Alpha-particle emission induced by neutron bombardment of carbon has been studied from threshold to over 30 MeV using the spallation neutron source at WNR/LAMPF. Targets include thin foils of CH{sub 2} and thicker foils of CH and polycrystalline graphite. Comparisons are made with evaluated data. Values for KERMA (kinetic energy released in materials) based on the results will be presented and compared with those obtained through other experimental approaches.
Research performed at LAMPF during 1985 is reported in the areas of: nuclear and particle physics; atomic and molecular physics; materials science; radiation-effects studies; biomedical research and instrumentation; nuclear chemistry; radioisotope production; and physics theory. Also reported are the status of LAMPF-II, facility development work, and accelerator operations. (LEW)
The effect of atmospheric radioactive emissions from United Kingdom nuclear installations on acid deposition is assessed. Nitrogen oxide and ozone production resulting from and associated with discharges of airborne radioactivity, comparison with conventional emissions, and the direct effects of radioactive emissions on trees, are all discussed. (UK).
Research reported here reveals that the reduction of CO{sub 2} emissions into the atmosphere, is mainly dependent on the decrease of the use of fossil fuels, but also on the development of environment-friendly technology and greening of the environment. 2 refs.
The document presents an overview on atmospheric pollution in Lebanon, with an analysis of sources of pollution, their impact on local and global environment and their control.Local causes of pollution are mainly: -Thermal power plants of electric power production which produce 75% SO_2 emission and 60% dust - Industries, especially cement industry - Land transportation which produces 70% NOX emission and 50% CO_2 A description of air pollution caused by these three sectors is revealed. Pollutants derived from fuel combustion are analyzed. It is estimated that in 2010, Co_2 emission will reach 5204450 tons, SO_2 emission will be 136470 tons, NOX emissions 96870 and dust estimated to 4130 tons. CFC consumption and measures of control according to Montreal Protocol are described. Recommendations for control of air pollution in Lebanon within a national policy are ...
The production of atmospheric pollutants in combustion processes depends on plant characteristic, combustion conditions and fuel quality. The influence of fuel quality on the emission of sulphur oxides, nitrogen oxides, carbon monoxide, dust and carbon dioxide and on the emission of some toxic pollutants, such as heavy metals and polycyclic aromatic hydrocarbons, is analysed. The comparison between the emission limits, fixed by the Italian legislation, and the uncontrolled pollutant emissions, produced by fossil fuel combustion in power plants and industrial use, shows that, in order to comply with the limits, a reduction of pollutant emissions is required through the use of abatement systems and cleaner fuels where natural gas has a primary role. The use of cleaner fuels is particularly required in heating plants and appliances for the residential sector, where ...
The article is an overview on atmospheric pollution in Lebanon. It presents an analysis of sources of pollution in the country and their impacts on local and global environment and describes their control. Air pollution is mainly due to the industrial, electrical and transportation sectors. Pollutants from fuel combustion are analyzed. It is estimated that in 2010, CO_2 emissions will reach 5987250 tons, SO_2 emissions is estimated to be 182950 tons, Nox to 105180 and dusts to 4965 tons. CFC consumption and measures of control according to Montreal protocol are described. Consumption of primary energy, consumption of petroleum products, quantity of petroleum in refineries and production of cement in Lebanon are also presented in tables
The paper discusses the Intergovernment Panel on Climate Change (IPCC) report on Aviation and the Global Atmosphere (published in 1999). It was considered necessary to treat air transport on its own since aircraft are unique in delivering emissions into the upper atmosphere rather than at ground level. The study was commissioned at the request of the International Civil Aviation Organisation and the Montreal Protocol. More than 300 experts contributed and the report has quantified the effect of aviation on the atmosphere on a world wide basis and highlighted areas where improved data are required. (UK)
Plasma with a gas temperature below room temperature is not yet fully understood although it is expected to be an attractive tool for applications to material processing. In the present work, gas-temperature-dependent generation of a cryoplasma jet was studied. So far, we have generated a helium cryoplasma jet (296-5 K) under atmospheric pressure. At gas temperatures below 20 K, the helium excimer, He2, was observed clearly from by optical emission spectroscopy.
The main pollutants from marine diesel engines are oxides of nitrogen (NOx), sulfur oxides (SOx) and particulates (soot). However, the proposed marine diesel engine emission regulations will primarily focus on the levels of NOx and SOx. In the future, once the proposed regulations are met, the limits and levels of other emissions will come under increasing scrutiny, such as particulates, hydrocarbons and carbon monoxide. Regardless of the type of pollutant, there are generally two classes of emission control: (1) techniques that reduce the amount of pollutant formed in the combustion process, or (2) prevent the pollutants from reaching the atmosphere. Unfortunately, some of these control techniques will not be able to meet the incoming regulations. Therefore, this paper identifies the diesel engine emissions of concern, the impending regulations, and the merits of current and future ...
It is necessary to establish scenarios for reducing CO2 emissions and for developing CO2 emission control technologies to obtain a global consensus, using appropriate analytical models. For modification of the DNE-21 (Dynamic New Earth 21) model, it has a category designated as innovative technologies not involving CO2 emission and an optional consideration for the absorption of atmospheric CO2 by biomass. A global carbon circulation model, including vegetation in its scope, is also incorporated. Major results of the simulation are shown. When 20% reduction in CO2 emissions is required for only OECD countries after the year 2020, it has been demonstrated that CO2 concentration in the atmosphere will reach as high as about 900 ppm in 2100 due to CO2 emission by developing countries, and will not be a tolerable level. Under the condition that ...
Heavy-duty trucks and buses are substantial contributors to the atmospheric oxides of nitrogen (NO_x) inventory, but prediction of their emissions in real use remains inchoate. Continuous emissions of NO_x were recorded from Chassis dynamometer testing of eight vehicles using a variety of transient cycles, including the Central Business District schedule. NO_x data were treated to account for sampling time lag and presented against instantaneous vehicle axle power. Data were repeatable from run to run and test schedule, but vehicle type and test cycle both influenced the instantaneous emissions rates. However, the resulting correlations may be used for mobile source NO_x contribution estimation when combined with vehicle activity data. The emissions data were also presented as NO_x/CO_2, which are valuable for comparison with remote sensing emissions data. The ...
The project is focusing on the formation and growth mechanisms of atmospheric aerosol and cloud droplets. Both aerosol particles and cloud droplets affect strongly on the atmospheric radiation fluxes by scattering and absorption. The droplet formation results from physical and chemical processes occurring simultaneously. The studies concerning the tropospheric cloud droplet formation, laboratory experiments with a cloud chamber and stratospheric cloud formation are summarized. The recent studies summarized in this presentation indicate that both aerosol particles and cloud droplets have a significant role in climatic change and ozone depletion problems. The anthropogenic emissions of gaseous and particulate pollutants change the properties of atmospheric aerosols and cloud droplets. The research in this field will be continued and more quantitative understanding based both experimental and theoretical ...
This paper deals with two common problems and then considers major aspects of chemistry in the atmospheres of Mars and Venus. (1) The atmospheres of the terrestrial planets have similar origins but different evolutionary pathways because of the different masses and distances to the Sun. Venus lost its water by hydrodynamic escape, Earth lost CO"2 that formed carbonates and is strongly affected by life, Mars lost water in the reaction with iron and then most of the atmosphere by the intense meteorite impacts. (2) In spite of the higher solar radiation on Venus, its thermospheric temperatures are similar to those on Mars because of the greater gravity acceleration and the higher production of O by photolysis of CO"2. O stimulates cooling by the emission at 15@mm in the collisions with CO"2. ...
To predict air quality properly at a given location, it is necessary to identify all emission sources that will have significant impact at that location. Furthermore, the atmospheric pollutants that are emitted by these sources must be identified and quantitatively characterized. Once the air-quality predictions have been made, it is desirable to have some historical air-quality data for comparison. An efficient means of obtaining this information is through the use of detailed emission inventories and an inventory of air-quality-monitoring stations. Therefore, as part of the Alberta Government/Industry Acid Deposition Research Program (ADRP), three comprehensive inventories have been developed, namely: a sulfur dioxide (SO/sub 2/) emission inventory, a nitrogen oxides (NOx) emission inventory, and an inventory of air-quality-monitoring stations. Volume 2, Design of the ...
Methane (CH{sub 4}) produced microbially in sediments of marshes is emitted to the atmosphere primarily by flowing through and out of emergent aquatic plants. The magnitude of such emission rates and factors controlling those rates are not well understood. We evaluated CH{sub 4} emission from the widely distributed aquatic emergent plant cattail (Typha latifolia L.) in several wetlands in the United States using a field gas-exchange system that concurrently estimated stomatal aperture (i.e., conductance) on the surface of leaves and net photosynthesis. We compared gas exchange among plants of different age and from sites with different soil and atmospheric conditions. The mean rate of CH{sub 4} emission was 0.22{mu}mol m{sup -2} [leaf] s{sup -1}, which is 940 mg CH{sub 4} m{sup -2} d{sup -1} on a ground-area basis, with individual rates ranging from 0.01 to 1.49 {mu}mol m{sup -2} ...
Ozone is the most important regional-scale air pollutant causing risks for vegetation and human health in many parts of the world. Ozone impacts on yield and quality of crops and pastures depend on precursor emissions, atmospheric transport and leaf uptake and on the plant?s biochemical defence capacity, all of which are influenced by changing climatic conditions, increasing atmospheric CO2 and altered emission patterns. In this article, recent findings about ozone effects under current conditions and trends in regional ozone levels and in climatic factors affecting the plant?s sensitivity to ozone are reviewed in order to assess implications of these developments for future regional ozone risks. Based on pessimistic IPCC emission scenarios for many cropland regions elevated mean ozone lev...
This report presents estimates of the annual anthropogenic UK emissions of greenhouse gases for the years 1990-93 for submission under the Framework Convention on Climate Change. The gases considered are carbon dioxide, methane, nitrous oxide, nitrogen oxides, carbon monoxide and non-methane volatile organic compounds. Emissions of all the gases have declined since 1990. In particular, those of carbon dioxide have fallen by 4%; those of methane by 8% and those of nitrous oxide by 28%. Emission estimates are reported in the IPCC Standard Tables format disaggregated by source category and fuel. The methodology used for the estimates and how they relate to the UK National AtmosphericEmissions Inventory is discussed in an appendix. (author)
Fugitive dust emissions from stockpiles in the open storage yards of industrial zones and the subsequent atmospheric dust dispersion have brought about many ecological and economical problems. This paper introduces a new approach to reduce pollutant emissions by simply changing pile configuration and without affecting the operational activity on these parks. Flow around piles of different geometries and for various wind conditions was studied using previously validated Computational Fluid Dynamic (CFD) simulations. Different pile height scenarios were investigated corresponding to a constant material volume and a fixed angle of repose under various wind magnitudes. The results obtained were integrated in order to evaluate the rate of dust emissions for the various configurations considered. It was found that, for the range of wind conditions and pile dimensions tested, an optimal geometry exists which ...
The terrestrial biosphere can significantly affect the exchange of water and energy at the biosphere-atmosphere interface. Additionally, the land cover type can affect regional atmospheric chemistry and climate via biogenic volatile organic carbon (VOC) emissions and their formation of secondary organic aerosols. The broad goal of this study is to investigate the impact of land cover and vegetation changes on these specific chemistry and climate effects. The Common Land Model (CLM) is used to parameterize the biosphere-atmosphere interface over the Shanghai region in China. Phase 1 of this study, described in this report, generates input parameters for this model based on a time series of actual and derived parameters. Atmospheric forcing data are generated on an hourly temporal resolution based on a 20-year series of monthly and daily averages. Surface data, including land ...
The Toxicological Evaluation of Realistic Emissions of Source Aerosols (TERESA) study involved withdrawal, aging, and atmospheric transformation of emissions of three coal-fired power plants. Toxicological evaluations were carried out in rats exposed to different emission scenarios with extensive exposure characterization. Data generated had multiple levels of resolution: exposure, scenario, and constituent chemical composition. Here, we outline a multilayered approach to analyze the associations between exposure and health effects beginning with standard ANOVA models that treat exposure as a categorical variable. The model assessed differences in exposure effects across scenarios (by plant). To assess unadjusted associations between pollutant concentrations and health, univariate analyses...
With regard to polybrominated diphenyl ether (PBDE), there is few scientific knowledge on the emission patterns into the environment and exposure pathways to humans, and basic information is insufficient to consider what measures effective are. For the purpose of promoting risk reduction of target substances more effectively and efficiently, it is desirable to comprehend accurately the causal chain from the target substances utilization to the risk intake, and to evaluate the measures covering the whole applications of target substances. As the existing researches on the PBDE emission inventory, there are EU risk assessment report (European Chemical Bureau 2000, 2002, 2003), Danish EPA (1999), Palm et al.(2002) and Alcock et al. (2003). In addition, emissions of DecaBDE are published in TRI (Toxic Release Inventory) of US EPA. However, the primary information of the previous inventories is often the same and estimations ...
Lebanon has imported in 1996 5000 Kt of carburants causing about 80 Kt of SO_x; 40 Kt of NO_x; 3 Kt of dusts and 3.5 million tons of CO_2. The atmospheric pollution in Lebanon is due to three main sources: - Thermal central of electric production - Industries (cement) - Transportation sector The document describes in tables: the inventory of pollutants and pollutant emissions in 1993 and 2010; industrial and heating gas oil; liquified petroleum gas commercial propane; fuel oil for EDL; consumption of energy in 1996; sectorial distribution of pollutants PPM; emissions of CO_2 per tons per habitant in 1993; consumption in 1993 broken down by use and application. Finally, three projects concerning public transportation were presented
This Progress Report describes the operation of the Los Alamos Meson Physics Facility (LAMPF) and the research programs carried out there for the years 1992 and 1993. The accelerator operated for over 100 days in 1992, providing beams of H{sup +}, H{sup {minus}}, and polarized H{sup {minus}} for a rich and varied research program in nuclear physics. The accelerator had only fair beam availability in 1992 (for example, the average H{sup +} beam availability was 72%), caused largely by problems in the 201-MHz rf system. A major effort was expended to address these problems before the 1993 run. These efforts were rewarded by good beam availability in 1993 and few problems with the 201-MHz system. LAMPF operated remarkably smoothly during 1993, in the midst of a period of great uncertainty in the future of the facility and the downsizing of MP Division, which led to the loss of a large number of key people to positions elsewhere in the Laboratory. ...
The LSND (Liquid Scintillator Neutrino Detector) experiment will be performed at LAMPF in the next several years. The main goal of the experiment is to search for {nu}{sub {mu}}-{nu}{sub e} oscillations with high sensitivity; however, an increasingly important by-product of this search is to measure {nu}p {yields} {nu}p elastic scattering and determine the strange quark contribution, {Delta}s, to the spin of the proton. With the 800-MeV proton energy of LAMPF, neutrinos are produced from pion decay-in-flight with an average energy of about 150 MeV. This energy is sufficiently high so that the {nu}p {yields} {nu}p cross section is large and is sufficiently low so that the low Q{sup 2} approximation (Q{sup 2} {much lt} m{sub p}{sup 2}) is valid and the cross section can be expressed in a simple form dependent upon {Delta}s as the only unknown. LAMPF with its 1-mA proton intensity is, therefore, an ideal accelerator to perform ...
The Pulsed Lepton Source (PLS) project opens some exciting possibilities for muon and neutrino physics . The PLS would use the 0.25 4s proton pulses from the upgraded Proton Storage Ring (PSR) at LAMPF to create short, intense bursts of muons and neutrinos. The neutrino beam would be used for a few fundamentally important weak interaction physics experiments. The muon beams would find a wide variety of applications in both fundamental and applied'' muon physics areas. After a brief discussion of the physical layouts of the PSR and the proposed PLS in Sec. 2 and muon area in Sec. 3, we note some of the muon physics experiments and areas that could advantageously be addressed at the PLS in Secs. 4 and 5, and conclude in Sec. 6.
Four interrelated projects are underway whose purpose is to migrate the LAMPF-PSR Accelerator Complex control systems to a system with a common set of hardware and software components. Project goals address problems in performance, maintenance and growth potential. Front-end hardware, operator interface hardware and software, computer systems, network systems and data system software are being simultaneously upgraded as part of these efforts. The efforts are being coordinated to provide for a smooth and timely migration to a client-sever model-based data acquisition and control system. An increased use of the distributed intelligence at both the front-end and operator interface is a key element of the projects. 2 refs., 2 figs.
Advances made in understanding the chemistry and dynamics of the atmosphere in the approximate altitude range of 50 to 90 km are addressed. Attention is given to mesospheric structure and seasonal variations, gravity waves and gravity wave saturation, the effects of gravity waves on thermal, momentum and constituent fluxes, and the effect of gravity waves on airglow emissions. A review of research on tides and planetary waves and their effects on the mesosphere are presented as well as discussions on ozone hydroxyl, water vapor, and noctilucent cloud research. 217 refs.
This work is directly to analysis of atmosphere surrounding Ipiranga Refinery; witch is located in the city of Rio Grande, in estate of Rio Grande do Sul. The refinery is surrounded by neighborhood, witch are impacted by atmosphericemissions of refinery. The objective of this work is correlating the refinery to the inhabitants that lives near the refinery, using an environmental sustainability index. This work will be achieve by analysis of Polycyclic Aromatic Hydrocarbons (PAH) bounded in particulate matter with diameter of 100 {mu}m (PTS), the acquisition of health data on the city hospitals and correlation of this data with PAH concentrations in Particulate Matter. The Samples were obtain by FEPAM, witch have three samples sites in the center of city. The samples was obtained by a High Volume Sampler equipped with quartz fiber filters. The meteorological data important to this work, like wind direction and speed, will ...
A three-dimensional mathematical model has been developed as a tool for furnace structure design and operation conditions optimization when the straw combustion is in oxygen-enriched or conventional air atmospheres. Mathematical methods have been used based on a combination of FLIC (A fluid Dynamic Incinerator Code) code for the in-bed incineration and commercial software FLUENT for the over-bed combustion. Oxygen-enriched atmospheres promote the destruction of most pollutants due to the high oxygen partial pressures and temperatures, which is reflected by very low residual amounts of organic combustion by-products in the bottom ash and flue gas of the straw-fired boiler unit. The predictions indicated that the maximum combustion temperature is around 1500 K, CO emission is 201 vppm and O{sub 2} concentration is about 6.9 vol% at furnace exit, and it is shown that mathematical models can serve as a reliable tool for ...
This study analyzed the atmosphericemissions produced by the live firing of a 155 mm Howitzer gun. The study was conducted during a live firing training exercise at a Canadian Forces Base. Air emissions were sampled continuously for 3 hours. Particles and chemicals were accumulated on sampling media during the firing of 69 rounds. A single round was fired using 4 bags of propellants, and an additional 3 rounds were fired using 5 bags of propellant. Samples included particulate matter; hydrogen cyanide; polycyclic aromatic hydrocarbons (PAHs); dinitrotoluene compounds; benzene; toluene; ethylbenzene; xylene; metals; aldehydes; nitric acid; nitric oxide; nitrogen dioxide; hydrogen sulphide; and sulphur dioxide. Samples were collected at 8 m to the left of the gun as well as at 22 m in front of the gun muzzle in the line of fire. Results of the study showed that 60 per cent of the particles were below 10 {mu}m. Formaldehyde ...
A study was undertaken to examine the uptake, distribution, and interaction of five activation products (Co-57, Be-7, Cs-134, Rb-83, and Mn-54) within the biotic and abiotic components surrounding the waste treatment lagoons of the Los Alamos Meson Physic...
The United Nations Framework Convention on Climate Change (UNFCCC) was approved in 1992 to respond to the worl-wide concern about the warming of the planet. The primary target was the stabilization of the concentration of greenhouse gases in the atmosphere, in an attempt to reduce to the minimum the degradation of the environment caused by humans. By virtue of the Convention, the Parts2 are committed to reach their objectives in the reduction of the emissions. A Conference of the Parts was stablished to promote the effective application of the Convention. The third Conference of the Parts, celebrated in Kyoto (Japan, 1997) approved, by consensus, the denominated Kyoto Protocol, in which 39 developed countries and countries with economies in transition were committed to reduce their emissions of greenhouse gases between years 2008 and 2012 in a 5.2 global percent with respect to the 1990 levels. Three {sup f}lexibility ...
In the framework of the European Fusion Technology Programme ECN participates in a NET task PSM-8 `Coatings and Surface Effects on Stainless Steel 316L`. High emissivity coatings were developed for enhanced heat transfer from graphite tiles to a Stainless Steel First Wall. Four candidate materials, Cr{sub 2}O{sub 3}, Black Cr, Al{sub 2}O{sub 3}/TiO{sub 2} and TiC were tested as candidate high emissivity coatings. These coatings were manufactured by atmospheric and vacuum plasma spraying technique and the Black Chromium coatings were manufactured by a galvanic coating technique. The tests included total emissivity measurements and Low Cycle Fatigue (LCF) experiments. The total emissivity of two TiC coatings at 525 K appeared to be 0.62 and 0.64. The total emissivity of the TiC and 5 wt% TiO{sub 2}/Al{sub 2}O{sub 3} coating was about 0.7. (orig.)
The problem during the continuous idling operation of diesel engine is about the time increase in emission of HC (hydrocarbon which is not burned yet) into the atmosphere. A pilot injector having been developed, the time increase in HC emission was studied in order to ameliorate the combustion during the idling. An engine and spray unit were used with the above developed pilot injector for the experiment. Three types of injector were also used for the comparison purpose. Investigation was made of penetration characteristics of spray on the pump tester in the atmosphere, locally averaged droplet size distribution inside the spray, both droplet size and velocity distributions, and emission characteristics by the mounting test onto the engine. The developed pilot injector was most effective in controlling the HC emission. The time increase in HC ...
Carbonyl compounds constitute an important reactive class of non methane volatile organic compounds. They can be emitted directly to the atmosphere from primary sources such as combustion engines, landfills and wastewater surfaces or as secondary products by the photochemical oxidation of hydrocarbons and other volatile organic compounds 1-3. Carbonyls photo-oxidize during the day to produce toxic radicals such as OH, HO_2, RO and RO_2. These species react with nitrogen oxides (NOx) and other VOCs present in the atmosphere to form tropospheric ozone (O_3); a highly reactive oxidizing agent that is harmful to human health, agricultural products and climate 4, 5. Hence identifying the levels and sources of ozone precursors such as low carbonyls, carbon monoxide (CO) and NOx derivatives, and understanding their physical and chemical transformation in the troposphere is an important task due to their atmospheric and adverse ...
The current situation in the development of nuclear power in the world and in Czechoslovakia is briefly outlined and the possibilities are discussed of alternative energy resources. The environmental impact is described of conventional power plants firing coal; sulphur and nitrogen oxides are mentioned and their environmental impacts shown. Their quantities and the quantities of other gaseous, liquid and soid wastes produced by coal power plants are given. Annual estimates are presented of radioactive material emissions; trace amount emissions of toxic metals and their ecological risks are shown. Concern over the increasing concentration of CO_2 in the atmosphere is voiced. For nuclear power plants, the amount of radionuclides in stack emission and of those released into water flows is tabulated. Their effect on the aqueous ecosystem is characterized as is thermal pollution of water flows and the ...
Measurements of dissolved and atmospheric nitrous oxide (N{sub 2}O) are presented for three coastal environments: (1) the central North Sea, (2) the German Bight, and (3) the Gironde estuary. The contribution of coastal regions to the oceanic emissions of atmospheric N{sub 2}O were also determined. N{sub 2}O was measured with a gas chromatograph equipped with an electron capture detector and analyzed. The surface waters of the central North Sea and the German bight were found to be near equilibrium with the overlying atmosphere, while the mean saturation in the Gironde estuary was 132%. Mean saturations in coastal regions without estuaries or upwelling phenomena were only slightly higher than in the open ocean. When estuaries and regions with upwelling are included, however, approximately 60% of the oceanic N{sub 2}O flux is attributable to coastal regions. A review of published data indicated that ...
Data on the postfire dynamics of soil properties in the foci of Siberian moth population outbreaks are considered. It has been shown that controlled fires set in pest-defoliated forests result in the loss of approximately 75% of carbon and 50% of nitrogen from the forest litter through their emission into the atmosphere and in the enrichment of the upper soil horizons with potassium and phosphorus (this concerns both total and movable forms). Microbiological processes in the organogenic horizon undergo significant transformation, the density of microarthropods decreases, and the abundance of mites becomes hundreds of times lower. PMID:15354965
Both the nature of international climate policy architectures and the development and diffusion of new energy technologies could dramatically influence future costs of reducing global emissions of greenhouse gases. This paper explores the implications of interactions between technology availability and performance and international policy architectures for technology choice and the social cost of limiting atmospheric CO2 concentrations to 500 ppm by the year 2095. Key issues explored in the paper include the role of bioenergy production with CO2 capture and storage (CCS), overshoot concentration pathways, and the sensitivity of mitigation costs to policy and technology.
In the prevention of atmospheric pollution by sulfur dioxide emissions from acid absorbers in contact process sulfuric acid plants in which the unconverted SO/sub 2/ is accumulated by adsorption in a zeolite adsorbent bed and desorbed back into the acid production system, it is found that ambient moist air, after partial dehydration in an acid scrubber is suitably used both to cool down and hot purge desorb the zeolite beds. In addition the pure water derived from the ambient air is advantageously used in the acid-making system.
The paper demonstrates an application of advanced decision support tools within the framework of the environmental information system of the Province of Milan. These tools include environmental simulation models, multi criteria analysis, risk analysis and environmental accounting for marketable emission permits. After describing the general structure of the system, three demonstrational case studies are introduced concerning: groundwater pollution management; atmospheric pollution management; urban environmental quality perception and management. In the conclusion, potential use of tools like the ones implemented by the province of Milan within the framework of Local Agenda 21 processes is recalled.
Progress reports on the European Research Centre for Air Pollution Control Measures project are presented. Topics covered were: assessment and analysis of the impacts of airborne pollutants on forest trees, and distinction from other potential causes of recent forest dieback; research into atmospheric dispersion, conversion and deposition of airborne pollutants; development and optimization of industrial technical processes to reduce or avoid emissions; and providing instruments and making recommendations to the industrial and political sectors.
Intensive measurements of organic acids, inorganic acids, aldehydes and peroxyacetyl nitrate (PAN) in urban air were carried out at a Southern California smog receptor site, Glendora, CA, August 12-22, 1986. The objective of this project was to augment the data base regarding organic acids in urban air and to assess their role with emphasis on ambient levels, diurnal variations, phase distribution, emissions, in-situ formation and removal. The relative abundance of organic acids and inorganic acids was determined for the first time from simultaneous measurements carried out during this study.
Before large-scale anthropogenetic emissions the environmental factors have been rather stable for thousands of years, varying yearly, seasonally and daily in rather regular manners around some mean values. In this century the emissions of CO{sub 2}, sulphur and nitrogen from society to atmosphere are changing both atmospheric and soil environment at rates not experienced before. The fluxes to soil affect the contents of plant available nutrients and solubility of toxic compounds in the forest soil. Additionally, the chemical state of soil environment is coupled to tree growth, litter production and nutrient uptake as well as to the activity of biological organisms in soil, which decompose litter and release nutrients from it. Trees have developed effective regulation systems to cope with the environment during the evolution. The resulting acclimations improve the functioning of the trees if the ...
The abatement of CO{sub 2} emissions is a huge technical and economical challenge. Fossil fuels, which represent 88% of the world primary energy consumption, are the main source of the 25 billions of CO{sub 2} released each year in the atmosphere. The mastery of CO{sub 2} emissions cannot come from a single technology but must result from the simultaneous implementation of several means, like the development of carbon-free energies and the mastery of fossil fuel emissions. The opportunities of progress are numerous and compatible with the economic development. This document presents, first, the different greenhouse gases, the CO{sub 2} emissions per country and the main sources of CO{sub 2} emissions (power and heat generation, transports). Then it presents different ways of abatement of CO{sub 2} emissions: clean coal technologies, gas ...
We present a proof-of-concept analysis of the measurement of the health damage of ozone (O_3) produced from nitrogen oxides (NO_x=NO+NO_2) emitted by individual large point sources in the eastern United States. We use a regional atmospheric model of the eastern United States, the Comprehensive Air quality Model with Extensions (CAMx), to quantify the variable impact that a fixed quantity of NO_x emitted from individual sources can have on the downwind concentration of surface O_3, depending on temperature and local biogenic hydrocarbon emissions. We also examine the dependence of resulting O_3-related health damages on the size of the exposed population. The investigation is relevant to the increasingly widely used 'cap and trade' approach to NO_x regulation, which presumes that shifts of emission over time and space, holding the total fixed over the course of the summer O_3 season, will have minimal effect on the ...
Prompt fission neutron spectrum measurements at the University of Massachusetts Lowell 5.5 MV Van de Graaff accelerator laboratory require that the neutron detector efficiency be well known over a neutron energy range of 100 keV to 20 MeV. The efficiency of the detector, has been determined for energies greater than 5.0 MeV using the Weapons Neutron Research (WNR) white neutron source at the Los Alamos Meson Physics Facility (LAMPF) in a pulsed beam, time-of-flight (TOF) experiment. Carbon matched polyethylene and graphite scatterers were used to obtain a hydrogen spectrum. The detector efficiency was determined using the well known H(n,n) scattering cross section. Results are compared to the detector efficiency calculation program SCINFUL available from the Radiation Shielding Information Center at Oak Ridge National Laboratory.
The world fusion program has advanced to the stage where it is appropriate to construct a number of devices for the purpose of burning DT fuel. In these next-generation experiments, the expected flux and fluence of 14 MeV neutrons and associated gamma rays will pose a significant challenge to the operation and diagnostics of the fusion device. Radiation effects include structural damage to materials such as vacuum windows and seals, modifications to electrical properties such as electrical conductivity and dielectric strength and impaired optical properties such as reduced transparency and luminescence of windows and fiber optics during irradiation. In preparation for construction and operation of these new facilities, the fusion diagnostics community needs to work with materials scientists to develop a better understanding of radiation effects, and to undertake a testing program aimed at developing workable solutions for this multi-faceted problem. A unique facility to help in this ...
This paper assesses the effects of including carbon dioxide capture and storage (CCS) damage costs in a long-term energy scenario analysis for Europe. An external cost sensitivity analysis is performed with a bottom-up energy technology model that accounts not only for CCS technologies but also for their external costs. Our main conclusion is that in a business-as-usual scenario (i.e. without climate change intervention or externality internalisation), CCS technologies are likely to be deployed at least to some extent, mainly in the power generation sector, given the economic benefits of opportunities such as enhanced coal bed methane, oil and gas recovery. Under a strict climate (CO{sub 2} emissions) constraint, CCS technologies are deployed massively. With the simultaneous introduction of both CO{sub 2} and CCS taxation in the power sector, designed to internalise the external atmospheric and geological effects of CO{sub 2} ...
