International Nuclear Information System (INIS)

Radionuclide x-ray fluorescence analysis was used for the determination of Y, Ba and Cu in thin high-temperature superconducting films. Atomic emission ICP spectrometry was used to estimate the precision and accuracy of analytical results. Reasonable agreement between both methods was obtained when a polynomial calibration curve was applied. (author) 4 refs.; 4 tabs.

International Nuclear Information System (INIS)

Samples of air-dust-concentration- and air-dust-deposit measurements were digested by a standardized wet digestion procedure and the amounts of substances in the dust according to class I TA Luft by Atomic Emission Spectroscopy with Inductively Coupled Plasma (AES-ICP). The characteristic values for procedures according to VDI 2449, sheet 1, were determined for lead, vanadium, cadmium, chromium, copper, nickel and zinc. By partial automatic control of the digestion procedure the personel expenditure of work could be reduced by a factor 13. Dust filter samples were analysed without sample preparation by evaporating the material with a solid state laser. The absolute detection limit was between 1 and 100 ng/cm"2 for the elements arsenic, cadmium, cobalt, chromium, mercury, antimony, selen and thallium. For sampling by means of the Beta-Staubmeter the relative detection limits for the laser-ICP were ...

International Nuclear Information System (INIS)

Fine ceramic particles of zirconia toughened alumina (ZTA), titania toughened alumina (TTA), and zirconia-titania toughened alumina (ZTTA) have been synthesized by ultrasonic spray pyrolysis (USP) at various temperatures from starting salt solutions of various compositions aiming for the development of catalytic material. These particles were characterized for properties such as shape, size and size distribution, diffraction pattern, and chemical and phase composition of elements by scanning electron microscopy (SEM), particle size analyzer (PSA), x-ray diffraction (XRD), and inductively coupled plasma-atomic emission spectroscopy (ICP-AES). Chemical compositions and sizes of ceramic composites have been controlled by the stoichiometry of salt solutions and the flow rate of spraying solutions. The optimum experimental conditions for the various composite particle synthesis have been proposed.

Energy Technology Data Exchange (ETDEWEB)

This study presents a rapid and selective method for the recovery of lanthanides and yttrium, existing in economically interesting concentrations, from red mud, the byproduct of the alumina production. The leaching process is based on the extraction of these elements with diluted nitric acid from red mud under moderate conditions and without using any preliminary treatment. Several parameters such as leaching agents, contact time, temperature, pressure and solid to liquid ratio were investigated in order to achieve an optimum recovery. The process followed here was selected taking into account its efficiency for the selective recovery of yttrium and lanthanides, but also its suitability for the subsequent liquid-liquid extraction of the leaching solution for the separation of the individual lanthanides. The achieved recovery percentages were for Y about 90%, for the investigated heavy lanthanides (Dy, Er, Yb) up to 70%, for the middle ones (Nd, Sm, Eu, Gd) up to 50% and for the group ...

International Nuclear Information System (INIS)

In the present paper the contamination levels of trace and toxic metals in drinking water collected from Tarapur industrial area, Thane were investigated. The concentrations of trace and toxic metals (Pb, Cd, Cu, Cr, Ni, Se, V, Zn, Mn, Mo, Co, As and Ba) were determined simultaneously using Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES). The results were compared with international water quality guidelines (WHO, 2008) and were found within the permissible limits. The quality assurance was checked by standard addition method and spike recovery. The concentration of Pb, Cd, Cu, Cr, Ni, Se, V, Zn, Mn, Mo, Co, As and Ba varies from 4.25-19.62 #mu#g/L, 0.13-1.49 #mu#g/L, 0.60-65.55 #mu#g/L, 0.46-4.15 #mu#g/L, <0.1 #mu#g/L, 0.5- 9.35 #mu#g/L, <0.5 #mu#g/L, 3.41-99.64 #mu#g/L, 0.80-9.62 #mu#g/L, 0.30-1.48 #mu#g/L, <0.1-0.90 #mu#g/L, <0.63 #mu#g/L and 0.71-9.0 #mu#g/L respectively. Similarly Na, K, Ca ...

International Nuclear Information System (INIS)

A newly synthesized glycine derivative (termed GlyD), 2-(4-(dimethylamino)benzylamino)acetic acid hydrochloride, was used to inhibit uniform and pitting corrosion processes of Al in 0.50 M KSCN solutions (pH 6.8) at 25 "oC. For uniform corrosion inhibition study, Tafel extrapolation, linear polarization resistance and impedance methods were used, complemented with SEM examinations. An independent method of chemical analysis, namely ICP-AES (inductively coupled plasma atomic emission spectrometry) was also used to test validity of corrosion rate measured by Tafel extrapolation method. GlyD inhibited uniform corrosion, even at low concentrations, reaching a value of inhibition efficiency up to 97% at a concentration of 5 x 10"-"3 M. Results obtained from the different corrosion evaluation techniques were in good agreement. This new synthesized glycine derivative was also used to control pit nucleation and growth on the pitted ...

Science.gov (United States)

Spontaneous radiation by an atom in a Rydberg state is inhibited by use of parallel conducting planes to eliminate the vacuum modes at the transition frequency. Spontaneous radiation emission is observed to turn off abruptly at the cutoff frequency of the waveguidelike structure, and the natural lifetime is measured to increase by a factor of at least 20.

International Nuclear Information System (INIS)

Two plasma chemistries, i.e., CH_4/H_2/Ar and Cl_2/Ar, were compared for the etching of InGaP, AlInP, and AlGaP under inductively coupled plasma (ICP) conditions. While the etching with CH_4/H_2/Ar discharges appears to be ion driven, Cl_2/Ar discharges showed an additional strong chemical enhancement. The highest etch rate (#approx#1 #mu#m/min) for InGaP was achieved at high ICP source power (#>=#750 W) with the Cl_2/Ar chemistry. Cl_2/Ar discharges provided very smooth surfaces in all three materials with root-mean-square roughness measured by atomic force microscopy around 2 nm. This result may be due to the efficient ion-assisted product desorption in this chemistry. The etched near-surface region of InGaP (#approx#100 Angstrom) with Cl_2/Ar maintained almost the same stoichiometry as that of the unetched control. By contrast, the CH_4/H_2/Ar plasma chemistry produced somewhat rougher surfaces and depletion of ...

International Nuclear Information System (INIS)

The total radiation rate, angular distribution of the emitted energy and photon correlations of the cooperative spontaneous radiation from two atoms with different resonance frequencies and spontaneous decay rates are calculated. Contrary to the case of two identical atoms oscillations appear in the total radiation rate and the spatial distribution of the total number of emitted photons differs from the single-atom radiation pattern. The effect of the dipole-dipole near-field interaction on the time evolution of the atomic system is discussed. (author).

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

CERN Document Server

Atomic pioneers

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

International Nuclear Information System (INIS)

Atomic ensembles, comprising clouds of atoms addressed by laser fields, provide an attractive system for both the storage of quantum information and the coherent conversion of quantum information between atomic and optical degrees of freedom. We describe a scheme for full-scale quantum computing with atomic ensembles, in which qubits are encoded in symmetric collective excitations of many atoms. We consider the most important sources of error-imperfect exciton-photon coupling and photon losses-and demonstrate that the scheme is extremely robust against these processes: the required photon emission and collection efficiency threshold is #approx#>86%. Our scheme uses similar methods to those already demonstrated experimentally in the context of quantum repeater schemes and yet has information processing capabilities far beyond those proposals.

Science.gov (United States)

We investigate the features of the spontaneous emission spectra in a coherently driven cold five-level atomic system by means of a radio frequency (rf) or microwave field driving a hyperfine transition within the ground state. It is shown that a few interesting phenomena such as spectral-line narrowing, spectral-line enhancement, spectral-line suppression, and spontaneous emission quenching can be realized by modulating the frequency and intensity of the rf-driving field in our system. In the dressed-state picture of the coupling and rf-driving fields, we find that this coherently driven atomic system has three close-lying levels so that multiple spontaneously generated coherence (SGC) arises. Our considered atomic model can be found in real atoms, such as rubidium or sodium, so a corresponding experiment can be done to observe the expected phenomena related to ...

International Nuclear Information System (INIS)

In Nuclear Magnetic Resonance (NMR) imaging, contrast is dependent on the emission of radiofrequency waves by atomic nuclei, balanced by several parameters. The high information content of NMR images is due to the multiplicity of its parameters. However, this advantage introduces a difficulty in the interpretation of the contrast. There are three contrast parameters for each tissue: hydrogen nuclei density; relaxation time T1; relaxation time T2. Contrast may be enhanced towards any of these parameters by increasing the emission of radiowaves by atomic nuclei using particular pulse sequences.

International Nuclear Information System (INIS)

In this work, the principal continuum radiative emission processes, which occur during the penetration of ions in solids or gases, are resumed. The characteristics of the following processes are discussed: secondary electron bremsstrahlung (SEB), atomic bremsstrahlung (AB), and internuclear bremsstrahlung (INB). Recent advances of the ion channeling effects in crystal solids on the spontaneous radiative spectra are exposed. (A.C.A.S.).

CERN Document Server

We derive the expression for spontaneous emission rate in finite one-dimensional photonic crystal with arbitrary defects using the effective resonator model to describe electromagnetic field distributions in the structure. We obtain explicit formulas for contributions of different types of modes, i.e. radiation, substrate and guided modes. Formal calculations are illustrated with a few numerical examples, which demonstrate that the application of effective resonator model simplifies interpretation of results.

Energy Technology Data Exchange (ETDEWEB)

The multielement determination of major-to-ultratrace elements in salmon egg was carried out by ICP-AES and ICP-MS. First, salmon eggs (30 eggs used) were digested with conc. nitric acid and 60% perchloric acid by heating almost to dryness repeatedly. Finally, the residues of salmon eggs were dissolved in 1 M nitric acid and the sample solutions were analyzed by ICP-AES and ICP-MS. About 40 elements could be determined over the concentration range in 9 orders of magnitude. The concentrations of bio-essential elements, such as Zn, Fe, and Cu, in salmon egg were 10-100 times higher than those in human blood serum. In addition, the major-to-ultratrace elements in cell cytoplasm and cell membrane were separately determined in a similar manner to those in whole egg cell. The concentrations of most bio-essential elements were higher in cell cytoplasm than in cell membrane, while those of Fe and Cu were higher ...

UK PubMed Central (United Kingdom)

Experience gained with a wide variety of missile injuries of the brain is presented. Clinical signs and intracranial pressure (ICP) studied in the early post-injury period have been correlated with...Full Text Available

International Nuclear Information System (INIS)

The possibilities of using both selective heavy ion induced X-ray emission and secondary ion mass spectroscopy (SIMS), for the identification of impurities present at low concentrations in cadmium telluride are examined. The relative concentrations of the impurities along CdTe crystals have been determined by exciting the X-ray emission of the elements in several slices with Ar and Kr ions and by comparing the relative characteristic X-ray emission yields. As a consequence of the quasimolecular inner shell ionization mechanism in heavy ion-atom collisions, Ar and Kr ions allow a strong excitation of the main impurities seen by SIMS namely Si, Cl and Ge, As, with only a minor contribution of Cd and Te. From the changes of the concentrations of the various impurities along the crystal, informations about segregation coefficients and compensation can be obtained.

British Library Electronic Table of Contents (United Kingdom)

We have studied the nature of continuum emitted in the visible spectral range from a noncontracted positive column of discharge in a cesium vapor-xenon mixture at a pressure of 45 Torr and at a degree of ionization below 3 ? 10?6. The main contribution to the continuous emission under such conditions is due to electron-xenon atom bremsstrahlung. The intensity of emission has been experimentally and theoretically studied as a function of the electric field strength and electron density in the positive column. It is established that an increase in the visible emission intensity with the electric field strength is related to an increase in the number of hot electrons in plasma.

CERN Document Server

We study the stability of the circular orbits of the electromagnetic two-body problem of classical electrodynamics. We introduce the concept of resonant dissipation, i.e. a motion that radiates the center-of-mass energy while the interparticle distance performs bounded oscillations about a metastable orbit. The stability mechanism is established by the existence of a quartic resonant constant generated by the stiff eigenvalues of the linear stability problem. This constant bounds the particles together during the radiative recoil. The condition of resonant dissipation predicts angular momenta for the metastable orbits in reasonable agreement with the Bohr atom. The principal result is that the emission lines agree with the predictions of quantum electrodynamics (QED) with 1 percent average error even up to the $40^{th}$ line. Our angular momenta depend logarithmically on the mass of the heavy body, such that the deuterium and the muonium ...

Science.gov (United States)

We describe the synthesis of metal-chelating polymers (MCPs) with four different pendant polyaminocarboxylate ligands (EDTA, DTPA, TTHA, DOTA) and an orthogonal end-group, either a fluorescein molecule or a bismaleimide linker for antibody attachment. Polymer characterization by a combination of (1)H NMR, UV/vis absorption measurements, and thermal gravimetric analysis (TGA) indicated that each chain of the fluorescein-terminated polymers contained one dye molecule. These polymer samples were loaded with three different types of lanthanide ions as well as palladium and platinum ions. The numbers of metal atoms per chain were determined by a combination of UV/vis and conventional ICP-MS measurements. The experiments with lanthanide ions demonstrated that a net anionic charge on the polymer is important for water solubility. These experiments also showed that at least one type of lanthanide ion (La(3+)) is capable of forming a bimetallic complex ...

