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In order to obtain the electronic structure of leucine (Leu) in aqueous solution, we studied three systems: Leu+7H2O, Leu+8H2O and Leu+9H2O. The results indicated that the system Leu+8H2O was the only choice which was both acceptable and doable: its computational effort was affordable, and it could simulate a main part of the solvent effect on the electronic structure of Leu in solution. Based on the system Leu+8H2O, all-electron, ab initio calculations were performed to construct an equivalent potential of water for the electronic structure of Leu with dipoles. The results showed that the main effect of water on ...

British Library Electronic Table of Contents (United Kingdom)

The effect of a series of complexing and reducing agents on the extraction-chemical behavior of technetium as applied to extraction splitting of uranium and plutonium in the Purex process was examined. Kinetic parameters of the catalytic decomposition of N2H5NO3 under the action of Tc in the presence of these agents were evaluated. Variation of the ratio of the oxidized and reduced Tc species in the course of the process and in the hydrazine-free systems was determined. Reagents preventing oxidation of the reduced technetium and decomposition of N2H5NO3 in nitric acid solutions (acetohydroxamic acid, hydroxylamine, ascorbic acid, etc.), inhibiting the reduction of Tc with hydrazine nitrate (H2O2, HN3, etc.), and known as complexing agents toward quadrivalent actinides but indifferent to Tc...

International Nuclear Information System (INIS)

The systems CH_3COHNC_6H_4CH_3-HI-H_2O, CH_3CONHC_6H_4CH_3-HIO_3-H_2O, CH_3CONHC_6H_4CH_3-H_5IO_6-H_2O have been studied by the solubility method. It has been ascertained that the systems containing periodic and iodic acids are referred to systems of simple eutonic type. Formation of compound of o-methylacetanilide with iodic acid of equimolecular composition has been proved. Concentrational boundaries of its existence in solutions have been established, its certain physicochemical characteristics being determined.

International Nuclear Information System (INIS)

Crystallization points of aqueous solution of the systems M(ClO_4)_2-H_2O (M"2 = Mg"2"+, Ca"2"+, Sr"2"+, Ba"2"+), depending on the salt concentration, were identified by visual-polythermal method. Relying on model notions on the structure of the electrolyte solutions, specific features of strontium perchlorate solubility polytherm and concentration dependence of the relative dynamic viscosity of the salt aqueous solutions are discussed

British Library Electronic Table of Contents (United Kingdom)

A method for range-resolved gas sensing using path-integrated optical systems is presented. The method involves dividing an absorption path into several measurement segments and extracting the gas concentration in each segment from two path-integrated measurements. We implemented the method with tunable lasers (a 1389-nm VCSEL and a 10.9-?m pulsed quantum cascade laser) and a group of retro reflectors (RRs) distributed along absorption paths. Using a rotating mirror with the VCSEL configuration, we could scan a group of seven tape RRs spaced by 10?cm in ??9?ms to extract an H2O concentration profile. Reduced H2O concentrations were recorded in the segments purged with dry air. Hollow corner cube RRs were used in the quantum cascade laser configuration at distances up to 1.1?km from the las...

International Nuclear Information System (INIS)

In a sufficiently large cluster of several polar molecules, collective interactions lead to localization or 'solvation' of electrons. The existence of the solvated electron is known since 1863 in liquid ammonia and since 1962 for liquid water. In 1984, electron localization in clusters was experimentally demonstrated in (H_2O)_N_#>=#_1_1 and (NH_3)_N_#>=#_3_4 clusters. In cooperation with K. Bowen, we recently initiated a test of the theory of electron binding by a dipole and a new ground state dipole bound dimer anion, (H_2O..NH_3), was predicted and observed. We here describe results of a search for new dipole-bound and solvated electron systems. (author).

International Nuclear Information System (INIS)

Equivalent circuit and electrical parameters for H-doped NH_4UO_2PO_4.3H_2O self supported membranes have been determined by impedance spectroscopy. The measurements were carried out with a dry membrane, at different temperatures, and a wet membrane in contact with different electrolyte solutions. Resistance values for the dry membrane decrease with temperature increase, which agrees with the weak protonic character of the H-doped ammonium uranylphosphate. On the other hand, differences in the electrical parameters, depending on the electrolyte considered were also obtained and are attributed to different conduction mechanisms. (Author).

International Nuclear Information System (INIS)

The pozzolanic behaviour of compound-activated red mud-coal gangue has been investigated through TG, DTA, XRD, FTIR and 27Al MAS NMR. From viewpoint of reaction kinetics, it is found that the pozzolanic reaction mechanism of the compound-activated red mud-coal gangue - lime system is clearly consistent with diffusion control up to 14 days, and the reaction rate constant calculated from Jander equation decreases with the increase of CaO addition in the system. The hydration products formed in the red mud-coal gangue - lime systems at ambient temperature are essentially aluminous C-S-H and Ca3Al2O6.xH2O. From TG analysis results, it is thought that the high amount of Ca(OH)2 in the pastes of studied system is not conducive to the continual increase of non-evaporable water content of the hydration products. Of particular interest, 27Al MAS NMR ...

International Nuclear Information System (INIS)

Influence of alkali elements on formation, composition, solubility and region of stability of complex hafnium sulfates, separated in the HfO"2-H"2SO"4-Me"2SO"4-H"2O (Me-Na, K, Rb, Cs and NH"4 group) systems is studied. In all cases hafnium forms the complex sulfates of three types differing by basicity or ratio HfO"2:SO"3 1:1, 1:1.5, 1:2. Three basic and three medium sulfates are crystallized in the systems with sodium; with rubidium, cesium and ammonium - two basic and two medium sulfates and with potassium - two basic and one medium salts. Anhydrous salts do not form in the investigated systems. Potassium salt approximately 0.3% according to HfO"2 is characterized by minimum solubility from the salts of 2HfOSO"4x(1-3)Me"2SO"4x(4-6)xH"2O while solubility of the same salts with rubidium, cesium and ...

International Nuclear Information System (INIS)

Molar extinction coefficients for the solid solutes in aqueous solutions of some alkaline earth chlorides such as MgCl_2.6H_2O, CaCl_2, SrCl_2.6H_2O and BaCl_2.2H_2O have been determined at 81, 356, 511, 662, 1173 and 1332 keV energies in different concentration using the narrow beam transmission methods. (author)

British Library Electronic Table of Contents (United Kingdom)

In this article, we present our consistent efforts to explore the dynamical pathways of the migration of electronic radiation by using ultrafast (picosecond/femtosecond time scales) F?rster resonance energy transfer (FRET) technique. The ultrafast non-radiative energy migration from an intrinsic donor fluorophore (Tryptophan, Trp214) present in domain IIA of a transporter protein human serum albumin (HSA) to various non-covalently/covalently attached organic/inorganic chromophores including photoporphyrin IX (PPIX), polyoxovanadate [V15As6O42(H2O)]-6 clusters (denoted as V15) and CdS quantum dots (QDs) has been explored. We have also used other covalently/non-covalently attached extrinsic fluorogenic donors (NPA, ANS) in order to exploit the dynamics of resonance energy migration of an enz...

International Nuclear Information System (INIS)

The electrochemical treatment of solutions containing C.I. Basic Yellow 2 (BY2) in aqueous solutions with carbon-PTFE (polytetrafluoroethylene) and carbon nanotube (CNT)-PTFE electrodes as cathode has been studied. The fabricated electrodes were characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The amount of electrogenerated H2O2 on the surface of these electrodes was investigated, too. The results showed that the amount of H2O2 obtained with the CNT-PTFE electrode was nearly three times higher than that of carbon-PTFE electrode. The decolorization efficiency of BY2 in peroxi-coagulation process reached 62% and 96% in the first 10 min by carbon-PTFE and CNT-PTFE electrodes at 100 mA, respectively. The effect of operational parameters such as applied current, initial pH and initial dye concentration was ...

International Nuclear Information System (INIS)

A study was made on complex formation of thiosemicarbazide diacetic acid (H_2L) with neodymium (3), holmium (3) and erbium (3) in solutions and formation of complexes of metal: ligand=4:1 composition was revealed. Synthesis conditions were developed and products of LnLClxnH_2O, LnLOHxnH_2O, Na[LnL_2]xnH_2O composition were separated in crystalline state. It was shown, that H_2L behaves in these compounds as tripod ligand with O, O, N, N donor atoms.

Energy Technology Data Exchange (ETDEWEB)

A class II atomistic force field with Lennard-Jones 6-9 nonbond interactions is used to investigate equations of state (EOS) for important high explosive detonation products N{sub 2} and H{sub 2}O in the temperature range 700-2500 K and pressure range 0.1-10 GPa. A standard 6th order parameter-mixing scheme is then employed to study a 2:1 (molar) H{sub 2}O:N{sub 2} mixture, to investigate in particular the possibility of phase-separation under detonation conditions. The simulations demonstrate several important results, including: (1) the accuracy of computed EOS for both N{sub 2} and H{sub 2}O over the entire range of temperature and pressure considered; (2) accurate mixing-demixing phase boundary as compared to experimental data; and (3) the departure of mixing free energy from that predicted by ideal mixing law. The results provide comparison and guidance to state-of-the-art chemical kinetic models.

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One salt and two Cu(II) complexes (H2hsm)(ox), 1, [Cu(hsm)(ox)], 2, and [Cu(hsm)(ox)H2O], 3, have been synthesized and X-ray characterized (hsm is histamine and ox2? is the oxalate dianion). Starting from the prochiral tetracoordinated complex 2, pentacoordinated complex 3 crystallizes as a racemic mixture of the enantiomeric ? and ? isomers, in space group P21/c. In all cases, the side chain of the hsm group is gauche, allowing the formation of strong hydrogen bonds in the salt 1, and to chelate the metal center in complexes 2 and 3. The combination hsm/ox seems to favor the formation of 2D supramolecular structures (planes or wavy planes), through efficient networks of N?H???O hydrogen bonds. Cell parameters: 1, P21/c, a?=?6.260 (2) ?, b?=?11.500 (4) ?, c?=?12.525 (4) ?, ??=?104.047 (17)...

British Library Electronic Table of Contents (United Kingdom)

Solar syngas production from CO"2 and H"2O is considered in a two-step thermochemical cycle via Zn/ZnO redox reactions, encompassing: 1) the ZnO thermolysis to Zn and O"2 using concentrated solar radiation as the source of process heat, and 2) Zn reacting with mixtures of H"2O and CO"2 yielding high-quality syngas (mainly H"2 and CO) and ZnO; the ZnO is recycled to the first, solar step, resulting in net reaction @bCO"2 + (1 - @b)H"2O -> @bCO + (1 - @b)H"2. Syngas is further processed to liquid hydrocarbon fuels via Fischer-Tropsch or other catalytic processes. Second-law thermodynamic analysis is applied to determine the cycle efficiencies attainable with and without heat recuperation for varying molar fractions of CO"2:H"2O and solar ...

International Nuclear Information System (INIS)

The search for alternative energy supplies continues since the oil crisis of 1973. One energy vector is dihydrogen, H_2. Of the group VI hydrides, water has been the focus of most studies in harnessing solar energy and generating H_2. Two basic photochemical strategies have been employed: molecular photocatalytic systems, and semiconductor based photocatalytic systems. The results have not met with the euphoric expectations of the mid-1970's because of the difficulties encountered in H_2O splitting (E"0 S"2 "-/S = + 0.51 eV, NHE) is another vehicle tapped as a potential source of H_2. Heterogeneous photocatalysis utilizing semiconductor particulates and sunlight as the photon source has been successful with interesting quantum efficiencies. To this end, novel photocatalytic devices have been developed; one of these uses two coupled semiconductors to achieve vectorial displacement of ...

Energy Technology Data Exchange (ETDEWEB)

The sequential layer-by-layer adsorption of polyanions and polycations to build polyelectrolyte multilayers has triggered enormous interest in their potential uses in a wide range of fields, from photonic to pharmaceutical applications. We show that the conformation of the solvent swollen films - prior to drying - is determined by the initial adsorption conditions, but can be altered ex-situ by exposure to a liquid phase of very high ionic strength. Recently it has been observed that the swelling depends on the charge of the outermost layer. In the PAH/PSS system we saw that assemblies with PSS as the outermost layer swell more than those with PAH outside. A neutron reflectivity study of this effect in addition indicated the existence of two kinds of water, bound with different strength within the films. Beside an unexpected two-step kinetics of swelling, the reflectivity curves of the layers against vacuum before and after re-hydration in D{sub 2}O vapor did not ...

International Nuclear Information System (INIS)

High general corrosion resistance of high-alloy OCTG (oil country tubular goods) to CO_2 may be limited by pitting corrosion in presence of chlorides and sulfides. The pitting resistance of 13% Cr steel, duplex and high Ni austenitic stainless steels have been examined by electrochemical measurements in a high temperature, high pressure autoclave simulating the well conditions. Each steel shows the pitting potential in CO_2-NaCl-H_2O system, the value of which being less noble as the Cl"- concentration and the temperature increase. The presence of H_2S is also detrimental. High alloying additions of Cr and Mo enhance pitting resistance whether or not H_2S is present. The corrosion potentials of these steels in the simulating well conditions in which oxygen is absent do not exceed the pitting potential. Therefore, pitting corrosion can not occur by the passivity break through mechanism.

Science.gov (United States)

The visible absorption spectra of 1,4-(dihydroxy)-9,10-anthraquinone and of Co(II), Ni(II), Cu(II) and Zn(II) chelates have been studied in different organic solvents. This system provides a model for the anthracycline antibiotics and their metal chelates. The band structure of the spectrum has been determined using the second and fourth derivatives of the spectrum. The visible absorption band of the parent molecule can be assigned to a single electronic state with a reduced dipole moment in the excited state; structure in this band is ascribed to two overlapping vibrational progressions. In contrast, the dianion (hydroxy protons removed) shows a single electronic state with an increased dipole moment in the excited state; structure in this band can be assigned to a single vibrational progression. All of the metal chelates show spectra which are similar in appearance to that of the dianion although the identity of the metal determines the bathochromic shift of the ...

