Science.gov (United States)

Natural bone consists of hard nanostructured hydroxyapatite (HA) in a nanostructured protein-based soft hydrogel template (ie, mostly collagen). For this reason, nanostructured HA has been an intriguing coating material on traditionally used titanium for improving orthopedic applications. In addition, helical rosette nanotubes (HRNs), newly developed materials which form through the self-assembly process of DNA base pair building blocks in body solutions, are soft nanotubes with a helical architecture that mimics natural collagen. Thus, the objective of this in vitro study was for the first time to combine the promising attributes of HRNs and nanocrystalline HA on titanium and assess osteoblast (bone-forming cell) functions. Different sizes of nanocrystalline HA were synthesized in this study through a wet chemical precipitation process ...

International Nuclear Information System (INIS)

The structure and properties of composite powder coatings on the base of titanium carbide are studied. It is shown the electron-beam welding deposition of powders on the base of nickel and titanium carbide allows to produce of high-quality wear-resistant coatings which superior in density and hardness compared with sputtered ones. Changes of hardening phase volume percentage as well as composition of metal matrix make possible to control coatings hardness

KoreaScience (Korea)

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Energy Technology Data Exchange (ETDEWEB)

TiB{sub 2} appears to be a promising material for the wear protection in various tribological systems, e.g. the diecasting of Al. This study focuses on the development of titanium boride coatings deposited by PACVD, a deposition method which is most suitable for the coating of substrates with complex shapes. All layers analysed are very smooth and exhibit a quasi-amorphous fracture surface. XRD and TEM analysis indicate a nanocrystalline structure with grain sizes in the order of 2 nm. The diffraction patterns can well be correlated to titanium diboride. WDS reveals an over stoichiometric B/Ti ratio. The layer hardness reaches the value of 33 GPa and the critical load in scratch tests rises to 35 N. Neither 100Cr6 nor Al as a counterpart in pin-on-disk tests leads to wear of the coating. (orig.)

Energy Technology Data Exchange (ETDEWEB)

17-4PH stainless steel was modified by direct current (DC) plasma nitriding and titanium nitride film duplex treatment in this study. The microstructure, wear resistance and corrosion resistance were characterized by X-ray diffraction (XRD), pin-on-disk tribological test and polarization experiment. The results revealed that the DC plasma nitriding pretreatment was in favor of improving properties of titanium nitride film. The corrosion resistance and wear resistance of duplex treatment specimen was more superior to that of only coated titanium nitride film.

Energy Technology Data Exchange (ETDEWEB)

The method of production of xAl{sub 2}O{sub 3}-yTiO{sub 2} compositions provides for the depth distribution of coating components and specifies its mechanical properties. In case of the composition obtained by cladding, titanium is mainly concentrated at the substrate. In case of mechanical mixture or composition obtained by sintering the oxides, the depth distribution of coating components is random.

International Nuclear Information System (INIS)

Slurry aluminizing is one method of protecting titanium alloys and intermetallics at temperatures at which oxidation would otherwise significantly degrade mechanical properties. The technique produces a continuous layer of alumina-forming TiAl_3 on exposed surfaces. The influence of composition, film thickness, and diffusion temperature upon the oxidation resistance of these slurry aluminides was studied in cyclic tests to 816degC (1500deg F). Degradation of slurry aluminized #beta#-titanium alloy and #alpha#-Z titanium aluminide intermetallic occurs by localized oxidation at cracks in the coating layer. These cracks are probably due to mismatch of coefficients of thermal expansion between the coatings and substrates. Addition of silicon to the slurry modifies the oxidation behaviour around a crack by introducing a continuous layer of titanium silicide at the ...

International Nuclear Information System (INIS)

The present invention provides a fuel cladding tube having an excellent corrosion resistance and thus a long life, and a suitable manufacturing method therefor. Namely, in the fuel cladding tube, the outer circumference of an inner layer made of a zirconium base alloy is coated with an outer layer made of a metal more corrosion resistant than the zirconium base alloy. Ti or a titanium alloy is suitable for the corrosion resistant metal. In addition, the outer layer can be coated by a method such as vapor deposition or plating, not limited to joining of the inner layer material and the outer layer material. Specifically, a composite material having an inner layer made of a zirconium alloy coated by the outer material made of a titanium alloy is applied with hot fabrication at a temperature within a range of from 500 to 850degC and at a fabrication rate of not less than 5%. The ...

Energy Technology Data Exchange (ETDEWEB)

In the early 1970s Yang and Menichelli demonstrated that direct laser illumination of low-density secondary explosive prr:ssings through a transparent window could produce detonation. 'The energy requirement for threshold initiation of detonation was reduced when a thin metal coating of metal covered the side of the window against which the low-density explosive was pressed. We have obtained experimental results that are in general agreement with the results of Renllund, Stanton and Trott (1 989) and recent: work by Nagayama, hou and Nakahara (2001). We report exploration of the effects of laser beam diameter, PEiTN density and specific surface area, and thickness of a titanium coating on the window.

International Nuclear Information System (INIS)

The combination of zero-valent iron (Fe0) and iron oxide-coated sand (IOCS) was used to remove Cr(VI) and As(V) from groundwater in this study. The efficiency and the removal mechanism of Cr(VI) and As(V) by using this combination, with the influence of humic acid (HA), were investigated using batch experiments. Results showed that, compared to using Fe0 or IOCS alone, the Fe0-IOCS can perform better on the removal of both Cr(VI) and As(V). Metal extraction studies showed that As(V) was mainly removed by IOCS and iron corrosion products while Cr(VI) was mainly removed by Fe0 and its corrosion products. Competition was found between Cr(VI) and As(V) for the adsorption sites on the iron corrosion products. HA had shown insignificant effects on Cr(VI) removal but some effects on As(V) removal kinetics. As(V) was adsorbed on IOCS at the earlier stage, but adsorbed/coprecipitated with the iron corrosion products at the later ...

Energy Technology Data Exchange (ETDEWEB)

A combined PVD/PECVD process for the vacuum deposition of titanium containing amorphous hydrogenated carbon films is described. Elemental compositions of the deposited films have been determined by in situ core level photoelectron spectroscopy (XPS). The long-term stability of the plasma process has been demonstrated. Target poisoning has not been observed. We have fabricated optical selective surfaces by the deposition of a-C:H/Ti multilayers onto aluminum substrates. Even though we have not optimized layer thicknesses and stoichiometries so far, the experimental results are promising: solar absorptance {alpha}{sub S} of 0.876 and thermal emittance {epsilon}{sub 100C} of 0.061 have been achieved yielding an optical selectivity sis defined as{alpha}{sub S}/{epsilon}{sub 100C} of 14.4. Accelerated aging tests of these coatings have demonstrated their aging stability: the service lifetime is predicted to amount to more than 25 years. Raman ...

Energy Technology Data Exchange (ETDEWEB)

Copper alloys are a suitable tubing material for turbine condensers and heat exchangers. Due to problems with corrosions copper alloys increasingly are displaced by high-grade steel and titanium. Blockages and surface formation in the pipes, disturbance of the oxide coating formation, erosion and quality faults with the production are the causes for the corrosion. In the contribution under consideration counter measures are designated for the solution of the problems with corrosions. The application limits for different copper alloys are designated. Recommendations for the optimized operation are given.

British Library Electronic Table of Contents (United Kingdom)

Chitosan (Ch) microspheres have been developed by precipitation method, cross-linked with glutaraldehyde and used as a template for layer-by-layer (LBL) deposition of two natural polyelectrolytes. Using a LBL methodology, Ch microspheres were alternately coated with hyaluronic acid (HA) and Ch under mild conditions. The roughness of the Ch-based crosslinked microspheres was characterized by atomic force microscopy (AFM). Morphological characterization was performed by environmental scanning electron microscopy (ESEM), scanning electron microscopy (SEM) and stereolight microscopy. The swelling behaviour of the microspheres demonstrated that the ones with more bilayers presented the highest water uptake and the uncoated cross-linked Ch microspheres showed the lowest uptake capability. Micros...

Energy Technology Data Exchange (ETDEWEB)

The surface of low alloy steel (En40B) has been engineered in the plasma of a glow discharge via plasma nitriding and ion plating of titanium nitride (TiN) coatings on the nitrided substrates with the purpose of enhancing the surface properties and fatigue strength. The nitriding response of the steel has been accessed by the evaluation of phase composition, layer thickness, hardness profile, residual stresses and nitrogen and carbon distributions. The wear and fatigue characteristics of the plasma-nitrided steel have been investigated and simple models have been developed to describe the influence of such properties as depth and strength of the nitrided case on the fatigue limit and load-bearing capacity of the nitrided steel. In order to further improve the tribological properties and load-bearing capacity of the low alloy steel, a duplex plasma surface-engineering technique has been developed. This is achieved by plasma nitriding the steel ...

Energy Technology Data Exchange (ETDEWEB)

The aim of this work is to combine the MCFC cathode Li{sub x}Ni{sub 1-x}O properties to those of the protective coatings of LiCoO{sub 2}, Li{sub 2}TiO{sub 3} or of CeO{sub 2}, less soluble in the molten carbonates. In the cases of LiCoO{sub 2}, have been carried out by controlled potential coulometry in aqueous solution, a deposition of Co{sub 3}O{sub 4} on dense Ni. The cobalt oxide reacts rapidly in the Li{sub 2}CO{sub 3}-Na{sub 2}CO{sub 3} medium at 650 C to give LiCoO{sub 2}, a spinel cubic phase revealed by Raman spectroscopy. (O.M.)

UK PubMed Central (United Kingdom)

BackgroundTitanium and titanium alloys are widely used for fabrication of dental implants. Since the material composition and the surface topography of a biomaterial play a fundamental...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

Science.gov (United States)

PMID:17346598

J-STORE (Japan)

Full Text Available

International Science & Technology Center (ISTC)

Multi-functional Bioactive Nano-structured Coatings for Load-Bearing Implants

International Science & Technology Center (ISTC)

Characterization and Testing of Coated Nickel- and Iron-Based Superalloys for Application in High-Temperature Power Installations

Energy Technology Data Exchange (ETDEWEB)

This paper summarizes an investigation carried out on Polish terrain occupied by Russian Federation military troops. The investigation identified natural environmental devastation, pollution, and contamination. Quantitative estimation of the devastation and its economic evaluation are provided. The results of the investigation are as follows: 406 ha have been contaminated by petrochemical products; 22.7 ha are chemically polluted; and 6,500 ha of underground water, as well as 17.5 ha of surface water, cannot be classified. On 15,300 ha the soil has been degraded, of which landfills comprise an area of 98 ha. No toxic warfare agents have been detected, nor any radioactivity levels exceeding those characteristic of the given region.

British Library Electronic Table of Contents (United Kingdom)

Ferroelectric barium strontium titanate (Ba0.7Sr0.3TiO3)(BST) thin films have been prepared from barium 2-ethylhexanoate [Ba[CH3(CH2)3CH(C2H5)CO2]2], strontium 2-ethylhexanoate [Sr[CH3(CH2)3CH(C2H5)CO2]2] and titanium(IV) isopropoxide [TiOCH(CH3)2]4 precursors using a modified sol-gel technique. The precursor except [TiOCH(CH3)2]4 were synthesized in the laboratory. Transparent and crack-free films were fabricated on pre-cleaned quartz substrates by spin coating. The structural and optical properties of films annealed at different temperatures have been investigated. The as-fired films were found to be amorphous that crystallized to the tetragonal phase after annealing at 550degreeC for 1h in air. The lattice constants "a" and "c" were found to be 3.974A and 3.990A, respectively. The grain...

