kaons 2: Topics by WorldWideScience.org

Effects of Coulomb and kaon nuclear potentials on soft K{sup +} production from nuclei

We investigate the possibility of kaon condensation in the dense interior of neutron stars through the s-wave interaction of kaons with nucleons. We include nucleon-nucleon interactions by using simple parametrizations of realistic forces, and include electrons and muons in #beta#-equilibrium. The equation of state above the condensate threshold is derived in the mean field approximation. The conditions under which kaon condensed cores undergo a transition to quark matter containing strange quarks are also established.The critical density for kaon condensation lies in the range (2.3-5.0)#rho#_0, where #rho#_0=0.16 fm"-"3 is the equilibrium density of nuclear matter. The critical density depends largely on the value of the strangeness content of the proton, the size of which is controversial. For too large a value of the strangeness content, matter with a kaon ...

2

Kaon properties in (proto-)neutron star matter

No abstract prepared.

2002-03-01

3

British Library Electronic Table of Contents (United Kingdom)

Abstract. The modification of kaon and antikaon properties in the interior of (proto-)neutron stars is investigated using a chiral SU(3) model. The parameters of the model are fitted to nuclear-matter saturation properties, baryon octet vacuum masses, hyperon optical potentials and low-energy kaon-nucleon scattering lengths. We study the kaon/antikaon medium modification and explore the possibility of antikaon condensation in (proto-)neutron star matter at zero as well as finite temperature/entropy and neutrino content. The effect of hyperons on kaon and antikaon optical potentials is also investigated at different stages of the neutron star evolution.

2010-01-01

4

KLOE-2 experiment at DA$\\Phi$NE upgraded in luminosity

Measurement of \\chi_cJ--> K+K-K+K-

Prospective presentation is given for the experimental program of the KLOE-2 Collaboration, to be performed using the DA$\\Phi$NE $e^+e^-$ collider upgraded in luminosity. Data with the total luminosity of 25 fb$^{-1}$ are aimed to be collected in 3 years. Major modifications of the accelerator and the spectrometer are described. The KLOE-2 physics program contains: CKM unitarity and lepton universality tests, $\\gamma\\gamma$ physics, search for quantum decoherence and testing CPT conservation, low-energy QCD, rare kaon decays, physics of $\\eta$ and $\\eta^\\prime$, structure of low-mass scalars, contribution of vacuum polarization to $(g-2)_{\\mu}$, possible search for WIMP dark matter. In this paper only selected physics subjects are reported.

2011-01-01

5

Light meson mass dependence of the positive-parity heavy-strange mesons

Using 14M psi(2S) events taken with the BES-II detector, chi_cJ-->K+K-K+K- decays are studied. For the four-kaon final state, the branching fractions are B(chi_c0,1,2 -->K+K-K+K-)=(3.47\\pm 0.22\\pm 0.48)\\times 10^{-3}, (0.68\\pm 0.13\\pm 0.10)\\times 10^{-3}, and (1.88\\pm 0.18\\pm 0.28)\\times 10^{-3}. For the \\phi K+K- final state, the branching fractions, which are measured for the first time, are B(chi_c0,1,2-->\\phi K+K-)=(1.02\\pm 0.22\\pm 0.15)\\times 10^{-3}, (0.44\\pm 0.14\\pm 0.07)\\times 10^{-3}, and (1.46\\pm 0.21\\pm 0.22)\\times 10^{-4}. For the \\phi\\phi final state, B(chi_{c0,2}-->\\phi\\phi)=(0.94\\pm 0.21\\pm 0.14)\\times 10^{-3} and (1.48\\pm 0.26\\pm 0.23)\\times 10^{-3}.

2006-01-01

6

Production of cumulative pions and kaons

We calculate the masses of the resonances D{sub s0}{sup *}(2317) and D{sub s1}(2460) as well as their bottom partners as bound states of a kaon and a D{sup (*)} - and B{sup (*)} -meson, respectively, in unitarized chiral perturbation theory at next-to-leading order. After fixing the parameters in the D{sub s0}{sup *}(2317) channel, the calculated mass for the D{sub s1}(2460) is found in excellent agreement with experiment. The masses for the analogous states with a bottom quark are predicted to be M{sub B{sup *}{sub s0}}=(5696{+-}40) MeV and M{sub B{sub s1}}=(5742{+-}40) MeV in reasonable agreement with previous analyses. In particular, we predict M{sub B{sub s1}}-M{sub B{sub s0}}{sup *}=46{+-}1 MeV. We also explore the dependence of the states on the pion and kaon masses. We argue that the kaon mass dependence of a kaonic bound state should be almost linear with slope about unity. Such a dependence is specific to the ...

2011-02-15

7

Electromagnetic structure of decuplet baryons towards the chiral regime

#pi#"#+-# and K"#+-# cumulative production in pA #-># #pi#"#+-#+x and pA #-># K"#+-#+x reactions at 10.14 GeV proton beam energy on nuclei (Be-Ta) was invesigated. Measurements were conducted using FAS-1 focusing hadron spectrometer. Invariant cross sections of #pi#"#+-# and K"#+-# cumulative production, values of ratio of this cross sections, dependences of production cross sections for pions and kaons on cumulative number and mass number of nucleus target, as well as on transverse momentum are measured. Difference of cumulative meson spectra occurring in different nuclei fragmentation is discussed in terms of flucton model. 17 refs.; 14 figs.

1988-06-14

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Experimental Study of Hypernuclei Electroproduction by High Precision Spectroscopy

The electromagnetic properties of the baryon decuplet are calculated in quenched QCD on a 20{sup 3}x40 lattice with a lattice spacing of 0.128 fm using the fat-link irrelevant clover fermion action with quark masses providing a pion mass as low as 300 MeV. Magnetic moments and charge radii are extracted from the electric and magnetic form factors for each individual quark sector. From these, the corresponding baryon properties are constructed. We present results for the higher-order moments of the spin-3/2 baryons, including the electric-quadrupole moment E2 and the magnetic-octupole moment M3. The world's first determination of a nonzero M3 form factor for the {delta} baryon is presented. With these results we provide a conclusive analysis which shows that decuplet baryons are deformed. We compare the decuplet-baryon results from a similar lattice calculation of the octet baryons. We establish that the environment sensitivity is far ...

2009-09-01

9

Extraction of Kaon Formfactors from K->mu nu gamma Decay at ISTRA+ Setup

Jlab experiment E01-011, carried out in 2005 in JLab Hall C, is the second generation of the hypernuclear spectroscopy experiments by the (e,e{prime}K{sup +}) reaction. The (e,e{prime}K{sup +}) reaction is complimentary to the associated production reactions (K{sup -},{pi}{sup -}), ({pi}{sup +},K{sup +}) since, due to a larger momentum transfer to a hyperon, excitations of both spin-non-flip and spin-flip states are possible. The experiment uses high quality and continuous primary electron beam to produce neutron rich hypernuclei on various targets by the electroproduction. The experimental setup consists of splitter magnet, high resolution kaon spectrometer (HKS) and electron spectrometer (Enge) implemented in new configuration, the so called 'Tilt Method'. Production data was taken on multiple targets: CH{sub 2}, {sup 6}Li, {sup 7}Li, {sup 9}Be, {sup 10}B, {sup 12}C and {sup 28}Si. In present study the analysis of CH{sub ...

2009-12-01

10

Cumulative kaon production by 10 GeV protons

The radiative decay K->mu nu gamma has been studied at ISTRA+ setup in a new kinematical region. About 46K events of K->mu nu gamma have been observed. The sign and value of Fv-Fa have been measured for the first time. The result is Fv-Fa=0.16(4)(5).

2010-01-01

11

Tests of New Family Gauge Symmetry

The K"+- and K"-meson cumulative production cross sections are measured at 119"0 in the laboratory system on nuclei Be, Al, Cu and Ta bombarded by 10 GeV protons. Spectra of the K"-mesons consisting of only sea quarks show universal features characteristic of the spectra of cumulative particles, which contain valence quarks. Evidence is obtained for the fact that the energy density in a flucton can exceed the mean nuclear density by an order of magnitude.

12

Light Scalar Mesons as Manifestation of Spontaneously Broken Chiral Symmetry

We explore the structure of a new family gauge symmetry U(3) and show its experimental signatures to search for. U(3) gauge bosons obviate an unwelcome deviation of the charged lepton mass formula with the running masses from that with the pole masses. The current structure of this model leads to flavor number violations via exchange of extra gauge bosons. We obtain bounds on the masses of the gauge bosons from rare kaon decay searches and muonium-antimuonium oscillation searches. We propose attractive signatures at LHC and lepton colliders and discuss feasibility of their discovery.

2010-01-01

13

Neutrino tagging through secondary beam scraping

Attention is paid to the production mechanisms of light scalars that reveal their nature. We reveal the chiral shielding of the \\sigma(600) meson. We show that the kaon loop mechanism of the \\phi radiative decays, ratified by experiment, points to the four-quark nature of light scalars. We show also that the light scalars are produced in the two photon collisions via four-quark transitions in contrast to the classic P wave tensor q\\bar q mesons that are produced via two-quark transitions $\\gamma\\gamma\\to q\\bar q$. The history of spontaneous breaking of symmetry in quantum physics is discussed in Appendix.

2010-01-01

14

Particle physics -- Future directions

We discuss an experimental technique aimed at tagging electron neutrinos in multi-GeV artificial sources on an event-by-event basis. It exploits in a novel manner calorimetric and tracking technologies developed in the framework of the LHC experiments and of rare kaon decay searches. The setup is based on an instrumented decay tunnel equipped with tagging units that intercept secondary and tertiary leptons from the bulk of undecayed pi+ and protons. We show that the taggers are able to reduce the nue contamination originating from K_e3 decays by about one order of magnitude. Only a limited suppression (~60%) is achieved for nue produced by the decay-in-flight of muons; for moderate beam powers, similar performance as for K_e3 can be reached supplementing the tagging system with an instrumented beam dump.

2010-01-01

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Wonderful opportunities await particle physics over the next decade, with the coming of the Large Hadron Collider at CERN to explore the 1-TeV scale (extending efforts at LEP and the Tevatron to unravel the nature of electroweak symmetry breaking) and many initiatives to develop our understanding of the problem of identity: what makes a neutrino a neutrino and a top quark a top quark. Here I have in mind the work of the B factories and the Tevatron collider on CP violation and the weak interactions of the b quark; the wonderfully sensitive experiments at Brookhaven, CERN, Fermilab, and Frascati on CP violation and rare decays of kaons; the prospect of definitive accelerator experiments on neutrino oscillations and the nature of the neutrinos; and a host of new experiments on the sensitivity frontier. We might even learn to read experiment for clues about the dimensionality of spacetime. If we are inventive enough, we may be able to follow this rich menu with the ...

2001-11-29

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BOOKMARKS:

2. 1.3. 1.4. ...2.1. 2.2 . 2.3. ...2.4. 2.5. 2.6. 2.7.Global air temperature change Natural disasters linked to climate

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X

11. Preparation of natural radioactive materials

... 2.2372 2.4460 2.7184 2.5852 2.5108 2.6860 2.8912 2.2248 2.5216 2.6180 2.7788 2.2432 2.4036 2.0228 2.4476 2.1160 2.5268 1.9312 2.8700 2.4188 3.2144 ...

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Aereal view of Point 3.2.

Uranium and thorium ores are the source of natural radionuclides. Briefly described are the original and current methods of long-lived nuclide separation ("2"3"8U, "2"3"5U, "2"2"6Ra, "2"3"0Th, "2"3"1Pa, "2"2"7Ac, "2"3"2Th, "2"2"8Ra+"2"2"8Ac, "2"2"8Th), some short-lived nuclides ("2"3"4Th and "2"2"8Ac), radon, short-lived radon daughter products and long-lived radon daughter products ("2"1"0Pb, "2"1"0Bi, "2"1"0Po). Some nuclides, such as "2"1"0Po or "2"3"1Pa can more easily be producedin reactors. (Ha).

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2-[(4-MepyH)2]2+ - GLTRS - NASA

Aereal view of Point 3.2.

1998-01-01

20

Synthesis and Structural Characterization of a Novel Indium Mercapto Derivative [Clln(SCH2(CO)O)2]2-[(4-MepyH)2]2+

Synthesis and Structural Characterization of a Novel Indium Mercapto Derivative [Clln(SCH2(CO)O)2]2-[(4-MepyH)2]2+. AUTHOR(S): ...

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Quenching of the 2psub(1/2)-2psub(3/2) proton spin-orbit splitting in the Sr-Zr region

The synthesis and structural characterization of a novel In(III) complex is described. The reaction

2004-01-01

22

RADC RELIABILITY PHYSICS NOTEBOOK

The constancy in excitation energy of the lowest 2/sup +/ state in the Sr isotopes across the N=56 subshell closure is shown to result from a reduction in the 2psub(1/2)-2psub(3/2) proton spin-orbit splitting as the 2dsub(5/2) neutron orbital is filled.

1984-06-14

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Level structure of "2"1"6At

... 2-37 2.3.1.5.4 Imperfect Bonding of Die ..... 2-37 2.3.1.5.5 "Purple Plague" .... 2-37 2.3.1.5.6 Tool Damage ..... 2-37 ...

1965-10-01

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Polythermal study of the M(ClO_4)_2-H_2O systems, where M"2 = Mg"2"+, Ca"2"+, Sr"2"+, Ba"2"+

The level structure and configurations of "2"1"6At have been studied by observing the alpha decay of "2"2"0Fr, which is in secular equilibrium with "2"2"4Ac. Six of the 16 observed states are tentatively assigned to the configuration #pi#(h_9_/_2)"3#upsilon#(g_9_/_2)"5, and four to the mixed configuration #pi#(h_9_/_2)"3#upsilon#(g_9_/_2)"4(i_1_1_/_2)+#pi#(h_9_/_2)"2(f _7_/_2)#upsilon#(g_9_/_2)"5. These two configurations in "2"1"6At are compared with the corresponding configurations in "2"1"2Bi and "2"1"0Bi. The shape transitions are traced from the quadrupole-octupole deformed "2"2"4Ac through "2"2"0Fr and "2"1"6At, to ...

25

Alpha decay of "2"1"6At and the level structure of "2"1"2Bi

Crystallization points of aqueous solution of the systems M(ClO_4)_2-H_2O (M"2 = Mg"2"+, Ca"2"+, Sr"2"+, Ba"2"+), depending on the salt concentration, were identified by visual-polythermal method. Relying on model notions on the structure of the electrolyte solutions, specific features of strontium perchlorate solubility polytherm and concentration dependence of the relative dynamic viscosity of the salt aqueous solutions are discussed

2005-03-01

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Superconductivity in the ternary rare-earth (Y, La, and Lu) compounds RPd_2Si_2 and RRh_2Si_2

The level structure of "2"1"2Bi has been studied by observing the alpha decay of "2"1"6At which is in secular equilibrium with "2"2"0Fr and "2"2"4Ac. Eight states are observed and tentatively assigned to the configuration #pi#h_9_/_2#nu#(g_9_/_2)"3 and three to the configuration #pi#h_9_/_2#nu#(g_9_/_2)"2i_1_1_/_2. These two lowest configurations in "2"1"2Bi are compared with the corresponding configurations in "2"1"0Bi and the calculations of Warburton.

27

On Low Energy Levels in 185W

We have investigated the superconducting and metallurgical properties of the ternary compounds RPd_2Si_2 and RRh_2Si_2 with R = Y, La, and Lu. All RPd_2Si_2 compounds and LaRh_2Si_2 were found to be type-I superconductors below 1 K. A detailed metallurgical analysis shows that segregation of second phases can easily mask the intrinsic (stoichiometric ratio 1:2:2) intermetallic-compound properties. Two sample-preparation techniques, viz., single crystals and off-stoichiometry, were utilized to establish where bulk superconductivity occurs. The type-I behavior of these compounds is explained with an analogous model as is used for the heavy-fermion superconductors CeCu_2Si_2 and URu_2Si_2.

28

The method and results of measurements of "2"2"2Rn emanation from building materials

Gamma ray spectra in the decay of 185Ta and 185mW have been studied with Ge (Li) detectors. The 185mW isomeric transition at 131.6 keV is shown to be of E3 multipolarity. A level scheme of 185W is proposed with the following energy levels (energies in keV, spin and K quantum numbers in brackets): 0 (3/2- 3/2), 23.5 (1/2- 1/2), 65.9 (5/2- 3/2), 93.5 (3/2- 1/2) (uncertain), 173.9 (7/2- 3/2), 188.1 (5/2- 1/2), 197.5 (11/2+ 11/2) , 243.5 (7/2- 7/2), and 390.8 (9/2- 7/2)

1996-03-04

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Total and spontaneous fission half-lives of the americium and curium nuclides

The method and results are presented of measurements of the coefficients of "2"2"2Rn emanation from samples of fly- ashes and slag and other commonly used building materials. A chamber was used for electrostatic collection of "2"2"2Rn decay products. The coefficients of emanation ranged from 0.2% (fly- ashes) to 21.3% (phosphogipsum from phosphorit). (author).

1979-01-01

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Alpha-spectrometric determination of uranium, plutonium, americium and curium isotope content in 'hot' particles and irradiated nuclear fuel

The total half-life and the half-life for spontaneous fission are evaluated for the various long-lived nuclides of interest. Recommended values are presented for "2"4"1Am, "2"4"2Am, "2"4"3Am, "2"4"2Cm, "2"4"3Cm, "2"4"4Cm, "2"4"5Cm, "2"4"6Cm, "2"4"7Cm, "2"4"8Cm, and "2"5"0Cm. The uncertainties are provided at the 95% confidence limit for each of the recommended values. (author).

1985-06-01

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Total and spontaneous fission half-lives for uranium, plutonium, americium and curium nuclides

A method for express determination of "2"3"4"-"2"3"8U, "2"3"8"-"2"4"2Pu, "2"4"1"-"2"4"3Am and "2"4"2"-"2"4"4Cm content in fuel 'hot' particles and spent nuclear fuel is offered. The method is based on precision measurement of a sample #alpha# activity followed by estimate of relative contributions of individual nuclides, or groups of radionuclides, to total activity. Segregation in separate fractions of uranium, plutonium, americium and curium was made with the help of ion-exchange chromatography. Results are presented of "2"3"4"U, "2"3"8U, "2"3"8"Pu,"2"3"9"+"2"4"0Pu, "2"4"1Pu, "2"4"2Pu, "2"4"1"Am, "2"4"2"mAm, "2"4"3Am "2"4"2"Cm and "2"4"4Cm definition in 'hot' particles ...

32

High-field magnetization of CeRh{sub 2}Si{sub 2} and CePd{sub 2}Si{sub 2}

Measurements of the half-lives of some long-lived nuclides of elements Z = 92, 94, 95 and 96 have been compiled and evaluated. Recommended values are presented for "2"3"2"-"2"3"6","2"3"8U, for "2"3"6","2"3"8"-"2"4"2","2"4"4Pu, for "2"4"1","2"4"2"m","2"4"3Am, and for "2"4"2"-"2"4"8","2"5"0Cm. Values are presented for both spontaneous fission half-life and total half-life. Problems with reported uncertainties are also discussed. (author).

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High-field magnetization of CeRh_2Si_2 and CePd_2Si_2

High-field magnetization properties of single crystalline CeRh{sub 2}Si{sub 2} and CePd{sub 2}Si{sub 2} were investigated. Two-step metamagnetic transition (H{sub c1}=25.4 T and H{sub c2}=26.0 T) was observed in the case of CeRh{sub 2}Si{sub 2}, whereas no anomaly was found in the magnetization process of CePd{sub 2}Si{sub 2} up to 28 T. The mean field analysis has shown that CeRh{sub 2}Si{sub 2} is quite anisotropic compared to CePd{sub 2}Si{sub 2}, which results in the sharp contrast between the magnetization processes of the two compounds.

1998-07-01

34

Performance Evaluation of the ONR Axial Waterjet 2 (AxWJ-2)

High-field magnetization properties of single crystalline CeRh_2Si_2 and CePd_2Si_2 were investigated. Two-step metamagnetic transition (H_c_1=25.4 T and H_c_2=26.0 T) was observed in the case of CeRh_2Si_2, whereas no anomaly was found in the magnetization process of CePd_2Si_2 up to 28 T. The mean field analysis has shown that CeRh_2Si_2 is quite anisotropic compared to CePd_2Si_2, which results in the sharp contrast between the magnetization processes of the two compounds

1997-08-04

35

Hart, W. D. - NASA Technical Reports Server

... Waterjet 2 (AxWJ-2) by ... 4. TITLE AND SUBTITLE Performance Evaluation of the ONR Axial Waterjet 2 (AxWJ-2) 5a. CONTRACT NUMBER 5b. ...

2009-12-01

36

Magnetic properties of CeRh_2Si_2 and CePd_2Si_2 single crystals

Mar 1, 2011 ... DIES (2) [x] : WELDING (2) [x] : GAS PRESSURE (2) [x] : WELD STRENGTH (2) [x] : MAGNETIC FORMING (2) [x] : FUSION WELDING (2) [x] ...

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WCOORDINAMTE SCIENCE ABOA TOVRY - NASA Technical Reports Server

Single-crystalline CeRh_2Si_2 and CePd_2Si_2 were grown by the Czochralsky pulling method and the temperature dependence of magnetic susceptibility was investigated. The crystalline electric field (CEF) states in each compound were determined by considering the tetragonal CEF Hamiltonian with mean-field approximation. Interactions between Ce"3"+ ion and the surrounding ligands in CeRh_2Si_2 turned out to be strong and highly anisotropic in comparison to CePd_2Si_2. (orig.)

1998-01-01

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2.1.1 Stochastic decision and control approaches .... 14. 2.1.2 Queueing theory ...... Infoton Vistar/2 terminal keyboard) is used by the pilot for ...

39

Two 2D SPH Simulations

TmPd_2Si_2 and YbPd_2Si_2. Crystal fields and intermediate valence

Not Available

2006-01-01

40

Preliminary design and cost considerations for a plant to produce nuclear purity uranium dioxide from Australian ore concentrates

... low temperature moessbauer effect palladium silicides thulium silicides thulium

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

41

Newer systems for bacterial resistances to toxic heavy metals.

... 2.1 Yellow Cake Specification3 Storage and Handling 2.2 Dissolution 2.3

1976-09-06

42

Fusion of Imaging and Inertial Sensors for Navigation

Bacterial plasmids contain specific genes for resistances to toxic heavy metal ions including Ag+, AsO2-, AsO4(3-), Cd2+, Co2+, CrO4(2-), Cu2+, Hg2+, Ni2+, Pb2+, Sb3+, and Zn2+. Recent progress with...Full Text Available

1994-09-01

43

A study of the interactions of some polypyridylruthenium (II) complexes with DNA using fluorescence spectroscopy, topoisomerisation and thermal denaturation.

... 2.5.6 Development of Observation Equations . . . . . 25 2.6 Inertial Navigation Error Model . . . . . ... 2 , as expected. 2.6 Inertial Navigation Error Model ...

2006-09-01

44

Structures and luminescent properties of new uranyl-based hybrid materials

The nature of binding of Ru(phen) 2+ (I), Ru(bipy) 2+ (II), Ru(terpy) 2+ (III) (phen = 1,10-phenanthroline, bipy 3 = 2,2'-bipyridyl, 3 terpy = 2,2'2," - 2 terpyridyl) to DNA, poly[d(G-C)] and poly[d(A-T)]...Full Text Available

1985-09-11

45

Magnetic characteristic of some TCu_2Si_2 ternary alloys (T = Nd, Dy, Ho, Er, Tm, Y, and La)

Six uranyl coordination compounds, UO_2(OH)(PYCA) (1), UO_2(PYCA)_2(H_2O).2H_2O (2), UO_2(PIC)_2 (3), UO_2(H_2O)_2(NIC)_2 (4), UO_2(OH)(HINIC)(INIC) (5), and UO_2(PYTAC)_2(H_2O)_2 (6) were grown as single crystals via hydrothermal synthesis (PYCA - pyrazine-2-carboxylate, PIC - picolinate, NIC - nicotinate, INIC - iso-nicotinate, and PYTAC - 2-(pyridin-4-yl)thiazole-5-carboxylate) to study their optical properties. All six compounds have been identified via single crystal X-ray diffraction and fully characterized via powder X-ray diffraction, infrared spectroscopy, UV-Vis ...

2011-06-01

46

Influence of some selected organic molecules on intensity of luminescence of TiO2:Eu3+ electrodes

Magnetic characteristics of the ternary alloys TCu_2Si_2 (T = Nd, Dy, Ho, Er, and Tm) have been investigated. Magnetic susceptibility measurements were carried out between 4.2 and 150 K and in magnetic fields of 1 to 18 kOe, using a vibrating sample magnetometer. The Curie-Weiss law is followed by NdCu_2Si_2 above 30 K, by DyCu_2Si_2 and HoCu_2Si_2 above 50 K, and by ErCu_2Si_2 and TmCu_2Si_2 above 9 K. Furthermore, the Curie paramagnetic temperatures are given.

1981-12-01

47

Fine structure excitation transfer between the potassium 4"2P states induced by collisions with caesium atoms

Eu3+ ions are anchored on TiO2 matrix by coupling with 2,2'-bipyridyl 4,4'-dicarboxylic acid. Five different luminescence centers are observed for TiO2|2,2'-bipyridyl 4,4'-dicarboxylic acid|Eu3+ electrodes due to electron transitions between d and f orbitals. Photo-luminescence of TiO2|2,2'-bipyridyl 4,4'-dicarboxylic acid|Eu3+ electrodes is increased by attaching 2-thenoyltrifluoroacetone to Eu3+ ions. Immersion of TiO2|2,2'-bipyridyl 4,4'-dicarboxylic acid|Eu3+|2-thenoyltrifluoroacetone electrodes in propylsulfide is found to be further increased intensities of luminescence bands by a factor of three.

2009-05-01

48

Equilibrium and pre-equilibrium emissions in proton-induced reactions on "2"0"3","2"0"5Tl

Applying diode-laser resonant fluorescence method, the cross sections for the excitation energy transfer of the collisional process K"*(4"2P_1_/_2)+Cs(6"2S_1_/_2)#reversible#K"*(4"2P_3_/_2)+Cs(6"2S_1_/_2) have been measured. The values we have obtained are #sigma#(1/2#->#3/2)=77 A"2 and #sigma#(3/2#->#1/2)=48 A"2. These results complete the sequence of data for the fine-structure mixing of the first-resonance states of alkali atoms colliding with the ground-state caesium atoms. (orig.).

49

Synthesis of [3,3-D[sub 2

In this study, the excitation functions for the reactions "2"0"3Tl(p, n)"2"0"3Pb, "2"0"5Tl(p, 3n)"2"0"3Pb, "2"0"3Tl(p, 2n)"2"0"2Pb, "2"0"5Tl(p, 4n)"2"0"2Pb, "2"0"3Tl(p, 3n)"2"0"1Pb, "2"0"5Tl(p, 5n)"2"0"1Pb, "2"0"3Tl(p, 4n)"2"0"0Pb and "2"0"5Tl(p, 6n)"2"0"0Pb have been calculated using pre-equilibrium and equilibrium reactions mechanisms. Calculated results based on hybrid model, geometry-dependent hybrid model and cascade-exciton model have been compared with the experimental data. (author)

2009-02-01

50

Synthesis and structure of the (tetrahydroxy)oligosiloxane [(tBuO)3SiOSi(OH)2]2O

The synthesis of [3, 3-D[sub 2

1993-01-01

51

Specific heat and magnetic properties of Ce(Ru{sub 1-x}Pd{sub x}){sub 2}Si{sub 2}

No abstract prepared.

2000-01-25

52

Specific heat and magnetic properties of Ce(Ru_1_-_xPd_x)_2Si_2

In Ce(Ru{sub 1-x}Pd{sub x}){sub 2}Si{sub 2} the dilution of the transition metal leads to strong electronic effects resulting in the disappearance and the appearance of long-range magnetic order in CePd{sub 2}Si{sub 2} and CeRu{sub 2}Si{sub 2}, respectively. ((orig.)).

1995-02-01

53

Relationship Between Gestational Diabetes and Type 2 Diabetes

In Ce(Ru_1_-_xPd_x)_2Si_2 the dilution of the transition metal leads to strong electronic effects resulting in the disappearance and the appearance of long-range magnetic order in CePd_2Si_2 and CeRu_2Si_2, respectively. ((orig.)).

54

Phenomenological 2 D-#chi#_2 analysis for AGS pion interferometry data

Gestational Diabetes; Type 2 Diabetes

2011-04-21

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Next Generation SSH2 Implementation Securing Data in Motion

Short communication.

1994-10-04

56

Molar extinction coefficients in aqueous solutions of some alkaline earth chlorides

Next Generation SSH2 Implementation

2008-01-01

57

Magnetic phase transition in UPd_2Si_2

Molar extinction coefficients for the solid solutes in aqueous solutions of some alkaline earth chlorides such as MgCl_2.6H_2O, CaCl_2, SrCl_2.6H_2O and BaCl_2.2H_2O have been determined at 81, 356, 511, 662, 1173 and 1332 keV energies in different concentration using the narrow beam transmission methods. (author)

1999-12-21

58

Evolution of a bifunctional enzyme: 6-phosphofructo-2-kinase/fructose-2,6-bisphosphatase.

... fields magnetic moments neel temperature neutron diffraction order-disorder

59

Electrospun Nanofibrous Polyacrylonitrile(PAN)/ Fe2O3 Membrane as Co2Gas Sensor

The bifunctional rat liver enzyme 6-phosphofructo-2-kinase/fructose-2,6-bisphosphatase (ATP:D-fructose-6-phosphate 2-phosphotransferase/D-fructose-2,6-bisphosphate 2-phosphohydrolase, EC 2.7.1.105/EC...Full Text Available

1989-12-01

60

Assembly Mechanism of [Fe2S2] Cluster in Ferredoxin from Acidithiobacillus ferrooxidans.

Full Text Available

2007-04-01

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

61

An Introduction to the Standard Theory of Electroweak Interactions (2/4)

Full Text Available

2011-02-01

62

Admissible representations and characters of the affine superalgebras osp(1,2) and sl(2/1)

An Introduction to the Standard Theory of Electroweak Interactions (2/4)

2011-01-01

63

Light Sterile Neutrino Effects at theta_13-Sensitive Reactor Neutrino Experiments

No abstract prepared.

1998-07-01

64

Control of Apple Ripening by Succinic Acid 2,2-Dimethyl Hydrazide, 2-Chloroethyltrimethylammonium Chloride, and Ethylene ¹

We study the impact of very light sterile neutrinos (Delta m^2_new around 1 to 10 times 10^(-2) eV^2, sin^2 2theta_new<10^(-1)) on upcoming theta_13-driven reactor antineutrino experiments like Double-CHOOZ and Daya Bay. Oscillations driven by these vales of Delta m^2_new affect data in the near and far detectors differently and hence potentially modify the capability of these experimental setups to constrain and measure sin^2 2theta_13. We find that the hypothesis theta_new different from zero negatively impacts one's ability to either place an upper bound on sin^2 2theta_13 in the advent of no oscillation signal or measure sin^2 2theta_13 if a theta_13-driven signal is observed. The impact of sterile neutrino effects, however, ...

2008-01-01

65

+ 2004 - The NASA Glenn Research Center Technical Report Server

Ripening of `Tydeman's Early' apples (Malus sylvestris L.) assessed by the occurrence of the respiratory climacteric was delayed by succinic acid 2,2-dimethyl hydrazide (B-9) but not...Full Text Available

1969-08-01

66

Soil to plant transfer of "2"3"8U, "2"2"6Ra and "2"3"2Th on a uranium mining-impacted soil from southeastern China

May 31, 2011 ... Synthesis and Structural Characterization of a Novel Indium Mercapto Derivative [Clln(SCH2(CO)O)2]2-[(4-MepyH)2]2+. 284. System Mass ...

67

Synthesis and Structural Characterization of a Novel Indium Mercapto Derivative (Clln(SCH2(CO) O)2)2-((4-MepyH)2)2+.

Both soil and plant samples of nine different plant species grown in soils from southeastern China contaminated with uranium mine tailings were analyzed for the plant uptake and translocation of "2"3"8U, "2"2"6Ra and "2"3"2Th. Substantial differences were observed in the soil-plant transfer factor (TF) among these radionuclides and plant species. Lupine (Lupinus albus) exhibited the highest uptake of "2"3"8U (TF value of 3.7x10"-"2), while Chinese mustard (Brassica chinensis) had the least (0.5x10"-"2). However, in the case of "2"2"6Ra and "2"3"2Th, the highest TFs were observed for white clover (Trifolium pratense) (3.4x10"-"2) and ryegrass (Lolium perenne) (2.1x10"-"3), respectively. "2"3"2Th in the tailings/soil mixture was less available for plant uptake ...

1000-01-01

68

Gastrointestinal absorption of transuranic elements by rats

The synthesis and structural characterization of a novel In(III) complex is described. The reaction between InCl3 with sodium mercapto-acetic acid, (NaSCH2(CO)OH) in 4-methylpyridine, (CH3(C5H5N), (4-Mepy)) at 25 C affords (ClIn(SCH2(CO)O)2)2- ((4-MepyH)2...

2004-01-01

69

Synthesis and characterization of luminescent square-planar platinum(II) complexes containing dithiolate or dithiocarbamate ligands

Absorption of ''organically bound'' "2"3"3U and "2"4"1Am from gastrointestinal tracts of adult rats was twice that of the inorganic nitrate form. There was no difference between transport of "2"3"2U and "2"3"3U by adult rats, but "2"3"2U absorption by newborn rats was four times that of "2"3"3U. Absorption of "2"3"8Pu nitrate through the gut of the newborn is relatively insensitive to dose but incorporation in the gut mucosa saturates at high dose levels. Absorption of "2"3"8Pu is greater at 4 hr of age than at 24 hr.

1977-05-01

70

Intercombination transitions in beryllium-like and boron-like iron

The synthesis, characterization, and emission properties of a series of Pt(L{sub 2})(S-S) complexes are reported. The (L{sub 2}) ligands include 4,7-diphenyl-1,10-phenanthroline (Ph{sub 2}phen), 4,4{prime}-dimethyl-2,2{prime}-bipyridine (Me{sub 2}bpy), 1,5-cyclo-octadiene (COD), trimethyl phosphite (P(OMe){sub 3}), and the {alpha}-C-deprotonated form of 2-phenylpyridine (2-phpy). The (S-S) ligands include 1-(tert-butoxycarbonyl)-1-cyanoethylene-2,2-dithiolate (tbcda), 1-(diethoxyphosphinyl)-1-cyanoethylene-2,2-dithiolate (cpdt), cis-1,2-dicarbomethoxyethylene-1,2-dithiolate (met), and N,N-diethyldithio-carbamate (Et{sub 2}dtc). The complexes are readily synthesized by the addition of the dithiolate or thiolate ligand to Pt(L{sub ...

1994-06-22

71

Magnetism of DyPd_2Si_2 and ErPd_2Si_2

Beam-foil spectroscopy techniques have been used to study intercombination transitions in Be-like Fe{sup 22+} and B-like Fe{sup 21+}. The method of time delayed spectroscopy was used to identify the Be-like 2s{sup 2} {sup 1}S{sub 0}-2s2p {sup 3}P{sub 1} and B-like 2s{sup 2}2p {sup 2}P{sub 3/2}-2s2p{sup 2} {sup 4}P{sub 5/2} transitions. Intensity decay curves for these transitions were recorded and level lifetimes were obtained. The latter were found to be 17.5 {+-} 1.5 ns for the Be-like 2s2p {sup 3}P{sub 1} level and 14.8 {+-} 1.0 ns for the B-like 2s2p{sup 2} {sup 4}P{sub 5/2} level. (orig.).

