Energy Technology Data Exchange (ETDEWEB)

This paper presents ionic conductivity results obtained with polymer electrolytes and also with propylene carbonate solutions. The domain of electrochemical activity of this salt has been determined using cycle volt-amperometry in propylene carbonate. Preliminary experiments on the stability of the polymer electrolyte with respect to the lithium electrode have been carried out for a possible subsequent use in lithium batteries. (J.S.) 4 refs.

Energy Technology Data Exchange (ETDEWEB)

The in-situ observation of dendritic growth in lithium/polymer electrolyte-LiTFSI/lithium battery cells shows that dendrites grow up with about the same rate as anion migration. Memory effects have been evidenced in cycling experiments and limit the dendrites length. An overall movement of the electrolyte due to variations of electrolyte concentration in the vicinity of the electrodes has been observed too. (J.S.) 13 refs.

Energy Technology Data Exchange (ETDEWEB)

The lithium carbon batteries studied in this paper use plasticized polymer electrolytes made with passive polymer matrix swollen by a liquid electrolyte with a high ionic conductivity (> 10{sup -3} S/cm at 25 deg. C). The polymers used to prepare the gels are polyacrylonitrile (PAN) and vinylidene poly-fluoride (PVdF). The electrochemical and physical properties of these materials are analyzed according to their composition. The behaviour of solid electrolytes with different materials of lithium ion insertion (graphite and LiNiO{sub 2}) are studied and compared to liquid electrolytes. The parameters taken into account are the reversible and irreversible capacities, the cycling performance and the admissible current densities. Finally, complete lithium ion batteries with gelled electrolytes were manufactured and tested. (J.S.) 2 refs.

Energy Technology Data Exchange (ETDEWEB)

The use of solvating polymers of polyether type is an interesting solution for the manufacturing of high capacity lithium batteries with lithium metal anodes and which can operate at T > 50 deg. C. These operating conditions are perfectly compatible with electric-powered vehicle and stationary battery applications. In order to improve the ionic conductivity of polymer electrolytes, new aprotic and amorphous polyether lattices have been synthesized having a good conductivity but also good thermal, mechanical and electrochemical stabilities. Two type of 3-D polyether lattices obtained by reticulation of linear pre-polymers have been selected as host polymers: unsaturated poly-condensate and unsaturated co-polyethers. (J.S.) 18 refs.

Energy Technology Data Exchange (ETDEWEB)

The BT-EdF-CEA consortium for the development and the performance improvement of lithium/polymer batteries has carried out a safety analysis of the industrial risk and the risk for users linked with this new technology. The process chosen for the manufacturing of lithium/polymer batteries does not generate any particular risk of personnel or environmental contamination. Security tests have permitted to observe and analyze the behaviour of 4 Ah elements during thermal shocks, perforation and crushing, and during external short-circuit on 20 Ah elements. These tests demonstrate the great thermal stability and the excellent behaviour of batteries in the case of partial destruction. (J.S.) 2 refs.

Energy Technology Data Exchange (ETDEWEB)

A solid electrolyte for lithium batteries requires several properties: a good ionic conductivity of about 10{sup -3} S/cm at 298 deg. K, a high cationic transport number (greater than 0.5), a redox stability window higher than 4.5 V, a good stability of the interface with the lithium electrode, and a sufficient mechanical stability. The family of gelled or hybrid electrolytes seems to meet all these requirements. Thus, a systematic study of the gelling of an ethylene carbonate and lithium bistrifluorosulfonimide (LiTFSI) based electrolyte has been carried out. The polymers used for gel or pseudo-gel synthesis are POE, PMMA and PAN which represent 3 different cases of interaction with the electrolyte. All the properties mentioned above have been studied according to the nature of the polymer and to the concentration of lithium salt, showing the advantages and ...

Energy Technology Data Exchange (ETDEWEB)

Single stage separation factors ..cap alpha.. have been determined for /sup 6/Li and /sup 7/Li between lithium ions in methanol and complexed ions with a cryptand (2 sub(B), 2, 1) polymer. The /sup 6/Li was concentrated in the cryptand. The separation factors were compared with the values of other chemical exchange systems. The maximum enrichment factor obtained was epsilon = 0.047 +- 0.002. The figure is one of the greatest in the chemical exchange reactions without valence change and almost 10 times larger than the values of ion exchangers. The variation in ..cap alpha.. depending on the chemical species was small in the non-aqueous system. High enrichment of lithium isotopes was expected to be achievable by means of the chromatographic application of the cryptand (2 sub(B), 2, 1).

Energy Technology Data Exchange (ETDEWEB)

The confocal Raman micro-spectroscopy has been used for the study of a Lithium/polymer electrolyte-LiTFSI/V{sub 2}O{sub 5} type battery in which the polymer electrolyte thickness is of about 80 {mu}m. The analysis is performed on the side of the battery thanks to a specially designed cell which preserves all the characteristics of the real system. The analysis is performed on 20 points aligned between the anode and the cathode and with a depth of several tenth of {mu}m. The analysis of data obtained during charging/output cycles allows to evaluate the gradients of salt concentration inside the electrolyte, the pollutions of LiOH, Li{sub 2}CO{sub 3}, Li{sub 2}O and Li{sub 3}N -type at the lithium interface, but also the structural modifications of the cathode material. The in-situ study of concentration gradients inside the electrolyte is of prime importance for the understanding of dendrites growth. (J.S.) 11 refs.

Energy Technology Data Exchange (ETDEWEB)

Lithium metal-polymer electrolyte batteries with improved utilisation of the active material at a moderate-low temperature (65degC) were realised. Low molecular weight poly(ethylene glycol) (PEG, MW=2000) was used as the lithium-ion conductive matrix in the composite cathode. The cathode active material was crystalline V{sub 2}O{sub 5}. A blend of poly(ethylene oxide) (PEO, MW=4x10{sup 6}) and PEG was used as a solid polymer electrolyte (SPE). The transport properties of the SPE were evaluated at various temperatures. A specific conductivity as high as 1.0x10{sup -4} S cm{sup -1} was calculated at 45degC. The temperature dependence of the interfacial resistances between lithium/SPE and cathode material/PEG was evaluated. The lithium/SPE interfacial resistance decreases linearly with the temperature. The charge transfer resistance between cathode material and PEG ...

British Library Electronic Table of Contents (United Kingdom)

The design of solid breeder blankets is strongly affected by the low values of thermal conductivity and density of ceramic breeder pebble beds. A significant rise of both quantities would enhance the thermal performance and lead to an increased tritium breeding ratio. In order to improve these quantities pretreated lithium orthosilicate pebble material was dry pressed and subsequently sintered. The thermal conductivity of cylindrical pellets was determined by the heat pulse method using a laser flash device. A pebble bed characteristic sample was also investigated in order to check the measurement accuracy in comparison with previous results. Furthermore, two samples of low density cellular ceramics were also prepared by infiltration of polymer foams with a ceramic slurry. The thermal cond...

DEFF Research Database (Denmark)

Polyacrylonitrile (PAN)-based polymer electrolytes have obtained considerable attention due to their fascinating characteristics such as appreciable ionic conductivity at ambient temperatures and mechanical stability. This study is based on the system PAN-ethylene carbonate (EC)-propylene carbonate (PC)-lithium trifluoromethanesulfonate (LiCF3SO3). The composition 15 mol% PAN-42 mol% EC-36 mol% PC-7 mol% LiCF3SO3 has shown a maximum room temperature conductivity of 1.2 x 10(-3) stop S cm(-1) stop. Also, it was possible to make a thin, transparent film out of that composition. Cells of the form, Li/PAN-EC-PC-LiCF3SO3/polypyrrole (PPy)-alkylsulfonate (AS) were investigated using cyclic voltammetry and continuous charge-discharge tests. When cycled at low scan rates, a higher capacity could be obtained and well-defined peaks were present. The appearance of peaks elucidates the fact that redox reactions occur completely. This well proves the reason ...

Energy Technology Data Exchange (ETDEWEB)

A range of additives has been developed for enhancing grafting yields in a variety of systems initiated by ionizing radiation. Cellulose has been adopted as the predominant naturally occurring model backbone polymer in these studies because of its structural relationship to wood which is the reference substrate for the work reported in the related second part of this paper concerning composites. Some experiments have been performed with the other major naturally occurring polymer, wool. For comparison purposes with synthetic materials, some studies have also been performed with polypropylene as trunk polymer. Styrene has been used as a predominant monomer in grafting with some experiments utilizing the acrulates like methyl methacrylate. The role of solvent in grafting has been evaluated. UV has been used as initiator to replace ionizing radiation for certain experiments. The additives used were mineral acids, ...

International Nuclear Information System (INIS)

Becchetti's reply to the preceding ''Comment on "4H clustering in lithium nuclei''.

Energy Technology Data Exchange (ETDEWEB)

A device for detecting neutrons includes a semi-insulated bulk semiconductor substrate having opposed polished surfaces. A blocking Schottky contact comprised of a series of metals such as Ti, Pt, Au, Ge, Pd, and Ni is formed on a first polished surface of the semiconductor substrate, while a low resistivity ("ohmic") contact comprised of metals such as Au, Ge, and Ni is formed on a second, opposed polished surface of the substrate. In one embodiment, n-type low resistivity pinout contacts comprised of an Au/Ge based eutectic alloy or multi-layered Pd/Ge/Ti/Au are also formed on the opposed polished surfaces and in contact with the Schottky and ohmic contacts. Disposed on the Schottky contact is a neutron reactive film, or coating, for detecting neutrons. The coating is comprised of a hydrogen rich polymer, such as a polyolefin or paraffin; lithium or lithium fluoride; or a heavy metal fissionable material. By varying the ...

International Nuclear Information System (INIS)

Wood-plastic composites from Syrian tree species (white poplar, cypress tree, and white willow) were prepared using gamma-ray irradiation. Dry wood was impregnated with acrylamide or butylmethacrylate at various methanol compositions as the swelling solvent. Effect of inorganic additives and co-additives such as lithium nitrate (LiNO_3), copper sulfate (CuSO_4) and sulfuric acid (H_2SO_4), used at a very low concentration (1%), on the polymer loading (PL) and the compression strength (CS) was also investigated. It has been found that all the additives and co-additives, except Cu"2"+, increase the PL values and only Li"+ has a positive effect on CS. (Author)

Energy Technology Data Exchange (ETDEWEB)

A electrochemical cell is described comprising an anode, a cathode, a solid polymer electrolyte; and a redox shuttle additive to protect the cell against overcharging and a redox shuttle additive to protect the cell against overcharging selected from the group consisting of: (a) a substituted anisole having the general formula shown in a figure (in an uncharged state): where R{sub 1} is selected from the group consisting of H, 0CH{sub 3}, OCH{sub 2}CH{sub 3}, and OCH{sub 2}phenyl, and R{sub 2} is selected from the group consisting of OCH{sub 3}, OCH{sub 2}CH{sub 3}, OCH{sub 2} phenyl, and O{sup {minus}}Li{sup +}; and (b) a di-anisole compound having the general formula shown in a second figure (in an uncharged state): where R is selected from the group consisting of -OCH{sup 3} and -CH{sub 3}, m is either 1 or 0, n is either 1 or 0, and X is selected from the group consisting of -OCH{sub 3} (methoxy) or its lithium salt -O{sup {minus}}Li{sup ...

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

KoreaScience (Korea)

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J-STORE (Japan)

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Energy Technology Data Exchange (ETDEWEB)

Crystalline MnV{sub 2}O{sub 6} has been synthesized by a polymer gellation method and investigated for its physical and electrochemical properties as an anode material for Li secondary battery. The physical characterization was carried out by thermal analysis (TG/DTA), FT-IR and SEM. Structural analysis by powder XRD and spectroscopic analysis by XANES showed that the synthesized compound is MnV{sub 2}O{sub 6} with brannerite structure. The Li insertion of MnV{sub 2}O{sub 6} anode during the first charge showed a large capacity of about 1400 mAh/g, accompanied by irreversible structural transformation into amorphous material. Despite its structural transformation to amorphous during the first lithiation, subsequent cycles showed a capacity of about 800 mAh/g. This paper presents the advantage of this material over existing anode material and discusses the mechanism underlying the electrode process.

International Nuclear Information System (INIS)

An attempt is made to estimate the lithium reserve (the economically recoverable lithium) for the tritium breeding in D-T fusion reactors and other uses. Similar development patterns for fusion energy and fission energy are assumed to estimate the future lithium requirements. These requirements are grouped into three categories; the commercial uses, the lithium batteries for electric cars, and the fusion reactor uses. 5 refs.