Geological carbon dioxide capture and storage (CCS) is currently seriously considered for addressing, in the near term, the problem of climate change. CCS technology is available today and is expected to become an increasingly affordable CO2 abatement alternative. Whereas the rapidly growing scientific literature on CCS as well as experimental and commercial practice demonstrate the technological and economic feasibility of implementing this clean fossil fuel option on a large scale, relatively little attention has been paid so far to the risks and environmental externalities of geological storage of CO2. This paper assesses the effects of including CCS damage costs in a long-term energy scenario analysis for Europe. An external cost sensitivity analysis is performed with a bottom-up energy technology model that accounts not only for CCS technologies but also for their external costs. Our main conclusion is that in a business-as-usual scenario (i.e. without climate change intervention ...
The Kyoto Protocol is often described as a good first step towards reducing greenhouse gas (GHG) emissions into the atmosphere. The Protocol endorses emissions trading, joint implementation including 'bubbling' between Annex 1 Parties, and a clean development mechanism that allows Annex 1 and non-Annex 1 Parties to act together to reduce emissions. However, the anticipated permit market will not function if uncertainties are not rigorously assessed and considered in any compliance process. With no reliable verification tool, it is impossible to effectively assess the different mechanisms and activities mentioned under the Protocol. Thus, it is very important to study the uncertainties underlying the Kyoto relevant GHGs, here with reference to Poland, because without the consideration of uncertainty robust verification can not occur. This paper presents information about the data used ...
The paper reports a work-in-progress outlook of a R and D project aimed at developing an advanced boiler for the combustion of virgin and exhaust olive husks at small scale. Fluidized bed technology has been preferred because of its well known advantages that include large thermal inertia, high combustion efficiency, low NOx emissions and considerable heat transfer rate. A 100 kW atmospheric bubbling fluidized bed combustor has been designed and built. The facility is equipped with devices for continuous fuel feeding as well as heat extraction from the bed region. Measurements of temperature and gas concentrations are obtained by using thermocouples and gas-analyzer. Steady state tests of combustion were carried out at typical fluidized bed combustion temperatures. Tests proved that not only exhaust olive husks but also the virgin ones - with a water content larger than 50% by mass - can be reliably fed onto the fluidized bed. Further, they ...
Subsurface and surface coalfires are a serious problem in many coal-producing countries. Combustion can occur within the coal seams (underground or surface), in piles of stored coal, or in spoil dumps at the surface. While consuming a non renewable energy source, coalfires promote several environmental problems. Among all GHGs that are emitted from coalfires, CO2 is the most significant because of its high quantity. In connection to this environmental problem, the core aim of the present research is to develop a hyperspectral remote sensing and radiative transfer based model that is able to estimate CO2 concentration (ppmv) from coalfires. Since 1960s remote sensing is being used as a tool to detect and monitoring coalfires. With time, remote sensing has proven a reliable tool to identify and monitor coalfires. In the present study multi-temporal, multi-sensor and multi-spectral thermal remote sensing data are being used to detect and monitor coalfires. Unlike the earlier studies, the ...
Subsurface and surface coalfires are a serious problem in many coal-producing countries. Combustion can occur within the coal seams (underground or surface), in piles of stored coal, or in spoil dumps at the surface. While consuming a non renewable energy source, coalfires promote several environmental problems. Among all GHGs that are emitted from coalfires, CO2 is the most significant because of its high quantity. In connection to this environmental problem, the core aim of the present research is to develop a hyperspectral remote sensing and radiative transfer based model that is able to estimate CO2 concentration (ppmv) from coalfires. Since 1960s remote sensing is being used as a tool to detect and monitoring coalfires. With time, remote sensing has proven a reliable tool to identify and monitor coalfires. In the present study multi-temporal, multi-sensor and multi-spectral thermal remote sensing data are being used to detect and monitor coalfires. Unlike the earlier studies, the ...
The use of global three-dimensional (3-D) models with satellite observations of CO2 in inverse modeling studies is an area of growing importance for understanding Earth s carbon cycle. Here we use the GEOS-Chem model (version 8-02-01) CO2 mode with multiple modifications in order to assess their impact on CO2 forward simulations. Modifications include CO2 surface emissions from shipping (0.19 PgC yr 1), 3-D spatially-distributed emissions from aviation (0.16 PgC yr 1), and 3-D chemical production of CO2 (1.05 PgC yr 1). Although CO2 chemical production from the oxidation of CO, CH4 and other carbon gases is recognized as an important contribution to global CO2, it is typically accounted for by conversion from its precursors at the surface rather than in the free troposphere. We base our model 3-D spatial distribution of CO2 chemical production on monthly-averaged loss rates of CO (a key precursor and intermediate in the oxidation of organic ...
A new emissivity measurement device with inductive sample heating is described. The disc shaped samples can be measured between 800 C and 2000 C in vacuum or in each available gas atmosphere. Two kinds of surface temperature measurement methods are described, one by measuring in a blackbody hole and one by measuring at the surface without additional measures to correct emissivity. Total normal and spectral emissivity at wavelengths between 0,5 {mu}m and 8,3 {mu}m of various high temperature materials like platinum and Pt-Rh-alloys, siliconcarbide and molybdenum disilicide have been measured. From the investigated materials a few have been selected as reference samples for comparative emissivity measurements fullfilling the requirement of stability on air up to 400 C to 1000 C in order to ensure reproducibility of the results at different measurement conditions in air and in vacuum. ...
We report the performance of a commercial recuperated micro gas turbine on biomass producer gas and mixtures of biomass producer gas with natural gas. The biomass producer gas, obtained by gasification at 850{sup o}C with air at atmospheric pressure, contains about 7% H2, 17% CO, 15% CO2, 4% CH4, 2% other hydrocarbons, 2% H2O, and a balance of N2 and Ar from air. It has a net heating value of about 6 MJ/(Nm{sup 3}). The micro gas turbine delivers full power (30 kW{sub e}) on gas mixtures with a net heating value of at least 15 MJ/(Nm{sup 3}). For gas of lower heating value, the maximum fuel gas flow allowed by the fuel control unit limits the attainable power. At reduced power, the lower limit for stable operation is a net heating value of about 8 MJ/(Nm{sup 3}). The gross efficiency of the micro gas turbine depends on the output power but not on the gas heating value, within our estimated measurement accuracy of about 2%. Above 70% of full power, NO ...
This paper examines the role that carbon dioxide capture and storage technologies could play in reducing greenhouse gas emissions if a significant unconventional fuels industry were to develop within the United States. Specifically, the paper examines the potential emergence of a large scale domestic unconventional fuels industry based on oil shale and coal-to-liquids (CTL) technologies. For both of these domestic heavy hydrocarbon resources, this paper models the growth of domestic production to a capacity of 3 MMB/d by 2050. For the oil shale production case, we model large scale deployment of an in-situ retorting process applied to the Eocene Green River formation of Colorado, Utah, and Wyoming where approximately 75% of the high grade oil shale resources within the United States lies. For the CTL case, we examine a more geographically dispersed coal-based unconventional fuel industry. This paper examines the performance of these industries under two ...
Present and potential future changes to the global environment have important implications for marine pollution and for the air-sea exchange of both anthropogenic and natural substances. This report addresses three issues related to the potential impact of global change on the air-sea exchange of chemicals: Global change and the air-sea transfer of the nutrients nitrogen and iron. Global change and the air-sea exchange of gases. Oceanic responses to radiative and oxidative changes in the atmosphere. The deposition of atmospheric anthropogenic nitrogen has probably increased biological productivity in coastal regions along many continental margins. Atmospheric deposition of new nitrogen may also have increased productivity somewhat in mid-ocean regions. The projected future increases of nitrogen oxide emissions from Asia, Africa and South America will provide significant increases in the rate of ...
Three independent studies have been conducted for assessing the impact of rocket launches on the earth`s environment. These studies have addressed issues of acid rain in the troposphere, ozone depletion in the stratosphere, toxicity of chemical rocket exhaust products, and the potential impact on global warming from carbon dioxide emissions from rocket launches. Local, regional, and global impact assessments were examined and compared with both natural sources and anthropogenic sources of known atmospheric pollutants with the following conclusions: (1) Neither solid nor liquid rocket launches have a significant impact on the earth`s global environment, and there is no real significant difference between the two. (2) Regional and local atmospheric impacts are more significant than global impacts, but quickly return to normal background conditions within a few hours after launch. And (3) vastly increased space launch ...
We describe the development of a fully coupled climate model configuration where the Community Climate System Model (CCSM) has been coupled with the VERDE (Visualizing Energy Resources Dynamically on the Earth) analysis modules that compute the response of the electric grid to temperature drivers. The VERDE model includes datasets characterizing the 26,500 sub-stations and 6,000 power generation stations fuel mix, efficiency, service areas, and future performance and these have been geo-located on a 1.4 degree latitude by 1.4 degree longitude CCSM grid (T85). The total electric customers have been computed using conversions derived from economic structure and population data. The carbon emissions per customer and the power generation in megawatts electric (MWe) have also been placed on reconciled 1 km, 4 km and the T85 climate model grid. The CCSM temperature for the present and future have been extracted from the climate model output and placed on the same grid as ...
The highly irradiated transiting exoplanet, HAT-P-7b, currently provides one of the best opportunities for studying planetary emission in the optical and infrared wavelengths. We observe six near-consecutive secondary eclipses of HAT-P-7b at optical wavelengths with the EPOXI spacecraft. We place an upper limit on the relative eclipse depth of 0.055% (95% confidence). We also analyze Spitzer observations of the same target in the infrared, obtaining secondary eclipse depths of 0.098+/-0.017%, 0.159+/-0.022%, 0.245+/-0.031% and 0.225+/-0.052% in the 3.6, 4.5, 5.8 and 8.0 micron IRAC bands respectively. We combine these measurements with the recently published Kepler secondary eclipse measurement, and generate atmospheric models for the day-side of the planet that are consistent with both the optical and infrared measurements. The data are best fit by models with a temperature inversion, as expected from the high incident flux. The models predict ...
Continuous-wave (cw) operation at temperatures up to 23 /sup 0/C of an Al/sub 0.26/Ga/sub 0.26/In/sub 0.48/P/Ga/sub 0.52/In/sub 0.48/P/ Al/sub 0.26/Ga/sub 0.26/In/sub 0.48/P double heterostructure (DH) laser has been achieved for the first time. The threshold current was 160 mA at 20 /sup 0/C for a device with a 10-..mu..m-wide and 250-..mu..m-long ion-implanted stripe geometry. The emission wavelength was 671 nm during cw operation at 10 /sup 0/C. To reduce thermal resistance to a heat sink, a dually stacked structure made of a thin (approx.0.3 ..mu..m) p-AlGaInP layer and a p-Al/sub 0.76/Ga/sub 0.24/As layer was used as a cladding layer. The DH wafer was grown by atmospheric pressure metalorganic chemical vapor deposition.
A new miniature high-frequency (HF) plasma source intended for bio-medical applications is studied using nitrogen/oxygen mixture at atmospheric pressure. This plasma source can be used as an element of a plasma source array for applications in dermatology and surgery. Nitric oxide and ozone which are produced in this plasma source are well-known agents for proliferation of the cells, inhalation therapy for newborn infants, disinfection of wounds and blood ozonation. Using optical emission spectroscopy, microphotography and numerical simulation, the gas temperature in the active plasma region and plasma parameters (electron density and electron distribution function) are determined for varied nitrogen/oxygen flows. The influence of the gas flows on the plasma conditions is studied. Ozone and nitric oxide concentrations in the effluent of the plasma source are measured using absorption spectroscopy and electro-chemical NO-detector at variable gas ...
Current hydrocarbon-based energy systems, current energy consumption and the push towards the utilization of renewable energy sources, fuelled by global warming and the need to reduce atmospheric pollution are discussed. The consequences of climatic change and the obligation of Annex B countries to reduce their greenhouse gas emissions in terms of the Kyoto Protocols are reviewed. The role that renewable energy sources such as hydrogen, solar and wind energy could play in avoiding the most catastrophic consequences of rapidly growing energy consumption and atmospheric pollution in the face of diminishing conventional fossil fuel resources are examined. The focus is on hydrogen energy as a means of storing and transporting primary energy. Some favorable characteristics of hydrogen is its abundance, the fact that it can be produced utilizing renewable or non-renewable sources, and the further fact that its combustion produces ...
The true nature of the progenitor to GRBs remains elusive; one characteristic that would constrain our understanding of the GRB mechanism considerably is gamma-ray polarimetry measurements of the initial burst flux. We present a method that interprets the prompt GRB flux as it Compton scatters off the Earth's atmosphere, based on detailed modelling of both the Earth's atmosphere and the orbiting detectors. The BATSE mission aboard the \\textit{CGRO} monitored the whole sky in the 20 keV - 1 MeV energy band continuously from April 1991 until June 2000. We present the BATSE Albedo Polarimetry System (BAPS), and show that GRB 930131 and GRB 960924 provide evidence of polarisation in their prompt flux that is consistent with degrees of polarisation of $\\Pi>35$% and $\\Pi>50$% respectively. While the evidence of polarisation is strong, the method is unable to strongly constrain the degree of polarisation beyond a systematics based estimation. ...
The distribution of environmental tritium and the correlation coefficients between tritium concentrations in several environmental samples and the emissions of tritiated water vapor from Wolsong NPP 1 were studied. The annual mean concentrations of atmospheric HTO were in the range 1#centre dot#31-29#centre dot#2 Bq m"-"3 and the long-term atmospheric dilution factors were in the range 10"-"7-10"-"6 s m"-"3. Annual mean concentrations of tritium in ground water were in the range 19#centre dot#2-27#centre dot#9 Bq l"-"1 at N-1 and 64#centre dot#1-189 Bq l"-"1 at S-2, and were generally less than 0#centre dot#2% of MPC_w (222 kBq l"-"1). The concentrations of tritium in precipitation decreased exponentially with distance from Wolsong NPP 1, falling to current global levels at about 25 km off-site. The highest concentration of tritium in soil moisture was observed in May and June, when the relative humidity was high. The ...
In this study, considering that Hg(2+) in wet flue gas desulfurization (FGD) systems can easily be reduced and then released into atmosphere, causing secondary pollution, the researches about Hg(2+) reduction and Hg(0) re-emission mechanism were carried out. The effects of several experimental parameters on the reduction were studied, including initial pH, temperature, and concentrations of Cl(-) and S(IV). Our experimental results indicated that Cl(-) had a restraining effect on the Hg(2+) reduction and Hg(0) re-emission, after 24h reaction, only 20.5% of Hg(2+) was reduced with 100mM Cl(-) in simulated desulfurization solution. Cl(-) can slow Hg(2+) reduction and Hg(0) re-emissions dramatically through changing reaction mechanism, with formation of new intermediate: ClHgSO(3)(-), which can decompose to Hg(0), but much more slowly than Hg(SO(3))(2)(2-) or HgSO(3). Simulating the conditions of the ...
Crystal Geyser in eastern Utah is a rare, non-geothermal geyser that emits carbon dioxide gas in periodic eruptions. This geyser is the largest single source of CO{sub 2} originating from a deep reservoir. For this study, the amount of CO{sub 2} emitted from Crystal Geyser is estimated through measurements of downwind CO{sub 2} air concentration applied to an analytical model for atmospheric dispersion. Five eruptions occurred during the 48-hour field study, for a total of almost 3 hours of eruption. Pre-eruption emissions were also timed and sampled. Slow wind during three of the active eruptions conveyed the plume over a grid of samplers arranged in arcs from 25 to 100 m away from the geyser. An analytical, straight-line Gaussian model matched the pattern of concentration measurements. Plume width was determined from least-squares fit of the CO{sub 2} concentrations integrated over time. The CO{sub 2} emission rate was ...
This paper describes an approach to solve air quality problems which frequently occur during iterations of the baseline change process. From a schedule standpoint, it is desirable to perform this evaluation in as short a time as possible while budgetary pressures limit the size of the staff available to do the work. Without a method in place to deal with baseline change proposal requests the environment analysts may not be able to produce the analysis results in the time frame expected. Using a concept called the Rapid Response Air Quality Analysis System (RAAS), the problems of timing and cost become tractable. The system could be adapted to assess other atmospheric pathway impacts, e.g., acoustics or visibility. The air quality analysis system used to perform the EA analysis (EA) for the Salt Repository Project (part of the Civilian Radioactive Waste Management Program), and later to evaluate the consequences of proposed baseline changes, consists of three ...
Studies have indicated that many people misunderstand climate change. Equipped with a limited mental model they inappropriately use a pattern matching heuristics to analyze climate change and mistakenly believe that we can stabilize atmospheric CO2 by keeping anthropogenic emissions at current rates. Drawing on the findings from cognitive and developmental psychology, I argue that the widespread misunderstanding of climate change may arise from an error in people?s ontological assumptions. The pattern matching heuristics highlights correlations in shape and associates with a static mental model, both of which are effective for understanding objects. When people adopt the pattern matching heuristics, they may have implicitly treated climate change as an object. However, climate change belon...
Climate change represents the largest social dilemma humans have ever faced, where individual actors maximise their personal gain by emitting greenhouse gases into the atmosphere even though this is detrimental to the collective global good. Cooperation on a global scale is urgently required if we are to overcome this problem. However, this is difficult to achieve because cooperators pay the cost of reducing emissions while any benefits are shared between cooperators and free-riders alike. In a risk-free, rational world cooperative behaviour can be promoted through mechanisms that increase the benefit of cooperating relative to free-riding, such as rewards or sanctions. In reality, however, outcomes are seldom certain and humans rarely behave rationally when confronted with risky prospects...
Within the framework of efforts to optimize state-of-the-art waste disposal methods, this research project makes a theoretical analysis of the propagation behaviour of pollutants from landfills and waste incineration plants into the immediate vicinity of such plants. In order to judge the propagation of pollutants near the above-mentioned waste disposal facilities, a calculation program was developed within the framework of this research project which permits simulation of the propagation of such emissions in a three-dimensional space by application of an Eulerian grid model. It is capable of realistically representing fluid flow conditions and pollutant concentrations for certain points of times within the complex building patterns of such plants, for randomly chosen atmospheric conditions. (orig.)
The coal-fired combined cycle with partial gasification and fluidized bed combustion (PGFBC-CC), also referred to as a hybrid cycle, has advantages of staged energy conversion and utilization, which can attain high thermal efficiency with low emissions. Four kinds of PGFBC-CC are studied in this paper, two based on pressurized fluidized bed combustion (PFBC) and two on atmospheric fluidized bed combustion (AFBC). Thermal performance calculations and parametric analyses were performed. On the basis of the results, from the above analyses, the best integration system for China is suggested. In addition, a preliminary exergetic analysis is carried out for three of the PGFBC-CC variants.
Room-temperature continuous-wave (cw) operation of a GaInP/AlGaInP multiquantum well (MQW) laser was achieved for the first time. The threshold current was 70 mA at 22 /sup 0/C for a device with an 8-..mu..m-wide and a 250-..mu..m-long planar stripe. The emission wavelength was 668 nm. The characteristic temperature T/sub 0/ was 138 K under cw operation. The wafer with the MQW structure composed of 100-A-thick GaInP wells and 40-A-thick AlGaInP barrier layers was grown by atmospheric pressure metalorganic chemical vapor deposition.
High energy consumption and the world population increase will lead to a shrinking use of fossil fuels. The combustion of Fossil fuel leads to the increase of carbon dioxide concentration in the atmosphere which leads to the probable increase of global warming. Therefore, concerns about carbon dioxide emissions may discourage widespread dependence on fossil fuels and encourage the development and use of renewable energy systems employing a variety of technologies Renewable energy systems have themselves an environmental impact. Land use and material employed are two areas that may have an adverse impact to the positive environmental picture of the renewable energy systems. The objective of this paper is to analyze these impacts with the use of a very powerful tool, the Life Cycle Assessment. (author)
At atmospheric pressure and room temperature, dielectric barrier discharge induced plasma oxidation for achieving supported TiO2 photocatalysts derived from TiCl4 adsorbed onto ?-Al2O3 pellets was studied. The supported TiO2/?-Al2O3photocatalysts prepared by a cyclic 'adsorption-discharge' approach, without requirement of heat treatment, exhibit high activity in the photocatalytic degradation reaction of formaldehyde. The mass spectra and optical emission spectra during O2/Ar discharge for oxidizing the adsorbed-state TiCl4 were measured. The mechanism for the TiO2 formation from adsorbed-state TiCl4 by plasma oxidation was discussed.
GaP and AlGaP were grown by atmospheric pressure OMVPE on GaP substrates using tertiarybutylphosphine as the phosphorus source. A specular surface of GaP was obtained on a (100) just-oriented surface at 700deg C. Hazy but uniform thickness AlGaP was obtained. The growth efficiency for GaP was 1.2x10{sup 3}{mu}m/mol and that for AlGaP was 2.1x10{sup 3}{mu}m/mol.4.2 K photoluminescence showed near-edge emission from both GaP and AlGaP. (orig.).
The scope of the present article is two-fold. Firstly, to conduct an experiment to provide the temperature-time history of the cooling of a hot ball bearing in quiescent ambient air. Secondly, to predict the temporal variation of the bearing under the hypothesis of natural convection, radiation or natural convection coexists with radiation for a non-vanishing total hemispherical emissivity of the surface of the bearing. Numerical solutions of the three governing nonlinear lumped heat equations were carried out with a Runge-Kutta-Fehlberg (RKF45) algorithm accounting for automatic step size control. The experimental data was obtained with chrome steel ball bearings of diameter 0.953 cm (7/16 in) heated in an electric oven to a pre-set temperature. The heated bearing was exposed later to ambient air at atmospheric temperature and pressure. (orig.)
Selective catalytic reduction (SCR) is a method of reducing the emissions of nitrogen oxides into the atmosphere. Peerless Manufacturing Co. specialises in designing and building SCR systems. The company uses fluid flow modelling to design systems, creating physical and/or numerical flow models to normalise the flow and eliminate potential problems. Computational fluid dynamics (CFD) is used to visualise fluid flow within SCR units and other types of equipment involving phase separators, air intake systems etc. An example is given of use of the commercial CFD code FLUENT to create a full-scale model of an SCR unit so its design could be modified for optimum performance. 1 fig., 1 photo.
Recently several investigators reported on various means of generating cold plasma jets at atmospheric pressure. More interestingly, these jets turned out to be not continuous plasmas but trains of small high velocity plasma packets/bullets. However, until now little is known of the nature of these 'bullets'. Here we present experimental insights into the physical and chemical characteristics of bullets. We show that their time of initiation, their velocity and the distance they travel are directly dependent on the value of the applied voltage. We also show that these bullets can be controlled by the application of an external electric field. Using an intensified charge coupled device camera we report on their geometrical shape, which was revealed to be 'donut' shaped, therefore giving an indication that solitary surface ionization waves may be responsible for the creation of these bullets. In addition, using emission spectroscopy, we follow ...
In order to quantify the biomass burning emissions, the main atmospheric pollution source of tropical and subtropical regions, we carried out the analysis of ashes that are also formed during these fires. To this end, we developed analytical methods to characterize the composition of savannah grass burning ashes by using X-ray fluorescence for mineral elements and microanalysis for C, H, O and N. Samples used in this work have been collected during laboratory combustion experiments, with chemically well-defined natural savannah grasses from Ivory Coasts and South Africa. The reproducibility and efficiency of different developed procedures have been studies. The analytical relative precision is generally better than 5%. This development has allowed to establish, for the first time, the global mass balance of ashes resulting from savannah grass burning. (authors). 16 refs., 3 figs., 8 tabs.
From the beginning of the 90s the analysis of the relationships between economic growth and environmental pressures has been influenced by the Environmental Kuznets Curve hypothesis or inverted-U shaped relationship between environmental pressure and per capita income. Following this hypothesis, once achieved certain income level, more economic growth is followed by environmental quality improvement. In this paper, we analyse and discuss the theories that support this hypothesis as well as the empirical evidence on this subject. Further on we analyse the relationship between per capita income and the main environmental pollutants for the case does not support the hypothesis. The empirical evidence shows that economic growth, by itself, does not entail a pollution reduction. (Author) 35 refs.
Full text.Lead is a toxic heavy metal. Nevertheless, it has been mined and used for more than 800 years. Among the different contemporary sources of lead pollution, emissions from the combustion of leaded gasoline is of particular concern, as it can constitutes more than 90 percent of total lead emissions into the atmosphere in congested urban areas. Concentrations of lead in air and blood are strongly correlated with gasoline lead content and traffic volume. As a result of the increasing awareness about the dangers of lead to human health and the measures to manage urban air pollution, the use of leaded gasoline has been decreasing worldwide. In Lebanon, in the absence of policies to reduce the use of lead in gasoline or to favor the use of unleaded gasoline, leaded gasoline is the predominant grade. The objective of this research work is to analyze the current status of gasoline, and to assess the feasibility and prospect ...
Nuclear energy provides a third of Europe's electricity with nearly no greenhouse-gas emissions. Sustained efforts are now being conducted to harmonize regulations all over Europe through WENRA and to converge on technical nuclear safety practices within the TSO network ETSON (European Technical Safety Organizations Network). In CANDU type NPP the tritiated water occurs by the neutron bombardment of deuterium. The tritiated water vapors imply health hazard (in the critical organs of the body the water presents a 10 day average biological half-life) and the early detection in nuclear plants of tritium emissions is important because the tritiated water vapors have the same characteristics as of atmospheric water vapors. By detecting tritiated vapors, the monitoring system ensures the following objectives: (a) indicates levels of tritium generally due to heavy water leakage, (b) reduces the possibility of health hazard. In ...
A high-performance power system (HIPPS) is being developed. This system is a coal-fired, combined-cycle plant that will have an efficiency of at least 47 percent, based on the higher heating value of the fuel. The original emissions goal of the project was for NOx and SOx to each be below 0.15 lb/MMBtu. In the Phase 2 RFP this emissions goal was reduced to 0.06 lb/MMBtu. The ultimate goal of HIPPS is to have an all-coal-fueled system, but initial versions of the system are allowed up to 35 percent heat input from natural gas. Foster Wheeler Development Corporation is currently leading a team effort with AlliedSignal, Bechtel, Foster Wheeler Energy Corporation, Research-Cottrell, TRW and Westinghouse. Previous work on the project was also done by General Electric. The HIPPS plant will use a high-Temperature Advanced Furnace (HITAF) to achieve combined-cycle operation with coal as the primary fuel. The HITAF is an ...
The growing global public concern over deteriorating air quality and greenhouse gases emissions released from various combustion processes, and particularly power plants and transportation system, led governments and local authorities, especially in industrialised countries into taking these issues seriously and establishing standards to reduce air pollution down to acceptable levels, (clean air act, earth summit,...). The transportation sector has another unwanted product, noise pollution caused by different segments of this sector including the noise produced by the engine, tires noise and exhaust noise, in addition to the noise product by private standby generals operating during electricity cut-off periods. To be able to estimate the environmental impacts of the national power plants and the transportation sector, it is necessary to collect enough data (samples of lead emissions, SO_2 concentration, sulfur dioxide, nitrogen oxides, ...
This study examined the atmospheric pollution created by some waste treatment and disposal facilities in the State of Kuwait. Air monitoring was conducted in a municipal wastewater treatment plant, an industrial wastewater treatment plant established in a petroleum refinery, and at a landfill site used for disposal of solid wastes. Such plants were selected as models for waste treatment and disposal facilities in the Arabian Gulf region and elsewhere. Air measurements were made over a period of 6 months and included levels of gaseous emissions as well as concentrations of volatile organic compounds (VOCs). Samples of gas and bioaerosols were collected from ambient air surrounding the treatment facilities. The results obtained from this study have indicated the presence of VOCs and other gaseous pollutants such as methane, ammonia, and hydrogen sulphide in air surrounding the waste treatment and disposal facilities. In some cases the levels ...
A cross-flow atmospheric plasma jet with distilled water or analyte solution nebulization has been investigated. The plasma gas flows perpendicularly to the RF powered electrode (11.21 MHz) and a grounded electrode was added for plasma stabilization. The working parameters of the plasma generator can be controlled in order to maximize either the plasma power (75 W) or the voltage on the RF powered electrode (plasma power, 40 W). The plasma gas, pure argon (0.4 l min-1) or a mixture of argon (0.3-0.4 l min-1) and helium (0-0.2 l min-1), was also used for liquid nebulization. Optical emission of the plasma, collected in the normal viewing mode, was used for plasma diagnostics and for evaluating its excitation capabilities. The influence of helium content in the mixed-gas plasma on the plasma characteristics and on the emission axial profiles of the plasma gas constituents and of the analytes originate from the wet aerosol was ...
Nitrogen oxides play a critical role in the chemistry of the atmosphere and indirectly influence global warming through the production of ozone. At Barrow, Alaska, the NOAA long-term surface ozone record indicates an increase of about 2% per year during the summer months. Since NO_x (NO+NO_2) concentrations above about 30 ppt (parts per trillion) result in net ozone production in the presence of sunlight, the authors propose that the observed Barrow surface ozone increase is related to anthropogenic nitrogen oxide emissions. A high-sensitivity chemiluminescent instrument for measurements of nitrogen oxides has been built to test this hypothesis. Measurement campaigns have been conducted during summer 1988 and spring 1989, and are continuing during spring and summer 1990. Periods during which the NOV concentrations measured at the GMCC site were unaffected by local (Barrow) emissions were selected from the data record. ...
Most prior climate change assessments for U.S. agriculture have focused on major world food crops such as wheat and maize. While useful from a national and global perspective, these results are not particularly relevant to the Northeastern U.S. agriculture economy, which is dominated by dairy milk production, and high-value horticultural crops such as apples (Malus domestica), grapes (vitis vinifera), sweet corn (Zea mays var. rugosa), cabbage (Brassica oleracea var. capitata), and maple syrup (sugar maple, Acer saccharum). We used statistically downscaled climate projections generated by the HadCM3 atmosphere-ocean general circulation model, run with Intergovernmental Panel on Climate Change future emissions scenarios Alfi (higher) and B1 (lower), to evaluate several climate thresholds of direct relevance to agriculture in the region. A longer (frostfree) growing season could create new opportunities for farmers with enough capital to take ...