1997-04-01

72

ZZ UKFY2, Fission Yields of Th, U, Np, Pu, Am, Cm, Cf Isotopes

Neutron diffraction and magnetometric measurements on polycrystalline samples of DyPd_2Si_2 and ErPd_2Si_2 were carried out in the temperature range from 2 to 293 K. Both compounds show tetragonal ThCr_2Si_2 type crystal structure and order at 12 K in a sine modulated magnetic structure with propagation vectors k=[0.609,0,0.155] and [0.575, 0, 0.083] respectively. The oscillatory character of magnetic order found in RPd_2Si_2 (R=Tb-Er) compounds suggests exchange interaction described by the RKKY model to be dominant, but the non-monotonic dependence of respective Neel temperatures on the number of f-electrons indicates the influence of a crystalline electric field (CEF) on the magnetic behaviour in this series. (orig.).

73

Superconductivity in the ternary rare-earth (Y, La, and Lu) compounds RPd/sub 2/Si/sub 2/ and RRh/sub 2/Si/sub 2/

Description of program or function: Format: ENDFB-6 format; Nuclides: Th-232, U-233, U-234, U-235, U-236, U-238, Np-237, Np-238, Pu-238, Pu-239, Pu-240, Pu-241, Pu-242, Am-241, Am-242, Am-243, Cm-243, Cm-244, Cm-245, and from the spontaneous fission of Cm-242, Cm-244, and Cf-252. Origin: New evaluation (Crouch 1, 2, 3, 4; UKFY1; JEF-1). A new evaluation of fission product yields from the thermal, fast, and 14 MeV neutron-induced fission of the following nuclides has been prepared in ENDFB-VI format: "2"3"2Th, "2"3"3U, "2"3"4U, "2"3"5U, "2"3"6U, "2"3"8U, "2"3"7Np, "2"3"8Np, "2"3"8Pu, "2"3"9Pu, "2"4"0Pu, "2"4"1Pu, "2"4"2Pu, "2"4"1Am, "2"4"2"mAm, ...

74

Positron annihilation in high-T/sub c/ superconductors

We have investigated the superconducting and metallurgical properties of the ternary compounds RPd/sub 2/Si/sub 2/ and RRh/sub 2/Si/sub 2/ with R = Y, La, and Lu. All RPd/sub 2/Si/sub 2/ compounds and LaRh/sub 2/Si/sub 2/ were found to be type-I superconductors below 1 K. A detailed metallurgical analysis shows that segregation of second phases can easily mask the intrinsic (stoichiometric ratio 1:2:2) intermetallic-compound properties. Two sample-preparation techniques, viz., single crystals and off-stoichiometry, were utilized to establish where bulk superconductivity occurs. The type-I behavior of these compounds is explained with an analogous model as is used for the heavy-fermion superconductors CeCu/sub 2/Si/sub 2/ and URu/sub ...

1986-10-01

75

Molar extinction coefficients of some fatty acids

We report ab initio calculations of positron wave functions in the high-T/sub c/ superconductors YBa_2Cu_3O_7, Bi_2Sr_2CaCu_2O_8, and Tl_2Ba_2CaCu_2O_8 using the general potential linearized augmented plane-wave method. The calculated positron wave functions are fairly insensitive to whether or not electron-positron correlation is included in the calculation for YBa_2Cu_3O_7 and Tl_2Ba_2CaCu_2O_8, but the calculated positron density is quite sensitive to correlation in Bi_2Sr_2CaCu_2O_8. While the positron wave function samples primarily the chain region in YBa_2Cu_3O_7, the results indicate that positrons should be good probes of the Cu-O layer-derived electronic states near ...

76

Magnetic properties of Y_2Cu_2O_5, Y_2BaCuO_5, and Y_2Ba_2O_5 compounds

The attenuation of gamma rays in some fatty acids, viz. formic acid (CH_2O_2), acetic acid (C_2H_4O_2), propionic acid (C_3H_6O_2), butyric acid (C_4H_8O_2), n-hexanoic acid (C_6H_1_2O_2), n-caprylic acid (C_8H_1_6O_2), lauric acid (C_1_2H_2_4O_2), myristic acid (C_1_4H_2_8O_2), palmitic acid (C_1_6H_3_2O_2), oleic acid (C_1_8H_3_4O_2) and stearic acid (C_1_8H_3_6O_2), has been measured at the photon energies 81, 356, 511, 662, 1173 and 1332 keV. Experimental values for the molar extinction coefficient, the effective atomic number and the electron density have been derived and compared with theoretical ...

2002-10-01

77

Unusual heterogeneity of the 5'-termini of human adenovirus type 2 early region E2 mRNA.

The magnetic susceptibility of Y_2Cu_2O_5, Y_2BaCuO_5, and Y_2Ba_2O_5 single-phase compounds in weak magnetic fields (H_0=0.1--20 Oe) and moderate magnetic fields (H_0#=#0.2 Oe it converts into a paramagnetic maximum #chi#(T) which corresponds to an antiferromagnetic transition. In a moderate magnetic field H=500 Oe a normal Curie-Weiss law, #chi##approx##mu#"2_e_f_f (T-#theta#) is observed. At temperatures T=150--300 K, #theta#=38 K and #mu#_e_f_f#approx#2.2 #mu#_B/at. Cu. At T<150 k the temperature dependence of #chi# is described by a simple Curie law with #theta##approx#0. Although the paramagnetic signal is extremely weak, in the Y_2Ba_2O_5 compound the curve of #chi#(T, H_0=100 Oe) for a Y_2ba_2O_5 sample exhibits a slightly ...

1989-01-01

78

Thermal conductivity of simple molecular substances at crystal-liquid phase transition

The 5'-terminal structures of human adenovirus type 2 (Ad2) early region 2 (E2) mRNA were investigated. The E2 transcription unit has several interesting properties, including the presence of a TATA-like...Full Text Available

1984-12-11

79

The K3 Fragment of Amyloidogenic ?₂-Microglobulin Forms Ion Channels: Implication for Dialysis Related Amyloidosis

By the example of CH2Cl2, CF2Cl2, CHF2Cl, C2F6, C2H6, SF6 and C6H12 we have investigated the isobaric thermal conductivity jump at crystal-liquid phase transition. It is shown that the reduction in the thermal conductivity at melting derives from the degree of orientational ordering of the crystals at pre-melting point.

2009-01-01

80

Stable halogen complexes of astatine cations in aqueous solutions

;2;₂-microglobulin (;2;₂m) amyloid deposits are linked to dialysis related amyloidosis (DRA) in hemodialysis patients. The mechanism by which ;2;₂m...Full Text Available

2009-10-21

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

81

Solvent isotope effect on the quartet #-># doublet intersystem crossing efficiencies of Cr(bpy)_3"3"+ and Cr(phen)_3"3"+"1

Halide complexes of astatine cations At"+ and AtO"+ were prepared and their rate of migration was measured. The complexes are of the type AtX_2"- and AtOX_2"- (X = Cl"-, Br"-, I"-). The bromo complexes, AtBr_2"- and AtOBr_2"-, have a higher stability than the chloro complexes. The hydrolysis in weakly alkaline solution of AtX_2"- resulted At"-, and that of AtOX_2"- AtO_2"-. (author).

82

Role of protracted exposure on the toxicology of inhaled "2"3"9PuO_2

The intensity of luminescence from the "2E state of Cr(bpy)_3"3"+ (bpy = 2, 2'-bipyridine) is lower in D_2O, although the "2E lifetime is unchanged, indicating that the "4T_2 (precursor to "2E) is sensitive to the isotopic nature of the solvent. A photophysical mechanism is proposed for Cr(NN)_3"3"+ complexes.

83

Growth differentiation factor-9 stimulates progesterone synthesis in granulosa cells via a prostaglandin E₂/EP2 receptor pathway

Studies were initiated to examine in rats the effects of a protracted exposure to inhaled "2"3"9PuO_2. Graphs are presented to show effect of multiple exposures to "2"3"9PuO_2 on the deposition and clearance of "2"3"9Pu in the alveoli.

1977-05-01

84

Electron scattering in molecular aggregates

Growth differentiation factor-9 (GDF-9), an oocyte-secreted member of the transforming growth factor ;2; superfamily, progesterone receptor, cyclooxygenase 2 (Cox2; Ptgs2), and the EP2 prostaglandin...Full Text Available

2000-08-29

85

Early disposition of inhaled uranyl nitrate ("2"3"2U and "2"3"3U) in rats

In this contribution we compare the electron scattering processes observed in pure O_2 clusters and mixed clusters like O_2/Ne, O_2/Ar and O_2/N_2. The overlap and positions of the potential curves of O_2 states show the different possible electron attachment processes and also explain the formation of O_2 in clusters. (author).

1994-03-20

86

Magnetic properties of some RPd_2Si_2 compounds (R = Gd, Tb, Dy, Ho and Er)

Uranyl nitrate ("2"3"3U) was retained mainly in lung, skeleton, pelt and kidney 60 days after inhalation exposure. The concentration in lung exceeded that in other tissues. Preliminary results with "2"3"2U indicate retention in lung similar to that of "2"3"3U, at total deposited mass levels of 0.1 #mu#g or less.

1977-05-01

87

Lithium ionic conductivity in LiI?Li2S?La2O2Sm (m=1, 2) composite electrolyte by solid state reaction

The magnetic susceptibility of the ternary compounds, RPd_2Si_2 (where R=Gd, Tb, Dy, Ho and Er) has been measured. GdPd_2Si_2 and TbPd_2Si_2 order antiferromagnetically at 13 and 20 K respectively; the rest of the compounds do not show clear ordering down to 4.2 K. Palladium carries no moment in these compounds. The De Gennes formula is not obeyed indicating that the exchange interaction between the 4f moments via conduction electrons is not isotropic. (orig.).

88

British Library Electronic Table of Contents (United Kingdom)

New lithium ion composite electrolyte, LiI?Li2S?La2O2Sm (m=1, 2) was synthesized from the binary Li2S?LaOI system through solid state reaction. The lithium ion conductive property was investigated by AC impedance spectroscopy. And the highest conductivity of the obtained electrolyte at room temperature was found to be 3.0?10?6?S cm?1. The notable ionic conduction was attributed to the in situ formed amorphous LiI.

2008-01-01

89

Identification of the #pi#g_9_/_2 band new levels in "1"2"1Cs

Mobilities of CO_2"+ and N_2O"+ in He, Ar and N_2 gases

The #pi#g_9_/_2 band structure in "1"2"1Cs is obtained. The experiment was performed at the HI-13 MV tandem accelerator of China Institute of Atomic Energy. The excited states of "1"2"1Cs were populated via the reaction "1"1"2Sn("1"2C, p2n). The #gamma#-#gamma# coincidence data were taken with five BGO-AC HpGe detectors at beam energy of 60 Mev. The energy-level schemes of "1"2"1Cs is presented.

1992-01-01

90

Magnetic properties of CeRh{sub 2}Si{sub 2} and CePd{sub 2}Si{sub 2} single crystals

... argon carbon dioxide cations electric fields gases helium ion mobility molecular

1976-01-01

91

Laboratory Description of Harbor Idealized Tests. Volume 1 ...

Single-crystalline CeRh{sub 2}Si{sub 2} and CePd{sub 2}Si{sub 2} were grown by the Czochralsky pulling method and the temperature dependence of magnetic susceptibility was investigated. The crystalline electric field (CEF) states in each compound were determined by considering the tetragonal CEF Hamiltonian with mean-field approximation. Interactions between Ce{sup 3+} ion and the surrounding ligands in CeRh{sub 2}Si{sub 2} turned out to be strong and highly anisotropic in comparison to CePd{sub 2}Si{sub 2}. (orig.) 10 refs.

1998-01-01

92

Kinetic energy dependence of the reactions of N"+ ions with NO, CO, CO_2, N_2O and SO_2

... modules 2 and 3, 45 ft from each end) in a ... The toe of the stone revetment was 2 ft out from the ... in parentheses are for the current meters in layout 2. ...

1993-03-01

93

Electrochemical and optical properties of sol-gel derived CeO{sub 2} and mixed CeO{sub 2}/SnO{sub 2} coatings

... kinetics chemical reactions energy dependence ion-molecule collisions milli

1977-07-01

94

Curium isotopes and americium-242 m in Irish Sea sediment

Ion storage CeO{sub 2} and CeO{sub 2}/SnO{sub 2} coatings were prepared by sol-gel dip-coating method using aqueous-based process. The influence of added SnO{sub 2} in the CeO{sub 2} oxide coatings on the inserted/extracted charge was determined by chronocoulometric measurements. It was found that for 60 nm thick film the inserted/extracted charge was twice larger (Q = 10mC/cm{sup 2}) for films containing 17 mol % SnO{sub 2} if compared to pure CeO{sub 2}. The addition of SnO{sub 2} to the mixed oxides coatings on their optical properties and structural characteristics were studied.

1994-12-31

95

Comparison of antioxidant abilities of magnolol and honokiol to scavenge radicals and to protect DNA

An intertidal estuarine sediment core was collected from Esk Estuary in the Irish Sea which had been contaminated by low-level radioactive liquid effluent from the nuclear fuel reprocessing plants at Sellafield, UK. The "2"4"2Cm and "2"4"3","2"4"4Cm radioactivity concentrations were determined to establish the present contamination levels compared with other radionuclides "1"3"7Cs, "2"3"7Np, "2"3"8Pu, "2"3"9","2"4"0Pu, "2"4"1Pu and "2"4"1Am. The results showed that "2"4"2Cm and "2"4"4Cm existed in the detectable levels in the Irish Sea sediment and the concentration of "2"4"2"mAm was evaluated from that of "2"4"2Cm. The "2"4"2"mAm/"2"3"9","2"4"0Pu and "2"4"4Cm/"2"3"9","2"4"0Pu ...

96

British Library Electronic Table of Contents (United Kingdom)

The antioxidant properties of magnolol and honokiol were evaluated in the experimental systems of reducing ONOO^- and ^1O"2, bleaching @b-carotene in linoleic acid (LH) emulsion, and trapping 2,2'-azinobis(3-ethylbenzothiazoline-6-sulfonate) cationic radical (ABTS^+?) and 2,2'-diphenyl-1-picrylhydrazyl radical (DPPH), and then were applied to inhibit the oxidation of DNA induced by Cu^2^+/glutathione (GSH) and 2,2'-azobis(2-amidinopropane hydrochloride) (AAPH). Magnolol and honokiol were active to reduce ONOO^- and ^1O"2. Honokiol showed a little higher activity to protect LH and to inhibit Cu^2^+/GSH-induced oxidation of DNA than magnolol. In addition, honokiol exhibited higher activities to trap ABTS^+? and DPPH than magnolol. In particular, honokiol trapped 2.5 radicals while magnolol o...

2011-01-01

97

BC

Antiferromagnetic Kondo lattice: CePdSi_2

1 ?3?4.1 ? ?4.2 ...4.3 ? ?5.1?5.2 ? ?6.1 ?? ?6.2 ? ...8?10 ?? ?11 ? ?? ?12 ??13

98

Adsorption of Pb^2^+ and Zn^2^+ from aqueous solutions by sulfured orange peel

The compounds CePdSi_2, CeIrSi_2 and CeRhSn_2 have been synthesized and studied by X-ray diffraction, electrical resistivity and magnetic susceptibility. The magnetic susceptibility of CePdSi_2 exhibits two peaks at 6.8 K and 2.5 K, respectively, indicating two antiferromagnetic phase transitions, while that of CeIrSi_2 shows a broad maximum at 150 K, characteristic of valence fluctuating Ce-compounds. CeRhSn_2 remains paramagnetic down to 5 K. The resistivity of CeIrSi_2 exhibits a T"2 dependence at low temperatures, indicating a Fermi-liquid ground state, while those of CePdSi_2 and CeRhSn_2 shows the presence of Kondo and crystal field effects. (orig.).

1996-08-19

99

British Library Electronic Table of Contents (United Kingdom)

In this study, sulfured orange peel (MOP) was used as adsorbent to investigate its adsorption behaviors of Pb^2^+ and Zn^2^+ from aqueous solutions. The effects of solution pH, adsorption time and metal ion concentration on adsorption were studied in batch experiments. Both adsorption kinetics of Pb^2^+ and Zn^2^+ proceeded rapidly and could be well described by pesudo-second-order equation. The maximum Langmuir adsorption capacities for Pb^2^+ and Zn^2^+ removal by MOP were evaluated as 164 and 80mg/g, respectively. A binary mixture of Pb^2^+ and Zn^2^+ was studied by using a packed column, suggesting that effective mutual separation and pre-concentration of Pb^2^+ away from Zn^2^+ using MOP could be satisfactory achieved. The results indicate that MOP could be employed as an ...

2011-01-01

100

Effect of D-amino acids at Asp"2"3 and Ser"2"6 residues on the conformational preference of A#beta#_2_0_-_2_9 peptides

Thermochemical water-splitting cycle, bench-scale investigations, and process engineering. Final report, February 1977-December 31, 1981

The effects of D-amino acids at Asp"2"3 and Ser"2"6 residues on the conformational preference of #beta#-amyloid (A#beta#) peptide fragment (A#beta#_2_0_-_2_9) have been studied using different spectroscopic techniques, namely vibrational circular dichroism (VCD), vibrational absorption, and electronic circular dichroism. To study the structure of the A#beta#_2_0_-_2_9, [D-Asp"2"3]A#beta#_2_0_-_2_9, and [D-Ser"2"6]A#beta#_2_0_-_2_9 peptides under different conditions, the spectra were measured in 10 mM acetate buffer (pH 3) and in 2,2,2-trifluoroethanol (TFE). The spectroscopic results indicated that at pH 3, A#beta#_2_0_-_2_9 peptide takes random coil with #beta#-turn structure, while [D-Ser"2"6]A#beta#_2_0_-_2_9 peptide adopts ...

2005-09-30

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

101

Glass-cordierite-mullite ceramics of low dielectric constant; Tworzywa szklano-kordierytowo-mulitowe o malej przenikalnosci elektrycznej

The sulfur-iodine water-splitting cycle is characterized by the following three reactions: 2H/sub 2/O + SO/sub 2/ + I/sub 2/ ..-->.. H/sub 2/SO/sub 4/ + 2HI; H/sub 2/SO/sub 4/ ..-->.. H/sub 2/O + SO/sub 2/ + 1/2 O/sub 2/; and 2HI ..-->.. H/sub 2/ + I/sub 2/. This cycle was developed at General Atomic after several critical features in the above reactions were discovered. These involved phase separations, catalytic reactions, etc. Estimates of the energy efficiency of this economically reasonable advanced state-of-the-art processing unit produced sufficiently high values (to approx.47%) to warrant cycle development effort. The DOE contract was largely directed toward the engineering ...

1982-05-01

102

Alpha particle spectroscopic strengths for levels populated in the "2"0 "2"1 "2"2Ne("6Li, d)"2"4 "2"5 "2"6Mg reactions

Glass-ceramic materials containing 0-60% glass, 0-40% cordierite and 0-40% mullite were developed with dielectric constant lower than of Al{sub 2}O{sub 3} (5.2-6.7). The following glasses were used: SiO{sub 2}, CaO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-SiO{sub 2}, CaO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}, CaO-ZnO-B{sub 2}O{sub 3}, CaO-ZnO-Al{sub 2}O{sub 3}B{sub 2}O{sub 3}, BaO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-SiO{sub 2} and BaO-ZnO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-SiO{sub 2}. The influence of the content of the particular components on the value of dielectric constant of the ceramics was investigated. (author). 9 refs, 3 tabs.

1997-12-31

103

A biogenic approach to the treatment of uranium mill effluents

The "2"0 "2"1 "2"2Ne("6Li, d)"2"4 "2"5 "2"6Mg reactions have been studied at a bombarding energy of 32 MeV. Alpha particle spectroscopic strengths have been extracted for several low-lying levels by a finite-range distorted wave analysis. These are compared with theoretical predictions. The agreement is good both for relative strengths to different levels within a nucleus and for ground-state strengths relative to the "1"6O("6Li, d) result. Strengths calculated using eigenfunctions determined in large shell-model computations agree well with pure symmetry SU(3) predictions. The "2"1Ne("6Li, d) angular distributions for transitions to the ground-state band of "2"5Mg are characterized by the lower of the two L-transfers allowed for populating each level. For the 3"+(5.24 MeV) unnatural parity level in ...

104

Structural Studies of Electron Deficient Titanacyclobutanes

A biogenic method for the treatment of uranium mill effluents containing toxic amounts of Mn"2 and "2"2"6Ra is described. The acidic tailings from the uranium mills are generally neutralised with lime and the overflow waters from tailing ponds at the discharge point, consisting of Mn"2"+ (>10 mg l"-"1) and "2"2"6Ra (> 3.0 pCi l"-"1), need further treatment before disposing off to the public utility. Arthrobacter sp. has been used for precipitating Mn"2"+ as hydrous oxide of manganes (MnO_2#centre dot#nH_2O) and along with "2"2"6Ra also gets precipitated. The effluent after bacterial treatment consisted of Mn"2"+ and "2"2"6Ra within the range of allowed concentrations as per the I.C.R.P. (International Committee of Radiological Protection) and MPC (maximum permissible ...

105

British Library Electronic Table of Contents (United Kingdom)

Two 16 electron titanacyclobutanes of the formula Ti(C5H4R)2(?2-CH2)2C(CH3)(i-C3H7) (R=H, CH3) have been prepared from the reaction of Ti(C5H5)2(?2-CH2)(?2-Cl)Al(CH3)2 or Ti(C5H4CH3)2(?2-CH2)(?2-Cl)Al(CH3)2 with H2C=C(CH3)(i-C3H7). Structural parameters, most notably lengthened C?C bonds in the titanacyclobutane ring, for both complexes reveal the expected presence of (C?C)?Ti agostic interactions. The complexes are isomorphous, crystallizing in the monoclinic space group Cc. For Ti(C5H5)2(?2-CH2)2C(CH3)(i-C3H7), a?=?11.3459(3)??, b?=?16.2108(4)??, c?=?8.1646(2)??, ??=?105.5276(16)?, V?=?1446.87(6)?, Dcalc?=?1.268 at 150(1)?K. For Ti(C5H4CH3)2(?2-CH2)2C(CH3)(i-C3H7), ...

2011-01-01

106

Enhanced oxygen storage capacity of cerium oxides in CeO sub 2 /La sub 2 O sub 3 /Al sub 2 O sub 3 containing precious metals

Whey protein potentiates the intestinotrophic action of glucagon-like peptide-2 in parenterally fed rats

Effects of the addition of precious metals (PM; Pt, Rh) on CeO{sub 2}/Al{sub 2}O{sub 3} and CeO{sub 2}/La{sub 2}O{sub 3}/Al{sub 2}O{sub 3} were confirmed to enhance the oxygen storage capacities (OSC). Increments in the OSC of the added CeO{sub 2}/La{sub 2}O{sub 3}/Al{sub 2}O{sub 3} catalysts were much greater than those in the OSC of the PM added CeO{sub 2}/Al{sub 2}O{sub 3}. The enhanced OSC is ascribed to the interaction between PM and a CeO{sub 2}-La{sub 2}O{sub 3} solid solution formed during the catalyst preparation. No enhancements in the OSC were observed on physical mixing of CeO{sub 2}/La{sub 2}O{sub 3}/Al{sub 2}O{sub 3} and Pt-Rh/Al{sub 2}O{sub ...

1990-08-09

107

VO{sub 2}(B) as a cathode material for lithium battery

Glucagon-like peptide-2 (GLP-2) is a nutrient-regulated intestinotrophic hormone derived from proglucagon in the distal intestine. Enteral nutrients (EN) potentiate the action of GLP-2 to reverse parenteral...Full Text Available

2009-11-01

108

Total cross sections of reactions from data on the 25.2 MeV alpha particle elastic scattering on "9"4Mo, "1"0"7Ag, "1"2"2","1"2"4Sn nuclei

No abstract prepared.

2002-07-01

109

Theoretical evaluation of radon emanation under a variety of conditions

Short note. 4 refs.; 1 tab.

1991-04-16

110

Technical, TO 31R2-2FRC181-31, F Publication Transfer ...

A cylindrical coordinate mathematical model to calculate "2"2"2Rn flux and movement was developed considering "2"2"2Rn production, decay, and diffusion in a multilayered, porous, permeable matrix. Air movement, transporting radon through the media, satisfies Darcy's law and is influenced by the air (barometric) pressure applied at the surface. Two zones of porous material have been defined, one with a "2"2"2Rn production term (the uranium ore zone) and the other without this term to simulate shotcrete or concrete ground support. A provision is made to evaluate the effect of a pinhole in an otherwise impermeable sealant. Comparisons are made between field measurements and predicted values. Specific examples are given of "2"2"2Rn flux from a finite ore-body model versus steady and periodic changes in barometric pressure. Also examined are "2"2"2Rn losses through pinholes for cases of ...

111

Synthesis, characterization and evaluation of antibacterial activity of some thiazolo[3,2-b][1,2,4]triazole incorporating diphenylsulfone moieties

... Title : Technical, TO 31R2-2FRC181-31, F Publication Transfer Using: O'Neil & Associates' Data Supporting ESC/MSL's MILSTAR Program, MIL ...

1994-08-05

112

British Library Electronic Table of Contents (United Kingdom)

A series of thiazolo[3,2-b][1,2,4]triazole incorporating diphenylsulfone moieties were synthesized starting from 5-[4-(4-X-phenylsulfonyl)phenyl]-4H-1,2,4-triazole-3-thioles 3a-c, X=H, Cl, Br. Thus, alkylation of 1,2,4-triazoles 3 with phenacyl bromide or 4-bromophenacyl bromide afforded S-substituted 1,2,4-triazoles 4, 5. These new intermediates 4 and 5, in the presence of H2SO4 (c), were cyclized to 2-[4-(4-X-phenylsulfonyl)phenyl]-6-(4-Y-phenyl)[1,3]thiazolo[3,2-b]-[1, 2,4]-triazoles 6, 7 (I) and not to isomeric thiazolo[2,3-c][1,2,4]-triazoles 6, 7 (II). The newly synthesized compounds were characterized by IR, 1H, 13C NMR and elemental analysis. MS spectra confirmed the formation of thiazolo[3,2-b][1,2,4]triazole ...

2009-01-01

113

Studies on some N-acyl N-phenylhydroxylamines as metal-complexing ligands - Part IX : formation constants of UO_2"2"+-complexes of some-hydroxysuccinamic acid

Serum HER2 Level Measured by Dot Blot: A Valid and Inexpensive Assay for Monitoring Breast Cancer Progression

The first-step formation constants of UO_2"2"+-complexes of some N-hydroxysuccinamic acids viz. N-phenyl N-hydroxysuccinamic acid (Rsub(p)H(sub(2))), N-o-toyl N-hydroxysuccinamic acid(Rsub(t)oHsub(2)) and N-m-tolyl N-hydroxysuccinamic acid (Rsub(t)mHsub(2)) have been determined spectrophotometrically. Stabilities are in the ligand order Risup(m)Hsub(2)>Rsub(t)oHsub(2)>Rsub(p)Hsub(2). The first-step hydrolysis constant k' of UO_2"2"+ ion has been determined spectrophotometrically and found to be pk'=4.00 at a constant ionic strength (#mu#=0.5) at 30deg-+0.5deg and the molar extinction coefficients of the species UO_2"2"+ and UO_2(OH)"+ at #LAMBDA#=385 nm are found to be 2.0 and 13.0 respectively. (author).

1976-01-01

114

Repressive BMP2 Gene Regulatory Elements Near the BMP2 promoter

Human epidermal growth factor receptor 2 (HER2) is one of the most important prognostic and predictive factors for breast cancer patients. Recently, serum HER2...Full Text Available

115

Regulation of Mixed Lineage Kinase 3 is Required for Neurofibromatosis-2-Mediated Growth Suppression in Human Cancer

The level of bone morphogenetic protein 2 (BMP2) profoundly influences essential cell behaviors such as proliferation, differentiation, apoptosis, and migration. The spatial and temporal pattern...Full Text Available

2010-02-05

116

Proposed Gulf of Mexico OCS Oil and Gas Lease Sale 206

The Neurofibromatosis-2 (NF2) tumor suppressor merlin negatively regulates cell proliferation in numerous cell types. We have previously shown that the NF2...Full Text Available

2011-02-17

117

Phospholipase A2 from rat liver mitochondria

... 2 km (0-1.2 mi) of new onshore pipelines projected as a result of proposed Lease Sale ... 2 km (0-1.2 mi) of new onshore pipelines projected as a result of proposed Lease Sale ... ...

118

PYRROLO[1,2-b][1,2,5]BENZOTHIADIAZEPINES (PBTDs) induce apoptosis in K562 cells

No abstract available.

1991-01-01

119

On fractal nature of the compound nucleus

BackgroundThe objective of this study was to gain insight into the molecular mechanism of induced cell death (apoptosis) by PYRROLO [1,2-b][1,2,5]BENZOTHIADIAZEPINES...Full Text Available

120

Nucleon-al'ha particle effective interaction and 50.5 MeV #alpha#-particle elastic scattering on "1"2C, "2"0Ne, "2"4Mg and "2"8Si nuclei

Short communication. 6 refs., 2 figs.

1995-12-31

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

121

Neutron activation analysis of ultra-trace elements. 2

Russian 1984. p. 349. USSR Burtebaev, NT Dujsebaev, AD Knyaz'kov, OM

1984-04-17

122

Modelling 18O2 and 16O2 unidirectional fluxes in plants: I. Regulation of pre-industrial atmosphere

No abstract prepared

1998-01-01

123

British Library Electronic Table of Contents (United Kingdom)

In closed systems, the O2 compensation point (?O) was previously defined as the upper limit of O2 level, at a given CO2 level, above which plants cannot have positive carbon balance and survive. Studies with 18O2 measure the actual O2 uptake by photorespiration due to the dual function of Rubisco, the enzyme that fixes CO2 and takes O2 as an alternative substrate. One-step modelling of CO2 and O2 uptakes allows calculating a plant specificity factor (Sp) as the sum of the biochemical specificity of Rubisco and a biophysical specificity, function of the resistance to CO2 transfer from the atmosphere to Rubisco. The crossing points (Cx, Ox) are defined as CO2 and O2 concentrations for which O2 and ...

2011-01-01

124

METHOD FOR PRODUCING 5-ALKYLIDENE-2-OXAZOLIDINONES

J-STORE (Japan)

Full Text Available

2004-11-17

125

Lipocalin 2 in the central nervous system host response to systemic lipopolysaccharide administration

Isolation and determination of "9"0Sr, "2"2"6Ra, "2"2"8Ra and "2"1"0Pb in food

BackgroundLipocalin 2 (Lcn2) is a bacteriostatic factor that may also modulate cellular function, however, little is known concerning the expression or role of Lcn2 in CNS inflammation....Full Text Available

126

In situ thermal desorption of H{sub 2} from LiNH{sub 2}-2LiH monitored by environmental SEM

A procedure is described for the isolation and determination of "9"0Sr, "2"2"6Ra, "2"2"8Ra and "2"1"0Pb in food. These nuclides are highly radiotoxic, above all for babies and children. Samples are dry ashed, alkali metals are removed as carbonates. Separation from other matrix ions and separation of Ra, Sr and Pb can be achieved with a column of Sr-Spec, an immobilized crown ether. For activity measurements membrane filters with SrSO_4, Ba(Ra)SO_4 and PbS are prepared. Ra is determined by gamma-spectrometry, "9"0Sr and "2"1"0Pb are determined by low-level-betacounting. The determination limits are 10 mBq/kg for "9"0Sr and "2"1"0Pb and 50 mBq/kg for "2"2"6Ra and "2"2"8Ra. The procedure is useful for all kinds of foodstuff. (orig.).

127

Human Performance Studies for Control of Multiple Remote ...

This article describes in situ heating and observation of a LiNH{sub 2}-2LiH mixture in an environmental scanning electron microscope (ESEM). The LiNH{sub 2}-2LiH mixture showed extensive morphological changes with heating and attendant hydrogen desorption. Static images and real-time movies were obtained during the dehydrogenation process. H{sub 2} evolution commences at {proportional_to}150 C (LiNH{sub 2} + 2LiH {yields} Li{sub 2}NH + H{sub 2} + LiH), and continues until {proportional_to}410 C. Dramatic morphological changes are observed at 220 and 410 C (Li{sub 2}NH + LiH {yields} Li{sub 3}N + H{sub 2}). The material converts to a microcrystalline phase at higher temperatures (>500 C). The observed H{sub 2} desorption and morphological changes occur at temperatures in ...

2009-01-15

128

Federal Logistics Information System (FLIS) Procedures ...

... 1 8.53 1.5448 2 12.45 2.1944 3 16.59 2.5224 Sensor Mobility fixed 8.92 1.9312 mobile 12.15 2.3625 Display Configuration conv. 10.92 1.7981 ...

1994-07-01

129

Evaluation of the PHQ-2 as a Brief Screen for Detecting Major Depression among Adolescents

... II Item Identification 1,2,3,4,5,,3JAN Joint Army-Navy 2 5,6,13 IIM Item Intelligence 2 JANAP Joint Army-Navy-Air 2,7 Maintenance Force Publication ...

1995-01-01

130

Dual Roles of Nrf2 in Cancer

ObjectiveTo examine the validity of the Patient Health Questionnaire - 2 (PHQ-2), a 2-item depression screening scale among adolescents.Full Text Available

2010-05-01

131

Concentrations of "2"2"6Ra and "2"1"0Pb in tap water, well water and rain water and adsorption of "2"1"0Pb to soil

In response to oxidative stress, the transcription factor NF-E2-related factor 2 (Nrf2) controls the fate of cells through transcriptional upregulation of antioxidant response element (ARE)-bearing...Full Text Available

2008-01-01

132

Japanese (Jul 1976). Japan Kametani, Katsuaki Tomura, Kayoko . National

133

B-1 Primary Safety

Assessment of Embryotoxicity of 2-Bromopropane in ICR Mice

... Page 2. Boston Scientific CRM 11/17/09 MADIT-CRT Clinical Report APPENDIX B 2 CONFIDENTIAL ... B-2 Primary Effectiveness B-2.1 Validation of Assumptions ...

134

Acute Asthma Responsiveness and B2 Adrenergic Receptors Polymorphisms

Full Text Available

2003-09-01

135

ATM-Dependent Phosphorylation of ATF2 Is Required for the DNA Damage Response

Acute Asthma

2011-05-24

136

40 CFR 261.2 - Definition of solid waste.

SummaryActivating transcription factor 2 (ATF2) is regulated by JNK/p38 in response to stress. Here, we demonstrate that the protein kinase ATM phosphorylates ATF2 on serines...Full Text Available

2005-05-27

137

Thermodynamic study of systems with lower critical solution temperatures: H_2O + (C_2H_5)_3N, D_2O + (C_2H_5)_3N

...2009-07-01 false Definition of solid waste. 261.2 Section 261.2 Protection...PROTECTION AGENCY (CONTINUED) SOLID WASTES (CONTINUED) IDENTIFICATION AND LISTING OF HAZARDOUS WASTE General § 261.2 Definition...

2009-07-01

138

Structure dependent luminescence characterization of green-yellow emitting Sr2SiO4:Eu2+ phosphors for near UV LEDs

Molar excess enthalpies and molar excess volumes are reported for the systems H_2O + (C_2H_5)_3N and D_2O + (C_2H_5)_3N at temperatures below and above their lower critical solution temperatures. The molar excess enthalpies are slightly less exothermic for the D_2O system. The molar excess volumes of the H_2O and D_2O systems are within experimental error of one another. Compositions of conjugate solutions estimated from the calorimetric and volumetric measurements agree with those obtained from published liquid-liquid phase diagrams. (Auth.).

