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Selectivity control is a key issue in the zeolite facilitated conversion of methanol to hydrocarbons. This work addresses: (a) How the zeolite topology (MFI versus BEA) determines the type of intermediate participating in the catalytic cycle thereby controlling the ethene/propene product selectivity in the methanol to alkenes reaction, and (b) to what extent light alkene formation occurs via aromatic and alkene reaction intermediates for H-ZSM-5. Three catalyst samples have been studied in experiments relying on isotopic labeling. For H-beta, penta- and hexamethylbenzene are involved in an aromatics based hydrocarbon pool type mechanism leading predominantly to propene and the higher alkenes (a very low yield of ethene is observed), whereas for H-ZSM-5, the lower methylbenzenes are the aro...

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This document reports the results of testing of spent ion exchange media pretreatment technologies. Emphasis of the testing activities has been on screening pretreatment technologies, such as drying and emulsification, which are compatible with vitrification, cementation, and incineration. Ion exchange media tested for cementation and incineration pretreatment technologies were typical organic ion exchange resins and inorganic zeolites. The ion exchange medium tested for vitrification pretreatment technologies was inorganic zeolite. The results of testing activities are discussed in detail in this report.

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The overall objective of this research work was to prepare hydrocracking catalysts using amorphous silica-alumina (ASA) supports in combination with USY and {beta}-zeolites. Three supports: namely silica-alumina, USY and {beta}-zeolites were selected to prepare the extrudates using AP-1 as a binder, while two metal pairs: namely Ni-W and Ni-Mo were loaded on the extrudates through co-impregnation using incipient wetness technique. The catalysts were then calcined at 550C for 2h. The catalysts were tested in a fixed-bed flow reaction system for their activity, using desulfurized vacuum gas oil (DS-VGO) as a feedstock. The catalytic evaluation results of the catalysts showed that {beta}-zeolite alone and in combination with the ASA used in this study, has a potential as a support for developing heavy oil hydrocracking catalysts. A balance of weak and strong acidities of {beta}-zeolite ...

British Library Electronic Table of Contents (United Kingdom)

The evaluation of the bactericidal effect of different silver-containing materials where silver is available as Ag^+ (silver nitrate and different silver-exchanged zeolites), as metallic Ag^0 (commercial silver nanoparticles) or as oxide (silver (I) oxide) was carried out in order to elucidate the importance of the bioavailability of silver (i.e., as free ions, metallic particles, combination of them, clusters, complexes, partially soluble or insoluble salts, etc.) on its bactericidal action. For the different materials tested, their bactericidal effect is ordered in the following sequence: AgNO"3>Ag-ZSM-5>Ag"2O>commercial silver-exchanged zeolite (granular)>commercial silver-exchanged zeolite (pellets)>Ag nanoparticles. In general, as the content of bioavailable ionic silver increases, th...

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British Library Electronic Table of Contents (United Kingdom)

In this study, a two-step process was developed to produce biodiesel from Calophyllum inophyllum oil. Pre-treatment with phosphoric acid modified b-zeolite in acid catalyzed esterification process preceded by transesterification which was done using conventional alkali catalyst potassium hydroxide (KOH). The objective of this study is to investigate the relationship between the reaction temperatures, reaction time and methanol to oil molar ratio in the pre-treatment step. Central Composite Design (CCD) and Response Surface Methodology (RSM) were utilized to determine the best operating condition for the pre-treatment step. Biodiesel produced by this process was tested for its fuel properties.

British Library Electronic Table of Contents (United Kingdom)

Cobalt supported on Beta zeolite catalysts were prepared by impregnation of metal salts in aqueous solution and were tested for the Fischer Tropsch reaction. The support consisted of a Beta zeolite composed by crystallites of nanometric dimensions and a SiO2/Al2O3 molar ratio of about 50. This support was impregnated with Co(NO3)2 aqueous solution using different metal loads of 7.5, 10, 15 and 20wt% Co. These materials were characterized by X-ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM), N2 adsorption (BET), thermal programmed reduction (TPR) and FTIR of adsorbed pyridine (i.e., surface acid sites distribution). All the catalysts showed a significant catalytic activity for the F-T reaction from synthesis gas (CO+2H2), in a continuous fixed bed reactor sys...

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We investigate the possibility of an intrinsic Baldwin effect (i.e., nonlinear emission-line

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The leached glass is subject to leachant attack and results in surface layer alteration which greatly affects the corrosion progress of glass forms. This work studied the composition change, precipitation, pitting corrosion as well as surface layer break and spallation of the leached glass forms. 6 conclusions can be made: 1. The extent of surface layer alteration is related to many factors such as temperature, pH, leachant chemistry, flow rate and leach duration, etc. 2. The alkali element Na is seriously depleted and the elements like U.Ti,Fe, Ca and Mg are enriched in the surface layer. The influence of media has such order: Fe{sub 2}O{sub 3} > Na-bentonite > Zeolite. 3. The precipitate formed in leach test for 56 days at 90 {infinity}C is mostly amorphous, but after 91 days has crystallized. There is K - Ca - Al - Si crystal,the amount of Al, K and Si is increasing, but the amount of Ca is decreasing along with leaching time. ...

Science.gov (United States)

Certain materials, especially Sn, passivate the rare earth-exchanged Y zeolite (REY) used in petrochemical fluid-cracking catalysts against vanadium degradation caused by V impurities in the feed oil. The mechanism of passivation was investigated here from the standpoint of high-temperature oxide acid-base reaction; i.e., where the controlling factors were considered to be Lewis acid-base reactions between V{sub 2}O{sub 5}, the RE oxides, SnO{sub 2}, etc. Molten salt tests at 680{degree}C showed SnO{sub 2}, presumably because of its acidic nature, to be essentially nonreactive with V{sub 2}O{sub 5} or Na{sub 2}O-V{sub 2}O{sub 5} compounds. A hypothesis was developed to explain how the passivation effect by Sn might result from the unique resistivity of SnO{sub 2} to reaction with V{sub 2}O{sub 5}.

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This patent describes a catalyst comprising: (a) a non-zeolitic inorganic oxide matrix, and (b) an ultrastable Y-type crystalline zeolite, the ziolite having been pretreated by contacting the zeolite with a phosphorus compound selected from the group consisting of phosphoric acid, phosphorous acid, a salt of phosphoric acid, a salt of phosphorous acid, and mixtures thereof for a time sufficient to composite an effective amount of phosphorus with the zeolite.

Science.gov (United States)

A process is provided for conducting organic compound conversion over a catalyst composition comprising a supported crystalline zeolite having a high initial silica-to-alumina mole ratio, said supported zeolite being prepared by compositing said crystalline zeolite with alumina, reacting the composite with a particular hydrogen fluoride solution in a specified way, drying the hydrogen fluoride reacted composite, treating the dried composite by hydrolysis, ammonolysis and/or by contact with an ammonium salt solution, and calcining the resulting material.

International Nuclear Information System (INIS)

The efficiency of the synthesized zeolite NaY from rice husk ash (RHA) in the removal of Cr(III) from aqueous solution was studied. Zeolite NaY was synthesized from RHA via seeding technique and the identification of its structure was done by X-ray Diffraction (XRD) technique and the elemental analysis was carried out by X-ray Fluorescence (XRF). The physicochemical properties which were related to the use of the zeolite NaY as a sorbent was also investigated. The synthesized zeolite NaY has higher cation exchange capacity (CEC) than the commercial zeolite NaY due to the higher amount of sodium content in the synthesized as well as the lower ratio of silica to alumina. The synthesized zeolite NaY together with the commercial one as comparison was used in the sorption of the Cr(III) in aqueous solution by batch sorption experiments. The kinetic study showed that ...

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Hydrogenation of carbon monoxide at 101.3 kPa has been studied over a series of ion-exchanged Ru catalysts supported on NaX, NaY, KL, Na mordenite, and HY zeolites. The type of zeolite had pronounced effects on the activity and selectivity of the Ru. The specific activity would appear to be related to the dispersion of reduced ruthenium in the zeolite. Methane selectivity, however, seems to be strongly influenced by the type and concentration of alkali cations remaining in the ion-exchanged zeolite. These cations appear to promote chain growth much as traditional alkali promoters would, though perhaps more indirectly. Due to bifunctional properties of the zeolite-supported catalysts, a significant fraction of C/sub 4/ was in the form of isobutane. Formation of isobutane seems to be related to either the Si/Al ratio in the zeolites or the concentration of the ...

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The combined Lewis and Broensted acidities were measured of 13X (sodium) zeolite and of its 84.2% calcium-exchanged, 86.0% lanthanum-exchanged, and 69.2% protonated forms, calcined at 400/sup 0/C. The butylamine titrations were performed to visible color changes of Hammett indicators. The H/sub 0/ acidities were 0 for the sodium X zeolite, and 0.2, 0.98, and 0.75 for the calcium, lanthanum, and hydrogen zeolites, respectively. These acidities compared well with trends reported in literature for zeolites pretreated under different conditions. Titration of Broensted sites with arylmethanol indicators did not give satisfactory visible endpoints.

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An alternative to synthetic materials for use in solar pond liners is to select clayey soils as hydraulic barriers. This option reduces the cost of construction and the risk of contamination of subsoil and groundwater by hot brines. This paper deals with the physical, chemical and hydraulic properties of different soils tested mainly as compacted clay liners. The underdeveloped nations have the option to use this type of liner, but before doing so several tests are recommended, including those for soil and water composition, permeability, plasticity and X-ray diffraction analysis. In this investigation the following samples are analyzed: native clayey soils with illite, montmorillonite and halloysite, treated and non-treated bentonites in powder and granulated form, a mixture of zeolite and sodium bentonite, and industrial minerals composed largely of halloysite, kaolinite and attapulgite selected clays. Neutral salt ...

Science.gov (United States)

The progress of laboratory studies on the removal of NO/sub x/ and SO/sub 2/ with zeolite molecular sieves is reported. The trademark of these zeolite molecular sieves is Zeolon. (LK)

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Zeolite Y is the active component of most commercial cracking catalysts. Interaction of H[sub 3]PO[sub 4] with extraframework aluminum of ultra-stable zeolite (USY) leads to the formation of different types of aluminum phosphates, while there is no indication of the formation of SAPO zeotype structures. The total acidity of USY slightly decreases upon the H[sub 3]PO[sub 4] treatment, while the maximum in the distribution of acid strength is shifted to milder acidities. Dealumination of the zeolite and creation of POH sites associated with AIPO[sub 4] are responsible for the modifications observed. 37 refs., 8 figs., 3 tabs.

Science.gov (United States)

This paper obtains the acidity spectra of modernites and SVK-zeolites from the heats of adsorption of NH/sub 3/ at 300 C and compares the catalytic activity of these zeolites with the cracking of n-octane and the isomerization of o-xylene. It is shown that the calculation of the specific catalytic activity of centers of different strengths by the method of regional rates allows one to predict the activity of the zeolites from the acidity spectra. It follows from the calculation that only the centers of Bronsted acidity are active towards cracking but that the centers of Lewis acidity are also active towards isomerization.

