Science.gov (United States)

... F.; Murray, R. W. J. Am. Chem. ... 14. Thackeray, J. W.; White, H. S.; Wrighton, M. SJ Phys. ... Dr. James S. Murday (1) Dr. Harold H. Singerman (i) ...

British Library Electronic Table of Contents (United Kingdom)

Summary Indigenous people demonstrably lived along rivers and around lakes and wetlands of Australia's Murray-Darling Basin in pre-European times. Waterways were, and continue to be, of major significance to the society and culture of Aboriginal peoples throughout Australia. Historically, they exploited most of the fauna - from mussels and crayfish, to fish and birds - and either ate, or used for other purposes, many species of aquatic plants. Such practices placed them in the role of environmental modifiers, a role played by all human groups from both past and present. They built sophisticated fish traps, cut gaps in river banks to allow fish to move on to floodplains, and there is evidence that they practised a form of fish culture by creating small impoundments in which small fish could...

UK PubMed Central (United Kingdom)

BackgroundMaintenance of healthy bone requires the balanced activities of osteoclasts (OCs), which resorb bone, and osteoblasts, which build bone. Disproportionate action of OCs...Full Text Available

Science.gov (United States)

C CCNA DPoPC @"y( mPC~ lPC; CCP0u# WSC# D kPC D`hPCs gOC0 D@dOC @Rq) bOCh DpaOC% @`0) ?u<9 D@]OC] DxZOC WOCR D@VOC D ROCG @vN% D`OOC LOC< D0KOC WPL` HOCs ...

Energy Technology Data Exchange (ETDEWEB)

In 1991, the air quality monitoring program in Alberta consisted of continuous, intermittent, static, portable, mobile, and acid precipitation monitoring networks. The air quality monitoring networks are described and results from the continuous, intermittent, static, and acid precipitation networks are summarized. Regulations and guidelines for individual pollutants are discussed in detail. Pollutants monitored continuously (1-h average basis) include ammonia, CO, coefficient of haze, H{sub 2}S, nitrogen oxides, ozone, SO{sub 2}, and total hydrocarbons. Good air quality was observed most of the time at all continuous monitoring stations in 1991. The frequency of good air quality ratings ranged from 81% at the Edmonton northwest station to 98% at the Fort McMurray station. Intermittent monitoring (every 6th day) was conducted for total suspended particulates and for vinyl chloride monomers in the Fort Saskatchewan area. Chemical analyses of benzo(a)pyrene and lead ...

Energy Technology Data Exchange (ETDEWEB)

Some properties of the remarkable Ti{sub 3}SiC{sub 2} based ceramic synthesised by hot pressing of elemental Ti, Si, and C powders have been investigated. Its flexural strength by using three point bending tests and fracture toughness by using single edge notched beam tests were measured at room temperature to be in the range 310-427 MPa and about 7.MPa m{sup 1/2}, respectively. This material is a relative 'soft' ceramic with a low hardness of 4 GPa. Ti{sub 3}SiC{sub 2} is similar to the soft metals and is a damage tolerant material that is able to contain the extent of microdamage. An oxidation test has been performed in the temperature range 1000-1400{sup o}C in air for 20 h. The oxidation resistance below 1100{sup o}C was good. Two oxidized layers were formed, the outer layer consisting of pure rutile-type TiO{sub 2}, and the inner layer a mixture of SiO{sub 2} and TiO{sub 2}. The average coefficient of thermal expansion ...

British Library Electronic Table of Contents (United Kingdom)

Using a new simulative technique developed by us, we systematically investigated new ternary or quaternary molten salt systems, which are based on LiF-LiCl, LiF-LiBr, and LiCl-LiBr binary systems, for use as electrolytes in thermal batteries, and evaluated their ionic conductivities and melting points experimentally. It was confirmed experimentally that LiF-LiBr-KF (melting point: 425^oC, ionic conductivity at 500^oC: 2.52Scm^-^1), LiCl-LiBr-KF (405^oC, 2.56Scm^-^1), LiCl-LiBr-NaF-KF (425^oC, 3.11Scm^-^1), LiCl-LiBr-NaCl-KCl (420^oC, 2.73Scm^-^1), and LiCl-LiBr-NaBr-KBr (420^oC, 2.76Scm^-^1) meet our targets for both melting point (350-430^oC) and ionic conductivity (2.0Scm^-^1 and higher at 500^oC). A single cell using the newly developed LiCl-LiBr-NaCl-KCl molten salt as an electrolyte w...

Energy Technology Data Exchange (ETDEWEB)

Geothermal energy resources are found in many countries. A reasonable and efficient utilization of these resources has been a worldwide concern. The application of geothermal heat pump systems (GHPS) can help increase the efficiency of using geothermal energy and reduce the thermal pollution to the earth surface. However, this is only possible with a proper working fluid. In this paper, a non-azeotropic working fluid (R290/R600a/R123) is presented for a GHPS where geothermal water at 40-45{sup o}C and heating network water at 70-80{sup o}C serve as the low and high temperature heat sources. Experimental results show that the coefficient of performance (COP) of a GHPS using the working fluid is above 3.5 with the condensation temperature above 80{sup o}C and the condensation pressure below 18 bar, while the temperature of the geothermal water is reduced from 40-46{sup o}C to 31-36{sup ...

Environmental Research Database

Objectives1) To develop and test a simple yet effective management tool which the Chemical Process Industry can~%~ incorporate into its Environmental Management Systems linking Life Cycle Assessment with Sustainable~%~ Development and through Risk Assessment produce a Methodology which will allow companies to~%~ prioritize their moves towards a more sustainable business practice.~%~~%~ 2) Through this network on sustainable processing practice establish an inter-disciplinary li [continued...]Description~%~'Sustainable Development is a network of Sustainable Processing Routes, or ways of doing things' (Boron, Murray,2000)~%~~%~We should like to explore this concept, through the network of academic colleagues listed, supported by key companies who have already established EMAS /ISO accreditation portfolios (letters attached), and through collaboration with other like-minded practitioners in the field (SIGMA), attempt to develop the ...

Science.gov (United States)

In the past decade, the large tailings pond (Mildred Lake Settling Basin) on the Syncrude Canada Ltd. lease near Fort McMurray, Alta., has gone methanogenic. Currently, about 60%-80% of the flux of gas across the surface of the tailings pond is methane. As well as adding to greenhouse gas emissions, the production of methane in the fine tailings zone of this and other settling basins may affect the performance of these settling basins and impact reclamation options. Enumeration studies found methanogens (10(5)-10(6) MPN/g) within the fine tailings zone of various oil sands waste settling basins. SRB were also present (10(4)-10(5) MPN/g) with elevated numbers when sulfate was available. The methanogenic population was robust, and sample storage up to 9 months at 4 degrees C did not cause the MPN values to change. Nor was the ability of the consortium to produce methane delayed or less efficient after storage. Under laboratory conditions, fine tailings samples ...

International Nuclear Information System (INIS)

The layered GdBa_0_._5Sr_0_._5Co_2O_5_+_#delta# (GBSC) perovskite oxides are synthesized by modified Pechini method and investigated as a novel cathode material for solid oxide fuel cells (SOFCs) based on a stable perovskite oxide BaCe_0_._5Zr_0_._3Y_0_._1_6Zn_0_._0_4O_3_-_#delta# (BCZYZ) as electrolyte. The fabricated single cells of NiO-BCZYZ/BCZYZ (#approx#20 #mu#m)/GBSC (#approx#20 #mu#m) were operated from 550 to 700 "oC with humidified hydrogen (#approx#5% H_2O) as fuel. The BCZYZ perovskite electrolyte was completely dense after sintered at 1250 "oC for 5 h, lower than that without zinc dopant about 150 "oC. An open circuit voltage of 1.009 V and a maximal power density of 0.35 W cm"-"2 were achieved at 700 "oC. The interfacial polarization resistance was as low as 1.46, 0.45, 0.25 and 0.15 #OMEGA# cm"2 at 550, 600, 650 and 700 "oC, respectively. The ratio of polarization ...

British Library Electronic Table of Contents (United Kingdom)

The effect of mean daily air temperature (MDT) on flowering rate (the reciprocal of days to flower) was quantified for 18 species of annual bedding plants. Plants were grown in environmental growth chambers at constant air temperature set points of 5, 7.5, 10, 15, 25, or 30^oC and under an irradiance of 160-180mmolm^-^2s^-^1, with a 16-h photoperiod. Nonlinear mathematical equations were developed to predict the effect of MDT on flowering rate and to estimate the base, optimum, and maximum temperatures (Tmin, Topt, and Tmax), which are the temperatures at which flowering rates are zero (low temperature), maximal, and zero once again (high temperature), respectively. The estimated Tmin varied among species and ranged from 1.1^oC in French marigold (Tagetes patula L.) to 9.9^oC in angelonia ...

Energy Technology Data Exchange (ETDEWEB)

Triethanolamine (TEA) has been evaluated as an additive to a commercial electrolyte to enhance the properties of aluminum electrolytic capacitors. The results showed 1-3wt.% TEA additive can prevent the pH and conductivity of the electrolytes from decreasing for 5000h at 60{sup o}C. The anodic restoration ability of an anode aluminum film in the electrolyte with TEA additive showed more efficient than the electrolyte without TEA additive. Low temperature electric characteristics of capacitors showed that TEA additive can prevent the electrolyte inside capacitors from freezing and losing electric characteristics even at -40{sup o}C. Load life test of capacitors impregnated with electrolytes with or without TEA additive showed remarkable differences. The TEA additive promoted 105{sup o}C load life time from 3019h up to 5624h and form 2144h up to 3621h for 125{sup o}C load life time test. (author)

British Library Electronic Table of Contents (United Kingdom)

The sycamore lace bug, Corythucha ciliata is a new, invasive pest of Platanus trees in China. Although C. ciliata is often subjected to acute low temperatures in early winter and spring in northern and eastern China, the cold tolerance of C. ciliata has not been well studied. The objectives of this study were to determine whether adults of C. ciliata are capable of rapid cold hardening (RCH), and to compare the benefits of RCH vs. cold acclimation (ACC) in the laboratory. When the adult females incubated at 26^oC were transferred directly to the discriminating temperature (-12^oC) for 2h, survival was only 22%. However, exposure to 0^oC for 4h before transfer to -12^oC for 2h induced RCH, i.e., increased survival to 68%. RCH could also be induced by gradual cooling of the insects at rates ...

International Nuclear Information System (INIS)

In the present study, Fe_4_1Co_4_1 B_1_0Zr_7Cu_1 alloy has been investigated in order to evaluate its thermal stability and structure after heat treatment, as well as the impact of heat treatment on magnetic properties. X-ray diffractometry, differential scanning calorimetry, chemical composition microanalysis, transmission electron microscopy, and magnetic hysteresis loop measurement techniques were employed. The crystallization temperature of the as-quenched alloy is 490"oC (continuous heating at 5 "oC/min). The melt spun ribbon having 27 #mu#m in thickness was annealed for 1 hour at temperatures from 400 to 700 "oC. The alloy after treatment at about 550"oC underwent primary crystallization, with the average size of crystals under 20 nm. This specimen shows the coercive field of 38 A/m, as compared to about 160 A/m reported for a similar alloy (Fe_4_4Co_4_4B_4Zr_7Cu_1) with a similar structure, annealed at ...

International Nuclear Information System (INIS)

The nanocrystallization process of amorphous Fe_7_3_._5Si_1_3_._5B_9Nb_3Cu_1 was investigated by active screen plasma nitriding (ASPN) treatment at temperatures ranging from 410 "oC to 560 "oC for 3 h in two gas mixtures of 75% N_2-25% H_2 and 25% N_2-75% H_2 at 5 mbar atmosphere. The amorphous ribbons were then annealed under vacuum at the same time and temperatures mentioned above. The structure of the samples was analyzed using various techniques such as X-ray diffraction (XRD), atomic force microscopy (AFM) and differential scanning calorimetry (DSC). Microhardness measurements, electrical resistivity and Vibrating Sample Magnetometer (VSM) were used to study mechanical, electrical and magnetic properties of the samples, respectively. It was observed that the ASPN treatment leads to finer grain size and higher crystalline volume fraction and modifies the structural features of Fe(Si) phase. The Fe(Si) lattice parameter for the nitrided ...

