyoxylate. Other two-carbon substrates (acetaldehyde, acetate,...Full Text Available
Recent work has indicated that the suppression of boron transient enhanced diffusion (TED) in carbon-rich Si is caused by nonequilibrium Si point defect concentrations, specifically the undersaturation of Si self-interstitials, that result from the coupled out-diffusion of carbon interstitials via the kick-out and Frank--Turnbull reactions. This study of boron TED reduction in Si{sub 1-x-y}Ge{sub x}C{sub y} during 750{sup o}C inert anneals has revealed that the use of an additional reaction that further reduces the Si self-interstitial concentration is necessary to describe accurately the time evolved diffusion behavior of boron. In this article, we present a comprehensive model which includes {l_brace}311{r_brace} defects, boron-interstitial clusters, a carbon kick-out reaction, a carbon Frank--Turnbull reaction, and a carbon interstitial-carbon substitutional ...
Recent work has indicated that the suppression of boron transient enhanced diffusion (TED) in carbon-rich Si is caused by nonequilibrium Si point defect concentrations, specifically the undersaturation of Si self-interstitials, that result from the coupled out-diffusion of carbon interstitials via the kick-out and Frank--Turnbull reactions. This study of boron TED reduction in Si_1_-_x_-_yGe_xC_y during 750"oC inert anneals has revealed that the use of an additional reaction that further reduces the Si self-interstitial concentration is necessary to describe accurately the time evolved diffusion behavior of boron. In this article, we present a comprehensive model which includes #left brace#311#right brace# defects, boron-interstitial clusters, a carbon kick-out reaction, a carbon Frank--Turnbull reaction, and a carbon interstitial-carbon substitutional (C_iC_s) ...
A laboratory differential simulation method is used for the design of carbonization columns at coal-tar processing in which phenols are regenerated from phenolate solution by carbon dioxide absorption. The design method is based on integration of local absorption rates of carbon dioxide along the column. The local absorption rates into industrial phenolate mixture are measured in a laboratory model contactor for various compositions of the gas and liquid phases under the conditions that ensure the absorption rates in the laboratory absorber simulate the local rates in the industrial column. On the bases of the calculations, two-step carbonization columns were designed for 30000 t/year of the phenolate solution treatment by carbon dioxide. The absorption proceeds at higher pressure of 500 kPa and temperatures from 50 to 65 C, pure carbon dioxide is used and ...
We have isolated a second gene (MLS1), which in addition to DAL7, encodes malate synthase from S. cerevisiae. Expression of the two genes is specific for their physiological roles in carbon and nitrogen...Full Text Available
Concentration of an amine solution for removal of hydrogen sulfides and carbon dioxide from natural gas, is tested by carbon dioxide absorption measurement in an apparatus allowing complete reaction to give reliable results.
Several inexpensive and non-toxic solvents with low vapour pressures were investigated for their suitability as alternative solvents for the absorption of carbon dioxide from flue gas. The solvents include poly(ethylene glycol)s, poly(ethylene glycol) ethers, poly(ethylenimine) and glycerol-based substances. Solvent properties such as thermal stability, solubility of carbon dioxide and selectivity over nitrogen were investigated in a systematic study using a thermogravimetric analyser. Absorption results are reported for pure carbon dioxide and nitrogen as well as a mixture of both gases. Desorption and long-term sorption behaviour are also discussed. Glycerol and poly(ethylene glycol)s show a high solubility of carbon dioxide. Due to the high viscosity of the solvent, carbon dioxide absorption in poly(ethylenimine) is very slow in spite of the presence of favourable amine groups. ...
A process is claimed for selectively preparing alpha-olefins having from 2 to about 22 carbon atoms by contacting a gaseous mixture containing carbon monoxide and hydrogen with an iron titanate alkali metal hydroxide catalyst at reaction conditions correlated so as to favor the formation of a substantial proportion of such alpha-olefin product.
Only half of the carbon dioxide produced by burning fossil fuels stays in the atmosphere. It is thought that the oceans absorb the rest. To understand the world's climate it is necessary to know how the atmosphere, ocean and biosphere interact.
Rationale: Ventilator-induced lung injury (VILI) leads to an unacceptably high mortality. In this regard, the antiinflammatory properties of inhaled carbon monoxide (CO) may provide...Full Text Available
... of waste food generated at McMurdo Station. Some of the difficulties of disposing of waste food ... change waste generation or management at the site? Yes. This will be a temporary waste management ...
Energy storage systems with extremely high specific energy (>400 Wh/kg) have been designed that use lightweight pressure vessels to contain the gases generated by reversible (unitized) regenerative fuel cells (URFCs).[1] URFC systems are being designed and developed for a variety of applications, including high altitude long endurance (HALE) solar rechargeable aircraft (SRA), zero emission vehicles (ZEVs), hybrid energy storage/propulsion systems for spacecraft, energy storage for remote (off-grid) power sources, and peak shaving for on-grid applications.[1-10] Energy storage for HALE SRA was the original application for this set of innovations, and a prototype solar powered aircraft (Pathfinder-Plus) recently set another altitude record for all propeller-driven aircraft on August 6, 1998, when it flew to 80,285 feet (24.47 km).[11
... The other standards in this group deal with heat exchangers, insulation, marking, valves, hydraulic cleanliness, storage of LPG, and centrifugal fire ...
... Special Purpse Lead Azide Lot #I3A-4-62 ... Standard X-ray techniques are not sufficiently sensitive ... the National Bureau of Standards, and examined ...
Recent progress in yttrium-based oxide high-temperature superconductors has enabled the production of a large diameter bulk with a strong flux-pinning force. A combination of this superconductor and a permanent magnet makes it feasible to fabricate a noncontact, non-controlled superconducting magnetic bearing with a very small rotational loss, applicable to a flywheel energy storage system. A conceptual design of an 8 MWh flywheel energy storage system using the new bearing has been developed, based on measured data on a miniature bearing model, which proved to be potentially capable of achieving a high energy storage efficiency of 84 pc. A 100 W h-class experimental system was then built, which attained a high revolution rate of 17000 rpm, with a rotational loss of about 0.6 W. (authors). 2 refs., 7 figs., 3 tabs.
The ability of the /sup 252/Cf-source-driven neutron noise analysis method to measure subcriticality has been demonstrated in a variety of experimental configurations of fissile materials. Calculations for an approximately 4-m-dia configuration of light water reactor (LWR) fuel elements indicated the feasibility of measuring the subcriticality of large, loosely coupled arrays of LWR fuel elements by this same method. These analysis suggested application to the initial loading of both pressurized and boiling water reactors, zero-power testing of reactors (such as shutdown margin measurements after initial loading), light water reactor refueling, and safe storage of LWR spent fuel. In the fuel storage application, direct measurement of subcriticality in the actual fuel storage facilities provides the parameter which is directly related to criticality safety.
Development of Scientific Foundations of the Technology of the Metal Matrix Packing of Leaky Unreprocessible Spent Nuclear Fuel of Different Purpose Reactors for a Long-term Environmentally Safe Storage.
This report presents the results of a study on Operation and Maintenance (O M) practices in hydroelectric pumped storage plants. The objective of this project, which was sponsored by EPRI, is to record the practical knowledge on the O M of a number of the domestic and foreign pumped storage plants which has been accumulated by their operating staff. Civil, geotechnical, mechanical and electrical aspects of O M of the thirty-five plants visited are discussed, and some general conclusions, as warranted by the commonality of the problems, are drawn. These conclusions may be useful to the planners and designers of future pumped storage projects. In general, due to their layout, diversity and different modes of operation, the plants have few common problems which, in most cases, are limited to the mechanical and electrical aspects of the plants' operation. The data on plants' specifications, operation and ...
All treatments for obesity, including dietary restriction of carbohydrates, have a goal of reducing the storage of fat in adipocytes. The chief enzyme responsible for the mobilization of FFA from adipose...Full Text Available
In this study, usage of a variable speed refrigeration system in latent heat thermal energy storage (LHTES) system is investigated to increase energy storage efficiency. Four different compressor speed control cases are compared to obtain a constant heat transfer fluid (HTF) temperature at the inlet of the energy storage tank. These control cases are (i) control with evaporation temperature, (ii) control with ethylene glycol temperature at the outlet section of evaporator, (iii) control with suction pressure of the compressor and (iv) on/off control. By means of the experimental analysis the best control strategy is obtained as control with Case (ii), in terms of stability of inlet temperature of heat transfer fluid, variations of energy efficiency of LHTES and coefficient of performance (...
Energy storage can be a cost-effective component of hybrid remote power systems. Storage serves the special role of taking advantage of intermittent renewable power sources. Traditionally this role has been played by lead-acid batteries, which have high life-cycle costs and pose special disposal problems. Hydrogen or zinc-air storage technologies can reduce life-cycle costs and environmental impacts. Using projected data for advanced energy storage technologies, LLNL ran an optimization for a hypothetical Arctic community with a reasonable wind resource (average wind speed 8 m/s). These simulations showed the life-cycle annualized cost of the total energy system (electric plus space heating) might be reduced by nearly 40% simply by adding wind power to the diesel system. An additional 20 to 40% of the wind-diesel cost might be saved by adding hydrogen storage or zinc-air fuel cells ...
The effects of time of seed maturation and dry seed storage and of light and temperature requirements during seed incubation on final germination percentage and germination rate were assessed for the invasive shrub Prosopis juliflora (Sw.) D.C., grown under desert environmental conditions of the United Arab Emirates (UAE). Seeds were collected from Fujira on the northern coast of the UAE at different times during the growing seasons (autumn, winter and spring) and were germinated immediately and after 8 months of dry storage under room temperature (20+-3degreeC). Seeds were germinated at three temperatures (15, 25 and 40degreeC) in both continuous light and darkness. The results showed significant effects for time of seed collection, seed storage, light and temperature of seed incubation a...
This paper presents a new application in dynamic voltage control based on an older method of voltage regulation. The resulting method is suitable for adoption inn multi-unit pumped storage plants. Inherent operation characteristics of pumped storage plants in the pumping mode can created visible load rejection overvoltages on the transmission and the nearby distribution networks and cause customer complaints. This paper proposes a method in which the on-line units' excitation system impedance compensators are utilized to reduce the magnitude of these overvoltages. This paper presents the theoretical background, computer simulation results, and the field test results at the Pacific Gas and Electric Company's Helms Pumped Storage Plant. This paper should be of interest in the areas of power system planning as well as power system operation.
This comprehensive final report for the Swiss Federal Office of Energy (SFOE) examines ways to optimise energy flows in mains networks that include distributed generation facilities. Increasing use of decentralised generation, its effects on the operation of low-voltage mains and the efficient use of the 400 V mains is discussed. The principles of operation and construction of controlled storage installations are discussed and concrete examples of their use in both grid-connected and island operation are quoted. Alternatives to storage are looked at from both the technical and economic points of view. The storage technologies used such as flywheels, supercaps, redox-flow batteries and lead-acid accumulators are briefly assessed and the results of simulations are discussed.
pumped storage plants; but these must be built as well since there is no correspondence with the pump and turbine operating times governed by normal network ...