Reinforcement of the legislation concerning the emission of atmospheric pollutants, aerosols, refrigerants, solvents etc and the reduction of the greenhouse effect, has led to the development of performing instruments for the survey and control of ambient air quality and for the limitation of exhaust gases, combustion products, volatile organic compounds (VOC), particulates and noxious compounds in the atmosphere. This study is divided in 4 main parts. The first part describes the context of the air quality control: the problems linked with the environment and health, the pollutants characteristics, the pollution levels and the detection sensitivity of instruments according to the different type of pollutants (petroleum products, VOCs, ozone compounds, particulates, smells..), the protocols of air pollution measurements and their application (chimney smokes, industrial volatile compounds, indoor and ambient air quality, ...
Bacteria and fungi are ubiquitous in the atmosphere. The diversity and abundance of airborne microbes may be strongly influenced by atmospheric conditions or even influence atmospheric conditions themselves...Full Text Available
Atmospheric electrodynamics research is summarized, focusing on three general areas: the ionosphere as a source for middle atmospheric electrodynamics, regional and global scale electrodynamics, and thunderstorms and lightning. New or improved instrumentation techniques which have furthered atmospheric electrodynamics research are also discussed. 93 refs.
This book is divided into the following chapters: the atmospheric boundary layer; atmospheric diffusion; pollutants and their properties; and environmental monitoring and impact.
... 2-93 An Atmospheric Particle Emits Electromagnetic ... atmospheric water vapor produces a hydrometeor. ... subject to wind movement (either blowing ...
A study was undertaken to examine the uptake, distribution, and interaction of five activation products (Co-57, Be-7, Cs-134, Rb-83, and Mn-54) within the biotic and abiotic components surrounding the waste treatment lagoons of the Los Alamos Meson Physics Facility (LAMPF). The study attempted to ascertain where, and what specific interactions were taking place among the isotopes and the biotic/abiotic components. A statistical approach, utilizing Multivariate Analysis of Variance (MANOVA), was conducted testing the radioisotopic concentrations by (1) the trophic levels (TROPLVL) in each position sampled on the grid, (2) where sampled on the grid (TRAN), (3) where sampled with-in each grid line (PLOT), and (4) the side with which sampled (SIDE). This provided both the dependent and independent variables that would be tested. The Null Hypothesis (Ho) tested the difference in the mean values of the isotopes within/between each of the four independent variables. The ...
A study was undertaken to examine the uptake, distribution, and interaction of five activation products (Co-57, Be-7, Cs-134, Rb-83, and Mn-54) within the biotic and abiotic components surrounding the waste treatment lagoons of the Los Alamos Meson Physics Facility (LAMPF). The study attempted to ascertain where, and what specific interactions were taking place among the isotopes and the biotic/abiotic components. A statistical approach, utilizing Multivariate Analysis of Variance (MANOVA), was conducted testing the radioisotopic concentrations by (1) the trophic levels (TROPLVL) in each position sampled on the grid, (2) where sampled on the grid (TRAN), (3) where sampled with-in each grid line (PLOT), and (4) the side with which sampled (SIDE). This provided both the dependent and independent variables that would be tested. The Null Hypothesis (Ho) tested the difference in the mean values of the isotopes within/between each of the four independent variables. The ...
The first essential before embarking on the radiation-hardening of electrical insulation - mostly magnet coils - in any beam line application is to obtain a reliable estimate of the dose to the components. These are examples ( switchyards at SLAC and LAMPF) where the degree of hardness specified was much higher than was required. Although experience shows that the cost premium for substantial radiation - hardening is of the order of 10%, it has also become clear that well - designed beam line have negligible losses: hardening is required only in the vicinity of targets, collimators or other beam - intercepting devices. Where the beam is deliberately scraped, local shielding will minimize the associated radiation in the surroundings. Electron machines have their own special problems due to synchrotron radiation, so certainly coils and other electrical equipment should be kept away from the beam bend - plane. Because proton beams interact with thick targets in the ...
ZnO thin films were electrodeposited in aqueous solution on gilded p-type Si wafer substrates. Thermal treatments were carried out on different films in Ar atmosphere at different temperatures, between 200 and 600 {sup 0}C. Surface morphology studies using scanning electron microscopy and atomic force microscopy show a smooth surface for an annealing temperature of 400 {sup 0}C with a roughness mean square value of about 15 nm and a precipitation of ZnO microcrystals on the deposit surface at 600 {sup 0}C. X-ray diffraction experiments reveal a decrease in the c-parameter value from 5.223 to 5.206 A after treatment at 600 {sup 0}C, due to the removal of hydrogen from the film. Raman spectroscopy analyses show an improvement in the crystal quality of the film and a decrease in the compressive stress inside the deposit. Photoluminescence observations reveal an important change in the UV emission band after annealing at 200 {sup 0}C. A visible ...
In front of the risks linked with the increase of the greenhouse gas emissions in the atmosphere, the decision makers must take into consideration first, the scientific advice of climatic change experts, and second, the considerable inertia of the climatic system. Thus, any action implemented so far will have an impact all along the 21. century and later whatever the future human activities. The aim of this memento is to sensibilize the decision makers about the possible consequences of their choice in terms of volume of greenhouse gases and of medium- and long-term evolution: 1 - stakes, role of local decision-makers (greenhouse effect and climatic change, France's international commitment, stakes, liabilities of local decision makers, decentralization laws, local plans of fight against greenhouse effect, public information and dialogue); 2 - urbanism and transports (urban displacements, alternatives to individual cars, collective ...
It is very difficult to compare environmental impacts of various electricity generation technologies and fuel types because they are extremely divergent. The most widely accepted common denominator today is the so-called external cost by which a monetary value is associated with environmental damage. In this paper, damages to human health resulting from Croatian thermal power plants annual operation are presented. Stack emissions have been translated into ambient concentrations by atmospheric dispersion modelling. Existing data on relations between human health degradation and ground concentrations of the analysed pollutants have been used. Geographic information software has been used in order to account for spatially dependent data. Monetary values have been assigned to the estimated human health damage. External costs resulting from impact of Croatian thermal power plants airborne emissions on human health have been ...
A method for the quantitative determination of atmospheric hydroperoxyl radical comprising: (a) contacting a liquid phase atmospheric sample with a chemiluminescent compound which luminesces on contact with hydroperoxyl radical; (b) determining luminescence intensity from the liquid phase atmospheric sample; and (c) comparing said luminescence intensity from the liquid phase atmospheric sample to a standard luminescence intensity for hydroperoxyl radical. An apparatus for automating the method is also included.
Yellow-emitting pulsed laser operation of an Al/sub 0.37/Ga/sub 0.15/In/sub 0.48/P/Al/sub 0.16/Ga/sub 0.36/In/sub 0.48/P/ Al/sub 0.37/Ga/sub 0.15/In/sub 0.48/P double heterostructure laser diode was obtained at 77 K. The emission wavelength was 579 nm. The threshold current density was 5.6 kA/cm/sup 2/ for a diode with a Si/sub 3/N/sub 4/ insulated 8-..mu..m-wide and 250-..mu..m-long stripe geometry. The device was made from a DH wafer grown by conventional metalorganic chemical vapor deposition using triethyl metals and phosphine as source materials.
The general responses proposed to reduce CO{sub 2} emissions to the atmosphere are conservation, improved efficiency and fuel substitution. These are valid options but other alternatives such as CO{sub 2} capture and disposal may be more attractive for specific areas. There are good reasons why the capture and disposal option fits the situation in Western Canada. The first and obvious reason is the importance of hydrocarbon energy to the regional economy. Here the economy is based on the production, utilization and sale of hydrocarbons such as coal, oil and natural gas and we intend to stay in business. Besides meeting the Canadian demand, natural gas from Alberta is used in the US as far away as Boston and Los Angeles. Canadian heavy crude oil serves much of the American Midwest and coal from the Canadian Rocky Mountains is exported to Japan. Although many may consider these hydrocarbon reserves and fossil fuel production as part of the ...
Ways of reducing the excessive energy consumption in the Polish sugar industry are examined. The three main areas where energy reduction measures might be taken are: reducing the process heat demand which arises from the need to evaporate excess water from the juice supplied to the crystallisers; improving the effectiveness of the thermal system by moving from the present four-effect evaporation to five-effect evaporation and using crystallisation vapours for juice heating; replacing old steam boilers with more efficient units. Most Polish sugar factories are relatively small, however, and the energy saving measures, all of which require the installation of more modern equipment, are not economically feasible in the short term. Moreover, the stringent limits on atmosphericemissions which come into effect in 1998 will require factories to use low-sulphur coal and install costly glue-gas cleaning equipment. With limited funds available this may ...
A workshop on radioactivity in coal use was held on September 15 through 17, 1981, under the auspices of the US Department of Energy, Office of Environmental Programs, and the Los Alamos National Laboratory. The purpose of the workshop was to identify research issues associated with radioactivity resulting from the use of coal for electric power generation. The concensus of the 10 scientists participating in the workshop was that a moderate to strong need exists for research in solubility of fly ash in different fluids and for determination of radioactivity in construction materials. Several additional research issues were identified but were given a lower priority. Summaries of each presentation are included. Titles are: some effects of coal combustion on the radiation environment; radionuclides in western coal at Mound; low-level radiation in coals utilized and ashes produced at New York State electric utilities; radioactivity from coal use - where are the problems; chemistry of ...
Very High Temperature gas cooled nuclear Reactor (VHTR), which was coupled with Sulfur-Iodine (SI) thermo-chemical cycle, has been selected for the Nuclear Hydrogen Development and Demonstration (NHDD) project in Korea Atomic Energy Research Institute. Among the various hydrogen production methods, Sulfur-Iodine (SI) thermo-chemical cycle is a good method as a massive hydrogen production without CO2 emission. In SI cycle, the sulfuric acid decomposition is one issue for the material corrosion on high temperature and pressure condition. For the simulation of the sulfuric acid decomposition, we designed a sulfuric acid loop with a small-scale gas loop which is simulated for the integrity and feasibility tests on a H2SO4 decomposition process. The primary objective of the loop is to validate the corrosion and the mechanical performances of a key component of the NHDD, Process Heat Exchanger (PHE). In this paper, we discussed the preliminary thermohydraulic analysis of ...
In this study, the effects of hydrogen peroxide on laminar, premixed, methane-air flames at atmospheric pressure and temperature were investigated using CHEMKIN III and GRI 3.5 mechanism. The range of fuel/air equivalence ratio {phi} was varied from 0.6 to 1.2, and the amount of hydrogen peroxide was altered from 0% to 20% volumetric fraction of the methane-hydrogen peroxide (air excluded) mixture. The burning velocity was found to increase with increasing hydrogen peroxide addition, with a relatively larger increase for the fuel-richer mixtures ({delta}S{sub u} up to 15 cm/s for {phi} {approx}=1.2). The adiabatic flame temperature rose with hydrogen peroxide addition, and the temperature rise per unit hydrogen peroxide addition was more significant ({delta}T up to 100 K) for the leaner mixtures. For the same mixture stoichiometry, adding hydrogen peroxide also increased CO concentration and NO{sub x} emissions somewhat. Accordingly, the ...
This study is part of a greater project from IPT (Sao Paulo's Institute of Technology), which foresaw an energetic use for elephant-grass (Pennisetum purpureum). Biomass gasification is an sustainable option for energy supply, which presents low pollutants emission rate and allows - through the global cycle of growing and consumption of feedstock (vegetables), a balance between consumption and production of carbonic gas, preventing an increase of the carbonic gas levels in the atmosphere. A gasifier was built with internal diameter of 400 mm and total height of 4600 mm . The equipment was tested for gasification of elephant-grass (Pennisetum purpureum) at a 100 kg/h rate. The equipment was tested and some constructive faults were detected. In the countryside, this biomass is commonly used for cattle feeding It was evaluated an adequate diesel-electric-generator. to work at hybrid regime, using 70% biomass gas and 30% diesel. With the ...
In car parks of considerable length, the removal of exhaust emissions, is carried out by air-conditioning systems mainly through transverse ventilation over short routes. The required air-conditioning ducts frequently produce a reduction in the available parking space simply due to their presence, resulting in restrictive effects on the level of acceptance by the users. In such cases, remedial action can be taken by creating ductless longitudinal ventilation. Depending on the required room air quality in the zones with the highest level of pollution, the volumetric flows for longitudinal disposal are no greater than those for conventional transverse ventilation. In conjunction with architecturally clear and positive lighting designs, clearly laid out car parks with a friendly atmosphere can be created which the user will be pleased to accept. (orig./BWI)
Catalytic combustion has demonstrated the ability to provide low NO /SUB x/ emissions while maintainin high combustion efficiency. Recently, under joint NASA Lewis, EPA, and Acurex sponsorship, a catalytic reactor was tested for 1000 hours to demonstrate durability in combustion environments representative of advanced automotive gas turbine engines. At a 740K air preheat temperature and a propane fuel/air ratio of 0.028 by mass (/phi/FA = 0.44), the adiabatic flame temperature was held at about 1700K. The graded cell monolithic reactor measured 5 cm in diameter by 10.2 cm in length and was operated at a reference velocity of 13.4 m/s at 1 atmosphere pressure Measured NO /SUB x/ levels remained below 5 ppm while unburned hydrocarbon concentrations registered near zero and carbon monoxide levels were nominally below 20 ppm. The durability test included several parametric turndown studies and ended with a series of on/off cycling tests to further ...
The rate coefficients for the reactions of OH radical with CH3Br and CH2Br2 were measured as functions of temperature using the laser photolysis - laser induced fluorescence method. This data was incorporated into a semiempirical model (Solomon et al., 1992) and a 2D model to calculate the steady-state ozone depletion potentials (ODP) and atmospheri lifetimes, tau, with greatly improved accuracy as compared to earlier studies. The calculated ODPs and tau are 0.65 and 1.7 years and 0.17 and 0.41 years for CH3Br and CH2Br2, respectively, using the semiempirical model. These lifetimes agree well with those calculated using a 2D model. This study better quantifies the ODPs and tau of these species which are needed inputs for discussion of possible regulation of human emissions currently under international considerations. 29 refs.
Significant development of an oil shale industry has been projected over the next few decades. The nation's largest oil shale reserves exist in the Wyoming Basin and Colorado Plateau physiographic provinces. This study presents a brief description of the environmental setting and land-use pattern of the region, with a review of the major environmental issues associated with each proposed technology for extracting shale oil. Serious effects may be expected from the modification of very large land surfaces through open-pit mining and spent-shale disposal. The impacts include habitat destruction, potential species loss, and deterioration of surface and groundwater quality. In situ retorting of shale may result in major alterations of groundwater quantity, quality, and flow regimes. Mine dewatering from in situ retorting requires the disposal of large volumes of highly saline water, threatening the quality of subsurface and surface water resources. A significant decline of water ...
This study explores the effects of atmospheric CO2 enrichment and climate change on soil moisture (W{sub r} ) and biome-level water limitation (L{sub TA}), using a dynamic global vegetation and water balance model forced by five different scenarios of change in temperature, precipitation, radiation, and atmospheric CO2 concentration, all based on the same IS92a emission scenario. L{sub TA} is defined as an index that quantifies the degree to which transpiration and photosynthesis are co-limited by soil water shortage (high values indicate low water limitation). Soil moisture decreases in many regions by 2071-2100 compared to 1961-1990, though the regional pattern of change differs substantially among the scenarios due primarily to differences in GCM-specific precipitation changes. In terms of L{sub TA}, ecosystems in northern temperate latitudes are at greatest risk of increasing water limitation, while in most other ...
Sulfuric acid and its partially or completely neutralized salts with ammonia are believed to result from the oxidation of sulfur dioxide in cloud water and in other heterogeneous media present in the atmosphere. Due to the natural abundance of ammonia and the ubiquitous presence of sulfur in the atmosphere, (NH/sub 4/)/sub 2/SO/sub 4/ is commonly the dominant chemical species in the ambient aerosol. The amounts of ammonium sulfates are expected to be very low in areas far removed from anthropogenic emissions of sulfur dioxide. The chemical composition of submicrometer aerosol particles was determined at the Mauna Loa Observatory (MLO) on Mauna Loa in Hawaii during an eight-day period in August 1986. The MLO site was selected for this measurement because it is the only ground-based aerosol observatory in the remote Pacific Ocean that allows extended sampling of aerosols in the free troposphere. Measurements were made using ...
We report on a recent search for {bar {nu}}{sub e} appearance from stopped {pi}{sup +} {yields} {mu}{sup +}{nu}{sub {mu}} and {mu}{sup +} {yields} e{sup +}{nu}{sub e}{bar {nu}}{sub {mu}} decay made by the LAMPF experiment E645. The appearance of {bar {nu}}{sub e} may occur from {bar {nu}}{sub {mu}} {yields} {bar {nu}}{sub e}, {nu}{sub e} {yields} {bar {nu}}{sub eL}, or {nu}{sub {mu}} {yields} {bar {nu}}{sub eL} oscillations. Appearance may also occur from rare {mu}{sup +} {yields} e{sup +}{bar {nu}}{sub e}{nu}{sub {mu}} decay, which is allowed by a multiplicative lepton charge conservation law. The neutrino energies range from E{sub {nu}} = 0 to 52.8MeV. The neutrino detector, which is located 26.1 meters from the neutrino source, consists of a segmented liquid scintillator and proportional drift tube central detector surrounded by both active and passive shielding. The central detector detects {bar {nu}}{sub e} through the {bar {nu}}{sub e}p {yields} ne{sup +} ...
With the improvements accomplished during the past 15 years in detection techniques and instrumentation and with the opening of space exploration, molecular spectroscopy has become a very efficient way to probe planetary atmospheres.
Recent field observations have shown that the atmospheric plumes of quiescently degassing volcanoes are chemically very active, pointing to the role of chemical cycles involving halogen species and...Full Text Available
Eu-#alpha#-SiAlON (Eu_m_/_2Si_1_2_-_m_-_nAl_m_+_nO_nN_1_6_-_n) was synthesized with nominal compositions having small m and n values, by firing the powder mixture of Eu_2Si_5N_8, #alpha#-Si_3N_4, AlN, and Al_2O_3 at 1900 "oC for 6 h under 1 MPa nitrogen atmosphere. The ratio of the oxidation state of Eu"2"+/Eu"3"+ was estimated from the X-ray absorption fine structure (XAFS) measurement. The observed X-ray absorption near edge spectrum (XANES) showed that the Eu ion in Eu-#alpha#-SiAlON was mainly in divalent state but also coexisted with a small amount of Eu in the trivalent state. The crystal structure of Eu-#alpha#-SiAlON was refined by the Rietveld analysis of the X-ray powder diffraction patterns. The lattice constants of the samples increased with increasing m and n values. The excitation band of Eu-#alpha#-SiAlON ranged from the ultraviolet to the visible light region and a broad emission band centered at about 590 nm were observed. The ...
The first part of the conference dealt with environmental effects of using coal. Papers dealt with the use of fly ash in agriculture and its effect on plant growth; the effect of airborne emissions on fish and wildlife resources, on watersheds, and on airsheds; the effects of surface mining on the ecology; blast effects; and health hazards associated with coal. The session on policy studies addressed the issue of cost of synthetic fuels and discussed the state and federal pollution regulations on burning coal and waste disposal. The session on combustion presented papers on atmospheric and pressurized fluidized-bed combustion for industrial and utility boilers. It also included papers on MHD power plants, coal-oil and coal-water mixtures, emission characterization and control, and catalytic combustors. The design of gasification plants, reaction kinetics, specific heats of coals and chars, simultaneous production of liquid ...
The first part of the conference dealt with environmental effects of using coal. Papers dealt with the use of fly ash in agriculture and its effect on plant growth; the effect of airborne emissions on fish and wildlife resources, on watersheds, and on airsheds; the effects of surface mining on the ecology; blast effects; and health hazards associated with coal. The session on policy studies addressed the issue of cost of synthetic fuels and discussed the state and federal pollution regulations on burning coal and waste disposal. The session on combustion presented papers on atmospheric and pressurized fluidized-bed combustion for industrial and utility boilers. It also included papers on MHD power plants, coal-oil and coal-water mixtures, emission characterization and control, and catalytic combustors. The design of gasification plants, reaction kinetics, specific heats of coals and chars, simultaneous production of liquid ...
Cereal straw, a by-product in the production of agricultural crops, is considered as a potentially large source of energy supply with an estimated value of 47 x 10{sup 18} J worldwide. However, there is some debate regarding the actual amounts of straw which could be removed from arable soils without jeopardizing their quality, as well as the potential trade-offs in the overall straw-to-energy chain compared to the use of fossil energy sources. Here, we used a deterministic model of C and N dynamics in soil-crop systems to simulate the effect of straw removal under various sets of soil, climate and crop management conditions in northeastern France. Model results in terms of nitrate leaching, soil C variations, nitrous oxide and ammonia emissions were subsequently inputted into the life-cycle assessment (LCA) of a particular bio-energy chain in which straw was used to generate heat and power in a plant producing bio-ethanol from wheat grains. Straw removal had ...
Since 1984 the Environmental Protection Agency (LfU) of the State of Baden-Wuerttemberg has been investigating the heavy metal burden of earthworms from representative long-term forest observation plots. These investigations are aimed at elucidating and assessing adverse effects of pollutants on the soil biocenosis. Methods: At first only lead and cadmium were measured in the worms; in repetitive measurements over the years further metals or metalloid elements such as aluminum, arsenic, chromium, cobalt, copper, manganese, mercury, nickel, thallium, vanadium, and zinc were added to the agenda. Results and conclusion: The frequency distribution of the metals in the earthworms was characterized statistically. For the first time state-wide background values, normal values and threshold values were established for all the elements measured. A comparable study with a similar range of parameters is known neither nationally nor internationally. Time trend studies have been available for lead ...
It has been understood that production of hydrogen from fossil and carbonaceous fuels with reduced CO{sub 2} emission to the atmosphere is key to the production of hydrogen-rich fuels for mitigating the CO{sub 2} greenhouse gas climate change problem. The conventional methods of hydrogen production from fossil fuels (coal, oil, gas and biomass) include steam reforming and water gas shift mainly of natural gas (SRM). In order to suppress CO{sub 2} emission from the steam reforming process, CO{sub 2} must be concentrated and sequestered either in or under the ocean or underground (in aquifers, or depleted oil or gas wells). Up to about 40% of the energy is lost in this process. An alternative process is the pyrolysis or the thermal decomposition of methane, natural gas (TDM) to hydrogen and carbon. The carbon can either be sequestered or sold on the market as a materials commodity or used as a fuel at a later date under less ...
In the Netherlands, the interest in biomass for electricity generation has increased, mainly due to environmental reasons. Currently, the Dutch energy sector is investigating technologies which can reduce CO{sub 2} emissions. The growth of biomass and its subsequent utilization for energy purposes circulates recycled atmospheric carbon and has no net discharge of CO{sub 2}. To reduce emissions from coal-fired power plants biomass co-firing options are investigated. After exhaustion of internal supplies of wood wastes and other residues an extra amount of 1.02 Mt{sub 20} would be needed. Two supply options exist: the use of internal energy crops and the import of biomass. Because production of energy crops in the Netherlands is a rather expensive option, biomass procurement and production outside the Netherlands is studied. Two countries were investigated for the possible import of biomass: Estonia and Uruguay. Estonia has ...
The Externally-Fired Combined Cycle (EFCC) is an attractive emerging technology for powering high efficiency combined gas and steam turbine cycles with coal or other ash bearing fuels. In the EFCC, the heat input to a gas turbine is supplied indirectly through a ceramic air heater. The air heater, along with an atmospheric coal combustor and ancillary equipment, replaces the conventional gas turbine combustor. A steam generator located downstream from the ceramic air heater and steam turbine cycle, along with an exhaust cleanup system, completes the combined cycle. A key element of the EFCC Development Program, the 25 MMBtu/h heat-input Kennebunk Test Facility (KTF), has recently begun operation. The KTF has been operating with natural gas and will begin operating with coal in early 1995. The US Department of Energy selected an EFCC repowering of the Pennsylvania Electric Company`s Warren Station for funding under the Clean Coal Technology Program Round V. The ...
Chemical composition of fine aerosol particles over the northern Chilean coastal waters was determined onboard the U.S. DOE G-1 aircraft during the VOCALS (VAMOS Ocean-Cloud-Atmosphere-Land Study) field campaign between October 16 and November 15, 2008. SO42-, NO3-, NH4+, and total organics (Org) were determined using an Aerodyne Aerosol Mass Spectrometer, and SO42-, NO3-, NH4+, Na+, Cl-, CH3SO3-, Mg2+, Ca2+, and K+ were determined using a particle-into-liquid sampler-ion chromatography technique. The results show the marine boundary layer (MBL) aerosol mass was dominated by non- sea-salt SO42- followed by Na+, Cl-, Org, NO3-, and NH4+, in decreasing importance; CH3SO3-, Ca2+, and K+ rarely exceeded their respective limits of detection. The SO42- aerosols were strongly acidic as the equivalent NH4+ to SO42- ratio was only ~0.25 on average. NaCl particles, presumably of sea-salt origin, showed chloride deficits but retained Cl- typically more than half the ...
Sources of industrial emissions of 1,3-butadiene are discussed both by process (production, consumers) and type (equipment leaks, point sources). Quantification of the emissions are presented, as reported...Full Text Available
When in resonance, Raman scattering exhibits strong enhancement ranging from four to six orders of magnitude. This physical phenomenon has been applied to remote sensing of the Earth`s atmosphere. With a 16 inch Cassegrain telescope and spectrometer/ CCD-detector system, 70-150 ppm-m of SO{sub 2} in the atmosphere has been detected at a distance of 0.5 kilometer. This system can be used to detect/monitor chemical effluence in the atmosphere by their unique Raman fingerprints. Experimental result together with detailed resonance Raman and atmospheric laser propagation effects will be discussed.
The radiation dose and the atmospheric dispersion for Pressurized Heavy Water Reactors (PHWR) are based on the CAN/CSA N288.2-M91 standards: for Pressurized Water Reactor (PWR) on the NRC Regulatory Guide 1.145. There are some differences between in the methodologies used in the standards, including the atmospheric dispersion model, the release height, the temperature lapse rate, the cutoff condition. This paper reports on a comparison of standards for atmospheric dispersion models of PHWRs and PWRs in order to determine which one is the more conservative. The comparison between PHWR and PWR for atmospheric dispersion factors and radiation doses confirms that there are no big differences
Hydroperoxides are important atmospheric oxidants. They are responsible for most of the oxidation of aqueous-phase SO(sub 2) to sulfate in the northeastern United States, resulting in the formation of acid precipitation and visibility-reducing sulfate aerosol (Penkett et al., 1979; Lind et al., 1987; Madronich and Calvert, 1990; Tanner and Schorran, 1995). Atmospheric hydrogen peroxide (H(sub 2)O(sub 2) or HP) is produced by the self-reaction of hydroperoxyl radicals (HO(sub 2)); higher organic peroxides are produced by reaction of HO(sub 2) with alkylperoxyl radicals (RO(sub 2)). Peroxyl radicals, along with OH, are chain carriers in the complex photochemical process that produces tropospheric ozone. Thus, concentrations of peroxides and their free radical precursors depend on solar intensity and ambient concentrations of water vapor, ozone, NO(sub x) (NO+ NO(sub 2)), and VOCs (volatile organic compounds). Several investigators have ...
The Kyoto Protocol foresees emission trading but does not yet specify verification of (uncertain) emissions. This paper analyses a setting in which parties can meet their emission targets by reducing emissions, by investing in monitoring (reducing uncertainty of emissions) or by (bilaterally) trading permits. We derive the optimality conditions and carry out various numerical simulations. Our applications suggest that including uncertainty could increase compliance costs for the USA, Japan and the European Union. Central Europe and the Former Soviet Union might be able to gain from trading due to higher permit prices. Emissions trading could also lower aggregate uncertainty on emissions.
Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this study, ALSTOM Power Inc. (ALSTOM) has investigated several coal fired power plant configurations designed to capture CO{sub 2} from effluent gas streams for use or sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating ...
{sup 14}C is a is a long-lived beta-emitting nuclide (T{sub 1/2} = 5730 years) produced naturally in the upper atmosphere as a result of reactions between neutrons and stable {sup 14}N({sup 14}N(n,p){sup 14}C). Although in a lesser extent, nuclear power plants produce {sup 14}C as well during their routine operation. Since it is converted in {sup 14}CO{sub 2} and mixed throughout the atmosphere, it is incorporated into plant tissues, via photosynthesis process, and hence in food chain. Because of the biological importance of {sup 14}C and long half-life, it is of interest to quantify the amounts released by nuclear industry. The Brazilian nuclear central named Nuclear Central Admiral Alvaro Alberto (CNAAA) has two nuclear reactors of PWR type in operation, Angra I (657 MWe) and Angra II (1350 MWe), and one under construction, Angra III (1309 MWe PWR). The aim of this study was to determine the strength of the sources and the {sup 14}C content ...
The 8 papers in the report deal with the following areas: Introduction to diesel particulate emissions, alternative fuels, and the transit industry; Technical problems and policy issues associated with the 1991 bus emissions standards; Reducing transit bus emissions: comparative costs and benefits of methanol, particulate traps, and fuel modification; Effects of applying emissions averaging, trading, and banking to transit buses; Strategic review of heavy-duty engine emission regulations and alternate fuels; Meeting bus emissions standards--a perspective; Economic evaluation of bus maintenance contracting; Objectives for a transit-bus-fleet management data, information, and knowledge exchange.
The growing concern of the population with regards to the problem of atmospheric pollution has induced a change in the role of air quality monitoring networks, especially those monitoring air pollution in large cities which suffer from summer smog. The population is no longer satisfied with real-time measurements but wants to be warmed of high pollutants concentrations in advance. Some countries have been forecasting air pollution, and especially ozone, for a large number of years. Although most of them use statistical models based on the analyses of past conditions which induced high pollution episodes, some predict ozone levels using only their knowledge of the meteorological situation. Nowadays two trends appear regarding ozone forecasting: either very basic statistical methods, such as regression, or more sophisticated ones, such as neural networks. The paper then reviews several behaviours common to most forecasting models: the uncertainly due to the great ...
Thin-film solar cells on flexible, lightweight, space-qualified substrates provide an attractive approach to fabricating solar arrays with high mass-specific power. A polycrystalline chalcopyrite absorber layer is among the new generation of photovoltaic device technologies for thin film solar cells. At NASA Glenn Research Center we have focused on the development of new single-source precursors (SSPs) for deposition of semiconducting chalcopyrite materials onto lightweight, flexible substrates. We describe the syntheses and thermal modulation of SSPs via molecular engineering. Copper indium disulfide and related thin-film materials were deposited via aerosol-assisted chemical vapor deposition using SSPs. Processing and post-processing parameters were varied in order to modify morphology, stoichiometry, crystallography, electrical properties, and optical properties to optimize device quality. Growth at atmospheric pressure in a horizontal hotwall reactor at 395 C ...
