The formalism of statistical mechanics of particles slower than light has been considered from the point of view of the application of this formalism for the description of tachyons. Properties of ideal gases of tachyons have been discussed in detail. After finding general formulae for quantum, Bose and Fermi gases the classical limit has been considered. It has been shown that Bose-Einstein condensation occurs. The tachyon gas of bosons violates the third principle of thermodynamics. Degenerated Fermi gas has been considered and in this case the entropy vanishes at zero temperature. Difficulties of formulating covariant statistical mechanics have been discussed.
The formalism of statistical mechanics of particles slower than light has been considered from the point of view of the application of this formalism for the description of tachyons. Properties of ideal gases of tachyons have been discussed in detail. After finding general formulae for quantum, Bose and Fermi gases the classical limit has been considered. It has been shown that Bose-Einstein condensation occurs. The tachyon gas of bosons violates the third principle of thermodynamics. Degenerated Fermi gas has been considered and in this case the entropy vanishes at zero temperature. Difficulties of formulating covariant statistical mechanics have been discussed.
The properties of the idealgas of classical (nonquantum) tachyons are considered. Starting from the definition of thermodynamic functions for this system, it may be found that tachyons and bradyons gases are similar. (AA).
... turbine blade heat-transfer and study the heat-transfer augmentation in idealized geometry and its ... responsible for heat transfer augmentation. ...
By comparison of standard entropies theoretically calculated and determined from gas-chromatographic data for 40 halo-aliphatic and halo-aromatic compounds 8 organic iodine compounds among them, adsorbed on graphitized thermal carbon black it was found that in all the cases the molecular model of ideal two-dimensional gas is a sufficiently good approximation. It was shown that for a number of systems the agreement can be improved if the vibrations of the center of molecular mass relative to the surface are taken into account
By using a laser and maser in tandem, it is possible to obtain laser action in the hot exhaust gases involved in heat engine operation. Such a "quantum afterburner" involves the internal quantum states of working gas atoms or molecules as well as the techniques of cavity quantum electrodynamics and is therefore in the domain of quantum thermodynamics. As an example, it is shown that Otto cycle engine performance can be improved beyond that of the "ideal" Otto heat engine.
We develop a framework based on microeconomic theory from which the idealgas like market models can be addressed. A kinetic exchange model based on that framework is proposed and its distributional features have been studied by considering its moments. Next, we derive the moments of the CC model (Eur. Phys. J. B 17 (2000) 167) as well. Some precise solutions are obtained which conform with the solutions obtained earlier. Finally, an output market is introduced with global price determination in the model with some necessary modifications.
Spectral room temperature photoluminescence (pl) of polycrystalline Cu(In,Ga)Se2 films (CIGSe) is evaluated with respect to optoelectronic properties and in particular for the determination of the splitting of quasi-Fermi levels (EFn - EFp). For lateral resolution of ? 1 ?m a confocal pl-setup is used. The depth profile of the excess carrier densities determining the rates of radiative transitions strongly govern the spectral pl-shape which has been numerically modeled with a matrix transfer formalism. In this optical approach we discriminate for wave propagation and attenuation in a multilayer system between a plane-wave ansatz and a 3D-spherical formalism, depending on excitation area large or small/similar compared to the thickness of the absorber. In both cases re-absorption of photons in energetic regimes with absorption approaches unity, from which the splitting of the quasi-Fermi levels is preferentially deduced, substantially influence the spectral luminescence signal. For ...
Application of an optimization technique to extract the non-ideal parameters of gas absorption with chemical reactions process was described. The gas absorption was modeled using mass transfer theory to represent the realistic behaviors of an absorber. The model was a highly non-linear iterative model which correlated the overall rate of absorption as the function of unknown non-ideal parameters, including the physical liquid mass transfer coefficient and the wetted interfacial area of of packings. The optimization program was developed to minimize the sum of squares of relative errors between the model predictions and the experimental data. Four sets of experimental data (case studies) with different operating conditions were used for extracting parameters. Comparisons between predicted and experimental measured overall absorption rate were in good agreement, average absolute value of relative errors ...
Momentum- and speed-dependent Maxwell-Boltzmann equilibrium distributions have been derived for tachyons and compared with the corresponding relativistic distributions. This is followed by a calculation of the mean, most probable and r.m.s. speeds for both the relativistic and tachyonic distributions. The idealgas of tachyons is discussed, including calculations of the internal energy and entropy. In each case a comparison is made with the corresponding bradyonic results. It is found that tachyons behave just like bradyons in the high-temperature limit, but have markedly different behaviour at low temperatures.
In this paper we have studied the relation between the intutionistic fuzzy left (respectively right) ideals of {\\Gamma}-semiring and that of operator semiring. Thereafter, we have established that the Lattices of all intutionistic fuzzy left (respectively right) ideal of {\\Gamma}-semiring is equivalent to that of Left operator semiring. We proved that Then there exist an inclusion preserving bijection ({\\mu}_{A,}\\u{psion}_{A})$\\rightarrow$({\\mu}_{B}^{+'},\\u{psion}_{B}^{+'}) between the lattices of all intuitionistic fuzzy right ideals (respectively intuitionistic fuzzy ideals) of S and the lattices of all intuitionistic fuzzy right ideals (respectively intuitionistic fuzzy ideals) of L. Where ({\\mu}_{A},\\u{psion}_{A}) is an intuitionistic fuzzy right (respectively intuitionistic fuzzy ideals) ideal of S. Also we ...
The notion of intuitionistic fuzzy set was introduced by Atanassov as a generalization of the notion of fuzzy set. In this paper we apply this concept of Atanassov to ideals, prime ideals and semiprime ideals of gamma semigroups in order to obtain some characterization theorems. We also introduce the notion of Atanassov's intuitionistic fuzzy ideal extension in a gamma semigroup and investigate some of their important properties. A regular gamma semigroup has been characterized in terms of Atanasov's intutionistic fuzzy ideal. Characterization of prime ideal of a gamma semigroup has also been obtained in terms of Atanassov's intutionistic fuzzy ideal extension.
This paper details the design of a premixed, swirl-stabilized combustor that was designed and built for the express purpose of obtaining validation-quality data for the development of large eddy simulations (LES) of gas turbine combustors. The combustor features nonambiguous boundary conditions, a geometrically simple design that retains the essential fluid dynamics and thermochemical processes that occur in actual gas turbine combustors, and unrestrictive access for laser and optical diagnostic measurements. After discussing the design detail, a preliminary investigation of the performance and operating envelope of the combustor is presented. With the combustor operating on premixed methane/air, both the equivalence ratio and the inlet velocity were systematically varied and the flame structure was recorded via digital photography. Interesting lean flame blowout and resonance characteristics were observed. In addition, the combustor exhibited ...
We investigate terms with four derivatives in the low-energy action of closed Bose strings. Our analysis is consistent with the possibility that the action involves only curvatures of an affine connection with torsion. The torsion is provided by the antisymmetric tensor gauge field.
We briefly report on zero-temperature photoassociation of a Bose-Einstein condensate, focusing on the many-body rate limit for atom-molecule conversion. An upgraded model that explicitly includes spontaneous radiative decay leads to an unanticipated shift in the position of the photoassociation resonance, which affects whether the rate (constant) maximizes or saturates, as well as the limiting value itself. A simple analytical model agrees with numerical experiments, but only for high density. Finally, an explicit comparison with the two-body unitary limit, set by the size of the condensate, finds that the many-body rate limit is generally more strict.
Based on the exact results obtained by Bethe ansatz, we demonstrate the existence of stable bound pair (BP) wave packet in Bose Hubbard model with arbitrary on-site interaction U. In large-U regime, it is found that an incoming single-particle (SP) can coherently pass through a BP wave packet and leave a coherent shift in the position of it. This suggests a simple scheme for constructing a BP charge qubit to realize a quantum switch, which is capable of controlling the coherent transport of one and only one photon in a one-dimensional waveguide.
Wet limestone scrubbing is once again becoming a popular technology for removal of sulfur dioxide (SO{sub 2}) from power plant emissions. Critical to the operation of wet limestone flue gas desulfurization (FGD) systems is accurate chemical analysis of scrubber solids. The analytical technique of thermogravimetry is ideal for this application, as the instrument can give precise readings of the principal scrubber solids components, calcium sulfite/sulfate hemihydrate, calcium sulfate dihydrate (gypsum), and unused calcium carbonate. The data provides plant chemists, engineers, and operators with information needed to fine-tune scrubber operation and detect process upsets. (orig.)
A visual study of film boiling is carried out to determine the flow regime transition in the post-CHF region. An idealized inverted annular flow is obtained by introducing a liquid jet of Freon 113 through a nozzle, precisely centered with respect to the internal diameter of the test section, with an annular gas flow. The respective ranges for liquid and gas velocities are 0.05-0.5 and 0.03-8.2 m s/sup -1/. Nitrogen and helium are used in the study. For the present configuration, there are four flow regimes; namely, the smooth inverted annular flow-section, the rough wavy, agitated and dispersed flow regimes.
A visual study of film boiling is carried out to determine the flow regime transition in the post-CHF region. An idealized inverted annular flow is obtained by introducing a liquid jet of Freon 113 through a nozzle, precisely centered with respect to the internal diameter of the test section, with an annular gas flow. The respective ranges for liquid and gas velocities are 0.05-0.5 and 0.03-8.2 m s"-"1. Nitrogen and helium are used in the study. For the present configuration, there are four flow regimes; namely, the smooth inverted annular flow-section, the rough wavy, agitated and dispersed flow regimes. (author).
A phase transition of gas-liquid type with an upper critical point is examined which arises in a model of charges of one sign on compensating background (OCP). The phase transition parameters are dependent on the detailed assumptions about the compressibility of the background, but the occurrence of this transition is independent on the background equation of state. In the electron-gas model ('jellium'), this transition appears to rule out Wigner crystallization. A variational principle in statistical mechanics is used to derive so-called Double-OCP model for a superposition of two one-component plasma models for charges of opposite sign. The free energy of this model sets an upper bound to that of a real plasma. Situations are discussed where this transition should manifest itself in anomalies in the approximate description of a non-ideal plasma.
We study the ground state of an ideal coupled two-component gas of ultracold atoms in a one dimensional optical lattice, either bosons or fermions. Due to the internal two-level structure of the atoms, the Brillouin zone is twice as large as imposed by the periodicity of the lattice potential. This is reflected in the Bloch dispersion curves, where the energy bands regularly possess several local minima. As a consequence, when the system parameters are tuned across a resonance condition, a non-zero temperature topological first order phase transition occurs which arises from an interplay between initernal and kinetic atomic energies. It is shown that these phenomena are also captured for two and three dimensional optical lattices.
Most palladium thin film based hydrogen gas sensors have response and recovery times that are too long to make them useful in vehicular and stationary gas leak detection applications. In contrast, a palladium-silver thin film based microcantilever (MC) hydrogen gas microsensor is reported herein with near ideal response characteristics for use in these hydrogen economy related applications. Specifically, 3-10 second response and recovery times have been measured for these sensors in contrast to previous sensor response measurements of several to tens of minutes using Pd thin film and MC based sensing techniques. The much reduced response times observed in the present study are attributed to a wet chemical Pd-Ag thin film deposition technique and a gas conditioning protocol that produces a highly nanostructured, porous film that rapidly adsorbs and desorbs H2, allowing rapid ...
The feasibility of developing a fusion power monitor based on a fluid activation detector is considered here. The activation fluid may be either a liquid or a gas and its composition can be selected from a number of candidate materials to provide desired activation and decay characterisitcs. Performance calculations indicate that ordinary water would be a nearly ideal activation fluid. The "1"6O(n,p)"1"6N reaction has a threshold at about 10 MeV and a cross section energy dependence giving it a predominant response for unmoderated D-T fusion neutrons. Adequate activation can be obtained at moderate flow rates for remote counting away from the high radiation area of the reactor. The 7.16 sec half-life of "1"6N is ideal for remote counting with subsequent decay in a small hold-up tank to eliminate activity build-up in the recycled water.
A visual study of film boiling using photographic and high speed motion-picture methods was carried out to determine the flow regime transition criteria in the post-CHF region. An idealized inverted annular flow was obtained by introducing a liquid jet of Freon 113 through a nozzle, precisely centered with respect to the internal diameter of the test section, with an annular gas flow. The respective ranges for liquid and gas exit velocities were 0.05 to 0.5 and 0.03 to 7.9 m/s. Nitrogen and helium were used in the study. For the present configuration, there are four basic flow regimes. Beginning from the nozzle exit, there is a smooth, inverted annular flow section with liquid in the core and gas in the annulus; followed by the rough wavy section with an intact liquid core, the agitated and the dispersed flow regimes. For a given liquid jet velocity, the axial extent of each flow regime decreases with ...
A visual study of film boiling using photographic and high speed motion-picture methods was carried out to determine the flow regime transition criteria in the post-CHF region. An idealized inverted annular flow was obtained by introducing a liquid jet of Freon 113 through a nozzle, precisely centered with respect to the internal diameter of the test section, with an annular gas flow. The respective ranges for liquid and gas exit velocities were 0.05 to 0.5 and 0.03 to 7.9 m/s. Nitrogen and helium were used in the study. For the present configuration, there are four basic flow regimes. Beginning from the nozzle exit, there is a smooth, inverted annular flow section with liquid in the core and gas in the annulus; followed by the rough wavy section with an intact liquid core, the agitated and the dispersed flow regimes. For a given liquid jet velocity, the axial extent of each flow regime decreases with ...
Electrical power is generated by steam turbines (steam being produced by coal, oil, gas or nuclear reactors), hydro units, gas turbines, internal combustion engines, jet engines, and pumped storage plants. Nuclear Power Plants generate only 15% of the total electrical power in the US. Nuclear Power Plants being cheaper to run are generally base loaded. The pumped-storage and gas turbine plants have ideal characteristics for peaking duty. In the pumping mode, pumped storage plants are used to provide additional system load and in the generating mode, they supply reactive power during peak load demands. Gas turbine plants have higher running costs, but are used as peaking units with a fast start capability. Fossil power plants need a minimum of 1 hour to stabilize expansion in the boiler and turbine generator. Due to a more competitive power supply market due to deregulation, most of ...
The line width of atom, situated near ideally conducting point or inside cone cavity in ideal conductor is analyzed. It is shown that the effect of point is decreased according to decreasing of its aperture angle
Using the operator approach we reexamine the two-dimensional model describing a massive Fermi field interacting via derivative couplings with two massless Bose fields, one scalar and the other pseudoscalar. Performing a canonical transformation on the Bose field algebra, the Fermi field operator is written in terms of the Mandelstam soliton operator and the derivative-coupling (DC) model is mapped into the massive Thirring model with two vector-current-scalar-derivative interactions (Schroer-Thirring model). The DC model with massless fermions can be mapped into the massless Rothe-Stamatescu model with a Thirring interaction (massless Rothe-Stamatescu-Thirring model). Within the present approach the weak equivalence between the fermionic sector of the DC model and the massive Thirring model is exhibited compactly.
The Lie algebra so(2n+1) and the Lie superalgebra osp(1/2n) are quantized in terms of 3n generators, called preoscillator generators. Apart from n "Cartan" elements the preoscillator generators are deformed para-Fermi operators in the case of so(2n+1) and deformed para-Bose operators in the case of osp(1/2n). The corresponding deformed universal enveloping algebras U_q[so(2n+1)] and U_q[osp(1/2n)] are the same as those defined in terms of Chevalley operators. The name "preoscillator" is to indicate that in a certain representation these operators reduce to the known deformed Fermi and Bose operators.
This paper constructs an analytic framework for calculating the assembly of galactic disks from the collapse of gas within dark matter halos, with the goal of determining the surface density profiles. Gas parcels (baryons) fall through the potentials of dark matter halos on nearly ballistic, zero energy orbits and collect in a rotating disk. The dark matter halos have a nearly universal form, as determined previously through numerical simulations. The calculation is first carried out for a variety of pre-collapse mass distributions and rotation profiles, including polytropic spheres in hydrostatic equilibrium with the halo potential. The resulting disk surface density profiles have nearly power-law forms, with well-defined edges. This idealized scenario is generalized to include non-spherical starting states and multiple accretion events (due to gas being added to the halo via merger events). This ...
The numerous challenges facing the North American electric utility industry were discussed. In addition to competition, electric utilities are faced with low demand growth, public pressure to avoid adding transmission and distribution capacity, and strict environmental requirements. In view of these developments, large central generation additions that have been industry norm until recently, do not always make economic sense in the current environment. Instead, smaller, distributed additions to generating capacity is becoming the new norm. Small-scale on-site generating capacity has the added advantage of reducing the need for expensive high-voltage transmission lines. The Ballard generation system described here is a modular, efficient fuel cell-based solution to implementing distributed power concepts. The system is natural gas fueled, with low noise, vibration and emissions. Apart from its other advantages, it provides ideal convergence ...
Inverted annular flow can be visualized as a liquid jet-like core surrounded by a vapor annulus. While many analytical and experimental studies of heat transfer in this regime have been performed, there is very little understanding of the basic hydrodynamics of the post-CHF flow field. However, a recent experimental study was done that was able to successfully investigate the effects of various steady-state inlet flow parameters on the post-CHF hydrodynamics of the film boiling of a single phase liquid jet. This study was carried out by means of a visual photographic analysis of an idealized single phase core inverted annular flow initial geometry (single phase liquid jet core surrounded by a coaxial annulus of gas). In order to extend this study, a subsequent flow visualization of an idealized two-phase core inverted annular flow geometry (two-phase central jet core, surrounded by a coaxial annulus of ...
The novel optical, electronic, and/or magnetic properties of metal and semiconductor nanoparticles have resulted in extensive research on new methods for their preparation. An ideal preparation method would allow the particle size, size distribution, crystallinity, and particle shape to be easily controlled, and would be applicable to a wide variety of material systems. Numerous preparation methods have been reported, each with its inherent advantages and disadvantages; however, an ideal method has yet to emerge. The most widely applied methods for nanoparticle preparation include the sonochemical reduction of organometallic reagents,(1&2) the solvothermal method of Alivisatos,(3) reactions in microemulsions,(4-6) the polyol method (reduction by alcohols),(7-9) and the use of polymer and solgel materials as hosts.(10-13) In addition to these methods, there are a variety of methods that take advantage of the unique properties of a ...
We revisited the quantum Zeno paradox, which claims that a generic quantum system prepared in a state which is not an eigenstate of the Hamiltonian operator and is continuously observed never decays. Since any perfectly isolated quantum system always interact with a vacuum field, we analyze the possibility of using this fact to solve the above mentioned conceptual problem. Therefore we discuss a two-level system or qubit-Bose field interaction Hamiltonians. We consider the quantum dynamics of this two-level system, prepared in the excited state interacting with a Bose field prepared in the Poincare invariant vacuum state. Using a first-order approximation in time-dependent perturbation theory, we evaluate the probability of spontaneous decay of the two-level system driven by the vacuum field. This probability is evaluated for a finite time interval. Using the standard argument to obtain the quantum Zeno paradox, we consider N measurements where ...
We consider a Bose-Einstein condensate (BEC) of N atoms of repulsive interaction #approx# U_0, in an elliptical trap, axially pierced by a Gaussian-intensity laser beam, forming an effective (quasi-2D) toroidal trap with minimum at radial distance #rho# = #rho#_p. The macroscopic angular momentum states #PSI#_l(#rho#,#theta#) #approx# #sq root#N#PHI#_l(#rho#)e"i"l"#theta# for integer l spread up to #rho# > #rho#_p. The spreading lowers rotational energies, so estimated low metastability barriers can support large l < or approx. l_m_a_x #approx# (NU_0)"1"/"4, < or approx. 10 for typical parameters. The l-dependent density profile module #PHI#_l(#rho#)"2 -#PHI#_0(#rho#)"2 is a signature of BEC rotation. Results are insensitive to off-axis laser displacements #rho#_0, for #rho#_0 #rho#_m_a_x << 1. (author).
In this paper, an investigation was performed on a failure pressure vessel, which was as an anti-freezing heater for General Gas Storage and Distribution (SGZ) system. Evident and serious deformation was observed on the body of the vessel. A metallurgical investigation was conducted to establish the mechanism and cause of deformation of the anti-freezing heater at Daya Bay PWR station in China. The investigation, which was performed on specimens cut from the most serious area deformed of the vessel, included macroscopic examination and microscopy examination. The results of the examinations showed that some lamellar pearlite in the microstructure were already spheroidized. It was confirmed that the vessel was operated at high temperature. Stress analysis for the vessel was conducted. And it was confirmed that, in ideal conditions, the vessel would be deformed at around 420 C. The overall results of the investigation showed that the failure of ...
There are several approaches to describe flows with particles e.g. Lattice-Gas Automata (LGA), Lattice-Boltzmann method (LBM) or smoothed particle hydrodynamics (SPH). These approaches do not use fixed grids on which the Navier-Stokes equations are solved via e.g. finite volume method. The flow is simulated using a multitude of particles or particle density distributions, which interacts and due to statistical laws and an even more fundamental approach than the Navier-Stokes equation, the averaged flow variables can be derived. After a short summary of the most popular particle methods the new DMPC (Dissipative Multiple Particles Collision) approach will be presented. The DMPC-model eliminates some of the weak points of the established particle methods and shows high potential for more accurate CFD solution especially in areas where standard CFD tools still have problems (e.g. aero-acoustics). The DMPC-model deals with discrete circular particles and calculates the ...
We propose triplet superconductors, such as ruthenates, as prospective materials for qubit construction. The vectorial nature of the order parameter in triplet superconductors makes it conceptually easy to estimate the performance of the qubits. The Cooper condensate of pairs in triplet superconductors has all the attributes of Bose-Einstein condensates and should facilitate long decoherence times for these qubits, relative to other vectorial schemes for qubits, such as small ferromagnets. There are other benefits, which the superconducting state provides for requirements such as entanglement between qubits via the proximity effect, etc. We consider these benefits in detail, although our consideration is only preliminary and further experimental and theoretical research will undoubtedly introduce correctives.
We duscuss a resonant microwave trap for neutral atoms. Because of the long spontaneous radiation time this trap is remarkably different from the optical trap. It also has advantages over static magnetic traps that trap the excited spin state of the lowest electronic level, in that atoms predominantly in the spin ground state can be trapped. We analyze the relaxation-ejection lifetime of atoms in such a trap using the formalism of dressed atomic states. Results are appliedi to atomic hydrogen and the possibility of Bose-Einstein condensation is considered.
We present a new approach for growing Si nanowires directly from a silicon substrate, without the use of a metal catalyst, silicon vapor or CVD gasses. The growth can be performed in a furnace type configuration at moderate temperatures or in localized regions by resistive heating. Since the silicon wires grow directly from the silicon substrate, they do not need to be manipulated nor aligned for subsequent applications. Wires in the 20-50 nm diameter range with lengths over 80 ?m can be grown by this technique. We have studied the effects of various growth parameters, including temperature, substrate orientation, initial sample cleaning and carrier gasses. Results indicate that most important parameters in the growth of the nanowires are the surface cleaning, the temperature and the type of carrier gas used. A model is proposed, which involves an oxide catalyst for the process, with the growth of the nanowires enabled by a significantly enhanced silicon surface ...
A numerical method for studying the flow field of an under-expanded axis-symmetric jet created by a converging-diverging nozzle and impinging on a flat plate is presented. The calculation domain of interest is a region that contains all the features of the jet that leaves the nozzle and impinges onto the plate. Axial symmetry of the domain allows a reduced 2-dimensional model to be used. FLUENT software is utilized to solve the continuity, momentum and energy equations using a coupled implicit scheme. The ideal-gas law is used to determine the gas density along with a k-#epsilon# turbulence model with a special modification to account for compressibility effects. In addition, the temperature dependency of viscosity has been taken into consideration. A number of different modeling techniques are investigated including different approximations to account for the flow inside the nozzle. Performance of non-equilibrium wall functions for near-wall ...
The preparation and performance of membranes for application to hydrogen separation from coal-derived gas is described. The membrane material investigated was dense amorphous silica deposited on a suitable support by chemical vapor deposition (CVD). Two types of support materials were pursued. One type consisted of a two-layer composite, zeolite silicalite/{alpha}-Al{sub 2}O{sub 3}, in the form of tubes approximately 0.7 cm in diameter. The other type was porous glass tubes of diameter below 0.2 cm. The first type of support was prepared starting from {alpha}-Al{sub 2}O{sub 3} tubes of 1{micro}m mean pore diameter and growing by hydrothermal reaction a zeolite silicalite layer inside the pores of the alumina at the OD side. After calcination to remove the organic template used in the hydrothermal reaction, CVD was carried out to deposit the final silica layer. CVD was carried out by alternating exposure of the surface with silicon tetrachloride and water vapor. SEM ...
We show that the eigenvalue equations describing a cylindrical ideal magnetophydrodynamicsw (MHD) plasma interacting with a thin resistive wall can be put into the standard mathematical form: ??? = ??? ?. This is accomplished by using a finite element basis for the plasma, and by adding an extra degree of freedom corresponding to the electrical current in the thin wall. The standard form allows the use of linear eigenvalue solvers, without additional interations, to compute the complete spectrum of plasma modes in the presence of a surrounding restrictive wall at arbitrary separation. We show that our method recovers standard results in the limits of (1) an infinitely resistive wall (no wall), and (2) a zero resistance wall (ideal wall).
We introduce a weak order ideal property that suffices for establishing the Evans-Griffith Syzygy Theorem. We study this weak order ideal property in settings that allow for comparison between homological algebra over a local ring R versus a hypersurface ring R =R/(x^n). Consequently we solve some relevant cases of the Evans-Griffith syzygy conjecture over local rings of unramified mixed characteristic p, with the case of syzygies of prime ideals of Cohen-Macaulay local rings of unramified mixed characteristic being noted. We reduce the remaining considerations to modules annihilated by p^s, s>0, that have finite projective dimension over a hypersurface ring.
Mice are an ideal mammalian model for studying the genetics of aging: considerable resources are available, the generation time is short, and the environment can be easily controlled, an important...Full Text Available
... modules 2 and 3, 45 ft from each end) in a ... The toe of the stone revetment was 2 ft out from the ... in parentheses are for the current meters in layout 2. ...
A process has been proposed to increase the efficiency of an ideal Otto cycle via a quantum heat engine that has no cooler reservoir. We show that such a process is not feasible.
Superfluidity in fermionic systems originates from pairing of fermions, and Bose condensation of these so-called Cooper pairs. The Cooper pairs are usually made of fermions of different species; for example in superconductors they are pairs of electrons with opposite spins. Thus the most favorable situation for pairing and superfluidity is when the two species of fermions that form pairs have the same density. This paper studies the possible superfluid states when the two pairing species have different densities, and show that the resultant states have remarkable similarities to the phases of liquid crystals. This enables us to provide a unified description of the possible pairing phases, and understand the phase transitions among them.
The thesis deals with measurement of the mass of the W boson at LEP2, based on the direct reconstruction of its decay products in the hadronic channel. A set of procedures necessary for the extraction of the W mass from the experimental data collected with the DELPHI detector in 1997 was developed (search of optimal variables for the event selection, development of a special method of kinematical reconstruction). The measured value of the mass was interpreted in the framework of the Standard Model, allowing to constrain the mass of the Higgs boson. A substantial part of the work is devoted to systematic effects due to the interactions between the hadronic decay products of the W bosons (colour reconnection and Bose-Einstein correlations), which may significantly influence the measurement of their mass. (author) 53 refs., 104 figs., 33 tabs.
A reduction of the mass of the \\eta'(958) meson may indicate the restoration of the UA(1) symmetry in a hot and dense hadronic matter, corresponding to the return of the 9th, "prodigal" Goldstone boson. We report on an analysis of a combined PHENIX and STAR data set on the intercept parameter of the two-pion Bose-Einstein correlation functions, as measuremed in \\sqrt{s_NN} = 200 GeV Au+Au collisions at RHIC. To describe this combined PHENIX and STAR dataset, an in-medium \\eta' mass reduction of at least 200 MeV is needed, at the 99.9 % confidence level in a broad model class of resonance multiplicities. Energy, system size and centrality dependence of the observed effect is also discussed.
A historical overview is given on the basic results which appeared by the year 1926 concerning Einstein's fluctuation formula of black-body radiation, in the context of light-quanta and wave-particle duality. On the basis of the original publications (from Planck's derivation of the black-body spectrum and Einstein's introduction of the photons up to the results of Born, Heisenberg and Jordan on the quantization of a continuum) a comparative study is presented on the first line of thoughts that led to the concept of quanta. The nature of the particle-like fluctuations and the wave-like fluctuations are analysed by using several approaches. With the help of the classical probability theory, it is shown that the infinite divisibility of the Bose distribution leads to the new concept of classical poissonian photo-multiplets or to the binary photo-multiplets of fermionic character. As an application, Einstein's fluctuation formula is derived as a sum of fermion type ...
We study the phonon fluxes emitted when the condensate velocity crosses the speed of sound, i.e., in backgrounds which are analogue to that of a black hole. We focus on elongated one dimensional condensates, and on stationary flows. Our theoretical analysis and numerical results are based on the Bogoliubov-de-Gennes equation without any further approximation. The spectral properties of the fluxes and of the long distance density-density correlations are obtained, with and without an initial temperature. In realistic conditions, we show that the condensate temperature dominates the fluxes, and thus hides the presence of the spontaneous emission (the Hawking effect). We also explain why the temperature amplifies the long distance correlations which are intrinsic to this effect. This confirms that the correlations pattern offers a neat signature of the Hawking effect. Optimal conditions to observe the pattern are discussed.
We investigate the profound relation between the equations of biological evolution and quantum mechanics by writing a biologically inspired equation for the stochastic dynamics of an ensemble of particles. Interesting behavior is observed which is related to a new type of stochastic quantization. We find that the probability distribution of the ensemble of particles can be decomposed into eigenfunctions associated to a discrete spectrum of eigenvalues. In absence of interactions between the particles, the out-of-equilibrium dynamics asymptotically relaxes towards the fundamental state. This phenomenon can be related with the Fisher theorem in biology. On the contrary, in presence of scattering processes the evolution reaches a steady state in which the distribution of the ensemble of particles is characterized by a Bose-Einstein statistics. In order to show a concrete example of this stochastic quantization we have solved explicitly the case in which the potential ...