The objective of this study is to describe the complete transport chain of CO2 between capture and storage including a ship transport. This last one is composed by the following steps:Shore terminal including the liquefaction, temporary storage and CO2 loading. Ship with a capacity of 30,000m^3. On or off shore terminal including an unloading system, temporary storage and export towards the final storage. Between all the possible thermodynamic states, the liquid one is most relevant two options are compared in the study (-50^oC, 7bar) and (-30^oC, 15bar). The ship has an autonomy of 6 days, is able to cover 1000km with a cargo of 2.5Mt/year. Several scenarios are studied varying the geographical position of the CO2 source, the number of harbours and the way the CO2 is finally stored. Depen...
from a military fuel storage facility released about 80,000 gallons of kerosine-based jet fuel. Immediate and extensive recovery measures managed to contain the spill, but...
from a military fuel storage facility released about 80,000 gallons of kerosine-based jet fuel. Immediate and extensive recovery measures managed to contain the spill, but...
We identify new organelles associated with the vacuolar system in plant cells. These organelles are defined biochemically by their internal content of three integral membrane proteins: a chimeric reporter...Full Text Available
... with the ability to capture imagery in raw 24-bit format, combined with large memory storage devices enable high resolution imagery to be captured ...
The operation of pumped-storage plants (PSP) is based on the daily load variations of power demand. It performs power generation at peak load times during the day, and pumps water up into the reservoir during the off-peak times at night. In the Taipower system in Taiwan, there are two pumped storage plants with ten units. These had a total installed capacity of 2,602 MW or a 12 percent capacity at the end of 1995. The plants were able to reduce system generation costs and improve reliability. A Pumped-Storage Plant Benefit Analysis (PSPBA) program was established using the principle of economic dispatch in 1985. This paper explains the rules of the program, the analysis results of the past 10 years, and a a cost benefit evaluation. It was found that the advantages of PSP are not only in supplying the power for peak load, but also in decreasing the total fuel cost. 5 figs., 4 refs.
A series of ball-on-disc wear and friction measurements were made for surfaces which have a chemical vapour deposition carbon silicon alloy layer on a carbon substrate (fine grain POCO graphite). Nitrogen ion irradiation was used to improve the wear resistance of the carbon alloy surface. For comparison, measurements were also taken for alumina against alumina. It was found that the lowest friction coefficient and lowest wear occurred for ion irradiated coated samples containing 4% Si in the alloy and that the performance was superior to that of alumina. ((orig.))
A series of ball-on-disc wear and friction measurements were made for surfaces which have a chemical vapour deposition carbon silicon alloy layer on a carbon substrate (fine grain POCO graphite). Nitrogen ion irradiation was used to improve the wear resistance of the carbon alloy surface. For comparison, measurements were also taken for alumina against alumina. It was found that the lowest friction coefficient and lowest wear occurred for ion irradiated coated samples containing 4% Si in the alloy and that the performance was superior to that of alumina. ((orig.)).
Research activity during the 1991--1992 funding period has been concerned with the following topics relevant to carbon monoxide activation. (1) Exploratory studies of water gas shift catalysts heterogenized on polystyrene based polymers. (2) Mechanistic investigation of the nucleophilic activation of CO in metal carbonyl clusters. (3) Application of fast reaction techniques to prepare and to investigate reactive organometallic intermediates relevant to the activation of hydrocarbons toward carbonylation and to the formation of carbon-carbon bonds via the migratory insertion of CO into metal alkyl bonds.
Research activity during the 1991--1992 funding period has been concerned with the following topics relevant to carbon monoxide activation. (1) Exploratory studies of water gas shift catalysts heterogenized on polystyrene based polymers. (2) Mechanistic investigation of the nucleophilic activation of CO in metal carbonyl clusters. (3) Application of fast reaction techniques to prepare and to investigate reactive organometallic intermediates relevant to the activation of hydrocarbons toward carbonylation and to the formation of carbon-carbon bonds via the migratory insertion of CO into metal alkyl bonds.
The accuracy of the carbon 14 dating method is dependent on the fluctuations of carbon 14 in the atmosphere over long periods of time. Fossil corals that are dated by both carbon 14 and uranium-thorium methods allows the setting of calibration curves for the carbon 14 method for the last 50.000 years. The uranium-thorium method is based on the measurement of the ratio of 2 isotopes: thorium 230 and uranium 234 that are both present in the decay chain of uranium 238. (A.C.)
A billet of low-density carbon-bonded carbon fiber (CBCF) composite is machined into a desired attenuator or load element shape (usually tapering). The CBCF composite is used as a free-standing load element or, preferably, brazed to the copper, brass or aluminum components of coaxial transmission lines or microwave waveguides. A novel braze method was developed for the brazing step. The resulting attenuator and/or load devices are robust, relatively inexpensive, more easily fabricated, and have improved performance over conventional graded-coating loads.
A process is claimed for selectively preparing a mixture of two-carbon atom oxygenated hydrocarbons, namely, acetic acid, ethanol and acetaldehyde, by continuously contacting a gaseous reaction mixture containing hydrogen and carbon monoxide with a solid catalyst comprising rhodium in combination with one or more alkali metals selected from the group consisting of lithium, potassium, cesium and rubidium at reaction conditions correlated so as to favor the formation of a substantial proportion of such two-carbon atom products.
... interactive surfaces and interfaces, and 3) the more complex a ... carbonate or calcium phosphate with a thin interface ... diameter) for nerve prosthesis. ...
Mixed microstructures have been studied in low- carbon microalloyed steels suitable for automotive applications, after continuous cooling from the hot-rolled condition. Microstructural features such as polygonal ferrite, bainitic and acicular ferrite and microphase constituent are identified using transmission electron microscopy. The influence of these mixed structures on the tensile strength, impact toughness and fracture behaviour is examined. It is found that improvements in impact toughness as compared with microalloyed medium- carbon ferrite/pearlite steels can be achieved from these predominantly acicular structures developed by controlling alloy composition and continuous cooling of these lower carbon steels. (orig.).
Mixed microstructures have been studied in low- carbon microalloyed steels suitable for automotive applications, after continuous cooling from the hot-rolled condition. Microstructural features such as polygonal ferrite, bainitic and acicular ferrite and microphase constituent are identified using transmission electron microscopy. The influence of these mixed structures on the tensile strength, impact toughness and fracture behaviour is examined. It is found that improvements in impact toughness as compared with microalloyed medium- carbon ferrite/pearlite steels can be achieved from these predominantly acicular structures developed by controlling alloy composition and continuous cooling of these lower carbon steels. (orig.).
...Investigating Biochar: from Source to Sink (Overview - Research) The Sustainable Agriculture Flagship is leading national collaborative research analysing the properties ...and potential of a variety of biochars to improve soil health and sequester carbon. The Sustainable Agriculture Flagship is leading national collaborative research ...analysing the properties and potential of a variety of biochars to improve soil health and sequester carbon. Biochar, sustainable agriculture, soil,...carbon, SAF, pyrolysis, fertiliser, biochar, soil types, greenhouse gas, herbicide, pesticide, bioenergy, soil science, carbon-rich solid, ...
The Forsmark and the Laxemar investigation areas are examined by the Swedish Nuclear Fuel and Waste Management Co. for a possible construction of a deep repository for nuclear waste. In the case of a future leakage of waste, the radioactive isotopes could end up in the ecosystems above the repository. The fate of the radionuclides and their possible radiological impacts are then highly determined by ecosystem carbon cycling. An important part of the carbon cycling is the soil carbon effluxes, and in the investigation areas soil carbon effluxes have been examined with the closed chamber technique. This paper is divided into two parts. Firstly, there were problems with the equipment measuring the soil carbon dioxide efflux, and the first part is a description of the problem, how it was corrected and its possible causes. The second part is a manual in how to analyse data and calculate ...
The present report concerns a research for the tritium and for the carbon 14 in lichens in a spirit of bio-indication: the first results appear in Daillant and al (2004 ) and additional results were presented to the congress B.I.O.M.A.P. in Slovenia, organized collectively by the institute Josef Stefan from Ljubljana and the international atomic energy agency from Vienna (Daillant and al 2003). (N.C.)
The thermodynamic characteristics of adsorption of sulfur-containing amino acids and their derivatives on the surface of graphitized thermal carbon black were calculated by the molecular statistical method. The parameters of the atom-atom potential function of intermolecular interaction between the S atom in amino acids and the graphite C atom were determined. It was shown that an intramolecular H-bond influenced the adsorption of amino acids on the surface of graphitized thermal carbon black.
The thermodynamic characteristics of adsorption of sulfur-containing amino acids and their derivatives on the surface of graphitized thermal carbon black were calculated by the molecular statistical method. The parameters of the atom-atom potential function of intermolecular interaction between the S atom in amino acids and the graphite C atom were determined. It was shown that an intramolecular H-bond influenced the adsorption of amino acids on the surface of graphitized thermal carbon black.
In this paper, the analysis of carbonate depositional systems, using high resolution sequence stratigraphy, studies the ratio between change in accommodation space and skeletal carbonate production. This approach establishes the concurrent change in nature of facies belts (expansion, retraction and type) and fossil communities, within the detailed time frame in accommodation. Carbonate production is generally considered to be a fairly simple function of environmental conditions such as climate and water depth. However, data from several case studies also show a covariance between change in stratigraphic architecture of carbonate systems (the seaward or landward stepping stacking patterns of stratigraphic units) and charge in facies. Case studies include Carboniferous algal mound development in the Paradox Basin (USA), Devonian stromatoporoid reef development in Alberta (Canada), and Cenomanian rudistid ...
In this paper structure and mechanical properties of PBZT and PBO fibers are briefly discussed. One limitation of the high-modulus polymeric fibers and ultrahigh-modulus carbon fibers in reinforced composites is their poor compressive strength. Issues related to the compressive strength of polymeric and carbon fibers are considered. 62 references, 7 figures, 4 tables.
The observed strength of the carbon dioxide absorption bands recorded on spectrobolograms of the transparency of the earth's atmosphere between wavelengths 300 and 2500 nanometers as part of the Smithsonian Solar Constant Program were used to extract the abundance of carbon dioxide in the atmosphere. The details of the analysis and the sources of error are discussed. 11 references, 5 figures, 1 table. (ACR)
The objective of this research is to gain a better understanding of the corrosion of the aluminized type 316 stainless steel employed in the seal areas of the molten carbonate fuel cell. The seals are formed between the aluminized Type 316 SS surface and the electrolyte (generally a mixture of molten alkali carbonates and lithium aluminate).
DescriptionThe overall objective of the project is to provide an improved understanding of the processes and linkages through which organic carbon additions influence soil bio-physical and physico-chemical properties. Soil organic carbon (SOC) levels and turnover rates are intimately linked to the soil properties that are important in the maintenance of soil quality and fertility, and sustainable crop production. However, it has been difficult to distinguish the various processes and linkages through which [continued...
Mutual influence of phosphorus and carbon on the tendency to integranular corrosion (IGC) of tempered austenitic stainless steels in boiling solutions of 65% HNO_3 and 27% of HNO_3+40 g/l Cr"6"+ was investigated. It is ascertained that under the action of carbon additions susceptibility of phosphorus-containing steels to IGC increases considerably in pure nitric acid and decreases in nitric acid containing the oxidant. Possible reasons for the effects observed are discussed.
Characteristics of advanced composites are investigated. The fibers considered are Kevlar and carbon. The greatest advantage of composites over metals is emphasized, and lies in their permitting designers to obtain properties in exactly the locations desired. Kevlar replaced S-glass on the Trident 2 missile, saving 800 lbs. and adding 800 miles to its range. Military aircraft builders find that advanced carbon composites more often than not win out over Kevlar.