International Nuclear Information System (INIS)

The layered PrBaCo_2O_5_+_#delta# (PBCO) perovskite oxides were synthesized by modified Pechini method and investigated as a cathode material for solid oxide fuel cells (SOFCs) based on a stable and easily sintered perovskite oxide BaCe_0_._5Zr_0_._3Y_0_._1_6Zn_0_._0_4O_3_-_#delta# (BCZYZ) as electrolyte. The fabricated single cell of NiO-BCZYZ/BCZYZ (#approx#20 #mu#m)/PBCO was operated from 550 to 700 "oC with humidified hydrogen (#approx#5% H_2O) as fuel and the static air as oxidant. The BCZYZ perovskite electrolyte was completely dense after sintered at 1250 "oC for 5 h, lower than that without zinc dopant about 150 "oC. A high open-circuit potential of 1.007 V, a peak power density of 361 mW cm"-"2, and a low polarization resistance of the electrodes of 0.12 #OMEGA# cm"2 was achieved at 700 "oC. The ratio of polarization resistance to total cell resistance decreased with the increase of operating ...

Energy Technology Data Exchange (ETDEWEB)

Biological marker maturity parameters were used to estimate the minimum HC generation temperatures of crude oils from Eastern Hungary. More than 50 oils and oil shows were analysed. Molecular- and homologous-ratios of biological marker compounds (triterpanes, steranes, mono- and triaromatic steroid hydrocarbons) were used as maturation parameters. The oils have at least five maturity stages, i.e. they have been generated under different thermal conditions. The highest reservoir temperature in each group was chosen as the best estimate of the groups' temperature just below the generation temperature, i.e. reservoirs of the group might be expected to be at shallower depths (lower temperatures) than those of the generation zone due to vertical migration into pools. For each maturation level, a threshold temperature range for genesis was inferred from reservoir temperatures; they are from 130-135{sup o}C for the least mature oils to 210-215{sup ...

British Library Electronic Table of Contents (United Kingdom)

Sm"1"."8Ce"0"."2CuO"4-xCe"0"."9Gd"0"."1O"1"."9"5 (SCC-xCGO, x=0-12vol.%) composite cathodes supported on Ce"0"."9Gd"0"."1O"1"."9"5 (CGO) electrolyte are studied for applications in IT-SOFCs. Results show that Sm"1"."8Ce"0"."2CuO"4 material is chemically compatible with Ce"0"."9Gd"0"."1O"1"."9"5 at 1000^oC. The composite electrode exhibits optimum microstructure and forms good contact with the electrolyte after sintering at 1000^oC for 4h. The polarization resistance (R"p) reduces to the minimum value of 0.17@Wcm^2 at 750^oC in air for SCC-CGO06 composite cathode. The relationship between R"p and oxygen partial pressure indicates that the reaction rate-limiting step is the surface diffusion of the dissociative adsorbed oxygen on the composite cathode.

Energy Technology Data Exchange (ETDEWEB)

Olive bagasse (Olea europea L.) was pyrolysed in a fixed-bed reactor. The effects of pyrolysis temperature, heating rate, particle size and sweep gas flow rates on the yields of the products were investigated. Pyrolysis runs were performed using pyrolysis temperatures between 350 and 550 {sup o}C with heating rates of 10 and 50 {sup o}C min{sup -} {sup 1}. The particle size and sweep gas flow rate varied in the ranges 0.224-1.8 mm and 50-200 cm{sup 3} min {sup -1}, respectively. The bio-oil obtained at 500 {sup o}C was analysed and at this temperature the liquid product yield was the maximum. The various characteristics of bio-oil obtained under these conditions were identified on the basis of standard test methods. The empirical formula of the bio-oil with heating value of 31.8 MJ kg{sup -1} was established as CH{sub 1.65}O{sub 0.25}N{sub 0.03}. The chemical characterization showed that the bio-oil obtained from olive ...

British Library Electronic Table of Contents (United Kingdom)

Triclinic b-BiNbO4 prepared below 750^oC and above 1040^oC (denoted as Low-b and High-b, respectively) and pure orthorhombic a-BiNbO4 at 900^oC were successfully derived from a citrate method and the phase transition from b-BiNbO4 to a-BiNbO4 was first observed in BiNbO4 powders. This phenomenon proves that the abnormal phase transition from b-BiNbO4 to a-BiNbO4 exists in BiNbO4 powder system. The synthesis of Low-b powders can be attributed to the formation of the intermediate phase of Bi5Nb3O15 by the citrate method. With increasing temperature, the Low-b phase gradually turns into a-BiNbO4 due to the thermodynamically metastable state of Low-b. We also identified that the stress in pellet format can accelerate the phase transition from Low-b to a phase of BiNbO4 in comparison with powde...

British Library Electronic Table of Contents (United Kingdom)

We investigated phase transition of ilmenite-type AgSbO3 to pyrochlore by post-heat treatment and the synergy effect of the mixed phases of AgSbO3 on the photocatalytic activities to enhance the activities. The AgSbO3 with an ilmenite structure was prepared by a cation-exchange method. Phase transition from the ilmenite to pyrochlore occurred by proper control of post-heat treatment. The sample that was obtained by post-heat treatment of ilmenite-type AgSbO3 at 660^oC for 3h consisted of both of the ilmenite and pyrochlore phases, and the sample at 685^oC for 4h mainly consisted of the pyrochlore phase. Together with an increase in the ratio of the pyrochlore phase, the optical absorption spectra blue-shifted. The band gaps of single phases of the ilmenite and the pyrochlore were 2.4 and 2...

Energy Technology Data Exchange (ETDEWEB)

Mass transfer to a wall of a horizontal rectangular channel reactor was investigated by the limiting current technique for Reynolds numbers ranging from 200 to 32000. Overall mass transfer coefficients at various mass transfer surface angles were obtained while the reactor was operated under isothermal and non-isothermal conditions. Dimensionless correlations were developed for isothermal flows from 25 to 55{sup o}C and for non-isothermal flows with applied temperature differences up to 30{sup o}C. In the laminar flow range natural convection dominated, but under turbulent conditions combined natural and forced convection prevailed. Mass transfer was approximately doubled under optimum selection of channel surface rotation, temperature gradient and flow rate. (author)

International Nuclear Information System (INIS)

Fly ash from Lagisza power station with addition of kaolin and calculated amount of carbon was reacted in flowing nitrogen at 1520"oC in order to obtain #beta#-sialon. The resulted powder was sintered with and without Y_2O_3 addition. Examinations show that it is possible to sinter that material without any sintering additives, however additive of Y_2O_3 decreases sintering temperature of about 100"oC. Sintering temperature influences the final mechanical properties like: flexural strength, microhardness, Young elastic modulus (E) and fracture toughness (K_I_c). (author)

British Library Electronic Table of Contents (United Kingdom)

In this study, ethanol organosolv pretreatment was investigated and optimized for the pretreatment of empty palm fruit bunch using (1) response surface methodology based on three-variable central composite design and (2) the combined severity parameters. The reaction parameters studied were sulfuric acid concentration (0.5-2.0%), reaction temperature (160-200^oC) and residence time (45-90min). Both models provide valuable and complementary informations: using combined severity parameters, very good predictions were obtained concerning xylan and lignin extraction whereas central composite design is the best model for glucose production. The optimal values of the variables were as the followings: sulfuric acid 2.0% w/w, 160^oC, 78min and the experimental values (96.0%) concerning glucose and...

British Library Electronic Table of Contents (United Kingdom)

Potential of spent biomass of a cyanobacterium, Nostoc linckia HA 46, from a hydrogen bioreactor was studied for biosorption of a textile dye, reactive red 198. The waste biomass was immobilized in calcium alginate and used for biosorption of the dye from aqueous solution using response surface methodology (RSM). Kinetics of the dye in aqueous solution was studied in batch mode. Interactive effects of initial dye concentration (100-500mg/L), pH (2-6) and temperature (25-45^oC) on dye removal were examined using Box-Behnken design. Maximum adsorption capacity of the immobilized biomass was 93.5mg/g at pH 2.0, initial concentration of 100mg/L and 35^oC temperature, when 94% of the dye was removed. Fourier transform infrared (FT-IR) studies revealed that biosorption was mainly mediated by fun...

British Library Electronic Table of Contents (United Kingdom)

The combined processes of plasma nitriding and cathodic arc deposition of (Ti,Cr,Nb)CN coatings were applied to HSS substrates. The nitrided layers, obtained in a mixture of H2 (70%) and N2 (30%) at two different temperatures (480^oC and 510^oC), were examined for the microhardness depth profiles. Characterization of the duplex coatings was performed by investigating elemental and phase composition, texture, hardness, friction and wear. XRD and XPS analyses revealed the formation of a mixture of a carbonitride fcc solid solution, in a dominant proportion, and metallic chromium. The film hardness was measured to be ~34GPa. The duplex (Ti,Cr,Nb)CN coatings exhibited superior tribological behavior as compared to both nitrided layers and non-duplex coatings.

Energy Technology Data Exchange (ETDEWEB)

A brief article gives an update on the commercial exploitation of superconductivity by the American Superconductor Corporation. Potential applications include transmission and distribution, motors, magnetic storage systems, current limiters and transport. The company have produced a kilometre long, ''wrappable'' cable capable of carrying thousands of amps when operating at a temperature of below -140[sup o]C. (UK)

Science.gov (United States)

... Iv mc.4N0 Kt afl qtl- 04n4 ( (Y 4 3.4 0.NO K0 00 0. 04 N oC 0 000 000 04 K1 0 a -# 0.N K) 0 0 0 00 00 a 0 0 0 00 0 C0 K ...

Energy Technology Data Exchange (ETDEWEB)

Assessing the potential environmental and human effects of deploying renewable energy on private and public lands, along our coasts, on the Outer Continental Shelf (OCS), and in the Great Lakes requires a new way of evaluating potential environmental and human impacts. The author argues that deployment of renewables requires a framework risk paradigm that underpins effective future siting decisions and public policies.

Science.gov (United States)

The effects of fluoride on the corrosion behavior of Titanium Grade 7 (0.12-0.25% Pd) have been investigated. Up to 0.1 mol/L fluoride was added to the NaCl brines at 95oC, and three pH values of 4, 8, and 11 were selected for studying pH dependence of fl...

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This final report for the Swiss Federal Office of Energy looks at the possibilities for improved waste water utilization in the Lavey-les-Bains thermal spa, Switzerland. According to the regulations in force, the temperature of the waste water rejected into the Rhone river shall not exceed 30 {sup o}C, what is currently not the case. Also the operational cost shall be reduced and the waste water quality improved. The installations are presented. From the two geothermal wells, mineral water comes out at an average flow rate of 940 l/min and a temperature of 63 {sup o}C. Actual waste water data are reported. The measured thermal water consumption data, including seasonal variations, are analysed by computerized simulation and measures to reduce the consumed volume by the optimization of internal procedures are evaluated. Measures to reduce the quantity of the rejected free chlorine are discussed. Several possible adaptations of the existing space ...

British Library Electronic Table of Contents (United Kingdom)

In this work, bismuth sodium titanate (Bi0.5Na0.5)TiO3 (BNT) and praseodymium (Pr)-doped BNT were successfully produced using the soft combustion technique. The effects of Pr doping on stoichiometry, microstructure, density and dielectric properties were studied. Pure Pr-doped BNT was obtained in all samples containing 5, 10 and 20mol% Pr after calcination at 800^oC for 3h. The produced powders were then pressed into pellets and sintered at 1100^oC for 3h. The very similar ionic radii of Pr^3^+ with Bi^3^+ and Na^+ made it possible to substitute both Bi and Na. The crystallite size and grain size decreased with increasing Pr amount because Pr acted as grain growth inhibitor, both for calcined powders and for sintered pellets. Maximum density was obtained in 5mol% Pr-doped BNT, beyond which...

British Library Electronic Table of Contents (United Kingdom)

TaC and TaC-1wt.% B4C powders were consolidated using spark plasma sintering (SPS) at 1850^oC and varying pressure of 100, 255 and 363MPa. The effect of pressure on the densification and grain size is evaluated. The role of nano-sized B4C as sintering aid and grain growth inhibitor is studied by means of XRD, SEM and high resolution TEM. Fully dense TaC samples were produced at a pressure of 255MPa and higher at 1850^oC. The increasing pressure also resulted in an increase in TaC grain size. Addition of B4C leads to an increase in the density of 100MPa sample from 89% to 97%. B4C nano-powder resists grain growth even at high pressure of 363MPa. The formation of TaB2/Carbon at TaC grain boundaries helps in pinning the grain boundary and inhibiting grain growth. The effect of B4C addition on...

Energy Technology Data Exchange (ETDEWEB)

The mixture of lauric acid and capric acid is a potential latent heat storage material. However, its eutectic melting temperature is quite high for low-temperature thermal energy storage. Addition of naphthalene is proposed. The ternary system lauric acid-capric acid-naphthalene has been investigated by differential scanning calorimetry (DSC), visual polythermal and chromatography of gases. The phase diagram is of an incongruent eutectic type. The eutectic mixture contains 18.4mol% lauric acid, 63.1mol% capric acid and 18.5mol% naphthalene and melts at 13.3{sup o}C. The peritectic mixture contains 32.4mol% lauric acid, 48.2mol% capric acid and 19.4mol% naphthalene and peritectic temperature of 16.2{sup o}C. The incongruent compound was analysed to be CH{sub 3}(CH{sub 2}){sub 10}COOH.CH{sub 3}(CH{sub 2}){sub 8}COOH. The melting temperature of the lauric acid-capric acid-naphthalene eutectic mixture makes it suitable for cooling applications.

