to Cool Spots Hanford Fun Facts Classroom Projects Famous People of Hanford Counterintelligence Home Employee Responsibilities CI Information CI Resources Points of Contact...
This report fulfills the annual environmental release reporting requirements of US Department of Energy (DOE) Order 5400.1. This report provides supplemental information to the HanfordSite Environmental Report (PNNL-11795). The HanfordSite Environmental Report provides an update on the environmental status of the HanfordSite. The sitewide annual report summarizes the degree of compliance with applicable environmental regulations and informs the public concerning the impact of HanfordSite operations on the surrounding environment. Like the HanfordSite Environmental Report, this annual report presents a summary of the environmental releases from facilities and activities managed by the Fluor Daniel Hanford, Incorporated (FDH), and Bechtel ...
The Waste Management Project manages and integrates (non-TWRS) waste management activities at the site. Activities include management of Hanford wastes as well as waste transferred to Hanford from other DOE, Department of Defense, or other facilities. This work includes handling, treatment, storage, and disposal of radioactive, nonradioactive, hazardous, and mixed solid and liquid wastes. Major Waste Management Projects are the Solid Waste Project, Liquid Effluents Project, and Analytical Services. Existing facilities (e.g., grout vaults and canyons) shall be evaluated for reuse for these purposes to the maximum extent possible.
to Cool Spots Hanford Fun Facts Classroom Projects Famous People of Hanford Counterintelligence Home Employee Responsibilities CI Information CI Resources Points of Contact...
Separation of the bulk soluble chemical salts from the insoluble metal hydroxides and radionuclides is central to the strategy of disposing Hanford tank waste. Sludge washing and caustic leaching have been selected as the primary methods for processing the 230 million L (61,000,000 gal) of Hanford tank waste. These processes are very similar to those selected for processing waste at the West Valley Site in New York and the Savannah River Site in South Carolina. The purpose of sludge washing is to dissolve and remove the soluble salts in the waste. Leaching of the insoluble solids with caustic will be used to dissolve aluminum hydroxide and chromium hydroxide, and convert insoluble bismuth phosphate to soluble phosphate. The waste will be separated into a high-level solids fraction and a liquid fraction that can be disposed of as low-level waste after cesium removal. The washing and ...
This report is a summary of the environmental status of the HanfordSite in 1989. It includes descriptions of the Site and its mission, the status of compliance with environmental regulations, planning and activities to accomplish compliance, environmental protection and restoration activities, and environmental monitoring. 97 refs., 67 figs., 14 tabs.
Radioactively contaminated acidic aqueous wastes and organic liquids were discharged to the soil column at three disposal sites within the 200 West Area of the HanfordSite, Washington. As a result, a portion of the underlying groundwater is contaminated with carbon tetrachloride several orders of magnitude above the maximum contaminant level accepted for a drinking water supply. Treatability testing and cleanup actions have been initiated to remove the contamination from both the unsaturated soils to minimize further groundwater contamination and the groundwater itself. To expedite cleanup, innovative technologies for (1) drilling, (2) site characterization, (3) monitoring, (4) well field development, and (5) contaminant treatment are being demonstrated and subsequently used where possible to improve the rates and cost savings associated with the removal of carbon tetrachloride ...
This manual is a guide to the services provided by the Hanford Internal Dosimetry Program (IDP), which is operated by the Pacific Northwest National Laboratory.( ) for the U.S. Department of Energy Richland Operations Office, Office of River Protection and their HanfordSite contractors. The manual describes the roles of and relationships between the IDP and the radiation protection programs of the HanfordSite contractors. Recommendations and guidance are also provided for consideration in implementing bioassay monitoring and internal dosimetry elements of radiation protection programs.
'As part of the Computer Protection Plan, this Network Security Plan identifies the specific security measures used to protect Bechtel Hanford, Inc.'s (BHI's) enterprise network. The network consists of the communication infrastructure and information systems used by BHI to perform work related to the Environmental Restoration Contract (ERC) at the HanfordSite. It provides electronic communication between the ERC-leased facilities in Richland, Washington, and facilities located on the HanfordSite. Network gateways to other site and offsite networks provide electronic communication with the remainder of the Hanford community.'
The purpose of this interim remedial measures (IRM) proposed plan is to present and solicit public comments on the IRM planned for the 200-ZP-1 Operable Unit at the HanfordSite in Washington state. The 200-ZP-1 is one of two operable units that envelop the groundwater beneath the 200 West Area of the HanfordSite.
The HanfordSite in eastern Washington state currently is engaged in the largest waste cleanup in world history. In order to make informed decisions about remediation options, the public throughout the Pacific Northwest and the nation needs to understand the wastes that are present, their sources of generation, their composition, and their behavior in the environment. The fact that Hanford operations` were conducted in secret for over four decades presents a unique public information challenge to those who currently are responsible for communicating with the public.
Grout has been evaluated as a means of containing low-level radioactive waste for long-term disposal. Concerns about hydrogen and reactive gas generation in the HanfordSite grout disposal facility lead to the development of the G3 model, which has predicted buildup of radiolytically formed gases in the grout region and their migration to air-filled regions. The G3 model is a one-dimensional code that couples models of gas diffusion with two-phase gas and liquid flow. It was coupled to a compartment diffusion model and these models predicted the concentrations of hydrogen I nitrous oxide, and other gases in air-filled regions of the grout disposal facility. The results have served as the technical basis for safety studies. A unique finding of the G3 model was that a liquid return, or expulsion of unbound liquid from the grout region, could occur. This liquid ...
The Hanford Waste Vitrification Plant Project has been established to convert the high-level radioactive waste associated with nuclear defense production at the HanfordSite into a waste form suitable for disposal in a deep geologic repository. The Hanford Waste Vitrification Plant will mix processed radioactive waste with borosilicate material, then heat the mixture to its melting point (vitrification) to forin a glass-like substance that traps the radionuclides in the glass matrix upon cooling. The Hanford Waste Vitrification Plant Quality Assurance Program has been established to support the mission of the Hanford Waste Vitrification Plant. This Quality Assurance Program Description has been written to document the Hanford Waste Vitrification Plant Quality Assurance Program.
The purpose of the Hanford Waste Management Plan (HWMP) is to provide an integrated plan for the safe storage, interim management, and disposal of existing waste sites and current and future waste streams at the HanfordSite. The emphasis of this plan is, however, on the disposal of HanfordSite waste. The plans presented in the HWMP are consistent with the preferred alternative which is based on consideration of comments received from the public and agencies on the draft Hanford Defense Waste Environmental Impact Statement (HDW-EIS). Low-level waste was not included in the draft HDW-EIS whereas it is included in this plan. The preferred alternative includes disposal of double-shell tank waste, retrievably stored and newly generated TRU waste, one pre-1970 TRU solid waste site near the Columbia River and encapsulated ...
The founding of the Hanford Engineering Works to produce plutonium is described. The 45-year defense mission has now been replaced with a peaceful mission, that of being the first site for massive cleanup of the 45-year nuclear waste. In order to establish a remedial investigation and feasibility plan, a process of discovery named the Technical Baseline Report must be performed; the task of this process is to discover all that is known about a proposed cleanup site (what the waste was, where did it go). When none of the documentation can answer the question, oral history is utilized. Some of the problems associated with the conduct of oral history interviews are described, particularly Hanford`s legacy of secrecy.
This report represents the timetables, responsible organizations, and methods required to comply with the newly promulgated Washington Administrative Code (WAC) 173-360 Underground Storage Tank (UST) Regulations which became effective December 29, 1990. This report only addresses UST systems that contain nonradioactive material. A total of 84 tanks at the HanfordSite are currently regulated under WAC 173-360. In addition, 32 regulated tanks have been removed as a result of the federally mandated program and the newly implemented state regulations. The majority of the USTs at the HanfordSite are operated by Westinghouse Hanford; however, one is operated by Kaiser Engineers Hanford (KEH) and one by Pacific Northwest Laboratory (PNL).
More important than waste generation numbers, the pollution prevention and waste minimization successes achieved at Hanford in 1993 have reduced waste and improved operations at the Site. Just a few of these projects are: A small research nuclear reactor, unused and destined for disposal as low level radioactive waste, was provided to a Texas University for their nuclear research program, avoiding 25 cubic meters of waste and saving $116,000. By changing the slope on a asphalt lot in front of a waste storage pad, run-off rainwater was prevented from becoming mixed low level waste water, preventing 40 cubic meters of waste and saving $750,000. Through more efficient electrostatic paint spraying equipment and a solvent recovery system, a paint shop reduced hazardous waste by 3,500 kilograms, saving $90,800. During the demolition of a large decommissioned building, more than 90% of the building's material was recycled by crushing the concrete for ...
Radioactive waste has been stored in large underground storage tanks at the HanfordSite since 1944. Approximately 212 million liters of waste containing approximately 240,000 metric tons of processed chemicals and 177 mega-curies of radionuclides are now stored in 177 tanks. These caustic wastes are in the form of liquids, slurries, saltcakes, and sludge. In 1991, the Tank Waste Remediation System (TWRS) Program was established to manage, retrieve, treat, immobilize, and dispose of these wastes in a safe, environmentally sound, and cost-effective manner. The Department of Energy (DOE) has believes that it is feasible to privatize portions of the TWRS Program. Under the privatization strategy embodied in the Request for Proposal (RFP), DOE will purchase services from a contractor-owned, contractor-operated facility under a fixed-price contract. Phase I of the TWRS privatization strategy is a proof-of-concept/commercial ...
The Waste Sampling and Characterization Facility (WSCF) complex consists of the main structure (WSCF) and four support structures located in the 600 Area of the Hanfordsite east of the 200 West area and south of the Hanford Meterology Station. WSCF is to be used for low level sample analysis, less than 2 mRem. The Laboratory features state-of-the-art analytical and low level radiological counting equipment for gaseous, soil, and liquid sample analysis. In particular, this facility is to be used to perform Resource Conservation and Recovery Act (RCRA) of 1976 and Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) of 1980 sample analysis in accordance with U.S. Environmental Protection Agency Protocols, room air and stack monitoring sample analysis, waste water treatment process support, and contractor laboratory quality assurance checks. The samples to be analyzed contain ...
The Fast Flux Test Facility (FFTF)is a 400 MW (th) sodium-cooled fast flux test reactor located on the HanfordSite in southeastern Washington State. The FFTF is operated by the Westinghouse Hanford Company for the United States Department of Energy. The FFTF is a three loop plant designed primarily for the purpose of testing full-scale core components in an environment prototypic of future liquid metal reactors. The plant design emphasizes features to enhance this test capability, especially in the area of the core, reactor vessel, and refueling system. Eight special test positions are provided in the vessel head to permit contact instrumented experiments to be installed and irradiated. These test positions effectively divide the core into three sectors. Each sector requires its own In-Vessel Handling Machine (IVHM) to access all the core positions. Since the core and the in-vessel refueling components ...
The Fast Flux Test Facility (FFTF) is a 400-MWt, sodium-cooled reactor located on the HanfordSite near Richland, Washington, USA. The FFTF is owned by the U.S. Department of Energy and is operated by the Westinghouse Hanford Company. The FFTF was designed to test fuels and materials for use in liquid metal reactors. Since initial operation in 1982, anticipated breaches of experimental fuel pins have released fission products, including cesium, into the primary sodium. Because of its high volatility, cesium vaporizes into the cover gas space, where it condenses on components and equipment and is transported into the cover gas outlet. Because of the long half-life of "1"3"7Cs, these deposits result in long-term, local radiation levels that make contact maintenance difficult. Thus, a cesium trap was installed in FFTF to reduce the cesium level in the sodium. The trap could also permit a Run Beyond ...
The Fast Flux Test Facility (FFTF) is a liquid-metal-cooled test reactor located on the HanfordSite. The FFTF is the only reactor of this type designed and operated with the intent of meeting the licensing requirements of the Nuclear Regulatory Commission (NRC). Unique characteristics of the FFTF that present special challenges related to leak rate testing include thin wall containment vessel construction, cover gas systems that penetrate containment, and a low-pressure design basis accident. The successful completion in 1986 of the third FFTF Integrated Leak Rate Test (ILRT) five days ahead of schedule and 10% under budget was a major achievement for the Westinghouse Hanford Company. The success of this operational safety test was due in large part to a special local area network (LAN) of three IBM PC/XT computers that monitored the sensor data, calculated the containment vessel leak rate, and ...
An updated listing of the vascular plants of the HanfordSite is provided, along with discussions of how humans may interact with local plants and have influenced the regional flora. Based on examinations of herbarium collections at the Westinghouse Hanford Company, Pacific Northwest Laboratory, Washington State University, and Brigham Young University, 590 vascular plant species have been identified on or near the HanfordSite. This is more than twice the number of species on previously published lists of HanfordSite vascular plants. A review of the plant species that are currently listed as endangered, threatened, sensitive, or otherwise of concern to the Washington State Natural Heritage Program and the Federal Fish and Wildlife Service is included. Color photographs of selected species are included to aid identification. Lists are ...
Large quantities of organic chemicals used in reprocessing spent nuclear-fuels at the HanfordSite have accumulated in underground high-level radioactive waste tanks. The organic content of these tanks must he known so that the potential for hazardous reactions between organic components and sodium nitrate/nitrite salts in the waste can he evaluated. The solubilities of organic compounds described in this report will help determine if they are present in the solid phases (salt cake and sludges) as well as the liquid phase (interstitial liquor/supernate) in the tanks. The solubilities of five significant sodium salts of carboxylic acids and aminocarboxylic acids [sodium oxalate, formate, citrate, nitrilotriacetate (NTA) and ethylendiaminetetraacetate (EDTA)] were measured in a simulated supernate solution at 25 degrees C, 30 degrees C, 40 degrees C, and 50 degrees C.
The U.S. Department of Energy Order 435.1, Radioactive Waste Management, requires a disposal authorization statement authorizing operation (or continued operation) for low-level waste disposal facilities. In fulfillment of these requirements, a disposal authorization statement was issued on October 25, 1999, authorizing the HanfordSite to transfer, receive, possess, and dispose of low-level radioactive waste at the 200 East Area burial grounds and the 200 West Area burial grounds. One of the conditions is that monitoring plans for the 200 East Area and 200 West Area low-level burial grounds be written and approved by the Richland Operations Office. As a result of a record of decision for the HanfordSite Solid Waste Program and acceptance of the HanfordSite Solid Waste Environmental Impact Statement, the use of the low-level burial ground (LLBG) as a disposal ...
This is the ninth quarterly report as required by the Hanford Federal Facility Agreement and Consent Order (Ecology et al. 1990), also known as the Tri-Party Agreement, established between the US Department of Energy (DOE), the US Environmental Protection Agency (EPA), and the Washington State Department of Ecology (Ecology). The Tri-Party Agreement sets the plan and schedule for achieving regulatory compliance and cleanup of waste sites at the HanfordSite. This report covers progress for the quarter that ended June 30, 1991. A total of 87 milestones have been completed to date. 39 refs., 1 fig.
A large amount of radioactive waste has been stored safely at the Savannah River and Hanfordsites over the past 46 years. The aim of this report is to review the experimental corrosion studies at Savannah River and Hanford with the intention of identifying the types and rates of corrosion encountered and indicate how these data contribute to tank failure predictions. The compositions of the High-Level Wastes, mild steels used in the construction of the waste tanks and degradation-modes particularly stress corrosion cracking and pitting are discussed. Current concerns at the HanfordSite are highlighted.
The UNSAT-H model was developed at Pacific Northwest National Laboratory (PNNL) to assess the water dynamics of arid sites and, in particular, estimate recharge fluxes for scenarios pertinent to waste disposal facilities. During the last 4 years, the UNSAT-H model received support from the Immobilized Waste Program (IWP) of the HanfordSite's River Protection Project. This program is designing and assessing the performance of on-site disposal facilities to receive radioactive wastes that are currently stored in single- and double-shell tanks at the HanfordSite (LMHC 1999). The IWP is interested in estimates of recharge rates for current conditions and long-term scenarios involving the vadose zone disposal of tank wastes. Simulation modeling with UNSAT-H is one of the methods being used to provide those estimates (e.g., Rockhold et al. 1995; Fayer et ...
The U. S. Department of Energy (DOE) is required by Comprehensive Environmental Response, Compensation, and Liability Act of 1980 regulations to develop a conceptual understanding of potential contaminant releases from the HanfordSite based on an evaluation of existing data and known historical practices. Polychlorinated biphenyls (PCBs) are one environmental contaminant potentially released through leaks, spills, or disposal. This document presents a summary of selected relevant existing information, including environmental studies and HanfordSite analytical data.
The DEFENSE WASTE MANAGEMENT PROGRAM has been chartered by the Department of Energy (DOE) to receive, reduce, store, and maintain all radioactive defense waste generated by Hanford and received from offsite DOE contractors in a safe condition and in accordance with DOE and Westinghouse Hanford Company (WHC) standards. These activities are accomplished through the use of TRU retrievable storage sites, solid waste burial grounds, liquid waste storage tanks, capsule storage pools, and other low-level waste disposal methods. Continuous and/or periodic surveillance is maintained. Through the use of improved packaging methods, evaporator-crystallization and capsule production waste has been and continues to be put in a safe and economic storage condition pending future reprocessing or final disposition. For this Program Plan, the scope of Defense Waste Management programmatic activities has been organized ...
This ACDR was performed following completed of the Conceptual Design Report in July 1992; the work encompassed August 1992 to January 1994. Mission of the WRAP Module 2A facility is to receive, process, package, certify, and ship for permanent burial at the Hanfordsite disposal facilities the Category 1 and 3 contact handled low-level radioactive mixed wastes that are currently in retrievable storage at Hanford and are forecast to be generated over the next 30 years by Hanford, and waste to be shipped to Hanford from about DOE sites. This volume provides an introduction to the ACDR process and the scope of the task along with a project summary of the facility, treatment technologies, cost, and schedule. Major areas of departure from the CDR are highlighted. Descriptions of the facility layout and operations are included.
Environmental monitoring at the HanfordSite, located in southeastern Washington State, is conducted by Battelle Memorial Institute, Pacific Northwest Division, as part of its contract to operate the Pacific Northwest Laboratory (PNL) for the US Department of Energy. The data collected provide a historical record of radionuclide and radiation levels attributable to natural causes, worldwide fallout, and Hanford operations. Data are also collected to monitor several chemicals. Pacific Northwest Laboratory publishes an annual environmental report for the HanfordSite each calendar year. The HanfordSite Environmental Report for Calendar Year 1990 is a summary of offsite and onsite environmental monitoring data collected during 1990 by PNL`s Environmental Monitoring Program. The data summaries included in the annual report were created from ...
Environmental monitoring at the HanfordSite, located in southeastern Washington State, is conducted by Battelle Memorial Institute, Pacific Northwest Division, as part of its contract to operate the Pacific Northwest Laboratory (PNL) for the US Department of Energy. The data collected provide a historical record of radionuclide and radiation levels attributable to natural causes, worldwide fallout, and Hanford operations. Data are also collected to monitor several chemicals. Pacific Northwest Laboratory publishes an annual environmental report for the HanfordSite each calendar year. The HanfordSite Environmental Report for Calendar Year 1990 is a summary of offsite and onsite environmental monitoring data collected during 1990 by PNL's Environmental Monitoring Program. The data summaries included in the annual report were created ...
This document defines the quality system requirements for the US Department of Energy, Richland Operations Office (DOE-RL), Environmental Restoration (ER) Project at the HanfordSite. The Environmental Restoration Project Quality System Requirements for the HanfordSite integrates quality assurance requirements from the DOE Orders, the Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement), the Hanford Facility Resource Conservation and Recovery Act of 1976 (RCRA) Permit, and applicable Federal and Washington State regulations. This document, based on ten criteria, provides user organizations with the flexibility to incorporate only those criteria and paragraphs applicable to their specific scopes of work. The requirements of this document are to be applied based on a graded approach that takes into consideration the risk inherent in, as well ...
Environmental data were collected for most environmental media including air, Columbia River water, external radiation, foodstuffs (milk, beef, eggs, poultry, and produce) and wildlife (deer, fish, and game birds), as well as soil and vegetation samples. In general, offsite levels of radionuclides attributable to Hanford operations during 1979 were indistinguishable from background levels. The data are summarized in the following highlights. Air quality measurements of NO/sub 2/ in the vicinity of the HanfordSite and releases of SO/sub 2/ onsite were well within the applicable federal and state standards. Particulate air concentrations exceed the standards primarily because of agricultural activities in the area. Discharges of waste water from Hanford facilities in the Columbia River under the National Pollution Discharge Elimination System (NPDES) permit were all within the parameter limits on the ...
Testing was initiated in March 1991 and completed in November 1992 to determine the rate at which asphalt is biodegraded by microorganisms native to the HanfordSite soils. The asphalt tested (AR-6000, US Oil, Tacoma, Washington) is to be used in the construction of a diffusion barrier for the Hanford grout vaults. Experiments to determine asphalt biodegradation rates were conducted using three separate test sets. These test sets were initiated in March 1991, January 1992, and June 1992 and ran for periods of 6 months, 11 months, and 6 months, respectively. The experimental method used was one originally developed by Bartha and Pramer (1965), and further refined by Bowerman et al. (1985), that determined the asphalt biodegradation rate through the measurement of carbon dioxide evolved.
This presentation focuses on the steps taken by the Westinghouse Hanford Company to meet an accelerated schedule for configuration and implementation of the MULTI LIMS in a multiple laboratory environment. The Westinghouse Hanford Company purchased the MULTI LIMS Laboratory Information Management System in August, 1993. Hardware delivery began in October, 1993. Less than four months later, the initial configuration was released for use in two Westinghouse Hanford Company laboratories. Several major obstacles were overcome during implementation. These include information gathering for base table loading, user training, acceptance of the new system by users of a legacy system, and hardware configuration issues. In summary, steps needed to be taken to meet the accelerated implementation schedule of the MULTI LIMS at the HanfordSite. The obstacles faced were overcome through the ...
Concentrations of {sup 90}Sr and {sup 137}Cs in Carey`s balsamroot (Balsamorhiza careyana) and Gray`s desert parsley (Lomatium grayi) were similar to concentrations observed in other plants collected on the HanfordSite and from offsite locations surrounding the Site as part of annual HanfordSite surveillance. Observed concentrations may be attributed to historic fallout more than to HanfordSite emissions, although the observation that 200 Area plants had slightly higher concentrations of {sup 137}Cs than 100 Area plants is consistent with other monitoring data of radioactivity in soil and vegetation collected onsite. The present concentrations of {sup 90}Sr and {sup 137}Cs in balsamroot and parsley fluctuate around background levels with some of the higher observed concentrations of {sup 90}Sr found on the Fitzner/Eberhardt Arid Lands ...
The HanfordSite, Richland, Washington, contains over 1,500 identified waste sites and numerous groundwater plumes that will be characterized and remediated over the next 30 years. As a result of the Hanford Federal Facility Agreement and Consent Order, the US Department of Energy (DOE) has initiated a remedial investigation/feasibility study (RI/FS) at the 200-BP-1 operable unit. The 200-BP-1 RI/FS is the first Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) investigation on the HanfordSite that involves highly radioactive and chemically contaminated soils. The initial phase of site characterization was designed to assess the nature and extent of contamination associated with the source waste sites within the 200-BP-1 operable unit. Characterization activities consisted of drilling and ...
The objective of the Hanford Environmental Dose Reconstruction Project (HEDR) is to estimate the potential radiation doses received by people living within the sphere of influence of the HanfordSite. A potential critical pathway for human radiation exposure is through the consumption of waterfowl that frequent onsite waste-water ponds or through eating of fish, shellfish, and waterfowl that reside in/on the Columbia River and its tributaries downstream of the reactors. This document summarizes information on fish, shellfish, and waterfowl radiation contamination for samples collected by Hanford monitoring personnel and offsite agencies for the period 1945 to 1972. Specific information includes the types of organisms sampled, the kinds of tissues and organs analyzed, the sampling locations, and the radionuclides reported. Some tissue concentrations are also included. We anticipate that these yearly ...
The Hanford Cultural Resources Laboratory (HCRL) was established by the US Department of Energy Field Office, Richland (RL) in 1987 as part of Pacific Northwest Laboratory. The HCRL provides support for managing the archaeological, historical, and cultural resources of the HanfordSite, Washington, in a manner consistent with federal statutes and regulations. This report summarizes activities of the HCRL during fiscal year (FY) 1990. The HCRL responsibilities have been set forth in the Hanford Cultural Resources Management Plan (HCRMP) as a prioritized list of tasks. The task list guided cultural resources management activities during FY 1990 and is the outline for this report. In order, these tasks were to (1) conduct cultural resource reviews, (2) develop an archaeological resources protection plan, (3) monitor the condition of known archaeological sites, (4) plan a curation ...
The W-259 project will provide upgrades to the 2706-T/TA Facility to comply with Federal and State of Washington environmental regulations for secondary containment and leak detection. The project provides decontamination activities supporting the environmental restoration mission and waste management operations on the HanfordSite.
The purpose of this report is to summarize the assumptions, dose factors, consumption rates, and methodology used to evaluate potential radiation doses to persons who may eat contaminated wildlife or contaminated plants collected from the HanfordSite. This report includes a description of the number and variety of wildlife and edible plants on the HanfordSite, methods for estimation of the quantities of these items consumed and conversion of intake of radionuclides to radiation doses, and example calculations of radiation doses from consumption of plants and wildlife. Edible plants on the publicly accessible margins of the shoreline of the HanfordSite and Wildlife that move offsite are potential sources of contaminated food for the general public. Calculations of potential radiation doses from consumption of agricultural plants and farm animal products are ...
Commercially available melter technologies were tested during 1994-95 as part of a multiphase program to test candidate technologies for vitrification of the low-level waste (LLW) stream to be derived from retrieval and pretreatment of HanfordSite tank wastes. Seven vendors were selected for Phase 1 testing to demonstrate vitrification of a high sodium content liquid LLW simulant. The tested melter technologies included four Joule-heated melters, a carbon electrode melter, a combustion melter, and a plasma melter. Various dry and slurry melter feed preparation processes were also tested. Various feed material samples, product glass samples, and process offgas streams were characterized to provide data for evaluation of process decontamination factors and material mass balances for each vitrification technology. This report describes the melter mass balance evaluations and results for six of the Phase 1 LLW melter vendor ...
The Fast Flux Test Facility (FFTF) is a liquid-metal-cooled test reactor located on the Hanfordsite. A dual computer system has been developed to monitor the reactor cover gas to detect and characterize any fuel or test pin fission gas releases. The system acquires gamma spectra data, identifies isotopes, calculates specific isotope and overall cover gas activity, presents control room alarms and displays, and records and prints data and analysis reports. The fission gas monitor system makes extensive use of commercially available hardware and software, providing a reliable and easily maintained system. The design provides extensive automation of previous manual operations, reducing the need for operator training and minimizing the potential for operator error. The dual nature of the system allows one monitor to be taken out of service for periodic tests or maintenance without interrupting the overall system functions. A ...
Following revisions to the Tri-Party Agreement for HanfordSite cleanup, which specified vitrification for Complete melter feasibility and system operability immobilization of the low-level waste (LLW) tests, select reference melter(s), and establish reference derived from retrieval and pretreatment of the radioactive LLW glass formulation that meets complete systems defense wastes stored in 177 underground tanks, commercial requirements (June 1996). Available melter technologies were tested during 1994 to 1995 as part of a multiphase program to select reference Submit conceptual design and initiate definitive design technologies for the new LLW vitrification mission.
This report documents radionuclide air emission from the HanfordSite in 1997, and the resulting effective dose equivalent to the maximally exposed member of the public, referred to as the MEI. The report has been prepared in accordance with reporting requirements in the Code of Federal Regulations, Title 40, Protection of the Environment, Part 61, National Emissions Standards for Hazardous Air Pollutants, Subpart H, National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities. This report has also been prepared in accordance with the reporting requirements of the Washington Administrative Code Chapter 246-247, Radiation Protection-Air Emissions. The effective dose equivalent to the MEI from the HanfordSite`s 1997 point source emissions was 1.2 E-03 mrem (1.2 E-05 mSv), which is well below the 40 CFR 61 Subpart H regulatory limit of 10 mrem/yr. Radon ...
An independent chemical compatibility review of various wrapping and absorbent/padding materials was conducted to evaluate resistance to chemicals and constituents present in liquid waste from the Hanford underground tanks. These materials will be used to wrap long-length contaminated equipment when such equipment is removed from the tanks and prepared for transportation and subsequent disposal or storage. The materials studied were Cooley L18KU, Herculite, and Elephant Mat. The study concludes that these materials are appropriate for use in this application.
The objective of the Hanford Environmental Dose Reconstruction Project (HEDR) is to estimate the potential radiation doses received by people living within the sphere of influence of the HanfordSite. A potential critical pathway for human radiation exposure is through the consumption of waterfowl that frequent onsite waste-water ponds or through eating of fish, shellfish, and waterfowl that reside in/on the Columbia River and its tributaries downstream of the reactors. This document summarizes information on fish, shellfish, and waterfowl radiation contamination for samples collected by Hanford monitoring personnel and offsite agencies for the period 1945 to 1972. Specific information includes the types of organisms sampled, the kinds of tissues and organs analyzed, the sampling locations, and the radionuclides reported. Some tissue concentrations are also included. We anticipate that these yearly ...
The objective of the Hanford Environmental Dose Reconstruction Project (HEDR) is to estimate the potential radiation doses received by people living within the sphere of influence of the HanfordSite. A potential critical pathway for human radiation exposure is through the consumption of waterfowl that frequent onsite waste-water ponds or through eating of fish, shellfish, and waterfowl that reside in/on the Columbia River and its tributaries downstream of the reactors. This document summarizes information on fish, shellfish, and waterfowl radiation contamination for samples collected by Hanford monitoring personnel and offsite agencies for the period 1945 to 1972. Specific information includes the types of organisms sampled, the kinds of tissues and organs analyzed, the sampling locations, and the radionuclides reported. Some tissue concentrations are also included. We anticipate that these yearly ...