Energy Technology Data Exchange (ETDEWEB)

Determination, uptake and distribution of various ions such as alkali metals in three different parts (leaf, stem and root) and seeds of radish (Kaiware daikon) were examined using flame emission spectrometry and ICP-AES. In order to examine the influence of concentration alkali metal ion concentration in the radish culture solution on the uptake and distribution of these metals, the radish was grown at pH 5.6 in solutions containing alkali metal chloride at concentrations ranging from 10{sup -5} to 10{sup -1} mol dm{sup -3}. When the radish were grown in culture solution with alkali metal ions of low concentrations (10{sup -5} and 10{sup -4} mol dm{sup -3}), Na, K, Rb and trace Li were detected in leaves, stems and roots while Cs was scarcely detected. However, the contents of Na, K, Li in these organs were the same as those in radish cultivated in pure water. An increase of Rb uptake was observed with an increased Rb concentration. In the ...

International Nuclear Information System (INIS)

Radionuclide X-ray fluorescence and particle induced X-ray emission methods were used for a rapid and nondestructive analysis of metallic glasses. The methods are compared in accuracy and precision with the atomic absorption method. Some results of analyses of Fe_xNi_8_0_-_xB_2_0 materials are briefly reviewed. The distribution of elements along the width and length, and a qualitative analysis of the composition of material surfaces are considered. (author) 3 refs.

International Nuclear Information System (INIS)

Uranium-aluminum alloys with a significant enrichment of uranium with "2"3"3U or "2"3"5U serve as nuclear fuels in research reactors. The quality assurance of this fuel requires, among other things, precise knowledge that all trace metal constituents that affect neutron economy, fuel integrity, and fuel fabrication process parameters are well within the specification limits. Trace metal characterization of "2"3"5U-Al alloy has been carried out by atomic spectrometry. The trace metal constituents of interest are grouped into common metals (silver, boron, calcium, cadmium, cobalt, chromium, copper, iron, magnesium, manganese, molybdenum, sodium, nickel, lead, silicon, tin, titanium, vanadium, tungsten, and zinc) and lanthanides (cerium, dysprosium, europium, gadolinium, holminium, lutetium, samarium, and terbium). The elements yttrium and zirconium are grouped with the latter in view of the chemical separation procedure used. The alloy samples are dissolved in 6 M ...

Energy Technology Data Exchange (ETDEWEB)

A new method for the determination of {sup 237}Np and Pu isotopes in large soil samples has been developed that provides enhanced uranium removal to facilitate assay by inductively coupled plasma mass spectrometry (ICP-MS). This method allows rapid preconcentration and separation of plutonium and neptunium in large soil samples for the measurement of {sup 237}Np and Pu isotopes by ICP-MS. {sup 238}U can interfere with {sup 239}Pu measurement by ICP-MS as {sup 238}UH{sup +} mass overlap and {sup 237}Np via {sup 238}U peak tailing. The method provides enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then transferring Pu to DGA resin for additional purification. The decontamination factor for removal of uranium from plutonium for this method is greater than 1 x 10{sup 6}. Alpha spectrometry can also be applied so that the shorter-lived {sup 238}Pu isotope can be measured successfully. {sup 239}Pu, ...

Energy Technology Data Exchange (ETDEWEB)

Fuel cell vehicles have been identified as the personal transportation technology of the future because of their high efficiency and very low emissions. To achieve the goal of road-ready fuel cell vehicles, great strides must be made in the development of fuel cells, hydrogen production and hydrogen storage technologies, that includes metal-H interaction studies and safety considerations. The interaction between two-hydrogen atoms and a {gamma}-Fe structure containing a vacancy has been studied using a cluster model and a theoretical method. For the study of the sequential absorption, the hydrogen atoms were positioned in their energy minima configurations, near the vacancy. The interactions mainly involve Fe 4s-H 1s atomic orbitals. The contribution of Fe 4p and Fe 3d orbitals is much less important. The Fe-Fe bond is weakened as new Fe-H-H and H-H pairs were formed. The effect of H ...

International Nuclear Information System (INIS)

Modern radiometric analytics demands a complex consideration of nuclear and electron shell processes, if more pretentious aims are envisaged. As an example the small variation of decay rates of radionuclides presents possibilities for information on chemical situations of decaying atoms. In principle this phenomenon is well known since many years, but now the situation is such that, e.g. in /sup 99m/Tc internal conversion, a full agreement of the difficult experiments and the respective theory was established. The secondary emission of X-rays as a consequence of high excitation of electron shells in combination with nuclear transitions supplies another example for a methodical progress of radiometry. Investigations on "5"1Cr as an electron capture nuclide have shown that chemically induced variations of the K/sub #alpha#/ to K/sub #beta#/ X-ray intensity ratio is at least qualitatively understood. (author).

International Nuclear Information System (INIS)

Much theoretical and experimental efforts have been expended in recent years to study those atomic processes which are specially relevant to understanding high temperature laboratory plasmas. For magnetically confined fusion plasmas, the temperature range of interest spans from the hundreds of eV at plasma edges to 10 keV at the center of the plasma, where most of the impurity ions are nearly fully ionized. These highly stripped ions interact strongly with electrons in the plasma, leading to further excitation and ionization of the ions, as well as electron capture. Radiations are emitted during these processes, which easily escape to plasma container walls, thus cooling the plasma. One of the dominant modes of radiation emission has been identified with dielectronic recombination. This paper reviews this work.

British Library Electronic Table of Contents (United Kingdom)

To diversify the mix of domestic energy resources and to reduce dependence on imported oil, ethanol is widely investigated for applying in combination with Diesel fuel to reduce pollutants, including smoke and NOx. Present work aims at developing a fumigation system for introduction of ethanol in a small capacity Diesel engine and to determine its effects on emission. Fumigation was achieved by using a constant volume carburetor. Different percentages of ethanol fumes with air were then introduced in the Diesel engine, under various load conditions. Ethanol is an oxygenated fuel and lead to smooth and efficient combustion. Atomization of ethanol also results in lower combustion temperature. During the present study, gaseous emission has been found to be decreasing with ethanol fumigation. ...

International Nuclear Information System (INIS)

The possibility of the group preconcentration of Zr(4), Hf(4), Nb(5), and Ta(5) countercurrent liquid chromatography using extraction systems based on di-2-ethylhexylphosphoric acid N-benzoyl-N-phenylhydroxylamine, and tetraoctylethylenediamine (TOEDA) is studied. A method have been proposed for the group extraction of Zr(4), Hf(4), Nb(5), and Ta(5) from solution of geological samples. At the stage of the preconcentration of Zr(40, Hf(4), Nb(5) and Ta(5) with a 0.1 M solution of TOEDA in chloroform from mixture of oxalic (0.01 M) and hydrochloric (0.1 M) acids, matrix components are eluted with a flow of the mobile phase, Then, upon changing the eluent (2.0 M HCl), the four elements mentioned above are extracted to a small (7-8 mL) eluate fraction. The results of determining Zr, Hf, Nb, and Ta by inductively coupled plasma atomic emission spectrometry in the international standard reference material Granite GM after their preconcentration in ...

International Nuclear Information System (INIS)

By the linear augmented plane wave method (APW) the energy zone of silver and technetium structure is calculated. The potential has been determined by means of superposition of atomic charge densities according to slater exchange method. Total and partial state densities have been calculated by the tetrahedron method. The APW-method convergence on the example of silver is studied, the comparison with the calculation results by the APW method and other data is carried out. The APW method high efficiency is pointed out. In dipole approximation the intensity distribution in L"3, M"5 N"3 technetium emission spectra is calculated.

Energy Technology Data Exchange (ETDEWEB)

The necessary conditions to design the methanol-fueled direct injection diesel engine with a reservoir type glow plug were cleared up from the points of view to prevent the air contamination and to use as an alternative oil for automotives, and as a result the good engine performance and emission characteristics could be obtained under the wide operating condition. The following facts were clarified: It is necessary to arrange the glow plug on the line of atomizing axis near the nozzle hole to ensure the ignitability under a wide operating condition. The reservoir type glow plug which reserves the premixed gas around the glow plug can shorten the ignition delay time and improve the combustion stability and the net thermal efficiency in the light load region. The combustion in the light load region was accelerated, NO{sub x} emission rate was suppressed and moreover, the net thermal efficiency and catalyst conversion rate ...

International Nuclear Information System (INIS)

A method was developed for the determination of plutonium in the soil samples by ICP-MS with TOA extraction chromatographic column. The optimized sample loading rate is below 0.2 mL/min (column inner diameter is 3.5 mm). Using hot 0.02 mol/L oxalic acid (H_2C_2O_4) in 0.16 mol/L HNO_3 to elute Pu from the solid phase in the column. The Pu recovery of 87.3%-96.8% in soil samples was obtained. The plutonium is separated with the ion exchange method in this work. Both extraction chroma- tography and ion-exchange methods efficiently remove the uranium and matrix interference from the ICP- MS measurement. The instrumental detection limit for "2"3"9Pu was 0.48 pg/mL, which corresponds to 1, 1 mBq/mL. (authors)

International Nuclear Information System (INIS)

Some magnetron sputtering systems experience rapid oscillations in the current and voltage of the plasma discharge after several hours when equipped with certain targets. These oscillations often lead to the plasma becoming extinguished, a condition known as ''flame-out.'' This article details the study of two 90% W--10% Ti magnetron targets which differed in density. The higher density targets sometimes experienced flame-out after approximately 3 h of sputtering. The less dense material could be sputtered for the entire 15 h life of the target. Scanning electron microscopy pictures and atomic composition depth profiles were obtained using Auger electron spectroscopy. In addition, a Colutron-based ion source with a high vacuum system was used to measure ion-induced secondary electron emission coefficients as a function of energy, ion specie, and gas coverage. Analysis of the sample from the group that suffers flame-out showed large regions of ...

Energy Technology Data Exchange (ETDEWEB)

A new method that allows rapid preconcentration and separation of plutonium and neptunium in water samples was developed for the measurement of {sup 237}Np and Pu isotopes by inductively-coupled plasma mass spectrometry (ICP-MS) and alpha spectrometry; a hybrid approach. {sup 238}U can interfere with {sup 239}Pu measurement by ICP-MS as {sup 238}UH{sup +} mass overlap and {sup 237}Np via peak tailing. The method provide enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then moving Pu to DGA resin for additional removal of uranium. The decontamination factor for uranium from Pu is almost 100,000 and the decontamination factor for U from Np is greater than 10,000. This method uses stacked extraction chromatography cartridges and vacuum box technology to facilitate rapid separations. Preconcentration is performed using a streamlined calcium phosphate precipitation method. Purified solutions are split between ...

Energy Technology Data Exchange (ETDEWEB)

The enhancement of positive secondary ion yields of silicon due to the presence of oxygen has been investigated quantitatively by low-energy (5 keV) oxygen implantation. Implantation and sputter profiling with 9 keV In/sup +/ were performed in the same ion microprobe instrument. Depth profiles of substrate and implanted oxygen atoms were measured for fluences ranging from 5x10/sup 15/ to 4x10/sup 16/ O-atoms/cm/sup 2/. The oxygen concentration, c(O), in the sample was deduced from the implanted fluence and the range distribution in the Gaussian approximation. It was found that the oxygen-enhanced Si/sup +/ intensity is proportional to c(O)sup(x) (with x=1.4) in the concentration regime, 1.5<=c(O)<=30 at%. The O/sup +/ intensity shows a similar dependence for c(O)> or approx.20 at.%.

International Nuclear Information System (INIS)

We present an atomistic simulation of the Ostwald ripening of extrinsic defects (clusters, #left brace#1 1 3#right brace#s and dislocation loops) which occurs during annealing of ion implanted silicon. The model describes the capture and emission of Si interstitial atoms to and from extrinsic defects of sizes up to thousands of atoms and includes a loss term due to the flux of interstitials to the recombining surface. Key input parameters of the simulation are the variations of the formation energy and of the capture efficiency with the size of the different defects. This model shows that the kinetics of the well-known dissolution of #left brace#1 1 3#right brace# defects is only driven by the recombination efficiency at the surface and the distance from the defects to the sample surface. We have subsequently used this model to study defect evolution in low and ultra low energy (ULE) B implanted Si during annealing. Defect ...

International Nuclear Information System (INIS)

The dependence of the photoluminescent properties of In_0_._4_8(Al_yGa_1_-_y)_0_._5_2P alloys (0#<=#y#<=#0.5) on growth temperature and substrate misorientation off GaAs(100) has been studied. Samples were grown using low-pressure metalorganic vapor phase epitaxy. By studying the dependence of ordering behavior in InGaP as a function of substrate misorientation and growth temperature simultaneously, a very large range in low-temperature photoluminescence emission energy---135 meV---has been obtained. The photoluminescence linewidth exhibits a strong, continuous dependence on the extent of atomic ordering (the emission energy) in the alloys. The results indicate that inhomogeneity in the microstructure of the material (i.e., between ''ordered'' domains and the ''disordered'' matrix) is the dominant photoluminescence broadening mechanism. This investigation has allowed a significant optimization of the optical ...