Energy Technology Data Exchange (ETDEWEB)

Recent work has indicated that the suppression of boron transient enhanced diffusion (TED) in carbon-rich Si is caused by nonequilibrium Si point defect concentrations, specifically the undersaturation of Si self-interstitials, that result from the coupled out-diffusion of carbon interstitials via the kick-out and Frank--Turnbull reactions. This study of boron TED reduction in Si{sub 1-x-y}Ge{sub x}C{sub y} during 750{sup o}C inert anneals has revealed that the use of an additional reaction that further reduces the Si self-interstitial concentration is necessary to describe accurately the time evolved diffusion behavior of boron. In this article, we present a comprehensive model which includes {l_brace}311{r_brace} defects, boron-interstitial clusters, a carbon kick-out reaction, a carbon Frank--Turnbull reaction, and a carbon interstitial-carbon substitutional (C{sub i}C{sub s}) pairing reaction that successfully simulates carbon suppression of boron TED at ...

Energy Technology Data Exchange (ETDEWEB)

A series of experiments have been conducted on AISI 5140 low alloy steel using a hollow cathode discharge-assisted plasma nitriding apparatus with the aim of elucidating the role of substrate bias voltages in plasma nitriding process. For comparison, some samples were nitrided with applied substrate bias (-50 V) while other samples were nitrided at floating potential. Treatments were carried out in NH{sub 3} atmosphere of 150 Pa at temperatures ranging from 450 {sup o}C to 550 {sup o}C for 2 h, 4 h, and 6 h. The nitrided samples were characterized by optical microscopy, X-ray diffraction and micro-hardness measurement. The corrosion behaviors were evaluated using anodic polarization tests in 3.5% NaCl solution. The results showed that the microstructure and phase constituents of the nitride layers were strongly influenced by the bias voltages. It was also demonstrated that the better corrosion resistance with a thicker nitrided layer was ...

British Library Electronic Table of Contents (United Kingdom)

A parameterized surface wave-induced vertical mixing (B"v) is incorporated into the Modular Ocean Model version 4 (MOM4). A comparison of the two numerical experiments with and without B"v shows that B"v can significantly improve the upper-ocean (20-100m) simulation in summer. The simulated upper-ocean temperature errors are reduced in summer due to the surface wave-induced vertical diffusive heat flux. The non-breaking-wave-induced vertical mixing can increase the probability of the simulated SST biases between -1^oC and 1^oC from 64% to 76% in the Southern Hemisphere (60^oS-10^oS) in January, and from 66% to 75% in the Northern Hemisphere (10^oN-60^oN) in July. The averaged mixed layer depth (MLD) simulated by the MOM4 without B"v is 14.4m shallower than the observations in 10^oS-60^oS i...

Energy Technology Data Exchange (ETDEWEB)

Oil and gas resources in the offshore areas of the US constitute a significant portion of US recoverable hydrocarbon resources. The exploration, development and production of these offshore resources in California, however, could have significant air quality implications for coastal air basins. This study was developed to address a problem that frequently arises with offshore air quality assessments. Typically, such assessments are performed for a specific activity scenario (e.g., a Federal OCS Lease Sale involving a projected number of drilling rigs, platforms, pipelines, etc.) and assume a projected (but uncertain) level of recoverable oil and gas resources. This study enables interested parties to estimate air emissions and impacts for a wide range of OCS-related development scenarios. The modular emission calculation procedure and the generic impact assessment provide for maximum flexibility in reassessing the emissions and impacts should ...

British Library Electronic Table of Contents (United Kingdom)

A Ni3Al coating was prepared by plasma spraying technique on the surface of titanium alloy. Ni-Al mixed powders, coatings and reaction products were investigated by scanning electron microscope, EDS, DSC and XRD. A tight bonding between the coating and the substrate was formed. The X-ray diffraction analysis of the patterns showed that the coating not only had Ni3Al phase, but also had NiO and Al2O3 phase microcontent. Comparing Ni coated Al to Ni3Al at 900^oC, the diffusion was stronger and the diffusion layer was thicker. A minute pore structure was formed at 1200^oC in the front edge of solid-state reaction layer. So Ni3Al restrained the solid-state reaction of the coating with the substrate, and as a whole weakened the entry of oxygen atoms into the substrate and quenched the out-diffu...

British Library Electronic Table of Contents (United Kingdom)

Ultra-fine ZnAl2O4 spinel hydrogel precursor synthesized from mixed salt solutions of Zn^2^+ and Al^3^+ ions using ammonium hydroxide-hexamethylenetetramine as basic media for co-precipitation was used as bonding material and sintering aid for pure alumina system. The hydrogel powder exhibited some well-defined ZnAl2O4 spinel phases at 800^oC. Alumina compacts were fabricated by incorporating small proportions of the precursor in alumina powder and firing at different temperatures (1350-1500^oC). The degree of densification was studied by measurement of fired shrinkage, apparent porosity, bulk density and cold crushing strength. Phase compositions and microstructural features of sintered samples were evaluated by XRD and SEM respectively. Addition of 0.2% hydrogel powder to alumina exhibit...

Energy Technology Data Exchange (ETDEWEB)

The relationship between coal properties and liquefaction or gasification characteristics was analyzed by using the analysis and test results and liquefaction characteristics in the coal data base. On liquefaction reaction, the close relation between an oil yield and coal constituent composition or a coal rank is well-known. Various multivariable regression analyses were conducted by using 6 factors as variables such as calorific value, volatile component, O/C and H/C atomic ratios, exinite+vitrinite content and vitrinite reflectance, and liquefaction characteristics as variate. On liquefaction characteristics, the oil yield of dehydrated and deashed coals, asphaltene yield, hydrogen consumption, produced water and gas quantities, and oil+asphaltene yield were predicted. The theoretical gasification efficiency of each specimen was calculated to evaluate the liquefaction reaction obtained. As a result, the oil yield increased with H/C atomic ratio, while the ...

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Aluminum-containing intergranular phases, forming intergranular films and secondary phase particles at triple-junctions in SiC hot-pressed with aluminum, boron, and carbon additions, were studied by transmission electron microscopy. Statistical high-resolution electron microscopy study of intergranular films indicated that a large fraction of the vitreous intergranular films in the s-hot-pressed SiC crystallized during postannealing in argon above 1000 C. However, brief heating to 1900 C indeed re-melted 25 percent of the crystallized intergranular films. The structural transitions were reflected in the statistical width distributions of the amorphous grain boundary layers. At triple-junctions, Al2O3, Al2OC-SiC solid solution, and mullite phases were newly identified. These phases,together with others reported before are represented in a quaternary phase diagram for 1900 C. It is proposed that a SiC-Al2OC liquid domain is to be included in this ...

Energy Technology Data Exchange (ETDEWEB)

This letter describes a new simple fabrication process, developed recently for blue response'' improvement in low-cost polycrystalline silicon solar cells. A selective emitter is created by heavily doping the emitter, followed by a wet etching-back of the cell area between the fingers. An improvement up to 17 mV in {ital V}{sub oc}, 1.5 mA/cm{sup 2} in {ital J}{sub sc}, and 1% (absolute value) in {eta} is obtained. Effective phosphorus gettering, self-alignment, and application in a low-cost full screenprinting technology are the main advantages of the proposed process.

Energy Technology Data Exchange (ETDEWEB)

We present the synthesis, magnetic and UV spectrometry of NiZn-ferrite nanofiber. The single phase of spinel ferrite was obtained at 600 {sup o}C. The NiZn-ferrite fibers fabricated by an electrospinning process were formed as a polygonal grain growth with firing temperature in fiber matrix. It appeared that the saturation magnetization (M{sub S}) of NiZn-ferrite nanofiber was dependent on Ni/Zn molar ratio which is similar to that of the inverse spinel ferrites. The NiZn-ferrite fibers showed good DNA adsorption efficiency that can be modified and utilized for DNA separation with magnetic nanofiber as a novel material in clinical applications.

International Nuclear Information System (INIS)

Unit one of Daya Bay, China's first nuclear power plant was officially opened in February 1994. The nuclear island has been built by Framatome and is an improved version of the Gravelines 5 and 6, 900MWe Pressurized Water Reactors. Extra seismic protection has been included because of greater earthquake risk. The heat exchanger capacity has also been increased as the sea cooling water can be at 30"oC. The technical specifications and details of the fuel loading are given. The technical assistance, management and training of Chinese personnel are discussed. Two further units may be built if Daya Bay 1 is successful. (UK).

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In this study attempts have been made to utilize biomass residues in a proper and efficient way. As a part of these attempts activated charcoal has been produced from coconut shell. The effects of temperature, time and impregnation ratio on activation and yield have also been studied. Experimental results show that higher temperature produces better activation but lower yield. The optimum values for activation time and impregnation ratio in producing activated charcoal were 50 min and 40%, respectively, at 600{sup o}C. (Author)

International Nuclear Information System (INIS)

The complex phase relationships near the BaO-poor region of the quaternary Ba-Sm-Y-Cu-O oxide system prepared in pure air (pO2=22 kPa, 950 oC) and in 0.1% O2 (pO2=100 Pa, 810 oC) have been determined. This investigation also included the subsolidus compatibilities in ten subsystems (Ba-Sm-Y-O, Ba-Sm-Cu-O, Ba-Y-Cu-O, Sm-Y-Cu-O, Ba-Sm-O, Ba-Y-O, Ba-Cu-O, Sm-Y-O, Sm-Cu-O, and Y-Cu-O), and the homogeneity range of five solid solutions (Ba(SmxY2-x)CuO5, (Sm,Y)2O3, (Sm,Y)2CuO4, (Y,Sm)2Cu2O5, and Ba(Sm,Y)2O4). The single phase range of the superconductor solid solution, (Ba2-xSmx)(Sm1-yYy)Cu3O6+z, and the phase compatibilities in its vicinity, which are particularly important for processing, are described in detail. The phase equilibrium data of the Ba-Sm-Y-Cu-O system will enable the improvement of the intrinsic superconducting properties of second-generation wires, and facilitate the flux-pinning process. -- Graphical Abstract: Phase diagram ...

Energy Technology Data Exchange (ETDEWEB)

Palmitic acid (PA, 59.8 {sup o}C) and lauric acid (LA, 42.6 {sup o}C) are phase change materials (PCM) having quite high melting temperatures which can limit their use in low temperature solar applications such as solar space heating and greenhouse heating. However, their melting temperatures can be tailored to appropriate value by preparing a eutectic mixture of the lauric and the palmitic acids. In the present study, the thermal analysis based on differential scanning calorimetry (DSC) technique shows that the mixture of 69.0 wt% LA and 31 wt% PA forms a eutectic mixture having melting temperature of 35.2 {sup o}C and the latent heat of fusion of 166.3 J g{sup -1}. This study also considers the experimental determination of the thermal characteristics of the eutectic mixture during the heat charging and discharging processes. Radial and axial temperature distribution, heat transfer coefficient between the heat transfer ...

International Nuclear Information System (INIS)

During the service in nuclear power plants, steam generator (SG) tubing will suffer from a vibration with a frequency from 30-40 Hz. This means that SG tubing will undergo a very high cycle fatigue process during the design life time (25 years=about 3x10"1"0cycles). The material degradation and the very high cycle fatigue life of SG tubing materials due to the vibration are therefore of concern. In this investigation, the fatigue properties of Alloy 690 and Alloy 800 SG tubing in the very high cycle fatigue regime (higher than 10"7 cycles) and strain controlled fatigue at temperatures up to 330"oC have been investigated. The fatigue properties of SG tubing of Alloy 690 are comparable to that of wrought material. The strain controlled fatigue properties of Alloy 690 and Alloy 800 are slightly better at 288"oC than at room temperature (RT). At the stress near the fatigue endurance, the influence of temperature on the high cycle fatigue properties ...

Energy Technology Data Exchange (ETDEWEB)

The present work mainly involves bench scale studies to investigate partitioning of mercury in pulverized fuel co-combustion at 1000 and 1300{sup o}C. High volatile bituminous coal is used as a reference case and chicken manure, olive residue, and B quality (demolition) wood are used as secondary fuels with 10 and 20% thermal shares. The combustion experiments are carried out in an entrained flow reactor with a fuel input of 7-8 kWth. Elemental and total gaseous mercury concentrations in the flue gas of the reactor are measured on-line, and ash is analyzed for particulate mercury along with other elemental and surface properties. Animal waste like chicken manure behaves very differently from plant waste. The higher chlorine contents of chicken manure cause higher ionic mercury concentrations whereas even with high unburnt carbon, particulate mercury reduces with increase in the chicken manure share. This might be a problem due to coarse fuel particles, low surface ...

