2,6-Diacetyl pyridine based ligand was synthesized by the reaction of 2,6-diacetyl pyridine with thiocarbohydrazide in presence of acetic acid. The coordination compounds with Cr(III) and Ni(II) metal ions having [Cr(L)X]X2 and [Ni(L)X]X compositions (where L=ligand and X=NO3^-, Cl^- and CH3COO^-) were synthesized and characterized by physicochemical and spectral studies. The studies like elemental analyses, molar conductance measurements, magnetic susceptibility measurements, IR, UV-Vis, NMR, mass and EPR reveal that the complexes are octahedral. The compounds were examined against the pathogenic fungal and bacterial strains like Alternaria brassicae, Aspergillus niger, Fusarium oxysporum, Xanthomonas compestris and Pseudomonas aeruginosa. A. niger causes the diseases Apergillosis and Oto...
With an objective to perform three-dimensional analysis with high accuracy in using the electromagnetic exploration method, characteristics in electromagnetic response were analyzed, and conditions for acquiring necessary data were discussed. The discussion defined a parameter called `response anomaly` which uses response from media to standardize response only from substances with abnormal resistivity. The receivers were located uniformly on the same plane, and the response anomaly was derived from electromagnetic response from each of the three horizontal and vertical components at each receiving point, which was expressed as a contour map. The parameter for the abnormal body was consisted of location and resistivity contrast with media. Discussions using the contour map were given on the response when these factors for the parameter were varied. As a result, it was found that the response anomaly appears in the form that reflects the abnormal body, and the response anomaly of the ...
Recent earthquake disasters have revealed the importance of countermeasures against soil Liquefaction in seismic design. In particular, the 1995 Hyogoken Nanbu earthquake caused several types of severe damages to pile foundations. This paper describes an analysis method for soil liquefaction using simple parameters such as SPT-N values and seismic response analyses for the pile-supported structure to consider soil-structure interaction effects and soil non-linearity using a modified Penzien model. It is important to find a way to determine the region of surrounding soil whose behavior is identical to that of piles. This paper adopts the thin layer element method to systematically determine the volume of the surrounding soil. The responses of pile-supported structure are similar, whether soil liquefaction and nonlinearity of pile are considered or not. However, the bending moment of pile become large as to soil liquefaction, and small as to nonlinearity of pile. (author)