The total and differential atomic pair-correlation functions of an icosahedral (quasicrystalline) solid were determined for the first time, directly by the differential anomalous-x-ray-scattering technique using synchrotron radiation. The observed atomic distances involving uranium atoms in icosahedral Pd/sub 58.8/U/sub 20.6/Si/sub 20.6/ suggest the presence of a quasicrystalline sublattice with vertex decoration. The pair distribution functions in the icosahedral and amorphous phases are similar up to the second-nearest neighbors, or up to 6 A-circle.
The total and differential atomic pair-correlation functions of an icosahedral (quasicrystalline) solid were determined for the first time, directly by the differential anomalous-x-ray-scattering technique using synchrotron radiation. The observed atomic distances involving uranium atoms in icosahedral Pd/sub 58.8/U/sub 20.6/Si/sub 20.6/ suggest the presence of a quasicrystalline sublattice with vertex decoration. The pair distribution functions in the icosahedral and amorphous phases are similar up to the second-nearest neighbors, or up to 6 A-circle.
The thermal transformation of Al-base icosahedralphases was studied in-situ by real time neutron powder diffraction. Different compositions have been selected in order to vary the initial phase morphology and change the neutron scattering contrast between species. Alloys with low silicon and large aluminium contents produce first the orthorhombic O-Al_6Mn modification. In alloys with larger silicon content, the #alpha#-AlMnSi cubic phase appears soon after the beginning of the transformation but is still preceeded by O-Al_6Mn. Depending on compositions, the crystallization of the icosahedralphase is controlled either by the diffusion of Al through its interface with the residual fcc aluminium or that of Si within the bulk. The results are discussed in the light of current structural models. (author) 40 refs., 14 figs., 3 tabs.
The occurrence of stable decagonal quasicrystallinephase in Al-Co-Ni and Al-Cu-Co alloys through conventional solidification is well established. Earlier, we have studied the effect of Cu substitution in place of Co in the Al_7_0Co_1_5Ni_1_5 alloy. Here we report the structural/micro-structural changes with substitution of Cu for Ni in rapidly solidified Al-Co-Ni alloys. The melt spun ribbons have been characterized using X-ray diffractometry, scanning and transmission electron microscopy. With an increase in Cu content in the melt spun Al_7_0Co_1_5Cu _xNi_1_5_-_x (x = 0-15 at.%) alloys, the relative amount of the decagonal phase decreased up to 10 at.% of Cu. At this composition, the quaternary alloy showed the co-existence of decagonal quasicrystal and superstructure of #tau#_3 vacancy ordered crystalline phases. The decagonal phase containing Cu showed more disordering than ...
While dealing with molecular systems, it is highly advantageous to work with a basis set which has definite total spin and also belongs to a definite irreducible representation of its symmetry (point) group. But unfortunately, there hadn't been any general simple technique to deal with the problem, especially when molecule possesses non-Abelian point group symmetry. In a previous paper \\cite{sahoo}, we presented a general technique which is a hybrid method based on Valence Bond basis and the basis of z-component of the total spin. The technique is applicable to all types of point groups and is easy to implement on computer. We illustrated the power of the method by applying it to a molecular magnetic system. Here we extend the method to electronic systems and demonstrate this extended technique by applying it to a model icosahedral half-filled electronic system (12 sites). Reasons we took this model are, its a system with huge Hilbert space (dimension 1,778,966; ...
Assembly of icosahedral capsids of proper size and symmetry is not understood. Residue F170 in bacteriophage P22 coat protein is critical for conformational switching during assembly. Substitutions at this site cause assembly of tubes of hexamerically arranged coat protein. Intragenic suppressors of the ts phenotype of F170A and F170K coat protein mutants were isolated. Suppressors were repeatedly found in the coat protein telokin-like domain at position 285, which caused coat protein to assemble into petite procapsids and capsids. Petite capsid assembly strongly correlated to the side chain volume of the substituted amino acid. We hypothesize that larger side chains at position 285 torque the telokin-like domain, changing flexibility of the subunit and intercapsomer contacts. Thus, a sing...
A massively-parallel ab initio computer code, which uses Gaussian bases, pseudopotentials, and the local density approximation, permits the study of transition-metal systems with literally hundreds of atoms. We present total energies and relaxed geometries for Ru, Pd, and Ag clusters with N = 55, 135, and 140 atoms; we also used the DMOL code to study 13-atom Pd and Cu clusters, with and without hydrogen. The N = 55 and 135 clusters were chosen because of simultaneous cubo-octahedral (fcc) and icosahedral (icos) sub-shell closings, and we find icos geometries are preferred. Remarkably large compressions of the central atoms are observed for the icos structures (up to 6% compared with bulk interatomic spacings), while small core compressions ({approx} 1 %) are found for the fcc geometry. In contrast, large surface compressive relaxations are found for the fcc clusters ({approx} 2-3% in average nearest neighbor spacing), while the icos surface displays small ...
Top quark is extremely sensitive to non-standard CP violating phases. General strategies for exposing different types of phases at the NLC are outlined. SUSY phase(s) cause PRA in $t\\to Wb$. The transverse polarization of the $\\tau$ in the reaction $t\\to b\\tau\
Despite their simplicity, diatomic molecules of first row elements can exhibit very complex phase diagrams. Determination of the phase diagrams can be further complicated by the existence of hysteretic molecular phases that can be observed over large regions of coexistence. Here we present evidence for a previously unreported molecular phase of nitrogen existing at room temperature at least over the range of 33-74 GPa. Our measurements show that sample history may have a significant impact on the thermodynamic states accessed by the molecular nitrogen solid and, by extension, also on the established phase diagram.
In connection with the different cyclical strengths of the two-phase (#alpha# + #beta#) titanium alloy in the case of the acicular and rounded formations of the #alpha#-phase, we have studied, employing the X-ray diffraction method, the phase composition of the alloy and the influence of heat treatment upon it. Using the method of electronic fractography, we examined the fractures in samples destroyed by the asymmetric twisting, in order to find out why the durability of the alloy is dependent upon the #alpha# - phase structure. It has been found that in the BT22 alloy, the decay the #beta#-phase may proceed in two ways; either with the formation of the martensite #alpha#'-phase of the acicular shape or with the separation of the non-martensite round-shaped #alpha#-phase. The character of the phase transformations #beta# ...
The Fourier transform of cosmological density perturbations can be represented in terms of amplitudes and phases for each Fourier mode. We investigate the phase evolution of these modes using a mixture of analytical and numerical techniques. Using a toy model of one-dimensional perturbations evolving under the Zel'dovich approximation as an initial motivation, we develop a statistic that quantifies the information content of the distribution of phases. Using numerical simulations beginning with more realistic Gaussian random-phase initial conditions, we show that the information content of the phases grows from zero in the initial conditions, first slowly and then rapidly when structures become non-linear. This growth of phase information can be expressed in terms of an effective entropy: Gaussian initial conditions are a maximum entropy realisation of the ...
The phase space of quantized systems that contain tachyons has been investigated. Interpretation difficulties and unexpected divergences are found when it is considered the volume of Lorentz-invariant phase space. These problems can be overcome, however, at the expense of Lorentz invariance.
The phase space of quantized systems that contain tachyons has been investigated. Interpretation difficulties and unexpected divergences are found when we consider the volume of Lorentz-invariant phase space. These problems can be overcome, however, at the expense of Lorentz invariance.
cdc18+ of Schizosaccharomyces pombe is a periodically expressed gene that is required for entry into S phase and for the coordination of S phase with mitosis. cdc18+ is related to the Saccharomyces...Full Text Available
French English ... Orig. Title Imagerie IRM des lesions focales hepatiques avec les antennes de surface en reseau phase (phased array): apnee ou imagerie haute resolution?.
Phase 2 of the four phase NASA/DoD Aerospace Knowledge Diffusion Research Project was undertaken to study the transfer of scientific and technical information (STI) from government to the aerospace industry and the role of librarians and technical informa...
Various measurement tools that are used in chaos theory were applied to analyze two-phase pressure signals with the objective of identifying and interpreting flow pattern transitions for two-phase flows in a small, horizontal rectangular channel. These me...
The authors present differential scanning calorimetry (DSC) and in situ Moessbauer spectroscopy results for Metglas ribbons, to which different heat treatments were made. The Curie temperature of the amorphous phase is determined and the evolution of the magnetic field of this phase is studied as a function of temperature
Previous studies have shown that iterative in-line x-ray phase retrieval algorithms may have higher precision than direct retrieval algorithms. This communication compares three iterative phase...Full Text Available
The heating history of a droplet during its flight can be divided into two phases: (a) the initial phase when evaporation, although it occurs, does not change the heat balance of the droplet much (the case considered in our previous paper and (b) the final phase when the cooling due to evaporation balances the heat flux from the plasma. The later phase is considered in Chen's comment. In our reply, a very straightforward consideration demonstrates that even in the final phase of the droplet flight, the 'rocket' effect can be significant. (reply)
The phase transition is a performance measure of the sparsity-undersampling tradeoff in compressed sensing (CS). This letter reports, for the first time, the existence of an exact phase transition for the $\\ell_1$ minimization approach to the complex valued CS problem. This discovery is not only a complementary result to the known phase transition of the real valued CS but also shows considerable superiority of the phase transition of complex valued CS over that of the real valued CS. The results are obtained by extending the recently developed ONE-L1 algorithms to complex valued CS and applying their optimal and iterative solutions to empirically evaluate the phase transition.
Recessive mutations of the early phase change (epc) gene in maize affect several aspects of plant development. These mutations were identified initially because of...Full Text Available
We investigated phase transition of ilmenite-type AgSbO3 to pyrochlore by post-heat treatment and the synergy effect of the mixed phases of AgSbO3 on the photocatalytic activities to enhance the activities. The AgSbO3 with an ilmenite structure was prepared by a cation-exchange method. Phase transition from the ilmenite to pyrochlore occurred by proper control of post-heat treatment. The sample that was obtained by post-heat treatment of ilmenite-type AgSbO3 at 660^oC for 3h consisted of both of the ilmenite and pyrochlore phases, and the sample at 685^oC for 4h mainly consisted of the pyrochlore phase. Together with an increase in the ratio of the pyrochlore phase, the optical absorption spectra blue-shifted. The band gaps of single phases of the ilmenite and the pyrochlore were 2.4 and 2...
... of a secondary standard (VCO) locally available. ... phase of the local secondary standards to the 10-min average of the phase of ... I3a - - \\.-e-~--. ...
... and high-quality photospheric-phase Type II SN spectra to constrain core- collapse SN explosions, massive star evolution, and distances in the Universe ...
The aim of this paper is to present the phase-space properties of the systems that contain bradyons, luxons and tachyons. It is shown that particularly at low energy, these properties are quite different from the well-known properties of bradyons.
The morphological aspects of ternary phase formation during the Pd-GaAs reaction have been studied by application of transmission electron microscopy (TEM) and Rutherford backscattering (RBS) techniques. The TEM images show that the first product phase, ''phase I'', forms during deposition of Pd onto (100) GaAs and exhibits the preferred orientation (0001)/sub I/ approx. // (01 anti 1)/sub GaAs/. In the presence of unreacted Pd, the second phase, ''phase II'', nucleates at large-angle grain boundaries in the phase I film as the annealing temperature increases above approx.250C. Energy dispersive analysis of x-rays and RBS suggest the nominal compositions Pd3GaAs and Pd4GaAs for phases I and II, respectively.
Halothane, chloroform, and carbon tetrachloride, in the vapor and liquid phases, stimulate the water receptor of the blowfly Phormia regina. There are three successive phases of response to long-lasting...Full Text Available
This study aims to investigate the difference in the interaction of antimicrobial peptides with two classes of zwitterionic peptides, phosphatidylethanolamines (PE) and phosphatidylcholines (PC). Further experiments were performed on model membranes prepared from specific bacterial lipids, lipopolysaccharides (LPS) isolated from Salmonella minnesota. The structure of the lipid-peptide aqueous dispersions was studied by small-and wide-angle X-ray diffraction during heating and cooling from 5 to 85 C. The lipids and peptides were mixed at lipid-to-peptide ratios 10-10000 (POPE and POPC) or 2-50 (LPS). All experiments were performed at synchrotron soft condensed matter beamline A2 in Hasylab at Desy in Hamburg, Germany. The phases were identified and the lattice parameters were calculated. Alamethicin and melittin interact in similar ways with the lipids. Pure POPC forms only lamellar phases. POPE forms lamellar phases at low ...
In order to understand the detail transient two-phase flow structure, more advanced two-phase flow instrumentation is required. One advanced technique for flow visualization is real-time neutron radiography. Reconstruction method of visualized radiographic image of liquid metal two-phase flow generated by the real-time neutron radiography system is proposed in this paper. Image processing techniques for noise reduction and image enhancement are discussed in detail. (author).
In order to understand the detail transient two-phase flow structure, more advanced two-phase flow instrumentation is required. One advanced technique for flow visualization is real-time neutron radiography. Reconstruction method of visualized radiographic image of liquid metal two-phase flow generated by the real-time neutron radiography system is proposed in this paper. Image processing techniques for noise reduction and image enhancement are discussed in detail. (author).
Outline: Discuss far-side weld problem and phased array techniques applied. Describe laboratory work on flawed piping specimens using L- and S-wave arrays and provide synopsis of results. Discuss conclusions ofr capability of phased array as applied to austenitic welds. Research Approach: Evaluate phased arrays on unifornly-welded piping specimens. Apply best methods to non-uniform welds. Correlate acoustic responses as function of weld microstructures.
In a three-phase tri-axial cable, the magnetic interaction between the phases makes the loss measurement by an electromagnetic method very complex. We developed the theoretical background showing that three-phase AC loss measurements by the electromagnetic method are, in principle, possible. We then implemented this theory in practical measurements on a 3 m long, tri-axial cable fabricated from RABiTS (rolling-assisted biaxially textured substrate) coated conductor. Initially, the proposed measurement technique was implemented in the simpler cases when the three cable phases are 180"0 out of phase, i.e. (0"0, 180"0, 360"0) or (0"0, 360"0, 180"0) rather than (0"0, 120"0, 240"0) as in a traditional three-phase system. For these cases, the currents in the phases are either in phase (360"0 phase ...
This paper describes phase-retrieval approaches in music by focusing on the particular case of the cyclic groups (beltway problem). After presenting some old and new results on phase retrieval, we introduce the extended phase retrieval for a generalized musical Z-relation. This concept is accompanied by mathematical definitions and motivations from computer-aided composition. We assume from the reader basic knowledge of groups, topological groups, group algebras, group actions, Lebesgue integration, convolution products, and Fourier transform.
The results of real-time neutron diffraction measurements during the superconducting phase formation process in the Bi(Pb)-Sr-Ca-Cu-O system are reported. A Sr-Ca-Cu-O type precursor, with the same stoichiometry as the 2223 phase, was used as starting material, and the temperature range favorable to the formation of the 2223 phase was investigated. The diffraction patterns were processed by a multiphase Rietveld refinement. The formation and decomposition of the 2201 and 2212 phases were directly observed. Experimental evidence on the existence of a partially melted phase in the range 855-860[degrees]C, involved in the formation of the 2223 phase, is discussed. 14 refs., 9 figs., 1 tab.
The results of real-time neutron diffraction measurements during the superconducting phase formation process in the Bi(Pb)-Sr-Ca-Cu-O system are reported. A Sr-Ca-Cu-O type precursor, with the same stoichiometry as the 2223 phase, was used as starting material, and the temperature range favorable to the formation of the 2223 phase was investigated. The diffraction patterns were processed by a multiphase Rietveld refinement. The formation and decomposition of the 2201 and 2212 phases were directly observed. Experimental evidence on the existence of a partially melted phase in the range 855-860 degrees C, involved in the formation of the 2223 phase, is discussed. 14 refs., 9 figs., 1 tab.
Apart from conventional phase transitions driven by the thermal effects, quantum phase transitions generated by quantum fluctuations have their own mechanisms that are reflected in critical phenomena. Quantum phase transitions have an origin from spontaneous symmetry breaking commonly to thermal phase transitions. Even in this case, inherent quantum fluctuations substantially modify and yield new aspects. Quantum phase transitions have, however, another mechanism caused by topology changes, which gives completely new characters. Recently, a mechanism which connects these two has been found. Proimities from first-order transitions and phase separatins as well as from multiphase coexistence also generate characteristic and unconventional quantum criticalities. Understanding novel quantum criticalities offers a firm basis of recent active researches on fields such ...
Here we reported a two-step procedure for preparing a novel polymeric based solid-solid phase change heat storage material. Firstly, a copolymer monomer containing a polyethylene glycol monomethyl ether (MPEG) phase change unit and a vinyl unit was synthesized via the modification of hydrogen group of MPEG. Secondly, by copolymerization of the copolymer monomer and phenyl ethylene, a novel polymeric based solid-solid phase change heat storage material was prepared. The composition, structure and properties of the novel polymeric based solid-solid phase change material were characterized by IR, "1H NMR, DSC, WAXD, and POM, respectively. The results show that the novel polymeric based solid-solid phase change material possesses of excellent crystal properties and high phase change enthalpy.
A new technique has been developed for the measurement of steam mass flowrate, water mass flowrate and total enthalpy of two-phase fluids produced from geothermal wells. The method involves precisely metered injection of liquid and vapor phase tracers into the two-phase production pipeline and concurrent sampling of each phase downstream of the injection point. Subsequent chemical analysis of the steam and water samples for tracer content enables the calculation of mass flowrate for each phase given the known mass injection rates of tracer. This technique has now been used extensively at the Coso geothermal project, owned and operated by California Energy Company. Initial validation of the method was performed at the Roosevelt Hot Springs geothermal project on wells producing to individual production separators equipped with orificeplate flowmeters for each ...
Lithium ammonium sulfate (LAS) undergoes a phase transition at Tsub(c1) = 459.5deg K from a paraelectric phase (phase 1) to a ferroelectric phase (phase II) and again at Tsub(c2) = 283deg K to a polar ferroelastic phase (phase III). Proton spin lattice relaxation investigations in the temperature range 480-77deg K at 10 MHz show discontinuous changes in Tsub(1) at the transition temperatures, indicating first order phase transitions. The absence of the slow motion region (#omega#sub(not)tausub(not)>>1) shows that the ammonium ions are reorienting fast enough to keep the resonance absorption line narrow down to liquid nitrogen temperatures. The possibility of a second minimum and a low activation energy, Esub(a) = 2.659 kcal/mole, in phase III suggest the possibility of tunnelling of the protons ...
Phase transformations occuring during cold deformation in hardened #alpha#+#beta# titanium alloy of the Ti-Al-Mo-Zr-Sn-Si system with 10% summary content of alloying elements are studied by X-ray diffraction analysis. Two stages of trapsformation of metastable #alpha#''-phase are found. A conclusiop is made that ability of the alloy containing #alpha#''-phase to cold deformation is determined by the presence of favourable texture, by high degree of metastability and by volume portion of #alpha#''-phase in the alloy structure.
In FY 1984 three specific tasks which are all related to not-well-understood two-phase phenomena of importance to LWR accidents have been identified under the program. These three tasks are: (1) inverted annular flow experiments and modeling; (2) hot leg U-bend two-phase flow simulation study; and (3) development and evaluation of two-phase flow scaling criteria. Some of the important results obtained under Tasks (1) and (2) are reported in this paper.
The author shows in this paper an interesting relation between elementary and topological excitations in the antiferromagnetic and d-wave superconducting phases of the t-J model at two dimensions. The topological spin and charge excitations in one phase have the same dynamics as elementary excitations in the other phase, except the appearance of energy gaps. Moreover, the transition from one phase to another can be described as a quantum disordering transition associated with the topological excitations. Based on the above picture, a plausible phase diagram of t-J model is constructed.
Crystal structure of monoclinic telluric acid ammonium phosphate (TAAP) has been studied by an X-ray diffraction method in the paraelectric phase at 333 K and in the ferroelectric phase at room temperature. It is confirmed that the space group in the paraelectric phase is P2/n. Comparison of the results between the two temperatures suggests that the plane which is made by the PO{sub 4} tetrahedron linked by hydrogen bonds has an important role for the ferroelectric phase transition. This plane is almost parallel to the direction of spontaneous polarization.
CIRNAT, a one-dimensional code for natural circulation analysis, was described. The homogeneous approach was adopted for the two-phase flow regime and different heat transfer regimes were considered. The code was exhaustively tested for one-phase flow systems. For two phase flows a boiling/condensing system was simulated. The results are qualitatively correct but the oscillations observed at the system were not captured by the model. Other two-phase flow tests must be done to show the limits of the homogeneous approach before the introduction of a more complex model. (author)
CIRNAT, a one-dimensional code for natural circulation analysis, was described. The homogeneous approach was adopted for the two-phase flow regime and different heat transfer regimes were considered. The code was exhaustively tested for one-phase flow systems. For two phase flows a boiling/condensing system was simulated. The results are qualitatively correct but the oscillations observed at the system were not captured by the model. Other two-phase flow tests must be done to show the limits of the homogeneous approach before the introduction of a more complex model. (author)
The Utility PhotoVoltaic Group (UPVG), supported by member dues and a grant from the US Department of Energy, has as its mission the acceleration of the use of cost-effective small-scale and emerging large-scale applications of photovoltaics for the benefit of electric utilities and their customers. Formed in October, 1992, with the support of the American Public Power Association, Edison Electric Institute, and the National Rural Electric Cooperative Association, the UPVG currently has 90 members from all sectors of the electric utility industry. The UPVG's efforts as conceived were divided into four phases: Phase 0--program plan; Phase 1--organization and strategy development; Phase 2--creating market assurance; and Phase 3--higher volume purchases. The Phase 0 effort developed the program plan and was completed early in 1993. The Phase 1 ...
The two-phase flow program is directed at understanding the hydrodynamics of two-phase flows. The two-phase flow regime is characterized by a series of flow patterns that are designated as bubble, slug, churn, and annular flow. Churn flow has received very little scientific attention. This lack of attention cannot be justified because calculations predict that the churn flow pattern will exist over a substantial portion of the two-phase flow zone in producing geothermal wells. The University of Houston is experimentally investigating the dynamics of churn flow and is measuring the holdup over the full range of flow space for which churn flow exists. These experiments are being conducted in an air/water vertical two-phase flow loop. Brown University has constructed and is operating a unique two-phase flow research facility specifically designed to address flow ...
Commissioning of a Pressurized heavy water reactor (PHWR) plant of NPCIL involves three phases viz phase-A which consist of pre-criticality activities such as hydro test, air hold test, no load test of motors etc., phase-B consist of criticality and post criticality physics experiments. The phase-C, which is considered the major phase, consist of initial power raise to about 10 % , TG rolling, synchronization, going to significant power in steps and performance tests such as load rejection tests from various power levels. In order to have smooth commissioning for the Phase-C, an integrated team consisting of engineers from various design and analysis groups of NPCIL headquarters was formed to participate along with site O and M engineers, closely observe and coordinate phase-C commissioning activities. During this commissioning some major ...
In order to study the two-phase natural circulation and flow termination during a small break loss of coolant accident in LWR, simulation experiments have been performed using two different thermal-hydraulic loops. The main focus of the experiment was the two-phase flow behavior in the hot-leg U-bend typical of BandW LWR systems. The first group of experiments was carried out in the nitrogen gas-water adiabatic simulation loop and the second in the Freon 113 boiling and condensation loop. Both of the loops have been designed as a flow visualization facility and built according to the two-phase flow scaling criteria developed under this program. The nitrogen gas-water system has been used to isolate key hydrodynamic phenomena such as the phase distribution, relative velocity between phases, two-phase flow regimes and flow termination mechanisms, whereas the Freon ...
We consider two-dimensional large N gauge theory with D adjoint scalars on a torus, which is obtained from a D+2 dimensional pure Yang-Mills theory on T^{D+2} with D small radii. The two dimensional model has various phases characterized by the holonomy of the gauge field around non-contractible cycles of the 2-torus. We determine the phase boundaries and derive the order of the phase transitions using a method developed in an earlier work (hep-th/0910.4526), which is nonperturbative in the 'tHooft coupling and uses a 1/D expansion. We embed our phase diagram in the more extensive phase structure of the D+2 dimensional Yang-Mills theory and match with the picture of a cascade of phase transitions found earlier in lattice calculations (hep-lat/0710.0098). We also propose a dual gravity system based on a Scherk-Schwarz compactification of a D2 brane wrapped on a ...
Based on a recently introduced phase X-ray imaging approach, a dual-detector prototype was developed for in-line X-ray phase imaging and phase retrieval utilizing a micro-focus X-ray source and two computed radiography (CR) cassette detectors. The system was built on a horizontal optical rail to facilitate manual adjustment of the positions of the X-ray source, the sample and the detectors. The novel design of the detector-1 is essential, it detects a portion of radiation to form an attenuation image; allows the rest of radiation to reach the detector-2 to form a phase contrast image, and the two images are used to retrieve a phase map. The two detectors are balanced for optimal phase-retrieval with reasonable radiation dose to the object to be imaged. The system was examined in terms of the linearity, the fractions of the X-ray photons detected by the two ...
We report on a hard X-ray phase imaging microscopy (a phase-difference microscopy) that consists of an objective and a transmission grating. The simple optical system provides a quantitative phase image, and does not need a wave field mostly coherent on the objective. Our method has a spatial resolution almost same as that of the absorption contrast microscope image obtained by removing the grating. We demonstrate how our approach provides a phase image from experimentally obtained images. Our approach is attractive for easily appending a quantitative phase-sensitive mode to normal X-ray microscopes, and has potentially broad applications in biology and material sciences.
The application of multi-objective genetic algorithms for green building design in two phases were presented in order to better help designers in the decision-making process. The purpose is to minimize two conflicting criteria: the life-cycle cost and the life-cycle environmental impact. Environmental impact criteria examined include energy and non-energy natural resources, global warming, and acidification. Variables focus on building envelope-related parameters. The application of multi-objective genetic algorithms is divided into two phases. The first phase intends to help designers in understanding the trade-off relationship between the two conflicting criteria. The second phase intends to refine the performance region that is of the designer's interest. The results after the two-phase application of the multi objective genetic algorithm were then presented. 13 refs., 4 ...
A series of #alpha#-sialon (#alpha#') compositions containing mixed stabilising cations were prepared, by introducing additional CaO to a basic Sm #alpha#-sialon compositions. The thermal stability of these Sm-Ca-containing #alpha#-sialon phases was investigated using XRD, SEM and EDXS techniques. It was found that the addition of calcium into the Sm #alpha#-sialon systems greatly improved the stability of the #alpha#-sialon phases. Calcium was found to be incorporated into the #alpha#-sialon structure, coexistent with the samarium, and partitioning of the calcium and samarium was observed between the #alpha#' phase and grain boundary phases. This indicates a technique which may be used to improve the thermal stability of the #alpha#' phase while maintaining good refractory phases at the sialon grain boundaries.
A simple tube-in-tube heat exchanger system for thermal energy storage employing stearic acid as PCM has been investigated. The performance and heat transfer characteristics of such a system were studied. Phase transition temperature range and times were measured and the speed of the phase transition front was computed. The melting front was found to move in the radial direction inward as well as in the axial direction from the top toward the bottom of the phase change material PCM tube. The speed of the melting front is enhanced by a convection heat transfer mechanism in the melted PCM. The heat transfer rate and, consequently, phase transition time can be altered by changing the water inlet temperature to the heat exchanger. In addition, a faster phase transition is realized by placing the heat exchanger in a horizontal position rather than a vertical one. (Author)
The advent, in the near future, of compact X-ray sources like Thomson Back-Scattering (TBS) will allow the clinical application of advanced X-ray imaging techniques, such as phase contrast, with higher sensitivity and lower impact in terms of dose delivery. In this work, we theoretically investigated the possibility of using such sources for phase contrast imaging of micro-calcifications included in a breast tissue. In our study we analyzed the phase and amplitude distribution of the TBS source and we showed that this source can be used for phase contrast imaging since the source coherence at the sample position is sufficiently high for achieving good contrast and micrometer spatial resolution. Indeed the spatial coherence of a TBS source is closer to that of a synchrotron radiation source, and much better than that of a laboratory source. Moreover, we showed the advantages of phase ...
Ternary diagrams are commonly used to provide a graphic representation of equilibrium fluid phase behavior for systems as diverse as distillation columns and miscible gas floods of oil reservoirs. The phase envelope, and the position of the critical point on it, are important to enhanced oil recovery engineers who are involved with miscible gas flood design. In the past, phase equilibrium data were laboriously plotted on the ternary diagram and special graphic techniques were utilized to locate the critical point on the phase envelope. This work presents a computerized curve fitting method to generate the phase envelope from a given set of phase equilibrium data and then use the tie-line slopes to position the critical point. Experimental data are included and show excellent agreement with this new method.
Ternary diagrams or pseudo ternary diagrams are commonly used to provide a graphical representation of equilibrium fluid phase behavior for systems as diverse as distillation columns and miscible gas floods of oil reservoirs. The phase envelope and the position of the critical point on it are important to enhanced oil recovery engineers who are involved with miscible gas flood design. In the past, phase equilibrium data were laboriously plotted on the pseudo ternary diagram and special graphical techniques were utilized to locate the critical point on the phase envelope. Presented in this article is a computerized curve fitting method to, firstly, generate the phase envelope from a given set of phase equilibrium data and then use the 'tie-line slopes' to position the critical point. Experimental data are included and show excellent agreement ...
Recently the authors showed that tetrazolium salts can be obtained during the oxidation of substituted 1,3,5-triarylformazans with potassium permanganate in a two-phase organic solvent-water system. The role of phase-transfer catalyst in this reaction is played by the tetrazolium salt, which is formed in a small amount as the result of oxidation of the formazan at the phase boundary. The method is distinguished by its extreme simplicity. However, the yield of the tetrazolium salts fluctuates within wide limits and does not exceed 62%. This is due to the fact that as the reaction proceeds the pH of the aqueous phase increases from 6 to 12. At the same time it is known that tetrazolium salts are unstable in aqueous alkaline solutions. They found that if the aqueous phase is replaced by aqueous hydrochloric acid (5 wt. %) the yields of the tetrazolium salts (Ia-g) are increased to ...