British Library Electronic Table of Contents (United Kingdom)

l-Carnitine is a critical metabolite indispensable for the metabolism of lipids as it facilitates fatty acid transport into the mitochondrion where b-oxidation occurs. Human astrocytes (CCF-STTG1 cells) and hepatocytes (HepG2 cells) exposed to aluminum (Al) and hydrogen peroxide (H2O2), were characterized with lower levels of l-carnitine, diminished b-oxidation, and increased lipid accumulation compared to the controls. g-Butyrobetainealdehyde dehydrogenase (BADH) and butyrobetaine dioxygenase (BBDOX), two key enzymes mediating the biogenesis of l-carnitine, were sharply reduced during Al and H2O2 challenge. Exposure of the Al and H2O2-treated cells to a-ketoglutarate (KG), led to the recovery of l-carnitine production with the concomitant reduction in ROS levels. It appears that the chann...

International Nuclear Information System (INIS)

The Advanced MAPLE is a research reactor design under development as a high-flux neutron source. The main performance goals for the reactor are a high peak thermal neutron flux in a heavy-water reflector tank, and a high average fast neutron flux in a central irradiation facility, with a maximum linear fuel rod rating of less than 120 kW/m. This study investigated the neutronic and reactor design consequences of the use of H_2O coolant as opposed to D_2O. The neutronics results, and several other considerations, indicate that H_2O coolant has a number of advantages. It is suggested that the H_2O coolant option be considered in the design of the Advanced MAPLE reactor. (L.L.) 9 refs., 4 figs., tab.

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A mechanism is proposed for the previously observed [1] jump in erythrocyte fluidity through a microcapillary 1.3 ?m in diameter at a temperature of 36.6?0.3?C. Our interpretation is based on the experimental evidence both for existence of ortho and para H2O isomers in water and on spin-selective interaction of proteins with para H2O isomers as hydration shells of biomolecules are being formed [2]. It is important that the formation of hydration shells of proteins and DNA in aqueous solutions is accompanied by an increase in the Brillouin shift to 0.4 cm?1 (?0.25 cm?1 in water), which points to the formation of icelike structures. We believe that the coincidence of the translational energy kT of the Brownian motion and the energy of the rotational quanta for the 313?202 transition of para ...

UK PubMed Central (United Kingdom)

We describe the characteristics of the rapidly rotating molecular disk in the nucleus of the mildly active galaxy NGC4258. The morphology and kinematics of the disk are delineated by the point-like...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

It was previously reported that the tritium tracer method is useful for the quantitative consideration of hydrogen behavior in coal during coal liquefaction reaction. Tetralin is excellent hydrogen donating solvent, and is considered as one of the model compounds of coal. In this study, effects of H2S and H2O on the hydrogen exchange reaction between tetralin and gaseous hydrogen labeled by tritium were investigated. It was suggested that the conversion of tetralin and the hydrogen exchange reaction between gaseous hydrogen and tetralin proceed through the radical reaction mechanism with a tetralyl radical as an intermediate product. When H2S existed in this reaction, the hydrogen exchange yield increased drastically without changing the conversion yield. This suggested that the hydrogen exchange reaction proceeds even in the reaction where radical does not give any effect. In the case of ...

International Nuclear Information System (INIS)

Six uranyl coordination compounds, UO_2(OH)(PYCA) (1), UO_2(PYCA)_2(H_2O).2H_2O (2), UO_2(PIC)_2 (3), UO_2(H_2O)_2(NIC)_2 (4), UO_2(OH)(HINIC)(INIC) (5), and UO_2(PYTAC)_2(H_2O)_2 (6) were grown as single crystals via hydrothermal synthesis (PYCA - pyrazine-2-carboxylate, PIC - picolinate, NIC - nicotinate, INIC - iso-nicotinate, and PYTAC - 2-(pyridin-4-yl)thiazole-5-carboxylate) to study their optical properties. All six compounds have been identified via single crystal X-ray diffraction and fully characterized via powder X-ray diffraction, infrared spectroscopy, UV-Vis spectroscopy, and fluorescence spectroscopy. Three of the complexes, 1, 3, and 6, represent new structures, and their synthesis and structural characterization is ...

International Nuclear Information System (INIS)

In order to qualify corrosion resistant materials for high level waste (HLW) packagings acting as a long-term barrier in a rock salt repository, the corrosion behaviour of the preselected materials Ti 99.8-Pd, Hastelloy C4 and two unalloyed steels was investigated. The resistance of the materials to general corrosion, local corrosion and stress corrosion cracking was examined under postulated accident conditions in the repository by long-term immersion tests of up to 4 years duration and electrochemical methods. The parameters investigated were different salt brines, temperatures of 90 deg. C, 170 deg. C and 200 deg. C as well as a gamma radiation field of 10"3Gy/h (10"5rad/h). Among the materials studied, Ti 99.8-Pd exhibited the highest corrosion resistance. This material corroded at a very low rate (

International Nuclear Information System (INIS)

The solvent extraction of 12-phosphotungstic acid, also known as 12-tungstophosphoric acid-H_3PW_1_2O_4_0, the so-called Keggin heteropolyacid - by 0.73 M (20%v/v) tri-n-butyl phosphate (TBP) in n-octane under conditions comparable to those used previously for the extraction of conventional inorganic mineral acids is described. A simplified phase diagram for the pentanary system comprised of H_3PW_1_2O_4_0, HNO_3, H_2O, TBP, and n-octane reveals an extremely low initial concentration of H_3PW_1_2O_4_0 (1.1 mM) at the LOC (limiting organic concentration) condition, far lower than the most effective third-phase-forming inorganic acid, namely HClO_4. The results from small-angle neutron scattering (SANS) indicate that the interparticle attraction energy - U(r) calculated through application of the Baxter sticky sphere model to the SANS data at the LOC condition - does not approach the -2 k_B T value ...

British Library Electronic Table of Contents (United Kingdom)

A magnetic core/shell Fe3O4/FeMnOx catalyst was prepared by a simple oxidation-precipitation method. The catalyst was characterized by X-ray diffraction, transmission electron microscope, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, thermogravimetric analysis and cyclic voltammetry. The characterization studies verified that Fe3O4 core was coated with a layer of Fe-Mn oxide. The Fe3O4/FeMnOx was found to be an effective and stable heterogeneous catalyst for the discoloration of methylene blue (MB) in aqueous solution by H2O2. The high catalytic activity is due to the FeMnOx shell, which not only increased the surface hydroxyl groups, but also enhanced the interfacial electron transfer. The discoloration of MB could be due to the decomposition of H2O2 into ?OH ...

Science.gov (United States)

An important advantage of carrying out enzymatic catalysis in organic media is the increased solubility of hydrophobic substrates. This study compares a model lipase catalyzed esterification of cholesterol using vinyl acetate (VA) in two such nontraditional media: high-pressure hexane and supercritical (SCF) ethane. The effect of using one of the reactants (VA) as a cosolvent to increase the solubility of the other reactant (cholesterol) in SCF ethane has been investigated. The thermodynamic activity of water (a(w)) in the reaction media was controlled by the direct addition of the salt hydrate pair Na(4)P(2)O(7)/Na(4)P(2)O(7).10H(2)O. The a(w) of the salt hydrate system is shown to be a function of pressure and its variation over the pressure range 104-173 bar has been estimated. The initial reaction rate in pressurized hexane was found to vary linearly with the cholesterol concentration. The reaction ...

International Nuclear Information System (INIS)

The possibility has been studied of oxidizing Prsup((3)) to Prsup((4)) when Prsup((3)) is added to an aqueous weakly-acid solution containing K_1_0[P_2W_1_7O_6_1H_2O] x H_2O. A sharp change in the solution colouring has been observed as a result of Prsup((3)) oxidation to Prsup((4)). The absorption spectra of solution of Prsup((4)) have been recorded and the values of the molar extinction coefficients have been determined. On storage of the solution, Prsup((4))reduces to Prsup((3)) with a half-reduction period of 0.2-0.5 hour.

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A new strontium metal-organic framework, [Sr2(BTEC)(H2O)4] 2H2O (1) (H4BTEC=benzene-1,2,4,5-tetracarboxylic acid), has been successfully synthesized by mixing the starting reagents. The single-crystal structure analysis showed that compound 1 displayed three-dimensional structures containing inorganic motifs with two-dimensional layers pillar-connected through organic linkers and forming water-coordinated neutral framework. Further studies revealed that compound 1 was insoluble in water and that it emitted strong luminescence at approximately 437nm after dehydration.

UK PubMed Central (United Kingdom)

The application of kinetic probes that allow one to determine relative reactivities of biologically relevant substrates with oxidizing intermediates in the Fenton reagent (H2O2 plus Fe2+ in acidic aqueous...Full Text Available

International Nuclear Information System (INIS)

Four inorganic hydrogen-bonded crystals with second-order nonlinear properties have been discovered: K_4LiH_3(SO_4)_4, Na_2SeO_4#centre dot#H_2SeO_3#centre dot#H_2O, Cs_1_,_5Li_1_,_5H(SO_4)_2 and NH_4HSeO_4. (author)

International Nuclear Information System (INIS)

The rapid corrosion of carbon steels in high temperature, acid chloride solutions is shown to be rate limited by the anodic reaction, 3Fe + 4H_2O = Fe_3O_4 + 8H"+ + 8e"-, based on experiments which find that the corrosion rate in 0.1M NiCl_2 solution has an activation energy of 60 kJ/ mole and is unaffected by adding NaCl or by replacing NiCl_2 with PtCl_4. (author).

International Nuclear Information System (INIS)

Carbon monoxide can be produced in severe accidents from interaction of ex-vessel molten core with concrete. Depending on the particular core-melt scenario, the type of concrete and geometric factors affecting the interaction, the quantities of carbon monoxide produced can vary widely, up to several volume percent in the containment. Carbon monoxide is a combustible gas. The carbon monoxide thus produced is in addition to the hydrogen produced by metal-water reactions and by radiolysis, and represents a possibly significant contribution to the combustible gas inventory in the containment. Assessment of possible accident loads to containment thus requires knowledge of the combustion properties of both CO and H_2 in the containment atmosphere. Extensive studies have been carried out and are still continuing in the nuclear industry to assess the threat of hydrogen in a severe reactor accident. However the contribution of carbon monoxide to the combustion threat has received less ...

Science.gov (United States)

A dialyzable factor(s) in human serum is known to stimulate gonococcal oxygen consumption. Its effect on other human pathogens was investigated. A 10% serum solution increased peak O2 consumption for Escherichia coli and Staphylococcus aureus to 157% (P less than 0.05) and 199% (P less than 0.02), respectively, of their O2 consumption when suspended in Hanks balanced salt solution, compared with a 356% increase for Neisseria gonorrhoeae with serum. Dialyzed serum lacked stimulatory capacity. Bacteria, serum, and neutrophils are often incubated to evaluate neutrophil bactericidal activity. Samples of 10(8) N. gonorrhoeae, S. aureus, and E. coli turned resazurin colorless (anaerobic conditions, Eh less than -42 mV) after 7.4, 13.3, and 15.1 min, respectively. Because neutrophil formation of reactive oxygen intermediates requires ambient O2, the effect of live bacteria and serum on this process was explored. After 5 min of incubation of 10(8) N. gonorrhoeae or S. aureus in 10% normal or ...

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PMID:18472586

British Library Electronic Table of Contents (United Kingdom)

Copper(II) complex coordinated with cyclam-type macrocyclic tetramine, C-meso-1,5,8,12-tetramethyl-1,4,8,11-tetraazacyclotetradecane (2Cdmc) has been synthesized and characterized by single crystal X-ray crystallographic analysis and UV?Vis absorption spectra. Solved molecular structure of [Cu(2Cdmc)(H2O)]Cl2?2H2O (1) revealed that macrocyclic ligand 2Cdmc was in the most stable trans-III structure, but the C-methyl groups of 2Cdmc adopted energetically unfavorable axial configuration (C-axial). This complex 1 is the second example of complex of cyclam-type tetramine with only axially oriented C-methyl groups. This complex adopted five-coordinated square-pyramidal geometry with one water molecule occupying one of the two apical sites. Network of hydrogen bonds involving counter anions (Cl?...

International Nuclear Information System (INIS)

Spectroscopic properties of Er"3"+ : CBS (CdSO_4 + B_2O_3 and R_2SO_4 + CdSO_4 + B_2O_3, R_2SO_4 = Li_2SO_4.H_2O, Na_2SO_4, K_2SO_4 and Gd_2(SO_4)_3.8H_2O) glasses are reported. The assigned energy level data of Er"3"+(4f"1"1) in these glasses are analysed in terms of a parametrized model Hamiltonian. The standard deviations of the data fits are between 39 and 47 cm"-"1 so that the energy level schemes of the Er"3"+(4f"1"1) ions in borosulphate (CBS) glasses are reasonably well reproduced. Radiative properties for the fluorescent levels of Er"3"+ : CBS glasses are determined by using the Judd-Ofelt theory. The potential laser transitions are identified with the help of predicted radiative properties which are compared and discussed with similar results. (author).

DEFF Research Database (Denmark)

It is well established from experiments in premixed, laminar flames, jet-stirred reactors, flow reactors, and batch reactors that SO2 acts to catalyze hydrogen atom removal at stoichiometric and reducing conditions. However, the commonly accepted mechanism for radical removal, SO2 + H(+M) reversible arrow HOSO(+M), HOSO + H/OH reversible arrow SO2 + H-2/H2O, has been challenged by recent theoretical and experimental results. Based on ab initio calculations for key reactions, we update the kinetic model for this chemistry and re-examine the mechanism of fuel/SO2 interactions. We find that the interaction of SO, with the radical pool is more complex than previously assumed, involving HOSO and SO, as well as, at high temperatures also HSO, SH, and S. The revised mechanism with a high rate constant for H + SO2 recombination and with SO + H2O, rather than SO2 + H-2, ...