The number of reports concerning the chemical toxicology of metals which are released in the environment by natural as well as anthropogenic sources, have been increasing constantly. Lead, cadmium, and manganese have found a variety of uses in industry, craft, and agriculture owing to their physical and chemical properties. The environmental burden of heavy metals has been rising substantially by smelter emission in air and waste sewage in water. Further, organic compounds of lead and manganese used as antiknock substances in gasoline are emitted into the atmosphere by automobile exhaustion. Such environmental contamination of air, water, soil, and food is a serious threat to all living kinds. Although these metals are known to produce their toxic effects on a variety of body systems, much emphasis has been placed on their effects on the nervous system owing to apparent association of relatively low or ...
The objective of the current study was the gradual development of the formation of the nitride layer during inductive r.f. plasma nitriding. The study centers on characterization of refined layers and plasma diagnostics in the vicinity of the sample, and raises critical questions of how the layers and interfacial microstructure might affect the near-surface properties. The composition of the plasma near the surface of the sample (plasma layer) was examined by optical emission spectroscopy and mass spectrometry during plasma nitriding and while sputtering the sample after the nitriding process. It was observed that during the nitriding process, the plasma layer contains Ti, NH[sub n] species, N (or/and N[sup +]), H[sub n] species (or/and H[sup +][sub 2]). However, when the nitrided sample was exposed to argon plasma, Ti, Al and NH were observed. It was found that two distinct sublayers, comprising [delta]-TiN and [delta]-TiN + [epsilon]-Ti[sub 2]N phases, were ...
Early in 1988 RWE decided to overhaul the power station at Goldenberg. This was necessary due to the age of the plant, the obligation to supply heat and process steam and recent amendments of environmental legislation. After analysing demands and needs one developed a plant concept with a 290 t/h and a 400 t/h steam generator. Due to lack of space the decision was made in favour of a circulating atmospheric fluidised bed combustion instead of steam generators with pulverised lignite combustion as these steam generators take up much more space due to the legally required desulphurisation plants for gaseous emissions. Apart from generating steam RWE wishes to gain experience with this combustion technology and test it for suitability and use in large-scale plant. (orig./KO) [Deutsch] Aufgrund des fortgeschrittenen Alters, der aktuellen Umweltschutzgesetzgebung sowie bestehender Versorgungsverpflichtungen fuer Waerme und Prozessdampf wurde Anfang ...
Anthropogenic sulfate aerosol, together with particles from biomass burning, may significantly reduce the climatic warming due to man-made greenhouse gases. The radiative forcing of aerosol particles is based on their ability to scatter and absorb solar radiation (direct effect), and on their influences on cloud albedos and lifetimes (indirect effect). The direct aerosol effect depends strongly on the size, number and chemical composition of particles, being greatest for particles of 0.1-1 {mu}m in diameter. The indirect aerosol effect is dictated by the number of particles being able to act as cloud condensation nuclei (CCN). For sulfate particles, the minimum CCN size in tropospheric clouds is of the order of 0.05-0.2 {mu}m. To improve aerosol parameterizations in future climate models, it is required that (1) both primary and secondary sources of various particle types will be characterized at a greater accuracy, and (2) the influences of various atmospheric ...
Ethanol has excellent fuel properties, such as high octane, high heat of vaporization and low photochemical reactivity in the atmosphere. It is less volatile than gasoline and there is lower smog formation from evaporative emissions of pure ethanol compared to gasoline. As such, ethanol has emerged as an important alternative energy source that is sustainable, efficient, cost effective, convenient and safe. In 2006, global production of ethanol reached 13.5 billion gallons, up from 12.1 billion gallons in 2005. However, in light of the current debate of food versus fuel, the industry must shift to non-food feedstocks. This paper described an emerging technology to cost-effectively produce ethanol from sweet sorghum stalks, the most promising alternative feedstock to corn, via solid state fermentation (SSF). Experiments of advanced solid state fermentation (ASSF) for ethanol production from sweet sorghum by Saccharomyces cerevisiae were ...
One of the five projects selected for funding within the Clean Coal Technology Program is a project proposed by the Pennsylvania Electric Company (Penelec) of Johnstown, Pennsylvania. Penelec proposes to enter into a cooperative agreement with DOE to design, construct and operate a 600 ton-per-day, 66-megawatt (MWe), coal-fueled, externally-fired combined cycle (EFCC) electric power generation facility. The EFCC is an emerging technology with promise for operating highefficiency combined gas- and steam-turbine cycles on coal. The central feature of EFCC is its coupling of the gas turbine to an external, atmospheric-pressure, coal combustor via a hightemperature ceramic heat exchanger (CerHx{reg_sign}) developed by Hague International. The EFCC technology is attractive because, unlike competing combined cycles such as Integrated Gasification (IGCC) and Pressurized Fluidized Bed Combustion (PFBC), it eliminates the need for a costly gas cleanup system to protect the ...
Several years of research on seven different plants (five terrestrial and two aquatic species) suggest that the beneficial effects of atmospheric CO2 enrichment may be divided into three...Full Text Available
The concentration of some organic acids in the atmosphere was determined using a wet effluent diffusion denuder-aerosol collector coupled with Ion Chromatography. Three organic acids and four inorganic anions were identified and quantified in the air sample, taken from the backyard of PSI. (author)
The growing use of coal for heating and electric power generation and diesel engines in light duty motor vehicles will increase not only the existing atmospheric concentrations of criteria pollutants...Full Text Available
We calculate the expected fluxes of cosmic ray nuclei with charge 5 ≤ Z ≤ 28 at various depths in the earth's atmosphere, taking into account the initial charge distribution,...Full Text Available
Only half of the carbon dioxide produced by burning fossil fuels stays in the atmosphere. It is thought that the oceans absorb the rest. To understand the world's climate it is necessary to know how the atmosphere, ocean and biosphere interact.
Laser devices are currently in widespread use in particular by armed forces for different tasks. Electro-optical sensors as well as unprotected human eyes are extremely sensitive to laser radiation and can be permanently damaged from direct or reflected beams. Laser damage depends on the interaction between the laser beam and the atmosphere in which it traverses. The atmospheric conditions, including the range, terrain features, turbulence, and atmospheric particulates, may alter the laser's effect on different electro-optical devices and systems. When a laser beam passes through the atmosphere the optical turbulence affects the beam. As a result, temporal intensity fluctuations (scintillations) or spatial variations in intensity within a beam cross-section occur. Atmospheric scintillations pose a safety problem because an observer or sensor can be subjected to the risk of a ...
Carbon steel, copper, zinc and aluminium samples were exposed in different sizes with known ambient parameters in Gran Canaria Island and atmospheric corrosion was investigated. Weight-loss measurements used to determine corrosion damage were complemented...
Secondary deuterium in the atmosphere are produced in interactions by primary cosmic rays. The shape of their energy spectrum depends on the primary cosmic ray spectrum incident at the top of the atmosphere. At high energies, the spectral shape depends on the primary spectrum of helium and heavy nuclei. However, at very low energies, specially below the geomagnetic cut-off, the spectral shape depends on the evaporation and recoil processes and hence almost independent of the spectral shape of the primary radiation. It is undertaken a calculation of the secondary deuterium spectrum at small atmospheric depths at various latitudes and the results will be presented.
NASA's Glory spacecraft is equipped to survey and map aerosols in Earth's atmosphere during a mission marking the return to flight of the Taurus XL rocket.
This contribution analyzes elastic-backscatter lidar data and temperature and humidity profiles from radiosondes acquired in Barcelona in July 1992. Elastic-backscatter lidar data reveal the distribution of aerosols within the volume of atmosphere scanned. By comparing this information with temperature and humidity profiles of the atmosphere at a similar time, we are able to asses de relationship among aerosol distribution and atmospheric stability or water content, respectively. Comparisons have shown how lidar`s revealed layers of aerosols correspond to atmospheric layers with different stability condition and water content.
It is carried out a calculation to determine the energy spectra of secondary {sup 3}He at small atmospheric depths. It is produced in the spallation reaction of primary helium and heavier nuclei in the overlying atmosphere. It is examined the effect of the geomagnetic cut-off on the spectral shape of the secondary {sup 3}He nuclei. The calculations are being carried out for both solar minimum and maximum periods. Results from these calculations will be presented at the Conference.
The observed strength of the carbon dioxide absorption bands recorded on spectrobolograms of the transparency of the earth's atmosphere between wavelengths 300 and 2500 nanometers as part of the Smithsonian Solar Constant Program were used to extract the abundance of carbon dioxide in the atmosphere. The details of the analysis and the sources of error are discussed. 11 references, 5 figures, 1 table. (ACR)
The horizontal spread of a plume in atmospheric dispersion can be described by the standard deviation of horizontal direction. The widely used Pasquill-Gifford classes of atmospheric stability have assigned typical values of the standard deviation of horizontal wind direction and of the lapse rate. A measured lapse rate can thus be used to estimate the standard deviation of wind direction. It is examined by means of a large dataset of fast wind measurements how good these estimates are. (author) 1 fig., 2 refs.
The method and results of the quantitative gas chromatographic determination of volatile organic substances in an urban atmosphere are presented. The concentration of organic substances was determined by using a mixed adsorber consisting of graphitized thermal carbon black and activated charcoal modified by pyrocarbon. Average, maximum and minimum concentrations of constant organic components in the atmosphere of Leningrad as a typical large industrial city are reported.
Laser-induced breakdown spectroscopy (LIBS) is typically performed at ambient Earth atmospheric conditions. However, interest in LIBS in other atmospheric conditions has increased in recent years, especially for use in space exploration (e.g., Mars and Lunar) or to improve resolution for isotopic signatures. This review focuses on what has been reported about the performance of LIBS in reduced pressure environments as well as in various gases other than air.
This report is a compilation of the Chalk Point surface weather and ambient atmospheric profile data for the months of September to December 1975. The atmospheric profiles were made using rawinsonde instrumentation. The compilation includes the 0700 EST d...
The atmospheric correction factor for cosmic-ray antiproton measurements has been re-calculated using an approximation of the slab model. It is found that the effect of the antiproton non-annihilation inelastic interaction is quite significant. Neglecting this effect has led to an overestimation of the expected antiproton flux at low energies at the atmosphere.
The resulting emissions of the firing of ceramic products of all type are described, the factors are enumerated to diminish the emissions in the kilns and the technologies applied in the kilns to reduce these emissions while carrying out energy saving are described briefly. (author)
Reliable and consistent characterization of the stable isotope composition of atmospheric water vapour and its temporal variability are important prerequisites to the wider application of isotope mass balance methods in atmospheric and water balance studies. A new approach is proposed which utilizes standard class-A evaporation pans, which have sufficient volume to buffer short-term transient variations in atmospheric conditions, justifying the assumption of constant kinetic isotopic fractionation effects in concert with precisely measured temperature and relative humidity to derive vapour isotopic composition. The results of the studies suggest that isotopic sampling of existing, conventionally operated class-A evaporation pans could offer a straightforward and cost-effective solution to the problem of documenting the shifting isotopic distribution in atmospheric moisture
The transport of air pollutants in coastal regions has been known to be strongly affected by the mesoscale atmospheric circulations such as sea-land breezes. These mesoscale atmospheric circulations depend on synoptic weather conditions. In this study, a three-dimensional sea-land breeze model was developed to evaluate the effects of the sea and land breezes on the atmospheric dispersion of radioactive materials released from nuclear power plants in Korea. In the model, the hydrostatic primitive equations in the terrain-following coordinate system were used. The mesoscale atmospheric circulation simulation were carried out under various synoptic weather conditions for all seasons around the Wolsung nuclear power plant site.
The transport of air pollutants in coastal regions has been known to be strongly affected by the mesoscale atmospheric circulations such as sea-land breezes. These mesoscale atmospheric circulations depend on synoptic weather conditions. In this study, a three-dimensional sea-land breeze model was developed to evaluate the effects of the sea and land breezes on the atmospheric dispersion of radioactive materials released from nuclear power plants in Korea. In the model, the hydrostatic primitive equations in the terrain-following coordinate system were used. The mesoscale atmospheric circulation simulation were carried out under various synoptic weather conditions for all seasons around the Wolsung nuclear power plant site.
In this study the soil/vegetation/atmosphere-model based on the formulation of Deardorff was refined to hour basis and applied to a field in Vihti. The effect of model parameters on model results (energy fluxes, temperatures) was also studied as well as the effect of atmospheric conditions. The estimation of atmospheric conditions on the soil-vegetation system as well as an estimation of the effect of vegetation parameters on the atmospheric climate was estimated. Areal surface fluxes, temperatures and moistures were also modelled for some river basins in southern Finland. Land-use and soil parameterisation was developed to include properties and yearly variation of all vegetation and soil types. One classification was selected to describe the hydrothermal properties of the soils. Evapotranspiration was verified against the water balance method
Water vapor is well known to be a critical component in many aspects of atmospheric research, such as radiative transfer and cloud and aerosol processes. This requires both improved measurements of the columnar water vapor and its profiles in the atmosphere in a wide range of conditions, and adjustment of water vapor parameterizations in radiation codes including the perfection of spectroscopic parameters. In this paper we will present the results of comparison of our calculations and downward solar fluxes measured with Rotating Shadowband Spectroradiometer under conditions of horizontally homogeneous clouds. We also will discuss the sensitivity of atmospheric radiation characteristics to variations of water vapor in the band 940 nm: these results may be useful for development of new methods of retrieval of the total column water vapor content (WVC) in the atmosphere from data of radiation observations.
A possibility of geophysical measurements using the large scale laser interferometrical gravitational wave antenna is discussed. An interferometer with suspended mirrors can be used as a gradiometer measuring variations of an angle between gravity force vectors acting on the spatially separated suspensions. We analyze restrictions imposed by the atmospheric noises on feasibility of such measurements. Two models of the atmosphere are invoked: a quiet atmosphere with a hydrostatic coupling of pressure and density and a dynamic model of moving region of the density anomaly (cyclone). Both models lead to similar conclusions up to numerical factors. Besides the hydrostatic approximation, we use a model of turbulent atmosphere with the pressure fluctuation spectrum f^{-7/3} to explore the Newtonian noise in a higher frequency domain (up to 10 Hz) predicting the gravitational noise background for modern ...
A three dimensional sea-land breeze model and lagrangian particle dispersion model have been employed for the study on the mesoscale atmospheric dispersion of radioactive materials released from Wolsung NPPs. In this study, atmospheric dispersion simulations are carried out under two synoptic weather conditions: the geostrophic flow is a weak northerly wind (CASE 1) and a strong northerly wind (CASE 2) on a clear day in spring. The results show that atmospheric dispersion is affected by sea-land breeze and the recirculation of particles by the change of wind direction between sea breeze and land breeze plays an important role in atmospheric concentration distribution of radioactive materials.
This paper summarizes the current scientific and technological knowledge about greenhouse gas emissions from various agricultural practices and the manufacturing of food. The study also provides estimates that compare agriculture-related alternatives for reducing greenhouse gas emissions.
In this study, a regional dynamical model (WRF) is used to drive biogenic emission models to calculate high resolution (10 x 10 km) biogenic emissions of isoprene (C_5H_8), monoterpenes (C_1H_1_6), and nitric oxide (NO) in China. This high resolution biogenic inventory will be available for the community to study the effect of biogenic emissions on photochemical oxidants in China. The biogenic emissions are compared to anthropogenic emissions to gain insight on the potential impact of the biogenic emissions on tropospheric chemistry, especially ozone production in this region. The results show that the biogenic emissions in China exhibit strongly diurnal, seasonal, and spatial variations. The isoprenoid (including both isoprene and monoterpenes) emissions are closely correlated to tree density and strongly vary with ...
A specific application of single photon emission tomography to the relative quantitation of the pituitary region is described together with the results obtained in 19 patients with pituitary adenoma...Full Text Available
activities, including the combustion of diesel fuel in heavy-duty vehicles and jet fuel in aircrafts. Current details on emissions from the transportation and other...
This report presents and discusses results from Task 5 of the study ''Fate of Mercury in Synthetic Gypsum Used for Wallboard Production,'' performed at a full-scale commercial wallboard plant. Synthetic gypsum produced by wet flue gas desulfurization (FGD) systems on coal-fired power plants is commonly used in the manufacture of wallboard. The FGD process is used to control the sulfur dioxide emissions which would result in acid rain if not controlled. This practice has long benefited the environment by recycling the FGD gypsum byproduct, which is becoming available in increasing quantities, decreasing the need to landfill this material, and increasing the sustainable design of the wallboard product. However, new concerns have arisen as recent mercury control strategies developed for power plants involve the capture of mercury in FGD systems. The objective of this study is to determine whether any mercury is released into the ...
The study described in this report is part of a project sponsored by the Toronto Atmospheric Fund, performed at the Lawrence Berkeley National Laboratory, to assess the potential role of surface property modifications on energy, meteorology, and air quality in the Greater Toronto Area (GTA), Canada. Numerical models were used to establish the possible meteorological and ozone air-quality impacts of increased urban albedo and vegetative fraction, i.e., ''cool-city'' strategies that can mitigate the urban heat island (UHI), significantly reduce urban energy consumption, and improve thermal comfort, particularly during periods of hot weather in summer. Mitigation is even more important during critical heat wave periods with possible increased heat-related hospitalization and mortality. The evidence suggests that on an annual basis cool-city strategies are beneficial, and the implementation of such measures is currently being ...
The Polarized Gamma-ray Observer (PoGOLite) is a balloon-borne instrument that will measure gamma-ray polarization in the energy range 25-80 keV from astronomical sources such as pulsars, accretion discs and jets from active galactic nuclei. The two additional parameters provided by such observations, polarization angle and degree, will allow these objects to be studied in a new way, providing information about their emission mechanisms and geometries. The instrument measures azimuthal scattering angles of photons within a close packed array of phoswich detector cells (PDCs) based on coincident detection of Compton scattering and photoelectric absorption. Each PDC comprises three different scintillating components and combines photon detection, active collimation and bottom anticoincidence into one single unit. The three parts are viewed by a photomultiplier tube (PMT) and pulse shape discrimination is used to identify signals from dierent parts. Surrounding the ...
An overview of emissive display technologies is presented. Display types briefly described include: cathode ray tubes (CRTs), field emission displays (FEDs), electroluminescent displays (ELDs), and plasma display panels (PDPs). The critical role of phosphors in further development of the latter three flat panel emissive display technologies is outlined. The need for stable, efficient red, green, and blue phosphors for RGB fall color displays is emphasized.
In this report is described the sources to nitrogen emission and how the emission have changed over time. The cost and effect of the proposals given by the Swedish Environmental Protection Agency to cope with the emission of nitrogen to the sea is also treated. A separate chapter describes what we know today about phosphorus and eutrophication Basic document to report SNV--4735. 25 figs, 11 tabs
Proper estimation of shipping emissions is essential for an impact assessment of shipping on air quality and health in port cities and coastal regions. In the Netherlands shipping is an important source of particulate matter. This report provides an internationally accessible and transparent summary and description of the methodologies used in the Netherlands Pollutant Release and Transfer Register (PRTR) to estimate PM emissions from shipping, including recently implemented updates.
This article analyses the role of energy intensity and the relationship between CO{sub 2} emissions and primary energy in order to explain the evolution of CO{sub 2} emissions by unit of real GDP. It also distinguishes two different meanings of CO{sub 2} emissions Kuznets curve hypothesis: the weak and the strong sense. It considers the case of Spain in the period 1972-1997 as an example in which there is not any evidence supporting this hypothesis in either sense. (author)
This paper reviews emission standards, technologies to control emissions, and the cost of these controls. It is concluded that international bodies will increasingly set minimum emissions, these standards will continue to be reduced, and in addition new substances will be controlled. The cost of this control will likely not exceed 0.5 cents per kWe-hr. 4 refs., 3 tabs.
The CO{sub 2} emissions can be reduced by using economic instruments, like carbon tax. This project included two specific questions related to CO{sub 2} taxation. First one was the economic effects of increasing CO{sub 2} tax and decreasing other taxes. Second was the economic adjustment costs of reducing net emissions instead of gross emissions. A computable general equilibrium (CGE) model was used in this analysis. The study was taken place in Helsinki School of Economics
Pollutant emissions due to fossil fuel and biomass energy utilization in Turkey have been estimated. Standard emission factors were used for estimating the levels of particulate matter, sulfur oxides, nitrogen oxides, carbon monoxide, volatile organic compounds, and aldehydes. The results are presented for different fuels and energy-consuming sectors for the reference year 1987. Total Turkish emissions vs energy consumption are presented for every fifth year since. 1960. (author).
In an attempt to obtain basic data for evaluation of exposure doses in Niigata Prefecture, the concentrations of tritium in atmospheric water, precipitation, river water, and tap water were measured. Samples of atmospheric water, river water, and tap water were collected once for 2 weeks; and precipitation collected for one week was used as sample. The concentration of atmospheric tritium depended on the concentration of tritium in moisture and the content of water in atmosphere. Tritium levels were high in May, November and March, and low in September. Regarding tritium concentrations, there was a good correlation between atmospheric water and precipitation. Tritium concentrations in both of them varied from sample to sample. The concentrations of tritium in river and tap water tended to be high during spring and low during summer and winter, although the variations were not so ...
Atmospheric transport represents one of the critically important pathways for the distribution of pollutants from any oil shale operation. Our experience in studying eastern and western shale resources and operation suggest many common features regarding the atmospheric domain, but also many significant differences. Any issue of atmospheric transport and dispersion can be broken down into major elements: source factors which include the spatial and temporal distribution of pollutant sources as well as their chemical and physical characteristics, boundary conditions which include the character of the underlying surface as a lower boundary and the large scale meteorological circulations as an ''upper'' boundary; and meteorological structure is the resulting wind, temperature, moisture, and turbulence environment in the volume of air occupied by emitted material in an ...
The costs of greenhouse gas emission-reductions vary among countries depending on emission levels, technologies used, past emission-reduction achievements, path of economic development, fuel mix, and initial endowment of hydrocarbon resources. The criterion of cost-effectiveness therefore suggests that the ways should be found to encourage emission reductions in the countries where the required costs of reduction of additional unit of emissions are the lowest. These countries usually face crucial capital constraints and have other development priorities than investing in reduction of greenhouse gas emissions. Developed countries could invest their resources in the former Soviet Union and the east European countries to achieve the same level of reduction of greenhouse gases with lower costs than they could in their own countries.
Proposed features of the competitive electricity market in Ontario were reviewed. The speaker predicted that demand for renewable energy in Ontario`s competitive electricity market will be affected by green power, emissions trading, labelling, and renewables portfolio standard. Under current regulations retailers can charge customers a premium for purchasing electricity generated by `green` sources. The existing limits on emissions of sulphur dioxide, nitrogen oxides and carbon dioxides will remain in place, but an emissions cap and trading program for all Ontario-based generation is an option to consider. Ontario`s Market Design Committee (MDC) has recommended the implementation of emissions trading for electricity-related air pollutants for all generators located in Ontario. The complex mechanics of emission trading are explained. The MDC recommendation of the use of standard ...
This report focuses on air quality at the Nevada Test Site (NTS) for 1994. A general description of the effluent sources are presented. Each potential source of NTS emissions was characterized by one of the following: (1) by monitoring methods and procedures previously developed at NTS; (2) by a yearly radionuclide inventory of the source, assuming that volatile radionuclides are released to the environment; (3) by the measurement of tritiated water concentration in liquid effluents discharged to containment ponds and assuming all the effluent evaporates over the course of the year to become an air emission; or (4) by using a combination of environmental measurements and CAP88-PC to calculate emissions. Appendices A through J describe the methods used to determine the emissions from the sources. These National Emission Standards for Hazardous Air Pollutants (NESHAP) ...
The methodology for studying the behaviour of the toxic pollutant metals (Hg, Pb, Cd, Cr) in the South Shetland region is presented here, toxic pollutants are caused by the urban and industrial activity at the Southern hemisphere and they are pressured to be incorporated to the region though atmospheric transport processes the Cs 137 (refI) was used as a tracing element, which was freed and dispersed in the atmosphere as a result of nuclear bombs testing. During the austral summer samples from ground, sediments, atmospheric and glacier were extracted.
Meteorological and radon concentration data referring to a measurement campaign carried out in Urbino, Central Italy, are reported and discussed. This study presents a method allowing monitoring of the vertical atmospheric stability using continuous measurements of radon gas near ground. In particular radon evidences the presence of temperature inversion such as the formation of the nocturnal stable layer and gives information on the vertical turbulence and the motion of air masses. This technique is very useful in describing the temporal evolution of the pollutants in the atmosphere. (author)
Recent developments in the analysis of Mira atmosphere, the determination of the pulsation mode, the problem of mass loss, and the evolution of the Mira variables are covered. Model atmospheres for Mira variables, including the opacities of the molecules expected in very late M-type atmospheres are discussed. The pulsation constant for Omicron Ceti is evaluated using T(eff) = 2900 + or - 200 K, and it is concluded that Miras are fundamental mode pulsators. The importance of molecular opacity to the driving of mass loss is evaluated, and it is pointed out that the radiation pressure on molecules is not a major factor in driving mass loss from Mira. Mass loss is considered as a factor in the calculations of the periods for Mira variables. 30 refs.
During a hypothetical severe incident in a nuclear power plant with core meltdown a large part of radioactive material is present as aerosol particles in the reactor containment. In current severe accident containment codes the potential influences of hydrogen combustions on the behaviour of aerosols are not considered. Among other effects dry resuspension can increase the aerosol concentration in the atmosphere. Already deposited aerosol material can be re-released into the containment atmosphere by atmospheric currents induced by hydrogen deflagrations or by other phenomena like steam explosions. The objective is to assess the possible influence of this dry resuspension effect on the radioactive source term. (author)
Carbon steel, copper, zinc and aluminium samples were exposed in different sizes with known ambient parameters in Gran Canaria Island and atmospheric corrosion was investigated. Weight-loss measurements used to determine corrosion damage were complemented with metallographic and XP S determination in order to characterize the structure and morphology of surface corrosion products. The ambient aggressiveness could be well evaluated from meteorological and pollution data. All atmospheric corrosion and environmental data were statistically processed for establishing general corrosion damage functions for carbon steel, copper, aluminium and zinc in terms of Gran Canaria extreme meteorological and pollution parameters. (Author)
This study investigates the carbon dioxide (CO2) emissions patterns in coordination with the economic development of Taiwan. The resulting quadratic relationship between emissions and income are partly due to the structural change of energy supply in Taiwan, with the introduction of nuclear energy in 1980 to 1986. This relationship is quite unique and different from the N-shaped relationships in some developed countries (de Bruyn and Opschoor, 1997; Friedl and Getzner, 2003). The CO2 emissions in Taiwan increase with the increasing imports of raw materials for economic activities and the increasing use of electricity. There is no evidence that the substantial increase of Taiwan's service sector contributed to slowing its CO2 emissions.
Method for determining the concentration of atomic species in gases and solids. Measurement of at least two emission intensities from a species in a plasma containing the species after a sufficient time period has elapsed after the generation of the plasma and during a second time period, permits an instantaneous temperature to be established within the sample. The concentration of the atomic species to be determined is then derived from the known emission intensity of a predetermined concentration of that species in the sample at the measured temperature, a quantity which is measured prior to the determination of the unknown concentration, and the actual measured emission from the unknown species, or by this latter emission and the emission intensity of a species having known concentration within the sample.
Mar 1, 2011... Science Research; Atmospheric Correction Prototype Algorithm for High ... spaceborne (Hyperion) and airborne (AVIRIS) hyperspectral data. ...
May 11, 2011 ... The Particle Environment Monitor (PEM) on NASA's Upper Atmosphere Research Satellite (UARS) measures the type, amount, energy, and ...
May 11, 2011 ... The Particle Environment Monitor (PEM) on NASA's Upper Atmosphere Research Satellite (UARS) measures the type, amount, energy, and ...
Information about the greenhouse effect, the role of greenhouse gases in global climate change, levels of greenhouse gases in the atmosphere, and references....
A floating boardwalk was constructed from the shore to ...... Irrespective of whether we could tie the outlier to a cause, a simple linear interpolation was ...
Fast automated analysis of hyperspectral imagery can inform ... hyperspectral image analysis. .... atmospheric correction with the Crism Analysis Tool [11]. ...
The impact of the azimuthal wave refraction in the middle atmosphere on the distribution of gravity wave amplitudes, propagation azimuths, and other wave parameters is investigated using a numerical ray-tracing model of gravity wave propagation through a representative zonal mean reference model of geostrophic winds and temperature in the middle atmosphere. Simulations are first performed with only a single type of gravity wave to help explain some important effects which occur during the refraction process. Then, a multiray simulation is performed which traces a crude spectrum of waves from different altitudes through the atmosphere for every month of a climatological year. The simulated wave climatologies are compared with observations. 108 refs.
Watkins, Harry L. Runyan, and Donald S. Woolston. Standard AtmosphereTables and Data for Altitudes ...... By W. S. Hyler, E. D. Abraham, and H. J. Grover. ...
This article addresses the need for new data on indirect effects of natural and anthropogenic aerosol particles on atmospheric ice clouds. Simultaneous measurements of the concentration and composition...Full Text Available
May 4, 2010 ... This routine interpolates atmospheric adtt seconds period forcing ... for one adtt interval. Interpolation is performed based on the value ...
In radio signal-based observing systems, such as Global Positioning System (GPS) and Interferometric Synthetic Aperture Radar (InSAR), the water vapor in the atmosphere will cause delays during the signal transmission. Such delays vary significantly with terrain elevation. In the case when atmospheric delays are to be eliminated from the measured raw signals, spatial interpolators may be needed. By taking advantage of available terrain elevation information during spatial interpolation process, the accuracy of the atmospheric delay mapping can be considerably improved. This paper first reviews three elevation-dependent water vapor interpolation models, i.e., the Best Linear Unbiased Estimator in combination with the water vapor Height Scaling Model (BLUE?+?HSM), the Best Linear Unbiased Es...
(1989], however, we modeled the phase using a sum of simple power law terms. We. chose to do our work on Triton's atmosphere using the exponential functions ...
The values of X = 0.77, Z = 0.035, and Y = 0.195 and the stage of evolution of Procyon are determined from the evolutionary tracks and the results of an analysis of the chemical composition of the atmosphere.
Abstract Satellite measurements and numerical forecast model reanalysis data are used to compute an updated estimate of the cloud radiative effect on the global multi-annual mean radiative energy budget of the atmosphere and surface. The cloud radiative cooling effect through reflection of short wave radiation dominates over the long wave heating effect, resulting in a net cooling of the climate system of - 21 Wm-2. The short wave radiative effect of cloud is primarily manifest as a reduction in the solar radiation absorbed at the surface of - 53 Wm-2. Clouds impact long wave radiation by heating the moist tropical atmosphere (up to around 40 Wm-2 for global annual means) while enhancing the radiative cooling of the atmosphere over other regions, in particular higher latitudes and sub-trop...
