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1

synergies between visible/near-infrared imaging spectrometry and ...  

1 Department of Geography, University of California Santa Barbara, CA, 93106, USA ... urban vegetation, roofs and roads was assembled from combined AVIRIS ... Impervious, Soil, Green Vegetation (GV) and Non-photosynthetic Vegetation ...

2

Improvement of urban impervious surface estimation in Shanghai using Landsat7 ETM+ data  

This paper explores the potential to improve the impervious surface estimation accuracy using a multi-stage approach on the basis of vegetation-impervious surface-soil (V-I-S) model. In the first stage of Spectral Mixture Analysis (SMA) process, pixel purity index, a quantitative index for defining endmember quality, and a 3-dimensional endmember selection method were applied to refining endmembers. In the second stage, instead of obtaining impervious surface fraction by adding high and low albedo fractions directly, a linear regression model was built between impervious surface and high/low albedo using a random sampling method. The urban impervious surface distribution in the urban central area of Shanghai was predicted by the linear regression model. Estimation accuracy of spectral mixt...

3

A comparison study of impervious surfaces estimation using optical and SAR remote sensing images  

The estimation of impervious surface area (ISA) is becoming increasingly important because of its environmental and socio-economic significance. However, accurate ISA estimation remains challenging due to the diversity of impervious materials, as well as the occurrence of clouds in subtropical humid areas. In order to address these challenges and provide an accurate estimation of ISA in cloudy areas, it is advantageous to use both optical and microwave remote sensing which can penetrate cloud coverage. Our study aims to conduct a comprehensive comparison between these two data sources and between different methods for mapping ISA. Both the classification results and accuracy assessment provide a better understanding about the differences between Landsat ETM+ and ENVISAT ASAR images and between artificial neural network (ANN) and support vector machine (SVM) classifier for estimating the impervious surfaces. The comparison demonstrates that ETM+ images alone provide a better ISA estimation (OA: about 90%; Kappa: about 0.88) than the estimation from ASAR images alone (OA: about 85%; Kappa: about 0.77). Additionally, the experiment indicates that SVM should be a better choice for ISA estimation using Landsat ETM+ images, while ANN turns out to be more sensitive to the confusion between dry soils and bright impervious surfaces, and between shade and dark impervious surfaces. For ENVISAR ASAR images, ANN gets a better result with higher accuracy, while the SVM classifier produces more noise and has some edge effects.

4

Restoring pre-development conditions in a urban environment using green roofs  

As development progresses in a urban environment, the impervious areas that rapidly contribute runoff to the receiving water bodies increase while the pervious areas that store and deliver subsurface flow over periods of hours, days or weeks diminish, with the direct consequence of higher runoff rates and volumes and shorter times of concentration. The construction of impervious surfaces modifies the surrounding soils through engineered compaction and eliminates superficial soil and its role as a significant pervious storage interface between the subsurface and the atmosphere. There are documented case studies that conclusively link urbanization and increased watershed imperviousness to hydrologic impacts on streams. The Effective Impervious Area (EIA) in a watershed is the impervious area directly connected to the storm drainage system that contributes to increased storm water volumes and runoff rates. It is shown in the literature that a reduction of EIA could compensate the adverse impact of possible global warming scenarios on urban hydrology and in particular on the efficiency of a combined sewer system. In this paper, the implementation of green roofs is analyzed as a technique able to reduce the amount of EIA in order to mitigate the impact of urbanization on the hydrologic response of the urban catchment of Colle Ometti in the town of Genoa (Italy). Although no green roof installations are now present in the area, this study modelled - using extensive green roof details - the hydrologic effects of hypothetical roof greening scenarios. The modelling of green roof systems was undertaken using the EPA SWMM and was calibrated and validated on a small size green roof test bed completed in September 2007 in the laboratory of the Department of Civil, Environmental and Architectural Engineering (DICAT - University of Genova).

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Effect of soil sealing on the microbial biomass, N transformation and related enzyme activities at various depths of soils in urban area of Beijing, China  

Purpose Sealing of soils prevents the exchange of gas, water and nutrient between soil and other environmental compartments, and affects urban N flux, thereby resulting in certain negative impacts on soil functioning and urban environment. However, little information is available on the biogeochemical cycling and biological activities after sealing of soils in urban areas. The aim of this study was to assess the effects of soil sealing on N transformation and associated microbial properties. Materials and methods Soil samples were collected at four depths (0???10, 10???20, 20???30, 30???40 cm) from three land cover types: impervious land (sealing of soil), forest (vegetation) and bare land (no sealing and no vegetation) in Beijing, China. Soil inorganic N, net potential N-mineralization a...

6

Modeling the distribution of organic contaminants in an urban watershed  

Urban systems are characterized by wide temporal fluctuations in environmental conditions that are superimposed on a highly disturbed ecosystem. A simple, multi-media model is developed to begin to understand the fate of organic contaminants in the urban environment. Based on an equilibrium fugacity model, the model incorporates impervious surfaces that comprise a large percentage of surface area in urbanized watersheds, in addition to other media considered, e.g., soil, air, surface water, sediment and vegetation. It is hypothesized that an organic film coats impervious surfaces and provides an active layer into which organic chemicals partition. The layer originates from (a) condensation of secondary organic compounds formed in atmospheric reactions, and (b) deposition of uncombusted and partially combusted hydrocarbons from vehicles. The model was applied to the Don River watershed, located in central Toronto. Model results indicate that elevated concentrations of high K{sub ow} chemicals considered, namely y-HCH, PCBs and B(a)P, occur in the organic film. The more volatile chemicals modeled, chloroform and naphthalene, remain in the air phase, as expected given their physical chemical properties. Urban soils and vegetation are significant reservoirs of chemical in the watershed. Overall, the results suggest that an organic film on impervious surfaces may act as a temporary sink for persistent organic compounds and affect their multi-media distribution.

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Storm Water Runoff Mitigation Using a Green Roof  

A prototype green roof was constructed and monitored in Pittsburgh, Pennsylvania, to demonstrate a way to reduce storm water runoff and combined sewer overflow (CSO) events. The large impervious surface area created by urban development in Pittsburgh creates a wet weather flow that the existing combined waste waster and storm water sewer system cannot contend with. Green or vegetated roofs can reduce the amount of storm water that reaches the sewer conveyance system by replacing an otherwise impervious roof with porous soil that retains rainwater and plants that evapotranspire resulting in reduced storm water flows to the sewer system. The prototype green roof reduced the runoff volume by up to 70% compared to a conventionally ballasted roof covering a control portion of the same building....

8

Extracting impervious surfaces from medium spatial resolution multispectral and hyperspectral imagery: a comparison  

Remote sensing estimation of impervious surfaces is significant in monitoring urban development and determining the overall environmental health of a watershed, and has therefore recently attracted increasing interest. The main objective of this study was to develop a general approach to estimating and mapping impervious surfaces by using medium spatial resolution satellite imagery. We have applied spectral mixture analysis (SMA) to Earth Observing 1 (EO-1) Advanced Land Imager (ALI) (multispectral) and Hyperion (hyperspectral) imagery in Marion County, Indiana, USA, to calculate the fraction images of vegetation, soil, high albedo and low albedo. The effectiveness of the two images was compared according to three criteria: (1) high-quality fraction images for the urban landscape, (2) rela...

9

Green roof retrofit project in North Vancouver  

This investigation focused on determining how much soil is required to meet Lower Mainland SWM objectives, whether an existing roof can support that weight, how much installation of a green roof would cost, and how success could be measured. The conclusion was that green roofs are extremely difficult to build on existing structures if they are designed to meet the Lower Mainland SWM objectives. Nevertheless, green roofs represent the greatest stormwater management opportunity at reducing total impervious area/effective impervious area in highly developed areas. It was considered unlikely that a structure built before 1973 would be strong enough to support the loading of a full green roof. Planters may work, however, inspection by a structural engineer is strongly advised. To be acceptable, the green roof should be able to capture 25 to 42 mm of rain which represents 50 per cent of mean annual rainfall. 36 figs.

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Remote sensing of impervious surfaces in the urban areas: Requirements, methods, and trends  

The knowledge of impervious surfaces, especially the magnitude, location, geometry, spatial pattern of impervious surfaces and the perviousness-imperviousness ratio, is significant to a range of issues and themes in environmental science central to global environmental change and human-environment interactions. Impervious surface data is important for urban planning and environmental and resources management. Therefore, remote sensing of impervious surfaces in the urban areas has recently attracted unprecedented attention. In this paper, various digital remote sensing approaches to extract and estimate impervious surfaces will be examined. Discussions will focus on the mapping requirements of urban impervious surfaces. In particular, the impacts of spatial, geometric, spectral, and tempora...

11

BCI: A biophysical composition index for remote sensing of urban environments  

Understanding urban environments and their spatio-temporal changes is essential for regional and local planning and environmental management. To facilitate monitoring and analyzing urban environments, remotely sensed data have been applied extensively because of its synoptic view and repeat coverage over large geographic areas. Compared with traditional per-pixel and sub-pixel image analyses, spectral indices have apparent advantages due to their easy implementation. However, most spectral indices are designed to highlight only one land cover, and confusion between other land cover types, in particular impervious surfaces and bare soil, has not been successfully addressed. This study proposes a biophysical composition index (BCI) for simple and convenient derivation of urban biophysical co...

12

Exploring roles for green roofs in the Greater Vancouver Regional District  

Observations of increasingly impervious areas resulting from urbanization and redevelopment and observed increases in rainfall, combined with long-term climate change scenarios suggest storm water management source control as the most appropriate potential application for green roofs. This conclusion was reached after intensive investigation of the hydrologic performance of green roofs for a variety of soil types, percentages of green roof area and precipitation scenarios, through continuous simulation modeling at both site and watershed scales. Results of this investigation are discussed in this paper. 29 figs.

13

Geospatial assessment of agroecosystem health: development of an integrated index based on catastrophe theory  

Assessing agroecosystem health at landscape scale has been rarely reported. A geospatial assessment framework, by integrating remote sensing, geographical information systems, landscape metrics, geostatistics and catastrophe theory, was proposed and applied to characterize the spatial variations of agroecosystem health for a typical region in the eastern coastal agricultural plain, China. After appropriate pretreatments, eleven hierarchically structured indicators, subject to catastrophe models, were aggregated into an integrated index for each 30 m grid cell across the study area. Great spatial variations in agroecosystem health were identified. Areas covered by water bodies and impervious surfaces, under which soils can not function, generally presented low values. Larger slope or highe...

14

Biomass and bio-energy production of ten multipurpose tree species planted in sodic soils of indo-gangetic plains  

Ten multipurpose tree species, Terminalia arjuna, Azadirechta indica, Prosopis juliflora, Pongamia pinnata, Casuarina equisetifolia, Prosopis alba, Acacia nilotica, Eucalyptus tereticornis, Pithecellobium dulce and Cassia siamea, were raised in a monoculture tree cropping system on the sodic soil of Gangetic alluvium in north India (26? 47? N: 80?46? E) for 10 years to evaluate the biomass and bio-energy production. The soil was compact, sodic and impervious to water associated with nutrient deficiency or toxicity. Maximum plant height was recorded with E. tereticornis followed by C.equisetifolia and P. juliflora. A. nilotica performed better than the other species in terms of diameter at breast height (DBH) with a basal area of 13.04 m2?ha?1, followed by P. juliflora and C. equisetifolia....

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Preliminary geotechnical investigation: Panhandle Reservoir No. 1 and appurtenances. Final technical report, November 1980-May 1982. [Proposed WyCoalGas project, Converse County, Wyoming  

The site of the proposed Panhandle Reservoir No. 1 is suitable for development of the proposed project from a geotechnical point of view. The maximum embankment section should consist of an impervious central core, Zone 1; a semi-previous shell on either side of the Zone 1 and part of the core, Zone 1A; an upstream previous shell, Zone 2; a downstream shell of miscellaneous materials, Zone 4; and a chimney drain and downstream drainage blanket, Zone 3. Suitable materials for all of the required construction are located in the immediate vicinity of the dam with the exception of the stone required for the riprap, riprap bedding, and gabions. This stone will have to be imported from off site. Reduction of seepage through the dam foundation and abutments requires stripping of the upper soils, construction of a shallow keyway trench, and grouting of the bedrock. If additional seepage reduction is required, additional methods such as positive cutoff through the upper more permeable bedrock or an upstream impervious blanket will be required. The dam should be monitored with frequent visual surveillance and instrumentation including surface displacement monuments, piezometers, and inclinometers. The maximum proposed embankment section and foundation have adequate strength to withstand the expected seismic and static loadings with a satisfactory factor of safety.

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Synergies between Visible/Near-Infrared imaging spectrometry and the Thermal Infrared in an urban environment: An evaluation of the Hyperspectral Infrared Imager (HyspIRI) mission  

More than half of humanity lives in urban areas, projected to exceed 80% by 2015. Urban areas are major sources of environmental contaminants and sinks of energy and materials. Globally, remote sensing contributes to improved understanding of urban impacts through mapping urban extent, vegetation and impervious cover fractions and urban energy balance including albedo, emissivity and land surface temperature (LST). HyspIRI is a NRC "Decadal Survey" mission combining a visible, near-infrared and shortwave infrared (VSWIR) imaging spectrometer with a multispectral thermal infrared (TIR) instrument . Potential synergies between VSWIR and TIR data were explored using analogous airborne data acquired over Santa Barbara in June, 2008. These data were analyzed at their native spatial resolutions (7.5m VSWIR and 15m TIR), and aggregated 60 m spatial resolution similar to HyspIRI. A spectral library of common urban materials (e.g., grass, trees, soil, roofs, roads) was built from field and airborne-measured spectra . LST and emissivity were also retrieved from the airborne data. Co-located pixels from airborne data were used to generate reflectance/emissivity spectra for a subset of urban materials. Multiple Endmember Spectral Mixture Analysis (MESMA) was used to map fractions of impervious, soil, green vegetation (GV) and non-photosynthetic vegetation (NPV) at the different spatial resolutions and to compare the fractional estimates across spatial scales. Surface energy parameters, including albedo, vegetation cover fraction, broadband emissivity and LST were also determined for urban and natural land-cover classes in the region. Fractions were validated using 1m digital photography. GV and NPV Fractions were highly correlated with validation data at all spatial scales, producing a near 1:1 relationship but with a 0.95) including vegetation, water and asphalt, and low emissivity surfaces (roof types, beach sands and senesced grass. Residential and commercial areas showed a general pattern of increasing LST with increasing impervious fraction. Fine scale spatial structure in cover fractions and LST showed important departures from a simple inverse relationship between GV and LST, even at 60m. The results demonstrate the utility of HyspIRI data for urban studies and provide an insight of what will be possible on a global scale with HyspIRI.

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Storm runoff as related to urbanization in the Portland, Oregon-Vancouver, Washington Area  

A series of equations was developed to provide a better method of determining flood frequencies in the Portland-Vancouver urban area than is now available. The resulting regression equations can be used to compute peak discharge and storm runoff with a standard error of estimate of approximately 30 percent. Basins used to define the regression equations ranged in size from 0.2 to 26 square miles. Those physical basin parameters that proved to be significant are: drainage area, effective impervious area, storage, rainfall intensity, basin slope, and soil infiltration. The equations indicate that total urbanization of an undeveloped basin can increase peak discharge as much as 3? times and almost double the volume of storm runoff.\\r\

18

Advancements in subsurface barrier wall technology  

Subsurface barrier walls are enjoying a resurgence in popularity as components of site remediation systems largely for two reasons. First, treatment technologies have shown themselves to be incapable of fully managing a large proportion of waste disposal sites, especially large landfills, DNAPL sites, and large industrial plant sites, thus underscoring the importance of site-wide containment technologies such as subsurface barrier walls. The second factor is a parallel advancement in the technologies of barrier wall construction. Advancements, include a variety of geomembrane-based barrier walls, jet grouting techniques, deep soil mixing, and the ability to construct deep barrier walls (greater than 150 feet deep) using interlocking plastic concrete panels. These advancements have led to barrier walls which are not only more impervious, more resistant to chemical attack, and capable of achieving greater depths, but in many cases are less costly than earlier technologies.

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Annual Water Budgets for a Seasonally Inundated Sinkhole Wetland  

Annual water budgets spanning 2 years, 2004 and 2005, are constructed for a sinkhole wetland in the Tennessee Highland Rim following conversion of 13 % of the watershed area to impervious surfaces. Surface runoff was the dominant input, with a contribution of 56.4 % of the total. An average of 18.9 % of gross precipitation was intercepted by the canopy and evaporated. Deep recharge varied from 55.5 % (2004) to 52.2 % (2005) of total outflow. Evapotranspiration accounted for 46.2 % of the total losses, with an average of 50.3 % lost from soil profile storage. The annual water budgets indicate that deep recharge is a significant hydrologic function performed by isolated sinkhole wetlands, or karst pans, on the Tennessee Highland Rim. Continued hydrologic monitoring of sinkhole wetlan...

20

Modeling diurnal variation of ground thermal radiance images using energy balance model and endmember composing technique  

Modeling and analyzing dynamic changes of land thermal radiance scenes play an important role in thermal remote sensing. In this paper, the diurnal variation of ground surface thermal scene is mainly discussed. Firstly, based on the land surface energy balance equation, the diurnal variation of land surface temperatures (LSTs) over bare land covers were simulated by an analytical thermal model with second harmonic terms, and the diurnal LST variation of vegetation canopy was simulated using the Cupid model. Secondly, normalized difference vegetation index (NDVI), normalized difference water index (NDWI), and ratio resident-area index (RRI) were used to evaluate the endmember abundance of four land cover types including vegetation, bare soil, impervious and water area, which were calculated...

 
 
 
 
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A parameter study of the two-phase ground water transport in the soil surrounding a growing hemispherical in situ vitrification melt  

Numerical simulation is used to test the effect of several parameters on the water balance and pressure field surrounding a growing hemispherical In Situ Vitrification (ISV) melt. In the current project, a hemispherical annulus of unsaturated soil contained between a growing melt and an impervious wall is modeled. Water vapor vents to atmospheric conditions. The soil is considered a porous media; consequently, fluid velocity can be modeled by Darcy`s equation. The capillary pressure and relative permeability are modeled using the equations derived by van Genuchten. The computer model employs a grid which adapts to the transient boundary of the growing melt. The parameters considered include: initial liquid saturation, soil permeability, and melt growth rate. The combined effect of capillary pressure and permeability is also studied. The variation of these parameters in a Hanford soil are studied for their effect on pressure history at the melt interface and total liquid mass history. Transport of heat and mass in the soil is illustrated graphically in terms of the saturation and pressure fields as well as mass flux of liquid and vapor water.

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Modeling Land Use Change In A Tropical Environment Using Similar Hydrologic Response Units  

Montane mainland South East Asia comprises areas of great biological and cultural diversity. Over the last decades the region has overcome an important conversion from traditional agriculture to cash crop agriculture driven by regional and global markets. Our study aims at understanding the hydrological implications of these land use changes at the catchment scale. In 2004, networks of hydro-meteorological stations observing water and energy fluxes were installed in two 70 km2 catchments in Northern Thailand (Chiang Mai Province) and Southern China (Yunnan Province). In addition, a detailed soil surveying campaign was done at the moment of instrument installation. Land use is monitored periodically using satellite data. The Thai catchment is switching from small agricultural fields to large extensions of cash crops. The Chinese catchment is replacing the traditional forest for rubber plantations. A first comparative study based on catchments' geomorphologic characteristics, field observations and rainfall-runoff response revealed the dominant hydrologic processes in the catchments. Land use information is then translated into three different Hydrologic Response Units (HRU): rice paddies, pervious and impervious surfaces. The pervious HRU include different land uses such as different stages of forest development, rubber plantations, and agricultural fields; the impervious ones are urban areas, roads and outcrops. For each HRU a water and energy balance model is developed incorporating field observed hydrologic processes, measured field parameters, and literature-based vegetation and soil parameters to better describe the root zone, surface and subsurface flow characteristics without the need of further calibration. The HRU water and energy balance models are applied to single hillslopes and their integrated hydrologic response are compared for different land covers. Finally, the response of individual hillslopes is routed through the channel network to represent each of the basins. Results from the model are compared to measured catchment-scale water and energy fluxes.

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Urbanization and nutrient retention in freshwater riparian wetlands  

Urbanization can degrade water quality and alter watershed hydrology, with profound effects on the structure and function of both riparian wetlands (RWs) and aquatic ecosystems downstream. We used freshwater RWs in Fairfax County, Virginia, USA, as a model system to examine: (1) the effects of increasing urbanization (indexed by the percentage of impervious surface cover [%ISC] in the surrounding watershed) on nitrogen (N) and phosphorus (P) concentrations in surface soils and plant tissues, soil P saturation, and soil iron (Fe) chemistry; and (2) relationships between RW soil and plant nutrient chemistries vs. the physical and biotic integrity of adjacent streams. Soil total P and NaOH-extractable P (representing P bound to aluminum [Al] and Fe hydrous oxides) varied significantly but nonlinearly with %ISC (r2 = 0.69 and 0.57, respectively); a similar pattern was found for soil P saturation but not for soil total N. Relationships were best described by second-order polynomial equations. Riparian wetlands appear to receive greater P loads in moderately (8.6-13.3% ISC) than in highly (25.1-29.1% ISC) urbanized watersheds. These observations are consistent with alterations in watershed hydrology that occur with increasing urbanization, directing water and nutrient flows away from natural RWs. Significant increases in total and crystalline soil Fe (r 2 = 0.57 and 0.53, respectively) and decreases in relative soil Fe crystallinity with increasing %ISC suggest the mobilization and deposition of terrestrial sediments in RWs, likely due to construction activities in the surrounding watershed. Increases in RW plant tissue nutrient concentrations and %ISC in the surrounding watershed were negatively correlated with standard indices of the physical and biotic integrity of adjacent streams. In combination, these data suggest that nutrient and sediment inputs associated with urbanization and storm-water management are important variables that affect wetland ecosystem services, such as water quality improvement, in urbanizing landscapes. ?? 2007 by the Ecological Society of America.

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Assessments of urban growth in the Tampa Bay watershed using remote sensing data  

Urban development has expanded rapidly in the Tampa Bay area of west-central Florida over the past century. A major effect associated with this population trend is transformation of the landscape from natural cover types to increasingly impervious urban land. This research utilizes an innovative approach for mapping urban extent and its changes through determining impervious surfaces from Landsat satellite remote sensing data. By 2002, areas with subpixel impervious surface greater than 10% accounted for approximately 1800 km2, or 27 percent of the total watershed area. The impervious surface area increases approximately three-fold from 1991 to 2002. The resulting imperviousness data are used with a defined suite of geospatial data sets to simulate historical urban development and predict future urban and suburban extent, density, and growth patterns using SLEUTH model. Also examined is the increasingly important influence that urbanization and its associated imperviousness extent have on the individual drainage basins of the Tampa Bay watershed. ?? 2005 Elsevier Inc. All rights reserved.

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Impervious surface quantification using a synthesis of artificial immune networks and decision/regression trees from multi-sensor data  

Impervious surface quantification is important for many planning and management applications because of the impacts that impervious surfaces have on a range of environmental resources such as groundwater. This research proposes an integrated method to quantify impervious surfaces at multiple spatial scales via a synthesis of several machine learning approaches. In this study, we 1) proposed a hierarchical classification method to detect impervious surfaces through a fusion of optimized artificial immune networks (OPTINC) and decision trees at high spatial resolution, 2) evaluated the method using multi-sensor data (i.e., high spatial resolution WorldView-2 and LiDAR data) to map impervious surfaces, 3) tested the applicability of the binary impervious surface maps to quantify sub-pixel imp...

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Determining Trends in Impervious Cover for the Mobile Bay, AL Region for 1974-2008, Based on a Landsat Time Series  

This presentation will discuss the development and use of Landsat-based impervious cover products in conjunction with land use land cover change products to assess multi-decadal urbanization across the Mobile Bay region at regional and watershed scales. This nationally important coastal region has undergone a variety of ephemeral and permanent land use land cover change since the mid-1970s, including gradual but consequential increases in urban surface cover. This urban sprawl corresponds with increased regional percent impervious cover. The region s coastal zone managers are concerned about the increasing percent impervious cover, since it can negatively influence water quality and is an important consideration for coastal conservation and restoration work. In response, we processed multi-temporal Landsat data to compute maps of percent impervious cover for multiple dates from 1974 through 2008, roughly at 5-year intervals. Each year of product was classified using one single date of leaf-on and leaf-off Landsat data in conjunction with Cubist software. We are assessing Landsat impervious cover product accuracy through comparisons to available reference data, including available NLCD impervious cover products from the USGS, raw Landsat data, plus higher spatial resolution aerial and satellite data. In particular, we are quantitatively comparing the 2008 Landsat impervious cover products to those from QuickBird 2.4-meter multispectral data. Initial visual comparisons with the QuickBird impervious cover product suggest that the 2008 Landsat product tends to underestimate impervious cover for high density urban areas and to overestimate impervious cover in established residential subdivisions mixed with forested cover. Landsat TM and ETM data appears to produce more accurate impervious cover products compared to those using lower resolution Landsat MSS data. Although imperfect, these Landsat impervious cover products have helped the Mobile Bay National Estuary Program visualize basic urbanization trends for multiple HUC-12 watersheds of concern to them and their constituents

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Integrating heterogeneous landscape characteristics into watershed scale modelling  

Two versions of the SWAT-model with different dominating runoff generation processes have been applied. One version comprises the original available SWAT version where only the basic input data are used. In the second version SWAT has been modified, by the integration of an impermeable layer at the subbasin level, in order to better reflect the boundary between soil and bedrock that results in increased lateral flow in low mountain ranges. As well, since conventional German soil maps do not describe soil horizons beyond 2 m depth, we also added a 4 m fixed depth in the lowland areas in order to reflect the deep loess deposits in this region. The decision for the location of the impermeable and the additional loess layer was based on a GIS analysis of additional geologic information. This study revealed that both model versions produced acceptable and comparable results regarding the evaluated goodness of fit measures. The GLUE analysis showed that the SWAT model set up with additional information about the distribution of impervious soil layers and the loess depth in the lowlands produced the highest simulation quality and the lowest uncertainty. Moreover, SWAT II version was able to better represent the spatial extend of the dominating runoff processes best. This leads to the conclusion that the SWAT II version is better suited for scenario analysis than the original model version.

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Green roofs; Les toitures vegetalisees  

Impervious surface coverage keeps spreading in cities. Streets, sidewalks, parking lots and roofs are waterproof, meaning greater amounts of water to channel and treat and higher flood risks during heavy rainfalls. Green roofing can play a key part in addressing this alarming issue. There are three types of green roofs: extensive, semi-intensive and intensive. The extensive green roof technique uses a thin soil covering with a variety of species providing year-round plant coverage. The plants are not necessarily horticultural in which case routine maintenance is minimal. No watering is needed. Usually extensive green roofs create an ecosystem. The semi-intensive green roof technique uses a soil covering of average thickness and serves to create decorative roofing. Although maintenance is moderate, watering is essential. The intensive green roof technique produces a terrace roof garden. Another advantage of green roofs is they increase the life cycle of the sealing. Roof sealing protection may see the span of its life cycle, now at about fifteen years, doubled if the building has a green roof. planning professionals still know very little about green roofing solutions. Yet, green roofing provides unquestionable ecological qualities and thermal and acoustic performance that have proven to be environmentally friendly. Yet France lags behind northern European countries in green roofing. The Germans, Swiss, Austrians, Scandinavians and Dutch have been using the technique for more than twenty years. (A.L.B.)

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Final results for the EPRI-DOE-SCS Chiyoda Thoroughbred CT-121 clean coal project at Georgia Power`s Plant Yates  

The Yates Clean Coal Project was a co-funded Clean Coal Technology effort, sponsored by the US Department of Energy, the Electric Power Research Institute and Southern Company Services (EPRI-DOE-SCS) to evaluate a retrofit wet-limestone-based, sulfur dioxide (SO{sub 2}) scrubbing system in treating the hot flue gases of a coal-fired, 110MW electric utility boiler. This Project tested the operational limits of Chiyoda`s CT-121 Jet Bubbling Reactor System (JBR ) at Georgia Power`s Plant Yates from 1992 through 1994. Although the original test plan called for a very conservative assessment, the CT-121 system proved robust, so it was tested at widely varying conditions. Fuel sulfur content was varied between 1.5% to 4.3%, various limestone sources at several grind sizes were used, particulate removal and air toxics performance were measured and by-product gypsum soil amendment experimentation was conducted. In all cases, the CT-121 system gave encouraging results with predictably high SO{sub 2} removals (95--99%) and particulate removals (99+%) at all conditions with high reliability. Closed loop operations (no liquids treated, none discharged) called for the extensive application of corrosion impervious, fiberglass reinforced plastics (FRP) that was also very successful. Gypsum by-product proved to be significant as a soil enhancement and was granted a plant food license by the State of Georgia. So far, the Yates Project has received several awards from industry and environmental groups for its performance including Power Plant of the Year in 1994 from Power magazine.

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A computer model for predicting two-phase ground water transport in the soil surrounding a growing melt in the in situ vitrification process  

Two different computer models are tested for their usefulness in predicting the water balance and pressure field surrounding a growing hemispherical In Situ Vitrification (ISV) melt. The melt is centered under the flat surface of a hemisphere of soil contained by an impervious wall. The control volume method is employed for balancing heat, and mass in each model. The soil is considered a porous media; consequently, fluid velocity can be modeled by Darcy`s equation. Both computer models employ grids which adapt to the transient boundary of the growing melt. Computational Grid I (CGI) adapts with the melt boundary by contracting in the radial direction only. In addition to adapting to the melt boundary, Computational Grid II (CGII) also adapts to the liquid-vapor interface which moves outward from the 1,700 C melt in response to the formation of Vapor. CGII has been devised in order to attempt to reduce, at a reasonable CPU cost, the numerical pressure oscillation which arises when the grid is too coarse. A very fine CGI is used as a benchmark to test CGII and a coarser version of CGI. Results from the two CGI and the one CGII cases are presented graphically to illustrate the mass flux of liquid and vapor water and the build-up in pressure as the melt boundary approaches the impermeable wall.

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Field application of farmstead runoff to vegetated filter strips: surface and subsurface water quality assessment.  

Farmstead runoff poses significant environmental impacts to ground and surface waters. Three vegetated filter strips were assessed for the treatment of dairy farmstead runoff at the soil surface and subsurface at 0.3- or 0. 46-m and 0. 76-m depths for numerous storm events. A medium-sized Michigan dairy was retrofitted with two filter strips on sandy loam soil and a third filter strip was implemented on a small Michigan dairy with sandy soil to collect and treat runoff from feed storage, manure storage, and other impervious farmstead areas. All filter strips were able to eliminate surface runoff via infiltration for all storm events over the duration of the study, eliminating pollutant contributions to surface water. Subsurface effluent was monitored to determine the contributing groundwater concentrations of numerous pollutants including chemical oxygen demand (COD), metals, and nitrates. Subsurface samples have an average reduction of COD concentrations of 20, 11, and 85% for the medium dairy Filter Strip 1 (FS1), medium dairy Filter Strip 2 (FS2), and the small Michigan dairy respectively, resulting in average subsurface concentrations of 355, 3960, and 718 mg L COD. Similar reductions were noted for ammonia and total Kjeldahl nitrogen (TKN) in the subsurface effluent. The small Michigan dairy was able to reduce the pollutant leachate concentrations of COD, TKN, and ammonia over a range of influent concentrations. Increased influent concentrations in the medium Michigan dairy filter strips resulted in an increase in COD, TKN, and ammonia concentrations in the leachate. Manganese was leached from the native soils at all filter strips as evidenced by the increase in manganese concentrations in the leachate. Nitrate concentrations were above standard drinking water limits (10 mg L), averaging subsurface concentrations of 11, 45, and 25 mg L NO-N for FS1, FS2, and the small Michigan dairy, respectively. PMID:22370421

32

Estimating impervious surfaces from medium spatial resolution imagery: a comparison between fuzzy classification and LSMA  

Impervious surfaces are important environmental indicators and are related to many environmental issues, such as water quality, stream health and the urban heat island effect. Therefore, detailed impervious surface information is crucial for urban planning and environment management. To extract impervious surfaces from remote sensing imagery, many algorithms and techniques have been developed. However, there are still debates over the strengths and limitations of linear versus nonlinear algorithms in handling mixed pixels in the urban landscapes. In the meantime, although many previous studies have compared various techniques, few comparisons were made between linear and nonlinear techniques. The objective of this study is to compare the performance between nonlinear and linear methods for...

33

Estimating impervious surfaces using linear spectral mixture analysis with multitemporal ASTER images  

Impervious surface is a key indicator of urban environmental quality and degree of urbanization. Therefore, estimation and mapping of impervious surfaces by using remote sensing digital images has attracted increasing attention recently. For mid-latitude cities, seasonal vegetation phenology has a significant effect on the spectral response of terrestrial features, and image analysis must take into account this environmental characteristic. In this paper, three Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) images, acquired on 3 October 2000, 16 June 2001 and 5 April 2004, respectively, were used to test the seasonal sensitivity of impervious surface estimation. The study area was the city of Indianapolis (Marion County), Indiana, USA. Linear spectral mixture analys...

34

Infiltration into pyroclastic slopes  

Mountainous areas of Northern Campania, Southern Italy, are characterized by steep slopes covered with pyroclastic deposits, in form of alternating layers of volcanic ashes and pumices, laying upon a pervious fractured calcareous bedrock, in some cases covered by a thin layer of impervious weathered ashes. Slope inclination is often larger than internal friction angle of such ashes (around 38°), thus equilibrium is assured by the contribution of apparent cohesion due to soil suction in unsaturated conditions. That is why, during intense and persistent rainfall events, when soil approaches saturation and consequently suction decreases, shallow landslides are frequently triggered. The physical characteristics of involved soils are such that landslides often evolve in form of debris flows, which can cause huge damages to buildings and infrastructures and, in some cases, even casualties. Understanding the role played by rainfall infiltration processes is essential to develop reliable models of slope response. To this aim, for the slope of Cervinara, where a large debris flow occurred in the past, laboratory infiltration tests and in situ monitoring are being carried out. Infiltration and evaporation tests are performed on artificial deposit reconstituted in a model slope subjected to controlled uniform rainfall, with various inclinations and bottom boundary conditions. The coupled values of soil suction and water content, observed during the experiments, have allowed defining the water retention curves experienced by the pyroclastic soil in the model slope. The performed infiltration experiments have been simulated with a mathematical model based on the integration of Richards equation with the finite volumes technique. The use of the retention curves obtained from the experiments allowed to build up reliable mathematical models of infiltration also in the case of layered slopes. Recently at the slope of Cervinara an automatic in situ monitoring station has been set up. The data of soil water content and suction collected during one year allow distinguishing different hydraulic behaviour of soil layers, and estimating soil hydraulic characteristic curves. In particular, the water retention curves derived from in situ monitoring show some differences compared to that observed in the infiltration tests on model slopes. The use of the in situ retention curves from the monitoring will allow better calibration of mathematical models of infiltration also in the case of complex geometry.

35

Stormwater performance of a green roof in Toronto  

Significant environmental benefits can be achieved from rooftop gardens in terms of stormwater runoff quantity and quality control. To date, rooftops cover as much as 30 to 35 per cent of the land's surface including existing and proposed developments. By greening rooftops, the total impervious coverage in Toronto can be reduced and new green spaces can be created. A study was conducted in 2003 in which two roofs with 10 per cent slope were covered by two surfaces, namely shingles (on the control roof) and a garden. The purpose was to evaluate the effectiveness of green roof infrastructure as a technique to reduce the quantity and improve the quality of stormwater runoff in Toronto's Remedial Action Plan Area of Concern. The research site was at the York University computer science building where measurements of climate, soil, and runoff data were taken to quantify the benefit of roof gardens for stormwater quality and quantity management in urban areas. The study showed that the roof garden is effective in reducing the total runoff volume and peak flow of rain water runoff. The roof garden performance was found to vary depending on soil moisture and rainfall intensity. However, most of the time the loadings and concentrations were far less than Provincial and Canadian water quality standards. It was noted that irrigation from municipal waterworks may have influenced some parameters by diluting or increasing concentrations and loadings. Furthermore, hardness values were much larger from the garden than the control roof, which could contribute to a reduction in the toxicity of metals in garden runoff. In all cases, the maximum monthly soil temperature was less than the maximum monthly air temperature. 7 refs., 4 tabs., 5 figs.

36

FGD liner experiments with wetlands  

The construction of artificial wetlands for wastewater treatment often requires impermeable liners not only to protect groundwater resources but also to ensure that there is adequate water in the wetland to support appropriate aquatic life, particularly wetland vegetation. Liners or relatively impervious site soils are very important to the success of constructed treatment wetlands in areas where ground water levels are typically close to the ground surface. This study, carried out at the Olentangy River Wetland Research Park, investigated the use of FGD material from sulfur scrubbers as a possible liner material for constructed wetlands. While several studies have investigated the use of FGD material to line ponds, no studies have investigated the use of this material as a liner for constructed wetlands. They used experimental mesocosms to see the effect of FGD liner materials in constructed wetlands on water quality and on wetland plant growth. This paper presents the results of nutrient analyses and physicochemical investigation of leachate and surface outflow water samples collected from the mesocosms. Plant growth and biomass of wetland vegetation are also included in this paper. First two year results are reported by Ahn et al. (1998, 1999). The overall goal of this study is the identification of advantages and disadvantages of using FGD by-product as an artificial liner in constructed wetlands.

37

Habitat conservation planning for California`s Central Valley grassland prairie/vernal pool landscapes  

Vernal Pools are shallow seasonal ponds that form in poorly drained depressions scattered across California`s vast Central Valley. The valley`s rolling terrain and Mediterranean climate, together with an essentially impervious soil horizon, are the key environmental factors affecting distribution of the habitat across valley grassland landscapes. Interest in this habitat heightened in 1993 when vernal pools were the first wetland type in the country to be designated as {open_quotes}Aquatic Resources of National importance{close_quotes} (ARNI). The 1994 listing of four invertebrate species, endemic to California vernal pools, for protection under the endangered Species Act placed further emphasis on them. A 90% loss hypothesis resulted in a strict regulatory policy of {open_quotes}on site{close_quotes} conservation where urbanization interfaces with valley grassland and vernal pool resources. Approximately 2.1 million acres of historic habitat were identified. The current resource covers approximately 1.0 million acres distributed primarily in expansive rangland tracts across 20 California counties. A GIS data base was developed for the Central Valley, with an emphasis on rapidly urbanizing Sacramento County, to provide resource planners with the information to develop a sound conservation strategy for acres was completed in 1994. Restoration and preservation can continue to conserve large tracts that have been well managed historically by ranchers. The findings indicate a tremendous conservation opportunity--thought to have been lost--is extant, and planning decisions can now be based upon sound science.

38

Assessing the Function of Cypress Knees - A Watershed Watch Student Project  

The research presented was conducted as part of Watershed Watch, a two-week hands-on summer program for undeclared entry-level undergraduates, designed to recruit and retain students in Science, Technology, Engineering, and Mathematics (STEM) disciplines. The research presented here was conducted on cypress knees of different ages from the campus of Elizabeth City State University in northeastern North Carolina. Samples were collected from Bald Cypress (Taxodium distichum) knees and thin sections were cut from the distal, medial, and proximal regions of each knee. Three specimens of each of young and old knees were analyzed. Structural differences in the location and amount of wood (secondary xylem), parenchyma, and aerenchyma tissues were compared in order to determine if both younger and older knees function as pneumatophores, and if only the younger knees are capable of providing oxygen to roots in waterlogged soils. Our findings include: younger knees have the most aerenchyma tissue (living cells associated with air canals) and a thinner bark (likely pervious) on the distal tips. The older knees are more woody with distinct growth rings, exhibit less aerenchyma tissue, and have a much thicker (likely impervious) bark at the distal tip. The conclusion regarding the purpose of cypress knees is that the younger knees likely function as aerating organs (peumatophores) for the growing roots tips, while the older knees have reduced amounts of aerenchyma tissue and a thicker bark, and therefore may lose the ability to function as an aerating organ for the older roots.

39

EVALUATING THE ACCOTINK CREEK RESTORATION PROJECT FOR IMPROVING WATER QUALITY, IN-STREAM HABITAT, AND BANK STABILITY  

Increased urbanization results in a larger percentage of connected impervious areas and can contribute large quantities of stormwater runoff and significant quantities of debris and pollutants (e.g., litter, oils, microorganisms, sediments, nutrients, organic matter, and heavy me...

40

EVALUATING THE ACCOTINK CREEK URBAN STREAM RESTORATION PROJECT FOR IMPROVING WATER QUALITY, IN-STREAM HABITAT, AND BANK STABILITY  

Increased urbanization results in a larger percentage of connected impervious areas and can contribute large quantities of stormwater runoff and significant quantities of debris and pollutants (e.g., litter, oils, microorganisms, sediments, nutrients, organic matter, and heavy me...

 
 
 
 
41

Mapping and analyzing change of impervious surface for two decades using multi-temporal Landsat imagery in Missouri  

Human population growth and associated sprawl has rapidly converted open lands to developed use and affected their distinctive ecological characteristics. Missouri reflects a full range of sprawl characteristics that include large metropolitan centers, which led growth in 1980s, and smaller metropolitan and rural areas, which led growth in 1990s. In order to study the historical patterns of sprawl, there is a need to quantitatively and geographically depict the extent and density of impervious surface for three time periods of 1980, 1990, and 2000 for the entire state of Missouri. We mapped impervious surface using Sub-pixel Classifier(TM), an add-on module of Erdas Imagine for the three time periods, where impervious surface growth was derived as the subtraction of impervious surface mapp...

42

CONSTRUCTED WETLANDS VS. RETENTION POND BMPS: MESOCOSM STUDIES FOR IMPROVED POLLUTANT MANAGEMENT IN URBAN STORMWATER TREATMENT  

Increased urbanization has increased the amount of directly connected impervious area that results in large quantities of stormwater runoff. This runoff can contribute significant amounts of debris and pollutants to receiving waters. Urban watershed managers often incorporate b...

43

CONSTRUCTED WETLANDS VS. RETENTION PONDS BMPS: THE ROLE OF VEGETATION IN IMPROVED POLLUTANT MANAGEMENT FOR URBAN STORMWATER TREATMENT  

Increased urbanization has resulted in a larger percentage of impervious areas that produce large quantities of stormwater runoff and contribute significant amounts of debris and pollutants (e.g., litter, oils, heavy metals, sediments, nutrients, organic matter, and microorganism...

44

EVALUATION OF CONSTRUCTED WETLAND AND RETENTION POND BMPS FOR ATTENUATING MICROBIAL CONTAMINANTS IN URBAN STORMWATER RUNOFF  

This project investigated the use of constructed wetlands and retention ponds for decreasing microbial concentrations from urban stormwater runoff. Increased urbanization has resulted in a larger percentage of impervious areas which cause large quantities of stormwater runoff an...

45

Unitary plate electrode  

Nov 14, 1983 ... tive electrode with a conductive, impervious layer resis- ... tant mats by capillary action. The bipolar plates must ... acetate, a weak salt readily soluble in the sulfuric acid electrolyte. ..... cells, fuel cells, electrophoresis cells, etc.

46

Landscape characteristics affecting streams in urbanizing regions of ...  

Oct 4, 2012 ... Identifying relations between stream ecological condition and urban ... to effectively address planning and management needs in such areas. ... landscape pattern, land cover, land use, water quality, impervious surface ...

47

Film bonded fuel cell interface configuration  

The present invention relates to improved elements for use in fuel cell stacks, and more particularly, to a stack having a corrosion-resistant, electrally conductive, fluid-impervious interface member therein.

48

MARKET INCENTIVES AND NONPOINT SOURCES: AN APPLICATION OF TRADABLE CREDITS TO URBAN STORMWATER MANAGEMENT  

Excess stormwater runoff can cause serious pollution, habitat degradation and flooding in cities where growth in impervious surface area (such as pavement, buildings, etc.) has created a situation where stormwater runoff routinely exceeds the normal capacity of natural and constr...

49

A Proof of the Convexity of the Free Boundary for Porous Flow through a Rectangular Dam Using the Maximum Principle.  

The steady two-dimensional flow is considered under gravity of water from one reservoir to another reservoir through a porous rectangular isotropic homogeneous dam with impervious bottom. Using the maximum principle, a proof of the convexity of the free b...

50

A WATERSHED-LEVEL APPROACH TO STUDY THE PUTATIVE RELATIONSHIPS BETWEEN LANDUSE CHANGE AND SURFACE WATER FLOW ALTERATION  

Inter-generationally prudent management of watershed resources will require attention to the interdependence between shifting landuse distributions and their effects on watershed hydrology. Development and increased proportion of impervious surface area has been found to alte lan...

51

Drought, Urbanization Were Ingredients for Atlanta's Perfect Storm  

Mar 11, 2009 ... Does urban development have an effect on such a storm? ... areas because impervious surfaces like glass, metal, concrete and asphalt absorb, ... ultimately they added fuel to the fire of an already energized storm," he added.

52

Road runoff management using over-the-shoulder infiltration: real-scale experimentation.  

