WorldWideScience
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Natural radionuclides in drinking water in Argentina  

International Nuclear Information System (INIS)

As part of the national survey to evaluate natural radioactivity in the environment, concentration levels of natural uranium and "2"2"6Ra have been analyzed in over 300 drinking water samples taken from different locations in Argentina. "2"2"6Ra was determined by "2"2"2Rn emanation and liquid scintillation counting, and natural uranium by a fluorimetric procedure. Values ranging from 0.03 to 24 #mu#g.l"-"1 of natural uranium and from 0.06 to 50 #mu#g.l"-"1, were measured on drinking water samples taken from tap water systems and private wells, respectively. Concentrations up to 15 mBq.l"-"1 and to 22 mBq.l"-"1 of "2"2"6Ra were found in drinking water samples taken from tap water systems and private wells, respectively. These values are compared with the reference values accepted for drinking water. Based on the water intake rate, the age distribution and the measured concentrations, an annual collective ...

2000-05-01

2

Sistema Federal de Areas Protegidas y Eco-regiones de Argentina (SIFAP)  

Science.gov (United States)

Este sistema de informacion provee al usuarion con un listado de areas protegidas argentinas ordenado por nombre, por provincia, ... ...

3

The Cordoba and Wolsung projects: a progress report  

International Nuclear Information System (INIS)

Progress on construction of the Cordoba reactor in Argentina and the Wolsung reactor in Korea is described. (E.C.B.).

1977-06-01

4

Pro-market educational governance: is Argentina a black swan?  

British Library Electronic Table of Contents (United Kingdom)

In this article we explore ways in which pro-market discourses have been interpreted in policy initiatives in Argentina since the 1970s. Our argument is that even though pro-market discourses have guided reforms in many aspects of public policies in Argentina, the arena of education has overall been resistant to taking them up. The first part of the article analyses the origins of a strong discursive and symbolic link between notions of 'public education' and 'National State-centred education' in Argentina and then examines the development of private education in that country. The second section analyses economic change in Argentina and describes the influence that pro-market ideologies had on policies of the military dictatorship of the 1970s. Third, we present reforms implemented during ...

2011-01-01

5

Rio Negro Floodplain, Patagonia, Argentina - NASA Earth Observatory  

Science.gov (United States)

Feb 15, 2010 ... This astronaut photo from January 4, 2010, shows meander scars and oxbow lakes in the floodplain of the Rio Negro in South America.

7

Miguel Sanchez Pena (1925-2009) organizer of the space activities in Argentina  

British Library Electronic Table of Contents (United Kingdom)

One of the most important and active pioneers of the space activities in Argentina was Miguel Sanchez Pena, an aeronautical engineer and an officer of the Argentine Air Force. Sanchez Pena was the organizer of Argentina's governmental space program in the 1970s and part of the 80s, and contributed immeasurably to the Nation's sounding rocket program. Born in Mendoza, Argentina in 1925, Sanchez Pena attended the Military Aviation School (Escuela de Aviacion Militar) in Cordoba, and later the Air Force Engineering School. Graduated as an engineer in 1959 he was sent to the University of Michigan in the United States to complete his graduate studies earning a Masters of Science degree in Aerospace Engineering. There he had the opportunity to study with several future NASA astronauts such as T...

2011-01-01

8

Malaria transmission in two localities in north-western Argentina  

UK PubMed Central (United Kingdom)

BackgroundMalaria is one of the most important tropical diseases that affects people globally. The influence of environmental conditions in the patterns of temporal distribution...Full Text Available

9

A new species of Demidospermus (Platyhelminthes, Monogenea, Ancyrocephalidae) from the catfish Parapimelodus valenciennis in Samboromb?n Bay, Argentina  

British Library Electronic Table of Contents (United Kingdom)

Demidospermus annulus sp. nov. (Platyhelminthes, Monogenea, Ancyrocephalidae) is described from the gills of the catfish Parapimelodus valenciennis L?tken collected in Samboromb?n Bay, Argentina. The new species differs from all congeneric species mainly by the structure of the accessory piece of the male copulatory organ, the sclerotized ring-shaped vaginal aperture and the dorsal bar articulation.

2011-01-01

10

Morphotypes of Varroa destructor collected in Apis mellifera colonies from different geographic locations of Argentina  

British Library Electronic Table of Contents (United Kingdom)

Parasites display considerable phenotypic plasticity in life-history traits such as, body size. Varroa destructor is an ectoparasitic mite of the western honey bee Apis mellifera. Several studies have reported that in V. destructor, there is a wide phenotypic plasticity within a population of mites. However, it is unknown if there are morphologic variations in V. destructor populations affecting different A. mellifera populations. A morphometric study of V. destructor populations was conducted to provide information concerned to the relationships among parasite populations found in different geographic locations from A. mellifera colonies of Argentina. The hypothesis tested was different morphotypes of V. destructor populations parasitizing different A. mellifera populations from Argentina...

2009-01-01

11

Cordoba and Wolsung Projects: A Progress Report.  

Science.gov (United States)

The Cordoba and Wolsung projects mark the entry into the international sales arena of the standardized Canadian 600 MWe CANDU-PHW reactor design. The Cordoba station experienced a setback in the early stages when severe inflation in Argentina led to a ren...

1977-01-01

12

Biotypology, Endocrinology, and Sterilization: The Practice of Eugenics in the Treatment of Argentinian Women during the 1930s  

UK PubMed Central (United Kingdom)

SUMMARYThis article looks at medical approaches to women’s fertility in Argentina in the 1930s and explores the ways in which eugenics encouraged the reproduction of the...Full Text Available

2007-01-01

13

Paravortex panopea n. sp. (Platyhelminthes: Rhabdocoela) on clams from the northern Patagonian coast, Argentina: pathogeny and specificity  

British Library Electronic Table of Contents (United Kingdom)

Summary During a histopathological survey of the geoduck, Panopea abbreviata (Hiatellidae), and the razor clam, Ensis macha (Pharidae), in northern Patagonian gulfs (Argentina), turbellarian worms were found in the intestine lumen. In this work, we described a new species of Paravortex (Platyhelminthes, Graffillidae). We collected the hosts by scuba diving and dissected alive for studying the turbellarians. In this new species, the pharynx continues in a short esophagus and the latter in a saccular intestine. Gravid specimens have from 2 to 8 twin embryos in the parenchyma. A short penis papilla arises from the seminal vesicle and the gonopore presents a strong sphincter. This species resembled P. nicolli Szidat, 1965, which was described paraziting Mytilus edulis platensis in Buenos Aires...

2011-01-01

14

Fusion of Imaging and Inertial Sensors for Navigation  

Science.gov (United States)

... 2.5.6 Development of Observation Equations . . . . . 25 2.6 Inertial Navigation Error Model . . . . . ... 2 , as expected. 2.6 Inertial Navigation Error Model ...

2006-09-01

15

Technical and economical analysis methodology for small power distribution systems; Metodo de analisis tecnico-economico de pequenas obras de distribucion  

Energy Technology Data Exchange (ETDEWEB)

This paper propose to show the technical and economic aspects of the implementation of small power distribution systems in small rural properties in some locations of Argentina. This paper presents a concrete methodology, with a rational cost composition and introduces project variables. 4 figs.

1986-12-31

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Nuclear fuel cycle. V. 2  

International Nuclear Information System (INIS)

Nuclear fuel cycle information in some countries that develop, supply or use nuclear energy is presented. Data about Argentina, Australia, Belgium, Netherlands, Italy, Denmarmark, Norway, Sweden, Switzerland, Finland, Spain and India are included. The information is presented in a tree-like graphic way. (C.S.A.).

1979-06-08

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Wastenet

... The structure comprises piled foundations supporting a steel frame, and is clad in both masonry and rainscreen cladding systems. The hotel is adjacent to the recently redeveloped bus station in the centre of Norwich. Related Services Structural Design Go View all Services Find Projects Sector All Sectors Buildings & Infrastructure Environment Natural Resources Transportation Sub Sector All Sub-Sectors Country All Countries Angola Antigua and Barbuda Argentina ...

18

NAME=\\  

Wastenet

... Further complications resulted from the requirement to use existing piled foundations and columns which had originally been designed to accommodate a six-storey office block. The hotel bedroom configurations and planning constraints were different from thos Related Services Structural Design Go View all Services Find Projects Sector All Sectors Buildings & Infrastructure Environment Natural Resources Transportation Sub Sector All Sub-Sectors Country All Countries Angola Antigua and Barbuda Argentina Australia Azerbaijan ...

19

INL Advanced Radiotherapy Research Program Annual Report 2004  

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the activities and major accomplishments for the Idaho National Laboratory Advanced Radiotherapy Research Program for calendar year 2004. Topics covered include boron analysis in biological samples, computational dosimetry and treatment planning software development, medical neutron source development and characterization, and collaborative dosimetry studies at the RA-1 facility in Buenos Aires, Argentina.

2005-06-01

20

Nuclear power plant support activities in reactors chemistry at CNEA  

International Nuclear Information System (INIS)

Argentina has two operating PHWR nuclear power plants. Atucha I NPP is a pressure vessel type heavy water reactor of 360 MW e with 25 years of operation and Embalse NPP is a pressure tube type CANDU-600 reactor of 640 MW e. Atucha II, a third plant of 600 MW e of the pressure vessel type similar to Atucha I, is being constructed. NASA (Nucleoelectrica Argentina S.A.) currently operates both nuclear power plants. The National Atomic Energy Commission (Comision Nacional de Energia Atomica - CNEA) provides operational support to the plants, including research and development assistance, and actual technical services and maintenance work in different areas. The Chemistry Department, formerly the Reactor Chemistry Department has carried out project and support activities to the plants during the past 20 years. The aim of this work is to describe the present organization and the activities in reactor chemistry of the Chemistry Department. In ...

1999-10-15

21

Production of "9"9Tc"m radiopharmaceuticals for brain, heart and kidney imaging. Final report of a co-ordinated research programme 1991-1994  

International Nuclear Information System (INIS)

The report contains highlights of the achievements of the IAEA Co-ordinated Research programme on Evaluation on the Use of Bulk Reagents for the Production of "9"9Tc_m Radiopharmaceutical and Kits, the participants' summary reports (Argentina, Chile, Greece, India, Indonesia, Japan, Malaysia, Portugal, Russian Federation, Thailand, Uruguay, United States of America), recommended product protocols for five compounds and the participants' recommendations regarding continued support and further directions of co-ordinated research work. Refs, 6 figs, 8 tabs, 6 schemes.

1990-06-24

22

Canadian nuclear review  

International Nuclear Information System (INIS)

Progress in the construction of Candu reactors at home and abroad is surveyed. Some A.E.C.L. research projects are also mentioned. During 1979, Candu reactors again showed their superior capacity factors, four of them being among the ten most reliable reactors in the world. Progress in construction at Pickering B, Bruce B, Point Lepreau, Gentilly-2, Darlington, Wolsung (Korea), Cordoba (Argentina), and Cernavoda (Romania) is recounted. In 1979, it was unfortunately necessary to replace installed steam generators at Pickering B, Bruce B, Point Lepreau and Gentilly-2. At Wolsung, the reactor was pre-assembled before installation, which is a new technique. (N.D.H.).

1979-01-01

23

Evolution of a bifunctional enzyme: 6-phosphofructo-2-kinase/fructose-2,6-bisphosphatase.  

UK PubMed Central (United Kingdom)

The bifunctional rat liver enzyme 6-phosphofructo-2-kinase/fructose-2,6-bisphosphatase (ATP:D-fructose-6-phosphate 2-phosphotransferase/D-fructose-2,6-bisphosphate 2-phosphohydrolase, EC 2.7.1.105/EC...Full Text Available

1989-12-01

24

Effect of pentachlorophenol on the activation of 2,6-dinitrotoluene to genotoxic urinary metabolites in CD-1 mice: A comparison of G1 enzyme activities and urine mutagenicity  

Energy Technology Data Exchange (ETDEWEB)

2,6-Dinitrotoluene (2,6-DNT) and pentachlorophenol (PCP) are used for industrial purposes and are found in the environment as hazardous contaminants. Because concurrent exposure to both compounds can occur, it is of interest to determine if organochlorine compounds potentiate the effect of nitroaromatic chemicals. A significant increase in mutagenicity was observed in urines from mice treated with 2,6-DNT alone and in combination with PCP. By week 4, mice that received both 2,6-DNT and PCP excreted urine that was more mutagenic than that from animals which received only 2,6-DNT. At weeks 2 and 4, mice were sacrificed and intestinal enzyme activities (nitroreductase, azo reductase, {beta}-glucuronidase, dechlorinase, and dehydrochlorinase) were quantitated. The enhanced genotoxicity observed in urines from 2,6-DNT/PCP-treated mice coincided with a decrease in ...

1991-01-01

25

The endophytic fungi from wheat (Triticum aestivum L.)  

British Library Electronic Table of Contents (United Kingdom)

In order to study the species composition of endophytes from wheat healthy plants in Buenos Aires Province (Argentina) and to determine their infection frequencies from leaves, stems, glumes and grains, wheat plants were collected from five cultivars at five growth stages from crop emergence to harvest. A total of 1,750 plant segments (leaves, stems, glumes and grains) were processed from the five wheat cultivars at five growth stages, and 722 isolates of endophytic fungi recovered were identified as 30 fungal genera. Alternaria alternata, Cladosporium herbarum, Epicoccum nigrum, Cryptococcus sp., Rhodotorula rubra, Penicillium sp. and Fusarium graminearum were the fungi that showed the highest colonization frequency (CF%) in all the tissues and organs analysed. The number of taxa isolated...

2007-01-01

26

The contribution of ear photosynthesis to grain filling in bread wheat (Triticum aestivum L.)  

British Library Electronic Table of Contents (United Kingdom)

The contribution of ear photosynthesis to grain filling in wheat (Triticum aestivum L.) is not well known. The main objective of this work was to evaluate this contribution through three different experimental approaches: (1) ear photosynthesis was reduced by removing awns or shading the ears (in combination with a defoliation treatment), (2) grain weight per ear was compared in an 'all shaded' crop versus plants where only the vegetative parts were shaded ('ear emerging'), and (3) ear photosynthesis was reduced with DCMU (3-(3,4-dichlorophenyl)-1,1-dimethylurea), a specific inhibitor of photosystem II. In field experiments in La Plata (Argentina), cultivars Klein Escudo and BioINTA 3000 were subjected to awn removal and ear shading treatments, with or without severe defoliation, and to 'a...

2010-01-01

27

Landscape Structural Complexity of High-Mountain Polylepis australis Forests: A New Aspect of Restoration Goals  

British Library Electronic Table of Contents (United Kingdom)

Forest restoration efforts should aim at creating landscapes with a balanced array of forest stands at varying successional stages, thus providing habitat for a wealth of species and multiple ecosystem services. In most high-mountain ecosystems of South America, long-term livestock rearing activities that include fires, browsing, and trampling have delayed or stopped forest succession resulting in simplified landscapes. To determine appropriate restoration goals for Polylepis australis mountain forests of Central Argentina, we established 146 plots of 900 m2 plots throughout five river basins with different historic livestock stocking rates. In each plot, we measured tree heights, canopy cover, estimated age of oldest tree, volume of standing and fallen dead wood, fern cover, and abundance...

2011-01-01

28

Bioactivity of propolis from different geographical origins on Varroa destructor (Acari: Varroidae)  

British Library Electronic Table of Contents (United Kingdom)

Varroa destructor is an ectoparasitic mite that affects colonies of honey bee Apis mellifera worldwide. In the last years, substances of botanical origin have emerged as natural alternative acaricides to diminish the population levels of the mite. In the present work, the bioactivity of propolis from different geographical locations of Pampean region from Argentina on V. destructor was evaluated. Fourteen propolis samples were organoleptic and physicochemically characterized and, by means topical applications, their activity was tested on mites. All propolis had a homogeneous composition and the bioactivity levels against mites were comparable among the different propolis samples. The percentage of mites killed by the treatments ranged between 60.5% and 90% after 30?s of exposure. Thus, V....

2010-01-01

29

BOOKMARKS:  

Wastenet

2. 1.3. 1.4. ...2.1. 2.2 . 2.3. ...2.4. 2.5. 2.6. 2.7.Global air temperature change Natural disasters linked to climate

30

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Wastenet

1 ?3?4.1 ? ?4.2 ...4.3 ? ?5.1?5.2 ? ?6.1 ?? ?6.2 ? ...8?10 ?? ?11 ? ?? ?12 ??13

31

Reaction of ethyl azidoformate with acenaphthylene: isolation and structure of an acenaphthylene-pyridinium-2,6 betaine adduct  

International Nuclear Information System (INIS)

Ethyl azidoformate reacts, on thermolysis with acenaphthylene, to give a 1:2 adduct involving sequential aziridine formation, ring-opening to a 1,3-dipolar pyridinium-2,6-betaine, and trapping of the dipole with acenaphthylene. The structure of the adduct was confirmed by X-ray crystallography.

32

Molar extinction coefficients in aqueous solutions of some alkaline earth chlorides  

International Nuclear Information System (INIS)

Molar extinction coefficients for the solid solutes in aqueous solutions of some alkaline earth chlorides such as MgCl_2.6H_2O, CaCl_2, SrCl_2.6H_2O and BaCl_2.2H_2O have been determined at 81, 356, 511, 662, 1173 and 1332 keV energies in different concentration using the narrow beam transmission methods. (author)

1999-12-21

33

A biogenic approach to the treatment of uranium mill effluents  

International Nuclear Information System (INIS)

A biogenic method for the treatment of uranium mill effluents containing toxic amounts of Mn"2 and "2"2"6Ra is described. The acidic tailings from the uranium mills are generally neutralised with lime and the overflow waters from tailing ponds at the discharge point, consisting of Mn"2"+ (>10 mg l"-"1) and "2"2"6Ra (> 3.0 pCi l"-"1), need further treatment before disposing off to the public utility. Arthrobacter sp. has been used for precipitating Mn"2"+ as hydrous oxide of manganes (MnO_2#centre dot#nH_2O) and along with "2"2"6Ra also gets precipitated. The effluent after bacterial treatment consisted of Mn"2"+ and "2"2"6Ra within the range of allowed concentrations as per the I.C.R.P. (International Committee of Radiological Protection) and MPC (maximum permissible concentration) standards (Mn"2"+ 95% of "2"2"6Ra could be precipitated using this method. (author). 11 refs.; ...

34

The role of CNEA as a TSO in the enhancement of nuclear safety  

International Nuclear Information System (INIS)

Argentina's National Atomic Energy Commission (CNEA) was created in 1950 to promote the development of the pacific technological applications of nuclear energy within the country. Since its very beginning CNEA considered that nuclear development is possible only if it is supported by broad scientific knowledge and accompanied by an adequate progress of the needed technological capacities. Thus, an important investment was done to educate and prepare professionals to form a technical staff that had broad backgrounds; as a consequence, excellent educational and training Institutes were created, and a number of researchers, engineers and technologists were educated. Since the early days, CNEA has paid special attention to crucial aspects such as radiological protection and nuclear safety. CNEA has had a role in contributing to the national growth of Argentine scientific and technical sector. This role has been necessary not only to provide the basis for the ...

2007-08-01

35

CANDU 6 operating experience  

International Nuclear Information System (INIS)

The CAMDU 6 reactor has an international reputation as one of the world's best performing and safe reactors. CANDU 6 reactors are consistently ranked in the world's top 10 for annual and lifetime performance. Six CANDU 6 units are currently in operation in four continents; in Quebec, New Brunswick, South Korea, Argentina and Romania. There are another two CANDU 6 units currently under construction at wolsong, in Korea which ore scheduled to go into service in 1998 and 1999 respectively. A second CANDU 6 unit is currently being considered for Romania. The construction of two CANDU 6 units at Qinshan, in China, is now underway. The performance of the four first-generation CANDU 6 plants, which have now been in service for 15 years, continue to show very good performance, with capacity factors on average since in-service of over 85%. The annual capacity factor of 10.21% during 1997 has been achieved by the Wolsong-1 unit in South Korea. These high capacity factors ...

1998-03-23

36

Argentinian doctors accused of spreading AIDS.  

Science.gov (United States)

The provincial ministry of health has taken over a dialysis center in La Plata, Argentina, following the discovery that at least 20 of the clinic's 34 regular patients have been infected with the human immunodeficiency virus (HIV). Catheters of the clinic's dialysis machines were found to be contaminated with HIV. The 5 physicians associated with the Centro Modelo de Dialisis have been discharged for negligence. 20 of the regular patients also contracted hepatitis C. Argentinian law stipulates that filters for the same patient must be changed after 4 times and prohibits the use of the same vessel to administer medication to more than 1 patient. Testimony from nurses at the La Plata clinic revealed that filters were reused for several patients and basic sanitary procedures were not followed. In 1990, 33 kidney disease patients at a dialysis center in Cordoba became infected with HIV and it was discovered that filters had been used up to 8 times for different ...

1993-09-01

37

USGS Fact Sheet 040-02  

Science.gov (United States)

and streambed sediment samples 2-6. Graphs showing: 2. Cesium-137 profile in HOE core 3. PAH trends in Lake Houston cores 4. DDE trends in Lake Houston cores 5. Trends in six trace...

2011-08-27

38

STUDY OF SYSTEMS AND COST/PERFORMANCE METHODOLOGIES FOR ...  

Science.gov (United States)

of first unit and learning curve (LC) factor for hardware, ETR, and WTR recurring cost respectively. ...... 105 FORMAT (12,A6,F4.2,6X.F7 0,F6 OF7 0.12. 2012) ...

39

Practical, Stereoselective Synthesis of Cecropia Juvenile Hormone  

UK PubMed Central (United Kingdom)

The high-yield, stereoselective conversion of geraniol (3,7-dimethyl-trans-2,6-octadien-1-ol) to the insect juvenile hormone, methyl 12,14-dihomojuvenate (methyl cis-10-epoxy-3,11-dimethyl-7-ethyl-trans,...Full Text Available

1971-06-01

40

Crystal structure of the human adenovirus proteinase with its 11 amino acid cofactor.  

UK PubMed Central (United Kingdom)

The three-dimensional structure of the human adenovirus-2 proteinase complexed with its 11 amino acid cofactor, pVIc, was determined at 2.6 A resolution by X-ray crystallographic analysis. The fold...Full Text Available

1996-04-15

42

Calculation of cosmic ray antiproton-proton ratio  

Energy Technology Data Exchange (ETDEWEB)

Cross section parameterizations for antiproton production in pp collisions are used to predict the antiproton/proton ratio resulting from a flux of cosmic protons with energy spectral index of 2.6 interacting with a 5 gm/cm/sup 2/ column density of H. (GHT)

1980-01-01

43

Collectivity at N=40 in neutron-rich "6"4Cr  

International Nuclear Information System (INIS)

"9Be-induced inelastic scattering of "6"2","6"4","6"6Fe and "6"0","6"2","6"4Cr was performed at intermediate beam energies. Excited states in "6"4Cr were measured for the first time. Energies and population patterns of excited states in these neutron-rich Fe and Cr nuclei are compared and interpreted in the framework of large-scale shell-model calculations in different model spaces. Evidence for increased collectivity and for distinct structural changes between the neighboring Fe and Cr isotopic chains near N=40 is presented.

