Science.gov (United States)

... Richrd Bals andLina PrissJames Lepowsky and Mirko Primc Richard Beaals, and Linda Preiss Rothschild, Editors 47 Linear algebra and its role in ...

Energy Technology Data Exchange (ETDEWEB)

The corrosion behavior of 304 stainless steel was characterized with cyclic voltammetry in a eutectic Li/K and Li/Na carbonate melt under anode and cathode gas of the molten-carbonate fuel cell (MCFC). The corrosion rate of 304 steel was determined in four different environments of the MCFC with electrochemical methods and from cross-sectional analysis of corrosion layers. These four environments were open-circuit and MCFC-load conditions both under anode and cathode gas. At open-circuit conditions corrosion was more severe under the oxidizing cathode gas then under the reducing anode gas. On the contrary, at load conditions corrosion was more severe under anode than under cathode gas. The anodic polarization under anode gas enhances corrosion, whereas the high anodic polarization under cathode gas leads to anodic protection. Corrosion currents were measured with chronoamperometry and determined with Tafel extrapolation from quasi-stationary polarization-curve ...