A new management policy regarding road runoff was proposed in 2002 by the Swiss Federal Office for the Environment (FOEN). This new concept is based on the diffuse infiltration of road runoff into embankment slopes, where soils will filter particles and contaminants. The shoulder lying between road surface and infiltration slopes must be impervious in order to maximise the amount of water reaching the slope and avoid losses in the road structure. The implementation of this new concept should lower the impact of roads on the environment, improve aquifer recharge and reduce construction costs. The Swiss Federal Road Office (FedRO) decided to carry out real-scale investigations regarding this new policy and thus commissioned the GEOLEP to design, build, and test 5 different shoulder structures. This paper presents the results of a 2-years survey of infiltration processes in these shoulders to establish the best performing structure. The first three shoulders were overlaid with 5 cm of gravel mixed with humus, gravel mixed with clay, and seeded with lawn, respectively. The latter two had impervious layers located 26 cm deep: the road bituminous basement (road base) was prolonged and coated with bitumen in the first case, and a sodic-bentonite geotextile was used in the second. Both were covered with gravel. All shoulders were equipped with basal collecting devices that measured hydraulic fluxes seeping through the shoulders. In total, 112 natural precipitations and 3 artificial events were monitored. Artificial events mimicked known transitory regimes (thunderstorms) or were performed with constant regime. The goal was to effectively assess infiltration processes in shoulders. Results showed that shoulders made of gravel and humus or lawn were highly ineffective (only 30 to 40% of runoff is conducted to the infiltration slope). Gravel and clay was more efficient with a proportion of approximately 60%. The shoulder with prolonged road base showed similar results since the bituminous coating was in fact rather permeable. The best results were exhibited by the shoulder waterproofed with bentonitic geotextile, which allowed no water to penetrate. This material already proved to be very powerful in groundwater catchments. The authors thus proposed a combination of sodic-bentonite geotextile covered by a gravel and clay mixture. This would be the most efficient shoulder: it will convey all the runoff to infiltration slopes, thereby optimising its filtration, which in turn will enhance environmental conditions in the vicinity of roads. PMID:19759460

53

Synegies Between Visible/Near-Infrared Imaging Spectrometry and the Thermal Infrared in an Urban Environment: An Evaluation of the Hyperspectral Infrared Imager (HYSPIRI) Mission  

A majority of the human population lives in urban areas and as such, the quality of urban environments is becoming increasingly important to the human population. Furthermore, these areas are major sources of environmental contaminants and sinks of energy and materials. Remote sensing provides an improved understanding of urban areas and their impacts by mapping urban extent, urban composition (vegetation and impervious cover fractions), and urban radiation balance through measures of albedo, emissivity and land surface temperature (LST). Recently, the National Research Council (NRC) completed an assessment of remote sensing needs for the next decade (NRC, 2007), proposing several missions suitable for urban studies, including a visible, near-infrared and shortwave infrared (VSWIR) imaging spectrometer and a multispectral thermal infrared (TIR) instrument called the Hyperspectral Infrared Imagery (HyspIRI). In this talk, we introduce the HyspIRI mission, focusing on potential synergies between VSWIR and TIR data in an urban area. We evaluate potential synergies using an Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) and MODIS-ASTER (MASTER) image pair acquired over Santa Barbara, United States. AVIRIS data were analyzed at their native spatial resolutions (7.5m VSWIR and 15m TIR), and aggregated 60 m spatial resolution similar to HyspIRI. Surface reflectance was calculated using ACORN and a ground reflectance target to remove atmospheric and sensor artifacts. MASTER data were processed to generate estimates of spectral emissivity and LST using Modtran radiative transfer code and the ASTER Temperature Emissivity Separation algorithm. A spectral library of common urban materials, including urban vegetation, roofs and roads was assembled from combined AVIRIS and field-measured reflectance spectra. LST and emissivity were also retrieved from MASTER and reflectance/emissivity spectra for a subset of urban materials were retrieved from co-located MASTER and AVIRIS pixels. Fractions of Impervious, Soil, Green Vegetation (GV) and Non-photosynthetic Vegetation (NPV), were estimated using Multiple Endmember Spectral Mixture Analysis (MESMA) applied to AVIRIS data at 7.5, 15 and 60 m spatial scales. Surface energy parameters, including albedo, vegetation cover fraction, broadband emissivity and LST were also determined for urban and natural land-cover classes in the region. Fractions were validated using 1m digital photography.

54

Modelling the impact of soakaway retrofits on combined sewage overflows in a 3km2 urban catchment in Copenhagen, Denmark  

Stormwater infiltration measures such as soakaways are expected to be part of future urban drainage systems. However, few studies exist on the effect of extensive stormwater infiltration through soakaways on the overall urban water system, including sewers and groundwater, at city catchment scale. In particular such estimates have not been made in real urban settings with multiple physical and structural constraints. This paper presents a methodology for conducting such an analysis, and provides quantitative estimates of the effects on the urban water flows. Using an interdisciplinary, three-step approach that employed GIS analyses and physically distributed, dynamic pipe flow modelling in an iterative manner, this study estimates the impact of infiltration on combined sewage overflows (CSOs) in a 3km2 urban catchment in Copenhagen. The first step was the creation of a baseline scenario. The second step led to a potential infiltration scenario where 65% of the total impervious area was connected to soakaways,and resulted in an estimated reduction in annual sewage overflow volume of 68%. This scenario was then further developed in the third step by adding groundwater constraints, which formed a more realistic scenario where only 8% of the impervious area was connected to soakaways and the reduction in CSO volume was 24%. The potential and realistic scenarios were modelled both with hydraulic coupling between soakaway and sewer, and as fully disconnected. Results show that infiltration is constrained mainly by the quality of the stormwater runoff from roads and limited land availability in the potential infiltration scenario, and by low-permeable soils and a problematically high groundwater level in the realistic infiltration scenario. The hydraulically coupled model gives higher CSO volume than the fully disconnected model for the potential infiltration scenario, whereas no difference is seen between these two models in the realistic infiltration scenario. The effect of infiltration on combined sewer overflows isthus expected to be limited in the case study area. General conclusions are that groundwater constraints are important to consider when evaluating the potential of infiltration-based stormwater management, and that it is important to include the hydraulic coupling between soakaways and sewers in models if soakaways are expected to give overflow to the sewers.

55

Identification of linear and threshold responses in streams along a gradient of urbanization in Anchorage, Alaska  

We examined biotic and physiochemical responses in urbanized Anchorage, Alaska, to the percent of impervious area within stream basins, as determined by high-resolution IKONOS satellite imagery and aerial photography. Eighteen of the 86 variables examined, including riparian and instream habitat, macroinvertebrate communities, and water/sediment chemistry, were significantly correlated with percent impervious area. Variables related to channel condition, instream substrate, water chemistry, and residential and transportation right-of-way land uses were identified by principal components analysis as significant factors separating site groups. Detrended canonical correspondence analysis indicated that the macroinvertebrate communities responded to an urbanization gradient closely paralleling the percent of impervious area within the subbasin. A sliding regression analysis of variables significantly correlated with percent impervious area revealed 8 variables exhibiting threshold responses that correspond to a mean of 4.4-5.8% impervious area, much lower than mean values reported in other, similar investigations. As contributing factors to a subbasin's impervious area, storm drains and roads appeared to be important elements influencing the degradation of water quality with respect to the biota.

56

Human-induced geomorphology: Modeling slope failure in Dominical, Costa Rica using Landsat imagery  

Unchecked human development has ravaged the region between Dominical and Uvita, Costa Rica. Much of the development transition has been driven by tourism and further foreign direct investment in residential, service and commercial enterprises. The resulting land-use/land-cover change has removed traditional forest cover in exchange for impervious surfaces, physical structures, and bare ground which is no longer mechanically supported by woody vegetation. Combined with a tropical climate, deeply weathered soils and lithography which are prone to erosion, land cover change has led to an increase in slope failure occurrences. Given the remoteness of the Dominical-Uvita region, its rate of growth and the lack of monitoring, new techniques for monitoring land use and slope failure susceptibility are needed. Two new indices are presented here that employ a Digital Elevation Model (DEM) and widely available Landsat imagery to assist in this endeavor. The first index, or Vegetation Influenced Landslide Index (VILI), incorporates slope derived from a DEM and Lu et al.'s (2007) Surface Cover Index to quantify vegetative cover as a means of mechanical stabilization in landslide prone areas. The second index, or Slope Multiplier Index (SMI), uses individual Landsat data bands and basic Landsat band ratios as environmental proxies to replicate soil, vegetative and hydrologic properties. Both models achieve accuracy over 70% and rival results from more complicated published literature. The accuracy of the indices was assessed with the creation of a landslide inventory developed from field observations occurring in December 2007 and November 2008. The creation of these indices represents an efficient and accurate way of determining landslide susceptibility zonation in data poor areas where environmental protection practitioners may be overextended, under-trained or both.

57

Continuous flow and temperature runoff monitoring of a green roof in the Pacific northwest[Vancouver Public Library green roof monitoring project  

Public Works and Government Services Canada (PWGSC) initiated a study to acquire information on Best Management Practices (BMPs) and Low Impact Development (LID) methods associated with green roof technologies. In June 2003, PWGSC partnered with Kerr Wood Leidal Associates Ltd. to conduct a year long monitoring project on the Vancouver Public Library (VPL) green roof. The green roof is inaccessible to the general public but can be viewed by occupants in the surrounding residential and commercial towers. The purpose of the project is to assess the performance of the green roof during the rainy and dry seasons. Data on air and runoff water temperature, soil moisture, relative humidity, rainfall, wind speed and direction, gust speed and solar radiation were collected. The information will be applied to a computer model that will predict stormwater impacts for various soil depths and climatic regions of the Pacific Northwest. This paper presented the first portion of that work highlighting the ability of the VPL green roof to reduce the total volume of runoff and attenuate peak flows. In particular, it presented stormwater quantity data, observations and findings for a period of eight months. The green roof was designed to replicate the Fraser River and the surrounding lands. The green roof on the White Rock Public Works building was also monitored, but the results are not yet available. Compared to a traditional impervious membrane roof, the green roof at the VPL provided a benefit in terms of total reduction in stormwater runoff through evaporation. The VPL green roof was able to attenuate the summer peak flows by more than 80 per cent and the small winter peak flows by approximately 30 per cent. However, it was unable to attenuate the peak flows from large storm events. 3 tabs., 9 figs.

58

Runoff Generation Processes At Headwater Scale In A Marly Torrential Catchment  

The study is carried out in a plot of 1330 m2 located on the experimental catchments of Draix (Alpes de Haute Provence, France). Approximately two thirds of the surface are made of a bare marly zone (marls of Callovo-Oxfordien called " Terres Noires "). The upper part is covered by a shrubby vegetation on a soil whose depth does not exceed 70 cm. The plot outlet is equipped with a V-notch weir and a stage recorder. Experiments of chemical and isotopic water tracing have been carried out on this site to (1) provide information about the flow processes (in relation with field observations and hydrometric measurements), (2) to test the relevance of isotope tracers to define at this scale the residence time distribution of new water, (3) to compare the results with those obtained using an hydrological model. For these objectives, a further equipment was added on the plot in spring 2001 : sequential sampler for the collection of discrete rainfall increments (increments of 3 mm), porous ceramic cups for the sampling of soil water and automatic sampler at the outlet. 3 flood events were sampled between the 4th and 25th July 2001. The rainfall amounts were 28.4 mm, 54.2 mm and 29.2 mm producing peak flows of 5.7 l/s, 16.4 l/s and 13.9 l/s, respectively. Despite the physical context (steep slope, impervious material), the discharge coefficients donSt exceed 30 %. This result emphasises the impact of the soil layer (and perhaps the marl itself) on water storage. The storage time and the delay of water transfer are studied using water tracing. Water samples were analysed for major species, dissolved organic carbon and oxygen-18. The first results confirm the important role of the soil on water quality. The chemographs show that a pre-event water contributes to the flow. This impact on water quality may be explained by a rapid movement of water through the subsurface into the soil macropores. The analysis of the input-output relation for isotope concentrations and the application of the EMMA approach using chemical tracers allow to characterise the variation of the hydrological behaviour between 3 successive flood events.

59

Quantifying multi-temporal urban development characteristics in Las Vegas from Landsat and ASTER data  

Urban development has expanded rapidly in Las Vegas, Nevada of the United States, over the last fifty years. A major environmental change associated with this urbanization trend is the transformation of the landscape from natural cover types to increasingly anthropogenic impervious surface. This research utilizes remote sensing data from both the Landsat and Terra-Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) instruments in conjunction with digital orthophotography to estimate urban extent and its temporal changes by determining sub-pixel impervious surfaces. Percent impervious surface area has shown encouraging agreement with urban land extent and development density. Results indicate that total urban land-use increases approximately 110 percent from 1984 to 2002. Most of the increases are associated with medium-to high-density urban development. Places having significant increases in impervious surfaces are in the northwestern and southeastern parts of Las Vegas. Most high-density urban development, however, appears in central Las Vegas. Impervious surface conditions for 2002 measured from Landsat and ASTER satellite data are compared in terms of their accuracy. ?? 2008 American Society for Photogrammetry and Remote Sensing.

60

Stormwater impacts on a coldwater resource  

The Kinnickinnic River in west-central Wisconsin is classified as a state outstanding resource water, and is a premiere Midwest trout stream, with a self-sustaining brown trout population. River Falls, Wisconsin (population 10,000), located in the heart of the Kinnickinnic River watershed, is developing rapidly because of its proximity to the Minneapolis/St. Paul, MN metropolis. With increasing residential, commercial, and industrial development, concerns about urban stormwater impacts on the Kinnickinnic River are also increasing. These impacts include higher stream flows, thermal pollution, and sedimentation, all of which pose threats to trout and aquatic habitat. In response to the concern about thermal pollution, the Kiap-TU-Wish Chapter of Trout Unlimited established a temperature monitoring network in 1992, at four Kinnickinnic River locations throughout River Falls. Data-logging thermometers continuously record stream temperatures at 10-minute intervals, clearly demonstrating stormwater-induced thermal changes. Rapidly-increasing stream temperatures are often evident at locations downstream from stormwater outfalls during summer rainfalls, and stormwater temperatures may exceed 80 F. The thermal impacts of two small municipal hydropower impoundments have also been documented. Storm event-based composite sampling of residential, commercial, and industrial areas of River Falls (1992) suggests that these areas are highly susceptible to soil erosion, with sediment concentrations greater than the NURP average. Concentrations of some sediment-associated metals are also high. In 1994, River Falls developed a stormwater management plan for the Kinnickinnic River. Plan recommendations include a limitation of 12% impervious area within the city, proper detention pond design to mitigate thermal impacts, stringent erosion control ordinances, additional stormwater BMP`S, and increased public awareness and involvement.

 
 
 
 
61

Bi-scale analysis of multitemporal land cover fractions for wetland vegetation mapping  

Land cover fractions (LCFs) derived through spectral mixture analysis are useful in understanding sub-pixel information. However, few studies have been conducted on the analysis of time-series LCFs. Although multi-scale comparisons of spectral index, hard classification, and land surface temperature images have received attention, rarely have these approaches been applied to LCFs. This study compared the LCFs derived through Multiple Endmember Spectral Mixture Analysis (MESMA) using the time-series Landsat Thematic Mapper (TM) and Terra Moderate Resolution Imaging Spectroradiometer (MODIS) data acquired in the Poyang Lake area, China between 2004 and 2005. Specifically, we aimed to: (1) propose an approach for optimal endmember (EM) selection in time-series MESMA; (2) understand the trends in time-series LCFs derived from the TM and MODIS data; and (3) examine the trends in the correlation between the bi-scale LCFs derived from the time-series TM and MODIS data. Our results indicated: (1) the EM spectra chosen according to the proposed hierarchical three-step approach (overall, seasonal, and individual) accurately modeled the both the TM and MODIS images; (2) green vegetation (GV) and NPV/soil/impervious surface (N/S/I) classes followed sine curve trends in the overall area, while the two water classes displayed the water level change pattern in the areas primarily covered with wetland vegetation; and (3) GV, N/S/I, and bright water classes indicated a moderately high agreement between the TM and MODIS LCFs in the whole area (adjusted R2 ? 0.6). However, low levels of correlations were found in the areas primarily dominated by wetland vegetation for all land cover classes.

62

Energy balance modelling applied to a comparison of white and green roof cooling efficiency  

Rooftops in urban areas comprise a substantial portion of the total land surface area, and their physical properties are important determinants of the urban environment. Black impervious rooftops contribute to heat island effects and combined sewage-stormwater overflows. Green rooftops can be used to mitigate these environmental problems if implemented on a wide scale. This study used a simple energy balance model to study the impact of roof types on urban heat island and building energy consumption rates. The model included equations for shortwave and longwave radiation as well as convective, latent and conductive heat fluxes. A temperature gradient model with a wind-dependent coefficient was used to measure convection. Latent heat flow for green roofs was modelled using the Bowen ratio. An equilibrium model was used to determine energy balance. Convection coefficients and the Bowen ratio were determined using a hierarchical approach applied to field data for 3 control and 3 green roofs monitored at Pennsylvania State University. The model showed good agreement with field data. A calibrated control roof model and data were then used to determine the performance of green roofs compared to white roofs. Results showed that in order to maintain their effectiveness, white roofs require regular washing, as their effectiveness drops due to natural weathering and soiling. The experiments suggested that green roofs cool as effectively as white roofs, with the added benefit of maintaining lower temperatures in the rooms beneath the roofs. It was concluded that although green roofs are more expensive than white roofs, the benefits of green roofs make them more desirable and cost-effective. White roofs offer surface cooling benefits, but require burdensome maintenance to be fully effective. 12 refs., 6 figs.

63

Green roof runoff water quality  

From 1997 to 2001 the rate of urban development averaged 890,000 ha/year, resulting in increased volumes of stormwater runoff and water quality problems throughout affected watersheds. Green roofs have been suggested as a method to reduce these impacts by reducing the amounts of impervious surfaces within a developed zone. The stormwater advantages offered by green roofs include direct retention of a portion of the rainfall, as well as delaying the runoff peak and decreasing the peak rate of runoff from the site. Growing medium depth and porosity plays a significant role in stormwater retention and plant growth. Plants provide shade to the surface below the foliage, intercept rainfall, and slow the direct runoff from sloped roofs. In addition to reducing runoff water quantity green roofs also have the potential to influence runoff water quality. In this study, stormwater runoff samples were collected from 5 small buildings at the Center for Green Roof Research at Rock Springs, Pennsylvania during the period from January 2005 through May 2006. Green roofs had many positive impacts on stormwater runoff quality in this study, with the most consistent benefit being the higher pH in runoff from green roofs. Another benefit was a pronounced reduction in the observed nutrient loading rate for nitrate. Total loading for metals was also reduced. The concentration in runoff solution and total loading of other common soil and fertilizer salts, phosphorous, potassium, calcium and magnesium was increased in the runoff from green roofs. However, this was seasonal and similar to what might be expected as leaching from any other planted system in the landscape. Concentrations of lead and mercury were below detection limits. 7 refs., 2 tabs., 9 figs.

64

Towards Sustainable Watershed Dvelopment: A Geographic Information Systems based Approach  

With an unprecedented projection of population and urban growth in the coming decades, assessment of the long-term hydrologic impacts of land use change is crucial for optimizing management practices to control runoff and non-point source (NPS) pollution associated with sustainable watershed development. Land use change, dominated by an increase in urban/impervious areas, can have a significant impact on water resources. Non-point source (NPS) pollution is the leading cause of degraded water quality in the US and urban areas are an important source of NPS pollution. Most planners, government agencies, and consultants lack access to simple impact-assessment tools despite widespread concern over the environmental impacts of watershed development. Before investing in complex analyses and customized data collection, it is often useful to utilize simple screening analyses using data that are already available. In this paper, we discuss such a technique for long-term hydrologic impact assessment (L-THIA) that makes use of basic land use, soils and long-term rainfall data to compare the hydrologic impacts of past, present and any future land use change. Long-term daily rainfall records are used in combination with soils and land use information to calculate average annual runoff and NPS pollution at a watershed scale. Because of the geospatial nature of land use and soils data, and the increasingly widespread use of GIS by planners, government agencies and consultants, the model is integrated with a Geographic Information System (GIS) that allows convenient generation and management of model input and output data, and provides advanced visualization of the model results. An application of the L-THIA/NPS model on the Little Eagle Creek (LEC) watershed near Indianapolis, Indiana is illustrated in this paper. Three historical land use scenarios for 1973, 1984, and 1991 were analyzed to track land use change in the watershed and to assess the impacts of land use change on annual average runoff and NPS pollution from the watershed and its five sub-basins. Results highlight the effectiveness of the L-THIA approach in assessing the long-term hydrologic impact of urban sprawl. The L-THIA/NPS GIS model is a powerful tool for identifying environmentally sensitive areas in terms of NPS pollution potential and for evaluating alternative land use scenarios to enhance NPS pollution management. Access to the model via the INTERNET enhances the usability and effectiveness of the technique significantly. Recommendations can be made to community decision makers, based on this analysis, concerning how development can be controlled within the watershed to minimize the long-term impacts of increased stormwater runoff and NPS pollution for better management of water resources.

65

Optimization of the concrete delayed deformations by Kalman filter; Optimisation des deformations differees du beton par filtre de Kalman  

Imperviousness of French nuclear power plants containments has to secure radioactive products confinement during incident or accident. Temporal evolution of containments is obtained through the numerical model Code Aster that purpose is to detect if some fissure could appear and as a consequence, imperviousness lost. In parallel, sensors are placed all around the containments to follow real time deformations. In this paper, Kalman filter analysis of an extensometer data is used to optimize eight parameters of the numerical model Code Aster. This method allows us to improve the concrete delayed behaviors modelization and supplies uncertainties to the forecast of the containment evolution. (author)

66

A multiprocess model of adaptable complexity for impervious surface detection  

Accurately estimating impervious surfaces is of considerable importance towards understanding human impacts on the environment. In this article, a sequential multiprocess model is presented to estimate the distribution of impervious surfaces using Landsat Enhanced Thematic Mapper Plus (ETM+) satellite imagery. Unlike typical single-thread classification processes, the multiprocess model consists of a series of classification steps. By separating the classification task into several subtasks of variable difficulty, multiple classifiers are integrated while adapting to different levels of complexity. The results show statistically significant improvements for the proposed model. An interesting finding is the uneven distribution of simple classifiers in either highly rural or suburban/urban a...

67

Satellite remotely-sensed land surface parameters and their climatic effects for three metropolitan regions  

By using both high-resolution orthoimagery and medium-resolution Landsat satellite imagery with other geospatial information, several land surface parameters including impervious surfaces and land surface temperatures for three geographically distinct urban areas in the United States - Seattle, Washington, Tampa Bay, Florida, and Las Vegas, Nevada, are obtained. Percent impervious surface is used to quantitatively define the spatial extent and development density of urban land use. Land surface temperatures were retrieved by using a single band algorithm that processes both thermal infrared satellite data and total atmospheric water vapor content. Land surface temperatures were analyzed for different land use and land cover categories in the three regions. The heterogeneity of urban land s...

68

Quantifying the Components of Impervious Surfaces  

This study's objectives were to (1) determine the relative contribution of impervious surface individual components by collecting digital information from high-resolution imagery, 1-meter or better; and to (2) determine which of the more advanced techniques, such as spectral unmixing or the application of coefficients to land use or land cover data, was the most suitable method that could be used by State and local governments as well as Federal agencies to efficiently measure the imperviousness in any given watershed or area of interest.\\r\

69

Analyzing the temporal variability of the hydrological connectivity to assess the critical source areas for pesticides losses  

In order to propose relevant pesticide mitigation strategies within agro-systems, i.e. grass strips or storm basins, it is necessary to identify the areas that mostly contribute to pesticide losses in surface water. At the agricultural catchment scale, this identification requires assessing the hydrological connectivity between plots and the river network. When the infiltration-excess (IE) runoff mechanism dominates, a plot can be disconnected from the hydrological network if landscape components such as hedges block or limit the runoff generated. Conversely, some elements as ditches or road network can enhance the runoff from upstream to downstream areas and increase the pesticide losses. The degree of connectivity is closely linked both to the characteristics of the rainfall event considered and the initial moisture content of soil. This study is aimed at analyzing the variability of connectivity degree according to the return period of rainfall event and the initial soil moisture content. This study was conducted on a vineyard catchment area located in the Alsatian piedmont (Rouffach, France). The transport of pesticides in surface water represents regionally a main threat because the runoff produced on the vineyard area rapidly flows towards downstream water bodies, which are closely linked to the large Rhenan aquifer. The Hohrain catchment, 40 ha, comprises more than 120 farming plots and a dense, mostly impervious road network. Hydrograms and pesticide chemograms are available for each storm event during the vine growing season since April 2003. The topographical information is provided by the digital elevation model obtained by the lidar technology. A field campaign allowed obtaining 1) the land use characteristics, including the identification of soil and water conservation methods, such as grass strips within or bordering the cropped area, and 2) the main soil hydrodynamic characteristics. The physically-based model LISEM (Limburg Soil Erosion Model) was retained to perform this analysis. This fully distributed model allows taking into account the spatial and temporal variability of hydrological processes, i.e. rainfall, interception, surface storage in micro-depression, infiltration, vertical movement of water in the soil, overland flow, and channel flow within the catchment. To correctly take into account the landscape components, e.g. grass strips, hedges and ditch networks, a 2 m grid cell size was used. Preliminary studies have demonstrated the predictive ability of the LISEM model in the Hohrain catchment in terms of both discharge and runoff pathway within the catchment with a reduced calibration step. To assess the impact of both the rainfall intensity and initial moisture conditions on the variability of the hydrological connectivity modeling with LISEM, six rainfall events were considered with associated return periods of 2, 5, 10, 20, 50 and 100 years respectively. Different initial moisture contents were considered based on the range of observed values at the field-scale. The hydrological connectivity is defined here as the upstream to downstream connectivity of active areas with respect to runoff process. The indicator of the connectivity variability used was the percentage of the catchment in which the active areas with respect to runoff are really connected to the outlet. The results showed that a risk of pesticide transfer can be associated for a combination of rainfall event intensity and initial moisture content. The results also underscored the limit of the Hydrological Response Unit (HRU) concept, especially for small catchment areas. Indeed, observed and simulated active areas (i.e., generating runoff) were smaller than the HRU obtained by crossing land use and soil type. This study showed that a detailed integration of the connectivity at the catchment scale is crucial to closely assess the dynamics of pesticides transfers. Keywords: Hydrological connectivity, pesticide transfer, vineyard catchment, LISEM model

70

Geomorphic implications of resistant bedrock in the 'uniform' sandstone beds of the Tyee Formation, Oregon Coast Range  

Differences in rock properties are reflected in landscape morphology and all else equal, harder rock should produce steeper hillslopes. While this concept is oft-stated, it is seldom characterized. In the humid, soil-mantled mountainous landscape of the Oregon Coast Range (OCR), steep hillslopes are sculpted in rhythmically bedded sandstones of the Eocene Tyee Formation where subtle variations in rock properties appear to have profound geomorphic implications. Numerous resistant beds appear unfractured and impervious to soil production mechanisms such as tree root activity and mountain beaver burrowing. Here we present observations from the field, thin section petrology, rock mechanics, and airborne lidar to characterize minor grain-scale differences in rock properties and their influence on rock strength and fracture density and thus hillslope processes and morphology. In Franklin Creek watershed, bands of cliff-forming resistant sandstone crop out in ~1-10m thick swaths. These cliff-forming bands are absent in the adjacent Harvey watershed due to the local structural setting. Harvey watershed is characterized by 'classic' OCR topography -repeating ridge and valley sequences, while Franklin watershed exhibits hanging valleys and changes in slope and curvature above the cliff-forming beds. Although calcite-cemented sandstone beds are reported in the literature for the Tyee Fm, we find no evidence for calcite in the resistant sandstone beds. Instead, preliminary petrographic analysis suggests that diagenetic clay rims in the resistant rock types may account for their higher strength. Preliminary point load and indirect tensile strength tests comparing 'typical' and 'resistant' beds of the Tyee Formation show a significant difference, with indirect tensile strength measurements of 0.83 ± 0.1 MPa for typical rock and 2.06 ± 0.7 MPa for the resistant rock type. Using airborne lidar data we explore how these resistant beds modulate topography. Soil production in much of the OCR is driven by tree turnover and root growth that generates a topographic signature via pit and mound features. To determine if resistant rock swaths lack this biotic signature, we compared topographic profiles from typical soil-mantled and resistant rock settings. To quantify how hillslopes adjust their form with and without resistant rock beds, we calculated distributions of gradient, hillslope curvature and roughness in both catchments. We also test whether a critical bed thickness or slope position of the resistant beds is required for persistent base level and therefore controls the presence or absence of hanging valleys. Based on field observations in multiple watersheds in the Oregon Coast Range, the resistant rock type has a lower fracture density than the typical rock type, and does not produce soil. At the watershed scale this resistant rock type creates knickpoints, leading to the formation of hanging valleys above and over-steepened hillslopes below, suggesting that rock properties and fracture density may be a first order control on soil production and hillslope processes.

71

Slope stability under rapid drawdown conditions  

The rapid drawdown condition arises when submerged slopes experience rapid reduction of the external water level. Classical analysis procedures are grouped in two classes: the “stress-based” undrained approach, recommended for impervious materials and the flow approach, which is specified for rigid ...

72

Imperviousness of the hydrophobic silica aerogels against various solvents and acids  

The experimental results on the imperviousness of the silica aerogels against various organic solvents and acids, are reported. Various types of hydrophobic silica aerogels were prepared using methyltrimethoxysilane (MTMS); tetraethoxysilane (TEOS) with ethyltriethoxysilane (ETES) and phenyltriethoxysilane (PTES) as co-precursors. The organic solvents used were: methanol, ethanol and acetone, and the acids used were: hydrochloric acid (HCl), nitric acid (HNO3) and sulphuric acid (H2SO4). The imperviousness of the aerogels against these solvents and acids were tested with the variation of the percentage of organic solvents and acids in water from 10 to 100% and was characterized by the contact angle measurements. It was observed that in all the cases, the contact angle decreased with an increase in the percentage of solvent in water. While there was no absorption of the solvent up to 20% in water by the ETES and PTES modified aerogels, the MTMS-based aerogels showed the imperviousness up to 60% of the solvent in water. The MTMS aerogels were also impervious against all the three acids up to 100%, while the ETES and PTES modified aerogels could withstand only up to 80% of acids in water.

73

Runoff and Infiltration Dynamics on Pervious Paver Surfaces  

When natural or agricultural land is converted for (sub)urban or commercial use, the addition of impervious surfaces becomes a dominating factor in the new urban hydrologic regime. To help minimize the negative hydrologic effects of this land use change, urban best management practices (BMPs) are co...

74

Spatial metrics modeling to analyse correlations between urban form and surface water drainage performance.  

Cities exhibit unique spatial patterns, and thus a distinctive heterogeneity. At different scales of influence, they introduce changes in the physical properties of the natural environment, as the diffusion of impervious surfaces. While climate change is expected to increase the frequency of hazard...

75

Urban Sustainability and Public Health: Throwing the Bath Water Out and Not the Baby  

This slide presentation reviews the affect of urbanization on community health. It exams urbanization trends in the Atlanta metro area and includes information on impervious surfaces, air quality, mitigation strategies, spatial growth modeling, land use, public health surveillance and different data collection methods.

76

QUANTIFICATION OF URBANIZATION IN EXPERIMENTAL WATERSHEDS  

Although urbanization has a major impact on watershed hydrology, there have not been many studies to quantify how basic hydrological relationships are altered by the addition of impervious surface under controlled conditions. The USDA-ARS and USEPA have jointly initiated a pilot program to study the...

77

IMPACTS OF URBANIZATION ON WATERSHED HYDROLOGIC FUNCTION  

Although urbanization has a major impact on watershed hydrology, there have not been studies to quantify basic hydrological relationships are altered by the addition of impervious surfaces. The USDA-ARS and USEPA-ORD-NRMRL have initiated a pilot program to study the impacts of different extents and...

78

Solar sheds; Solarstadel  

PV systems on buildings get more funds than open-field PV systems. This is an attempt to prevent urbanization and impervious surface changes. Agricultural buildings are an exemptions. As a result, hay sheds and tool sheds are getting more attention than ever before.

79

EVALUATION OF URBANIZATION IMPACTS ON HYDROLOGY - LABORATORY AND FIELD APPROACHES  

Although urbanization has a major impact on watershed hydrology, there have not been many studies to quantify how basic hydrological relationships are altered by the addition of impervious surface under controlled conditions. In addition, few studies have been conducted to quanti...

80

Mechanisms of gas transport in clay barriers Mecanismos de transporte de gas en barreras de arcilla  

Laboratory experiments show that preferential paths develop through saturated impervious clay bodies. A procedure to integrate gas transmission discontinuities into a general THM formulation is described. The technique has been incorporated into a general purpose FE THM code (CODE_BRIGHT) and it has...

 
 
 
 
81

A biphasic poroelastic analysis of the flow dependent subcutaneous tissue pressure and compaction due to epidermal loadings: Issues in pressure sore  

A layer of skin and subcutaneous tissue on a bony substratum was modeled as a homogeneous layer of biphasic poroelastic material with uniform thickness. The epidermal surface and the bony interface were taken to be impervious. The soft tissue on the bony interface was assumed either fully adhered or...

82

Circulating gamma delta T cells are activated and depleted during progression of high-grade gliomas: Implications for gamma delta T cell therapy of GBM  

Glioblastoma multiforme (GBM) remains frustratingly impervious to any existing therapy. We have previously shown that GBM is sensitive to recognition and lysis by ex vivo activated gamma delta T cells, a minor subset of lymphocytes that innately recognize autologous stress-associated target antigens...

83

ROENTGEN RAY INTOXICATION : III. THE PATH OF A BEAM OF HARD RAYS IN THE LIVING ORGANISM.  

X-rays which injure intestinal epithelium (and presumably other body or tumor cells) travel in straight lines from the target through the living tissues, forming a cone or beam of rays as controlled by impervious screens. It is probable that secondary radiation is formed, especially deep in the bod...

84

Film bonded fuel cell interface configuration  

An improved interface configuration for use between adjacent elements of a fuel cell stack. The interface is impervious to gas and liquid and provides resistance to corrosion by the electrolyte of the fuel cell. A multi-layer arrangement for the interface provides bridging electrical contact with a hot-pressed resin filling the void space.

85

Crucible cast from beryllium oxide and refractory cement is impervious to flux and molten metal  

Crucible from a mixture of a beryllium oxide aggregate and hydraulic refractory cement, and coated with an impervious refractory oxide will not deteriorate in the presence of fused salt- molten metal mixtures such as uranium- magnesium-zinc-halide salt systems. Vessels cast by this process are used in the flux reduction of oxides of thorium and uranium.

86

CONTROLLING EXCESS STORM WATER RUNOFF WITH TRADABLE CREDITS  

Development that increases the impervious surface in a watershed causes excess storm water runoff (SWR) that has been identified as a major contributor to stream and riparian habitat degradation. Reduction of storm water runoff can be achieved through establishment of a number of...

87

CONTROLLING STORM WATER RUNOFF WITH TRADABLE CREDITS FOR IMPERVIOUS SURFACES  

Storm water flow off impervious surface in a watershed can lead to stream degradation, habitat alteration, low base flows and toxic leading. We show that a properly designed tradable runoff credit (TRC) system creates economic incentives for landowners to employ best management p...

88

IMPREGNATION OF CARBONACEOUS MATERIALS WITH EPOXY RESINS  

Baked, impervious carbon articles may be produced by impregnating carbonaceous materials with a thermosetting epoxy resin and curing with dicyanamide solution. Data are presented on the pot life of various epoxy impregnant compositions and on the properties of impregnated graphite bars. (D.L.C.)

89

Roof storage systems: Modelling and performance’s comparison  

Rainwater runoff problems have become critical in large cities because of the increasing imperviousness of surfaces. Best practices to manage urban runoff improve water infiltration and evaporation through green areas establishment and, therefore, natural hydrological cycle restoration. The aim is t...

90

Remote sensing based evapotranspiration and runoff modeling of agricultural, forest and urban flux sites in Denmark: From field to macro-scale  

Evapotranspiration (E) and runoff (RT) was modeled for the island of Sjælland (?7330 km2) in Denmark at multiple spatial scales encompassing agricultural, forest and urban land surfaces. National data were used to represent spatial variations in climate, soil properties and lower boundary conditions, and the EOS/MODIS Normalized Difference Vegetation Index (NDVI) was used to map (a) the temporal development in leaf area index for agricultural fields, (b) a dynamic “canopy” coefficient (Kc) of forests being scaled between its minimum and maximum values for use in the FAO Penman–Monteith equation, and (c) the impervious land cover fraction of urban regions. At field level, the use of local-scale model parameters, NDVI time series and site-specific methodologies to simulate E of the 3 major land surface types (agricultural land, forests and urban regions) explained 67–79% of the observed variability in eddy covariance latent heat fluxes. The “effective” spatial resolution needed to adopt local-scale model parameters for spatial-deterministic hydrological modeling was assessed using a high-spatial resolution (30 m) variogram analysis of the NDVI. The use of the NDVI variogram to evaluate land surface heterogeneity is based on the assumption that sub-class soil heterogeneity can be indirectly represented by the observed spatial variations in NDVI due to its close affiliation with vegetation growth, soil water uptake and evapotranspiration. Multiple spatial resolution water balance simulations were compared to validate the identified effective spatial resolution (500 m) model representation of land cover, NDVI and drainage pattern. Simulated RT of 30 catchments were compared with the fast-flow component of stream discharge data (Q ? Qb) which is insensitive to groundwater abstraction and most sensitive to the spatial land surface representation. A good agreement was observed in the timing and size of peak flows in catchment dominated by agricultural, forest and urban land uses in periods when E has important control on the water balance and soil water percolation to groundwater is negligible (Days 125–300). The presence/absence of pipe drains, urban surface runoff and forest parameterization cause very large differences in the water balance of agricultural, forest and urban regions. The results show that the use of local-scale standard model parameters and NDVI time series representing agricultural, forest and urban land surfaces in physically based hydrological modeling makes it possible to reproduce much of the observed variability (48–73%) in stream flow (Q ? Qb) when data and modeling is applied at an effective spatial resolution capable of representing land surface heterogeneity. In order to further improve the results, (1) advanced spatial parameterization methods are needed to improve the modeling of bare soil E of agricultural fields, (2) the impact of local conditions, such as tree age and nutrient levels, should be used to parameterize the maximum Kc used for forest E modeling, (3) high accuracy remote sensing based estimation of vegetation parameters is particularly important during sparsely vegetated conditions, and (4) the use of component stream flow data to evaluate the physical consistency of spatial-deterministic models appears to be feasible and should be further explored.

91

Análise temporal da permeabilidade da superfície urbana da sub-bacia do córrego centenário em Lavras, MG/ Temporal analysis of permeability urban surfaces locaty of the Centenário sub-basin creek in Lavras, MG  

Abstract in portuguese Nos últimos anos, séries de estudos têm sido realizadas por estudiosos de diferentes áreas para estabelecer os efeitos da urbanização na hidrologia de sub-bacias. O processo de urbanização freqüentemente produz alterações na drenagem da água pluvial. Um SIG com dados cadastrais planaltimétricos e fotografias aéreas permitiram estudar a ocupação em 3 diferentes períodos (1999, 1986 e 1971) na sub-bacia do Centenário, na cidade de Lavras, MG. Objetivou-se (more) com este estudo realizar a análise temporal da permeabilidade da superfície na sub-bacia do Centenário comparando os 3 períodos. A permeabilidade da superfície urbana foi obtida pela análise da ocupação dos quarteirões por área construída ou pavimentada. Os resultados permitiram verificar que a permeabilidade da superfície decaiu de 1971 para 1999. Nestes anos a área urbana cresceu reduzindo a permeabilidade do solo da sub-bacia. Conclui-se que, sendo óbvio que a urbanização causou impactos na sub-bacia, as metodologias utilizadas para essas análises foram muito eficientes para determinar os impactos de superfícies impermeáveis. Abstract in english Over the past years, a series of studies have been undertaken by scientists of different areas, to assess the effects of urbanization on the hidrology of subbasins. The urbanization process has frequently been done alterations on the drainage of pluvial water. A GIS data base containing the cadastral planiltimetric charts and aerial photographies allowed to study the land occupation in three different periods (1999, 1986 and 1971) of the Centenário Subbasin in Lavras cit (more) y, MG. So, the subject of this study was to realize a temporal analysis of the surface permeability of the Centenário subbasin comparing the three periods. The urban surface permeability was avaibled by the analysis of the city's squares occupation per builted or paved area. The results permitted verify that the surface permeability downed from 1971 to 1999 years. In these years the urban area growed up avoiding the soil subbasin permeability. The conclusion that urbanization caused impacts on the subbasin was obvious, however the methodologies employed for the analysis in this work were too much efficient to determine the impacts of impervious surfaces.

92

Effects Of Bedrock Shape And Hillslope Gradient On The Pore-Water Pressure Development: Implication For Slope Stability  

Shallow Landslides are one of the most important causes of loss of human life and socio-economic damage related to the hydro-geological risk issues. The danger of these phenomena is related to their speed of development, the diffculty of foreseeing their location, and the high density of individual phenomena, whose downhill trajectories have a relevant probability of interfering with urbanized areas. Research activity on precipitation-induced landslides has focused mainly on developing predictive understanding of where and when landslides are likely to occur. Nevertheless, some major aspects that may be related to activation of landslides have been poorly investigated. For instance, landslide susceptibility zones are generally predicted assuming constant thickness of soil over an impervious bedrock layer. Nevertheless, recent studies showed subsurface topography could be a first order control for subsurface water-flow dynamics, because of the effects of its own irregular shape. Tromp-van Meerveld and McDonnell (2006) argued that connectivity of patches of transient saturation were a necessary prerequisite for exceeding the rainfall threshold necessary to drive lateral flow. Connectivity - "how the hillslope architecture controls the filling and spilling of isolated patches of saturation" (Hopp and McDonnell, 2009) - appears to be a possible unifying concept and theoretical platform for moving hillslope and watershed hydrology forward. Connectivity could also have important implications on triggering of shallow landslides, because the particular shape of bedrock may limit the water-flow downhill. Here we present a number of virtual numerical experiments performed to investigate the role of bedrock shape and hillslope gradient on pore-water pressure development. On this purpose, our test is represented by the subsurface topography of the Panola Experiment Hillslope (PEH). That is because scientific literature on PEH provides substantial documentation about the role of bedrock layer on subsurface water-flow dynamics. We also exploit the concept of Downslope Index (DWI) (Hjerdt et al., 2004) and Upslope Contributing Area (UCA) as indicators of the areas more susceptible to landslide. The results indicate that bedrock shape influences the max pore-water pressure, even with different hillslope gradients; meanwhile, hillslope gradient affects the persistence-time of the max pore-water pressure. Moreover, results suggest DWI as an useful index to improve the capability of the very-used SHALSTAB model to assess for landslide susceptibility areas.

93

Runoff response for a peri-urban watershed in the Atlantic Forest Biome, southern Brazil, using the Kineros2 model  

Simulating the hydrologic response of a watershed for different scenarios is an important tool for assessing the rational use of the land and natural resources, especially in environments where urbanization is not ever an organized procedure. This study used the Kineros2 event oriented hydrological model to simulate the runoff response of a 4.9 km2 peri-urban basin located in the Atlantic Forest biome in Southern Brazil, with 47% of the area being impermeable. The goal of the simulations was to estimate the characteristic parameters of the soils and land cover of the watershed to then enable the prediction of basin response for different land uses. To acheive this objective, the responses of ten measured rainfall-runoff events were used to calibrate five parameters of the model. The PEST (Model-Independent Parameter Estimation and Uncertainty Analysis) package was used for automatic calibration of the model parameters. The quality of results is shown in Nash-Sutcliffe efficiency index values varying from 0.64 up to 0.98, with an average value of 0.88. The average absolute error in the simulated peak flow was 4.5% and 20.7% in the simulated runoff volume. A cross-validation using the same events used in the calibration and using average values of the calibrated parameters. gave Nash-Sutcliffe index values varying from 0.26 up to 0.92, with an average value of 0.73. The average absolute error in the simulated peak flow and runoff volume were 22.7% and 25.6%, respectively. We used two validated events to simulate distinct scenarios, being representative of a wet and of dry antecedent moisture conditions. For a scenario of a totally forested land cover, the simulated peak flow and runoff volume for a dry condition changed -53% and -46% respectively, and for a wet condition, -63% and -41% respectively, relatively to the present land use. For a complete pasture land use, the simulated peak flow and runoff volume for a dry condition changed -31% and -27% respectively and for a wet condition, -43% and -36% respectively, relatively to the present land use. If the present pattern of urbanization is applied to the whole area of the basin, an impermeable area of 81% would be achieved and the simulated peak flow and the runoff volume for a dry condition would be changed +24% and +25%, respectively, and for a wet condition, +44% and +25% respectively, relatively to the present land use. Finally, if the entire basin is considered impervious, for a dry condition, these changes would be in +101% and +65% respectively and, for a wet condition, in +158% and +87% respectively, relatively to the present land use.

94

Integrated assessment of climate change and urbanization impact on adaptation strategies: a case study in two small Korean watersheds  

This study develops an integrated approach to assess climate change and urbanization impacts on adaptation strategies in watersheds. We considered the two adaptation strategies for two small watersheds in Korea: the redevelopment of an existing reservoir and the reuse of highly treated wastewater treatment plant (WWTP) effluent. Climate change scenarios were obtained by statistically downscaling the predicted precipitation and temperature with a global climate model (A1B and A2), and urbanization scenarios were derived by estimating the impervious area ratios with an impervious cover model. With the climate change and urbanization scenarios, we used the Hydrological Simulation Program-Fortran model to derive the flow and biochemical oxygen demand (BOD) concentration (conc.) duration curves...

95

HuBac and nifH source tracking markers display a relationship to land use but not rainfall  

Identification of the source of fecal pollution is becoming a priority for states and territories in the U.S. in order to meet water quality standards and to develop and implement total maximum daily loads. The goal of this research was to relate microbial source tracking (MST) assay concentrations to land use and levels of impervious surfaces in order to gauge how increasing development is associated with human fecal contamination in inland watersheds. The concentrations of two proposed MST markers, targeting nifH of Methanobrevibacter smithii and HuBac of Bacteroides sp., were positively correlated with increasing anthropogenic development and impervious surfaces. Higher concentrations of these MST markers in more urbanized watersheds suggest that increasing development negatively affect...

96

Fabrication of solid oxide fuel cell by electrochemical vapor deposition  

In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100{sup 0}-1300{sup 0}C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

97

Application of ground penetrating radar for hydro-geological study  

Impact of mining in India may affect availability of groundwater, and this has become a matter of concern because villages in that region suffer from water scarcity during dry periods. In most places, clay layers exist above groundwater table. Due to presence of impervious clay layers above the groundwater table, extraction of ores will most likely not affect surrounding hydrological regime of those areas. This paper aims to highlight the significance of Ground Penetrating Radar (GPR) survey prior to excavation in areas where impervious clay layers occur as underlying strata. GPR will be very helpful to check groundwater depletion in open cast mines indirectly after exploring the subsurface geological scenario. Hydrological regime of the mining areas will be saved with the help of GPR by distinguishing between groundwater and clay.

