Intensification of Harmonic Spontaneous Radiation with a Novel Undulator
We have calculated the on-axis spectrum of spontaneous radiation emitted by an electron moving along a planar undulator that has a magnetic profile along the axis that approximates a square wave. (This could be obtained in practice by driving a ferromagnetic undulator into saturation by excessive current in the windings.) We find considerable enhancement of the harmonic radiation spectrum. We compare the harmonic power emitted by an electron moving through an undulator having a sine-wave field profile with the radiation emitted from an undulator having a square-wave profile; the latter is approximated by the first three Fourier components of the undulator magnetic field profile along the axial direction. Examples are computed for 40MeV electrons taking K < 1, for spontaneous radiation emitted along the axis of the system. The emission at harmonics f > 1 is greatly enhanced for the approximate ...
1998-11-01
Intensification of harmonic spontaneous radiation with a novel undulator
International Nuclear Information System (INIS)
We have calculated the on-axis spectrum of spontaneous radiation emitted by an electron moving along a planar undulator that has a magnetic profile along the axis that approximates a square wave. (This could be obtained in practice by driving a ferromagnetic undulator into saturation by excessivecurrent in the windings.) We find considerable enhancement of the harmonic radiation spectrum. We compare the harmonic power emitted by an electron moving through an undulator having a sine-wave field profile with the radiation emitted from an undulator having a square-wave profile; the latter is approximated by the first three Fourier components of the undulator magnetic field profile along the axial direction. Examples are computed for 40MeV electrons taking K1 is greatly enhanced for the approximate square-wave magnetic profile: the ratio of the power emitted at f=5 by the square-wave undulator to that of the sine-wave undulator ...
1999-07-01
Improvement of spatial resolution in the longitudinal direction for isotropic imaging in helical CT
Energy Technology Data Exchange (ETDEWEB)
Experiments were conducted to confirm the isotropic spatial resolution of multislice CT with a 0.5 mm slice thickness. Isotropic spatial resolution means that the spatial resolution in the transaxial plane (X-Y plane) and that in the longitudinal direction (Z direction) are equivalent. To obtain point spread function (PSF) values in the X-Y-Z directions, three-dimensional voxel data were obtained by helical scanning of a bead phantom. The modulation transfer function (MTF) values were then obtained by three-dimensional Fourier transform of the PSF. Evaluation of the spatial resolution in the X-Y-Z directions by the MTF values showed that the spatial resolution in the Z direction does not depend on the reconstruction kernel used. It was also found that the spatial resolution in the Z direction, as compared with that in the X-Y plane, is superior with the standard kernel for the abdomen and is inferior with the high-definition kernel for the ...
2007-02-07
UK PubMed Central (United Kingdom)
The ability of bovine polymorphonuclear leukocytes (PMN) to phagocytose fluorescent beads in vitro was studied using flow cytometry. The effects of varying laboratory conditions (bead:PMN ratio, length...Full Text Available
2001-01-01
Refractometry of organosilica microspheres
The refractive index of novel organosilica (nano/micro)material is determined using two methods. The first method is based on analysis of optical extinction efficiency of organosilica beads versus wavelength, which is obtained by a standard laboratory spectrometer. The second method relies on the measurable trapping potential of these beads in the focused light beam (laser tweezers). Polystyrene beads were used to test these methods, and the determined dispersion curves of refractive index values have been found accurate. The refractive index of organosilica beads has been determined to range from 1.60-1.51 over the wavelength range of 300-1100 nm.
2007-01-01
UK PubMed Central (United Kingdom)
Two problems of Fourier analysis on GL(n,R) are studied. The first concerns the decomposition of the additive Fourier operator in terms of the group representation...Full Text Available
1970-01-01
The wash-off of dyeings using interstitial water part 1: Initial studies
British Library Electronic Table of Contents (United Kingdom)
The extent to which a novel wash-off process using polyamide beads removed five different types of dye from three different types of fibre was similar to that achieved using conventional aftertreatments. Whilst bead wash-off and the conventional aftertreatments were of similar duration and temperature, conventional aftertreatment employed a 10:1 or 20:1 liquor ratio whereas bead wash-off used a < 1:1 liquor ratio. As vagrant dye was adsorbed onto the bead material during wash-off, the low amount of wastewater generated contained little residual dye, thereby offering the potential of reduced environmental and cost benefits. Bead wash-off did not impair the fastness of two non-metallised acid dyes on nylon 6,6 to washing at 60 ?C.
2011-01-01
British Library Electronic Table of Contents (United Kingdom)
Laser welding of AISI 904 L super austenitic stainless steel using a diffusion cooled slab 3.5kW CO2 laser and employing two different shielding gases, namely argon and helium, was carried out. The laser weld bead profile depends on various parameters such as beam power (BP), travel speed (TS) and focal position (FP) of the laser spot. These parameters have to be selected suitably to obtain the desirable output. The cross sectioned area of the bead profiles measured using an optical microscope to determine the bead width and depth of penetration. X-ray diffraction used for phase identification confirmed that the weld structure was fully austenitic and dendritic. Hardness was observed to increase in the weld bead with respect to the parent metal and it was related to the microstructural ref...
2010-01-01
Analysis of even harmonics generation in an isolated electric power system
British Library Electronic Table of Contents (United Kingdom)
Harmonics bred from loads are mainly odd order because the current waveforms have half-wave symmetry. Since the even harmonics are negligibly small, they generally are not measured in electric power systems. However, even harmonics were measured at a 500/275/154 kV substation in Hokuriku Electric Power Company after a transmission line fault was corrected. The even harmonics caused malfunctions of protective digital relays because the relays used 4th harmonics at the input filter as the automatic supervisory signal. This paper describes mechanisms of generation of the even harmonics by comparing the measured waveforms with the ATP-EMTP simulation results. Analysis of these results has clearly shown that there are three different mechanisms of generation of even harmonics. The first mechani...
2009-01-01
Microrheological Studies of Regenerated Silk Fibroin Solution by Video Microscopy
We have carried out studies on the rheological properties of regenerated silk fibroin (RSF) solution using video microscopy. The degummed silk from the Bombyx mori silkworm was used to prepare RSF solution by dissolving it in calcium nitrate tetrahydrate-methanol solvent. Measurements were carried out by tracking the position of an embedded micron-sized polystyrene bead within the RSF solution through video imaging. The time dependent mean squared displacement (MSD) of the bead in solution and hence, the complex shear modulus of this solution was calculated from the bead's position information. An optical tweezer was used to transport and locate the bead at any desired site within the micro-volume of the sample, to facilitate the subsequent free-bead video analysis. We present here the results of rheological measurements of the silk polymer network in solution over a frequency ...
2007-01-01
Automated bead-positioning system for measuring impedances of R-F cavity modes
Energy Technology Data Exchange (ETDEWEB)
We describe a fully automated bead puller system which uses stepping motors to position the bead, and an HP-8510 network analyzer to measure the resulting frequency shifts, both devices being under computer control. Longitudinal motion of the bead is used for measurement of cavity shunt impedance. In addition, azimuthal scans at fixed longitudinal position aid in determining the multipole character of higher-order modes. High sensitivity/accuracy is made possible by measuring phase shifts at the unperturbed resonant frequencies (rather than frequency shifts themselves), thereby permitting averaging factors of > 500 with only modest increases in data acquisition time. Sample measurements will be presented. A comprehensive analysis of the experimental results is presented in an accompanying paper.
1993-05-01
Appropriate welding conditions of temper bead welding for SQV2A reactor pressure vessel steel
International Nuclear Information System (INIS)
Feb 2006 p. 80-84 Japan Mizuno, R. Matsuda, F. Japan Power Engineering
2006-02-01
Harmonic decomposition of orbit data for multipole analysis
Energy Technology Data Exchange (ETDEWEB)
This paper describes a simple analysis procedure that transforms a set of beamline orbit data into a set of harmonic orbits of first, second, and third order or higher. Each harmonic orbit can be studied individually to identify errors of the specific order with minimum interference from other orders. Effectively these are orbits caused by kicks, due to harmonic errors, propagated through linear lattice. Examples from accelerator study will be presented. The application and inherent limitations of this analysis procedure are discussed.
2005-05-01
Third harmonic lasing in a storage ring free-electron laser
International Nuclear Information System (INIS)
We report the first experimental achievement of a storage ring free-electron laser (FEL) oscillation on the third harmonic in the near-infrared region. The FEL gain was evaluated as 0.029% per mA. The measured linewidth of the third-harmonic FEL was less than that of the fundamental FEL, and the measured pulse width of the third-harmonic FEL was wider than that of the fundamental FEL. A higher-harmonic FEL should be developed not only to enhance the wavelength region of the FEL but also to vary the characteristics of an FEL micropulse. (author)
2010-09-01
Evaluations of half-bead weld repair procedures with thick-wall pressure vessels
The results of research on the evaluation of the half-bead weld repair method for use on nuclear reactor components are reviewed from data obtained on thick-section test pieces and intermediate-size pressure vessels. Material properties, the magnitude of residual stresses and the structural behavior of flawed pressure vessels are being obtained to determine the adequacy of the weld repair method for application in thick-section components.
1978-01-01
Energy Technology Data Exchange (ETDEWEB)
Temperature and concentration profiles of CO in a laminar, axisymmetric, premixed methane-air Bunsen flame are measured using line-of-sight diode laser absorption spectroscopy and computer tomographic (CT) reconstruction. Absorption spectra for P(20) (v=2<-1) and P(27) (v=1<-0) vibrotational transitions of CO were measured at 21 evenly spaced positions over a 1.33 cm span for a 1.3 cm radius flame. CT reconstruction algorithm was based on Fourier convolution. The tomographically reconstructed normalized transmission profiles derived from absorption spectra, in conjunction with a quantum mechanical model for vibrotational behavior of CO, yielded both temperature and concentration profiles. The Bunsen flame had 3 distinct zones: an inner rich-premixed flame zone, an outer non-premixed flame zone and an unburnt core region. The reconstructed temperature profile showed that the core region temperature was close to ambient and rapidly increased to adiabatic flame ...
1993-12-01
Influence of anchor behaviour on the earthquake response of liquid storage tanks
International Nuclear Information System (INIS)
The dynamic response of thin liquid storage tanks to earthquakes is a very complicated phenomenon, because it can be highly non linear. Among others, one can meet material and geometric non linearities of the tank shell leading eventually to static or dynamic buckling non linear behavior of anchor bolts, contact non-linearities due to the uplift of the tank base and to the unilateral character of the fluid pressure on the shell and high amplitude fluid oscillations. Moreover, linear or non linear soil structure interaction affects considerably the response of the fluid structure system under consideration. In this paper we focus attention on problems related only to the base uplift and anchors plastification. We study a tank similar to the Hualien project tank, but we neglect the soil structure interaction. The studied tank is representative of medium height to radius ratio ratio tanks with relatively thick bottom plate. The contact is simulated via a simple discrete penalty method in ...
International Nuclear Information System (INIS)
The present communication deals with the synthesis, single crystal growth and characterization of a new nonlinear optical material L-proline strontium chloride monohydrate (L-PSCM). Single crystals have been grown using the slow solvent evaporation technique. Single crystal XRD analysis confirmed that the crystal belongs to the orthorhombic structure with lattice parameter a=6.6966(3) A, b=12.4530(5) A, c=15.2432(5) A and space group P2_12_12_1. Presence of various functional groups in L-PSCM and protonation of the ions were confirmed by Fourier transform infrared spectroscopy (FT-IR) analysis. The melting point of the single crystal was found to be 126 "oC using DSC. Ultraviolet-visible spectral analyses showed that the crystal has low UV cut-off at 226 nm combined with very good transparency of 90% in a wide range. The optical band gap was estimated to be 5.82 eV. Capacitance and dielectric-loss measurements were carried out at different temperatures in the ...
2011-01-01
Nonlinear response of superconductors to alternating fields and currents
This report discusses the following topics on superconductivity: nonlinearities in hard superconductors such as surface impedance of a type II superconductimg half space and harmonic generation and intermodulation due to alternating transport currents; and nonlinearities in superconducting weak links such as harmonic generation by a long Josephson Junction in a superconducting slab.
1997-10-08
Optimum plasma conditions for the efficient high-order harmonic generation in platinum plasma
International Nuclear Information System (INIS)
We studied the optimum plasma conditions that are required for efficient high-order harmonic generation in platinum plume. Harmonics up to the 49th order (?=16.32 nm) are analyzed under various conditions of laser-plasma interaction. Time-resolved ultraviolet spectra of platinum plasma at both optimum and nonoptimum conditions of harmonic generation are presented. We calculated the ionization states of the plasma, free electron density, and singly charged ion density at different prepulse intensities and compared them with experimental results.
2007-06-01
Operating Manual for Single-Shot Autocorrelator
... pulses by a 50/50 beamsplitter and recombined in space and in time inside a wafer of KDP crystal which generates a second harmonic of the ...
1993-01-01
INTERACTIONS OF COHERENT OPTICAL RADIATION WITH ...
... and flashtube. Unfortunately, we had insufficient laser intensity to use the harmonic from a KDP crystal as a monitor. This ...
1964-08-31
Augmented-plane-wave calculation of indirect-exchange matrix elements for gadolinium
International Nuclear Information System (INIS)
(15 Dec 1974). United States Harmon, BN Freeman, AJ Ames
International Nuclear Information System (INIS)
An explicite PN solution of the multi-dimensional homogeneous neutron transport equation is given by expanding the angular flux into a series of geometry-independent spherical harmonics operators. An algorithm is developed for representing the spherical harmonic operators in orthogonal curvilinear coordinates. The general formulae are applied to two-dimensional spherical geometry; detailed P3 formulae are given. (orig.).
Second harmonic generation of copper-vapor pulsed laser radiation
Energy Technology Data Exchange (ETDEWEB)
An experimental study of second harmonic generation in a copper-vapor pulsed laser with an ADP crystal is presented. The ratio of the conversion into the second harmonic is found to depend on the average power of the exciting radiation. The maximum conversion ratio was 8.5%. Thermal self-defocusing is the main obstacle to obtaining high average powers at the double frequency.
1980-08-01
Evaluation of solid phase system in radioimmunoassay of triiodothyronine (Preprint No. RA.24)
International Nuclear Information System (INIS)
This paper describes the evaluation of antibody coated polystyrene beads using "1"2"5I-labelled T_3 ("1"2"5I-T_3). (author).
Bacterial Fouling in a Model Core System
UK PubMed Central (United Kingdom)
We have used a sintered glass bead core to simulate the spaces and surfaces of reservoir rock in studies of the bacterial plugging phenomenon that affects waterflood oil recovery operations. The passage...Full Text Available
1985-03-01
Viral RNA testing and automation on the bead-based CBNE detection microsystem.
Energy Technology Data Exchange (ETDEWEB)
We developed prototype chemistry for nucleic acid hybridization on our bead-based diagnostics platform and we established an automatable bead handling protocol capable of 50 part-per-billion (ppb) sensitivity. We are working towards a platform capable of parallel, rapid (10 minute), raw sample testing for orthogonal (in this case nucleic acid and immunoassays) identification of biological (and other) threats in a single sensor microsystem. In this LDRD we developed the nucleic acid chemistry required for nucleic acid hybridization. Our goal is to place a non-cell associated RNA virus (Bovine Viral Diarrhea, BVD) on the beads for raw sample testing. This key pre-requisite to showing orthogonality (nucleic acid measurements can be performed in parallel with immunoassay measurements). Orthogonal detection dramatically reduces false positives. We chose BVD because our collaborators (UC-Davis) can supply samples from ...
2008-09-01
Pseudospin symmetry and the relativistic harmonic oscillator
A generalized relativistic harmonic oscillator for spin 1/2 particles is studied. The Dirac Hamiltonian contains a scalar, $S$, and a vector, $V$, quadratic potentials in the radial coordinate, as well as a tensor potential, $U$, linear in $r$. Setting either or both combinations $\\Sigma=S+V$ and $% \\Delta=V-S$ to zero, analytical solutions for bound states of the corresponding Dirac equations are found. The eigenenergies and wave functions are presented and particular cases are discussed, devoting a special attention to the non-relativistic limit and the case $\\Sigma=0$, for which pseudospin symmetry is exact. We also show that the case $U=\\Delta=0$ is the most natural generalization of the non-relativistic harmonic oscillator. The radial node structure of the Dirac spinor is studied for several combinations of harmonic oscillator potentials, and that study allows us to explain why nuclear intruder levels cannot be ...
2004-01-01
On the Approach to Spherical Harmonics by Maxwell, Thomson and Tait
We present a unified self-consistent review of the approach to spherical harmonics developed in the second half of the 19th century by Maxwell and by Thomson and Tait. We remark how this spherical coordinate-free approach straightforwardly leads to physically very important results of the theory of solid and surface harmonics which become rather tedious to work out when using spherical coordinates and associated Legendre functions. These results include, among others, the addition theorem, spherical wave expansions, the construction of the standard set of normalized spherical harmonics, Y_lm - together with their rotational properties-, and recursion relations. We provide new proofs for Maxwell's theorem, the addition theorem and Hobson's theorem, respectively, using in the latter some elementary notions of the symbolic techniques proper of the theory of invariants. Also, we give an approach based on compact vector methods ...
2008-01-01
Energy Technology Data Exchange (ETDEWEB)
In this report the effects of harmonics in marine power systems is discussed and a comparison is given between the most typical converter types, including pulse width modulated drives, load commutated inverters and cycloconverters. The effect of harmonic distortion on the power system equipment and loads is first briefly discussed. Special attention is given to the circumstances in the low voltage distribution system, where general load equipment is connected. In addition to the total harmonic distortion the effect of voltage deviation to the supply quality is also considered. The origin of harmonics in the load currents of the three converter types is then considered. The differences between the converters are outlined, and the most typical spectra are presented. The possible means for reducing the harmonic distortion are also studied. The solutions considered are the increasing of ...
1996-11-01
UK PubMed Central (United Kingdom)
BackgroundFourier Transform Infrared Imaging (FTIRI) is used to investigate the amide anisotropies at different surfaces of a three-dimensional cartilage or tendon block. With the...Full Text Available
Sidelobe Suppression in an Acousto-Optic Filer with a Raised ...
... Abstract : The acousto-optic filter (AOF) is ... for large switch networks. ... FOURIER TRANSFORMATION, OPTICAL SWITCHING, SURFACE ACOUSTIC ...
1992-04-01
International Nuclear Information System (INIS)
An optical klystron is built in the 800 MeV electron storage ring at University of Science and Technology of China for harmonic super-radiation generation. In single bunch operation mode the repetition rate of the spontaneous radiation pulses is about 4.533 MHz, and the repetition rate of the seed laser pulses is about 3 Hz, while the radiation pulse duration is 300 ps. For measuring harmonic radiation a high on/off ratio ICCD is used as an optical switch to reject spontaneous radiation pulses of high repetition rate
2001-07-01
Confocal Imaging of Biological Tissues Using Second Harmonic Generation
Energy Technology Data Exchange (ETDEWEB)
A confocal microscopy imaging system was devised to selectively detect Second harmonic signals generated by biological tissues. Several types of biological tissues were examined using this imaging system, including human teeth, bovine blood vessels, and chicken skin. All these tissues generated strong second harmonic signals. There is considerable evidence that the source of these signals in tissue is collagen. Collagen, the predominant component of most tissues, is known to have second order nonlinear susceptibility. This technique may have diagnostic usefulness in pathophysiological conditions characterized by changes in collagen structure including malignant transformation of nevi, progression of diabetic complications, and abnormalities in wound healing.
2000-03-06
International Nuclear Information System (INIS)
The spherical harmonic analysis of cosmic ray neutron data from the worldwide network neutron monitor stations during the years 1966 to 1969 was carried out. The second zonal harmonic component obtained from the analysis corresponds to the Pole-Equator anisotropy of the cosmic ray neutron intensity. Such an anisotropy makes a semiannual variation. In addition to this, it is shown that the Pole-Equator anisotropy makes a variation depending on the interplanetary magnetic field (IMF) sector polarities around the passages of the IMF sector boundary. A mechanism to interpret these results is also discussed.
1985-08-01
Energy Technology Data Exchange (ETDEWEB)
Safety in general and harmonization of International Maritime Organization rules on mobile offshore drilling rig operation in particular are discussed. The improvement of the industry's safety record is also discussed.
1985-02-01
Preliminary representation of world population by spherical harmonics.
UK PubMed Central (United Kingdom)
The geographical arrangement of people on the surface of the earth is approximated by a mathematical equation of 361 terms. This is a convenient form for comparison with other distributions and for...Full Text Available
1992-07-15
Harmonized Tariff Schedule Codes Flagged with Prior Notice ...
... 3004505040***, MEDICAMENTS, DOSED, VITAMINS, MULTIPLE, OTHER COMBINATIONS, FD3***. 3104100000**, CARNALLITE, SYLVITE AND OTHER CRUDE POTASSIUM SALTS, FD3**. ...
International Nuclear Information System (INIS)
The aim of the study is to prepare ionic exchangers using the polymerization of unsaturated polyster with monomeric styrene units in a ratio of 60%: 40% respectively. The type of method involved in this preparation, is called An Emulsion Polymerization. Such type of polymerization was carried out by two techniques: chemical and irradiation techniques. The first techniques requires the formation of free radical monomers by use of methyl Ethy Ketone Peroxide capable of decomposing into free radicals upon heating, while the other technique involves the use of gamma rays (using Co-60 source) capable of activating monomers towards free radical formations. A number of very effective chemical parameters and physical factors were used and investigated throughout the reactions such as: dispersant matrix, viscosity, rate of mixing, and irradiation dose. Besides, the study has included the study of the rate of Resin Beads Swelling which is thought to be another important part ...
3087-01-01
Energy Technology Data Exchange (ETDEWEB)
Aqueous radioactive high-level waste slurries are combined during processing steps that ultimately produce a stable borosilicate glass waste form. Chemically treated waste slurries are combined with each other and with glass frit-water slurries to produce the melter feed. Understanding the evolution of the rheological properties of the slurries is an important aspect of removing and treating the stored waste. To a first approximation, combinations of colloidal waste slurry with {approx}0.1-mm mean diameter glass frit or glass beads act in an analogous matter to slurries of spherical beads in Newtonian liquids. The non-Newtonian rheological properties of the waste slurries without frit, however, add complexity to the hydrodynamic analysis. The use of shear rate dependent apparent viscosities with the modified Einstein equation was used to model the rheological properties of aqueous frit-waste slurries.
2009-09-02
British Library Electronic Table of Contents (United Kingdom)
A concentric reducer tube, which was a part of the top exit roughing hydraulic descaler in a hot strip mill failed prematurely under working pressure. A detailed metallurgical investigation comprising physical examination, optical microscopy, scanning electron microscopy, and electron probe microanalysis was carried out to find out the genesis of the failure. Physical examination revealed cracks located symmetrically around the circumference of the tube that ran along its full length, up to the weld beads at both ends. Optical microscopy of etched samples revealed a banded ferrite-pearlite structure and the existence of forging folds near the change-in-section(160? fillets). Cracks were found to initiate from these forging folds. No structural abnormalities were found in the weld beads and...
2007-01-01
Energy Technology Data Exchange (ETDEWEB)
The influence of common welding defects such as internal under-cut, incomplete penetration of the root bead, internal concavity and hollow bead have been evaluated in a sour environment. Tests were performed on samples cut from actual pipeline welds. The individual defects were subjected to slow strain rate testing. The samples were then examined by metallography, scanning electron microscopy, and hardness testing. It was established that a threshold stress intensity exists for sulphide stress cracking. The test results were compared to those obtained from samples of the weld and pipe which did not contain any defects. This comparison indicated that the metallurgical variations associated with the presence of a weld are the main factor for sulphide stress cracking rather than any specific defects or geometry. 5 tabs., 9 figs.
1992-12-31
Biosorption of uranium (VI) by immobilized Aspergillus fumigatus beads
Energy Technology Data Exchange (ETDEWEB)
Biosorption of uranium (VI) ions by immobilized Aspergillus fumigatus beads was investigated in a batch system. The influences of solution pH, biosorbent dose, U (VI) concentration, and contact time on U (VI) biosorption were studied. The results indicated that the adsorption capacity was strongly affected by the solution pH, the biosorbent dose and initial U (VI) concentration. Optimum biosorption was observed at pH 5.0, biosrobent dose (w/v) 2.5%, initial U (VI) concentration 60 mg L{sup -1}. Biosorption equilibrium was established in 120 min. The adsorption process conformed to the Freunlich and Temkin isothermal adsorption models. The dynamic adsorption model conformed to pseudo-second order model.
2010-06-15
Shaping pulses using frequency conversion with a modulated picosecond free electron laser
Energy Technology Data Exchange (ETDEWEB)
Computer simulations and experiments indicate that we can shape the infrared picosecond pulses of the Mark III FEL in amplitude, frequency, and phase. Strongly modulated fundamental and second harmonic pulses have been generated by operating the Mark III FEL in the regime of strong sideband growth. In this paper, we present the results of simulations and experiments for second harmonic generation with fundamental inputs from 2 to 3 {mu}m.
1995-12-31
Real time closed orbit correction system
Energy Technology Data Exchange (ETDEWEB)
We describe a global closed orbit feedback experiment, based upon a real time harmonic analysis of both the orbit movement and the correction magnetic fields. The feedback forces the coefficients of a few harmonics near the betatron tune to vanish, and significantly improves the global orbit stability. We present the results of the experiment in the UV ring using 4 detectors and 4 trims, in which maximum observed displacement was reduced by a factor of between 3 and 4. 4 refs., 3 figs.
1989-01-01
Nonlinear effect in vibroseis data; Vibroseis kiroku ni oite mitomerareru hisenkei koka
Energy Technology Data Exchange (ETDEWEB)
This paper describes nonlinear effect recognized in Vibroseis data. Harmonics is a wave of frequency in integer factors generated in association with basic sweep vibrated by Vibroseis. Harmonics is generated because vibration in the vicinity of seismic source contains nonlinear terms. Seismic exploration using the reflection method often discusses propagation of seismic waves hypothesized as a linear phenomenon. Vibroseis data analysis, however, requires evaluation of the effect of the harmonics on accuracy. Vibroseis investigation measures may be taken by eliminating n-order harmonics by using the phase control method, and generating seismic source sweep in which the phase is shifted by 180/(n-1) each time in order to leave the basic sweep. Methods to increase the sweep length include a method to expel strain to a location outside the range of the subject travel time. Up-sweep (a sweep changing from ...
1997-05-27
UK PubMed Central (United Kingdom)
The purpose of this prospective study was to compare two different milk preparation methods to assay for the presence of Mycobacterium bovis by PCR. Detection by a C18-carboxypropylbetaine...Full Text Available
1998-08-01
International Nuclear Information System (INIS)
The purpose of this study was to evaluate the safety and efficacy of TACE with microspheres preloaded with doxorubicin in unresectable intrahepatic cholangiocarcinoma (UCH). Twenty patients with UCH were observed; 9 refused, preferring other palliative care or chemotherapy, and 11 agreed to be treated with one or more cycles of DC beads loaded with doxorubicin (100-150 mg) in a TACE procedure between February 2006 and September 2007. A total of 29 individual TACE procedures were performed. Follow-up imaging was performed on all patients before, immediately after, and 4 weeks after each TACE procedure to evaluate the response and need for further treatment. Each patient received i.v hydration, antibiotics, and medications against nausea and pain before TACE. Survival rate was calculated using Kaplan-Meier survival curve. A response rate of 100% followed RECIST criteria was observed. Eight of eleven patients are alive, with a median survival of 13 months. TACE was ...
2008-09-01
The forward modeling and reverse time migration of seismic wave field in complex medium
Energy Technology Data Exchange (ETDEWEB)
The space derivation term of a wave equation is accurately calculated using Fourier transform method, and the wave equation only relating to time derivative in time-space domain is derived. Solving this equation with the aid of central difference method brings the numerical recursion formula for forward modeling or reverse time migration of seismic wave field in the medium in which seismic velocity varies. The key to this method lies in introducing two auxiliary wave fields relating to velocity and spacial frequency of Fourier transform respectively after multi-dimensional Fourier transform respectively after multi-dimensional Fourier transform of space vector is made. Theoretically, this method is suitable to the forward modeling and migration of seismic wave field in complex area where seismic velocity and structure shape vary arbitrarily. Theoretical results proved this method satisfactory.
1988-01-01
Optical Spectroscopy for Noninvasive Monitoring of Stem Cell Differentiation
UK PubMed Central (United Kingdom)
There is a requirement for a noninvasive technique to monitor stem cell differentiation. Several candidates based on optical spectroscopy are discussed in this review: Fourier transform infrared (FTIR)...Full Text Available
2010-01-01
Fourier duality as a quantization principle
Energy Technology Data Exchange (ETDEWEB)
The Weyl-Wigner prescription for quantization on Euclidean phase spaces makes essential use of Fourier duality. The extension of this property to more general phase spaces requires the use of Kac algebras, which provide the necessary background for the implementation of Fourier duality on general locally groups. Kac algebras - and the duality they incorporate are consequently examined as candidates for a general quantization framework extending the usual formalism. Using as a test case the simplest non-trivial phase space, the half-plane, it is shown how the structures present in the complete-plane case must be modified. Traces, for example, must be replaced by their noncommutative generalizations - weights - and the correspondence embodied in the Weyl-Wigner formalism is no more complete. Provided the underlying algebraic structure is suitably adapted to each case, Fourier duality is shown to be indeed a very powerful ...
1996-08-01
Investigation by physical methods of the possible role of telomeres in DNA in aging process
The interaction energies between the different types of bases of a single strand of DNA molecule have been calculated. Using these original values of energies the harmonic behavior of a number of base patterns of DNA has been studied. In view of the great interest aroused by the discovery of the role of the telomere segment of the DNA in the replication process and its possible link with the aging process, we have investigated, with simple models, the harmonic behavior of the telomeric pattern of bases as well as the thermodynamic response in the biological system. With these results a conclusion on the probable role of the telomeric pattern on aging has also been drawn. Here the calculated values of harmonic frequencies of the telomeric pattern of bases and of other possible patterns show that the telomeric pattern is associated with the highest vibrational frequency among all patterns of base combinations at the ...
2003-01-01
The analysis of coupled heat and particle transport in Tokamaks by means of Fourier transform
Energy Technology Data Exchange (ETDEWEB)
A method to deduce the 2 x 2 transport matrix for coupled heat and particle transport in Tokamaks is proposed. The method applies to perturbative experiments, and is based on a Fourier transform of the measured signals of temperature and density. By analyzing different linear combinations of temperature and density, the eigenvectors and eigenvalues of the transport matrix are determined. The method is tested for a number of illustrative cases using simulated data, and the sensitivity to noise on the signals is evaluated. (author).
1992-04-01
Quantum Discrete Fourier Transform in an Ion Trap System
International Nuclear Information System (INIS)
We propose two schemes for the implementation of quantum discrete Fourier transform in the ion trap system. In each scheme we design a tunable two-qubit phase gate as the main ingredient. The experimental implementation of the schemes would be an important step toward complex quantum computation in the ion trap system.
2007-06-15
Energy flux operator, current conservation and the formal Fourier's law
International Nuclear Information System (INIS)
By revisiting previous definitions, we show that one can define an energy current operator that satisfies the continuity equation for a general Hamiltonian in one dimension. This expression is useful for studying electronic, phononic and photonic energy flow in linear systems and in hybrid structures. The definition allows us to deduce the necessary conditions that result in current conservation for general-statistics systems. The discrete form of the Fourier's law of heat conduction naturally emerges in the present definition.
2009-01-16
Cesium ion desorption ionization with Fourier transform mass spectrometry
International Nuclear Information System (INIS)
Cesium ions (Cs"+) are used for the production of the feed ions necessary to obtain Fourier transform mass spectra (FTMS). The molecule chosen for the initial study of this Cs"+ desorption ionization (DI-FTMS) was vitamin B-12 because of its nonvolatile, thermally labile character. 21 references.
Utility activities that create power quality problems
Energy Technology Data Exchange (ETDEWEB)
Power quality problems are caused by activities normal to utility operations such as maintenance outages and capacitor switching or events that are abnormal such as lightning strikes and equipment failures. Disconnection and reconnection of transmission lines and transformers can cause switching surges, and are more severe on extra high voltage transmission lines than high voltage lines. Capacitor switching can cause transients and harmonics that may affect sensitive equipment, and are the source of 3rd, 5th, 7th and 9th harmonics in the hundreds of hertz ranges. Overload, sudden loss of generating capacity and transmission line faults are typical problems affecting system stability. Fault interruptions and reclosings can cause surges in the distribution system, and lightning strikes may cause voltage surges or dips due to arrester sparkover. Blackouts, brownouts, voltage fluctuations, travelling wave overvoltages, capacitor restrikes, ...
1992-02-01
Energy Technology Data Exchange (ETDEWEB)
The A(..pi../sup +/,/sup 3/He)B reaction near threshold is studied in a model where the pion is absorbed by an /sup 4/He constituent of the target nucleus. The predictions of this model using harmonic oscillator cluster wave functions agree semi-quantitatively with the experimental data on the inverse reaction.
1982-03-10
NSF/Tokyo Report: MITI's Polymer Project
... Highly-Functional Materials" was launched in JFY1996 under the New Materials field. This project was ... Bio-mimetic materials" (1) Advanced stimuli responsive materials (2) Harmonized molecular materials ...
Efficient Second Harmonic Conversion of Broadband High ...
... Rev. Lett., vol. 42, no. 24, pp. 1625-1628, June 1979. 3 ... Trans. Plasma Science, vol. PS-10, no. 1, pp. 55-58, March 1982. ...
1989-06-23
Effects of introducing low-frequency harmonics in the perception of vocoded telephone speech1
UK PubMed Central (United Kingdom)
Several studies have demonstrated that telephone use presents a challenge for most cochlear implant (CI) users, and this is attributed mainly to the narrow bandwidth (300–3400 Hz) introduced...Full Text Available
2010-09-01
UK PubMed Central (United Kingdom)
The temporal fine structure (TFS) of sound contributes significantly to the perception of music and speech in noise. The evaluation of new strategies to improve TFS delivery in cochlear implants (CIs)...Full Text Available
2008-03-01
Nonlinear vibrations and chaos in electrostatic torsional actuators
British Library Electronic Table of Contents (United Kingdom)
Electrostatic torsional micro-mirrors have wide spread use in different industries for diverse purposes. This paper investigates the development of superharmonics and chaotic responses in electrostatic torsional micro-mirrors near the pull-in condition. Appearance of nonlinear phenomena is investigated in models accounting for and disregarding the coupling of torsional and flexural deflections. Analysis of the system response to step and harmonic excitation reveals the appearance of DC and AC symmetry breaking. Increasing the amplitude of harmonic excitation, the response in the form of distinct superharmonics changes to a broad band response, where there is loss of periodicity and the response becomes chaotic. Accounting for flexural deflections in coupled model reduces the voltage thresh...
2011-01-01
Multi-megajoule Nd: glass fusion laser design
Energy Technology Data Exchange (ETDEWEB)
New technologies make multi-megajoule glass lasers economically feasible. Laser architectures using harmonic switchout, target plane holographic injection, phase conjugation, continuous apodization and higher amplifier efficiencies have been devised. A plan for a multi-megajoule laser which can be built for an acceptable cost relies on manufacturing economies of scale and the demonstration of the new technologies presented here. These include continuous pour glass production, rapid harmonic crystal growth, switching of large blocks of power using larger capcaitors packed more economically and by using large identical parts counts.
1986-04-04
Harmonic oscillator representation in the theory of scattering and nuclear reactions
Energy Technology Data Exchange (ETDEWEB)
The following questions, concerning the application of the harmonic oscillator representation (HOR) in the theory of scattering and reactions, are discussed: the formulation of the scattering theory in HOR; exact solutions of the free motion Schroedinger equation in HOR; separable expansion of the short range potentials and the calculation of the phase shifts; `isolated states` as generalization of the Wigner-von Neumann bound states embedded in continuum; a nuclear coupled channel problem in HOR; and the description of true three body scattering in HOR. As an illustration the soft dipole mode in the (11)Li nucleus is considered in a frame of the (9)Li+n+n cluster model taking into account three body continuum effects.
1995-01-01
Free electron laser seeded by ir laser driven high-order harmonic generation
International Nuclear Information System (INIS)
Coherent x-ray production by a seeded free electron laser (FEL) is important for next generation synchrotron light sources. The authors examine the feasibility and features of FEL emission seeded by a high-order harmonic generation (HHG) of an infrared laser. In addition to the intrinsic FEL chirp, the longitudinal profile and spectral bandwidth of the HHG seed are modified significantly by the FEL interaction well before saturation. This smears out the original attosecond pulselet structure. The authors introduce criteria for this smearing effect on the pulselet and the stretching effect on the entire pulse. They discuss the noise issue in such a seeded FEL.
2007-01-08
Energy Technology Data Exchange (ETDEWEB)
The non linear electrical loads can give rise to a number of disturbances in electrical power networks. Among them, the high consumption of relative power is to be noted and so is the several harmonic components which may be injected in the industry system and very often in the utility system. So, by using appropriate technical considerations, as well as measurements in typical special electrical loads, such negative effects are analyzed and ways of minimizing them are suggested. (author) 3 refs., 11 figs., 6 tabs.
1994-12-31
Synthesis of pellet-type red mud adsorbents for removal of heavy metal ions
Energy Technology Data Exchange (ETDEWEB)
Red mud is generated as a by-product in the production of Al(OH){sub 3}/Al{sub 2}O{sub 3} from bauxite ore. In this study the pellet-type adsorbents have been made from the red mud, and their adsorption capacities of heavy metal ions have been tested. The pellet-type adsorbents were synthesized to utilize the excellent adsorption capacity of the powder-type adsorbent for industrial application. The pellet-type adsorbents were prepared by mixing several kinds of additives with the red mud. It is found that the pellet-type adsorbent, made by sintering a mixture of red mud (96.0 wt%), polypropylene (2.5 wt%), fly ash (0.5 wt%), and sodium meta-silicate (1.0 wt%) at 1200 deg.C for 30 minutes, has the highest adsorption capacity. In this work, the two kinds of pellet-type adsorbents (bead-type, crushed-type) were prepared. The crushed-type adsorbent was found to show a better adsorption/desorption performance than the bead-type adsorbent. The ...
2000-02-28
British Library Electronic Table of Contents (United Kingdom)
A laboratory-scale multi-layer system was developed for the adsorption of PCDD/Fs from gas streams at various operating conditions, including gas flow rate, operating temperature and water vapor content. Excellent PCDD/F removal efficiency (>99.99%) was achieved with the multi-layer design with bead-shaped activated carbons (BACs). The PCDD/F removal efficiency achieved with the first layer adsorption bed decreased as the gas flow rate was increased due to the decrease of the gas retention time. The PCDD/F concentrations measured at the outlet of the third layer adsorption bed were all lower than 0.1ng I-TEQNm-3. The PCDD/Fs desorbed from BAC were mainly lowly chlorinated congeners and the PCDD/F outlet concentrations increased as the operating temperature was increased. In addition, the r...