In this article carbon co-implantation and step-by-step thermal treatments of shallow p"+-n-junctions formation were used with the purpose of extended defect suppression and reduction of boron transient enhanced diffusion. A substantial improvement of the structural and electrical parameters of shallow p"+-n-junctions has been achieved by using the additional carbon implantation and step-by-step thermal treatments. (authors)
This document generates a supernatant hydroxide ion depletion model based on mechanistic principles. The carbon dioxide absorption mechanistic model is developed in this report. The report also benchmarks the model against historical tank supernatant hydroxide data and vapor space carbon dioxide data. A comparison of the newly generated mechanistic model with previously applied empirical hydroxide depletion equations is also performed.
This paper investigates the spectral characteristics of three-dimensionally porous carbon dioxide indicators based on a porous silicate glass and phenolphthalein. The absorption spectra of the original solutions of phenolphthalein in alkaline and acid solutions are shown. The solutions were acidified by bubbling CO/sub 2/ through an alkaline phenolphthalein solution. The authors have succeeded in producing a reversible colorimetric adsorption indicator for carbon dioxide which after proper calibration enables the CO/sub 2/ content of an atmosphere to be estimated quantitatively.
The carbon isotope profiles of shallow-marine carbonates from the Barremian-Aptian Kharaib and Shuaiba formations of the Arabian Gulf region range between 0.5 and 7{per_thousand} {delta}{sup 13}C PDB (Peedee belemnite). Systematic variations can be correlated with isotope profiles reported from Tethyan pelagic limestone sequences. The detailed correspondence between the isotopic signature of the relatively well-dated pelagic limestones and the poorly dated shallow-water limestones from the Arabian Gulf region suggests that global marine carbon isotope changes apparently affected deep-sea and shallow-water carbonate sediments similarly and at a similar time resolution. Although oxygen isotopes have been reset during diagenesis, carbon isotopes appear to have maintained their primary marine signature through time. No evidence has been found to connect carbon ...
Henry constants for the adsorption of o- and p-phenylenediamines on the surface of graphitized thermal carbon black within the temperature range 433?479 K were calculated by the molecular statistical method. The parameters of the atom-atom potential function of intermolecular interaction between the nitrogen atom in aniline and isomeric phenylenediamines and the carbon atom of the basal face of graphite were determined. It was shown that an intramolecular H bond influenced the geometry and adsorption properties of o-phenylenediamine.
Henry constants for the adsorption of o- and p-phenylenediamines on the surface of graphitized thermal carbon black within the temperature range 433-479 K were calculated by the molecular statistical method. The parameters of the atom-atom potential function of intermolecular interaction between the nitrogen atom in aniline and isomeric phenylenediamines and the carbon atom of the basal face of graphite were determined. It was shown that an intramolecular H bond influenced the geometry and adsorption properties of o-phenylenediamine.
Carbon films have been made by a variety of techniques, including evaporation, sputtering, and laser or thermal pyrolysis of organic polymers. Polyacrylonitrile (PAN) is often used as a carbon precursor, since low-temperature thermo-oxidative pretreatment produces a material which can be pyrolyzed without loss of shape. This is the basis for the production of carbon fibers with good mechanical properties. We report here the formation of very thin films of carbon (500 to 1500 A) by pyrolysis of spin-cast PAN. Using this technique, large, conductive films can be made which are sufficiently robust to allow intact lift-off and transfer of the films from one substrate to another. Such films are chemically inert, but can be photolithographically patterned and etched with an oxygen plasma.
This is a process for manufacturing a semi-rigid, folding solar generator manufactured from several coated solar cells (Cics), which has at least two folding parts connected together so as to turn by hinges, characterized by the following stages of the process: a) On the back of matrix subsections, in order to cover the connector, carbon fibre strips are glued on, which project over the upper or lower edge of each matrix subsection. b) The projecting ends of adjacent carbon fiber strips are connected with two carbon fibre strips. c) At least two matrix subsections are fixed in separately manufactured carbon fiber frames, and d) the carbon fiber frames, together with the matrix subsections are connected via hinges to a solar generator.
The shift to renewable energy options and low-carbon technologies, in response to the concerns over energy security and climate change, is proceeding more slowly than many would like. The usual argument against rapid deployment of new technologies is the costs imposed on the economy, commonly interpreted in terms of upfront costs to be borne or involving large cash transfers to fund, for example, efforts to preserve rainforests. In this contribution I argue that such a perspective provides a continuing barrier to taking effective action, whereas a perspective based on creation and use of carbon credits provides a means of avoiding the shock of abrupt industrial change. Carbon credits granted for bona fide carbon load reductions could be created through private initiative, for example by me...
The document provides: An overview of CCS technology including what plant equipment is novel and what is currently in use within the CCS or other industries; An in depth guide to carbon dioxide to broaden the readers understanding of the material and its health and safety issues; Key design features of plant and pipelines for carbon dioxide service including experience gained from the industrial gases sector; and Key operational information for plant and pipelines for carbon dioxide service including experience gained from the industrial gases sector to ensure that your operating practices take into account the latest operational experiences from carbon dioxide plant. 45 figs., 18 tabs.
A pilot cropland carbon sequestration program within north central Montana has allowed farmers to receive carbon credit for management adjustments associated with changing from tillage-based agricultural systems to no-till. Carbon credit can also be obtained by adopting conservation reserve, where cropland is planted into perennial vegetation. Summer fallowing is also considered within the crediting process as credit is not given in years that a field is left un-vegetated. The carbon sequestration program has been advocated as a means to mitigate climate change while providing an added source of income for Montana farmers. There is lack of data, however, pertaining to the percentage of lands within this region that have not converted to no-till management, lands under certain crop intensit...
The authors report here, for the first time, high frequency testing of a new type of electrochemical double layer capacitor (EDLC), based on carbon aerogels: the Aerocapacitor. Carbon aerogels, are a novel type of carbon foam developed by Lawrence Livermore National Laboratory for military applications. The unique properties of carbon aerogels, high surface area (700 m{sup 2}/g), high density (1g/cc), well controlled pore diameter and high material conductivity (25 S/cm) made it an ideal EDLC electrode material. Using carbon aerogel as the electrode material, the authors have developed Aerocapacitors. These new EDLC`s have a frequency response comparable to that of aluminum electrolytic capacitors and are thus ideally suited to power conversion applications.
This objective of this work was to summarize the main results obtained in previous papers related to the adsorbent-adsorbate interactions involved in the adsorption of naphthalenesulphonic acids and heavy metals (Cd(II) or Hg(II)) by modified activated carbons. The adsorption of organic compounds (1-naphthalenesulphonic acid, 1,5-naphthalenedisulphonic acid and 1,3,6-naphthalenetrisulphonic acid) and inorganic species (Cd(II) and Hg(II)) was studied on a series of ozonized activated carbon in aqueous phase. Commercial activated carbon (Filtrasorb 400) was treated with different ozone doses to study the effect of ozone treatment on its surface properties and investigate the behavior of the treated carbon samples in the above adsorption processes. After ozonation, carbonyl- and carboxyl-type...
The characteristics of per-fluorocarbon compounds (PFC) are colorless, non-toxic, easily vaporized and nonflammable. Also, some of them are liquids of a high density, low surface tension, low latent heat and low specific heat. These particular chemical and physical properties of fluoro-organic compounds permit their use in very different fields such as electronics, medicine, tribology, nuclear and material science. The Sonatol process was developed under a contract with the DOE. The Sonatol process uses an ultrasonic agitation in a PFC solution that contains a fluorinated surfactant to remove radioactive particles from surfaces. Filtering the suspended particles allows the solutions to be reused indefinitely. They applied the Sonatol process to the decontamination of a heterogeneous legacy Pu-238 waste that exhibited an excessive hydrogen gas generation, which prevents a transportation of such a waste to a Waste Isolation Pilot Plant. Korea Atomic Energy Research Institute (KAERI) is ...
This article describes acoustic methods used in the in-service inspection of the dams and peripheral concrete structures of the Toktogul, Kurpsai, and Bratsk hydroelectric and pumped storage plants. The tests were conducted to assess the compression strength, elasticity, and tensile strength of the concretes. Comparative evaluations against drill core studies proved the acoustic methods to be sufficiently accurate in predicting aging behavior and loss of mechanical and physical integrity in the concretes.
Photoinduced charge separation reactions form the basis for energy storage processes in both natural and artificial photosynthesis. Moreover, rapid reversible photoinduced electron transfer reactions are a class of photophysical phenomena that can be exploited to develop schemes for optical switching. Examples from each of these fields are discussed.
Cooling of residential California buildings contributes significantly to electrical consumption and peak power demand mainly due to very poor load factors in milder climates. Thermal mass can be utilized to reduce the peak-power demand, downsize the cooling systems, and/or switch to low-energy cooling sources. Large thermal storage devices have been used in the past to overcome the shortcomings of alternative cooling sources, or to avoid high demand charges. The manufacturing of phase change material (PCM) implemented in gypsum board, plaster or other wall-covering material, would permit the thermal storage to become part of the building structure. PCMs have two important advantages as storage media: they can offer an order-of-magnitude increase in thermal storage capacity, and their discharge is almost isothermal. This allows the storage of high amounts of energy without ...
In a funded program at the Lawrence Livermore National Laboratory new materials and novel designs are being incorporated into a new approach to an old concept -- flywheel energy storage. Modular devices, dubbed ``electromechanical batteries`` (EMB) are being developed that should represent an important alternative to the electrochemical storage battery for use in electric vehicles or for stationary applications, such as computer back-up power or utility load-leveling.
It is shown that the interpretation of the experimental results reported in the publication "Storage of Light in Atomic Vapor" by D.F.Phillips et al., Phys. Rev.Lett. 86, 783 (2001) [quant-ph/0012138] is incorrect. The experimental observation of this paper can be consistently explained in the framework of standard concepts of the physics of optical pumping and has nothing to do with "storage of light", or "dynamic reduction of the group velocity", or "light pulse compression".
Previous models and evaluation techniques based on the Monte Carlo simulation for the reliability assessment of mixed hydrothermal generation systems are extended. Models for reservoirs on multiple rivers and pumped storage plants are developed. Operating and water management policies are extended to include the relative economical effects of operating alternative sources of generation. These effects and the benefits are described and discussed using an extended IEEE reliability test system. (Author).
Pumped storage plants (PSP) supply up to several GW of power and several ten GWh of capacity. Short start-up times and low start-up costs predestine PSP for the control energy market. Grid charges for PSP endanger the further integration of renewable energy and lead to higher electricity supply costs. Therefore, an amendment of legislation is urgently required. Requirements for building large PSP are met at numerous sites in the low mountain ranges of Germany. (orig.)
This paper suggests how nonlinear periodic optimal control of a pumped storage plant can be realized. The control problem consists in maximization of the plant benefits over an operational period. An optimal control law is proposed, yielding a bang-off-bang mode of operation. An algorithm for numerical solution of the problem was developed, and its effectiveness was demonstrated by simulation experiments.
A method for bistable storage of binary optical information includes an antiferroelectric (AFE) lead lanthanum zirconate titanate (PLZT) layer having a stable antiferroelectric first phase and a ferroelectric (FE) second phase obtained by applying a switching electric field across the surface of the device. Optical information is stored by illuminating selected portions of the layer to photoactivate an FE to AFE transition in those portions. Erasure of the stored information is obtained by reapplying the switching field.