We present ultraviolet through far-infrared (FIR) surface brightness profiles for the 75 galaxies in the Spitzer Infrared Nearby Galaxies Survey (SINGS). The imagery used to measure the profiles includes Galaxy Evolution Explorer UV data, optical images from Kitt Peak National Observatory, Cerro Tololo Inter-American Observatory, and Sloan Digital Sky Survey, near-IR data from Two Micron All Sky Survey, and mid- and FIR images from Spitzer. Along with the radial profiles, we also provide multi-wavelength asymptotic magnitudes and several nonparametric indicators of galaxy morphology: the concentration index (C 42), the asymmetry (A), the Gini coefficient (G), and the normalized second-order moment of the brightest 20% of the galaxy's flux (M-bar20). In this paper, the first of a series, we describe the technical aspects regarding the surface photometry, and present a basic analysis of the global and structural properties of the SINGS galaxies at different wavelengths. The homogeneity ...
We present and characterize an experimental system in which we achieve the integration of an ultrahigh finesse optical cavity with a Bose-Einstein condensate (BEC). The conceptually novel design of the apparatus for the production of BECs features nested vacuum chambers and an in vacuo magnetic transport configuration. It grants large scale spatial access to the BEC for samples and probes via a modular and exchangeable ''science platform.'' We are able to produce 87Rb condensates of 5x106 atoms and to output couple continuous atom lasers. The cavity is mounted on the science platform on top of a vibration isolation system. The optical cavity works in the strong coupling regime of cavity quantum electrodynamics and serves as a quantum optical detector for single atoms. This system enables us to study atom optics on a single particle level and to further develop the field of quantum atom optics. We describe the technological modules and the operation of the combined ...
The present project examined the operating characteristics and application possibilities of a new, compact combined heating and electricity generating unit with a thermal output of 14,5 kW and a generating capacity of 5,5 kW. Such a module was installed in a plant in Arlesheim (Canton of Basel-Country) and subject to performance measurements. The small heating and generating plant is designed for cyclic operation (without heat storage) and is very compact and low in cost. The heating and generating unit conforms to all Swiss regulations relating to electrical installations and air pollution control. The NO{sub x} emissions of the unit (400 mg/m{sup 3} in steady state operation) are above the limits of LRV 92 (80 mg/m{sup 3}), but the regulation does not apply for units in this power range. The electricity generation costs are approximately CHF 0.16/kWh. It therefore makes sense to install the module in regions with average supply tariffs of at least CHF 0.16/kWh. ...
The use of the focused ion beam (FIB) systems has increased to a high level in recent years. The imaging, milling, and deposition capabilities of the FIB make it the ideal instrument for e.g., site-specific failure analysis, specimen preparation and nano-machining. Ion channelling contrast allows for selective imaging of polycrystalline and polyphase microstructures. In addition, the FIB and CrossBeam registered instruments are unique stand-alone analytical tools. Their vast capabilities have enabled numerous applications into the semiconductor and materials sciences applications. These integrated CrossBeam registered Tools enable the observation and direct control of the FIB operation in real time. In addition to the improved accuracy and resolution the electron beam adds analytical capabilities as STEM, EDS and EBSP to the instruments. To ensure a safe and reliable operation of the instrument, a dedicated vacuum system is needed. This type of instrument combines ...
The objective of this paper is to present a theoretical evaluation of soil and house related factors that may affect the transport of radon from the soil into houses. A two-dimensional mathematical model was used to simulate the diffusive and convective transport of radon into the house through idealized openings in the understructure. With the help of model predictions we tried to find out whether diffusion or convection predominates and under which circumstances. Radon transport through cracks in the house understructure is influenced mainly by the soil permeability, radon concentration at the soil-crack interface, the total area of cracks and the pressure difference across cracks. Because of its large range of variability, the soil permeability appears to have the greatest effect on the radon transport through cracks. At permeabilities below 1x10"-"1"2 m"2 diffusive transport predominates and is almost invariable with the soil permeability. For permeabilities ...
The adsorption equilibria of Kr, Xe and N{sub 2}, which are constituents of the off-gas from nuclear reprocessing processes, on representative adsorbents (Molecular Sieve 5A (MS5A) and activated charcoal) were studied. Adsorption experiments were conducted in the temperature range of 77 to 323 K using a packed bed column. The adsorption isotherms for the activated charcoal adsorbent were successfully correlated by the vacancy solution model. The adsorption isotherms for the MS5A adsorbent were properly correlated by the Langmuir model and the vacancy solution model. The adsorption experiments for the binary component systems (Kr-Xe, Kr-N{sub 2} systems) were also performed, and the results suggest that the coexistence of Xe greatly inhibits the adsorption of Kr. The coexistence of large amounts of N{sub 2} was also found to inhibit the adsorption of Kr. The experimental results for the adsorption equilibrium of binary component systems on the activated charcoal ...
Full text of publication follows: Energy and environment are two major concerns in our modern society due to the coming shortage in fossil energy sources and the growing of greenhouse gas emissions. The challenge for the coming years is to discover new energy resources and to develop devices that are compatible with a sustainable development and generate few (or zero) emission. One of these devices is the fuel cell feed by hydrogen, whose application fields are very large. In particular, the proton exchange membrane fuel cell (PEMFC) is the most realistic device for automotive application. However, hydrogen storage remains one of the most important challenges regarding its development. Although different techniques are available for storing hydrogen, no ideal solution has been found yet. Compression needs elaborated tanks in shape for supporting high pressures, liquefaction requires an expensive hydrogen cooling and adapted tanks. Chemical ...
Full text of publication follows: Energy and environment are two major concerns in our modern society due to the coming shortage in fossil energy sources and the growing of greenhouse gas emissions. The challenge for the coming years is to discover new energy resources and to develop devices that are compatible with a sustainable development and generate few (or zero) emission. One of these devices is the fuel cell feed by hydrogen, whose application fields are very large. In particular, the proton exchange membrane fuel cell (PEMFC) is the most realistic device for automotive application. However, hydrogen storage remains one of the most important challenges regarding its development. Although different techniques are available for storing hydrogen, no ideal solution has been found yet. Compression needs elaborated tanks in shape for supporting high pressures, liquefaction requires an expensive hydrogen cooling and adapted tanks. Chemical ...
Peri-prosthetic infections are notoriously difficult to treat as the biomaterial implant is ideal for bacterial adhesion and biofilm formation, resulting in decreased antibiotic sensitivity....Full Text Available
The t-butyldimethylsilyl group is shown to be an ideal protecting group for the 2T-hydroxyl function of ribonucleosides during the synthesis of ribonucleotides using any of nine commonly used condensing...Full Text Available
Chemoprevention, especially through the use of naturally occurring phytochemicals capable of impeding the process of carcinogenesis at one or more steps, is an ideal approach for cancer management....Full Text Available
Background and Objectives:Sound enamel manifests peak transparency in the near-IR (NIR) at 1310-nm, therefore the near-IR is ideally suited for high contrast imaging...Full Text Available
Chemoprevention strategies to prevent the development of lung cancer in at-risk individuals are a key component in disease management. In addition to being highly effective, an ideal chemopreventive...Full Text Available
Atrial septal defect closure is now routinely performed using a percutaneous approach under echocardiographic guidance. Centrally located, secundum defects are ideal for device closure but there is...Full Text Available
There has been a major interest in the drug treatment of osteoporosis and an increase in the number of drugs available in most countries. The ideal drug (one which increases or restores bone density...Full Text Available
The overarching goal of medical training is to nurture the growth of knowledgeable, caring and insightful clinicians guided by the ideals of medical professionalism. Recent definitions of professional...Full Text Available
BackgroundPrevious research has demonstrated that exposure to images depicting the thin female ideal has negative effects on some females' levels of body dissatisfaction. Much of...Full Text Available
The conventional IMRT planning process involves two stages in which the first stage consists of fast but approximate idealized pencil beam dose calculations and dose optimization and the second...Full Text Available
Several nematode species have now attained ‘model organism’ status, yet there remain many niches in basic biological inquiry for which nematodes would be ideal model systems of study....Full Text Available
Delivering the promise of personalised medicine is the challenge that the current generation of scientists face. The variations in human physiology and disease are considerable, and designing appropriate strategies to deliver what has been promised will require access to tissue from a large number of volunteers. The NHS provides an ideal infrastructure for sample acquisition, but requires two things to make this available?public consent and support for extra manpower and administration. There is a disconnection between the NHS and tissue based research that needs to be addressed on a number of levels to provide a translational platform. This should enable the path to be beaten to provide the ideal tailored treatment for future patients; one that preserves quality of life by curing the dise...
System identification is a necessity in control theory. Classical control theory usually considers processes with integer order transfer functions. Real processes are usually of fractional order as opposed to the ideal integral order models. A simple and elegant scheme is presented for approximation of such a real world fractional order process by an ideal integral order model. A population of integral order process models is generated and updated by PSO technique, the fitness function being the sum of squared deviations from the set of observations obtained from the actual fractional order process. Results show that the proposed scheme offers a high degree of accuracy.
The mean-field pictures based on the standard time-dependent variational approach have widely been used in the study of nonlinear many-boson systems such as the Bose-Hubbard model. The mean-field schemes relevant to Gutzwiller-like trial states $|F>$, number-preserving states $|\\xi >$ and Glauber-like trial states $|Z>$ are compared to evidence the specific properties of such schemes. After deriving the Hamiltonian picture relevant to $|Z>$ from that based on $|F>$, the latter is shown to exhibit a Poisson algebra equipped with a Weyl-Heisenberg subalgebra which preludes to the $|Z>$-based picture. Then states $|Z>$ are shown to be a superposition of $\\cal N$-boson states $|\\xi>$ and the similarities/differences of the $|Z>$-based and $|\\xi>$-based pictures are discussed. Finally, after proving that the simple, symmetric state $|\\xi>$ indeed corresponds to a SU(M) coherent state, a dual version of states $|Z>$ and ...
The development of modern techniques for the cooling and the manipulation of atoms in recent years, and the possibility to create Bose-Einstein condensates and degenerate Fermi gases and to load them into regular optical lattices or disordered optical potentials, has evoked new interest for the disorder-induced localization of ultra-cold atoms. This work studies the transport properties of matter waves in disordered optical potentials, which are also known as speckle potentials. The effect of correlated disorder on localization is first studied numerically in the framework of the Anderson model. The relevant transport parameters in the configuration average over many different realizations of the speckle potential are then determined analytically, using self-consistent diagrammatic perturbation techniques. This allows to make predictions for a possible experimental observation of coherent transport phenomena for cold atoms in speckle potentials. Of particular ...
The invention relates to a method for purifying a gas mixture containing at least one undesirable gas compound utilizing certain sulfonamide or sulfamide solvents.
Energy from biomass is a CO{sub 2} neutral, sustainable form of energy. Anaerobic digestion is an established technology for converting biomass to biogas, which contains around 60% methane, besides CO{sub 2} and various contaminants. Most types of biomass contain material that cannot be digested; in woody biomass, this portion is particularly high. Therefore, conventional anaerobic digestion is not suited for the production of biogas from woody biomass. While wood is already being converted to energy by conventional thermal methods (gasification with subsequent methanation), dung, manure, and sewage sludge represent types of biomass whose energy potential remains largely untapped (present energetic use of manure in Switzerland: 0.4%). Conventional gas phase processes suffer from a low efficiency due to the high water content of the feed (enthalpy of vaporization). An alternative technology is the hydrothermal gasification: the water contained within the biomass ...
A solar thermophotovoltaic (STPV) system has both terrestrial and space applications because thermal energy storage can be utilized. Excellent properties (heat of fusion=1800 j/gm and melting temperature=1680 K) make silicon the ideal thermal storage material for an STPV system. Using a one dimensional model with tapering of the silicon storage material, it was found that several hours of running time with modest lengths ({approximately}15 cm) of silicon are possible. Calculated steady-state efficiencies for an STPV system using an Er-YAG selective emitter and ideal photovoltaic (PV) cell model are in the range of 15{percent}{endash}17{percent}. Increasing the taper of the storage material improves both efficiency and power output. {copyright} {ital 1996 American Institute of Physics.}
The dynamical decoupling (DD) aims at suppressing the decoherence by means of coherent control pulses. Even if devices exist where instantaneous pulses are an adequate approximation, experimentally a finite duration #tau#_p and a bounded amplitude are inevitable. They are the cause of additional errors which can be corrected by designing the pulse shape appropriately. The new pulse has the overall effect of an ideal, instantaneous pulse with the advantage of decoupling the spin (or qubit) from the bath up to the order O(#tau#_p"3). The limitation of the no-go theorem for #pi# pulses is avoided. Hence, the Uhrig sequence (UDD), originally thought for ideal #pi# pulses, works also for bounded control Hamiltonians. Numerical simulations show that concatenated sequences of real pulses are effective against general decoherence.
The role of shear in determining the ideal MHD stability properties of tokamaks is discussed. In particular, we assess the effects of low shear within the plasma upon pressure-driven modes. The standard ballooning theory is shown to break down, as the shear is reduced and the growth rate is shown to be an oscillatory function of n, the toroidal mode number, treated as a continuous parameter. The oscillations are shown to depend on both the pressure and safety-factor profiles. When the shear is sufficiently weak, the oscillations can result in bands of unstable n values which are present even when the standard ballooning theory predicts complete stability. These instabilities are named ''infernal modes.'' The occurrence of these instabilities at integer n is shown to be a sensitive function of q-axis, raising the possibility of a sharp onset as plasma parameters evolve. 20 refs., 31 figs.
Ideal free distribution (IFD) models are perhaps the group of mathematical models of behavior that have been the most widely and successfully applied by empiricists. These models can be applied to nearly any situation in which consumers compete?by any mechanism?for resources that are patchily distributed in their environment. Although IFD models have come to be broadly accepted, experiments that simultaneously test more than a single prediction are rare. Instead, investigators normally either test (1) for a relationship between the distribution of consumers and the distribution of resources or (2) whether average fitnesses are equal across resource patches. We conducted experiments with pea aphids (Acyrthosiphon pisum Harris) feeding on two patches of fava beans (Vicia faba L.) to fully in...
The authors report here, for the first time, high frequency testing of a new type of electrochemical double layer capacitor (EDLC), based on carbon aerogels: the Aerocapacitor. Carbon aerogels, are a novel type of carbon foam developed by Lawrence Livermore National Laboratory for military applications. The unique properties of carbon aerogels, high surface area (700 m{sup 2}/g), high density (1g/cc), well controlled pore diameter and high material conductivity (25 S/cm) made it an ideal EDLC electrode material. Using carbon aerogel as the electrode material, the authors have developed Aerocapacitors. These new EDLC`s have a frequency response comparable to that of aluminum electrolytic capacitors and are thus ideally suited to power conversion applications.
A publication on Norwegian gas and gas export. The content is wide spread from use of gas in daily life via sub sea pipeline repair systems to an overview over tomorrows gas fields. (AG)
... Another solution, hybrid vehicles, combine two sources of energy (electric and chemical), reducing the global consumption of fossil fuels. Fuel cell vehicles are also one of the most promising technologies for the future, with the capacity to use any fuel - hydrogen being the ideal fuel ecologically, but constrained by infrastructure and storage issues. This book explores all these different solutions for moving our vehicles from fossil ...
Landscape visive pollution due to photo-biodegradable plastic bags is assessed in an ideal case, the most favorable to their use. The result is that mean permanent visive pollution is 100 times higher than established norms. Both photo and biodegradability of plastic bags in the real world are discussed. The conclusion is that photo-biodegradability does not solve the problem of landscape visive pollution due to plastic bags.
This comprehensive guide offers several tried and true steps to help you successfully manage the complex process of developing free software. Topics include project management, developer motivation, technical infrastructure to support collaboration, and project promotion. Producing Open Source Software is ideal for developers starting their own free software projects, or people who simply want to participate in the process.
It is maintained that special features of FFTF make it an ideal system to test sodium boiling detection techniques by acoustic/neutronic methods and to test the response of acoustic/neutronic sensors to vibrations. It is shown that accumulated research results indicate that such tests in FFTF are feasible, predictable, promising and safe. (author).
An inner-city development with pile foundations as well as the proximity to the river Neckar with a groundwater flow offered ideal conditions for this new building in Mannheim in order to heat and cool geothermally. Already with the planning phase, detailed numerical flow computations were necessary in order to prove the functionality of the energy concept.
...Butley river and Ore estuary, Boyton Marshes attracts breeding wading birds in spring and ducks, geese and swans in winter. It's also ... During spring and autumn, it is an ideal place to see migrant wading birds, gulls and terns. Insh Marshes Insh ... Spring is also an excellent time to visit. Leighton Moss Leighton Moss is the largest reedbed in north-west England, and home ... When they leave in spring, wading birds take centre stage. Watch it all take place from our viewing centre and hide,...
...Butley river and Ore estuary, Boyton Marshes attracts breeding wading birds in spring and ducks, geese and swans in winter. It's also ...The spectacular cliffs at Fowlsheugh are packed with 130,000 breeding seabirds in the spring and summer, including guillemots, razorbills and kittiwakes. Freiston ...for its breeding avocets and terns, which can be seen throughout the spring and summer. Access is by boat only and the trip ... During spring and autumn, it is an ideal place to see migrant wading birds, gulls and terns. Leighton Moss Leighton ...
In a reactor environment, the surface of a limiter or wall is primarily determined by the mechanism of erosion and deposition of surface material. It should be possible to use pellet injection to reduce net erosion to zero everywhere if low-Z materials are used for the surface. Erosion rates can, in general, be minimized by large area limiters and high plasma temperatures, which transmit power to the walls with less sputtering. Under ideal steady state conditions the wall surface is dominated by metallurgical effects in the wall.
A three-dimensional numerical simulation of mammatus-like clouds is presented. A portion of a cirrus outflow anvil cloud is simulated including cloud ice and snow microphysical representations. The simulated mammatus clouds appear in a cellular pattern and are compared with the few available previously published physical observations of mammatus. Copyright Copyright 2006 Royal Meteorological Society
Calibration-Free Laser-Induced Breakdown Spectroscopy (CF-LIBS) has been proposed several years ago as an approach for quantitative analysis of Laser-Induced Breakdown Spectroscopy spectra. Recently developed refinement of the spectral processing method is described in the present work. Accurate quantitative results have been demonstrated for several metallic alloys. However, the degree of accuracy that can be achieved with Calibration-Free Laser-Induced Breakdown Spectroscopy analysis of generic samples still needs to be thoroughly investigated. The authors have undertaken a systematic study of errors and biasing factors affecting the calculation in the Calibration-Free Laser-Induced Breakdown Spectroscopy spectra processing. These factors may be classified in three main groups: 1) experimental aberrations (intensity fluctuations and inaccuracy in the correction for spectral efficiency of a detection system), 2) inaccuracy in theoretical parameters used for calculations (Stark ...
Calibration-Free Laser-Induced Breakdown Spectroscopy (CF-LIBS) has been proposed several years ago as an approach for quantitative analysis of Laser-Induced Breakdown Spectroscopy spectra. Recently developed refinement of the spectral processing method is described in the present work. Accurate quantitative results have been demonstrated for several metallic alloys. However, the degree of accuracy that can be achieved with Calibration-Free Laser-Induced Breakdown Spectroscopy analysis of generic samples still needs to be thoroughly investigated. The authors have undertaken a systematic study of errors and biasing factors affecting the calculation in the Calibration-Free Laser-Induced Breakdown Spectroscopy spectra processing. These factors may be classified in three main groups: 1) experimental aberrations (intensity fluctuations and inaccuracy in the correction for spectral efficiency of a detection system), 2) inaccuracy in theoretical parameters used for calculations (Stark ...
A gas diffusion semiconductor electrode and solar cell and a process for gaseous fixation, such as nitrogen photoreduction, CO/sub 2/ photoreduction and fuel gas photo-oxidation are described. The gas diffusion photosensitive electrode has a central electrolyte porous matrix with an activated semiconductor material on one side adapted to be in contact with an electrolyte and a hydrophobic gas diffusion region on the opposite side adapted to be in contact with a supply of molecular gas.
The book tries about the International and national aspects, natural gas situation, production, consumption, prices, demand projection, energetic plans, norms and laws of the natural gas in Colombia
This document provides information on the supply and disposition of natural gas to a wide audience. The 1996 data are presented in a sequence that follows natural gas from it`s production to it`s end use.
The origin of natural gas in the Japanese oil and gas fields are geochemically studied. Samples are taken from structural natural gas, surface gas seepage, water-dissolved natural gas and coal-field gas of the Japan Sea coast area. The origins of primary hydrocarbons are classified into bacteria gas and thermogenic gas, the latter being subclassified into gas in oil production zone with the per million deviation of the carbon isotope (/sup 13/C/sup 1/) of methane less than -35 and those gases with maturity higher than this. Surface gas seepage is subjected to migration and bacterial oxidation. Coal gas is similar to oil gas. The CO/sub 2/ concentration is 0 - 2% and /sup 13/CO/sub 2/ deviations from -30 - +30. The origin can be barely ...
Many older homes are equipped with mercury-containing gas regulators that reduce the pressure of natural gas in the mains to the low pressure used in home gas piping. Removal of these regulators can...Full Text Available
Sewage gas or biogas as a product of anaerobic digestion contains methane and carbon dioxide as its main components. Biogas is scrubbed off carbon dioxide in absorption columns and purified to natural-gas quality. The purified gas then is piped to the gas pressure control station and fed into the public network. Description of process and plant is given.
We report the performance of a micro gas turbine on biomass producer gas and mixtures of biomass producer gas with natural gas. The micro gas turbine delivers full power on gas mixtures with a heating value of at least 15 MJ/Nm{sup 3}. For gas of lower heating value, the maximum fuel gas flow limits the attainable power. The lower limit for stable operation is about 8 MJ/Nm{sup 3}. The gross efficiency of the micro gas turbine depends on output power but not on the gas heating value, within our measurement accuracy. Above 70% of full power, emissions of CO and NO are 40 and 10 times lower than those of a gas engine of similar size. At part load below 70% of full power, the micro gas turbine burner switches to a different operating mode ...
Ultraviolet light can be used to immobilize biomolecules onto thiol reactive surfaces in order to, e.g., make biosensors. The mechanism involves light-induced formation of free, reactive thiol groups in disulphide containing molecules. This technology allows for the creation of arrays of biomolecules with a high degree of reproducibility, circumventing the need for often expensive nano/micro-dispensing technologies. The ultimate size of the immobilized spots is defined by the focal area of the UV beam. Light-induced immobilization has the added benefit that the immobilized molecules will be spatially oriented and covalently bound to the surface. In this paper, we demonstrate the utility of a sensor array created with the new sensor technology when integrated into a microfluidic system. Protein arrays made using light-induced immobilization showed successful antigen/antibody binding in a flow cell allowing the visualisation of real time binding and enzyme activity. This new technology ...
Several observational studies suggest that solar wind dynamic pressure fluctuations can drive magnetospheric ultra-low frequency (ULF) waves on the dayside. To investigate this causal relationship, we present results from Lyon-Fedder-Mobarry (LFM) global, three-dimensional magnetohydrodynamic (MHD) simulations of the solar wind-magnetosphere interaction. These simulations are driven with synthetic solar wind input conditions, where idealized ULF dynamic pressure fluctuations are embedded in the upstream solar wind. In three of the simulations, a monochromatic, sinusoidal ULF oscillation is introduced into the solar wind dynamic pressure time series. In the fourth simulation, a continuum of ULF fluctuations over the 0-50 mHz frequency band is introduced into the solar wind dynamic pressure time series. In this numerical experiment, the idealized solar wind input conditions allow us to study only the effect of a fluctuating solar wind dynamic ...
Simulations and experiments have been carried out to explore using a plastic scintillator as a dosimetry probe in the vicinity of a pulsed bremsstrahlung source in the range 4 to 20 MeV. Taking advantage of the tissue-equivalent properties of this detector in conjunction with the use of a fast digital signal processor near real-time dosimetry was shown to be possible. The importance of accounting for a broad energy electron beam in bremsstrahlung production, and photon scattering and build-up, in correctly interpreting dosimetry results at long stand-off distances is highlighted by comparing real world experiments with ideal geometry simulations. Close agreement was found between absorbed energy calculations based upon spectroscopic techniques and calculations based upon signal integration, showing a ratio between 10 MeV absorbed dose to 12 MeV absorbed dose of 0.66 at a distance of 91.4 m from the accelerator. This is compared with an ...
The influence of the velocity profile at the inlet boundary on the simulation of air velocity distribution inside an electrostatic precipitator is presented in this study. Measurements and simulations were performed in a duct and an electrostatic precipitator (ESP). A four-hole cobra probe was used for the measurement of velocity distribution. The flow simulation was performed by using the computational fluid dynamics (CFD) code FLUENT. Numerical calculations for the air flow were carried out by solving the Reynolds-averaged Navier-Stokes equations coupled with the realizable k-{epsilon} turbulence model equations. Simulations were performed with two different velocity profiles at the inlet boundary - one with a uniform (ideal) velocity profile and the other with a non-uniform (real) velocity profile to demonstrate the effect of velocity inlet boundary condition on the flow simulation results inside an ESP. The real velocity profile was obtained from the velocity ...
Near-ideal Schottky barrier contacts to n-type Al0.22Ga0.78N have been developed by a two-step surface treatment technique. Plasma etching of the AlxGa1-xN surface prior to Schottky metal deposition, combined with sequential chemical treatment of the etched surface, holds promise for developing high quality low-leakage Schottky contacts for low noise applications and for recessed gate high electron mobility transistors. In this work, the effect of postetch chemical treatment of the n-type Al0.22Ga0.78N surface on the performance of the Ni/Au based Schottky contact has been investigated. Three different types of chemical treatment: viz, reactive ion etching, reactive ion etching plus dipping in hot aqua regia, and reactive ion etching plus dipping in hot KOH, are studied. Detailed current-voltage studies of three different surface treated diodes and a comparison with as-deposited diodes reveal significant improvement in the diode characteristics. The latter surface ...
This report describes the design of an on-board battery charger for an electric car. There are already various battery charger units on the market. However, these are not specifically designed for this application, and consequently do not provide an ideal solution. Because these products are not specific to one application, and instead opt to cover a variety of briefs, they are not ideal. They also tend to be heavier and more expensive than if the charger was built specifically for one purpose. The main design considerations were that the charger should be compact and lightweight. It was also specified that the design should be able to operate using either the single-phase or three-phase AC supply. Before the design process for the battery charger could commence, it was necessary for the author to get an appreciation of power electronics, since he had no previous experience in the subject. The author focused his attention on areas of the ...
Most of the organic electronic devices are nowadays fabricated under poor vacuum conditions. In this regard, there is only little knowledge about the impact of contamination of the metal electrode on the charge injection barrier in this kind of electronic devices. In our study we have performed X-ray and ultra violet photoemission spectroscopy (XPS, UPS) on interfaces between the organic semiconductor -sexithiophene and sputter cleaned (ideal) metals as well as contaminated (realistic) metals. As metal substrates we have used silver, gold, palladium, and platinum. These metals provide us a wide range of metal work functions from 4.2 eV for silver up to 5.5 eV for platinum. For all interfaces of -sexithiophene and contaminated metals we have observed a reduction of the interface dipole and the hole injection barrier. The charge injection barrier in all four cases is almost independent of the underlying metal (within an error of 0.2 eV) and the interface dipole ...
We suggest and describe the use of a binary pseudo-random (BPR) grating as a standard test surface for measurement of the modulation transfer function (MTF) of interferometric microscopes. Knowledge of the MTF of a microscope is absolutely necessary to convert the measured height distribution of a surface undergoing metrology into an accurate power spectral density (PSD) distribution. For an'ideal' microscope with an MTF function independent of spatial frequency out to the Nyquist frequency of the detector array with zero response at higher spatial frequencies, a BPR grating would produce a flat 1D PSD spectrum, independent of spatial frequency. For a'real' instrument, the MTF is found as the square root of the ratio of the PSD spectrum measured with the BPR grating to the'ideal,' spatial frequency independent, PSD spectrum. We present the results from a measurement of the MTF of MicromapTM-570 ...
Novel hybrid organic/inorganic nanocomposites made of metal oxide and conjugated polymer nanocomposite and its application in bulk-heterojunction solar cells were studied. The composite was composed of different concentrations of strontium titanate (SrTiO_3) and polyaniline doped phosphoric acid. The optimum concentration of strontium titanate was found to be 0.2 v/v. An inorganic-organic photovoltaic device with a structure of Ag/Pani-H_3PO_4-SrTiO_3/Al has been fabricated. The ideality factor value of the diode was found to be 1.8. This n value of the diode implies a deviation from ideal junction behaviour. The barrier height #phi#_b value for the diode was found to be 0.56 eV. The Ag/Pani-H_3PO_4-SrTiO_3/Al diode shows a photovoltaic behaviour with a maximum open-circuit voltage V_o_c of 2.49 V, and short-circuit current I_s_c of 5.6 mA under light illumination #lambda# = 460 nm. The conversion efficiency was found to be 5.2%. It is ...
For spintronic applications it is important to establish how efficiently spins can be injected from a magnetic material into a non-magnetic material and the distance over which those spins survive. It is thought that spin polarised transport current can be determined by using the suppression of the Andreev reflection between a superconductor and the spin polarised material (Science 282 (1998) 85). Cu/Co bilayers are potentially an ideal test system for such study. In this paper we assess the feasibility of using point contact Andreev reflection spectroscopy to address this problem using a superconducting niobium tip at 4.2 K.