2011-01-01
We show the existence of global-in-time weak solutions to a general class of coupled FENE-type bead-spring chain models that arise from the kinetic theory of dilute solutions of polymeric liquids with noninteracting polymer chains. The class of models involves the unsteady incompressible Navier-Stokes equations in a bounded domain in two or three space dimensions for the velocity and the pressure of the fluid, with an elastic extra-stress tensor appearing on the right-hand side in the momentum equation. The extra-stress tensor stems from the random movement of the polymer chains and is defined by the Kramers expression through the associated probability density function that satisfies a Fokker-Planck-type parabolic equation, a crucial feature of which is the presence of a center-of-mass diffusion term. We require no structural assumptions on the drag term in the Fokker-Planck equation; in particular, the drag term need not be corotational. With a square-integrable ...
2010-01-01
Is OD peening of Alloy 800 SG tubes desirable?
Energy Technology Data Exchange (ETDEWEB)
The shot peening of the outer surface of Alloy 800 is proposed by the steam generator supplier in order to increase the stress corrosion cracking resistance of the tubes. The benefits and drawbacks of such a treatment are evaluated, focusing on the main concern i.e. a possible enhanced tendency of stress corrosion cracking at the transition of the expanded tube-to-tubesheet joint. Stress corrosion tests as well as residual stresses measurements demonstrate no significant difference between peened and unpeened tubes at that location. The other concerns such as stability of the compressive stresses, increased risk of pitting or intergranular attack and pollution of the secondary circuit by fragmented beads appear the as minor concerns.
1992-12-31
Technology base research on zinc/air battery systems: Final report
Energy Technology Data Exchange (ETDEWEB)
The capacity extension of additives was tested in a 200 cm/sup 2/bi-cell and a Zn powder moving-bed slurry. It was found that for the Type A additives in 12 M KOH, 25 g/l of silicate provided higher capacity than stannate, titanate and aluminate additives. The optimum concentration of sorbitol (a Type B additive that stabilizes polymeric chains involving ZnO) was found to be 15 g/l in 12 M KOH. A silicate and sorbitol combination added to Zn powder slurry in 12 M KOH provided a 20% increase in discharge capacity (195 Ah/l at 200 A/cm/sup 2/) compared to the maximum capacity obtained with silicate alone. A much lower capacity (74 Ah/l) was realized with silicate as Type C additive (precipitation of ZnO away from the Zn surface, for low KOH concentrations). The mechanisms of passivation and capacity extension were discussed and a model presented. The cell voltage and power densities were determined for the discharge process as a function of (a) current densities, (b) cathode depolarizer ...
1987-09-01
Fourier analysis of energy transfer data obtained by simulating a 14-MeV #alpha#-particle in water
International Nuclear Information System (INIS)
Data from Monte Carlo transport codes are used to model radiobiological effects. We previously reported the Fourier analysis of ionization data generated by simulating a 500-keV proton traversing water. Here, we extend Fourier analysis to energy transfer data of another radiation type, a 14-MeV #alpha#-particle. A radiobiological model based on this frequency-domain analysis views cell as an information processing system . It lends itself naturally to traditional engineering analyses. One engineering principle-the output response of a linear system to random signal-is applied here to explain the fact that there is measurable difference in the magnitude of the biological effectiveness when a given biological system is irradiated with two different radiation types of the same Linear Energy Transfer (LET).
2010-01-15
Computational Complexity of Cyclotomic Fast Fourier Transforms over Characteristic-2 Fields
Cyclotomic fast Fourier transforms (CFFTs) are efficient implementations of discrete Fourier transforms over finite fields, which have widespread applications in cryptography and error control codes. They are of great interest because of their low multiplicative and overall complexities. However, their advantages are shown by inspection in the literature, and there is no asymptotic computational complexity analysis for CFFTs. Their high additive complexity also incurs difficulties in hardware implementations. In this paper, we derive the bounds for the multiplicative and additive complexities of CFFTs, respectively. Our results confirm that CFFTs have the smallest multiplicative complexities among all known algorithms while their additive complexities render them asymptotically suboptimal. However, CFFTs remain valuable as they have the smallest overall complexities for most practical lengths. Our additive complexity analysis also leads to a ...
2011-01-01
Resolution enhancement by subtraction of confocal signals taken at different pinhole sizes.
Subtractive imaging in confocal fluorescence light microscopy is based on the subtraction of a suitably weighted widefield image from a confocal image. An approximation to a widefield image can be obtained by detection with an opened confocal pinhole. The subtraction of images enhances the resolution in-plane as well as along the optic axis. Due to the linearity of the approach, the effect of subtractive imaging in Fourier-space corresponds to a reduction of low spatial frequency contributions leading to a relative enhancement of the high frequencies. Along the direction of the optic axis this also results in an improved sectioning. Image processing can achieve a similar effect. However, a 3D volume dataset must be acquired and processed, yielding a result essentially identical to subtractive imaging but superior in signal-to-noise ratio. The latter can be increased further with the technique of weighted averaging in Fourier-space. A comparison ...
2003-01-01
Global Environmental Data for Mapping Infectious Disease Distribution
UK PubMed Central (United Kingdom)
This contribution documents the satellite data archives, data processing methods and temporal Fourier analysis (TFA) techniques used to create the remotely sensed datasets on the DVD distributed...Full Text Available
2006-01-01
UK PubMed Central (United Kingdom)
BackgroundNew technology allows more precise definition of structural alterations of all retinal layers although it has not been used previously in cases of optic...Full Text Available
2008-06-01
UK PubMed Central (United Kingdom)
Assessment of subtle changes in the primary macromolecular components of cartilage, proteoglycan (PG) and collagen, is critical for the diagnosis of early stages of osteoarthritis (OA), but...Full Text Available
2007-03-01
UK PubMed Central (United Kingdom)
The polymorphic phase behavior of a homologous series of n-saturated 1,2-diacyl phosphatidylethanolamines was investigated by differential scanning calorimetry, 31P-nuclear magnetic resonance, and Fourier...Full Text Available
1993-04-01
UK PubMed Central (United Kingdom)
Context: Mild primary hyperparathyroidism (PHPT) is characterized by asymptomatic hypercalcemia, most commonly in the absence of classical signs and symptoms. Hence, there is need to characterize...Full Text Available
2008-09-01
Vibrations of circular cylindrical shells
An exact solution method for the free vibration problem of thin circular cylindrical shells is presented. The differential equations of motion are solved directly with the use of simple Fourier series as the modal displacement functions. Stokes' transformation is exploited to obtain correct series expressions for the derivatives of the Fourier series. From this method an explicit expression of the exact frequency equation can be obtained for any kind of boundary conditions. The accuracy of the present method is checked against available data. The proposed method is then used to find the modal characteristics of the thermal liner of the Fast Test Reactor (FTR). The numerical results obtained are compared with finite element method solutions. (auth)
1975-07-01
Fourier Transform Infrared (FTIR) spectroscopy has been utilized during high rate E-beam evaporation/deposition of YBa2Cu3O7 (YBCO). The results demonstrate the great utility of FTIR as an in situ monitor of YBCO deposition and processing. We detect different (amorphous/fine polycrystalline) insulating pre-existing phases to the high Tc superconducting phase which appear to have distinct reflectivity fingerprints dominated by thin film interference effects, as a function of temperature and oxygen pressure. These fingerprints reveal some of the kinetic and thermodynamic pathways during the growth of YBCO.
2007-01-01
Fourier Synthesization of Optical Pulses and "Polar'' Light
It is shown that the direct Fourier synthesization of light beams allows one to create polarity-asymmetric waves, which are able, in the process of nonlinear interaction with a medium, to break its inversion symmetry. As a result, these "polar" waves may show the effect of optical rectification in nonlinear centrosymmetric media by generating light-induced dc electric polarization. At the same time, the waves of this type, due to their unusual symmetry properties, can be used for detecting the direction and sign of a dc electric field applied to the medium. The prospects of application of polar waves to data recording and processing are discussed.
2002-01-01
Energy Technology Data Exchange (ETDEWEB)
This paper describes a novel Fourier transform infrared (FTIR) spectroscopic method that can be used to rapidly screen soil samples from potentially hazardous waste sites. Samples are heated in a thermal desorption unit and the resultant vapors are collected and analyzed in a long-path gas cell mounted in a FTIR. Laboratory analysis of a soil sample by FTIR takes approximately 10 minutes. This method has been developed to identify and quantify microgram concentrations of explosives in soil samples and is directly applicable to the detection of selected volatile organics, semivolatile organics, and pesticides.
1995-06-01
Dependence of Energy Thresholds on Laser Radiation Wavelength in Initiation of Heavy Metal Azides
The behavior of silver and lead azides (scaly and threadlike crystals, and compacted powders) in initiation of explosive decomposition by laser pulsed radiation has been investigated. Initiation energy thresholds in irradiation at wavelengths of 1064 nm, 532 nm, 354.7 nm, 266 nm corresponding to four laser radiation harmonics have been measured. Samples both uncovered and covered with a transparent dielectric (a quartz plate) with the compressive force of up to 0.5GPa were initiated. In the transparent spectral region (the first and second laser harmonics) of the heavy metal azide matrix the effect of covering the sample surface with a plate on initiation energy threshold was insignificant, whereas, in the region of bandgap absorption (the fourth harmonic) strong dependence of the initiation threshold on whether the surface under irradiation is uncovered or covered. The results obtained have been considered with the account ...
2010-01-01
Critical assessment of the Schroedinger picture of quantum mechanics
Energy Technology Data Exchange (ETDEWEB)
We provide an example in which the Heisenberg and the Schroedinger pictures of quantum mechanics give different results, thus confirming the statement of P.A.M. Dirac that the two pictures may lead to inequivalent results. We consider a one-dimensional nonrelativistic charged harmonic oscillator (frequency {omega}{sub 0} and mass m), and take into account the action of the radiation reaction and the vacuum electromagnetic forces on the charged oscillator. We show that the Heisenberg picture gives the correct value, {Dirac_h}{omega}{sub 0}/2, for the ground state energy of the harmonic oscillator in both cases of classical and quantized vacuum fields. In the case of the Schroedinger picture, considering classical vacuum fields, and using a simple calculation for the classical radiation reaction force that is valid in the limit of large mass (mc{sup 2} >> {Dirac_h}{omega}{sub 0}), we obtain the value {Dirac_h}{omega}{sub 0} for the ...
2002-12-16
VLF wave stimulation by pulsed electron beams injected from the space shuttle
International Nuclear Information System (INIS)
Among the investigations conducted on the space shuttle flight STS 3 March 1982 was an experiment in which a 1-keV, 100-mA electron gun was pulsed at 3.25 and 4.87 kHz. The resultant waves were measured with a broadband plasma wave receiver. At the time of flight the experimental setup was unique in that the electron beam was square wave modulated and that the shuttle offered relatively long times for in situ measurements of the ionospheric plasma response to the VLF pulsing sequences. In addition to electromagnetic response at the pulsing frequencies the waves exhibited various spectral harmonics as well as the unexpected occurrence of satellite lines around those harmonics. Both phenomena occurred with a variety of different characteristics for different pulsing sequences.
International Nuclear Information System (INIS)
We have studied the features of formation and the possible stationary structures of a self-consistent magnetic field in a relativistic collisionless plasma, which are characteristic of a simple geometry of the Weibel instability that is well known in the nonrelativistic case. The universal condition is established, the growth rate is determined, and the criteria of saturation of the Weibel instability are analyzed for a broad class of anisotropic particle distribution functions (for definiteness, in application to an electron-positron plasma). A nonlinear equation of the Grad-Shafranov type describing the potential current structures is derived and its solutions are analytically studied. Special attention is paid to spatially harmonic, nonlinear current configurations with parameters determined by the properties of the initial homogeneous plasma subject to the Weibel instability. It is demonstrated that the magnetic field energy density in the obtained solutions ...
2008-12-01
Predicting moisture state of timber members in a continuously varying climate
British Library Electronic Table of Contents (United Kingdom)
A prerequisite for a sensible estimate of moisture induced stresses in timber members is an accurate prediction of the members' moisture states during their service life. There are, however, an infinite number of possible moisture states for an arbitrary timber member in a natural varying climate. The naturally varying humidity is possible to describe as harmonic cycles, with different periods, superimposed. This work presents realizations of envelop curves over the possible moisture states in a timber member for some carefully chosen harmonic humidity variations. The calculations, on which the realizations were made, are based on a fully coupled transport model including a model for the influential sorption hysteresis of wood. A format containing required information suitable for assessin...
2011-01-01
Pharmaceutical applications of non-linear imaging
British Library Electronic Table of Contents (United Kingdom)
Non-linear optics encompasses a range of optical phenomena, including two- and three-photon fluorescence, second harmonic generation (SHG), sum frequency generation (SFG), difference frequency generation (DFG), third harmonic generation (THG), coherent anti-Stokes Raman scattering (CARS), and stimulated Raman scattering (SRS). The combined advantages of using these phenomena for imaging complex pharmaceutical systems include chemical and structural specificities, high optical spatial and temporal resolutions, no requirement for labels, and the ability to image in an aqueous environment. These features make such imaging well suited for a wide range of pharmaceutical and biopharmaceutical investigations, including material and dosage form characterisation, dosage form digestion and drug rele...
2011-01-01
Irreversible Performance of a Quantum Harmonic Heat Engine
The unavoidable irreversible losses of power in a heat engine are found to be of quantum origin. Following thermodynamic tradition a model quantum heat engine operating by the Otto cycle is analyzed. The working medium of the model is composed of an ensemble of harmonic oscillators. A link is established between the quantum observables and thermodynamical variables based on the concept of canonical invariance. These quantum variables are sufficient to determine the state of the system and with it all thermodynamical variables. Conditions for optimal work, power and entropy production show that maximum power is a compromise between the quasistatic limit of adiabatic following on the compression and expansion branches and a sudden limit of very short time allocation to these branches. At high temperatures and quasistatic operating conditions the efficiency at maximum power coincides with the endoreversible result. The optimal compression ratio varies from the square ...
2006-01-01
High-gain harmonic generation free electron laser seeded by few-cycle laser
International Nuclear Information System (INIS)
Tunable output wavelength is an important character of a free electron laser (FEL). As generally understood, to alter the wavelength of a high-gain harmonic generation (HGHG) FEL laser, the seed laser must be tunable. A few-cycle, high intensity laser obtained by optical compression usually has pretty broad bandwidth in the spectral domain, which can be used as the seed laser of a HGHG and may open the possibility to approach a HGHG scheme with fully tunable wavelength. In this paper, a HGHG FEL seeded by a few-cycle laser is theoretically discussed and numerically investigated. A few-cycle seed laser significantly influences HGHG FEL performance, especially in output wavelength tuning. For a HGHG FEL seeded by a 4-cycle 786 nm laser, output wavelength tunability range up to 14.9% of the central wavelength 262 nm is observed by adjusting the resonant condition.
2008-06-07
Development of the SSC (Superconducting Super Collider) trim coil beam tube assembly
Energy Technology Data Exchange (ETDEWEB)
The Superconducting Super Collider uses approx. =9600 dipole magnets. The magnets have been carefully designed to exhibit minimal magnetic field harmonics. However, because of superconductor magnetization effects, iron saturation and conductor/coil positioning errors, certain harmonic errors are possible and must be corrected by use of multipole correctors called trim coils. For the most efficient use of axial space in the magnet, and lowest possible current, a distributed internal correction coil design is planned. The trim coil assembly is secured to the beam tube, a uhv tube with special strength, size, conductivity and vacuum. The report details the SSC trim coil/beam tube assembly specifications, history, and ongoing development.
1987-01-01
Cluster models of light nuclei and the method of hyperspherical harmonics: Successes and challenges
International Nuclear Information System (INIS)
Hyperspherical-harmonics method to investigate the lightest nuclei having three-cluster structure is discussed together with recent experiments. Properties of bound states and methods to explore three-body continuum are presented. The challenges created by large neutron excess and halo phenomena are highlighted. Astrophysical aspects of the "7Li + n "#-># "8Li + #gamma# reaction and the solar-boron-neutrinos problem are analyzed. Three-cluster structure of highly excited states in "8Be is shown to be responsible for extreme isospin mixing. Progress in studies of "6He- and "1"1Li-induced inclusive and exclusive nuclear reactions is demonstrated, providing information on the nature of continuum structures of Borromean nuclei.
2009-08-01
A fast multipole transformation for global climate calculations
Energy Technology Data Exchange (ETDEWEB)
A fast multipole transformation is adapted to the evaluation of summations that occur in global climate calculations when transforming between spatial and spherical harmonic representations. For each summation, the timing of the fast multipole transformation scales linearly with the number of latitude gridpoints, but the timing for direct evaluations scales quadratically. In spite of a larger computational overhead, this scaling advantage renders the fast multipole method faster than direct evaluation for transformations involving greater than approximately 300 to 500 gridpoints. Convergence of the fast multipole transformation is accurate to machine precision. As the resolution in global climate calculations continues to increase, an increasingly large fraction of the computational work involves the transformation between spatial and spherical harmonic representations. The fast multipole transformation offers a significant reduction in ...
1996-01-01
Numerical results on the translocation of long biopolymers through mid-sized and wide pores are presented. The simulations are based on a novel methodology which couples molecular motion to a mesoscopic fluid solvent. Thousands of events of long polymers (up to 8000 monomers) are monitored as they pass through nanopores. Comparison between the different pore sizes shows that wide pores can host a larger number of multiple biopolymer segments, as compared to smaller pores. The simulations provide clear evidence of folding quantization in the translocation process as the biopolymers undertake multi-folded configurations, characterized by a well-defined integer number of folds. Accordingly, the translocation time is no longer represented by a single-exponent power law dependence on the length, as it is the case for single-file translocation through narrow pores. The folding quantization increases with the biopolymer length, while the rate of translocated beads at each ...
2009-01-01
British Library Electronic Table of Contents (United Kingdom)
Abstract Lysis and extraction of cells are essential sample processing steps for investigations pertaining to metabolism of xenobiotics in cell culture studies. Of particular importance to these procedures are maintaining high lysis efficiency and analyte integrity as they influence the qualitative and quantitative distribution of drug and toxicant metabolites in the intra- and extracellular milieus. In this study we have compared the efficiency of different procedures viz. homogenization, sonication, bead beating, and molecular grinding resin treatment for disruption of HT-29 colon cells exposed to benzo(a)pyrene (BaP), a polycyclic aromatic hydrocarbon (PAH) compound and a suspected colon carcinogen. Also, we have evaluated the efficiency of various procedures for extracting BaP parent c...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
A new method of plasma treatment for powder particles was investigated. A glass bottle horizontally held on a rotating system was used for the treatment. The outside of the bottle was covered by the grounded metal net, and the rod electrode was provided at the center of the bottle, which was connected to an ac high voltage source. Powder particles were placed in the bottle with stainless steel beads of large diameter and the plasma was generated between two electrodes and while the bottle was rotating. Using this system, powder particles were uniformly plasma-treated without coagulation. After 40 seconds treatment with plasma of 0.55 W in Ar gas, the charge to mass ratio for polyethylene powder particles having 160 {mu}m mean diameter generated by stainless before treatment. (author)
2000-03-31
British Library Electronic Table of Contents (United Kingdom)
Immobilized eggshell with a polymer mixture of alginate and polyvinyl alcohol was applied as a biocomposite adsorbent (ESC) for the adsorption of C.I. Remazol Reactive Red 198 from aqueous solution. ESC was characterized using XRD, TGA, FTIR and SEM. The Red dye adsorption onto the ESC was investigated in a batch system with respect to initial dye concentration, pH, contact time, agitation speed, solution temperature and biocomposite dosage. The prepared biocomposite exhibits high efficiency for red dye adsorption and the equilibrium states could be achieved in 3h for the different studied initial dye concentrations. The equilibrium isotherm study indicated that sorption data were analyzed and fitted well by both Langmuir and Temkin models compared to Freundlich model. The maximum monolaye...
2011-01-01
Application of alloy 800 in PWRs
International Nuclear Information System (INIS)
Alloy 800 has been used by Siemens since 1968 and is now used by KWU for U-tubed steam generators in PWR's. The particular grade of alloy 800 that is used is within the ASTM-Specification B 163, but there have been modifications in composition to improve the corrosion resistance. First the permitted upper limit of carbon was reduced to 0.04% and was then further reduced to 0.03% and a stabilisation ratio of Ti : C >= 12 and Ti : C + N >= 8 was specified. The minimum permitted chromium and nickel levels were increased to 20% and 32% respectively. The maximum permitted levels of other elements or impurities were reduced. At the final fabrication stage peening with glass beads on the outer surface was specified to introduce a compressive stress to depth greater than that allowed for production flaws. An account is given of the behaviour of the alloy in service in four power plants already in operation, and future developments are discussed. (author).
International Nuclear Information System (INIS)
New non-collinear schemes are suggested for transverse velocity modulation of electron beams and for the generation of coherent spontaneous radiation by these transversely modulated beams. It is shown that due to the non-collinearity some orders of magnitude enhancement can be achieved for the coherent spontaneous radiation (CSR) power at both the fundamental and harmonic frequencies.
2000-05-01
The triaxial motion in Mo isotopes
Energy Technology Data Exchange (ETDEWEB)
The nuclear shapes of transitional Mo isotopes are calculated by means of a model based on the cranking approximation and the Strutinksy method. The recent experimental results of the high-spin spectroscopy and lifetime measurement of [sup 87]Mo are studied in detail and explained by the evolution of the [gamma]-deformation with the quasiparticle configurations. The shape calculations with the modified-harmonic-oscillator potential give a critical neutron number N [>=] 47 for the spherical shape of the Mo isotopes. (orig.)
1993-11-22
The triaxial motion in Mo isotopes
International Nuclear Information System (INIS)
The nuclear shapes of transitional Mo isotopes are calculated by means of a model based on the cranking approximation and the Strutinksy method. The recent experimental results of the high-spin spectroscopy and lifetime measurement of "8"7Mo are studied in detail and explained by the evolution of the #gamma#-deformation with the quasiparticle configurations. The shape calculations with the modified-harmonic-oscillator potential give a critical neutron number N #>=# 47 for the spherical shape of the Mo isotopes. (orig.).
Spontaneous radiation decay of weakly bound system in externa field
International Nuclear Information System (INIS)
A new channel of nonlinear ionization of quantum system in a strong laser field is discussed. The probability of spontaneous radiation decay from the ground state in a short-range potential to the final Volkov wave function, is calculated by the first order of the perturbation theory. It is shown that this process at high intensities of the laser field will be comparable with the high harmonic generation. (orig.)
2001-02-01
P3 flux from anisotropic point source
International Nuclear Information System (INIS)
One-velocity angular flux of a neutron field generated by a polarly anisotropic point source in an infinite homogeneous region is calculated in P3 approximation, using the spherical harmonics operator formalism adapted to two-dimensional spherical geometry. The problem is reduced to simple algebraic equations. For weak absorption and linearly anisotropic scattering, the solution is given in closed form. (orig.).
In an earlier paper (Phys. Rev. Lett. 66, 41 (1991)), we calculated both the dielectric constant ({epsilon}{sub {infinity}}) and the nonlinear optical susceptibilities for second-harmonic generation ({chi}{sup (2)}) in the static limit for AlP, AlAs, GaP, and GaAs in the local-density approximation with and without a self-energy correction in the form of a scissors operator,'' including local-field effects. In this paper, we expand our presentation of this calculation. Agreement with experiment to within 15% for the nonlinear susceptibility is demonstrated where experiments are available (GaP and GaAs); the dielectric constants are in no worse than 4% agreement with experiment. The virtual hole'' contributions are reformulated to avoid large numerical cancellations in the case of near degeneracies. The virtual electron'' terms dominate over the virtual hole'' terms by about one order of ...
1991-12-15
Nuclear level densities in self-consistent field approximation
International Nuclear Information System (INIS)
The effect of two-body nature of the nuclear shell model potential on the recent numerical calculations of the nuclear level density has been examined. For the two most widely used single particle energy level schemes based on harmonic oscillator and Woods-Saxon potential, this effect is shown to significantly modify the excitation energy dependence of the level densities. (author).
1976-01-01
Monitoring interfacial dynamics by pulsed laser techniques. [Annual report
Energy Technology Data Exchange (ETDEWEB)
Goal was developing optical methods for study of dynamic processes at the electrode/electrolyte interface. In the past year, optical second harmonic generation was used for time-resolved measurements of thallium deposition on Cu(111). The studies of carrier dynamics in photo-excited materials have involved both steady-state and picosecond time-resolved luminescence measurements following photoexcitation of the semiconductor material.
1992-12-31
Imaging Three Dimensional Two-Particle Correlations for Heavy-Ion Reaction Studies
Energy Technology Data Exchange (ETDEWEB)
The authors report an extension of the source imaging method for analyzing three-dimensional sources from three-dimensional correlations. The technique consists of expanding the correlation data and the underlying source function in spherical harmonics and inverting the resulting system of one-dimensional integral equations. With this strategy, they can image the source function quickly, even with the extremely large data sets common in three-dimensional analyses.
2005-06-27
Higher harmonics of spontaneous radiation of ultrarelativistic channeled particles
International Nuclear Information System (INIS)
The case of spontaneous radiation of channeled ultrarelativistic particles is considered when the dipolarity condition is not satisfied. The change of the particle longitudinal velocity affecting the maximum radiation frequency is included. The angular and frequency characteristics of the radiation for superhigh energies are studied for the first time. It is shown that there is an optimum energy at which the radiation density is maximum. The influence of the angle at which electrons enter a crystal and of the beam divergence on the radiation is investigated. The problem of quasichanneled particle radiation and also the radiation in axis-plane transitions are considered. (author).
1980-06-01
Feynman integrals and difference equations
Energy Technology Data Exchange (ETDEWEB)
We report on the calculation of multi-loop Feynman integrals for single-scale problems by means of difference equations in Mellin space. The solution to these difference equations in terms of harmonic sums can be constructed algorithmically over difference fields, the so-called {pi}{sigma}{sup *}-fields. We test the implementation of the Mathematica package Sigma on examples from recent higher order perturbative calculations in Quantum Chromodynamics. (orig.)
2007-09-15
International Nuclear Information System (INIS)
Coherent oscillator radiation is considered. A comparison is made with classical particle radiation with gauss distribution. Decay probability for coherent state in spontaneous radiation is estimated. The method suggested for describing harmonic oscillator allows to separate the effect of classical field radiation from quantum description of particle state within the framework of a self-consistent quantum mechanical problem.
1982-04-01
Energy Technology Data Exchange (ETDEWEB)
This book examines the nonlinear optical properties of laser materials. The physical radiation effects on laser materials are also considered. Topics considered include: nonlinear optical properties; nonlinear and harmonic generation materials; two-photon absorption; nonlinear refractive index; stimulated Raman scattering; radiation damage; crystals; and glasses.
1986-01-01
Insect host/parasitoid interactions are co-evolved systems in which host defenses are balanced by parasitoid mechanisms to disable or hide from host immune effectors. Although there is a rich literature on these systems, parasitoid immune-disabling mechanisms have not been fully elucidated. Here we report on a newly discovered immune-disabling mechanism in the Pieris rapae/Pteromalus puparum host/parasitoid system. Because venom injections and parasitization suppresses host phagocytosis, we turned attention to the P. rapae scavenger receptor (Pr-SR), posing the hypothesis that P. puparum venom suppresses expression of the host Pr-SR gene. To test our hypothesis, we cloned a full-length cDNA of the Pr-SR. Multiple sequences alignment showed the deduced amino acid sequence of Pr-SR is similar to scavenger receptors of other lepidopterans. Bacterial and bead injections induced Pr-SR mRNA and protein expression, which peaked at 4h post-bead ...
2011-07-22
Energy Technology Data Exchange (ETDEWEB)
Three model boilers, manufactured to simulate full-size tube sheet crevices, were tested with various secondary side environments. The first was faulted with organics representative of the decomposition of humic acid. The second was faulted with sodium carbonate and sodium hydroxide, while the third was faulted with sodium sulfate and sodium hydroxide. Each model contained seven tubes, which included Alloy 600 in the mill-annealed (MA) and thermally-treated (TT) conditions and Alloy 690 in the thermally-treated condition. Two models contained Alloy 800 tubes in the mill-annealed condition and one had Alloy 800 in the mill-annealed/cold-worked/glass-bead-peened condition. Two different sizes of tubesheet crevices were used in all model boilers. In the organics-faulted boiler, tubes of Alloy 600MA, Alloy 690TT and Alloy 800MA experienced no significant intergranular attack (IGA); however, the Alloy 600TT had intergranular attack (IGA) three to four grains deep. The ...
1987-07-01
International Nuclear Information System (INIS)
Three model boilers, manufactured to simulate full-size tube sheet crevices, were tested with various secondary side environments. The first was faulted with organics representative of the decomposition of humic acid. The second was faulted with sodium carbonate and sodium hydroxide, while the third was faulted with sodium sulfate and sodium hydroxide. Each model contained seven tubes, which included Alloy 600 in the mill-annealed (MA) and thermally-treated (TT) conditions and Alloy 690 in the thermally-treated condition. Two models contained Alloy 800 tubes in the mill-annealed condition and one had Alloy 800 in the mill-annealed/cold-worked/glass-bead-peened condition. Two different sizes of tubesheet crevices were used in all model boilers. In the organics-faulted boiler, tubes of Alloy 600MA, Alloy 690TT and Alloy 800MA experienced no significant intergranular attack (IGA); however, the Alloy 600TT had intergranular attack (IGA) three to four grains deep. The ...
Predicting neuronal responses during natural vision.
A model that fully describes the response properties of visual neurons must be able to predict their activity during natural vision. While many models have been proposed for the visual system, few have ever been tested against this criterion. To address this issue, we have developed a general framework for fitting and validating nonlinear models of visual neurons using natural visual stimuli. Our approach derives from linear spatiotemporal receptive field (STRF) analysis, which has frequently been used to study the visual system. However, prior to the linear filtering stage typical of STRFs, a linearizing transformation is applied to the stimulus to account for nonlinear response properties. We used this approach to compare two models for neurons in primary visual cortex: a nonlinear Fourier power model, which accounts for spatial phase invariant tuning, and a traditional linear model. We characterized prediction accuracy in terms of the total explainable variance, ...
The optimization of gamma spectra processing in prompt gamma neutron activation analysis (PGNAA)
International Nuclear Information System (INIS)
The uncertainty of the elemental analysis is one of the major factors governing the utility of on-line Prompt Gamma Neutron Activation Analysis (PGNAA) in the blending and sorting of bulk materials. In this paper, a general method applicable to Gamma spectra processing is presented and applied to PGNAA in mineral industry. Based on the Fourier transform of spectra and their de-correlation in the Fourier space (the improvement of the conditioning of the correlation matrix), processing of overlapping of characteristic peaks minimizes the propagation of random errors, which optimizes the accuracy and decreases the detection limits of elemental analyses. In comparison with classical methods based on the linear combinations of relevant regions of spectra the improvement may be considerable, especially when several elements are interfering. The method is applied to four case stories covering both borehole logging and on-line analysis on conveyor belt ...
2009-04-15
Surface analysis by Fourier-transform infrared (FTIR) spectroscopy
Energy Technology Data Exchange (ETDEWEB)
A diffuse-reflectance capability for the Fourier transform infrared spectrometer at the Y-12 Plant Laboratory has been implemented. A sample cell with a 25 to 400/sup 0/C temperature-controlled sample stage and an ultrahigh-vacuum-to-atmospheric pressure gas-handling capability has been developed. Absorbance of light from the spectrometer beam, resulting from the beam being scattered from a powder sample, can be measured. This capability of detecting molecular species on and in powders is to be used to study chemisorption on actinide and rare-earth metals, alloys, and compounds. Cell design is described along with experiments demonstrating its performance in detecting moisture absorption on uranium oxide, moisture and carbon dioxide absorption on the lithium hydride/hydroxide system, and carbon dioxide absorption on potassium borohydride. 13 figures.
1981-08-12
Structure analysis of cation selective Cr-goethite as protective rust of weathering steel
International Nuclear Information System (INIS)
We have performed extended X-ray absorption fine structure (EXAFS) analysis for artificial Cr-goethite to elucidate the local structure around Cr in Cr-goethite. The spectra were obtained using synchrotron radiation X-rays at the Photon Factory in Tsukuba. The first shell contributions were isolated by Fourier filtering EXAFS data, and the inverse Fourier transformed single-shell data were analyzed using a curve fitting method. The results show that Cr is coordinated with (7#+-#1)O"2"- ions. The protective characteristics of the Cr-goethite protective rust layer on weathering steel can be interpreted in terms of the O"2"- coordination around Cr"3"+ resulting in the creation of negative fixed charge in the Cr-goethite particles. (author)
2005-02-01
Phase Information and the Evolution of Cosmological Density Perturbations
The Fourier transform of cosmological density perturbations can be represented in terms of amplitudes and phases for each Fourier mode. We investigate the phase evolution of these modes using a mixture of analytical and numerical techniques. Using a toy model of one-dimensional perturbations evolving under the Zel'dovich approximation as an initial motivation, we develop a statistic that quantifies the information content of the distribution of phases. Using numerical simulations beginning with more realistic Gaussian random-phase initial conditions, we show that the information content of the phases grows from zero in the initial conditions, first slowly and then rapidly when structures become non-linear. This growth of phase information can be expressed in terms of an effective entropy: Gaussian initial conditions are a maximum entropy realisation of the initial power spectrum, gravitational evolution decreases the phase entropy. We show that ...
2000-01-01
British Library Electronic Table of Contents (United Kingdom)
ResumeLa convergence des solutions faibles du systeme de Navier-Stokes-Fourier-Poisson compressible avec un terme de frottement est etudiee dans la limite dun frottement infini, la loi de pression incluant, comme cas particulier, celle correspondant aux particules de Fermi-Dirac. La limite se trouve etre une solution faible dun systeme de Smoluchowski-Poisson non isotherme, la temperature ne dependant que de la variable temporelle et etant determinee par la conservation de lenergie totale.
2007-01-01
Multifractal Fourier detrended cross-correlation analysis of traffic signals
Multifractal detrended cross-correlation analysis (MF-DXA) has been developed to detect the long-range power-law cross-correlation of considered signals in the presence of non-stationarity. However, crossovers arising from extrinsic periodic trends make the scaling behavior difficult to analyze. We introduce a Fourier filtering method to eliminate the trend effects and systematically investigate the multifractal cross-correlation of simulated and real traffic signals. The crossover locations are found approximately corresponding to the periods of underlying trend. Traffic velocity on one road and flows on adjacent roads show strong cross-correlation. They also present weak multifractality after periodic trends are removed. The traffic velocity and flow are cross-correlated in opposite directions which is accordant to their actual evolution.
2011-10-01
British Library Electronic Table of Contents (United Kingdom)
Fourier-transform infrared (FTIR) spectroscopy was used to monitor amino acids, organic acids, and changes during ripening. Twelve Cheddar cheese samples were ripened for 73 days and samples were drawn periodically. Water-soluble fractions of samples were analyzed by gas chromatography (20 amino acids), liquid chromatography (three organic acids), and FTIR spectroscopy (4000-700 cm-1). Spectra were correlated with chromatographic data and ripening events and analyzed by multivariate statistics to develop prediction and classification models. Most models showed a good fit (correlation coefficient > or =0.89) and could predict the levels of amino acids and organic acids and age of the cheese in less than 20 min. Lactic acid, leucine, glutamic acid, asparagine, phenylalanine, and valine were ...
2011-01-01
Fourier transform IR studies on the interaction of selected chemicals with isolated cuticles
International Nuclear Information System (INIS)
It is known that the plant cuticle represents the first barrier that must be overcome by any chemical reaching the plant surface from the atmosphere before entering the plant. Because of the importance of the cuticle as a barrier to penetration of a wide variety of compounds, its morphology, chemistry, and permeability have been extensively studied. However, only limited information is available on the nature of functional chemical groups present and their interaction and role during the penetration process. The usefulness of in situ Fourier transform infrared spectroscopy studies in identifying functional groups present in isolated cuticles is described and their relationships to the structure of the cuticular membrane are discussed. Applications of infrared spectroscopy on the presence and role of phenolics in the cuticle structure and during the cuticle development, nitrogen oxide binding to isolated cuticles, and the interactions between selected chemical ...
British Library Electronic Table of Contents (United Kingdom)
Successful electron capture dissociation (ECD) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) applications to peptide and protein structural analysis have been enabled by constant progress in implementation of improved electron injection techniques. The rate of ECD product ion formation has been increased to match the liquid chromatography and capillary electrophoresis timescales, and ECD has been combined with infrared multiphoton dissociation in a single experimental configuration to provide simultaneous irradiation, fast switching between the two techniques, and good spatial overlap between ion, photon, and electron beams. Here we begin by describing advantages and disadvantages of the various existing electron injection techniques for ECD in FT-ICR MS. We next ...
2008-01-01
A novel algebraic topology approach to supersymmetry (SUSY) and symmetry breaking in quantum field and quantum gravity theories is presented with a view to developing a wide range of physical applications. These include: controlled nuclear fusion and other nuclear reaction studies in quantum chromodynamics, nonlinear physics at high energy densities, dynamic Jahn-Teller effects, superfluidity, high temperature superconductors, multiple scattering by molecular systems, molecular or atomic paracrystal structures, nanomaterials, ferromagnetism in glassy materials, spin glasses, quantum phase transitions and supergravity. This approach requires a unified conceptual framework that utilizes extended symmetries and quantum groupoid, algebroid and functorial representations of non-Abelian higher dimensional structures pertinent to quantized spacetime topology and state space geometry of quantum operator algebras. Fourier transforms, generalized ...
2009-01-01
Tachyons and the radiation of an accelerated charge
Energy Technology Data Exchange (ETDEWEB)
The motion of an accelerated charge in a vacuum is analyzed, via the superposition principle and Fourier analysis, into uniform-motion components, which include bradyonic as well as tachyonic contributions. It is shown that the former contribute only to the induction fields whereas the latter are the source of the radiation emitted by the charge, via the Sommerfeld-Cerenkov mechanism. This result calls for a reexamination of some recently formulated theories of superluminal particles.
1982-10-15
International Nuclear Information System (INIS)
By the methods of the angular distribution of photon annihilation, time distribution of photon annihilation, photoluminescence spectroscopy, Fourier IR-spectroscopy, atomic force microscopy the detail information on relation of the structural and physical properties of the porous nano-structures is obtained. Study of pores sizes in a different nano-porous materials, such as the porous silicon, porous anode aluminium oxide, porous solids exposed to light atoms ion implantation (hydrogen, deuterium, helium) is carried out.
2003-09-15
Predictive wavefront control for Adaptive Optics with arbitrary control loop delays
Energy Technology Data Exchange (ETDEWEB)
We present a modification of the closed-loop state space model for AO control which allows delays that are a non-integer multiple of the system frame rate. We derive the new forms of the Predictive Fourier Control Kalman filters for arbitrary delays and show that they are linear combinations of the whole-frame delay terms. This structure of the controller is independent of the delay. System stability margins and residual error variance both transition gracefully between integer-frame delays.
