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1

Hazard Evaluation and Technical Assistance Report No. TA 76-100, ASARCO, East Helena, Montana.  

Science.gov (United States)

A Hazard Evaluation and Technical Assistance investigation was performed by NIOSH on February 1-4, 1977, at ASARCO, East Helena, Montana, a facility engaged in lead smelting. The survey was prompted by a request from the Regional OSHA Director in referenc...

1977-01-01

2

Evidence for the nature of true Lewis sites in faujasite-type zeolites  

Science.gov (United States)

An IR spectroscopic study of the reduction of copper-exchanged Linde Na-Y zeolite with hydrogen or carbon monoxide and oxidation with oxygen or oxygen-18 showed that copper(I) and AlO(+1) are formed during reduction, and that oxidation generates copper(II) ions but does not change the aluminum species. Trigonally coordinated aluminum was not detected.

1979-05-03

3

Effects of electric field on the II-III phase transition in lithium ammonium sulphate and its deuterated analogue  

International Nuclear Information System (INIS)

Experimental results are presented on the quasi-statistic polarization reversal and on the effect of high dc electric field on the behaviour of LiNH_4SO_4 and LiND_4SO_4 monocrystals, namely in the vicinity of the II-III phase transformation.

1984-03-01

4

Evaluation of SO2 Emission Control Technology Applicable to the East Helena Lead Smelter.  

Science.gov (United States)

Contents: Lead smelter operations generating SO2 and particulate; Sulfuric acid plant technology; Lead smelters with sulfuric acid plant SO2 control; Sulfuric acid plant operation with lead sinter machine problems and solutions; SO2 control for ASARCO lea...

1975-01-01

5

EFFECTS OF PH AND PHOSPHATE ON METAL DISTRIBUTION WITH EMPHASIS ON AS SPECIATION AND MOBILIZATION IN SOILS FROM A LEAD SMELTING SITE  

Science.gov (United States)

Arsenic in soils from the Asarco Lead Smelter in East Helena, Montana was characterized by X-ray absorption spectroscopy (XAS). As oxidation state and geochemical speciation were analyzed as a function of depth (two sampling sites) and surface distribution. These results were c...

6

Field Studies of the Electrical Properties of Permeable Reactive Barriers for Monitoring Barrier Aging  

Science.gov (United States)

Permeable reactive barriers (PRB) are a promising technology for the remediation of groundwater containing a range of organic and inorganic contaminants. Although there are number of different types of reactive barriers, some of the most important are constructed from granular zero valent iron (ZVI). One challenge in the large- scale, long-term implementation of PRBs is to monitor the change in barrier properties over time. For example, mineral precipitates can reduce the effectiveness of the barrier by either insulating the reaction surfaces of the ZVI particles and/or by filling the pore space in the barrier and thus reducing its hydraulic permeability. Previous research has shown that resistivity and induced polarization (IP) measurements are sensitive to corrosion and precipitation due to redox reactions between ions in solution and the ZVI mineral surface. New field studies, supported by additional laboratory studies appear to confirm this work. Resisitivity and IP surveys ...

2006-12-01

7

Production of olefins from recycling polyolefins by means of thermal steam cracking; Olefinerzeugung aus Recycling-Polyolefinen durch thermische Dampfspaltung  

Energy Technology Data Exchange (ETDEWEB)

As one of the largest contractors for the construction of ethylene plants featuring steam cracker furnaces as their core component Linde AG has examined the `real` chemical recycling of polymers in steam cracker furnaces as an alternative to their thermal utilisation. In steam cracker furnaces the feedstock, i.e., hydrocarbons, is broken down to ethylene, propylene, and other valuable products in a steam dilution of approx. 800-870 C. In the ideal case, if polyolefins are used as feedstock, then the initial product which led to the polymers can be fully recycled. In this context a series of experiments was carried out in a laboratory-scale cracker plant. The purpose of this was to demonstrate the technical feasibility and the economic advantage of using recycling polyethylene or polypropylene as feedstock for steam cracker plants. (orig./SR) [Deutsch] Die Linde AG als einer der bedeutendsten Kontraktoren fuer den Bau von Ethylenanlagen, deren ...