98

Immobilization mechanisms in solidification/stabilization of Cd and Pb salts using Portland cement fixing agents  

The authors have investigated the behavior of Cd and Pb salts toward cement-based solidification using TCLP leaching tests, conduction calorimetry, and solid-state NMR as a function of time. Concentrations of Cd in leachates are very low, while Pb concentrations are considerably higher and would represent a serious threat to groundwater. The Cd/cement system involves Cd(OH){sub 2}, while provides nucleation sites for precipitation of calcium silicate hydrate (C-S-H) gel and calcium hydroxide, resulting in Cd being in the form of the insoluble hydroxide with a very impervious coating. On the other hand, the Pb/cement system involves hydroxide, sulfate, and nitrate mixed salts, which retard cement hydration reactions by forming an impervious coating around cement clinker grains. However, as pH in the cement pore waters undergoes fluctuations during the progress of hydration, the Pb salts undergo solubilization and reprecipitation on leachable surfaces of the cement matrix.

99

Fabrication of solid oxide fuel cell by electrochemical vapor deposition  

In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

100

The Schwartzwalder uranium deposit. I: Geology and structural controls on mineralization.  

Numerous uranium veins occupy fractures and faults in brittle Proterozoic gneisses along the east central Front Range of Colorado. The deposit size correlates with the density and localization of brittle fracture. The largest deposit, the Schwartzwalder, is explained by a singular configuration of complexly broken, deep-reaching brittle gneisses between impervious schists. The gneisses are described as being derived from volcanic rocks, shales, and chemical sediments, including iron, quartz and sulphide formations.-G.J.N.

 
 
 
 
101

Urbanization affects stream ecosystem function by altering hydrology, chemistry, and biotic richness.  

Catchment urbanization can alter physical, chemical, and biological attributes of stream ecosystems. In particular, changes in land use may affect the dynamics of organic matter decomposition, a measure of ecosystem function. We examined leaf-litter decomposition in 18 tributaries of the St. Johns River, Florida, USA. Land use in all 18 catchments ranged from 0% to 93% urban which translated to 0% to 66% total impervious area (TIA). Using a litter-bag technique, we measured mass loss, fungal biomass, and macroinvertebrate biomass for two leaf species (red maple [Acer rubrum] and sweetgum [Liquidambar styraciflua]). Rates of litter mass loss, which ranged from 0.01 to 0.05 per day for red maple and 0.006 to 0.018 per day for sweetgum, increased with impervious catchment area to levels of approximately 30-40% TIA and then decreased as impervious catchment area exceeded 40% TIA. Fungal biomass was also highest in streams draining catchments with intermediate levels of TIA. Macroinvertebrate biomass ranged from 17 to 354 mg/bag for red maple and from 15 to 399 mg/bag for sweetgum. Snail biomass and snail and total invertebrate richness were strongly related to breakdown rates among streams regardless of leaf species. Land-use and physical, chemical, and biological variables were highly intercorrelated. Principal-components analysis was therefore used to reduce the variables into several orthogonal axes. Using stepwise regression, we found that flow regime, snail biomass, snail and total invertebrate richness, and metal and nutrient content (which varied in a nonlinear manner with impervious surface area) were likely factors affecting litter breakdown rates in these streams. PMID:17069372

102

IRRADIATION OF MATERIALS  

A process is described for curing or hardening an organic synthetic resin coating on one face of an impervious sheet by electron-induced cross- linking of the resin by an unsaturated monomer. The electrons are of 50 to 250 kev. The monomer is vinyl carbazole, diallylphthalate, or styrene, and the polyester resin is in liquid form prior to irradiation. Examples are given. (R.E.U.)

103

Odd Khovanov homology is mutation invariant  

We define a link homology theory that is readily seen to be both isomorphic to reduced odd Khovanov homology and fully determined by data impervious to Conway mutation. This gives an elementary proof that odd Khovanov homology is mutation invariant, and therefore that mod 2 Khovanov homology is mutation invariant. We also establish mutation invariance for the entire Ozsvath-Szabo spectral sequence from reduced Khovanov homology to the Heegaard Floer homology of the branched double cover.

104

Internal combustion engine  

An internal combustion engine is described that has walls delimiting the working space or spaces of the internal combustion engine, in which a hydrogen-impervious, encapsulated metal hydride storage device is provided which is in heat-conducting contact with these walls; the interior of the encapsulation is adapted to be selectively connected to a source of hydrogen and/or to a separate further hydrogen storage device.

105

Three-dimensional computer modeling of particulate flow around dust monitors  

SOLA-DM is a three-dimensional finite-difference computer code designed to model the dynamics of an incompressible fluid and the transport of discrete particulate material around obstacles impervious to flow. The numerical methods used in this code are described. SOLA-DM was used to predict the particle flux sampled by the 10-mm Dorr-Oliver Cyclone and MINIRAM dust monitors. Various geometric and dynamic variations of monitor and airflow combinations were tested. The code predictions are shown in computer-generated graphic plots.

106

Lightweight zinc electrode  

This document describes a light weight zinc electrode made of a sintered mat of copper metal coated graphite fibers, a composite material of zinc active material, and a hydrogel dispersed in a solid, impervious, inert polymer matrix. The composite material surrounds the individual copper metal coated graphite fibers of the sintered mat which support the composite material and provide paths of electrical conductivity throughout the composite material.

107

Edge seal for a porous gas distribution plate of a fuel cell  

In an improved seal for a gas distribution plate of a fuel cell, a groove is provided extending along an edge of the plate. A member of resinous material is arranged within the groove and a paste comprising an immobilized acid is arranged surrounding the member and substantially filling the groove. The seal, which is impervious to the gas being distributed, is resistant to deterioration by the electrolyte of the cell.

108

Impacts of urbanization on nitrogen cycling and aerosol, surface and groundwater transport in semi-arid regions  

Semi-arid regions are experiencing disproportionate increases in human population and land transformation worldwide, taxing limited water resources and altering nitrogen (N) biogeochemistry. How the redistribution of water and N by urbanization affects semi-arid ecosystems and downstream water quality (e.g. drinking water) is unclear. Understanding these interactions and their feedbacks will be critical for developing science-based management strategies to sustain these limited resources. This is especially true in the US where some of the fastest growing urban areas are in semi-arid ecosystems, where N and water cycles are accelerated, and intimately coupled, and where runoff from urban ecosystems is actively managed to augment a limited water supply to the growing human population. Here we synthesize several ongoing studies from the Tucson Basin in Arizona and examine how increasing urban land cover is altering rainfall-runoff relationships, groundwater recharge, water quality, and long range transport of atmospheric N. Studies across 5 catchments varying in impervious land cover showed that only the least impervious catchment responded to antecedent moisture conditions while hydrologic responses were not statistically related to antecedent rainfall conditions at more impervious sites. Regression models indicated that rainfall depth, imperviousness, and their combined effect control discharge and runoff ratios (p transport of N and N emissions from Tucson are being transported and deposited at high elevation in areas that recharge regional groundwater. Combined, our findings suggest that urbanization in semi-arid regions results in tradeoffs in the redistribution of water and N that have important implications for water management and sustaining water quality.

109

Cross-flow electrochemical reactor cells, cross-flow reactors, and use of cross-flow reactors for oxidation reactions  

This invention discloses cross-flow electrochemical reactor cells containing oxygen permeable materials which have both electron conductivity and oxygen ion conductivity, cross-flow reactors, and electrochemical processes using cross-flow reactor cells having oxygen permeable monolithic cores to control and facilitate transport of oxygen from an oxygen-containing gas stream to oxidation reactions of organic compounds in another gas stream. These cross-flow electrochemical reactors comprise a hollow ceramic blade positioned across a gas stream flow or a stack of crossed hollow ceramic blades containing a channel or channels for flow of gas streams. Each channel has at least one channel wall disposed between a channel and a portion of an outer surface of the ceramic blade, or a common wall with adjacent blades in a stack comprising a gas-impervious mixed metal oxide material of a perovskite structure having electron conductivity and oxygen ion conductivity. The invention includes reactors comprising first and second zones seprated by gas-impervious mixed metal oxide material material having electron conductivity and oxygen ion conductivity. Prefered gas-impervious materials comprise at least one mixed metal oxide having a perovskite structure or perovskite-like structure. The invention includes, also, oxidation processes controlled by using these electrochemical reactors, and these reactions do not require an external source of electrical potential or any external electric circuit for oxidation to proceed.

110

Influences of Watershed Urbanization and Instream Habitat on Macroinvertebrates in Cold Water Streams  

We analyzed data from riffle and snag habitats for 39 small cold water streams with different levels of watershed urbanization in Wisconsin and Minnesota to evaluate the influences of urban land use and instream habitat on macroinvertebrate communities. Multivariate analysis indicated that stream temperature and amount of urban land use in the watersheds were the most influential factors determining macroinvertebrate assemblages. The amount of watershed urbanization was nonlinearly and negatively correlated with percentages of Ephemeroptera-PlecopteraTrichoptera (EPT) abundance, EPT taxa, filterers, and scrapers and positively correlated with Hilsenhoff biotic index. High quality macroinvertebrate index values were possible if effective imperviousness was less than 7 percent of the watershed area. Beyond this level of imperviousness, index values tended to be consistently poor. Land uses in the riparian area were equal or more influential relative to land use elsewhere in the watershed, although riparian area consisted of only a small portion of the entire watershed area. Our study implies that it is extremely important to restrict watershed impervious land use and protect stream riparian areas for reducing human degradation on stream quality in low level urbanizing watersheds. Stream temperature may be one of the major factors through which human activities degrade cold-water streams, and management efforts that can maintain a natural thermal regime will help preserve stream quality.

111

Quantifying sub-pixel urban impervious surface through fusion of optical and inSAR imagery  

In this study, we explored the potential to improve urban impervious surface modeling and mapping with the synergistic use of optical and Interferometric Synthetic Aperture Radar (InSAR) imagery. We used a Classification and Regression Tree (CART)-based approach to test the feasibility and accuracy of quantifying Impervious Surface Percentage (ISP) using four spectral bands of SPOT 5 high-resolution geometric (HRG) imagery and three parameters derived from the European Remote Sensing (ERS)-2 Single Look Complex (SLC) SAR image pair. Validated by an independent ISP reference dataset derived from the 33 cm-resolution digital aerial photographs, results show that the addition of InSAR data reduced the ISP modeling error rate from 15.5% to 12.9% and increased the correlation coefficient from 0.71 to 0.77. Spatially, the improvement is especially noted in areas of vacant land and bare ground, which were incorrectly mapped as urban impervious surfaces when using the optical remote sensing data. In addition, the accuracy of ISP prediction using InSAR images alone is only marginally less than that obtained by using SPOT imagery. The finding indicates the potential of using InSAR data for frequent monitoring of urban settings located in cloud-prone areas. Copyright ?? 2009 by Bellwether Publishing, Ltd. All right reserved.

112

Urbanization Trends (2001-2006) In The Conterminous United States And Regional Climate Impacts  

More than 50% of the world population now lives in urban and suburban areas. The rate of urbanization in the world is expected to continue to accelerate in the near future. As urban areas expand by transforming the surrounding landscape into impervious surface, the changes of urban land cover (ULC) have significant implications for wide range consequences. Monitoring changes in large urban areas becomes increasingly important. The U.S. Geological Survey (USGS) recently published the National Land Cover Database (NLCD) 2006 products including land cover and percent impervious surface area (ISA) for the conterminous United States (CONUS). The percent ISA, which represents the fraction of impervious area in a 30 m grid, was estimated using regression tree algorithms with both Landsat and nighttime lights imagery. Generally, the approach comprises four major procedures: creating a training dataset, modeling a synthetic impervious surface, comparing model outputs for optimal selection and final product clean up. The ISA product was used to define four different ULC types by categorizing percent ISA and quantitatively determining the extent of ULC. We analyzed 2001 and 2006 imperviousness variations to summarize two areal increments: ISA, which calculates the area of imperviousness proportion in every 30 m pixels, and urban area, which totals the number of 30 m pixels that contain any impervious surface. The new ISA in 2006 increases 4.1% (4095 km2) from the 2001 base amount across the CONUS. The growth of ISA reached approximately 819 km2 per year during the period. The total ISA in 2006 reached 103,615 km2, which is slightly smaller than the state of Kentucky. The new urban area in 2006 was 12,365 km2 and the total urban area reached 500,153 km2, which is close to the size of California and Indiana combined. To analyze the interactions between ULC change and climate systems, we used both the gridded climate data from the Parameter-elevation Regressions on Independent Slopes Model (PRISM) dataset and NLCD ISA product. Mean annual precipitation, mean annual minimum temperature (Tmin), and mean annual maximum temperature (Tmax) from 1980 to 2010 were converted to a raster format. A standardized anomaly method was used to calculate climatic anomalies by A(t)=(X(t)-Xmean)/? , where A(t) is the standardized anomaly of a given quantity X (e.g., mean annual Tmin) in a specific year t, Xmean is the long time mean, and ? is the standard deviation. The means of annual Tmin in the periods of 1995-2000 and 2001-2006 were averaged in the newly urbanized areas that emerged after 2001. The average in the urbanized time period (2001-2006) is about 0.3 °C higher than the average in the pre-urbanized time (1995-2000). Similarly, in the new urban areas, the six year averages of standardized anomaly of Tmin were 0.12 and 0.52 in the periods of 1995-2000 and 2001-2006, respectively, indicating a larger anomaly due to ULC change. The land cover change characterized by urbanization apparently affects surrounding ecological system conditions and imposes a significant forcing function on the climate system.

113

Sources of Potential Water Imbalance in Low-gradient Coastal Watersheds  

In recent years there has been an increasing concern of water yield/balance from watersheds because of population growth, land use change, and climate change, including variability of its extremes. These concerns are equally valid for the humid Southeastern Coastal Plain as well as arid/semi-arid regions. The Coastal Plain is generally characterized by flat, low-gradient systems where the average annual rainfall generally equals or exceeds the potential evapotranspiration (ET) often resulting in excess soil-water. More than 60% of the region is covered by forest ecosystems, including wetlands, where the regional long-term water balance includes 70-80% of average annual precipitation lost to ET. Maintaining this balance is important to both economic development as well as land and water management practices in this landscape. However, both anthropogenic and natural disturbances can easily create "imbalance" of rainfall, ET, and eventually, in water yield and supply. In this presentation we summarize various reasons that can and are tending to cause the imbalance of water in this region. Clearing of forest ecosystems near the coastal waters for rapid and expanded urbanization with increased imperviousness results in decreased transpiration, dramatic increase in surface runoff and flooding as well as decrease in sustained base flows. Understanding of such imbalances from pre-developed forested conditions is critical for developing best management practices (BMPs) to create a new sustained "balance" in the developed system. An " imbalance" caused by a dramatic temporal shift in water balance as may occur in the forest ecosystem due to continuous climate change or changes in magnitude and frequency of extreme climatic events. This may be caused by shift in vegetation species and growth patterns, including invasive species and forest die-off, all of which affect rainfall-ET balance and, thereby, water yield. Similarly, the extreme climatic events characteristic to the coastal plain like hurricanes and droughts may also be responsible for temporal imbalance in components like surface runoff (water yield) and ET. Increased frequency and magnitude of high intensity storms and droughts forecasted for the Southeastern coastal region may also likely exacerbate the current seasonal water balances. An imbalance in fresh and salt water contents of available groundwater resources of the coastal plain may also result if current climate change trends with drought and/or a sea level rise continue. Therefore, current land management practices including the BMPs and water resources development approaches based on the classic water balance will have to be re-evaluated perhaps with an "adaptive management approach" in response to these "imbalances" of water in coastal landscapes. Furthermore, current eco-hydrologic models, applied for assessment of regional hydrology, should also be re-evaluated continuously for their ability to accurately simulate the effects of shifts in seasonal and annual water balances caused by these various anthropogenic and natural disturbances.

114

A River Runs Under It: Modeling the Distribution of Streams and Stream Burial in Large River Basins  

Stream network density exerts a strong control on hydrologic processes in watersheds. Over land and through soil and bedrock substrate, water moves slowly and is subject to chemical transformations unique to conditions of continuous contact with geologic materials. In contrast, once water enters stream channels it is efficiently transported out of watersheds, reducing the amount of time for biological uptake and stream nutrient processing. Therefore, stream network density dictates both the relative importance of terrestrial and aquatic influences to stream chemistry and the residence time of water in watersheds, and is critical to modeling and empirical studies aimed at understanding the impact of land use on stream water quantity and quality. Stream network density is largely a function of the number and length of the smallest streams. Methods for mapping and measuring these headwater streams range from simple measurement of stream length from existing maps, to detailed field mapping efforts, which are difficult to implement over large areas. Confounding the simplest approaches, many headwater stream reaches are not included in hydrographical maps, such as the U.S. National Hydrography Dataset (NHD), either because they were buried during the course of urban development or because they were seen as smaller than the minimum mapping size at the time of map generation. These "missing streams" severely limit the effective analyses of stream network density based on the NHD, constituting a major problem for many efforts to understand land-use impacts on streams. Here we report on research that predicts stream presence and absence by coupling field observations of headwater stream channels with maximum entropy models (MaxEnt) commonly implemented in biogeographical studies to model species distributions. The model utilizes terrain variables that are continuously accumulated along hydrologic flowpaths derived from a 10-m digital elevation model. In validation, the model correctly predicts the presence of 91% of all 10-m stream segments, and rarely miscalculates tributary numbers. We apply this model to the entire Potomac River Basin (37,800 km2) and several adjacent basins to map stream channel density and compare our results with NHD flowline data. We find that NHD underestimates stream channel density by a factor of two in most sub watersheds and this effect is strongest in the densely urbanized cities of Washington, DC and Baltimore, MD. We then apply a second predictive model based on impervious surface area data to map the extent of stream burial. Results demonstrate that the extent of stream burial increases with decreasing stream catchment area. When applied at four time steps (1975, 1990, 2001, and 2006), we find that although stream burial rates have slowed in the recent decade, streams that are not mapped in NHD flowline data continue to be buried during development. This work is the most ambitious attempt yet to map stream network density over a large region and will have lasting implications for modeling and conservation efforts.

115

New insight into unstable hillslopes hydrology from hydrogeochemical modelling.  

In the black marl outcrops of the French South Alps, sub surface flow conditions are considered as the main triggering factor for initiation and reactivation of landslides. The problem is traditionally addressed in term of hydrological processes (how does percolation to the water table occur?) but in some cases the origin of water is also in question. Direct rainfall is generally assumed as the only water source for groundwater recharge in shallow hillslope aquifers. The bedrock is also supposed impervious and continuous. Yet the geological environment of the study area is very complex owing to the geological history of this alpine sector. The autochthonous callovo-oxfordian black marl bedrock is highly tectonized (Maquaire et al., 2003) and may be affected by large, possibly draining discontinuities. A deep water inflow at the slip surface may at least locally result in increase the pore pressure and decrease the effective shearing resistance of the landslide material. In the active slow-moving landslide of Super-Sauze (Malet and Maquaire, 2003), this question has been addressed using hydrochemical investigations. The groundwater was sampled during five field campaigns uniformly spread out over the year from a network of boreholes. Water chemistry data were completed by geochemical and mineralogical analyses of the marl material. The major hydro-geochemical processes over area proved (1) mixing processes, (2) pyrite alteration, (3) dissolution/precipitation of carbonates and (4) cations exchange (de Montety et al., 2007). A geochemical modelling was carried out using the model Phreeqc (Parkhurst and Appelo, version 2.15, 2008) to check how suitable was observed water chemistry with the reservoir characteristics. The modelling exercise was based on a kinetics approach of soil-water interactions. The model simulates the rock alteration by the dissolution of the primary minerals and the precipitation of new phases. Initial parameters were obtained from geochemical and mineralogical analyses or from the literature (kinetics constants). The simulations showed that pH, sulphate and calcium concentrations in groundwater could be reproduced from reasonable assumptions. However, the observed high concentrations in magnesium and sodium were not correctly simulated by the model. Furthermore, a particular anomaly in the Na+ concentration was observed in the most active part of the landslide. Lastly, isotopic investigation showed that groundwater 3H content in this sector was significantly lower than groundwater content in the other parts of the landslide and lower than the mean rainwater content. This result showed that the mean groundwater age in the active part was probably higher than elsewhere in the landslide. All these arguments led us to conclude that groundwater was locally recharged with saline waters from areas outside the watershed, coming up through the bedrock using major discontinuities. This assumption is in agreement with the geological context. de Montety, V., V. Marc, C. Emblanch, J.-P. Malet, C. Bertrand, O. Maquaire, and T. A. Bogaard, 2007, Identifying the origin of groundwater and flow processes in complex landslides affecting black marls: insights from a hydrochemical survey.: Earth Surface Processes and Landforms, v. 32, p. 32-48. Malet, J.-P. and Maquaire, O., 2003. Black marl earthflows mobility and long-term seasonal dynamic in southeastern France. In: Picarelli, L. (Ed). Proceedings of the International Conference on Fast Slope Movements: Prediction and Prevention for Risk Mitigation. Patron Editore, Bologna: 333-340. Maquaire, O., Malet, J.-P., Remaître, A., Locat, J., Klotz, S. and Guillon, J., 2003. Instability conditions of marly hillslopes: towards landsliding or gullying? The case of the Barcelonnette Bassin, South East France. Engineering Geology, 70(1-2): 109-130. Parkhurst, D.L. and Appelo, C.A.J., 1999, User's guide to PHREEQC (version 2)--A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations: U.S. Geological Survey Water-Resources I

116

INTEGRATED ASSESSMENTS OF POSSIBLE EFFECTS OF HYDROCARBON AND SALT WATER INTRUSION ON THE GROUNDWATER OF IGANMU AREA OF LAGOS METROPOLIS, SOUTHWESTERN NIGERIA  

Abstract in spanish Los métodos de Sondeo Eléctrico Vertical (VES) y Polarización Inducida (IP) se incorporaron al análisis físico-químico de las muestras de agua de pozo para determinar la extensión vertical de contaminación por petróleo en el subsuelo y las aguas subterráneas desde los almacenamientos de combustible y terminales de distribución en Iganmu, en la zona de Lagos. La interpretación de resultados de VES y IP revelaron cuatro capas geo-eléctricas. Arcilla con resisti (more) vidad y valores IP que van desde 1,5 hasta 14 Qm y 50 - 400 mV / V respectivamente, fue encontrada en la última capa alcanzada por el estudio, excepto en cuatro estaciones de VES, donde se delineó el horizonte de arcilla en la tercera capa. Esto implica que los acuíferos del subsuelo están sellados por una capa impermeable que posiblemente impide que sean contaminados por hidrocarburos y otros materiales desechos de la superficie. Los registros de pozos y la resistividad eléctrica de un sitio de control dentro de la zona fueron incorporados con las mediciones geofísicas y éstas confirman similitud litológica y la presencia de un sellador encima de la capa acuífera. En adición, los resultados de los análisis geo-químicos y físicos llevados a cabo en muestras de agua subterránea de pozos poco profundos dentro del área muestran un nivel insignificante de contaminación por hidrocarburos que no tiene graves consecuencias medioambientales sobre el agua del subsuelo en la zona. Sin embargo, la conductividad eléctrica, la salinidad y los valores TDS obtenidos muestran el alto grado de minerales disueltos (sales) haciendo que el agua sea altamente salina y no apta para beber, ya que está muy por encima de los valores recomendados para ser agua potable. De esta manera se infiere que la laguna de Lagos ha invadido el acuífero en algunos lugares dando paso a la elevada salinidad observada. Abstract in english Vertical electrical sounding (VES) and Induced Polarisation (IP) methods of geophysical survey were incorporated with physiochemical analysis of well water samples to determine vertical extent of petroleum-product contamination in subsurface soils and groundwater from bulk-fuel storage and distribution terminals in Iganmu area of Lagos. Interpreted results of VES and IP revealed four geoelectric layers. Clay with resistivity and IP values ranging from 1.5-14 Qm and 50 - 4 (more) 00mV/V respectively was encountered at the last layer penetrated by the survey except in four VES stations where the clay horizon was delineated at the third layer. This implies that subsurface aquifer is sealed by impervious layer which possibly prevents it from being contaminated by hydrocarbon and other refuse materials from the surface. Borehole log and electrical resistivity survey from a control site within the area were also incorporated with the geophysical measurements and these confirm lithologic similarity and the presence of a sealant above the aquifer layer. In addition to this, the results of the physical and geochemical analyses carried out on groundwater samples from shallow wells within the pack show very negligible level of hydrocarbon contamination which has no serious environmental implications on subsurface water in the area. However, electrical conductivity, salinity and TDS values obtained show high level of dissolved minerals (salts) making the water highly saline and unsuitable for drinking being far above recommended values for drinking water. We thus inferred that Lagos lagoon must have invaded the aquifer in some places leading to high salinity observed.

117

Pollination success of Lotus corniculatus (L.) in an urban context  

Most anthropogenic activities are known to have deleterious effects on pollinator communities. However, little is known about the influence of urbanization on pollination ecosystem services.Here, we assessed the pollination service on Lotus corniculatus (L.), a self-sterile, strictly entogamous Fabaceae commonly observed in urban and suburban areas. We assessed the pollination success of artificial Lotus corniculatus populations at three levels: at large scale, along an urbanization gradient; at intermediate scale, based on landscape fragmentation within a 250 m radius and at local scale based on floral resource abundance and local habitat type.The main findings were that the pollination success, when assessed with the number of fruit produced per inflorescence, was lower in urban areas than in suburban ones, and was negatively affected by the number of impervious spaces in the neighborhood. The relationship between the number of fruits and the distance to the nearest impervious space was either positive or negative, depending on the gray/green ratio (low vs. high). Finally, on a local scale, floral resource abundance had a negative effect on pollination success when L. corniculatus populations were located in paved courtyards, and a positive one when they were located in parks.Pollination success seems to be explained by two intertwined gradients: landscape fragmentation estimated by the number of impervious spaces in a 250 m radius around L. corniculatus populations, and the behavior of bumblebees toward birdsfoot trefoil and floral displays, which appears to differ depending on whether a neighborhood is densely or sparsely urbanized. An abundance of attracting floral resources seems to enhance pollination success for L. corniculatus if it is not too isolated from other green spaces.These results have important implications for the sustainability of pollination success in towns by identifying local and landscape factors that influence reproductive success of a common plant.

118

Performance of stormwater detention tanks for urban drainage systems in northern Italy.  

The performance of stormwater detention tanks with alternative design configurations (insertion in the storm sewer network; volume per impervious hectare) and operating conditions (continuous and intermittent emptying rules) have been evaluated according to an integrated approach. Various performance indices have been adopted to describe the mitigation of the pollution impact to the natural environment, the reduction of the management and maintenance charges for the urban drainage system, the preservation of the normal purification efficiency, and the limitation of the costs at the treatment plant. The US EPA Storm Water Management Model has been used to simulate the rainfall-runoff process and the pollutant dynamics on theoretical catchments and storm sewer networks for an individual event, as well as for a continuous run of events and inter event periods of one year recorded at the rain gauge of Cascina Scala (Pavia, northern Italy). Also the influence of the main characteristics of the urban catchment and the drainage system (area of the catchment and slope of the network) on the performance of alternative design and operating solutions has been examined. Stormwater detention tanks combined with flow regulators demonstrated good performance with respect to environmental pollution: satisfactory performance indicators can be obtained with fairly low flow rates of flow regulators (0.5-1 L/s per hectare of impervious area) and tank volumes of about 35-50 m(3) per impervious hectare. Continuous emptying guaranteed the lowest number and duration of overflows, while an intermittent operation minimised the volume sent for purification reducing the costs and the risks of impairment in the normal treatment efficiency of the plant. Overall, simulation outcomes revealed that the performance indexes are scarcely affected by the area of the catchment and the slope of the drainage network. The result of this study represents a key issue for the implementation of environmental policies in large urban areas. PMID:22387328

119

Silicon nitride protective coatings for silvered glass mirrors  

A protective diffusion barrier for metalized mirror structures is provided by a layer or coating of silicon nitride which is a very dense, transparent, dielectric material that is impervious to water, alkali, and other impurities and corrosive substances that typically attack the metal layers of mirrors and cause degradation of the mirrors' reflectivity. The silicon nitride layer can be deposited on the substrate before metal deposition to stabilize the metal/substrate interface, and it can be deposited over the metal to encapsulate it and protect the metal from corrosion or other degradation. Mirrors coated with silicon nitride according to this invention can also be used as front surface mirrors.

120

"This Is Produced by a Brain-Process!" Wittgenstein, Transparency and Psychology Today  

This paper examines sections of Wittgenstein's "Philosophical Investigations" with a view to exposing trail-effects of psychology in educational and social practice today. These are seen in understandings of the relations between mind and body, and language and thought, and their influence is identified in such contemporary preoccupations as accounting transparency and the new science of happiness. A Wittgensteinian critique is offered, with attention paid to the idea that "nothing is hidden". Finally a question is raised as to how far it is the imperviousness of these practices to criticism that is the key to understanding them.

 
 
 
 
121

Field emission devices for advanced electronics comprised of lateral nanodiamond or carbon nanotube emitters  

Nanocarbon-derived electron emission devices, specifically, nanodiamond lateral field emission diodes and gated carbon nanotube triodes are new configurations for robust nanoelectronic devices. These novel micro/nanostructures provide an alternative and efficient means of accomplishing electronics that are impervious to temperature and radiation. Nitrogen-incorporated nanocrystalline diamond has been lithographically micropatterned to utilize the material as an electron field emitter. Arrays of laterally arranged ?finger-like?? nanodiamond emitters constitute the cathode in a versatile diode configuration with small interelectrode separation. Nanodiamond lateral tip conditioning techniques are employed to improve emission and the subsequent device performance discussed. A low diode turn-on...

122

Behaviour of alumina-coated 304L steel in a Waste-to-Energy plant  

Pieces of 304L stainless steel, alumina-coated by plasma spraying, were placed during one week at about 1170K in the furnace of the Waste-to-Energy plant of Limoges, France. The resistance against corrosion was only slightly improved compared to non-coated alloy. The origin of this unsatisfactory result lies in the cracking of the coating that occurred when the pieces were introduced in the furnace, due to the great difference in the Coefficient of Thermal Expansion (CTE) of alumina and 304L steel. However, the plasma-sprayed alumina coatings themselves appear as impervious enough to provide an efficient protection of this alloy against the very corrosive atmosphere of the incinerator.

123

Discretization approach in integrated Hydrologic Model for surface and groundwater interaction  

The commonly used discretization approaches for distributed hydrological models can be broadly categorized into four types, based on the nature of the discrete components: Regular Mesh, Triangular Irregular Networks (TINs), Representative Elementary Watershed (REWs) and Hydrologic Response Units (HRUs). In this paper, a new discretization approach for landforms that have similar hydrologic properties is developed and discussed here for the Integrated Hydrologic Model (IHM), a combining simulation of surface and groundwater processes, accounting for the interaction between the systems. The approach used in the IHM is to disaggregate basin parameters into discrete landforms that have similar hydrologic properties. These landforms may be impervious areas, related areas, areas with high or low...

124

Impacts of urbanization on stream habitats and macroinvertebrate communities in the tributaries of Qiangtang River, China  

The impacts of watershed urbanization on streams have been studied worldwide, but are rare in China. We examined relationships among watershed land uses and stream physicochemical and biological attributes, impacts of urbanization on overall stream conditions, and the response pattern of macroinvertebrate assemblage metrics to the percent of impervious area (PIA) of watersheds in the middle section of the Qiantang River, Zhejiang Province, China. Environmental variables and benthic macroinvertebrates of 60 stream sites with varied levels of watershed urban land use were sampled in April, 2010. Spearman correlation analysis showed watershed urbanization levels significantly correlated with increased stream depth, width, and values of conductivity, total nitrogen, ammonia, phosphate, calcium...

125

Valuing vegetation in an urban watershed  

This study uses the hedonic price method to examine if land cover types-trees, shrubs, water and impervious surface areas-affect the sale price of single-family residential properties in Multnomah County, Oregon. We combine detailed structural and location information for 36,753 single-family residential property sales with the percentage of land cover on each property and within three buffers surrounding each property. Trees contribute positively to a property's sale price, but the estimated increase may be less than the costs of planting and caring for trees. Benefits received by nearby property owners may justify actions by government agencies to expand canopy coverage.

126

Value of Landsat in urban water resources planning  

The reported investigation had the objective to evaluate the utility of satellite multispectral remote sensing in urban water resources planning. The results are presented of a study which was conducted to determine the economic impact of Landsat data. The use of Landsat data to estimate hydrologic model parameters employed in urban water resources planning is discussed. A decision regarding an employment of the Landsat data has to consider the tradeoff between data accuracy and cost. Bayesian decision theory is used in this connection. It is concluded that computer-aided interpretation of Landsat data is a highly cost-effective method of estimating the percentage of impervious area.

127

Effects of urbanization on stream quality at selected sites in the seacoast region in New Hampshire, 2001-03  

A study of selected water-quality and macroinvertebrate community data was conducted at 10 stream sites in the Seacoast region of New Hampshire to determine if a relation is present between stream quality and the extent of urbanization in a watershed. Watersheds with similar characteristics, but varying in their degree of urban development, were studied. The percent of impervious surface, the percent of urban land use in a watershed, and the percent of urban land use in two types of stream buffers were compared and correlated with stream-quality variables. \\r\

128

Fuel cell having electrolyte  

A fuel cell having an electrolyte control volume includes a pair of porous opposed electrodes. A maxtrix is positioned between the pair of electrodes for containing an electrolyte. A first layer of backing paper is positioned adjacent to one of the electrodes. A portion of the paper is substantially previous to the acceptance of the electrolyte so as to absorb electrolyte when there is an excess in the matrix and to desorb electrolyte when there is a shortage in the matrix. A second layer of backing paper is positioned adjacent to the first layer of paper and is substantially impervious to the acceptance of electrolyte.

129

Air tight electrical box  

An air-impervious electrical box to facilitate air sealing a house comprises an integral, rigid box body having a continuous flange, integral with the body, circumscribing and outwardly extending from the sides of the body. This flange is rearwardly positioned behind the front edges of the sides of the body a predetermined distance so that the electrical box may be secured to framing by nailing through the flange. Drywall is then secured to the frame on top of and adjecent to the flange. Such box eliminates the necessity for solid backing and minimizes passage of air through the box and space between the drywall and the box.

130

Recent technological developments for lead sheathed cables  

Continuous extruders have replaced the ram-press as the most common and economical means of producing lead sheathed power cable. The intrinsic ability of the extruder to produce a significantly more uniform sheath composition should allow for a more dilute version of standard alloy compositions to be used, with equal or better performance of the sheath in service. No power cable sheathing alloy has yet been developed expressly for manufacture by a continuous extruder. New techniques for testing of lead pipe provides further insight into the behavior of the alloy sheath near its bursting limit. Simplified impervious splice designs, without the need for lead wiping, have been developed to overcome environmental concerns.

131

High efficiency tantalum-based ceramic composite structures  

Tantalum-based ceramics are suitable for use in thermal protection systems. These composite structures have high efficiency surfaces (low catalytic efficiency and high emittance), thereby reducing heat flux to a spacecraft during planetary re-entry. These ceramics contain tantalum disilicide, molybdenum disilicide and borosilicate glass. The components are milled, along with a processing aid, then applied to a surface of a porous substrate, such as a fibrous silica or carbon substrate. Following application, the coating is then sintered on the substrate. The composite structure is substantially impervious to hot gas penetration and capable of surviving high heat fluxes at temperatures approaching 3000.degree. F. and above.

132

Local and landscape scale variables impact parasitoid assemblages across an urbanization gradient  

Urbanization is a major driver of land cover change worldwide, yet little is known about how urbanization affects beneficial arthropod communities. This study examined how local and landscape scale variables associated with urbanization influenced parasitic Hymenoptera abundance and diversity in residential and commercial properties along a rural to urban landscape gradient in Wisconsin. At a landscape scale, 300m surrounding sites, land cover percentages were calculated for five cover classes: impervious cover, forest, grassland, agriculture, and urban green space. In addition, habitat diversity (Simpson's index) was calculated for the landscape surrounding study sites. At a local scale (within the boundaries of an individual property), flower diversity, flower area, tree density, and har...

133

Roof panel  

This invention relates to a roof panel, which includes a support course for the supporting of a water-impervious or a wind-proof layer. The roof panel additionally includes a lower diffusion-proof layer and normally one insulating course located in the region between the lower diffusion-proof layer and the support course. The roof panel is disposed with a frame which forms the outer edges of the roof panel, in addition to which the frame along opposite edges is disposed with devices in order to affix adjacent roof panels in relation to one another and to affix the roof panels to a substrate, such as a roof truss or support wall.

134

Slip-Cast Superconductive Parts  

Complex shapes fabricated without machining. Nonaqueous slip-casting technique used to form complexly shaped parts from high-temperature superconductive materials like YBa(2)Cu(3)O(7-delta). Such parts useful in motors, vibration dampers, and bearings. In process, organic solvent used as liquid medium. Ceramic molds made by lost-wax process used instead of plaster-of-paris molds, used in aqueous slip-casting but impervious to organic solvents and cannot drain away liquid medium. Organic-solvent-based castings do not stick to ceramic molds as they do to plaster molds.

135

Nationwide regression models for predicting urban runoff water quality at unmonitored sites  

Regression models are presented that can be used to estimate mean loads for chemical oxygen demand, suspended solids, dissolved solids, total nitrogen, total ammonia plus nitrogen, total phosphorus, dissolved phosphorus, total copper, total lead, and total zinc at unmonitored sites in urban areas. Explanatory variables include drainage area, imperviousness of drainage basin to infiltration, mean annual rainfall, a land-use indicator variable, and mean minimum January temperature. Model parameters are estimated by a generalized-least-squares regression method that accounts for cross correlation and differences in reliability of sample estimates between sites. The regression models account for 20 to 65 percent of the total variation in observed loads.

136

National housing and impervious surface scenarios for integrated climate impact assessments  

Understanding the impacts of climate change on people and the environment requires an understanding of the dynamics of both climate and land use/land cover changes. A range of future climate scenarios is available for the conterminous United States that have been developed based on widely used international greenhouse gas emissions storylines. Climate scenarios derived from these emissions storylines have not been matched with logically consistent land use/cover maps for the United States. This gap is a critical barrier to conducting effective integrated assessments. This study develops novel national scenarios of housing density and impervious surface cover that are logically consistent with emissions storylines. Analysis of these scenarios suggests that combinations of climate and land use/cover can be important in determining environmental conditions regulated under the Clean Air and Clean Water Acts. We found significant differences in patterns of habitat loss and the distribution of potentially impaired watersheds among scenarios, indicating that compact development patterns can reduce habitat loss and the number of impaired watersheds. These scenarios are also associated with lower global greenhouse gas emissions and, consequently, the potential to reduce both the drivers of anthropogenic climate change and the impacts of changing conditions. The residential housing and impervious surface datasets provide a substantial first step toward comprehensive national land use/land cover scenarios, which have broad applicability for integrated assessments as these data and tools are publicly available.

137

3D Model of the Torrevieja Tertiary aquifer. Geometry of the aquifer; Modelizacion 3D del acuifero Terciario de Torrevieja. Geometria del acuifero  

The Torrevieja coastal aquifer is located in Accentual, SE Spain. Intensive exploitation of the aquifer began in the 1960s, mainly in order to meet agricultural needs. During these last four decades, the hospitality industry has also experienced a dramatic boost in the area, which in turn has led to a further increase in groundwater abstraction. About 5 million cubic metres per year are currently pumped, leading to seawater intrusion concerns. According to the existing estimates, the average thickness of the sandstone/limestone aquifer level ranges between 30 and 100 m over an area of approximately 167 km{sup 2}. This level is underlain by an impervious Upper Miocene marl layer, whilst a white Pliocene marl layer partially confines the aquifer top. There are about 13 km{sup 2} of permeable outcrops which allow for rain water recharge to take place. Impervious boundaries completely surround the aquifer, except along the eastern side, where it is in contact with the sea. Newly obtained borehole data however seems to modify these, and suggests that the aquifer area might be significantly smaller. This paper presents an analysis of new and old borehole records that ultimately aims at developing a 3D representation of the in-depth geometry of the system. (Author) 12 refs.

138

Unitary plate electrode  

The unitary electrode comprises a porous sheet of fiberglass the strands of which contain a coating of conductive tin oxide. The lower portion of the sheet contains a layer of resin and the upper layer contains lead dioxide forming a positive active electrode on an electrolyte-impervious layer. The strands form a continuous conduction path through both layers. Tin oxide is prevented from reduction by coating the surface of the plate facing the negative electrode with a conductive, impervious layer resistant to reduction such as a thin film of lead or graphite filled resin adhered to the plate with a layer of conductive adhesive. The plate can be formed by casting a molten resin from kettle onto a sheet of glass wool overlying a sheet of lead foil and then applying positive active paste from hopper into the upper layer. The plate can aslo be formed by passing an assembly of a sheet of resin, a sheet of sintered glass and a sheet of lead between the nip of heated rollers and then filling lead oxide into the pores of the upper layer.

139

Effects of urbanization on stream ecosystems along an agriculture-to-urban land-use gradient, Milwaukee to Green Bay, Wisconsin, 2003-2004  

In 2003 and 2004, 30 streams near Milwaukee and Green Bay, Wisconsin, were part of a national study by the U.S. Geological Survey to assess urbanization effects on physical, chemical, and biological characteristics along an agriculture-to-urban land-use gradient. A geographic information system was used to characterize natural landscape features that define the environmental setting and the degree of urbanization within each stream watershed. A combination of land cover, socioeconomic, and infrastructure variables were integrated into a multi-metric urban intensity index, scaled from 0 to 100, and assigned to each stream site to identify a gradient of urbanization within relatively homogeneous environmental settings. The 35 variables used to develop the final urban intensity index characterized the degree of urbanization and included road infrastructure (road area and road traffic index), 100-meter riparian land cover (percentage of impervious surface, shrubland, and agriculture), watershed land cover (percentage of impervious surface, developed/urban land, shrubland, and agriculture), and 26 socioeconomic variables (U.S. Census Bureau, 2001). Characteristics examined as part of this study included: habitat, hydrology, stream temperature, water chemistry (chloride, sulfate, nutrients, dissolved and particulate organic and inorganic carbon, pesticides, and suspended sediment), benthic algae, benthic invertebrates, and fish. Semipermeable membrane devices (SPMDs) were used to assess the potential for bioconcentration of hydrophobic organic contaminants (specifically polycyclic aromatic hydrocarbons, polychlorinated biphenyls, and organochlorine and pyrethroid insecticides) in biological membranes, such as the gills of fish.\\r\

140

Cation Chemistry in Baltimore Streams: Another Syndrome Symptom?  

Urban streams are degraded due to a variety of physical and chemical factors including impervious surfaces, sewer cross-connections, and multiple chemical contaminants. There is particular interest in the loading of anionic nutrients and heavy metals into urban streams, especially those draining to nutrient sensitive receiving waters. However, there has been less characterization of cation chemistry in urban streams. We examined metal concentrations in archived water samples as part of the stream monitoring program of the Baltimore Ecosystem Study (BES), an urban component of the U.S. National Science Foundation Long Term Ecological Research network. Preliminary analysis suggests sewer cross-connections (storm and sanitary) influence metal concentrations (e.g. Si, Ca, Mg). For example, while silica content is elevated in water draining BES agricultural watersheds, it is also elevated in watersheds with extensive impervious surface coverage, areas with the least water-rock interaction. These results raise questions about the effects of urbanization on chemical weathering, the stoichiometry of urban storm and sewer waters, and the potential for human inputs to function as hydrologic tracers in urban watersheds.

 
 
 
 
141

Plastic cooling towers keep zoo's generation station cool  

This article described the measures taken by the Bronx Zoo in New York City to operate in an environmentally sound manner while saving maintenance costs. In particular, the new cooling towers which were recently purchased to chill the intercooler for the natural gas engines and the power generation station have saved substantial costs on maintenance and manpower. High-density polyethylene (HDPE) cooling towers were installed when the zoo switched over to natural gas engines to avoid the corrosive and acidic vapours that are associated with the sulphur content in diesel-powered generators. The plastic cooling tower was developed by Delta Cooling Towers in Rockaway, New Jersey. Two advanced Delta cooling towers were also installed to draw heat off the intercooler water systems. Energy is provided to the park by 4 Superior natural gas engines ranging in power from 665 kW to 1,660 kW. HDPE piping systems have also been integrated in which both fresh and marine water can be used because the plastic cooling tower is impervious to corrosion. It is composed of material that is also impervious to the harsh pH environments that destroy metal cooling towers. The engineered plastic cooling towers are energy efficient and available in a wide array of capacities and air flows. 1 fig.

142

Increased salinization of fresh water in the Northeastern United States  

Chloride concentrations are increasing at a rate that threatens the availability of fresh water in the northeastern United States. Increases in roadways and deicer use are now salinizing fresh waters, degrading habitat for aquatic organisms, and impacting large supplies of drinking water for humans throughout the region. We observed chloride concentrations of up to 25% of the concentration of seawater in streams of Maryland, New York, and New Hampshire during winters, and chloride concentrations remaining up to 100 times greater than unimpacted forest streams during summers. Mean annual chloride concentration increased as a function of impervious surface and exceeded tolerance for freshwater life in suburban and urban watersheds. Our analysis shows that if salinity were to continue to increase at its present rate due to changes in impervious surface coverage and current management practices, many surface waters in the northeastern United States would not be potable for human consumption and would become toxic to freshwater life within the next century. ?? 2005 by The National Academy of Sciences of the USA.

143

Green roof stormwater retention: effects of roof surface, slope, and media depth.  