2007-10-30
Optical measurement of electron bunching in vacuum
International Nuclear Information System (INIS)
We report the homodyne detection of phase modulation sidebands induced on a laser beam by a coherently bunched electron beam. This provides a sensitive and nonperturbing measurement of complex Fourier time series components of the electron density. A proof-of-principle measurement of the microwave frequency component of electron density in a crossed-field device, which agrees well with a calculation of the same quantity, is reported.
Longitudinal and transverse mode evolution in free electron laser
Energy Technology Data Exchange (ETDEWEB)
We use the method of Padg approximants and Fourier transform techniques to treat analytically the problem of transverse and longitudinal mode evolution in FELs. We obtain simple relations providing a transparent understanding of the dynamic of pulse propagation effects and of transverse mode guiding. We discuss the interplay with inhomogeneous broadening effects and derive gain formulae including longitudinal and transverse mode couplings.
1995-12-31
From nuclear science symposium; San Francisco, California, USA (14 Nov 1973). A digital Fourier analyzer was programmed to perform reactor neutron noise analysis measurements and on-line processing of the data to obtain the steady-state reactivity. The system is suitable for recovering cross spectral density with low correlatedsignal component and for repetitive measurements with efficient use of reactor time. (auth)
1973-01-01
Discrete phase retrieval in musical structures
British Library Electronic Table of Contents (United Kingdom)
This paper describes phase-retrieval approaches in music by focusing on the particular case of the cyclic groups (beltway problem). After presenting some old and new results on phase retrieval, we introduce the extended phase retrieval for a generalized musical Z-relation. This concept is accompanied by mathematical definitions and motivations from computer-aided composition. We assume from the reader basic knowledge of groups, topological groups, group algebras, group actions, Lebesgue integration, convolution products, and Fourier transform.
2011-01-01
Dielectric barrier discharge using corona-modified silicone rubber
Results from scanning electron microscopy, Fourier transform infrared spectroscopy and the measurement of thermally stimulated current show that a high density of the physical defects and the chemical defects are introduced into the surface of the silicone rubber plates after they are treated by corona discharge plasma. These defects behave electrically as shallow electron traps, leading to the formation of a uniform discharge in air at higher pressure when the corona-modified silicone rubber is used in dielectric barrier discharge.
2008-10-01
Absolute absorption of ozone in the midinfrared
Energy Technology Data Exchange (ETDEWEB)
The absolute absorption of ozone in the midinfrared has been measured relative to 253.7-nm ultraviolet absorption to an accuracy of 1% using a Bruker Fourier transform spectrometer. These new results agree with previous measurements by diode laser measurements after the latter are corrected for more recent infrared calculations and ultraviolet cross sections. They also agree with a determination based on refractive index measurements in the infrared. 16 refs., 4 figs., 3 tabs.
1992-12-20
Ab initio calculations in a uniform magnetic field using periodic supercells
Energy Technology Data Exchange (ETDEWEB)
We present a formulation of ab initio electronic structure calculations in a finite magnetic field, which retains the simplicity and efficiency of techniques widely used in first principles molecular dynamics simulations, based on plane-wave basis sets and Fourier transforms. In addition we discuss results obtained with this method for the energy spectrum of interacting electrons in quantum wells, and for the electronic properties of dense fluid deuterium in a uniform magnetic field.
2003-10-21
International Nuclear Information System (INIS)
The thermodynamics of the Sr-Si system is of fundamental importance for the understanding of eutectic modification of Al-Si alloys. At the same time, strontium silicides have recently been found to have potential applications in electronic devices. Renewed research efforts have led to a re-evaluation of the phase equilibria in this system, resulting in the discovery of previously undetected stable intermetallic compounds. In this work, we investigate the finite temperature thermodynamic properties of the stable (and metastable) Sr-Si intermetallics. The vibrational properties of the intermetallic compounds are calculated within harmonic theory, with quasi-harmonic corrections to account for the effects of thermal expansion. The total free energies of the compounds are computed considering vibrational and electronic contributions, as well as weak anharmonic corrections. The ground state of the system is predicted and compared to previous ...
2009-09-18
String Junctions and Holographic Interfaces
In this paper we study half-BPS type IIB supergravity solutions with multiple $AdS_3\\times S^3\\times M_4$ asymptotic regions, where $M_4$ is either $T^4$ or $K_3$. These solutions were first constructed in [1] and have geometries given by the warped product of $AdS_2 \\times S^2 \\times M_4 $ over $\\Sigma$, where $\\Sigma$ is a Riemann surface. We show that the holographic boundary has the structure of a star graph, i.e. $n$ half-lines joined at a point. The attractor mechanism and the relation of the solutions to junctions of self-dual strings in six-dimensional supergravity are discussed. The solutions of [1] are constructed introducing two meromorphic and two harmonic functions defined on $\\Sigma$. We focus our analysis on solutions corresponding to junctions of three different conformal field theories and show that the conditions for having a solution charged only under Ramond-Ramond three-form fields reduce to relations involving the positions of the poles ...
2010-01-01
International Nuclear Information System (INIS)
The advances in laser technology have made available very short and intense laser pulses which can be used to seed a high-gain single-pass free-electron laser (FEL) amplifier. With these seed pulses, a regime of the FEL interaction where the radiation evolution is simultaneously dominated by nonlinear effects (saturation) and time-dependent effects (slippage) can be explored. This regime is characterized by the propagation of a solitary wavelike pulse where the power of the optical wave grows quadratically with time, its pulse length decreases and the spectral bandwidth increases. We analyze the interplay between the field and particle dynamics of this propagation regime which was studied before and termed super-radiance. Furthermore we analyze the properties of the strong higher-order harmonic emission from this wave and its behavior when propagating in a cascade FEL. The super-radiant pulse is indeed capable of passing through the stages of a cascade FEL and to ...
2005-08-15
Interim cryo-cooler/detector report
Energy Technology Data Exchange (ETDEWEB)
This report describes development of an electronic system designed to reduce vibration generated by a cryocooler. The diminished vibration makes it practical to use the active cooler to extract heat from a portable gamma ray detector instrument. The system was developed for a Sunpower cryocooler with an integrated counterbalance mass. The overall momentum cancellation approach is also applicable to other similar cryocoolers. The cancellation system is an assembly of several components tailored to accomplish the required vibration reduction with minimum power consumption and volume. It is designed to be powered by a 18--32 Volt battery. Up to ten harmonics of the 58.65 Hz drive frequency are controlled. In addition to the vibration cancellation, the electronic system produces the drive signal for the cryocooler and regulates the cooler temperature. The system employs a sinusoidal drive to reduce the amount of higher harmonic vibration. A digital ...
1995-04-19
Energy Technology Data Exchange (ETDEWEB)
A highly efficiency partial smoothing method is proposed to be used for inverters for 40W class household fluorescent inverters. In this system, the input current from the commercial AC power source is accumulated in a capacitor with comparatively small capacity as the electric charge, and then the lamp circuit is driven by the inverter utilizing the charging voltage of the capacitor and the charging voltage of the separately prepared partial smoothing capacitor. By this method, the RF harmonic components in the supply current can be decreased to improve the power factor with no complicated feedback controlling device. In addition, comparatively small capacity coils and capacitors can be used. The structure of the circuit and the operation of this proposed method are described, and the operational characteristic of the prototype circuit and the result of analysis are shown. Furthermore, problems and improving method of the actual circuit are investigated by an ...
1997-06-20
Gauge invariant perturbation theory in spatially homogeneous cosmology
International Nuclear Information System (INIS)
The perturbations of the L.R.S. class A spatially homogeneous spacetimes are treated using Hamiltonian methods in conjunction with techniques from the theory of Lie group harmonic analysis. These latter techniques lead to a simple way of handling any set of tensor equations on these background spacetimes which has the same symmetry group as the space-time metric. Once this approach is developed, the Hamiltonian formulation is used to recover in a clean way the Bonanos equations for the perturbations of the perfect fluid models of the class of spacetimes under consideration. The conserved quantities associated with the four-dimensional symmetry group are evaluated and their role in the linearized Hamiltonian dynamics is discussed. The time-dependent linear canonical transformation of the linearized vacuum gravitational phase space adapted to Moncrief's gauge invariant decomposition is described in general for these models and evaluated explicitly for a class of ...
Development of quality assurance requirements - an international comparison
International Nuclear Information System (INIS)
Total quality management strategy and the worldwide introduction of the DIN/ISO 9000 (EN 29 000) series of standards have given new impetus to traditional quality assurance. The most important change must surely be seen in the holistic approach of total quality management and its strict orientation towards customer requirements and satisfaction. International codes and standards for the nuclear industry will also have to be brought into line as part of the process of harmonizing quality assurance system standards. One possible approach is simply to specify a supplementary 'delta' of nuclear-specific requirements to be appended to the broad range of conventional requirements. It is a particular feature of quality-assured procedures in Germany that product and/or component related quality requirements and quality verifications are defined in the specifications of the architect engineer so that full implementation of the requirements from the design phase through to ...
International Nuclear Information System (INIS)
Single crystals of semi-organic L-histidine hydrobromide have been grown by slow evaporation technique from a mixture of L-histidine and hydrobromic acid in aqueous solution at ambient temperature. From high-resolution X-ray diffraction analysis, the crystalline perfection of the grown crystal has been studied. Single crystal X-ray diffraction analyses, Nuclear Magnetic Resonance spectral analysis, Thermo-Gravimetry (TG), Differential Thermal Analysis (DTA) and hardness test have been employed to characterize the as-grown crystals. The UV cutoff wavelength of the grown crystal is below 300 nm and has a wide transparency window, which is suitable for second harmonic generation of laser in the blue region. Nonlinear optical characteristics have been studied using Q switched Nd:YAG laser (#lambda#=1064 nm). The second harmonic generation conversion efficiency of the grown crystals confirms their suitability for frequency conversion applications.
2010-12-15
British Library Electronic Table of Contents (United Kingdom)
As one of the evolutionary oldest parts of the brain, the diencephalon evolved to harmonize changing environmental conditions with the internal state for survival of the individual and the species. The pioneering work of physiologists and psychologists around the middle of the last century clearly demonstrated that the hypothalamus is crucial for the display of motivated behaviors, culminating in the discovery of electrical self-stimulation behavior and providing the first neurological hint accounting for the concepts of reinforcement and reward. Here we review recent progress in understanding the role of the lateral hypothalamic area in the control of ingestive behavior and the regulation of energy balance. With its vast array of interoceptive and exteroceptive afferent inputs and its equ...
2011-01-01
Target identification of buried coated objects
Scientific Electronic Library Online (English)
Abstract in english We consider the three dimensional electromagnetic inverse scattering problem of determining information about a buried coated object from a knowledge of the electric and magnetic fields measured on the surface of the earth corresponding to time harmonic electric dipoles as incident fields. We assume that the buried object is a perfect conductor that is (possibly) partially coated by a thin dielectric layer. No a priori assumption is made on the extent of the coating, i.e. (more) the object can be fully coated, partially coated or not coated at all. We present an algorithm based on the linear sampling method and reciprocity gap functional for reconstructing the shape of the scattering obstacle together with an estimate of the surface impedance of the coating.
2006-01-01
Polarized proton acceleration at the Brookhaven AGS
Energy Technology Data Exchange (ETDEWEB)
At the conclusion of polarized proton commissioning in February 1986, protons with an average polarization of 45%, momentum of 21.7 GeV/c, and intensity of 2 x 10/sup 10/ protons per pulse, were extracted to an external polarimeter at the Brookhaven AGS. In order to maintain this polarization, five intrinsic and nearly forty imperfection depolarizing resonances had to be corrected. An apparent interaction between imperfection and intrinsic resonances occurring at very nearly the same energy was observed and the correction of imperfection resonances using ''beat'' magnetic harmonics discovered in the previous AGS commissioning run was further confirmed.
1986-01-01
Measurement of low-energy laser pulse duration in femtosecond range
International Nuclear Information System (INIS)
Measurements of low-energy (#approx#10"- "1"0 J) femtosecond laser pulse durations have been carried out on the basis of second-order autocorrelation function analysis. The scheme of non collinear second harmonic generation realized in KDP crystal has been used for increasing of the measurement contrast and accuracy. Proposed scheme can be used for measurements in wide enough ranges of laser pulse durations (from tens femto seconds to hundreds picoseconds) and energies. (authors)
Magnetic fluctuation measurement in Sino United Spherical Tokamak plasma
International Nuclear Information System (INIS)
To investigate the magnetic fluctuations and for further transport study, the poloidal and radial magnetic field measurement is conducted on the Sino United Spherical Tokamak (SUNIST). Auto-power spectral density indicates that the magnetic fluctuation energy mainly concentrates in the frequency region lower than 10 kHz. The magnetic field oscillations, which are characterized by harmonic frequencies of 40 kHz, are observed in the scrape-off layer; by contrast, in the plasma core, the magnetic fluctuations are of Gaussian type. The time-frequency profiles show that the poloidal magnetic fluctuations are temporally intermittent. The autocorrelation calculation indicates that the fluctuations in decorrelation time vary between the core and the edge. (authors)
2007-07-01
British Library Electronic Table of Contents (United Kingdom)
We study a generalization of the classical Riemannian Tonnetz to N-tone equally tempered scales (for all N) and arbitrary triads. We classify all the spaces that result. The torus turns out to be the most common possibility, especially as N grows. Other spaces include 2-simplices, tetrahedra boundaries, and the harmonic strip (in both its cylinder and Mobius band variants). The final and most exotic space we find is something we call a 'circle of tetrahedra boundaries'. These are the Tonnetze for spaces of triads which contain a tritone. They are closely related to Peck's Klein bottle Tonnetz.
2011-01-01
Electromagnetic characterization of superconducting radio-frequency cavities for gw detection
International Nuclear Information System (INIS)
The electromagnetic properties of a prototype gravitational wave detector, based on two coupled superconducting microwave cavities, were tested. The radio-frequency (rf) detection system was carefully analysed. With the use of piezoelectric crystals small harmonic displacements of the cavity walls were induced and the parametric conversion of the electromagnetic field inside the cavities explored. Experimental results of bandwidth and sensitivity of the parametric converter versus stored energy and voltage applied to the piezoelectric crystal are reported. A rf control loop, developed to stabilize phase changes on signal paths, gave a 125 dBc rejection of the drive mode on a time scale of 1 h.
2004-03-07
A preliminary design for a one GHz NMR spectrometer magnet
International Nuclear Information System (INIS)
The authors have performed a preliminary design for a persistent GHz NMR magnet at 23.5 T and 1.8 K operating conditions. In this paper the authors shall address the issues of realistic conductor selection, the coil design, the magnetic and mechanical analysis of the coil, and the required field uniformity. In addition, they shall describe the GHz magnet cryostat with a practical 1.8 K J-T refrigerator system. Finally vibration isolation system and field shield design and its associated field harmonics will be analyzed.
1993-09-20
The hydroclimatology of the United States during El Nino/Southern Oscillation
Energy Technology Data Exchange (ETDEWEB)
Palmer Drought Severity Index (PDSI) monthly data are analyzed, building on a previous study that investigated the influence of the El Nino/Southern Oscillation (ENSO) on US streamflow. Harmonic analysis is performed using data from 1,035 selected climatological stations, allowing observation of the biennial tendency in climate data. With the middle twelve months defined as the El Nino year (0), an idealized first harmonic fit to a 24-month ENSO composite is computed for each station. By plotting the first harmonic vectors of each station, regions of similar, or coherent, response are identified. The regions identified using PDSI data represent wet conditions in the Gulf of Mexico (Gm1 and GM2) and central (C) US, and dry conditions in the Pacific northwest (PNW) and northeast (NE) US. The PNW region exhibits the strongest interrelationship between ENSO and extreme drought events. Comparing PDSI data results with other ...
1995-12-31
Energy Technology Data Exchange (ETDEWEB)
Free-electron laser (FEL) experiments have been conducted with the 38-MeV L-band electron linac at the Institute of Scientific and Industrial Research, Osaka University. It is a 1.3 GHz RF linac with a thermoionic gun, and equipped with two 12th and one 6th sub-harmonic prebunchers for producing the high-intensity single-bunch beam with a charge up to 67 nC/bunch. For oscillation experiments of FEL, the gun is replaced with that with a smaller cathode area in order to reduce the emittance of the beam. The normalized emittance has been measured to be 200 {pi} mm-mrad. The linac is operated in the long-pulse mode and one of the 12th sub-harmonic bunchers and the 6th sub-harmonic buncher are operated, so that the time duration of the macropulse is 4 {mu}s and the spacing between micropulses is 9.2 ns. The length of the micropulse is 30-40 ps and the charge in each micropulse is 2 nC. The electron beam from the linac is ...
1995-12-31
Is the Short Distance Scale a Result of a Problem with the LMC Photometric Zero Point?
Energy Technology Data Exchange (ETDEWEB)
I present a promising route to harmonize distance measurements based on clump giants and RR Lyrae stars. This is achieved by comparing the brightness of these distance indicators in three environments: the solar neighborhood, Galactic bulge and Large Magellanic Cloud (LMC). As a result of harmonizing the distance scales in the solar neighborhood and Baade's Window, I derive the new absolute magnitude of RR Lyrae stars, M{sub v}(RR) at [Fe/H] = -1.6 (0.59 {+-} 0.05, 0.70 {+-} 0.05). Being somewhat brighter than the statistical parallax solution, but fainter than typical results of the main sequence fitting to Hipparcos data, these values of M{sub V}(RR) favor intermediate or old ages of globular clusters. Harmonizing the distance scales in the LMC and Baade's Window, I show that the most likely distance modulus to the LMC, {mu}{sub LMC} is in the range 18.24 - 18.44. The Hubble constant of about 70 km/s/Mpc ...
2004-03-29
Energy Technology Data Exchange (ETDEWEB)
Concerning the transient phenomenon of solid-gas two-phase flow, an attempt was made to visualize and measure a flow phenomenon in which three-dimensional bubbles occurred, grew and collapsed in the vicinity of a gas injection nozzle while solid particles were circulating. Such a phenomenon could not or hardly be visualized and measured by conventional methods. Such two-phase flow was visualized using neutron radiography, its characteristics measured and the usefulness of the visualization by neutron radiography confirmed. For this purpose, three-dimensional fluidized bed vessels, rectangular or cylindrical-shaped, made of steel or aluminum sheet, were prepared. Polyethylene or glass beads were used as solid particles and activated carbon particles as the tracer. In the experiment, nitrogen gas was blown into the vessel from one nozzle and distributors provided at the bottom of the vessel and exhausted from the top via the exhaust valve, by which the pressure in ...
1998-01-01
Separation Science and Technology. Semiannual progress report, April 1993--September 1993
Energy Technology Data Exchange (ETDEWEB)
This document reports on the work done by the Separations Science and Technology Programs of the Chemical Technology Division, Argonne National Laboratory, in the period April-September 1993. This effort is mainly concerned with developing the TRUEX process for removing and concentrating actinides from acidic waste streams contaminated with transuranic (TRU) elements. The objectives of TRUEX processing are to recover valuable TRU elements and to lower disposal costs for the nonTRU waste product of the process. Other projects are underway with the objective of developing (1) evaporation technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process, (2) treatment schemes for liquid wastes stored or being generated at Argonne, (3) a process based on sorbing modified TRUEX solvent on magnetic beads to be used for separation of contaminants from radioactive and hazardous waste streams, and (4) a process that uses ...
1996-01-01
We prepared submicron-scale spherical hollow particles of anatase TiO2 by using a polystyrene-bead template. The obtained particles were very uniform in size, with a diameter of 490 nm and a shell thickness of 30 nm. The Brunauer-Emmett-Teller surface area measurements revealed a large value of 70 m2/g. The photocatalytic property was investigated by the complete decomposition of gaseous isopropyl alcohol under UV irradiation. It was indicated that the activity of the hollow spheres was 1.8 times higher than that of the conventional P25 TiO2 nanoparticles with a diameter of 30 nm. Furthermore, we fabricated a dye-sensitized solar cell (DSC) using an electrode of the TiO2 hollow spheres, and examined the photovoltaic performance under simulated sunlight. Although the per-area efficiency was rather low (1.26%) because of a low area density of TiO2 on the electrode, the per-weight efficiency was 2.5 times higher than those of the conventional DSCs of TiO2. ...
2007-12-19
International Nuclear Information System (INIS)
Partially purified UDPgalactosyltransferase (EC 2.4.1.22) from bovine milk has been used to synthesize millimolar amounts of compounds such as Gal#beta#(1#->#4)Glc, Gal#beta#(1#->#4)GlcNAc-#beta#-hexanolamine, and Gal#beta#(1#->#4)-GlcNAc#beta#(1#->#4)GlcNAc. The same method has been used to prepare similar compounds containing "1"3C-enriched galactopyranosyl moieties. Gal#beta#(1#->#4)GlcNAc-#beta#-hexanolamine was also synthesized in a solid-phase system in which the GlcNAc-#beta#-hexanolamine glycoside was covalently linked to agarose beads. At pH 7.0 and at 1 to 5 mM Mn"2"+"+ the yields of the galactosyl saccharides are greater than 90% by using 10% excess of UDPGal donor. The use of a 90% enriched [1-"1"3C]galactosyl residue allowed the determination of the most abundant conformer about the galactopyranosyl-glycoside linkage by analysis of the carbon-carbon coupling constants from Cl to Gal to the C3', C4', and C5' of GlcNAc or Glc. 3 figures, 1 ...
Apoferritin-Templated Yttrium Phosphate Nanoparticle Conjugates for Radioimmunotherapy of Cancers
Energy Technology Data Exchange (ETDEWEB)
We report a templated-synthetic approach based on apoferritin to prepare radionuclide nanoparticle (NP) conjugates. Non-radioactive yttrium (89Y) was used as model target and surrogate for radioyttrium (90Y) to prepare the nanoparticle conjugate. The center cavity and multiple channel structure of apoferritin offer a fast and facile method to precipitate yttrium phosphate by diffusing yttrium and phosphate ions into the cavity of apofrritin, resulting a core-shell nanocomposite. The yttrium phosphate/apoferritin nanoparticle was functionalized with biotin for further application. The synthesized nanoparticle was characterized by transmission electron microscopy (TEM) and x-ray photoelectron spectroscopy (XPS). We found that the resulting nanoparticles were uniform in size, with a diameter of around 8 nm. We tested the pre-targeting capability of the biotin-modified yttrium phosphate/apoferritin nanoparticle (yttrium phosphate/apoferritin nanoparticle) conjugate with ...
2008-05-01
A laser pyrolysis technique has been used to produce ultrafine particles of iron carbide with diameters ranging from 2 to 20 nm. Catalysis using iron carbide was investigated in the liquefaction of Wyodak subbituminous coal; yields were determined. A study was carried out to examine the possibility of using an ultrasonic extraction technique as a rapid method of product work-up of samples following pretreatment or liquefaction experiments. A similar study had shown that extraction of coal-derived products by an ultrasonic method was rapid and gave yields and product distributions comparable to those obtained by Soxhlet extraction. On another project, three different types of supported catalysts were used to test activity for the combined water-gas shift hydrogenation of a synthetic donor solvent. The three catalysts tested were: (1) Alumina supported NiMo catalyst-Shell 324m; (2) Bulk hydrous TiO NiMo catalyst; (3) Thin film hydrous TiO catalyst supported on silica ...
1991-12-31
A new kind of immobilized lipase in organic solvent and its structure model.
In this paper, we used Ca-alginate gel beads coated with polyetheneimine and glutaraldehyde to adsorb Expansum penicillium lipase. The immobilized lipase catalyzed esterification of 1-dodecanol with dodecanoic acid in benzene. The results show that when the concentration of Ca-alginate, polyetheneimine (PEI) and glutaraldehyde is 1%, 6% and 1%, respectively, the activity of the immobilized lipase and the amount of adsorbed protein are the highest. The immobilized lipase is better than the SDS-immobilized lipase. The activity of the immobilized lipase connected by glutaraldehyde is higher than the activity of that without glutaraldehyde. The initial rate of the immobilized lipase and lyophilized lipase powder is 5.9 x 10(2) nmol/min.mgpr and 2.8 x 10(1) nmol/min.mgpr, respectively. After the immobilized lipase catalyzed the esterification reaction at 37 degrees C for about 12 hours, 93.3% of 1-dodecanol was converted to ester, but for lyophilized lipase powder, only ...
1994-04-15
British Library Electronic Table of Contents (United Kingdom)
The A2P-X2+Dv=-3 bands of the 12C14N radical have been observed by time-resolved Fourier transform spectroscopy in the 1850-3100cm-1 region with a wavenumber resolution of 0.025cm-1. The radical was produced in a pulsed positive column discharge in a cyanogene and helium mixture. Seven bands of v=0-3, 1-4, 2-5, 3-6, 4-7, 5-8, and 6-9 were analyzed to give the molecular constants of each state by least-squares fitting of 801 lines. The pulsed discharge was found to be efficient for production of CN in the excited A2P state. The vibrational excitation temperature was determined to be 6680+-835K and 6757+-534K for the A2P and X2+ states, respectively. The population of the A2P was found to be 4% of that of the X2+ state in the time after turning off the discharge.
2008-01-01
Real Paley-Wiener theorems and local spectral radius formulas
We systematically develop real Paley-Wiener theory for the Fourier transform on R^d for Schwartz functions, L^p-functions and distributions, in an elementary treatment based on the inversion theorem. As an application, we show how versions of classical Paley-Wiener theorems can be derived from the real ones via an approach which does not involve domain shifting and which may be put to good use for other transforms of Fourier type as well. An explanation is also given why the easily applied classical Paley-Wiener theorems are unlikely to be able to yield information about the support of a function or distribution which is more precise than giving its convex hull, whereas real Paley-Wiener theorems can be used to reconstruct the support precisely, albeit at the cost of combinatorial complexity. We indicate a possible application of real Paley-Wiener theory to partial differential equations in this vein and furthermore we give evidence that a ...
2008-01-01
Matrix-assisted laser desorption fourier transform mass spectrometry for biological compounds
The recent development of matrix-assisted UV laser desorption (LD) mass spectrometry has made possible the ionization and detection of extremely large molecules (with molecular weights exceeding 100,000 Daltons). This technique has generated enormous interest in the biological community for the direct examination of large peptides and oligonucleotides. Although this matrix-assisted ionization method has been developed and used almost exclusively with time-of-flight (TOF) mass spectrometers, research is currently in progress to demonstrate this technique with trapped ion mass spectrometers, such as Fourier transform ion cyclotron resonance mass spectrometry (FTMS). The potential capabilities of FTMS for wide mass range, high resolution measurement, and ion trapping experiments suggest that this instrumental technique should be useful for the detailed structural characterization of large ions generated by the matrix-assisted technique. We have recently demonstrated ...
1990-01-01
British Library Electronic Table of Contents (United Kingdom)
We describe a method for the analysis of multi-site phosphorylation in serine/threonine (Ser/Thr)-rich protein sequences. Site-specific mutagenesis was used to introduce tryptic cleavage sites in the serine glutamine/threonine glutamine cluster domain (SCD) of the human checkpoint protein kinase (Chk2). The mutant proteins were shown to autophosphorylate on residues that are inducibly phosphorylated when mammalian cells are exposed to ionizing radiation (serine 33/35, serine 516, threonine 68 and threonine 432). Five Ser/Thr clusters within the SCD were flanked by arginine or lysine residues to produce tryptic peptides for nanospray liquid chromatography (nanoLC)/linear quadrupole ion trap Fourier transform ion cyclotron resonance mass spectrometry. Phosphorylation sites were assigned usin...
2007-01-01
Fluctuation properties of strength function phenomena: A model study
Energy Technology Data Exchange (ETDEWEB)
We study fluctuation properties of strength function phenomena by employing a quantum mechanical model where a single parent state couples with a large number of background states. The background system is devised in such a way that the classical dynamics of the system may show a regular, an irregular, or a chaotic character as a function of a single parameter. The coupling of the parent state to the background states produces a fragmentation of the parent state, giving rise to a strength function phenomenon. We study various measures of the strength function that characterize its bulk structure or fluctuation properties. They include energy moments, strength distribution, fractal dimensions of the strength function, and Fourier transform of the autocorrelation function. Some of these measures, such as strength distribution or Fourier transform of the autocorrelation function, reflect characteristic aspects of the dynamics of the background ...
1997-07-01
Energy Technology Data Exchange (ETDEWEB)
Radon concentrations in homes have been shown to vary considerably with season. It is important to account for this by applying a correction factor to any home radon measurement of less than one year. To date, Irish radon measurement services have used correction factors based on data derived for the UK in the 1980s. In the absence of similar data for Ireland at the time, these were considered suitable for use due to the similarities between the climates, house types and lifestyles in the two countries. In order to better estimate the long-term radon concentration, measurements from 5640 Irish homes were used to derive a set of correction factors specifically for Ireland. These were generated by means of Fourier decomposition analysis and the new correction factors compared, using 95% confidence intervals, to those derived for the UK using the same analysis and to those currently in use for Ireland. In both cases, a significant difference was found between 10 of ...
2010-09-15
Bar strengths in spiral galaxies estimated from 2MASS images
Non-axisymmetric forces are presented for 107 spiral galaxies using the 2 Micron All Sky Survey (2MASS) images. We apply both Cartesian integration and a polar grid integration utilizing a limited number of azimuthal Fourier components of density. We found that bar strength is independent of the method used to evaluate the gravitational potential. However, the polar method is more suitable for weak and noisy images. Bar strength was found to be sensitive to the Hubble-type dependent scale height of the disk, which has been ignored in the previous studies. On the other hand, the method is rather insensitive to the vertical model of the disk, as long as a same vertical dispersion is assumed, or to the boxy/peanut shaped structure, studied in terms of non-constant vertical scale height along the disk. In the near-IR most galaxies in our sample show non-axisymmetric forces in some level, and 40 percent of them have bars in a sense that they have regions with a constant ...
2002-01-01
British Library Electronic Table of Contents (United Kingdom)
A comprehensive and highly selective method for detecting in bacterial supernatants a modified sulfur nucleoside, S-adenosyl-L-methionine (SAM), and its metabolites, i.e., S-adenosylhomocysteine (SAH), adenosine (Ado), 5prime-deoxy-5prime-methylthioadenosine (MTA), adenine (Ade), S-adenosyl-methioninamine (dcSAM), homocysteine (Hcy) and methionine (Met), was developed. The method is based on reversed-phase liquid chromatography with positive electrospray ionization (ESI+) coupled to a hybrid linear quadrupole ion trap (LTQ) and 7-T Fourier transform ion cyclotron resonance mass spectrometry (FTICRMS). A gradient elution was employed with a binary solvent of 0.05 M ammonium formate at pH 4 and acetonitrile. The assay involves a simultaneous cleanup of cell-free bacterial broths by solid-pha...
2009-01-01
Energy Technology Data Exchange (ETDEWEB)
Negative ion electrospray ionization (ESI) coupled with high field Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) allows for the direct detection of acidic NSO compounds in petroleum. The technique requires no chromatographic separation, is able to distinguish 18 different compound classes (e.g., neutral nitrogen, carboxylic acids and oxygenates), and can identify {approx}14,000 distinct masses by ultra-high mass resolution and mass accuracy. We previously studied three crude oils from different geological origins [Organic Geochemistry 33 (2002b) 743-759]. Here, we expand our research by comparing two source-equivalent Smackover oils of different levels of thermal maturity. We observe clear differences in the distribution of NSO compound classes, types (number of rings plus double bonds within a class), and number of alkyl carbons. With increasing thermal stress, the relative amount of sulfur and oxygen containing compounds decreases, ...
2004-07-01
Vibrational spectroscopy of silica sol-gel components during microwave irradiation
Energy Technology Data Exchange (ETDEWEB)
In order to study the effects of microwaves on chemical reactions equipment was designed to acquire in-situ vibrational spectra of sol-gel components as they are irradiated with microwaves. Fourier Transform Infrared (FTIR) and Raman spectroscopy were used. A low temperature (10K) FTIR cell was used to trap samples in an argon matrix at 10{sup -7} Torr. For the liquid samples no differences were seen in spectra of irradiated and nonirradiated samples, but the argon matrix isolation technique showed dramatic differences.
1995-12-31
Synthesis and characterization of Rosebengal/folicacid-functionalized multiwall carbon nanotubes
British Library Electronic Table of Contents (United Kingdom)
Multiwall carbon nanotubes (MWCNTs) were functionalized with a photosensitizer, rosebengal (RB), and folicacid (FA), an anti-cancer drug simultaneously and individually, which was characterized with various analytical instruments like Fourier Transform Iinfrared (FTIR) spectroscopy, UV?Vis spectroscopy, Thermogravimetric analysis (TGA), Photoluminescence (PL) spectroscopy, X-ray photoelectron spectroscopy (XPS), and Transmission electron microscopy (TEM). FTIR spectra confirmed the chemical modification of MWCNT. The chemical functionalization of MWCNT with RB was further supported by UV?Vis and PL spectra.
2011-01-01
State-of-the-art technique for power system stabilizer tuning
Energy Technology Data Exchange (ETDEWEB)
Power System Stabilizers (PSS) have broad application throughout the world. PSS application requires careful tuning which is usually accomplished in the field with the generator and power system in an abnormal condition. Recently developed equipment which combines fast Fourier transform capability with digital computer technique provides a means of PSS tuning which is faster and more accurate than was previously obtainable. This paper describes a PSS tuning test conducted using the new technique. The advantages will be apparent to the reader. The described test is very poignant as evidenced by two unexpected occurrences of instability.
1983-03-01
Selection of transverse modes in laser cavities containing waveguides and open parts
International Nuclear Information System (INIS)
The transverse modes of a submillimetre laser cavity that contains waveguides and open parts were studied theoretically and experimentally with the purpose of finding methods for mode selection. Two methods based on the filtering of the Fourier spectra of the waveguide modes and the use of their interference were substantiated numerically and realised in experiment. Special attention was paid to the mode selection in tunable lasers. Scaling laws allowing one to use the obtained results in a wide range of the cavity parameters and wavelengths are presented. (laser applications and other topics in quantum electronics)
2001-04-30
Optimal oscillation-center transformations
Energy Technology Data Exchange (ETDEWEB)
A variational principle is proposed for defining that canonical transformation, continuously connected with the identity transformation, which minimizes the residual, coordinate-dependent part of the new Hamiltonian. The principle is based on minimization of the mean-square generalized force. The transformation reduces to the action-angle transformation in that part of the phase space of an integrable system where the orbit topology is that of the unperturbed system, or on primary KAM surfaces. General arguments in favor of this definition are given, based on Galilean invariance, decay of the Fourier spectrum, and its ability to include external fields or inhomogeneous systems. The optimal oscillation-center transformation for the physical pendulum, or particle in a sinusoidal potential, is constructed.
1984-08-01
Energy Technology Data Exchange (ETDEWEB)
This study shows that the physical conditions necessary for thermal waves to materialize in Dual-Phase-Lagging porous media conduction are not attainable in a porous slab subject to a combination of constant heat flux and temperature (Neumann and Dirichlet) boundary conditions. It is demonstrated that the approximate equivalence between Dual-Phase-Lagging (DuPhlag) heat conduction model and the Fourier heat conduction in porous media subject to Lack of Local Thermal Equilibrium (La Lotheq) that suggested the possibility of thermal oscillations and resonance reveals a condition that cannot be fulfilled because of physical constraints. (author)
2005-07-01
Interpretation of EXAFS data from laser shock compressed plasmas
Energy Technology Data Exchange (ETDEWEB)
Measurements on laser shock compressed aluminium using the EXAFS (Extended X-ray Absorption Fine Structure) technique on the Al K-edge are described. Two methods of analysis of this data were used for the determination of density: the standard EXAFS technique using Fourier transforms and curve fitting, and a method based on a bandstructure calculation of the absorption spectra as a function of compression. These two techniques give results which are in fairly good agreement with each other and also with a hydrodynamic simulation of the experiment. The ion correlation parameter is estimated and shows that two-sided laser irradiation of aluminium foils produces a dense plasma which is strongly coupled. (author).
1989-01-01
Discrete simulation of power law noise
A method for simulating power law noise in clocks and oscillators is presented based on modification of the spectrum of white phase noise, then Fourier transforming to the time domain. Symmetric real matrices are introduced whose traces--the sums of their eigenvalues--are equal to the Allan variances, in overlapping or non-overlapping forms, as well as for the corresponding forms of the modified Allan variance. Diagonalization of these matrices leads to expressions for the probability distributions for observing a variance at an arbitrary value of the sampling or averaging interval $\\tau$, and hence for estimating confidence in the measurements. A number of applications are presented for the common power-law noises.
2011-01-01
British Library Electronic Table of Contents (United Kingdom)
Dimethyl methylphosphonate (DMMP), a chemical simulant of the nerve gas GB, was decontaminated with a nonthermal atmospheric pressure plasma. The decontamination efficiency was measured qualitatively by means of Fourier transform spectroscopy and quantitatively by means of gas chromatography. With helium gas only, 10g/m2 of DMMP on an aluminum surface was 99.9% decontaminated in 2min, furthermore, with the addition of 5% of oxygen gas, it was 99.99% decontaminated in 10min. Given the low input power (<100W) and temperature (<75degreeC), this plasma is eligible for nondestructive decontamination of almost all material surfaces.
2009-01-01
Application of the neutron television fluoroscopic system to neutron computed tomography
Energy Technology Data Exchange (ETDEWEB)
Recently the real-time neutron radiography system of the Kyoto University Reactor (KUR) has been developed and practically applied to penetrating the side plates of the MTR type reactor fuels and investigation of moving objects. In this paper an application of the KUR neutron TV system to neutron computed tomography (NCT) is described. By using the NTV system, projection data can be acquired in a single measurement and simultaneously the projection image can be observed on a CRT monitor. The Fourier-convolution technique is used to produce the reconstructed image and its image has a good enough quality for revealing water in a small hole of 1.5 mm in diameter. (orig.).
1984-10-01
Application of the neutron television fluoroscopic system to neutron computed tomography
Energy Technology Data Exchange (ETDEWEB)
Recently the real-time neutron radiography system of the Kyoto University Reactor (KUR) has been developed and practically applied to penetrating the side plates of the MTR type reactor fuels and investigation of moving objects. In this paper an application of the KUR neutron TV system to neutron computed tomography (NCT) is described. By using the NTV system, projection data can be acquired in a single measurement and simultaneously the projection image can be observed on a CRT monitor. The Fourier-convolution technique is used to produce the reconstructed image and its image has a good enough quality for revealing water in a small hole of 1.5 mm in diameter.
1984-10-01
An application of the neutron television fluoroscopic system to neutron computed tomography
International Nuclear Information System (INIS)
Recently the real-time neutron radiography system of the Kyoto University Reactor (KUR) has been developed and practically applied to penetrating the side plates of the MTR type reactor fuels and investigation of moving objects. In this paper an application of the KUR neutron TV system to neutron computed tomography (NCT) is described. By using the NTV system, projection data can be acquired in a single measurement and simultaneously the projection image can be observed on a CRT monitor. The Fourier-convolution technique is used to produce the reconstructed image and its image has a good enough quality for revealing water in a small hole of 1.5 mm in diameter. (orig.).