Recently, the Tri-Party Agreement (TPA) among the State of Washington Department of Ecology, U.S. Department of Energy (DOE) and the US Environmental Protection Agency (EPA) for the cleanup of the HanfordSite was renegotiated. The revised agreement specifies vitrification as the encapsulation technology for low level waste (LLW). A demonstration, testing, and evaluation program underway at Westinghouse Hanford Company to identify the best overall melter-system technology available for vitrification of HanfordSite LLW to meet the TPA milestones. Phase I is a {open_quotes}proof of principle{close_quotes} test to demonstrate that a melter system can process a simulated highly alkaline, high nitrate/nitrite content aqueous LLW feed into a glass product of consistent quality. Seven melter vendors were selected for the Phase I evaluation: joule-heated melters from GTS Duratek, ...
This document provides information on septic systems with a design capacity of greater than 14,500 gal/d and cribs submitted as requested by the Washington State Department of Ecology. Data for this submittal were taken from the Waste Information Database System (WIDS) and the Hanford Environmental Compliance Record (HECR) database. The current definition used in WIDS for an ''inactive facility'' is one that either no longer receives waste or plans to in the future. Information concerning the deactivation method for a facility is included when such information is available.
The environmental Restoration Remedial Action Quality Assurance Requirements Document (DOE/RL 90-28) defines the quality assurance program requirements for the US Department of Energy-Richland Field Office Environmental Restoration Remedial Action Program at the HanfordSite, Richland, Washington. This paper describes the objectives outlined in DOE/RL 90-28. The Environmental Restoration Remedial Action Program implements significant commitments made by the US Department of Energy in the Hanford Federal Facility Agreement and Consent Order entered into with the Washington State Department of Ecology and the US Environmental Protection Agency.
A testing program has been conducted by the Westinghouse Hanford Company to confirm the baseline waste form selection for use in Waste Receiving and Processing (WRAP) Module 2A. WRAP Module 2A will provide treatment required to properly dispose of containerized contact-handled, mixed low-level waste at the US Department of Energy HanfordSite in south-central Washington State. Solidification/stabilization has been chosen as the appropriate treatment for this waste. This work is intended to test cement-based, thermosetting polymer, and thermoplastic polymer solidification media to substantiate the technology approach for WRAP Module 2A. Screening tests were performed using the major chemical constituent of each waste type to measure the gross compatibility with the immobilization media and to determine formulations for more detailed testing. Surrogate materials representing each of the eight waste types were prepared in the ...
This report documents radionuclide air emissions from the HanfordSite in I998 and the resulting effective dose equivalent to the maximally exposed individual (MEI) member of the public. The report has been prepared in accordance with the Code of Federal Regulations, Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants (40 CFR SI), Subpart H, ''National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities,'' and with the Washington Administrative Code Chapter 246-247, Radiation Protection--Air Emissions. The federal regulations in 40 CFR 61, Subpart H; require the measurement and reporting of radionuclides emitted from Department of Energy facilities and the resulting offsite dose from those emissions. A standard of 10 mrem/yr effective dose equivalent (EDE) is imposed on them. The EDE to the MEI due to ...
The T Plant facilities in the 200-West Area of the Hanfordsite were constructed in the early 1940s to produce nuclear materials in support of national defense activities. T Plant includes the 271-T facility, the 221-T facility, and several support facilities (eg, 2706-T), utilities, and tanks/piping systems. T Plant has been recommended as the primary interim decontamination facility for the Hanfordsite. Project W-259 will provide capital upgrades to the T Plant facilities to comply with Federal and State of Washington environmental regulations for secondary containment and leak detection. This document provides an advanced conceptual design concept that complies with functional requirements for the T Plant Secondary Containment and Leak Detection upgrades.
Environmental monitoring has been conducted at the U.S. Department of Energy`s (DOE`s) HanfordSite in southeastern Washington State since 1945. Fish and wildlife have been monitored since 1945, however, a major emphasis on mammals did not occur until the 1970s. This report focuses on the 10-year period from 1983 through 1992. The objectives of this report are to evaluate {sup 90}Sr and {sup 137}Cs concentrations in Site wildlife populations and, when possible, evaluate trends in concentrations over this period of time. No distinct trends in radionuclide concentrations were apparent in most species sampled. Many measurements were at or below the analytical limit of detection. This evaluation found that concentrations of {sup 90}Sr in rabbit and deer bone were elevated in animals collected from areas adjacent to industrialized areas. Similarly, radionuclide concentrations in duck muscle from waterfowl collected at B Pond ...
This document defines the quality assurance program requirements for the US Department of Energy, Richland Field Office, Environmental Restoration program at the HanfordSite. This document integrates quality assurance requirements from US Department of Energy Orders, the Hanford Federal Facility Agreement and Consent Order, and applicable industry standards into a single source document for the development of quality assurance programs applicable to the Environmental Restoration program items and activities. This document has been configured into three parts and fifteen criteria to provide user organizations with a workable document that best facilitates line operations. When developing individual user organization quality assurance programs, the document configuration provides each organization with the Flexibility to incorporate only those parts and criteria that are applicable to their individual scope of work as it is ...
An aerial radiological survey was conducted over the Department of Energy's HanfordSite near Richland, Washington, during the period 5 July through 26 August 1988. The survey was expanded, and additional flights were conducted to the east of the site and along the banks of the Columbia River down to McNary Dam near Umatilla. The survey was flown at altitude of 61 meters (200 feet) by a helicopter containing 17 liters (eight 2 in. x 4 in. x 16 in.) of sodium iodide detectors. Gamma ray data were collected over the survey area by flying north-south lines spaced 122 meters (400 feet) apart. The processed data indicated that detected radioisotopes and their associated gamma ray exposure rates were generally consistent with those expected from normal background emitters and man-made fission/activation products resulting from activities at the site. External exposure rates were generally 10 microroentgens ...
The Fast Flux Test Facility (FFTF) is a 400-megawatt (thermal) sodium-cooled reactor designed for irradiation testing of fuels, materials and components for LMRs. It is operated by the Westinghouse Hanford Company for the US Department of Energy on the government-owned Hanford reservation near Richland, Washington. The first 100-day operating cycle began in April 1982 and the eighth operating cycle was completed in July 1986. Argon is used as the cover gas for all sodium systems at the plant. A program for cover gas monitoring has been in effect since the start of sodium fill in 1978. The argon is supplied to the FFTF by a liquid argon Dewar System and used without further purification.
This document describes the proposed strategy for disposal of spent and failed melters from the tank waste treatment plant to be built by the Office of River Protection at the Hanfordsite in Washington. It describes program management activities, disposal and transportation systems, leachate management, permitting, and safety authorization basis approvals needed to execute the strategy.
Software quality assurance (SQA) for robotic systems used in nuclear waste applications is vital to ensure that the systems operate safely and reliably and pose a minimum risk to humans and the environment. This paper describes the SQA approach for the control and data acquisition system for a robotic system being developed for remote surveillance and inspection of underground storage tanks (UST) at the HanfordSite.
The Fast Flux Test Facility (FFTF) is a liquid-metal-cooled, fast neutron test reactor located on the HanfordSite. A dual computer system has been developed to monitor the reactor cover gas to detect and characterize any fuel or test pin fission gas releases. The system acquires gamma spectra data, identifies isotopes, calculates specific isotope and overall cover gas activity, presents control room alarms and displays, and records and prints data and analysis reports. The Fission Gas Monitor System (FGMS) integrates commercially available hardware and software, providing a reliable and easily maintained system. The design provides extensive automation of previous manual operations, reducing the need for operator training and minimizing the potential for operator error. The dual nature of the system allows either system A or B to be taken out of service for periodic tests or maintenance without interrupting the overall ...
Plans for the disposal of radioactive liquid and solid wastes presently stored in double-shell tanks at the HanfordSite call for retrieval and processing of the waste to create forms suitable for permanent disposal. Waste will be retrieved from a tank using a submerged slurry pump in conjunction with one or more rotating slurry jet mixer pumps. Pacific Northwest Laboratory (PNL) has conducted tests using simulated waste slurries to assess the effects of a impinging slurry jet on the corrosion rate of the tank wall and floor, an action that could potentially compromise the tank's structural integrity. Corrosion processes were investigated on a laboratory scale with a simulated neutralized cladding removal waste (NCRW) slurry and in a subsequent test with simulated neutralized current acid waste (NCAW) slurry. The test slurries simulated the actual NCRW and NCAW both chemically and physically. The tests simulated ...
Plans for the disposal of radioactive liquid and solid wastes presently stored in double-shell tanks at the HanfordSite call for retrieval and processing of the waste to create forms suitable for permanent disposal. Waste will be retrieved from a tank using a submerged slurry pump in conjunction with one or more rotating slurry jet mixer pumps. Pacific Northwest Laboratory (PNL) has conducted tests using simulated waste slurries to assess the effects of a impinging slurry jet on the corrosion rate of the tank wall and floor, an action that could potentially compromise the tank`s structural integrity. Corrosion processes were investigated on a laboratory scale with a simulated neutralized cladding removal waste (NCRW) slurry and in a subsequent test with simulated neutralized current acid waste (NCAW) slurry. The test slurries simulated the actual NCRW and NCAW both chemically and physically. The tests simulated those ...
An ion exchange unit has been manufactured for WSRC by British Nuclear Fuels, Ltd. This unit consists of three columns, ancillary valving, pumps, lines, and computer controls. It has been delivered to TNX for use in testing a cesium-specific ion exchange resin, developed at WSRC as a potential second generation process for the decontamination of Defense Waste Processing Facility (DWPF) supernate. This resin also has Department of Energy applications at both Oak Ridge and Hanford. Oak Ridge is interested in decontaminating the Melton Valley storage tank supernate, while Hanford is interested in decontaminating the 101-AW and 101-SY supernate streams. Another potential developmental interest is the Savannah River Site (SRS) DWPF recycle stream. The three primary waste streams of interest are the Oak Ridge, Hanford, and SRS, SWPF supernate streams. For these three waste streams, the cesium decontamination ...
Over 360 distribution coefficients (KJ for cesium, iodine, selenium, Strontium, technetium, and uranium were measured in fiscal year 1998 using 20 sediments collected fkom borehole 299-El 7-21 on the HanfordSite as part of the Immobilized Low-Activity Waste-Performance Assessment (ILAW-PA). Additionally, the pH and cation-exchange capacity (a measure of the total quantity of cations that a sediment can adsorb) of these sediment samples were measured. The sediment samples originated from the Hanford formation (informal name). Statistical analyses, using Student's t-test and correlation were conducted with the measured values. There were no significant differences between layers 1 and 2 for the selenium, strontium, technetium, and uranium & values (statistics could not be applied to evaluate layer 3 &values). Significant differences between the cesium and iodine&values for layem 1 and 2 were observed. ...
Pacific Northwest National Laboratory and a group of expert collaborators are using the U.S. Department of Energy HanfordSite 300 Area uranium plume within the footprint of the 300-FF-5 groundwater operable unit as a site for an Integrated Field-Scale Subsurface Research Challenge (IFRC). The IFRC is entitled Multi-Scale Mass Transfer Processes Controlling Natural Attenuation and Engineered Remediation: An IFRC Focused on the HanfordSite 300 Area Uranium Plume Project. The theme is investigation of multi-scale mass transfer processes. A series of forefront science questions on mass transfer are posed for research that relate to the effect of spatial heterogeneities; the importance of scale; coupled interactions between biogeochemical, hydrologic, and mass transfer processes; and measurements/approaches needed to characterize and model a mass transfer-dominated system. This Quality ...
The technical baseline is a hierarchical description of the HanfordSite cleanup mission. This technical baseline does not address the science, technology, or economic transition missions. It begins with a definition of the existing conditions at the HanfordSite, provides a description of the end product or mission accomplishments at completion, presents a statement of the major requirements and constraints that must be observed during the performance of the mission, and provides a statement of the top-level strategic approach to accomplish the mission. Mission-level interfaces are also described. This information is further defined hierarchically in increasing levels of detail. This definition is composed of the following major elements: functions that are key task descriptions; requirements that are the measurable standards to which the functions must be performed; architectures which are specific ...
The Fast Flux Test Facility (FFTF) is a 400 MWt sodium-cooled fast reactor operated by Westinghouse Hanford Company for the US Department of Energy to conduct fuels and materials testing in support of the US Liquid Metal Fast Breeder Reactor programme. Early in 1982, the FFTF began its first 100 day irradiation cycle. Since that time the plant has operated very well, achieving a cycle capacity factor of 94 per cent in the most recent irradiation cycle. The authors describe the results achieved in the first three cycles of operation and carrying through to the fourth reactor cycle which began in January 1984. (author).
A novel device called the gas expansion model (GEM) is being developed at the Hanford Engineering Development Laboratory for testing in the 400-MW(th) fast flux test facility (FFTF) reactor. Incorporation of the GEM into liquid-metal reactor designs is intended to measurably contribute to the achievement of inherent safety, by allowing the reactor to passively shut down even in the extremely remote (hypothetical) event of an unprotected (no scram) loss-of-flow accident. The purpose of this paper is to describe the GEM and present predictive analyses of the effectiveness of the device during unprotected loss-of-flow experiments in the FFTF.
A novel device called the gas expansion model (GEM) is being developed at the Hanford Engineering Development Laboratory for testing in the 400-MW(th) fast flux test facility (FFTF) reactor. Incorporation of the GEM into liquid-metal reactor designs is intended to measurably contribute to the achievement of inherent safety, by allowing the reactor to passively shut down even in the extremely remote (hypothetical) event of an unprotected (no scram) loss-of-flow accident. The purpose of this paper is to describe the GEM and present predictive analyses of the effectiveness of the device during unprotected loss-of-flow experiments in the FFTF.
The Richland Operations Office (RL) and Office of River Protection (ORP) are pleased to issue the attached Pollution Prevention Progress Report. We have just met the most aggressive waste reduction and A recycling goals to date and are publishing this report to recognize A the site's progress, and to ensure it will sustain success beyond 1 Fiscal Year 2000. This report was designed to inform the been made by RL and ORP in Waste Minimization (WMin) and Pollution Prevention (P2). RL, ORP and their contractors are committed to protecting the environment, and we reiterate pollution prevention should continue to be at the forefront of the environmental cleanup and research efforts. As you read the attached report, we believe you will see a clear demonstration of RL and ORP's outstanding performance as it has been responsible and accountable to the nation, its employees, and the community in which we live and work. commitment that all employees have for ...
A major initiative to develop and irradiate a long-life, mixed-oxide fuel system in the Fast Flux Test Facility (FFTF) has been implemented by Westinghouse Hanford Company for the US Department of Energy. The FFTF, shown in Figures 1 and 2, is a 400 megawatt thermal, fast liquid metal reactor that tests liquid metal, space and fusion fuels and materials. The new fuel system, called the Core Demonstration Experiment (CDE) demonstrates the capability of achieving a three- to four-year life in a prototypic heterogeneous reactor environment under prototypic power and temperature conditions. This fuel system will greatly increase fuel performance and lifetime from the current standard FFTF driver fuel. New design features, fabrication development, CDE assembly fabrication, and irradiation status have been described.
The structural acceptance criteria contained herein for the evaluation of existing underground double-shell waste storage tanks located at the HanfordSite is part of the Life Management/Aging Management Program of the Tank Waste Remediation System. The purpose of the overall life management program is to ensure that confinement of the waste is maintained over the required service life of the tanks. Characterization of the present condition of the tanks, understanding and characterization of potential degradation mechanisms, and development of tank structural acceptance criteria based on previous service and projected use are prerequisites to assessing tank integrity, to projecting the length of tank service, and to developing and applying prudent fixes or repairs. The criteria provided herein summarize the requirements for the analysis and structural qualification of the existing double-shell tanks for continued operation. Code reconciliation ...
This Environmental Assessment evaluates the proposed action to operate two laboratory-size muffle furnaces in glovebox HC-21C, located in the Plutonium Finishing Plant (PFP), HanfordSite, Richland, Washington. The muffle furnaces would be used to stabilize chemically reactive sludges that contain approximately 25 kilograms (55 pounds) of plutonium by heating to approximately 500 to 1000{degrees}C (900 to 1800{degrees}F). The resulting stable powder, mostly plutonium oxide with impurities, would be stored in the PFP vaults. The presence of chemically reactive plutonium-bearing sludges in the process gloveboxes poses a risk to workers from radiation exposure and limits the availability of storage space for future plant cleanup. Therefore, there is a need to stabilize the material into a form suitable for long-term storage. This proposed action would be an interim action, which would take place prior to completion of an Environmental Impact ...
This report is an overview of current spent nuclear fuel management in the DOE complex. Sources of information include published literature, internal DOE documents, interviews with site personnel, and information provided by individual sites. Much of the specific information on facilities and fuels was provided by the DOE sites in response to the questionnaire for data for spent fuels and facilities data bases. This information is as accurate as is currently available, but is subject to revision pending results of further data calls. Spent fuel is broadly classified into three categories: (a) production fuels, (b) special fuels, and (c) naval fuels. Production fuels, comprising about 80% of the total inventory, are those used at Hanford and Savannah River to produce nuclear materials for defense. Special fuels are those used in a wide variety of research, development, and testing activities. Special ...
Wind tunnel tests were performed of three fugitive dust control agents derived from potato and sugar beet products. These materials are being considered for use as dust suppressants to reduce the potential for transport of radioactive materials by wind from radioactive waste construction and remediation sites. Soil and dust control agent type, solution concentrations, application quantities, aging (or drying) conditions, surface disturbance, and wind and saltating sand eolian erosive stresses were selected and controlled to simulate application and exposure of excavated soil surfaces in the field. A description of the tests, results, conclusions, and recommendations are presented in this report. The results of this study indicate that all three dust control agents can protect exposed soil surfaces from extreme eolian stresses. It is also clear that the interaction and performance of each agent with various soil types may differ dramatically. Thus, soils similar to ...
Six safety initiatives have been identified for accelerating the resolution of waste tank safety issues and closure of unreviewed safety questions. Safety Initiative 5 is to reduce safety and environmental risk from tank leaks. Item d of Safety Initiative 5 is to complete corrosion studies of single-shell tanks to determine failure mechanisms and corrosion control options to minimize further degradation by June 1994. This report has been prepared to fulfill Safety Initiative 5, Item d. The corrosion mechanisms that apply to HanfordSite single-shell tanks are stress corrosion cracking, pitting/crevice corrosion, uniform corrosion, hydrogen embrittlement, and microbiologically influenced corrosion. The corrosion data relevant to the single-shell tanks dates back three decades, when results were obtained from in-situ corrosion coupons in a few single-shell tanks. Since that time there have been intertank transfers, evaporation, and chemical ...
Prompted by a $10 million Congressional allocation to identify supplemental actions to protect the Columbia River from groundwater contamination beneath the Hanford Reservation, the U. S. Department of Energy (DOE) Environmental Management (EM) Office of Clean-up Technology identified twenty-three potential technical projects and then down-selected ten of these for further evaluation. An independent expert peer review was conducted for the ten down-selected proposals. The review panel consisted of twenty-three recognized subject matter experts that broadly represented academia, industry, and federal laboratories. Of the initial ten proposals reviewed, one was given unconditional support, six were given conditional support, and three were not supported as proposed. Three additional proposals were then submitted by DOE for review--these proposals were structured, in part, to respond to the initial round of technical peer review comments. Peer reviews of these ...
This document defines analytical services the Waste Sampling and Characterization Facility (WSCF) shall provide the Environmental Compliance Program (ECP) throughout calendar year (CY) 2000. Two organizations within ECP are responsible for monitoring liquid and gaseous effluents and the environment immediately around facilities that contain or may contain radioactive and hazardous materials. Monitoring & Reporting (M&R), of Fluor Hanford Environmental Services, is responsible for effluent monitoring data, and Environmental Monitoring & Investigations (EMI), of Waste Management Technical Services, Inc., for near-facility environmental monitoring data. These organizations serve numerous projects, some of which are managed by other companies such as CH2M HILL and Bechtel Hanford, Inc. Monitoring data are collected and evaluated to determine their state of compliance with applicable federal and state regulations ...
The Fast Flux Test Facility (FFTF) reactor, which started operating in 1982, is a 400 MWt sodium-cooled fast neutron reactor located in Hanford, Washington State, and operated by Westinghouse Hanford Co. under contract with U.S. Department of Energy. The reactor has a wide variety of functions for irradiation tests and special tests, and its major purpose is the irradiation of fuel and material for liquid metal reactor, nuclear reactor and space reactor projects. The review first describes major technical specifications and current conditions of the FFTF reactor. Then the plan for irradiation testing is outlined focusing on general features, fuel pin/assembly irradiation tests, and absorber irradiation tests. Assemblies for special tests include the material open test assembly (MOTA), fuel open test assembly (FOTA), closed loop in-reactor assembly (CLIRA), and other special fuel assemblies. An interim examination and ...
The Fast Flux Test Facility (FFTF) reactor, which started operating in 1982, is a 400 MWt sodium-cooled fast neutron reactor located in Hanford, Washington State, and operated by Westinghouse Hanford Co. under contract with U.S. Department of Energy. The reactor has a wide variety of functions for irradiation tests and special tests, and its major purpose is the irradiation of fuel and material for liquid metal reactor, nuclear reactor and space reactor projects. The review first describes major technical specifications and current conditions of the FFTF reactor. Then the plan for irradiation testing is outlined focusing on general features, fuel pin/assembly irradiation tests, and absorber irradiation tests. Assemblies for special tests include the material open test assembly (MOTA), fuel open test assembly (FOTA), closed loop in-reactor assembly (CLIRA), and other special fuel assemblies. An interim examination and ...
A vendor glass formulation study was carried out at Pacific Northwest Laboratory (PNL), supporting the Phase I and Phase II melter vendor testing activities for Westinghouse Hanford Company. This study is built upon the LLW glass optimization effort that will be described in a separate report. For Phase I vendor melter testing, six glass formulations were developed at PNL and additional were developed by Phase I vendors. All the doses were characterized in terms of viscosity and chemical durability by the 7-day Product Consistency Test. Twelve Phase II glass formulations (see Tables 3.5 and 3.6) were developed to accommodate 2.5 wt% P{sub 2}O{sub 5} and 1.0 wt% S0{sub 3} without significant processing problems. These levels of P{sub 2}O{sub 5} and SO{sub 3} are expected to be the highest possible concentrations from HanfordSite LLW streams at 25 wt% waste loading in glass. The Phase H compositions formulated were 6 to 23 ...
Census and environmental surveillance information on waterfowl that use the HanfordSite 200 Area waste water ponds are described and evaluated. Physical features of the ponds are discussed in relation to their use and suitability for waterfowl. Seasonal distributions observed for the years 1971 through 1974 indicate that the highest use by waterfowl occurs during the spring and fall migratory periods. Base population estimates are 300 to 400 resident waterfowl with a few tens of pairs nesting during the summer. Environmental surveillance data on "1"3"7Cs in muscle tissue are presented for the years 1971 through 1977. Comparisons are made between Columbia River and waste water pond waterfowl, between waterfowl groups, and among ponds. Waterfowl collected from ponds frequently have easily detected levels of "1"3"7Cs in muscle tissue. However, those waterfowl collected from the Columbia River seldom show a "1"3"7Cs level above that expected from ...
This report presents the status of development of a three-dimensional conceptual model for the unconfined aquifer system at Hanford. A conceptual model is needed to support development of a realistic three-dimensional numerical model for predicting ground-water flow and the transport of contaminants. The report focuses on developing a hydrogeologic framework, assessing available hydraulic property data, describing flow-system boundaries, and evaluating areal recharge and leakage. Geologic descriptions of samples obtained during well drilling were used to prepare cross sections that correlate relatively continuous layers. The layers were defined based on textural differences that are expected to reflect differences in hydraulic properties. Assigning hydraulic properties to the layers is a critical part of the conceptual model. Available hydraulic property data for the study area were compiled and were correlated with the geologic layers where possible. Flow-system ...
This document was requested by the Washington State Department of Ecology. Based on the State Underground Injection Control Program, as described in the Washington Administrative Code, French drains and reverse wells are being registered as Class V wells. Information on out-of-service French drains, out-of-service reverse wells, and out-of-service cribs that are deeper than their largest surface dimension is also provided. The data for this submittal were taken from the Waste Information Database System (WIDS) and the Hanford Environmental Compliance Record (HECR) database. The current definition used in WIDS for an ''inactive facility'' is one that either no longer receives waste or plans to in the future. The facilities listed in WIDS as inactive have all been listed as ''out-of-service.'' Information concerning the deactivation method for a facility is included when such information is ...
This document defines the quality assurance requirements for the US Department of Energy-Richland Operations Office Environmental Restoration Remedial Action program at the HanfordSite. The Environmental Restoration Remedial Action program implements significant commitments made by the US Department of Energy in the Hanford Federal Facility Agreement and Consent Order entered into with the Washington State Department of Ecology and the US Environmental Protection Agency. This document combines quality assurance requirements from various source documents into one set of requirements for use by the US Department of Energy-Richland Operations Office and other Environmental Restoration Remedial Action program participants. This document will serve as the basis for developing Quality Assurance Program Plans and implementing procedures by the participants. The requirements of this document will be applied to activities affecting ...
The Tank Waste Remediation System (TWRS) Program mission is to store, treat, and immobilize highly radioactive HanfordSite waste (current and future tank waste and the strontium/cesium capsules) in an environmentally sound, safe, and cost-effective manner. The scope of the TWRS Waste Pretreatment Program is to treat tank waste and separate that waste into HLW and LLW fractions and provide additional treatment as required to feed LLW and HLW immobilization facilities. Enhanced sludge washing was chosen as the baseline process for separating Hanford tank waste sludge. Section 1.0 briefly discusses the purpose of the evaluation plan and provides the background that led to the choice of enhanced sludge washing as the baseline process. Section 2.0 provides a brief summary of the evaluation plan details. Section 3.0 discusses, in some detail, the technical work planned to support the evaluation of enhanced sludge washing. ...
A pretreatment flowsheet was tested for separating key radionuclide components from the sludge stored in one of the high level waste tanks (B-110) at the HanfordSite; this sludge resulted primarily from the bismuth phosphate process, which was one of the three major plutonium separation processes used at Handford. This test involved (1) washing with water, (2) caustic leaching, (3) acid dissolution, (4) separation of transuranic elements (TRUs) by extraction with octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide(CMPO), (5) separation of Sr by extraction with di-t-butylcyclohexano-18-crown-6, (6) separation of Cs from the acid-dissolved sludge solution by treatment with ammonium molybdophosphate (AMP), and (7) separation of Cs from the sludge wash and caustic leach solutions by ion exchange using a phenol-formaldehyde resin (CS-100). The results of the radionuclide separation steps indicated that the proposed flowsheet is a viable ...
The Fast Flux Test Facility (FFTF) is a 400 Mw(t), loop-type, sodium-cooled, fast neutron reactor. It is operated by the Westinghouse Hanford Company for the United States Department of Energy at Richland, Washington. The FFTF is a multipurpose test reactor used to irradiate fuels and materials for programs such as Liquid Metal Reactor (LMR) research, fusion research, space power systems, isotope production and international research. FFTF is also used for testing concepts to be used in Advanced Reactors which will be designed to maximize passive safety features and not require complex shutdown systems to assure safe shutdown and heat removal. The FFTF also provides experience in the operation and maintenance of a reactor having prototypic components and systems typical of large LMR (LMFBR) power plants. The 5 year operational performance of the FFTF reactor is discussed in this report. 6 refs., 10 figs., 2 tabs.
The Fast Flux Test Facility (FFTF) is a 400 Mw(t), loop-type, sodium-cooled, fast neutron reactor. It is operated by the Westinghouse Hanford Company for the United States Department of Energy at Richland, Washington. The FFTF is a multipurpose test reactor used to irradiate fuels and materials for programs such as Liquid Metal Reactor (LMR) research, fusion research, space power systems, isotope production and international research. FFTF is also used for testing concepts to be used in Advanced Reactors which will be designed to maximize passive safety features and not require complex shutdown systems to assure safe shutdown and heat removal. The FFTF also provides experience in the operation and maintenance of a reactor having prototypic components and systems typical of large LMR (LMFBR) power plants. The 5 year operational performance of the FFTF reactor is discussed in this report. 6 refs., 10 figs., 2 tabs.
The Fast Flux Test Facility (FFTF) is a 400 Mwt sodium-cooled fast reactor operating at the Hanford Engineering Development Laboratory, Richland, Washington, to conduct fuels and materials testing in support of the US Liquid Metal Fast Breeder Reactor (LMFBR) program. Startup and initial power testing included a comprehensive series of nonnuclear and nuclear tests to verify the thermal, hydraulic, and neutronic characteristics of the plant. A specially designed series of natural circulation tests were then performed to demonstrate the inherent safety features of the plant. Early in 1982, the FFTF began its first 100-day irradiation cycle. Since that time the plant has operated very well, achieving a cycle capacity factor of 94% in the most recent irradiation cycle. Seventy-five specific test assemblies and 25,000 individual fuel pins have been irradiated, some in excess of 80 MWd/Kg.
This report to the Nuclear Regulatory Commission (NRC) describes the development and application of a methodology to systematically and quantitatively assess predictive uncertainty in groundwater flow and transport modeling that considers the combined impact of hydrogeologic uncertainties associated with the conceptual-mathematical basis of a model, model parameters, and the scenario to which the model is applied. The methodology is based on a n extension of a Maximum Likelihood implementation of Bayesian Model Averaging. Model uncertainty is represented by postulating a discrete set of alternative conceptual models for a site with associated prior model probabilities that reflect a belief about the relative plausibility of each model based on its apparent consistency with available knowledge and data. Posterior model probabilities are computed and parameter uncertainty is estimated by calibrating each model to observed system behavior; prior parameter estimates ...
This Maintenance Implementation Plan (MIP)was developed for implementation of the U.S. Department of Energy (DOE) Order 4330.4A, A Maintenance Implementation Program (DOE 1990) which has been replaced by 4330.4B (DOE 1994) at the HanfordSite SWM complex. It addresses maintenance functions associated with SWM, which includes the field operational group and the facilities operational group. An assessment of the existing maintenance programs for SWM was performed, and the results of this assessment were evaluated to determine corrective actions required to bring Solid Waste Maintenance into compliance with the order. The objective of this MIP is to provide baseline information for the control and execution of SWM Maintenance activities relative to the requirements of Order 4330.4B, Chapter II. (Nuclear Facilities) It also describes actions that are planned to achieve compliance. Section 2.0 of this MIP summarizes the mission, history, and future ...