International Nuclear Information System (INIS)

Radionuclides exhibiting in decaying a strong interaction between nucleus and electron shell (especially electron capture and internal conversion) are, in principle, sensitive to their chemical surroundings. Consequently, they can be used to yield chemical information after an appropriate labelling procedure. The information can be extracted from the decay rate variation as well as from their X-ray emission as a response to an inner-shell vacancy creation during nuclear deexcitation. As an example of the former method the relationship between the decay rate of /sup 99m/Tc and the chemical structures of pertechnetate and bis(meso-dimercapto-succinate)oxotechnetate(V) is considered. Lower expectations with respect to measuring techniques are associated with the observation of X-ray emission. For a number of elements (especially 3d transition elements) the K/sub #alpha#//K/sub #betta#/ X-ray intensity ratio was found to be an indicator of the ...

International Nuclear Information System (INIS)

Selective formation of ZnO nanodots was accomplished by metalorganic chemical vapor deposition on nanopatterned SiO_2/Si substrates. Self-organized ZnO nanodots were selectively formed in nanopatterned lines of Si created by etching of SiO_2 with focused ion beam (FIB), whereas any nanodots were hardly observed on the SiO_2 surface in the vicinity of the FIB-sputtered Si areas. The mechanism of the selective formation of ZnO nanodots on FIB-nanopatterned lines is mainly attributed to the effective migration of Zn adatoms diffusing on the SiO_2 surface into the Si lines followed by the nucleation at surface atomic steps and kinks created by Ga"+ ion sputtering. Cathodoluminescence measurements confirmed that the emission originated from the selectively grown ZnO nanodots.

International Nuclear Information System (INIS)

Thick targets of several heavy lanthanide (Ho-Lu) compounds were bombarded by protons and "3He ions of 3 MeV/amu, and M_#alpha# and M_#beta# X-rays were measured with a crystal spectrometer. Ionization probabilities of the N-shell for zero impact parameter were obtained from the X-ray intensity ratio for proton and "3He ion impacts. A shell dependence of the ionization probability was found in a scaling plot. X-ray spectra of lanthanide compounds were compared and no chemical effect was observed. This result is considered to be due to the fact that the main component of M_#alpha# and M_#beta# lines is for radiative transition after the refilling of the 4f orbit (3d"-"14f"n"+"1 #-># 4f"n) where n denotes the number of 4f electrons of the target atom before ionization. (orig.).

International Nuclear Information System (INIS)

Nowadays, diamond and the nitrogen-vacancy (NV) colour centres constitute the best solid-state system in view of quantum-computing applications. It has also been shown recently that single NV centres could be used as nanoscale magnetic sensors. Such applications require the creation of single NV centres with very high resolution and with a high efficiency. The nano-implanter at the university of Bochum provides low energy nitrogen ions which can be implanted through a hole pierced in the tip of an atomic force microscope. Ultrapure diamond samples have been implanted with spot sizes of 50nm and less. Stimulated Emission Depletion (STED) microscopy has been used to characterise and resolve the implanted spots.

Science.gov (United States)

... 4 Joint Committee on Atomic Energy as a Model . . . . . ... Joint Committee on Atomic Energy as a Model ...

International Nuclear Information System (INIS)

First-principles self-consistent band-structure calculations of potassium titanyl arsenate, KTiOAsO_4 (KTA), have been made using the full potential linearized augmented plane wave (FP-LAPW) method. Total and partial densities of states of the constituent atoms of KTA have been derived. The results obtained show that the valence band of KTA is dominated by contributions of the O 2p-like states, while the Ti 3d-like states are the main contributors into the conduction band of the compound. Additionally, the FP-LAPW calculations have revealed that potassium atoms are highly ionized in KTA. In the present work, the X-ray emission spectroscopy (XES) and X-ray photoelectron spectroscopy (XPS) methods were also employed to investigate experimentally the electronic structure of potassium titanyl arsenate. For the mentioned compound, the XES K Ll, Ti L#alpha#, As K#beta#_2 and O K#alpha# bands reflecting the valence K s-, Ti s,d-, ...

Energy Technology Data Exchange (ETDEWEB)

We present a collisional-radiative approach of the theoretical analysis of laser-induced breakdown spectroscopy (LIBS) plasmas. This model, which relies on an optimized effective potential atomic structure code, was used to simulate a pure aluminum plasma. The description of aluminum involved a set of 220 atomic levels representative of three different stages of ionization (Al{sup 0}, Al{sup +} and Al{sup ++}). The calculations were carried for stationary plasmas, with input parameters (n{sub e} and T{sub e}) ranging respectively between 10{sup 13-18} cm{sup -3} and 0.3-2 eV. A comparison of our atomic data with some existing databases is made. The code was mainly developed to address the validity of the local thermodynamic equilibrium (LTE) assumption. For usual LIBS plasma parameters, we did not reveal a sizeable discrepancy of the radiative equilibrium of the plasma towards LTE. For cases where LTE was firmly believed to ...

International Nuclear Information System (INIS)

A series of crown ethers carrying a pyrene group with nitrogen-sulfur donor atoms, that differ in having three, four and five sulfur atoms in the macrocycle was designed and synthesized by the reaction of the corresponding macrocyclic compound and 1-bromomethylpyrene. The influence of metal cations such as Mn2+, Fe2+, Fe3+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+, Pb2+ and Al3+ on the spectroscopic properties of the ligands was investigated in acetonitrile-dichloromethane (1:1) by means of absorption and emission spectrometry. Absorption spectra show isosbestic points in the spectrophotometric titration of Fe2+, Zn2+, Cu2+, Pb2+ and Hg2+. The results of spectrophotometric titration experiments disclosed the complexation compositions and complex stability constants of the novel ligands with Fe2+, Zn2+, Cu2+, Pb2+ and Hg2+ cations. The monoazatetrathia crown ether showed good sensitivity for Cu2+ with linearity in the range ...

Energy Technology Data Exchange (ETDEWEB)

This document is the final report for Cooperative Agreement DE-FC26-04NT42314, 'Kinetics Study of Mercury Reactions in FGD Liquors'. The project was co-funded by the U.S. DOE National Energy Technology Laboratory and EPRI. The objective of the project has been to determine the mechanisms and kinetics of the aqueous reactions of mercury absorbed by wet flue gas desulfurization (FGD) systems, and develop a kinetics model to predict mercury reactions in wet FGD systems. The model may be used to determine optimum wet FGD design and operating conditions to maximize mercury capture in wet FGD systems. Initially, a series of bench-top, liquid-phase reactor tests were conducted and mercury species concentrations were measured by UV/visible light spectroscopy to determine reactant and byproduct concentrations over time. Other measurement methods, such as atomic absorption, were used to measure concentrations of vapor-phase elemental mercury, that cannot be ...

Energy Technology Data Exchange (ETDEWEB)

Since living things began their activities on the earth, the extermination of living things in large number on global scale occurred twice 230 million years ago (P-Tr boundary) and 65 million years ago (K-T boundary). As to the cause of exterminating living things in short period, there are volcano eruption theory, meteorite collision theory and so on, but still it is not decided. Therefore, as to the strata of P-Tr boundary in south-western part of China where it has been known the preservation of P-Tr strata is especially good, the existence of elements was measured by instrument neutron activation analysis and ICP-MS, and the state of change was examined. According to the results, the change occurred at the P-Tr boundary on the earth, and further, the possibility of meteorite collision by paying attention to Ir were examined. The samples, the neutron activation analysis, the ICP-MS and the results are reported. The distinction by strata and ...

Energy Technology Data Exchange (ETDEWEB)

In nuclear fuel, in approximately one quarter of the fissions, one of the two formed fission products is gaseous. These are mainly the noble gases xenon and krypton with isotopes of xenon contributing up to 90% of the product gases. These noble fission gases do not combine with other species, and have a low solubility in the normally used uranium oxide matrix. They can be dissolved in the fuel matrix or precipitate in nanometer-sized bubbles within the fuel grain, in micrometer-sized bubbles at the grain boundaries, and a fraction also precipitates in fuel pores, coming from fuel fabrication. A fraction of the gas can also be released into the plenum of the fuel rod. With increasing fission, and therefore burn-up, the ceramic fuel material experiences a transformation of its structure in the 'cooler' rim region of the fuel. A subdivision occurs of the original fuel grains of few microns size into thousands of small grains of sub-micron sizes. Additionally, larger ...

Science.gov (United States)

Deforestation in Mato Grosso, Brazil. atom_author. atom_name, Jesse Allen. atom_link. kml_href, http://earthobservatory.nasa.gov/Feeds/GoogleEarth/ ...

Science.gov (United States)

Oxidative stress is demonstrated to be involved in the pathophysiological mechanism of erectile dysfunction (ED). Quercetin, a potent bioflavonoid, has been reported to have the antioxidant role. In the present study, we examined the effect of quercetin on ED and oxidative stress in streptozotocin (STZ)-induced diabetic rats. Diabetes was induced in Sprague-Dawley rats with a single intravenous injection of STZ. The diabetic rats were then randomized to diabetic group and quercetin therapy groups which were treated with quercetin at different doses of 5, 20 and 50mg/kg per day respectively. At the end of the 8th week, erectile function was assessed by measuring the rise in intracavernous pressure (ICP) following cavernous nerve electrostimulation. Superoxide dismutase (SOD) activity, thiobarbituric acid-reacting substance (TBARS) and nitrite and nitrate (NOx) levels were measured in cavernosum tissue. Endothelial NO synthase (eNOS) expression was determined using ...

Science.gov (United States)

... 3 Joint Committee on Atomic Energy as a Model . . . . . ... Joint Committee on Atomic Energy as a Model Page 8. CRS-4 ...

UK PubMed Central (United Kingdom)

Sources of industrial emissions of 1,3-butadiene are discussed both by process (production, consumers) and type (equipment leaks, point sources). Quantification of the emissions are presented, as reported...Full Text Available

International Nuclear Information System (INIS)

Very High Temperature gas cooled nuclear Reactor (VHTR), which was coupled with Sulfur-Iodine (SI) thermo-chemical cycle, has been selected for the Nuclear Hydrogen Development and Demonstration (NHDD) project in Korea Atomic Energy Research Institute. Among the various hydrogen production methods, Sulfur-Iodine (SI) thermo-chemical cycle is a good method as a massive hydrogen production without CO2 emission. In SI cycle, the sulfuric acid decomposition is one issue for the material corrosion on high temperature and pressure condition. For the simulation of the sulfuric acid decomposition, we designed a sulfuric acid loop with a small-scale gas loop which is simulated for the integrity and feasibility tests on a H2SO4 decomposition process. The primary objective of the loop is to validate the corrosion and the mechanical performances of a key component of the NHDD, Process Heat Exchanger (PHE). In this paper, we discussed the preliminary ...

Energy Technology Data Exchange (ETDEWEB)

Thick targets of several heavy lanthanide (Ho-Lu) compounds were bombarded by protons and /sup 3/He ions of 3 MeV/amu, and M/sub ..cap alpha../ and M/sub ..beta../ X-rays were measured with a crystal spectrometer. Ionization probabilities of the N-shell for zero impact parameter were obtained from the X-ray intensity ratio for proton and /sup 3/He ion impacts. A shell dependence of the ionization probability was found in a scaling plot. X-ray spectra of lanthanide compounds were compared and no chemical effect was observed. This result is considered to be due to the fact that the main component of M/sub ..cap alpha../ and M/sub ..beta../ lines is for radiative transition after the refilling of the 4f orbit (3d/sup -1/4f/sup n+1/ -> 4f/sup n/) where n denotes the number of 4f electrons of the target atom before ionization.

Energy Technology Data Exchange (ETDEWEB)

The crystal structure and the luminescence properties of a new carbonate, Na{sub 3}Eu(CO{sub 3}){sub 3}, are presented. Na{sub 3}Eu(CO{sub 3}){sub 3} is orthorhombic, acentric, Ama2, Z = 4; a = 9.942(2) {angstrom}, b = 11.024(3) {angstrom}, c = 7.147(2) {angstrom}; R = 0.019, R{sub w} = 0.051, 2374 unique reflections. The anionic subnetwork is built up from the stacking of {open_quotes}standing on edge{close_quotes} and {open_quotes}flat lying{close_quotes} carbonate layers into which Na{sup +} and Eu{sup 3+} ions are inserted. The symmetry of the EuO{sub 9} polyhedra is C{sub s}. The Eu{sup 3+} ions are inserted. The symmetry of the EuO{sub 9} polyhedra is C{sub s}. The Eu{sup 3+} luminescence technique confirms the presence of a unique low symmetry site for the rare earth atom. The electrostatic crystal field (cf) effects on the {sup 7}F multiplet are evaluated on the basis of the phenomenological cf theory. The simulation using C{sub 2v} symmetry for the rare ...

Energy Technology Data Exchange (ETDEWEB)

Gamma scanning measurements are used to determine the radioactive nuclides from an irradiated fuel rod in a hot cell which is a routine task in the Irradiated Materials Examination Facility (IMEF) of the Korea Atomic Energy Research Institute (KAERI), Total gamma spectra of radioactive nuclides and the atomic ratio of {sup 134}Cs to {sup 137}Cs in a few segments of a single fuel rod are measured by the present gamma scanning system. For the purpose of determining the radioactive nuclide's distribution in detail within a fuel rod quantitatively, we attempt to upgrade the present gamma scanning system in this paper, therefore, an investigation of the feasibility of the tomographic gamma scanning (TGS) technique, which is one of the promising nondestructive assay (NDA) methods is proposed. The TGS technique is an efficient method and it has an accurate precision for the characterization of several fuel parameters. In this paper, a ...