Developing a modern electric power sector is necessary for economic growth and development to proceed. Institutions to implement an IRP (integrated resource planning) process do not exist in many countries. Hainan`s economy is growing rapidly with a concomitant increase in electricity demand. This is an ideal time in Hainan`s development to implement an IRP process. The challenge is for Hainan to develop institutions and incentive mechanisms for HEPCO (Hainan Electric Power Co.) to adopt cost-based pricing, run DSM programs, construct renewable generating plants, etc. One proposal is to great a Hainan government-wide IRP committee.
Single photon tomography using lipophilic tracers provides tomographic representations of regional blood flow. To penetrate a healthy blood-brain barrier requires that radiotracers either are fat-soluble or have an affinity for one of the selective blood-brain barrier transport systems. In recent years there has been an increasing interest to explore the ideal physical characteristics of "9"9"mTc for diagnostic problems of brain diseases. The development of radiopharmaceuticals for brain imaging including the intensively studied "9"9"mTc-propyleneamineoxime derivatives is discussed. (author).
The paper takes as its starting point the diffusion of ICT applications associated with so-called 'customer relationship management' (CRM). CRM encourages organisations to shift their understanding of customers from an episodic and transaction-based perspective to one that emphasises continuous 'relationship management'. CRM applications thus promise to deliver more, real-time accurate information about consumer habits and behaviours therefore allowing organisations to maximise their extraction of business value. This paper explores the ways in which such inscriptive technologies are not merely referential but also constitutive of contemporary re-presentations and ideals of the consuming subject. Focusing on what we might call the 'digital doubles' of customer relationship management the a...
Let $n\\in\\mathds{N}$ and $B_n(r,q)$ be the generic Birman-Murakami-Wenzl algebra with respect to indeterminants $r$ and $q$. It is known that $B_n(r,q)$ has two distinct linear representations generated by two central elements of $B_n(r,q)$ called the symmetrizer and antisymmetrizer of $B_n(r,q)$. These generate for $n\\geq 3$ the only one dimensional one sided ideals of $B_n(r,q)$ and generalize the corresponding notion for Hecke algebras of type $A$. In this paper the coefficients of these elements with respect to the graphical basis of $B_n(r,q)$ are determined explicitly.
A high pressure waterjet has been used to study the surface roughening of superalloys as preparation for thermal spraying. Designed experiments for Mar-M 509 and Rene 80 were carried out for the effects of jet pressure and mass of water delivered per unit area. Comparisons were made of several superalloys in terms of erosion, surface roughness and topology. The mechanism of jet erosion of Rene 80 was studied in relation to its metallurgical microstructure. An MCrAlY coating by shrouded plasma spray was made over a waterjet prepared surface with excellent bonding and having an ideally clean interface.
Solenoid transport of high current, heavy ion beams is considered for several stages of a heavy ion fusion driver. In general this option is more efficient than magnetic quadrupole transport at sufficiently low kinetic energy and/or large e/m, and for this reason it has been employed in electron induction linacs. Ideally an ion beam would be transported in a state of Brillouin flow, i.e. cold in the transverse plane and spinning at one half the cyclotron frequency. The design of appropriate solenoids and the equilibrium and stability of transported ion beams are discussed. An outline of application to a fusion driver is also presented.
A discussion of some of the difficulties with previous analyses of the resistivity of A-15 compounds is given. Precise high-temperature data on ..cap alpha..-particle- and electron-damaged Nb/sub 3/Ge and Nb/sub 3/Sn samples with different defect concentrations are presented here and analyzed in a simple way with use of a phenomenological model based on the idea that the ideal resistivity must approach some limiting value in the regime where the mean free path becomes comparable to the interatomic spacing.
A method for conditioning electron beams is proposed, making use of the TM{sub 210} mode of microwave cavities, to reduce the axial velocity spread within the beam, in order to enhance gain in resonant electron beam devices, such as the free-electron laser (FEL). Effectively, a conditioner removes the restriction on beam emittance. The conditioner is analyzed using a simple model for beam transport and ideal RF cavities. Analysis of an FEL is employed to evaluate performance with reduced axial velocity spread. Examples of FELs are presented showing the distinct advantage of conditioning.
Trapped ions are a near ideal system to study quantum information processing due to the high degree of control over the ion's external confinement and internal degrees of freedom. We demonstrate the key steps necessary for trapped ion quantum computing and focus on phonon-mediated entangling gates. We highlight several key algorithms implemented over the last decade with these gates and give a detailed description of Grover's quantum database search implemented with two trapped ion qubits.
A thermodynamic model was used to estimate enthalpy of solution of carbon dioxide (CO{sub 2}) in methyldiethanolamine (MDEA) aqueous solutions. The model was based on a set of equations for chemical equilibria, phase equilibria, charge, and mass balances. Non-ideality in the liquid phase was taken into account by interaction parameters fitted to (vapor + liquid) equilibrium data. The enthalpies of solution of CO{sub 2} were derived from the model using classical thermodynamic relations and were compared to experimental values obtained in previous works.
A thermodynamic model was used to estimate enthalpy of solution of carbon dioxide (CO_2) in methyldiethanolamine (MDEA) aqueous solutions. The model was based on a set of equations for chemical equilibria, phase equilibria, charge, and mass balances. Non-ideality in the liquid phase was taken into account by interaction parameters fitted to (vapor + liquid) equilibrium data. The enthalpies of solution of CO_2 were derived from the model using classical thermodynamic relations and were compared to experimental values obtained in previous works.
Radioactive "1"4C sucrose was found to be an ideal marker for microleakage because it did not penetrate tooth tissue, dental cement, or mounting resin. The main finding is that the adhesive cements--the glass-ionomer and polycarboxylate--are significantly more effective at preventing microleakage than are the traditional phosphate cements--silicate and zinc phosphate. The differences can be as high as two orders of magnitude. The adhesive cements provide almost perfect and reliable seals. By contrast, the nonadhesive cements are erratic sealants with most of the restorations leaking.
This article gives a survey of the history, properties and applications of 'Kevlar' aramide fibers. For example, the 'Kevlar' para-aramide fiber is used in compound materials in ship-, aircraft- and vehicle construction. 'Kevlar' is used as a replacement for asbestos, for example in brakes, clutches and seals or as rubber reinforcement (tyres, conveyor belts, hoses). The aramide fibers also offer manufacturers of ropes, hawsers and cables a near ideal range of properties. (MM).
... Removal of this layer facilitates the unreeling of cocoons into long strands of silk comparable to those derived from the domesticated mulberry silkworm (Bombyx mori, B. mori). The research was funded in part by the SABIP ('Silks as biomimetic ideals for polymers) project, which has clinched a European Research Council (ERC) grant worth almost EUR 2.3 million under the EU's Seventh Framework Programme (FP7). Presented in the journal Biomacromolecules, the findings could lead to the development of new silk industries in ...
Ascochyta blight causes significant yield loss in pulse crops worldwide. Integrated disease management is essential to take advantage of cultivars with partial resistance to this disease. The most effective practices, established by decades of research, use a combination of disease-free seed, destruction or avoidance of inoculum sources, manipulation of sowing dates, seed and foliar fungicides, and cultivars with improved resistance. An understanding of the pathosystems and the inter-relationship between host, pathogen and the environment is essential to be able to make correct decisions for disease control without compromising the agronomic or economic ideal. For individual pathosystems, some components of the integrated management principles may need to be given greater consideration tha...
Having always been at the forefront of information management and open access, High-Energy Physics (HEP) proves to be an ideal test-bed for innovations in scholarly communication including new information and communication technologies. Three selected topics of scholarly communication in High-Energy Physics are presented here: A new open access business model, SCOAP3, a world-wide sponsoring consortium for peer-reviewed HEP literature; the design, development and deployment of an e-infrastructure for information management; and the emerging debate on long-term preservation, re-use and (open) access to HEP data.
The design of High-Voltage, Direct-Current transmission cables insulated with oil-impregnated cellulose paper is constrained by the maximum temperature and the maximum steady-state and transient stresses (voltage gradients) that the cable insulation can reliably withstand over the desired operating lifetime. Because the electrical stresses in the insulation are related in a very complex fashion to temperature, applied voltage and cable geometry, iterative techniques are required to compute the values of these stresses. Digital computers are ideally suited for these iterative techniques. This paper presents the principal equations and logic needed to develop suitable computer programs.
A classical linear group GJ between the graded ring S= d=0^~Sd, where Sd is the character group of the symmetric group Sd, and the inverse limit J with respect to n of rings of symmetric polynomials in n variables. As a consequence, we complete the description of relations between generators for O(n)-invariants as well as the description of relations for invariants of mixed representations of quivers. We also obtain an independent proof of the result that the ideal of free relations for GL(n)-invariants is zero, which was proved by Donkin in [S. Donkin, Invariant functions on matrices, Math. Proc. Cambridge Philos. Soc. 113 (1993) 23-43].
In an ideal system the surface of the dish is perfectly parabolic (no contour flaws are present), and the sun rays fall on the dish surface parallel to the focal axis (no sun tracking flaws are present). These two conditions are not realizable in practice; in this case, the parabolic dish system is called real system. In this paper a procedure for analysing the flux distribution on the receiver internal surfaces is presented for a cavity receiver with a real parabolic dish collector. First, the theoretical principles are discussed. Then the effect of the inaccuracy in the collector and in the sun tracking on the insolation pattern is described using an example.
A methods is presented for an accurate numerical determination of eigenvalues of real symmetric para-p diagonal matrices. The method takes advantage of the band structure to break up the matrix into p x p blocks and performing algebraic operations including inversions on these blocks only, no matter what the size of the matrix is. The eigenvalues are determined independently one at a time. Thus any error in the determination of one eigenvalue does not affect the other eigenvalues. The method is ideally suited for the Schroedinger eigenvalue problem of the anharmonic potentials. (author).
The development of detailed chemical kinetic reaction mechanisms for analysis of autoignition and knocking of hydrocarbon fuels is described. In particular, kinetic processes of concern for the oxidation of complex hydrocarbon fuel molecules are emphasized. The wide ranges of temperature and pressure which are encountered by end gases in automobile engine combustion chambers result in extreme demands on reaction mechanisms which are intended to describe knocking conditions and predict rates of combustion and ignition. The reactions and chemical species which are most important in each temperature and pressure regime are discussed, and the validation of these reaction mechanisms through comparison with idealized experimental results is described. 53 refs., 8 figs., 5 tabs.
The effect of the electric field on an exciton confined in a pair of vertically coupled quantum dots is studied. We use a single-band approximation and a parabolic model potential. As a result of these idealizations, we obtain a numerically solvable model, which is used to describe the influence of the electron-hole interaction on the Stark effect for the lowest-energy photoluminescence lines. We show that for intermediate tunnel coupling between the dots this interaction leads to an anomalous Stark effect with an essential deviation of the recombination energy from the usual quadratic dependence on the electric field.
The linear integral equation based computer code (RON: Roger Oleg Nikolai), which was recently developed at Argonne National Laboratory, was used to calculate the self-amplified spontaneous emission (SASE) performance of the free-electron laser (FEL) being built at Argonne. Signal growth calculations under different conditions are used for estimating tolerances of actual design parameters. The radiation characteristics are discussed, and calculations using an ideal undulator magnetic field and a real measured magnetic field will be compared and discussed.
An ideal introduction to the entire process of setting up a Web site using PHP (a scripting language), MySQL (a database management system), and Apache (a Web server)* Programmers will be up and running in no time, whether they're using Linux or Windows servers* Shows readers step by step how to create several Web sites that share common themes, enabling readers to use these examples in real-world projects* Invaluable reading for even the experienced programmer whose current site has outgrown the traditional static structure and who is looking for a way to upgrade to a more efficient, user-f
A hyperbolic Stefan problem based on the linearized Gurtin-Pipkin heat conduction law is considered. The temperature and free boundary are controlled by a thermostat acting on the boundary. This feedback control is based on temperature measurements performed by real thermal sensors located within the domain containing the two-phase system and/or at its boundary. Three different types of thermostats are analyzed: simple switch, relay switch, and a Preisach hysteresis operator. The resulting models lead to integrodifferential hyperbolic Stefan problems with nonlinear and nonlocal boundary conditions. Existence results are proved in all the cases. Uniqueness is also shown, except in the situation corresponding to the ideal switch.
Anesthetic techniques vary widely in the endovascular repair of abdominal aortic aneurysms (EVAR). Previous studies have demonstrated the feasibility of using local anesthesia. However, the ideal anesthetic technique has not been determined. This study examines whether anesthesic technique influences the outcomes of EVAR. Data regarding demographics, risk factors, procedural characteristics, recovery characteristics, treatment complications, acute ( 0.05, ANOVA). From these results we concluded that EVAR with local anesthesia is a safe and efficacious method that may reduce recovery times and postoperative medical morbidity compared to use of genera1 or spinal/epidural anesthesia.
This work reviews the differences in fuel economy between two direct injection diesel engine versions through the use of a First Law energy balance and a Second Law availability balance. Both experimental data and simulated results are used in the analysis. The use of an engine simulation allowed the important processes in each engine to be analyzed and a Second Law effectiveness calculated. The availability balances and effectiveness values are used to determine the effect of major engine components on the fuel economy. A comparison is also made with an ideal engine with selected perfect or reversible processes.
The most effective way to generate electricity out of biomass is the gasification and the use of the gas in a gas engine. The conversion of the organic carbon with the gasification of biomass is higher than 95 %. Depending on the gasification concept, the efficiency of gasifiers is found between 70 and 90 %. If the pyrolysis gas is used in a gas engine, an electric efficiency of about 26 % referring to the primary amount of energy can be obtained. With efficient gas cleaning (cleaning for tar and dust), pyrolysis gas is well qualified for engine combustion. Through modern state of engine controlling there are ways to have complete control of the fluctuations in the gas composition. Furthermore, the minor calorific value of offered wood gas poses no problem for turbo charged lean-burn gas engines. ...
This patent describes an electrodeless lamp. It comprises: a microwave cavity; a source of microwaves in communication with the cavity; a lamp envelope containing a plasma-forming medium mounted within the microwave cavity; a gas manifold for feeding gas to at least one gas passageway for directing a stream of gas to the outer surface of the envelope; a gas leak passageway leading from the gas manifold; a conductive mesh assembly for retaining microwaves within the cavity and permitting light to be emitted from the cavity. The assembly including gas flow blocking means for preventing the flow of gas through the gas leak passageway when the screen is in place in the lamp; and means for shutting off the source of microwaves when the gas pressure in the manifold drops below a ...
Volumetric properties of liquid mixtures of neon and hydrogen have been calculated using path integral hybrid Monte Carlo simulations. Realistic potentials have been used for the three interactions involved. Molar volumes and excess volumes of these mixtures have been evaluated for various compositions at 29 and 31.14 K, and 30 atm. Significant quantum effects are observed in molar volumes. Quantum simulations agree well with experimental molar volumes. Calculated excess volumes agree qualitatively with experimental values. However, contrary to the existing understanding that large positive deviations from ideal mixtures are caused due to quantum effects in Ne{endash}H{sub 2} mixtures, both classical as well as quantum simulations predict the large positive deviations from ideal mixtures. Further investigations using two other Ne{endash}H{sub 2} potentials of Lennard{endash}Jones (LJ) type show that excess volumes are very sensitive to the ...
Volumetric properties of liquid mixtures of neon and hydrogen have been calculated using path integral hybrid Monte Carlo simulations. Realistic potentials have been used for the three interactions involved. Molar volumes and excess volumes of these mixtures have been evaluated for various compositions at 29 and 31.14 K, and 30 atm. Significant quantum effects are observed in molar volumes. Quantum simulations agree well with experimental molar volumes. Calculated excess volumes agree qualitatively with experimental values. However, contrary to the existing understanding that large positive deviations from ideal mixtures are caused due to quantum effects in Ne - H_2 mixtures, both classical as well as quantum simulations predict the large positive deviations from ideal mixtures. Further investigations using two other Ne - H_2 potentials of Lennard - Jones (LJ) type show that excess volumes are very sensitive to the cross-interaction potential. ...
Appendices to this summary consist of twelve individual status reports that will be available through the National Technical Information Service (NTIS) in the United States and of course limited copies will be available through NATO. The twelve report titles which are appendices to the summary are: (A) Status Report on the Limestone/Sludge Flue Gas Desulfurization Process; (B) Status Report on the Lime/Sludge Flue Gas Desulfurization Process; (C) Status Report on the Double Alkali/Sludge Flue Gas Desulfurization Process; (D) Status Report on the Sea Water Scrubbing Flue Gas Desulfurization Process; (E) Status Report on the Limestone/Gypsum Flue Gas Desulfurization Process; (F) Status Report on the Lime/Gypsum Flue Gas Desulfurization Process; (G) Status Report on the Double Alkali/Gypsum Flue Gas Desulfurization Process; (H) Status Report on ...
Gas hydrates have impacted the oil and gas industry since 1934, when they were first found to plug pipelines. Today we know that in deep oceans and in permafrost, very substantial gas reserves are present in hydrated form. Concerns are being raised about in situ dissociation for both energy and greenhouse implications upon methane release. In Japan work is underway to consider the storage of carbon dioxide, concentrated in clathrates. This talk will deal with some basic questions. Why should we be interested in gas hydrates? What are gas hydrates? How do gas hydrates form? How might hydrates impact on the energy/environmental picture?
This book discusses the progress and problems of current interest in gaseous dielectrics and their use, with special emphasis on insulation in high-voltage transmission lines and substations. Topics covered include: basic physics of gaseous dielectrics; basic mechanisms; gas decomposition, reactions and toxicity; diagnostics and field probes; gases and mixtures for GIS transformers and circuit breakers; gaseous media for discharge chemistry and etching/corona; gas engineering for pulsed power and switching; gas breakdown under steep-fronted voltages; new developments in gas-insulated equipment and gas handling; gas/insulator interface/flashover; and quality control in testing gas-insulated equipment. Contains approximately 85 papers.
Gas hydrates are crystalline substances composed of water and gas, in which a solid-water-lattice accommodates gas molecules in a cage-like structure. Gas hydrates are globally widespread in permafrost regions and beneath the sea in sediment of outer continental margins. While methane, propane, and other gases can be included in the clathrate structure, methane hydrates appear to be the most common in nature. The amount of methane sequestered in gas hydrates is probably enormous, but estimates are speculative and range over three orders of magnitude from about 100,000 to 270,000,000 trillion cubic feet. The amount of gas in the hydrate reservoirs of the world greedy exceeds the volume of known conventional gas reserves. Gas hydrates also represent a significant drilling and production hazard. A fundamental question ...
Gas hydrates are crystalline substances composed of water and gas, in which a solid-water-lattice accommodates gas molecules in a cage-like structure. Gas hydrates are globally widespread in permafrost regions and beneath the sea in sediment of outer continental margins. While methane, propane, and other gases can be included in the clathrate structure, methane hydrates appear to be the most common in nature. The amount of methane sequestered in gas hydrates is probably enormous, but estimates are speculative and range over three orders of magnitude from about 100,000 to 270,000,000 trillion cubic feet. The amount of gas in the hydrate reservoirs of the world greedy exceeds the volume of known conventional gas reserves. Gas hydrates also represent a significant drilling and production hazard. A fundamental question ...
We report the performance of a commercial recuperated micro gas turbine on biomass producer gas and mixtures of biomass producer gas with natural gas. The biomass producer gas, obtained by gasification at 850{sup o}C with air at atmospheric pressure, contains about 7% H2, 17% CO, 15% CO2, 4% CH4, 2% other hydrocarbons, 2% H2O, and a balance of N2 and Ar from air. It has a net heating value of about 6 MJ/(Nm{sup 3}). The micro gas turbine delivers full power (30 kW{sub e}) on gas mixtures with a net heating value of at least 15 MJ/(Nm{sup 3}). For gas of lower heating value, the maximum fuel gas flow allowed by the fuel control unit limits the attainable power. At reduced power, the lower limit for stable operation is a net heating value of about 8 MJ/(Nm{sup 3}). The gross efficiency of the micro ...
The situation of natural gas in the Federal Republic of Germany is described, with particular emphasis on the advantages and consequences of natural gas supply. The brochure discusses the role of natural gas on the energy market, the reliability of natural gas supply, the environmental impacts, the energy-saving effect of natural gas, natural gas prices, the competitive strength of the German gas industry, and the long-term reliability of natural gas supply. (orig.) [German] Die Situation des Erdgases in der Bundesrepublik Deutschland wird beschrieben, wobei die wichtigsten Vorteile und Auswirkungen der Erdgasversorgung besonders hervorgehoben werden. Es geht um die Stellung des Erdgases im Energiemarkt, die Sicherheit der Energieversorgung, Umweltschutz, Energieeinsparung durch Erdgaseinsatz, Erdgaspreise, ...
Effects of combustion conditions on the critical calorific value of flame blowout were reported for low calorific gas on the assumption of using coal derived gaseous fuel. Further, calculations of adiabatic flame temperature by using chemical equilibrium calculation were conducted in order to get a possibility of increasing exit gas temperature of gas turbine combustor to 1,300 C for low calorific value gas fuel. As a result, effects of (1) fuel composition, (2) preheating fuel temperature, (3) calorific value, and (4) combustion air velocity and fuel nozzle diameter, on the critical calorific values of flame blowout were clarified. In increasing exit gas temperature of gas turbine combustor to 1,300 C when using low calorific value gas fuel, it is essential to get an advanced cooling technology for the gas turbine ...
The genetic type, source and charging history of natural gas in the Yulin gas field in the Ordos Basin have been studied by combining the carbon isotopic composition of natural gas and geochemical characteristics of light hydrocarbons with carbon isotope fractionation model results and fluid inclusion analysis. The carbon isotopic composition of methane and ethane in the Yulin gas field is relatively enriched in {sup 13}C with {delta}{sup 13}C{sub 1} values ranging from - 35.3 permille to - 29.8 permille (average value = - 32.4 permille) and {delta}{sup 13}C{sub 2} ranging from - 26.3 permille to - 23.5 permille (average value = - 24.8 permille). The C{sub 7} light hydrocarbons are predominated by methylcyclohexane, accounting for 65.8% to 80.9% (average value = 71.6%), which is characteristic of coal-derived gas. Furthermore, the gas geochemistry indicates ...
The production, principal applications, characteristics and properties, advantages of the gas natural is showed. A sectorial overview of the ceramic industry and the utilization of the natural gas in the ceramic industry is presented. The expectations are systematized and the impact of the natural gas utilization in the ceramic industry is evaluated. Some conclusions are withdrawn and recommendations suggested.
A combined gas/steam turbine process includes a high-pressure furnace and a high pressure gasification unit with a mounted upstream of a combustion chamber there is a gas turbine with a waste heat system. Combustion heat which is not needed to heat the flue gas to combustion temperature is released from the furnace and transferred to ths combustion air going into the combustion chamber.
Nomographs have been developed to simplify site performance estimates for various types of gas turbine engines used for industrial applications. The nomographs can provide valuable data for engineers to use for an initial appraisal of projects where gas turbines are to be considered. General guidelines for the selection of gas turbines are also discussed. In particular, site conditions that influence the performance of gas turbines are described.
The budding natural gas markets in East Europe attract a great deal of interest from natural gas industries in the Western countries. Dutch companies, institutions and the government, too, are active in this market. So far the results have not been spectacular. An analysis is made of the present situation and the Dutch approach
This article puts the case for coal fired combined cycle gas turbine (CCGT) power plants. The need to gasify the coal for the CCGT, use of fluidised bed combustors or gasification systems, the difference in prices of coal and natural gas, and coal and natural gas reserves are discussed. (UK)
Natural gas is essential to the world economy. Gas now accounts for almost a quarter of OECD primary energy requirements and is expected to become the second most important fuel in the world in the next decade. Industrial and residential consumers increasingly rely on natural gas to keep their houses warm, their lights on and their factories running. Meanwhile the gas industry itself has entered a new phase. Where gas used to be restricted to regional markets, it is now increasingly traded on a global scale. While gas production and transport requires long-term investment, now it is optimised on a short-term basis. Demand continues to grow, but local gas production has become much more expensive. How should we react? How will demand be satisfied? What changes are required to promote flexibility and trade? What are the implications for ...
Mist eliminators for flue gas desulphurisation units remove liquid droplets entrained in the flue gas leaving the SO/sub 2/-absorber vessels. The commercial designs currently available are described.
The purpose of this project was to build a long-range, parallel hybrid gas/electric vehicle capable of driving beyond the communter capabilities of series hybrid vehicles. It was envisioned that since the gas engine would be able to independently propel t...
Radon-222 has been measured in natural gas produced from experimental geopressured-geothermal test wells. Comparison with published data suggests that while radon activity of this unconventional natural gas resource is higher than conventional gas produced in the gulf coast, it is within the range found for conventional gas produced throughout the US. A method of predicting the likely radon activity of this unconventional gas is described on the basis of the data presented, methane solubility, and known or assumed reservoir conditions of temperature, fluid pressure, and formation water salinity.
BackgroundEmphysematous cholecystitis is a variant of acute cholecystitis which is generally caused by gas-forming organisms. Emphysematous cholecystitis may cause gas spreading...Full Text Available
... Accession Number : ADD135818. Title : Performance of Titanium in Flue Gas Desulfurization Scrubber Systems,. Descriptive Note : Journal Article,. ...
A new surveillance system for Oil-Filled cable, which can provide continuous monitoring, using a newly developed optical gas sensor that can detect the concentration of the gas dissolved in the oil with extremely high sensitivity has been developed. It was proved that the degree of deterioration of the insulating oil can be detected by measuring C{sub 2}H{sub 2} and CH{sub 4} by investigating the relation between the degree of deterioration and amount of combustible gas generated. In order to detect extremely small amounts of gas, a new gas detecting method using absorption line of the gas using a frequency modulated technique has been developed. The gas detection ability was also confirmed by examination using a 66 kV of cable and the possibility of detection at an early stage is expected.
Rapid technology improvements, resulting in high efficiency, emissions reduction and low generation cost, are making gas turbines the generation technology of choice despite some recent reliability problems. The basic reason for the dominance is high efficiency. The rapid pace of gas-turbine technology improvement in the 1990s drove combined-cycle thermal efficiency to nearly 60 percent with natural gas as the fuel. It will probably go even higher after the year 2000. In addition, the gas-fired combined cycle is a bargain. With natural gas prices where they are right now, it is the least-cost generation operation for power producers with access to gas. Many will replace older, high-cost power plants with new gas-fired combined cycle power plants.
The oxygen production of a photosynthetic gas exchanger containing Chlorella pyrenoidosa (1% packed cell volume) was measured when various concentrations of carbon dioxide were present...Full Text Available
The purpose of this publication is to provide a better understanding of flue gas desulfurization. It provides brief answers to questions concerning its applicability, cost, effectiveness, and operation.
This bibliography contains 3920 references including abstracts, to information on the technology of flue gas desulfurization and denitrification. These references and others are included in the Department of Energy's Energy Data Base (EDB) through Decembe...
Tests to measure the maximum horsepower of commercial vehicles converted for use with natural gas fuel indicate a reduction of approximately 20% in horsepower compared with gasoline-driven vehicles. This reduction in horsepower resulting from the use of gas is due basically to the lower thermal efficiency of the cycle of natural gas compared with that of gasoline and to its lower volumetric efficiency, since natural gas is injected into the combustion chamber in gaseous form, unlike gasoline, in which part of the fuel entering the cylinder is in the liquid phase. Natural gas used as a fuel generates lower quantities of air pollutants, particularly unburned hydrocarbons (HCs) and carbon monoxide (CO). Despite the downside of reduced horsepower, the use of natural gas as a fuel for automotive vehicles equipped with Otto-cycle engines is economically viable owing ...
The natural gas industry has proposed an increase in the DOE gas R&D budget from about $100 million to about $250 million per year for each of the next 10 years. The proposal includes four programs: natural gas supplies, fuel cells, natural gas vehicles and stationary combustion systems. This paper is a qualitative assessment of the gas industry proposal and recommends a natural gas R&D strategy for the DOE. The methodology is a conceptual framework based on an analysis of market failures and the energy policy objectives of the DOE`s (1991) National Energy Strategy. This framework would assist the DOE in constructing an R&D portfolio that achieves energy policy objectives. The natural gas supply program is recommended to the extent that it contributes to energy price stability. Stationary combustion programs are supported on ...
Prepared to make housing project managers, maintenance engineering staff, and designers and architects of HUD - assisted and HUD - insured housing projects and mobile home parks aware of their responsibilities under the Natural Gas Pipeline Safety Act, this handbook provides technical guidance for the reduction of gas leaks and the handling of gas leak incidents in residential areas. The hazards of natural gas, concern over gas safety in residential areas, applicable codes and standards, and sources of information and help are reviewed, along with maintenance and engineering considerations relating to gas pipe failures, the detection of gas leaks, appliance servicing, and pipe installation, repair, and replacement. Housing management considerations are also examined, with attention to recordkeeping and reporting, emergency contingency ...
Gas Supplies of Interstate Natural Gas Pipeline Companies 1987 was prepared by the Reserves and Natural Gas Division, Office of Oil and Gas, Energy Information Administration (EIA). The publication provides information on the total reserves, production, and deliverability capabilities of the 87 interstate pipeline companies required to file the Federal Energy Regulatory Commission (FERC) Form 15, ''Interstate Pipeline's Annual Report of Gas Supply.'' This publication is the 25th in a series of annual reports on the total gas supplies of interstate pipeline companies since the inception of individual company reports to the Federal Power Commission (FPC) in 1964 for report year 1963. This publication provides information on the interstate pipeline companies' supply of natural gas during ...
The corrosion behavior of 304 stainless steel was characterized with cyclic voltammetry in a eutectic Li/K and Li/Na carbonate melt under anode and cathode gas of the molten-carbonate fuel cell (MCFC). The corrosion rate of 304 steel was determined in four different environments of the MCFC with electrochemical methods and from cross-sectional analysis of corrosion layers. These four environments were open-circuit and MCFC-load conditions both under anode and cathode gas. At open-circuit conditions corrosion was more severe under the oxidizing cathode gas then under the reducing anode gas. On the contrary, at load conditions corrosion was more severe under anode than under cathode gas. The anodic polarization under anode gas enhances corrosion, whereas the high anodic polarization under cathode gas leads to anodic protection. Corrosion ...