The lowest-mass stars, brown dwarfs and extrasolar planets present challenges and opportunities for understanding dynamics and cloud formation processes in low-temperature atmospheres. For brown dwarfs, the formation, variation and rapid depletion of photospheric clouds in L- and T-type dwarfs, and spectroscopic evidence for non-equilibrium chemistry associated with vertical mixing, all point to a fundamental role for dynamics in vertical abundance distributions and cloud/grain formation cycles. For exoplanets, azimuthal heat variations and the detection of stratospheric and exospheric layers indicate multi-layered, asymmetric atmospheres that may also be time-variable (particularly for systems with highly elliptical orbits). Dust and clouds may also play an important role in the thermal energy balance of exoplanets through albedo effects. For all of these cases, 3D atmosphere models are becoming an increasingly essential ...
The energy spectra of atmospheric-secondary protons and deuterium nuclei have been measured during the September 23, 1991, balloon flight of the NMSU/Wizard - MASS2 instrument. The apparatus was launched from Fort Sumner, New Mexico. The geomagnetic cutoff at the launch site is about 4.5 GV/c. The instrument was flown for 9.8 hours at an altitude of over 100,000 feet. Particles detected below the geomagnetic cutoff have been produced mainly by the interactions of the primary cosmic rays with the atmosphere. The measurement of cosmic ray energy spectra below the geomagnetic cutoff provide direct insights into the particle production mechanism and allows comparison to atmospheric cascade calculations.
Mar 1, 2011 ... NASA Technical Reports Server (NTRS) ... output (Southwest Research Institute's Mars Regional Atmospheric .... the University of Central Florida, the University of Michigan, and the University of Alabama in Huntsville. ...
There is a need to reduce air pollutant emissions in some U.S. urban regions to meet federal and state air quality guidelines. Opportunities exist for reducing pollutant emissions from natural gas appliances in the residential sector. A cost-benefit analysis on various pollutant-reducing strategies is needed to evaluate these opportunities. The effectiveness of these pollutant-reducing strategies (e.g., low-emission burners, energy conservation) can then be ranked among themselves and compared with other pollutant-reducing strategies available for the region. A key step towards conducting a cost-benefit analysis is to collect information on pollutant emissions from existing residential natural gas appliances. An extensive literature search was conducted to collect data on residential natural-gas-appliance pollutant emission factors. The literature primarily describes laboratory ...
Major advances in 'Energy and Materials Cycles' have been achieved in the removal of heavy metals from the solid residues of municipal waste incineration. It has been conclusively shown that the oxidation/reduction conditions established during the thermal treatment of filter ash have a decisive influence on the evaporation of groups of heavy metals. With respect to biomass gasification, studies have been carried out with respect to the best way of extracting pure hydrogen from the low calorific value gas that is typically obtained from a biomass gasifier. The overarching goal of the laboratory 'High Temperature Solar Technology' is the use of solar energy for the production of solar fuels, or for the reduction of CO{sub 2} emissions in large scale industrial processes that are conventionally carried out with the use of fossil fuels. In a short-term project targeted at the solar production of lime, highly encouraging results (98% ...
The analysis of oceanographic lidar systems measurements is often carried out with semi-empirical methods, since there is only a rough understanding of the effects of many environmental variables. The development of techniques for interpreting the accuracy of lidar measurements is needed to evaluate the effects of various environmental situations, as well as of different experimental geometric configurations and boundary conditions. A Monte Carlo simulation model represents a tool that is particularly well suited for answering these important questions. The PREMAR-2F Monte Carlo code has been developed taking into account the main molecular and non-molecular components of the marine environment. The laser radiation interaction processes of diffusion, re-emission, refraction and absorption are treated. In particular are considered: the Rayleigh elastic scattering, produced by atoms and molecules with small dimensions with respect to the laser ...
Ion Beam Induced Luminescence (IBIL) and Ion Beam Induced Charge Collection (IBICC) have been applied in the study of the luminescence emission efficiency and investigation of the homogeneity of the luminescence emission in phosphors. The IBIL imaging was performed by using sharply focused ion beams or broad/partially-focused ion beams. The luminescence emission homogeneity in samples was examined to reveal possible distributed crystal-defects that may lead to the inhomogeneity of the luminescence emission in samples.The purpose of the study is to search for suitable luminescent thin films that have high homogeneity of luminescence emission, large IBIL efficiency under heavy ion excitation, and can be placed as a thin layer on the top of microelectronic devices to be analyzed with Ion Photon Emission Microscopy (IPEM). The emission yield was ...
The objectives of this study were to characterize the changes of VOC material emission profiles over time and develop a method to account for such changes in order to enhance a source identification technique that is based on the measurements of mixed air samples and the emission signatures of individual building materials determined by PTRMS. Source models, including powerlaw model, doubleexponential decay model and mechanistic diffusion model, were employed to track the change of individual material emission signatures by PTRMS over a ninemonth period. Samples of nine typical building materials were tested individually for nine months and later in combination to obtain actual mixture emissions. VOC emissions from each material were measured in a 50liter smallscale chamber. Chamber air was sampled by PTRMS over a 28day period to determine their emission rate ...
This publication describes the modification of the road traffic exhaust emission calculation model LIISA and presents the new calculation results. The model has already established its position as the most important inventory tool for regional road traffic emissions in Finland. The LIISA model calculates road traffic emissions as a whole. The system comprises of three separate models: 1. a model for calculating automobile emissions for the years 2001-2021, 2. a model for calculating emissions backwards for the years 1980-2000, 3. a model for calculating the emissions of motorcycles and mopeds. All three parts have been modified. The LIISA model is one of the submodels of the comprehensive LIPASTO calculation system developed at VTT Building and Transport. The LIPASTO model is an inventory tool for emissions regarding all traffic modes in ...
Air toxics from the industrial wastewater treatment plants (IWTPs) impose serious health concerns on its surrounding residential neighborhoods. To address such health concerns, one of the key challenges is to quantify the air emissions from the IWTPs. The objective here is to characterize the air emissions from the IWTPs and quantify its associated uncertainty. An IWTP receiving the wastewaters from an airplane maintenance facility is used for illustration with focus on the quantification of air emissions for benzyl alcohol, phenol, methylene chloride, 2-butanone, and acetone. Two general fate models, i.e., WATER9 and TOXCHEM+V3.0 were used to model the IWTP and quantify the air emissions. Monte Carlo and Bootstrap simulation were used for uncertainty analysis. On average, air emissions fr...
Kelvin-Helmholtz instability of short gravity waves is examined in order to explain the recent findings of the decrease in momentum transfer from hurricane winds to sea waves. A three-fluid configuration of a foam layer between the atmosphere and the ocean is suggested to provide signifficant stabilization of the system and shifting the marginal critical wavelength to the shortwave part of the spectrum. It is conjectured that such stabilization leads to the observed drag reduction. The high contrasts in three fluid densities provide a universal mechanism for stabilizing surface perturbations.
DescriptionThis new research programme activity on Urban Atmospheric Science will deliver aspects of the NERC strategy: Next Generation Science for Planet Earth. It has been developed as part of the Environment, Pollution & Human Health theme. Research in the Environment, Pollution & Human Health theme is directed at elucidating key environmental processes that form part of a causal pathway between an environmental hazard and disease outcome, and providing a predictive capability of the risk to human heal [continued...
The sunlight-induced photocatalytic oxidation of aqueous benzene on TiO(2)-supported gold nanoparticles was considerably improved when the reaction was conducted under a CO(2) atmosphere. 13% yield and 89% selectivity of phenol was obtained on P25-supported gold nanoparticles under 230 kPa of CO(2). PMID:21952312
A mathematical model describing the behavior of a gas of any density released into a turbulent atmosphere was developed. A numerical treatment was established for two dimensional flow. An understanding of the effects of accidental or continuous release wa...
NH4+ inhibition kinetics for CH4 oxidation were examined at near-atmospheric CH4 concentrations in three upland forest soils. Whether NH4+-independent...Full Text Available
Organic molecules are a significant and highly varied component of atmospheric aerosols. Measurement of aerosol composition and improvements in our understanding of the complex chemistry involved in their formation and aging are being aided by innovations in soft ionization aerosol MS. (To listen to a podcast about this feature, please go to the Analytical Chemistry multimedia page at pubs.acs.org/page/ancham/audio/index.html.). PMID:21275431
A Lagrangian atmospheric dispersion model(K-LADM) combining a three dimensional sea-land breeze model has been developed and applied to the estimation of the quaterly and the annual averaged air tritium concentration around Wolsung NPP site. The estimated concentrations were compared with the observed concentration data. The results showed that the present Lagrangian Atmospheric dispersion model(K-LADM) provided very good agreement with the observations.
Immature seeds of castor bean (Ricinus communis) removed from the capsule at 25 to 40 days after pollination (25-40 DAP) and placed in an atmosphere of high relative humidity undergo...Full Text Available
''Climates of the Oceans'' deals with the atmosphere over the world oceans and provides a treatment not only of the climatic elements such as temperature, pressure, wind, precipitation etc., but also of the circulation of the atmosphere and its changes throughout the year. The connection between sea and overlying air is examined through studies of the water and heat balance. Numerous maps and tables illustrate the elements and their fluctuations over the water and on islands and coasts.
This work deals with a time-resolved optical study of the avalanche and streamer formation phases leading to breakdown in atmospheric nitrogen. The authors present the results obtained for nitrogen, from experiments and two-dimensional model simulations. This model is used to obtain a better insight in the relevant mechanisms and processes by a comparison of measurements and simulation data. The trends of externally measured quantities correspond with those predicted by the model.
Transport and deposition of atmospheric lead over the coastal zone of Northern Germany are investigated. It is shown that marked differences in the impact of the ecologically valuable wadden sea areas can occur between summer and winter time. Due to the formation of sea breeze systems in summer the coastal zone is likely to be less stressed than in winter when the pollutant is confined to a shallow layer above ground. (orig.) 10 refs.
In conducting aircraft surveys for uranium, it is found that temperature inversions can give spurious results because they promote accumulation of radon gas in the atmosphere. The "2"1"4Bi (daughter product of radon) gamma-rays detected from the atmosphere-borne radon are difficult to separate from the "2"1"4Bi gamma-rays originating from the ground, and providing a signature for uranium deposits. The purpose of the present study was to examine the feasibility of making remote temperature soundings of the atmosphere below a low-flying aircraft (140 m or less above ground) by the inversion of radiance measurements taken in the 15-micron carbon dioxide absorption band. Such measurements would identify those temperature inversion conditions possibly leading to an unacceptably large background of gamma-rays from the atmospheric radon. Thus, the incidence of spurious aerial survey data could be greatly ...
The close-in extrasolar giant planets (CEGPs) reside in irradiated environments much more intense than that of the giant planets in our solar system. The high UV irradiance strongly influences their photochemistry and the general current view believed that this high UV flux will greatly enhance photochemical production of hydrocarbon aerosols. In this letter, we investigate hydrocarbon aerosol formation in the atmospheres of CEGPs. We find that the abundances of hydrocarbons in the atmospheres of CEGPs are significantly less than that of Jupiter except for models in which the CH$_4$ abundance is unreasonably high (as high as CO) for the hot (effective temperatures $\\gtrsim 1000$ K) atmospheres. Moreover, the hydrocarbons will be condensed out to form aerosols only when the temperature-pressure profiles of the species intersect with the saturation profiles--a case almost certainly not realized in the hot CEGPs ...
The effect of atmospheric pressure on tracking resistance of organic insulating materials were investigated in the range of 500 to 1007 hPa. The tracking resistance for Polycarbonate (PC), Modified Polyphenylene Oxide (M-PPO) and Paper Base Phenolic Resin Laminate (PL) increase with the decrease in atmospheric pressure. The scintillating discharges on these samples surface lead to the ignition. The tracking failure on these results from the ignition on the surface. For Polybutylene Terephthalate (PBT) and Polyethylene Terephthalate (PET), the tracking resistance decrease with the decrease in atmospheric pressure. The discharges observed on the these surface are the glow-like. The discharge area spreads on the surface between the electrodes at the lower pressure. The failure on this group results from the carbonization by the discharges on the surface. However, the tracking resistance for Unsaturated Polyester Resins (UP) ...
Microwave dielectric properties and far-infrared reflectivity spectra of (Zr{sub 0.8}Sn{sub 0.2})TiO{sub 4} ceramics with 1.0mol.% Sb{sub 2}O{sub 5} or WO{sub 3} were investigated in the various sintering atmospheres. The Q{center_dot}f value of the specimens sintered in oxygen atmosphere was enhanced due to the decrease of lattice anharmonic interaction resulting from the decrease of oxygen vacancies, whereas the dielectric constants remained constant regardless of sintering atmosphere. The effects of the sintering atmosphere on the changes of ionic and electronic polarization and the intrinsic microwave losses of the specimens were investigated by using the infrared reflectivity spectra from 50 to 4000cm{sup -1}, which were evaluated using Kramers-Kronig analysis and classical oscillator model. The relative tendency of microwave dielectric properties of the specimens calculated from the reflectivity ...
The fluxes of atmospheric electrons, positrons, positive and negative muons and negative pions have been determined using the NMSU Wizard-MASS2 balloons-borne instrument. The instrument was launched from Fort Sumner, New Mexico, (geomagnetic cut-off about 4.5 GV/c) on september 23, 1991. The flight lasted 9.8 hours and remained above 100.000 ft. Muons and negative pions were observed and their momenta were determined. Since these particles are not a part of the primary component, the measurement of their fluxes provides information regarding production and propagation of secondary particles in the atmosphere. Similarly, observations of electrons and positrons well below the geomagnetic cut-off provides insight into electromagnetic cascade processes in the upper atmosphere. In addition, the determination of the energy spectra of rare particles such as positrons can be used for background subtraction for cosmic ray ...
For Stage II of the European Dioxin Project the following objectives were set: - Amendment of existing emission data collected for most relevant emission sources in order to reduce uncertainties of emission estimates. Collecting first emission data from countries not yet performing dioxin emission measurement programs. Extending the inventory of dioxin emissions to ambient air produced in Stage I by a complementary study on emissions to land and water. Extending the regional scope of data collection to countries in Central Europe. The report of Stage II of the European Dioxin Project is presented in 3 Volumes. Volume 1 contains an overview on the background and approach of different activities carried out and on the results obtained. These results are put into a broader view regarding the dioxin reduction measures in Europe leading to ...
An improved method of counting acoustic emission (AE) events from water-stressed stems of cedar (Thuja occidentalis L.) is presented. Amplified AEs are analyzed on a real time basis...Full Text Available
Measurements are reported of ultrasonic acoustic emissions (AEs) measured from sapwood samples of Thuja occidentalis L. and Tsuga canadensis (L.) Carr. during air dehydration....Full Text Available
An ASTER (advanced spaceborne thermal emission and reflection radiometer) is one of the image sensors. It is to be installed in an earth survey polar orbit platform satellite, EOS-AM1, which is to be launched in 1998, and it is going to start its operation. Data observed by the thermal infrared remote sensing of ASTER include the spectral emissivity, and the spectral emission reflectivity which is expressed by the function of temperature. It is required to overcome technical problems how to extract the spectral emissivity from the observed data. The spectral emissivity extracted from the remote sensing data by the MMD method, measured for samples collected in Cuprite area, Nevada, and/or measured at sampled points were compared to each other and discussed. The hemisphere spectral reflectivity, which is indirect spectral emissivity, agreed well with the direct ...
In order to investigate the effects ethanol-diesel blends and altitude on the performance and emissions of diesel engine, the comparative experiments were carried out on the bench of turbo-charged diesel...Full Text Available
A historical prospective mortality study was conducted on a cohort of 34 156 male members of a heavy construction equipment operators union with potential exposure to diesel exhaust emissions. This...Full Text Available
The Natural Gas Vehicle Challenge `92, organized by Argonne National Laboratory and sponsored by the US Department of Energy, the Energy, Mines, and Resources - Canada, the Society of Automotive Engineers, and many others, resulted in 20 varied approaches to the conversion of a gasoline-fueled, spark-ignited, internal combustion engine to dedicated natural gas use. Starting with a GMC Sierra 2500 pickup truck, donated by General Motors, teams of college and university student engineers strived to optimize Chevrolet V-8 engines operating on natural gas for improved emissions, fuel economy, performance, and advanced design features. This paper focuses on the results of the emission event, and compares engine mechanical configurations, engine management systems, catalyst configurations and locations, and approaches to fuel control and the relationship of these parameters to engine-out and tailpipe emissions of regulated ...
In VHTGR (Very High Temperature Gas-cooled Reactor), the radiation plays an important role in heat transfer through the cavity in RCCS (Reactor Cavity Cooling System). We performed the series of experiments to measure the emissivity using the infrared thermometer with wavelength range of 8#approx#14 #mu#m. As the first step, the transmittance of Zinc Selenide (ZnSe) window was measured to estimate the emissivity that can compensate the attenuation effect of window. The kind of gas with various concentrations in the cavity will be released during postulated accidents to the coolant type, so it is essential to estimate the effects of gas on the measurement of emissivity. In this manner we measured the emissivity with the air, the helium and the steam inside chamber. The results represent that the concentration of the air and the helium do not affect the emissivity significantly while ...
Spontaneous radiation by an atom in a Rydberg state is inhibited by use of parallel conducting planes to eliminate the vacuum modes at the transition frequency. Spontaneous radiation emission is observed to turn off abruptly at the cutoff frequency of the waveguidelike structure, and the natural lifetime is measured to increase by a factor of at least 20.
Simulations with a regional chemical transport model show that anthropogenic emissions of volatile organic compounds and nitrogen oxides (NOx = NO + NO2) lead to a dramatic diurnal...Full Text Available
Emissions of sulphur and nitrogen oxides are continuing to fall in Europe but rise in Asia, according to calculations based on individual countries' predictions of economic development. The upward trend is slower than in previous predictions. 2 refs., 2 figs., 2 tabs.
Proper assessment of the hypothesis which correlates polycyclic aromatic hydrocarbons (PAHs) with the unidentified infrared emission bands requires additional experimental laboratory data. In order to address this need, thermal infrared emission studies were performed on a subset of PAHs suggested to be of astrophysical importance. It was proposed that infrared emission from interstellar PAHs occurs following absorption of an ultraviolet photon. Since energy transfer to the ground electronic state can be rapid for a species in which intersystem crossing is negligible, the emission spectrum may be viewed as resulting from an equilibrium vibrational temperature (Leger and d'Hendecourt, 1987). This has been the basis for using infrared absorption spectra to calculate the corresponding emission spectra at various temperatures. These calculations were made using room temperature infrared ...
Air pollution abatement measures are not an end in themselves, and undesirable side effects should be taken into account. The proposed emission index takes into account the total emissions caused by a technical project as well as the effects of the individual pollutants.
The pharmacokinetic concepts of bioavailability and biotransformation are introduced into the assessment of public health risk from experimental data concerning the emissions of potentially mutagenic...Full Text Available
This study was undertaken to collect emissions performance data for Canadian and comparable American refineries. The objective was to examine parameters that affect refinery air emissions performance and develop methods or correlations to normalize emissions performance. Another objective was to correlate and compare the performance of Canadian refineries to comparable American refineries. For the purpose of this study, benchmarking involved the determination of levels of emission performance that are being achieved for generic groups of facilities. A total of 20 facilities were included in the benchmarking analysis, and 74 American refinery emission correlations were developed. The recommended benchmarks, and the application of those correlations for comparison between Canadian and American refinery performance, were discussed. The benchmarks were: sulfur oxides, nitrogen oxides, ...
A survey of various mechanisms for particle emission in hydrodynamics is presented. First, in the case of sudden freeze out, the problem of negative contributions in the Cooper-Frye formula and ways out are presented. Then the separate chemical and thermal freeze out scenario is described and the necessity of its inclusion in a hydrodynamical code is discussed. Finally, we show how to formulate continuous particle emission in hydrodynamics and discuss extensively its consistency with data. We point out in various cases that the interpretation of data is quite influenced by the choice of the particle emission mechanism.
The production of and emission factors for the air-polluting matters sulfur dioxide, nitrogen oxides, carbon monoxide, hydrocarbons (esp. benz(a)pyrene), aldehyde and soot with regard to natural gas, excluding process furnaces, are dealt with. The comparison with other fuels indicates that only as to nitrogen oxides and carbon monoxide are emission factors equal in order of magnitude. As a summary measure of all air-polluting matters the emission index as proposed already in 1972 is applied. It shows emissions with single-room furnaces for heating oil EL to be six times as high as with natural gas; with black-coal briquettes the factor is at least 33, with wood chimneys about 200.
The Federal Republic of German (FRG) had uniquely strict emission legislation for particulates SO_2 and NO_X from fossil-fired power plants. The 13th Regulation to the Federal Emission Control Act required that by 1 July 1988 all large furnaces fired with solid or liquid fuels that would not be decommissioned by 1993 be retrofitted with SO_2 control technology. The emission limits are 15 per cent of the sulphur introduced with the fuel (400 mg/m"3 maximum) at thermal capacities above 300 MW. 1 ref., 9 figs, 15 bibliographies.
The emission of light charged particles from heavy fragments of uranium fission induced by 153-MeV protons is studied. The probability of their emission is 2.7 x 10{sup - 2} per fission event. It is found that these particles affect the distribution of angles of fragment divergence and the angular distribution of heavy fragments with respect to the primary-proton beam. Experimental results suggest that the preequilibrium emission of particles is correlated with fission. Two mechanisms of interaction between 153-MeV protons and uranium nuclei are considered. 13 refs., 10 figs., 1 tab.
In this paper, the control scheme of a liquefied petroleum gas (LPG)-diesel dual-fuel engine with electronic control is illustrated, the external characteristics and load characteristics of the LPG-diesel dual-fuel engine and the diesel engine are compared and analysed, and the results of automobile road tests are also given. The experimental results show that, compared with diesel, the output performance of dual fuel is not reduced, while smoke emission of dual fuel is significantly reduced, NO{sub x} emission of dual fuel is hardly changed, but HC emission and CO emission of dual fuel are increased and fuel consumption of dual fuel is reduced. (Author)
One requirement of a thermophotovoltaic (TPV) radiator is to efficiently emit photons at high temperatures to TPV cells for conversion to electric power. Because many candidate radiator materials with adequate structural properties display low emissivity, coatings or other surface modifications are required for enhancement of emissivity. Six plasma sprayed coatings and one textured surface demonstrated adequate thermal stability and emittance values of 0.8 or greater. Promising attributes of modified surfaces are identified.
This article, with 25 references, reviews the soil sources and sinks of carbon dioxide, methane, and nitrous oxide. The mitigation of greenhouse gas releases is discussed covering reduction of carbon dioxide emissions by a change in land use, the use of alternative waste disposal methods such as composting or recycling to reduce methane emissions, and management of nitrogen fertiliser applications to reduce nitrous oxide emissions. (Author)
Designing efficient policies for curbing greenhouse gas (GHG) emissions is of particular interest for todays policy makers, in view of global climate change threats. This paper analyses the options Switzerland has for curbing its CO{sub 2} emissions. Using MARKAL and MARKAL-NACRO models, it investigates, in particular effects of national and international carbon taxes. (author) 3 figs., 1 tab., 6 refs.
The report summarizes the results of a dioxin/furan emissions test of a secondary copper recovery cupola furnace equipped with an afterburner for hydrocarbon emissions control and two baghouses for particulate emissions control. The cupola furnace is used...
Greenhouse gas emissions from international maritime transport are exempt from liabilities under the Kyoto Protocol. Research into quantifying these emissions is ongoing, and influences policy proposals to reduce emissions. This paper presents a cargo-based analysis of fuel consumption and greenhouse gas emissions from New Zealand's international maritime transport of goods. Maritime transport moves 99.5% (by mass) of New Zealand's internationally traded products. It is estimated that 73% of visiting vessels' activity can be directly attributed to the movement of goods in and out of New Zealand. A cargo-based methodology was used to estimate that the international maritime transport of New Zealand's imports and exports consumed 2.5 million tonnes (Mt; 2.6 billion litres) of fuel during the year 2007, which generated 7.7 Mt of carbon dioxide (CO_2) emissions. Double-counting of ...
The method of life-cycle assessment (LCA) has been applied to cars with different power trains. As an example, the results for greenhouse gas (GHG) emissions are presented. They show possibilities and limits for the reduction of these emissions in the transportation sector by means of advanced technology. (author) 2 figs., 4 refs.
The method for calculating emissions to air has been revised, which has led to adjustments. Because of this, emissions in 1999 cannot yet be compared with previous years. Emissions in 1990 - 1998 are being recalculated now using the new method and are expected to be ready during 2001. Emissions to air of carbon dioxide (CO_2) in Sweden was 56.58 million tonnes in 1999, not including emissions from biofuels and international bunkers. The major sources of CO_2 emissions are the combustion of fossil fuels and the use of fuels for mobile sources. Total emissions to air of sulphur dioxide (SO_2) and nitrogen oxides (NO_x, counted as NO_2) in Sweden was 66 000 and 263 000 tonnes respectively in 1999. International bunkers are not included. The major source of SO_2 emissions is combustion of fossil fuels. Road traffic is the ...
The Baldwin Effect, a negative correlation between emission-line equivalent width and luminosity in active galactic nuclei, is still of interest as a diagnostic of accretion physics nearly thirty years after its discovery. This review examines recent developments in the study of correlations between line and continuum emission in AGNs, as measured both in ensembles and in individual sources.
Full text: This presentation will review the progress achieved so far by the Irish national regulatory agency, the Radiological Protection Institut e of Ireland (R.P.I.I.) in the investigation of work activities where the presence of natural radiation sources (NORM) could lead to a significant increase in exposure to workers or members of the public which cannot be disregarded from the radiation protection point of view. Since the coming into force in Ma y 2000 of the Radiological Protection Act, 1991 (Ionising Radiation) Order, 2000 (S.I. No. 125 of 2000) which implements the Eu B.S.S. Directive 96/29/EURATOM, four major NORM industries currently active in Ireland have been investigated. According to the literature, they are all considered liable to involve work practices resulting in exposure to NORM. They include: the gas extraction and production industry, the peat- and coal-firing power generation industry and the bauxite/alumina refining industry. For the gas industry, monitoring ...
Radon concentration measurements in atmosphere were taken in years from 1997 to 1999 in Milan and at pre-alpine sites located north of Lombardy. In this paper the results of measuring campaigns and a comparison of radon levels observed in the hilly area north of the town and on the pre-Alps are reported. The general criteria of the measurements and the interpretative models of radon concentration are presented. The Lake Maggiore area shows evidence of a great nocturnal stability and frequent formation of Nocturnal Stable Layer. The peculiar findings in the high altitude stations confirm the use of radon as an indicator of atmospheric dispersion of pollutants in an area with complex orography. The afternoon minimum values are concordant for the different stations: this implies a remixing in afternoon hours over the whole area investigated.
There are clearly identified scientific requirements for continuous profiling of atmospheric water vapor at the Department of Energy, Atmospheric Radiation Measurement program, Southern Great Plains CART (Cloud and Radiation Testbed) site in northern Oklahoma. Research conducted at several laboratories has demonstrated the suitability of Raman lidar for providing measurements that are an excellent match to those requirements. We have developed and installed a ruggedized Raman lidar system that resides permanently at the CART site, and that is computer automated to eliminate the requirements for operator interaction. In addition to the design goal of profiling water vapor through most of the troposphere during nighttime and through the boundary layer during daytime, the lidar provides quantitative characterizations of aerosols and clouds, including depolarization measurements for particle phase studies.
This report covers the second year of the 28 month grant current grant to Clarkson University to study the chemical and physical behavior of the polonium 218 atom immediately following its formation by the alpha decay of radon. Because small changes in size for activity result in large changes in the delivered dose per unit exposure, this behavior must be understood if the exposure to radon progeny and it dose to the cells in the respiratory tract are to be fully assessed. Two areas of radon progeny behavior are being pursued; laboratory studies under controlled conditions to better understand the fundamental physical and chemical process that affect the progeny`s atmospheric behavior and studies in actual indoor environments to develop a better assessment of the exposure of the occupants of that space to the size and concentration of the indoor radioactive aerosol. This report describes the progress toward achieving these objectives.
This report covers the second year of the 28 month grant current grant to Clarkson University to study the chemical and physical behavior of the polonium 218 atom immediately following its formation by the alpha decay of radon. Because small changes in size for activity result in large changes in the delivered dose per unit exposure, this behavior must be understood if the exposure to radon progeny and it dose to the cells in the respiratory tract are to be fully assessed. Two areas of radon progeny behavior are being pursued; laboratory studies under controlled conditions to better understand the fundamental physical and chemical process that affect the progeny's atmospheric behavior and studies in actual indoor environments to develop a better assessment of the exposure of the occupants of that space to the size and concentration of the indoor radioactive aerosol. This report describes the progress toward achieving these objectives.
We have demonstrated that, with simple pH adjustment, volatile drugs such as methamphetamine, amphetamine, 3,4-methylenedioxymethamphetamine (MDMA), ketamine, and valproic acid could be analyzed rapidly from raw biofluid samples (e.g. urine and serum) without dilution, or extraction, using atmospheric pressure ionization. The ion source was a variant type of atmospheric pressure chemical ionization (APCI) that used a dielectric barrier discharge (DBD) to generate the metastable helium gas and reagent ions. The sample solution was loaded in a disposable glass pipette, and the volatile compounds were purged by nitrogen gas to be reacted with the metastable helium gas. The electrodes of the DBD were arranged in such a way that the generated glow discharge was confined within the discharge tub...
As lidar technology is able to provide fast data collection at a resolution of meters in an atmospheric volume, it is imperative to promote a modeling counterpart of the lidar capability. This paper describes an integrated capability based on data from a scanning water vapor lidar and a high-resolution hydrodynamic model (HIGRAD) equipped with a visualization routine (VIEWER) that simulates the lidar scanning. The purpose is to better understand the spatial and temporal representativeness of the lidar measurements and, in turn, to extend their utility in studying turbulence fields in the atmospheric boundary layer. Raman lidar water vapor data collected over the Pacific warm pool and the simulations with the HIGRAD code are used for identifying the underlying physics and potential aliasing effects of spatially resolved lidar measurements. This capability also helps improve the trade-off between spatial-temporal resolution and coverage of the ...