1984-10-01
Alpha-particle scattering from Ca-nuclei
International Nuclear Information System (INIS)
The possibilities, advantages, and difficulties of determining nuclear matter densities by elastic scattering of alpha-particles are generally discussed. On the basis of particular experimental data - 104 MeV alpha-particle scattering from "4"0,"4"2,"4"4,"4"8Ca - a refined folded potential is introduced using a density-dependent alpha-nucleon-interaction and target nucleus densities described by Fourier-Bessel-series. Thereby, the total nucleon densities of these isotopes were determined with little model dependence. The resulting root-mean-square radii and density differences are compared with other experimental results obtained by different methods. (orig.).
1979-07-01
The accurate magnetic structure of CeAl{sub 2} at various temperatures in the ordered state
Energy Technology Data Exchange (ETDEWEB)
The magnetic structure of the cubic compound CeAl{sub 2} is incommensurate and double-k. The moments on the two Ce sites describe two elliptical helices of opposed chiralities and lie in the (11-bar0) plane, with their Fourier components m{sup k} close to the [111] direction. Recent symmetry considerations, including for the first time the inversion center of the crystal, have reduced the number of parameters of this structure and have underlined the existence of a phase difference between the projections m{sub x}{sup k}, m{sub y}{sup k} and m{sub z}{sup k} of m{sup k}. Up to now, although many neutron investigations have been carried out on CeAl{sub 2} single crystals, no set of magnetic intensities was available which was large and good enough to check whether this phase difference exists or not. We have measured such a set of data, taking great care of the instrumental resolution in order to avoid unwanted contributions to the intensities from other domains. As ...
2008-04-02
The accurate magnetic structure of CeAl_2 at various temperatures in the ordered state
International Nuclear Information System (INIS)
The magnetic structure of the cubic compound CeAl_2 is incommensurate and double-k. The moments on the two Ce sites describe two elliptical helices of opposed chiralities and lie in the (11-bar0) plane, with their Fourier components m"k close to the [111] direction. Recent symmetry considerations, including for the first time the inversion center of the crystal, have reduced the number of parameters of this structure and have underlined the existence of a phase difference between the projections m_x"k, m_y"k and m_z"k of m"k. Up to now, although many neutron investigations have been carried out on CeAl_2 single crystals, no set of magnetic intensities was available which was large and good enough to check whether this phase difference exists or not. We have measured such a set of data, taking great care of the instrumental resolution in order to avoid unwanted contributions to the intensities from other domains. As the magnetic form factor of the #GAMMA#_7 ground ...
2008-04-02
Dynamic-stiffness matrix of embedded and pile foundations by indirect boundary-element method
Energy Technology Data Exchange (ETDEWEB)
The boundary-integral equation method is well suited for the calculation of the dynamic-stiffness matrix of foundations embedded in a layered visco-elastic halfspace (or a transmitting boundary of arbitrary shape), which represents an unbounded domain. It also allows pile groups to be analyzed, taking pile-soil-pile interaction into account. The discretization of this boundary-element method is restricted to the structure-soil interface. All trial functions satisfy exactly the field equations and the radiation condition at infinity. In the indirect boundary-element method distributed source loads of initially unknown intensities act on a source line located in the excavated part of the soil and are determined such that the prescribed boundary conditions on the structure-soil interface are satisfied in an average sense. In the two-dimensional case the variables are expanded in a Fourier integral in the wave number domain, while in three dimensions, ...
1984-08-01
de Haas--van Alphen effect and Fermi surface of lutetium
International Nuclear Information System (INIS)
We report de Haas--van Alphen measurements of the Fermi surface of lutetium at temperatures down to 0.3 K and in fields up to 150 kG in the (1010) and (1120) planes. Lutetium, having a filled 4f shell, serves as a nonmagnetic prototype of the structurally similar (hcp), trivalent, heavy rare-earth elements from Gd to Tm. The fact that no complete frequency branches were observed indicates that there are no closed pieces of the Fermi surface. We observed all but one orbit predicted by relativistic augmented-plane-wave calculations of Keeton and Loucks and by recent spin-orbit--linearized-augmented-plane-wave calculations of Tibbetts and Harmon. The data support a geometry similar to that of yttrium, and in good qualitative agreement with energy-band theory.
The high-density regime of kinetic-dominated loop quantum cosmology
We study the dynamics of states perturbatively expanded about a harmonic system of loop quantum cosmology, exhibiting a bounce. In particular, the evolution equations for the first and second order moments of the system are analyzed. These moments back-react on the trajectories of the expectation values of the state and hence alter the energy density at the bounce. This analysis is performed for isotropic loop quantum cosmology coupled to a scalar field with a small but non-zero constant potential, hence in a regime in which the kinetic energy of matter dominates. Analytic restrictions on the existence of dynamical coherent states and the meaning of semi-classicality within these systems are discussed. A numerical investigation of the trajectories of states that remain semi-classical across the bounce demonstrates that, at least for such states, the bounce persists and that its properties are similar to the standard case, in which the moments of the states are ...
2010-01-01
The electron cyclotron absorption diagnostic for the JET pumped divertor plasma
International Nuclear Information System (INIS)
We present the design of a diagnostic system to measure electron cyclotron absorption at the second harmonic E-mode resonance in the JET pumped divertor plasma. The diagnostic will measure transmission as a function of frequency along one or more sightlines from which the spatial profile of the n_eT_e product will be deduced. The divertor is briefly described, and the electron cyclotron resonance physics relevant to this measurement is reviewed. The problems of measuring transmission using an oversized transmission system are discussed and the chosen measurement technique, a swept frequency interferometer using a coherent radiation source, is described. A prototype of the instrument has been assembled to test the measurement technique. Some data demonstrating the instrument's characteristics are presented. The nonresonant losses, which may affect the interpretation of the measurement, are also discussed. (orig.).
1993-03-01
Synchrotron radiation from electron beams in plasma-focusing channels.
Spontaneous radiation emitted from relativistic electrons undergoing betatron motion in a plasma-focusing channel is analyzed, and applications to plasma wake-field accelerator experiments and to the ion-channel laser (ICL) are discussed. Important similarities and differences between a free electron laser (FEL) and an ICL are delineated. It is shown that the frequency of spontaneous radiation is a strong function of the betatron strength parameter a(beta), which plays a role similar to that of the wiggler strength parameter in a conventional FEL. For a(beta) > or approximately 1, radiation is emitted in numerous harmonics. Furthermore, a(beta) is proportional to the amplitude of the betatron orbit, which varies for every electron in the beam. The radiation spectrum emitted from an electron beam is calculated by averaging the single-electron spectrum over the electron distribution. This leads to a frequency broadening of the radiation spectrum, which places ...
2002-05-20
British Library Electronic Table of Contents (United Kingdom)
Background: Mechanisms underlying the association between myocardial bridge (MB)-stenting and in-stent restenosis (ISR) are still unclear. Objective: To assess the impact of MB on ISR using intravascular ultrasound (IVUS). Methods: In the Harmonizing Outcomes with Revascularization and Stents in Acute Myocardial Infarction (HORIZONS-AMI) trial, 100 left anterior descending artery (LAD) culprit lesions (79 treated with paclitaxel-eluting stents [PES] and 21 treated with bare metal stents) were imaged with serial IVUS immediately postprocedure and at 13 months. Results: At baseline the LAD stent extended into the MB segment beyond the culprit lesion in seven patients (MB-stent group). In the remaining 93 patients the LAD stent was implanted only in the culprit lesion without extending into t...
2010-01-01
Perturbations of Schwarzschild Black Holes in Chern-Simons Modified Gravity
We study perturbations of a Schwarzschild black hole in Chern-Simons modified gravity. We begin by showing that Birkhoff's theorem holds for a wide family of Chern-Simons coupling functions, a scalar field present in the theory that controls the strength of the Chern-Simons correction to the Einstein-Hilbert action. After decomposing the perturbations in spherical harmonics, we study the linearized modified field equations and find that axial and polar modes are coupled, in contrast to general relativity. The divergence of the modified equations leads to the Pontryagin constraint, which forces the vanishing of the Cunningham-Price-Moncrief master function associated with axial modes. We analyze the structure of these equations and find that the appearance of the Pontryagin constraint yields an overconstrained system that does not allow for generic black hole oscillations. We illustrate this situation by studying the case characterized by a canonical choice of the ...
2007-01-01
Parametric study of pulsed thermal bumps in supersonic boundary layer
British Library Electronic Table of Contents (United Kingdom)
A three-dimensional numerical study is performed to explore the effect of pulsed spanwise-periodic surface thermal perturbation (also denoted as thermal bump) in a Mach 1.5 flat plate laminar boundary layer. A high-resolution upwind-biased Roe method is used with the compressive Van Leer harmonic limiter on a suitably refined mesh. The dependence of flow stability characteristics on the variation of thermal bump geometry (shape and dimension) and pulsing properties (disturbance amplitude and frequency) is assessed. It is shown that the finite-span thermal bumps generate streamwise vortices. When the thermal bump is pulsed, vortex shedding is observed, and the streamwise vorticity grows with the downstream distance. Analysis of the integrated disturbance energy indicates that the streamwise...
2011-01-01
Los Alamos Advanced Free-Electron Laser
Energy Technology Data Exchange (ETDEWEB)
At Los Alamos, we are building a free-electron laser (FEL) for industrial, medical, and research applications. This FEL, which will incorporate many of the new technologies developed over the last decade, will be compact in size, robust, and user-friendly. Electrons produced by a photocathode will be accelerated to 20 MeV by a high-brightness accelerator and transported using permanent-magnet quadrupoles and dipoles. They will form an electron beam with an excellent instantaneous beam quality of 10 {pi} mm mrad in transverse emittance and 0.3% in energy spread at a peak current up to 300 A. Including operation at higher harmonics, the laser wavelength extends form 3.7 {mu}m to 0.4 {mu}m. In this paper, we will describe the project and the programs to date. 10 refs., 10 figs., 1 tab.
1991-01-01
Locally resonant acoustic metamaterials with 2D anisotropic effective mass density
British Library Electronic Table of Contents (United Kingdom)
A two-dimensional (2D) lattice model with anisotropic resonant microstructures is found to provide an anisotropic band gap structure. A 2D continuum with anisotropic effective mass density is introduced to represent this lattice system. Two methods are proposed to derive the equivalent continuum. In the first method, the effective mass density of the equivalent continuum is obtained by matching the dispersion relations for harmonic waves propagating in the principal directions. The second approach employs an approximate estimation of the effective mass density by volume-averaging an effective mass that represents the resonant microstructure. For both equivalent continuum models, the effective mass density is frequency-dependent and may become negative in certain frequency ranges. Subsequen...
2011-01-01
Language and Music in the Musician Brain
British Library Electronic Table of Contents (United Kingdom)
Abstract Results of numerous experiments conducted over the past 15-years by using behavioural as well as brain imaging methods have shown that musical expertise influences brain anatomy, brain functions and behaviour. The musician- brain is thus considered as a very good model of brain plasticity. Moreover, many results have demonstrated that musical expertise not only impacts on music processing but also on several aspects of speech processing including lexical pitch, sentence intonation and the metric structure of words. Conversely, recent results indicated that linguistic expertise with tone or quantity languages such as Mandarin Chinese, Thai, Finnish and Japanese, influences the processing of harmonic tones and musical intervals. We discuss possible interpretations of these findings ...
2011-01-01
Infrared (IR) vs x-ray power generation in the SLAC Linac Coherent Light Source (LCLS)
Energy Technology Data Exchange (ETDEWEB)
The LCLS, a Free-Electron Laser (FEL) designed for operation at a first harmonic energy of 300 eV ({lambda} {congruent} 40{Angstrom}) in the Self-Amplified Spontaneous Emission (SASE) regime, will utilize electron bunches compressed down to durations of <0.5ps, or lengths of <150 {mu}. It is natural to inquire whether coherent radiation of this (and longer) wavelength will constitute a significant component of the total coherent output of the FEL. In this paper a determination of a simple upper bound on the IR that can be generated by the compressed bunches is outlines. Under the assumed operating parameters of the LCLS undulator, it is shown that that IR component of the coherent output should be strongly dominated by the x-ray component.
1993-05-01
High Tc superconducting magnetic multivibrators for fluxgate magnetic-field sensors
Sensitive and quick-response nonlinear inductance characteristics are found for high Tc superconducting (YBa/sub 2/Cu/sub 3/O/sub 7-chi/) disk cores at 77K in which soft magnetic BH hysteresis loops are observed. Various quick response magnetic devices such as modulators, amplifiers and sensors are built using these cores. The magnetizing frequency can be set to more than 20 MHz, which is difficult for conventional ferromagnetic bulk materials such as Permalloy amorphous alloys and ferrite. New quick-response fluxgate type magnetic-field sensors are made using ac and dc voltage sources. The former is used for second-harmonic type sensors, while the latter is for voltage-output multivibrator type sensors. Stable and quick-response sensor characteristics were obtained for two-core type multivibrators.
1989-09-01
Gravity-wave insights to Bianchi type-IX universes
Energy Technology Data Exchange (ETDEWEB)
Every Bianchi type-IX universe can be interpreted as a closed Friedmann universe on which is superimposed circularly polarized gravitational waves with the longest wavelength that will fit into a closed universe. In this paper, I give a new derivation of this result based on the concept of homogeneous tensor fields on the three-sphere. Every homogeneous symmetric traceless tensor field is shown to be a longest-wavelength three-sphere harmonic. Contrary to previous authors, I show that the wavelength of these gravitational waves is one-half the circumference of the universe. In order to maintain homogeneity, the gravitational waves must all have the same polarization. There are five longest-wavelength modes for each polarization. This interpretation is an {ital exact} description that is valid for every Bianchi type-IX universe---it is in no way limited to first-order perturbations of a Friedmann universe.
1991-10-15
Energy Technology Data Exchange (ETDEWEB)
In a laser system for converting infrared laser light waves to visible light comprising a source of infrared laser light waves and means of harmoic generation associated therewith for production of light waves at integral multiples of the frequency of the original wave, the improvement of said means of harmonic generation comprising a crystal having the chemical formula X.sub.2 Y(NO.sub.3).sub.5 .multidot.2 nZ.sub.2 o wherein X is selected from the group consisting of Li, Na, K, Rb, Cs, and Tl; Y is selected from the group consisting of Sc, Y, La, Ce, Nd, Pr, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Al, Ga, and In; Z is selected from the group consisting of H and D; and n ranges from 0 to 4.
1992-01-01
Free-electron laser driven by the LBNL laser-plasma accelerator
Energy Technology Data Exchange (ETDEWEB)
A design of a compact free-electron laser (FEL), generating ultra-fast, high-peak flux, XUV pulses is presented. The FEL is driven by ahigh-current, 0.5 GeV electron beam from the Lawrence Berkeley National Laboratory (LBNL) laser-plasma accelerator, whose active acceleration length is only a few centimeters. The proposed ultra-fast source (~;;10 fs) would be intrinsically temporally synchronized to the drive laser pulse, enabling pump-probe studies in ultra-fast science. Owing to the high current (>10 kA) of the laser-plasma-accelerated electron beams, saturated output fluxes are potentially greater than 10^13 photons/pulse. Devices based both on self-amplified spontaneous emission and high-harmonic generated input seeds, to reduce undulator length and fluctuations, are considered.
2008-08-04
Energy Technology Data Exchange (ETDEWEB)
The electron cyclotron resonance layer in a tokamak, {omega}={omega}{sub c}(r), is not accessible by the extraordinary wave from the low field side, because it is shielded by a cutoff layer. However, a X-mode launched with a nonzero toroidal angle propagates at the cutoff parallel to the magnetic field and has a circular polarization. Therefore it can already at the cutoff layer interact efficiency with electrons via the Doppler shifted resonance. The driven current can be substantially higher than that driven by the second harmonic X-mode. The applicability of this current drive scheme is limited to rather low values of {omega}{sub p}{sup 2}/{omega}{sub c}{sup 2}, but may be of interest for high magnetic field devices. (author)
2000-02-01
Effects of velocity-dependent force on the magnetic form factors of odd-Z
International Nuclear Information System (INIS)
We investigate the effects of the velocity-dependent force on the magnetic form factors and magnetic moments of odd-Z nuclei. The form factors are calculated with the harmonic-oscillator wavefunctions. It is found that the contributions of the velocity-dependent force manifest themselves in the very large momentum transfer region (q?4 fm-1). In the low and medium q region the contributions of the velocity-dependent force are very small compared with those without this force. However, in the high-q region the contributions of the velocity-dependent force are larger than the normal form factors. The diffraction structures beyond the existing experimental data are found after the contributions of the velocity-dependent force are included. The formula of the correction to the single particle magnetic moment due to the velocity-dependent force is reproduced exactly in the long-wavelength limit (q=0) of the M1 form factor. (authors)
2008-03-01
Double plasma mirror for ultrahigh temporal contrast ultra-intense laser pulses
International Nuclear Information System (INIS)
We present and characterize a very efficient optical device that employs the plasma mirror technique to increase the contrast of high-power laser systems. Contrast improvements higher than 104 with 50% transmission are shown to be routinely achieved on a typical 10 TW laser system when the pulse is reflected on two consecutive plasma mirrors. Used at the end of the laser system, this double plasma mirror preserves the spatial profile of the initial beam, is unaffected by shot-to-shot fluctuations, and is suitable for most high peak power laser systems. We use the generation of high-order harmonics as an effective test for the contrast improvement produced by the double plasma mirrors. (authors)
Couple stress fluid improve rub-impact rotor-bearing system - Nonlinear dynamic analysis
British Library Electronic Table of Contents (United Kingdom)
This study performs a dynamic analysis of the rub-impact rotor supported by two couple stress fluid film journal bearings. The strong nonlinear couple stress fluid film force, nonlinear rub-impact force and nonlinear suspension (hard spring) are presented and coupled together in this study. The displacements in the horizontal and vertical directions are considered for various non-dimensional speed ratios. The numerical results show that the dynamic behaviors of the system vary with the dimensionless speed ratios, the dimensionless unbalance parameters and the dimensionless parameter, l*. Inclusive of the periodic, sub-harmonic, quasi-periodic and chaotic motions are found in this analysis. The results of this study contribute to a further understanding of the nonlinear dynamics of a rotor-...
2010-01-01
Construction of the maximal solution of Backus? problem in geodesy and geomagnetism
British Library Electronic Table of Contents (United Kingdom)
The (simplified) Backus? Problem (BP) consists in finding a harmonic function u on the domain exterior to the three dimensional unit sphere S, such that u tends to zero at infinity and the norm of the gradient of u takes prescribed values g on S. Except for a change of sign, the solution is not unique in general. However, there is uniqueness of solutions in the class of functions with the additional property that the radial component of the gradient of u on S is nonpositive. This is the geodetically relevant case. If a solution u with this property exists, then u is the maximal solution of the problem (and -u the minimal one). In this paper we propose a method of successive approximations to get this particular solution of BP and prove the convergence for functions g close to a constant fu...
2011-01-01
Chatter resistance of non-uniform turning bars with attached dynamic absorbers—Analytical approach
British Library Electronic Table of Contents (United Kingdom)
Forced harmonic vibration of a non-uniform elastic beam with attached dynamic vibration absorbers (DVA) is studied. Analytical approximation of the solution is obtained by the functional perturbation method (FPM). The problem has application to cutting tools operations where the resistance of the tool holder against regenerative chatter can be enhanced by optimizing the real part of the frequency response function (FRF). A test case of a beam with step-like heterogeneity and single DVA at the tip shows that the FPM solution is very accurate for up to ?40 percent deviation in both stiffness and mass density. Using the analytical results and Sims approach, optimal DVA tuning is found for each set of beam heterogeneity parameters by solving a set of nonlinear algebraic equations numer...
2010-01-01
Atomic density functions: atomic physics calculations analyzed with methods from quantum chemistry
This contribution reviews a selection of findings on atomic density functions and discusses ways for reading chemical information from them. First an expression for the density function for atoms in the multi-configuration Hartree--Fock scheme is established. The spherical harmonic content of the density function and ways to restore the spherical symmetry in a general open-shell case are treated. The evaluation of the density function is illustrated in a few examples. In the second part of the paper, atomic density functions are analyzed using quantum similarity measures. The comparison of atomic density functions is shown to be useful to obtain physical and chemical information. Finally, concepts from information theory are introduced and adopted for the comparison of density functions. In particular, based on the Kullback--Leibler form, a functional is constructed that reveals the periodicity in Mendeleev's table. Finally a quantum similarity measure is ...
2011-01-01
A unified framework for biological evolution and stochastic quantization
We investigate the profound relation between the equations of biological evolution and quantum mechanics by writing a biologically inspired equation for the stochastic dynamics of an ensemble of particles. Interesting behavior is observed which is related to a new type of stochastic quantization. We find that the probability distribution of the ensemble of particles can be decomposed into eigenfunctions associated to a discrete spectrum of eigenvalues. In absence of interactions between the particles, the out-of-equilibrium dynamics asymptotically relaxes towards the fundamental state. This phenomenon can be related with the Fisher theorem in biology. On the contrary, in presence of scattering processes the evolution reaches a steady state in which the distribution of the ensemble of particles is characterized by a Bose-Einstein statistics. In order to show a concrete example of this stochastic quantization we have solved explicitly the case in which the potential energy has the ...
2010-01-01
Synthesis, crystal structure and nonlinear optical property of Rb3V5O14
International Nuclear Information System (INIS)
The new nonlinear optical crystal Rb3V5O14 has been synthesized by solid state reaction and characterized by single-crystal X-ray diffraction, IR and thermogravimetric analysis. The crystal Rb3V5O14 crystallizes in the trigonal system with space P31m (No. 157), a=b=8.7134(12) A, c=5.2807(11) A and ?=90o, ?=90o, ?=120o, Z=1, ?=3.516 g/cm3. It is a layered structure that is very flat and strongly parallel to c. The V5O14 layer structure consists of corner-linked square and triangular pyramids. The layers are separated by Rb+ ions, which fit equally well on the V5O14 layer. The Kurtz powder SHG measurement, using 1064 nm radiation, showed that the second-harmonic generation efficiency of Rb3V5O14 is about two times that of KDP. -- Graphical abstract: The new nonlinear optical crystal Rb3V5O14 has been synthesized by solid state reaction and characterized by single-crystal X-ray diffraction, IR and thermogravimetric analysis. The crystal Rb3V5O14 crystallizes in the ...
2010-12-01
Smith-Purcell radiation in the highly relativistic regime
International Nuclear Information System (INIS)
An electron moving over the surface of a diffraction grating will transfer a part of its kinetic energy to radiation via a velocity synchronous coupling with a slow space harmonic component of the field. Since the phase velocity of a slow space harmonic is less than the speed of light, the slow components decay exponentially, or evanesce, with distance above the grating and the evanescence scale is determined by the product of the relative velocity, #beta#, the relative energy, #gamma#, and the wavelength #lambda#. Thus, in the relativistic regime, good electron - grating coupling can be maintained at beam heights that are greater than the emitted wavelength. In order to explore this regime a series of experiments have been carried out with moderately energetic beams and an experiment with the 70-MeV beam at the Accelerator Test Facility is in the planning stage. The work has two basic goals: the first is to explore the characteristics of the ...
1995-08-21
Energy Technology Data Exchange (ETDEWEB)
To heighten durability and safety of materials/parts for undersea oil drilling, the development of ceramic base materials was made by developing function harmony type process technology which harmonizes on a high grade contrary characteristics and various functions. The paper summed up the fiscal 1997 results. In the design of system formation, computational simulation technology was developed to the composite process and the diploid system. The development of multifunction simultaneous manifestation materials was trially made by the higher nano structure process. A study was made of control of microstructures of porous materials and matrix filling by the gas phase precipitation control. Proposed were selective control of grain growth from species crystals and the columnar particle orientation laminated structure of simultaneous manifestation of strength and toughness. By composite precipitation reaction control, studied were simultaneous dispersion of whisker and ...
1998-03-01
International Nuclear Information System (INIS)
This paper presents a group's efforts to introduce national newborn screening in Lebanon. Tandem mass spectrometry (MS) technology offers the prospect of utilizing filter paper blood specimens to screen newborns for several metabolic disorders. In order to be cost-effective, it is necessary to have a mandatory newborn screening policy. At present such a policy is not available in Lebanon. A national screening survey for congenital hypothyroidism (CH) was carried out to assess the incidence of this anomaly in the Lebanese population. Such an initiative is essential as a first step for assessing the feasibility and cost of a national screening programme. Coated beads, blood spot standards for quality control and buffer solutions used for assays were prepared in-house to minimize costs. At first, samples of umbilical cord blood spots were assayed for TSH using IRMA technique. Those samples showing borderline or high values of TSH were then assayed for total T4 (TT4) ...
2004-10-01
Screening for congenital hypothyroidism in Lebanon
International Nuclear Information System (INIS)
Full text.National programs of neonatal screening were introduced in most countries and have proved their effectiveness against different types of retardation in children. Congenital hypothyroidism is one of the most common causes of physical and mental retardation in children. Programs of screening have shown that the incidence of this disorder is ethnic-background: it is low in Africans: 1-32000 whereas it is 1-3500 and 1-5000 in Hispanic and European newborns respectively. No previous mass screening programs were done in Lebanon. For this purpose, this program was introduced in collaboration with the IAEA. Cord blood is spotted into circles on filter paper just after delivery. These samples are air-dried at room temperature and kept at 4 degree C. They are then collected from hospitals to be screened. In the laboratory, all samples are assayed for IRMA TSH first. Those showing high or borderline TSH level (20mU/L) are then assayed for RIA TT4. Only those showing straight forward ...
1999-11-02
Energy Technology Data Exchange (ETDEWEB)
Two geochemical surveys were conducted in 1992 and 2000 respectively in the Yimeng Uplift of the Ordos Basin, China. The earlier survey grid had 1 x 5km spacing and the later survey grid had 0.5 x 0.5km spacing. The acid-extractable hydrocarbons of both surveys show similar geochemical trends. However, the anomalies obtained with traditional statistical methods do not correlate with existing oil/gas fields. This study reveals two problems in the data and their processing. The first one is interference caused by the variation of soil composition. We applied a wavelet-analysis-based method to eliminate this interference in the data of the later survey. The second is that micro-seepage anomalies did not identify existing oil/gas fields and seepage anomalies related with faults had not been previously recognized. We modified the logic multiplication cluster analysis and applied a multi-fractal model and a back propagation artificial neural network to recognize these two types of anomalies ...
2006-06-15
This study is a contribution to the growing body of work on the influence of changes in the composition of an acrylic bone cement on various properties of the curing and cured material. The focus is on one commercially-available acrylic bone cement brand, Surgical Simplex P, and three variants of it and a series of properties, namely, setting time, maximum exotherm temperature, activation energy and frequency factor for the polymerization reaction, diffusion coefficient for the uptake of phosphate buffered saline, at 37 degrees C, ultimate compressive strength (UCS), plane-strain fracture toughness, fatigue life (under fully-reversed tension-compression stress), hardness (H) and elastic modulus (both determined using quasi-static nanoindentation), and the variation of the storage and loss moduli with frequency of the applied force in a dynamic nanoindentation test. It was found that (a) a 68% reduction in the volume of the activator, N,N dimethyl-4-toluidine, relative to the total ...
2007-05-05
Energy Technology Data Exchange (ETDEWEB)
Partially purified UDPgalactosyltransferase (EC 2.4.1.22) from bovine milk has been used to synthesize millimolar amounts of compounds such as Gal..beta..(1..-->..4)Glc, Gal..beta..(1..-->..4)GlcNAc-..beta..-hexanolamine, and Gal..beta..(1..-->..4)-GlcNAc..beta..(1..-->..4)GlcNAc. The same method has been used to prepare similar compounds containing /sup 13/C-enriched galactopyranosyl moieties. Gal..beta..(1..-->..4)GlcNAc-..beta..-hexanolamine was also synthesized in a solid-phase system in which the GlcNAc-..beta..-hexanolamine glycoside was covalently linked to agarose beads. At pH 7.0 and at 1 to 5 mM Mn/sup 2 + +/ the yields of the galactosyl saccharides are greater than 90% by using 10% excess of UDPGal donor. The use of a 90% enriched (1-/sup 13/C)galactosyl residue allowed the determination of the most abundant conformer about the galactopyranosyl-glycoside linkage by analysis of the carbon-carbon coupling constants from Cl to Gal to the ...
1980-02-05
CHEMICAL TECHNOLOGY DIVISION, UNIT OPERATIONS SECTION MONTHLY PROGRESS REPORT, JULY 1960
A critical review of the literature revealed no experiments on uranyl ion transfer from an aqueous to a tributyl phosphate phase which positively measured the kinetics of the chemical reaction at the interphase. Drawing isorhythmic lines on a three component diagram gives a complex correlation for the compaction of three sizes of glass beads. Neither the use of thoria sols nor high feed solution concentrations of thorium nitrate gave any significant increase in mean particle diameters over those obtained from nitrate solutions of lower concentrations in flame denitration. A hydraulic film resistance has been detected in the anion exchange of uranyl sulfate into Dowex 2lK, and chloride elution was found to give a higher apparent uranium diffusion coefficient than nitrate elution. The rate of dissolution of mixed thorium-uranium oxides was determined as a function of the per cent of mixed oxides dissolved. Mixing in tanks packed with ...
1960-10-27
Energy Technology Data Exchange (ETDEWEB)
Particle shape is an important parameter in numerous civil, environmental, and petroleum engineering applications. In ground-water flow, the shape of individual particles comprising the soil affects the soil`s pore size distribution and, hence, the important flow characteristics such as hydraulic conductivity and headloss. A model for delineating the relative importance of particle size, particle shape, and porosity, (and their interactions), in explaining the variability of hydraulic conductivity of a granular porous medium is developed and tested. Three types of porous media are considered in this work: spherical glass beads; granular sand; and irregularly shaped, shredded glass particles. A reliable method for quantifying the three-dimensional shape and packing of large samples of irregular particles based on their angle of repose is presented. The results of column experiments indicate that in the size range examined (i.e., 149 {micro}m to 2,380 {micro}m), the ...
1995-11-01
Z-relation and homometry in musical distributions
British Library Electronic Table of Contents (United Kingdom)
This paper defines homometry in the rather general case of locally-compact topological groups, and proposes new cases of its musical use. For several decades, homometry has raised interest in computational musicology and especially set-theoretical methods, and in an independent way and with different vocabulary in crystallography and other scientific areas. The link between these two approaches was only made recently, suggesting new interesting musical applications and opening new theoretical problems. We present some old and new results on homometry, and give perspective on future research assisted by computational methods. We assume from the reader's basic knowledge of groups, topological groups, group algebras, group actions, Lebesgue integration, convolution products, and Fourier trans...
2011-01-01
Thermal and mechanical properties of poly(vinyl alcohol) plasticized with glycerol
British Library Electronic Table of Contents (United Kingdom)
Abstract Thermomechanical behavior of membranes based on blends of poly(vinyl alcohol) (PVA) with different weight percentage (wt %) of glycerol has been studied. Solid-state PVA/Glycerol polymer membranes were prepared by a solution casting method. The films were studied for thermal characteristics by differential scanning calorimetry (DSC) and thermogravimetric analysis and for the mechanical properties including hardness and modulus by nanoindentation method. The dispersion of glycerol within the polymer matrix was examined using scanning electron microscopy. Fourier transform infrared spectroscopy was used to confirm the formation of hydrogen bonding between the plasticizer and PVA in their blends and also to provide information on compatibility and physical interactions between the gl...
2011-01-01
We formulate a complete theory of Edge Radiation based on a novel method relying on Fourier Optics techniques. Similar types of radiation like Transition Undulator Radiation are addressed in the framework of the same formalism. Special attention is payed in discussing the validity of approximations upon which the theory is built. Our study makes consistent use of both similarity techniques and comparisons with numerical results from simulation. We discuss both near and far zone. Physical understanding of many asymptotes is discussed. Based on the solution of the field equation with a tensor Green's function technique, we also discuss an analytical model to describe the presence of a vacuum chamber. In particular, explicit calculations for a circular vacuum chamber are reported. Finally, we consider the use of Edge Radiation as a tool for electron beam diagnostics. We discuss Coherent Edge Radiation, Extraction of Edge Radiation by a mirror, and other issues ...
2008-01-01
The Advanced Loose Parts Monitoring System (ALPS) and wavelet analysis
International Nuclear Information System (INIS)
The Advanced Loose Parts monitoring System (ALPS), is installed in each Unit of Paks NPP. Its characteristics and some interesting results are presented. Wavelet analysis is being introduced to data evaluation techniques. The short-time Fourier transform and the continuous wavelet transform techniques have been used to present the time signal in a time-frequency and time-scale plane. Characteristic frequencies of the physical acoustic system and the growing frequencies of spectrum components during the start-up of the main coolant pumps are clearly seen on those pictures. The newly applied wavelet coherence promises to find new oscillation in the pair of signals, which remain hidden in time-dependent autospectra. (author)
Synthesis and characterization of Fe3O4Gg nanocomposites and their antibacterial performance
British Library Electronic Table of Contents (United Kingdom)
We synthesized Fe3O4Gg nanocomposites through a combination of solvothermal, hydrothermal, and chemical redox reactions. Characterization of the resulting samples by X-ray diffraction, Fourier-transform infrared spectroscopy, field-emission scanning and transmission electron microscopy, and magnetic measurement is reported. Compared to Fe3O4g nanocomposites, the Fe3O4Gg nanocomposites showed enhanced antibacterial activity. The Fe3O4Gg nanocomposites were able to almost entirely prevent growth of Escherichia coli when the concentration of Ag nanoparticles was 10mg/mL. Antibacterial activity of the Fe3O4Gg nanocomposites was maintained for more than 40h at 37^oC. The intermediate carbon layer not only protects magnetic core, but also improves the dispersion and antibacterial activity of the...
2011-01-01
Synthesis and characterization of Co-Ag core-shell nanoparticles
Energy Technology Data Exchange (ETDEWEB)
A micellar method has been used to prepare silver-coated cobalt (Co-Ag) nanoparticles. The synthesized particles have been deeply characterized by several methods, i.e., XRD, UV-Vis, TEM, XPS, and electrochemical techniques. There is every indication that the obtained particles show a truly core-shell structure. All the nanoparticles obtained under different conditions are in the size range 3-5 nm. High-resolution TEM (HRTEM), Fast Fourier Transformation (FFT), and Selected Area Electron Diffraction (SAED) indicated that the presence of hcp-Co and fcc-Ag, in which cobalt is located in the central area; meanwhile silver is at the edges of the nanoparticle. The absorption band of the Co-Ag colloid shifts to a longer wavelength and broadens relative to that of pure silver colloid. Voltammetric characterization allowed to determine the coverage of the cobalt core.
2010-08-15
Submegahertz linewidth at 240 GHz from an injection-locked free-electron laser
International Nuclear Information System (INIS)
Radiation from an ultrastable 240 GHz solid state source has been injected, through an isolator, into the cavity of the University of California, Santa Barbara millimeter-wave free-electron laser (FEL). High-power FEL emission, normally distributed among many of the cavity's longitudinal modes, is concentrated into the single mode to which the solid state source has been tuned. The linewidth of the FEL emission is 0.5 MHz, consistent with the Fourier transform limit for the 2 #mu#s pulses. This demonstration of frequency-stable, ultranarrow-band FEL emission is a critical milestone on the road to FEL-based pulsed electron paramagnetic resonance spectroscopy.
2007-10-22
We investigate the existence of time-periodic solutions of the Dirac equation in the Kerr-Newman background metric. To this end, the solutions are expanded in a Fourier series with respect to the time variable $t$ and the Chandrasekhar separation ansatz is applied so that the question of existence of a time-periodic solution is reduced to the solvability of a certain coupled system of ordinary differential equations. First, we prove the already known result that there are no time-periodic solutions in the non-extreme case. Then it is shown that in the extreme case for fixed black hole data there is a sequence of particle masses $(m_N)_{N\\in\\mathbb N}$ for which a time-periodic solution of the Dirac equation does exist. The period of the solution depends only on the data of the black hole described by the Kerr-Newman metric.
2006-01-01
British Library Electronic Table of Contents (United Kingdom)
Soluble starch?based biodegradable and microporous microspheres (SDM-Ms) were prepared by emulsion chemical cross-linking technique using trisodium trimetaphosphate (TSTP) as the cross-linker. The resultant amorphous SDM-Ms were excellently identified by scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FT-IR). The internal rupture and surface-controlled erosion were the predominant degradation mechanisms for SDM-Ms. The obtained SDM-Ms were applied to adsorb coix seed oil (CSO) by immersing method. The adsorption capacity of CSO within SDM-Ms was determined, namely 0.5238?g/g, and the thermal stability was shown higher than that of the free CSO. A burst release appeared in the second hour, followed by controlled release. Diffusion, d...
2011-01-01
Simulation Studies of the X-Ray Free-Electron Laser Oscillator
Energy Technology Data Exchange (ETDEWEB)
Simulations of the x-ray free-electron laser (FEL) oscillator are presented that include transverse effects and realistic Bragg crystal properties with the two-dimensional code GINGER. In the present cases considered the radiation divergence is much narrower than the crystal acceptance, and the numerical algorithm can be simplified by ignoring the finite angular bandwidth of the crystal. In this regime GINGER shows that the saturated x-ray pulses have 109 photons and are nearly Fourier-limited with peak powers in excess of 1 MW. Wealso include preliminary results for a four-mirror cavity that can be tuned in wavelength over a few percent, with future plans to incorporate the full transverse response of the Bragg crystals into GINGER to more accurately model this tunable source.
2009-08-14
British Library Electronic Table of Contents (United Kingdom)
To elucidate biosorption mechanism and removal efficiency of plant residues as a biosorbent to abate polycyclic aromatic hydrocarbons (PAHs) in wastewater, sorption of PAHs onto wood chips (WC), ryegrass roots (RR), orange peels (OP), bamboo leaves (BL), and pine needles (PN) were investigated. The structural characterization of the biosorbents was analyzed by elemental composition, BET-N2 surface area, and Fourier transform infrared spectroscopy. PAHs sorption to the selected biosorbents were compared and correlated with their structures. Biosorption isotherms fit well with Freundlich equation and the mechanism was dominated by partition process. The magnitude of phenanthrene partition coefficients (Kd) followed the order of PN>BL>OP>RR>WC, ranged from 2484+/-24.24 to 5306+/-92.49L/kg. Ex...
2011-01-01
Propagation of pressure perturbations in bubbly air/water flows
Energy Technology Data Exchange (ETDEWEB)
The propagation of acoustic pressure perturbations in an adiabatic low-quality air/water flow were investigated both theoretically and experimentally. A linearized dispersion model is correlated with data to extract information on the behavior of interfacial momentum transfer controlled by the virtual volume coefficient. The dispersion model is examined in limiting cases of low and high frequency and related to current models for critical flow velocity. Fourier decomposition techniques are employed to predict the dispersion of measured pressure pulses and to relate data for standing waves and propagating pulses. The dispersion model is based on a two-fluid model and is the most complete model available in the literature at this time. The dispersion data presented herein is also the best available to date for low frequency (i.e., frequencies less than bubble resonance) sound propagation in bubbly air/water mixtures.