The magnitude of electric and magnetic fields around a high voltage three-phase transmission line was studied. A three-phase transmission circuit with parallel conductors produces rotating elliptic electric and magnetic fields. This study investigated the optimum arrangement of the phase conductors to minimize the maximum value of the magnetic flux density and to minimize the intensity of the resultant electric field. Two different types of high voltage double circuit transmission lines of 400 kV were considered. The optimum arrangement of the phase conductors was determined. It was concluded that the optimum arrangement can be easily applied to already constructed high voltage transmission lines by properly interchanging the phase conductors at the substations. 10 refs., 1 tab., 4 figs.
The magnitude of electric and magnetic fields around a high voltage three-phase transmission line was studied. A three-phase transmission circuit with parallel conductors produces rotating elliptic electric and magnetic fields. This study investigated the optimum arrangement of the phase conductors to minimize the maximum value of the magnetic flux density and to minimize the intensity of the resultant electric field. Two different types of high voltage double circuit transmission lines of 400 kV were considered. The optimum arrangement of the phase conductors was determined. It was concluded that the optimum arrangement can be easily applied to already constructed high voltage transmission lines by properly interchanging the phase conductors at the substations. 10 refs., 1 tab., 4 figs.
A localization criterion for the crystal-liquid phase transition (PT) is suggested, according to which the PT starts when the ratio E d/k B T reaches a boundary value E d(s)/k B T m, above which a solid phase, and below which, a liquid phase is located in the phase diagram. Here, E d is the energy of the delocalization of an atom, k B is the Boltzmann constant, T is the temperature, and E d(s) is the energy of delocalization for the solid phase at the melting point T m. It is shown that this criterion extends the Lindemann criterion of melting to the case of crystallization, and the L?ven criterion of crystallization to the case of melting. It is shown that the localization criterion suggested is applicable both for the normally melting substances and for the substances melting with a decr...
A localization criterion is proposed for the crystal-liquid phase transition (PT). According to this criterion, the PT begins when the E d/k b T ratio reaches a boundary value E d(s)/k b T m such that a solid phase is present above it and a liquid phase is present below it in a phase diagram. Here, E d is the energy of atom delocalization, k b is the Boltzmann constant, T is the temperature, and E d(s) is the delocalization energy for a solid phase at melting point T m. This criterion is shown to generalize the Lindemann criterion of melting to the case of crystallization and the L?ven criterion of crystallization to the case of melting. This localization criterion is found to be applicable for both normally melting substances and substances that melt with a decrease in the specific volume...
Adjustment of the rf phase in a linear accelerator is crucial for maintaining optimal performance. If phasing is incorrect, the beam will in general have an energy error and increased energy spread. While an energy error can be readily detected and corrected using position readings from beam position monitors at dispersion locations, this is not helpful for correcting energy spread in a system with many possible phase errors. Uncorrected energy spread results in poor capture efficiency in downstream accelerators, such as the Advanced Photon Source's (APS's) particle accumulator ring (PAR) or booster synchrotron. To address this issue, APS has implemented beam-to-rf phase detectors in the linac, along with software for automatic correction of phase errors. We discuss the design, implementation, and performance of these detectors and how they improved APS top-up ...
An iterative phase retrieval algorithm was previously investigated for in-line x-ray phase imaging. Through detailed theoretical analysis and computer simulations, we now discuss the limitations, robustness, and efficiency of the algorithm. The iterative algorithm was proved robust against imaging noise but sensitive to the variations of several system parameters. It is also efficient in terms of calculation time. It was shown that the algorithm can be applied to phase retrieval based on one phase-contrast image and one attenuation image, or two phase-contrast images; in both cases, the two images can be obtained either by one detector in two exposures, or by two detectors in only one exposure as in the dual-detector scheme.
The transformation mechanism of hexagonal delta phase from the disordered bcc gamma phase has not been reported before in the Zr-rich U-Zr alloy system. With the help of X-ray diffraction, transmission electron microscopy (TEM) and high-resolution TEM analyses it was shown that the gamma to delta conversion takes place by the lattice collapse mechanism of omega transformation. It was also ascertained that a higher aging temperature or time promotes the growth of all four variants of the delta phase within a parent gamma grain. In addition, ab initio electronic structure calculations showed that the bcc to hexagonal transformation, involving partial ordering of the parent bcc phase followed by (111) plane collapse, is energetically favorable.
A survey is presented of the principles and practice of tailoring sintering liquid composition and processing cycle to enable crystallisation of intergranular phases in silicon nitride and sialon ceramics. Critical features in sialon ceramics are the O/N balance in residual glasses and post-sintering heat-treatment temperatures to enable nucleation of either intermediate phases at constant composition or oxide phases with re-partitioning of non stoichiometric components in #beta#' or #alpha#' solid solutions. Crystallisation of disilicate phases in non-sialon compositions exemplifies a problem in control of polymorphs with differing atomic volumes. Crystallisation of intergranular phases has an influence mainly on high-temperature mechanical and environmental behaviour of these ceramics. (orig.).
Various measurement tools that are used in chaos theory were applied to analyze two-phase pressure signals with the objective of identifying and interpreting flow pattern transitions for two-phase flows in a small, horizontal rectangular channel. These measurement tools included power spectral density function, autocorrelation function, pseudo-phase-plane trajectory, Lyapunov exponent,s and fractal dimensions. It was demonstrated that the randomlike pressure fluctuations characteristic of two-phase flow in small rectangular channels are chaotic, and governed by a high-order deterministic system. The correlation dimension is potentially a new approach for identifying certain two-phase flow patterns and transitions.
Phase contrast X-ray imaging has been studied intensively using X-rays from synchrotron radiation and micro-focus X-ray tubes. However, these studies have revealed the difficulty of this technique's application to practical medical imaging. We have created a phase contrast imaging technique using a molybdenum X-ray tube with a small focal spot size for mammography. We identified the radiographic conditions in phase contrast magnification mammography with a screen-film system, where edge effect due to phase contrast overcomes geometrical unsharpness caused by the 0.1 mm-focal spot of a molybdenum X-ray tube. The edge enhancement due to phase imaging was observed in an image of a plastic tube, and then geometrical configuration of the X-ray tube, the object and the screen-film system was determined for phase imaging of mammography. In order to investigate a ...
This paper describes a long term course of research into the fundamentals of two phase flow regime dynamics that had lead to a differential description of regime properties. The development has included experiment, microscale simulation, and mathematical averaging to produce a dynamic equation for interfacial area.
Staphylococcus aureus preferentially catabolizes glucose, generating pyruvate, which is subsequently oxidized to acetate under aerobic growth conditions. Catabolite repression of the...Full Text Available
The amorphization of a quenched sample of the GaSb-II high-pressure phase was studied at ambient pressure by real-time neutron diffraction in the course of the sample heating from 100 K to room temperature at a rate of 0.4 K min{sup -1}. The transformation to the amorphous state begins at 140 K and is completed near room temperature. The {beta}-Sn type structure was shown to represent only the mean lattice of the high-pressure GaSb-II phase. The superstructure of this phase widely varied with temperature and is caused by the ordered displacement of atoms. The temperature range of the metastable crystalline phase relaxation is divided into three intervals according to the temperature dependence of the tetragonality ratio (c/a). At the boundaries of these temperature intervals, i.e. temperatures T = 170 and 230 K, two second-order phase transitions are observed. Anomalous heat and ...
The amorphization of a quenched sample of the GaSb-II high-pressure phase was studied at ambient pressure by real-time neutron diffraction in the course of the sample heating from 100 K to room temperature at a rate of 0.4 K min-1. The transformation to the amorphous state begins at 140 K and is completed near room temperature. The ?-Sn type structure was shown to represent only the mean lattice of the high-pressure GaSb-II phase. The superstructure of this phase widely varied with temperature and is caused by the ordered displacement of atoms. The temperature range of the metastable crystalline phase relaxation is divided into three intervals according to the temperature dependence of the tetragonality ratio (c/a). At the boundaries of these temperature intervals, i.e. temperatures T = 170 and 230 K, two second-order phase transitions are observed. Anomalous heat and volumetric ...
The flow of water through a dam of fairly arbitrary shape is examined in the limit of large frictional drag on the flow. The relation of the problem to the one-phase Stefan problem and a problem of anodic smoothing is explored. Monotonicity and uniqueness...
Phosphoramidite reagents can phosphitylate guanine bases at the O6-position during solid phase synthesis and serious chain cleavage occurs if the base phosphitylation is not eliminated before the iodine/water...Full Text Available
It is shown that calculation of the anomalous expectation values for the massless Gross-Neveu model in the Hartree-Fock approximation indicates the presence of an ordinary chiral phase transition if the coupling constant has the normal sign (g > 0) and of a different transition of the superconductivity type if g < 0.
A detailed comparative assessment was made of the use of solid-phase-coupled antibodies in radioimmunoassay, by using an assay for human placental lactogen as a model system. The major advantages of...Full Text Available
Anatomical specimens and normal persons were studied by gradient echo MR imaging to determine the influence of different echo times (TE) on bone marrow contrast. First of all, six normal persons were studied to determine specific echo times for in-phase and opposed-phase states. Using different sequences bone marrow contrast in isolated femoral bones was determined and compared to results of pathological exams. Red bone marrow had no signal on opposed-phase images; contrast between red and yellow marrow was higher on opposed-phase than on in-phase images. Bone marrow lesions can be expected to be visualised with high signal on opposed-phase images; this technique should be especially suited for MR imaging of bone marrow. (orig.).
[Leu]- and [Met]enkephalin from thoracic ganglia of the shore crab Carcinus maenas have been purified to homogeneity by a reversed-phase HPLC procedure. Automated gas-phase sequencing revealed a primary...Full Text Available
The three-dimensional (3-D), multiphase, computational fluid dynamic (CFD) code FLUENT is used to simulated two-phase flow behaviour in a CANDU header manifold under low (natural circulation) flow conditions. This behaviour was previously inferred from experimental data. The CFD simulations reported here are being used to support these inferences and to obtain a better understanding of phase distribution in the header manifold. The simulations seem to show that the vapor-water mixture models in the FLUENT code do not capture properly phase separation in the header and proper phase branching at the header-feeder connections that have been observed in experiments at low flows. The simulations using discrete-phase model in FLUENT, which tracks the pathlines of the individual vapor bubbles in the water continuum phase, show interesting, complicated and, in some ...
During Phase II multi-junction solar cell will be grown on the large grain thin film produced during Phase I on flexible/low cost metal foil substrate. ...
The effect of growth phase on expression of virulence-associated factors was studied by Northern hybridization in an M1T1 clinical isolate of Streptococcus pyogenes. Expression of M...Full Text Available
This cost-effectiveness analysis supports the proposed effluent limitations guidelines and standards for the Metal Products and Machinery Industry (MP and M) Phase I Industry. The report assesses the cost-effectiveness of five regulatory options for indir...
To attain reproducible and stable contacts to compound semiconductor devices, it is necessary to achieve thermodynamically stable phases after the reaction of metals with the compound semiconductor. In this study, the final phases produced by the reactions between GaAs and thin metal films of Co, Rh, Ir, Ni, Pd, and Pt have been investigated. They are identified as MGa for M = Co, Rh, Ni, Pd, and Pt, monoarsenides of Co and Ni, diarsenides of Rh, Ir, Pd, and Pt, and Ir/sub 3/Ga/sub 5/. These phases, if deposited directly onto GaAs, will produce thermally stable contacts. In addition to the identification of these stable phases, analyses of the products of thin-film M/GaAs reactions by transmission electron microscopy, x-ray diffraction, and Rutherford backscattering spectrometry reveal the distribution, grain size, and crystallographic texture of these end phases. Trends in these ...
A solid-phase radioimmunoassay employing 125I-labeled enterotoxins and polystyrene tubes coated with specific antibody has been developed for assaying the relative concentrations of antibodies...Full Text Available
The polymorphic phase behavior of a homologous series of n-saturated 1,2-diacyl phosphatidylethanolamines was investigated by differential scanning calorimetry, 31P-nuclear magnetic resonance, and Fourier...Full Text Available
The Δ- and Λ-isomerism of octahedral metal complexes is employed as a source of chirality for inducing chiral nematic phases. By applying a wide range of chiral metal complexes as a...Full Text Available
The main objective of Phase I of this SBIR project was to demonstrate the feasibility for successful development of an antimicrobial wound dressing based on a hydrogel sustained release matrix. This goal has been achieved. In vitro studies of drug diffusi...
A safety analysis code to design a pressurized water reactor and to obtain the licenses including entire proprietary rights is under development in domestic R and D project. The tasks of KAERI is to develop the constitutive relations including models for defining flow regimes and flow regime related models for inter-phase friction, wall frictions, wall heat transfer, and interphase heat and mass transfer in the two-phase three-field equations. In this paper, the process will be presented for choosing the best flow regime maps which occur in gas-liquid two-phase flow in horizontal and vertical tubes.
A safety analysis code to design a pressurized water reactor and to obtain the licenses including entire proprietary rights is under development in domestic R and D project. The tasks of KAERI is to develop the constitutive relations including models for defining flow regimes and flow regime related models for inter-phase friction, wall frictions, wall heat transfer, and interphase heat and mass transfer in the two-phase three-field equations. In this paper, the process will be presented for choosing the best flow regime maps which occur in gas-liquid two-phase flow in horizontal and vertical tubes.
The phase space beam analyzer is a measurement instrument that is applied in laser technology to perform analyses of the spatial and angular distribution of rays. We are interested in this instrument as a means to characterize non-coherent light sources. In this context, a closer look at the tolerances of this optical instrument was considered useful. Having a so-called quadrupole lens as a key element, the phase space beam analyzer is a device that features anamorphic optical properties. To describe these anamorphic properties, recurrence was made to a description by extended ray-transfer matrices. This formalism allows for an analysis of the alignment tolerances of the phase space beam analyzer and facilitates a study of the sensitivities of the instrument. The analysis is complemented using numerical ray tracing.
Heat transfer and flow characteristics of water boiling flow were experimentally investigated in narrow horizontal rectangular channels with the gaps of 0.6mm-2.03mm. The heat transfer of two-phase boiling flow was weakend in smaller gap. The two-phase friction pressure drop decreased with the gap size and the two-phase friction multipliers were smaller compared with those in normal channels. Correlations to predict te boiling heat transfer coefficients were obtained. (author)
The GERDA experiment is located in the underground Gran Sasso laboratory. The experiment aims at studying the neutrinoless ?? decay of 76Ge. The implementation of the experiment is divided in two consecutive phases. Phase I will allow within one year of data taking to reach a sensitivity limit for the half life of the process of the order of Formula Not Shown years. Phase II, with an increased amount of active material and a background index lower by one order of magnitude than in Phase I, will allow to reach a half life limit of about Formula Not Shown years. In the present paper a brief review of the status of the experiment and its perspectives is given.
... as time delay shifters for large-area phased arrays in military (MILSTAR) as well as commercial (Sky phone and other satellite communication) systems, ...
The authors attemps to confirm a modification of the phase-absprotion method applicable to the study of the decay rate of energy stored in the upper level in the active medium of a CO/sub 2/-laser. The essence of the method is described. Relationships are determined which allow one to obtain the unknown parameters of the experimentally measured phase shift. The work exeprimentally shows the possibility of studying vibratioanl relaxation in the active medium of a CO/sub 2/-laser by the phase-absorption method using both ordinary and isotope-substitued molecules.
In reservoir fluid flow, the situation described by an increase in nonwetting phase saturation followed by an increase in wetting phase saturation causes a relative permeability hysteresis effect that is well known. This paper presents a method which allows the calculation of imbibition relative permeability starting at any saturation. The data required are the drainage curve, the historical maximum non wetting saturation, and a minimum of one additional point on some corresponding experimental imbibition curve. In this development, all imbibition curves are shown to be parallel. Also significant is the fact that the residual nonwetting phase saturation can be calculated without a complete experimental specification of the imbibition curve. 5 refs.
The wide-angle neutron diffractometer recently installed at the HFIR has the capability of performing time-resolved or time-slicing measurements. One of the interesting problem areas the authors have explored using this time-slicing function of the diffractometer is the kinetics of structural changes occurring after a temperature jump across a value at which a first-order phase transition occurs. Two measurements of this sort have been carried out: the phase III to II transition in RbNO_3 and the transition between the alpha and beta phases in Sn.
A model of a solid disordered ortho-parahydrogen mixture with infinite long-range interaction J/sub ij/ between orthomolecules distributed in accordance with a normal law with first moment J/sub 0/ is investigated. It is shown that the introduction of an external electric field gradient ..gamma.. can give rise to a phase transition to an orientational phase. The possible existence of an orientational glass phase is established. The influence of the degeneracy of the hydrogen orthomolecules on the low-temperature thermal properties of these systems is demonstrated, and a condition of stability of the replica-symmetric solution is established. At low temperatures, this solution is stable for a large value of ..gamma.. or J/sub 0/.nctio
A possible novel application of hard x-ray emitted during laser-plasma interaction was discussed. The authors established an Optical Transform Function to study the joint effect of the spectral distribution and temporal profile of the laser-produced x-ray on x-ray phase imaging. Though the laser-produced x-ray pulse duration is short and incoherent, the analysis confirms that the current x-ray phase imaging theory still holds for laser-produced x-ray phase imaging
... Progress: For a one-dimensional two-phase degenerate Stefan problem, it was proved that the boundary and the solutions up to the boundary are C ...
A method of preparing a high temperature superconductor from an amorphous phase. The method involves preparing a starting material of a composition of Bi.sub.2 Sr.sub.2 Ca.sub.3 Cu.sub.4 Ox or Bi.sub.2 Sr.sub.2 Ca.sub.4 Cu.sub.5 Ox, forming an amorphous phase of the composition and heat treating the amorphous phase for particular time and temperature ranges to achieve a single phase high temperature superconductor.
The refractory nature and high ductility of body centered cubic (bcc) phase tantalum makes it a suitable material for corrosion- and wear-resistant coatings on surfaces that are subjected to high stresses and harsh chemical and erosive environments. Sputter deposition can produce thick tantalum films but is prone to forming the brittle tetragonal beta phase of this material. Efforts aimed at forming thick bcc phase tantalum coatings in both flat plate and cylindrical geometries by high-rate triode sputtering methods are discussed. In addition to substrate temperature, the bcc-to-beta phase ratio in sputtered tantalum coatings is shown to be sensitive to other substrate surface effects.
Weakly absorbing materials, such as biological, soft tissues, can be imaged by generating contrast due to the phase shift of X-rays. In the past decade, several methods for X-ray phase imaging were proposed and demonstrated. The performance of X-ray phase imaging is attractive in the field of medical imaging technology, and its development for practical use is expected. Many methods, however, have been developed under the assumption of the use of synchrotron radiation, which is an obstacle to practical use. The method based on Talbot (-Lau) interferometry enables us to use a compact X-ray source, and its development is expected as a breakthrough for medical applications. (author)
A theory of nonunitary-invertible as well as unitary canonical transformations is formulated in the context of Weyl's phase space representations. Exact solutions of the transformation kernels and the phase space propagators are given for the three fundamental canonical maps as fractional-linear, gauge and contact (point) transformations. Under the nonlinear maps a phase space representation is mapped to another phase space representation thereby extending the standard concept of covariance. This extended covariance allows Dirac-Jordan transformation theory to naturally emerge from the Hilbert space representations in the Weyl quantization.
We present results from ab-initio electronic-structure calculations of mechanical properties of the rhombohedral phase of vanadium reported in recent experiments (R Ia), and other predicted high-pressure phases (R Ib and bcc), focusing on properties relevant to dynamic experiments. We find that of the three transitions the largest volume collapse (1.3%) is for the R Ia to R Ib transition. Calculations of the single crystal and polycrystal elastic constants reveal a remarkably small discontinuity across the phase transitions even at zero temperature where the transitions are first order.
Corrosion testings of model alloys, corresponding by chemical composition to simple and complex-alloyed #gamma#- and #gamma#'-phases of nickel heat-resistant alloys are conducted in sodium sulfate and chloride melts. It is ascertained that heat resistant nickel alloys containing over 50 % of hardening #gamma#'-phase, are subject to disastrous sulfide corrosion (SC). Resistance against SC alloys containing below 50 % of #gamma#'-phase is determined by the resistance of #gamma#-solid solution. 10 refs., 3 figs., 2 tabs.
A method of using gamma radiation to determine the density and phase distribution in two-phase flows in pipes is described. Three collimated beams of radiation that pass through a pipe cross-section at different radial positions are used. A theory and computer program used to relate the measured attenuation of these beams to a three-parameter model of the phase distribution and to the average density and void fraction are discussed. Data obtained during both static and dynamic verification experiments using Lucite inserts are presented, as well as the results of several tests done in high pressure, steam-water flows.
A new high capacity anode composite based on mesoporous silicon is proposed. By virtue of a structure that resembles a pseudo one-dimensional phase, ...
We present both the theory and an experimental method to accurately set up a Guoy phase telescope, where both the output spot size and orthogonality condition are invariant to distance from the cavity beam waist. We demonstrate that Gaussian spot size measurements can be used as a diagnostic to determine the desired locations of split area photodetectors. The Guoy phase invariance is verified using the tilt-locking technique.
Purpose of the Phase I effort was to demonstrate feasibility of the fuel cell/battery system for powering a small bus (under 30 ft or 9 m) on an urban bus route. A brassboard powerplant was specified, designed, fabricated, and tested to demonstrate feasibility in the laboratory. The proof-of-concept bus, with a powerplant scaled up from the brassboard, will be demonstrated under Phase II.
The quantitative imaging of a phase object using 16 keV x-rays is reported. The theoretical basis of the techniques is presented along with its implementation using a synchrotron x-ray source. It is found that the phase image is in quantitative agreement with independent measurements of the object. 13 refs., 5 figs.
A method for the quantitative determination of atmospheric hydroperoxyl radical comprising: (a) contacting a liquid phase atmospheric sample with a chemiluminescent compound which luminesces on contact with hydroperoxyl radical; (b) determining luminescence intensity from the liquid phase atmospheric sample; and (c) comparing said luminescence intensity from the liquid phase atmospheric sample to a standard luminescence intensity for hydroperoxyl radical. An apparatus for automating the method is also included.
X-ray imaging is a very useful plasma diagnostic method. A theoretical analysis of the x-ray phase imaging in the method based on Fresnel diffraction is given. The authors show it is a linear band pass filter, a property suit for Rayleigh-Taylor (R-T) instability measurement. The evaluation permits the possibility of R-T instability measurement in x-ray phase imaging
After slow progress in the efforts to develop phase plates for electron microscopes, functional phase plate using thin carbon film has been reported recently. It permits collecting high-contrast images...Full Text Available
A method for bistable storage of binary optical information includes an antiferroelectric (AFE) lead lanthanum zirconate titanate (PLZT) layer having a stable antiferroelectric first phase and a ferroelectric (FE) second phase obtained by applying a switching electric field across the surface of the device. Optical information is stored by illuminating selected portions of the layer to photoactivate an FE to AFE transition in those portions. Erasure of the stored information is obtained by reapplying the switching field.
A mathematical model is proposed for three-phase filtering which is a particular case of a more general model of filtering multiple component mixtures and makes it possible to describe three-phase filtering flows under conditions where the pressure of saturation is variable in time and in space. In the proposed model, the system of unknown functions is selected so that it makes it possible to trace fairly simply the pressure of saturation and to compute the corresponding equation coefficients.
According to the present invention, a joined product is at least two ceramic parts, specifically bi-element carbide parts with a bond joint therebetween, wherein the bond joint has a metal silicon phase. The bi-element carbide refers to compounds of MC, M.sub.2 C, M.sub.4 C and combinations thereof, where M is a first element and C is carbon. The metal silicon phase may be a metal silicon carbide ternary phase, or a metal silicide.
Experiments were performed on horizontal air-water bubbly two-phase flow, axial flow, stratified wavy flow, and annular flow. Theoretical studies were also undertaken on interfacial parameters for a horizontal two-phase flow.
A large inguino-scrotal hernia was detected in the early phase of a radionuclide bone scan performed for evaluation of a femoral neck fracture not visualized on plain x-rays. The patient was administered 1 GBq of Scrotal scintigraphy using "9"9"mTc-MDP and a regional three-phase bone scan of the pelvis, hips and proximal femora was obtained on the gamma camera. Copyright (1999) Blackwell Science Pty Ltd
It if first shown, that the effective field of uniaxial magnetic anisotropy of Fe-Cr-P-C and Fe-Ni-B-Si system amorphous alloys is reduced with an increase of the source melt isothermal exposure time. The behaviour noted is conditioned by microcoherence and relaxation processes in the nonequilibrium liquid phase after crystal-liquid phase transition.
Heat transfer augmentation by straight grid spacers in rod bundles is studied for single phase flow and for post critical heat flux dispersed flow. The heat transfer effect of swirling grid spacers in single phase flow is also examined. Governing heat transfer mechanisms are analyzed, and predictive formulations are established. For single phase flow, the local heat transfer at a straight spacer and at its upstream or downstream locations are treated separately. 18 refs.
Phased array provides many advantages over conventional ultrasonic testing method, but phased array has also limitations. This paper describes typical results of the experimental sound field analysis generated from the array probe. A photo-elastic ultrasonic visualization technique was applied in this study. The sound fields of shear wave generated from the array probe was equivalent to that from the fixed angle probe. (author)
Previous studies demonstrated that perinatal exposure to polybrominated diphenyl ethers (PBDEs), a major class of brominated flame retardants, may affect thyroid hormone (TH) concentrations by inducing...Full Text Available
The objective of the program is to develop a domestic cooktop with low NOx emissions and higher efficiency. During the first phase of the program, a developmental prototype incorporating four IR-Jet burners was assembled. The report describes the work performed during the second phase of the program and covers optimization, and testing of the developmental prototype and design, fabrication and testing of the field-test prototype.
This report presents the methodologies and results of the field/laboratory experiments and mathematical modeling defined for the phase III of the project. Results from test cases 2-6 are given in separate chapters of the report (which have been indexed separately), and the last chapter discusses the lessons learned from the three phases of the DECOVALEX project.
Several aspects of heat transfer at the annular two phase flow regime are considered. Nucleate boiling is supposed to be absent. Theoretical solutions for cases of laminar and turbulent flow in the liquid film, respectively, are considered, when steam presence does not effect the heat transfer. Heat transfer in annular flows is also considered, where steam phase consists totally or partially of the so-called incondensable gas. In this case steam phase can be a considerable resistance to heat transfer.
The accelerating flow of a lighter continuous phase through a heavier one is considered. Small nonuniformities grow into large ones due to the Rayleigh-Taylor instability. An experiment exemplifying the large bubble formation due to Rayleigh-Taylor instability was performed and simulated using the PHOENICS 84 computer code. The same numerical procedure was applied to the two-phase flow in a gun barrel. It shows that the acceleration provided by the movement of the projectile can cause initial nonuniformities to grow with time.
Cyclin-Dependent Kinase 1 (CDK1) is the major M-phase kinase known also as the M-phase Promoting Factor or MPF. Studies performed during the last decade have shown many details of how CDK1 is regulated...Full Text Available
We present in this paper the computer code BACCHUS, to analyze the thermal-hydraulics in a rod bundle in single or two-phase flow regime. The model is 2-D and uses the porous body approach. The two-phase model is an extension of the classical homogeneous model, and includes a differential non-equilibrium equation. Results are shown for the extension of the boiling region in a 19-pin bundle.
We present in this paper the computer code BACCHUS, to analyze the thermal-hydraulics in a rod bundle in single or two-phase flow regime. The model is 2-D and uses the porous body approach. The two-phase model is an extension of the classical homogeneous model, and includes a differential non-equilibrium equation. Results are shown for the extension of the boiling region in a 19-pin bundle. (orig.).
Phase-contrast imaging with a practical cone-beam X-ray tube has been realized for clinical use in digital mammography using computed radiography (CR). To perform phase-contrast imaging, the X-ray detector must be distanced from an object so that the phase-contrast image achieves magnification; in a mammography unit dedicated to phase-contrast imaging, the magnification ratio is 1.75. When using an X-ray tube with a 0.1-mm focal spot, it appears that the penumbra in magnification blurs both projected images and the phase contrast, which generates an edge effect. However, where the sampling pitch of the CR plate is 43.75 {mu}m, the blur stretches the width of the phase contrast so that unit pixels in the detector can capture it. Note that the width of an ideal phase contrast using an X-ray point source results in a phase ...
Flow-induced vibration is an important concern to the designers of heat exchangers subjected to high flows of gases or liquids. Two-phase cross-flow occurs in industrial heat exchangers, such as nuclear steam generators, condensers, and boilers, etc. Under certain flow regimes and fluid velocities, the fluid forces result in tube vibration and damage due to fretting and fatigue. Prediction of these forces requires an understanding of the flow regimes found in heat exchanger tube bundles. Excessive vibrations under normal operating conditions can lead to tube failure. Relatively little information exists on two-phase vibration. This is not surprising as single-phase flow induced vibration; a simpler topic is not yet fully understood. Vibration in two-phase is much more complex because it depends upon two-phase flow regime, i.e. characteristics of two-phase ...