International Nuclear Information System (INIS)

Full text: The isotopic assay instrument under development at Pacific Northwest National Laboratory (PNNL) is capable of rapid prescreening to detect small and rare particles containing high concentrations of uranium in a heterogeneous sample. The isotopic measurement concept is based on laser vaporization of solid samples followed by sensitive isotope-specific detection using either uranium atomic fluorescence emission or uranium atomic absorbance. Both isotopes are measured concurrently, following a single ablation laser pulse using two external-cavity violet diode lasers. The simultaneous measurement of both isotopes enables the correlation of the fluorescence and absorbance signals on a shot-to-shot basis. This measurement approach demonstrated negligible channel crosstalk between isotopes. Scanning the heterogeneous samples provides high-resolution imagery of sample isotopic fluorescence and absorbance. Isotopically ...

Science.gov (United States)

The dependence of the photoluminescent properties of In{sub 0.48}(Al{sub {ital y}}Ga{sub 1{minus}{ital y}}){sub 0.52}P alloys (0{le}{ital y}{le}0.5) on growth temperature and substrate misorientation off GaAs(100) has been studied. Samples were grown using low-pressure metalorganic vapor phase epitaxy. By studying the dependence of ordering behavior in InGaP as a function of substrate misorientation and growth temperature simultaneously, a very large range in low-temperature photoluminescence emission energy---135 meV---has been obtained. The photoluminescence linewidth exhibits a strong, continuous dependence on the extent of atomic ordering (the emission energy) in the alloys. The results indicate that inhomogeneity in the microstructure of the material (i.e., between ordered'' domains and the disordered'' matrix) is the dominant photoluminescence broadening mechanism. This ...

International Nuclear Information System (INIS)

Iron is one of the main constituents of stainless steel which is used as a structural material in nuclear reactors. In fast and conceptual fusion and fusion-fission hybrid systems the primary energy range of neutron interaction lies between 1 and 20 MeV which opens up several reaction channels. The reaction cross-sections in this energy range are important for dosimetry, radiation damage, neutronics and safety studies of nuclear reactors. Keeping this in view Nuclear Data Section of the International Atomic Energy Agency has sponsored a Research Co-ordination Programme on Methods for the Calculation of Fast Neutron Nuclear Data for Structural Elements. Under this programme we propose to study (n,n'), (n,2n), (n,3n), (n,p), (n,np), (n,pn), (n,#alpha#), (n,n#alpha#), (n,#alpha#n) and (n,#gamma#) reaction cross-sections. Besides these, total, elastic and discrete level inelastic scattering cross-sections, angular distributions of neutron production cross-sections, ...

Energy Technology Data Exchange (ETDEWEB)

The Kyoto Protocol foresees emission trading but does not yet specify verification of (uncertain) emissions. This paper analyses a setting in which parties can meet their emission targets by reducing emissions, by investing in monitoring (reducing uncertainty of emissions) or by (bilaterally) trading permits. We derive the optimality conditions and carry out various numerical simulations. Our applications suggest that including uncertainty could increase compliance costs for the USA, Japan and the European Union. Central Europe and the Former Soviet Union might be able to gain from trading due to higher permit prices. Emissions trading could also lower aggregate uncertainty on emissions.

International Nuclear Information System (INIS)

Intensive work has long been going on to find out the unknown origin that sets off curious tribo-physicochemical phenomena and that causes various kinds of problems in oil-lubricated sliding contacts in mechanical and processing systems. The strange tribochemical reaction is one of the such curious chemical phenomena observed in the degradation of perfluoropolyether (PFPE) lubricating oil film in a hard disk drive. Plasma (triboplasma) (Nakayama and Mirza 2006 Tribol. Trans. 49 17) would be one of the most probable origins of the problems if it were generated sufficiently intensely in oil-lubricated sliding contacts, as it is in such a highly energetic state. The generation of plasma was predicted in both dry and oil-lubricated sliding (Nakayama 1997 Japan. J. Tribol. 42 1077, Nakayama 2004 Surf. Coat. Technol. 188-189 599). However, plasma generation in industrially important oil-lubricated contacts has not yet been proven, though it has been found in dry sliding (Nakayama and ...

Energy Technology Data Exchange (ETDEWEB)

To our knowledge, the fluorescence studies of lanthanides in LiCl-KCl eutectic molten salt at a high temperature are not reported yet. The fluorescence of the lanthanide-ions was generally decreased when the temperature was increased. Moreover, the fluorescence of the lanthanides was strong when the sample was solidified to or from the melt. The temperature, where the fluorescence was decreased, was identified to be different depending on the species of the lanthanides and the substrates was considered to possibly be from quenching of the fluorescence due to either the collisions of melted samples induced by high temperature media or the re-absorption of fluorescence by the samples. Several comparison experiments were performed to explain and understand this phenomenon and improve the fluorescence. In this way, an on-line monitoring of chemical species and the concentration for lanthanides elements in molten salt media of pyrochemical process can be accomplished, and it can replace the ...

International Nuclear Information System (INIS)

The paper describes novel analytical methods developed for the detection of previous neutron irradiation and reprocessing of illicit nuclear materials, which is an important characteristic of nuclear materials of unknown origin in nuclear forensics. Alpha spectrometry and inductively coupled plasma sector-field mass spectrometry (ICP-SFMS) using solution nebulization and direct, quasi-non-destructive laser ablation as sample introduction were applied for the measurement of trace-level "2"3"2U, "2"3"6U and plutonium isotopes deriving from previous neutron irradiation of uranium-containing nuclear materials. The measured radionuclides and isotope ratios give important information on the raw material used for fuel production and enable confirm the supposed provenance of illicit nuclear material.

Energy Technology Data Exchange (ETDEWEB)

Objective is to study the effects of local structure, interatomic forces, and atom size on the mobility of metal atoms in amorphous silica and at the silica surface. EXAFS studies of Zn and Pt in silica are reported. (DLC)

International Nuclear Information System (INIS)

Surface energy of III-V semiconductors ended by (110) clean surface and surface covered by atomic monolayer of aluminium, copper and sulfur has been calculated. We have used the Greens-function technique based on the scheme of linear muffin-tin orbitals in the atomic sphere approximation (LMTO-ASA) for the crystal potential and width the local density approximation (LDA) for electrons. Two types of coverage are considered: full monolayer with two additional atoms per two-dimensional unit cell and half monolayer with one additional atom per unit cell. Full monolayer of metallic atoms increases the surface energy. Cu atoms lead to greater destabilization than Al atoms. Sulfur atoms stabilize (110) surface for all considered compounds. (author)

Science.gov (United States)

We study a two-level atom in interaction with a real massless scalar quantum field in a spacetime with a reflecting boundary. The presence of the boundary modifies the quantum fluctuations of the scalar field, which in turn modifies the radiative properties of atoms. We calculate the rate of change of the mean atomic energy of the atom for both inertial motion and uniform acceleration. It is found that the modifications induced by the presence of a boundary make the spontaneous radiation rate of an excited inertial atom oscillate near the boundary and this oscillatory behavior may offer a possible opportunity for experimental tests for geometrical (boundary) effects in flat spacetime. While for accelerated atoms, the transitions from ground states to excited states are found to be possible even in a vacuum due to changes in the vacuum fluctuations induced by ...

International Nuclear Information System (INIS)

English Sep 2008 p. 56-57 International Atomic Energy Agency (IAEA)

Energy Technology Data Exchange (ETDEWEB)

The resulting emissions of the firing of ceramic products of all type are described, the factors are enumerated to diminish the emissions in the kilns and the technologies applied in the kilns to reduce these emissions while carrying out energy saving are described briefly. (author)

Energy Technology Data Exchange (ETDEWEB)

The potentiodynamic polarization measurement of 254SMO stainless steel (UNS 31254) was conducted in 3.5% NaCl solutions with pH ranging from 0.1 to 5. The results indicated that this stainless steel offered excellent pitting corrosion resistance in corrosive environments. Further, it also exhibited various features on the polarization curves in different pH solutions. The electrochemical constant-potential passivation treatment performed at different pH followed by XPS analysis revealed that the primary constituents of the outermost layer of the passive films formed in the weak (pH 5) and strong (pH 0.8) acid solutions are iron oxides and Cr{sub 2}O{sub 3} and Cr(OH){sub 3}, respectively. Molybdenum oxides, primarily in the six-valence state, existed in the outermost layer of the passive film. Only very weak signals corresponding to that of nickel oxides were detected in the film formed in the weak acid (pH 5) solution. The ICP-MS analyses indicated selective ...

Energy Technology Data Exchange (ETDEWEB)

Savannah River National Laboratory (SRNL) evaluated the previous monosodium titanate (MST) purchase specifications for particle size and strontium decontamination factor. Based on the measured particle size and filtration performance characteristics of several MST samples with simulated waste solutions and various filter membranes we recommend changing the particle size specification as follows. The recommended specification varies with the size and manufacturer of the filter membrane as shown below. We recommend that future batches of MST received at SRS be tested for particle size and filtration performance. This will increase the available database and provide increased confidence that particle size parameters are an accurate prediction of filtration performance. Testing demonstrated the feasibility of a non-radiochemical method for evaluating strontium removal performance of MST samples. Using this analytical methodology we recommend that the purchase specification include the ...

Science.gov (United States)

... Results of Source Emissions Testing UTC Fuel Cell Model PC25C ... Results of Source Emissions Testing: UTC Fuel Cell Model PC25C ...

International Nuclear Information System (INIS)

In this study, a regional dynamical model (WRF) is used to drive biogenic emission models to calculate high resolution (10 x 10 km) biogenic emissions of isoprene (C_5H_8), monoterpenes (C_1H_1_6), and nitric oxide (NO) in China. This high resolution biogenic inventory will be available for the community to study the effect of biogenic emissions on photochemical oxidants in China. The biogenic emissions are compared to anthropogenic emissions to gain insight on the potential impact of the biogenic emissions on tropospheric chemistry, especially ozone production in this region. The results show that the biogenic emissions in China exhibit strongly diurnal, seasonal, and spatial variations. The isoprenoid (including both isoprene and monoterpenes) emissions are closely correlated to tree density and strongly vary with ...

Science.gov (United States)

The thermodynamic characteristics of adsorption of sulfur-containing amino acids and their derivatives on the surface of graphitized thermal carbon black were calculated by the molecular statistical method. The parameters of the atom-atom potential function of intermolecular interaction between the S atom in amino acids and the graphite C atom were determined. It was shown that an intramolecular H-bond influenced the adsorption of amino acids on the surface of graphitized thermal carbon black.

Energy Technology Data Exchange (ETDEWEB)

I propose that an interpretation of the interaction of noble gas atoms with metal surfaces as predominantly physisorbing provides the best explanation for the systematics of their binding energies and surface dipoles, as well as for the tendency of noble gas atoms to bind in low coordinated sites. In the present context physisorption is defined as a process driven by the overlap of the electrostatic atomic potentials of the interacting species. (orig.)

British Library Electronic Table of Contents (United Kingdom)

Henry constants for the adsorption of o- and p-phenylenediamines on the surface of graphitized thermal carbon black within the temperature range 433?479 K were calculated by the molecular statistical method. The parameters of the atom-atom potential function of intermolecular interaction between the nitrogen atom in aniline and isomeric phenylenediamines and the carbon atom of the basal face of graphite were determined. It was shown that an intramolecular H bond influenced the geometry and adsorption properties of o-phenylenediamine.

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This two-volume reference uses many equations to provide detailed information on atomic and nuclear decay phenomena.

UK PubMed Central (United Kingdom)

A specific application of single photon emission tomography to the relative quantitation of the pituitary region is described together with the results obtained in 19 patients with pituitary adenoma...Full Text Available

Science.gov (United States)

activities, including the combustion of diesel fuel in heavy-duty vehicles and jet fuel in aircrafts. Current details on emissions from the transportation and other...

CERN Document Server

Searches for permanent electric-dipole moments (EDM) of atoms provide important constraints on competing extensions to the standard model of elementary particles. Recently proposed experiment with liquid $^{129}$Xe [M.V. Romalis and M.P. Ledbetter, Phys. Rev. Lett. \\textbf{87}, 067601 (2001)] may significantly improve present limits on the EDMs. To interpret experimental data in terms of CP-violating sources, one must relate measured atomic EDM to various model interactions via electronic-structure calculations. Here we study density dependence of atomic EDMs. The analysis is carried out in the framework of the cell model of the liquid coupled with relativistic atomic-structure calculations. We find that compared to an isolated atom, the EDM of an atom of liquid Xe is suppressed by about 40%.

British Library Electronic Table of Contents (United Kingdom)

Resonant scattering of atoms with formation of the Feshbach resonance in the presence of a laser radiation coupling the levels of two bound atoms (a molecule) is considered. The laser field leads to a second resonance in scattering and broadening of resonances, which facilitates the possibility of experimental observation of asymmetry of the total scattering cross-section arising because of interference between resonant and potential scatterings. The effects associated with interference of the two channels of decay of a bound system of two atoms (a molecule) in the laser field are studied. An expression is obtained for the scattering length in collision of two cold atoms in the field of laser radiation.