UK PubMed Central (United Kingdom)

Purpose:Methicillin-resistant Staphylococcus aureus (MRSA) strains are commonly classified as hospital-acquired (HA) or community-acquired (CA). Typical HA-MRSA...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

In this paper coating developments for advanced gas turbine engines (diffusion aluminide coatings, overlay coatings, and ceramic thermal barrier coatings) were desorbed, a selection of current metallic coatings was made and their performance as outlined. Finally coating developments for advanced diesel engines with a view to improved turbocharging or to low heat rejection engines (adiabatic diesel concept) were dealt with. (IHOE).

Energy Technology Data Exchange (ETDEWEB)

This paper reported on a study in which a life cycle assessment (LCA) of cotton production in Australia was conducted to evaluate energy use and greenhouse gas (GHG) emissions from tillage to export shipping. The study showed that on-farm indirect cotton-farming is the most energy consuming component, consuming nearly 32.36 GJ/ha of energy. On-farm indirect cotton-farming is the most GHG emitting component, emitting about 1.64 tonne of carbon dioxide (CO{sub 2})/ha. Energy use and the emissions by off-farm direct cotton-farming were calculated as 5.09 GJ/ha and 0.14 tonne CO{sub 2}/ha respectively. Energy consumed by off-farm indirect farming was found to be 0.036 GJ/ha or 0.002 tonne CO{sub 2}/ha. The total energy usage and greenhouse gas emissions in the Australian cotton farming system were estimated to be 46.43 GJ/ha and 2.42 tonnes ...

Energy Technology Data Exchange (ETDEWEB)

The possibility of rapid heat treatment (RHT) application to titanium castings has been studied. It was shown that such treatment provides a significant improvement of intragrain structure and mechanical properties of cast ({alpha}+{beta})-titanium alloys. ((orig.))

Science.gov (United States)

... Accession Number : ADD815206. Title : Waterjet Cutting System Adds Value to Titanium Parts. Descriptive Note : Journal article. Corporate Author : ...

British Library Electronic Table of Contents (United Kingdom)

Statement of problem The use of titanium has increased for metal ceramic restorations, as well as for use in titanium implants, with developments in CAD/CAM technology. Some surface treatments of titanium have been introduced to enhance the titanium bond strength to low-fusing porcelains; however, a more reliable, easily used dental laboratory method has not been established. Purpose The purpose of this study was to compare the effect of laser etching as a titanium surface treatment with 3 other surface treatments (machining, airborne-particle abrasion, and acid etching), evaluating their ability to enhance the bond strength between a titanium substrate and porcelain. Material and methods A total of 64 specimen rods of commercially pure titanium (ASTM grade 2, 20 mm in length and 5.7 mm in...

Science.gov (United States)

Hilled Bend Spechene of an Alpha-Beta Titanium Alloy. Ti-6M14V. ..... The all beta titanium alloy was nllled from both sides; only the edges were taped. ...

Science.gov (United States)

... Accession Number : ADD135818. Title : Performance of Titanium in Flue Gas Desulfurization Scrubber Systems,. Descriptive Note : Journal Article,. ...

Science.gov (United States)

... CLOSURE DURING HOT WORKING OF AN ALPHA/BETA TITANIUM ALLOY (PREPRINT) ... HOT WORKING OF AN ALPHA/BETA TITANIUM ALLOY ...

Science.gov (United States)

... Accession Number : ADD144314. Title : Beta-21S: A High Temperature Metastable Beta Titanium Alloy. Descriptive Note : Conference Proceedings, ...

Wastenet

as well as their use in optimizing the coating process .It will be shown how the differences

Science.gov (United States)

... Descriptors : *PROTECTIVE COATINGS, *WATER REPELLENTS, *COMBUSTIBLE CARTRIDGE CASES, COMPUTER PROGRAMS, SOLVENTS ...

Science.gov (United States)

... Descriptors : *Combustible cartridge cases, *Water repellents, *Protective coatings, *Patents, Silica gel, Aluminum compounds, Binders ...

Energy Technology Data Exchange (ETDEWEB)

In vitro cytocompatibility and cellular interactions of lauric acid and dextran-coated magnetite nanoparticles were evaluated with two different cell lines (mouse fibroblast and human cervical carcinoma). Lauric acid-coated magnetite nanoparticles were less cytocompatible than dextran-coated magnetite nanoparticles and cellular uptake of lauric acid-coated magnetic nanoparticles was more than that of dextran-coated magnetite nanoparticles. Lesser cytocompatibility and higher uptake of lauric acid-coated magnetite nanoparticles as compared to dextran-coated magnetic nanoparticles may be due to different cellular interactions by coating material. Thus, coating plays an important role in modulation of biocompatibility and cellular interaction of magnetic nanoparticles.

International Nuclear Information System (INIS)

(Nov 1973). United States Greenfield, MA Pierce, CM Chicago, IL.

Science.gov (United States)

An economical way to reduce the deleterious effects of titanium, one of the impurities present in metallurgical grade silicon material, is disclosed. By adding copper to approximately the same concentration level of the titanium during the melting process, the conversion efficiency will be restored to about 99.3% of what it would have been if the single crystal silicon had been grown free of titanium impurities.

International Nuclear Information System (INIS)

Cyclic strength of #alpha#+#beta#-titanium alloy BT3-1 is studied under load frequencies of 33 and 300 Hz. The increase in the cyclic strength with growing frequency is caused by formation of FCC interphase layers of titanium hydrides. Their formation is one of possible ways of raising the fatigue strength of titanium alloys. Peculiarities of FCC interlayer formation in #alpha#+#beta# phases under loading frequency variation are revealed.

Science.gov (United States)

... THE STRENGTH, TOUGHNESS, AND STRESS-CORROSION CRACKING SUSCEPTIBILITY OF A METASTABLE BETA TITANIUM ALLOY (Ti-11. ...

Energy Technology Data Exchange (ETDEWEB)

Results are reported which were obtained when investigating the anodic behavior of titanium in sodium iodide solutions. It was concluded that in order to explain the special features in the anodic behavior and anionic anodic activity of titanium one must take into account, both a redistribution of the potential drop between the oxide and the Helmholtz layer and a potential-dependent variation of the catalytic and adsorption properties of the oxidized titanium anode.

Energy Technology Data Exchange (ETDEWEB)

Despite their high medical relevance, the principles of lubrication in natural joints are still unclear. It is generally accepted, that the presence of hyaluronic acid (HA), the main component of the synovial liquid, plays an important role for the low friction observed. Furthermore, it is assumed that surface active lipids participate in the lubrication. Using a model system of lipid bilayers deposited on a polyelectrolyte (PE) cushion and in contact with HA solution, we started to investigate the effects of pressure and shear forces, as experienced by natural joints, on the internal structure of the SiO{sub 2}/PE/lipid/HA interface and the bulk HA solution by neutron reflectometry (NR), complemented by in situ ellipsometry and quartz crystal microbalance (QCM-D) measurements. Only on positively charged polyelectrolyte surfaces, the successful build-up of the model system could be demonstrated. By NR, ...

Energy Technology Data Exchange (ETDEWEB)

Periureteral or subtrigonal injection of dextranomer/hyaluronic acid (Dx/HA) copolymer (Deflux, Q-Med, Uppsala, Sweden) is an increasingly common endoscopic treatment for vesicoureteral reflux. We report a confusing radiographic finding of bilateral calcified Dx/HA injections initially thought to represent bilateral distal ureteral stones in a boy who presented with intermittent periumbilical pain. Urologists, radiologists, and emergency room physicians should be aware of the potential for calcification of ureteral implants of Dx/HA, and of the potentially confusing radiographic images that may result. (orig.)

Energy Technology Data Exchange (ETDEWEB)

Individual canine synovial villi were used to establish short-term synovial organ cultures. These villi incorporated /sup 3/H-glucosamine into highly-polymerized /sup 3/H-hyaluronic acid (/sup 3/H-HA), which was the only /sup 3/H-glycosaminoglycan identified in the culture medium. Some /sup 3/H-HA, and larger amounts of other /sup 3/H-glycosaminoglycans, were recovered from cultured tissues. Culture medium /sup 3/H-HA content was proportional to the surface area of cultured villi. Organ cultures of nonvillous synovium were compared with villi; nonvillous cultures synthesized less /sup 3/H-HA per mm2 of their synovial intimal surface than villi. These cultures complement cell culture techniques for in vitro studies of synovial lining cell function.

Energy Technology Data Exchange (ETDEWEB)

Short rotation trials using cuttings poplar (Populus x rasumowskyana) in Southern Finland investigated the establishment of poplar plantations and the effects of spacing and application of nitrogen fertilizer on biomass production over a period of 6 years. Thicker cuttings grew better whilst those of less than 1 cm diameter grew only moderately. Nitrogen fertilization improved height and diameter growth and above-ground dry mass yield. Woody biomass production was 4.2 dry tons/ha per year, at 300 kg/ha nitrogen. A spacing of 15 000 stems/ha gave the best yield after 4 years, but 5000 stems/ha was more productive spacing in the next 2 years. (author).

Science.gov (United States)

MilStar,. Globalstar,. Others. DVB. Satellite. Internet. Home Agent. Foreign Agent. Foreign Agent . Reparenting the HA. Primary. Home Agent. Secondary ...

International Nuclear Information System (INIS)

Technology of plasma sputtering, structure and properties of zirconium dioxide coatings were studied. Necessity of void number increase to enhance coating heat-resistance is shown. Optimal powder particle size (20-60 #mu#m) providing optimal coating porosity was determined. Weight part of stabilizating oxide (Y_2O_3) in ZrO_2 for formation in coating of microcracks serving as barriers for macro-cracks propagation was determined.

British Library Electronic Table of Contents (United Kingdom)

Statement of problem Computer-aided design/computer-aided manufacturing (CAD/CAM) titanium ceramic restorations were developed with the potential for replacing expensive, high noble metal ceramic restorations. However, there is a lack of information about the clinical performance of CAD/CAM titanium ceramic single crowns. Purpose The purpose of this study was to evaluate CAD/CAM titanium ceramic single crowns after 3 years in function. Material and methods A total of 41 crowns were fabricated for 21 patients. The titanium copings were CAD/CAM milled (Everest CAD/CAM system) with an even thickness of 0.5 mm, and low-fusing veneering porcelain (Vita Titanium Porcelain) was added incrementally. The crowns were cemented using zinc phosphate cement after confirming that there were no mechanical...

Science.gov (United States)

An investigation was conducted to determine the cause of coating residue found in the test gun chambers during qualification firing of 120-mm combustible cartridge case (CCC) ammunition for the MlAl/A2 main battle tank. The CCC is coated with a clear epox...

British Library Electronic Table of Contents (United Kingdom)

The purpose of this study is to investigate the influence of tungsten carbide/carbon (WC/C) coating on the surface durability of casehardened steel gear. Two kinds of WC/C coatings were deposited on the ground gear pair made of chromium molybdenum steel with carburizing and quenching. One is the conventional WC/C coating, and the other is WC/C coating with about 1 ?m CrN interlayer. Here, the WC/C-coated test pinion and the WC/C-coated one with CrN interlayer are represented by WT and ST, respectively. Non-coated test pinion is represented by NT. The surface roughness along the tooth profile direction of WT and ST was almost the same as that of NT. A spur gear test was carried out with an IAE power circulating type gear test rig under EP gear oil lubricating condition. The fatal failure mo...