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The effect of neutralizing cations on the secondary reactions of the primary products from CO hydrogenation over ion-exchanged zeolite-supported Ru catalysts was investigated using zeolites with different alkali cations (Li/sup +/, Na/sup +/, K/sup +/, Rb/sup +/, Cs/sup +/). The transformation of olefins (propylene and butene) on the zeolites without the metal, under conditions similar to those used for CO hydrogenation, was also studied in order to understand the effect of the various constituents of the support, i.e., the Broensted acid sites generated during catalyst preparation and the alkali cations, on possible secondary reactions of the primary olefinic products. It was established that secondary acid-catalyzed reactions of these primary products can play a major role in shaping product selectivity during CO hydrogenation over zeolite-supported catalysts. Depending on the concentration and the ...

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The research has involved the characterization of catalyst acidity, [sup 2]D NMR studies of Bronsted acid sites, and kinetic, calorimetric, and spectroscopic studies of methylamine synthesis and related reactions over acid catalysts. Approach of this work was to explore quantitative correlations between factors that control the generation, type, strength, and catalytic properties of acid sites on zeolite catalysts. Microcalorimetry, thermogravimetric analysis, IR spectroscopy, and NMR spectroscopy have provided information about the nature and strength of acid sites in zeolites. This was vital in understanding the catalytic cycles involved in methylamine synthesis and related reactions over zeolite catalysts.

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International Nuclear Information System (INIS)

Russian (Jan 1978). USSR Chorna, IM Beshta, EI Kvitkovskij, LN L'vovskij

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A phosphorus-containing low alkali metal content zeolitic catalyst made from a clay starting material is provided. The catalyst is obtained by contacting a partially cation exchanged calcined zeolite-containing catalyst with a dihydrogen phosphate anion or a dihydrogen phosphite anion. A hydrocarbon catalytic cracking process utilizing the phosphorus-containing catalyst is also provided.

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Clays and zeolites are among the most important of natural dusts by virtue of their occurrence through out the world on the earth`s surface and their important industrial uses. (The 1:1 layer silicates, including the serpentine and kaolin minerals, are not addressed in this chapter.) This chapter provides basic information on a variety of important aspects of each mineral, including crystal structure diagrams of each and references to more detailed discussions. 110 refs., 20 figs.

British Library Electronic Table of Contents (United Kingdom)

The catalytic performance of alkaline-treated zeolite H-ZSM-5 in the conversion of methanol to gasoline has been studied. After treatment with 0.20M NaOH, the total conversion capacity increased by a factor of 3.3, and the selectivity towards the gasoline fraction increased by a factor of 1.7. Physical characterization indicated the formation of mesopores and improved crystallinity.

CERN Document Server

Historically, emission lines have been considered a valuable tool for estimating the bolometric thermal luminosity of the accretion flow in AGN, $L_{bol}$. We study the reliability of this method by comparing line strengths to the optical/UV continuum luminosity of SDSS DR7 radio quiet quasars with $0.4H$\\beta$ and Mg II, as well as the narrow lines of [O III] and [O II]. We determine the standard errors of the formulae that are fitted to the data. Our new estimators are shown to be more accurate than archival line strength estimations in the literature. It is demonstrated that the broad lines are superior estimators of the continuum luminosity (and $L_{bol}$) with $H\\beta$ being the most reliable. The fidelity of the each of the estimators is determined in the context of the SDSS DR7 radio loud quasars as an illustrative ...

Science.gov (United States)

The work presented in part 1 of this study established that the sorption of anhydrous HX into dehydrated Na{sub 56}Y progresses through a sequence of steps involving HX ionization and charge separation, oxygen framework protonation, formation of {alpha}-cage confined cation-anion contact ion pairs, and proton solvation by HX. A logical extension, which is the subjected of this study, concerns the effect of extraframework alkali metal cation type (M = Li{sup +}, Na{sup +}, K{sup +}, Rb{sup +}, Cs{sup +}) on the sorption process. The question of the acidity of proton-loaded zeolites compared to Broensted acid zeolites is addressed by using probe reactions with weak bases like ethane and cyclopropane. Additional insight into these systems is also obtained from a quantitative comparison of the kinetic and thermodynamic activation parameters for the dehydrohalogenation of proton-loaded zeolites exemplified by (HX){sub 8}Na{sub ...

Science.gov (United States)

The nature of extralattice aluminum and its effect on acidity in zeolites was studied. A series of zeolites (some commercial), dealuminated by various methods, were obtained having Si/Al ratios between 1.5 and 20. These were characterized using volumetric sorption, XRD, AA, NMR, and reaction studies. Samples dealuminated using ammonium hexafluorosilicate were found to contain little or no extralattice aluminum. In contrast, steam-dealuminated zeolites had large amounts of extralattice aluminum. In some cases a significant portion of the extralattice aluminum was unobservable by [sup 27]Al NMR, suggesting the existence of an aluminum species of low symmetry. Proton NMR indicated that all the protons were associated with the lattice aluminum atoms. Depending on the preparation history, different groups of H-Y zeolites exhibited different maxima in catalytic activity as a function of aluminum content. The ...

Science.gov (United States)

Under different sintering temperatures(340 degrees C, 440 degrees C, 540 degrees C, 640 degrees C), four TiO2 particles were prepared. The crystal types of all four samples were found to possess anatase structures by XRD. It was obtained by N2 experimental adsorption at low temperature (77K) that their surface areas and average pore size were between 79 and 124 m2/g, 56.8 and 254.8 A respectively. The pore structure of TiO2 particles was characterized by scanning electron microscope (SEM). The tests of adsorption dynamics for FGD and the performance of SO2 removal were investigated in a fixed-bed system for different samples. The results show that SG540 sample which made at 540 degrees C sintering temperature had the most quality among the four samples. It can adsorb SO2 of 38.9 mg for one gram SG540 sample. Different operating conditions for SG540 such as adsorption temperature, SO2 concentration in flue gas and the superficial velocity of flue gas were ...

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The present paper is a comparative study of the cerium-containing nickel catalysts supported on x- and y-zeolites. In general, the addition of cerium ions caused an increase in the catalytic activity for CO hydrogenation and shifted the product selectivity to high molecular weight hydrocarbons. The degree of the effect of cerium additive depends on the ratio of cerium to nickel contents, the reduction temperature, and the nature of the supporting materials. Catalyst characterization, including volumetric hydrogen chemisorption, temperature programmed reduction/desorption, x-ray diffraction, surface area measurements, in-situ infrared spectroscopy and x-ray photoelectron spectroscopy, was performed in order to interpret the phenomena due to the effects of cerium additives and the support effect on Ni/zeolite catalysts.

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We have obtained convincing evidence for localization of the optical electron on a single-ring fragment of a chelated bipyridine-like'' ligand (ie., pyridylpyrazine or 4-Methyl-bipyridine). In addition we have completed studies of Ru(bipyrazine){sub 3}{sup 2+} in aqueous sulfuric acid (0--98% by weight) and find clear evidence for sequential addition of six-protons to the six peripheral nitrogen atoms. Studies of zeolite-entrapped complexes are continuing and a series of homo- and heteroleptic complexes have been prepared and characterized. Finally, the synthesis of zeolite-entrapped metallophthalocyanines has now been developed and the copper and cobalt analogues synthesized. The characterization of these materials is now in progress.

International Nuclear Information System (INIS)

When clinoptilolite is immobilized in cement-based composites, a series of reactions occur, leading to release of Cs. These reactions occur in three overlapping stages: a rapid ion exchange, followed by a somewhat slower reaction between clinoptilolite and principally the Ca(OH)_2 component of cement, and, in the longer term, slower reactions with C-S-H leading either to formation of low-lime C-S-H at temperatures below 100"0C or 11 A (1.1 nm) tobermorite at higher temperatures. Kinetic data are presented to evaluate the rate of physical consumption of the zeolites at 70 and 150"0C. Reactions occurring above 100"0C appear to result in the development of extensive microcracking of cement-zeolite composites containing 50% zeolite.

International Nuclear Information System (INIS)

A research was started aiming at evaluating the possible use of natural zeolites as exchange conditioners to improve and make durable the soil resilience against the adverse effects of the use of anomalous waters for irrigation purposes. This paper deals with a preliminary investigation on the comparative resilience of an Entisol with poor exchange properties and of a Neapolitan yellow tuff (NYT) sample against the adverse features of a dirty municipal sewage (DSW). Results showed that NYT treatment largely and significantly improved the poor soil exchange activity. In particular. NYT exchange sites selectively took up ammonium from DSW. As a consequence, ammonium was trapped, then protected against losses in the environment and, concurrently, exchangeable cations, such as K and Ca, were made free as plant nutrients. The results highlight the possible positive role of zeolitized tuff in restoring and sustaining soil resilience.

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The N{sub 1s} XPS band of pyridine chemisorbed on Al-ZSM-5 zeolite was found to be properly deconvoluted into three component peaks. In a previous contribution these three components were assigned to pyridine chemisorbed on two kinds of Bronsted acid sites and one Lewis acid site. This analysis is extended here to Fe-ZSM-5 and B-ZSM-5. Isomorphous substitution of Fe for Si or Al in the zeolite framework leads to a slight decrease in the binding energy of the N{sub 1s} Lewis component. In the case of B substitution a decrease in the binding energy of all three N{sub 1s} components is observed.

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A catalytic process for the oxidation of sulfur-containing gases , E.G., sulfur dioxide and simultaneous production of sulfuric acid wherein a sulfur-containing gas is reacted with an oxygencontaining gas in the presence of a catalyst comprising an iron group metal on a solid support comprising a zeolite in a silicaalumina matrix.

International Nuclear Information System (INIS)

This paper reports on the superiority of zeolites over amorphous solids which is well documented for solid acid catalysts of industrial use. Crystalline supports, likewise, open attractive perspectives for catalysis by metals, alloys, and ligated metal clusters. Size and location of clusters can be controlled by careful design of the preparation conditions. Pore dimensions control the access of reactants to active sites and escape paths for products. Cage dimensions determine which transition states can be attained; window apertures are functional in isolating metal clusters from each other, thus preventing ther coalescence and growth. The ship-in-a-bottle method permits deisgn of fairly large active complexes entrapped in zeolite cages. Orientation of non-spherical molecules in a zeolite proe helps to direct their collision with a metal particle to the head on mode; however, isolated Pt atoms hidden in niches of the pore ...