1979-01-01

139

Structural and Magnetic Properties of the Brownmillerite $Ca_2Al_xFe_{2-x}O_5$ System

Not Available

2012-01-01

140

Spin-density-wave transition and {mu}SR in the heavy-fermion Ce(Ru, T){sub 2}Si{sub 2}, T = Rh, Pd

Full Text Available

1995-10-01

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

141

Preparation and evaluation of Tc-99m complexes of aromatic bridged amine-amide-thiol-thioether N_2S_2 ligands

No abstract prepared.

1999-02-28

142

Nondestructive analysis for "2"3"2U and decay progeny in animal tissues

Short communication.

143

Magnetic phase diagrams of the TbRh{sub 2-x}Pd{sub x}Si{sub 2} and TbRu{sub 2-x}Pd{sub x}Si{sub 2} systems

Direct determination of "2"3"2U and its decay products in animal tissues appears to be feasible using an intrinsic Ge(Li) diode detector (for energies of 5-100 keV) and a NaI(Tl) anticoincidence-shielded Ge(Li) diode for higher-energy gamma photons. The detection sensitivity for "2"3"2U and "2"2"8Th is 0.03 and 0.01 nCi, respectively, using a 300-min counting time.

1977-05-01

144

Latent Heat Storage Characteristics of Some Paraffins(CnH2n+2) for Thermal Environment Control of Greenhouse

The a.c. susceptibility and high field magnetization of TbRh{sub 2-x}Pd{sub x}Si{sub 2} and TbRu{sub 2-x}Pd{sub x}Si{sub 2} compounds were investigated up to 140 kOe. The (T, x) magnetic phase diagrams were determined. For both systems, an increase in the Pd content causes a decrease in the Neel temperature and changes the magnetization curves. (orig.)

1995-12-01

145

Excitation of the 2_1"+ and 2_2"+ states in the "8"8Sr(p,p') reaction at 25 and 31 MeV: A look behind the nuclear surface

Full Text Available

1996-03-01

146

Excitation of the 2/sub 1//sup +/ and 2/sub 2//sup +/ states in the /sup 88/Sr(p,p') reaction at 25 and 31 MeV: A look behind the nuclear surface

Data for the excitation of the 2_1"+ and 2_2"+ states in the "8"8Sr(p,p') reaction at 25 and 31 MeV indicate sustantial contributions from the interior of the nucleus, Microscopic DWBA calculations reproduce this and yield a fair description of the data. A detailed description, especially of the 2_2"+ state, is sensitive to the effective nucleon-nucleon interaction used and the non-locality of the optical potential, which are insufficiently known at present. (orig.).

147

Differential regulation of iPLA2beta splice variants by in vitro ischemia in C2C12 myotubes

Data for the excitation of the 2/sub 1//sup +/ and 2/sub 2//sup +/ states in the /sup 88/Sr(p,p') reaction at 25 and 31 MeV indicate sustantial contributions from the interior of the nucleus, Microscopic DWBA calculations reproduce this and yield a fair description of the data. A detailed description, especially of the 2/sub 2//sup +/ state, is sensitive to the effective nucleon-nucleon interaction used and the non-locality of the optical potential, which are insufficiently known at present.

1986-07-03

148

Coordination compounds of oxovanadium(4), nickel(2) and copper(2) with bis-(salicyliden)-thiocarbazide

Udgivelsesdato: March

2006-01-01

149

Complete intersection Calabi-Yau manifolds ; 2, three generation manifolds

A reaction of aqueous-methanol solutions of thiocarbazide and salycilic aldehyde, taken in a molal ratio of 1:2 on the matrix of oxovanadium(VO) in the presence of aqueous ammonium results in a coordination compound of the VC_1_5H_1_2N_4O_3S composition. Similar compounds are obtained with salts of nickel(2) and copper(2). Complexes of oxovanadium(4) and copper(2) have effective magnetic moments normal for systems with a spin of 1/2. The compound with nickel is diamagnetic. These data agree with the configuration of the coordination compounds obtained.

150

Calculated neutron capture cross sections to the americium ground and isomeric states

Complete intersection Calabi-Yau manifolds ; 2, three generation manifolds

1988-01-01

151

Advanced Nondestructive Evaluation (NDE) for Retirement for ...

The neutron capture cross sections of "2"4"1Am and "2"4"3Am to the ground and isomeric states of "2"4"2Am and "2"4"4Am have been calculated using the Hauser-Feshbach statistical theory of nuclear reactions for energies from thermal to 2 MeV. The parameters for the calculations were obtained from recent data on ("2"4"1Am + n) and ("2"4"3Am + n) or, where necessary, from systematics of actinide nuclei. The calculated values are in good agreement with the sparse experimental data.

152

ARM: Infrared Thermometer: Sky brightness temperature, instantaneous 2-second

... 21 2.3 Eddy Current Probes ..... 22 2.3.1 Improved Probe Internal ...

2000-08-01

153

A measurement of the cross section for electron impact ionization of Ar"2"+, Kr"2"+ and Xe"2"+

Infrared Thermometer: Sky brightness temperature, instantaneous 2-second

2003-02-19

154

Two and 8-azido photoaffinity probes. 2. Studies on the binding process of 2-5A synthetase by photosensitive ATP analogues

The crossed electron-ion beams technique was used to measure absolute cross sections for single ionization of Ar"2"+, Kr"2"+ and Xe"2"+ ions at electron energies ranging from threshold to 2000 eV. In contrast to some previous measurements, the metastable contents of the ion beams were small even in the case of Xe"2"+. All measured cross section curves show significant contributions from excitation-autoionization and possibly direct ionization of inner-shell electrons. There is evidence for resonance-excitation-double-autoionization in the case of Xe"2"+. (author).

155

Ternary aluminides LnPd[sub 2]Al with YPd[sub 2]Si-type structure

The photoaffinity probes [#gamma#-"3"2P]2-azidoATP (2-N_3ATP) and [#alpha#-"3"2P]8-azido-ATP (8-N_3ATP) were used to investigate the binding of ATP to highly purified 2-5A synthetase. 2-N_3APT and 8-N_3ATP are substrates for 2-5A synthetase. In this study the authors show that 2- and 8-N_3ATP are competitive inhibitors of the enzymatic conversion of ATP to 2-5A. Ultraviolet irradiation results in the photoinsertion of 2-N_3ATP and 8-N_3ATP into the enzyme. The covalent photoinsertion of [#alpha#-"3"2P]8-N_3ATP into the 2-5A synthetase is proportional to the inactivation of the enzyme as UV irradiation is increased. Photolabeling of 2-5A synthetase is saturated at 1.5 mM 2-N_3ATP and ...

156

Synthesis and physicochemical properties of iron (2) perrhenates

Attempts to synthesize YPd[sub 2]Si-type representatives LnPd[sub 2]Al were successful only with Ln triple bond Ce, Pr, Nd. This orthorhombic structure (oP16; space group Pnma) is an ordered variant of the Fe[sub 3]C type. Only NdPd[sub 2]Al undergoes magnetic ordering above 2 K. (orig.)

1993-04-13

157

Sensitivity of Ru(bpy)₂dppz²⁺ Luminescence to DNA Defects

By dissolution of iron (2) carbonate in rhenium acid iron (2) perrhenate of the Fe(ReO/sub 4/)/sub 2/x4H/sub 2/O composition is obtained. By the method of thermal analysis the limits of tetra-, dihydrate and anhydrous iron (2) perrhenate stability are revealed. By means of X ray phase and IR spectroscopic analysis methods modification of structure in the process of synthesized salt dehydration is shown.

1983-01-01

158

Nucleation and crystal growth of Li{sub 2}O{center_dot}2SiO{sub 2} in a microwave field

The luminescent characteristics of Ru(bpy)₂dppz²⁺ (dppz = dipyrido[3,2-a:2′,3′-c]phenazine), a DNA light switch, were...Full Text Available

2009-06-15

159

Mean magnetic moments of polycrystalline Ce compounds in a tetragonal crystal field

A comparison of nucleation and crystallization of Li{sub 2}O{sm_bullet}2SiO{sub 2} between microwave and conventional heating was investigated. Standard stereological techniques were used to evaluate the results. Nucleation and crystallization behaviors during microwave heating appeared different from conventional heating. Work is in progress to better understand the effects of microwaves on nucleation and crystallization in glass.

1995-12-31

160

Marker studies of silicide formation, silicon self-diffusion and silicon epitaxy using radioactive silicon and Rutherford backscattering

An alternative and graphical representation of the magnetic moment and the effective paramagnetic moment for polycrystalline Ce compounds with tetragonal site symmetry is described. The reduced moments can be calculated by means of standard perturbation theory. The calculated values deduced from the ground states of CeCu_2Si_2, CeRu_2Si_2, and CePd_2Si_2 polycrystals are compared with experimental magnetic moments.

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

161

FT-IR spectroscopic studies of fulvic acid from weathered coal and its complexes

Radioactive "3"1Si(Tsub(1/2) = 2.62 h) and Rutherford backscattering were used to study Ni_2Si, Pd_2Si and Pt_2Si formation, silicon self-diffusion in silicides and silicon epitaxy in the Si(100)/Pd_2Si/Si (amorphous) system. (Auth.).

162

Enhanced ?₂-adrenergic receptor (?₂AR) signaling by adeno-associated viral (AAV)-mediated gene transfer

FT-IR spectrum of fulvic acid from wheathered coal of Gongxian is determined using second derivative spectroscopy and the spectroscopic resolution is enhanced. Moreover, FT-IR spectra of the complexes of fulvic acid with Ca"2"+, Ba"2"+, Cu"2"+, Pb"2"+ and UO_2"2"+ under different pH are determined and the nature of the coordination of these complexes is discussed.

1995-01-01

163

Differences of the deformation parameter #beta# for 2"+_1 states of even-even spherical nuclei from electromagnetic excitation and proton scattering

Background;2;₂-Adrenergic receptors (;2;₂AR) play important regulatory roles in a variety of cells and organ systems and are important therapeutic...Full Text Available

164

Cloning and sequencing of a 2,5-dichloro-2,5-cyclohexadiene-1,4-diol dehydrogenase gene involved in the degradation of gamma-hexachlorocyclohexane in Pseudomonas paucimobilis.

Differences of the deformation parameters for the 2"+_1 states of even-even spherical nuclei extracted from electromagnetic excitation #beta#sup(em)_2 and from proton scattering #beta#sup(pp')_2 are discussed. It is found that the ratio #beta#sup(pp')_2/#beta#sup(em)_2 is equal to about unity and that there is a small isotope dependence for several incomplete shell nuclei. (orig.).

165

A Real-Time US Army Tactical Telephone Network ...

In Pseudomonas paucimobilis UT26, gamma-hexachlorocyclohexane (gamma-HCH) is converted to 2,5-dichloro-2,5-cyclohexadiene-1,4-diol (2,5-DDOL), which is then metabolized to 2,5-dichlorohydroquinone....Full Text Available

1994-06-01

166

Synthesis, crystal structures and spectroscopic properties of RbBaTaS{sub 4} and K{sub 2}BaTa{sub 2}S{sub 11}

... To CA 2 TOM 2 L= DTO 2 4 9"ylem 2 a Systsm2OTO 3 Figure 25: Node I C-5 Internal Connectivity C5 DTO 2 GM I sy~stm I 1 RC-IOS L3 To CA ...

1993-09-01

167

Thin TiO2 grown by metal?organic chemical vapor deposition on (NH4)2S x -treated InP

Single crystals of RbBaTaS{sub 4} (1) and K{sub 2}BaTa{sub 2}S{sub 11} (2) were obtained from the reactions of Ta, with in situ formed fluxes of A{sub 2}S{sub 3} (A = K, Rb), BaS, and S at 500 C. Compound 1 crystallizes in the orthorhombic space group Pnma with a = 9.3286(5), b = 7.0391(4), c = 12.4365(7) A, V = 816.6(1) A{sup 3}, Z = 4. Compound 2 crystallizes in the monoclinic space group P2{sub 1}/c with a = 14.5280(10), b = 12.6347(7), c = 17.5148(12) A, {beta} = 94.744(8) , V = 3203.9(4) A{sup 3}, Z = 4. The structure of RbBaTaS{sub 4} (1) consists of isolated tetrahedral [TaS{sub 4}]{sup 3-} anions and Rb{sup +} and Ba{sup 2+} cations. The Ba{sup 2+} cations are surrounded by nine sulfur atoms forming distorted tricapped trigonal prisms, whereas the Rb{sup +} cations are in an irregular environment of ten sulfur ...

2010-10-15

168

British Library Electronic Table of Contents (United Kingdom)

The electrical characteristics of thin TiO2 films prepared by metal?organic chemical vapor deposition grown on a p-type InP substrate were studied. For a TiO2 film of 4.7?nm on InP without and with ammonium sulfide treatment, the leakage currents are 8.8?10?2 and 1.1?10?4?A/cm2 at +2 V bias and 1.6?10?1 and 8.3?10?4?A/cm2 at ?2?V bias. The lower leakage currents of TiO2 with ammonium sulfide treatment arise from the improvement of interface quality. The dielectric constant and effective oxide charge number density are 33 and 2.5?1013?cm2, respectively. The lowest mid-gap interface state density is around 7.6?1011?cm?2?eV?1. The equivalent oxide thickness is 0.52?nm. The breakdown electric field increases with decreasing thickness in the range of ...

2011-01-01

169

Rare-earth-rich tellurides: Gd_4NiTe_2 and Er_5M_2Te_2 (M=Co, Ni)

Methimazole complexes of platinum(II): Synthesis, characterization and redox behavior

Three new rare earth metal-rich compounds, Gd_4NiTe_2, and Er_5M_2Te_2 (M=Ni, Co), were synthesized in direct reactions using R, R_3M, and R_2Te_3 (R=Gd, Er; M=Co, Ni) and single-crystal structures were determined. Gd_4NiTe_2 is orthorhombic and crystallizes in space group Pnma with four formula units per cell. Lattice parameters at 110(2)K are a=15.548(9), b=4.113(2), c=11.7521(15)A. Er_5Ni_2Te_2 and Er_5Co_2Te_2 are isostructural and crystallize in the orthorhombic space group Cmcm with two formula units per cell. Lattice parameters at 110(2)K are a=3.934(1), b=14.811(4), c=14.709(4)A, and a=3.898(1), b=14.920(3), c=14.889(3)A, respectively. Metal-metal bonding correlations were analyzed using the empirical Pauling bond order concept.

2004-11-01

170

British Library Electronic Table of Contents (United Kingdom)

A variety of platinum(II) complexes of methimazole (2-mercapto-1-methylimidazole; HImS=neutral form and ImS=thiolate form), coordinated in both thione and thiolate forms, have been isolated by reacting methimazole with [PtCl(terpy)]Cl (terpy=2,2prime:6prime,2Prime terpyridine), [PtCl2(bipy)] (bipy=bipyridine), [PtCl2(o-phen)] (o-phen=o-phenanthroline), [PtCl2(CH3CN)2] and [PtCl2(COD)] (COD=1,5-cyclooctadiene). These complexes were characterized by electronic absorption, IR and NMR (1H, 13C, 195Pt) spectroscopies. Molecular structure of [Pt(bipy)(HImS)2]Cl23H2O (3a3H2O) has been established by single crystal X-ray crystallography. Platinum thiolate complex, [Pt(ImS)2(HImS)2] (5), could be obtained by treatment of ...

2011-01-01

171

Indoor thoron and radon concentration measurements with passive cup monitors

Cross section measurement for "2"0"4Pb(n,2n)"2"0"3Pb and "2"0"6Pb(n, #alpha#)"2"0"3Hg reactions

A new type of passive integrating cup monitors was developed to measure indoor thoron("2"2"0Rn) and radon("2"2"2Rn) concentrations. By placing a pair of cup monitors with different size a air exchange windows in the same place during a sufficient period of time the concentrations of both gases can be assessed from the alpha track densities on the CN films of the two monitors. The lower detection limit with a 3 months measurement period is for "2"2"0Rn 26.1 Bq*m"-"3 and is for "2"2"2Rn 6.1 Bq*m"-"3. Radon-220 and "2"2"2Rn concentrations have been measured in about 20 different types of dwellings around the Nagoya area with these monitors. The results suggest that the "2"2"0Rn concentrations were rather high in traditional Japanese dwellings made of a timber frame and mud. (orig.). (4 refs., 4 figs.).

1993-07-04

172

Photocatalytic degradation of gaseous benzene over TiO{sub 2}/Sr{sub 2}CeO{sub 4}: Preparation and photocatalytic behavior of TiO{sub 2}/Sr{sub 2}CeO{sub 4}

The cross sections of "2"0"4Pb(n,2n)"2"0"3Pb and "2"0"6Pb(n, #alpha#)"2"0"3Hg reactions have been measured by using the activation method in the neutron energy range of 13.50-14.81 MeV. Neutron fluence dose was calibrated with the cross sections of "2"7Al(n, #alpha#)"2"4Na reaction and neutron energies were determined by using the cross section ratios of "9"0Zr(n,2n)"8"9"m"+"gZr to "9"3Nb(n,2n)"9"2"mNb reactions. The results obtained are compared with the published data.

173

Highly enriched isotope samples of uranium and transuranium elements for scientific investigation

The paper demonstrates that the photocatalytic activity of TiO{sub 2} towards the decomposition of gaseous benzene in a batch reactor can be greatly improved by loading TiO{sub 2} on the surface of Sr{sub 2}CeO{sub 4}. The research investigates the optimum loading amount of TiO{sub 2} on Sr{sub 2}CeO{sub 4} in enhancing the photocatalytic activity of TiO{sub 2}. The prepared photocatalyst was characterized by XRD, UV-vis diffuse reflectance and XPS analyses. TiO{sub 2} is loaded on Sr{sub 2}CeO{sub 4} at 773 K. TiO{sub 2}/Sr{sub 2}CeO{sub 4} absorbs much more visible light than TiO{sub 2}. The XPS spectrum shows that there are Ti, O, C, Sr elements on the surface of the TiO{sub 2}/Sr{sub 2}CeO{sub 4}, and that the ...

2007-02-09

174

The Significance of PITX2 Overexpression in Human Colorectal Cancer

The paper describes the production of highly enriched isotopes of uranium, plutonium, americium and curium by electromagnetic separation for scientific and applied researches in physics, chemistry, geology, medicine, biology and other fields. Using the equipment described, the isotopes are produced in quantities sufficient to set up nuclear physical experiments, to produce nuclear reference materials and standard sources for calibration of radiometrical and mass spectrometrical equipment, in radionuclide metrology, etc. For the following isotopes the indicated degrees of isotopic enrichment were achieved: "2"3"3U-99.97%; "2"3"5U-99.97%; "2"3"6U-98.0%; "2"3"8U-99.997%; "2"3"8Pu-99.6%; "2"3"9Pu-99.9977%; "2"4"0Pu-99.9-100%; "2"4"1Pu-96.998%; "2"4"2Pu-97.8-99.96%; "2"4"4Pu-96.7%; ...

175

British Library Electronic Table of Contents (United Kingdom)

Purpose The paired-like homeodomain transcription factor 2 (PITX2) gene encodes a transcription factor controlled by the WNT/Dvl/CTNNB1 and Hedgehog/TGFB pathways in the pathogenesis of colorectal cancer (CRC). Although PITX2 is reportedly involved in various functions, including tissue development by controlling cell growth, its significance in CRC remains unclear. We report our findings regarding abnormal PITX2 expression in human CRC. Methods PITX2 expression was evaluated in 5 human CRC cell lines and 92 primary CRC samples. Cell growth was evaluated after inhibition of PITX2 expression or after exogenous introduction of PITX2. Results PITX2 expression was seen in all the five CRC cell lines. The study of tissue samples indicated that PITX2 expression was significantly higher in cancer...

2011-01-01

176

Tantalum nitride as a diffusion barrier between Pd_2Si or CoSi_2 and aluminum

Tantalum nitride as a diffusion barrier between Pd/sub 2/Si or CoSi/sub 2/ and aluminum

Reactively sputtered tantalum nitride (Ta_2N) has been investigated as a diffusion barrier between Pd_2Si and aluminum and CoSi_2 and Al. Ta_2N is found to be an excellent matallurgical diffusion barrier for the two systems up to 555 "0C, with no intermixing observed in Rutherford backscattering and Auger electron spectroscopic studies. Schottky barrier devices n-Si/Pd_2Si/Ta_2N/Al were excellent and showed no deterioration after annealing at 500 "0C. However, similar devices with CoSi_2 contacts and Ta_2N barrier showed a creation of high contact resistance between the silicide and the as-deposited nitride.

177

Symbiotic N2 fixation by legumes growing in pots. 2. Uptake of VN-labelled NO3 , C2H2 reduction and H2 evolution by Trifolium subterraneum L. , Medicago truncatula Gaertn. and Acacia dealbata Link

Reactively sputtered tantalum nitride (Ta/sub 2/N) has been investigated as a diffusion barrier between Pd/sub 2/Si and aluminum and CoSi/sub 2/ and Al. Ta/sub 2/N is found to be an excellent matallurgical diffusion barrier for the two systems up to 555 /sup 0/C, with no intermixing observed in Rutherford backscattering and Auger electron spectroscopic studies. Schottky barrier devices n-Si/Pd/sub 2/Si/Ta/sub 2/N/Al were excellent and showed no deterioration after annealing at 500 /sup 0/C. However, similar devices with CoSi/sub 2/ contacts and Ta/sub 2/N barrier showed a creation of high contact resistance between the silicide and the as-deposited nitride.

1989-04-15

178

Study of interaction between 7-(6-Br-2-benzthiazolylazo)-8-oxiquinoline-5-sulfonic acid and uranium (6), zinc (2) and manganese (2)

The objectives of this study were to estimate symbiotic nitrogen fixation by two common pasture legumes, Trifolium subterraneum L. and Medicago truncatula Gaertn., and an Australian native legume, Acacia dealbata Link, growing in pots using an indirect isotopic method. This method was also used to calibrate the C2H2 reduction assay of the intact plants. In addition, hydrogen evolution was measured in an attempt to explain the variations in C2H2:N2 ratios between the species. 25 refs.; 1 figure; 4 tabs.

1983-01-01

179

Sensitization and radiation hardening of the photostimulable X-ray storage phosphor CsBr:Eu2+

A new reagent 7-(6-Br-2-henzthiazolilazo)-8-oxyquinoline-5-sulphoacid has been studied spectrophotometrically. Dissociation constants have been determined in 50% acetone (pK_1=2.5 and pK_2=5.9) and 50% dioxane (pK_1=1.7 and pK_2=6.1) as well as molar extinction coefficients of the reagent dissociated form in the same solvents (71.1.10"3 and 72.4.10"3). The conditions have been studied of complexing the reagent with ions of uranium (6), zinc (2), and manganese (2) in 50% dioxane (pH 2.5-4.5) and the properties of the formed complexes.

1977-01-01

180

British Library Electronic Table of Contents (United Kingdom)

The X-ray storage phosphor CsBr:Eu2+ in form of needle image plates is believed to be a promising alternative to the granular BaFBr:Eu2+ with regard to PSL yield and spatial resolution. Unfortunately, CsBr:Eu2+ exhibits poor radiation hardness, which is caused by a migration of europium ions initiated by naturally existing defect centers like (Eu2+-VCs)-centers and X-ray generated MEu-centers. It will be shown that the formation of (Eu2+-O2?)-dipoles at the expense of (Eu2+-VCs)-dipoles, incorporated by thermal annealing in O2-containing and humid atmosphere, does not improve the radiation stability. There is, however, a strong improvement in the radiation hardness by codoping of CsBr:Eu2+ with lithium ions, which is accompanied by a complete suppression of the previously observed MEu-cent...

2009-01-01

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181

Role of Fgf receptor 2c in adipocyte hypertrophy in mesenteric white adipose tissue

British Library Electronic Table of Contents (United Kingdom)

Fgf receptor 2c (Fgfr2c) was expressed in mature adipocytes of mouse white adipose tissue (WAT). To examine the role of Fgfr2c in mature adipocytes, we generated adipocyte-specific Fgfr2 knockout (Fgfr2 CKO) mice. The hypertrophy impairment of adipocytes in the mesenteric WAT but not in the subcutaneous WAT and decreased plasma free fatty acid (FFA) levels were observed in Fgfr2 CKO mice. Although the expression of genes involved in adipocyte differentiation and lipid metabolism in the mesenteric WAT was essentially unchanged, the expression of uncoupling protein 2 potentially involved in energy dissipation was significantly increased. Among potential Fgf ligands for Fgfr2c, Fgf9 was preferentially expressed in the mesenteric WAT. The present findings indicate that Fgfr2c potentially activ...

2008-01-01

182

Kinetic and mass transfer analyses of metal biosorption by Caulerpa lentillifera

British Library Electronic Table of Contents (United Kingdom)

This study examined kinetics and mass transfer in the biosorption of heavy metals onto Caulerpa lentillifera. The sorption capacity of Cu^2^+, Pb^2^+ and Cd^2^+ from aqueous solution increased with initial metal concentration and decreased with biosorbent dose. Kinetic data were well described using the pseudo-second-order model. Results showed that both external mass transfer and intraparticle diffusion were rate limiting steps in the biosorption process. Activation energy of biosorption kinetics fell in the range of 3-13kJ/mol. The biosorption of Cu^2^+, Cd^2^+ and Pb^2^+ on the biomass correlated well with the Langmuir isotherm (R^2>0.99) with maximum sorption capacities at 293K of 0.169, 0.085 and 0.177mol/kg for Cu^2^+, Cd^2^+ and Pb^2^+ ions, respectively. Thermodynamic ...

2011-01-01

183

G-factor of the 21/2/sup +/ isomer in /sup 203/Pb

Decay behaviors of H{sub 2}{sup -} anions in solid parahydrogen. Effect of nuclear spins on chemical reactions

The g-factor of the 21/2/sup +/ state at 1921.9 keV in /sup 203/Pb has been measured through the time differential perturbed angular distribution technique in an external magnetic field B=2.028 T. The measured g-factor g=-0.063(2) indicates a predominantly three neutron hole configuration described by the wave function 0.68vertical strokei/sup -1//sub 13/2/f/sup -2//sub 5/2/>+-0.73vertical strokei/sup -1//sub 13/2/f/sup -1//sub 5/2/p/sup -1//sub 3/2/>.

1986-12-01

184

Azathia crown ethers carrying pyrene pendant as receptor molecules for metal sensor systems

Decay processes of H{sub 2}{sup -} anions in {gamma}-rays-irradiated solid parahydrogen were studied by using ESR spectrometer. The following interesting results were obtained. First, the initial amount of ortho-H{sub 2}{sup -} anions in the {gamma}-irradiated solid parahydrogen was three times as large as those of para-H{sub 2}{sup -} anions. Second, the amount of para-H{sub 2}{sup -} anions decreases faster than that of ortho-H{sub 2}{sup -} anions upon storage of the irradiated samples at 4.2 K. Third, the decay rate of H{sub 2}{sup -} anions is accelerated by the addition of D{sub 2} molecules. Forth, H{sub 2}{sup -} anions at 2.2 K decay faster than at 4.2 K. According to the parity conservation rule in a homonuclear diatomic molecule, the energy of ...

1996-11-01

185

T{sub 1} and T{sub 2} relaxivities of succimer-coated MFe{sub 2}{sup 3+}O{sub 4} (M=Mn{sup 2+}, Fe{sup 2+} and Co{sup 2+}) inverse spinel ferrites for potential use as phase-contrast agents in medical MRI

A series of crown ethers carrying a pyrene group with nitrogen-sulfur donor atoms, that differ in having three, four and five sulfur atoms in the macrocycle was designed and synthesized by the reaction of the corresponding macrocyclic compound and 1-bromomethylpyrene. The influence of metal cations such as Mn2+, Fe2+, Fe3+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+, Pb2+ and Al3+ on the spectroscopic properties of the ligands was investigated in acetonitrile-dichloromethane (1:1) by means of absorption and emission spectrometry. Absorption spectra show isosbestic points in the spectrophotometric titration of Fe2+, Zn2+, Cu2+, Pb2+ and Hg2+. The results of spectrophotometric titration experiments ...

2011-04-01

186

The effect of relative humidity on ozone production by corona discharge in oxygen or air - A numerical simulation - Part 2: Air

Superparamagnetic MFe{sub 2}{sup 3+}O{sub 4} (M=Mn{sup 2+}, Fe{sup 2+} and Co{sup 2+}) inverse spinel ferrite (ISF) nanoparticles with narrow size distribution having average diameters of 6-8 nm were synthesized by a diol reduction of organic metals and the surface was modified to be hydrophilic by coating with succimer. Magnetic resonance imaging (MRI) contrast enhancement by dipolar coupling defined interactions between the synthesized ISFs and protons in the bulk water was investigated with initial susceptibility, magnetization and anisotropy of the succimer-coated ISFs. The relaxivity ratios, r{sub 2}/r{sub 1}, for MnFe{sub 2}O{sub 4}, Fe{sub 3}O{sub 4} and CoFe{sub 2}O{sub 4} were measured to be 12.2, 23.1 and 62.3, respectively, which demonstrate the potential usefulness of these magnetic nanoparticles as T{sub ...

2009-12-15

187

Synthesis, spectral and X-ray structural studies of a NO donor Schiff base ligand and its Ni(II) complexes

The simulation of the temporal evolution of the various neutral gaseous species studied (O, O{sub 3}, H, OH, HO{sub 2}, H{sub 2}O{sub 2}, N, NO, NO{sub 2}, NO{sub 3}, N{sub 2}O, N{sub 2}O{sub 5}, HNO{sub 2}, and HNO{sub 3}) use corona effects. The physical conditions of the discharge were used. The reactions take place in dry or humid air, after the dissociation of O{sub 2}, N{sub 2}, and H{sub 2}O by an electronic pulse. When water vapor is present, there is a probability of production of H{sub 2}O{sub 2}, HNO{sub 2}, and HNO{sub 3} in air. Temperature and humidity have cumulative effects. With multiple pulses, the O{sub 3} maximal concentration is obtained for a limited number of pulses.

188

British Library Electronic Table of Contents (United Kingdom)

The Schiff base ligand, 4-isopropylbenzaldehyde[N-(3-oxo-3,4-dihydro-2-quinoxalinyl)hydrazone] (Ipbh), the 1:1 condensation product of 4-isopropylbenzaldehyde and 2-hydroxy-3-hydrazinoquinoxiline, has been synthesized and characterized by X-ray crystallography. A series of complexes of Ipbh with Nickel(II), viz., [Ni(Ipbh)2]Cl2 (1), [Ni(Ipbh)2]Br2 (2), [Ni(Ipbh)2]I2 (3), [Ni(Ipbh)2(CH3OH)2](NO3)2(CH3OH)2 (4) and [Ni(Ipbh)2ClO4]ClO4 (5) have been synthesized. All the complexes were characterized by elemental analysis, molar conductivity, CHN analysis, spectroscopic studies, magnetic susceptibility measurements and TG/DTA methods. The solid-state structure of the complex 4 was established by single ...

2011-01-01

189

Study of the thermodynamic properties of (U,Ce)O{sub 2}

Studies on the extraction equilibria of Cu, Ni, Co and Mn with Versatic Acid 911

The X-ray diffraction analysis of (U,Ce)O{sub 2} with the CeO{sub 2} contents ranging from 0 to 20 mol% CeO{sub 2} was performed at room temperature to obtain the variation in the lattice parameter with the CeO{sub 2} content. Ultrasonic pulse echo measurements were also carried out to estimate the change in the mechanical properties of (U,Ce)O{sub 2} with the CeO{sub 2} content. The lattice parameter of (U,Ce)O{sub 2} was found to decrease with increasing CeO{sub 2} content. The variation in the lattice parameter with the CeO{sub 2} content closely followed the Vegard law. The shear and longitudinal velocities in (U,Ce)O{sub 2} were found to decrease with increasing CeO{sub 2} content. The Young`s and shear moduli, and Poisson`s ratio estimated from the wave ...

1997-08-01

190

Solid electrolyte and lithium battery employing it. Kotai denkaishitsu oyobi sore wo shiyo shite naru richiumu denchi

The distribution of Cu, Ni, Co and Mn between an aqueous solution of constant ionic strength and Versatic Acid 911 diluted with benzene was investigated. Only one extracted species of Cu was revealed to have a dimeric structure of the composition (CuR_2.RH)_2, while both monomer and dimer were found in the extraction of Ni, Co and Mn. The curve-fitting method was employed to determine these species, from which the composition of the extracted species was found to be NiR_2.4RH and (NiR_2.2RH)_2, CoR_2.4RH and (CoR_2.2RH)_2, and MnR_2.4RH and (MnR_2.2RH)_2, respectively. The apparent equilibrium constants of the above species and those between monomer and dimer were also determined. The curve-fitting method was proved to be a precise method for determining the ...

191

Solar syngas production from CO"2 and H"2O in a two-step thermochemical cycle via Zn/ZnO redox reactions: Thermodynamic cycle analysis

Recently, the lithium ion-conductive solid electrolyte draws attention because there is a possibility of producing the maintenance-free battery which is characterized by having such advantages as high energy density and no possibility of electrolyte leak because of solid state structure. The invented lithium ion-conductive solid electrolyte is formed by sintering the granular electrolyte expressed in the following general formula: Li(1+(4-n)x)MxTi(2-x)(PO4)3 (M = mono- or di-valent cation, x = 0.1 - 0.5). Examples of the monovalent cation are Na[sup +], K[sup +], Rb[sup +], Cs[sup +], and Cu[sup +]. Examples of divalent cation are Mg[sup 2+], Fe[sup 2+], Be[sup 2+], Ca[sup 2+], Sr[sup 2+], Ba[sup 2+], Ra[sup 2+], Mn[sup 2+], Co[sup 2+], Cu[sup 2+], Ni[sup ...

1993-11-12

192

British Library Electronic Table of Contents (United Kingdom)

Solar syngas production from CO"2 and H"2O is considered in a two-step thermochemical cycle via Zn/ZnO redox reactions, encompassing: 1) the ZnO thermolysis to Zn and O"2 using concentrated solar radiation as the source of process heat, and 2) Zn reacting with mixtures of H"2O and CO"2 yielding high-quality syngas (mainly H"2 and CO) and ZnO; the ZnO is recycled to the first, solar step, resulting in net reaction @bCO"2 + (1 - @b)H"2O -> @bCO + (1 - @b)H"2. Syngas is further processed to liquid hydrocarbon fuels via Fischer-Tropsch or other catalytic processes. Second-law thermodynamic analysis is applied to determine the cycle efficiencies attainable with and without heat recuperation for varying molar fractions of CO"2:H"2O and solar ...

2011-01-01

193

Silver(I), mercury(II) and palladium(II) complexes of functionalized N-heterocyclic carbenes: Synthesis, structural studies and catalytic activity

British Library Electronic Table of Contents (United Kingdom)

A series of NHC silver(I), mercury(II) and palladium(II) complexes, [(1,3-diethylbimy)6Ag4I3]I (2), [(1-benzyl-3-picolylbimy)Ag2Br2]n (3), [(1-benzyl-3-picolylbimy)HgI(CH2CN)]2 (4), {[(1-picolyl-3-npropylbimy)2Hg][Hg2I6]}n (5) and [(1,3-dipicolylbimy)PdCl]Cl (6), as well as one anionic complex [1,3-diethylbimidazolium]2[HgI4] (1) (bimy=benzimidazol-2-ylidene), have been prepared and characterized. Interestingly, a wind wheel-like Ag4I3 arrangement in 2 is formed, 1D polymeric chain containing 12-membered macrometallocycles and quadrangle Ag2Br2 units in 3 is generated, and the a-carbon atom of deprotonated acetonitrile ([CH2CN]-) in 4 participates in coordination with mercury(II) atom. In the crystal packings of ...