Nickel-titanium alloys may coexist in more than one crystalline structure. There is a high temperature phase, austenite, and a low temperature phase, martensite. The metallurgical basis for the superelasticity and the shape memory effect relies in the ability of these alloys to transform easily from one phase to another. There are three essential factors for the orthodontist to understand nickel-titanium alloys behaviour: stress; deflection; and temperature. These three factors are related to each other by the stress-deflection, stress-temperature and deflection-temperature diagrams. This work was undertaken with the objective to analyse commercial nickel-titanium alloys for orthodontics application, using the dynamical mechanical analyser - DMA. Four NiTi 0,017 X 0,025'' archwires were studied. The archwires were Copper NiTi 35 deg C (Ormco), Neo Sentalloy F200 (GAC), Nitinol Superelastic (Unitek) and ...
The two-fluid model representation for calculations of two-phase flow characteristics in the FBR fuel pin bundles with liquid metal cooling is presented and analysed. Two conservation equations systems of the mass, momentum and energy have been written for each phase. Components accounted the mass-, momentum- and heat transfer throughout the interface occur in the macro-field equations after the averaging procedure realisation. The pattern map and correlations for two-fluid model in vertical liquid metal flows are presented. The description of processes interphase mass- and heat exchange and interphase friction is determined by the two-phase flow regime. The opportunity of the liquid metal two-phase flow regime definition is analysed. (author)
The constituent phases and associated deformed microstructure of the quenched Ti-xNb-(0.5-1.5) at.% Si alloy consisting of non-cytotoxicity elements, where x = 24-30 at.%, were investigated to provide pseudoelasticity for biomedical and sensor applications. Optical microscopy revealed that stress-induced martensitic transformation takes place during the deformation in the present alloys. It is confirmed from the X-ray diffraction results of the deformed specimens that the crystal structure of the stress-induced martensite phase is the orthorhombic so-called #alpha#'' structure. Within the alloys having #beta#(bcc) phase studied Nb-poor region appeared to exhibit a dominant behavior for stress-induced martensitic transformation than Nb-rich region. This result suggests that metastable #beta# phase is superior to stable #beta# phase for the occurrence of stress-induced martensitic ...
Equilibrium and energy equations have been developed in describing the solid-fluid transition zone during the melting and solidification of the binary alloys. Due to the existence of the transition region exhibited both solid and fluid phases at the same material point from continuum point of view, mixture theory was utilized to analyze the region. Unlike the Stefan problem, the latent heat due to the phase change appears as a source term in the heat equation. The molten fluid is treated as a thermoviscous and incompressible fluid, whereas the solid is thermoviscoplastic described by the Bodner-Partom/Walker type of constitutive equations. Thermal mechanical behaviors of the solid and the fluid phases are determined separately because of insignificant mechanical interactions between them. Volume fractions of the phases are obtained according to the equilibrium phase diagram. The ...
Raman and infrared spectroscopy of para-H{sub 2} to pressures in excess of 200GPa and to 8K using new ultrapure synthetic diamond anvils reveals numerous new vibrational excitations in the three high-pressure phases. Highly resolved Raman-active librons indicate differences in orientational ordering between phasesII and III, including evidence for changes within phaseII. The librons in phaseIII are strongly pressure dependent and reflect a substantial increase in ordering with pressure. Multiple vibrons in all three phases (I, II, and III) are observed. The results place new bounds on predicted crystal structures and dynamics of the dense molecular solid. {copyright} {ital 1997} {ital The American Physical Society}
Magnetization, specific heat, and electrical resistivity measurements were made on single crystals of the filled skutterudite compound PrOs{sub 4}As{sub 12}. Specific heat measurements indicate an electronic specific heat coefficient {gamma} {approx} 50-200 mJ/mol K{sup 2} at temperatures 10 K {le} T {le} 18 K, and {approx} 1 J/mol K{sup 2} for t {le} 1.6 K. Magnetization, specific heat, and electrical resistivity measurements reveal the presence of two, or possibly three, ordered phases at temperatures below {approx} 2.3 K and in fields below {approx} 3 T. The low temperature phase displays antiferromagnetic characteristics, while the nature of the ordering in the other phase(s) has yet to be determined.
The automotive industry desires to optimize safety and lightweight construction for the production of cars and trucks. The resulting task for steel suppliers is to make steel grades available that can fulfil these requirements. Different projects have shown optimistic outlooks for optimization of safety and reduction of the weight of automobile bodies by using different high strength and ultra high strength steels. In the last group the dual phase steels play the lead. In recent years different steel grades have been developed and optimized for these applications. On one hand developing the mechanical properties as well as joining and forming of dual phase steels is one of the first steps. On the other hand different coated surfaces for various applications of dual phase steels is another step. Starting with characteristic production conditions for cold rolled hot dip galvanised dual phase steels, the ...
Classic and recent results for gauge effects on the properties of the normal-to-superconducting phase transition in bulk and thin film superconductors are reviewed. Similar problems in the description of other natural systems (liquid crystals, quantum field theory, early universe) are also discussed. The relatively strong gauge effects on the fluctuations of the ordering field at low spatial dimensionality D and, in particular, in thin (quasi-2D) films are considered in details. A special attention is paid to the fluctuations of the gauge field. It is shown that the mechanism in which these gauge fluctuations affect on the order of the phase transition and other phase transition properties varies with the variation of the spatial dimensionality D. The problem for the experimental confirmation of the theoretical predictions about the order of the phase transitions in gauge systems is discussed.
Phase transformations from #alpha#- to #beta#-SiAlONs (i.e., from #alpha#' to #beta#') have been recently reported in a number of rare-earth SiAlON systems during postsintering heat treatment. In the present work, this transformation process in a Sm (#alpha# + #beta#)-SiAlON material is studied by using XRD, TEM, and EDS X-ray mapping techniques. It is observed that in addition to the formation of #beta#' and M' phases, the #alpha#'-to-#beta#' transformation is accompanied by a significant increase in the amount of an AlN-polytypoid phase. The results suggest that some #alpha#' phases are thermodynamically unstable at temperatures lower than the material sintering temperature and will decompose when conditions allow. For the composition studied in this work, the #alpha#-SiAlON decomposition can be described in general as #alpha#' #-># #beta#' + M' + AlN polytypoid.
This Field Sampling Plan outlines the collection and analysis of samples in support of Phase IV of the Waste Area Group 10, Operable Units 6-05 and 10-04 remedial action. Phase IV addresses the remedial actions to areas with the potential for unexploded ordnance at the Idaho National Laboratory Site. These areas include portions of the Naval Proving Ground, the Arco High-Altitude Bombing Range, and the Twin Buttes Bombing Range. The remedial action consists of removal and disposal of ordnance by high-order detonation, followed by sampling to determine the extent, if any, of soil that might have been contaminated by the detonation activities associated with the disposal of ordnance during the Phase IV activities and explosives during the Phase II activities.
This paper explores the through-/in-plane characteristics of water transport in the cathode gas diffusion layer (GDL) of a polymer electrolyte fuel cell (PEFC). Theoretical analysis is performed on the non-isothermal two-phase flow under flow channels. A dimensionless group Da (Damkohler number for PEFC operation), defined as the ratio of water generation rate to water vapor-phase removal rate, is formulated to characterize the flow regimes in a PEFC. This group, lumping geometrical parameters and physical properties, compares the water vapor-phase removal capability (via water diffusion and holding capacity) with the rate of water production by the oxygen reduction reaction. We find that this dimensionless group can be used to characterize the non-isothermal, two-phase phenomena: when Da&...
The phase transformations and properties of a precipitation-hardened Ni-Cr-based alloy are investigated as a function of C, B, Nb, and Cr contents. It is found that the primary role of Nb consists in the formation of an independent phase, delta-Ni3Nb, a part of a gamma/gamma-prime-delta eutectoid (for high C and B concentrations) and in stimulating the gamma-sigma reaction consecutively with the gamma double prime-delta reaction (for low C and B concentrations). In both cases, the long-term strength characteristics of the Nb-alloyed system are relatively low. The substitution of boron for carbon contributes to a reduction in the number of nucleation sites for topologically close-packed phases and to the formation of more stable (with respect to excess compounds) M3B2 and MB2 borides. The high-boron material exhibits better properties and phase stability under mechanical and thermal loading. 13 ...
Experimental investigations have been conducted to determine two-phase natural circulation interfacial parameters by real-time neutron radiography. The natural circulation loop used in the present experiments consists of a vertical two-phase section, a gas liquid separator, and a gas injection/heating section. Experiments were performed in a neutron beam for visualization using realtime neutron radiography system. The natural circulation was initiated by injection of known gas flow rate in the heated section. Two-phase flow interfacial parameters including interfacial geometry and phase velocities etc. for bubbly flow and slug flow patterns observed in the experiments will be given in detail. The results indicate that while the natural circulation is largely as expected and that steady stable flows are possible, there are some local phenomena that introduce instabilities due to the interfacial phenomena ...
Experimental investigations have been conducted to determine two-phase natural circulation interfacial parameters by real-time neutron radiography. The natural circulation loop used in the present experiments consists of a vertical two-phase section, a gas liquid separator, and a gas injection/heating section. Experiments were performed in a neutron beam for visualization using realtime neutron radiography system. The natural circulation was initiated by injection of known gas flow rate in the heated section. Two-phase flow interfacial parameters including interfacial geometry and phase velocities etc. for bubbly flow and slug flow patterns observed in the experiments will be given in detail. The results indicate that while the natural circulation is largely as expected and that steady stable flows are possible, there are some local phenomena that introduce instabilities due to the interfacial phenomena ...
Analysis of the dynamics of the cavity radiation of a coherently pumped correlated emission laser is presented. The phase fluctuation and dephasing are found to affect the time evolution of the two-mode squeezing and intensity of the cavity radiation significantly. The intensity and degree of the two-mode squeezing increase at early stages of the process with time, but this trend changes rapidly afterwards. It is also shown that they increase with phase fluctuation and dephasing in the strong driving limit, however the situation appears to be opposite in the weak driving limit. This essentially suggests that the phase fluctuation and dephasing weaken the coherence induced by a strong driving mechanism so that the spontaneous emission gets a chance. The other important aspect of the phase fluctuation, in this regard, is the relaxation of the time at which the maximum squeezing is manifested as well as ...
The application of the phased array technique was limited to heavy and thick wall components as present in the nuclear industry. With the improvement of the equipment and probes other application areas are now open for the phased array technique, e.g. the inspection of the turbine blade root, weld inspection in a wall thickness range between 12 and 40 mm, inspection of aircraft components, inspection of spot welds or inspection of concretes. The aim of the use of phased array techniques has not been changed related to the first applications, i.e. the adaptation of the sound beam to the geometry by steering the angel of incidence or the skewing angle as well as the focussing of sound fields. Due to the fact, that the new applications of the phased array techniques in some cases don't leave the laboratories for the time being, the examples of this contribution will focus applications with ...
Experimental data on A-15 binary phases (the lattice parameter dependence on composition, phase diagrams, etc.) have been considered and the so-called ''compounds with A-15 structure'' are shown to be solid solutions of element substitution in the structure of A-15 type. Values of lattice parameter and atomic volume of A-15 modifications for 21 elements have been obtained (for Zr, W, Nb, Mo, V in particular). There has been shown the possibility of calculation of atomic volumes and lattice parameters of A-15 binary phases at the lack of direct experimental data. The essential role of atomic volume relations of different phases has been observed for the estimation of stability conditions of A-15 phase.
Experimental data on A-15 binary phases (the lattice parameter dependence on composition, phase diagrams, etc.) have been considered and the so-called ''compounds with A-15 structure'' are shown to be solid solutions of element substitution in the structure of A-15 type. Values of lattice parameter and atomic volume of A-15 modifications for 21 elements have been obtained (for Zr, W, Nb, Mo, V in particular). There has been shown the possibility of calculation of atomic volumes and lattice parameters of A-15 binary phases at the lack of direct experimental data. The essential role of atomic volume relations of different phases has been observed for the estimation of stability conditions of A-15 phase.
A very simple theoretical scheme is proposed to implement two- and three-qubit controlled-phase gates firstly only using a single resonant interaction between ladder-type three-level atoms and the single-mode cavity. In the presented protocol, the quantum information is encoded on the stable ground states of the atoms (as the controlling qubits) and the zero- and one-photon Fock states of cavity-field (as the target qubit). Under the influence of the atomic spontaneous emission, the decay of the cavity-mode, and deviation of the coupling strength, the three-qubit controlled-phase gate may have a comparatively high fidelity. The experimental feasibility of controlled-phase gate and the case that is extended to realize N-qubit controlled-phase gate are also discussed. (general)
To compare the accuracy of MR imaging using an endorectal-pelvic and a pelvic phased-array coil for preoperative local staging of rectal carcinoma. To determine preoperative staging, 38 patients with rectal carcinoma underwent MR imaging. All patients were examined with both an endorectal-pelvic and a pelvic phased-array coil. All underwent surgery and staging was pathologically confirmed. Two radiologists blinded to pathologic stage analyzed perirectal invasion and perirectal node metastasis, and scored according to a four-point scale. Radiologic and pathologic findings were correlated. Receiver operating characteristic (ROC) analysis of Wilcoxon statistic (W values) was used to compare diagnostic accuracy between the two different MR methods. Interobserver variation was measured using {kappa} statistics. For perirectal invasion, T1WI endorectal-pelvic phased-array coil images (reader 1:0. 854, reader 2:0.818) showed ...
Characteristics of pressure drop and heat transfer have been investigated for a lithium single-phase flow and a helium-lithium two-phase flow in a horizontal conducting circular channel in the presence of a uniform transverse magnetic field up to 1.4 T as related to the lithium cooling for magnetic-confinement fusion reactors. By the application of the magnetic field to the lithium single-phase flow, remarkable heat transfer enhancement has been observed at the top wall due to the suppression of the mixed convection occurring in the low Peclet number range, while appreciable heat transfer deterioration appeared in the high Peclet number range. It has been confirmed that the helium-lithium two-phase flow can reduce the high magnetohydrodynamic (MHD) pressure drop in a lithium single-phase flow, and it can provide much better heat transfer performance than that in a helium ...
This paper describes the comprehensive modeling method of fluid and heat flows in the hydrological system. Based upon the concept that the hydrological system is composed of the air-water 2-phase fluids, and the rock phase, various natural processes are modeled including surface/subsurface 2-phase mass transfer, heat exchanges between fluid phases, between fluid and solid phases, and sensible/latent heat exchanges on the ground surface. A field-oriented numerical simulator is developed, in which a set of governing equations is solved for different variables on the surface and in subsurface regions, respectively. Results of an experimental study are presented, in which transient formulation of heat exchange between fluid/solid phases is examined through matching of the observation and calculated performances. (author)
This paper describes the comprehensive modeling method of fluid and heat flows in the hydrological system. Based upon the concept that the hydrological system is composed of the air-water 2-phase fluids, and the rock phase, various natural processes are modeled including surface/subsurface 2-phase mass transfer, heat exchanges between fluid phases, between fluid and solid phases, and sensible/latent heat exchanges on the ground surface. A field-oriented numerical simulator is developed, in which a set of governing equations is solved for different variables on the surface and in subsurface regions, respectively. Results of an experimental study are presented, in which transient formulation of heat exchange between fluid/solid phases is examined through matching of the observation and calculated performances. (author)
Iron undergoes a polymorphic phase transformation from alpha phase (bcc) to the epsilon phase (hcp) when compressed to stresses exceeding 13 CPa. Bccause the epsilon phase is denser than the alpha phase, a single shock wave is unstable and breaks up into an elastic wave, a plastic wave, and a phase transition wave. Examination of this structured wave coupled with various phase transformation models has been used to indirectly examine the transition kinetics. Recently, multimillion atom simulations (molecular dynamics) have been used to examine the shock-induced transition in single crystal iron illustrating an orientation dependence of the transition stress, mechanisms, and kinetics. The objective of the current work was to perform plate impact experiments to examine the shock-response of polycrystalline and single crystal iron with ...
This study explores a method to characterize temporal structure of intermittent phase locking in oscillatory systems. When an oscillatory system is in a weakly synchronized regime away from a synchronization threshold, it spends most of the time in parts of its phase space away from synchronization state. Therefore characteristics of dynamics near this state (such as its stability properties/Lyapunov exponents or distributions of the durations of synchronized episodes) do not describe system's dynamics for most of the time. We consider an approach to characterize the system dynamics in this case, by exploring the relationship between the phases on each cycle of oscillations. If some overall level of phase locking is present, one can quantify when and for how long phase locking is lost, and how the system returns back to the phase-locked state. We consider ...
The effect of the nitrogen uptake in {alpha}-iron upon spark erosion in gaseous and liquid ammonia, plasma nitriding, and plasma immersion ion implantation is studied. The resulting phases and hyperfine parameters, measured by the Moessbauer spectroscopy, are discussed from the point of view of initial conditions of their preparation and subsequent heat and/or mechanical treatment. Spark erosion in the ammonia gas produces fine particles with the dominating ferromagnetic {alpha}-Fe phase (50%). The 20% of specimen volume form {alpha}'-Fe and {alpha}''-Fe{sub 16}N{sub 2} phases. The last 30% occupy the {gamma}'-Fe{sub 4}N, ferro- and paramagnetic {epsilon} phases, and {gamma}-Fe(N). Nitriding in the liquid ammonia allows to incorporate the higher content of nitrogen into {alpha}-iron particles which results in the formation of paramagnetic {epsilon}({zeta})-Fe{sub 2}N ...
The effect of the nitrogen uptake in #alpha#-iron upon spark erosion in gaseous and liquid ammonia, plasma nitriding, and plasma immersion ion implantation is studied. The resulting phases and hyperfine parameters, measured by the Moessbauer spectroscopy, are discussed from the point of view of initial conditions of their preparation and subsequent heat and/or mechanical treatment. Spark erosion in the ammonia gas produces fine particles with the dominating ferromagnetic #alpha#-Fe phase (50%). The 20% of specimen volume form #alpha#'-Fe and #alpha#''-Fe_1_6N_2 phases. The last 30% occupy the #gamma#'-Fe_4N, ferro- and paramagnetic #epsilon# phases, and #gamma#-Fe(N). Nitriding in the liquid ammonia allows to incorporate the higher content of nitrogen into #alpha#-iron particles which results in the formation of paramagnetic #epsilon#(#zeta#)-Fe_2N phase. This ...
Aluminum-containing intergranular phases, forming intergranular films and secondary phase particles at triple-junctions in SiC hot-pressed with aluminum, boron, and carbon additions, were studied by transmission electron microscopy. Statistical high-resolution electron microscopy study of intergranular films indicated that a large fraction of the vitreous intergranular films in the s-hot-pressed SiC crystallized during postannealing in argon above 1000 C. However, brief heating to 1900 C indeed re-melted 25 percent of the crystallized intergranular films. The structural transitions were reflected in the statistical width distributions of the amorphous grain boundary layers. At triple-junctions, Al2O3, Al2OC-SiC solid solution, and mullite phases were newly identified. These phases,together with others reported before are represented in a quaternary phase diagram for 1900 C. It is ...
Triclinic b-BiNbO4 prepared below 750^oC and above 1040^oC (denoted as Low-b and High-b, respectively) and pure orthorhombic a-BiNbO4 at 900^oC were successfully derived from a citrate method and the phase transition from b-BiNbO4 to a-BiNbO4 was first observed in BiNbO4 powders. This phenomenon proves that the abnormal phase transition from b-BiNbO4 to a-BiNbO4 exists in BiNbO4 powder system. The synthesis of Low-b powders can be attributed to the formation of the intermediate phase of Bi5Nb3O15 by the citrate method. With increasing temperature, the Low-b phase gradually turns into a-BiNbO4 due to the thermodynamically metastable state of Low-b. We also identified that the stress in pellet format can accelerate the phase transition from Low-b to a phase of BiNbO4 in comparison with powde...
We present differential scanning calorimetry (DSC), X-ray diffractometry, in situ Moessbauer spectroscopy (MS), and transmission electron microscopy (TEM) studies in Metglas ribbons subjected to different heat treatments. The temperature evolution of the hyperfine field H_h_f(T) and the Curie temperature (T_c) of the amorphous phase are determined. The magnetic field originally present in the amorphous phase has a 'normal' behavior, in the sense that it can be described by the Weiss molecular field theory. The total angular momentum of the iron atoms turns out to be 5/2 and this implies Fe"3"+ in which the electronic spins are uncoupled. When the samples are maintained near T_c (#approx#673 K), three new magnetic phases are detected in the Moessbauer spectra, indicating an onset of a crystallization process well below the first crystallization temperature (T_X_1), as determined by DSC (#approx#820 K). The magnetic behavior ...
In conventional microtremor prospecting methods, underground structure is estimated using the phase velocity of Rayleigh-wave only. However, it is considered that the underground structure can be estimated at a higher accuracy by using two phase velocities of Rayleigh-wave and Love-wave that directly reflects S-wave velocity structure. Therefore, three-component microtremor array observation of a circle (equilateral triangle) with the maximum radius of 40 to 250 m was carried out at the center of Morioka city. Analysis was carried out by means of extended space with autocorrelation to obtain phase velocities of Love- and Rayleigh-waves. The frequency zone of the obtained Rayleigh-wave phase velocity is 1.5 Hz to 8.6 Hz, and the phase velocity is 2670 m/s to 733 m/s. The frequency zone of the obtained Love-wave phase velocity is 3 Hz to 8.6 Hz, and the ...
The use of capacitance sensors for measuring phase concentrations in two-phase flow has gained popularity in recent years. In designing such sensors, there are many issues which must be considered in order to optimize performance: two-phase flow regime, permittivity of the phases, duct geometry, electrical shielding, desired spacial resolution of film thickness, and temperature variation in the flow field. These design issues are discussed and are used to optimize the design of a capacitance sensor which is used to measure vapor volume fraction in annular, two-phase vertical upflow and downflow in a square duct. The sensor was tested and implemented in a 12.7 mm square duct mounted in a flow boiling facility containing FC-72, a low permittivity dielectric fluid ({epsilon}{sub r} = 1.75). Using analytical modeling, an adjustable-length, parallel-plate design was developed and refined ...
The effect of one on-ramp (entry) and one off-ramp (exit) is investigated numerically in one dimensional-cellular automaton traffic flow model, with open boundary conditions, using parallel dynamics. Our aim in this paper is to study how the injecting rates $\\alpha$ and $\\alpha_{0}$ and the extracting rates $\\beta$ and $\\beta_{0}$ acts on the density and flux of cars in one dimensional road. The priority of occupation at entry site $i_{1}$ (moving at exit site $i_{2}$) is attributed to the particle which entered (absorbed) in the chain. Phase diagrams in ($\\beta_{0},\\alpha_{0}$), and ($\\beta,\\alpha_{0}$) plans are established. For $\\alpha=0.1$, they show three different topologies in the flow behaviour. The first one correspond to the presence of four regions, by varying $\\alpha_{0}$; namely low density phase (LDP), intermediate density phase (IDP), plateau current phase (PCP) and high density ...
This paper deals with the energy required to separate ethanol from an aqueous solution in a distillation column containing a solid phase. The solid phases evaluated consisted of either an amylatious (ground corn) or a cellulose (sugar cane bagasse) absorber whit particle sizes smaller than 4 mm. The water-retention capacity of each solid phase was measured by passing vapors or ethanol-water mixtures through the solid phase. When starting with initial concentrations bellow the azeotropic point, ethanol concentrations up to 99,5% (on corn) and 97,2% (on sugar cane) were achieved. The water content was evaluated potentiometrically (Karl`Fischer). Regarding the 2-4 mm ground corn solid phase column, the energy consumed was estimated to be reduced by 15,6% and 60% (by weight) ethanol-water mixture respectively. (author) 11 refs., 2 figs., 2 tabs
The current work focuses on the pressure drop, heat transfer and stability in two phase flow in microchannels with hydraulic diameter of less than one hundred microns. Experiments were conducted in smooth microchannels of hydraulic diameter of 45, 65 {mu}m, and a rough microchannel of hydraulic diameter of 70 {mu}m, with deionised water as the working fluid. The local saturation pressure and temperature vary substantially over the length of the channel. In order to correctly predict the local saturation temperature and subsequently the heat transfer characteristics, numerical techniques have been used in conjunction with the conventional two phase pressure drop models. The Lockhart-Martinelli (liquid-laminar, vapour-laminar) model is found to predict the two phase pressure drop data within 20%. The instability in two phase flow is quantified; it is found that microchannels of smaller hydraulic diameter ...
The effects of alloying elements and precipitated phases on the corrosion rate of high alloy OCTG in the ferric chloride solution have been evaluated. The corrosion rate of Fe-Cr-Ni-Mo alloys without precipitated phases, e.g. carbides and sigma phase, can be estimated from the composition using the following equation: log(C.R.)=-0.144xPRE-7690/(273+T)+28.6 where C.R. is the corrosion rate in g/m/sup 2//hr; PRE is Cr+3Mo+16N in percent and T is the test temperature in "0C. The activation energies of the ferric chloride test are almost the same regardless of PRE or Ni content when no detrimental phase precipitates. When carbides or the sigma phase precipitate, the corrosion rate is higher and the activation energy is lowered. This suggests that secondary phases give preferential sites for initiation of pitting corrosion.
Within the framework of a study on the chemical wear behaviour of sialon ceramics a range of compositions were prepared in which the alumina content was varied from 6 to 77 weight percent. The materials were hot-pressed from alumina and silicon nitride powders to a density of at least 97%. The structure and compositions of the phases occurring in these samples i.e. the O' phase, #beta#'-sialon solid solution and especially the X-phase were thoroughly characterized with respect to structure and composition using electron microprobe and transmission electron microscopy techniques. These results will be discussed in the light of earlier phase diagram studies. Some basic properties such as E-modulus and toughness were measured and related to microstructural features. E-modulus as well as toughness are at a minimum for materials with a high content of the X-phase. Oxidation of the ...
A new separation process of saturated fatty acids (lauric acid-myristic acid) using crystallization from an aqueous ethanol solution has been examined. There were two vessels in this separation process: an extraction vessel and a crystallization vessel. The fatty acids in the aqueous phase were first extracted from their organic phase (melt) in the extraction vessel. The fatty acids in the aqueous phase were continuously introduced to the crystallization vessel, and then the fatty acids were crystallized there. The crystals of the fatty acids were collected continuously above the aqueous phase in the crystallization vessel. In this process, the yield and the purity of the crystals over time were measured, and it was found that the purity of lauric acid increased unsteadily up to 0.98 mole fraction of lauric acid with an increase in the yield of the low yield range. The mole fraction of ethanol in the ...
The multidimensional countercurrent two-phase flow regimes that occur in a pressurized-water reactor (PWR) vessel downcomer during the refill phase of a large-break loss-of-coolant accident are studied using a transparent 1/10 scale model of a PWR vessel. The various flow regimes and their distribution in the downcomer have been identified and mapped for a range of air-water flooding experiments. The two-phase flow patterns that are identified in the downcomer included various types of film flows, droplet flows, countercurrent churn flows and cocurrent flows depending on the flooding condition. Through observation of the two-phase flow dynamics it was deduced that the physical mechanisms associated with the flooding processes could be separated into a liquid entrainment process and a film flow reversal process. In addition to the above exercise, the effect of non-uniform injection of water into the ...
The multidimensional countercurrent two-phase flow regimes that occur in a pressurized-water reactor (PWR) vessel downcomer during the refill phase of a large-break loss-of-coolant accident are studied using a transparent 1/10 scale model of a PWR vessel. The various flow regimes and their distribution in the downcomer have been identified and mapped for a range of air-water flooding experiments. The two-phase flow patterns that are identified in the downcomer included various types of film flows, droplet flows, countercurrent churn flows and cocurrent flows depending on the flooding condition. Through observation of the two-phase flow dynamics it was deduced that the physical mechanisms associated with the flooding processes could be separated into a liquid entrainment process and a film flow reversal process. In addition to the above exercise, the effect of non-uniform injection of water into the ...
Piezoelectric ceramics for acoustic applications have been prepared by mixing the piezoelectric phase Pb{sub 1-1.5x}La{sub x}{open_square}{sub x/2}(Ti{sub 1-y}Zr{sub y})O{sub 3} (PLZT) with variable fractions of Al{sub 2}O{sub 3}. The samples are in form of pellets and polarized at high temperature. After thermal treatment, X-ray diffraction and scanning electron microscopy have been used to determine the phase and morphological modifications. The morphotropic PLZT initial phase disproportionates into modified PLZT and ZrO{sub 2} phases. Using electrical impedance spectroscopy, the resonance frequencies of the composite system have been determined and analyzed. As the Al{sub 2}O{sub 3} volume fractions increase, the resonance frequency and the amplitude of the electrical response both decrease. An interpretation of the role of Al{sub 2}O{sub 3} additions is proposed in terms of ...
Because of their austenitic-ferritic microstructures, duplex stainless steels offer a good combination of mechanical and corrosion resistance properties. However, heat treatments can lower the mechanical strength of these stainless steels as well as render them susceptible to intergranular corrosion (IGC) and pitting corrosion. In this study, a low-carbon (0.02%) duplex stainless steel is subjected to various heat treatments at 450 to 950 C for 30 min to 10 h. The heat-treated samples than undergo ASTM IGC and pitting corrosion tests, and the results are correlated with the microstructures obtained after each heat treatment. In the absence of Cr_2_3C_6 precipitation, #sigma#-phase precipitates render this duplex stainless steel susceptible to IGC and pitting corrosion. Even submicroscopic #sigma#-phase precipitates are deleterious for IGC resistance. Longer-duration heat treatments (at 750 to 850 C) induce chromium diffusion to replenish the ...
We present results from Spitzer Space Telescope observations of the mid-infrared phase variations of three short-period extrasolar planetary systems: HD 209458, HD 179949 and 51 Peg. We gathered IRAC images in multiple wavebands at eight phases of each planet's orbit. We find the uncertainty in relative photometry from one epoch to the next to be significantly larger than the photon counting error at 3.6 micron and 4.5 micron. We are able to place 2-sigma upper limits of only 2% on the phase variations at these wavelengths. At 8 micron the epoch-to-epoch systematic uncertainty is comparable to the photon counting noise and we detect a phase function for HD 179949 which is in phase with the planet's orbit and with a relative peak-to-trough amplitude of 0.00141(33). Assuming that HD 179949b has a radius R_J < R_p < 1.2R_J and a small Bond albedo, it must recirculate less than ...