Science.gov (United States)

Recently there has been considerable interest in the Cu-ZSM-5 catalysts for the selective reduction of NO by light hydrocarbons for the purpose of atmospheric pollution abatement. Isobutane and n-pentane cracking were studied over Cu zeolite catalysts and these results were compared with their HY analogues at low conversions and at temperatures of 673 K and below. Three forms of the catalysts were used: those reduced in CO at 773 K; those reduced with H[sub 2] at 473 K; and those in the oxidic form (following flushing with He at 773 K). In contrast with an earlier publication, very little difference in activity was found between the two reduced forms of the catalysts did not differ significantly from each other nor from the H-form of the zeolite. They are typical of a Bronsted acid catalysis. The oxidic form of the catalyst produced excess H[sub 2] in increasing amounts with time on stream. This could be quantitatively accounted for by the ...

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Several possibilities of the use of molecular models in quantum-chemical investigations of the structure of defect centers on the surfaces of oxides on nontransition elements have been illustrated. There has been a special discussion of the assumption of the local nature of the chemical interactions in these systems, which underlies such an approach, and of the consequent laws governing the formation of their lattices in the example cases of zeolites, kaolinites, and comparable boron- and aluminum-containing oxides. A quantum-chemical interpretation of the body of experimental data from investigations of the dehydroxylation of H forms of zeolites has been given. The structure of the Lewis acid centers formed as a result, and their chemisorption properties, have been discussed.

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SO/sub 2/ adsorption onto faujasite-type zeolites (Na-X, Na-Y) was investigated by combined UV and IR spectroscopy. Formation of chemisorbed HSO/sub 3//sup -/ species, indicated by a UV band around 215 nm and a low-frequency IR band at 1240 cm/sup -1/, was shown to depend significantly upon the presence of water. Differences in the behavior of Na-X and Na-Y were discussed in terms of different site populations.

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Nanocrystalline zeolites with discrete crystal sizes of less than 100 nm have different properties relative to zeolites with larger crystal sizes. Nanocrystalline zeolites have improved mass transfer properties and very large internal and external surface areas that can be exploited for many different applications. The additional external surface active sites and the improved mass transfer properties of nanocrystalline zeolites offer significant advantages for selective catalytic reduction (SCR) catalysis with ammonia as a reductant in coal-fired power plants relative to current zeolite based SCR catalysts. Nanocrystalline NaY was synthesized with a crystal size of 15-20 nm and was thoroughly characterized using x-ray diffraction, electron paramagnetic resonance spectroscopy, nitrogen adsorption isotherms and Fourier Transform Infrared (FT-IR) spectroscopy. Copper ions were ...

Science.gov (United States)

We report the existence of a previously unsuspected peak in the [sup 1]H magic angle spinning spectrum of commercially available HZSM-5 samples. At 298 K, this resonance is a broad shoulder on the downfield side of the Bronsted acid signal at 4.3 ppm. Cooling the sample caused the line to narrow, and a clear peak at 6.9 ppm was visible at 123 K. This technique resulted in selective broadening of the 4.3 and 6.9 ppm resonances as a result of conflicting averaging of the [sup 1]H-[sup 27]Al dipolar coupling. We conclude that the 6.9 ppm resonance corresponds to a novel aluminum-containing site in zeolite HZSM-5 and is not an artifact due to exchange with the Bronsted site or an aluminum-rich impurity phase. A possible interpretation of these results is a second Bronsted site for the zeolite. 49 refs., 8 figs.

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The selective catalytic reduction of nitric oxide by methane over copper ion-exchanged natural zeolites was investigated in a packed-bed tubular reactor. The catalytic activity of Cu-N and Cu-H-N catalysts was confirmed as NO, CH{sub 4}, and O{sub 2} displayed very little reaction in the absence of any catalyst and zeolite without ion exchange was totally inactive. A maximum NO conversion of 33% at 650 C for Cu-N-66 was achieved with 2% NO and 1% CH{sub 4} and a contact time of 0.9 g s/cm{sup 3}, but the introduction of 2% O{sub 2} reduced the NO conversion to only 12%. Ion exchange for the H-form prior to copper ion exchange was essential for oxygen to promote catalytic activity over the temperature range 250--650 C, with a maximum conversion of 30% at 450 C with O{sub 2} present. The direct reduction of NO by methane was ruled out as a possible reaction pathway.

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This thesis is in the field of gas emission control from automobile and stationary sources. Out of the possible approaches to the elimination of pollutant gases, such as nitrogen oxides (NO{sub x}), one consists in the selective catalytic reduction (SCR) of these NO{sub x} on a suitable heterogeneous catalyst. Ammonia or hydrocarbons are employed as reducing agents. The most important catalysts active in the SCR of NO{sub x} are based on ions of transition metal either supported on several oxides or dispersed in zeolites. The catalysts have been characterized by electron magnetic resonance techniques (EPR, ENDOR, ESEEM) and the interaction of catalysts with nitrogen oxides, with reducing and poisoned agents have been followed with the same techniques. Copper dispersed on alumina and its interaction with both NO and ammonia has been investigated. Also the interaction between both water and ammonia with copper dispersed in zeolite ZSM-5 has been ...

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The photocatalyzed degradation of pyridine in the gas phase was investigated using titanium dioxide semiconductor supported on mordenite. The complete mineralization was found to occur over a catalyst containing 75 wt% TiO{sub 2} and 25 wt% mordenite in about 180 min in the presence of saturated water vapor at O{degrees}C (4.6 Torr). Low water vapor pressure of 0.096 Torr was found to be sufficient to achieve a reasonably high percentage and rate of degradation. Diffusion of pyridine within the catalyst adversely affects the activity when the thickness of the catalyst coating exceeds the penetration depth of illumination. The activity of the zeolite-supported catalysts was higher than that of TiO{sub 2}. The photonic efficiency for the complete mineralization of pyridine to CO{sub 2} was determined to be 0.48. 29 refs., 6 refs., 1 tab.

International Nuclear Information System (INIS)

Potassium clusters arrayed in zeolite A are known to show ferromagnetic properties at low temperature. The origin of the spontaneous magnetization has been explained by a model of spin-canting in an antiferromagnetically ordered state. The direct information for the magnetic structure, however, has not been obtained so far. In the present work, we measure the neutron powder diffraction by using pulsed neutron source at KEK-KENS below and above the Curie temperature. No significant temperature-dependence was, however, obtained within the statistical errors, namely, magnetic scattering could not be detected separately. We also estimate the intensity of magnetic scattering by assuming some possible magnetic structures with considering the magnetic form factor of the cluster wave function. The intensity of magnetic scattering is estimated to be extremely weak and higher S/N of ?104 or more is required to detect the magnetic scattering of this material.

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The increasing use of quantum-chemical methods in catalysis has underscored the importance of developing and improving semiempirical approximations oriented toward calculations of the total energy and geometry, offering a means for examining intermolecular interactions. In this article a general approach is proposed, using weighting factors for certain regions of distances, i.e., introducing different parametrization into the various regions. A scheme designated MINDO/3-HB is presented as an extension of the MINDO/3 scheme to the region of hydrogen bonds and ..pi..-complexes of olefins with Broensted acid centers (BACs). Examples of cluster calculations are given for the adsorption of ammonia, pyridine, ethylene, and ethanol on the BACs of zeolites. In the example of the process of zeolite synthesis, the possibilities of the cluster approach are discussed for calculations related to the formation of catalysts.

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A Selective Catalytic Reduction (SCR) catalyst was prepared by slurry coating ZSM-5 zeolite onto a cordierite monolith, then subliming an iron salt onto the zeolite, calcining the monolith, and then dipping the monolith either into an aqueous solution of manganese nitrate and cerium nitrate and then calcining, or by similar treatment with separate solutions of manganese nitrate and cerium nitrate. The supported catalyst containing iron, manganese, and cerium showed 80 percent conversion at 113 degrees Celsius of a feed gas containing nitrogen oxides having 4 parts NO to one part NO.sub.2, about one equivalent ammonia, and excess oxygen; conversion improved to 94 percent at 147 degrees Celsius. N.sub.2O was not detected (detection limit: 0.6 percent N.sub.2O).

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An amorphous mesoporous titania-silica aerogel (20 wt%TiO{sub 2} - 80 wt% SiO{sub 2}) and tert.-butylhydroperoxide (TBHP) have been used for the epoxidation of various allylic alcohols. Allylic alcohols possessing an internal double bond were more reactive than those with a terminal C=C bond. Epoxide selectivities could be improved by addition of (basic) zeolite 4 A and NaHCO{sub 3} to the reaction mixture. (orig.)

UK PubMed Central (United Kingdom)

Outbred Wistar rats were immunised with a single intraperitoneal injection of a mixture of 30 mg of A1(OH)3 and 100microng of gonococcal zeolite antigen (ZA). Ten days after immunisation, ZA prepared...Full Text Available

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Most chemical reactions in industry and biology are catalytic and play a role at some stage of the processing of about 80% of the goods manufactured in the U.S., yet catalysis is a neglected subject in chemical education. This book integrates the fragmentary treatment accorded the topic until now. It covers, in a unified way, catalysis in solutions, by enzymes, in synthetic polymers within the molecular scale cages of zeolites and other molecular sieves, and on surfaces of inorganic solids. The central ideas are chemical; and principles are illustrated by emphasizing industrial reactions and catalysts.

International Nuclear Information System (INIS)

The crystal structure of outer surface protein A (OspA) from Borrelia burgdorferi contains a single-layer #beta#-sheet connecting the N- and C-terminal globular domains. The central #beta#-sheet consists largely of polar amino acids and it is solvent-exposed on both faces, which so far appears to be unique among known protein structures. We have accomplished nearly complete backbone H, C and N and C";/H"#beta# assignments of OspA (28 kDa) using standard triple resonance techniques without perdeuteration. This was made possible by recording spectra at a high temperature (45 "oC ). The chemical shift index and "1"5N T_1/T_2 ratios show that both the secondary structure and the global conformation of OspA in solution are similar to the crystal structure, suggesting that the unique central #beta#-sheet is fairly rigid.

Energy Technology Data Exchange (ETDEWEB)

Calcined and sulfided Ni-Mo catalysts supported on ultrastable Y zeolite (USY), NaY zeolite, mordenite, and ZSM-5 were studied by high-resolution electron transmission microscopy (HRTEM) with selected-area electron diffraction (SAED) and energy-dispersive spectroscopy (EDS). Ni and Mo oxide aggregates were rarely observed in the USY-supported Ni-Mo catalyst, indicating that most of Ni and Mo may be incorporated into USY, e.g., supercavities and possibly sodalite cages. However, there were a large number of {alpha}-NiMoO{sub 4} aggregates of different particle sizes in NaY-, mordenite-, and ZSM-5-supported catalysts, and the mordenite-supported catalyst also contained MoO{sub 3} crystals. The {alpha}-NiMoO{sub 4} may be attached to the surface of substrates as individual particles or needle aggregates, it may be disseminated into mordenite particles, or it may even form an isolated sphere (in Ni-Mo/NaY) or a needle (in Ni-Mo/ZSM-5) aggregates. ...