2011-01-01

194

Excitation cross sections of Cd"+ ions for the upper and lower states of the Cd II 441.6-nm laser line by electron impact

Effect of pressure on iodine complexes, 2

The excitation cross sections by electron impact from the Cd II ground state to the laser upper state 5s_2 _2D/sub 5/2/ (Beutler state) and the laser lower state 5p _2P/sub 3/2/ (resonance state) have been measured by using a crossed-beam method of electrons and Cd"+ ions and a photon-counting method. The electron-energy region investigated was from the threshold energy (5.8 eV) for the excitation of the 5p _2P/sub 3/2/ state to 20 eV. It has been shown that the excitation cross section for the ionic Beutler state 5s_2 _2D/sub 5/2/ is of the order of 10"-_1_5 cm_2 and has a sharp peak near the threshold energy for the excitation. The excitation cross section for the resonance state 5p _2P/sub 3/2/ has also been of the ...

195

EPR and FT-IR spectroscopic studies of Bi2O3-B2O3-CuO glasses

Absorption spectra of the CT bands of I_2 complexes with Et_2O, Et_2S, and Et_2Se in heptane have been measured up to 4400 bar at 25"0C. The equilibrium constants and the volume changes accompanying complex formation, and the molar extinction coefficients and absorption maxima have been estimated. The volume changes were comparable with those estimated by the visible I_2 bands and by the X-ray data of the I_2 complexes in the crystalline state. In the CT bands of Et_2S-I_2 and Et_2Se-I_2 complexes inversion of shift from red to blue has been observed with increasing pressure though the CT band of Et_2O-I_2 complex shifted only through red. This inversion appears to be characteristic of the strong CT complex. Enhancement of the molar ...

1979-01-01

196

Dependence of fast reactor fuel burnup characteristics on nuclear data libraries

EPR and FT-IR absorption measurements have been performed for xCuO.(100-x)[2Bi2O3.B2O3] glass system, with 0?x?50 mol%. The mode in which the addition of the copper ions influences the structure of 2Bi2O3.B2O3 glass matrix was analyzed. The EPR absorption spectra revealed the presence in the glass structure of Cu2+ ions in axially distorted octahedral environments. EPR data pointed out the simultaneous presence of Cu2+ and Cu+ ionic species in the glasses with x?5 mol%. For x>10 mol%, the Cu2+ ions participate in the superexchange magnetic interactions, which increase with CuO content. The FT-IR spectra showed the presence of some bands that are assigned to vibrations of Bi-O bonds from BiO3 pyramidal and BiO6 octahedral units and B-O bonds from BO3 and BO4 units. The data obtained by these ...

2008-10-01

197

Cu adatom interactions with single- and polycrystalline Bi_2Ca/sub 1+//sub x/Sr/sub 2-//sub x/Cu_2O/sub 8+//sub y/ and YBa_2Cu_3O/sub 7-//sub x/

In the framework of the development of burnup calculation method for commercial fast reactors, a sensitivity analysis was carried out to clarify the dependence of fuel burnup characteristics on nuclear data libraries (NDLs). The following NDLs were compared: JEF-2.2, ENDF/B-VI Release 5, JENDL-3.2 and JENDL-3.3. The NDL-dependence of material balance for main heavy metal nuclides ("2"3"5U, "2"3"8U, "2"3"9Pu, "2"4"0Pu and "2"4"1Pu) was small, since the number densities at the end of one-cycle burnup did not change over 1 or 2% among the above-mentioned libraries. Relatively large differences were found for minor actinide nuclides, especially for "2"3"6U, "2"3"7Np, "2"4"2"mAm, "2"4"3Am and curium isotopes. The number densities for these ...

2005-04-01

198

Anomalous angular distributions in pion and #alpha# particle scattering to the 2_2"+ state of "5"2Cr

The electronic structure and surface interactions vapor-deposited Cu on single-crystal and polycrystalline Bi_2Ca/sub 1+//sub x//sub Sr>2-//sub x//sub Cu>2/O/sub 8+//sub y/ were studied using x-ray photoelectron spectroscopy. The results are compared to the Cu/YBa_2Cu_3O/sub 7-//sub x/ interface. Changes in the Cu 2p satellite emission indicate that the Cu adatoms do not disrupt Bi_2Ca/sub 1+//sub x/Sr/sub 2-//sub x/Cu_2O/sub 8+//sub y/ as extensively as YBa_2Cu_3O/sub 7-//sub x/. However, deposition of Cu induces changes in the Bi environment in the superconductor, and surface segregation of Bi metal was observed at high coverages. Core-level attenuation results suggests minimal outdiffusion of oxygen, in contrast with what is observed for Cu/YBa_2Cu_3O/sub 7-//sub x/.

5545-01-01

199

Inelastic scattering of 180 MeV #pi#"+ and #pi#"- from "5"2Cr shows an angular distribution for the 2_2"+ state at 2.96 MeV that differs greatly from the usual L = 2 shapes for 2"+ states. This state is perhaps the only case from pion-inelastic scattering in which standard distorted-wave impulse approximation models (including multistep and single-step responses) fail to reproduce the measured angular distribution. Furthermore, this unique excitation has been shown to have the features expected of a seniority-four proton excitation yet the pion data show charge symmetry. While coupled-channel calculations are not able to reproduce the pion data, they do agree with the shape observed for 42 MeV #alpha# particle scattering to this state, but the magnitude of the #alpha# scattering data is not consistent with a collective model and known #gamma# ray deexcitations. Scattering to the ...

200

for wheelie bins.\\

The Proton structure function F(2) in the resonance region

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1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

201

S-matrix elements and covariant tachyon action in type 0 theory

Unique measurement of the proton structure function F2 in a wide two-dimensional region of x and Q**2 has been reported. The accessible kinematics covers entire resonance region up to W=2.5 GeV in the Q**2 interval from 0.1 to 4.5 GeV**2. Obtained data allowed for the first time an evaluation of moments of the structure function F2 directly from experimental data as well as an intensive study of the Bloom-Gilman duality phenomenon.

2003-06-01

202

Progress towards a 20 Ah/12 V zinc/air battery

We evaluate the sphere level S-matrix element of two tachyons and two massless NS states, the S-matrix element of four tachyons, and the S-matrix element of two tachyons and two Ramond-Ramond vertex operators, in type 0 theory. We then find an expansion for theses amplitudes that their leading order terms correspond to a covariant tachyon action. To the order considered, there are no T4, T2(-bar T)2, T2H2, nor T2R tachyon couplings, whereas, the tachyon couplings FF-bar T and T2F2 are non-zero.

2005-01-17

203

Activities and activity ratios of U and Ra radioisotopes in drinking wells, springs and tap water samples in Morocco

Electrode areas, for the bifunctional O{sub 2}-electrodes and the pasted Zn-electrodes, have been successfully scaled up from 25 cm{sup 2} up to 250 cm{sup 2}. A filter press type cell was used to measure the cycle life of larger electrodes (100 cm{sup 2}). Up to now, more than 100 charge-discharge cycles (900 hours) with these scaled up Zn/O{sub 2}-cells could be demonstrated. (author) 2 figs., 2 refs.

1997-06-01

204

Weakly-bridged dimeric diorganotin(IV) compounds derived from pyruvic acid hydrazone Schiff base ligands: Synthesis, characterization and crystal structures

Radiochemical results ("2"3"4U, "2"3"8U, "2"2"6Ra and "2"2"8Ra activities; "2"3"4U/"2"3"8U, "2"2"8Ra/"2"2"6Ra and "2"2"6Ra/"2"3"8U activity ratios) are reported for 31 drinking water samples collected from 8 wells, 12 hot mineral springs, 5 cold springs, and 6 tap water samples. Activities of the Ra isotopes were measured by gamma spectrometry using a low background and high efficiency well type germanium detector. The U isotopes were counted in an alpha spectrometer. The results show that "2"3"8U activity varies between 4.46 and about 308 mBq l"-"1 in wells, 0.59 and 17.88 mBq l"-"1 in hot springs, 2.19 and 3.21 mBq l"-"1 in cold springs, and between 2.5 and 15.70 mBq l"-"1 in tap water samples. ...

205

British Library Electronic Table of Contents (United Kingdom)

We report the synthesis of four diorganotin(IV) compounds of Schiff base pyruvic acid hydrazone derivatives formulated as [R2SnLY]2, where L1 is 2-SC4H3CON2C(CH3)CO2 with Y = CH3CH2CH2CH2OH, R = n-Bu (1); L2 is C6H5CON2C(CH3)CO2 with Y = CH3CH2OH, R = p-F-Bz (2); L3 is 2-HOC6H4CON2C(CH3)CO2 with YH2O, R = p-CN-Bz (3); and L4 is 4-NO2-C6H4CON2C(CH3)CO2 with YCH3CH2OH, R = Bz (4). The structures of all compounds have been established by a combination of single-crystal X-ray diffraction analysis, 1H and 119Sn NMR spectroscopy, IR spectroscopy, and ...

2011-01-01

206

Synthesis, crystal structure, spectroscopic and photoluminescence studies of manganese(II), cobalt(II), cadmium(II), zinc(II) and copper(II) complexes with a pyrazole derived Schiff base ligand

British Library Electronic Table of Contents (United Kingdom)

Varying coordination modes of the Schiff base ligand H"2L [5-methyl-1-H-pyrazole-3-carboxylic acid (1-pyridin-2-yl-ethylidene)-hydrazide] towards different metal centers are reported with the syntheses and characterization of four mononuclear Mn(II), Co(II), Cd(II) and Zn(II) complexes, [Mn(H"2L)(H"2O)"2](ClO"4)"2(MeOH) (1), [Co(H"2L)(NCS)"2] (2), [Cd(H"2L)(H"2O)"2](ClO"4)"2 (3) and [Zn(H"2L)(H"2O)"2](ClO"4)"2 (4), and a binuclear Cu(II) complex, [Cu"2(L)"2](ClO"4)"2 (5). In the complexes 1-4 the neutral ligand serves as a 3N,2O donor where the pyridine ...

2011-01-01

207

Reactive ceramics of CeO{sub 2}-MO{sub x} (M=Mn, Fe, Ni, Cu) for H{sub 2} generation by two-step water splitting using concentrated solar thermal energy

Basic research on cermet nuclear fuel

The addition of MO{sub x} (M: di- or tri-valent transition metal ion) into cerium dioxide (CeO{sub 2}) enhanced the ability of CeO{sub 2} for the oxygen (O{sub 2})-releasing reaction at lower temperature and swift hydrogen (H{sub 2})-generation reaction. CeO{sub 2}-MO{sub x} (M=Mn, Fe, Ni, Cu) reactive ceramics having high melting points were synthesized with the combustion method from their nitrates for solar H{sub 2} production. The prepared CeO{sub 2}-MO{sub x} samples were solid solutions between CeO{sub 2} and MO{sub x} with the fluorite structure through the X-ray diffractometry measurement. Two-step water-splitting reactions with CeO{sub 2}-MO{sub x} reactive ceramics proceeded at 1573-1773 K for the O{sub 2}-releasing step and at 1273 K for the H{sub ...

2007-05-15

208

Application of passive type radon detectors to find fissures in banks caused by the southern Hyogo prefectural earthquake in Japan

Production of cermet nuclear fuel having fine uranium dioxide (UO{sub 2}) particles dispersed in matrix metal requires basic property data on the compatibility of matrix metal with fission product compounds. It is thermodynamically suggested that, as burnup increases, cesium in oxide fuel reacts with the fuel, other fission products or cladding pipe and produces cesium uranates, cesium molybdate, or cesium chromate in stainless steel cladding pipe. Attempt was made to measure the thermal expansion coefficient and thermal conductivity of cesium uranates (Cs{sub 2}UO{sub 4} and Cs{sub 2}U{sub 2}O{sub 7}), cesium molybdate (Cs{sub 2}MoO{sub 4}) and cesium chromate (Cs{sub 2}CrO{sub 4}). Thermal expansion was measured by X-ray diffraction and determined by Cohen`s method. Thermal conductivity was obtained by measuring thermal diffusion by laser flash method. The ...

1998-01-01

209

Uranium (VI)Bis(imido) chalcogenate complexes:synthesis and density functional theory analysis

Innumerable fissures were formed widely in Hanshin area in Japan by the former southern Hyogo prefectural earthquake occurred on Jan.17, 1995. In this study, as a preliminary investigation, we applied passive type radon detector Pico-Rad (U.S. Packard Instrument Co. Ltd.) with hemispheric plastic cover over them around the fissure along on the bank of two reservoirs to examine whether there is possibility to find fissures using the characteristics of "2"2"2Rn migration. One of the reservoir, Taniyamakami-ike, is located at the north of the Awaji-shima island at a distance of about 4 km from the seismic center of this earthquake. On the whole, "2"2"2Rn exhalation rates were high on a line of 2 m below the edge of the bank and got lower in proportion to the distance from this line. Those top of the bank had middle values among the lines. The mean "2"2"2Rn exhalation rate was 4.7 mBq ...

210

T=(5/2) "2"7Na from "1"4C+"1"4C, and the N=16 shell gap

Bis(imido) uranium(VI) trans- and cis-dichalcogenate complexes with the general formula U(NtBu)2(EAr)2(OPPh3)2 (EAr = O-2-tBuC6H4, SPh, SePh, TePh) and U(NtBu)2(EAr)2(R2bpy) (EAr = SPh, SePh, TePh) (R2bpy = 4,4'-disubstituted-2,2'-bipyridyl, R = Me, tBu) have been prepared. This family of complexes includes the first reported monodentate selenolate and tellurolate complexes of uranium(VI). Density functional theory calculations show that covalent interactions in the U-E bond increase in the trans-dichalcogenate series U(NtBu)2(EAr)2(OPPh3)2 as the size of the chalcogenate donor increases and that both 5f and 6d orbital participation is important in the M-E bonds of U-S, U-Se, and U-Te complexes.

2009-01-01

211

Study of the susceptibility of an austenitic stainless steel stabilized with niobium to stress corrosion damage in a H_2S medium (SSC) and to intergranular corrosion (IGC) in other aggressive environments

For the first time a comprehensive level and decay scheme has been obtained for a T=(5/2) nucleus in the s-d shell ("2"7Na) by using a radioactive beam and target. Particle-#gamma# and p-#gamma#-#gamma# coincidences were measured following the "1"4C("1"4C,p#gamma#)"2"7Na reaction at E_l_a_b=22 MeV. The results do not support an inversion of the 2s_1_/_2 and 1d_5_/_2 orbitals, as previously proposed for T_z#>=#3, but they do suggest an increased N=16 gap between the 2s_1_/_2 and 1d_3_/_2 orbitals due to the neutron excess. A consistent interpretation of the level scheme in terms of the s-d shell model using the USD Hamiltonian is possible below 4 MeV, but differences increase at higher excitation energies. Another interpretation is that the influences of both the p_1_/_2 and ...

2002-05-01

212

Sequence of Potentials Lying Between the U(5) and X(5) Symmetries

Behavior to hydrogen damage caused by stress corrosion in a H_2S medium (SSC) and to intergranular corrosion (IGC) in different mediums, such as oxalic acid (C_2H_2.2H_2O), iron sulphate-50% sulfuric acid (Fe_2(SO_4)_3-50% H_2SO_4), nitric acid (HNO_3), copper sulphate-16% sulfuric acid (CuSO_4.5H_2O-16% H_2SO_4) and cooper sulphate-50% sulfuric acid (CuSO_4.5H_2O-50% H_2SO_4), is studied in an AISI 347 austenitic stainless steel stabilized with 0.61 mass % Nb and hot rolled to a seamless pipe with 273.1 mm in diameter and 18.2 mm in thickness. (Author) 12 refs.

1998-01-01

213

Nuclear data evaluation for sup 2 sup 3 sup 7 Np, sup 2 sup 4 sup 1 Am, sup 2 sup 4 sup 2 sup g Am and sup 2 sup 4 sup 2 sup m Am irradiated by neutrons and protons at energies up to 250 MeV

Starting from the original collective Hamiltonian of Bohr and separating the beta and gamma variables as in the X(5) model of Iachello, an exactly soluble model corresponding to a harmonic oscillator potential in the beta-variable (to be called X(5)-$\\beta^2$) is constructed. Furthermore, it is proved that the potentials of the form $\\beta^{2n}$ (with n being integer) provide a ``bridge'' between this new X(5)-$\\beta^2$ model (occuring for n=1) and the X(5) model (corresponding to an infinite well potential in the beta-variable, materialized for n going to infinity. Parameter-free (up to overall scale factors) predictions for spectra and B(E2) transition rates are given for the potentials $\\beta^2$, $\\beta^4$, $\\beta^6$, $\\beta^8$, corresponding to E(4)/E(2) ratios of 2.646, 2.769, 2.824, and ...

2004-01-01

214

Influence of valency and labelling chemistry on in vivo targeting using radioiodinated HER2-binding Affibody molecules

Evaluation of nuclear data has been performed for sup 2 sup 3 sup 7 Np, sup 2 sup 4 sup 1 Am, sup 2 sup 4 sup 2 sup g Am and sup 2 sup 4 sup 2 sup m Am. Neutron data were obtained at energies from 20 to 250 MeV and combined with JENDL-3.3 data at 20 MeV. Evaluation of the proton data has been done from 1 to 250 MeV. The coupled channel optical model was used to obtain angular distributions for elastic and inelastic scattering and transmission coefficients. Pre-equilibrium exciton model and Hauser-Feshbach statistical model were used to describe neutron and charged particles emission from excited nuclei. These evaluation is the first work for producing full sets of evaluated file up to 250 MeV for sup 2 sup 3 sup 7 Np and Americium isotopes.

2002-01-01

215

British Library Electronic Table of Contents (United Kingdom)

Purpose HER2 is a transmembrane tyrosine kinase, which is overexpressed in a number of carcinomas. The Affibody molecule ZHER2:342 is a small (7?kDa) affinity protein binding to HER2 with an affinity of 22?pM. The goal of this study was to evaluate the use of ((4-hydroxyphenyl)ethyl)maleimide (HPEM) for radioiodination of ZHER2:342 and to compare the targeting properties of monomeric and dimeric forms of ZHER2:342. Methods The biodistribution of different radioiodinated derivatives of ZHER2:342 was studied in BALB/C nu/nu mice bearing HER2-expressing SKOV-3 xenografts. Biodistributions of 125I-PIB-ZHER2:342 and site-specifically labelled 125I-HPEM-ZHER2:342-C were compared. Biodistributions of monomeric 131I-HPEM-ZHER2:342-C and dimeric ...

2009-01-01

216

Influence of residual K{sup +} on the catalytic performance of CuO-CeO{sub 2} catalysts in preferential oxidation of CO in excess hydrogen

Evolution of magnetic structures in the UNi{sub 2}Si{sub 2}-UPd{sub 2}Si{sub 2} system

Influence of residual K{sup +} on the preferential oxidation of CO in excess hydrogen (PROX) over CuO-CeO{sub 2} catalysts was investigated. CuO-CeO{sub 2} catalysts were characterized by BET, ICP, XRD, UV-Raman and TPR techniques. The results showed that the existence of residual K{sup +} made {alpha} peak in TPR of CuO-CeO{sub 2} catalysts shift to higher temperatures and depressed the PROX in the absence of CO{sub 2} and H{sub 2}O in the feed over CuO-CeO{sub 2} catalysts. However, small amount of residual K{sup +} was beneficial to the catalytic performance of CuO-CeO{sub 2} catalysts in the PROX in the presence of CO{sub 2} and H{sub 2}O in the feed. Consequently, residual K{sup +} with an appropriate content was beneficial to improve the catalytic performance of CuO-CeO{sub ...

2008-01-15

217

Evolution of magnetic structures in the UNi_2Si_2-UPd_2Si_2 system

The influence of Pd-Ni substitution on the formation of magnetic phases in the tetragonal U(Ni{sub 1-x}, Pd{sub x}){sub 2}Si{sub 2} system and the concentration magnetic phase diagram are presented. A series of different substitutions was prepared and detailed studies by powder neutron diffraction were performed for x=0.25, 0.5 and 0.75. All compounds order antiferromagnetically and form ferromagnetic basal planes stacked along the c axis (q=(0,0,q{sub z}) propagation). The ground-state phase (AF3) of UNi{sub 2}Si{sub 2} is an uncompensated AF structure (++- stacking (q{sub z}=2/3)). In UPd{sub 2}Si{sub 2} the ground-state phase corresponds to the simple AF structure AF2 (+-+-(q{sub z}=1)). In solid solutions, no traces of the AF3 phase were found for x=0.25 and the ground-state powder patterns correspond to ...

2002-07-01

218

Effects of sintering atmospheres and addition of ZrO_2 on mechanical properties of #alpha#-Sialon ceramics(x=0.15)

The influence of Pd-Ni substitution on the formation of magnetic phases in the tetragonal U(Ni_1_-_x, Pd_x)_2Si_2 system and the concentration magnetic phase diagram are presented. A series of different substitutions was prepared and detailed studies by powder neutron diffraction were performed for x=0.25, 0.5 and 0.75. All compounds order antiferromagnetically and form ferromagnetic basal planes stacked along the c axis (q=(0,0,q_z) propagation). The ground-state phase (AF3) of UNi_2Si_2 is an uncompensated AF structure (++- stacking (q_z=2/3)). In UPd_2Si_2 the ground-state phase corresponds to the simple AF structure AF2 (+-+-(q_z=1)). In solid solutions, no traces of the AF3 phase were found for x=0.25 and the ground-state powder patterns correspond to AF2 for x#>=#0.25. (orig.)

219

Comparative crystal field study of Ni{sup 2+} energy levels in NiCl{sub 2}, NiBr{sub 2}, and NiI{sub 2} crystals

4.82 wt% AIN and 2.98 wt% Y_2O_3 were added to Si_3N_4 as sintering agents in order to have #alpha#_Sialon composition of x=0.15 and monoclinic ZrO_2 between 0 to 10 wt% was admixed with Si_3N_4 based ceramics were fabricated by hot-pressing at 1,750 deg C for 90 min under 30 MPa in argon and nitrogen atmospheres effects of sintering atmospheres and addition of ZrO_2 on mechanical properties of Si_3N_4 based ceramics were investigated. As ZrO_2 content increased, the fraction of #alpha#-Sialon tended to decrease and the amount of cubic ZrO_2 increased because Y_2O_3 acted as the stabilizer of ZrO_2. The sintering atmospheres didn't affect on the sintering behavior and the product phases in hot-pressing of Si_3N_4. Bending strength increased when ZrO_2 content. ZrO_2 didn't ...

220

Comparative crystal field study of Ni"2"+ energy levels in NiCl_2, NiBr_2, and NiI_2 crystals

The exchange charge model of crystal field theory has been used to analyze systematically the ground state absorption spectra of octahedrally coordinated Ni{sup 2+} ion in isostructural nickel halide crystals NiCl{sub 2}, NiBr{sub 2}, and NiI{sub 2}. The parameters of the crystal field acting on the Ni{sup 2+} ion are calculated from the available crystal structure data. The obtained energy level schemes are compared with experimental absorption spectra; a good agreement with experimental data is demonstrated. Dependencies of the crystal field invariants and covalence effects on the type of ligands are considered. It is shown numerically that the overlap effects between Ni{sup 2+} ion and ligands increase with an increase of the ligands' atomic number resulting in the following order of the degree of covalence: NiI{sub ...

2006-01-15

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

221

Changes in intracellular Ca2+ levels induced by cytokines and P2 agonists differentially modulate proliferation or commitment with macrophage differentiation in murine hematopoietic cells.

The exchange charge model of crystal field theory has been used to analyze systematically the ground state absorption spectra of octahedrally coordinated Ni"2"+ ion in isostructural nickel halide crystals NiCl_2, NiBr_2, and NiI_2. The parameters of the crystal field acting on the Ni"2"+ ion are calculated from the available crystal structure data. The obtained energy level schemes are compared with experimental absorption spectra; a good agreement with experimental data is demonstrated. Dependencies of the crystal field invariants and covalence effects on the type of ligands are considered. It is shown numerically that the overlap effects between Ni"2"+ ion and ligands increase with an increase of the ligands' atomic number resulting in the following order of the degree of covalence: ...

2006-01-15

222

Time-series records of pCO{sub 2} and NO{sub 3} during the OMP Field Program: a final report for DOE Grant DE-FG03-96ER62224

The role of intracellular Ca2+ (Ca2+i) on hematopoiesis was investigated in long term bone marrow cultures using cytokines and agonists of P2 receptors. Cytokines interleukin 3 and granulocyte/macrophage colony stimulator factor promoted a modest increase in Ca2+i concentration ([Ca2+]i) with activation of phospholipase Cgamma, MEK1/2, and Ca2+/calmodulin kinase II. Involvement of protein kinase C was restricted to stimulation with interleukin 3. In addition, these cytokines promoted proliferation (20 times) and an increase in the Gr-1(-)Mac-1+ population with participation of gap junctions (GJ). Nevertheless ATP, ADP, and UTP promoted a large increase in [Ca2+]i, moderate proliferation (6 times), a reduction in the primitive Gr-1(-)Mac-1(-)c-Kit+ population, and differentiation into macrophages without participation of ...

2008-09-05

223

Synthesis of I-125 labeled photoaffinity rapamycin analogs

The specific goals of this research are to (1) determine daily and seasonal variability of seawater pCO{sub 2} partial pressure of CO{sub 2} and NO{sub 3} in Middle Atlantic Bight (MAB) waters; (2) estimate seasonal CO{sub 2} fluxes between the MAB shelf and the atmosphere; and (3) determine the primary controls of surface seawater pCO{sub 2} in this coastal system. During the first phase of the DOE-OMP (1992-1995) we developed the Submersible Autonomous Moored Instrument for CO{sub 2} (SAMI-CO{sub 2}) which is designed to measure seawater CO{sub 2} on ocean moorings for extended periods.

2000-04-01

224

Structure-activity relationships of anthraquinone derivatives derived from bromaminic acid as inhibitors of ectonucleoside triphosphate diphosphohydrolases (E-NTPDases)

Two no-carrier-added "1"2"5I-labelled photoaffinity rapamycin analogs were prepared: 7-demethoxy-7-(4-azido-3-"1"2"5I-benzyloxy) rapamycin and its C_2_8-C_2_9 seco analog. The key reactions of the synthesis were substitution of the C_7 methoxyl of rapamycin with 4-azido-3-tributylstannylbenzyloxy group, exchange of tributyltin with "1"2"5I using Na"1"2"5I and Chloramine-T, and a ZnCl_2 mediated retro-Aldol cleavage of the C_2_8-C_2_9 bond of rapamycin. (author).

225

British Library Electronic Table of Contents (United Kingdom)

Reactive blue 2 (RB-2) had been characterized as a relatively potent ectonucleoside triphosphate diphosphohydrolase (E-NTPDase) inhibitor with some selectivity for NTPDase3. In search for the pharmacophore and to analyze structure-activity relationships we synthesized a series of truncated derivatives and analogs of RB-2, including 1-amino-2-sulfo-4-ar(alk)ylaminoanthraquinones, 1-amino-2-methyl-4-arylaminoanthraquinones, 1-amino-4-bromoanthraquinone 2-sulfonic acid esters and sulfonamides, and bis-(1-amino-4-bromoanthraquinone) sulfonamides, and investigated them in preparations of rat NTPDase1, 2, and 3 using a capillary electrophoresis assay. Several 1-amino-2-sulfo-4-ar(alk)ylaminoanthraquinone derivatives inhibited E-NTPDases in a concentration-dependent manner. The 2-sulfonate group ...

2009-01-01

226

Spin dynamics in Ho_2Ru_2O_7

Spectral investigation of primary uranyl orthophosphate

The spin relaxation processes within the pyrochlore Ho_2Ru_2O_7 have been investigated by neutron scattering and bulk property techniques. A single-ion process, that is thermally activated, dominates the spin-spin relaxation spectrum above 2 K. Assuming Arrhenius behaviour, we found an activation energy #DELTA# = (329 #+-# 6) K and characteristic relaxation time #tau#_0 (5.2 #+-# 0.3) x 10"-"1"2 s in the paramagnetic state, akin to those found in the spin ice, Ho_2Ti_2O_7. Atlow temperature (T<95 K) the activation energy lowers and below 20 K the entropy and ac susceptibility are similar to that observed in other spin ice compounds within a 10 kOe field.

2005-11-09

227

Pretreatment of empty palm fruit bunch for production of chemicals via catalytic pyrolysis

By methods of vibrational (infrared, Raman) and PMR spectroscopy, crystallohydrate forms of monosubstituted uranyl orthophosphate have been examined. The vibrational frequencies of the groupings from the compounds were identified. The existence of non-equivalent H_2PO_4"--groups in the substances under investigation was ascertained. It has been suggested that one of them is a bridged group, and the other is the end group. A fragment of the VO_2(H_2PO_4)_2 hydrate structure is given, its main constituents being uranylphosphate chains. The analysis of water vibrations assumes coordination of one mole of H_2O in VO_2(H_2PO_4)_2:3H_2O to uranium, while two other molecules are only hydrogen-bonded with phosphate anions. Absorption within the region of 2100-2550 cm"-"1 is assigned to vibrations of ...

228

British Library Electronic Table of Contents (United Kingdom)

The effect of chemical pretreatments using NaOH, H2O2, and Ca(OH)2 on Empty Palm Fruit Bunches (EPFB) to degrade EPFB lignin before pyrolyis was investigated. Spectrophotometer analysis proved consecutive addition of NaOH and H2O2 decomposed almost 100% of EPFB lignin compared to 44% for the Ca(OH)2, H2O2 system while NaOH and Ca(OH)2 used exclusively could not alter lignin much. Next, the pretreated EPFB was catalytically pyrolyzed. Experimental results indicated the phenolic yields over Al-MCM-41 and HZSM-5 catalysts were 90wt% and 80wt%, respectively compared to 67wt% yield for the untreated sample under the same set of conditions. Meanwhile, the experiments with HY zeolite yielded 70wt% phenols.

2009-01-01

229

Magnetic properties of some RPd/sub 2/Si/sub 2/ compounds (R = Gd, Tb, Dy, Ho and Er)

La{sup 3+} modified Al{sub 2}O{sub 3} as a support for CeO{sub 2}

The magnetic susceptibility of the ternary compounds, RPd/sub 2/Si/sub 2/ (where R=Gd, Tb, Dy, Ho and Er) has been measured. GdPd/sub 2/Si/sub 2/ and TbPd/sub 2/Si/sub 2/ order antiferromagnetically at 13 and 20 K respectively; the rest of the compounds do not show clear ordering down to 4.2 K. Palladium carries no moment in these compounds. The De Gennes formula is not obeyed indicating that the exchange interaction between the 4f moments via conduction electrons is not isotropic.

1982-10-01

230

Investigation of nuclear fusion in reaction of "4","6He and "7Li on "2"0"8Pb and "2"0"9Bi nuclei

X-ray photoelectron spectroscopy measurements indicate that the Ce{sup 3+} like fraction in {gamma}-Al{sub 2}O{sub 3} supported CeO{sub 2} can be decreased by the incorporation of La{sup 3+}. If La{sup 3+} is incorporated into the {gamma}-Al{sub 2}O{sub 3} before CeO{sub 2} is added, a higher CeO{sub 2} dispersion and a greater range of reversible reducibility of the CeO{sub 2} may also be obtained. These changes offer potential for improvement in the oxygen storage capacity provided by CeO{sub 2} in three-way catalysts. The actual effect of La{sup 3+} incorporation on the activity and durability of a Pt catalyst is assessed by a combination of temperature programmed reduction and flow reactor measurements.

1993-12-31

231

Interaction studies between Crofer-22APU alloy and P2O5 containing barium calcium alumino-borosilicate (BCABS) sealant glass-ceramics

One measured fission and fusion cross sections of "4","6He+"2"0"9Bi and "7Li+"2"0"8Pb reactions within the range from the Coulomb barrier up to 200 MeV. The measured functions of fission and fusion for the mentioned reactions are shown to have close values within the excitation energy wide range. One analyzed the excitation functions of fusion and fission for "4He+"2"0"9Bi, "6He+"2"0"9Bi and "7Li+"2"0"8Pb reactions resulting in formation of "2"1"3","2"1"5At compound systems

2006-11-01

232

Effect of pressure on iodine complexes, 1

We present the effect of P2O5 addition on barium calcium aluminum borosilicate BCABS glasses of composition (mol %) 35BaO-15CaO-5Al2O3-(37-x)SiO2-8B2O3-xP2O5 (0?x?5). The incorporation of P2O5 increased network polymerization and crystallization tendency. However, addition of P2O5 leads to the formation of Cr2O3 at the interface, saturating it in the ions of the metal. This improves glass-to-metal bonding. (author)

2010-09-01

233

Current status and future prospects of rocket propellants

Absorption spectra of the visible I_2 band of I_2 complexes with Et_2O, Et_2S, and Et_2Se in heptane have been measured up to 3300 bar at 25"0C. The equilibrium constants and volume changes accompanying complex formation, the molar extinction coefficients and the absorption maxima have been estimated. The volume changes were found comparable with those estimated from the X-ray data of the I_2 complexes in the crystalline state. The enhancement of the molar extinction coefficient and the blue shift of the visible I_2 band with increasing pressure have been established. The results suggest a decrease in the bond distance between an n-donor and I_2, compared with the spectroscopic properties of the I_2 complex at 1 bar. The decrease has been estimated as 0.008 nm with increasing pressure up to 3300 bar. ...

1979-01-01

234

Concentrations of 239+240 Pu and 137 Cs in seawater near Wolsung nuclear power plant

This paper presents the current status and future prospects of rocket propellants and the development of rocket engines. The combinated rocket propellant of liquid oxygen (LO/sub 2/) and liquid hydrogen (LH/sub 2/) is so much effective that it is typically used for the main engine of the space shuttle of the U.S. LE-7 engine with the thrust output of 100 tons is being developed for H-2 launcher following H-1 launcher in Japan. Meanwhile, HM-60 engine is being developed for ARIANE-5 launcher in Europe. Although the LO/sub 2//LH/sub 2/ engine predominates in this field at present, a dual fuel engine combining LO/sub 2//LH/sub 2/ and LO/sub 2//hydrocarbon will be realized in near future. The fuel such as LNG (methane) and LPG (propane) will be used for rocket and ramjet engines. (10 refs, 2 figs, 3 ...

1987-06-20

235

Channelrhodopsin-2 gene transduced into retinal ganglion cells restores functional vision in genetically blind rats

Concentrations of "2"3"9"+"2"4"0 Pu and "1"3"7 Cs were measured for vertical direction and horizontal direction in seawater collected at 21 locations on the 8 directions near Wolsung nuclear power plant. The inventories of "2"3"9"+"2"4"0 Pu and "1"3"7 Cs were calculated in seawater column. The concentrations of "2"3"9"+"2"4"0 Pu and "1"3"7 Cs were in seawater in the range of 8-36 #mu#Bq/L, 2.4-4.5 mBq/L, respectively. The "2"3"9"+"2"4"0 Pu concentration increased with depth, however, the "1"3"7 Cs concentrations not greatly changed with depth above thermocline.

2002-05-01

236

British Library Electronic Table of Contents (United Kingdom)

To test the hypothesis that transduction of the channelrhodopsin-2 (ChR2) gene, a microbial-type rhodopsin gene, into retinal ganglion cells of genetically blind rats will restore functional vision, we recorded visually evoked potentials and tested the experimental rats for the presence of optomotor responses. The N-terminal fragment of the ChR2 gene was fused to the fluorescent protein Venus and inserted into an adeno-associated virus to make AAV2-ChR2V. AAV2-ChR2V was injected intravitreally into the eyes of 6-month-old dystrophic RCS (rdy/rdy) rats. Visual function was evaluated six weeks after the injection by recording visually evoked potentials (VEPs) and testing optomotor responses. The expression of ChR2V in the retina was investigated histologically. We found that VEPs could not b...