As the Electric Power Industry is actively preparing for a restructured future where retail wheeling is practiced ideally and efficiently in a competitive market-based environment, concerns may arise legitimately on how system reliability and integrity can be ensured in an environment where markets have an enhanced role. As these concerns may be justified, at least for a transition period, this paper presents a proposal which outlines how the generally accepted requisite capacity, energy, and ancillary services standards may be satisfied through market reliance and minimal coordination by a Reliability Monitoring and Ancillary Services Managing Entity or Independent System Operator. A Strawman detailing one -- and by no means the only -- future scenario inspired by the recent NEPOOL restructuring discussions in New England is presented to demonstrate that market-based competition and flexibility are compatible with a reliable Power System.
The observation that Type Ia supernovae are fainter than expected given their red shifts has led to the conclusion that the expansion of the universe is accelerating. The widely accepted hypothesis is that this acceleration is caused by a cosmological constant or, more generally, some dark energy field that pervades the universe. This hypothesis presents a challenge to physics so severe that one is motivated to explore alternative explanations. In this paper, we explore whether the data from Type Ia supernovae can be explained with an idea that is almost as old as that of the cosmological constant, namely, that the strength of gravity varies on a cosmic timescale. This topic is an ideal one for investigation by an undergraduate physics major because the entire chain of reasoning from models to data analysis is well within the mathematical and conceptual sophistication of a motivated undergraduate.
"2"0"3Pb, an ideal radionuclide for toxicological studies, can be artificially produced by bombardment of a thallium target but due to the extreme toxicity of thallium the lead has to be separated completely from the thallium. A single step method is here described consisting of removing the thallium from a dilute acid chloride solution using a continuous ethyl ether extraction. Essentially all of the thallium and almost none of the lead is removed in a 3-hr extraction. Because the ether is recycled, only about 30 ml are needed. If other contaminants are introduced from the bombardment and its subsequent manipulations, an additional step is used in which the lead is extracted from an iodide solution with methyl isopropyl keton. (U.K.).
An effective computer program for three dimensional relativistic hydrodynamical model has been developed. It implements a new approach to the early hot phase of relativistic heavy-ion collisions. The computer program simulates time-space evolution of nuclear matter in terms of ideal-fluid dynamics. Equations of motions of hydrodynamics are solved making use of finite difference methods. Commonly-used algorithms of numerical relativistic hydrodynamics RHLLE and MUSTA-FORCE have been applied in simulations. To speed-up calculations, parallel processing has been made available for solving hydrodynamical equations. The test results of simulations for 3D, 2D and Bjorken expansion are reported in this paper. As a next step we plan to implement the hadronization algorithm by implementing the continuous particle emission for freeze-out and comparing it with Cooper-Frye formula.
The theoretical performance of ideal single- and multijunction cells are compared at 100xconcentration under a range of cloudless-sky conditions. The sensitivities of device performance to cell temperature and spectral variations are shown to depend on the number of junctions (one, two or three), the way in which the junctions are connected (series, parallel or independent), and the band gaps of the devices. The average performances of all of the multijunction devices surpass that of a single-junction GaAs device, but the inconsistency in performance of some of the multijunction devices is significant for large variations in cell temperature and incident spectrum. The choice of band gap and connection scheme is more important than the number of junctions in determining the consistency of device performance. (orig.).
Simple hydroxamic acids are shown to be useful reagents for the separation of Np and Pu from U within simplified, single cycle Purex flowsheets. They are compatible with the use of centrifugal contactors and laboratory scale flowsheet trials with aceto-hydroxamic acid have demonstrated high actinide recoveries and decontamination factors on products for active feeds of up to 40 wt.% Pu. They therefore show many ideal characteristics for Pu and Np recovery within flowsheet options for actinide recovery in advanced fuel cycles. Furthermore, in order to optimise the routing of Np with the Pu product in advanced flowsheets, additional studies of Np extraction in the primary co-decontamination contactor, prior to U/Pu partition, have been undertaken, combining experiment, modelling and flowsheet tests. (author)
Introduction.Microfluidic technology allows fast reactions in a simple experimental setup, while using very low volumes and amounts of starting material. Consequently, microfluidic technology is an ideal tool for radiolabeling reactions involving short-lived positron emitters. Optimization of the complex array of different reaction conditions requires knowledge of the different reaction parameters linked to the microfluidic system as well as their influence on the radiochemical yields. 1-(5-Deoxy-5-fluoro-?-d-arabinofuranosyl)-2-nitroimidazole ([18F]FAZA) is a frequently used radiotracer for PET imaging of tumor hypoxia. The present study describes the radiosynthesis of [18F]FAZA by means of microfluidic technology and subsequent small animal PET imaging in EMT-6 tumor-bearing mice.Methods...
A protocol adapter ideally suited to enable enterprises to gradually transition from SOAP Web Services to RESTful HTTP Web Services without impacting existing clients is presented in this paper. The inherent advantage of such a transition is the visibility of RESTful HTTP messages to Web intermediaries such as caches. In contrast, SOAP messages are opaque, which disables Web intermediaries. While both approaches can use HyperText Transfer Protocol (HTTP) for message transfer, the paradigms contrast sharply. SOAP uses an interface specific approach whereas RESTful HTTP uses a Uniform Interface approach. SOAP marks up its payload with eXtensible Markup Language (XML) whereas in certain situations RESTful HTTP requires no XML. We present the disadvantages of the SOAP approach and outline how ...
The major problem of measurement of a power spectral density (PSD) distribution of surface heights with surface profilometers arises due to the unknown Modulation Transfer Function (MTF) of the instruments, which tends to distort the PSD at higher spatial frequencies. The special mathematical properties of binary pseudo-random patterns make them an ideal basis for developing MTF calibration test surfaces. Two-dimensional binary pseudo-random arrays (BPRAs) have been fabricated and used for the MTF calibration of the MicroMap{trademark}-570 interferometric microscope with all available objectives. An investigation into the effects of fabrication imperfections on the quality of the MTF calibration and a procedure for accounting for such imperfections are presented.
A brief survey is presented of the methods of preparation and of the applications of radiopharmaceuticals labelled with short-lived positron radionuclides "1"1C, "1"8F, "1"3N and "1"5O which, thanks to their energy level schemes, short half-life and the 511 keV photon radiation energy are almost ideal tracers in modern nuclear medicine and pharmacology. In conjunction with computerized tomography, they represent one of the most sensitive diagnostic imaging methods, the so-called positron emission tomography. In addition, their incorporation in the molecule of a pharmaceutical does not change the biological and chemical properties of the original molecule unlike those of radiopharmaceuticals labelled with technetium, iodine, etc. (author). 125 refs.
Positronium is an ideal system for the research of the bound state QED. New precise measurement of orthopositronium decay rate has been performed with an accuracy of 150 ppm, and the result combined with the last three is 7.0401 +- 0.0007 mu s^-1. It is the first result to validate the 2nd order correction. The Hyper Fine Splitting of positronium is sensitive to the higher order corrections of the QED prediction and also to the new physics beyond Standard Model via the quantum oscillation into virtual photon. The discrepancy of 3.5 sigma is found recently between the measured values and the QED prediction (O(alpha^3)). It might be due to the contribution of the new physics or the systematic problems in the previous measurements: (non-thermalized Ps and non-uniformity of the magnetic field). We propose new methods to measure HFS precisely without the these uncertainties.
SummaryA meshless numerical model is proposed to investigate shallow-water dam break flows in 1D open channels. The numerical model is to solve the shallow water equations (SWE) based on smoothed particle hydrodynamics (SPH). The concept of slice water particles (SWP) is adopted in the SPH-SWE formulation. The numerical sensitivity analysis is first performed to study the appropriate SWP number and variable smoothing length through dam break flows in an idealized 1D channel with dry/wet beds. Extensive validation by comparison with laboratory and field data is next conducted for four benchmark problems, including dam break flows through a rough flat channel, a rough bumpy channel with various downstream boundary conditions, a nonprismatic channel, and a realistic scale model of the Toce ri...
Grating cloaks are a variation of dielectric carpet (or ground- plane) cloaks. The latter were introduced by Li and Pendry. In contrast to the numerical work involved in the quasi-conformal carpet cloak, the refractive-index profile of a conformal grating cloak follows a closed and exact analytical form. We have previously mentioned that finite-size conformal grating cloaks may exhibit better cloaking than usual finite-size carpet cloaks. In this letter, we directly visualize their performance using photorealistic ray-tracing simulations. We employ a Newtonian approach that is advantageous compared to conventional ray tracing based on Snell's law. Furthermore, we quantify the achieved cloaking quality by computing the cross-correlations of rendered images. The cross-correlations for the grating cloak are much closer to 100% (i.e., ideal) than those for the Gaussian carpet cloak.
An experimental capability, developed at Lawrence Livermore National Laboratory (LLNL), is being used to study the yield behavior of elastic-plastic materials. The objective of our research is to develop better constitutive equations for polycrystalline metals. We are experimentally determining the multidimensional yield surface of the material, both in its initial state and as it evolves during large inelastic deformations. These experiments provide a more complete picture of material behavior than can be obtained from traditional uniaxial tests. Experimental results show that actual material response can differ significantly from that predicted by simple idealized models. These results are being used to develop improved constitutive models of anisotropic plasticity for use in continuum computer codes.
We outline a neo-Meinongian framework labeled as Modal Meinongian Metaphysics (MMM) to account for the ontology and semantics of fictional discourse. Several competing accounts of fictional objects are originated by the fact that our talking of them mirrors incoherent intuitions: mainstream theories of fiction privilege some such intuitions, but are forced to account for others via complicated paraphrases of the relevant sentences. An ideal theory should resort to as few paraphrases as possible. In Sect.?1, we make this explicit via two methodological principles, called the Minimal Revision and the Acceptability Constraint. In Sect.?2, we introduce the standard distinction between internal and external fictional discourse. In Sects.?3?5, we discuss the approaches of (traditional) Meinongia...
This paper presents a theoretical analysis based on the second law of thermodynamics for estimating the minimum work required for air dehumidification process to produce potable water in a humidification-dehumidification (HD) desalination cycle. The general air dehumidification process is analyzed through an equivalent path consisting of an isothermal dehumidification followed by a sensible cooling Dehumidification is treated as separation process of an ideal mixture consisting of two components, namely air and water vapor. The present analysis assumes the dead state to be the dry ambient and the final state for complete dehumidification to be saturated air at 0.01?C. Contours of the minimum work are plotted on psychrometric chart and presented as a handy engineering tool to estimate the p...
Magnesium alloys are ideal candidates to benefit from equal channel angular extrusion (ECAE) because of their poor forming characteristics due to a hcp structure. In this study, ECAE processing was applied to ZK31 and AZ31 magnesium alloys under various conditions. The grain size of as-ECAE specimens decreases with decreasing the processing temperature, however, the grain size decreases slightly with increasing number of repetitive processing. Both the tensile strength and 0.2% proof stress of as-ECAE specimens are high when processed at low temperature, but the elongation is high when processed at high temperature. Crystal orientation is different in the two alloys and it also varies according to the processing temperature for the two alloys. The difference of the crystal orientation influences the tensile properties, especially 0.2% proof stress. (orig.)
1,3-Dienes derived from steroidal D-ring C17-ketones undergo Ni(II)-catalyzed hydrovinylation to give 1,2- or 1,4-addition of ethylene. Using finely tuned phosphoramidite ligands it is possible to synthesize either the C20 (R)- or the C20 (S)-derivatives without mutual contamination. The proportion of the 1,4-adduct, which is also formed stereoselectively, can be minimized by optimizing the reaction conditions. Since the two alkenes in the resultant dienes have differing steric demands for many potential reactions, and are ideally juxtaposed for further D-ring functionalization, these intermediates could be useful for the preparation of biologically important compounds such as vitamin D analogs and various antitumor steroidal glycosides.
We discuss theoretically and numerically the intramolecular form factor $F(q)$ in dense polymer systems. Following Flory's ideality hypothesis, chains in the melt adopt Gaussian configurations and their form factor is supposed to be given by Debye's formula. At striking variance to this, we obtain noticeable (up to 20%) non-monotonic deviations which can be traced back to the incompressibility of dense polymer solutions beyond a local scale. The Kratky plot ($q^2F(q)$ {\\it vs.} wavevector $q$) does not exhibit the plateau expected for Gaussian chains in the intermediate $q$-range. One rather finds a significant decrease according to the correction $\\delta(F^{-1}(q)) = q^3/32\\rho$ that only depends on the concentration $\\rho$ of the solution, but neither on the persistence length or the interaction strength.
Large single crystals of PETN, RDX, and TNT can be grown easily from evaporating ethyl acetate solutions. The crystals all share a similar type of defect that may not be commonly recognized. The defect generates conical faces ideally mosaic crystals, and may account for the polymorphs'' of TNT and detonator grades of PETN. TATB crystals manufactured by the amination of trichlorotrinitrobenzene in dry toluene entrain two forms of ammonium chloride. One of these forms causes worm holes'' in the TATB crystals that may be the reason for its unusually low failure diameters. Strained HMX crystals form mechanical twins that can spontaneously revert back to the untwinned form when the straining force is removed. Large strains or temperatures above 100[degrees]C lock in the mechanical twins.
Large single crystals of PETN, RDX, and TNT can be grown easily from evaporating ethyl acetate solutions. The crystals all share a similar type of defect that may not be commonly recognized. The defect generates conical faces ideally mosaic crystals, and may account for the ``polymorphs`` of TNT and detonator grades of PETN. TATB crystals manufactured by the amination of trichlorotrinitrobenzene in dry toluene entrain two forms of ammonium chloride. One of these forms causes ``worm holes`` in the TATB crystals that may be the reason for its unusually low failure diameters. Strained HMX crystals form mechanical twins that can spontaneously revert back to the untwinned form when the straining force is removed. Large strains or temperatures above 100{degrees}C lock in the mechanical twins.
Entorhinal grid cells in mammals fire as a function of animal location, with spatially periodic response patterns. This nonlocal periodic representation of location, a local variable, is unlike other neural codes. There is no theoretical explanation for why such a code should exist. We examined how accurately the grid code with noisy neurons allows an ideal observer to estimate location and found this code to be a previously unknown type of population code with unprecedented robustness to noise. In particular, the representational accuracy attained by grid cells over the coding range was in a qualitatively different class from what is possible with observed sensory and motor population codes. We found that a simple neural network can effectively correct the grid code. To the best of our kn...
Legal context Can we imagine the patent case as a play? As Johann Huizinga, the Dutch historian and cultural theorist writes, "The lawsuit can be regarded as a game of chance, a contest or a verbal battle." According to Huizinga, science is actually a play itself, thus scientific recognition is nothing more than the solution of a task of a play. In this context, a patent suit is nothing more than a play played with the play (in other words a `Game of the Game'). Key points and practical significance In our view in an ideal world the enforcement of patent rights should be a game of chess, where all the information is available to both players and the rules are simple and unquestionable. All players accept, understand and interpret the rules the same way. The referee has no role to play. How...
Abstract In the 1990s, significant efforts were invested in the research and development of food-grade expression systems in lactic acid bacteria (LAB). At this time, Lactococcus lactis in particular was demonstrated to be an ideal cell factory for the food-grade production of recombinant proteins. Steady progress has since been made in research on LAB, including Lactococcus, Lactobacillus and Streptococcus, in the areas of recombinant enzyme production, industrial food fermentation, and gene and metabolic pathway regulation. Over the past decade, this work has also led to new approaches on chromosomal integration vectors and host/vector systems. These newly constructed food-grade gene expression systems were designed with specific attention to self-cloning strategies, food-grade selection...
The present paper deals with the experimental determination of pressure drop across a four-cusped vertical channel. This geometry represents, ideally, the blockage condition in a typical pressurized water reactor with core degraded by accident. Experiments were performed for both single and two-phase flow. Water was utilized for the single-phase measurements whilst simultaneous flow of air and water simulated the steam-water flow. Observation of the prevailing two-phase flow regime was carried out, so that its mechanism could be fully understood. The averaged void fraction was also measured, by the gamma-ray attenuation technique. A wide range of water and air mass flow rates was covered, so that all flow conditions, possible to exist in a reactor with LOCA, could be investigated. New correlations for pressure drop are proposed. (Author).
Oils, tars, and degraded oils of varying degrees of biodegradation occur in the Permian Phosphoria Formation along the eastern flank of the Wind River mountains, Wyoming, US. Biodegradation has altered the isomer distributions of steranes, the hopanes, and the mono- and triaromatised steroids in these oils. The conventional maturity parameters based on these biomarkers are of limited use in estimating their maturity. On the other hand, even in severely biodegraded oils the vanadylporphyrin distributions are unaltered. Because of this, the Porphyrin Maturity Parameter (PMP) derived from the vanadylporphyrin distribution is an ideal parameter for estimating the maturity of these oils. This study also confirms the previous observation that T[sub s] and T[sub m] are unaffected by even severe biodegradation. 14 refs., 5 figs., 2 tabs.
Chitosan (a?-(1-4)-amino-2-deoxy-b?-D-glucan) is a deacetylated form of chitin, a polysaccharide from crustacean shells. Its unique characteristics, such as positive charge, biodegradability, biocompatibility, nontoxicity, and rigid structure, make this macromolecule ideal for an oral vaccine delivery system. We prepared reverse-phase evaporation vesicles (REVs) sandwiched by chitosan (Chi) and polyvinylic alcohol (PVA). However, in this method, there are still some problems to be circumvented related to protein stabilization. During the inverted micelle phase of protein nanoencapsulation, hydrophobic interfaces are expanded, leading to interfacial adsorption, followed by protein unfolding and aggregation. Here, spectroscopic and immunological techniques were used to ascertain the effects ...
The energy dispersive beamline X6A at the National Synchrotron Light Source employs a curved crystal monochromator (polychromator) which focuses a range ([similar to]1 keV) of x-ray energies into a narrow (100--120 [mu]m) line image. Although this beamline was constructed primarily for time-dependent EXAFS experiments, we have begun to explore the use of this instrument for energy dispersive diffraction experiments with different types of sample including macromolecular crystals. The tunability ([ital E]=6.5 to 21 keV) and flexibility ([Delta][ital E]=100--1000 eV) of the instrument makes the beamline ideal as a test bed for the application of polychromatic single-crystal diffraction techniques to different chemical or biological materials.
In order to alleviate the inefficiencies caused by the interaction of the logic and functional sides, integrated languages may take advantage of \\emph{demand} information -- i.e. knowing in advance which computations are needed and, to which extent, in a particular context. This work studies \\emph{demand analysis} -- which is closely related to \\emph{backwards strictness analysis} -- in a semantic framework of \\emph{partial predicates}, which in turn are constructive realizations of ideals in a domain. This will allow us to give a concise, unified presentation of demand analysis, to relate it to other analyses based on abstract interpretation or strictness logics, some hints for the implementation, and, more important, to prove the soundness of our analysis based on \\emph{demand equations}. There are also some innovative results. One of them is that a set constraint-based analysis has been derived in a stepwise manner using ideas taken from the area of program ...
This studys purpose was to explore the relationship between creativity and integrity in the ideation phase of feature filmmaking. Integrity refers to ones self-defined ability to maintain authenticity and moral autonomy while preserving ones sense of membership and loyalty to the team or organization. When team members choose elements for the screenplays story that they feel will attract the ideal audience, the dynamic tension between creativity and integrity is most apparent. The forces at play during this phase of work yielded the research question: In what ways and to what degree do screenwriters andor studio executives feel their personal integrity is in alignment with the creative process of feature film development? Several concepts from the literature formed the design around which ...
The earthworm gut provides ideal in situ conditions for ingested heterotrophic soil bacteria capable of anaerobiosis. High amounts of mucus- and plant-derived saccharides such as glucose are abundant in the earthworm alimentary canal, and high concentrations of molecular hydrogen (H2) and organic acids in the alimentary canal are indicative of ongoing fermentations. Thus, the central objective of this study was to resolve potential links between fermentations and active fermenters in gut content of the anecic earthworm Lumbricus terrestris by 16S ribosomal RNA (rRNA)-based stable isotope probing, with [13C]glucose as a model substrate. Glucose consumption in anoxic gut content microcosms was rapid and yielded soluble organic compounds (acetate, butyrate, formate, lactate, propionate, succi...
Background: Chloroquine has in-vitro activity against influenza and could be an ideal candidate for worldwide prevention of influenza in the period between onset of a pandemic with a virulent influenza strain and the development and widespread dissemination of an effective vaccine. We aimed to assess the efficacy of such an intervention. Methods: In this randomised, double-blind, placebo-controlled trial done at a single centre in Singapore, we randomly assigned (1:1) healthy adults to receive chloroquine phosphate (500 mg/day for 1 week, then once a week to complete 12 weeks) or matching placebo by use of a computer-generated randomisation list. Participants filled an online symptom diary every week, supplemented by daily diaries and self-administered nasal swabs when unwell. Haemagglutin...
Calibration-Free Laser-Induced Breakdown Spectroscopy (CF-LIBS) has been proposed several years ago as an approach for quantitative analysis of Laser-Induced Breakdown Spectroscopy spectra. Recently developed refinement of the spectral processing method is described in the present work. Accurate quantitative results have been demonstrated for several metallic alloys. However, the degree of accuracy that can be achieved with Calibration-Free Laser-Induced Breakdown Spectroscopy analysis of generic samples still needs to be thoroughly investigated. The authors have undertaken a systematic study of errors and biasing factors affecting the calculation in the Calibration-Free Laser-Induced Breakdown Spectroscopy spectra processing. These factors may be classified in three main groups: 1) experi...
System identification refers to estimation of process parameters and is a necessity in control theory. Physical systems usually have varying parameters. For such processes, accurate identification is particularly important. Online identification schemes are also needed for designing adaptive controllers. Real processes are usually of fractional order as opposed to the ideal integral order models. In this paper, we propose a simple and elegant scheme of estimating the parameters for such a fractional order process. A population of process models is generated and updated by particle swarm optimization (PSO) technique, the fitness function being the sum of squared deviations from the actual set of observations. Results show that the proposed scheme offers a high degree of accuracy even when the observations are corrupted to a significant degree. Additional schemes to improve the accuracy still further are also proposed and analyzed.
This contribution deals with identification of fractional-order dynamical systems. System identification, which refers to estimation of process parameters, is a necessity in control theory. Real processes are usually of fractional order as opposed to the ideal integral order models. A simple and elegant scheme of estimating the parameters for such a fractional order process is proposed. This method employs fractional calculus theory to find equations relating the parameters that are to be estimated, and then estimates the process parameters after solving the simultaneous equations. The said simultaneous equations are generated and updated using particle swarm optimization (PSO) technique, the fitness function being the sum of squared deviations from the actual set of observations. The data used for the calculations are intentionally corrupted to simulate real-life conditions. Results show that the proposed scheme offers a very high degree of accuracy even for ...
Full text: Chemical-technology approaches allowing to intensification the prevention processes of gas hydrates formation at motion of gas-liquid stream of natural gas in system natural gas well - gas wire have been worked up. Technological regimes of treatment of gas stream have been determined. Linear correlation dependences inhibitor electrolytes contained hydrated ions with different ion radii and charges of subgroups of alkali elements with one - type electron configuration were obtained. Important physico-chemical parameters of electrolytes have been determined: activity; coefficients of activity, viscosity, diffusion; density; heat capacity; heat conductivity; surface tension and freezing-point. The features of continuous influence of inhibitory factors on process of gas flow at low temperatures and relatively high pressure differences ...
The passive continental margin in the northern South China Sea is a weakly active area. It has been found to be favorable for large gas field development and also to be profitable for gas hydrate. The active faults, diapir structure, slump deposits, faults break of slopes, gas chimneys and sandstone of submarine fan, control the concentration of gas hydrate. Gas chimneys are widely distributed in the northern South China Sea. They supply the pathway for migration of deeper gas to gas hydrate stability zones especially in the basin of tectonic inactive zone. This paper discussed the geological structures of gas hydrate occurrence in gas fields and presented a detailed analysis of gas chimneys within the northern slope of the South China Sea. The paper described the geological ...
The paper deals with a model in which the motion of a gas in plasma accerators and high-curent discharges in the present of a skin effect is treated as expulsion by a 'magnetic piston' under the action of surface current flow. Specifically examined is the situation where the initial gas pressure is negligible in comparison with the magnetic pressure, and the motion of the gas may be treated as a self-simulating one. A system of hydrodynamic equations of the problem is derived and integrated by Adam's method. Results are plotted and discussed.
Gas contaminated with at least one noxious component, such as SO/sub 2/, HF or NOx, is scrubbed with a clear, calcium-containing, initially-basic washing liquid which also comprises the anion of a strong inorganic acid, that of a polybasic carboxylic acid and, optionally, that of a monobasic carboxylic acid. Apparatus is provided for scrubbing the gas, oxidizing produced calcium bisulfite to calcium sulfate, separating out and removing solids, and recirculating clarified liquid for scrubbing contaminated gas.
The Rayleigh scattering length has been calculated for rare-gas liquids in the ultraviolet for the frequencies at which they luminesce. The calculations are based on the measured dielectric constants in the gas phase, except in the case of xenon for which measurements are available in the liquid. The scattering length mayplace constraints on the design of some large-scale detectors, using uv luminescence, being proposed to observe solar neutrinos and dark matter. Rayleigh scattering in mixtures of rare-gas mixtures is also discussed.
The fission gas xenon bonded in bubbles, in pore, and in the lattice of mixed carbide fuels is measured by electron-probe microanalysis. Radial xenon distribution and release curves are determined and are calibrated by gas chromatography of the bonded fission gas and by burnup analysis in the respective pin sections of the irradiation experiments FR2 6A and 6C, Mol 11/K 2, and DFR 330/1. The results are correlated to the microstructure of the fuel, bonding medium, temperature, and burnup. (Auth.).
Analysis of the coke gas combustion porcess is presented. Standard kinetic relationships were utilized. Calculations were performed for coke gas with high and low content of H/sub 2/ and for blasting air 20 and 100/sup 0/C. Temperature relationships, composition of gas combustion products and release of nitrogen oxides were determined. Results are analyzed which will make it possible to control the composition of combustion products.
This thesis dealt with the metal-organic gas phase epitaxy with nitrogen as carrier gas. For this first by means of three-dimensional modelings of the epitaxy process the influence of the carrier gas on the processes was explained. The optimization of the growth parameter for the whole light-emitting-diode structure in double-hetero arrangement resulted that an a temperature of 770 C and a V/ III-ratio of 150 layers with a high crystal quality could be reached.
Plasma with a gas temperature below room temperature is not yet fully understood although it is expected to be an attractive tool for applications to material processing. In the present work, gas-temperature-dependent generation of a cryoplasma jet was studied. So far, we have generated a helium cryoplasma jet (296-5 K) under atmospheric pressure. At gas temperatures below 20 K, the helium excimer, He2, was observed clearly from by optical emission spectroscopy.
The gas composition of recent thermal waters is in perfect conformity with their geologic-tectonic positions. The composition of gas-liquid inclusions in the basic-hyperbasic xenoliths of basaltoid lavas depends on the depth from which xenoliths are supplied. (The depth is determined by using the methods of geological thermobarometers). By comparing available data the conclusion was drawn that the gas compositions of thermal waters reflect the depth of generation of deep fluid which heats them and depends on the penetration depth of the fluid-conducting fissure zones.
Spark ignition internal combustion engines perform satisfactorily when the fueled with biomass producer gas from a fluidized bed gasifier. Although power output is reduced compared to natural gas levels, full power recovery can be achieved with a relatively low level of supercharging. Important considerations are an adequate fuel delivery system and adquate gas cleaning. ref.
... harassment, incidental to construction and operation of an offshore liquefied natural gas (LNG) facility. Under the Marine Mammal Protection ... ...
The primary objective of this study is to assess the oil and gas potential of the West Siberian Basin of Russia. The study does not analyze the costs or technology necessary to achieve the estimates of the ultimate recoverable oil and gas. This study uses reservoir data to estimate recoverable oil and gas quantities which were aggregated to the field level. Field totals were summed to a basin total for discovered fields. An estimate of undiscovered oil and gas, from work of the US Geological Survey (USGS), was added to give a total basin resource volume. Recent production decline points out Russia`s need to continue development of its discovered recoverable oil and gas. Continued exploration is required to discover additional oil and gas that remains undiscovered in the basin.
Details of a 1 day conference designed to create more efficient interactions between the gas supply and electricity systems in Ontario and new models for gas supply and the electricity system were presented. Market efficiency, generators' perspectives on critical gas issues, an overview of the North American gas and an outline of issues concerning Ontario were discussed. A natural gas industry forecast and issues concerning marketers and producers were presented. The terms on which gas is bought and sold were discussed. Regulatory tools, cost allocation and issues relating to unbundling were also presented. Infrastructure needs were reviewed, as well as basic market structures. It was suggested that appropriate commercial service options need to be developed and approved, including cross-utility services.
The Department of Energy has proposed a rulemaking process to set minimum standards for the efficiency of gas ranges under the National Appliance Energy Conservation Act (NAECA). The Gas Research Institute is compiling information on annual household range gas usage in order to prepare a response to the proposed rulemaking. The data base from the Northern Illinois Gas residential load study provides recent information (data taken from 1990 through 1992) over a comprehensive study of household types and appliance and user characteristics (150 variables noted for each household). The stated Objective is to study the Northern Illinois Gas residential load study data base and to evaluate its effectiveness in predicting annual household gas usage.