Science.gov (United States)

... Accession Number : ADA544419. Title : Omental Lipid-Coated Mesh. Descriptive Note : Final rept. 1 Jul 2009-16 Jun 2011. ...

Wastenet

Hexavalent chromium in corrosion preventive coating 64 ...To prevent corrosion of rims, weights can be provided with a coating. ...integrated clips brought up technical problems due to corrosion

Science.gov (United States)

Results showed that a simple yttrium coating offered more potential for ... was from 70 to 150 K (125' to 200' F) above that for the yttrium coating. ...

Science.gov (United States)

Sputtering of glass coatings on cadmium sulfide thin film solar cells

DEFF Research Database (Denmark)

The heavy chain (HC) subunits of the bikunin proteins are covalently attached to a single chondroitin sulfate (CS) chain originating from bikunin and can be transferred to different hyaluronan (HA) molecules by TSG-6/HC2. In the present study, we demonstrate that HCs transferred to HA may function as HC donors in subsequent transfer reactions, and we show that the CS of bikunin may serve as an HC acceptor, analogous to HA. Our data suggest that TSG-6/HC2 link HCs randomly on the CS chain of bikunin, in contrast to the ordered attachment observed during the biosynthesis. Moreover, the results show that the transfer activity is indifferent to the new HC position, and the relocated HCs are thus prone to further TSG-6/HC2-induced transfer reactions. The data suggest that HCs may be transferred directly from HA to HA without the involvement of the bikunin CS chain. The results ...

Energy Technology Data Exchange (ETDEWEB)

This hazard analysis (HA) has been prepared for the 300 Area N Reactor Fuel Fabrication and Storage Facility (Facility), in compliance with the requirements of Westinghouse Hanford Company (Westinghouse Hanford) controlled manual WHC-CM-4-46, Nonreactor Facility Safety Analysis Manual, and to the direction of WHC-IP-0690, Safety Analysis and Regulation Desk Instructions, (WHC 1992). An HA identifies potentially hazardous conditions in a facility and the associated potential accident scenarios. Unlike the Facility hazard classification documented in WHC-SD-NR-HC-004, Hazard Classification for 300 Area N Reactor Fuel Fabrication and Storage Facility, (Huang 1993), which is based on unmitigated consequences, credit is taken in an HA for administrative controls or engineered safety features planned or in place. The HA is the foundation for the accident analysis. The significant event scenarios identified by ...

Science.gov (United States)

Probabilistic sensitivities using the score function method are developed for a lifing analysis of an alpha + beta titanium alloy in a round bar under axial fatigue load. Sensitivities with respect to the statistical inputs of the crack initiation size (a...

Science.gov (United States)

Quantitative metallography is often used to confirm the proper processing of aerospace metallic materials. A microstructural feature of great importance for titanium alloys processed in the alpha-beta phase field is the volume fraction of primary alpha. S...

International Nuclear Information System (INIS)

Some results on mechanical property study of copper and titanium subjected to impact load and next to neutron irradiation are presented. It was shown that shock wave influence involves a substantial shape change of the stress-strain diagram and of respective mechanical characteristics. Yield- and ultimate strength were substantially increased, as well as hardness with a considerable drop of plasticity. Also a heat stability of copper and titanium specimens was studied after being treated with shock-waves and neutron radiation. Results are given of electron microscope study of titanium structure sfter explosion hardening, which caused decomposition of hydride segregations in titanium and increased dislocation density.

Energy Technology Data Exchange (ETDEWEB)

Alloys are described which contain nickel, aluminum, boron, iron and in some instances manganese, niobium and titanium.

Science.gov (United States)

... Accession Number : ADA136144. Title : Characteristics of the Mechanical Properties and the Fractures of an Alpha Beta Titanium Alloy,. ...

International Nuclear Information System (INIS)

On the basis of symmetry way of texture description a calculation method of elastic moduli of two-phase titanium alloys with rolling texture has been suggested. Efficiency of the calculation formulas is checked by comparing the calculation results of Young modulus anisotropy in the sheet plane of (#alpha#+#beta#)-titanium alloy VT23 with the experimental data.

International Nuclear Information System (INIS)

Aim: Rheumatoid arthritis is a limiting disease having, among its pathological features, the inflammation of synovial tissue with progressive and later destruction of the articulation. This leads to joint deformation and loss of its function, generating pain and reducing the mobility of the affected articulation. The aim was to evaluate "1"6"6Ho-Hydroxyapatite ("1"6"6 Ho-HA) as potential radiopharmaceutical for the symptomatic treatment of chronic and acute arthritis. Materials and Methods: Holmiun-166 was produced by irradiation of Ho_2O_3 at La Reina Research Reactor, Nuclear Chilean Energy Commission. Hydroxyapatite was in-house synthesized. Its labelling and quality controls follows the internationally accepted procedures. An antigen's arthritis was induced to eight New Zealand rabbits with the "1"6"6 Ho-HA radiochemical being administered thereafter in two dosage modalities (single and double). The compound therapeutic efficiency was ...

KoreaScience (Korea)

Full Text Available

KoreaScience (Korea)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Short communication.

KoreaScience (Korea)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Simulated atmospheric corrosion studies were performed to determine the corrosion protection provided by galvanized zinc coatings on depleted uranium, U-0.75 Ti alloy, and U-6 Nb alloys. The accelerated ASTM tests consisted of exposing the galvanized samples to aqueous and aqueous chloride environments. The test results showed that anodic protection was provided by the electronegative zinc coatings on uranium and uranium alloys. Treating zinc with chromate conversion coatings also provided more protection.

International Nuclear Information System (INIS)

The leaching of phosphorus (P), nitrogen (N), and radionuclides "2"3"2Th, "2"2"6Ra, "2"2"8Ra, and "4"0K from Joel sands amended with red mud/gypsum (RMG) at 9 rates (0, 2, 4, 8, 16, 32, 64, 128, and 256 t/ha) was measured using columns. Intense leaching conditions (34 mm/day for 12 days) and a high rate of applied P (320 kg/ha as superphosphate) and N (680 kg/ha as ammonium nitrate) were used to simulate extremes of irrigated vegetable production on the Swan Coastal Plain. Addition of the highest rate of RMG (256 t/ha) reduced leaching of fertiliser P and ammonium-nitrogen (NH4-N) by 85% and 50%, respectively, compared with 0 t/ha after 12 days. At 64 t RMG/ha P leaching was reduced 50% compared with 0 t/ha. Nitrate-nitrogen (NO3-N) leaching was not affected by addition of RMG. Reduced leaching of NH4-N was attributed to an increase in ...

British Library Electronic Table of Contents (United Kingdom)

Nowadays there are many sun-protection cosmetics incorporating organic or inorganic UV filters as active ingredients. Chemically stable inorganic sunscreen agents, usually metal oxides, are widely employed in high-SPF (sun protection factor) products. Titanium dioxide is one of the most frequently used inorganic UV filters. It has been used as a pigment for a long period of cosmetic history. With the development of micronization techniques, it has become possible to incorporate titanium dioxide in sunscreen formulations without the previous whitening effect, and hence its use in cosmetics has become an important research topic. However, there are very few works related to quantitation of titanium dioxide in sunscreen products. In this research, we analysed the amounts of titanium dioxide i...

Energy Technology Data Exchange (ETDEWEB)

There is an increasing number of applications for hard coatings in engineering where the properties of the single-layer coating are not sufficient. One way to solve this problem is to use a multilayer coating that combines the properties of several coating materials. In this study, TiN-CrAlN and CrN-CrAlN multilayer coatings were deposited on 100Cr6 and S6-5-2 (DIN) steel substrates, by means of unbalanced magnetron sputtering. For comparison, TiN, CrN and CrAlN single-layer coatings were also prepared. For all depositions the coating temperature was below 473 K. Indentation testing, hardness measurements and scratch tests were performed to characterize the mechanical properties. The correlation between the wear behavior in rolling contact and the mechanical properties of the multilayer coatings is reported. A ball ...

Energy Technology Data Exchange (ETDEWEB)

From a macroscopic point of view, corrosion of Zn alloy coated steel sheet occurs by the coating preceding corrosion mechanism; microscopically, however, the coated layer corrosion velocity in the tip of corrosion is different. In order to find the main factors of under-film corrosion of Zn and Zn-Fe alloy coatings in the salt water spray atmospheric exposure test, the correlation between point inflation-exfoliation width and chlorine penetration behavior, point adhesion, and the difference in chlorine penetration behavior due to alloy coating components were investigated. Consequently, the following results were obtained: 1. The better correlation was observed between chlorine penetration distance and point inflation-point exfoliation width. 2. The durability of coating against chlorine penetration improved by increase in point adhesion and Zn content in the ...

International Nuclear Information System (INIS)

The effect of a substrate on the results of measuring tantalum coating thickness in two-layer compositions according to gamma radiation scattered by the substrate is studied. It is shown that by means of an albedo-radiometer realizing the physical model absorber-scatterer one can determine the thickness (application uniformity) of tantalum coatings up to 150-300 #mu#m depending on the substrate material (plexiglas, aluminium, iron, copper). In case of testing coatings on substrates of alloys and high-alloy steels in order to ensure high accuracy of measrurement it is expedient with the above albedo-radiometer to determine the value of the backscattered radiation flux for the substrate before coating application.

UK PubMed Central (United Kingdom)

The hemagglutinin (HA) glycoprotein of influenza virus performs two critical roles during infection: it binds virus to cell surface sialic acids, and under mildly acidic conditions it induces fusion...Full Text Available

International Nuclear Information System (INIS)

Russian 1984. p. 349. USSR Burtebaev, NT Dujsebaev, AD Knyaz'kov, OM

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As reported previously (Namba et al., 1985), normal human fibroblasts were transformed by 60Co gamma-ray irradiation into immortal cells with abnormal karyotypes. These transformed cells (KMST-6), however, showed a low cloning efficiency in soft agar and no transplantability. However, upon treatment with Harvey murine sarcoma virus (Ha-MSV), the cells acquired elevated clonability in soft agar and transplantability in nude mice. Ha-MSV alone, however, did not convert normal human fibroblasts into either immortal or tumorigenic cells. The Ha-MSV-transformed KMST-6 cells showed an enhanced expression of the ras oncogene, but normal and 60Co gamma-ray-transformed cells did not. Our current data suggest that gamma rays worked against normal human cells as an initiator, giving rise to chromosome aberrations and immortality, and that Ha-MSV, probably through its ras oncogene, played a role in the progression ...

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Jun 16, 2011 ... Results indicated that fuel loadings averaged 24.05 Mg ha 1 in 2004–2006. Forest litter decreased from wetter to drier forest life zones. ...

International Nuclear Information System (INIS)

Hybrid organic-inorganic coatings with phosphonate functionalities have been synthesized and evaluated as prospective surface treatments for magnesium materials. These coatings have been processed via a sol-gel route by hydrolysis and condensation of a mixture of diethylphosphonatoethyltriethoxy-silane and tetraethoxy-silane with variable molar ratios. The coatings morphology and the surface chemistry at the coating/substrate interface have been characterized using scanning electron microscopy, X-ray photoelectron spectroscopy, "3"1P nuclear magnetic resonance spectroscopy, and time-of-flight secondary ion mass spectrometry. The corrosion protection performance of the coatings deposited on magnesium alloy AZ31B has been examined by a group of electrochemical techniques including potentiodynamic polarization and electrochemical impedance spectroscopy. In addition, a scanning Kelvin ...