Urban areas generate considerably more stormwater runoff than natural areas of the same size due to a greater percentage of impervious surfaces that impede water infiltration. Roof surfaces account for a large portion of this impervious cover. Establishing vegetation on rooftops, known as green roofs, is one method of recovering lost green space that can aid in mitigating stormwater runoff. Two studies were performed using several roof platforms to quantify the effects of various treatments on stormwater retention. The first study used three different roof surface treatments to quantify differences in stormwater retention of a standard commercial roof with gravel ballast, an extensive green roof system without vegetation, and a typical extensive green roof with vegetation. Overall, mean percent rainfall retention ranged from 48.7% (gravel) to 82.8% (vegetated). The second study tested the influence of roof slope (2 and 6.5%) and green roof media depth (2.5, 4.0, and 6.0 cm) on stormwater retention. For all combined rain events, platforms at 2% slope with a 4-cm media depth had the greatest mean retention, 87%, although the difference from the other treatments was minimal. The combination of reduced slope and deeper media clearly reduced the total quantity of runoff. For both studies, vegetated green roof systems not only reduced the amount of stormwater runoff, they also extended its duration over a period of time beyond the actual rain event. PMID:15888889

144

Urbanization, Forest Vulnerability and Resource Land Loss in the Chesapeake Bay Watershed  

The contemporary pattern of urban development in industrialized countries is increasingly taking the form of low density, decentralized residential and commercial development. In the Chesapeake Bay watershed, which is located within the mid-Atlantic region of the United States, dispersed development patterns have been linked to habitat fragmentation and declining water quality. Our objectives were to document how this urbanization process has expanded throughout the watershed and to explore how lands comprising the natural resource base, particularly forests, have been replaced by a matrix of the built environment. We accomplished this by mapping impervious surface cover (houses, roads, etc) across the ~168,000 km2 area using a time series of satellite imagery. We calculated metrics of land use change and used these to estimate the loss of resource lands across the region. We conservatively estimate that 334 km2 of forest, 888 km2 of agriculture and 2 km2 of wetlands have been converted to impervious surfaces between 1990 and 2000. We also used the time series to calibrate a spatial model of urban land use change, and forecasted future development patterns in Maryland out to 2030 under different policy scenarios. Using Maryland Department of Natural Resources' (DNR) Strategic Forest Lands Assessment (SFLA), which evaluates forest resources in terms of their economic and ecologic value, and Maryland's Green Infrastructure, which identifies ecologically valuable patches of contiguous forests and wetlands, we evaluated the vulnerability of natural resources in Maryland. Threats associated with loss and fragmentation were identified.

145

SURFACTANT SELECTION FOR ENHANCING EX SITU SOIL WASHING. (R825511C064)  

Ex situ soil washing is commonly used for treating contaminated soils by separating the most contaminated fraction of the soil for disposal. Surfactant-enhanced soil washing is being considered with increasing frequency to actually achieve soil-contaminant separation. I...

146

Ecological Forecasting Project on  

and Soils. Soil Quality. Biological soil crusts, soil structure and stability, soil cover, permafrost ... exotic aquatic assemblages. Infestations and ... Land birds, forest vegetation structure & composition, fish communities, intertidal communities, salt ...

147

ISRIC_WISE5by5min_ver1-1  

Feb 29, 2012... base saturation, aluminium saturation, calcium carbonate content, gypsum content, ... AGRICULTURE > SOILS > ELECTRICAL CONDUCTIVITY ... AGRICULTURE > SOILS > SOIL BULK DENSITY · Parameter Definition ...

148

Evaluating DEM results with FEM perspectives of load : soil interaction  

Keywords: Load - soil interaction, soil structure, soil mechanical properties, FEM (Finite Element Method), Plaxis (Finite Element Code), granular particles, shear stress, DEM (Distinct Element Method), mic...

149

Microbial survival on food contact surfaces in the context of food hygiene regulation  

Bacterial food poisoning causes substantial suffering and financial loss worldwide. One way organisms enter foods is via cross contamination directly or indirectly from structural and food contact surfaces. An 'in situ' method was developed for the detection of surviving bacteria on surfaces. Samples of test surfaces were overlaid with agar and after incubation, colonies were visualised by reaction with nitroblue tetrazolium, which was reduced to a purple insoluble dye. It was shown that the death of bacteria applied as liquid films to surfaces, occurred largely at the point of drying. For impervious surfaces (ceramic, stainless steel, glass and polystyrene), surface type had little effect on survival. In contrast, survival was markedly affected by the nature of the suspension fluid in which cells were dried. In deionised water, survival was low and for Gram negative organisms was strongly influenced by cell density. Where cells were dried in simulated food films (containing brain heart infusion, NaCI, serum or sucrose), survival values increased with increasing concentrations and approached 100% for Staphylococcus aureus cells suspended in 10% w/v sucrose. The survival of Gram positive organisms on impervious surfaces was generally greater than for Gram negative organisms and consistent with this observation, scanning electron microscopy indicated that Gram negative cells collapsed during drying. On wood surfaces, survival was generally similar to or higher than on impervious surfaces. However, neither of the Gram positive organisms tested (Staphylococcus aureus and Listeria monocytogenes) could be recovered following inoculation onto the surface of the African hard-wood, iroko, although Gram negative organisms survived well. Scanning electron microscopy confirmed that cells had not been adsorbed below the wood surface and an ethanol-soluble toxic factor was extracted from iroko, which killed Staphylococcus aureus cells, but had no effect on the viability of Salmonella enteritidis PT4. In metabolic studies, it was also shown that this extract caused greater inhibition of ethanol and glucose oxidation in Gram positive than in Gram negative bacteria. Following the washing of iroko in ethanol for 36 days, the survival of Staphylococcus aureus was similar to or higher than on beech wood or ceramic, showing that the toxic factor had been effectively removed. The results are discussed in relation to current legislation and associated guidance concerning the use of surface materials in food businesses and domestic settings. (author)

150

Effects of impervious pavements on reducing runoff in an arid urban catchment  

The progressive urbanization of US arid and semi-arid southwestern territories has transformed undeveloped aridlands into dynamic, radially expanding metropolitan centers. As these mature, infill development further reduces undeveloped area, inversely coupling surface imperviousness to infiltration rates, with a subsequent increase in runoff generation. Intensified runoff carries undesirable environmental consequences, magnifying urban flooding events and concentrations, transport, and propagation of contaminants. Pervious pavements offer one potential solution for decreased urban infiltration. At present, the application potential of pervious pavements as an effective urban infiltration management tool exceeds its exploitation. While entirely eliminating urban Total Impervious Area is not a feasible solution, pervious pavements significantly reduce Effective Impervious Area at costs competitive with traditional Best Management Practices. Previous research into pervious pavements has largely consisted of laboratory prototypes or small-scale field experiments, with a heavy bias towards parking lots. In this study we explore the effectiveness of pervious pavements in increasing infiltration, thus decreasing runoff volume during summer monsoonal and winter convective rainfall events in an 8 ha residential catchment in Scottsdale, Arizona. Analysis focuses on the interaction dynamics between surface area of pervious pavement application and its net effect on runoff response at the catchment level. Hydrological response was modeled using MAHLERAN (Model for Assessing Hillslope-Landscape Erosion, Runoff and Nutrients), a spatially explicit, event-based model, parameterized at a spatial resolution of 0.25 sq m. Data for model parameterization was obtained from analysis of aerial imagery and field-based monitoring of surface properties. The model was tested against measurements of flow at the catchment outlet for multiple rainfall events with total event rainfall ranging from 5 mm to 25 mm. Model testing shows total event discharge simulated well, although low Nash-Sutcliffe coefficients for events indicate a poor fit between the shape and timing of the modeled and monitored hydrograph, which we attribute to poor characterization of friction factors in urban catchments. Scenario-based model analysis tested catchment response to substitution of pervious for conventional pavement by percent and pavement-function scenarios. Results are consistent with previous findings in that short duration-high intensity storms trigger threshold infiltration capacity, past which pervious pavement damping of runoff volume levels off, approaching conventional levels. However at the modeled catchment scale, this initial damping represents a significant reduction in volume, peak flow velocity, and contaminant loading potential. Urban surface drainage networks concentrate and channel flow along roads: the capacity of pervious pavements to simultaneously increase infiltration directly at location of greatest runoff and mitigate inflow effects from remote points has compelling potential as a hydrologic and urban systems engineering tool.

151

Stratification ratios in a rainfed Mediterranean Vertisol in wheat under different tillage, rotation and N fertilization rates  

Semiarid Mediterranean climatic conditions and intensive tillage systems accelerate soil organic matter losses. Therefore, assessing agricultural practices that enhance storage of soil organic matter is needed. Stratification of soil properties with soil depth, expressed as a ratio, could indicate s...

152

In-Situ Soil Testing Chapter 2: CF Cone (Cone Penetration Test)  

The cone penetration test (CPT) is used to determine stratification of soil, soil type, soil density and stresses and soil shear strength parameters. This type of information is useful for geotechnical design and information.

153

Soil Respiration in Response to Landscape Position  

Variations in soil type, due to landscape position, may influence soil respiration. This study was conducted to determine how landscape position (summit, side-slope, and depression) influences heterotrophic and autotrophic soil respiration. Soil respiration was determined at three landscape positio...

154

Nuclear Test Scenarios for Discussion of On-Site Inspection Technologies  

The purpose of the ISS OSI Invited Meeting being held in Vienna March 24-27, 2009 is to obtain a better understanding of the phenomenology of underground nuclear explosions for On-Site Inspection (OSI) purposes. In order to focus the technology discussions, we have developed two very general scenarios, or models, of underground nuclear test configurations and phenomena that will help us explore the application of OSI methodologies and techniques. The scenarios describe testing environments, operations, logistics, equipment, and facilities that might be used in conducting an underground nuclear test. One scenario involves emplacement of a nuclear device into a vertical borehole in an area with relatively flat terrain; the other involves emplacement within a tunnel (horizontally) in an area with mountainous terrain. Vertical borehole geometry The example for this scenario is an intermediate yield nuclear explosion carried out in a flat desert area. The ground was cleared and smoothed over a 200 X 200 m fenced area for operational support activities, access to the borehole, and in order to place a few structures to house diagnostics equipment and control functions. Power lines were provided for local electrical power. The vertical emplacement borehole was 2 m in diameter and bored to a depth of 350 m. The emplacement hole was lined with steel pipe in order to keep the hole open and to avoid cave-ins during emplacement of the nuclear device. Emplacement was above the local water table, and the top of the saturation zone is about 30 m below the bottom of the emplacement hole. The detonation point was at a depth of 340 m. All of the rock material removed while drilling the borehole was removed to another place. Diagnostics and control for the test were relatively simple: about 2 dozen high capacity coaxial cables feed from the down hole instruments to the surface and then about 100 m laterally to a diagnostics trailer. Two strong steel cables were used to emplace the device and diagnostic instruments and to support the down hole cables. The borehole was stemmed after the device was emplaced. The stemming material was relatively simple: the hole was backfilled with sand or gravel about 20-30 m above the nuclear experiment package, a grouted plug about 3 m thick is added, and the hole backfilled with a mixture of sand and gravel to the surface. After the test, the testing party removed all structures and power lines and covered the top of the borehole with a small building. Geologic environment before the test--The geology for the test consists of flat-lying alluvium and tuff, with 50 m of poorly consolidated alluvium near the surface and moderately welded tuff from 50 m depth to 50 m below the bottom of the hole. The upper tuff is underlain by a densely welded tuff unit, with basement Paleozoic sedimentary rock beginning at a depth of about 1000 m. The tuff is intact with a few fractures. There are no known faults located within 500 m of the borehole. Alteration of the underground environment--The blast created a spherical or near spherical cavity with a lens of vitrified material at the bottom. There are several zones surrounding the detonation point with decreasing levels of rock damage. The zones are: (1) the crushed zone (several tens of meters)where the rock has lost all prior integrity; (2) the fractured zone (out to a couple of hundred meters) characterized by radial and concentric fissures; and (3) the zone of irreversible strain (out to a couple of thousand meters) with local media deformation. A collapse chimney formed one hour after the detonation, in which overlying material fell into the explosion cavity. This chimney zone reached up to within 50 m of the surface and a small apical void formed (10 m high and 80 m in diameter) at the top of the rubble chimney. The rubble chimney is dry and density is about 20% less than the surrounding intact rock. Alteration at the surface--No surface depression formed, but there is significant 'fluffing' of the surface soil from the effects of the initial shock wave. A few radial and concentric fractures formed from the shock effects within a radius of 200 m of the borehole. Radionuclide environment--No particulates or aerosol radiological material reached the surface. However, the stemming is not completely impervious to gas release and a small amount of gas and vapor was released along the emplacement pipe immediately after the explosion and before the rubble chimney formed. Most of the gas venting stopped as soon as cavity collapse occurred. After the rubble chimney formed and the pressure in the explosion cavity reached equilibrium, gases began to migrate up through the rubble chimney aided by barometric pumping. There is also an unknown fault located 300 m from the explosion cavity that provided another gas migration pathway between the damage zone of the cavity and the surface.

155

Spatial variability in nutrient concentration and biofilm nutrient limitation in an urban watershed  

Nutrient enrichment threatens river ecosystem health in urban watersheds, but the influence of urbanization on spatial variation in nutrient concentrations and nutrient limitation of biofilm activity are infrequently measured simultaneously. In summer 2009, we used synoptic sampling to measure spatial patterns of nitrate (NO3 ?), ammonium (NH4 +), and soluble reactive phosphorus (SRP) concentration, flux, and instantaneous yield throughout the Bronx River watershed within New York City and adjacent suburbs. We also quantified biofilm response to addition of NO3 ?, phosphate (PO4 3?), and NO3 ??+?PO4 3? on organic and inorganic surfaces in the river mainstem and tributaries. Longitudinal variation in NO3 ? was low and related to impervious surface cover across sub-watersheds, but spatial va...

156

External geo-information in the segmentation of VHR imagery improves the detection of imperviousness in urban neighborhoods  

Object-based image analysis (OBIA) has become an established way to detect imperviousness and other land cover classes from very high resolution (VHR) multispectral imagery. Data fusion with LiDAR derived digital surface models (DSM) and large scale vectorial datasets containing building footprints and road boundaries have the potential to significantly improve this method. However, the individual contribution of the large scale vectorial dataset remains unclear. In this paper, we studied the improvement of segmentation and classification results when including a vectorial dataset in the OBIA. Two slightly different segmentation methods making use of the vectorial dataset (boundary suggestion method and absolute boundary method) are compared with each other, with a per-pixel classification...

157

Determination of a rational injection pressure related to in-situ stress in dam foundation grouting. Dam kiso ganban ni okeru chiatsu sokutei to goritekina grouting chunyu atsuryoku sentei ho  

The result of study on injection pressure is reported which is considered to be the factor having the highest effect on the mechanism of dam foundation grouting. Cement absorption in dam foundation grouting is strongly influenced by injection pressure. If a higher pressure than a reasonable one is applied, the grout take increases rapidly, but a harmful heave will occur. The injection pressure of dam grouting is closely related with the ground pressure at the injection site. The injection pressure, therefore, must be a little higher than the minimum horizontal ground pressure. An example of work, in which the injection pressure based on this concept is employed, proves that no water leakage through the foundation is observed after impounding and a grout curtain with a good impervious function is formed. Therefore, the injection pressure determined basing on this study is verified to be appropriate. 23 refs., 15 figs., 5 tabs.

158

Tunisia's Jasmine Revolution & the Arab Spring: Implications for International Intervention  

Tunisia's Jasmine revolution and the Arab Spring are unfolding amidst the resurgence of five sets of debates over the proper role of the international community in democracy promotion efforts abroad, including in the Middle East and North Africa, which were once thought to be impervious to democratic change. These debates, which are explored here within the context of the Arab Spring, range from the normative question of whether the international community should be actively involved in democracy promotion efforts abroad, to what forms of intervention should constitute part of the global arsenal for those intent on seeking democracy's spread. A final section reflects on whether international efforts will contribute to the further strengthening of the Arab Spring or a return to an Arab Wint...

159

Effects of urbanization on macroinvertebrates in tributaries of the St. Johns River, Florida, USA  

The effects of urbanization on hydrology, water quality and macroinvertebrates were examined in 7 headwater tributaries of the St. Johns River in the Atlantic Coastal Plain of northeast Florida. All streams had sandy substrata and drained small catchments (24?231?ha) that ranged from 0 to 51% total impervious area (TIA). Streams unaffected by urbanization had intermittent stream flow and completely dry channels for several weeks in autumn and spring. Urbanized streams always possessed channel water, but 2 streams ceased flowing and became stagnant in autumn and spring. Principle components analysis of chemical and physical measures (i.e. conductivity, nutrients, pH, metals, and stream flow) produced one axis (PCA1) that explained 54% of the total variation among the streams. The variables ...

160

The role of climate on inter-annual variation in stream nitrate fluxes and concentrations  

In recent decades, temporal variations in nitrate fluxes and concentrations in temperate rivers have resulted from the interaction of anthropogenic and climatic factors. The effect of climatic drivers remains unclear, while the relative importance of the drivers seems to be highly site dependent. This paper focuses on 2???6 year variations called meso-scale variations, and analyses the climatic drivers of these variations in a study site characterized by high N inputs from intensive animal farming systems and shallow aquifers with impervious bedrock in a temperate climate. Three approaches are developed: 1) an analysis of long-term records of nitrate fluxes and nitrate concentrations in 30 coastal rivers of Western France, which were well-marked by meso-scale cycles in the fluxes and conc...

 
 
 
 
161

Modelling the artificial recharge of a wetland and its influence on regional hydrological process in China: a case study  

Abstract Wetlands are constantly affected by human activities such as landscaping, additional abstractions, and changes in catchment imperviousness, resulting in the reduction of wetland area and degeneration of water quality. Modelling of such anthropogenic factors should be explicitly considered, in order to provide better understanding of the hydrological impacts of wetland restoration. In this paper, the wetland module in a distributed hydrological model, SWAT, is modified to simulate the artificial water input to the designated wetlands. The impact and effect of recharging wetlands on local hydrological cycle, sea outflow and estuary ecology is discussed. The Qingdianwa depression, located in the north of Tianjin city, China, is used as a case study to investigate the effect of human ...

162

Experiences in environmental monitoring with BeO ceramic dosimeters  

Ceramic BeO disks used as radiation detectors have been evaluated in environmental radiation fields by observing the TL and TSEE signals given off after heating the disks. Fluxes of low energy photons cause the values for the two apparent exposure rates to diverge; this provides a measure of the quality of the photon radiation field. The mean of the TL and TSEE derived exposure rates is close to the exposure rate as determined by other means. The TL-TSEE dosimeters perform satisfactorily provided moisture is not allowed to condense onto the BeO and wet its surface when the temperature falls below the dew point. Thin impervious plastic packets or aluminium cans, containing silica gel desiccant, provide adequate protection. (auth)

163

Novel Concepts for the Design and Manufacture of Solid Supports for Synthesis of Peptides  

Two novel concepts for the design and manufacture of polymer supports for solid phase synthesis of peptides are described. The first concept involves the encapsulation of polymers within the hole of short pieces of capillary tubing often referred to as seed beads. This provides a rigid exo-skeleton for the support of soft polymer gel and other mechanically fragile polymer based matrices. The rigidity of the support provides a polymeric media that is particularly suited to continuous flow based peptide synthesis. The second concept complements this by providing an inexpensive approach to the preparation of spherical polymer particles by coating commercially available impervious hollow glass microspheres with polymer. The added advantage of this approach lies in the buoyancy of the resultant...

164

Proceedings of the 2004 High Spatial Resolution Commercial Imagery Workshop  

Topics covered include: NASA Applied Sciences Program; USGS Land Remote Sensing: Overview; QuickBird System Status and Product Overview; ORBIMAGE Overview; IKONOS 2004 Calibration and Validation Status; OrbView-3 Spatial Characterization; On-Orbit Modulation Transfer Function (MTF) Measurement of QuickBird; Spatial Resolution Characterization for QuickBird Image Products 2003-2004 Season; Image Quality Evaluation of QuickBird Super Resolution and Revisit of IKONOS: Civil and Commercial Application Project (CCAP); On-Orbit System MTF Measurement; QuickBird Post Launch Geopositional Characterization Update; OrbView-3 Geometric Calibration and Geopositional Accuracy; Geopositional Statistical Methods; QuickBird and OrbView-3 Geopositional Accuracy Assessment; Initial On-Orbit Spatial Resolution Characterization of OrbView-3 Panchromatic Images; Laboratory Measurement of Bidirectional Reflectance of Radiometric Tarps; Stennis Space Center Verification and Validation Capabilities; Joint Agency Commercial Imagery Evaluation (JACIE) Team; Adjacency Effects in High Resolution Imagery; Effect of Pulse Width vs. GSD on MTF Estimation; Camera and Sensor Calibration at the USGS; QuickBird Geometric Verification; Comparison of MODTRAN to Heritage-based Results in Vicarious Calibration at University of Arizona; Using Remotely Sensed Imagery to Determine Impervious Surface in Sioux Falls, South Dakota; Estimating Sub-Pixel Proportions of Sagebrush with a Regression Tree; How Do YOU Use the National Land Cover Dataset?; The National Map Hazards Data Distribution System; Recording a Troubled World; What Does This-Have to Do with This?; When Can a Picture Save a Thousand Homes?; InSAR Studies of Alaska Volcanoes; Earth Observing-1 (EO-1) Data Products; Improving Access to the USGS Aerial Film Collections: High Resolution Scanners; Improving Access to the USGS Aerial Film Collections: Phoenix Digitizing System Product Distribution; System and Product Characterization: Issues Approach; Innovative Approaches to Analysis of Lidar Data for the National Map; Changes in Imperviousness near Military Installations; Geopositional Accuracy Evaluations of QuickBird and OrbView-3: Civil and Commercial Applications Project (CCAP); Geometric Accuracy Assessment: OrbView ORTHO Products; QuickBird Radiometric Calibration Update; OrbView-3 Radiometric Calibration; QuickBird Radiometric Characterization; NASA Radiometric Characterization; Establishing and Verifying the Traceability of Remote-Sensing Measurements to International Standards; QuickBird Applications; Airport Mapping and Perpetual Monitoring Using IKONOS; OrbView-3 Relative Accuracy Results and Impacts on Exploitation and Accuracy Improvement; Using Remotely Sensed Imagery to Determine Impervious Surface in Sioux Falls, South Dakota; Applying High-Resolution Satellite Imagery and Remotely Sensed Data to Local Government Applications: Sioux Falls, South Dakota; Automatic Co-Registration of QuickBird Data for Change Detection Applications; Developing Coastal Surface Roughness Maps Using ASTER and QuickBird Data Sources; Automated, Near-Real Time Cloud and Cloud Shadow Detection in High Resolution VNIR Imagery; Science Applications of High Resolution Imagery at the USGS EROS Data Center; Draft Plan for Characterizing Commercial Data Products in Support of Earth Science Research; Atmospheric Correction Prototype Algorithm for High Spatial Resolution Multispectral Earth Observing Imaging Systems; Determining Regional Arctic Tundra Carbon Exchange: A Bottom-Up Approach; Using IKONOS Imagery to Assess Impervious Surface Area, Riparian Buffers and Stream Health in the Mid-Atlantic Region; Commercial Remote Sensing Space Policy Civil Implementation Update; USGS Commercial Remote Sensing Data Contracts (CRSDC); and Commercial Remote Sensing Space Policy (CRSSP): Civil Near-Term Requirements Collection Update.

165

Passivation coating for flexible substrate mirrors  

A protective diffusion barrier for metalized mirror structures is provided by a layer or coating of silicon nitride which is a very dense, transparent, dielectric material that is impervious to water, alkali, and other impurities and corrosive substances that typically attack the metal layers of mirrors and cause degradation of the mirrors' reflectivity. The silicon nitride layer can be deposited on the substrate before metal deposition thereon to stabilize the metal/substrate interface, and it can be deposited over the metal to encapsulate it and protect the metal from corrosion or other degradation. Mirrors coated with silicon nitride according to this invention can also be used as front surface mirrors. Also, the silver or other reflective metal layer on mirrors comprising thin, lightweight, flexible substrates of metal or polymer sheets coated with glassy layers can be protected with silicon nitride according to this invention.

166

The use of a solid polymer electrolyte in alkaline fuel cells; Utilisation d'electrolyte solide polymere dans les piles a combustibles alcalines  

The objective of this research was to develop a new type of cheap anion exchange membranes for use in alkaline fuel cells. The polyelectrolyte anion exchange membrane was prepared by grafting quaternary amines (DABCO, TEA) on the epichlorohydrin polymer, consolidated by reticulation. Obtained ionic conductivities are over 10{sup -2} S.cm{sup -1}, with a concentration of positive ionic sites of a few milli-equivalents per gram of material. Measured anionic transport numbers are greater than 0.90. Membranes, which can absorb 30 to 50 % of water, are quasi impervious to gases such as H{sub 2} and O{sub 2} and can operate at temperatures up to 120 deg C. Alkaline fuel cells assembled with both types of membranes showed good performances. Particular attention was devoted to the membrane-electrode interface. (authors)

167

Understanding Economic Justice Attitudes in Two Countries: Kazakhstan and Kyrgyzstan  

Analyzing data from the 2007 Kazakhstan and Kyrgyzstan Inequality Survey, I identify and compare the determinants of economic justice attitudes in two formerly similar majority-Muslim nations that are now distinguished almost exclusively by their dissimilar economic circumstances following the collapse of the Soviet Union. In Kazakhstan, where the economy is growing rapidly, the important factors predicting economic egalitarianism are connected to people's perceived ability to do well in the future. In contrast, in Kyrgyzstan, which has stagnated in the post-Soviet era, people's immediate economic vulnerability predicts egalitarianism, while their economic prospects are irrelevant. Finally, the effect of several factors on support for egalitarianism appears impervious to the prevailing economic winds: religious orthodoxy, the urban vs. rural divide, and membership in a historically privileged ethnic group. These patterns reflect both the commonalities in the two countries' histories, demography, and religion and their divergent economic trajectories since the collapse of the USSR. (Contains 5 tables and 10 notes.)

168

Perforation sealer  

An improved perforation sealer is described for use in oil wells, gas wells, and similar boreholes. The sealer includes an at least partially spheroidal body of resilient material of sufficient size to lodge in a perforation as fluid enters the perforation. A flexible skirt of fluid-impervious material is attached to and extends outward about the body for a distance sufficient to overspread the wall surface adjacent to the perforation. When such a sealer seats in a non-circular perforation, the escape of fluid through the unplugged portion of the perforation around the sealer body forces the flexible skirt into or over the opening. This seals the irregular opening and thus reduces or prevents further escape of the fluid. When the pressure within the pipe is reduced and the well is placed on production, the sealer is dislodged and carried to the surface with the produced fluid. (6 claims)

169

A Smart Market for Impervious Cover  

When farmland or undeveloped ground is covered over, runoff can cause environmental damage and flood risk. Policymakers want to compare the economic improvement of new development to the costs produced by the associated environmental impacts. In this paper, we propose a smart market in impervious cover. A smart market is a periodic auction which is cleared by an optimization model, a linear program (LP) in this case. The LP constraint coefficients come from a hydrological model. The LP objective coefficients come from users? bids. To operate the auction, local government would appoint an auction manager, who would be responsible for maintaining the hydrological model and the LP, for operating the auction, and for maintaining the desired environmental standards. At regular intervals, the au...

170

Phosphate ceramic process for macroencapsulation and stabilization of low-level debris wastes  

Across the DOE complex, large quantities of contaminated debris and irradiated lead bricks have been accumulated for disposal. Under the US Environmental Protection Agency`s Alternative Treatment Standards, the preferred method of disposal of these wastes is macroencapsulation. Chemically bonded phosphate ceramic (CBPC) is a novel binder that was developed at Argonne National Laboratory to stabilize and solidify various low-level mixed wastes. This binder is extremely strong, dense, and impervious to water. In this investigation, CBPC has been used to demonstrate macroencapsulation of various contaminated debris wastes, including cryofractured debris, lead bricks, lead-lined plastic gloves, and mercury-contaminated crushed glass. This paper describes the fabrication of the waste forms, as well as the results of various characterizations performed on the waste forms. The results show that the simple and low-cost CBPC is an excellent material system for the macroencapsulation of debris wastes.

171

Macroencapsulation of low-level debris waste with the phosphate ceramic process  

Across the DOE complex, large quantities of contaminated debris and irradiated lead bricks require disposal. The preferred method for disposing of these wastes is macroencapsulation under U.S. Environmental Protection Agency Alternative Treatment Standards. Chemically bonded phosphate ceramics serve as a novel binder, developed at Argonne National Laboratory, for stabilizing and solidifying various low-level mixed wastes. Extremely strong, dense, and impervious to water intrusion, this material was developed with support from the U.S. Department of Energy`s Office of Science and Technology (DOE OST). In this investigation, CBPCs have been used to demonstrate macroencapsulation of various contaminated debris wastes, including cryofractured debris, lead bricks, and lead-lined plastic gloves. This paper describes the processing steps for fabricating the waste forms and the results of various characterizations performed on the waste forms. The conclusion is that simple and low-cost CBPCs are excellent material systems for macroencapsulating debris wastes.

172

Forms and behaviour of vacuum emission electronic devices comprising diamond or other carbon cold cathode emitters.  

Nanocarbon-derived electron emission devices, specifically nanodiamond lateral field emission (FE) diodes and gated carbon nanotube (CNT) triodes, are new configurations for robust nanoelectronic devices. These novel micro/nanostructures provide an alternative and efficient means of accomplishing electronics that are impervious to temperature and radiation. For example, nitrogen-incorporated nanocrystalline diamond has been lithographically micropatterned to use the material as an electron field emitter. Arrays of laterally arranged 'finger-like' nanodiamond emitters constitute the cathode in a versatile diode configuration with a small interelectrode separation. A low diode turn-on voltage of 7V and a high emission current of 90 microA at an anode voltage of 70V (electric field of approx. 7V microm(-1)) are reported for the nanodiamond lateral device. Also, a FE triode amplifier based on aligned CNTs with a low turn-on voltage and a small gate leakage current has been developed. PMID:18024363

173

Vegetated roofs for stormwater management at multiple spatial scales  

Stormwater runoff from impervious surfaces and other urban land cover is particularly detrimental to receiving water bodies in urban centers. A variety of management practices exist to combat the environmental degradation associated with the altered hydrology in urban areas. Vegetated, or green, roofs are emerging as one of these stormwater management tools in the United States. Investigations have primarily been focused on roof-scale processes such as individual roof stormwater retention, plant growth, or growing media composition. Few studies have examined the impact that widespread green roof application could have on the hydrology of a real-world watershed. Using local green roof stormwater retention data, this study modeled hydrologic effects of green roofing scenarios in an urban wat...

174

Conspirators in a Neo-Liberal Agenda? Adult Educators in Second-Chance Private Training Establishments  

This paper presents the findings of a qualitative study that explored the impact of neo-liberal policy and ideology on educators and directors working in second-chance Private Training Establishments (PTEs) which were created at the height of the neo-liberal reforms in New Zealand. By examining the experiences of 14 educators and directors in four PTEs, this research found that although those working in second-chance PTEs are not impervious to neo-liberal discourse and policy, they do not automatically reflect a rightist agenda. While assessment, funding, outcomes, and monitoring have encouraged tutors and directors to adopt a more behaviourist approach in the classroom and in their jobs, the findings also indicate that adult educators critically examine and constantly negotiate their practice. (Contains 2 figures and 3 notes.)

175

Time of concentration on impervious overland  

Many types of factors were devised to calculate time of concentration. Singh(1976) derived time of concentration of overland flow using kinematic wave theory for plane, converging, and diverging geometric configurations. The present paper investigated the time of concentration for particularly plane geometric configuration. A theoretical equation of time of concentration is derived based on the assumption of impervious overland flow as in the open channel flow. The study characterized the overland flow by many types of characteristic flow such as rough turbulent flow, smooth turbulent flow, laminar flow, and then suggested a theoretical equation on each flow condition. The present paper further considered the rainfall intensity as a main factor and devised an approximate composite equation reflecting the effect of rainfall intensity given at various return periods. (author). 4 refs., 3 tabs., 2 figs.

176

Regulated assembly of the transenvelope protein complex required for lipopolysaccharide export.  

Gram-negative bacteria are impervious to many drugs and environmental stresses because they possess an outer membrane (OM) containing lipopolysaccharide (LPS). LPS is biosynthesized at the cytoplasmic (inner) membrane and is transported to the OM by an unknown mechanism involving the LPS transport proteins, LptA-G. These proteins have been proposed to form a bridge between the two membranes; however, it is not known how this bridge is assembled to prevent mistargeting of LPS. We use in vivo photo-cross-linking to reveal the specific protein-protein interaction sites that give rise to the Lpt bridge. We also show that the formation of this transenvelope bridge cannot proceed before the correct assembly of the LPS translocon in the OM. This ordered sequence of events may ensure that LPS is never transported to the OM if it cannot be translocated across it to the cell surface. PMID:22668317

177

A Method for the Removal of Tungsten Carbide Rings  

BackgroundThe removal of metal rings from fingers is a well-described process that often employs a toothed cutting wheel or bolt cutters to sever the ring and allow it to be pried open. However, tungsten carbide (TC) rings are impervious to these traditional ring-cutting devices. Study ObjectivesWe sought to describe a method for removal of TC rings from cadaveric fingers and characterize potential complications of the technique. MethodsOn cadaveric fingers, we placed TC rings and created a snug fit by injecting a fluorescein and saline solution. The rings were removed by a controlled crushing technique using a pair of locking pliers. Fingers were inspected under magnification and using an LED (light-emitting diode) black light, and X-ray studies of each finger were obtained. Injuries were...

178

Simplified Model for CO2 Leakage and its Attenuation due to Geological Structures  

For risk associated with storage of CO2 under the Earth’s surface, the impervious cap is one of the most significant factors. Geological structures such as faults can provide conduits for CO2 to escape through the cap. When conductive faults intersect the storage formation and overlying permeable layers, CO2 leaks may exhibit three distinct behaviors: initial upward migration of fluids through the fault, lateral fluid movement through permeable layers, and continued movement of CO2 along the fault above the leakage pathways. To quantify this behavior, especially the attenuation, we develop a quasi-1D model for migration of buoyant fluid from a reservoir along a conductive fault. The fault can intersect multiple shallower formations. The model accounts for flow from the fault into a ...

179

Amount of water runoff from different vegetation types on extensive green roofs: Effects of plant species, diversity and plant structure  

Increased stormwater runoff from impervious surfaces is a major concern in urban areas and green roofs are increasingly used as an innovative means of stormwater management. However, there are very few studies on how different vegetation types affect the amount of water runoff. This paper describes an experiment that investigates the influence of plant species and plant diversity on the amount of water runoff from a simulated green roof. Twelve species were selected from the three major taxonomic and functional plant groups that are commonly used for extensive green roofs (forbs, sedum and grasses). Four species were chosen from each group and planted in combinations of increasing diversity and complexity: monocultures, four-species mixtures and twelve-species mixtures. The results showed ...

180

Performance of stormwater detention tanks for urban drainage systems in northern Italy  

The performance of stormwater detention tanks with alternative design configurations (insertion in the storm sewer network; volume per impervious hectare) and operating conditions (continuous and intermittent emptying rules) have been evaluated according to an integrated approach. Various performance indices have been adopted to describe the mitigation of the pollution impact to the natural environment, the reduction of the management and maintenance charges for the urban drainage system, the preservation of the normal purification efficiency, and the limitation of the costs at the treatment plant. The US EPA Storm Water Management Model has been used to simulate the rainfall-runoff process and the pollutant dynamics on theoretical catchments and storm sewer networks for an individual even...

 
 
 
 
181

Remote sensing of the urban heat island effect across biomes in the continental USA  

Impervious surface area (ISA) from the Landsat TM-based NLCD 2001 dataset and land surface temperature (LST) from MODIS averaged over three annual cycles (2003-2005) are used in a spatial analysis to assess the urban heat island (UHI) skin temperature amplitude and its relationship to development intensity, size, and ecological setting for 38 of the most populous cities in the continental United States. Development intensity zones based on %ISA are defined for each urban area emanating outward from the urban core to the non-urban rural areas nearby and used to stratify sampling for land surface temperatures and NDVI. Sampling is further constrained by biome and elevation to insure objective intercomparisons between zones and between cities in different biomes permitting the definition of h...

182

Gas-path leakage seal for a gas turbine  

A gas-path leakage seal for generally sealing a gas-path leakage-gap between spaced-apart first and second members of a gas turbine (such as combustor casing segments). The seal includes a generally imperforate foil-layer assemblage which is generally impervious to gas and is located in the leakage-gap. The seal also includes a cloth-layer assemblage generally enclosingly contacting the foil-layer assemblage. In one seal, the first edge of the foil-layer assemblage is left exposed, and the foil-layer assemblage resiliently contacts the first member near the first edge to reduce leakage in the "plane" of the cloth-layer assemblage under conditions which include differential thermal growth of the two members. In another seal, such leakage is reduced by having a first weld-bead which permeates the cloth-layer assemblage, is attached to the metal-foil-layer assemblage near the first edge, and unattachedly contacts the first member.

183

Immersion transients reveal potential of zero charge of nanoparticle films  

We present a simple yet absolute method for the assignment of the zero charge state of metal nanoparticle films during their electrochemical charging. The method is based on measuring the current transient that accompanies the potential controlled immersion of a pristine, ion-free cluster film in an electrolyte, and does not rely on relative quantities such as mass changes of an already immersed film. Therefore, the method is impervious to details of counter ion insertion - for instance whether the electrolyte can partition into the film or not - without which no charging can be observed. Examples of positive and negative ion-limited charging are presented, and an example of ambipolar cluster charging, covering the three possible cases. The immersion method can be readily applied to other ...

184

Effects of wounding and fungal infection with Armillaria ostoyae in three conifer species. II. Host response to the pathogen  

Summary Structural responses in the bark and wood were described following penetration by Armillaria ostoyae in the roots of 20- to 30-year-old Douglas-fir, western hemlock and western redcedar trees. Tissue necrosis presumably caused by fungal exudates was commonly observed at inoculum contact. In Douglas-fir and western hemlock, A.ostoyae interfered with the initiation of active defence mechanisms involving the development of a lignified zone of impervious tissue (IT), necrophylactic periderm (NP) formation and compartmentalization of infected woody tissue. Breaching of IT and NP barriers was frequent, particularly around the clusters of sclereid cells in western hemlock. In western redcedar, the IT zone was inconspicuous. Induced rhytidome formation occurred in western redcedar either s...

185

Composition and apparatus for detecting gamma radiation  

A gamma radiation detector and a radioluminiscent composition for use therein. The detector includes a radioluminscent composition that emits light in a characteristic wavelength region when exposed to gamma radiation, and means for detecting said radiation. The composition contains a scintillant such as anglesite (PbSO.sub.4) or cerussite (PbCO.sub.3) incorporated into an inert, porous glass matrix via a sol-gel process. Particles of radiation-sensitive scintillant are added to, a sol solution. The mixture is polymerized to form a gel, then dried under conditions that preserve the structural integrity and radiation sensitivity of the scintillant. The final product is a composition containing the uniformly-dispersed scintillant in an inert, optically transparent and highly porous matrix. The composition is chemically inert and substantially impervious to environmental conditions including changes in temperature, air pressure, and so forth. It can be fabricated in cylinders, blocks with holes therethrough for flow of fluid, sheets, surface coatings, pellets or other convenient shapes.

186

The Mycobacterium DosR regulon structure and diversity revealed by comparative genomic analysis  

Abstract Tuberculosis (TB), caused by Mycobacterium tuberculosis (Mtb), which claims approximately two million people annually, remains a global health concern. The non-replicating or dormancy like state of this pathogen which is impervious to anti-tuberculosis drugs is widely recognized as the culprit for this scenario. The dormancy survival regulator (DosR) regulon, composed of 48 co-regulated genes, is held as essential for Mtb persistence. The DosR regulon is regulated by a two-component regulatory system consisting of two sensor kinases-DosS (Rv3132c) and DosT (Rv2027c), and a response regulator DosR (Rv3133c). The underlying regulatory mechanism of DosR regulon expression is very complex. Many factors are involved, particularly the oxygen tension. The DosR regulon enables the pathoge...

187

Modeling urban storm rainfall runoff from diverse underlying surfaces and application for control design in Beijing  

Managing storm rainfall runoff is paramount in semi-arid regions with urban development. In Beijing, pollution prevention in urban storm runoff and storm water utilization has been identified as the primary strategy for urban water management. In this paper, we sampled runoff during storm rainfall events and analyzed the concentration of chemical oxygen demand (COD), total suspended solids (TSS) and total phosphorus (TP) in the runoff. Furthermore, the first flush effect of storm rainfall from diverse underlying surfaces was also analyzed. With the Storm Water Management Model (SWMM), the different impervious rates of underlying surfaces during the storm runoff process were expressed. The removal rates of three typical pollutants and their interactions with precipitation and underlying sur...

188

Modeling and validation of on-road CO2 emissions inventories at the urban regional scale.  

On-road emissions are a major contributor to rising concentrations of atmospheric greenhouse gases. In this study, we applied a downscaling methodology based on commonly available spatial parameters to model on-road CO(2) emissions at the 1 × 1 km scale for the Boston, MA region and tested our approach with surface-level CO(2) observations. Using two previously constructed emissions inventories with differing spatial patterns and underlying data sources, we developed regression models based on impervious surface area and volume-weighted road density that could be scaled to any resolution. We found that the models accurately reflected the inventories at their original scales (R(2) = 0.63 for both models) and exhibited a strong relationship with observed CO(2) mixing ratios when downscaled across the region. Moreover, the improved spatial agreement of the models over the original inventories confirmed that either product represents a viable basis for downscaling in other metropolitan regions, even with limited data. PMID:22776716

189

Project for the establishment of photovoltaic and aeolian renewable energy station in the TLC field; Realizzazione di un programma per il dimensionamento di stazioni di energia rinnovabile, fotovoltaica ed eolica, per il settore delle telecomunicazioni  

The rising problems connected with atmospheric (environmental) pollution, the difficulties reaching telecommunication sites placed in inaccessible areas with electric lines, can induce everyone to look for new solutions for the power supplying of TLC devices. The renewable energy systems, even if more expensive in proportion, have the required specifications. This study was made to assess, from a technical and economical point of view, the possibility to build photovoltaic and aeolian equipment. [Italian] I crescenti problemi legati all'inquinamento atmosferico, la difficolta' a raggiungere con linee elettriche siti di telecomunicazioni posti in zone impervie, spingono a trovare nuove soluzioni per l'alimentazione di apparati di TLC. I sistemi di energia rinnovabili, anche se relativamente piu' costosi, possiedono le caratteristiche richieste. Questo studio serve a valutare, dal punto di vista tecnico, ed economico, la fattibilita' di questi impianti fotovoltaici ed eolici.

190

Fate and distribution of fipronil on companion animals and in their indoor residences following spot-on flea treatments.  

Use of fipronil {5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile CAS 120068-37-3} topical pet products on dogs and cats introduces low level residues into residences. Distribution and fate studies of fipronil on pets and in residences were performed to evaluate potential determinants of human exposure. Fipronil, desulfinyl fipronil, fipronil sulfone and fipronil sulfide were measured on hair clippings and brushed hair. The derivatives usually represented <10% of fipronil applied. Cotton gloves worn over impervious nitrile gloves, cotton cloths placed indoors in locations frequented by pets, and cotton socks worn by residents as direct dosimeters collected fipronil and its derivatives listed above in low amounts during 4-week study periods. Subsequent acid hydrolysis urine biomonitoring did not reveal significant excretion of biomarkers at ppb levels. The human exposure potential of fipronil is low relative to levels of health concern. PMID:22938575

191

Method for making a lightweight bipolar metal-gas battery  

A method is described for constructing a multi-cell bipolar metal-gas battery stack, in which a metal and a primary gas are reactants. The method consists of: fabricating a dielectric frame generally in the shape of a hollowed-out prism having inner width and inner length dimensions defining the common width and the common length of each stacked cell; placing, within the hollowed-out portion of the frame, substantially planar solid components constituting several substantially identical stacked cells, wherein each cell comprises positive and negative electrodes separated by an electrolyte impervious layer; and electrically series-connecting adjacent cells by means of forming, outside the frame, electrical connections between oppositely polarized electrodes from adjacent pairs of cells; wherein the frame confines, within each cell, electrolyte and secondary gas generated by the positive electrode of the cell; and all of the cells have equal access to a common supply of the primary gas.

192

Potassium sulfate mud - meeting the needs of the demanding Rainbow Lake Field  

Potassium sulphate fluid has been used in wells in the Rainbow Field at times when Fort Simpson shale was to be drilled. An evaluation of the process was conducted. The focus of the system evaluation was cost and problem time. Since the introduction to the Rainbow Field in 1996, results have been found to be favourable. The cost savings was estimated at $11,000 to $19,000 per well. Characteristics features of the potassium sulphate system are: (1) it minimizes borehole instability and is impervious to anhydrite contamination, (2) presents minimal environmental risk and disposal issues, and (3) is an effective fluid for hole cleaning provided chemical dispersion is kept to a minimum. The potassium sulphate mud system resulted in 15 to 23 fewer problem hours per well. It was concluded that the use of potassium sulphate fluid compared very favourably with gel chemical-polymer performance. 8 refs., 8 figs.

193

The Politics of Obesity: A Current Assessment and Look Ahead  

Context: The continuing rise in obesity rates across the United States has proved impervious to clinical treatment or public health exhortation, necessitating policy responses. Nearly a decade's worth of political debates may be hardening into an obesity issue regime, comprising established sets of cognitive frames, stakeholders, and policy options. Methods: This article is a survey of reports on recently published studies. Findings: Much of the political discussion regarding obesity is centered on two "frames," personal-responsibility and environmental, yielding very different sets of policy responses. While policy efforts at the federal level have resulted in little action to date, state and/or local solutions such as calorie menu labeling and the expansion of regulations to reduce unhea...

194

Subterranean well safety valve with reference pressure chamber  

A subsurface safety valve for use in subterranean oil and gas well which is actuated by pressure fluctuations in the tubing-casing annulus is disclosed. The safety valve assembly consists of a safety valve mounted in a packer which is actuated by a subsurface control located above the packer. Annulus pressure variations are controlled by a surface unit. The subsurface control utilizes a reference pressure chamber in which the pressure is initially adjustable to compensate for hydrostatic pressure in the annulus. Leakage of the gas in a dome pressure chamber in the subsurface control is impeded by the presence of a barrier fluid impervious to the passage of gas there through, with the barrier fluid being maintained at a higher pressure than the reference pressure in the dome charged chamber.