Research was performed to assess the feasibility of barrier membrane substances, for use within mining or associated high risk environments, in restricting the diffusion transport of radon gas quantities. Specific tests were conducted to determine permeability parameters of a variety of membrane materials with reference to radon flow capabilities. Tests were conducted both within laboratory and in-situ emanation environments where concentrations and diffusion flows of radon gas were known to exist. Equilibrium radon gas concentrations were monitored in initially radon-free chambers adjacent to gas sources, but separated by specified membrane substances. Membrane barrier effectiveness was demonstrated to result in reduced emanation concentrations of radon gas within the sampling chamber atmosphere. Minimum gas concentrations were evidenced where the barrier ...
The light gain due to S/sub 2/ molecules in a supersonically cooled gas mixture is calculated. The S/sub 2/ molecules formed due to the recombination of the sulfur atoms, and the combustion gas mixture was preheated in a precombustion chamber. Optimal gas flow and nozzle parameters are found which correspond to the highest possible light gain using Cs/sub 2/-Ar and S/sub 2/-Ar gas mixtures. The steady state gas flow in the nozzle was calculated, taking into account the chemical reactions in the one-dimensional approximation. It is shown that the maximum gain values vary in the 0.0001-0.002 range for gas pressures in the precombustion chamber in the range 10-100 atm. The optimal initial relative concentration of Cs/sub 2/ molecules and S/sub 2/ molecules are given. 32 references.
The use of natural gas in China is still relatively immature, as gas production only supplies a low percentage of the domestic energy system. In contrast, Chinese economy mainly relies on coal with a 67% share of the total primary energy supply. The environmental impact from this high coal dependence is significant and planners have sought for cleaner energy sources. Natural gas is both cleaner and generally more efficient than coal and gas consumption is rising quickly due to these facts. The growth tendency indicates that natural gas will become an important substitution for coal in some parts of the Chinese primary energy consumption. To quantify this tendency, this paper uses a system dynamics model to create a possible outlook. The results show that the gas consumption in China will c...
Biomass gasification provides the potential to efficiently and economically produce a renewable source of a clean gaseous fuel suitable for power generation or synthesis gas (syngas) applications. An important side benefit of the use of biomass is the effective minimization of the primary greenhouse gas, carbon dioxide (CO{sub 2}), by providing a means to close-loop the CO{sub 2} cycle. However, high molecular weight hydrocarbon constituents (tar) in the product gas from gasification can complicate the downstream uses of the gas. This paper discusses both the development of a low cost, disposable catalyst system that can eliminate these heavy hydrocarbons from the gas and the use of the catalyst in conjunction with the Battelle high-throughput gasification process for power generation and synthesis applications. (author)
The presence of an extraneous light gas must be taken into account in consideration of centrifugal separation of uranium isotopes, when there is inevitable leakage of such a gas through the gas sealant and/or leaking in from the atmosphere. Consideration is first given to the influence of the presence of the light gas on the maximum separative power. Then the basic equation for isotope separation containing a light gas is derived from Hirschfelder's diffusion equations. This equation is solved and the separative performance is expressed in terms of the shape factor and reflux parameter. The formulas for expressing the flow configurations of the gases are obtained for a simple model in which inflow and outflow prevail throughout the centrifuge. The corresponding equation for a model in which the gases flow in two concentric thin streams is also derived. It is concluded that the ...
A patent is claimed for a process by which a low-hydrogen gas containing at least 90 percent by volume of methane which is suited for natural gas substitution is produced by transformation of vaporizable hydrocarbons with the aid of steam in the presence of a catalyst containing nickel, at temperatures of 350 to 600/sup 0/C and at increased pressure. Hydrocarbons and steam are supplied to the reaction in mixed form with recycle product gas. Per kilogramme of hydrocarbons to be converted in the high btu gas reactor, less than 1 kilogramme of fresh steam is needed. High btu gas is fed back from the high btu gas reactor to the input end of the same via a gas cycle comprising a cooler, a carbon dioxide absorption device, and a saturator. Between the carbon dioxide absorption device and the saturator a product gas is branched ...
The performance of the gas-jet transport system coupled to the RIKEN gas-filled recoil ion separator GARIS was investigated using 255No produced in the 238U(22Ne, 5n)255No reaction. Alpha particles of 255No separated with GARIS and transported by the gas-jet system were measured with a rotating wheel apparatus for ? spectrometry under low background condition. The high gas-jet efficiencies of about 75% were independent of the recoil ranges of 255No in the gas-jet chamber. The present results suggest that the GARIS/gas-jet system is a promising tool for the next-generation superheavy element chemistry: (1) the background radioactivities of unwanted reaction products are strongly suppressed, (2) the intense beam is absent in the gas-jet chamber and hence the high gas-jet efficiency is achieved, and (3) the beam-free ...
The purpose of this study is to identify the radiative heat transfer augmentation by a coaxial cylinder introduced in the infinite cylindrical pipe enclosing a participating gas. The gas is either a mixture of water vapor and carbon dioxide or gray. The gas is assumed to be homogeneous at a constant temperature, and has a refractive index of unity. All of the surfaces are opaque and gray, diffusely emitting and reflecting at a constant temperature. The effect of system diameter, diameter ratio, wall emittances, gas and surface temperatures, mixture component on heat transfer augmentation are studied by using the zone method with participating gas radiative properties evaluated from the weighted sum of gray gases model. From the radiative equilibrium condition, the installed wall temperature is formulated and calculated by the iteration method. If the medium is a gray ...
Visible smoke of exhaust gas from iron ore sintering plants spoil the scenery around the works. In this paper, the mechanism of formation of visible smoke is discussed by detailed analysis of the exhaust gas components and dust in the Oita No. 1 sintering plant. The main substance of visible smoke was mist condensing in the air during the cooling of exhaust gas that contained 0.1 ppm of sulfuric acid. Sulfuric acid is considered to raise the dew point and so facilitate mist condensation, and to lower the vaporization of visible mist containing sulfuric acid solution. Dust in the exhaust gas is also considered to act as nucleation sites for mist condensation. This proposed mechanism was confirmed by the test remixing SOx-rich gas with desulfurization gas in the Nagoya No. 3 sintering plant. Long trails of visible smoke were observed by remixing SOx-rich ...
Pressurized fluidized bed combustion (PFBC) is an emerging coal-fired, combined-cycle power generation technology nearing commercial status through several operating and planned demonstration plants throughout the world. Current-generation PFBC plants use ``ruggedized`` gas turbines that can tolerate dust loading common with conventional cyclone gas cleaning. The next generation of PFBC will apply advanced hot gas cleaning systems that will reuse the dust loading to low levels acceptable to high performance, industrial gas turbines. These advances should result in performance and cost advantages. This article examines the demonstration of PFBC technology at Tidd power station.
Sigma 1) examines ways to reduce the number of breakdowns of pressure-regulating stations and to minimize the energy consumed in warming the gas, 2) determines the optimal gas temperatures upstream from the pressure reduction, and 3) shows the dependence of energy consumption upon the water dewpoint. The method of calculating the optimal input temperature relies on Mollier's diagram. Tables and nomographs for natural gas and water dewpoint at 19/sup 0/F and 580 psi (-7/sup 0/C and 4 MPa) are useful in achieving the desired gas temperatures. Heating the regulators' control valves is important.
A study was conducted to examine the energy consumption in existing and new hog farming facilities and to analyse the potential for increased natural gas use in the Saskatchewan hog industry. Existing heating/cooling, ventilation and feed mill equipment choices offer possibilities for running on electricity, natural gas or propane. Energy costs are lowest when natural gas is used. To put the study in context, an overview of the Saskatchewan hog industry was provided. The potential increase in natural gas use in hog production by year 2005 was estimated. 10 refs., 6 tabs., 8 figs.
Increased use of natural gas has positive effects for the environment and the climate, because it primarily replaces petroleum products. Moreover, the natural gas does not pose a threat to bio fuel in Norway. But introducing CO2 taxes on natural gas will significantly increase the emission of greenhouse gases, concludes a report conducted by Norsk Energi (Norwegian Energy) on behalf of Norsk Naturgassforening (Norwegian Natural Gas Association) and Norsk Gassforum (Norwegian Gasforum). A brief presentation of the main conclusions in the report (ml)
National Power is building its first gas turbine combined cycle power station at Killingholme, situated to the south of the River Humber in the East of England. NEI ABB Gas Turbines Limited was awarded the turnkey contract in July 1990 to build a nominal 650 MW combined cycle power station based around three Asea Brown Boveri GT13E gas turbines. The project is outlined in this article. The plant is due for completion in July 1993. (author)
This article outlines the use of gasifiers during World War II and how, with soaring fuel prices, producer gas may provide an alternate energy path for agribusiness and farms today. In the last few years, the University of California has become a focus of producer gas research in the US. Biomass fuels used include crushed walnut shells, fruit pits, cereal straw and corn cobs. Particle size, moisture content and slagging create problems and the right kind of gas producer must be used to obtain reliable conversion to producer gas.
The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through February 1999.
The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through September 1999.
The waste tail gas fuel emitted from refinery plant in Taiwan e.g. catalytic reforming unit, catalytic cracking unit and residue desulfurization unit, was recovered and reused as a replacement fuel. In this study, it was slowly added to the fuel stream of a heater furnace to replace natural gas for powering a full-scale distillation process. The waste tail gas fuel contained on average 60 mol% of hydrogen. On-site experimental results show that both the flame length and orange-yellowish brightness decrease with increasing proportion of waste gas fuel in the original natural gas fuel. Moreover, the adiabatic flame temperature increases as the content of waste gas fuel is increased in the fuel mixture since waste gas fuel has a higher adiabatic flame temperature than that of natural gas. The complete replacement of natural ...
This paper provided an outline of the Canadian natural gas commodity market and a forecast for Canadian natural gas supply and prices for the 2007 winter heating season. Since 2001, steady demand growth and slow supply growth have contributed to higher North American natural gas commodity prices. The loss of natural gas supply due to hurricanes pushed North American natural gas commodity prices to record levels in 2005. Canadian natural gas production levels currently exceed domestic gas consumption. In 2005, Canada produced 16.5 billion cubic feet per day of marketable natural gas. Approximately 45 per cent was consumed domestically, and the remainder was exported to the United States. Despite high levels of drilling activity, production of natural gas from western Canada has flattened out since ...
Radiopharmaceuticals for brain imaging are used for the detection of ischemia, tumours and dementia associatied with disorders of the blood flow in the brain. The current radiopharmaceuticals for brain imaging have various limitations: 2-(F-18)fluoro-2-deoxyglucose (F-18-FDG) has a very short half-life. The physical properties of di-#beta#-(piperidinoethyl)-(Se-75)selenide (Se-75-PIPSE) and di-#beta#-(morpholinoethyl)-(Se-75)-selenide (Se-75-MOSE) are not ideal. Thallium-201 diethyldithricarbamate (T1-201-DDC) has unfavourable nuclidic characteristics, limited availability, a long half-life and high cost. I-123 in N-isopropyl-p-iodoamphetamine (I-123-IMP) and N,N,N'-trimethyl-N'-(2-hydroxy-3-methyl-5-iodobenzyl)-1,3-propanediamine (I-123-HIPDM) are not freely available and are expensive. N-13-labelled ammonia has a very short half-life. Technetium-99m hexamethylpropyleneamineoxime (Tc-99m-HM-PAO) is unstable both in vitro and in vivo and has a low brain-to-blood ...
Background and purpose: A series of phase I/II clinical trials are being initiated in several UK centres to explore the use of dose-escalated schedules for the treatment of non-small cell lung cancer (NSCLC). Among them the IDEAL-CRT trial (ISRCTN12155469) will investigate the introduction of individualised 'isotoxic' treatment schedules based on the relative mean lung normalised total dose (rNTDmean), an estimator related to lung toxicity. Since treatment planning will be performed using different treatment planning systems (TPSs), for the quality assurance of the trial we have carried out work to quantify the influence of dose calculation algorithms based on the determination of rNTDmean and on the choice of individualised prescription doses. Material and methods: Twenty-five patient plans with stage I, II and III NSCLC were calculated, with the same prescription dose, using the Adaptive Convolve (AC) and Collapsed Cone (CC) algorithms of the Pinnacle TPS, the ...
The absorption of solar heat and the attendant thermal and mechanical loadings on the tubes of cavity receivers depend predominantly on the flux distribution of the incident solar radiation. For an axially symmetric cavity receiver with a parabolic dish collector, it is simple to determine the insolation pattern on the receiver internal surfaces if the system is ideal. In such a system the surface of the dish is perfectly parabolic (no contour flaws are present), and the sun's central ray impinges on the dish surface parallel to the focal axis (no sun tracking flaws are present). These two conditions cannot be achieved in practice, and therefore the feasible parabolic dish system is referred to as a real system although, in actual fact, it is only an approximation to any actual system. The purpose of this paper is to devise calculation principles which permit analysis of a receiver designed for ideal conditions to verify its structural ...
The State of the Espirito Santo will become until the end of 2008, one of the main producers and natural gas exporters of Brazil, where, according to PETROBRAS, the State will produce about 20 million /day m{sup 3}, what it will go to contribute significantly for reduction of the dependence of the Bolivian gas, and still to give support to the natural gas sector in Brazil. The Intention of this work, is to identify proposals so that it has left of the gas produced in the State of the Espirito Santo, has a differentiated price. It does not make sensible the State to pay for the gas that is removed in its proper territory the same price that paid Sao Paulo for the gas that consumes imported of national Bolivia. With the markdown of the gas the State will be able to attract investments of great transport, to generate job and income and to ...
We have used the SINFONI integral field spectrograph to map the near-infrared K-band emission lines of molecular and ionised hydrogen in the central regions of two cool core galaxy clusters, Abell 2597 and Sersic 159-03. Gas is detected out to 20 kpc from the nuclei of the brightest cluster galaxies and found to be distributed in clumps and filaments around it. The ionised and molecular gas phases trace each other closely in extent and dynamical state. Both gas phases show signs of interaction with the active nucleus. Within the nuclear regions the kinetic luminosity of this gas is found to be somewhat smaller than the current radio luminosity. Outside the nuclear region the gas has a low velocity dispersion and shows smooth velocity gradients. There is no strong correlation between the intensity of the molecular and ionised gas emission and either the radio or ...
Nova Corporation and its related businesses are involved in natural gas production, gas pipelines, consulting services, and upgrading of natural gas into chemicals and plastics. Nova owns Alberta Gas Transmission Division, the primary gas transportation system in Alberta, with 11,400 miles of pipeline and total deliveries in 1992 of 3.4 trillion ft"3. Nova also owns 50% of Foothills Pipe Lines Ltd., one of Canada's largest carriers of exported gas, and 50% of TQM Pipeline Partnership, which transports natural gas in Quebec. Nova conducts its chemicals business through Novacor Chemicals Ltd., which has plants in Alberta, Ontario, Quebec, and the USA. Novacor's major petrochemicals are methanol, ethylene, propylene, and styrene and its major plastics are polystyrene, polypropylene, and polyethylene. Nova's gas-producing ...
Gas transmission pipelines are susceptible to both internal (gas side) and external (soil side) corrosion attack. Internal corrosion is caused by the presence of salt laden moisture, CO{sub 2}, H{sub 2}S, and perhaps O{sub 2} in the natural gas. Internal corrosion usually manifests itself as general corrosion. However, the presence of chlorides in entrained water also can lead to pitting corrosion damage. The electrochemical noise technique can differentiate general from localized corrosion and provide estimates of corrosion rates without external perturbation of the corroding system. It is increasingly being applied to field and industrial installations for in situ corrosion monitoring. It has been used here to determine its suitability for monitoring internal and external corrosion damage on gas transmission pipelines. Corrosion measurements were made in three types of environments: (1) aqueous ...
Short-lived fission gas release from fuel pellets during irradiation was investigated based on the experimental results of the gas-flow rigs irradiated in the Halden Heavy Water Reactor (HBWR). The release-to-birth (R/B) rates of short-lived fission gas were measured by means of gas-flow measurement during the irradiation experiments. Surface-to-volume (S/V) ratios of fuel pellets and diffusion coefficients of short-lived fission gas release were evaluated from the obtained (R/B) values. The increase of (S/V) ratio agreed well with the point where the fuel temperature exceeded the threshold of 1% fission gas release. This indicates that the interlinkage of fission gas bubbles occurred there. The evaluated diffusion coefficients scattered in the range between 10"-"2"3 and 10"-"1"7 m"2/s, and the effects of fuel type (UO_2 or MOX) were not ...
The European gas market is continuing to expand due to increased industrial, domestic and power generation demand. As a result of this demand, and the trend toward liberalization of the market, the need for storage of gas is also increasing. One key segment of the large scale storage of gas is underground storage, either in partially depleted gas or oil fields, naturally occurring caverns, aquifers and salt cavities. In most cases the gas produced after storage requires conditioning to meet the water of hydrocarbon dew point specification of the gas transmission system. For that reason export gas from storage will require gas conditioning in order to meet pipeline specifications. Adsorption as a feasible and reliable process will be presented in detail and especially in regards to hydrocarbon dew-pointing compared with ...
Geologically estimated natural gas resources are 500 Tcm. With the advance in geological science increase of estimated resources is expected. Natural gas reserves in 2000 have been proved to be around 165 Tcm. As it is known the reserves are subject to two constraints, namely: capital invested in the exploration and drilling technologies used to discover new reserves. The natural gas scarcity factor, i.e. ratio between available reserves and natural gas consumption, is around 300 years for the last 50 years. The new discovery of natural gas reserves has given rise to a new energy strategy based on natural gas. Natural gas utilization is constantly increasing in the last 50 years. With new technologies for deep drilling, we have come to know that there are enormous gas resources available at relatively low price. These ...
Geologically estimated natural gas resources are 500 Tcm. With the advance in geological science increase of estimated resources is expected. Natural gas reserves in 2000 have been proved to be around 165 Tcm. As it is known the reserves are subject to two constraints, namely: capital invested in the exploration and drilling technologies used to discover new reserves. The natural gas scarcity factor, i.e. ratio between available reserves and natural gas consumption, is around 300 years for the last 50 years. The new discovery of natural gas reserves has given rise to a new energy strategy based on natural gas. Natural gas utilization is constantly increasing in the last 50 years. With new technologies for deep drilling, we have come to know that there are enormous gas resources available at relatively low price. These ...
Two-phase flow in horizontal parallel channels has been experimentally investigated under fuel cell related operating conditions. Pronounced hysteresis is observed in the pressure drop versus flow characteristic curve when starting from either flooded or dry conditions. When gas is introduced into channels initially filled with water (flooded initial condition), both gas and liquid tend to flow predominantly in one channel at low gas or liquid flow velocities. As the gas flow velocity increases, even distribution of gas and liquid flow in both channels is observed, accompanied with a sudden decrease in the pressure drop. On the other hand, even gas and liquid flow distribution between both channels is found at comparatively lower gas flow velocities when starting with dry-gas flow conditions with liquid introduced into ...
A report is given of a meeting of the Netherlands Association for Energy Legislation (NEVER), which was held in Amsterdam, Netherlands, April 2006. After the meeting a presentation was made about the report 'Government involvement in liberalised gas markets. A welfare-economic analysis of the Dutch gas-depletion policy' of the Netherlands Bureau for Economic Policy Analysis (CPB). This report analyses the welfare effects of two major components of the Dutch gas-depletion policy: the offtake guarantee for small-fields gas and the cap on production from the Groningen field. After the presentation a reaction was given to the report. Both presentations give an overview of the governmental policy and insight in the effects.
A high-density gas jet supersonic nozzle is reported in this paper. The jitter and actuation time of the nozzle is determined by the pin discharge and laser spark radiation respectively. The jitter time of the nozzle is within 10 ?s with the backing pressure as high as 25 bar. With a nanosecond laser pulse focused on the gas jet about 1 mm below the nozzle, the actuation time is calculated to be about 15 ms by detecting the laser produced spark radiation, which reveals the existence of the gas jet and the relative gas density evolving with time. Consequently the gas density is estimated to be well above 1019 cm-3, compared with theoretical simulations from the nozzle parameters.
Some aspects of the PSO scheme for natural gas are examined critically. Two central arguments used for justifying the PSO subsidy scheme of natural gas and its distribution are reviewed; these include the 'smallholder argument' and the 'environmental argument'. The 'smallholder argument' claims that since Norway has the natural gas resources, it should also make use of the natural gas in the country, and not simply send the raw material to other countries. The 'environmental argument' states that natural gas compared to other fossil fuels such as coal and fuel oil, is a far cleaner alternative, thus an environmental-friendly alternative entitled to financial support. The arguments are critically examined by the author (ml)
We report on the discovery of kinematic shock signatures associated with a localized radio jet interaction in the merging Seyfert galaxy NGC 5929. We explore the velocity-dependent ionization structure of the gas and find that low-ionization gas at the interaction site is significantly more disturbed than high-ionization gas, which we attribute to a local enhancement of shock ionization due to the influence of the jet. The characteristic width of the broad low-ionization emission is consistent with shock velocities predicted from the ionization conditions of the gas. We interpret the relative prominence of shocks to the high density of gas in the nuclear environment of the galaxy and place some constraints of their importance as feedback mechanisms in Seyferts.
Natural gas is a promising alternative fuel to meet strict engine emission regulations in many countries. Natural gas engines can operate at lean burn and stoichiometric conditions with different combustion and emission characteristics. In this paper, the operating envelope, fuel economy, emissions, cycle-to-cycle variations in indicated mean effective pressure and strategies to achieve stable combustion of lean burn natural gas engines are highlighted. Stoichiometric natural gas engines are briefly reviewed. To keep the output power and torque of natural gas engines comparable to those of their gasoline or Diesel counterparts, high boost pressure should be used. High activity catalyst for methane oxidation and lean deNOx system or three way catalyst with precise air-fuel ratio control str...
During the 1990's, natural gas was the energy source with the fastest rate of growth in the world energy balance. Nevertheless, recent evolutions of the energy context, in particular in terms of prices, have had a rather strong impact on the progress of the different energy sources penalizing gas a little. Beyond this competition between energies, which may increase, the medium-term perspectives of natural gas development is in keeping with an environment full of uncertainties. This article presents: the world supply and demand prospects for 2010-2015 (impact of high gas prices on other energy sources, occurrence of production constraints, political decisions of producing countries and world gas industry balance), trends on main markets (North America, Europe, Asia-Oceania), and international trade. (J.S.)
An increasing share of natural gas supplies distributed to residential appliances in the U.S. may come from liquefied natural gas (LNG) imports. The imported gas will be of a higher Wobbe number than domestic gas, and there is concern that it could produce more pollutant emissions at the point of use. This report will review recently undertaken studies, some of which have observed substantial effects on various appliances when operated on different mixtures of imported LNG. While we will summarize findings of major studies, we will not try to characterize broad effects of LNG, but describe how different components of the appliance itself will be affected by imported LNG. This paper considers how the operation of each major component of the gas appliances may be impacted by a switch to LNG, and how this local impact may affect overall safety, performance and pollutant emissions.
The 575-mile Statpipe gas transportation system entails 191 miles of wet-gas line running from the Statfjord field across the Norwegian trench to the Karsto, Norway, conditioning plant and 384 miles of dry-gas line from Karsto, again across the trench, to the Heindal and Sleipner fields for final connection at Ekofisk with the Norpipe system for transport to Emden, West Germany. Special construction considerations include the 1000-ft-deep trench crossings, the rocky shore approach and departure, and the subsea tie-ins required at depths of up to 500 ft. The system has an initial annual design capacity of 186 billion CF of wet gas and 260 billion CF through the dry-gas line to Emden.
The Sulige gas field and the Yulin gas field are located in the north of the Ordos Basin. Reservoir pressure in the Sulige area is subnormal, whereas reservoirs in the Yulin area have normal hydrostatic pressure. This paper provides an explanation of this difference. The characteristics of reservoir sediment and formation water chemistry in the gas reservoirs of these two areas were analyzed. The results showed that both reservoirs have good sealing ability. Data of numerical simulation showed that tectonic uplift resulted in a great reduction in formation pressure in the northern Ordos Basin during the late Cretaceous period, and the decrease was greater in the Yulin gas field than in the Sulige gas field. However, because the total hydrocarbon-generating intensity of the Sulige area (<24...
The Granger instantaneous-causality test is applied to explore the potential causal relationships between wholesale electricity and natural-gas prices in California. The test shows these relationships to be bi-directional, and reveals California's electricity and natural-gas markets to be as inextricably intertwined as casual observation and theoretical considerations would suggest they ought to be. This meshing of markets exacerbated the effects of California's natural-gas crisis on the contemporaneous electricity crisis, while concurrently the electricity crisis may have contributed to the dysfunction in the national-gas market and helped to precipitate the natural-gas crisis. The finding supports an integrated approach, as opposed to a piecemeal approach, for formulating energy policy recommendations, not just in California but in the world at large. (author)
The Granger instantaneous-causality test is applied to explore the potential causal relationships between wholesale electricity and natural-gas prices in California. The test shows these relationships to be bi-directional, and reveals California's electricity and natural-gas markets to be as inextricably intertwined as casual observation and theoretical considerations would suggest they ought to be. This meshing of markets exacerbated the effects of California's natural-gas crisis on the contemporaneous electricity crisis, while concurrently the electricity crisis may have contributed to the dysfunction in the national-gas market and helped to precipitate the natural-gas crisis. The finding supports an integrated approach, as opposed to a piecemeal approach, for formulating energy policy recommendations, not just in California but in the world at large.
In this study the technical and economical possibilities of burning carbon monoxide (CO) of the flue gas and utilizing of the released heat in hot air cupola furnace used for melting have been studied. As basis for examining was burning of cleaned furnace...
The paper is an overview of utility flue gas desulfurization (FGD) technology and costs. The two commercially offered throwaway and salable product systems that are considered to be the most important for near-term (through 1990) SO2 control are: throwawa...
This patent describes a method of improving the S0{sub 2} scrubbing efficiency of flue gas desulfurization scrubbers. It comprises conducting the scrubbing operation in such scrubbers in the presence of an oil-soluble surfactant.
Gas turbine component protection remains essential but environmental regulations emphasize the gas-turbine efficiency. Heating and cooling are features often integrated into the GI air intake packages to provide the optimum operating conditions. This paper describes modern inlet air treatment systems and discusses their effectiveness. (author)
The structure of the skin in the epauletted fruit bat (Epomophorus wahlbergi) wing and body trunk was studied with a view to understanding possible adaptations for gas metabolism and...Full Text Available
The genetic type, source and charging history of natural gas in the Yulin gas field in the Ordos Basin have been studied by combining the carbon isotopic composition of natural gas and geochemical characteristics of light hydrocarbons with carbon isotope fractionation model results and fluid inclusion analysis. The carbon isotopic composition of methane and ethane in the Yulin gas field is relatively enriched in ^1^3C with d^1^3C1 values ranging from -35.3%% to -29.8%% (average value=-32.4%%) and d^1^3C2 ranging from -26.3%% to -23.5%% (average value=-24.8%%). The C7 light hydrocarbons are predominated by methylcyclohexane, accounting for 65.8% to 80.9% (average value=71.6%), which is characteristic of coal-derived gas. Furthermore, the gas geochemistry indicates that, although marine lime...
The Bureau of Mines performed chemical research to elaborate details of sulfur chemistry pertaining to the citrate flue gas desulfurization process in which sulfur dioxide (SO2), absorbed (as bisulfite ion) in a buffered sodium citrate solution, is reduce...
This report gives the results of a survey of operational flue gas desulfurization (FGD) systems on coal-fired utility boilers in the United States. The FGD systems installed on Units 1 and 2 at the Bruce Mansfield Station of the Pennsylvania Power Company...
A catalytic process for the oxidation of sulfur-containing gases , E.G., sulfur dioxide and simultaneous production of sulfuric acid wherein a sulfur-containing gas is reacted with an oxygencontaining gas in the presence of a catalyst comprising an iron group metal on a solid support comprising a zeolite in a silicaalumina matrix.
Gas exchange between the plant and the environment is severely hampered when plants are submerged, leading to oxygen and energy deficits. A straightforward way to reduce these shortages of oxygen and...Full Text Available
TSS (thermal swing sublimation) method was studied which uses vaporization heat and sensible heat of LNG for solidification and separation of CO2 gas in waste gases of LNG-fired combined cycle power generation system. In experiment, the mixed gas composed of CO2, H2O and N2 was used for simulating waste gas of LNG-fired combined cycle power generation systems, and the growth behavior of ice and dry ice was studied for developing dry ice making technology under low-temperature condition. As the experimental result, the following were clarified: various crystal structures depending on cooling temperature, the effect of gas flow rate on peeling of surface precipitated solids, and solidification characteristics of H2O/CO2 mixed gas. The growth rate of precipitated solid film thickness decreased with an increase in gas flow rate, while increased with CO2 ...
Limestone slurry needs to move efficiently through a complex process, meaning that selecting the right pumps and valves is critical. The article discusses factors to consider in selecting pumps and values for flue gas desulfurization process in coal-fired power plants. 2 photos.
The possibility has been explored of using a laser scattering technique to detect the imminent onset of rock activity associated with gas outbursts. The instrument described in this paper provides a sensitive, remote and rapid means of passively monitoring micro-seismic activity at the exposed face.
Petroleum is the unchallenged energy market leader in West Germany,having a share of 42%; natural gas accounts for 16-17%. West Germany imports 29% of its natural gas from the Soviet Union, 28% from the Netherlands, 14% from Norway, and 1% from Denmark. In West Germany many-branched natural gas distribution system is operated, equipped with a.o. 21 installations for underground storage which results in a great flexibility of the system. Because of the preferential treatment given to the use of coal as fuel for power plants the share of natural gas has decreased to the present 6% in the last ten years. In the indutrial sector the share is 18%. Strict air pollution abatement measures ('TA-Luft') favour the use of natural gas. However, duty has been levied on the use of natural gas per January 1st, 1989. For space heating of houses and commercial ...
The Monthly Energy Review provides an overview of the production, distribution, and consumption of energy derived from petroleum natural gas, coal, electricity, and nuclear energy. It also discusses oil and gas resource development, energy prices, and issues relevant to international energy markets.