International Nuclear Information System (INIS)

Bituminization has to be selected as the process for conditioning radioactive liquid wastes arising from the two VVER V-230 reactors being built at Temelin in the Czech Republic. In the process, a thin-film evaporator, operating at a waste-product temperature of 160"oC, evaporates all free water from the waste effluents. Remaining solids are homogeneously dispersed in a bitumen matrix which solidifies through natural cooling of the binder. The relative simplicity of the process reduces construction costs for on-line waste facilities and operating costs are less given the cheap basic material and simple maintenance. The reliability of the process has been demonstrated at Western reactors and reprocessing plants though adaptations have had to be made to accept VVER effluents. (UK).

International Nuclear Information System (INIS)

The effects of the heating rate from 0.6 up to 50"oC.s"-"1 on the thermoluminescence of #alpha#-Al_2O_3:C are very intensive. The material rapidly loses its high sensitivity as the heating rate increases. The peak shape characteristics, peak maximum and full width at half maximum agree only qualitatively with those theoretically predicted. The trapping parameters calculated by the curve fitting method, the peak shape method, the variable heating rate method and the initial rise method, were found to decrease as the heating rate increases. The validity of the results are discussed in the framework of the kinetic models. (author).

International Nuclear Information System (INIS)

Based on the Weinberg-Salam theory, the competition of the Neutrino Energy Loss (NEL) rates due to the pair, photo- and plasma process are canvassed. The ratio factor C1, C2 and C3 which correspond the different contributions of the pair, photo- and plasma neutrino process to those of the total NEL rates are accurately taken into account. The ratio factors are very sensitive to the temperature and density. The ratio factor C2 always is lower than the ratio factor C1 and C3. The pair NEL process is the dominant contribution before the crossed point O(C1=C3=0.45) and the plasma NEL process will be the main dominant contribution after the crossed point O. With increasing temperature, the crossed point O will move to the direction of higher density. (authors)

British Library Electronic Table of Contents (United Kingdom)

There are mainly two protocols in isoflavone analysis, one that involves hydrolysis prior to HPLC analysis and the other direct HPLC analysis. In this study, three different hydrolysis methods were systematically re-evaluated, and compared with direct HPLC analysis. Acidic hydrolysis (1.2-3M HCl in ethanol at 80^oC) showed a maximum conversion of ca. 92% from glucosides to aglycones in 2h; however, longer reaction caused degradation of genistein. Alkaline hydrolysis using 2M NaOH converted acetylglucosides and malonylglucosides to their respective glucosides within 10min. Glucuronidase from H. pomatia effectively converted isoflavone glucosides and acetylglucosides to aglycones. Quantification of the total isoflavones in various soy food products showed no significant difference among dire...

British Library Electronic Table of Contents (United Kingdom)

The physicochemical properties of binary lipid mixtures of diether C25,25 lipids and dipalmitoyl-L-a-phosphatidylcholine (DPPC) were studied using photon correlation, fluorescence and electron paramagnetic resonance spectroscopy, and transmission electron microscopy. These two types of lipids can be mixed at all molar ratios to form unilamellar and multilamellar liposomes. Fluorescence anisotropy of 1,6-diphenyl-1,3,5-hexatrien in mixed liposomes indicates that the abrupt changes in order parameter in the hydrophobic part of bilayer membranes made of DPPC lipids disappears with increasing mol%C25,25 lipids. Electron paramagnetic resonance spectroscopy shows that at temperatures below 50^oC, the interfacial regions of membrane bilayer of mixed liposomes is more fluid than for pure DPPC lipo...

British Library Electronic Table of Contents (United Kingdom)

We present a novel fabrication route yielding Raney-platinum film electrodes intended as glucose oxidation anodes for potentially implantable fuel cells. Fabrication roots on thermal alloying of an extractable metal with bulk platinum at 200^oC for 48h. In contrast to earlier works using carcinogenic nickel, we employ zinc as potentially biocompatible alloying partner. Microstructure analysis indicates that after removal of extractable zinc the porous Raney-platinum film (roughness factor ~2700) consists predominantly of the Pt3Zn phase. Release of zinc during electrode operation can be expected to have no significant effect on physiological normal levels in blood and serum, which promises good biocompatibility. In contrast to previous anodes based on hydrogel-bound catalyst particles the ...

Energy Technology Data Exchange (ETDEWEB)

This paper presents the design, development and performance characteristics of a low cost solar steam generating system which incorporates recent design and materials innovations of parabolic dish technology. The concentrator is a deep dish of rather imperfect optics, made of silvered polymer reflectors fitted in the aluminum frame of a satellite communication dish. Conventional cavity receivers tend to be inadequate for this concentrator. Semi-cavity and modified cavity receivers, thermally optimised, with the fuzzy focal image have, therefore, been investigated. Preliminary field measurements and cost, as well as performance analyses of the system, indicate a solar to steam conversion efficiency of 70-80% at 450{sup o}C and a collector system cost of Rs 8000-9000/m{sup 2} (1 US dollar = Rs, 40.0). (author)

Energy Technology Data Exchange (ETDEWEB)

The microstructure evolution of nine samples from three Ir-base ternary systems, Ir-Nb-Hf, Ir-Nb-Ta, and Ir-Nb-Ti, was investigated by microstructure observation using scanning electron microscopy (SEM), composition map-analysis using electron probe microscopy analysis (EPMA), and phase determination using X-ray diffraction (XRD) patterns. The fcc/L1{sub 2} two-phase structure was detected in all the samples. Lattice misfits between fcc and L1{sub 2} phases were calculated. Ir-Nb-Ta and Ir-Nb-Ti alloys exhibited a microstructure quite similar to that of Ni-base superalloys, and the cuboidal L1{sub 2} precipitates in Ir-Nb-Ta and Ir-Nb-Ti alloys could maintain up to 1900 {sup o}C.

British Library Electronic Table of Contents (United Kingdom)

In this study structural and magnetic character of the expanded austenite phase (gN) layer formed on a medical grade CoCrMo alloy by a low-pressure Radio-Frequency plasma nitriding process was investigated. The formation of the expanded austenite phase is facilitated at a substrate temperature near 400^oC for 1, 2, 4, 6 and 20h under a gas mixture of 60% N2-40% H2. The magnetic state of the gN layers was determined by a surface sensitive technique, magneto-optic Kerr effect (MOKE), and with a scanning probe microscope in magnetic force mode (MFM). Strong evidence for the ferromagnetic nature of the gN-(Co,Cr,Mo) phase is provided by the observation of stripe domain structures and the hysteresis loops. The ferromagnetic state for the gN phase observed here is mainly linked to large lattice ...

International Nuclear Information System (INIS)

This paper studies the effect upon the thermoluminescence (TL) signal of four feldspar samples of exposing them to infrared stimulation, as occurs during infrared-stimulated luminescence (IRSL) measurement. Together with pulse annealing measurements these results are used to show which part of the TL signal is removed by exposure to IR and which part is directly related to the IRSL signal that is observed. When the samples are preheated prior to measurement in order to remove any low-temperature (< 200"oC) TL signals, a linear relationship is observed between the amount of TL that is lost and the IRSL light sum that is produced. The IRSL light sum is consistently four times larger than the amount of TL that is lost. Three possible explanations are proposed for this, but no conclusive evidence could be obtained to support any of them. A close similarity is observed in the pulse annealing results and the loss of TL due to IR exposure of the four samples. (author).

British Library Electronic Table of Contents (United Kingdom)

Background: The environment preferred by Acanthamoeba trophozoites and the mechanism by which the amebae enters the cornea are not yet fully understood. A better understanding of the pathogenesis of this disease may help with prevention and treatment. Purpose: To define the preferred environments for Acanthamoeba survival and proliferation in vitro by examining the effect of tonicity, nutrient concentration, and free chlorine content on Acanthamoeba. Materials and methods: Human corneal isolates of Acanthamoeba castellanii and Acanthamoeba polyphaga trophozoites were cultured at 22^oC (room temperature) in PYG (peptone-yeast extract-glucose) medium. The effect of tonicity on amebae was determined by incubating trophozoites in sodium chloride solutions in concentrations ranging from 0% to 1...

British Library Electronic Table of Contents (United Kingdom)

The transformation of ferrihydrite to siderite (FeCO3) in the presence of supercritical CO2 (scCO2) and aqueous sulfide has been investigated by in situ attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) and ex situ X-ray diffraction (XRD). The chemical transformation of iron-bearing minerals to form iron carbonates may play a role in the chemistry related to the geological sequestration of carbon dioxide in the Earth's (sub)surface. The iron oxyhydroxide ferrihydrite in an aqueous solution containing sodium sulfide in contact with scCO2 at 100^oC reacts within 24h to form siderite and elemental sulfur. In situ studies of this reaction with ATR-FTIR show that ferrihydrite exists with an adsorbed layer of carbonate. However, the presence of the carbonate adsorbat...

Energy Technology Data Exchange (ETDEWEB)

Development drilling from Chevron-operated Platform Hermosa, located on OCS-P 0316 of the Point Arguello field, began on January 30, 1987. To date, seven development wells have been drilled in to the northwest-southeast-trending, doubly plunging anticlinal structure. The results from drilling have confirmed the presence of intense folding and fracturing in the targeted Monterey Formation. Over 700 ft of conventional core were recovered from the B-2 well in the lower Sisquoc and Monterey Formations. Analysis of the core material has yielded important information on lithologic variations and fracture patterns in the productive Monterey Formation. Initial results of core studies, DST data, and wireline studies indicate a correlation between rock type and fracturing. Fracture trends and directional permeability suggested by drill-stem testing may affect future drilling patterns in the field.

International Nuclear Information System (INIS)

Alloy 800 and Alloy 600 are well known for their resistance to corrosion in an aqueous medium at high pressure and temperature, for which they have been widely used for more than 3 decades in different structural components of water refrigerated nuclear reactors, especially as material for the steam generator tubes (SG) in these nuclear plants. The SG tubes in the Atucha I and Embalse Nuclear Plants are made with Alloy 800. The speed of corrosion of these materials in a reactor's refrigerant medium, while very small is perfectly measurable and can be described by parabolic or logarithmic type kinetics. In other words this speed is high in the first states of growth during the formation of a protective oxide film but then drops to almost stationary values. One characteristic of these films is the formation of a double layer (or duplex): i) an internal adhering layer, of approximately constant thickness, formed by small microcrystals (#<=#0.05 mm), ii) a less adhering external one, ...

British Library Electronic Table of Contents (United Kingdom)

Functional properties of commercial and membrane processed pea protein isolates (PPI) prepared from yellow peas were investigated. Four protein isolates were prepared from yellow pea flour using water and KCl extractions at 25^oC followed by ultrafiltration and diafiltration (UF and DF) at pHs of 7.5 and 7.5 or 6 respectively. Following assessment of compositional attributes; solubility, foaming, flow and dynamic rheology, emulsification ability and heat-induced textural and rheological properties of prepared PPIs and a commercially available PPI were tested and compared. Membrane purification of proteins resulted in 28% to 68% reduction in phytic acid and enhanced, comparatively, the tested functional properties. Solubility of membrane processed PPIs, at all tested pHs, was superior and t...

British Library Electronic Table of Contents (United Kingdom)

Carbon monoxide (CO) and carbon dioxide (CO2) emissions during a spontaneous heating event in a coal mine are important gases to monitor for detecting the spontaneous heating at an early stage. However, in underground coal mines, the CO and CO2 concentrations and their related fire ratios may be affected by mine ventilation. In this study, CO and CO2 emissions from spontaneous heating of a U.S. coal sample were evaluated in an isothermal oven under different airflow ventilation rates ranging from 100 to 500cm^3/min. Laboratory experiments were conducted at oven temperatures of 70, 90, and 100^oC. The temperature at the center of the coal sample was continually monitored, while the CO, CO2, and oxygen (O2) concentrations of the exit gas were continually measured. The results indicate that C...

Energy Technology Data Exchange (ETDEWEB)

Conversion of biomass into producer gas by thermal gasification broadens the scope of biomass applications. Usually, tar has to be removed from the producer gas. Tar recycling within the gasification process may solve the associated waste problem and increase the system efficiency, provided tar is broken down under gasification conditions. We present results of tar recycling experiments at a Circulating Fluidised Bed gasifier. At 830{sup o}C, from each of 15 main tar compounds 70-80% are broken down. Continuous recycling of tar would increase the tar content in raw producer gas by 50% at most and save about 3% fuel input. 10 refs., 3 figs., 3 tabs.