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In the framework of the European Fusion Technology Programme ECN participates in a NET task PSM-8 `Coatings and Surface Effects on Stainless Steel 316L`. High emissivity coatings were developed for enhanced heat transfer from graphite tiles to a Stainless Steel First Wall. Four candidate materials, Cr{sub 2}O{sub 3}, Black Cr, Al{sub 2}O{sub 3}/TiO{sub 2} and TiC were tested as candidate high emissivity coatings. These coatings were manufactured by atmospheric and vacuum plasma spraying technique and the Black Chromium coatings were manufactured by a galvanic coating technique. The tests included total emissivity measurements and Low Cycle Fatigue (LCF) experiments. The total emissivity of two TiC coatings at 525 K appeared to be 0.62 and 0.64. The total emissivity of the TiC and 5 wt% TiO{sub 2}/Al{sub 2}O{sub 3} ...

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Hyaluronic acid (HA) is a significant component of the extracellular matrix (ECM), particular interest being shown herein in synovial fluid. The present study aims to investigate the degrading effects of X-ray radiation on HA at radiotherapy doses. Measurements of viscosity and shear stresses on HA solutions have been made at different shear rates using various types of viscometer for different concentrations in the range 0.01-1% w/v of HA. The HA has been subjected to doses of 6 MV photon radiation ranging from 0 to 20 Gy, the major emphasis being on doses below 5 Gy. It is found that there is a dose-dependent relationship between viscosity and shear rate, viscosity reducing with radiation dose, this being related to polymer scissions via the action of radiation-induced free radicals. The dependency appears to become weaker at higher concentrations, possibly due to the contribution ...

International Nuclear Information System (INIS)

This study was designed to identify abnormalities in the hepatic-arterial/portal-venous scintiangiogram (SA) in alcoholic hepatitis (AH). SA's were performed in 35 patients with acute alcoholic hepatitis (AAH), 8; acute alcoholic hepatitis superimposed on cirrhosis (A/C), 14; and cirrhosis (C), 13. Posterior flows were done with a bolus of 10 mCi Tc-99m sulfur colloid with computer time-activity curves over the liver and left kidney. Curves were analyzed for per cent of hepatic arterial (HA) and portal venous contribution using the slope ratio method. Hepatic arterialization was estimated from the angle of the HA component of the curve. Reversal of the relative contribution of the hepatic and portal components of total flow were seen in all groups. Although quite severe in AH, the degree of reversal could not be used to differentiate among the groups. The average HA angle in AAH was 48.3 +- 8.1, in A/C 41.5 +- 10.6, and in ...

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In this paper, the influence of plasma nitriding at temperature 720 deg. C for 20 h on the surface microstructure and interface microstructure of electroplated chromium coating was investigated. In these conditions, interdiffusion, mixing and reaction phenomena of elements originating from the substrate and coating material are more likely to occur, thus increasing the bonding strength between the coating and carbon steel substrate. The change of the structures from the substrate side to the coating surface, and the effect of the substrate steel on the interface structure were studied by cross-sectional transmission electron microscope observation (XTEM). The nitride layer formed on the surface was analyzed by X-ray diffraction method (XRD). After treatment at above conditions a 6-7 {mu}m thick nitride compound layer was formed in surface region and the same thick carbide compound layer was also formed ...

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Phosphate/chromate and accelerated chromate coatings were produced on commercially available aluminium. The Cr, P and Fe components of the conversion coatings were determined by radioactive tracer technique. The tracer technique was combined with ion-exchange and film-sectioning methods to determine the chromium(III)/total chromium ratio in the accelerated chromate coating. It was found that during the acidic dissolution of the conversion coating the chromium(III)/total chromium ratio may suffer changes. The film-forming components in the metal/bath interface are supersaturated and deposited onto the aluminium. The identified components of the accelerated chromate coatings are Cr(OH)sub(3), Cr(OH)CrOsub(4) and Crsub(4)(Fe(CN)sub(6))sub(3) and the chromium(III)/total chromium ratio was found to be cca. 2/3. (author). 11 refs.; 5 figs.

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Assembly of icosahedral capsids of proper size and symmetry is not understood. Residue F170 in bacteriophage P22 coat protein is critical for conformational switching during assembly. Substitutions at this site cause assembly of tubes of hexamerically arranged coat protein. Intragenic suppressors of the ts phenotype of F170A and F170K coat protein mutants were isolated. Suppressors were repeatedly found in the coat protein telokin-like domain at position 285, which caused coat protein to assemble into petite procapsids and capsids. Petite capsid assembly strongly correlated to the side chain volume of the substituted amino acid. We hypothesize that larger side chains at position 285 torque the telokin-like domain, changing flexibility of the subunit and intercapsomer contacts. Thus, a sing...

International Nuclear Information System (INIS)

By the methods of microstructural and electron-microscopic analyses by the tension test and impact test studied is the effect of quenching conditions on structure and mechanical properties of the TS6 titanium-#beta# alloy. It is shown that low temperature quenching from 700 deg C, recommended earlier for analogous VT15 titanium alloy, leads to appearence of intercrystalline fracture and to sharp decrease of impact strength of the TS6 alloy. Established are optimum conditions for quenching of half-finished products and articles of the TS6 alloy depending on their subsequent working or operation.

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The feasibility of the anodic protection of titanium evaporators in Al[sub 2](SO[sub 4])[sub 3] solution was studied by the measurement of polarization curves, weight loss, solubility of passive film and AC impedance. The protection parameters and efficiency were determined. In addition, the practical technology of anodic protection was studied by screening reference electrodes and auxiliary cathodes. Throwing power was also measured. Four rows of tube-type evaporators of titanium have been anodically protected in situ. Field tests lasting more than one year shows satisfactory results. (orig.)

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Low-cost fabrication of PMC composite sandwich panels, including metallic surface preparations for bonding the PMC to titanium honeycomb. ...

KoreaScience (Korea)

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... [11]Richter, K., Orban, S., and Nowotny, S., Laser cladding of the titanium alloy TI6242 to restore damaged blades, Proceedings of the 23rd ...

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Development efforts have been undertaken to improve the processing and structural efficiencies of

International Nuclear Information System (INIS)

Corrosion tests of titanium alloys VTI-0, OT4, VT5-1 and steel Kh18N1OT in 10% and 18% HCl with additions of carnallite at 40 deg C have been carried out. It has been established that titanium alloys in 10% and 18% HCl containing 5 and 10% carnallite are sufficiently corrosion resistant in the presence of 0.1-1% FeCl or HNO_3 and can be used for manufacturing the equipment of recirculation gas scrubbers. Steel Kh18N10T is unstable in all the media tested. It is subjected to intensive pitting. Specimens of steel Kh18N10T have also revealed edge cracking.

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(Feb 1972). United States Nelson, HG Williams, DP Stein, JE v. 3(2)

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Procedures for a New High-Strength, Beta Titanium Alloy having. Superior Formability, " Technical Report AFML-TR-69-171, Air ...

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... transformed at 705°C. The cooling rate and temperature dependence of matrix decomposition for Ti6242 was thus similar to that for Ti64 x [9]. ...

UK PubMed Central (United Kingdom)

The purpose of this study was to synthesize biocompatible polyvinylpyrrolidone (PVP)-coated iron oxide (PVP-IO) nanoparticles and to evaluate their efficacy as a magnetic resonance imaging (MRI)...Full Text Available

UK PubMed Central (United Kingdom)

The objective of this work was to evaluate the physical properties and in vivo circulation of chitosan (CH)-coated liposomes of mitoxantrone (MTO). Changes in particle size and zeta...Full Text Available

UK PubMed Central (United Kingdom)

A serological trapping technique for detecting rotaviruses is described which involves coating electron microscope grids with protein A and specific rotavirus antiserum. The presence of a layer of antibodies...Full Text Available

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The metal-semiconductor solar cell is a potential candidate for converting solar energy to electrical energy for space and terrestrial application. In this paper, a method for obtaining parameters of practical antireflection (AR) coatings for the metal-semiconductor solar cells is given. This method utilizes the measured equivalent index of refraction obtained from ellipsometry, since the surface to be AR coated has a multilayer structure. Both the experimental results and theoretical calculations of optical parameters for Ta/sub 2/O/sub 5/ AR coatings on Au-GaAs and Au-GaAs/sub 0.78/P/sub 0.22/ solar cells are presented for comparison. (AIP)

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New data about the structure of high-temperature resistant metalloceramic plasma sprayed coatings in micro and nano areas are presented. Application of the new instrumental methods: transmission electron microscopy combined with selected area electron diffraction mode is possible to obtain these data. The first layer in Ni based metallic bond coat shows nanocrystalline structure. External ceramic layer based on stabilised ZrO_2 is polycrystalline and contains both cubic and tetragonal crystalline phases. Local inhomogeneities in coatings phase composition are determined. (author)

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... The data were transformed into total hemispherical emittance values and correlated with respect to ceramic coating thickness and temperature ...

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This book describes the uses, coatings, and fabrication of laser materials. Topics considered include: optical waveguide materials; optical storage materials; holographic recording materials; phase conjunction materials; holographic recording materials; phase conjunction materials; laser crystals; laser glasses; quantum counter materials; thin films and coatings; multilayer dielectric coatings; graded-index surfaces and films; optical materials fabrication; fabrication techniques; fabrication procedures for specific materials.

International Nuclear Information System (INIS)

With the deposition of PVD hard coatings on the tools applied in machining operations it is possible to achieve significant improvements in the performance and quality of the machining processes. Depending on the machined material and the operating principle, e.g. turning, milling or drilling, not only different machining parameters but also different coating materials are necessary. In interrupted cut machining of tempered steel, for example, the life time of Ti-C-N coated inserts is several times greater than the Ti-C-N coated ones. This is a result of the favourable thermophysical and tribological properties of Ti-N-C. The potential for tool protection by CrN coatings is a result of the high ductility and low internal stress of this coating materials. CrN films can be deposited with greater film thickness, still maintaining very good adhesion. This paper ...

International Nuclear Information System (INIS)

The cathodic vacuum arc provides a means of producing large currents of positive ions of a wide variety of materials. These ions can be utilized to produce coatings with improved properties such as higher density and adhesion. The processing is particularly useful in reactive deposition of ceramic coatings having excellent stoichiometry. In this review, emerging aspects of the technology are emphasized.

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The method of the present invention comprises a step of previously coating a positive type resist on the surface of equipment, a step of solidifying the coated positive type resist and a step of bringing the coated equipment to circumstances for use and cleaning the positive type resist. With such procedures, the amount of radioactive materials deposited on the equipment can be reduced, and redeposition of nuclides on the surface to be cleaned can be prevented. (T.M.)

International Nuclear Information System (INIS)

The high nutrient nitrogen and organic matter contents of sewage sludge (SS) make it a potential organic fertilizer for sandy soil. In this study, "1"5N-labelled ammonium sulphate was used to investigate the availability of nitrogen from irradiated and non-irradiated sewage sludge to tomato plants. The application of sewage sludge to sandy soil increased dry matter production (DMP), nitrogen yield (NY) and nitrogen recovery (NR) over two successive years. A positive relationship was found between sludge application rate and DMP and NY. The increase was significantly higher (P=0.05) in irradiated than non-irradiated sewage sludge. Total nitrogen derived from non-irradiated sewage sludge are : 48.0, 63.7, 73.5, 105.2 Kg/ha, whereas, the total nitrogen derived from irradiated sewage sludge are: 55.1, 72.5, 88.9, 141.4 Kg/ha corresponding to application rates of 10 t/ha, 20 t/ha, 30 ...