2010-05-01

44

Soil to plant transfer of "2"3"8U, "2"2"6Ra and "2"3"2Th on a uranium mining-impacted soil from southeastern China  

International Nuclear Information System (INIS)

Both soil and plant samples of nine different plant species grown in soils from southeastern China contaminated with uranium mine tailings were analyzed for the plant uptake and translocation of "2"3"8U, "2"2"6Ra and "2"3"2Th. Substantial differences were observed in the soil-plant transfer factor (TF) among these radionuclides and plant species. Lupine (Lupinus albus) exhibited the highest uptake of "2"3"8U (TF value of 3.7x10"-"2), while Chinese mustard (Brassica chinensis) had the least (0.5x10"-"2). However, in the case of "2"2"6Ra and "2"3"2Th, the highest TFs were observed for white clover (Trifolium pratense) (3.4x10"-"2) and ryegrass (Lolium perenne) (2.1x10"-"3), respectively. "2"3"2Th in the tailings/soil mixture was less available for plant uptake than "2"2"6Ra or "2"3"8U, and this was especially evident for Chinese mustard and corn (Zea mays). The root/shoot (R/S) ratios obtained for different plants and ...

1000-01-01

45

Isolation and determination of "9"0Sr, "2"2"6Ra, "2"2"8Ra and "2"1"0Pb in food  

International Nuclear Information System (INIS)

A procedure is described for the isolation and determination of "9"0Sr, "2"2"6Ra, "2"2"8Ra and "2"1"0Pb in food. These nuclides are highly radiotoxic, above all for babies and children. Samples are dry ashed, alkali metals are removed as carbonates. Separation from other matrix ions and separation of Ra, Sr and Pb can be achieved with a column of Sr-Spec, an immobilized crown ether. For activity measurements membrane filters with SrSO_4, Ba(Ra)SO_4 and PbS are prepared. Ra is determined by gamma-spectrometry, "9"0Sr and "2"1"0Pb are determined by low-level-betacounting. The determination limits are 10 mBq/kg for "9"0Sr and "2"1"0Pb and 50 mBq/kg for "2"2"6Ra and "2"2"8Ra. The procedure is useful for all kinds of foodstuff. (orig.).

46

Distribution of "2"3"0Th in milling wastes from the Zirovski vrh uranium mine (Slovenia), and its radioecological implications  

International Nuclear Information System (INIS)

Thorium-230, together with "2"3"8U and "2"2"6Ra, was determined (mainly by #gamma#-spectrometry) in samples from the waste piles at Borst and Jazbec in the vicinity of the former uranium mine at Zirovski vrh, Slovenia. Activity (and in the case of uranium, also mass) balances for these nuclides were constructed for the overall operation of the mine and yellow cake plant, using experimental data and known data on ore and uranium production, and nuclide emissions to the environment. All the "2"2"6Ra resulting from ore exploitation is presently contained in the Borst tailings pile. However, because of the very high content of "2"3"0Th in red mud deposited at Jazbec, where 60% of this nuclide is found, the majority of "2"2"6Ra will be found at the Jazbec pile in the future, due to its ingrowth from "2"3"0Th over the next few thousand years. (Author).

47

Spin transition in octahedral metal complexes containing tetraazamacrocyclic ligands  

British Library Electronic Table of Contents (United Kingdom)

This review focusses on spin crossover complexes with octahedral metal ions which are bound to a tetraazamacrocyclic ligand and additionally either to two monodentate ligands or to one bidentate ligand. Macrocyclic ligands with a sufficiently large ring size prefer to coordinate to metal ions in an equatorial fashion yielding trans-octahedral coordination environments. In contrast, twelve-membered tetraazamacrocycles with high steric rigidity, such as 2,11-diaza[3.3](2,6)pyridinophanes or 2,11-dithia[3.3](2,6)pyridinophane, are prone to form cis-octahedral complexes. While the electronic and the steric properties of the coordinated tetraazamacrocycle in trans-octahedral complexes are very likely responsible for the paucity of observed spin transitions, the cis-octahedral coordination mode ...

2009-01-01

48

Spectroscopy of "2"5Al and "2"6","2"7","2"8P using high-energy stripping reactions  

International Nuclear Information System (INIS)

We report here results of an application of single-nucleon stripping reactions at high energies (65 MeV/u) in inverse kinematics to obtain spectroscopic factors. From measurements of the partial cross-sections for ground and excited states in residual nuclei formed in one-proton stripping reactions, single particle orbits and occupancies of light nuclei have been studied in the s-d shell. Single proton stripping cross-sections of "2"5Al and "2"6","2"7","2"8P on a Be target have been measured using the S800 spectrograph and the NaI(Tl) array at the NSCL. These results indicate that this technique may provide a general tool for the intermediate energy range analogous to transfer (pick-up) reactions at low-energy.

1998-12-21

49

Reactive blending of poly(ethylene 2,6-naphthalate) and Vectra A  

British Library Electronic Table of Contents (United Kingdom)

In situ composites based on poly(ethylene 2,6-naphthalate) (PEN) and a thermotropic liquid crystal polymer (Vectra A950) were prepared by melt blending under different processing conditions. Thermal behaviour, mechanical and physical properties and morphology of the blends were investigated. The DSC analysis indicates that, as expected, Vectra enhances the crystallization process of PEN. Moreover, mechanical and thermal tests evidence the significant role of 20wt% Vectra on increasing the material performances; tensile properties, coupled with SEM, show that strength and modulus of PEN are significantly improved when Vectra domains are long and continuous fibrils. The overall results can be attributed to the compatibilisation of the system induced by the mixing conditions that affect the e...

2009-01-01

50

Near-threshold {eta}-meson production in the dd{yields}He{eta} reaction  

Energy Technology Data Exchange (ETDEWEB)

The dd{yields}{sup 4}He{eta} reaction has been investigated near threshold using the ANKE facility at COSY-Juelich. Both total and differential cross-sections have been measured at two excess energies, Q=2.6 MeV and 7.7 MeV, with a subthreshold measurement being undertaken at Q=-2.6 MeV to study the physical background. While consistent with isotropy at the lower energy, the angular distribution reveals a pronounced anisotropy at the higher one, indicating the presence of higher partial waves. Options for the decomposition into partial amplitudes and their consequences for the determination of the s-wave {eta}{alpha} scattering length are discussed. (orig.)

2005-12-01

51

Geochemical fingerprints by activation analysis of tephra layers in Lake Van sediments, Turkey  

International Nuclear Information System (INIS)

We discuss geochemical and sedimentological characteristics of 12 tephra layers, intercalated within the finely laminated sediments of Lake Van. Within the about 15 kyr long sediment record studied, volcanic activity concentrated in the periods 2.6-7.2 and 11.9-12.9 kyr B.P. Concentrations of 25 elements provide the geochemical fingerprint of each tephra layer and allow comparison to literature values of potential source volcanoes such as Mts. Nemrut and Suephan. The youngest two tephra layers (and probably also the other three ashes from the 2.6-7.2 kyr B.P. eruptions) originate from the Nemrut volcano. The source of the older tephra (11.9-12.9 kyr B.P.), however, remains unidentified.

2011-07-01

52

Complexation of nitrogen and sulphur donor Schiff's base ligand to Cr(III) and Ni(II) metal ions: Synthesis, spectroscopic and antipathogenic studies  

British Library Electronic Table of Contents (United Kingdom)

2,6-Diacetyl pyridine based ligand was synthesized by the reaction of 2,6-diacetyl pyridine with thiocarbohydrazide in presence of acetic acid. The coordination compounds with Cr(III) and Ni(II) metal ions having [Cr(L)X]X2 and [Ni(L)X]X compositions (where L=ligand and X=NO3^-, Cl^- and CH3COO^-) were synthesized and characterized by physicochemical and spectral studies. The studies like elemental analyses, molar conductance measurements, magnetic susceptibility measurements, IR, UV-Vis, NMR, mass and EPR reveal that the complexes are octahedral. The compounds were examined against the pathogenic fungal and bacterial strains like Alternaria brassicae, Aspergillus niger, Fusarium oxysporum, Xanthomonas compestris and Pseudomonas aeruginosa. A. niger causes the diseases Apergillosis and Oto...

2011-01-01

53

The role of the state oil company in Latin America  

International Nuclear Information System (INIS)

The role of the Latin American state oil companies (LASOCs) in establishing national industries to fuel economic development is discussed. LASOCs are represented internationally in an organization called ARPEL (Asistencia Reciproca Petrolera Estatal Latinoamericana) which is aimed to foster interchange, cooperation, and mutual assistance among its 20 member companies, as well as to promote economic integration of Latin America through its petroleum sector. State oil companies in Latin America date from 1922, when the oldest LASOC was created in Argentina. LASOCs are responsible for ca 80% of petroleum activities in Latin America. As of 1990, Latin American oil reserves, including gas liquids, amounted to ca 122 billion bbl or 12.2% of the world total. Regional oil production averaged 7.4 million bbl/d in 1990. Refining capacity is ca 7.7 million bbl/d, of which 80% is operated directly by LASOCs. Natural gas reserves are 7.3 trillion m"3, ca 6% of the world total, ...

54

Instrumentation for monitoring and control of cycle chemistry for the steam-water circuits of fossil-fired and combined-cycle power plants  

Energy Technology Data Exchange (ETDEWEB)

A guidance document on the instrumentation for monitoring and control of cycle chemistry for the steam-water circuits of fossil-fired and combined-cycle power plants was developed within the IAPWS Power Cycle Chemistry Working Group. This technical guidance document has been authorized by the International Association for the Properties of Water and Steam (IAPWS) at its meeting in Doorwerth, The Netherlands, 6-11 September, 2009, for issue by its Secretariat. The members of the IAPWS are: Britain and Ireland, Canada, the Czech Republic, Denmark, France, Germany, Greece, Japan, Russia, and the United States of America, and the associate members Argentina and Brazil, Italy, and Switzerland. In order to achieve suitable chemical conditions in steam-water circuits it is essential to establish reliable monitoring of key parameters on every plant. This enables the demonstration of operation within cycle chemistry targets, and alerts the operators to the need to take ...

2009-10-15

55

Engineering masterpieces : from the Andes to Siberia, Canadian talent is in demand  

Energy Technology Data Exchange (ETDEWEB)

Canadian oilfields are a prime breeding ground for talent, technology and industrial management. This paper described how Canadian talent was recognized in 2001 for three major projects which included a cold-ocean production platform in the Sea of Okhotsk in Siberia, a mountain pipeline project in South America, and an in-situ underground extraction technology in the oilsands of Alberta. The cold-ocean production platform project was recruited by Sakhalin Energy Investment Co., an international consortium originally led by Marathon Oil Co which is now led by Royal Dutch Shell. The oil production platform is stationed 16 kilometres offshore of Sakhalin Island in the Sea of Okhotsk. Sakhalin Energy bought and converted the Molikpaq, an innovative platform made in the 1980s for the Beaufort Sea by Gulf Canada Resources Ltd. The second project included Calgary's Hydroconsult EN3 Services Ltd. which was responsible for the construction of the 940-km GasAtacama 24-inch diameter ...

2001-03-05

56

The Protein Kinase SnRK2.6 Mediates the Regulation of Sucrose Metabolism and Plant Growth in Arabidopsis[W][OA]  

UK PubMed Central (United Kingdom)

In higher plants, three subfamilies of sucrose nonfermenting-1 (Snf1)-related protein kinases have evolved. While the Snf1-related protein kinase 1 (SnRK1) subfamily has been shown to share pivotal...Full Text Available

2010-05-01

57

Tachyons  

International Nuclear Information System (INIS)

An interpretation of effects connected with the possible existence of tachyons, i.e. particles moving at a velocity higher than the velocity of light, is given. It is proposed that if there exist in nature particles with super-luminal velocities then they are likely to be found in domains of extremely small space-time intervals #DELTA#xx10"-"1"6cm and #DELTA#t<10"-"2"6s, in which processes involving a violation of spatial and temporal parities are playing an important role.

58

Synthesis of non-steroidal anti-inflammatory drug analogues for selective studies on the COX-II enzyme  

International Nuclear Information System (INIS)

Synthesis of the azido substituted non-steroidal anti-inflammatory drug 2-(2,6-dichloroanilino)phenylacetic acid and isotope labeling of this compound have been performed and are described. Initial evaluation of the binding ability and photoreactivity indicates that this compound has potential for photoaffinity labeling as well as enzyme selectivity studies. (author).

59

Radial distribution of bonded fission gas in mixed carbide fuel pins  

International Nuclear Information System (INIS)

The fission gas xenon bonded in bubbles, in pore, and in the lattice of mixed carbide fuels is measured by electron-probe microanalysis. Radial xenon distribution and release curves are determined and are calibrated by gas chromatography of the bonded fission gas and by burnup analysis in the respective pin sections of the irradiation experiments FR2 6A and 6C, Mol 11/K 2, and DFR 330/1. The results are correlated to the microstructure of the fuel, bonding medium, temperature, and burnup. (Auth.).

1979-01-01

60

Isotope effects on the metabolism and pulmonary toxicity of butylated hydroxytoluene in mice by deuteration of the 4-methyl group  

Energy Technology Data Exchange (ETDEWEB)

A comparative test in mice for pulmonary toxicity between butylated hydroxytoluene (2,6-di-tert.-butyl-4-methylphenol, BHT) and 2,6-di-tert.-butyl-4-(alpha, alpha, alpha-2H3)methylphenol (BHT-d3) showed a significantly lower toxic potency of the latter. The rate of in vitro BHT metabolism to 2,6-di-tert.-butyl-4-methylene-2,5-cyclohexadienone (BHT-QM) was slowed by deuterating BHT in the 4-methyl group. On the other hand, the rate of in vitro metabolism to 2,6-di-tert.-butyl-4-hydroxy-4-methyl-2,5-cyclohexadienone (BHT-OH) was increased with the deuteration. A similar isotope effect of the deuterium substitution on the in vivo metabolic rates of BHT was observed. These observations support the concept that the lung damage caused by BHT is mediated by BHT-QM. The pulmonary toxicity of 2-tert.-butyl-4-ethylphenol (4-EP) and their deuterated analogs was also compared. 2-tert.-Butyl-4-(1,1-2H2)ethylphenol ...

1983-06-30

61

DECOVALEX - Mathematical models of coupled T-H-M processes for nuclear waste repositories. Report of phase III  

Energy Technology Data Exchange (ETDEWEB)

This report presents the methodologies and results of the field/laboratory experiments and mathematical modeling defined for the phase III of the project. Results from test cases 2-6 are given in separate chapters of the report (which have been indexed separately), and the last chapter discusses the lessons learned from the three phases of the DECOVALEX project.

1995-12-01

62

Bragg curve spectroscopy detector for particle identification  

International Nuclear Information System (INIS)

The operation principle, construction and characteristics of the Bragg curve spectroscopy detector (BCS detector) are described. The electric field of the BCS detector is parallel to the particle trajectories. The detector was tested by 8.78 MeV and 6.02 MeV #alpha# particles from a ThC-ThC's source. The energy resolutions are 1.5% and 2.6% respectively for two groups of #alpha# particles, and the charge resolution is 2.7%. Further test experiments with heavy ions will be arranged.

63

Bilateral adrenocortical carcinoma in a patient with multiple endocrine neoplasia type 1 (MEN1) and a novel mutation in the MEN1 gene  

UK PubMed Central (United Kingdom)

The incidence of adrenal involvement in MEN1 syndrome has been reported between 9 and 45%, while the incidence of adrenocortical carcinoma (ACC) in MEN1 patients has been reported between 2.6 and 6%....Full Text Available

64

Effect of D-amino acids at Asp"2"3 and Ser"2"6 residues on the conformational preference of A#beta#_2_0_-_2_9 peptides  

International Nuclear Information System (INIS)

The effects of D-amino acids at Asp"2"3 and Ser"2"6 residues on the conformational preference of #beta#-amyloid (A#beta#) peptide fragment (A#beta#_2_0_-_2_9) have been studied using different spectroscopic techniques, namely vibrational circular dichroism (VCD), vibrational absorption, and electronic circular dichroism. To study the structure of the A#beta#_2_0_-_2_9, [D-Asp"2"3]A#beta#_2_0_-_2_9, and [D-Ser"2"6]A#beta#_2_0_-_2_9 peptides under different conditions, the spectra were measured in 10 mM acetate buffer (pH 3) and in 2,2,2-trifluoroethanol (TFE). The spectroscopic results indicated that at pH 3, A#beta#_2_0_-_2_9 peptide takes random coil with #beta#-turn structure, while [D-Ser"2"6]A#beta#_2_0_-_2_9 peptide adopts significant amount of polyproline II (PPII) type structure along with #beta#-turn contribution and D-Asp-substituted peptide ([D-Asp"2"3]A#beta#_2_0_-_2_9) adopts predominantly PPII type structure. ...

2005-09-30

65

Natural gas integration in Latin America: end of a dream?  

International Nuclear Information System (INIS)

Throughout the 1990's to year 2000, energy integration, and particularly natural gas integration, was seen as a major goal in the southern cone of South America. The regional perspective for energy was related to an even more challenging objective - Latin American economic integration, which was quickly moving forward by the constitution of Mercosur, the free trade zone built by Argentina, Brazil, Uruguay and Paraguay, and also having Bolivia and Chile as special partners. Mercosur was getting stronger and becoming a successful political project. Trade conflicts existed, but they were considered normal and nobody would disagree about the viability of Mercosur. By the beginning of the 21. century, the economic integration process in South America was already advancing timidly as compared to the impetus from the beginning of 1990's. Mercosur started facing complex and almost insurmountable challenges after the numerous global financial crises (from 1998 to 2003) had ...

66

Radiolysis and photolysis of crystalline 2,4,6-triazido-3,5-dichloropyridine: generation of quintet dinitrenes  

International Nuclear Information System (INIS)

Low-temperature #gamma# radiolysis and photolysis of crystalline 2,4,6-triazido-3,5-dichloropyridine (TAP) were studied by means of the ESR technique. It was found that the long-term irradiation of TAP at 77 K leads to the appearance of characteristic signals of quintet 2,6-dinitreno-4-azido-3,5-dichloropyridine and 2,4-dinitreno-6-azido-3,5-dichloropyridine; the radiation-chemical yield was 0.035 and 0.012 molecule/100 eV, respectively. The photolysis of crystalline 2,4,6-triazido-3,5-dichloropyridine proceeded less effectively, producing only quintet 2,6 dinitrene with a quantum yield of #approx#4.5 x 10"-"4. The study showed that the generation of high-spin nitrenes via radiolysis of crystalline azides is much superior to the photochemical technique in efficiency and may be of practical importance for the preparation of magnetically active organic materials

67

Pulsed-plasma nitriding of a niobium-alloyed PM tool steel  

Energy Technology Data Exchange (ETDEWEB)

The aim of this work is to describe the processes during plasma nitriding of Nb-containing, powder metallurgy prepared (PM) tool steel. PM steel was studied containing 2.5% C, 3.3% Si, 6.2% Cr, 2.2% Mo, 2.6% V, 2.6% Nb and 1.0% W, produced by melt atomization and hot isostatic pressing. The hardened and tempered steel was plasma nitrided at temperatures ranging from 470 to 530 deg. C. The nitriding time was 30-180 min. Optical microscopy, electron microscopy, XRD, EDS, WDS and hardness measurements were used to study the steel's properties, microstructure, phases and chemical composition. The nitriding temperature of 470 deg. C was found to be unsuitable for practical use because the layers prepared at this temperature were non-uniform. The compound layer formed by M{sub 2,3}(C,N) and M{sub 4}N was found after nitriding at temperatures of 500 and 530 deg. C for at least 60 min. The effect of niobium on the formation of this layer was ...

2005-02-25

68

Pulsed-plasma nitriding of a niobium-alloyed PM tool steel  

International Nuclear Information System (INIS)

The aim of this work is to describe the processes during plasma nitriding of Nb-containing, powder metallurgy prepared (PM) tool steel. PM steel was studied containing 2.5% C, 3.3% Si, 6.2% Cr, 2.2% Mo, 2.6% V, 2.6% Nb and 1.0% W, produced by melt atomization and hot isostatic pressing. The hardened and tempered steel was plasma nitrided at temperatures ranging from 470 to 530 deg. C. The nitriding time was 30-180 min. Optical microscopy, electron microscopy, XRD, EDS, WDS and hardness measurements were used to study the steel's properties, microstructure, phases and chemical composition. The nitriding temperature of 470 deg. C was found to be unsuitable for practical use because the layers prepared at this temperature were non-uniform. The compound layer formed by M_2_,_3(C,N) and M_4N was found after nitriding at temperatures of 500 and 530 deg. C for at least 60 min. The effect of niobium on the formation of this layer was studied.

2005-02-25

69

Alpha particle spectroscopic strengths for levels populated in the "2"0 "2"1 "2"2Ne("6Li, d)"2"4 "2"5 "2"6Mg reactions  

International Nuclear Information System (INIS)

The "2"0 "2"1 "2"2Ne("6Li, d)"2"4 "2"5 "2"6Mg reactions have been studied at a bombarding energy of 32 MeV. Alpha particle spectroscopic strengths have been extracted for several low-lying levels by a finite-range distorted wave analysis. These are compared with theoretical predictions. The agreement is good both for relative strengths to different levels within a nucleus and for ground-state strengths relative to the "1"6O("6Li, d) result. Strengths calculated using eigenfunctions determined in large shell-model computations agree well with pure symmetry SU(3) predictions. The "2"1Ne("6Li, d) angular distributions for transitions to the ground-state band of "2"5Mg are characterized by the lower of the two L-transfers allowed for populating each level. For the 3"+(5.24 MeV) unnatural parity level in "2"4Mg, a two-step calculation gives a better account of the data than does a compound nuclear calculation. (Auth.).

70

Radioiodinated 2-nitrobenzyl carbamates as bioreductive alkylating agents for tissue hypoxia  

Energy Technology Data Exchange (ETDEWEB)

Three N-methylcarbamates of iodonitrobenzyl alcohols (4-iodo-2-nitrobenzyl alcohol 2, 5-iodo-2-nitrobenzyl alcohol 3 and 4-iodo-2,6-dinitrobenzyl alcohol 4) bearing [[sup 125]I] have been prepared and characterized for their lipophilicity, their reduction potentials and the in vivo lability of the radioiodine in healthy mice. Based upon these results, 2 and 4 were tested in tumor-bearing mice showing limited uptake of radioactivity in tumours and a tumor-to-blood ratio of less than 1. Consequently these particular carbamates are not satisfactory as hypoxia imaging agents. (author).

1993-05-01

71

Preoperative MR-guided localization of suspicious breast lesions; MR-gesteuerte praeoperative Drahtmarkierung unklarer Mammalaesionen  

Energy Technology Data Exchange (ETDEWEB)

Purpose: Small suspicious breast lesions that are only visible at MR imaging were preoperatively marked with a hook wire under MR-guidance to allow the removal of the lesion with tissue-sparing surgery. Method: In all patients the suspicious lesions were marked preoperatively under MR guidance with a hook wire using a commercially available stereotactic device. Interventions were performed with MR guidance on a 1.0 T and on a 1.5 T system. Results: In 19 patients 22 lesions were localized. One lesion was missed and removed in a second procedure. The mean duration for localization was 66{+-}20 min (range 38-119 min). In two patients two lesions were localized. The mean deviation of the wire tip to the lesion was 2,0{+-}2,6 mm. In this series, 6 of 22 lesions were malignant. The mean diameter of the lesion was 7.6{+-}2.6 mm (range 3-14 mm). Conclusion: Suspicious breast lesions detectable only in MR imaging can be accurately localized with a hook ...