Understanding the processes responsible for coastal change is important for managing our coastal resources, both natural and economic. The current scientific understanding of coastal sediment transport and geology suggests that examining coastal processes at regional scales can lead to significant insight into how the coastal zone evolves. To better identify the significant processes affecting our coastlines and how those processes create coastal change we developed a Coupled Ocean-Atmosphere-Wave-Sediment Transport (COAWST) Modeling System, which is comprised of the Model Coupling Toolkit to exchange data fields between the ocean model ROMS, the atmosphere model WRF, the wave model SWAN, and the sediment capabilities of the Community Sediment Transport Model. This formulation builds upon ...
This report is a compilation of the Chalk Point surface weather and ambient atmospheric profile data for the second intensive test period, June 14-24, 1976. The atmospheric profiles were made using rawinsonde instrumentation. The compilation includes the 0700 EST daily weather chart, hourly surface observations from Chalk Point, Patuxent River Naval Test Center, MD and Andrews Air Force Base, MD. Temperature, relative humidity, dew point, wind speed and wind direction are presented in graphical profiles. All other data are presented in tabular form.
We propose a method of plasma production by capacity-coupled multidischarge (CCMD) at atmospheric pressure. The discharge gaps in the CCMD consist of a common electrode and a number of compact electrodes (CCE) which are directly coupled with small capacitors for quenching the discharge. A simple CCE structure is provided by a cylindrical capacitor, the inner conductor of which is used as a gap electrode. A short pulse discharge is observed to appear homogeneously at each CCE. A charge transfer for the single-pulsed discharge is 10-100 times as large as that of the conventional dielectric barrier discharge. A high efficiency of ozone production has been confirmed in the CCMD using O_2 gas. A device configuration of the CCMD is quite flexible with respect to its geometrical shape and size. The CCMD could be used to produce plasmas for various kinds of industrial applications at atmospheric pressure.
The Lawrence Livermore National Laboratory has developed a mobile field laboratory for remote measurement of atmospheric processes and observables that are important in global climate change, dispersal of hazardous materials, and atmospheric pollution. Specific observables of interest are water vapor, trace gases, aerosol size and density, wind, and temperature. The goal is to study atmospheric processes continuously for extended periods in remote field locations. This laboratory has just reached field ready status with sensors for aerosol and trace gas measurement based on established techniques. A development program is underway to enhance the sensor suite with several new techniques and instruments that are expected to significantly extend the state of the art in remote trace gas analysis. The new sensors will be incorporated into the lab during the next two years.
The method is related to hydrodynamic methods for studying wells and may be used in the prospecting and mapping of gas and gas condensate deposits and formations. The method consits of drilling exploratory wells and measurement of the physical parameters of the stratum liquid. The piezometric levels are periodically determined simultaneously in all the observation wells during a change in the atmospheric pressure, and the presence of a remoteness of the gas deposit from the well is judged from the size of the increments in the piezometric levels intime. The determinations of the piezometric levels in the wells are conducted during an abrupt change in atmospheric pressure, for instance, during the replacement of a cyclone by an anticyclone or the reverse. The atmospheric pressure is measured by a barograph, while the piezometric levels are measured by high precision level meters or pressure gauges of low pressure. The method ...
Radon concentration measurements in atmosphere were taken in years from 1997 to 1999 in Milan and at pre-alpine sites located north of Lombardy. In this paper the results of measuring campaigns and a comparison of radon levels observed in the hilly area north of the town and on the pre-Alps are reported. The general criteria of the measurements and the interpretative models of radon concentration are presented. The Lake Maggiore area shows evidence of a great nocturnal stability and frequent formation of Nocturnal Stable Layer. The peculiar findings in the high altitude stations confirm the use of radon as an indicator of atmospheric dispersion of pollutants in an area with complex orography. The afternoon minimum values are concordant for the different stations: this implies a remixing in afternoon hours over the whole area investigated.
This patent describes a low emission duel fuel engine system. It comprises: a dual fuel engine having a combustion chamber; a fuel oil supply connected to the engine; a fuel gas supply connected to the engine; and means connected between the fuel oil supply and the engine for injecting fuel oil into the engine. The means connected between the engine and fuel oil supply limiting the injection of fuel oil to the combustion chamber to pilot ignition quantities only, wherein the limiting means includes means for limiting the injection of fuel oil such that the exhaust emission of NO{sub x} is at an emission rate of less than 1 GM/PH-HR, whereby the exhaust emission performance of the dual fuel engine is enhanced.
The formaldehyde surface emission monitor (FSEM) has been developed for passive non-destructive measurement of formaldehyde (CH/sub 2/O) emission rates from CH/sub 2/O resin-containing materials. It is envisaged as a potential quality control and in-situ monitoring technique. For quality control applications to pressed-wood products, strong correlations between the results of the FSEM and environmentally controlled (small scale) chamber tests were observed. The FSEM is used to measure the cumulative CH/sub 2/O emission from a finite area of pressed-wood product during a fixed test period. The final result is reported as an average CH/sub 2/O emission rate (mg CH/sub 2/O/m/sup 2/h).
Investigations were conducted on the range of emission rates of NO, NO[sub 2], CO and hydrocarbons, and the thermal efficiencies produced by each burner on three production cookers, supplied by different Australian manufacturers. It was found that the emissions and efficiencies were markedly affected by (1) the thermal input, both with and without a load on the burner, and (2) the load-height to flame-length ratio, with a load on the burner. The effect of hydrocarbon leakage into the secondary/dilution air was investigated, to explain the observed correlation of hydrocarbon emission rate with dilution air flow. The hydrocarbons were found to arise from two sources: -leakage from the stabilisation ports at the base of the burner, which was found to be significant at the higher thermal input; -incomplete combustion of the fuel in the premix, which was the dominant source of hydrocarbons emissions at the ...
This report documents radionuclide air emission from the Hanford Site in 1997, and the resulting effective dose equivalent to the maximally exposed member of the public, referred to as the MEI. The report has been prepared in accordance with reporting requirements in the Code of Federal Regulations, Title 40, Protection of the Environment, Part 61, National Emissions Standards for Hazardous Air Pollutants, Subpart H, National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities. This report has also been prepared in accordance with the reporting requirements of the Washington Administrative Code Chapter 246-247, Radiation Protection-Air Emissions. The effective dose equivalent to the MEI from the Hanford Site`s 1997 point source emissions was 1.2 E-03 mrem (1.2 E-05 mSv), which is well below the 40 CFR 61 ...
Using a sample of 30,000 quasars from SDSS-DR7, we explore the range of properties exhibited by high-ionization, broad emission lines, such as CIV 1549. Specifically we investigate the anti-correlation between L_UV and emission line EQW (the Baldwin Effect) and the "blueshifting" of high-ionization emission lines. The blueshift of the CIV emission line is nearly ubiquitous, with a mean shift of 810 km/s for radio-quiet (RQ) quasars and 360 km/s for radio-loud (RL) quasars, and the Baldwin Effect is present in both RQ and RL samples. Composite spectra are constructed as a function of CIV emission line properties in attempt to reveal empirical relationships between different line species and the SED. Within a two-component disk+wind model of the broad emission line region (BELR), where the wind filters the continuum seen by the disk component, we find that RL ...
Activities of the Referenzlaboratorium Reinhaltung der Luft at Magdeburg as well as existing air pollution standards in the German Democratic Republic are reviewed. The laboratroy coordinates research and standardization in the field of industrial air pollution for the Ministry of Health. The standards provide orientation for emission control by state district health inspectorates. Emission limits (in g/m/sup 3/) which are international standards for 15 selected industries are listed. Emission limits (in g/m/sup 3/) of GDR standards, issued between 1971 and 1984 are also provided. They concern emission of brown coal dust from coal preparation plants, dust and chemical compound emission from metallurgical plants, dust emission from plants of the limestone and cement industry as well as from cupola furnace plants, boiler plants, plants of the wood industry and ...
Magnetically driven non-stationary acceleration of jets in active galactic nuclei results in the leading parts of the flow being accelerated to much higher Lorentz factors than in the case of steady-state acceleration with the same parameters. The higher Doppler-boosted parts of the flow may dominate the high-energy emission of blazar jets. We suggest that highly variable GeV and TeV emission in blazars is produced by the faster moving leading edges of highly magnetized non-stationary ejection blobs, while the radio data trace the slower-moving bulk flow. Thus, the radio and gamma-ray emission regions have different, but correlated, Doppler factors. High-energy emission is generated, typically within the optically thick core, in the outer parts of the broad-line emission region, avoiding the radiative drag on the faster parts of the flow. The radio emission ...
This guide explained the requirements for Off-Road Compression Ignition Engine Emission Regulations established under the Canadian Environmental Protection Act. The regulations are enforced by Environment Canada, which authorizes and monitors the use of the national emissions mark. The regulations prescribe standards for off-road engines that operate as reciprocating, internal combustion engines, other than those that operate under characteristics similar to the Otto combustion cycle and that use a spark plug or other sparking device. The regulations apply to engines that are typically diesel-fuelled and found in construction, mining, farming and forestry machines such as tractors, excavators and log skidders. Four different types of persons are potentially affected by the regulations: Canadian engine manufacturers; distributors of Canadian engines or machines containing Canadian engines; importers of engines or machines for the purpose of ...
This guide explained the requirements for Off-Road Compression Ignition Engine Emission Regulations established under the Canadian Environmental Protection Act. The regulations are enforced by Environment Canada, which authorizes and monitors the use of the national emissions mark. The regulations prescribe standards for off-road engines that operate as reciprocating, internal combustion engines, other than those that operate under characteristics similar to the Otto combustion cycle and that use a spark plug or other sparking device. The regulations apply to engines that are typically diesel-fuelled and found in construction, mining, farming and forestry machines such as tractors, excavators and log skidders. Four different types of persons are potentially affected by the regulations: Canadian engine manufacturers; distributors of Canadian engines or machines containing Canadian engines; importers of engines or machines for the purpose of ...
This paper describes the development and a detailed analysis carried out on the luminescence characteristics of Pr"3"+ doped ZrF_4-BaF_2-LaF_3-YF_3-AlF_3-NaF glasses. In the present work our objectives are to elucidate the possible mechanisms that are responsible for NIR to red upconversion process and yellow to blue upconversion emission in terms of energy level schemes from the praseodymium containing fibre optical glass composition. We have studied their different physical and optical properties. Besides our investigation on the upconversion emission of these glasses, normal fluorescence studies have also been undertaken in explaining the mechanisms in demonstrating bright red and blue emissions upon excitations at visible and UV wavelengths. Besides these measurements works, a bright blue colour emission was observed under an UV source (202 nm) and upconverted prominent red ...
Measurements of ion-induced electron emission have been performed with helium and argon ions with energies between 300 and 900 eV on W, W with 10% Ti, Al, Al with 1% Cu, Al with 1% Si, Si, and Be. This article describes many of the important surface characteristics that influence the ion-induced electron emission. For low-energy ions, the substrate material was found to be less important as the velocity of the incident ion decreased. In the case of incident Ar"+ the substrate material had a negligible effect on the emission for this energy range. The presence of an adsorbed layer enhanced emission in all cases. Heating the substrates resulted in oxidation of the surfaces and a subsequent increase in emission. The electron emission from aluminum samples with smaller grain sizes was higher than samples of identical composition with larger grains. This effect is ...
The increasing diffusion of small-scale energy systems within the distributed generation (DG) paradigm is raising the need for studying the environmental impact due to the different DG solutions in order to assess their sustainability. Addressing the environmental impact calls for building specific models for studying both local and global emissions. In this framework, the adoption of natural gas-fueled DG cogeneration technologies may provide, as a consequence of cogeneration enhanced overall energy efficiency and of natural gas relatively low carbon content, a significant reduction of global impact in terms of CO2 emissions with respect to the separate production of electricity and heat. However, a comprehensive evaluation of the DG alternatives should take into account as well the impact due to the presence of plants spread over the territory that could increase the local pollution, in particular due to CO and NOx, and thus could worsen the ...
This study tried to reduce NO{sub x} and particulate emissions simultaneously in a high speed direct-injection diesel engine. Fuel-rich combustion was used to reduce NO{sub x} emission at initial combustion stage and high turbulence combustion was used to reduce particulate emission at diffusion combustion stage. Experiments were carried out to investigate the effects of high squish combustion chambers with small throat on combustion process and exhaust emissions. Results showed that in the high squish combustion chamber, both NO{sub x} and particulate emissions reduced with retarded injection timing. Endoscopic high speed photography was employed to analyze experimental results. In the original combustion chamber at the early combustion stage, the high luminosity flame tended to spread out of the cavity. Fuel-rich mixture burned slowly over the piston crown. In the high squish ...
For terrestrial animals and plants, a fundamental cost of living is water vapor lost to the atmosphere during exchange of metabolic gases. Here, by bringing together previously developed models for...Full Text Available
Trace gas molecules absorb specific wavelengths of incoming solar ... These data(with information collected from similar experiments carried on balloons, rockets, ... The ATMOS sensor instrumentis a state-of-the-art version of a 19th century ...
The pollutants from the exhausts of internal combustion engines cause a range of illnesses and are the main source of atmospheric contamination. This article explores the options for curbing pollution in the UK including catalytic converters, electric cars, and natural gas cars. It is likely that the onus will remain with the car manufacturers for developing solutions. (UK)
Postulated impacts of large energy releases were examined in the light of existing technical information. The magnitudes of direct atmospheric modifications were estimated, and the ecological and economic implications of the modifications were explored. Energy releases from energy centers (10 to 40 power plants at a single site) and individual power plant clusters (1 to 4 power plants) were considered. In the atmosphere the energy will exist initially as increased temperature (sensible heat), moisture (latent heat), and air motion (kinetic energy). Addition of energy could result in increased cloudiness and fog, and changed precipitation patterns. A framework for economic analysis of the impacts of the postulated atmospheric modifications was established on the basis of costs and benefits. Willingness-to-pay was selected as the appropriate measure for valuing each impact. The primary and secondary ...
This review covers research done at Lawrence Livermore National Laboratory under DOE contract. Areas of research are as follows: star evolution supernovae, and nucleosynthesis; stellar atmospheres and winds; galaxies and interstellar space; and high-energy astrophysics.
This review covers research done at Lawrence Livermore National Laboratory in the fields of astronomy and astrophysics. The research areas mentioned are as follows: star evolution, supernovae, and nucleosynthesis; stellar atmospheres and winds; galaxies and the interstellar medium; and high-energy astrophysics.
This article consists of a series of manufacturer's descriptions outlining specifications of underground monitoring equipment which range in complexity from gas sensitive personal badges to full mine monitoring systems. 8 figs.
The OH-initiated photo-oxidation of n-butane was used as a source of 1- and 2-butoxy radicals. Reactions producing ketones and other organic compounds are explained. Rates of photolysis were determined and are discussed.
4.82 wt% AIN and 2.98 wt% Y_2O_3 were added to Si_3N_4 as sintering agents in order to have #alpha#_Sialon composition of x=0.15 and monoclinic ZrO_2 between 0 to 10 wt% was admixed with Si_3N_4 based ceramics were fabricated by hot-pressing at 1,750 deg C for 90 min under 30 MPa in argon and nitrogen atmospheres effects of sintering atmospheres and addition of ZrO_2 on mechanical properties of Si_3N_4 based ceramics were investigated. As ZrO_2 content increased, the fraction of #alpha#-Sialon tended to decrease and the amount of cubic ZrO_2 increased because Y_2O_3 acted as the stabilizer of ZrO_2. The sintering atmospheres didn't affect on the sintering behavior and the product phases in hot-pressing of Si_3N_4. Bending strength increased when ZrO_2 content. ZrO_2 didn't contribute to the increase of fracture toughness because stabilized cubic ZrO_2 was produced by the added Y_2O_3. (Author).
One tiny marine plant makes life on Earth possible: phytoplankton. These microscopic photosynthetic drifters form the basis of the marine food web, they regulate carbon in the atmosphere, and are responsible for half of the photosynthesis that takes place on this planet.
The behaviour of bare aluminium is studied in atmospheric exposure at 11 natural testing stations with salinity levels ranging between 2.1 and 684 mg Cl''- m''-2 d''-1. In atmospheres of low or moderate aggressivity aluminium behaves as a passive material, though the insignificant corrosion that is produced is sufficient to spoil its appearance. In contrast, at salinity levels of 50 mg Cl''- m''-2 ''-1 or above, aluminium is susceptible to pitting corrosion even in the first year of atmospheric exposure, or in the second year at salinities of {<=} 10 mg Cl''- m''-2 d''-1. For comparative purposes, results are included for aluminium protected with an anodic film of 28 {mu}m thickness exposed at the same testing stations. A 28 {mu}m anodic film, correctly ...
A new process for the hydrogenation of coal in the presence of wide-cut coal tar was proposed; it involves cavitation treatment, mixing with catalytic additives, and heating the resulting mixture at an elevated pressure in an atmosphere of hydrogen. The yields of hydrocarbon fractions to 300?C and gas condensate were evaluated.
This study effort was required as a preliminary step prior to initiation of field measurements of atmospheric dispersion in coastal regions. The Nuclear Regulatory Commission (NRC) is in the process of planning an extensive field measurement program to generate data which will serve as improved data bases for licensing decisions, confirmation of regulations, standards, and guides, and for site characterizations. The study being reported here is an effort directed to obtaining as much information as is possible from existing studies that is relevant toward NRC's objectives. For this study, reports covering research and meteorological measurements conducted for industrial purposes, utility needs, military objectives, and academic studies were obtained and critically reviewed in light of NRC's current data needs. This report provides an interpretation of the extent of existing usable information, an indication of the potential for tailoring existing ...
This report presents a study on the use of computerised, continuous remote monitoring systems for fire and explosive atmosphere safety in underground coal mines. The effects of these systems on the safety level in mines are investigated, and the relationship between mine safety regulations and computerised, continuous, remote monitoring is analysed.
Measurement of local steam condensation rates of cocurrent stratified flow of steam and subcooled water was carried out at atmospheric pressure in a horizontal rectangular channel. The channel was constructed of stainless steel with pyrex glass windows, a...
In this college-level introductory text the authors outline the fundamental principles of meteorology. The text is divided into three sections: meteorology, regionalization of climate, and climate change. Numerous charts, graphs, and photographs are displayed with each subject. A glossary of terms is also provided at the end of the book.
In recent years the modelling of interannual climate variability has been studied, the atmospheric energy and water cycles, and climate simulations with the ECHAM3 model. In addition, the climate simulations of several models have been compared with special emphasis in the area of northern Europe
The techniques of thermogravimetry and derivative thermogravimetry (dTG) have been applied to a range of fuel oils and two 'fingerprinting' tests have been developed, one using an inert and the other an oxidizing atmosphere. These tests have been named evaporation profile and burning profile. 4 refs.
Additional results using a calorimetric technique for measuring the total hemispherical emittance of pipe surfaces from 400 to 600 K are described. Two different Pyrex pipe enclosures were used, one of 15 cm i.d. and the other of 30 cm i.d. An error analysis showed that the larger diameter Pyrex pipe should have a smaller error, but the difference was negligible for the 4.4-cm test pipe diameter used. Measurements on a short length of a previously-measured pipe agreed with earlier measurements, but only over the temperature range of the measurements. While the technique normally uses a vacuum to minimize nonradiative heat transfer, measurements were done succesfully with an argon atmosphere in a closed system. A nickel-plated pipe, measured first in a vacuum and then in an argon atmosphere, allowed calculation of an effective convective heat-transfer coefficient for use with test pipes of unknown emittances. Measurements done with an ...
Nov 18, 2010 ... Roughly speaking, the fidelity interval we quote is a "3 sigma" value. ... surface of the foremost quartz filter which is then chemically altered by ... ( CERES) scanner point accuracy using a coastline detection system", ...
A combined ozone and aerosol LIDAR was developed at the Institute of Physics of the Atmosphere at the DLR in Oberpfaffenhofen. It is an airborne version, that, based on the DIAL-principle, permits the recording of two-dimensional ozone profiles. This presentation will focus on the ozone-part; the aerosol subsection will be treated later.
Lycopersicon esculentum Mill. cv Vedettos and Lycopersicon chmielewskii Rick, LA 1028, were exposed to two CO2 concentrations (330 or 900 microliters per...Full Text Available
Over the last decade {\\it ab initio} modeling of material properties has become widespread in diverse fields of research. It has proved to be a powerful tool for predicting various properties of matter under extreme conditions. We apply modern computational chemistry and materials science methods, including density functional theory (DFT), to solve lingering problems in the modeling of the dense atmospheres of cool white dwarfs ($T_{\\rm eff}\\rm <7000 \\, K$). Our work on the revision and improvements of the absorption mechanisms in the hydrogen and helium dominated atmospheres resulted in a new set of atmosphere models. By inclusion of the Ly-$\\rm \\alpha$ red wing opacity we successfully fitted the entire spectral energy distributions of known cool DA stars. In the subsequent work we fitted the majority of the coolest stars with hydrogen-rich models. This finding challenges our understanding of the spectral ...
The atmosphere and the biosphere are inherently coupled to one another. Atmospheric surface state variables such as temperature, winds, water vapor, precipitation, and radiation control biophysical, biogeochemical, and ecological processes at the surface and subsurface. At the same time, surface fluxes of momentum, moisture, heat, and trace gases act as time-dependent boundary conditions providing feedback on atmospheric processes. To understand such phenomena, a coupled set of interactive models is required. Costs are still prohibitive for computing surface/subsurface fluxes directly for medium-resolution atmospheric general circulation models (AGCMs), but a technique has been developed for testing large-scale homogeneity and accessing surface parameterizations and models to reduce this computational cost and maintain accuracy. This modeling system potentially bridges the observed spatial and temporal ...
This article briefly comments on some stumbling-blocks to climatic change modelling accuracy - in assessments of the greenhouse effect, 25% (missing link) of atmospheric carbon dioxide absorption is still unaccounted for; 1989 World Bank estimates of the Amazon rain forest deforestation rate have since proven to be inaccurate; there are difficulties in assessing the movement of the earth's crust relative to variations in sea level; and different studies vary in results relative to global temperature measurement and trend assessment. The need for an assessment of the economic impacts of increased atmospheric concentrations of carbon dioxide is also pointed out.
In this paper uptake of tritium by market foods from tritiated water vapor in the air is investigated using cereals and beans purchased in Deep River, Canada. The concentrations of tissue free water tritium (TFWT) and organically bound tritium (OBT) range from 12 to 79% and from 10 to 38% respectively, of that estimated for atmospheric water vapor of the sampling month. The specific activity ratios of OBT to TFWT were constant for cereals, but variable for beans. The elevated OBT was shown to be the result of isotopic exchange of labile hydrogen by the fact that washing the foods with tritium free-water reduced their tritium contents to levels characteristic of their production sites.
The universe is full of exotic particles and waves. Some, such as neutrinos, pass through our neighbourhood unnoticed; others, such as extreme uv radiation, are absorbed by the upper atmosphere before they are able to do too much damage. For a long time, any systematic attempt to understand how our weather can be affected by extra-terrestrial sources other than solar visible and infrared radiation has been a lively and often controversial diversion from mainstream research. But recent scientific and technological breakthroughs and concern over long-term climate change have brought this subject into the spotlight.
Atmospheric pressure plasma enhanced chemical vapour deposition system is built. The electrical and optical characteristics of the APPECVD system is given. The system is used to deposit conductive polymers and nano composites onto glass and metal surfaces. The morphological, optical, chemical and electrical characteristics of deposited surfaces are investigated using SEM, AFM four probe deposition purposes. The photovoltaic applications of plasma deposited polymers and nonconsumption are compared with deposited with electrochemical methods show different results. The electrical, chemical and morphological structures of the samples will be given.
The validation of the forecast model for early emergency response to nuclear accidents is evaluated by trace tests in atmosphere in Daya Bay nuclear power site. The simulation experiment of the Daya Bay nuclear power site shows that the particle spreading image and the time-integrated concentration distribution given by plume concentration prediction model can perform the variation of pathway of the pollutant transport, as well as the effects of topography on transport and diffusion of pollutants. The simulation of five trace tests in field shows that 59.1% of ratios between predicted results and observed results are within the range of 10, and 41% of ratios are within the range of 5 approximately. (authors)
The invention concerns an integrated nuclear reactor comprising natural convection cooling of the supporting skirt on which rests the shield closing the reactor vessel. Cooling is achieved by making the air circulate from the bottom to the top around the skirt and removing this air by a stack. The air can be atmospheric air or air taken from the low parts of the reactor. In the latter case, the stack emerges near a metal roof releasing its heat to the atmosphere by radiation, the air then dropping to the low parts. Application to fast nuclear reactors.
The Meteorological Information System (MIS) comprising the meteorological instruments, the computers, and the software for data processing and recording, is part of the KfK safety and control system. In 1982 is was equipped with an independent data processing system. The report explains the arrangement and the operation of the sensors and thw two process computers. For selected meteorological situations the ability of the system is demonstrated, i.e., the presentation of the vertical profiles of wind, temperature and turbulence in the lower atmospheric boundary layer as well as the calculation and graphical representation of the transport and dispersion into the KfK environment of radioactive pollutants being released by the nuclear installations of the KfK into the atmosphere.
Studied are the mechanical properties of welded joints and heat affected zones of the Kh8N10T steel and OT4 and VT1-2 titanium alloys on welding in Ar+deltaF_6 and Ar+CCl_2F_2 mixtures contributed to a decrease of porosity. Tensile and impact tests of welded joints have revealed that additions of sulfur hexafluoride into argon causes a decrease of impact strength in titanium alloy when the tensile strength does not depend on the composition of a halogen-containing atmosphere. Freon (CCl_2F_2) additions decrease only slightly the impact strength of the investigated alloys.
Dimethyl methylphosphonate (DMMP), a chemical simulant of the nerve gas GB, was decontaminated with a nonthermal atmospheric pressure plasma. The decontamination efficiency was measured qualitatively by means of Fourier transform spectroscopy and quantitatively by means of gas chromatography. With helium gas only, 10g/m2 of DMMP on an aluminum surface was 99.9% decontaminated in 2min, furthermore, with the addition of 5% of oxygen gas, it was 99.99% decontaminated in 10min. Given the low input power (<100W) and temperature (<75degreeC), this plasma is eligible for nondestructive decontamination of almost all material surfaces.
We develop a new cavity with a mode similar to TE13 to produce microwave plasma, named APMPS II, which is able to produce a mass of air plasma with diameter of around 6 cm, equipped with about 3 kW input power under one atmosphere. The plasma seems to be homogeneous without significant filamentous discharge as observed by common camera device. We present the theory of this cavity, show the distribution of electric field of several planes inside the cavity and give some experimental results. (authors)
Atmospheric and ionospheric perturbations associated with the acoustic-gravity waves (AGW) with typical frequencies of a few hertz -millihertz are considered. These events may be caused by the influence from space and atmosphere as well as by oscillations of the Earth surface and other near-surface phenomena. The surface sources include long-period oscillations of the Earth's surface, earthquakes, explosions, thermal heating, seisches and tsunami waves. The wavelike phenomena manifest themself as travelling disturbances of air (in the atmosphere) and of electron density (in the ionosphere). Travelling ionospheric disturbances (TIDs) are well detected by radio physical methods. AGW generation by near-surface sources is modeled by the numerical solution of the equation of geophysical fluid dynamics for different sources in two-dimensional non-linear dissipative compressible atmosphere. The numerical ...
Climates at regional scale are strongly dependent on the interaction between atmosphere and its lower boundary, the oceans and the land surface mosaic. Land surfaces influence climate through their albedo, and the aerodynamic roughness, the processes of the biosphere and many soil hydrological properties; all these factors vary considerably geographically. Land surfaces receive a certain portion of the solar irradiance depending on the cloudiness, atmospheric transparency and surface albedo. Short-wave solar irradiance is the source of the heat energy exchange at the earth`s surface and also regulates many biological processes, e.g. photosynthesis. Methods for estimating solar irradiance, atmospheric transparency and surface albedo were reviewed during the course of this project. The solar energy at earth`s surface is consumed for heating the soil and the lower atmosphere. Where moisture is available, ...
Fully fluorinated compounds (perfluoro compounds) represent a class of chemicals which include many extremely inert species-inert to both chemical reaction and photodissociation. Well known examples include SF6 and the perfluorocarbons (PFCs) CF_4 and Teflon. SF_6 is used industrially in electrical switch gear and as an atmospheric tracer. CF_4 and C_2F_6 are released into the atmosphere as a by-product of aluminum manufacture. Several perfluoro compounds have been proposed as substitutes for the ozone-destroying Freons and halons; proposed substitutes include SF_6, c-C_4F_8, C_5F_1_2, and C_6F_1_4. These chemicals were chosen in part because they do not harm the stratospheric ozone layer and were therefore considered environmentally friendly. Recently, Ravishankara et al. reported that perfluoro compounds have significant global warming potential (GWP), contributing to the greenhouse effect due to strong infrared absorption. The perfluoro ...
A link is made in this paper between proposed low energy scenarios for different Western European countries and the amount of pollutants that may result from these scenarios. Air pollutant emissions are calculated for the ten countries for which low energy scenarios are available. These scenarios emphasize stringent energy efficiency, maximizing the use of renewable (other than nuclear) energy, and minimizing the use of fossil fuels. Under these low energy scenarios, the average per capita energy use (year 2030) in the ten countries is estimated as 97 GJ/person, which is a decrease of 38% relative to 1980. Using the energy consumption figures from the low energy scenarios, together with sector- and fuel-specific emission factors from Europe, the resulting emissions of SO_2 , NO_x , and CO_2 were computed. These estimates do not take into account any add-on pollution controls over and above what was in place in 1980, or ...
This paper deals with estimating aircraft landing and take-off (LTO) emissions (HC, CO, NO_x, SO_2) at 40 Turkish airports including the biggest airports, i.e. Ataturk International Airport (AIA) in Istanbul, Antalya Airport in Antalya and Esenboga Airport in Ankara in 2001. The calculation model is based on flight data recorded by the State Airports Authority. The flight data include the type and number of aircraft, number of passengers, amount of cargo etc., which depend on day-time and date. For the emission calculations the International Civil Aviation Organization (ICAO)-Engine emission data bank, which includes minimum and maximum values for both fuel flow rates and emissions factors, is used. By using first the minimum and then the maximum values from the data bank, two estimations of aircraft LTO emissions at Turkish airports are calculated: i.e. minimum and maximum ...
This Statistical Report presents results from the physical Swedish Environmental and Economic Accounts for the years 1993 and 1995 according to the classification NACE. The Environmental Economic Accounts constitute an integrated and comprehensive system for environmental and economic statistics. Environmental data are systematically presented together with economic data in a common framework. The system can be used for analyses of various relationships between economy and environment. Data on emissions to air of carbon dioxide, sulphur dioxide, nitrogen oxides, carbon monoxide, methane, nitrous oxide and ammonia are presented for 39 industries, government services and private consumption. The use of energy commodities in monetary and physical terms are also presented for the same sectors. Economic, energy and emission data are also presented in environmental and economic profiles and indicators. Environmental and economic profiles provide an ...