Energy Technology Data Exchange (ETDEWEB)

The passivity and breakdown of passivity of 1018 carbon steel in propylene carbonate (PC) and 1,2-dimethoxyethane (DME) mixtures with 0.5 molar lithium hexafluoroarsenate supporting electrolyte were examined via several electrochemical and surface analytical methods. The PC-DME/0.5 M LiAsF{sub 6} mixtures ranged from 10 to 90 mol % PC. The results from the PC/DME mixtures were compared to passivating mechanisms found in pure PC and DME solutions. In PC-rich mixtures, the breakdown of passivity occurred near the oxidation potentials of either organic solvent. Premature breakdown of the carbon steel in PC-DME mixtures occurred at sulfide inclusions as was observed earlier in PC/0.5 M LiAsF{sub 6} solutions although passive films attempted to form at these inclusion sites in mixtures containing at least 10 mol % DME. As the DME content increased in the PC-DME mixtures, the passive films formed on bare steel surfaces possessed an increasing polymer ...

Energy Technology Data Exchange (ETDEWEB)

Lithium isotope separation by displacement chromatography is studied using fundamental principles; the equations are derived assuming theoretical stages in lithium adsorption bands. The concentration profiles in the band are calculated numerically under unsteady state.

Science.gov (United States)

The possibility of using lead or lead-bismuth mixed oxides as positive materials in organic electrolyte lithium cells with a working voltage similar to those of conventional systems (1.5 V) has been considered. Performances and main characteristics of this new class of lithium batteries are described.

British Library Electronic Table of Contents (United Kingdom)

Abstract:- The demand for Lithium-ion batteries as a major power source in portable electronic devices and vehicles is rapidly increasing. I use cumulative data of vehicle, mobile phone, laptop, and digital camera production to show that demand will overshoot the available global Lithium resources before 2025. Even if 100% of all Lithium-ion batteries were recycled today, recycling could not prevent this resource depletion in time. As the increasing Lithium scarcity will increase the price, it will be feasible to mine diluted resources with a strong environmental impact. I highlight these impacts in Lithium-rich Bolivia, the potential new -Saudi Arabia of Lithium.- Lithium extraction is likely to cause substantial water pollution, and-through impacts on native diversity-facilitate human he...

Energy Technology Data Exchange (ETDEWEB)

Observation of lithium lines in two halo stars could bring some information about /sup 7/Li abundance at the time of the formation of the galaxy.

KoreaScience (Korea)

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J-STORE (Japan)

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Energy Technology Data Exchange (ETDEWEB)

A piezoelectric biosensor substrate useful for immobilizing biomolecules in an oriented manner on the surface of a piezoelectric sensor has a ladder polymer of polyacrylonitrile. To make the substrate, a solution of an organic polymer, preferably polyacrylonitrile, is applied to the surface of a piezoelectric sensor. The organic polymer is modifying by heating the polymer in a controlled fashion in air such that a ladder polymer is produced which, in turn, forms the attachment point for the biomolecules comprising the piezoelectric biosensor. 3 figs.

Energy Technology Data Exchange (ETDEWEB)

The membrane transport of the two stable lithium isotopes, {sup 6}Li and {sup 7}Li, by erythrocytes has been studied using a dual channel atomic absorption spectroscopic technique. {sup 6}Li appears to be taken up preferentially to {sup 7}Li, in the ratio of 10 to 40%, depending on the concentration of total lithium and on the lithium isotopic ratio in the external medium.

British Library Electronic Table of Contents (United Kingdom)

There is strong interest in lithium imaging, particularly because of its significance in battery materials. However, light atoms only scatter electrons weakly and atomic resolution direct imaging of lithium has proven difficult. This paper explores theoretically the conditions under which lithium columns can be expected to be directly visible using annular bright field scanning transmission electron microscopy. A detailed discussion is given of the controllable parameters and the conditions most favourable for lithium imaging.

International Nuclear Information System (INIS)

In order to understand the physical processes concerned with the selective heating by ion cyclotron resonance and with the subsequent collection of heated particles, experiments were carried out with the extraction of lithium samples, enriched with "6Li isotopes. Probe and integral extractors allow to collect enriched Li at the end of the selective heating region. Surface density distribution on the collector and local isotopic content of lithium are measured, as a function of the screen height and the retarding potential. Dependence of the collected amount of lithium and of its isotopic content on the value of the magnetic field is also measured. 4 figs., 2 tabs., 5 refs.

Energy Technology Data Exchange (ETDEWEB)

The lithium battery, also called `lithium-carbon` or `lithium ion`, is today the most promising candidate that can reach the expected minimum traction performances of electric powered vehicles. Thanks to a more than 20 years experience on lithium generators and to a specific research program on lithium batteries, the SAFT company has developed a 100 Ah electrochemical system, and full-scale prototypes have been manufactured for this application. These prototypes use the Li{sub x}NiO{sub 2} lithiated graphite electrochemical pair and were tested in terms of their electrical performances. Energy characteristics of 125 Wh/kg and 265 Wh/dm{sup 3} could be obtained. The possibility of supplying a power greater than 200 W/kg, even at low temperature (-10 deg. C) has been demonstrated with these elements. A full battery set of about 20 kWh was built and its evaluation is in progress. It ...

Energy Technology Data Exchange (ETDEWEB)

Wood/polymer composites (WPC) have been prepared from pinewood with different compounds using gamma irradiation: butyl acrylate, butyl methacrylate, styrene, acrylamide, acrylonitrile, and unsaturated polyester styrene resin. The polymer loading was determined with respect to the compound concentration and the irradiation dose. The polymer loading increases generally with increase in the monomer or polymer concentration. Tensile and compression strength have been improved in the four cases, but no improvement was observed using unsaturated polyester styrene resin or acrylamide.

Energy Technology Data Exchange (ETDEWEB)

Our institute has been investigating laser-produced tin, lithium and xenon plasma for extreme ultraviolet (EUV) light source of EUV lithography system, and found the highest conversion efficiency of 3% at 13.5 nm in 2% bandwidth. In the present paper, we introduce fabrication methods of density-controlled tin targets to generate relatively monochromatic EUV, and higher conversion efficiency than bulk tin. The first method is the nano-template method, where liquid tin solution was immersed into a polymer film with monodispersed size nano-particle. The density can be controlled by tin concentration of the solution. The target can be classified into mass-limited target. We have shown a tendency of monochromatic EUV emission around 13.5 nm with decreasing of tin density. The intensity was higher than tin foil with bulk density. The tendency has a merit to mitigate heat effect of the first EUV mirror. The fabrication method has another merit to ...

Energy Technology Data Exchange (ETDEWEB)

The advent of light metal alloys and advanced materials (polymer, composites, etc.) have brought the possibility of achieving important energy reductions into the full life cycle of these materials, especially in transportation applications. 1 These materials have gained acceptance in the aerospace industry but use of light metal alloys needs to gain wider acceptance in other commercial transportation areas. Among the main reasons for the relatively low use of these materials are the lack of manufacturability, insufficient mechanical properties, and increased material costs due to processing inefficiencies. Considering the enormous potential energy savings associated with the use of light metal alloys and advanced materials in transportation, there is a need to identify R&D opportunities in the fields of materials fabrication and forming aimed at developing materials with high specific mechanical properties combined with energy efficient processes and good ...

Science.gov (United States)

Graphene nanosheets (GNSs) were synthesized and used as cathode active materials in a nonaqueous lithium-oxygen battery. The GNSs electrode delivered an extremely high discharge capacity in comparison to carbon powders, which is attributed to its unique morphology and structure. PMID:21779551

Energy Technology Data Exchange (ETDEWEB)

A test to determine the lithium compatibility and impurity gettering capabilities of various materials including yttrium was performed in Beryllium-7 Experimental Lithium (7BELL) at 270/sup 0/C. Yttrium coupons were exposed in liquid lithium for a total of 3,718 hours. X-ray diffraction and bulk chemical analysis data indicated that yttrium absorbs hydrogen from liquid lithium at 270/sup 0/C and transforms to yttrium dihydride (YH/sub 2/). The transformation of yttrium to YH/sub 2/ resulted in embrittlement of the coupons and subsequent fragmentation to small pieces. Additional analysis, based on the equilibrium hydrogen pressures for the transition of yttrium to YH/sub 2/, and Sievert's relationship for hydrogen in equilibrium with hydrogen in lithium, indicates that the temperature of yttrium cannot exceed 280/sup 0/C to control the hydrogen concentration in ...

Science.gov (United States)

... Title : Wear Rate and Friction Coefficient in Liquid Nitrogen and Hydrogen of Steel Sliding on Polymer Laminates (Various Fabrics and Polymers. ...

UK PubMed Central (United Kingdom)

Synthetic polymers and nanomaterials display selective phenotypic effects in cells and in the body that affect signal transduction mechanisms involved in inflammation, differentiation, proliferation,...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Advanced lithium batteries presently under development operate either at the high temperatures associated with the LiCl-KCl molten salt (350-450/degree/C), or at ambient temperatures employing organic solvent based electrolytes. An intermediate temperature lithium battery is proposed as an alternative if it reduces corrosion problems present at high temperatures and improved kinetic performance with respect to ambient temperature cells. 17 refs.

Energy Technology Data Exchange (ETDEWEB)

Certain transition metal chalcogenides are promising materials for use as cathodes in nonaqueous lithium batteries involving the intercalation into these layered compounds. The electrochemical behavior of the chalcogenides depends on various properties such as structure, stoichiometry, electrical conductivity, crystal morphology, etc. The influence of these properties and of the ultimate practical application of the battery on the selection of cathode material is discussed. Battery performance of selected cathode materials is discussed and life limitations due to the limited cycle life of lithium anodes are outlined. 15 refs.

Energy Technology Data Exchange (ETDEWEB)

In order to get the separation of natural isotopes of lithium by electrolytic amalgamation, an electrolytic cell with a confined mercury cathode was used to obtain data for the design of a separation stage. The initial work was followed by the design of a moving mercury cathode electrolytic cell and three experiments with six batches stages were performed for the determination of the elementary separation factor. The value obtained, 1.053, was ill agreement: with the specialized literature. It was verified in all experiments that the lithium - 6 isotope concentrated in the amalgam phase and that the lithium - 7 isotope concentrated in the aqueous phase. A stainless-steel cathode for the decomposition of the lithium amalgam and the selective desamalgamation were also studied. In view of the results obtained, a five stages continuous scheme was proposed. (author)

British Library Electronic Table of Contents (United Kingdom)

Previously, we demonstrated that the lithium ion conduction in the perovskite-type manganese fluoride is attributed to counter cation-site vacancy mechanism. The divalent counter cation-doped KxBa(1-x)/2MnF3 was theoretically predicted as the lithium ion conductor in the perovskite-type manganese fluoride. In this study, we considered the oxygen doping for KxBa(1-x)/2MnF3 to realize the higher lithium ion conductivity. It is because lithium ion forms the stronger ionic bond with the doped oxygen anion. The hybrid-DFT calculations were performed to investigate the lithium ion conduction in the oxygen-doped KxBa(1-x)/2MnF3. The calculation results were discussed from the viewpoints of the potential energy curve, electron densities, and charge and spin densities. The effect of the lithium ion...

Energy Technology Data Exchange (ETDEWEB)

Information is given on the theoretical principles underlying the technology of producing fibrous plastics and wood slabs. An examination is made of the most important characteristics of the physics and chemistry of polymers, and the properties of synthetic polymers used in the wood processing industry. A description is given of the chemical composition and properties of wood and its components as well as of synthetic polymers made of cellulose. The book is designed for students of technical schools of the wood and pulp processing industry. 7 references, 14 figures, 1 table.

Energy Technology Data Exchange (ETDEWEB)

A quantitative description is proposed for the depletion-induced slip thickness and velocity profile of a polymer solution near the wall-fluid interface in simple shear flow. The inhomogeneous polymer density profile at a flat wall is inserted into the equations of motion for the flow of a polymer solution near the flat wall. The theory is in quantitative agreement with simulation results. (letter to the editor)

International Nuclear Information System (INIS)

... compounds polymers polyolefins polyvinyls radiation effects SYNTHESIS.

Science.gov (United States)

... Descriptors : *POLYMERS, *BINDERS, *HOWITZERS, *COMBUSTIBLE CARTRIDGE CASES, CHEMICAL COMPOSITION, PROPELLING ...

International Nuclear Information System (INIS)

The thermal properties of five types of radiation-induced wood-polymer composites based on a tropical hardwood, rubberwood (Hevea braziliensis), was studied by oxygen index measurement, differential thermal analysis (DTA) and thermogravimetry (TG). The DTA and TG curves of composites were different from those of rubberwood, which can be attributed to the presence of the incorporated polymers. Of the five composites, the one impregnated with bis(2-chloroethyl)vinyl phosphonate reduced the initial temperature of decomposition, increased the peak temperatures of exothermic reactions, and increased the char yield. Comparison with physical blends of rubberwood and the corresponding polymer provided some evidence of chemical interaction of wood and polymer in some of the composites. (author).