1987-01-01
Preparation and characterization of nano hydroxyapatite/polymeric composites materials. Part I
British Library Electronic Table of Contents (United Kingdom)
The present study is focused on preparation of nano composite materials and the effect of citric acid on their different properties. The formation of nano HA and its interaction with chitosan (C), gelatin (G) polymers and citric acid (CA) materials were studied. The Fourier Transformed Infrared Spectroscopy (FT-IR), X-ray diffraction (XRD), thermo-gravimetric analysis (TGA), transmission electron microscope (TEM), and scanning electron microscope (SEM) were used to characterize these composite materials. The compressive strength (CS) was also measured to know the reinforcement of the prepared composites. The results show that carboxylic and amino groups play crucial role for HA formation on chitosan-gelatin polymeric matrix in the presence of citric acid (CA). The formation of nano HA part...
2011-01-01
Preparation and Characterization of a Novel Polyamide Charged Mosaic Membrane
British Library Electronic Table of Contents (United Kingdom)
A novel composite charged mosaic membrane (CCMM) was prepared via interfacial polymerization (IP) of polyamine [poly(epichlorohydrin amine)] and trimesoyl chloride (TMC) on the polyethersulfone (PES) support. Fourier transform infrared spectroscopy (FT-IR), environmental scanning electron microscopy (ESEM), atomic force microscopy (AFM) and water contact angle analysis were applied to characterize the resulted CCMM. The FT-IR spectrum indicates that TMC reacts sufficiently with polyamine. ESEM and AFM pictures show that the IP process produces a dense selective layer on the support membrane. The water contact angle of the CCMM is smaller than that of the substrate membrane because of the cross-linked hydrophilic polyamine network. Several factors affecting the IP reaction and the performan...
2010-01-01
British Library Electronic Table of Contents (United Kingdom)
The objective of this study is to develop an artificial neural network (ANN) model to predict the thermal conductivity of ethylene glycol-water solutions based on experimentally measured variables. The thermal conductivity of solutions at different concentrations and various temperatures was measured using the cylindrical cell method that physical properties of the solution are being determined fills the annular space between two concentric cylinders. During the experiment, heat flows in the radial direction outwards through the test liquid filled in the annual gap to cooling water. In the steady state, conduction inside the cell was described by the Fourier equation in cylindrical coordinates, with boundary conditions corresponding to heat transfer between the solution and cooling water. ...
2009-01-01
British Library Electronic Table of Contents (United Kingdom)
Abstract Poly(butylene terephthalate) (PBT) composites containing multiwalled carbon nanotubes (MWCNTs) were prepared using a melt-blending process and used to examine the effects on the composite structure and properties of replacing PBT with acrylic acid-grafted PBT (PBT-g-AA). PBT-g-AA and multihydroxyl-functionalized MWCNTs (MWCNTs-OH) were used to improve the compatibility and dispersibility of the MWCNTs within the PBT matrix. The composites were characterized morphologically using transmission electron microscopy, and chemically using Fourier transform infrared, solid-state 13C NMR and UV-visible absorption spectroscopy. The antibacterial and electrical conductivity properties of the composites were also evaluated. MWCNTs or MWCNTs-OH enhanced the antibacterial activity and electric...
2011-01-01
Photoreceptor Inner and Outer Segment Defects in Myopic Foveoschisis
British Library Electronic Table of Contents (United Kingdom)
PurposeTo evaluate pathologic features of the photoreceptors in myopic foveoschisis with the Fourier-domain optical coherence tomography (FD-OCT).DesignObservational case series.MethodsSeventeen eyes of 15 patients with myopic foveoschisis (foveal detachment type, six eyes; foveoschisis type, 11 eyes) were included. We observed the photoreceptor inner and outer segments (IS/OS) and evaluated the morphologic status using FD-OCT. Fundus photographs and time-domain OCT (TD-OCT) images also were obtained.ResultsIS/OS defects, which are uncommon in retinal detachments in eyes with myopia, were seen clearly in five eyes (three eyes [50%] with the foveal detachment type; two eyes [18%] with the foveal schisis type). Fundus photographs showed myopic chorioretinal atrophy in eight study eyes (47%),...
2008-01-01
Partition Functions of Normal Factor Graphs
One of the most common types of functions in mathematics, physics, and engineering is a sum of products, sometimes called a partition function. After "normalization," a sum of products has a natural graphical representation, called a normal factor graph (NFG), in which vertices represent factors, edges represent internal variables, and half-edges represent the external variables of the partition function. In physics, so-called trace diagrams share similar features. We believe that the conceptual framework of representing sums of products as partition functions of NFGs is an important and intuitive paradigm that, surprisingly, does not seem to have been introduced explicitly in the previous factor graph literature. Of particular interest are NFG modifications that leave the partition function invariant. A simple subclass of such NFG modifications offers a unifying view of the Fourier transform, tree-based reparameterization, loop calculus, and the Legendre ...
2011-01-01
PLZT spatial light modulator for a 1-D hologram memory.
A 100-bit slitlike aperture array spatial light modulator has been developed using 8.8/65/35 PLZT for a high-bit-density 1-D hologram memory. The most desirable characteristics, such as distortion-free diffraction-limited Fourier transform patterns and good uniformity of displayed bit patterns over 100 bits, have been realized. The lowest SNR was 86, and rise time and fall time have been 30 microsec and 8 microsec, respectively, at 190-V halfwave voltage. One-dimensional holographic storage experiments have been successfully performed using this PLZT spatial light modulator. PMID:20216813
1980-01-01
Oxidation of polycaprolactone to induce compatibility with other degradable polyesters
British Library Electronic Table of Contents (United Kingdom)
Chemical modification of poly(?-caprolactone) PCL by oxidation with potassium permanganate in solution was investigated. According to the data obtained from Fourier transform infrared spectroscopy (FT-IR) and nuclear magnetic resonance 1H NMR, after the oxidation reactions the PCL chains exhibited new functional groups (vinyl and hydroxyl) and possible intermolecular recombination, producing an oxidized-polycaprolactone (PCL-OX). Solution viscometry indicated that degradation also occurred during the oxidation reactions (30% drop in viscosity average molecular weight was detected). Differential scanning calorimetry (DSC) also indicated that PCL was chemically modified and degraded. The successive self-nucleation/annealing (SSA) treatment confirmed that a reduction (or interruption) in line...
2007-01-01
Normalized noise power spectrum of full field digital mammography detector system
International Nuclear Information System (INIS)
Full text: A method to measure noise power spectrum of a full field digital mammography system is presented. The effect of X-ray radiation dose, size and configuration of region of interest on normalized noise power spectrum (NNPS) was investigated. Flat field images were acquired using RQA-M2 beam quality technique (Mo/Mo anode-filter, 28 kV, 2 mm Al) with different clinical radiation doses. The images were cropped at about 4 cm from the edge of the breast wall and then divided into different size of non-overlapping or overlapping segments. NNPS was determined through de trending, 2-D fast Fourier transformation and normalization. Our measurement shows that high radiation dose gave lower NNPS at a specific beam quality. (author)
Normalized Noise Power Spectrum of Full Field Digital Mammography System
International Nuclear Information System (INIS)
A method to measure noise power spectrum of a full field digital mammography system is presented. The effect of X-ray radiation dose, size and configuration of region of interest on normalized noise power spectrum (NNPS) was investigated. Flat field images were acquired using RQA-M2 beam quality technique (Mo/Mo anode-filter, 28 kV, 2 mm Al) with different clinical radiation doses. The images were cropped at about 4 cm from the edge of the breast wall and then divided into different size of non-overlapping or overlapping segments. NNPS was determined through detrending, 2-D fast Fourier transformation and normalization. Our measurement shows that high radiation dose gave lower NNPS at a specific beam quality.
2010-01-05
Multi walled carbon nanotubes/epilson polylysine nanocomposite with enhanced antibacterial activity
British Library Electronic Table of Contents (United Kingdom)
Abstract Aims: To develop a new nano composite of multi walled carbon nanotubes (MWNTs) with enhanced antimicrobial activity. Methods and Results: A novel antimicrobial nanocomposite [MWNT epilson polylysine (MEPs)] was synthesized via covalent attachment of epilson polylysine on MWNTs with hexamethylene diisocyanate (HDI) as the coupling agent. UV visible spectra and Fourier transform infrared spectra (FT IR) investigations indicate that MEPs is stable, with epilson polylysine leaching effectively eliminated. When compared to MWNTs, the new nano composite MEPs exhibits enhanced antimicrobial activities. In 20 mg l 1 suspensions, significant increases of 72 1, 64 5 and 69% against Escherichia coli, Pseudomonas aeruginosa and Staphylococcus aureus can be observed. The deposited film of MEPs...
2011-01-01
British Library Electronic Table of Contents (United Kingdom)
Polypyrrole (PPy) was prepared from different mixed-surfactant solutions with ammonium persulfate as an oxidant. Three types of combinations were selected, including cationic/anionic, cationic/nonionic, and anionic/nonionic mixed-surfactant solutions. The surfactants used in the experiments included cetyltrimethylammonium bromide (cationic surfactant), sodium dodecyl sulfate (anionic surfactant), sodium dodecyl sulfonic acid salt (anionic surfactant), poly(vinyl pyrrolidone) (nonionic surfactant), and poly(ethylene glycol) (nonionic surfactant). The morphology, structure, and conductivity of the resulting PPy were investigated in detail with scanning electron microscopy, Fourier transform infrared spectra, and the typical four-probe method, respectively. The results showed that the interac...
2007-01-01
Molecular structure of platinum(III) hydroxoacetates according to data from EXAFS spectra
Energy Technology Data Exchange (ETDEWEB)
The EXAFS spectra of the platinum(III) complexes Pt/sub 4/(OAc)/sub 10/(OH)/sub 2/ (I) and Pt/sub 4/ (OAc)/sub 4/(OH)/sub 8/(H/sub 2/O)/sub 2/ (II) have been investigated. It has been found by a curve-fitting method and with the aid of Fourier transformations that the shortest Pt-Pt distances are 2.61 A in complex I and 2.36 and 2.6 A in II. The values of the bond lengths obtained are consistent with the molecular structures proposed for complexes I and II, which contain skeletons of four platinum atoms in the form of a square or a rectangle, as well as with the known literature data on the lengths of Pt-Pt bonds in Pt(III) complexes.
1986-04-01
Mode shape and natural frequency identification for seismic analysis from background vibration
International Nuclear Information System (INIS)
Background vibration in a CANDU plant can be used to determine the dynamic characteristics of major items of equipment, such as calandria, the fuelling machines and the primary heat transport pumps. These dynamic characteristics can then be used to verify the seismic response of the equipment which, at present, is based on theoretical models only. The feasibility and basic theory of this new approach (which uses accelerations measured at several points on a structure and does not require knowledge of the source of excitation) was established in Phase I of the study. This report is based on Phase II in which the methods of analysis developed in Phase I were improved and verified experimentally. A Fast Fourier Transform (FFT) algorithm was incorporated and an interactive curve fitting technique was developed to obtain the dynamic characteristics in the form of natural frequencies, mode shapes and damping ratios. The method is now available for use at a CANDU plant.
1984-02-06
Miscibility enhancement of PP/PBT blends with a side-chain liquid crystalline ionomer
British Library Electronic Table of Contents (United Kingdom)
Side-chain liquid crystalline ionomer (SLCI) containing sulfonic acid groups with a polymethylhydrosiloxane main-chain was used in the blends of polypropylene (PP) and polybutylene terephthalate (PBT) as a compatibilizer. The crystalline behavior, morphological, and mechanical properties of the blends were investigated in detail by differential scanning calorimetry (DSC), polarizing optical microscope (POM), Fourier transforms infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). Revealed by the shift of Tm in DSC thermogram and the shift of the absorbed peak in FTIR spectra, specific interaction led to stronger interfacial adhesion between these phases, which resulted in much finer dispersion of the minor PBT phase in PP matrix. The SLCI containing sulfonate acid groups ac...
2009-01-01
Microstructure analysis of nanocrystalline powders by X-ray diffraction
International Nuclear Information System (INIS)
The use of X-ray diffraction line profile analysis for the study of nanocrystalline powders is described. The fundamentals of the theory are presented in terms of crystallite/domain size, size distribution, lattice distortion, dislocations density and stacking faults. Line profile parameters and the methods of pattern fitting introduced to overcome the diffraction-line overlap problem are discussed. The approaches based of the integral breadth of the measured line profiles and the Fourier method are discussed. In addition, simplified approaches are also commented. Representative examples are selected to illustrate various cases of microstructure, such as nanomaterials with strain-free spherical nano crystallites, strain-free crystallites with anisotropic crystallite shape, anisotropic crystallites with microstrains and spherical crystallites with dislocation densities and crystallite size distributions. (author)
2001-09-23
Layered double hydroxide as novel antibacterial drug delivery system
British Library Electronic Table of Contents (United Kingdom)
The cephalosporin class antibacterial agent, cefazolin, was intercalated into layered double hydroxides (LDHs) in order to improve the drug efficiency as well as to achieve the controlled release property. Cefazolin molecules were incorporated into LDH through conventional ion exchange reaction. X-ray diffraction pattern analyses confirmed that cefazolin molecules were intercalated between the interlayer spaces of LDH. Fourier-transform infrared spectra and high performance liquid chromatographs clearly showed that the drug molecules were stabilized in LDH lattice through electrostatic interaction and released without any changes in their chemical integrity. Antibacterial activity of the cefazolin-LDH nanohybrid was also examined by an in vitro test, such as the minimal inhibitory concentr...
2010-01-01
Kramers-Kronig Analysis of Infrared Reflectance Spectra for Quaternary In_xAl_yGa_1_-_x_-_yN Alloy
International Nuclear Information System (INIS)
In this paper, a Kramers-Kronig (KK) analysis of infrared (IR) reflectance spectrum of quaternary In_0_._0_1Al_0_._0_6Ga_0_._9_3N film grown by molecular beam epitaxy (MBE) is reported. The infrared measurement is performed in the reflection mode at an incident angle of 15 degree sign by Fourier transform infrared (FTIR) spectroscopy at T = 300 K. The Kramers-Kronig analysis of the reflectivity data has been used to obtain the real and imaginary parts of the index of refraction (n and k), and the real and imaginary parts of the dielectric response function (#epsilon#' and #epsilon#') of the materials. Finally, the transverse optical and longitudinal optical phonons for quaternary In_xAl_yGa_1_-_x_-_yN were obtained.
2010-07-07
Impedance Noise Identification for State-of-Health Prognostics
Energy Technology Data Exchange (ETDEWEB)
Impedance Noise Identification is an in-situ method of measuring battery impedance as a function of frequency using a random small signal noise excitation source. Through a series of auto- and cross-correlations and Fast Fourier Transforms, the battery complex impedance as a function of frequency can be determined. The results are similar to those measured under a lab-scale electrochemical impedance spectroscopy measurement. The lab-scale measurements have been shown to correlate well with resistance and power data that are typically used to ascertain the remaining life of a battery. To this end, the Impedance Noise Identification system is designed to acquire the same type of data as an on-board tool. A prototype system is now under development, and results are being compared to standardized measurement techniques such as electrochemical impedance spectroscopy. A brief description of the Impedance Noise Identification hardware system and representative test ...
2008-07-01
British Library Electronic Table of Contents (United Kingdom)
The enzyme TEM1-b-lactamase has been used as a model to study the impact of different cultivation and induction regimes on the structure of cytosolic inclusion bodies (IBs). The protein has been heterologously expressed in Escherichia coli in fed-batch cultivations at different temperatures (30, 37, and 40degreeC) as well as induction regimes that guaranteed distinct product formation rates and ratios of soluble to aggregated protein. Additionally, shake flask cultivations at 20, 30, and 37degreeC were performed. IBs were sampled during the whole bioprocess and structural analysis was performed by attenuated total reflectance Fourier transform infrared (ATR-FT-IR) spectroscopy. This work clearly demonstrates that the tested production regimes and rates had no impact on the IB structure, wh...
2008-01-01
High-throughput proteomics of breast carcinoma cells: a focus on FTICR-MS
Energy Technology Data Exchange (ETDEWEB)
Discovery of better biomarkers for diagnosis, prognosis, and therapy-response prediction is the most critical task of a scientific quest aimed at developing newly designed, tailor-made therapies for patients with cancer. Consequently, a proteome wide analysis, in addition to genomic studies, is an absolute requirement for a complete functional understanding of tumor biology. Ultra-sensitive, high-performance Fourier transform ion cyclotron resonance (FTICR) mass spectrometry (MS) currently holds an important role in fulfilling the demands of biomarker discovery. In this review, we describe the applicability of FTICR MS for breast cancer proteomics, particularly for the analysis of complex protein mixtures obtained from a limited number of cells typically available from clinical specimens.
2008-06-05
High channel density wavelength division multiplexer with defined diffracting means positioning
Energy Technology Data Exchange (ETDEWEB)
A wavelength division multiplexer/demultiplexer having optical path lengths between a fiber array and a Fourier transform lens, and between a dispersion grating and the lens equal to the focal length of the lens. The optical path lengths reduce losses due to angular acceptance mismatch in the multiplexer. Close orientation of the fiber array about the optical axis and the use of a holographic dispersion grating reduces other losses in the system. Multi-exposure holographic dispersion gratings enable the multiplexer/demultiplexer for extremely broad-band simultaneous transmission and reflection operation. Individual Bragg plane sets recorded in the grating are dedicated to and operate efficiently on discrete wavelength ranges.
1990-01-01
Energy Technology Data Exchange (ETDEWEB)
The transmission of electrical energy by use of underground cables is increasing. Fault location techniques have certain limitations; incipient fault detection and location would help reduce the maintenance cost of these lines as well as improve the reliability of service. The report discusses some test results related to RF-probing techniques applied to high-voltage transmission lines. The high-frequency losses and attenuation in high-voltage cables places certain ultimate limitations on RF-probing techniques for incipient fault detection. Time-domain reflectrometry methods were employed to assess the RF-transmission properties of high-voltage cables at frequencies as high as 6 GHz. Fast-Fourier-transform deconvolution was used to obtain loss measurements as a function of frequency. The loss mechanisms were identified. The measurement hardware and methods are discussed as well as analysis approach leading to the conclusions.
1986-04-01
Ferrihydrite phase transformation in the presence of aqueous sulfide and supercritical CO2
British Library Electronic Table of Contents (United Kingdom)
The transformation of ferrihydrite to siderite (FeCO3) in the presence of supercritical CO2 (scCO2) and aqueous sulfide has been investigated by in situ attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) and ex situ X-ray diffraction (XRD). The chemical transformation of iron-bearing minerals to form iron carbonates may play a role in the chemistry related to the geological sequestration of carbon dioxide in the Earth's (sub)surface. The iron oxyhydroxide ferrihydrite in an aqueous solution containing sodium sulfide in contact with scCO2 at 100^oC reacts within 24h to form siderite and elemental sulfur. In situ studies of this reaction with ATR-FTIR show that ferrihydrite exists with an adsorbed layer of carbonate. However, the presence of the carbonate adsorbat...
2010-01-01
Evidence for a supermassive black hole in the nucleus of M31
International Nuclear Information System (INIS)
Stellar rotation velocities and velocity dispersions along three slit positions in M31 have been measured, and three-dimensional velocity and velocity dispersion fields are obtained in order to search for a central black hole. Synthetic apparent spectra are constructed to eliminate problems with the reaction of the Fourier quotient program to stellar population mixes. Models are constructed to explore parameter space. The large velocities and velocity gradients that are found imply that the total mass-to-light ratio rises sharply at r of 0.5 arcsec or less to values greater than 100. This is much larger than normal for old stellar populations. Velocity anisotropies are not a major uncertainty because of the rapid rotation. There is thus strong evidence for a dark central mass, probably a supermassive black hole. 48 references.
International Nuclear Information System (INIS)
Irradiation processing of food in the prepackaged form may affect chemical and physical properties of the plastic packaging materials. The effect of #gamma#-irradiation doses (2.5-10.0 kGy) on polypropylene (PP)-based retortable food packaging materials, were investigated using Fourier transform infrared (FTIR) spectroscopic analysis, which revealed the changes happening to these materials after irradiation. The mechanical properties decreased with irradiation while oxygen transmission rate (OTR) was not affected significantly. Colour measurement indicated that Nylon 6 containing multilayer films became yellowish after irradiation. Thermal characterization revealed the changes in percentage crystallinity.
2007-07-01
International Nuclear Information System (INIS)
The intensity of superstructure reflections and associated diffuse scattering from In_0_._5Ga_0_._5P and In_0_._5Al_0_._5P epitaxic layers grown on (001) GaAs substrates was mapped in reciprocal space. The Warren-Cowley short-range-order parameters were obtained through the usual process for evaluating Fourier coefficients. Varying values for the correlation length in different directions indicate how group III atoms stack up in ordered states. The resultant structure with long-range order confirms the hypothesis made on the basis of electron diffraction and high-resolution transmission electron microscopy studies. (orig.).
British Library Electronic Table of Contents (United Kingdom)
This work reports a systematic comparative study of the technological properties of natural lattices and rubbers extracted from Hancornia speciosa Gomes and Hevea brasiliensis [(Willd. ex Adr. de Juss.) Muell.-Arg.] (clone RRIM 600) trees from 11 collections in Brazil throughout 2004. Natural rubber latex particle sizes and distributions were quite similar with an average diameter around 1 mm. Molecular weight, Wallace plasticity, and Mooney viscosity values were approximately the same for both rubbers. Fourier transform infrared spectroscopy peaks characteristic of natural rubber were observed for both Hancornia and Hevea. The measured differences in technological properties included lower values for Hancornia dry rubber content, % ash, % nitrogen, and plasticity retention index but highe...
2009-01-01
Chemistry between crosslinks affects the properties of peptide hydrogels
British Library Electronic Table of Contents (United Kingdom)
Protein hydrogels were prepared by substituting ovalbumin with different concentrations of ethyl vinyl sulfone (EVS) or acrylic acid (AA) and crosslinking with divinyl sulfone (DVS). Fourier transform-infrared (FT-IR) spectroscopic studies confirmed the addition of EVS, AA, and DVS onto the protein. Swelling was assessed as a function of pH in the range of 2.5 to 9.4 and ionic strength. The elastic modulus of the gels was determined in shear and compression. Stress relaxation was assessed in compression. The substituent highly affected swelling and modulus with both hydrogels displaying non-Gaussian behavior in the range of hydrogel environments studied. Acrylic acid substituted ovalbumin exhibited a decreasing modulus with increasing swelling behaving as a polyelectrolyte with low added s...
2011-01-01
British Library Electronic Table of Contents (United Kingdom)
SBA-15 supported nano-scaled copper oxide was synthesized by impregnation method via ultrasonic-assisted route. The removal test from gas mixture containing 0.1?vol.% hydrogen sulfide was carried out over this material at atmospheric conditions. The effects of the chemical nature of copper oxide and the textural properties of the material on removal capacity were studied. The materials before and after the removal test were analyzed by nitrogen adsorption, X-ray diffraction, Transmission Electron Microscope, X-ray photoelectron Spectroscopy, Fourier Transform Infrared Spectrometer and Inductive Coupled Plasma. The results showed that copper species are located predominantly in mesopore channels, existing as copper oxide nanoparticles. Mesopores are active sites for removal reaction. The ou...
2011-01-01
Biosorption of reactive dye by waste biomass of Nostoc linckia
British Library Electronic Table of Contents (United Kingdom)
Potential of spent biomass of a cyanobacterium, Nostoc linckia HA 46, from a hydrogen bioreactor was studied for biosorption of a textile dye, reactive red 198. The waste biomass was immobilized in calcium alginate and used for biosorption of the dye from aqueous solution using response surface methodology (RSM). Kinetics of the dye in aqueous solution was studied in batch mode. Interactive effects of initial dye concentration (100-500mg/L), pH (2-6) and temperature (25-45^oC) on dye removal were examined using Box-Behnken design. Maximum adsorption capacity of the immobilized biomass was 93.5mg/g at pH 2.0, initial concentration of 100mg/L and 35^oC temperature, when 94% of the dye was removed. Fourier transform infrared (FT-IR) studies revealed that biosorption was mainly mediated by fun...
2011-01-01
Banana peel extract mediated novel route for the synthesis of palladium nanoparticles
British Library Electronic Table of Contents (United Kingdom)
Bio-inspired palladium nanoparticles were synthesized by using banana peel extract (BPE), a non-toxic eco-friendly material. Boiled, crushed, acetone precipitated, air-dried peel powder was used to reduce palladium chloride. The palladium nanoparticles were characterized by using UV-Visible spectroscopy, scanning electron microscope-energy dispersive spectra (SEM-EDS) and X-ray diffraction (XRD) analysis. Dynamic light scattering (DLS) studies revealed the average size of nanoparticles to be 50nm. Fourier transform infra red spectroscopy (FTIR) implicated the role of carboxyl, amine and hydroxyl groups in the synthetic process. This paper thus describes a novel green method for the synthesis of palladium nanoparticles.
2010-01-01
A study of reconstruction algorithms and filters for an industrial X-ray tomography system
Energy Technology Data Exchange (ETDEWEB)
Computed tomography (CT) has been incorporated in an industrial Diode-Array Digital Radiography (DADR) system. An input data size of 512 pixel points x 400 projections yielded a 400x400 output image matrix. Reconstruction algorithms used are the filtered backprojection (FBP) and the direct Fourier reconstruction (DFR). Various filters were used in the FBP reconstruction process and their effects on image quality were evaluated. A spatial resolution of 100 {mu}m was measured with a block of plates and a minimum detectable feature size in the range of 10-100 {mu}m was measured using thin wires. Industrial specimens imaged have included ceramic samples, ball bearings and integrated circuits. A number of engineering problems have been solved, such as adjustment of the X-ray source, centering of the rotator spindle in the view field and beam-hardening corrections. (orig.).
1990-12-20
A Laplacian approach to multi-oriented text detection in video.
In this paper, we propose a method based on the Laplacian in the frequency domain for video text detection. Unlike many other approaches which assume that text is horizontally-oriented, our method is able to handle text of arbitrary orientation. The input image is first filtered with Fourier-Laplacian. K-means clustering is then used to identify candidate text regions based on the maximum difference. The skeleton of each connected component helps to separate the different text strings from each other. Finally, text string straightness and edge density are used for false positive elimination. Experimental results show that the proposed method is able to handle graphics text and scene text of both horizontal and nonhorizontal orientation. PMID:20733217
2011-02-01
Energy Technology Data Exchange (ETDEWEB)
Fourier transform infrared absorption spectroscopy has been used for the determination of the line strengths of 41 CO and CO[sub 2] absorption lines at temperatures between 295 and 1250 K. The CO vibrational-rotational lines were from the [ital P] branch of the fundamental absorption band (2150--1950 cm[sup [minus]1]) while the CO[sub 2] vibrational-rotational lines were from the far wing of the [ital R] branch of the [nu][sub 3] fundamental band (2395--2380 cm[sup [minus]1]). The intensities of the lines were measured from absorption spectra recorded in a high-temperature gas cell containing known concentrations of CO/CO[sub 2]/N[sub 2] gas mixtures at atmospheric pressure. Absorption spectra were recorded through the cell with the use of a moderate-resolution Fourier transform infrared spectrometer. The absorption spectra were mathematically corrected for distortions resulting from the finite resolution of the spectrometer and for peak ...
1994-11-01
International Nuclear Information System (INIS)
Fourier transform infrared absorption spectroscopy has been used for the determination of the line strengths of 41 CO and CO_2 absorption lines at temperatures between 295 and 1250 K. The CO vibrational-rotational lines were from the P branch of the fundamental absorption band (2150--1950 cm"-"1) while the CO_2 vibrational-rotational lines were from the far wing of the R branch of the #nu#_3 fundamental band (2395--2380 cm"-"1). The intensities of the lines were measured from absorption spectra recorded in a high-temperature gas cell containing known concentrations of CO/CO_2/N_2 gas mixtures at atmospheric pressure. Absorption spectra were recorded through the cell with the use of a moderate-resolution Fourier transform infrared spectrometer. The absorption spectra were mathematically corrected for distortions resulting from the finite resolution of the spectrometer and for peak overlap. Line strength measurements were made from the corrected ...
3D Fourier synthesis of a new X-ray picture identical in projection to a previous picture
Energy Technology Data Exchange (ETDEWEB)
A central problem in diagnostic radiology is to compare a new X-ray picture with a previous picture and from this comparison be able to decide if anatomical changes have occurred in the patient or not. It is of primary interest that these pictures are identical in projection. If not it is difficult to decide with confidence if differences between the pictures are due to anatomical changes or differences in their projection geometry. In this thesis we present a non invasive method that makes it possible to find the relative changes in the projection geometry between the exposure of a previous picture and a new picture. The method presented is based on the projection slice theorem (central section theorem). Instead of an elaborate search for a single new picture a pre-planned set of pictures are exposed from a circular orbit above the patient. By using 3D Fourier transform techniques we are able to synthesize a new X-ray picture from this set of pictures that is ...
1993-11-01
Energy Technology Data Exchange (ETDEWEB)
This paper presents a technique for speed control three-phase induction motor using the pulse width modulation (PWM), in open loop while maintaining the tension for constant frequency. The technique is adapted from a thesis entitled 'Control of the three-phase induction motor, using discrete PWM generation, optimized and synchronized', where studies are presented aimed at their application in home appliances, to eliminate mechanical parts, replaced by low cost electronic control, thus having a significant reduction in power consumption. Initially the experiment was done with the Intel 80C31 micro controller. In this paper, the PWM modulation is implemented using a PIC micro controller, and the speed control kept a low profile, based on tables, synchronized with transitions and reduced generation of harmonics in the network. Confirmations were made using the same process of building tables, but takes advantage of the program of a RISC device.
2009-07-01
Validation of the 3D finite element transport theory code EVENT for shielding applications
Energy Technology Data Exchange (ETDEWEB)
This paper is concerned with the validation of the 3D deterministic neutral-particle transport theory code EVENT for shielding applications. The code is based on the finite element-spherical harmonics (FE-P{sub N}) method which has been extensively developed over the last decade. A general multi-group, anisotropic scattering formalism enables the code to address realistic steady state and time dependent, multi-dimensional coupled neutron/gamma radiation transport problems involving high scattering and deep penetration alike. The powerful geometrical flexibility and competitive computational effort makes the code an attractive tool for shielding applications. In recognition of this, EVENT is currently in the process of being adopted by the UK nuclear industry. The theory behind EVENT is described and its numerical implementation is outlined. Numerical results obtained by the code are compared with predictions of the Monte Carlo code MCBEND and also with the results ...
2000-03-01
The quantum N-body problem with a minimal length
The quantum $N$-body problem is studied in the context of nonrelativistic quantum mechanics with a one-dimensional deformed Heisenberg algebra of the form $[\\hat x,\\hat p]=i(1+\\beta \\hat p^2)$, leading to the existence of a minimal observable length $\\sqrt\\beta$. For a generic pairwise interaction potential, analytical formulas are obtained that allow to estimate the ground-state energy of the $N$-body system by finding the ground-state energy of a corresponding two-body problem. It is first shown that, in the harmonic oscillator case, the $\\beta$-dependent term grows faster with $N$ than the $\\beta$-independent one. Then, it is argued that such a behavior should be observed also with generic potentials and for $D$-dimensional systems. In consequence, quantum $N$-body bound states might be interesting places to look at nontrivial manifestations of a minimal length since, the more particles are present, the more the system deviates from standard quantum ...
2010-01-01
The mixmaster universe in Horava-Lifshitz gravity
Energy Technology Data Exchange (ETDEWEB)
We consider spatially homogeneous (but generally non-isotropic) cosmologies in the recently proposed Horava-Lifshitz gravity and compare them to those of general relativity using Hamiltonian methods. In all cases, the problem is described by an effective point particle moving in a potential well with exponentially steep walls. Focusing on the closed-space cosmological model (Bianchi type IX), the mixmaster dynamics is now completely dominated by the quadratic Cotton tensor potential term for a very small volume of the universe. Unlike general relativity, where the evolution toward the initial singularity always exhibits chaotic behavior with alternating Kasner epochs, the anisotropic universe in Horava-Lifshitz gravity (with parameter lambda > 1/3) is described by a particle moving in a frozen potential well with fixed (but arbitrary) energy E. Alternating Kasner epochs still provide a good description of the early universe for very large E, but the evolution appears to be ...
2010-02-21
The mixmaster universe in Horava-Lifshitz gravity
International Nuclear Information System (INIS)
We consider spatially homogeneous (but generally non-isotropic) cosmologies in the recently proposed Horava-Lifshitz gravity and compare them to those of general relativity using Hamiltonian methods. In all cases, the problem is described by an effective point particle moving in a potential well with exponentially steep walls. Focusing on the closed-space cosmological model (Bianchi type IX), the mixmaster dynamics is now completely dominated by the quadratic Cotton tensor potential term for a very small volume of the universe. Unlike general relativity, where the evolution toward the initial singularity always exhibits chaotic behavior with alternating Kasner epochs, the anisotropic universe in Horava-Lifshitz gravity (with parameter #lambda# > 1/3) is described by a particle moving in a frozen potential well with fixed (but arbitrary) energy E. Alternating Kasner epochs still provide a good description of the early universe for very large E, but the evolution appears to be ...
2010-02-21
Spontaneous Radiation Emission from Short, High Field Strength Insertion Devices
Energy Technology Data Exchange (ETDEWEB)
Since the earliest papers on undulaters were published, it has been known how to calculate the spontaneous emission spectrum from ''short'' undulaters when the magnetic field strength parameter is small compared to unity, or in ''single'' frequency sinusoidal undulaters where the magnetic field strength parameter is comparable to or larger than unity, but where the magnetic field amplitude is constant throughout the undulater. Fewer general results have been obtained in the case where the insertion device is both short, i.e., the magnetic field strength parameter changes appreciably throughout the insertion device, and the magnetic field strength is high enough that ponderomotive effects, radiation retardation, and harmonic generation are important physical phenomena. In this paper a general method is presented for calculating the radiation spectrum for short, high-field insertion devices. It ...
2005-09-15
Short wave length and high qualification of free-electron laser
International Nuclear Information System (INIS)
The oscillation experiment of free-electron laser (FEL) was carried at the wave length 488 nm. The space and time properties and power of FEL were investigated. The typical macropulse structure indicated the time interval 20 ms and the pulse width 2 to 3 ms. About 1 ns was necessary to build up FEL. The space distribution of FEL showed beautiful TEM_0_0 mode, TEM_0_1 and TEM_0_2 mode. On the basis of data, 39 #mu#W average power was calculated at 2.9 mA accumulated current per bunch by integrating each response of pixel of CCD camera. The peak power was 1.2 W. In the oscillator, FEL power was average 1.2 W, peak 38 kW. On the electron beam, the stability of head tail was controlled by 6-pole-Quadrupole-6-pole (SQS) system made by an experimental basis. We succeeded the single set test, setting up single set in the ring. The characteristic properties of electron beam evaporation mirror of photo oscillator were studied and then new type photo oscillator to obtain large peak power was ...
1998-02-01
Sequence of Potentials Lying Between the U(5) and X(5) Symmetries
Starting from the original collective Hamiltonian of Bohr and separating the beta and gamma variables as in the X(5) model of Iachello, an exactly soluble model corresponding to a harmonic oscillator potential in the beta-variable (to be called X(5)-$\\beta^2$) is constructed. Furthermore, it is proved that the potentials of the form $\\beta^{2n}$ (with n being integer) provide a ``bridge'' between this new X(5)-$\\beta^2$ model (occuring for n=1) and the X(5) model (corresponding to an infinite well potential in the beta-variable, materialized for n going to infinity. Parameter-free (up to overall scale factors) predictions for spectra and B(E2) transition rates are given for the potentials $\\beta^2$, $\\beta^4$, $\\beta^6$, $\\beta^8$, corresponding to E(4)/E(2) ratios of 2.646, 2.769, 2.824, and 2.852 respectively, compared to the E(4)/E(2) ratios of 2.000 for U(5) and 2.904 for X(5). Hints about nuclei showing this behaviour, as well as about potentials ...
2004-01-01
Energy Technology Data Exchange (ETDEWEB)
The document describes the outcome of the CSN/CIEMAT-00 interlaboratory test comparison among environmental radioactivity laboratories. the exercise was organised according to the ISO-43 and the ISO/IUPAC/AOAC Harmonized Protocol for the proficiency testing of analytical laboratories. the test sample was a soil containing environmental levels of K-40, Ra-226, Ac-228, Sr-90, Cs-137, Cs-134, Pu (239-240) y Am-241. the Universidad Autonoma de Barcelona prepared the material and reported adequate statistical studies of homogeneity. The results of the exercise were computed for 30 participating laboratories, and their analytical performance was assessed using the u-score approach. A raised percentage of satisfactory laboratory performance has been obtained for all the analysis, being the best performance in gamma measurements. The exercise has drawn that several laboratories have difficulties in the evaluation of combined uncertainty, mainly in analysis involving ...
2002-07-01
Renewable energy forecasts for solar applications : an Environment Canada perspective
Energy Technology Data Exchange (ETDEWEB)
The Meteorological Service of Canada has made weather datasets available in real-time on the Internet, for use by those with an interest in solar applications. Ensemble weather models can be used to produce medium range forecasts of weather events and to predict the likely available kilowatt-hours (kWhrs) of solar energy. As such, solar sites can maximize their harvest and use of solar energy. This presentation highlighted several different types of renewable energy forecasts obtained from weather models, including forecasts of expected kWhrs from solar panels and wind turbines, daily forecasts of expected solar heated water volumes and forecasts of water collection potential from impending precipitation events. The value of renewable energy forecasts in helping the solar energy sector monitor daily energy loads as well as daily and weekly solar energy supply was emphasized. It was suggested that renewable energy forecasts could raise public awareness of the potential of solar energy ...
2006-07-01
We summarize results of recent studies of heavy quarkonia correlators and spectral functions at finite temperatures from lattice QCD and systematic T-matrix studies using QCD motivated finite-temperature potentials. We argue that heavy quarkonia dissociation shall occur in the temperature range $1.2 \\le T_d/T_c \\le 1.5$ by the interplay of both screening and absorption in the strongly correlated plasma medium. We discuss these effects on the quantum mechanical evolution of quarkonia states within a time-dependent harmonic oscillator model with complex oscillator strength and compare the results with data for $R_{\\rm AA}/R_{\\rm AA}^{\\rm CNM}$ from RHIC and SPS experiments. We speculate whether the suppression pattern of the rather precise NA60 data from In-In collisions may be related to the recently discovered X(3872) state. Theoretical support for this hypothesis comes from the cluster expansion of the plasma Hamiltonian for heavy quarkonia in a strongly ...