British Library Electronic Table of Contents (United Kingdom)

Determination of the radiocarbon (14C) content of airborne particulate matter yields insight into the proportion of the carbonaceous material derived from fossil and contemporary carbon sources. Daily samples of PM2.5 were collected by high-volume sampler at an urban background site in Birmingham, UK, and the fraction of 14C in both the total carbon, and in the organic and elemental carbon fractions, determined by two-stage combustion to CO2, graphitisation and quantification by accelerator mass spectrometry. OC and EC content was also determined by Sunset Analyzer. The mean fraction contemporary TC in the PM2.5 samples was 0.50 (range 0.27-0.66, n=26). There was no seasonality to the data, but there was a positive trend between fraction contemporary TC and magnitude of SOC/TC ratio and fo...

British Library Electronic Table of Contents (United Kingdom)

Pyogenic sacroiliitis is a rare entity in children. Diagnosis is often delayed because of its variable clinical presentation, low suspicion by the examining physician, and rare findings on radiographs. Delayed diagnosis, however, results in complications such as iliopsoas abscess. We report the case of a 12-year-old girl hospitalized with a 21-day history of fever, pain in the left iliac fossa, and flexion contracture of the hip. On examination, she had fever (38.9 ^oC), psoitis, localized tenderness at the left sacroiliac joint, and pain elicited by lateral compression of the pelvis. The abdominal examination was normal. The erythrocyte sedimentation rate was 130mm in the first hour, C-reactive protein was 186mg/l, and the white blood cell count was 18,400/mm^3, with 79% neutrophils. Urin...

Energy Technology Data Exchange (ETDEWEB)

An exergoeconomic model of a vertical ground-source heat pump residential heating system presented in this study uses exergy and cost energy mass (EXCEM) methods. The data obtained from a ground-source heat pump (GSHP) residential heating system installed at the Solar Energy Institute, Ege University, Turkey, are utilized for calculations at different reference temperature values in the range 0-25{sup o}C. The performance of the geothermal heat pump residential heating system is evaluated to indicate how exergoeconomic parameter values change with system. We also undertake a parametric study to investigate how varying reference temperatures will affect the exergoeconomic analysis of the GSHP system. A correlation between the ratio of thermodynamic loss rate to capital cost and reference state temperature is developed. (author)

Energy Technology Data Exchange (ETDEWEB)

Thermal energy storage performance of fatty acids and a eutectic mixture as phase change materials (PCMs) has been investigated experimentally. The selected PCMs for this study were palmitic acid, myristic acid, stearic acid, and a mixture of stearic and myristic acids in eutectic combination ratio of 65.7 wt% myristic acid and 34.3 wt% stearic acid. The PCMs have a melting temperature range of 50.0{sup o}C to 61.20{sup o}C and a latent heat range of 162.0 J/g to 204.5 J/g. The inlet temperature and the mass flow rate of heat transfer fluid (HTF) were selected as experimental parameters to test the thermal energy storage performance of the PCMs. The transition times, temperature range, propagation of the solid-liquid interface, as well as heat flow rate characteristics of the employed cylindrical tube storage system were studied at varied experimental parameters. The experimental results show that the melting front moves to inward in the radial ...

Energy Technology Data Exchange (ETDEWEB)

To prepare porous carbons with high adsorption capacity from rice straws, two different kinds of precursors, i.e. one as the raw rice straws (one-stage process) and the other as pre-carbonized rice straws (two-stage process), were active with KOH of various impregnation ratios. The two-stage process was found very effective for manufacturing porous carbons with high surface area and adsorption capacities for MB and I{sub 2}. For example, the porous carbon that was carbonized at 700{sup o}C and subsequently activated at 900{sup o}C exhibited the surface area of 2410 m{sup 2}/g, the adsorption capacities of 800 and 1720 mg/g for MB and I{sub 2}, respectively, and the total pore volume of 1.4 ml/g. In the two-stage method, there was a preferential optimum impregnation ratio of KOH to a precursor carbon, i.e. 4:1, with which high surface area of porous carbons could be achieved. The formation of uni- and bidentate carboxylic salt structure, induced ...

Energy Technology Data Exchange (ETDEWEB)

The carbon dioxide capture potential of amine amino acid salts (AAAS), formed by mixing equinormal amounts of amino acids; e.g. glycine. B-alanine and sarcosine, with an organic base; 3-(methylamino)propylamine (MAPA), was assessed by comparison with monoethanolamine (MEA), and with amino acid salt (AAS) from amino acid neutralized with an inorganic base; potassium hydroxide (KOH). Carbon dioxide absorption and desorption experiments were carried out on the solvent systems at 40{sup o}C and 80{sup o}C respectively. Experimental results showed that amine amino acid salts have similar CO{sub 2} absorption properties to MEA of the same concentration. They also showed good signs of stability during the experiments. Amino acid salt from an inorganic base, KOH, showed lower performance in CO{sub 2} absorption than the amine amino acid salts (AAAS) mainly due to a lower equilibrium temperature sensitivity. AAAS showed better performance than MEA of ...

Energy Technology Data Exchange (ETDEWEB)

Activated carbons (ACs) were prepared from chicken waste (CW) and coal (E-coal) blended at the ratios of 100:0, 80:20, 50:50, 20:80, and 0:100. The process included carbonization in flowing gaseous nitrogen (300 mL min{sup -1}) at ca. 430{sup o}C for 60 min and successive steam activation (0.1 mL min{sup -1} water injection with a flow of N{sub 2} at 100 mL min{sup -1}) at 650{sup o}C for 30 min. Chicken waste is low in sulfur content but is high in volatile matter (about 55 wt %), and ACs with higher specific surface area were more successfully obtained by mixing with coal. The specific surface area of the CW/Coal blend AC can be estimated by SSA{sub BET} = -65.8x{sup 2} + 158x + 168, where SSA{sub BET} is the specific surface area in m{sup 2} g{sup -1} as determined by the BET method using CO{sub 2} as the adsorbent, where x is the coal fraction by weight in the CW/coal blend ranging from 0.0 to 1.0 (e.g., x = 0.0 signifies the blend contains ...

Energy Technology Data Exchange (ETDEWEB)

CeO{sub 2}-TiO{sub 2} catalysts are prepared by coprecipitation method, and the activity and stability in the catalytic wet air oxidation (CWAO) of phenol are investigated in a batch reactor and packed-bed reactor. CeO{sub 2}-TiO{sub 2} mixed oxides show the higher activity than pure CeO{sub 2} and TiO{sub 2}, and CeO{sub 2}-TiO{sub 2} 1/1 catalyst displays the highest activity in the CWAO of phenol. In a batch reactor, COD and TOC removals are about 100% and 77% after 120 min in the CWAO of phenol over CeO{sub 2}-TiO{sub 2} 1/1 catalyst at reaction temperature of 150 {sup o}C, the total pressure of 3 MPa, phenol concentration of 1000 mg/L, and catalyst dosage of 4 g/L. In a packed-bed reactor using CeO{sub 2}-TiO{sub 2} 1/1 particle catalyst, over 91% COD and 80% TOC removals are obtained at the reaction temperature of 140 {sup o}C, the air total pressure of 3.5 MPa, the phenol concentration of 1000 mg/L for 100 h continue reaction. Leaching ...

Energy Technology Data Exchange (ETDEWEB)

Many commercial processes for the removal of carbon dioxide from high-pressure gases use aqueous potassium carbonate systems promoted by secondary amines. This paper presents thermodynamic and kinetic data for aqueous potassium carbonate promoted by piperazine. Research has been performed at typical absorber conditions for the removal of CO{sub 2} from flue gas. Piperazine, used as an additive in 20-30 wt% potassium carbonate, was investigated in a wetted-wall column using a concentration of 0.6 m at 40-80{sup o}C. The addition of 0.6 m piperazine to a 20 wt% potassium carbonate system decreases the CO{sub 2} equilibrium partial pressure by approximately 85% at intermediate CO{sub 2} loading. The distribution of piperazine species in the solution was determined by proton NMR. Using the speciation data and relevant equilibrium constants, a model was developed to predict system speciation and equilibrium. The addition of 0.6 m piperazine to 20 wt% potassium carbonate ...

Energy Technology Data Exchange (ETDEWEB)

A novel, obligately anaerobic, extremely thermophilic, cellulolytic bacterium, designated OB47T, was isolated from Obsidian Pool, Yellowstone National Park, WY, USA. The isolate was a non-motile, non-spore forming, Gram-positive rod approximately 2 m long by 0.2 m wide and grew at temperatures between 55-85oC with the optimum at 78oC. The pH range for growth was 6.0-8.0 with values of near 7.0 being optimal. Growth on cellobiose produced the fastest specific growth rates at 0.75 hr-1. The organism also displayed fermentative growth on glucose, maltose, arabinose, fructose, starch, lactose, mannose, sucrose, galactose, xylose, arabinogalactan, Avicel, xylan, filter paper, processed cardboard, pectin, dilute acid-pretreated switchgrass and Populus. OB47T was unable to grow on mannitol, fucose, lignin, Gelrite, acetate, glycerol, ribose, sorbital, carboxymethylcellulose and casein. Yeast extract stimulated growth and thiosulfate, sulfate, nitrate, ...

Science.gov (United States)

Silicon carbide (SiC) based electronic devices are of great importance for applications under the condition of high temperature, high power and high radiation. Schottky diodes of Palladium/SiC are good candidates for hydrogen and hydrocarbon gas sensors at elevated temperature. The detection sensibility of the diodes has been found heavily temperature dependent. In this work, the electrical and chemical properties of Pd/SiC Schottky contacts were studied by XPS and AES at different annealing temperatures. Schottky diodes were made by depositing ultra-thin palladium films onto a silicon carbide substrate. No significant change in the Schottky barrier height of the Pd/SiC contact was found in the temperature range of 300-673K. Palladium diffusion into SiC and the formation of palladium silicides were observed at room temperature and became significant at 300^oC and higher temperature. The mechanism of diffusion and reaction at the Pd/SiC interface will be discussed. ...

Energy Technology Data Exchange (ETDEWEB)

The study was directed towards determining the usability of clay and fine wastes (CW and FW) of boron from the concentrator plant in Kirka (Turkey) as a fluxing agent in production of red mud (RM) brick. Both laboratory studies on the characterization of materials and industrial-scale tests for production of bricks were carried out. CW and FW, which have similar chemical composition but include different types and amounts of oxides, were added in amounts of 5, 10 and 15wt% to RM, which consists of high amounts of Fe{sub 2}O{sub 3}, Al{sub 2}O{sub 3}, SiO{sub 2} and alkalies. Six different sets of samples have been produced and fired at 700, 800 and 900{sup o}C. Dry shrinkage of green body, bending and compressive strength, firing shrinkage, water absorption, frost resistance and harmful magnesia and lime tests on heat-treated bodies have been performed. The mineralogical and mechanical tests showed that usability of boron wastes as a fluxing agent in the production ...

Energy Technology Data Exchange (ETDEWEB)

By increasing the price of crude oil and natural gas and the decline in their stock a possibility of more intense use of coal reserves as a feedstock not only for energy purposes but also as a feedstock source for other industries, mainly chemical and steel industry, is opening up. At present brown coal exploited in the Czech Republic is explicitly burned in the power sources of various outputs. Coal pyrolysis under the defined conditions may be an outstanding way of non-energetic brown coal processing. The target of our work was to determine the behaviour of various types of brown coal from the North Bohemian Basin under the pyrolysis up to the temperature 750{sup o}C. At the same time, qualitative parameters of the pyrolysis products in dependence on the features of the input brown coal were observed. Various types of brown coal were used for the pyrolysis tests differing mainly in the content of ash, sulphur and tar. Within the work mass balances of the incurred ...

Energy Technology Data Exchange (ETDEWEB)

The purpose of this study is to determine the thermal reliability of stearic acid, palmitic acid, myristic acid and lauric acid as latent heat energy storage materials with respect to various numbers of thermal cycles. The fatty acids, as phase change materials (PCMs), of industrial grade (purity between 90% and 97%) were subjected to accelerated thermal cycle tests. The differential scanning calorimetry (DSC) analysis technique was applied to the PCMs after 0, 120, 560, 850 and 1200 melt/freeze cycles in order to measure the melting temperatures and the latent heats of fusion of the PCMs. The DSC results indicated that the change in melting temperature for the PCMs was in the range of 0.07-7.87 {sup o}C, and the change in latent heat of fusion was -1.0% to -27.7%, except for stearic acid between 560 and 1200 melt/freeze cycles. However, the decrease in the latent heats of fusion for all the PCMs was not regular with increasing thermal cycles. The experimental ...