Particularly high coherence of the x-ray beam is associated, on the ID19 beamline at ESRF, with the small angular size of the source as seen from a point of the sample (0.1-1 #mu#rad). This feature makes the imaging of phase objects extremely simple, by using a 'propagation' technique. The physical principle involved is Fresnel diffraction. Phase imaging is being simultaneously developed as a technique and used as a tool to investigate light natural or artificial materials introducing phase variations across the transmitted x-ray beam. They include polymers, wood, crystals, alloys, composites or ceramics, exhibiting inclusions, holes, cracks, ... . 'Tomographic' three-dimensional reconstruction can be performed with a filtered back-projection algorithm either on the images processed as in attenuation tomography, or on the phase maps retrieved from the images with a reconstruction procedure similar to ...
Two-phase pressure drop and fluctuating static pressures were measured in a small horizontal rectangular channel (hydraulic diameter = 5.44 mm). The two-phase fluid was an air/water mixture at atmospheric pressure tested over a mass flux range of 50 to 2,000 kg/m[sup 2] [center dot] s. Two-phase flow patterns were identified and an objective method was found for determining the flow pattern transition from bubble or plug flow to slug flow. The method is based on an RMS static pressure measurement. In particular, it is shown that the transition is accompanied by a clear and abrupt increase in the RMS pressure when plotted as a function of mass quality. Use of the RMS pressure as a two-phase flow pattern transition indicator is shown to have advantages over pressure-versus-time trace evaluations reported in the literature. The transition is substantiated by a clear local change in slope in the curve of ...
Volume VII of the documentation for the Phase I Data Analysis Task performed in support of the current Regional Flow Model, Transport Model, and Risk Assessment for the Nevada Test Site Underground Test Area Subproject contains the tritium transport model documentation. Because of the size and complexity of the model area, a considerable quantity of data was collected and analyzed in support of the modeling efforts. The data analysis task was consequently broken into eight subtasks, and descriptions of each subtask's activities are contained in one of the eight volumes that comprise the Phase I Data Analysis Documentation.
Volume VI of the documentation for the Phase I Data Analysis Task performed in support of the current Regional Flow Model, Transport Model, and Risk Assessment for the Nevada Test Site Underground Test Area Subproject contains the groundwater flow model data. Because of the size and complexity of the model area, a considerable quantity of data was collected and analyzed in support of the modeling efforts. The data analysis task was consequently broken into eight subtasks, and descriptions of each subtask's activities are contained in one of the eight volumes that comprise the Phase I Data Analysis Documentation.
Volume IV of the documentation for the Phase I Data Analysis Task performed in support of the current Regional Flow Model, Transport Model, and Risk Assessment for the Nevada Test Site Underground Test Area Subproject contains the hydrologic parameter data. Because of the size and complexity of the model area, a considerable quantity of data was collected and analyzed in support of the modeling efforts. The data analysis task was consequently broken into eight subtasks, and descriptions of each subtask's activities are contained in one of the eight volumes that comprise the Phase I Data Analysis Documentation.
Volume II of the documentation for the Phase I Data Analysis Task performed in support of the current Regional Flow Model, Transport Model, and Risk Assessment for the Nevada Test Site Underground Test Area Subproject contains the potentiometric data. Because of the size and complexity of the model area, a considerable quantity of data was collected and analyzed in support of the modeling efforts. The data analysis task was consequently broken into eight subtasks, and descriptions of each subtask's activities are contained in one of the eight volumes that comprise the Phase I Data Analysis Documentation.
FLOWTRAN-TF is a new two-component, two-phase thermal-hydraulics code to capture the detailed assembly behavior associated with loss-of-coolant accident analyses in multichannel assemblies of the SRS reactors. The local interfacial area of the two-phase mixture is computed by summing the interfacial areas contributed by each of three flow regimes. For smooth flow regime transitions, the code uses an interpolation technique in terms of component void fraction for each basic flow regime.
FLOWTRAN-TF is a new two-component, two-phase thermal-hydraulics code to capture the detailed assembly behavior associated with loss-of-coolant accident analyses in multichannel assemblies of the SRS reactors. The local interfacial area of the two-phase mixture is computed by summing the interfacial areas contributed by each of three flow regimes. For smooth flow regime transitions, the code uses an interpolation technique in terms of component void fraction for each basic flow regime.
During solvent extraction of At"-, [At(H_2O)_2]"+, AtCl, AtCl_2"- as well as of astatine compounds with higher oxidation states like AtO_n"-, the astatine species are changed into astatine of the oxidation state zero at the phase boundary independent on the organic solvent used. At(O) probably reacts with components of the organic phase or with decomposition products formed by chemical reactions or by radiolysis. The extraction coefficients of the astatine species depend on the experimental conditions applied, the redox potential, and on complex forming reactions or associations, resp., occuring in the aqueous phase. (author).
A weak shift of the isotope concentration ratio Li{sup 6}/Li{sup 7} was measured in the coexisting phases of the miscibility gap of lithium-ammonia solutions. Li{sup 6} is slightly enriched in the concentrated metallic phase (enrichment factor {alpha} = 1.009 {+-} 0.002). This effect can be enhanced in a counter-current column to yield any desired enrichment of the two isotopes. The counter current system and its operation were tested succesfully with a sodium-potassium-ammonia solution.
We present investigations of the potential between static charges from a simulation of quantum gravity coupled to an SU(2) gauge field on 6^{3}\\times 4 and 8^{3}\\times 4 simplicial lattices. In the well-defined phase of the gravity sector where geometrical expectation values are stable, we study the correlations of Polyakov loops and extract the corresponding potentials between a source and sink separated by a distance R. In the confined phase, the potential has a linear form while in the deconfined phase, a screened Coulombic behavior is found. Our results indicate that quantum gravitational effects do not destroy confinement due to non-abelian gauge fields.
Phase transformations in TiD_#approx#_0_._7_5 subjected to high-pressure treatment were investigated by simultaneous real-time measurements of neutron diffraction and small-angle neutron scattering. The neutron spectra were taken on heating the samples in temperature ranges 100 to 300 K and 300 to 870 K. A sequence of structural transitions was observed, which involves 7 different phases and intermediate states with hcp, fcc, fco or bcc metal sublattices and hydrogen atoms. 30 refs., 9 figs., 1 tab.
The first successful application of a new method to investigate phase transformations in real time, like the decomposition of austenite into bainite in grey iron, is described. During the ongoing transformation, transmission spectra of thermal neutrons, which contain Bragg edges corresponding to the crystal structure of the transforming phases, are recorded. By evaluating the height of these Bragg edges, which is a measure of the volume fraction of the phase, at different transformation times, the transformation can be followed in-situ in a time resolved manner. The method is compared to other previously used methods (micrographs, dilatometry, diffraction techniques); also a summary and an outlook are given. ((orig.))
The first successful application of a new method to investigate phase transformations in real time, like the decomposition of austenite into bainite in grey iron, is described. During the ongoing transformation, transmission spectra of thermal neutrons, which contain Bragg edges corresponding to the crystal structure of the transforming phases, are recorded. By evaluating the height of these Bragg edges, which is a measure of the volume fraction of the phase, at different transformation times, the transformation can be followed in-situ in a time resolved manner. The method is compared to other previously used methods (micrographs, dilatometry, diffraction techniques); also a summary and an outlook are given. ((orig.)).
The reaction of RbC/sub 24/ with C/sub 6/D/sub 6/ vapour was studied by neutron diffraction on a time scale of 5 min/spectrum. As for the reaction of KC/sub 24/, a second stage phase RbC/sub 24/(C/sub 6/D/sub 6/)sub(y) is initially formed and subsequently transformed into a first stage phase. Model calculations indicate that the benzene rings are canted against the graphite planes both in the first and in the second stage phase.
A computed tomography (CT) cut-off for differentiating neoplastic lesions (polyps/carcinoma) from normal colon in contrast-enhanced CT colonography (CTC) relating to the contrast phase and lesion size is determined. CT values of 64 colonic lesions (27 polyps <10 mm, 13 polyps {>=}10 mm, 24 carcinomas) were determined by region-of-interest (ROI) measurements in 38 patients who underwent contrast-enhanced CTC. In addition, the height (H) of the colonic lesions was measured in CT. CT values were also measured in the aorta (A), superior mesenteric vein (V) and colonic wall. The contrast phase was defined by xA + (1 - x)V using x as a weighting factor for describing the different contrast phases ranging from the pure arterial phase (x=1) over the intermediate phases (x=0.9-0.1) to the pure venous phase (x=0). The CT values of the lesions were correlated ...
A fundamental and very well studied region of the Erd\\"os-R\\'enyi process is the phase transition at n/2 edges in which a giant component suddenly appears. We examine the process beginning with an initial graph. We further examine the Bohman-Frieze process in which edges between isolated vertices are more likely. While the positions of the phase transitions vary, the three processes belong, roughly speaking, to the same universality class. In particular, the growth of the giant component in the barely supercritical region is linear in all cases.
In recent years, the phase stability of austenitic stainless steels, and its effect on the mechanical properties of stainless steels, have been the subject of much interest. With the availability of new experimental techniques, new theoretical methods, and new computational procedures, significant advances have been made in understanding, and being able to predict, phase stability and mechanical properties of stainless steel welds. This paper reviews some of these developments, with an emphasis on recent work that has been done at Oak Ridge National Laboratory.
The normal-incommensurate phase transition in K2ZnCl4 was studied by neutron scattering measurements. A well-defined soft phonon behavior was not observed above the normal-incommensurate transition temperature of Tsub(i)=288C. Diffuse scattering develops around(h,0,1 +- 0.3) as temperature approaches Tsub(i) from above, and the peak intensity obeys a Curie-Weiss law above Tsub(i). The results indicate that the normal-incommensurate phase transition in K2ZnCl4 can be interpreted as an order-disorder process.
New data about the structure of high-temperature resistant metalloceramic plasma sprayed coatings in micro and nano areas are presented. Application of the new instrumental methods: transmission electron microscopy combined with selected area electron diffraction mode is possible to obtain these data. The first layer in Ni based metallic bond coat shows nanocrystalline structure. External ceramic layer based on stabilised ZrO_2 is polycrystalline and contains both cubic and tetragonal crystalline phases. Local inhomogeneities in coatings phase composition are determined. (author)
We show that in the Landau gauge of the SU(2) Yang-Mills theory the residual global symmetry supports existence of the topological vortices which resemble disclination defects in the nematic liquid crystals and the Alice (half-quantum) vortices in the superfluid heluim 3 in the A-phase. The theory also possesses half-integer and integer charged monopoles which are analogous to the point-like defects in the nematic crystal and in the liquid helium. We argue that the deconfinement phase transition in the Yang-Mills theory in the Landau gauge is associated with the proliferation of these vortices and/or monopoles. The disorder caused by these defects is suggested to be responsible for the confinement of quarks in the low-temperature phase.
This study shows that the physical conditions necessary for thermal waves to materialize in Dual-Phase-Lagging porous media conduction are not attainable in a porous slab subject to a combination of constant heat flux and temperature (Neumann and Dirichlet) boundary conditions. It is demonstrated that the approximate equivalence between Dual-Phase-Lagging (DuPhlag) heat conduction model and the Fourier heat conduction in porous media subject to Lack of Local Thermal Equilibrium (La Lotheq) that suggested the possibility of thermal oscillations and resonance reveals a condition that cannot be fulfilled because of physical constraints. (author)
The stability constant values of Pa(V) with some complexing ligands (chloride, sulfate and oxalate) are graphically determined using solvent extraction data. The organic phase was at constant composition of HTTA in benzene while the aqueous phase was held at constant hydrogen ion concentration and ionic strength of 3. The curve-fitting method was adopted throughout this investigation, giving the following values. The stability constants obtained are used to calculate the distribution of the different Pa (V) species in the corresponding aqueous phase (expressed in mole fraction) as a function of ligand ion concentration.
An interferometric technique for hard X-rays is presented. It is based on two transmission gratings and a phase-stepping technique, and it provides separate radiographs of the phase and absorption profiles of bulk samples. Tomographic reconstruction yields quantitative three-dimensional maps of the X-ray refractive index and of the attenuation coefficient, with a spatial resolution down to a few microns. The method is mechanically robust, it requires little monochromaticity, and can be scaled up to large fields of view. These are important prerequisites for use with laboratory X-ray sources. Numerous applications ranging from wave front sensing to medical radiography are presently under investigation.
The objective of the program was to develop a domestic cooktop with low-NOx emissions and high efficiency. During the first two phases of the program, three design concepts were developed, and two versions of developmental prototypes using the IR-Jet approach were fabricated and tested. The third phase was initiated to address the design issues of a simmer setting, air/gas metering, and jet plate durability and to develop prototypes for interested manufacturers.
This work describes the development of a synchronous key based on micro controller to the switching of three-phase power transformers, which makes possible the achievement of tests to register the inrush current, and the previous establishment of the instantaneous values of the voltage firstly applied to different phases of the energy process. This key is a value tool to the development electric power system projects and to the teaching and researching activities at the laboratory related to transitory phenomena and electric system protection.
Objective was to develop a mathematical model of the cupola furnace (cast iron production) in on-line and off-line process control and optimization. In Phase I, the general structure of the heat transfer, fluid flow, and chemical models were laid out, providing reasonable descriptions of cupola behavior with a one-dimensional representation. Work was also initiated on a two-dimensional model. Phase II was focused on perfecting the one-dimensional model. The contributions include these from MIT, Michigan University, and GM.
We present a protocol for quantum key distribution using discrete modulation of coherent states of light. Information is encoded in the variable phase of coherent states which can be chosen from a regular discrete set ranging from binary to continuous modulation similar to phase-shift keying in classical communication. Information is decoded by simultaneous homodyne measurement of both quadratures and requires no active choice of basis. The protocol utilizes either direct or reverse reconciliation both with and without postselection. We analyze the security of the protocol and show how to enhance it by the optimal choice of all variable parameters of the quantum signal.
The SY-101 Equipment Removal System 100 Ton Hydraulic Trailer was designed and built by KAMP Systems, Inc. Performance of the Acceptance Test Procedure at KAMP`s facility in Ontario, California (termed Phase 1 in this report) was interrupted by discrepancies noted with the main hydraulic cylinder. The main cylinder was removed and sent to REMCO for repair while the trailer was sent to Lampson`s facility in Pasco, Washington. The Acceptance Test Procedure was modified and performance resumed at Lampson (termed Phase 2 in this report) after receipt of the repaired cylinder. At the successful conclusion of Phase 2 testing the trailer was accepted as meeting all the performance criteria specified.
The reaction of RbC_2_4 with C_6D_6 vapour was studied by neutron diffraction on a time scale of 5 min/spectrum. As for the reaction of KC_2_4, a second stage phase RbC_2_4(C_6D_6)sub(y) is initially formed and subsequently transformed into a first stage phase. Model calculations indicate that the benzene rings are canted against the graphite planes both in the first and in the second stage phase. (Auth.).
The objective of the three-phase Holly Sugar Geothermal Project was to replace fossil fuels with geothermal energy for sugar beet processing at the Holly Sugar plant located in Brawley, California, in a technically straightforward, economically sound and environmentally acceptable manner. The first phase of the project, discussed in this final report, encompassed the design and analysis of a geothermal industrial heat system for Holly Sugar and addresses: (1) assessment of the geothermal resource; (2) development of a preliminary system design; (3) analysis and publication of an environmental analysis and monitoring report; (4) preliminary economic analyses; (5) dissemination of project related information; and (6) the development of a proposal for the follow-on phases.
A method and system for enhancing the transient stability of an intertied three-phase electric power generating system. A set of power exporting generators (10) is connected to a set of power importing generators (20). When a transient cannot be controlled by conventional stability controls, and imminent loss of synchronism is detected (such as when the equivalent rotor angle difference between the two generator sets exceeds a predetermined value, such as 150 degrees), the intertie is disconnected by circuit breakers. Then a switch (30) having a 120-degree phase rotation, or a circuit breaker having a 120-degree phase rotation is placed in the intertie. The intertie is then reconnected. This results in a 120-degree reduction in the equivalent rotor angle difference between the two generator sets, making the system more stable and allowing more time for the conventional controls to stabilize the transient.
... The acousto-optic device have a 30 MHz 1 ... coherent systems including compact non-coherent optical ... a relatively simple phase switching approach. ...
Twenty eight reports presented in the 7th Eurotherm seminar are contained in this publication. They cover the main aspects of the thermodynamics in relation to nuclear systems or having reference to them.
The SCF approximation is used in a statistical theory of melting based on equality of the chemical potentials. The results for the melting points of the inert gases are close to the observed values.
New ICRH antennas on JET were designed to couple to the new JET divertor plasma configurations and to improve the Fast Wave Current Drive (FWCD) capabilities. The A2 antenna consists of 4 straps whose currents can be phased at arbitrary angles. The real time automatic tuning acts on frequency, line length (line phase shifters) and stub length. Provision is made for the coupling resistance/plasma position feedback to accommodate the fast changes in antenna loading. The first coupling, tuning and heating results are reported in 0{pi}0{pi}, 0000 and 00{pi}{pi} phasing. A new antenna model is described, which was developed to simulate the measured antenna loading in terms of plasma parameters and to provide a starting point for the real time automatic tuning. 5 refs., 4 figs.
In this study polycrystalline specimens of as-cast DyCu with B2 crystal structure were compressed to different strains at room temperature to test if stress-induced phase transformation and twinning occur during deformation. In these tests DyCu exhibited high ductility with plastic strain as high as 35% and ultimate compressive strength of ~790MPa. X-ray diffraction and transmission electron microscopy (TEM) showed no indications that DyCu had undergone stress-induced phase transformation or twinning. -type dislocations have been observed to play an important role for imparting the ductile behavior. TEM analyses showed the presence of second phases, Dy2O3 and DyCu2 within the DyCu. The mechanisms of ductility and impurity phase formation are discussed.
For the application of dynamic neutron radiography to the two-phase flow research using HANARO, several experimental items to which the radiography technique is beneficial were identified through the review of the outputs from the related researches and the discussions with experts. Also, the investigation of the equipments including the beam port, camera and converter was made and a hardware and a software for image processing were equipped. It was confirmed that the calibration curve for the attenuation of neutron beam in fluid which is required for the two-phase flow experiment could be obtained by the computer code calculation. Based on the investigation results on the equipment and the results from the measurement of BNCT beam characteristics, a high speed camera and an image intensifier will be purchased. Then, the high speed dynamic neutron radiography facility for two-phase flow experiments will be fully equipped.
This comprehensive final report for the Swiss Federal Office of Energy (SFOE) presents the results of research done in the third phase of a research project that investigated components for small heat pump systems that use ammonia as a working fluid. The report includes a summary of the findings of the first two phases of the project and goes on to describe tests done with rotary vane and scroll compressors. The aims of the project are discussed and the work done is listed chronologically. The construction and the components of the test installation are described in detail. Also, the heat pump testing facilities at the University of Applied Science in Rapperswil, Switzerland, are described. The results of the measurements made for various temperature gradients are presented in detail and commented on; also, the various types of compressor tested and other heat pump compressors are compared.
Site occupancies in three C15-structured AB{sub 2}(X) Laves phases have been determined by Atom Location by CHanneling Enhanced MIcroanalysis (ALCHEMI). In NbCr{sub 2}(V), the results were consistent with exclusive site occupancies of Nb for the A sublattice and Cr and V for the B sublattice. The B-site occupancy of V is not expected from atom size effects alone. In NbCr{sub 2}(Ti), the results were consistent with Ti partitioning mostly to the A sites with some anti-site defects likely. In HfV{sub 2}(Nb), the results were consistent with Nb partitioning between the A and B sites. The results of the ALCHEMI analyses of these ternary C15 Laves phase materials will be discussed with respect to previously determined phase diagrams and first-principles total energy and electronic structure calculations.
Monolithic SiAlON ceramics are hard and brittle with little possibility for property design, but multi-phase SiAlON ceramics offer great scope for controlling microstructural development and desired properties. The ceramics can also be reinforced by separate additions of other hard, refractory compounds. The toughness in all these SiAlON composites can be increased by several mechanisms, and the best effect is reached if they are combined. When glassy phase is present, crack paths are affected by the strains caused by different thermal expansion of the glassy phase and the crystals and also by the interface properties. The crystal shape influence toughness, especially pronounced is the effect of the elongated #beta#- grains. Different toughening mechanisms are achieved by separately added reinforcement phases. The hardness is raised by the presence of #alpha# SiAlON and other hard constituents, such as ...
Improvements in electric submersible pumping systems have resulted in a demonstrated downhole running life of one year for low horsepower units operating in 180 C brine. The implementation of a prototype pressurized lubrication system to prevent brine intrusion and loss of lubricating oil from the motor and protector sections has been successfully tested. Second generation pressurized lubrication systems have been designed and fabricated and will be utilized in downhole production pumping tests during FY84. Pumping system lifetime is currently limited by available power cable designs that are degraded by high-temperature brine. A prototype metal-sheathed power cable has been designed and fabricated and is currently undergoing destructive and nondestructive laboratory testing. This cable design has the potential for eliminating brine intrusion into the power delivery system through the use of a hermatically sealed cable from the surface to the downhole motor. The ...
A rapid and highly reproducible chromatographic technique has been developed for analysis and purification of complex mixtures of oligoribonucleotides. The method utilizes a column of microparticulate...Full Text Available
This report documents a one-dimensional numerical model, SAMFT1D, developed to simulate single-phase and multiphase fluid flow and solute transport in variably saturated porous media. The formulation of the governing equations and the numerical procedures used in the code for single-phase and multiphase flow and transport are presented. The code is constructed to handle single-phase as well as two or three-phase flow conditions using two integrated sets of computational modules. The fully implicit scheme is used in the code for both single-phase and multiphase flow simulations. Either the Crank-Nicholson scheme or the fully implicit scheme may be used in the transport simulation. The single-phase modules employ the Galerkin and upstream weighted residual finite element techniques to model flow and transport of water (aqueous phase) ...
The 1992 New Mexico State Legislature directed the Interstate Stream Commission (ISC) to study the feasibility of clearing and deepening the channel of the Rio Grande between Albuquerque and Elephant Butte to improve water conveyance and water conservation. The ISC requested the US Army Corps of Engineers-Albuquerque District (COE) to undertake this study under the Planning Assistance to States Program. The study was divided into two phases. Phase 1 consisted of an analysis of the sediment contribution to the Rio grande from the tributaries and an evaluation of the existing US Geological Survey (USGS) sediment gage data. Phase 2 will be an analysis, through the use of an HEC-6, Scour and Deposition in Rivers and Reservoirs, computer model, to determine the long-term performance of any Rio Grande channel improvements. This narrative presents the Phase 1 methods and results.
Results of ongoing research project at the McMaster Nuclear Reactor Facility on real-time neutron radiography for the visualization of interfacial geometry, movements and phase distributions in gas-liquid and gas-liquid-metal multi-phase flows are presented. Experiments were conducted with bubble column tubes with boiling liquid nitrogen, air-water and air-mercury mixtures. Discussions are also focused on air-water flowing within a tube containing a CANDU type 37 rod fuel bundle assembly positioned both horizontally and vertically. Computer processing using a digital image format to enhance the real-time images was used. Imaging techniques include frame averaging, background substraction, edge enhancement (spatial filtering), contrast enhancement and video densitometry. (orig.).
Superfluidity in fermionic systems originates from pairing of fermions, and Bose condensation of these so-called Cooper pairs. The Cooper pairs are usually made of fermions of different species; for example in superconductors they are pairs of electrons with opposite spins. Thus the most favorable situation for pairing and superfluidity is when the two species of fermions that form pairs have the same density. This paper studies the possible superfluid states when the two pairing species have different densities, and show that the resultant states have remarkable similarities to the phases of liquid crystals. This enables us to provide a unified description of the possible pairing phases, and understand the phase transitions among them.
Abstract The electrochemical properties of a perfluorosulfonic acid (PFSA) membrane are estimated using a combination of molecular dynamics simulation and statistical thermodynamic model. We obtain all parameters in an ionic conductivity model from an atomistic simulation and remove all adjusted model parameters. From a microscopic point of view, the hydrated PFSA membrane shows micro-phase segregation which separated into hydrophilic and hydrophobic phases. Our present work originates with this phenomenon and we treat this phase segregation as if it is a continuous phase for each of which the proton (H+) is transported inside the PFSA membrane/solvent (water and alcohols) mixture. The chemical potential for a given system is estimated using a molecular simulation technique to predict the ...
The distribution of the alkaline earth elements strontium and barium between the solid phases of phosphates of transition elements of group 4 and chloride melts was studied. The distribution coefficients of strontium and barium were found at T = 700-800/sup 0/C. Phosphates of the type NaM/sub 2//sup (IV)/(PO/sub 4/)/sub 3/, where M/sub (IV)/ represents titanium, zirconium, and hafnium, were used as the solid phases. It was established that there is an enrichment of the precipitates with the distributed components. The distribution coefficient depends on the nature of the solid phase and the temperature. It was suggested that M/sup (II)/ x M/sub 4//sup (IV)/(PO/sub 4/)/sub 6/ is formed in processes of distribution, where M/sup (II)/ represents Sr, Ba.
The structural stability, electronic and elastic properties of ScN under high pressure were investigated by using full-potential linearized augmented plane-wave (FP-LAPW) method. Our calculations indicate that there exists a pressure-induced structural phase transformation from the ambient rock-salt (B1) phase to CsCl-type (B2) phase above 335 GPa. The origin of moderate high bulk modulus, mechanical and high melting point was analyzed by electronic properties. The variations of elastic constants (C_i_j) with volume and pressure have been investigated. Moreover, the volume dependencies of Debye temperature, the longitudinal and transverse elastic wave velocities have been presented.
In order to investigate interactions of (Ti,W)(C,N) and (Ti,Mo)(C,N) with binder metals solid/solid diffusion couples were annealed. These two-dimensional arrangements provide good access to phase reactions occurring upon sintering already in the solid state. It was found in (Ti,W)(C,N)/Co- and (Ti,W)(C,N)/Ni-based couples that the reaction zone is thinner in contact with Co than with Ni. It was also observed that the reaction rate with both Co and Ni is lower if nitrogen is added to the hard phases. Beside a thickness variation of the diffusion zones a change in the microstructure was found. At the interface of nitrogen-free hard phases in contact with Co elongated microstructural constituents are formed with the main axis perpendicular to the interface, while at the interface of nitrogen-containing hard phases these elongated microstructural constituents were found in contact with Ni. Also ...
This paper describes a novel psychophysical and analytical technique, called periodic perturbation, for creating and characterizing perceptual waves associated with transitions in visibility...Full Text Available
indicated for the phase spectral density measurements; how- ever, Ref. 7 provides a very tentative estimate of : ORW ~ 2 ><10"'(RW); Ta = 1000 seconds ...
... Finally, the one dimensional, one phase Stefan problem is well known as a model for the melting of ice (see, eg, [5]). There are many approaches to ...
The goal of this experiment is to evaluate the usefulness of existing normal gravity two-phase flow heat transfer augmentation techniques under microgravity ...
A brief article considers the possible result of the enquiry into Nirex`s plan to build an underground rock laboratory at Sellafield in relation to radioactive waste disposal in the UK. (UK).
Metastable yttrium-oxide films are synthesized using reactive sputter deposition. The yttrium concentration of the as-deposited film is found to vary as a function of the sputter deposition rate. In addition to the synthesis of the cubic equilibrium phase...
A theoretical analysis of formation and symmetry transformations is presented for Wigner molecules with N = 2,..., 20 electrons confined in quantum dots at high magnetic fields. Using the unrestricted Hartree-Fock method with the multicentre Gaussian basis, we have found that Wigner molecules with N {>=} 6 abruptly change their shape and symmetry with an associated jump in the first derivative of the ground-state energy, i.e. they undergo phase transitions. In particular, the phases of the Wigner molecules obtained just after emerging from the maximum-density droplet (MDD) phase possess a different symmetry from that formed at a high magnetic field. We show that the properties of the electron-electron interaction energy demonstrate very well both the breakdown of the MDD and the quasi-classical character of the Wigner molecule in the high magnetic field. Possible mechanisms of the MDD decay are discussed.
In this study structural and magnetic character of the expanded austenite phase (gN) layer formed on a medical grade CoCrMo alloy by a low-pressure Radio-Frequency plasma nitriding process was investigated. The formation of the expanded austenite phase is facilitated at a substrate temperature near 400^oC for 1, 2, 4, 6 and 20h under a gas mixture of 60% N2-40% H2. The magnetic state of the gN layers was determined by a surface sensitive technique, magneto-optic Kerr effect (MOKE), and with a scanning probe microscope in magnetic force mode (MFM). Strong evidence for the ferromagnetic nature of the gN-(Co,Cr,Mo) phase is provided by the observation of stripe domain structures and the hysteresis loops. The ferromagnetic state for the gN phase observed here is mainly linked to large lattice ...
The confining effect of a spherical substrate inducing anchoring (normal to the surface) of rod-like liquid crystal molecules contained in a thin film spread over it has been investigated with regard to possible changes in the nature of the isotropic-to-nematic phase transition as the sample is cooled. The focus of these Monte Carlo simulations is to study the competing effects of the homeotropic anchoring due to the surface inducing orientational ordering in the radial direction and the inherent uniaxial order promoted by the intermolecular interactions. By adopting entropic sampling procedure, we could investigate this transition with a high temperature precision, and we studied the effect of the surface anchoring strength on the phase diagram for a specifically chosen geometry. We find that there is a threshold anchoring strength of the surface below which uniaxial nematic phase results, and above which the isotropic ...