Energy Technology Data Exchange (ETDEWEB)

X-ray ablation of material from the first wall and other components of an ICF (Inertial Confinement Fusion) chamber is a major threat to the laser final optics. Material condensing on these optics after a shot may cause damage with subsequent laser shots. To ensure the successful operation of the ICF facility, removal rates must be predicted accurately. The goal for this dissertation is to develop an experimentally validated x-ray response model, with particular application to the National Ignition Facility (NIF). Accurate knowledge of the x-ray and debris emissions from ICF targets is a critical first step in the process of predicting the performance of the target chamber system. A number of 1-D numerical simulations of NIF targets have been run to characterize target output in terms of energy, angular distribution, spectrum, and pulse shape. Scaling of output characteristics with variations of both target yield and hohlraum wall thickness are also described. ...

Science.gov (United States)

Silver iron oxide nanoparticles of fairly small size (average diameter approximately 1 nm) with narrow size distribution have been synthesized by the interaction of colloidal beta- Fe2O3 and silver nanoparticles. The surface morphology and size of these particles have been analyzed by using atomic force microscopy (AFM), field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). Their structural analysis has been carried out by employing x-ray diffraction (XRD), selected-area electron diffraction (SAED), optical and infrared (IR) spectroscopic techniques. The ageing of these particles exhibits the formation of self-assembly, possibly involving weak supramolecular interactions between Ag(I)O4 and Fe(III)O4 species. These particles display the onset of absorption in the near-infrared region and have higher absorption coefficient in the visible range compared to that of its precursors. Magnetic measurements ...

Energy Technology Data Exchange (ETDEWEB)

The object and the purpose of the present work was to develop, to assemble and to start running a new TOF (time of flight) mass spectrometer for imaging SNMS analytic which is optimized for the analysis of highly molecular secondary ions. The most important purpose was the characterization of the TOF mass spectrometer. The obtained mass spectra of indium, tantalum and silver clusters reflect the excellent properties of the TOF mass spectrometer for the detection of large clusters with good detection efficiency up to masses of 16000 amu. The possibility of the deflection of selected saturated atom and cluster peaks serves for further improvement of the detection efficiency for large molecules. The accessible mass resolution was determined to be of the order of m/{delta}m=1000 in the high mass region. Numerous measurements were carried out to characterize the useful yield of this spectrometer. For a best possible adaptation of the TOF mass spectrometer for the ...

Energy Technology Data Exchange (ETDEWEB)

Proton induced X-ray and {gamma}-ray emission (PIXE/PIGE) have been used to analyze major and trace elements in a suite of 140 core samples from around of the Jim`s Find South gold anomaly in the Tanami desert, located in heavily weathered terrain. Simultaneous analyses were obtained for 30 elements, ranging in atomic number from {sup 3}Li to {sup 90}Th. The method was chosen because of its speed and the wide range of determination, its flexibility, precision and low detection limits. The regolith powder samples were treated by hot aqua regia before making them into pills. The PIXE/PIGE data of the acid insoluble residue give three factor analysis clusters. The first cluster comprises the elements F, Al, K, V, Mn, Fe, Ga, Rb, W and Au and is essentially related to sericitic wallrock alteration. The second cluster consists of Ti, As, Y, Zr, and Nb and is largely related to resistant minerals. The third cluster consists of Na, Ca and Sr and is ...

Science.gov (United States)

The relationship between the fluxes of the two strongest UV emission lines and flux in the continuum

Energy Technology Data Exchange (ETDEWEB)

An overview of emissive display technologies is presented. Display types briefly described include: cathode ray tubes (CRTs), field emission displays (FEDs), electroluminescent displays (ELDs), and plasma display panels (PDPs). The critical role of phosphors in further development of the latter three flat panel emissive display technologies is outlined. The need for stable, efficient red, green, and blue phosphors for RGB fall color displays is emphasized.

Energy Technology Data Exchange (ETDEWEB)

In this report is described the sources to nitrogen emission and how the emission have changed over time. The cost and effect of the proposals given by the Swedish Environmental Protection Agency to cope with the emission of nitrogen to the sea is also treated. A separate chapter describes what we know today about phosphorus and eutrophication Basic document to report SNV--4735. 25 figs, 11 tabs

KoreaScience (Korea)

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KoreaScience (Korea)

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Science.gov (United States)

... entitled: In-country Pilot Activities: Reducing Emissions from Deforestation and Degradation)...

Energy Technology Data Exchange (ETDEWEB)

This article analyses the role of energy intensity and the relationship between CO{sub 2} emissions and primary energy in order to explain the evolution of CO{sub 2} emissions by unit of real GDP. It also distinguishes two different meanings of CO{sub 2} emissions Kuznets curve hypothesis: the weak and the strong sense. It considers the case of Spain in the period 1972-1997 as an example in which there is not any evidence supporting this hypothesis in either sense. (author)

Energy Technology Data Exchange (ETDEWEB)

The CO{sub 2} emissions can be reduced by using economic instruments, like carbon tax. This project included two specific questions related to CO{sub 2} taxation. First one was the economic effects of increasing CO{sub 2} tax and decreasing other taxes. Second was the economic adjustment costs of reducing net emissions instead of gross emissions. A computable general equilibrium (CGE) model was used in this analysis. The study was taken place in Helsinki School of Economics

International Nuclear Information System (INIS)

Pollutant emissions due to fossil fuel and biomass energy utilization in Turkey have been estimated. Standard emission factors were used for estimating the levels of particulate matter, sulfur oxides, nitrogen oxides, carbon monoxide, volatile organic compounds, and aldehydes. The results are presented for different fuels and energy-consuming sectors for the reference year 1987. Total Turkish emissions vs energy consumption are presented for every fifth year since. 1960. (author).

Energy Technology Data Exchange (ETDEWEB)

Proposed features of the competitive electricity market in Ontario were reviewed. The speaker predicted that demand for renewable energy in Ontario`s competitive electricity market will be affected by green power, emissions trading, labelling, and renewables portfolio standard. Under current regulations retailers can charge customers a premium for purchasing electricity generated by `green` sources. The existing limits on emissions of sulphur dioxide, nitrogen oxides and carbon dioxides will remain in place, but an emissions cap and trading program for all Ontario-based generation is an option to consider. Ontario`s Market Design Committee (MDC) has recommended the implementation of emissions trading for electricity-related air pollutants for all generators located in Ontario. The complex mechanics of emission trading are explained. The MDC recommendation of the use of standard ...

CERN Document Server

The presented results are the first measurements at RHIC for direct $\\gamma$-charged hadron azimuthal correlations in heavy ion collisions. We use these correlations to study the color charge density of the medium through the medium-induced modification of high-p$_T$ parton fragmentation. Azimuthal correlations of direct photons at high transverse energy (8 $<$ p$_T$ $<$ 16 GeV) with away-side charged hadrons of transverse momentum (3 $<$ p$_T$ $<$ 6 GeV/c) have been measured over a broad range of centrality for $Au+Au$ collisions and $p+p$ collisions at $\\sqrt{s_{NN}}$ = 200 GeV in the STAR experiment. A transverse shower shape analysis in the STAR Barrel Electromagnetic Calorimeter Shower Maximum Detector is used to discriminate between the direct photons and photons from the decays of high p$_T$ $\\pi^{0}$. The per-trigger away-side yield of direct $\\gamma$ is smaller than from $\\pi^{0}$ trigger at the same centrality class. Within the current uncertainty the ...

Energy Technology Data Exchange (ETDEWEB)

Influence of residual K{sup +} on the preferential oxidation of CO in excess hydrogen (PROX) over CuO-CeO{sub 2} catalysts was investigated. CuO-CeO{sub 2} catalysts were characterized by BET, ICP, XRD, UV-Raman and TPR techniques. The results showed that the existence of residual K{sup +} made {alpha} peak in TPR of CuO-CeO{sub 2} catalysts shift to higher temperatures and depressed the PROX in the absence of CO{sub 2} and H{sub 2}O in the feed over CuO-CeO{sub 2} catalysts. However, small amount of residual K{sup +} was beneficial to the catalytic performance of CuO-CeO{sub 2} catalysts in the PROX in the presence of CO{sub 2} and H{sub 2}O in the feed. Consequently, residual K{sup +} with an appropriate content was beneficial to improve the catalytic performance of CuO-CeO{sub 2} catalysts in the presence of CO{sub 2} and H{sub 2}O. (author)

International Nuclear Information System (INIS)

Functionalizing nanoparticle surfaces is essential for achieving homogeneous dispersions of monodisperse particles in polymer nanocomposites for successful utilization in engineering applications. Functionalization reduces the surface energy of the nanoparticles, thereby limiting the tendency to agglomerate. Moreover, reactive groups on the surface can also participate in the polymerization, creating covalent bonds between the inorganic and organic phases. In this paper, a fluidized bed inductively coupled plasma (FB-ICP) reactor is used to break apart the agglomerates and functionalize commercial TiO2 nanoparticle powders in a batch of several grams. The fluidized bed could be implemented into a continuous flow reactor, potentially making this a viable method to treat larger quantities of commercial powders. The particles are treated with acrylic acid (AA) and tetraethylorthosilicate (TEOS) plasma and the functionalized particles were collected separately from ...

CERN Document Server

We study spontaneously generated entanglement (SGE) between two identical multilevel atoms in free space via vacuum-induced radiative coupling. We show that the SGE in two-atom systems may initially increase with time but eventually vanishes in the time scale determined by the excited state lifetime and radiative coupling strength between the two atoms. We demonstrate that a steady-state SGE can be established by incoherently pumping the excited states of the two-atom system. We have shown that an appropriate rate of incoherent pump can help producing optimal SGE. The multilevel systems offer us more chanel to establish entanglement. The system under consideration could be realized in a tight trap or atoms/ions doped in a solid substrate.

CERN Document Server

This contribution reviews a selection of findings on atomic density functions and discusses ways for reading chemical information from them. First an expression for the density function for atoms in the multi-configuration Hartree--Fock scheme is established. The spherical harmonic content of the density function and ways to restore the spherical symmetry in a general open-shell case are treated. The evaluation of the density function is illustrated in a few examples. In the second part of the paper, atomic density functions are analyzed using quantum similarity measures. The comparison of atomic density functions is shown to be useful to obtain physical and chemical information. Finally, concepts from information theory are introduced and adopted for the comparison of density functions. In particular, based on the Kullback--Leibler form, a functional is constructed that reveals the periodicity in ...

Energy Technology Data Exchange (ETDEWEB)

There is a need to reduce air pollutant emissions in some U.S. urban regions to meet federal and state air quality guidelines. Opportunities exist for reducing pollutant emissions from natural gas appliances in the residential sector. A cost-benefit analysis on various pollutant-reducing strategies is needed to evaluate these opportunities. The effectiveness of these pollutant-reducing strategies (e.g., low-emission burners, energy conservation) can then be ranked among themselves and compared with other pollutant-reducing strategies available for the region. A key step towards conducting a cost-benefit analysis is to collect information on pollutant emissions from existing residential natural gas appliances. An extensive literature search was conducted to collect data on residential natural-gas-appliance pollutant emission factors. The literature primarily describes laboratory ...

Energy Technology Data Exchange (ETDEWEB)

An atom-by-atom understanding of life processes is emerging from a flurry of experiments fueled by synchrotron sources and DNA technology. {copyright} 1995 {ital American} {ital Institute} {ital of} {ital Physics}.

Energy Technology Data Exchange (ETDEWEB)

At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is: (Zr,Hf).sub.a (Al,Zn).sub.b (Ti,Nb).sub.c (Cu.sub.x Fe.sub.y (Ni,Co).sub.z).sub.d wherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 ...

Energy Technology Data Exchange (ETDEWEB)

This report includes the issuances received during the specified period from the Commission (CLI), the Atomic Safety and Licensing Appeal Boards (ALAB), the Atomic Safety and Licensing Boards (LBP), the Administrative Law Judge (ALJ), the Directors' Decisions (DD), and the Denials of Petitions for Rulemaking (DPRM).

International Science & Technology Center (ISTC)

Investigation of Interaction of Laser Radiation with Radioactive Deposits on the metal Surface and Creation of Experimental Stand for Development of Laser Technology for Remote Treatment of Materials Contaminated with Radioactive Substances at the Atomic Power Plants

UK PubMed Central (United Kingdom)

The United Kingdom Atomic Energy Authority mortality study was designed to investigate the relation between exposure to ionising radiation and mortality among the authority's employees. The present...Full Text Available

International Nuclear Information System (INIS)

Full text: Thermoluminescence (TL) is a phenomenon of light emission caused by heating a pre-irradiated material. When ionizing radiation hits a TL material, electrons are freed from some atoms and moved in the material, leaving behind 'holes' of positive charge. Subsequently when the TL material is heated, the electrons and the 'holes' re-combine, and release the extra energy in the form of light. The light intensity can be measured, and related to the amount of energy initially absorbed through exposure to the ionizing radiation. In nineteen sixties thermoluminescence dosimeters (TLD) became popular for dosimetric applications in view of their small size, sensitivity and accuracy. Consequently, in early seventies, several countries started adopting of TLD for personnel monitoring. The idea of introducing TLD to replace the then prevalent film dosimeter for personnel monitoring in India was mooted and successfully implemented by Dr. K G Vohra. ...