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Orujillo, sometimes called wood matter from pressed oil-stone (WPOS) is a residue from the olive oil mill industry. The generation of this biomass residue is concentrated in small areas allowing its use as fuel for medium size gasification and combustion plants. Rates of gasification of WPOS char were measured in a TGA at various temperatures (800-850-875-900-950{sup o}C), CO{sub 2} partial pressures (0.20-0.35-0.50 bar) and CO partial pressures (0.0-0.20 bar). The experiments were carried out with a monolayer bed of very fine particles well exposed to the gas so as to minimise mass and heat transfer resistances. Two kinetic models, the nth order model and Langmuir-Hinshelwood model, have been used to fit with the reactivity data. For pure CO{sub 2} experiments the kinetic parameters of nth order model were E=133 kJ/mol and n=0.43. The Langmuir-Hinshelwood kinetic model clearly describes the observed CO inhibition effect on the CO{sub 2} gasification.(author)

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Carbon nanofiber (CNF) supported cobalt oxide composites as high-capacity anode materials were prepared through a facile, effective method for potential use in rechargeable lithium-ion batteries. The effects of the calcining temperature on the crystallinity, grain size, specific surface area of Co{sub 3}O{sub 4} and phase transformation from Co{sub 3}O{sub 4} to CoO were studied in detail. Both the specific surface area and CNF content in CNF-cobalt oxide composites strongly affect the electrochemical performance of these series composites. The CNF-Co{sub 3}O{sub 4} composite with 24.3% CNF pyrolyzed at 500{sup o}C in Ar shows an excellent cycling performance, retaining a specific capacity of 881 mAh g{sup -1} beyond 100 cycles. Homogeneous deposition and distribution of nanosized Co{sub 3}O{sub 4} particles on the surface of CNF can stabilize the electronic and ionic conductivity as well as the morphology of Co{sub 3}O{sub 4} phase, which may be the main reason ...

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A series of experiments were carried out to examine the resistant capacity of a chemically treated hard wood, Anthocephalus cadamba (Roxb) Miq. to thermal and termite degradation. The treatment with thermosetting resins viz. urea formaldehyde (UF), melamine formaldehyde (MF) and phenol formaldehyde (PF) at 31-33 levels of weight percent gain (WPG) increased the strength property i.e. modulus of rupture (MOR) by 7.50-21.02% and stiffness i.e. modulus of elasticity (MOE) by 9.50-12.18% over the untreated one with no remarkable effect on specific gravity. The treated samples were found resistant to termite attack, while the untreated one was badly damaged by termites on 12 months' exposure to a termite colony. The thermal degradations of untreated and treated wood samples were studied using thermogravimetric (TGA) and differential thermogravimetric (DTG) techniques at heating rates 20 and 30 {sup o}Cmin{sup -1} in temperature range 30-650{sup o}C. The treated ...

British Library Electronic Table of Contents (United Kingdom)

TaC-4wt.% CNT composites were synthesized using spark plasma sintering. Two kinds of CNTs, having long (10-20mm) and short (1-3mm) length, were dispersed by wet chemistry and spray drying techniques respectively. Spark plasma sintering was carried out at 1850^oC at pressures of 100, 255 and 363MPa. Addition of CNTs leads to an increase in the density of 100MPa sample from 89% to 95%. Short CNTs are more effective in increasing the density of the composites whereas long CNTs are more effective grain growth inhibitors. The longer CNTs are more effective in increasing the fracture toughness and an increase up to 60% was observed for 363MPa sample. Hardness and elastic modulus are found to increase by 22% and 18% respectively for 100MPa samples by addition of long CNTs. Raman spectroscopy, SEM...

Energy Technology Data Exchange (ETDEWEB)

The feasibility of using three different solid fuels in chemical-looping combustion (CLC) has been investigated using NiO as oxygen carrier. A laboratory fluidized-bed reactor system for solid fuel was used, simulating a chemical-looping combustion system by exposing the sample to alternating reducing and oxidizing conditions. In each reducing phase 0.2g of fuel was added to the reactor containing 20g oxygen carrier. The experiments were performed at 970{sup o}C. Compared to previously published results with other oxygen carriers the reactivity of the used Ni-particles was considerably lower for the high-sulphur fuel and higher for the low-sulphur fuel. Much more unconverted CO was released and the fuel conversion was much slower for high-sulphur fuel such as petroleum coke, suggesting that the nickel-based oxygen carrier was deactivated by the presence of sulphur. The NiO particles also showed good reactivity with methane and a syngas mixture of 50% H{sub 2} and ...

International Nuclear Information System (INIS)

In this study, SnO2 thin films have been grown using spray pyrolysis technique on glass substrates under a substrate temperature (Ts = 440 oC). The precursors were methanol CH4O and anhydrous tin tetrachloride. XRD analyses yielded strong (1 1 0)-(1 0 1)-(2 0 0) X-ray diffraction peaks which are characteristics to tetragonal crystals. Atomic Force Microscopy (AFM) analyses showed the existence of clusters with particular pyramidal shapes. The main part of this study concerns the optical measurements of transmittance T(?) and reflectance R(?) spectra inside 250-1800 nm domain. Conjoint optical and thermal properties were deduced using the Amlouk-Boubaker Opto-Thermal Expansivity ?AB. The obtained value: ?AB ? 23.4 m3 s-1 helped situating the performance of the as-grown SnO2 compound among most known PV-T oxides like ZnO and TiO2.

British Library Electronic Table of Contents (United Kingdom)

Solid-state fermentation of soybean hulls supplemented with wheat bran using a co-culture of Trichoderma reesei and Aspergillus oryzae was performed. Three parameters - initial moisture content, incubation temperature, and initial pH - were optimized in culture flasks using response surface methodology. Parameter optimization was carried out with respect to filter paper activity and b-glucosidase activity in the culture. Temperature of 30^oC, pH of 5, and moisture content of 70% were found to be optimum. Optimized parameters were used for laboratory scale-up in static tray fermenters. The maximum filter paper activity of 10.7FPU/g-ds and b-glucosidase of 10.7IU/g-ds were obtained after 96-h incubation period in static tray fermenters in agreement with optimized activities at shake flask le...

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The CaWO{sub 4}:Ln{sup 3+} SiO{sub 2} (Ln=Tb, Dy and Ho) nanoparticles were synthesized via a combustion process at 800 {sup o}C, using citric acid as chelating agent and fuel, ammonium nitrate as fuel, boric acid as flux material and silica as supports. The persistent phosphor nanoparticles were characterized by X-ray diffraction (XRD), reflectance UV-vis and fluorescence spectroscopy (PL) and transmission electron microscopy (TEM) techniques. XRD patterns indicated that crystalline calcium tungstate with scheelite structure was produced. The reflectance UV-vis spectra showed the broad absorption band of WO{sub 4}{sup 2-} groups and the PL spectra showed the WO{sub 4}{sup 2-} wide excitation band, broad emission band of WO{sub 4}{sup 2-} and characteristic emissions of Ln{sup 3+} ions. The average particle sizes were determined by TEM, which are about 50 nm.

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This paper discusses the potential for geothermal energy use in the central part of Southern Poland, such as the availability of thermal aquifers and the techniques for putting the latter to practical use. The geological and geothermal features of the region are presented within the context of the existence of aquifers containing geothermal resources that could be used in space heating. Also discussed are the three main geological units where thermal waters are known to exist: the Carpathians, the Miechow Trough, and the Silesian-Cracow Monocline. Particularly favourable hydrogeological conditions exist in the Inner Carpathians, in the Podhale Trough, where there is already one geothermal company using geothermal energy, Geotermia Podhalanska S.A. Equally interesting from the geothermal point of view are the areas north of the Cracow-Tarnow line, where, in Mesozoic aquifers, water temperatures range from 20 to 60 {sup o}C. In this paper we propose technological ...

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This paper presents the performance analysis on a hybrid air-conditioning system according to the hybrid building energy system of the green building demonstration project in Shanghai, in which a 150 m{sup 2} solar collector is used to power two 10 kW adsorption chillers, a vapor compression heat pump is used to cool air in the evaporating end while the condensing heating at about 80{sup o}C is fully used to regenerate a liquid desiccant dehumidification system. In the hybrid system, the sensible cooling to the air is treated mainly by solar adsorption cooling and vapor compression cooling, whereas the latent heat is treated by the liquid desiccant dehumidification system with regeneration from the condensing heat of the heat pump. The results show that the performance of this system is 44.5% higher than conventional vapor compression system at a latent load of 30% and this improving can be achieved by 73.8% at a 42% latent load. The optimal ratio of adsorption ...

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Panel cooling of buildings offers energy savings over conventional space-cooling systems. We present a procedure for calculating the performance of H[sub 2]O-LiBr absorption-panel cooling systems, in which the evaporator is the panel itself. Nomographs have been developed for this approach. Under the conditions examined, the H[sub 2]O-LiBr absorption unit operates with a theoretical performance coefficient of about 90% and with a practically constant specific cooling capacity of 2394 kJ/kg H[sub 2]O. For common values of the parameters involved, the panel cooling power varies from 25 to 175 W/m[sup 2] and the cooling water mass-flow through the panel is 40-260 g/m[sup 2]h. The thermal power needed to drive the system varies from 27 to 200 W/m[sup 2] and the associated temperatures from 70 to 100[sup o]C; thus, the system may be operated on solar energy. (Author).

British Library Electronic Table of Contents (United Kingdom)

Herein, we report engineering of nanostructured p-CuIn3Se5/n-CdS heterojunction thin film on a glass substrate, which is prepared at room temperature using simple wet chemical approach involving ion exchange reactions between CdS and Cu^+, In^3^+ and Se^2^- ions in alkaline medium. The uniform deposition of heterojunction thin films is achieved by optimizing the pH, temperature and molarity of the reactant bath. The as-deposited thin-films were annealed at 200^oC in air for 1h and further characterized for structural, optical and electrical properties using UV-Vis spectrophotometer, X-ray diffraction (XRD), scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy (XPS), Hall effect for type of conductivity, and I-V measurement to investigate the char...

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Mullite long fibres, which are a candidate for high temperature applications were prepared by sol-gel method from water solvent systems. They were synthesized from three different combinations of raw materials as follows: (1):Al(O{sub 1}C{sub 3}H{sub 7}){sub 3}, Al-nitrate and Si(OC{sub 2}H{sub 5}){sub 4} (TEOS), (2):Al metal, Al-chloride and TEOS, (3):Al metal, Al-nitrate and TEOS. In the methods (1) and (2), very fine SiO{sub 2} aerosol particles were also used partially replacing TEOS. The prepared solutions were condensed and examined the spinability by a hand drawing method. Dense and crack free mullite fibres were prepared from the methods (1) and (3) by firing up to 1100 C. Whereas the fibres prepared from the method (2) were less SiO{sub 2} than mullite composition and were porous by the firing due to evaporation of residual Cl ions at high temperature. (orig.) 10 refs.

Energy Technology Data Exchange (ETDEWEB)

Graft copolymerization of sodium styrene sulfonate (SSS) onto electron beam (EB) irradiated poly(vinylidene fluoride) (PVDF) films was investigated to find out a simple preparation process for sulfonic acid proton exchange membranes with respect to monomer concentration, absorbed dose, temperature, film thickness and storage time. The reaction order of the monomer concentration and absorbed dose of grafting was found to be 2.84 and 1.20, respectively. The overall activation energy for graft copolymerization reaction was calculated to be 11.36 kJ/mol. The initial rate of grafting was found to decrease with an increase in the film thickness. The trapped radicals in the irradiated PVDF films remained effective in initiating the reaction without considerable loss in grafting level up to 180 days, when stored under -60 {sup o}C. The presence and distribution of polystyrene sulfonate grafts in the obtained membranes were observed by Fourier transform infrared (FTIR) ...

British Library Electronic Table of Contents (United Kingdom)

This study examined the oxygen permeation behavior of Ce0.9Gd0.1O2-d (Gadolinium-Doped Ceria, GDC)/Ba0.5Sr0.5Co0.8Fe0.2O3-d (BSCF) composite membranes fabricated using a conventional sintering technique. GDC/BSCF composite membranes with a relative density >95% could be obtained when a green compact of BSCF and GDC was sintered at 1150^oC for 5h. It appears that GDC serves as a grain growth inhibitor because the average grain size of the composite decreased with increasing GDC content. The oxygen permeability of the BSCF and GDC/BSCF composite membranes strongly depends on the grain size and membrane thickness. The addition of GDC to BSCF resulted in a small grain size, low thermal expansion coefficient and high hardness. However, it is believed that oxygen permeation was blocked by GDC, a...