Jul 25, 2011 ... Koji Mukai's Bibliography. Invited Reviews. Mukai, K. 1994, "ASCA PV Phase Observations of Cataclysmic Variables," in "New Horizon of X-ray ...
By using megaelectronvolt /sup 4/He ion backscattering techniques and transmission electron microscopy, the authors have investigated the interactions of ion beams with thin film structures in a number of silicide-forming systems. The mixed layer was found to be an equilibrium compound for near-noble metals and an amorphous phase for refractory metals. Differences in behavior have also been observed in near-noble metal systems. For palladium, the Pd/sub 2/Si phase grew with ion dose and remained crystalline up to high dose. For nickel, the compound Ni/sub 2/Si was formed initially and became amorphous on prolonged irradiation. All the results indicate the significance of atomic mobility at target temperatures in determining the phase formation and in explaining the sensitivity of the silicides to ion bombardment.
By using megaelectronvolt "4He ion backscattering techniques and transmission electron microscopy, the authors have investigated the interactions of ion beams with thin film structures in a number of silicide-forming systems. The mixed layer was found to be an equilibrium compound for near-noble metals and an amorphous phase for refractory metals. Differences in behavior have also been observed in near-noble metal systems. For palladium, the Pd_2Si phase grew with ion dose and remained crystalline up to high dose. For nickel, the compound Ni_2Si was formed initially and became amorphous on prolonged irradiation. All the results indicate the significance of atomic mobility at target temperatures in determining the phase formation and in explaining the sensitivity of the silicides to ion bombardment. (Auth.).
(1989], however, we modeled the phase using a sum of simple power law terms. We. chose to do our work on Triton's atmosphere using the exponential functions ...
The refractory nature and high ductility of body centered cubic (bcc) phase tantalum makes it a suitable material for corrosion- and wear-resistant coatings on surfaces which are subjected to high stresses and harsh chemical and erosive environments. Sputter deposition can produce thick tantalum films but is prone to forming the brittle tetragonal beta phase of this material. Efforts aimed at forming thick bcc phase tantalum coatings in both flat plate and cylindrical geometries by high-rate triode sputtering methods are discussed. In addition to substrate temperature, the bcc-to-beta phase ratio in sputtered tantalum coatings is shown to be sensitive to other substrate surface effects.
Extraction of hafnium by 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone (HL) in benzene, toluene, chloroform and tetrachloromethane from aqueous-alcoholic solutions of the formal acidity of 2M-HClO_4 was studied. Methyl, ethyl, n- and isopropyl, tert-butyl and allyl alcohol as well as ethylene glycol monomethyl ether and propylene glycol were used as organic components of the mixed aqueous-organic phase. Their presence in some cases resulted in a synergic increase in the distribution ratio of hafnium. The increase is interpreted using the results of a slope analysis and measurements of the alcohol distribution and the relative permittivity of the organic phase. It is suggested that HfL_4 molecules were solvated by alcohol molecules in the organic phase. At high alcohol concentration synergism changed into antagonism. This was caused by changes in the distribution of HL and its interaction with the alcohol in the organic ...
The present paper deals with the experimental determination of pressure drop across a four-cusped vertical channel. This geometry represents, ideally, the blockage condition in a typical pressurized water reactor with core degraded by accident. Experiments were performed for both single and two-phase flow. Water was utilized for the single-phase measurements whilst simultaneous flow of air and water simulated the steam-water flow. Observation of the prevailing two-phase flow regime was carried out, so that its mechanism could be fully understood. The averaged void fraction was also measured, by the gamma-ray attenuation technique. A wide range of water and air mass flow rates was covered, so that all flow conditions, possible to exist in a reactor with LOCA, could be investigated. New correlations for pressure drop are proposed. (Author).
The phase stability of silicides of Ni, Pt and Pd in contact with single crystal or amorphous silicon is examined. The presence of a particular silicide phase is identified by X-ray diffraction, and Rutherford backscattering is used to study composition. It is concluded that Pt or Pd silicides are suitable for Schottky barriers. Layers of silicon can be grown quickly by solid phase epitaxy at temperatures of 300-500C and using an intermediate metal film. Experimental results are reported. Doped layers have been obtained which have electrical characteristics suitable for the junctions in solar cells. The effects of impurities and orientation of the substrate on the growth kinetics are discussed.
The effects of five extraction solvents and their mixtures on the yield of metabolites in crude and fractionated extracts of Annona muricata L. leaves were investigated by direct comparison. Extraction media were prepared using simplex centroid mixtures of ethanol, ethyl acetate, dichloromethane, acetone, and chloroform. The effects of the mobile phase solvent strength and the analysis wavelength on the chromatographic separation were also investigated. Solvent mixtures rather than pure solvents were found to be the most efficient extractors for the different fractions. The results indicated that the mobile phase composed of methanol/acetonitrile/water (26:27:47 v/v/v) was most suitable for the basic fraction analysis at 254 nm, whereas the mobile phase composed of methanol/acetonitrile/wa...
Quantitative analytical electron microscopy study of dopant distribution in the microstructure of selected Nd-#alpha#-sialon samples revealed the presence of relatively large amounts of glassy phase at quadruple pockets, which exhibited a common composition similar to a melilite solution. Al segregants were depleted from adjacent grain boundaries to satisfy the 'stoichiometry' of such glass. Existence of this glass results in significant deviation of the Nd-#alpha#-sialon composition from the expected values, which shifts the #alpha#-#beta#-sialon phase boundary. Only extra Nd_2O_3 additives enable a monolithic #alpha#-sialon microstructure. The absence of similar glass in Yb-#alpha#-sialon materials keeps the phase relations from such deviations.
The authors present results of grazing incidence X-ray diffraction studies concerning the effect of pH (and thus, of headgroup dissociation) on Langmuir monolayers of fatty acids, in the absence of any divalent cations in the aqueous subphase. An increase in pH transforms the distorted-hexagonal S phase first to the partially disordered Rotator-I phase with less distortion, and then to the completely disordered Rotator-II phase with an undistorted hexagonal structure. The S-Rotator-I and Rotator-I-Rotator-II transitions are pushed to lower temperatures with increase in pH. The fact that the effects of pH increase are almost identical to the effects of increasing temperature indicates the important role of headgroup-headgroup interactions in these monolayer phases.
The thermal stability and deformability of Mn-Al-C alloys containing 0.6 pct C are investigated experimentally as a function of excess phase content. It is shown that an increase in Mn content from 68.9 to 73.5 pct leads to increased stability of the high-temperature epsilon phase. The enrichment of the system Mn-Al-Cu in Mn and Al above the optimum composition leads to the formation of nonmagnetic excess phases, eta and beta, which reduce the magnetization of the alloy. In addition, a decrease in thermal stability is observed in the alloy with 73.5 pct Mn due to the decomposition of the ferromagnetic phase. 7 references.
SAMPSON is an integration of twelve analysis modules under the final development phase (phase-2) and will be capable of simulating hypothesized severe accidents in a nuclear power plant. One of these modules, the Molten Core Relocation Analysis (MCRA) module, simulates the relocation behavior of a molten core during a severe accident. MCRA models severe accident phenomena by using mechanistic formulations for multi-phase, multi-component, and multi-velocity field. As one of the verification studies of SAMPSON in Phase-1, the in-core phenomena of PHEBUS/FPT0 was analyzed with three modules, MCRA, fuel rod heat up analysis (FRHA) module, and the analysis control module (ACM) of SAMPSON. (author)
In the present study, a new measurement technique which uses a ultrasonic transmission signals in order to determine the vertical two phase flow pattern even under high pressure condition. The ultrasonic measurement system developed in the present study not only provides the measurement functions required for the determination of vertical two phase flow pattern but also makes the real time determination possible. The developed ultrasonic measurement system accurately determined the various vertical two phase flow patterns such as bubbly, slug, churn, annular flow etc. In addition to the determination of flow patterns, qualitative informations for each flow pattern can be obtained, which include void fraction in bubbly flow, length of slug bubble and liquid tail characteristics in slug flow, and stable or transient condition of flow pattern, etc. 13 refs., 24 figs., 3 tabs. (Author)
The objectives of the Phase-I research address the development of mechanics- based structural integrity analysis methodologies for composite sandwich panels ...
tions, final noise-power spectral density measurements were made. These measurements of the noise-power spectral density were not the desired phase- noise ...
FeSi{sub 6}/graphite composite was prepared by mechanical ball milling. The FeSi{sub 6} alloy particles consist of an electrochemically active silicon phase and inactive phases FeSi{sub 2}, distributed uniformly in the graphite matrix. The composite anode offers a large reversible capacity (about 800 mAh g{sup -1}) and good cycleability, due to the buffering effect of the inactive FeSi{sub 2} phase and graphite layers on the volumetric changes of Si phase during lithium-Si alloying reaction. Since FeSi{sub 6} alloy is a low-cost industrial material, this alloy compound provides a possible alternative for development of high capacity lithium-ion batteries. (author)
The z-phase, existing between 35% and 70% U in Pu, belongs to the high-density phases seen from the point of view of systematics of allotropic modifications of Pu metal. Despite the volume per actinide atom only slightly higher than for a-Pu, it magnetic susceptibility is much higher than for a-Pu and exceeds even the d-Pu value. Similarly, the Sommerfeld coefficient g>40mJ/mol Pu K2 exceeds the experimental d-Pu value. The data confirm that the volume is not the primary control parameter affecting the situation around the Fermi level of common Pu phases and they point against the traditional belief that they are essentially narrow 5f band systems. Electronic structure calculations suggest that the 5f states of Pu have slightly lower occupancy comparing with d-Pu. A tendency to the 5f loca...
Observations concerned with the formation of isothermal #omega# in the beta-titanium alloy RMI (38-6-44) are presented as part of a more general study of the aging characteristics of the alloy.
allowed an initial assessment of ADS-33 handling quality requirements for an aircraft of this ...... then executing 180 or 360 degree turns in an attempt to ...
Apr 23, 2009 ... Wolf-Rayet stars have over 20 times the mass of the Sun and are thought to be in a brief, pre-supernova phase of massive star evolution. ...
A Real-Time Neutron Radiography (RTNR) system is developed to determine two-phase flow parameters for a vertical co-current two-phase flow channel with a hexagonal finned bundle. Image processing techniques are applied to visualize the two-phase flow, and procedures for measuring flow regime, cross-sectional averaged void fraction, time averaged void fraction, and void distribution for this complex geometry are discussed. The results show that the experimental flow regime map agrees well with an existing flow regime model for a hexagonal fined bundle. The hexagonal finned bundle is observed to significantly affect the void fraction, void migration, and void fluctuation along the axial flow channel.
A metal matrix is inserted into a phase-change material to enhance the heat transfer during phase-change processes. The metal matrix tends to act like a heat transfer fin from the heated or cooled surface and to increase the effective thermal conductivity of the phase-change fluid. The scope of the study involves numerically modeling the heat transfer to and from constant-temperature cylindrical tubes surrounded by water during the freezing and melting processes. Comparisons of heat transfer with and without the metal matrix are made, with different porosities and densities of the metal matrix being examined. The results of this study are discussed in terms of the effectiveness of the metal matrix as a heat transfer enhancement device.
The techniques in order to measure the depth of defect in weldment and structure accurately have been developed. Many researches have made efforts to develop the methods for the accurate depth sizing of defect. TOFD is known as the most accurate method of various methods for measuring depth sizing. However, there is a possibility to miss defects because of the limitation of beam coverage for the ultrasound incident angle. In this study, the results for detectability and depth sizing using phased array ultrasonic technique for thick body were compared with those of conventional TOFD technique. It was experimentally confirmed that the phased array ultrasonic TOFD technique gives good detectability and accurate depth measurement for the various types of defects. The phased array ultrasonic TOFD technique developed in this study will contribute to increase the inspection reliability in thick component such as the pressure ...
... 3. Critical constants, and triple point 4. Compressibility isothermE S. Density, molar volume (of a condensed phase) 6. Equations of state, general ...
It is shown that it is necessary to take into account locality of the analysis and to introduce additional corrections for partial capture of matrix and fluorescent subexcitation by matrix during quantitative X-ray spectral microanalysis of finely dispersed materials. Cast two-phase (#alpha#+#beta#) titanium alloy VT3-1 is chosen as an investigation object.
Circularly polarized X-rays produced by a diamond X-ray phase retarder of thickness 0.5 mm in the Laue transmission configuration have been used for recording X-ray magnetic circular dichroism...Full Text Available
BackgroundThe Mre11/Rad50/Nbs1 (MRN) complex is a regulator of cell cycle checkpoints and DNA repair. Defects in MRN can lead to defective S-phase arrest when cells are damaged....Full Text Available
The use of europium as a local structural probe allows the various phases appearing in the NaCaPO_4-Na_3Eu(PO_4)_2 and NaSrPO_4-Na_3Eu(PO_4)_2 systems to be detected. The broadening of the europium emission lines in going from the calcium to the strontium phases illustrates the ease of displacement of the PO_4 groups. (Auth.).
A series of real-time, neutron radiography, experiments are ongoing at the Texas A and M Nuclear Science Center Reactor (NSCR). These tests determine the resolving capabilities for radiographic imaging of two phase water and air flow regimes through small diameter flow channels. Though both film and video radiographic imaging is available, the real-time video imaging was selected to capture the dynamic flow patterns with results that continue to improve. (author)
Inverted annular flow can be visualized as a liquid jet-like core surrounded by a vapor annulus. While many analytical and experimental studies of heat transfer in this regime have been performed, there is very little understanding of the basic hydrodynamics of the post-CHF flow field. However, a recent experimental study was done that was able to successfully investigate the effects of various steady-state inlet flow parameters on the post-CHF hydrodynamics of the film boiling of a single phase liquid jet. This study was carried out by means of a visual photographic analysis of an idealized single phase core inverted annular flow initial geometry (single phase liquid jet core surrounded by a coaxial annulus of gas). In order to extend this study, a subsequent flow visualization of an idealized two-phase core inverted annular flow geometry (two-phase central jet core, surrounded by ...
The solvent extraction of 12-phosphotungstic acid, also known as 12-tungstophosphoric acid-H_3PW_1_2O_4_0, the so-called Keggin heteropolyacid - by 0.73 M (20%v/v) tri-n-butyl phosphate (TBP) in n-octane under conditions comparable to those used previously for the extraction of conventional inorganic mineral acids is described. A simplified phase diagram for the pentanary system comprised of H_3PW_1_2O_4_0, HNO_3, H_2O, TBP, and n-octane reveals an extremely low initial concentration of H_3PW_1_2O_4_0 (1.1 mM) at the LOC (limiting organic concentration) condition, far lower than the most effective third-phase-forming inorganic acid, namely HClO_4. The results from small-angle neutron scattering (SANS) indicate that the interparticle attraction energy - U(r) calculated through application of the Baxter sticky sphere model to the SANS data at the LOC condition - does not approach the -2 k_B T value associated with phase ...
Equations are derived to calculate the work required for the isentropic compression of a 2-phase fuel-air mixture. Methanol evaporation during compression substantially reduces compression work and improves cycle efficiency and maximum power. Effects of evaporative cooling in the intake manifold are calculated. Energy d. of methanol and gasoline fuel-air charges are compared. The phase equilibrium and evaporation rate are causes of the poor cold-starting performance of methanol.
By the example of CH2Cl2, CF2Cl2, CHF2Cl, C2F6, C2H6, SF6 and C6H12 we have investigated the isobaric thermal conductivity jump at crystal-liquid phase transition. It is shown that the reduction in the thermal conductivity at melting derives from the degree of orientational ordering of the crystals at pre-melting point.
This articles deals with an approach that has given some key information about the mechanisms of the liquid phase oxidation of butane to acetic acid. This procedure has been developed over the last 34 years; however, much of what will be discussed represents a synthesis of previous insights. Many of the observations are relatively recent and have not been previously published. In principle, this approach should be applicable to many oxidation processes. (orig.)
This report describes the test of a dynamic phase compensation unit for a wind turbine with directly connected induction generators. The compensation unit is based on thyristor switched capacitors, where conventional wind turbine compensations use mechanical contactors to switch the capacitors. The influence on power quality analysed, and influence on component lifetime is discussed. Besides, simulation models in Matlab/Simulink are presented, including a flicker meter model. (au)
We study the one-phase Stefan problem on a semi-infinite strip x> or =0, with the convective boundary condition -KT/sub x/(0,t) = h[T/sub L/--T(0,t)]. Points of intrest include: a) behavior of the surface temperature T(0,t); b) asymptotic behavior as h#->#infinity; c) uniqueness, and d) bounds on the phase change front and total system energy.
No information on steam/water two-phase flow behavior in large diameter pipes (10 inch or larger) at elevated pressures is available in the open literature. However, there are many applications, in the nuclear, chemical and petroleum industries among others where two-phase flows in large diameter pipes at elevated pressures and temperatures are encountered routinely or under accident scenarios. Experimental data on steam-water two-phase flow in a large diameter (20 inch, 50.08 cm I.D.) vertical pipe at elevated pressures and temperatures (2.8 MPa/230 C--6.4 MPa/280 C) have been obtained. Void fraction, two-phase mass flux, phase and velocity distributions as well as pressure drop along the test pipe have been measured using the Ontario Hydro Technologies (OHT) Pump Test Loop. The void fraction distributions were found to be axially symmetric and nearly flat over a wide range of ...
No information on steam/water two-phase flow behavior in large diameter pipes (10 inch or larger) at elevated pressures is available in the open literature. However, there are many applications, in the nuclear, chemical and petroleum industries among others where two-phase flows in large diameter pipes at elevated pressures and temperatures are encountered routinely or under accident scenarios. Experimental data on steam-water two-phase flow in a large diameter (20 inch, 50.08 cm I.D.) vertical pipe at elevated pressures and temperatures (2.8 MPa/230 C--6.4 MPa/280 C) have been obtained. Void fraction, two-phase mass flux, phase and velocity distributions as well as pressure drop along the test pipe have been measured using the Ontario Hydro Technologies (OHT) Pump Test Loop. The void fraction distributions were found to be axially symmetric and nearly flat over a wide range of ...
In a slurry explosive, the fine droplets of the aqueous phase are dispersed in a continuous oily phase which comprises a thin film surrounding each droplet, the latter being less than one micron in size. The authors present these commercial explosives in three different forms, indicate their explosive properties and discuss their advantages from the safety viewpoint. They also report on tests undertaken with slurry explosives in quarries possessing different types of rock and using deep vertical shotholes.
The peculiarities of pulsed laser melting and evaporation of the superconducting ceramics are analyzed by means of numerical simulation. The appearance of the overheated metastable states in solid and liquid phases is shown as a result of the phase front dynamics and volume nature of laser energy release. A method of dynamic adaptation for the multifront Stefan problem is proposed.
The objective of Phase IV of the contract is to design a conceptual flue gas treating unit based on the fluidized-bed Copper Oxide (FBCO) process for a new coal-fired 500 MW(e) power plant. A technical and economic evaluation of the FBCO process, based on the conceptual design, will also be completed. Progress is described.
The possibility of modifying the functional composition of humic acids by gas-phase ozonation of bed-oxidized brown coal was examined. About 90% of the organic matter of brown coal was converted to low-molecular weight soluble oxygen-containing products by stepwise liquid-phase ozonation (in chloroform and acetic acid).
This report summarizes preliminary 2-D reactive-transport simulations on the injection, storage and transport of supercritical CO{sub 2} in dolostone formations in the Ordos Basin in China. The purpose of the simulations was to evaluate the role that basin heterogeneity, permeability, CO{sub 2} flux, and geochemical reactions between the carbonate geology and the CO{sub 2} equilibrated brines have on the evolution of porosity and permeability in the storage reservoir. The 2-D simulation of CO{sub 2} injection at 10{sup 3} ton/year corresponds to CO{sub 2} injection at a rate of 3 x 10{sup 5} ton/year in a 3-D, low permeable rock. An average permeability of 10 md was used in the simulation and reflects the upper range of permeability reported for the Ordos Basin Majiagou Group. Transport and distribution of CO{sub 2} between in the gas, aqueous, and solid phases were followed during a 10-year injection phase and a 10-year post injection ...
The physics and technology of a new class of efficient composite piezoelectrics are described. This material combines nanostructured and micropiezoelectric matrix composites. They consist of a polymer matrix, an insulating nanodimensional phase, and a microdimensional piezoelectric phase. It is shown that the nanostructuring of the near-surface region of polymer-PZT piezoelectric composites greatly improves their piezoelectric, mechanical, and electromechanical characteristics. A plausible mechanism underlying this effect is suggested.
We introduce a discrete multiplicative process as a generic model of competition. Players with different abilities successively join the game and compete for finite resources. Emergence of dominant players and evolutionary development occur as a phase transition. The competitive dynamics underlying this transition is understood from a formal analogy to statistical mechanics. The theory is applicable to bacterial competition, predicting novel population dynamics near criticality.
The beta transformation characteristics and mechanical properties of the #beta# titanium alloy Ti_5_0Zr_3_0Nb_1_0Ta_1_0 in the temperature range between 200 and 900 deg. C have been studied by means of X-ray diffraction (XRD), Vickers hardness (HV), and tensile test techniques. In the as-rolled state, only #beta#-phase was identified by XRD. Upon heat-treating at 250 deg. C for 4 h, the #alpha#-phase was precipitated from the #beta#-phase matrix, and leading to an increase of Vickers hardness. A maximum HV value was observed at 400 deg. C, and then HV value decreased with increasing heat-treating temperature. Above 650 deg. C, HV value remained almost constant. During heat-treating at 300-650 deg. C, the decomposition of the metastable #beta#-phase has been found to proceed through a phase separation reaction leading to the formation of #beta#-Ti and #beta#-Zr b.c.c. solid solution ...
This phase report summarizes the results of field investigations conducted in 1992 at Technical Area 21 of Los Alamos National Laboratory, as prescribed by the RCRA Facility Investigation work plan for the Technical Area 21 operable unit (also known as OU 1106). This phase report is the last part of a three-part phase report describing the results of field work conducted in 1992 at this operable unit. Phase Report lA, issued on l4 June l993, summarized site geologic characterization activities. Phase report 1B, issued on 28 January 1994, included an assessment of site-wide surface soil background, airborne emissions deposition, and contamination in the locations of two former air filtration buildings. The investigations assessed in Phase Report 1C include field radiation surveys and surface and near-surface sampling to characterize potential contamination at 25 ...
To analyze the enhancement patterns and morphology of peripheral cholangiocar-cinomas (CCs), as seen on three-phase helical CT. Three-phase helical CT scans of 25 cases of 24 patients with pathologically-proven CCs were retrospectively reviewed. After intravenous administration of contrast media, scans of the hepatic arterial phase (HAP) were obtained at 30 seconds, of the portal venous phase (PVP) at 70 seconds, and of the delayed phase (DP) at 3 minutes. Linear, dense, marginal enhancement was seen in 17 CCs (68%), mainly on HAP images (64%) while thick, band-like, peripheral enhancement was seen in 18 (72%), on either PVP (52%) or DP (44%). Internal enhancement was observed in 23 CCs (92%) on PVP (68%) and/or DP (88%), and 19 CCs (76%) among them showed incomplete enhancement of stippled and/or septated patterns. Most (76%) were seen throughout all three ...
This paper presents results of solid-liquid phase change, driven by volumetric energy generation, in a vertical cylinder. We show excellent agreement between a quasi-static, approximate analytical solution valid for Stefan numbers less than one, and a computational model solved using the CFD code FLUENT®. A computational study also shows the effect that the volumetric energy generation has on both the mushy zone thickness and convection in the melt during phase change.
We develop a theory of Smectic A - Smectic C phase transition with anomalously weak smectic layer contraction. We construct a phenomenological description of this transition by generalizing the Chen-Lubensky model. Using a mean-field molecular model, we demonstrate that a relatively simple interaction potential suffices to describe the transition. The theoretical results are in excellent agreement with experimental data.
Free-electron laser (FEL) amplifiers have demonstrated high efficiencies and high output power at microwave wavelengths. However, measurements and simulations have indicated that the present level of phase stability for these devices is not sufficient for driving linear accelerators. Fluctuations in the diode voltage, which is needed to accelerate the electron beam, are the largest cause of the shifts in the phase of the output power. Pulse-power technology cannot keep the voltage fluctuations less than 1/4%. However, we have found a scheme that will make the output phase much less sensitive to these fluctuations by exploiting the traveling wave nature of the FEL interaction. In this paper we study the phase stability issue by analyzing the dispersion relation for an axial FEL, in which the rf field is transversely wiggled and the electron trajectories are purely longitudinal. The advantage of using the ...
We study the possibility of utilizing the superfluid to Mott-insulator quantum phase transition in an array of quantum well exciton-polariton traps to generate indistinguishable single photons in a massive parallel fashion. By means of analytical and numerical methods, the device operations and system properties are examined using realistic experimental parameters. Such a deterministic, massive parallel generation may find new applications in photonic quantum information processing.
This paper is concerned with the development and application of an analytical method for the performance prediction of air cooled condensers. A local analysis is employed in which the condenser is considered as a matrix of small basic heat transfer modules. For each element, local film coefficients for both the air and the condensing fluid are determined according to the existing local conditions, including the two-phase flow regime. The paper considers an application of the method to heat pump condensing.
Given the spectrum of a Hamiltonian, a methodology is developed which employs the Landau-Ginsburg theory for characterizing phase transitions in infinite systems to identify phase transition remnants in finite fermion systems. As a first application of our approach we discuss pairing in finite nuclei. (orig.)
The field algebra of the minimal models of W-algebras is amenable to a very simple description as a polynomial algebra generated by a few elementary fields, corresponding to order parameters. Using this description, the complete Landau-Ginzburg lagrangians for these models are obtained. Perturbing these lagrangians we can explore their phase diagrams, which correspond to multicritical points with D[sub n] symmetry. In particular, it is shown that there is a perturbation for which the phase structure is similar to that of the IRF models of Jimbo et al. (orig.)
The field algebra of the minimal models of W-algebras is amenable to a very simple description as a polynomial algebra generated by a few elementary fields, corresponding to order parameters. Using this description, the complete Landau-Ginzburg lagrangians for these models are obtained. Perturbing these lagrangians we can explore their phase diagrams, which correspond to multicritical points with D_n symmetry. In particular, it is shown that there is a perturbation for which the phase structure is similar to that of the IRF models of Jimbo et al. (orig.).
Net heats of reaction were measured in an isothermal calorimeter for both single phase (organic) and two phase (organic and aqueous) TBP/HNO{sub 3} reacting solutions at temperatures above 100 C. The oxidation rate constant was determined to be 5.4E-4 min{sup {minus}1} at 110 C for an open ``vented`` system as compared to 1.33 E-3 min{sup {minus}1} in the closed system. The heat released per unit material oxidized was also reduced. The oxidation in both phases was found to be first order in nitric acid and pseudo-zero order in butylnitrate and water. The hydrolysis (esterification) rate constant determined by Nichols` (1.33E-3 min{sup {minus}1}) fit the experimental data from this work well. Forced evaporation of the volatile components by the product gases from oxidation resulted in a cooling mechanism which more than balanced the heat from the oxidation reaction in the two-phased systems. Rate ...
Loss of organic matter is one of the main forms of soil degradation in Mediterranean agricultural soils, and external sources of organic matter are required to improve soil properties. the two-phase centrifugation system in the olive-oil extraction industry produces a large amount of olive mill waste sludge (TPOMW) which can be used to add organic C to degraded soils. (Author)
The droplet concentration profile in a liquid film-mist two-phase flow in a developing flow region of a horizontal rectangular channel was analyzed theoretically and experimentally. The effects of the mean settling velocity of droplets v sub(f) and the turbulent diffusion coefficient epsilon sub(p) on the droplet concentration profile were investigated by the theoretical analysis. The calculated results of the droplet concentration profile using the proper values of v sub(f) and epsilon sub(p) agreed with the experimental results.
The droplet concentration profile in a liquid film-mist two-phase flow in a developing flow region of a horizontal rectangular channel was analyzed theoretically and experimentally. The effects of the mean settling velocity of droplets v sub(f) and the turbulent diffusion coefficient epsilon sub(p) on the droplet concentration profile were investigated by the theoretical analysis. The calculated results of the droplet concentration profile using the proper values of v sub(f) and epsilon sub(p) agreed with the experimental results. (author).
Dense sialon ceramics along the tie line between Si_3N_4 and Nd_2O_3#centre dot#9AlN were prepared by hot-pressing at 1,800 C. The materials were subsequently heat-treated in the temperature range 1,300--1,750 C and cooled either by turning off the furnace (yielding a cooling rate (T_c_o_o_l) of #approx# 50 C/min) or quenching (T_c_o_o_l #>=# 400 C/min). It was found necessary to use the quenching technique to reveal the true phase relationships at high temperature, and it was established that single-phase #alpha#-sialon forms for 0.30 #<=# x #<=# 0.51 in the formula Nd_xSi_1_2_-_4_._5_xAl_4_._5_xO_1_._5_xN_1_6_-_1_._5_x. The #alpha#-sialon is stable only at temperatures above 1,650 C, and it transforms at lower temperatures by two slightly different diffusion-controlled processes. Firstly, an #alpha#-sialon phase with lower Nd content is formed together with an Al-containing Nd-melilite phase, ...
This project, conducted under The United States Department of Energy (DOE) Cooperative Agreement DE-FC36-94GO10002/A002, was part of a multiple-phase effort to develop technologies that improve the energy efficiency and economics of chemical process recovery in the pulp and paper industry. The approach taken was to consider two major alternatives in two phases. Phase I, conducted previously, considered means to improve pulp mill recovery boilers using high-solids advanced combustion of black liquor; while this project, Phase la, considered means to recover kraft pulping mill process chemicals by low-temperature black liquor gasification. The principal steps previously proposed in this program were: (1) Evaluate these two technologies, high-solids advanced combustion and gasification, and then select a path forward using the more promising of these two options for future work. (2) Design and construct a ...