2000-09-01

72

CMOS/SOI hardening at 100 MRAD (SiO_2)  

International Nuclear Information System (INIS)

Hardened CMOS/SOI 29101 microprocessor, elementary cells and transistor shave been irradiated at levels between 10 Mrad(SiO_2) and 1 Grad(SiO_2) ("6"0Co and 10 keV x-rays). SIMOX buried oxide behavior in the range of 100 Mrad(SiO_2) and a channel-stopped MOS/SOI structure avoiding lateral leakage current are presented. These two items indicate the feasibility of a CMOS/SOI technology operating in the hundred Mrad(SiO_2) range.

1990-07-16

73

Activities and activity ratios of U and Ra radioisotopes in drinking wells, springs and tap water samples in Morocco  

International Nuclear Information System (INIS)

Radiochemical results ("2"3"4U, "2"3"8U, "2"2"6Ra and "2"2"8Ra activities; "2"3"4U/"2"3"8U, "2"2"8Ra/"2"2"6Ra and "2"2"6Ra/"2"3"8U activity ratios) are reported for 31 drinking water samples collected from 8 wells, 12 hot mineral springs, 5 cold springs, and 6 tap water samples. Activities of the Ra isotopes were measured by gamma spectrometry using a low background and high efficiency well type germanium detector. The U isotopes were counted in an alpha spectrometer. The results show that "2"3"8U activity varies between 4.46 and about 308 mBq l"-"1 in wells, 0.59 and 17.88 mBq l"-"1 in hot springs, 2.19 and 3.21 mBq l"-"1 in cold springs, and between 2.5 and 15.70 mBq l"-"1 in tap water samples. "2"3"4U/"2"3"8U activity ratio is generally higher than 1 which is the equilibrium activity ratio value in closed systems. It varies in the ranges 0.79-2.11 in wells, 0.97-7.39 in hot springs, 2.53-8.30 in cold springs, and ...

74

Performance of LiNi{sub 0.5}Mn{sub 1.5}O{sub 4} prepared by solid-state reaction  

Energy Technology Data Exchange (ETDEWEB)

LiNi{sub 0.5}Mn{sub 1.5}O{sub 4} was prepared through a solid-state reaction using various Ni precursors. The effect of precursors on the electrochemical performance of LiNi{sub 0.5}Mn{sub 1.5}O{sub 4} was investigated. LiNi{sub 0.5}Mn{sub 1.5}O{sub 4} made from Ni(NO{sub 3}){sub 2}.6H{sub 2}O shows the best charge-discharge performance. The reversible capacity of LiNi{sub 0.5}Mn{sub 1.5}O{sub 4} is about 145 mAh g{sup -1} and remained 143 mAh g{sup -1} after 10 cycles at 3.0-5.0 V. The XRD results showed that the precursors and the dispersion methods had significant effect on their phase purity. Pure spinel phase can be obtained with high energy ball-milling method and Ni(NO{sub 3}){sub 2}.6H{sub 2}O as precursor. Trace amount of NiO and Li{sub 2}MnO{sub 3} phase were detected in LiNi{sub 0.5}Mn{sub 1.5}O{sub 4} with manual-mixture method and using Ni(CH{sub 3}COO){sub 2}.6H{sub 2}O, NiO and Ni{sub 2}O{sub 3} as ...

2009-04-01

75

Trace elements and radioactivity measurements in some terrestrial food crops in Jos-plateau, north central, Nigeria  

International Nuclear Information System (INIS)

Some crops of important nutritive requirements have been collected from farmlands located in Bitsichi an old tin mining town in north central region of Nigeria. The food crops were analyzed in order to determine trace element concentrations level using Neutron Activation Analysis (NAA). The activity concentrations due to natural radionuclides in the food samples and soil samples collected within the root zone of the crops were also determined using gamma-ray spectrometry (GRS). The NAA results obtained showed higher concentration of Potassium among the essential elements in all the crops. Calcium concentration in both maize and Guinea corn was below detection limit and also Zn in Green beans, sweet potato and cassava. The trace elements; Sc, Hf, Sm, and Th, were below detection limit in all the crops except in Green beans. Rubidium (Rb) and lanthanum (La) were below detection limits only in Cabbage. The activity concentrations of the natural radionuclides in the food samples were found ...

76

Phosphorus, nitrogen, and radionuclide retention and leaching from a Joel sand amended with red mud/gypsum  

International Nuclear Information System (INIS)

The leaching of phosphorus (P), nitrogen (N), and radionuclides "2"3"2Th, "2"2"6Ra, "2"2"8Ra, and "4"0K from Joel sands amended with red mud/gypsum (RMG) at 9 rates (0, 2, 4, 8, 16, 32, 64, 128, and 256 t/ha) was measured using columns. Intense leaching conditions (34 mm/day for 12 days) and a high rate of applied P (320 kg/ha as superphosphate) and N (680 kg/ha as ammonium nitrate) were used to simulate extremes of irrigated vegetable production on the Swan Coastal Plain. Addition of the highest rate of RMG (256 t/ha) reduced leaching of fertiliser P and ammonium-nitrogen (NH4-N) by 85% and 50%, respectively, compared with 0 t/ha after 12 days. At 64 t RMG/ha P leaching was reduced 50% compared with 0 t/ha. Nitrate-nitrogen (NO3-N) leaching was not affected by addition of RMG. Reduced leaching of NH4-N was attributed to an increase in cation exchange capacity of the soil with the addition of RMG. Bicarbonate-extractable P in the soil increased with rate of RMG to ...

77

Wood-polymer composites. Polymerization of methyl-metacrylate in Pinus strobus var. chiapensis wood by gamma radiation  

Energy Technology Data Exchange (ETDEWEB)

To obtain Pinus wood-plastic composites, wood samples were impregnated with methyl methacrylate and polymerized by the use of gamma rays from a /sup 60/Co at different dose exposure and total dose. The best percentage of polymerization was obtained with the exposure of 2.0 MR of gamma radiation. It was found that the impregnation and polymerization, determined by the density values along the samples were uniform. The density became 2.6 times higher in relation to the control samples. The storage of the impregnated wood samples showed losses of the monomer, even when wrapped with aluminum or polyethylene film. It is recommended that the wood samples should be irradiated soon after impregnation.

1984-12-01

78

Study of oxygen diffusion in YBaCuO by isothermal internal friction. Etude par frottement interieur isotherme de la diffusion de l'oxygene dans YBaCuO  

Energy Technology Data Exchange (ETDEWEB)

The elastic behaviour of YBaCuO specimens has been studied by very low-frequency isothermal internal-friction measurements. A relaxation peak is observed which is attributed to oxygen atom jumps, between A(1/2 0 0) and B(0 1/2 0) sites, in the CuO planes of the orthorhombic phase. A limit relaxation time {tau}{sub 0}, 2.6 {center dot} 10{sup -15}s, and an activation energy, 1.3eV, have been obtained from the shift of the maximum damping frequency observed when the measurement temperature is changed. The proposed values for the limit relaxation time and the activation energy are in good agreement with those previously proposed in the literature.

1992-02-07

79

Study of interaction between 7-(6-Br-2-benzthiazolylazo)-8-oxiquinoline-5-sulfonic acid and uranium (6), zinc (2) and manganese (2)  

International Nuclear Information System (INIS)

A new reagent 7-(6-Br-2-henzthiazolilazo)-8-oxyquinoline-5-sulphoacid has been studied spectrophotometrically. Dissociation constants have been determined in 50% acetone (pK_1=2.5 and pK_2=5.9) and 50% dioxane (pK_1=1.7 and pK_2=6.1) as well as molar extinction coefficients of the reagent dissociated form in the same solvents (71.1.10"3 and 72.4.10"3). The conditions have been studied of complexing the reagent with ions of uranium (6), zinc (2), and manganese (2) in 50% dioxane (pH 2.5-4.5) and the properties of the formed complexes.

1977-01-01

80

Structure and properties of Li2Zn2(MoO4)3 crystals activated with copper and chromium ions  

British Library Electronic Table of Contents (United Kingdom)

Based on the corrected phase diagrams proper growth conditions for Li2Zn2(MoO4)3 crystals are selected. Large crystals (up to 100 mm), both impurity-free and activated by transition metal ions (Cu, Cr), are grown by the low-gradient Czochralski method. By the EPR method the charge state and structural position of copper and chromium ions are determined. The performed studies of luminescent properties show that for impurity-free crystals luminescence with ? = 388 nm with a two-exponential luminescence decay with ?1 = 2 ns and ?2 = 6 ns is observed at room temperature. At 77 K for both impurity-free crystals and those activated with transition metal ions luminescence with ? = 560 nm and the luminescence lifetime ? = 100 ns is observed, the intensity of luminescence with ? = 560 nm depending ...

2011-01-01

81

Some sulfonamide drugs inhibit ATPase activity of heat shock protein 90: investigation by docking simulation and experimental validation  

British Library Electronic Table of Contents (United Kingdom)

Eight selected sulfonamide drugs were investigated as inhibitors of heat shock protein 90 (Hsp90). The investigation included simulated docking experiments to fit the selected compounds within the binding pocket of Hsp90. The selected molecules were found to readily fit within the ATP-binding pocket of Hsp90 in low-energy poses. The sulfonamides torsemide, sulfathiazole, and sulfadiazine were found to inhibit the ATPase activity of Hsp90 with IC50 values of 1.0, 2.6, and 1.5 mM, respectively. Our results suggest that these well-established sulfonamides can be good leads for subsequent optimization into potent Hsp90 inhibitors.

2011-01-01

82

Short-term study of infliximab treatment for Crohn's disease in China  

British Library Electronic Table of Contents (United Kingdom)

OBJECTIVE:- To determine the effectiveness and safety of short-term treatment of infliximab (IFX) in a group of Chinese patients with active Crohn's disease (CD). METHODS:- Patients with established diagnosis of active CD were treated with IFX intravenously with a dose of 5-mg/kg at week 0, 2, 6. Clinical assessments were performed at baseline (week 0) and every week after IFX infusion until 8 weeks after the induction dose. RESULTS:- Fourteen patients (nine male, five female) with a mean age of 29.7 years (range from 15 to 65 years) were included in the analysis. The mean subjective scores were decreased from 2.85--0.57 at baseline to 1.3--0.4 at week 14 (P-CONCLUSIONS:- Treatment with three infusions of IFX at a dose of 5-mg/kg was effective for induction of remission for active CD patie...

2011-01-01

83

Radon diffusion studies through building construction materials using solid state nuclear track detectors  

International Nuclear Information System (INIS)

Radon appears mainly by diffusion processes from the point of origin following #alpha#- decay of "2"2"6Ra in underground soil and building materials used, in the construction of floors, walls, and ceiling. The transport phenomenon of radon through diffusion is a significant contributor to indoor radon entry. In the present study radon diffusion through sand, cement, mixtures of sand + cement (1:1), sand + cement (2:1), sand + cement (3:1), sand + cement (4:1) has been carried out using LR-115 type II solid state nuclear track detectors (SSNTDs). The radon diffusion coefficient and diffusion lengths have been calculated for different materials. The effect of compaction, which changes the porosity and permeability of the materials, on radon diffusion has also been studied. (author)

2003-10-16

84

Radon Levels and Related Doses in a Prototype Jamaican House Constructed with Bauxite Waste Blocks  

International Nuclear Information System (INIS)

Measurements are presented of indoor radon levels made in a prototype house constructed partly of bauxite waste (red mud) and partly of conventional materials. The mud used contains higher than the average amounts of "2"2"6Ra and "2"3"2Th found in local building materials. The rates of exhalation of radon from the material used in the construction of the house are measured and employed with measured air change rates to make estimates of the average contribution of the various materials to the measured radon levels indoors. There is fairly good agreement between the two. The increment of radon related dose equivalents above background are also estimated and these are combined with previously determined gamma dose equivalents and used as a basis for assessing the acceptability of the practice of using red mud as a building material. (author)

85

Production of "6"2Zn, "6"5Zn and "2"0"3Pb radioisotopes for studying the transport of zinc and lead in plants  

International Nuclear Information System (INIS)

In the Carpathian Basin, significant percentage of watershed area and floodplains of rivers are utilised agriculturally. Several potential sources of poisonous metal pollution have been identified in these areas. Because of spills from some of them a few severe accidents have happened especially in the watershed area of Tisza River during the last decades. The motivation of our present work was to produce "6"2","6"5Zn and "2"0"3Pb radioisotopes because they can be used especially as tracers for studying the kinetics of uptake, transport and accumulation of zinc and lead by plants under different circumstances. (orig.)

86

Preparation of some nuclear fuel materials on A pilot scale  

International Nuclear Information System (INIS)

This study started with a comprehensive and critical review of the published information of relevance to the different methods to produce uranium dioxide from raw materials. we have chosen this method 'flame denitration' or flame process to produce Uo_2. from its compounds, uranyl nitrate Uo_2 ( NO_3) _2 .6H_2o) prepared from raw uranium 'yellow cake'. This method in short produces uranium dioxide from aqueous uranyl nitrate by contacting the atomized liquid which has 40 #mu# in diameter with hot reducing gases (butane and oxygen mixture) till we obtain a suitable and yellow red colour light for the flame and this is a prof that there is carbon monoxide and hydrogen, the temperature of the reactor at is least 950 degree C.

1979-01-01

87

Optimisation of pectin acid extraction from passion fruit peel (Passiflora edulis flavicarpa) using response surface methodology  

British Library Electronic Table of Contents (United Kingdom)

Summary Pectin was extracted from passion fruit peel using three different acids (citric, hydrochloric or nitric) at different temperatures (40-90 degreeC), pH (1.2-2.6) and extraction times (10-90 min), with and without skins using a 24 factorial design. Temperature, pH and extraction time had highly significant effects on the pectin yield. A central composite design with face centring was used to optimise the extraction process conditions for citric acid without skins. Pectin yields varied from 10% to 70%. The optimal conditions for maximisation of pectin yield were the use of citric acid at 80 degreeC and pH 1 with an extraction time of 10 min considering model extrapolation.

2009-01-01

88

Molecular structure of platinum(III) hydroxoacetates according to data from EXAFS spectra  

Energy Technology Data Exchange (ETDEWEB)

The EXAFS spectra of the platinum(III) complexes Pt/sub 4/(OAc)/sub 10/(OH)/sub 2/ (I) and Pt/sub 4/ (OAc)/sub 4/(OH)/sub 8/(H/sub 2/O)/sub 2/ (II) have been investigated. It has been found by a curve-fitting method and with the aid of Fourier transformations that the shortest Pt-Pt distances are 2.61 A in complex I and 2.36 and 2.6 A in II. The values of the bond lengths obtained are consistent with the molecular structures proposed for complexes I and II, which contain skeletons of four platinum atoms in the form of a square or a rectangle, as well as with the known literature data on the lengths of Pt-Pt bonds in Pt(III) complexes.

1986-04-01

89

Isolation and mapping of a polymorphic DNA sequence (pEFD64. 2) on chromosome 3 (D3S46)  

Energy Technology Data Exchange (ETDEWEB)

A 4.0 kb TaqI fragment of cosmid EFD64 isolated by a HBV-3 oligonucleotide was subcloned into AccI site of pUC18. MspI identifies 5 allelic VNTR polymorphism with bands between 2.6 and 4.6 kb. RsaI, TaqI, EcoRI, BamHI, HindIII and PvuII identify the same VNTR polymorphism. With RsaI, 80% heterozygosity were observed in 80 unrelated Caucasians. This RFLP pEFD64.2 has been assigned to chromosome 3 by linkage analysis with loci (APOD) known to span this chromosome. Co-dominant segregation for the RsaI RFLP was observed in 40 three generation families. RFLPs were observed under the normal hybridization and washing condition.

1988-10-11

90

Gadolinium (III) chelates of O, N-donor Schiff bases derived from 2, 3-dimethyl-4-formyl-1-phenyl-3-pyrazoline-5-one and certain aromatic amines  

International Nuclear Information System (INIS)

New Schiff base chelating ligands were synthesized by reacting equimolar quantities of 2,3-dimethyl-4-formyl-1-phenyl-3-pyrazoline-5-one and o-anisidine, p-anisidine, m-anisidine, o-toluidine, p-toluidine, m-toluidine, 2,6-xylidine or 2,4-xylidine in ethanol medium. Their subsequent reaction with gadolinium (III) nitrate hexahydrate in 2:1 molar ratio gave complexes that were characterized by elemental analyses, molar conductances, magnetic measurements, electronic and I.R. spectral studies. All the chelates were found to be non-electrolytic in nature. (author). 15 refs., 1 fig., 1 tab.

1994-01-01

91

Flavonols and an oxychromonol from Piliostigma reticulatum  

British Library Electronic Table of Contents (United Kingdom)

The leaf extract from the plant Piliostigma reticulatum was found to exhibit antimicrobial activity against some bacteria and fungi such as Staphylococcus aureus (NCTC 6571), Escherichia coli (NCTC 10418), Bacillus subtilis (NCTC 8236), Proteus vulgaris (NCTC 4175), Aspergillus niger (ATCC 10578) and Candida albicans (ATCC 10231). Upon investigation of the chemical constituents present in the leaf extract, a total of seven compounds were isolated and their structures were unambiguously established by spectroscopic methods including HR-MS and NMR spectrometry. Four of the isolated compounds were novel, namely 6-C-methyl-2-p-hydroxyphenyloxychromonol (piliostigmol), 1, 6,8-di-C-methylquercetin-3,3prime,7-trimethyl ether, 2, 6,8-di-C-methylquercetin-3,3prime-dimethyl ether, 3 and 3prime,6,8,-...

2008-01-01

92

Extraction of rare earths by carbonic acids melts  

Energy Technology Data Exchange (ETDEWEB)

Extraction of rare earths (La, Ce, Pr, Eu, Gd, Er, Yb) from nitrate solutions by melts of carboxylic acids of the C/sub 17/-C/sub 20/ fraction and stearic acid with paraffin, depending on the temperature (60-90 deg), phase contact time and their volume ratio (O:B from 1:5 up to 1:100), pH of the aqueous phase (2-6), rare earth concentration (10/sup -6/-10/sup -3/ m) is studied. It is shown that in the whole concentration range investigated rare earths are extracted quantitatively into the carboxylic acid melt of C/sub 17/-C/sub 20/ fraction at the equilibrium value of pH>=3.8, while into the melt of 0.1 M stearic acid in paraffin at pH>=4.5.

1980-10-01

93

Experimental limits on quarks, tachyons, and massive particles in cosmic rays  

Energy Technology Data Exchange (ETDEWEB)

A large detector with high redundancy is used to search for various types of anomalous particles in cosmic rays at sea level. The detector is sensitive to zenith angles between 45/sup 0/ and 90/sup 0/. Previously obtained limits on the fluxes of charge (1/3) and (2/3) particles are reduced to 2.9 x 10/sup -10/ and 2.6 x 10/sup -10/ cm/sup -2/sr /sup -1/ sec/sup -1/, respectively. The flux of ionizing tachyons is determined to be less than 2.4 x 10/sup -9/ cm/sup -2/ sr/sup -1/ sec/sup -1/. The massive-particle flux limit we obtain is inconsistent with previous claims of such particles assuming that these particles are isotropic in zenith angle.

1982-10-01

94

Experimental limits on quarks, tachyons, and massive particles in cosmic rays  

International Nuclear Information System (INIS)

A large detector with high redundancy is used to search for various types of anomalous particles in cosmic rays at sea level. The detector is sensitive to zenith angles between 45"0 and 90"0. Previously obtained limits on the fluxes of charge (1/3) and (2/3) particles are reduced to 2.9 x 10"-"1"0 and 2.6 x 10"-"1"0 cm"-"2sr "-"1 sec"-"1, respectively. The flux of ionizing tachyons is determined to be less than 2.4 x 10"-"9 cm"-"2 sr"-"1 sec"-"1. The massive-particle flux limit we obtain is inconsistent with previous claims of such particles assuming that these particles are isotropic in zenith angle.

95

Effects of simulated acidic rain applied alone and in combination with ambient rain on growth and yield of field-grown snap bean  

Energy Technology Data Exchange (ETDEWEB)

Field-grown snap bean plants were treated with simulated acidic rain applied either alone or in combination with ambient rain and the effects on growth and yield were determined. In plots where ambient rain was excluded, a retractable canopy was activated to shield the crop. Four levels of acidity at pH values of 5.0, 4.2, 3.4 and 2.6 were applied in four replicate treatments and the experiment was conducted in two successive years (1981 and 1982). In plots that received only simulated rain, yield was not adversely affected by acidic rain; in 1981, a positive linear relationship was present between acidity of simulated rain and yield, but in 1981, no effect was found. In contrast, in plots that received both simulated and ambient rain, a negative linear relationship between acidity in simulated rain and yield was observed in both years.

1984-01-01

96

Degredation of superconductive properties in type A 15 compounds after irradiation  

International Nuclear Information System (INIS)

The influence of irradiation with 2.6 MeV H and He nuclei on the superconducting properties (critical temperature Tsub(c), critical current Isub(c)) of the intermetallic compound Nb_3Sn was studied. Irradiation led to a significant lowering of Tsub(c), while Isub(c) is increasing with the radiation dose. This is assumed to be due to the formation of active pinning centres in the lattice. There is a fast drop of Isub(c) after a peak value has been reached. Annealing of the samples (600-1,000"0C) led to an almost complete recovery of the initial value of Tsub(c). X-ray diffraction showed that irradiation causes considerable distortions of the lattice while the A15 crystal structure is retained. The causes of the radiation effects related to structural defects are discussed. (GSCH).

97

Codon-modifications and an endoplasmic reticulum-targeting sequence additively enhance expression of an Aspergillus phytase gene in transgenic canola  

British Library Electronic Table of Contents (United Kingdom)

Transgenic plants offer advantages for biomolecule production because plants can be grown on a large scale and the recombinant macromolecules can be easily harvested and extracted. We introduced an Aspergillus phytase gene into canola (Brassica napus) (line 9412 with low erucic acid and low glucosinolates) by Agrobacterium-mediated transformation. Phytase expression in transgenic plant was enhanced with a synthetic phytase gene according to the Brassica codon usage and an endoplasmic reticulum (ER) retention signal KDEL that confers an ER accumulation of the recombinant phytase. Secretion of the phytase to the extracellular fluid was also established by the use of the tobacco PR-S signal peptide. Phytase accumulation in mature seed accounted for 2.6% of the total soluble proteins. The enzy...

2006-01-01

98

Biosorption of reactive dye by waste biomass of Nostoc linckia  

British Library Electronic Table of Contents (United Kingdom)

Potential of spent biomass of a cyanobacterium, Nostoc linckia HA 46, from a hydrogen bioreactor was studied for biosorption of a textile dye, reactive red 198. The waste biomass was immobilized in calcium alginate and used for biosorption of the dye from aqueous solution using response surface methodology (RSM). Kinetics of the dye in aqueous solution was studied in batch mode. Interactive effects of initial dye concentration (100-500mg/L), pH (2-6) and temperature (25-45^oC) on dye removal were examined using Box-Behnken design. Maximum adsorption capacity of the immobilized biomass was 93.5mg/g at pH 2.0, initial concentration of 100mg/L and 35^oC temperature, when 94% of the dye was removed. Fourier transform infrared (FT-IR) studies revealed that biosorption was mainly mediated by fun...