The Savannah River Site has successfully used robots, teleoperators, and remote video to reduce exposure to ionizing radiation, improve worker safety, and improve the quality of operations. Previous reports have described the use of mobile teleoperators in coping with a high level liquid waste spill, the removal of highly contaminated equipment, and the inspection of nuclear reactor vessels. This report will cover recent applications at the Savannah River, as well as systems which SRS has delivered to other DOE site customers.
In early 2004, the U.S. Department of Energy (DOE) Richland and Fluor Hanford requested technical assistance from the DOE Headquarters EM-23 Technical Assistance Program to provide a team of technical experts to develop recommendations for mending the In Situ Redox Manipulation (ISRM) Barrier in the 100-D Area of the HanfordSite in Washington State. To accommodate this request, EM-23 provided support to convene a group of technical experts from industry, a national laboratory, and a DOE site to participate in a 2 1/2-day workshop with the objective of identifying and recommending options to enhance the performance of the 100-D Area reactive barrier and of a planned extension to the northeast. This report provides written documentation of the team's findings and recommendations. In 1995, a plume of dissolved hexavalent chromium [Cr(VI)], which resulted from operation of the D/DR Reactors at the ...
The 177 underground storage tanks at the DOE's HanfordSite contain an estimated 180 million tons of high-level radioactive wastes. It is desirable to remove and concentrate the highly radioactive fraction of the tank wastes for vitrification. Resorcinol-formaldehyde (R-F) resin, an organic ion-exchange resin with high selectivity and capacity for the cesium ion, which is a candidate ion-exchange material for use in remediation of tank wastes. The report includes information on the structure/function analysis of R-F resin and the synthetic factors that affect performance of the resin. CS-100, a commercially available phenol-formaldehyde (P-F) resin, and currently the baseline ion-exchanger for removal of cesium ion at Hanford, is compared with the R-F resin. The primary structural unit of the R-F resin was determined to consist of a 1,2,3,4-tetrasubstituted resorcinol ring unit while CS-100, was composed mainly of a ...
The operation of nuclear processing facilities and defense-related nuclear activities has resulted in contamination of near-surface and deep-subsurface sediments with both radionuclides and metals. The presence of mixed inorganic contaminants may result in undetectable microbial populations or microbial populations that are different from those present in uncontaminated sediments. To determine the impact of mixed radionuclide and metal contaminants on sediment microbial communities, we sampled a processing pond that was used from 1948 to 1975 for the disposal of radioactive and metal-contaminated wastewaters from laboratories and nuclear fuel fabrication facilities on the HanfordSite in Washington State. Because the HanfordSite is located in a semiarid environment with average rainfall of 159 mm/year, the pond dried and a settling basin remained after wastewater input into the pond ceased in 1975. ...
The Rotary Mode Core Sample System (RMCSS) is used to obtain stratified samples of the waste deposits in single-shell and double-shell waste tanks at the HanfordSite. The samples are used to characterize the waste in support of ongoing and future waste remediation efforts. Four sampling trucks have been developed to obtain these samples. Truck I was the first in operation and is currently being used to obtain samples where the push mode is appropriate (i.e., no rotation of drill). Truck 2 is similar to truck 1, except for added safety features, and is in operation to obtain samples using either a push mode or rotary drill mode. Trucks 3 and 4 are now being fabricated to be essentially identical to truck 2.
This document describes an educational program designed to provide a pool of highly qualified administrative, technical, and managerial graduates that are familiar with the HanfordSite and business operations. The program is designed to provide work experience and mentoring to a culturally diverse student base which enhances affirmative employment goals. Short-term and long-term objectives of the program are outlined in the report, and current objectives are discussed in more detail. Goals to be completed by the year 2003 are aimed at defining the criteria necessary to establish partnerships between schools, community organizations, and human resources departments. Actions to be implemented includes providing instructors and equipment, enhancing skills of local teachers, and establishing collaboration with human resources organizations. Long-term goals of the program are to ensure a constant supply of qualified, trained workers to support ...
The magnetic and electronic properties of non-Fermi liquid UCu{sub 4Pd} depend on annealing conditions. Local structural changes due to this annealing are reported from UL{sub III}- and Pd K-edge x-ray absorption fine-structure measurements. In particular, annealing decreases the fraction of Pd atoms on nominally Cu 16e sites and the U-Cu pair-distance distribution width. This study provides quantitative information on the amount of disorder in UCu{sub 4Pd} and allows an assessment of its possible importance to the observed non-Fermi liquid behavior.
Concern for the environment and cost reduction are driving forces for a broad effort in government and the private sector to develop new, more cost-effective technologies for characterizing, monitoring and remediating environmental sites. Secondary goals of the characterization, monitoring and remediation (CMR) activity are: minimize secondary waste generation, minimize site impact, protect water tables, and develop methods/strategies to apply new technologies. The Sandia National Laboratories (SNL) project in directional boring for CMR of waste sites with enhanced machinery from the underground utility installation industry was initiated in 1990. The project has tested a variety of prototype machinery and hardware built by the industrial partner, Charles Machine Works (CMW), and SNL at several sites (Savannah River Site (SRS), Hanford, SNL, Kirtland AFB (KAFB), ...
Developing and deploying innovative environmental cleanup technologies is an important goal for the U.S. Department of Energy (DOE), which faces challenging remediation problems at contaminated sites throughout the United States. Achieving meaningful, constructive stakeholder involvement in cleanup programs, with the aim of ultimate acceptance of remediation decisions, is critical to meeting those challenges. DOE`s Office of Technology Development sponsors research and demonstration of new technologies, including, in the past, the Volatile Organic Compounds Arid Site Integrated Demonstration (VOC-Arid ID), hosted at the HanfordSite in Washington State. The purpose of the VOC-Arid ID has been to develop and demonstrate new technologies for remediating carbon tetrachloride and other VOC contamination in soils and ground water. In October 1994 the VOC-Arid ID became a part of the Contaminant Plume ...
Potential maximum radiation dose rates over a 1,000-year time horizon were calculated for exposure to the decontaminated concrete removed from the 183-H Solar Evaporation Basins at the HanfordSite, Richland, Washington. The RESRAD computer code, Version 5.62, which implements the methodology described in the US Department of Energy`s manual for developing residual radioactive material guidelines, was used in this evaluation. Currently, the concrete is not being used. Four potential exposure scenarios were developed for the land area where the decontaminated concrete will be stored. In Scenario A industrial use of the land is assumed; in Scenario B recreational use of the land is assumed; in Scenario C residential use of the land is assumed; and in Scenario D (a plausible but unlikely land-use scenario), the presence of a subsistence farmer in the immediate vicinity of the land is assumed. For Scenarios A and B, water used for drinking is ...
A new opportunity to improve the safety and efficiency of environmental restoration operations, using robotics has emerged from advances in industry, academia, and government labs. Self-Guided Vehicles (SGV`s) have recently been developed in industry and early systems have already demonstrated much, though not all, of the functionality necessary to support driverless transportation of waste within and between processing facilities. Improved materials databases are being developed by at least two DOE remediation sites, the Fernald Environmental Management Project (FEME) in the State of Ohio and the Hanford Complex in the State of Washington. SGV`s can be developed that take advantage of the information in these databases and yield improved dispatch, waste tracking, report and shipment documentation. In addition, they will reduce the radiation hazard to workers and the risk of damaging containers through accidental collision. In this document, ...
The US Department of Energy (DOE) Defense Waste Management Plan has the objective of final disposal for high-level waste (HLW) generated from defense programs. The DOE sites that generate HLW are located at the Savannah River Operations Office in Aiken, South Carolina, the Hanfordsite in Richland, Washington, and the Idaho Operations Office in Idaho Falls, Idaho. The purpose in the development of a quality assurance (QA) specification for organizations involved in HLW production is to establish uniform requirements that ensure that radioactive waste is converted to a waste form and canistered in such a way that it is acceptable in a federal repository licensed by the US Nuclear Regulatory Commission (NRC). A QA specification has been developed that will be applied to those activities important to certification of the product. The basic requirements are defined in national consensus standards and DOE directives. The ...
Waste Management Area U (WMA U) includes the U Tank Farm, is currently regulated under RCRA interim-status regulations, and is scheduled for closure probably post-2030. Groundwater monitoring has been under an evaluation program that compared general contaminant indicator parameters from downgradient wells to background values established from upgradient wells. One of the indicator parameters, specific conductance, exceeded its background value in one downgradient well triggering a change from detection monitoring to a groundwater quality assessment program. The objective of the first phase of this assessment program is to determine whether the increased concentrations of nitrate and chromium in groundwater are from WMA U or from an upgradient source. Based on the results of the first determination, if WMA U is not the source of contamination, then the site will revert to detection monitoring. If WMA U is the source, then a second part of the groundwater quality ...
The Pacific Northwest National Laboratory (PNNL) operates a number of research and development (R and D) facilities for the Department of Energy on the HanfordSite. According to DOE Order 5400.1, a Facility Effluent Monitoring Plan is required for each site, facility, or process that uses, generates, releases, or manages significant pollutants or hazardous materials. Three of the R and D facilities: the 325, 331, and 3720 Buildings, are considered major emission points for radionuclide air sampling and thus individual Facility Effluent Monitoring Plans (FEMPs) have been developed for them. Because no definition of ''significant'' is provided in DOE Order 5400.1 or the accompanying regulatory guide DOE/EH-0173T, this FEMP was developed to describe monitoring requirements in the DOE-owned, PNNL-operated facilities that do not have individual FEMPs. The remainder of the DOE-owned, ...
The NATO Advanced Research Workshop on Nuclear Submarine Decommissioning and Related Problems was held in Moscow June 19--22, 1995. It was preceded by a visit to the Zvezdotchka Shipyard at Severodvinsk, a repair and maintenance yard for Russian nuclear submarines, for a subgroup of the workshop attendees. Most of the material in this paper is drawn directly form the workshop proceedings. Slightly less than 500 nuclear ships and submarines (the vast majority are submarines) have been constructed by the countries with nuclear navies. This includes approximately 250 by Russia, 195 by the United States, 23 by the United Kingdom, 11 by France and 6 by China. By the year 2000 it is expected that approximately one-half of these nuclear vessels will be removed from service and in various states of decommissioning. A newspaper account in June 1997 indicated that 156 Russian nuclear submarines had been removed from service. In August 1996 it was reported that 55 reactor compartment sections ...
In this paper, we evaluate the performance of the 1- and 5-site models of methane on the description of adsorption on graphite surfaces and in graphitic slit pores. These models have been known to perform well in the description of the fluid-phase behavior and vapor-liquid equilibria. Their performance in adsorption is evaluated in this work for nonporous graphitized thermal carbon black, and simulation results are compared with the experimental data of Avgul and Kiselev (Chemistry and Physics of Carbon; Dekker: New York, 1970; Vol. 6, p 1). On this nonporous surface, it is found that these models perform as well on isotherms at various temperatures as they do on the experimental isosteric heat for adsorption on a graphite surface. They are then tested for their performance in predicting the adsorption isotherms in graphitic slit pores, in which we would like to explore the effect of confinement on the molecule packing. Pore widths of 10 and 20 ...
The behavior of melter feed (a mixture of nuclear waste and glass-forming additives) during waste-glass processing has a significant impact on the rate of the vitrification process. We studied the effects of silica particle size and sucrose addition on the volumetric expansion (foaming) of a high-alumina feed and the rate of dissolution of silica particles in feed samples heated at 5 C/min up to 1200 C. The initial size of quartz particles in feed ranged from 5 to 195 {micro}m. The fraction of the sucrose added ranged from 0 to 0.20 g per g glass. Extensive foaming occurred only in feeds with 5-{micro}m quartz particles; particles {ge}150 {micro}m formed clusters. Particles of 5 {micro}m completely dissolved by 900 C whereas particles {ge}150 {micro}m did not fully dissolve even when the temperature reached 1200 C. Sucrose addition had virtually zero impact on both foaming and the dissolution of silica particles. Over 100 sites in the United States are currently ...
Most of the low-level liquid radioactive wastes generated from PWR plants are classified into high or low total suspended solid(HTDS or LTDS), radio-chemical waste and radioactive laundry waste. Although the evaporation process has a high decontamination ability, it has several problems such as corrosion, foaming, and congestion. A new liquid waste disposal process using the ion-exchange demineralizer(IED) has been introduced into the Yonggwang NPP 5 and 6 to complement the current evaporation process. To determine the differences, these two methods have been compared in this study. Those aspects compared here were the released radioactivity volume of the liquid radioactive wastes, The dose of off-site residents, the decontamination factor, and the amount of the solid radioactive wastes. While it was expected that the liquid radioactive waste volume in the evaporating system would ...
The FFTF is a 400-MWt sodium-cooled fast neutron flux test reactor located on the US government-owned HanfordSite in southeastern Washington state. The reactor is operated for the US Department of Energy by the Westinghouse Hanford Company. Since FFTF started routine operation in 1982, the commercially fabricated driver fuel has performed flawlessly to well beyond the design goal peak burnup of 80 MWd/kgM. The core average discharge exposure is now some 60% beyond the original design expectations and attests to the ruggedness and reliability of the mixed oxide fuel system. In Cycle 9 sixteen long-life assemblies were installed to begin the irradiation of mixed oxides in the advanced low-swelling alloy HT-9 as the Core Demonstration Experiment (CDE). Operation of the plant from initial startup testing to ten cycles of operation has confirmed that the nuclear characteristics are well within the design predictions, and all ...
Soils and groundwater beneath an abandoned process sewer line in the A/M Area of the Savannah River Site (SRS) contain elevated levels of volatile organic compounds, specifically trichloroethylene (TCE) and tetrachloroethylene (PCE), two common chlorinated solvents. These compounds have low aqueous solubilities, thus when released to the subsurface in sufficient quantity, tend to exist as immiscible fluids or nonaqueous phase liquids (NAPLs). Because chlorinated solvents are also denser than water, they are referred to by the acronym DNAPLs, or dense non-aqueous phase liquids. Technologies targeted at the efficient characterization or removal of DNAPL are not currently proven. For example, most DNAPL studies rely on traditional soil and water sampling and the fortuitous observation of immiscible solvent. Once DNAPL is identified, soil excavation (which is only applicable to small contained spill sites) ...
A compartment model is described which is currently used by the Ministry of Agriculture, Fisheries and Food to calculate collective radiation exposure due to liquid radioactive wastes discharged to sea from UK nuclear sites. Collective dose is a useful indicator of the radiological impact of a disposal practice and is one of the quantities needed to show compliance with the ICRP system of dose limitation. The model has been used for the purposes of the Sizewell Inquiry to predict the collective radiation exposure from reactor operation at Sizewell and, on the basis of current Sellafield experience, correlations between dose and discharge for disposals of fuel reprocessing wastes. (author).
This report was prepared in response to a request from the Nuclear Energy Research Advisory Committee (NERAC) subcommittee on ''Long-Term Isotope Research and Production Plans.'' The NERAC subcommittee has asked for a reply to a number of questions regarding (1) ''How well does the Department of Energy (DOE) infrastructure sme the need for commercial and medical isotopes?'' and (2) ''What should be the long-term role of the federal government in providing commercial and medical isotopes?' Our report addresses the questions raised by the NERAC subcommittee, and especially the 10 issues that were raised under the first of the above questions (see Appendix). These issues are related to the isotope products offered by the DOE Isotope Production Sites, the capabilities and condition of the facilities used to produce these products, the management of the isotope production ...
SRS high-level radioactive waste tanks will not experience erosion corrosion to any significant degree during slurry pump operations. Erosion corrosion in carbon steel structures at reported pump discharge velocities is dominated by electrochemical (corrosion) processes. Interruption of those processes, as by the addition of corrosion inhibitors, sharply reduces the rate of metal loss from erosion corrosion. The well-inhibited SRS waste tanks have a near-zero general corrosion rate, and therefore will be essentially immune to erosion corrosion. The experimental data on carbon steel erosion corrosion most relevant to SRS operations was obtained at the HanfordSite on simulated Purex waste. A metal loss rate of 2.4 mils per year was measured at a temperature of 102 C and a slurry velocity comparable to calculated SRS slurry velocities on ground specimens of the same carbon steel used in SRS waste tanks. Based on these data and the much lower ...
This document outlines the Maintenance Implementation Plan (MIP) for the Plutonium Finishing Plant (PFP) located at the Hanfordsite at Richland, Washington. This MIP describes the PFP maintenance program relative to DOE order 4330.4B. The MIP defines the key actions needed to meet the guidelines of the Order to produce a cost-effective and efficient maintenance program. A previous report identified the presence of significant quantities of Pu-bearing materials within PFP that pose risks to workers. PFP`s current mission is to develop, install and operate processes which will mitigate these risks. The PFP Maintenance strategy is to equip the facility with systems and equipment able to sustain scheduled PFP operations. The current operating run is scheduled to last seven years. Activities following the stabilization operation will involve an Environmental Impact Statement (EIS) to determine future plant activities. This strategy includes ...
This Maintenance Implementation Plan (MIP) has been developed for maintenance functions associated with the B Plant/WESF (Waste Encapsulation Storage Facility) complex. The objective of this plan is to provide baseline information for establishing and identifying WHC conformance programs and policies applicable to implementation of DOE order 4330.4B guidelines. In addition, this maintenance plan identifies the actions necessary to develop a cost-effective and efficient maintenance program at B Plant/WESF. The B Plant WESF facility complex consists of three main facilities and several support structures located in the 200 East Area of the Hanfordsite. B Plant is a transition facility that is required to ensure safe storage and management of WESF (operating facility) cesium and strontium capsules. B Plant/WESF also contains substantial radiological inventory from previous campaigns. There are no production activities at B Plant, but several of ...
This Maintenance Implementation Plan (MIP) has been developed for. implementation of the US Department of Energy (DOE) Order 4330.4A. Maintenance Implementation Program (DOE 1990) at the HanfordSite Solid Waste complex. It addresses maintenance functions associated with Solid Waste Management, which includes the field operational group and the facilities operational group. An assessment of the existing maintenance programs for Solid Waste was performed, and the results of this assessment were evaluated to determine corrective actions required to bring Solid Waste Maintenance into compliance with the order. The MIP assessment disclosed that most elements defined in the order are currently implemented for Solid Waste. It also identified issues which must be addressed to bring the maintenance function into full compliance with DOE Order 4330.4A. These include documentation of the maintenance training program, expanded scope of inspections to ...
The 105-KE and 105-KW Fuel Storage Basins were constructed more than 35 years ago as repositories for irradiated fuel from the K East and K West Reactors. Currently, the basins contain irradiated fuel from the N Reactor. To continue to use the basins as desired, seismic adequacy in accordance with current US Department of Energy facility requirements must be demonstrated. The 105-KE and 105-KW Basins are reinforced concrete, belowground reservoirs with a 16-ft water depth. The entire water retention boundary, which currently includes a portion of the adjacent reactor buildings, must be qualified for the HanfordSite design basis earthquake. The reactor building interface joints are sealed against leakage with rubber water stops. Demonstration of the seismic adequacy of these interface joints was initially identified as a key issue in the seismic qualification effort. The issue of water leakage through seismicly induced cracks was also ...
Pre-waste-emplacement groundwater travel time is one indicator of the isolation capability of the geologic system surrounding a repository. Two distinct modeling approaches exist for prediction of groundwater flow paths and travel times from the repository location to the designated accessible environment boundary. These two approaches are: (1) the deterministic approach which calculates a single value prediction of groundwater travel time based on average values for input parameters and (2) the stochastic approach which yields a distribution of possible groundwater travel times as a function of the nature and magnitude of uncertainties in the model inputs. The purposes of this report are to (1) document the theoretical (i.e., mathematical) basis used to calculate groundwater pathlines and travel times in a basalt system, (2) outline limitations and ranges of applicability of the deterministic modeling approach, and (3) explain the motivation for the use of the stochastic modeling ...
We describe a method for the analysis of multi-site phosphorylation in serine/threonine (Ser/Thr)-rich protein sequences. Site-specific mutagenesis was used to introduce tryptic cleavage sites in the serine glutamine/threonine glutamine cluster domain (SCD) of the human checkpoint protein kinase (Chk2). The mutant proteins were shown to autophosphorylate on residues that are inducibly phosphorylated when mammalian cells are exposed to ionizing radiation (serine 33/35, serine 516, threonine 68 and threonine 432). Five Ser/Thr clusters within the SCD were flanked by arginine or lysine residues to produce tryptic peptides for nanospray liquid chromatography (nanoLC)/linear quadrupole ion trap Fourier transform ion cyclotron resonance mass spectrometry. Phosphorylation sites were assigned usin...
The comprehensive theoretical and experimental study of the adsorption of water and methanol molecules on active sites (carboxyl and phenol hydroxyl groups) on the graphitized thermal carbon black is performed. It is shown that microclusters formed upon the adsorption of these molecules on such sites are characterized by the cyclic structure comprising 4?5 molecules similar to that whose existence was revealed previously in liquid water and on the surface of silver iodide. The analysis of the studied adsorption clusters demonstrated that the formation of such cycles is governed primarily by the hydrogen bonding; however, a definite role is played also by energy effects associated with the changes in the state of molecular motion during adsorption. It is shown that the generalized Langmuir ...
The Fast Flux Test Facility (FFTF) is a 400-MW(t) sodium-cooled fast reactor operating at the Hanford Engineering Development Laboratory in Richland, Washington, to conduct fuels and materials testing in support of the US liquid-metal fast breeder reactor program. Startup and initial power testing included a comprehensive series of nuclear and nonnuclear tests to verify the thermal and neutronic characteristics of the plant and to demonstrate its inherent safety features. Extensive reactor core characterization measurements were completed to provide the neutron and gamma spectra, fission rates, and other physics data needed to design and evaluate tests irradiated in the FFTF. A specially designed series of natural-circulation tests was performed to demonstrate the inherent safety features of the plant. Early in 1982 the FFTF began its first 100-d irradiation cycle. Since that time the plant has operated beyond expectations; it achieved a cycle ...
Most of the low-level liquid radioactive wastes generated from PWR plants are classified into high or low total suspended solid(HTDS or LTDS), and into radiochemical and radioactive laundry waste. Although the evaporation process has a high decontamination ability, it has several problems such as corrosion, foam, and congestion. A new liquid waste disposal process using the ion-exchange demineralizer(IED), instead of the current evaporation process, has been introduced into the Yonggwang NPP No 5 and 6. These two methods have been compared to understand the differences in this study. Aspects compared here were the released radioactivity amount of the liquid radioactive wastes, the dose of off-site residents, the decontamination factor, and the amount of the solid radioactive wastes. The IED system is designed to discharge higher radioactivity about 20% than the evaporating system, and the actual ...
The overall goal of the proposed project is to explore the use of partitioning tracers to characterize dense nonaqueous phase liquids (DNAPLs) in aquifer systems. Bulk-phase partitioning tracers will be investigated to detect and determine DNAPL saturation, while interface partitioning tracers will be investigated to measure the area of the DNAPL-water interface. The specific objectives that will be addressed to accomplish this goal are: (1) Investigate the use of partitioning tracers to detect and determine both the saturation and interfacial area of DNAPLs in saturated porous media. (2) Investigate the effect of rate-limited mass transfer on the transport behavior of partitioning tracers. (3) Investigate the effect of porous-media heterogeneity on the transport behavior of partitioning tracers. (4) Develop and evaluate mathematical models capable of simulating the transport of partitioning tracers in complex systems. This proposal outlines an integrated approach ...
This description of work (DOW) details the field activities associated with the sampling of the vadose zone soils beneath the 1301-N and 1325-N cribs and trenches and will serve as a field guide for those performing the work. These activities are undertaken pursuant to the Hanford Federal Facility Agreement and Consent Order (Ecology et al., 1994a) Milestone M-16-94-01H-Tl and the June 30, 1994 Milestone Change Request M-16-94-02 (Ecology et al., 1994b). Three vadose zone borings, 1301-N-1, 1301-N-2, and 1325-N-1, will be constructed to investigate the vertical and horizontal distribution of radionuclide contamination in sediments beneath the cribs and trenches. The boreholes are also intended to intersect subsurface areas that may have been contaminated by dangerous wastes, i.e., metals, in effluent disposed during past operation of the facilities. This limited field investigation will provide data for the evaluation of remedial alternatives. Data from the ...
This Closure Report (CR) documents closure activities for Corrective Action Unit (CAU) 543, Liquid Disposal Units, according to the Federal Facility Agreement and Consent Order (FFACO, 1996) and the Corrective Action Plan (CAP) for CAU 543 (U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office [NNSA/NSO], 2007). CAU 543 is located at the Nevada Test Site (NTS), Nevada (Figure 1), and consists of the following seven Corrective Action Sites (CASs): CAS 06-07-01, Decon Pad; CAS 15-01-03, Aboveground Storage Tank; CAS 15-04-01, Septic Tank; CAS 15-05-01, Leachfield; CAS 15-08-01, Liquid Manure Tank; CAS 15-23-01, Underground Radioactive Material Area; CAS 15-23-03, Contaminated Sump, Piping; and CAS 06-07-01 is located at the Decontamination Facility in Area 6, adjacent to Yucca Lake. The remaining CASs are located at the former U.S. Environmental ...
The Washington Department of Fish and Wildlife (WDFW) has been contracted through the Bonneville Power Administration (BPA) and the Grant County Public Utility District (GCPUD) to perform an evaluation of juvenile fall chinook salmon (Oncorhynchus tshawytscha) stranding on the Hanford Reach of the Columbia River. The evaluation, in the fifth year of a multi-year study, has been developed to assess the impacts of water fluctuations from Priest Rapids Dam on rearing juvenile fall chinook salmon, other fishes, and benthic macroinvertebrates of the Hanford Reach. This document provides the results of the 2001 field season.
The Washington Department of Fish and Wildlife (WDFW) has been contracted through the Bonneville Power Administration (BPA) and the Grant County Public Utility District (GCPUD) to perform an evaluation of juvenile fall chinook salmon (Oncorhynchus tshawytscha) stranding on the Hanford Reach. The evaluation, in the fourth year of a multi-year study, has been developed to assess the impacts of water fluctuations from Priest Rapids Dam on rearing juvenile fall chinook salmon, other fishes, and benthic macroinvertebrates of the Hanford Reach. This document provides the results of the 2000 field season.
The Washington Department of Fish and Wildlife (WDFW) has been contracted through the Bonneville Power Administration (BPA) and the Grant County Public Utility District (GCPUD) to perform an evaluation of juvenile fall chinook salmon (Oncorhynchus tshawytscha) stranding on the Hanford Reach. The evaluation, in the third year of a multi-year study, has been developed to assess the impacts of water fluctuations from Priest Rapids Dam on rearing juvenile fall chinook salmon, other fishes, and benthic macroinvertebrates of the Hanford Reach. This document provides the results of the 1999 field season.
The Washington Department of Fish and Wildlife (WDFW) has been contracted through the Bonneville Power Administration (BPA) and the Grant County Public Utility District (GCPUD) to perform an evaluation of juvenile fall chinook salmon (Oncorhynchus tshawytscha) stranding on the Hanford Reach. The evaluation, in the second year of a multi-year study, has been developed to assess the impacts of water fluctuations from Priest Rapids Dam on rearing juvenile fall chinook salmon, other fish species, and benthic macroinvertebrates of the Hanford Reach. This document provides the results of the 1998 field season.
Aqueous radioactive high-level waste slurries are combined during processing steps that ultimately produce a stable borosilicate glass waste form. Chemically treated waste slurries are combined with each other and with glass frit-water slurries to produce the melter feed. Understanding the evolution of the rheological properties of the slurries is an important aspect of removing and treating the stored waste. To a first approximation, combinations of colloidal waste slurry with {approx}0.1-mm mean diameter glass frit or glass beads act in an analogous matter to slurries of spherical beads in Newtonian liquids. The non-Newtonian rheological properties of the waste slurries without frit, however, add complexity to the hydrodynamic analysis. The use of shear rate dependent apparent viscosities with the modified Einstein equation was used to model the rheological properties of aqueous frit-waste slurries.
The scope of this RA is limited to the evaluation of potential human health risks associated with a failure event of a tank containing Basin F liquid. Section 1.0 contains an introduction to the health risk assessment. Section 2.0 describes the site history, location, and land use. Section 3.0 provides a brief description of exposure pathways and potention receptors. Section 4.0 describes the sources of data used and identifies chemicals of concern. Section 5.0 discusses the toxicity of concern. Section 6.0 explains the methods used for calculation of carcinogenic risks and the noncarcinogenic hazard indexes. Section 7.0 describes uncertainties inherent in the current methodology used to determine potential human health risks. Section 8.0 presents a summary of results and conclusions. Section 9.0 includes the references cited.
The nuclear complex in Tarapur, Maharashtra is a multi facility nuclear site comprising of power reactors and research facilities. Each facility has independent liquid effluent discharge line to Arabian Sea. Experimental studies were conducted to evaluate dilution factors in the aquatic environment using liquid effluent releases as tracer from one of the facilities. 3H and 137Cs radioisotopes present in the routine releases were used as simulated tracer nuclides. The dilution factors(D.F) observed for tritium were in the range of 20-20000 in a distance range of 10 m to 1500 m respectively and for 137Cs the D.F. were in the range of 50 to 900 over a distance range of 10-200 m. The paper describes the analytical methodology and sampling scenarios and the results of dilution factors obtained for Tarapur aquatic environment. (author)
Thirty bacterial isolates were obtained from different sources and sites at Jeddah, Saudi Arabia, on chitin agar medium; 9 of the 30 isolates were cultured in liquid medium containing chitin as sole carbon and nitrogen sources. Isolate SM21, which was isolated from shrimp shells, showed the best growth and chitinase production in liquid medium. According to its morphological, physiological and biochemical characteristics, SM21 belongs to the genus Streptomyces and was identified as Streptomyces anulatus SM21. Identification was confirmed using 16S rDNA analysis. The chitinase enzyme was precipitated with 80% NH4SO4 and purified using DEAE-cellulose ion exchange chromatography followed by Sephadex G-100 gel filtration. The molecular weight determined using sodium dodecyl sulfate polyacrylam...