CERN Document Server

We report on the detection of SiO and water masers toward a newly found bipolar nebula, IRAS 19312+1950. This object exhibits extreme red IRAS color log (F25/F12)=0.5 and log (F60/F25)=0.7 and a nebulosity having a size of about 30" extended to the South-West in the 2MASS near-infrared image. Toward this object, we have detected emission from the H2O 6(1,6)-5(2,3) transition, the SiO J=1-0, v=1 and 2, and J=2-1, v=1 transitions, and the SO 2(2)--1(1) and H13CN J=1-0 transitions. The thermal lines of SO and H13CN are shifted by about 12 km/s in radial velocity with respect to the maser lines, indicating that thermal emission comes from the background molecular cloud. However, the SiO J=2-1, v=2 spectrum shows another component of SiO emission separated by 26 km/s from the main component, that might be formed in a rotating or expanding shell.

International Nuclear Information System (INIS)

This paper reports measurements of absolute differential cross sections for the direct scattering of oxygen atoms by He, Ne, Ar, Kr, Xe, H_2, N_2, O_2, CO, CO_2, H_2O, SO_2, NH_3, CH_4, CF_4, and SF_6 targets. The measured cross sections include contributions from all elastic and inelastic processes that result in a fast neutral oxygen atom product. Cross sections are presented for 0.5- and 1.5-keV projectile energies over the laboratory angular range 0.2 degree endash 5 degree. When compared in the center-of-mass reference frame, these cross sections exhibit a high degree of similarity in both amplitude and angular dependence. The cross sections for N_2, CO, CO_2, and H_2O are inverted using a partial-wave analysis to yield empirical interaction potentials, which can then be used to extrapolate the measurements down to lower energies. Using these potentials, ...

International Nuclear Information System (INIS)

During solvent extraction of At"-, [At(H_2O)_2]"+, AtCl, AtCl_2"- as well as of astatine compounds with higher oxidation states like AtO_n"-, the astatine species are changed into astatine of the oxidation state zero at the phase boundary independent on the organic solvent used. At(O) probably reacts with components of the organic phase or with decomposition products formed by chemical reactions or by radiolysis. The extraction coefficients of the astatine species depend on the experimental conditions applied, the redox potential, and on complex forming reactions or associations, resp., occuring in the aqueous phase. (author).

British Library Electronic Table of Contents (United Kingdom)

Thermal desorption spectroscopy (TDS) was used to study outgassing from polycrystalline SiGe (poly-SiGe), SiC and SiO"2 films used for poly-SiGe-based MEMS thin film vacuum package technology. Primary desorption products were found to be H"2, H"2O and CO"2. The CO"2 outgassing could be correlated with CF"4 plasma interface cleaning used for thick SiGe PECVD, which can leave carbon at the CF"4-plasma-cleaned interface.

International Nuclear Information System (INIS)

Photoluminescence spectra for solutions containing Sm"3"+ isotope ions in heavy and normal water were studied in the wave length #lambda# = 500-700 nm and for absorption spectra and photoluminescence excitation spectra within the range of #lambda# = 260-600 nm. Differences in molar extinction coefficients for "1"4"4Sm"3"+ and "1"5"4Sm"3"+ were established both in the solutions with D_2O and by transition from the solutions with D_2O to the solutions with H_2O. New possible causes of the identified effects are discussed

International Nuclear Information System (INIS)

The radiation properties of the #alpha# emitter "2"1"1At are in favor of its application malignant tumor therapy. As a basis for further investigations the biokinetics of At"-, At x H_2O, At I_2"-, and [At(thio)_2]"+ were determined after i.v. injection into healthy and tumor-bearing mice. The estimation of the ion mobility of the carrier-free compounds allowed the use of uniquely characterized initial compounds. The organ distribution of all species examined was similar to the distribution of astatide. Accumulation was found in the thyroid and other inner organs. (author).

British Library Electronic Table of Contents (United Kingdom)

Four advanced oxidation processes (UV/TiO2, UV/IO4^-, UV/S2O8^2^-, and UV/H2O2) were tested for their ability to mineralize naphthenic acids to inorganic carbon in a model oil sands process water containing high dissolved and suspended solids at pH values ranging from 8 to 12. A medium pressure mercury (Hg) lamp was used, and a Quartz immersion well surrounded the lamp. The treatment goal of 5mg/L naphthenic acids (3.4mg/L total organic carbon (TOC)) was achieved under four conditions: UV/S2O8^2^- (20mM) at pH 8 and 10, and UV/H2O2 (50mM) at pH 8 (all with the Quartz immersion well). Values of electrical energy required to meet the treatment goal were about equal for UV/S2O8^2^- (20mM) and UV/H2O2 (50mM) at pH 8, but three to four times larger for treatment by UV/S2O8^2^- (20mM) at pH 10. ...

International Nuclear Information System (INIS)

1 - Description of program or function: Continuous energy cross-section data library for the Monte Carlo program MCNP based on the ENDF/B-VI Release 3 evaluated nuclear data library (ACE Format). Format: ACE; Number of groups: Continuous energy; Nuclides (107): H-1, H-2, He-4, Li-6, Li-7, Be-9, B-10, B-11, C-nat, N-14, N-15, O-16, O-17, Na-23, Mg-nat, Al-27, Si-nat, Cl-nat, Ti-nat, Cr-50, Cr-52, Cr-53, Cr-54, Mn-55, Fe-54, Fe-56, Fe-57, Fe-58, Co-59, Ni-58, Ni-60, Ni-61, Ni-62, Ni-64, Zr-90, Zr-91, Zr-92, Zr-94, Zr-96, Zr-nat, Nb-93, Mo-94, Mo-95, Mo-96, Mo-97, Mo-nat, Tc-99, Ru-101, Ru-102, Ru-104, Rh-103, Pd-105, Pd-107, Ag-109, I-129, Xe-131, Cs-133, Pr-141, Nd-143, Nd-145, Pm-147, Sm-147, Sm-149, Sm-150, Sm-151, Sm-152, Eu-153, Gd-154, Gd-155, Gd-156, Gd-157, Gd-158, Gd-160, Hf-174, Hf-176, Hf-177, Hf-178, Hf-179, Hf-180, Hf-nat, Pb-206, Pb-207, Pb-208, Bi-209, Th-232,U-233, U-234, U-235, U-236, U-238, Np-237, Pu-238, Pu-239, Pu-240, Pu-241, Pu-242, Am-241, Am-242, Am-242m, Am-243, ...

Science.gov (United States)

... to changes in some of the system parameters by means of figures which show the two standard isotherme and two slightly distorted isotherms. ...

British Library Electronic Table of Contents (United Kingdom)

This paper presents studies carried out on tin-doped indium sulfide films prepared using Chemical Spray Pyrolysis (CSP) technique. Effect of both in-situ and ex-situ doping were analyzed. Ex-situ doping was done by thermal diffusion, which was realized by annealing Sn/In2S3 bilayer films. In-situ doping was accomplished by introducing Sn into the spray solution by using SnCl45H2O. Interestingly, it was noted that by ex-situ doping, conductivity of the sample enhanced considerably without affecting any of the physical properties such as crystallinity or band gap. Analysis also showed that higher percentage of doping resulted in samples with low crystallinity and negative photosensitivity. In-situ doping resulted in amorphous films. In contrast to ex-situ doping, `in- situ doping' resulted i...

International Nuclear Information System (INIS)

Reactions of At(#THETA#)"+, 'At"0.H_2O', AtCl_2"- and AtBr_2 with the pseudohalogenides tricyanomethanide and azide are described. Information on the compound formation of astatine with C(CN)_3"- and N_3"- could be obtained on the basis of electromigration investigations under variation of the conditions (composition of the electrolyte, pH, exchange reactions of ligands). Astatine(I)-tricyanomethanide is classified between AtI_2"- and At(SCN)_2"-. The formation of astatine(I)-azide-compounds is confirmed. Their composition is probably At(N_3)_2"-. There is no dependence of the ion mobility of astatine(I)-azide in the investigated range on azide concentration which is due to its high stability. (author).

British Library Electronic Table of Contents (United Kingdom)

MINER?A is a high resolution, fully active detector designed to study neutrino interactions on nuclei in the NuMI beam at Fermi National Accelerator Laboratory. The active volume of the detector consists of 3 tons of plastic scintillator and includes embedded targets of 4He, C, H2O, Fe and Pb. The MINER?A collaboration expects to perform precision, A-dependent neutrino cross section measurements in the 1?10 GeV region, measure the axial form factor, and study nuclear shadowing of F2, quark-hadron duality and coherent pion production, among other topics. MINER?A began data taking in the fall of 2009. This paper describes the MINER?A experiment and provides an overview of the physics objectives along with estimated uncertainties of the measurements and the tentative projected schedule of dat...

CERN Document Server

An effect of laser-cooling of water was observed for the first time with a temperature decrease dT = -2.2 K after irradiation of liquid water surface by a powerful Ar-Xe pulse laser with a pulse energy of about 1 J and wavelength L = 1.73, 2.63 and 2.65 um. The discovered effect can apparently be ascribed to the optical excitation of vibrational states of H2O molecules followed by an endothermic consolidation of chemically active excited molecules into a quasi-stable cluster-like structure. The measured time dependences of the cooling effect show that a typical life time of the new state of water amounts to hours. It has also been shown that the life time of the excited vibrational molecular states due to a radiation trapping effect can be estimated to at least hundreds of seconds.

International Nuclear Information System (INIS)

The effect of alloying low carbon 18Cr-30Ni steel with silicon (up to 5.1%), copper (up to 5.4%), cobalt (up to 15.3%) on the resistance to corrosion cracking and pitting corrosion, is studied. Tests on uniaxial tension are carried out in 42% MgCl_2 solution and gravimetric studies in 10% FeCl_3x6H_2O. It is established that alloying steel of the Kh18N30 type with silicon increases strength and resistance to corrosion cracking. Copper and cobalt decrease a resistance to pitting corrosion but somewhat increase a resistance to corrosion cracking.

International Nuclear Information System (INIS)

The Monte-Carlo transport code MCNP was used to evaluate possible arrangements of cores for the MIT Reactor using monolithic LEU fuel. Plate and moderator thicknesses were varied, and fixed absorbers and inner reflectors added in an effort to maximize available neutron fluxes at in-core and ex-core locations of experimental facilities. Addition of D_2O in the H_2O moderator was also evaluated. Comparisons of the fast, epithermal, and thermal fluxes were made at selected locations. Keff was also evaluated and critical blade heights compared with the existing HEU core. Results indicate that the LEU fluxes could approach HEU values with the use of a fueled in-core experimental facility, a fixed boron absorber spider and an inner beryllium reflector. (author)

British Library Electronic Table of Contents (United Kingdom)

Direct electrochemistry and electrocatalysis of catalase (Cat) was studied based on a nano-composite film consisting of amine functionalized graphene and gold nanoparticles (AuNPs) modified glassy carbon electrode. Graphene was synthesized chemically by Hummers and Offeman method and then was functionalized with amino groups via chemical modification of carboxyl groups introduced on the graphene surface. The nano-composite film showed an obvious promotion of the direct electron transfer between Cat and the underlying electrode, which attributed to the synergistic effect of graphene-NH2 and AuNPs. The resultant bioelectrode retained its biocatalytic activity and offered fast and sensitive H2O2 quantification. Under the optimized experimental conditions, hydrogen peroxide was detected in the...

British Library Electronic Table of Contents (United Kingdom)

As lithium battery technology sets out to bridge the gap between portable electronics and the electrical automotive industry, cathode materials still stand as the bottleneck regarding performances. In the realm of highly attractive polyanion-type structures as high-voltage cathode materials, the sulfate group (SO4)^2^- possesses an acknowledged superiority over other contenders in terms of open circuit voltage arising from the inductive effect of strong covalent S-O bonds. In parallel, novel lithium insertion mechanisms are providing alternatives to traditional intercalation, enabling reversible multi-electron processes securing high capacities. Combining both of these advantageous features, we report here the successful electrochemical reactivity of copper sulfate pentahydrate (CuSO4.5H2O...

British Library Electronic Table of Contents (United Kingdom)

An electrochemical biosensor for determination of hydrogen peroxide (H2O2) was fabricated, based on the electrostatic immobilization of horseradish peroxidase (HRP) with one-dimensional gold nanowires (Au NWs) and TiO2 nanoparticles (nano-TiO2) on a gold electrode. The nano-TiO2 can give a biocompatible microenvironment and compact film, and the Au NWs can provide fast electron transferring rate and greatly add the amount of HRP molecules immobilized on the electrode surface. Au NWs were characterized by ultraviolet?visible spectra and transmission electron microscope. The electrode modification process was probed by cyclic voltammetry and electrochemical impedance spectroscopy. Chronoamperometry was used to study the electrochemical performance of the resulting biosensor. Under optimal co...

British Library Electronic Table of Contents (United Kingdom)

The monoanionic bidentate Schiff base, N-(phenolyl)-benzaldimine (HL), has been employed to synthesize a new vanadium(IV) complex of general composition [VO(L)2] (where L = O, N donor of Schiff base). The ligand and complex have been fully characterized by elemental analyses, molar conductance data, FT-IR, 1H- and 13C-NMR, and UV-Vis spectroscopies. Oxidation of alcohols to their corresponding aldehydes and ketones was conducted by this complex catalyst using Oxone as oxidant under biphasic reaction conditions (CH2Cl2/H2O) and tetra-n-butylammonium bromide as phase transfer agent under air at room temperature.

Energy Technology Data Exchange (ETDEWEB)

In this paper the concept of a composite power system stabilizer is investigated. This stabilizer comprises a properly designed, robust, conventional power system stabilizer (CPSS) and an auxiliary stabilizer (AS) which can be either a self-tuning stabilizer (ASTS) or a fixed-parameter stabilizer (AFPS). For small disturbances, the CPSS performs satisfactorily over a wide range of operating conditions. When large disturbances occur the auxiliary stabilizer augments the performance of the CPSS. It has been demonstrated that the composite power system stabilizer can significantly improve the dynamic performance of the system when there is a major disturbance such as a short circuit in the system. Because in the case of a single-machine system the parameters of the ASTS do not vary appreciably, it can also be implemented as ...