British Library Electronic Table of Contents (United Kingdom)

Reaction between [V^I^VO(acac)2] and the ONN donor Schiff base Hpydx-aepy (I) (Hpydx-aepy=Schiff base obtained by the condensation of pyridoxal and 2-aminoethylpyridine) resulted in the formation of a complex [V^I^VO(acac)(pydx-aepy)] (1). Addition of aqueous 30% H2O2 to 1 yields the poor stable oxidoperoxidovanadium(V) complex [V^VO(O2)(pydx-aepy)] (2). Its formation has also been demonstrated in solution by treating 1 with H2O2 in methanol. Reaction of vanadium exchanged zeolite-Y with I in methanol followed by aerial oxidation gave zeolite-Y encapsulated dioxidovanadium(V) complex, abbreviated as [V^VO2(pydx-aepy)]-Y (4). The crystal and molecular structure of 1 has been determined, confirming the ONN binding mode of the ligand. The encapsulated complex [V^VO2(pydx-aepy)]-Y (4) catalyse...

Energy Technology Data Exchange (ETDEWEB)

Petrographic research for the Nevada Nuclear Waste Storage Investigations focused on xenolithic variability in the Topopah Spring Member and on variations of clinoptilolite composition at Yucca Mountain. Zeolite and smectite occurrences were considered in terms of their relation to a disturbed zone beneath the potential repository, and mineral stability experiments have produced a new clinoptilolite structure as a result of prolonged heating at low temperature. Limitations were defined on the abundance of erionite and of sulfur. X-ray diffraction studies lead to improved analytical methods. Progress was made in the comparative study of mineralogy in sand ramps and in faults. Geological modeling considered the differences of the diffusion of nonsorbing tracers in vertically and in horizontally fractured rock. Modeling also treated the diffusion of a nonsorbing tracer in devitrified and in zeolitized rock. The results of these experiments in all ...

International Nuclear Information System (INIS)

Propylene polymerizations were carried out with #phi#_2C(Flu)(Cp)ZrCl_2 and SiMe_2(Ind)2ZrCl_2 catalysts supported on silica, zeolite sodic mordenite (NaM) and acid mordenite (HM). The polymerizations were performed at different temperatures and varying aluminium/zirconium molar ratios ([Al]/[Zr]). The effect of these reaction parameters on the catalyst activity was investigated using a proposed statistical experimental planning. In the case of f_2C(Flu)(Cp)ZrCl_2, SiO_2 and NaM were used as support and the catalyst performance evaluated using toluene and pentane as polymerization solvent. The molecular weight, molecular weight distribution, melting point and crystallinity of the polymers were examined. The results indicate very high activities for the syndiospecific heterogeneous system. Also, the polymers obtained had superior Mw and stereo regularity. (author)

Scientific Electronic Library Online (English)

Abstract in english Higher olefins are produced as a by product in a number of refinery processes and are one of the potential raw materials to produce propylene. In the present study, FCC model feed compound was considered to explore the olefin cracking features and options to enhance propylene using 30% SAPO-34 zeolite as catalyst in a micro-reactor. The superior selectivity of propylene (73 wt%) and higher total olefin selectivity was obtained over 30% SAPO-34 catalyst than over Y or ZSM- (more) 5 zeolite catalysts. The thermodynamical constraints were found to be relatively less serious in the case of 1-hexene conversion. Most of the 1-hexene follows a direct cracking pathway to give two propylene molecules, due to weak acid sites and better diffusion opportunities. The higher temperature and short residence time could also suppress the hydrogen transfer reactions. From OPE (olefins performance envelop) the products were classified as ...

Energy Technology Data Exchange (ETDEWEB)

Cyclopropane isomerization to propylene over various Eu[sup 3+] loadings in NaX zeolite have been studied by measurements of steady-state and transient kinetics and by Fourier transform infrared spectroscopy. As Eu[sup 3+] loading increases, the rate of deactivation increases, the conversion increases, apparent activation energies are lowered, and Bronsted acid site strength and amounts increase. Apparent activation energies of 13-15 kcal/mol for propylene formation have been observed for these systems, consistent with literature reports for other metal supported heterogeneous catalyst systems. Deactivation studies have shown that activity can be restored by heating in He at 380[degrees]C between various temperature runs, and that gases desorbed during regeneration are predominantly propylene. Poisoning studies of Bronsted sites with Na vapor lead to deactivation of these catalysts. A reaction mechanism scheme based on [pi] allyl intermediates in the supercages of ...

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A research program has been initiated to screen and select electrolyte materials for use in steam electrolyzers in the 300-600/sup 0/C temperature range. Screening of a significant number of acid anhydrides, hydroxides, oxides, and phospates for their electrolytic conductivity properties is underway. Of the binary materials examined to date, only polymerized phosphoric acid, immobilized on an H/sup +/ substituted zeolite, shows promise. A substantial number of ternary compounds remain to be synthesized and evaluated.

Science.gov (United States)

Feasibility of depositing continuous films of nano-porous alumino-silicates, primarily zeolites and MCM-41, on metallic and non-metallic substrates was examined with an aim to develop membranes for separation of gaseous mixtures and also for application as hydrogen storage material. Mesoporous silica was deposited in-side the pores of these nano-porous disks with an aim to develop membranes for selective separations. Our study involves supported zeolite film growth on substrates using in-situ hydrothermal synthesis. Faujasite, Silicalite and Mesoporous silica have been grown on various metallic and non-metallic supports. Metallic substrates used for film growth included anodized titanium, sodium hydroxide treated Titanium, Anodized aluminum, and sintered copper. A non-metallic substrate used was nano-porous aluminum oxide. Zeolite film growth was characterized using Scanning Electron Microscope (AMRAY 1820) and High ...

International Nuclear Information System (INIS)

Short communication.

CERN Document Server

Metals and alloys : atmospheric corrosion testing : General requirements for field tests

Energy Technology Data Exchange (ETDEWEB)

Neopentane, because of its unique structural features, was found to be a useful probe for the assay of the acidity of various zeolites. The C-C bond was attacked by catalyst protons yielding CH/sub 4/ and the isobutyl carbenium ion in equal quantities. The latter either decomposed to produce isobutene or underwent secondary reactions. New avenues for reaction were opened with isobutane. The reaction of the Bronsted protons with the tertiary CH bonds produced H/sub 2/ and the same isobutyl carbenium ion. Hydride ion transfer of the same tertiary hydrogen to existing carbenium ions also occurred and the results showed that about half of the reaction was carried by this pathway. As with Neopentane, the C-C bond could also be attacked yielding the sec-propyl carbenium ion. These tools are being further developed.

Science.gov (United States)

Within the framework of the cluster approach and the semiempirical SCF MO LCAO method in the CNDO/BW valence approximation, possible pathways have been compared for the dehydroxylation of aluminosilicate systems. It has been shown that dehydroxylation as a result of splitting of a water molecule from an acidic bridge hydroxyl group and a more basic terminal group Al-OH is the most energyfavorable. Apparently, such a dehydroxylation pathway is primarily characteristic for amorphous aluminosilicates. Typical of crystalline aluminosilicates at moderate heat-treating temperature is dehydroxylation through splitting of a water molecule from an acidic bridge hydroxyl group and a neutral Si-OH group; at higher temperatures, there is a possible pathway of dehydroxylation of highsilica zeolites as a result of condensation of two acidic surface hydroxyls.

Energy Technology Data Exchange (ETDEWEB)

The invention is regeneration and recirculation of nitrogen oxides in the exhaust gas of a nitric acid plant without using any material current and heat energy other than that generated in the process of producing nitric acid. Nitrogen oxide is recovered by at least two adsorbers each containing an acid resistant zeolite molecular sieve and operating in an alternate heat cycle; adsorption occurring at 20-40 degrees C and regeneration at 300-350 degrees C. The hot gas exiting from the oxidation U used in the production of nitric acid is used to regenerate the adsorbers and the nitrogen oxides set free during the said regeneration are introduced into the main feed stream of the nitric acid plant. In the final stage of the regeneration the adsorbers are cooled by rinsing them with exhaust gas or air at a temperature of 20-40 degrees C.

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This paper is a review concerning the application of Nuclear Analytical Techniques in the Cuban sugar industry. The most complete elemental composition of final molasses (34 elements) and natural zeolites (38) this last one employed as an auxiliary agent in sugar technological processe4s has been performed by means of instrumental Neutron Activation Analysis (INAA) and X-Ray Fluorescence Analysis (XRFA). The trace elemental sugar cane soill-plant relationship and elemental composition of different types of Cuban sugar (raw, blanco-directo and refine) were also studied. As a result, valuable information referred to the possibilities of using these products in animal and human foodstuff so as in the other applications are given. (author). 34 refs., 6 figs., 1 tab.

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Counter-current regeneration of 2-stage sodium zeolite softeners has been employed in reducing hardness leakage level of steamflooding water to less than 1 ppm when raw water contains as much as 5,000 ppm of the total dissolved solids. Hardness leakage is caused by sodium displacement of calcium and magnesium from the bottom of the exchanger bed. This study presents nomographs providing for rapid calculations to be made, for which a convenient operational mode does not already exist. The nomographs relate the hardness leakage as a function of salt quality and influent water quality and present solutions for predicting the leakage level, salt quality requirement or the treatability of raw water required for steamflooding projects.

Energy Technology Data Exchange (ETDEWEB)

Very high cobalt catalysts have been prepared on steamed and acid-washed y zeolite. These catalysts are very active. Some of them have proven to be very stable. Additionally, if provisions are made to control the temperature build up on the catalyst bed, low methane selectivities result. Additional work is indicated, for instance, perhaps even higher activity catalysts can result from higher levels of cobalt or changes in the catalyst preparation procedure. Since the issue of whether small amounts of ruthenium can promote the catalyst is not completely resolved, catalyst preparation procedure experiments should continue with ruthenium vs. ruthenium-free catalysts. For instance, different methods of impregnation and/or activation should be investigated.

Energy Technology Data Exchange (ETDEWEB)

The trend towards more effective use of fossil fuels and reduced environmental pollution represents a major task of improvement within the refinery processes. The highly isomerized and high octane paraffins produced from isobutane and light olefins by alkylation fulfill all the requirements for reformulated gasoline. This doctoral thesis discusses new catalyst systems because of their potential in alkylation. A slurry reactor apparatus for solid-acid catalysed isobutane/butene alkylation was developed and used to investigate the performance of various heterogeneous catalysts. The selected materials were mainly zeolite types with faujasite structures. The samples were characterized by various methods before alkylation. In general, the order of decreasing catalyst activity after 3 h of reaction at 80{sup o}C was found to be: H-EMT >> H-FAU, dealuminated H-FAU >> NS.500, TA-Y, CeY-98 > Nafion-H. The order of decreasing alkylate selectivity of the ...