Y-zeolite supported catalysts were applied to the hydrocracking of coal-derived liquids. By the introduction of two-stage upgrading consisting of hydrotreating and hydrocracking, Wandoan coal-derived middle distillate was hydrocracked over Ni-Mo/Y-zeolite, producing a high gasoline fraction yield. Zeolite supported catalysts gave little hydrocracked compounds in the hydroprocessing of coal-derived heavy oils, even after hydrotreatment. The reaction inhibitors which seriously poison the active sites of zeolites were found to be small nitrogen-containing molecules. In the hydroprocessing of coal-derived heavy oils, zeolite supported catalysts were inferior to alumina supported catalysts. This is due to the high hydrocracking but low hydrogenation activity of zeolite supported catalysts. 22 refs., 5 figs., 11 tabs.
A multifunctional protein kinase, purified from rat liver as ATP-citrate lyase kinase, has been identified as a glycogen synthase kinase. This kinase catalyzed incorporation of up to 1.5 mol of and)2numberSPO4/mol of synthase subunit associated with a decrease in the glycogen synthase activity ratio from 0.85 to a value of 0.15. Approximately 65-70% of the TUPO4 was incorporated into site 3 and 30-35% into site 2 as determined by reverse phase high performance liquid chromatography. This multifunctional kinase was distinguished from glycogen synthase kinase-3 on the basis of nucleotide and protein substrate specificities. Since the phosphate contents in glycogen synthase of sites 3 and 2 are altered in diabetes and by insulin administration, the possible involvement of the multifunctional kinase was explored. Glycogen synthase purified from diabetic rabbits was phosphorylated in vitro by this ...
The patent describes a method for repairing leakage-causing cracks and fissures in a cryogenic heat exchanger. It comprises: reducing the interior pressure of the heat exchanger to a level which does not exceed the external pressure upon the hear exchanger while maintaining the temperature of the heat exchanger at a low level relative to the ambient external temperature; applying a curable liquid filler composition to the surface of the heat exchanger proximal the leakage site for seepage into the cracks and fissures located at the leakage. The composition upon a relatively short period of cure at low temperature forming a solid material which fills the cracks and fissures; curing the filler composition; and, applying a sealant composition to the surface of the heat exchanger at the filled leakage site. The sealant composition having long-term sealing performance under cyrogenic conditions.
In order to determine the viability of any Liquids from Coal (LFC) commercial venture, TEK-KOL and its partner, Mitsubishi Heavy Industries (MHI), have put together a technical and economic feasibility study for a commercial-size LFC Plant located at Zeigler Coal Holding Company`s North Rochelle Mine site. This resulting document, the ENCOAL Mild Coal Gasification Plant: Commercial Plant Feasibility Study, includes basic plant design, capital estimates, market assessment for coproducts, operating cost assessments, and overall financial evaluation for a generic Powder River Basin based plant. This document and format closely resembles a typical Phase II study as assembled by the TEK-KOL Partnership to evaluate potential sites for LFC commercial facilities around the world.
Soils and groundwater beneath an abandoned Process sewer line in the A/M Area of the Savannah River Site (SRS) contain elevated levels of volatile organic compounds, specifically trichloroethylene (TCE) and tetrachloroethylene (PCE), two common chlorinated solvents. These compounds have low aqueous solubilities, thus when released to the subsurface in sufficient quantity, tend to exist as immiscible fluids or nonaqueous phase liquids (NAPLs). Because chlorinated solvents are also denser than water, they are referred to by the acronym DNAPLS, or dense non aqueous Phase liquids. Technologies targeted at the efficient characterization or removal of DNAPL are not currently proven. For example, most DNAPL studies rely on traditional soil and water sampling and the fortuitous observation of immiscible solvent. Once DNAPL is identified, soil excavation (which is only applicable to small contained spill sites) ...
The recent attempt to degassify a self contained liquid filled (SCLF) cable in Ontario Hydro is described. In September 1989, there was a high pressure alarm on one phase of a SCLF 115 kV cable circuit. The direct buried cable circuit is about 1,890 m long with two joints and was installed in 1968. Oil samples from the cable had 10 to 12% gas content with high levels of hydrogen, methane, and ethane, and very low levels of carbon monoxide, carbon dioxide, and acetylene. From these results it was concluded that the gas was generated by low energy electrical discharges and the paper insulation was not degraded. Various utilities and cable manufacturers were contacted to find if they had experienced similar problems. The cable duct oil was flushed and gasified and the successive oil samples were analyzed in order to locate the gassing site. The joints were examined and oil samples were taken through holes drilled in the cable sheath. From the test ...
The formation of textured YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} (123) from a liquid phase according to the peritectic reaction Y{sub 2}BaCuO{sub 5} (211) + liquid {yields} 123 was analyzed using real-time analysis techniques of high-temperature X-ray diffraction, high-temperature optical microscopy, and environmental scanning electron microscopy (ESEM). Results were coupled with conventional ''post-mortem'' SEM analysis of processed samples at various stages of microstructural development. Observations of 123 formation and growth from the peritectic melt permit the conclusion that the presence of crystalline 211 primarily acts as a source of yttrium. The slow dissolution of 211 into the yttrium deficient liquid phase is the rate controlled step in the formation and growth of the textured 123, rather that its acting as a nucleation site for 123 grains as has been widely ...
A decision must be made regarding whether the United State`s stockpile of neptunium should be discarded into the waste stream or kept for the production of Pu-238. Although the cost of long term storage is not inconsequential, to dispose of the material means the closing of our option to maintain control over our Pu-238 stockpile. Within the Fuels and Materials Examination Facility at Hanford there exists a remotely operated facility that can be converted for neptunium storage. This paper describes the facility and the anticipated handling requirements.
This document provides structural load requirements and their basis for maintaining the structural integrity of the Hanford Single-Shell Tanks during waste feed delivery and retrieval activities. The requirements are based on a review of previous requirements and their basis documents as well as load histories with particular emphasis on the proposed lead transfer feed tanks for the privatized vitrification plant.
This report is an Implementation Guide for Hanford Tanks Initiative C-106 heel retrieval contract management HNF-2511 to provide a set of uniform instructions for managing the two contractors selected. The primary objective is to produce the necessary deliverables and services for the HTI project within schedule and budget.
The Fast Flux Test Facility (FFTF) reactor characterization by the Hanford Engineering Development Laboratory (HEDL) includes extensive neutronic measurements during startup and initial operation. To aid in the handling and counting of the thousands of passive dosimeters used as part of this effort, an automated dosimetry specimen handling, positioning, and counting system was designed and developed by Westinghouse Hanford for the Department of Energy.
The `Hanford Facility Dangerous Waste Permit Application` is considered to be a single application organized into a General Information Portion (this document, DOE/RL-91-28) and a Unit- Specific Portion. The scope of the General Information Portion includes information that could be used to discuss operating units, units undergoing closure, or units being dispositioned through other options. Documentation included in the General Information Portion is broader in nature and could be used by multiple treatment, storage, and/or disposal units. A checklist indicating where information is contained in the General Information Portion, in relation to the Washington State Department of Ecology guidance documentation, is located in the Contents Section. The intent of the General Information Portion is: (1) to provide an overview of the Hanford Facility; and (2) to assist in streamlining efforts associated with treatment, storage, and/or disposal ...
This plan establishes both the scope of the review and the acceptance criteria to be utilized for the review of Quality Assurance Program Plans (QAPPs) developed in accordance with the requirements of DOE/RL-90-28. DOE/RL-90-28, the Environmental Restoration Remedial Action Quality Assurance Requirements Document (QARD) defines all quality assurance (QA) requirements governing activities that affect the quality of the Environmental Restoration Remedial Action (ERRA) program at the HanfordSite. These requirements are defined in three parts, Part 1 of Quality Management and Administration tasks, Part 2 for Environmental Data Operations, and Part 3 of the Design and Construction of items, systems, and facilities. The purpose of this document is to identify the scope of the review by the DOE Field Office, Richland staff, and establish the acceptance criteria (Parts 1, 2, and 3) that the DOE Field Office, Richland staff will utilize to evaluate the ...
The EPA has designated vitrification as the best developed available technology for immobilization of High-Level Nuclear Waste. In a recent federal facilities compliance agreement between the EPA, the State of Washington, and the DOE, the DOE agreed to vitrify all of the Low Level Radioactive Waste resulting from processing of High Level Radioactive Waste stored at the HanfordSite. This is expected to result in the requirement of 100 ton per day Low Level Radioactive Waste melters. Thus, there is increased need for the rapid adaptation of commercial melter equipment to DOE`s needs. DOE has needed a facility where commercial pilot scale equipment could be operated on surrogate (non-radioactive) simulations of typical DOE waste streams. The DOE/Industry Center for Vitrification Research (Center) was established in 1992 at the Clemson University Department of Environmental Systems Engineering, Clemson, SC, to address that need. This report ...
The Ringold Formation consists of lacustrine and fluvial deposits overlying the Columbia River Basalt. The Ringold Formation, because of its thickness, extent, and age, is an excellent unit in which to detect and possibly data the deformation that has occurred since deposition of the basalt. One objective of this study was to investigate the paleomagnetism of the upper Ringold unit exposed at one location in the White Bluffs in enough detail to resolve, with reasonable confidence, the magnetostratigraphy of the rock units sampled. The other objective was to evaluate, in a preliminary manner, the paleomagnetic favorability and magnetostratigraphy of the subsurface Ringold Formation in the Pasco Basin and at selected exposures outside the Pasco Basin. The scope of this study was the collection of 300 paleomagnetic samples, their measurement, and analysis. Samples were collected from the White Bluffs, from core recovered from six drill holes on the Hanford ...
The dominant shrubs were sagebrush and spiny hopsage; the herbs were dominated by cheatgrass and Sandberg bluegrass. Spiny hopsage appeared to be vulnerable to burning and also to damage by off-road vehicular traffic. It appears to have little or no ability to reproduce through seedlings; once the existing plants are killed they are not likely to be replaced, even if seed-producing plants are nearby. The only pure stand of spiny hopsage known to exist on the HanfordSite is on and near study plot 2H. Sagebrush, like spiny hopsage, is killed by burning and by heavy vehicles. Sagebrush is capable of reproducing via seeds, indicating that it is an inherently aggressive species with a capacity to reestablish itself if parent plants are in the vicinity to act as seed sources. Alien, annual plants, especially cheatgrass, were a major contributor to the herbaceous canopy cover in plots 3S, 4S, and 5S. However, native perennial grasses, especially ...
The proposed action is to recycle slightly activated copper that is currently stored in a warehouse leased by Lawrence Berkeley Laboratory (LBL) to a scrap metal dealer. Subsequent reutilization of the copper would be unrestricted. This document addresses the potential environmental effects of recycling and reutilizing the activated copper. In addition, the potential environmental effects of possible future uses by the dealer are addressed. Direct environmental effects from the proposed action are assessed, such as air emissions from reprocessing the activated copper, as well as indirect beneficial effects, such as averting air emissions that would result from mining and smelting an equivalent quantity of copper ore. Evaluation of the human health impacts of the proposed action focuses on the pertinent issues of radiological doses and protection of workers and the public. Five alternatives to the proposed action are considered, and their associated potential impacts are addressed. The ...
The strategy for management of the Oak Ridge National Laboratory`s (ORNL) radioactively contaminated liquid waste was reviewed in 1991. The latest information available through the end of 1990 on waste characterization, regulations, US Department of Energy (DOE) budget guidance, and research and development programs was evaluated to determine how the strategy should be revised. Few changes are needed to update the strategy to reflect new waste characterization, research, and regulatory information. However, recent budget guidance from DOE indicates that minimum funding will not be sufficient to accomplish original objectives to upgrade the liquid low-level waste (LLLW) system to comply with the Federal Facilities Agreement, provide long-term LLLW treatment capability, and minimize environmental, safety, and health risks. Options are presented that might allow the ORNL LLLW system to continue operations temporarily, but they would significantly ...
The strategy for management of the Oak Ridge National Laboratory`s (ORNL`s) radioactively contaminated liquid waste was reviewed. The latest information on waste characterization, regulations, US Department of Energy (DOE) budget guidance, and research and development programs was evaluated to determine how the strategy should be revised. Few changes are needed to update the strategy to reflect new waste characterization, research, and regulatory information. However, recent budget guidance from DOE indicates that minimum funding will not be sufficient to accomplish original objectives to upgrade the liquid low-level waste (LLLW) system to be in compliance with the Federal Facilities Agreement compliance, provide long-term LLLW treatment capability, and minimize Environmental Safety & Health risks. Options are presented that might allow the ORNL LLLW system to continue operations temporarily but significantly reduce its capabilities to ...
The active site of chicken gizzard myosin was labeled by direct photoaffinity labeling with ["3H]UDP. ["3H] UDP was stably trapped at the active site by addition of vanadate (Vi) and Co"2"+. The extraordinary stability of the myosin.Co2+.[3H]UDP.Vi complex (t1/2 greater than 5 days at 0 degrees C) allowed it to be purified free of extraneous ["3H]UDP before irradiation began. Upon UV irradiation, greater than 60% of the trapped ["3H]UDP was photoincorporated into the active site. Only the 200-kDa heavy chain was labeled, confirming earlier results using ["3H]UTP. Extensive tryptic digestion of photolabeled myosin subfragment 1 followed by high performance liquid chromatography separations and removal of nucleotide phosphates by treatment with alkaline phosphatase allowed two labeled peptides to be isolated. Sequencing of the labeled peptides and radioactive counting showed that Glu185 was the residue ...
According to the present concept, the low and intermediate level wastes generated during the Cernavoda NPP operation will be disposed in a near surface repository. The Saligny site, placed in the NPP protected area, has been proposed for their disposal. Geologically, the main components of this site are the quaternary loess, the Precambrian and Pre-quaternary clays, the Eocene and Barremian limestone. Hydrologically, the site can be divided into a vadose zone down to 45-50 m and three distinct aquifers, two of them in the limestone beds and the third in the lenses of sand and limestone existing in the pre-quaternary clay layer. A large research program for site characterization was initiated in 1996. At present, the site characteristics requested for safety analysis have been experimentally measured on soil samples or calculated by different computer programs. Hundreds of ...
Although the Federal Facility Agreement (FFA) addresses the entire Oak Ridge Reservation, specific requirements are set forth for the liquid low-level radioactive waste (LLLW) storage tanks and their associated piping and equipment, tank systems, at ORNL. The stated objected of the FFA as it relates to these tank systems is to ensure that structural integrity, containment and detection of releases, and source control are maintained pending final remedial action at the site. The FFA requires that leaking LLLW tank systems be immediately removed from service. It also requires the LLLW tank systems that do not meet the design and performance requirements established for secondary containment and leak detection be either upgraded or replaced. The FFA establishes a procedural framework for implementing the environmental laws. For the LLLW tank systems, this framework requires the specified plans and schedules be submitted to EPA and TDEC for ...
10%Pt/C catalysts were prepared by liquid reduction method. PTFE and Pt/ C catalysts were adhered to porous metal and hydrophobic Pt/C/PTFE catalysts were prepared. The structure and size of Pt crystal particles of Pt/C catalysts were analyzed by XRD, and their mean size was 3.1 nm. The dispersion state of Pt/C and PTFE was analyzed by SEM, and they had good dispersion mostly, but PTFE membrane could be observed on local parts of Pt/C/PTFE surface. Because of low hydrophobicity, Pt/C/ PTFE catalysts have low activity when the mass ratio of PTFE and Pt/C is 0.5: 1, and their catalytic activity increases markedly when the ratio is 1:1. When the ratio increases again, more Pt active sites would be covered by PTFE and interior diffusion effect would increase, which result in the decrease of catalytic activity of Pt/C/PTFE. By PTFE pretreatment of porous metal carrier, the activity of Pt/C/PTFE catalysts decreases when the mass ratio of PTFE and ...
An analytical method was developed for the determination of eleven agrochemicals [abamectin (as B1a), bifenazate, bifenthrin, carfentrazone-ethyl, cymoxanil, hexythiazox, imidacloprid, mefenoxam, pymetrozine, quinoxyfen, and trifloxystrobin] in dried hops. The method utilized polymeric and NH2 solid phase extraction (SPE) column cleanups and liquid chromatography with mass spectrometry (LC-MS/MS). Method validation and concurrent recoveries from untreated dried hops ranged from 71 to 126% for all compounds over three levels of fortification (0.10, 1.0, and 10.0 ppm). Commercially grown hop samples collected from several field sites had detectable residues of bifenazate, bifenthrin, hexythiazox, and quinoxyfen. The control sample used was free of contamination below the 0.050 ppm level for all agrochemicals of interest. The limit of quantitation and limit of detection for all compounds were 0.10 and 0.050 ppm, respectively. PMID:18593182
Abstract: The Hanford Tanks Initiative (HTI) is a five-year project resulting from the technical and financial partnership of the U.S. Department of Energy`s Office of Waste Management (EM-30) and Office of Science and Technology Development (EM-50). The HTI project accelerates activities to gain key technical, cost performance, and regulatory information on two high-level waste tanks. The HTI will provide a basis for design and regulatory decisions affecting the remainder of the Tank Waste Remediation System`s tank waste retrieval Program.
The US Department of Enregy (DOE) Subsurface Contaminants Focus Area is developing technologies to address environmental problems associated with hazardous and radioactive contaminants in soil and groundwater that exist throughout the DOE complex, including radionuclides, heavy metals; and dense non-aqueous phase liquids (DNAPLs). More than 5,700 known DOE groundwater plumes have contaminated over 600 billion gallons of water and 200 million cubic meters of soil. Migration of these plumes threatens local and regional water sources, and in some cases has already adversely impacted off-site rsources. In addition, the Subsurface Contaminants Focus Area is responsible for supplying technologies for the remediation of numerous landfills at DOE facilities. These landfills are estimated to contain over 3 million cubic meters of radioactive and hazardous buried Technology developed within this specialty area will provide efective methods to contain ...
This study sought to quantitate lidocaine's interaction with alpha-1-acid glycoprotein (AAG), human serum albumin (HSA), and AAG in the presence of HSA, and to determine the extent of displacement of lidocaine from its binding site(s) by selected cardiovascular drugs (dipyridamole, disopyramide and quinidine). Since the limited experimental work reported in this area has involved the use of a single lidocaine concentration, this study involved the evaluation of a range of lidocaine concentrations. Lidocaine interaction with plasma proteins (AAG and HSA) was studied at 37/sup 0/C using an isothermal equilibrium dialysis system and /sup 14/C-lidocaine HCl. A dialysis membrane (M.W. cutoff 12,000 to 14,000) separated the two chambers of each dialysis cell. The extent of /sup 14/C-lidocaine dialysis was studied with respect to both drug and protein concentrations. Aliquots of each chamber of each of the cells were subjected to liquid ...
This project was supported through ERDA to demonstrate that the temporal distribution of tritium can be documented by the analysis of bound hydrogen in annual tree-ring samples. The project focuses on two sample locations at the Savannah River Site (SRS), a nuclear material production facility located in Aiken, SC. The SRS provided samples of cross-sections from a single tree that were to be pooled together for analysis. Annual tree-rings were identified in each cross-section sample and separated for the period 1954 to 1993. These annual samples were ground and chemically treated to separate the hollocellulose fraction of the wood, then subsequently combusted and the resulting water counting using low-level liquid scintillation counting equipment. Additionally, the ground annual tree-rings were gamma-counted to determine any temporal variation in radionuclide activity and analyzed with x-ray fluorescence to find any temporal variation in ...
Solid polymer fuel cell (SPFC) systems are compared to spark ignition (SI) engine power systems for utility vehicle applications. Utility vehicles provide crew and payload transport and electrical power at work sites lacking grid supply. The methodology emphasizes comparison on an equal service basis. Using power system component models and numerical analysis, power systems are designed using SI engine and SPFC technologies. The power systems are compared on the basis of fuel energy consumed and life cycle cost (LCC). Gasoline is the fuel for the SI engines, while liquid hydrogen is used for the SPFC. Three types of SPFC power system configurations are studied. The superior SPFC in terms of LCC is a fuel cell/battery hybrid where the fuel cell is sized to provide average driving power. Using today's technology, SPFC power systems have a lower fuel consumption but have higher capital costs and consequently lose to SI engine power ...
Results are presented of experiments on partial discharge in liquid nitrogen, including insulation breakdown characteristics of liquid nitrogen, partial discharge characteristics of composite insulation systems, lifetime of polymer films, impulse breakdown of polymer films in liquid nitrogen, etc. The partial discharge characteristics of liquid nitrogen are examined with increasing liquid-nitrogen pressure. It is concluded that a composite insulation structure of polymer film and liquid nitrogen can be used as effective electrical insulators at cryogenic temperatures.
The thermal transpiration method has been employed to replace the temperature of liquid nitrogen by #approx#12 K. This is done by bubbling He (g) through the liquid nitrogen.
A fuel composition comprising a liquid hydrocarbon fuel and a detergent amount of the product of reaction between a polyamine and a stearic acid is described.
The present invention is a device for a solar heating system having a solar collector, a storage tank connected to the solar collector, a pump for circulating liquid from the tank to the solar collector, a supply of liquid at a temperature above freezing and a connection from the supply of liquid to the solar collector for replacing any liquid lost from said solar collector. The device comprises a sensor for sensing the temperature of liquid in the solar collector, and a valve for bleeding liquid from the solar collector when the sensed temperature falls below a predetermined minimum whereby cool liquid in the solar collector is automatically replaced by liquid at a temperature above freezing.
In early 2006 we designed and built low energy consumption, pump-operated system, for dosing of the liquid nutrient in the summer 2006 season. This operated successfully, and the system was used again during the 2007 and 2008 seasons for dosing. During the early winter period, 2008, laboratory tests were made of the liquid nutrient pump system, and it was noted that small amounts of air were being entrained on the suction side of the pump, during conditions when the inlet pressure was low. It was believed that this was the cause of diurnal fluctuations in the flow supplied, characteristic of the 2007 year flow data. Replacement of '0' rings on the inlet side of the pumps was the solution to this problem, and when tested in the field during the summer season, the flow supplied was found to be stable. A decision was made by the IKERT committee at the meeting of 20th to 21st May 2008 (held in Coeur d'Alene, Idaho) to use ...
A portion of the active site of rabbit skeletal myosin near the ribose ring of ATP can be labeled by the photoaffinity analogue 3{prime}(2{prime})-O-(4-benzoylbenzoyl)adenosine triphosphate (Bz{sub 2}ATP). The specificity of the photolabeling was assured by first trapping ({sup 14}C)Bz{sub 2}ATP at the active site by use of thiol cross-linking agents. Five radioactive peptides were isolated by high-performance liquid chromatography after extensive trypsin and subtilisin digestion of photolabeled myosin subfragment 1. Four of these peptides were sequenced by Edman techniques, and all originated from a region with the sequence Gly-Glu-Ile-Thr-Val-Pro-Ser-Ile-Asp-Asp-Gln, which corresponds to rabbit myosin heavy chain residues 312-328. The fifth labeled peptide had an amino acid composition appropriate for residues 312-328. Amino acid composition, radiochemical analysis, and sequence data indicate that Ser-324 is the major ...
Nitrite was measured in atmospheric liquid phase samples between 1998 and 2005 to investigate the heterogeneous formation of nitrous acid in the lower atmosphere, as well as to assess the quality of water recovered from dew. The samples were collected during ground-based cloud field experiments at different German mountain sites (Brocken, Schmucke, and Hohenpeissenberg) and at a site south of the Bordeaux urban area (France). Concentrations found in Bordeaux dew samples (up to 2800 ?gl-1) are comparable to those found elsewhere in urban fog and dew water and considerably higher than those detected in cloud water or rain. Particulate nitrite (and nitrate) as well as HNO2 (HNO3) data in air masses from a foothill site of Mt. Schmucke, before involved in cloud processing, are also presented. In clouds at Mt. Brocken, both the interstitial HNO2 gas and the aqueous phase nitrite concentration have been ...
Environmental Survey Laboratory at Tarapur, Maharashtra site carries out environmental radioactivity measurements in different matrices to evaluate the impact of operating nuclear installations. In this paper, the evaluation of data of 1983-2007 (25 years) is presented. Time trends of particulate radioactivity, correlation between "1"3"7Cs in discharge canal seawater and station discharged activity and correlation of "1"3"7Cs, "6"0Co, and "1"3"1I in marine species like Sponge and Nerita and corresponding discharged activity were carried out. Statistical analysis of environmental data of seawater and marine fish for several radionuclides, for distributions, showed that the data best fits lognormal distribution. A strong correlation between "1"3"7Cs in seawater and "1"3"7Cs in liquid waste discharge was observed (R"2 = 0.8, P = 0.000). Similarly correlation was very good for Nerita and discharged concentration for "1"3"7Cs, "1"3"1I and "6"0Co ...
Magnetic particles (MAG*SEP"S"M) coated with various absorbents were evaluated for the separation and recovery of low concentrations of cesium from nuclear waste solutions. The MAG*SEP"S"M particles were coated with (1) clinoptilolite, (2) transylvanian volcanic tuff, (3) resorcinol formaldehyde, and (4) crystalline silico-titanate, and then were contacted with a Hanford supernatant simulant. Particles coated with the crystalline silico-titanate were identified by Bradtec as having the highest capacity for cesium removal under the conditions tested (variation of pH, ionic strength, cesium concentration, and absorbent/solution ratio). The MAG*SEP"S"M particles coated with resorcinol formaldehyde had high distribution ratios values and could also be used to remove cesium from Hanford supernant simulant. Gamma irradiation studies were performed on the MAG*SEP"S"M particles with a gamma dose equivalent to 100 cycles of use. This irradiation ...
This report discusses the procedures that establish the configuration control processes for the Hanford Environmental Information System (HEIS) software. The procedures also provide the charter and function of the HEIS Configuration Control Board (CCB) for maintaining software. The software configuration control items covered under these procedures include the HEIS software and database structure. The configuration control processes include both administrative and audit functions. The administrative role includes maintaining the overall change schedule, ensuring consistency of proposed changes, negotiating change plan adjustments, setting priorities, and tracking the status of changes. The configuration control process audits to ensure that changes are performed to applicable standards.
A major new initiative to develop and irradiate a long-life mixed oxide fuel system in the Fast Flux Test Facility (FFTF) has been implemented by the Westinghouse Hanford Company at the Hanford Engineering Development Lab. for the US Dept. of Energy. The purpose of this new fuel system, called the Core Demonstration Experiment (CDE), is to demonstrate the capability of achieving a 3-yr life in a prototypical heterogeneous reactor environment under prototypical power and temperature conditions. Three Core Demonstration Lead Experiments (CDLEs) will establish the performance characteristics of entire fuel assemblies of wire-wrapped, large diameter, advanced oxide fuel pins with HT-9 stainless steel alloy cladding and wire wrap and an HT-9 duct. Their performance characteristics provided the basis for design, fabrication, and irradiation of the CDE.
Gas well load up is the loss of available reservoir energy due to the accumulation of liquids in the wellbore over time, and these liquids arise from liquids (hydrocarbons and water) condensed from the gas. Accumulation of these liquids near the wellbore can cause severe reduction to complete loss of available transport energy. A systematic experimental approach was undertaken to evaluate the performance of foam in removing liquids from the bottom of wells. The objectives of the research were: (1) to determine the efficiency of liquid lifting with foam; and (2) to compare the effects of surfactant type and concentration on liquid lifting. A flowloop successfully simulated the effects of completions with and without packer for low-pressure gas well with liquid production. In the base-case runs (air and water flow), the ...
A novel system has been deployed to obtain geochemical samples of water and gas, at in situ pressure, during a geologic CO2 sequestration experiment conducted in the Frio brine aquifer in Liberty County, Texas. Project goals required high-frequency recovery of representative and uncontaminated aliquots of a rapidly changing two-phase (supercritical CO2-brine) fluid from 1.5 km depth. The datasets collected, using both the liquid and gas portions of the downhole samples, provide insights into the coupled hydro-geochemical issues affecting CO2 sequestration in brine-filled formations. While the basic premise underlying the U-Tube sampler is not new, the system is unique because careful consideration was given to the processing of the recovered two-phase fluids. In particular, strain gauges mounted beneath the high-pressure surface sample cylinders measured the ratio of recovered brine to supercritical CO2. A quadrupole mass spectrometer provided real-time gas ...
The spectroscopic properties of Eu{sup 3+} doped into two lanthanum chlorotungstates matrices, namely LaWO{sub 4}Cl (1-1) and La{sub 3}WO{sub 6}Cl{sub 3}(3-1), are investigated. The fluorescence spectra of these compounds, recorded at room and liquid nitrogen temperatures, show that the lanthanide ion occupies only one site with the low symmetry, C{sub s}, in both cases. From the energy level schemes of the {sup 7}F{sub J} levels (J = 0, 1, 2, 3, 4, 5), two sets of crystal field parameters (cfp) are deduced, in a C{sub 2v} approximated point symmetry (i.e., 9 cfp), simulating the experimental data, correctly. Furthermore, for the 3-1 compound, the data is complete enough to extend the calculations to the real point group, C{sub s} (14 cfp).
This report focuses on air quality at the Nevada Test Site (NTS) for 1994. A general description of the effluent sources are presented. Each potential source of NTS emissions was characterized by one of the following: (1) by monitoring methods and procedures previously developed at NTS; (2) by a yearly radionuclide inventory of the source, assuming that volatile radionuclides are released to the environment; (3) by the measurement of tritiated water concentration in liquid effluents discharged to containment ponds and assuming all the effluent evaporates over the course of the year to become an air emission; or (4) by using a combination of environmental measurements and CAP88-PC to calculate emissions. Appendices A through J describe the methods used to determine the emissions from the sources. These National Emission Standards for Hazardous Air Pollutants (NESHAP) emissions are very conservative, are used to calculate the effective dose ...