International Nuclear Information System (INIS)

The threshold values of indicator species and ratios delineating the transition between NO_x and VOC sensitivity of ozone formation are assumed to be universal by various investigators. However, our previous studies suggested that threshold values might vary according to the locations and conditions. In this study, threshold values derived from various model simulations at two different locations (the area of Switzerland by UAM Model and San Joaquin Valley of Central California by SAQM Model) are examined using a new approach for defining NO_x and VOC sensitive regimes. Possible definitions for the distinction of NO_x and VOC sensitive ozone production regimes are given. The dependence of the threshold values for indicators and indicator ratios such as NO_y, O_3/NO_z, HCHO/NO_y, and H_2O_2/HNO_3 on the definition of NO_x and VOC sensitivity is discussed. Then the variations of threshold values under low emission conditions ...

Science.gov (United States)

MnO2 in pyrolusite can react with SO2 in flue gas and obtain by-product MnSO4 x H2O. A pilot scale jet bubbling reactor was applied in this work. Different factors affecting both SO2 absorption efficiency and Mn2+ extraction rate have been investigated, these factors include temperature of inlet gas flue, ration of liquid/solid mass flow rate (L/S), pyrolusite grade, and SO2 concentration in the inlet flue gas. In the meantime, the procedure of purification of absorption liquid was also discussed. Experiment results indicated that the increase of temperature from 30 to 70 K caused the increase of SO2 absorption efficiency from 81.4% to 91.2%. And when SO2 concentration in the inlet flue gas increased from 500 to 3000 ppm, SO2 absorption efficiency and Mn2+ extraction rate decreased from 98.1% to 82.2% and from 82.8% to 61.7%, respectively. The content of MnO2 in pyrolusite had a neglectable effect on SO2 absorption ...

British Library Electronic Table of Contents (United Kingdom)

The problem of electrical parameters identification in complex systems, and in particular in electric railway traction systems, is considered. Parameters are determined by an indirect approach: only the terminal variables (voltages and currents and, impedance and admittance, which can be readily calculated) are measured and the per-unit-length electrical parameters are determined using a multiconductor transmission line model of the track section under test. It will be shown that some parameters cannot be measured directly, that they are not constant with frequency and that they may depend on other external conditions. An indirect method for parameters identification is proposed through an adaptive algorithm (AA), so that the calculated terminal variables match the measured ones. The AA is...

Energy Technology Data Exchange (ETDEWEB)

This paper describes the technical design and performance of the diagnostic system installed in the tokamak TCABR to measure parameters of the plasma edge. The system consists of four Langmuir probes under remote control. (author)

International Nuclear Information System (INIS)

Description or function: WLUP contains validated WIMS-D formatted cross section libraries in 69 and 172 energy group structures for nuclear reactor calculations. Materials from recently released evaluated nuclear data libraries are included. The NJOY nuclear data processing system was applied for generating the cross section files following the models and conventions built into the WIMS-D lattice code. The relevant features for the WIMS users are: - Energy group structures: 69 and 172 energy groups. - List of materials: WIMS ID, general information, source of data. - Cross sections: 69 and 172 group plots. - Resonance data: WIMS ID, temperature, background cross sections. - Goldstein-Cohen factors: Goldstein-Cohen lambda values. - Thermal scattering data: thermal scattering laws and P1 matrixes. - Fission spectrum: fission spectrum data. - Burnup data: burnup chains. - Fission product yields: fission yield tables. - Pseudo lumped fission product: Description of ...

Energy Technology Data Exchange (ETDEWEB)

A heuristic algorithm that employs fuzzy logic is proposed to the power system transmission expansion planning problem. The algorithm is based on the divide to conquer strategy, which is controlled by the fuzzy system. The algorithm provides high quality solutions with the use of fuzzy decision making, which is based on nondeterministic criteria to guide the search. The fuzzy system provides a self-adjusting mechanism that eliminates the manual adjustment of parameters to each system being solved. (author)

International Nuclear Information System (INIS)

The results for development of methods and computer programs for integrated optimization of parameters of perspective fast reactors are given. The possibilities of the program for the reactor campaign calculation are analysed. This program is based on utilisation of the Bubnov-Galerkin method and Wigner disturbance theory. The possibility of application of approximation methods for the optimization researches is discussed. The results of development of the programs for complex reactor computations with account of control rods system and change of physical parameters in the reactor campaign are discussed. (author).

International Nuclear Information System (INIS)

Experience with the identification and tuning of exciter constants for a generating unit as the Second Nuclear Power Plant of Taiwan Power Company is reported. Field test is first performed on the excitation system with the generator open-circuited. Since the field test results differ from the computer simulation results using manufacturer's constants, the authors first modify the manufacturer's constants based on their previous experience to reach a preliminary set of parameters for the excitation system. Then a hybrid nonlinear simulation-sensitivity matrix method is developed to further refine the excitation system parameters. The exciter constants are tuned in order to give better dynamic response before a power system stabilizer is applied to the generator. Field tests are then performed in order to compare the dynamic response of the generator without and ...

CERN Document Server

This contribution deals with identification of fractional-order dynamical systems. System identification, which refers to estimation of process parameters, is a necessity in control theory. Real processes are usually of fractional order as opposed to the ideal integral order models. A simple and elegant scheme of estimating the parameters for such a fractional order process is proposed. This method employs fractional calculus theory to find equations relating the parameters that are to be estimated, and then estimates the process parameters after solving the simultaneous equations. The said simultaneous equations are generated and updated using particle swarm optimization (PSO) technique, the fitness function being the sum of squared deviations from the actual set of observations. The data used for the calculations are intentionally corrupted to simulate ...

UK PubMed Central (United Kingdom)

An estimator for the load share parameters in an equal load-share model is derived based on observing k-component parallel systems of identical components that have a continuous...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Dynamic stability improvement of a longitudinal power system using a power system stabilizer (PSS) and a static VAR compensator (SVC) is reported in this paper. An analytical approach is developed for the determination of PSS parameters. Results from time domain simulations indicate that the PSS and the SVC are very effective in damping system oscillations.

International Nuclear Information System (INIS)

From the numbers of radiographs of the different examinations and the total amount of radiological diagnostics in the GDR their possible modification by new imaging techniques is discussed under the aspects of costs and radiation burden. Film-screen-systems are of special importance, because they also will be most frequently used image recording system in future. The importance of their various properties and parameters, methods of determining these parameters as well as future developments are analyzed from the standpoint of practical requirements. (author).

International Nuclear Information System (INIS)

This paper proposes a model to explain tritium release behavior of an irradiated Li_4SiO_4 sample made by Forschungszentrum Karlsruhe. The release curves were obtained in a series of experiments carried out using out-pile temperature programmed desorption techniques in the Kyoto University Reactor (KUR). Tritium release curves obtained for different purge gas compositions (N_2, N_2 + H_2, N_2 + H_2O) were compared for selection of suitable conditions to determine the apparent diffusivity of tritium in a crystal grain of Li_4SiO_4.In the model formation, some mass transfer steps in the bulk of the crystal grain and those on the surface of the grain were taken into account, which were diffusion of tritium in the grain, adsorption and desorption of water on the surface of the grain, two types of isotope exchange reactions, and water formation reaction by the addition of hydrogen to the purge gas.Diffusivities of tritium in the ...

International Nuclear Information System (INIS)

Electrodeposition of semiconducting iron oxide (Fe_2O_3) thin film was carried out from an alkaline sulphate bath. A 0.1 M ferrous sulphate (FeSO_4#centre dot#7H_2O) was complexed with 0.1 M citric acid. By addition of 1 N NaOH, pH of the solution was made alkaline (pH=9) and deposition of iron oxide (Fe_2O_3) thin films was carried out potentiostatically at room temperature (300 K). From cyclic voltametry (CV), electrochemical studies were carried out for deposition of iron oxide thin films. The XRD studies reveal that Fe_2O_3 with epsilon (#epsilon#) phase having monoclinic crystal structure is formed. By observing scanning electron microscope (SEM), it is seen that iron oxide films were homogeneous, uniform and well covered to surface of the substrate. Grain size was found to be in nanometers range from XRD analysis. The optical band gap of Fe_2O_3 thin film was estimated to be 1.90 eV. Electrical resistivity was order ...

International Nuclear Information System (INIS)

Synthesis of Eu-doped #beta#- and 15R-SiAlONs was studied by the ammonia nitridation of precursors derived from an #alpha#-Si_3N_4 fine powder dispersed in aluminum glycine gel with various Si/Al ratio and post-annealing in a nitrogen pressure furnace. The largest amount of #beta#-SiAlON was observed in the product at 1750 deg. C for Si/Al = 1/1 with small amounts of both #alpha#- and 15R-SiAlON impurities. The product showed two emissions at around 420 nm and 560 nm. The emission intensities decreased with increasing amount of #beta#-SiAlON. The former and latter emissions were assigned to Eu"2"+ in the 15R- and #alpha#-SiAlONs impurities. A mixture of Eu-doped 15R-SiAlON with #alpha#-Al_2O_3 impurity was obtained for Si/Al = 1/6, using AlN together with Al(NO_3)_3.9H_2O in a 2/1 atomic ratio as the aluminum source. It showed a bluish-white emission at 450 nm under 254 nm radiation.

International Nuclear Information System (INIS)

75 mg (NH_4)_6Mo_7O_24 #centre dot# 4H_2O solution was irradiated for 20 min in miniature neutron source reactor (MNSR) and cooled for 12 min. In the conditions of 0.8 mol/L HNO_3, phase ratio 1:1, the solution of "1"0"1Tc sample was extracted twice with #alpha#-benzoin oxime/ethyl acetate phase to remove "1"0"1Mo and a radiochemically pure and carrier-free "1"0"1Tc product was obtained. The half-life of "1"0"1Tc was accurately measured with a HPGe #gamma#-detector by following 306.8 keV #gamma#-ray about 150 min, and processed the data by three methods, R-value method, iterative method and translation method. Five parallel measurments gave a half-life (14.02 #+-# 0.01) min (n=5) for "1"0"1Tc. (authors)

International Nuclear Information System (INIS)

Volatile compounds produced in flexible food packaging materials (LDPE, EVAc, PET/PE/EVOH/PE) during electron beam irradiation were isolated by purge and trap technique and identified by combined gas chromatography-mass spectrometry (GC/MS), after thermal desorption and concentration. For comparison purposes non-irradiated films were also studied. Film samples were irradiated at low (5 kGy, corresponding to cold pasteurization), intermediate (20 kGy, corresponding to cold sterilization) and high (100 kGy) doses. It was observed that a number of volatile compounds are produced after irradiation in all cases. Furthermore the amounts of all volatile compounds increase with increasing irradiation dose. Both primary (methyl-derivatives etc.) as well as secondary i.e. oxidation products (ketones, aldehydes, alcohols, carboxylic acids etc.) are produced upon irradiation. These products may affect organoleptic properties and thus shelf-life of prepackaged irradiated foods. No significant ...

International Nuclear Information System (INIS)

Direct electrochemistry and electrocatalysis of catalase (Cat) was studied based on a nano-composite film consisting of amine functionalized graphene and gold nanoparticles (AuNPs) modified glassy carbon electrode. Graphene was synthesized chemically by Hummers and Offeman method and then was functionalized with amino groups via chemical modification of carboxyl groups introduced on the graphene surface. The nano-composite film showed an obvious promotion of the direct electron transfer between Cat and the underlying electrode, which attributed to the synergistic effect of graphene-NH2 and AuNPs. The resultant bioelectrode retained its biocatalytic activity and offered fast and sensitive H2O2 quantification. Under the optimized experimental conditions, hydrogen peroxide was detected in the concentration range from 0.3 to 600 ?M with a detection limit of 50 nM at S/N = 3. The biosensor exhibited some advantages, such as ...

International Nuclear Information System (INIS)

To reduce the volume of radioactive wastes after evaporation, activity carriers can be separated from the inactive salt load. Boric acid separation from PWR concentrates was considered a preliminary stage for nuclide precipitation. In connection with the precipitation process, the reaction conditions for boric acid separation were determined by bench-scale experiments. After evaluating the known purification processes, crystallization was suggested as a practicable method. After inactive bench-scale experiments, mixed crystal formation with iron hexacyanoferrate for Cs removal was chosen. The disturbing effect of the complexing agents was neutralized by a pre-dose of iron-III-salts. By specifying the precipitation conditions, for Cs-134 an activity separation from 3,0 E + 06 Bg/l to 1,9 E + 02 Bg/l, and for Cs-137 from 5,9 E + 06 Bg/l to 1,2 E + 02 Bg/l was achieved. Accordingly, the decontamination factor for Cs-134 was 16000, and for Cs-137 48000. For the precipitation of ...

International Nuclear Information System (INIS)

The mobility of oxidized astatine in solutions H(Na)ClO_4 (#mu#=0.4M)-1.10"-"4M K_2Cr_2O_7 has been measured at 25 degC in the interval 0.63<=pH<=1.68. Under these conditions astatine migrates to the cathode only. The speeds of the migration depends upon the concentration of hydrogen ions in solutions are: pH 1.68 Usub(c)=1.17.10"-"4 cm"2 V"-"1 s"-"1; pH 0.63 Usub(c)=2.67.10"-"4 cm"2 V"-"1 s"-"1. The effect agrees with the opinion that the singly charged cation of astatine formed in acidic solutions is a strong aquacomplex [(H_2O)sub(x)At]"+ (x=1-2) (protonated hypoastatic acid). Deprotonation constant of this cation is Ksub(dp)=0.032+-0.005. Specific properties of the astatine cation are given. They can be explained, probably, through the peculiarities of its structure. (author).