2011-01-01

99

Application of CaSO4:Dy (TLD-900) to diagnostic x-ray exposures  

International Nuclear Information System (INIS)

The properties of a new commercial thermoluminescent dosimeter, CaSO4:Dy without a LiF binder (TLD-900) was studied for low-exposure measurements in diagnostic radiology. The former TLD-900 had a LiF binder (herein referred to as ''TLD-900/LiF''). The principle features of this dosimeter are its high sensitivity to low-energy radiation and its relatively low fading which permits measurements down to less than 2.6 X 10(-8) C kg (0.1 mR) with an accuracy better than 20%. The characteristics, annealing procedures, light sensitivity, energy response, reproducibility, and fading, of TLD-900 are discussed and compared with TLD-900/LiF. When the precautions presented in this paper are used, the dosimeters can be used for the measurement of x-ray exposures.

100

Adsorption of Db and its homologues Nb and Ta, and the pseudo-homologue Pa on anion-exchange resin in HF solution  

International Nuclear Information System (INIS)

Anion-exchange chromatography of element 105, dubnium (Db), produced in the "2"4"8Cm("1"9F, 5n)"2"6"2Db reaction is investigated together with the homologues Nb and Ta, and the pseudo-homologue Pa in 13.9 M hydrofluoric acid (HF) solution. The distribution coefficient (K_d) of Db on an anion-exchange resin is successfully determined by running cycles of 1702 chromatographic column separations. The result clearly indicates that the adsorption of Db on the resin is significantly different from that of the homologues and that the adsorption of anionic fluoro complexes of these elements decreases in the sequence of Ta#approx#Nb>Db#>=#Pa. (orig.)

101

A principle of charged particle trapping by RF electromagnetic field in the spherical cavity  

Energy Technology Data Exchange (ETDEWEB)

A new principle of particle trapping in the simple spherical cavity using both electric and magnetic components of radiofrequency electromagnetic field is proposed. The electric component of H {sub 12} oscillating mode drives the fast particle oscillations, while the magnetic component synchronously bends the trajectories to the cavity center. A specially developed theory of particle stability predicts dense and energetic electron cluster in the trap. Numerical simulations of particle dynamics in the complete electromagnetic field taking into account both space charge and particle-induced magnetic field are in good agreement with the analytic results, giving a density of 2.6*10{sup 1} electrons/cm{sup 3} and an average kinetic energy of around 30 keV at an operating frequency of 3 GHz. Being used at lower frequency, spherical cavity can trap protons and heavier ions too, but with lower density and kinetic energy.

2005-11-21

102

A mobile gamma scanning system for detecting radiation anomalies  

International Nuclear Information System (INIS)

A mobile gamma-ray scanning system has been developed by Oak Ridge National Laboratory for use in the U.S. Department of Energy's remedial action survey programs. The unit consists of NaI(Tl) detectors housed in a specially equipped van. The system is operator controlled through an on-board minicomputer with data output provided on the computer video screen, strip chart recorders, and an on-line printer. Data storage is provided on floppy disk. Multichannel analysis capabilities are included for qualitative radionuclide identification. A "2"2"6Ra-specific algorithm is currently employed to identify locations containing residual radium-bearing materials.

103

11. Preparation of natural radioactive materials  

International Nuclear Information System (INIS)

Uranium and thorium ores are the source of natural radionuclides. Briefly described are the original and current methods of long-lived nuclide separation ("2"3"8U, "2"3"5U, "2"2"6Ra, "2"3"0Th, "2"3"1Pa, "2"2"7Ac, "2"3"2Th, "2"2"8Ra+"2"2"8Ac, "2"2"8Th), some short-lived nuclides ("2"3"4Th and "2"2"8Ac), radon, short-lived radon daughter products and long-lived radon daughter products ("2"1"0Pb, "2"1"0Bi, "2"1"0Po). Some nuclides, such as "2"1"0Po or "2"3"1Pa can more easily be producedin reactors. (Ha).

104

Valence electronic structure of Ti, Cr, Fe and Co in some alloys from K#beta#-to-K#alpha# X-ray intensity ratio studies  

International Nuclear Information System (INIS)

K#beta#-to-K#alpha# X-ray intensity ratios of Ti, Cr, Fe and Co in pure metals and in Cr_0_._2_6Fe_0_._7_4, Cr_0_._8_0Co_0_._2_0 and Ti_0_._8_0Cr_0_._2_0 alloys have been measured following excitation by 59.54 keV #gamma#-rays from a 7400 MBq (200 mCi) "2"4"1Am point-source. The valence electronic structure of Ti, Cr, Fe and Co in the samples have been evaluated by the comparison of the measured K#beta#-to-K#alpha# intensity ratios with the results of multiconfiguration Dirac-Fock calculations performed for various electronic configurations of these metals. The 3d-electron populations obtained for pure metallic Ti, Cr, Fe and Co agree well with the results of band structure calculations of Papaconstantopoulos (Handbook of band structure of elemental solids, Plenum Press, New York, 1986). Our analysis indicates significant increase of 3d-electron population of Ti, Cr and Fe in the alloys with respect to the pure metals, except for Cr in ...

2002-10-01

105

Synthesis of Ln_0_._6Sr_0_._4Co_0_._8Fe_0_._2O_3_-_#delta# powders through glycine-nitrate combustion process  

International Nuclear Information System (INIS)

Solid oxide fuel cell (SOFC) is a promising source of power generation in terms of conversion efficiency which is higher than the conventional one, as it is not limited by the Carnot efficiency. Theoretically, the SOFC have an efficiency of the order of 60-80 % but it is limited by the number of active side available for the reaction i.e. TPB (triple phase boundary) at the electrode-electrolyte interface which depends on the particle size of the materials employed during the fabrication of SOFC components (i.e. the method employed during the synthesis). Literally, there are several methods used in the syntheses of oxide materials such as conventional solid-state reaction, co-precipitation, hydrothermal rout, sol-gel and Glycine nitrate process (GNP) but among these GNP found to be effective over the other because of homogeneity, phase purity and smaller particle size of final product. In this work, the Nano-crystalline Ln_0_._6Sr_0_._4Co_0_._8Fe_0_._2O_3_-_#delta# (LSCF) cathode was ...

2010-12-01

106

Radionuclide contents in food products from domestic and imported sources in Nigeria  

International Nuclear Information System (INIS)

Samples of some domestic and imported food products of nutritive importance to both the child population and the adult population in Nigeria were collected and analysed in order to determine their radionuclide contents. The samples were collected from open markets in major commercial cities in the country. Gamma-ray spectrometry was employed in the determination of the radionuclide contents in the products. The gamma-ray peaks observed with reliable regularity in all the samples analysed belong to naturally occurring radionuclides, namely "2"2"6Ra, "2"2"8Th and "4"0K. The activity concentrations of these radionuclides in both the domestic and imported products were observed to be not significantly different. Essentially radioactive elements such as "1"3"7Cs were not detected in any of the samples. The non-detection of "1"3"7Cs in the imported products may be attributed to the suitably modified agricultural practices and countermeasures being employed to reduce ...

2008-09-01

107

Radionuclide air emissions report for the Hanford Site -- calendar year 1997  

Energy Technology Data Exchange (ETDEWEB)

This report documents radionuclide air emission from the Hanford Site in 1997, and the resulting effective dose equivalent to the maximally exposed member of the public, referred to as the MEI. The report has been prepared in accordance with reporting requirements in the Code of Federal Regulations, Title 40, Protection of the Environment, Part 61, National Emissions Standards for Hazardous Air Pollutants, Subpart H, National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities. This report has also been prepared in accordance with the reporting requirements of the Washington Administrative Code Chapter 246-247, Radiation Protection-Air Emissions. The effective dose equivalent to the MEI from the Hanford Site`s 1997 point source emissions was 1.2 E-03 mrem (1.2 E-05 mSv), which is well below the 40 CFR 61 Subpart H regulatory limit of 10 mrem/yr. Radon and thoron emissions, exempted from 40 CFR 61 Subpart H, resulted in an effective ...

1998-06-17

108

Lithium ion conductive polymer electrolyte by side group rotation  

Energy Technology Data Exchange (ETDEWEB)

Ionic conductive materials are of much interest as an electrolyte for solid-state lithium batteries. Poly(alkylene oxide) and lithium salt complex exhibits high ionic conductivity in terms of its high solubility for lithium salts. However, the temperature dependency of its ionic conductivity is quite large and non-linear, the ionic conductivity drops down at low temperature, especially below glass transition temperature of the polymer. Because its ionic conductive mechanism is derived from its segmental motion of polymer main chain. A novel ionic conductive material, poly[2,6-dimethoxy-N-(4-vinylphenyl)benzamide] is synthesized and confirm ionic conductivity even below glass transition temperature. Ionic conductivity of the polymer with lithium ditrifluoromethylsulfonate imide complex shows 10{sup -5}Scm{sup -1} from 0 to 60{sup o}C. Its temperature dependency is linear, namely Arrehnius type dependency. Evaluating from these data, activation energy of ionic ...

2005-08-26

109

A campaign of discrete radon concentration measurements in soil of Niska Banja town, Serbia  

International Nuclear Information System (INIS)

The first radon soil gas survey in Serbia, using passive detectors (SSNTD, CR-39), was carried out in June 2005 at field sites in Niska Banja town. The aim of the survey was to identify risk zones characterised by high levels of this radioactive gas. Radon measurements were made at the depth of 50 cm, in the ground according to a systematic grid pattern. Furthermore, at all 48 measurement points, the surface gamma dose rates in the air was also measured at the same locations and soil samples were collected for gamma spectrometric analysis for the radionuclides "2"2"6Ra, "2"2"8Th and "4"0K. Radon concentrations were found to range from 1270 to 155000Bqm"-"3 with an average of 33765Bqm"-"3 and a median value of 12626Bqm"-"3. The geometrical mean value and geometrical standard deviation were calculated as 16160Bqm"-"3 and 3.5Bqm"-"3, respectively. Gamma dose rate varies from 92 to 316nGyh"-"1, with an average of 132nGyh"-"1. The radium content in collected soil ...

2007-11-01

110

Water-soluble cis-[(NHC)PdBr2(TPPTS)] catalysts and their applications in Suzuki-Miyaura coupling of aryl chlorides  

British Library Electronic Table of Contents (United Kingdom)

New palladium(II) complexes (2), bearing NHC/TPPTS ligands, (NHC=benzimidazol-2-ylidene; TPPTS=triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt) have been prepared and characterized by elemental analyses and spectroscopic methods. Their ability to catalyze the Suzuki-Miyaura reaction in neat water has been studied at 100^oC. Very high activities have been observed in the coupling of phenylboronic acid with aryl chlorides in the presence of 1% of the catalyst. We have compared the electronic properties of cis-[PdBr2(NHC)(TPPTS)] with the related complexes, [PdX2(NHC)]2 and [trans-PdBr2(NHC)(pdca)] (pdca=pyridine-2,6-dicarboxyic acid) (3) via three different techniques: cyclic voltammetry, thermogravimetric analysis and ^1^3C NMR spectroscopy.

2011-01-01

111

The radiosensitivity of spermatogonial stem cells in C3H/101 F[sub 1] hybrid mice  

Energy Technology Data Exchange (ETDEWEB)

The radiosensitivity of spermatogonial stem cells of C3H/HeHx101/H F[sub 1] hybrid mice was determined by counting undifferentiated spermatogonia at 10 days after X-irradiation. During the spermatogenic cycle, differences in radiosensitivity were found, which were correlated with the proliferative activity of the spermatogonial stem cells. In stage VIII[sub irr], during quiescence, the spermatogonial stem cells were most radiosensitive with a D[sub 0] of 1.4 Gy. In stages XI[sub irr]-V[sub irr], when the cells were proliferatively active, the D[sub 0] was about 2.6 Gy. Based on the D[sub 0] values for sensitive and resistant spermatogonia and on the D[sub 0] for the total population, a ratio of 45:55% of sensitive to resistant spermatogonial stem cells was estimated for cell killing. When the present data were compared with data on translocation induction obtained in mice of the same genotype, a close fit was obtained when the translocation yield (Y; in % abnormal ...

1993-12-01

112

The first placebo-controlled trial of a special butterbur root extract for the prevention of migraine: reanalysis of efficacy criteria.  

Science.gov (United States)

This is an independent reanalysis of a randomised, placebo-controlled parallel-group study on the efficacy and tolerability of a special butterbur root extract (Petadolex) for the prophylaxis of migraine. The original protocol and analysis had a number of major shortcomings. In order to follow regulatory requirements, an independent reanalysis of the original data was performed. Following a 4-week baseline phase, 33 patients were randomised to treatment with two capsules 25 mg butterbur twice a day and 27 to placebo. The mean attack frequency per month decreased from 3.4 at baseline to 1.8 after 3 months (p = 0.0024) in the verum group and from 2.9 to 2.6 in the placebo group (n.s.). The responder rate (improvement of migraine frequency > or =50%) was 45% in the verum group and 15% in the placebo group. Butterbur was well tolerated. This small trial indicates that butterbur may be effective in the prophylaxis of migraine. PMID:14752215

2004-01-28

113

The Use of Particulate Bone Grafts From the Mandible for Maxillary Sinus Floor Augmentation Before Placement of Surface-Modified Implants: Results From Bone Grafting to Delivery of the Final Fixed Prosthesis  

British Library Electronic Table of Contents (United Kingdom)

PurposeThis prospective study followed 61 patients who were partially dentulous and considered to have insufficient bone volume for routine implant treatment and consequently underwent sinus inlay bone grafting.Patients and MethodsThe patients were treated with maxillary sinus floor augmentation with particulated autogenous bone from the mandibular ramus/corpus. After a healing period, dental implants (n = 180) were installed.ResultsRadiographic examination revealed average residual vertical bone heights of 6.5 mm in the first premolar region, 3.8 mm in the second premolar region, 3.5 mm in the first molar region, and 2.6 mm in the second molar region. The average implant lengths were 12 mm in the first premolar region and 11 mm in the second premolar, first, and second molar regions. All ...

2008-01-01

114

The Contribution of Sympathetic Mechanisms to Postamputation Phantom and Residual Limb Pain: A Pilot Study  

British Library Electronic Table of Contents (United Kingdom)

Postamputation pain (PAP) affects over 60% of major limb amputees. One of the main challenges in treating PAP is the difficulty involved in identifying pain mechanism(s), which pertains to both residual limb pain (RLP) and phantom limb pain (PLP). In this study, sympathetic blocks were performed on 17 major limb amputees refractory to treatment, including 2 placebo-controlled blocks done for bilateral amputations. One hour postinjection, mean RLP scores at rest declined from 5.2 (SD 2.8) to 2.8 (SD 2.6) (P = .0002), and PLP decreased from 5.3 (SD 3.1) to 2.3 (SD 2.1) (P = .0009). By 1 week, mean pain scores for RLP and PLP were 4.3 (SD 2.9) and 4.2 (SD 3.0), respectively. Overall, 8 of 16 (50%) patients experienced ?50% reduction in RLP 1-hour postinjection, with the beneficial effects ...

2011-01-01

115

Synthesis and photoluminescence properties of Sm3+-doped LaMgB5O10 and GdMgB5O10  

International Nuclear Information System (INIS)

Luminescence and reflection spectra as well as luminescence kinetics of the 1 mol% Sm3+-doped crystalline lanthanum magnesium meta borate (LaMgB5O10) and gadolinium magnesium meta borate (GdMgB5O10) were analyzed. Materials were synthesized by conventional solid state route and showed bright orange-red emission under UV excitation. Emission spectra contain sharp and well resolved Sm3+4G5/2#->#6HJ transitions indicating a strong crystal-field effect. In case of gadolinium compound energy transfer between Gd3+ and Sm3+ was detected. The luminescent kinetics of the Sm3+ in analyzed powders is characterized by single exponential decay and experimental values vary in the range 2.2-2.4 ms. - Research highlights: ? Phosphorescence of samarium-doped lanthanide magnesium meta borates. ? Bright and well resolved orange-red emission of Sm3+ under UV excitation. ? Energy transfer from Gd3+ to Sm3+ in gadolinium magnesium meta borate is observed. ? The decay lifetimes is ...

2011-07-01

116

Study of structural and optical properties of sprayed WO{sub 3} thin films using enhanced characterization techniques along with the Boubaker Polynomials Expansion Scheme (BPES)  

Energy Technology Data Exchange (ETDEWEB)

In this study, WO{sub 3} thin films were grown on glass substrates using an aqueous solution containing tungstate (NH{sub 4}){sub 2}WO{sub 4} as precursor. The substrate temperature incremented from 250 to 500 deg. C, by steps of 50 deg. C. The structural properties were investigated using XRD, atomic force microscopy and scanning electronic microscopy techniques. Microprobe analyses showed that a balanced stoichiometric composition was obtained for thin films prepared at T{sub s} = 350 and 400 deg. C. The X-ray diffraction analyses showed different structure crystallography in function of the substrate temperature. Moreover, films deposited at 400 deg. C were annealed in air for 2 h at 450 and 500 deg. C, respectively and the structural changes due to heat treatment were studied. Finally, the optical properties of these films were carried out using optical measurements of transmittance T({lambda}) and reflectance R({lambda}) spectra in 300-1800 nm domain. The refractive and absorption ...

2009-11-13

117

Study of structural and optical properties of sprayed WO3 thin films using enhanced characterization techniques along with the Boubaker Polynomials Expansion Scheme (BPES)  

International Nuclear Information System (INIS)

In this study, WO3 thin films were grown on glass substrates using an aqueous solution containing tungstate (NH4)2WO4 as precursor. The substrate temperature incremented from 250 to 500 deg. C, by steps of 50 deg. C. The structural properties were investigated using XRD, atomic force microscopy and scanning electronic microscopy techniques. Microprobe analyses showed that a balanced stoichiometric composition was obtained for thin films prepared at Ts = 350 and 400 deg. C. The X-ray diffraction analyses showed different structure crystallography in function of the substrate temperature. Moreover, films deposited at 400 deg. C were annealed in air for 2 h at 450 and 500 deg. C, respectively and the structural changes due to heat treatment were studied. Finally, the optical properties of these films were carried out using optical measurements of transmittance T(?) and reflectance R(?) spectra in 300-1800 nm domain. The refractive and absorption indexes, n and k were calculated. The band ...

2009-11-13

118

Structural and transport properties of illitized samples from drillhole OL-KR12 in Olkiluoto. Porosity, diffusion coefficient, permeability and tomographic imaging  

Energy Technology Data Exchange (ETDEWEB)

Six illitized samples from drillhole OL-KR12 in Olkiluoto were analyzed by helium gas methods for their diffusion coefficient, permeability and porosity. The diffusion coefficients measured varied in the range 2.1 x 10-10 - 3.5 x 10-8 m2/s, permeabilities in the range 6 x 10-21 - 5.8 x 10-16 m2, and porosities in the range 0.2 6.2%. Variations observed in these quantities were concluded to arise from the heterogeneous structure of the sample rock. A 4 mm x 4 mm x 4 mm subsample was sawed from each of the six samples for structural analysis by x-ray microtomography. The three-dimensional structure of tomographic reconstructions, and thereby that of the samples themselves, was analyzed visually, which confirmed their heterogeneity. Samples represent altered rock whose structure and thereby transport properties vary significantly depending on the local alteration history of the rock. (orig.)

2009-10-15

119

Rotation periods of late-type stars in the young open cluster IC 2602  

CERN Document Server

We present the results of a monitoring campaign aimed at deriving rotation periods for a representative sample of stars in the young (30 Myr) open cluster IC 2602. Rotation periods were derived for 29 of 33 stars monitored. The periods derived range from 0.2d (one of the shortest known rotation periods of any single open cluster star) to about 10d (which is almost twice as long as the longest period previously known for a cluster of this age). We are able to confirm 8 previously known periods and derive 21 new ones, delineating the long period end of the distribution. Despite our sensitivity to longer periods, we do not detect any variables with periods longer than about 10d. The combination of these data with those for IC 2391, an almost identical cluster, leads to the following conclusions: 1) The fast rotators in a 30 Myr cluster are distributed across the entire 0.5 < B-V < 1.6 color range. 2) 6 stars in our sample are slow rotators, ...

1999-01-01

120

Reduced exposure to microwave radiation by rats: frequency specific effects  

Energy Technology Data Exchange (ETDEWEB)

Previous research has shown that SAR hotspots are induced within the laboratory rat and that the resulting thermal hotspots are not entirely dissipated by bloodflow. Two experiments were conducted to determine if hotspot formation in the body and tail of the rat, which is radiation frequency specific, would have behavioral consequences. In the first experiment rats were placed in a plexiglas cage one side of which, when occupied by the rat, commenced microwave radiation exposure; occupancy of the other side terminated exposure. Groups of rats were tested during a baseline period to determine the naturally preferred side of the cage. Subsequent exposure to 360-MHz, 700-MHz or 2450-MHz microwave radiation was made contingent on preferred-side occupancy. A significant reduction in occupancy of the preferred side of the cage, and hence, microwaves subsequently occurred. Reduced exposure to 360-MHz and 2450-MHz microwaves at 1, 2, 6 and 10 W/kg were ...

1988-01-01

121

Radiological aspects of the usability of red mud as building material additive  

International Nuclear Information System (INIS)

Several researchers have examined and achieved favourable results in connection with the building industry's use of red mud extracted in large quantities from the processing of bauxite. These days more and more precedence is being given to limiting the radiological dose to the population. In this study carried out in Hungary, the use of red mud, bauxite, and clay additives recommended for the production of special cements, were examined from a radiological aspect. "2"2"6Ra and "2"3"2Th activity concentrations measured in Hungarian bauxite, red mud and clay samples were significantly similar with the levels for such raw materials mentioned in international literature. Taking radiation protection aspects into consideration, none of these products can be directly used for building construction. Taking Hungarian and international values into consideration, a small amount of red mud, not exceeding 15% could be used for brick production, for example as a colouring ...

2008-02-11

122

Radio-frequency optical double-resonance spectrum of SrF: the X/sup 2/. sigma. /sup +/ state  

Energy Technology Data Exchange (ETDEWEB)

The isotropic and anisotropic hyperfine constants of the ground X/sup 2/..sigma../sup +/ state of /sup 88/SrF and /sup 86/SrF are reported. Vibrational and rotational dependences are studied in a Dunham expansion analysis. Furthermore, the vibrational, rotational, and isotopic dependence of the spin-rotation constant is determined. The following values are obtained for X/sup 2/..sigma../sup +/, ..nu.. = 0, in /sup 88/SrF: ..gamma../sub 0/ = 74.79485 MHz, ..gamma../sub 1/ = 5.752 x 10/sup -5/ MHz, ..gamma../sub 2/ = -6.3 x 10/sup -10/ MHz, b/sub 0/ = 97.0834 MHz, b/sub 1/ = -3.300 x 10/sup -4/ MHz, c/sub 0/ = 30.268 MHz, C/sub I/ = 0.00230 MHz, where ..gamma.. is the spin-rotation parameter, b and c are the Frosch and Foley hyperfine parameters, and C/sub I/ is a nuclear spin-rotation correction. 4 figures, 4 tables.