International Nuclear Information System (INIS)

Polymerizing effects of high energy radiation has been found suitable for preparation of wood-polymer composites. In the present work after evaluating polymer products that have been obtained by irradiation method, wood-polymer composites have been prepared by in situ polymerization of vinyl acetate, acrylic acid and acrylic acid/styrene mixture using two samples of Iranian hardwoods, Beech and Hornbeam. These woods and their composites have been tested for their physical and mechanical properties. The results have shown that chemical bonding between polymer and the cell wall component lead to better strength properties in the composites. (author).

International Nuclear Information System (INIS)

A wood/polymer composite was produced by impregnating Ramin wood with methyl methacrylate monomer and subsequently polymerizing it by gamma irradiation. To assess the improvement in compression strength of the wood caused by the polymer impregnation, a microbuckling compression failure mechanism was used to model the compression failure of the composite. Such a mechanism was found to predict a linear relationship between the compression strength and the percentage polymer impregnation (by weight). Uniaxial compression test results at 45(#+-#5)% and 90(#+-#5)% relative humidity levels, after being statistically analysed, showed that such a linear relationship was valid for up to 100% polymer impregnation. (author).

Energy Technology Data Exchange (ETDEWEB)

Characteristics of pressure drop and heat transfer have been investigated for a lithium single-phase flow and a helium-lithium two-phase flow in a horizontal conducting circular channel in the presence of a uniform transverse magnetic field up to 1.4 T as related to the lithium cooling for magnetic-confinement fusion reactors. By the application of the magnetic field to the lithium single-phase flow, remarkable heat transfer enhancement has been observed at the top wall due to the suppression of the mixed convection occurring in the low Peclet number range, while appreciable heat transfer deterioration appeared in the high Peclet number range. It has been confirmed that the helium-lithium two-phase flow can reduce the high magnetohydrodynamic (MHD) pressure drop in a lithium single-phase flow, and it can provide much better heat transfer performance than that in ...

Energy Technology Data Exchange (ETDEWEB)

the development of lithium metal batteries is hindered by the bad reversibility of the Li{sup +}/Li pair, due to dendrites formation which limits the amount of active matter and can generate short-circuits. The chemical and electrochemical phenomena which take place at the electrode/organic electrolyte interface lead to the formation of a complex passivation film which is of prime importance for the functioning of this type of batteries. The in-situ infrared reflection spectroscopy is well adapted to the chemical study of the passivation layer. Two different techniques were used: the substraction normalized interfacial transform infrared spectroscopy (SNIFTIRS) and the electro-chemically modulated infrared reflectance spectroscopy. These methods have shown that the passivation layer that develops on the surface of the lithium electrode in contact with organic solutions (propylene carbonate, ethylene carbonate and dimethoxyethane) is mainly made ...

Energy Technology Data Exchange (ETDEWEB)

A weak shift of the isotope concentration ratio Li{sup 6}/Li{sup 7} was measured in the coexisting phases of the miscibility gap of lithium-ammonia solutions. Li{sup 6} is slightly enriched in the concentrated metallic phase (enrichment factor {alpha} = 1.009 {+-} 0.002). This effect can be enhanced in a counter-current column to yield any desired enrichment of the two isotopes. The counter current system and its operation were tested succesfully with a sodium-potassium-ammonia solution.

Energy Technology Data Exchange (ETDEWEB)

This paper presents a prototype of an entirely inorganic lithium ions battery cell. LiCoO{sub 2} thin film cathodes and Li{sub 4/3}Ti{sub 5/3}O{sub 4} thin film anodes have been deposited on Li{sub 3x}La{sub 2/3-x}TiO{sub 3} sintered solid electrolyte pellets and the performances of these battery cells have been tested. (J.S.) 5 refs.

Energy Technology Data Exchange (ETDEWEB)

Differences in the biological disposition and in the effects of the stable lithium isotopes, Li-6 and Li-7, in animals were characterized. A somewhat higher toxicity was associated with WLiCl compared to XLiCl with NLiCl intermediate. All lithium treatments increased water intake and resulted in weight gain. Peak plasma concentration was slightly high for 6Li than 7LiCl suppressed action potential amplitudes during tetanic stimulation more than NaCl when added to Renger solution bathing ganglia.

Energy Technology Data Exchange (ETDEWEB)

Electrochemical techniques have been used to study the reversible insertion of sodium into hard-carbon host structures at room temperature. In this paper the authors compare these results with those for lithium insertion in the same materials and demonstrate the presence of similar alkali metal insertion mechanisms in both cases. Despite the gravimetric capacities being lower for sodium than lithium insertion, the authors achieved a reversible sodium capacity of 300 mAh/g, close to that for lithium insertion in graphitic carbon anode materials. Such materials may therefore be useful as anodes in rechargeable sodium-ion batteries.

British Library Electronic Table of Contents (United Kingdom)

In this paper we describe a Ni-Sn intermetallic material obtained via template electroplating synthesis. The structure and the morphology of this material are investigated by X ray diffraction (XRD) and Scanning Electron Microscopy (SEM) analyses. We demonstrate that Ni-Sn behaves as a sub-micrometric electrode showing a favourable response when cycled in a lithium cell. The results here reported suggest that the template electroplating is a promising synthetic approach that can lead to an optimized structure and morphology of the Ni-Sn electrode, such as to confer it a role of a high capacity anode in advanced lithium ion batteries.

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...Polymer Fuel Cells Challenge Publications News Events Login Register Search Content type All Web pages Case studies Publications News Video Home ...Buildings Carbon capture & storage Combined heat & power Electricity transmission & distribution Energy storage Fuel cells Geothermal Hydroelectric Hydrogen Industry Lighting Marine Metering Nuclear Solar Transport Wind ...Home Emerging technologies Current focus areas Polymer Fuel Cell Challenge Polymer Fuel Cells Challenge The objective of the Polymer Fuel Cells Challenge is to develop,...prove and commercialise novel polymer fuel cell technologies that have the potential to deliver a step-change in overall system cost. What are ...

Energy Technology Data Exchange (ETDEWEB)

Lithium (Li) plating-stripping reaction properties at the lithium phosphorus oxynitride glass electrolyte (LiPON)/copper thin film (Cu) interface is improved by the insertion of nano-thickness platinum (Pt) layer at the interface. The LiPON films are formed on mirror-polished lithium-ion conductive solid electrolyte sheets, and current collector thin films of Li, Cu-Pt multi layer, and Cu are formed on the LiPON films. The plating-stripping reactions at the LiPON/current collector films interface are carried out by galvanostatic and potential sweep measurements. Galvanostatic measurements reveal that Pt layer insertion reduces the overvoltage of the reaction and improves its coulomb efficiency. Also, cyclic voltammetry measurement suggests formation of Li-Pt alloys at higher voltages than 0 V (vs. Li/Li{sup +}) during the lithium plating process. Scanning electron microscopy observation clarifies that ...

British Library Electronic Table of Contents (United Kingdom)

Porous SnO2 nanotubes were prepared via electrospinning followed by calcination in air. As anode materials for lithium ion batteries, the porous nanotubes delivered a high discharge capacity of 807mAhg^-^1 after 50cycles. Even after cycled at high rates, the electrode still retained a high fraction of its theoretical capacity. Such excellent performances of porous SnO2 nanotubes could be attributed to the porous and hollow structure which facilitated liquid electrolyte diffusion into the bulk materials and buffered large volume changes during lithium ions insertion/extraction. Furthermore, the nanoparticles of nanotubes provided the shorter diffusion length for lithium ions insertion which benefited in retaining the structural stability and good rate performance. Our results demonstrated t...

Energy Technology Data Exchange (ETDEWEB)

We present a laser spectroscopic approach for measuring the charge radius of the halo nucleus {sup 11}Li and report on recent progress in the development of the experimental apparatus.

UK PubMed Central (United Kingdom)

Tropomyosin (Tm) is a conserved dimeric coiled-coil protein, which forms polymers that curl around actin filaments in order to regulate actomyosin function. Acetylation of the Tm N-terminal...Full Text Available

UK PubMed Central (United Kingdom)

This neutron reflectometry study evaluates the structures resulting from different methods of preparing polymer-cushioned lipid bilayers. Four different techniques to deposit a dimyristoylphosphatidylcholine...Full Text Available

UK PubMed Central (United Kingdom)

Hydrogen cyanide polymerizes readily under a variety of conditions and significant prebiotic roles have been suggested for these polymers due to the abundance of HCN in universe. However, the structures...Full Text Available

International Nuclear Information System (INIS)

This investigation clearly demonstrates that through partial impregnation techniques wood-polymer composites can be formed from the Pinus species grown in South Africa with a considerable saving in monomer costs without sacrificing the important physical properties of these materials.

Science.gov (United States)

Commercial introduction of new polymer materials for use as the electrolyte in solid tantalum and solid aluminum electrolytic capacitors is underway. ...

Science.gov (United States)

Demand for compact instrumentation, portable field equipment, and new electromagnetic weapons is

Energy Technology Data Exchange (ETDEWEB)

The chemistries of reactants, plasticizers, solvents and additives in an epoxy paint are discussed. Polyamide additives may play an important role in the absorption of molecular iodine by epoxy paints. It is recommended that the unsaturation of the polyamide additive in the epoxy cure be determined. Experimental studies of water absorption by epoxy resins are discussed. These studies show that absorption can disrupt hydrogen bonds among segments of the polymers and cause swelling of the polymer. The water absorption increases the diffusion coefficient of water within the polymer. Permanent damage to the polymer can result if water causes hydrolysis of ether linkages. Water desorption studies are recommended to ascertain how water absorption affects epoxy paint.

KoreaScience (Korea)

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British Library Electronic Table of Contents (United Kingdom)

The concentrates of scattered organic matter???kerogen-like polymer, which is insoluble in acids and organic solvents???were isolated from rock samples taken at different depths from various stratigraphic units at the productive deposits of the Orenburg oil-gas condensate field using chemical methods. The chemical composition of the kerogen-like polymer and the concentrations of trace elements in it were studied. The regularities of evolutionary changes in the composition of the organic matter and the concentrations of trace elements in it in the order of the kerogen-like polymer and the following its consecutive derivatives were established: asphaltenes, ethanol-benzene tars, benzene tars, oils, and paraffins

Science.gov (United States)

... polypropylene, polylactic acid and polyvinyl chloride to form wood plastic composites (WPC). WPCs have seen a large growth in ... ...

Energy Technology Data Exchange (ETDEWEB)

This invention relates to a water soluble polymer and method for its preparation. The water soluble polymer exhibits superior thermal stability characteristics when used as an additive in aqueous drilling fluids. The polymer consists of a major portion of a catechol based monomer and a dicarboxylic acid. Other monomers and materials are added to enhance the functional characteristics of the drilling fluid additive. The method of this invention includes the mixing of monomers, polymerization of that mixture and optionally the steps of hydrolysis and sulfonation.

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Threshold pump intensity values leading to irreversible damage to colored laser elements based on elastic polymers were measured. The damage to colored elastomers is connected with absorbing microinclusions but is independent of molecular absorption. It is shown that damage to the elastomers has a pronounced threshold character in contrast to the microdamage accumulation effect in glassy polymers. The damage threshold for elastomers is 1.5 times higher, which is connected with the absence of microstresses (characteristics for organic glasses) in the specimens. 13 references.

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It is shown that observations of the lithium isotope ratio in high surface temperature Population II stars may be critical to cosmological nucleosynthesis models. In particular, decaying particle scenarios as derived in some supersymmetric models may stand or fall with such observations. 18 references.

Energy Technology Data Exchange (ETDEWEB)

Calculations of total and angle-differential excitation cross sections for the electron impact excitation of lithium-like iron were performed with the R-matrix formulation. The alignments of the excited states 1s{sup 2}np {sup 2}P{sub 3/2} are also presented for n=3 and 4 along with the angular photon distribution from these states to the ground state. Relativistic effects were included in the present calculations by the Breit-Pauli Hamiltonian.

International Nuclear Information System (INIS)

In a cold fusion method by electrolysis, a hydrogen occluding material mainly comprising vanadium is used as a material for a negative electrode, and lithium isotopes are incorporated in the material by more than 93%. That is, the ratio of lithium 7 ("7Li) isotope is increased to higher than the natural existent ratio, so that tritium ("3H) concentration in the hydrogen occluding material can be increased, to attain energy at high efficiency. (T.M.).

Energy Technology Data Exchange (ETDEWEB)

A method for quick, high-accuracy measurement of lithium isotopes has become necessary in carrying out research on the separation and concentration of lithium isotopes by ion exchange. The present report focuses on the application of a hollow cathode, as excitation source, to emission spectral analysis for lithium isotope measurement. The grating monochromator used incorporates a pressure scanned etalon. With decreased Doppler broadening and pressure broadening, the hollow cathode, used as excitation source, can give narrow spectral lines, permitting good separation among them. To achieve a high accuracy, the emission intensity of the hollow cathode should be maintained as stable as possible relative to time. In particular, the stability of a light source can be affected significantly by the chemical form of the sample. A study is also made here to identify a condition where lithium acetate effluent ...