DEFF Research Database (Denmark)

The objectives of this study were to characterize the changes of VOC material emission profiles over time and develop a method to account for such changes in order to enhance a source identification technique that is based on the measurements of mixed air samples and the emission signatures of individual building materials determined by PTRMS. Source models, including powerlaw model, doubleexponential decay model and mechanistic diffusion model, were employed to track the change of individual material emission signatures by PTRMS over a ninemonth period. Samples of nine typical building materials were tested individually for nine months and later in combination to obtain actual mixture emissions. VOC emissions from each material were measured in a 50liter smallscale chamber. Chamber air was sampled by PTRMS over a 28day period to determine their emission rate ...

Energy Technology Data Exchange (ETDEWEB)

This publication describes the modification of the road traffic exhaust emission calculation model LIISA and presents the new calculation results. The model has already established its position as the most important inventory tool for regional road traffic emissions in Finland. The LIISA model calculates road traffic emissions as a whole. The system comprises of three separate models: 1. a model for calculating automobile emissions for the years 2001-2021, 2. a model for calculating emissions backwards for the years 1980-2000, 3. a model for calculating the emissions of motorcycles and mopeds. All three parts have been modified. The LIISA model is one of the submodels of the comprehensive LIPASTO calculation system developed at VTT Building and Transport. The LIPASTO model is an inventory tool for emissions regarding all traffic modes in ...

International Nuclear Information System (INIS)

... thermal power plants thermal reactors water cooled reactors WATER

Energy Technology Data Exchange (ETDEWEB)

This patent describes a radioiodinated benzodiazepine derivative. It comprises a lower alkyl group with 1-4 C-atoms and a radioactive iodine.

International Nuclear Information System (INIS)

This publication is the collection of the paper presented at the title meeting. The 19 of the presented papers are indexed individually. (J.P.N.)

Energy Technology Data Exchange (ETDEWEB)

We present ab-initio calculations of the electronic structure of small Fe clusters (1-9 atoms) on Ni(001), Ni(111), Cu(001) and Cu(111) surfaces. Our focus is on the spin moments and their dependence on cluster size and shape. We derive a simple quantitative rule that relates the moment of each Fe atom linearly to its coordination number. Thus, for an arbitrary Fe cluster the spin moment of the cluster and of the individual Fe atoms can be readily found if the positions of the atoms are known. (orig.)

Energy Technology Data Exchange (ETDEWEB)

The authors trace the early history of nuclear power regulation in the US. Focusing on the Atomic Energy Commission, they describe the role of other groups that figured in the development of regulatory policies, including the Congressional Joint Committee on Atomic Energy, other federal agencies, state governments, the nuclear industry, and scientific organizations. They consider changes in public perceptions of and attitudes toward atomic energy and the dangers of radiation exposure. The basic purpose of the book is to provide the Nuclear Regulatory Commission and the general public with information on the historical antecedents and background of regulatory issues so that there will be continuity in policy decisions. The book concludes with an annotated bibliography of selected references. 19 figures.

Science.gov (United States)

The congressional Joint Committee on Atomic Energy issued the panel report Transportation of Radioactive Material by Passenger Aircraft. ...

International Nuclear Information System (INIS)

A diode-laser fluorescence experiment was performed in order to study fine-structure transitions between 5"2P states of rubidium atoms colliding with ground-state potassium or caesium atoms. The Rb(5"2P_3_/_2) state was optically excited and the intensity ratio of sensitized to direct fluorescence was measured. (author).

International Nuclear Information System (INIS)

The compound UC_2Si_2 has been found to be ferromagnetic at low temperatures with a Curie temperature of 101"0K. The magnetization follows a Curie-Weiss law in the paramagnetic region with an effective magneton number of 2.12 Bohr magnetons per uranium atom. Partial substitution of Th atoms for the U atoms results in an expansion of the lattice, a rapid drop in the Curie temperature, and a sizable increase in the coercive field.

Energy Technology Data Exchange (ETDEWEB)

This thesis is devoted to studies which prepared the construction of an atom Mach-Zehnder interferometer. In such an interferometer, the propagating waves are spatially separated, and the internal state of the atom is not modified. The beam-splitters are diffraction gratings, consisting of standing optical waves near-resonant with an atomic transition. We use the Bloch functions to define the atom wave inside the standing wave grating and thus explain the diffraction process in different cases. We developed a nearly all-analytical model for the propagation of an atom wave inside a Mach-Zehnder interferometer. The contrast of the signal is studied for many cases: phase or amplitude gratings, effects of extra paths, effects of the main mismatches, monochromatic or lightly polychromatic sources. Finally, we discuss three interferometric measurements we think very interesting. The ...

Energy Technology Data Exchange (ETDEWEB)

The main pollutants from marine diesel engines are oxides of nitrogen (NOx), sulfur oxides (SOx) and particulates (soot). However, the proposed marine diesel engine emission regulations will primarily focus on the levels of NOx and SOx. In the future, once the proposed regulations are met, the limits and levels of other emissions will come under increasing scrutiny, such as particulates, hydrocarbons and carbon monoxide. Regardless of the type of pollutant, there are generally two classes of emission control: (1) techniques that reduce the amount of pollutant formed in the combustion process, or (2) prevent the pollutants from reaching the atmosphere. Unfortunately, some of these control techniques will not be able to meet the incoming regulations. Therefore, this paper identifies the diesel engine emissions of concern, the impending regulations, and the merits of current and future ...

Energy Technology Data Exchange (ETDEWEB)

The proton beam has an advantage of the sharp dose falloff in dose distribution called Bragg peak while conventional radiation therapy modalities such as photons exhibit considerable amount of exit dose. To take advantage of this property it is important to know the exact location of the distal dose falloff. An error can cause overdose to the normal tissue or underdose to the tumor volume. The only way of finding out the dose distribution in-situ in particle therapy is to measure the gammas produced by nuclear reactions with tissue materials. Two kinds of gammas can be used: one is prompt gamma and the other is coincident gamma from the positron-emission isotopes. We chose to detect prompt gammas, and developed a prompt gamma scanning system (PGS). The proton beams of the proton therapy facility at National Cancer Center were used. The gamma distribution was compared to the dose distribution measured by an ionization chamber at three different energies of 100, 150, ...

Energy Technology Data Exchange (ETDEWEB)

Background: Cu-diacetyl-bis(N{sup 4}-methylthiosemicarbazone) [Cu-ATSM], although excellent for oncology applications, may not be suitable for delineating cardiovascular or neurological hypoxia. For this reason, new Cu hypoxia positron emission tomography (PET) imaging agents are being examined to search for a higher selectivity for hypoxic or ischemic tissue at higher oxygen concentrations found in these tissues. Two approaches are to increase alkylation or to replace the sulfur atoms with selenium, resulting in the formation of selenosemicarbazones. Methods: Three {sup 64}Cu-labeled selenosemicarbazone complexes were synthesized and one was screened for hypoxia selectivity in vitro using EMT-6 mouse mammary carcinoma cells. Rodent biodistribution and small animal PET images were obtained from BALB/c mice implanted with EMT-6 tumors. One alkylated thiosemicarbazone was synthesized and examined. Results: Of the three bis(selenosemicarbazone) ...

Energy Technology Data Exchange (ETDEWEB)

For Stage II of the European Dioxin Project the following objectives were set: - Amendment of existing emission data collected for most relevant emission sources in order to reduce uncertainties of emission estimates. Collecting first emission data from countries not yet performing dioxin emission measurement programs. Extending the inventory of dioxin emissions to ambient air produced in Stage I by a complementary study on emissions to land and water. Extending the regional scope of data collection to countries in Central Europe. The report of Stage II of the European Dioxin Project is presented in 3 Volumes. Volume 1 contains an overview on the background and approach of different activities carried out and on the results obtained. These results are put into a broader view regarding the dioxin reduction measures in Europe leading to ...

Energy Technology Data Exchange (ETDEWEB)

A body-centered cubic (bcc) Mg-12Li-9Al-1Zn (wt.%) alloy was fabricated in air by electrolysis from LiCl-KCl molten salt at 500 deg. C. Electrolytic deposition of Li atoms on cathode (Mg-Al-Zn alloy) and diffusion of the Li atoms formed the bcc Mg-Li-Al-Zn alloy with 12 wt.% Li and only 0.264 wt.% K. Low K concentration in the bcc Mg alloy strip after the electrolysis process resulted from 47% atomic size misfit between K and Mg atoms and low solubility of K in Mg matrix.

Wastenet

Emissions and residues: Emissions may include, inter alia, nitrogen oxides, carbon monoxide, sulphur dioxide and other oxides

UK PubMed Central (United Kingdom)

An improved method of counting acoustic emission (AE) events from water-stressed stems of cedar (Thuja occidentalis L.) is presented. Amplified AEs are analyzed on a real time basis...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

An ASTER (advanced spaceborne thermal emission and reflection radiometer) is one of the image sensors. It is to be installed in an earth survey polar orbit platform satellite, EOS-AM1, which is to be launched in 1998, and it is going to start its operation. Data observed by the thermal infrared remote sensing of ASTER include the spectral emissivity, and the spectral emission reflectivity which is expressed by the function of temperature. It is required to overcome technical problems how to extract the spectral emissivity from the observed data. The spectral emissivity extracted from the remote sensing data by the MMD method, measured for samples collected in Cuprite area, Nevada, and/or measured at sampled points were compared to each other and discussed. The hemisphere spectral reflectivity, which is indirect spectral emissivity, agreed well with the direct ...

UK PubMed Central (United Kingdom)

A historical prospective mortality study was conducted on a cohort of 34 156 male members of a heavy construction equipment operators union with potential exposure to diesel exhaust emissions. This...Full Text Available

International Nuclear Information System (INIS)

In VHTGR (Very High Temperature Gas-cooled Reactor), the radiation plays an important role in heat transfer through the cavity in RCCS (Reactor Cavity Cooling System). We performed the series of experiments to measure the emissivity using the infrared thermometer with wavelength range of 8#approx#14 #mu#m. As the first step, the transmittance of Zinc Selenide (ZnSe) window was measured to estimate the emissivity that can compensate the attenuation effect of window. The kind of gas with various concentrations in the cavity will be released during postulated accidents to the coolant type, so it is essential to estimate the effects of gas on the measurement of emissivity. In this manner we measured the emissivity with the air, the helium and the steam inside chamber. The results represent that the concentration of the air and the helium do not affect the emissivity significantly while ...

Energy Technology Data Exchange (ETDEWEB)

Emissions of sulphur and nitrogen oxides are continuing to fall in Europe but rise in Asia, according to calculations based on individual countries' predictions of economic development. The upward trend is slower than in previous predictions. 2 refs., 2 figs., 2 tabs.

Energy Technology Data Exchange (ETDEWEB)

Air pollution abatement measures are not an end in themselves, and undesirable side effects should be taken into account. The proposed emission index takes into account the total emissions caused by a technical project as well as the effects of the individual pollutants.

International Nuclear Information System (INIS)

This study was undertaken to collect emissions performance data for Canadian and comparable American refineries. The objective was to examine parameters that affect refinery air emissions performance and develop methods or correlations to normalize emissions performance. Another objective was to correlate and compare the performance of Canadian refineries to comparable American refineries. For the purpose of this study, benchmarking involved the determination of levels of emission performance that are being achieved for generic groups of facilities. A total of 20 facilities were included in the benchmarking analysis, and 74 American refinery emission correlations were developed. The recommended benchmarks, and the application of those correlations for comparison between Canadian and American refinery performance, were discussed. The benchmarks were: sulfur oxides, nitrogen oxides, ...

Energy Technology Data Exchange (ETDEWEB)

The construction of networks consisting of optically interconnected processing units is a promising way to scale up quantum information processing systems. To store quantum information, single trapped atoms are among the most proven candidates. By placing them in high finesse optical resonators, a bidirectional information exchange between the atoms and photons becomes possible with, in principle, unit efficiency. Such an interface between stationary and ying qubits constitutes a possible node of a future quantum network. The results presented in this thesis demonstrate the prospects of a quantum interface consisting of a single atom trapped within the mode of a high-finesse optical cavity. In a two-step process, we distribute entanglement between the stored atom and two subsequently emitted single photons. The long atom trapping times achieved in the system together with the high ...

International Nuclear Information System (INIS)

An energy analyzer has been constructed and operated in UHV for the purpose of analyzing the energy of neutral atoms scattered from solid surfaces. The analyzer consists of a LiF single crystal located at an angle close to the normal to the sample crystal so that the diffraction pattern obtained by scanning the LiF crystal yields the energy of the scattered atoms. Two designs which have been used are described. The temperature of both sample and analyzer crystal is near 20 K and once cleaned they can be maintained in the state of initial preparation for many weeks. The sample was a (001) Cu surface in this case. Such an energy analyzer can only be used, in most cases, for He atom scattering although Ne atoms could be used if the scattered intensities were adequate. The detector developed in this study is able to detect about 2 x 10"5 atoms/s. The resolution of the spectrometer ...