1981-01-01

123

Radiation-induced reduction of ditetrazolium salt in aqueous solutions  

Energy Technology Data Exchange (ETDEWEB)

Color formation in aqueous solutions of the ditetrazolium salt blue tetrazolium (BT{sup 2+}) in the absence or presence of oxygen is a complex radiation chemical reaction. The final stable product is the poorly soluble diformazan violet to blue pigment having a broad spectral absorption band ({lambda}{sub max}=552 nm). The reaction of BT{sup 2+} with the hydrated electron proceeds by rapid reduction of BT{sup 2+} followed by protonation at the nitrogen closest to the unsubstituted phenyl group, via the two intermediate tetrazolinyl radicals shared by the ditetrazole ring nitrogens. The effect of solution pH, N{sub 2}O saturation, and the presence of the reducing agent dextrose are examined. The system serves as a radiochromic sensor and a dosimeter of ionizing radiations. Solutions of 5 mmol l{sup -1} BT{sup 2+} at pH 7.3 serve as dosimeters over an absorbed-dose range of approximately 0.2-6 kGy (dearated, with a range of 1-8 mmol l{sup -1} dextrose) and of about ...

2002-04-01

124

Proposing radioactivity limits for building materials  

International Nuclear Information System (INIS)

A nation-wide survey of natural radioactivity in building materials was conducted during 1982-1984. Samples including industrial wastes, by-products and common building materials were collected from main building material manufactories in 29 provinces except Taiwan. The results of exposure rates, specific activities and release rate for "2"2"2Rn are presented. The specific activities of common materials are listed in declining order as follows: clay bricks > common concrete and sandstones > limes and ordinary cement. The highest level was found in breeze bricks made of stone coal, phosphogypsum and red mud with high intrinsic radioactivity. Therefore, these raw materials should be strictly controlled in manufacturing building materials. The measurement results also showed that the typical specific activities of common building materials in our country were "2"2"6Ra 50 Bq/kg, "2"3"2Th 50 Bq/kg and "4"0K 500 Bq/kg. Based on the surveyed results and foreign ...

125

Part-load analysis of a chemical looping combustion (CLC) combined cycle with CO2 capture  

International Nuclear Information System (INIS)

This paper presents part-load evaluation of a natural gas-fired chemical looping combustion (CLC) combined cycle with CO2 capture. The novel combined cycle employs an air-based gas turbine, a CO2-turbine and a steam turbine cycle. In this combined cycle, the CLC reactors replace combustion chamber of the gas turbine. The proposed combined cycle has a net plant efficiency of about 52.2% at full-load, including CO2 compression to 200 bar. The part-load evaluation shows that reducing the load down to 60% results in an efficiency drop of 2.6%-points. However, the plant shows better relative part-load efficiency compared to conventional combined cycles. The pressure in CLC-reduction and -oxidation reactors is balanced by airflow control, using a compressor equipped with variable guide vanes. A combination of control strategies is discussed for plant start-up and shutdown and for part-load when airflow reduction is not practically possible with current generation of ...

2007-04-01

126

Parity-projected shell model Monte Carlo level densities for medium-mass nuclei  

International Nuclear Information System (INIS)

We investigate the effects of single-particle structure and pairing on the equilibration of positive and negative-parity level densities for the even-even nuclei "5"8","6"2","6"6Fe and "5"8Ni and the odd-A nuclei "5"9Ni and "6"5Fe. Calculations are performed using the shell model Monte Carlo method in the complete fp-gds shell-model space using a pairing+quadrupole type residual interaction. We find for the even-even nuclei that the positive-parity states dominate at low excitation energies due to strong pairing correlations. At excitation energies at which pairs are broken, single-particle structure of these nuclei is seen to play the decisive role for the energy dependence of the ratio of negative-to-positive parity level densities. We also find that equilibration energies are noticeably lower for the odd-A nuclei "5"9Ni and "6"5Fe than for the neighboring even-even nuclei "5"8Ni and "6"6Fe.

2008-11-11

127

Parity-projected shell model Monte Carlo level densities for fp-shell nuclei  

International Nuclear Information System (INIS)

We calculate parity-dependent level densities for the even-even isotopes "5"8","6"2","6"6Fe and "5"8Ni and the odd-A nuclei "5"9Ni and "6"5Fe using the shell model Monte Carlo method. We perform these calculations in the complete fp-gds shell-model space using a pairing+quadrupole residual interaction. We find that, due to pairing of identical nucleons, the low-energy spectrum is dominated by positive parity states. Although these pairs break at around the same excitation energy in all nuclei, the energy dependence of the ratio of negative-to-positive parity level densities depends strongly on the particular nucleus of interest. We find equilibration of both parities at noticeably lower excitation energies for the odd-A nuclei "5"9Ni and "6"5Fe than for the neighboring even-even nuclei "5"8Ni and "6"6Fe.

2007-06-01

128

Pa0148 from Pseudomonas aeruginosa Catalyzes the Deamination of Adenine.  

Science.gov (United States)

Four proteins from NCBI cog1816, previously annotated as adenosine deaminases, have been subjected to structural and functional characterization. Pa0148 (Pseudomonas aeruginosa PAO1), AAur1117 (Arthrobacter aurescens TC1), Sgx9403e, and Sgx9403g have been purified and their substrate profiles determined. Adenosine is not a substrate for any of these enzymes. All of these proteins will deaminate adenine to produce hypoxanthine with k(cat)/K(m) values that exceed 10(5) M(-1) s(-1). These enzymes will also accept 6-chloropurine, 6-methoxypurine, N-6-methyladenine, and 2,6-diaminopurine as alternate substrates. X-ray structures of Pa0148 and AAur1117 have been determined and reveal nearly identical distorted (?/?)(8) barrels with a single zinc ion that is characteristic of members of the amidohydrolase superfamily. Structures of Pa0148 with adenine, 6-chloropurine, and hypoxanthine were also determined, thereby permitting identification of the residues responsible for ...

2011-07-06

129

New technology for the comprehensive utilization of Chinese oil shale resources  

Energy Technology Data Exchange (ETDEWEB)

In China, the conventional utilization of oil shale is concentrated mainly on retorting oil shale to produce shale oil and fuel gas, and burning oil shale to generate electricity. The growth of petroleum price, and the development in heavy industry, make these conventional utilization facilities become unavailable on the energy market. In this paper, a new comprehensive utilization system is recommended for the future use of Huadian oil shale, based on the current status of energy and the characteristics of oil shale. The system involves three subsystems: retort subsystem, where coarse oil shale (8-80 mm) is retorted to shale oil, hydrocarbon gases and oil shale semicoke; combustion subsystem, where the mixture fuel of oil-shale semicoke and fine oil shale (0-8 mm) is fed to a circulating fluidized bed (CFB) furnace to burn, in order to generate high-pressure steam which is used to supply heat and generate electricity via a traditional steam-electric power mode; and ash processing ...

2007-05-15

130

Morphological classification and structural parameters for early-type galaxies in the Coma cluster  

CERN Document Server

We present the results of an isophotal shape analysis of three samples of galaxies in the Coma cluster. Quantitative morphology, together with structural and photometric parameters, is given for each galaxy. Special emphasis has been placed on the detailed classification of early-type galaxies. The three samples are: i) a sample of 97 early-type galaxies brighter than m_B = 17.00 falling within one degree from the center of the Coma cluster; these galaxies were observed with CCD cameras, mostly in good to excellent resolution conditions; ii) a magnitude complete sample of 107 galaxies of all morphological types down to m_B = 17.00 falling in a circular region of 50 arcmin diameter, slightly offcentered to the North-West of the cluster center; the images for this and the next sample come from digitized photographic plates; iii) a complete comparison sample of 26 galaxies of all morphological types down to m_R = 16.05 (or m_B \\simeq 17.5), also in a region of 50 arcmin diameter, but ...

1995-01-01

131

Mixed waste landfill corrective measures study final report Sandia National Laboratories, Albuquerque, New Mexico.  

Energy Technology Data Exchange (ETDEWEB)

The Mixed Waste Landfill occupies 2.6 acres in the north-central portion of Technical Area 3 at Sandia National Laboratories, Albuquerque, New Mexico. The landfill accepted low-level radioactive and mixed waste from March 1959 to December 1988. This report represents the Corrective Measures Study that has been conducted for the Mixed Waste Landfill. The purpose of the study was to identify, develop, and evaluate corrective measures alternatives and recommend the corrective measure(s) to be taken at the site. Based upon detailed evaluation and risk assessment using guidance provided by the U.S. Environmental Protection Agency and the New Mexico Environment Department, the U.S. Department of Energy and Sandia National Laboratories recommend that a vegetative soil cover be deployed as the preferred corrective measure for the Mixed Waste Landfill. The cover would be of sufficient thickness to store precipitation, minimize infiltration and deep percolation, support a ...

2004-03-01

132

Melilite formation in a samarium-stabilized #alpha#-sialon ceramic during postsintering heat treatments  

International Nuclear Information System (INIS)

The formation of the melilite solid solution phase (M'), Sm_2Si_3_-_xAl_xO_3_+_xN_4_-_x, in an #alpha#-sialon sample of overall composition Sm_0_._6Si_9_._2_8Al_2_._6_9O_1_._3_6N_1_4_._7_6, was studied as a function of time in the temperature interval 1,375--1,525 C. The #alpha#-sialon ceramic contained only minor amounts of the 21R sialon polytype and some residual grain-boundary glass before heat treatment. In situ studies by high-temperature X-ray diffraction were combined with postsintering heat treatment followed by quenching. The M'-phase was found to be formed by two different mechanisms: either crystallization of the residual grain-boundary liquid or a direct decomposition of the #alpha#-sialon phase. The liquid crystallized during the first 10--15 min of heat treatment, yielding a rapid M'-phase formation, and further formation of M'-phase continued at a much slower rate, related to the decomposition of #alpha#-sialon.

133

Medical image transmission via communication satellite. Evaluation of bone scintigraphy  

International Nuclear Information System (INIS)

As compared with terrestrial circuits, the communication satellite possesses superior characteristics such as wide area coverage, broadcasting, high capacity, and robustness to disasters. Utilizing the narrow band channel (64 kbps) of the geostationary satellite JCSAT 1 located at the altitude of 36,000 km above the equator, the authors investigated satellite-relayed medical imagings by video signals, with bone scintigraphy as a model. Each bone scintigraphy was taken by a handy-video camera, digitalized and transmitted from faculty of technology located at 25 kilometers apart from our department. Clear bone scintigraphy was obtained via satellite, as seen on the view box. Eight nuclear physicians evaluated 20 cases of bone scintigraphy. ROC (Receiver Operating Characteristic) analysis was performed between the scintigraphies on view box and via satellite by the rating method. The area under the ROC curve was 91.6#+-#2.6% via satellite, and 93.2#+-#2.4% on the view ...

134

Measurement of relative K X-ray intensity ratio following radioactive decay and photoionization  

International Nuclear Information System (INIS)

The measurements of the K X-ray intensity ratio I(K#alpha# _2/K#alpha# _1), I(K#beta# _1/K#alpha# _1) and I(K#beta#/K#alpha#) for elements V, Mn, Zn, Tc, Ru, Cd, Xe, Ba, Cs, Hg and Rn were experimentally determined both by photon excitation, in which 59.5 keV #gamma#-rays from a "2"4"1Am and 123.6 keV #gamma#-rays from a "6"0Co were used, and following the radioactive decay of "5"1Cr, "5"5Fe, "6"7Ga, "9"9Tc, "1"1"1In, "1"3"1I, "1"3"3Ba, "1"3"3Xe, "1"3"7Cs, "2"0"1Tl and "2"2"6Ra. K X-rays emitted by samples were counted by a Si(Li) detector with resolution 160 eV at 5.9 keV. Obtained values were compared with the theoretical values. It was observed that present values agree with the previous theoretical and other experimental results.

2007-01-01

135

Intracellular monitoring of superoxide dismutase expression in an Escherichia coli fed-batch cultivation using on-line disruption with at-line surface plasmon resonance detection.  

Science.gov (United States)

An on-line cell disruption system for at-line monitoring of the intracellular concentration of recombinant human superoxide dismutase (rhSOD) in a genetically modified Escherichia coli strain, HMS174(DE3) (pET11a/rhSOD), in bioreactor cultivations is described. The sampled bacteria were disrupted on-line by rapid mixing with a nonionic detergent. The recombinant protein content of the lysed bacterial sample was quantitated by a subsequent surface plasmon resonance biosensor with a specific monoclonal antibody. Extraction efficiency of the monitoring system was optimized with respect to the flow rate ratio of the cell suspension and the detergent at relevant cell densities with the aim to attain rapid monitoring. Monitoring was demonstrated for a shake flask culture and a glucose-limited fed-batch cultivation. The results are compared with a traditional enzyme-linked immunosorbent assay method showing a correlation coefficient of R2 = 0.97. Extraction efficiency of rhSOD reached 95-99% ...

2005-07-01

136

Interpreting the visible absorption bands of 1,4-(dihydroxy)-9,10-anthraquinone and its metal chelates.  

Science.gov (United States)

The visible absorption spectra of 1,4-(dihydroxy)-9,10-anthraquinone and of Co(II), Ni(II), Cu(II) and Zn(II) chelates have been studied in different organic solvents. This system provides a model for the anthracycline antibiotics and their metal chelates. The band structure of the spectrum has been determined using the second and fourth derivatives of the spectrum. The visible absorption band of the parent molecule can be assigned to a single electronic state with a reduced dipole moment in the excited state; structure in this band is ascribed to two overlapping vibrational progressions. In contrast, the dianion (hydroxy protons removed) shows a single electronic state with an increased dipole moment in the excited state; structure in this band can be assigned to a single vibrational progression. All of the metal chelates show spectra which are similar in appearance to that of the dianion although the identity of the metal determines the bathochromic shift of the absorption band. ...

1990-08-15

137

Glass-cordierite-mullite ceramics of low dielectric constant; Tworzywa szklano-kordierytowo-mulitowe o malej przenikalnosci elektrycznej  

Energy Technology Data Exchange (ETDEWEB)

Glass-ceramic materials containing 0-60% glass, 0-40% cordierite and 0-40% mullite were developed with dielectric constant lower than of Al{sub 2}O{sub 3} (5.2-6.7). The following glasses were used: SiO{sub 2}, CaO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-SiO{sub 2}, CaO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}, CaO-ZnO-B{sub 2}O{sub 3}, CaO-ZnO-Al{sub 2}O{sub 3}B{sub 2}O{sub 3}, BaO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-SiO{sub 2} and BaO-ZnO-Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-SiO{sub 2}. The influence of the content of the particular components on the value of dielectric constant of the ceramics was investigated. (author). 9 refs, 3 tabs.

1997-12-31

138

Estimation of frequency, population doses and stochastic risks in brachytherapy in Japan, 1983  

International Nuclear Information System (INIS)

Based on the replies to a questionnaire distributed throughout Japan in 1983, genetically significant dose (GSD), per Caput mean bone marrow dose (CMD), leukemogenically significant dose (LSD), malignantly significant dose (MSD), and per Caput effective dose equivalent (EDE) from using small sealed radiation sources for radiotherapy were estimated. Annual frequencies of brachytherapy were estimated to be 2.6 x 10"3 for men and 36.3 x 10"3 for women, with a total of 38.9 x 10"3. The annual frequencies of using afterloading technique were 0.3 x 10"3 for men and 18.8 x 10"3 for women, with a total of 19.1 x 10"3. The annual population doses per person were 7.9 nGy for GSD, 118 #mu#Gy for CMD, 19.3 #mu#Gy for LSD, 172 #mu#Gy for MSD, and 428 #mu#Gy for EDE. The annual collective effective dose equivalent was estimated to be 5.13 x 10"4 man Sv. (Namekawa, K.).

1988-01-01

139

Enhanced MALDI-TOF MS Analysis of Phosphopeptides Using an Optimized DHAP/DAHC Matrix  

Science.gov (United States)

Selecting an appropriate matrix solution is one of the most effective means of increasing the ionization efficiency of phosphopeptides in matrix-assisted laser-desorption/ionization time-of-flight mass spectrometry (MALDI-TOF-MS). In this study, we systematically assessed matrix combinations of 2, 6-dihydroxyacetophenone (DHAP) and diammonium hydrogen citrate (DAHC), and demonstrated that the low ratio DHAP/DAHC matrix was more effective in enhancing the ionization of phosphopeptides. Low femtomole level of phosphopeptides from the tryptic digests of ?-casein and ?-casein was readily detected by MALDI-TOF-MS in both positive and negative ion mode without desalination or phosphopeptide enrichment. Compared with the DHB/PA matrix, the optimized DHAP/DAHC matrix yielded superior sample homogeneity and higher phosphopeptide measurement sensitivity, particularly when multiple phosphorylated peptides were assessed. Finally, the DHAP/DAHC matrix was ...

2010-01-01

140

Economic Assessment of the Negative Impacts of Ozone on Crop Yields and Forest Production. A Case Study of the Estate Oestads Saeteri in Southwestern Sweden  

Energy Technology Data Exchange (ETDEWEB)

Ground level ozone concentrations, in combination with the prevailing climate, at the estate Oestads Saeteri in southwestern Sweden were estimated to reduce the yield of wheat and potato ranging between 5% and 10%. Occasionally, in years with the highest ozone concentrations and/or climatic conditions favoring high rates of ozone uptake to the leaves, yield loss levels above 10% may occur. Based on simple extrapolation, these ozone-induced reductions of crop yields at Oestads Saeteri represent a potential total annual yield loss in Sweden in the range of 24.5 million Euro for wheat and 7.3 million Euro for potato, respectively. A simulation of forest growth at Oestads Saeteri predicted that prevailing mean ozone exposure during 1993-2003 had the potential to reduce forest growth by 2.2% and the economic return of forest production by 2.6%. Using this value for extrapolation to the national level, the potential annual economic loss for Sweden due to negative impacts ...

2005-02-01

141

Easy access to 6-membered iminoalditols - important glycosidase inhibitors  

DEFF Research Database (Denmark)

Stereoselective methods for synthesising iminoalditols are still needed, as this class of compounds is known to contain strong glycosidase inhibitors. We have for some time investigated (1) the possibilities for using 2-amino-6-bromo-2,6-dideoxy-aldonolactones as starting materials for such compounds, since a substitution at C-6 by the 2-amino group should lead to the target molecules. We have found that treatment of mentioned 2-aminolacones with aqueous base gave 5- or 6-membered iminoalditols depending of the stereochemistry of the lactone, while under non aqueous conditions only formation of 6-membered iminoalditols were observed. The use of triethylamine in methanol thus gave methylesters of 6-membered iminouronic acids. Reduction of the ester group with sodium borohydride gave the target compounds. The mechanisms of the reactions will be discussed as well as specific results obtained. (1) Lundt, I. Top. Curr. Chem. 1997, 187, 117-156

142

Dynamics of accumulation and disappearance of cobalt-60 in wheat-soil system  

International Nuclear Information System (INIS)

The dynamics of transportation, accumulation, disappearance and distribution of "6"0Co in the wheat-soil system was studied by using isotope-tracer techniques for simulated pollutants, and the mathematical model of the behavior was established. Rescilts showed that (1) "6"0Co was transported rapidly in the system after the application on soil surface layer. The uptake of "6"0Co by wheat was mainly via root, and redistribution in all parts of wheat occurred consequently. The concentration in root was much higher than that in other parts of wheat plant. The specific activity of "6"0Co in wheat plant rapidly increased to a maximum value, then decreased. The specific activity of "6"0Co in each part of wheat plant was found in the order of root > straw > husk > seed. (2) "6"0Co is mainly detained with in 6cm of soil surface, and specific activity of "6"0Co in soil present a simple exponential declining with depth of soil. (3) The dynamic ...

2008-10-01

143

Comparison between children and adolescents with and without chronic benign pain: consultation rate and pain characteristics.  

Science.gov (United States)

The aim of the study was to determine whether children with chronic benign pain are in contact with their general practitioner (GP) more frequently than those without chronic benign pain. A random sample of children and adolescents aged between 0 and 18 years of age was drawn from the records of ten general practices. According to their responses to a pain questionnaire, subjects were assigned to the chronic benign pain group (n = 95) if they had pain of more than three months' duration, or to the control group (n = 105) if they had pain of less than three months' duration or no pain at all. All the subjects had an average GP consultation rate of 2.6 contacts per year. No significant age and sex differences were found. Chronic benign pain in childhood and adolescence is not related to increased use of healthcare services, suggesting that somatisation does not play a major role in children with chronic benign pain. PMID:12030664

2002-03-01

144

Capacitance behaviour of passive films on ferritic and austenitic stainless steel  

Energy Technology Data Exchange (ETDEWEB)

The electrochemical behaviour of passive films formed on one austenitic stainless steel (AISI 304) and one ferritic stainless steel (AISI 446) in solutions with pH between 0.6 and 8.4 was studied by capacitance measurements and photocurrent spectroscopy. Compositional characterization of the passive films was done by X-ray photoelectron spectroscopy. The capacitance increases with decreasing pH. Doping densities evaluated from Mott-Schottky plots are in the range 2-6 x 10{sup 20} cm{sup -3} and increased with the pH in the neutral/alkaline range while in pH 0.6, values above 10{sup 21} cm{sup -3} were found. The bandgap energy indicates two transitions, at 2.5-2.8 and 3.2 eV. The analytical data reveal that, as the pH increased, the films become enriched in Fe(II) and Fe(III), whereas the Cr(III) gradually decreases. The films formed at very low pH had a behaviour that contrasts with that of the films formed in the neutral/alkaline media. The films are described by ...

2005-03-01

145

Capacitance behaviour of passive films on ferritic and austenitic stainless steel  

International Nuclear Information System (INIS)

The electrochemical behaviour of passive films formed on one austenitic stainless steel (AISI 304) and one ferritic stainless steel (AISI 446) in solutions with pH between 0.6 and 8.4 was studied by capacitance measurements and photocurrent spectroscopy. Compositional characterization of the passive films was done by X-ray photoelectron spectroscopy. The capacitance increases with decreasing pH. Doping densities evaluated from Mott-Schottky plots are in the range 2-6 x 10"2"0 cm"-"3 and increased with the pH in the neutral/alkaline range while in pH 0.6, values above 10"2"1 cm"-"3 were found. The bandgap energy indicates two transitions, at 2.5-2.8 and 3.2 eV. The analytical data reveal that, as the pH increased, the films become enriched in Fe(II) and Fe(III), whereas the Cr(III) gradually decreases. The films formed at very low pH had a behaviour that contrasts with that of the films formed in the neutral/alkaline media. The films are described by a bilayer ...

2005-03-01

146

Bioaccumulation of trace metals in farmed fish from South China and potential risk assessment  

British Library Electronic Table of Contents (United Kingdom)

Concentrations of trace metals were determined in water, sediment, fish feed and two species of farmed fish, pompano and snapper, collected from Daya Bay and Hailing Bay of South China in July 2007 and January 2008. Total average concentrations of Cu, Pb, Zn, Cd, Cr, Hg and As were 1.6, 2.7, 27.3, 0.025, 0.62, 0.18 and 0.59?g/gdrywt in pompano and 1.5, 2.6, 23.6, 0.020, 0.55, 0.22 and 0.53?g/gdrywt in snapper. In general, the concentrations of all target metals except Hg were positively correlated with lipid contents whereas negative correlations were observed between the metal concentrations and fish body weights. Model calculation indicated that dietary uptake of Zn and Cd predominate their accumulation in snapper, accounting for 99.9% and 98.2% of the total inputs. Risk ...