This report presented some quick facts about oil and gas pipelines in Turkey and presented opportunities for trade. The key players and customers in the oil and gas sector were described along with an export check list. Turkey is looking into becoming an energy bridge between oil and gas producing countries in the Middle East, Central Asia and Europe. The oil and gas sectors are dominated by the Turkish Petroleum Corporation, a public enterprise dealing with exploration and production, and the State Pipeline Corporation which deals with energy transmission. They are also the key buyers of oil and gas equipment in Turkey. There are several pipelines connecting countries bordering the Caspian Sea. Opportunities exist in the areas of engineering consulting as well as contracting services for oil and gas pipeline transmission and distribution. Other opportunities ...
The report gives results of the measurement of dissolution rates of reagent CaCO3 and commercial limestones (9 types/19 grinds) at constant pH and solution composition by batch titration with HC1. Conditions were selected to simulate flue gas desulfurizat...
The influence of geometry and operating conditions of the centrifugal compressor stage on the radial gas force is determined on the basis of the theoretical method and calculation program using experimental boundary conditions.
... Radon gas concentrations are measured using instruments with calibrations traceable to the UK National Physical Laboratory and PTB, Germany. The primary facility is a 43 m3 walk-in chamber accessed by an airlock. Radon gas is maintained at a level in this chamber that is ...
The various steps of gas treatment in the Sasol II coal liquefaction plant are discussed: CO/sub 2/ removal, separation of the hydrocarbon fractions and the recirculated hydrogen by low-temperature decomposition, production of pure hydrogen by alternating pressure absorption.
Jeltes, R., Burghardt, E., and Breman, J. (1971). Brit. J. industr. Med., 28, 96-99. Gas chromatographic determination of phosgene and dichloroacetylene in air. Phosgene and dichloroacetylene...Full Text Available
An experimental investigation of heat transfer characteristics for various configurations of air jets impinging on the leading edge inner surface of a gas turbine blade wall is presented. Three configurations were investigated, namely a slot jet, a round ...
The goal of GRI's Gas Appliance Technology Center is to encourage the introduction of highly efficient, cost-effective, convenient gas appliances for residential and commercial gas users. The report covers activity at Battelle from February 1989 to April 1990 in broad support tasks, residential and commercial appliances, and residential space conditioning. Broad support tasks included the G/A/S Newsletter; the GATC InfoBase; and technology transfer, workshops, and GATC coordination. Residential appliance tasks included burner technology research, gas appliance venting, gas lighting, and plastics durability. Commercial appliance tasks included development of a commercial cooktop fuel/air mixing valve. Residential space conditioning tasks included a corrosion test method for gas appliances and vents, generic technology for condensing ...
This paper summarizes the current scientific and technological knowledge about greenhouse gas emissions from various agricultural practices and the manufacturing of food. The study also provides estimates that compare agriculture-related alternatives for reducing greenhouse gas emissions.
Legal aspects of using natural gas as boiler fuel for electric utilities are reviewed through one utility's challenges to the Power Plant and Industrial Fuel Use implementation. ASARCO vs. FPC, 1973, and City of Willcox vs. FPC are discussed. (PSB)
The report, generated by a computerized data base system, presents a survey of operational and planned domestic utility flue gas desulfurization (FGD) systems, operational domestic particle scrubbers, and Japanese coal-fired utility FGD installations. It ...
The report presents detailed technical information concerning application of flue gas desulfurization (FGD) systems to industrial boilers. The information was obtained by a survey of plant personnel, control system vendors, regulatory agencies, and consulting engineering firms. T...
The report discusses the capabilities of equipment vendors to supply and install the quantity of flue gas desulfurization systems required to meet alternative standards for coal-fired steam generators. It analyzes limiting factors affecting supply capabilities (such as the availa...
The effects of freeze-thaw cycling on the strength and durability of samples of compacted, stabilized, wet flue gas desulfurization (FGD) by-products are reported. The results of laboratory tests show a clear relationship between higher water contents and...
NO[sub x] emission legislation requirements for large-bore internal combustion engines have required engine manufacturers to continue to develop and improve techniques for exhaust emission reduction. This paper describes the development of the Cooper-Bessemer Clean Burn gas-diesel (dual-fuel) engine that results in NO[sub x] reductions of up to 92 percent as compared with an uncontrolled gas-diesel engine. Historically, the gas-diesel and diesel engine combustion systems have not responded to similar techniques of NO[sub x] reduction that have been successful on straight spark-ignited natural gas burning engines. NO[sub x] levels of a nominal 1.0 g/BHP-h, equal to the spark-ignited natural gas fueled engine, have been achieved for the gas-diesel and are described. In addition, the higher opacity exhaust plume characteristic of gas-diesel ...
Concentration of an amine solution for removal of hydrogen sulfides and carbon dioxide from natural gas, is tested by carbon dioxide absorption measurement in an apparatus allowing complete reaction to give reliable results.
The increasing price differential between natural gas and coal will create a demand for technology that can allow the displacement of natural gas with coal in power plants. Coal gasification is the standard approach suggested to allow coal to displace natural gas. However, the relatively high capital investment required for coal gasification will require fuel cost differentials higher than those anticipated in the near term before coal gasification replaces natural gas. One way of achieving shorter term displacement of natural gas by coal would be to develop technology that would allow coal to be used as the heat source for the endothermic reforming of natural gas. In a natural gas-fired combined cycle power plant, the endothermic heat of reforming, which would be provided by coal combustion, is recovered in the combined-cycle. Therefore, ...
At the St. Joe Minerals Corp.'s zinc smelter powerplant, an SO2 emission control program evolved into a cooperative program with the Bureau of Mines for installation and initial operation of a citrate process flue gas desulfurization demonstration plant. ...
The report describes a computer model developed by TVA to simulate the performance and determine the economics of coal cleaning, or coal cleaning combined with flue gas desulfurization (FGD), for power plant emission control processes over a wide range of user-specified condition...
The manual describes a combined coal-cleaning and flue gas desulfurization (FGD) computerized design and cost-estimate model and gives detailed procedures for using it. All inputs and outputs are described, as well as the various options available. Design and economic premises ar...
This project addresses the problem of flue gas desulfurization (FGD) sludge disposal to land. Specifically, the chemical species of FGD sludge constituents are thermodynamically modeled using the equilibrium constant approach, in an attempt to predict the constituent concentratio...
The report gives an initial assessment of the feasibility of disposing of flue gas desulfurization wastes in mines and in the ocean. The purpose of the assessment was to evaluate environmental, technical, regulatory, and economic aspects of the use of such disposal sites. Availab...
Crockford, G. W., Crowder, M., and Prestidge, S. P. (1972).Brit. J. industr. Med.,29, 378-386. A trace gas technique for measuring clothing microclimate...Full Text Available
In this paper we have proposed a novel gas turbine cycle with hydrogen-fueled chemical-looping combustion, and the system study on two hydrogen-fueled power plants, the new gas turbine cycle and an advanced gas turbine cycle with H{sub 2}/O{sub 2} combustion, has been investigated with the aid of exergy principle (EUD methodology). The hydrogen fueled chemical-looping combustion in the new gas turbine cycle consists of two successive reactions: hydrogen fuel is reacted with metal oxide (reduction of metal oxide), and then instead of air or pure oxygen, the reduced metal is successively oxidized by the saturated air. As a result, the new hydrogen-fueled gas turbine cycle has a breakthrough performance, with at least about 12 percentage-point higher efficiency compared to the gas turbine cycle with H{sub 2}/O{sub 2} combustion, and will be environmentally superior ...
Gas-fired combined cycle plant may be the norm when it comes to new plant but it comes in a variety of shapes and sizes. Samarinda uses aero-derivatives with the famous Rolls-Royce RB211 gas generator. (author)
The feasibility of producing a pocket-sized air contaminant monitor based upon a miniature gas chromatograph and an integrated microcomputer has been demonstrated and a practical design for the instrument is presented. This pocket-sized instrument is intended to be used as a pers...
Apparatus and method for selective measurement of tritium oxide in an environment which may include other radioactive components and gamma radiation, the measurement including the selective separation of tritium oxide from a sample gas through a membrane into a counting gas, the generation of electrical pulses individually representative by rise times of tritium oxide and other radioactivity in the counting gas, separation of the pulses by rise times, and counting of those pulses representative of tritium oxide. The invention further includes the separate measurement of any tritium in the sample gas by oxidizing the tritium to tritium oxide and carrying out a second separation and analysis procedure as described above.
A high-voltage cathode initiates an electron emission, resulting in a reduction in the carbon dioxide concentration in exhaust gas from the burning of hydrocarbon fuel. Assuming that the observed carbon dioxide reduction is originated from the molecular decomposition, the energy needed for the endothermic reaction of this carbon dioxide reduction may stem primarily from the internal energy reduction in the exhaust gas in accordance of the first law of the thermodynamics. An oxygen increase due to the reduction in carbon dioxide in a discharge gas was observed in real time.
This report consists of three sections. The first section is a brief general overview of all the issues that impact the competition between natural gas and electricity in industrial applications. The second section of this report focus on the all the marketing issues and provides detail analysis of the status of these issues in Europe, Japan and United States. The third section of this report is a detail review of the current status of the competition between gas technologies and electro-technologies, it also make recommendation for developing new gas technologies. The fourth section is a contribution from M. Pettersson and S. Stenstroem, Sweden, on infrared dryers. (authors)
Makeup water is distilled internally in an amine gas treating unit by adding it to the reclaimer used to process a slipstream of lean amine from the stripper.
Experimental data on the gas holdup and the mean bubble size in a bubble column with a single nozzle was obtained for gas-molten salt systems of a eutectic mixture of LiCl (58 mol %)-KCl (42 mol %) and molten NaNO/sub 3/. The liquid-phase mass transfer coefficient K /SUB L/ was evaluated from the specific surface area a and the volumetric coefficient K /SUB L/ a data for oxygen and carbon dioxide absorption into molten NaNO/sub 3/. The dimensionless correlations of the performance of bubble columns for aqueous solutions can be extended to the gas-molten salt systems.
This dissertation deals with membrane gas absorption in the application of CO{sub 2} removal by aqueous alkanolamines, using microporous PTFE hollow fiber membranes. A new lab-scale apparatus was constructed and an extensive experimental study executed to determine the performance of the membrane gas absorber, with aqueous solutions of monoethanolamine (MEA) and methyldiethanolamine (MDEA) as absorbents. The important operation parameters CO{sub 2} partial pressure, gas velocity, liquid velocity, temperature and liquid CO{sub 2} loading were systematically varied within the range typically experienced in a process for exhaust gas CO{sub 2}-removal
This thesis dealt with the metal-organic gas phase epitaxy with nitrogen as carrier gas. For this first by means of three-dimensional modelings of the epitaxy process the influence of the carrier gas on the processes was explained. The optimization of the growth parameter for the whole light-emitting-diode structure in double-hetero arrangement resulted that an a temperature of 770 C and a V/ III-ratio of 150 layers with a high crystal quality could be reached.
Access for independents to retail gas markets was a central concern in European policy reform efforts in the 1990s. Upstream oil and gas companies reacted with strategic intentions of forward integration. By late 2004, forward integration was still weak, however. An important explanation of the gap between announced strategic re-orientation and actual strategy implementation lies in the political failure of EU member states to dismantle market barriers to entry for independents. Variations between companies in downstream strategy implementation are explained by variations in business opportunities and internal company factors.
Kawasaki Heavy Industries, Ltd. has developed a gas turbine combined cycle and cogeneration plant computer aided engineering (CAE) system, which creates cycle heat balance automatically on given configurations of gas turbines, heat recovery boilers, steam turbines and auxiliaries. The system can predict the performance of the plant as a function of control set points, loads, process steam requirements and ambient conditions, which enables accurate and fast design of gas turbine combined cycle and cogeneration plants. (author)
Dimethyl methylphosphonate (DMMP), a chemical simulant of the nerve gas GB, was decontaminated with a nonthermal atmospheric pressure plasma. The decontamination efficiency was measured qualitatively by means of Fourier transform spectroscopy and quantitatively by means of gas chromatography. With helium gas only, 10g/m2 of DMMP on an aluminum surface was 99.9% decontaminated in 2min, furthermore, with the addition of 5% of oxygen gas, it was 99.99% decontaminated in 10min. Given the low input power (<100W) and temperature (<75degreeC), this plasma is eligible for nondestructive decontamination of almost all material surfaces.
The purpose of this work was to develop and evaluate a method of locating breached fuel within the Fast Flux Test Facility (FFTF) reactor based on the relative response of the delayed neutron monitors (DNM) located on each of the three primary sodium cooling loops. The primary method of location is the use of tag gas containing unique ratios of the noble gases xenon and krypton. Although the tag gas system works quite well, it is relatively expensive because of the costs of preparing and loading the gas into each fuel pin. Triangulation of DNM signals could potentially decrease tag gas costs while maintaining overall location reliability.
Biogas supply to the public gas grid is a new option discussed in the most recent publication of Fachagentur Nachwachsende Rohstoffe (FNR) e.V. The biogas is purified, upgraded to natural gas quality and fed into an existing gas grid. Once there, it can be transported across long distances and also used for electric power generation at the consumer side. The study investigates inhowfar and in what instances this method is feasible and promising. It discusses the technical background and the regional potential of biogas. Seven model biogas systems are presented as examples. (orig.)
This paper is a quarterly report describing the use of a new soil gas collection device which allows the collection of soil gas in the field for later analysis in the laboratory. It describes the installation of this sampling device and the procedure for setting the probe, extraction of soil gas beneath the surface, and sealing of the soil gas for transport. The sites used for initial testing was the top of Yucca Mountain and Crystal Spring in Ash Meadows National Wildlife Refuge. The results from this initial test showed no volatile matter present in the soil at these locations.
The multicell proportional chambers at the backing calorimeter of the ZEUS experiment at the storage ring HERA are supplied with a gas mixture of Ar/CO[sub 2] by an open gas system. Flow proportional counters with the build-up [sup 55]Fe sources are used as gas system monitoring detectors. The ZEUS experiment is planned to collect data for about 10 years. Therefore, the lifetime of the Ar/CO[sub 2] mixture should be known. In this paper, the results of laboratory tests and preliminary measurements of the aging effects for monitoring counters are presented. ((orig.))
The risk perception of the public consists of two components: the objectively factual component and the subjectively irrational component. The two strategies adopted by the German gas supply industry are the internal and the external communication strategy. Concepts and measures of accident precaution, registration and analysis of accident data (installation and operating errors, defects on flue systems, pipelines and valves, subsequent installation of gas appliances) are discussed. (R.P.)
The energy price volatility model suggests that some of the proposed natural gas programs can contribute to energy price stability. The sector most vulnerable to fuel price variations is, of course, the transportation sector. The most effective strategy to achieve energy pace stability is to reduce petroleum consumption in this sector. The natural gas vehicle program is therefore recommended as potentially important and worthy of further consideration. At this point, distinguishing the merits of various subprograms is not feasible. This result farther supports the conclusion that the DOE`s energy R&D portfolio is not efficiently balanced and an increase in oil and gas research should be a high priority. The DOE has responded favorably and has significantly increased its proposed research with the explicit objective of displacing oil in the transportation sector. The enhanced research and development program for energy ...
This paper gives a Coulomb gas representation for level kN = 1 supersymmetric SU(2) Kac-Moody algebra in terms of three free scalar superfields. It is clarified how this representation reduces to a Coulomb gas representation for the corresponding bosonic SU(2) Kac-Moody algebra and the free fermionic algebra. The primary superfields and the correlation functions, which satisfy the supersymmetric Knizhnik-Zamolodchikov equation, are also discussed.
The US$360 million project to increase gas supplies to Eastern and Southern Thailand is discussed, and the use of international competitive bidding to purchase the line pipe and other facilities is reported. The government approved proposal for a gas fired combined-cycle power station and gas separation plant are discussed. (UK).
The need is substantiated for using remote control of technological processes on blowout dangerous beds. A method is proposed for this control based on recording with the help of AGZ apparatus for gas release into the roadway. Distinguishing features are indicated for the change in methane concentration in the roadway with normal occurrence of the process and in the case of blowout of coal and gas.
Smart electricity and gas supply grids are a prerequiste for full-scale utilization of the potential of modern energy-saving appliances and equipment. Direct exchange of information between the supplier and the consumer is indispensable for reducing costly and energy-intensive peak loads. (orig.)
This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid vapor condensed in both the high temperature and low temperature ...
This invention pertains to a Fischer Tropsch process for converting synthesis gas to an oxygenated hydrocarbon with particular emphasis on dimethyl ether. Synthesis gas comprising carbon monoxide and hydrogen are converted to dimethyl ether by carrying out the reaction in the presence of an alkali metal-manganese-iron carbonyl cluster incorporated onto a zirconia-alumina support.
To suppress space charge blowup in an ion beam passing through a photoneutralizer, it is necessary to introduce some background gas. An analysis is presented of the neutralization of a high-energy, >200-keV negative deuterium ion beam, exposed to photodetachment while in the presence of deuterium. With a gas thickness of <0.01 Torr.cm, the neutral fraction in the output beam is found to be about the same as that gotten from the photoneutralizer operating in vacuum. Neutral atom beam injection for plasma heating is discussed.
This paper describes a practical knowledge on gas engine performance and combustion characteristics which are required by experimental studies for two types of developed gas burning engines, i. e. a spark ignited gas engine and a dual fuel engine, and also introduces their practical use and application. As for dual fuel engine performance, a manifold air pressure of about 27% was decreased, a scavenging ratio of 23% reduced and an exhaust temperature at the turbine inlet on 14% was increased at the gas engine operation under the mean effective cylinder pressure of 1.22 MPa in comparison with the diesel operation. Furthemore, empirical data on the effect of excess air ration on the engine performance and combustion characteristics, a risk of knocking during changing over on the dual fuel engine operation, and the rated output in case of using alternate fuel gas were reported. Two ...
Triassic sedimentary rocks are widespread in the Pechora sineclise and Pre-Uralian edge trough territory. They are up to 920 and 400 m thick respectively. Commercial flows of oil and gas have been obtained from these deposits in the last few years. The geology of the area is described and its is concluded that the main oil and gas potential should be connected with the northern areas of the Pechora sineclise.
I propose that an interpretation of the interaction of noble gas atoms with metal surfaces as predominantly physisorbing provides the best explanation for the systematics of their binding energies and surface dipoles, as well as for the tendency of noble gas atoms to bind in low coordinated sites. In the present context physisorption is defined as a process driven by the overlap of the electrostatic atomic potentials of the interacting species. (orig.)
The technical and economic feasibility of using a typical, elemental, phosphorus byproduct gas stream in methanol production is assessed. The purpose of the study is to explore the potential of a substitute for natural gas. The first part of the study establishes economic tradeoffs between several alternative methods of supplying the hydrogen which is needed in the methanol synthesis process to react with CO from the off gas. The preferred alternative is the Battelle Process, which uses natural gas in combination with the off gas in an economically sized methanol plant. The second part of the study presents a preliminary basic design of a plant to (1) clean and compress the off gas, (2) return recovered phosphorus to the phosphorus plant, and (3) produce methanol by the Battelle Process. Use of elemental phosphorus byproduct gas in methanol ...
This paper reports that Sen. Bennett Johnston (D-La.) has vowed if Congress enacts an omnibus energy bill in the fall, it will not include a restriction on states' rights to proration natural gas production. Johnston, Senate energy committee chairman, will lead Senate conferees in their negotiations with members of the House of Representatives. The House energy bill has an antiproration amendment. The Senate's bill does not. Oklahoma's and Texas' recent actions to proration gas production prompted the federal legislation.
The 66 fields discovered since the 1960s in the northern West Siberian basin contain at least 22 trillion m/sup 3/ (777 tcf) of proved gas, almost one-third of the world's reserves. Half of these fields are giants (> 85 billion m/sup 3/ or 3000 bcf of reserves). These include the largest and second-largest gas fields in the world-Urengoy (8.099 trillion m/sup 3/ or 286 tcf of gas) and Yamburg (4.81 trillion m/sup 3/ or 170 tcf of gas)-as well as most of the other ten largest gas fields in the world. The West Siberian basin occupies a 3.4-million km/sup 2/ (1.31-million mi/sup 2/) arctic lowland immediately east of the Ural Mountains, extending north under the Kara Sea. It is a composite basin, with Mesozoic-Cenozoic basin fill on top of a Paleozoic basin that overlies a crystalline Archean-Proterozoic framework. The productive zones in the northern basin are principally ...
Cattle or chicken manure is pelletized, and a bed of the pellets is combusted at the bottom to create a temperature gradient and to generate a fuel gas. Thus, an approximately 25 cm-high bed of approximately 5 mm-diameter chicken manure pellets was combusted to produce a fuel gas of 1622 kcal/kg manure.
There are several concerns which bring to consider natural gas as a viable alternative to liquid fuels in transport. First, natural gas allows the curbing of global pollution in this steadily growing industry. Indeed, decoupling greenhouse gas emissions from transport growth has become a major issue in tackling climate change. Second, a more extensive use of natural gas would relieve city air quality, which is presently at levels harmful of human health. Nonetheless, this is just one side of the coin. The other side entails building a refuelling station network, and this carries financial requirements. The financing fraction holds a pivotal role in deciding whether natural gas for automotive purposes is an efficient solution. The final aim of this work is, therefore, to compare the natural gas advantages, stemming from avoided global and local emission, with the ...
In order to facilitate observations of low energy nuclear reactions, a new type recoil mass-separator together with a new gas-jet target system is being developed at the tandem accelerator facility in Kyushu University. The expected mass-resolving power of the separator is 220 for a solid angle of 10 msr and the practical thickness of the gas-jet target will exceed 0.1 atm#centre dot#cm for the light elements of H and He. (author).
The EPA proposed effluent limitations guidelines and standards for the offshore segment of the oil and gas industry on August 26, 1985. On November 26, 1990, and March 13, 1991, the Agency reproposed effluent limitations guidelines and standards for both drilling and production wastes. The report is primarily concerned with the total annualized cost incurred by the offshore oil and gas industry in complying with the regulations.
In a suicide committed using aluminium phosphide (AlP) the liberated toxic phosphine gas was detected in post-mortem specimens using a headspace gas chromatographic procedure with a nitrogen-phosphorous detector (HS-GC/NPD). At autopsy a direct sampling into airtight headspace vials for a later analysis is recommended. AlP has to be considered a potent pesticide and its use and availability should be restricted as much as possible.
The most striking feature of quantum mechanics is the existence of superposition states, where an object appears to be in different situations at the same time. Up to now, the existence of such states has been tested with small objects, like atoms, ions, electrons and photons, and even with molecules. Recently, it has been even possible to create superpositions of collections of photons, atoms, or Cooper pairs. Current progress in optomechanical systems may soon allow us to create superpositions of even larger objects, like micro-sized mirrors or cantilevers, and thus to test quantum mechanical phenomena at larger scales. Here we propose a method to cool down and create quantum superpositions of the motion of sub-wavelength, arbitrarily shaped dielectric objects trapped inside a high--finesse cavity at a very low pressure. Our method is ideally suited for the smallest living organisms, such as viruses, which survive under low vacuum pressures, and optically behave ...
The basic idea is to implement Thomson scattering with free electron laser (FEL) radiation at near-solid density plasmas as a diagnostic method which allows the determination of plasma temperatures and densities in the warm dense matter (WDM) regime (free electron density of n{sub e} = 10{sup 21}-10{sup 26} cm{sup -3} with temperatures of several eV). The WDM regime [1] at near-solid density (n{sub e} = 10{sup 21}-10{sup 22} cm{sup -3}) is of special interest because, it is where the transition from an ideal plasma to a degenerate, strongly coupled plasma occurs. A systematic understanding of this largely unknown WDM domain is crucial for the modeling and understanding of contemporary plasma experiments, like laser shock-wave or Z-pinch experiments as well as for inertial confinement fusion (ICF) experiments as the plasma evolution follows its path through this domain.
III-V semiconductors, GaAs and in particular InGaP, are used in many different electronic applications, such as high power and high frequency devices, laser diodes and high brightness LED. Their direct bandgap and high reliability make them ideal candidates for the realisation of high efficiency solar cells: in the past years they have been successfully used as power sources for satellites in space, where they are able to produce electricity from sunlight with an overall efficiency of around 30%. Nowadays, the use of arsenides and phosphides as photovoltaic (PV) devices is confined only to space applications since their price is much higher than conventional Si flat panel modules, the leading PV market technology. But with the introduction of multijunction solar cells capable of operating in high concentration solar light, the area and, therefore, the cost of these cells can be reduced and will eventually find an application and market also on Earth. This article ...
A computer controlled digital system, Fuji Computed Radiography (FCR) is capable of providing more stable output image than conventional screen/film system. So FCR would be an ideal system for the detection of pneumoconiosis due to the constant high quality of the output films. We tried to find the optimum image processing to compensate the small size (1/2 in length of a full-size radiograph) of the output image of digital radiography. The best result for FCR was given with gamma 0.85 and 0.30 enhancement of response at spatial frequency of 0.085 cycle/mm. On the other hand, the digitally processed FCR size ILO standard films, the characteristics of which is different from FCR output films, proved to be most preferable when the image processing is made with gamma 0.85 and 0.25 enhancement at spacial frequency of 0.17 cycle/mm. If the above mentioned image processings are adopted, FCR can be used for the diagnosis of pneumoconiosis with the same accuracy as the ...
A computer controlled digital system, Fuji Computed Radiography (FCR) is capable of providing more stable output image than conventional screen/film system. So FCR would be an ideal system for the detection of pneumoconiosis due to the constant high quality of the output films. We tried to find the optimum image processing to compensate the small size (1/2 in length of a full-size radiograph) of the output image of digital radiography. The best result for FCR was given with gamma 0.85 and 0.30 enhancement of response at spatial frequency of 0.085 cycle/mm. On the other hand, the digitally processed FCR size ILO standard films, the characteristics of which is different from FCR output films, proved to be most preferable when the image processing is made with gamma 0.85 and 0.25 enhancement at spacial frequency of 0.17 cycle/mm. If the above mentioned image processings are adopted, FCR can be used for the diagnosis of pneumoconiosis with the same accuracy as the ...
The structure of Poisson polynomial algebras of the type obtained as semiclassical limits of quantized coordinate rings is investigated. Sufficient conditions for a rational Poisson action of a torus on such an algebra to leave only finitely many Poisson prime ideals invariant are obtained. Combined with previous work of the first-named author, this establishes the Poisson Dixmier-Moeglin equivalence for large classes of Poisson polynomial rings, such as semiclassical limits of quantum matrices, quantum symplectic and euclidean spaces, quantum symmetric and antisymmetric matrices. For a similarly large class of Poisson polynomial rings, it is proved that the quotient field of the algebra (respectively, of any Poisson prime factor ring) is a rational function field $F(x_1,...,x_n)$ over the base field (respectively, over an extension field of the base field) with $\\{x_i,x_j\\}= \\lambda_{ij} x_ix_j$ for suitable scalars $\\lambda_{ij}$, thus establishing a ...
The layered cobaltate La0.30CoO2 was prepared from NaxCoO2 precursor by a solid-state ionic exchange and was characterized by means of X-ray and neutron diffraction, magnetic, thermal and electric transport measurements. The compound consists of hexagonal sheets of edge-sharing CoO6 octahedra interleaved by lanthanum monolayers. Compared to Na+ in the parent system, the La3+ ions occupy only one-third of available sites, forming a 2-dimensional superstructure. The deviation from the ideal stoichiometry La1/3CoO2 introduces extra hole carriers into the diamagnetic LS Co3+ matrix making the sample Pauli paramagnetic. The temperature dependence of the electrical conductivity in La0.30CoO2 follows Mott's T?1/3 law up to about 400K, which is in contrast w...
The use of n-alkanethiolate self-assembled monolayers on gold has blossomed in the past few years. These systems have functioned as models for common interfaces. Thiolate monolayers are ideal because they are easily modified before or after deposition. The works contained within this dissertation include interfacial characterization (inbred reflection absorption spectroscopy, ellipsometry, contact angle, scanning probe microscopy, and heterogeneous electron-transfer kinetics) and various modeling scenarios. The results of these characterizations present ground-breaking insights into the structure, function, and reproducible preparation of these monolayers. Surprisingly, three interfacial properties (electron-transfer, contact angle, and ellipsometry) were discovered to depend directly on the odd-even character of the monolayer components. Molecular modeling was utilized to investigate adlayer orientation, and suggests that these effects are adlayer structure ...
The amorphization of a quenched sample of the GaSb-II high-pressure phase was studied at ambient pressure by real-time neutron diffraction in the course of the sample heating from 100 K to room temperature at a rate of 0.4 K min{sup -1}. The transformation to the amorphous state begins at 140 K and is completed near room temperature. The {beta}-Sn type structure was shown to represent only the mean lattice of the high-pressure GaSb-II phase. The superstructure of this phase widely varied with temperature and is caused by the ordered displacement of atoms. The temperature range of the metastable crystalline phase relaxation is divided into three intervals according to the temperature dependence of the tetragonality ratio (c/a). At the boundaries of these temperature intervals, i.e. temperatures T = 170 and 230 K, two second-order phase transitions are observed. Anomalous heat and volumetric effects were observed earlier by means of calorimetry and dilatometry in the same temperature ...
The amorphization of a quenched sample of the GaSb-II high-pressure phase was studied at ambient pressure by real-time neutron diffraction in the course of the sample heating from 100 K to room temperature at a rate of 0.4 K min-1. The transformation to the amorphous state begins at 140 K and is completed near room temperature. The ?-Sn type structure was shown to represent only the mean lattice of the high-pressure GaSb-II phase. The superstructure of this phase widely varied with temperature and is caused by the ordered displacement of atoms. The temperature range of the metastable crystalline phase relaxation is divided into three intervals according to the temperature dependence of the tetragonality ratio (c/a). At the boundaries of these temperature intervals, i.e. temperatures T = 170 and 230 K, two second-order phase transitions are observed. Anomalous heat and volumetric effects were observed earlier by means of calorimetry and dilatometry in the same temperature range. ...