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An electrolyte for high voltage lithium metal anode cells must simultaneously satisfy at least the following requirements; (i) high cycling efficiency on the lithium metal anode; (ii) higher oxidation potential than the charging voltage, and (iii) high specific conductivity. We have examined various electrolytes for lithium metal anode cells using a high voltage cathode, LiMn{sub 1.9}Co{sub 0.1}O{sub 4}. Of the electrolytes resistant to high voltage that we used, a system containing 60 to 90 vol.% of dimethyl carbonate (DMC) mixed with ethylene carbonate (EC) and 1.0 M lithium hexafluorophosphate (LiPF{sub 6}) provided the best cycling efficiency on a lithium metal anode, as well as a high specific conductivity around 10 mS cm{sup -1} at 20 C. (orig.)

Energy Technology Data Exchange (ETDEWEB)

This is the final report of a three-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The primary aim of this project is to obtain a basic scientific understanding of electrical transport processes at interfaces that contain an organic electronic material. Because of their processing advantages and the tunability of their electronic properties, organic electronic materials are revolutionizing major technological areas such as information display. We completed an investigation of the fundamental electronic excitation energies in the prototype conjugated polymer MEH-PPV. We completed a combined theoretical/experimental study of the energy relation between charged excitations in a conjugated polymer and the metal at a polymer/metal interface. We developed a theoretical model that explains injection currents at polymer/metal interfaces. We have made ...

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Step-scan Fourier transform infrared spectroscopy in conjunction with impulse stress on polymer films has been used to monitor dynamic rheological responses in real time. A novel piezo-electrically-driven polymer microrheometer was employed to apply repetitive impulses to the polymer sample while time-domain spectra were recorded. Recent results include the study of both semi-crystalline polymers such as isotactic polypropylene (iPP) and elastomers such as Estane polyester/polyurethane copolymer and Kraton tri-block copolymer. The spectral changes of iPP are consistent with frequency-domain results. For iPP at room temperature, large differences in the response times of different absorption bands are not seen. However, the orientation response of the CH{sub 3} rocking mode is slightly slower than the responses of the backbone modes. To the authors` knowledge, this is the first reported successful ...

International Nuclear Information System (INIS)

Complimentary spectroscopic, microscopic and electrochemical studies were performed to characterise the barrier properties as well as the interface structure of model iron substrates covered with thin plasma polymer films. Cathodic plasma polymers were deposited which show high barrier properties. The metal surface was pre-treated by a reducing or oxidising plasma. This allowed the adjustment of the oxidation state of the interface layer. The interface structure was characterised by means of X-ray photoelectron sputter profiles, infrared spectroscopy and the application of a Kelvin probe. The investigations show that the measured Voltapotential on the plasma polymer surface can be correlated with the oxidation state of the interface. Reducing plasmas lead to an almost oxide free surface. After deposition of the plasma polymer, this reduced state of the oxide is sensitive to re-oxidation of the interface ...

Energy Technology Data Exchange (ETDEWEB)

The new generation of performing rechargeable lithium-ion batteries (``rocking-chair``-type) are penalized by important self-output phenomena linked with the use of highly oxidizing positive electrodes. In order to limit this problem in LiMn{sub 2}O{sub 4}/C batteries, two different passivation techniques were used in order to limit the surface contact between the positive electrode and the electrolyte. Thanks to these treatments, a significant reduction of the percentage of irreversible capacity losses is effectively observed. (J.S.) 3 refs.

British Library Electronic Table of Contents (United Kingdom)

SnO2/graphene nanocomposites have been fabricated by a simple chemical method. In the fabrication process, the control of surface charge causes echinoid-like SnO2 nanoparticles to be formed and uniformly decorated on the graphene. The electrostatic attraction between a graphene nanosheet (GNS) and the echinoid-like SnO2 particles under controlled pH creates a unique nanostructure in which extremely small SnO2 particles are uniformly dispersed on the GNS. The SnO2/graphene nanocomposite has been shown to perform as a high capacity anode with good cycling behavior in lithium rechargeable batteries. The anode retained a reversible capacity of 634 mA?h?g?1 with a coulombic efficiency of 98% after 50 cycles. The high reversibility can be attributed to the mechanical buffering by the GNS against...

International Nuclear Information System (INIS)

A high-precision Li isotope analysis was developed for determining the Li"+ ion emitted from lithium phosphate as an ion source material by a Re double-filament ionization method in the thermal ionization mass spectrometry. In this method, Li isotopic fractionation is distinctly less sensitive to the filament temperature than those in the previous methods, and stable and high ion beam intensity of more than 8 x 10"-"1"1 A for "7Li is obtained. These advantages in determining the "7Li/"6Li ratio result in the analytical reproducibility of 0.26 per mille (1#sigma#). Furthermore, the sample preparation is simple and the low temperature (850degC) required by this method ensures the analysis of the isotopic composition of small amounts of Li with less influence of Li contamination to the sample, compared with the previous methods. (author).

Energy Technology Data Exchange (ETDEWEB)

We report synthesis, characterization and ion transport in polyether-based ionic melt electrolytes consisting of Li salts of low-basicity anions covalently attached to polyether oligomers. Purity of the materials was investigated by HPLC analysis and electrospray ionization mass spectrometry. The highest ionic conductivity of 7.1 x 10{sup -6} S/cm at 30 deg. C was obtained for the sample consisting of a lithium salt of an arylfluorosulfonimide anion attached to a polyether oligomer with an ethyleneoxide (EO) to lithium ratio of 12. The conductivity order of various ionic melts having different polyether chain lengths suggests that at higher EO:Li ratios the conductivity of the electrolytes at room temperature is determined in part by the amount of crystallization of the polyether portion of the ionic melt.

Energy Technology Data Exchange (ETDEWEB)

The incorporation of additives designed to sacrificially react on the surface of cathode materials of lithium ion batteries has been investigated. Addition of low concentrations of inorganic additives including lithium bisoxalatoborate (LiBOB), lithium difluorooxalatoborate (LiBF{sub 2}(C{sub 2}O{sub 4})), and tetramethoxy titanium (TMTi) to 1 M LiPF{sub 6} in 1:1:1 EC/DEC/DMC improves the capacity retention of Li/Li{sub 1.17}Mn{sub 0.58}Ni{sub 0.25}O{sub 2} cells cycled to 4.9 V vs. Li. Surface analysis of the cathode materials (XPS and IR) suggests that structure of the cathode surface film is modified by the presence of the additives resulting in a decrease in detrimental electrolyte oxidation reactions on the cathode surface. (author)

Energy Technology Data Exchange (ETDEWEB)

It is well known that a protective film is formed on the graphite negative electrode in ethylene carbonate (EC) electrolyte solution. This film is lithium-ion conductive and protects the decomposition of the electrolyte solution. In the present paper, the electrode/electrolyte interfaces in lithium-ion rechargeable batteries were characterized by three-dimensional complex impedance plots, whose axes are real, imaginary parts and time. The film resistance R {sub sei} and charge transfer resistance R {sub ct} were determined for negative electrodes in EC/ethyl methyl carbonate (EMC) electrolyte solution, and the formation mechanisms of the interfacial film were discussed. Furthermore, the contributions of vinylene carbonate and ethylene sulfite, which are added into the electrolyte solution for the film formation, were investigated.

Energy Technology Data Exchange (ETDEWEB)

Cathode materials for rechargeable rocking chair or lithium-ion batteries, are reviewed. The emphasis is placed on the comparison between specific capacities and rechargeability of lithium-containing high voltage cathode materials such as manganese oxides and LiMO{sub 2} compounds, where M is Co or Ni. It is generally found that the maximum reversible capacities for the most promising materials fall in the range 100-120 mAh/g, and decaying to around 75 mAh/g after several hundred cycles. The rechargeability is similar for the most commonly considered materials: LiMn{sub 2}O{sub 4}, LiCoO{sub 2} and LiNiO{sub 2}. No improvements in capacity or rechargeability, beyond what have been found for these materials, is observed by substitution of other elements into these compounds

Energy Technology Data Exchange (ETDEWEB)

During past two decades, the importance of rechargeable lithium cells has been emphasized and a large variety of materials has been discovered and evaluated for use as reversible cathodes and electrolytes. Materials that undergo intercalation or topochemical reactions with lithium have been investigated as candidates for cathodes in nonaqueous secondary lithium cells (1). Recent interest in researching cathode active materials has mainly focussed on crystalline transition metal chalcogenides. On the other hand, electrochemical behaviors of several amorphous materials have been reported, for example MoS/sub 2/,MoS/sub 3/,V/sub 2/S/sub 5/ (2) and LiV/sub 3/O/sub 8/ (3). However, no successful cycling behavior has been obtained except for MoS/sub 2/ in the amorphous state. This paper reports electrochemical data on rechargeable vanadate glasses in the system V/sub 2/O/sub 5/-P/sub 2/O/sub 5/.

Energy Technology Data Exchange (ETDEWEB)

A novel process was proposed to synthesize nano Sb-encapsulated pyrolytic polyacrylonitrile composite for anode material in lithium secondary batteries. The preparation started with the dissolution of SbCl{sub 3} and polyacrylonitrile (PAN) in dimethylformamide (DMF) solution, followed by the addition of KBH{sub 4} to reduce Sb{sup 3+} in the solution. The Sb composite was obtained by pyrolysis of the Sb/PAN mixture that precipitated out when the DMF solution was added by plentiful water. The TEM analysis showed that about 100-200 nm Sb particles were embedded by the pyrolyzed PAN, which provided a conductive matrix to relieve the morphological change of Sb during electrochemical cycling. As-prepared composite presented good cycleability for lithium storage. The proposed process paves an effective way to prepare high performance alloy based composite anode materials for high performance lithium-ion batteries. (author)

Energy Technology Data Exchange (ETDEWEB)

Recently, the lithium ion-conductive solid electrolyte draws attention because there is a possibility of producing the maintenance-free battery which is characterized by having such advantages as high energy density and no possibility of electrolyte leak because of solid state structure. The invented lithium ion-conductive solid electrolyte is formed by sintering the granular electrolyte expressed in the following general formula: Li(1+(4-n)x)MxTi(2-x)(PO4)3 (M = mono- or di-valent cation, x = 0.1 - 0.5). Examples of the monovalent cation are Na[sup +], K[sup +], Rb[sup +], Cs[sup +], and Cu[sup +]. Examples of divalent cation are Mg[sup 2+], Fe[sup 2+], Be[sup 2+], Ca[sup 2+], Sr[sup 2+], Ba[sup 2+], Ra[sup 2+], Mn[sup 2+], Co[sup 2+], Cu[sup 2+], Ni[sup 2+], Zn[sup 2+], and Cd[sup 2+]. The electric conductivity of lithium ion is increased with the increase in the content of Li[sup +] in the electrolyte. 4 figs.

UK PubMed Central (United Kingdom)

Two xyloglucan fractions have been isolated from the cotyledons of resting white-mustard seeds, the first by extraction with hot EDTA, and the second by subsequent extraction with alkali or lithium...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

A combination of degenerate four-wave mixing spectroscopy and a low-pressure sampling technique has been studied for isotopic analysis in an air-acetylene flame. Hyperfine spectra of D lines of sodium and several mixtures of lithium isotopes obtained in this way are presented.

Energy Technology Data Exchange (ETDEWEB)

Carbons derived from the phase separation of polyacrylonitrile/solvent mixtures were investigated as lithium intercalation anodes for rechargeable lithium-ion batteries. The carbon electrodes have a bulk density of 0.35-0.5 g/cm{sup 3}, relatively low surface areas (< 10 m{sup 2}/g), and micron-size cells. Pyrolysis temperature influences the reversible lithium intercalation and the irreversible capacity (associated with the formation of the passivating layer). Carbon electrodes pyrolyzed at 600{degrees}C have first-cycle capacity as high as 550 mAh/g as well as large irreversible capacity, 440 mAh/g. Electrodes prepared at 1050{degrees}C have reversible capacities around 270 mAh/g with relatively lower capacity losses (120 mAh/g). Doping the organic precursors with phosphoric acid, prior to pyrolysis at 1050{degrees}C, leads to carbon electrodes with reversible capacities as high as 450 mAh/g. The capacity of doped ...

UK PubMed Central (United Kingdom)

BackgroundThe mammalian FoxO transcription factors function to regulate diverse physiological processes. Emerging evidence that both BDNF and lithium suppress FoxO...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

This document, Part 2 of Volume 2, provides appendices to this report and includes the following technologies, zinc/air battery; lithium/molybdenum disulfide battery; sodium/sulfur battery; nickel/cadmium battery; nickel/iron battery; iron/oxygen battery and iron/air battery. (FI)

International Nuclear Information System (INIS)

Calculations in "7Li have been carried out for the differential coherent elastic scattering cross-section of thermal neutrons at a fixed scattering angle #theta#_0(148"o) and varying the energy of incident neutrons (or corresponding d-spacings). The results are reported, as variations of the ratio #SIGMA#_0"c"o"h (#theta#_0, d)/#SIGMA#_0"c"o"h (#theta#_0) with d-spacing, at atmospheric pressure and at two temperatures, 80 and 20 K. The calculations at 80 K correspond to BCC lithium whereas at 20 K all the possible crystallographic structures of polytype lithium (BCC, 9R, HCP and FCC) were considered. On comparing our results with the time-of-flight (TOF) measurements of Berliner et al. (Physical Review, B40, 12086, 1989) we find that up to 80 K lithium-7 does not undergo any martenistic transformation whereas the structural state at 20 K can be described by the co-existence of the original BCC phase with 9R, HCP and FCC ...