Energy Technology Data Exchange (ETDEWEB)

The catalytic nature of Mo(CO)/sub 6/ supported on ..gamma..-Al/sub 2/O/sub 3/, KOH-doped ..gamma..-Al/sub 2/O/sub 3/, and HY-zeolite was investigated in CO oxidation with N/sub 2/O in comparison with that of a conventional partially reduced MoO/sub 3//..gamma..-Al/sub 2/O/sub 3/ catalyst. Kinetic parameters of this reaction were obtained in the range 0 to 100/sup 0/C; the rate law r = kP/sub N/sub 2/O//sup 1/P/sub CO//sup 0/ was found on all catalysts, and the activation energy was estimated to be 9.1 kcal/mol on the Mo(CO)/sub 6/-derived catalysts and 7.1 kcal/mol on the partially reduced MoO/sub 3//..gamma..-Al/sub 2/O/sub 3/ catalyst. Maximum catalytic activities were obtained by activating the Mo(CO)/sub 6/-derived catalysts at 400/sup 0/C. To obtain similar activity on the MoO/sub 3//..gamma..-Al/sub 2/O/sub 3/ catalyst, it was necessary to reduce at 600/sup 0/C. The former catalysts were deactivated on repeating the reaction. On the basis of these results ...

Science.gov (United States)

The procedure describes the procedures to be used in evaluating consumable and combustible cartridge cases. Included are ballistic tests, environmental tests, adverse condition tests, fungus resistance tests, drop tests and safety tests. (Author)

Science.gov (United States)

Our research in the general area of acid catalysis involves the characterization of solid acidity and the corresponding assessment of catalytic performance of acidic materials. Acid characterization studies are required to provide essential information about the type of acid site (i.e., Lewis versus Bronsted), the strength of the sites, and the mobility of molecules adsorbed on the acid sites. An accurate measure of acid strength is given by the heat of adsorption of a basic probe molecule on the acid site. A thermodynamic representation of the mobility of adsorbed species on these sites is given by the entropy of adsorption. Important techniques used in these acid site characterization studies include microcalorimetry, thermogravimetric measurements, temperature programmed desorption, infrared spectroscopy and solid state nuclear magnetic resonance. The combination of these acid site characterization studies with reaction kinetics measurements of selected catalytic processes allows ...

Science.gov (United States)

Catalytic reactions of 3-methylpentane and 2,3-dimethylbutane on HY, amorphous silica-alumina, and HZSM-5 have been studied at 500{degree}C. Both kinetic phenomena and product selectivities have been reported. Cracking reactions an HZSM-5 can be attributed to initiation through protonation occurring at Bronsted sites. Bimolecular processes leading to chain reaction via hydride transfer are restricted within the narrow pore pentasil zeolite. On HY and amorphous silica-alumina, initiation of cracking also occurs at Bronsted sited. No direct evidence was found for participation of Lewis acid sites on the catalyst framework itself. Following initiation, reactions on these catalysts are accelerated through a chain process occurring at Lewis sites generated by adsorption of product olefins at Bronsted sites. The resulting change in the dominant cracking mechanism is reflected in the product selectivity, illustrated here by a falling off in formation of molecular hydrogen ...

Science.gov (United States)

A pyrochemical partitioning process has been conceptually designed so that the transmutation of spent LWR fuels in PEACER can produce mainly low-level waste (Class C waste) for near-surface burial. Chloride salt technology developed for IFR has been employed as the baseline. Electrorefining, reductive extraction and salt recycling steps are used to construct overall flowsheet in order to support PEACER operation. The decontamination factor for transuranic elements was estimated based on both thermodynamic models and reported experimental data. It is expected that overall decontamination factor can be as high as 10{sup 5} for transuranic elements. Final wastes from pyrochemical processing for PEACER are noble metals, alkaline earth metal, and lanthanides. The final wastes are stabilized by mixing with zeolite and glass-frits such that concentration limit for class C waste can be met. The volume of Class C waste is estimated to be small enough to make PEACER concept ...

International Nuclear Information System (INIS)

This paper demonstrates that a commercial-scale facility for encapsulating krypton-85 in zeolite-5A or glass at a 2000 MTHM per year nuclear fuel reprocessing plant can be designed to contain fragments and the 340 to 850 kCi krypton-85 inventory from an assumed catastrophic failure of the high pressure vessel. The vessel failure was assumed as a worst case and was not based on a detailed design evaluation or operating experience. The process design is based on existing commercial hot isostatic pressing technology operated at up to 40 times the scale required for krypton encapsulation. From the calculated process gas inventory in the pressure vessel and vessel design, the maximum explosive energy of 8.4 kg TNT and resulting vessel plug and fragment velocities were calculated. The facility Containment Cell housing the high pressure vessel was designed to contain the gases, fragments, and the shock wave energy calculated for a hypothetical vessel failure. The Access ...

Environmental Research Database

ObjectivesThe overall aim of this work is to use an in-situ FTIR probe to investigate selected heterogeneous catalysts in industrially relevant organic reactions. This approach will be broadly applicable to the UK fine chemical manufacturing base.~%~~%~The project has the following specific objectives:~%~~%~- To demonstrate and develop the use of an in-situ FTIR probe in a batch reactor at elevated temperatures (eg greater than 100 deg C) to monitor reactant usage and product formation.~%~~%~- To validat [continued...]DescriptionThis proposal concerns the in-situ study of catalytic processes and reaction kinetics. The catalysts concerned are microporous materials, such as, zeolites, containing pores and cavities of molecular dimensions. These catalysts constitute crystal reactors on a nanometer scale that are selective on a size and shape basis for organic molecules used in this ...

Science.gov (United States)

... Accession Number : ADD457408. Title : FIELD CORROSION TESTS FOR COMPARISON OF CORROSIVITY IN JAPAN AND CHINA. ...

International Nuclear Information System (INIS)

The author describes the results of post-test analyses of PANDA transient (M-series) tests M2 and M3. The purpose of the PANDA post-test analysis activity is to demonstrate that TRACG is applicable for the calculation of long-term SBWR containment response to a LOCA. Comparisons between TRACG predictions and test measurements are presented and discussed in the dual context of what the test results show and the capability of TRACG to predict their key features

Energy Technology Data Exchange (ETDEWEB)

Two accelerated aging test procedures are proposed for use on solid dielectric extruded distribution cables under wet conditions. One test method is a fixed time duration test in which the degree of cable specimen aging is assessed in terms of breakdown tests, while the other test method is a time to breakdown test in which the cable specimens are voltage stressed until failure ensues.

Wastenet

Performance testing and ...Performance testing and commissioning In either an Authority-owned or a dedicated MRF, the Contracting Authority should ...Performance testing is done to demonstrate that the contractor is able to meet the guarantees given

Science.gov (United States)

... Construction, Geology, and Aquifer Testing of the Maalo ... 8-98) Prescribed by ANSI Std Z39-18 Page 3. Construction, Geology, and Aquifer Testing ...

KoreaScience (Korea)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

This paper describes a radiation shield verification survey of a large hot cell at the Fast Flux Test Facility (FFTF). The following aspects of the shield test are discussed: description of the FFTF; description of the hot cell; the test procedures; radiation protection, and the test results.

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

UK PubMed Central (United Kingdom)

IntroductionChest pain with ST-segment elevation is a rare clinical problem during dobutamine stress testing. Although beta-agonists treatment prior to dobutamine stress testing...Full Text Available

DEFF Research Database (Denmark)

GB:Abstract

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

Science.gov (United States)

Sunflower power conversion system development test program

Science.gov (United States)

This study tested the prediction, derived from the goal-setting hypothesis, that the facilitating

Science.gov (United States)

... Accession Number : ADD318302. Title : ELECTROMAGNETIC MATERIALS TESTING USING RL AND RC-MULTIVIBRATORS. Corporate Author : ...

Science.gov (United States)

... solid particle contamination. Solid particulate impact is a good mechanism for surface heat transfer augmentation. The aug ...

Energy Technology Data Exchange (ETDEWEB)

While the methodology used in developing test items can vary significantly, to ensure quality examinations, test items should be developed systematically. Test design and development is discussed in the DOE Guide to Good Practices for Design, Development, and Implementation of Examinations. This guide is intended to be a supplement by providing more detailed guidance on the development of specific test items. This guide addresses the development of written examination test items primarily. However, many of the concepts also apply to oral examinations, both in the classroom and on the job. This guide is intended to be used as guidance for the classroom and laboratory instructor or curriculum developer responsible for the construction of individual test items. This document focuses on written test items, but includes information relative to ...

Energy Technology Data Exchange (ETDEWEB)

In this article, the technical feasibility of the use of activated carbon, synthetic resins, and various low-cost natural adsorbents for the removal of phenol and its derivatives from contaminated water has been reviewed. Instead of using commercial activated carbon and synthetic resins, researchers have worked on inexpensive materials such as coal fly ash, sludge, biomass, zeolites, and other adsorbents, which have high adsorption capacity and are locally available. The comparison of their removal performance with that of activated carbon and synthetic resins is presented in this study. From our survey of about 100 papers, low-cost adsorbents have demonstrated outstanding removal capabilities for phenol and its derivatives compared to activated carbons. Adsorbents that stand out for high adsorption capacities are coal-reject, residual coal treated with H{sub 3}PO{sub 4}, dried activated sludge, red mud, and cetyl-trimethylammonium bromide-modified montmorillonite. ...

Energy Technology Data Exchange (ETDEWEB)

The Fast Flux Test Facility (FFTF) reactor, which started operating in 1982, is a 400 MWt sodium-cooled fast neutron reactor located in Hanford, Washington State, and operated by Westinghouse Hanford Co. under contract with U.S. Department of Energy. The reactor has a wide variety of functions for irradiation tests and special tests, and its major purpose is the irradiation of fuel and material for liquid metal reactor, nuclear reactor and space reactor projects. The review first describes major technical specifications and current conditions of the FFTF reactor. Then the plan for irradiation testing is outlined focusing on general features, fuel pin/assembly irradiation tests, and absorber irradiation tests. Assemblies for special tests include the material open test assembly (MOTA), fuel open test ...

Energy Technology Data Exchange (ETDEWEB)

Improved test techniques are needed for evaluating the inherent stability of middle distillate fuels both in surveillance and in procurement activities. A project was initiated to define and evaluate the contributing conditions leading to the formation of deleterious products in accelerated aging tests of middle distillate fuels and to relate these results to an experimental definition of more repeatable/reliable middle distillate fuel stability test technique(s). A literature search was conducted to provide a list of stability test techniques and their interpretations which could be used in a correlative middle distillate fuel stability test program. For this program, seven accelerated stability tests were chosen and evaluated using a set of six test fuels. The test techniques were selected to represent a wide variety ...