The High-Level Waste Storage Tank Farms/242-A Evaporator Standards/Requirements Document (S/RID) is contained in multiple volumes. This document (Volume 2) presents the standards and requirements for the following sections: Quality Assurance, Training and Qualification, Emergency Planning and Preparedness, and Construction.
This paper mainly deals with the charging processes of a cylindrical heat storage capsule filled with stearic acid, sliced paraffin and lauric acid as phase-change materials (PCMs). Experimental results demonstrate that, compared to the capsule with a single PCM, the charging rate of the capsule employing three PCMs is enhanced obviously. (author)
Within the Westeuropean network of the electric current supply a continuing compensation is necessary with respect to the permanent alterations of capacity and frequency. Pumped-storage plants are of considerable significance to meet these requests. The Schluchseewerk AG, Freiburg/Breisgau, has among others five pumped-storage plants in the southern part of the Black Forest. The conception and the operation of them are described. (orig.).
The technology status of the dynamics and controls discipline as it applies to energy storage wheel systems was evaluated. No problems were identified for which an adequate solution could not be proposed. Design issues that influence control were addressed. The dynamics and control aspects associated with the energy storage system concept and its various constituent parts, and the control tasks attendant to large, manned spacecraft are discussed.
A preliminary study of two different kinds of solar receivers (a rotating cavity receiver and a volumetric receiver) suitable to operate in the 1 kW solar facility at the University of Rome is presented. Possible applications of solar energy in the aluminum extraction from leucite and chemical storage by the CuO/Cu[sub 2]O cycle are presented and discussed. (author).
Protein bodies within the endosperm of castor bean (Ricinus communis L. cv. Hale) seeds arise from numerous small vacuoles which progressively become filled with storage protein, of...Full Text Available
The Interim Decay Storage tank (IDS) will be located in a concrete cell in the FFTF reactor building. The tank will have capacity to store 112 driver fuel assemblies and 10 test assemblies in sodium. A criticality safety analysis for the design of the IDS tank was performed. From the analysis, it is concluded that under normal operating conditions and minor abnormal conditions that might shift the fuel, the IDS tank will remain adequately subcritical. (auth)
The invention concerns a container for the long term storage of irradiated nuclear reactor fuel elements, which consists mainly of a basic body, at least one lid and an outside ring shaped lid tightening device, which acts on the basic body and the lid and holds the contact surface of the lid tight against the contact surface of the basic body, where the basic body, lid and the lid tightening device consist of corrosion-proof materials. (orig./HP).
Data for estimating average construction costs and operation and maintenancerequirements are presented for combined sewer overflow treatment plants ranging from about 5 to 200 million gallons per day in capacity, and storage facilities ranging in size from I to 240 million gallon...
We propose a system for the on-line monitoring of short and medium term radioactive waste repositories. Such a system is distributed, fine-grained, robust, reliable, and must be based on low-cost components. It could, in principle, open new perspectives on the modality of waste packaging and storage. In particular we propose to employ a new family of cheap and powerful micro sensors to be placed in shape of a fine grid around each single drum. (authors)
Carbons derived from the phase separation of polyacrylonitrile/solvent mixtures were investigated as lithium intercalation anodes for rechargeable lithium-ion batteries. The carbon electrodes have a bulk density of 0.35-0.5 g/cm{sup 3}, relatively low surface areas (< 10 m{sup 2}/g), and micron-size cells. Pyrolysis temperature influences the reversible lithium intercalation and the irreversible capacity (associated with the formation of the passivating layer). Carbon electrodes pyrolyzed at 600{degrees}C have first-cycle capacity as high as 550 mAh/g as well as large irreversible capacity, 440 mAh/g. Electrodes prepared at 1050{degrees}C have reversible capacities around 270 mAh/g with relatively lower capacity losses (120 mAh/g). Doping the organic precursors with phosphoric acid, prior to pyrolysis at 1050{degrees}C, leads to carbon electrodes with reversible capacities as high as 450 mAh/g. The ...
The carbon transfer has been analyzed in the Alloy 800/sodium/stainless steel system by determining the carbon-uptake of Alloy 800 foils, which were exposed in liquid sodium of known carburizing potential. Under equilibrium condistions between 650 and 550_0C the measured total carbon concentrations in the Alloy 800 tabs were found to be roughly related to the carbon activities of the sodium environment by the equation already stated for the 18 Cr-8/10 Ni stainless steels, extrapolated to the chemical composition of the Ni-rich austenitic alloy. However the Alloy 800 was not found to undergo any decarburization in low-carbon activity environments. The carbon diffusion kinetics was determined as a function of temperature, it was found to be similar to that reported for the AISI-304 type of steel. The effects of sodium exposure on microstructural and mechanical ...
The carbon transfer has been analyzed in the Alloy 800/sodium/stainless steel system by determining the carbon-uptake of Alloy 800 foils, which were exposed in liquid sodium of known carburizing potential. Under equilibrium conditions between 650 and 550/sup 0/C the measured total carbon concentrations in the Alloy 800 tabs were found to be roughly related to the carbon activities of the sodium environment by the equation already stated for the 18 Cr-8/10 Ni stainless steels, extrapolated to the chemical composition of the Ni-rich austenitic alloy. However the Alloy 800 was not found to undergo any decarburization in low-carbon activity environments. The carbon diffusion kinetics was determined as a function of temperature, it was found to be similar to that reported for the AISI-304 type of steel. The effects of sodium exposure on microstructural and mechanical ...
Capacitance dispersion on the fractal carbon electrode with edge and basal orientations was investigated using atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and a.c.-impedance spectroscopy. For this purpose, four types of as-received pyrolytic graphite electrode, as-received, mechanically polished, and as-activated glassy carbon electrodes were prepared with different surface irregularities and amounts of edge orientations. The apparent self-similar fractal dimensions of the carbon electrodes were determined from the analyses of AFM images based upon triangulation method. The amounts of edge orientations on the surface of the carbon electrodes were qualitatively estimated from the XPS analysis of surface acidic functional groups that were preferably formed on the edge planes by the heat treatment of the carbon electrodes. The values of the constant phase ...
An approximate solution was proposed in which a sensitivity analysis by the storage and release of heat was performed for the subject issues and in which an operating method was thereby determined for the equipment constituting the system by means of a linear programming. Accordingly, a heat storage type energy supply system for a district cooling and heating was taken up as a concrete object to be examined. This system consisted of a gas turbine generator, initial power receiving equipment, gas boiler, electric heat pump for ice heat storage, cooling tower, heat exchanger, steam absorbing refrigerating machine, ice heat storage tank, cold and warm water heat storage tank, etc. As a result of comparison between the proposed method and the resolving method, the former showed -0.92 to 2.58% in the increase in the operating cost compared with the latter. A case where the operating cost ...
There are 4 CANDU reactors at Wolsung site together with a spent fuel dry storage associated with unit 1. These CANDU reactors, classified as On-Load Reactor (OLR) for Safeguards application, change 16- 24 fuel bundles with fresh fuel in everyday. Especially, the spent fuel bundles are transferred from spent fuel bays to dry storage throughout a year because of the insufficient capacity of spent fuel pond. Safeguards inspectors verify the spent fuel transfer to meet safeguards purposes according to the safeguards criteria by means of inspector's presence during the transfer campaign. For the verification, 60-80 person-days of inspection (PDIs) are needed during approximately 3 months for each unit. In order to reduce the inspection effort and operators' burden, an Unattended Monitoring System (UMS) was designed and developed by the IAEA for the verification of spent fuel bundles transfers from wet storage ...
The objective of the project was to provide a readily understandable and usable methodology for preliminary analysis of the economic benefit that can accrue from the use of thermal energy storage for building heating and cooling. The procedure was to be capable of providing an estimate of cooling plant and storage size, as well as the monthly savings that can be saved. The research focused on the development of a procedure for a limited class of commercial and institutional buildings in North Carolina. A simplified procedure for analyzing the potential for using thermal energy storage (TES) in such buildings in North Carolina was developed. The procedure developed consists of charts and nomographs that can be used for estimating the size of TES systems, and for estimating the monthly demand savings. The monthly demand savings can be combined with the applicable rate schedule to determine the annual cost savings. An overview ...
The trade-off which must be established between the various functions of pumped-storage plants is examined. A compromise between supply security and economic planning can be found only by coordinated planning of pumped-storage units and thermal generation plants. A model used by Electricite de France (EDF) to ensure optimized daily planning of thermal and pumped-storage units is described. The model, called the DEMETER model, ensures the optimization of the daily planning of thermal and pumped-storage plants. The model iterates between two levels: coordination where the prices of the generated energy and the operating reserve are determined to adjust generation to load and keep a sufficient reserve; and decomposition where the schedule of each unit is optimized on the basis of the above prices and taking into account local constraints such as unavailability, and minimum shut down time. The role of EDF ...
The Underground Hydroelectric Pumped Storage (UHPS) Program Plan describes in detail the planned activities and expected accomplishments in the conduct of UHPS technology development and validation envisioned in the 1976 to 1990 time frame. This document describes the program objectives, implementation strategy, and management methodology. The concept of underground hydroelectric pumped storage is fully directed to application in the electric utility industry. This technology involves using electrical energy generated by base-load plants during off-peak load periods to drive a high-head pump/turbine which pumps water from a lower reservoir to a substantially elevated (upper) reservoir corresponding to a head of 1000 m or so. The upper reservoir is at ground level and the lower reservoir is below ground. Then, during peak-load periods, water in the upper reservoir is allowed to flow to the lower reservoir which, in turn, drives a hydraulic ...
A cooling system was developed which could be used even in such areas where the maximum and minimum temperatures of a day might differ widely. The system features in that a latent heat storage unit is connected to the natural circulation cooling unit consisting of 2 heat exchangers where condensed gas (refrigerant) which performs gas-liquid change has been sealed, enabling to cool objects night and day without the requirement for any power source. Electronic equipment was installed in an insulated shelter. Lauric acid and refrigerant R-22 were used as the latent heat storage medium and the heat transport medium respectively. Natural convection heat transfer performance of the outside surfaces of the condenser and the evaporator and the transient behavior of the system during the melting and solidification periods of the latent heat storage medium were tested. As a result of a 48 hour simulation experiment with load ...
As shown in various new examples, HABOG facility (Netherlands), CERNAVODA (Candu - Romania), KOZLODUY (WWER - Bulgaria), CHERNOBYL ( RMBK - Ukraine), MAYAK (Spent Fuel from submarine and Icebreakers - Russia), recent studies allow to confirm the flexibility and performances of the CASCAD system proposed by SGN, both in safety and operability, for the dry storage of main kinds of spent fuel. The main features are: A multiple containment barrier system: as required by international regulation, 2 independent barriers are provided (tight canister and storage pit); Passive cooling, while the Fuel Assemblies are stored in an inert atmosphere and under conditions of temperature preventing from degradation of rod cladding; Sub-criticality controlled by adequate arrangements in any conditions; Safe facility meeting ICPR 60 Requirements as well as all applicable regulations (including severe weather conditions and earthquake); Safe handling operations; ...