International Nuclear Information System (INIS)

Research highlights: ? Reports a high protection system for the alloy in corrosive environment. ? Describes an interfacial process with self-healing properties. ? Reports the influence of substrate pre-treatment in the coating performance. - Abstract: In this paper the interface of poly(vinylidene fluoride) coatings prepared by the dip coating method and HF-treated AZ31 magnesium alloy was evaluated. The best performance of this system in corrosion tests compared to ground, as-received and acetic acid cleaned substrates is related to an acid-base interaction at the interface and to interfacial reactions which resulted in a self-healing process. The protectiveness of the samples was investigated using impedance and immersion tests while the coating morphology and interface stability were investigated by scanning electron microscopy, X-ray photoelectron spectroscopy and adhesion tests.

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The effect of the coated composite surface of particles on the mechanical properties of the powder bed was investigated. Polyethylene-silica surface composite powder was prepared at several coating ratios with Hybridizer. Various tests on mechanical properties of the powder bed were carried out with the prepared powder, and the following results were obtained: The ultimate tensile strength depends only on the cohesive force between particles, and the contact probability model of composite particles led to good agreement between the experimental and calculated values. The coefficient of internal friction and cohesive shear strength were influenced due to the interlocking effect of the surface roughness of composite particles. The effects of coating particles became small with dynamic properties like angle of repose. It is possible to control the mechanical properties in a step wise fashion by changing the ...

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Analysis reproducibility and detection sensitivity of capillary electrophoresis (CE) are often questioned by applied scientists, which has hindered its application as a routine method. To address these issues, a simple, precise, and reproducible dynamic coating method was developed by applying carboxymethyl chitosan (CMC) dynamic coating on fused silica capillary. The proposed coating was accomplished by simply rinsing the capillary with CMC solution for 1?min in between runs, with no regeneration procedure or buffer additives needed. Electroosmotic flow could be well controlled by adjusting the pH of background electrolyte, and the adsorption of analytes onto the capillary inner wall was effectively eliminated. The main parameters of the coating condition were optimized, and extensive app...

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Ion storage CeO{sub 2} and CeO{sub 2}/SnO{sub 2} coatings were prepared by sol-gel dip-coating method using aqueous-based process. The influence of added SnO{sub 2} in the CeO{sub 2} oxide coatings on the inserted/extracted charge was determined by chronocoulometric measurements. It was found that for 60 nm thick film the inserted/extracted charge was twice larger (Q = 10mC/cm{sup 2}) for films containing 17 mol % SnO{sub 2} if compared to pure CeO{sub 2}. The addition of SnO{sub 2} to the mixed oxides coatings on their optical properties and structural characteristics were studied.

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The determination of residual stress (RS) in case-hardened steel gear truck synchronisers coated with thermal sprayed molybdenum was carried out using neutron and synchrotron X-ray diffraction. Two samples with different coating thicknesses (about 120 ?m and 1.4 mm) and different steel substrates (16MnCr5 and SAE4140, respectively) were investigated. Microanalysis revealed substantial porosity in both samples and some debonding was observed between the thin coating and the substrate. The bulk hardness of the SAE 4140 proved to be much higher than the 16MnCr5 and the surface case-hardening increased it by a further 20%. The full three-dimensional stress depth-profile was determined by neutron diffraction (ND) in both the coatings and the substrates, while synchrotron radiation allowed a dep...

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Abstract Introduction.- Infection is the worst complication seen with inflatable penile prosthesis (IPP). Both the American Medical Systems (AMS) and Coloplast IPP have infection retardant coatings. AMS is coated at the factory with rifampicin and minocycline (InhibiZone). The Coloplast IPP has a hydrophilic coating covalently bonded to its components that will absorb any aqueous solution before implantation and provides increased surface lubricity to decrease bacterial adherence. Aim.- We tested several antibiotic dips comparing zones of inhibition (ZOI) against five commonly infecting bacteria with coated Coloplast implants. Results were compared with those ZOI created with strips of an AMS IPP precoated with InhibiZone. Methods.- Pieces of sterile Coloplast Titan IPP were dipped in (i) ...

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The combined processes of plasma nitriding and cathodic arc deposition of (Ti,Cr,Nb)CN coatings were applied to HSS substrates. The nitrided layers, obtained in a mixture of H2 (70%) and N2 (30%) at two different temperatures (480^oC and 510^oC), were examined for the microhardness depth profiles. Characterization of the duplex coatings was performed by investigating elemental and phase composition, texture, hardness, friction and wear. XRD and XPS analyses revealed the formation of a mixture of a carbonitride fcc solid solution, in a dominant proportion, and metallic chromium. The film hardness was measured to be ~34GPa. The duplex (Ti,Cr,Nb)CN coatings exhibited superior tribological behavior as compared to both nitrided layers and non-duplex coatings.

International Nuclear Information System (INIS)

The influence of heat treatment on the structure, mechanical properties and fracture peculiarities of high-strength (#alpha#+#beta#)-titanium alloy VT22 has been studied. It is ascertained that thermal cycling and subsequent high-temperature aging permit to reduce considerably crack growth rate. Thermal cycling is realized in the following mode: heating in #beta#-region, cooling and allowance in (#alpha#+#beta#)-region, heating in #beta#-region.

International Nuclear Information System (INIS)

VT6 titanium alloy long-range fibers have been extracted from the suspended melt drop with the following high-rate solidification. Formation of the structure of fibrous porous material prepared from these fibers has been studied. 7 refs.; 5 figs.; 2 tabs.

International Nuclear Information System (INIS)

The influence of structure on mechanical properties in the course of tensile tests in a wide range of temperatures was studied, using the VT16 structure thermally strengthened (alpha+beta)-titanium alloy by way of example. It is ascertained that transition from ductile to brittle fracture at the temperature of -196 deg C is observed only in coarse-grain alloy having alpha-eldging of beta grains.

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The relationships of hydrogen alloyed #beta#-titanium alloy deformation behaviour to its microstructure and texture are investigated. It is shown that plasticity increases and strain induced texture changes at low hydrogen contents (0.1-0.2 mass %). Possible mechanisms responsible for specific features of #beta#-Ti alloy deformation are discussed. The study is made using alloy VT35 doped with hydrogen

International Nuclear Information System (INIS)

Peculiarities of metastable #beta#-solid solution decmposition in titanium alloy VT30 in the process of isothermal ageing in the range 500-650 deg C are investigated. Using the methods of transmittion electron microscopy, X-ray diffraction analysis, etc., it is shown that in the case of alloy quenching from the temperature below the point of complete polymorphous transformation (T_t_._t_.), as well as after warm rolling the course of subsequent decomposition of solid solution can be consierably complicated.

UK PubMed Central (United Kingdom)

This study prospectively assessed the outcome of 134 cemented titanium stems and serum ion levels. The stems were polished (0.1 μm Ra) with circular cross section. At the end point,...Full Text Available

International Nuclear Information System (INIS)

The physical, chemical and mechanical properties of magnesium alloys make them attractive materials for automotive and aerospace applications. However, these materials are susceptible to corrosion and wear. This work discusses the potential of using sol-gel based coatings consisting of ZrO_2 and 15 wt.% of CeO_2. The CeO_2 component provides enhanced corrosion protection, while ZrO_2 impart corrosion as well as wear resistance. Coating deposition was performed by the dip coating technique on two magnesium alloy substrates with different surface finishes: AZ91D (as-casted, sand-blasted, and machined) and AZ31 (rolled and machined). All as-deposited coatings (xerogel coatings) were then subjected to 10 h annealing: a temperature of 180 C was applied to the AZ91D alloy and 140 C to the AZ31 alloy. Morphological and structural properties of the annealed coatings ...

Science.gov (United States)

The papers contained in this volume provide an overview of recent theoretical and experimental research related to the fracture toughness and fatigue crack growth characteristics of titanium alloys. Topics discussed include room temperature fatigue crack propagation in beta-titanium alloys, fatigue crack growth rate acceleration in alpha+beta Ti alloys, influence of transformed beta microstructures on fatigue crack growth rates in Ti-6Al-4V, and the role of inclusion and pore content on the fracture toughness of powder processed blended elemental Ti-10V-2Fe-3Al. Papers are also presented on fatigue crack growth measurements in an alpha-beta titanium alloy, the effects of thermal processing variation on the properties of Ti-6Al-4V, and the effect of microstructure on ductility and fracture toughness of alpha+beta titanium alloys.

International Nuclear Information System (INIS)

Vanadium(V) in aqueous HCl, HNO_3 or H_2SO_4 solutions is extracted with 2-carbethoxy-5-hydroxy-1-(4-tolyl)-4-pyridone (HA) dissolved in CHCl_3 and determined spectrophotometrically, Depending on the composition of the aqueous phase, two complexes are formed. At pH 1 (HCl, HNO_3, H_2SO_4) VO_2A(HA)_2 is formed with maximal absorption at 478 nm. However, from 4-5 M HCl, VO_2Cl(HA)_3 is extracted, and has maximal absorption at 615 nm. The same complex is extracted from 2-3 M HNO_3 or 3-4 M H_2SO_4 if enough chloride is added. Solutions of both complexes follow Beer's law and the molar extinction coefficients are 4.15x10"3 1.mole"-"1cm"-"1 at 478 nm and 5.10x10"3 at 615 nm. The determination of vanadium at both wavelengths is very simple, fast and selective. The composition of the complexes was established by the usual methods as well as by characterization of the isolated crystalline compounds by elemental analysis and ...

International Nuclear Information System (INIS)

Establishment of a continuous population has been prevented over a 24 year period in the San Joaquin Valley, USA, through continuous, daily in-season release of sterile pink bollworms based on an extensive trap monitoring programme. A post-harvest crop destruction ordinance and occasional use of pheromones as disruptants were the only other factors used by programme management, except in 1990. In 1990, the programme used a conventional insecticide on 280 acres (113 ha) out of 1.18 million acres (477,546 ha) of cotton. During the four year period 1986-1989, a management system was explored using a high rate pheromone disruption system and sterile insects. Major reductions in conventional insecticide usage, while maintaining extremely low populations, were evident in this semi-isolated valley of southern California. It is hoped that this will provide a model for a future large scale test on up to 20,000 acres (8100 ha) of ...

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Mechanistic studies on a charged ultrafiltration (UF) membrane fouled with natural organic matter (NOM) and colloidal particles are systematically investigated to understand the relative role of each NOM fraction and the presence of colloidal particulate to membrane fouling. Humic acid (HA), dextran, and kaolin were employed as surrogate model foulants representing the organic hydrophobic acid NOM, hydrophilic neutral NOM, and inorganic colloidal materials, respectively. The results obtained showed that the organic NOM of hydrophilic surrogate (dextran) plays a primary role in promoting membrane fouling, followed by hydrophobic acids and inorganic kaolin, but to a lesser extent than organic NOM compounds. Significant differences in the extent of fouling between dextran and HA have been obs...