CERN Document Server

A survey of various mechanisms for particle emission in hydrodynamics is presented. First, in the case of sudden freeze out, the problem of negative contributions in the Cooper-Frye formula and ways out are presented. Then the separate chemical and thermal freeze out scenario is described and the necessity of its inclusion in a hydrodynamical code is discussed. Finally, we show how to formulate continuous particle emission in hydrodynamics and discuss extensively its consistency with data. We point out in various cases that the interpretation of data is quite influenced by the choice of the particle emission mechanism.

International Nuclear Information System (INIS)

The Federal Republic of German (FRG) had uniquely strict emission legislation for particulates SO_2 and NO_X from fossil-fired power plants. The 13th Regulation to the Federal Emission Control Act required that by 1 July 1988 all large furnaces fired with solid or liquid fuels that would not be decommissioned by 1993 be retrofitted with SO_2 control technology. The emission limits are 15 per cent of the sulphur introduced with the fuel (400 mg/m"3 maximum) at thermal capacities above 300 MW. 1 ref., 9 figs, 15 bibliographies.

Wastenet

However, these intra-industrial structural changes are not considered in this bottom-up study.

KoreaScience (Korea)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

One requirement of a thermophotovoltaic (TPV) radiator is to efficiently emit photons at high temperatures to TPV cells for conversion to electric power. Because many candidate radiator materials with adequate structural properties display low emissivity, coatings or other surface modifications are required for enhancement of emissivity. Six plasma sprayed coatings and one textured surface demonstrated adequate thermal stability and emittance values of 0.8 or greater. Promising attributes of modified surfaces are identified.

Energy Technology Data Exchange (ETDEWEB)

Designing efficient policies for curbing greenhouse gas (GHG) emissions is of particular interest for todays policy makers, in view of global climate change threats. This paper analyses the options Switzerland has for curbing its CO{sub 2} emissions. Using MARKAL and MARKAL-NACRO models, it investigates, in particular effects of national and international carbon taxes. (author) 3 figs., 1 tab., 6 refs.

International Nuclear Information System (INIS)

Greenhouse gas emissions from international maritime transport are exempt from liabilities under the Kyoto Protocol. Research into quantifying these emissions is ongoing, and influences policy proposals to reduce emissions. This paper presents a cargo-based analysis of fuel consumption and greenhouse gas emissions from New Zealand's international maritime transport of goods. Maritime transport moves 99.5% (by mass) of New Zealand's internationally traded products. It is estimated that 73% of visiting vessels' activity can be directly attributed to the movement of goods in and out of New Zealand. A cargo-based methodology was used to estimate that the international maritime transport of New Zealand's imports and exports consumed 2.5 million tonnes (Mt; 2.6 billion litres) of fuel during the year 2007, which generated 7.7 Mt of carbon dioxide (CO_2) emissions. Double-counting of ...

International Nuclear Information System (INIS)

The method for calculating emissions to air has been revised, which has led to adjustments. Because of this, emissions in 1999 cannot yet be compared with previous years. Emissions in 1990 - 1998 are being recalculated now using the new method and are expected to be ready during 2001. Emissions to air of carbon dioxide (CO_2) in Sweden was 56.58 million tonnes in 1999, not including emissions from biofuels and international bunkers. The major sources of CO_2 emissions are the combustion of fossil fuels and the use of fuels for mobile sources. Total emissions to air of sulphur dioxide (SO_2) and nitrogen oxides (NO_x, counted as NO_2) in Sweden was 66 000 and 263 000 tonnes respectively in 1999. International bunkers are not included. The major source of SO_2 emissions is combustion of fossil fuels. Road traffic is the ...

Energy Technology Data Exchange (ETDEWEB)

This report presents estimates of the annual anthropogenic UK emissions of greenhouse gases for the years 1990-93 for submission under the Framework Convention on Climate Change. The gases considered are carbon dioxide, methane, nitrous oxide, nitrogen oxides, carbon monoxide and non-methane volatile organic compounds. Emissions of all the gases have declined since 1990. In particular, those of carbon dioxide have fallen by 4%; those of methane by 8% and those of nitrous oxide by 28%. Emission estimates are reported in the IPCC Standard Tables format disaggregated by source category and fuel. The methodology used for the estimates and how they relate to the UK National Atmospheric Emissions Inventory is discussed in an appendix. (author)

International Nuclear Information System (INIS)

The document presents an overview on atmospheric pollution in Lebanon, with an analysis of sources of pollution, their impact on local and global environment and their control.Local causes of pollution are mainly: -Thermal power plants of electric power production which produce 75% SO_2 emission and 60% dust - Industries, especially cement industry - Land transportation which produces 70% NOX emission and 50% CO_2 A description of air pollution caused by these three sectors is revealed. Pollutants derived from fuel combustion are analyzed. It is estimated that in 2010, Co_2 emission will reach 5204450 tons, SO_2 emission will be 136470 tons, NOX emissions 96870 and dust estimated to 4130 tons. CFC consumption and measures of control according to Montreal Protocol are described. Recommendations for control of air pollution in Lebanon within a national policy are presented.

Energy Technology Data Exchange (ETDEWEB)

This patent describes a low emission duel fuel engine system. It comprises: a dual fuel engine having a combustion chamber; a fuel oil supply connected to the engine; a fuel gas supply connected to the engine; and means connected between the fuel oil supply and the engine for injecting fuel oil into the engine. The means connected between the engine and fuel oil supply limiting the injection of fuel oil to the combustion chamber to pilot ignition quantities only, wherein the limiting means includes means for limiting the injection of fuel oil such that the exhaust emission of NO{sub x} is at an emission rate of less than 1 GM/PH-HR, whereby the exhaust emission performance of the dual fuel engine is enhanced.

Energy Technology Data Exchange (ETDEWEB)

Investigations were conducted on the range of emission rates of NO, NO[sub 2], CO and hydrocarbons, and the thermal efficiencies produced by each burner on three production cookers, supplied by different Australian manufacturers. It was found that the emissions and efficiencies were markedly affected by (1) the thermal input, both with and without a load on the burner, and (2) the load-height to flame-length ratio, with a load on the burner. The effect of hydrocarbon leakage into the secondary/dilution air was investigated, to explain the observed correlation of hydrocarbon emission rate with dilution air flow. The hydrocarbons were found to arise from two sources: -leakage from the stabilisation ports at the base of the burner, which was found to be significant at the higher thermal input; -incomplete combustion of the fuel in the premix, which was the dominant source of hydrocarbons emissions at the ...

CERN Document Server

Using a sample of 30,000 quasars from SDSS-DR7, we explore the range of properties exhibited by high-ionization, broad emission lines, such as CIV 1549. Specifically we investigate the anti-correlation between L_UV and emission line EQW (the Baldwin Effect) and the "blueshifting" of high-ionization emission lines. The blueshift of the CIV emission line is nearly ubiquitous, with a mean shift of 810 km/s for radio-quiet (RQ) quasars and 360 km/s for radio-loud (RL) quasars, and the Baldwin Effect is present in both RQ and RL samples. Composite spectra are constructed as a function of CIV emission line properties in attempt to reveal empirical relationships between different line species and the SED. Within a two-component disk+wind model of the broad emission line region (BELR), where the wind filters the continuum seen by the disk component, we find that RL ...

International Nuclear Information System (INIS)

Magnetically driven non-stationary acceleration of jets in active galactic nuclei results in the leading parts of the flow being accelerated to much higher Lorentz factors than in the case of steady-state acceleration with the same parameters. The higher Doppler-boosted parts of the flow may dominate the high-energy emission of blazar jets. We suggest that highly variable GeV and TeV emission in blazars is produced by the faster moving leading edges of highly magnetized non-stationary ejection blobs, while the radio data trace the slower-moving bulk flow. Thus, the radio and gamma-ray emission regions have different, but correlated, Doppler factors. High-energy emission is generated, typically within the optically thick core, in the outer parts of the broad-line emission region, avoiding the radiative drag on the faster parts of the flow. The radio emission ...

International Nuclear Information System (INIS)

This guide explained the requirements for Off-Road Compression Ignition Engine Emission Regulations established under the Canadian Environmental Protection Act. The regulations are enforced by Environment Canada, which authorizes and monitors the use of the national emissions mark. The regulations prescribe standards for off-road engines that operate as reciprocating, internal combustion engines, other than those that operate under characteristics similar to the Otto combustion cycle and that use a spark plug or other sparking device. The regulations apply to engines that are typically diesel-fuelled and found in construction, mining, farming and forestry machines such as tractors, excavators and log skidders. Four different types of persons are potentially affected by the regulations: Canadian engine manufacturers; distributors of Canadian engines or machines containing Canadian engines; importers of engines or machines for the purpose of ...

International Nuclear Information System (INIS)

Measurements of ion-induced electron emission have been performed with helium and argon ions with energies between 300 and 900 eV on W, W with 10% Ti, Al, Al with 1% Cu, Al with 1% Si, Si, and Be. This article describes many of the important surface characteristics that influence the ion-induced electron emission. For low-energy ions, the substrate material was found to be less important as the velocity of the incident ion decreased. In the case of incident Ar"+ the substrate material had a negligible effect on the emission for this energy range. The presence of an adsorbed layer enhanced emission in all cases. Heating the substrates resulted in oxidation of the surfaces and a subsequent increase in emission. The electron emission from aluminum samples with smaller grain sizes was higher than samples of identical composition with larger grains. This effect is ...

International Nuclear Information System (INIS)

The increasing diffusion of small-scale energy systems within the distributed generation (DG) paradigm is raising the need for studying the environmental impact due to the different DG solutions in order to assess their sustainability. Addressing the environmental impact calls for building specific models for studying both local and global emissions. In this framework, the adoption of natural gas-fueled DG cogeneration technologies may provide, as a consequence of cogeneration enhanced overall energy efficiency and of natural gas relatively low carbon content, a significant reduction of global impact in terms of CO2 emissions with respect to the separate production of electricity and heat. However, a comprehensive evaluation of the DG alternatives should take into account as well the impact due to the presence of plants spread over the territory that could increase the local pollution, in particular due to CO and NOx, and thus could worsen the ...

International Nuclear Information System (INIS)

Heavy-duty trucks and buses are substantial contributors to the atmospheric oxides of nitrogen (NO_x) inventory, but prediction of their emissions in real use remains inchoate. Continuous emissions of NO_x were recorded from Chassis dynamometer testing of eight vehicles using a variety of transient cycles, including the Central Business District schedule. NO_x data were treated to account for sampling time lag and presented against instantaneous vehicle axle power. Data were repeatable from run to run and test schedule, but vehicle type and test cycle both influenced the instantaneous emissions rates. However, the resulting correlations may be used for mobile source NO_x contribution estimation when combined with vehicle activity data. The emissions data were also presented as NO_x/CO_2, which are valuable for comparison with remote sensing emissions data. The overall average ratio ...

International Nuclear Information System (INIS)

Atomic oxygen is measured in a pulsed dielectric barrier discharge (DBD) using two-photon absorption laser-induced fluorescence (TALIF). The ground-level atomic oxygen is excited to the 3p "3P state by two-photon absorption at 226 nm. Negative (-40 kV) or positive (+30 kV) pulsed DBD occurs in an O_2-N_2 mixture at atmospheric pressure. The pulse width of the DBD current is approximately 50 ns. The TALIF experiment shows that the decay rate of atomic oxygen increases linearly with O_2 concentration. This result proves that atomic oxygen decays mainly by the third-body reaction, O + O_2 + M #-># O_3 + M. The rate coefficient of the third-body reaction is estimated to be 2.2 x 10"-"3"4 cm"6 s"-"1 in the negative DBD and 0.89 x 10"-"3"4 cm"6 s"-"1 in the positive DBD. It is shown that the decay rate of atomic oxygen increases linearly with humidity. This can explain the well-known ...

Energy Technology Data Exchange (ETDEWEB)

The production of polarized negative ion beams by collisional pumping is described. Collisional pumping utilizes repeated charge changing collisions in a thick electron-spin-polarized gas or vapor target to form a polarized fast atom beam. The polarized fast atom beam is then partially converted into a polarized negative ion beam in a vapor target. Analysis is presented for a hydrogen beam passing through either a thick polarized H atom target or a thick polarized alkali target. Large polarizations and large currents may be possible.

Energy Technology Data Exchange (ETDEWEB)

A process is claimed for selectively preparing a mixture of two-carbon atom oxygenated hydrocarbons, namely, acetic acid, ethanol and acetaldehyde, by continuously contacting a gaseous reaction mixture containing hydrogen and carbon monoxide with a solid catalyst comprising rhodium in combination with one or more alkali metals selected from the group consisting of lithium, potassium, cesium and rubidium at reaction conditions correlated so as to favor the formation of a substantial proportion of such two-carbon atom products.

International Nuclear Information System (INIS)

Doubly-excited 2s-12p-13pnp autoionizing resonance series of Ne atom as well as autoionizing resonances in the 2s region of Na and Mg atoms have been studied with monochromatized synchrotron radiation. Use of charge-separated photoion-yield method allowed us to detect these weak resonances in a clarified way in the yield curves of doubly-charged ions. The observed resonance states have been interpreted with the help of MCDF calculations, and the decay processes of these resonance states are discussed briefly.