2011-01-01
PWM applications for the electric railway traction system fed by the AC/DC dual power line
Energy Technology Data Exchange (ETDEWEB)
The latest electronic circuit technology that can be used for the electric railway traction system fed by an AC/DC dual power line was developed. This system consists of reverse conducting GTO thyristors, microprocessors, and DSP`s. In the AC power supply line section, the line converter is controlled by PWM technology to secure a high power factor and reduce the higher harmonic generation of an input current as far as possible. The line converter and motor converter use reverse conducting GTO thyristors. Since these converters are cooled using a heat pipe cooler, they are reduced in size and weight. The electric grounding point of the main power circuit is set to the negative side of the DC line for AC and DC line sections. Therefore, the AC/DC selector switch was simplified in structure. Moreover, the DC input for the auxiliary power supply can be obtained from multiple line converters using diodes. As the result of the actual operational test, the expected ...
1996-01-01
This paper proposes an optimization algorithm to reduce the distortion produced in the loop-filter of Continuous-Time Sigma-Delta Modulators. The aim of the algorithm is to find the loop-filter implementation that minimizes distortion at the output of the modulator, by modifying the output swing of every integrator. The algorithm is implemented in Matlab as an evolutive searching. During each step of the searching, the algorithm evaluates the harmonical distortion of a tone when it is applied to the modulator with a certain loop-filter implementation. The output of the algorithm is an optimum linear state-space representation of the loop-filter. This particular state-space representation leads to minimum distortion at the output of the modulator when the loop-filter is implemented with some specific circuitry previously defined. As long as the search is of evolutive type, the solution represents a local minimum only. The algorithm computes a random guess solution ...
2005-06-01
New intelligent monitor for CANDU type NPP
International Nuclear Information System (INIS)
Nuclear energy provides a third of Europe's electricity with nearly no greenhouse-gas emissions. Sustained efforts are now being conducted to harmonize regulations all over Europe through WENRA and to converge on technical nuclear safety practices within the TSO network ETSON (European Technical Safety Organizations Network). In CANDU type NPP the tritiated water occurs by the neutron bombardment of deuterium. The tritiated water vapors imply health hazard (in the critical organs of the body the water presents a 10 day average biological half-life) and the early detection in nuclear plants of tritium emissions is important because the tritiated water vapors have the same characteristics as of atmospheric water vapors. By detecting tritiated vapors, the monitoring system ensures the following objectives: (a) indicates levels of tritium generally due to heavy water leakage, (b) reduces the possibility of health hazard. In order to attain this goal of safety function, ...
2009-10-12
International Nuclear Information System (INIS)
This work aims at improving the understanding of the dynamics of a Free Electron Laser (FEL) based on a storage ring. A new phenomenon of saturation by the electron bunch transverse dimensions is pointed out, during the FEL operation with a magnetic optics ''low emittance''. A part of this thesis work concerns the study of the longitudinal dynamics of the FEL depending on a parameter: the detuning between the pass frequency of the electrons and the back and return frequency of the laser pulse in the optical cavity. This study shows that the FEL presents a pulsed or a steady state behavior depending on the detuning. Besides, a spectro-temporal behavior of the FEL is pointed out showing the FEL pulse substructures and holes in the spectrum. Another part of this work concerns the response of the resonant FEL system, when a perturbation is applied on the gain. Under the effect of a modulation, the FEL can present a periodic or chaotic regime. The analysis of these regimes shows that a ...
Energy Technology Data Exchange (ETDEWEB)
For rational use of energy resources, the process technology which allows harmonization and multiplication of conflicting characteristics was developed for development of new ceramic system materials. This paper summarizes the result in fiscal 1997. On a structural reaction process among creation technologies of ultra-reliable structure, study was made on structure control and hot-working technology through atmosphere control in ceramics synthesis. On basic technology for analysis and evaluation, study was made on the effect of particle bridging on strengthening and toughening of ceramic materials. Study was also made on a toughness expression mechanism, FEM model analysis of particle bridging, and crack growth resistance of ceramics. On control of solid solution precipitation, new alumina ceramics with high strength, hardness and wear resistance was obtained by transgranularly precipitating nano-size particles from a fine-grain high-density matrix through an ...
1998-03-01
Damping the. pi. -mode instability in the SLC damping rings with a passive cavity
Energy Technology Data Exchange (ETDEWEB)
Operating the Stanford Linear Collider (SLC) at 120Hz repetition rate requires the presence of two bunches in both the electron and the positron damping ring. The {pi}-mode instability, a coupled bunch instability where the two bunches oscillate with a phase difference of 180{degrees}, had been observed in both rings with low current thresholds of 7{sup *}10{sup 9} particles per bunch. To avoid the instability, the RF system had to be operated in ways which in general reduced the cavity gap voltages and required constant operational attention. For the 1992 running cycle a passive cavity was installed and successfully tested. It is tuned to the frequency of the lower synchrotron oscillation sideband of an odd revolution harmonic. The impedance of the cavity then damps {pi}-mode oscillations very similar to the Robinson damping provided by the main RF cavities which damps O-mode synchrotron oscillations. In this report we describe the motivation and physical ...
1992-07-01
Damping the {pi}-mode instability in the SLC damping rings with a passive cavity
Energy Technology Data Exchange (ETDEWEB)
Operating the Stanford Linear Collider (SLC) at 120Hz repetition rate requires the presence of two bunches in both the electron and the positron damping ring. The {pi}-mode instability, a coupled bunch instability where the two bunches oscillate with a phase difference of 180{degrees}, had been observed in both rings with low current thresholds of 7{sup *}10{sup 9} particles per bunch. To avoid the instability, the RF system had to be operated in ways which in general reduced the cavity gap voltages and required constant operational attention. For the 1992 running cycle a passive cavity was installed and successfully tested. It is tuned to the frequency of the lower synchrotron oscillation sideband of an odd revolution harmonic. The impedance of the cavity then damps {pi}-mode oscillations very similar to the Robinson damping provided by the main RF cavities which damps O-mode synchrotron oscillations. In this report we describe the motivation and physical ...
1992-07-01
CARM-klystron amplifier for accelerator applications
International Nuclear Information System (INIS)
We consider the possibility of a cyclotron-autoresonance-maser (CARM) klystron configuration for accelerator applications as an alternative to the gyroklystron amplifier. The potential advantages, compared to gyroklystrons, include: 1) comparable efficiencies at lower values of the electron beam pitch ratio #alpha#, which should improve the beam quality and make the device substantially more stable against the excitation of parasitic mode, 2) operation far from cutoff, which should reduce the fields at cavity walls, allowing higher power operation, and 3) operation at lower magnetic fields for the same cyclotron harmonic number. However, there are two significant issues associated with the design of efficient, high-power CARMs. First, because of the higher value of k_Z, compared to gyroklystrons, CARMs are substantially more sensitive to parallel velocity spread (pitch-angle spread). Second, conventional cavities support a variety of near-cutoff modes, which can ...
2001-05-31
CANDU licensing in Korea : status review and future requirements
International Nuclear Information System (INIS)
The licensing status and procedures, regulatory framework, and current safety issues of CANDU type reactors, Wolsong units 2, 3 and 4 are examined. Licensing difficulties and lessons learned during the safety review of Wolsong 2, 3 and 4 and future requirements are also summarized. The review was conducted, not only to confirm the design adequacy with respect to the domestic atomic laws and regulatory requirements of the vendor country, Canada, but also to reflect into the design the lessons learned from the regulatory experiences of operating Wolsong I to enhance the safety as high as practically possible. Safety issues observed during the licensing review, such as containment integrity, fuel channel integrity, etc., are summarized. Several efforts have been conducted to harmonize the Canadian regulations with the Korean ones by establishing domestic regulatory positions and guidelines. For example, the utility was requested to produce the CANDU safety analysis ...
1998-05-03
Broad-band stigmatic spectrograph for the soft x-ray range
International Nuclear Information System (INIS)
We describe a panoramic stigmatic spectrograph comprising a grazing-incidence toroidal mirror and a large-aperture free-standing transmission diffraction grating (5000 lines mm-1 ). Two spectrograph versions were constructed, with grazing angles of 7.6 and 40 and the short-wavelength spectral limits near 4 and 1.5 nm. The spectrograph aberrations were studied by numerical ray tracing. The spectrograph was used to record line and quasi-continuous spectra (1.5 - 30 nm) of multiply charged ions in a plasma generated by the second-harmonic pulses of an yttrium aluminate laser (Q = 0.15 J, ? = 5 ns, ? = 0.54 ?m, repetition rate = 0.5 Hz). In combination with a laser-produced plasma radiation source, the arrangement was used to characterise soft x-ray optical components and to generate collimated beams of polarised radiation in the 14 - 20 nm range. (laser applications and other topics in quantum electronics)
1998-09-30
AC motor drive system for electric cars
Energy Technology Data Exchange (ETDEWEB)
Various main circuit equipment with large capacity GTO thyristors are outlined for AC and DC electric cars. The configuration of a PWM converter system is presented for the AC main motor drive system of the Shinkansen trains, and its following features are described: the high power factor control capable of keeping a power factor 100% constantly, energy saving by power regenerative braking, the small triple structure with large capacity reverse-conducting GTO thyristors of 4,500V/3,000A, and the reduction of equivalent interfering current and harmonic current by three phase-triple phase difference operation. Furthermore, a control logic equipment with 16 bit MPU and a main transformer are outlined, and the verification test results of the control logic equipment by an analog model simulation and the combinational test results of the commercial equipment are reported. Prototype VVVF inverter system for DC electric cars is also presented. 6 refs., 13 figs., 3 tabs.
1989-08-10
A model of coherent fluctuations of nuclear density
International Nuclear Information System (INIS)
A model for coherent fluctuations of the nuclear density including all nucleons in the fluctuation movement is formulated. The wave function of the flucton satisfies a Schroedinger-type equation in which the role of potential energy is played by the energy of the nuclear matter for the A nucleons. The appearance of high-momentum components in the one-particle momentum distribution is related to the volume fluctuations of the density. These fluctuations are supposed to be of coherent nature, i.e. all nucleons are involved in the motion. An explicit expression for the momentum distribution of the nucleons in "1"2C and "1"8"1Ta nuclei is obtained and compared with the phenomenological momentum distribution as well as with the results given by the model of a non-relativistic harmonic oscillator and by the Dirac equation in the self-consistent model. The differential cross-section of 1 GeV proton scattering by the "2"8Si, "3"2S, "4"0Ca, "4"8Ca, "5"8Ni, "2"0"8Pb are ...
X-ray scattering signatures of {beta}-thalassemia
Energy Technology Data Exchange (ETDEWEB)
X-ray scattering from lyophilized proteins or protein-rich samples is characterized by the presence of two characteristic broad peaks at scattering angles equivalent to momentum transfer values of 0.27 and 0.6 nm{sup -1}, respectively. These peaks arise from the interference of coherently scattered photons. Once the conformation of a protein is changed, these two peaks reflect such change with considerable sensitivity. The present work examines the possibility of characterizing the most common cause of hemolytic anaemia in Egypt and many Mediterranean countries; {beta}-thalassemia, from its X-ray scattering profile. This disease emerges from a genetic defect causing reduced rate in the synthesis of one of the globin chains that make up hemoglobin. As a result, structurally abnormal hemoglobin molecules are formed. In order to detect such molecular disorder, hemoglobin samples of {beta}-thalassemia patients are collected, lyophilized and measured using a conventional X-ray ...
2009-08-11
Wind turbulence used as searching signal for MPPT in variable-speed wind energy conversion systems
Energy Technology Data Exchange (ETDEWEB)
The control problem associated to a class of horizontal-axis fixed-pitch variable-speed low-power wind energy conversion systems, working in the partial load region, consisting in the energy conversion maximization, is approached here under the assumption that the wind turbine model and its parameters are poorly known. Using a new approach derived from the optimum seeking methods category, generically called Maximum Power Point Tracking (MPPT), the proposed control solution aims at driving the average position of the operating point near to optimality. Instead of inducing sinusoidal search signals, the wind turbulence is here used as search disturbance. The high-speed shaft's average rotational speed is slowly adjusted using the Fast Fourier Transform processing of some available measures from the system as an estimate of the operating point's position/distance to optimality. Numerical simulations are used for preliminary checking the control law ...
2009-01-15
Energy Technology Data Exchange (ETDEWEB)
Fourier transform infrared (FTIR) difference spectra have been obtained for the bR----K, bR----L, and bR----M photoreactions in bacteriorhodopsin mutants in which Asp residues 85, 96, 115, and 212 have been replaced by Asn and by Glu. Difference peaks that had previously been attributed to Asp COOH groups on the basis of isotopic labeling were absent or shifted in these mutants. In general, each COOH peak was affected strongly by mutation at only one of the four residues. Thus, it was possible to assign each peak tentatively to a particular Asp. From these assignments, a model for the proton-pumping mechanism of bR is derived, which features proton transfers among Asp-85, -96, and -212, the chromophore Schiff base, and other ionizable groups within the protein. The model can explain the observed COOH peaks in the FTIR difference spectra of bR photointermediates and could also account for other recent results on site-directed mutants of bR.
1988-11-15
VAWT (Vertical-Axis Wind Turbine) stochastic loads produced by atmospheric turbulence
Blade fatigue life is an important element in determining the economic viability of the Vertical-Axis Wind Turbine (VAWT). A principal source of blade fatigue is thought to be the stochastic (i.e., random) aerodynamic loads created by atmospheric turbulence. This paper discusses the development of a model for the simulation of these stochastic loads, given the rotor geometry, operating conditions, and assumed turbulence properties. A Double-Multiple-Streamtube analysis is employed, which includes the effects of wind shear. Reynolds number variations, different airfoil sections and chord lengths along the blade span, and an empirical model for dynamic stall effects. Calculations are presented for the VAWT 34-m Test Bed currently being assembled at Bushland, Texas. Time histories of the loads, as well as their Fourier spectra, are presented and discussed. An unexpected finding is that the average output power is predicted to be more sensitive to turbulence level than ...
1987-01-01
Energy Technology Data Exchange (ETDEWEB)
Step-scan Fourier transform infrared spectroscopy in conjunction with impulse stress on polymer films has been used to monitor dynamic rheological responses in real time. A novel piezo-electrically-driven polymer microrheometer was employed to apply repetitive impulses to the polymer sample while time-domain spectra were recorded. Recent results include the study of both semi-crystalline polymers such as isotactic polypropylene (iPP) and elastomers such as Estane polyester/polyurethane copolymer and Kraton tri-block copolymer. The spectral changes of iPP are consistent with frequency-domain results. For iPP at room temperature, large differences in the response times of different absorption bands are not seen. However, the orientation response of the CH{sub 3} rocking mode is slightly slower than the responses of the backbone modes. To the authors` knowledge, this is the first reported successful step-scan FTIR time-domain dynamic polymer opto-rheology experiment. ...
1998-07-01
Time-dependent infrared emission following photodissociation of nitromethane and chloropicrin.
Nitromethane (CH(3)NO(2)) and its chlorinated analogue, chloropicrin (CCl(3)NO(2)), were photolyzed at 193, 248, and 266 nm, and the products were observed by time-dependent Fourier transform infrared emission spectroscopy. At 193 and 248 nm, the primary photodissociation pathway for nitromethane was cleavage of the C-N bond to produce CH(3) + NO(2)(A (2)B(2)). At 266 nm, weak emission was observed following photodissociation of nitromethane, but an infrared spectrum could not be obtained. The photodissociation of chloropicrin at 193 nm produced the analogous product channel CCl(3) + NO(2)(A (2)B(2)) in addition to several other product channels. At 248 and 266 nm, only CCl(3) + NO(2)(A (2)B(2)) was observed. The production of phosgene (CCl(2)O) from chloropicrin photodissociation was not observed in this study. PMID:16571044
2006-04-01
Thermal effect on superhydrophobic performance of stearic acid modified ZnO nanotowers
Energy Technology Data Exchange (ETDEWEB)
The thermal desorption of stearic acid on superhydrophobic zinc oxide nanotowers has been investigated. The stearic acid passivated zinc oxide nanotowers provide a very high contact angle of {approx}173 {+-} 1.1 deg. with a very low hysteresis of {approx}1.4 {+-} 0.5 deg. due to the presence of a binary structure composed of several nanosteps on each nanotower of height {approx}700 nm that eventually reduces the area of contact between the drop and the nanotowers and trapping more air as revealed by the field emission scanning electron microscopy images. The superhydrophobic performance of these nanotowers, however, declines following annealing at elevated temperatures. Fourier transform infrared spectra show a reduction in the intensity of stearic acid -CH{sub n} peaks at elevated temperatures revealing the cause of the decrease in contact angle and confirming the occurrence of thermal desorption at 184 deg. C. The corresponding activation energy for desorption ...
2008-02-28
Two dimensional Fourier spectra of near-infrared images of galaxies provide a powerful diagnostic tool for the detection of spiral arm modulation in stellar disks. Spiral arm modulation may be understood in terms of interference patterns of outgoing and incoming density wave packets or modes. The brightness along a spiral arm will be increased where two wave crests meet and constructively interfere, but will be decreased where a wave crest and a wave trough destructively interfere. Spiral arm modulation has hitherto only been detected in grand design spirals (such as Messier 81). Spiral arm amplitude variations have the potential to become a powerful constraint for the study of galactic dynamics. We illustrate our method in two galaxies: NGC 4062 and NGC 5248. In both cases, we have detected trailing and leading m=2 waves with similar pitch angles. This suggests that the amplification mechanism is the WASER type II. In this mechanism, the bulge region reflects ...
2000-01-01
Energy Technology Data Exchange (ETDEWEB)
This work presents the development of a streak camera 'jitter free' sweep unit synchronized on a femtosecond laser. This application of high voltage photoconductive switches ('High voltage Auston switch') yields subpicosecond resolution for accumulated images on streak camera on a few hundreds micro joule femtosecond laser. Two others applications of these photoconductive switches are studied: - ultrafast optical commutation by a Pockels cell directly driven by a photoconductive switch (rising edge < 100 ps and jitter < 2 ps), - laser pulse energy self-stabilization experimentally proving that driving a Pockels cell by a photoconductive switch can increase the stability of the laser pulse energy from 7 % to 0.7 % rms. Additionally, the application of the acoustic-optical programmable dispersive filter (Dazzler) to the self referenced spectral phase measurement is presented. As these measurements require a linear filter combined with a ...
2004-12-15
Synthesis of nanocrystalline YSZ (ZrO_2-8Y_2O_3) powder by polymerized complex method
International Nuclear Information System (INIS)
In this study nanocrystalline powders of yttria-stabilized zirconia (ZrO_2-8Y_2O_3) have been synthesized through 'polymerized complex method'. Zirconium chloride, yttrium nitrate, citric acid and ethylene glycol were polymerized at 80 "oC to produce a gel-like mass in which metallic ions were uniformly distributed. During the thermal treatment of dried gel, nanocrystalline powder was formed at 450 "oC and 650 "oC for 2 h. Thermal reactions and crystalline phase formation of the dried gel were investigated through thermal analysis and X-ray diffraction analysis, respectively. The results of thermal analysis and XRD showed the formation of nanocrystalline powder at less than 600 "oC. Chemical bonding of the dried gel was investigated by Fourier transform infrared spectroscopy analysis. Morphology of powder calcined at 650 "oC was analyzed by scanning electron microscope. Yttria-stabilized zirconia powders with the mean crystallite size of 6 nm were prepared ...
2010-02-18
Energy Technology Data Exchange (ETDEWEB)
The thermal energy storage performance and phase change stability of mix phase change materials consisted of stearic acid and Na{sub 2}PO{sub 4}.12H{sub 2}O are studied by means of Fourier transformation infrared spectrum analyses (FTIR) and Differential Scanning Calorimetry (DSC). The specific heat capacity of mix materials is also determined experimentally. The results show that all absorption peaks of functional groups and chemical bonds of stearic acid still exist, which suggests that these crystal materials composed of stearic acid and Na{sub 2}PO{sub 4}.12H{sub 2}O have good phase change stability and chemical compatibility. Thus, disadvantages caused by the subcooling of Na{sub 2}PO{sub 4}.H{sub 2}O and the low specific heat capacity of stearic acid can be solved, it is speculated that complement each other on the basis of organic/inorganic characteristics in itself is carried out for these two component materials of the mixture. (author)
2010-07-15
Energy Technology Data Exchange (ETDEWEB)
Stearic acid gel is employed to study the phase evolution of MgTiO{sub 3} nanoparticles by thermal gravimetric analysis, X-ray diffraction, and Fourier transform infrared. During the preparation of stearic acid gel, tetrabutyl titanate easily absorbed moisture to hydrolyze into Ti(OH){sub 4} firstly, and then reacts with stearic acid and magnesium stearate to form magnesium-titanium oxide network polymer gel, meanwhile n-butanol is generated. When stearic acid gel is calcined in air, a series of oxidation and combustion reactions occur, meanwhile apparent heat is given off. The results show that a metastable intermediate phase Mg{sub 2}TiO{sub 4} is generated at 450 {sup o}C and nearly disappeared at 550 {sup o}C. Simultaneously, a new solid phase of MgTiO{sub 3} appears. The metastable intermediate phase Mg{sub 2}TiO{sub 4} is successfully identified in the current work.
2010-03-04
Size-dependent surface plasmon resonance in silver silica nanocomposites
Energy Technology Data Exchange (ETDEWEB)
Silver silica nanocomposites were obtained by the sol-gel technique using tetraethyl orthosilicate (TEOS) and silver nitrate (AgNO{sub 3}) as precursors. The silver nitrate concentration was varied for obtaining composites with different nanoparticle sizes. The structural and microstructural properties were determined by x-ray diffractometry (XRD), Fourier transform infrared spectroscopy (FTIR) and transmission electron microscopy (TEM). X-ray photoelectron spectroscopic (XPS) studies were done for determining the chemical states of silver in the silica matrix. For the lowest AgNO{sub 3} concentration, monodispersed and spherical Ag crystallites, with an average diameter of 5 nm, were obtained. Grain growth and an increase in size distribution was observed for higher concentrations. The occurrence of surface plasmon resonance (SPR) bands and their evolution in the size range 5-10 nm is studied. For decreasing nanoparticle size, a redshift and broadening of the ...
2008-02-20
Energy Technology Data Exchange (ETDEWEB)
The objective of this study is to develop an artificial neural network (ANN) model to predict the thermal conductivity of ethylene glycol-water solutions based on experimentally measured variables. The thermal conductivity of solutions at different concentrations and various temperatures was measured using the cylindrical cell method that physical properties of the solution are being determined fills the annular space between two concentric cylinders. During the experiment, heat flows in the radial direction outwards through the test liquid filled in the annual gap to cooling water. In the steady state, conduction inside the cell was described by the Fourier equation in cylindrical coordinates, with boundary conditions corresponding to heat transfer between the solution and cooling water. The performance of ANN was evaluated by a regression analysis between the predicted and the experimental values. The ANN predictions yield R{sup 2} in the range of 0.9999 and MAPE ...
2009-10-15
Precise characterisation of nanochannels in track etched membranes by SAXS and SANS
Energy Technology Data Exchange (ETDEWEB)
Poster session: Abstract is full text. Track membranes are thin polymer foils irradiated by heavy ions. The defects created by the heavy ions are located along the ions trajectory, the track. It is possible to open channels by etching with a chemical agent. These channels are very uniform. Small Angle Scattering (of X rays and neutrons) give global information about the characteristics of the channel shape. As the nanochannels are strictly parallel, an excellent sample orientation is required to obtain interpretable spectra. Then shoulders due to the oscillations of the Bessel function (radial part of the channel shape Fourier transform) are easily seen in the scattered intensity in the PXY data treatment software of SAS spectra allow to determine the channel diameter with its dispersion law, to demonstrate the existence of a wall thickness with a linearly varying density, and to assess the roughness. PXY can also detect non cylindric shapes like single or double ...
2003-05-01
Energy Technology Data Exchange (ETDEWEB)
An IEC-TDG waveform analysis program that can accurately calculate the waveform parameters in waveforms containing much noise as well as waveforms based on the IEC 1083-2 standard was developed in the impulse voltage and current test field. In the conventional curve fitting method, it is difficult to solve the non-linear equation directly when obtaining waveform parameters from the assigned discrete data. An approximate solution method is low in precision. Therefore, the residual between the standardized data and approximate function was calculated for high-speed Fourier transformation. Unrelated components were eliminated from the calculated frequency spectrum to synthesize waveforms. An L-M method is used for analysis. The solution is first tracked by a maximum diving method. If the convergence is judged to have been largely promoted, the method is switched into a Newton method to continue the calculation. The non-linear equation in a curve fitting part can be ...
1997-04-20
On-line analysis of chemical composition using an FT-Raman spectrometer in the near-ir
Newly commercialized Fourier transform Raman spectroscopic instrumentation provides a simpler alternative for vibrational spectroscopic analysis. Instrument vendors currently design for laboratory use, but there are many potential process applications of these stable, easy to use instruments. Raman spectroscopy is highly suited to analysis of aqueous samples. Near infrared excitation minimized fluorescence interference and allows for remote operation via fiber optic probes. The Department of Energy has funded research at the Measurement and Control Center to establish the utility of this method for on-line composition analysis in distillation columns. Laboratory evaluation and instrument employs an air-cooled laser and a thermoelectrically cooled detector. The device is mounted on a three by foot cart for convenient location in control rooms. Current fiber optic extension cables allow for analysis in a cell thirty five meters from the instrument. Application of the ...
1992-01-01
Energy Technology Data Exchange (ETDEWEB)
Theoretical prediction of nuclear masses is analyzed as a pattern recognition problem on the N-Z plane. A global pattern is observed by plotting the differences between measured masses and Liquid Drop Model (LDM) predictions. After unfolding the data by removing the smooth LDM mass contributions, the remaining microscopic effects have proved difficult to model, although they display a striking pattern. These deviations carry information related to shell closures, nuc]ear deformation and the residual nuclear interactions. In the present work the more than 2000 known nuclear masses are studied as an array in the N-Z plane viewed through a mask, behind which the approximately 7000 unknown unstable nuclei that can exist between the proton and neutron drip lines are hidden. We show here that employing a Fourier transform deconvolution method these by masses can be predicted with similar accuracy than standard methods. We believe that a more general approach needs to be ...
2006-07-01
International Nuclear Information System (INIS)
Theoretical prediction of nuclear masses is analyzed as a pattern recognition problem on the N-Z plane. A global pattern is observed by plotting the differences between measured masses and Liquid Drop Model (LDM) predictions. After unfolding the data by removing the smooth LDM mass contributions, the remaining microscopic effects have proved difficult to model, although they display a striking pattern. These deviations carry information related to shell closures, nuc]ear deformation and the residual nuclear interactions. In the present work the more than 2000 known nuclear masses are studied as an array in the N-Z plane viewed through a mask, behind which the approximately 7000 unknown unstable nuclei that can exist between the proton and neutron drip lines are hidden. We show here that employing a Fourier transform deconvolution method these by masses can be predicted with similar accuracy than standard methods. We believe that a more general approach needs to be ...
British Library Electronic Table of Contents (United Kingdom)
A series of new non-discoid chiral copper(ii)-salen type complexes, [Cu((4-CnH2n+1O)2salen)], n = 14, 16, 18 and salen = N,N'-cyclohexane bis (salicylideneiminato), containing 4-substituted alkoxy tails in the side aromatic rings and a cyclohexane spacer, have been prepared and their mesogenic properties investigated. The compounds were characterised by Fourier transform infra-red spectroscopy, 1H and 13C nuclear magnetic resonance spectroscopy, UV-vis spectroscopy and fast atom bombardment mass spectrometry. Mesomorphic properties of these compounds were studied by polarising optical microscopy, differential scanning calorimetry and X-ray diffraction (XRD). The ligands are non-mesogenic but the complexes exhibited enantiotropic rectangular columnar mesophases (Colr) with extended temperat...
2011-01-01
Noise bias in the refinement of structures derived from single particles
Energy Technology Data Exchange (ETDEWEB)
One of the main goals in the determination of three-dimensional macromolecular structures from electron microscope images of individual molecules and complexes (single particles) is a sufficiently high spatial resolution, about 4 A, at which the interpretation with an atomic model becomes possible. To reach high resolution, an iterative refinement procedure using an expectation maximization algorithm is often used that leads to a more accurate alignment of the positional and orientational parameters for each particle. We show here the results of refinement algorithms that use a phase residual, a linear correlation coefficient, or a weighted correlation coefficient to align individual particles. The algorithms were applied to computer-generated data sets that contained projections from model structures, as well as noise. The algorithms show different degrees of over-fitting, especially at high resolution where the signal is weak. We demonstrate that the degree of over-fitting is reduced ...
2004-12-15
Micropatterned polysaccharide surfaces via laser ablation for cell guidance
Energy Technology Data Exchange (ETDEWEB)
Micropatterned materials were obtained by a controlled laser ablation of a photoimmobilised homogeneous layer of hyaluronic acid (Hyal) and its sulphated derivative (HyalS). The photoimmobilisation was performed by coating the polysaccharide, adequately functionalised with a photoreactive group, on aminosilanised glass substrate and immobilising it on the surface under UV light. Hyal or HyalS photoimmobilised samples were then subjected to laser ablation with wavelengths in the UV regions in order to drill the pattern. Four different patterns with stripes of 100, 50, 25 and 10 {mu}m were generated. A chemical characterisation by attenuated total reflection/Fourier transform infrared (ATR/FT-IR) and time of flight-secondary ions mass spectrometry (TOF-SIMS) confirmed the success of the laser ablation procedure and the presence of alternating stripes of polysaccharide and native glass. The exact dimensions of the stripes were determined by atomic force microscopy. ...
2003-03-03
DEFF Research Database (Denmark)
The National Survey and Cadastre - Denmark (KMS) has for several years produced gravity anomaly maps over the oceans derived from satellite altimetry. During the last four years, KMS has also conducted airborne gravity surveys along the coast of Greenland dedicated to complement the existing onshore gravity coverage and fill in new data in the very-near coastal area, where altimetry data may contain gross errors. The airborne surveys extend from the coastline to approximately 100 km offshore, along 6000 km of coastline. An adequate merging of these different data sources is important for the use of gravity data especially, when computing geoid models in coastal regions. The presence of reliable marine gravity data for independent control offers an opportunity to study procedures for the merging of airborne and satellite data around Greenland. Two different merging techniques, both based on collocation, are investigated in this paper. Collocation offers a way of combining the individual ...
2002-01-01
British Library Electronic Table of Contents (United Kingdom)
The removal of Ni(II) from aqueous solution by magnetic nanoparticles prepared and impregnated onto tea waste (Fe3O4-TW) from agriculture biomass was investigated. Magnetic nanoparticles (Fe3O4) were prepared by chemical precipitation of a Fe^2^+ and Fe^3^+ salts from aqueous solution by ammonia solution. These magnetic nanoparticles of the adsorbent Fe3O4 were characterized by surface area (BET), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM) and Fourier Transform-Infrared Spectroscopy (FT-IR). The effects of various parameters, such as contact time, pH, concentration, adsorbent dosage and temperature were studied. The kinetics followed is first order in nature, and the value of rate constant was found to be 1.90x10^-^2min^-^1 at 100mgL^-^1 and 303K. Removal ef...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
Graft copolymerization of sodium styrene sulfonate (SSS) onto electron beam (EB) irradiated poly(vinylidene fluoride) (PVDF) films was investigated to find out a simple preparation process for sulfonic acid proton exchange membranes with respect to monomer concentration, absorbed dose, temperature, film thickness and storage time. The reaction order of the monomer concentration and absorbed dose of grafting was found to be 2.84 and 1.20, respectively. The overall activation energy for graft copolymerization reaction was calculated to be 11.36 kJ/mol. The initial rate of grafting was found to decrease with an increase in the film thickness. The trapped radicals in the irradiated PVDF films remained effective in initiating the reaction without considerable loss in grafting level up to 180 days, when stored under -60 {sup o}C. The presence and distribution of polystyrene sulfonate grafts in the obtained membranes were observed by Fourier transform infrared (FTIR) ...
2011-01-15
Isolation and characterization of humic acids from peat soil
International Nuclear Information System (INIS)
In this study, two different humic acids extracted from England and China peat soil, as well as three purified products extracted from commercially available humic acids [Fluka (Fluka, Neu-Ulm, Germany, Alfa (Alfa Aesar, Ward Hill, USA) and Aldrich (Aldrich-Chemical Co, Gillingham-Dorset)] were obtained respectively with the modified IHSS (International humic substances society) procedure. The chemical and structural information of these humic acids were characterized by some techniques, such as elemental analysis, ultraviolet-visible spectroscopy (UV-Vis), Fourier transform infrared spectroscopy (FTIR) and electropotential titration. UV-Vis spectra, infrared spectra, values for elemental composition and the contents of carboxyls, phenolic hydroxyls and total acidities of these humic acids were acquired. It is indicated that all these humic acids are different in the aspect of chemical structure, respectively, and these humic acids would be used for the ...
2009-05-01
Energy Technology Data Exchange (ETDEWEB)
When a metallic alloy is quenched into a miscibility gap, a mixture of two phases develops, whose domain structure then coarsens because of the interfacial energy between the two phases. This spatial arrangement of the domains and the rate at which they evolve may be strongly influenced by elastic interactions. In a recent paper, the authors described a method for simulating the effect of anisotropic elastic interactions in a two-dimensional Ising model of a cubic alloy, using Kawasaki dynamics with the elastic interactions represented by a long-range two-body interaction potential. Here they present the results of such simulations at various temperatures, alloy compositions and misfits (by misfit they mean the difference in size between the two kinds of atom), exhibiting snapshots both of the microscopic configurations (corresponding to experimental measurements using transmission electron microscopy) and of their squared Fourier transforms (corresponding to ...
1996-08-01
Interactions of metal cations with anionic groups on the cell Wall of the macroalga vaucheria sp.
Energy Technology Data Exchange (ETDEWEB)
The aim of this article was to investigate the interactions of metal cations in aqueous solutions with the biomass of the freshwater macroalga Vaucheria sp. This problem is important when elaborating new applications of biosorption, e.g. the production of mineral feed additives for livestock from the biomass of algae enriched with microelement ions. Potentiometric titration was applied as a quick and cheap screening test to search for new efficient biosorbents. It revealed a variety of functional groups capable of cation exchange on the macroalgal surface, including carboxyl, phosphate, hydroxyl or amino groups. Fourier transform infrared spectroscopy on natural and chromium-loaded Vaucheria sp. confirmed that carboxyl groups played a dominant role in the biosorption. The study also showed that Ca(II), Na(I), K(I), and Mg(II) ions were released from the biomass after biosorption of Cu(II), Mn(II), Zn(II), and Co(II) ions, indicating that ion exchange was a key ...
2010-06-15
Interaction of bovine serum albumin with some novel PEG-containing diblock copolymers
British Library Electronic Table of Contents (United Kingdom)
A comparative study on the interaction of different PEG-containing diblock copolymers including SA400, SA600, SA1500 and OA1500 (stearyl and oleyl esters of polyethylene glycol with 400, 600 and 1500 molecular weights, respectively) with bovine serum albumin (BSA) was carried out using isothermal titration calorimetry (ITC), attenuated total reflectance Fourier transform infrared (ATR-FTIR), circular dichroism (CD), and fluorescence spectroscopies. ITC data show that SA400, SA600, SA1500 and OA1500 bind to BSA, with association constants of (14.5, 3.16, 50.7 and 17.6)x103M-1, respectively. Results also show that the binding is enthalpically driven, disfavored by conformational entropy. Quantitative analysis of the FTIR absorbance spectra at amide Iprime (1600-1700cm-1) as well as far UV ci...
2008-01-01
Energy Technology Data Exchange (ETDEWEB)
A Tm{sup 3+}- Ho{sup 3+} -codoped single crystal of monoclinic BaY{sub 2}F{sub 8} has been characterized by means of high resolution FTIR spectroscopy in the wave number range 2000-24000 cm{sup -1} and in the temperature range 9-300 K. The energy level schemes of the two lanthanide ions as determined by the optical absorption spectra is presented, analyzed, and fitted within a single ion Hamiltonian model. The very small energy separation (about 0.6-1.6 cm{sup -1}) measured between the first and second sublevels of the ground state manifolds for both the ions is in line with the theoretical predictions. The impurity-phonon coupling is put into evidence by the thermally induced line shift and broadening, and by the detection of vibronic replicas of a few lines. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
2005-01-01
High resolution Fourier transform spectroscopy and crystal-field analysis in Tm,Ho:BaY_2F_8
International Nuclear Information System (INIS)
A Tm"3"+- Ho"3"+ -codoped single crystal of monoclinic BaY_2F_8 has been characterized by means of high resolution FTIR spectroscopy in the wave number range 2000-24000 cm"-"1 and in the temperature range 9-300 K. The energy level schemes of the two lanthanide ions as determined by the optical absorption spectra is presented, analyzed, and fitted within a single ion Hamiltonian model. The very small energy separation (about 0.6-1.6 cm"-"1) measured between the first and second sublevels of the ground state manifolds for both the ions is in line with the theoretical predictions. The impurity-phonon coupling is put into evidence by the thermally induced line shift and broadening, and by the detection of vibronic replicas of a few lines. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
2005-01-01
Functionalizing titania nanoparticle surfaces in a fluidized bed plasma reactor
International Nuclear Information System (INIS)
Functionalizing nanoparticle surfaces is essential for achieving homogeneous dispersions of monodisperse particles in polymer nanocomposites for successful utilization in engineering applications. Functionalization reduces the surface energy of the nanoparticles, thereby limiting the tendency to agglomerate. Moreover, reactive groups on the surface can also participate in the polymerization, creating covalent bonds between the inorganic and organic phases. In this paper, a fluidized bed inductively coupled plasma (FB-ICP) reactor is used to break apart the agglomerates and functionalize commercial TiO2 nanoparticle powders in a batch of several grams. The fluidized bed could be implemented into a continuous flow reactor, potentially making this a viable method to treat larger quantities of commercial powders. The particles are treated with acrylic acid (AA) and tetraethylorthosilicate (TEOS) plasma and the functionalized particles were collected separately from bulk powder. High ...
2009-11-18
Chlorinated organics are frequently found as harmful soil contaminants and persisted for extended periods of time. A novel approach, named pulsed corona discharge plasma (PCDP), was employed for the degradation of pentachlorophenol (PCP) in soil. Experimental results showed that 87% of PCP could be smoothly removed in 60 min. Increasing pulse voltage, enhancing soil pH, lowering humic acid (HA) in soil and reducing granular size of the soil were found to be favorable for PCP degradation efficiency. Oxidation and physical processes simultaneously contributed to PCP removal in soil and ozone was the main factor in PCDP treatment. C-Cl bonds in PCP were cleaved during PCDP treatment by Fourier transform infrared spectroscopy (FTIR) analysis. The mineralization of PCP was confirmed by total organic carbon (TOC) and dechlorination analyses. The main intermediate products such as tetrachlorocatechol, tetrachlorohydroquinone, acetic acid, formic acid, and oxalic acid were ...