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Nitrogen use efficiency (NUE) of tef, a major staple crop in Ethiopia, is very low, either caused by untimely use of nitrogen (N) fertilizers or lack of other essential nutrients like sulphur (S). The average grain yield of this crop is low, averaging ?1 in farmer?s fields of the semi-arid conditions. Therefore, the present study was conducted to see the effect of the timing of combined N and S fertilization on the yield, yield components, and N and S concentration in the plant parts of the crop. A factorial combination of three rates of N (0, 70, and 105?kg?ha?1) with four rates of S (0, 16, 32, and 48?kg?ha?1) was applied in randomized complete blocks in three replications. The experiment was carried out in the 2004 and 2005 cropping seasons in the Cambisols of the semi-arid area of Ethi...

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Copper coatings deposited on Al-6061 substrates by radio frequency magnetron sputtering, to prevent the retention and permeation of energetically implanted tritium in Al-6061, were evaluated by a variety of characterization techniques. The coatings, weighing in the 0.03 to 0.088 kg/m{sup 2} range, were smooth and had a fine grain structure. They contained the intermetallic phases Cu{sub 9}Al{sub 4} and CuAl{sub 2} as well as copper. The fractions of Al and Cu in any coating increased and decreased, respectively, with increasing depth below the surface. Furthermore, the fractions of Al and Cu on the coating surface decreased and increased, respectively, with increasing coating weight. There was no texture or preferred orientation in the Cu phase of the coatings. A significant amount of oxygen was also detected at the original substrate surface. Residual stress ...

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Fluoroalkyl end-capped vinyltrimethoxysilane oligomer suffered the sol-gel reaction under alkaline conditions in the presence of titanium oxide nanoparticles in tetrahydrofuran to afford the corresponding fluorinated oligomer/titanium oxide nanocomposites[RF-(VM-SiO2)n-RF/TiO2] in excellent to moderate isolated yields. These fluorinated composites thus obtained were nanometer size-controlled fine particles, and exhibited good dispersibility and stability in traditional organic solvents except for water. These fluorinated nanocomposites were applied to the surface modification of glass to exhibit not only a completely superhydrophobic characteristic (a water contact angle: 180degree) with a non-wetting property against water droplets but also a good oleophobicity imparted by fluoroalkyl seg...

International Nuclear Information System (INIS)

A thermodynamic analysis of the behaviour of Alloy 800 in helium based atmospheres relevant to the High Temperature Gas Cooled Reactor indicates that, depending upon the precise gas composition, oxidation and carburisation, or carburisation alone may be expected. The prime influence appears to be the moisture level. The morphology and structure of the reaction products are discussed. It is shown that the 'reactive' elements chromium, manganese, titanium and silicon are concentrated in the oxide scale which is normally duplex in structure. Aluminium oxide is formed at grain boundaries and in an internal oxidation zone together with titanium and sometimes silicon. In carburising conditions, mixed titanium-chromium carbides are formed. When this occurs, intergranular penetration is maximised. Weight gain data are assessed and briefly described and a tentative model for the mechanism of corrosion of Alloy 800 in HTR helium is ...

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Titanium oxides were grown anodically to selected final potentials on grade II polycrystalline titanium under different anodization rates. XPS and RBS results show that the oxide consists of primarily TiO2 with a non-stoichiometric oxide/metal interface, with the slower growth rate associated with a thicker layer at the interface. Characterization using TEM reveals that the structure of the oxide evolves from a primarily amorphous phase to islands of crystallites in an amorphous matrix, to an entirely crystalline phase by increasing the polarization potential. Slower growth rates tend to remain crystalline at higher potentials. The mechanical strength of oxide films extracted from load-depth data by nanoindentation varies dramatically for oxide films grown by different rates at 9.4 V, and to a lesser extent at lower potentials. The variation of film strength is associated with both compositional and structural characteristics.

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An inorganic particulate adsorbent of a titania-alumina is described for treating a superheated water containing radioactive materials such as cobalt ions, which is free from release of corrosive impruities, and which has a high adsorption capacity of radioactive materials and a high mechanical strength is prepared by hydrolyzing a titanium alkoxide and an aluminum alkoxide, thereby forming a hydrous titanium oxide and a hydrous aluminum oxide, respectively; precalcining the hydrous titanium oxide and aluminum oxide, mixing and molding the resulting titania and alumina into a particulate mixture thereof having a titania mole fraction of 0.2 to 0.9, and calcining the particulate mixture at 500/sup 0/-700/sup 0/C. This absorbent is effectively used in treat boiling water-type nuclear reactor core-circulating water to remove radioactive substances therefrom.

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Titanium diboride was heated to high temperatures using microwaves. The highest temperature obtained was 2245/degree/C. Unfortunately, oxidation was a problem, especially at the higher temperatures, although an argon flush and a carbon getter were used. To completely stop oxidation, the oxygen potential must be below 10/sup /minus/18/ atmospheres. Using an argon flush and a carbon getter, titanium diboride was successfully densified to 82% of theoretical without measurable oxidation by heating with microwaves to 1860/degree/C. Density actually decreased upon reaching temperatures above 1860/degree/C due to void formation adjacent to the surface. Void formation is thought to be due to the formation of B/sub 2/O/sub 3/(g) which evolves rapidly above 1860/degree/C because of the loss of a TiO/sub 2/ protective film which melts at this temperature. 9 refs., 12 figs., 2 tabs.

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Asymmetric Incremental Sheet Forming (AISF) is a relatively new manufacturing process. In AISF, a CNC driven forming tool imposes a localized plastic deformation as it moves along the contour of the desired part. Thus, the final shape is obtained by a sequence of localized plastic deformations. AISF is suitable for small series production of sheet metal parts as needed in aeronautical and medical applications. Two main process limits restrict the range of application of AISF in these fields. These are the low geometrical accuracy of parts made from titanium alloys or high strength steels and, for titanium alloys, the limited formability at room temperature. In this paper a new concept for laser-assisted AISF is introduced including the required components. Furthermore, the CAX tools used f...

International Nuclear Information System (INIS)

The effect of various hydrogen concentrations on the crystal lattice period and the hardness of titanium alloy was examined, the alloy containing about 16 at.% Mo (27.5 wt. % Mo) and having #beta# structure. The peculiar features of the mechanism of plastic deformation of the alloy were studied after adding hydrogen to it. A dependence of the crystal lattice period on the concentration of hydrogen was obtained for TixMoxH_2 alloy. It has been established that the hardness of the Ti-Mo alloy does not change when hydrogen is added to it. The presence of hydrogen introduces changes into the mechanism of deformation of #beta#-titanium alloy. The configuration of the inverse pole figures after rolling proves that the transverse slip process in an alloy with hydrogen is hampered, and that the coplanar slip process is developing in it.

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Statement of problem Titanium is the most biocompatible metal used for dental casting; however, there is concern about its marginal accuracy after porcelain application since this aspect has direct influence on marginal fit. Purpose The purpose of this study was to determine the effect that metal selection and the porcelain firing procedure have on the marginal accuracy of metal ceramic prostheses. Material and methods Cast CP Ti, milled CP Ti, cast Ti-6Al-7Nb, and cast Ni-Cr copings (n=5) were fired with compatible porcelains (Triceram for titanium-based metals and VITA VMK 95 for Ni-Cr alloy). The Ni-Cr alloy fired with its porcelain served as the control. Photographs of metal copings placed on a master die were made. Marginal discrepancy was determined on the photographs using an image ...

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The production method of the elastic composite containing ferrous particles and titanium barium particles dispersed in the porous silicone matrix is described in this article. Since it contains ferrous and titanium barium particles, this composite shows magnetorheological and also electrorheological properties. The electrostriction of composite samples in the electric field with maximal intensity 1.5x10{sup 6} V/m was investigated. The magnetostriction in the magnetic field with maximal induction 1 T was also investigated. It was found that samples elongate with increased electric field intensity, and the magnetic field induction was detected. By increasing the samples' elongation with increase of ferrous particles, titanium barium particles and pores number were also detected. In the investigated division of the electric and magnetic field the elongation changed in a linear way. The maximal elongation achieved was ...

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This paper describes an investigation of electrodeposited Zn-14% Ni and aluminium-based SermeTel 1140/962 coatings as possible replacements for cadmium. Slow strain rate tests were performed to measure the extent of direct hydrogen embrittlement of a high strength steel substrate as a result of the coating process and of hydrogen re-embrittlement caused by coating corrosion. The level of re-embrittlement was shown to depend on both the electrochemical potential of the coating and its barrier properties. Zn-14% Ni coatings caused the most re-embrittlement as they had the most active potential and contained through-thickness defects which left the steel exposed to hydrogen uptake. The microstructure of the high strength steel was also shown to be an important factor affecting the extent of embrittlement. AerMet 100 steel was more resistant than 300M steel and this was attributed to ...

Energy Technology Data Exchange (ETDEWEB)

Several types of coatings have previously been visually identified on the surface of 105-K East and 105-K West Basins fuel elements. One type of coating (found only in K West Basin) in particular was found to be a thick translucent material that was often seen to be dislodged from the elements as flakes when the elements were handled during visual examinations (Pitner 1997). Subsequently it was determined (for one element only in a hot cell) that this material, in the dry condition, could easily be removed from the element using a scraping tool. The coating was identified as Al(OH){sub 3} through X-ray diffraction (XRD) analyses and to be approximately 60 {micro}m thick via scanning electron microscopy (SEM). However, brushing under water in the basin using numerous mechanical strokes failed to satisfactorily remove these coatings in their thickest form as judged by appearance. Such brushing was done ...

International Nuclear Information System (INIS)

The photon rupture method, by which oxide film and metal are removed by focused pulsed Nd-YAG laser beam irradiation, was applied to form artificial micro-pits in Zn-5 mass% Al alloy-coated steel. The zinc alloy-coated layer was removed by pulsed laser irradiation treatment for about one second in a neutral buffer solution with NaCl. The rest potential transient with the laser treatment was measured. In the early stage of the laser treatment the rest potential of zinc alloy-coated steel changed to the negative direction immediately after every irradiation of a laser pulse and then returned to the previous value. However, after the steel substrate was exposed to the solution, the rest potential moved to the positive direction immediately after every irradiation of a laser pulse and then returned to the previous value. The amplitude and duration of the potential change after the laser irradiation increased with repetition of ...

Energy Technology Data Exchange (ETDEWEB)

Lower cost painting flock-like in appearance and touch feeling was developed as a new surface softening method for automobile interior plastic molded parts. The base coat with the same color as piles mixed into a top coat was first painted on the surface of a plastic molded part after cleaning, and after the top coat with less pitch mixed with piles was painted on the wet base coat and dried by a heater, excess piles were removed with suction and air blowing to produce flock-like appearance. Nylon 66 of 0.4mm in length was used as piles, and mixed into the top coat by 8.0wt% in content. This painting method was applicable to even such parts as one with a complex configuration, and one impossible to set piles on it by conventional methods because of poor durability. As a certain amount of piles with different colors were mixed into the top coat, sprinkly colored ...

International Nuclear Information System (INIS)

The authors describe measurements of emittance made on samples of solar cell coverglasses incorporating new coatings both on C-7940 fused silica and on CMX ceria doped microsheet. Samples of a conventional, MgF_2 coating on the same two types of coverglass substrates were included in the measurements as controls. Measurements were made by the calorimetric method of total hemispherical emittance within a cooled chamber as well as by the more common infrared reflectance method. Emittance enhancements from 1 to 4% were measured for the new coatings.