195

The effect of urban leaf area on summertime urban surface kinetic temperatures: A Terre Haute case study  

The urban heat island effect (UHIE) has been documented in many temperate region cities. One cause of the UHIE is the replacement of green spaces with impervious materials as urbanization commences and the city builds up and fills in. During the summer, elevated urban temperatures result in increased electricity usage, higher pollution levels, and greater resident discomfort. Through evapotranspiration and the interception of solar radiation, increasing urban tree canopy cover can help mitigate the UHIE. While this is universally accepted, the exact statistical relationship between urban leaf area (as measured by leaf area index, LAI) and urban temperatures has not been extensively studied. In a case study conducted in urban/suburban Terre Haute, Indiana, USA, simple linear regression was ...

196

Evaluation of the DisTrad thermal sharpening methodology for urban areas  

The goal of this paper is to evaluate the DisTrad sharpening technique for deriving land surface temperatures over urban areas. While the original DisTrad technique is based on the correlation between land surface temperature and NDVI, this study evaluates the performance of DisTrad over different land covers by analysing the correlation between land surface temperature and 15 different indices: BASVI, R, B, NDWI, NDBaI, SVI, SAVI, NDBI, NDSI, UI, FC, VC, V, IBI, NDVI. In addition, we have analysed the correlation between land surface temperature and impervious percentage. These indices and land surface temperature were derived from a Landsat 7 ETM+ image of 2001 covering the city of Dublin. It is concluded that for most indices selecting 25% of the pixels with the lowest coefficient of va...

197

Enhanced performance of organic electroluminescent diodes by UV-ozone treatment of molybdenum trioxide  

The operating voltage is reduced and luminous efficiency is improved in the organic light-emitting diodes (OLEDs) with UV-ozone treatment of molybdenum trioxide (MoO"3) anode buffer layer. The interface of indium tin oxide (ITO)/MoO"3 was investigated by X-ray photoelectron spectroscopy. It was found that the binding energies of Mo 3d, O 1s, In 3d and C 1s were shifted to higher after UV-ozone treated MoO"3. The enhanced properties are impervious to the UV-ozone treatment of ITO. Therefore, the improved performance can be attributed that the binding energies of Mo 3d, O 1s, In 3d and C 1s are changed to higher and also that the sheet resistance of ITO/MoO"3 films is decreased after UV-ozone treated MoO"3.

198

Seismic expression of subtle strat trap in upper Cretaceous Almond  

The east flank of the Rock Springs uplift and the adjacent Wamsutter arch contain several large hydrocarbon accumulations. Among these accumulations are Patrick Draw field, which produces oil and gas from a stratigraphic trap in the upper Cretaceous Almond formation, and Table Rock field, a faulted anticlinal trap that produces gas from multiple Tertiary, Mesozoic, and Paleozoic reservoirs. The principal petroleum reservoir in Patrick Draw field is a sandstone at the top of the Almond formation. This sandstone attains a maximum thickness of 35 ft (11 m) and pinches out westward into relatively impervious siltstone and shale that constitute the trapping facies. The objective of this investigation is to determine whether or not the stratigraphic trap at Patrick Draw can be detected on a 12 fold, common depth point seismic profile.

199

Faecal Coliforms in Bivalve Harvesting Areas of the Alvor Lagoon (Southern Portugal): Influence of Seasonal Variability and Urban Development  

Faecal coliform (FC) levels in surface water and clams (Ruditapes decussatus) and variations in environmental parameters were studied in two bivalve harvesting areas in the Alvor lagoon (southern Portugal). Land use and cover characteristics in adjacent subwatersheds were also analysed to assess their contributions as sources of faecal contamination. High FC levels in clams from the harvesting area in the most urbanized subwatershed (impervious surface coverage ? 10.5%) were positively associated with rainfall and with the cooler periods of the year. FC levels in clams from the least urbanized subwatershed were generally very low and did not present any detectable seasonal trend. From these results, it was concluded that the periodic deterioration of the microbiological quality of clams de...

200

Faecal coliforms in bivalve harvesting areas of the Alvor lagoon (southern Portugal): influence of seasonal variability and urban development.  

Faecal coliform (FC) levels in surface water and clams (Ruditapes decussatus) and variations in environmental parameters were studied in two bivalve harvesting areas in the Alvor lagoon (southern Portugal). Land use and cover characteristics in adjacent subwatersheds were also analysed to assess their contributions as sources of faecal contamination. High FC levels in clams from the harvesting area in the most urbanized subwatershed (impervious surface coverage approximately 10.5%) were positively associated with rainfall and with the cooler periods of the year. FC levels in clams from the least urbanized subwatershed were generally very low and did not present any detectable seasonal trend. From these results, it was concluded that the periodic deterioration of the microbiological quality of clams derives from the cumulative impact of the reservoir of faecal contamination created in urbanized areas, entering into the lagoon during storm water runoff. PMID:17286181

 
 
 
 
201

Agrobacterium-mediated gene transfer and enhanced green fluorescent protein visualization in the mycorrhizal ascomycete Tuber borchii: a first step towards truffle genetics.  

Mycorrhizal ascomycetes are ecologically and commercially important fungi that have proved impervious to genetic transformation so far. We report here on the successful transient transformation of Tuber borchii, an ectomycorrhizal ascomycete that colonizes a variety of trees and produces highly prized hypogeous fruitbodies known as "truffles". A hypervirulent Agrobacterium tumefaciens strain bearing the binary plasmid pBGgHg was used for transformation. The genes for hygromycin resistance and the enhanced green fluorescent protein (EGFP), both under the control of vector-borne promoters, were employed as selection markers. Patches of dark and fluorescent hyphae were observed upon fluorescence microscopic examination of hygromycin-resistant mycelia. The presence of EGFP was confirmed by both confocal microscopy and PCR analysis. The lack in the transformed mycelia of the DNA coding for kanamicin resistance (a trait encoded by a vector-borne gene located outside of the T-DNA region) indicates that Agrobacterium-mediated gene transfer correctly occurred in T. borchii. PMID:15868150

202

Effects of projected future urban land cover on nitrogen and phosphorus runoff to Chesapeake Bay  

This paper examined the effects of simulated land cover/land use (LC/LU) change from 2000 to 2030 on nutrient loadings to the Chesapeake Bay. The SPAtially Referenced Regression On Watershed Attributes (SPARROW) model was used with anticipated watershed-wide LC/LU change from a growth forecast model that provides spatially explicit probabilities of conversion to impervious surface. The total nitrogen (TN) and total phosphorus (TP) loadings estimated to enter the Chesapeake Bay were reduced by 20% and 19%, respectively. In general, as development replaced other LC/LUs from 2000 to 2030, TN and TP runoff was significantly reduced by losses of non-point, non-urban source loadings, yields, and land-to-water delivery. The simulation results suggest future changes in landscape composition and co...

203

Evaluating impervious surface growth and its impacts on water environment in Beijing-Tianjin-Tangshan Metropolitan Area  

The impervious surface area (ISA) at the regional scale is one of the important environmental factors for examining the interaction and mechanism of Land Use/Cover Change (LUCC)-ecosystem processes-climate change under the interactions of urbanization and global environmental change. Timely and accurate extraction of ISA from remotely sensed data at the regional scale is challenging. This study explored the ISA extraction based on MODIS and DMSP-OLS data and the incorporation of China?s land use/cover data. ISA datasets in Beijing-Tianjin-Tangshan Metropolitan Area (BTTMA) in 2000 and 2008 at a spatial resolution of 250 m were developed, their spatiotemporal changes were analyzed, and their impacts on water quality were then evaluated. The results indicated that ISA in BTTMA increased rapi...

204

Modeling of continuous-time land cover change using satellite imagery: an application from North Carolina  

This study examines the determinants of urbanized area across a 10,000-mile square swath in central North Carolina, an area undergoing extensive conversion of forest and agricultural land. We model the temporal and spatial dimensions of these landscape changes using a database that links five satellite images spanning 1976-2001 to a suite of socioeconomic, ecological and GIS-created explanatory variables. By specifying the complementary log-log derivation of the proportional hazards model, we employ a methodology for modeling a continuous time process - the conversion of land to impervious surface - using discrete-time satellite data. Spatial hypotheses are tested using several variables derived from the imagery that measure the landscape configuration surrounding a pixel. Empirical result...

205

Long-term stormwater quantity and quality performance of permeable pavement systems.  

This study examined the long-term effectiveness of permeable pavement as an alternative to traditional impervious asphalt pavement in a parking area. Four commercially available permeable pavement systems were evaluated after 6 years of daily parking usage for structural durability, ability to infiltrate precipitation, and impacts on infiltrate water quality. All four permeable pavement systems showed no major signs of wear. Virtually all rainwater infiltrated through the permeable pavements, with almost no surface runoff. The infiltrated water had significantly lower levels of copper and zinc than the direct surface runoff from the asphalt area. Motor oil was detected in 89% of samples from the asphalt runoff but not in any water sample infiltrated through the permeable pavement. Neither lead nor diesel fuel were detected in any sample. Infiltrate measured 5 years earlier displayed significantly higher concentrations of zinc and significantly lower concentrations of copper and lead. PMID:14511707

206

Modeling urban films using a dynamic multimedia fugacity model  

A thin film coats impervious urban surfaces that can act as a source or sink of organic pollutants to the greater environment. We review recent developments in the understanding of film and film-associated pollutant behavior and incorporate them into an unsteady-state version of the fugacity based Multimedia Urban Model (MUM), focusing on detailed considerations of surface film dynamics. The model is used to explore the conditions under which these atmospherically-derived films act as a temporary source of chemicals to the air and/or storm water. Assuming film growth of 2.1nmd-1 (Wu et al., 2008a), PCB congeners 28 and 180 reach air-film equilibrium within hours and days, respectively. The model results suggest that the film acts as a temporary sink of chemicals from air during dry and coo...

207

Molten carbonate fuel cell reduction of nickel deposits  

A fuel cell is described comprising a porous anode, a transition metal-based porous cathode separated from the anode, means for directing a hydrogen-affording fuel gas to the anode and an oxidant including oxygen gas to the cathode, and an electrolyte component between the anode and cathode including an alkali metal carbonate as an electrolyte, a first gas-impervious tile member adjacent the anode and a second gas-permeable tile member adjacent the cathode. Both tile members have small pores containing the carbonate electrolyte with the second tile member having an interior and including interconnecting larger pores extending into the interior. The larger pores are arranged for receiving oxygen gas and provide an oxidizing environment within the second tile. The second tile member has an ionic resistance per unit thickness greater than that of the first tile member.

208

Quorum quenching quandary: resistance to antivirulence compounds.  

Quorum sensing (QS) is the regulation of gene expression in response to the concentration of small signal molecules, and its inactivation has been suggested to have great potential to attenuate microbial virulence. It is assumed that unlike antimicrobials, inhibition of QS should cause less Darwinian selection pressure for bacterial resistance. Using the opportunistic pathogen Pseudomonas aeruginosa, we demonstrate here that bacterial resistance arises rapidly to the best-characterized compound that inhibits QS (brominated furanone C-30) due to mutations that increase the efflux of C-30. Critically, the C-30-resistant mutant mexR was more pathogenic to Caenorhabditis elegans in the presence of C-30, and the same mutation arises in bacteria responsible for chronic cystic fibrosis infections. Therefore, bacteria may evolve resistance to many new pharmaceuticals thought impervious to resistance. PMID:21918575

209

Effects of urbanization on macroinvertebrates in tributaries of the St. Johns River, Florida, USA  

The effects of urbanization on hydrology, water quality and macroinvertebrates were examined in 7 headwater tributaries of the St. Johns River in the Atlantic Coastal Plain of northeast Florida. All streams had sandy substrata and drained small catchments (24?231 ha) that ranged from 0 to 51% total impervious area (TIA). Streams unaffected by urbanization had intermittent stream flow and completely dry channels for several weeks in autumn and spring. Urbanized streams always possessed channel water, but 2 streams ceased flowing and became stagnant in autumn and spring. Principle components analysis of chemical and physical measures (i.e. conductivity, nutrients, pH, metals, and stream flow) produced one axis (PCA1) that explained 54% of the total variation among the streams. The variables ...

210

Characteristics of washed-off pollutants and dynamic EMCs in parking lots and bridges during a storm  

Given the importance of water quality in drinking water sources, the Korean Ministry of Environment is designing and instigating the total maximum daily load (TMDL) program for major large rivers. For the successful implementation of this program, nonpoint pollutants resulting from various land uses should be controlled. Especially, paved areas such as parking lots and bridges are stormwater intensive land uses because of their high imperviousness and high pollutant mass emissions from vehicular activity. Vehicle emissions from these paved areas include various pollutants such as heavy metals, oil, grease and particulates. This research was conducted to investigate the magnitude and nature of the stormwater emissions with the goal of quantifying stormwater pollutant concentrations and mass...

211

Effect of pH on tooth discoloration from food colorant in vitro  

Objectives: The purpose of this study was to evaluate the effect of acidic, neutral and alkaline food colorant media (FCM) on tooth discoloration in vitro. Methods: Treatment (n=24) and control (n=24) sterile, hydrated human molars were prepared in individual, impervious holders and their color measured (pretest) using a non-contact spectroradiometer system. Specimens were randomly assigned to and immersed in one of the three buffer solutions (pH 2, pH 7 or pH 12). Red food color (Red 40) was added to the treatment buffer solutions at 0.025%. Immersed specimens were incubated for 4h at 37^oC. Color was also measured after immersion/incubation (posttest) and again after subsequent 2-min of polish using plain-pumice slurry with a slow-speed handpiece (post-polish). Differences in CIE a* (red...

212

Quantification of impervious surface in the Snohomish Water Resources Inventory Area of Western Washington from 1972?2006  

A 34?year time series (1972?2006) of Landsat imagery for a portion of Snohomish and King Counties, Washington (the Snohomish Water Resource Inventory Area (WRIA)) was analyzed to estimate the amount of land that was converted into impervious surface as a result of urban and residential development. Spectral unmixing was used to determine the fractional composition of vegetation, open, and shadow for each pixel. Unsupervised and supervised classification techniques were then used to derive preliminary land cover maps for each time period. Digital orthophotos were used to create agricultural, forest management, high elevation, and riparian masks. In conjunction with established Urban Growth Areas (UGAs), these masks were utilized for the application of spatial rules that identified imperviou...

213

Mapping impervious surfaces from superresolution enhanced CHRIS/Proba imagery using multiple endmember unmixing  

In this paper, the potential of superresolution (SR) image reconstruction methods for sub-pixel land-cover mapping in dense urban areas is studied. A multiple endmember approach (MESMA) is used for unmixing both original hyperspectral CHRIS/Proba and SR enhanced CHRIS/Proba data. Validation based on high resolution orthophotos (25cm) shows that land-cover fraction maps generated from SR-enhanced CHRIS/Proba data (9m) have a lower overall fractional error compared to the land-cover fractions produced from the original CHRIS data (18m), when validating both results at the 18m resolution. Validation of SR results at the 9m resolution produces an overall mean absolute error (OMAE) of 16.7% compared to an OMAE of 14.3% at the 18m resolution, with the original data, yet the impervious surface ma...

214

Industrial hygiene report: preliminary survey of wood-preservative treatment facility at Permapost Products Company, Hillsboro, Oregon  

A walk-through survey was conducted at Permapost Products Company, Hillsboro, Oregon in June, 1979. Area air monitoring for pentachlorophenol was conducted using a NIOSH method and a silica-gel tube technique. The facility treated prefabricated bridge structures, playground equipment, picnic tables, and other specialty items with pentachlorophenol or chromated copper arsenate. The facility had no formal medical-monitoring program. Audiometric testing was performed annually on a contract basis. The company utilized the local hospital emergency room, located 5 minutes away. Work practices, processing methods, and protective equipment such as cartridge half-face respirators, elbow length gloves, and impervious aprons were used to control exposures to the wood preservatives. The authors note that since they took only a small number of samples, a meaningful comparison of the two analytical methods cannot be made.

215

Method and etchant to join ag-clad BSSCO superconducting tape  

A method of removing a silver cladding from high temperature superconducting material clad in silver (HTS) is disclosed. The silver clad HTS is contacted with an aqueous solution of HNO.sub.3 followed by an aqueous solution of NH.sub.4 OH and H.sub.2 O.sub.2 for a time sufficient to remove the silver cladding from the superconducting material without adversely affecting the superconducting properties of the superconducting material. A portion of the silver cladding may be masked with a material chemically impervious to HNO.sub.3 and to a combination of NH.sub.4 OH and H.sub.2 O.sub.2 to preserve the Ag coating. A silver clad superconductor is disclosed, made in accordance with the method discussed.

216

Arrangement in boom structure. Anordning ved lensekonstruksjon  

A boom structure comprises a skirt of impervious fabric, elongated floating means in the form of pipes, and spacers which are attached to the floating means and to the upper and lower edges of the skirt for keeping the skirt extended. The floating means are constituted by two adjacent plastic pipes held together by lashings. The spacers are constituted by short pieces of pipe, also of plastic material, with the axial direction transversely of the longitudinal direction of the boom. The spacers are attached to the floating means of the same lashings, which may be constituted by belts provided with buckles. The supporting structure of the boom consisting of the lashed pipes and pieces of pipe give the boom good sideways stability and also sufficient flexibility in the vertical plane.

217

Saltless solar pond  

A solar pond adapted for efficiently trapping and storing radiant solar energy without the use of a salt concentration gradient in the pond is disclosed. A body of water which may be fresh, saline, relatively clear or turbid, is substantially covered by a plurality of floating honeycomb panels. The honeycomb panels are made of a material such as glass which is pervious to short wave solar radiation but impervious to infrared radiation. Each honeycomb panel includes a multitude of honeycomb cells. The honeycomb panels are divided into the elongated honeycomb cells by a multitude of intermediate plates disposed between a bottom plate and top plate of the panel. The solar pond is well suited for providing hot water of approximately 85 to 90 C temperature for direct heating applications, and for electrical power generation.

218

Are Tutor Behaviors in Problem-Based Learning Stable? A Generalizability Study of Social Congruence, Expertise and Cognitive Congruence  

The purpose of this study was to investigate the stability of three distinct tutor behaviors (1) use of subject-matter expertise, (2) social congruence and (3) cognitive congruence, in a problem-based learning (PBL) environment. The data comprised the input from 16,047 different students to a survey of 762 tutors administered in three consecutive semesters. Over the three semesters each tutor taught two of the same course and one different course. A generalizability study was conducted to determine whether the tutor behaviors were generalizable across the three measurement occasions. The results indicate that three semesters are sufficient to make generalizations about all three tutor behaviors. In addition the results show that individual differences between tutors account for the greatest differences in levels of expertise, social congruence and cognitive congruence. The study concludes that tutor behaviors are fairly consistent in PBL and somewhat impervious to change. Implications of these findings for tutor training are discussed. (Contains 2 tables.)

219

Exploring the response of functional indicators of stream health to land-use gradients  

Summary 1. Broad-scale assessment of stream health is often based on correlative relationships between catchment land-use categories and measurements of stream biota or water chemistry. Few studies have attempted to characterise the response curves that describe how measures of ecosystem function change along gradients of catchment land use, or explored how these responses vary at broad spatial scales. 2. In autumn 2008, we conducted a survey of 84 streams in three bioregions of New Zealand to assess the sensitivity of functional indicators to three land-use gradients: percentage of native vegetation cover, percentage of impervious cover (IC) and predicted nitrogen (N) concentration. We examined these relationships using general linear models and boosted regression trees to explore monoton...

220

Runoff transport of pyrethroids from a residential lawn in central California.  

An irrigation runoff study on a residential lawn was conducted in California, northeast of Sacramento, during the summer and fall of 2008 to investigate the contribution of turf uses of pyrethroids to residues in Californian urban creek sediments. This study examined how over irrigation (i.e., irrigation that produces runoff) in the summer season may transport recently applied pyrethroids. The study included liquid and granular applications of both bifenthrin [(2-methyl-3-phenyl-phenyl) methyl 3-(2-chloro-3,3,3-trifluoro-prop-1-enyl)-2,2-dimethyl-cyclopropane-1-carboxylate] and beta-cyfluthrin [Cyano(4-fluoro-3-phenoxyphenyl)methyl 3-(2,2-dichloroethenyl)-2,2-dimethyl-cyclopropanecarboxylate]. Generally, runoff did not occur at irrigation rates of 2.03 cm/h (0.8 in/h) but did occur when the irrigation rates were increased to about 3.81 cm/h (1.5 in/h), generating chemical losses in the first runoff event of up to 0.58 and 0.08% of applied for beta-cyfluthrin and bifenthrin, respectively. Chemical runoff losses dropped significantly between over-irrigation events with the third over-irrigation event chemical runoff losses representing 0.026 and 0.015% of applied for beta-cyfluthrin and bifenthrin, respectively. Runoff losses were generally less for liquid formulations than granular formulations but within a factor of three. Additionally, the study included a simulated winter rainstorm 8 wk after application. The low runoff losses from turf seen in this study suggest that other sources could be contributing to observed residues in urban streams. Other sources could include pyrethroids ending up on impervious surfaces, such as concrete driveways from off-target applications to turf, spills, and other poor handling practices, or pyrechroids applied directly to impervious surfaces for insect control. PMID:21520766

 
 
 
 
221

Langbjorn dam : adaptation for safe discharge of extreme floods  

The Langbjorn hydropower scheme, composed of an embankment dam with an impervious core of compacted moraine, a spillway section and a powerhouse, is located on the Angermanalven River in north Sweden. The scheme was commissioned in 1959 and is owned by Vattenfall. As part of its dam safety program, Vattenfall plans to adapt and refurbish many of its dams to the updated design-flood and dam-safety guidelines. Langbjorn is classified as a high hazard dam, as its updated design flood is 30 per cent higher than the existing spillway capacity. Safety evaluations were conducted for the Langbjorn dam, and, as required by the higher safety standard, there was a need to rebuild the dam, so that the design flood could be safely released without causing failure of the dam. This paper provided information on the Langbjorn hydropower scheme and discussed the planned rebuilding measures. For example, the design flood was accommodated by allowing a temporary raise of the water level by 1.3 metres above the legal retention reservoir level, which required heightening and reinforcement of the dam. Specifically, the paper discussed measures to increase the discharge capacity; handling and control of floating debris; improvement and heightening of impervious core in left and right connecting dam and abutment; measures to increase the stability of the left steep riverbank; and measures to increase stability of the spillway monoliths and the left guide wall. In addition, the paper discussed measures to ensure stability of the downstream stretch of the river bank and increase instrumentation. The paper also presented the results of hydraulic investigations to investigate the risk of erosion downstream of the dam. It was concluded that the dam could discharge the design flood and that the stability of the dam was improved and judged to be satisfactory during all foreseeable conditions. 2 refs., 8 figs.

222

Minneapolis earns stars and scars by charging for hardscape  

The City of Minneapolis, Minnesota has set a goal to have the stormwater utility be revenue-neutral, with higher stormwater fees offset by lower sanitary sewer charges. A credit system was designed to promote the adoption of onsite best management practices, even on residential and other small sites. This paper examined the city council's policy considerations that drove the impervious-surface-based stormwater utility fee ordinance, the legal and institutional barriers that had to be overcome, and the successes and failures of the effort. The policy objective was to have an equitable stormwater fee credit system, whereby property owners paid for stormwater management in proportion to the demand their properties placed on the system. As such, property owners were encouraged to manage stormwater onsite. The first objective was achieved when in March 2005 the City of Minneapolis began charging property owners for management of stormwater based on the degree to which their property was covered by impervious surfaces. Previously, property owners had paid a combined stormwater and sewerage fee based on water usage. The city also launched a program allowing property owners to apply for fee reductions of up to 100 percent when establishing onsite water-quality or water-quantity treatment systems, such as rain gardens, detention ponds and green roofs. The charges for the properties were based on the size of the property and the land use. It was determined that the city's policy could not accommodate all of the economic issues in green roof development. This paper demonstrated that it is not yet clear that the fee and performance-based fee reduction program has been a significant contributor to the growth of green building in the area. 7 refs., 1 tab.

223

Nuclear fuel rod containing a hybrid gadolinium oxide, boron carbide burnable absorber  

A nuclear reactor fuel rod assembly having a fuel rod containing a hybrid burnable absorber-containing nuclear fuel, the fuel rod having a predetermined absorption capability, the fuel assembly comprising: a nuclear fuel pellet containing a fissionable material and a hybrid absorber material, the hybrid absorber material comprising gadolinium oxide, and coated boron carbide particles, the carbon carbide particles being of a particle size of between 20 to 100 microns in diameter and each coated by 0.5 to 10 micron coating of a helium gas-impervious material, the total weight percent of hybrid absorber material in the fuel pellet being less for a fuel rod having the predetermined absorption capability of the fuel rod assembly than the total weight percent of gadolinium oxide required when used without boron carbide and of the total weight percent of boron carbide required when used without gadolinium oxide. A nuclear reactor fuel composition, containing an hybrid burnable absorber, for use in fuel rod assemblies of a nuclear reactor, consisting essentially of a fissionable material, gadolinium oxide in an amount of between 1 to 20 percent by weight of the composition, and 0.02 to 1.0 percent by weight of boron carbide particles, the boron carbide particles being of a particle size of between 20 to 100 microns in diameter and each coated by a 0.5 to 10 micron coating of a helium gas-impervious material, the addition of boron carbide particles as well as gadolinium oxide absorber material to the fissionable material resulting in a fuel composition having less weight percent of absorber material than a fuel composition having the same absorption capabilities but having only gadolinium oxide or only boron carbide absorber material.

224

BIOLOGICAL FINGERPRINTING OF SOIL FOR SOURCE IDENTIFICATION  

The biological portion of soil can be used to differentiate displaced soils. Fatty acid analyses of soils yield characteristic "fingerprints" that are unique to a given soil at a given time. We found that molecular techniques for fingerprinting the soil successfully identified different soils and ...

225

Estimation of Soil Degradation Rate Constants from Vertical Distribution of Soil Carbon Content  

A simple model interpreting vertical distribution of soil carbon was constructed and annual degradation rate constants of soil carbon for various forest soils were estimated. The model is based on the material balance at the soil surface, and assumes that the relationship between soil depth and soil carbon is linear. The estimated soil degradation rates were of the similar order of magnitude, and we concluded that this model might be used for rough estimation of soil carbon degradation rates of forest soils where vertical distributions of soil carbon are available.   

226

Sensitivity of screening-level toxicity tests using soils from a former petroleum refinery  

The authors tested five composite soil samples from a former refinery. The samples included a reference soil (Mineral Oil and Grease, MO and G < 40 ppm), thermally-treated soil, biotreated soil, and two untreated soils. They evaluated toxicity using the earthworm E. foetida, lettuce, cress, barley, Microtox, green algae, fathead minnow, and D. magna. The endpoints measured were lethality, seed germination, root elongation, growth, and bioluminescence. Toxicity, as measured by the number of positive responses, increased as follows: biotreated soil < untreated soil No. 1 < reference soil < thermally-treated soil and untreated soil No. 2. The biotreated soil generated only one positive response, whereas the thermally-treated soil and untreated soil No. 2 generated five positive responses. The most sensitive and discriminant terrestrial endpoint was lettuce root elongation which responded to untreated soil No. 1, thermally-treated soil, and reference soil. The least sensitive was barley seed germination for which no toxicity was detected. The most sensitive and discriminant aquatic endpoint was green algae growth which responded to untreated soil No. 1, thermally-treated soil, and reference soil. The least sensitive was D. magna for which no toxicity was detected. Overall, soil and aqueous extract toxicity was spotty and no consistent patterns emerged to differentiate the five soils. Biotreatment significantly reduced the effects of the contamination. Aqueous toxicity was measured in the reference soil, probably because of the presence of unknown dissolved compounds in the aqueous extract. Finally, clear differences in sensitivity existed among the test species.

227

Review of current study on plant uptake of metal for application on environmental fate model for metals and a case study on an estimation of cadmium uptake in rice  

The author critically reviewed existing researches on soil-plant transfer coefficients or soil-plant relation equations for environmental fate model that estimating transferring metals and metalloids. Although soil-plant relation equations were available for some crops, the equations on staple foods for Japanese were not existed. Soil factors affecting phytoavailability were critically reviewed. Metal concentration in soil, pH in soil, organic carbon contents in soil, and cation exchange capacities (CECs) in soil were often used for dependant variables of soil-plant relation equations, however, another factors should play an important role for explaining variance. Finally, as for a case study, the factors that affect soil-rice transfer of cadmium (Cd) were analyzed. Results showed that a difference of water management condition in a paddy field was a critical factor. The soil-plant relation equation including water management condition successfully estimated Cd concentration in rice from Cd concentration in soil, pH in soil and CECs in soil.   

228

Fate and transport of chromium through soil; Destino e trasporto del cromo attraverso il suolo  

Chromium chemistry relevant to the problem facing state of New Jersey (Usa) was examined. Transport of chromium through soil depends on its chemical forms. Transformation of chromium within bulk of soil depends on soil constituents, soil condition, such as pH, Eh and organic compounds applied onto soil or present in soil. Total chromium in soil can be determined. Speciation of chromium based on ionization, hydrolysis, complex formation, redox reactions and adsorption is predicted using MINIQ program.

229

Evaluation of soil structure in the framework of an overall soil quality rating  

Soil structure is an important aspect of agricultural soil quality, and its preservation and improvement are key to sustaining soil functions. Methods of overall soil quality assessment which include visual soil structure information can be useful tools for monitoring and managing the global soil resource. The aim of the paper is: (i) to demonstrate the role of visual quantification of soil structure within the procedure of the overall soil quality assessment by the Muencheberg Soil Quality Rating (M-SQR), (ii) to quantify the magnitude and variability of soil structure and overall M-SQR on a number of agricultural research sites and (iii) to analyse the correlations of soil quality rating results with crop yields. We analysed visual soil structure and overall soil quality on a range of 20 experimental sites in seven countries. To assess visual soil structure we utilised the Visual Soil Assessment (VSA) and Visual Evaluation of Soil Structure (VESS) methods. Results showed the feasibility and reliability of both VSA and VESS methods and the overall soil quality M-SQR rating approach to give scores and classes which characterised the soil potential for cropping. The structure status of soil can be reliably assessed by these procedures. In soils with clay contents > 30% unfavourable soil structure could not be reliably recognised by measurements of the dry bulk density, but significantly by evaluation of visual soil structure. Structure scores were clearly associated with the drainage status of soil. More than 70% of the variability of crop yields at a given intensity of input may be explained by the overall M-SQR-score which includes information on soil texture, relief and climate in addition to soil structure. We conclude that methods of visual soil assessment are useful diagnostic tools for monitoring and controlling agricultural soil quality over different scales, ranging from within-fields to global. Controlling the drainage status of land and action of machinery at appropriate drainage states are pre-conditions for preserving a suitable soil structure.

230

Equal-area spline functions applied to a legacy soil database to create weighted-means maps of soil organic carbon at a continental scale  

There is a growing need for raster-based soil data to support modelling at regional and continental scales. The GlobalSoilMap consortium aims to satisfy this need with the production of a suite of digital soil maps of various soil properties at six standard depths for most of the land surface of the Earth. Initially, the maps will be produced using legacy soil data (soil data already available). In the United States, the State Soil Geographic (STATSGO2) database is a rich source of legacy soil information, but the STATSGO2 map is vector-based and soil components' soil property data is organised by horizon. We therefore applied the equal-area spline function to the soil components of STATSGO2 map units in order to obtain estimates of soil organic carbon (SOC) content at the GlobalSoilMap st...

231

Preparation of Artificially Spiked Soil with Polycyclic Aromatic Hydrocarbons for Soil Pollution Analysis  

To confirm the method for preparing artificially spiked soil with polycyclic aromatic hydrocarbons (PAHs), we tested the homogeneity of PAHs in spiked soils, which were prepared by three different procedures, by using kaolin and ando soil. When the slurry of kaolin and acetone containing PAHs were evaporated by a rotary evaporator at 30 - 35°C, the most homogeneous distribution of PAHs was obtained in the spiked soil. This procedure was applied to the preparation of PAH-spiked soil for natural soil (ando soil). Such spiked soils can be useful as the standard materials for standardization of the analytical methods for PAHs in the soil and sediment samples.   

232

The effect of model soil contamination with Cr, Cu, Ni, and Pb on the biological properties of soils in the dry steppe and semidesert regions of southern Russia  

Model soil contamination with Cr, Cu, Ni, and Pb in the dry steppes and semideserts of southern Russia has worsened the biological soil properties. With respect to the degree of deterioration of the biological properties, the soils can be arranged in the following sequence: dark chestnut soils > chestnut soils > light chestnut soils > brown semidesert soils > sandy brown semidesert soils. The sequence of metal oxides according to the adverse effect on the biological soil properties is as follows: CrO3 > CuO ? PbO ? NiO.

233

The effect of model soil contamination with Cr, Cu, Ni, and Pb on the biological properties of soils in the dry steppe and semidesert regions of southern Russia  

Model soil contamination with Cr, Cu, Ni, and Pb in the dry steppes and semideserts of southern Russia has worsened the biological soil properties. With respect to the degree of deterioration of the biological properties, the soils can be arranged in the following sequence: dark chestnut soils > chestnut soils > light chestnut soils > brown semidesert soils > sandy brown semidesert soils. The sequence of metal oxides according to the adverse effect on the biological soil properties is as follows: CrO3 > CuO ? PbO ? NiO.

234

Phenanthrene removal from soil slurries with surfactant-treated oxides  

A soil-slurry washing technique to decontaminate soils containing low-solubility nonionic organic pollutants was investigated, using phenanthrene as a model pollutant. The technique is based on first transferring the sorbed phenanthrene from the soil to anionic surfactant-coated oxide particles, and then separating these anionic surfactant-coated oxide particles with the sorbed phenanthrene from the soil slurry via a magnetic separation technique. The decontamination of two soils with different particle sizes and soil organic matter content was investigated. The proposed soil-slurry washing technique was effective in removing a strongly sorbing nonionic organic contaminant from soil slurries. Various operational scenarios of multistage soil-slurry reactors were evaluated with a mathematical model.

235

Carbon turnover in aggregated soils determined by natural 13C abundance  

Soil organic matter influences all soil functions and is a crucial factor in the global carbon cycle. The stabilization mechanisms of organic matter in soils are poorly understood. The objective of this study was to quantify soil carbon dynamics in soils from long-term monocultures with a change fro...

236

In Vitro And In Vivo Approaches For The Measurement Of Oral Bioavailability Of Lead (Pb) In Contaminated Soils: A Review  

We reviewed the published evidence of lead (Pb) contamination of urban soils, soil Pb risk to children through hand-to-mouth activity, reduction of soil Pb bioavailability due to soil amendments, and methods to assess bioaccessibility which correlate with bioavailability of soil ...

237

Soil total carbon content, aggregation, bulk density, and penetration resistance of croplands and nearby grasslands  

Converting native grassland (NGL) to cropland (CL) decreases soil organic matter contents (components of soil total carbon contents, STCCs), which often leads to soil degradation. Reestablishing grass on CL generally increases soil organic matter, which improves soil conditions. This study was condu...

238

Relationships between soil buffer capacity and selected soil properties in a resource-poor farming area in the Mpumalanga Province of South Africa  

In this study, the soil buffer capacity (soil BC) was measured for 80 topsoil samples of the most dominant soil forms in a small-scale farming area. Soils used in the study ranged from weakly to strongly buffered, with soil BC values ranging from 0.12 to 2.23 cmol (+) kg-1 pH unit-1. Relationships o...

239

Soil macroaggregate dynamics in a mountain spatial climate gradient  

We investigated the response of soil macroaggregate dynamics to soil temperature modification along a spatial gradient located on a forested north-facing slope in the southern French Alps, simulating long-term adjustment of soil-plant interactions to absence or occurrence of soil frost. Soil macroag...

240

European Journal of Soil Biology ?????????  

The European Journal of Soil Biology covers all aspects of fundamental and applied soil biology relating to soil microbial and faunal ecology, and processes promoted by soil organisms. Soils from managed and natural ecosystems of biomes worldwide are of interest, and the Journal is open to su...

 
 
 
 
241

Applied Soil Ecology ???????  

Applied Soil Ecology addresses the role of soil organisms and their interactions in relation to: agricultural productivity, nutrient cycling and other soil processes, the maintenance of soil structure and fertility, the impact of human activities and xenobiotics on soil ecosystems and bio(tec...

242

SOIL TEXTURE AND PARTICLE DISTRIBUTION AS INPUT TO THE ESTIMATION OF SOIL HYDRAULIC PROPERTIES  

Soil texture represents the relative proportion of soil particles with different sizes, which is a fundamental physical property of soils, correlated to just any other soil property. Soil hydraulic properties are difficult to determine, especially for large areas of land. Predictive models to estima...

243

In Field Monitoring of Potential Detrimental Effects of Biofuels Production on Soil Quality  

Soil organic carbon (SOC) content is recognized as a soil quality indicator that is susceptible to degradation with tillage and with biomass removal from the soil surface. In addition to reported benefits of leaving crop residue on the soil surface in preventing soil erosion, providing plant nutrien...

244

In Situ Stabilization of Trace Metals in a Copper-Contaminated Soil using P-Spiked Linz-Donawitz Slag  

P-spiked Linz-Donawitz (LD) slag was used as a soil additive to improve physico-chemical soil properties and in situ stabilize Cu and other trace metals in a sandy Cu-contaminated soil (630 mg kg-1 soil) from a former wood preservation site. The LD slag was incorporated into the contaminated soil to...

245

The peatlands of Ireland  

This publication was prepared to accompany the peatland map of Ireland (which is included). It discusses peat formation, classification of peat soils, peat soils of Ireland and land use of Irish peat soils. Profile descriptions and analyses of raised and blanket bog soils, and man-modified peat soils are included in appendices. A glossary of terms is also included. (43 refs.)

246

Finite element analysis of cone penetration in soil for prediction of hardpan location  

An accurate soil hardpan determination is important for maximum precision tillage performance. Soil cone penetrometer data are often analyzed to predict soil hardpan depths. The prediction in layered soils may be limited due to the complexity of soil reaction to cone penetration. An axisymmetric fin...

247

SOIL REDOX AND PH EFFECTS ON METHANE PRODUCTION IN A FLOODED RICE SOIL  

Methane formation in soil is a microbiological process controlled by many factors. f them soil redox potential (Eh) and soil pH are considered as critical controls. aboratory incubation experiment was conducted to study the critical initiation soil Eh, the optimum soil pH and the...

248

In-situ vitrification of soil  

A method of vitrifying soil at or below a soil surface location. Two or more conductive electrodes are inserted into the soil for heating of the soil mass between them to a temperature above its melting temperature. Materials in the soil, such as buried waste, can thereby be effectively immobilized.

249

Soil Science & Plant Nutrition ?????????  

Soil Science & Plant Nutrition is the official English journal of the Japanese Society of Soil Science and Plant Nutrition (JSSSPN), and publishes original research and reviews in soil physics, chemistry and mineralogy; soil biology; plant nutrition; soil genesis; classification and survey; s...

250

Aggregation and Aggregate Carbon in a Forested Southeastern Coastal Plain Spodosol  

Soil aggregation is influenced by the soil environment and is a factor in soil carbon sequestration. Sandy Coastal Plain soils often do not have the clay to promote aggregation nor have been considered soils with high levels of aggregation. This study was conducted to examine the aggregate morpholog...

251

S on the Study (BOREAS) 248 ,S TGB-12 Soil Carbon and Flux ...  

of soil carbon stocks by horizon based on soil survey data and analyses of data from individual soil profiles; .... Scientist, The Woods Hole Research. Center ... of Carbon in Boreal Forest Soils: Integrating. 14C ... In addition to field techniques, ...... organic ash present. Quantities of woody fragments present. (organic soils) ii.

252

BIOGENESIS SOIL WASHING TECHNOLOGY - INNOVATIVE TECHNOLOGY EVALUATION REPORT  

Soil washing technologies are designed to transfer contaminants from soil to a liquid phase. he BioGenesis Soil Washing Technology uses soil washing with a proprietary surfactant solution to transfer organic contaminants from soils to wastewater. ontaminant levels are further red...

253

SITE TECHNOLOGY CAPSULE: BIOGENESIS SOIL WASHING TECHNOLOGY  

Soil washing technologies are designed to transfer contaminants from soil to a liquid phase. The BloGenesis? soil washing technology uses a proprietary surfactant solution to transfer organic contaminants from soil to wastewater. The surfactant used in the soil washing process wa...

254

Adaptation of ammonia-oxidizing microorganisms to environment shift of paddy field soil.  

Adaptation of microorganisms to the environment is a central theme in microbial ecology. The objective of this study was to investigate the response of ammonia-oxidizing bacteria (AOB) and ammonia-oxidizing archaea (AOA) to a soil medium shift. We employed two rice field soils collected from Beijing and Hangzhou, China. These soils contained distinct AOB communities dominated by Nitrosomonas in Beijing rice soil and Nitrosospira in Hangzhou rice soil. Three mixtures were generated by mixing equal quantities of Beijing soil and Hangzhou soil (BH), Beijing soil with sterilized Hangzhou soil (BSH), and Hangzhou soil with sterilized Beijing soil (HSB). Pure and mixed soils were permanently flooded, and the surface-layer soil where ammonia oxidation occurred was collected to determine the response of AOB and AOA to the soil medium shift. AOB populations increased during the incubation, and the rates were initially faster in Beijing soil than in Hangzhou soil. Nitrosospira (cluster 3a) and Nitrosomonas (communis cluster) increased with time in correspondence with ammonia oxidation in the Hangzhou and Beijing soils, respectively. The 'BH' mixture exhibited a shift from Nitrosomonas at day 0 to Nitrosospira at days 21 and 60 when ammonia oxidation became most active. In 'HSB' and 'BSH' mixtures, Nitrosospira showed greater stimulation than Nitrosomonas, both with and without N amendment. These results suggest that Nitrosospira spp. were better adapted to soil environment shifts than Nitrosomonas. Analysis of the AOA community revealed that the composition of AOA community was not responsive to the soil environment shifts or to nitrogen amendment. PMID:22145990

255

Studies on Soil-Cement Stabilization.  

Soil-cement stabilization has been attempted on a large number of soil samples. An arbitrary criterion for minimum strength requirements has been assigned. Those soils that could not be stabilized and those requiring additional confirmatory tests have bee...

256

Genesis and development of the pedosphere during the geohistory and its preservation functions towards the biological environment. Chishi ni okeru dojoken no hassei, hatten to, sono seibutsu kankyo hozen kino ni tsuite  

This paper explains the genesis, classification and geography of soil mainly in relation to life. In soil science, the basic field of dealing with the component, classification and distribution of soil is called pedology or soil geography. The fist chapter describes the definition of soil and the process of its genesis. The next chapter deals with the characteristics, genetic causes and distribution of typical soil at present in Japan and in the world. The ways of classifying soil are divided roughly into 2 schools and 17 kinds of typical soil types are explained. The heading of the third Chapter is the genesis and development of soil in geohistory and 3 theories are explained. Soil can not be produced without life. Therefore soil does not exist on the planets other than the earth. The last chapter describes the preservation functions towards the earth environment and the countermeasures of maintenance in connection with soil systems. 42 refs., 8 figs., 5 tabs.

257

Methods to Estimate the Protection of Soil Organic Carbon within Macroaggregates, 1: Does Soil Water Status Affect the Estimated Amount of Soil Organic Carbon Protected inside Macroaggregates?  

The additional mineralized soil organic carbon (SOC) after soil crushing is considered to be the amount of SOC protected within aggregates (>200 ?m). This study investigated the effect of soil moisture in crushed and uncrushed soil samples on the calculated amounts of protected SOC in five tropical soils (Arenosol, two Ferralsols, Nitisol, and Vertisol). No differences in soil moisture optimum were observed between crushed and uncrushed soil samples, except in clayey soils with high SOC contents and high SOC mineralization rates (Nitisol and Vertisol). Crushing the soil increased soil respiration by 0.9 to 2.4 times. Soil moisture seemed to be a confounding factor in estimation of the SOC-protected amount only in soil with a high amount of protected SOC or with a low macroaggreg...

258

77 FR 29619 - Notice of Intent to Grant Partially Exclusive License of the United States Patent No. 7,824,569...  

...of the biopolymer salt formulation related to soil stabilization and dust control. DATES: Written...of synthetic, petroleum-based polymers for soil amendment applications to achieve increased soil strength, reduced air transport, and...

259

77 FR 31340 - Notice of Intent To Grant Partially Exclusive License of the United States Patent No. 7,824,569...  

...use of the biopolymer product as a natural soil amendment and seed coating that promotes more efficient...synthetic, petroleum-based polymers for soil amendment applications to achieve increased soil strength, reduced air transport, and...

260

76 FR 29238 - Methyl Bromide; Cancellation Order for Registration Amendments To Terminate Certain Soil Uses  

...for Registration Amendments To Terminate Certain Soil Uses AGENCY: Environmental...EPA's order for the amendments to terminate soil uses, voluntarily...effective date of the amendment of methyl bromide products that include soil uses other...

 
 
 
 
261

Relating soil biochemistry to sustainable crop production  

Amino acids, amino sugars, carbohydrates, phenols, and fatty acids together comprise appreciable proportions of soil organic matter (SOM). Their cycling contribute to soil processes, including nitrogen availability, carbon sequestration and aggregation. For example, soil accumulation of phenols has ...

262

Unsaturated Soil Hydraulic Parameter Studies.  

Different field and laboratory methods for determining the hydraulic properties of unsaturated soils were studied. Drying moisture retention curves were measured on undisturbed soil samples with a pressure plate apparatus, and wetting soil moisture retent...

263

UNSODA: UNSATURATED SOIL HYDRAULIC PROPERTY DATABASE  

Initially released in 1996, the UNSODA database contains unsaturated soil hydraulic properties (water retention, hydraulic conductivity, soil water diffusivity) and auxiliary data (particle-size distribution, bulk density, organic matter content, etc.) for more than 800 soils. With the recent launc...