2010-04-15
Estimating $\\omega$ from Galaxy Redshifts Linear Flow Distortions and Nonlinear Clustering
We propose a method to determine the cosmic mass density Omega from redshift-space distortions induced by large-scale flows in the presence of nonlinear clustering. Nonlinear structures in redshift space such as fingers of God can contaminate distortions from linear flows on scales as large as several times the small-scale pairwise velocity dispersion sigma_v. Following Peacock & Dodds (1994), we work in the Fourier domain and propose a model to describe the anisotropy in the redshift-space power spectrum; tests with high-resolution numerical data demonstrate that the model is robust for both mass and biased galaxy halos on translinear scales and above. On the basis of this model, we propose an estimator of the linear growth parameter beta = Omega^0.6/b, where b measures bias, derived from sampling functions which are tuned to eliminate distortions from nonlinear clustering. The measure is tested on the numerical data and found to recover the true value of beta ...
1997-01-01
International Nuclear Information System (INIS)
Si/Ni alloy and graphite composites were synthesized using arc-melting followed by high energy mechanical milling (HEMM). Alloy particles comprising of NiSi2, NiSi and Si phases were distributed finely and uniformly on the surface of graphite in the composites obtained after Hem. The composite containing 60 wt.% of Si/Ni alloy exhibited a stable capacity of ?780 mAh/g. Fourier transform infrared spectroscopy (FTIR) analysis confirmed that some bonds were formed between alloy and graphite after HEMM, which appeared to retain the electrical connection between alloy and graphite during cycling. X-ray diffraction (XRD) analysis indicated that NiSi2 and NiSi phases, which acted as an inactive alloy matrix remained invariant during charge and discharge. In addition to NiSi2 and NiSi phases, disordered graphite layers also played the role of media for the accommodation of large volume change of Si during cycling. The large reversible capacity and good cycleability showed ...
2005-09-30
Energy Technology Data Exchange (ETDEWEB)
Two major modes of CO adsorption on SiO{sub 2}-supported Pd reflect different extents of back-donation, which is, at least in part, controlled by the local electron density at the adsorption site. The fraction of CO in the bridging mode (B) increases and that of the linear mode (L) decreases, with increasing size of the Pd particles, indicating high electron density at Pd atoms in terraces of close-packed crystal faces, in agreement with Smoluchowski's classical model. For samples reduced at 300{degree}C our data points and those of other authors are located on a common curve of B/L vs metal dispersion. Extensive reduction at 600{degree}C results in significantly lower B/L values, attributed to the incipient formation of a palladium silicide. Oxidation followed by reduction at 300{degree}C destroys the silicide, and the B/L value returns to the original curve.
1989-06-15
Two major modes of CO adsorption on SiO{sub 2}-supported Pd reflect different extents of back-donation, which is, at least in part, controlled by the local electron density at the adsorption site. The fraction of CO in the bridging mode (B) increases and that of the linear mode (L) decreases, with increasing size of the Pd particles, indicating high electron density at Pd atoms in terraces of close-packed crystal faces, in agreement with Smoluchowski's classical model. For samples reduced at 300{degree}C our data points and those of other authors are located on a common curve of B/L vs metal dispersion. Extensive reduction at 600{degree}C results in significantly lower B/L values, attributed to the incipient formation of a palladium silicide. Oxidation followed by reduction at 300{degree}C destroys the silicide, and the B/L value returns to the original curve.
1989-06-15
Energy Technology Data Exchange (ETDEWEB)
An experimental investigation was conducted to evaluate the effect of three different oxygenated compounds, diglyme, diethyl maleate and dibutyl maleate, on emissions from a Volkswagen 1.9 litre, turbocharged, direct injection diesel engine. Sampling was performed using a mini-dilution tunnel technique to obtain particulate matter and a Fourier transform infrared (FTIR) spectrometer for gaseous emissions. The particulate samples were analysed using thermal analysis and Soxhlet extraction to determine the fraction of volatile and soluble organic material respectively. All three oxygenated compounds were found to be effective at reducing particulate emissions, with the maleate compounds being more effective overall than the diglyme. Analysis of the relative contributions of changes in the soot and soluble organic fraction (SOF) to the reduction of particulate matter indicated that, for diethyl maleate and diglyme, reductions in soot were the dominant effect. No ...
2000-02-01
Direct observation of ordered orbital of YTiO_3 by the X-ray magnetic diffraction technique
International Nuclear Information System (INIS)
X-ray magnetic diffraction (XMD) technique was applied to an orbital ordering compound of ferromagnetic YTiO_3 for the first time. The orbital-magnetic form factor #mu# _L(k) and the spin-magnetic form factor #mu# _S(k) were independently measured by utilizing the LS separation ability of the XMD. The #mu# _L(k) was measured for ten reciprocal-lattice points. No significant values of the #mu# _L(k) were observed for most of the reciprocal-lattice points within the estimated statistical errors, which suggested quenching of the orbital moment. The #mu# _S(k) was measured for 22 reciprocal-lattice points. Fourier synthesis of the #mu# _S(k) gave the spin density distribution m _S(r) in the real space. The obtained m _S(r) map shows the characteristic feature of the electron distribution of 3d electron in the t_2_g state of a Ti atom coordinated by O"2"- ions, in which the electrons are distributed away from the negative O"2"- ions. It is concluded that the electron ...
2005-08-01
Energy Technology Data Exchange (ETDEWEB)
The real-time neutron radiography system of the Kyoto University Reactor (KUR) has been practically applied to penetrating the side plates containing boron burnable poison to test MTR type reactor fuels and to investigation of moving objects. Compared with the image obtained by the direct film method, however, the image from the TV system is in low-contrast and poor-resolution. This paper presents some digital processing approaches to improve the image quality and the neutron TV system is successfully applied to neutron computed tomography (NCT). The frame summing technique is effective to increase the quality of the radiographic image. By using the NTV system in NCT, the projection data are able to be acquired in a single measurement as observing the projection image on a CRT monitor. Two weighting functions based on the Fourier-convolution algorithm are employed to obtain the reconstructed image. The image quality could be satisfactory to distinguish acrylic ...
1984-09-01
International Nuclear Information System (INIS)
The real-time neutron radiography system of the Kyoto University Reactor (KUR) has been practically applied to penetrating the side plates containing boron burnable poison to test MTR type reactor fuels and to investigation of moving objects. Compared with the image obtained by the direct film method, however, the image from the TV system is in low-contrast and poor-resolution. This paper presents some digital processing approaches to improve the image quality and the neutron TV system is successfully applied to neutron computed tomography (NCT). The frame summing technique is effective to increase the quality of the radiographic image. By using the NTV system in NCT, the projection data are able to be acquired in a single measurement as observing the projection image on a CRT monitor. Two weighting functions based on the Fourier-convolution algorithm are employed to obtain the reconstructed image. The image quality could be satisfactory to distinguish acrylic ...
1984-01-01
Energy Technology Data Exchange (ETDEWEB)
A new method is being developed to quickly screen for the human exposure potential to polycyclic aromatic hydrocarbons (PAHs) and organochlorines (OCs). The development involves two key elements: identifying suitable signals that represent intracellular changes that are specific to PAH and OC exposure, and constructing a device to guide the biological cell growth so that signals from individual cells are consistent and reproducible. We are completing the identification of suitable signals by using synchrotron radiation-based (SR) Fourier-transform infrared (FTIR) spectromicroscopy in the mid-infrared region (4000-400 cm-1). Distinct changes have been observed in the IR spectra after treatment of human cells in culture medium with PAHs and OCs. The potential use of this method for detecting exposure to PAHs and OCs has been tested and compared to a reverse transcription polymerase chain reaction (RT-PCR) assay that quantifies increased expression of the CYP1A1 gene ...
1999-01-10
International Nuclear Information System (INIS)
2-hydroxyethyl methacrylate (HEMA) has been deposited onto the surface of silicon substrate (thickness = 500 ?m) using plasma polymerization technique. Polymerization process was carried out in an in-house developed inductively coupled plasma polymerization setup. The depositions were carried out using RF power supply (13.56 MHz) at power of 75 W for 10 and 40 min. The RF supply was coupled to the inductance through a matching network. The effect of plasma polymerization (surface grafting) on the degree of surface modification has been investigated. The chemical changes on the polymer backbone are followed from the results of Fourier transform infrared (FTIR) spectroscopy and X-ray photoelectron spectroscopy (XPS), which show the peaks corresponding to the functional groups of the HEMA polymerized onto the silicon surface. The morphology of the modified surfaces has also been investigated using scanning electron microscopy (SEM) and atomic force microscopy (AFM). ...
2005-05-30
Cyclopropane isomerization over Eu[sup 3+]NaX zeolites
Energy Technology Data Exchange (ETDEWEB)
Cyclopropane isomerization to propylene over various Eu[sup 3+] loadings in NaX zeolite have been studied by measurements of steady-state and transient kinetics and by Fourier transform infrared spectroscopy. As Eu[sup 3+] loading increases, the rate of deactivation increases, the conversion increases, apparent activation energies are lowered, and Bronsted acid site strength and amounts increase. Apparent activation energies of 13-15 kcal/mol for propylene formation have been observed for these systems, consistent with literature reports for other metal supported heterogeneous catalyst systems. Deactivation studies have shown that activity can be restored by heating in He at 380[degrees]C between various temperature runs, and that gases desorbed during regeneration are predominantly propylene. Poisoning studies of Bronsted sites with Na vapor lead to deactivation of these catalysts. A reaction mechanism scheme based on [pi] allyl intermediates in the supercages of ...
1992-11-01
Energy Technology Data Exchange (ETDEWEB)
The Linac Coherent Light Source (LCLS) is required to deliver a high quality electron beam for producing coherent X-rays. As a result, high resolution beam position monitoring is required. The Beam Position Monitor (BPM) digitizer acquires analog signals from the beam line and digitizes them to obtain beam position data. Although Matlab is currently being used to test the BPM digitizer?s functions and capability, the Controls Department at SLAC prefers to use Experimental Physics and Industrial Control Systems (EPICS). This paper discusses the transition of providing similar as well as enhanced functionalities, than those offered by Matlab, to test the digitizer. Altogether, the improved test stand development system can perform mathematical and statistical calculations with the waveform signals acquired from the digitizer and compute the fast Fourier transform (FFT) of the signals. Finally, logging of meaningful data into files has been added.
2011-06-22
Coriolis effect on thermal convection in a couple-stress fluid-saturated rotating rigid porous layer
Energy Technology Data Exchange (ETDEWEB)
Both linear and weakly nonlinear stability analyses are performed to study thermal convection in a rotating couple-stress fluid-saturated rigid porous layer. In the case of linear stability analysis, conditions for the occurrence of possible bifurcations are obtained. It is shown that Hopf bifurcation is possible due to Coriolis force, and it occurs at a lower value of the Rayleigh number at which the simple bifurcation occurs. In contrast to the nonrotating case, it is found that the couple-stress parameter plays a dual role in deciding the stability characteristics of the system, depending on the strength of rotation. Nonlinear stability analysis is carried out by constructing a set of coupled nonlinear ordinary differential equations using truncated representation of Fourier series. Sub-critical finite amplitude steady motions occur depending on the choice of physical parameters but at higher rotation rates oscillatory convection is found to be the preferred ...
2011-04-15
International Nuclear Information System (INIS)
High quality graphene sheets are synthesized through efficient oxidation process followed by rapid thermal expansion and reduction by H2. The number of graphene layers is controlled by tuning the oxidation degree of GOs. The higher the oxidation degree of GOs is getting, the fewer the numbers of graphene layers can be obtained. The material is characterized by elemental analysis, thermo-gravimetric analysis, scanning electron microscopy, atomic force microscopy, transmission electron microscopy and Fourier transform infrared spectroscopies. The obtained graphene sheets with single, triple and quintuplicate layers as anode materials exhibit a high reversible capacity of 1175, 1007, and 842 mA h g-1, respectively, which show that the graphene sheets with fewer layers have higher reversible capacity. -- Graphical abstract: The typical TEM images of the graphene sheets derived from GO3(a), GO2(b) and GO1(c). Display Omitted Highlights: ? With the oxidation degree of GO ...
2011-05-01
Energy Technology Data Exchange (ETDEWEB)
The industrial standard process for the purification of natural gas is to remove acid gases, mainly hydrogen sulfide and carbon dioxide, by the absorption and reaction of these gases with alkanolamines. The natural gas industry requires vapor-liquid equilibrium (VLE) data to develop more energy efficient amine mixtures. Some energy reductions have been realized in the past decade by applying such amine systems as hindered amines, methyldiethanolamine (MDEA), and MDEA based amine mixtures. However, the lack of reliable and accurate VLE data impedes the commercial application of these more efficient alkanolamine systems. The first objective of this project is to improve the accuracy of vapor-liquid equilibrium measurements at low hydrogen sulfide concentrations. The second objective is to make VLE measurements for amine mixtures. By improving the accuracy of the VLE data on MDEA and other amines, energy savings can be implemented in the many existing absorption units already in use. If ...
1995-08-01
Energy Technology Data Exchange (ETDEWEB)
The industrial standard process for the purification of natural gas is to remove acid gases, mainly hydrogen sulfide and carbon dioxide, by the absorption and reaction of these gases with alkanolamines. Inadequate data for vapor -- liquid equilibrium (VLE) hinder the industry from converting operations to more energy efficient amine mixtures and conserving energy. Some energy reductions have been realized in the past decade by applying such amine systems as ``hindered`` amines, methyldiethanolamine (MDEA), and MDEA based amine mixtures. However, the lack of reliable and accurate fundamental VLE data impedes the commercial application of these more efficient alkanolamine systems. The first project objective is to improve the accuracy of vapor -- liquid equilibrium measurements at low hydrogen sulfide concentrations. The second project objective is to measure the VLE for amine mixtures. By improving the accuracy of the VLE measurements on MDEA and mixtures with other amines, energy ...
1991-09-01
Energy Technology Data Exchange (ETDEWEB)
The industrial standard process for the purification of natural gas is to remove acid gases, mainly hydrogen sulfide and carbon dioxide, by the absorption and reaction of these gases with alkanolamines. Inadequate data for vapor -- liquid equilibrium (VLE) hinder the industry from converting operations to more energy efficient amine mixtures and conserving energy. Some energy reductions have been realized in the past decade by applying such amine systems as hindered'' amines, methyldiethanolamine (MDEA), and MDEA based amine mixtures. However, the lack of reliable and accurate fundamental VLE data impedes the commercial application of these more efficient alkanolamine systems. The first project objective is to improve the accuracy of vapor -- liquid equilibrium measurements at low hydrogen sulfide concentrations. The second project objective is to measure the VLE for amine mixtures. By improving the accuracy of the VLE measurements on MDEA and mixtures with other ...
1991-09-01
Chemical imaging of wood-polypropylene composites.
Recent investigations of wood plastic composites have revealed a detrimental effect of using lubricant systems in production. This includes nullifying part or all of the mechanical benefit of using a polar compatibilizer, maleic anhydride polypropylene (MAPP), in the composite formulation. This investigation utilizes lubricants labeled with deuterium in conjunction with Fourier transform infrared (FT-IR) spectroscopy to allow for the separation of individual lubricants from all other material constituents. All of the deuterium labeled lubricants, used without MAPP, revealed their expulsion from the wood interface during crystallization. MAPP coupling agent was found to exist near the wood, but it is unclear if any covalent bonding with the hydroxyl functionality on the wood surface occurred. The addition of zinc stearate lubricants appears to nullify the activity of the anhydride functionality near the wood surface as evidenced by a shift in the FT-IR spectra to ...
2006-08-01
British Library Electronic Table of Contents (United Kingdom)
A magnetic core/shell Fe3O4/FeMnOx catalyst was prepared by a simple oxidation-precipitation method. The catalyst was characterized by X-ray diffraction, transmission electron microscope, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, thermogravimetric analysis and cyclic voltammetry. The characterization studies verified that Fe3O4 core was coated with a layer of Fe-Mn oxide. The Fe3O4/FeMnOx was found to be an effective and stable heterogeneous catalyst for the discoloration of methylene blue (MB) in aqueous solution by H2O2. The high catalytic activity is due to the FeMnOx shell, which not only increased the surface hydroxyl groups, but also enhanced the interfacial electron transfer. The discoloration of MB could be due to the decomposition of H2O2 into ?OH ...
2011-01-01
CZT vs FFT: Flexibility vs Speed
Energy Technology Data Exchange (ETDEWEB)
Bluestein's Fast Fourier Transform (FFT), commonly called the Chirp-Z Transform (CZT), is a little-known algorithm that offers engineers a high-resolution FFT combined with the ability to specify bandwidth. In the field of digital signal processing, engineers are always challenged to detect tones, frequencies, signatures, or some telltale sign that signifies a condition that must be indicated, ignored, or controlled. One of these challenges is to detect specific frequencies, for instance when looking for tones from telephones or detecting 60-Hz noise on power lines. The Goertzel algorithm described in Embedded Systems Programming, September 2002, offered a powerful tool toward finding specific frequencies faster than the FFT.Another challenge involves analyzing a range of frequencies, such as recording frequency response measurements, matching voice patterns, or displaying spectrum information on the face of an amateur radio. To meet this challenge most ...
2003-10-01
Energy Technology Data Exchange (ETDEWEB)
A newly constructed Fourier transform microwave spectrometer has been used to record the pure rotational spectra of four isotopomers of SrS ({sup 88}Sr{sup 32}S, {sup 87}Sr{sup 32}S, {sup 86}Sr{sup 32}S, and {sup 88}Sr{sup 34}S) between 6 and 26 GHz. The molecules were produced by reacting laser ablated strontium with carbonyl sulfide (0.1% in argon). Pure rotational transitions in the ground, first and second vibrational states have been observed. The data set has enabled a multi-isotopomer fit. Born-Oppenheimer breakdown terms for both atoms have been determined. The {sup 87}Sr nuclear quadrupole coupling constant in {sup 87}Sr{sup 32}S has been determined for the first time.
2007-12-06
Application of spectroscopic techniques for the study of paper documents: A survey
International Nuclear Information System (INIS)
For many centuries paper was the main material for recording cultural achievements all over the world. Paper is mostly made from cellulose with small amounts of organic and inorganic additives, which allow its identification and characterization and may also contribute to its degradation. Prior to 1850, paper was made entirely from rags, using hemp, flax and cotton fibres. After this period, due to the enormous increase in demand, wood pulp began to be commonly used as raw material, resulting in rapid degradation of paper. Spectroscopic techniques represent one of the most powerful tools to investigate the constituents of paper documents in order to establish its identification and its state of degradation. This review describes the application of selected spectroscopic techniques used for paper characterization and conservation. The spectroscopic techniques that have been used and will be reviewed include: Fourier-Transform Infrared spectroscopy, Raman ...
2009-06-01
Analysis of complex systems using neural networks
Energy Technology Data Exchange (ETDEWEB)
The application of neural networks, alone or in conjunction with other advanced technologies (expert systems, fuzzy logic, and/or genetic algorithms), to some of the problems of complex engineering systems has the potential to enhance the safety, reliability, and operability of these systems. Typically, the measured variables from the systems are analog variables that must be sampled and normalized to expected peak values before they are introduced into neural networks. Often data must be processed to put it into a form more acceptable to the neural network (e.g., a fast Fourier transformation of the time-series data to produce a spectral plot of the data). Specific applications described include: (1) Diagnostics: State of the Plant (2) Hybrid System for Transient Identification, (3) Sensor Validation, (4) Plant-Wide Monitoring, (5) Monitoring of Performance and Efficiency, and (6) Analysis of Vibrations. Although specific examples described deal with nuclear power ...
1992-01-01
Analysis of complex systems using neural networks
Energy Technology Data Exchange (ETDEWEB)
The application of neural networks, alone or in conjunction with other advanced technologies (expert systems, fuzzy logic, and/or genetic algorithms), to some of the problems of complex engineering systems has the potential to enhance the safety, reliability, and operability of these systems. Typically, the measured variables from the systems are analog variables that must be sampled and normalized to expected peak values before they are introduced into neural networks. Often data must be processed to put it into a form more acceptable to the neural network (e.g., a fast Fourier transformation of the time-series data to produce a spectral plot of the data). Specific applications described include: (1) Diagnostics: State of the Plant (2) Hybrid System for Transient Identification, (3) Sensor Validation, (4) Plant-Wide Monitoring, (5) Monitoring of Performance and Efficiency, and (6) Analysis of Vibrations. Although specific examples described deal with nuclear power ...
1992-12-31
Advanced nanoscale separations and mass spectrometry for sensitive high-throughput proteomics
Energy Technology Data Exchange (ETDEWEB)
We review recent development in separations and mass spectrometric instrumentation for sensitive and high-throughput proteomic analyses. These efforts have been primarily focused on the development of high-efficiency (separation peak capacity of ~103) nanoscale liquid chromatography (nanoLC; e.g., flow rates extending down to ~20 nL/min at optimal separation linear velocities through narrow packed capillaries) in combination with advanced mass spectrometry (MS), including high sensitivity and high resolution Fourier transform ion cyclotron resonance (FTICR) MS. This technology enables MS analysis of low nanogram-level proteomic samples (i.e., nanoscale proteomics) with individual protein identification sensitivity at the low zeptomole-level. The resultant protein measurement dynamic range can reach 106 for nanogram-sized proteomic samples, while more abundant proteins can be detected from complex sub-picogram size proteome samples. The average proteome ...
2005-06-01
In order to model transport of dissolved ions in subsurface environments, one should understand how these ions interact with solid phase adsorbents. Our primary goal has been investigating the reaction mechanisms which affect microcontaminant partitioning between aqueous solutions and solid phase adsorbents, using goethite ({alpha}-FeOOH) as a model adsorbent. Cylindrical internal reflection -- Fourier transform infrared (CIR-FTIR) spectroscopy has been developed as the primary technique for this study. Wet chemical adsorption studies, acoustophoresis and electrophoretic mobility have been used to obtain supporting information as needed. Phenol and o-nitrophenol did not adsorb to goethite. Benzoate, phthalate and p-hydroxybenzoate all adsorbed via a bidentate mechanism to two adjacent iron atoms, while salicylate and 2,4-dihydroxybenzoate formed a chelate complex to single iron atoms. Phosphate adsorption was predominately bidentate.
1990-07-01
British Library Electronic Table of Contents (United Kingdom)
We propose and demonstrate a facile room-temperature synthetic method for obtaining water-soluble magnetic Fe3O4 nanoparticles (NPs) by combining the in situ synthesis and decomposition of a magnetic polymer hydrogel. The Fe3O4 NPs with average diameters of 6.3-8.3nm were synthesized in a cross-linked polyacrylamide (PAAm) hydrogel by coprecipitating iron ions. The decomposition of the magnetic polymer hydrogel by an aqueous solution of sodium hydroxide led to the transfer of Fe3O4 NPs into the aqueous medium. The NPs can be dispersed stably in water for more than three months. The Fe3O4 NPs were characterized by X-ray photoelectron spectra (XPS), X-ray powder diffraction (XRD), transmission electron microscope (TEM), and Fourier transform infrared spectroscopy (FT-IR). The saturation magn...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
Natural, formaldehyde-treated and copolymer-grafted orange peels were evaluated as adsorbents to remove lead ions from aqueous solutions. The optimum pH for lead adsorption was found to be pH 5. The adsorption process was fast, reaching 99% of sorbent capacity in 10 min for the natural and treated biomasses and 20 min for the grafted material. The treated biomass showed the highest sorption rate and capacity in the batch experiments, with the results fitting well to a pseudo-first order rate equation. In the continuous test with the treated biomass, the capacity at complete exhaustion was 46.61 mg g{sup -1} for an initial concentration of 150 mg L{sup -1}. Scanning electronic microscopy and energy dispersive X-ray spectroscopy indicated that the materials had a rough surface, and that the adsorption of the metal took place on the surface. Fourier transform infrared spectroscopy revealed that the functional groups responsible for metallic biosorption were the -OH, ...
2009-01-30
What will keep the lights on in Ontario: Responses to a policy short-circuit
Energy Technology Data Exchange (ETDEWEB)
Ontario's electricity industry restructuring program is reviewed, with a view to identify the reasons behind the failure of deregulation which was expected to create competition, to stabilize, or even reduce, prices to consumers, and attract serious private sector investment for the construction of new generating capacity. The report painstakingly reviews the series of events which resulted in a steep rise in electricity rates during the summer of 2002, immediately after deregulation came into effect, which led to freezing retail electricity rates and related charges by the then Conservative provincial government, and the reversal of that decision by the newly-elected Liberal government in the fall of 2003, and plans to bring back retail hydro rates that reflect the cost of production. The authors provide a discussion of policy options and a series of recommendations that are expected to create incentives to reduce and shift demand, encourage the use of more energy-efficient ...
2003-12-01
Two branches of research are conducted in this thesis. The first deals with nonlinear combustion response as a mechanism for triggering combustion instabilities in solid rocket motors. A nonlinear wave equation is developed to study a wide class of combustion response functions to second-order in fluctuation amplitude. Conditions for triggering are derived from analysis of limit cycles, and regions of triggering are found in parametric space. Introduction of linear cross-coupling and quadratic self-coupling among the acoustic modes appears to be how the nonlinear combustion response produces triggering to a stable limit cycle. Regions of initial conditions corresponding to stable pulses were found, suggesting that stability depends on initial phase angle and harmonic content, as well as the composite amplitude, of the pulse. Also, dependence of nonlinear stability upon system parameters is considered. The second part of this thesis presents research for a ...
1999-01-01
Energy Technology Data Exchange (ETDEWEB)
The paper addresses the major items of relevance to compensation for nuclear damage under civil liability law. The revision of the Vienna Convention deserves support as a contribution to enhancing the protection of those who suffered damage, and of the environment. The results of the revision will have an impact on the liability regimes in existing and future signatory states, and to some extent will also set the goals of a future reshaping of the Paris Convention, all the more since the Joint Protocol calls for harmonization of at least basic provisions of substantive law in the two Conventions. (orig./HP) [Deutsch] Es werden die wesentlichen Punkte dargestellt, die fuer die zivilrechtliche Praxis im Schadensfall von Belang sein koennten. Die Revision ist als Beitrag zu einem verbesserten Schutz Geschaedigter, aber auch der Umwelt zu begruessen und zu unterstuetzen. Die Ergebnisse werden sich auf die Rechtsordnungen der gegenwaertigen und zukuenftigen ...
1995-12-31
The controversy about '1/m{sub Q} duality violation': a quark model point of view
Energy Technology Data Exchange (ETDEWEB)
Non relativistic quark models have been invoked to support the statement of a 1/m{sub Q} duality violation in semileptonic B decays. However, as we recall, we have very explicitly shown that no 1/m{sub Q} duality violation is present in totally integrated rates, in such quark models. Then: 1) it is shown that some contributions under discussion are misleadingly described as '1/m{sub Q} duality violation'; as they stand, they are in fact parametrically much smaller: they are O((1/m{sub Q}){sup 5/2}) when properly referred to the total rate under discussion; numerically this is below 10{sup -2}; 2) moreover, relying on our rigorous expansion of the harmonic oscillator model around the Shifman-Voloshin limit, it is shown that even such small terms are not present at all in the total rate, and must therefore merely cancel; 3) finally, for physical masses, by an exact treatment of this particular, but not too unrealistic model, one finds a departure ...
2006-06-15
Survey of Radiation Protection Education and Training in Finland in 2003
Energy Technology Data Exchange (ETDEWEB)
The current state and need for radiation protection training in Finland have been surveyed by the Radiation and Nuclear Safety Authority STUK. The survey sought to determine whether the current requirements for radiation protection training had been met, and to promote radiation protection training. Details of the scope and quality of present radiation protection training were requested from all educational institutes and organizations providing radiation protection training. The survey covered both basic and further training, special training of radiation safety officers, and supplementary training. The questionnaire was sent to 77 educational organization units, 66 per cent of which responded. Radiation workers and radiation safety officers were asked about radiation protection knowledge and needs for additional training. The questionnaire was sent to 880 radiation users and 170 radiation safety officers, 70 per cent of whom responded. The survey covered all professional groups and ...
2004-07-01
Single-pass high-gain free electron laser electron beam diagnostics
International Nuclear Information System (INIS)
Consensus reached in the last few years that fourth generation light source will most likely be a X-ray or a UV coherent source based on single-pass high-gain free electron laser (FEL), such as Self Amplified Spontaneous Emission (SASE), or seeded high-gain harmonic-generation (HGHG) free electron lasers. High-gain (>10"7) required for single-pass FEL puts great constrain on the quality of electron beam, and demands detailed distribution information of electron beam in six-dimension. The typical accelerator system for single-pass FEL consists of a photocathode RF gun injection system, a linac and magnetic bunch compressors, and a long undulator. The major challenges in beam diagnostics for single-pass FEL are to characterize the pico-seconds high-brightness electron beam in six-dimension produced by photocathode RF gun injector, and improve the stability and reliability of the photocathode RF gun injection system. Characterization of short electron bunch ...
2000-11-27
Energy Technology Data Exchange (ETDEWEB)
After the transcription of the electricity directive in national legislations, the European electricity market appears to be a vast set of juxtaposed markets which are weakly connected at the level of their wholesale contracts compartment. Referring to the technological peculiarities of electricity as a commodity, the paper identifies the direct conditions of regional integration of the electricity markets, those which would favour cross-border trade and allow to be near the normal functioning of a regional commodity market. The infrastructure network dependence and the need of a stringent technical coordination necessitate to unify the operation of the different systems and the rules of access, or at the least to come near this unification by strong coordination. A second major condition, which is not fully debated, is the increasing connexion of short-term markets, via daily physical trade and emergence of a European financial market, which could trade various standardised contracts ...
2000-11-01
Reply to comments on the proposed on-road vehicle and engine emission regulations
Energy Technology Data Exchange (ETDEWEB)
In February 2001, the Minister of Environment Canada outlined a series of measures to be implemented over the next decades to reduce emissions from vehicles, engines and fuels. The agenda includes the development of new regulations under the authority of Part 7, Division 5 of the Canadian Environmental Protection Act (CEPA) to align Canada's emission standards for on-road vehicles with those of the United States Environmental Protection Agency. This paper presents a detailed summary of comments received by the interested parties that appeared at a public consultation in November 2001 to discuss and raise issues about the proposed regulations. The parties that provided submissions included: governments; the vehicle and engine manufacturing industry; the oil industry; other groups of associations such as the Canadian Trucking Alliance, David Suzuki Foundation, and West Coast Environmental Law; and, five private individuals. The report presents comments and replies from each ...
2002-12-01
Energy Technology Data Exchange (ETDEWEB)
This document is an executive summary of the colloquium organized by the French syndicate of renewable energies (SER) which took place at the Maison de l'UNESCO in Paris during the national debate on energies organized by the French government in spring 2003. The colloquium was organized around 6 round tables dealing with: the world perspectives and the environmental context of the contribution of renewable energies to the sustainable development (respect of Kyoto protocol commitments, contribution to the security of energy supplies, lack of large scale program of development of decentralized power generation in developing countries, lack of market tools linked with CO{sub 2} emissions, improvement of competitiveness); development of renewable energies in Europe (promotion and sustain in all European countries, obligation of supply and purchase, pricing regulation, European harmonization of practices); renewable electricity and its place in the new ...
2003-05-01
Energy Technology Data Exchange (ETDEWEB)
The high voltage/high power DC-cathode power supply for the Gyrotron Test Facility at the Forschungszentrum in Karlsruhe consists of a 12-pulse thyristor star-point-controller, a 130 kV capacitor-bank followed by a tetrode regulator. Originally designed for 80 kV/30 A CW (continous-wave) operation, its operating regime has been extended in line with gyrotron development to pulses of 65 kV/45 A/3 min and more recently to 65 kV/80 A/10 s without any changes to the main load bearing components (thyristors, transformers or power tetrode). This allows testing of gyrotrons in the 0.5 MW (CW), 1 MW (3 min) and 2 MW (10 s) output power range. The paper describes the system, its operation and some critical aspects of the last upgrade, such as the issue of harmonics in the 20 kV distribution mains-grid, the dynamic response of the thyristor-controller and the avoidance of microwave parasitic oscillations in the high power tetrode (a CQK-200-4, developed by ABB, Switzerland ...
2009-06-15
Normal-state conductance used to probe superconducting tunnel junctions for quantum computing
International Nuclear Information System (INIS)
Here we report normal-state conductance measurements of three different types of superconducting tunnel junctions that are being used or proposed for quantum computing applications: p-Al/a-AlO/p-Al, e-Re/e-AlO/p-Al, and e-V/e-MgO/p-V, where p stands for polycrystalline, e for epitaxial, and a for amorphous. All three junctions exhibited significant deviations from the parabolic behavior predicted by the WKB approximation models. In the p-Al/a-AlO/p-Al junction, we observed enhancement of tunneling conductances at voltages matching harmonics of Al-O stretching modes. On the other hand, such Al-O vibration modes were missing in the epitaxial e-Re/e-AlO/p-Al junction. This suggests that absence or existence of the Al-O stretching mode might be related to the crystallinity of the AlO tunnel barrier and the interface between the electrode and the barrier. In the e-V/e-MgO/p-V junction, which is one of the candidate systems for future superconducting qubits, we observed ...
2010-04-01
Inverse Bloch-oscillator: Strong Thz-photocurrent resonances at the Bloch frequency
Energy Technology Data Exchange (ETDEWEB)
We have observed resonant changes in the current-voltage characteristics of miniband semiconductor superlattices when the Bloch frequency is resonant with a terahertz field and its harmonics: the inverse Bloch oscillator effect. The resonant feature consists of a peak in the current which grows with increasing laser intensity accompanied by a decrease of the current at the low bias side. The peak position moves linearly with the laser frequency. When the intensity is increased further the first peak starts to decrease and a second peak at about twice the voltage of the first peak is observed due to a two photon resonance. At the highest intensities we observe up to a four photon resonance. A superlattice is expected to show negative differential conductance due to the strong nonparabolicity of the miniband. In this situation the carriers should undergo Bloch oscillations with a frequency {omega}{sub B} = eEd/h. Transient Bloch oscillations of photo excited carriers ...
1995-12-31
Energy Technology Data Exchange (ETDEWEB)
The adsorption of glycolate anions at sputtered gold thin-film electrodes was studied in perchloric acid solutions by cyclic voltammetry experiments combined with in situ Surface Enhanced Raman Scattering (SERS) and Surface Enhanced Infrared Reflection Absorption Spectroscopy under attenuated total reflection conditions (ATR-SEIRAS). Theoretical harmonic vibrational frequencies and band intensities obtained from B3LYP/LANL2DZ,6-31+G(d) calculations for glycolate species adsorbed on Au clusters with (1 1 1) orientation were used to interpret the experimental spectra. Vibrational data confirm the bidentate bonding of glycolate anions through the oxygen atoms of the carboxylate group, in a bridge configuration with the OCO plane perpendicular to the metal surface. The DFT calculations show no significant effect of the total charge of the metal cluster-adsorbate adduct on the vibrational frequencies of adsorbed glycolate species. The infrared experimental study is ...
2010-02-15
Energy Technology Data Exchange (ETDEWEB)
The computer program is developed based on Visual C++, which is equipped with a user-friendly interface of the input/output(I/O) and a display function for the measuring conditions. This program consists of three parts which are the port communication, PLC(Programmable Logic Controller) and the MCA(Multi Channel Analyzer) control parts. The communication type between the CPU of the PLC module box and the computer is selected as be the Rs-232 asynchronous type and the thread method is adapted in the development of the first part of the program. The PLC-related program has been developed so that the data communication between the PLC CPU and the computer could be harmonized with the unique commands which have already been defined in the PLC. The measuring space and time intervals, the start and end ROI(region of interest) values, and the allowable error limitation are input at each measurement in this program. Finally the controlling MCA program has been developed by ...
2005-11-15
Design and operating experience of a 40 MW, highly-stabilized power supply
Energy Technology Data Exchange (ETDEWEB)
Four 10 MW, highly-stabilized power supply modules have been installed at the National High Magnetic Field Laboratory in Tallahassee, FL, to energize water-cooled, resistive, high-field research magnets. The power supply modules achieve a long term current stability if 10 ppM over a 12 h period with a short term ripple and noise variation of <10 ppM over a time period of one cycle. The power supply modules can operate independently, feeding four separate magnets, or two, three or four modules can operate in parallel. Each power supply module consists of a 12.5 kV vacuum circuit breaker, two three-winding, step-down transformers, a 24-pulse rectifier with interphase reactors, and a passive and an active filter. Two different transformer tap settings allow rated dc supply output voltages of 400 and 500 V. The rated current of a supply module is 17 kA and each supply module has a one-hour overload capability of 20 kA. The isolated output terminals of each power supply module are ...
1995-07-01
Energy Technology Data Exchange (ETDEWEB)
This paper describes considerations given on factors affecting radon concentrations, and the radon concentration measurements in hot springs distributed in the northern part of Kumamoto Prefecture. As a result of analyzing radon concentration attenuation in the vertically upward direction using a diffusion equation, it was revealed that radon carrier gas velocities affect strongly the radon concentration, and the [sup 220]Rn source is limited to a very shallow bed below the ground surface. An inclined face was prepared against the [sup 222]Rn decay constant distribution using an inclined face analyzing method. The [sup 222]Rn concentration direction based on this inclined face harmonized approximately well with the hot spring distribution direction. Base rocks that well up hot springs were inferred to be granite from the concentration distribution and pH of chemical components in each hot spring. As a result of surveying joints and linearments in granite rocks ...
1993-02-01
Energy Technology Data Exchange (ETDEWEB)
A new thin film manufacturing method is established to add a function to glass material surface, as a new material technology which harmonizes with global environment, and is suitable for resource re-utilization and energy conservation. It is intended to develop a leading technology to promote recycling of colored glasses by applying this technical method to colored glasses. Fiscal 1998 has implemented subsequently to fiscal 1997 the following subjects in the three research items composed of a new manufacturing method of functional thin films, application of the functional thin films to colored glasses, and the comprehensive investigative studies: establishment of an industrial manufacturing method for color coating liquid and evaluation of basic characteristics of the colored functional thin films, optimization of element technology for photo-sensitive gel films by means of chemically modifying metallic alkoxide, tests of forming films on glass bottles and plate ...
1999-03-01
Development of a computerized portal verification scheme for pelvic treatment fields
International Nuclear Information System (INIS)
Purpose/Objective: At present, treatment verification between portal and reference images is performed based on manually-identified features by radiation oncologist, which is both time-consuming and potentially error-prone. There is a demand for the computerized verification procedure in clinical application. The purpose of this study is to develop a computerized portal verification scheme for pelvic treatment fields. Materials/Methods: The automated verification system involves image acquisition, image feature extraction, feature matching between reference and portal images and quantitative evaluation of patient setup. Electronic portal images with a matrix size of 256 x 256 and 12 bit gray levels were acquired using a liquid matrix electronic portal imaging device. Simulation images were acquired by digitizing simulation films using a TV camera into images with 256 x 256 matrix and 8 bit gray levels. Initially a Canny edge detector is applied to identify the field edges and an ...