International Nuclear Information System (INIS)

The PANDA test facility at the Paul Scherrer Institute is used to study the long-term performance of the Simplified Boiling Water Reactor's passive containment cooling system. The PANDA tests demonstrate performance on a larger scale than previous tests and examine the effects of any non-uniform spatial distributions of steam and non-condensable gases in the system. The facility is in 1:1 vertical scale and 1:25 scale for volume, power etc. Extensive facility characterization tests and steady-state passive containment condenser performance tests are presented. The results of the base case test of a series of transient system behaviour tests are reviewed. The first PANDA tests exhibited reproducibility, and indicated that the Simplified Boiling Water Reactor's containment is likely to be favorably responsive and highly ...

Energy Technology Data Exchange (ETDEWEB)

This paper describes the dielectric and accelerated aging tests on prototype {plus minus}500 kV dc oil-filled self-contained cables. The extensive test program was required to evaluate the High-Voltage cables for the St. Lawrence river crossing of the {plus minus}500 kV Quebec-New England HVDC power transmission system. The paper relates the main elements of the test program. It describes the required insulation levels, the characteristics of the cables supplied by three different manufacturers, as well as the cables' installation for the type tests and accelerated aging tests. Details of the test program and procedures followed to carry out the tests are given. Findings of the tests are also reported.

International Nuclear Information System (INIS)

Four unique deisgn features are described which make the Fast Flux Test Facility eminently suitable for irradiation test programs. These features are a fast flux level of 7 x 10"1"5 neutrons/cm"2/sec, a 36-inch reference (breeder reactor) core height, test volumes suitable for testing of statistical quantities of materials, and the capability for direct (contact) or indirect (proximity) instrumentation of active core experiments.

International Nuclear Information System (INIS)

The author discusses the accelerated aging tests performed using Hondo and Maya as aging resids with a commercial large pore hydrotreating catalyst. The results from these tests were compared with those obtained under a normal full life test. The test resid was a sample of a typical refinery charge and the activities for sulfur and vanadium removal were determined at 720"0F after successive brief periods of exposure to the heavier oils.

Science.gov (United States)

A limited program of field measurements was undertaken in order to define the wind characteristics of the DOE/Sandia vertical axis wind turbine test facility. Because micrometeorological conditions under which a particular wind turbine is tested may have ...

Energy Technology Data Exchange (ETDEWEB)

This paper defines a rigorous seal test program conducted to develop a functional and proven high-pressure, multi-product swivel suitable for use as a Floating Production Storage and Offloading (FPSO) unit for the transfer of liquids and gases at high pressures and high temperatures through a rotating system. The test program was accomplished with specially designed test equipment with computer monitoring of temperature, torque, fluid pressures, seal lip temperatures, number of cycles, and leakage. The three primary phases are: (A) Seal Laterial screening with a computer-automated Falex testing machine, plus physical testing of chemically exposed samples. (B) One-third scale testing of several seal system configurations using a hydraulic driven, computer controlled test machine. (C) Full scale testing of prototype ...

UK PubMed Central (United Kingdom)

The blood beryllium lymphocyte proliferation test (BeLPT) is a modification of the standard lymphocyte proliferation test that is used to identify persons who may have chronic beryllium disease. A major...Full Text Available

Science.gov (United States)

This report is the final report on the seismic testing of reactor components conducted since 1977 with opening of the vibration laboratory at KAERI. In 1979, forced vibration testing of Wolsung-1 steam generator model using sine dwell and white nosie rand...

UK PubMed Central (United Kingdom)

A single radial hemolysis test was developed for quantitation of specific antibody to non-hemagglutinating viruses. With the human coronaviruses as models, this test utilizes the binding properties...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The proper selection of materials of construction is necessary to provide process equipment with optimum performance and corrosion resistance. If properly chosen, the selected material should deteriorate at a uniform, predictable rate, which will allow for maintenance or replacement at scheduled intervals. This concept of risk assessment for predictive maintenance is a minimum requirement for proper materials selection. Materials selection is based on prior service history, field corrosion tests, pilot-plant tests, and laboratory bench-top tests--in that relative order of usefulness. Corrosion test methods are usually divided into two groups: laboratory and field (plant-site) tests. The main difference between the two is that field test specimens are exposed to actual process conditions will all of the variables involved, while laboratory ...

Energy Technology Data Exchange (ETDEWEB)

The stand is designed to test supports of development workings. To expand the test range for various types of supports, the cross pieces have fixing devices in the form of winches interacting by cables through blocks fastened to the stand body with the support hinges.

Science.gov (United States)

This report provides test results on the thermal performance of an Owens-Illinois Sunpak liquid, evacuated tube, solar collector under simulated conditions. The test was conducted using the Marshall Space Flight Center Solar Simulator in accordance with the test requirements specified in ASHRAE 93-77 (Method of Testing to Determine the Thermal Performance of Solar Collectors) and the procedures contained in MTCP-FA-SHAC-400 (Procedure for Operation of the MSFC Solar Simulator Facility). The tests were performed on a module used on the early demonstration projects. A current production module is undergoing tests with results to be in a subsequent report.

Energy Technology Data Exchange (ETDEWEB)

Epoxy-resin based neutron shielding material, NS-4-FR, is used for spent fuel transport and/or storage cask. In this paper the outline of thermal aging test performed to evaluate the heating effect on this neutron shielding material, NS-4-FR, is introduced. The test is consisted of two kinds of thermal aging test, one is 'Basic Test' and the other is 'Block Heating Test'. The former is cooperatively performed by ten Japanese Electrical Power Companies, and the latter is done by GESC and NOF Corporation. (authors)

International Nuclear Information System (INIS)

The Fast Flux Test Facility has provided a very useful framework for testing the advances in Liquid Metal Reactor Safety Technology. During the licensing phase, the switch from a nonmechanistic bounding technique to the mechanistic approach was developed and implemented. During the operational phase, the consideration of new tests and core configurations led to use of the anticipated-transients-without-scram approach for beyond design basis events and the move towards passive safety. The future role of the Fast Flux Test Facility may involve additional passive safety and waste transmutation tests. 26 refs.

Science.gov (United States)

... Abstract : Interlaboratory evaluation of the Radiant Panel Method (ASTM E 162-67) for flame spread testing of two flexible foam and one hardboard ...

UK PubMed Central (United Kingdom)

BackgroundGenetic predisposition to scrapie in sheep is associated with several variations in the peptide sequence of the prion protein gene (PRNP). DNA-based tests...Full Text Available

UK PubMed Central (United Kingdom)

The Department of Defense (DOD) will soon issue a directive to test all incoming military personnel for the presence of hemoglobin S. The military testing program for hemoglobin S is an occupational...Full Text Available

Science.gov (United States)

... An explosive charge (exploding bridgewire (EBW) detonator) was used for the crosshole P-wave tests. For the crosshole S-wave tests a ...

Science.gov (United States)

... 24 5 Exploding Bridgewire Test Vehicle.... . 0..... 25 ... 18 7 Results of Exploding Bridgewire TestLng of TP-41 and TP-41 Mixtures ..... ...

Medline Plus

... experts agree-- a colonoscopy is the most accurate test to detect the cancer, but because of cost ... method. Dr. Randall Burt: Colonoscopy is the best test. The question is therefore shouldn't everyone, since ...

International Nuclear Information System (INIS)

Included are descriptions of welding methods and joint design, welding equipment, and qualification tests.

Energy Technology Data Exchange (ETDEWEB)

The Japan Atomic Energy Research Institute has conducted a piping reliability test program to demonstrate the safety and reliability of light water reactor primary piping. In this program, pipe fatigue test, leak-before-break (LBB) verification test and pipe rupture test were carried out to examine the integrity of piping, to verify the LBB and to demonstrate the effectiveness of protective measures against jet impingement and pipe whip loads under a pipe rupture event.In the pipe fatigue test, a procedure to predict the fatigue crack growth was developed, and the integrity of piping during the plant service life was evaluated. In the LBB verification test, the pipe fracture test and the leak rate test were performed to verify the LBB in the primary piping.In the pipe rupture test, the influence of ...

Energy Technology Data Exchange (ETDEWEB)

JAERI has been performing transient core thermal-hydraulic test program. In the program, authors performed BWR/ABWR DBE simulation tests with a test facility, which can simulate BWR/ABWR transients. The test facility has a 4 x 4 bundle core simulator with 15-rod heaters and one non-heated rod. Through the tests, authors quantified the thermal safety margin for core cooling. In order to quantify the thermal safety margin, authors collected experimental data on post-CHF. The data are essential for the evaluation of clad temperature transient when core heat-up occurs during DBEs. In comparison with previous post-CHF tests, present experiments were performed in much wider experimental condition, covering high clad temperature, low to high pressure and low to high mass flux. Further, data at wider elevation (lower to higher elevation of core) were obtained in the ...

Science.gov (United States)

PMID:7177024

Science.gov (United States)

PMID:17236670

Science.gov (United States)

... above. In the initial round of experiments, the venom of Dendroaspis augustepsis was tested for its actions on neuromuscular transmission. ...

Science.gov (United States)

No Abstract Available

Energy Technology Data Exchange (ETDEWEB)

Modern microprocessor-based relays for the protection of the various power system components such as generators, transformers, feeders, and high voltage transmission lines are becoming more sophisticated as increasingly more complex functions and capabilities can be included in the microprocessor. With this increasing complexity, and the increasing complexity of the power system itself, there is even more value in testing the suitability of relaying equipment for the intended applications. This paper reviews the testing philosophy, experience, and capabilities developed at Ontario Hydro over more than 25 years of testing protective relays.

Energy Technology Data Exchange (ETDEWEB)

Abstract not provided

Science.gov (United States)

... and testing of unidirectional composites, there are serious doubts about the possibility of obtaining a true ultimate compressive strength for this kind ...

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

KoreaScience (Korea)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

Medline Plus

... a test for HIV, the virus that causes AIDS. Do a Pap smear to check for cervical ...

Energy Technology Data Exchange (ETDEWEB)

Operational Final Test Report for Integrated Systems, Project W-030 (Phase 2 test, RECIRC and HIGH-HEAT Modes). Project W-030 provides a ventilation upgrade for the four Aging Waste Facility tanks, including upgraded vapor space cooling and filtered venting of tanks AY101, Ay102, AZ101, AZ102.

Medline Plus

... diagnosed. A complete blood count (CBC), urinalysis, blood chemistries, and erythrocyte sedimentation rate (ESR) tests can provide ...

International Nuclear Information System (INIS)

This document describes the High Performance Electrical Modeling and Simulation (HPEMS) Global Verification Test Suite (VERTS). The VERTS is a regression test suite used for verification of the electrical circuit simulation codes currently being developed by the HPEMS code development team. This document contains descriptions of the Tier I test cases.