This work presents comparative results of a numerical investigation of four possible models for the prediction of thermal performance of fixed bed storage units and their thermal design. These models includes Schumann's model, the radial dispersion model, a model that include both axial heat conduction in the fluid phase and admits thermal gradient in the solids particles and finally a two dimensional single phase model. For each of these models a computer code was written and tested to evaluate the computing time of same data and analyze any other computational problems. The tests of thermal performance included particle size, porosity, particle material, flow rate, inlet temperature and heat losses form tank walls and extremities. Dynamics behaviour of the storage units due to transient variation in either flow rate or inlet temperature was also investigated. The results presented include temperature gradients, pressure drop and heat ...
A lightweight, low permeability liner for graphite epoxy composite compressed gas storage vessels. The liner is composed of polymers that may or may not be coated with a thin layer of a low permeability material, such as silver, gold, or aluminum, deposited on a thin polymeric layer or substrate which is formed into a closed bladder using torispherical or near torispherical end caps, with or without bosses therein, about which a high strength to weight material, such as graphite epoxy composite shell, is formed to withstand the storage pressure forces. The polymeric substrate may be laminated on one or both sides with additional layers of polymeric film. The liner may be formed to a desired configuration using a dissolvable mandrel or by inflation techniques and the edges of the film seamed by heat sealing. The liner may be utilized in most any type of gas storage system, and is particularly applicable for hydrogen, gas ...
Under Federal law, the Department of Energy (DOE) is responsible for safe disposal of Greater-Than-Class C Low-Level Waste (GTCC LLW) generated by licenses of the Nuclear Regulatory commission (NRC) or Agreement States. Such waste must be disposed of in a facility licensed by the NRC. It is unlikely that licensed disposal of GTCC LLW will be available prior to the year 2010. Pending availability of disposal capacity, DOE is assessing the need for collective, long-term storage of GTCC LLW. Potential risks to public health and safety caused by long-term storage of GTCC LLW at the place of generation will be evaluated to determine if alternative facilities are warranted. If warranted, several options will be investigated to determine the preferred alternative for long-term storage. These options include modification of an existing DOE facility, development of a new DOE facility, or development of a facility by the private ...
AIM: To define the value of digital radiography with a clinical flat panel detector system for evaluation of wrist fractures in comparison with state of the art storage phosphor radiography. MATERIAL AND METHODS: Hard copy images of 26 fractured wrist specimens were acquired with the same exposure dose on a state of the art storage phosphor radiography system and a clinical flat panel detector. Image features like cortical bone surface, trabecular bone, soft tissues and fracture delineation were independently analysed by 4 observers using a standardised protocol. Image quality ratings were evaluated with an analysis of variance (ANOVA). RESULTS: Flat panel detector radiographs were rated superior with respect to cortical and trabecular bone representation as well as fracture evaluation, while storage phosphor radiographs produced better soft tissue detail. CONCLUSION: In some of the observed image quality aspects, the ...
AIM: To define the value of digital radiography with a clinical flat panel detector system for evaluation of wrist fractures in comparison with state of the art storage phosphor radiography. MATERIAL AND METHODS: Hard copy images of 26 fractured wrist specimens were acquired with the same exposure dose on a state of the art storage phosphor radiography system and a clinical flat panel detector. Image features like cortical bone surface, trabecular bone, soft tissues and fracture delineation were independently analysed by 4 observers using a standardised protocol. Image quality ratings were evaluated with an analysis of variance (ANOVA). RESULTS: Flat panel detector radiographs were rated superior with respect to cortical and trabecular bone representation as well as fracture evaluation, while storage phosphor radiographs produced better soft tissue detail. CONCLUSION: In some of the observed image quality aspects, the ...
The Savannah River Site (SRS) is currently developing a new facility, the Actinide Packaging and Storage Facility (APSF), to process and store legacy materials from the United States nuclear stockpile. A variety of materials, with a variety of properties, packaging and handling/storage requirements, will be processed and stored at the facility. Since these materials are hazardous and radioactive, automation will be used to minimize worker exposure. Other benefits derived from automation of the facility include increased throughput capacity and enhanced security. The diversity of materials and packaging geometries to be handled poses challenges to the automation of facility processes. In addition, the nature of the materials to be processed underscores the need for safety, reliability and serviceability. The application of automation in this facility must, therefore, be accomplished in a rational and disciplined manner to satisfy the strict ...
The conversion of off-peak surplus electricity into peak electricity through an electrolyzer, hydrogen storage, and fuel cell energy storage system was discussed. Development efforts in high pressure alkaline electrolysis and Proton-Exchange Membrane (PEM) fuel cells have improved the near-term viability of these systems. Potential use of wind turbines and other renewable energy-based generation systems, through hydrogen-based energy storage, were discussed as a new supply of surplus electricity. An integrated set of nomographs were presented for providing quick estimates of peak electricity costs derived from an electrolyzer/hydrogen fuel cell system. The nomographs allowed first order cost comparisons of centralized versus distributed hydrogen energy systems considering trade-offs between production economies of scale and hydrogen storage and transport costs. Use of the nomographs to compare ...
To prepare porous carbons with high adsorption capacity from rice straws, two different kinds of precursors, i.e. one as the raw rice straws (one-stage process) and the other as pre-carbonized rice straws (two-stage process), were active with KOH of various impregnation ratios. The two-stage process was found very effective for manufacturing porous carbons with high surface area and adsorption capacities for MB and I{sub 2}. For example, the porous carbon that was carbonized at 700{sup o}C and subsequently activated at 900{sup o}C exhibited the surface area of 2410 m{sup 2}/g, the adsorption capacities of 800 and 1720 mg/g for MB and I{sub 2}, respectively, and the total pore volume of 1.4 ml/g. In the two-stage method, there was a preferential optimum impregnation ratio of KOH to a precursor carbon, i.e. 4:1, with which high surface area of porous ...
The performance of intermolecular potential models on the adsorption of carbon tetrachloride on graphitized thermal carbon black at various temperatures is investigated. This is made possible with the extensive experimental data of Machin and Ross(1), Avgul et al.,(2) and Pierce(3) that cover a wide range of temperatures. The description of all experimental data is only possible with the allowance for the surface mediation. If this were ignored, the grand canonical Monte Carlo (GCMC) simulation results would predict a two-dimensional (2D) transition even at high temperatures, while experimental data shows gradual change in adsorption density with pressure. In general, we find that the intermolecular interaction has to be reduced by 4% whenever particles are within the first layer close to the surface. We also find that this degree of surface mediation is independent of temperature. To understand the packing of carbon ...
In this paper we investigate the effects of surface mediation on the adsorption behavior of argon at different temperatures on homogeneous graphitized thermal carbon black and on heterogeneous nongraphitized carbon black surface. The grand canonical Monte Carlo (GCMC) simulation is used to study the adsorption, and its performance is tested against a number of experimental data on graphitized thermal carbon black (which is known to be highly homogeneous) that are available in the literature. The surface-mediation effect is shown to be essential in the correct description of the adsorption isotherm because without accounting for that effect the GCMC simulation results are always greater than the experimental data in the region where the monolayer is being completed. This is due to the overestimation of the fluid-fluid interaction between particles in the first layer close to the solid surface. It is the surface mediation ...
The aim of this paper was to describe ability to intercalation of laboratory prepared carbon composites and their constituents. In work the following materials were tested; pinch-based fibres of P-120 and K-1100 manufacturer's designations, carbon matrix and resulting composites. To prepare a matrix of composites, phenol-formaldehyde resin (Z) and pinch-based precursor (PAK) were used. After initial carbonization, the carbon matrix was heated to 2150 "oC i to improve ability to the future intercalation. Three kinds of composites (P/Z, K/Z and K/PAK), with two directional reinforcement (2D), were prepared. All carbon samples were intercalated with copper chloride(II). To study the structure of all materials, before and after intercalation, X-ray diffraction method was used. It enabled to measure microstructure parameters (L_c and L_a), interplanar distance (d_0_0_2) thickness of an ...
Remote Alaskan communities pay economic and environmental penalties for electricity, because they must import diesel as their primary fuel for electric power production, paying heavy transportation costs and potentially causing environmental damage with empty drums, leakage, and spills. For these reasons, remote villages offer a viable niche market where sustainable energy systems based on renewable resources and advanced energy storage technologies can compete favorably on purely economic grounds, while providing environmental benefits. These villages can also serve as a robust proving ground for systematic analysis, study, improvement, and optimization of sustainable energy systems with advanced technologies. This paper presents an analytical optimization of a remote power system for a hypothetical Alaskan village. The analysis considers the potential of generating renewable energy (e.g., wind and solar), along with the possibility of using energy ...
This report investigates methods to utilize existing bulk tobacco kilns for curing (drying) of shelled corn, peanuts, and baled hay. In recent years Ontario tobacco producers have had to reduce production levels due to a declining demand for flue-cured tobacco. Many tobacco producers are currently diversifying into other crops. Some of these crops require curing and/or storage. Because of high capital costs to purchase conventional curing and/or storage facilities, tobacco producers wish to reduce their initial diversification costs by modifying their existing tobacco kilns (tobacco drying structures) and/or tobacco storage barns for this purpose. The investigation included high profile and low profile downdraft stick kilns, bulk kilns, and tobacco storage (pack) barns. Corn, peanuts, and hay were considered in relation to bulk kiln specifications and modifications, handling, drying and ...
We examined, using thermo analytical methods, the effects of 2000 deg. C heat-treated graphite powders and heating rate of cure after impregnation on the thermal stability and carbon yield of furfuryl alcohol, which is frequently used not only as an impregnation but also as a matrix precursor for carbon fiber-reinforced carbon composites. It was founded that the addition of 30 wt%. graphite powders of furfuryl alcohol and the heating rate 35 deg. C/min showed the highest thermal stability of furfuryl alcohol/graphite powder mixture. The carbon yield above 1000 deg. C was enhanced more than 10% in comparison with the absence of graphite powders. It would be expected that this result can contribute to some extent to reduce the repeating number of processing cycle (carbonization {yields} impregnation {yields} cure {yields} re-carbonization) required to density a ...
Removal of sulfonamide (SAs) and tetracycline (TAs) classes of antibiotic compound from deionized water and DOC water by powdered activated carbon (PAC) adsorption was evaluated in this study. According to the study results, TAs were more easily adsorbed than SAs although TAs were more hydrophilic than SAs. The phenolic compounds in TAs might be responsible for their high adsorption. Complex formation of TAs with metal and metal oxide on the surface of activated carbon might also contribute to higher adsorption. The hydrophobic effect was important for removal of SAs. More hydrophobic SAs were removed more easily. The carbon type was not important for adsorption of SAs and TAs. Coal based carbon and coconut based carbon showed similar removal efficiencies for these antibiotics. Dissolved organic materials interfered with adsorption of SAs and TAs. Organic interference was more ...
The deposition of platinum on various carbon blacks was carried out by forming active functional groups on the surface of the carbon support, and exchanging these active groups with different platinum complexes. Using H{sub 2}PtCl{sub 6} solution, an impregnation rather than an exchange takes place. However, using divalent platinum complexes [Pt(NH{sub 3}){sub 4}]{sup 2+}, a fast exchange takes place which leads to extremely small platinum particles highly dispersed on the surface of carbon black. A comparison of the catalytic activities of platinum supported on various carbon blacks was also carried out. The performances of PEFC (Polymer Electrolyte Fuel Cell) based on the process of the ion exchange are reported. (authors) 3 refs.