1996-09-01
Energy Technology Data Exchange (ETDEWEB)
We present high-quality X-ray scattering experiments on pure water taken over a temperature range of 2 to 77 C using a synchrotron beam line at the advanced light source (ALS) at Lawrence Berkeley National Laboratory. The ALS X-ray scattering intensities are qualitatively different in trend of maximum intensity over this temperature range compared to older X-ray experiments. While the common procedure is to report both the intensity curve and radial distribution function(s), the proper extraction of the real-space pair correlation functions from the experimental scattering is very difficult due to uncertainty introduced in the experimental corrections, the proper weighting of OO, OH, and HH contributions, and numerical problems of Fourier transforming truncated data in Q-space. Instead, we consider the direct calculation of X-ray scattering spectra using electron densities derived from density functional theory based on real-space configurations generated with ...
2003-03-01
Uncertainty and Sensitivity of Alternative Rn-222 Flux Density Models Used in Performance Assessment
Energy Technology Data Exchange (ETDEWEB)
Performance assessments for the Area 5 Radioactive Waste Management Site on the Nevada Test Site have used three different mathematical models to estimate Rn-222 flux density. This study describes the performance, uncertainty, and sensitivity of the three models which include the U.S. Nuclear Regulatory Commission Regulatory Guide 3.64 analytical method and two numerical methods. The uncertainty of each model was determined by Monte Carlo simulation using Latin hypercube sampling. The global sensitivity was investigated using Morris one-at-time screening method, sample-based correlation and regression methods, the variance-based extended Fourier amplitude sensitivity test, and Sobol's sensitivity indices. The models were found to produce similar estimates of the mean and median flux density, but to have different uncertainties and sensitivities. When the Rn-222 effective diffusion coefficient was estimated using five different published predictive models, ...
2007-06-01
UNSAT-H Version 3.0: Unsaturated Soil Water and Heat Flow Model Theory, User Manual, and Examples
Energy Technology Data Exchange (ETDEWEB)
The UNSAT-H model was developed at Pacific Northwest National Laboratory (PNNL) to assess the water dynamics of arid sites and, in particular, estimate recharge fluxes for scenarios pertinent to waste disposal facilities. During the last 4 years, the UNSAT-H model received support from the Immobilized Waste Program (IWP) of the Hanford Site's River Protection Project. This program is designing and assessing the performance of on-site disposal facilities to receive radioactive wastes that are currently stored in single- and double-shell tanks at the Hanford Site (LMHC 1999). The IWP is interested in estimates of recharge rates for current conditions and long-term scenarios involving the vadose zone disposal of tank wastes. Simulation modeling with UNSAT-H is one of the methods being used to provide those estimates (e.g., Rockhold et al. 1995; Fayer et al. 1999). To achieve the above goals for assessing water dynamics and estimating recharge rates, the UNSAT-H model addresses ...
2000-06-12
Energy Technology Data Exchange (ETDEWEB)
Biodegradable and green plastics are the new tendency in the world. The effect of the electron beam irradiation in aromatic aliphatic copolyester and the blend with corn starch films (Ecoflex{sup R} and Ecobras{sup R}) were studied by tensile strength at break, elongation at break, Scanning Electronic Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FT-IR), Differential Scanning Calorimetry (DSC), crosslinking degree and biodegradability. The measurements in both, the machine direction and the transverse direction were made for mechanical tests. It was found that, the electron irradiation caused an increase in the strength at break of the blend with corn starch film, when doses of up to 10 kGy were applied. A significant decrease of the elongation at break of the blend with corn starch was observed at doses of 10 kGy and 40 kGy. It was not found important change in tensile properties for aromatic aliphatic copolyester. Structural changes of the samples ...
2008-07-01
International Nuclear Information System (INIS)
Biodegradable and green plastics are the new tendency in the world. The effect of the electron beam irradiation in aromatic aliphatic copolyester and the blend with corn starch films (Ecoflex"R and Ecobras"R) were studied by tensile strength at break, elongation at break, Scanning Electronic Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FT-IR), Differential Scanning Calorimetry (DSC), crosslinking degree and biodegradability. The measurements in both, the machine direction and the transverse direction were made for mechanical tests. It was found that, the electron irradiation caused an increase in the strength at break of the blend with corn starch film, when doses of up to 10 kGy were applied. A significant decrease of the elongation at break of the blend with corn starch was observed at doses of 10 kGy and 40 kGy. It was not found important change in tensile properties for aromatic aliphatic copolyester. Structural changes of the samples ...
Energy Technology Data Exchange (ETDEWEB)
Fourier transform infrared spectroscopy is a simple, fast, reliable and nondestructive analytical method. By using the method developed in Clark Atlanta University, consistent and reliable infrared spectral results can be obtained. An accurate radiant energy can be calculated from these infrared spectra by using a blackbody as the calibration standards. By means of the specially-designed-and-lab-made sampling inlet and the Horiba gas analyzers, the compositions of CO{sub 2}, CO, UCH, NOx and O{sub 2} etc. from the combustion exhaust gases have been on-line accurately analyzed. The commercial natural gas IR burner performed differently in the different conditions. For the methane-air combustion, at the equivalence ratio {Phi} = 1, the IR burner produced its maximum radiation efficiency, {approximately}31.4%, and the concentration of CO{sub 2} reached its maximum value, {approximately}10.7%. In the fuel-lean region, the O{sub 2} concentration in the emission gas ...
1997-03-31
Structures and properties of fluorinated amorphous carbon films
International Nuclear Information System (INIS)
Fluorinated amorphous carbon (a-C:F) films were deposited by radio frequency bias assisted microwave plasma electron cyclotron resonance chemical vapor deposition with tetrafluoromethane (CF_4) and acetylene (C_2H_2) as precursors. The deposition process was performed at two flow ratios R=0.90 and R=0.97, where R=CF_4/(CF_4+C_2H_2). The samples were annealed at 300 deg. C for 30 min. in a N_2 atmosphere. Both Fourier transform infrared and electron spectroscopy for chemical analyzer were used to characterize the a-C:F film chemical bond and fluorine concentration, respectively. A high resolution electron energy loss spectrometer was applied to detect the electronic structure. The higher CF_4 flow ratio (R=0.97) produced more sp"3 linear structure, and it made the a-C:F film smoother and softer. A lifetime of around 0.34 #mu#s and an energy gap of #approx#2.75 eV were observed in both the as-deposited and after annealing conditions. The short carriers lifetime in ...
2004-07-01
Space charge field in a FEL with axially symmetric electron beam
Energy Technology Data Exchange (ETDEWEB)
Nonlinear two-dimensional theory of the space charge of an axially symmetric electron beam propagating in combined right-hand polarized wiggler and uniform axial guide fields in a presence of high-frequency electromagnetic wave is presented. The well-known TE{sub 01} mode in a cylindrical waveguide for the model of radiation fields and paraxial approximation for the wiggler field are used. Space charge field components are written in the Lagrange coordinates by the twice averaged Green`s functions of two equally charged infinitely thin discs. For that {open_quotes}compensating charges{close_quotes} method is applied in which an electron ring model is substituted by one with two different radii and signs discs. On this approach the initial Green`s functions peculiarities are eliminated and all calculations are considerably simplified. Coefficients of a twice averaged Green`s function expansion into a Fourier series are obtained by use of corresponding expansion ...
1995-12-31
Energy Technology Data Exchange (ETDEWEB)
A number of high voltage cathode materials are now being considered for their ability to increase the energy density of lithium-ion batteries. In this study, a lithium-nickel composite alloy (LiNiVO{sub 4}) was synthesized using a rheological phase reduction method that incorporated mixtures of LiOH-H{sub 2}O, Ni(CH{sub 3}COO){sub 2}, 4H{sub 2}O, NH{sub 4}VO{sub 3} and C{sub 2}H{sub 2}O{sub 4}-2H{sub 2}O. The rheological phase method was used to prepare the compounds from a solid-liquid rheological mixture. Solid reactants were first mixed in a proper molar ratio, and water or solvents were added to the solid-liquid rheological body. X-ray powder diffraction (XRD) and Fourier Transform (FT) analyses were conducted to characterize the powders. Scanning electron microscopy (SEM) was used to characterize the morphological features and particle sizes of the powders. Results of the analyses indicated that the single-phase LiNiVO{sub 4} composite is capable of being ...
2008-08-15
We have measured the Raman isotropic profiles of the ?(C?N) band at 2235 cm(-1) for five solutions of ME6N (4-cyanophenyl-4'-hexylbenzoate) liquid crystal dissolved in CCl(4) in the range from x = 0.12 to 0.007 (x, mole fraction of ME6N) and then obtained the corresponding vibrational correlation functions, C(v)(t), by time Fourier transformation. The increase with dilution of the dephasing times ?(v) complies with the behavior of the nonmonotonic concentration dependence predicted by the fluctuation concentration model for this concentration range (x Rothschild, which, being based on the assumption that the environmental modulation is described by a stretched exponential decay e(-(t/?(0))(?)), is more appropriate for the interpretation of the vibrational correlation function arising from a distribution of relaxation processes caused, as in the present case, by the persistence of pseudonematic domains. With dilution the dispersion parameter ? and the average ...
2010-11-11
Radiation testing of organic ion exchange resins
International Nuclear Information System (INIS)
A number of ion exchange materials are being evaluated as part of the Tank Waste Remediation System (TWRS) Pacific Northwest Laboratory (PNL) Pretreatment Project for the removal of "1"3"7Cs from aqueous tank wastes. Two of these materials are organic resins; a phenol-formaldehyde resin (Duolite CS-100) produced by Rohm and Haas Co. (Philadelphia, Pennsylvania) and a resorcinol-formaldehyde (RF) resin produced by Boulder Scientific Co. (Mead, Colorado). One of the key parameters in the assessment of the organic based ion exchange materials is its useful lifetime in the radioactive and chemical environment that will be encountered during waste processing. The focus of the work presented in this report is the radiation stability of the CS-100 and the RF resins. The scope of the testing included one test with a sample of the CS-100 resin and testing of two batches of the RF resin (BSC-187 and BSC-210). Samples of the exchangers were irradiated with a "6"0Co source to a total absorbed dose ...
1983-04-11
Radiation testing of organic ion exchange resins
Energy Technology Data Exchange (ETDEWEB)
A number of ion exchange materials are being evaluated as part of the Tank Waste Remediation System (TWRS) Pacific Northwest Laboratory (PNL) Pretreatment Project for the removal of {sup 137}Cs from aqueous tank wastes. Two of these materials are organic resins; a phenol-formaldehyde resin (Duolite CS-100) produced by Rohm and Haas Co. (Philadelphia, Pennsylvania) and a resorcinol-formaldehyde (RF) resin produced by Boulder Scientific Co. (Mead, Colorado). One of the key parameters in the assessment of the organic based ion exchange materials is its useful lifetime in the radioactive and chemical environment that will be encountered during waste processing. The focus of the work presented in this report is the radiation stability of the CS-100 and the RF resins. The scope of the testing included one test with a sample of the CS-100 resin and testing of two batches of the RF resin (BSC-187 and BSC-210). Samples of the exchangers were irradiated with a {sup 60}Co source to a total ...
1995-09-01
Quantum dots for lasers, amplifiers and computing
Energy Technology Data Exchange (ETDEWEB)
For InAs-GaAs based quantum dot lasers emitting at 1300 nm, digital modulation showing an open eye pattern up to 12 Gb s{sup -1} at room temperature is demonstrated, at 10 Gb s{sup -1} the bit error rate is below 10{sup -12} at -2 dB m receiver power. Cut-off frequencies up to 20 GHz are realised for lasers emitting at 1.1 {mu}m. Passively mode-locked QD lasers generate optical pulses with repetition frequencies between 5 and 50 GHz, with a minimum Fourier limited pulse length of 3 ps. The uncorrelated jitter is below 1 ps. We use here deeply etched narrow ridge waveguide structures which show excellent performance similar to shallow mesa structures, but a circular far field at a ridge width of 1 {mu}m, improving coupling efficiency into fibres. No beam filamentation of the fundamental mode, low a-factors and strongly reduced sensitivity to optical feedback are observed. QD lasers are thus superior to QW lasers for any system or network. Quantum dot semiconductor ...
2005-07-07
Energy Technology Data Exchange (ETDEWEB)
Significant ion irradiation during film growth is required for the formation of cubic boron nitride (cBN) films. Meanwhile, a huge level of intrinsic stress possibly induced by the ion bombardment has been frequently reported to result in cracking and/or lack of adhesion of deposited cBN films. The present work has been performed to investigate the interfacial and/or the buffer layer structures with better matching to the cBN film by relaxation of the film stress using ion-beam-assisted deposition (IBAD). Boron nitride films have been synthesized on Si(100) wafer and tungsten carbide (WC) substrates by depositing boron vapor under simultaneous bombardment with nitrogen ions and nitrogen-argon mixture ions in the energy range of 0.5-10 keV. Cubic BN films with enhanced tribological properties have been explored by inserting a BN layer with various B/N compositions as a controlled buffer at the interface. Significant relaxation of the film stress has been observed for the buffer layer ...
1999-09-01
Photodegradation and photostabilization of weathered wood flour filled polyethylene composites
Wood plastic composites (WPCs) have gained popularity as building materials because of their usefulness in replacing solid wood in a variety of applications. These composites are promoted as being low-maintenance, high-durability products. However, it has been shown that WPCs exposed to weathering may experience a color change and/or loss in mechanical properties. An important requirement for building materials used in outdoor applications is the retention of their aesthetic qualities and mechanical properties during service life. Therefore, it is critical to understand the photodegradation mechanisms of WPCs exposed to UV radiation and to develop approaches to stabilize these composites against ultraviolet light. In this dissertation, the surface chemistries of weathered composites (both unstabilized and stabilized) as well as the effect of weathering on the color fade and the retention of mechanical properties were characterized. Since different methods of manufacturing WPCs lead to ...
2003-01-01
Energy Technology Data Exchange (ETDEWEB)
Blade fatigue life is an important element in determining the economic viability of the Vertical-Axis Wind Turbine (VAWT). A principal source of blade fatigue is thought to be the stochastic (i.e., random) aerodynamic loads created by atmospheric turbulence. This report describes the theoretical background of the VAWT Stochastic Aerodynamic Loads (VAWT-SAL) computer code, whose purpose is to numerically simulate these random loads, given the rotor geometry, operating conditions, and assumed turbulence properties. A Double-Multiple-Stream Tube (DMST) analysis is employed to model the rotor's aerodynamic response. The analysis includes the effects of Reynolds number variations, different airfoil sections and chord lengths along the blade span, and an empirical model for dynamic stall effects. The mean ambient wind is assumed to have a shear profile which is described by either a power law or a logarithmic variation with height above ground. Superimposed on this is a full 3-D ...
1991-09-01
Neutron-computer tomography using real-time neutron radiography
Energy Technology Data Exchange (ETDEWEB)
A real-time neutron radiography facility was constructed including the capability of neutron tomography. The neutron beam was measured for total neutron flux ((1.0 +/- 0.2) x 10/sup 11/ m/(m/sup 2/-sec)), gold cadmium ratio (52 +/- 3) and effective neutron temperature (83/sup 0/C +/- 8/sup 0/C). The angular divergence or nonparallelism of the neutron beam was measured to be 2.3/sup 0/ +/- 0.1/sup 0/ thereby providing a means of quantifying the collimator effectiveness. The resolution capabilities of both static film and real-time neutron radiographs were quantified using a Fourier transform algorithm to calculate the modulation transfer function of both types of radiographs. The contrast sensitivity of both types of radiographs. The contrast sensitivity of both types of radiographs was measured as 3.1% for film and 4.0% for real-time radiographs. Two tomography algorithms, the simultaneous iterative reconstruction technique (SIRT) and the convolution method, were ...
1986-01-01
Neutron-computer tomography using real-time neutron radiography
International Nuclear Information System (INIS)
A real-time neutron radiography facility was constructed including the capability of neutron tomography. The neutron beam was measured for total neutron flux ((1.0 +/- 0.2) x 10"1"1 m/(m"2-sec)), gold cadmium ratio (52 +/- 3) and effective neutron temperature (83"0C +/- 8"0C). The angular divergence or nonparallelism of the neutron beam was measured to be 2.3"0 +/- 0.1"0 thereby providing a means of quantifying the collimator effectiveness. The resolution capabilities of both static film and real-time neutron radiographs were quantified using a Fourier transform algorithm to calculate the modulation transfer function of both types of radiographs. The contrast sensitivity of both types of radiographs. The contrast sensitivity of both types of radiographs was measured as 3.1% for film and 4.0% for real-time radiographs. Two tomography algorithms, the simultaneous iterative reconstruction technique (SIRT) and the convolution method, were programmed on an Intellect 100 ...
1986-01-01
Investigating the formation mechanism of soot-like materials present in blast furnace coke samples
An attempt to gain an understanding of the formation mechanism of these 'soot-like' materials has been made by means of tracing the changes in the molecular-mass distribution and molecular structure of the NMP-extractable materials from an injectant coal as well as its partially gasified chars and its pyrolytic tars. Variations in the SEC chromatograms provide clues about changes in the apparent molecular-mass distributions of these NMP extracts. Results suggest that the build-up of 'soot-like' materials follows from the secondary reactions of tars evolved from the injectant coal. The likely secondary-reaction pathways have been probed by collating structural information on these NMP extracts. The time-resolved 13-16 and 22-25 min elution fractions from the SEC column have been characterized using UV fluorescence (UV F) spectroscopy. Greater concentrations of larger aromatic ring systems are found present in samples formed under conditions appearing ...
2008-09-15
Energy Technology Data Exchange (ETDEWEB)
This paper discusses spectral change in brown coal and bituminous coal as a result of low-temperature drying. The experiment used a Fourier transform infrared (FT-IR) spectroscopy disposed with an in-situ diffuse reflector as a water content measuring method. The FT-IR spectra of coal showed the existence of two types of adsorbed water. One of the two spectral peaks was thought to have been caused by isolated water molecules which may have been hydrogen bonded to hydrocarbon in the coal molecules and weakly bound. The other peak was thought to have been caused by water which may have been hydrogen bonded to functional groups such as hydroxyl groups in the coal molecules and strongly bound. Drying behavior in brown coal and bituminous coal showed the absorption peak at 3640 cm[sup -1] reducing faster than the absorption peak at 3360cm[sup -1]. Depressurized drying was found to be more effective than flowing nitrogen gas. The extent of absorption strength restoration ...
1993-01-29
Energy Technology Data Exchange (ETDEWEB)
The diminishing clean oil reserve is driving the search for new or improved ways to reduce the level of NSO-containing species found in high abundance in heavy crude oils. Hydrotreatment is the currently preferred technique to remove those polar species. Unfortunately, nitrogen-containing compounds cause coke formation on the surface of the hydrotreatment catalyst, leading to partial or complete deactivation. Here, positive- and negative-ion electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS) identify those nitrogen compounds that resist hydrotreatment. ESI preferentially ionizes polar (e.g., heteroatom-containing) species: basic molecules are detected as positive ions and acidic/neutral molecules as negative ions. FT-ICR MS resolves thousands of species in a single mass spectrum, allowing for unambiguous determination of elemental composition, C{sub c}H{sub h}N{sub n}O{sub o}S{sub s}, for identification of compound ...
2006-10-15
Energy Technology Data Exchange (ETDEWEB)
The purpose of this study was to correlate MR imaging findings with pathology in experimental hyperoxia-induced acute lung injury, which has similar pathology to diffuse alveolar damage (DAD). Seventeen Yorkshire pigs were studied. These animals were exposed to more than 80% oxygen for 24, 48, 72, and 96 hours in a sealed cage. The lungs were removed and inflated with air infused through the trachea, and then examined by both MRI and high-resolution CT (HRCT). T1-weighted spin-echo (T1WSE), T2-weighted fast (T2WFSE), and half-Fourier acquisition single-shot turbo spin-echo (HASTE) sequences were performed. Severity in MR findings and signal-to-noise ratios (SNR) on MR images were well correlated with pathological scores. CT values were also correlated well with pathologic scores. Abnormal SNR values were obtained from a pathological score of 5, whereas abnormal CT values were obtained from a pathological score of 15. Furthermore, significant differences in SNR were ...
2001-06-01
General formulation of neutron noise for fast reactor systems
Energy Technology Data Exchange (ETDEWEB)
A general space- and energy-dependent formalism is developed in order to analyze zero-power neutron noise experiments in fast reactor systems. A generalized dispersion equation is combined with theoretical expressions for the experimentally measured power spectral density and variance-to-mean ratio which makes it possible to express these quantities in terms of a double moment of the Laplace and Fourier transformed Green's function of a slowing-down operator rather than those of the full Boltzmann operator. Several spatial approximations are analyzed in the context of the general formalism. In each case, the power spectral density and variance-to-mean ratio are written in terms of an appropriate fast reactor dispersion law for the medium which can be calculated from the solution to a simple slowing-down equation. The resultant expression for the power spectral density are analyzed for various combinations of neutron migration descriptions, slowing-down ...
1982-01-01
Energy Technology Data Exchange (ETDEWEB)
With an objective to know coal condensation structure which has influence on coal conversion reaction, an attempt was made on quantitative evaluation of hydrogen bonding in coal. Using as test samples the VDC made from Taiheiyo coal swollen by tetralin and vacuum-dried, and its pyrolyzed char, DSC measurement and Fourier transform infrared spectroscopy (FT) were performed. An FT spectrum comparison revealed that the VDC swollen at 220{degree}C has the hydrogen bonding relaxed partly from the original coal. However, since the change is in a huge coal molecular structure restraining space, it has stopped at relaxation of the bonding energy without causing separation as far as free radicals. On the other hand, the DSC curve shows that the VDC has slower endothermic velocity than the original coal. In other words, the difference in heat absorption amounts in both materials is equivalent to the difference of enthalpy ({Delta} H) of both materials, which corresponds to ...
1996-10-28
Energy Technology Data Exchange (ETDEWEB)
Batch and dynamic flow biosorption studies were carried out using the waste biomass entrapped in silica-gel matrix for the removal of nickel(II) ions from synthetic solutions and real wastewater. Batch biosorption conditions were examined with respect to initial pH, S/L ratio, contact time, and initial nickel ion concentration. Zeta potential measurements showed that immobilized biosorbent was negatively charged in the pH range of 3.0-8.0. The immobilized biomass was found to possess relatively high biosorption capacity (98.01 mg g{sup -1}), and biosorption equilibrium was established in a short time of operation (5 min). The equilibrium data were followed by Langmuir, Freundlich, and Dubinin-Radushkevich isotherm models. Scanning electron microscope analysis was used to screen the changes on the surface structure of the waste biomass after immobilization and nickel(II) biosorption. Sorbent-sorbate interactions were confirmed by Fourier transform infrared ...
2009-04-30
Enhanced Activity of Nanocrystalline Zeolites for Selective Catalytic Reduction of NOx
Energy Technology Data Exchange (ETDEWEB)
Nanocrystalline zeolites with discrete crystal sizes of less than 100 nm have different properties relative to zeolites with larger crystal sizes. Nanocrystalline zeolites have improved mass transfer properties and very large internal and external surface areas that can be exploited for many different applications. The additional external surface active sites and the improved mass transfer properties of nanocrystalline zeolites offer significant advantages for selective catalytic reduction (SCR) catalysis with ammonia as a reductant in coal-fired power plants relative to current zeolite based SCR catalysts. Nanocrystalline NaY was synthesized with a crystal size of 15-20 nm and was thoroughly characterized using x-ray diffraction, electron paramagnetic resonance spectroscopy, nitrogen adsorption isotherms and Fourier Transform Infrared (FT-IR) spectroscopy. Copper ions were exchanged into nanocrystalline NaY to increase the catalytic activity. The reactions of ...
2006-12-31
Effects of inorganic cation templates on octahedral molecular sieves of manganese oxide
Five hydrated inorganic divalent cations, Mg[sup 2+], Co[sup 2+], Ni[sup 2+], Cu[sup 2+], and Zn[sup 2+], have successfully been used as templates for the synthesis of manganese oxide octahedral molecular sieves (OMS-1) having the todorokite structure. The OMS-1 samples have been well characterized by X-ray diffraction, differential scanning calorimetry, thermogravimetric analysis, scanning electron microscopy/energy dispersive X-ray studies, inductively coupled plasma analysis, electron paramagnetic resonance, Fourier transform infrared spectroscopy, thiosulfate titration, and cyclohexane sorption. Catalytic CO oxidation and 2-propanol decomposition were carried out. Results show that these OMS-1 samples with a tunnel size of about 6.9 angstroms are crystalline and chemically pure. They have the following formulas: Mg[sub 3.17]Mn[sub 5.05]O[sub 12] [center dot] 4.52H[sub 2]O, Co[sub 1.84]Mn[sub 5.59]O[sub 12] [center dot] 3.45H[sub 2]O, Ni[sub 1.64]Mn[sub ...
1994-11-30
Dynamic behaviour of dc double anode plasma torch at atmospheric pressure
International Nuclear Information System (INIS)
An original dc double anode plasma torch which provides a long-time and highly stable atmospheric plasma jet has been devised for the purpose of hazardous waste treatment. The arc fluctuations and dynamic behaviour of the argon and argon-nitrogen plasma jets under different operating conditions have been investigated by means of classical tools, such as the statistic method, fast Fourier transform (FFT) and correlation analysis. In our experiments, the takeover mode is identified as the fluctuation characteristic of the argon plasma jet while the restrike mode is typical in the argon-nitrogen plasma dynamic behaviour. In the case of pure argon, the FFT and correlation calculation results of electrical signals exhibit the only characteristic frequency of 150 Hz, which originates from the torch power and is independent of any change in the operating conditions. It indicates that the nature of fluctuations in an argon plasma jet is mainly induced by the undulation of ...
2007-07-07
Direct observation of ordered orbital of YTiO{sub 3} by the X-ray magnetic diffraction technique
Energy Technology Data Exchange (ETDEWEB)
X-ray magnetic diffraction (XMD) technique was applied to an orbital ordering compound of ferromagnetic YTiO{sub 3} for the first time. The orbital-magnetic form factor {mu} {sub L}(k) and the spin-magnetic form factor {mu} {sub S}(k) were independently measured by utilizing the LS separation ability of the XMD. The {mu} {sub L}(k) was measured for ten reciprocal-lattice points. No significant values of the {mu} {sub L}(k) were observed for most of the reciprocal-lattice points within the estimated statistical errors, which suggested quenching of the orbital moment. The {mu} {sub S}(k) was measured for 22 reciprocal-lattice points. Fourier synthesis of the {mu} {sub S}(k) gave the spin density distribution m {sub S}(r) in the real space. The obtained m {sub S}(r) map shows the characteristic feature of the electron distribution of 3d electron in the t{sub 2g} state of a Ti atom coordinated by O{sup 2-} ions, in which the electrons are distributed away from the ...
2005-08-15
Energy Technology Data Exchange (ETDEWEB)
The samples comprise the foliage of four pteridosperm-medullosalean plant fossil species of differing preservation states and one of a cordaitean species from two Canadian Maritime sub-basins of Carboniferous age (300 Ma; Sydney and Stellarton coalfields, Nova Scotia, respectively). Included in the sample set were some coal samples from Sydney Coalfield, along with published data for coal macerals for comparison. By applying Schulze's maceration process to the fossil foliage to obtain the cuticles, five sample forms evolved, viz. compressions, cuticles and fossilized cuticles, and acidic and alkaline solutions from Schulze's process, to which was added the Sydney coal samples as the sixth form. Area integration of the absorbance spectra from solid and liquid state Fourier transform infrared (FTIR) spectroscopy, produced functional chemical parameters which were organized into a data matrix of eight variables and 62 samples (8 x 62 matrix). ...
2010-12-15
Energy Technology Data Exchange (ETDEWEB)
Spectroscopic constants and absolute intensities from more than 2150 transitions belonging to 52 bands of 7 isotopic species of carbon dioxide have been determined using a multispectrum nonlinear least-squares fitting technique. The spectral data (0.01 cm{sup -1} resolution) were obtained at room temperature and low pressure (<10 Torr) using the McMath-Pierce Fourier transform spectrometer of the National Solar Observatory on Kitt Peak, Arizona. A natural sample of carbon dioxide with absorption path lengths between 24 and 385m were used in recording the spectra. The first measurements have been made of the theoretically predicted 2v{sub 2}{sup 2} 2+v{sub 3} {open_quotes}forbidden{close_quotes} band of {sup 12}CO{sub 2}. Two bands which have not been predicted so far, one belonging to {sup 13}CO{sub 2} and the other to {sup 13}C{sup 16}O{sup 18}O, have been identified. The measured line intensities obtained for each band have been analyzed to determine the ...
1995-12-31
Energy Technology Data Exchange (ETDEWEB)
Acidic constituents in crude oil are associated with the formation of stable emulsions during production and present a challenge for efficient oil recovery and processing. Acid molecules, including naphthenic acids and acidic sulfur in crude oil cause corrosion in refineries and pipelines. Naphthenic acids are also significant because of their surface activity and marginal water solubility, so that they may leach to wastewaters and cause adverse environmental effects. Acidic components of oil are not limited to carboxylic acids but also molecules that contain sulfur and nitrogen. As such, an improved understanding of the chemistry and physics of petroleum at the molecular level is needed in order to understand the range of problems associated with acidic oil components and to design better solutions. The applications of negative-ion electrospray ionization (ESI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) for speciation of acidic oil ...
2008-07-01
Energy Technology Data Exchange (ETDEWEB)
The reaction of ethanol on unreduced and H{sub 2}-reduced CeO{sub 2} and 1 wt% Pd/CeO{sub 2} has been investigated by steady state reactions, temperature programmed desorption (TPD), and in situ Fourier transform infrared (FT-IR) spectroscopy. Steady state reactions have shown a zero reaction order dependency for diatomic oxygen at and above 20%, while the addition of Pd to CeO{sub 2} decreases the apparent activation energy of the reaction from 75 kJ/mol on CeO{sub 2} alone to 40 kJ/mol (Pd/CeO{sub 2}). TPD experiments following ethanol adsorption on both CeO{sub 2} and Pd/CeO{sub 2} have shown desorption profiles corresponding to unreacted ethanol and various reaction and decomposition products (acetaldehyde, acetone, CO, CO{sub 2}, and methane). Ethanol conversion to reaction products was increased by the addition of Pd, from 15 to 30% on CeO{sub 2} and H{sub 2}-reduced CeO{sub 2}, to 71 and 63% on Pd/CeO{sub 2} and H{sub 2}-reduced Pd/CeO{sub 2}, respectively.
1999-09-10
Nuclear forensics support. Reference manual
International Nuclear Information System (INIS)
Illicit trafficking of nuclear and other radioactive material has been an issue of concern since the first seizures in the early 1990s. By the end of 2004 Member States had confirmed 540 cases, while about another 500 remain unconfirmed. Most of the confirmed cases have a criminal dimension, even if they were not for known terrorist purposes. The attacks of September 2001 in the USA dramatically emphasized the requirement for the enhanced control and security of nuclear and other radioactive material. In response to a resolution by the IAEA General Conference in September 2002 the IAEA has adopted an integrated approach to protection against nuclear terrorism. This brings together IAEA activities concerned with the physical protection of nuclear material and nuclear installations, nuclear material accountancy, detection and response to illicit nuclear trafficking, the security and safety of radioactive sources, emergency response measures - including pre-emergency measures in Member ...
International Nuclear Information System (INIS)
Power extraction using a dielectric-loaded (DL) waveguide is a way to generate high-power radio frequency (RF) waves for future particle accelerators, especially for two-beam-acceleration. In a two-beam-acceleration scheme, a low-energy, high-current particle beam is passed through a deceleration section of waveguide (decelerator), where the power from the beam is partially transferred to trailing electromagnetic waves (wakefields); then with a properly designed RF output coupler, the power generated in the decelerator is extracted to an output waveguide, where finally the power can be transmitted and used to accelerate another usually high-energy low-current beam. The decelerator, together with the RF output coupler, is called a power extractor. At Argonne Wakefield Accelerator (AWA), we designed a 7.8GHz power extractor with a circular DL waveguide and tested it with single electron bunches and bunch trains. The output RF frequency (7.8GHz) is the sixth harmonic ...
Sulfur behavior in chemical looping combustion with NiO/Al{sub 2}O{sub 3} oxygen carrier
Energy Technology Data Exchange (ETDEWEB)
Chemical looping combustion (CLC) is a novel technology where CO{sub 2} is inherently separated during combustion. Due to the existence of sulfur contaminants in the fossil fuels, the gaseous products of sulfur species and the interaction of sulfur contaminants with oxygen carrier are a big concern in the CLC practice. The reactivity of NiO/Al{sub 2}O{sub 3} oxygen carrier reduction with a gas mixture of CO/H{sub 2} and H{sub 2}S is investigated by means of a thermogravimetric analyzer (TGA) and Fourier Transform Infrared spectrum analyzer in this study. An X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and scanning electron microscope (SEM) are used to evaluate the phase characterization of reacted oxygen carrier, and the formation mechanisms of the gaseous products of sulfur species are elucidated in the process of chemical looping combustion with a gaseous fuel containing hydrogen sulfide. The results show that the rate of NiO reduction with ...
2010-05-15
International Nuclear Information System (INIS)
We have performed self-consistent (SC) band structure calculations for the A15 compounds V_3X and Nb_3X, X = Al, Ga, Si, Ge, and Sn, using the augmented-plane-wave (APW) method. Relativistic effects (except the spin-orbit interaction) have been included in each SC cycle, along with corrections to the usual muffin-tin approximation. The latter apply the APW wave functions outside of the muffin-tin spheres to compute the interstitial charge densities and potentials. The resulting interstitial potential has full cubic symmetry (no spherical averaging), although a spherically averaged muffin-tin form is retained inside the spheres. The final SC potentials were used to generate energies and wave functions on a cubic mesh of 35 k points in 1/48th of the Brillouin zone. These results were interpolated onto a finer mesh of 969 k points using a symmetrized Fourier method; the densities of states (DOS), N (E), were determined using tetrahedral integration. These accurate ...
Energy Technology Data Exchange (ETDEWEB)
A model system, described by the consistent Vlasov-Poisson equations under periodical boundary conditions, has been studied numerically near the point of a marginal stability. The power laws, typical for a system, undergoing a second-order phase transition, hold in a vicinity of the critical point: (i) A {proportional_to} -{theta}{sup {beta}}, {beta}=1.907{+-}0.006 for {theta} {<=} 0, where A is the saturated amplitude of the marginally-stable mode; (ii) {chi} {proportional_to} {theta}{sup -{gamma}} as {theta} {yields} 0, {gamma}={gamma}{sub -}=1.020{+-}0.008 for {theta} < 0, and {gamma}={gamma}{sub +}=0.995{+-}0.020 for {theta} > 0, where {chi}={partial_derivative}A/{partial_derivative}F{sub 1} at F{sub 1} {yields} 0 is the susceptibility to external drive of the strain F{sub 1}; (iii) at {theta}=0 the system responds to external drive as A {proportional_to} F{sub 1}{sup 1/{delta}}, and {delta}=1.544{+-}0.002. {theta}=(<v{sup 2}>-<v{sub ...
2000-08-01
Energy Technology Data Exchange (ETDEWEB)
Fatty acids such as stearic acid (SA), palmitic acid (PA), myristic acid (MA), and lauric acid (LA) are promising phase change materials (PCMs) for latent heat thermal energy storage (LHTES) applications, but high cost is the most drawback which limits the utility area of them in thermal energy storage. The use of fatty acids as form-stable PCM will increase their feasibilities in practical LHTES applications due to reduced cost of the energy storage system. In this regard, a series of fatty acid/poly(methyl methacrylate) (PMMA) blends, SA/PMMA, PA/PMMA, MA/PMMA, and LA/PMMA were prepared as new kinds of form-stable PCMs by encapsulation of fatty acids into PMMA which acts as supporting material. The blends were prepared at different mass fractions of fatty acids (50, 60, 70, 80, and 90% w/w) to reach maximum encapsulation ratio. All blends were subjected to leakage test by heating the blends over the melting temperature of the PCM. The blends that do not allow leakage of melted PCM ...
2008-02-15
Unsteady aerodynamic forces of a flapping wing.
The unsteady aerodynamic forces of a model fruit fly wing in flapping motion were investigated by numerically solving the Navier-Stokes equations. The flapping motion consisted of translation and rotation [the translation velocity (u(t)) varied according to the simple harmonic function (SHF), and the rotation was confined to a short period around stroke reversal]. First, it was shown that for a wing of given geometry with u(t) varying as the SHF, the aerodynamic force coefficients depended only on five non-dimensional parameters, i.e. Reynolds number (Re), stroke amplitude (Phi), mid-stroke angle of attack (alpha(m)), non-dimensional duration of wing rotation (Delta tau(r)) and rotation timing [the mean translation velocity at radius of the second moment of wing area (U), the mean chord length (c) and c/U were used as reference velocity, length and time, respectively]. Next, the force coefficients were investigated for a case in which typical values of these ...
2004-03-01
Environmental trace gas analysis by proton-transfer-reaction mass spectrometry (PTR-MS)
International Nuclear Information System (INIS)
The work presented here demonstrates the ability of proton-transfer-reaction mass spectrometry (PTR-MS) to perform fast-response measurements of volatile organic compounds (VOCs) (including methanol, acetonitrile, acetaldehyde, acetone, PAN-type compounds, alpha- and beta-pinene, nopinone and pinonaldehyde) at the pptv level and its versatile applicability in the field of environmental trace gas analysis. Laboratory and field experiments including various calibration techniques and intercomparisons with other measurement techniques such as gas chromatography, atmospheric pressure chemical ionization and Fourier transformation infrared spectroscopy were performed providing a first characterization of the PTR-MS instrument performance (sensitivity, detection limit, precision, accuracy). Typically a detection limit (S/N=2) of 50 pptv for a 10 s signal integration time, a precision of 5 % and an accuracy in the range between 10 and 25 % were observed. Due to its ...
Emplacement technology for the direct disposal of spent fuel into deep vertical boreholes
International Nuclear Information System (INIS)
In the early sixties it was decided to investigate salt formations on its suitability to host heat generating radioactive waste in Germany. In the reference repository concept consequently the emplacement of vitrified waste canisters in deep vertical boreholes inside a salt mine was considered whereas spent fuel should be disposed of in self shielding casks (type POLLUX) in horizontal drifts. The POLLUX casks, 65 t heavy carbon steel casks, will be laid down on the floor of a horizontal drift in one of the disposal zones to be constructed in the salt dome at the 870 m level. The space between casks and drift walls will be backfilled with crushed salt. The transport, the handling und the emplacement of POLLUX casks were subject of successfully performed demonstration and in situ tests in the nineties and resulted in an adjustment of the atomic law. The borehole disposal concept comprises the emplacement of unshielded canisters with vitrified HLW in boreholes with a diameter of 60 cm and ...
2008-09-01
Final Scientific EFNUDAT Workshop
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