This document, the Standards/Requirements Identification Document (S/RID) Phase 2 Assessment Report for the subject facility, represents the results of a Performance Assessment to determine whether procedures containing S/RID requirements are fully implemented by field personnel in the field. It contains a summary report and three attachments; an assessment schedule, performance objectives, and assessments for selected functional areas.
This document, the Standards/Requirements Identification Document (S/RID) Phase I Assessment Report for the subject facility, represents the results of an Administrative Assessment to determine whether S/RID requirements are fully addressed by existing policies, plans or procedures. It contains; compliance status, remedial actions, and an implementing manuals report linking S/RID elements to requirement source to implementing manual and section.
This workshop on heat pipes and two-phase capillary pumping loops was organized by the French society of thermal engineers. The 11 papers presented during this workshop deal with the study of thermal performances of heat pipes and on their applications in power electronics (cooling of components), and their use in satellites, aircrafts and trains. (J.S.)
This paper mainly deals with the charging processes of a cylindrical heat storage capsule filled with stearic acid, sliced paraffin and lauric acid as phase-change materials (PCMs). Experimental results demonstrate that, compared to the capsule with a single PCM, the charging rate of the capsule employing three PCMs is enhanced obviously. (author)
A review of the information on the electron and phonon spectra in the A-15 compounds and Chevrel phase superconductors obtained from nuclear magnetic resonance, heat capacity, and Moessbauer effect experiments is presented. Relationships of the Fermi energy electrons and the soft phonons to the strength of the electron-phonon interaction are discussed.
A review of the information on the electron and phonon spectra in the A-15 compounds and Chevrel phase superconductors obtained from nuclear magnetic resonance, heat capacity, and Moessbauer effect experiments is presented. Relationships of the Fermi energy electrons and the soft phonons to the strength of the electron-phonon interaction are discussed.
Experimental results are presented on the quasi-statistic polarization reversal and on the effect of high dc electric field on the behaviour of LiNH_4SO_4 and LiND_4SO_4 monocrystals, namely in the vicinity of the II-III phase transformation.
If the soft supersymmetry (SUSY) breaking masses and couplings are complex and cancellations do take place in the SUSY induced contributions to the fermionic electric dipole moments, then the CP- violating soft phases can drastically modify much of the known phenomenological pattern of the minimal supersymmetric standard model. In particular, the squark loop content of the dominant Higgs production mechanism at the large hadron collider, the gluon-gluon fusion mode, could be responsible for large corrections to the known cross sections. (15 refs).
Two sets of analytical correlations describing transitions between two-phase flow regimes are reviewed and discussed. One, the T-D set, is based on mechanistic models; the other, the Weisman set, on experimental correlations. The T-D set is preferred for horizontal flow, whereas the Weisman set seems preferrable for vertical flow. A computer code (FLOP) based on the T-D theory is described and applied to validate the theory.
Compton scatter tomography utilizes the electronic collimation characteristics available through the Compton scattering angle-energy correlation to obtain tomographic images. In this work we present particular aspects of the technique, which are relevant to the inverse radiation transport problem of reducing marginal projection data to radial two-phase flow regime maps. The results indicate a viable technique for the tomographic imaging of tow-phase flow using practical source strengths and reasonably few detectors.
The nature of interaction of some boromagnesium minerals with water is studied, the main stages of interaction are established. The methods of thermo-gravimetric, X-ray phase and chemical analyses are applied to state intermediate and final phases of magnesium borate interaction with water. ''Preobrazhenskite'' - ''inderite'' paragenesis is established. The notion ''magnesium borate solubility'' is shown to be senseless.
Four solutions of the Cauchy problem for Mathieu?s equation away from parametric resonance domains are analytically constructed using an asymptotic averaging method in the fourth approximation. Three solutions occur near fractional parameter values at which slow combination phases exist. The fourth solution occurs in the absence of slow phases away from parametric resonance domains and the fractional parameter values.
On the basis of symmetry way of texture description a calculation method of elastic moduli of two-phase titanium alloys with rolling texture has been suggested. Efficiency of the calculation formulas is checked by comparing the calculation results of Young modulus anisotropy in the sheet plane of (#alpha#+#beta#)-titanium alloy VT23 with the experimental data.
A formula for calculating the Dirac S-matrix for central Lorentz scalar and vector potentials is derived by use of a new amplitude-phase method. The derivation also makes use of certain invariants of the reduced 2-spinor radial Dirac equations.
A formula for calculating the Dirac S-matrix for central Lorentz scalar and vector potentials is derived by use of a new amplitude-phase method. The derivation also makes use of certain invariants of the reduced 2-spinor radial Dirac equations.
Implementation of quantum logical gates for multilevel systems is demonstrated through decoherence control under the quantum adiabatic method using simple phase modulated laser pulses. We make use of selective population inversion and Hamiltonian evolution with time to achieve such goals robustly instead of the standard unitary transformation language. (letter to the editor)
The vast majority of fundamental studies of metal oxide selective oxidation catalysts have been performed with single phase systems. These investigations established the basic tenents of the redox mechanism of selective oxidation and ammoxidation catalysis. By comparison, structural and kinetic investigations of multiphase oxide catalysts are less numerous because of the inherent difficulties in understanding the relative contributions of separate phases to the catalytic behavior of the composite catalyst. Some attempts have been made in the past to understand the complex chemistry of multiphase catalysts and additional important insights have been realized more recently. However, a clear understanding of the most significant catalytic interactions between individual phases of a multiphase multicomponent redox catalyst is still lacking. In an effort to provide an understanding and a physical basis for the observed synergism ...
We performed a randomized trial to compare IVF outcomes in 54 poor responder patients undergoing a microdose leuprolide acetate (LA) protocol or a GnRH antagonist protocol incorporating a luteal phase E2 patch and GnRH antagonist in the preceding menstrual cycle. Cancellation rates, number of oocytes retrieved, clinical pregnancy rates (PR), and ongoing PRs were similar between the two groups.
This report describes the selection of candidate surface mining sites for the development of oil shale resources in the western United States. The purpose of this study is to input the various scenarios into an economic mine model developed for underground oil shale mines in an earlier project. Site selection was a three-phase effort. Phase I consisted of a thorough review of available resource data, which resulted in a definition of surface mineable areas. Phase II was a detailed investigation of the regions identified in the initial phase. The end result of this task was a list of potential sites having favorable overburden, grade, shale thickness, and topography values. Phase III identified those sites from which a wide range of site specific parameters can be obtained for mine design and model testing purposes. This report describes the procedures used to obtain the candidate ...
Condensing two-phase channel flow occurs in many industrial applications, including heating and refrigeration systems. It can also occur in certain nuclear reactor accidents. For example, during a small-break loss-of-coolant accident in a pressurized water reactor, following the partial depletion of the primary coolant, condensation of steam on the primary side of the steam generator tubes can provide a heat sink for disposal of the decay heat generated in the reactor core. Condensing two-phase flow can also play an important role in the operation of the passive emergency cooling system in the advanced simplified boiling water reactor. Here, steady-state condensation in the presence of a noncondensable in a concurrent two-phase channel flow is analyzed using a two-fluid model. The effect of noncondensables on the combined heat transfer at the liquid-gas mixture interphase is accounted for by using the stagnant film model, ...
The rates of spontaneous interbilayer and transbilayer exchange of ["3H]dimyristoylphosphatidylcholine (["3H]DMPC) were examined in the DMPC and DMPC/dimyristoylphosphatidylethanolamine (DMPE) large unilamellar vesicles in the liquid-crystalline-, gel-, and mixed-phase states. DMPC desorption rates from either gel or liquid-crystalline phases containing DMPE are very similar to the corresponding rates from pure DMPC gel or liquid-crystalline phases. The authors proposed that the DMPC/DSPC behavior results from packing defects in gel phases composed of both DMPC and DSPC molecules because of the four-carbon difference in the acyl chain lengths of the two species. The present results strongly support this hypothesis because no such anomalous behavior is observed in DMPC/DMPE, which is similar to DMPC/DSPC in phase behavior but does not have the chain length difference. These results ...
The thermal performance and phase change stability of stearic acid as a latent heat energy storage material has been studied experimentally. The thermal performance and heat transfer characteristics of the stearic acid were tested and compared with other studies given in the literature. In the present study, parameters such as transition times, temperature range and propagation of the solid-liquid interface as well as the effect of heat flow rate on the phase change stability of stearic acid as a phase change material (PCM) were studied. The experimental results showed that the melting stability of the PCM is better in the radial direction than in the axial direction. The variation in the melting and solidification parameters of the PCM with the change of inlet water temperature is also studied. We observed that while the heat exchanger tube is in the horizontal position, the PCM has more effective and steady ...
Stearic acid gel is employed to study the phase evolution of MgTiO{sub 3} nanoparticles by thermal gravimetric analysis, X-ray diffraction, and Fourier transform infrared. During the preparation of stearic acid gel, tetrabutyl titanate easily absorbed moisture to hydrolyze into Ti(OH){sub 4} firstly, and then reacts with stearic acid and magnesium stearate to form magnesium-titanium oxide network polymer gel, meanwhile n-butanol is generated. When stearic acid gel is calcined in air, a series of oxidation and combustion reactions occur, meanwhile apparent heat is given off. The results show that a metastable intermediate phase Mg{sub 2}TiO{sub 4} is generated at 450 {sup o}C and nearly disappeared at 550 {sup o}C. Simultaneously, a new solid phase of MgTiO{sub 3} appears. The metastable intermediate phase Mg{sub 2}TiO{sub 4} is successfully identified in the current work.
In order to study the two-phase natural circulation and flow termination during a small break loss of coolant accident in LWR, simulation experiments have been performed. Based on the two-phase flow scaling criteria developed under this program, an adiabatic hot leg U-bend simulation loop using nitrogen gas and water and a Freon 113 boiling and condensation loop were built. The nitrogen-water system has been used to isolate key hydrodynamic phenomena from heat transfer problems, whereas the Freon loop has been used to study the effect of phase changes and fluid properties. Various tests were carried out to establish the basic mechanism of the flow termination and reestablishment as well as to obtain essential information on scale effects of parameters such as the loop frictional resistance, thermal center, U-bend curvature and inlet geometry. In addition to the above experimental study, a preliminary modeling study has been ...
In order to study the two-phase natural circulation and flow termination during a small break loss of coolant accident in LWR, simulation experiments have been performed. Based on the two-phase flow scaling criteria developed under this program, an adiabatic hot leg U-bend simulation loop using nitrogen gas and water and a Freon 113 boiling and condensation loop were built. The nitrogen-water system has been used to isolate key hydrodynamic phenomena from heat transfer problems, whereas the Freon loop has been used to study the effect of phase changes and fluid properties. Various tests were carried out to establish the basic mechanism of the flow termination and reestablishment as well as to obtain essential information on scale effects of parameters such as the loop frictional resistance, thermal center, U-bend curvature and inlet geometry. In addition to the above experimental study, a preliminary modeling study has been ...
The Si_3N_4-rich corner of the phase diagrams for neodymia and ytterbia containing sialons has been investigated by a systematic variation of the m and n values for compositions between 0.5 and 2.0 with a step size of 0.5. Samples requiring nitrides of the rare earth elements have not been prepared. Sintering has been performed at 1800 C for one hour in a nitrogen atmosphere of 1 MPa. The sintered samples were characterized by X-ray diffraction analysis to identify the crystalline phases in equilibrium with sialon. #alpha#- and #beta#-sialon, the 21R AlN polytypoid, and N-melilite M' were found in the Nd containing system. Materials with Yb showed the formation of #alpha#- and #beta#-sialon, and the AlN polytypoids 12H and 21R. The m and n values of the #alpha#-sialon phase have been calculated via their lattice parameters that were refined by a least squares routine. The occurrence and composition of the ...
Direct current (DC) glow discharge plasma nitriding was carried out on three selected surface-roughened AISI 304 stainless steel samples at 833 K under 4 mbar pressures for 24 h in the presence of N{sub 2}:H{sub 2} gas mixtures of 50 : 50 ratios. After plasma nitriding, the phase formation, case depth, surface roughness, and microhardness of a plasma-nitrided layer were evaluated by glancing angle x-ray diffractogram, optical microscope, stylus profilometer, and Vickers microhardness tester techniques. The case depth, surface hardness, and phase formation variations were observed with a variation in initial surface roughness. The diffraction patterns of the plasma-nitrided samples showed the modified intensities of the {alpha} and {gamma} phases along with those of the CrN, Fe{sub 4}N, and Fe{sub 3}N phases. Hardness and case depth variations were observed with a variation in surface roughness. A ...
For optimizing the microstructure of the (#alpha# + #beta#)-titanium alloy TiAl5Fe2.5 the content of the two alloying elements aluminium and iron in the #alpha#- and #beta#-phase was determined by microprobe analysis. The alloys with the composition of the #alpha#- and of the #beta#-phase at 850 degC TiAl6Fe0.5 (#alpha#-phase) and TiAl3.5Fe6.5 (#beta#-phase) were prepared by arc melting and rolling at 850 degC. The mechanical properties of the '#alpha#'- and of the '#beta#'-phase-alloy are compared with the properties of the (#alpha# + #beta#)-alloy TiAl5Fe2.5 in the as rolled and swaged condition and after an additional aging at 550 degC. By this optimizing process it was possible to achieve a tensile strength of Rsub(m) = 1012 N/mm"2, an yield strength of Rsub(p0.2) 954 N/mm"2 and an elongation at fracture A = 14.5% in the TiAl5Fe2.5-alloy, although the degree of hot deformation ...
The reactions between (100) GaAs and the near-noble metals Ni, Pd, and Pt have been investigated by application of high-resolution transmission electron microscopy (TEM), energy-dispersive analysis of x rays in the scanning TEM and Rutherford backscattering spectrometry. Emphasis is placed on the evolution of the phase distributions, film compositions, and interface morphologies during annealing at temperatures up to 480 /sup 0/C. The first phase in the Ni/GaAs reaction is shown to have the nominal composition Ni/sub 3/GaAs. Ternary phases of the type Pd/sub x/GaAs are also found to be the dominant products of the Pd/GaAs reaction. Conversely, only binary phases result from the Pt/GaAs reaction. These observations are used to construct isothermal sections of the M--Ga--As thin-film phase diagrams. The behavior of a thin (1--2 nm) native oxide--hydrocarbon layer during the Ni/GaAs, ...
This document is a synthesis of data and analysis concerning natural circulation cooling in US Pressurized Water Reactors during off-normal operation and accident transients. Its objective is the integration of important research findings concerning PWR natural circulation phenomena into a single reference document. Sources of information include the Nuclear Regulatory Commission, reactor vendors, utility sponsored research groups, utilities, national laboratories, research reports, meeting papers, archival literature, and foreign sources. Three modes of natural circulation are discussed: single-phase, two-phase, and reflux/boiling condensation. General characteristics, analytical expressions, noncondensible gas effects, secondary effects, and nonuniform flow are described with regard to each of the natural circulation modes. Plant operational data, tests in scaled experimental facilities, and analysis with thermal hydraulic system codes have ...
Nanodimensional powders of cubic copper ferrite are synthesized by two-steps procedure of co-precipitation of copper and iron hydroxide carbonates, followed by mechanochemical treatment. X-ray powder diffraction, Moessbauer spectroscopy and temperature-programmed reduction are used for the characterization of the obtained materials. Their catalytic behavior is tested in methanol decomposition to hydrogen and CO and total oxidation of toluene. Formation of nanosized ferrite material is registered even after one hour of milling time. It is established that the prolonging of treatment procedure decreases the dispersion of the obtained product with the appearance of Fe2O3. It is demonstrated that the catalytic behavior of the samples depends not only on their initial phase composition, but on the concomitant ferrite phase transformations by the influence of the reaction medium. -- Graphical abstract: It is demonstrated that the catalytic behavior ...
The two-phase heat-transfer and pressure-drop characteristics of offset-strip-fin heat-exchanger geometries are examined using both experimental and analytical modeling techniques. Newly-obtained boiling-flow heat-transfer data are presented for two large-scale offset fin geometries at low-to-moderate wall-superheat conditions. Data for which nucleate boiling appeared to be completely suppressed were analyzed together with similar results for other offset fin surfaces to study the effects of channel dimensions on the convective evaporation component of the local heat transfer coefficient. Although these data were found to be well correlated in terms of modified forms of the F and Martinelli parameters used in previous studies of round-tube flows, a single F-factor correlation valid for all combinations of fin and channel dimensions did not appear to exist. The two-phase pressure-drop characteristics of offset-fin surfaces were found to be much ...
The formation of the melilite solid solution phase (M'), Sm_2Si_3_-_xAl_xO_3_+_xN_4_-_x, in an #alpha#-sialon sample of overall composition Sm_0_._6Si_9_._2_8Al_2_._6_9O_1_._3_6N_1_4_._7_6, was studied as a function of time in the temperature interval 1,375--1,525 C. The #alpha#-sialon ceramic contained only minor amounts of the 21R sialon polytype and some residual grain-boundary glass before heat treatment. In situ studies by high-temperature X-ray diffraction were combined with postsintering heat treatment followed by quenching. The M'-phase was found to be formed by two different mechanisms: either crystallization of the residual grain-boundary liquid or a direct decomposition of the #alpha#-sialon phase. The liquid crystallized during the first 10--15 min of heat treatment, yielding a rapid M'-phase formation, and further formation of M'-phase continued at a much slower rate, ...
When a metallic alloy is quenched into a miscibility gap, a mixture of two phases develops, whose domain structure then coarsens because of the interfacial energy between the two phases. This spatial arrangement of the domains and the rate at which they evolve may be strongly influenced by elastic interactions. In a recent paper, the authors described a method for simulating the effect of anisotropic elastic interactions in a two-dimensional Ising model of a cubic alloy, using Kawasaki dynamics with the elastic interactions represented by a long-range two-body interaction potential. Here they present the results of such simulations at various temperatures, alloy compositions and misfits (by misfit they mean the difference in size between the two kinds of atom), exhibiting snapshots both of the microscopic configurations (corresponding to experimental measurements using transmission electron microscopy) and of their squared Fourier transforms ...
A mathematical model of a mineral melting cupola furnace for stone wool production has been developed for improving cupola operation. The 1-D, first-engineering-principles model includes mass and heat balances for the gas phase, five solid phases, and four liquid phases. The gas and solid/liquid phases flow countercurrently. Seven chemical reactions account for the conversions of coke, iron oxide, limestone, and gaseous species. The heterogeneous reactions of coke conversion are limited by both kinetics and mass transport. Heat transfer between phases is modeled including both convection and radiation. The model predicts gas concentrations; mass flow rates; and temperature profiles of the solid, melt, and gas in the cupola, as well as heat loss to the water-cooled walls. Inputs to the model include the coke, rock, and blast air properties, the blast air amount, and the coke ...
The primary objective of the project is to investigate the long-term effects of commercially available tangentially-fired low NO{sub x} combustion technologies on NOx emissions and boiler performance on Unit 2 at Gulf Power Company`s Plant Lansing Smith located near Lynn Haven, Florida. The project will characterize emissions and performance of a tangentially-fired boiler operating in the following configurations: Baseline ``as-found`` configuration: Phase 1; retrofitted low NO{sub x} concentric firing system (LNCFS) Level 2 and simulated low NO{sub x} bulk furnace staging (LNBFS): Phase 2; retrofitted low NO{sub x} concentric firing system (LNCFS) Level 3, Phase 3a and simulated LNCFS Level 1, Phase 3b.
Cobalt-60 gamma radiation has been found to be an effective means of immobilizing stationary phases onto gas and liquid chromatographic supports. The ability of a phase to crosslink was determined to be highly dependent on its chemical structure. Gamma radiation was employed to immobilize Se-30, a methylsilicone, and 216 PS onto Chromosorb WHP for packed column chromatography. The resultant columns exhibited increased thermal stability and a high degree of efficiency. Several blended phases containing varying ratios of Se-30:216 PS were also immobilized onto chromatographic packings. This work was further extended to the immobilization of Se-30 and 216 PS onto fused silica capillaries via gamma radiation. Columns exhibited excellent efficiency and improved thermal stability. An investigation into the role of immobilization of polymeric phases for HPLC was undertaken. Results indicate that gamma ...
Local properties and heat transfer have been investigated in a NaK-nitrogen two-phase flow in a vertical tube under transverse magnetic field. An objective two-phase flow regime identification was also carried out systematically, using the probability distribution function of two-phase electromagnetic flowmeter signals. The application of a magnetic field was bound to bring about a drastic change in the void fraction profile, i.e., asymmetric profile perpendicular to the field direction. This effect was more remarkably observed in bubbly flows. The magnetic field was also observed to decrease the number of bubbles, by promoting the agglomeration of small bubbles into larger ones and also break-up of large slugs, and, thus, to shift the flow regime boundaries. It has been also shown that the two-phase Nusselt number increases in bubbly flows, while it decreases in slug flows. This trend however reduces ...
Epitaxial metastable (GaSb)/sub 1-x/Ge/sub x/ alloys with compostions across the pseudobinary phase diagram have been grown on (100) GaAs substrates by multitarget rf sputtering. An essential feature allowing the growth of these metastable materials was low-energy ion bombardment of the growing film during deposition to enhance surface diffusion, promote mixing, and preferentially sputter incipient second-phase precipitates. Annealing experiments indicated that the metastable films exhibit good high-temperature stability and that they transform through a continuous series of GaSb-rich and Ge-rich phases in which the solute concentrations decrease until the equilibrium two-phase alloy is obtained. While the calculated free-energy difference between the single-phase metastable and equilibrium states is approx.18 meV, the measured activation barrier for the transformation is approx.3 ...
Differential phase-contrast X-ray imaging has been performed in a Talbot-Lau configuration, where a multiline X-ray source was used instead of a combination of a hard-X-ray multiple slit and a normal focus X-ray generator. When the multiple slit is used, a high aspect ratio structure is needed and slit width should be below 10 ?m for its function. The fabrication and use of such a multislit can be omitted using the presented configuration. The multiline X-ray source was developed by making grooves on a tungsten rotating anode, which was irradiated by an electron beam to generate X-rays. An array of 10?m line sources with a pitch of 30?m was formed and combined with a 4.5 ?m pitch phase grating and a 5.3 ?m pitch amplitude grating to generate differential phase contrast. With a total exposure time of 40 s, a differential phase image depicting cartilages was obtained. (author)
The influence of Pd-Ni substitution on the formation of magnetic phases in the tetragonal U(Ni{sub 1-x}, Pd{sub x}){sub 2}Si{sub 2} system and the concentration magnetic phase diagram are presented. A series of different substitutions was prepared and detailed studies by powder neutron diffraction were performed for x=0.25, 0.5 and 0.75. All compounds order antiferromagnetically and form ferromagnetic basal planes stacked along the c axis (q=(0,0,q{sub z}) propagation). The ground-state phase (AF3) of UNi{sub 2}Si{sub 2} is an uncompensated AF structure (++- stacking (q{sub z}=2/3)). In UPd{sub 2}Si{sub 2} the ground-state phase corresponds to the simple AF structure AF2 (+-+-(q{sub z}=1)). In solid solutions, no traces of the AF3 phase were found for x=0.25 and the ground-state powder patterns correspond to AF2 for x{>=}0.25. (orig.)
The influence of Pd-Ni substitution on the formation of magnetic phases in the tetragonal U(Ni_1_-_x, Pd_x)_2Si_2 system and the concentration magnetic phase diagram are presented. A series of different substitutions was prepared and detailed studies by powder neutron diffraction were performed for x=0.25, 0.5 and 0.75. All compounds order antiferromagnetically and form ferromagnetic basal planes stacked along the c axis (q=(0,0,q_z) propagation). The ground-state phase (AF3) of UNi_2Si_2 is an uncompensated AF structure (++- stacking (q_z=2/3)). In UPd_2Si_2 the ground-state phase corresponds to the simple AF structure AF2 (+-+-(q_z=1)). In solid solutions, no traces of the AF3 phase were found for x=0.25 and the ground-state powder patterns correspond to AF2 for x#>=#0.25. (orig.)
The main objectives of Phase 2 are to determine the feasibility of using cements with controlled particle size distributions (CPSD cements) in practical concrete applications, and to refine our estimates of the potential energy savings that may ensue from such use. The work in Phase 2 is divided into two main tasks, some parts of which will be carried out simultaneously: Task 1 will continue cement paste studies to optimize cement performance similar to those of Phase 1, but with particular emphasis on gypsum requirements, blended cements, and water-reducing admixtures. This task will also include preparation of sufficient CPSD cements for use in all Phase 2 work. Task 2 will be a comprehensive examination of the properties of concretes made with CPSD cements. This will include optimization of concrete mix designs to obtain the best possible performance for practical applications of both portland and ...
The objective of the study was to investigate neuronal processing during the encoding, retention and retrieval phases of a serial visual working memory task. Particularly, we were interested in how these phases are affected by working memory load and how processing is modulated by methylphenidate. Healthy adults were asked to memorize the order of four, five or six pictures under methylphenidate (20mg) and under placebo while brain electrical activity was recorded. On the performance level, the number of correct responses decreased with increasing working memory load. Concerning brain electrical activity, in the encoding phase P3 amplitudes increased at midline electrodes with increasing memory load while load had no effect in the retention and retrieval phase. Medication neither influenced performance nor the different processing stages significantly. Our data provide evidence that during the encoding ...
Location of transmission line faults are traditionally estimated by measuring the apparent impedance from a line terminal to the fault and converting the reactive component of the impedance to line length. None of the methods proposed to date address adequately the problems of fault location on distribution systems that have single or multiphase laterals and/or tapped loads. The research for this dissertation resulted in the development of a technique that estimates the location of a shunt fault on a radial distribution system that has several single and/or multiphase laterals. The technique takes into account load taps and non-homogeneity of the system, and has been tested for its ability to handle single-phase-to-ground, two-phase-to-ground, phase-to-phase and balanced three-phase faults. Computer simulations indicate that the technique is more accurate than the reactive component method. Results from ...
The concept of relative permeability is the key concept in extending Darcy's law for single phase flow through porous media to the two-phase flow regime. Relative permeability functions are needed for simulation studies of two-phase geothermal reservoirs. These are poorly known inspite of considerable theoretical and experimental investigations during the last decade. Since no conclusive results exist, many investigators use ad hoc parametrization, or adopt results obtined from flow of oil and gas (Corey, 1954). It has been shown by Reda and Eaton (1980) that this can lead to serious deficiencies. Sensitivity of the relative permeability curves for prediction of mass flow rate and flowing enthalpy into geothermal wells has been studied by many investigators (e.g. Eaton and Reda (1980), Bodvarsson et al (1980), Sun and Ershagi (1979) etc.). It can be concluded from these studies that the beehavior of a ...
A numerical model of multiphase air-water flow and contaminant transport in the unsaturated zone is presented. The multiphase flow equations are solved using the two-pressure, mixed form of the equations with a modified Picard linearization of the equations and a finite element spatial approximation. A volatile contaminant is assumed to be transported in either phase, or in both phases simultaneously. The contaminant partitions between phases with an equilibrium distribution given by Henry`s Law or via kinetic mass transfer. The transport equations are solved using a Galerkin finite element method with reduced integration to lump the resultant matrices. The numerical model is applied to published experimental studies to examine the behavior of the air phase and associated contaminant movement under water infiltration. The model is also used to evaluate a hypothetical design for a low-level radioactive ...
This work concerns the development of a methodology the objective of which is to characterize and diagnose two-phase flow regime transitions. The approach is based on the fundamental assumption that a transition flow is less stationary than a flow with an established regime. During the first time, the efforts focused on: (1) the design and construction of an experimental loop, allowing to reproduce the main horizontal two-phase flow patterns, in a stable and controlled way; (2) the design and construction of an electrical impedance probe, providing an imaged information of the spatial phase distribution in the pipe; and (3) the systematic study of the joint time-frequency and time-scale analysis methods, which permitted to define an adequate parameter quantifying the unstationarity degree. During the second time, in order to verify the fundamental assumption, a series of experiments were conducted, the objective of which ...
This work concerns the development of a methodology the objective of which is to characterize and diagnose two-phase flow regime transitions. The approach is based on the fundamental assumption that a transition flow is less stationary than a flow with an established regime. During the first time, the efforts focused on: (1) the design and construction of an experimental loop, allowing to reproduce the main horizontal two-phase flow patterns, in a stable and controlled way; (2) the design and construction of an electrical impedance probe, providing an imaged information of the spatial phase distribution in the pipe; and (3) the systematic study of the joint time-frequency and time-scale analysis methods, which permitted to define an adequate parameter quantifying the unstationarity degree. During the second time, in order to verify the fundamental assumption, a series of experiments were conducted, the objective of which ...
A safety analysis code to design a pressurized water reactor and to obtain the licences including entire proprietary rights is under development in domestic research and development project. The purpose and scope of this report is to develop the flow regimes related models for inter-phase friction, wall frictions, wall heat transfer, and inter-phase heat and mass transfer in two-phase three-field equations. In order to choose choose the flow regime criteria, we have investigated various exiting best-estimate T/H codes in this chapter 2. They are the RELAP5-3D, TRAC-M, CATHARE, MARS codes. Around 500 references used in these codes have been collected and reviewed. Also we have investigated eleven papers in detail. In chapter 3, based on the selected flow regimes, the flow regime maps for a gas-liquid flow in horizontal and vertical tubes have decided including the mechanisms of flow regime transition regions. Conclusively, ...