The optical properties of divalent europium activated Ca-#alpha#-SiAlON were investigated and the excitation and emission processes were discussed. The emission wavelength is influenced by the activator concentration of Eu more than the codopant concentration of Ca, in case of the same matrix composition of #alpha#-SiAlON. The red-shift of emission increases when the concentration of Eu increases. In addition, it was revealed that the red-shift of emission would be caused by the construction of the package of optical device. The correlated color temperature becomes low by the red-shift for the white light-emitting diode (LED) lamp using Ca-#alpha#-SiAlON:Eu phosphor when the phosphor powder concentration increases in the transparent resin which coats the primary light source of a blue LED die. The additional red-shift can be observed when the excessive amount of phosphor coating is intentionally poured ...
To aid in the study of lower hybrid current drive as a means of current profile control, the radial profile and velocity distribution of the fast current-carrying electrons and their time evolution must be known. As part of the recent effort to understand this fast electron transport, a diagnostic has been installed on PBX-M to measure the electron cyclotron emission from the fast electrons. An oblique horizontal view of upshifted cyclotron emission in the midplane can give radial as well as velocity space information about the fast electrons. Emission in X mode frequencies refracted by the right-hand cutoff is radially localized. The observed emission at a specific frequency comes only from the radial region r_t_u_r_n=#0. Emission measured by this new diagnostic has been found to be radially localized as predicted. It is also expected that localized moments of the distribution ...
This presentation gives the results of a research programme aimed at evaluating exhaust emissions from ships moving within confined coastal zones, as in Piraeus harbour. The level of various exhaust emissions were estimated on the basis of a mathematical model applied for each sea traffic element (ship). Hourly and daily records of all ships` movements in different parts of the harbour were compiled, covering extended periods of time and associated with different shipping operational characteristics (peaks, lows, etc). In order to correlate the exhaust emissions from shipping with the quality of the air in the area of interest, land-based measurements for the same pollutants were carried out in selected locations, near the port and in the greater Athens area. This enabled the investigation of time and spatial diffusion of exhaust emissions from shipping within the area of interest, taking into account ...
The report gives results of a project conducted to create a file containing comprehensive data on all electric utilities in the US. The National Acid Precipitation Assessment Program's (NAPAP's) emissions inventory activities focus on the estimation of emissions from pollutants that contribute to acid deposition. Electric utilities, which emit a large share of total acid deposition precursor emissions, are important for modeling analyses. Data reported by states to the National Emissions Data System (NEDS) for the 1985 NAPAP Emissions Inventory and data reported to the U.S. Department of Energy (DOE) on EIA Form 759, EIA Form 767, FERC Form 423, and the Integrated Data Base System (IDBS) were matched and combined. The resulting 1985 National Utility Reference File (NURF) contains detailed unit level data for nearly 10,000 electricity generating plants.
This report is an assessment of emission-control costs for municipal-waste combustors (MWCs). The details of the cost estimates, including their development, components, and cost premises, are addressed. A model-plant approach was used in the sizing and costing of the emission control systems. Due to differences in the feed-waste characteristics, combustion parameters, and emissions, separate cost estimates were required for mass burning (MB), modular (MOD), refuse-derived fuel (RDF), and fluid-bed combustion (FBC) type furnaces. Cost estimates were developed for control of particulate matter (PM) emissions only and for control of both acid gas and PM emissions from the MWC model plants. Controlled PM emission levels of 0.03, 0.02, and 0.01 gr/dscf, corrected to 12% CO/sub 2/, and 90 and 70% reductions of HC1 and SO2, respectively, were used to develop the ...
We present the results of a study on the 1.4 GHz kpc-scale radio emission in the complete flux density limited MOJAVE sample, comprising 135 radio-loud AGNs. While extended emission is detected in the majority of the sources, about 7% of the sources exhibit only radio core emission. Many BL Lacs exhibit extended radio power and kpc-scale morphology typical of powerful FRII jets, while a substantial number of quasars possess radio powers intermediate between FRIs and FRIIs. This poses challenges to the simple radio-loud unified scheme, which links BL Lacs to FRIs and quasars to FRIIs. We find a significant correlation between extended radio emission and pc-scale jet speeds: the more radio powerful sources possess faster jets. This indicates that the 1.4 GHz (or low frequency) radio emission is indeed related to jet kinetic power. Various properties such as extended radio power and ...
The exhaust emissions of a Diesel direct injection Perkins engine fueled with waste olive oil methyl ester were studied at several steady-state operating conditions. Emissions were characterized with neat biodiesel from used olive oil and conventional Diesel fuel. Results revealed that the use of biodiesel resulted in lower emissions of CO (up to 58.9%), CO{sub 2} (up to 8.6%, excepting a case which presented a 7.4% increase), NO (up to 37.5%), and SO{sub 2} (up to 57.7%), with increase in emissions of NO{sub 2} (up to 81%, excepting a case which presented a slight reduction). Biodiesel also presented a slight increase in brake-specific fuel consumption (lower than 8.5%) that may be tolerated due to the exhaust emission benefits. Combustion efficiency remained constant using either biodiesel or Diesel fuel. The proposed alternative for Diesel fuel could significantly decrease the ...
The document gives statistics on the pollutive emissions from Danish power plants during the period 1987-1996, the main pollutants being sulphur dioxide, nitrogen oxides and carbon dioxide. Data on efficiency levels relative to the production of electricity and heating and on the power plants` contribution to the total emission of CO{sub 2}, NO{sub x}, and SO{sub 2} from energy consumption in Denmark, are presented, and also as corrected for the net import of electricity. Other data on the emission of each of these chemicals by power plants are presented as factual, and corrected in accordance with the net import of electricity, and as factual per consumed and produced energy unit at the power plants. Short notes on related Danish legislation are found in addition to information on sources, methods and definitions used as a basis for the production of this document. Emission from power stations is ...
Historically, the bulk production of electricity has been achieved by burning fossil fuels, with unavoidable gaseous emissions, including large quantities of carbon dioxide: an average-sized modern coal-burning power station is responsible for more than 10 Mt of CO{sub 2} each year. This paper details typical emissions from present-day power stations and discusses the options for their reduction. Acknowledging that the cuts achieved in the past decade in the UK CO{sub 2} emissions have been achieved largely by fuel switching, the remaining possibilities offered by this method are discussed. Switching to less-polluting fossil fuels will achieve some measure of reduction, but the basic problem of CO{sub 2} emissions continues. Of the alternatives to fossil fuels, only nuclear power represents a zero-carbon large-scale energy source. Unfortunately, public concerns over safety and radioactive waste have ...
This paper investigates the relationship between economic growth and pollutant emissions for a small and open developing country, Tunisia, during the period 1961-2004. The investigation is made on the basis of the environmental Kuznets curve hypothesis, using time series data and cointegration analysis. Carbon dioxide (CO{sub 2}) and sulfur dioxide (SO{sub 2}) are used as the environmental indicators, and GDP as the economic indicator. Our results show that there is a long-run cointegrating relationship between the per capita emissions of two pollutants and the per capita GDP. An inverted U relationship between SO{sub 2} emissions and GDP has been found, with income turning point approximately equals to $1200 (constant 2000 prices) or to $3700 (in PPP, constant 2000 prices). However, a monotonically increasing relationship with GDP is found more appropriate for CO{sub 2} emissions. Furthermore, the ...
This paper investigates the relationship between economic growth and pollutant emissions for a small and open developing country, Tunisia, during the period 1961-2004. The investigation is made on the basis of the environmental Kuznets curve hypothesis, using time series data and cointegration analysis. Carbon dioxide (CO2) and sulfur dioxide (SO2) are used as the environmental indicators, and GDP as the economic indicator. Our results show that there is a long-run cointegrating relationship between the per capita emissions of two pollutants and the per capita GDP. An inverted U relationship between SO2 emissions and GDP has been found, with income turning point approximately equals to $1200 (constant 2000 prices) or to $3700 (in PPP, constant 2000 prices). However, a monotonically increasing relationship with GDP is found more appropriate for CO2 emissions. Furthermore, the causality results show that ...
This paper investigates the relationship between economic growth and pollutant emissions for a small and open developing country, Tunisia, during the period 1961-2004. The investigation is made on the basis of the environmental Kuznets curve hypothesis, using time series data and cointegration analysis. Carbon dioxide (CO{sub 2}) and sulfur dioxide (SO{sub 2}) are used as the environmental indicators, and GDP as the economic indicator. Our results show that there is a long-run cointegrating relationship between the per capita emissions of two pollutants and the per capita GDP. An inverted U relationship between SO{sub 2} emissions and GDP has been found, with income turning point approximately equals to 1200 (constant 2000 prices) or to 3700 (in PPP, constant 2000 prices). However, a monotonically increasing relationship with GDP is found more appropriate for CO{sub 2} emissions. Furthermore, the ...
We study the emission zone in a single-layer polymer light-emitting diode. The emission zone is found by studying the angular distribution of the electroluminescence. The emission is modeled by accounting for optical interference. We account for birefringence of the anode layer in our model. The active polymer was, however, found to be isotropic. The anode consists of a single-layer of the conducting polymer complex poly(3,4-ethylenedioxythiophene) and poly(styrene sulfonate) (PEDOT-PSS), with enhanced conductivity. As a cathode we use plain aluminum. By using only PEDOT-PSS we avoid having a thin metal layer or indium-tin-oxide as the anode in the path of the escaping light. The active material is a substituted polythiophene with excellent film forming properties. A comparison between the experimental and calculated angular distribution of light emission from a single-layered polymer light-emitting ...
A method was developed in which the potential of various measures is assessed systematically with a view to meeting the future EU5 emission specifications. Varied boundary conditions are taken into account, and their influence on the PM-NOx tradeoff was investigated. The relative cost is compared to an existing EU4 injection system. It was attempted to apply these measures to the impending US regulations (Tier2 Bin5) and to offer an outlook to EU6. The result shows that it is possible in principle for a car of the 1600 kg class to reduce NOx emissions while maintaining the EU4-PM emission standards.In the case of envisaged serial application subject to emission standards like US Tier 2 and EU6, much work is still required in terms of system robustness and life. In higher-class vehicles, the NOx reduction potential is lower, and it will be more difficult to make do without NOx treatment, especially with ...
Deregulation of the electric power industry in Alberta holds the prospect of providing greater choice for customers. One such option will be `green power` which is provided by renewable energy technologies. The energy produced would be without environmental impacts such as air emissions, water pollution, flooding, thermal emissions or waste by-products. Wind power, small scale hydro power, photovoltaics and biomass technologies have been termed as `green power`. The choices that customers make will not be focused on price alone. Market forces are emerging to demand reduction in emissions which will result in a market for `green energy` products and facilitate achieving goals for a sustainable future.
Divergence between aircraft engine emission regulations proposed by EPA and ICAO is discussed. Every engine, upon entering service, requires a certificate as to its compliance with emission standards. It is shown that despite the large variability in the measurements, it is possible to devise a certification procedure requiring the testing of one engine only. Statistical modeling of such a test at the 5% significance level is described. Values of the parameter standard deviation/mean recommended as certification standards for various pollutants are given. Features of a rational certification scheme to be formulated are outlined.
The problem of spectra formation in hydrodynamic approach to A+A collisions is discussed. It is analyzed in terms of the two different objects: distribution and emission functions. We show that though the process of particle liberation, described by the emission function, is, usually, continuous in time, the observable spectra can be also expressed by means of the Landau/Cooper-Frye prescription. We argue that such an approximate duality results from some symmetry properties that systems in A+A collisions reach to the end of hydrodynamic evolution and reduction of the collision rate at post hydrodynamic stage
An important aspect, which has to be considered in terms of municipal solid waste (MSW) management, is the stage of collection. The emissions generated from these systems can arrive to values that are of the same order of magnitude of emissions from combustion of waste in waste-to-energy plants. The present work faces the problem of transport, from intermediate station to the center of final combustion, placing attention to the emissions from scenarios that has been selected between real systems of management. This analysis can lead to highlight some important elements that can be useful to minimize the impacts.
The focus of this study is on the preparatory detection of uncertain net greenhouse gas (GHG) emission changes (also termed emission signals) under the Kyoto Protocol. The crucial question to be addressed is: How well do we need to know net emissions if we want to detect a specified emission signal after a given time? No restrictions exist as to what concerns the net emitter, which may be any GHG source or sink. Annex I countries are chosen as net emitters, simply for reasons of data availability and because of the excellent possibility of comparing net emitters (inter-country comparison). The countries' emissions - in an increasing number of cases even their uncertainties - are available permitting the application of preparatory signal detection techniques, which are suited to address the aforementioned question. We currently discuss four hierarchically-ordered detection ...
Hydrogen piston engines can be simultaneously optimized for improved thermal efficiency and for extremely low emissions. Using these engines in constant-speed, constant-load systems such as series hybrid-electric automobiles or home cogeneration systems can result in significantly improved energy efficiency. For the same electrical energy produced, the emissions from such engines can be comparable to those from natural gas-fired steam power plants. These hydrogen-fueled high-efficiency, low-emission (HELE) engines are a mechanical equivalent of hydrogen fuel cells. HELE engines could facilitate the transition to a hydrogen fuel cell economy using near-term technology.
A finite three-dimensional layer-by-layer photonic crystal with planar defects in a layer is shown to drastically modify the spontaneous emission rate of an embedded dipole. Finite-difference time-domain calculations with one quarter symmetric boundary condition and perfectly matched layer demonstrate the strong enhancement effects induced by the cavity resonance of defect modes and band-edge resonant modes. Simulation shows that the emission spectra are quite different when the position or polarization of the dipole is changed. Moreover, the extraction efficiency is calculated to observe the percentage of light leakage through a substrate.
Emission spectra obtained for three irradiated granular quartz samples under 1.43 eV excitation exhibited the 2.2 and 3.1 eV emission bands characteristic of feldspars. Excitation spectra of these same samples and several others show the 1.44 eV resonance typical of feldspars. This provides convincing evidence that the 2.2 and 3.1 eV infrared stimulated luminescence observed in these granular quartz samples arises from feldspar inclusions.
As part of a project to complete a comprehensive catalogue of astrophysically relevant emission lines in support of new-generation X-ray observatories using the Lawrence Livermore electron beam ion traps EBIT-I and EBIT-II, we studied emission lines of argon and sulfur in the soft X-ray and extreme ultraviolet region. Here we present observations of Ar IX through Ar XVI and S VII through S XIV between 20 and 75 {angstrom} to illustrate our work.
This paper presents an analysis of the performance of a selective emitter using small particles of rare earth compounds stable at high temperatures in a low emittance inert gas stream. An expression for the spectral emissive power excluding radiation scattering was derived to include the radiation in the emission band, produced by electronic transitions of the rare earth ion, and the continuum radiation outside the emission band produced by the rare earth host. Preliminary results suggest that a selective emitter based on suspended rare earth oxide particles will have high efficiency and merits further experimental investigation. {copyright} {ital 1996 American Institute of Physics.}
The possibilities of using both selective heavy ion induced X-ray emission and secondary ion mass spectroscopy (SIMS), for the identification of impurities present at low concentrations in cadmium telluride are examined. The relative concentrations of the impurities along CdTe crystals have been determined by exciting the X-ray emission of the elements in several slices with Ar and Kr ions and by comparing the relative characteristic X-ray emission yields. As a consequence of the quasimolecular inner shell ionization mechanism in heavy ion-atom collisions, Ar and Kr ions allow a strong excitation of the main impurities seen by SIMS namely Si, Cl and Ge, As, with only a minor contribution of Cd and Te. From the changes of the concentrations of the various impurities along the crystal, informations about segregation coefficients and compensation can be obtained.
This perspective view of Venus, generated by computer from NASA's Magellan data and color-coded with emissivity, shows part of the lowlands to the north of ...
The introduction of oxygen in the vicinity of a metallic target surface, bombarded with positive argon ions of twenty kiloelectron-volts, increases the number of sputtered atoms in the excited state. This phenomenon of exaltation, very sensitive in the case of nickel and aluminium, is much less marked in the case of molybdenum. Moreover, the emission of excited particles coming from the beam's ions is not modified. A quantum-mechanical model of a kinetic emission process, which permits the interpretation of the clean metallic target's emission phenomena, seems insufficient to explain all of the results obtained in the presence of oxygen. In this last case one can therfore use a thermodynamic model in which excited metallic particles can be formed directly by chemical surface reactions of neutralization or reduction. (orig.).
Gas separation membranes with polydimethylsiloxane(PDMS)/polystyrene(PS) were prepared by using the sequential interpenetrating polymer network (IPN) method with various PS contents (10?70wt%). These gas separation membranes can be applied to reduce the smoke density in the emission gas of diesel engines. PS content has a pronounced effect on the membrane performance. It was found that the optimized PS contents in the final membrane were 50wt%. The emission capacities of diesel engines used in this study were 632 cc and 11,149 cc. When the oxygen separation membrane was used in the diesel engines, the smoke density of both diesel engines was remarkably reduced (35?73%). The oxygen concentration in the inlet air affects the composition of the emission gases. Especially, hydrocarbon (HC) dec...
The purpose of this statement of work (SOW) is to establish laboratory analytical criteria and requirements for radioactive airborne emissions measurement sample and/or analysis activities.
Performance and emissions data were gathered on a normally aspirated single cylinder DI engine with various combinations of ceramic coatings installed. Thin ceramic thermal barrier coatings were applied to the piston crown and bowl, the head and valves, and the cylinder liner. The coated piston and head were run singly and in combination with the cylinder liner to investigate the effects of these different coated surfaces on emissions and performance. Coating the piston crown alone results in generally lower cylinder pressure, lower brake specific fuel consumption and lower NO(x) emission compared to the baseline engine. Soot emission is typically increased below 2000 RPM and decreased above 2000 RPM. Coating the head alone reduces cylinder pressure, but generally increases specific fuel consumption and NO(x) and soot emission. The KIVA-II code was used to model the Hydra engine ...
Corrosion of steam generator heat transfer tubes (SGHTT) is one of the important problems which affect safety operation of nuclear power plants (NPP), and the hazard of pitting corrosion of heat transfer tubes is the most serious. With an acoustic emission device, the signals during a corrosion test on SGHTT were collected and analyzed, and the corrosion points in the tubes were located accurately. The results show that pitting corrosion of heat transfer tubes has passed through three periods in its development: expansion phase, stationary phase and rapid developing phase. The corrosion damage of HTT can be found earlier with acoustic emission than any other non-destructive testing methods. Acoustic emission can be used for on-line and real-time monitoring of the safety and operation of the steam generator and has therefore a great significance. (orig.)
Global climate policy initiatives are now being proposed to compensate tropical forest nations for reducing carbon emissions from deforestation and forest degradation (REDD). These proposals have the potential to include developing countries more actively in international greenhouse gas mitigation and to address a substantial share of the world's emissions which come from tropical deforestation. For such a policy to be viable it must have a credible benchmark against which emissions reduction can be calculated. This benchmark, sometimes termed a baseline or reference emissions scenario, can be based directly on historical emissions or can use historical emissions as input for business as usual projections. Here, we review existing data and methods that could be used to measure historical deforestation and forest degradation reference scenarios including ...
Global climate policy initiatives are now being proposed to compensate tropical forest nations for reducing carbon emissions from deforestation and forest degradation (REDD). These proposals have the potential to include developing countries more actively in international greenhouse gas mitigation and to address a substantial share of the world's emissions which come from tropical deforestation. For such a policy to be viable it must have a credible benchmark against which emissions reduction can be calculated. This benchmark, sometimes termed a baseline or reference emissions scenario, can be based directly on historical emissions or can use historical emissions as input for business as usual projections. Here, we review existing data and methods that could be used to measure historical deforestation and forest degradation reference scenarios including FAO ...
This paper summarizes the main features of four current REDD proposals: Compensated Reduction, Papua New Guinea et al; Joint Research Center; and Brazil. ... ...
The influence of engine operating variables on the performance, emissions and heat release in a compression ignition engine operating in normal diesel and dual-fuel modes (with natural gas fuelling) was investigated. Substantial reductions in NO{sub x} emissions were obtained with dual-fuel engine operation. There was a corresponding increase in unburned hydrocarbon emissions as the substitution of natural gas was increased. Brake specific energy consumption decreased with natural gas substitution at high loads but increased at low loads. Experimental results at fixed pilot injection timing have also established the importance of intake manifold pressure and temperature in improving dual-fuel performance and emissions at part load. (Author)
The factors influencing premixed burning and the importance of premixed burning on the exhaust emissions from a small high-speed direct-injection diesel engine were investigated. The characteristics of premixed and diffusion burning were examined using a single-zone heat-release analysis. The mass of fuel burned in premixed combustion was found to be linearly related to the product of engine speed and ignition-delay time and to be essentially independent of the total amount of fuel injected. Accordingly, the premixed-burned fraction increased with increasing engine speed, with decreasing fuel-air ratio and with retarding injection timing. The hydrocarbon emissions did not correlate well with the premixed-burned fraction. In contrast, the oxides of nitrogen emissions were found to increase with decreasing premixed-burned fraction, indicating that diffusion burning, and not premixed burning, is the primary source of oxides of ...
NEWTON's first law prohibits the coupling of free tachyons to ordinary matter, if it is interpreted as selection rule interdicting emission without change of the rest-mass of the emitting system.
This is the final report of a three-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The authors investigated the evolution and radiation characteristics of individual neutron stars and stellar systems. The work concentrated on phenomena where new techniques and observations are dramatically enlarging the understanding of stellar phenomena. Part of this project was a study of x-ray and gamma-ray emission from neutron stars and other compact objects. This effort included calculating the thermal x-ray emission from young neutron stars, deriving the radio and gamma-ray emission from active pulsars and modeling intense gamma-ray bursts in distant galaxies. They also measured periodic optical and infrared fluctuations from rotating neutron stars and search for high-energy TeV gamma rays from discrete celestial sources.
(e.g. enclosed cooktop with built in emissions capture and treatment) . " Test hardware in laboratory, reduced pressure and analog habitat. " Objective 1. ...
Divergence betyveen aircraft engine emission regulations pro- posed by EPA and ICAO is discussed Every engine, upon entering service, requires a certificate ...
We have studied the nature of continuum emitted in the visible spectral range from a noncontracted positive column of discharge in a cesium vapor-xenon mixture at a pressure of 45 Torr and at a degree of ionization below 3 ? 10?6. The main contribution to the continuous emission under such conditions is due to electron-xenon atom bremsstrahlung. The intensity of emission has been experimentally and theoretically studied as a function of the electric field strength and electron density in the positive column. It is established that an increase in the visible emission intensity with the electric field strength is related to an increase in the number of hot electrons in plasma.
This paper reports extensive new optical and radio observations of NGC 5728, emphasizing the central regions. Deep photographs revealing detail in the faint spiral arms are briefly discussed. Broad-band UBV CCD images obtained to examine the colors of the stellar populations that comprise the bar and central ring are presented. The velocity field and emission maps obtained from imaging spectroscopic measurements in the H-alpha emission line are discussed. Conventional long-slit spectra covering the ionized gas in the nuclear region are described. Detailed maps of the radio emission in the central regions of NGC 5728 are presented. These combined data provide considerable evidence for the inflow of gas into the nuclear region, in response to the nonaxisymmetric gravitational potential of the bar. The possible relation of this phenomenon to the Seyfert nature of NGC 5728 is also considered. 48 references.
We report novel, high-angular resolution interferometric measurements that imply the near-infrared nuclear emission in NGC 4151 is unexpectedly compact. We have observed the nucleus of NGC 4151 at 2.2 microns using the two 10-meter Keck telescopes as an interferometer and find a marginally resolved source ~0.1 pc in diameter. Our measurements rule out models in which a majority of the K band nuclear emission is produced on scales larger than this size. The interpretation of our measurement most consistent with other observations is that the emission mainly originates directly in the central accretion disk. This implies that AGN unification models invoking hot, optically thick dust may not be applicable to NGC 4151.
The performance of the gaseous fuel supply and its influence on hydrocarbon (HC) emissions of dual-fuel engines have been investigated. A new design of manifold respirators with mixers is also presented in the paper. The design of the gaseous fuel supply system has a great influence on HC emissions in the dual-fuel engine at light load. The problem of scavenging is discussed and solved by using the manifold respirators in the dual-fuel engine. It performs the function of retarding the gaseous fuel entry timing from the moment of intake valve opening, and its delaying effects have been measured and tested. Experimental results show that the manifold respirator gives the best performance in reducing HC emissions compared with a common pipe mixer and a respirator with bo miser. In addition, the mixing effects are sensitive to the mixer configuration. (Author)
Ceramic coatings with high emission were fabricated on Ti6Al4V alloy by microarc oxidation (MAO) with additive FeSO4 into the electrolyte. The microstructure, chemical composition and chemical state of the coatings were determined by SEM, XRD, EDS and XPS, respectively. The bonding strength between the coating and substrate was studied by tensile strength test, together with the thermal shock resistance of the coating. The results showed that Fe content in the coating layer significantly affect its thermal emissivity. The relative content of Fe in the coatings surface increased at first and then decreased with increasing the concentration of FeSO4 in electrolytes, so does the emissivity of the coatings. The bonding strength became weaker with increasing the concentration of FeSO4. In addit...
The Kyoto Protocol attempts through political negotiations to guide participating industrialized countries' greenhouse gas (GHG) emissions from a positive growing trend, to reach a peak point (or turning point), and then be reduced to a negative growth. That means the relationship between decreasing GHG emissions and economic growth may be described by an inverted-U curve (or called a bell-shaped curve), which is consistent with the concept of the Environmental Kuznets Curve (EKC) hypothesis.This research observed that the economic development and GHG emissions in Economies in Transition (EITs) exhibit a hockey-stick curve trend (or called quasi-L-shape curve), that also generates a lot of "hot air" which is significant to the implementation of the Kyoto Protocol. In addition, through the ...
... non- emissive guidance and collision alert, automated transport in dynamic environments, and assembly and inspection. Foveal Vision, Autonomous Agents, ...
Biomass combustion is an important part in a sustainable energy system, but as well a source of submicron (particles < 1 #mu#m) particles in the air. Consequently, to obtain a good air quality together with increased biomass combustion there is a need for a better understanding of particle formation. This work is a part of a larger project about formation and emissions of particles from biofuel combustion. The report includes the work performed in the project during the year 2004. The aim of the project is to describe the release of inorganic components, which cause particle emissions, during combustion of single fuel particles of biofuel, e.g. wood pellets. The work is carried out by emission measurements, systematic combustion experiments and modelling work. The results are expected to contribute to the understanding of which parameters that influence the formation of fine particles and thus gain a better insight into ...
The report contains general information on aluminium and aluminium compounds concerning the existing standards, emissions, exposure levels and effect levels. The document is to be considered as a first evaluation to be used for the national discussion dur...
The iron foundry industry is considered to be a potential source of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). This study investigated the emission factors and total emission amounts of PCDD/Fs and dioxin-like polychlorinated biphenyls (DL-PCBs) from iron foundries in China. The concentrations and the World Health Organization toxicity equivalents (WHO-TEQs) are presented and the congener profiles are discussed in this paper. In the present work, 26 fly ash samples were collected and tested to quantify the PCDD/Fs and DL-PCBs generated by 14 plants of different scales, and five stack gas samples were collected from two (named as EFG and LFG) of those plants. The emission levels of PCDD/Fs and DL-PCBs indicated that hot-air cupolas had lower emissions than cold-air cupol...
The paper discusses a number of recent studies investigating into the energy conservation and environmental impacts of electric heating systems (off-peak storage systems). In future, i.e. in and after 1993, off-peak storage systems will be evaluated through comparative analyses of oil-fired heating systems, pollutant emission analyses, the eventual success of pollution abatement measures designed for power plant emissions to keep within the legal limiting values, and the possible abandonment of pollution abatement measures abroad. Opposing the electric heating studies submitted by the electric power industry the author refutes their favourable results referring to the palliative selection of inadequate or vague parameters. Assuming average power plant pollutant emissions of 180 mg/standard/sup 3/ the nitrogen oxide emissions of oil-fired heating systems (134.1 kg/Tj) are found to be below those of ...
Before the 1997 Kyoto Protocol on Climate Protection, the fluorinated greenhouse gases HFCs, PFCs, and SF6 (F-gases) aroused little public attention. Since then, the standards on surveying and reporting on national emissions have been rising constantly. Amongst others, the annual reporting to the UNFCCC secretariat makes detailed declarations on use and emissions of F-gases necessary, which have to be filled in specified formats for submission (Common Reporting Format = CRF). The scientific basis has been set out by the UNFCCC guidelines on reporting, in accordance with the instructions laid down in IPCC good practice guidance. Additionally, in Germany the Centralised System of Emissions (ZSE) shall provide a suitable tool to satisfy any quality needs of both activity data and emission factors. From 1995 onwards, activity data and emissions of each individual application sector ...
Los Alamos National Laboratory (the Laboratory) is subject to emissions reporting requirements for regulated air contaminants under Title 20 of the New Mexico Administrative Code, Chapter 2, Part 73 (20 NMAC 2.73), Notice of Intent and Emissions Inventory Requirements. The Laboratory has the potential to emit 100 tons per year of suspended particulate matter, nitrogen oxides, carbon monoxide, sulfur oxides, and volatile organic compounds. For 1998, combustion products from the industrial sources contributed the greatest amount of criteria air pollutants from the Laboratory. Research and development activities contributed the greatest amount of volatile organic compounds. Emissions of beryllium and aluminum were reported for activities permitted under 20 NMAC 2.72 Construction Permits.
Although various legislation and regulations have been adopted to promote the use of alternative-fuel vehicles for curbing urban air pollution problems, there is a lack of systematic comparisons of emission control cost-effectiveness among various alternative-fuel vehicle types. In this paper, life-cycle emission reductions and life-cycle costs were estimated for passenger cars fueled with methanol, ethanol, liquefied petroleum gas, compressed natural gas, and electricity. Vehicle emission estimates included both exhaust and evaporative emissions for air pollutants of hydrocarbon, carbon monoxide, nitrogen oxides, and air-toxic pollutants of benzene, formaldehyde, 1,3-butadiene, and acetaldehyde. Vehicle life-cycle cost estimates accounted for vehicle purchase prices, vehicle life, fuel costs, and vehicle maintenance costs. Emission control cost-effectiveness presented in dollars ...