The release of any potential radioactive pollutant to the environment during routine operation of a Nuclear Power Plant should be the subject of appropriate controls and assessments. It is impossible to monitor directly the dose contribution of normal releases because the environmental radioactivity levels are very small but source monitoring provides a means of assessing the radiation exposure of population groups, critical groups and individual members of the public. Derived emissions limits ( DELs ) are used to quantify the relationship between releases of radioactivity and doses to public - critical groups. CNE Cernavoda DELs are based on a pathway analysis conducted for Cernavoda site specific conditions and they were computed using a compartment transfer model. Annual air and water emissions for the most significant radionuclides between 1997 and 2008 are presented in terms of doses and can be observed that population doses are far below the authorized limit ...
The Department of Energy currently has over 100 million liters of high-level radioactive waste in storage at the Savannah River Site (SRS). In the late 1970's, the Department of Energy recognized that there were significant safety and cost advantages associated with immobilizing the high-level waste in a stable solid form. Several alternative waste forms were evaluated in terms of product quality and reliability of fabrication. This evaluation led to a decision to build the Defense Waste Processing Facility (DWPF) at SRS to convert the easily dispersed liquid waste to borosilicate glass. In accordance with the NEPA (National Environmental Policy Act) process, an Environmental Impact Statement was prepared for the facility, as well as an Environmental Assessment of the alternative waste forms, and issuance of a Record of Decision (in December, 1982) on the waste form. The Department of Energy, recognizing that start-up of the DWPF would ...
The Department of Energy currently has over 100 million liters of high-level radioactive waste in storage at the Savannah River Site (SRS). In the late 1970`s, the Department of Energy recognized that there were significant safety and cost advantages associated with immobilizing the high-level waste in a stable solid form. Several alternative waste forms were evaluated in terms of product quality and reliability of fabrication. This evaluation led to a decision to build the Defense Waste Processing Facility (DWPF) at SRS to convert the easily dispersed liquid waste to borosilicate glass. In accordance with the NEPA (National Environmental Policy Act) process, an Environmental Impact Statement was prepared for the facility, as well as an Environmental Assessment of the alternative waste forms, and issuance of a Record of Decision (in December, 1982) on the waste form. The Department of Energy, recognizing that start-up of the DWPF would ...
Liquid high-level nuclear waste will be immobilized at the Savannah River Site (SRS) by vitrification in borosilicate glass. The glass will be produced and poured into stainless steel canisters in the Defense Waste Processing Facility (DWPF). Eventually these canistered waste forms will be sent to a geologic repository for final disposal. In order to assure acceptability by the repository, the Department of Energy has defined requirements which DWPF canistered waste forms must meet. These requirements are the Waste Acceptance Preliminary Specifications (WAPS). The WAPS require DWPF to identify the crystalline phases expected to be present in the final glass product. Knowledge of the thermal history of the borosilicate glass during filling and cooldown of the canister is necessary to determine the amount and type of crystalline phases present in the final glass product. Glass samples of seven projected DWPF compositions were cooled following the ...
The kinetics of {sup 14}C-photosynthate import by developing wheat grains was followed after pulse-labeling the flag leaf with {sup 14}CO{sub 2}. Samples were collected from four successive points along the transport pathway to and within the grain: exuding aphid stylets on the peduncle, exuding grain pedicels, the grain crease tissues, and the liquid contents of the endosperm cavity. In addition, microautoradiographs were prepared of the grain crease tissues during movement of the {sup 14}C pulse into the grain. At all times, sucrose accounted for 93 to 97% of the total {sup 14}C present at all four sampling sites. The main features of the {sup 14}C kinetics could be accounted for by a simple compartmental model consisting of sucrose pools in series. Microautoradiographs of the crease tissues showed fairly uniform labeling of vascular parenchyma at all times, with a sharp gradient in labeling across the chalaza to the nucellus. Thus the ...
A number of different theoretical approaches have been used to model to atomic structure and properties of solid-liquid interfaces. Most calculations indicate that ordering occurs in the first several layers of the liquid, adjacent to the crystal surface. In contrast to the numerous theoretical investigations, there have been no direct experimental observations of the atomic structure of a solid-liquid interface for comparison. Saka et al. examined solid-liquid interfaces in In and In-Sb at lattice-fringe resolution in the TEM, but their data do not reveal information about the atomic structure of the liquid phase. The purpose of this study is to determine the atomic structure of a solid-liquid interface using a highly viscous supercooled liquid, i.e., a crystal-amorphous interface.
Nanoparticles of silver halides have been prepared by mixing silver halide powder with a single liquid phase consisting of an ionic liquid, isooctane, n-decanol and water. Much higher nanoparticle concentrations may be formed with ionic liquids using this new simple method than are found with conventionally applied surfactants. This method also emphasizes the applicability of ionic liquids as versatile components in microemulsions and as solvents for the synthesis of nanomaterials. The effect on the nanoparticles of changing the composition of the liquid mixtures and the nature of the ionic liquid is analysed. High nanoparticle concentrations were only found with chloride based ionic liquids, indicating the importance of the ionic liquid anion in the mechanism of the reaction.
This paper details the development of a decontamination approach for the West Valley Demonstration Project (WVDP), Decontamination Project Plan (Plan). The WVDP is operated by West Valley Nuclear Services Company (WVNSCO), a subsidiary of Westinghouse Government and Environmental Services, and its parent companies Washington Group International and British Nuclear Fuels Limited (BNFL). The WVDP is a waste management effort being conducted by the United States Department of Energy (DOE) at the site of the only commercial nuclear fuel reprocessing facility to have operated in the United States. This facility is part of the Western New York Nuclear Service Center (WNYNSC), which is owned by the New York State Energy Research and Development Authority (NYSERDA). As authorized by Congress in 1980 through the West Valley Demonstration Project Act (WVDP Act, Public Law 96-368), the DOE's primary mission at the WVDP is to solidify high-level ...
Coupled modeling of subsurface multiphase fluid and heat flow, solute transport and chemical reactions can be used for the assessment of acid mine drainage remediation, mineral deposition, waste disposal sites, hydrothermal convection, contaminant transport, and groundwater quality. Here they present a numerical simulation model, TOUGHREACT, which considers non-isothermal multi-component chemical transport in both liquid and gas phases. A wide range of subsurface thermo-physical-chemical processes is considered. The model can be applied to one-, two- or three-dimensional porous and fractured media with physical and chemical heterogeneity. The model can accommodate any number of chemical species present in liquid, gas and solid phases. A variety of equilibrium chemical reactions is considered, such as aqueous complexation, gas dissolution/exsolution, cation exchange, and surface complexation. Mineral ...
There are five tasks within this project on thermally stable coal-based jet fuels. Progress on each of the tasks is described. Task 1, Investigation of the quantitative degradation chemistry of fuels, has 5 subtasks which are described: Literature review on thermal stability of jet fuels; Pyrolytic and catalytic reactions of potential endothermic fuels: cis- and trans-decalin; Use of site specific {sup 13}C-labeling to examine the thermal stressing of 1-phenylhexane: A case study for the determination of reaction kinetics in complex fuel mixtures versus model compound studies; Estimation of critical temperatures of jet fuels; and Surface effects on deposit formation in a flow reactor system. Under Task 2, Investigation of incipient deposition, the subtask reported is Uncertainty analysis on growth and deposition of particles during heating of coal-derived aviation gas turbine fuels; under Task 3, Characterization of solid gums, sediments, and carbonaceous deposits, ...
The biological age (BA) of the majority of the liquidators of the consequences of the radiation accidents in the Navy and of the liquidators of the Chernobyl' APS accident exceeds the medium standard and the DBA (due BA). The index of the BA can be a characteristic of the influence of the social-hygienic factors on the health condition of the Special Risk Subunit--the liquidators of the consequences of the radiation accidents. It was established, that the radiation influence concerns to the factors dramatically increasing the BA and the rate of senescence of the liquidators of the consequences of the radiation accidents. PMID:21809627
This handbook is a unique compendium of knowledge on all aspects of the physics of liquid crystals. In over 500 pages it provides detailed information on the physical properties of liquid crystals as well as the recent theories and results on phase transitions, defects and textures of different types of liquid crystals. An in-depth understanding of the physical fundamentals is a prerequisite for everyone working in the field of liquid crystal research. With this book the experts as well as graduate students entering the field get all the information they need.
Research at the Savannah River Technology Center aided development of a technical design basis for a Waste Treatment Plant (WTP) to pre-treat and vitrify Hanford tank waste as part of the River Protection Project (RPP). The research addresses safety concerns, process optimization, and waste form compliance. This program will provide technical data to ensure that the process functions as it was designed and minimizes costs.
The ROI Proposal Preparation Guide is a tool to assist Hanford waste generators in preparing ROI proposal forms for submittal to Department of Energy, Richland Operations Office (DOE/RL) for funding. The guide describes the requirements for submitting an ROI proposal and provides examples of completed ROI forms. The intent is to assist waste generators in identifying projects that meet the criteria, provide information necessary to complete the ROI forms, and submit a proposal that is eligible to receive funding.
This document provides an inventory of Tank Farm equipment stored or abandoned aboveground and potentially subject to regulation. This inventory was conducted in part to ensure that Westinghouse Hanford Company (WHC) does not violate dangerous waste laws concerning storage of potentially contaminated equipment/debris that has been in contact with dangerous waste. The report identifies areas inventoried and provides photographs of equipment.
The Fast Flux Test Facility on the federal reservation at Hanford, Washington, has become a bright star in the universe of nuclear science and engineering technologies. The entire FFTF enterprise is now a success story, and this is particularly significant in these days when good news about nuclear power is scarce. The reactor, its testing capabilities and associated test facilities are described.
These guidelines discuss in more detail the radiological design review process used by the Project Hanford Management Contractors as described in HNF-PRO-1622, Radiological Design Review Process. They are intended to supplement the procedure by providing background information on the design review process and providing a ready source of information to design reviewers. The guidelines are not intended to contain all the information in the procedure, but at points, in order to maintain continuity, they contain some of the same information.
This document provides data on aerosol concentrations in tank headspaces, total mass of aerosols in the tank headspace, and mass of aerosols sent to the exhauster during rotary mode core sampling from November 1994 through June 1999. A decontamination factor for the RMCS exhauster filter housing is calculated based upon operational data and non-destructive assay.
This document provides data on aerosol concentrations in tank head spaces, total mass of aerosols in the tank head space and mass of aerosols sent to the exhauster during Rotary Mode Core Sampling from November 1994 through June 1999. A decontamination factor for the RMCS exhauster filter housing is calculated based on operation data.
(-)-N6-(R-4-Hydroxyphenylisopropyl)adenosine (HPIA) was iodinated with NaI and trace /sup 125/I. Mono- and diiodinated reaction products and the starting material were separated by high pressure liquid chromatography and the structures of the reaction products were verified by NMR. (-)-N6-(R-Phenylisopropyl)adenosine (PIA), IHPIA, and I2HPIA decreased rat atrial contractility with ED50 values of 24, 28, and 33 nM, respectively. The contractile effects of these compounds were competitively blocked by theophylline (KI . 7.9 microM), but were not affected by adenosine deaminase. IHPIA also inhibited (-)isoproterenol-stimulated cyclic AMP accumulation in adipocytes with an ED50 (10 nM) and to an extent (83%) nearly identical to PIA. (/sup 125/I)HPIA prepared using carrier-free /sup 125/I bound to adenosine receptors on membranes from rat cerebral cortex, adipocyte ghosts, and heart ventricles. Binding was inhibited stereospecifically by PIA and by other adenosine ...
While tritium exposure to the site-workers in Wolsung NPP is upto about 40 % of the total personnel exposure, Korea Institute of Nuclear Safety has asked tritium removal facility, as one of the requirements for post reactor construction, after operation of four CANDU reactors in Wolsung site. For the purpose of essential removal of tritium from the heavy water system of the heavy water reactors, an experiment of Ar-N{sub 2} cryogenic distillation tower was carried out as a preliminary study for development of liquid-phase catalytic exchange - cryogenic hydrogen distillation process. The steady-state reached after 50 minutes under 90 K in the Ar-N{sub 2} distillation column (inner diameter 20 mm, height 500 mm) packed with Dixon ring ({phi} 3 mm x H 3 mm), and the ratios of Ar-concentration at the top and at the bottom measured by gas chromatography within {+-}1 % relative error was approximately 93 : 3. This value was ...
Laser excited luminescence and site selective excitation spectra of trivalent terbium (Tb{sup 3+}) in two rare earth oxyfluoride (ROF) matrices, LaOF and GdOF, were detected at temperatures down to liquid helium. From the analyses of spectra, the crystal field (c.f.) fine structure of the {sup 7}F{sub J} (J=0-6) ground multiplet was obtained for the 4f{sup 8} electron configuration. The energy level schemes comprising 26 c.f. sublevels out of 33 allowed for the C{sub 3v} point symmetry of the R{sup 3+} site were simulated according to a phenomenological model taking into account only the c.f. effect. The simulation including six c.f. parameters (B{sub 0}{sup 2}, B{sub 0}{sup 4}, B{sub 3}{sup 4}, B{sub 0}{sup 6}, B{sub 3}{sup 6}, and B{sub 6}{sup 6}) reproduced the experimental energy level schemes in a satisfactory manner with rms deviations of 5 and 6 cm{sup -1} for the LaOF and GdOF hosts, respectively. The c.f. parameter ...
Laser excited luminescence and site selective excitation spectra of trivalent terbium (Tb"3"+) in two rare earth oxyfluoride (ROF) matrices, LaOF and GdOF, were detected at temperatures down to liquid helium. From the analyses of spectra, the crystal field (c.f.) fine structure of the "7F_J (J=0-6) ground multiplet was obtained for the 4f"8 electron configuration. The energy level schemes comprising 26 c.f. sublevels out of 33 allowed for the C_3_v point symmetry of the R"3"+ site were simulated according to a phenomenological model taking into account only the c.f. effect. The simulation including six c.f. parameters (B_0"2, B_0"4, B_3"4, B_0"6, B_3"6, and B_6"6) reproduced the experimental energy level schemes in a satisfactory manner with rms deviations of 5 and 6 cm"-"1 for the LaOF and GdOF hosts, respectively. The c.f. parameter sets are characterized by B_0"2 values close to zero while the fourth and sixth rank ...
The influence of the main factors on device efficiency of pulsed liquid jet pump with gas-liquid piston is analysed, the theoretical equation and its time-averaged solution of pulsed liquid jet pump device efficiency are derived. The theoretical and experimental results show that the efficiency of transmission of energy and mass to use pulsed jet is greatly raised, compared with steady jet, in the same device of liquid jet pump. The calculating results of time-averaged efficiency of pulsed liquid jet pump are approximately in agreement with the experimental results in our and foreign countries
Miscanthus is a potential feedstock for the production of biofuels. Lignocellulosic biomass is not soluble in conventional solvents, but Miscanthus and other lignocellulosic biomass have reasonable solubilities in some ionic liquids. The solubility of Miscanthus in a variety of hydrophilic ionic liquids was measured as a function of particle size, temperature and time for dissolution. In addition to temperature and time, the ionic liquid anion has a significant effect on solubility and rate of dissolution. The moisture content of Miscanthus lowers its solubility in certain ionic liquids. Chloride, acetate, and phosphate-based ionic liquids favor solubility. A tentative correlation for the solubility of Miscanthus is proposed in terms of Abraham solvation parameters obtained from quantum-ch...
... Title : Wear Rate and Friction Coefficient in Liquid Nitrogen and Hydrogen of Steel Sliding on Polymer Laminates (Various Fabrics and Polymers. ...
A technique for quantitative determination of cephalothin and desacetylcephalothin in serum using a method based on high-pressure liquid chromatography is described. Both compounds were quantitatively...Full Text Available
Sep 21, 2006 ... NASA has selected Air Products and Chemicals, Inc., Allentown, Pa., to design, furnish and install a plant to produce liquid nitrogen for ...
Under the repository storage conditions of Eram and Konrad, waste packages designed for permanent storage must not contain or release freely mobile liquids, except for the minimum residues attainable by reasonable efforts or unavoidable. In accordance with a directive issued by the German Federal Ministry for the Environment (BMU), waste conditioning must be carried out so as to minimize waste volumes and, if possible, on the site where the waste arises. Liquid waste is conditioned most effectively by drying. At the present time, various different processes for drying liquid waste are employed as reflected by the state of the art: The Robe process; roller drying; the RDA process; Favorit; in-drum drying; and HPA liquid waste drying with make-up feed. The HPA process offers these advantages: Drying under atmospheric conditions, which means high level of dryness (freely mobile and ...
In this paper, the compulsory site requirements and the site design assumptions which are being used for the present ITER plant are briefly described. A set of different parameters from the site design assumptions is also described, which was adopted as an additional exercise for cost sensitivity analysis of the ITER plant for these parameters. (orig.) 1 refs.
In this paper, the compulsory site requirements and the site design assumptions which are being used for the present ITER plant are briefly described. A set of different parameters from the site design assumptions is also described, which was adopted as an additional exercise for cost sensitivity analysis of the ITER plant for these parameters. (orig.)
In order to reduce the potential for severe liquid pipeline accidents, the U.S. Materials Transportation Bureau (MTB) proposes to require a hydrostatic test on all onshore pipelines carrying highly volatile liquids which have not been previously tested to at least 1.25 times their maximum operating pressure for at least 24 hr. Comments should be received by the MTB by 2/15/79. Late filed comments will be considered as far as practicable.
The review is devoted to the use of ionic liquids as solvents, immobilized organocatalysts and reagents in reactions involving carbon acids and 1,3-dipoles, which are widely used to prepare practically valuable organic compounds of various classes. The characteristic features of processes in the presence of ionic liquids, the effects of the structure of cations and anions on the regio-, stereo- and enantioselectivities of reactions and methods of recovery of ionic liquids are considered.
A composition of matter to treat particles entrained in flue gas, is described comprising: a caustic liquid used to adjust resistivity of the entrained particles; and inert particulate matter supporting the caustic liquid for inhibiting chemical action of the caustic liquid until used to adjust the resistivity of the entrained particles, the inert particulate matter supporting sufficient caustic liquid to adjust the resistivity of the entrained particles.
A qualitatively different manifestation of the Rayleigh instability is demonstrated, where, instead of the usual extended undulations and breakup of the liquid into many droplets, the instability is localized, leading to an isolated narrowing of the liquid filament. The localized instability, caused by a nonuniform curvature of the liquid domain, plays a key role in the evaporation of thin liquid films off solid surfaces.
A length of metal sheathed metal oxide cable is perforated to permit liquid access to the insulation about a pair of conductors spaced close to one another. Changes in resistance across the conductors will be a function of liquid level, since the wetted insulation will have greater electrical conductivity than that of the dry insulation above the liquid elevation.
Tthe acceleration of a liquid from a cylindrical container by the products of instantaneous detonation of a superimposed explosive charge (implosion method) is studies numerically in a two-dimensional formulation. Analytical formulas for the asymptotic velocities of liquid expansion and acceleration of the container body were obtained using numerical calculations in a one-dimensional approximation. The effect of the fracture of the body on the velocity of liquid expansion was studied in a two-dimensional formulation.
A description is given of an automatic liquid nitrogen pumping system. Pamping of liquid nitrogen iato cooling traps up to a predetermined level is achieved by an automatically controlled compressed air system. An impontant feature of the equipment is the ability to switch automatically from an empty liquid nitrogen reservoir to a full one. This allows for a much more flexible operation than in conventional systems where the reservoir has to be replaced manually when empty. (auth)
Co-current stratified flow of liquid metal and water was investigated in a horizontal rectangular channel. Position of the interface pressure drop and direct contact heat transfer between these immisci ble liquids were measured in a fully developed flow. A turbulence model was proposed to explain the experimental results considering that the turbulence is damped near the liquid-liquid interface by surface tension. The analytical results showed good agreement with the experimental ones. Main results are that (1) position of the interface mainly depends on the flow rate ratio of both liquids, that (2) the pressure drop is approximately proportional to square of the average velocity of water, and that (3) heat transfer rate at direct contact interface is several times higher than that of co-current flow separated by a thin solid plate. (author).
Hydrothermal systems typically consist of hot permeable rock which contains either liquid or liquid and saturated steam within the voids. These systems vent fluids at the surface through hot springs, fumaroles, mud pools, steaming ground and geysers. They are simultaneously recharged as meteoric water percolates through the surrounding rock or through the active injection of water at various geothermal reservoirs. In a number of geothermal reservoirs from which significant amounts of hot fluid have been extracted and passed through turbines, superheated regions of vapor have developed. As liquid migrates through a superheated region of a hydrothermal system, some of the liquid vaporizes at a migrating liquid-vapor interface. Using simple physical arguments, and analogue laboratory experiments we show that, under the influence of gravity, the liquid-vapor ...
Thermal hydraulics of a liquid metal is important to design the blanket of a magnetic confined fusion reactor. Since a liquid metal has high thermal and electrical conductivity, the flow characteristics are often different from those of an ordinary liquid like water especially in thermal convection and under a magnetic field. It is difficult to simulate such flows in a liquid metal cooled blanket by water. Flow visualization is a popular method to study thermal hydraulics. Since most of metals are visible by neutron rays, neutron radiography is available to the flow visualization of a liquid metal. The purpose of this study is to develop a visualization technique of the flow in a liquid metal by real-time neutron radiography using the tracer and the dye injection methods. A real-time thermal neutron radiography system of JRR-3M in Japan Atomic Energy Research ...
Thermal hydraulics of a liquid metal is important to design the blanket of a magnetic confined fusion reactor. Since a liquid metal has high thermal and electrical conductivity, the flow characteristics are often different from those of an ordinary liquid like water especially in thermal convection and under a magnetic field. It is difficult to simulate such flows in a liquid metal cooled blanket by water. Flow visualization is a popular method to study thermal hydraulics. Since most of metals are visible by neutron rays, neutron radiography is available to the flow visualization of a liquid metal. The purpose of this study is to develop a visualization technique of the flow in a liquid metal by real-time neutron radiography using the tracer and the dye injection methods. A real-time thermal neutron radiography system of JRR-3M in Japan Atomic Energy Research ...
An all-atom polarizable chloroform (CHCl{sub 3}) potential model has been developed using the classical molecular dynamics techniques. This potential is shown to reproduce reasonably well the structural, dynamical, and thermodynamic properties of bulk liquid CHCl{sub 3} at various temperatures and pressures. With this potential, we carried out computer simulations to investigate the CHCl{sub 3}-H{sub 2}O liquid/liquid interface. Detailed structural and electrical properties at the interface will be analyzed via the density profile, radial distribution functions, molecular orientation, hydrogen bonding, and the z-dependent dipole distributions. Comparison will also be made to the results of the CCl{sub 4}-H{sub 2}O liquid/liquid interface.
The atomic mechanism of a glass-to-liquid transition in a monatomic Lennard-Jones (LJ) glass was studied using the molecular dynamics (MD) method. Glassy models were heated up from low temperature at two different heating rates and a glass-to-liquid transition found to occur at the higher heating rate. The temperature dependence of the potential energy, mean-squared-displacements (MSD) of the atoms and the self-intermediate scattering function indicate clearly that a glass transition occurs in the system. The atomic mechanism of the glass-to-liquid transition was investigated by analyzing the spatio-temporal arrangement of liquid-like atoms in the system upon heating. Liquid-like atoms were detected using the Lindemann-melting-like criterion. Upon heating, liquid-like atoms occur at temper...
Five cycles of loading, elution, and regeneration were performed to remove technetium from a Hanford waste sample retrieved from Tank 241-AW-101 using SuperLig 639 resin. The waste sample was diluted to 4.95 M Na plus and then was processed to remove 137Cs through dual ion exchange columns each containing 15 mL of SuperLig 644. To remove 99Tc, the cesium decontaminated solution was processed downwards through two ion exchange columns, each containing 12 mL of SuperLig 639 resin. The columns, designated as lead and lag, each had an inside diameter of 1.45 cm and a height of 30 cm. The columns were loaded in series, but were eluted and then regenerated separately. The average technetium loading for the cycles was 250 BV at 10 percent breakthrough. There was no significant difference in the loading performances among the five cycles. The percent removal of 99Tc was greater than 99.94 percent and the average decontamination factor (DF) was approximately 1.7 x 103. ...
This hazard analysis (HA) has been prepared for the 300 Area N Reactor Fuel Fabrication and Storage Facility (Facility), in compliance with the requirements of Westinghouse Hanford Company (Westinghouse Hanford) controlled manual WHC-CM-4-46, Nonreactor Facility Safety Analysis Manual, and to the direction of WHC-IP-0690, Safety Analysis and Regulation Desk Instructions, (WHC 1992). An HA identifies potentially hazardous conditions in a facility and the associated potential accident scenarios. Unlike the Facility hazard classification documented in WHC-SD-NR-HC-004, Hazard Classification for 300 Area N Reactor Fuel Fabrication and Storage Facility, (Huang 1993), which is based on unmitigated consequences, credit is taken in an HA for administrative controls or engineered safety features planned or in place. The HA is the foundation for the accident analysis. The significant event scenarios identified by this HA will be further evaluated in a ...
The underground storage tanks at the Hanford Complex contain mixed wastes generated over many years from plutonium production and recovery processes. The chemical changes of the organic materials used in the extraction processes and disposed to the tanks have a direct bearing on several specific safety issues, including potential energy releases from these tanks. This paper will give details of a study that is directed towards elucidating thermal and radiological decomposition mechanisms and products of the organic contents of the tanks. The study is being conducted in two parts. The first part, an aging study, will determine kinetics and products of the degradation of a simulated waste subjected to #gamma#-radiation from an external source. Although the simulant will not contain radioactive elements, it will contain other representative inorganic compounds and the primary organic compounds thought to have been disposed to the tanks. The second part of the ...
A schematic diagram shows the various processing steps to be performed during feed preparation in the Hanford Waste Vitrification Plant (HWVP). The pretreated NCAW is transferred to the slurry receipt adjustment tank (SRAT) in the HWVP for concentration. Water removed during boildown is collected in the slurry mix evaporator condensate tank (SMECT). After waste treatment the water is returned to the storage tanks for eventual disposal. The pretreated Neutralized Current Acid Waste (NCAW) is concentrated in the SRAT to approximately 125 g waste oxides/ liter. Formic acid is then added at a controlled rate to improve rheological properties and achieve a required reduction/oxidation state. Reflux boiling is initiated and continued for several hours. The concentrated slurry is cooled and pumped to the slurry mix evaporator (SME). In the SME, glass frit is added, and the slurry is further concentrated to achieve a nominal composition of 500 g total oxides/liter. This ...
The study is concerned with the Stefan problem of evaporation of a volatile component from its solution with a virtually non-volatile material. The analysis provides an analytical solution to the problem based on mass-transfer fundamentals. Results yield the evaporation rate, interfacial mole fractions, concentration profiles in the gas and liquid phases, and the location of the evaporation front. The analysis can be used to provide the binary liquid diffusion coefficient of the volatile component based on experimental data for the liquid gas interface position as a function of time. The requirements for such a measurement are discussed in terms of the volatility of the evaporating component and its initial concentration in the liquid mixture.[Figure not available: see fulltext.
The temperature and pressure dependence of the mobilities of negative charges injected into liquid hydrogen and deuterium have been measured. The authors propose the existence of two types of charge carriers in liquid parahydrogen. One is a bubble with an electron inside while the other has higher mobility. Relaxation of the current through liquid hydrogen was observed. It is suggested that in liquid and solid hydrogen under {beta}-irradiation neutral complexes are created which can trap the negative charges and have a lifetime of about 10 hours. 6 refs., 5 figs.
This document outlines the significant accomplishments of fiscal year 1998 for the Tank Waste Remediation System (TWRS) Project Hanford Management Contract (PHMC) team. Opportunities for improvement to better meet some performance expectations have been identified. The PHMC has performed at an excellent level in administration of leadership, planning, and technical direction. The contractor has met and made notable improvement of attaining customer satisfaction in mission execution. This document includes the team`s recommendation that the PHMC TWRS Performance Expectation Plan evaluation rating for fiscal year 1998 be an Excellent.
In October 1992, the US Department of Energy, Richland Field Office (RL) requested that Westinghouse Hanford Company (WHC) respond to a letter from EM-331 asking for completion of a survey of items in storage but not categorized as waste (Roberts 1992). The letter contained an attachment with instructions on how to fill out the attached form and what to exclude from the survey (Appendix A). This report is a summary of the information from the response issued to RL. This report primarily is for use in estimating future waste volumes that may have been overlooked because of the nature of their classification as material not categorized as waste (MNCAW) (i.e., not yet declared Waste).
This document is a Maintenance Implementation Plan (MIP) for the T Plant Facility complex located in the 200 West Area of the Hanford Reservation in Washington state. This plan has been developed to provide a disciplined approach to maintenance functions and to describe how the T Plant facility will implement and comply with the regulations according to US DOE order 4330.4B, entitled Maintenance Management Program, Chapter 2.0 {open_quotes}Nuclear Facilities{close_quotes}. Physical structures, systems, processes, as well as all associated equipment specifically assigned to these groups are included in the MIP.
Before low-level waste may be disposed of, a performance assessment must be written and then approved by the DOE (DOE 1988a DOE 1999a). The performance assessment is to determine whether ''reasonable assurance'' exists that the performance objectives of the disposal facility will be met. The DOE requirements for waste disposal (DOE 1988a DOE 1999a) require the protection of public health and safety; and the protection of the environment. Although quantitative limits are sometimes stated (for example, the all-pathways exposure limit is 25 mrem/year), usually the requirements are stated in a general nature. Quantitative limits were established by: investigating all potentially applicable regulations as well as interpretations of the review panels which DOE has established to review performance assessments, interacting with program management to establish the additional requirements of the program, and interacting with the public (i.e., the ...
The US Department of Energy (DOE) is now evaluating its facility requirements in support of its cleanup mission at Hanford. One of the early findings is that the 200-Area steam plants, constructed in 1943, will not meet future space heating and process needs. Because the 200 Area will serve as the primary area for waste treatment and long-term storage, a reliable steam supply is a critical element of Hanford operations. This Analysis and Decision Document (ADD) is a preliminary review of the steam supply options available to the DOE. The ADD contains a comprehensive evaluation of the two major acquisition options: line-term versus privatization. It addresses the life-cycle costs associated with each alternative, as well as factors such as contracting requirements and the impact of market, safety, security, and regulatory issues. Specifically, this ADD documents current and future steam requirements for the 200 Area, describes alternatives ...