This report introduces a microprocessor system composed of a Z-80 single-board computer controlling a gas-carburizing process. The system has 7 analogical input and output signals 24 switch signal-input and 12 switch signal-output signals, which are applicable for temperature, carbon potential, and mechanical-movement control of multipurpose sealed furnaces, or for mutiple-zone temperature, carbon potential, and mechanical-movement control of continuous gas carburizing furnaces; or for distributed control of pit-type carburizing furnaces. The setpoints of variables, such as treating time, temperature, carbon potential of carburizing period, carbon potential of diffusion period, depth of carburizing layer, P.I.D. etc., are entered by keyboard and stored into memories, and actual values are displayed by digital tubes. Furthermore, the fault of thermocouple, oxygen probe, or infrared CO/sub 2/ analyzer; ...
An assessment was carried out to identify where the Carbon Trust's Low Carbon Innovation Programme (LCIP) should concentrate its investment. LCIP acts in a similar manner to a venture capital company, seeking the best carbon return rather than a specific financial return. Over the next 3 years LCIP plans to invest 75 million dollars in selected technologies and businesses that can help the UK move towards a low carbon economy. The assessment will be updated annually. 49 technologies were assessed in areas of: demand-side: buildings; demand-side: industry; supply-side: fuels and conventional energy production; supply-side: renewables; transport; and enabling technologies. Technologies were rated in categories according to their technology impact and the extent to which LCIP funding could make an impact. Coal bed methane is identified as one technology profile to consider; cleaner coal production ...
Two important greenhouse gases, CO{sub 2} and CH{sub 4}, are closely connected to the carbon cycling of wetlands. Although virgin wetlands are mostly carbon accumulating ecosystems, major proportion of the CO{sub 2} bound annually in photosynthesis is released back to the atmosphere. Main portion of the carbon cycling in wetlands is quite fast while a small proportion of carbon diffusing from soil is released from organic matter, which may be ten thousand years old. Methane is formed in the anaerobic layers of wetlands, from where it is released gradually to the atmosphere. The decomposition in anaerobic conditions is very slow, which means that usually only a few percent of the annual carbon cycling takes place as methane. Research on CO{sub 2} fluxes of different virgin and managed peatlands was the main topic of this project during the first phase of SILMU. The measurements were ...
The possible contribution of short rotation cultures (SRC) to carbon sequestration in both current and elevated carbon dioxide concentrations was investigated using the free-air carbon dioxide enrichment (FACE) technique. Three poplar species were grown in an SRC plantation for three growing seasons. Above-ground and below-ground biomass increased by 15 to 27 per cent and by 22 to 38 per cent, respectively; light-efficiency also increased as a result. Depletion of inorganic nitrogen from the soil increased after three growing seasons at elevated carbon dioxide levels, but carbon dioxide showed no effect on stem wood density. Stem wood density also differed significantly from species to species. These results confirmed inter-specific differences in biomass production in poplar, and demonstrated that elevated carbon dioxide enhanced biomass productivity and ...
The possible contribution of short rotation cultures (SRC) to carbon sequestration in both current and elevated carbon dioxide concentrations was investigated using the free-air carbon dioxide enrichment (FACE) technique. Three poplar species were grown in an SRC plantation for three growing seasons. Above-ground and below-ground biomass increased by 15 to 27 per cent and by 22 to 38 per cent, respectively; light-efficiency also increased as a result. Depletion of inorganic nitrogen from the soil increased after three growing seasons at elevated carbon dioxide levels, but carbon dioxide showed no effect on stem wood density. Stem wood density also differed significantly from species to species. These results confirmed inter-specific differences in biomass production in poplar, and demonstrated that elevated carbon dioxide enhanced biomass productivity and ...
Sterile aqueous N-methylaniline solutions were allowed to equilibrate at various nitrite, F-400 granular-activated carbon, and pH levels for 1 week. The aqueous and activated carbon phases were extracted and analyzed for nitrosamines relative to an added internal standard. Selected ion monitoring GC/MS, utilizing continuous monitoring of the NO/sup +/ ion (m/z 29.9980) characteristic of nitrosamines, at medium resolution (R = 2500-3000) was applied to quantitatively measure nitrosamines at picograms per microliter concentrations. This method selected for nitrosamine products only and eliminated interferences from non-nitrosamine reaction products. Results indicate that the pressure of granular-activated carbon significantly enhanced the formation of nitrosamine from N-methyl-aniline (F = 145, P< 0.0001). The amount of N-nitrosomethylaniline formed in the presence of activated carbon was 75 times more ...
Desorption behavior of pyrene, phenanthrene and naphthalene from fullerene, single-walled carbon nanotubes (SWCNTs) and multi-walled carbon nanotubes (MWCNTs) was examined. Available adsorption space of carbon nanotubes (CNTs) was found to be the cylindrical external surface, neither the inner cavities nor inter-wall spaces due to impurities in the CNTs and restricted spaces (0.335 nm) of the MWCNTs, respectively. Desorption hysteresis was observed for fullerene but not for CNTs. Deformation-rearrangement was proposed to explain the hysteresis of polycyclic aromatic hydrocarbons (PAHs) for fullerene, due to the formation of closed interstitial spaces in spherical fullerene aggregates. However, long, cylindrical carbon nanotubes could not form such closed interstitial spaces in their aggregates due to their length, thus showing no significant hysteresis. High adsorption capacity and reversible adsorption ...
This invention relates to the production method of composite electrode substrate for fuel cell. An impermeable material is used for edge sealant. The sealant is put in the clearance between two electrodes consisting of porous carbon material via thermoplastic resin sheet, and heated while being pressed. This production method increases the adherence between the porous carbon bodies and reduces the contact resistivity at the joint interface. Consequently, it becomes possible to produce the composite electrode for fuel cell without separator, resulting in simplification of assembly work, weight reduction, and downsizing. The preferable porous carbon body is made from shrinkage-treated fiber. After sheet forming, the thermosetting resin is impregnated, and then it is burnt to carbonization. Or mixed sheet of rayon and acrylic fiber is laminated to be heated and pressed without impregnating the resin. The ...
Aqueous mineral carbonation is a potentially attractive sequestration technology to reduce CO2 emissions. In this paper, the energy consumption and costs of this technology were assessed using either wollastonite (CaSiO3) or steel slag as feedstock. The major energy-consuming process steps were found to be the grinding of the feedstock and the compression of the CO2. Within ranges of experimentally investigated process conditions, optimum energetic CO2 sequestration efficiencies were 79 and 74% for wollastonite and steel slag, respectively. It was shown that the energetic performance for both feedstock might be improved up to >90% by e.g. further grinding of the feedstock and reducing the amount of process water applied. At energetically optimized process conditions, a preliminary cost estimate was made of 93 and 66 euro/ton CO2 avoided for wollastonite and steel slag, respectively (sequestration costs excluding possible capture). For wollastonite, major ...
A stable isotope mass-balance of dissolved inorganic carbon during a blue-green algae bloom in a softwater lake demonstrates that at low partial pressure of carbon dioxide there must be a large net negative carbon isotope fractionation between atmospheric CO/sub 2/ and the CO/sub 2/ absorbed by lake water at pH = 9.5. Chemical enhancement of CO/sub 2/ invasion at high pH by the reaction CO/sub 2/ + OH/sup -/ ..-->.. HCO/sub 3//sup -/ at large apparent film thicknesses may result in carbon isotope fractionation approaching that for a hydroxide solution. This phenomenon, coupled with a decrease in the photosynthetic fractionation, forced the surface water of a softwater lake to achieve increasingly negative delta /sup 13/C values during an algal bloom, which is in the opposite sense to the trend that results from photosynthesis under less extreme conditions. This and other similar systems must operate ...
Thermal-fluid flow analysis and demonstration test were performed for a spent fuel storage system. The commercial computational fluid dynamics (CFD) code, FLUENT was used for the numerical analysis. Effective thermal conductivities of a spent fuel assembly and a fuel basket were derived to optimize a thermal analysis model. Also, a porous model, which can simplify a complex configuration of a fuel assembly, was used in the thermal analysis. Demonstration test were performed to verify the thermal analysis method and procedure using a half scaled-down model and an electrically heated dummy fuel. The numerical analysis results were compared with the experimental data. Thermal analyses of the storage system were carried out for normal and off-normal conditions by using the verified analysis method.
In this paper we present status and developments of the Duke storage ring facility. The Duke storage ring facility provides the unique combination of phase-locked light sources ranging from high power OK-4 XUV FEL to quasimonochromatic {gamma}-ray beam and IR/X-ray spontaneous radiation. The XUV OK-4 FEL, which is collaborative project with BlNP, Novosibirsk, is in operation since November, 1996. The OK-4 UV FEL is also used for production of nearly monochromatic {gamma}-ray s with tunable energy. We present the results of UV lasing with the OK4 FEL and selected results of its applications. We will discuss our future plans for extension of this source and status of the construction of dedicated used facility adjacent to the FEL building. (author)
The mixture of 65 mol% capric acid and 35 mol% lauric acid (C-L acid) is a potential latent heat storage material. However, its melting temperature of 18.0 {sup o}C is quite high for low-temperature thermal energy storage. Addition of pentadecane, with a melting point of 9.9 {sup o}C, is proposed. The thermal characteristics of the combination of the C-L acid with pentadecane (CL:P) in different volume ratio are investigated employing the DSC analysis. The actual thermal performance of each CL:P combination is further determined from their radial and axial temperature distribution employing a fabricated thermal storage capsule. The 90:10 CL:P combination manifests an improvement in the melting characteristic of the C-L acid.(author)
New cassettes for 201 mm{times}252 mm (8{double_prime}{times}10{double_prime}) and 201 mm{times}400 mm (8{double_prime}{times}15.75{double_prime}) storage phosphor plates have been developed at the Synchrotron Resource of the Howard Hughes Medical Institute. The purpose for this work was mainly twofold. Firstly, to diminish the number of manual operations when putting the storage phosphor plate into the cassette or when extracting it from the cassette. Secondly, to render such a cassette much lighter than the former metal cassette previously in use. These two goals were achieved by making new cassettes that are operated as one piece instead of two or three independent parts as with the former systems. The cassettes have been extensively tested and found to be very useful.
Storage of thermal energy in aquifers has obvious benefits of saving energy and decreasing the consumption of fossil fuels. However, aquifer thermal energy storage (ATES), which involves groundwater aquifers as the storage medium for heat or chill, impinges on the environment. A literature review of pertinent microbiology publications (Hicks and Stewart, 1988) identified the potential for the interaction of ATES systems and microbiological processes to create a source of infectious diseases and the potential for damage to the environment. In addition, the review identified a potential for microbiological processes to develop conditions that would interfere with the operation of an ATES system. As a result of this research effort, investigators from Finland, Germany, Switzerland, and the United States have examined several ATES systems in operation and have observed that the ATES systems studied do not contribute to ...
Storage of thermal energy in aquifers has obvious benefits of saving energy and decreasing the consumption of fossil fuels. However, aquifer thermal energy storage (ATES), which involves groundwater aquifers as the storage medium for heat or chill, impinges on the environment. A literature review of pertinent microbiology publications (Hicks and Stewart, 1988) identified the potential for the interaction of ATES systems and microbiological processes to create a source of infectious diseases and the potential for damage to the environment. In addition, the review identified a potential for microbiological processes to develop conditions that would interfere with the operation of an ATES system. As a result of this research effort, investigators from Finland, Germany, Switzerland, and the United States have examined several ATES systems in operation and have observed that the ATES systems studied do not contribute to ...