Science.gov (United States)

A simple one-step method to fabricate hierarchically porous TiO2/Pd composite hollow spheres without any template was developed by using solvothermal treatment. Pd nanoparticles (2-5 nm) were well dispersed in the mesopores of the TiO2 hollow spheres via in-situ reduction. In our experiment, polyvinylpyrrolidone played an important role in the synthetic process as the reducing agent and the connective material between TiO2 and Pd nanoparticles. HF species generated from solvothermal reaction leaded to the formation of TiO2 hollow spheres and Ostwald ripening was another main factor that affected the size and structure of the hollow spheres. The as-prepared TiO2/Pd composite hollow spheres exhibited high electrocatalytic activity towards the reduction of H2O2. The sensitivity was about 226.72 ?A mM-1 cm-2 with a detection limit of 3.81 ?M at a signal-to-noise ratio of 3. These results made the hierarchically porous TiO2/Pd ...

International Nuclear Information System (INIS)

This study was carried out mainly to produce uranium trioxide (UO_3), matching standard commercial specification from rock phosphate deposits in Uro and Kurun at eastern part of the Nuba Mountains. A simplified hydrometallurgical procedure has been adopted for production of yellow cake from the ore. The powdered ore sample was leached with concentrated H_2SO_4 acid with and without addition of KCIO_3 as an oxidant. The crude yellow cake was precipitated from the resulting green solution of phosphoric acid as Na_2U_2O_7 and (NH_4)_2U_2O_7 and subsequently purified by TBP extraction (tributylphosphate) and hydrogen peroxide as UO_4.2H_2O. TBP purified product was dried and calcined to UO_3 whereas UO_4.2H-2O was dried and reduced to UO_3 by Na_2S_2O_3. Prior to precipitation of crude yellow cake, Fe in the phosphoric acid solution was precipitated using magnesia. ...

Energy Technology Data Exchange (ETDEWEB)

A decentralized power system stabilizer output feedback design approach is considered, which is compatible with expanding the construction of multi-machine systems. We presume that the interconnected power system is constructed by connecting closed-loop subsystems one after another. We take the proper stable factorization approach for calculating the local compensators. We apply the result to the new subsystem at each connection stage with unfixed power system stabilizer parameters. We then determine the parameters appropriately, before connection, so that the expanded system is stable after connection. A numerical example is worked out to illustrate the proposed design technique. 14 refs, 5 figs, 3 tabs

International Nuclear Information System (INIS)

The heavy water reactor such as Wolsung No.1 and No.2 has a purification system to purify the reactor coolant. The control system regulates the coolant temperature to protect the ion exchanger. After the fuel exchanges of operating plant, the increase of the coolant pressure makes the purification temperature control difficult. In this paper, the controllability of the control dynamics of the purification system was analysed and the optimal parameters were proposed. To reduce the effects of the flow disturbance, the feedforward control structure was proposed and analysed.

International Nuclear Information System (INIS)

Development of evaluation technology of electrochemical reactions is very essential to understand chemical behavior of actinides and lanthanides in molten salt media in relation to the development of Pyrochemical process. The on-line electrochemical/spectroscopic measurement system is to produce electrochemical parameters and thermodynamic parameters of actinides and lanthanides in molten salts by using spectroscopic techniques such as UV-VIS absorption as well as electrochemical in-situ measurement techniques. The on-line electrochemical/spectroscopic measurement system can be applied to understand the chemical reactions and oxidation states of actinides and lanthanides in molten salts eventually for the Pyrochemical process

Energy Technology Data Exchange (ETDEWEB)

Power system stabilizers (PSSs) are used to enhance damping of power system oscillations through excitation control of synchronous generator. The objective of the PSS is to generate a stabilizing signal, which produces a damping torque component on the generator shaft. Conventional PSSs are designed with the phase compensation technique in the frequency domain and include the lead-lag blocks whose parameters are determined according to a linearized power system model. The performance of conventional PSSs (CPSSs) depends upon the generator operating point and the system parameters, but a reasonable level of robustness can be achieved depending on the tuning method. This paper presents a new three-dimensional PSS (3D PSS), which uses rotor speed deviation, rotor acceleration and load angle deviation as input signals. The 3D PSS attempts to return the generator to ...

DEFF Research Database (Denmark)

A simple closed-form equation to calculate the envelope correlation between any two receiver or transmitter antennas in a multi-input multi-output (MIMO) system of an arbitrary number of elements is derived. The equation uses the scattering parameters obtained at the antenna feed point to calculate the envelope correlation coefficient. This approach has the advantage that it does not require knowledge of the antenna radiation pattern. Numerical data that include conductor and permittivity loss are shown to validate the approach. Using the scattering parameters for calculating the envelope correlation is less laborious and relatively cheaper, as compared to the radiation pattern approach.

Energy Technology Data Exchange (ETDEWEB)

A new power system stabilizer (PSS) design method for single-machine infinite-bus systems is developed. This design method not only assigns the poles corresponding to the electro-mechanical oscillation modes in the system, but also located other system poles in suitable places in the s-plane. The design procedure is used first to translate a PSS design problem to an equivalent constant output feedback controller design problem for a single-input multi-output (SIMO) system. Then, a new algorithm developed in this paper is applied to design a constant output feedback controller to achieve the desired closed-loop system pole locations. Finally, the controller gains are transferred back to the parameters in the PSS. The extension of the method to multi-machine power systems is also illustrated. (Author).

Energy Technology Data Exchange (ETDEWEB)

Performance and operating characteristics are presented for a solar powered aircraft intended to remain aloft for long periods. The critical technologies which limit the performance are identified. By using the techniques presented, the effects of variation in the system parameters are studied. Practical design consideration are discussed.

UK PubMed Central (United Kingdom)

ObjectivesThe aim of this study was to investigate the effect of cigarette smoking on clinical parameters and signs anemia of chronic disease in chronic periodontitis patients.Full Text Available

UK PubMed Central (United Kingdom)

Skin and hair phenotypes are powerful cues in human communication. They impart much information, not least about our racial, ethnic, health, gender and age status. In the case of the latter parameter,...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The multi-spray direct injection diesel engine has the best efficiency of all combustion systems. The optimization of the air-fuel mixture parameters, especially of the fuel injection, enables the forming of the combustion process in a way, that all requirements and legislative regulations concerning power output, noise and exhaust emissions can be fulfilled. Electronic controlled unit injector systems, as developed by Voest-Alpine Automotive GmbH, Linz, offer the necessary potential to meet the complex requirements.

Energy Technology Data Exchange (ETDEWEB)

In this paper, the adaptive optics (AO) system at Keck Observatory is characterized. The AO system is described in detail. The physical parameters of the lenslets, CCD and deformable mirror, the calibration procedures and the signal processing algorithms are explained. Results of sky performance tests are presented: the AO system is shown to deliver images with an average Strehl ratio of up to 0.37 at 1.59 {micro}m using a bright guide star. An error budget that is consistent with the observed image quality is presented.

Energy Technology Data Exchange (ETDEWEB)

The theoretical formula for the statistical error estimation in Mihalczo method was derived, and the dependence of the error were investigated on the facility to be measured and on the parameter in the data analysis. The formula was derived based on the reactor noise theory and the error theory for the frequency analysis, and found that the error depends on such parameters as the prompt neutron decay constant, detector efficiencies, and the frequency bandwidth. Statistical errors estimated with the formula was compared with experimental values and verified to be reasonable. Through parameter surveys, it is found that there is an optimum combination of the parameters to reduce the magnitude of the errors. In the experiment performed in DCA subcriticality measurement facility, it is estimated experimentally that the measurement requires 20 minutes to obtain the statistic error of 1% for the keff 0.9. ...

Energy Technology Data Exchange (ETDEWEB)

This paper presents the eigenvalue control strategy which utilizes an adaptive power system stabilizer for the decentralized control of damping and frequency of electromechanical oscillations in power systems. The control procedure includes the complete identification of the decoupled subsystem model in real-time from local measurements only and the assignment of its estimated electromechanical eigenvalue by the change of stabilizer parameters. The robustness and efficiency of the proposed adaptive controller to enhance overall system stability are illustrated in several examples, including the three-machine power system model.

British Library Electronic Table of Contents (United Kingdom)

The common envelope phase of binary star evolution plays a central role in many evolutionary pathways leading to the formation of compact objects in short period systems. Using three dimensional hydrodynamical computations, we review the major features of this evolutionary phase, focusing on the conditions that lead to the successful ejection of the envelope and, hence, survival of the system as a post common envelope binary. Future hydrodynamical calculations at high spatial resolution are required to delineate the regime in parameter space for which systems survive as compact binary systems from those for which the two components of the system merge into a single rapidly rotating star. Recent algorithmic developments will facilitate the attainment of this goal.

Energy Technology Data Exchange (ETDEWEB)

This article deals with the need for control strategies and control systems in buildings with hybrid ventilation. In this respect, control strategies are methods of keeping certain parameters like temperature, air quality etc within specified limits. A control system is automatic and includes sensors, motors, dampers etc. The article also discusses consequences with respect to thermal comfort, air quality and energy use following selection of control parameters for controlling air masses.

Science.gov (United States)

The function of the hypothalamo-pituitary-gonadal system has been studied in 118 males with different stages of alcoholism. Comparison with the control group has shown decreased levels of interstitial cell stimulating hormone (ICSH), follicle-stimulating hormone (FSH), and testosterone, and elevated concentrations of prolactin (Prl). Differences in the parameters of hormonal activity expressed in a varying degree of a decrease in FSH, ICSH, and testosterone, and a Prl elevation are related to change in mutual regulatory influences between the gonads and hypothalamo-pituitary complex. The most informative parameters were concentrations of Prl and testosterone (considering elevation in the former and reduction in the latter hormone) and the ratio of their concentrations. Difference of these parameters in each group (corresponding to the stages of alcoholism) may be used as an additional diagnostic ...

Energy Technology Data Exchange (ETDEWEB)

This report describes all time and frequency analysis parameters measured with the new Nuclear Weapons Identification System (NWIS) processor with three input channels: (1) the 252Cf source ionization chamber (2) a detection channel; and (3) a second detection channel for active measurements. An intuitive and physical description of the various functions is given as well as a brief mathematical description and a brief description of how the data are acquired. If the fill five channel capability is used, the number of functions increases in number but not in type. The parameters provided by this new NWIS processor can be divided into two general classes: time analysis signatures including multiplicities and frequency analysis signatures. Data from measurements with an 18.75 kg highly enriched uranium (93.2 wt 0/0, 235U) metai casting for storage are presented to illustrate the various time and frequency analysis ...

Energy Technology Data Exchange (ETDEWEB)

In order to match the output capacity of a geothermal heat pump system (GHPS) with the actual load requirement, research has been carried out in finding the influence of two systematic parameters, the water flow rate inside the condenser and the compressor input frequency on the GHPS operation. Experiments are done on a small-scale GHPS at the water flow rate ranging from 0.054 kg/s to 0.174 kg/s and the frequency from 30 Hz to 55 Hz. The analysis of the experimental data reveals the relationships among the compressor frequency, the water flow rate and other important parameters such as coefficient of performance (COP), heat capacity and compressor power input. The conclusions in the paper can serve as some guidance to the load adjustment of GHPS. (author)

Energy Technology Data Exchange (ETDEWEB)

This paper discusses how specialized techniques for machine condition monitoring can help to eliminate false alarms and undetected faults, leading to a truly cost effective predictive maintenance program. It is vital to base the monitoring system on the parameter which will give the most useful information about potential faults and breakdowns. This parameter is generally agreed to be vibration. While oil debris analysis and variations in temperature, geometry and machine speed can all give advance warning of faults, no other parameter can reveal as wide a range of fault types as vibration. The vibration transducers job is to accurately and faithfully convert the vibration into an electric signal for assessment. If this part of the system is weak, reliability will be badly affected. Data integrity is crucial.

CERN Document Server

System identification refers to estimation of process parameters and is a necessity in control theory. Physical systems usually have varying parameters. For such processes, accurate identification is particularly important. Online identification schemes are also needed for designing adaptive controllers. Real processes are usually of fractional order as opposed to the ideal integral order models. In this paper, we propose a simple and elegant scheme of estimating the parameters for such a fractional order process. A population of process models is generated and updated by particle swarm optimization (PSO) technique, the fitness function being the sum of squared deviations from the actual set of observations. Results show that the proposed scheme offers a high degree of accuracy even when the observations are corrupted to a significant degree. Additional schemes to improve the ...

Energy Technology Data Exchange (ETDEWEB)

The purpose of this study is to identify the radiative heat transfer augmentation by a coaxial cylinder introduced in the infinite cylindrical pipe enclosing a participating gas. The gas is either a mixture of water vapor and carbon dioxide or gray. The gas is assumed to be homogeneous at a constant temperature, and has a refractive index of unity. All of the surfaces are opaque and gray, diffusely emitting and reflecting at a constant temperature. The effect of system diameter, diameter ratio, wall emittances, gas and surface temperatures, mixture component on heat transfer augmentation are studied by using the zone method with participating gas radiative properties evaluated from the weighted sum of gray gases model. From the radiative equilibrium condition, the installed wall temperature is formulated and calculated by the iteration method. If the medium is a gray gas, the augmentation observed are negligible. For the range of values studied for a real gas, if ...

Energy Technology Data Exchange (ETDEWEB)

The RF system for the SuperHILAC injector linac was designed and constructed for minimum system complexity, wide dynamic range, and ease of maintenance. The final amplifier is close coupled to the linac and operates in an efficient semilinear mode, eliminating troublesome transmission lines, modulators, and high level regulators. The system has been operated at over 250 kW, 23 MHz with good regulation. The low level RF electronics are contained in a single chassis adjacent to the RF control computer, which monitors all important operating parameters. A unique 360/sup 0/ phase and amplitude modular is used for precise control and regulation of the accelerating voltage.