Full text of publication follows: The heat transfer and flow in narrow channels has lots of advantages such as compact structure, high efficiency, design flexibility and so on. So it is widely used in the fields such as the new reactor core plate elements, the once-through stream generator, compact heat exchangers as well as electronic components. In recent years, more strong attentions have been attracted to the thermal-hydraulic characteristics and mechanism of the two-phase flow in narrow channels. As the flow regime characteristics of two-phase flow is fundamental one of them, the research on the two-phase flow regimes and the regime transitions in horizontal rectangular narrow heated channels can provide theoretical foundation and engineering directions to the whole research on the thermal-hydraulic characteristics and mechanism of the two-phase flow in narrow channels. The characteristics of ...
Full text of publication follows: The heat transfer and flow in narrow channels has lots of advantages such as compact structure, high efficiency, design flexibility and so on. So it is widely used in the fields such as the new reactor core plate elements, the once-through stream generator, compact heat exchangers as well as electronic components. In recent years, more strong attentions have been attracted to the thermal-hydraulic characteristics and mechanism of the two-phase flow in narrow channels. As the flow regime characteristics of two-phase flow is fundamental one of them, the research on the two-phase flow regimes and the regime transitions in horizontal rectangular narrow heated channels can provide theoretical foundation and engineering directions to the whole research on the thermal-hydraulic characteristics and mechanism of the two-phase flow in narrow channels. The characteristics of ...
The overall objective of this project is the three phase development of an Early Entrance Coproduction Plant (EECP) which uses petroleum coke to produce at least one product from at least two of the following three categories: (1) electric power (or heat), (2) fuels, and (3) chemicals using ChevronTexaco's proprietary gasification technology. The objective of Phase I is to determine the feasibility and define the concept for the EECP located at a specific site; develop a Research, Development, and Testing (RD&T) Plan to mitigate technical risks and barriers; and prepare a Preliminary Project Financing Plan. The objective of Phase II is to implement the work as outlined in the Phase I RD&T Plan to enhance the development and commercial acceptance of coproduction technology. The objective of Phase III is to develop an engineering design package and a financing and ...
The objective of this research project is to demonstrate sensing, communication, information and control technologies to achieve a seamless integration of multivendor distributed energy resource (DER) units at aggregation levels that meet individual user requirements for facility operations (residential, commercial, industrial, manufacturing, etc.) and further serve as resource options for electric and natural gas utilities. The fully demonstrated DER aggregation system with embodiment of communication and control technologies will lead to real-time, interactive, customer-managed service networks to achieve greater customer value. Work on this Advanced Communication and Control Project (ACCP) consists of a two-phase approach for an integrated demonstration of communication and control technologies to achieve a seamless integration of DER units to reach progressive levels of aggregated power output. Phase I involved design and proof-of-design, ...
Two-phase flow, thermal management systems are currently being considered as an alternative to conventional, single phase systems for future space missions because of their potential to reduce overall system mass, size, and pumping power requirements. Knowledge of flow regime transitions, heat transfer characteristics, and pressure drop correlations is necessary to design and develop two-phase systems. This work is concerned with microgravity, two-phase flow regime analysis. The data come from a recent sets of experiments. The experiments were funded by NASA Johnson Space Center (JSC) and conducted by NASA JSC with Texas A M University. The experiment was on loan to NASA JSC from Foster-Miller, Inc., who constructed it with funding from the Air Force Phillips Laboratory. The experiment used R12 as the working fluid. A Foster-Miller two phase pump was used to circulate the two ...
Two-phase flow, thermal management systems are currently being considered as an alternative to conventional, single phase systems for future space missions because of their potential to reduce overall system mass, size, and pumping power requirements. Knowledge of flow regime transitions, heat transfer characteristics, and pressure drop correlations is necessary to design and develop two-phase systems. This work is concerned with microgravity, two-phase flow regime analysis. The data come from a recent sets of experiments. The experiments were funded by NASA Johnson Space Center (JSC) and conducted by NASA JSC with Texas A ampersand M University. The experiment was on loan to NASA JSC from Foster-Miller, Inc., who constructed it with funding from the Air Force Phillips Laboratory. The experiment used R12 as the working fluid. A Foster-Miller two phase pump was used to circulate the ...
Plasma arc welding processes are used in off-shore industry for construction and maintenance in the wet surrounding of underwater structures and pipelines. In greater water depth the density of the plasma gas increase because of the greater hydrostatic pressure. This causes the increase of conductive heat losses to the wet surrounding. To keep up the energy flux to the workpiece to be welded, the plasma arc has to burn in a local dry area with an inside pressure of 1 bar. This requirement can be fulfilled by a rotating cylinder with a liquid film flowing down the inner wall. The flow around the rotating cylinder to create a local dry area around the plasma arc under water is experimentally investigated. The rotating cylinder is placed above the work surface which is simulated by a flat plate. According to the centrifugal forces of the rotating flow inside the gap between the lower end of the cylinder and the flat plate the water is forced out of the cylinder. The velocity distribution ...
New RNAA determinations of Ba, Sr, Zr, U, Re, Pd, Ag, Zn and Se and INAA measurements of Lu are added to published data for 21 other elements in the same suite of ten samples. On the average, 21 refractory elements are not significantly fractionated from one another. The mean of their enrichment factors relative to C1 chondrites is 17.5 +- 0.4, indicating that the high-temperature condensate inclusions represent 5.7 wt% of the total condensable matter. Os, Ir, Ru, Re and most of the W condensed in one or more refractory siderophile element alloys along with small fractions of the Pd, Co, Au and Ag. The bulk of the Eu and Sr condensed in solid solution in melilite. Sc, Zr, Hf, Ta, U and the remaining REE condensed in a phase whose abundance in the inclusions in negatively correlated with that of melilite, either diopside or one or more minor or trace phases, including perovskite. Ba condensed in a different phase, separately ...
The n=4 Aurivillius phase, Bi5Ti3CrO15, was synthesised by solid state reaction. Rietveld analysis of high resolution neutron diffraction data demonstrated this material to adopt the polar space group A21am at room temperature, transforming to the aristotype I4/mmm structure above 650 oC. This phase transition is coincident with an anomaly in DSC signal and relative permittivity, which are characteristic of a ferroelectric-paraelectric phase transition. Bi5Ti3CrO15 exhibits paramagnetic behaviour at low temperature, with short range antiferromagnetic interactions, but no evidence for long range magnetic ordering. This is considered a consequence of significant disorder of Ti and Cr over the available octahedral sites, as demonstrated by analysis of neutron diffraction data. -- Graphical abstract: We report here the synthesis, structure and characterisation of the n=4 Aurivillius phase Bi5Ti3CrO15. ...
We study the surface and interface roughness of a two-liquid film system using neutron reflectometry. The middle phase and bottom phase are extracted from a three-phase microemulsion containing 2 wt% non-ionic surfactant C{sub 10}E{sub 4}, 81 wt% D{sub 2}O and 17 wt% octane (C{sub 8}H{sub 18}). The system is formed by spreading a few drops of the middle phase of the microemulsion on the bottom phase of the microemulsion. The middle phase does not wet the bottom phase, but demixes to form a top octane-water mixture layer with a thickness of {proportional_to}580 A. The mean surface roughness of the system is found to be 7 A but the data are insensitive to interface roughness. An extended capillary wave model for a two-liquid-film system is derived to account for the coupling between the surface and interface. The dispersion relation yields two ...
The information of phase transformation is attained by in situ XRD experiments leading to the knowledge of topological threshold in GeS2-Ga2S3 glasses. The turning point of phase transformation behavior is demonstrated to be glasses containing 14-15 mol% Ga2S3. To interpret it a network demixing model is further improved and proposed for the structure of these ternary or quasi-binary chalcogenide glasses. For the nearest-neighbor coordination environment of glass with a transitional composition of 85.7 mol% (6/7) GeS2.14.3 mol% (1/7) Ga2S3, six-coordinated [S3Ga-X-GaS3] units (X=S or None) are well isolated by the [GeS4] structures, which contributes to the decreasing of precipitation of Ga2S3 crystals in (100-x)GeS2-xGa2S3 (x?14.3) glasses corresponding to the experimental evidence of the phase transformation behavior. This scenario of intermediate-range structural order, firstly, includes the arrangement of structural ...
A vendor glass formulation study was carried out at Pacific Northwest Laboratory (PNL), supporting the Phase I and Phase II melter vendor testing activities for Westinghouse Hanford Company. This study is built upon the LLW glass optimization effort that will be described in a separate report. For Phase I vendor melter testing, six glass formulations were developed at PNL and additional were developed by Phase I vendors. All the doses were characterized in terms of viscosity and chemical durability by the 7-day Product Consistency Test. Twelve Phase II glass formulations (see Tables 3.5 and 3.6) were developed to accommodate 2.5 wt% P{sub 2}O{sub 5} and 1.0 wt% S0{sub 3} without significant processing problems. These levels of P{sub 2}O{sub 5} and SO{sub 3} are expected to be the highest possible concentrations from Hanford Site LLW streams at 25 wt% waste loading in glass. The ...
The purpose was to develop a simplified and reliable method of separating free from antibody-bound ligand using a precipitating antibody linked to a cellulose derivative. Dose-response curves and control sera were set up in parallel for various pituitary and placental polypeptides, steroid hormones, insulin, glucagon, triiodothyronine, thyroxine, angiotensin I, calcitonin, gastrin, cyclic AMP, and digoxin. After first-antibody reactions had reached equilibrium, free and bound ligand were separated using a double-antibody solid-phase system in parallel with conventional methods, including dextran-coated charcoal, double-antibody precipitation, single-antibody solid phase, organic solvents, salt precipitation, and anion-exchange resins. The effect of variations in temperature, incubation time, protein content, pH, and amount of separating material added were studied. The results showed that separation was complete within 1 hr for small ligand ...
The purpose was to develop a simplified and reliable method of separating free from antibody-bound ligand using a precipitating antibody linked to a cellulose derivative. Dose-response curves and control sera were set up in parallel for various pituitary and placental polypeptides, steroid hormones, insulin, glucagon, triiodothyronine, thyroxine, angiotensin I, calcitonin, gastrin, cyclic AMP, and digoxin. After first-antibody reactions had reached equilibrium, free and bound ligand were separated using a double-antibody solid-phase system in parallel with conventional methods, including dextran-coated charcoal, double-antibody precipitation, single-antibody solid phase, organic solvents, salt precipitation, and anion-exchange resins. The effect of variations in temperature, incubation time, protein content, pH, and amount of separating material added were studied. The results showed that separation was complete within 1 hr for small ligand ...
. This study investigates the geometric effects of 90-degree vertical elbows and flow configurations in two-phase flow. The study shows that the elbows make a significant effect on the transport characteristics of two-phase flow, which includes the changes in interfacial structures, bubble interaction mechanisms and flow regime transition. The effect of the elbows is characterized for global and local two-phase flow parameters. The global two-phase flow parameters include two-phase pressure, interfacial structures and flow regime transition. In order to characterize the frictional pressure drop and minor loss across the vertical elbows, pressure measurements are obtained across the test section over a wide range of flow conditions in both single-phase and two-phase flow conditions. A two-phase pressure drop correlation ...
In this study, the effects of channel surface wettability, cross-sectional geometry and orientation on the two-phase flow in parallel gas channels of proton exchange membrane fuel cells (PEMFCs) are investigated. Ex situ experiments were conducted in flow channels with three different surface wettability (hydrophilically coated, uncoated, and hydrophobically coated), three cross-sectional geometries (rectangular, sinusoidal and trapezoidal), and two orientations (vertical and horizontal). Flow pattern map, individual channel flow variation due to maldistribution, pressure drop and flow visualization images were used to analyze the two-phase flow characteristics. It is found that hydrophilically coated gas channels are advantageous over uncoated or slightly hydrophobic channels regarding un...
A real-time two-dimensional void fraction distribution measurement of gas-liquid two-phase flow was carried out by real-time neutron radiography and real-time image processing. The JRR-3M real-time thermal neutron radiography system and a Musashi dynamic image processing system were used. Image processing methods to calculate two-dimensional and cross-sectional void fraction distributions were proposed. The void fraction distribution was calculated by non-linear processing of the neutron radiography image and displayed by pseudo-color in real-time. A simple gas-liquid two-phase flow induced by injecting gas through needles at the bottom of water pool in a rectangular vessel was tested. (orig.).
Volume V of the documentation for the Phase I Data Analysis Task performed in support of the current Regional Flow Model, Transport Model, and Risk Assessment for the Nevada Test Site Underground Test Area Subproject contains the transport parameter and source term data. Because of the size and complexity of the model area, a considerable quantity of data was collected and analyzed in support of the modeling efforts. The data analysis task was consequently broken into eight subtasks, and descriptions of each subtask's activities are contained in one of the eight volumes that comprise the Phase I Data Analysis Documentation.
Volume III of the documentation for the Phase I Data Analysis Task performed in support of the current Regional Flow Model, Transport Model, and Risk Assessment for the Nevada Test Site Underground Test Area Subproject contains the data covering groundwater recharge and discharge. Because of the size and complexity of the model area, a considerable quantity of data was collected and analyzed in support of the modeling efforts. The data analysis task was consequently broken into eight subtasks, and descriptions of each subtask's activities are contained in one of the eight volumes that comprise the Phase I Data Analysis Documentation.
In this paper, the widely used models of Taitel-Dukler and Weisman et al. are extrapolated to microgravity levels to compare predicted flow pattern boundaries for horizontal and vertical flows. Efforts have been made to analyze how the two-phase flow models available in the literature predict flow regime transitions in microgravity. The models of Taitel-Dukler and Weisman et al. have been found to be more suitable for extrapolation to a wide range of system parameters than the other two-phase flow regime maps available in the literature. The original criteria for all cases are used to predict the transition lines, except for the transition to dispersed flow regime in case of the Weisman model for horizontal flow. The constant 0.97 on the righthand side of this correlation should be two times that value, i.e., 1.94, in order to match this transition line in their original paper.
This paper describes a series of tests investigating two-phase flow regimes in a transparent model of a PWR hot leg. Test conditions were selected to cover a wide range of gas and liquid superficial velocities (.01 m/s 2 m/s) were also performed for comparison with semi-analytical predictions. Results include average void fractions, flow rates, and visual characterizations of the two-phase flow phenomena. Results show generally good agreement with Taitel and Duckler flow regime map and Zuber-Findlay correlation for average void fraction in vertical pipes. Results also indicate that flow regimes and collapsed liquid level (void fraction) are more strongly dependent on air flow rate (air superficial velocity) than water flow rate (water superficial velocity).
In order to practice a design-by-analysis of thermohydraulics design of BWR fuel rod bundles, the subchannel analysis would play a major role. There, the immediate concern is improvement in its predictive capability of CHF due in particular to the film dryout (boiling transition phenomena: BT) on the fuel rod surface. Constitutive equations in the subchannel analysis formulation are responsible for the quality of calculated results. The constitutive equations are a result of integration of the local and instantaneous description of two-phase flows over the subchannel control volume. In general, they are expressed in terms of subchannel-control-volume- as well as area-averaged two-phase flow state variables. In principle the information on local and instantaneous physical phenomena taking place inside subchannels must be counted for in the algebraic form of the equations on the basis of a more mechanistic modeling approach. They should include ...
In recent years, there has been increased emphasis on techniques to enhance two-phase flow heat transfer. The resulting increase in the use of heat transfer augmentation and the engineering importance of the subject presents this investigation in order to study the effect of different heater surface configurations on two-phase flow instabilities. The authors present the results of an experimental and theoretical study, summarized as: instabilities are not affected by small changes in heat transfer; nucleate boiling increases system unstability; amplitude of the oscillations increases as the axial temperature gradient over the heater increases; for the same type heater surfaces system stability increases with decreasing equivalent diameter; period of the oscillations depend on the heater surfaces; and linearized analysis and steady-state data can be used to determine the oscillation thresholds.
A magnetic rhombohedral PrCo_2C_x (x = 0.05 #approx#0.25) phase (space group Rbar 3m), which is heavily twinned along the #left brace#110#right brace# and #left brace#211#right brace# planes, was identified. The twinning mechanism was explored by analyzing the reduction of crystal symmetry due to the cubic-rhombohedral phase transformation. The origin of the twinning and the formation of four twin variants were attributed to the insertion of carbon interstitials into Co_4 tetrahedrons along the bar 3 axis in the rhombohedral lattice, which corresponds to one of the four equivalent axes of its parent PrCo_2 cubic-lattice.
The project is focused on the thermal hydraulic analyses of nuclear power plants. Specific areas of research have been the modelling of heat transfer in horizontal steam generator in presence of non-condensable gas, and the development of tools for multidimensional two-phase flow simulations. The effect of non-condensable gas on the heat transfer in the horizontal steam generator (SG) has been studied by calculating with APROS the PACTEL experiments NCG-1 (air injection) and NCG-3 (helium injection). The work done for the two-phase flow model development consists of two parts; improving the solution algorithm of porous media code PORFLO, and adding a homogeneous two-phase model to the commercial CFD code Fluent. (orig.)
La{sub 1-x}Sr{sub x}MnO{sub 3} (LSMO) compounds (0.175{<=}x{<=}0.30) were prepared by conventional solid-state reaction method. Temperature dependence of the total hemispherical emittance ({epsilon}{sub H}) of the compounds from 173 to 373 K was measured on a calorimetric emissometer (CE) which was constructed based on the steady-state calorimetric method. The compounds show thermochromic properties and {epsilon}{sub H}'s have low value at low temperature and have high value at high temperature, because the compounds are dominated by metallic phase and insulator phase, respectively. We use the phase separation model to interpret the temperature dependence of {epsilon}{sub H}. (author)
The thermal conductivity of liquid CHCl3, C6H6, and CCl4 is measured by a steady-state method under saturated vapor pressure in the temperature regions corresponding to pre-crystallization temperatures. The experimental results obtained are used to investigate the isobaric thermal conductivity jump ? ?p at the crystal-liquid phase transition in CHCl3, C6H6, and CCl4. The contributions of the phonon-phonon and phonon-rotational interaction to the total thermal resistance in solid and liquid state are specified using a modified method of reduced coordinates. The decrease in the thermal conductivity at the crystal-liquid phase transition, ? ?p, is explained by a combined effect of variations in positional distribution of molecules and in the form of rotational molecular motion.
The thermal conductivity of liquid CHCl3, C6H6, and CCl4 is measured by a steady-state method under saturated vapor pressure in the temperature regions corresponding to pre-crystallization temperatures. The experimental results obtained are used to investigate the isobaric thermal conductivity jump ??p at the crystal-liquid phase transition in CHCl3, C6H6, and CCl4. The contributions of the phonon-phonon and phonon-rotational interaction to the total thermal resistance in solid and liquid state are specified using a modified method of reduced coordinates. The decrease in the thermal conductivity at the crystal-liquid phase transition, ??p, is explained by a combined effect of variations in positional distribution of molecules and in the form of rotational molecular motion.
Comparative patterns of equilibrium adsorption of argon on the surface of graphitized thermal carbon black (GCB) and the inhomogeneous surfaces of nongraphitized carbon black and silica at 77 and 87.3 K were considered. It was shown that argon acquires the properties of a special phase with a layered structure and exhibits two-dimensional phase transitions with the formation of crystal-like layers near the homogeneous surface of GCB even at a temperature exceeding the triple point. However, already at a distance of three-four molecular diameters from the surface, adsorbed argon behaves as a bulk phase in a weak external field. The defect surface of nongraphitized carbon black and the amorphous surface structure of silica destroy the longrange order of adsorbed argon and lower its solidific...
The stability of a couple stress fluid saturated horizontal porous layer heated from below and cooled from above when the fluid and solid phases are not in local thermal equilibrium is investigated. The Darcy model is used for the momentum equation and a two-field model is used for energy equation each representing the solid and fluid phases separately. The linear stability theory is employed to obtain the condition for the onset of convection. The effect of thermal non-equilibrium on the onset of convection is discussed. It is shown that the results of the thermal non-equilibrium Darcy model for the Newtonian fluid case can be recovered in the limit as couple stress parameter C?0. We also present asymptotic analysis for both small and large values of the inter phase heat transfer coefficient H. We found an excellent agreement between the exact solutions and asymptotic solutions when H is very small.
We study the finite temperature electroweak transition with non-perturbative lattice Monte Carlo simulations. We find that it is of first order, at least for Higgs masses up to 80 GeV. The critical temperature of the phase transition is found to be smaller than that determined by a 2-loop renormalization group improved effective potential. The jump of the order parameter at the critical temperature is considerably larger than the perturbative value. By comparing lattice data and perturbation theory, we demonstrate that the latter, for the computation of the vacuum expectation value of the Higgs field v(T) in the broken phase at given temperature, converges quite well, provided v(T)/T>1. An upper bound on the Higgs mass necessary for electroweak baryogenesis in the light of the lattice data is briefly discussed.
In this study the results of mathematical simulation and experimental research of texture transition in stress assisted shear phase transformations are discussed. The orientation distribution function (ODF) calculation model to the any type crystalline lattice symmetry materials has been suggested. By crystalline lattice symmetry analysis this computer program determines necessary amount of the initial experimental data. The experimental verification supports this model well. The ODF calculation model after shear phase transformation with equal use of all possible variants of orientation relationship or with various degrees of variant selection worked out. In this study the experimental and calculating data of the direct and reversal shear transformations #alpha# <=> #gamma# in Fe-alloys and B2 <=> B19' in Ti-Ni alloys are discussed. The stress assisted shear phase transformation model and computer program to ...
In this work, the pulse plasma nitriding process of pure iron is modelled using a kinetic model derived from the Fick's laws. This approach based on the error function model allows to simulate the growth kinetics of a biphase configuration consisting of {gamma}'-Fe{sub 4}N{sub 1-x} and {epsilon}-Fe{sub 2-3}N iron nitrides under specified conditions. By coupling the kinetics data about the diffusivities of nitrogen in {alpha}-Fe, {gamma}' and {epsilon} phases to the thermodynamic description of the Fe-N phase diagram, it is possible to evaluate the kinetic constant at each growing phase interface, the thickness of nitrided layer, and predict the nitrogen concentration profiles. The comparison between the experimental and theoretical results shows the reliability of the simulation results.
In this work, the pulse plasma nitriding process of pure iron is modelled using a kinetic model derived from the Fick's laws. This approach based on the error function model allows to simulate the growth kinetics of a biphase configuration consisting of #gamma#'-Fe_4N_1_-_x and #epsilon#-Fe_2_-_3N iron nitrides under specified conditions. By coupling the kinetics data about the diffusivities of nitrogen in #alpha#-Fe, #gamma#' and #epsilon# phases to the thermodynamic description of the Fe-N phase diagram, it is possible to evaluate the kinetic constant at each growing phase interface, the thickness of nitrided layer, and predict the nitrogen concentration profiles. The comparison between the experimental and theoretical results shows the reliability of the simulation results.
The temperature dependences of the Grueneisen parameter, heat capacity, bulk modulus and linear thermal expansion coefficient of sixteen III-V zincblende compounds are studied by first-principles response-function calculations. The fundamental relationships among these physical parameters are explored. Negative thermal expansions at lower temperature are found in most of these III-V phases except for the nitrides and boron compounds. By analyzing the cell-volume dependences of the phonon spectrum, it is found that the phases with a negative thermal expansion show a significant acoustic phonon weakening at the X-point in their phonon dispersion, while slight weakening is only seen around the L-point for those boron phases. There is no sign of phonon weakening in the nitrides. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
Phase and structural transformations in a multicomponent (5.05 mas.% Mo-4.95V-3.00Cr-3.05Al) metastable #beta#-titanium alloy on aging after plastic deformation are studied using methods of electron microscopy and X-ray diffraction analysis. The alloy is deformed by twinning in a #left brace#332#right brace# system, and even at initial stages the formation of a twin skeleton takes place in the structure, on further loading the deformation of the skeleton is by secondary twinning resulting in a high plasticity of the alloy. On annealing mechanical twins transform into #alpha#-phase - a ductile twin skeleton is replaced by a rigid skeleton of #alpha#-phase plates. The aging enhances the yield strength of the alloy but decreases sharply its plasticity
Strain embrittlement in Ti base alloys during tensile testing was investigated. Results show that in an #alpha#-#beta# titanium alloy the local activity of H in alpha phase (#alpha#/sub H//sup #alpha#) increases and activity of H in beta phase (#alpha#/sub H//sup #beta#) decreases as the equiaxed #alpha# particle size decreases at constant volume fraction of phases. Thus with decreasing particle size there would be a tendency for H to move from #alpha# to #beta#, decreasing the H content of #alpha#. Also whether H tended to move from #beta# to #alpha# or from #alpha# interiors to the #alpha#-#beta# interface this tendency would be reduced by surface tension effects, making the alloy less susceptible to embrittlement.
Remote detection of chemicals using LIDAR (Light Detection and Ranging) utilizing DIAL (Differential Absorption LIDAR) is now a standard detection technique for both military and civilian activities. We have developed a novel nonlinear optical phase conjugation system that can reduce the effects of speckle noise and atmospheric turbulence on DIAL remote detection systems. We have shown numerically and experimentally that it is possible to increase the signal-to-noise (S/N) ratio for LIDAR systems under certain conditions using optical phase conjugation. This increase in S/N can result in more accurate detection of chemical effluents while simultaneously reducing the time necessary to acquire this information.
Low energy (<100 eV) Ar"+ ion bombardment of the growing film during the deposition of amorphous GaSb+Ge mixtures was found to affect both the transformation rate kinetics as well as the reaction path during subsequent annealing. Ion bombardment induced collisional cascades resulted in more random mixing in the growing films thus retarding the rate of the amorphous to equilibrium state phase transformation during annealing and allowing the formation of homogeneous metastable randomly oriented single phase (GaSb)/sub 1-x/Ge/sub x/ alloys. The films were approx.1.5 #mu#m thick and the average grain size in the metastable state was approx.300 A.
We report the simultaneous formation of self-assembled surface ripples in Cd{sub 2}Nb{sub 2}O{sub 7} pyrochlore caused by focused ion beam (FIB) patterning and uniformly distributed metallic nanodots induced by phase decomposition under ion bombardment. The characteristic wavelength of the surface ripples is controllable from the nm to the sub-{micro}m scale. High-density Cd metallic nanoparticles, {approx} 5 nm, formed and the distribution of nanoparticles is consistent with the morphological characteristics of the ripple pattern. This approach provides a means of fabricating surface nanostructure with various patterns and a controllable particle size and distribution by combining ion beam-induced phase decomposition with high-precision FIB patterning.
Corrosion of steam generator heat transfer tubes (SGHTT) is one of the important problems which affect safety operation of nuclear power plants (NPP), and the hazard of pitting corrosion of heat transfer tubes is the most serious. With an acoustic emission device, the signals during a corrosion test on SGHTT were collected and analyzed, and the corrosion points in the tubes were located accurately. The results show that pitting corrosion of heat transfer tubes has passed through three periods in its development: expansion phase, stationary phase and rapid developing phase. The corrosion damage of HTT can be found earlier with acoustic emission than any other non-destructive testing methods. Acoustic emission can be used for on-line and real-time monitoring of the safety and operation of the steam generator and has therefore a great significance. (orig.)
The #beta#-CEZ alloy : Ti-5%Al-2%Sn-4%Zr-4%Mo-2%Cr-1%Fe is a near #beta# titanium alloy. Since its processing routes include heat treatment (consisting of solution treatment and ageing), it has been decided to study the influence of the #beta# phase stability on #alpha# phase precipitation and hardening kinetics. Small sized specimens, coming from industrial heats, have been heat treated above and below the #beta# transus, and then water quenched. Therefore, several degree of #beta# stability are obtained. When it is increased (i.e. the solution treatment temperature is lowered), #alpha# or #omega# phases precipitations are delayed, as well as the hardening phenomena. Moreover, the #omega# stability domain is reduced. The mechanisms of #alpha# or #omega# precipitation are discussed, and related to the hardening kinetics. (orig.).
In the present investigation, the properties of plasma nitrided AISI 304 steel were studied by changing the presence of nitrogen in the gas mixture. The plasma nitriding was performed at temperature -560 deg C, pressure -4 mbar and duration 24 hours. The nitrided samples were characterized by evaluating the phase composition, micro hardness, and diffusion layer thickness. The phase analysis indicates the mixed phases of CrN and Fe_3N, Fe_3N and Fe_4N which has the highest intensity. The results show the glow discharge plasma nitriding in presence of N_2 (80 vol. %) and H_2 (rest) produced higher hardness as well as higher case depth. (author)
Photoelectron resonance capture ionization (PERCI) is a soft and sensitive ionization method, based on the attachment of low-energy (<1 eV) photoelectrons to organic analyte molecules. PERCI has been developed in our laboratory for the real-time analysis of organic particles by mass spectrometry, and is employed here to monitor the heterogeneous reaction of ozone with oleic acid. Simplified identification of the reaction products is possible as a result of the soft nature of PERCI, giving predominantly the [M--H](-) ions. The major particle-phase products are identified as: 1-nonanal, nonanoic acid, 9-oxononanoic acid, and azelaic acid, consistent with proposed mechanisms. New insight into this well-studied heterogeneous reaction is gained as additional minor particle-phase products, consistent with the Criegee mechanism, are readily detected. PMID:15468105
Abstract Phase-separation dynamics are investigated by SALS in aqueous MC solutions in the presence of 5% NaCl, promoted by a quench temperature. The observed scattering peak indicates that the phase separation occurs by the SD mechanism, leading to a bicontinuous structure. A semilog plot of I(q) against time in the early stage of SD gives a straight line, but the position of qmax varies; also, a Cahn-Hilliard plot indicates that diffusive processes dominate and the data can be described by linear CHC theory. Dapp shows a kinetic dependency on the quench temperature. The spinodal temperature of the sample is 41-C. In the late stages, S(q,t) collapses into a universally time-independent curve.