264

77 FR 21870 - National Oil and Hazardous Substances Pollution Contingency Plan; National Priorities List...  

...facility were excavated into the unsaturated portion of the alluvial aquifer...contaminating the surrounding soil and water drainage pathway...Site in which contaminated soils, sediments, tank, and buildings...and disposal of contaminated soils and sediments, removal...

265

Estimating saturated hydraulic conductivity of soil containing rock fragments with disc infiltrometer ?????????????????????  

[????]?Simulation experiment was conducteds in soil columns and the effects of rock fragments on soil saturated hydraulic conductivity by disc infiltrometer were analyzed. Results indicate that saturated hydraulic conductivity of soil containing rock fragments can be calculated through nonlin...

266

Investigations on Distribution of Copper in Soil, Vegetation and Soil Fauna of a Vineyard Ecosystem.  

Investigations were carried through to test the effects of different copper contents in soils on soil fauna. The experiments were carried out in vineyards. Soil copper contents were correlated with the contents in invertebrates as earthworms, spiders, bee...

267

A Global Data Set of Soil Particle Size Properties  

textures (particle size distributions) has been compiled from the. FAO/UNESCO Soil Map ... of surface characteristics that influence water movement in the soil profile. ..... homogeneous information at a much lower resolution. Variability in soil ...

268

75 FR 26287 - Notice of Permit Applications Received Under the Antarctic Conservation Act of 1978 (Pub. L. 95-541)  

...wet soils, and soils and sediment associated with mosses, lichens and algal mats. The applicant will extract nematodes, tardigrades and rotifers from these soils for identification and classification. The collection of these samples will help to...

269

76 FR 75558 - Environmental Impact Statement for Restoration of the Mariposa Grove of Giant Sequoias, Yosemite...  

...typically supplied by melting snow; soil and air moisture; temperature...water. Giant sequoias have expansive but shallow root systems that...canopy openings and releasing soil nutrients needed for seedling...vehicle traffic have compacted soils and exposed shallow...

270

Sanborn Field, Long Term Crop / Soil Organic Matter Experiment  

CO2 concentration in soil air also measured: disposable chromatographic tubes ( Buyanovsky .... decomposition of corn, wheat, and soybean residue. Soil Sci. ... Crop residue input to SOM on ... Significance of microbial tissue to soil organic ...

271

Environmental fate of two sulfonamide antimicrobial agents in soil  

Veterinary antimicrobials have been detected in a number of environmental samples, including agricultural soils. In this study, the persistence and sorption of the sulfonamide sulfamethazine (SMZ) and sulfachloropyridine (SCP) in soil and their potential effects on soil microorganisms were investiga...

272

Mineralogical and Chemical Characterization of Lunar Highland ...  

Aug 9, 2009 ... In a logical continuation of our soil characterization studies for mare soils, we .... Ferromagnetic Resonance (FMR) measurements performed in the .... soils in proportions correlated to the type of basalt, the agglutinitic glass ...

273

Fate and bioavailability of (14)C-pyrene and (14)C-lindane in sterile natural and artificial soils and the influence of aging.  

Soil organic matter is used to extrapolate the toxicity and bioavailability of organic pollutants between different soils. However, it has been shown that other factors such as microbial activity are crucial. The aim of this study was to investigate if sterilization can reduce differences in the fate and bioavailability of organic pollutants between different soils. Three natural soils with increasing total organic carbon (TOC) content were collected and three artificial soils were prepared to obtain similar TOCs. Soils were sterilized and spiked with (14)C-pyrene and (14)C-lindane. Total (14)C radioactivity, HPCD extractability, and bioaccumulation in Eisenia fetida were measured over 56 days. When compared to non-sterile soils, differences between the natural and artificial soils and the influence of soil-contaminant contact time were generally reduced in the sterile soils (especially with middle TOC). The results indicate the possibility of using sterile soils as "the worst case scenario" in soil ecotoxicity studies. PMID:22892571

274

77 FR 23007 - Endangered and Threatened Wildlife and Plants; Designation of Revised Critical Habitat for Allium...  

...CNDDB 2011a). Mineral-rich clay soils within grassland...and contains the mineral-rich clay soils, subsurface geology...this subunit include thatch build-up from herbaceous plants...substrate components and mineral-rich soils, conditions...

275

CATALYTIC POTENTIAL OF SOIL HYDROLASES IN NORTHEAST CHINA UNDER DIFFERENT SOIL MOISTURE CONDITIONS  

Abstract in english An incubation test with black soil (Phaeozem), Albic soil (Albic Luvisols), brown soil (Cambisols), and cinnamon soil (Chromic Luvisol) from Northeast China was conducted under the conditions of 10%, 20% and30 % field capacity, and the kinetic parameters of soil urease, phosphatase, and arylsulphatase were determined, aimed to study the changes in the catalytic potential of these enzymes under different soil moisture conditions. All test enzymes exhibited typical Michaeli (more) s-Menten kinetic behaviors. The test enzymes exhibited the highest enzyme-substrate affinity (l/Km) at 20% or 30% field capacity. With increasing soil moisture content, the Fmax of test soil urease decreased, while that of soil phosphatase and arylsulphatase increased, with the maximum Vmax/Km of urease at 20% field capacity and that of phosphatases and arylsulphatase at 30% field capacity. To control soil moisture condition could be a feasible way in regulating the biochemical transformation processes of soil nutrients catalyzed by soil hydrolases.

276

GRACE BIOREMEDIATION TECHNOLOGIES - DARAMEND¿ BIOREMEDIATION TECHNOLOGY. INNOVATIVE TECHNOLOGY EVALUATION REPORT  

Grace Dearborn's DARAMEND™ Bioremediation Technology was developed to treat soils/sediment contaminated with organic contaminants using solid-phase organic amendments. The amendments increase the soil’s ability to supply biologically available water/nutrients to micro...

277

75 FR 54116 - Notice of Intent To Grant Partially Exclusive License of the United States Patent Application No...  

...applications in the fields of soil and slope stabilization, enhanced bioremediation, dust and run-off control, fly ash removal, emissions particulate removal, metal and inorganic chelation in soils and water, soil erosion, road stabilizer, and dust...

278

Zinc Fertilization of Flooded Rice. Summary of the Results of the Five-Year FAO/IAEA CO-Ordinated Research Programme on Isotope-Aided Micronutrient Studies in Rice Production with Special Reference to Zinc Deficiency Carried out During the Years 1974 to 1979.  

Local scientists studied Zn fertilization of flooded rice soils in Bangladesh, India, Indonesia, the Republic of Korea, Egypt, the Philippines, Thailand and Turkey. Diagnosis of Zn deficiency was carried out for submerged rice soils. Soil maps were prepar...

279

Soil quality in a pecan – Kura clover alley cropping system in the midwestern USA  

Intercropping alleys in agroforestry provides an income source until the tree crop produces harvestable yields. However, cultivation of annual crops decreases soil organic matter and increases soil erosion potential, especially on sloping landscapes. Perennial crops maintain a continuous soil cover,...

280

Laboratory studies of CCA-C leaching : influence of wood and soil ...  

Oct 4, 2012 ... Unfortunately, migration of a soil component (likely iron) into the stakelets ... one of the five soils interfered with Cr determination by X-ray fluorescence; ... A negative correlation was observed between Soil Cu Content and the ...

 
 
 
 
281

DIGISOIL: An Integrated System of Data Collection Technologies for Mapping Soil Properties  

The multidisciplinary DIGISOIL consortium intends to integrate and improve in situ proximal measurement technologies for assessing soil properties and soil degradation indicators, moving from the sensing technologies themselves to their integration and application in (digital) soil mapping (DSM). Th...

282

Soil Science Education - Soil Quality Student Project  

Soil filters water, decomposes waste, stores heat, and exchanges gases. ... It is a material used for construction, medicine, and art. .... PG County Soil Survey Report; liter-sized plastic bags for each site and marker; newspaper for drying soil on ...

283

Characterization, desorption, and mining of phosphorus in noncalcareous sandy soils  

In areas with intensive livestock farming, soils have been enriched with phosphorus (P), following heavy applications of animal manure.These soils are a risk for nearby surface waters, as the leaching of P from these soils contributes to eutrop...

284

76 FR 49324 - National Oil and Hazardous Substances Pollution Contingency Plan; National Priorities List...  

...removing 24 inches of soil, back-filling the excavation with clean soil and reseeding. A thorough...enhancement of wildlife indigenous to the Oquirrh Range...and removal of top soil and other materials...residential dwellings in the community of Pine Canyon,...

285

Simulation model for unsaturated submarine soil  

An approach is proposed to investigate the mechanical characteristics of unsaturated soil offshore as well as onshore. The change of phases of pore water in the unsaturated soil is discussed. The numerical method for heat transfer in soil is proposed to investigate the mechanical behavior of unsaturated submarine soil. The model for voids and its numerical experiment are also presented to investigate the suction and permeability behaviors of unsaturated soil. Finally, the synthesis to model the mechanical behavior of unsaturated soil is discussed.

286

Forest Ecosystem Recovery in the Southeast U.S.: Soil Ecology as an Essential Component of Ecosystem Management  

This study integrates land-use history, pine ecology, silviculture, soil ecology research and the implications for forest management into one discussion. Best management practices that foster soil recovery include less intensive stand utilization and reduced soil disturbance. Stem-only harvest and longer rotation permit a recovery of soil biodiversity and an accrual of detritus and soil organic matter. Windrowing and similar techniques have dramatic and lasting effects on soil development. No-tillage agriculture as a model for pine plantations is discussed.

287

Hanford Environmental Information System (HEIS). Volume 6, Soil subject area  

The purpose of the Soil subject area of the Hanford Environmental Information System (HEIS) is to manage the data acquired from soil samples, both geologic and surface, and sediment samples. Stored in the Soil subject area are data relevant to the soil samples, laboratory analytical results, and field measurements. The two major types of data make up the Soil subject area are data concerning the samples and data about the chemical and/or radiologic analyses of soil samples.

288

Agricultural Online Access (AGRICOLA) Database  

in electronic form began in 1970, but the database covers materials in ... AGRICULTURE > ANIMAL COMMODITIES > DAIRY PRODUCTS · Parameter Definition ... AGRICULTURE > SOILS > SOIL MECHANICS · Parameter Definition ...

289

Temporal and spatial variability and controls of soil respiration in a temperate steppe in northern China  

In this study, soil respiration and environmental variables were examined to explore the temporal and spatial variability and controls of soil respiration in eight plant communities along an east-west transect in a temperate steppe of Inner Mongolia, China. Our results show that there was substantial temporal (coefficient of variation (CV) = 58.6 ± 1.54%, n = 14) and spatial variability (CV = 32.6 ± 2.65%, n = 8) in soil respiration. Soil temperature and moisture were more important than plant growth in controlling the seasonal patterns of within-site soil respiration in all the eight steppe communities. Spatial differences in soil respiration rate could be mainly attributed to the differences in soil moisture and net primary productivity (NPP) among the study sites, whereas soil temperature played a minor role in regulating the spatial pattern of soil respiration. Significantly, positive site-to-site correlations were found between soil respiration and site soil traits such as soil C, N, and clay contents. In contrast, soil respiration was negatively correlated with soil bulk density and sand content. These findings indicate that the relative importance of abiotic and biotic factors in regulating soil respiration differs temporally from spatially. The conclusions drawn from the present study provide valuable information for developing future models of soil respiration driven by site climatic and soil variables, applicable for large-scale estimates of soil respiration in grassland ecosystems.

290

Responses of soil microbial and nematode communities to aluminum toxicity in vegetated oil-shale-waste lands  

Both soil nematodes and microorganisms have been shown to be sensitive bioindicators of soil recovery in metal-contaminated habitats; however, the underlying processes are poorly understood. We investigated the relationship among soil microbial community composition, nematode community structure and soil aluminum (Al) content in different vegetated aluminum-rich ecosystems. Our results demonstrated that there were greater soil bacterial, fungal and arbuscular mycorrhizal fungal biomass in Syzygium cumini plantation, greater abundance of soil nematodes in Acacia auriculiformis plantation, and greater abundance of soil predatory and herbivorous nematodes in Schima wallichii plantation. The concentration of water-soluble Al was normally greater in vegetated than non-vegetated soil. The residu...

291

Chemical contamination of adygea soils and changes in their biological properties  

Soil pollution with Cr, Cu, Ni, and Pb oxides and with oil products in the Adygea Republic leads to the deterioration of the soil biological properties. According to the degree of deterioration of the biological properties, the soils of Adygea may be arranged into the following sequence: brown forest soils > mountainous meadow (subalpine) soils > gray forest soils > soddy calcareous soils = leached vertic chernozems. With respect to the negative effect of heavy metal oxides on the biological properties of the soils, they form the following sequence: CrO3 > CuO = PbO ? NiO.

292

SALTIRSOIL: a simulation model for the mid to long-term prediction of soil salinity in irrigated agriculture  

Abstract The SALTIRSOIL model predicts soil salinity, sodicity and alkalinity in irrigated land using basic information on soil, climate, crop, irrigation management and water quality. It extends the concept of the WATSUIT model to include irrigation and crop management practices, advances in the calculation of evapotranspiration and new algorithms for the water stress coefficient and calculation of electrical conductivity. SALTIRSOIL calculates the soil water balance and soil solution concentration over the year. A second module, SALSOLCHEM, calculates the inorganic ion composition of the soil solution at equilibrium with soil calcite and gypsum at the soil-s CO2 partial pressure. Results from comparing predicted and experimentally determined concentrations, observations and predictions o...

293

What shapes edaphic communities in mineral and ornithogenic soils of Cierva Point, Antarctic Peninsula?  

Three mineral soil and four ornithogenic soil sites were sampled during summer 2006 at Cierva Point (Antarctic Peninsula) to study their bacterial, microalgal and faunal communities in relation to abiotic and biotic features. Soil moisture, pH, conductivity, organic matter and nutrient contents were consistently lower and more homogeneous in mineral soils. Ornithogenic soils supported larger and more variable bacterial abundances than mineral ones. Algal communities from mineral soils were more diverse than those from ornithogenic soils, although chlorophyll-a concentrations were significantly higher in the latter. This parameter and bacterial abundance were correlated with nutrient and organic matter contents. The meiofauna obtained from mineral soils was homogeneous, with one nematode sp...

294

Soil treatment to remove uranium and related mixed radioactive heavy metal contaminants. Quarterly report, January--March 1995  

The objective of this project is to design and develop a physico- chemical treatment process for the removal of uranium and heavy metals from contaminated soil to achieve target contamination levels below 35 pCi/g of soil and a target for non-radioactive heavy metals below concentration levels permissible for release of the soil. Ex- situ pilot-scale soil decontamination and leachate treatment test using Chalk River Chemical Pit soil are nearing completion. Soil decontamination tests using Fernald Incinerator Area soil originally scheduled for February 1995 was postponed to May 1995 as result of unexpected delays in the preparation of two drums of soils.

295

Research in Biogeosciences 2005 (BioGeo)  

... including minerals, rocks, hydrates, soils and dust). Proposers should seek: to increase our ... atmosphere, the acidification of mine-waste waters, and metal distributions in soils and sediments ...

296

Analysis of volatile-phase transport in soils using natural radon gas as a tracer  

We have conducted a field study of soil gas transport processes using radon gas as a naturally occurring tracer. The experiment monitored soil gas radon activity, soil moisture, and soil temperature at depth; barometric pressure, rainfall, and wind speed were monitored at the soil surface. Linear and multiple regression analysis under natural environmental conditions are influenced by soil moisture content, barometric pressure variations, soil temperature, and soil structure. The effect of wind speed on subsurface radon activities under our field conditions has not been observed. 25 refs., 12 figs., 1 tab.

297

DEVELOPING ECOLOGICAL SOIL SCREENING LEVELS: BENCHMARK VALUES FOR SOIL INVERTEBRATES, PLANTS, AND MICROBIAL FUNCTIONS  

Soils are repositories for environmental contaminants (COCs) in terrestrial ecosystems. Time, effort, and money repeatedly are invested in literature-based evaluations of potential soil-ecotoxicity......

298

Effects of thermically-dry sewage sludge and municipal waste compost amendment on microbial biomass, dehydrogenase activity and CO{sub 2} fluxes in a degraded agricultural soil  

Understanding the dynamic of soil C is a key to managing soil organic matter to enhance soil fertility and ecosystem functioning and reduce trace gas emission from soils. Our objective was to determine the influence of thermically-dry sewage sludge (TSL) and municipal waste compost and the application management on soil (mixed or on soil surface) applied at sludge (TSL) and municipal waste compost and the application management on soil (mixed or on soil surface) applied at two rates of 30 t ha{sup -}1 and 60 t ha{sup -}1, on CO{sub 2} fluxes, microbial biomass C (MBC) and dehydrogenase activity (DH), during an incubation study. (Author)

299

Number and Effectiveness of Pea Rhizobia in Danish Soils  

Most of 44 Danish soils tested contain between 1000 and 10 000 pea rhizobia (Rhizobium leguminosarum biovar viceae) per gram. Pea rhizobia were not detected in acid moor and forest soils. Only one case of failed nodulation in peas in the field has been noted, in spots in a reclaimed sandy heath moor at pH 4.7. Soil suspensions of nine of the soils were tested as inoculum in large outdoor pot cultures of peas grown to maturity in nitrogen free vermiculture. One soil approached the effectiveness of commercial inoculants, and four soils were quite effective. Two reclaimed soils and two of the three noncultivated soils showed low effectiveness.

300

A Review of Soil Nitrogen Mineralization as Affected by Water and Salt in Coastal Wetlands: Issues and Methods  

Abstract The availability of soil nutrients can have significant influence on water quality and wetland productivity. Nitrogen mineralization is the important process transferred from organic nitrogen to plant-available inorganic forms by soil animals and microorganism. Soil nitrogen mineralization processes in coastal wetlands will be greatly impacted by the significant changes of soil water and salt conditions caused by global climate change in the future. However, further studies concerning the effects of water and salt on soil nitrogen mineralization is still needed. The influences of other soil physical-chemical properties and plant community on soil nitrogen mineralization processes are also concluded. The influencing mechanism of soil nitrogen mineralization can be explained using t...

 
 
 
 
301

Evaluation of Regional Pedotransfer Functions Based on the BP Neural Networks  

The unsaturated soil hydraulic properties, including soil water retention curve and hydraulic conductivity, are the crucial input parameters for simulating soil water and solute transport through the unsaturated zone at regional scales, and are expensive to measure. These properties are frequently predicted with pedotransfer functions (PTFs) using the routinely measured soil properties. 110 soil samples at 22 soil profiles from Jiefangzha Irrigation Scheme in the Hetao Irrigation District of Inner Mongolia, China were collected for the analysis of soil properties i.e. soil bulk density, soil texture, particle size distribution, organic content, and soil water retention curve (SWRC). The Brooks-Corey (BC) model and van Genuchten (VG) model were used to fit the measured SWRC data for each soil sample by using the RETC software. Pedo-transfer functions (PTFS), which describes relationship between the basic soil properties and the parameters of the BC and VG models, were then established with the artificial neural networks (ANN) model. It is found that the ANN model has better effect on the clay loam, loamy clay, loam soil and silty clay to simulate BC model. However, it has better effect on the loam soil, loamy clay and sandy clay to simulate VG model. So, we can draw the conclusion that the ANN model can conveniently establish PTFS between soil basic feature parameters and SWRC model and has reasonable precision. This will be a good method to estimate soil water characteristic curve model and soil hydraulic parameter in the regional soil water and salt movement simulation and water resources evaluation.

302

Commercial potential of natural gas storage in lined rock caverns (LRC)  

The geologic conditions in many regions of the United States will not permit the development of economical high-deliverability gas storage in salt caverns. These regions include the entire Eastern Seaboard; several northern states, notably Minnesota and Wisconsin; many of the Rocky Mountain States; and most of the Pacific Northwest. In late 1997, the United States Department of Energy (USDOE) Federal Energy Technology Center engaged Sofregaz US to investigate the commercialization potential of natural gas storage in Lined Rock Caverns (LRC). Sofregaz US teamed with Gaz de France and Sydkraft, who had formed a consortium, called LRC, to perform the study for the USDOE. Underground storage of natural gas is generally achieved in depleted oil and gas fields, aquifers, and solution-mined salt caverns. These storage technologies require specific geologic conditions. Unlined rock caverns have been used for decades to store hydrocarbons - mostly liquids such as crude oil, butane, and propane. The maximum operating pressure in unlined rock caverns is limited, since the host rock is never entirely impervious. The LRC technology allows a significant increase in the maximum operating pressure over the unlined storage cavern concept, since the gas in storage is completely contained with an impervious liner. The LRC technology has been under development in Sweden by Sydkraft since 1987. The development process has included extensive technical studies, laboratory testing, field tests, and most recently includes a storage facility being constructed in southern Sweden (Skallen). The LRC development effort has shown that the concept is technically and economically viable. The Skallen storage facility will have a rock cover of 115 meters (375 feet), a storage volume of 40,000 cubic meters (250,000 petroleum barrels), and a maximum operating pressure of 20 MPa (2,900 psi). There is a potential for commercialization of the LRC technology in the United States. Two regions were studied in some detail - the Northeast and the Southeast. The investment cost for an LRC facility in the Northeast is approximately $182 million and $343 million for a 2.6-billion cubic foot (bcf) working gas facility and a 5.2-bcf working gas storage facility, respectively. The relatively high investment cost is a strong function of the cost of labor in the Northeast. The labor union-related rules and requirements in the Northeast result in much higher underground construction costs than might result in Sweden, for example. The LRC technology gas storage service is compared to other alternative technologies. The LRC technology gas storage service was found to be competitive with other alternative technologies for a variety of market scenarios.

303

Urbanization and climate change impacts on future urban flood risk in Can Tho city, Vietnam  

Urban development increases flood risk in cities due to local changes in hydrological and hydrometeorological conditions that increase flood hazard, and also to urban concentrations that increase the vulnerability. The relationship between the increasing urban runoff and flooding due to increased imperviousness better perceived than that between the cyclic impact of urban growth and the urban rainfall via microclimatic changes. The large-scale, global impacts due to climate variability and change could compound these risks. We present the case of a typical third world city - Can Tho (the biggest city in Mekong River Delta, Vietnam) - faced with multiple future challenges, namely: (i) climate change-driven sea-level rise and tidal effect, (ii) increase river runoff due to climate change, (iii) increased urban runoff driven by imperviousness, and (iv) enhancement of extreme rainfall due to urban growth-driven micro-climatic change (urban heat islands). A set of model simulations were used to assess the future impact of the combination of these influences. Urban growth of the city was projected up to year 2100 based on historical growth patterns, using a land-use simulation model (Dinamica-EGO). A dynamic limited-area atmospheric model (WRF), coupled with a detailed land-surface model with vegetation parameterization (Noah LSM), was employed in controlled numerical experiments to estimate the anticipated changes in extreme rainfall patterns due to urban heat island effect. Finally, a 1-D/2-D coupled urban-drainage/flooding model (SWMM-Brezo) was used to simulate storm-sewer surcharge and surface inundation to establish the increase in the flood risk resulting from the changes. The results show that, if the city develops as predicted, the maximum of inundation depth and area in Can Tho will increase by about 20%. The impact of climate change on inundation is more serious than that of urbanization. The worse case may occur if the sea level rises 100 cm and the flow from upstream happen in the high-development scenarios. The relative contribution of causes of flooding are significantly different at various locations; therefore, detailed research on adaptation are necessary for the future investments to be effective.

304

Characterizing Urban Heat Island Effect at Global Settlements Using MODIS and Nightlight Products  

Impervious surface area (ISA) from the National Geophysical Data Center (NGDC) and land surface temperature (LST) and Normalized Difference Vegetation Index (NDVI) from MODIS averaged over three annual cycles (2003-2005) are used in a spatial analysis to assess the urban heat island (UHI) skin temperature amplitude and its relationship to development intensity, size, and ecological setting for more than 3000 urban settlements over the globe. Development intensity zones based on %ISA were defined for each urban area emanating outward from the urban core to the non-urban rural areas nearby and used to stratify sampling for land surface temperatures and NDVI. Sampling was further constrained by biome and elevation to insure objective intercomparisons between zones and between settlements in different biomes. Stratification based in ISA permits the definition of hierarchically ordered zones that are consistent across urban areas in different ecological setting and across scales. We find that ecological context and settlement sizes significantly influence the amplitude of summer daytime UHI (urban-rural temperature difference). An average of 3.8 C UHI is found in cities built in biomes dominated by forests; 1.89 C UHI in cities embedded by grass/shrubs; and only a weak heat island or sometime heat sink in cities in arid and semi-arid biomes. Overall, the amplitude of UHI is significantly negative correlated (R=-0.66) with vegetation activity difference between urban and rural represented by MODIS NDVI. The average UHI is 4.7 C for global settlements larger than 500 km2, compared to 2.5 C for global settlements smaller than 50 km2 and larger than 10 km2. For all global settlements, the average amplitude of the UHI is 2.6 C in summer daytime and only 1.4 C in winter and impervious surface area is one of the primary drivers for increase in temperature with variations in different ecological context and latitudinal zones. More than 60% of the total variances in LST can be explained by ISA for urban settlements in forests at mid-to-high latitudes. The percentage will increase to more than 80% when only USA settlements are examined. Overall, our results indicate a possible way to examine and compare the amplitude as well as the driver of the UHI over global settlements. The relationship between UHI and key factors indicates that the energy consumption required for cooling is likely to increase with urban growth especially during summertime and in larger urban areas.

305

Use of the AGNPS model to assess impacts of development and best management practices in an urban watershed  

A Geographical Information System (GIS) is an invaluable tool in the estimation of land use changes and spatial variability in urban areas. (Non-Point Source (NPS) models provide hypothetical opportunities to assess impacts which storm water management strategies and land use changes have on watersheds by predicting loadings on a watershed scale. This study establishes a methodology for analyzing land use changes and management associated with them by utilizing a GIS analysis of impervious surfaces and AGricultural Non- Point Source (AGNPS) modeling. The GIS analysis of Total Impervious Area (TIA) was used to quantify increases in development and provided land use data for use in AGNPS modeling in a small artificially- delineated urban watershed. AGNPS modeling was executed in several different scenarios to predict changes in NPS loadings associated with increases in TIA and its subsequent management in a small artificially- delineated urban watershed. Data editing, creation and extracting was completed using ArcView (3.2) GeoMedia (6) GIS systems. The GIS analysis quantified the increase in urbanization via TIA within the Bluebonnet Swamp Watershed (BSW) in East Baton Rouge Parish (EBRP), Louisiana. The BSW had significant increases in urbanization in the 8 year time span of 1996 2004 causing and increase in quantity and decrease in quality of subsequent runoff. Datasets made available from the GIS analysis included TIA and the change in percentage from 1996 to 2004. This information is fundamental for the AGNPS model because it was used to calculate TIA percentages within each AGNPS cell. A 30 year daily climate file was used to execute AGNPS in different land use and storm water management scenarios within the 1100 acre BSW. Runoff qualities and quantities were then compared for different periods of 1996 and 2004. Predictions of sediment, erosion and runoff were compared according by scenario year. Management practices were also simulated by changing the Runoff Curve Number (RCN) within AGNPS and their results were also compared. This study provides an aid to planners and managers in estimating increases in urbanization by artificially- delineated watershed. It also in illustrates how to use AGNPS to predict NPS pollution and the influence that change in TIA, land use and storm water management strategies have on sediment loadings, erosion and runoff in a watershed.

306

Numerical Modeling of Coupled Groundwater and Surface Water Interactions in an Urban Setting  

The Dominguez Channel Watershed (DCW), located in the southern portion of Los Angeles County (Figure A.1), drains about 345 square miles into the Los Angeles Harbor. The cities and jurisdictions in DCW are shown in Figure A.2. The largest of these include the cities of Los Angeles, Carson, and Torrance. This watershed is unique in that 93% of its land area is highly developed (i.e. urbanized). The watershed boundaries are defined by a complex network of storm drains and flood control channels, rather than being defined by natural topography. Table (1) shows a summary of different land uses in the Dominguez Channel Watershed (MEC, 2004). The Dominguez Watershed has the highest impervious area of all watersheds in the Los Angeles region. The more impervious the surface, the more runoff is generated during a storm. Storm water runoff can carry previously accumulated contaminants and transport them into receiving water systems. Point sources such as industrial wastewater and municipal sewage as well as urban runoff from commercial, residential, and industrial areas are all recognized as contributors to water quality degradation at DWC. Section 303(d) of the 1972 Federal Clean Water Act (CWA) requires states to identify and report all waters not meeting water quality standards and to develop action plans to pursue the water quality objectives. These plans specify the maximum amount of a given pollutant that the water body of concern can receive and still meet water quality standards. Such plans are called Total Maximum Daily Loads (TMDLs). TMDLs also specify allocations of pollutant loadings to point and non-point sources taking into account natural background pollutant levels. This demonstrates the importance of utilizing scientific tools, such as flow and transport models, to identify contaminant sources, understand integrated flow paths, and assess the effectiveness of water quality management strategies. Since overland flow is a very important component of the water balance and hydrology of DCW, a parallel, distributed watershed model that treats flow in groundwater and surface water in a dynamically coupled manner will be used to build a flow model of the watershed. This coupled model forms the basis for modeling and understanding the transport of contaminants through the Dominguez Channel Watershed, which can be used in designing and implementing TMDLs to manage the water quality in this basin. In this report, the coupled surface water-groundwater flow model of DCW will be presented. This flow model was calibrated against a storm that occurred in February 21st, 2004. The model and approach are explained further in the following sections.

307

Trace Metals in Urban Stormwater Runoff and their Management  

In past decades, due to the rapid urbanization, land development has replaced forests, fields and meadows with impervious surfaces such as roofs, parking lots and roads, significantly affecting watershed quality and having an impact on aquatic systems. In this study, non-point source pollution from a diesel bus loop was assessed for the extent of trace metal contamination of Cu, Mn, Fe, and Zn in the storm water runoff. The study was carried out at the University of British Columbia (UBC) in the Greater Vancouver Regional District (GVRD) of British Columbia, Canada. Fifteen storm events were monitored at 3 sites from the diesel bus loop to determine spatial and temporal variations of dissolved and total metal concentrations in the storm water runoff. The dissolved metal concentrations were compared with the provincial government discharge criteria and the bus loop storm water quality was also compared with previous studies conducted across the GVRD urban area. To prevent storm water with hazardous levels of contaminants from being discharged into the urban drainage system, a storm water catch basin filter was installed and evaluated for its efficiency of contaminants removal. The perlite filter media adsorption capacities for the trace metals, oil and grease were studied for better maintenance of the catch basin filter. Dissolved copper exceeded the discharge criteria limit in 2 out of 15 cases, whereas dissolved zinc exceeded the criteria in 4 out of 15 cases, and dissolved manganese was below the criteria in all of the events sampled. Dissolved Cu and Zn accounted for 36 and 45% of the total concentration, whereas Mn and Fe only accounted for 20 and 4% of their total concentration, respectively. Since they are more mobile and have higher bioaccumulation potentials, Zn and Cu are considered to be more hazardous to the aquatic environment than Fe and Mn. With high imperviousness (100%) and intensive traffic at the UBC diesel bus loop, trace metal concentrations were 3, 0.7, 9, and 3.2 times higher than the GVRD urban area limits for Cu, Mn, Fe, and Zn, respectively. The filter showed high and stable capture efficiencies in total metals (Cu 62%, Mn 75%, Fe 83%, Zn 62%), dissolved metals (Cu 39%, Mn 37%, Fe 47%, Zn 32%), turbidity (72%), and suspended solids (74%) removal during the first month of operation. After that, there was gradual degradation. The catch basin filter performance improved significantly for the suspended solids and total metal removal after cleaning. However, the perlite filter medium showed poor performance for dissolved metal removal in the second study period. Based on the findings, a catch basin filter is effective in storm water management to control suspended solids loading from storm water runoff.

308

Freeze-Thaw Cycles Effects on Soil Compaction in a Clay Loam  

Inappropriate soil management practices and heavier farm machinery and equipment have led to an increase in soil compaction in the last two decades prompting increased global concern regarding the impact of soil compaction on crop production and soil quality in modern mechanized agriculture. A 3-yr comprehensive study was established to evaluate the dynamic of freeze-thaw cycles on soil compaction in a clay loam soil. Plots of frozen soils were compared with plots where soils were prevented from freezing with electrically heated blankets commonly used on concrete. Results showed that frequent freeze-thaw cycles over the winter alleviated a majority of soil compaction at the 0 - 20 cm depth. Soil penetration resistance in compacted soils was reduced by 73 and 68% over the winter at the 0 - 10 and 10 - 20 cm depths, respectively, due to dynamic effects of freeze-thaw cycles on soil structure and particles configuration. In unfrozen compacted soils, the penetration resistance was also reduced by 50 and 60% over winter at the 0 - 10 and 10 - 20 cm depths, respectively, due to the biology of soil, microbial activity, and disruptive effects of shrink-swell cycles. These results have demonstrated of how repeated freeze-thaw cycles can alleviate soil compaction, alter soil physical quality and create optimal soil conditions required for profitable growth of agricultural crops. The results from this study will save growers considerable time, money and energy currently required to alleviate soil compaction using other methods such as sub-soiling and deep tillage. We believe that Mother Nature provides ways to reverse soil compaction and improve soil structure and aggregation through the dynamic of freeze-thaw cycles that soils in Montana and other parts of the country go through each year. We concluded that the Mother Nature is the most effective and cheapest way to alleviate soil compaction.

309

Trace element-rich litter in soils: influence on biochemical properties related to the carbon cycle  

Purpose The aim of this work was to study the effect of ?trace element-rich litter? on the properties of two reforested polluted soils of different pH values (acidic and neutral) in terms of (1) availability of trace elements and (2) chemical and biochemical properties of the soil at different pH. We hypothesized that this litter would affect several parameters related to the organic matter cycle in soils, depending on initial soil pH. Materials and methods The experiment was carried out in three different soils: a non-polluted soil (NP) and two trace element-polluted soils (PN, neutral soil, and PA, acidic soil). Soil samples were placed in 2,000-cm3 microcosms and were incubated for 40?weeks in controlled conditions. Each soil was mixed with its corresponding litter, NP-L, PN-L and PA-L,...

310

Bioassays for the ecotoxicological and genotoxicological assessment of contaminated soils (results of a round-robin test). Part II. Assessment of the habitat function of soils - tests with soil microflora and fauna  

For the assessment of contaminated or remediated soils, aside from chemical analyses, ecotoxicological tests are performed which focus on the retention function of soils (determined by tests with aqueous soil extracts) and on the habitat function (determined by tests with soil). Whereas numerous tests exist as standardized guidelines for identifying the effect of chemicals, this is not the case for the assessment of soil quality. A round-robin test was performed to monitor the comparability of the results from ecotoxicological test methods on soils and to facilitate the standardization of corresponding test methods. Four contaminated soils were tested using a total number of fifteen test systems, including ecotoxicological and genotoxicological tests with soil extracts and soil. In the second part of this publication series, the results obtained from the tests with soil microorganisms and soil fauna are presented. (orig.)

311

Spatial distribution and development of soils in tropical karst areas from the Peninsula of Yucatan, Mexico  

Better understanding of soil formation requires knowing the spatial distribution of the soils that allows constructing models of soil sequences in multiple directions along various types of gradients. This approach was applied to comprehend the soil formation from the soil distribution in the tropical karst areas of the Peninsula of Yucatan, Mexico. For soil mapping, a two-step methodology was followed. First, a geomorphic analysis was performed; subsequently, 382 soil profiles were reclassified and integrated into a geopedologic map. Additional soil survey was carried out in areas where soil information was lacking (123 soil profiles). Satellite images were used to identify flooded areas. After conducting numerous field verifications and analyses, landforms and soils were combined to make...

312

The effects of agricultural management on selected soil properties of the arable soils in Tibet, China  

Lhasa is a crucial agricultural region of the Tibetan plateau for local grain and vegetable supplies. Therefore, to sustain soil productivity, it is important to understand how agricultural management practices can cause changes in soil properties. Based on the information from the soil survey conducted in the late 1980s, we selected and sampled the following sites in the summer of 2007: 17 sites of the tillage (A) layer soils and 13 sites of soil profiles, including the tillage and subsoil layers from three types of arable land soils in Lhasa (alluvial soil, steppe soil, and meadow soil). At the same time, another 55 composite samples and core samples were taken from the grain-crop land, open vegetable land and greenhouse vegetable land of the alluvial soil. The selected soil properties w...

313

The effects of different urban land use patterns on soil microbial biomass nitrogen and enzyme activities in urban area of Beijing, China  

Soil microbes are affected by various abiotic and biotic factors in urban ecosystem due to land use change. The effects of different land use patterns on soil microbial properties and soil quality are, however, largely unknown. This study compared soil nutrient status, microbial biomass nitrogen and enzyme activities under five different land use patterns-nature forest, park, farmland, street green, and roadside tree sites at various soil depths in Beijing, China. The results showed that soil properties were significantly affected by urban land use patterns and soil depths in the urban environment. Compared to forest sites, soil nutrients were markedly decreased in other land use patterns, except the highest soil organic matter content in roadside tree sites in 0-10cm soil layer. Soil micr...

314

Modification to degradation of hexazinone in forest soils amended with sewage sludge  

Influences of one sewage sludge on degradation of hexazinone and formation of its major metabolites were investigated in four forest soils (A, B, C and D), collected in Zhejiang Province, China. In non-amended forest soils, the degradation half-life of hexazinone was 21.4, 30.4, 19.4 and 32.8 days in forest soil A, B, C and D, respectively. Degradation could start in soil A and C without lag period because the two soils had been contaminated by this herbicide for a long time, possibly leading to completion of acclimation period of hexazinone-degrading bacteria. In forest soils amended with sewage sludge, the degradation rate constant increased by 17.3% in soil A, 48.2% in soil B, 8.1% in soil C and 51.6% in soil D, respectively. The higher degradation rates (soil A and C) in non-amended so...

315

Long-term effects of farming practices on soil quality, as influenced by farmer attitude and farm characteristics: Final report  

The objective of this study was to evaluate the impact of various farming systems on the quality of sandy to loam textured soils in the Dark Brown soil zone of Saskatchewan. The research was designed to identify farming practices that are soil-conserving or soil-degrading, the characteristics and attitudes of farmers who used soil-conserving farming systems, and soil properties that reflect management effects on soil, with sufficient magnitude and sensitivity to be practical and measurable indicators of soil quality. The research was carried out on 20 fields which had been farmed using crop-fallow, continuous cropping, extended rotation, and permanent cover farming systems. By controlling for soil and landscape characteristics, it was possible to compare the long-term effects of the farming systems on soil quality. The study notes measurable differences in soil quality among the farming systems studied and also discusses the socio-economic differences among the farming systems and farmers.

316

Effects of a surface wildfire on soil nutrient and microbial functional diversity in a shrubbery  

The aim of the study was to determine effects of a wildfire on soil nutrients and soil microbial functional diversity in short-term time scales. Burned and unburned control soil samples were collected 1day, and 2, 4, 8, 10, 12 and 15months after a shrubbery fire in Yumin county of Xinjiang, Northwest China. Nutrients of soil in each sampling time were detected and soil microbial functional diversity was measured by Biolog Eco plates. Results of the study showed that soil nutrients were significantly affected by fire. Soil pH increased immediately after the wildfire and was higher than that of unburned soil during 15months post fire. Soil organic matter and total N significantly decreased immediately after the fire and was even lower than control soil at the 15thmonth post fire. Soil availa...

317

The impact of soil freezing/thawing processes on water and energy balances  

A frozen soil parameterization coupling of thermal and hydrological processes is used to investigate how frozen soil processes affect water and energy balances in seasonal frozen soil. Simulation results of soil liquid water content and temperature using soil model with and without the inclusion of freezing and thawing processes are evaluated against observations at the Rosemount field station. By comparing the simulated water and heat fluxes of the two cases, the role of phase change processes in the water and energy balances is analyzed. Soil freezing induces upward water flow towards the freezing front and increases soil water content in the upper soil layer. In particular, soil ice obviously prevents and delays the infiltration during rain at Rosemount. In addition, soil freezing/thawing processes alter the partitioning of surface energy fluxes and lead the soil to release more sensible heat into the atmosphere during freezing periods.

318

Soil inoculation method determines the strength of plant-soil interactions  

There is increasing evidence that interactions between plants and biotic components of the soil influence plant productivity and plant community composition. Many plant-soil feedback experiments start from inoculating relatively small amounts of natural soil to sterilized bulk soil. These soil inocula may include a variety of size classes of soil biota, each having a different role in the observed soil feedback effects. In order to examine what may be the effect of various size classes of soil biota we compared inoculation with natural field soil sieved through a 1 mm mesh, a soil suspension also sieved through a 1 mm mesh, and a microbial suspension sieved through a 20 @mm mesh. We tested these effects for different populations of the same plant species and for different soil origins. Pla...

319

Distribution of cadmium among geochemical fractions in floodplain soils of progressing development.  

Initial soil development in river floodplains influences soil properties and processes. In this study, suites of young floodplain soils sampled at three European rivers (Danube/Austria, Ebro/Spain and Elbe/Germany) were used to link soil development to the soils' retention capacity for cadmium. Geochemical fractionation of original and metal-spiked soils was conducted. Cadmium remained in weakly bound fractions in both original and spiked soils, representing an entirely different behaviour than observed for copper in an earlier study. The tendency of incorporation into more stable forms over time was only slightly expressed. Correlation analysis revealed the involvement of different sorption surfaces in soil, with no single soil constituent determining cadmium retention behaviour. Nevertheless, in the calcareous soils of the Danube floodplain, we found increased cadmium retention and decreased portions of desorbable cadmium with progressing soil development. PMID:18222578

320

Long-Term Estimation of Soil Heat Flux Using Single Layer Time Series Data of Soil Temperature  

Soil heat flux may play an important role in surface energy balance. In this study, we examined the performances of two methods for predicting soil heat flux from single layer time series data of soil temperature. The first one is the traditional method, which an analytical solution of soil heat flux can be obtained by assuming the surface soil temperature varies sinusoidally. The second one is the connection between surface soil temperature and soil heat flux derived by half-order time derivative/integral, and is based on a simple model of heat transfer described by a one-dimensional diffusion equation with a constant heat diffusivity. Good agreements between measured and predicted soil heat fluxes were found for both methods. However, it was shown that the half-order derivative method has a better capability to capture flux accuracy and trend than the traditional method for long-term soil heat flux estimation. Keywords: soil heat flux, half-order derivative method, soil temperature

 
 
 
 
321

Biogenesis (trade name) soil washing technology: Innovative technology evaluation report  

Soil washing technologies are designed to transfer contaminants from soil to a liquid phase. The BioGenesis Soil Washing Technology uses soil washing with a proprietary surfactant solution to transfer organic contaminants from soils to wastewater. The BioGenesis soil washing process was evaluated under the SITE program at a refinery where soils were contaminated with crude oil. Results of chemical analyses show that levels of total recoverable petroleum hydrocarbons (TRPH), an indicator of degraded crude oil, decreased by 65 to 73 percent in washed soils. The TRPH in residual soils were allowed to biodegrade for an additional 120 days. Results indicate that soil washing and biodegradation removed 85 to 88 percent of TRPH in treated soils. The Innovative Technology Evaluation Report provides information on the technology applicability, economic analysis, technology limitations, a technology description, process residuals, site requirements, latest performance data, the technology status, vendors claims, and the source of further information.

322

EPA site demonstration of the Biotrol Soil Washing Process  

A pilot-scale soil washing process, patented by BioTrol, was demonstrated on soil that was contaminated by wood treating waste. The BioTrol Soil Washing was demonstrated in a treatment train sequence with two other pilot-scale units of BioTrol technologies for treatment of waste streams from the soil washer. The three technologies of the treatment train were: The BioTrol Soil Washer (BSW), the BioTrol Aqueous Treatment System (BATS), and the Slurry Bioreactor (SBR). The BioTrol processes were evaluated on pentachlorophenol (PCP) and polynuclear aromatic hydrocarbons (PAHs), which were the primary soil contaminants at the site. The sandy site soil, consisting of less than 10% of fines, was well suited for treatment by soil washing. The BSW successfully separated the feed soil (100% by weight) into 83% of washed soil, 10% of woody residues, and 7% of fines. The soil washer achieved up to 89% removal of PCP and PAHs, based on the difference between their levels in the feed soil and in the washed soil. The BATS degraded up to 94% of PCP in the process water from soil washing. The SBR achieved over 90% removals of PCP and 70-90% removals of PAHs, respectively from the soil washing. Cost of a commercial-scale soil washing, assuming use of all three technologies, was estimated to be $168 per ton of treated soil.

323

[Impact of biochar amendment on the sorption and dissipation of chlorantraniliprole in soils].  