Energy Technology Data Exchange (ETDEWEB)

An ever first attempt has been made to investigate the possible anode performance characteristics of LiFePO{sub 4}, popularly known so far as an environmentally compatible and economically viable lithium battery cathode material. The compound LiFePO{sub 4} has been synthesized via solid state method and explored for the first time as an anode material against lithium metal through the present study. Surprisingly, an initial capacity of circa 620 mAh/g has been exhibited by LiFePO{sub 4} anode, which is about 4-5 times higher than the capacity of the corresponding LiFePO{sub 4} cathodes. Also an excellent coulombic efficiency value of 99% has been shown by the compound, especially upon extended cycling. The extraordinarily higher specific capacity values of LiFePO{sub 4} anodes may be exploited suitably for practical lithium battery applications.

Energy Technology Data Exchange (ETDEWEB)

This invention pertains to passivation-free solid-state rechargeable batteries composed of Li.sub.4 Ti.sub.5 O.sub.12 anode, a solid polymer electrolyte and a high voltage cathode. The solid polymer electrolyte comprises a polymer host, such as polyacrylonitrile, poly(vinyl chloride), poly(vinyl sulfone), and poly(vinylidene fluoride), plasticized by a solution of a Li salt in an organic solvent. The high voltage cathode includes LiMn.sub.2 O.sub.4, LiCoO.sub.2, LiNiO.sub.2 and LiV.sub.2 O.sub.5 and their derivatives.

Energy Technology Data Exchange (ETDEWEB)

Researchers are developing polymer-based coating systems to reduce scaling and corrosion of air-cooled condensers that use a geothermal fluid spray for heat transfer augmentation. These coating systems act as barriers to corrosion to protect aluminum fins and steel tubing; they are formulated to resist the strong attachment of scale. Field tests have been done to determine the corrosion and scaling issues related to brine spraying and a promising organometallic polymer has been evaluated in salt spray tests.

Energy Technology Data Exchange (ETDEWEB)

Fractal dimensional analysis was employed to obtain a quantitative measure of the morphology of polymer networks formed by UV irradiation induced polymerization of photo-reactive mesogenic monomers dissolved in a liquid crystal host medium. The fractal dimensions obtained, may be interpreted by polymer network growth following a percolation-like model for monomer concentrations well below the solubility limit. On passing the solubility limit, the polymerization process changes from a (radical chain) solution polymerization to a dispersion polymerization, with fractal dimensions decreasing and suggesting a cluster-cluster aggregation process for monomer concentrations above the solubility limit, similar to the aggregation of colloidal particles.

International Nuclear Information System (INIS)

The effect of additives on the grafting of a monomer, butylmethacrylate (BA), into simul (a soft wood) has been studied using "6"0Co source at 3 Mrad. The enhancement of polymer loading (grafting) by the addition of minute amounts (1%) of oligomers and of polyfunctional monomers into simul + BA system has been further increased in the presence of acid and urea. The synergistic polymer loading yields by acid addition cause substantial decrease of tensile strength values of wood-plastic composite; but urea increases both polymer loading and tensile strength values synergistically in these systems. (author).

International Nuclear Information System (INIS)

Separation of lithium isotope by NTOE compound was carried out with 0.01M HCl solution. The ion exchange capacity of NTOE was 0.8 meq/g. The separation factor, #alpha#=("7Li/"6Li)_s_o_l_i_d/("7Li/"6Li)_l_i_q_u_i_d was 1.0242 by the elution chromatography. The lighter isotope, "6Li was concentrated in the liquid phase, while the heavior isotope, "7Li was enriched in the solid phase. (author).

Science.gov (United States)

The possibility of using lead and lead-bismuth mixed oxides as positive active materials in organic electrolyte lithium cells with a working voltage similar to those of silver zinc cells has been considered. Button cells of SR 44 size have been developed as a test vehicle and studied under various conditions of discharge rate and storage. This paper describes the performance characteristics obtained under these conditions and suggests in conclusion the possible replacement of silver zinc cells by such systems for a large range of low-rate applications on the basis of cost effectiveness.

Energy Technology Data Exchange (ETDEWEB)

The effects of temperature and the use of macroreticular resins were studied in lithium isotope separation by an ion-exchange method. The isotope separation factors obtained decreased by increasing the temperature, and the factors for macroreticular resins were identical with those for the usual gel-type resins. However, the performance of isotope separation per unit band length in displacement chromatography was found to be improved by increasing the temperature and using macroreticular resins, because accelerating the interphase mass transfer caused the reduction of HETP (Height Equivalent to a Theoretical Plate).

Energy Technology Data Exchange (ETDEWEB)

Excitation transfer between the 3S[sub 1/2] states of the lithium isotopes [sup 6]Li and [sup 7]Li is measured in a thermionic diode. The 3S level is excited by off-resonant two-photon transitions with a single mode cw laser. The relative densities of the directly excited and collisionally populated levels are probed by further laser excitation to the 12P levels. An energy transfer cross section of 585 A[sup 2] [+-] 160 A[sup 2] is found at the experimental temperature of about 850 K. A simple semiclassical calculation yields a cross section of 450 A[sup 2]. (orig.)

UK PubMed Central (United Kingdom)

Axon outgrowth and guidance to the proper target requires the coordination of filamentous (F)-actin and microtubules (MTs), the dynamic cytoskeletal polymers that promote shape change and locomotion....Full Text Available

UK PubMed Central (United Kingdom)

The rejection thresholds of Phormia regina Meigen for twenty-four glycols have been determined. A definite relationship between the concentration of the test material and the distribution...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The research carried out in Canada in the design of containers for the disposal of radioactive waste has focussed on spent nuclear fuel, even though the quantities of other currently stored radioactive wastes are substantially greater. Research carried out at the Royal Military College of Canada on the effects of mixed fields of radiation on high polymer adhesives and composite materials has shown that some polymers are quite resistant to radiation and could well serve in the fabrication of radioactive waste disposal containers. The purpose of this research was to determine if thermoplastic polymers could be used as superior materials to replace metals in the application of low and intermediate level radioactive waste disposal containers. Polymers have the advantage that they do not corrode like metals. The experimental methods, used in this research, focused on the effects of radiation on the ...

Science.gov (United States)

... Accession Number : ADD014577. Title : Phthalonitrile Monomers Containing Imide and/or Phenoxy Linkages, and Polymers Thereof. ...

International Nuclear Information System (INIS)

A poly(ether urethane) (PEUR)/poly(ethylene oxide) (PEO)/SiO2 based nanocomposite polymer is prepared and employed in the construction of high efficiency all-solid-state dye-sensitized nanocrystalline solar cells. The introduction of low-molecular weight PEUR prepolymer into PEO electrolyte has greatly enhance the electrolyte performance by both improving the interfacial contact properties of electrode/electrolyte and decreasing the PEO crystallization, which were confirmed by XRD and SEM characteristics. The effects of polymer composition, nano SiO2 content on the ionic conductivity and I3- ions diffusion of polymer-blend electrolyte are investigated. The optimized composition yields an energy conversion efficiency of 3.71% under irradiation by white light (100 mW cm-2).

International Nuclear Information System (INIS)

English 2004 2 p. Brazil Rocha, RM Centro Tecnico Aeroespacial (CTA),

KoreaScience (Korea)

Full Text Available

British Library Electronic Table of Contents (United Kingdom)

Abstract The effects of the type of coupling agent and virgin polypropylene (PP) content on the mechanical properties and water absorption behavior of recycled low-density polyethylene/wood flour (WF) composites were investigated. The fractured surfaces of these recycled wood/plastic composites (rWPCs) were examined to gain insight into the distribution and dispersion of WF within the polymer matrix. The results indicate that the use of 100% recycled polymer led to inferior mechanical properties and to a greater degree of moisture absorption and swelling when compared to recycled polymer-virgin PP wood/plastic composites. This could have been related to the poor melt strength and inferior processability of the recycled polymer. The extent of improvement of the mechanical properties depende...

British Library Electronic Table of Contents (United Kingdom)

Wood plastic composites (WPCs) are comprised of wood flour and thermoplastic polymer. The matrix is typically high-density polyethylene, poly (vinyl chloride), or polypropylene. The effect of morphology and micromechanics of wood flour particles on the mechanical performance of the bulk composite is a relatively unexplored area. The knowledge about the in situ properties of wood particles and the interfacial properties between the wood particles and the polymer matrix in the bio-composites is very limited. The objective of this work is to characterize the full-field deformation and strain distribution in and around wood particles embedded in polymer matrix. The mechanical tests are performed in small-scale tensile loading stage on thin composite samples containing 1-3 wood particles orient...

Energy Technology Data Exchange (ETDEWEB)

Since several years we apply the radiation-grafting technique to prepare polymeric membranes for application in polymer electrolyte fuel cells (PEFCs). Our investigations presented here focus on changes in toughness of these materials after the various synthesis steps and the importance of membrane toughness for their application in PEFCs. (author) 2 figs., 4 refs.

International Nuclear Information System (INIS)

Esters of dihydric alcohols with alkenylphosphonic or alkenylphosphinic acids which are polymerizable by free radicals are described. They are combined with polymer binders, in particular water-soluble polymers, and photoinitiators forming free radicals to give photopolymerizable mixtures which are suitable for the production of photoresists and printing plates. The mixtures display low heat-sensitivity and have long shelf lives. (author) 1 tab.

British Library Electronic Table of Contents (United Kingdom)

The physics and technology of a new class of efficient composite piezoelectrics are described. This material combines nanostructured and micropiezoelectric matrix composites. They consist of a polymer matrix, an insulating nanodimensional phase, and a microdimensional piezoelectric phase. It is shown that the nanostructuring of the near-surface region of polymer-PZT piezoelectric composites greatly improves their piezoelectric, mechanical, and electromechanical characteristics. A plausible mechanism underlying this effect is suggested.

Energy Technology Data Exchange (ETDEWEB)

Water transport in the ionomeric membrane, typically Nafion{reg_sign}, has profound influence on the performance of the polymer electrolyte fuel cell, in terms of internal resistance and overall water balance. In this work, high resolution neutron imaging of the Nafion{reg_sign} membrane is presented in order to measure water content and through-plane gradients in situ under disparate temperature and humidification conditions.

International Nuclear Information System (INIS)

Radiation processed wood-polymer composites (WPC) can replace conventional wood in many industrial applications. However, for proper utilization of the composites, adequate testing and evaluation programmes are essential. The paper briefly describes the development of WPC at the Bhabha Atomic Research Centre, Bombay, and the evaluation of WPC for various applications in greater details. The various mechanical properties and their significance in overall performance of WPC are also discussed. (author).

Energy Technology Data Exchange (ETDEWEB)

A membrane process utilizing dialysis and selective complexation by water-soluble polymers has been developed. This process, termed affinity dialysis, has been shown to be selectively extract and concentrate both cations and anions in a manner similar to ion exchange or solvent extraction. The selective removal of calcium from sodium with selectivity of about 30, removal of chromate ion from dilute streams, and separation of transition metal ions such as Cu/Fe and Cu/Zn have all been successfully demonstrated. Effects of different polymers, polymer concentration, temperature, and flow rates have been studied. The effect of increased polymer concentration is to increase product concentration if appropriate changes in feed, polymer solution, and strip flow rates are made. A continuous polymer solution recycle and regeneration system has been constructed and ...

Energy Technology Data Exchange (ETDEWEB)

Nanoimprinting is a fast-growing technique for nanoscale patterning. One of the remaining issues in nanoimprinting is the removal of the residual layer after nanoimprinting. Traditionally the residual layer is removed by an oxygen reactive-ion etching (RIE) step. The need for a vacuum environment and dedicated equipment in this step lowers the throughput and increases the cost of the nanoimprinting process. It also prevents the possibility of patterning isolated functional polymers because oxygen RIE destroys the functional materials. In this work, novel nanoimprinting schemes are developed to nondestructively remove the residual layer in thermal nanoimprinting by solvent developing and dewetting. Combined with a transfer-bonding technique, three-dimensional polymer scaffolds are achieved. The techniques developed here eliminate the RIE step in thermal nanoimprinting and are compatible with roller nanoimprinting for large-scale patterning of ...