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Electron paramagnetic resonance was used to investigate surface-coated magnetite-based magnetic fluids doped with TEMPOL. Two magnetic fluid samples, having magnetite nanoparticles with average diameter of 94 A and coated with different coating layers (lauric acid plus ethoxylated polyalcohol in one case and oleoylsarcosine in the other case), were doped with TEMPOL (6 mM and pH 7.4) and investigated as a function of the nanoparticle concentration. The resonance field and the resonance linewidth both scale linearly with the nanoparticle concentration.

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In Italy, short rotation coppice (SRC) has become very popular in recent years, with over 4000 ha already planted - almost exclusively with clonal poplar. Commercial harvesting operations are dominated by modified foragers, equipped with dedicated SRC headers. At present, contractors use two main header types: German Claas HS-2 and Italian GBE. The former fits smaller foragers with a power below 300 kW, the latter is used on larger harvest units. This study models the performance of modified foragers on a range of short-rotation poplar plantations. Data were collected from 45 operations, covering a total of 118 ha and producing over 4400 green tonnes of wood chips. The average yield of the fields harvested during the trials was about 23 gt ha{sup -1} year{sup -1} (at a moisture content of 59%), and machine productivity ranged from 9 to 70 green tonnes per scheduled machine hour (gt SMH{sup -1}), with an average value of 35 ...

International Nuclear Information System (INIS)

The heavy Higgs bosons H,A of the minimal supersymmetric extension of the Standard Model can be produced as resonances in high-energy #gamma##gamma# colliders. Prospects of the search for these particles in bb-bar and neutralino-pair final states are studied in this report. Heavy Higgs bosons can be found with masses up to about 70-80% of the initial e"+e"- collider energy for moderate values of tan #beta#, i.e. in areas of the parameter space not accessible at other colliders.

Science.gov (United States)

Quantification of the downed woody materials that comprise forest fuels has gained importance in Caribbean forest ecosystems due to the increasing incidence and severity of wildfires on island ecosystems. Because large-scale assessments of forest fuels have rarely been conducted for these ecosystems, forest fuels were assessed at 121 US Department of Agriculture forest service inventory plots on Puerto Rico, Vieques, and the US Virgin Islands. Results indicated that fuel loadings averaged 24.05 Mg ha(-1) in 2004-2006. Forest litter decreased from wetter to drier forest life zones. These island forests showed a paucity of coarse woody fuels (CWD) (2.91 Mg ha(-1)) and relatively greater quantities of smaller-sized fine woody fuels (FWD) (10.18 Mg ha(-1) for FWD and 10.82 Mg ha(-1) for duff/litter) when compared to continental tropical forests. Between 2001 and 2006, CWD fuel loads decreased, while fine ...

International Nuclear Information System (INIS)

The first step in the protection of the environment is the control of pollutant level in the components of the environment. The application is compared of radionuclide X-ray fluorescence analysis (RXFA) used for this purpose with polarographic and nuclear analytical techniques. The advantage of RXFA is its high sensitivity and selectivity, its low time and cost exactingness. The origins and development of RXFA are described. (Ha).

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Performance and emissions data were gathered on a normally aspirated single cylinder DI engine with various combinations of ceramic coatings installed. Thin ceramic thermal barrier coatings were applied to the piston crown and bowl, the head and valves, and the cylinder liner. The coated piston and head were run singly and in combination with the cylinder liner to investigate the effects of these different coated surfaces on emissions and performance. Coating the piston crown alone results in generally lower cylinder pressure, lower brake specific fuel consumption and lower NO(x) emission compared to the baseline engine. Soot emission is typically increased below 2000 RPM and decreased above 2000 RPM. Coating the head alone reduces cylinder pressure, but generally increases specific fuel consumption and NO(x) and soot emission. The KIVA-II code was used to model ...

International Nuclear Information System (INIS)

Jun 1973. 2 p. United States USAEC Directorate of Regulatory Standards,

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Aluminium AA5182 coupons covered by a polyaniline film in the emeraldine base (EB) form showed increasing corrosion potential and decreasing corrosion current as a function of the thickness of the polymer layer. The cathodic reaction was proved not limited by diffusion of species inside the electrolyte solution and oxygen had no effect on the electrochemical behaviour of the coated samples. An EB coating on indium tin oxide conducting layer appeared slightly electroactive in neutral media. The IR spectra of aluminium coated samples, before and after heating in argon atmosphere, confirmed a redox reaction between the polymer film and the metal. This galvanic coupling can explain the good protective behaviour of emeraldine base against corrosion of aluminium.

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The mechanical stability of diamond-like carbon (DLC) films coated on nitinol vascular stents was investigated under cyclic loading condition by employing a stent crimping system. DLC films were coated on the vascular stent of a three dimensional structure by using a hybrid ion beam system with rotating jig. The cracking or delamination of the DLC coating occurred dominantly near the hinge connecting the V-shaped segments of the stent where the maximum strain was induced by a cyclic loading of contraction and extension. However the failures were significantly suppressed as the amorphous Si (a-Si) buffer layer thickness increased. Interfacial adhesion strength was estimated from the spalled crack size in the DLC coating for various values of the a-Si buffer layer thickness.

UK PubMed Central (United Kingdom)

• Background and Aims The occurrence of stomata in seed coats is uncommon and there is limited information about their function(s). The aim of this study was to verify the distribution...Full Text Available

British Library Electronic Table of Contents (United Kingdom)

Polymer-coated magnetic nanoparticles (MNPs) have been prepared and used as an immobilization matrix for the fabrication of solid-state tris(2,2prime-bipyridyl)ruthenium(II) (Ru(bpy)32+) electrogenerated chemiluminescence (ECL) sensor. The pre-synthesized maghemite (g-Fe2O3) MNPs were coated with poly(3-thiopheneacetic acid) based on an oxidative polymerization method using KMnO4. The poly(3-thiopheneacetic acid)-coated MNPs have formed the clusters with average diameter of 200-500nm. The multilayer films of poly(3-thiopheneacetic acid)-coated MNPs were uniformly formed on the surface of a Pt electrode by an external magnet. The Ru(bpy)32+ was rapidly incorporated into the multilayer films within 5min through the electrostatic interaction between the Ru(bpy)32+ and the negatively charged c...

British Library Electronic Table of Contents (United Kingdom)

A test bench was designed and assembled to carry out impact tests on samples and components. The system allows simple and rapid adjustment of the test parameters, such as the shot size and air pressure, with good repeatability of the results. Tests on steel and light alloys were carried out under both as-produced condition and on thin hard-coated samples. Significant reductions in dimple dimensions were seen after coating. FE models simulating the experiments overestimated the dimple depths, although the parameter trend was satisfactorily captured. The residual stresses from coating and shot peening determined numerically are believed to have been proven effective against fatigue.

British Library Electronic Table of Contents (United Kingdom)

Fluorocarbon polymers are used to enhance thermal stability and electrostatic protection of composite propellant compositions. A precipitation technique has been developed to coat ammonium perchlorate (AP) using a copolymer of hexafluoropropylene and vinylidene fluoride (HFP-VF) with the help of solvent-counter solvent method. The coated AP has been used to prepare propellant compositions in different ratio based on hydroxyl terminated polybutadiene (HTPB), aluminium powder along with uncoated AP and studied for viscosity build-up and visco-elastic behaviour as well as mechanical, ballistic, thermal and sensitivity properties keeping 86% solid loading. The data on viscosity build-up indicate that as the percentage of viton coated AP increases end of mix viscosity and viscosity build-up inc...

British Library Electronic Table of Contents (United Kingdom)

Amino-rich polymeric coatings are widely used in biomedical applications, since they promote adsorption of diverse biomolecules or facilitate cell growth. As a consequence, there is a growing interest in fabrication of such coatings that is focused predominantly on the optimization of the deposition process in terms of high density of primary amino groups. In addition, the nature of biomedical applications requires also sufficient stability of the films in aqueous environments. This aspect is investigated in this contribution. In particular, the effect of water and phosphate buffer saline on the coatings prepared by RF magnetron sputtering of Nylon 6,6 in Ar/N2 and N2/H2 gas mixtures is evaluated. The samples exposed to liquids are characterized by various diagnostic methods and their prop...

International Nuclear Information System (INIS)

In the present study, surfaces of cylinder head, piston, exhaust and inlet valve of a four-stroke, direct injection, single cylinder diesel engine were coated with molybdenum (Mo) by plasma spray method. Thus, thermal barrier characteristic was brought to these parts. Variances in performance and emission values of cotton methyl ester and 2D fuel mixtures were studied in the ceramic coated and uncoated engines under the same running conditions. Performance (6.0% for specific fuel consumption) and emission values (up to 18.0% for CO, 8.0% for smoke density) of the test fuel were improved in the coated engine compared with the uncoated engine. NO_x increase (4.5%) with the increased temperatures expected in the coated engine.

UK PubMed Central (United Kingdom)

Peri-prosthetic infections are notoriously difficult to treat as the biomaterial implant is ideal for bacterial adhesion and biofilm formation, resulting in decreased antibiotic sensitivity....Full Text Available

Science.gov (United States)

This study deals with the torsional response of Ti-8823 and 18Ni (200) maraging steel. The effect of different heat treatments and the subsequent change in microstructure are investigated. In the case of the Ti-8823, a comparison was made between the solu...

Science.gov (United States)

The corrosion behavior of Ta, Ti, and Zr in inorganic acids, bases, chlorides and miscellaneous salts, waters and gases, and organic acids and miscellaneous organic chemicals is summarized. (W.L.H)

International Nuclear Information System (INIS)

Ti-15Mo-2.7Nb-3Al-0.2Si (Timetal-21S), a metastable #beta#-titanium alloy, is a candidate material for titanium matrix composite structures in hydrogen-fueled hypersonic planes because of its excellent formability and adequate mechanical properties in the 500--800 C temperature range. The alloy is strengthened through the precipitation of fine #alpha# particles in the #beta# matrix. The mechanical properties and microstructures are controlled by a solutionizing/aging heat treatment. A major concern in using titanium alloys in hydrogen service is the embrittlement caused by the precipitation of hydrides. It is believed that the large solubility of hydrogen in the #beta#-phase would preclude the precipitation of hydrides in Beta titanium alloys, especially at low hydrogen pressures. However, depending on the hydrogen content, a shift in the ductile/brittle transition temperatures to levels much higher ...

International Nuclear Information System (INIS)

Three types of titanium hydrides have been reported: #delta#, #epsilon# and #gamma# hydrides. The #delta# hydride forms in the composition range from TiH/sub 1.5/ to TiH/sub 1.99/ and has a CaF/sub 2/ structure with metal atoms on an fcc lattice and hydrogen atoms randomly occupying tetrahedral interstitial sites. At higher hydrogen concentrations, TiH/sub 2/, the fct (c/a # #epsilon# transformation is apparently diffusionless, similar to that operating in the cubic/tetragonal transformation in zirconium hydride. The metastable fct #gamma# hydride having a c/a value of 1.09 or 1.12 forms from solid solutions of hydrogen in the hcp #alpha# matrix. While the titanium hydride precipitation in #alpha#-Ti and its alloys has attracted extensive investigation, hydride formation in bcc #beta#-Ti alloys has rarely been studied because they have not been thought to be liable to hydride formation. This paper shows conclusive evidence for the fcc #delta# ...

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The development of structural barriers for nuclear waste packages involves selection of candidate materials, their screening by mechanical and corrosion testing, rigorous accelerated testing, and evaluation and comparison with other package elements. This document presents results from work conducted on titanium and ferrous alloys.