Energy Technology Data Exchange (ETDEWEB)

Linear properties of ion temperature gradient (ITG) modes in helical systems are studied. The real frequency, growth rate, and eigenfunction are obtained for both stable and unstable cases by solving a kinetic integral equation with proper analytic continuation performed in the complex frequency plane. Based on the model magnetic configuration for toroidal helical systems like the Large Helical Device (LHD), dependences of the ITG mode properties on various plasma equilibrium parameters are investigated. Particularly, relative effects of {nabla}B-curvature drifts driven by the toroidicity and by the helical ripples are examined in order to compare the ITG modes in helical systems with those in tokamaks. (author)

International Nuclear Information System (INIS)

Plans, engineering parameters, and some test results for several FFTF core and primary sodium circuit instrument systems are presented. The systems discussed include temperature, flow, pressure, leak detectors, level sensors, fuel failure monitoring, sodium impurity analysis and cover gas monitors. Since many of these instruments are similar to those used in other fast reactors around the world, only a brief description is presented for these systems. Results of recent demonstration tests of the FFTF Under-Sodium Viewing and Ranging system are also presented. (U.K.).

Energy Technology Data Exchange (ETDEWEB)

An adaptive power system stabilizer (APSS) employing a new self-optimizing pole shifting control strategy and its application to a power system are described in this paper. Based on an identified model of the system, the control is computed by an algorithm which shifts the closed-loop poles of the system to some optimal locations inside the unit circle in the z-domain to minimize a given performance criterion. With the self-optimization property, outside intervention in the controller design procedure is minimized, thus simplifying the tuning procedure during commissioning. Also, a new method of calculating the variable forgetting factor in real-time parameter identification is discussed. Studies show that the proposed APSS can provide good damping of the power system over a wide operating range and significantly improve the dynamic performance of the ...

Energy Technology Data Exchange (ETDEWEB)

Use of an adaptive optimal control algorithm for two realtime control applications, optimal excitation control of a synchronous generator (OEC) and power system stabilizer (PSS) is described in this paper. Experimental studies on a physical model of a power system show that the proposed OEC and PSS can track the controlled system by parameter identification at different operating conditions. The proposed control algorithm is based on the linear optimal control theory and a special 5th order discrete Riccati equation is solved in each sampling period. The proposed OEC and PSS can always guarantee that in closed loop the controlled system is stable based on the identified parameters. As the actual output of the controlled system and control are directly used in the controller, no observer is required. Also, the proposed OEC and PSS can track ...

Energy Technology Data Exchange (ETDEWEB)

Implementation of an adaptive power system stabilizer (APSS) and experimental studies are presented in this paper. The APSS consists of an adaptive linear element (ADALINE) based identifier that identifies the power system as a third-order discrete auto-regressive moving average (ARMA) model and a pole-shift controller. The ADALINE is modeled so that its weights have a one-to-one relationship with the ARMA model parameters. The weights are updated at each sampling interval to track the dynamic characteristics of the actual system. The on-line updated ARMA parameters are used in the PS control algorithm to calculate the new closed-loop poles of the system that are always inside the unit circle in the z-plane. The calculated control is such that it achieves regulation of the system to a constant setpoint in the shortest interval of time. ...

Science.gov (United States)

The maximum fissile fuel production capacity of three conceptual fusion breeder systems is examined on the basis of the dominant isotopic-balance processes. Compact relationships involving system power output, plasma and energy multiplication, and parameters which describe the fuel cycle and neutron spectrum in the blanket are established. It is found that the fusion breeder, as characterized herein, possesses a substantial fissile fuel breeding capacity the extent of which is governed primarily by the neutron spectrum in the conversion blanket and the break-even condition of the plasma.

Energy Technology Data Exchange (ETDEWEB)

Various topics include: (1) direction finding, (2) range finding, (3) Doppler measurements, (4) construction of a receiver for radio interferometry, (5) mobile laser range finding system, (6) figure-and field parameter determination/geopotential, (7) dynamics of the Earth-Moon system, and (8) kinematics of geodetic point fields.

Energy Technology Data Exchange (ETDEWEB)

Wax appearance temperature (WAT) of three petroleum waxes in different solvent systems under varying thermal conditions has been determined. It is observed that this temperature mainly is a function of the concentration of the wax and the solubility parameter ([delta]) of the solvent taken. This dependence of WAT has been quantified in terms of these variables in the form of mathematical equation and nomographs. (orig.)

Energy Technology Data Exchange (ETDEWEB)

This study presents a dynamic analysis of a rotor supported by two turbulent flow model journal bearings and lubricated with couple stress fluid under nonlinear suspension. The dynamics of the rotor center and bearing center is studied. The dynamic equations are solved using the Runge-Kutta method. The analysis methods employed in this study is inclusive of the dynamic trajectories of the rotor center and bearing center, power spectra, Poincare maps and bifurcation diagrams. The maximum Lyapunov exponent analysis is also used to identify the onset of chaotic motion. The results show that the values of dimensionless parameters l* strongly influence dynamic motions of bearing and rotor centre. It is found that couple stress fluid improve the stability of the system when l* > 0.4 even if the flow of this system is turbulent. We also demonstrated that the dimensionless rotational speed ratios s and the dimensionless ...

International Nuclear Information System (INIS)

The effects of neutron irradiation on the superconducting and normal state properties of alloys and compounds are presented. Particular emphasis is placed on the A-15 compounds where the effects of neutron irradiation on Tsub(c), Hsub(c_2), long range order parameter and lattice parameter are described. Large depressions (up to 80%) in Tsub(c) are observed for all the A-15 compounds studied with the exception of Mo_3Os where much smaller decreases in Tsub(c) are seen. Along with the decrease in Tsub(c) and increase in lattice parameter, the degree of long range order, as measured by X-ray and neutron diffraction, decreases. Also presented are the results of isothermal and isochronal anneals up to 900"0C. The unirradiated value of Tsub(c) can be restored by annealing, and for those systems where measurements have been made, recovery of the lattice parameter and order ...

International Nuclear Information System (INIS)

The interaction of Np(V), Pu(VI) and Tc(VII) with metal reductants Zn, Cr, Sn and their alloys was investigated in 0.5-4 mol l"-"1 NaOH solutions in static and dynamic conditions (by filtration of solutions through the column filled with grains of metal). In this paper, it was found that the reduction and succeeding precipitation hydroxides of these elements, on the surface of metal grains from 0.5 to 4 mol l"-"1 NaOH solutions, gives a decontamination factor (DF) from 1.1 to 67. The best result was achieved for Pu (DF=67) on Cr grains after 2.5 h contact at 60 C with 0.5 mol l"-"1 NaOH solution containing Pu(VI). Increasing the NaOH concentration, and the addition of chromate ions and complex-forming agents to alkaline solution results in a decrease of the decontamination factor (DF). A better result for Np sorption from 1 mol l"-"1 NaOH solutions was achieved after longer contact, than for Pu, with Cr and Zn grains. The maximum DF=8.9 was achieved for Tc on a column with Zn grains ...

International Nuclear Information System (INIS)

The central benzodiazepine receptor tracer [N-methyl-"1"1C]iomazenil (Ro 16-0154) was synthesized by alkylation of the desmethyl precursor noriomazenil with ["1"1C]methyl iodide. The ["1"1C]CH_3I (prepared by reduction of ["1"1C]CO_2 with LiAlH_4 followed by reaction with HI) was reacted with noriomazenil inN,N -dimethylformamide and Bu_4N"+OH"- for 1 min at 80 deg. C and purified by HPLC (C_1_8, 34% CH_3CN/H_2O, 7 mL/min). The product was obtained with synthesis time 35 #+-# 5 min (mean #+-# SD, n = 7), radiochemical yield (EOB) 36 #+-# 16%, radiochemical purity 99 #+-# 1%, and specific activity 5100 #+-# 2800 mCi/#mu#mol. Absorbed radiation doses were calculated from previously acquired human biodistribution data. The urinary bladder wall received the highest dose (0.099 mGy/MBq) for 4.8 h voiding interval and the effective dose equivalent was 0.015 mSv/MBq. After i.v. injection of ["1"1C]iomazenil in an adult baboon or ...

CERN Document Server

We present deep images of dust continuum emission at 450, 800, and 850 micron of the dark cloud LDN 1689N which harbors the low-mass young stellar objects (YSOs) IRAS 16293-2422A and B (I16293A and I16293B) and the cold prestellar object I16293E. Toward the positions of I16293A and E we also obtained spectra of CO-isotopomers and deep submillimeter observations of chemically related molecules with high critical densities. To I16293A we report the detection of the HDO 1_01 - 0_00 and H2O 1_10 - 1_01 ground-state transitions as broad self-reversed emission profiles with narrow absorption, and a tentative detection of H2D+ 1_10 - 1_11. To I16293E we detect weak emission of subthermally excited HDO 1_01 - 0_00. Based on this set of submillimeter continuum and line data we model the envelopes around I16293A and E. The density and velocity structure of I16293A is fit by an inside-out collapse model, yielding a sound speed of ...

International Nuclear Information System (INIS)

The layered PrBaCo_2O_5_+_#delta# (PBCO) perovskite oxides were synthesized by modified Pechini method and investigated as a cathode material for solid oxide fuel cells (SOFCs) based on a stable and easily sintered perovskite oxide BaCe_0_._5Zr_0_._3Y_0_._1_6Zn_0_._0_4O_3_-_#delta# (BCZYZ) as electrolyte. The fabricated single cell of NiO-BCZYZ/BCZYZ (#approx#20 #mu#m)/PBCO was operated from 550 to 700 "oC with humidified hydrogen (#approx#5% H_2O) as fuel and the static air as oxidant. The BCZYZ perovskite electrolyte was completely dense after sintered at 1250 "oC for 5 h, lower than that without zinc dopant about 150 "oC. A high open-circuit potential of 1.007 V, a peak power density of 361 mW cm"-"2, and a low polarization resistance of the electrodes of 0.12 #OMEGA# cm"2 was achieved at 700 "oC. The ratio of polarization resistance to total cell resistance decreased with the increase of operating temperature, from ...

CERN Document Server

Mon R2, at a distance of 830 pc, is the only ultracompact HII region (UC HII) where the photon-dominated region (PDR) between the ionized gas and the molecular cloud can be resolved with Herschel. HIFI observations of the abundant compounds 13CO, C18O, o-H2-18O, HCO+, CS, CH, and NH have been used to derive the physical and chemical conditions in the PDR, in particular the water abundance. The 13CO, C18O, o-H2-18O, HCO+ and CS observations are well described assuming that the emission is coming from a dense (n=5E6 cm-3, N(H2)>1E22 cm-2) layer of molecular gas around the UC HII. Based on our o-H2-18O observations, we estimate an o-H2O abundance of ~2E-8. This is the average ortho-water abundance in the PDR. Additional H2-18O and/or water lines are required to derive the water abundance profile. A lower density envelope (n~1E5 cm-3, N(H2)=2-5E22 cm-2) is responsible for the absorption in the NH 1_1-0_2 line. The emission ...

International Nuclear Information System (INIS)

The ELEX process for isotopic enrichment and separation of tritium from aqueous reprocessing effluents is described. After the development of an appropriate hydrophobic catalyst and the study of the separate constituent steps of the ELEX process, an integrated bench-scale installation with a detritiation capacity of 10 mol water per hour was constructed. It comprises essentially a 1.5 kW electrolyser and two 2 cm diameter by 3 m high exchange columns. In this mini-pilot the ELEX process was successfully demonstrated by detritiating more than 1000 dm"3 water containing up to 100 mCi tritium per dm"3, which is the feed concentration expected for application of the process in a reprocessing plant. The process decontamination factor was always larger than 100 and the overall tritium balance could be kept within the experimental errors of the various measurements. Depending on the duration of the runs, the volume reduction factor was between 10 and 15, but this factor will become much ...

International Nuclear Information System (INIS)

Ab initio total energy calculations within the framework of density functional theory have been performed for water molecule adsorption on the (0001) surface of double hexagonal packed americium using a full-potential all-electron linearized augmented plane wave plus local orbitals method (FP-L/APW+lo). Subsequent partial dissociation (OH+H) and complete dissociation (H+O+H) of the water molecule have been examined. The completely dissociated H+O+H configuration exhibit the strongest binding with the surface (3.35 eV), followed by partially dissociated species OH+H (2.23 eV), with all molecular H_2O configurations showing weak physisorption (0.366 eV). For molecular adsorptions, the flat lying orientation of the water molecule if found to be more favorable for majority of the cases. In the case of partial dissociation (OH+H), the vertical orientation of OH molecule with O facing the surface adsorbed at a h3 adsorption site ...

Energy Technology Data Exchange (ETDEWEB)

An adjustment support system using computer for start-up operation of cyclotron is being developed in order to support operators who, using their experiences and intuition, tune up dozens of components to maximize beam efficiency. This paper describes a method of beam pattern diagnosis and adjustment guidance based on fuzzy relation as one function of the adjustment support system. The followings are the basic processes of this method. (1) The computer extracts features of beam pattern which correspond with operators' criteria. (2) The computer calculates causative possibility of each adjustment parameters by inverse operation of fuzzy relational equation, which formulates the relationship between criteria of beam pattern and adjustment parameters. (3) The computer displays those causative probabilities in a graphical manner as a operation guidance. Not only the probabilities but also the ...

Science.gov (United States)

Up to the present, the generic values of the Common cause failure (CCF) event parameters have been used in most PSA projects for the Korean NPPs. However, the CCF analysis should be performed with plant specific information to meet Category II of the ASME PRA Standard. Therefore, we estimated the Alpha factor parameters of the emergency diesel generator (EDG) for Ulchin Unit 3 by using the International Common-Cause Failure data Exchange (ICDE) database. The ICDE database provides the member countries with only the information needed for an estimation of the CCF parameters. The Ulchin Unit A3, pressurized water reactor, has two onsite EDGs and one alternate AC (AAC) diesel generator. The onsite EDGs of Unit 3 and 4 and the AAC are manufactured by the same company, but they are designed differently. The estimation procedure of the Alpha factor used in this study follows the approach of the NUREG/CR-5485. Since we did not ...