The effects of biochar amendment on sorption and dissipation of chlorantraniliprole (CAP) in 5 different agricultural soils were studied. Red gum wood (Eucalyptus spp.) derived biochar was amended into a black soil, a yellow soil, a red soil, a purplish soil, and a fluvo-aquic soil at the rate of 0.5% (by weight). The sorption and dissipation behaviors of CAP in soils with and without biochar amendment were measured by batch equilibration technique and dissipation kinetic experiment, respectively. The objective was to investigate the impact of biochar application on the environmental fate of pesticides in agricultural soils with different physical-chemical properties, and evaluate the potential ecological impacts of field application of biochar materials. The results showed that biochar application in soils could enhance the sorption of CAP, but the magnitudes were varied among soils with different properties. Amendment of 0.5% (by weight) biochar in the black soil, which have high content of organic matter (4.59%), resulted in an increase of sorption coefficient (K(d)) by 2.17%; while for the fluvo-aquic soil with organic matter content of 1.16%, amendment of biochar at the same level led to an increase of 139.13%. The sorption capacity of biochar was partially suppressed when biochar was mixed with soils. The calculated K(Fbiochar) of biochar after mixed in the black soil, yellow soil, red soil, purplish soil, and fluvo-aquic soil were decreased by 96.94%, 90.6%, 91.31%, 68.26%, and 34.59%, respectively, compared to that of the original biochar. The half-lives of CAP in black soil, yellow soil, red soil, purplish soil, and fluvo-aquic soil were 115.52, 133.30, 154.03, 144.41 and 169.06 d, respectively. In soils amended with biochar, the corresponding half-lives of CAP were extended by 20.39, 35.76, 38.51, 79.19, and 119.75 d, respectively. Similar to the effects of biochar on CAP sorption, in soil with higher content of organic matter, the retardation of CAP dissipation by amending biochar was smaller than that in soil with lower content of organic matter. Our results suggested that application of biochar in soils could enhance the sorption and sequestration of CAP, and retard its soil dissipation, but the magnitudes depended on the organic matter content of the soils. PMID:22720587

324

Enhanced microbial degradation of deethylatrazine in atrazine-history soils  

Persistence and degradation of deethylatrazine, the primary metabolite of atrazine, was measured in soil with atrazine history (15 consecutive years of atrazine application) and no atrazine history (no atrazine application for 15 consecutive years). Uniformly ring-labeled {sup 14}C-deethylatrazine was applied to surface and subsurface soils for metabolism studies. After 60 d of incubation, mineralization of deethylatrazine to {sup 14}CO{sub 2} in the atrazine-history surface soil was twice that in the no-history surface soils (34% and 17% of the applied {sup 14}C, respectively). In surface soils, 25% of the applied {sup 14}C remained as deethylatrazine in the atrazine-history soil, compared with 35% in the no-history soil. Microbial plate counts indicated an increase in numbers of bacteria and fungi in soils incubated with deethylatrazine compared to control soils. Total microbial biomass of soils incubated with deethylatrazine, as determined by CO{sub 2} efflux using an infrared (IR) gas analyzer, showed no significant difference between atrazine-history, and no-history soil, but did show an increase above untreated control soils. Prior to treating soils with deethylatrazine, specific deethylatrazine degraders were quantified using a {sup 14}C-most-probable-number procedure. Deethylatrazine degraders were more numerous in atrazine-history surface soil compared to no-history surface soil. After incubation of soils with deethylatrazine, deethylatrazine degraders were more numerous in both history soils as compared to control soils. From these studies, it appears that deethylatrazine is degraded microbially to a greater extent in soils that have had long-term exposure to atrazine at field application rates compared to soils with no long-term exposure. Decreased persistence of this major metabolite of atrazine in atrazine-history soils is important in that there will be less available for movement in surface runoff and to groundwater.

325

Effects of compost and phosphate amendments on arsenic mobility in soils and arsenic uptake by the hyperaccumulator, Pteris vittata L  

Chinese brake fern (Pteris vittata L.), an arsenic (As) hyperaccumulator, has shown the potential to remediate As-contaminated soils. This study investigated the effects of soil amendments on the leachability of As from soils and As uptake by Chinese brake fern. The ferns were grown for 12 weeks in a chromated-copper-arsenate (CCA) contaminated soil or in As spiked contaminated (ASC) soil. Soils were treated with phosphate rock, municipal solid waste, or biosolid compost. Phosphate amendments significantly enhanced plant As uptake from the two tested soils with frond As concentrations increasing up to 265% relative to the control. After 12 weeks, plants grown in phosphate-amended soil removed >8% of soil As. Replacement of As by P from the soil binding sites was responsible for the enhanced mobility of As and subsequent increased plant uptake. Compost additions facilitated As uptake from the CCA soil, but decreased As uptake from the ASC soil. Elevated As uptake in the compost-treated CCA soil was related to the increase of soil water-soluble As and As(V) transformation into As(III). Reduced As uptake in the ASC soil may be attributed to As adsorption to the compost. Chinese brake fern took up As mainly from the iron-bound fraction in the CCA soil and from the water-soluble/exchangeable As in the ASC soil. Without ferns for As adsorption, compost and phosphate amendments increased As leaching from the CCA soil, but had decreased leaching with ferns when compared to the control. For the ASC soil, treatments reduced As leaching regardless of fern presence. This study suggest that growing Chinese brake fern in conjunction with phosphate amendments increases the effectiveness of remediating As-contaminated soils, by increasing As uptake and decreasing As leaching. - Phosphate amendment increases the effectiveness of Chinese brake fern to remediate As-contaminated soils, by increasing As uptake and decreasing As leaching.

326

Predicting risk of rill initiation in a sub-catchment of Lake Balaton, Hungary  

Rill erosion is an accelerated form of soil degradation. It removes much more soil and nutrients from the agricultural land than sheet erosion. Soils in the southern sub-watershed of Lake Balaton are especially prone to rill erosion and they contribute to siltation of ditches, to muddy floods and to eutrofication of the lake. The parent material in this region is mainly (sandy) loess and the soils are already moderately or strongly eroded thus, the low tolerance of loess against erosion determines erodibility. Identification of soils with high risk of rill erosion is crucial to plan mitigation measures. Soil erodibility has been investigated in this study in the catchment of Tetves stream. The USLE soil erodibility factor and soil slaking are widely accepted indicators for soil erosion. Both of them are published for all soil texture classes in handbooks of soil mapping. We have found that erodibility derived from our physical model has a close linear correlation with the product of the USLE soil erodibility factor and soil slaking grade thus, USLE could be directly used to assess parameters for physical based models. Rill erosion is highly probable if the product of KUSLE X slaking grade is above 2. Digital maps were produced to delineate soils with high potential for rill erosion. The basic data for the soil properties were drawn from the 1:10,000 soil map. Soil texture classes were used to assign KUSLE and slaking grade to the soil units. Beyond soil properties, other factors also influence rill formation: slope, surface cover, rainfall intensity. However, identifying soil properties, which make soils prone to rill erosion, is an important initial step for the reduction of diffuse agricultural loads to Lake Balaton. It might be the objective of River Basin Management Plans in the Water Framework Directive to prevent rill erosion and our study provides scientific evidence for targeting this policy.

327

Generalized Density-Corrected Model for Gas Diffusivity in Variably Saturated Soils  

Accurate predictions of the soil-gas diffusivity (Dp/Do, where Dp is the soil-gas diffusion coefficient and Do is the diffusion coefficient in free air) from easily measureable parameters like air-filled porosity (?) and soil total porosity (?) are valuable when predicting soil aeration and the emission of greenhouse gases and gaseous-phase contaminants from soils. Soil type (texture) and soil density (compaction) are two key factors controlling gas diffusivity in soils. We extended a recently presented density-corrected Dp(?)/Do model by letting both model parameters (? and ?) be interdependent and also functions of ?. The extension was based on literature measurements on Dutch and Danish soils ranging from sand to peat. The parameter ? showed a promising linear relation to total porosity, while ? also varied with ? following a weak linear relation. The thus generalized density-corrected (GDC) model gave improved predictions of diffusivity across a wide range of soil types and density levels when tested against two independent data sets (total of 280 undisturbed soils or soil layers) representing Danish soil profile data (0–8 m below the ground surface) and performed better than existing models. The GDC model was further extended to describe two-region (bimodal) soils and could describe and predict Dp/Do well for both different soil aggregate size fractions and variably compacted volcanic ash soils. A possible use of the new GDC model is engineering applications such as the design of highly compacted landfill site caps.

328

Tillage Effects on Microbial and Carbon Dynamics During Plant Residue Decomposition  

One goal of soil carbon (C) sequestration, a greenhouse gas mitigation strategy, is to increase the mass of C stored in agricultural soils. Reducing soil disturbance, e.g. no-tillage, facilitates soil fungal growth and results in higher C sequestration rates. However, the specific mechanisms associa...

329

Soil Liquefaction  

This tutorial provides general information on soil liquefaction, a hazard associated with earthquakes, for interested lay persons, and more detailed information for engineers. Topics include what soil liquefaction is, and when, where, and why it occurs. There are also suggestions for minimizing the risk of soil liquefaction, links to sites on soil liquefaction research, and links to sites on related topics.

330

EFFECTS OF GRAPEVINE ROOTS, SOIL RESOURCES AND DEPTH ON SOIL MICROBIAL COMMUNITIES IN A PINOT NOIR VINEYARD  

Soil microbial communities are influenced by many factors, including root presence, soil disturbance, variation in soil type and texture, and gradients in resource availability. We investigated the relationship between these factors and the associated soil microbial communities under Pinot Noir grap...

331

Fate of diuron and terbuthylazine in soils amended with two-phase olive oil mill waste  

The addition of organic amendments to soil increases soil organic matter content and stimulates soil microbial activity. Thus, processes affecting herbicide fate in the soil should be affected. The objective of this work was to investigate the effect of olive oil production industry organic waste (a...

332

Tillage Effects on Soil Organic Carbon Fractions in Mediterranean Dryland Agroecosystems  

Under semiarid conditions, soil quality and productivity can be improved by enhancing soil organic matter content by means of alternative management practices. In this study, we evaluated the feasibility of no-till (NT) and cropping intensification as alternative soil practices to increase soil orga...

333

Method for treatment of soils contaminated with organic pollutants  

A method for treating soil contaminated by organic compounds wherein an ozone containing gas is treated with acid to increase the stability of the ozone in the soil environment and the treated ozone applied to the contaminated soil to decompose the organic compounds. The soil may be treated in situ or may be removed for treatment and refilled.

334

WATER AND METHYL ISOTHIOCYANATE DISTRIBUTION IN SOIL AFTER DRIP FUMIGATION WITH METAM SODIUM.  

Alternative soil fumigants to methyl bromide do not distribute as readily in the soil. Application methods and soil conditions are important to their efficacy. Metam sodium degrades in the soil to a fumigant, methyl isothiocyanate (MITC). It is soluble and can be applied with irrigation water. E...

335

Remediation of radioactive contaminated soils  

Distribution of radionuclides in Republic of Belarus` soils after Chernobyl NPP accident has been investigated. Different methods of soils cleaning from radionuclides and effectiveness of these methods in the conditions of large-scale contamination were examined. Cutting and localizing of soil upper layer were shown to be the most effective method for decreasing the soil radioactive contamination level.

336

Quantifying the linkages among soil health, organic farming, and food  

Organic farming systems utilize organic amendments, diverse crop rotations and cover crops to promote soil fertility and enhance soil health. These practices increase biologically available forms of soil organic matter, and increase the activities of beneficial soil microbes and invertebrates. Physi...

337

Carbon mineralization and microbial biomass in soil aggregates from two tillage systems  

Soil quality is a concept of many interrelated factors that perform in concert to improve soil productivity. Few of the factors for soil quality are microbial biomass, soil aggregate fractions, and carbon mineralization in different aggregate fractions that are influenced by the agricultural practic...

338

Determinants of oral bioavailability of soil-borne contaminants  

Children ingest soil, either accidentally via hand-to-mouth behavior or deliberately. In this manner, a child ingests on average between 50 and 200 mg soil/day, although amounts of as much as 60 g/day have also been observed. Hence, soil ingestion can be a main route of exposure to soil-borne ...

339

Exploring soils and ecohydrological structure in small watersheds using electromagnetic induction  

Soil moisture sensors generally strive to use the real permittivity as the basis for estimating soil water content from measured electrical properties of soil. It has been shown that a reasonably good general calibration can be developed for mineral soils on this basis. However, at the low measureme...

340

Development and validation of a method to determine threshold values for effects of genetically modified plants on the habitat function of soils: Poster at the 13th SETAC Europe Annual Meeting, Hamburg, 27.4.-1.5.2003  

The safe cultivation of genetically modified plants (GMP) requires a comprehensive investigation of possible harmful soil changes - especially with respect to the natural habitat function of soils for soil organisms, as mentioned in §2 of the BBodSchG (Bundesbodenschutzgesetz; German Federal Soil Pr...

 
 
 
 
341

Research progress on real-time measurement of soil attributes for precision agriculture  

In order to develop a real-time analyzer for soil attributes, this study analyzed the needs for real-time measurement of soil attributes and reviewed major soil attributes to be measured in soil testing and commonly-used testing methods, including traditional chemical analysis, methods based on elec...

342

Surfactant Effects on the Water-stable Aggregation of Wettable Soils from the Continental U.S  

Surfactants may affect soil structure differently depending upon a soil’s wettability or the quality of rainfall or irrigation water. This study evaluated surfactant and water quality effects on water repellency and water-stable aggregation of wettable and nonwettable soils by quantifying water dro...

343

Mechanical behaviour of unsaturated aggregated soils  

Particle aggregation is a commonly observed phenomenon in many types of soils, such as natural clays and agricultural soils. These soils contain porous aggregates, often separated by large, interaggregate pores. Two levels of intra- and interaggregate porosity are, therefore, present in these soils....

344

Prediction of Hydraulic Conductivity as Related to Pore Size Distribution in Unsaturated Soils  

Soil pore volume as well as pore size, shape, type (i.e. biopore versus crack), continuity, and distribution in soil affect soil water and gas exchange. Vertical and lateral drainage of water by gravitational forces occurs through large, non-capillary soil pores, but redistribution and upward moveme...

345

Effect of the filter paper calibration on the soil-water retention curve of an unsaturated compacted silt sand Efeito da calibração do papel filtro na curva de retenção de um solo arenoso siltoso compactado  

The soil suction is a key variable in the analysis of the hydro-mechanical behavior of unsaturated soils. The filter paper method (FPM) calculates soil suction indirectly by measuring the gravimetric water content of the filter paper at equilibrium that is related to soil suction through a predeterm...

346

Soil organic matter chemistry in allophanic soils: a pyrolysis-GC/MS study of a Costa Rican Andosol catena  

Soil organic matter (SOM) in allophanic soils is supposed to accumulate due to protection caused by binding to allophane, aluminium and iron. We investigated a catena of allophanic and non-allophanic soils in Costa Rica to determine the effect of such binding mechanisms on SOM chemistry. These soils...

347

Unsaturated soil hydraulic conductivity: The field infiltrometer method  

Theory: Field methods to measure the unsaturated soil hydraulic conductivity assume presence of steady-state water flow. Soil infiltrometers are desired to apply water onto the soil surface at constant negative pressure. Water is applied to the soil from the Marriott device through a porous membrane...

348

AUTOMATION OF A FALLING HEAD PERMEAMETER FOR RAPID DETERMINATION OF HYDRAULIC CONDUCTIVITY ON MULTIPLE SAMPLES  

Soil management can be improved if soil spatial variability is taken into account. We initiated a study to quantify spatial variability of soil hydraulic properties. Initially we focused on hydraulic conductivity of saturated soil (Ks) by horizons. In situ Ks measurements made in the Ap, Bt, and t...

349

Application of observation operators for field scale soil moisture averages and variances in agricultural landscapes  

Soil moisture is a key variable in understanding hydrologic processes and energy fluxes at the land surface. In spite of developing technologies for in-situ soil moisture measurements and increased availability of remotely sensed soil moisture data, scaling issues between soil moisture observations ...

350

Soil fauna, soil properties and geo-ecosystem functioning  

The impact of soil fauna on soil processes is of utmost importance, as the activity of soil fauna directly affects soil quality. This is expressed by the direct effects of soil fauna on soil physical and soil chemical properties that not only have great importance to food production and ecosystems services, but also on weathering and hydrological and geomorphological processes. Soil animals can be perceived as ecosystem engineers that directly affect the flow of water, sediments and nutrients through terrestrial ecosystems. The biodiversity of animals living in the soil is huge and shows a huge range in size, functions and effects. Most work has been focused on only a few species such as earthworms and termites, but in general the knowledge on the effect of soil biota on soil ecosystem functioning is limited as it is for their impact on processes in the soil and on the soil surface. In this presentation we would like to review some of the impacts of soil fauna on soil properties that have implications for geo-ecosystem functioning and soil formation processes.

351

Derivation of partition relationships to calculate Cd, Cu, Ni, Pb, Zn solubility and activity in soil solutions  

The distribution of heavy metals (Cd, Cu, Ni, Pb and Zn) between soil and soil solution was measured in more than 1400 soil - solution samples. These samples reflect the variability that occurs within the Netherlands and covers all major soil types. The distribution of metals between solid phase (ad...

352

Can Infrared Spectroscopy Be Used to Measure Change in Potassium Nitrate Concentration as a Proxy for Soil Particle Movement?  

Displacement of soil particles caused by erosion influences soil condition and fertility. To date, the cesium 137 isotope (137Cs) technique is most commonly used for soil particle tracing. However when large areas are considered, the expensive soil sampling and analysis present an obstacle. Infrared...

353

Can infrared spectroscopy be used to measure change in potassium nitrate concentration as a proxy for soil particle movement  

Displacement of soil particles caused by erosion influences soil condition and fertility. To date, the cesium 137 isotope (137Cs) technique is most commonly used for soil particle tracing. However when large areas are considered, the expensive soil sampling and analysis present an obstacle. Infrared...

354

Near-infrared reflectance spectroscopy (NIRS): a practical tool for the assessment of soil carbon and nitrogen budget  

The assessment of greenhouse gas emissions from soils requires an accurate knowledge on the fate of carbon (C) and nitrogen (N) in soils. This knowledge shouldn't be limited to C and N stocks in soils but should incorporate the quantification of functional soil organic matter (SOM) fractions with di...

355

Relationship between magnesium extracted by 0.01 M calcium chloride extraction procedure and conventional procedures  

A multinutrient soil extraction procedure in routine soil testing is attractive. Therefore, it has been suggested to convert conventional soil testing programs into a 0.01 M calcium chloride (CaCl2) multinutrient soil testing program using the relationship between test values of the 0.01 M CaCl2 ext...

356

MODELING SOIL FAILURE CAUSED BY PRISMATIC AND CONICAL TOOLS  

Soil strength, or mechanical resistance of a soil to failure, has been widely used to estimate the degree of soil compaction. Conventional measurements with cone penetrometers are laborious; therefore, we are working to develop an on-the-go soil strength profile sensor to collect data dense enough t...

357

The engineering significance of shrinkage and swelling soils in blast damage investigations  

In the US each year it has been estimated that expansive soils cause approximately $9.0 billion in damage to buildings, roads, airports, and other facilities. This figure alone exceeds the damage estimate for earthquakes, floods, tornadoes, and hurricanes combined. Unfortunately, some cases of expansive soil damage (swelling) are blamed on rock blasting operations if the blasting operations are located within the immediate area. While simple tests, such as the Atterberg limits test, can characterize a soil as expansive, it does not necessarily answer the question whether the foundation soils are causing distresses to a structure. In particular, it appears that once a soil has been labeled as nonexpansive it is no longer considered as a problem soil, in which case blast vibrations become the prime suspect. It should be emphasized, however, that even non-plastic soils, those soils with low to nonexistent plastic indexes, can exhibit significant shrinkage characteristics that can result in significant damage to structures. While expansive soil is a function of the mineralogy of the soil particles, i.e., swelling clay minerals, shrinkage is caused by the loss of moisture from soil as capillary pressures exceed the cohesion or tensile strength and is therefore a function of the soils particle size and its pore size distribution. This is a significant problem for all fine grained soils regardless of the soil`s mineralogy. It`s particularly important for regions of the US that typically have a positive water balance but experience significant drought periods when soil moisture is lost.

358

Triazine Soil Interactions  

The fate of triazine herbicides in soils is controlled by three basic processes: transformation, retention, and transport. Sorption of triazines on surfaces of soil particles is the primary means by which triazines are retained in soils. Soils are very complex mixtures of living organisms, various t...

359

DISTRIBUTION AND DISSIPATION OF 1,3-D AND CHLOROPICRIN AFTER SHANK AND DRIP APPLICATIONS IN A CLAY LOAM SOIL  

Soil conditions (e.g., texture and water content) and use of tarps affect fumigation efficacy in controlling soil pests and emissions. Research has found that standard HDPE is not an effective barrier for 1,3-D and high soil moisture is more effective in reducing emission than HDPE. High soil moistu...

360

Emergence and growth of plant species in coal mine soil  

Experiments were conducted in the laboratory and greenhouse in Arizona with the following objectives: to evaluate the chemical properties of undisturbed soil, surface-mined coal land (coal mine soil) on the Black Mesa Coal Mine, and Gila loam soil; and to study the emergence of seven plant species in the greenhouse in Gila loam soil and coal mine soil. The pH of coal mine soil (6.2) was lower than the pH of undisturbed soil (7.5) or Gila loam (7.6). The total soluble salts in coal mine soil (3241) and undisturbed soil (4592) were much higher than in Gila loam (378); however, coal mine soil was lower in total soluble salts than undisturbed soil. The nitrogen content of coal mine soil was higher than the nitrogen content of undisturbed soil or gila loam. Emergence percentages for seven plant species grown in coal mine soil were similar to emergence percentages for the same species grown in Gila loam. Alfalfa (Medicago sativa L.), barley (Hordeum vulgare L.), and wheat (Triticum aestivum L. em Thell.) had from 84 to 93% emergence in coal mine soil. Indian ricegrass (Oryzopsis hymenoides Roem. and Shult), fourwing saltbush (Atriplex canescens Pursh), yellow sweetclover (Melilotus officinalis Lam.), and winterfat (Euroti lanata Pursh.) emerged alfalfa, barley, and wheat as were produced in Gila loam under the same soil-moisture and fertility conditions.

 
 
 
 
361

Soil decontamination method  

A method of processing contaminated soil is disclosed whereby the soil in the form of feed stock is heated in a combustion chamber of a processor with the hydrocarbons being evacuated to a condensing system resulting in a petroleum product while the soil feed stock is detoxified in an afterburner to form clean soil for general use. 1 fig.

362

FREQUENCY ANALYSIS OF YIELD FOR DELINEATING MANAGEMENT ZONES  

Use efficiency of agricultural inputs and farm profitability could be improved by identifying management zones for variable rate applications. Management zones may be delineated by using soil properties such as soil texture, series, electrical conductivity and soil color. Using one of these soil pro...

363

On dynamic soil properties for marine environment  

Offshore structures are subjected to the action of wind, wave, sea storms, and sea-quakes, and transmit dynamic loads to the underlying soils. This paper highlights the role of dynamic loading on the design soil properties in marine environment. Factors affecting dynamic soil properties and typical soil properties of marine deposits are presented.

364

Willow growth in response to nutrients and moisture on a clay landfill cap soil. II: Water use  

This paper describes studies into the effects of soil factors and water stress on water use by willow (Salix viminalis L.) on a clay landfill cap soil and a sandy loam. Individual plants were grown in lysimeters containing these soils under different watering regimes and with different soil amendmen...

365

Effect of basic slag addition on soil properties, growth and leaf mineral composition of beans in a Cu-contaminated soil  

Basic slag (BS) is an alkaline by-product of the steel industry with potential properties to ameliorate nutrient supply and metal stabilisation in contaminated soils. The BS effects on soil pH, soil conductivity, growth and chemical composition of beans were investigated using an acid, sandy soil fr...

366

Print - Nasa  

May 26, 2009 ... Image of global root-zone soil moisture data overlaid on a Google Earth map ... Scientists taking measurements of soil moisture with ground-based sensors ... in recent years have caused soil to dry up, crippling crop production. ... Crop analysts must estimate root-zone soil moisture, the amount of water ...

367

Practical Method for Extraction of PCR-Quality DNA from Environmental Soil Samples ? †  

Methods for the extraction of PCR-quality DNA from environmental soil samples by using pairs of commercially available kits were evaluated. Coxiella burnetii DNA was detected in spiked soil samples at <1,000 genome equivalents per gram of soil and in 12 (16.4%) of 73 environmental soil samples.

368

Organic matter dynamics in coarse sandy calcareous soils  

The decomposition of organic matter in coarse sandy calcareous soils (beach sand) is thought to be much higher than in acid fine sandy soils but relatively little research is performed on these soils. Laboratory incubation experiments in which the release of soil carbon (C) is determined may overest...

369

The use of earthworms in ecological soil classification and assessment concepts  

Without doubt, earthworms are the most important soil invertebrates in most soils worldwide, in terms of both biomass and activity. Several species are even considered to be ecosystem engineers. Earthworms are also known to influence soil structure, soil chemistry, and, in particular, processes like...

370

Influence of flooding and metal immobilising soil amendments on availability of metals for willows and earthworms in calcareous dredged sediment-derived soils  

Soil amendments previously shown to be effective in reducing metal bioavailability and/or mobility in calcareous metal-polluted soils were tested on a calcareous dredged sediment-derived soil with 26 mg Cd/kg dry soil, 2200 mg Cr/kg dry soil, 220 mg Pb/kg dry soil, and 3000 mg Zn/kg dry soil. The amendments were 5% modified aluminosilicate (AS), 10% w/w lignin, 1% w/w diammonium phosphate (DAP, (NH{sub 4}){sub 2}HPO{sub 4}), 1% w/w MnO, and 5% w/w CaSO{sub 4}. In an additional treatment, the contaminated soil was submerged. Endpoints were metal uptake in Salix cinerea and Lumbricus terrestris, and effect on oxidation-reduction potential (ORP) in submerged soils. Results illustrated that the selected soil amendments were not effective in reducing ecological risk to vegetation or soil inhabiting invertebrates, as metal uptake in willows and earthworms did not significantly decrease following their application. Flooding the polluted soil resulted in metal uptake in S. cinerea comparable with concentrations for an uncontaminated soil. - Some soil amendments resulted in higher metal uptake by earthworms and willows than when the polluted soil was not amended but submersion of the polluted soil resulted in reduced Cd and Zn uptake in Salix cinerea.

371

Driving forces from soil invertebrates to ecosystem functioning: the allometric perspective.  

The European soil policy is being focussed towards a more conscious and sustainable use of the soil, taking into account ecological, economical and societal dimensions. Living soil organisms are reliable bioindicators, as they provide the best reflection of the soil system, ecological services and e...

372

SCALING METHODS IN SOIL PHYSICS  

Soil physical properties are needed to understand and manage natural systems spanning an extremely wide range of scales. Much of soil data are obtained from small soil samples and cores, monoliths, or small field plots, yet the goal is to reconstruct soil physical properties across fields, watershed...

373

MILESTONES IN SOIL PHYSICS  

This special issue of “Soil Science“ celebrates the enormous accomplishments made during the past century or more in the field of soil science, including some of the key articles published in Soil Science during its 90 years of existence. In this article, we focus on the contributions in soil physic...

374

Soil Test Calibration for Predicting Corn Response to Phosphorus in the Northeast USA  

The consensus of soil fertility specialists working in the Northeast USA was that soil testing and recommendation systems for P needed to be reexamined because of recent changes in soil testing methodology in the laboratory and corn (Zea mays L.) production technology in the field. Soil tests (M-COL...

375

Communications in Soil Science and Plant Analysis ???????????  

International in coverage, Communications in Soil Science and Plant Analysis presents recent advances in soil science and crop production, with particular reference to elemental content of soils and plants and plant nutrition. Topics include soil chemistry, mineralogy, fertility and testing o...

376

Soil Science ????  

Soil Science satisfies the professional needs of all scientists and laboratory personnel involved in soil and plant research by publishing primary research reports and critical reviews of basic and applied soil science, especially as it relates to soil and plant studies and general environmen...

377

Canadian Journal of Soil Science ?????????  

Canadian Journal of Soil Science is an international peer-reviewed journal published in cooperation with the Canadian Society of Soil Science. The journal publishes original research on the use, management, structure and development of soils and draws from the disciplines of soil science, agr...

378

[Relationships between soil nutrients and rhizospheric soil microbial communities and enzyme activities in a maize-capsicum intercropping system].  

By using plastic sheet and nylon mesh to partition the root systems of maize and capsicum in a maize-capsicum intercropping system, this paper studied the relationships between soil biological factors and nutritive status in the intercropping system, with no partitioning and maize monoculture and capsicum monoculture as the control. The results showed that intercropping maize and capsicum had its high superiority. In the treatments of no partitioning and nylon mesh portioning in the intercropping system, soil enzyme activities, microbial individuals and nutrient contents were significantly higher, compared with those in the treatments of nylon mesh partitioning and monocultures. All kinds of soil available nutrients showed significant or very significant positive correlations with soil biological factors, except that soil available Mg was negatively correlated with soil fungi and catalase activity. Pathway analysis indicated that in the intercropping system, soil urease, catalase, protease, and bacteria were the main factors affecting the accumulation of soil organic matter, saccharase was the most important factor affecting soil alkali-hydrolyzable N, urease was the most important factor affecting soil available P, and bacteria largely determined soil available K. Soil alkaline phosphatase and fungi selectively affected the accumulation of soil organic matter and available N, P and K. There was a slight negative correlation between soil actinomycetes and soil nutrients, suggesting that actinomycetes had little effect on soil nutrient formation. PMID:18333449

379

Can we predict uranium bioavailability based on soil parameters? Part 1: Effect of soil parameters on soil solution uranium concentration  

Present study aims to quantify the influence of soil parameters on soil solution uranium concentration for U-238 spiked soils. Eighteen soils collected under pasture were selected such that they covered a wide range for those parameters hypothesised as being potentially important in determining U so...

380

Quantitative soil vapor as an alternative to traditional soil sampling for VOCs: Characterization and remediation  

This paper will present the results of a Soil Vapor Demonstration Project that compared pairs of soils and adjacent soil vapor samples. This study was conducted at the Aerojet General Corporation site in Rancho Cordova, CA. The author will describe the use of soil vapor sampling as a better alternative to traditional soil sampling and analysis for volatile organic compounds, and as a tool to locate possible DNAPL. The paper will present how the Demonstration Project was performed to substantiate to the U.S. EPA and state agencies that soil vapor is a viable and quantitative sampling methodology. This approach utilized various soil properties including measured soil partitioning coefficients, to calculate VOC mass in soils based on soil vapor data and equilibrium conditions. The results showed that traditional soil samples underestimated the mass of VOCs present in over 90 percent of the soil/soil vapor pairs. The paper also will include observations of other physical parameters which were monitored during the program to assess the effect on the soil vapor concentrations. In addition, the flexibility, speed, and cost-effectiveness of sampling allowed for more comprehensive characterization with a higher level of confidence. The data collected demonstrated that the soil vapor technique provides a more comprehensive evaluation of VOC distribution in the vadose zone than traditional soil sampling.

 
 
 
 
381

Exploring the potential of near-surface geophysical methods to delineate a shallow hardpan in a southeastern U.S. sandy coastal plain soil  

A hardpan, which is a dense soil layer near the ground surface, is an undesirable feature of many soils in the Southeast U.S., especially sandy Coastal Plain soils. Shallow hardpans restrict root growth and water penetration through the soil profile, in turn reducing the effective crop root zone and...

382

Effectiveness of exclosures to control soil erosion and local community perception on soil erosion in Tigray, Ethiopia  

The study investigated how effective exclosures are in the fight against soil erosion and how they are perceived as a means to control soil erosion by the local community (farmers and local experts). The universal soil loss equation (USLE) used to estimate potential soil erosion. Data on local commu...

383

Effectiveness of exclosures to control soil erosion and local communities perception on soil erosion  

The study investigated how effective exclosures are in the fight against soil erosion and how they are perceived as a means to control soil erosion by the local community (farmers and local experts). The universal soil loss equation (USLE) used to estimate potential soil erosion. Data on local commu...

384

Infiltration process and groundwater table raising in a paddy field area  

The water coming from the soil surface after the saturation of the soil stratum over the groundwater table at field saturation raises the groundwater level. The soil structure and the soil texture characterize the infiltration process. The resultant of the gravitational force and the capillary force...

385

Methane consumption by indigenous grassland and peat soil microflora  

Soils taken from both Dutch grassland on peat soils and from Dutch peat soil were investigated for their ability to oxidize both very high and atmospheric concentrations of methane. In batch cultures the kinetics of methane oxidation by soil from different depths incubated with 1, 10, 100 and 10.000 ppmv methane, respectively, were determined. All 4 applied concentrations of methane were degraded by both types of soil. Especially at higher methane concentrations (100 and 10.000 ppmv) the peat soil showed much higher degradation rates than the grassland soil. This observation correlated positively with field measurements made with both types of soil showing the formation of methane was much greater in the peat soil. The highest oxidative activities were observed in both soils between 5 and 10 cm soil depth. Thereby, the degradation rates for peat soil were between 2.5 and 6 times higher than that of grassland on peat soil. Most importantly, these experiments demonstrated that both types of soil act as a sink for methane because they were able to degrade even atmospheric concentrations of about 1 ppmv. In continuous experiments, grassland soil was incubated in columns receiving a continuous gas-flow of 4 ml/min containing methane at 4 different concentrations. Thereby, an increase in the degradative capacities of the soil at all concentrations of methane was observed. It was attempted to isolate low affinity methane-oxidizing bacteria from these columns. Unfortunately, these experiments were not successful. 13 figs., 29 refs.

386

SOIL FAILURE MODELS FOR VERTICALLY OPERATING AND HORIZONTALLY OPERATING STRENGTH SENSORS  

Soil strength, or mechanical resistance of a soil to failure, has been widely used to estimate the degree of soil compaction. Conventional measurements with cone penetrometers are laborious; therefore, an on-the-go soil strength profile sensor that collects data dense enough to show the spatial with...

387

Electrical Resistivity in a Loamy Soil: Identification of the Appropriate Pedo-Electrical Model  

Electrical resistance tomography (ERT) can be used for the noninvasive characterization of soil moisture and soil structural heterogeneity. Any attempt to relate electrical resistivity measurements to soil moisture content or soil bulk density, however, must rely on a “pedo-electrical” function, i.e...

388

Soil sampling methods for pH tests in soils of different genesis and relief and geostatistical analysis of data PH ?mini? pa?mimo metodai ir duomen? geostatistin? analiz? skirtingo reljefo bei genez?s dirvožemiuose  

Tasks: 1. To determine a soil sampling method most suitable for pH tests in soils on flat, rolling and hilly relief using regular grid sampling, soil database (Dirv_DB10LT) and soil agrochemical properties database (DirvAgroch_DB10LT). 2. To investigate the suitability of geostatistical methods for ...

389

MHTGR licensing approach and plant response to off normal events  

The MHTGR design meets stringent top-level regulatory and user safety requirements that require that the normal and off-normal operation of the plant not disturb the public's day-to-day activities. Quantitative, generic top-level regulatory criteria have been specified from US NRC and EPA sources to guide the design. A probabilistic risk assessment has been utilized to select licensing basis events that cover a wide spectrum of events. The MHTGR fuel has been designed to limit the primary circuit activities to levels that, even if completely released, are within those allowed by 10CFR100. The focus of the safety approach has then been centered on retaining the radionuclide inventory within the fuel by removing core heat, controlling chemical attack, and by controlling heat generation. The core geometry, core power, core power density, heat removal geometry, and heat sinks are designed to provide passive core temperatures during accidents. To limit the potential for chemical attack of the MHTGR core, the primary coolant boundary is designed to make large ingress of air and water very unlikely. Furthermore, the fuel particle coatings are highly impervious to oxidizing agents that do enter the primary coolant. The core heat generation is controlled by the large negative temperature coefficient and by insertion of control material to maintain a subcritical core configuration during the span of the accidents.

390

Conservation planning for imperiled aquatic species in an urbanizing environment  

As the global area devoted to urban uses grows, an increasing number of freshwater species will face imperilment due to urbanization effects. Management of these impacts on both private and public lands is necessary to ensure species persistence. Such management entails several hallenges: (1) development of a management policy appropriate to the stressors; (2) linking stressor levels to species population attributes; (3) forecasting the effects of alternative management policy decisions on the species, and (4) using adaptive management to adjust the policy in the future. We illustrate how these challenges were addressed under the Etowah Habitat Conservation Plan (Etowah HCP), a management plan for three federally protected fish species in Georgia, USA. The plan involved the creation of a management policy to address the impacts of the greatest stressor, stormwater runoff, as well as other stressors. Models were constructed to link population indices of the three species with a key indicator of stormwater runoff, effective impervious area (EIA). Then, models were applied to projected levels of EIA under full watershed buildout to fine-tune the parameters of the management policy. Forecasting indicated that the most sensitive species, the Etowah darter, was likely to decline by 84% in the absence of the Etowah HCP, but only 23% if the Etowah HCP were implemented. Although there was substantial uncertainty in model predictions, an adaptive management plan was established to incorporate new data and to adjust management policies as necessary.

391

Dynamics of moving interfaces in porous media: 1. Instantaneous velocity field  

Mobility changes from region to region can occur in a reservoir due to inhomogeneities in permeability and due to change in saturating fluid. In either case interfaces are present across which mobility changes abruptly. The problem of fluid flow in porous media in the presence of such interfaces is solved in this paper by using complex velocity potentials. On the interface tangential component of efflux vector is discontinuous. A vortex sheet appears on the interface and it affects the flow. Complex velocity potential in such a case can be expressed as a linear superposition of the potentials due to sources (injection wells), sinks (production wells) and due to vortex sheets along the interfaces of mobility discontinuity. Vorticity distribution on interfaces and the velocity field are inter-related. Therefore we get an integral equation for the vorticity distribution. The solution of the integral equation enables us to define the complex velocity potential completely and hence the velocity field in the flow region. It is shown that in the general case of several wells and interfaces the integral equation has a unique solution and leads to a unique flow pattern. An exact solution of the integral equation for a circular interface is obtained. An impervious no-flow boundary is an extreme case of mobility discontinuity. It is shown that its effect on the flow can be considered by an appropriate vortex sheet along it. Thus a formal solution in the form of an integral equation is obtained for instantaneous velocity distribution for arbitrary well pattern and mobility distribution.

392

Dynamics of moving interfaces in porous media: II. Pistonlike displacement  

A fluid-fluid interface is formed when oil in porous media is displaced by another fluid, say water, in a pistonlike manner. This interface is in the shape of a closed curve surrounding the injection well. The exact manner in which the size and shape of this interface changes with time depends upon the well configuration, rates and the mobility ratio. A general method for tracing the time development of such an interface is presented in this paper. A complex velocity potential for the flow at any instant is expressed by the superposition of the potentials due to the sources (injection wells), sinks (production wells) and the vortex sheet developed along the interface. An impervious no-flow boundary affects the flow and thus contributes to the velocity potential. Across this boundary the mobility ratio is infinite since the mobility in the exterior region is zero. The contribution to the complex velocity potential of such a boundary is accounted for by replacing it with the appropriate vortex sheet. The working of the method is demonstrated by implementing the calculation scheme for some simple patterns such as two spots and five spots. The results obtained are in good agreement with the known analytical results for the case of unit mobility ratio and with experimental results for other mobility ratios.

393

Green roofs and amenity space in the Pacific region  

Concrete is one of the most commonly used building materials in the world, but its use has been limited for green roofs due to its inherent porosity and ability to absorb water. Therefore, for green roof applications, regular concrete needs a membrane to waterproof it. This paper examined case histories of green roof projects and roofs with ponded water. Both types of roofs were constructed using Hydrophobic Pore Blocking Ingredient (HPI) technology that makes the concrete roof totally impervious. The design, construction and maintenance of these roofs were simplified by the elimination of membranes. The green roofs in this case study featured permanent built-in waterproofing, which cannot be punctured, torn or damaged in the construction phase, in service, or deteriorate with age. Construction savings were realized since water-proofing sub-contract jobs were eliminated. The projects also saved money due to the lower square foot cost compared to green roof membranes. Cracks were quickly repaired with a simple injection from the bottom side of the green roof deck. The waterproof concrete system presented in this paper allowed the concrete to takes on hydrophobic properties through the use of a super plasticizer. This study also compared the proposed waterproofing system to other waterproofing schemes for green roof applications. In general, the proposed system was shown to be the better technology, backed by a proven track record of over forty years. Without the design and detailing of membranes, these projects experienced reduced design time and costs. 12 figs.

394

Comprehensive, consistent and systematic approach to the mathematical modeling of PEM fuel cells  

Mathematical modeling was used in this study to advance PEM fuel cell technology and provide insight to the physical phenomena occurring within fuel cells. A comprehensive, consistent and systematic PEM fuel cell model was developed to simulate the effect of changes in design and operating conditions on performance. The fuel cell was assumed to be composed of several, co-existing phases. The conservation of mass, momentum, species, and energy were applied to each phase in the fuel cell. The interactions between the phases were modeled using a volume-averaging procedure to the conservation equations in each phase. Simplifying assumptions were applied to the general formulation in order to reduce the number of governing equations. The cell was assumed to be 2-dimensional, steady state and isothermal. In addition, the polymer electrolyte was assumed to be impervious to the gas phase and liquid water was assumed to exist only in the gas phase or polymer electrolyte. The numerical solution explained the transport phenomena within the anode and cathode gas flow channels, electrode backing layers, and catalyst layers, as well as the polymer electrolyte membrane layer. It provided information on the bulk velocity of the gas phase; the concentrations of the species within the gas phase; the potential and current density in the solid phase and polymer electrolyte; the water content in the polymer electrolyte; and the distribution of reaction rate within the catalyst layers. The study contributed to a better understanding of fuel cells which are a promising zero-emission power source for transportation applications.

395

Cross-species RNAi rescue platform in Drosophila melanogaster.  

RNAi-mediated gene knockdown in Drosophila melanogaster is a powerful method to analyze loss-of-function phenotypes both in cell culture and in vivo. However, it has also become clear that false positives caused by off-target effects are prevalent, requiring careful validation of RNAi-induced phenotypes. The most rigorous proof that an RNAi-induced phenotype is due to loss of its intended target is to rescue the phenotype by a transgene impervious to RNAi. For large-scale validations in the mouse and Caenorhabditis elegans, this has been accomplished by using bacterial artificial chromosomes (BACs) of related species. However, in Drosophila, this approach is not feasible because transformation of large BACs is inefficient. We have therefore developed a general RNAi rescue approach for Drosophila that employs Cre/loxP-mediated recombination to rapidly retrofit existing fosmid clones into rescue constructs. Retrofitted fosmid clones carry a selection marker and a phiC31 attB site, which facilitates the production of transgenic animals. Here, we describe our approach and demonstrate proof-of-principle experiments showing that D. pseudoobscura fosmids can successfully rescue RNAi-induced phenotypes in D. melanogaster, both in cell culture and in vivo. Altogether, the tools and method that we have developed provide a gold standard for validation of Drosophila RNAi experiments. PMID:19720858

396

Resilient and Corrosion-Proof Rolling Element Bearings Made from Superelastic Ni-Ti Alloys for Aerospace Mechanism Applications  

Mechanical components (bearings, gears, mechanisms) typically utilize hard materials to minimize wear and attain long life. In such components, heavily loaded contact points (e.g., meshing gear teeth, bearing ball-raceway contacts) experience high contact stresses. The combination of high hardness, heavy loads and high elastic modulus often leads to damaging contact stress. In addition, mechanical component materials, such as tool steel or silicon nitride exhibit limited recoverable strain (typically less than 1 percent). These material attributes can lead to Brinell damage (e.g., denting) particularly during transient overload events such as shock impacts that occur during the launching of space vehicles or the landing of aircraft. In this paper, a superelastic alloy, 60NiTi, is considered for rolling element bearing applications. A series of Rockwell and Brinell hardness, compressive strength, fatigue and tribology tests are conducted and reported. The combination of high hardness, moderate elastic modulus, large recoverable strain, low density, and intrinsic corrosion immunity provide a path to bearings largely impervious to shock load damage. It is anticipated that bearings and components made from alloys with such attributes can alleviate many problems encountered in advanced aerospace applications.

397

Distributed measurements of tracer response on packed bed flows using a fiberoptic probe array. Final report  

Scale-up of packed bed processes, particularly those involving chromatographic separations, is made difficult by a seemingly inevitable increase in dispersion due to packing nonuniformity. To provide a suitable characterization, the authors measured the spatial distribution of dispersion and mixing in packed beds of uniform impervious spherical glass particles by a tracer impulse technique. The key feature in this work is the use of a fiberoptic array at the exit plane to obtain a time-resolved spatially distributed response. All experiments were in the creeping flow regime. The authors used a fluorescent dye with laser excitation through the fiber terminations in the bed. The fluoresced radiation was collected through the same fibers. They analyzed the data by the use of indices of the extent of micromixing based on Danckwerts`s original degree of segregation and an additional index of structural uniformity. The computations involve a moment analysis of the individual and average probe responses. A simple model gives expressions for the indices in terms of the Peclet number and is shown to provide a useful limiting case. The computed indices are also shown to be very sensitive to adsorption of dye on the surface of the glass. However, for some of the experiments with the largest spheres using Pyrex glass, the effects of adsorption are indiscernible. This technique successfully separates the contribution of micromixed fluid to overall bed dispersion from the contribution due to the transverse variation of the flow residence time.

398

Production of polymer-plaster composite by gamma irradiation  

The estimated amount of plaster wastes in the construction industry is 45%. The reduction of this waste is of concern, because the cost of lost material and the waste management can affect the competitiveness of the company. The mixture of plaster with a particular resin generates a composite, which gives the pre-molded obtained from this mixture, special properties. In this case, the plasticity of the plaster generates pre-molded products with wealth of details. Additionally, the use of nuclear techniques for the initiation of polymerization reaction for obtaining this type of composite can eliminate the need for a heat source which is the conventional way to obtain polymerization, considerably reducing the costs of the process. As a function of the availability and the cost of styrene monomer, in the initial phase of the research test samples were prepared from plaster composites with this type of material. The test samples, composed of plaster and styrene, were irradiated in the presence of a Cs-137 (662 keV) gamma source for a period of time of two days in an air pressurized chamber. Tests of resistance to compression, tensile strength in bending and water absorption, were based on a type of experimental design, CCRD (Central Composite Rotatable Design). The percent average weight of polymer by weight of the test sample was 14.0%. The presence of a polymerized resin gives the sample qualities such as being highly impervious to water and high mechanical strength, allowing its use in the manufacture of different types of materials. (author)

399

Structural Basis for Streptogramin B Resistance in Staphylococcus aureus by Virginiamycin B Lyase  

The streptogramin combination therapy of quinupristin-dalfopristin (Synercid) is used to treat infections caused by bacterial pathogens, such as methicillin-resistant Staphylococcus aureus and vancomycin-resistant Enterococcus faecium. However, the effectiveness of this therapy is being compromised because of an increased incidence of streptogramin resistance. One of the clinically observed mechanisms of resistance is enzymatic inactivation of the type B streptogramins, such as quinupristin, by a streptogramin B lyase, i.e., virginiamycin B lyase (Vgb). The enzyme catalyzes the linearization of the cyclic antibiotic via a cleavage that requires a divalent metal ion. Here, we present crystal structures of Vgb from S. aureus in its apoenzyme form and in complex with quinupristin and Mg{sup 2+} at 1.65- and 2.8-{angstrom} resolution, respectively. The fold of the enzyme is that of a seven-bladed {beta}-propeller, although the sequence reveals no similarity to other known members of this structural family. Quinupristin binds to a large depression on the surface of the enzyme, where it predominantly forms van der Waals interactions. Validated by site-directed mutagenesis studies, a reaction mechanism is proposed in which the initial abstraction of a proton is facilitated by a Mg{sup 2+}-linked conjugated system. Analysis of the Vgb-quinupristin structure and comparison with the complex between quinupristin and its natural target, the 50S ribosomal subunit, reveals features that can be exploited for developing streptogramins that are impervious to Vgb-mediated resistance.