Energy Technology Data Exchange (ETDEWEB)

The adverse effect of moisture diffusion on the properties of wood has been one of the main weaknesses of wood. Using a gamma irradiation method, wood-polymer composites have been produced which exhibit significant improvement in mechanical properties like compression, creep deformation and creep rupture particularly at high humidity. It has been thought that the impregnation of polymer into the wood has affected the moisture diffusion in the wood, so that its adverse effects on the mechanical properties has been reduced. In this report the apparent diffusion coefficients of a Ramin wood impregnated with varying amounts of polymethyl methacrylate (PMMA) were determined using a Fick's law approach. An initial linear relationship was found for impregnation of up to 70% PMMA, after which the diffusion coefficient levels off to a maximum value, for the three environmental relative humidity levels of 40, 60 and 90({plus minus}5)%. The ...

Science.gov (United States)

The kinetics of electrical breakdown of thin (15-70 ?m) layers of polymers and ceramics in a constant-sign field at 77-480 K has been investigated. The temperature dependences of the longevity (breakdown waiting time) of both dielectrics have been found to be similar to each other. At elevated temperatures, the longevity of the dielectrics varies exponentially with increasing temperature, and at reduced temperatures, it is temperature-independent (there is an athermal plateau). The mechanisms of elementary events controlling the process of preparation of the dielectrics for breakdown at elevated and reduced temperatures are the thermal-fluctuation over-barrier electron transition from trap to trap and the tunneling (under-barrier) transition, respectively. The hopping electron transport in the field direction gives rise to critical space charges causing breakdown of the dielectrics. The transition barrier heights (trap depths) have been determined. The ...

Science.gov (United States)

We study the emission zone in a single-layer polymer light-emitting diode. The emission zone is found by studying the angular distribution of the electroluminescence. The emission is modeled by accounting for optical interference. We account for birefringence of the anode layer in our model. The active polymer was, however, found to be isotropic. The anode consists of a single-layer of the conducting polymer complex poly(3,4-ethylenedioxythiophene) and poly(styrene sulfonate) (PEDOT-PSS), with enhanced conductivity. As a cathode we use plain aluminum. By using only PEDOT-PSS we avoid having a thin metal layer or indium-tin-oxide as the anode in the path of the escaping light. The active material is a substituted polythiophene with excellent film forming properties. A comparison between the experimental and calculated angular distribution of light emission from a single-layered polymer light-emitting ...

Energy Technology Data Exchange (ETDEWEB)

Major advances in 'Energy and Materials Cycles' have been achieved in the removal of heavy metals from the solid residues of municipal waste incineration. It has been conclusively shown that the oxidation/reduction conditions established during the thermal treatment of filter ash have a decisive influence on the evaporation of groups of heavy metals. With respect to biomass gasification, studies have been carried out with respect to the best way of extracting pure hydrogen from the low calorific value gas that is typically obtained from a biomass gasifier. The overarching goal of the laboratory 'High Temperature Solar Technology' is the use of solar energy for the production of solar fuels, or for the reduction of CO{sub 2} emissions in large scale industrial processes that are conventionally carried out with the use of fossil fuels. In a short-term project targeted at the solar production of lime, highly encouraging results (98% degree of ...

Energy Technology Data Exchange (ETDEWEB)

This thesis is devoted to studies which prepared the construction of an atom Mach-Zehnder interferometer. In such an interferometer, the propagating waves are spatially separated, and the internal state of the atom is not modified. The beam-splitters are diffraction gratings, consisting of standing optical waves near-resonant with an atomic transition. We use the Bloch functions to define the atom wave inside the standing wave grating and thus explain the diffraction process in different cases. We developed a nearly all-analytical model for the propagation of an atom wave inside a Mach-Zehnder interferometer. The contrast of the signal is studied for many cases: phase or amplitude gratings, effects of extra paths, effects of the main mismatches, monochromatic or lightly polychromatic sources. Finally, we discuss three interferometric measurements we think very interesting. The first, the index of refraction of gas for atomic waves, is studied in detail, with numerical simulations. The ...

International Nuclear Information System (INIS)

By means of an audio frequency plasma polymerisation ultra-thin gradient plasma polymer layers were deposited on zinc and zinc-coated iron. The aim was to generate an interfacial polymeric layer which bonds to an oxidised metal as well as to a subsequently applied organic coating and acts as an interfacial barrier layer for ions and water. Surface modifications were done in an in situ plasma cell with infrared reflection absorption spectroscopy (IRRAS). The zinc surface was first activated by an oxygen plasma to provide a freshly oxidised and contamination free oxide surface. The intermediate stages of the surface reactions could be revealed. Carbon dioxide molecules as oxidation products adsorbed on the growing zinc oxide and were desorbed at a later stage. An organosilicon plasma polymer was deposited directly on top of the oxide layer from a hexamethyldisilane (HMDS) plasma. Afterwards a cyclohexene (CHEX)/hexamethyldisilane co-plasma ...

Energy Technology Data Exchange (ETDEWEB)

LiNiO{sub 2} is one of the most promising material for positive electrodes of lithium-ion batteries. However, its behaviour during cycling and the existence of several phase transitions induced by the lithium ions de-intercalation process has not been explained so far. A transition electron microscopy study of various Li{sub x}NiO{sub 2} (0.25lithium ions and gaps during electrochemical charging. This study is in agreement with the potential levels of the electrochemical cycle and with the polarization phenomena during cycling. Abstract only. (J.S.)

Energy Technology Data Exchange (ETDEWEB)

The aim of this work is the comparative study of the properties of the natural graphite/liquid organic electrolyte interface by impedance spectroscopy with respect to different lithium salts (LiX with X = ClO{sub 4}{sup -}, BF{sub 4}{sup -}, CF{sub 3}SO{sub 3}{sup -}, N(CF{sub 3}SO{sub 2}){sub 2}{sup -}, PF{sub 6}{sup -}). The evolution of the interface properties during the first electrochemical reduction suggests different mechanisms of formation of passivation films. A more stable, thin and homogenous film seems to develop when the LiN(CF{sub 3}SO{sub 2}){sub 2} or LiPF{sub 6} lithium salts are used. The chemical diffusion coefficient of lithium in graphite has been determined by impedance spectroscopy. (J.S.) 16 refs.

British Library Electronic Table of Contents (United Kingdom)

The glasses with the composition of 37.5Li2O?(25?x)Fe2O3?xNb2O5?37.5P2O5 (mol%) (x=5,10,15) are prepared, and it is found that the addition of Nb2O5 is effective for the glass formation in the lithium iron phosphate system. The glass?ceramics consisting of Nasicon-type Li3Fe2(PO4)3 crystals with an orthorhombic structure are developed through conventional crystallization in an electric furnace, showing electrical conductivities of 3?10?6?Scm?1 at room temperature and the activation energies of 0.48?eV (x=5) and 0.51?eV (x=10) for Li+ ion conduction in the temperature range of 30?200??C. A continuous wave Nd:YAG laser (wavelength: 1064?nm) with powers of 0.14?0.30?W and a scanning speed of 10??m/s is irradiated onto the surface of the glasses, and the formation of Li3Fe2(PO4)3 crystals is c...

International Nuclear Information System (INIS)

Liquid-liquid extractive separation of lithium isotopes was carried out in order to investigate the fluctuation of separation factors (a) as a function of salt concentrations in an aqueous phase. Two equations for separation factor (a_o_b_s) as a function of the concentration were introduced; one for the diluted region, and another for the concentrated region. In the former solution where hydrated lithium ions are predominant, 1n a_o_b_s = Ac + B, and in the latter where ion-pairs with anions are predominant, 1n a_o_b_s = Dc + E(c - F)"1"/"3 + G. Some guidelines are derived from the salt-specific constants A, B, D, E, F and G. The heavier isotopes are inclined to be in the more hydrated state in the diluted solution, while the lighter isotopes tend to be in a less hydrated state. In the concentrated solution, heavier isotopes are more likely to be in ion-pair form. Ionic association occurs from the lower concentration in the order of LiI < ...

Energy Technology Data Exchange (ETDEWEB)

As lithium battery technology sets out to bridge the gap between portable electronics and the electrical automotive industry, cathode materials still stand as the bottleneck regarding performances. In the realm of highly attractive polyanion-type structures as high-voltage cathode materials, the sulfate group (SO{sub 4}){sup 2-} possesses an acknowledged superiority over other contenders in terms of open circuit voltage arising from the inductive effect of strong covalent S-O bonds. In parallel, novel lithium insertion mechanisms are providing alternatives to traditional intercalation, enabling reversible multi-electron processes securing high capacities. Combining both of these advantageous features, we report here the successful electrochemical reactivity of copper sulfate pentahydrate (CuSO{sub 4}.5H{sub 2}O) with respect to lithium insertion via a two-electron displacement reaction entailing the extrusion of metallic ...

Energy Technology Data Exchange (ETDEWEB)

Many investigations of anode materials for lithium-ion secondary batteries have been carried out in order to obtain batteries of higher capacity and energy density. Recently, SnO-based glasses, which were prepared by the usual melt quenching technique, have been proposed as a new anode for lithium-ion secondary batteries by Idota et al. It has been reported that the capacity per unit weight was higher than 600 mAh g{sup {minus}1} and the capacity per unit volume was higher than 2,200 mAh cm{sup {minus}3}, values which are almost double those for carbon materials used as anodes of commercial lithium-ion batteries at present. Thus SnO-based glasses have attracted much interest as high-capacity anode materials for lithium-ion secondary batteries. Amorphous materials in the system SnO-B{sub 2}O{sub 3}-P{sub 2}O{sub 5}, with or without the addition of Li{sub 2}O, were synthesized by mechanical milling ...

Science.gov (United States)

Before electroless plating, polymer surfaces must be sensitized and/or activated by using either the conventional two-step or one-step process. The latter stage is a compulsory one to make such surfaces catalytic, e.g., for Ni-P deposition. These processes are performed here using O{sub 2}, NH{sub 3}, or N{sub 2} plasma pretreatments. Reaction mechanisms are proposed for each of the processes and for each type of surface considered (oxygenated or both oxygenated and nitrogenated by the plasma treatment). Direct palladium chemisorption onto nitrogenated groups is highlighted. This allows one to simplify the process making the surface catalytic via elimination of the use of SnCl{sub 2} and to extend the method to any polymer. An additional interest of the plasma treatments, besides their high efficiency in grafting chemical functions, is to perform this grafting at will on selected areas which results in selective metallization.

British Library Electronic Table of Contents (United Kingdom)

Nanocapsules coated by medicinal plants have many applications in drug manufacturing. Medicinal plants can be loaded on nanocapsules with polyesteric triblock copolymer poly ethylene glycol-poly butylene adipate-poly ethylene glycol (PEG-PBA-PEG) as shell and olive oil can be introduced as a core of nanocapsules by a method known as polymer deposition solvent evaporation method. In this research, first, certain amount of polymer, Matricaria recutita extract and olive oil were mixed with acetone and then, water was added to the solution using magnetic stirrer. After which the acetone was removed by vacuuming and finally nanocapsules were found by freezing-drier. The study showed the size of nanocapsules depends on variety of factors such as the ratio of polymer to oil and concentration of p...

Energy Technology Data Exchange (ETDEWEB)

Considerable interest has focused recently on the use of lignocellulosic fibers as a reinforcement for thermoplastic polymers. The combination of these dissimilar materials, however, is characterized by a widespread incompatibility that leads to a weak fiber/polymer interface and poor performance properties for the composite. In an effort to improve compatibility a number of fiber surface modification approaches have been investigated including plasma, ozone, and polymer grafting treatments. Evaluation of adhesion improvements has been complicated by processing variables that are difficult to control. This paper will discuss the use of the-micro-debond test in quantifying the interfacial shear strength (ISS) in wood fiber/polystyrene composites. Wood fibers were modified to different degrees with styrene-maleic anhydride copolymers that varied in their composition. The effect of fiber modification on surface energetics was ...

British Library Electronic Table of Contents (United Kingdom)

Abstract:- In recent years, the study of polymer/clay nanocomposites has attracted major research and commercial interests due to their superior mechanical and thermal properties to those of the neat polymers. Numerical modelling is an advantageous approach to understand the material behaviour. In this work a symmetric two dimensional finite element model is developed to simulate the fully exfoliated Polymer/Clay nanocomposite behaviour and evaluate its- before stress stress-strain curve. The Nylon 66/Clay in this study has a nonlinear elastic behaviour. The influence of volume fraction and aspect ratio of clay platelet (defined as the ratio of the particle length to the particle thickness) on the tensile behaviour of exfoliated Nylon 66/clay nanocomposite is investigated with the aid of n...