CERN Document Server

The physical foundations of a variety of emerging technologies --- ranging from the applications of quantum entanglement in quantum information to the applications of nonequilibrium bulk and interface phenomena in microfluidics, biology, materials science, energy engineering, etc. --- require understanding thermodynamic entropy beyond the equilibrium realm of its traditional definition. This paper presents a rigorous logical scheme that provides a generalized definition of entropy free of the usual unnecessary assumptions which constrain the theory to the equilibrium domain. The scheme is based on carefully worded operative definitions for all the fundamental concepts employed, including those of system, property, state, isolated system, environment, process, separable system, system uncorrelated from its environment, and parameters of a system. The treatment ...

Energy Technology Data Exchange (ETDEWEB)

The paper discusses a number of recent studies investigating into the energy conservation and environmental impacts of electric heating systems (off-peak storage systems). In future, i.e. in and after 1993, off-peak storage systems will be evaluated through comparative analyses of oil-fired heating systems, pollutant emission analyses, the eventual success of pollution abatement measures designed for power plant emissions to keep within the legal limiting values, and the possible abandonment of pollution abatement measures abroad. Opposing the electric heating studies submitted by the electric power industry the author refutes their favourable results referring to the palliative selection of inadequate or vague parameters. Assuming average power plant pollutant emissions of 180 mg/standard/sup 3/ the nitrogen oxide emissions of oil-fired heating systems (134.1 ...

Energy Technology Data Exchange (ETDEWEB)

An exergoeconomic model of a vertical ground-source heat pump residential heating system presented in this study uses exergy and cost energy mass (EXCEM) methods. The data obtained from a ground-source heat pump (GSHP) residential heating system installed at the Solar Energy Institute, Ege University, Turkey, are utilized for calculations at different reference temperature values in the range 0-25{sup o}C. The performance of the geothermal heat pump residential heating system is evaluated to indicate how exergoeconomic parameter values change with system. We also undertake a parametric study to investigate how varying reference temperatures will affect the exergoeconomic analysis of the GSHP system. A correlation between the ratio of thermodynamic loss rate to capital cost and reference state temperature is developed. (author)

Energy Technology Data Exchange (ETDEWEB)

This paper presents a systematic approach to the automatic determination of the evolution of the rigid-plastic structural response caused by a proportional or single parameter pressure loading which varies with time in a monotonic non decreasing fashion. The frame structure is envisaged as a network, and the fundamental vectorial conditions characterising its behaviour at any instant of time are combined in a consistent manner. By considering the level of the pressure loading to be a single load parameter ranging monotonically from zero to infinity, the structural governing system may be regarded as a parametric linear complementary problem. (author). 13 refs., 2 figs.

Energy Technology Data Exchange (ETDEWEB)

Metallic multilayers offer a fantastic playground to investigate elastic stresses in films of nanometer thickness. We will present and discuss a few examples from our recent work on Au-Ni and Ag-Cu systems where we combined plate bending measurements and electron or X-ray diffraction to investigate stress buildup and interfacial mixing. Comparing these two cases we discuss the results with respect to basic parameters like the misfits in lattice parameters and in elastic moduli, the mixing enthalpies and the surface energies.

International Nuclear Information System (INIS)

Formation of basis type texture at rolling of Ti + 6.0% Al + 1.5% V + 1.0% Mo system alloy with initial prismatic texture is investigated by means of X-ray techniques. Variations of mechanical features in titanium alloy sheets depending on temperature-deformation conditions of rolling are investigated. Main conditions for formation of the intensive basis textute in the investigated alloy sheets which provides for isotropic properties in sheet plane and for increased ductility are determined.

International Nuclear Information System (INIS)

A pipe whip test is one of the main subjects of the pipe rupture tests performed in Japan Atomic Energy Research Institute. In 1979, the pipe whip test of 4B, sch-80 pipe will be done under the BWR condition. As the preliminary analysis of this test, the pipe whip analysis of 4B, sch-80 pipe was implemented in order to make clear of the influences of the physical parameters on the pipe whip behavior. The pipe whip analysis was treated as nonlinear dynamic analysis of pipe-restraint system by using the general purpose finite element program ADINA. Overhang length, clearance between pipe and restraint, restraint length and cross section area of restraint were taken as physical parameters. It was clarified through this analysis how restraint displacement, restraint strain and distribution of energy between pipe and restraint were influenced by these parameters. (author).

CERN Document Server

Strong gravitational lensing of an extended object is described by a mapping from source to image coordinates that is nonlinear and cannot generally be inverted analytically. Determining the structure of the source intensity distribution also requires a description of the blurring effect due to a point spread function. This initial study uses an iterative gravitational lens modeling scheme based on the semilinear method to determine the linear parameters (source intensity profile) of a strongly lensed system. Our 'matrix-free' approach avoids construction of the lens and blurring operators while retaining the least squares formulation of the problem. The parameters of an analytical lens model are found through nonlinear optimization by an advanced genetic algorithm (GA) and particle swarm optimizer (PSO). These global optimization routines are designed to explore the parameter space thoroughly, mapping ...

International Nuclear Information System (INIS)

Experimental investigations have been conducted to determine two-phase natural circulation interfacial parameters by real-time neutron radiography. The natural circulation loop used in the present experiments consists of a vertical two-phase section, a gas liquid separator, and a gas injection/heating section. Experiments were performed in a neutron beam for visualization using realtime neutron radiography system. The natural circulation was initiated by injection of known gas flow rate in the heated section. Two-phase flow interfacial parameters including interfacial geometry and phase velocities etc. for bubbly flow and slug flow patterns observed in the experiments will be given in detail. The results indicate that while the natural circulation is largely as expected and that steady stable flows are possible, there are some local phenomena that introduce instabilities due to the interfacial phenomena between the liquid ...

International Nuclear Information System (INIS)

In view of no satisfactory mathematical model is presently available for the dose-response curve of immunoradiometric assay, a three parameter model based on single binding site mass action law has been derived. A curve fitting method based on similar principle of linear robust regression was designed and a software was prepared for use on IBM personal computers. Experiments revealed that the model is applicable to a variety of IRMA systems as well as to time-resolved immunofluorometric assay of hAFP. When there was outlier(s) of the calibration curve, the average bias of unknown samples obtained with this method is significantly smaller than methods using four parameter logistic model or four parameter single site mass action model.

Energy Technology Data Exchange (ETDEWEB)

Multi-dimensional modelling of two-phase flow requires accurate constitutive relationships for interfacial parameters such as interfacial heat transfer, void fraction distribution, interfacial area, etc. However, existing diagnostic systems for measurement of two-phase flow parameters have difficulty measuring two or three-dimensional void distributions required for determination of interfacial parameters. In this work, a Real-Time Neutron Radiography (RTNR) system is developed for non-intrusive measurement of two-phase flow parameters in nuclear fuel channels at low thermal neutron fluxes (on the order of 10{sup 6}n/cm{sup 2}-s). This advanced radiation technique has the advantage of measuring two-phase flow in 3 1/2 dimensions (x,{integral}dy,t) where the 1/2 dimension refers to an integrated or averaged space dimension. Pipe flow channels, annulus flow ...

Science.gov (United States)

The properties of the mixing layer in dynamic systems were studied by the example of a mathematical model of the cubic image type. Its role in the generation of information and the evolution of its significance was shown. At the moment of generation, information is of zero significance, and this significance then increases. A criterion of efficiency was proposed, and the optimum moment of making a decision in creative work was determined. It was shown that the increase in the variability of the parameters of a living system upon entry into the mixing layer and its decrease upon exit can serve as objective indicators of the transition of the system from one dynamic regime (attractor) to another. PMID:12723364

Energy Technology Data Exchange (ETDEWEB)

This paper consists of two parts. Part 1 deals with the thermodynamic and thermoeconomic methodology of a trigeneration (TRIGEN) system with a rated output of 6.5 MW gas-diesel engine while the application of the methodology is presented in Part 2. The system has been installed in the Eskisehir Industry Estate Zone in Turkey. Thermodynamic methodology includes the relations and performance parameters for energy and exergy analysis, while thermoeconomic methodology covers the cost balance relations, cost of products and thermodynamic inefficiencies, relative cost difference and exergoeconomic factor. (author)

CERN Document Server

The Rabi Hamiltonian, describing the coupling of a two-level system to a single quantized boson mode, is studied in the Bargmann-Fock representation. The corresponding system of differential equations is transformed into a canonical form in which all regular singularities between zero and infinity have been removed. The canonical or Birkhoff-transformed equations give rise to a two-dimensional eigenvalue problem, involving the energy and a transformational parameter which affects the coupling strength. The known isolated exact solutions of the Rabi Hamiltonian are found to correspond to the uncoupled form of the canonical system.

Energy Technology Data Exchange (ETDEWEB)

The fuzzy polar power system stabilizer (FPPSS) which has been recently developed is analyzed using frequency domain methods. the frequency domain approach allows the PSS designer to compare the new FPPSS with more conventional controllers. The significance of the three FPPSS design parameters are readily seen from the frequency response data, and their relationship to the conventional lead-lag design approach can be evaluated. Furthermore, the frequency response data for the FPPSS allows an alternate design approach for this stabilizer, and can be used to develop information concerning the small signal stability of the resulting system.

Energy Technology Data Exchange (ETDEWEB)

The aim of this research is the design and implementation of a decentralized power system stabilizer (PSS) capable of performing well for a wide range of variations in system parameters and/or loading conditions. The framework of the design is based on Fuzzy Logic Control (FLC). In particular, the neuro-fuzzy control rules are derived from training three classical PSSs; each is tuned using GA so as to perform optimally at one operating point. The effectiveness and robustness of the designed stabilizer, after implementing it to the laboratory model, is investigated. The results of real-time implementation prove that the proposed PSS offers a superior performance in comparison with the conventional stabilizer. (author)

Energy Technology Data Exchange (ETDEWEB)

The Reliability and Availability Data System (RADS) is a database and analysis code, developed by the Idaho National Engineering and Environmental Laboratory (INEEL) for the U.S. Nuclear Regulatory Commission (USNRC). The code is designed to estimate industry and plant-specific reliability and availability parameters for selected components in risk-important systems and initiating events for use in risk-informed applications. The RADS tool contains data and information based on actual operating experience from U.S. commercial nuclear power plants. The data contained in RADS is kept up-to-date by loading the most current quarter's Equipment Performance and Information Exchange (EPIX) data and by yearly lods of initiating event data from licensee event reports (LERS). The reliability parameters estimated by RADS are (1) probability of failure on demand, (2) failure rate during operation (used to ...

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the major features of the advisory tool `TUNDTEMP`, developed to act as a decision support in the continuous steel casting process. `TUNDTEMP` provides a means to predict abnormal phenomena of temperature origin in the casting that may be difficult to foresee in practical situations. The heart of the system is a semi-empirical calculation model that yields an estimate of the evolution of the tundish temperature of the liquid steel on the basis of a few important casting factors. The user interface of the system is to a large extent based on the visual presentation of the simulated results. The system also contains an optional rule based mechanism that provides assistance in the result interpretation and, if wished, linguistically formulates action recommendations. A separate program has been built for the tuning of the calculation model and for maintenance of the system. At the ...

CERN Document Server

In many online systems, individuals provide services for each other. Typically, the recipient of the service obtains a benefit while the provider of the service incurs a cost. Assuming that benefit exceeds cost, provision of the service increases social welfare and should therefore be encouraged -- but the individuals providing the service gain no (immediate) benefit from providing the service and hence have an incentive to withhold service. This paper studies the design of a system to encourage provision of service; the emphasis is on how the system designer should choose a protocol -- a supply of tokens and suggested strategies -- to maximize social welfare. In choosing this protocol, the system designer must take into account that agents are self-interested, and hence will comply with the protocol if and only if it is in their interests to do so. Moreover, we insist that the chosen protocol must be ...

Energy Technology Data Exchange (ETDEWEB)

In this paper the newly developed discrete-time adaptive sliding mode control method is proposed and applied to the power system stabilization problem. In contrast to the conventional continuous-time sliding mode controller, the proposed method is developed in the discrete-time domain and based on the input/output measurements instead of the continuous-time and the full-states feedback, respectively. Because the proposed control method has the adaptivity property in addition to the natural robustness property of the sliding mode control, it is possible to design the power system stabilizer which can overcome both the minor variations of the parameters of the power system and the diverse operating conditions and faults of the power system. Mathematical proof and the various computer simulations are done to verify the performance and stability of the proposed method. (author). 14 ...

International Nuclear Information System (INIS)

Optimum processing parameters were searched for the pilot-scale production of wood-polyester composites by irradiation of resin-impregnated wood material. The radiation initiation of the following systems were examined in wood and without wood matrix: methyl methacrylate, mixture of styrene and acrylonitryle, and their combination with unsaturated polyester. In the most cases the over-all rate of the complete polymerization process in wood matrix is proportional to the square root of the initiation rate. The parameters of the radiation technology of wood-polyester composites have been determined, using 260 TBq (7 kCi) "6"0Co radiation source. A pilot plant has been constructed using an underwater irradiation system of 1.85 PBq (50 kCi) "6"0Co. The successful production rate of 200 kg wood-polyester composite per day, as well as the application tests have demonstrated the technical feasibility of this ...

British Library Electronic Table of Contents (United Kingdom)

The ECOSYS model is used to estimate ingestion dose in the ARGOS and RODOS decision support systems for nuclear emergency management. It is recommended that nation-specific values for several parameters are used in the model. However, this is generally overlooked when the systems are used in practice. We have estimated first year ingestion doses in two scenarios with wet and dry deposition of 137Cs, using the ECOSYS model. We calculated doses for each country using national dietary data while keeping all other parameters at their default values. These dose calculations were then used to estimate the variation in ingestion doses resulting from the variation in the diets only. The dietary data demonstrated that the average consumption of milk, meat and vegetables varied by a factor of 2-4 am...