This paper examines the role that carbon dioxide capture and storage technologies could play in reducing greenhouse gas emissions if a significant unconventional fuels industry were to develop within the United States. Specifically, the paper examines the potential emergence of a large scale domestic unconventional fuels industry based on oil shale and coal-to-liquids (CTL) technologies. For both of these domestic heavy hydrocarbon resources, this paper models the growth of domestic production to a capacity of 3 MMB/d by 2050. For the oil shale production case, we model large scale deployment of an in-situ retorting process applied to the Eocene Green River formation of Colorado, Utah, and Wyoming where approximately 75% of the high grade oil shale resources within the United States lies. For the CTL case, we examine a more geographically dispersed coal-based unconventional fuel industry. This paper examines the performance of these industries under two ...
Critical power at boiling transition is an important factor in a boiling water reactor (BWR) fuel bundle design. Boiling transition under high quality accounts for dryout as the result of the complete disappearance of film flow on a fuel rod. This liquid film vanishing process can be calculated by the liquid film model, which takes into account the evaporation due to heat from the rod surface, liquid film entrainment by steam flow, and liquid droplet deposition. It is known that spacers affect liquid film entrainment and liquid droplet deposition, so the detailed study of spacer effects on hydrodynamic characteristics is necessary for critical power prediction based on the film flow model. Many studies have been conducted to examine spacer effects on liquid film flow. However, most of them are restricted to simple test sections such as a ...
Macrokinetics of benzene sulfonation in liquid-liquid and gas-liquid systems has been studied in continuous mixed reactors. It has been shown that the rate of sulfonation of benzene at 25/sup 0/C in two liquid phases using concentrated sulfuric acid is kinetically controlled. Whereas the rate of the latter reaction by gaseous sulfur trioxide at the same temperature is largely affected by the diffusional phenomena. At this temperature, the rate of reaction in gas-liquid system was described by a model assuming a fast reaction in the liquid phase. However, by increasing the temperature, the fast reaction region gradually changed to instantaneous reaction regime. A model, describing such a regime has also been developed and verified experimentally.
Purpose: To enable the solidification of liquid waste containing radioactive substance in a free shape with large volume reduction ratio without a pulverizing step by producing solute in the liquid waste as a slurry in a predetermined organic solvent and forming it into a cake by mechanical exfoliation. Method: Liquid waste containing suitably concentrated radioactive substances is supplied to a centrifugal thin film evaporator together with an organic agent having a higher boiling point than water and a non aqueous solution to evaporate the water content, the solute in the waste is produced as a slurry in the organic solvent, and removed as cake-state solute slightly residued with the organic solvent by the mechanical exfoliation such as centrifugal exfoliation or settling exfoliation from the slurry-state liquid. Accordingly, it can be increased in size as compared with the powder reduced in volume of ...
Both simulations and recent experiments conducted at the Advanced Photon Source showed that the performance of liquid-nitrogen-cooled single-silicon crystal monochromators can degrade in a very rapid nonlinear fashion as the power and for power density is increased. As a further step towards improving the performance of silicon optics, we propose cooling with liquid helium, which dramatically improves the thermal properties of silicon beyond that of liquid nitrogen and brings the performance of single silicon-crystal-based synchrotrons radiation optics up to the ultimate limit. The benefits of liquid helium cooling as well as some of the associated technical challenges will be discussed, and results of thermal and structural finite elements simulations comparing the performance of silicon monochromators cooled with liquid nitrogen and helium will be given.
This study resumes the discovery of an excess of actinium 227 found around by EL4 nuclear reactor actually in dismantling. The search for the origin of this excess revealed a real inquiry of investigation during three years. Because a nuclear reactor existed in this area a particular attention will have concerned this region. The doubt became the line of conduct to find the answer to the human or natural origin of this excess. Finally and against any evidence, it appears that the origin of this phenomenon was natural, consequence of the particular local geology. The detail of the different investigations is given: search of a possible correlation with the composition of elevations constituent of lanes, search (and underlining) of new sites in the surroundings of the Rusquec pond and the Plouenez station, study of the atmospheric deposits under winds of the nuclear power plant and in the east direction, search of a possible relationship with the gaseous effluents of ...
Full text: There are following general tendencies linking to SNF and radioactive waste management (RWM) in the Russian nuclear industry now. The intention to use the closed nuclear fuel cycle based on power water reactors and fast reactor. The intensification of measures aimed at the solution of 'nuclear legacy' from defenses programs of USSR. The intention to improve the existing national RW management infrastructure in the near years by means of the creation of a centralized national system (including managing corporation responsible for operation of long-storage and disposal facilities of conditioned RW). The main aims radioactive waste management (RWM) in nuclear power plants (NPP) for the next 10-15 years are to equip all NPPs with the necessary set of facilities for conditioning of the stored and currently generated RW with packaging the end-product into containers, to build regional NPPs RW repositories and to introduce evaporator bottoms selective purification technology from ...
This short survey focuses on the main radiation-induced base lesions that have been identified within cellular DNA. For this purpose, sensitive assays that are aimed at measuring a few modifications per 10{sup 7} normal bases were set-up. In that respect high performance liquid chromatography - tandem mass spectrometry (CLHP-MS/MS) was found to be able to single out the formation of 9 oxidized nucleosides and two modified nucleo-bases out of the 70 oxidative base lesions that have been identified in model systems. As a striking result, it was found that in the DNA of {gamma}-irradiated human monocytes, the formamide-pyrimidine derivative of guanine is produced in a higher yield than the ubiquitous 8-oxo-7,8-dihydro-guanine damage, both arising from the same radical precursor. However, relatively high doses of ionizing radiation (> 20 Gy) have to be applied in order to detect an increase in the level of the damage. This is due to the low efficiency for both ...
The object of this survey of small US electric utility systems was to determine the potential utilization of small, fuel-flexible, advanced-cycle combustion turbines for power generation. Three prototype concepts were evaluated. Concept A: a 2.5 MWe externally fired, closed-cycle combustion turbine, with fluidized-bed combustor, burning solid fuels. Concept B: an open 3.8 MWe, indirect-fired, combined-cycle turbine system using solid, liquid or gaseous fuels, with downstream stack cleanup. Concept C: 11.6 MWe, utilizing an open, direct-fired, combined-cycle turbine arrangement, gas or oil fueled employing components of advanced development. It was presumed such units might be commercially available circa 1985 to 1990. Fifty-three utilities, encompassing a variety of ownerships, geographical distribution and system sizes, were interviewed on-site. Questions covered the probable use of such generating concepts and their perceived attributes. The ...
This thesis is concerned with the crystallisation behaviour of polymers near to a free surface or a buried interface. The properties of polymers are expected to differ significantly near to an interface (either with air or another polymer), due to the contributions of (a) chain configurations induced at the interface, and (b) different mobilities between interfacial regions and the bulk of the sample. For a semi-crystalline polymer, properties such as the degree of crystallinity and the crystallisation kinetics may be enhanced near to a free surface. Grazing incidence x--ray diffraction (GIXD) is used to investigate such effects in poly(ethylene terphthalate) (PET), showing that a lower crystallisation temperature is obtained at the surface, and the crystallisation kinetics are faster at the surface for all temperatures. It is proposed that in thin films of PET, this surface-induced ordering provides nucleation sites for crystallisation in the bulk. GIXD is also ...
While tritium exposure to the site-workers in Wolsung NPP is up to about 40% of the total personnel exposure, Ministry of Science and Technology has asked tritium removal facility for requirement of post heavy-water reactor construction. For the purpose of essential removal of tritium from the Wolsung heavy-water reactor system, a preliminary study on the cryogenic Ar-N{sub 2} and H{sub 2}-D{sub 2} distillation process for development of liquid-phase catalytic exchange cryogenic hydrogen distillation process technology. The Ar-N{sub 2} distillation column showed good performance with approximately 97% of final Ar concentration, and a computer simulation code was modified using these data. A simulation code developed for cryogenic hydrogen isotopes (H{sub 2}, HD, D{sub 2}, HT, DT, T{sub 2}) distillation column showed good performance after comparison with the result of a JAERI code, and a H{sub 2}-D{sub 2} distillation column was made. Gas ...
The study area is located in the Bekaa plain of Lebanon totaling about 12753 ha. It lies between the eastern foothills of Mount Lebanon chain and expands across the Litani River towards the foothills of the eastern Anti-Lebanon Mountains. Its characteristics, i.e. natural terrain, climate and socio-economy, make it vulnerable especially due to soil pollution. This paper tries to identify the nature and level of soil pollution by heavy metals. Valley slopes represent a complex landform and lithology that contributed to the formation of different soil. Agriculture in the plain is being practiced mainly with cash, field crops and vegetables. Throughout the central part of the plain, groundwater table is abundant and relatively high (<1.0 m. locally) that multiplies the vulnerability of the soil-groundwater system. There are different sources of pollution, such as industrial (tanneries, batteries, leather manufacturing), solid and liquid wastes, and agricultural due ...
of Colorado at Boulder Search This Site Natural Hazards Observer Disaster Research CU Web Site CU People go Search This Site Natural Hazards Observer Disaster Research CU Web...
This report presents geologic considerations that are pertinent to the Remedial Action Plan for Slick Rock mill tailings. Topics covered include regional geology, site geology, geologic stability, and geologic suitability.
The adenovirus fiber knob causes the first step in the interaction of adenovirus with cell membrane receptors. To obtain information on the receptor binding site(s), the interaction of labeled cell...Full Text Available
Expedited site characterization (ESC), developed by Argonne National Laboratory, is an interactive, integrated process emphasizing the use of existing data of sufficient quality, multiple complementary characterization methods, and on-site decision making to optimize environmental site investigations. The Argonne ESC is the basis for the provisional ESC standard guide of the ASTM (American Society for Testing and Materials). QuickSite{sup SM} is the implementation package developed by Argonne to facilitate ESC of sites contaminated with hazardous wastes. At various sites, Argonne has successfully implemented QuickSite{sup SM} and demonstrated the technical superiority of the ESC process over traditional methodologies guided by statistics and random-sampling approaches. A key feature in the success of QuickSite{sup SM} ...
The classical Stefan theory for the melting of a solid or the freezing of a liquid is too simplistic to describe phenomena such as supercooling, in which a liquid supports temperatures below its freezing point, or superheating, the analog for solids, or d...
This paper introduces recent instances of polymerizers for highly viscous liquid needed in the field of synthetic resin and synthetic fiber. A horizontal twin-shaft type polymerizer has two horizontally rotating shafts with stirring blades of spectacle-shaped type, which are arranged at a 90 [degree] phase difference. As they rotate, they scrape highly viscous liquid sticking to the surface inside the polymerizer and on the rotating shafts. This polymerizer is capable of processing highly viscous liquid up to about 2000 Pa[center dot]s. A lattice-type twisting blade polymerizer is a vertical-type reactor and features a special stirring blade capable of stirring highly viscous liquid up to 5000 Pa[center dot]s This polymerizer has no central rotating shaft so that highly viscous liquid does not stick on it. A sloped blade-type thin-film evaporator has spiral blades in the ...
By a direct Archimedes' technique, volumetric data were obtained for liquid In, Mg, Pb, and Sb and mixtures of In-Sb, Mg-Sb, and Pb-Sb. In this paper the excess volumes for the alloys studied are presented and discussed.
A high performance liquid chromatography (HPLC) procedure suitable for the simultaneous determination of the molecular size and concentration of macromolecular hyaluronate and proteoglycans in synovial...Full Text Available
The use of ionic liquids for post combustion capture was discussed. Compared to other solvents, ionic liquids can be used in higher concentrations. Other advantages include the large variation in physical and chemical properties and the non measurable vapor pressure. In this study, 78 different ionic liquids were synthesized and the carbon dioxide absorption rate was measured. The most promising ionic liquids were produced and various tests were made to identify the most suitable absorption solvent. The vapor-liquid equilibrium curve was measured between 40 and 110 degrees C. Pilot plant tests with MEA and one selected ionic liquid test with 30 per cent MEA at the pilot plant at the EVNs Duernrohr Power Station in Lower Austria are running successfully with a capture performance of approximately 87 per cent. The experiments will provide a direct comparison of ...
A new series of lithium ionic liquids were prepared by introducing of two electron-withdrawing trifluoroacetyl groups in borate salts containing two methoxy-oligo(ethylene oxide) groups in the structures. Successive substitution reactions of oligo-ethylene glycol monomethyl ether and trifluroacetic acid from LiBH_4 yielded the lithium salts, which were clear and colorless liquids at room temperature. The fundamental physicochemical properties, such as density, thermal property, viscosity, ionic conductivity, self-diffusion coefficients, and electrochemical stability, were measured. The lithium ionic liquids had self-dissociation ability and conducted ions even in the absence of organic solvents. New polymer electrolytes, named 'ion gels', were prepared by radical cross-linking reactions of a poly(ethylene oxide-co-propylene oxide)tri-acrylate macromonomer in the presence the lithium ionic liquid. An ...
Ionic liquids can enhance the activity, selectivity, and stability of enzyme catalysts. Enzymes and ionic liquids as catalysts are seen as a more environmentally friendly technology than the use of traditional catalyst materials in biofuels production. This study investigated the lipase catalyzed esterification reaction for biodiesel production in the presence of the ionic liquid BMIM PF{sub 6}. Methyl acetate was used as the acyl acceptor. A titremetric assay was conducted to measure the activity of the lipase with various amounts of ionic liquid. Reaction parameters were investigated in order to determine their effects on biodiesel conversion. An 80 per cent overall methyl oleate biodiesel yield was successfully produced in the presence of the ionic liquid. The ionic liquid improved lipase activity as well as overall biodiesel yield. Results also showed that ...
A liquid chromatography/tandem mass spectrometric (LC/MS/MS) assay was developed for the quantitative determination of salirasib (S-trans, trans-farnesylthiosalicylic acid,...Full Text Available
Denaturing high-performance liquid chromatography (DHPLC) has been used extensively to detect genetic variation. We used this method to detect and identify Yersinia pestis KIM5 ciprofloxacin-resistant...Full Text Available
An anion-exchange column technique for extraction of antibiotics from serum proteins has been developed for use in the assay of cephapirin, cefotaxime, and cefoxitin by high-pressure liquid chromatography....Full Text Available
Mitochondrial superoxide production is an important source of reactive oxygen species in cells, and may cause or contribute to ageing and the diseases of ageing. Seven major sites of superoxide...Full Text Available
Quantitative determination of Broensted acid site concentrations in calcined H-mordenite and H-ZSM-5 by means of conductometric titration and infrared spectroscopy reveals that the concentration of Broensted acid sites present is lower than would be expected on the basis of the aluminum content. This discrepancy is attributed to dealumination and dehydroxylation processes occurring during calcination. A model is proposed according to which the degree of these processes strongly depends on the concentration of vicinal aluminum T sites in the zeolite: Broensted acid sites associated with these T sites are lost, and the remaining Broensted acidity is related to the concentration of the (remaining) isolated aluminum T sites. This model quantitatively correlates the experimentally determined concentration of Broensted acid sites with the ...
Washington West Virginia Wisconsin Wyoming Cancer --- Choose a Cancer Site --- All Cancer Sites Bladder Brain & ONS Breast (Female) Breast (Female in situ) Cervix Childhood...
may experience difficulty opening the Facebook page due to current HHS policy and network security that blocks access to the site. Site Map - Contact Us - Linking to USPHS.gov -...
A consistent statistical theory of the crystal-liquid phase transition is developed, being based on a method which takes into account liquidlike fluctuations in crystals and solidlike clusters in liquids. It is shown that degenerate fluidlike droplets have a finite number density at zero temperature, while nondegenerate fluctuations disappear when the temperature goes to zero. The existence of a melting point is proved. This method, which takes into consideration the heterophase fluctuations, provides the possibility of describing metastable states such as a supercooled liquid or an overheated crystal. Conditions for the existence of metastable states are found. The liquid-glass transition can also be described by the method presented here.
This paper presents anew design concept for a gamma irradiation plant for the continuous processing of pumpable liquids. Typical applications of such a plant include: the irradiation vulcanisation of natural latex rubber; disinfection of municipal sewage sludge for agricultural use; sterilisation of liquids in the pharmaceutical and cosmetics industries; industrial processing of bulk liquids The authors describe the design and operation of the latex irradiator now operating on a small production scale in Malaysia and proposed developments. The design allows irradiation processing to be carried out under an inert or other gaseous environment. State-of-the-art computer control system ensures the fully automatic processing operation needed by industrial computers.
We searched for signs of an instability on the interface between the two phases of a binary-liquid mixture, isobutyric acid and water, after the mixture was quenched further into the two-phase region. Such an instability would be the liquid-liquid analog of the Mullins-Sekerka instability seen in quenched alloys. Never is any dramatic growth observed, but under conditions of small dimensionless quench depth (theta<1.5 x 10/sup -3/), the intensity of light scattered from the interface grows for small values of the momentum transfer k.
Scintillation light in liquid xenon excited by 100 MeV/n Al ions was detected with a home-made silicon photodiode. The diameter of the photodiode was 2 inch. The effective quantum efficiency was observed to be 22% for the wavelength of liquid xenon scintillation light (170 nm), while the effective quantum efficiency for 5.486 MeV alpha-particle excitation was 44%. An energy resolution of 0.5% rms was achieved for the energy deposition of 2.5 GeV in liquid xenon using a fast preamplifier ({approx equal} 20 ns). (orig.).
Computational fluid dynamics(CFD) code FLUENT was used to simulate the thermal hydraulic processes occurring in conceptual design of the accelerator-driven subcritical reactor(ADSR) liquid lead target. The purpose of the analysis is to investigate the thermal hydraulic characteristics of liquid lead as ADSR target material with various target geometries and injection locations of proton beam. In the calculation analysis, the local temperature of the liquid lead target rises to the boiling temperature very rapidly. When the proton beam is injected from the bottom of the target system, the duration time to reach the boiling temperature is longer and the temperature distribution is flatter than other cases.
The separation, concentration, and determination of trace elements in iron ores are described. After the sample has been dissolved, the iron is separated by liquid-liquid extraction with a liquid cation-exchanger, di-(2-ethylhexyl) phosphoric acid. The trace elements aluminium, cadmium, calcium, chromium, cobalt, copper, lead, magnesium, manganese, mercury, potassium, sodium, vanadium, and zinc are determined in the aqueous phase by atomic-absorption spectrophotometry.
The Rayleigh scattering length has been calculated for rare-gas liquids in the ultraviolet for the frequencies at which they luminesce. The calculations are based on the measured dielectric constants in the gas phase, except in the case of xenon for which measurements are available in the liquid. The scattering length mayplace constraints on the design of some large-scale detectors, using uv luminescence, being proposed to observe solar neutrinos and dark matter. Rayleigh scattering in mixtures of rare-gas mixtures is also discussed.
A method for the quantitative determination of atmospheric hydroperoxyl radical comprising: (a) contacting a liquid phase atmospheric sample with a chemiluminescent compound which luminesces on contact with hydroperoxyl radical; (b) determining luminescence intensity from the liquid phase atmospheric sample; and (c) comparing said luminescence intensity from the liquid phase atmospheric sample to a standard luminescence intensity for hydroperoxyl radical. An apparatus for automating the method is also included.
A cryostat is described that was developed for irradiating a number of small metal specimens with a high beamcurrent of heavy particles at liquid nitrogen temperature. The specimens, which are mounted on a block, are taken out of the cryostat after irradiation and subsequently annealed in a temperature bath. The progress of annealing is followed by measuring the change in electrical resistivity of the specimens in liquid helium. (auth)
The results of calculated and experimental investigation of interphase isotopic exchange efficiency in countercurrent columns are given when separation processes of isotope mixtures are taken place with use of liquid-solid systems. Effect of liquid phase flow on transfer unit height in ion exchange separation of boron, lithium, nitrogen isotopes is considered. 40 refs.; 5 figs.
It if first shown, that the effective field of uniaxial magnetic anisotropy of Fe-Cr-P-C and Fe-Ni-B-Si system amorphous alloys is reduced with an increase of the source melt isothermal exposure time. The behaviour noted is conditioned by microcoherence and relaxation processes in the nonequilibrium liquid phase after crystal-liquid phase transition.
The geology and hydrology of the reference New Production Reactor (NPR) site at Savannah River Site (SRS) have been summarized using the available information from the NPR site and areas adjacent to the site, particularly the away from reactor spent fuel storage site (AFR site). Lithologic and geophysical logs from wells drilled near the NPR site do not indicate any faults in the upper several hundred feet of the Coastal Plain sediments. However, the Pen Branch Fault is located about 1 mile south of the site and extends into the upper 100 ft of the Coastal Plain sequence. Subsurface voids, resulting from the dissolution of calcareous portions of the sediments, may be present within 200 ft of the surface at the NPR site. The water table is located within 30 to 70 ft of the surface. The NPR ...
The US National Energy Policy of 2001 advocated the development of advanced fuel and fuel cycle technologies that are cleaner, more efficient, less waste-intensive, and more proliferation resistant. The need for advanced fuel development is emphasized in on-going DOE-supported programs, e.g., Global Nuclear Energy Initiative (GNEI), Advanced Fuel Cycle Initiative (AFCI), and GEN-IV Technology Development. The Directorates of Energy & Environment (E&E) and Chemistry & Material Sciences (C&MS) at Lawrence Livermore National Laboratory (LLNL) are interested in advanced fuel research and manufacturing using its multi-disciplinary capability and facilities to support a design concept of a small, secure, transportable, and autonomous reactor (SSTAR). The E&E and C&MS Directorates co-sponsored this Laboratory Directed Research & Development (LDRD) Project on Mono-Uranium Nitride Fuel Development for SSTAR and Space Applications. In fact, three out ...
The following paragraphs summarize the progress of each research project funded under the WVU Cooperative Agreement during the third quarter of 1997 (July - September 1997). The projects are arranged according to their 1997 WVU task number. WVU Focus Area 1.0: Subsurface Contaminants, Containment and Remediation Task No. 1.1: Project discontinued. Task No. 1.2: Development of Standard Test Protocols and Barrier Design Models for Desiccation Barriers (K. Amininan & S. Ameri): A number of experiments were preformed this period to evaluate the ability of the dried sand-packs to act as a barrier to liquids. Water infiltration tests were done with a constant head, dispersing 80 ml of water, and by adding water in small increments. Results indicate that when the water is spilled over the sand-pack, it has the tendency to channel through the sand-pack, significantly reducing the capacity of the dried zone to retain liquid contaminants. This ...
TiO{sub 2} is a vital material in several technologies including, photocatalysis, gas sensing, biomaterials and optical coatings. Among the several crystal structures of this oxide, rutile has the highest density and microhardness, the highest index of refraction and the highest temperature stability. The processing of dense polycrystalline materials often includes the addition of a liquid-forming phase at higher temperatures. This technique is known as liquid-phase sintering and has been studied extensively. Rutile boundaries containing an amorphous phase have been used to study boundary migration and grain-boundary grooving. Visible-light (VLM), scanning electron (SEM) and transmission electron microscopy (TEM) in addition to electron-backscatter diffraction (EBSD) and a focused-ion beam (FIB) tool were used to characterize boundary migration in rutile. EBSD analysis was carried out on a Philips XL30 FEG SEM equipped with a DigiView 1612 ...
The evolution of metallic substance atomic structure is studied on temperature variation including crystal heating up to melting points, a crystal- liquid phase transition and initiation of a high-density liquid specific structure. It is marked that heat induced changes of simple metal structure can be described as changes around a natural elementary cell which is common for both a crystal and a liquid and consists of a central atom and Z_1 atoms of the first coordination sphere. On this basis the vacancy model of melting is verified. Concentrations of melting vacancies are determined by coordination numbers in the form of Z_1/(1+Z_1)"2 which are the same for both a crystal and a natural elementary cell. The size of natural elementary cells is in an agreement with that of the coordination sphere featured in the liquid and phase transition statistical theory. Calculated data are given for a number of ...
The thermal conductivity of liquid CHCl3, C6H6, and CCl4 is measured by a steady-state method under saturated vapor pressure in the temperature regions corresponding to pre-crystallization temperatures. The experimental results obtained are used to investigate the isobaric thermal conductivity jump ? ?p at the crystal-liquid phase transition in CHCl3, C6H6, and CCl4. The contributions of the phonon-phonon and phonon-rotational interaction to the total thermal resistance in solid and liquid state are specified using a modified method of reduced coordinates. The decrease in the thermal conductivity at the crystal-liquid phase transition, ? ?p, is explained by a combined effect of variations in positional distribution of molecules and in the form of rotational molecular motion.
The thermal conductivity of liquid CHCl3, C6H6, and CCl4 is measured by a steady-state method under saturated vapor pressure in the temperature regions corresponding to pre-crystallization temperatures. The experimental results obtained are used to investigate the isobaric thermal conductivity jump ??p at the crystal-liquid phase transition in CHCl3, C6H6, and CCl4. The contributions of the phonon-phonon and phonon-rotational interaction to the total thermal resistance in solid and liquid state are specified using a modified method of reduced coordinates. The decrease in the thermal conductivity at the crystal-liquid phase transition, ??p, is explained by a combined effect of variations in positional distribution of molecules and in the form of rotational molecular motion.
A detergent-containing radioactive liquid waste originating from atomic power plants is concentrated to have about 10 wt. % detergent concentration, then dried in a thin film evaporator, and converted into powder. Powdered activated carbon is added to the radioactive waste in advance to prevent the liquid waste from foaming in the evaporator by the action of surface active agents contained in the detergent. The activated carbon is added in accordance with the COD concentration of the radioactive liquid waste to be treated, and usually at a concentration 2-4 times as large as the COD concentration of the liquid waste to be treated. A powdery product having a moisture content of not more than 15 wt. % is obtained from the evaporator, and pelletized and then packed into drums to be stored for a predetermined period.
A detergent-containing radioactive liquid waste originating from atomic power plants is concentrated to have about 10 wt. % detergent concentration, then dried in a thin film evaporator, and converted into powder. Powdered activated carbon is added to the radioactive waste in advance to prevent the liquid waste from foaming in the evaporator by the action of surface active agents contained in the detergent. The activated carbon is added in accordance with the COD concentration of the radioactive liquid waste to be treated, and usually at a concentration 2-4 times as large as the COD concentration of the liquid waste to be treated. A powdery product having a moisture content of not more than 15 wt. % is obtained from the evaporator, and pelletized and then packed into drums to be stored for a predetermined period.
The measurement of level in the liquid nitrogen vessel has been carried out by the weight conversion method using weigher or by putting directly a stick in the vessel. On a large CE tank, the pressure difference was read by manometer. These methods can not be used when the vessel does not put on the weigher or the pipe for manometer is stopped. We noticed the interaction between radiation ({gamma}-ray) and substance and applied it to determine the liquid nitrogen level. The results proved it the easy method for measurement of the level in the large CE tank. Cesium 137 ({gamma}-ray energy: 662 keV) was used as the radiation source. {gamma}-ray transmission dose was determined by GM survey meter. The liquid nitrogen level could be determined by using the change of the transmission dose with amount of liquid nitrogen. (S.Y.)
Object: To minimize the range of the liquid level variation of the cooling system and reduce the time required for the liquid level control by sealing the gas of a cover gas respiration system which acts upon an evaporator and pump overflow column. Structure: In liquid level control by the cover gas pressure of a high-speed reactor secondary cooling system, upon occurrence of a sudden change in the rate of flow of the recirculated liquid, automatic check valves provided in an evaporator and pump overflow column cover gas respiration system are completely or substantially closed, while at the same time the recirculation cooling medium is sucked up and an automatic check valve provided in the overflow system is closed. (Kamimura, M.).
Liquid radioactive waste treatment method of using evaporator was widely used from Kori 1 to Uljin 3 and 4, but a liquid radioactive waste treatment equipment that uses an ion exchange method instead of an evaporator was adopted aiming to minimize amount of radioactive waste and radiation exposure. However, the same equipment was introduced and applied for the first time in Korea and had experienced difficulties in securing credibility for the equipment and handling of liquid radioactive waste with inadequate data about performance and experience in operation and maintenance. In this study, examination, application and effect analysis was performed on the optimization measure for handling liquid radioactive waste of Yonggwang Nuclear Power Unit 5 and 6(YGN 5 and 6) that applies an ion exchange method
A qualitative method, involving supported liquid?liquid extraction (SLE) and ultra high pressure liquid chromatography coupled to tandem mass spectrometry (UHPLC-MS?MS), was developed for the rapid tentative identification of various drugs of abuse in urine. In this study, 28 drugs and metabolites were covered by the screening procedure. Before analysis, urine samples were extracted by SLE and good extraction recoveries were obtained for most investigated compounds. The UHPLC strategy was then selected for the rapid separation of amphetamines, cocaine, opiates and related compounds in urine. Using columns packed with sub-2??m particles, analysis time was reduced down to 2?min, while maintaining acceptable performance. Finally, the detection was by tandem MS operating in the single reaction...
The authors study, in forced convection, the evaporation of an Ostwaldian film flowing over an isothermal inclined plane surface to determine the influence of the behaviour index of the liquid on the dynamic and thermal characteristics of liquid-air system. The liquid flow is considered partially two-dimensional whereas for the air it is two-dimensional. The coupled equations with the interfacial conditions are solved using a fully implicit finite differences method. From the study, it appears that the behaviour index influences considerably the transfers which are more important for pseudo-plastic liquids than for dilatant ones. (authors)
The US Department of Energy (DOE) has millions of gallons of high level nuclear waste stored in underground tanks at Hanford, Washington and Savannah River, South Carolina. These tanks will eventually be emptied and decommissioned. This will leave a residue of sludge adhering to the interior tank surfaces that may contaminate groundwaters with radionuclides and RCRA metals. Experimentation on such sludges is both dangerous and prohibitively expensive so there is a great advantage to developing artificial sludges. The US DOE Environmental Management Science Program (EMSP) has funded a program to investigate the feasibility of developing such materials. The following text reports on the success of this program, and suggests that much of the radioisotope inventory left in a tank will not move out into the surrounding environment. Ultimately, such studies may play a significant role in developing safe and cost effective tank closure strategies.