400

Optimization of multiple-layer microperforated panels by simulated annealing  

Sound absorption by microperforated panels (MPP) has received increasing attention the past years as an alternative to conventional porous absorbers in applications with special cleanliness and health requirements. The absorption curve of an MPP depends on four parameters: the holes diameter, the panel thickness, the perforation ratio, and the thickness of the air cavity between the panel and an impervious wall. It is possible to find a proper combination of these parameters that provides an MPP absorbing in one octave band or two, within the frequency range of interest for noise control applications. However, when a wider absorption frequency band is required, it is necessary to design multiple-layer MPP (ML-MPP). The design of an N-layers MPP depends on 4N parameters. Consequently, the tuning of an optimal ML-MPP by exhaustive search within a prescribed frequency band becomes impractical. Therefore, simulated annealing is proposed in this paper as a tool to solve the optimization problem of finding the bestcombination of the constitutive parameters of an ML-MPP providing the maximum average absorption within a prescribed frequency band.

 
 
 
 
401

Relationships Between Litter Processing and Impervious Surface Cover in Headwater Tributaries of the St. Johns River, Florida  

We investigated relationships between land-use and litter processing in 18 tributaries of the St. Johns River, Florida. The percent total impervious area (PTIA) of these catchments ranged from 0-66%. We measured mass loss and fungal biomass (as ergosterol) and associated macroinvertebrate biomass for 2 litter species (red maple [Acer rubrum] and sweetgum [Liquidambar styraciflua]). Processing rates ranged from 0.010-0.046d-1 for maple and 0.006-0.018d-1 for sweetgum. The fastest processing occurred at intermediate PTIA. Fungal biomass peaked at 24 days with the lowest biomass occurring in the low PTIA stream. Rates of processing were positively related to both mean macroinvertebrate biomass and taxa richness. Shredder biomass was not related to maple, but was negatively related to sweetgum processing. Scraper biomass peaked at intermediate PTIA, and was positively related to processing rates for both leaf species. We reduced correlated physicochemical, land-use and biological variables to several orthogonal variables using principle components analysis. Regression models based on these variables accounted for 70% of the variance in processing rates for both leaf species. Collectively, these results demonstrate that PTIA and other land-use indicators are associated with differences in stream ecosystem patterns and processes between low gradient, subtropical streams.

402

Leak test fixture and method for using same  

A method and apparatus are described which are especially useful for leak testing seams such as an end closure or joint. The test does not require an enclosed pressurized volume within the article or joint section to be leak checked. A flexible impervious membrane is disposed over an area of the seamed surfaces to be leak checked and sealed around the outer edges. A preselected vacuum is applied through an opening in the membrane to evacuate the area between the membrane and the surface being leak checked to essentially collapse the membrane to conform to the article surface or joined adjacent surfaces. A pressure differential is concentrated at the seam bounded by the membrane and only the seam experiences a pressure differential as air or helium molecules are drawn into the vacuum system through a leak in the seam. A helium detector may be placed in a vacuum exhaust line from the membrane to detect the helium. Alternatively, the vacuum system may be isolated at a preselected pressure and leaks may be detected by a subsequent pressure increase in the vacuum system.

403

Roofing panels  

A roofing panel of glass-reinforced plastic (G.R.P.) or sheet metal is stiffened by longitudinal beams on its underside to span one pitch of a pitched roof from eaves to ridge. It has an outer skin and an inner impervious liner spaced therefrom and supported on the stiffening beams so as to form a tunnel open at both ends and extending from the vicinity of the eaves to theline of the roof ridge, where vents to atmosphere are provided in the outer skin. Air is convected upwards through the tunnel due to the heating of the outer skin by radiation from the sun. At the eaves end the tunnel also has an inlet port communicating with the roof space, and a damper controls the air flowing in from outside the building and the air flowing in from the roof space. At the line of the ridge the liner meets and is sealed on the corresponding liner of a counterpart panel on the opposite pitch of the roof so as to maintain the integrity of the convection air circuit in each section of the roof. A heat exchanger located in the tunnel transfers heat from the convected air to a hot water system in the building. A hollow box girder spans the width of the panel across the beams so as to rest on the top of a flank wall of the building and can be filled with concrete to anchor the panel in position.

404

A multi-scale segmentation approach to filling gaps in Landsat ETM+ SLC-off images  

On 31 May 2003, the Landsat Enhanced Thematic Plus (ETM+) Scan Line Corrector (SLC) failed, causing the scanning pattern to exhibit wedge-shaped scan-to-scan gaps. We developed a method that uses coincident spectral data to fill the image gaps. This method uses a multi-scale segment model, derived from a previous Landsat SLC-on image (image acquired prior to the SLC failure), to guide the spectral interpolation across the gaps in SLC-off images (images acquired after the SLC failure). This paper describes the process used to generate the segment model, provides details of the gap-fill algorithm used in deriving the segment-based gap-fill product, and presents the results of the gap-fill process applied to grassland, cropland, and forest landscapes. Our results indicate this product will be useful for a wide variety of applications, including regional-scale studies, general land cover mapping (e.g. forest, urban, and grass), crop-specific mapping and monitoring, and visual assessments. Applications that need to be cautious when using pixels in the gap areas include any applications that require per-pixel accuracy, such as urban characterization or impervious surface mapping, applications that use texture to characterize landscape features, and applications that require accurate measurements of small or narrow landscape features such as roads, farmsteads, and riparian areas.

405

Distribution of polycyclic aromatic hydrocarbons in urban stormwater in Queensland, Australia  

This paper reports the distribution of Polycyclic Aromatic Hydrocarbons (PAHs) in wash-off in urban stormwater in Gold Coast, Australia. Runoff samples collected from residential, industrial and commercial sites were separated into a dissolved fraction (<0.45 {mu}m), and three particulate fractions (0.45-75 {mu}m, 75-150 {mu}m and >150 {mu}m). Patterns in the distribution of PAHs in the fractions were investigated using Principal Component Analysis. Regardless of the land use and particle size fraction characteristics, the presence of organic carbon plays a dominant role in the distribution of PAHs. The PAHs concentrations were also found to decrease with rainfall duration. Generally, the 1- and 2-year average recurrence interval rainfall events were associated with the majority of the PAHs and the wash-off was a source limiting process. In the context of stormwater quality mitigation, targeting the initial part of the rainfall event is the most effective treatment strategy. The implications of the study results for urban stormwater quality management are also discussed. - The presence of organic carbon on impervious surfaces and rainfall duration plays a dominant role in the distribution of PAHs in urban stormwater.

406

A review of stormwater management practices at petroleum product bulk terminals  

Stormwater runoff is the major source of effluent discharge from petroleum bulk terminals. The major pollutants associated with these operations are oil and grease and sometimes suspended solids. This report addresses several aspects of stormwater management at these facilities including treatment technologies, operating procedures, sampling and analytical procedures, and monitoring devices. It is based on a literature review, and several site vists conducted to document current practices. Recommendations for stormwater management include the following: contaminated and uncontaminated flows should be separated; tank water bottoms which may contain high levels of toxic components should not be discharged into the stormwater treatment system; tank farm dykes should be completely impervious and should have a holding capacity of the largest tank plus 10% of the balance of the tanks or 110% of the largest tank whichever is largest; runoff within the dyked area should be inspected prior to discharge to the treatment system; over-the-dyke drainage systems are desirable; minimum design parameters should be adhered to as underdesign is a major cause of poor performance of treatment systems; gravity collection systems are preferred over pumps; regular inspections and maintenance of separators should be instituted; and a monitoring program should be designed to determine the adequacy of environmental protection measures. 18 refs., 14 figs., 10 tabs.

407

Yorktowne Square condominium green roof retrofit and stormwater management plan  

This paper provided details of a green roof retrofit and and stormwater management plan developed for the Yorktowne Square Condominiums, a 15.3 acre site located in the highly developed county of Fairfax, Virginia. The 4700 square foot green roof system was installed as the first step to implement an effective stormwater management plan. The loss of forested areas and increased impervious surfaces in the region has meant that stormwater drainage in the region is increasingly allowing trash, sediment and other pollutants to enter the Chesapeake Bay. A lightweight EnviroTech green roof system was used to address structural concerns due to the age of the buildings. The specialized modified bitumen membrane incorporated waterproofing, root barrier, water retention and drainage systems in a single layer. The Yorktowne plan will reduce the nutrient load in the Chesapeake Bay and maintain the 40 per cent nutrient reduction goal agreed to in 1987, in addition to not using pesticides, fertilizers or herbicides. Studies have shown that the living roof has increased stormwater retention by up to 80 per cent. The roof has been the subject of television shows and newspaper articles. It was concluded that Yorktowne has become a model for residential and business communities by demonstrating how green roofs and other stormwater management designs can be implemented to improve water quality, decrease erosive stormwater, and conserve resources in the Chesapeake Bay watershed. 1 fig.

408

A covalently attached film based on poly(methacrylic acid)-capped Fe{sub 3}O{sub 4} nanoparticles  

Poly(methacrylic acid) (PMAA)-capped Fe{sub 3}O{sub 4} nanoparticles were prepared by coprecipitation with PMAA in aqueous solution. Fe{sub 3}O{sub 4} nanoparticles were further assembled with 2-nitro-N-methyl-4-diazonium-formaldehyde resin (NDR) to form a photosensitive precursor film, by virtue of the coulombic attraction between the negatively charged PMAA surface capping agent and the cationic polyelectrolyte of NDR. Covalent bonds were formed under ultraviolet irradiation. As a result of polymer capping of the nanoparticles and covalent linkage, a highly stable multilayer structure was formed. Transmission electron micrographs and selected area electron diffraction pattern revealed the Fe{sub 3}O{sub 4} nanoparticles to be approximately 8 nm in diameter with a cubic phase structure. X-Ray photoelectron spectroscopy provided evidence for the presence of Fe{sub 3}O{sub 4} nanoparticles and NDR within the ultrathin films. The UV-visible spectroscopy and atomic force microscopy measurements supported the improvement of the stability of the film, which became impervious to polar solvents when the linkages between the nanoparticles and polymer changed from ionic bonds to covalent bonds.

409

ANNUAL SUMMARY RESEARCH REPORT IN ENGINEERING FOR JULY 1, 1959-JUNE 30, 1960  

Work was continued on the determination of size and distribution of dispersed phase droplets in a pulse column. The droplet behavior and dispersed phase hold-up in Yorkmesh packing was studied with an equilibrated system of methyl isobutyl ketone and water with the ketone phase dispersed. An investigation is being made of the recovery of copper and EDTA from rare-earth ion exchange wastes. The effect of vapor properties on entrainment from bubble cap trays is being investigated. The design, construction, and operation of forced convection loops for circulating liquid metals are reported. The corrosion of 430 stainless steel and 21/2% Cr-l% Mo steel by a liquid lead- bismuth eutectic is reported. The operation of a stainless-steel sodium-cooled liquid-metal condenser is described. The effect of ten additives, including V, Mg, Zr, and Ce in inhibiting the corrosion of stainless steel by lead-bismuth eutectic is being investigated. The current process for preparation of sodium ethyl sulfate is given. Single crystals of Zn, Sn, Pb, and AgCl were grown with a simple, low cost, Bridgman-type crystallizer. Tests were performed at 800 to 1000 deg C on Y, Nb, and Ta loops, circulating Th-Mg and U-Cr eutectics. Work on the development of electromagnetic pumps is reported. A new technique was developed for applying an impervious coating of glass to yttrium. (For preceding period see IS-16.) (W.L.H.)

410

Diffusiophoretic motion of a charged spherical particle in a nanopore.  

The diffusiophoretic motion of a charged spherical particle in a nanopore, subjected to an axial electrolyte concentration gradient, is investigated using a continuum theory, which consists of the ionic mass conservation equations for the ionic concentrations, the Poisson equation for the electric potential in the solution, and the Stokes equations for the hydrodynamic field. With the concentration gradient imposed, the particle motion is induced by two different mechanisms: an electrophoresis generated by the induced electric field arising from the difference of ionic diffusivities and the double layer polarization (DLP) and a chemiphoresis by the resulting osmotic pressure gradient induced by the solute gradient in the electrical double layer around the particle. The particle diffusiophoretic velocity along the axis of the nanopore is computed as functions of the ratio of the particle size to the thickness of the electrical double layer, the ratio of the nanopore size to the particle size, the particle surface charge density, and the properties of the salt solution. The diffusiophoretic behavior of a particle comparable to the nanopore size is governed predominantly by the induced electrophoresis generated by the DLP-induced electric field, caused by the imposed concentration gradient and the double layer compression due to the presence of the impervious nanopore wall. PMID:20426445

411

Assessing the Urban Heat Island Effect Across Biomes in the Continental USA Using Landsat and MODIS  

Impervious surface area (ISA) from the Landsat TM and land surface temperature (LST) from MODIS averaged over three annual cycles (2003-2005) are used in a spatial analysis to assess the urban heat island (UHI) skin temperature amplitude and its relationship to development intensity, size, and ecological setting for 38 of the most populous cities in the continental United States. Development intensity zones based on %ISA are defined across urban gradients and used to stratify sampling of LST and NDVI. We find that ecological context significantly influences the amplitude of summer daytime UHI (urban - rural temperature difference) with the largest 8 C (average) for cities built in mixed forest biomes. For all cities ISA is the primary driver for increase in temperature explaining 70% of the total variance. Annually, urban areas are warmer than the non-urban fringe by 2.9 C, except in biomes with arid and semiarid climates. The average amplitude of the UHI is asymmetric with a 4.3 C difference in summer and 1.3 C in winter. In desert environments, UHI's point to a possible heat sink effect. Results show that the urban heat island amplitude increases with city size and is seasonally asymmetric for a large number of cities across most biomes. The implications are that for urban areas developed within forested ecosystems the summertime UHI can be quite high relative to the wintertime UHI suggesting that the residential energy consumption required for summer cooling is likely to increase with urban growth within those biomes.

412

Method of making radio frequency ion source antenna  

In the method, the radio frequency (RF) antenna is made by providing a clean coil made of copper tubing or other metal conductor, which is coated with a tacky organic binder, and then with a powdered glass frit, as by sprinkling the frit uniformly over the binder. The coil is then heated internally in an inert gas atmosphere, preferably by passing an electrical heating current along the coil. Initially, the coil is internally heated to about 200.degree. C. to boil off the water from the binder, and then to about 750.degree. C.-850.degree. C. to melt the glass frit, while also burning off the organic binder. The melted frit forms a molten glass coating on the metal coil, which is then cooled to solidify the glass, so that the metal coil is covered with a thin continuous homogeneous impervious glass coating of substantially uniform thickness. The glass coating affords complete electrical insulation and complete dielectric protection for the metal coil of the RF antenna, to withstand voltage breakdown and to prevent sputtering, while also doubling the plasma generating efficiency of the RF antenna, when energized with RF power in the vacuum chamber of an ion source for a particle accelerator or the like. The glass frit preferably contains apprxoimately 45% lead oxide.

413

The design of foundation treatment measures for dams on Karst foundations  

In order to be effective, foundation treatment measures for dams must consider the site-specific problems of individual dam sites. This article discussed foundation treatment measures for the Kavar Dam located on a karst foundation in a mountainous region near the city of Shiraz in Iran. The bedrock geology consists of a highly permeable limestone, while the overburden consists of lacustrine materials flanked by slopewash. Modern practices for treating karsitic foundations require a means of reducing seepage as well as techniques to prevent the dissolution of soluble materials in order to ensure that the foundation has sufficient capacity to resist post impoundment loadings without excessive settlement. A surficial impervious surface membrane was used to reduce the reliance on grouting. The membrane was a 120 mm thick silica fume reinforced shot-crete membrane anchored into the slope. A gypsum surcharge was installed upstream of the dam to cause water seeping through the fill to become saturated with dissolved gypsum at concentrations close to the solubility limit. 10 refs., 2 tabs., 8 figs.

414

Relation between urbanization and water quality of streams in the Austin area, Texas  

Selected water quality properties and constituents of stormflow and base flow at 18 sites on 11 streams in the Austin area, Texas, were compared to determine the relation between degree of urbanization and water quality. Sample sites were grouped into four development classifications based on percentage of impervious cover of the drainage basin. For each site and development classification, concentrations and densities of water quality properties and constituents in samples collected during base flow were compared. Except for dissolved solids, concentrations during the rising stage of stormflow generally were larger than during the falling stage. The concentrations in stormflow were larger than in base flow. For the five sites that had sufficient samples from each flow category for statistical comparisons, median concentrations in stormflow were significantly larger than in base flow. Concentrations in the rising stage were more variable and significantly larger than in the falling stage. Except for dissolved solids, median concentrations in samples collected during stormflow increased with increasing urbanization. Medians for base flow also were larger for more urban classifications. The ratio of the number of samples with detectable concentrations to total sample analyzed of 18 minor inorganic constituents and the concentrations of many of these constituents increased with increasing urbanization. Twenty-two of 42 synthetic organic compounds investigated were detected in one or more samples and were detected more frequently and in larger concentrations at sites with more urban classifications.

415

Surface modification of Ti{sub 3}Al for improved oxidation resistance  

Ti{sub 3}Al has very attractive properties such as low density and high temperature mechanical strength for elevated temperature structural applications. Its major drawback however, is poor oxidation resistance at temperatures above 600{degrees}C. Potential use of Ti{sub 3}Al in high temperature applications depends on its protection from excessive oxidation. To this effect, Al{sub 2}O{sub 3} and Al{sub 3}Ti were selected as coating materials chemically compatible with Ti{sub 3}Al. Al{sub 2}O{sub 3} acts as a protective layer on the surface of Ti{sub 3}Al and is impervious to oxygen diffusion. Al{sub 3}Ti is resistant to high temperatures and also protects the Ti{sub 3}Al substrate by forming an oxide layer consisting primarily of Al{sub 2}O{sub 3}. In this study, Al{sub 2}O{sub 3} was plasma sprayed onto the surface of Ti{sub 3}Al, while the Al{sub 3}Ti was applied by laser melting. Effectiveness of the coatings were investigated after 10 hours of cyclic oxidation.

416

System for reducing heat losses from indoor swimming pools by use of automatic covers. [Quarterly] report No. 5, January 1, 1995--March 31, 1995  

To maintain comfortable and healthful temperatures in an indoor swimming pool, heat must be continually supplied to the pool water and to fresh air-that must be brought in for ventilation. Nearly all the heat added to the water is lost by evaporation into the air above the water surface. That very moist air must then be removed and replaced with relatively dry outdoor air that requires heating during most of the year. The cost of natural gas for supplying heat in a typical institutional pool is $10,000 to $25,000 Per Year. When the pool is not being used, typically half to two-thirds of the time, evaporation and the resulting heat demands can be eliminated by placing impervious covers on the water surface. On a schedule of use such as at Skyland, the pool can be covered and evaporation suppressed about two-thirds of the time, thereby saving about ten thousand dollars per year. Determination of the actual savings achieved by use of pool covers is the principal objective of this project. The program goal is the development of the technology and tools for achieving major reductions in the nation`s waste of energy.

417

inertial orientation tracker having automatic drift compensation using an at rest sensor for tracking parts of a human body  

A self contained sensor apparatus generates a signal that corresponds to at least two of the three orientational aspects of yaw, pitch and roll of a human-scale body, relative to an external reference frame. A sensor generates first sensor signals that correspond to rotational accelerations or rates of the body about certain body axes. The sensor may be mounted to the body. Coupled to the sensor is a signal processor for generating orientation signals relative to the external reference frame that correspond to the angular rate or acceleration signals. The first sensor signals are impervious to interference from electromagnetic, acoustic, optical and mechanical sources. The sensors may be rate sensors. An integrator may integrate the rate signal over time. A drift compensator is coupled to the rate sensors and the integrator. The drift compensator may include a gravitational tilt sensor or a magnetic field sensor or both. A verifier periodically measures the orientation of the body by a means different from the drift sensitive sate sensors. The verifier may take into account characteristic features of human motion, such as stillness periods. The drift compensator may be, in part, a Kalman filter, which may utilize statistical data about human head motion.

418

Separation of Carbon Dioxide from Flue Gas Using Ion Pumping  

We are developing a new way of separating carbon dioxide from flue gas based on ionic pumping of carbonate ions dissolved in water. Instead of relying on large temperature or pressure changes to remove carbon dioxide from solvent used to absorb it from flue gas, the ion pump increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, which can be removed from the downstream side of the ion pump as a nearly pure gas. This novel approach to increasing the concentration of the extracted gas permits new approaches to treating flue gas. The slightly basic water used as the extraction medium is impervious to trace acid gases that destroy existing solvents, and no pre-separation is necessary. The simple, robust nature of the process lends itself to small separation plants. Although the energy cost of the ion pump is significant, we anticipate that it will be compete favorably with the current 35% energy penalty of chemical stripping systems in use at power plants. There is the distinct possibility that this simple method could be significantly more efficient than existing processes.

419

Priority pollutants in urban stormwater: Part 1 - Case of separate storm sewers.  

Organic and mineral pollutants have become part of today's urban environment. During a rain event, stormwater quality as well as the corresponding contaminant loads is affected by both atmospheric deposition and the various types of impervious surfaces (roads, rooftops, parking lots etc.) on which runoff occurs. This study provides results on stormwater pollution in Paris and its suburbs from three separate storm sewers (n=20 samples). These results show that the stormwater had been contaminated by 55 chemical substances out of the 88 investigated. A particular attention was given to stormwater particle contamination. Concentrations are provided for: metals, PAHs, PCBs, organotins, alkylphenols, phthalates, pesticides, and VOCs. Our findings are among the first available in the literature since the relevant analyses were all conducted on both the particulate (P) and dissolved (D) phases. For most substances, particles from the three storm sewers were more heavily contaminated than dredged sediments and settleable particles from the Seine River. As a consequence of this finding, the release of untreated stormwater discharges may impact the receiving waters and contribute to sediment contamination. PMID:22209279

420

Phosphorus export across an urban to rural gradient in the Chesapeake Bay watershed  

Watershed export of phosphorus (P) from anthropogenic sources has contributed to eutrophication in freshwater and coastal ecosystems. We explore impacts of watershed urbanization on the magnitude and export flow distribution of P along an urban-rural gradient in eight watersheds monitored as part of the Baltimore Ecosystem Study Long-Term Ecological Research site. Exports of soluble reactive phosphorus (SRP) and total P (TP) were lowest in small watersheds with forest and low-density residential land use (2.8-3.1 kg-1 km-2 yr-1). In contrast, SRP and TP exports increased with watershed impervious surface coverage and reached highest values in a small urban watershed (24.5-83.7 kg-1 km-2 yr-1). Along the Gwynns Falls, a larger watershed with mixed land use, the greatest proportion of SRP (68%) and TP (75%) was contributed from the lower watershed, where urban areas were the dominant land use. Load duration curve analysis showed that increasing urbanization in watersheds was associated with shifts in P export to high-flow conditions (>2 mm d-1). SRP concentrations during low-flow conditions at urban headwater sites were highest during summer and lowest during winter. This seasonal pattern was consistent with sediment incubation experiments showing that SRP release from sediments was temperature dependent. Our results suggest that shifts in streamflow and alterations in water temperatures owing to urbanization and climate can influence stream water P concentrations and P export from urban watersheds.

 
 
 
 
421

Temporal mixture analysis for estimating impervious surface area from multi-temporal MODIS NDVI data in Japan  

As a proxy measure of the human ecological footprint, impervious surface area (ISA) has recently become a key concept in the field of urban remote sensing, with a focus on estimation of the ISA at a city-scale by using Landsat-style satellite images. However, ISA estimation is also in demand in disciplines such as the environmental assessment and policy making at a national scale. This paper proposes a new method for estimating the ISA fraction in Japan based on a temporal mixture analysis (TMA) technique. The required inputs for the proposed method are rearranged MODIS NDVI time-series datasets at the temporal stable zone (i.e., the first to the sixth largest NDVI values in a year). Three ISA distribution maps obtained from Landsat-5 TM data were used as reference maps to evaluate the performance of the proposed method. The results showed that the proposed TMA-based method achieved a large reduction in the effects of endmember variability compared with the previous methods (e.g., SMA and NSMA), and thus the new method has promising accuracy for estimating ISA in Japan. The overall root mean square error (RMSE) of the proposed method was 8.7%, with a coefficient of determination of 0.86, and there was no obvious underestimation or overestimation for the whole ISA range.

422

Cost reduction in absorption chillers: Phase 2  

A research program at Brookhaven National Laboratory (BNL) has addressed the possibility of dramatically lowering the first costs of absorption chillers through lowered material intensity and the use of lower cost materials, primarily in the heat exchangers which make up the bulk of the operating components of these systems. This must be done while retaining the best performance characteristics available today, a gross design point coefficient of performance (COP) of 1.3 and a net design (seasonal) average COP of 1.0 (0.90) in a directly fired, double effect unit. We have investigated several possible routes to these goals, and here report on these findings, focusing on the areas that appear most promising. The candidate technologies include the use of polymer film heat exchangers in several applications, the use of thin strips of new, corrosion resistant alloys to replace thicker, less impervious metals in applications exposed to gas flames, and copper or cupro-nickel foils in contact with system water. The use of such materials is only possible in the context of new heat exchanger and system designs, which are also discussed. To lend focus, we have concentrated on a directly fired double effect system providing capacity only. If successful, these techniques will also find wide applicability in heat pumps, cogeneration systems, solar cooling, heat recovery and chemical process heat transfer. 46 refs., 24 figs., 22 tabs.

423

Diagenesis and porosity development of a subcropped Mississippian carbonate oil reservoir, an example from the Alida beds of the Pheasant Rump Pool, southeast Saskatchewan  

The complex diagenetic history of the Mississippian carbonates of the Williston Basin in southeastern Saskatchewan was described. An example from the Alida beds in the Pheasant Rump Pool was presented. The Pheasant Rump is a subcrop Alida pool which has produced more than 50,000 cubic metres of medium gravity oil in the first 18 months since its discovery in 1996. The pool is delineated with the vertical discovery well at 15-15-10-6W2 and six horizontal wells drilled up to 1997. Trapping of oil at the subcrop is accentuated by a subdued northeast trending hill on the paleotopography. Important byproducts of initial diagenesis were the formation of syntaxial calcite cement in the grainstones and matrix dolomite in the pack/wackestone. Subsequent dolomitization and anhydrization are associated with the pre-Watrous erosion surface and created the impervious `caprock`. Significant alteration of the carbonates and development of effective secondary porosity resulted from late burial diagenesis involving dedolomitization in the pack/wackestone, and the dissolution of anhydrite cement in the grainstone. 40 refs., 2 tabs., 11 figs.

424

A high-resolution sensor based on tri-aural perception  

By virtue of their low cost and simplicity, ultrasonic sensors are widely used in time-of-flight ranging systems. Unfortunately, correctly interpreting the readings from such sensors proves to be very difficult. The authors present a high-resolution sensor composed of three ultrasonic sensors: one transmitter/receiver and two extra receivers, which allows a significant improvement in the information-extraction process. With this sensor they can determine the position, both distance and bearing, of all isolated objects in the field of view ([approx]25[degree]) using information contained in one single snapshot of a moderately complex scene. It is further shown that, within limits, the sensor system can also discriminate between different types of reflectors, based on their radius of curvature. In particular, the sensor can discriminate between walls and edges. These results are all based on the determination of the arrival times of the echoes present at the three receivers. In this respect, too, the authors sensor differs from the conventional ultrasonic sensor, which processes only the first echo to arrive at the receiver. A noise model, explaining the measured variations of the arrival times, is used to derive limits on the resolution of the results provided by the sensor. Furthermore, based on this model it is shown that, to a large extent, the results of the sensor are impervious to measurement variations common to all three receivers. Finally, this sensor is used in a realistic environment and the results are compared with those obtained from a conventional time-of-flight sensor.

425

Computer-aided exploration with THEMISED software: pressure, maturation analyses, and migration studies in various geological environments, Rifts (North Sea), Intracratonic basins (Paris), Tertiary deltas (Indonesia)  

The THEMISED software describes on a geologic cross section the progressive compaction of the sediments due to water expulsion, the formation of hydrocarbons as a result of temperature increase with burial, their expulsion from the source rocks, and their migration as a separate flow within the carrier beds toward the traps. This tool points out the main geological factors leading to hydrocarbon accumulation (oil and/or gas) in relatively quiet tectonic settings. It gives an objective geological interpretation on the basis of the geological hypotheses made by the explorationist. In the North Sea basin, the writers show how the difference of behavior of the various source rocks during maturation may affect the distribution and kind of hydrocarbon accumulation. In addition, the pressure buildup within the impervious shaly seal and within the reservoir may lead to hydrocarbon dismigration, because of the seal leakage, or hydrocarbon accumulation per descensum within the reservoirs. In some intracratonic basins like the Paris basin, the hydrodynamic conditions may perturb hydrocarbon migration. The timing of hydrocarbon expulsion is also crucial when considering the timing of traps' structuring. In thick, recent sedimentary basins such as the Mahakam Tertiary delta (Indonesia), the rapid sedimentation causes a specific pressure buildup and a perturbation of the heat flow. The possibilities of carrier bed connections within the delta also influence the pressure regime. As a consequence, the distribution of hydrocarbon accumulations is linked both with the source beds' relations to the carrier beds and the general pressure and temperature history of the basin.

426

Development of statistical linear regression model for metals from transportation land uses.  

The transportation landuses possessing impervious surfaces such as highways, parking lots, roads, and bridges were recognized as the highly polluted non-point sources (NPSs) in the urban areas. Lots of pollutants from urban transportation are accumulating on the paved surfaces during dry periods and are washed-off during a storm. In Korea, the identification and monitoring of NPSs still represent a great challenge. Since 2004, the Ministry of Environment (MOE) has been engaged in several researches and monitoring to develop stormwater management policies and treatment systems for future implementation. The data over 131 storm events during May 2004 to September 2008 at eleven sites were analyzed to identify correlation relationships between particulates and metals, and to develop simple linear regression (SLR) model to estimate event mean concentration (EMC). Results indicate that there was no significant relationship between metals and TSS EMC. However, the SLR estimation models although not providing useful results are valuable indicators of high uncertainties that NPS pollution possess. Therefore, long term monitoring employing proper methods and precise statistical analysis of the data should be undertaken to eliminate these uncertainties. PMID:19542656

427

Determination of first flush criteria using dynamic EMCs (event mean concentrations) on highway stormwater runoff.  

Recently the Ministry of Environment in Korea has developed the total maximum daily load program in accordance with the target pollutant and its concentration goal on four major large rivers. Since the program is largely related to regional development, nonpoint source control is both important and topical. Of the various nonpoint sources, highways are stormwater intensive land uses since they are impervious and have high pollutant mass emissions from vehicular activity. The event mean concentration (EMC) is useful in estimating the loadings to receiving water bodies. However, the EMC does not provide information on the time varying changes in pollutant concentration or mass emissions, which are often important for best management practice development, or understanding shock loads. Therefore, in this study a new concept, the dynamic EMC determination method, will be introduced to clearly verify the relationship between EMC and the first flush effect. Three monitoring sites in Daejeon metropolitan city areas were equipped with an automatic rainfall gauge and a flow meter for accumulating the data such as rainfall and runoff flow. The dynamic EMC method was applied to more than 17 events, and the improved first flush criteria were determined on the ranges of storm duration and accumulated rainfall. PMID:17410842

428

The Henry Ford Production System: reduction of surgical pathology in-process misidentification defects by bar code-specified work process standardization.  

Misidentification defects are a potential patient safety issue in medicine, including in the surgical pathology laboratory. In addressing the Joint Commission's national patient safety goal of accurate patient and specimen identification, we focused our lens internally on our own laboratory processes, with measurement tools designed to identify potential misidentification defects and their root causes. Based on this knowledge, aligned with our lean work culture in the Henry Ford Production System, we redesigned our surgical pathology laboratory workflow with simplified connections and pathways reinforced by a bar code technology innovation to specify and standardize work processes. We also adopted just-in-time prestain slide labeling with solvent-impervious, bar-coded slide labels at the microtome station, eliminating the loop-back pathway of poststain, batch slide matching, and labeling with adhesive paper labels. These changes have enabled us to dramatically reduce the overall misidentification case rate by approximately 62% with an approximate 95% reduction in the more common histologic slide misidentification defects while increasing technical throughput at the histology microtomy station by 125%. PMID:19289582

429

Impact of permafrost development on groundwater flow patterns: a numerical study considering freezing cycles on a two-dimensional vertical cut through a generic river-plain system  

The impact of glaciation cycles on groundwater flow was studied within the framework of nuclear waste storage in underground geological formations. The eastern section of the Paris Basin (a layered aquifer with impervious/pervious alternations) in France was considered for the last 120 ka. Cold periods corresponded with arid climates. The issue of talik development below water bodies was addressed. These unfrozen zones can maintain open pathways for aquifer recharge. Transient thermal evolution was simulated on a small-scale generic unit of the landscape including a "river" and "plain". Coupled thermo-hydraulic modeling and simplified conductive heat transfer were considered for a broad range of scenarios. The results showed that when considering the current limited river dimensions and purely conductive heat transfer, taliks are expected to close within a few centuries. However, including coupled advection for flows from the river to the plain (probably pertinent for the eastern Paris Basin aquifer recharge zones) strongly delays talik closure (millennium scale). The impact on regional underground flows is expected to vary from a complete stop of recharge to a reduced recharge, corresponding to the talik zones. Consequences for future modeling approaches of the Paris Basin are discussed.

430

Near Infrared Spectroscopy during pediatric cardiac surgery: errors and pitfalls.  

As a result of improvements in early outcomes, long-term neurologicalal outcomes are becoming a major issue in pediatric cardiac surgery. The mechanisms of brain injury are numerous, but a vast majority of injuries are impervious to therapy and only a few are modifiable. The quality of perfusion during cardiac surgery is a modifiable factor and cerebral monitoring during bypass is the way to assess the quality of intra-operative cerebral perfusion. Near infrared spectroscopy (NIRS), as a diagnostic tool, has gained in popularity within the perfusion community. However, NIRS is becoming the standard of care before its scientific validation. This manuscript relates four clinical cases, demonstrating the limitations of NIRS monitoring during pediatric cardiac surgery as well as uncertainties about the interpretation of the recorded values. The clinical relevance of cerebral oxymetry is needed before the use of NIRS as a decision making tool. Multimodal brain monitoring with NIRS, trans-cranial Doppler and electroencephalogram are currently under way in several pediatric centers. The benefit of this time-consuming and expensive monitoring system has yet to be demonstrated. PMID:21593082

431

Hydrologic Behavior of Vegetated Roofs  

Control of stormwater runoff from impervious surfaces is an important national goal because of disruptions to downstream ecosystems, water users, and property owners caused by increased flows and degraded quality. One method for reducing stormwater is the use of vegetated (green) roofs, which efficiently detain and retain stormwater when compared to conventional (black) roofs. A paired green roof-black roof test plot was constructed at the University of Georgia and monitored between November 2003 and November 2004 for the green roof's effectiveness in reducing stormwater flows. Stormwater mitigation performance was monitored for 31 precipitation events, which ranged in depth from 0.28 to 8.43 cm. Green roof precipitation retention decreased with precipitation depth; ranging from just under 90 percent for small storms ( 7.62 cm). Runoff from the green roof was delayed; average runoff lag times increased from 17.0 minutes for the black roof to 34.9 minutes for the green roof, an average increase of 17.9 minutes. Precipitation and runoff data were used to estimate the green roof curve number, CN = 86. This information can be used in hydrologic models for developing stormwater mitigation programs.

432

Modeling the historical water cycle of the Copenhagen Area 1850-2003  

The paper describes a set of modelling utilities (a root-zone model, a grid-distribution tool, and a modified Modflow-2000 model) that can be used to simulate the water cycle of a city in terms of root-zone water balance, water supply, wastewater, storm runoff, groundwater flow, streamflow, and the interactions between these subsystems. The utilities are used to simulate the water cycle in the Copenhagen area (976 km2) during the period 1850–2003. Long-term time series of hydraulic head, streamflow, and inflow to sewage works have been used to manually calibrate the model parameters. We used a step-wise calibration strategy, using different parts of the data in the various steps, to calibrate hydrogeological parameters, storm runoff parameters, and parameters governing the interactions between groundwater and leaky pipe systems, respectively. Simulations indicate that present rates of groundwater leakage into streams, lakes, and wetlands constitute 60% of pre-urbanization levels due to massive groundwater extraction. However, the current problems of groundwater shortages and streamflow depletion would have been far worse, if precipitation had not increased by 20% since 1850. Model simulations indicate that urbanization has lowered current groundwater recharge due to the establishment of impervious areas and due to negligible contributions from leaky pipe systems. This is opposite to the reported general tendency of enhanced recharge due to urbanization. However, current recharge rates within Copenhagen are simulated to be 20% higher than prior to urbanization, which is attributed to the increase in precipitation during the study period.

433

[Responses of wetland water quality to influence the strengthness of urbanization in Nanjing, China].  

28 typical wetlands were selected to monitor the contaminants in water monthly, that influenced by urbanization in different scales. On the other hand, the land use types such as impervious area and forest area in the catchments of urban wetlands were analyzed by GIS and landscape ecology. And then the effects of urbanization index (UEI) was employed to reveal the relationship between urbanization level and water quality in Xianlin New City of Nanjing. Results indicated that: (1) the seasonal variations of water quality showed that water quality in summer was worse than those in other seasons, and the water quality in winter was good. However there were no significant differences between the spring and the autumn. (2) the relationship was significant between urbanization level and water quality, and the water quality tended to be getting worse when the urbanization level was getting higher. The concentrations of TP, TN, NH(4+)-N, and Chla were 0.27, 1.07, 0.15 and 17.94 mg x L(-1) respectively in the high urbanization (HU) level wetland while the concentrations were 0.12, 0.56, 0.12 and 4.85 mg x L(-1) in the low urbanization (LW) level wetland. (3) there was a threshold between UEI and the water quality. On the whole, the water quality would get worse quickly when the value of UEI exceeded 2.2. PMID:23002599

434

Evaluation and comparison of the IRS-P6 and the landsat sensors  

The Indian Remote Sensing Satellite (IRS-P6), also called ResourceSat-1, was launched in a polar sun-synchronous orbit on October 17, 2003. It carries three sensors: the highresolution Linear Imaging Self-Scanner (LISS-IV), the mediumresolution Linear Imaging Self-Scanner (LISS-III), and the Advanced Wide-Field Sensor (AWiFS). These three sensors provide images of different resolutions and coverage. To understand the absolute radiometric calibration accuracy of IRS-P6 AWiFS and LISS-III sensors, image pairs from these sensors were compared to images from the Landsat-5 Thematic Mapper (TM) and Landsat-7 Enhanced TM Plus (ETM+) sensors. The approach involves calibration of surface observations based on image statistics from areas observed nearly simultaneously by the two sensors. This paper also evaluated the viability of data from these nextgeneration imagers for use in creating three National Land Cover Dataset (NLCD) products: land cover, percent tree canopy, and percent impervious surface. Individual products were consistent with previous studies but had slightly lower overall accuracies as compared to data from the Landsat sensors.

435

Electrical resistance sensors record spring flow timing, Grand Canyon, Arizona  

Springs along the south rim of the Grand Canyon, Arizona, are important ecological and cultural resources in Grand Canyon National Park and are discharge points for regional and local aquifers of the Coconino Plateau. This study evaluated the applicability of electrical resistance (ER) sensors for measuring diffuse, low-stage (sensors were used to conduct a baseline survey of spring flow timing at eight sites in three spring-fed tributaries in Grand Canyon. Sensors were attached to a nearly vertical rock wall at a spring outlet and were installed in alluvial and bedrock channels. Spring flow timing data inferred by the ER sensors were consistent with observations during site visits, with flow events recorded with collocated streamflow gauging stations and with local precipitation gauges. ER sensors were able to distinguish the presence of flow along nearly vertical rock surfaces with flow depths between 0.3 and 1.0 cm. Laboratory experiments confirmed the ability of the sensors to monitor the timing of diffuse flow on impervious surfaces. A comparison of flow patterns along the stream reaches and at springs identified the timing and location of perennial and intermittent flow, and periods of increased evapotranspiration.

436

Experimental comparison of bone revascularization by musculocutaneous and cutaneous flaps  

Revascularization, one of the major components of bone healing, was examined in an experimental model. The radioactive microsphere technique demonstrated that after 4 weeks beneath a musculocutaneous flap, isolated bone segments had significant blood flow, whereas bone beneath a cutaneous flap did not. The muscle flap bone had a blood flow approximately half that of normal control bone. The muscle of the musculocutaneous flap had a blood flow three times that of the skin of the cutaneous flap. The bipedicle cutaneous flap used was designed to have a healthy blood supply, and at 4 weeks it had a blood flow twice that of control skin. Despite this, there was essentially no demonstrable blood flow in the cutaneous flap bone segments at 4 weeks. Only 3 of 17 bone segments underneath cutaneous flaps showed medullary vascularization, whereas 10 of 11 muscle flap bones did. All bone segments underneath muscle flaps showed osteoblasts and osteoclasts at 4 weeks; neither were seen in the cutaneous bone segments. The process of revascularization occurred through an intact cortex and penetrated into the cancellous bone. Because the bone segments were surrounded by an impervious barrier except for one cortical surface, the cellular activity seen is attributed to revascularization by the overlying flap. In this model, a muscle flap was superior to a cutaneous flap in revascularizing isolated bone segments at 4 weeks. This was documented by blood flow measured by the radioactive microsphere technique and by bone histology.

437

Oil containment boom  

An oil containment boom is described comprising a sufficient number of sections to enable the boom to surround a ship in a spaced relationship thereto, a flexible joint interconnecting adjacent sections in a manner enabling the boom to be stored with the sections folded, one on another, each section including an oil impervious, flexible barrier in sheet form, an inflatable tubular chamber closed at its ends and extending lengthwise of the barrier to establish upper and lower portions thereof, each flexible joint including a rod to which the ends of adjacent barriers are sealed, top and bottom self supporting battens extending lengthwise of the top and bottom margins of the barrier portions and pivotally connected to corresponding ends of the adjacent rods, the bottom battens of a weight such that they serve as ballasting battens and the top battens relatively light in weight, means operable to inflate the chambers, means operable to interconnect the end sections to complete the boom, and means operable to immobilize the joint between each two sections with a predetermined angular relationship between the adjacent ends of the ballasting battens whereby the boom, when in place, has a relatively stable form.

438

Observation and removal of daily quasi-periodic components in soil radon data  

We report (quasi) periodic oscillations observed in soil radon emanation data especially during summer period. Soil radon has been continuously monitored in the Marmara region of Turkey over the past nine years to reveal possible relationships between soil radon and seismic activities. This long term monitoring has clearly demonstrated that soil radon concentrations are affected by various parameters such as seasonal and daily changes in atmospheric parameters (temperature, pressure, precipitation). Sometimes, soil temperature variations as well as barometric pressure and precipitation may dominantly influence the soil radon concentration; leading to seemingly complex radon time series. One may need to remove such components for better analysis of the possible relationships between soil ra...

439

Prominent effect of soil network heterogeneity on microbial invasion  

Using a network representation for real soil samples and mathematical models for microbial spread, we show that the structural heterogeneity of the soil habitat may have a very significant influence on the size of microbial invasions of the soil pore space. In particular, neglecting the soil structural heterogeneity may lead to a substantial underestimation of microbial invasion. Such effects are explained in terms of a crucial interplay between heterogeneity in microbial spread and heterogeneity in the topology of soil networks. The main influence of network topology on invasion is linked to the existence of long channels in soil networks that may act as bridges for transmission of microorganisms between distant parts of soil.

440

Development of Soil Crusts Under Simulated Rainfall and Crust Formation on a Loess Soil as Influenced by Polyacrylamide  

This study evaluated the morphological characteristics and dynamic variation in characteristics of soil crust and identified the relationships between soil crust and splash erosion under simulated rainfall. The effect of polyacrylamide (PAM) on soil aggregate stabilization and crust formation was also investigated. A laboratory rainfall simulation experiment was carried out using soil sample slices. The slices were examined under a polarized light microscopy and a scanning electron microscope (SEM). The results revealed that the soil crusts were thin and were characterized by a greater density, higher shear strength, finer porosity, and lower saturated hydraulic conductivity than the underlying soil. Two types of crusts, i.e., structural and depositional crusts, were observed. Soil texture...

 
 
 
 
441

Catchment-scale spatial variability of soil properties and implications on site-specific soil management in northern Ethiopia  

Scientific information on the spatial variability and distribution of soil properties is critical for understanding ecosystem processes and designing sustainable soil-crop and environmental management decisions. However, little is known on spatial distribution and variability of soil properties at catchment-scale in many tropical developing regions including Ethiopia. This study aims to examine catchment-scale spatial dependence and variability of soil properties using classical and geostatistical methods to indicate for site-specific soil management in the Mai-Negus catchment, northern Ethiopia. Soil samples were collected based on sampling zones identified by the knowledge of local farmers and field observation and analyzed following standard laboratory procedures for selected soil prope...

442

The impact of soil organism composition and activated carbon on grass-legume competition  

Belowground mechanisms involved in plant competition are still poorly understood. Since plant species are differently affected by soil organisms, changes in soil community composition might affect interspecific competition with consequences for plant community structure. We studied whether soil community composition affects competition between the grass Holcus lanatus L. and the legume Lotus corniculatus L. We