British Library Electronic Table of Contents (United Kingdom)

This study performs a dynamic analysis of the rub-impact rotor supported by two couple stress fluid film journal bearings. The strong nonlinear couple stress fluid film force, nonlinear rub-impact force and nonlinear suspension (hard spring) are presented and coupled together in this study. The displacements in the horizontal and vertical directions are considered for various non-dimensional speed ratios. The numerical results show that the dynamic behaviors of the system vary with the dimensionless speed ratios, the dimensionless unbalance parameters and the dimensionless parameter, l*. Inclusive of the periodic, sub-harmonic, quasi-periodic and chaotic motions are found in this analysis. The results of this study contribute to a further understanding of the nonlinear dynamics of a rotor-...

Energy Technology Data Exchange (ETDEWEB)

A pole placement technique for power system stabilizer (PSS) and thyristor controlled series capacitor (TCSC) based stabilizer using simulated annealing (SA) algorithm is presented in this paper. The proposed approach employs SA optimization technique to PSS (SAPSS) and TCSC-based stabilizer (SACSC) design. The design problem is formulated as an optimization problem where SA is applied to search for the optimal setting of the proposed SAPSS and SACSC parameters. A pole placement-based objective function to shift the dominant eigenvalues to the left in the s-plane is considered. The proposed SAPSS and SACSC have been examined on a weakly connected power system with different disturbances, loading conditions, and system parameter variations. Eigenvalue analysis and nonlinear simulation results show the effectiveness and the robustness of the proposed stabilizers and their ability to ...

Energy Technology Data Exchange (ETDEWEB)

The Fast Wave Current Drive (FWCD) system at DIII-D has increased its available radio frequency (RF) power capabilities with the addition of two new high power transmitters along with their associated transmission line systems. A Sun Sparc-10 workstation, functioning as the FWCD operator console, is being used to control transmitter operating parameters and transmission line tuning parameters, along with acquiring data and making data available for integration into the DIII-D data acquisition system. Labview, a graphical user interface application, is used to manage and control the above processes. This paper will discuss the three primary branches of the FWCD computer control system: transmitter control, transmission line tuning control, and FWCD data acquisition. The main control program developed uses VXI, GPIB, CAMAC, Serial, and Ethernet protocols to blend ...

International Nuclear Information System (INIS)

This paper presents a practical case study on the dynamic stability of the Saudi Electricity Company (SEC) power system and its effect on increasing power transfer limit of the interconnection between Eastern Operating Area (SEC-EOA). The problem of optimal tuning of the power system stabilizer parameters was converted into optimization problem wth eigenvalue-based objective functions, which was then solved by genetic algorithms. In this regard, two eigenvalue-based objective functions were considered and the problem is solved using real-coded genetic algorithm (RCGA). The effectiveness of the suggested technique to enhance the power system dynamic stability and to extend the power transfer capability limit of the SEC-EOA and the SEC-EOA power system was verified through a comprehensive eigenvalue analysis and time-domain nonlinear simulation. The results also indicated that the ...

Energy Technology Data Exchange (ETDEWEB)

Traditional two-phase flow-regime criteria based on the gas and liquid superficial velocities may not be suitable to the analyses of rapid transient or entrance flows by the two-fluid model. Under these conditions, it is postulated that direct geometrical parameters such as the void fraction are conceptually simpler and therefore more reliable parameters to be used in flow-regime criteria than the traditional parameters. From this point of view, new flow-regime criteria for upward gas-liquid flow in vertical tubes have been developed considering the mechanisms of flow-regime transitions. These new criteria can be compared to existing criteria and experimental data under steady-state and fully developed flow conditions by using relative velocity correlations. The criteria showed reasonable agreements with the existing data for atmospheric air-water flows. Further comparisons with data for steam-water in round tubes and a ...

Energy Technology Data Exchange (ETDEWEB)

The uptake of sup(99m)Tc-methylenediphosphonate (MDP) in different parts of rat femur was simulated using a local three-space model for tracer transfer. The model consisted of bone blood, bone ECF-space and space for tracer deposition. The measured sup(99m)Tc-MDP concentration in the systemic blood and the local bone blood flow measured by /sup 131/I-macroaggregated albumin microspheres were used as input parameters. The measured blood flow values were 6.3, 3.1 and 15.3 ml/100 g/min for proximal, middle and distal femur, respectively. the model parameters that gave the best fit to measured sup(99m)Tc-MDP uptake curves in computer simulation showed that bone blood flow, volume of ECF-space, permeability surface area product and accretion constant from ECF-space to space for tracer deposition were highest in distal and lowest in middle femur. The values corresponded to peak extraction fractions of 0.38, 0.62, and 0.31 for ...

International Nuclear Information System (INIS)

Objective: To investigate the relationship between exposure dose and image quality for a direct digital radiography system and to determine the optimum exposure parameters for pelvic examination. Methods: A contrast-detail phantom CDRAD2.0 was exposed to different doses and the IQF of phantom images were calculated. The optimum exposure parameters were determined by ANOVA and SNK analysis. The image of an anthropomorphic phantom taken with optimized exposure parameters was verified using CEC image criteria. Results: The IQF of the images of CDRAD2.0 phantom was significantly different for different doses, as the exposure dose was greater than 0.61 mGy. The IQFs have no difference for different dose groups. The image quality between this optimized exposure dose and conventional exposure dose not was significantly different. Conclusion: The image quality of direct digital radiography ...

Science.gov (United States)

Orientational constraints obtained from solid state NMR experiments on anisotropic samples are used here in molecular dynamics (MD) simulations for determining the structure and dynamics of several different membrane-bound molecules. The new MD technique is based on the inclusion of orientation dependent pseudo-forces in the COSMOS-NMR force field. These forces drive molecular rotations and re-orientations in the simulation, such that the motional time-averages of the tensorial NMR properties approach the experimentally measured parameters. The orientational-constraint-driven MD simulations are universally applicable to all NMR interaction tensors, such as chemical shifts, dipolar couplings and quadrupolar interactions. The strategy does not depend on the initial choice of coordinates, and is in principle suitable for any flexible molecule. To test the method on three systems of increasing complexity, we used as constraints some deuterium ...

International Nuclear Information System (INIS)

Orientational constraints obtained from solid state NMR experiments on anisotropic samples are used here in molecular dynamics (MD) simulations for determining the structure and dynamics of several different membrane-bound molecules. The new MD technique is based on the inclusion of orientation dependent pseudo-forces in the COSMOS-NMR force field. These forces drive molecular rotations and re-orientations in the simulation, such that the motional time-averages of the tensorial NMR properties approach the experimentally measured parameters. The orientational-constraint-driven MD simulations are universally applicable to all NMR interaction tensors, such as chemical shifts, dipolar couplings and quadrupolar interactions. The strategy does not depend on the initial choice of coordinates, and is in principle suitable for any flexible molecule. To test the method on three systems of increasing complexity, we used as constraints some deuterium ...

Energy Technology Data Exchange (ETDEWEB)

Dynamic Flowgraph Methodology (DFM) is a methodological approach to modeling and analyzing the behavior of software-driven embedded systems for the purpose of reliability/safety assessment and verification. The methodology has two fundamental goals: (a) to identify how certain postulated events may occur in a system and (b) to identify an appropriate testing strategy based on an analysis of system functional behavior. To achieve these goals, the methodology employs a modeling framework in which system models are developed in terms of causal relationships between physical variables and temporal characteristics of the execution of software modules. These models are then analyzed to determine how a certain state (desirable or undesirable) can be reached. This is done by developing timed fault trees, which take the form of logical combinations of static trees relating system ...

Energy Technology Data Exchange (ETDEWEB)

Part 1 of the Electric Utility Engineer`s Flue Gas Desulfurization (FGD) Manual emphasizes the chemical and physical processes that form the basis for design and operation of lime- and limestone-based FGD systems applied to coal- or oil-fired steam electric generating stations. The objectives of Part 1 are: to provide a description of the chemical and physical design basis for lime- and limestone-based wet FGD systems; to identify and discuss the various process design parameters and process options that must be considered in developing a specification for a new FGD system; and to provide utility engineers with process knowledge useful for operating and optimizing a lime- or limestone-based wet FGD system.

Energy Technology Data Exchange (ETDEWEB)

Using the Relativistic Mean Field Theory (RMF) it is shown that different proton fraction which is directly connected with the neutron excess and with the asymmetry of the system affects proto-neutron stars parameters and changes their composition. The obtained form of the equation of state allows to construct the mass-radius relations and shows that the increasing asymmetry creates more compact stars. The inclusion of {delta} meson together with nonlinear vector meson interaction terms and magnetic field make this effect even stronger.

Energy Technology Data Exchange (ETDEWEB)

Presented are some preliminary studies made in preparation for the design of a solar powered loop for desalination by humidification - dehumidification process. The studies concentrated on the evaluation of different parameters affecting the performance of the combination of different components in such a loop in the hope of outlining the most decisive factors for the choice or design of solar collectors or heat source. The results presented relate to the performance of two of the most important components in a loop of such purpose, that is: the humidifying and the dehumidifying columns or stacks. 4 refs.

British Library Electronic Table of Contents (United Kingdom)

Patient monitoring during mechanotherapy based on electrocutaneous impedance measurement is discussed. Methods implemented by the Alpharhythmica computer-assisted system are described. Mechanotherapy modifies electrocutaneous impedance as compared to other parameters: heart rate, arterial pressure, and body temperature. Real time criteria of mechanotherapy efficacy based on electrocutaneous impedance measurement are suggested. Results of electrocutaneous impedance monitoring are presented.

International Nuclear Information System (INIS)

We study the possibility of utilizing the superfluid to Mott-insulator quantum phase transition in an array of quantum well exciton-polariton traps to generate indistinguishable single photons in a massive parallel fashion. By means of analytical and numerical methods, the device operations and system properties are examined using realistic experimental parameters. Such a deterministic, massive parallel generation may find new applications in photonic quantum information processing.

Energy Technology Data Exchange (ETDEWEB)

Experiments were performed on horizontal air-water bubbly two-phase flow, axial flow, stratified wavy flow, and annular flow. Theoretical studies were also undertaken on interfacial parameters for a horizontal two-phase flow.

International Nuclear Information System (INIS)

The two favourable dry storage concepts being under consideration in the Federal Republic of Germany are presented and the physical behaviour or natural convection cooling with air is explained. With the three examples cask store, vault storage horizontally and vertically arranged the main thermodynamical design parameters and their influence on the efficiency of the cooling system and on the temperature distribution inside the store and of the stored material are discussed. Moreover, the importance of the fulfilment and the harmony of all safety criteria and the difficulties while to do so are carried out especially with the vault store.

International Nuclear Information System (INIS)

The #beta# decay half-lives of neutron-rich isotopes with Z=24-28 are calculated in the QRPA with a Gamow-Teller residual interaction. For odd-mass and odd-odd systems QRPA phonon correlations are introduced to quasiparticle transitions in first-order perturbation. The calculated half-lives agree very well with the experimental values. For later application of this model to nuclei far from stability, we have examined the dependence of the calculated half-lives on the model parameters. (orig.).

British Library Electronic Table of Contents (United Kingdom)

We present a comparative study on the acoustic tunneling through artificial periodical composites, from phononic crystals to acoustic metamaterials. We find that the features of the acoustic tunneling are closely related with the origins of band gaps. In particular, the band gap associated with the negative effective material parameter in the metamaterial results in a better analog of the tunneling effect to the quantum system.

International Nuclear Information System (INIS)

Scattered radiation generated in patient and imaging system has to be considered when quality-assurance tests involve dose detection or image-quality estimations. Measurement of automatic-exposure control dose can be altered by backscattering from intensifying screens of more than 10% and the equipment transmission factor can be overestimated up to a factor of 10 when only primary radiation is used. The sensitivity of intensifying screens depends on the angle of incidence of the radiation and so primary and scattered radiation are detected differently. The quality-control aspects of anti-scatter grids are discussed. (author).

Science.gov (United States)

This paper presents a systematic study on the stability of a two-dimensional vibration isolation floating raft system with a time-delayed feedback control. Based on the generalized Sturm criterion, the critical control gain for the delay-independent stability region and critical time delays for the stability switches are derived. The critical conditions can provide a theoretical guidance of chaotification design for line spectra reduction. Numerical simulations verify the correctness of the approach. Bifurcation analyses reveal that chaotification is more likely to occur in unstable region defined by these critical conditions, and the stiffness of the floating raft and mass ratio are the sensitive parameters to reduce critical control gain.

Energy Technology Data Exchange (ETDEWEB)

In an effort to improve the extrapolation of laboratory data to man and estimate risk of human reproductive toxicity associated with environmental exposure, the pharmacokinetic parameters of the testicular compartment are being studied. Of particular interest is the variety of enzyme systems capable of activating and detoxicating environmental chemicals and drugs. This report compares the metabolism of benzo(a)pyrene by the isolated perfused testis and testicular homogenates in vitro. The cell free in vitro system metabolized benzo(a)pyrene at a much greater rate than the perfused testis and produced a different spectrum of metabolites. Reliable laboratory prediction of biotransformation by the whole organ or intact animal is an essential aspect of reproductive toxicology.

International Nuclear Information System (INIS)

High (spatial) resolution imaging detectors for X-ray astronomy were developed. Several prototype detectors built and their feasibility and baseline performance were assessed. Two of these detector types are proposed for investigations on the advanced X-ray astrophysics facility (AXAF). The readiness of a new X-ray imaging system, the charge coupled device (CCD) imaging specctrometer is outlined, and state of the art performance parameters for microchannel plate (MCP) and CCD detectors are measured. Laboratory facilities and procedures for coating MCP are developed general high resolution imagery systems are analyzed.

British Library Electronic Table of Contents (United Kingdom)

The computational analysis of the model system consisting of the processes of CO2 assimilation and photorespiration shows the appearance of sustained oscillations in the system which might reflect their presence in photosynthesizing cells. Concentrations of CO2 and O2 oscillate in opposite phases causing Rubisco switching continuously between the carboxylase (CO2 assimilation) and the oxygenase (photorespiration) reactions. The results of modeling are consistent with carbon isotopic and other observed data. They show that the oscillation period varies from about 1 s to 3 s depending on the values of parameters taken. Too high concentrations of O2 suppress the oscillations.