Encapsulation of a unique isotopic blend of krypton and xenon gas employs a special application of laser technology. The encapsulated gas is then used as the primary medium for detection and identification of failed nuclear fuel rods. The use of gas tagging as a means of detecting and identifying failed nuclear fuel rods has been successfully demonstrated and used by the Argonne National Laboratory, Experimental Breeder Reactor (EBR-2) Project, and the Westinghouse Hanford Company (WHC), Fast Flux Test Facility (FFTF) Fast Breeder Reactor Program. The Power Reactor and Nuclear Fuel Development Corporation (PNC) of Japan has selected this leak detection system for use in their MONJU Prototype Reactor fuel assemblies. The MONJU reactor is almost identical in design to the highly successful FFTF reactor, which is currently in standby status.
A major new initiative to develop and irradiate a long-lived, mixed-oxide (MOX) fuel system in the Fast Flux Test Facility (FFTF) has been implemented by Westinghouse Hanford Company for the U.S. Department of Energy. The purpose of this new fuel system, called the core demonstration experiment (CDE), is to demonstrate the capability of achieving a 3-yr life in a prototypical, heterogeneous reactor environment under prototypical power and temperature conditions. Ten fuel and six blanket CDEs are establishing the performance characteristics of entire fuel assemblies of wire-wrapped, large-diameter, annular-pellet, advanced MOX fuel pins with the tempered martensitic HT-9 alloy cladding and end caps, HT-9 wire wrap, and an HT-9 duct in a heterogeneous array with the blanket assemblies. The CDE performance characteristics are confirming the basis for design, fabrication, and irradiation of the CDE.
Fuel Management at the Fast Flux Test Facility (FFTF) involves more than just the usual ex-core and in-core management of standard fuel and non-fuel components between storage locations and within the core since it is primarily an irradiation test facility. This mission involves testing an ever increasing variety of fueled and non-fueled experiments, each having unique requirements on the reactor core as well as having its own individual impact on the reload design. This paper describes the fuel management process used by the Westinghouse Hanford Company Core Engineering group that has led to the successful reload design of nine operating cycles and the irradiation of over 120 tests.
This case study is an application, to a nuclear power plant, of the methodology for quantifying environmental costs and benefits, contained in the regional energy plan, adopted in April, 1983, by the Northwest Power Planning Council, pursuant to Public Law 96-501.The study is based on plant number 2 of the Washington Public Power Supply System (WNP-2), currently nearing completion on the Hanford Nuclear Reservation in eastern Washington State. This report describes and documents efforts to quantify and estimate monetary values for the following seven areas of environmental effects: radiation/health effects, socioeconomic/infrastructure effects, consumptive use of water, psychological/health effects (fear/stress), waste management, nuclear power plant accidents, and decommissioning costs. 103 references.
Development testing has been conducted by Rockwell Hanford Operations (Rockwell) with simulated Fast Flux Test Facility (FFTF) Reactor fuel and unirradiated N-Reactor fuel, to identify the various problems associated with rotary shearing these fuels. This report discusses the results of tests segmenting FFTF and N-Reactor fuels using electrically driven slow-speed rotary shredders. From these tests, it has been determined that slow-speed rotary shredding of both fuels can be accomplished. Final equipment arrangements and operating parameters have been established for definitive design of the FFTF Rotary Shear. Development testing is continuing on the N-fuel rotary shear. However, it has been established that two-stage shearing is necessary and the outer N-fuel elements pose few problems, while the smaller inner elements have created numerous problems, which are being addressed.
High energy muon colliders, such as the TeV-scale conceptual designs now being considered, are found to produce enough high energy neutrinos to constitute a potentially serious off-site radiation hazard in the neighbourhood of the accelerator site. A general characterization of this radiation hazard is given, followed by an order-of-magnitude calculation for the off-site annual radiation dose and a discussion of accelerator design and site selection strategies to minimize the radiation hazard.
The Formerly Utilized Sites Remedial Action Program (FUSRAP) is to evaluate the radiological conditions at former MED-US AEC sites. Purpose of the Ocean FUSRAP program is to assess the feasibility of ocean disposal of FUSRAP waste which contains trace natural radioactive materials. This paper presents soil characterization information on the Middlesex, NJ, Sampling Plant site, and reports preliminary ocean dispersion calculations. (DLC)
The objectives of this project to interface the site-specific real-time radiological dose assessment system FADAS(Following Accident Dose Assessment System) to CARE. In this study, the results of the field tracer experiments conducted on the Younggwang site have been analysed. And the experimental procedure on Ulchin site has been introduced. The environmental characteristics on Ulchin and Wolsung has been investigated.
After a presentation of methods and tools for the basic and extensive characterization of polluted sites and the study of evolution and transfer of current organic pollutants in the ground, the example of the rehabilitation of an old Rhone-Poulenc site (at Chauny, France) polluted with metals and arsenic, is described: soil and aquifer diagnosis, risk analysis and determination of migration schemes
An examination of chemical and radiological characteristics of RI organic liquid waste, wet oxidation by Fenton reaction and decomposition liquid waste treatment process were studied. These items will be applied to develop the equipment of wet oxidation and decomposition liquid waste treatment mixed processes for the safe treatment of RI organic liquid waste which is consisted of organic solvents such as toluene, alcohol and acetone. Two types of toluene solutions were selected as a candidate decomposition material. As for the first type, the concentration of toluene was above 20 vol percent. As for the second type, the solubility of toluene was considered. The decomposition ration by Fenton reaction was above 95 percent for both of them. From the adsorption equilibrium tests, a -Na{sup +} substituted/acid treated activated carbon and Zeocarbon mixed adsorbent was selected for the fixed adsorption ...
The Time Projection Chamber (TPC) magnet at LBL and its compensation solenoids are adiabatically stable superconducting solenoid magnets. The cryogenic system developed for the TPC magnet is discussed. This system uses forced two-phase tubular cooling with the two cryogens in the system. The liquid helium and liquid nitrogen are delivered through the cooled load by forced tubular flow. The only reservoirs of liquid cryogen exist in the control dewar (for liquid helium) and the conditioner dewar (for liquid nitrogen). The operation o these systems during virtually all phases of system operation are described. Photographs and diagrams of various system components are shown, and cryogenic system data are presented in the following sections: (1) heat leaks into the TPC coil package and the compensation solenoids; (2) heat leaks to various components of the TPC magnet cryogenics system ...
Purpose: To permit accurate detection of sodium leakage by distinguishing between variations in the overflow tank level due to changes in sodium temperature accompanying changes in the power level or operating state of a liquid metal sodium cooled fast breeder, and a reduction in power level due to duct leakage. Constitution: The volume of sodium in the primary cooling system is roughly estimated from the temperatures of hot and cold legs, and the duct leak preset level with respect to the sodium liquid level within an overflow tank when the plant is normal is varied according to the state of the plant. More particularly, the volume of sodium within the overflow tank is calculated on the basis of a signal representing the liquid level detected by a liquid level gauge in the overflow tank and a signal representing the temperature detected by hot leg and cold leg thermometers, thereby obtaining the preset ...
In nuclear power plant Paks, Hungary, alkaline oxidative (NaOH, KMnO_4, H_2O) and acidic reductive (citric- and oxalic acid, water) liquids are using for the decontamination of primary circuit equipment (main liquid circulating pumps, steam generators, pipelines etc). The above mentioned decontamination liquids are containing "1"1"0"mAg, "9"5Nb, "5"4Mn, "5"8 Co, "6"0Co, "5"1 Cr, "1"2"4 Sb radioisotopes, summarized radioactivity is between 10"3-8x10"4 kBq/dm"3 liquid. The decontamination liquid can be cleaned with reactive adsorption (active carbon) and ion-exchange process at elevated temperature (333-368 K) in multilayered columns. After purification the summarized radioactivity for "5"4Mn, "6"0Co, and "1"1"0"mAg are in the outlet liquid below 1 kBq/dm"3. Decontamination factor DF#approx =#10"3-10"4, volumetric reduction factor VRF#approx =#50-500.
Site occupancies in three C15-structured AB{sub 2}(X) Laves phases have been determined by Atom Location by CHanneling Enhanced MIcroanalysis (ALCHEMI). In NbCr{sub 2}(V), the results were consistent with exclusive site occupancies of Nb for the A sublattice and Cr and V for the B sublattice. The B-site occupancy of V is not expected from atom size effects alone. In NbCr{sub 2}(Ti), the results were consistent with Ti partitioning mostly to the A sites with some anti-site defects likely. In HfV{sub 2}(Nb), the results were consistent with Nb partitioning between the A and B sites. The results of the ALCHEMI analyses of these ternary C15 Laves phase materials will be discussed with respect to previously determined phase diagrams and first-principles total energy and electronic structure calculations.
Data from natural runoff plots at two experimental sites in northern Iraq were used to predict soil erodibility in this semiarid region. The first site has a mean seasonal rainfall of about 400mm with the plots situated on 40% uniform slope; the soil at the site has a loam texture and belongs to the Xerorthent suborder; it has 46% of gravel by weight in its surface layer. The second site has a mean seasonal rainfall of more than 900mm with the plot situated on 17% uniform slope; the soil at the site is silty clay and belongs to the Calcixeroll suborder. At both sites, soil loss and runoff measurements were collected for two rainfall seasons. Results from both experimental sites showed that storm-to-storm variation in soil erodibility is high reflecting the importance of long term measureme...
This report provides an overview of the scope and status of the US Department of Energy (DOE`s) Salt Repository Project (SRP) at the time when the project was terminated by the Nuclear Waste Policy Amendments Act of 1987. The report reviews the 10-year program of siting a geologic repository for high-level nuclear waste in rock salt formations. Its purpose is to aid persons interested in the information developed during the course of this effort. Each area is briefly described and the major items of information are noted. This report, the three salt Environmental Assessments, and the Site Characterization Plan are the suggested starting points for any search of the literature and information developed by the program participants. Prior to termination, DOE was preparing to characterize three candidate sites for the first mined geologic repository for the permanent disposal of high-level nuclear waste. The ...
Shewanella oneidensis MR-1 is a model environmental organism that possesses diverse respiratory capacities, including the ability to reduce soluble Cr(VI) to sparingly soluble, less toxic Cr(III). Effective bioremediation of Cr-contaminated sites requires knowledge of the molecular mechanisms and regulation of heavy metal resistance and biotransformation by dissimilatory metal-reducing bacteria. Towards this goal, our ERSP-funded work is focused on the identification and functional analysis of genes/proteins comprising the response pathways for chromate detoxification and/or reduction. Previous transcriptomic profiling and whole-cell proteomic analyses implicated the involvement of a functionally undefined DNA-binding response regulator (SO2426) and a putative azoreductase (SO3585) in the chromate stress response of MR-1. Here we describe a detailed functional analysis of SO2426 and SO3585 in order to begin to understand the role of these proteins in the cellular ...
This was a university-based research project in support of distributed reforming production technologies for hydrogen. Our objective was to examine the steam reforming of bio-ethanol and other related bio-derived liquids over non-precious metal catalyst systems to enable small-scale distributed hydrogen production technologies from renewable sources. The study targeted development of a catalytic system that does not rely on precious metals and that can be active in the 350-550 C temperature range, with high selectivity and high stability. To this end, we adopted a multi-prong research strategy, that included catalyst formulation and synthesis, detailed catalyst characterization, reaction kinetics and reaction engineering, molecular modeling and economic analysis studies. Our approach was an iterative one, where the knowledge gained in one aspect of the study was utilized to modify and fine-tune catalyst development. The research addressed many fundamental and ...
Film boiling is the mode if boiling during which the hot surface is separated from the vaporizing liquid by a nearly continuous film vapor. Film boiling is usually considered a very undesirable boiling regime since it is a relatively quiet and inefficient mode of heat transfer, particularly as compared to nucleate boiling. It is customary to analyze the two-phase flow regime of laminar flow film boiling by assuming the two-phase flow regime of laminar flow film boiling by assuming an idealized vapor film flow characterized by a smooth liquid-vapor interface. However, during stable flow film boiling, the wavy nature of the liquid-vapor interface and its role in local heat and mass transport have been largely ignored. The vapor interface is rarely stationary. Interfacial waves may substantially augment the heat transfer rates throughout the layer. The present analysis treats stagnation point flow film boiling on a sphere ...
This report summarizes the major activities conducted in the Chemical and Energy Research Section of the Chemical Technology Division at Oak Ridge National Laboratory (ORNL) during the period October--December 1997. The section conducts basic and applied research and development in chemical engineering, applied chemistry, and bioprocessing, with an emphasis on energy-driven technologies and advanced chemical separations for nuclear and waste applications. The report describes the various tasks performed within six major areas of research: Hot Cell Operations, Process Chemistry and Thermodynamics, Separations and Materials Synthesis, Fluid Structure and Properties, Biotechnology Research, and Molecular Studies. The name of a technical contact is included with each task described, and readers are encouraged to contact these individuals if they need additional information. Activities conducted within the area of Hot Cell Operations included efforts to optimize the processing conditions ...
Detailed investigations of geologic, geomorphic, and seismic conditions at the Bodo Canyon disposal site were conducted. The purpose of these investigations was basic site characterization and identification of potential geologic hazards that could affect long-term site stability. Subsequent engineering studies, such as analyses of hydrologic and liquefaction hazards, used the data developed in these studies. The geomorphic analysis was employed in the design of effective erosion protection. Studies of the regional and local seismotectonic setting, which included a detailed search for possible capable faults within a 65 kilometer radius of the site, provided the basis for seismic design parameters. The scope of work performed included the following: Compilation and analysis of previous published and unpublished geologic literature and maps; Review of historical and instrumental earthquake data; Review ...
The environmental data for the NSDN are presented in the form of tables for each solar site. The solar sites are grouped into 12 zones, each of which consists of several adjacent states. The solar energy sites are in alphabetical sequence within each zone. The tables provide available meteorological data for reporting sites in the NSDN as follows: Insolation - the insolation table presents the total, diffuse, direct, maximum, and extra-terrestrial radiation for the solar site. It also shows the ratio of total extra-terrestrial radiation, as a percent. Temperature - the temperature table gives the average, daytime, nightime, maximum, minimum and inlet-water temperatures for the solar site. Additional tables are presented for some of these NSDN sites, supplying either wind or relative humidity data, or both. Wind - all of the passive and some ...
The Department of Energy`s Office of Technology Development initiated an Integrated Demonstration Program at the Savannah River Site in 1989. The objective of this program is to develop, demonstrate, and evaluate innovative technologies that can improve present-day environmental restoration methods. The Integrated Demonstration Program at SRS is entitled ``Cleanup of Organics in Soils and Groundwater at Non-Arid Sites.`` New technologies in the areas of drilling, characterization, monitoring, and remediation are being demonstrated and evaluated for their technical performance and cost effectiveness in comparison with baseline technologies. Present site characterization and monitoring methods are costly, time-consuming, overly invasive, and often imprecise. Better technologies are required to accurately describe the subsurface geophysical and geochemical features of a site and the nature and extent of ...
When liquids are confined in nano-scopic dimensions, their properties differ from the corresponding bulk liquid, due to their reduced dimensionality and surface effects. Phase transition temperatures and pressures are often shifted from the bulk values and new phases can appear due to the strong interactions of the molecules with the confining walls. We have studied the structural and dynamical properties of aromatic liquids such as benzene, toluene, and ortho-terphenyl confined in nano-porous materials, MCM-41 and SBA-15, synthesized and characterized in our laboratory. A non-trivial dependence of the glass transition temperature, Tg, on the pore size and surface treatment of nano-porous materials is confirmed and interpreted as resulting from a competition between the fluid-wall and fluid-fluid intermolecular interactions. An increase of Tg is observed for small pore sizes and attractive surface while Tg decreases for non ...
Object: To control the average liquid level of each steam generator at a constant level irrespective of the flow rate of sodium thereby to decrease change in the retained amount of sodium and at the same time to improve the load response characteristic. Construction: A method for decreasing to as large an extent as possible a change in the amount of sodium retained in a steam generator due to change in the flow rate, which comprises the steps of detecting the main recirculating flow rate of liquid sodium by the use of a sodium flow rate detector, amplifying the detected flow rate signal depending upon the ratio between the flow rates respectively in a super-heater and a re-heater (distribution ratio), delivering the amplified signal to a function generator which generates a liquid level setting signal for maintaining the respective average liquid levels of the super-heater and the re-heater at constant ...
In the region of annular liquid film-mist flow, the behavior of the droplets formed from the liquid film and the rate of formation are the subjects to be clarified in connection with the forecast of dry-out point, which becomes a problem in the region of high dryness such as reactor cooling system and steam generators. Many researches have been performed on such problem in vertical tubes, but the characteristics in horizontal flow have not yet been sufficiently clarified. This series of research is to clarify various characteristics, such as the velocity of vapor phase, the flow rate distribution of droplets, the formation and adhesion of droplets and the structure of liquid film, in the region of liquid film-mist flow, where liquid film exists on the bottom of a horizontal rectangular channel, and vapor flow is accompanied by droplets. In this study, by the measurement of the flow ...
In the region of annular liquid film-mist flow, the behavior of the droplets formed from the liquid film and the rate of formation are the subjects to be clarified in connection with the forecast of dry-out point, which becomes a problem in the region of high dryness such as reactor cooling system and steam generators. Many researches have been performed on such problem in vertical tubes, but the characteristics in horizontal flow have not yet been sufficiently clarified. This series of research is to clarify various characteristics, such as the velocity of vapor phase, the flow rate distribution of droplets, the formation and adhesion of droplets and the structure of liquid film, in the region of liquid film-mist flow, where liquid film exists on the bottom of a horizontal rectangular channel, and vapor flow is accompanied by droplets. In this study, by the measurement of the flow ...
The tremendous heat generated in a computer chip or very large scale integrated circuit raises many challenging issues to be solved. Recently, liquid metal with a low melting point was established as the most conductive coolant for efficiently cooling the computer chip. Here, by making full use of the double merits of the liquid metal, i.e. superior heat transfer performance and electromagnetically drivable ability, we demonstrate for the first time the liquid-cooling concept for the thermal management of a computer chip using waste heat to power the thermoelectric generator (TEG) and thus the flow of the liquid metal. Such a device consumes no external net energy, which warrants it a self-supporting and completely silent liquid-cooling module. Experiments on devices driven by one or two stage TEGs indicate that a dramatic temperature drop on the simulating chip has been realized ...
In culture migrating and interacting amoeboid cells can form nematic liquid crystal phases. A polar nematic liquid crystal is formed if the interaction has a polar symmetry. One type of white blood cells (granulocytes) form clusters where the cells are oriented towards the center. The core of such an orientational defect (disclination) is either a granulocyte forced to be in an isotropic state or another cell type like a monocyte. An apolar nematic liquid crystal is formed if the interaction has an apolar symmetry. Different cell types like human melanocytes (=pigment cells of the skin), human fibroblasts (=connective tissue cells), human osteoblasts (=bone cells), human adipocytes (= fat cells) etc., form an apolar nematic liquid crystal. The orientational elastic energy is derived and the orientational defects (disclination) of nematic liquid crystals are investigated. The ...
The Davis GSR Landfill (GSR) is listed by the U.S. Environmental Protection Agency on the National Priorities List. Preliminary on-site sampling results have demonstrated volatile organic compounds in ground water and surface water. The contaminants present in groundwater at this site are trichloroethylene, ethylbenzene, toluene, chloromethane, tetrahydrofuran, 1,1,1-trichloroethane, and 1,2 dichloroethane. GSR represents a potential public health concern to area residents. However, information available on this site is not currently adequate to determine if a public health concern exists to these residents. At a minimum, future investigations of this site should include a characterization of the site and site contaminants, and a characterization of the hydrogeology of the area.
Thinning and burning forests established on revegetated mine pits in jarrah (Eucalyptus marginata) forests of south-west Australia is being considered as a management option to accelerate succession in sites with excessive tree densities. To assess the impact of thinning and burning on reptiles and small mammals, we installed trapping grids in eight thinned and burned sites, each paired with untreated controls. Of the eight pairs, four were in rehabilitated sites (planted with nonlocal species) and four were in restored sites (seeded with local species). Thinning and burning had no significant impact on the small mammal community, although Cercatetus concinnus was more abundant in rehabilitated sites. In contrast, thinning and burning significantly increased reptile abundance and species r...
A nitrogen liquefier and computer controlled valving system have been added to the Bevatron cryoliner vacuum system to cut operating costs by reducing liquid nitrogen consumption. The computer and interface electronic systems, which control the temperatures of twenty-eight liquid nitrogen circuits, have been chosen and designed to operate in the Bevatron's pulsating magnetic field. The nitrogen exhaust is routed back to a liquefier, of about five kilowatt capacity, liquefied, and rerouted through the cooling circuits. A description of the system and operating results are presented.
We consider a holographic description of a system of strongly-coupled fermions in 2+1 dimensions based on a D7-brane probe in the background of D3-branes. The black hole embedding represents a Fermi-like liquid. We study the excitations of the Fermi liquid system. Above a critical density which depends on the temperature, the system becomes unstable towards an inhomogeneous modulated phase which is similar to a charge density and spin wave state. The essence of this instability can be effectively described by a Maxwell-axion theory with a background electric field. We also consider the fate of zero sound at non-zero temperature.
The US DOE is calling on the nations' industries and academic institutions to develop a new approach for converting coal into liquid fuels at costs that can be competitive with imported oil. Based on a number of innovations, the department is looking for new approaches that can substantially reduce the cost of liquids from coal, essentially capping the price of imported oil. If successful, the new process will define the next generation of coal liquefaction technology and represent a dramatic improvement over the current state-of-the-art integrated two-stage process. 1 fig.
A thermodynamic model was used to estimate enthalpy of solution of carbon dioxide (CO{sub 2}) in methyldiethanolamine (MDEA) aqueous solutions. The model was based on a set of equations for chemical equilibria, phase equilibria, charge, and mass balances. Non-ideality in the liquid phase was taken into account by interaction parameters fitted to (vapor + liquid) equilibrium data. The enthalpies of solution of CO{sub 2} were derived from the model using classical thermodynamic relations and were compared to experimental values obtained in previous works.
A thermodynamic model was used to estimate enthalpy of solution of carbon dioxide (CO_2) in methyldiethanolamine (MDEA) aqueous solutions. The model was based on a set of equations for chemical equilibria, phase equilibria, charge, and mass balances. Non-ideality in the liquid phase was taken into account by interaction parameters fitted to (vapor + liquid) equilibrium data. The enthalpies of solution of CO_2 were derived from the model using classical thermodynamic relations and were compared to experimental values obtained in previous works.
Purpose: To prevent evaporization stills against corrosion due to radioactive liquid wastes. Constitution: Microwaves are supplied from a microwave generator by way of a wave guide tube and through a microwave permeation window to the inside of an evaporatization still. A matching device is attached to the wave guide tube for transmitting the microwaves in order to match the impedance. When the microwaves are supplied to the inside of the evaporization still, radioactive liquid wastes supplied from a liquid feed port by way of a spray tower to the inside of the evaporization still is heated and evaporated by the induction heating of the microwaves. (Seki, T.).
We show that in the Landau gauge of the SU(2) Yang-Mills theory the residual global symmetry supports existence of the topological vortices which resemble disclination defects in the nematic liquid crystals and the Alice (half-quantum) vortices in the superfluid heluim 3 in the A-phase. The theory also possesses half-integer and integer charged monopoles which are analogous to the point-like defects in the nematic crystal and in the liquid helium. We argue that the deconfinement phase transition in the Yang-Mills theory in the Landau gauge is associated with the proliferation of these vortices and/or monopoles. The disorder caused by these defects is suggested to be responsible for the confinement of quarks in the low-temperature phase.
A heat storage compostion comprises sodium sulfate decahydrate as main component, a supercooling inhibitor, and a solid-liquid separation inhibitor. The composition is characterized in that hydraulic calcium sulfate and/or calcium sulfate dihydrate is contained as the solid-liquid separation inhibitor in an amount of 2-15 wt% base on the whole weight of the composition, whereby the solid-liquid separation, i.e. the sedimentation of the anhydrous sodium sulfate during the phase transition, is effectively prevented and the long-term stability is improved. The long-term stabilty of the composition can be more improved by addition of a silcia series of thickener.
Biomass can provide a substantial energy source. Liquids are preferred for use as transportation fuels because of their high energy density and handling ease and safety. Liquid fuel production from biomass can be accomplished by any of several different processes including hydrolysis and fermentation of the carbohydrates to alcohol fuels, thermal gasification and synthesis of alcohol or hydrocarbon fuels, direct extraction of biologically produced hydrocarbons such as seed oils or algae lipids, or direct thermochemical conversion of the biomass to liquids and catalytic upgrading to hydrocarbon fuels. This report discusses direct thermochemical conversion to achieve biomass liquefaction and the requirements for wastewater treatment inherent in such processing. 21 refs.
The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through February 1999.
The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through September 1999.
Hydrogenolysis reactions of a mixture of coal liquid and coal liquefaction residue were carried out using red mud - sulfur or Co-Mo/Al{sub 2}O{sub 3} catalyst. The effect of deashing treatment of coal liquefaction residue were also investigated. Notable synergistic effects such as the increase of n-hexane soluble and the decrease of dichloromethane insoluble were observed only with the hydrogenolysis of the basic fraction of coal liquid and nondeashed coal liquefaction residue using red mud-sulfur catalyst. 4 refs., 2 figs., 2 tabs.
I formulate a model in which money coexists with equity shares on a risky aggregate endowment. Agents can use equity as a means of payment, so shocks to equity prices translate into aggregate liquidity shocks that disrupt the mechanism of exchange. I characterize a family of optimal monetary policies and find that the resulting equity prices are independent of monetary considerations. I also study a perturbation of the family of optimal policies that targets a positive constant nominal interest rate and find that in this case the real equity return includes a liquidity return that depends on monetary considerations.
Solid-state acoustic sensors for monitoring conditions at a surface immersed in a liquid and for monitoring concentrations of species in a liquid and for monitoring electrical properties of a liquid are formed by placing interdigital input and output transducers on a piezoelectric substrate and propagating acoustic plate modes therebetween. The deposition or removal of material on or from, respectively, a thin film in contact with the surface, or changes in the mechanical properties of a thin film in contact with the surface, or changes in the electrical characteristics of the solution, create perturbations in the velocity and attenuation of the acoustic plate modes as a function of these properties or changes in them.
It is imperative to use a leak-proof container for counting liquid sample to prevent contamination of costly gamma detectors. A sealant that ensures no leak is reported. It is a vinyl adhesive sealant used for household purposes, marketed by Gloucester Co., Inc, Franklin, MA under the trade name of Phenoseal (translucent variety). This sealant was superior to other sealants studied because it cures quickly, peels off easily after counting, and contains no detectable radioactivity. This sealant has been thoroughly tested and successfully employed it in the routine analysis of environmental liquid samples. (author)
We examined the spectral behaviors of lasing from a asymmetrically deformed liquid jet (a ? 14 ?m) which is induced by a laterally flowing gas. Th liquid sample was methanols which contains DCM dye. When n distortion is induced, the lasing spectrum appears as two periodic peaks which are corresponding to the resonance modes of cylindrical cavity. As the distortion parameter exceeds about 4%, the lasing spectrum shifts continuously to short wavelength. When the distortion parameter reaches ? 10%, the amount of blue shift was ? 30 nm. The blue shift can be explained as the shift of optimum wavelength of threshold curves. From the absorption and fluorescence curve of liquid sample, we estimated the spoiled Q with the distortion parameter.
The National Coal Board is investigating two routes for production of oils: liquid solvent extraction and supercritical gas extraction. Both these processes are considered ready for major development to plants of the 1 t/h scale.
The SCF approximation is used in a statistical theory of melting based on equality of the chemical potentials. The results for the melting points of the inert gases are close to the observed values.
The two-fluid model representation for calculations of two-phase flow characteristics in the FBR fuel pin bundles with liquid metal cooling is presented and analysed. Two conservation equations systems of the mass, momentum and energy have been written for each phase. Components accounted the mass-, momentum- and heat transfer throughout the interface occur in the macro-field equations after the averaging procedure realisation. The pattern map and correlations for two-fluid model in vertical liquid metal flows are presented. The description of processes interphase mass- and heat exchange and interphase friction is determined by the two-phase flow regime. The opportunity of the liquid metal two-phase flow regime definition is analysed. (author)
... The addition of 0.5 pphr of fine thermal carbon black to the polymers gave good resistance to 500 hours of ultraviolet (UV) xposure in a Weather ...
Inorganic nanoparticles are indispensable for science and technology as materials, pigments and cosmetics products. Improving the dispersion stability of nanoparticles in various liquids is essential for those applications. In this review, we discuss why it is difficult to control the stability of nanoparticles in liquids. We also overview the role of surface interaction between nanoparticles in their dispersion and characterization, e.g. by colloid probe atomic force microscopy (CP-AFM). Two types of surface modification concepts, post-synthesis and in situ modification, were investigated in many previous studies. Here, we focus on post-synthesis modification using adsorption of various kinds of polymer dispersants and surfactants on the particle surface, as well as surface chemical reactions of silane coupling agents. We discuss CP-AFM as a technique to analyze the surface interaction between nanoparticles and the effect of surface ...