2010-01-01

237

Cerium moment collapse in ternary silicides CePd_2_-_xMn_xSi_2 (0#<=#x#<=#2)

CO2 CAPTURE BY ABSORPTION WITH POTASSIUM CARBONATE

Cerium L_3 XANES (x-ray-absorption near-edge-structure) spectra were analyzed to separate Ce moment contributions and mixed valence (MV) in complex magnetic silicides CePd_2_-_xMn_xSi_2 (0#<=#x#<=#2). The Ce valence mixing does not vary linearly with x, but increases rapidly for x#>=#1.5. The associated moment collapse correlates with pronounced deviations of the unit-cell volume from Vegard law and the onset of structural instability. Reorientation of [001] Mn 3d antiferromagnetic order for x<2 appears to rapidly suppress the weak Ce valence mixing coexisting with antiferromagnetic order in CeMn_2Si_2.

238

Absolute values of three neutrino masses from atmospheric mixing and an ansatz for the mixing-matrix elements

The objective of this work is to improve the process for CO{sub 2} capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous K{sub 2}CO{sub 3} promoted by piperazine. CO{sub 2} mass transfer rates are second order in piperazine concentration and increase with ionic strength. Modeling of stripper performance suggests that 5 m K{sup +}/2.5 m PZ will require 25 to 46% less heat than 7 m MEA. The first pilot plant campaign was completed on June 24. The CO{sub 2} penetration through the absorber with 20 feet of Flexipac{trademark} 1Y varied from 0.6 to 16% as the inlet CO{sub 2} varied from 3 to 12% CO{sub 2} and the gas rate varied from 0.5 to 3 kg/m{sup 2}-s.

2004-07-29

239

Transport and superconducting properties of RNi_2B_2C (R=Y, Lu) single crystals

Using data from atmospheric neutrino mixing, and a simple functional form for mixing angles, the absolute values of three neutrino masses are calculated: $m_3\\cong 5.37\\times 10^{-2} eV$, $m_2\\cong 1.94\\times 10^{-2} eV$, $m_1\\cong 1.46\\times 10^{-2} eV$. The quantities relevant for solar neutrino mixing are calculated: $(m_2^2-m_1^2) \\cong 1.63\\times 10^{-4} eV^2$, with non-maximal mixing $\\tan^2\\theta_\\sol \\cong 0.56$. The analysis gives a suggestion of a dynamical origin for the empirical, large CP-violating phase associated with an intrinsically, very small mixing angle in the quark sector.

2003-01-01

240

Theoretical studies of metal-phosphate interactions: interaction of Li+, Na+, K+, Be++, Mg++, and Ca++ with H2PO4- and (CH3O)2PO2-: implications for nucleic acid solvation.

The in-plane resistivity, in-plane absolute thermopower, and upper critical field measurements are reported for single-crystal samples of YNi_2B_2C and LuNi_2B_2C superconductors. The in-plane resistivity shows metallic behavior and varies approximately linearly with temperature near room temperature (RT) but shows nearly quadratic behavior in temperature at low temperatures. The YNi_2B_2C and LuNi_2B_2C single-crystal samples exhibit large transverse magnetoresistance (#approx#6 8% at 45 kOe) in the ab plane. The absolute thermopower S(T) is negative from RT to the superconducting transition temperature T_c. Its magnitude at RT is a few times of the value for a typical good metal. S(T) is approximately linear in temperature between #approx#150 K and RT. Extrapolation to T=0 gives large intercepts (few #mu#V/K) for both ...

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

241

Sunlight-induced efficient and selective photocatalytic benzene oxidation on TiO(2)-supported gold nanoparticles under CO(2) atmosphere.

Model phosphate-metal solvation complexes have been studied by ab-initio self-consistent-field techniques. The complexes studied include (RO)2PO2-(R = H or CH3) with Li+, Na+, K+, Be++, Mg++, Ca++,...Full Text Available

1975-10-01

242

Selective stimulation of catecholamine release from bovine adrenal chromaffin cells by an ionotropic purinergic receptor sensitive to 2-methylthio ATP

The sunlight-induced photocatalytic oxidation of aqueous benzene on TiO(2)-supported gold nanoparticles was considerably improved when the reaction was conducted under a CO(2) atmosphere. 13% yield and 89% selectivity of phenol was obtained on P25-supported gold nanoparticles under 230 kPa of CO(2). PMID:21952312

2011-09-26

243

Quantative autoradiography of inhaled "2"3"9PuO_2 in the lung

Background2-Methylthioadenosine 5'-triphosphate (2-MeSATP), formerly regarded as a specific P2Y (metabotropic) purinergic receptor agonist, stimulates Ca²⁺influx and...Full Text Available

244

Purinergic receptors are involved in tooth-pulp evoked nocifensive behavior and brainstem neuronal activity

PuO_2 particles behaved similarly in the lungs of rat and hamster. The relative concentrations of PuO_2 up to 1-yr postexposure were 1.0 for lung parenchyma, 1.3 for subpleural areas, 0.5 for peribronchiolar regions and 0.2 for perivascular regions in the lungs.

1977-05-01

245

Plasma nitriding of Sm[sub 2]Fe[sub 17

BackgroundTo evaluate whether P2X receptors are involved in responses to noxious pulp stimulation, the P2X₃and P2X_2/3receptor agonist α,;2;-methyleneATP...Full Text Available

246

Monte Carlo calculation of "1"2"9I and "2"3"7Np transmutation with relativistic protons

An intermetallic compound Sm[sub 2]Fe[sub 17]N[sub x] was synthesized by plasma nitriding of Sm[sub 2]Fe[sub 17] in a stream of N[sub 2]-H[sub 2] mixed gas. The reaction proceeded at a lower temperature (around 423 K) than that of the conventional thermal technique, but not at room temperature. This is discussed on the basis of the difference between the reaction mechanisms of plasma and thermal nitridings. (orig.)

1993-03-15

247

Magnetic behavior in the U/sub 1-x/Th/sub x/Cu_2Si_2 system

Monte Carlo calculations performed to validate observed capture reaction rates of "1"2"9I and "2"3"7Np were in a reasonable agreement with experimental data obtained by the Joint Institute for Nuclear Research. The most significant discrepancy between the measurements and calculations (within a factor of 3) was observed for the NpO_2 sample and Pb target at 3.7 GeV proton energy

1999-09-01

248

Influence of the oxygen partial pressure on the reduction of CeO{sub 2} and CeO{sub 2}-ZrO{sub 2} ceramics

The compound UC_2Si_2 has been found to be ferromagnetic at low temperatures with a Curie temperature of 101"0K. The magnetization follows a Curie-Weiss law in the paramagnetic region with an effective magneton number of 2.12 Bohr magnetons per uranium atom. Partial substitution of Th atoms for the U atoms results in an expansion of the lattice, a rapid drop in the Curie temperature, and a sizable increase in the coercive field.

1986-06-23

249

Hydrogen-induced phase transformations in H-storing alloys of zirconium

Based on recent thermodynamic estimations on the CeO{sub 2}-CeO{sub 1.5}, CeO{sub 2}-2ZrO{sub 2} and CeO{sub 1.5}-ZrO{sub 2} systems, isothermal sections of the ternary CeO{sub 2}-ZrO{sub 2}-CeO{sub 1.5} system are calculated in the 1300-1700 C region. Additionally, the complex relation between the nonstoichiometry, y, in CeO{sub 2-y}, the composition of the CeO{sub 2}-ZrO{sub 2} solid solution and the oxygen partial pressure (PO{sub 2}) for different ZrO{sub 2} containing solid solutions Ce{sub z}Zr{sub 1-z}O{sub 2-x} (with z=0.2, 0.5, 0.8) are evaluated from 600 to 900 C. The relation between the degree of Ce{sup +4} to Ce{sup +3} reduction under different PO{sub 2} in the fluorite CeO{sub ...

2005-07-01

250

High-pressure transport properties of CePd{sub 2}Si{sub 2}

In this work, the ability of a number of Zr-containing intermetallic compounds with the Zr{sub 2}Me stoichiometry, including Zr{sub 2}Fe, Zr{sub 2}Ni, Zr{sub 2}Co and Zr{sub 4}Fe{sub 2}O{sub 0.6}, to participate in the Hydrogenation-Disproportionation-Desorption-Recombination process was investigated, revealing for the first time that the HDDR route can be employed successfully for all these compounds. 24 refs.

1998-07-01

251

High-pressure transport properties of CePd_2Si_2

We report resistivity and thermopower measurements of the heavy fermion compound CePd{sub 2}Si{sub 2} at pressures up to 56 kbar. At pressures from 21 to 34.5 kbar, we measured the resistivity down to 30 mK, for all other pressure steps the temperature range was 1.2-300 K. (orig.).

1996-07-01

252

Formation and reaction activity of CeO{sub 2} nanoparticles of cubic structure and various shaped CeO{sub 2}-TiO{sub 2} composite nanostructures

We report resistivity and thermopower measurements of the heavy fermion compound CePd_2Si_2 at pressures up to 56 kbar. At pressures from 21 to 34.5 kbar, we measured the resistivity down to 30 mK, for all other pressure steps the temperature range was 1.2-300 K. (orig.).

253

Excited-state properties of platinum(II) complexes containing biphenyl as a ligand: Complexes of the type [(bph)PtL[sub 2

Mono-dispersed cubic CeO{sub 2} nanoparticles have been synthesized using a surfactant-assisted method with laurylamine hydrochloride and cerium alkoxide modified with acetylacetone in an aqueous solution system. The prepared cubic CeO{sub 2} nanoparticles had a highly crystallized structure at 353 K and formed rod-like structures by calcination at 673 K after freeze-drying the CeO{sub 2} gel. We discovered a clear potential to make 1D, 2D or 3D CeO{sub 2}-materials with a well-controlled characteristic length and shape by assembling cubic-shaped CeO{sub 2} nanoparticle building blocks. CeO{sub 2}-TiO{sub 2} composite nanostructures have also been synthesized by changing the mole ratio of cerium alkoxide/titanium alkoxides. By utilizing the redox characteristic of CeO{sub 2}, CeO{sub ...

2007-07-15

254

Effect of Rapid Human N-acetyltransferase 2 Haplotype on DNA Damage and Mutagenesis Induced by 2-Amino-3-methylimidazo [4,5-f] quinoline (IQ) and 2-Amino-3,8-dimethylimidazo-[4,5-f]quinoxaline (MeIQx)

The preparation, physical properties, and photophysical properties of [Pt(bph)(C[sub 2]H[sub 5])[sub 2]S][sub 2], [Pt(bph)(CH[sub 3]CN)[sub 2

1992-07-22

255

Dramatic Effects of 2-Bromo-5,6-Dichloro-1-?-d-Ribofuranosyl Benzimidazole Riboside on the Genome Structure, Packaging, and Egress of Guinea Pig Cytomegalovirus

Heterocyclic amines such as 2-amino-3-methylimidazo [4,5-f] quinoline (IQ) and 2-amino-3,8-dimethylimidazo [4,5-f] quinoxaline (MeIQx) are dietary carcinogens generated when meats are cooked...Full Text Available

2010-02-03

256

Densities and molar volumes of molten alkaline earth bromide - alkali bromide salt mixtures

The halogenated benzimidazoles BDCRB (2-bromo-5,6-dichloro-1-;2;-d-riborfuranosyl benzimidazole riboside) and TCRB (2,5,6-trichloro-1-;2;-d-riborfuranosyl benzimidazole...Full Text Available

2004-02-01

257

Conductance quantization in ferromagnetic Ni nano-constriction

The temperature and concentration dependence of the densities of binary CaBr_2-(Li, Na, K, Rb, Cs)Br, NaBr-(Sr, Ba)Br_2 and KBr-SrBr_2 mixtures have been measured using the method of hydrostatic weighing. With exception of the systems LiBr-CaBr_2 and NaBr-(Sr, Ba)Br_2 the calculated molar excess volumes are positiv in the investigated mixtures. (author).

1980-01-01

258

Clavulanic Acid, a Novel Inhibitor of ?-Lactamases

The conductance in ferromagnetic Ni nano-wire is quantized in units of 2e{sup 2}/h in the absence of magnetic field, while the units switch to e{sup 2}/h in the magnetic field. The fractional units of 0.7e{sup 2}/h and 1.4e{sup 2}/h with and without magnetic field appear under the application of high bias-voltage. The spin polarization and bias-voltage play an important role in the electric conduction.

2002-02-01

259

Cellular Sources of Transforming Growth Factor-? Isoforms in Early and Chronic Radiation Enteropathy

Clavulanic acid, Z-(2R,5R)-3-(;2;-hydroxyethylidene)-7-oxo-4-oxa-1-azabicyclo-[3,2,0] heptane-2-carboxylic acid, has been shown to be an effective inhibitor of the ;2;-lactamases of the...Full Text Available

1978-11-01

260

Binding the Mammalian High Mobility Group Protein AT-hook 2 to AT-Rich Deoxyoligonucleotides: Enthalpy-Entropy Compensation

The three mammalian transforming growth factor (TGF)-;2; isoforms (TGF-;2;1, TGF-;2;2, and TGF-;2;3) differ in their putative roles in radiation-induced fibrosis in intestine...Full Text Available

1998-11-01

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261

Analysis of Am-242m in solidified products

HMGA2 is a DNA minor-groove binding protein. We previously demonstrated that HMGA2 binds to AT-rich DNA with very high binding affinity where the binding of HMGA2 to poly(dA-dT)₂ is enthalpy-driven...Full Text Available

2009-05-20

262

An enhancer element is located 340 base pairs upstream from the adenovirus-2 E1A capsite.

When solidified products made from low-level radioactive waste with melting treatment are disposed of in near surface repositories, concentrations of the radionuclides contained in the waste package have to be evaluated. Americium-242m is one of the targeted nuclides. In this study, simple analytical methods to evaluate the activity of "2"4"2"mAm are studied. Americium, Cm and Eu in a sample solution made from simulated solidified product and tracer of "1"5"2Eu and "2"4"4Cm and unknown solution of "2"4"1"+"2"4"2"m"+"2"4"3Am were separated from matrix elements with TRU resin. The fraction containing Eu, Am and Cm was passed through pyridine resin to separate Am from Eu and Cm. The contamination factor of "2"4"4Cm/"2"4"1Am was less than 3.0x10"-"3. Curium-242 generated from "2"4"2Am was measured to evaluate the activity of ...

2006-10-01

263

?₂ integrins are required for skin homing of primed T cells but not for priming naive T cells

A chimeric recombinant, containing the 270 bp left-terminal fragment of Adenovirus-2 (Ad2) inserted upstream from the -34 to +33 Ad2 major late promoter (Ad2MLP) element, has been used to characterize...Full Text Available

1983-12-20

264

(Phospinoalkyl)silyl complexes. 10. Formation of chelated bis[(diphenylphosphinoethyl)diorganosilyl]platinum(II) complexes. Precoordination through phosphorus, intermediacy of a platinum(IV) disilyl, and diastereoisomerism at planar platinum(II) in 'chelate-assisted' hydrosilylation

;2;₂ integrins are of critical importance for leukocyte extravasation through vascular endothelia and for T cell activation. To elucidate the role of ;2;₂ integrins...Full Text Available

2002-01-15

265

DECAY OF Ta$sup 177$ AND Lu$sup 177$ TO LEVELS IN Hf$sup 17$$sup 7$

Addition of the silane PPh[sub 2]CH[sub 2]CH[sub 2]SiMe[sub 2]H (chelH, 1a) to Pt(COD)[sub 2] (COD = cycloocta-1,5-diene) affords in high yield the cis-bis chelate Pt(chel)[sub 2] (2); formation of the same product from Pt(COD)(X)Y (X = Y = Me; X = Me, Y = Cl) has been shown by NMR spectroscopy ([sup 1]H, [sup 31]P, [sup 195]Pt) to proceed via prior coordination of chelH through P to afford Pt(chelH)[sub 2](X)(Y) (cis and trans isomers) and through intermediacy of PtH(chel)[sub 2]Cl (22) in which P trans to Si at Pt(IV) leads to an exceptionally low [sup 2]J(Pt-P) = 1084 Hz. Cleavage of Pt-Si bonds in 2 by HCl can be controlled to give the monochelate species Pt(chel)(chelH)Cl (7), from which chelH is displaced by PMe[sub 2]Ph, or ...

1991-08-21

266

Spectroscopic Studies of Phosphazene Polymers Containing Photoluminescent Metal Complexes

The decays of Ta/sup 177/ and Lu/sup 177/ to levels in vestigated with beta spectrometers, NaI(Tl) gamma spectrometers, and fast coincidence and angular correlation techniques. Energy levels in Hf/sup 177/ were characterized according to their energy (kev), the Nilsson asymptotic quantum numbers (Nn/sub 2/ LAMBDA ), the total angular momentum and its component along the symmetry axis (I,K), and the parity ( pi ) as follows: 0STA5I4 7/2, 7/2-!; 112.97STA514 9/2, 7/ 2-!; 249.7STA5I4 11/2, 7/1-!; 32l.34STA624 9/2, 9/2+1; 447.9STA624 11/2, 585.8STA642 7/2, 3/2+1; 509.0STA5I2 5/2, 5/1-1; 605.5STA512 7/2, 5/2-!; 746.04STA633 7/2, ...

1961-10-15

267

British Library Electronic Table of Contents (United Kingdom)

Abstract A series of small phosphazene ligands with pendant 6-phenyl-2,2--bipyridyl moieties, namely L1 [N3P3(OPh)5(OPhbpyPh)], L2 [N3P3(biph)2(OPhbpyPh)2], L3 [N3P3(tBubiph)2(OPhbpyPh)2], L4 [N3P3(biph)2(OPhbpyPh)Cl] and L5 [N3P3(biph)2(OPhbpyPh)(OPh)] [OPhbpyPh = 4-(4-phenoxy)-6-phenyl-2,2--bipyridine, OPh = phenoxy, biph = 2,2--oxybiphenyl and tBubiph = 4,4--di-tert-butyl-2,2--oxybiphenyl], have been used to synthesise the new cyclometallated palladium(II) and platinum(II) complexes [(L1-H)PdCl], [(L1-H)PtCl], [(L1-H)(PdCl)2], [(L3-H)(PdCl)2], [(L4-H)PtCl], [(L5-H)PtCl] and the rhenium(I) complex [L5Re(CO)3Cl]. Single-crystal X-ray diffraction analysis was performed on the free ligand L2 and ...

2011-01-01

268

Role of CeO{sub 2} in Ni/CeO{sub 2}-Al{sub 2}O{sub 3} catalysts for carbon dioxide reforming of methane

Optical and electrochemical properties of CeO[sub 2] and CeO[sub 2]-TiO[sub 2] coatings

Ni catalysts supported on {gamma}-Al{sub 2}O{sub 3}, CeO{sub 2} and CeO{sub 2}-Al{sub 2}O{sub 3} systems were tested for catalytic CO{sub 2} reforming of methane into synthesis gas. Ni/CeO{sub 2}-Al{sub 2}O{sub 3} catalysts showed much better catalytic performance than either CeO{sub 2}- or {gamma}-Al{sub 2}O{sub 3}-supported Ni catalysts. CeO{sub 2} as a support for Ni catalysts produced a strong metal-support interaction (SMSI), which reduced the catalytic activity and carbon deposition. However, CeO{sub 2} had positive effect on catalytic activity, stability, and carbon suppression when used as a promoter in Ni/{gamma}-Al{sub 2}O{sub 3} catalysts for this reaction. A weight loading of 1-5wt% CeO{sub 2} was found to ...

1998-12-07

269

Effective thickness of CeO{sub 2} buffer layer for YBCO coated conductor by advanced TFA-MOD process

Thin solid films of CeO[sub 2] and mixed CeO[sub 2]-TiO[sub 2] were prepared by the sol-gel route via the dip-coating technique. Particulate sols of ceria were made from inorganic ((NH[sub 4])[sub 2]Ce(NO[sub 3])[sub 6]) precursor which were used for preparation of CeO[sub 2] thin solid films while CeO[sub 2]-TiO[sub 2] coatings have been made by using mixed organic-inorganic (Ti(OiPr)[sub 4] and CeCl[sub 3].7H[sub 2]O) precursors. The solar transmission values (T[sub s]) of both coatings are in the range 0.6-0.8 and depend on coating thickness. Cyclic voltammetric (CV) measurements show that the CeO[sub 2]/LiOH system exhibits higher overall electrochemical reversibility when compared to the CeO[sub 2]-TiO[sub 2]/LiOH system. The CeO[sub ...

1993-11-01

270

Calculated doses from inhaled transuranium radionuclides and potential risk equivalence to whole-body radiation

YBCO films were fabricated on PLD-CeO{sub 2}/IBAD-Gd{sub 2}Zr{sub 2}O{sub 7}/Hastelloy substrates using the advanced TFA-MOD process. The effective thickness of the CeO{sub 2} buffer layer for obtaining high I{sub c} was investigated in short samples of YBCO films. The CeO{sub 2} buffer layer was epitaxially grown on an IBAD-Gd{sub 2}Zr{sub 2}O{sub 7} template tape with 18 deg. of {delta}{phi} by a reel-to-reel PLD system. The in-plane grain alignment of PLD-CeO{sub 2} buffer layers rapidly improved with the thickness and saturated at a critical thickness of 0.8 {mu}m. The size of CeO{sub 2} grains was about 1 {mu}m at the saturated thickness of {delta}{phi}. YBCO films with the thickness of 1 {mu}m were deposited by the TFA-MOD on the CeO{sub 2} buffer layer with different ...

2007-10-01

271

An experimental investigation of H{sub 2} emissions of a 2004 heavy-duty diesel engine supplemented with H{sub 2}

The distribution of radiation dose commitments within the body that can result from the lung deposition of a number of transuranic radionuclides ("2"3"7Pu, "2"3"8Pu, "2"3"9Pu, "2"4"0Pu, "2"4"1Pu, "2"4"2Pu, "2"4"3Pu, "2"4"4Pu, "2"4"1Am, "2"4"2Am, "2"4"3Am, "2"4"4Am, "2"4"2Cm, "2"4"3Cm, "2"4"4Cm, and "2"4"6Cm) was calculated. The variables that influence these organ dose commitments include the mobility of the particle or its dissolution products within the body, the radiation characteristics of the inhaled radionuclides and their progeny, and the size of the particles inhaled. In the calculation of organ dose commitments for whole-body, lungs, liver, bone ...

1975-11-17

272

{alpha}-Sb{sub 2}O{sub 4}-induced improvements of the catalytic behavior of MoO{sub 3}-(010) in the oxygen-assisted dehydration of 2-butanol: implications in selective oxidation

Hydrogen (H{sub 2}) emissions characteristics of H{sub 2}-diesel dual fuel engine were measured using a 2004 turbocharged heavy-duty diesel engine with H{sub 2} supplemented into the intake air. The emissions of H{sub 2} were measured using an Electron Pulse Ionization (EPI) Mass Spectrometer (MS). The effect of the amount of H{sub 2} added, the engine load, and diesel fuel flow rates on the emissions of H{sub 2} and its combustion efficiency in the engine were investigated. The addition of H{sub 2} under high load operation was notable for its ability to obtain high H{sub 2} combustion efficiency and improve brake thermal efficiency. However, the addition of H{sub 2} at low load resulted in high emissions of H{sub 2} due to the failure to initiate and support a sufficiently ...

2010-10-15

273

Use of synthetic oligoribonucleotides to probe RNA-protein interactions in the MS2 translational operator complex.

This article concerns the synergetic effects between an MoO{sub 3} sample composed of crystallites exposing preferentially the (010) basal faces and {alpha}-Sb{sub 2}O{sub 4} in the oxygen-assisted dehydration of 2-butanol at 220 C. The conversion of 2-butanol and the yield to butene improved when MoO{sub 3} was reacted in the presence of {alpha}-Sb{sub 2}O{sub 4}. The origin of the synergism is discussed. When reacted in the absence of {alpha}-Sb{sub 2}O{sub 4}, MoO{sub 3} got over-reduced and fragmented to MoO{sub 2}. MoO{sub 2} is intrinsically less active than MoO{sub 3} thus explaining that the deep reduction of MoO{sub 3} corresponds to its tendency to deactivate. In the presence of {alpha}-Sb{sub 2}O{sub 4}, the formation of MoO{sub 2} is inhibited with, as a consequence, the absence of ...

1998-12-31

274

Understanding the nature of the statistics behind energy-related CO{sub 2} emissions

Synthetic oligoribonucleotides have been used to probe the interaction of MS2 coat protein with the translational operator of the MS2 replicase gene. We have investigated the possible formation of a...Full Text Available

1990-06-25

275

Type I Collagen Is a Genetic Modifier of Matrix Metalloproteinase 2 in Murine Skeletal Development

Research reported here reveals that the reduction of CO{sub 2} emissions into the atmosphere, is mainly dependent on the decrease of the use of fossil fuels, but also on the development of environment-friendly technology and greening of the environment. 2 refs.

2001-07-01

276

Towards Formalizing the Java Security Architecture of JDK 1.2

Recessive inactivating mutations in human matrix metalloproteinase 2 (MMP2, gelatinase A) are associated with syndromes that include abnormal facial appearance, short stature, and severe bone...Full Text Available

2007-06-01

277

Time-dependent infrared emission following photodissociation of nitromethane and chloropicrin.

Page 1. Towards Formalizing the Java Security Architecture of JDK 1.2 Lora L. Kassab1 and Steven J. Greenwald2 ... 4 Java Access Model ...

2011-05-14

278

The implication of Sir2 in replicative aging and senescence in Saccharomyces cerevisiae

Nitromethane (CH(3)NO(2)) and its chlorinated analogue, chloropicrin (CCl(3)NO(2)), were photolyzed at 193, 248, and 266 nm, and the products were observed by time-dependent Fourier transform infrared emission spectroscopy. At 193 and 248 nm, the primary photodissociation pathway for nitromethane was cleavage of the C-N bond to produce CH(3) + NO(2)(A (2)B(2)). At 266 nm, weak emission was observed following photodissociation of nitromethane, but an infrared spectrum could not be obtained. The photodissociation of chloropicrin at 193 nm produced the analogous product channel CCl(3) + NO(2)(A (2)B(2)) in addition to several other product channels. At 248 and 266 nm, only CCl(3) + NO(2)(A (2)B(2)) was observed. The production of phosgene ...

2006-04-01

279

The Notochord, Notochordal cell and CTGF/CCN-2: ongoing activity from development through maturation

The target of rapamycin (TOR) pathway regulates cell growth and aging in various organisms. In Saccharomyces cerevisiae, silent information regulator 2 (Sir2) modulates cellular senescence. Moreover,...Full Text Available

280

The Effect of O2, H2O, and N2 on the Fatigue Crack Growth Behavior of an Alpha + Beta Titanium Alloy at 24 C and 177 C

The growth regulating factor CTGF/CCN-2 is an integral factor in growth and development, connective tissue maintenance, wound repair and cell cycle regulation. It has recently been reported that CTGF/CCN-2...Full Text Available

2008-12-01

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281

The Arabidopsis ref2 Mutant Is Defective in the Gene Encoding CYP83A1 and Shows Both Phenylpropanoid and Glucosinolate Phenotypes

To study the effects of atmospheric species on the fatigue crack growth behavior of an a+B titanium

2001-01-01

282

T1 and T2 relaxivities of succimer-coated MFe23+O4 (M=Mn2+, Fe2+ and Co2+) inverse spinel ferrites for potential use as phase-contrast agents in medical MRI

The Arabidopsis ref2 mutant was identified in a screen for plants having altered fluorescence under UV light. Characterization of the ref2 mutants showed that they...Full Text Available

2003-01-01

283

Syndecan-2 Regulates the Migratory Potential of Melanoma Cells*

Superparamagnetic MFe23+O4 (M=Mn2+, Fe2+ and Co2+) inverse spinel ferrite (ISF) nanoparticles with narrow size distribution having average diameters of 6-8 nm were synthesized by a diol reduction of organic metals and the surface was modified to be hydrophilic by coating with succimer. Magnetic resonance imaging (MRI) contrast enhancement by dipolar coupling defined interactions between the synthesized ISFs and protons in the bulk water was investigated with initial susceptibility, magnetization and anisotropy of the succimer-coated ISFs. The relaxivity ratios, r2/r1, for MnFe2O4, Fe3O4 and CoFe2O4 were measured to be 12.2, 23.1 and 62.3, respectively, which demonstrate the potential usefulness of these magnetic nanoparticles as T2 contrast agents for MRI.

2009-12-01

284

Sunlight photocatalytic activity of CdS modified TiO2 loaded on activated carbon fibers

Syndecan-2, a transmembrane heparan sulfate proteoglycan, is a critical mediator in the tumorigenesis of colon carcinoma cells. We explored the function of syndecan-2 in melanoma, one of the most invasive...Full Text Available

2009-10-02

285

British Library Electronic Table of Contents (United Kingdom)

To improve the photocatalytic application performances of TiO2, in this work, firstly CdS modified Degussa P25 TiO2 (CdS/TiO2) composites were prepared by two methods, sol-gel method and precipitation method. Next they, sol-gel-CdS/TiO2 (sg-CdS/TiO2) and precipitation-CdS/TiO2 (pp-CdS/TiO2), were loaded on activated carbon fibers (ACFs) by dip-coating method using the sodium carboxymethyl cellulose as adhesives. The composites were characterized by XRD, UV-vis absorbance spectra, SEM, EDS and BET. The photocatalytic activities under sunlight were investigated by the degradation of methylene blue. The results showed that CdS/TiO2 composites were mainly composed of anatase-TiO2 and little CdS cubic phases. The absorption wavelengths of sg-CdS/TiO2 and ...

2010-01-01

286

Structural Characterization and Photoluminescent Properties of (La1-xSmx)2Ti2O7 Solid Solutions Synthesized by a Sol-Gel Route

British Library Electronic Table of Contents (United Kingdom)

Abstract A series of compounds with the general formula (La1-xSmx)2Ti2O7 (0-- x --1.0) has been synthesized by a sol-gel method and characterized by XRD, Raman spectroscopy, and scanning electron microscopy (SEM). These compounds are structurally isomorphic to perovskite-type La2Ti2O7 until a substitution rate of x = 0.8. Above this substitution rate (x >-0.8), a biphasic mixture is obtained between the substituted perovskite layered phase and the pyrochlore Sm2Ti2O7 phase. The unusual phosphor (La1-xSmx)2Ti2O7 has been elaborated and its luminescent properties were investigated for low rates of substitution. The emission and excitation spectra were used to study the luminescent properties. The (La1.9Sm0.1)2Ti2O7 powders emit bright red-orange lightunder UV excitation. The ...

2011-01-01

287

Stability studies of the chlorine containing phase at the SiO/sub 2//Si interface produced by HCl/O/sub 2/ oxidation of silicon

SiO/sub 2//Si samples prepared in 2% and 4% HCl/O/sub 2/ mixtures at 1200/sup 0/C have been annealed in H/sub 2/O/N/sub 2/ ambients at 1200/sup 0/C. The anneals ranged up to 16 hrs in ambients with 4 or 40 ppM H/sub 2/O in N/sub 2/. Rutherford backscattering measurements have been made to determine the amount and location of Cl incorporated in these samples. A linear loss of Cl with annealing time is found for all samples. Changes in the distribution of Cl near the SiO/sub 2//Si interface are found. These changes are interpreted in terms of morphological changes in the third (Cl containing) phase. A significant effect of the H/sub 2/O content of the N/sub 2/ ambient is observed.

1980-01-01

288

September 30, .999

SIRT1 contributes to telomere maintenance and augments global homologous recombination

... JSTARS 98 8,759.8 8,351.2 15 - - - MILSTAR 90 - - 6 - - - MINUTEMAN III GRP 93 2,032.3 2,403.6 652- - - MINUTEMAN III PRP ...

289

Revision number 2 to test design description Volume IB, Part 2 (WHC-SP-0214) FSP-1R FFTF test assembly (HF191A)

Yeast Sir2 deacetylase is a component of the silent information regulator (SIR) complex encompassing Sir2/Sir3/Sir4. Sir2 is recruited to telomeres through Rap1, and this complex spreads into subtelomeric...Full Text Available

2010-12-27

290

Protein thiolation and reversible protein-protein conjugation. N-Succinimidyl 3-(2-pyridyldithio)propionate, a new heterobifunctional reagent.

Based on changes to the fuel pin gas gap composition, pin location and assembly location, revisions to the TDD-IB, Part 2 are provided.

1989-07-14

291

Production of 'no-carrier-added' "2"0"1Tl

A heterobifunctional reagent, N-succinimidyl 3-(2-pyridyldithio)propionate, was synthesized. Its N-hydroxysuccinimide ester group reacts with amino groups and the 2-pyridyl disulphide structure reacts...Full Text Available

1978-09-01

292

Plasma nitriding of austenitic stainless steel in N_2 and N_2/H_2 gas admixture

A procedure has been developed for producing a radiopharmaceutically pure ''no-carrier-added'' "2"0"1Tl. The procedure is based on irradiating enriched metallic thallium (> 96% "2"0"3Tl) targets with approx. 30 Mev protons, separating "2"0"1Pb by co-precipitation with SrSO_4 from sulphuric acid solution, and extracting "2"0"1Tl (after its in-growth) with butyl acetate from a hydrochloric solution. The average overall yield of "2"0"1Tl is approx. 92%. The radioactive concentration of the product exceeds 2 mCi/mL; radionuclide impurities-"2"0"0Tl <= 0.5%; "2"0"2Tl <= 0.1%; "2"0"3Pb <= 0.02%; inactive impurities (#mu#g/mL)-Tl < 2, Sr < 1, Fe < 0.25, Cu < 0.05; pH within the range 5-8. The product is sterile, apyrogenic, and suitable for clinical application. ...

293

Physicochemical Characterization of Berberine Chloride: A Perspective in the Development of a Solution Dosage Form for Oral Delivery

Plasma nitriding in glow discharge is a process of modifying surface properties of a material by which surface hardness, corrosion resistance, fatigue strength etc. of a material can be improved

2004-09-01

294

Photosynthesis by sugar-cane leaves

The objective of the present research was to evaluate the physicochemical characteristics of berberine chloride and to assess the complexation of drug with 2-hydroxypropyl-;2;-cyclodextrin (HP;2;CD),...Full Text Available

295

Photoaffinity-labeled Cytokinins

1. Radioactive products in detached leaf segments were examined after periods of steady-state photosynthesis in ¹⁴CO₂. 2. After exposure to ¹⁴CO₂ for approx....Full Text Available

1966-10-01

296

Two new azidopurine derivatives, 2-azido-N⁶-(Δ²-isopentenyl)adenine and 2-azido-N⁶-benzyladenine, have been synthesized as...Full Text Available

1976-12-01

297

On the decay of "2"0"3Bi

Observation of two charged bottomonium-like resonances

The radioactive decay of "2"0"3Bi is studied. A level scheme is proposed for "2"0"3Pb on the basis of #gamma#-ray and electron spectra and #gamma#-#gamma# coincidence measurements. The experimental data are compared with theoretical results obtained in a three quasiparticle approximation. (Auth.).