2011-01-01

147

Beta-decay studies of neutron-rich Sc-Cr nuclei  

International Nuclear Information System (INIS)

The neutron-rich nuclei"5"7","5"8_2_1Sc,"5"8"-"6"0_2_2Ti,"6"0"-"6"3_2_3V,"6"2"-"6"6_2_4Cr have been produced at Ganil via interactions of a 61.8A MeV "7"6Ge beam with a "5"8Ni target. Beta-decay studies have been performed using combined #beta#- and #gamma#-ray spectroscopy. Half-lives have been determined and #beta#-decay schemes are proposed for "5"8Ti, "6"1V and "6"2Cr. From these studies, new hints for the existence of #beta#-decaying isomers in "6"0V and in "6"2Mn are provided. These results are compared to shell model calculations. The role of the #pi#f_7_/_2- #nu#f_5_/_2 proton-neutron interaction is examined through its influence on the lifetime values. (orig.)

2005-01-01

148

BWNT assessment of TRAC/PF1-MOD2  

International Nuclear Information System (INIS)

The TRAC/PFI-MOD2 Version 5.3 code was assessed against six FLECHT-SEASET forced reflood tests (31504, 31203, 31302, 31701, 34209, and 31922) and two cylindrical core test facility (CCTF) tests [C1-19 and C2-6]. The objective of this study was to evaluate the clad thermal response predictive capabilities of the code with the newly added reflood model under large-break loss-of-coolant accident (LOCA) conditions in a pressurized water reactor (PWR). The TRAC model for the FLECHT-SEASET test facility was developed from a RELAP5 model. The test section was modeled using a vessel component with 23 axial levels, 1 radial ring, and 1 azimuthal cell. Test inlet and exit conditions were modeled using fill and break components, respectively. The measured lower and upper plenum test conditions were input to the model. The electrically heated rod was modeled using a rod component with 22 axial mesh points. The axial boundary of each mesh point coincided with a fluid cell ...

1993-11-14

149

Application of Global and One-Dimensional Local Optimization to Operating System Scheduler Tuning  

CERN Document Server

This paper describes a study of comparison of global and one-dimensional local optimization methods to operating system scheduler tuning. The operating system scheduler we use is the Linux 2.6.23 Completely Fair Scheduler (CFS) running in simulator (LinSched). We have ported the Hackbench scheduler benchmark to this simulator and use this as the workload. The global optimization approach we use is Particle Swarm Optimization (PSO). We make use of Response Surface Methodology (RSM) to specify optimal parameters for our PSO implementation. The one-dimensional local optimization approach we use is the Golden Section method. In order to use this approach, we convert the scheduler tuning problem from one involving setting of three parameters to one involving the manipulation of one parameter. Our results show that the global optimization approach yields better response but the one- dimensional optimization approach converges to a solution faster than the global ...

2010-01-01

150

Analysis of semiconductor structures by nuclear and electrical techniques. Final technical report  

Science.gov (United States)

This report summarizes the results obtained under a contract from 1974 to 1977, focusing on silicide formation of thin metal films on a Si substrate. The main thrust of the effort was directed at: (1) Development of the data base on thin-film silicide formation, and the investigation of the influence of the Si substrate on the silicide formation. When taken in context with results of other studies, the data obtained exhibit a clear pattern of behavior among the various metal films, but the detailed picture appears to be complex; (2) Development of marker experiments by ion-implanted Ar or Xe markers; (3) Clarification of the role played by oxygen contamination in silicide formation; (4) Stability of silicide layers; (5) Reaction of metal layers with SiO/sub 2/; (6) Electrical characteristics of Pd/sub 2/Si; and (7) A computer program was written to synthesize backscattering spectra for thin-film samples composed of successive layers of uniform ...

1978-06-01

151

Alternate alloying for environmental resistance; Proceedings of the Symposium, New Orleans, LA, Mar. 2-6, 1986  

Energy Technology Data Exchange (ETDEWEB)

Papers are presented on the development of oxidation- and sulfidation-resistant ferritic alloys; the microstructural stability of sulfidation-resistant FeCrAl stainless steels around 500 C; age hardening in Fe-Mn-Al-C austenitic alloys; the oxidation/corrosion behavior of low-Cr Fe-Cr-Ni alloys containing Zr or Nb; the high temperature oxidation/corrosion of iron-based superalloys; and the role of Mo in the Na/sub 2/SO/sub 4/ induced corrosion of superalloys at high temperature. Topics discussed include the effect of variations of Co content on the cyclic oxidation resistance of selected Ni-base superalloys; high temperature oxidation of Fe based alloys; the morphological development of high temperature oxide scales of Fe-Mn-Al base alloys; and the oxidation of an Fe-Mn-Al-C alloy at 1000 C. Consideration is given to the corrosion properties of Fe-Mn-Al alloys; passive films formed on nonmagnetic Cr-Mn-N stainless steels in chloride containing environments; the tubo 25 nickel base ...

1987-01-01

152

A comparison with result of normalized image to different template image on statistical parametric mapping of ADHD children patients  

Energy Technology Data Exchange (ETDEWEB)

We studied 64 ADHD children patients group (4 {approx} 15 ys, mean age: 8 {+-} 2.6 ys. M/F: 52/12) and 12 normal group (6 {approx} 7 ys, mean age: 9.4 {+-} 3.4 ys, M/F: 8/4) of the brain had been used to analysis of blood flow between normal and ADHD group. For analysis of Children ADHD, we used 12 children's mean brain images and made Template image of SPM99 program. In crease of blood flow (P-value 0.05), the result of normalized images to Template image to offer from SPM99 program, showed significant cluster in inter-Hemispheric and occipital Lobe, in the case of normalized images to children template image, showed inter-hemispheric and parietal lobe.

2003-06-15

153

A comparative evaluation of electrical velocimetry and inert gas rebreathing for the non-invasive assessment of cardiac output  

British Library Electronic Table of Contents (United Kingdom)

Background When assessing the function of the cardiovascular system, cardiac output (CO) is a substantial parameter. For its determination, numerous non-invasive techniques have been proposed in the recent years including inert gas rebreathing (IGR) and impedance cardiography (ICG). The aim of our study was to evaluate whether a novel ICG algorithm (electrical velocimetry) and IGR can be used interchangeably in the clinical setting. Methods A total of 120 consecutive stable patients were included resulting in two pairs of repeated non-invasive cardiac output measurements. Results The mean CO was 5.0???1.2?l/min (range 2.6?8.6?l/min) using IGR and 4.4???1.1?l/min (1.7?7.4?l/min) using ICG, respectively. Bland?Altman analysis revealed an acceptable agreement with a mean bias of 0.6???1.2?l/m...

2011-01-01

154

The effects of a calcium deficient diet on the mechanical properties and morphology of goose bone.  

Science.gov (United States)

A control group of geese (Anser anser) on a normal calcium diet for egg laying poultry was compared to egg laying geese on a calcium deficient diet. The ultimate compressive strength and modulus of elasticity of femoral cortical bone from each group were determined by compressing right circular cylinders which were 2.4 mm in height and 0.8 mm in diameter. The bending strength and bending modulus of elasticity of tibial cortical bone were determined by three point bend tests on rectangular prisms which were approximately 25 mm by 0.8 mm by 0.8 mm. Bone calcium content and eggshell calcium content were determined by atomic absorption spectrophotometry. Blood samples were analyzed for free calcium ion concentration. Histological observations included studies of cross-sectional microradiographs, examinations of cross sections stained by a modified Masson's technique, and a determination of fractional area of voids by quantitative microscopy. The average compressive modulus for the control ...

1986-01-01

155

Structures and luminescent properties of new uranyl-based hybrid materials  

International Nuclear Information System (INIS)

Six uranyl coordination compounds, UO_2(OH)(PYCA) (1), UO_2(PYCA)_2(H_2O).2H_2O (2), UO_2(PIC)_2 (3), UO_2(H_2O)_2(NIC)_2 (4), UO_2(OH)(HINIC)(INIC) (5), and UO_2(PYTAC)_2(H_2O)_2 (6) were grown as single crystals via hydrothermal synthesis (PYCA - pyrazine-2-carboxylate, PIC - picolinate, NIC - nicotinate, INIC - iso-nicotinate, and PYTAC - 2-(pyridin-4-yl)thiazole-5-carboxylate) to study their optical properties. All six compounds have been identified via single crystal X-ray diffraction and fully characterized via powder X-ray diffraction, infrared spectroscopy, UV-Vis spectroscopy, and fluorescence spectroscopy. Three of the complexes, 1, 3, and 6, represent new structures, and their synthesis and structural characterization is detailed within. The structures of 2, 4, and 5 have previously been reported in the literature. Coordination polymer 1 crystallizes in the orthorhombic space group Pca21 (a = 13.5476(5) Angstroms, b = 6.6047(2) ...

2011-06-01

156

Evaluation of the hemodynamics of the femoral head compared with the ilium, femoral neck and femoral intertrochanteric region in healthy adults. Measurement with positron emission tomography (PET)  

International Nuclear Information System (INIS)

Non-traumatic osteonecrosis of the femoral head (ONF) is considered to be a disease that occurs primarily due to ischemia of the femoral head, while its etiology and pathology are not fully understood. It is therefore necessary to identify the characteristics of the hemodynamics of the femoral head. In this study, the hemodynamics in the ilium and proximal regions of the femur, including the femoral head, was investigated using positron emission tomography (PET). The subjects of this study consisted of 8 hip joints of four healthy male adults and 3 hip joints on the contralateral side of a femoral neck fracture, avulsion fracture of the greater trochanter and coxarthrosis (1 case each, all females) for a total of 11 hip joints of 7 subjects. The ages of the subjects ranged from 25 to 87 years (average age: 54 years). Blood flow was measured by means of the H_2"1"5O dynamic study method and blood volume was measured by means of the "1"5O-labeled carbon monoxide bolus inhalation method. ...

2005-10-01

157

Review of JT-60U experimental results from February to October, 1999  

International Nuclear Information System (INIS)

In 1999, the plasma parameters of reversed shear (RS) plasmas had been extended in 1) DT-equivalent fusion power gain Q_D_T"e"q - 0.5 (n_D(0)#tau#_ET_i(0) - 4x10"2"0 m"-"3#centre dot#keV#centre dot#s) for 0.8 s and 2) full non-inductive current drive with 80% of the bootstrap current fraction. Physics of the internal transport barriers (ITBs) in RS plasmas, including the energy transport and the formation of ITB, were extensively studied. A nearly full current drive (92% non-inductively) was obtained with negative ion based neutral beam (NNB) injection (360 keV, 3.4 MW) in a high #beta#_p H-mode plasma (I_p=1.5 MA, B_T=3.7 T, q_9_5=4.2) with high plasma performance (#beta#_N=2.4 and H_8_9=2.56). Rise in the central electron temperature (T_e - 9 keV) resulted in the current drive efficiency #eta#_C_D of NNB reached 1.3x10"1"9 A/W/m"2, the highest for the neutral beam current drive. As for the H-mode plasmas, decrease in the pedestal ion temperature due to strong gas was found cause ...

1994-06-01

158

High efficiency power production from biomass and waste  

Energy Technology Data Exchange (ETDEWEB)

Two-stage gasification allows power production from biomass and waste with high efficiency. The process involves pyrolysis at about 550C followed by heating of the pyrolysis gas to about 1300C in order to crack hydrocarbons and obtain syngas, a mixture of H2, CO, H2O and CO2. The second stage produces soot as unwanted by-product. Experimental results are reported on the suppression of soot formation in the second stage for two different fuels: beech wood pellets and Rofire pellets, made from rejects of paper recycling. Syngas obtained from these two fuels and from an industrial waste fuel has been cleaned and fed to a commercial SOFC stack for 250 hours in total. The SOFC stack showed comparable performance on real and synthetic syngas and no signs of accelerated degradation in performance over these tests. The experimental results have been used for the design and analysis of a future 25 MWth demonstration plant. As an alternative, a 2.6 MWth system was considered ...

2008-11-15

159

The effect of nickel on irradiation hardening of pressure vessel steels  

International Nuclear Information System (INIS)

An experimental investigation of the effect of nickel content on irradiation hardening of reactor pressure vessel steels was conducted. The alloys studied, with nickel contents ranging from 0 to 1.7%, included five sets of steels representing variations in copper contents and other metallurgical variables. Various subsets of the alloys were irradiated at selected combinations of flux, fluence, and irradiation temperature. Irradiation hardening was measured by either changes in the uniaxial yield stress or diamond pyramid hardness. Higher hardening rates with increasing nickel were observed in controlled experiments on commercial-type steels containing high copper concentrations (0.4% Cu). The effect of nickel increased with increasing fluence and decreasing temperature. At high fluence (>10"1"9 n/cm"2) the hardening increased with nickel at an average rate of about 100 MPa/%Ni. There also appeared to be an influence of heat treatment on the nickel sensitivity of these alloys. ...

1988-06-27

160

The OECD/NEA TDB review on nickel  

Energy Technology Data Exchange (ETDEWEB)

Nickel is present in radioactive waste (as activation products {sup 59}Ni and {sup 63}Ni) besides being an element widely distributed in the geosphere and considered for alloys in the engineered barrier systems for underground repositories. For these reasons, within the scope of the OECD Nuclear Energy Agency (NEA) Thermochemical Data Base (TDB) Project a comprehensive review of thermodynamic data has been carried out by the present authors [1]. Over 700 original bibliography sources have been considered, resulting in recommended data for over 50 inorganic species and compounds. Central to the new database are the selections for {delta}{sub f}G{sub m}{sup 0}(Ni{sup 2+}, 298.15 K), established on the basis of re-evaluations of potentiometric data for Ni{sup 2+} | Ni (cr) and S{sub m}{sup 0}(Ni{sup 2+}, 298.15 K) established on the dissolution equilibria for NiSO{sub 4}.7H{sub 2}O(cr). The resulting value for {delta}{sub f}H{sub m}{sup 0}(Ni{sup 2+}, 298.15 K) is consistent with the ...

2005-07-01

161

Structure-activity relationships of anthraquinones on the suppression of DNA-binding activity of the aryl hydrocarbon receptor induced by 2,3,7,8-tetrachlorodibenzo-p-dioxin.  

Science.gov (United States)

Anthraquinones are widely present in plant kingdom, and clinically used as laxatives. Environmental contaminants, dioxins, develop various adverse effects through transformation of a cytosolic aryl hydrocarbon receptor (AhR). We investigated the effects of 18 anthraquinones and 7 of their structurally related compounds on transformation of the AhR estimated by its DNA-binding activity in the cell-free system. 1,4-Dihydroxyanthraquinone (quinizarin), 1,5-dihydroxyanthraquinone (anthrarufin), 1,8-dihydroxyanthraquinone (danthron), and 5-hydroxy-1,4-naphthoquinone (juglone) strongly suppressed DNA-binding activity of the AhR induced by 0.1 nM 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD), with their IC(50) values around 1 muM. On the other hand, anthraquinone, 2,6-dihydroxyanthraquinone (anthraflavic acid), and 2-hydroxy-1,4-naphthalendione (lawsone) showed moderate effects. Quantitative structure-activity relationships analysis demonstrated that hydroxyl groups at C1 or ...

2009-03-01

162

Separation and determination of cadmium and zinc as their thenoyltrifluoroacetone complexes with dibenzo-18-crown-6 by means of synergistic extraction and atomic absorption spectrometry  

Energy Technology Data Exchange (ETDEWEB)

A new method for the separation and determination of trace amounts of cadmium and zinc in water as their thenoyltrifluoroacetone (TTA) complexes with dibenzo-18-crown-6 (DB18C6) in o-dichlorobenzene has been established by means of synergistic extraction and back-extraction combined with atomic absorption spectrometry. The effect of various factors (synergism with TTA and DB18C6, shaking time, composition of the extracted species, and mutual separation etc.) on the extraction and back-extraction of cadmium and zinc has been in- vestigated. When the mixtures were extracted for 4 min at pH 4.9, only zinc was extracted quantitatively, whereas cadmium remained in the aqueous phase. After the phases were separated, cadmium was again extracted quantitatively at pH 7.5. Then, the two phases were each shaken with 0.05-0.1 mol/l HCl in order to back-extract cadmium and zinc from the organic phases; the ions were determined individually by atomic absorption spectrometry. In the process cadmium ...

1997-01-01

163

Seasonal variations in photosynthetic response of algae epiphytic on Myriophyllum spicatum L  

Energy Technology Data Exchange (ETDEWEB)

The photosynthetic response to light of epiphytic algae from Lake Wingra, Wisconsin was determined monthly during the 1978 and 1979 growing seasons.A /sup 14/C technique was developed for measurement of photosynthesis of the intact epiphyte community which was then removed by shaking. The photosynthetic rate at low light, ..cap alpha.., varied from 5.56 to 18.26 ..mu..g C (mg Chl a)/sup -1/ h/sup -1/ (..mu..Em/sup -2/s/sup -1/)/sup -1/ while P/sup B//sub max/, the photosynthetic rate at light saturation, ranged from 1.0 to 2.6 mg C (mg Chl a)/sup -1/ h/sup -1/. During 1979, variations in ..cap alpha.. and P/sup B//sub max/ followed the sun-shade model for photosynthetic adaptation: P/sup B//sub max/ was highest in summer and lowest in spring and fall, while ..cap alpha.. followed the opposite pattern. Patterns in ..cap alpha.. and P/sup B//sub max/ for 1978 were less apparent. During 1979, P/sup B//sub max/ was significantly correlated with both temperature and ...

1982-07-01

164

Radiotherapy in Ewing's sarcoma and PNET of the chest wall: results of the trials CESS 81, CESS 86 and EICESS 92  

International Nuclear Information System (INIS)

Purpose: Treatment results and the pattern of relapse were evaluated in the multimodal treatment of Ewing's sarcomas of the chest wall. Methods and Materials: In a retrospective analysis, 114 patients with non-metastatic Ewing's sarcoma of the chest wall were evaluated. They were treated in the CESS 81, CESS 86, or EICESS 92 studies between January 1981 and December 1993. The treatment consisted of polychemotherapy (VACA, VAIA, or EVAIA) and local therapy, either surgery alone (14 patients), radiotherapy alone (28 patients) or a combination of both (71 patients). The median follow-up was 46.6 months (range 5-170). A relapse analysis for all patients with local or combined relapses was performed. Results: Overall survival was 60% after 5 years, event-free survival was 50%. Thirty-seven patients had a systemic relapse (32.4%), 11 patients had a local relapse alone (9.6%), and 3 patients had a combined local and systemic relapse (2.6%). The risk to relapse locally ...

1998-12-01

165

Radiolytic stabilization of industrial poly(methyl methacrylate); Estabilizacao radiolitica do poli(metacrilato de metila) industrial  

Energy Technology Data Exchange (ETDEWEB)

Poly(methyl methacrylate), PMMA, Acrigel, a Brazilian polymer, is used in the manufacture of medical supplies sterilisable by ionizing radiation. However, when PMMA is gamma-irradiated it undergoes main chain scissions, which promote molecular degradation causing reduction in its physical properties. Therefore, radiolytic stabilization of PMMA is important for to become it commercially radio sterilisable. In this work we investigated the radiolytic stabilization of PMMA by using HALS (Hindered Amine Light Stabilizer) additive, commercially used for photo and thermo oxidative stabilization of polymers. The investigation of the radiation-induced main chain scissions was carried out by viscometric method. The additive added to the polymer system at 0.3 % w/w promotes a molecular radioprotection of 61%. That means a reduction of G value (scissions/100 eV) from 2.6 to 1.0. In addition, the glassy transition temperature (Tg) of PMMA (no additive), significantly changed ...

2005-03-15

166

Radiochemical Analyses of the Filter Cake, Granular Activated Carbon, and Treated Ground Water from the DTSC Stringfellow Superfund Site Pretreatment Plant  

Energy Technology Data Exchange (ETDEWEB)

The Department of Toxic Substance Control (DTSC) requested that Lawrence Livermore National Laboratory (LLNL) evaluate the treatment process currently employed at the Department's Stringfellow Superfund Site Pretreatment Plant (PTP) site to determine if wastes originating from the site were properly managed with regards to their radioactivity. In order to evaluate the current management strategy, LLNL suggested that DTSC characterize the effluents from the waste treatment system for radionuclide content. A sampling plan was developed; samples were collected and analyzed for radioactive constituents. Following is brief summary of those results and what implications for waste characterization may be made. (1) The sampling and analysis provides strong evidence that the radionuclides present are Naturally Occurring Radioactive Material (NORM). (2) The greatest source of radioactivity in the samples was naturally occurring uranium. The sample results indicate that the uranium ...

2005-09-16

167

Radiochemical Analyses of the Filter Cake, Granular Activated Carbon, and Treated Ground Water from the DTSC Stringfellow Superfund Site Pretreatment Plant  

International Nuclear Information System (INIS)

The Department of Toxic Substance Control (DTSC) requested that Lawrence Livermore National Laboratory (LLNL) evaluate the treatment process currently employed at the Department's Stringfellow Superfund Site Pretreatment Plant (PTP) site to determine if wastes originating from the site were properly managed with regards to their radioactivity. In order to evaluate the current management strategy, LLNL suggested that DTSC characterize the effluents from the waste treatment system for radionuclide content. A sampling plan was developed; samples were collected and analyzed for radioactive constituents. Following is brief summary of those results and what implications for waste characterization may be made. (1) The sampling and analysis provides strong evidence that the radionuclides present are Naturally Occurring Radioactive Material (NORM). (2) The greatest source of radioactivity in the samples was naturally occurring uranium. The sample results indicate that the uranium concentration ...

168

Preoperative staging of rectal carcinoma with combined sonography and pelvic computed tomography  

International Nuclear Information System (INIS)

The accurate staging of rectal carcinoma is very important for treatment planning. The histological data obtained from surgical specimens of 22 patients with rectal carcinoma were compared with pre-and postoperative endorectal US findings and with preoperative CT results. According to an adapted version of Astler and Coller classification, the different degrees of tumor spread into the rectal wall were represented as follows: stage A: 1 patient; stage B1: 5 patients; stage B2: 6 patients; stage C1: 1 patient; stage C2: 8 patients and stage D: 1 patient. Preoperative staging, based on the overall results of CT and US, was in agreement with histology in 19 of 22 cases. Individual analysis of US and CT results, in comparison with histological data, showed US staging accuracy to be 77.3% (17/22 patients). US accuracy in demonstrating tumor spread into the rectal wall (stages A, B1, C1) was 100% (7/7 patients); US was 70% accurate in lymph node ...