A comprehensive assessment on the eligibility of reduced activation (RA) steels as structural chamber material in Inertial Fusion Energy thick-liquid concepts is performed. As far as alloying elements, it is shown that the activation of tungsten is a question to discuss. Regarding impurity elements, it is analyzed if they could question the possibility of obtaining real RA steels for shallow land burial (SLB). The effect of the thickness of the liquid wall on the SLB response of alloying and impurity elements is computed. It seems that a reasonable liquid thickness of about 80 cm is allowable to obtain SLB acceptability of real RA steels. And above all, we have estimated the impact of cross section uncertainties when addressing the former questions, and we identify those to be improved. The necessary improvement of some tungsten and niobium cross sections is justified. (authors)
A simple, sensitive and rapid method for analysis of granisetron in human plasma, utilizing liquid chromatography tandem mass spectrometry (LC-MS/MS), has been developed and validated to satisfy FDA guidelines for bioanalytical methods. The analyte and internal standard (IS) were isolated from 100ml plasma samples by liquid-liquid extraction (LLE). A Varian 1200l tandem mass spectrometer equipped with an electrospray ionization source was operated in selected reaction monitoring (SRM) mode with the precursor-to-product ion transitions m/z 313.4/138 for granisetron and m/z 270/201 for the IS used for quantitation. The assay exhibited a linear dynamic range of 0.02-20ng/ml for granisetron in human plasma. The lower limit of quantification (LLOQ) was 0.02ng/ml with a relative standard deviati...
... The phenol and cresylic acid stream is flashed in a thin film evaporator over a concentrated sulfuric acid mixture to remove pyridine type substances ...
The effect of different media and pH on the formation of amylase by Aspergillus oryzae EI 212 is described. Depending upon the composition of the medium and growth...Full Text Available
Visualization of a liquid metal flow and image processing methods to measure the vector field are carried out by real-time neutron radiography. The JRR-3M real-time thermal neutron radiography facility in the Japan Atomic Energy Research Institute was used. Lead-bismuth eutectic was used as a working fluid. Particles made from a gold-cadmium intermetallic compound (AuCd{sub 3}) were used as the tracer for the visualization. The flow vector field was obtained by image processing methods. It was shown that the liquid metal flow vector field was obtainable by real-time neutron radiography when the attenuation of neutron rays due to the liquid metal was less than l/e and the particle size of the tracer was larger than one image element size digitized for the image processing. (orig.).
Visualization of a liquid metal flow and image processing methods to measure the vector field are carried out by real-time neutron radiography. The JRR-3M real-time thermal neutron radiography facility in the Japan Atomic Energy Research Institute was used. Lead-bismuth eutectic was used as a working fluid. Particles made from a gold-cadmium intermetallic compound (AuCd_3) were used as the tracer for the visualization. The flow vector field was obtained by image processing methods. It was shown that the liquid metal flow vector field was obtainable by real-time neutron radiography when the attenuation of neutron rays due to the liquid metal was less than l/e and the particle size of the tracer was larger than one image element size digitized for the image processing. (orig.).
A case of mycotic encephalitis in a horse with guttural pouch mycosis is described. A liquid pellet feed binder contaminated with Aspergillus sp. and erroneously mixed in a feed concentrate...Full Text Available
Two-phase flow in horizontal parallel channels has been experimentally investigated under fuel cell related operating conditions. Pronounced hysteresis is observed in the pressure drop versus flow characteristic curve when starting from either flooded or dry conditions. When gas is introduced into channels initially filled with water (flooded initial condition), both gas and liquid tend to flow predominantly in one channel at low gas or liquid flow velocities. As the gas flow velocity increases, even distribution of gas and liquid flow in both channels is observed, accompanied with a sudden decrease in the pressure drop. On the other hand, even gas and liquid flow distribution between both channels is found at comparatively lower gas flow velocities when starting with dry-gas flow conditions with liquid introduced into channels filled with gas (stratified flow regime). The flow ...
The nitric oxide molecule is being studied in order to understand the energetics and chemistry of initiation and detonation in liquid NO at the molecular level. An overview is presented of the work being done. (DLC)
Apparatus and method are described for the vaporization of liquid fuel oils to produce a gaseous mixture suitable for burning in a burner normally designed for operation utilizing natural gas.
We investigate Fermi liquid in the single-channel U-infinite N fold degenerate Anderson lattice with use of the expansion from the large limit of the spin-orbital degeneracy N. By collecting all diagrams up to O(N{sup -2}) of the imaginary part of the self-energy of the conduction electrons, the sum of those is shown to be given by a form proportional to {omega}{sup 2} + {pi}{sup 2}T{sup 2} up to O(N{sup -2}) in the single-channel model. On the other hand, the imaginary part of the self-energy of O(N{sup -1}) in the multichannel model has more singular frequency-/temperature-dependence, so the system is regarded as non-Fermi liquid. (author)
... The fuel proposed was a medium-thermal carbon black-liquid JP-i1 mixture. JP-iO or exo-tetrahydrodi (cyclopentadieue) is a pure hydrocarbon with ...
A novel electrogenerated chemiluminescence (ECL) sensor based on natural clay and ionic liquid was fabricated. Tris(2,2prime-bipyridine)ruthenium(II) (Ru(bpy)32+) was immobilized on natural clay surface through simple adsorption. An ECL sensor was prepared by mixing Ru(bpy)32+-incorporated clay, graphite powder and an ionic liquid (1-butyl-3-methylimidazolium hexafluorophosphate) as the binder. The electrochemical behavior and ECL of the immobilized Ru(bpy)32+ was investigated. It was observed that the ECL of immobilized Ru(bpy)32+ was activated by the ionic liquid. The proposed ECL sensor showed high sensitivity to tri-n-propylamine (TPrA) and the detection limit was found to be 20 pM. In addition, the ECL sensor displayed good stability for TPrA detection and long-term storage stability.
Searches for permanent electric-dipole moments (EDM) of atoms provide important constraints on competing extensions to the standard model of elementary particles. Recently proposed experiment with liquid $^{129}$Xe [M.V. Romalis and M.P. Ledbetter, Phys. Rev. Lett. \\textbf{87}, 067601 (2001)] may significantly improve present limits on the EDMs. To interpret experimental data in terms of CP-violating sources, one must relate measured atomic EDM to various model interactions via electronic-structure calculations. Here we study density dependence of atomic EDMs. The analysis is carried out in the framework of the cell model of the liquid coupled with relativistic atomic-structure calculations. We find that compared to an isolated atom, the EDM of an atom of liquid Xe is suppressed by about 40%.
The virucidal effect of _6_0Co gamma radiation was studied in cell culture medium and in liquid swine manure involving the most important porcine viruses that can be spread by liquid manure. The radiation doses (20 kGy and 30 kGy) were determined in preliminary experiments employing a porcine enterovirus from the serogroup 1 (Teschen group). In the main experiment, the following viruses were employed: swine vesicular disease (SVD) virus, type C foot-and-mouth disease (FMD) virus, a field strain of Aujeszky's disease (AD) virus, transmissible gastroenteritis (TGE) virus, as well as bovine viral diarrhoea (BVD) virus. The latter strain served as a model for hog cholera virus. The results of the experiments indicate that safe disinfection of the virus infected liquid swine manure by ionizing radiation requires a radiation dose of 30 kGy. (author).
BackgroundIn nuclear medicine, liquid radiopharmaceuticals for diagnostic or therapeutic purposes are administered to patients by using various types of syringes with different volumes....Full Text Available
Budding yeasts are highly suitable for aging studies, because the number of bud scars (stage) proportionally correlates with age. Its maximum stages are known ...Full Text Available
Halothane, chloroform, and carbon tetrachloride, in the vapor and liquid phases, stimulate the water receptor of the blowfly Phormia regina. There are three successive phases of response to long-lasting...Full Text Available
An efficient micropropagation protocol was established for Cryptocoryne wendtii and Cryptocoryne becketti using shoot tips explants. Multiple shoots were induced from shoot tip explants of both species cultured on agar-gelled as well as liquid MS medium supplemented with 0.5?mg/L BA and 0.2?mg/L IBA (proliferation medium). The multiple shoots of both the species formed on agar-gelled as well as liquid medium were vigorously growing with well-developed roots and leaves after 4?weeks of culture. Highest number of multiple shoots was obtained from shoot tip explants of both the species cultured in liquid proliferation medium after 4?weeks of culture. The shoot tip explants of C. wendtii and C. becketti, that were cultured in liquid proliferation medium (2?weeks) followed by culturing on agar-...
... 5.9-585/T; thermal stability; solubility in liquid nitrogen, oxygen and Freons; molar extinction coefficients in the visible range and EPR spectrum. ...
Although hydrogen is the simplest of atoms, it does not form the simplest of solids or liquids. Quantum effects in these phases are considerable (a consequence of the light proton mass) and they have a demonstrable and often puzzling influence on many physical properties, including spatial order. To date, the structure of dense hydrogen remains experimentally elusive. Recent studies of the melting curve of hydrogen indicate that at high (but experimentally accessible) pressures, compressed hydrogen will adopt a liquid state, even at low temperatures. In reaching this phase, hydrogen is also projected to pass through an insulator-to-metal transition. This raises the possibility of new state of matter: a near ground-state liquid metal, and its ordered states in the quantum domain. Ordered quantum fluids are traditionally categorized as superconductors or superfluids; these respective systems feature dissipationless electrical ...
Gaseous Nitrogen Dewar apparatus developed by Dr. Alex McPherson of the University of California, Irvine for use aboard Mir and the International Space ...
Full text: The site selection process for a near surface repository dedicated for the radioactive waste resulted from the Cernavoda NPP operation and decommissioning started early in 90's. Each site selection stage included the collection of data from specific field and laboratory works as well as the appropriate safety performance evaluation. In order to assess/confirm the performance of the natural barrier of the Saligny site, the radionuclide concentration in the disposal system compartments has been evaluated, as complementary safety indicator of repository. The siting process was made in accordance with national and international regulations and standards and using a conceptual design similar to those used at L'Aube (France), ElCabril (Spain) or Mohovce (Slovak Republic). ANDRAD, the Romanian waste management organization that has continued the siting process in the last three ...
BackgroundWe aimed to compare visual and refractive outcome following phacoemulsification and intraocular lens implant (IOL) and combined one-site phacotrabeculectomy.MethodWe...Full Text Available
Subcellular-fractionation techniques were used to characterize the endocytic pathway followed by ricin in rat liver in vivo and tentatively identify the site(s) at which the ricin interchain disulphide...Full Text Available
Our research in the general area of acid catalysis involves the characterization of solid acidity and the corresponding assessment of catalytic performance of acidic materials. Acid characterization studies are required to provide essential information about the type of acid site (i.e., Lewis versus Bronsted), the strength of the sites, and the mobility of molecules adsorbed on the acid sites. An accurate measure of acid strength is given by the heat of adsorption of a basic probe molecule on the acid site. A thermodynamic representation of the mobility of adsorbed species on these sites is given by the entropy of adsorption. Important techniques used in these acid site characterization studies include microcalorimetry, thermogravimetric measurements, temperature programmed desorption, infrared spectroscopy and solid state nuclear magnetic resonance. The ...
Paraquat poisoning in mammals results in a characteristic lung lesion manifested principally as progressive pulmonary fibrosis. Paraquat is actively concentrated into the lung but the site of uptake remains undefined. A method is described for the autoradiographic localization of paraquat in rats. Preliminary evidence for the site of uptake implicates the bronchiol. (author).
The U.S. Department of Energy (DOE) has developed comparatively detailed quality assurance requirements for the high-level radioactive waste disposal systems. Quality assurance is recognized as a key issue for confidence building and smooth implementation of the HLW program in Japan, and Japan is at an initial phase of repository development. Then the quality assurance requirements at site research and site selection, site characterization, and site suitability analysis used in the Yucca Mountain project were examined in detail and comprehensive descriptions were developed using flow charts. Additionally, the applicability to the Japan high-level radioactive waste disposal project was studied. The examination and study were performed for the following QA requirements: The requirements that have the relative importance at site research and site selection, ...
Experiments were carried out to learn methanol sorption characteristics of heat-treated coal. When Taiheiyo coal is heat-treated at 125{degree}C, performed with a first methanol adsorption at 25{degree}C, and then desorption at 25{degree}C, a site with strong interaction with methanol and a site with relatively weak interaction are generated in test samples. A small amount of methanol remains in both sites. Then, when the methanol is desorbed at as low temperature as 70{degree}C, the methanol in the site with strong interaction remains as it has existed therein, but the methanol in the site with relatively weak interaction desorbs partially, hence the adsorption amount in a second adsorption at 25{degree}C increases. However, when desorption is performed at as high temperature as 125{degree}C, the methanol in the site with strong interaction also desorbs, ...
Human chromosomal fragile sites are specific loci that are especially susceptible to DNA breakage following conditions of partial replication stress. They often are found in genes involved in tumorigenesis...Full Text Available
This report documents site remediation at ORNL, including ORNL site characterization technologies, waste management and robotics and automation of the laboratory for waste processing and analysis.
The integration sites for viral DNA in cells infected with Moloney murine leukemia virus (M-MuLV) were studied by restriction endonuclease cleavage of cellular DNA followed by electrophoresis in agarose...Full Text Available
Chromosomal common fragile sites (CFSs) are genetically unstable regions of the genome that are induced by conditions that impair DNA replication. In this report, we show that treatment with the DNA...Full Text Available
Brownfields redevelopment contributes to the revitalization of communities across the U.S. Reuse of these abandoned, contaminated sites spurs economic growth, builds community pride, protects public health, and helps maintain our nation's "greenfields," often at a relatively low ...
UK Nirex has announced four sites which it wishes to assess for the disposal of low-level and short-lived intermediate-level radioactive wastes. There is local opposition at all four of the potential sites. (U.K.).
The Protein Data Bank contains the description of more than 45,000 three-dimensional protein and nucleic-acid structures today. Started to exist as the computer-readable depository of crystallographic...Full Text Available
Photobilirubin II, a stereoisomer of bilirubin, binds to human serum albumin at a single binding site (K = 2.2 x 10(6)M-1), presumably the high-affinity bilirubin-binding site. Binding in the secondary...Full Text Available
BackgroundA relevant problem in drug design is the comparison and recognition of protein binding sites. Binding sites recognition is generally based on geometry often combined with...Full Text Available
Brine from active oil wells seeped through the soil of a forested site in north-western Pennsylvania and killed all vegetation in its path, leaving the affected area unproductive and unsightly. After the brine source was eliminated, herbaceous plants, shrubs and forest tree seedlings became established and developed rapidly. Establishment began in the first year and by Year 4 the site had developed into a healthy young forest. Results show that Allegheny hardwood forest sites damaged by brine water will rapidly revegetate once the brine water discharge is stopped if there is a seed supply and if the area is fenced to exclude deer. 3 figs., 12 refs.
Surface temperature is measured with an infrared thermometer. Measuring Surface Temperature. Nine sample points are selected with a site of uniform land ...
In accordance with the requirements of Section 113 (b) (3) of the Nuclear Waste Policy Act of 1982, as amended (NWPA), the US Department of Energy (DOE) has prepared this report on the progress of site characterization activities at Yucca Mountain, Nevada, for the period October 1, 1990, through March 31, 1991. This report is the fourth in a series of reports that are issued at intervals of approximately six months during site characterization. The report covers a number of initiatives to improve the effectiveness of the site characterization program, and covers continued efforts related to preparatory activities, Study Plans, and performance assessment.
This document outlines the major steps that must be taken by the Savannah River Site (SRS) to migrate the SRS information technology (IT) environment to the new architecture described in the Savannah River Site Computing Architecture. This document proposes an IT environment that is {open_quotes}...standards-based, data-driven, and workstation-oriented, with larger systems being utilized for the delivery of needed information to users in a client-server relationship.{close_quotes} Achieving this vision will require many substantial changes in the computing applications, systems, and supporting infrastructure at the site. This document consists of a set of roadmaps which provide explanations of the necessary changes for IT at the site and describes the milestones that must be completed to finish the migration.
Using low-temperature adsorbed dihydrogen and carbon monoxide as molecular probes, the dehydroxylation of the hydrogen forms of the zeolites Y, and ZSM-5 has been studied. The high stability of the high-silica zeolites to dealumination and their difference from faujasites has been established as being due not only to the strength of their Broensted acid sites but also to the nature of their Lewis acid sites. The chemical properties of the Lewis acid sites and their possible role in catalytic reactions are discussed.
A three dimensional sea-land breeze model has been employed for the study on the inland penetration of sea breeze around Wolsung NPP site. In this study, the sea breeze simulation was carried out under the weak northwesterly geostrophic wind (3.2 m/s, 339 .deg.) at 850 hPa in Spring. The results showed that sea breezes developed near Wolsung site penetrated into about 20 km inland under the weak northwesterly geostrophic wind in Spring. This result agreed with observation data around Wolsung site on May 1996.
A three dimensional sea-land breeze model has been employed for the study on the inland penetration of sea breeze around Wolsung NPP site. In this study, the sea breeze simulation was carried out under the weak northwesterly geostrophic wind (3.2 m/s, 339 .deg.) at 850 hPa in Spring. The results showed that sea breezes developed near Wolsung site penetrated into about 20 km inland under the weak northwesterly geostrophic wind in Spring. This result agreed with observation data around Wolsung site on May 1996.
This plan outlines the procedures and operations used at LLNL's Site 300 for the management of the hazardous waste generated. This waste consists primarily of depleted uranium (a by-product of U-235 enrichment), beryllium, small quantities of analytical chemicals, industrial type waste such as solvents, cleaning acids, photographic chemicals, etc., and explosives. This plan details the operations generating this waste, the proper handling of this material and the procedures used to treat or dispose of the hazardous waste. A considerable amount of information found in this plan was extracted from the Site 300 Safety and Operational Manual written by Site 300 Facility personnel and the Hazards Control Department.
New technological advances make it possible to perform on site gas-in-oil analysis quickly and efficiently. Gas-in-oil analysis is crucial in assessing the status of oil-filled electrical equipment. The new technique is used for extracting and measuring gases dissolved in electrical insulating oil. On-site sampling requires the use of a specially designed 100 ml capacity syringe. Extraction of the dissolved gases is made with a precise ratio of oil to air. A comparison was made between the analysis of the on-site and the laboratory techniques. Results showed that the detection limits of the on-site technique were comparable to those obtained by laboratory methods.
A complete electron paramagnetic resonance power pattern characterization of Fe"3"+ in cubic sites in presented. A one-to-one correspondence among the peaks appearing in the powder pattern and the outer fine-structure transitions (Mnot = 1/2 ) observed in the single crystal along the , , and directions is shown. It is shown that the process of mechanically grinding the single crystal to a powder (particle size approx.1--10 #mu#) does not remove the cubic symmetry sites. No axial or lower symmetry sites which may be induced by lattice distortion of the crystallites due to strain have been observed.
Aluminum electrolytic capacitors have a long history of reliable operation in unattended field sites. However, their use in the expected space applications ...
Volume four contains calculations for: Borrow areas--site evaluation; temporary facilities--material quantities; embankment quantities--excavation and cover materials; Burro Canyon site excavation quantities--rippable and unrippable materials; site restoration--earthwork quantities and seeding; and bid schedule quantities and material balance.
We apply our work on fracture- and matrix-dominated flow to develop a conceptual model of hydrological flow processes in the unsaturated zone at Yucca Mountain. The possibility of fracture-dominated flow is discussed, and various deductions are made on its impact on natural and total system performance, site characterization activities, and site suitability determination.
1. The fluorescent fatty acid probe 11-(dansylamino)undecanoic acid (DAUDA) binds with high affinity to bovine and human serum albumin (BSA and HSA) at three sites. 2. The Kd of the primary binding...Full Text Available
In rat adipocyte membranes, both beta-adrenergic agonists and beta-adrenergic antagonists competed with (--)(/sup 3/H)dihydroalprenolol for high affinity (KD 2-4 nM) and low capacity binding sites. The antagonists but not the agonists competed with (--)(/sup 3/H)dihydroalprenolol for lower affinity and higher capacity sites. The present studies were performed in order to characterize the adipocyte beta-adrenergic receptor and distinguish it from low affinity, higher capacity sites which were heat-labile and not stereoselective. When isoproterenol was used to define the nonspecific binding, saturation studies showed a single binding site with a capacity of approximately 100 fmol/mg membrane protein (corresponding to approximately 50,000 sites/adipocyte). Binding was saturated by 10 nM (--)(/sup 3/H)dihydroalprenolol. Approximate KD's of 204 nM were observed. Kinetic analysis ...
We report the existence of a sixth replication arrest site, TerF, that is located within the coding sequences of the rcsC gene, a negative regulator of capsule biosynthesis. The TerF site is oriented...Full Text Available
Human serum albumin (HSA) has two primary binding sites for drug molecules. These sites selectively bind different dansylated amino acid compounds, which—due to their intrinsic fluorescence—have...Full Text Available
This volume contains appendices D6 through D8 containing laboratory test data: from MK-F investigation, 1987, Old Rifle and New Rifle sites; on bentonite amended radon barrier material; and from MK-F investigation, 1987, riprap tests.
Papers presented at a meeting on indoor and outdoor climates on sites polluted with volatile organic chemicals. The papers deal with the subject of evaporation of organic chemicals on the polluted sites in relation to the influence on indoor and outdoor climates. Themes dealt with are diffusion through soils and transport of pollutants from the soil into buildings. (AB).
The Department of Energy's National Solar Data Program established solar energy systems in residential and commercial buildings across the United States. These solar sites are linked to Vitro Laboratories Division's computer in the National Solar Data Network (NSDN). Vitro collects and analyzes data from this network to determine the thermal performance of each of the solar systems. The network consists of: (1) sensors which measure key performance parameters at a selected site; (2) a Site Data Acquisition Subsystem (SDAS); (3) telephone transmission circuits; and (4) a Central Data Processing System (CDPS). For the majority of parameters, raw data is collected approximately every five minutes. Solar insolation and certain other parameters, which are subject to rapid variance, are sampled every 32 seconds. Environmental information collected at the sites for the reporting month are ...
Nomographs have been developed to simplify site performance estimates for various types of gas turbine engines used for industrial applications. The nomographs can provide valuable data for engineers to use for an initial appraisal of projects where gas turbines are to be considered. General guidelines for the selection of gas turbines are also discussed. In particular, site conditions that influence the performance of gas turbines are described.
EPA's Brownfields Economic Redevelopment Initiative was established to assist states, site planners and other community stakeholders to work together to assess, cleanup and sustainably reuse brownfields sites. EPA has developed a series of guides to help these parties effectively...
This report has been prepared in conjunction with an environmental baseline study for a commercial coal conversion facility being conducted by Ashland Synthetic Fuels, Inc. (ASFI) and Airco Energy Company (AECO). This report represents a cultural resource assessment for the proposed plant site and two potential solid waste disposal areas. This assessment presents data collected by Dames and Moore during a recent archaeological reconnaissance of the unsurveyed southeastern portion of the proposed plant site and two potential solid waste disposal areas. Also, results of two previous surveys on the northern and southwestern portion of the plant site for American Smelting and Refining Company (ASARCO) and Kentucky Utilities are included. The Dames and Moore survey of the southeastern portion of the plant site identified one archaeological site, three standing structures and one historic ...
This report consists of a broad overview of activities at Los Alamos National Laboratory (LANL). The following topics are discussed: The growth of the waste management group; what we do today; the mission of the waste management group; the liquid waste treatment section; the radioactive liquid waste project office; the chemical waste section; the radioactive waste section; and the technical support section.
The Gibbs energy of mixing in liquid phase and the Gibbs energy of formation of various compounds in a binary Pu-Cd system were re-optimized by applying both recent and earlier experimental data. Those of the binary Pu-Bi and U-Bi systems were newly optimized. The results were summarized in a database and applied to the preliminary prediction of multi-solute systems in liquid Cd or Bi solvent. (author)
The pyrometallurgic method consisting in introduction of refining agent into the liquid cadmium has been presented. The refining agent consisting of silicon nitride, carbon dust and sodium hydroxide has been added in several portion into the liquid cadmium. Iron has been removed from the cadmium surface in the form of floating slag.
This articles deals with an approach that has given some key information about the mechanisms of the liquid phase oxidation of butane to acetic acid. This procedure has been developed over the last 34 years; however, much of what will be discussed represents a synthesis of previous insights. Many of the observations are relatively recent and have not been previously published. In principle, this approach should be applicable to many oxidation processes. (orig.)
Gas contaminated with at least one noxious component, such as SO/sub 2/, HF or NOx, is scrubbed with a clear, calcium-containing, initially-basic washing liquid which also comprises the anion of a strong inorganic acid, that of a polybasic carboxylic acid and, optionally, that of a monobasic carboxylic acid. Apparatus is provided for scrubbing the gas, oxidizing produced calcium bisulfite to calcium sulfate, separating out and removing solids, and recirculating clarified liquid for scrubbing contaminated gas.
For rapid and low-cost detection of multidrug-resistant (MDR) Mycobacterium tuberculosis, we applied the nitrate reductase assay (NRA) using a liquid medium directly to sputum samples....Full Text Available
A borohydride, for instance sodium borohydride, is added to the radioactive effluent, with eventually a carrier such as Cu{sup +}, to give a precipitate containing ruthenium. The processing can be combined to Sr and Cs precipitation be know processes giving barium sulfate and nickel ferrocyamide precipitates. Influence of borohydride concentration on decontamination factor is given.
Radial distribution functions of liquid sodium and caesium at 100"0C have been calculated by the method of molecular dynamics with interionic pair potentials derived from Heine-Abarenkov-Shaw type model potential. The results were found to be in good agreement with recent experimental data. (Auth.).
Research and development activities are reported on absorption spectroscopy, calorimetry, electrolysis, emission spectroscopy, fluorimetry gas chromatography, infrared spectroscopy, liquid chromatography, liquid scintillation counting, mass spectroscopy, microscopy, radiometric analysis, and thermal analysis. A group of miscellaneous projects are also described.
To the crushed ore leaching is applied. The resulting solid-liquid mixture is fed to a hydro-cyclon grading facility; here the superfine grain is separated before the concentrated mixture can be filtered or centrifuged. The grading is done in several steps. From the liquid, ultimately ridded of the solid, uranium compounds are precipitated and the yellow cake is obtained. (DG).
For the first time a segmented n-type HPGe detector was operated directly submerged in liquid nitrogen over a long period. As this kind of detector is envisioned to be used in GERDA phase II, it was operated with a low mass signal cable with snap-contacts and mounted in a low-mass copper holder. The detector performance was stable over 146 days, indicating that neither detector nor contacts deteriorated.
Reported on here are studies of various methods for liquefying coal. Hydropyrolysis as an alternative method for producing liquid hydrocarbons and a carbon enriched char is discussed. Other methods described involve supercritical gas extraction of coal and use of natural gas as a hydrogenating agent. Relevant waste water treatments are discussed as well. 65 refs., 9 figs.
The liquid-metal-cooled fast breeder reactor presented includes a fuel assembly made up of several long sub-assemblies rising side by side. Each of the sub-assemblies of an external area of the fuel assembly comprises an electromagnetic braking system for regulating the flow of coolant in the sub-assembly, the magnetic fields of the braking systems being temperature sensitive.
We describe a liquid hydrogen droplet as an optical cavity via whispering gallery modes. We show that the droplet leads to an ultrahigh-cavity-Q value of 2.5x10{sup 9} in visible region. We show also that the high-Q droplet results in a huge Raman nonlinearity, generating a stimulated Raman comb series covering whole visible region.
The droplet concentration profile in a liquid film-mist two-phase flow in a developing flow region of a horizontal rectangular channel was analyzed theoretically and experimentally. The effects of the mean settling velocity of droplets v sub(f) and the turbulent diffusion coefficient epsilon sub(p) on the droplet concentration profile were investigated by the theoretical analysis. The calculated results of the droplet concentration profile using the proper values of v sub(f) and epsilon sub(p) agreed with the experimental results.
The droplet concentration profile in a liquid film-mist two-phase flow in a developing flow region of a horizontal rectangular channel was analyzed theoretically and experimentally. The effects of the mean settling velocity of droplets v sub(f) and the turbulent diffusion coefficient epsilon sub(p) on the droplet concentration profile were investigated by the theoretical analysis. The calculated results of the droplet concentration profile using the proper values of v sub(f) and epsilon sub(p) agreed with the experimental results. (author).
Means for increasing heat transfer characteristics between the surface of a solid and a boiling liquid are described in which the solid is immersed is comprised of a solid with passages which extend therethrough to the surface for the circulation of liquid through the passages for emergence from the surface to eliminate at least a portion of the unstable vapor film otherwise formed on the surface.
It is desirable to avoid vibration problems by following appropriate guidelines and specifications at the design stage. Accordingly, design specifications were developed to prevent tube failures due to vibration in nuclear steam generators and liquid heat exchangers. These specifications are outlined in this report. (author). 14 refs., 2 figs.
Zanker has recently presented nomographs for determining particle settling velocities in solid-liquid systems. These nomographs were based on the general correlations developed by Barnea and Mizrahi and Barnea and Mednick. This work presents an equation directly computing particle settling velocities, eliminating the uncertainty associated with nomographs.
The interaction between gravity convection and Marangoni convection in a horizontal rectangular channel filled with a liquid containing a surfactant and a drop of another liquid is numerically investigated. For large Schmidt numbers the occurring oscillatory regime of solutal convection is analyzed. In the model with a surface phase the effect of the adsorption and desorption processes on the convective flow structure is determined. The corresponding initial and boundary value problem is solved using a difference method.
ERDA's coal liquefaction program is reviewed, especially the progress with several pilot plant operations. Other items involve the possible recovery of organic chemicals from coal liquids, the filtration of coal liquids, some experiments on hydrogenation and carbonization, and renovation of the Cresap materials and equipment test facility. (LTN)
Explosives have been used in the removal of offshore wellhead devices for a number of years. In 1975, the first liquid explosives were run to remove wellheads and have proved to be a safe and reliable method of severing and salvaging the wellhead equipment from most depths of water. Methods of explosive wellhead removal and the areas of safety, reliability, and economics are discussed.
Large scale flows of liquids can be controlled by using power fluidic devices that harness the hydrodynamic properties of liquids rather than use moving parts. Included among the fluidic devices considered are fluidic pumps, reverse flow diverters, fluidic diodes and vortex amplifiers. These devices are of potential use in the nuclear industry, particularly in reprocessing. (U.K.).
The apex dimensions and length are calculated as a function of current for the ion-emitting jet in liquid-metal ion sources (LMIS). The results agree well with observations. Since the final expressions are analytical, they give more insight into the fundamental mechanisms involved than do numerical calculations. Some implications of the model are discussed concerning focused ion beam (FIB) systems employing LMIS. (author).