The properties of negative-ion beams are very important for designing negative-ion apparatus and applications of negative-ion beams, especially, electron detachment cross-sections at the interaction between negative-ion beams and gas particles in the transport system, and secondary-electron emission factors when negative ions are incident on solid surfaces. These properties of negative-ion beams were investigated experimentally as a function of the ion energy under 50 keV. The single electron detachment cross-sections are almost constant in the other of 10[sup -15] cm[sup 2] in this energy range, but double electron detachment cross-sections increase in proportion to the ion velocity and much smaller than the single one. As for the secondary-electron emission factor, the emission factors for negative-ion beam are found to be larger by 1 than those for positive-ion beams. (author).
The properties of negative-ion beams are very important for designing negative-ion apparatus and applications of negative-ion beams, especially, electron detachment cross-sections at the interaction between negative-ion beams and gas particles in the transport system, and secondary-electron emission factors when negative ions are incident on solid surfaces. These properties of negative-ion beams were investigated experimentally as a function of the ion energy under 50 keV. The single electron detachment cross-sections are almost constant in the other of 10"-"1"5 cm"2 in this energy range, but double electron detachment cross-sections increase in proportion to the ion velocity and much smaller than the single one. As for the secondary-electron emission factor, the emission factors for negative-ion beam are found to be larger by 1 than those for positive-ion beams. (author).
Experiments have been conducted to study the effect of injection pressure on the combustion process and exhaust emissions of a direct injection diesel engine fueled with Orange Skin Powder Diesel Solution (OSPDS). Earlier investigation by the authors revealed that 30% OSPDS was optimum for better performance and emissions. In the present investigation the injection pressure was varied with 30% OSPDS and the combustion, performance and emissions characteristics were compared with those of diesel fuel. The different injection pressures studied were 215bar, 235bar and 255bar. The results showed that the cylinder pressure with 30% OSPDS at 235bar fuel injection pressure, was higher than that of diesel fuel as well as at other injection pressures. Similarly, the ignition delay was longer and wi...
This standard specifies requirements for the flameproofing and the limiting of surface temperature and exhaust emission control of diesel engine systems for use in underground coal mines.
The work described in the following is a portion of the MEET project (Methodologies for Estimation Air Pollutant Emissions from Transport). The overall goal of the MEET project is to consolidate and present methodologies which can be used to estimate air pollutant emissions from various types of traffic sources. One of the goals of MEET is to provide methodologies to be used in the COMMUTE project also funded by DG VII. COMMUTE is developing computer software which can be used to provide emissions inventories on the European scale. Although COMMUTE is viewed as a prime user of the information generated in MEET, the MEET results are intended to be used in a broader area, and on both smaller and larger spatial scales. The methodologies and data presented will be useful for planners on a more local scale than a national or continental basis. While most attention in previous years has been concentrated on ...
... 1-sigma ZOHF pixel-to-plxel statistical fluctuations ... Spatial frequency filtering shows distinct bands, but miss ... LOS emissivity at the point of closest ...
Fire-driven deforestation is the major source of carbon emissions from Amazonia. Recent expansion of mechanized agriculture in forested regions of Amazonia ...
on the range of available deforestation, forest degradation, ... Results: Deforestation estimates showed good agreement for multi-year trends of increasing ...
A series of meteorological and tracer experiments, was conducted during May and June 1984 over the 20-km wide /O/resund strait between Denmark and Sweden for the purpose of studying atmospheric dispersion processes over cold water and warm land surfaces and providing the data needed to evaluate meso-scale models in a coastal environment. In concert with these objectives the data from these experiments have been used as part of a continuing effort to evaluate the capability of the three-dimensional MATHEW/ADPIC (M/A) atmospheric dispersion models to simulate pollutant transport and diffusion characteristics of the atmospheric during a wide variety of meteorological conditions. Since previous studies have focused primarily on M/A model evaluations over rolling and complex terrain at inland sites, the /O/resund experiments provide a unique opportunity to evaluate the models in a coastal environment. The M/A models are used by ...
Conventional plasma carburizing or nitriding for austenitic stainless steels results in a degradation of corrosion resistance. However, a low temperature plasma surface treatment can improve surface hardness without deteriorating the corrosion resistance. The 2-step low temperature plasma processes (the combined carburizing and post nitriding) offers the increase of both surface hardness and thickness of hardened layer and corrosion resistance than the individually processed low temperature nitriding and low temperature carburizing techniques. In the present paper, attempts have been made to investigate the influence of the introduction of Ar gas (0#approx#20%) in nitriding atmosphere during low temperature plasma nitriding at 370 .deg. C after low temperature plasma carburizing at 470 .deg. C. All treated specimens exhibited the increase of the surface hardness with increasing Ar level in the atmosphere and the surface hardness value reached ...
This paper reports the estimates concerning the atmospheric carbon dioxide absorption and storage by living plants all over the world. It is necessary to decrease atmospheric carbon dioxide concentrations for avoiding global warming. As living plants absorb carbon dioxide by photosynthesis and accumulate carbon in their bodies, they can play an important role to remove atmospheric carbon dioxide. Literatures describing distribution areas, biomass values and net primary productivity (NPP) of forests, marine plants and microorganisms were collected. Examining those data, the biomass and NPP of forests, marine plants and microorganisms can be summarized as follows: (1) Forest biomass and their NPP of the world. The world's forest area is recently estimated as 4 billion hectares, and their biomass is about 400 billion tons of carbon which is equal to 2/3 of the total atmospheric carbon. The NPP of ...
Corrosion characteristics of Al and Cu thin films have been studied in cyclic fog tests using tap water fog and fog created with 0.1% NaCl solution in tap water. Likewise, their corrosion features have been analyzed in continuous immersion testing in the laboratory in distilled water, tap water, in 0.1% NaCl and 3.5% NaCl solutions in distilled water. The corrosion potentials and the corrosion currents of these thin films change and reach steady state values after some time. However, steady state is not realized in 3.5% NaCl solutions. The corrosion current density data have been used to calculate lifetime of 1 {mu}m thick thin films of Al and Cu in the various tests, and assuming that the fog test data would hold under normal exposure conditions, life spans for these thin film sensor elements in actual exterior exposure have also been calculated. According to estimates, an Al-TF of about 1 {mu}m would last about 9 months in exterior exposure in chloride containing ...
In cold countries, the design of transmission lines and communication networks requires the knowledge of ice loads on conductors. Atmospheric icing is a stochastic phenomenon and therefore probabilistic design is used more and more for structure icing analysis. For strength and reliability assessments, a data base on atmospheric icing is needed to characterize the distributions of ice load and corresponding meteorological parameters. A test site where icing is frequent is used to obtain field data on atmospheric icing. This test site is located on the Mt. Valin, near Chicoutimi, Quebec, Canada. The experimental installation is mainly composed of various instrumented but non-energized test cables, meteorological instruments, a data acquisition system, and a video recorder. Several types of icing events can produce large ice accretions dangerous for land-based structures. They are rime due to in-cloud icing, glaze caused by ...
'Within 15 years the energy consumption bottleneck has shifted from the supply side to emissions, i.e. to the waste side.' Reflecting this statement one may realize the importance of lending more weight to energy conservation but may also be induced to critically analyze the corresponding measures. First results of such reflections are given with regard to the payback periods of air pollution abatement measures relative to the additional emissions they cause. (orig.).
Lectures were held on forest and wood management, the forest as an energy source and the emission problem of wood combustion, future emission limitating regulations for wood firing, influence of firing technique on air pollution abatement and constructive and operational air pollution abatement measures with manually and continuously fuelled furnaces.
The emission of Cerenkov radiation by tachyons has been examined by using the reduced expansions of superluminal electromagnetic fields in terms of standard helicity representation of Poincare group. It has been shown that the tachyons emit Cerenkov radiation through their coupling only with subluminal electromagnetic fields and that a charged tachyon can emit Cerenkov radiation only in the media in which it travels with a velocity lower than that of light while in the usual medium in which its velocity is more than that of light, it will never emit Cerenkov radiation.
In this work, the principal continuum radiative emission processes, which occur during the penetration of ions in solids or gases, are resumed. The characteristics of the following processes are discussed: secondary electron bremsstrahlung (SEB), atomic bremsstrahlung (AB), and internuclear bremsstrahlung (INB). Recent advances of the ion channeling effects in crystal solids on the spontaneous radiative spectra are exposed. (A.C.A.S.).
In February 2001, the Minister of Environment Canada outlined a series of measures to be implemented over the next decades to reduce emissions from vehicles, engines and fuels. The agenda includes the development of new regulations under the authority of Part 7, Division 5 of the Canadian Environmental Protection Act (CEPA) to align Canada's emission standards for on-road vehicles with those of the United States Environmental Protection Agency. This paper presents a detailed summary of comments received by the interested parties that appeared at a public consultation in November 2001 to discuss and raise issues about the proposed regulations. The parties that provided submissions included: governments; the vehicle and engine manufacturing industry; the oil industry; other groups of associations such as the Canadian Trucking Alliance, David Suzuki Foundation, and West Coast Environmental Law; and, five private individuals. The report ...
In response to a need of the safeguards community, we have begun an evaluation effort to upgrade the recommended values of the prompt neutron emission multiplicity distribution, P/sub nu/ and its average value, nubar. This paper will report on progress achieved thus far. The evaluation of the uranium, plutonium, americium and curium nuclide's nubar values will be presented. The recommended values will be given and discussed. 61 references.
It is shown that low-frequency elastic vibrations of near-surface planar defects cause high-frequency ultrasonic radiation in surrounding air. The frequency conversion mechanism is concerned with contact nonlinearity of the defect vibrations and provides efficient generation of air-coupled higher-order ultraharmonics, ultrasubharmonics, and combination frequencies. The nonlinear air-coupled ultrasonic emission is applied for location and high-resolution imaging of damage-induced defects in a variety of solid materials.
The present work reports an experimental study on the behavior of a jet flame surrounded by a shroud of combustion air. Measurements focussed on the flame length and the emissions of NO{sub x}, total unburned hydrocarbons, CO{sub 2}, and O{sub 2}. Four different fuel flow rates (40.0, 78.33, 138.33, and 166.6 cm/s), air flow rates up to 2500 cm{sup 3}/s and four different air injector diameters (0.079 cm, 0. 158 cm, 0.237 cm, and 0.316 cm) were used. The shroud of combustion air causes the flame length to decrease by a factor proportional to 1/[p{sub a}/p{sub f} + C{sub 2}({mu}{sub a}Re,a/{mu}{sub f}Re,f){sup 2}]{sup {1/2}}. A substantial shortening of the flame length occurred by increasing the air injection velocity keeping fuel rate fixed or conversely by lowering the fuel flow rate keeping air flow rate constant. NO{sub x} emissions ranging from 5 ppm to 64 ppm were observed and the emission of NO{sub x} decreased ...
The Clean Air Act establishes New Source Review (NSR) programs that apply to the construction or modification of major stationary emissions sources. In 2002 and 2003, the U.S. Environmental Protection Agency revised its rules to narrow the applicability of NSR to facility renovations. Congress then mandated a National Research Council study of the effects of the rules. An electricity-sector model - the Integrated Planning Model (IPM) - was used to explore the possible effects of the equipment replacement provision (ERP), the principal NSR change that was to affect the power-generation industry. The studies focused in particular on coal-fired electricity generating units, EGUs, for two reasons. First, coal-fired EGUs are important contributors of these pollutants, accounting for approximately 70 and 20% of nations SO{sub 2} and NOx emissions in 2004, respectively. Second, the shares of total capacity of large coal-fired EGUs that lack flue-gas ...
Auger-electron emission from different silicides has been studied for 4 and 10 keV Ar ion excitation. The intensity of the SiLMM Auger line changes significantly with channing concentration and atomic number of the metal-parthner. The experimental results can be explained in terms of a simple model based on the probability of Si-Si collision symmetric cascade in these binary compounds.
In this report statistical data are presented on a national level on emissions to air in Sweden in 1995 of sulphur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}, counted as NO{sub 2}) and carbon dioxide (CO{sub 2}). Corresponding data for 1980 and 1994 are presented as a comparison. For CO{sub 2} data for 1990 and 1994 are presented as a comparison. The total amount of SO{sub 2}-emissions to air in 1995 were 94 000 tons, which means a decrease by 3 percent since 1994. The total amount of NO{sub x}-emissions to air were 362 000 tons, a 3 percent decrease since 1993. The total amount of CO{sub 2}-emissions to air were 63 200 000 tons, an increase by 7 percent compared with 1990. Differentiated data are given for various sources of emissions, i.e. combustion of fuels, industrial processes and mobile sources. Further data are presented on emission of SO{sub 2} and ...
Experiments have been conducted to study the effect of injection pressure on the combustion process and exhaust emissions of a direct injection diesel engine fueled with Orange Skin Powder Diesel Solution (OSPDS). Earlier investigation by the authors revealed that 30% OSPDS was optimum for better performance and emissions. In the present investigation the injection pressure was varied with 30% OSPDS and the combustion, performance and emissions characteristics were compared with those of diesel fuel. The different injection pressures studied were 215 bar, 235 bar and 255 bar. The results showed that the cylinder pressure with 30% OSPDS at 235 bar fuel injection pressure, was higher than that of diesel fuel as well as at other injection pressures. Similarly, the ignition delay was longer and with shorter combustion duration with 30% OSPDS at 235 bar injection pressure. The brake thermal efficiency was better at 235 bar than ...
Due to the 'novel forest diseases' the political parties of the Federal Republic of Germany unanimously attend to the reduction of emissions. The transportation sector is considered to be a major emission source. A study discussed in the publication abstracted did therefore aim at giving a detailed account and description of the recently ratified technical requirements and tax credits expected to reduce vehicle exhaust gas air pollution. Moreover, the study researches into the regulations' importance as to the low emission properties of individual automobiles. Based on the results obtained the study arrives at assumptions as to emissions to be expected from the transportation sector. It tries to assess the financial import with respect to the individual citizen, overall internal revenues and federal motor vehicle taxes. The introductory chapter is followed by a review of ...
A large IMF- and event characterizing multidetector system (CHICSI) is under development for storage ring experiments. In ''test'' experiments with telescopes of CHICSI type the IMF production has been measured for "1"4N induced reactions at 14A and 32A MeV. Detailed information about the emission sources, particularly from the IMF yield in reactions with isotope separated targets and from isobaric yield ratios in the sub-Coulomb region is discussed. (orig.).
This study presents and applies a coherent methodological framework to compare biomass cascading chains, i.e. the subsequent use of biomass for materials, recycling and energy recovery, considering land use, CO2 emission reduction and economic performance. Example cascading chains of short rotation poplar wood are compared with each other on the basis of literature data. Results for these chains vary strongly, namely, from CO2 mitigation benefits of 200 euro/Mg CO2 to CO2 mitigation costs of 2200 euro/Mg CO2, and from net CO2 emission reductions per hectare of biomass production of 28 Mg CO2/(ha yr) to net CO2 emissions of 8 Mg CO2/(ha yr). Using a present-value approach to determine CO2 emissions and costs affects the performance of long-term cascading chains significantly, i.e. cost and CO2 emission reduction are decreased. In general, cascading has the potential to improve both ...
This paper describes New York State Electric and Gas Corporation`s concept for a comprehensive, centrally located data system for management of their continuous emission monitoring systems (CEMS) data. The topics of the paper include the power system`s mix of generating units; data reporting requirements; data base management; nitrogen oxides compliance tracking; sulfur dioxide, nitrogen oxides, carbon dioxide and flow monitoring; and allowance tracking.
Characterization and optimization of electron-beam parameters are important aspects of optimizing free-electron laser (FEL) performance. The visible spontaneous emission ({lambda}{approximately}650 nm) from the 5-meter long undulator of the Boeing FEL experiment can be characterized in sufficient detail with a streak/spectrometer to deduce time-resolved electron-beam spatial position and profile, micropulse duration, and energy. 7 refs., 13 figs., 2 tabs.
Discussion is presented of world CO{sub 2} emissions and the effect rising population and population distribution has on this. Possible ways of decreasing emissions are presented, including potential for heat recovery, exhaust-air purification as an energy supply, shared power supply in industry, the use of cogeneration, and multiple use of heat in industry. 9 refs., 10 figs., 3 tabs.
We derive the expression for spontaneous emission rate in finite one-dimensional photonic crystal with arbitrary defects using the effective resonator model to describe electromagnetic field distributions in the structure. We obtain explicit formulas for contributions of different types of modes, i.e. radiation, substrate and guided modes. Formal calculations are illustrated with a few numerical examples, which demonstrate that the application of effective resonator model simplifies interpretation of results.
In the last issue of 'L'Industrie ceramique et verriere', we presented the first part of this study. We describe in this issue the experimental procedure, the results and the conclusions of this work. (authors)
The paper investigates the controversial relation between the continuum luminosity and the C IV 1550 emission-line strength in the spectra of quasars, commonly referred to as the Baldwin effect, as a possible indicator of absolute luminosity. It is concluded that the Baldwin effect does represent a physical correlation between the continuum and the C IV 1550 equivalent width rather than a consequence of selection effects. In addition to the C IV results, a similar relation is found for the Lyman-alpha emission line. 38 refs.
This paper reviews three key initiatives undertaken in the historical city of Oxford to bring about reductions in energy-related CO_2 emissions on a city-wide scale. The author has been part of all the three initiatives. In 2002, a collaborative partnership between academia, industry and city council started the Oxford Solar Initiative (OSI) which uses a community-based approach to help households and organisations in Oxford, financially and technically, to install solar energy systems and energy efficiency measures in buildings. So far OSI has facilitated the installation of 80 active solar systems, over 450 energy efficiency measures and 3,000 low energy bulbs. The scientific basis of OSI is a GIS-based DECoRuM model which estimates and maps baseline energy use and CO_2 emissions on a house-by house level, identifies 'pollution' hotspots, predicts the potential for reductions in CO_2 emissions and monitors reductions ...
The authors present design methodology and initial experimental results for a high power microwave switch. The switch is designed for application to the pulse compression system associated with the Next Linear Collider Test Accelerator (NLCTA). The switch is based on the excitation of a plasma layer within a silicon wafer by either a laser or an electron beam. They investigate problems associated with high power operation of such a switch. They explore solutions to the problems of thermal runaway, avalanche breakdown, photo-emission, and secondary emission.
This critical review with 28 references examines absorption and emission in the v2 band of the carbon dioxide molecule at around the 15micron wavelength. The argument for additional infrared absorption, the enhanced greenhouse effect due to increased carbon dioxide concentrations, and radiation transport and increased emissions are discussed. Experiments studying the transmission spectra of pure carbon dioxide and carbon dioxide in nitrogen, and comparing them with the results of climate modelling using the HITRAN and GEISA databases, are described.
Solar ultraviolet radiation is damaging for living organisms due to its high energy pro each photon. The UV radiation is often separated into three regions according to the wavelength: UVC (200-280 nm), UVB (280-320 nm) and UVA (320-400 nm). The most hazardous part, UVC is absorbed completely in the upper atmosphere by molecular oxygen. UVB radiation is absorbed by atmospheric ozone partly, and it is reaching Earth`s surface, as UVA radiation. Besides atmospheric ozone, very important factors in determining the intensity of UVB radiation globally are the solar zenith angle and cloudiness. It may be calculated from global ozone changes that the clear-sky UVB doses may have enhanced by 10-15 % during spring and 5-10 % during summer at the latitudes of Finland, following the decrease of total ozone between 1979-90. The Finnish ozone and UV monitoring activities have become a part of international activities, especially the EU ...
Experimental investigations have been shown that the thermal stability of carnallite shows a clear change to hogher temperature with increasing pressure if the decomposition atmosphere is not removed. Around 40 bar, constitutional water is released from the carnallite lattice at 139/sup 0/C, around 100 bar at 145/sup 0/C. The available temeprature data on thermal release of constitutional water in carnallite (80 to 110/sup 0/C) are not relevant to the possible heat load in a final-storage salt done as all investigations have been carried out in vacuum or in open systems under atmospheric conditions. The author's investigations show the decomposition temeprature of carnallite will be much higher under in-situ conditions with blocked or delayed removal of decomposition atmosphere. However, this applies only to carnallite as isolated mineral phase. Final statements cannot be made until the pressure-temperature ...
One of the least understood regions of the upper atmosphere is the thermosphere, principally due to the difficulty of making observations. The neutral atmosphere is known to be highly variable, and its composition and density varies by several orders of magnitude due to solar activity, diurnal cycles, latitude, geomagnetic activity, and gravity waves. In the past, most in-situ measurements of the neutral atmosphere have utilized detectors that are dependent on arrival angle and energy accommodation of incoming species, so that information related to nascent velocity distribution and reactive species abundances is often masked. This paper will review design concepts and laboratory tests related to the development of a novel open-ionizer, neutral particle detector for space environment measurements which can overcome these limitations. The sensor features a very large field-of-view suitable for sounding rocket missions. ...
The Argonne Boundary Layer Experiments (ABLE) facility, located in south central Kansas, east of Wichita, is devoted primarily to investigations of and within the planetary boundary layer (PBL), including the dynamics of the mixed layer during both day and night; effects of varying land use and land form; the interactive role of precipitation, runoff, and soil moisture; storm development; and energy budgets on scales of 10 to 100 km. Located entirely within the Walnut River watershed, ABLE provides intense measurements within the northeast quadrant (Fig. 1) of the Southern Great Plains (SGP) Cloud and Radiation Testbed (CART) of the Atmospheric Radiation Measurement (ARM) Program (Stokes and Schwarz, 1994). By combining the continuous measurements of ABLE with ancillary continuous measurements of, for example, the ARM and the Global Energy Water cycle Experiment (GEWEX) (Kinster and Shukla, 1990) programs, ABLE provides a platform within which shorter, more ...
Biofumigation with Muscodor albus was investigated to control four fungal decay pathogens (Phytophthora erythroseptica, Sclerotinia sclerotiorum, Botrytis cinerea and Penicillium expansum) and four bacterial pathogens (Erwinia carotovora pv. carotovora, Pseudomonas fluorescens, Escherichia coli, Listeria innocua) in controlled atmosphere conditions (regular air (20.8% O2+0.03% CO2), high CO2 (20.8% O2+15% CO2) or low O2 (1% O2+0.03% CO2)). In vitro experiments involved 48h exposure to M. albus at 3degreeC or 20degreeC, in vivo experiments involved 72h exposure to M. albus at 3degreeC. In vitro biofumigation with M. albus in regular air at 20degreeC killed all the pathogens. Bacterial growth was best controlled by M. albus at 20degreeC regardless of atmospheric conditions whereas fungal gro...
Purpose: To obtain a roof slab cooling device capable of retaining cooling performance even in a case of electric power supply stop or failure and effective from economical point of view. Constitution: Atmospheric air is introduced into the cooling chamber of a proof slab and spontaneously passed to a exit pipeway connected to a stack thereby cooling the roof slab. Specifically, atmospheric air entered from the inlet pipeway is introduced to the cooling chamber and absorbs heat generate from the inside of the reactor container. Warmed air is sucked from the exit pipeway and then released into the atmosphere passing through the stack. The air cools the roof slab during circulation due to spontaneous passage and keeps the slab at a low temperature. Since the air is passed spontaneously, no power such as for a blower is required at all and, if the electric power supply should be lost, the cooling power can be maintained as it ...
The Atmospheric Radiation Monitor (ARM) uninhabited aerospace vehicle (UAV) program aims to develop measurement techniques and instruments suitable for a new class of high altitude, long endurance UAVs while supporting the climate community with valuable data sets. Using the Scaled Composites Proteus aircraft, ARM UAV participated in Mixed-Phase Arctic Cloud Experiment (M-PACE), obtaining unique data to help understand the interaction of clouds with solar and infrared radiation. Many measurements obtained using the Proteus were coincident with in-situ observations made by the UND Citation. Data from M-PACE are needed to understand interactions between clouds, the atmosphere and ocean in the Arctic, critical interactions given large-scale models suggest enhanced warming compared to lower latitudes is occurring.
In closed systems, the O2 compensation point (?O) was previously defined as the upper limit of O2 level, at a given CO2 level, above which plants cannot have positive carbon balance and survive. Studies with 18O2 measure the actual O2 uptake by photorespiration due to the dual function of Rubisco, the enzyme that fixes CO2 and takes O2 as an alternative substrate. One-step modelling of CO2 and O2 uptakes allows calculating a plant specificity factor (Sp) as the sum of the biochemical specificity of Rubisco and a biophysical specificity, function of the resistance to CO2 transfer from the atmosphere to Rubisco. The crossing points (Cx, Ox) are defined as CO2 and O2 concentrations for which O2 and CO2 uptakes are equal. It is observed that: (1) under the preindustrial atmosphere, photorespir...
Meltdown and gasification of waste in an oxygen atmosphere ('2sv' process) is an economically efficient alternative to energetic and thermal utilisation of biomass. Organic pollutants are split at temperatures up to 2000 C in a reducing atmosphere. The process uses elements of the oxygen cupola furnace for melting and gasification of many different waste fractions, e.g. polluted waste wood, household refuse and bulk waste, old tyres, light shredder fractions, sewage sludge, etc. [German] Die Sauerstoff-Schmelz-Vergasung ('2sv') stellt eine wirtschaftliche Alternative zur energetischen Nutzung von Biomassen wie auch zur thermischen Abfallverwertung dar. Organische Schadstoffe werden bei diesem neuen Verfahren bei Temperaturen bis zu 2000 C unter reduzierenden Bedingungen aufgespalten. Das Verfahren nutzt Elemente des Sauerstoff-Kupolofens fuer die Schmelzvergasung und eignet sich fuer zahlreiche Abfallarten ...
ObjectivesThe overall objective of the proposal is to test the conclusions reached in a recent article by Magnani, Mencuccini et al (2007), in which we proposed for the first time that the Net Ecosystem Productivity (NEP) of forests of the temperate and boreal region does not depend on temperature or rainfall but, rather, on nitrogen deposition (Ndep) from the atmosphere. It is widely accepted that Ndep can increase forest C sequestration, however the results from our 2007 paper reported a sensitivity dC/ [continued...]DescriptionCombustion of fossil fuels and use of fertilisers in agriculture has increased the amount of nitrogen compounds present in the atmosphere and the biosphere. More atmospheric nitrogen is converted into reactive nitrogen by anthropogenic activities than by all natural processes combined. This phenomenal historical increase in nitrogen deposition is responsible for several serious environmental ...
Understanding feedbacks between terrestrial and atmospheric systems is vital for predicting the consequences of global change, particularly in the rapidly changing Arctic. Fire is a key process in this context, but the consequences of altered fire regimes in tundra ecosystems are rarely considered, largely because tundra fires occur infrequently on the modern landscape. We present paleoecological data that indicate frequent tundra fires in northcentral Alaska between 14,000 and 10,000 years ago. Charcoal and pollen from lake sediments reveal that ancient birchdominated shrub tundra burned as often as modern boreal forests in the region, every 144 years on average (+/- 90 s.d.; n = 44). Although paleoclimate interpretations and data from modern tundra fires suggest that increased burning was aided by low effective moisture, vegetation cover clearly played a critical role in facilitating the paleo-fires by creating an abundance of fine fuels. These records suggest ...
Results related to the experimental measurement campaign to characterize atmospheric aerosol carried out near Avigliana (Turin) from 18 to 22 October 1994 are presented in this paper. In the frame of the project aimed at evaluating the impact of the mountain motor way A-32 Rivoli-Bardonecchia-Frejus on the Susa Valley environment and on man the present measurement campaign is the second, and last, one envisaged in the project. The sampling place is in the initial part of the Susa Valley while previous measurements were carried out in the high part of it. Mass mean concentrations result greater in the low than in the high part of the valley approximately by a factor of 3. It is not possible to prove a difference between the 3 sampling positions transversely placed from 20 to 80 m. in comparison with the motor way axis. Whereas mass mean concentrations dropped substantially due to atmospheric precipitations during the last two measurement day. ...
The X-ray spectra of some magnetized isolated neutron stars (NSs) show absorption features with equivalent widths (EWs) of 50 - 200 eV, whose nature is not yet well known. To explain the prominent absorption features in the soft X-ray spectra of the highly magnetized (B ~ 10^{14} G) X-ray dim isolated NSs (XDINSs), we theoretically investigate different NS local surface models, including naked condensed iron surfaces and partially ionized hydrogen model atmospheres, with semi-infinite and thin atmospheres above the condensed surface. We also developed a code for computing light curves and integral emergent spectra of magnetized neutron stars with various temperature and magnetic field distributions over the NS surface. We compare the general properties of the computed and observed light curves and integral spectra for XDINS RBS\\,1223 and conclude that the observations can be explained by a thin hydrogen atmosphere above ...
The Convective and Orographically-induced Precipitation Study (COPS) has the aim to advance the quality of forecasts of orographically-induced precipitation in complex terrain. COPS is a Research and Development Project of the World Weather Research Program and considered to be one of the largest field campaigns on quantitative precipitation forecasting that has been performed so far. A network of state-of-the-art active and passive remote sensing systems was combined with in total 10 airborne platforms, Meteosat rapid scans and dense networks of standard meteorological instruments during the three months long field phase (June-August, 2007) in south-western Germany/eastern France to observe atmospheric variables in the three spatial dimensions and in time. By the University of Hohenheim, two novel ground-based mobile scanning lidar systems were deployed: a scanning rotational Raman lidar which provides combined measurements of the field of ...
We propose to investigate the spontaneous emission of radiation arising out of the interaction of a relativistic electron beam with a metallic grating (the Smith-Purcell effect). The work will concentrate, primarily, in the 50-120 #mu#m part of the infrared spectrum and will be an extension of the work begun by the Oxford-Dartmouth-Essex collaboration; one of the early objectives of the project will be to develop a quantitative understanding of the power spectrum of the emitted radiation over a wide range of emission angles. In particular, the limits of relativistic peaking of forward directed emission will be investigated. The electron beam will be produced by laser irradiation of a metallic cathode in the terminal of a small Van de Graff accelerator located in the Technische Universitaet, Muenchen. Beam energies will be in the range of 2 - 4 MeV. Initial tests on photoproduction of electrons have yielded 10 mA pulses with ...
We present the results of a search for Extreme Ultraviolet emission in A4059, a cluster with an X-ray emitting cluster gas. Our analysis of Extreme Ultraviolet Explorer (EUVE) Deep Survey observations of this cluster shows that it is associated with diffuse EUV emission. Outside the central 2 arcmin radius the entire EUV emission detected is explained by the low energy tail of the X-ray emitting gas. Within the central 2 arcmin region of the cluster we find a deficit of EUV emission compared to that expected from the X-ray gas. This flux deficit is discussed in the context of the cluster's cooling flow. The results derived for A4059 are compared to EUVE results obtained for other clusters such as Coma, Virgo, A1795, and A2199. As part of the study we have carried out a detailed investigation of the stability of the EUVE Deep Survey detector background. Based on long integrations of blank sky over 27 ...