1991-01-01

169

Porous silica ceramics prepared by sol-gel process-effect of H{sub 2}O/TEOS molar ratio-  

Energy Technology Data Exchange (ETDEWEB)

porous silica ceramics were prepared(with HCL catalyst)using H{sub 2}O/TEOS molar ratios of 2.6-59.0, with the EtOH/TEOS ratio fixed. After preparing 9 kinds of sol, the followings were investigated; measurement of the gelation time, thermal analyses by TG/DTA, property analyses of the intermediates by FT-IR and X-ray diffractometry with dried samples, analyses of SiO{sub 2} polymer by FT-IR, the investigation of specific surface area and pore size distribution by N{sub 2}-adsorption isotherm, and structural change of SiO{sub 2} polymer and pore morphology by TEM observation, with samples heat-treated to 500 deg. C. In the concentrations of investigated compositions and catalyst, gelation time showed a minimum at ca. 11 moles of water per one mole of TEOS, the highest degree of polymerization at ca.8-18 moles, and the largest specific surface area at ca. 11 moles, which means that the polymerization proceeded fastest at ca. 11 moles of water. In conclusion, the ...

1997-02-01

170

Photoluminescent properties of heteroleptic cyclometalated platinum(II) complexes bearing 1,3-bis(3,4-dibutoxyphenyl)propane-1,3-dionate as an ancillary ligand  

Energy Technology Data Exchange (ETDEWEB)

A new series of heteroleptic cyclometalated platinum(II) complexes Pt-1a-f was synthesized, employing 2-arylpyridine (or 1-arylisoquinoline) (HC{sup L}AMDAN-1) and 1,3-bis(3,4-dibutoxyphenyl)propane-1,3-dione (HO{sup L}AMDAO-1) for cyclometalation and as ancillary ligands, respectively, and photoluminescent properties were investigated. Focusing on red-shifted phosphorescence, C{sup L}AMDAN ligands containing pi-extended aromatics and electron-rich heterocycles were examined. All obtained complexes exhibited photoluminescence at ambient temperature, and the emission maxima ranged from green (lambda{sub PL}=518 nm) to far red (lambda{sub PL}=708 nm). The large Stokes shifts of more than 100 nm and sub-microsecond or microsecond emission lifetimes revealed that these complexes are phosphorescent emissive. The quantum yield of Pt-1 ranged from 0.02 to 0.59 at ambient temperature and decreased as the emission maximum was red-shifted. In comparison with the reference platinum(II) complexes, ...

2010-02-15

171

PRELIMINARY CROSS SECTION AND NU-BAR COVARIANCES FOR WPEC SUBGROUP 26  

Energy Technology Data Exchange (ETDEWEB)

We report preliminary cross section covariances developed for the WPEC Subgroup 26 for 45 out of 52 requested materials. The covariances were produced in 15- and 187-group representations as follows: (1) 36 isotopes ({sup 16}O, {sup 19}F, {sup 23}Na, {sup 27}Al, {sup 28}Si, {sup 52}Cr, {sup 56,56}Fe, {sup 58}Ni, {sup 90,91,92,94}Zr, {sup 166,167,168,170}Er, {sup 206,207,208}Pb, {sup 209}Bi, {sup 233,234,236}U, {sup 237}Np, {sup 238,240,241,242}Pu, {sup 241,242m,243}Am, {sup 242,243,244,245}Cm) were evaluated using the BNL-LANL methodology. For the thermal region and the resolved and unresolved resonance regions, the methodology has been based on the Atlas-Kalman approach, in the fast neutron region the Empire-Kalman method has been used; (2) 6 isotopes ({sup 155,156,157,158,160}Gd and {sup 232}Th) were taken from ENDF/B-VII.0; and (3) 3 isotopes ({sup 1}H, {sup 238}U and {sup 239}Pu) were taken from JENDL-3.3. For 6 light nuclei ({sup 4}He, ...

2007-01-31

172

Optical properties of crystalline and non-crystalline iron oxide thin films deposited by spray pyrolysis  

International Nuclear Information System (INIS)

Crystalline and non-crystalline iron oxide (#alpha#-Fe_2O_3) thin films were obtained by spray pyrolysis onto glass substrate at different temperatures. The results of X-ray diffraction showed that with increasing the deposition time, the film structure changed from non-crystalline to crystalline at the same substrate temperature. At different substrate temperatures and low deposition times (5 min), iron oxide appears almost in non-crystalline form. With rising the substrate temperature and deposition time, the crystallinity was improved. The effect of substrate temperature as well as deposition time on the optical features (absorption coefficient and bandgap) and optical constants of these films has been investigated. Optical constants of the films were determined from spectrophotometric measurement of reflectance and transmittance. Analysis of the results showed that, for non-crystalline iron oxide films of different thicknesses (76-118 nm) deposited at deposition time 5 min at a ...

2004-06-30

173

Open top chamber experiment ``Edelmannshof``: carbohydrate and energy metabolism in needles and trunks from Norway spruce fumigated with unfiltered or charcoal-filtered air in comparison with untreated trees  

Energy Technology Data Exchange (ETDEWEB)

As part of a five-year-lasting open-top-chamber experiment at the `Edelmannshof` site (Welzheimer Wald) we analyzed Norway spruce trees (Picea abies (L.) Karst.) with regard to carbohydrate and energy (ATP/ADP ratio) metabolism. End products, intermediates, and a regulator of carbon allocation (starch, sucrose, hexoses, fructose-2,6-bisphosphate) as well as enzyme activities involved in sucrose metabolism (sucrose-P synthase, sucrose synthase, acid invertase) were determined in needle and trunk samples of the different treatments (charcoal-filtered, unfiltered, ambient air). Changes of these parameters were documented annually and with regard to needle development (up to 2 years after bud break), and diurnally during an ozone period in midsummer. Samples from trees grown in an unfiltered atmosphere showed relatively high sucrose and hexose contents of the needles. The capacities of sucrose-P synthase (increased; sucrose synthesis) and acid invertase (decreased; ...

1997-12-01

174

Occupational exposure to natural radionuclides due to mining activities in Ibadan, Southwestern Nigeria  

International Nuclear Information System (INIS)

The activity concentrations of potassium, uranium and thorium in minerals and soil samples from a mining site in Ibadan, Southwestern Nigeria were measured using gamma ray spectroscopy method. Effective dose per annum has been calculated from the activity concentrations of dominant gamma-emitting natural radionuclides, potassium, uranium and thorium. Samples collected include minerals (beryl, quartz and feldspar), soil samples from the mining pits, heaps and undisturbed land around the mining site. The activity concentrations of "4"0K, "2"3"8U and "2"3"2Th, respectively in Bq kg-1 in the mineral samples were as follows: 1985 #+-# 16, 4.8 #+-# 0.9 and 11.8 #+-# 5.8 for beryl sample, 115.1 #+-# 27.9, 5.0 #+-# 1.3 and 6.3 #+-# 5.0 for feldspar samples and 1421 #+-# 122, <4.8 and 20.1 #+-# 3.5 for quartz samples. For the soil samples, the mean activity concentrations of "4"0K, "2"3"8U and "2"3"2Th, respectively, were 314.2 #+-# 5.7, 27.7 #+-# 2.6 and 11.5 #+-# 5.9 ...

175

Neutron reflectometry study of surface segregation in an isotopic poly(ethylene propylene) blend : deviation from mean field theory.  

Energy Technology Data Exchange (ETDEWEB)

Neutron reflectometry (NR) was used to measure the concentration profile of a symmetric PEP/dPEP polymer blend with nanometer-scale resolution in the one-phase region. The shape of the profile near the surface was found to differ significantly from mean-field theory predictions for all bulk concentrations and temperatures surveyed. The profile shape is flattened at the surface over a distance about half the bulk correlation length, a length scale far greater than that of the dispersive forces that are the dominant microscopic interaction in such blends. We introduce a new method for extracting the surface energy difference that drives segregation based on the Gibbs adsorption equation (GAE) and compare it to a previous method based on mean-field theory. While both methods produce qualitatively similar results (the surface energy of pure dPEP is {approx}0.21 mJ/m{sup 2} smaller than pure PEP), the GAE method is much less model dependent, requiring knowledge of only the free energy of ...

1995-12-04

176

Mechanisms of cobalt uptake in plants: "6"0Co uptake and distribution in Chara  

International Nuclear Information System (INIS)

The mechanism of cobalt uptake was investigated using cells of the giant alga Chara corallina in which it is possible to resolve separately uptake by the cell wall and actual influx across the cell membrane. The absorption of "6"0Co by Chara cells appeared to saturate within 2 h. but this was mainly due to rapid uptake into the cell wall which accounted for 87-92% of the total activity. Even after prolonged desorption most of the cell-associated "6"0Co was found on the cell wall. The intracellular distribution of absorbed "6"0Co was investigated by fractionating the cell into cytoplasm and vacuole. It was shown that "6"0Co influx to the vacuole occurs simultaneously with influx to the cytoplasm. The transported species appears to be Co"2"+ rather than the less charged Co(OH)"+ or Co(O)_2. "6"0Co influx is pH dependent (optimum pH 7-9), and is sensitive to some other divalent metals. Influx from solutions containing 1 #mu#M "6"0Co was inhibited ...

1998-01-01

177

Magnetization and magnetic susceptibilities of GdH_3, HoH_3, ErH_3 and YbH_3  

International Nuclear Information System (INIS)

The magnetic susceptibility of powdered samples of HoH_3, ErH_3, GdH_3 and YbH_3 have been measured in the temperature range from 4.2 to 1.2 K. Two broad, local maxima are observed in the variation of chi versus T for GdH_3, with maxima in (delta chi/delta T) versus T at 1.8 K and 3.3 K. The inverse susceptibilities for HoH_3 and ErH_3 both obey a Curie--Weiss law over a limited range (4.2 to 2.6 K and 4.2 to 2 K, respectively) with values for the Weiss constant of -4.25 K and -1.11 K, and effective moments of 8.6 and 7.7 Bohr magnetons, respectively. The susceptibility of YbH_3 is independent of temperature over the range investigated. High-field magnetization measurements yield extrapolated saturation moments of 7.0 +- 0.25 Bohr magnetons/ion for GdH_3, 6.1 +- 0.2 Bohr magnetons/ion for HoH_3 and 3.74 +- 0.11 Bohr magnetons/ion for ErH_3. In addition, ErH_3 exhibits a van Vleck paramagnetism in the high-field region.

1976-03-29

178

Luminescence and laser transition studies of Dy3+:K-Mg-Al fluorophosphate glasses  

International Nuclear Information System (INIS)

Dysprosium ion doped fluorophosphate glasses with compositions of PKMAFDy: (56-x/2) P2O5+17K2O+8Al2O3+(15-x/2)MgO+4AlF3+xDy2O3 (x=0.01, 0.05, 0.1, 1.0 and 2.0 mol%) have been prepared by melt quenching technique and are characterized by optical absorption, emission spectra and fluorescence lifetime measurements. The observed bands in the absorption spectrum are analysed by using free-ion Hamiltonian (HFI) model. The Judd-Ofelt (JO) analysis has been performed and the intensity parameters (??, ?=2, 4, 6) have been evaluated that are used to predict radiative properties. From emission spectra, the effective bandwidth (??eff) and the stimulated emission cross-section (?(?p)) were evaluated. The fluorescence decay from the 4F9/2 level of Dy3+ ions have been measured by monitoring the intense 4F9/2#->#6H13/2 transition (573 nm). The lifetimes (?) are found to decrease with increasing concentration due to concentration quenching. The decay curves are single ...

2009-02-28

179

Isothermal heat measurements of TBP-nitric acid solutions  

Energy Technology Data Exchange (ETDEWEB)

Net heats of reaction were measured in an isothermal calorimeter for both single phase (organic) and two phase (organic and aqueous) TBP/HNO{sub 3} reacting solutions at temperatures above 100 C. The oxidation rate constant was determined to be 5.4E-4 min{sup {minus}1} at 110 C for an open ``vented`` system as compared to 1.33 E-3 min{sup {minus}1} in the closed system. The heat released per unit material oxidized was also reduced. The oxidation in both phases was found to be first order in nitric acid and pseudo-zero order in butylnitrate and water. The hydrolysis (esterification) rate constant determined by Nichols` (1.33E-3 min{sup {minus}1}) fit the experimental data from this work well. Forced evaporation of the volatile components by the product gases from oxidation resulted in a cooling mechanism which more than balanced the heat from the oxidation reaction in the two-phased systems. Rate expressions were derived and rate constants determined for both the single and two phase ...

1994-12-16

180

Greenhouse gas emissions from the international maritime transport of New Zealand's imports and exports  

International Nuclear Information System (INIS)

Greenhouse gas emissions from international maritime transport are exempt from liabilities under the Kyoto Protocol. Research into quantifying these emissions is ongoing, and influences policy proposals to reduce emissions. This paper presents a cargo-based analysis of fuel consumption and greenhouse gas emissions from New Zealand's international maritime transport of goods. Maritime transport moves 99.5% (by mass) of New Zealand's internationally traded products. It is estimated that 73% of visiting vessels' activity can be directly attributed to the movement of goods in and out of New Zealand. A cargo-based methodology was used to estimate that the international maritime transport of New Zealand's imports and exports consumed 2.5 million tonnes (Mt; 2.6 billion litres) of fuel during the year 2007, which generated 7.7 Mt of carbon dioxide (CO_2) emissions. Double-counting of emissions would occur if a similar method was applied to all New Zealand's trading ...

2011-03-01

181

Four years of North American registry home parenteral nutrition outcome data and their implications for patient management  

International Nuclear Information System (INIS)

The OASIS Registry started annual collection of longitudinal data on patients on home parenteral nutrition (HPN) in 1984. This report describes outcome profiles on 1594 HPN patients in seven disease categories. Analysis showed clinical outcome was principally a reflection of the underlying diagnosis. Patients with Crohn's disease, ischemic bowel disease, motility disorders, radiation enteritis, and congenital bowel dysfunction all had a fairly long-term clinical outcome, whereas those with active cancer and acquired immunodeficiency syndrome (AIDS) had a short-term outcome. The long-term group had a 3-year survival rate of 65 to 80%, they averaged 2.6 complications requiring hospitalization per year, and 49% experienced complete rehabilitation. The short-term group had a mean survival of 6 months; they averaged 4.6 complications per year and about 15% experienced complete rehabilitation. The registry data also indicated HPN was used for 19,700 patients in 1987 with ...

182

Extraction behavior of short-lived isotopes of Mo/W using #alpha#-benzoinoxime: a model system for the study of seaborgium  

International Nuclear Information System (INIS)

The liquid-liquid extraction behavior of short-lived molybdenum and tungsten isotopes from HCl and HNO_3 as well as HF/HNO_3 acid media was studied using the #alpha#-benzoinoxime/chloroform system. The goal of the present experiments was to find an extraction system with a high selectivity for the group 6 elements in the periodic table which is suitable for the study the solution chemistry of seaborgium (Z = 106). It was found that Mo and W are both effectively extracted using #alpha#-benzoinoxime as an extractant and the maximum extraction yield is 100% and 94% for Mo and W, respectively. Ions of MO_2"2"+ (M = Mo, W) exist in HCl between the concentration range of 0.1-3 M and can be extracted quantitatively into the organic phase. The decrease of extraction yields at lower or higher acid concentration is due to the formation of anionic species MO_4"2"- or MO_2Cl_3"-. The extraction behavior of Mo and W in HNO_3 solution is similar to that in HCl solution. In HNO_3/HF mixed acid ...

183

Experiences in radioactive gaseous effluent management in JAERI  

International Nuclear Information System (INIS)

In the Japan Research Reactor-II (JRR-2), the main source of _4_1Ar generation is the exhaust air from the horizontal experimental holes and the pneumatic tubes. For the horizontal experimental holes, the flow of exhaust air through the holes was decreased by improving the airtightness, and a decay duct of capacity 2.4 m_3 was installed in the middle of the exhaust line. In consequence, the release rate of _4_1Ar was reduced by 6-8%. For the pneumatic tubes, a mechanical shutter was installed in the tube. The shutter stops the exhaust air flow, except when the pneumatic tube is used. Prior to the use, the activated air in the tube is led to a decay tank. As a result, the _4_1Ar release rate was reduced by 10-20%. By the above means, the yearly exposure at the site boundary was reduced to 0.36 mR from 2.6 mR. In Hot Laboratory for metallurgical examination of spent fuel, the exhaust filtration system consists of filters in the cave, i.e. frame trap, prefilter, HEPA ...

1983-05-01

184

Effects of irradiation on the microstructural evolution and corrosion resistance of zirconium alloys  

International Nuclear Information System (INIS)

Zircaloy-2 and Zircaloy-4 tubing materials were irradiated with 1 MeV proton at 350 degrees C to doses of 0.01, 0.1, and 1 dpa respectively. Both microstructure examination and nodular corrosion test (500 degrees C, 1500 psi steam) were performed in order to understand the relationship between the microstructural evolution and the corrosion resistance of these alloys under irradiation. Neutron-irradiated Zircaloy-2 specimens which were obtained from a failed BWR fuel rod cladding were also studied. Specimens of three different neutron fluences were investigated; namely, 2.6x10"2"4, 3.2x10"2"5, 3.8x10"2"5, (E_n#>=#1MeV). The results indicated that the higher the irradiation dose the better the nodular corrosion resistance of both Zircaloy-2 and Zircaloy-4. It is concluded that irradiation-induced precipitate dissolution and irradiation-enhanced diffusion may increase the solute concentration in the matrix and make it distributed more evenly which in turn ...

1991-08-25

185

Effects of antioxidants on lipid peroxide formation in irradiated synthetic diets  

International Nuclear Information System (INIS)

The effects of the antioxidants, vitamin E, propyl gallate, 2-t-butyl-4-methoxy phenol (BHA), 2,6-di-t-butyl-4-methoxy phenol (BHT), nor-dihydroguaiaretic acid (NDGA) and diphenyl-p-phenylene diamine (DPPD) in concentrations ranging between 0.001 per cent and 0.1 per cent have been tested on lipid peroxide formation in synthetic diet mixtures containing herring oil (10 per cent) mixed with starch (90 per cent) irradiated with #gamma#-ray doses of 100 to 2000 krad. On a weight basis NDGA, DPPD, BHA and BHT were most effective and vitamin E and propyl gallate were least effective. An antioxidant concentration of 0.01 per cent normally protected against peroxide formation after a dose of 500 krad but if the dose was increased to 1000 or 2000 krad, much higher doses of antioxidant, up to 0.1 per cent, were required to give protection. Antioxidants prevented peroxide developing during post-irradiation storage even when added after irradiation. Antioxidants were ...

186

Effect of soil amendments and crop varieties on the amelioration of heavy metal uptake into crops grown on polluted soils of Bangladesh  

International Nuclear Information System (INIS)

Bangladesh possesses many industrial sites, whereby wastes and effluents are directly discharged into the environment without any treatment. Agricultural areas are contaminated thereby and the food quality is impaired. Therefore, the aim of the present work was to develop simple and cost effective strategies to reduce soil-plant transfer of harmful substances. Three sites were selected in the vicinity of Dhaka city (Tongi pharmaceutical, Tejgaon industrial and Hazaribagh tannery area). Field and pot experiments were carried out with different varieties of field crops (rice, wheat and tomato) and different soil amendments (cowdung, city waste compost, oil cake, waterhyacinth, poultry litter, lime and red mud). At the site Tongi, pollutants mainly consists of organic compounds. The soil of Tejgaon is acidic (pH=5.7), contains high organic matter and elevated concentrations of Zn (685 mg/kg), Pb (136 mg/kg), and Cd (2.6 mg/kg). The Hazaribagh region is polluted by a ...

187

ELM resolved energy distribution studies in the JET MKII Gas-Box divertor using infra-red thermography  

International Nuclear Information System (INIS)

Using infra-red (IR) thermography, power loads onto the MKII Gas-Box divertor targets have been investigated in Type-I ELMy H-Mode plasmas at JET in medium current discharges (Ip = 2.6 MA and BT = 2.7 T). Heat fluxes are calculated from the measured divertor target tile surface temperatures taking into account the influence of co-deposited surface layers on tile surfaces. This is particularly important when estimating the energy deposition during transient events such as ELMs. Detailed energy balance analysis is used, both from IR and tile embedded thermocouples, to demonstrate an approximately constant ELM-averaged in/out divertor target asymmetry of ?0.55 and to show that the ELM in/out energy deposition ratio ranges from 1 : 1 to 2 : 1. The inter-ELM in/out ratio is close to the ELM-averaged value at low pedestal collisionalities and decreases down to values close to zero when the inner target plasma detaches at the highest pedestal collisionalities. The ...

2007-05-01

188

Determinants of warfarin use and international normalized ratio levels in atrial fibrillation patients in Japan.  

Science.gov (United States)

Background: Determinants of warfarin use and anticoagulation levels in atrial fibrillation (AF) patients have not been clarified thoroughly. Methods and Results: A total of 6,324 patients with non-valvular AF and congestive heart failure, hypertension, age, diabetes, prior stroke (CHADS(2)) score ?1 were used to investigate determinants of warfarin use, and 6,932 patients with AF receiving warfarin were used to investigate determinants of international normalized ratio (INR) of prothrombin time. Target INR levels for non-valvular AF patients were 1.6-2.6 for patients aged ?70 years and 2-3 for patients aged transient ischemic attack (TIA), and had higher CHADS(2) scores than those not receiving warfarin. Determinants of warfarin use were age (?60 years), AF type (persistent and permanent), and comorbidities (congestive heart failure, diabetes mellitus, and prior stroke or TIA). Use of antiplatelet drugs was a negative determinant of warfarin use. Only 53% of ...

2011-07-27

189

Clinical significance of changes of plasma endothelial vasoactive factors contents after treatment in patients with systemic sclerosis (SSc)  

International Nuclear Information System (INIS)

Objective: To investigate the relationship between endothelial vasoactive factors and development of systemic sclerosis (SSc). Methods: Blood circulating endothelial cell count (CEC, with density gradient precipitation method); plasma endothelin (ET), thromboxane B2 (TXB2 ), 6-keto-prostaglandin F1? concentrations (all above three with RIA); nitric oxide (NO) contents (with Griss method) and plasma intercellular adhesion molecule-1 (ICAM-1), p-selectin (P-S) contents (with ELISA) were measured in 52 patients with systemic sclerosis (SSc) both before and after treatment with prostaglandin E1 and 30 controls. Results: Plasma ET, TXB2, ICAM-1, P-S contents and CEC were significantly higher and plasma NO, 6-K-PGF1? contents were significantly lower in all the patients with SSc before treatment than those in the controls, After treatment, the patients with satisfactory responses (n=33) had the abnormal plasma values of these parameters greatly ...

2005-02-01

190

Characterization and Source Term Assessments of Radioactive Particles from Marshall Islands Using Non-Destructive Analytical Techniques  

Energy Technology Data Exchange (ETDEWEB)

A considerable fraction of radioactivity entering the environment from different nuclear events is associated with particles. The impact of these events can only be fully assessed where there is some knowledge about the mobility of particle bound radionuclides entering the environment. The behavior of particulate radionuclides is dependent on several factors, including the physical, chemical and redox state of the environment, the characteristics of the particles (e.g., the chemical composition, crystallinity and particle size) and on the oxidative state of radionuclides contained in the particles. Six plutonium-containing particles stemming from Runit Island soil (Marshall Islands) were characterized using non-destructive analytical and microanalytical methods. By determining the activity of {sup 239,240}Pu and {sup 241}Am isotopes from their gamma peaks structural information related to Pu matrix was obtained, and the source term was revealed. Composition and elemental distribution ...