298

Nrf2 increases survival and attenuates alveolar growth inhibition in neonatal mice exposed to hyperoxia

We report the observation of two narrow structures at 10610MeV/c^2 and 10650MeV/c^2 in the pi^{\\pm}Upsilon(nS) (n=1,2,3) and pi^{\\pm}h_b(mP) (m=1,2) mass spectra that are produced in association with a single charged pion in Upsilon(5S) decays. The measured masses and widths of the two structures averaged over the five final states are M_1=10608.4\\pm2.0MeV/c^2, Gamma_1=15.6\\pm2.5MeV and M_2=10653.2\\pm1.5MeV/c^2, Gamma_2=14.4\\pm3.2MeV. Analysis favors quantum numbers of I^G(J^P)=1^+(1^+) for both states. The results are obtained with a 121.4fb^{-1} data sample collected with the Belle detector near the Upsilon(5S) resonance, at the KEKB asymmetric-energy e+e- collider.

2011-01-01

299

New dioxomolybdenum(VI) complexes with tridentate dibasic ONO donor schiff bases

Increased oxidative stress is associated with perinatal asphyxia and respiratory distress in the newborn period. Induction of nuclear factor erythroid 2 p45-related factor (Nrf2) has been shown to decrease...Full Text Available

2009-04-01

300

NKX2-3 Transcriptional Regulation of Endothelin-1 and VEGF Signaling in Human Intestinal Microvascular Endothelial Cells

Several dioxomolybdenum(VI) complexes of the schiff bases derived from salicylaldehyde, 2-hydroxy-1-naphthaldehyde, o-hydroxyacetophenone or pyridoxal and o-aminobenzylalcohol, o-aminophenol, o-hydroxybenzylamine, o-hydroxy(methylbenzyl)amine or 3-amino-2-naphthoic acid have been synthesized and characterized by elemental analysis, electrical conductance, molecular weight, IR and electronic spectral and magnetic susceptibility measurements. The schiff bases behave as dibasic, tridentate ligands and coordinate through ONO donor system forming complexes of the type MoO_2L.X (where LH_2=schiff base, X=H_2O or Ch_3OH). The compounds MoO_2L.Ch_3OH react with 2,2'-dipyridyl to form heterochelates of the type MoO_2L.dipyridyl. The complexes are non-electrolytes, monomers, diamagnetic and possess a cis-MoO_2 ...

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301

NASA reopens space station job notices - Johnson Space Center

BackgroundNKX2-3 is associated with inflammatory bowel disease (IBD). NKX2-3 is expressed in microvascular endothelial cells and the muscularis...Full Text Available

302

N-acetyltransferase 2 slow acetylator genotype associated with adverse effects of sulfasalazine in the treatment of inflammatory bowel disease

Oct 11, 1993 ... Lease: Meadowgreen,3-2.5-2, 2 storyon cuI- ..... also will have the Lunar Landing Training Vehicle elevated over the center of the ...

303

Morbidity in relation to stage of diabetic nephropathy in type-2 diabetic patients.

AIM:N-acetyltransferase 2 (NAT2) is an important enzyme catalyzing N-acetylation of sulfasalazine (SASP). The aim of the present study was to investigate...Full Text Available

2007-03-01

304

Microbial transformation of artificial estrogens of the allenolic group.

AIMS OF THE STUDY: Type-2 diabetic patients have excessive cardiovascular mortality, primarily related to diabetic nephropathy. The extent of the morbidity due to nephropathy in type-2 diabetes mellitus...Full Text Available

2003-11-01

305

When 2,2-dimethyl 3-(2'-naphthyl 6'-hydroxy) pentanoic acid, an artificial estrogen of the allenolic acid group, was added to an exponential-phase growth culture of Neurospora crassa (in Horowitz medium),...Full Text Available

1975-06-01

306

Metabolism of Cytokinin

Long-term effects of inhaled uranyl nitrate in rats

As part of the study of cytokinin metabolic pathways, an enzyme, adenosine phosphorylase (EC 2.4.2.-), which catalyzed the ribosylation of N⁶-(Δ²-isopentenyl)adenine,...Full Text Available

1978-12-01

307

Insulin and Glucagon Regulate Pancreatic ?-Cell Proliferation

Rats were exposed to aerosols of "2"3"3U and "2"3"2U nitrate in a study of the long-term biological effects. Preliminary radiation dose estimates show lung > skeleton > kidney in each dose group.

1977-05-01

308

Influence of crystallization on the spectral features of nano-sized ferroelectric barium strontium titanate (Ba0.7Sr0.3Tio3) thin films

Type 2 diabetes mellitus (T2DM) results from insulin resistance and ;2;-cell dysfunction, in the setting of hyperglucagonemia. Glucagon is a 29 amino acid peptide hormone, which is secreted from...Full Text Available

309

British Library Electronic Table of Contents (United Kingdom)

Ferroelectric barium strontium titanate (Ba0.7Sr0.3TiO3)(BST) thin films have been prepared from barium 2-ethylhexanoate [Ba[CH3(CH2)3CH(C2H5)CO2]2], strontium 2-ethylhexanoate [Sr[CH3(CH2)3CH(C2H5)CO2]2] and titanium(IV) isopropoxide [TiOCH(CH3)2]4 precursors using a modified sol-gel technique. The precursor except [TiOCH(CH3)2]4 were synthesized in the laboratory. Transparent and crack-free films were fabricated on pre-cleaned quartz substrates by spin coating. The structural and optical properties of films annealed at different temperatures have been investigated. The as-fired films were found to be amorphous that crystallized to the tetragonal phase after annealing at 550degreeC for 1h in air. The lattice constants "a" and "c" were found to be 3.974A and 3.990A, respectively. ...

2008-01-01

310

Inactivation and Heat Stabilization of Poliovirus by 2-Thiouracil ¹

Hot-pressed MoSi_2-particulate-reinforced #alpha#-SiAlON composites

Treatment of poliovirus Type I with 10⁻³m 2-thiouracil (2-TU) resulted in the inactivation of greater than 90% of the virus infectivity and stabilization of approximately...Full Text Available

1967-08-01

311

Haplotype of N-Acetyltransferase 1 and 2 and Risk of Pancreatic Cancer

MoSi_2-particulate-reinforced #alpha#-SiAlON ceramic composites 10, 20, 25, and 30 vol% were prepared by at 1,750--1,800C. The #alpha#-SiAlON matrix was of the composition (Y_0_._4_8Si_1_0_._0_0Al_2_._3_0O_1_._1_7N_1_5_._2_9). The hardness for the fully dense samples changed from HV10 = 22.5 to 15.3 GPa and the toughness from 3.2 to around 5.2 MPa#centre dot#m"1"/"2 when up to 30 vol% MoSi_2 was present. Two interesting microstructural features have been found. First, with an increasing amount of MoSi_2 a pronounced coalescence of MoSi_2 particles formed a ''dual phase'' material. The second effect was the growth of elongated #alpha#-SiAlON grains in the matrix with 10 vol% MoSi_2 added. The oxidation resistance has been determined, to be unaffected by the addition of 20 vol% ...

312

Half-lives of "1"9"6Au, "1"9"5","1"9"7","2"0"3Hg, and "2"0"3Pb from photoactivation experiments

We examined the association between N-acetyltransferase 1 and 2 (NAT1 and NAT2) haplotype and risk of pancreatic cancer by genotyping eight...Full Text Available

2007-11-01

313

... v. 36(2) NUCLEAR PHYSICS AND RADIATION PHYSICS beta-minus decay

314

Global emission trends

Fluorescence quantum yields and cascade-free lifetimes of state selected CO_2"+, COS"+, CS_2"+ and N_2O"+ determined by photoelectron-photon coincidence spectroccopy

Emissions of sulphur and nitrogen oxides are continuing to fall in Europe but rise in Asia, according to calculations based on individual countries' predictions of economic development. The upward trend is slower than in previous predictions. 2 refs., 2 figs., 2 tabs.

2005-06-01

315

FLIS Procedures Manual. Multiple Application Procedures.

The details and principles of an apparatus built for measurements of fluorescence quantum yields and cascade-free lifetimes of open-shell cations are reported. These rely on the detection of coincidences between energy selected photo-electrons and undispersed photons. The results of such measurements for CO"+_2,COS"+,CS"+_2 and N_2O"+ in selected vibrational levels of their excited states are presented. Non-unity fluorescence quantum yields are found for some vibronic levels of CO"+_2(B), COS"+(A), N_2O"+(A) and a non-exponential decay is observed for CS"+_2(B). The data yield the following values for the radiative lifetimes: CO"+_2(A) 124 +- 6 ns,CO"+_2(B) 140 +- 7 ns, COS"+(A) 550 +- 50 ns and N_2O"+(A) 240 +- 12 ns. (orig.).

1980-10-01

316

Experimental infection of Foxes with European bat Lyssaviruses type-1 and 2

... Volume(s) Volume(s) II Item Identification 1,2,3,4, JANAP Joint Army-Navy- 2,7 5,6,13 Air Force JIM Item Intelligence 2 Publication Maintenance ...

1996-10-01

317

Essential Role of Phox2b-Expressing Ventrolateral Brainstem Neurons in the Chemosensory Control of Inspiration and Expiration

BackgroundSince 1954, there have been in excess of 800 cases of rabies as a result of European Bat Lyssaviruses types 1 and 2 (EBLV-1, EBLV-2) infection, mainly...Full Text Available

318

Emergence of Klebsiella pneumoniae Coproducing KPC-2 and 16S rRNA Methylase ArmA in Poland ?

Phox2b-expressing neurons of the retrotrapezoid nucleus (RTN) located in the ventrolateral brainstem are sensitive to changes in PCO₂/pH, have excitatory projections...Full Text Available

2010-09-15

319

Effects of Protons and HZE Particles on Glutamate Transport in Astrocytes, Neurons and Mixed Cultures

A Klebsiella pneumoniae epidemic strain that coproduced carbapenemase KPC-2 (K. pneumoniae carbapenemase 2) and 16S rRNA methylase ArmA has emerged in Poland. Four...Full Text Available

2011-01-01

320

Effects of Cr content and the addition of Cr_2O_7"2"- ion on corrosion resistance of stainless steel in nitric acid solutions

... ions. MATERIALS AND METHODS Cell Culture Culture of NT2/D1 cells was carried out as described previously (18, 19). NT2 cells were plated at a density of 2. ... ...

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321

Different distribution of fluorinated anesthetics and nonanesthetics in model membrane: a 19F NMR study.

A nitric acid solution containing Cr_2O_7"2"- ion is used for a corrosion test which simulates the condition in a nuclear fuel reprocessing plant. As the effect of Cr content on the corrosion resistance of stainless steel is not yet fully understood in that solution, the effects of Cr content in an alloy and that of Cr_2O_7"2"- ion in nitric acid on the corrosion rate were studied by using electro-chemical measurements. The increase of Cr content reduced the general corrosion rate in nitric acid solution without Cr_2O_7"2"- ion, however it increased that in nitric acid solution containing Cr_2O_7"2"- ion. It is considered that the reversal of the Cr content dependency is due to a rise of the corrosion potential caused by addition of Cr_2O_7"2"- ion to the potential region where a ...

322

Diet-induced changes in uncoupling proteins in obesity-prone and obesity-resistant strains of mice

Despite their structural resemblance, a pair of cyclic halogenated compounds, 1-chloro-1,2,2-trifluorocyclobutane (F3) and 1,2-dichlorohexafluorocyclobutane (F6), exhibit completely different anesthetic...Full Text Available

1997-04-01

323

Cyclopalladated 2-phenyldihydrooxazole complexes with ethylenediamine, 2,2?-bipyridine, and bridging acetate ligands

Uncoupling protein 2 (UCP2) maps to a region on distal mouse chromosome 7 that has been linked to the phenotypes of obesity and type II diabetes. We recently reported that UCP2 expression is increased...Full Text Available

1998-03-31

324

British Library Electronic Table of Contents (United Kingdom)

The 1H NMR, electronic absorption, and luminescence spectra, as well as voltammograms of the reduction and oxidation of the complexes [Pd(C?N)(N?N)]ClO4 and [Pd(C?N)(?-OOCCH3)]2 [where (C?N)? is deprotonated 2-phenyl-4,5-dihydro-1,3-oxazole, and N?N is ethylenediamine or 2,2?-bipyridine (bpy)] were compared. Magnetic nonequivalence of protons in the dihydrooxazole ring and upfield shift of the corresponding signals were observed as a result of anisotropic effect of the ring current in palladated phenyl substituents in the [Pd(C?N)(?-OOCCH3)]2 complex having a C 2 symmetry. One-electron reduction wave of [Pd(C?N)bpy]+ was assigned to ligand-centered electron transfer to the ?* orbital of 2,2?-bipyridine, and two oxidation waves of [Pd(C?N)(?-OOCCH3)]2 were attributed to successive one-elect...

2011-01-01

325

Crystallohydrate forms of trisubstituted uranyl orthophosphate

Co-localization of Sorting Nexin 2 and Androgen Receptor in the Song System of Juvenile Zebra Finches

The conditions of production and the stability regions have been studied for the following crystallohydrates of trisubstituted uranyl orthophosphates: (UO_2)_3(PO_4)_2x6H_2O, (UO_2)_3(PO_4)_2x4H_2O, and (UO_2)_3(PO_4)_2xH_2O. Their thermal stability has been studied. It is shown that thermal dehydration of high-water hydrates at 220-240 deg C gives (UO_2)_3(PO_4)_2xH_2O. The anion composition and crystal structure of the compound remain constant up to 1000 deg C. The mixture of the composition of U_3O_8xU_3(PO_4)_4 is the final product of decomposition at 1000 deg C. The thermodynamic constants of dehydration processes have been calculated. A conclusion has been made about the polymer structure of the compound in which water is located ...

326

Change in HER-2/neu Status from Negative to Positive following Treatment in Breast Cancer: A Case Report

Mechanisms regulating sexual differentiation of the zebra finch song system appear to include both genetic and hormonal factors. Sorting Nexin 2 (SNX2), which is involved in trafficking proteins...Full Text Available

2010-07-09

327

Cell proliferation depends on mitochondrial Ca²⁺ uptake: inhibition by salicylate

IntroductionApproximately 25–30% of breast cancers are assumed to be HER-2/neu positive. It is well known that HER-2/neu-positive cancers after treatment with trastuzumab...Full Text Available

328

Cancer Risk in Type 2 Diabetes Mellitus: Metabolic Links and Therapeutic Considerations

Store-operated Ca²⁺ entry (SOCE) is a ubiquitous Ca²⁺ influx pathway involved in control of multiple cellular and physiological processes including cell proliferation. Recent evidence...Full Text Available

2006-02-15

329

Calcium gradients and buffers in bovine chromaffin cells.

Type 2 diabetes mellitus (DM2) is increasing in incidence, creating worldwide public health concerns and impacting morbidity and mortality rates. An increasing number of studies have demonstrated shared...Full Text Available

2011-01-01

330

CaF sub 2 passivation layers for high temperature superconductors

1. Digital imaging and photometry were used in conjunction with the fluorescent Ca2+ indicator, Fura-2, to examine intracellular Ca2+ signals produced by depolarization of single adrenal chromaffin...Full Text Available

1992-05-01

331

CHANDFS2MS - Chandra Deep Field South 2 ... - HEASARC - NASA

This patent describes a method comprising applying a passivation layer of CaF{sub 2} to the surface of a superconductive ceramic oxide by evaporation. The CaF{sub 2} layer is effective to passivate the oxide surface without disrupting the superconductive properties.

1990-10-23

332

This table contains point-source catalogs for the ~2 Ms exposure of the Chandra Deep ... Source positions are determined using centroid and matched-filter techniques; .... The 1-sigma upper statistical error (Gehrels 1986, ApJ, 303, ...

333

BOOKMARKS:

Association between erectile dysfunction and cardiovascular risk in individuals with type-2 diabetes without overt cardiovascular disease

2 ...Amount received and number years supported Project Duration: 2 years Funding received from APN in Year1: US$...00 Funding received from APN in Year 2: US$40,000.00

334

Association Analysis of the Tryptophan Hydroxylase 2 Gene Polymorphisms in Patients with Methamphetamine Dependence/Psychosis

Background:Erectile dysfunction in type-2 diabetes may be an independent marker for coronary artery disease. Present study was undertaken to investigate whether type-2 diabetic...Full Text Available

2009-10-01

335

Antiferromagnetic Kondo lattice: CePdSi{sub 2}

There is a growing evidence that serotoninergic systems modulate dopaminergic neurotransmission. We analyzed the association between the variations in the brain tryptophan hydroxylase 2 (TPH2)...Full Text Available

2011-03-01

336

Acute atrial arrhythmogenicity and altered Ca²⁺ homeostasis in murine RyR2-P2328S hearts

The compounds CePdSi{sub 2}, CeIrSi{sub 2} and CeRhSn{sub 2} have been synthesized and studied by X-ray diffraction, electrical resistivity and magnetic susceptibility. The magnetic susceptibility of CePdSi{sub 2} exhibits two peaks at 6.8 K and 2.5 K, respectively, indicating two antiferromagnetic phase transitions, while that of CeIrSi{sub 2} shows a broad maximum at 150 K, characteristic of valence fluctuating Ce-compounds. CeRhSn{sub 2} remains paramagnetic down to 5 K. The resistivity of CeIrSi{sub 2} exhibits a T{sup 2} dependence at low temperatures, indicating a Fermi-liquid ground state, while those of CePdSi{sub 2} and CeRhSn{sub 2} shows the presence of Kondo and crystal field effects. (orig.). 5 refs.

1997-02-01

337

A simplified assay for the arylamine N-acetyltransferase 2 polymorphism validated by phenotyping with isoniazid.

AimsThe experiments explored for atrial arrhythmogenesis and its possible physiological background in recently developed hetero-(RyR2^+/S) and homozygotic...Full Text Available

2011-03-01

338

Human arylamine N-acetyltransferase (NAT) activity is determined by two distinct genes, NAT1 and NAT2, and the classical acetylation polymorphism in NAT2 has been associated with a variety of disorders,...Full Text Available

1997-09-01

339

?H2AX and cancer

46 CFR 111.15-2 - Battery construction.

Histone H2AX phosphorylation on a serine four residues from the carboxyl terminus (producing γH2AX) is a sensitive marker for DNA double-strand breaks (DSBs). DSBs may lead to cancer...Full Text Available

2008-12-01

340

np-nh bands in the N=28 isotones

...Shipping 4 2010-10-01 2010-10-01 false Battery construction. 111.15-2 Section 111.15-2... ELECTRIC SYSTEMS-GENERAL REQUIREMENTS Storage Batteries and Battery Chargers: Construction and Installation §...

2010-10-01

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341

Wind-To-Hydrogen Project: Operational Experience, Performance Testing, and Systems Integration

The existence of n-particle n-hole deformed yrare bands in the N=28 isotones is explored using full pf-shell diagonalizations and the Lanczos Strength Function method. We find different 2p-2h and 4p-4h collective bands that, when allowed to mix, more often disappear. Only the 2p-2h yrare band in Cr-52 and the 4p-4h yrare band in Ni-56 survive, and only in this latter case, due to the reduced density of 2p-2h states, can the band be seen as a gamma-cascade.

2002-01-01

342

Valence transition and magnetic ordering in Sn doped EuPd/sub 2/Si/sub 2/

The Wind2H2 system is fully functional and continues to gather performance data. In this report, specifications of the Wind2H2 equipment (electrolyzers, compressor, hydrogen storage tanks, and the hydrogen fueled generator) are summarized. System operational experience and lessons learned are discussed. Valuable operational experience is shared through running, testing, daily operations, and troubleshooting the Wind2H2 system and equipment errors are being logged to help evaluate the reliability of the system.

2009-03-01

343

Synthesis of high specific activity tritium labelled [2-{sup 3}H]-adenosine-5`-triphosphate

The sharp, temperature induced, continuous valence transition in EuPd/sub 2/Si/sub 2/ is drastically changed by doping with Sn at the Si site up to 5 at.%. Only a first order valence transition occurs for a 3% Sn doped sample and the 2/sup +/ component which survives the valence transition orders magnetically at 4.2 K. No valence transition at all occurs for a 5% Sn doped sample right up to 1.9 K and magnetic ordering sets in around 30 K.

1983-12-01

344

Session 6: Redox Behavior of Cerium-Zirconium-Bismuth Mixed Oxides

A procedure for high level tritium labelling at the C2-H position of adenosine 5`-triphosphate ([2-{sup 3}H]-ATP, 1), based on the tritiodehalogenation reaction of 2-bromoadenosine 5`-triphosphate (2) has been elaborated. This precursor was prepared in a six-step synthesis from guanosine. The tritiodehalogenation of (2) for three hours over palladium oxide in phosphate buffer yielded tritium labelled ATP with high specific activity, in good chemical yield. (author).

1996-08-01

345

Radioiodinated 2-nitrobenzyl carbamates as bioreductive alkylating agents for tissue hypoxia

The CeO{sub 2}-ZrO{sub 2}-Bi{sub 2}O{sub 3} samples with different bismuth content were prepared in this study. By the doping of Bi{sub 2}O{sub 3} into the lattice, TPR profiles of the CeO{sub 2}-ZrO{sub 2} shifted to lower temperatures and oxygen storage capacity increased remarkably. It is concluded that the reason for such a behavior is probably due to both the formation of oxygen vacancies which enhance the oxygen mobility and the simultaneous reduction of Ce{sup 4+} and Bi{sup 3+} in the mixed oxides. (authors)

2004-07-01

346

Particle-hole excitations in N=50 nuclei

Three N-methylcarbamates of iodonitrobenzyl alcohols (4-iodo-2-nitrobenzyl alcohol 2, 5-iodo-2-nitrobenzyl alcohol 3 and 4-iodo-2,6-dinitrobenzyl alcohol 4) bearing [[sup 125]I] have been prepared and characterized for their lipophilicity, their reduction potentials and the in vivo lability of the radioiodine in healthy mice. Based upon these results, 2 and 4 were tested in tumor-bearing mice showing limited uptake of radioactivity in tumours and a tumor-to-blood ratio of less than 1. Consequently these particular carbamates are not satisfactory as hypoxia imaging agents. (author).

1993-05-01

347

Lifetime in {sup 181}Ir and {sup 187}Au: enhanced deformation of the {pi}i {sub 13/2} intruder orbital

Energy levels in N=50 nuclei are calculated allowing single-particle excitations from the p{sub 1/2} and g{sub 9/2} shells into the d{sub 5/2}, s{sub 1/2}, d{sub 3/2}, and g{sub 7/2} shells. Important parts of the interaction are determined by least-squares fits to known levels. Agreement with experiment is very good. The high-spin particle-hole states appear to be mainly yrast levels in mass 93 and higher, but are not in {sup 90}Zr. {copyright} {ital 1997} {ital The American Physical Society}

1997-03-01

348

Lifetime in "1"8"1Ir and "1"8"7Au: enhanced deformation of the #pi#i _1_3_/_2 intruder orbital

Lifetimes have been measured in the {pi}h{sub 9/2} (yrast) and {pi}i{sub 13/2} (excited) bands in the nuclei {sup 181}Ir and {sup 187}Au using the Recoil Distance Method (RDM). The results clearly indicate that the {pi}i{sub 13/2} band exhibits an increased deformation over the {pi}h{sub 9/2} band, in keeping with the premise that the delayed crossing in this band is due to enhanced quadrupole deformation. (author). 3 refs, 1 fig, 2 tab.

1995-02-01

349

Heavy fermion behavior in Ce(Ni_xPd_1_-_x)_2Si_2

Lifetimes have been measured in the #pi#h_9_/_2 (yrast) and #pi#i_1_3_/_2 (excited) bands in the nuclei "1"8"1Ir and "1"8"7Au using the Recoil Distance Method (RDM). The results clearly indicate that the #pi#i_1_3_/_2 band exhibits an increased deformation over the #pi#h_9_/_2 band, in keeping with the premise that the delayed crossing in this band is due to enhanced quadrupole deformation. (author). 3 refs, 1 fig, 2 tab.

1994-09-05

350

Heat capacity measurement of some breeder materials

Measurements of the magnetic susceptibility #chi#, specific heat C, and thermoelectric power S were carried out for the solid solution Ce(Ni_xPd_1_-_x)_2Si_2 (0#<=#x#<=#1). With increasing x, the ground state changes from an antiferromagnetic Kondo state (x<0.2) to an intermediate valence state (x>0.3). The heavy fermion state was found to evolve at the crossover concentration at x=0.2, where the long-range magnetic order seems to disappear. [copyright] 2001 American Institute of Physics.

2001-06-01

351

Determination methods of alpha activity ratio

Isobaric molar heat capacities of powder and microsphere form of Li2TiO3 (s) and powder form of LiAlO2 (s) and Li2ZrO3 (s) were measured using a heat flux type differential scanning calorimeter in the temperature range 320 - 870 K. Specific heat capacities of LiAlO2 (s) was found to be much larger compared to those of Li2TiO3 (s) and Li2ZrO3 (s). (author)

2009-01-07

352

Coordination lanthanide compounds with thiosemicarbazide diacetic acid

The three determination methods of alpha activity ration are described, namely geometric progression method, extrapolation method and curve fitting method. The validity of the geometric progression method is demonstrated in the present work. The "2"3"8Pu/("2"3"9Pu + "2"4"0Pu) evaluated by extrapolation method is compared with that by geometric progression method. Also, the "2"3"8Pu/("2"3"9Pu + "2"4"0Pu)evaluated by curve fitting method is compared with that by geometric progression.

353

Coordination lanthanide compounds with thiosemicarbazide diacetic acid

A study was made on complex formation of thiosemicarbazide diacetic acid (H/sub 2/L) with neodymium (3), holmium (3) and erbium (3) in solutions and formation of complexes of metal: ligand=4:1 composition was revealed. Synthesis conditions were developed and products of LnLClxnH/sub 2/O, LnLOHxnH/sub 2/O, Na(LnL/sub 2/)xnH/sub 2/O composition were separated in crystalline state. It was shown, that H/sub 2/L behaves in these compounds as tripod ligand with O, O, N, N donor atoms.

1983-02-01

354

Computational analysis of the oscillatory dynamics in the processes of CO2 assimilation and photorespiration

A study was made on complex formation of thiosemicarbazide diacetic acid (H_2L) with neodymium (3), holmium (3) and erbium (3) in solutions and formation of complexes of metal: ligand=4:1 composition was revealed. Synthesis conditions were developed and products of LnLClxnH_2O, LnLOHxnH_2O, Na[LnL_2]xnH_2O composition were separated in crystalline state. It was shown, that H_2L behaves in these compounds as tripod ligand with O, O, N, N donor atoms.

355

British Library Electronic Table of Contents (United Kingdom)

The computational analysis of the model system consisting of the processes of CO2 assimilation and photorespiration shows the appearance of sustained oscillations in the system which might reflect their presence in photosynthesizing cells. Concentrations of CO2 and O2 oscillate in opposite phases causing Rubisco switching continuously between the carboxylase (CO2 assimilation) and the oxygenase (photorespiration) reactions. The results of modeling are consistent with carbon isotopic and other observed data. They show that the oscillation period varies from about 1 s to 3 s depending on the values of parameters taken. Too high concentrations of O2 suppress the oscillations.

2011-01-01

356

this issue NASA Cloud Computing Platform: Nebula

iII1TEImETFlIES - NASA Technical Report Server (NTRS)

National Aeronautics and Space Administration. Issue 2. June 2010 this issue. Nebula: Cloud Computing p.1. Better Business with EA p.2 ...

357

Volume 1 Cost Estimating - Cost Analysis Division - NASA

The various sources of inertial navigation error are discussed in Section 2.2. It is the nature of inertial navigation errors ...

358

VIGILANCE, PREDATION RISK, AND THE ALLEE EFFECT IN DESERT BIGHORN SHEEP

2.1 The Importance of Life Cycle Management and Cost Estimating................. ........... 1-2 .... 4.3.5 Task 12: Update Cost Estimate on Regular Basis. ...

359

Tissue-specific expression of Fgfr2b and Fgfr2c isoforms, Fgf10 and Fgf9 in the developing chick mandible

... 2004)068[0519:VPRATA]2.0.CO;2 VIGILANCE, PREDATION RISK, AND THE ALLEE EFFECT IN DESERT ... revealed that predation risk (as es...

360

British Library Electronic Table of Contents (United Kingdom)

SummaryExperimental evidence has demonstrated the importance of FGF signalling in morphogenesis of the mandibular processes. FGFs transmit their signals through four tyrosine kinase transmembrane receptors (FGFRs). Alternative splicing in FGFRs including FGFR2 generates different isoforms that exhibit different ligand-specificities, exclusive tissue distributions and specific biological functions. Despite extensive information regarding the isoform-specific patterns of expression Fgfr2c and Fgfr2b during morphogenesis of many organs, a comparative analysis of these specific isoforms in the chick mandible has not been reported. To better understand the function of FGFR2 in mandibular morphogenesis, we have analysed the expression Fgfr2b, Fgfr2c and their putative ligands Fgf10 and Fgf9, in ...

2006-01-01

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

361

Tightly Integrating Optical And Inertial Sensors For Navigation ...

The phosphate complexation of neptunium(V)

... 13 2.4 Inertial Navigation Error Model . . . . . ... sources such as electrical noise, thermal noise, etc. 2.4 Inertial Navigation Error Model ...

2008-03-01

362

Synthesis of 3,4-Dihydropyrimidin-2(1H)-ones Using HClO4-SiO2 as a Heterogeneous and Recyclable Catalyst

The phosphate complexation of Np(V) is investigated in the pH range from 6.4 to 10.0 in 0.1 M NaClO_4 at 22#+-#2 C by absorption spectroscopy. The formation of two phosphate complexes is confirmed by spectroscopic speciation: NpO_2HPO"-_4 at 988.8 nm and NpO_2PO"2"-_4 at 993.6 nm with molar extinction coefficients of 251#+-#8 and 201#+-#11 1/mol cm, respectively. The complexation constants are determined to be log #beta# = 2.54#+-#0.02 for NpO_2HPO"-_4 and log #beta# = 6.33#+-#0.08 for NpO_2PO"2"-_4. The competition of the phosphate complexation with the carbonate complexation is demonstrated by speciation calculation under different geochemical conditions. (orig.).

1996-01-01

363

Synthesis and biodistribution of ["1"2"3I]-4-Iodo-N-(2-morpholino-ethyl)benzamide - one molecule in a class of potential brain imaging agents

Full Text Available

2008-09-01

364

Synthesis and Crystal Structures of Octahedral Metal Complexes containing the New Dianion [PhP(Se,O)Se-Se(O,Se)PPh]2-

Short communication.

365

British Library Electronic Table of Contents (United Kingdom)

The synthesis and structures of three new compounds are reported. [Mg2{PhP(Se,O)Se-Se(O,Se)PPh}2(thf)7(H2O)3] (1), [Mg{PhP(Se,O)Se-Se(O,Se)PPh}(thf)3(H2O)] (2), and [Mn{PhP(Se,O)Se-Se(O,Se)PPh}(thf)3(H2O)] (3) were prepared by treatment of Woollins reagent [PhP(Se)(m-Se)]2 with the corresponding hydrated metal acetates.

2007-01-01

366

Study on Solvent Extraction Using Salen(NEt2)2 as a Chelating Agent for Determination of Trace Cu(II), Mn(II), and Zn(II) in Water Samples

Spin-density-wave transition and #mu#SR in the heavy-fermion Ce(Ru, T)_2Si_2, T = Rh, Pd

Full Text Available

2008-05-01

367

Spin dynamics in Ho{sub 2}Ru{sub 2}O{sub 7}

... 900526-11-8 277 p. MATERIALS SCIENCE antiferromagnetic materials cerium

1999-02-28

368

Spectroscopy of "2"5Al and "2"6","2"7","2"8P using high-energy stripping reactions

The spin relaxation processes within the pyrochlore Ho{sub 2}Ru{sub 2}O{sub 7} have been investigated by neutron scattering and bulk property techniques. A single-ion process, that is thermally activated, dominates the spin-spin relaxation spectrum above 2 K. Assuming Arrhenius behaviour, we found an activation energy {delta} = (329 {+-} 6) K and characteristic relaxation time {tau}{sub 0} (5.2 {+-} 0.3) x 10{sup -12} s in the paramagnetic state, akin to those found in the spin ice, Ho{sub 2}Ti{sub 2}O{sub 7}. Atlow temperature (T<95 K) the activation energy lowers and below 20 K the entropy and ac susceptibility are similar to that observed in other spin ice compounds within a 10 kOe field.

2005-11-09

369

Size and shape of the nuclear density distributions of "2"0Ne and "2"8Si from 104 MeV alpha particle scattering

We report here results of an application of single-nucleon stripping reactions at high energies (65 MeV/u) in inverse kinematics to obtain spectroscopic factors. From measurements of the partial cross-sections for ground and excited states in residual nuclei formed in one-proton stripping reactions, single particle orbits and occupancies of light nuclei have been studied in the s-d shell. Single proton stripping cross-sections of "2"5Al and "2"6","2"7","2"8P on a Be target have been measured using the S800 spectrograph and the NaI(Tl) array at the NSCL. These results indicate that this technique may provide a general tool for the intermediate energy range analogous to transfer (pick-up) reactions at low-energy.

1998-12-21

370

Single crystal growth and magnetic structure investigations of Er{sub 2}PdSi{sub 3} and Tm{sub 2}PdSi{sub 3} intermetallic compounds

(1973). Germany Rebel, H. Schweimer, GW Kernforschungszentrum Karlsruhe

371

Single crystal growth and magnetic structure investigations of Er_2PdSi_3 and Tm_2PdSi_3 intermetallic compounds

No abstract prepared.

2006-07-01

372

Sexual Differences in Vigilance of Paired Ruddy Shelduck in Winter

... magnetic susceptibility magnetization monocrystals neutron diffraction

2006-03-27

373

Screening for depression with the Patient Health Questionnaire-2 (PHQ-2) among the general population in Hong Kong

... SDIVOP]2.0.CO;2 Sexual Differences in Vigilance of Paired Ruddy Shelduck in WinterRui-Chang Quan, ... pairs of the Ruddy Sheldu...

374

British Library Electronic Table of Contents (United Kingdom)

Background: This study investigates the psychometric properties of the Patient Health Questionnaire-2 (PHQ-2) in the general population of Hong Kong. Methods: Random sampling was used to recruit 6028 participants aged 15years or over. Among them, 203 were surveyed twice within a two-week period. Participants completed the Chinese version of the PHQ-9 (including 2 items of the PHQ-2), the Chinese Health Questionnaire, the Happiness Scale, the SF-12, and questions about diagnosis and health service utilization. Internal consistency, test-retest reliability, construct and discriminant validity of the PHQ-2 were assessed. Results: Cronbach's a was 0.76. The test-retest reliability over two weeks calculated by intraclass correlation was 0.70. Spearman correlation results showed that the PHQ-2 s...

2011-01-01

375

SPACEWARN Bulletin 579 - the NSSDC! - NASA

SECTION 3.0 TRIAL CONDUCT

Mar 5, 2003 ... The 4545 kg, 5 kW satellite belongs to the fleet of Milstar 2 satellites ... Being the fifth in the Milstar 2 series, it also carries the ...

376

Robonaut 2 Makes First Motions on Station

... adverse events and potential major events. 3.2.2.4 Clinical Events Committee (CEC) The independent CEC (cardiologists and neurologists ...