Very large sparse linear least-squares problems arise in a variety of applications, such as geodetic network adjustments, photogrammetry, earthquake studies, and certain types of finite element analysis. Many of these problems are so large that it is impossible to solve them without using auxiliary storage devices. Some problems are so massive that the storage needed for their solution exceeds the virtual address space of the largest machines. A method for solving such problems on a typical (large) computer is described, and the results of some experiments illustrating the effectiveness of this approach are provided. The method includes an automatic partitioning scheme that is essential to the efficient management of the data on auxiliary files. 8 figures, 2 tables
A model for the simulation of the time dependent behavior and the analysis of the equilibrium of the coupled system of storage ring and Free Electron Laser (FEL) is presented. The analysis comprises both amplifier and oscillator FEL. Bunch lengthening and energy widening due to wake forces are taken into account in a self-consistent way. The method is based on a mapping algorithm for means and correlations of the electron distribution function, pioneered by K. Hirata. The evolution of the laser field in the oscillator FEL is described by K. Hirata. The evolution of the laser field in the oscillator FEL is described by supermodes. The model is used to simulate an FEL in a small 500 MeV storage ring with 100 m circumference. Typical values for the output power, spatial, and spectral characteristics of the emitted radiation are presented.
A relocatable storage magazine apparatus for storing and retrieving explosives and ordnance and for partially containing and attenuating the blast, conflagration and flying debris from an accidental explosion is described comprising: (a) a container having an access hole; (b) a debris trap attached to the container, the debris trap communicating with said container via the access hole, said debris trap having vent holes for venting the pressure of an explosion from said debris trap to the atmosphere; (c) means for covering said access hole; (d) means for suspending explosives and ordnance from the covering means; (e) means for entering the storage magazine to store and retrieve explosives and ordnance; (f) means for retaining said covering means in a position above the access hole wherein said explosives and ordnance are accessible from the entering means.
Summary Background: Red blood cell (RBC) transfusion in hemorrhagic shock is life saving. However, several clinical trials have shown that blood transfusion in the critically ill patient might be associated with adverse outcomes. Furthermore, an association between prolonged blood storage and adverse effects of RBC transfusion has been postulated. The aim of this study is to examine the effect of blood storage time on resuscitation outcome, in an animal model of hemorrhagic shock. Methods: 20 Wistar rats were phlebotomized in order to induce reversible hemorrhagic shock. Half of them were resuscitated with blood stored for a short period of time (4 days), and the other ones were resuscitated with blood stored for a prolonged time (14 days). Blood samples for hemoglobin, pH, lactate, bicarb...
Here we reported a two-step procedure for preparing a novel polymeric based solid-solid phase change heat storage material. Firstly, a copolymer monomer containing a polyethylene glycol monomethyl ether (MPEG) phase change unit and a vinyl unit was synthesized via the modification of hydrogen group of MPEG. Secondly, by copolymerization of the copolymer monomer and phenyl ethylene, a novel polymeric based solid-solid phase change heat storage material was prepared. The composition, structure and properties of the novel polymeric based solid-solid phase change material were characterized by IR, "1H NMR, DSC, WAXD, and POM, respectively. The results show that the novel polymeric based solid-solid phase change material possesses of excellent crystal properties and high phase change enthalpy.
The removal of paraffinic bottom accumulations from refinery storage tanks represents an increasingly costly area of petroleum storage management. Microorganisms can be used to reduce paraffinic bottoms by increasing the solubility of bottom material and by increasing the wax-carrying capacity of carrier oil used in the cleaning process. The economic savings of such treatments are considerable. The process is also intrinsically safer than alternative methods, as it reduces and even eliminates the need for personnel to enter the tank during the cleaning process. Both laboratory and field sample analyses can be used to document changes in tank material during the treatment process. These changes include increases in volatile content and changes in wax distribution. Several case histories illustrating these physical and chemical changes are presented along with the economics of treatment.
Theoretical investigations of fatty acids as a phase change material (PCM) for energy storage system have been conducted in this study. The selected fatty acids were capric acid, lauric acid, myristic acid, palmitic acid and stearic acid. For the two-dimensional simulation model based on the enthalpy approach, calculations have been made for the melt fraction with conduction only. Glass, stainless steel, tin, aluminium mixed, aluminium and copper were used as heat exchanger materials in the numerical calculations. Theoretical results show that capric acid was found good compatibility with latent heat storage system. The large value of thermal conductivity of heat exchanger materials did not make significant contribution on the melt fraction. (author)
The fundamental points to be considered in a waste treatment system for a country like Japan, where the final disposal method has not been decided and the wastes have to be stored in the power plants, are volume reduction of the wastes, safe storage of the wastes in the plant, and flexibility regarding the final disposal. A system has been developed that consists of a thin film evaporator for the direct solidification of the liquid waste, a pelletizer for producing hard pellets from the powdered wastes, a pellet storage unit, and a solidification unit for the final disposal. A pilot plant with waste treatment capacity of 200 kg/h was built in 1976 and has proved the system feasibility. This paper reports on pilot plant tests of the thin film evaporator and other components, tests on pellet deterioration during long term storage, and integrity tests on the final disposal of the pellet bitumen package.
The fundamental points to be considered in a waste treatment system for a country like Japan, where the final disposal method has not been decided and the wastes have to be stored in the power plants, are volume reduction of the wastes, safe storage of the wastes in the plant, and flexibility regarding the final disposal. A system has been developed that consists of a thin film evaporator for the direct solidification of the liquid waste, a pelletizer for producing hard pellets from the powdered wastes, a pellet storage unit, and a solidification unit for the final disposal. A pilot plant with waste treatment capacity of 200 kg/h was built in 1976 and has proved the system feasibility. This paper reports on pilot plant tests of the thin film evaporator and other components, tests on pellet deterioration during long term storage, and integrity tests on the final disposal of the pellet bitumen package.
The first U.S. demonstration of the NGK sodium/sulfur battery technology was launched in August 2002 when a prototype system was installed at a commercial office building in Gahanna, Ohio. American Electric Power served as the host utility that provided the office space and technical support throughout the project. The system was used to both reduce demand peaks (peak-shaving operation) and to mitigate grid power disturbances (power quality operation) at the demonstration site. This report documents the results of the demonstration, provides an economic analysis of a commercial sodium/sulfur battery energy storage system at a typical site, and describes a side-by-side demonstration of the capabilities of the sodium/sulfur battery system, a lead-acid battery system, and a flywheel-based energy storage system in a power quality application.
Abstract Microbiological quality and biophenol content evolution was studied in minimally processed Thassos cv table olives by hot air dehydration under mild conditions (40C, 24-h, aw-=-0.893) and storage under characteristic packaging conditions (vacuum, 100% N2 and air) at 4 and 20C over a period of 180 days. No salt was used in the production line or packaging. The undesirable microorganisms (Enterobacteriaceae, Staphylococcus aureus, Bacillus, Clostridium) were undetectable until the end of the storage period. Also, modified atmospheres prevented fungal growth at both temperatures apart from the samples stored in air, in which Penicillium and Aspergillus spp. were identified. At 20C, a coexistence of mesophilic bacteria and yeasts occurred. At 4C, yeasts were the predominant microflora...
This report is a description of the West Valley Demonstration Project`s radioactive waste storage facility, the Chemical Process Cell (CPC). This facility is currently being used to temporarily store vitrified waste in stainless steel canisters. These canisters are stacked two-high in a seismically designed rack system within the cell. Approximately 300 canisters will be produced during the Project`s vitrification campaign which began in June 1996. Following the completion of waste vitrification and solidification, these canisters will be transferred via rail or truck to a federal repository (when available) for permanent storage. All operations in the CPC are conducted remotely using various handling systems and equipment. Areas adjacent to or surrounding the cell provide capabilities for viewing, ventilation, and equipment/component access.
SPEOS takes advantage of a geological situation which apparently does not occur much in Switzerland. The SPEOS pilot installation, which was erected in 1982, is designed for the supply of heat for about 500 persons. In the course of 10 cycles, the possibilities and limits of the seasonal heat storage were displayed. It was demonstrated that large quantities of heat with temperatures of up to 75 C can be stored in an aquifer. The behaviour of such a storage can be predicted with sufficient accuracy with mathematical models. (author) 12 refs.
The primary objective of this study was to evaluate the potential environmental effects (both adverse and beneficials) of aquifer thermal energy storage (ATES) technology pertaining to microbial communities indigenous to subsurface environments (i.e., aquifers) and the propagation, movement, and potential release of pathogenic microorganisms (specifically, Legionella) within ATES systems. Seasonal storage of thermal energy in aquifers shows great promise to reduce peak demand; reduce electric utility load problems; contribute to establishing favorable economics for district heating and cooling systems; and reduce pollution from extraction, refining, and combustion of fossil fuels. However, concerns that the widespread implementation of this technology may have adverse effects on biological systems indigeneous to aquifers, as well as help to propagate and release pathogenic organisms that enter thee environments need to be resolved. 101 refs., 2 ...
The paper discusses a number of recent studies investigating into the energy conservation and environmental impacts of electric heating systems (off-peak storage systems). In future, i.e. in and after 1993, off-peak storage systems will be evaluated through comparative analyses of oil-fired heating systems, pollutant emission analyses, the eventual success of pollution abatement measures designed for power plant emissions to keep within the legal limiting values, and the possible abandonment of pollution abatement measures abroad. Opposing the electric heating studies submitted by the electric power industry the author refutes their favourable results referring to the palliative selection of inadequate or vague parameters. Assuming average power plant pollutant emissions of 180 mg/standard/sup 3/ the nitrogen oxide emissions of oil-fired heating systems (134.1 kg/Tj) are found to be below those of off-peak storage systems ...
Ultrafine particles of Co-P were synthesized by direct ball milling of Co and P powders and also investigated as a reversible hydrogen storage electrode material. The electrochemical results demonstrated that the reversible charge-discharge capacity of the Co-P electrode can reach more than 300mAh/g. In addition, the cycling ability and high rate capability of the Co-P electrode are excellent with only 5% capacity decay after 100 cycles at a high rate of 300mA/g. The temperature-programmed desorption measurements (TPD) of the Co-P electrode revealed that the charge and discharge reactions of the Co-P electrode proceeds predominantly through electrochemical hydrogen storage mechanism and the electrooxidation of cobalt contributes only a negligible part to the reversible electrochemical capacity. (author)
For investigating carryover of some organophosphorus pesticide residues in the cereal food chain from grain to consumer, a study was set up on wheat bran, flour and cookies, with and without bran. Special emphasis was given to malathion and chlorpyrifos-methyl residues in cookies for better protection of consumers. Pesticide-free wheat was placed in a small-scale model of a commercial storage vessel and treated with these pesticides. The residue levels of insecticides were determined in wheat, as well as in bran, flour and cookies produced from stored wheat at various time intervals during storage. A multiresidue analysis was performed using GC-NPD and GC-MS. Malathion and chlorpyrifos-methyl residue levels were higher than the maximum residue limits (MRLs) in wheat after 240days of storag...