International Nuclear Information System (INIS)

The performance of different polymers used to flocculate red mud particulate materials in the Bayer process can be evaluated on the basis of their efficiency to achieve adequate settling velocities and turbidity levels. In this study, three commercially available flocculants are evaluated under typical conditions found in the last washer of a Bayer plant. The different shear levels are produced by using a modified Couette flow system. Great differences are noticed in the performance of the polymers when they are compared at different dosages and at different shear rate levels. The data collected also suggests that conventional cylinder settling tests may not be adequate to measure the performance of certain types of polymers. (author)

Energy Technology Data Exchange (ETDEWEB)

We demonstrate control and improvement of charge injection in organic electronic devices by utilizing self-assembled monolayers (SAMs) to manipulate the Schottky energy barrier between a metal electrode and the organic electronic material. Hole injection from Cu electrodes into the electroluminescent conjugated polymer poly[2-methoxy,5-(2{sup {prime}}-ethyl-hexyloxy)-1,4-phenylene vinylene] was varied by using two conjugated-thiol based SAMs. The chemically modified electrodes were incorporated in organic diode structures and changes in the metal/polymer Schottky energy barriers and current{endash}voltage characteristics were measured. Decreasing (increasing) the Schottky energy barrier improves (degrades) charge injection into the polymer. {copyright} {ital 1997 American Institute of Physics.}

International Nuclear Information System (INIS)

In this work, a water-soluble polymer, polyethylenimine (PEI) was used for the simultaneous separation and preconcentration of trace Cu and Mn prior to their determination by flame atomic absorption spectrometry. For this purpose, the sample and the PEI solution were mixed and the metal-bound polymer was precipitated by adding acetone. The precipitate was separated and dissolved in a minimum amounts of water and aspirated into a flame AAS. By increasing the ratio of the volumes of sample to water used in dissolving the precipitate, the analyte elements were concentrated as needed. The sorption is quantitative in the pH ?6. Detection limits were 5.2 ?g/L for Cu and 5.4 ?g/L for Mn. This method is simple, fast and precise.

British Library Electronic Table of Contents (United Kingdom)

As portable electronics become more advanced and alternative energy demands become more prevalent, the development of advanced energy storage technologies is becoming ever more critical in today's society. In order to develop higher power and energy density batteries, innovative electrode materials that provide increased storage capacity, greater rate capabilities, and good cyclability must be developed. Nanostructured materials are gaining increased attention because of their potential to mitigate current electrode limitations. Here we report on the use of vertically aligned multi-walled carbon nanotubes (VA-MWNTs) as the active electrode material in lithium-ion batteries. At low specific currents, these VA-MWNTs have shown high reversible specific capacities (up to 782mAhg^-^1 at 57mAg^-...

Energy Technology Data Exchange (ETDEWEB)

LiNi{sub 0.8}Co{sub 0.2}O{sub 2} particles from high-power lithium-ion cells were examined to determine material changes that result from accelerated aging tests. X-ray absorption spectroscopy (XAS) and transmission electron microscope (TEM) data indicated a Li{sub x}Ni{sub 1-x}O-type layer on the particle surfaces. The greater thickness on particles from high-power fade cells indicate that these surface layers are a significant contributor to cathode impedance rise observed during cell tests.

Energy Technology Data Exchange (ETDEWEB)

A solar thermal powered aircraft powered by heat energy from the sun. A Rankine-Brayton hybrid cycle heat engine is carried by the aircraft body for producing power for a propulsion mechanism, such as a propeller or other mechanism for enabling sustained free flight. The Rankine-Brayton engine has a thermal battery, preferably containing a lithium-hydride and lithium mixture, operably connected to it so that heat is supplied from the thermal battery to a working fluid. A solar concentrator, such as reflective parabolic trough, is movably connected to an optically transparent section of the aircraft body for receiving and concentrating solar energy from within the aircraft. Concentrated solar energy is collected by a heat collection and transport conduit, and heat transported to the thermal battery. A solar tracker includes a heliostat for determining optimal alignment with the sun, and a drive motor actuating the solar concentrator into optimal ...

Energy Technology Data Exchange (ETDEWEB)

Nanocrystalline MnO thin film has been prepared by a pulsed laser deposition (PLD) method. The reversible lithium storage capacity of the MnO thin film electrodes at 0.125C is over 472 mAh g{sup -1} (3484 mAh cm{sup -3}) and can be retained more than 90% after 25 cycles. At a rate of 6C, 55% value of the capacity at 0.125C rate can be obtained for both charge and discharge. As-prepared MnO thin film electrodes show the lowest values of overpotential for both charge and discharge among transition metal oxides. All these performances make MnO a promising high capacity anode material for Li-ion batteries. (author)

British Library Electronic Table of Contents (United Kingdom)

A range of new nanomaterials to replace the active materials in lithium ion batteries are currently being studied and employed in an attempt to overcome various performance limitations of previous technologies. Nanomaterial production and manufacturing techniques appear to fit into a general trend towards more energy intensive production methods for high-tech goods. This does not necessarily imply an increase in lifecycle energy use; artefacts that consume or transform energy during use could possibly regain this increased initial input via increased efficiency in use. In particular, this paper highlights that larger gains could be possible if the artefact in question allows a given service to be provided via an alternative and more efficient system entirely.The lifecycle energy efficienci...

Energy Technology Data Exchange (ETDEWEB)

Observations are reported of the lithium feature (6708 A) in some bright southern stars, most of which are F, G, or K dwarfs. Three of these stars have been suggested as belonging to the Ursa Major Group. Two of these three have the large Li abundance and strong Ca II H and K emission expected of such young stars. The third potential Ursa Major Group member has little Li, but is also not a true kinematic member. No stars were found with abnormal (Li-6)/(Li-7) ratios, in accord with other recent analyses. Thus it appears that all stars have (Li-6)/(Li-7) near the solar/terrestrial value of 0.08. 31 references.

Energy Technology Data Exchange (ETDEWEB)

Recent developments in rechargeable Li-ion battery technology include the use of lithium-carbon compounds instead of metallic anodes. Non-graphitizable carbons offer high capacity as the anode material but it's large irreversible capacity must be solved. The ultimate goals of the present work are to understand the origin of the high capacity and large irreversible capacity in conjunction with the structural change due to Li intercalation and thus to establish a scientific basis for optimizing their performance in real batteries. 'House of cards' model is considered and emphasis is given to find out the size of the pores present in the carbon fibers prepared from an isotropic petroleum pitch and heat treated at 1200degC. Small angle neutron scattering and wide angle neutron scattering results provide enlargement of pores and d-spacing of grapheme layers after Li intercalation. (author)

British Library Electronic Table of Contents (United Kingdom)

As lithium battery technology sets out to bridge the gap between portable electronics and the electrical automotive industry, cathode materials still stand as the bottleneck regarding performances. In the realm of highly attractive polyanion-type structures as high-voltage cathode materials, the sulfate group (SO4)^2^- possesses an acknowledged superiority over other contenders in terms of open circuit voltage arising from the inductive effect of strong covalent S-O bonds. In parallel, novel lithium insertion mechanisms are providing alternatives to traditional intercalation, enabling reversible multi-electron processes securing high capacities. Combining both of these advantageous features, we report here the successful electrochemical reactivity of copper sulfate pentahydrate (CuSO4.5H2O...

UK PubMed Central (United Kingdom)

A method for the study of conjugated polyelectrolyte (CPE) photophysics in solution at the single-molecule level is described. Extended observation times of single polymer molecules are enabled by the...Full Text Available

Science.gov (United States)

Wood Plastic Composite (WPC) was prepared with simul (soft wood, density = 0.4g/cc) and butylmethacrylate (BMA) monomer using 10% methanol as the swelling agent. Effect of additives including (i) multifunctional acrylates such as tripropylene glycol diacrylate (TPGDA), trimethylol propane triacrylate (TMPTA) (ii) oligomer acrylates like the urethane (UA), epoxy (EA) and polyester (PEA) acrylates and (iii) N-vinyl pyrrolidone (NVP) was investigated using 1 to 3 Mrad dose at 0.8 Mrad/h. Synergistic increases in polymer loading yields was achieved in presence of the additives, particularly with the trifunctional acrylate (TMPTA). In addition, acid as well as urea were also used as co-additives and synergistic enhancement in yields of polymer loading were obtained. The synergistic polymer loading by acid addition causes substantial decrease in tensile strength of the composite; but other additives and co-additives increase both ...

UK PubMed Central (United Kingdom)

We describe the interactions of two benzimidazole derivatives, astemizole (AST) and lansoprazole (LNS), with anomalous aggregates of tau protein (neurofibrillary tangles). Interestingly, these...Full Text Available

UK PubMed Central (United Kingdom)

In this study, we report the physico-chemical and biological properties of a novel biodegradable composite scaffold made of nano-hydroxyapatite and natural derived polymers of chitosan and carboxymethyl...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Polysaccharides like cellulose and chitosan are known for their filmic properties. This paper concerns the synthesis and the study of chitosan-based polymer electrolytes. A preliminary work concerns the study of glucosamine reactivity. The poly-condensation of chitosan ethers (obtained by reaction with ethylene oxide or propylene oxide) with bifunctional and monofunctional oligo-ethers leads to the formation of thin lattices (10 {mu}m) having excellent mechanical properties. The presence of grafted polyether chains along the polysaccharide skeleton allows to modify the vitreous transition temperature and the molecular disorder of the system. Two type of polymer electrolytes have been synthesized: electrolytes carrying a dissolved alkaline metal salt and ionomers. The analysis of their thermal, dynamical mechanical, nuclear magnetic relaxation, electrical, and electrochemical properties shows that this new class of polymer ...

Science.gov (United States)

Kusy,. R. P. and. Corneliussen,. R. D.,. Polym. Eng. Sci.,. 15,. 1975 pp. 107. DeAraujo,. F. T. and. Rostenberg,. H. M.,. Jour. Phys.,. Sec. D,. Appl. ...

Energy Technology Data Exchange (ETDEWEB)

In the synthesis of the peptidyl-polymer corresponding to the sequence (57-100) of the ..beta.. chain of human hemoglobin on Teflon with radiationally grafted polystyrene a comparative study was made of different methods of fragment condensation. It was shown that the most effective methods are azide condensation and condensation with the use of complex F.

UK PubMed Central (United Kingdom)

BackgroundVascular stents are small tubular scaffolds used in the treatment of arterial stenosis (narrowing of the vessel). Most vascular stents are metallic and are deployed either...Full Text Available

International Nuclear Information System (INIS)

Nanoporous materials have become indispensable in many fields ranging from photonics, catalysis and semiconductor processing to biosensor infrastructure. Rapid and energy efficient process fabrication of these materials is, however, nontrivial. In this communication, we describe a simple method for the rapid fabrication of these materials from colloidal dispersions of Polymethyl Silsesquioxane nanoparticles. Nanoparticle-polymer composites above the decomposition temperature of the polymer are examined and the entropic gain experienced by the nanoparticles in this rubric is harnessed to fabricate novel highly porous films composed of nanoparticles. Optically smooth, hydrophobic films with low refractive indices (as low as 1.048) and high surface areas (as high as 1325 m2 g-1) have been achieved with this approach. In this communication we address the behavior of such systems that are both temperature and substrate surface energy dependent. The ...

Energy Technology Data Exchange (ETDEWEB)

This patent describes a delayed acrylamide containing polymer crosslinker having stability in an aqueous solution at high temperatures. It comprises: a combination of an aldehyde and a salicylic acid derivative selected from salicylamide and acetysalicylic acid.

Energy Technology Data Exchange (ETDEWEB)

A 300 W fuel cell power pack has been developed for educational purposes in close collaboration with the Fachhochschule Solothurn Nordwestschweiz. The project was initiated and financed by the Swiss Federal Office of Energy. The outlay and the performance of the power pack are described. (author) 3 figs.

CERN Document Server

The scattering and recombination processes between two triplet excitons in conjugated polymers are investigated by using a nonadiabatic evolution method, based on an extended Su-Schrieffer-Heeger model including interchain interactions. Due to the interchain coupling, the electron and/or hole in the two triplet excitons can exchange. The results show that the recombination induces the formation of singlet excitons, excited polarons and biexcitons. Moreover, we also find the yields of these products, which can contribute to the emission, increase with the interchain coupling strength, in good agreement with results from experiments.

International Nuclear Information System (INIS)

Radiation-initiated polymerization of styrene and acrylic acid in poplar wood were investigated for the preparation of wood-polymer composites. The direct irradiation method was applied to the monomer adsorbed poplar wood specimens. 8000 Ci "6"0Co source at a dose rate of about 0.4 Mrad/h was used. Furthermore the effects of carbon tetrachloride, methanol, dioxane and acrylonitrile on styrene polymerization were investigated and the reaction rates were calculated for each case. The influence of CCl_4 (10%) on acrylic acid polymerization in poplar wood was also determined. (author).