Energy Technology Data Exchange (ETDEWEB)

Engineering materials for use in low heat rejection engines are required to function under stringent tribological conditions. Severe wear damage and high friction between the components of the tribosystem limit the number of potential materials suitable for such application conditions. The superalloys X-750 and 188 are composed of alloying elements that not only promote a high mechanical and chemical stability but may also result in a reduced wear rate and friction coefficient at elevated temperatures. As a part of the DOE-ECUT Tribology program at Argonne, the present study was undertaken to evaluate the tribological characteristics of these alloys that will also be utilized as the substrates for ion beam deposited lubricous coatings. A wear test rig that crudely simulated the sliding conditions between a piston ring and a cylinder liner in an operating engine was utilized for friction and wear studies. The test results indicated that the wear and friction properties of these alloys ...

International Nuclear Information System (INIS)

In the present paper it is assumed that above a limiting value of fission fluency (burn-up) a more intensive process of irradiation introduced chemical interaction occurs. A significant part of fission gas product is thus expected to be chemically bounded in the matrix of UO_2 fuel. The fission gas atoms substituting, for example, uranium atoms in the crystallographic lattice can form weak facets. At a certain saturation condition, division of the grains can occur at the weak facets and the increase in fission-gas products release may be expected. The fact that the process of grain division for high burn-ups (70-80 MWd/kgU) forms an extremely fine structure up to the temperature as high as 1100 "oC and simultaneously the observed decreases in fission gas concentration in the fuel supports this concept. The analysis of fission gas concentration change due to the formation of nanostructures in UO_2 fuel at high burn-ups in terms of total surface area change in a ...

International Nuclear Information System (INIS)

A common evaluation is given for creep crack growth and fatigue crack growth experiments which have been performed at the companies ABB, Siemens-KWU and KFA. The materials under investigation were X10NiCrAlTi32 20 (Alloy 800) and NiCr22Col2Mo (Alloy 617). Several production lots and semi-finished materials as well as welded materials have been tested. Testing techniques differed at the different labs. In order to eliminate the influence of individual testing techniques, material from some production lots was investigated at different labs. The given data cover fatigue crack growth (the materials were tested between room temperature and 1050"oC; the influence of temperature, R-ratio, and frequency was investigated) and creep crack growth (Alloy 800 was tested between 550sup(o)C and 900sup(o)C, Inconel 617 between 800sup(o)C and 1000sup(o)C; the evaluation was done on the basis of the fracture mechanics parameters Ksub(1) and Csup(*)). (Author).

International Nuclear Information System (INIS)

The 9.50 GHz electron paramagnetic resonance (EPR) spectra of unirradiated and "6"0Co #gamma#-ray irradiated cardamom (Elettaria cardamomum L. Maton, Zingiberaceae), ginger ((Zingiber officinale Rosc., Zingiberaceae), and saffron (Crocus sativus L., Iridaceae) have been investigated at room temperature. All unirradiated spices presented a weak resonance line with g-factors around free-electron ones. After #gamma#-ray irradiation at an absorbed dose of up to 11.3 kGy, the presence of EPR spectra whose amplitude increase monotonously with the absorbed dose has been noticed with all spices. A 100 "oC isothermal annealing of 11.3 kGy irradiated samples has shown a differential reduction of amplitude of various components that compose initial spectra, but even after 3.6 h of thermal treatment, the remaining amplitude represents no less then 30% of the initial ones. The same peculiarities have been noticed after 83 days storage at room temperature but after 340 days ...

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Dynamic behaviors of gaseous sulfur-containing compounds evolved from pyrolysis of six Chinese coals were studied in the temperature range of up to 800{sup o}C under N{sub 2} and H{sub 2}. The released amount of total sulfur-containing gases was traced by an online flame photometric detector (FPD). Simultaneously, the changes of different sulfur forms, including H{sub 2}S, SO{sub 2}, COS and CS{sub 2}, also were investigated using an online mass spectrometer (MS). FPD results show that the effect of H{sub 2} on gaseous sulfur evolved is complex, which promoted certain peak and suppresses other peaks. Based on the data from MS, it is suggested that a series of competitive reactions between active sulfur and other active matters during pyrolysis may impact on the sulfur form in gas phase. Interactions between active sulfur-containing intermediates and the coal matrix are attributed to be the main factor determining the dynamic behavior.

Energy Technology Data Exchange (ETDEWEB)

This report for the Swiss Federal Office of Energy (SFOE) describes the borehole that has been driven into the underlying crystalline rock of the Rhine valley near Basle. This work has been carried out within the framework of the 'Deep Heat Mining' project. The 2,755 metre deep borehole provides geological information essential for the realisation of a proposed geothermal power station using the 'Hot Dry Rock' process. The boring of the test borehole is described. The results obtained from samples taken from the test borehole and the measurements made in it are presented, including details on geological formations, temperature, gas measurements and rock strain values. The author is of the opinion that the chances of finding temperatures of at least 200 {sup o}C in a depth of 5 km - as foreseen in the 'Deep Heat Mining' project - can be considered as being quite high.

Energy Technology Data Exchange (ETDEWEB)

Jordan is an example of a third world country that is non-oil producing but contains huge reserves of other energy sources such as tar sand, oil shale, and olive cake. Some limited research is available about how to utilize these energy sources in pure form. However, available research does not deal with combinations of these energy sources. This experimental study investigates combinations of these energy forms as potential energy sources in Jordan. The experimental procedure involves characterization of samples by proximate analysis, calorific value determination of different combinations, and a compacting process of the different particles. The best combination, with respect to calorific value, is found to be 20% tar sand, 20% olive cake, and 60% oil shale. Compacting materials either with starch or with heated tar sand up to 110{sup o}C for 1 h indicates a feasible process for handling, packaging, and transporting. (author)

International Nuclear Information System (INIS)

Sr3In0.9Co1.1O6, isostructural to Ca3Co2O6, is revealed by the study of the phase relations in the system SrO-InO1.5-CoOx (1000 oC). The structure of Sr3In0.9Co1.1O6 is refined by the combination of powder X-ray and neutron diffraction. Sr3In0.9Co1.1O6 crystallizes in a trigonal lattice with the cell parameters a=b=9.59438(3) A, c=11.02172(4) A with the space group R-3c. Its structure possesses 1D (In/Co)O3 chains running along the c-axis constructed by alternating face-sharing CoO6 octahedra and (In0.9Co0.1)O6 trigonal prisms. The co-occupation of In3+ and Co3+ at the trigonal prismatic site is evidenced by elementary analysis and determined by the structure refinement. Sr3In0.9Co1.1O6 is paramagnetic, and the susceptibility is consistent with the occupation of Co3+ at 10% of the trigonal prismatic positions in a high spin state (HS, S=2). The HS Co3+ is well separated by diamagnetic CoO6 octahedra and InO6 trigonal prisms and shows a g factor of 2.0 in the ...

Energy Technology Data Exchange (ETDEWEB)

The absence of high-temperature electronics is an obstacle to the development of untapped energy resources (deep oil, gas and geothermal). US natural gas consumption is projected to grow from 22 trillion cubic feet per year (tcf) in 1999 to 34 tcf in 2020. Cumulatively this is 607 tcf of consumption by 2020, while recoverable reserves using current technology are 177 tcf. A significant portion of this shortfall may be met by tapping deep gas reservoirs. Tapping these reservoirs represents a significant technical challenge. At these depths, temperatures and pressures are very high and may require penetrating very hard rock. Logistics of supporting 6.1 km (20,000 ft) drill strings and the drilling processes are complex and expensive. At these depths up to 50% of the total drilling cost may be in the last 10% of the well depth. Thus, as wells go deeper it is increasingly important that drillers are able to monitor conditions down-hole such as temperature, pressure, heading, etc. ...

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Chemical-looping combustion is a two-stage process proposed as an alternative for the combustion of carbonaceous materials, such as natural gas or coal gas, for almost complete CO{sub 2} capture. In the reduction stage, the structural oxygen contained in the lattice of a reducible inorganic oxide, is used for combustion of the carbonaceous material. In the regeneration stage the oxygen carrier, found in a reduced state after the reduction stage, is regenerated with pure air to recover the physical and chemical properties of the carrier, ready to reinitiate a new cycle reduction-regeneration. In a typical multicycle reactor test, the carriers are subjected to accumulative chemical and thermal stresses and the performance will, probably, decay progressively with the number of cycles. The occurrence of some side reactions may limit the efficiency of the overall process in CO{sub 2} capture. In this paper, titania-supported iron oxides with different iron loadings have been tested in ...

Energy Technology Data Exchange (ETDEWEB)

The ternary zirconium palladium silicide ZrPd{sub 3}Si{sub 3} has been synthesized by arc-melting of the elemental components. It adopts a new structure type and crystallizes in the orthorhombic space group Cmcm with a = 3.8127(4){angstrom}, b = 15.551(1){angstrom}, c = 7.0390(5){angstrom}, and Z = 4 (Pearson symbol oC28). The structure can be regarded as being built up of Re{sub 3}B-type slabs of composition Pd{sub 3}Si alternating with {alpha}-FeSi{sub 2} slabs of composition ZrSi{sub 2}. Notable features include the presence of Si{sub 2} pairs, square pyramidal and tetrahedral coordination of Pd centers by Si atoms, an unusual distorted cubic coordination of the Zr atoms by the Si{sub 2} pairs, and an extensive network of Zr-Zr, Zr-Pd, and Pd-Pd metal-metal bonds. ZrPd{sub 3}Si{sub 3} is weakly metallic with a room-temperature resistivity of 1.7 x 10{sup {minus}3} {Omega} cm. Extended Hueckel band structure calculations confirm the metallic behavior; support the ...

Energy Technology Data Exchange (ETDEWEB)

The thesis relates to an investigation done on greenhouse gases in coniferous forest soils. The production of nitrous oxide (N{sub 2}O) and carbon dioxide (CO{sub 2}), and the consumption of methane (CH{sub 4}) in a temperate forest soil were studied by a rapid and sensitive gas chromatographic (GC) method for analysing all three greenhouse gases at or below ambient levels. Gas fluxes were measured in soil incubation and lysimeter experiments. 15 soil samples were taken at random within a 100 m{sup 2} area in a Norway spruce forest stand (Picea abies). The fluxes of N{sub 2}O, CH{sub 4} and CO{sub 2} were measured under standardized laboratory incubation conditions to investigate spatial variability in relation to other factors such as nitrogen (N) mineralization rate, nitrification rate, organic carbon (OC), total N and pH. The effects of temperature, soil moisture content, and ammonium addition were also studied in an incubation experiment. A more detailed study ...

Energy Technology Data Exchange (ETDEWEB)

The studies of {sup 137}Cs and {sup 239+240}Pu distributions in surface seawater at South China Sea within the Exclusive Economic Zone (EEZ) of Peninsular Malaysia were carried out in June 2008. The analysis results will serve as additional information to the expanded baseline data for Malaysia's marine environment. Thirty locations from extended study area were identified in the EEZ from which large volumes of surface seawater samples were collected. Different co-precipitation techniques were employed to concentrate cesium and plutonium separately. A known amount of {sup 134}Cs and {sup 242}Pu tracers were used as yield determinant. The precipitate slurry was collected and oven dried at 60 {sup o}C for 1-2 days. Cesium precipitate was fine-ground and counted using gamma-ray spectrometry system at 661.62 keV, while plutonium was separated from other radionuclides using anion exchange, electrodeposited and counted using alpha spectrometry. The activity ...

Energy Technology Data Exchange (ETDEWEB)

Aiming to understand the formation mechanism of dioxins in the iron ore sintering process, dust samples obtained from some windboxes of a commercial iron ore sintering plant have been characterized with a powder X-ray diffraction (XRD), by the transmission electron microscope (TEM) equipped with an electron energy loss spectroscopy (EELS), and by the temperature-programmed desorption (TPD) and temperature-programmed oxidation (TPO) techniques. The elemental and XRD analyses reveal that the content of the Cl present in the samples ranges from 0.075 mass%-dry to 5.1 mass%-dry and tends to be higher at smaller dust particles, and that some of the Cl exists as KCl with the average crystalline size between 40 nm and 50 nm. Dust samples also contain a significant amount of unburned carbon, and the smallest dust particles, < 500 {mu}m, show the highest C contents in many cases and consist partly of C, K, and Cl elements. The TPD and TPO experiments exhibit that the dust samples have ...