377

National Aeronautics and Space Administration (NASA)

Robonaut 2 goes through a series of tests aboard the International Space Station, including its first motions on the orbital outpost. n

2011-10-14

378

Resveratrol causes COX-2- and p53-dependent apoptosis in head and neck squamous cell cancer cells

British Library Electronic Table of Contents (United Kingdom)

Cyclooxygenase-2 (COX-2) content is increased in many types of tumor cells. We have investigated the mechanism by which resveratrol, a stilbene that is pro-apoptotic in many tumor cell lines, causes apoptosis in human head and neck squamous cell carcinoma UMSCC-22B cells by a mechanism involving cellular COX-2. UMSCC-22B cells treated with resveratrol for 24 h, with or without selected inhibitors, were examined: (1) for the presence of nuclear activated ERK1/2, p53 and COX-2, (2) for evidence of apoptosis, and (3) by chromatin immunoprecipitation to demonstrate p53 binding to the p21 promoter. Stilbene-induced apoptosis was concentration-dependent, and associated with ERK1/2 activation, serine-15 p53 phosphorylation and nuclear accumulation of these proteins. These effects were blocked by ...

2008-01-01

379

Resistivity, Hall effect, and magnetic susceptibility of UPd_2Si_2

Resistivity, Hall effect, and magnetic susceptibility of UPd[sub 2]Si[sub 2

The electrical resistivity, Hall effect, and magnetic susceptibility of single-crystal UPd_2Si_2 have been studied between 4.2 and 300 K. A large anisotropy was observed in both the magnetic and transport properties. There is a quadratic temperature dependence of the resistivity for a range of temperatures between 4.2 and 80 K. At higher temperatures, the resistivity indicates a Kondo-type behavior. The behavior of these quantities is accounted for by the magnetic phase transitions at 108 and 136 K reported from neutron-scattering studies. At high temperatures, the magnetic susceptibility of UPd_2Si_2 is Curie-Wiess-like along the c axis. The temperature dependence of the Hall coefficient above 108 K is accounted for by a theoretical model invoking skew scattering of conduction electrons by localized magnetic moments.

380

Redetermination of several half-lives

The electrical resistivity, Hall effect, and magnetic susceptibility of single-crystal UPd[sub 2]Si[sub 2] have been studied between 4.2 and 300 K. A large anisotropy was observed in both the magnetic and transport properties. There is a quadratic temperature dependence of the resistivity for a range of temperatures between 4.2 and 80 K. At higher temperatures, the resistivity indicates a Kondo-type behavior. The behavior of these quantities is accounted for by the magnetic phase transitions at 108 and 136 K reported from neutron-scattering studies. At high temperatures, the magnetic susceptibility of UPd[sub 2]Si[sub 2] is Curie-Wiess-like along the [ital c] axis. The temperature dependence of the Hall coefficient above 108 K is accounted for by a theoretical model invoking skew scattering of conduction electrons by localized magnetic moments.

1993-12-15

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

381

Radiation cryochemistry of water glass. 2. Intermediate products stabilized at 4 K; Kriochemia radiacyjna wody. 2. Produkty posrednie stabilizowane w temperaturze 4 K

The half-lives of "4"1Ar, "8"0"mBr, "9"4"mNb, "1"0"1Mo, "1"0"1Tc, "1"0"9Pd, "1"0"9"mPd, "1"2"2Sb, "1"2"2"mSb, "1"2"3"mSn, "1"5"2"mEu and "2"3"9Np have been measured more accurately compared to previous measurements. All of these half-lives and 39 others published earlier will be cited by M.S. Antony in the forthcoming project 'Chart of the nuclides - Strasbourg, 1990' due to appear early 1991. (author) 34 refs.; 4 figs.; 2 tabs.

382

Quantization of the Lie algebra so(2n+1) and of the Lie superalgebra osp(1/2n) with preoscillator generators

No abstract prepared

1998-12-31

383

Purification of cyclotron-produced "2"0"3Pb for labeling Herceptin

The Lie algebra so(2n+1) and the Lie superalgebra osp(1/2n) are quantized in terms of 3n generators, called preoscillator generators. Apart from n "Cartan" elements the preoscillator generators are deformed para-Fermi operators in the case of so(2n+1) and deformed para-Bose operators in the case of osp(1/2n). The corresponding deformed universal enveloping algebras U_q[so(2n+1)] and U_q[osp(1/2n)] are the same as those defined in terms of Chevalley operators. The name "preoscillator" is to indicate that in a certain representation these operators reduce to the known deformed Fermi and Bose operators.

1994-01-01

384

Power spectral density measurements with "2"5"2Cf for a mockup of the FFTF

A simple and rapid procedure was developed for the purification of cyclotron-produced "2"0"3Pb via the "2"0"3Tl(d,2n) "2"0"3Pb reaction. A Pb(II) selective ion-exchange resin, with commercial name Pb Resin from Eichrom Technologies, Inc., was used to purify "2"0"3Pb from the cyclotron-irradiated Tl target with excellent recovery of the enriched Tl target material. The purified "2"0"3Pb was used to radiolabel the monoclonal antibody Herceptin. The in vitro and in vivo properties of the "2"0"3Pb radioimmunoconjugate were evaluated.

2005-04-01

385

Phylogeny of Steinernema Travassos, 1927 (Cephalobina: Steinernematidae) Inferred From Ribosomal DNA Sequences and ...

... californium 252 fftf reactor mockup power density reactor cores reactor noise

1975-06-08

386

Packaging, Storage, and Containerization Center: Reports ...

... 0877:POSTCS]2.0.CO;2 Phylogeny of Steinernema Travassos, 1927 (Cephalobina: Steinernematidae) Inferred From Ribosomal DNA ... C...

387

O-Plan2 VS Sipe-2 - A General Comparison

... 9 SIMPLIFICATION STUDY RECOMMENDATIONS - MIL-STD-2073-1/2 ... SIMPLIFICATION STUDY RECOMMENDATIONS - MIL-STD-2073-1/2 ...

1993-12-01

388

Nuclear magnetic moment measurements through hyperfine interactions in highly stripped ions

... At that time, it seemed obvious to us that the Missionaries and Cannibals puzzle (MC puzzle) would qualify as a simple classical Al planning ...

1994-07-01

389

Multinational C2 Experiments Supported by C2 Systems and ...

Time-differential magnetic moment measurements on the first-excited Isup(#pi#)=2"+ states in "2"0Ne and "2"4Mg with mean lives of 1.0 and 2.1 ps, respectively are described. The lifetime of the latter state was determined simultaneously. A special detection geometry was designed to improve the experimental #gamma#-ray anisotropy measured with finite-size detectors. For "2"0Ne also a time-integral measurement with charge-state separation was performed. The necessary electronics circuitry built to perform these complicated measurements and the plunger assembly with laser interferometer are also described. A magnetic moment measurement of "2"2Ne(2_1"+) with tau=5.0 ps and transient field measurements at low and high recoil velocities are reported. A discussion of possible extensions of the techniques are given. (Auth.).

1975-09-15

390

Moessbauer study of mixed valent silicides Eu(Ir_1-_xPd_x)_2Si_2

... WHS- Washington Headquarters Service ... but also with respect to other Joint, National and ... unit of action (UA) combat team or task force is organized ...

2003-06-01

391

Magnetic properties of ErPd_2Si_2 from magnetization Moessbauer and neutron diffraction measurements

The solid solutions Eu(Ir_1_-_xPd_x)_2Si_2, which exist for 0#<=#x#<=#0.125 and 0.75#<=#x#<=#1, cristallize with the tetragonal ThCr_2Si_2-type structure. The variation of the europium valence with composition has been thoroughly studied at temperatures 4.2#<=#T#<=#293 K by "1"5"1Eu Moessbauer resonance. For 0#<=#x#<=#0.125 the europium valence at room temperature decreases as x increases. For 0.75#<=#x#<=#1 the valence transition temperature Eu"3"+#->#Eu"2"+ increases as x increases. (orig.).

392

Luminescence and second harmonic generation in Eu3+/Eu2+ embedded B2O3: LiNbO3 non-linear glass-ceramics

Magnetization, neutron diffraction and "1"6"6Er Moessbauer measurements on ErPd_2Si_2 are reported. Below 4.8 K ErPd_2Si_2 orders AF with complex modulated magnetic structures, where the Er moments are aligned along the c-axis. At 1.5 K a squared structure with #mu#_E_r #approx# 7.8(1)#mu#_B is found while a saturation Er moment of 8.2(2)#mu#_B is inferred from the hyperfine field data. The temperature dependence of the Moessbauer spectra in the paramagnetic region is explained in the framework of a relaxation model implying excited crystal field levels. Its analysis is used to estimate the B"m_n CEF parameters. (orig.).

393

Levels in "1"5"2Gd and "1"5"2Sm populated by the decay of "1"5"2Eu

Not Available

2011-09-01

394

Investigation of Distributions of Mn2+ Ions in Fully Dehydrated and Fully Mn2+-exchanged Zeolites Y, |Mn37.5|[Si117Al75O384]-FAU

The energy level schemes of "1"5"2Gd and "1"5"2Sm have been established on the basis of single #gamma#-spectra, and #gamma#-#gamma# coincidence measurements. Ge(Li) detectors were used to study the gamma spectra produced in the EC/#beta#"+ and #beta#"- decays of "1"5"2Eu to "1"5"2Sm and "1"5"2Gd, respectively. Thirteen new transitions are reported and data from eleven coincidence gates enabled five new levels to be suggested. Relative intensities and log ft values were calculated and spin/parities deduced. Comparisons are made with new predictions of the Interacting Boson Model. (orig.).

1990-01-01

395

Influence of technological factors on thermal and mechanical properties of Al_2O_3 - ZrO_2 ceramics

Full Text Available

2010-08-01

396

Industrial-process control valves Part2 : Flow capacity Section Four : Inherent flow characteristics and rangeability

... INIS-UA--158 488 p. MATERIALS SCIENCE additives aluminium oxides

2010-09-06

397

Image Smearing in a Quantum Well Infrared Photodetector ...

Industrial-process control valves Part2 : Flow capacity Section Four : Inherent flow characteristics and rangeability

1989-01-01

398

Hypomethylation and induction of retinoic acid receptor beta 2 by concurrent action of adenosine analogues and natural compounds in breast cancer cells

... Assuming isotropic emission, the 25' half angle cone represents only -9% [= 1/(2(ngaas/nopticglue) 2)] of the spontaneous radiation. ...

1998-12-01

399

British Library Electronic Table of Contents (United Kingdom)

DNA methylation is considered as a potential cause of aberrations in regulation of gene expression during carcinogenesis. Therefore, changes in DNA methylation patterns may be targets for chemoprevention. In the present study, we investigated effects of all-trans retinoic acid (ATRA), vitamin D3, and resveratrol alone and in combination with adenosine analogues: 2-chloro-2'-deoxyadenosine (2CdA) and 9-beta-d-arabinosyl-2-fluoroadenine (F-ara-A), on methylation and expression of retinoic acid receptor beta 2 (RARbeta2) in MCF-7 and MDA-MB-231 breast cancer cell lines. Alterations in methylation and expression levels after treatment of cells with the tested compounds were evaluated by methylation-sensitive restriction analysis (MSRA) and real-time PCR, respectively. RARbeta2 promoter in the ...

2010-01-01

400

Graphene-Pt nanocomposite for nonenzymatic detection of hydrogen peroxide with enhanced sensitivity

British Library Electronic Table of Contents (United Kingdom)

A sensitive hydrogen peroxide (H2O2) sensor was fabricated based on graphene-Pt (GN-Pt) nanocomposite. The GN-Pt was synthesized by photochemical reduction of K2PtCl4 on GNs, and characterized by atomic force microscope (AFM), transmission electron microscope (TEM), and energy-dispersive X-ray spectroscopy (EDS). Electrochemical investigations indicated that the GN-Pt exhibited a high peak current and low overpotential towards the reduction of H2O2. The GN-Pt modified glass carbon electrode displayed a wide linear range (2-710mM), low limit of detection (0.5mM) and good selectivity for detection of H2O2 with a much higher sensitivity than that of Pt nanoparticles or graphene modified electrode.

2011-01-01

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

401

Glassy Carbon, Alloys

General Disclaimer One or more of the Following Statements may ...

... 2.2.1 Polymerization of DVB Under Pressure DVB was polymerized at 300*C in thin-walled Pd-Ag capsules at pressures up to 60,000 psi. ...

1972-07-27

402

Fusion in the W_3 algebra

Aug 3, 2011 ... System (NASS) and the NERVA Effluent Purification System ... Effluent Purification System (NEPS). 7.4.2.2. Requirements ...

403

Foreign Object Impact Design Criteria. Volume 2

We develop the notions of fusion for representations of the WA_2 algebra along the lines of Feigin and Fuchs. We present some explicit calculations for a WA_2 minimal model. (orig.).

1995-01-01

404

Fixation of CO_2 and export of photosynthate by the carpel in Pisum sativum

... This Level 2 analysis will be somewhat less detailed, but experience in other fields including pipe whip 4 , locomotive dynamics, and nuclear fuel ...

1982-02-01

405

Electron capture decay of "2"0"3Bi

... School of Plant Biology. v. 23(2) p. 316-322. carbon dioxide absorption carbon

1970-01-01

406

Effect of pressure and magnetic field on the magnetism of a U(Ni_0_._9_1Pd_0_._0_9)_2Si_2 single crystal

The electron capture decay scheme of "2"0"3Bi is studied. Energies and relative intensities of gamma rays are given.

407

Effect of Deforestation on a Southwest Ghana Dung Beetle Assemblage (Coleoptera: Scarabaeidae) at the Periphery of ...

... parameters magnetic fields magnetic properties magnetization monocrystals

2003-04-01

408

Effect of COX-2 (PGE2) and IL-6 on Prostate Cancer Bone ...

... 1081:EODOAS]2.0.CO;2 Effect of Deforestation on a Southwest Ghana Dung Beetle Assemblage (Coleoptera: ... The survey provided a...

409

Dynamics of southwest Asian dust particle size characteristics with ...

... of the AR (25). Dihydrotestosterone increases Wnt signaling activity in preosteoblasts. Functional interactions between ...

2008-02-02

410

Dynamic response of a PEM fuel cell under reactant gas starvation

dust measured in the Arabian Gulf region during UAE2 and examine the hypothesis that ... [8] UAE2 took place in the southern Arabian Gulf region in August and ...

411

Development of a 2-Aza-Cope-[3+2] Dipolar Cycloaddition Strategy for the Synthesis of Quaternary Proline Scaffolds

The fuel cell control problem was studied. Attempts were made to control the output current of the fuel cell by starving it of hydrogen and oxygen. The motivation of this work was to increase efficiency by minimizing waste of fuel. The following findings were obtained: H2 starvation works better than O2 starvation; An optimal H2 to O2 ratio exists for combined H2&O2 starvation; The control scheme for H2&O2 starvation works well for 3 different disturbance tests and at 25 degrees C, 60 degrees C, and 80 degrees C; Fuel cell under reactant starvation is stable for at least 72 hrs.

2005-08-05

412

Description of the ER-2 Dropwindsonde System The ... - ESPO - NASA

A one-pot multicomponent procedure for the synthesis of highly functionalized pyrrolidine rings through a domino...Full Text Available

2010-09-03

413

Carbon-12 induced fission of "2"0"9Bi at 84.2 MeV

2 illustrates the design of the launch tube, the gun barrel design of the multi-tube dispenser and integrated hardware pressure cannister. ...

414

Anisotropic exchange in frustrated pyrochlore Yb2Ti2O7

The "1"2C induced fission of "2"0"9Bi at particle energy of 84.2 MeV has been studied using gamma ray spectrometry. The cross sections for the production of fission products have been determined. The charge distribution has also been studied and the relative fractional cumulative yields of "9"2Y, "9"7Zr, "9"9Mo, "1"0"1Mo, "1"0"5Rh, "1"1"2Pd and "1"1"7"mCd determined. The yield distribution of fission products has been found to be broad (FWHM #approx =# 18) with a peak near mass #approx =# 105. (author). 7 refs., 2 tabs.

415

Analysis of the Seasonal Effects on Cesium Clocks to Improve ...

The local Yb3+ magnetic susceptibility tensor was recently measured in the frustrated pyrochlore compound Yb2Ti2O7 by means of in-field polarized neutron scattering in a single crystal. A very anisotropic effective exchange tensor was derived for the Yb3+ ion. Using this result, we reinterpret here the data for the powder susceptibility in Yb2Ti2O7. We show that, in the case of a well-isolated Kramers doublet with anisotropic g and exchange tensors, the inverse susceptibility for a powder sample does not strictly obey a Curie-Weiss law at low temperature. We discuss the consequences regarding the paramagnetic Curie temperature, usually taken as a measure of the exchange/dipolar interaction, and the exotic 'slow fluctuation' ground state of Yb2Ti2O7. (fast track communication)

2009-12-09

416

Abnormalities of dystrophin, the sarcoglycans, and laminin alpha2 in the muscular dystrophies.

... XVIII, n. 1, p. 50-67. [2] G. Becker: Zeitskalenprobleme: jahreszeitliche Gangschwankungen von Atomuhren, PTB Mitteilungen 92 2/82, p. 105-113. ...

1987-12-01

417

6-Substituted imidazo[1,2-a]pyridines: Synthesis and biological activity against colon cancer cell lines HT-29 and Caco-2

Abnormalities of dystrophin, the sarcoglycans, and laminin alpha2 are responsible for a subset of the muscular dystrophies. In this study we aim to characterise the nature and frequency of abnormalities...Full Text Available

1998-05-01

418

British Library Electronic Table of Contents (United Kingdom)

A range of 6-substituted imidazo[1,2-a]pyridines were synthesized using a multicomponent coupling reaction. Most of these compounds were found to exhibit excellent activity against the colon cancer cell lines HT-29 and Caco-2, whilst not showing significant toxicity against white blood cells. Our studies have shown that the proteolytic phase of apoptosis was initiated 2 h after treatment with these imidazo-[1,2-a]pyridines. The data suggests that the imidazo[1,2-a]pyridine-induced cell death in HT-29 and Caco-2 cells is mediated via pathway(s) that include the release of cytochrome c from the mitochondria to the cytosol and the activation of caspase 3 and caspase 8.

2011-01-01

419

2,3-dihydroxybenzoic acid amides of tetraazaalkanes and tetraaza cycloalkanes

The present compounds are useful as specific sequestering agents for actinide (IV) ions. Also described is a method for the 2,3-dihydroxybenzamidation of azaalkanes.

1980-01-01

420

1700r.img

Production and characterisation of the transition metal chalcogenides MoS[sub 2], MoSe[sub 2], WS[sub 2] and WSe[sub 2] as thin films in photovoltaics. Herstellung und Charakterisierung der Uebergangsmetallchalkogenide MoS[sub 2], MoSe[sub 2], WS[sub 2] und WSe[sub 2] als Duennfilme fuer die Photovoltaik

%++")-""# $$ (& 06DJDD84468:DPX\\Z`dhnnljr| vh^Zntx???|`?R ?? `|njThh^PVd\\\\VZXTJ<(&:FLXX\\`hljlrtxpb^\\VVNL@8.(*2,&($"&,,2.260" ? Y "A ...

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

421

Photoaffinity labeling of ATP and NAD"+ binding sites on recombinant human interleukin 2

The production and characterisation of thin films made from molybdenum sulphide, molybdenum selenide, tungsten sulphide and tungsten selenide are described. The electronic properties of the thin films were examined by Hall measurements and by thermal sensors. For the MoSe[sub 2] films, the majority of the samples were n-conducting and p-conduction was only found for a few examples. All the other films (MoS[sub 2], WS[sub 2], WSe[sub 2]) were p-conducting. The electrical transport properties of the thin films are comparable to those of single crystals. With these thin films as absorber materials, it was possible for the first time to produce the polycrystalline solid n-ZnO/p-MoSe[sub 2], n-ZnO/WSe[sub 2], n-ZnO/WS[sub 2]- and n-ITO/WS[sub 2] solar cells. In spite of not yet optimized diode geometry (lateral build-up), a ...

1993-01-01

422

Effect of magnetic field and pressure on U(Ni_1_-_xPd_x)_2Si_2 single crystals

Interleukin 2 (IL-2) is a T-cell-derived lymphokine critical in the activation and proliferation of T cells, B cells, and lymphokine-activated killer cells. It is a glycoprotein of #approx#15,500 daltons that is synthesized and secreted after activation by antigen or mitogen. By using the analogs 8-azidoadensoine 5'-[#gamma#-"3"2P]triphosphate ([#gamma#-"3"2P]8N_3ATP) and nicotinamide 2-azidoadenine [adenylate-"3"2P]dinucleotide ([#alpha#-"3"2P]2N_3NAD"+) as photoaffinity probes, the authors have detected specific, metal ion-requiring nucleotide binding sites on recombinant human IL-2 (rhIL-2). The specificity of these nucleotide interactions with rhIL-2 was demonstrated by saturation effects and by competition by the parent nucleotides at physiologically ...

423

Decay of H{sub 2}{sup -} anions in solid parahydrogen by quantum tunneling: observations of electron bubbles

Single crystals of U(Ni_1_-_xPd_x )_2Si_2 for x = 0.05, 0.10 and 0.15 have been grown. Magnetization and electrical resistivity measurements were performed in a wide range of temperatures, magnetic fields and high pressures in order to study stability of magnetic phases in the solid solutions between UNi_2Si_2 and UPd_2Si_2 with a special emphasis on the type of ground state. In UPd_2Si_2 the simple AFI-type antiferromagnetic structure of U moments is observed at low temperatures. UNi_2Si_2 adopts the uncompensated AF structure (UAF) with the ++- stacking of U moments along the c-axis and consequently this compound exhibits a spontaneous magnetization corresponding to 1/3 of the U moment. The substitution of Pd for Ni leads to a rapid decay of the spontaneous magnetization. The ...

2002-07-01

424

Chelation of intracellular calcium blocks insulin action in the adipocyte

Decay mechanism of H{sub 2}{sup -} anions produced by {gamma}-ray or X-ray radiolysis of solid para-H{sub 2} (p-H{sub 2}) has been studied using high-resolution ESR spectroscopy in the temperature range between 2.7-6.6 K. The results can be summarized as follows; First, the decay rate constant of the H{sub 2}{sup -} anion is not proportional to initial yields of reactive species such as H radical and cation but proportional to concentrations of HD and D{sub 2} impurities in p-H{sub 2}. Second, ESR spectra assigned as electron bubbles were observed in solid p-H{sub 2} containing large amount of HD or D{sub 2} (11 mol %), while they were not observed in pure solid p-H{sub 2}. Third, the decay rate constant of the H{sub 2}{sup -} anion increases with the ...

1998-02-01

425

Catalytic wet air oxidation of phenol over CeO{sub 2}-TiO{sub 2} catalyst in the batch reactor and the packed-bed reactor

The hypothesis that intracellular Ca"2"+ is an essential component of the intracellular mechanism of insulin action in the adipocyte was evaluated. Cells were loaded with the Ca"2"+ chelator quin-2, by preincubating them with quin-2 AM, the tetrakis(acetoxymethyl) ester of quin-2. Quin-2 loading inhibited insulin-stimulated glucose transport without affecting basal activity. The ability of insulin to stimulate glucose uptake in quin-2-loaded cells could be partially restored by preincubating cells with buffer supplemented with 1.2 mM CaCl_2 and the Ca"2"+ ionophore A23187. These conditions had no effect on basal activity and omission of CaCl_2 from the buffer prevented the restoration of insulin-stimulated glucose uptake by A23187. Quin-2 ...

426

A dinuclear Ni(I) system having a diradical Ni2N2 diamond core resting state: synthetic, structural, spectroscopic elucidation, and reductive bond splitting reactions.

CeO{sub 2}-TiO{sub 2} catalysts are prepared by coprecipitation method, and the activity and stability in the catalytic wet air oxidation (CWAO) of phenol are investigated in a batch reactor and packed-bed reactor. CeO{sub 2}-TiO{sub 2} mixed oxides show the higher activity than pure CeO{sub 2} and TiO{sub 2}, and CeO{sub 2}-TiO{sub 2} 1/1 catalyst displays the highest activity in the CWAO of phenol. In a batch reactor, COD and TOC removals are about 100% and 77% after 120 min in the CWAO of phenol over CeO{sub 2}-TiO{sub 2} 1/1 catalyst at reaction temperature of 150 {sup o}C, the total pressure of 3 MPa, phenol concentration of 1000 mg/L, and catalyst dosage of 4 g/L. In a packed-bed reactor using CeO{sub 2}-TiO{sub 2} 1/1 particle ...

2008-05-30

427

Using the alkoxomethod to obtain the oxide phases of Fe_2O_3-Y_2O_3 system

One-electron reduction of the square-planar nickel precursor (PNP)NiCl ( 1) (PNP (-) = N[2-P(CHMe 2) 2-4-methylphenyl] 2) with KC 8 effects ligand reorganization of the pincer ligand to assemble a Ni(I) dimer, [Ni(mu 2-PNP)] 2 ( 2), containing a Ni 2N 2 core structure, as inferred by its solid-state X-ray structure. Solution magnetization measurements are consistent with a paramagnetic Ni(I) system likely undergoing a monomer dimer equilibrium. The room-temperature and 4 K solid-state X-band electron paramagnetic resonance (EPR) spectra display anisotropic signals. Low-temperature solid-state X-band EPR data at 4 K reveal rhombic values g z = 1.980(4), g x = 2. 380(4), and g y = 2.225(4), as well as a forbidden signal at g = 4.24 for the Delta M S = ...

2008-10-15

428

Understanding of the volatility of GeO/sub 2/ in the presence of WO/sub 2/

Production of Fe_2O_3, Y_2O_3, YFeO_3, Y_3Fe_5O_1_2 powders using the alkoxomethod - during hydrolysis by yttrium and iron alcohol solutions, is studied. It is stated that production of the powders of Y_2O_3-Fe_2O_3 system oxides using alkoxomethod permits to decrease essentially the reaction volumes, number of operations, their duration as compared to the cooxidation of oxide hydrates from inorganic salt aqueous solutions. During heat treatment of iron (3) alcohol hydrolysis products #gamma#-Fe_2O_3 is first crystallized by contrast to #alpha#-FeOOH, usually produced by deposition from solutions. Further heat treatment of #gamma#-Fe_2O_3 results in production of #alpha#-Fe_2O_3. Conditions for crystallization of Y_3Fe_5O_1_2 and YFeO_3 phases, prepared by both methods, and their crystallite mean ...

429

The solubility of hydrogen and deuterium in crystalline Pd{sub 9}Si{sub 2}

The equilibria composition of the gaseous and the solid phase in the system GeO/sub 2//WO/sub 2/ is calculated with an improved thermodynamical program for temperatures 1100 < T < 1400 K and constant volume. By means of the results the experimental observed migration of GeO/sub 2/ in the presence of WO/sub 2/ in a temperature gradient T/sub 2/ ..-->.. T/sub 1/ (1200 ..-->.. 1100 K) in sealed evacuated silica tubes is due to a chemical transport with H/sub 2/ as the transporting agent. The H/sub 2/ is formed by H/sub 2/O which is desorbed by the quartz glass of the ampoules. The also observed volatility of WO/sub 2/ and its deposition in form of Ge/sub 0.75/W/sub 3/O/sub 9/ at the 'cold' end (T/sub 1/) of the tubes is performed by gaseous GeWO/sub 4/. The calculated and ...

1983-08-01

430

Synthesis, structure and bonding of Gd_6MTe_2 (M=Co, Ni), Er_6RuTe_2

Isotherms have been measured for H(D){sub 2}(g) solution in crystalline Pd{sub 9}Si{sub 2} in the temperature range from 235 to 373 K. The solubilities are significant, e.g., at 1.0 MPa (298 K), (H/Pd) = 0.052 or Pd{sub 9}Si{sub 2}H{sub 0.47}, however, there is no indication of hydride phase formation even down to 235 K at 1.0 MPa. The thermodynamic values for hydrogen solutions at infinite dilution of hydrogen are {Delta}H{degrees}{sub H}= -11.9 kJ/mole {1/2}H{sub 2} and {Delta}S{degrees}{sub H} = -50 J/K mole {1/2}H{sub 2}. The former is more negative than for Pd-H{sub 2} and the latter is somewhat more positive; but generally the values are not that different from Pd-H{sub 2}. The isotope effect is similar to that found for Pd-H(D){sub 2}.

1995-11-15

431

Synthesis, characterization and catalytic activities of vanadium complexes containing ONN donor ligand derived from 2-aminoethylpyridine

Three new rare earth metal-rich compounds, Gd_6MTe_2 (M=Co, Ni) and Er_6RuTe_2, were synthesized in direct reactions between the R, R_3M, and R_2Te_3 (R=Gd, Er, M=Co, Ni, Ru). These materials all adopt the same Zr_6CoAl_2 structure type with space group P6-bar 2m (No. 189, Z=1). Single crystal structures of Gd_6CoTe_2 and Er_6RuTe_2 were determined and lattice parameters are a=b=8.3799(5), c=3.9801(4) A, and a=b=8.1473(5) A, c=3.9962(4) A, respectively. Gd_6NiTe_2 was characterized by X-ray powder diffraction; lattice parameters are a=b=8.412(2), c=3.9577(9) A. Metal-metal bonding correlations were analyzed using the empirical Pauling bond order concept.

2003-08-25

432

British Library Electronic Table of Contents (United Kingdom)

Reaction between [V^I^VO(acac)2] and the ONN donor Schiff base Hpydx-aepy (I) (Hpydx-aepy=Schiff base obtained by the condensation of pyridoxal and 2-aminoethylpyridine) resulted in the formation of a complex [V^I^VO(acac)(pydx-aepy)] (1). Addition of aqueous 30% H2O2 to 1 yields the poor stable oxidoperoxidovanadium(V) complex [V^VO(O2)(pydx-aepy)] (2). Its formation has also been demonstrated in solution by treating 1 with H2O2 in methanol. Reaction of vanadium exchanged zeolite-Y with I in methanol followed by aerial oxidation gave zeolite-Y encapsulated dioxidovanadium(V) complex, abbreviated as [V^VO2(pydx-aepy)]-Y (4). The crystal and molecular structure of 1 has been determined, confirming the ONN binding mode of the ligand. The encapsulated complex [V^VO2(pydx-aepy)]-Y ...

2011-01-01

433

Synthesis, Crystal Structure and Spectroscopic Properties of an Oximato Bridged Cu(II) Dimer

British Library Electronic Table of Contents (United Kingdom)

Schiff-base condensation of a equimolar proportion of diacetyl-monoxime monohydrazone and 1-methylimidazole-2-carboxaldehyde in methanol gives rise to the imidazole azine, 3-(1-methylimidazol-2-yl)methylenehydrazonobutan-2-one oxime(HL). Reaction of 1:1 stoichiometric proportion of HL with copper(II)perchlorate hexahydrate in methanol yields a dimeric oximato bridged copper compound, [Cu2L2(H2O)2](ClO4)2 (1). The compound is characterized by C, H and N analyses, FT-IR, ESI?MS, conductivity measurement, UV?Vis spectra and X-ray single crystal diffraction. The title compound (1) crystallizes in the monoclinic space group P21/c with a?=?6.8533 (8), b?=?18.413 (2), c?=?11.7399 (14) ?, ??=?93.685 (2)?, V?=?1478.4 (3) ?3 and Z?=?2. The geometry around each copper ...

2011-01-01

434

Survey of implementation plan constructed for `the New Earth 21 Project`; Chikyu saisei keikaku no jisshi keikaku sakusei ni kansuru chosa jigyo

Study on laminar burning velocity of premixed CH{sub 4}/O{sub 2}/CO{sub 2} flames; CH{sub 4}/O{sub 2}/CO{sub 2} yokongo kaen no soryu nensho sokudo ni kansuru kenkyu

It is necessary to establish scenarios for reducing CO2 emissions and for developing CO2 emission control technologies to obtain a global consensus, using appropriate analytical models. For modification of the DNE-21 (Dynamic New Earth 21) model, it has a category designated as innovative technologies not involving CO2 emission and an optional consideration for the absorption of atmospheric CO2 by biomass. A global carbon circulation model, including vegetation in its scope, is also incorporated. Major results of the simulation are shown. When 20% reduction in CO2 emissions is required for only OECD countries after the year 2020, it has been demonstrated that CO2 concentration in the atmosphere will reach as high as about 900 ppm in 2100 due to CO2 emission by developing countries, and will not be a tolerable level. Under the condition that ...

1997-03-01

435

Sodium oxonitridometallates(VI) of molybdenum and tungsten, Na[sub 4]MO[sub 2]N[sub 2] (M = Mo, W). Natriumoxonitridometallate(VI) von Molybdaen und Wolfram, Na[sub 4]MO[sub 2]N[sub 2] (M = Mo, W)

Experimental and numerical investigations were performed for the laminar burning velocity and the flame structure of laminar premixed CH{sub 4}/O{sub 2}/CO{sub 2} flames. Measurements of the laminar burning velocity were conducted by using a flame cone angle method for a circular nozzle burner. Numerical simulation was performed using one-dimensional plane flame code including radiation heat loss with an optically thin model. It was shown that the laminar burning velocity decrease with CO{sub 2} addition even though the adiabatic flame temperature is the same as that for CH{sub 4}/Air flames. The radiation heat loss is significant for the CH{sub 4}/O{sub 2}/CO{sub 2}, flames, and the flame temperature and laminar burning velocity decreases when the radiation heat loss is considered. Effects of thermal properties, radiation, and chemical reaction on the determination of the laminar ...

1999-07-25

436

Review of integral data on higher transactinides

MoO[sub 3] as well as WO[sub 3] react with an excess of NaNH[sub 2] in autoclaves at temperatures ranging from 250 C to 750 C to yield - in contrast to Ta[sub 2]O[sub 5] backslash lbrackvertical stroke 1 backslash rbrackvertical stroke - oxonitridometallates of general composition Na[sub 4]MX[sub 4] and other products like Na[sub 5]WO[sub 4]N backslash lbrackvertical stroke 2 backslash rbrackvertical stroke . The compounds decompose in moist air within minutes to Na[sub 2]WO[sub 4], Na[sub 2]MoO[sub 4] and Na[sub 2]MoO[sub 4].xH[sub 2]O, respectively. (orig.)

1993-07-01

437

Photochemistry on surfaces. 2. Intermolecular electron transfer on colloidal alumina-coated silica particles

A review of the status of integral measurements is presented for "2"4"0Pu, "2"4"1Pu, "2"4"2Pu, "2"4"1Am and "2"4"3Am. This review includes integral measurements pertinent to thermal reactor systems, i.e., thermal cross sections and resonance integrals, as well as measurements for fast reactor systems. It appears that for these nuclides the data for thermal reactors are in good shape; however, more work is recommended in defining the branching ratio of the capture cross section of "2"4"1Am to the isomeric and ground states of "2"4"2Am. Also, benchmark irradiation data are needed for cross section data testing using depletion/production codes. For fast reactors, experiments are in progress, in the UK, in France, and also in the US, with partial results available at this time. Fast integral data obtained from these measurements will be very ...

1979-05-01

438

Mechanisms of radical removal by SO2

Reductive quenching of two photoexcited ruthenium(II) complexes by an anionic electron donor, 2,2{prime}-azinobis(3-ethyl-benzothiazoline-6-sulfonate) (ABTS{sup 2{minus}}), in aqueous solution was examined by laser flash photolysis before and after adding positively charged colloidal (250-{angstrom} diameter) alumina-coated silica particles. The kinetics and quantum yields of electron transfer with an anionic sensitizer, RuL{sub 3}{sup 4{minus}} (L = bathophenanthroline disulfonate), and a cationic one, Ru(bpy){sub 3}{sup 2+} (bpy = 2,2{prime}-bipyridine), were compared. Coadsorption of ABTS{sup 2{minus}} and RuL{sub 3}{sup 4{minus}} by the particles greatly enhanced the rate of quenching such that only the reaction occurring on the surfaces of the particles was observed. Electron transfer from ABTS{sup 2{minus}} to RuL{sub 3}{sup 4-*} occurred by a static ...