Science.gov (United States)

The removal of Reactive Black 5 dye in an aqueous solution by electrocoagulation (EC) as well as addition of flocculant was investigated. The effect of operational parameters, i.e. current density, treatment time, solution conductivity and polymer dosage, was investigated. Two models, namely the artificial neural network (ANN) and the response surface method (RSM), were used to model the effect of independent variables on percentage of dye removal. The findings of this work showed that current density, treatment time and dosage of polymer had the most significant effect on percentage of dye removal (p0.8). PMID:21411950

British Library Electronic Table of Contents (United Kingdom)

Purpose - This paper aims to describe the technology and applications of nanocomposite materials. Design/methodology/approach - This paper discusses products, applications and technological developments in polymer, ceramic and metal nanocomposites. It concludes with a brief consideration of electronic component applications. Findings - It is shown that polymer nanocomposites and the materials used in their production are commercially available and finding applications in several industries, including automotive, military, food, electronics and leisure, due to their enhanced mechanical, electrical and thermal properties. Ceramic and metallic nanocomposites are at an earlier stage of development and a critical issue to resolve is optimising the dispersion of nanomaterials in the matrices. Pa...

Energy Technology Data Exchange (ETDEWEB)

This paper describes the experimental results of accelerated aging tests conducted on three different types of polymer materials. Salt fog chamber tests were used to study the surface degradation modes for all materials. The work presented here was performed using a newly constructed fog chamber system that was able to control both chamber humidity and UV radiation. The changes in the surface morphology, material structure and leakage current were examined to study the influence of environmental humidity.

International Nuclear Information System (INIS)

Wood-plastic composites (WPC) have been prepared with five low-grade woods, native to Syria, using three monomer systems; acrylamide, butylmethacrylate, and styrene, with methanol as the swelling solvent. Polymerization was induced at various radiation doses (10, 20, and 30 kGy) at a dose rate of 3.5 kGy/h using a "6"0Co gamma radiation source. Some physical properties of WPC, namely polymer loading and compression strength have been measured. The polymer loading decreases approximately with increasing density of the wood species used.

International Nuclear Information System (INIS)

Two species of wood, viz. Haldu (Adina Cordifolia) and Jamun (Syzygium Cumini) were vacuum-impregnated with two styrene-based monomer systems and polymerized in situ with gamma radiation from a cobalt-60 source. The electrical conductivity of these specimens was determined at various polymer loadings under dry conditions, after wetting and after wet recovery as per ASTM standards. The water absorption characteristics are also presented. The results are discussed with special reference to the role of water. Potential applications are also discussed. 7 figures.

Energy Technology Data Exchange (ETDEWEB)

In the framework of the development of new generations of surface ships, the Royal Netherlands Navy is studying the option of the all-electric ship concept. Background is the growing demand of electric power on board of naval ships for various services (including weapons and sensors). Important features of such an all-electric ship concept are decentralized electric energy generation and storage. In such an all-electric ship concept, fuel cells are expected to play an important role in the future, not only for reasons of energy efficiency and low emissions, but also because of their potential military advantages. Especially polymer electrolyte fuel cell systems appear to be very interesting for this application.

British Library Electronic Table of Contents (United Kingdom)

Abstract The creation of chirality on Earth and the development of chiral life have been discussed in this highlight. Convincing evidence for the introduction of chirality on Earth is still fragmentary. We believe that by a combination of chiral crystallization and formation of helical polymers with preferred chiral conformational structure is the key to this question. This concept of macromolecular asymmetry has inspired ideas and resulted in possible rules for how chiral life as we know it, could have been introduced. These investigations needed the understanding of the requirements for chiral crystallization, for the stereochemistry of the initial formation of helical polymers, the measurements of optical activity of solids and their coordination with the fundamentals of chirality. Spac...

DEFF Research Database (Denmark)

All-optical envelope detection of a 5 GHz 200 Mbit/s modulated radio frequency signal is achieved using a 650 nm resonant cavity light emitting diode. Error-free transmission is achieved over a 50 m-long link of 1 mm diameter graded index polymer optical fibre (POF). The presented system has potential applications in low cost and low complexity short range wireless and wireline POF-based transmission links.

International Nuclear Information System (INIS)

Thermoplastic polymer materials and the compounds made with them are being used more frequently for industrial components and for general use. However, the application of these materials for the production of complex shaped or relatively large pieces is limited, because of the difficulty and cost of making the necessary tool kit for the job. One solution is the use of the welding process. But the safe and reliable union of different thermoplastic material parts is not a simple process, even less so in the case of unions of large components. Welding by microwaves using polymer conductors can help, since the large scale equipment is available, and methods for continuous processes by microwave have been developed, that can be used to weld large and small components. Many thermoplastics (ex. polyethylene) do not absorb, or absorb very little, energy from microwaves. Polymer conductors, however, heavily absorb from microwaves ...

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the objectives, background, technical progress, and status of ANL electric vehicle battery R D tasks for DOE-EHP during the period of January 1 through March 31, 1991. The work is organized into the following six task areas: Project management; battery systems technology; lithium/sulfide batteries; advanced sodium/metal chloride battery; aqueous batteries; and EV Battery performance/life evaluation.

International Nuclear Information System (INIS)

The radiation dose to a series of adult and paediatric patients undergoing cardiac catheterisations and adults having percutaneous transluminal coronary angioplasty has been measured/determined directly using lithium fluoride thermoluminescent dosemeters and indirectly using an air ionisation chamber which indicated exposure-area product. Somatic and genetic risks are estimated from the dosimetry results. It is suggested that the magnitude of the radiation hazard is negligible compared with other clinical hazards associated with these procedures. (author).

Energy Technology Data Exchange (ETDEWEB)

Crystalline {alpha}-Fe{sub 2}O{sub 3} powder was prepared by the mechanical milling of crystalline {alpha}-FeOOH at room temperature in air. This result means that crystalline {alpha}-FeOOH is dehydrated by mechanical milling at room temperature. The obtained {alpha}-Fe{sub 2}O{sub 3} powder worked as a rechargeable electrode material in lithium ion conductive organic electrolytes. The electrodes exhibited high discharge capacities of over 1000mAhg{sup -1} corresponding to 6 Li per {alpha}-Fe{sub 2}O{sub 3} at potentials ranging from the open circuit potential to 0.5V (versus Li{sup +}/Li) in the first discharging (lithium insertion) process. This suggests that the valence deviation from Fe{sup 3+} in {alpha}-Fe{sub 2}O{sub 3} to Fe{sup 0} may be caused by electrochemical reduction. In contrast, after the first discharge, the electrodes exhibited high charge capacities of more than 700mAhg{sup -1} corresponding to 4.2 Li per {alpha}-Fe{sub ...

Energy Technology Data Exchange (ETDEWEB)

Nano-sized particles of a lithium ion conductive solid electrolyte, LiTi{sub 2}(PO{sub 4}){sub 3}, were prepared by laser ablation. The obtained particles were ca. 10nm in diameter. X-ray powder diffraction and Raman spectroscopy showed that they were amorphous with local structure similar to the crystalline counterpart. They were crystallized by the heating at ca. 630{sup o}C. (author)

International Nuclear Information System (INIS)

Experimental results are presented on the quasi-statistic polarization reversal and on the effect of high dc electric field on the behaviour of LiNH_4SO_4 and LiND_4SO_4 monocrystals, namely in the vicinity of the II-III phase transformation.

International Nuclear Information System (INIS)

Lithium Ceramics offer tremendous potential as a source for the production of tritium ("3H) for fusion power reactors. Their successful application will depend to a great extent upon the diffusion properties of the "6Li within the matrix. Consequently knowledge of "6Li concentration gradients in the ceramic matrices is an important requirement in the continued development of the technology. In this investigation, the neutron depth profile (NDP) technique has been applied to the study of concentration profiles of "6Li in lithium aluminate ceramics, doped with 1.8%, 50% and 95% "6Li isotopic concentrations. Specimen for analysis were prepared at Battelle (PNL) as pellet discs. Samples for diffusion studies were arranged as diffusion couples in the following manner: 1.8% "6Li discs/85% "6Li powder. Experiments were performed at the Texas A and M Nuclear Science Center Reactor Building, utilizing 1 MW equivalent thermal neutron fluxes 3x10"1"1 ...

Science.gov (United States)

A simple approach to controlling the loading percentage and size of zero-valent iron nanoparticles (ZVI NPs) immobilized within polyacrylic acid (PAA)/polyvinyl alcohol (PVA) nanofibrous mats for dye remediation applications is described. A functional "nanoreactor" comprised by electrospun PAA/PVA nanofibers served to bind ferric ions with the carboxyl groups of PAA, prior to their reduction to ZVI NPs. The resulting ZVI NP-immobilized hybrid polymer nanofibers were characterized using scanning electron microscopy, transmission electron microscopy, and thermogravimetric analysis. The morphology of the polymer nanofibers exhibited no appreciable change even after eight cycles of ferric ion binding/reduction, and the loading percentage and size of the ZVI NPs were controlled simply by varying the number of ferric ion binding/reduction cycles. Dye remediation experiments revealed that the decoloration effect of ZVI NPs immobilized within the ...

Energy Technology Data Exchange (ETDEWEB)

Two sources of ultraviolet (UV) radiation with peak wavelengths in the UV-C or UV-B ranges were compared for their ability to sterilize contact lenses infected with Pseudomonas aeruginosa, Streptococcus pneumoniae, Acanthamoeba castellani, Candida albicans, and Aspergillus niger. Also examined was the effect of prolonged UV light exposure on soft and rigid gas permeable (RGP) contact lenses. The UV-C lamp (253.7 nm, 250 mW/cm2 at 1 cm) was germicidal for all organisms within 20 minutes but caused destruction of the soft lens polymers within 6 hours of cumulative exposure. UV-C caused damage to RGP lenses in less than 100 hours. The UV-B lamp (290-310 nm, 500 mW/cm2 at 1 cm) was germicidal for all organisms tested (except Aspergillus) with a 180-minute exposure and caused less severe changes in the soft lens polymers than did the UV-C lamp, although cumulative exposure of 300 hours did substantially weaken the soft lens material. RGP materials ...

Energy Technology Data Exchange (ETDEWEB)

The surface coverage of amorphous silica gels used in the synthesis of silica polyamine composites has been investigated by 29Si NMR. By diluting the polyamine anchor silane, chloropropyl trichlorosilane, with methyl trichlorosilane it was found that surface coverage could be markedly improved for a range of amine polymers after grafting to the silica surface. The commensurate decrease in the number of anchor points and increase in the number of free amines results in an increase in metal capacity and/or an improvement in capture kinetics. Solid state CPMAS-13C NMR has been employed to investigate the structure and metal ion binding of a series of these composite materials. It is reported that the highly branched polymer, poly(ethyleneimine) (PEI) exhibits much broader 13C NMR resonances than the linear polymers poly(allylamine) (PAA) and poly(vinylamine) (PVA). These results are understood in terms of the low energy ...

Energy Technology Data Exchange (ETDEWEB)

Selected local woods and their wood-polymer combinations or composites (WPC) were tested for their thermal conductivity and their fire resistance. WPC were prepared by polymerizing monomers ''in situ'' in oven dried woods by gamma radiation. The monomers included acrylonitrile (AN), 60% styrene-40% acrylonitrile (STAN), methyl methacrylate (MMA), 95% methyl methacrylate-5% dioxane (MD), and vinylidene chloride (VDC). A reduction in thermal conductivity was exhibited by all the composites prepared. W-PAN showed the greatest reduction in thermal conductivity and W-PSTAN in general showed the least. An explanation is suggested for this behaviour. The polymers PMMA and PMD were found to enhance flammability of the woods while PVDC, PAN, and PSTAN imparted fire resistance to the woods. Of the six local woods studied, Ramin-and-Keruing-polymer composites showed the highest flammable tendencies ...

Energy Technology Data Exchange (ETDEWEB)

A testing program has been conducted by the Westinghouse Hanford Company to confirm the baseline waste form selection for use in Waste Receiving and Processing (WRAP) Module 2A. WRAP Module 2A will provide treatment required to properly dispose of containerized contact-handled, mixed low-level waste at the US Department of Energy Hanford Site in south-central Washington State. Solidification/stabilization has been chosen as the appropriate treatment for this waste. This work is intended to test cement-based, thermosetting polymer, and thermoplastic polymer solidification media to substantiate the technology approach for WRAP Module 2A. Screening tests were performed using the major chemical constituent of each waste type to measure the gross compatibility with the immobilization media and to determine formulations for more detailed testing. Surrogate materials representing each of the eight waste types were prepared in the laboratory. These ...

Environmental Research Database

Objectives1. To develop new photoactive materials and fabricate demonstration QD (quantum dot) solar cells. This will be achieved by:~%~1.1. Materials preparation and characterisation of QD/polymer systems~%~1.2. Optimising structures of QDs, nanorods and polymer for quantum yield and charge transfer~%~1.3 Fabricating demonstration QD/polymer solar cells and measuring power conversion efficiencies~%~2. To demonstrate multiexciton generation (MEG) and harvesting within nanostructured QDs. This will involv [continued...]DescriptionWidespread implementation of photovoltaic electricity to meet changing energy demands requires a step-change in the cost of photovoltaic power. This proposal assembles a consortium of chemists, physicists, materials scientists and electrical engineers from The University of Manchester and Imperial College London to address this need through the development of new low-cost, high-efficiency, ...