1996-12-31

8

Hydrogen activities in the European Union work-programme. Paper  

Energy Technology Data Exchange (ETDEWEB)

Looking at some of the national and international developments in hydrogen technology it becomes clear which important contributions the hydrogen technology oriented activities of the EU have helped to prepare and trigger: (a) Transport Energy Strategy (TES): This initiative of 7 major German automobile and mineral oilcompanies is aimed at an industrial consensus on one or two gasoline alternative fuels, which are to be presented to the German Ministry of Transport. An intermediate trend is that hydrogen may become the fuel of choice. (b) BMW: The Bayerischen Motorenwerke have already very early exposed themselves to the vehicle and component development of hydrogen as a vehicle fuel, focussing on a strategy from CNG to LNG and LH{sub 2}. (c) Opel and GM: Opel has recently announced they have chosen hydrogen as the primary long term fuel for their fuel cell vehicles to be commercialized starting in 2004. (d) CFCP: The California Fuel Cell Partnership with partners from industry and ...

2000-07-01

9

Isotope and trace element systematics in a spinel-lherzolite-bearing suite of basanitic volcanic rocks from San Luis Potosi, Mexico  

Energy Technology Data Exchange (ETDEWEB)

Lherzolite-bearing basanitic magmas of Quaternary age have erupted to form maars, lava/cinder cones and lava flows in two volcanic fields (Ventura and Santo Domingo) in the central Mexican state of San Luis Potosi. The systematics of the radiogenic isotopes of Sr, Nd, and Pb and the relationship between these parameters and elemental compositions are used to investigate the petrogenesis of the volcanic rocks and the nature of their mantle sources. Sr and Nd isotopic data are presented for 19 basanitic rocks, 5 kaersutites, and 6 lherzolitic xenoliths; Pb data presented for the same 19 volcanic rocks and 4 of the 5 kaersutites. The isotopic compositions for all of these samples fall within the mantle range defined by MORBs and OIBs. The basanites generally plot within the OIB field on isotopic diagrams; most of the kaersutites are displaced to slightly more-depleted (i.e. MORB-like) values than the volcanic samples and the xenoliths, with one exception, are significantly more-depleted ...

1989-01-01

10

Effects of pH and phosphate on metal distribution with emphasis on As speciation and mobilization in soils from a lead smelting site  

Energy Technology Data Exchange (ETDEWEB)

Arsenic in soils from the Asarco lead smelter in East Helena, Montana was characterized by X-ray absorption spectroscopy (XAS). Arsenic oxidation state and geochemical speciation were analyzed as a function of depth (two sampling sites) and surface distribution. These results were compared with intensive desorption/dissolution experiments performed in a pH stat reactor for samples from the site with the highest degree of As heterogeneity. The objectives of the study were to investigate the solid-phase geochemical As speciation, assess the speciation of As in solutions equilibrated with the solids under controlled pH (pH=4 or 6) and Eh (using hydrogen or air) environments, observe the effects of phosphate on the release of As into solution, and examine the effects of phosphate on metal mobility in the systems. Arsenic was predominantly found in the As(V) valence state, though there was evidence that As(III) and As(0) were present also. The dominant geochemical phase ...

2005-06-01

11

MEASUREMENT OF HYDROPEROXIDES DURING THE TEXAS 2000 AIR QUALITY STUDY  

International Nuclear Information System (INIS)

Hydroperoxides are important atmospheric oxidants. They are responsible for most of the oxidation of aqueous-phase SO(sub 2) to sulfate in the northeastern United States, resulting in the formation of acid precipitation and visibility-reducing sulfate aerosol (Penkett et al., 1979; Lind et al., 1987; Madronich and Calvert, 1990; Tanner and Schorran, 1995). Atmospheric hydrogen peroxide (H(sub 2)O(sub 2) or HP) is produced by the self-reaction of hydroperoxyl radicals (HO(sub 2)); higher organic peroxides are produced by reaction of HO(sub 2) with alkylperoxyl radicals (RO(sub 2)). Peroxyl radicals, along with OH, are chain carriers in the complex photochemical process that produces tropospheric ozone. Thus, concentrations of peroxides and their free radical precursors depend on solar intensity and ambient concentrations of water vapor, ozone, NO(sub x) (NO+ NO(sub 2)), and VOCs (volatile organic compounds). Several investigators have demonstrated that HP and ...