A state-of-the-art review and assessment of storage effects on crude oil and product quality was undertaken through a literature search by computer accessing several data base sources. Pertinent citations from that literature search are tabulated for the years 1980 to the present. This 1990 revision supplements earlier reviews by Brinkman and others which covered stability publications through 1979 and an update in 1983 by Goetzinger and others that covered the period 1952--1982. For purposes of organization, citations are listed in the current revision chronologically starting with the earliest 1980 publications. The citations have also been divided according to primary subject matter. Consequently 11 sections appear including: alternate fuels, gasoline, distillate fuel, jet fuel, residual fuel, crude oil, biodegradation, analyses, reaction mechanisms, containment, and handling and storage. Each section contains a brief narrative followed by ...
Antisense- or RNAi-mediated suppression of the biosynthesis of nutritionally inferior storage proteins is a promising strategy for improving the amino acid profile of seeds. However, the potential pleiotropic effects of this on interconnected pathways and the agronomic quality traits need to be addressed. In the current study, a transcriptomic analysis of an antisense C-hordein line of barley was performed, using a grain-specific cDNA array. The C-hordein antisense line is characterized by marked changes in storage protein and amino acid profiles, while the seed weight is within the normal range and no external morphological irregularities were observed. The results of the transcriptome analysis showed excellent correlation with data on changes in the relative proportions of storage protei...
In-situ sodium activated organo modified bentonite clay was also used for partial replacement of the carbon black (N330). Detailed study with the black filled compound revealed that, with slight modification of the curing package, up to 10 phr of the carbon black replacement is possible. At equivalent loading of 5 and 10 phr of in-situ sodium activated organo modified bentonite clay exhibited better properties in comparison to carbon black filled compound.
Samples of 100Cr6 steel were treated by different ion beams in order to study the evolution of their tribological properties. A strong correlation was found between the amount of surface carbon, whatever its origin (contamination, direct C implantation or ion-beam mixing of a deposited carbon layer), and the reduction of the friction coefficient as well as the improvement of the wear resistance. These results are discussed in the framework of a recent statistical model founded on the asperity concept and describing the tribological behaviour of bilayer systems.
This paper describes statistical methods used to evaluate data for toluene (at several typical operating temperatures and humidity levels) and to determine which measure of humidity (relative or absolute) is more important in determining carbon adsorption efficiency. The water content of a solvent-laden stream is critical for its control via carbon adsorption, especially at relative humidities about 50-70%. (Relative humidity is the percent of saturation: absolute humidity is the total water content.)
Growing competitiveness of alternative manufacturing routes requires cost minimization in the production of drop forged components. The authors analyse the potential of medium carbon, vanadium microalloyed steels for drop forging. Laboratory and industrial experiments have been carried out emphasizing deformation and temperature cycles, strain rates and dwell times showing a typical processing path, associated mechanical properties and corresponding microstructures. The steels the required levels of mechanical properties on cooling after forging, eliminating subsequent heat treatment. The machinability of V-microalloyed steels is also improved when compared with plain medium carbon steels. (author)
Isosteric heats and adsorption isotherms of methane on nanometer active carbon were measured at supercritical temperature (273-373 K) and pressure from 0 to 10 MPa. The measured data agreed well with Dubinin-Astakhov (DA) model at lower pressure but failed when pressure exceeded a special range. General Freundlich (GF) equation was used to modify the DA equation at high pressure and thus formed a combined bisection model GFDA. The adsorption mechanism of methane on nanometer active carbon was raised according to GFDA model and the heterogeneous energy distribution of the adsorbent was analyzed.
The authors investigated phase equilibria in the system carbon dioxide-hexametapol. Vacuum-distilled solvent of ''pure'' grade was used. The solubility of CO/sub 2/ in hexametapol under pressures at various temperatures and the temperature dependence of the Henry's law coefficient is show. It is concluded that the solubility of carbon dioxide in hexametapol in the temperature and pressure ranges corresponding to the operating conditions of industrial equipment for removing CO/sub 2/ from gases conforms to the Krichevskii-II'inskaya equation. The experimental data can be used for equipment design.
author.The chemical and mechanical properties of S235jr structural low carbon mild steel were tested and reported for specimens collected from the Lebanese steel market. European and American standards were presented as references and compared with the achieved results. Discussion was conducted to show the similarities and differences between S235JR steel samples and standard requirements. Some of the reasons for such differences were discussed. A database was furnished through this work for the public and mainly for the Lebanese Standard Organization LIBNOR to easily adopt and implement a standard that has been tested in Lebanon concerning the hot rolled low carbon structural steels
The key component for improving the energy efficiency and cycle life of the electrically rechargeable zinc-air battery is the bifunctional air electrode. The air electrodes described in this paper contained different types of carbon black as the substrate for the perovskite catalyst (La{sub 0.6}Ca{sub 0.4}CoO{sub 3}). Morphological and physical properties of the carbon substrates play an important role in enhancing the activity and stability of the bifunctional air electrode. Current-potential curves and cycle-life tests were applied in order to gather information on the activity and stability of these electrodes. (authors)
In the experimental fast Reactor JOYO, gripper of Fuel Handling Machine and Ex-Vessel Transfer Machine that the sodium adhered is being washed with alcohol. This radioactive alcohol waste that was used to the washing is stored to the tank. If it is able to separate the alcohol and sodium in the alcohol waste it becomes possible to dispose of the alcohol waste. Japan Nuclear Institute and Fuji Electric Systems CO., LTD. Developed the device that adds carbonic acid gas to the alcohol waste and cause the sodium in the alcohol waste separated as carbonate and remove this carbonate by using the thin film evaporator. (author)
The first objective is to utilize reservoir characterization and advanced technologies to optimize the design of a carbon dioxide (CO{sub 2}) project for the South Cowden Unit (SCU) located in Ector County, Texas. The SCU is a mature, relatively small, shallow shelf carbonate unit nearing, waterflood depletion. The second objective is to demonstrate the performance and economic viability of the project in the field. This report includes work on the reservoir characterization and project design objective and the demonstration project objective.
Absorption and desorption rate data for the system CO/sub 2/-hot carbonate solutions are presented. The data are interpreted on the basis of a film-theory model developed following the procedure recently presented by Astarita and Savage. The agreement is very satisfactory. Values of the kinetic constant of the rate-determining step, previously known only up to a temperature of 40/sup 0/C, have been obtained up to 110/sup 0/C.
Mercury has had various uses in nuclear fuel reprocessing and other nuclear processes, and so is often present in radioactive and mixed (both radioactive and hazardous according to the Resource Conservation and Recovery Act) wastes. Depending on regulatory requirements, the mercury in the off-gas must be controlled with sometimes very high efficiencies. Compliance to the Hazardous Waste Combustor (HWC) Maximum Achievable Control Technology (MACT) standards can require off-gas mercury removal efficiencies up to 99.999% for thermally treating some mixed waste streams. Several test programs have demonstrated this level of off-gas mercury control using fixed beds of granular sulfur-impregnated activated carbon. Other results of these tests include: (a) The depth of the mercury control mass transfer zone was less than 15-30 cm for the operating conditions of these tests, (b) MERSORB(reg_sign) carbon can sorb Hg up to 19 wt% of the ...
Measurements of carbon metabolism, production and exchange along food webs suggest that large fractions of the organic matter produced on continental shelves must be exported to continental slopes. The annual loss of organic matter from continental shelf ecosystems is far greater than in the open ocean. If part of the loss of nearshore primary production has increased in those coastal zones where anthropogenic inorganic nutrient supplies have been consistently increasing since the industrial revolution, then burial and diagenesis of this material in slope depocentres could represent the missing BMTs of carbon in global CO/sub 2/ budgets.
A comparative study has been performed to compare the 30 wt% of 2-amino-2-methyl-1-propanol (AMP) aqueous solution and 30 wt% of methyldiethanol amine (MDEA) aqueous solution to capture carbon dioxide contained in the flue gas stream. The equilibrium constants for each electrolyte reactions have been used to estimate the carbon dioxide absorption process. Henry's constants for each binary pairs between solute gases and solvent have been used to estimate solubility of the gas components.
A highly sensitive and stable tris(2,2prime-bipyridyl)ruthenium(II) (Ru(bpy)32+) electrogenerated chemiluminescence (ECL) sensor was developed based on carbon nanotube (CNT) dispersed in mesoporous composite films of sol-gel titania and perfluorosulfonated ionomer (Nafion). Single-wall (SWCNT) and multi-wall carbon nanotubes (MWCNT) can be easily dispersed in the titania-Nafion composite solution. The hydrophobic CNT in the titania-Nafion composite films coated on a glassy carbon electrode certainly increased the amount of Ru(bpy)32+ immobilized in the ECL sensor by adsorption of Ru(bpy)32+ onto CNT surface, the electrocatalytic activity towards the oxidation of hydrophobic analytes, and the electronic conductivity of the composite films. Therefore, the present ECL sensor based on the CNT-...
Research Center last approximately 1.5 hours and include stops at the Space Weather Prediction Center, ESRL Global Monitoring Division for information on the carbon dioxide...
Cfiber/Si3N4 composites were prepared by hot-pressed sintering using a-Si3N4 powders, short carbon fibers and sintering additives as starting materials. The mechanical and dielectric properties of these composites were studied. When the short carbon fiber content of the composites increases from 0 to 1wt.%, the fracture toughness increases from 3.456 to 4.203MPam1/2, and both the real and imaginary part of permittivity increase greatly over the frequency range 8.2-12.4GHz. These effects were due to the anisotropy of short carbon fibers.
The influence of the regimes of modification of carbon fibers by an argon ion beam on the change in the angle of their wetting by an epoxy oligomer has been investigated. It has been shown that ion-beam treatment of carbon fibers leads to a considerable decrease in the wetting angles (the difference between the wetting angles for non modified and modified fibers is up to 32.2-38.7). Accordingly, there is also an increase in the value of the equilibrium work of adhesion by 36.2-41.6% in the contact zone. It has been established that ion-beam treatment of carbon fibers by argon ions leads to an increase in the shear strength when microplastics based on them are formed. (authors)
To improve the friction and wear behavior of carbon fabric reinforced polymer composites (CFRP), nano-SiO2 was deposited on the fabric surface. The friction and wear behavior of the resulting composites were investigated on a model ring-on-block test rig. Experimental results revealed that fiber surface treatment contributed to largely improve the tribological properties of the CFRP composites. Scanning electron microscope (SEM) investigation showed that the worn surface of the surface modified CFRP composite was smoother under given load and sliding rate. Field emission scanning electron microscopy (FESEM), FTIR and X-ray photoelectron spectroscopy (XPS) studies of the carbon fiber surface showed that nanostructured Sio2 thin film can be obtained by SiO2 sols deposition, which improved th...
2011 Department of Energy Investments in Carbon Capture Technologies 2010 Smart Meter Installations DOE Recovery Field Projects and State Memos Advanced Vehicle...
The basic feature in the functional ecology of any mire ecosystem is retardation of the effective decay of organic material resulting in a conspicuous accumulation of plant debris as peat overtime. The carbon accumulation process is slow, and climatic change may have an impact on the carbon cycle of peatlands, therefore, it has been of interest to study the rate of carbon accumulation by geological methods from dated peat strata. The approach is hampered by several facts. First, the mires vary enormously as to their vegetation and hydrology and hence their production and decay properties. It follows that a great number of study sites are needed. Second, the peat in mires expands both vertically and laterally, and this requires a spatial reconstruction of carbon accumulation within a mire basin. Third, simple geological methods cannot account for the actual rate of carbon ...