A phase transition of gas-liquid type with an upper critical point is examined which arises in a model of charges of one sign on compensating background (OCP). The phase transition parameters are dependent on the detailed assumptions about the compressibility of the background, but the occurrence of this transition is independent on the background equation of state. In the electron-gas model ('jellium'), this transition appears to rule out Wigner crystallization. A variational principle in statistical mechanics is used to derive so-called Double-OCP model for a superposition of two one-component plasma models for charges of opposite sign. The free energy of this model sets an upper bound to that of a real plasma. Situations are discussed where this transition should manifest itself in anomalies in the approximate description of a non-ideal plasma.
This work reports phase equilibrium measurements for the ternary systems linoleic (acid+CO2+ethanol) and (linolenic acid+CO2+ethanol). The fatty acids present in the ternary systems were selected based on composition of banana peel oil extracted by supercritical CO2 at 20MPa and 313K. The motivation of this research relies on the fact that these unsaturated fatty acids are recognized to play an important role in lowering blood pressure and serum cholesterol and because they are present in high concentrations in banana peel extract. Besides that, equilibrium data of these compounds are scarce in literature. The phase equilibrium experiments were performed using a high-pressure variable-volume view cell over the temperature range of (303 to 343)K and pressures up to 19MPa. For both systems, ...
This paper investigates the phase change behavior of 65 mol% capric acid and 35 mol% lauric acid, calcium chloride hexahydrate, n-octadecane, n-hexadecane, and n-eicosane inside spherical enclosures to identify a suitable heat storage material. Analytical models are developed for solidification and melting of sphere with conduction, natural convection, and heat generation. Both the models are validated with previous experimental studies. Good agreement was found between the analytical predictions and experimental study and the deviations were lesser than 20%. Heat flux release at the wall, cumulative energy release to the external fluid, are revealed for the best PCM. The influence of the size of encapsulation, initial temperature of the PCM, the external fluid temperature on solidified and molten mass fraction, and the total phase change time are also investigated. (author)
#beta#-sialon ceramics of equal overall compositions but containing amorphous, partly crystalline and almost completely crystalline intergranular phase(s) have been oxidized in oxygen at 1350 deg C for 20 hours. The obtained weight gain curves do not follow the parabolic rate law (#DELTA#W/A_0)"2= k_pt + #beta#. To the extent that crystallization occurs in the oxide scale during the oxidation experiment, the amorphous cross section area through which oxygen most easily diffuses will decrease with time. A brief description of this new rate law is given, and the obtained oxidation curves will be discussed within that framework. 4 refs., 2 tabs., 2 figs.
The microstructure evolution of nine samples from three Ir-base ternary systems, Ir-Nb-Hf, Ir-Nb-Ta, and Ir-Nb-Ti, was investigated by microstructure observation using scanning electron microscopy (SEM), composition map-analysis using electron probe microscopy analysis (EPMA), and phase determination using X-ray diffraction (XRD) patterns. The fcc/L1{sub 2} two-phase structure was detected in all the samples. Lattice misfits between fcc and L1{sub 2} phases were calculated. Ir-Nb-Ta and Ir-Nb-Ti alloys exhibited a microstructure quite similar to that of Ni-base superalloys, and the cuboidal L1{sub 2} precipitates in Ir-Nb-Ta and Ir-Nb-Ti alloys could maintain up to 1900 {sup o}C.
A method of modeling freeze-thaw cycles of naturally deposited snowpacks is presented. The model involves the Stefan condition as an independent governing equation on the exterior moving boundary to calculate snowpack thinning, flow of water through a variably saturated layered porous medium as described by the Richards equation, and heat conduction with a phase change. The heat conduction problem was treated in two ways. Local heat conduction between a snow grain and its surrounding water film was treated by using a simple energy balance. Global heat conduction with a phase change (the Stefan problem) was introduced to calculate the space-time temperature distribution. In order to handle multiple interior moving boundaries, a specific form of the enthalpy formulation was used for heat conduction with a phase change. Changing material properties were considered according to the calculated meltwater refreezing. 48 refs., 11 ...
Background vibration in a CANDU plant can be used to determine the dynamic characteristics of major items of equipment, such as calandria, the fuelling machines and the primary heat transport pumps. These dynamic characteristics can then be used to verify the seismic response of the equipment which, at present, is based on theoretical models only. The feasibility and basic theory of this new approach (which uses accelerations measured at several points on a structure and does not require knowledge of the source of excitation) was established in Phase I of the study. This report is based on Phase II in which the methods of analysis developed in Phase I were improved and verified experimentally. A Fast Fourier Transform (FFT) algorithm was incorporated and an interactive curve fitting technique was developed to obtain the dynamic characteristics in the form of natural frequencies, mode shapes and damping ratios. The method is ...
The in-depth distribution of phases in c-BN films deposited by Ion Beam Assisted Deposition (IBAD) at two different ion energy values (300 and 600 eV) was investigated using the quantitative IR transmission measurements and the HREM technique. Whatever the value of the studied ion energies, the characteristic layered morphology of c-BN film is observed including the interfacial sp"2 zone between the substrate and the c-BN volume. In the case of 600 eV ion energy, this interfacial zone is less well-defined in comparison with 300 eV ion energy and the corresponding thickness is more important. Furthermore, the h-BN phase is more diluted within the c-BN film volume showing that the purest phase concentration of c-BN is found for the lowest ion energy, i.e., 300 eV.
A micromachined vertical actuator utilizing a levitational force, such as in electrostatic comb drives, provides vertical actuation that is relatively linear in actuation for control, and can be readily combined with parallel plate capacitive position sensing for position control. The micromachined electrostatic vertical actuator provides accurate movement in the sub-micron to micron ranges which is desirable in the phase modulation instrument, such as optical phase shifting. For example, compact, inexpensive, and position controllable micromirrors utilizing an electrostatic vertical actuator can replace the large, expensive, and difficult-to-maintain piezoelectric actuators. A thirty pound piezoelectric actuator with corner cube reflectors, as utilized in a phase shifting diffraction interferometer can be replaced with a micromirror and a lens. For any very precise and small amplitudes of motion` micromachined ...
A flow pattern or flow regime is the characteristics spatial distribution of the phases of fluid in a duct. Since heat transfer and pressure drop are dependent on the characteristic distribution of the phases, it is necessary to describe flow patterns in an appropriate manner so that a hydrodynamic or heat transfer theory applicable to that pattern can be chosen. The objective of the present analysis is to create a flow regime map based on physical modeling of vapor/liquid interaction phenomena in a microgravity environment. In the present work, four basic flow patterns are defined: dispersed flow, stratified flow, slug flow, and annular flow. Fluid properties, liquid and vapor flow rates, and pipe size were chosen as the principal parameters. It is assumed that a transition from one flow pattern to another will occur when there is a change in the dominant force which controls that flow pattern. The forces considered in this modeling are ...
The separation and the mechanism of retention of ion associates of #alpha#-isomers of molybdic and tungstic heteropoly acids (HPA) of phosphorus(5), silicon(4), and germanium(4) with trioctylamine (TOA) on a column (80x3 mm) packed with Diasorb-130-CN (8 #mu#m) were studied in a flow of chloroform-tetrahydrofuran (THF) and chloroform-n-butanol-TOA mixtures with spectrophotometric detection at 320 nm. It is demonstrated that the adsorption of all the studied ion associates proceeds through the displacement THF molecule from the surface of the stationary phase and without the displacement of TOA molecules. Conditions for the separation of phospho- and silicomolybdic HPA and also phospho- and germanolybdic HPA were found. The chromatographic system using silica gel modified with nitrile groups as the stationary phase is of higher selective than that using ummodified silica gel.
In the frame of the Primary Wall Module prototype manufacturing for ITER, a consistent R and D phase was conducted in order to identify the industrial allowable tolerances and manufacturing problems which would occur when joining pieces by HIPping process during the PW module manufacturing. The purpose of this development was to give as industrial as possible manufacturing routes for joining together large Stainless Steel or DS-Copper pieces with Stainless Steel tubes and for bonding Beryllium tiles onto a curved component surface. The study concerned surface preparations, allowable gaps and joint geometry, Beryllium tile geometry, Titanium interlayer thickness, etc. This R and D phase also allowed the development and validation of different ultrasonic inspection tools needed for plate-plate, tube-plate, edge to edge plate bonding.
This paper introduces a novel three-phase power flow approach for unbalanced radial distribution systems. The proposed approach is developed based on the loop frame of reference, rather than the traditional bus frame of reference. On the basis of the loop frame of reference, a simple direct iterative method in impedance form is applied. Basic graph theory and injection current technique are also applied in the proposed approach. The clear theoretical foundation and the simple topology of the radial distribution network make the proposed method efficient and reliable. To demonstrate the better convergence performance and the efficiency of the proposed approach, four three-phase IEEE test feeders are used for comparisons. The test results show that the proposed method has robust convergence characteristics and high performance, especially for large-scale radial distribution systems. (author)
In globulitic gray iron (3.6 wt.% C, 2.4 wt.% Si and 0.45 wt.% Mn) the decomposition of austenite into bainite is investigated in real time using a new method based on neutron scattering. During the phase transformation transmission spectra of thermal neutrons are continuously recorded containing specific Bragg edges. Thus, the transformation is followed in-situ time resolved by evaluating the relative (micro)structural fractions of the transforming phases from the heights of the corresponding Bragg edges. The progression of the transformation is described and the results are discussed. The observed late time deviations from the Avrami law are explained by residual stresses of the second kind (homogeneous microstresses), which occur during the transformation because of the different specific volumes of the phases. ((orig.))
In globulitic gray iron (3.6 wt.% C, 2.4 wt.% Si and 0.45 wt.% Mn) the decomposition of austenite into bainite is investigated in real time using a new method based on neutron scattering. During the phase transformation transmission spectra of thermal neutrons are continuously recorded containing specific Bragg edges. Thus, the transformation is followed in-situ time resolved by evaluating the relative (micro)structural fractions of the transforming phases from the heights of the corresponding Bragg edges. The progression of the transformation is described and the results are discussed. The observed late time deviations from the Avrami law are explained by residual stresses of the second kind (homogeneous microstresses), which occur during the transformation because of the different specific volumes of the phases. ((orig.)).
Heat-transfer augmentation by straight grid spacers in rod bundles is studied for single-phase flow and for post-critical heat flux dispersed flow. The heat transfer effect of swirling grid spacers in single-phase flow is also examined. Governing heat-transfer mechanisms are analyzed, and predictive formulations are established. For single-phase flow, the local heat transfer at a straight spacer and at its upstream or downstream locations are treated separately. The effect of local velocity increasing near swirling spacer is considered. For post critical heat flux (CHF) dispersed flow, the heat transfer by thermal radiation, fin cooling, and vapor convection near the spacer are calculated. The predictions are compared with experimental data with satisfactory agreement.
The difference between the two nonclassical lights, i.e., the squeezed state and number-phase minimum uncertainty state (NUS) is discussed. The four different generation principles for NUS are described. They are: unitary evolution using self-phase modulation; nonunitary state reduction by the first kind measurement; controlled state reduction by quantum correlation measurement-feedback, and high saturated laser oscillation with suppressed-pump-noise. The constant current-driven semiconductor laser based on the last principle generated the NUS with photon number noise reduced below the standard quantum limit by 40 percent in the entire frequency region from dc to 1.1 GHz. Several applications of NUS including quantum communication, quantum mechanical computers and interferometric gravitational detection are discussed briefly. This presentation is represented by viewgraphs only.
Fractionation of isotopes of the alkali metals and the alkaline earth metals in ion exchange chromatography of their chlorides was studied. The heavier isotopes of potassium and rubidium were found to be preferentially fractionated into the ion exchanger phase while the lighter isotopes of lithium, magnesium, calcium and strontium were enriched in the exchanger phase. This can be interpreted as a resultant of the relative significance of isotope effect upon dehydration and isotope effect accompanying the phase change of the hydrated metal ion. Found was no evidence of anomalous isotope effect attributable to the odd-even difference in mass number of isotopes. Based on the spectroscopic and solution chemical data (experimental and theoretical), the isotopic reduced partition function ratios of the hydrated alkaline metal ions and stretching force constants of metal ion-hydrating water bonds were estimated. (author).
The Weyl-Wigner prescription for quantization on Euclidean phase spaces makes essential use of Fourier duality. The extension of this property to more general phase spaces requires the use of Kac algebras, which provide the necessary background for the implementation of Fourier duality on general locally groups. Kac algebras - and the duality they incorporate are consequently examined as candidates for a general quantization framework extending the usual formalism. Using as a test case the simplest non-trivial phase space, the half-plane, it is shown how the structures present in the complete-plane case must be modified. Traces, for example, must be replaced by their noncommutative generalizations - weights - and the correspondence embodied in the Weyl-Wigner formalism is no more complete. Provided the underlying algebraic structure is suitably adapted to each case, Fourier duality is shown to be indeed a very powerful ...
First-principles density functional theory (DFT) based calculations were performed to study the electronic and cohesive properties of all the intermediate ordered phases appearing in the transformation from bcc-based #beta# to hexagonal ordered #omega# phase in Zr_3Al alloy. Full-potential linear augmented plane wave (FPLAPW) method under the GGA was employed to establish the stability hierarchy and structure-property correlations. Further, effective pair potentials upto the fourth nearest neighbours were extracted, which, subsequently, were used for the thermodynamics analysis of the thermally-induced #beta##->##omega# transformation. The lattice collapse mechanism involving the concept of the onset of a displacement wave where the extent of collapse is viewed as an amplification of the displacement wave was employed for further analysis. (author)
X-ray diffraction enhanced imaging (DEI) is one of X-ray phase-contrast imaging methods, which is applied to inspect internal structures of weakly absorbing low-Z samples. The key problem of the DEI is how to extract phase information which is expressed by refraction-angle images from a series of DEI images measured in different positions of the rocking curve of the analyzer. Three effective extraction methods are presented in this paper: the statistical geometric-optics-approximation method, the maximum refraction-angle method and the Gaussian curve fitting method. They are compared with the existing methods, such as the D. Chapman's geometric optics approximation method and the multiple-images statistical method. A 2D computer simulation experiment is performed to draw comparisons of these methods. The experimental results prove that the above three methods have more precision of refraction-angle values than existing methods.
X-ray diffraction enhanced imaging (DEI) is one of X-ray phase-contrast imaging methods, which is applied to inspect internal structures of weakly absorbing low-Z samples. The key problem of the DEI is how to extract phase information which is expressed by refraction-angle images from a series of DEI images measured in different positions of the rocking curve of the analyzer. Three effective extraction methods are presented in this paper: the statistical geometric-optics-approximation method, the maximum refraction-angle method and the Gaussian curve fitting method. They are compared with the existing methods, such as the D. Chapman's geometric optics approximation method and the multiple-images statistical method. A 2D computer simulation experiment is performed to draw comparisons of these methods. The experimental results prove that the above three methods have more precision of refraction-angle values than existing methods.
The investigation of steam, water, and air flow characteristics in horizontal channel is a part of major investigations program at the Lithuanian Energy Institute. The objective of this program is to identify condensation effects on two-phase flow stability and to predict conditions when rapid condensation could be induced in two-phase condensable flow. This article presents investigation of steam-water and air multiphase flow in nearly horizontal rectangular channel. The experimental data for pressure drop and interfacial and wall shear stresses in the channel with uniform distribution of void fraction are presented in this paper. Overall channel dimensions are length = 1.2 m, width = 0.02 m, height = 0.1 m; however, the test section was about 0.84 m in length. Three different flow types ...
As a method to make use of a high latent heat of a liquid-solid phase change material in a confined convective heat transfer, a phase change material, lauric acid, was encapsulated in a tiny hollow sphere, and mixed with water, forming a slurry of microencapsulated phase-change material (MCPCM slurry). Four different sizes (200, 100, 50, and 25 {mu}m ID) of MCPCMs were tested in this study. Thermal characteristics of the pure lauric acid and lauric acid MCPCMs were tested by a differential scanning calorimeter. Viscosity of the slurries of water and the capsules was measured by a rotating viscometer. The slurries were also tested in a convective-heat-transfer-test apparatus. (author). 11 refs., 5 figs., 1 tab.
Comparative indices are given for the efficiency of phase control of remote-controlled self-compensating high-voltage transmission lines, including a consideration of the power transfer effect between high-voltage line circuits. A description is given of certain circuit variations for performing the technical means of regulating phase shift, and their characteristics which make it possible to evaluate the effect of the phase regulators on the electrical transmission system are also given. An examination is made of problems concerned with the design of lines, relay protection, computation of transfer processes and dynamic stability as well as the computation of over-voltage when shutting off short circuits during amplified electromagnetic ties between line circuits.
Thin Pt, Pd, Pt/sub 2/Si, PtSi, Pd/sub 2/Si, Ni, Mo, W, Nb, Ti, V films deposited on Si single crystal were treated by using electron beam pulses of 60 ns duration in the 0.4-4 J/cm/sup 2/ energy density range. Irradiation of these structures produces at the same time many phases. Post-thermal annealing of the reacted layer induces the formation of a stable phase, the same obtained by only thermal treatment in a conventional furnace. A linear relationship between the energy density range and the lowest eutectic temperature of the compounds formed has been found. Further SEM observations seem to identify a liquid layer from which the phases are forming by subsequent fast cooling.
Thin Pt, Pd, Pt_2Si, PtSi, Pd_2Si, Ni, Mo, W, Nb, Ti, V films deposited on Si single crystal were treated by using electron beam pulses of 60 ns duration in the 0.4-4 J/cm"2 energy density range. Irradiation of these structures produces at the same time many phases. Post-thermal annealing of the reacted layer induces the formation of a stable phase, the same obtained by only thermal treatment in a conventional furnace. A linear relationship between the energy density range and the lowest eutectic temperature of the compounds formed has been found. Further SEM observations seem to identify a liquid layer from which the phases are forming by subsequent fast cooling. (author).
In the paper results of the investigation on the effect of microstructure on room temperature tensile properties and fracture toughness of two-phase #alpha#+#beta# titanium alloy Ti-6Al-2Mo-2Cr have been presented. Microstructure has been varied by changes in the cooling rate from the solution treatment temperature and aging time and temperature. Mechanical properties examined show dependence on the treatment conditions, especially aging conditions. It has been attributed mainly to the amount and morphology of #alpha# phase obtained after heat treatment. The higher volume fraction of lamellar #alpha# structure, the higher fracture toughness. (author)
In this study, effects of alloying elements such as Mo, Cr and Ni on intergranular corrosion (IGC) resistance of Mo contained austenitic stainless steels in boiling 65% nitric acid solution (Huey Test) were studied. Obtained results are as follows; (1) Mo deteriorates IGC resistance of austenitic stainless steel in Huey test due to enhance precipitation of Laves ((Fe, Cr)_2Mo) phase at grain boundary. (2) Cr improves IGC resistance of Mo contained austenitic stainless steel in Huey test, which is considered to reduce dissolution rate of Laves phase into nitric acid solution by increasing Cr content in Laves phase as increasing Cr content of stainless steel. (3) Ni suppresses occurrence of IGC of Mo contained austenitic stainless steel in Huey test. (author).
#alpha#/#beta# sialon based composites containing silicon nitride whisker and silicon carbide platelet were fabricated by hot pressing. Effect of the reinforcing agents on the #alpha# to #beta# phase transformation of the sialon as well as on the mechanical properties was investigated. Silicon nitride whisker and silicon carbide platelet promoted the phase transformation. TEM/EDS analysis revealed that the grain containing the whisker had 'core-rim' structure; core being high purity Si_3N_4 whisker and rim being #beta#-sialon. Flexural strength of the composite decreased with the reinforcement addition which, on the other hand, improved fracture toughness of it. High temperature strength was measured at 1300 deg C to be about 130 MPa lower than that measured at RT for the whisker reinforced composite. (author).
Injections of fuel-grade ethanol (95% v/v ethanol, 5% v/v hydrocarbon mixture as a denaturant) near the water table were conducted in two-dimensional physical models tightly packed with fine sands under varying water-table conditions. As the fuel migrated in the porous media following injection, the denaturant phase separated leaving a residual Light Non-Aqueous Phase Liquid (LNAPL) phase that occupied a region with a volume similar to that of an equal-sized spill of 100% LNAPL without ethanol. When the water table was raised, as may be expected following a catastrophic release that reaches groundwater, most of the ethanol-fuel mixture was mobilized and the vertical distribution of the generated LNAPL was increased. The lower boundary of the residual LNAPL was established during the initia...
This report accounts for Task 3 of DOE Contract No. AC01-81FE-05077. It reviews the developments in indirect coal liquefaction with emphasis on slurry-phase reactors and catalysis. This report also discusses topics related to indirect coal liquefaction research, such as analytical techniques in catalysis. The subjects covered in this report were selected by DOE. This report is the third and final task report of the three major tasks in this contract. The first task, ''Direct Coal Liquefaction Catalyst Development - Program Review and Research Perspectives'', was completed in November 1982. The second task, ''Review of Direct Coal Liquefaction by Slurry-Phase Catalysis'', was completed in September 1983. 47 refs., 66 figs., 50 tabs.
The cubic-tetragonal lattice transformation in A-15 compounds is described by an empirical model in which the density of states function near the Fermi energy is characterized by a two-parametric peak in addition to the constant part. Two types of peak splitting under tetragonal deformation are considered, leading to qualitatively different results about the phase transition. Results are given for the order parameter, the phase stability, the soft elastic modulus, and the paramagnetic spin susceptibility. Comparing with measurements of the magnetic susceptibility of V_3Si single crystals near the phase transition a better agreement is obtained for a twofold degenerate density of states peak than for a threefold degenerate one. (author).
The results of a computational scheme of Rose (a method for calculating solutions of parabolic equations with free boundary, Math. Comp., 14: 249-256(1960)) are compared with the known analytic solution of a single-phase Stefan problem with constant boundary temperature. Rose's scheme was implemented in FORTRAN on a DEC PDP-10. Computations were performed for Stefan numbers St = 0.01, 0.1, 1, 10, and 100. Three relative mesh sizes (..gamma.. = DT/(DX)/sup 2/ = 1/2, 1/6, and 1/25) were used. For each St, the relative mesh size had very little effect on accuracy. However, taking ..gamma.. = 1/25 resulted in dramatically increased computing time. The relative errors of temperature were large near the phase change front. 11 figures, 5 tables.
The CERL Code was developed to describe the solution chemistry of the water on the steam generating side of PWR reactors. It is designed to calculate the equilibrium species distribution resulting from the interaction of impurities, corrosion products, and additives in the aqueous solution. It calculates the extent of ion-ion interactions, the precipitation of insoluble species and the amount of solute that partitions into the vapor phase when some of the water evaporates. This knowledge of the bulk phase equilibrium distribution of species, especially the pH should be useful in describing the corrosion processes at the solid liquid boundary. The code does not calculate any changes in oxidation states or any rates of reaction. Therefore, it is incapable of calculating the actual corrosion rates. It is anticipated that it will be used as a subprogram of a larger program that will include the redox reactions and the rates of the reactions. The ...
MRT is able to demonstrate arteries while MR angiography can quantify blood flow by a non-invasive method. In the present paper blood flow measurements were carried out in four selected cases on the basis of phase mapping. In 3 patients with lesions in the pelvis or thigh, angiography was performed in order to localise the stenosis or occlusion and this was followed by qantitative blood flow measurements. The results showed that angiography may not always provide all necessary information concerning a haemodynamically significant stenosis. The method may also be used for quantifying blood flow in the renal arteries and that it has significant advantages over the colour Doppler method. (orig.).
CMSX-4 superalloy laser beam welds were investigated by transmission electron microscopy and atom probe field-ion microscopy (APFIM). The weld microstructure consisted of fine (10- to 50-nm) irregularly shaped {gamma}` precipitates (0.65 to 0.75 volume fraction) within the {gamma} matrix. APFIM compositions of the {gamma} and {gamma}` phases were found to be different from those in the base metal. Concentration profiles across the {gamma} and {gamma}` phases showed extensive variations of Cr, Co and Al concentrations as a function of distance within the {gamma} phase. Calculated lattice misfits near the {gamma}/{gamma}` interface in the welds are positive values compared to the negative values for base metal. (orig.).
Although hydrogen is the simplest of atoms, it does not form the simplest of solids or liquids. Quantum effects in these phases are considerable (a consequence of the light proton mass) and they have a demonstrable and often puzzling influence on many physical properties, including spatial order. To date, the structure of dense hydrogen remains experimentally elusive. Recent studies of the melting curve of hydrogen indicate that at high (but experimentally accessible) pressures, compressed hydrogen will adopt a liquid state, even at low temperatures. In reaching this phase, hydrogen is also projected to pass through an insulator-to-metal transition. This raises the possibility of new state of matter: a near ground-state liquid metal, and its ordered states in the quantum domain. Ordered quantum fluids are traditionally categorized as superconductors or superfluids; these respective systems feature dissipationless electrical currents or mass ...
Summary Background Sorafenib is an oral multikinase inhibitor that blocks cell proliferation via the ERK pathway and angiogenesis via the VEGF pathway. This phase II trial was conducted to determine the efficacy and tolerability of sorafenib for the treatment of patients with metastatic urothelial cancer (UC) who had not had prior chemotherapy for advanced disease. Patients and Methods Seventeen chemo-na?ve UC patients with adequate performance status and organ function were treated with sorafenib 400?mg twice daily on a continuous basis until progression or unacceptable toxicity. The primary endpoint was objective tumor response rate as measured by RECIST criteria. Secondary endpoints included rate of prolonged stable disease (>3?months), time to progression, median and 1?yr survival and ...
A one-dimensional, steady-state, two-phase direct methanol fuel cell (DMFC) model is developed to precisely investigate complex physiochemical phenomena inside DMFCs. In this model, two-phase species transport through the porous components of a DMFC is formulated based on Maxwell-Stefan multi-component diffusion equations, while capillary-induced liquid flow in the porous media is described by Darcy's equation. In addition, the model fully accounts for water and methanol crossover through the membrane, which is driven by the effects of electro-osmotic drag, diffusion, and the hydraulic pressure gradient. The developed model is validated against readily available experimental data in the literature. Then, a parametric study is carried out to investigate the effects of the operating temperat...
A high sensitivity, high bandwidth, two-color interferometer (1064 and 532 nm) has been tested on the Hawk pulsed power generator at the Naval Research Laboratory. The phase resolution is 10"-"5 waves with a rise time of 3 ns, a new capability for diagnosing plasmas, and neutrals in pulsed power experiments. The two-color feature is used to distinguish phase shifts from free (plasma) electrons and bound (neutral and ion) electrons. Simultaneous electron and neutral density measurements were demonstrated in a plasma opening switch (POS) experiment. The ability to measure small phase shifts with fast rise time were demonstrated in a plasma filled diode experiment. The high sensitivity and vibration isolation enable neutral gas distribution measurements from supersonic nozzles used in plasma radiation source experiments. Examples of these measurements and future applications are described. copyright 1997 American Institute of ...
A diffusion criterion of the crystal-liquid phase transition (PT) is proposed according to which the PT begins when the E d/ k b ratio reaches a threshold value of E d( s)/ k b T m, where E d is the self-diffusion energy, k B is the Boltzmann constant, T is the absolute temperature, and E d( s) is the self-diffusion energy in the solid phase at the melting temperature T m. It is shown that this criterion is a generalization of the Lindemann criterion and is applicable both to solids exhibiting normal melting and to those melting with a decrease in the specific volume. Based on the new criterion, it is possible to explain the relation T N < T m, where T N, is the crystallization onset temperature. The results of calculations of the T N/ T m ratio well coincide with experimental data.
The problem on the ratio between the instability of physical systems and tachyons is discussed. It is shown that the tachyons participation in the real physical process of the system rearranging does not contradict any principles. It is noted that the tachyons constitute the most significant element of the systems, identifying the instability relative to the phase transition into the stable state.
Neutron irradiation embrittlement of reactor pressure vessel (RPV) steels is one of the critical issues on aging management for long term operation of nuclear power plants. Mechanistic understanding of embrittlement is a key to accurate prediction of embrittlement, especially after long term operation where the mechanical test data are sparse. Since matrix hardening is the source of the embrittlement, we focus on matrix hardening of A533B bainitic pressure vessel steel. Bainitic matrix is composed of lath structure made by ferrite and carbides, therefore it is important to understand how this structure affects hardening behavior, and to understand irradiation response of each phase. As the typical dimension of lath structure of A533B is about one micron, nanoindentation technique is suitable for the estimation of hardening of each phase. MV ion accelerators were used for controlled irradiation because MeV ion irradiation can produce defects to ...
The US Department of Energy`s Pittsburgh Energy Technology Center (PETC) is actively pursuing the development and testing of coal-fired combustion systems for residential, commercial, and industrial market sectors. In response, MTCI initiated the development of a new combustor technology based on the principle of pulse combustion under the sponsorship of PETC (Contract No. AC22-83PC60419). The initial pulse combustor development program was conducted in three phases (MTCI, Development of a Pulsed Coal Combustor Fired with CWM, Phase III Final Report, DOE Contract No. AC22-83PC60419, November 1986). Phase I included a review of the prior art in the area of pulse combustion and the development of pulse combustor design concepts. It led to the conclusion that pulse combustors offer technical and base-of-operation advantages over conventional burners and also indicated favorable economics for replacement of oil- and gas-fired ...
The US Department of Energy's Pittsburgh Energy Technology Center (PETC) is actively pursuing the development and testing of coal-fired combustion systems for residential, commercial, and industrial market sectors. In response, MTCI initiated the development of a new combustor technology based on the principle of pulse combustion under the sponsorship of PETC (Contract No. AC22-83PC60419). The initial pulse combustor development program was conducted in three phases (MTCI, Development of a Pulsed Coal Combustor Fired with CWM, Phase III Final Report, DOE Contract No. AC22-83PC60419, November 1986). Phase I included a review of the prior art in the area of pulse combustion and the development of pulse combustor design concepts. It led to the conclusion that pulse combustors offer technical and base-of-operation advantages over conventional burners and also indicated favorable economics for replacement of oil- and ...