Science.gov (United States)

Wood, R. A.; and Ogden, H. R.: The All-Beta Titanium Alloy (Ti-13V-llCr-3Al). DMIC Rept. 110 (ASTIA AD 214002), Battelle Mem. Inst., Apr. 17, 1959. 22. White ...

International Nuclear Information System (INIS)

The tool materials durability problem, in particular shock and wear resistance, has allowed to formulate a set of requirements and also to stablish the dependence between physical properties and wear. However, for understanding the nature of the process, for example determining the tribological property of the cutting tool, it is necessary to consider the atom interactions in a crystal. A theoretical study of the physical properties of cutting tool materials (W-Ti-C) with varying concentration of titanium is presented. Total and partial local electronic density for each atom in such hard solutions were calculated. (nevyjel)

International Nuclear Information System (INIS)

Strain rate effects for the high strength, metastable beta-titanium alloy Ti-8Mo-8V-2Fe-3Al are assessed in terms of tensile and fracture toughness behavior. It is shown that as the strain rate increases the yield strength, ultimate tensile strength, and ductility also increase. As a result of the decrease in the amount of intergranular fracture as the strain rate is increased, the dynamic fracture toughness values K/sub Id/ are greater than those obtained under static conditions as given by K/sub Q/.

International Nuclear Information System (INIS)

We demonstrate reversible movement of (1/2)[110](110) dislocation loops generated from nanodisturbances in a #beta#-titanium alloy. High resolution transmission electron microscope observations during an in situ tensile test found three reversible deformation mechanisms, nanodisturbances, dislocation loops and martensitic transformation, that are triggered in turn with increasing applied stress. All three mechanisms contribute to the nonlinear elasticity of the alloy. The experiments also revealed the evolution of the dislocation loops to disclination dipoles that cause severe local lattice rotations.

International Nuclear Information System (INIS)

Production of titanium alloys from the mixture containing large amounts of metallurgy wastes is very promising. It is shown that unlimited possibilities of the waste material use in the mixture (up to 100%) are provided by garnissage melting, the size of the cast being limited only by that of the vessel. With garnissage being used as a consumed electrode the metal is refined from hydrogen and the blank ingots to serve as consumed electrodes in electro-slag remelting are chemically homogeneous. The ingots thus obtained have dense structure, rather fine grain homogeneous chemical composition, are no less pure than those obtained by vacuum arc remelting and provide for economic savings.

International Nuclear Information System (INIS)

Studied are the mechanical properties of welded joints and heat affected zones of the Kh8N10T steel and OT4 and VT1-2 titanium alloys on welding in Ar+deltaF_6 and Ar+CCl_2F_2 mixtures contributed to a decrease of porosity. Tensile and impact tests of welded joints have revealed that additions of sulfur hexafluoride into argon causes a decrease of impact strength in titanium alloy when the tensile strength does not depend on the composition of a halogen-containing atmosphere. Freon (CCl_2F_2) additions decrease only slightly the impact strength of the investigated alloys.

International Nuclear Information System (INIS)

Formation of basis type texture at rolling of Ti + 6.0% Al + 1.5% V + 1.0% Mo system alloy with initial prismatic texture is investigated by means of X-ray techniques. Variations of mechanical features in titanium alloy sheets depending on temperature-deformation conditions of rolling are investigated. Main conditions for formation of the intensive basis textute in the investigated alloy sheets which provides for isotropic properties in sheet plane and for increased ductility are determined.

Energy Technology Data Exchange (ETDEWEB)

Micron-size Ni-base alloy (NBA) powders were mixed with both 1.5 wt.% (hereinafter %) micron-size CeO{sub 2} (m-CeO{sub 2}) and also 1.5% and 3.0% nano-size CeO{sub 2} (n- CeO{sub 2}) powders. These mixtures were coated on low-carbon steel (Q235) by 2.0 kW CO{sub 2} laser cladding. The effects on the microstructures, phases and electrochemical corrosion of the coatings upon the addition of m- and n- CeO{sub 2} powders to NBA (m- and n- CeO{sub 2} /NBA) have been investigated. The results showed that a smooth coating was prepared under suitable processing parameters (P= 2.0 kW, V= 180 mm min{sup -1}) by adding 1.5% n- CeO{sub 2}. In addition to the primary phases of {gamma}-Ni, Cr{sub 23} C{sub 6} and Ni{sub 3} B in the Ni-base alloy coating, CeNi{sub 3} was formed in Ni-base alloy coatings with both n- CeO{sub 2} and m-CeO{sub 2} particles, and CeNi{sub 5} appeared in the ...

International Nuclear Information System (INIS)

The temperature dependences of the heat capacity of commercial titanium VT1-0 and alloys on its base, VT5 and VT5-1, have been derived in the temperature range of 4 to 290 K. For comparison, similar measurements have been conducted on pure titanium and specially prepared solid solutions on its base (Ti+3.7 at.% Al and Ti+0.82 at.% Sn). The measurement accuracy has been sufficient for comparing the results with calculation data. The obtained results are interpreted using the known concepts of the role of the mass of interstitial atoms and changes in the interatomic bond forces. It is shown that the phonon components of the molar heat capacities of solid solutions of Al in titanium have lower values in the entire temperature range, as compared to titanium. The corresponding differences are proportional to the Al concentrations. The lower molar heat capacity in the case of dissolution of Al is due to the ...

Energy Technology Data Exchange (ETDEWEB)

PVD-coatings based on TiB{sub 2} are expected to show high wear resistance and low tendency of adhesion on metal forming tools. Coating adhesion and morphology can be modified over a wide range by varying the content of nitrogen (N{sub 2}) and the deposition parameters power and bias voltage. All coatings were deposited using commercial unbalanced magnetron equipment, the deposition was homogeneous in a volume of 400 x 400 x 400 mm{sup 3}. Hipped and hot pressed TiB{sub 2}-targets were used, nitrogen (N{sub 2}) was added as gas, Ti and Al by a solid Ti-Al-target. The tribological behaviour was tested by a pin-on-disc wear test. The coatings investigated were TiB{sub 2}, TiAlB(N), TiAl(N) and TiB{sub 2}/TiAl(N). As counterpart in the pin-on-disc wear test, 6 mm diameter spheres of steel (100Cr6), aluminium, brass and bronze were used. The experiments showed a non-uniform wear behaviour. For the ...

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This Test Plan outlines the testing to be done on the Special Protective Coating (SPC) Polyurea which includes: Tank Waste Compatibility, Decontamination Factor Testing, and Adhesion Strength Testing after a sample has been exposed to Radiation.

International Nuclear Information System (INIS)

The effectiveness of an acrylic latex wall sealant in limiting the escape of radon from rock in underground mines is the subject of this paper. Application of the latex as a two-coat system over a fillter coat of gunite produced a reduction of radon concentration from an initial level of 80 to 100 pCi/L to a final average of 25 to 30 pCi/L under similar conditions.

Energy Technology Data Exchange (ETDEWEB)

Four subprojects were completed: development and evaluation of die coatings, accelerated die life characterization of die materials, evaluation of fluid flow and solidification modeling programs, selection and characterization of Al-based die casting alloys, and influence of die materials and coatings on die casting quality.

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This heat exchanger is a critical step in the development of the Externally Fired Combined Cycle power system, a direct-coal combustion power plant (gas turbine). SiC is the only material with the needed resistance to creep, thermal shock, and oxidation; however a protective coating is needed. Ten candidate materials were identified: alumina-based materials, materials stable with SiO, and low expansion materials. An initial screening study should be performed.

Energy Technology Data Exchange (ETDEWEB)

Chromium nitride/Cr coating has been deposited on surface of 316L stainless steel to improve conductivity and corrosion resistance by physical vapor deposition (PVD) technology. Electrochemical behaviors of the chromium nitride/Cr coated 316L stainless steel are investigated in 0.05 M H{sub 2}SO{sub 4}+2 ppm F{sup -} simulating proton exchange membrane fuel cell (PEMFC) environments, and interfacial contact resistance (ICR) are measured before and after potentiostatic polarization at anodic and cathodic operation potentials for PEMFC. The chromium nitride/Cr coated 316L stainless steel exhibits improved corrosion resistance and better stability of passive film either in the simulated anodic or cathodic environment. In comparison to 316L stainless steel with air-formed oxide film, the ICR between the chromium nitride/Cr coated 316L stainless steel and carbon paper is about 30 m{omega} cm{sup 2} that is ...

Energy Technology Data Exchange (ETDEWEB)

The dispersion of more than 20 vol pct submicrometer ceramic particles within a metallic matrix and the deposition of such a cermet to form a thick and tough coating presents problems. Most of the coating techniques have failed in attempting to homogeneously disperse very fine and hard particles in large amounts while avoiding their decomposition or reaction with the metal matrix during the deposition process. A simple and efficient method has been developed for producing ceramic-containing composite coatings. It consists in synthesizing cermet-based materials and in depositing them by a rapid solidification process, such as thermal spraying. Boride- and carbide-based materials have been successfully obtained by plasma spraying reactive powders comprising the basic reagents. These materials, with a microstructure of submicrometer ceramic particles dispersed in a metallic matrix, exhibit good wear-resistant properties ...

International Nuclear Information System (INIS)

There has been a growing interest in new laser systems for use at mid-infra-red wavelengths, driven by requirements for a number of diverse applications. Developments in mid-IR coating technology are following three major thrusts. In the first, the potential of ion-assisted process is being exploited and the technology is already becoming well established in the optical coating industry. In the second, the benefits of using gas-phase precursors are being explored, driven by the potential of avoiding the generation of second phase inclusion in the coatings with associated reduction in laser damage threshold. Research is also addressing the use of nanocomposite materials with an engineered microstructure to produce coatings with dielectric properties of choice. This paper presents a review of progress in some of these areas with special emphasis on the comparison of the properties of materials at DF laser ...

International Nuclear Information System (INIS)

This paper presents the first results on formation and study of structure and properties of micro- and nanocomposite combined coatings. By means of modeling the deposition processes (deposition conditions, current density-discharge, plasma composition and density, voltage) we formed the three-layer nanocomposite coatings of Ti-Al-N/Ti-N/Al_2O_3. The coating composition, structure and properties were studied using physical and nuclear-physical methods. The Rutherford proton and helium ion backscattering, scanning electron microscopy with microanalysis, grazing incidence X-ray diffraction, as well as nanohardness tests (hardness) were used. Measurements of wear resistance and corrosion resistance in NaCl, HCl and H_2SO_4 solutions were also performed. For testing mechanical properties such characteristics of layered structures as hardness H, elastic modulus E: H"3/E"2 etc. were measured. It is demonstrated that the formed ...

CERN Document Server

Non-evaporable thin film getters of various compositions have been produced by sputtering. Among about 20 materials which have been studied, the lowest activation temperature (about 180 degree C) has been displayed by a Ti-Zr-V coating obtained from a cathode made of intertwisted elemental wires. In order to optimize the vacuum properties of this film various production parameters, including the substrate temperature during coating, have been varied. The films have been characterized by pumping speed measurement, secondary electron microscopy, and X-ray diffraction. It has been found that the substrate coating temperature affects significantly the activation temperature, the pumping speed and the gas surface capacity. The highest pumping speed values, obtained for substrate coating temperatures of 250 degree C and 300 degree C, are clearly correlated with the increased surface roughness and porosity of ...