1989-02-23

439

In situ, real-time RBS measurement of solid state reaction in thin films

It is well established from experiments in premixed, laminar flames, jet-stirred reactors, flow reactors, and batch reactors that SO2 acts to catalyze hydrogen atom removal at stoichiometric and reducing conditions. However, the commonly accepted mechanism for radical removal, SO2 + H(+M) reversible arrow HOSO(+M), HOSO + H/OH reversible arrow SO2 + H-2/H2O, has been challenged by recent theoretical and experimental results. Based on ab initio calculations for key reactions, we update the kinetic model for this chemistry and re-examine the mechanism of fuel/SO2 interactions. We find that the interaction of SO, with the radical pool is more complex than previously assumed, involving HOSO and SO, as well as, at high temperatures also HSO, SH, and S. The revised mechanism with a high rate constant for H + SO2 recombination and with SO + ...

2007-01-01

440

Fractal dimensions of coals and cokes

The applicability of in situ, real-time RBS is demonstrated by characterizing the growth of thin Pd_2Si films on Si left angle 111 right angle substrates using isothermal as well as non-isothermal annealing. In contrast to the currently fashionable in situ ramped resistance technique, it is possible to extract the activation energy from a single run with a constant heating rate. The results, which are in excellent agreement with the literature, will be compared for isothermal annealing, fitting an appropriate model for the growth process to data from a single run and a Kissinger-like analysis with different ramp rates. In situ, real-time RBS was also used to study marker motion during CrSi_2 formation in the Si left angle 100 right angle /Pd_2Si/Cr system. It is possible to distinguish between the following mechanisms: (1) CrSi_2 formation via dissociation of the Pd_2Si at the ...

1998-04-01

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

441

Electron-impact excitation of multiply-charged ions using energy loss in merged beams: e+Si"3"+(3s"2S_1_/_2)#->#e+Si"3"+(3p"2P_1_/_2_,_3_/_2)

Using adsorption data, the authors get formulas for the calculation of fractal dimensions: log[A{sub CO{sub 2}(DP)}/A{sub N{sub 2}(BET)}] = {minus}5.3984(2 {minus} D{sub 1})/2 and log[A{sub CO{sub 2}(BET)}/A{sub N{sub 2}(BET)}] = {minus}4.9569(2 {minus} D{sub 2})/2. The fractal dimensions (D) of 27 coals and 2 cokes have been obtained. The D of coals decreased with the increase of f{sub a} and reached a maximum at H/C equal to 0.66 (or C{sub daf} about 86%). The fractal dimension is relative to ash and volatiles of coal: D = 2.2237 + 0.6249 V{sub daf} + 0.8863 A{sub d}. The relationship between D of coal coke and its conversions (X) obeys the following equation: D = a exp({minus}bX) + c.

1997-06-15

442

Dose-effect studies with inhaled plutonium oxide in beagles

For the first time absolute total cross sections for electron-impact excitation of a multiply-charged ion have been measured using an electron-energy-loss technique. Measurements were made near threshold for the process e + Si"3"+(3s"2S_1_/_2) #-># e+Si"3"+(3p"2P_1_/_2_,_3_/_2)-8.88 eV. The 10"-"1"5 cm"2 measured cross section agrees with results of 7-state close coupling calculations to better than the #+-#20% (90% CL) total uncertainty of the measurements. Convoluting the theoretical curve with a Gaussian energy distribution indicates an energy width of 0.15 < or approx. #DELTA#E < or approx. 0.20 eV. (orig.).

443

Crystal-field excitations in the visible spectrum of Nd{sub 2}CuO{sub 4}

Beagle dogs given a single exposure to "2"3"9PuO_2 or "2"3"8PuO_2 aerosols are being observed for life-span dose-effect relationships. The "2"3"9Pu body burden of the nine dogs that died of pulmonary fibrosis-induced respiratory insufficiency during the first 3 yr after exposure was 1 to 12 #mu#Ci. One of these dogs had a pulmonary tumor. Five additional dogs with body burdens of 0.7 to 1.8 #mu#Ci died due to pulmonary neoplasia 3 to 5 yr after exposure. None of the dogs exposed to "2"3"8Pu have died during the first 3 postexposure yr. Lymphocytopenia was the earliest observed effect after inhalation of "2"3"9PuO_2 or "2"3"8PuO_2, occurring 0.5 to 2 yr after deposition of greater than or equal to 80 nCi plutonium in the lungs.

1977-05-01

444

Crystal-field excitations in the visible spectrum of Nd_2CuO_4

A phenomenological simulation was carried out for 41 experimental crystal-field (CF) levels within the {sup 4}I{sub 9/2-15/2}, {sup 4}F{sub 3/2-9/2}, {sup 4}S{sub 3/2} and {sup 2}H{sub 9/2} J manifolds, including the available infrared (IR) data up to {approx}15 000 cm{sup -1} for the Nd{sup 3+} ions in the Nd{sub 2}CuO{sub 4} single crystals. The CF Hamiltonian for the tetragonal C{sub 4v} symmetry was diagonalized together with the free-ion Hamiltonian in a basis that spans the entire 4f{sup 3} configuration. A rms error of 9 cm{sup -1} between the calculated and experimental energy level schemes was obtained. A comparison of the spectra in the visible region between the insulating Nd{sub 2}CuO{sub 4} and the metallic Nd{sub 2-x}Ce{sub x}CuO{sub 4}, allowed identifying the absorption bands associated with the ...

2004-07-14

445

Bulk-sensitive high-resolution photoemission study of a temperature-induced valence transition system EuPd{sub 2}Si{sub 2}

A phenomenological simulation was carried out for 41 experimental crystal-field (CF) levels within the "4I_9_/_2_-_1_5_/_2, "4F_3_/_2_-_9_/_2, "4S_3_/_2 and "2H_9_/_2 J manifolds, including the available infrared (IR) data up to #approx#15 000 cm"-"1 for the Nd"3"+ ions in the Nd_2CuO_4 single crystals. The CF Hamiltonian for the tetragonal C_4_v symmetry was diagonalized together with the free-ion Hamiltonian in a basis that spans the entire 4f"3 configuration. A rms error of 9 cm"-"1 between the calculated and experimental energy level schemes was obtained. A comparison of the spectra in the visible region between the insulating Nd_2CuO_4 and the metallic Nd_2_-_xCe_xCuO_4, allowed identifying the absorption bands associated with the development of the charge-doping induced local structural distortions in the ...

2004-07-14

446

Anomalous angular distributions in pion and {alpha} particle scattering to the 2{sub 2}{sup +} state of {sup 52}Cr

Eu 4f electronic structures of a temperature-induced valence transition system EuPd{sub 2}Si{sub 2} have been investigated by bulk-sensitive high-resolution photoemission spectroscopy at temperatures from 20 to 300 K. The bulk Eu{sup 2+} 4f component is definitely distinguished from two surface Eu{sup 2+} 4f components. The changes in the spectral intensity of the bulk Eu{sup 2+} and Eu{sup 3+} 4f configurations and in the energy separation between these states are observed in the temperature dependent photoemission spectra. These temperature dependences are related to the valence transition of EuPd{sub 2}Si{sub 2}. The Eu mean valence is evaluated to be 2.75{+-}0.03 at 20 K and 2.30{+-}0.05 at 300 K. These values are in good agreement with those evaluated from Moessbauer and Eu L{sub III}-edge X-ray ...

2004-07-01

447

A one-pot synthetic approach to prepare palladium nanoparticles embedded hierarchically porous TiO2 hollow spheres for hydrogen peroxide sensing

Inelastic scattering of 180 MeV {pi}{sup +} and {pi}{sup {minus}} from {sup 52}Cr shows an angular distribution for the 2{sub 2}{sup +} state at 2.96 MeV that differs greatly from the usual {ital L} = 2 shapes for 2{sup +} states. This state is perhaps the only case from pion-inelastic scattering in which standard distorted-wave impulse approximation models (including multistep and single-step responses) fail to reproduce the measured angular distribution. Furthermore, this unique excitation has been shown to have the features expected of a seniority-four proton excitation yet the pion data show charge symmetry. While coupled-channel calculations are not able to reproduce the pion data, they do agree with the shape observed for 42 MeV {alpha} particle scattering to this state, but the magnitude of the {alpha} scattering data is not consistent with a collective model and known ...

1996-02-01

448

A biomass-supported Na2CO3 sorbent for flue gas desulfurization.

A simple one-step method to fabricate hierarchically porous TiO2/Pd composite hollow spheres without any template was developed by using solvothermal treatment. Pd nanoparticles (2-5 nm) were well dispersed in the mesopores of the TiO2 hollow spheres via in-situ reduction. In our experiment, polyvinylpyrrolidone played an important role in the synthetic process as the reducing agent and the connective material between TiO2 and Pd nanoparticles. HF species generated from solvothermal reaction leaded to the formation of TiO2 hollow spheres and Ostwald ripening was another main factor that affected the size and structure of the hollow spheres. The as-prepared TiO2/Pd composite hollow spheres exhibited high electrocatalytic activity towards the reduction of H2O2. The sensitivity was about 226.72 ?A mM-1 ...

2010-10-01

449

Synthesis, characterization, and evaluation of a novel bifunctional chelating agent for the lead isotopes "2"0"3Pb and "2"1"2Pb

A novel sorbent for SO2 removal has been investigated. The sorbent is obtained by conventional incipient wetness impregnation of abandoned biomaterials (straw or dried leaves) with an aqueous solution of Na2CO3. A material with the composition 80 wt % Na2CO3/straw shows a desulfurization activity which is both higher and faster than that of the reference sample Na2CO3/gamma-Al2O3. The breakthrough and stoichiometric SO2 adsorption efficiencies for 80 wt % Na2CO3/straw reach 48.9% and 80.6%, respectively, at a temperature of 80 degrees C. The adsorption efficiencies are almost constant in the temperature range 70 to 300 degrees C. According to IR and XPS analysis the main products observed on the spent sorbent are sulfite below 150 degrees C and sulfate at 300 degrees C. The Na2CO3 in 80 wt % ...

2003-06-01

450

Structure-function studies on inhibitory activity of Bungarus multicinctus protease inhibitor-like protein on matrix metalloprotease-2, and invasion and migration of human neuroblastoma SK-N-SH cells.

Radioisotopes of Pb(II) have been of some interest in radioimmunotherapy and radioimmunoimaging (RII). However, the absence of a kinetically stable bifunctional chelating agent for Pb(II) has hampered its use for these applications. "2"0"3Pb (T_1_/_2=52.02 h) has application potential in RII, with a #gamma#-emission that is ideal for single photon emission computerized tomography, whereas "2"1"2Pb (T_1_/_2=10 h) is a source of highly cytotoxic #alpha#-particles via its decay to its "2"1"2Bi (T_1_/_2=60 min) daughter. The synthesis of the novel bifunctional chelating agent 2-(4-isothiocyanotobenzyl)-1,4,7,10-tetraaza-1,4,7,10-tetra-(2-carbamoyl methyl)-cyclododecane (4-NCS-Bz-TCMC) is reported herein. The Pb[TCMC]"2"+ complex was less labile to metal ion release than Pb[DOTA]"2"- ...

2000-01-01

451

Ni/CeO{sub 2}/ZSM-5 catalysts for the production of hydrogen from the pyrolysis-gasification of polypropylene

In view of the findings that several Kunitz-type protein inhibitors suppress tumor invasion and metastasis, the aim of the present study is to explore whether Bungarus multicinctus protease inhibitor-like protein-2 (PILP-2) and PILP-3 exhibit anti-tumor activity. Although approximately 28% of amino acid substitutions occurred between PILP-2 and PILP-3, molecular modeling suggested that PILP-2 and PILP-3 shared similar folded structures. Unlike PILP-2, PILP-3 showed a notable activity in abolishing migration and invasion of human neuroblastoma SK-N-SH cells. The ability of PILP-3 to inhibit matrix metalloprotease-2 (MMP-2) activity was higher than that of PILP-2. Pull-down assay revealed protein-protein interaction between PILP-3 and MMP-2. In contrast to mutation on N-terminal region, replacement of ...

2009-08-23

452

Low-temperature behavior of two ternary lanthanide nickel carbides: Superconducting LaNiC_2 and magnetic CeNiC_2

The production of hydrogen from the two-stage pyrolysis-gasification of polypropylene using a Ni/CeO{sub 2}/ZSM-5 catalyst has been investigated. Experiments were conducted on CeO{sub 2} loading, calcination temperature and Ni loading of the Ni/CeO{sub 2}/ZSM-5 catalyst in relation to hydrogen production. The results indicated that with increasing CeO{sub 2} loading from 5 to 30 wt.% for the 10 wt.% Ni/CeO{sub 2}/ZSM-5 catalyst calcined at 750 C, hydrogen concentration in the gas product and the theoretical potential hydrogen production were decreased from 63.0 to 49.8 vol.% and 50.4 to 21.6 wt.%, respectively. In addition, the amount of coke deposited on the catalyst was reduced from 9.5 to 6.2 wt.%. The calcination temperature had little influence on hydrogen production for the catalyst containing 5 wt.% of CeO{sub 2}. However, for the 10 ...

2009-08-15

453

Isotope effects on the metabolism and pulmonary toxicity of butylated hydroxytoluene in mice by deuteration of the 4-methyl group

A study of the magnetic properties and the heat capacity as functions of temperature and magnetic field of two ternary carbides RNiC_2, where R=La and Ce, confirms that LaNiC_2 becomes superconducting at T_c=2.7thinspK, and that CeNiC_2 orders antiferromagnetically below 18thinspK. LaNiC_2 is a conventional superconductor with a critical field of 900 Oe at T=2thinspK. CeNiC_2 obeys the Curie-Weiss law between 50 and 300thinspK showing the nearly full Ce"3"+ magnetic moment, p_e_f_f=2.47(1)#mu#_B, and has a negative paramagnetic Weiss temperature #THETA#_p=-18.3(8)thinspK. A low net magnetic moment in the ordered state, which is far from saturation in a magnetic field of 5thinspT, is consistent with an antiferromagnetic ground state. Below 20thinspK CeNiC_2 shows multiple-step magnetic transitions at ...

1998-07-01

454

Investigation of (CeO_2)_x(Sc_2O_3)_(_0_._1_1_-_x_)(ZrO_2)_0_._8_9 (x = 0.01-0.10) electrolyte materials for intermediate-temperature solid oxide fuel cell

A comparative test in mice for pulmonary toxicity between butylated hydroxytoluene (2,6-di-tert.-butyl-4-methylphenol, BHT) and 2,6-di-tert.-butyl-4-(alpha, alpha, alpha-2H3)methylphenol (BHT-d3) showed a significantly lower toxic potency of the latter. The rate of in vitro BHT metabolism to 2,6-di-tert.-butyl-4-methylene-2,5-cyclohexadienone (BHT-QM) was slowed by deuterating BHT in the 4-methyl group. On the other hand, the rate of in vitro metabolism to 2,6-di-tert.-butyl-4-hydroxy-4-methyl-2,5-cyclohexadienone (BHT-OH) was increased with the deuteration. A similar isotope effect of the deuterium substitution on the in vivo metabolic rates of BHT was observed. These observations support the concept that the lung damage caused by BHT is mediated by BHT-QM. The pulmonary toxicity of 2-tert.-butyl-4-ethylphenol (4-EP) ...

1983-06-30

455

Improvement of electrochemical stability of LiMn{sub 2}O{sub 4} by CeO{sub 2} coating for lithium-ion batteries

Oxide ionic conductivities of (CeO_2)_x(Sc_2O_3)_(_0_._1_1_-_x_)(ZrO_2)_0_._8_9 (x = 0.01-0.10) electrolytes were optimized for the application in intermediate-temperature solid oxide fuel cell (IT-SOFC). Powders with different contents of CeO_2 and Sc_2O_3 were prepared via a co-precipitation method. The obtained powders and pellets were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and impedance spectroscopy. Among all the compositions, (CeO_2)_0_._0_4(Sc_2O_3)_0_._0_7(ZrO_2)_0_._8_9(4Ce7ScZr) gives the highest ionic conductivity of 0.065 S cm"-"1 at 800 "oC. The effects on densification and electrical properties of different sintering additives, such as SiO_2, MgO, Co_3O_4, MoO_3 and Bi_2O_3, were studied and ...

2010-07-23

456

Evidence of network demixing in GeS2-Ga2S3 chalcogenide glasses: A phase transformation study

CeO{sub 2}-coated LiMn{sub 2}O{sub 4} spinel cathode was synthesized using two-step synthesis method. All the samples exhibited a pure cubic spinel structure without any impurities in the XRD patterns. The results of the electrochemical performances on CeO{sub 2}-coated electrode are compared to those of electrodes based on LiMn{sub 2}O{sub 4} spinel without CeO{sub 2} coating. CeO{sub 2}-coated LiMn{sub 2}O{sub 4} cathode improved the cycling stability of the electrode. The capacity retention of 2 wt% CeO{sub 2}-coated LiMn{sub 2}O{sub 4} was more than 82% after 150 cycles between 3.0 and 4.4 V at room temperature and 82% after 40 cycles at elevated temperature of 60 C. The amounts of dissolved manganese-ions in CeO{sub 2}-coated LiMn{sub ...

2007-02-15

457

Chelation of intracellular calcium blocks insulin action in the adipocyte

The information of phase transformation is attained by in situ XRD experiments leading to the knowledge of topological threshold in GeS2-Ga2S3 glasses. The turning point of phase transformation behavior is demonstrated to be glasses containing 14-15 mol% Ga2S3. To interpret it a network demixing model is further improved and proposed for the structure of these ternary or quasi-binary chalcogenide glasses. For the nearest-neighbor coordination environment of glass with a transitional composition of 85.7 mol% (6/7) GeS2.14.3 mol% (1/7) Ga2S3, six-coordinated [S3Ga-X-GaS3] units (X=S or None) are well isolated by the [GeS4] structures, which contributes to the decreasing of precipitation of Ga2S3 crystals in (100-x)GeS2-xGa2S3 (x?14.3) glasses corresponding to the experimental evidence of the phase transformation behavior. ...

2011-03-01

458

A study of the reactions of ethanol on CeO{sub 2} and Pd/CeO{sub 2} by steady state reactions, temperature programmed desorption, and in situ FT-IR

The hypothesis that intracellular Ca/sup 2 +/ is an essential component of the intracellular mechanism of insulin action in the adipocyte was evaluated. Cells were loaded with the Ca/sup 2 +/ chelator quin-2, by preincubating them with quin-2 AM, the tetrakis(acetoxymethyl) ester of quin-2. Quin-2 loading inhibited insulin-stimulated glucose transport without affecting basal activity. The ability of insulin to stimulate glucose uptake in quin-2-loaded cells could be partially restored by preincubating cells with buffer supplemented with 1.2 mM CaCl/sub 2/ and the Ca/sup 2 +/ ionophore A23187. These conditions had no effect on basal activity and omission of CaCl/sub 2/ from the buffer prevented the restoration of insulin-stimulated glucose uptake by A23187. ...

1987-02-01

459

A pilot-scale jet bubbling reactor for wet flue gas desulfurization with pyrolusite.

The reaction of ethanol on unreduced and H{sub 2}-reduced CeO{sub 2} and 1 wt% Pd/CeO{sub 2} has been investigated by steady state reactions, temperature programmed desorption (TPD), and in situ Fourier transform infrared (FT-IR) spectroscopy. Steady state reactions have shown a zero reaction order dependency for diatomic oxygen at and above 20%, while the addition of Pd to CeO{sub 2} decreases the apparent activation energy of the reaction from 75 kJ/mol on CeO{sub 2} alone to 40 kJ/mol (Pd/CeO{sub 2}). TPD experiments following ethanol adsorption on both CeO{sub 2} and Pd/CeO{sub 2} have shown desorption profiles corresponding to unreacted ethanol and various reaction and decomposition products (acetaldehyde, acetone, CO, CO{sub 2}, and methane). Ethanol conversion to reaction products was ...

1999-09-10

460

Two and 8-azido photoaffinity probes. 1. Enzymatic synthesis, characterization, and biological properties of 2- and 8-azido photoprobes of 2-5A and photolabeling of 2-5A binding proteins

MnO2 in pyrolusite can react with SO2 in flue gas and obtain by-product MnSO4 x H2O. A pilot scale jet bubbling reactor was applied in this work. Different factors affecting both SO2 absorption efficiency and Mn2+ extraction rate have been investigated, these factors include temperature of inlet gas flue, ration of liquid/solid mass flow rate (L/S), pyrolusite grade, and SO2 concentration in the inlet flue gas. In the meantime, the procedure of purification of absorption liquid was also discussed. Experiment results indicated that the increase of temperature from 30 to 70 K caused the increase of SO2 absorption efficiency from 81.4% to 91.2%. And when SO2 concentration in the inlet flue gas increased from 500 to 3000 ppm, SO2 absorption efficiency and Mn2+ ...

2005-01-01

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

461

Estimating the stabilities of aqueous actinide complexes with sulfoxy-anions

The 2- and 8-azido trimer 5'-triphosphate photoprobes of 2-5A have been enzymatically synthesized from [#gamma#-"3"2P]2-azidoATP and [#alpha#-"3"2P]8-azidoAPT by 2-5A synthetase from rabbit reticulocyte lysates. Identification and structural determination of the 2- and 8-azido adenylate trimer 5'-triphosphates were accomplished by enzymatic hydrolyses with T2 RNase, snake venom phosphodiesterase, and bacterial alkaline phosphatase. Hydrolysis products were identified by HPLC and PEI-cellulose TLC analyses. The 8-azido photoprobe of 2-5A displaces p_3A_4["3"2P]pCp from RNase L with affinity equivalent to p_3A_3. The 8-azido photoprobe also activates RNase L to hydrolyze poly(U)["3"2P]pCp 50% at 7 /times/ 10/sup /minus/9/ M in core-cellulose assays. The ...

462

Synthesis and spectral characteristics of Sr2Y8(SiO4)6O2: Eu polycrystals

Full text of publication follows: Stable aqueous sulfur species are mainly sulfide (H{sub 2}S) and sulfate (SO{sub 4}{sup 2-}) ions. However, several sulfoxy-anions may be detected as metastable anions in natural environment, as typically thiosulfate (S{sub 2}O{sub 3}{sup 2-}) and sulfite (SO{sub 3}{sup 2-}) ions [1]. In natural systems, uranium speciation and migration are mainly governed by carbonate complexes in non reducing conditions. Whereas sulfate is already known as a complexing agent of actinides, data relating to U-SO{sub 3}{sup 2-} and U-S{sub 2}O{sub 3}{sup 2-} complexes have only been proposed for U(VI) [2], but are usually not included in thermodynamic databases [3]. Therefore, it appears to be relevant to determine complexation constants of actinides with sulfur ligands, for RN ...

2005-07-01

463

Modeling global atmospheric CO2 with improved emission inventories and CO2 production from the oxidation of other carbon species

Spectral-luminescent characteristics of Sr2Y8(SiO4)6O2: Eu powder crystal phosphor with the apatite structure and high-intensity luminescence of Eu3+ ions have been studied. The charge state of europium in the samples has been characterized by means of X-ray L3-adsorption spectroscopy. It was established that Eu3+ forms two types of optical centers. Besides, luminescence of Eu2+ions was found. Reduction Eu3+#->#Eu2+ was considered, which may be due to VSr|| vacancy formation in the 4f crystal lattice position and to negative charge transfer by this vacancy to two EuY3+ ions. Thus, in the silicate lattice there exist inhomogeneously distributed oxygen-deficient centers, which are responsible for nonradiative transfer of excitation energy to Eu3+ and Eu2+ ions. To study electron-vibrational interactions in the crystal phosphor samples, their IR and Raman spectra were examined. In ...

2011-01-01

464

A kinetic and mechanistic study of the oxidation of silicon- and thin metal silicide layers

The use of global three-dimensional (3-D) models with satellite observations of CO2 in inverse modeling studies is an area of growing importance for understanding Earth s carbon cycle. Here we use the GEOS-Chem model (version 8-02-01) CO2 mode with multiple modifications in order to assess their impact on CO2 forward simulations. Modifications include CO2 surface emissions from shipping (0.19 PgC yr 1), 3-D spatially-distributed emissions from aviation (0.16 PgC yr 1), and 3-D chemical production of CO2 (1.05 PgC yr 1). Although CO2 chemical production from the oxidation of CO, CH4 and other carbon gases is recognized as an important contribution to global CO2, it is typically accounted for by conversion from its precursors at the surface rather than in the free troposphere. We base our model 3-D spatial distribution of ...

2010-01-01

465

Virtual Compton Scattering: Results from Jefferson Lab

The formation of thin SiO_2 layers on silicon and metal silicides was studied by phase- and thickness measurements with Rutherford back-scattering of 2 MeV alfa particles. Thermal oxidation was done in steam and dry oxygen at temperatures between 750 degrees Celsius and 1 100 degrees Celsius, while SiO_2 formation at room temperature was carried out by anodic oxidation. The study of silicon oxidation was done on Si<100>, Si<111> and amorphous silicon substrates. Thermal oxidation of CoSi_2, CrSi_2, NiSi_2, PtSi and TiSi_2 was investigated. The oxidation rates of the silicides were found to be much higher than for silicon. The oxidation process is also diffusion-limited with a higher oxidation rate for steam as compared to dry oxygen. The silicide layers were found to stay intact during thermal oxidation. A certain amount of ...

466

Virtual Compton Scattering o013 the proton has been studied at Q 2 -values of 1:0 and 1:9 (GeV=c) 2 in Hall A at the Thomas Je013erson National Accelerator Facility (JLab). Data were taken below and above the pion production threshold as well as in the resonance region. Results obtained below pion threshold at Q 2 = 1:0 (GeV=c) 2 are presented in this paper.

2003-05-01

467

Unclas

Thallium-201 yields and excitation functions for the lead radioactivities produced by irradiation of natural thallium with 15-60 MeV protons

Another difference lies in the speed of star evolution. 2. Computation of Stellar Structure and Their Evolution. The structure of stars at certain instants ...

468

Synthesis of substituted ["1"2"5I]iodophenyl amine derivatives: possible brain imaging agents

Excitation functions, production yields and radionuclidic purities are described for "2"0"1Tl production by the "2"0"3Tl(p,3n) "2"0"1Pb #-># "2"0"1Tl and "2"0"5Tl(p,5n)"2"0"1Pb#->#"2"0"1Tl nuclear reactions. The yields (mCi g"-"1 cm"2/#mu#A-hr) of the parent "2"0"1Pb(9.4hr), as well as the radiocontaminants "2"0"0Pb(21.5hr), sup(202m)Pb(3.62 hr), "2"0"3Pb(52.1 hr) and sup(204m)Pb(1.115 hr) were measured by irradiating a stack of thin natural Tl foils with protons from the 76-in isochronous cyclotron at the Crocker Nuclear Laboratory. The "2"0"1Tl thick-target yield (mCi/#mu#A hr) was calculated for different target thicknesses and corresponding incident proton energies. The excitation functions for the ...

469

Synthesis of Some 2-Amino-5-Substituted-1,3,4-Oxadiazoles Through the Electrooxidation of Semicarbazone

Brief item.

470

Synthesis and stereochemical effects of pyrrolidinyl-acetylenic thieno[3,2-d]pyrimidines as EGFR and ErbB-2 inhibitors

Full Text Available

2009-04-01

471

British Library Electronic Table of Contents (United Kingdom)

A novel class of pyrrolidinyl-acetyleneic thieno[3,2-d]pyrimidines has been identified which potently inhibit the EGFR and ErbB-2 receptor tyrosine kinases. Synthetic modifications of the pyrrolidine carbamate moiety result in a range of effects on enzyme and cellular potency. In addition, the impact of the absolute stereochemical configuration on cellular potency and oral mouse pharmacokinetics is described.

2009-01-01

472

Sulphate addition of Fe-Nb, Co-Nb and Ni-Nb alloys in mixtures H{sub 2}-H{sub 2} S at 800 deg C; Sulfetacao de ligas Fe-Nb, Co-Nb e Ni-Nb em misturas H{sub 2}-H{sub 2} S a 800 C

Role of B2 Adrenergic Receptors in Labor Pain

Short communication

1993-12-31

473

Regulation of cloned, Ca2+-activated K+ channels by cell volume changes.

Pain; Pain Threshold; Labour Pain

2010-10-01

474

Radiometric measurement of lead-201 and thallium-201 activity in industrial production of thallium chlorides

Udgivelsesdato: 2002-May

2002-01-01

475

Preparation and radiolabeling of IBZM: a potential D-2 specific brain imaging agents for SPECT

The spectrometric methods and equipment for "2"0"1Pb and "2"0"1Tl activity control in the prepared thallium chloride in industrial production are described. Estimation of thallium-201 activity is carried out in accord with the square of summary photopeak caused by #gamma#-quanta at 167 keV energy. Attenuation is paid to spectrometer calibration. 5 refs.; 2 figs.; 2 tabs.

476

Part 2: Terms of Reference

In developing new receptor-site specific brain imaging agents labeled with I-123 for single photon emission computed tomography (SPECT), an analog of raclopride, 3-["1"2"5I]-iodo-N-[(1-ethyl-2-pyrrolidinyl)-methyl]-2-hydroxy-6-me-thoxy benzamide (IBZM), was prepared using a method similar to that reported for raclopride and its derivatives. (author).

477

Occult brain metastases in HER2-positive breast cancer patients: Frequency and response to radiotherapy

The paragraph shall start with a simple declarative sentence in bold font that presents the subject matter

478

Novel inorganic hydrogen-bonded crystals with nonlinear optical properties

No abstract prepared.

2007-10-15

479

Four inorganic hydrogen-bonded crystals with second-order nonlinear properties have been discovered: K_4LiH_3(SO_4)_4, Na_2SeO_4#centre dot#H_2SeO_3#centre dot#H_2O, Cs_1_,_5Li_1_,_5H(SO_4)_2 and NH_4HSeO_4. (author)

2000-01-01

480

N7'5 20853

Mechanochemical synthesis of the high lithium ion conductive amorphous materials in the systems Li{sub 2}S-SiS{sub 2} and Li{sub 2}S-SiS{sub 2}-Li{sub 4}SiO{sub 4}

of fracture -stimulated geothermal reservoirs; 2) the development of ... of the mathematical simulation model of geothermal reservoirs. ...

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25

481

Localization of "2"0"3Pb-chloride in myocardial infarction

Amorphous materials in the system xLi{sub 2}S{center_dot}(100-x)SiS{sub 2}, where x ranged from 50 to 70 mol %, and (100-y) (0.6Li{sub 2}S{center_dot}0.4SiS{sub 2}){center_dot}yLi{sub 4}SiO{sub 4}, where y ranged from 0 to 10 mol %, were synthesized by mechanical milling of crystalline starting materials, Li{sub 2}S, SiS{sub 2} and Li{sub 4}SiO{sub 4}. At the compositions with large amounts of Li{sup +} ions, a part of crystalline Li{sub 2}S used as a starting material remained in the milled powder samples. It was found that the milled powder samples in both systems obtained by mechanical milling exhibited high conductivities in the order of 10{sup -4}S{center_dot}cm{sup -1} at room temperature in spite of the presence of small amounts of Li{sub 2}S crystals. The conductivity values of the pelletized samples of xLi{sub ...

2000-02-01

482

High temperature creep with an additional fatigue loading of alloy 800 type

... AND NUCLEAR MEDICINE biological localization cardiovascular diseases

483

GaAs/(ordered) GaInP2 Heterostructures under Pressure and HighMagnetic Fields

Short communication. 6 refs., 2 figs.

1992-12-31

484

G2 checkpoint siRNA screen in irradiated cancer cells: validation of candidate positive hits

No abstract prepared.

1998-09-01

485

Norwegian Open Research Archives (NORA)

Full Text Available

486

Enteric neural pathways mediate the anti-inflammatory actions of glucagon-like peptide 2

Effects of Elevated Atmospheric $CO_2$ Concentrations on Soil Microorganisms

Udgivelsesdato: 2007/7

2007-01-01

487

Effect of Heat Treatment on CO2 Adsorption of Ammonized Graphite Nanofibers

Full Text Available

2004-12-01

488

Economic effects on taxing CO{sub 2} emissions

Full Text Available

2010-03-01

489

EOP-MOD Ver 2.0 2444055.5 1.0 11875 UT1-TAI UNDEF # Earth ...

The CO{sub 2} emissions can be reduced by using economic instruments, like carbon tax. This project included two specific questions related to CO{sub 2} taxation. First one was the economic effects of increasing CO{sub 2} tax and decreasing other taxes. Second was the economic adjustment costs of reducing net emissions instead of gross emissions. A computable general equilibrium (CGE) model was used in this analysis. The study was taken place in Helsinki School of Economics

1996-12-31

490

... 2.3385 -27064396 0.0037 0.0030 15. .000 .000 .000 2449038.5 1.9466 2.3213 - 27066977 0.0037 0.0035 12. .000 .000 .000 2449039.5 1.9312 2.3064 -27069688 ...

491

Duct and cladding alloy

Discrimination between UTP- and P2-purinoceptor-mediated depolarization of rat superior cervical ganglia by 4,4'-diisothiocyanatostilbene-2,2'- disulphonate (DIDS) and uniblue A.

An austenitic alloy having good thermal stability and resistance to sodium corrosion at 700.degree. C. consists essentially of 35-45% nickel 7.5-14% chromium 0.8-3.2% molybdenum 0.3-1.0% silicon 0.2-1.0% manganese 0-0.1% zirconium 2.0-3.5% titanium 1.0-2.0% aluminum 0.02-0.1% carbon 0-0.01% boron and the balance iron.

1983-01-01

492

Decomposition of tar in pyrolysis gas by partial oxidation and thermal cracking. Part 2

1. Using a grease-gap recording technique we have investigated the effects of some antagonists of P2-purinoceptors on the depolarization of the rat isolated superior cervical ganglion evoked by 100...Full Text Available

1995-06-01

493

CIR11_A14_17Apr01_all_r.asc - NASA

No abstract prepared

1998-12-31

494

Apr 17, 2001... 128.38428 2.074 2.075 793.07 0.3929 0.1131 0 2.0467 2.0394 1.9932 1.9810 1.9751 1.9556 1.9488 1.9312 1.9256 1.9232 1.9382 1.9140 1.9388 ...

495

CBD2_9

Building LAMMPS data files with car/mdf files and the msi2lmp utility.

yes Grab sam- plers, wire mesh sieve, Rose Bengal stain, buoys, boat, sorting

496

An identity on the $2m$-th power mean value of the generalized Gauss sums

No abstract prepared.

2010-03-01

497

A precise structure redetermination of nickel ammonium sulfate hexahydrate, Ni(H_2O)_6.2NH_4.2SO_4

In this paper, using combinatorial and analytic methods, we prove an exact calculating formula on the $2m$-th power mean value of the generalized quadratic Gauss sums for $m\\geq 2$. This solves a conjecture of He and Zhang [`On the $2k$-th power mean value of the generalized quadratic Gauss sums', Bull. Korean Math. Soc. 48 (2011), No.1, 9-15].

2011-01-01

498

A new unified approach to bradyons and tachyons by conformal transformations

The Ni(H_2O)_6 ion is located at an inversion center. Six octahedral water molecules surround the Ni"I"I ion and form hydrogen bonds with the sulfate groups. Each ammonium group binds to the sulfate groups through hydrogen bonds. (orig.).

1994-05-01

499

${T_2}weighted$- Half courier Echo Planar Imaging

By using linearized conformal transformations in six dimensions, a new unified approach to bradyons (v"2< c"2) and tachyons (v"2>c"2) is suggested, the essential tool being (real and imaginary) dilatations. The usual ''Generalized Lorentz transformations'' are got, In six dimensions the quadrate form is always positive, both for bradyons and for tachyons.

500