International Nuclear Information System (INIS)

The symmetry properties of the Coulomb potential allow for a dynamical spin-1/2 description of any fixed n level of a hydrogenlike atom in a time-dependent sufficiently weak electric and/or magnetic field. An explicit expression for the time dependence of the l,m amplitudes pertaining to a general n level is derived. The derivation follows on purely algebraic operations. Based on the derivation, we give analytical n-independent solutions to established and proposed schemes for driving the atom into a high angular-momentum state.

Energy Technology Data Exchange (ETDEWEB)

The total and differential atomic pair-correlation functions of an icosahedral (quasicrystalline) solid were determined for the first time, directly by the differential anomalous-x-ray-scattering technique using synchrotron radiation. The observed atomic distances involving uranium atoms in icosahedral Pd/sub 58.8/U/sub 20.6/Si/sub 20.6/ suggest the presence of a quasicrystalline sublattice with vertex decoration. The pair distribution functions in the icosahedral and amorphous phases are similar up to the second-nearest neighbors, or up to 6 A-circle.

British Library Electronic Table of Contents (United Kingdom)

The thermodynamic characteristics of adsorption of iodobenzene, 2-iodothiophene, and 1- and 2-iodoadamantanes on the surface of graphitized thermal carbon black were determined experimentally. The influence of the special features of the molecular structure of the adsorbates on the thermodynamic characteristics of adsorption was studied. The atom-atom approximation of the semiempirical molecular-statistical theory of adsorption was used to calculate the thermodynamic characteristics of adsorption of the adsorbates using the newly determined potential function parameters of pair intermolecular interaction (?(r)) of I with C atoms of the basal graphite face. For the example of isostructural monohalogenated benzenes, thiophenes, and adamantanes, a comparative analysis of the contributions of ...

International Nuclear Information System (INIS)

A scheme of evaluating a generalized three-photon excitation cross section #sigma#/sub (3)/ in neutral atomic argon at 3144.67 A is outlined. Three photons at this wavelength can excite the neutral argon atoms from the ground 3p"6 "1S_0 state to the 3p"54s'[1/2]_1"0 state. The fourth photon will ionize the argon atoms. Assuming linear polarization of the incident laser radiation, contributions from several channels in various energy-level schemes are summed in the evaluation of the transition probability. For a laser linewidth of #DELTA##lambda#/sub L/ = 1 A, our maximum numerical value of the computed result for the three-photon excitation cross section is #sigma#/sub (3)/ = 1.414 x 10/sup -80/ cm"6 s"2. .AE.

International Nuclear Information System (INIS)

The total interaction cross sections (#sigma#_t) of some sugars and amino acids and five elements: lithium, carbon, oxygen, aluminium and calcium have been measured for 6.4 keV, 13.95 keV, 14.4 keV, 17.74 keV, 24.14 keV, 30.8 keV, 35 keV, 59.54 keV, 81 keV, 122 keV and 136 keV photons in a narrow beam good geometry set up, by using high resolution detectors such as a Si-PIN diode detector and a high purity germanium detector. The #sigma#_t values have been used in a matrix method to evaluate the effective atomic numbers Z_e_f_f of the samples from their effective atomic cross sections #sigma#_a. The effective atomic cross section of a sample #sigma#_a is the total interaction cross section divided by the total number of atoms of all types in it. Further, a quantity called the effective atomic weight A_e_f_f of a sample was defined as the ratio of the molecular weight A to the total ...

International Nuclear Information System (INIS)

... Masahiro Tsukada, Takashi Japan Atomic Energy Agency, Tokai, Ibaraki (Japan)

British Library Electronic Table of Contents (United Kingdom)

Although the outer surface of single-walled carbon nanotubes (atomically thin cylinders of carbon) can be involved in a wide range of chemical reactions, it is generally thought that the interior surface of nanotubes is unreactive. In this study, we show that in the presence of catalytically active atoms of rhenium inserted into nanotubes, the nanotube sidewall can be engaged in chemical reactions from the inside. Aberration-corrected high-resolution transmission electron microscopy operated at 80?keV allows visualization of the formation of nanometre-sized hollow protrusions on the nanotube sidewall at the atomic level in real time at ambient temperature. Our direct observations and theoretical modelling demonstrate that the nanoprotrusions are formed in three stages: (i) metal-assisted d...

Science.gov (United States)

... The insu- lation between gate and nanowire is the high-k dielectric HfO2, deposited by atomic layer depo- sition (ALD). ...

Science.gov (United States)

by the radionuclide X-ray fluorescence analysis into several groups according to the atomic number of the determined element. Table I documents this. ...

Energy Technology Data Exchange (ETDEWEB)

Ozone plays a critical role in both the chemistry and radiation balance of the troposphere. Understanding the factors controlling tropospheric ozone levels is critical to our understanding of a variety of issues in global chemistry and climate change. Chlorine atoms have the potential to contribute significantly to the ozone balance in the free troposphere. They can react directly with ozone or alternately, with organics and may actually lead to the formation of ozone in the presence of sufficient NO. Reactions of alkali halides in sea salt particles are a potential source of atomic chlorine, hence reactions of these alkali halides, especially those producing precursors to atomic chlorine, are of great interest. Finally, the mechanisms, intermediates and products of the Cl-biogenic reactions are unknown; these could serve as unique markers of chlorine atom chemistry in the troposphere, and hence are ...

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(Jan 1974). United States Ashraf, M. Anwar, M. Siddiqui, QH Atomic Energy

Energy Technology Data Exchange (ETDEWEB)

The development of nano/molecular devices will require atomic-sized electrical contacts or nano metric conductors for wiring. As metal nano wires exhibit quantized conductance at room temperature, quantum transport effects will play an important role in the practical implementation of nano devices. As copper is currently used as interconnecting metal in standard microelectronics, the characterization of Cu nano wire properties deserves special attention. In this work, we show a detailed study of structural and electronic properties of atomic-sized Cu wires. In particular, we have established a complete correlation between the conductance and the structure by associating real-time atomic resolution transmission electron microscopy imaging with molecular dynamic simulations, conductance measurements and conductance calculations. Our study has revealed the structural relaxation of Cu wires forming a pentagonal ...

International Nuclear Information System (INIS)

... Dozaki, Koji Takiguchi, Hideki Japan Atomic Power Company, Tokyo (Japan)

Energy Technology Data Exchange (ETDEWEB)

Mechanisms and associated energetics for adatom diffusion on the (100) and (110) surfaces of Ni, Cu, Rh, Pd, and Ag are investigated. Self-diffusion was studied on (100) and (I 10) surfaces of Ni, Cu, Pd and Ag using corrected effective medium method (CEM) and approximation to CEM used for molecular dynamics and Monte Carlo studies (MD/MC-CEM). Self-diffusion on Pd(100), Ag(100), Ni(110), Cu(110), Pd(110), and Ag(110) is accomplished by classical diffusion: the adatom hops from its equilibrium adsorption site over an intervening bridge site to an adjacent equilibrium site. Self-diffusion on Ni(100) and Cu(100) proceeds by atomic-exchange diffusion: the adatom on the surface displaces an atom in the first surface layer. Aside from explicit inclusion of the kinetic-exchange-correlation energy, it is critical to include enough movable atoms in the calculation to insure correct energetics. Distortions induced by these diffusion ...

International Nuclear Information System (INIS)

... structure crystal-phase transformations fluorescence fluorescence spectroscopy

International Nuclear Information System (INIS)

Published in summary form only.

Science.gov (United States)

... Schioler (703) 306-1836 lschiole@nsf.gov This material is available primarily for archival purposes ... of superconducting materials. Colossal magnetoresistance materials are those in which the electrical ...

Science.gov (United States)

... (l0)6o). 316. Statf,'ent. In Hearings before the Subcommittee on Research, Do'v,-Iopment, and Radiation of the Joint Committee on Atomic Energy. ...

International Nuclear Information System (INIS)

... 45 p. absorption spectroscopy errors lead lead 203 beta decay radioisotopes

British Library Electronic Table of Contents (United Kingdom)

Abstract Electronic structures of two representative zigzag and armchair models of aluminum phosphide nanotube (AlPNT) were investigated by density functional theory calculations. The structures were optimized and the bond lengths, tip diameters, band gaps, and dipole moments were calculated. Moreover, the quadrupole coupling constants (CQ) were calculated for the Al-27 atoms of the optimized structures. The same values of AlP bond lengths were calculated for both models. The larger value of band gap of armchair model than the zigzag model indicated the stronger dielectric property for the former model. The values of CQ(27Al) were the largest for the Al atoms placed at the tips of both zigzag and armchair AlPNT than other Al atoms, which could reveal dominant role of the Al atoms placed at...

International Nuclear Information System (INIS)

This paper deals with estimating aircraft landing and take-off (LTO) emissions (HC, CO, NO_x, SO_2) at 40 Turkish airports including the biggest airports, i.e. Ataturk International Airport (AIA) in Istanbul, Antalya Airport in Antalya and Esenboga Airport in Ankara in 2001. The calculation model is based on flight data recorded by the State Airports Authority. The flight data include the type and number of aircraft, number of passengers, amount of cargo etc., which depend on day-time and date. For the emission calculations the International Civil Aviation Organization (ICAO)-Engine emission data bank, which includes minimum and maximum values for both fuel flow rates and emissions factors, is used. By using first the minimum and then the maximum values from the data bank, two estimations of aircraft LTO emissions at Turkish airports are calculated: i.e. minimum and maximum ...

International Nuclear Information System (INIS)

Methods currently being used or developed for the elemental analysis of materials are chemical analysis, non-destructive inspection and calorimetry. The chemical analysis, which removes high-level radioactive elements through chemical treatments and then performs the quantitative analysis using the ICP-MS(Inductively Coupled Plasma - Mass Spectrometer) or the ID-MS(Isotope Dilution Mass Spectrometer), is recognized the most accurate. However, it requires a long, complex pre-treatment process in which a mass spectrometer could be contaminated. To solve this problem, a new method, which can be performed with high-level radioactivity and at high temperature, was desired. Such a method should also have the same accuracy as the chemical analysis, with a less possibility for instruments to be contaminated. In addition, as interests in the environment and the life quality are increased, a detailed analysis on the environmental impacts is also required. Satisfying all of ...

International Nuclear Information System (INIS)

The use of environmental monitoring as a technique to identify activities related to the nuclear fuel cycle has been proposed by international safeguards organizations. The elements specific for each kind of nuclear activity, or 'nuclear signatures', inserted in the ecosystem can be intercepted by different live organisms. This work demonstrates the technical viability of using pine needles as bioindicators of nuclear signatures associated with uranium enrichment activities. Additionally, it proposes the use of HR-ICP-MS to identify the signature corresponding to that kind of activities in the ecosystem. Nitric acid solutions, used to wash pine needles sampled near nuclear facilities and containing only 0.1 #mu#g x kg"-"1 of uranium, exhibit a n("2"3"5U)/n("2"3"8U) isotopic abundance ratio of 0.0092#+-#0.0002, while solutions originated from samples collected at places located more than 200 km far from activities related to the nuclear fuel cycle exhibit a value of ...

International Nuclear Information System (INIS)

This Statistical Report presents results from the physical Swedish Environmental and Economic Accounts for the years 1993 and 1995 according to the classification NACE. The Environmental Economic Accounts constitute an integrated and comprehensive system for environmental and economic statistics. Environmental data are systematically presented together with economic data in a common framework. The system can be used for analyses of various relationships between economy and environment. Data on emissions to air of carbon dioxide, sulphur dioxide, nitrogen oxides, carbon monoxide, methane, nitrous oxide and ammonia are presented for 39 industries, government services and private consumption. The use of energy commodities in monetary and physical terms are also presented for the same sectors. Economic, energy and emission data are also presented in environmental and economic profiles and indicators. Environmental and economic profiles provide an ...

International Nuclear Information System (INIS)

To aid in the study of lower hybrid current drive as a means of current profile control, the radial profile and velocity distribution of the fast current-carrying electrons and their time evolution must be known. As part of the recent effort to understand this fast electron transport, a diagnostic has been installed on PBX-M to measure the electron cyclotron emission from the fast electrons. An oblique horizontal view of upshifted cyclotron emission in the midplane can give radial as well as velocity space information about the fast electrons. Emission in X mode frequencies refracted by the right-hand cutoff is radially localized. The observed emission at a specific frequency comes only from the radial region r_t_u_r_n=#0. Emission measured by this new diagnostic has been found to be radially localized as predicted. It is also expected that localized moments of the distribution ...

Energy Technology Data Exchange (ETDEWEB)

The report gives results of a project conducted to create a file containing comprehensive data on all electric utilities in the US. The National Acid Precipitation Assessment Program's (NAPAP's) emissions inventory activities focus on the estimation of emissions from pollutants that contribute to acid deposition. Electric utilities, which emit a large share of total acid deposition precursor emissions, are important for modeling analyses. Data reported by states to the National Emissions Data System (NEDS) for the 1985 NAPAP Emissions Inventory and data reported to the U.S. Department of Energy (DOE) on EIA Form 759, EIA Form 767, FERC Form 423, and the Integrated Data Base System (IDBS) were matched and combined. The resulting 1985 National Utility Reference File (NURF) contains detailed unit level data for nearly 10,000 electricity generating plants.