Research and development has been performed on photochromic materials expected to be used in ultra-high density recording, high resolution indication and photoswitches. With regard to molecular orientation in the ternary system mixed LB film, the result of structural analysis by XPM spectrum revealed that the acceptor constituent in the LB film is so structured that it is separated and laminated with two other constituents, and that the sensitizer constituent and the donor constituent are not recognized of being separated definitely. Regarding the electron movement reaction in the solid phase system, a photo-current measuring experiment was carried out on the laminated film which is vacuum-deposited with the ternary system comprising of the donor, sensitizer, and acceptor. It was concluded that the observed photo-current reflects the electron movement reaction in the solid phase as it is. For the photo-current in the LB film, increase in the photo-current was observed according to the ...
Uncertainty in computer vision can arise at various levels. It can occur in the low level in the raw sensor input, and extends all the way through intermediate and higher levels. Ideally, at any level where decisions are being made on the basis of previous processing steps, a computer vision system must have sufficient flexibility for representation of uncertainty in any of these levels. The input cue representation portion of a computer vision system should maintain the information content of the original input images, while at the same time allowing for uncertainty in the identification of attributes required by other parts of the system for decision making. Processes such as edge detection, segmentation, and shape matching yield results which could bias higher level decision making, unless some framework is defined for the representation of uncertainty in the context of fuzzy set theory where membership values associated with the fuzzy sets contain a consistent ...
Wood sawdust has been applied to manufacture the sawdust-clay-plastic composite (SDCPC) by radiation process for the purpose of disposing large amount of wood sawdust waste material. The process comprises the impregnation of liquid vinyl monomers into the completely dried molded sawdust-clay specimens followed by exposure to Co-60 gamma-radiation to induce graft-copolymerization of the impregnated vinyl monomers onto the sawdust-clay matrix. The comonomer system of unsaturated polyester and vinyl compounds was found to be the ideal impregnating monomer for the preparation of the SDCPC from the viewpoint of the technological and economical advantages. The SDCPC material has a variety of the sawdust content which enables the composite to have wide range of mechanical properties, e.g., 410 to 1100 kg/cm/sup 2/ in compressive strength, 120 to 380 kg/cm/sup 2/ in tensile strength and 0.32 to 4.41 kg/mm/sup 2/ in static bending strength. The SDCPC having higher content ...
The goal of this work was to develop a process flow diagram to economically produce a clean-burning fuel from fine Illinois coal. To accomplish this, the process of pelletizing fine coal with calcium hydroxide, a sulfur capturing sorbent, was investigated. Carbonation, which is the reaction of calcium hydroxide with carbon dioxide (in the presence of moisture) to produce a bonding matrix of calcium carbonate, was investigated as a method for improving pellet quality and reducing binder costs. Proper moisture level is critical to allow the reaction to occur. If too much moisture is present in a pellet, the pore spaces are filled and carbon dioxide must diffuse through the water to reach the calcium hydroxide and react. This severely slows or stops the reaction. The ideal situation is when there is just enough moisture to coat the calcium hydroxide allowing for the reaction to proceed. The process has been successfully demonstrated on a pilot-scale as a method of ...
Obtaining precise values of the undulator parameter, K, is critical for producing high-gain FEL radiation. At the LCLS [1], where the FEL wavelength reaches down to 1.5 {angstrom}, the relative precision of K must satisfy ({Delta}K/K){sub rms} {approx}< 0.015% over the full length of the undulator. Transverse misalignments, construction errors, radiation damage, and temperature variations all contribute to errors in the mean K values among the undulator segments. It is therefore important to develop some means to measure relative K values, after installation and alignment. We propose a method using the angle-integrated spontaneous radiation spectrum of two nearby undulator segments, and the natural shot-to-shot energy jitter of the electron beam. Simulation of this scheme is presented using both ideal and measured undulator fields. By ''leap-frogging'' to different pairs of segments with extended separations we hope to ...
Measurement of redshifted 21-cm emission from neutral hydrogen promises to be the most effective method for studying the reionisation history of hydrogen and, indirectly, the first galaxies. These studies will be limited not by raw sensitivity to the signal, but rather, by bright foreground radiation from Galactic and extragalactic radio sources and the Galactic continuum. In addition, leakage due to gain errors and non-ideal feeds conspire to further contaminate low-frequency radio obsevations. This leakage leads to a portion of the complex linear polarisation signal finding its way into Stokes I, and inhibits the detection of the non-polarised cosmological signal from the epoch of reionisation. In this work, we show that rotation measure synthesis can be used to recover the signature of cosmic hydrogen reionisation in the presence of contamination by polarised foregrounds. To achieve this, we apply the rotation measure synthesis technique to the Stokes I ...
When one deals with a plasma column whose radius a is much smaller than its length L, one can think of it as of a thin filament whose kink instability can be adequately described simply by a 2D displacement vector, {xi}{sub x} = {xi}{sub s}(z,t); {xi}{sub y} = {xi}{sub y}(z,t). Details of the internal structure of the column such as the current, density, and axial flow velocity distribution would be lumped into some phenomenological parameters. This approach is particularly efficient in the problems with non-ideal (sheath) boundary conditions (BC) at the end electrodes, with the finite plasma resistivity, and with a substantial axial flow. With the sheath BC imposed at one of the end-plates, we find instability in the domain well below the classical Kruskal-Shafranov limit. The presence of an axial flow causes the onset of rotation of the kink and strong axial ''skewness'' of the eigenfunction, with the perturbation amplitude ...
A class II atomistic force field with Lennard-Jones 6-9 nonbond interactions is used to investigate equations of state (EOS) for important high explosive detonation products N{sub 2} and H{sub 2}O in the temperature range 700-2500 K and pressure range 0.1-10 GPa. A standard 6th order parameter-mixing scheme is then employed to study a 2:1 (molar) H{sub 2}O:N{sub 2} mixture, to investigate in particular the possibility of phase-separation under detonation conditions. The simulations demonstrate several important results, including: (1) the accuracy of computed EOS for both N{sub 2} and H{sub 2}O over the entire range of temperature and pressure considered; (2) accurate mixing-demixing phase boundary as compared to experimental data; and (3) the departure of mixing free energy from that predicted by ideal mixing law. The results provide comparison and guidance to state-of-the-art chemical kinetic models.
Kevlar 49/epoxy laminates often exhibit substantial material nonlinearity when subjected to bending. This is a consequence of the yeild-like behavior of a Kevlar 49/epoxy lamina in fiber-directed compression. In this paper, analyses that utilize a simple idealization of compressive yielding are described and calculated results for Kevlar 49 reinforced beams and rings are compared with available data. First, results of a finite element analysis of a thin, unidirectionally reinforced ring subjected to diametral compression are presented. This analysis uses beam elements that incorporate linear tensile and elastic-perfectly plastic compressive behavior. Then a method used to analyze quasi-isotropic beams tested in four-point bending is discussed. This finite element analysis uses a layered shell element with a lamina constitutive model that permits elastic-perfectly plastic response to fiber-directed compression, but otherwise assumes linear elastic behavior. ...
Projected scenarios for the proposed Yucca Mountain repository include significant periods of time when high relative humidity atmospheres will be present, thus the reaction processes of interest will include those known to occur under these conditions. The ideal natural analog for the proposed Yucca Mountain repository would consist of natural borosilicate glasses exposed to expected repository conditions for thousands of years; however, the prospects for identifying such an analog are remote, but an important caveat for using natural analog studies is to relate the reaction processes in the analog to those in the system of interest, rather than a strict comparison of the glass compositions. In lieu of this, identifying natural glasses that have reacted via reaction processes expected in the repository is the most attractive option. The goal of this study is to quantify molecular water diffusion in the natural analogs obsidian and tektites. Results from this study ...
In the spring of 2002, the Department of Energy provided an initial 1-year grant to the Bureau of Economic Geology (BEG) at The University of Texas at Austin (UT). The grant covered the one-year operational expenses of a worldclass core and cuttings facility located in Houston, Texas, that BP America donated to the BEG. The DOE investment of $300,000, matched by a $75,000 UT contribution, provided critical first-year funds that were heavily leveraged by the BP gift of $7.0 million in facilities and cash. DOE also provided a one-month extension and grant of $30,000 for the month of May 2003. A 5-year plan to grow a permanent endowment in order to manage the facility in perpetuity is well under way and on schedule. The facility, named the Houston Research Center, represents an ideal model for a strong Federal, university, and private partnership to accomplish a national good. This report summarizes the activities supported by the initial DOE grant during the first 13 ...
Monte-Carlo simulations of 2-MeV #alpha#-particle channeling in Si_1_-_xSn_x alloys with 0#<=#x#<=#1 have been performed. The simulations are compared with measured channeling-angular scans for strained Si_0_._9_5Sn_0_._0_5 layers grown by molecular beam epitaxy (MBE). Agreement between simulated and measured angular scans can only be achieved if we assume a deviation of the crystal structure from the ideal one. This deviation can be attributed to a mosaic structure in the films and to an atomic-scale distortion of the crystal lattice due to an expected difference in the bond lengths between the Si-Si, Si-Sn and Sn-Sn atoms (such a difference in bond lengths has been observed in the epitaxial Si_1_-_xGe_x system). The contributions from both of these imperfections are estimated and discussed.
An axisymmetric unit cell model based on a regular array of second-phase particles arranged on a BCC lattice is used to study deformation mechanisms of ferrite-pearlite structural steels. Microstructural characteristics of the steels were parameterized by the pearlite volume fraction, the aspect ratio of the pearlite particles, and the neighboring factor, which represents the ratio of interparticle spacing in the longitudinal direction to that in the transverse direction. FE analyses were carried out to investigate the macroscopic and microscopic response of unit cells with morphological features based on idealizations of the microstructures of the actual steels. Tensile properties of each constituent phase were obtained experimentally and used in the analyses. As compared to traditional axisymmetric models, the BCC tell model appears to be able to capture more realistically the behavior of the materials, and it accurately estimates the tensile behavior of the ...
The LSND (Liquid Scintillator Neutrino Detector) experiment will be performed at LAMPF in the next several years. The main goal of the experiment is to search for {nu}{sub {mu}}-{nu}{sub e} oscillations with high sensitivity; however, an increasingly important by-product of this search is to measure {nu}p {yields} {nu}p elastic scattering and determine the strange quark contribution, {Delta}s, to the spin of the proton. With the 800-MeV proton energy of LAMPF, neutrinos are produced from pion decay-in-flight with an average energy of about 150 MeV. This energy is sufficiently high so that the {nu}p {yields} {nu}p cross section is large and is sufficiently low so that the low Q{sup 2} approximation (Q{sup 2} {much lt} m{sub p}{sup 2}) is valid and the cross section can be expressed in a simple form dependent upon {Delta}s as the only unknown. LAMPF with its 1-mA proton intensity is, therefore, an ideal accelerator to perform this measurement. 12 refs., 7 figs., 2 ...
Gallium is present in surplus weapons-grade plutonium (WG-Pu) at a concentration of approximately 1 wt %. Plans are to dispose of surplus WG-Pu by converting it to UO{sub 2}-PuO{sub 2} mixed oxide (MOX) fuel and irradiating it in commercial power reactors. However, the presence of high concentrations of gallium in plutonium poses a potential corrosion problem during the process of MOX fuel irradiation. The batch experiments performed in this study were designed to measure the capability of the PUREX solvent extraction process to separate gallium from plutonium under idealized conditions. Radioactive tracing of the gallium with {sup 72}Ga enabled the accurate measurement of low concentrations of extractable gallium. The experiments approximated the proposed flowsheet for WG-Pu purification, except that only one stage was used for each process: extraction, scrubbing, and stripping. The gallium decontamination factor (DF) obtained after one extraction stage was about ...
Radiation defects produced by helium implantation were used to shape profiles of palladium (Pd) and platinum (Pt) atoms in-diffusing (for 20 min at temperatures 600-800 deg. C) either from surface silicide (Pd_2Si, PtSi) or implanted layers. Results show that this procedure allows a strong localization of substitutional Pd and Pt at the depth where the damage produced by helium peaks. This results in local reduction of carrier lifetime by an almost ideal recombination centers - the acceptor level of substitutional Pd (E _c - 0.22 eV) or Pt (E _c - 0.23 eV). While optimum conditions for Pt in-diffusion are about 700 deg. C, Pd gives the best results already at lower temperatures (600 deg. C) where it also exhibits higher peak solubility. Both methods were used for optimization of turn-off properties of high power PiN diodes. The devices, where the lifetime was killed locally by Pd and Pt, exhibited similar trade-off between the static and dynamic parameters as the ...
Excellent silicided shallow p{sup +}n junctions have been successfully achieved by the implantation of BF{sub 2}{sup +} ions into thin Pd{sub 2}Si films on Si substrates to a dose of 5 {times} 10{sup 15} cm{sup {minus}2} and subsequent low temperature (even at 550 C) furnace annealing. The formed junctions have been characterized for respective implantation conditions. In this experiment, the implant energy is the key role in obtaining a low leakage diode. Reverse current density of about 3 nA/cm{sup 2} and an ideality factor of about 1.05 can be attained by the implantation of BF{sub 2}{sup +} ions at 80 keV and subsequent annealing at 550 C. The junction depth is about 0.09 {mu}m, measured by the spread resistance method. As compared with the results of unimplanted specimens, the implantation of BF{sub 2}{sup +} ions into a thin Pd{sub 2}Si layer can stabilize the silicide film and prevent it from forming islands during high temperature annealing.
Laser frequency stabilization giving a 500-Hz Allan deviation for a 2-ms integration time with drift reduced to 7 kHz/min over several minutes was achieved at 1536 nm in the optical communication band. A continuously regenerated spectral hole in the inhomogeneously broadened "4I_1_5_/_2(1)#->#"4I_1_3_/_2(1) optical absorption of an Er"3"+:Y_2SiO_5 crystal was used as the short-term frequency reference, while a variation on the locking technique allowed simultaneous use of the inhomogeneously broadened absorption line as a long-term reference. The reported frequency stability was achieved without vibration isolation. Spectral hole burning frequency stabilization provides ideal laser sources for high-resolution spectroscopy, real-time optical signal processing, and a range of applications requiring ultra-narrow-band light sources or coherent detection; the time scale for stability and the compatibility with spectral hole burning devices make this technique ...
Measurements of the Kapitza conductance to liquid helium II across the (100) surface of single crystals of copper are presented. The temperature range of these measurements was 1.6-- 2.1 K. The sample surfaces were subjected to several different treatments. Some surfaces were cleaned by low-energy argon ion bombardment, annealed in an ultrahigh-vacuum system, and preserved under vacuum until purified liquid helium was admitted. Other surfaces were intentionally damaged by machining and/or exposure to the atmosphere. The conductance after these latter treatments was found to be about a factor of three higher than that of the more ideally cleaned and annealed surfaces, and a significant difference in the temperature dependence of the conductance was also observed. Conductances were reproducible for similarly treated surfaces and correlated with surface damage determined by x-ray diffraction. The relationship of these results to the numerous current theories of the ...
The purpose of this study was to determine the optimal technique for delivering postoperative radiotherapy for vulvar cancer and other tumors requiring treatment of the inguinal nodes. This project compared tumor coverage and normal tissue sparing for the 5 main radiotherapy techniques that are used to treat vulvar cancer. The intensity-modulated radiation therapy (IMRT) plan was undesirable because it resulted in an excessive dose to portions of the central pelvic structures. The photon thunderbird with skin match was unacceptable because it underdosed a portion of the groin region. The electron thunderbird was ideal for thin patients but was not applicable for most patients because of excessive dose to the skin and subcutaneous tissues. The photon through-and-through and the photon thunderbird with deep match were acceptable in most situations. In thin patients, where the depth of the inguinal vessels is less than 3 cm, the electron thunderbird is the technique ...
Pd/sub 2/Si layers produced by evaporation or sputtering onto silicon substrates were examined by high resolution electron microscopy, microdiffraction, X-ray, energy loss and Auger spectroscopy. The Si-Pd/sub 2/Si interfaces produced by evaporation were in all cases rougher and more polycrystalline than those produced by sputtering. X-ray microanalysis showed the predictable variation in palladium distribution across the interface but quantification did not produce the expected palladium-to-silicon ratios, primarily because of probe broadening and X-ray-induced fluorescence. Energy loss spectra showed plasmon energy shifts and changes in Si L edge shape due to bond formation with palladium. Auger data provided evidence for a small amount of oxygen at the Si-Pd/sub 2/Si interface. Electrical measurements of the ideality factor for Schottky barriers made from the materials produced higher values for the rougher evaporation-formed interfaces consistent with ...
High-purity and doped GaAs films have been grown by Liquid-phase epitaxy (LPE) for development of a blocked impurity band (BIB) detector for far-infrared radiation. The film growth process developed has resulted in the capability to grow GaAs with a net active impurity concentration below 1 x 10{sup 13} cm{sup -3}, ideal for the blocking layer of the BIB detector. The growth of n-type LPE GaAs films with donor concentrations below the metal-insulator transition, as required for the absorbing layer of a BIB detector, has been achieved. The control of the donor concentration, however, was found to be insufficient for detector production. The growth by LPE of a high-purity film onto a commercially grown vapor-phase epitaxial (VPE) n-type GaAs doped absorbing layer resulted in a BIB device that showed a significant reduction in the low-temperature dark current compared to the absorbing layer only. Extended optical response was not detected, most likely due to the high ...
A fully quantized many-particle theory of the standard free-electron laser in the small-signal, cold-beam regime is presented. The approach is based on an evaluation of the time-evolution operator in the interaction picture to first order in the quantum-mechanical recoil. For algebraic convenience we use the moving (Bambini-Renieri) frame, in which resonance occurs for zero electron momentum. Though we neglect space-charge effects, genuine many-particle contributions still show up, because the radiation emitted by one electron can be amplified by another electron. Our main results are gross features of the amplification, such as gain and spread, are virtually without many-particle effects. These effects are mainly important in the case of spontaneous emission. For a sufficiently high current, the buildup of the laser field from vacuum is enhanced by amplified spontaneous emission. Incoherence of the spontaneous radiation from several electrons induces deviations from Poisson statistics ...
The linearized-augmented-plane-wave (LAPW) method for thin films is generalized by removing the remaining shape approximation to the potential inside the atomic spheres. A new technique for solving Poisson's equation for a general charge density and potential is described and implemented in the film LAPW method. In the resulting full-potential LAPW method (FLAPW), all contributions to the potential are completely taken into account in the Hamiltonian matrix elements. The accuracy of the method: already well known for clean metal surfaces: is demonstrated for the case of a nearly free (noninteracting) O_2 molecule which is a severe test case of the method because of its large anisotropic charge distribution. Detailed comparisons show that the accuracy of the FLAPW results for O_2 exceeds that of existing state-of-the-art local-density linear-combination-of-atomic-orbitals (LCAO)-type calculations, and that taking the full potential LAPW results as a reference, the LCAO basis can be ...
We report the first direct detection of an exoplanet in polarized scattered light. The transiting planet HD189733b is one of the very hot Jupiters with shortest periods and, thus, smallest orbits, which makes them ideal candidates for polarimetric detections. We obtained polarimetric measurements of HD189733 in the $B$ band well distributed over the orbital period and detected two polarization maxima near planetary elongations with the peak amplitude of $\\sim2\\cdot10^{-4}$. Assuming Rayleigh scattering, we estimated the effective size of the scattering atmosphere (Lambert sphere) to be 1.5$\\pm$0.2 $R_{\\rm J}$, which is 30% larger than the radius of the opaque body previously inferred from transits. If the scattering matter fills the planetary Roche lobe, the lower limit of the geometrical albedo can be estimated as 0.14. The phase dependence of polarization indicates that the planetary orbit is oriented almost in the north-south direction with the longitude of ...
The {sup 252}Cf-source-driven frequency analysis method can be used for measuring the subcritical neutron multiplication factor of arrays of LWR fuel and as little as a single PWR fuel assembly. These measurements can be used to verify the criticality safety margins of spent LWR fuel configurations and thus could be a means of obtaining the information to justify burnup credit for spent LWR transportation/storage casks. In addition, the data can be used to validate calculational methods for criticality safety. These measurements provide parameters that have a higher sensitivity to changes in fissile mass than neutron multiplication factor and thus serve as a better test of calculational methods. The analysis have also shown that measurement of the cross power spectral density (CPSD) between detectors on one side of a single fuel assembly and an internal or external {sup 252}Cf source driving the fission chain multiplication process can be used for nondestructive assay of fissile mass ...
One of the most densely populated urban regions in the world is the Sao Paulo Metropolitan region (SPMR) in the State of Sao Paulo, Brazil. Air pollution is a real problem, mainly caused by vehicle exhaust fumes. The air pollution abatement measures adopted in the SPMR, such as the addition of ethanol to gasoline, the use of cars running on pure alcohol, the restrictions in the circulation of vehicles and the utilization of electronic fuel injection and catalyst have had a positive effect on the environment. The 25,000 buses and approximately 400,000 trucks, all operating on diesel, have not been affected by these measures, and it is believed that SPMR is the ideal location for testing new vehicular pollution reduction technologies. A project to this effect was launched by the Ministry of Mines and Energy in conjunction with a host of other partners, and it involved the operation of a fuel cell bus using hydrogen produced by electrolysis. The project was divided ...
Deteriorating air quality in urban areas is leading bus manufacturers to look for cleaner drives of urban buses. Various new systems are now available, but it is difficult to compare them and verify their effects without having a driving cycle accurately representing contemporary average urban bus use. The idealized form (engine cycle, passenger car cycle or different kW/tonnes ratio and traffic conditions) of existing driving cycles disqualifies them for the purpose. For this reason, it was decided to attempt the development of a new driving cycle for urban buses. To this end, measurements were carried out on buses in service in four major Dutch towns. The resulting data were combined to produce a reference cycle comprising all data relating to urban bus use. Statistical methods were then used to compare a large number of 15-20 minute cycles with this reference cycle, until one was found that corresponded closely to the reference cycle. 5 figs., 1 tab., 6 refs.
Automated, variable volume unloaders provide the ability to smoothly load/unload reciprocating compressors to maintain ideal operations in ever-changing environments. Potential advantages provided by this load control system include: maximizing unit capacity, optimizing power economy, maintaining low exhaust emissions, and maintaining process suction and discharge pressures. Obstacles foreseen include: reliability, stability, serviceability and automation integration. Results desired include: increased productivity for the compressor and its operators, increased up time, and more stable process control. This presentation covers: system design features with descriptions of how different types of the devices were developed, initial test data, and how they can be effectively operated; three actual-case studies detailing the reasons why automated, hydraulically controlled, variable volume, head-end unloaders were chosen over other types of unloading devices; ...
Burnable poisons are used in nuclear reactors to produce a more level distribution of power in the reactor core and to reduce to necessity for a large control system. An ideal burnable poison would burn at the same rate as the fuel. In this study, separation of neutron-absorbing isotopes was investigated in order to eliminate isotopes that remain as absorbers at the end of fuel life, thus reducing useful fuel life. The isotopes Gd-157, Dy-164, and Er-167 were found to have desirable properties. These isotopes were separated from naturally occurring elements by means of plasma separation to evaluate feasibility and cost. It was found that pure Gd-157 could save approximately $6 million at the end of four years. However, the cost of separation, using the existing facility, made separation cost- ineffective. Using a magnet with three times the field strength is expected to reduce the cost by a factor of ten, making isotopically separated burnable poisons a favorable ...
Quaternary semiconductor compounds are ideal candidates for use in monolithic cascade solar cells because the lattice constant and the bandgap of such compounds can be independently varied. The quaternary semiconductor compound Ga[sub 0.83]In[sub 0.17]As[sub 0.67]P[sub 0.33] not only is lattice matched to GaAs and Ge but also provides a current matched top cell for the GaInAsP/Ge monolithic cascade solar cell. Under concentration of 100 suns, the projected efficiency for such a cell is about 34%. The growth of Ga[sub 0.83]In[sub 0.17]As[sub 0.67]P[sub 0.33] lattice matched to GaAs and Ge has been demonstrated. GaInAsP solar cells have been grown on both GaAs and Ge substrates. A GaInAsP on GaAs solar cell with an active area efficiency of 23.2% for 1 sun, AM 1.5 direct illumination has been prepared. A proposed structure for the GaInAsP/Ge cascade cell is also given.
The objective of our research was to obtain fundamental information regarding the functional dependence of the diffusion coefficient of coal molecules on the ratio of molecule to pore diameter. That is, the objective of our study was to examine the effect of molecule size and configuration on hindered diffusion of coal macromolecules through as porous medium. To best accomplish this task, we circumvented the complexities of an actual porous catalyst by using a well defined porous matrix with uniform capillaric pores, i.e., a track-etched membrane. In this way, useful information was obtained regarding the relationship of molecular size and configuration on the diffusion rate of coal derived macromolecules through a pore structure with known geometry. Similar studies were performed using a pellet formed of porous alumina, to provide a link between the idealized membranes and the actual complex pore structure of real catalyst extrudates. The fundamental information ...
Computed tomography (CT) of the thorax shows early promise of important diagnostic advances. We believe that CT often provides information superior to that provided by standard roentgenographic techniques, is capable of significantly influencing patient management, and in selected instances, offers unique information not available by other methods. Computed tomography permits the imaging of mediastinal structures not possible with conventional roentgenographic methods and can diagnose with certainty benign mediastinal conditions such as pericardial cysts and focal or diffuse accumulations of fat. It is ideal for detecting pleural abnormalities and for displaying underlying parenchymal disease in patients with complex pleuroparenchymal shadows on conventional films. Pulmonary metastases unseen on the plain chest film can be detected with greater sensitivity than by any other method. Future applications of CT include the staging of mediastinal lymph nodes in ...
Computed tomography (CT) of the thorax shows early promise of important diagnostic advances. We believe that CT often provides information superior to that provided by standard roentgenographic techniques, is capable of significantly influencing patient management, and in selected instances, offers unique information not available by other methods. Computed tomography permits the imaging of mediastinal structures not possible with conventional roentgenographic methods and can diagnose with certainty benign mediastinal conditions such as pericardial cysts and focal or diffuse accumulations of fat. It is ideal for detecting pleural abnormalities and for displaying underlying parenchymal disease in patients with complex pleuroparenchymal shadows on conventional films. Pulmonary metastases unseen on the plain chest film can be detected with greater sensitivity than by any other method. Future applications of CT include the staging of mediastinal lymph nodes in ...
This work presents an overview of the characterization physical-chemistry and energy of the aca pit used as input in process of generation of electricity through gasification. Acai pits analyses were accomplished with relationship to the acai pit drying, energy content, proximate and ultimate analyses, size, TGA experiments, bulk density. It was observed that the acai pit can be used as bioenergy but, it presents a low energy content (16,36 MJ/kg) in relationship that of the ' typical' biomass (21 MJ/kg ) and this is not due to the ash content that is very low (1,15%), but yes, the only composition that resembles each other more the Carbohydrates than to the typical composition of the usual biomass. The average diameter of 10 pits chosen at random was 9.5 mm. The acai pits have an angle of repose of {approx}20 degrees, making them ideal for feeding into gasification and combustion processes. (author)
The staring point of the project was to design and construct, by taking the silvicultural point of view into account, a harvesting and processing system especially for energy-wood, containing manually driven bundling harvester, automatizing of the harvester, and automatized loading. The equipment forms an ideal method for entrepreneur`s-line harvesting. The target is to apply the system also for owner`s-line harvesting. The profitability of the system promotes the utilization of the system in both cases. The objectives of the project were: to construct a test equipment and prototypes for all the project stages, to carry out terrain and strain tests in order to examine the usability and durability, as well as the capacity of the machine, to test the applicability of the Eko-Log system in simultaneous harvesting of energy and pulp woods, and to start the marketing and manufacturing of the products. The basic problems of the construction of the bundling harvester have ...
The purpose of the study was to investigate the adequacy of educational services available for the implementation of the ideals of the Universal Basic Education (UBE) in Southern Nigeria. Using the multistage sampling technique, 800 primary school teachers were selected from the three geo political zones in Southern Nigeria as participants in the study. However, 1457 usable copies of the questionnaire administered to participants were used for the final study. The researchers collected and analyzed data to (1) Ascertain how free the UBE was in Southern Nigeria and (2) to determine if educational services were adequately provided for the implementation of the programme. Results of data analysis suggest that the UBE was not entirely free as parents still buy books and report cards for their children in primary schools. Also, educational services were not adequately provided in the schools. Recommendations were made to government on how to improve the situation so as ...
A first-principles task-based approach to the design of medical ultrasonic imaging systems for breast lesion discrimination is described. This study explores a new approximation to the ideal Bayesian observer strategy that allows for object heterogeneity. The new method, called iterative Wiener filtering, is implemented using echo data simulations and a phantom study. We studied five lesion features closely associated with visual discrimination for clinical diagnosis. A series of human observer measurements for the same image data allowed us to quantitatively compare alternative beamforming strategies through measurements of visual discrimination efficiency. Employing the Smith-Wagner model observer, we were able to breakdown efficiency estimates and identify the processing stage at which performance losses occur. The methods were implemented using a commercial scanner and a cyst phantom to explore development of spatial filters for systems with shift-variant ...
Divided into three sections, this paper briefly presents Kohlberg's theory of moral reasoning; surveys some key research relating childrearing practices to adolescents' social competence, including moral reasoning; and reports research findings concerning the value systems adolescents develop. The first section characterizes preconventional, conventional, and postconventional morality and explores ways of promoting the development of a mature concept of justice, which includes role taking and living in a "just community." The second section focuses on aspects of social learning, which include authoritative parenting, inductive discipline, argumentative discourse, and tradition-based upbringing. In addition, this section explores socialization practices that hinder the development of mature moral reasoning. Focusing initially on characteristics of alienated youth and parental influences on such youth, the third section describes studies investigating the values development of New York ...