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

KoreaScience (Korea)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Testing results obtained from simple shear and direct shear tests were conducted for investigating the frictional properties between steel pile shaft and silty clay in this paper. By using the analyzed results of these tests, a hyperbolic curve fitting method for estimating skin friction of pile shaft was proposed in which was verified by its application on the results of undrained uplift triaxial model pile tests.

Energy Technology Data Exchange (ETDEWEB)

Prior to an industrial-scale test of zinc/air batteries at Greven, the TUeV Bayern-Sachsen carried out preliminary tests on behalf of the Deutsche Bundespost. The results were quite promising: The energy density of the new battery is ten times as high as that of conventional lead batteries, and the battery-powered test vehicle had a range of up to 300 km. (orig.)

Science.gov (United States)

The performance of the leukocyte test area of the new multiple urine test strip, Multistix-10-SG, was evaluated in both field trials and model experiments. The detection limit was found to be adequate for routine purposes. Unspecific reactions are rare and generally indicated by the results of the other test areas. PMID:3572312

Science.gov (United States)

Not Available

International Nuclear Information System (INIS)

Safety-related instrument in nuclear power plants must be checked for reliability over their projected operating life. A method of conducting accelerated aging tests is presentd. It uses the Arrhenius activation energy concept and manipulation of the parameters of the test e.g. by raising test temperature, by relying on a model characterizing the chemical-related reactions of materials.

Energy Technology Data Exchange (ETDEWEB)

Extensive well testing in geothermal resources has been carried out throughout the western United States and in northern Mexico since 1975. Each resource tested and each well test conducted by LBL during the eight-year period are covered in brief. The information, collected from published reports and memoranda, includes test particulars, special instrumentation, data interpretation when available, and plots of actual data. Brief geologic and hydrologic descriptions of the geothermal resources are also presented. The format is such that well test descriptions are grouped, in the order performed, into major sections according to resource, each section containing a short resource description followed by individual test details. Additional information regarding instrumentation is provided. Source documentation is provided throughout to facilitate access to further ...

International Nuclear Information System (INIS)

The purposes of this report are (1) to perform a Verification and Validation (V and V) test for the VIPEX(Vital-area Identification Package EXpert) software and (2) to improve a software quality through the V and V test. The VIPEX was developed in Korea Atomic Energy Research Institute (KAERI) for the Vital Area Identification (VAI) of nuclear power plants. The version of the VIPEX which was distributed is 3.2.0.0. The VIPEX was revised based on the first V and V test and the second V and V test was performed. We have performed the following tasks for the V and V test on Windows XP and VISTA operating systems: ? Testing basic functions including fault tree editing ? Testing all kind of functions ? Research for update from Visual BASIC 6.0 to Visual BASIC 2008

British Library Electronic Table of Contents (United Kingdom)

Purpose - The purpose of this paper is to help library technology staff understand the process of beta testing software, determine if it is appropriate for them to engage in the process, and provide suggestions on how to the time invested in the process. Design/methodology/approach - The paper explains what beta testing is, why it should be used and how to become a beta tester. Findings - The paper reveals that beta testing is not convenient for everyone, but those taking place in these activities should be thorough, positive and generous in order to maximize the return on investment in this kind of testing. Practical Implications - While beta testing new software features can take a significant amount of time, the resulting benefits of early access to new features and improved vendor-staf...

International Nuclear Information System (INIS)

The ALPHA project is centered around the experimental and analytical investigation of the long-term decay heat removal from the containments of the next generation of open-quotes passiveclose quotes ALWRs. The project includes integral system tests in the large-scale (1:25 in volume) PANDA facility as well as several other series of tests and supporting analytical work. The first series of experiments to be conducted in PANDA have become a required experimental element in the certification process for the General Electric Simplified Boiling Water Reactor (SBWR). The PANDA general experimental philosophy, facility design, scaling, and instrumentation are described. Steady-state PCCS condenser performance tests and extensive facility characterization tests were already conducted. The transient system behavior tests are underway; preliminary results from the first transient ...

International Nuclear Information System (INIS)

This paper describes new test methodologies to obtain data used to evaluate the ultimate seismic strength of Nuclear Power Plant (NPP) equipment related to nuclear safety. The paper first reviews existing equipment seismic test data from the viewpoint of the evaluation of their ultimate seismic strength and/or seismic design margins, and extracts the issues in the existing data with regard to their applicability to the evaluation. Then, the paper proposes new test methodologies for the equipment to evaluate their ultimate seismic strength. The test methodology of the equipment employs a vibration amplification system to a shaking table and enhances its applicable maximum acceleration up to 6g. The test methodology herein is cost effective for obtaining test data that is indispensable for evaluating proper seismic margins of NPPs. (author)

International Nuclear Information System (INIS)

We provide a detailed overview of an on-going, multinational test programme that is developing aerosol data for some spent fuel sabotage scenarios on spent fuel transport and storage casks. Experiments are being performed to quantify the aerosolised materials plus volatilised fission products generated from actual spent fuel and surrogate material test rods, due to impact by a high-energy/density device. The programme participants in the United States plus Germany, France and the United Kingdom, part of the international Working Group for Sabotage Concerns of Transport and Storage Casks (WGSTSC) have strongly supported and coordinated this research programme. Sandia National Laboratories has the lead role for conducting this research programme; test programme support is provided by both the US Department of Energy and the US Nuclear Regulatory Commission. We provide a summary of the overall, multiphase ...

International Nuclear Information System (INIS)

The authors provide a detailed overview of an on-going, multinational test program that is developing aerosol data for some spent fuel sabotage scenarios on spent fuel transport and storage casks. Experiments are being performed to quantify the aerosolized materials plus volatilized fission products generated from actual spent fuel and surrogate material test rods, due to impact by a high-energy-density device. The program participants in the United States plus Germany, France and the United Kingdom, part of the international Working Group for Sabotage Concerns of Transport and Storage Casks (WGSTSC) have strongly supported and coordinated this research program. Sandia National Laboratories has the lead role for conducting this research program; test program support is provided by both the US Department of Energy and the US Nuclear Regulatory Commission. The authors provide a summary of the overall, multiphase ...

Science.gov (United States)

A schematic of the Bench cavity receiver system is given, and the primary objectives, schedule and research plan for each of four tests are discussed. The tests are: (1) cold flow testing to functionally check all valves and their response using high pressure nitrogen gas; (2) a hot checkout to simulate both steady state and transient flux inputs to the receiver which are expected at the French facility; (3) basic performance using solar energy at the French facility; and (4) ir radiant heat testing. (LEW)

International Nuclear Information System (INIS)

The Programmable Logic Controller (PLC) for use in Nuclear Power Plant safety-related applications is being developed and tested first time in Korea. This safety-related PLC is being developed with requirements of regulatory guideline and industry standards for safety system. To test that the quality of the developed PLC is sufficient to be used in safety critical system, document review and various product testings were performed over the development documents for S/W, H/W, and V/V. This paper provides the performance testing methodology and its effectiveness for PLC platform conducted by KOPEC

Energy Technology Data Exchange (ETDEWEB)

In order to assess whether an oil shale test facility would be of significant use to private sector oil shale developers, the US DOE has studied the past history of oil shale development and its potential for replacing petroleum supplies. A generic test facility's primary function would be to test concepts of mining, retorting, upgrading, and environmental aspects at the engineering scale. This paper summarizes the US oil shale resources, gives a technology analysis, and discusses the potential for a test facility.

Wastenet

...com: The Art of Application Performance Testing : Help for Programmers and Quality Assurance (9780596520663): Ian Molyneaux: Books Amazon.com:...The Art of Application Performance Testing : Help for Programmers and Quality Assurance (9780596520663): Ian Molyneaux: Books Ian Molyneaux,The ...Art of Application Performance Testing : Help for Programmers and Quality Assurance,O'Reilly Media,0596520662,LA9780596520663,Computer Books: General,Application software,Computer software,...com: The Art of Application Performance Testing : Help for Programmers and Quality Assurance (9780596520663): Ian Molyneaux: Books ...

Science.gov (United States)

There are very few examples of audio-based computerized tests, but for many disciplines, such as foreign language and music, there appear to be many benefits to this type of testing. The purpose of the present study was to develop and compare computer-delivered and audiocassette/paper-and-pencil versions of a listening test. The test was a measure of progress achievement of academic listening comprehension and vocabulary for high-intermediate level students of English as a Second Language (ESL) at a university-affiliated institute. The underlying assumption investigated was that the use of computer and audio technology for classroom progress tests would provide benefits of convenience and improved sound quality while providing measurement quality and validity that were at least comparable to the paper form of such tests. Results with 28 students indicate that ...

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) is a liquid-metal-cooled test reactor located on the Hanford Site. The FFTF is the only reactor of this type designed and operated with the intent of meeting the licensing requirements of the Nuclear Regulatory Commission (NRC). Unique characteristics of the FFTF that present special challenges related to leak rate testing include thin wall containment vessel construction, cover gas systems that penetrate containment, and a low-pressure design basis accident. The successful completion in 1986 of the third FFTF Integrated Leak Rate Test (ILRT) five days ahead of schedule and 10% under budget was a major achievement for the Westinghouse Hanford Company. The success of this operational safety test was due in large part to a special local area network (LAN) of three IBM PC/XT computers that monitored the sensor data, calculated the containment vessel ...

Energy Technology Data Exchange (ETDEWEB)

Constant extension rate (CERT) tests were performed on Alloy 690 and Alloy 800 nuclear steam generator tubing specimens. For the Alloy 690 specimens, tests were performed in deaerated 10% sodium hydroxide solutions at 315 deg C with a +100 mV applied potential. For the Alloy 800 specimens, tests were performed in deaerated 5% sodium hydroxide solutions at 343 deg C with no applied potential. The test specimens were machined from tubing which was produced by different manufacturing processes and in different heat treated conditions. The Alloy 690 tubing was tested in six different thermomechanical conditions, while the Alloy 800 tubing was tested in four different thermomechanical conditions. The results from the test program include a complete microstructural examination using light-optical and scanning electron microscopy. The CERT ...

International Nuclear Information System (INIS)

The paper describes the experimental and analytical results of the pipe whip tests performed under the PWR LOCA conditions using 4, 6 and 8 inch test pipes. The tests were carried out at an initial pressure and a temperature of 15.7 MPa and 325 "0C. Two different types of tests were performed. One was the cantilever type pipe whip test using the test pipe of 3000 mm in length and U-shaped restraints. The other was the cross-over leg pipe whip test using a 1/6 model of piping in the PWR nuclear power plants. The cantilever type pipe whip tests were performed to investigate the influences of overhang length and pipe diameter on the pipe whip behavior. The movement of the test pipe is limited effectively by the restraints when the overhang length is short. The restraint force increases in proportion to ...