2005-06-11

191

Catalyst for utilization of methane in selective catalytic reduction of NO{sub x}, Task 2.6  

Energy Technology Data Exchange (ETDEWEB)

Selective catalytic reduction (SCR) of nitrogen oxides(NO{sub x}) in flue gas or engine exhaust gas with hydrocarbons as the reductant has great potential for less expense, less pollution, and easier operation than SCR with ammonia. Methane is the preferred reducing gas because of its low cost and low toxicity. Stable, low-cost catalysts for SCR with methane are required to demonstrate this technology for controlling NO{sub x} emissions. Several cobalt and nickel catalysts on synthetic clay and uranium oxide supports were investigated for their activities in reducing NO{sub x} with methane in the presence of air. The efficiency of the synthetic clay-supported nickel and cobalt catalysts for nitric oxide (NO) reduction with methane as the reducing gas was poor. The nickel oxide-uranium oxide catalyst, which was chosen for its high stability, was also ineffective. Results from the two-step experiments conducted at two-temperatures produced some interesting information on the reactions of ...

1996-02-01

192

CNN Newsroom Classroom Guides, October 2000.  

Science.gov (United States)

These classroom guides, designed to accompany the daily CNN (Cable News Network) Newsroom broadcasts for the month of October 2000, provide program rundowns, suggestions for class activities and discussion, student handouts, and a list of related news terms. Top stories include: Chinese authorities detain Falun Gong protesters on Tiananmen Square and Pope John Paul II angers China by canonizing Chinese martyrs, U.S. presidential candidates prepare for the first presidential debate, U.S. presidential candidates debate education issues, Danville, Kentucky prepares for the first U.S. vice presidential debate, and Yugoslav protesters seize parliament (October 2-6); Yugoslavian president Vojislav Kostunica takes office, recent clashes between Arabs and Israelis concern neighboring Arab states, North Korea observes 55 years of communism with celebrations, Al Gore and George W. Bush meet in the second presidential debate, and Violence in the Mideast and an attack on a ...

1999-12-01

193

Analysis of the direct contamination pathway of "8"5Sr, "1"0"3Ru and "1"3"4Cs in radish  

International Nuclear Information System (INIS)

For analyzing the direct contamination pathway of the radionuclide in radish, a solution containing "8"5Sr, "1"0"3Ru and "1"3"4Cs was sprayed to the aerial part of the plant in a greenhouse at 5 different times before harvest. Plant interception factor showed little difference among radionuclides and increased with decreasing time interval between application and harvest with the maximum value of 0.86. The fractions of the initial deposition that remained in the radish plant at harvest were in the range of 16#approx#37% for "8"5Sr, 15#approx#68% for "1"0"3Ru and 35#approx#58% for "1"3"4Cs. The remaining fraction was the highest in "1"3"4Cs at earlier applications while it was the highest in "1"0"3Ru at later applications. Translocation factors of "8"5Sr, "1"0"3Ru and "1"3"4Cs were in the range of 3.2x10"-"3#approx#1.7x10"-"2 , 7.3x10"-"4#approx#2.6x10"-"2 and 6.6x10"-"2#approx#1.7x10"-"2, respectively, in upper root and in the range of 2.2x10"-"3#approx#5.5x10"-"3, ...

2000-05-01

194

Aerometric measurement and modeling of the mass of CO2 emissions from Crystal Geyser, Utah  

Energy Technology Data Exchange (ETDEWEB)

Crystal Geyser in eastern Utah is a rare, non-geothermal geyser that emits carbon dioxide gas in periodic eruptions. This geyser is the largest single source of CO{sub 2} originating from a deep reservoir. For this study, the amount of CO{sub 2} emitted from Crystal Geyser is estimated through measurements of downwind CO{sub 2} air concentration applied to an analytical model for atmospheric dispersion. Five eruptions occurred during the 48-hour field study, for a total of almost 3 hours of eruption. Pre-eruption emissions were also timed and sampled. Slow wind during three of the active eruptions conveyed the plume over a grid of samplers arranged in arcs from 25 to 100 m away from the geyser. An analytical, straight-line Gaussian model matched the pattern of concentration measurements. Plume width was determined from least-squares fit of the CO{sub 2} concentrations integrated over time. The CO{sub 2} emission rate was found to be between 2.6 and 5.8 kg/s during ...

2005-02-07

195

Additives to lower and stabilize the viscosity of pyrolysis oils during storage  

Energy Technology Data Exchange (ETDEWEB)

The initial development of additives to stabilize the viscosity of biocrude during long-term storage has produced dramatic results. The additives investigated were ethyl acetate, methyl isobuyl ketone and methanol, acetone, methanol, acetone and methanol, and ethanol. These additives represent three chemical families, which all demonstrated the ability to drastically reduce the aging rate of biocrude, as defined by the increase in viscosity with time. Accelerated aging tests were run at 90{degree}C to screen the additives. The additives not only lowered the initial viscosity at 40{degree}C by half but also reduced the aging rate of a hot gas filtered pyrolysis oil made from hybrid poplar (NREL run 175) by factors of 1-18 compared to the original pure oil. With the best additive, methanol, at a 10 wt% level in the pyrolysis oil, the modified biocrude was still a single-phase liquid and still met the ASTM no. 4 diesel fuel specification for viscosity even after 96 h exposure to ...

1997-09-01

196

A radiologic analysis and comparative evaluation of hysterosalpingographic and laparoscopic findings in infertile patients  

Energy Technology Data Exchange (ETDEWEB)

Hystreosalpingogram of 375 patients with infertility were reviewed with reference to radiological feature of each pathology and a comparative study of hysterosalpingography and laparoscopy in 36 patients was presented. This results were as follows;1. In 375 cases of infertility, 191 cases (50.9%) were primary infertility and 181 cases (49.1%) were secondary infertility. 2. The peak age distribution was 26 to 30 year old group in 211 cases (56.3%), and the peak duration of infertility was less than 3 years in 256 cases (68.3%). 3. Abnormal uterine findings were 115 cases (30.7%) and there were 73 cases of filling defects, 13 cases of irregularity, 12 cases of uterine flexion, 11 cases of congenital anomaly, and 9 cases of hypoplasia among them. 4. Abnormal tubal findings were 196 cases (52.3%) and there were 103 cases of simple obstruction, 69 cases of hydrosalpinx, and 50 cases of peritubal adhesion among them. 5. Intravasation of contrast media was noted in 42 cases ...

1984-09-15

197

Evaluation of left ventricular volumes in patients with congenital heart disease and abnormal left ventricular geometry. Comparison of MRI and transthoraic 3-dimensional echocardiography; Vergleich der transthorakalen 3D-Echokardiographie mit der MRT zur Bestimmung linksventrikulaerer Volumina bei Patienten mit pathologischer Ventrikelgeometrie aufgrund angeborener Herzfehler  

Energy Technology Data Exchange (ETDEWEB)

Purpose: To assess the new method of 3-dimensional echocardiography in comparison to the 'gold standard' MRI as to its ability to calculate left ventricular volumes in patients with congenital heart disease. Materials and methods: Eighteen patients between the ages of 3.9 to 37.3 years (mean: 12.8{+-}9.7) with a geometrically abnormal left ventricle were examined using a 1.5 T scanner with a fast gradient-echo sequence (TR=14 ms, TE=2.6-2.9 ms, FOV=300-400 mm, flip angle=20 , matrix=128:256, slice thickness=5 mm, retrospective gating) in multislice-multiphase technique. Transthoracic 3D-echocardiography was performed with a 3.5 MHz transducer and a Tomtec {sup trademark} (Munich, Germany) system for 3D reconstruction. Results: Volume calculation was possible in all patients with 3D-echocardiography, but the muscle mass calculation only succeeded in 11 to 18 patients (61%) due to inadequate visualization of the entire myocardium. Comparing MRI and ...

2003-07-01

198

Solution conformations of CaCl sub 2 and Ca(NO sub 3 ) sub 2 complexes of chiral tetramethyl 18-crown-6 macrocycles: A 1D and 2D sup 1 H and sup 13 C NMR investigation  

Energy Technology Data Exchange (ETDEWEB)

One- and two-dimensional NMR techniques have been used to investigate the solution structures of (2S,6S,11S,15S)-2,6,11,15-tetramethyl-1,4,7,10,13,16-hexaoxacyclooctadecane (I) and (2R,3R,11R,12R)-2,3,11,12-tetramethyl-1,4,7,10,13,16-hexaoxyacyclooctadecane (II) macrocycle complexes of CaCl{sub 2} and Ca(NO{sub 3}){sub 2} in CDCl{sub 3}. Previous chiroptical studies of these and similar crown complexes by circularly polarized luminescence (CPL), total luminescence (TL), and circular dichroism (CD) spectroscopy have shown that the macrocycle asymmetric carbons in these complexes constrain the ring such that the sense of the ring twist in the S chiral ring complexes is opposite to that in the R chiral ring complexes. These studies have also shown that there is an added chirality element in the di- and trivalent (alkaline earth and lanthanide metal, respectively) nitrate complexes of I and II associated with the twist of the nitrate anions relative to one another as ...

1989-10-04

199

Single and double ionization of strontium in the vicinity of four-photon excitation of the 5p{sup 2} {sup 1}S{sub 0} doubly excited state  

Energy Technology Data Exchange (ETDEWEB)

We report on the single and double multiphoton ionization of ground state Sr atoms observed in an atomic beam experiment with laser pulses of {approx}5 ns duration, maximum intensity {approx}4 x 10{sup 11} W cm{sup -2} and within the 710-740 nm wavelength range. The Sr{sup +} spectrum consists of two strong lines originating from three-photon resonant four-photon ionization of bound states, a number of weak autoionizing resonances and a broad line due to four-photon excitation of the doubly excited 5p{sup 2} {sup 1}S{sub 0} state. The latter, along with a strong, broad and structured spectral feature, is also evident in the wavelength dependence of the doubly charged Sr{sup 2+} ion. A weakly evident but reproducible inflection point ('knee' structure) appears in the intensity dependence of the Sr{sup 2+} yield at the location of the 5p{sup 2} {sup 1}S{sub 0} resonance. A complementary fluorescence experiment revealed the accumulation of population in the 5p{sub ...

2008-02-28

200

Occupational exposure to natural radionuclides due to mining activities in Ibadan, Southwestern Nigeria; Exposition professionnelle aux radionucleides naturels emis par les activites minieres a Ibadan au sud-ouest du Nigeria  

Energy Technology Data Exchange (ETDEWEB)

The activity concentrations of potassium, uranium and thorium in minerals and soil samples from a mining site in Ibadan, Southwestern Nigeria were measured using gamma ray spectroscopy method. Effective dose per annum has been calculated from the activity concentrations of dominant gamma-emitting natural radionuclides, potassium, uranium and thorium. Samples collected include minerals (beryl, quartz and feldspar), soil samples from the mining pits, heaps and undisturbed land around the mining site. The activity concentrations of {sup 40}K, {sup 238}U and {sup 232}Th, respectively in Bq kg-1 in the mineral samples were as follows: 1985 +- 16, 4.8 +- 0.9 and 11.8 +- 5.8 for beryl sample, 115.1 +- 27.9, 5.0 +- 1.3 and 6.3 +- 5.0 for feldspar samples and 1421 +- 122, <4.8 and 20.1 +- 3.5 for quartz samples. For the soil samples, the mean activity concentrations of {sup 40}K, {sup 238}U and {sup 232}Th, respectively, were 314.2 +- 5.7, 27.7 +- 2.6 and 11.5 +- 5.9 ...

2010-01-15

201

Disposal of De-ionizer Vessels Highly Contaminated with 14Carbon at SRS  

International Nuclear Information System (INIS)

At the Savannah River Site (SRS), nuclear production reactors used de-ionizers to control the chemistry of the reactor moderator during their operation to produce nuclear materials primarily for the weapons program. These de-ionizers were removed from the reactors and stored as a legacy waste with no path to disposal due to the relatively high 14C contamination (i.e., on the order of 20 curies per de-ionizer for 48-50 de-ionizers) and the low disposal limit of 4.2 Ci previously established for the Intermediate Level Vault (ILV). The ILV is considered most appropriate facility within which to dispose these items due to the method of solidifying waste items with cementitious material inside concrete vaults. In previous analyses the 14C ILV disposal limit was established at 4.2 Ci resulting from the use of a very conservative method to analyze the dose received from atmospheric releases of gaseous 14C. This investigation implemented a more rigorous evaluation of the physical and chemical ...

2008-01-01

202

DEVELOPMENT OF TECHNOLOGIES AND ANALYTICAL CAPABILITIES FOR VISION 21 ENERGY PLANTS  

Energy Technology Data Exchange (ETDEWEB)

The training of a new project team member was completed (Task 2.1). The Software Requirements Document was written (Task 2.3). It was determined that the CAPE-OPEN interfaces are sufficient for the communication between Fluent and V21 Controller (Task 2.4). The AspenPlus-Fluent prototype on allyl/triacetone alcohol production was further developed to assist the GUI and software design tasks. The prototype was also used to analyze the sensitivity of a process simulation result with respect to a parameter in a CFD model embedded in the process simulation. Thus the integration of process simulation and CFD provides additional process insights and enables the engineer to optimize overall process performance (e.g., product purity and yield) with respect to important CFD design and operation parameters (e.g., CSTR shaft speed). A top-level design of the V21 Controller was developed and discussed. A draft version of the Software Design Document was written (Task 2.5/2.6). ...

2001-07-10

203

/sup 18/O isotope effect in carbon-13 nuclear magnetic resonance spectroscopy. Part 8. Oxygen exchange of 2,4,6-trimethylpyrylium cation  

Energy Technology Data Exchange (ETDEWEB)

The rate of the oxygen-exchange reaction in an aqueous solution of a heterocyclic oxygen compound, 2,4,6-trimethylpyrylium perchlorate, was quantitated. The /sup 18/O isotope effect in /sup 13/C NMR spectroscopy affords a direct, continuous, and relatively simple analysis of the reaction and was used to obtain data on the incorporation of /sup 18/O from solvent H/sub 2//sup 18/O into the pyrylium salt. Due to the low solubility of this salt in aqueous solutions, 2,4,6-trimethyl(2-/sup 13/C)pyrylium perchlorate and 2,4,6-trimethyl(2,6-/sup 13/C/sub 2/)pyrylium perchlorate were synthesized to facilitate the acquisition of the data on an NTC-200 spectrometer operating at 50.31 MHz. Upon incorporation of /sup 18/O into the pyrylium salt, the /sup 13/C NMR signal of the directly bonded carbon atom is shifted upfield 0.038 ppm. A /sup 13/C isotope effect is also detected in the doubly /sup 13/C-enriched pyrylium salt where the /sup 13/C NMR signal for /sup 13/C-O-/sup ...

1984-12-12

204

X-ray dosimetry of TlGaSe_2 single crystals  

International Nuclear Information System (INIS)

TlGaSe_2 compound belongs to group of layered semiconductors of A"3B"3C_2"6-type. Photoelectric and optical properties of TlGaSe_2 single crystals were investigated in detail. Influence of gamma-, electron and neutron radiation on photoelectric properties of TlGaSe_2 single crystals is investigated too. The present work deals with experimental results relative to X-ray dosimetric characteristics of TlGaSe_2 crystals at 300 K. X-ray conductivity and X-ray dosimetric characteristic measurements are carried out in low load resistance regime. The source of X-ray radiation is the installation of X-ray diffraction analysis (URS-55a) with the BCV-2(Cu). Intensity of X-ray radiation (E) is regulated by measurement with current variation in tube at each given value of X-ray radiation dose E (R/min) are measured by crystal dosimeter DRGZ-02. X-ray conductivity coefficients K_#sigma# characterising X-ray sensitivity of investigated crystals are determined as the relative ...

205

The radioecological risk of decommissioning of nuclear submarines. Possible accidents and normal conditions  

International Nuclear Information System (INIS)

In the report the results of the estimations of radiological risk of various stages of decommissioning of nuclear submarines are presented. At occurrence on nuclear submarine the heavy failure, relating to the class hypotetical volume of acting of radionuclides in atmosphere can reach 1.6E(15) Bq. Results of estimations probable doses on an axis of a trace of a radioactive loop show, that at distribution of radionuclides during atmospheric carry to 'agreed' settlement (500-1000 m) the maximum doses on its territory can make: about 6.0E(-3) Sv (for the whole body); 3.0E(-3) Gy for the leather (basal layer); 6.3E(-2) Gy for the lungs (acute exposure) and up to 1.8 Gy for the thyroid gland. Hypotetical failure for the estimation of the greatest possible radioecological consequences for hydrobiocenosis is considering, connected with single discharge of liquid radioactive waste (LRW) in water area. At navigating failure of the tanker with LRW in water area can arrive 300 M3 of LRW with the ...

2000-05-01

206

Investigation of the influence of nitrogen on the pitting corrosion of high alloyed austenitic Cr-Ni-Mo-steels (Part II); Untersuchungen zum Einfluss des Stickstoffs auf das Lochkorrosionsverhalten hochlegierter austenitischer Cr-Ni-Mo-Staehle (Teil II)  

Energy Technology Data Exchange (ETDEWEB)

Austenitic stainless steel (18% Cr, 12% Ni, Mo gradation between 0,06 to 3,6%) had been solution nitrided. By step-by-step removing, the samples could be prepared with various surface contents of nitrogen from 0.04 to 0.42%. In two test series the influence of nitrogen had been determined. The susceptibility against pitting corrosion of these samples had been tested by the chronopotentiostatical method. For the investigated steel composition and the used corrosion system there is no influence of molybdenum on the effectiveness of nitrogen. The effectiveness of nitrogen can be described by the factor 25 in the PRE. By the investigation of the surfaces with the XPS analysis, it could be shown that the passivation and the pit nucleation is influenced by nitrogen. In these ranges NO{sub x}, NH{sub x}, and NH{sub z}-spectra have been detected. Bound Mo was found in steels containing molybdenum. It is assumed that the repassivation mechanisms of N and Mo work independently of each other. ...

2004-11-01

207

In vitro and in vivo evaluation of novel ligands for radioimmunotherapy  

Energy Technology Data Exchange (ETDEWEB)

Novel ligands cis-2,6-bis[N,N-bis(carboxymethyl)aminomethyl]-1-piperidineacetic acid (PIP-DTPA), cis-[(1R,11S)-6,9,15-Tris-carboxymethyl-3,6,9,15-tetraazabicyclo[9.3.1] pentadec-3-yl]-acetic acid (PIP-DOTA), cis-{l_brace}2,7-bis-[bis-carboxymethyl-amino)-methyl]-azepan-1-yl{r_brace}-acetic acid (AZEP-DTPA), [2-(4,7-bis-carboxymethyl-[1,4,7]triazacyclononan-1-yl-ethyl] -2-carbonylmethyl-amino]-tetraacetic acid (NETA) and [{l_brace}4-carboxymethyl-7-[2-(carboxymethylamino)-ethyl]-perhydro-1,4,7-triazonin-1-yl{r_brace}-acetic acid (NPTA) are investigated as potential chelators of {sup 177}Lu, {sup 9}Y, {sup 212}Pb and {sup 213}Bi for radioimmunotherapy (RIT). The new ligands are radiolabeled with {sup 177}Lu, {sup 86/88/9}Y, {sup 203}Pb and {sup 205/6}Bi, and in vitro stability and in vivo stability of the radiolabeled complexes are assessed in human serum and athymic mice, respectively. In vitro studies indicate that all radiolabeled complexes with the exception of ...

2006-05-15

208

Deep subsurface structure modeling based on microtremor and earthquake observation. Applicability of microtremor array measurements at the Kashiwazaki-Kariwa Nuclear Power Station  

International Nuclear Information System (INIS)

During the 2007 Niigataken Chuetsu-oki earthquake, strong ground motion with the peak acceleration of 680 cm/s/s which was larger than that of the empirical prediction was recorded at the base mat of the No.1 reactor building of Kashiwazaki-Kariwa Nuclear Power Station (NPS). Furthermore, in the Kashiwazaki-Kariwa NPS, over twice difference of 680 vs. 322 cm/s/s of peak acceleration between the No.1 and the No.6 reactor buildings was observed on the base mat. From the results of recent research, it is suggested that the deep sedimentary layers can be one of the important factors to elucidate these phenomena. In this study, at first, the applicability of microtremor array measurements for estimation of deep S-wave velocity structure (#approx#Vs=3 km/s layer) are discussed. Vertical microtremors were observed in three arrays at the Kashiwazaki-Kariwa NPS with the maximum station spacings of 3.04 km, 1.49 km and 0.75 km, respectively. The Rayleigh wave phase velocity in a frequency range ...

2010-05-01

209

Automatic segmentation of thoracic and pelvic CT images for radiotherapy planning using implicit anatomic knowledge and organ-specific segmentation strategies  

Energy Technology Data Exchange (ETDEWEB)

Automatic segmentation of anatomical structures in medical images is a valuable tool for efficient computer-aided radiotherapy and surgery planning and an enabling technology for dynamic adaptive radiotherapy. This paper presents the design, algorithms and validation of new software for the automatic segmentation of CT images used for radiotherapy treatment planning. A coarse to fine approach is followed that consists of presegmentation, anatomic orientation and structure segmentation. No user input or a priori information about the image content is required. In presegmentation, the body outline, the bones and lung equivalent tissue are detected. Anatomic orientation recognizes the patient's position, orientation and gender and creates an elastic mapping of the slice positions to a reference scale. Structure segmentation is divided into localization, outlining and refinement, performed by procedures with implicit anatomic knowledge using standard image processing operations. ...

2008-03-21

210

Advanced Instrumentation and Control Methods for Small and Medium Reactors with IRIS Demonstration. Final Report. Volume 1  

International Nuclear Information System (INIS)

Development and deployment of small-scale nuclear power reactors and their maintenance, monitoring, and control are part of the mission under the Small Modular Reactor (SMR) program. The objectives of this NERI-consortium research project are to investigate, develop, and validate advanced methods for sensing, controlling, monitoring, diagnosis, and prognosis of these reactors, and to demonstrate the methods with application to one of the proposed integral pressurized water reactors (IPWR). For this project, the IPWR design by Westinghouse, the International Reactor Secure and Innovative (IRIS), has been used to demonstrate the techniques developed under this project. The research focuses on three topical areas with the following objectives. Objective 1 - Develop and apply simulation capabilities and sensitivity/uncertainty analysis methods to address sensor deployment analysis and small grid stability issues. Objective 2 - Develop and test an autonomous and fault-tolerant control ...

2009-02-23

211

Neutron beam experiments using nuclear research reactors: honoring the retirement of professor Bernard W. Wehring -I. 6. Neutronics Analyses for Beamline Upgrades to the High Flux Isotope Reactor  

International Nuclear Information System (INIS)

The High Flux Isotope Reactor (HFIR) located at Oak Ridge National Laboratory is one of the world's most powerful research reactors. In 1996, one year after the demise of the Advanced Neutron Source Project, the U.S. Department of Energy embarked on an aggressive program to upgrade the neutron scattering facilities at the HFIR. These upgrades, which are now in progress, include the installation of larger beam tubes, a high-performance hydrogen cold source, and additional neutron guides and neutron scattering instruments. An extensive analysis effort was performed over the past 4 yr to support the design of the modified beamlines and new user facilities and to assess the impact of the upgrades on the integrity of the existing reactor system. The results of three of these analyses are summarized here. Specifically, results are presented for analyses related to the design of the new cold neutron source (CNS), the assessment of beam tube changes on the anticipated pressure vessel lifetime, ...

2001-06-17