We present new results from accurate and fully general-relativistic simulations of the coalescence of unmagnetized binary neutron stars with various mass ratios. The evolution of the stars is followed through the inspiral phase, the merger and prompt collapse to a black hole, up until the appearance of a thick accretion disk, which is studied as it enters and remains in a regime of quasi-steady accretion. Although a simple ideal-fluid equation of state with \\Gamma=2 is used, this work presents a systematic study within a fully general relativistic framework of the properties of the resulting black-hole--torus system produced by the merger of unequal-mass binaries. More specifically, we show that: (1) The mass of the torus increases considerably with the mass asymmetry and equal-mass binaries do not produce significant tori if they have a total baryonic mass M_tot >~ 3.7 M_sun; (2) Tori with masses M_tor ~ 0.2 M_sun are measured for binaries with M_tot ~ 3.4 ...
In this article, we review and clarify some of the points made by previous authors regarding chemical looping combustion (CLC). While much of the recent interest in chemical looping combustion has been associated with carbon sequestration, our primary interest here is its potential to increase the thermodynamic efficiency of converting fuel chemical energy into useful work. We expand on several points about the details of CLC that we feel have not previously been sufficiently explored, and suggest alternative (and possibly more practical) approaches that exploit some of the same thermodynamic concepts. We illustrate our key points with {First} and {Second} Law analyses of ideal conceptual processes, which in addition to {CLC} also include isothermal, non-equilibrium, preheated combustion and combustion with thermochemical recuperation. Our results suggest that a significant portion of the potential efficiency benefit of CLC might be achieved without the need to ...
The paper presents the procedure of an investigation of WWER-1000 primary circuit temperature-stress field by the use of thermohydraulic computation data for a pressurized thermal shock event ''Core overcooling''. The procedure is based on a model of the plane stress state with ideal contact between wall and medium for the calculation. The computation data are calculated on the base of WWER-1000 thermohydraulic model by the RELAP5/MOD3 codes. This model was developed jointly by the Bulgarian and BNL/USA staff to provide an analytical tool for performing safety analysis. As a result of calculations by codes the computation data for temperature field law (linear laws of a few distinguished parts) and pressure of coolant at points on inner surface of WWER-1000 primary circuit equipment are received. Such calculations can be used as a base for determination of all-important load-carrying sections of the primary circuit pipes and vessels, which need further ...
IMRT with inverse planning allows simultaneous integrated boost strategies that exploit the heterogeneous dose distribution within the planning target volumes (PTVs). In this scenario, the location of cold spots within the target becomes a crucial issue and has to be related to the distribution of the clonogenic cell density (CCD). The main aim of this work is to provide the means to calculate the optimal prescription dose in a relative inhomogeneous dose distribution. To achieve this, the prescription dose has to be assigned to obtain the same tumor control probability (TCP) as the ideal homogeneous distribution, taking into account different CCDs in different PTVs (i.e. visible and subclinical regions). An adapted formulation of the linear-quadratic model, within the F-factor formalism, has been derived to preserve a chosen TCP value for the whole target volume. The F-factor has been investigated to show its potential applications in clinical practice.
Accurate dose calculation in radiation treatment planning is most important for successful treatment. Since human body is composed of various materials and not an ideal shape, it is not easy to calculate the accurate effective dose in the patients. Many methods have been proposed to solve inhomogeneity and surface contour problems. Monte Carlo simulations are regarded as the most accurate method, but it is not appropriate for routine planning because it takes so much time. Pencil beam kernel based convolution/superposition methods were also proposed to correct those effects. Nowadays, many commercial treatment planning systems have adopted this algorithm as a dose calculation engine. The purpose of this study is to verify the accuracy of the dose calculated from pencil beam kernel based treatment planning system comparing to Monte Carlo simulations and measurements especially in inhomogeneous region. Home-made inhomogeneous phantom, Helax-TMS ver. 6.0 and Monte ...
The complete complementary code (CCC) is a sequence family with ideal correlation sums which was proposed by Suehiro and Hatori. Numerous literatures show its applications to direct-spread code-division multiple access (DS-CDMA) systems for inter-channel interference (ICI)-free communication with improved spectral efficiency. In this paper, we propose a systematic framework for the construction of CCCs based on $N$-shift cross-orthogonal sequence families ($N$-CO-SFs). We show theoretical bounds on the size of $N$-CO-SFs and CCCs, and give a set of four algorithms for their generation and extension. The algorithms are optimal in the sense that the size of resulted sequence families achieves theoretical bounds and, with the algorithms, we can construct an optimal CCC consisting of sequences whose lengths are not only almost arbitrary but even variable between sequence families. We also discuss the family size, alphabet size, and lengths of constructible CCCs based ...
Diffuse {gamma}-ray emission produced by the interaction of cosmic-ray particles with matter and radiation in the Galaxy can be used to probe the distribution of cosmic rays and their sources in different regions of the Galaxy. With its large field of view and long observation time, the Milagro Gamma Ray Observatory is an ideal instrument for surveying large regions of the Northern Hemisphere sky and for detecting diffuse {gamma}-ray emission at very high energies. Here, the spatial distribution and the flux of the diffuse {gamma}-ray emission in the TeV energy range with a median energy of 15 TeV for Galactic longitudes between 30{sup o} and 110{sup o} and between 136{sup o} and 216{sup o} and for Galactic latitudes between -10{sup o} and 10{sup o} are determined. The measured fluxes are consistent with predictions of the GALPROP model everywhere except for the Cygnus region (l {element_of} [65{sup o}, 85{sup o}]). For the Cygnus region, the flux is twice the ...
A novel compact CT-guided intensity modulated proton radiotherapy (IMPT) system is described. The system is being designed to deliver fast IMPT so that larger target volumes and motion management can be accomplished. The system will be ideal for large and complex target volumes in young patients. The basis of the design is the dielectric wall accelerator (DWA) system being developed at the Lawrence Livermore National Laboratory (LLNL). The DWA uses fast switched high voltage transmission lines to generate pulsed electric fields on the inside of a high gradient insulating (HGI) acceleration tube. High electric field gradients are achieved by the use of alternating insulators and conductors and short pulse times. The system will produce individual pulses that can be varied in intensity, energy and spot width. The IMPT planning system will optimize delivery characteristics. The system will be capable of being sited in a conventional linac vault and provide intensity ...
By means of a global mode analysis of ideal MHD modes for Mercier-unstable equilibria in a planar axis L=2/M=10 heliotron/torsatron system with an inherently large Shafranov shift, the conjecture from local mode analysis for Mercier-unstable equilibria given in [N. Nakajima, Phys. Plasmas 3, 4556 (1996)] has been confirmed and the properties of pressure-driven modes, namely, ballooning modes and interchange modes, inherent to such three-dimensional systems have been clarified. The change of the local magnetic shear due to the Shafranov shift, which is related to toroidicity, reduces the field line bending stabilizing effects on ballooning modes. According to the degree of the reduction of the local magnetic shear by the Shafranov shift, the Mercier-unstable equilibria are categorized into toroidicity-dominant (strong reduction) and helicity-dominant (weak reduction) Mercier-unstable equilibria. Since the local magnetic curvature due to helicity has the same period ...
Information about surface soil moisture conditions is of critical importance to real-world applications such as agricultural production, water resource management, flood prediction, fire prediction, water supply, military mobility, etc.. Near-surface soil moisture is currently available from non-ideal sensor configuration observations, and two missions targeted at measuring near-surface soil moisture with ideal sensor configuration are expected before the end of the decade (the European Space Agency (ESA), Soil Moisture and Ocean Salinity (SMOS) mission, and the National Aeronautics and Space Administration (NASA), Hydrospheric states "Hydros" mission). Though remote sensing can make spatially comprehensive measurements of surface soil moisture, it cannot provide information on the entire land surface hydrologic system, and the measurements represent only a snap shot in time. Alternatively, land surface hydrology process models may be used to ...
Turkey's natural gas (NG) production is very small and is almost all imported. Turkish natural gas production in 2000, 23 billion cubic feet (Bcf), met around 4% of domestic natural gas consumption requirements. NG consumption is estimated at around 700 Bcf in year 2002, accounting for around 17% of Turkey's total energy consumption. Turkish natural gas demand had been projected to increase extremely rapidly in coming years. Country oil production is 50,674 barrels per day (bbl/d) of which 46,674 bbl/d was crude oil in 2002. In 2002, oil consumption was 635,000 bbl/d and net oil imports was 584,326 bbl/d in Turkey. Oil provides around 43% of Turkey's total energy requirements. (Author)
This article describes how a natural gas-fired combined cycle with increased firing temperature, reduced cooling air usage, improved component efficiencies, and cycle enhancements could achieve a lower heating value plant efficiency of greater than 60%. Today's gas turbine systems feature high fuel-to-electricity efficiencies. Efficiencies, on a lower-heating-value (LHV) basis, for large natural gas-fired combined-cycle systems for the utility market have been demonstrated at 54%. Even though manufacturers will make improvements in the 1990s, efficiency levels will reach a plateau. Cycle innovations and gas turbine design changes will achieve LHV efficiencies in the 60% range for natural gas-fired utility machines.
A new process for the removal of tar from biosyngas, OLGA (Oil and Gas Washer), is presented. This gas cleaning technology is based on physical principles and is designed to eliminate tar problems that relate to fouling and er pollution. The applied principles are confirmed by experimental validation. OLGA can be operated without suffering from harmful effects on important gasification characteristics as cold gas efficiency, gasifier simplicity, and feedstock flexibility. Some fundamental considerations in the development of OLGA are discussed. Amongst these is a different approach to the tar problem. This approach does not consider the total tar content as decisive in the evaluation of gas cleaning equipment. Instead, evaluation is focussed on whether tar properties as condensation behaviour and water solubility can still occur. A biosyngas free of tar should therefore be synonymous to a biosyngas that ...
Gas separation membranes with polydimethylsiloxane(PDMS)/polystyrene(PS) were prepared by using the sequential interpenetrating polymer network (IPN) method with various PS contents (10?70wt%). These gas separation membranes can be applied to reduce the smoke density in the emission gas of diesel engines. PS content has a pronounced effect on the membrane performance. It was found that the optimized PS contents in the final membrane were 50wt%. The emission capacities of diesel engines used in this study were 632 cc and 11,149 cc. When the oxygen separation membrane was used in the diesel engines, the smoke density of both diesel engines was remarkably reduced (35?73%). The oxygen concentration in the inlet air affects the composition of the emission gases. Especially, hydrocarbon (HC) dec...
Thailand's demand for gas will outstrip supplies in the late 1990s as rapid economic growth continues. Gas will be a cornerstone for Thai energy policy throughout the growth, although sources in neighboring countries need development. Thai gas production will rise 25% from 1992 to average 1 bcfd by 1995. Including production from new discoveries, production could rise to 1.5 bcfd by 2000, up almost 90% from the 1992 level. Increased gas flow output in the mid-1990s will be due largely to development of Gulf of Thailand fields. By 1998, production from Gulf of Thailand fields will not be enough to offset the decline in today's fields. Thailand will need to import more than 1 bcfd by 2005 in the absence of future discoveries in the country. The paper discusses new pipelines and imports.
The ElectroStatic Precipitator (ESP) removes dust and tar droplets very efficiently from biomass product gas. Dust was removed for more than 99%. The tar dewpoint was reduced from 130C to 21C, which is sufficient for the application of the product gas in a gas engine. Tar removal is not sensitive to the voltage or fluctuations in the gas residence time . The voltage was varied between 28 to 37 kV{sub arith} and the gas residence time between 4 and 11s. Fouling of the ESP collector plates was negligible, which was concluded from visual inspection after 200 hours of operation. A reduction in the residence time reduces the size of the ESP and has a significant impact on the investment costs of the ESP. Keywords: electrostatic filter, tar removal, circulating fluidised bed (CFB)
The authors report the fabrication and characterization of a low temperature (200--400 C) thin film gas sensor constructed from a MOCVD-grown yttria-stabilized zirconia (YSZ) layer sandwiched between two platinum thin film electrodes. A reproducible gas-sensing response is produced by applying a cyclic voltage which generates voltammograms with gas-specific current peaks and shapes. Growth conditions are optimized for preparing YSZ films having dense microstructures, low leakage currents, and maximum ion conductivities. In particular, the effect of growth temperature on film morphology and texture is discussed and related to the electrical and gas-sensing properties of the thin film sensor device.
A survey was undertaken of literature on the conversion of coke-fired cupola furnaces so that they can be fuelled, either wholly or partially, with natural gas. The aim was to determine the most suitable method for a specific furnace. Substitution with natural gas can result in speedier adjustment and control of the smelting process and in addition operational costs are reduced as natural gas is a cheaper fuel. The payback period would be one year. Pollutive emissions would be reduced. It was concluded that the most satisfactory solution would be that 3-4 gas burners should be placed immediately above the smelting zone in the furnace. Each burner should be placed in a separate combustion box in which the complete combustion process could take place. The burners should be placed symmetrically about the furnace, pointing at a small degree downwards. In this way the combustion chamber will not be filled ...
In this paper, the authors investigate the technical and economical aspects of the natural gas injection in non-integrated pig-iron plants using charcoal in the blast furnace. The effects of the natural gas injection concerning the blast furnace flame temperature, charcoal consumption, productively and permeability are analyzed. It was found that the injection is beneficial in many ways, such as in the improvement of the productivity and quality, if the flame temperature is kept within an appropriate range. In the financial-economic project`s evaluation, the cash flow for the natural gas injection was analysed considering two blast conditions: through the drying and oxygen enrichment of the air. A sensibility analysis is presented in which the internal rate of return of the investment varies according to the prices of charcoal and oxygen. 3 refs., 3 figs., 3 tabs
The majority of Brazilian big cities served by conventional railroad systems with routes starting in the center of the URBIS, destinate them the long distances transport of passengers and cargo. Actually, these systems are being transformed to become commuter trains which join a great capacity of transportation to a much lower costs of implantation than subway ones. The most important characteristic of this train, when talking about energy consumption, is the possibility of using different kinds of explosion engines from three cycles: Diesel, mixed (Diesel + Natural Gas), and Otto moved by natural gas, besides the traditional electric traction. The use of natural gas in Otto cycle engines shows itself competitive from the point of view of investments, operational costs and environmental preservation. (author). 10 refs., 1 fig
Lean premixed combustion (LPC) of natural gas is of considerable interest in land-based gas turbines for power generation. However, modeling such combustors and adequately addressing the concerns of LPC, which include emissions of nitrogen oxides, carbon monoxide and unburned hydrocarbons, remains a significant challenge. In this paper, characteristics of published simulations of gas turbine combustion are summarised and methods of modeling turbulent combustion are reviewed. The velocity-composition PDF method is selected for implementation in a new comprehensive model that uses an unstructured-grid flow solver. Reduced mechanisms for methane combustion are evaluated in a partially stirred reactor model. Comprehensive model predictions of swirl-stabilised LPC of natural gas are compared with detailed measurements obtained in a laboratory-scale combustor. The model is also applied to industrial combustor ...
Remote, offshore gas reserves have long been a challenging deepwater petroleum resource to tap. Natural gas in many offshore regions is plentiful, but lacks access to the market because of the logistical challenges and costs. Most large offshore gas discoveries are capped, and gas associated with oil production is re-injected into the reservoir or is flared. A more attractive option is to convert the gas into a liquid product on a floating production, storage, and offloading (FPSO) vessel. However, some conventional process technologies are not well suited for operation on floating vessels that are highly space and weight constrained and may challenge vessel stability during inclement weather. Microchannel process technology units under development offer intensified processes that are suit...
In this paper it will be discussed how to most effectively give room to competitive forces in natural gas markets, given the traditional merchant pipeline as point of departure. Alternative models of organizing the market will be reviewed: we first consider decreasing barriers to entry and then analyse advantages and drawbacks of a third party access system. In this context different forms of implementing a competitive market for transportation capacity and coordinating it with gas trade are discussed, among them a simultaneous auction of gas and transmission capacity. Finally a hub system of point markets will be suggested to improve the currently implemented third party access system and to allow for competitive markets for gas and transportation service. 33 refs., 6 figs.
The Gas Research Institute established the Gas Appliance Technology Center (GATC) in 1982 to develop improved gas appliances. Between 1986 and 1992, the scope of GATC activities at Battelle included technology transfer and overall industry support, residential appliances, commercial appliances, and residential space conditioning. The following tasks are representative of the GATC activities described in the report; gas burner technology, appliance venting, emissions, water heating, range/oven technology, self-powered appliances, commercial cooktop burners, reconstituting ovens, appliance reliability improvement, combination space-heating/water-heating systems, condensing heat exchangers, corrosion testing, and space heating technology. The report includes references to available sources for further reading.
One of the unsolved problems of the natural gas dual fuel engine is that there is too much exhaust of Total Hydrogen Carbon(THC) at a low equivalent mixture ratio. To fix it, a natural gas mixed with hydrogen was applied to engine test. The results showed that the higher the mixture ratio of hydrogen to natural gas, the higher the combustion efficiency. And when the amount of the intake air is reached to 90% of WOT, the combustion efficiency was promoted. But, like a case making the injection timing earlier, the equivalent mixture ratio for the nocking limit decreases and the produce of NOx increases. 5 refs., 9 figs., 1 tab.
AISI 5140 steel was plasma nitrided at various gas mixtures of nitrogen, hydrogen, and argon to investigate the actions of hydrogen and argon on plasma nitriding. The structural and mechanical properties of ion-nitrided AISI 5140 steel have been assessed by evaluating composition of phases, surface hardness, compound layer thickness, and case depth by using X-ray diffraction (XRD), microhardness tests, and scanning electron microscopy (SEM). It was found that the growth of compound layer can be controlled and the diffusion improved when the gas mixture includes H_2 gas. Additionally, it was determined that the amount of Ar in dual gas mixture must be at 20% minimum to obtain distinctive surface hardness and compound layer thickness.
Laboratory tests have been done to assess the feasibility of using microwaves to manufacture refractory liner boards as used in the steel industry. Results show that microwaves cured and dried the product about ten times faster than the conventional gas-oven process. The quality of boards dried with microwaves appears to be as good or better than of those dried with gas. The potential for fast, energy-optimized drying in a small space has been demonstrated. Economically, the energy-cost of using microwaves is comparable to using gas when drying the last 30% moisture content, that is, for about the last 50% of the present gas-drying time. For higher moisture contents, such as encountered in the early stages of drying, the energy can be supplied at a lower cost by gas. 8 figs.
In energy industries, it is always of difficulty to produce high heat value(HHV) gas continuously using pulverized coal. In this paper, a new type furnace for partitioned alternative gasification using pulverized coal is developed, in which the oxidation and reduction reaction occur alternatively with the dropping of pulverized coal and finally HHV gas could be continuously obtained at the reduction zone exit and low heat value(LHV) gas at the oxidation zone exit. Furthermore, the gasification characteristics and their factors in furnace are numerically simulated under two dimensional model with a self-coded program, based on heat, mass and energy transfer as well as reaction principles. It is found that the producing rate of HHV gas is 1.10Nm3/kg with heat value of 11.72MJ/Nm3, however, t...
Various theories and examples of modelling, forecasting and optimization designing in the different parts of the petroleum and gas industries are presented, stochastic programming for long term planning in the refining industry, stochastic model for gasoline blending, feedstock optimization, location and sizing for offshore platforms, hydrocarbon exploration simulation rapid method, valuation of oil field development leases, economic models for petroleum allocation, models for oil supply market, trade embargo game theory, stochastic programming of gas contract portfolio management, scheduling transportation of oil and gas, strategic planning in an oil pipeline company, simulation of offshore oil terminal systems, hierarchical selection of oil and gas distribution systems.
The method is related to hydrodynamic methods for studying wells and may be used in the prospecting and mapping of gas and gas condensate deposits and formations. The method consits of drilling exploratory wells and measurement of the physical parameters of the stratum liquid. The piezometric levels are periodically determined simultaneously in all the observation wells during a change in the atmospheric pressure, and the presence of a remoteness of the gas deposit from the well is judged from the size of the increments in the piezometric levels intime. The determinations of the piezometric levels in the wells are conducted during an abrupt change in atmospheric pressure, for instance, during the replacement of a cyclone by an anticyclone or the reverse. The atmospheric pressure is measured by a barograph, while the piezometric levels are measured by high precision level meters or pressure gauges of low pressure. The method ...
The purpose of this project was to build a long-range, parallel hybrid gas/electric vehicle capable of driving beyond the communter capabilities of series hybrid vehicles. It was envisioned that since the gas engine would be able to independently propel the car when needed and that the electric motor would be capable of doing the same, then you have a very desirable situation where this car can operate much more cheaply on electricity for the short distance runs under approximately 60 miles and also be able to propel the vehicle via the gas engine on the long-distance trips. During the time the car would be operating in the gas engine mode, it would be also recharging the 16 deep cycle batteries via the electric motor now being used as a generator. Then, even on long-distance trips, the electric motor could be used, after having been fully or partially recharged, to even further reduce cost per mile.
Ordos Basin, the second largest sedimentary basin in China, contains enormous natural gas resources. Each of the four giant gas fields discovered so far in this basin (i.e., Sulige, Yulin, Wushenqi and Jingbian) has over 100 billion cubic meters (bcm) or 3.53 trillion cubic feet (tcf) of proven gas reserves. This study examines the stable carbon isotope data of 125 gas samples collected from the four giant gas fields in the Ordos Basin. Source rocks in the Upper Paleozoic coal measures are suggested by the generally high {delta}{sup 13}C values of C{sub 2}-C{sub 4} gaseous hydrocarbons in the gases from the Sulige, Yulin and Wushenqi gas fields. The {delta}{sup 13}C values of methane, benzene and toluene in gases from the Lower Paleozoic reservoirs of the Jingbian field indicate a significant contribution from humic source rocks, as they are similar to those in ...
The productivity characteristics of perforated gas well are investigated for the first time under real conditions considering drilling damage, perforation compacted zone and anisotropy in this paper. A non-linear finite element model for non-Darcy flow in perforated gas reservoir is built to consider the effects of twelve factors on productivity ratio (PR) of perforated gas well. The nomographs for two cases are presented in this paper. Compared with previous works, the following results are found: (1) the effects of drilling damage and perforation diameter on PR of gas well are more remarkable than that in oil well; (2) any perforation phase may be the best or the worst as to perforating gas well, which depends on anisotropy, drawdown and that whether or not perforations are beyond drilling damage zone; (3) the increase in perforation length hardly improve PR of ...
Puffer gas circuit breaker used widely in interrupters with from middle capacity to large capacity does not keep away from reacting force of the puffer with high functions in principle and there is a limit in low operation. In this study, aiming at low operation of the interrupters, in order to clarify the basic motions of hybrid circuit interrupter that is the combination of thermal puffer gas circuit breaker and vacuum circuit breaker, the interrupting ability of simple thermal puffer gas breaker and the voltage sharing characteristics in the cases of series connection with the vacuum circuit breaker are studied. The results of the study are as follows. In comparing terminal short circuit accident interrupting ability of single flow typed thermal puffer gas breaker with that of double flow typed thermal puffer gas breaker, the interrupting ability of the double flow typed thermal ...
Electricity generation from natural gas in gas turbine units can be made substantially more efficient by preliminary methane conversion to a synthesis gas containing hydrogen and carbon monoxide and/or by the use of some of the synthesis gas produced in industry. An alternative improvement involves the introduction of solid oxide fuel cells (SOFCs) and the use of the synthesis gas in them. In this study, a modified scheme of gas turbine cycle that includes an SOFC, a membrane reactor (instead of a traditional combustion chamber), and a catalytic reactor to perform methane conversion to produce hydrogen (synthesis gas) is proposed. Variations of the energy and exergy efficiencies of the integrated system with operating conditions are provided, showing, for example, that SOFC efficiency is enhanced if the fuel cell active area is augmented. ...
The following industrial-scale power station processes are compared with natural gas/light fuel oil heating: Conventional steam generation, steam generation with gas turbine upstream, gas turbine process with low-pressure-waste heat boiler and cogeneration. Industrial gas turbines between 10 and 25 MW are compared with one another; typical boilers and industrial turbines are described. CO{sub 2} and NO{sub x} emissions are indicated. The steam turbines used are the efficient and robust turbines used in industry, wherever possible they are built as single-line plant with the gas turbine. (orig.) [Deutsch] Es werden folgende Industriekraftwerksprozesse mit Erdgas-Leichtoelfeuerung verglichen: Konventioneller Dampfprozess, Dampfprozess mit Vorschaltgasturbine, Gasturbinenprozess mit ND-Abhitzekessel und Kombianlage. Die Industriegasturbinen zwischen 10 und 25 MW werden ...
In order to establish the optimum fueling in a natural gas fueled dual fuel engine, tests were made for some operational parameters and their combination on the engine performances and the exhaust emissions. The results show that the gas oil quantity should be increased and gas oil injection timing should be advanced to suppress unburned hydrocarbon emission at middle and low output range, while the quantity should be reduced and the timing should be retarded to avoid onset of knock at high loads. The unburned hydrocarbon emission and the thermal efficiency are improved at the same load avoiding too lean natural gas premixture by restriction of intake charge air. However the improvement is limited because the ignition and initial combustion of pilot diesel fuel is deteriorated when the cylinder pressure is excessively lowered by throttling. The increase in pilot gas oil amount is ...
This dissertation concerns a study of the utilization of sorghum biomass as the fuel for a methane production system. The objective of this research is to determine an optimal sorghum-methane production system based on anaerobic batch digestion technology. The system is described as the interaction of three components: estimation of available biomass, storage of biomass, and the gas production. Levelized costs are obtained for each component. The biomass supply is assumed to decay exponentially in quality with storage time. The gas production process is a batch type of digestion with an exponential production rate. Gas production is formulated for a fixed planning horizon (one year) as a function of the number of batches and the batch residence times. The cost equation is then described as a function of these gas production equations and their levelized costs. The structure of this resulting equation is ...
The energy recovery scheme at Mucking Marshes landfill site, operated by Cory Environmental Limited, has been in operation since October 1991. Using landfill gas abstracted from the site, a gas turbine generates up to 3.2 MW net electric power for export. Operation and performance of the scheme has been monitored over the period January 1995 to August 1996. Overall performance since the first use of the turbine has also been studied, and has shown reliable and profitable operation. The capital cost of the gas turbine and gas compressor plant was approximately 1.8 million. Actual gas collection wells, pipework, pumping and monitoring facilities, while essential to the scheme, are considered part of the gas control equipment needed for the landfill site. Based on a notional electricity selling price of 4p/kWh, the current annual income from exported power is ...
In response to the Clean Coal II solicitation, Bethlehem Steel Corporation (BSC) submitted a proposal to the DOE in May 1988. The proposal submitted by BSC describes a Unique integration of commercial technologies developed by Davy/Still Otto to clean coke oven gas being produced at its Sparrows Point, Maryland steel plant. This innovative coke oven gas cleaning system combines secondary gas cooling with hydrogen sulfide and ammonia removal, hydrogen sulfide and ammonia recovery, ammonia destruction and sulfur recovery to produce a cleaner fuel gas for plant use. The primary environmental benefit associated with employing this innovative coke oven gas cleaning system is realized when the fuel gas is burned within the steel plant. Emissions of sulfur dioxide are reduced by more than 60 percent. The removal, recovery and destruction of ammonia eliminates the ...
In our previous work, we demonstrated that biomass-generated producer gas can be converted to ethanol and acetic acid using a microbial catalyst Clostridium carboxidivorans P7{sup T}. Results showed that the producer gas (1) induced cell dormancy, (2) inhibited H{sub 2} consumption, and (3) affected the acetic acid/ethanol product distribution. Results of this work showed that tars were the likely cause of cell dormancy and product redistribution and that the addition of a 0.025{mu}m filter in the gas cleanup negated the effects of tars. C. carboxidivorans P7{sup T} can adapt to the tars (i.e. grow) only after prolonged exposure. Nitric oxide, present in the producer gas at 150ppm, is an inhibitor of the hydrogenase enzyme involved in H{sub 2} consumption. We conclude that significant conditioning of the producer gas will be required for the successful coupling of biomass-generated ...
Gas Distribution Companies have long paid great attention to improving the quality of gas supply service to the consumer. This has involved them in an on-going attempt to successfully define and establish a clear computer assisted replacement programme which, when drawn up on a reliability basis, may also prove cost effective. The reasons which drive any gas line replacement programme are mainly related to the necessity: to improve the gas network asset so as to face a striking expected growth in gas demand; to refurbish old distribution systems with the purpose not only to increase the reliability and continuity of gas supply but also to reduce the rate of maintenance costs due to frequent repair works; to prevent the possibility of massive replacement works for a progressing ageing of the network. This paper will present the computer assisted procedure being ...
This contribution presents different approaches for the modeling of gas entrainment under water by a plunging jet. Since the generation of bubbles happens on a scale which is smaller than the bubbles, this process cannot be resolved in meso-scale simulations, which include the full length of the jet and its environment. This is why the gas entrainment has to be modeled in meso-scale simulations. In the frame of a Euler-Euler simulation, the local morphology of the phases has to be considered in the drag model. For example, the gas is a continuous phase above the water level but bubbly below the water level. Various drag models are tested and their influence on the gas void fraction below the water level is discussed. The algebraic interface area density (AIAD) model applies a drag coefficient for bubbles and a different drag coefficient for the free surface. If the AIAD model is used for the simulation ...
The overall goal of the Gas-to-Liquids Program at the U.S. Department of Energy`s Pittsburgh Energy Technology Center (PETC) is to develop technologies for the production of hydrocarbon fuels and premium chemicals from light alkane gases. PETC`s current Gas-to-Liquids Program comprises the development of four primary advanced conversion technologies, namely, partial oxidation, oxidative coupling, oxyhydrochlorination, and novel conversion processes. Based on the current state of development, it can be concluded that, in the near future, one or more of these technologies will reach proof-of-concept demonstration. Oxyhydrochlorination is the most advanced direct conversion technology, and the synthesis of lower cost methyl chloride from natural gas would impact several commercial technologies that utilize methyl chloride as an intermediate to high value products. Technology development for the partial oxidation of methane to ...