British Library Electronic Table of Contents (United Kingdom)

The laboratory environment existing outside the test situation itself can have a substantial influence on results of some behavioral tests with mice, and the extent of these influences sometimes depends on genotype. For alcohol research, the principal issue is whether genotype-related ethanol effects will themselves be altered by common variations in the lab environment or instead will be essentially the same across a wide range of lab environments. Data from 20 inbred strains were used to reduce an original battery of seven tests of alcohol intoxication to a compact battery of four tests: the balance beam and grip strength with a 1.25g/kg ethanol dose and the accelerating rotarod and open-field activation tests with 1.75g/kg. The abbreviated battery was then used to study eight inbred str...

Energy Technology Data Exchange (ETDEWEB)

The OSP (Operating Safety Procedure) required for performance of electrical arc testing of CFC replacement fluids was renewed. Electrical breakdown tests at one atmosphere pressure have been performed for R-22, R-134a, and R-125/R-143a (50:50 blend; R-507), and breakdown products identified. No differences in HCFC breakdown products are seen in the presence or absence of lubricant oils. The design of the high pressure-high temperature test stand has been finalized, and construction initiated during this quarter. Three motor stators and rotors were received from Tecumseh Products Company for use in motor burnout tests. A test plan for the motor breakdown tests is in preparation.

British Library Electronic Table of Contents (United Kingdom)

Greenman J, Thorn RMS, Saad S, Austin AJ. In vitro diffusion bed, 3-day repeat challenge `capacity' test for antimicrobial wound dressings. Int Wound J 2006;3:322-329. Abstract The aim of this study was to develop an in vitro wound infection model that allows the comparison of the bacterial kill rate of antimicrobial wound dressings over the course of 3 days, with renewed microbial challenges each day, under realistic wound-like conditions. A test bed model of a moderately exuding wound was constructed from a hydrogel containing releasable foetal calf serum (FCS), and cellulose discs dosed with test microbes (Methicillin-resistant Staphylococcus aureus and Pseudomonas aeruginosa) suspended in 50% FCS applied at the interface between the test dressing and the hydrogel test bed. Freshly prep...

Energy Technology Data Exchange (ETDEWEB)

A technique for the measurement of the total hemispherical emittance of pipe surfaces is described, and design and operational details are given. The technique is conceptually simple. A long test pipe (e.g., 3.4 m) is mounted concentrically inside a Pyrex glass pipe. The system is evacuated, and the test pipe is heated by means of an electrical resistance heater. Heat transfer from the test pipe to the enclosure is almost solely radiative, allowing an average emittance for the test pipe and the Pyrex pipe and the electrical power input to the heater. By varying the electrical power level, one can measure the test pipe emittance as a function of temperature. By using a simple correction to account for the finite length of the test pipe, one can calculate the results using the simple expression for infinite, concentric cylinders. Results agree with measurements by ...

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) is a 400 MW(th) sodium cooled reactor and is the largest test reactor of its type in the world. It was designed and is being operated to serve two purposes: gaining liquid metal system experience and serving as a test bed for fuels and materials. During test operations it is possible that cladding breaches and escape of fission gas to the reactor cover gas region can occur. To identify the source of such a leak all 78 fuel pin assemblies contain ''gas tag'' with a unique ''tag'' mixture in each assembly. The mass spectrometric identification of tag isotope ratios makes possible rapid location and thus faster removal (if required) of breached test pins.

Energy Technology Data Exchange (ETDEWEB)

This document describes the development testing phase associated with the OTA Shear activity and defines the controls to be in place throughout the testing. The purpose of the OTA Shear Program was to provide equipment that is needed for the processing of 40 foot long, sodium wetted, irradiated core components previously used in the FFTF reactor to monitor fuel and materials tests. There are currently 15 of these OTA test stalks located in the Test Assembly Conditioning Station (TACS) inerted vault. These need to be dispositioned for a shutdown mission to eliminate this highly activated, high dose inventory prior to turnover to the ERC since they must be handled by remote operations. These would also need to be dispositioned for a restart mission to free up the vault they currently reside in. The waste handling and cleaning equipment in the J33M Cell was designed and built for the ...

Energy Technology Data Exchange (ETDEWEB)

This report provides the results of a JASON review of the technical feasibility of using the Department of Energy`s (DOE`s) Fast Flux Test Facility (FFTF) to generate tritium needed for the enduring United States nuclear weapons stockpile.

International Nuclear Information System (INIS)

It is of utmost importance to have a computer code in order to analyze how different parameters (like test duration time) affect the unavailability of safety systems of nuclear. In this context, a study was performed in order to evaluate the model employed by the FRANTIC computer code, which performs detailed calculations on the contribution to the system unavailability originated by hardware failures, component tests and repairs, aiming at considering the influence of different test schemes on the system unavailability. It was shown, by means of the results attained that the numerical model used by the FRANTIC code and the analytical model proposed by APOSTOLAKIS and CHU (4) give unavailability values much similar when the component tests are supposed to be perfect. When a test is supposed to be imperfect (that is, when it may induce a test is supposed to be ...

UK PubMed Central (United Kingdom)

The use of an extraction of the heme pigments hemoglobin and myoglobin as a test for the heat exposure of back bacon was investigated by treating back bacon at varying temperatures of 50-70 degrees...Full Text Available

UK PubMed Central (United Kingdom)

BackgroundWith a growing number of genetic tests becoming available to the health and consumer markets, genetic health care providers in Canada are faced with the challenge of developing...Full Text Available

UK PubMed Central (United Kingdom)

Today, hospitals are involved extensively in social marketing and promotional activities. Recently, investigators from the Centers for Disease Control and Prevention (CDC) estimated that routine testing...Full Text Available

Science.gov (United States)

Astronomical Society of Northern New England: Solar System Test Kit Baldwin 3rd grade Astronomical Society of Northern New England ...

UK PubMed Central (United Kingdom)

Experienced users of the Clarion cochlear implant were tested acutely with the HiResolution (HiRes) and HiRes Fidelity120 (F120) processing strategies. Three psychophysically-based tests were...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Bench Scale methane cracking tests have been completed using a stack of ten whole SAES(R) St909 pellets - a 6 gram sample size. Methane was found to be the most difficult impurity to process and can impact diffuser operation.

Energy Technology Data Exchange (ETDEWEB)

Based on changes to the fuel pin gas gap composition, pin location and assembly location, revisions to the TDD-IB, Part 2 are provided.

UK PubMed Central (United Kingdom)

Direct identification of group B streptococci from a selective broth medium was performed with the Phadebact streptococcus test to determine the feasibility of this technique for early detection of...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Handheld, backpack, and mobile sensors are elements of the Global Nuclear Detection System for the interdiction and control of illicit radiological and nuclear materials. They are used by the U.S. Department of Homeland Security (DHS) and other government agencies and organizations in various roles for border protection, law enforcement, and nonproliferation monitoring. In order to systematically document the operational performance of the common commercial off-the-shelf portable radiation detection systems, the DHS Domestic Nuclear Detection Office conducted a test and evaluation campaign conducted at the Nevada Test Site from January 18 to February 27, 2006. Named 'Anole', it was the first test of its kind in terms of technical design and test complexities. The Anole test results offer users information for selecting appropriate mission-specific portable ...

Science.gov (United States)

This plan describes the Quality Assurance Program which will be applied to spent fuel handling and packaging tests conducted at the Area 25 E-MAD facility, Nevada Test Site (NTS).

Energy Technology Data Exchange (ETDEWEB)

In the fuel testing facilities of Japan Atomic Energy Research Institute, the post-irradiation test of practical fuel used in nuclear power stations was begun in December, 1979, and the soundness of practical fuel has been confirmed, and the valuable post-irradiation test data on the behavior of fuel have been acquired. Recently, the heightening of fuel burnup has been advanced, and also in fuel testing facilities, the development and preparation of the post-irradiation testing facility required for examining in detail high burnup fuel have been carried out. The course of the installation of the post-irradiation testing facility and the outline of the facility are reported. As the preparation of the post-irradiation testing facility for high burnup fuel, a hyperfine hardness tester that measures dynamic hardness, the measuring instrument for ...

Wastenet

... Austrian Environment Minister Nikolaus Berlakovich called for such stress tests on Sunday (13 March) to make sure that nuclear power stations were quake-proof following Japan's massive earthquake and tsunami. Austria, a mountainous country rich in geothermal energy, has no NPPs and no plans to develop ...

UK PubMed Central (United Kingdom)

We have exploited ``progeny testing'' to map quantitative trait loci (QTL) underlying the genetic variation of milk production in a selected dairy cattle population. A total of 1,518 sires, with progeny...Full Text Available

International Nuclear Information System (INIS)

The fusion materials program has little irradiation effects data at temperatures from 100 to 350 degree C. Near-term machines such as the International Thermonuclear Engineering Reactor (ITER) will expose materials to neutron doses of 38 to 50 dpa at 150 degree C or less. The data base for structural materials must be extended into this range. Also, lower temperatures are needed to investigate the lower bound for tritium release from solid breeder materials. A low temperature test vehicle is proposed for the Fast Flux Test Facility (FFTF), which will provide test temperatures of 100 to 350 degree C. An 8.5-cm dia. by 100-cm test volume will be instrumented to collect temperature data and provide feedback for control. The spectrum and flux will provide accelerated damage accumulation for structural materials testing and the best available approximation of fusion reactor conditions ...

Energy Technology Data Exchange (ETDEWEB)

Laboratory studies were performed to support field-testing of base injection into the F-Area Seepage Basins groundwater. The general purpose of these experiments is to provide information to guide the test of base injection and to identify potential adverse effects.

Energy Technology Data Exchange (ETDEWEB)

Test Area North (TAN) was a site of the Aircraft Nuclear Propulsion (ANP) Project of the U.S. Air Force and the Atomic Energy Commission. Its Cold War mission was to develop a turbojet bomber propelled by nuclear power. The project was part of an arms race. Test activities took place in five areas at TAN. The Assembly & Maintenance area was a shop and hot cell complex. Nuclear tests ran at the Initial Engine Test area. Low-power test reactors operated at a third cluster. The fourth area was for Administration. A Flight Engine Test facility (hangar) was built to house the anticipated nuclear-powered aircraft. Experiments between 1955-1961 proved that a nuclear reactor could power a jet engine, but President John F. Kennedy canceled the project in March 1961. ANP facilities were adapted for new reactor projects, the most important of which were Loss of Fluid ...

Science.gov (United States)

A corrosion-testing program has been initiated in Purex and Redox storage tnnks to obtain corrosion data on carbon steel and three associated materials in neutralized process wastes. (C.W.H.)

Science.gov (United States)

Under a cooperative agreement, the Bureau of Mines, Magma Copper Co., and ASARCO, Inc., tested backfilled ground support systems at two elevations in Magma's San Manuel, AZ, mine. The tests were mainly for guidance in designing the loading crosscuts of th...