International Nuclear Information System (INIS)

Two new cyclopentadienyl piperidine derivatives, namely ferrocene carboxylic acid 1-ethyl-3-hydroxypiperidinyl ester and ferrocene carboxylic acid 4-hydroxypiperidinyl ester, were synthesized. The ligands were then radiolabelled with "9"9"mTc using two different approaches. The first method consisted of reacting the ligand precursor with Mn(CO)_5Br in pertechnetate "9"9"mTcO_4 - in normal saline and dimethyl formamide (DMF) at 150 "oC for 1 h. The yields were 70% and 90%, respectively. For the second method, the reactions mixtures were placed in a microwave oven for 2 min at 650 watt. The yields were higher than 90% for both "9"9"mTc complexes. Biodistribution studies showed that tricarbonyl[#eta#"5-[carboxy-3-hydroxy(N-ethyl)piperidine]cyclopentadienyl] technetium(I) had the highest brain uptake. The regional distribution in the brain also demonstrated relatively higher uptake of tricarbonyl [#eta#"5-[carboxy-3-hydroxy(N-ethyl) piperidine]cyclopentadienyl] ...

Energy Technology Data Exchange (ETDEWEB)

We report the performance of a commercial recuperated micro gas turbine on biomass producer gas and mixtures of biomass producer gas with natural gas. The biomass producer gas, obtained by gasification at 850{sup o}C with air at atmospheric pressure, contains about 7% H2, 17% CO, 15% CO2, 4% CH4, 2% other hydrocarbons, 2% H2O, and a balance of N2 and Ar from air. It has a net heating value of about 6 MJ/(Nm{sup 3}). The micro gas turbine delivers full power (30 kW{sub e}) on gas mixtures with a net heating value of at least 15 MJ/(Nm{sup 3}). For gas of lower heating value, the maximum fuel gas flow allowed by the fuel control unit limits the attainable power. At reduced power, the lower limit for stable operation is a net heating value of about 8 MJ/(Nm{sup 3}). The gross efficiency of the micro gas turbine depends on the output power but not on the gas heating value, within our estimated measurement accuracy of about 2%. Above 70% of full power, NO emission is 5 ...

International Nuclear Information System (INIS)

Single-phased Sr3B2SiO8:Eu3+ phosphor was prepared by a solid-state method at 1020 oC. The luminescence spectra showed that Sr3B2SiO8:Eu3+ phosphor can be effectively excited by near ultraviolet light (393 nm) and blue light (464 nm). When excited at 393 or 464 nm Sr3B2SiO8:Eu3+ exhibited the main emission peaks at 611 and 620 nm, which resulted from the supersensitive 5D0#->#7F2 transition of Eu3+. The luminescence intensity of Sr3B2SiO8:Eu3+ at 611 and 620 nm reached the maximum when the doping content of Eu3+ was 4.5 mol%. Its chromaticity coordinates (0.646, 0.354) were very close to the NTSC standard values (0.67, 0.33). Thus, Sr3B2SiO8:Eu3+ is considered to be an efficient red-emitting phosphor for long-UV InGaN-based light-emitting diodes. - Highlights: ? Sr3B2SiO8:Eu3+ was synthesized using solid-state reaction method for the first time. ? The phosphor can be efficiently excited by the near-UV chips and gives strong red emission. ? The phosphor is a ...

Science.gov (United States)

From the dried fruiting bodies of the mushroom Armillaria luteo-virens, a dimeric lectin with a molecular mass of 29.4 kDa has been isolated. The purification procedure involved (NH{sub 4}){sub 2}SO{sub 4} precipitation, ion exchange chromatography on DEAE-cellulose, CM-cellulose, and Q-Sepharose, and gel filtration by fast protein liquid chromatography on Superdex 75. The hemagglutinating activity of the lectin could not be inhibited by simple sugars but was inhibited by the polysaccharide inulin. The activity was stable up to 70 {sup o}C but was acid- and alkali-labile. Salts including FeCl{sub 3}, AlCl{sub 3}, and ZnCl{sub 2} inhibited the activity whereas MgCl{sub 2}, MnCl{sub 2}, and CaCl{sub 2} did not. The lectin stimulated mitogenic response of mouse splenocytes with the maximal response achieved by 1 {mu}M lectin. Proliferation of tumor cells including MBL2 cells, HeLa cells, and L1210 cells was inhibited by the lectin with an IC{sub 5} of 2.5, 5, and 10 ...

Energy Technology Data Exchange (ETDEWEB)

The purified integral membrane protein, band 3, from human erythrocytes was inserted into egg lecithin liposomes. The insertion of band 3 was determined from thermal transition data from the analysis of the C-H stretching region bands recorded at temperatures from 25 to -22[sup o]C. Raman spectra show that band 3 considerably broadens and lowers the thermal transition of egg lecithin liposomes, suggesting the insertion of band 3. The band 3-inserted liposomes were irradiated with gamma-rays (40 Gy) and the radiation target groups were determined by the analysis of the structural sensitive Raman bands in the 1600-1700 cm[sup -1] (amide I), 1200-1300 cm[sup -1] (amide III) and 550-1030 cm[sup -1] (side chain amino groups) regions. The radiation-sensitive groups as identified from Raman spectra in the region 550-1030 cm[sup -1] are tyrosines and cysteines. The radiation-induced changes in the secondary structure were determined from amide I and III bands. Quantitative ...

International Nuclear Information System (INIS)

The present communication deals with the synthesis, single crystal growth and characterization of a new nonlinear optical material L-proline strontium chloride monohydrate (L-PSCM). Single crystals have been grown using the slow solvent evaporation technique. Single crystal XRD analysis confirmed that the crystal belongs to the orthorhombic structure with lattice parameter a=6.6966(3) A, b=12.4530(5) A, c=15.2432(5) A and space group P2_12_12_1. Presence of various functional groups in L-PSCM and protonation of the ions were confirmed by Fourier transform infrared spectroscopy (FT-IR) analysis. The melting point of the single crystal was found to be 126 "oC using DSC. Ultraviolet-visible spectral analyses showed that the crystal has low UV cut-off at 226 nm combined with very good transparency of 90% in a wide range. The optical band gap was estimated to be 5.82 eV. Capacitance and dielectric-loss measurements were carried out at different temperatures in the ...

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The gasification reactivities of six typical Chinese anthracite chars with steam and CO{sub 2} at 0.02-0.1 MPa and 920-1050{sup o}C were investigated by using thermogravimetric analysis (TGA). The reactivities of anthracite chars during steam gasification were found to have a good correlation to the coal volatile matter contents. The higher the coal volatile matter content, the higher the reactivity. The difference in reactivities of anthracite chars during CO{sub 2} gasification seems to be more dependent on the catalytic effect of inherent minerals in anthracite. The results show that the greater the alkali index, the higher the reactivity. The reactivities of demineralized anthracite chars vary very little compared with those the undemineralized chars at higher temperatures, whereas the reactivities of demineralized chars from Jincheng and Rujigou are lower than those of undemineralized ones and the reactivities of demineralized chars from Yangquan, Hunan, ...

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In order to obtain knowledge about formation and growth of condensed ring structure in a coalification process, discussions were given on product skeleton structure by using hydrogenation and hydrocracking of heated cellulose. In underwater heating of cellulose, reaction of dehydration has occurred at 200{degree}C or lower, that of decarbonation at 250{degree}C or higher, and that of demethanizing at 300{degree}C, resulting in production of a dark-brown coal-like substance. The substance has lower H/C value and higher O/C value than coal. As the underwater heating temperature rises, the hydrogenation reactivity of the heated substance decreases, and so does the ratio of conversion into toluene solubles. These phenomena are related to strength of cross-linking bond between unit skeleton structures. A substance heated at an underwater heating temperature of 200{degree}C turns toluene-soluble almost completely even during the hydrogenation reaction (350{degree}C for 2 ...

International Nuclear Information System (INIS)

A newly synthesized glycine derivative (termed GlyD), 2-(4-(dimethylamino)benzylamino)acetic acid hydrochloride, was used to inhibit uniform and pitting corrosion processes of Al in 0.50 M KSCN solutions (pH 6.8) at 25 "oC. For uniform corrosion inhibition study, Tafel extrapolation, linear polarization resistance and impedance methods were used, complemented with SEM examinations. An independent method of chemical analysis, namely ICP-AES (inductively coupled plasma atomic emission spectrometry) was also used to test validity of corrosion rate measured by Tafel extrapolation method. GlyD inhibited uniform corrosion, even at low concentrations, reaching a value of inhibition efficiency up to 97% at a concentration of 5 x 10"-"3 M. Results obtained from the different corrosion evaluation techniques were in good agreement. This new synthesized glycine derivative was also used to control pit nucleation and growth on the pitted Al surface based on cyclic polarization, ...

International Nuclear Information System (INIS)

We have observed the CH_3OH J = 2-1, SiO J = 2-1, C"3"4S J = 2-1, H"1"3CO"+ J = 1-0, HN"1"3C J = 1-0, CCH N = 1-0, OCS J = 8-7, and SO J_N = 2_2-1_1 lines toward 20 massive clumps, including Midcourse Space Experiment (MSX) 8 #mu#m dark sources (infrared dark clouds) and MSX 8 #mu#m sources, by using the Nobeyama Radio Observatory 45 m telescope. We have found that the velocity widths of the CH_3OH and C"3"4S lines are broader than those of the H"1"3CO"+ line in the MSX dark sources. On the other hand, they are comparable to the velocity width of the H"1"3CO"+ line in the MSX sources. In addition, the [SiO]/[H"1"3CO"+] abundance ratio is found to be enhanced in the MSX dark sources in comparison with the MSX sources. These results suggest that shocks caused by interaction between an outflow and an ambient dense gas would have substantial impact on the chemical composition of the MSX dark sources. The velocity widths of the CH_3OH and C"3"4S lines relative to that ...

International Nuclear Information System (INIS)

There is a lot of interest in the studies that would help to understand whether there is a casual association between cancer and various types of molecular or cytogenetic damage detected in human cells. One major oncogenesis process is activation of proto-oncogenes by point mutations or chromosomal translocation. There are substantial evidence that indicates that the loss of heterozygosity of certain chromosomes is involved in human cancerogenesis. Our study aimed to elicit the possible association between cancer and DNA and cytogenetic abnormalities induced in lymphocytes of people bearing various categories of skin cancer cells. Fresh blood was collected by venipuncture from 25 individuals (including nine prior to cancer treatment). All patients were nonsmoking males, however 42.3 % of them were former smokers. Blood samples were divided into two parts and in the first part of samples cytogenetic studies were performed immediately, while from the second part lymphocytes were isolated ...

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We consider the case of a test sphere (ball) of radius a{sub 1} rotating at constant angular velocity {omega} in an otherwise quiescent unbounded suspension of uniformly sized spheres of radii a{sub 2} dispersed in a Newtonian fluid of viscosity {mu}. To the first order in the volume fraction c of suspended spheres it is shown that when the ball is small compared with the suspended spheres the suspension does not behave as regards the hydrodynamic torque L exerted on the ball like a homogeneous Newtonian fluid characterized by the usual Einstein viscosity coefficient {mu}{sub s}={mu}(1+5/2c). Explicitly, the torque on the rotating sphere does not obey Kirchoff{close_quote}s law, L=8{pi}{mu}{sub s}a{sub 1}{sup 3}{omega} for no slip. Rather, a modified form of Kirchoff{close_quote}s law is obtained in which the Einstein coefficient of 5/2 is multiplied by a coefficient which is less than unity in magnitude and is functionally dependent only upon the suspended-sphere/test-sphere size ...

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This thesis deals with the evaluation of Solar Grade Silicon (SoG-Si) purified by different techniques, and also the fabrication and characterization of high efficiency and advanced bifacial solar cells. In the beginning of Chapter 1, various SoG-Si production methods relevant for this work are qualitatively described. The three feedstock materials used in this work are from the Fluidized Bed Reactor (FBR) process, metallurgical feedstock-I and feedstock-II process. In metallurgical feedstock-I, the lifetime of the minority charge carriers in multicrystalline silicon (mc-Si) samples at the grain boundaries are found to be higher than the grains themselves possibly due to lower resistivities in the grain boundaries. The efficiency of the best solar cell obtained using the mc-Si metallurgical feedstock-I is 16.1%. It has been identified that the fast light induced degradation, whose magnitude is lower than that of a reference cell suggests the formation of a B-metal complex in the SoG-Si ...

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This study follows previous experimental work showing that the shrinking-core model applies to the pyrolysis (i.e., heating in the absence of oxygen) of particles (diam.{approx}14 mm) of a bituminous coal or a lignite in a fluidized bed at 700-950 {sup o}C. These experimental facts are in accord with the production of volatile matter being endothermic and not thermoneutral, as often assumed. Also, the rate at which volatile matter is produced in the presence of oxygen (i.e., devolatilization) or in its absence (pyrolysis) is demonstrated here to be controlled not at all by mass transfer, but by heat conduction to a moving reaction front inside a coal particle, provided its diameter exceeds {approx}3 mm. The resulting steady-state model of devolatilization indicates that six dimensionless groups are required to describe the rate of(I)coal->char+volatile matter for a nonfragmenting and nonswelling coal. This reaction occurs for a total time of c{sub 1}r{sub ...