Energy Technology Data Exchange (ETDEWEB)

This report details the status of the Biological Conversion of Synthesis Gas Project. The following tasks are described as being completed: (1) the test plan, (2) culture development, and (3) the mass transfer/kinetic studies. The bioreactor studies (Task 4) are underway. The continuous stirred tank reactor system for the conversion of H{sub 2}S to elemental sulfur using Chlorobium thiosulfatophilum has been studied for varying light intensities. The system was also modified to include both sulfur recovery and cell recycle using ceramic membranes. Studies were also performed to observe the effects of cell recycle using a polysulfone hollow filter membrane module. Work on Task 5, limiting conditions/scale-up, includes a scale-up study with three different size reactors to establish the optimum operating conditions for hydrogen production from synthesis gas by the biological water-gas ...

Energy Technology Data Exchange (ETDEWEB)

This report discusses environmental surveillance activities conducted on the Nevada Test Site during the first calendar quarter of 1996. Surveillance activities included collection and analysis of air, noble gas, tritiated water vapor, and other water samples. Samples were analyzed for both radiological and non-radiological effluents.

Energy Technology Data Exchange (ETDEWEB)

Research is presented on oil and gas technologies, advanced systems for fossil fuels, environmental technologies for remediation and waste management, applied energy science on heavy oil and plastics coprocessing, and fossil fuel and hydrocarbon conversion using hydrogen rich plasma.

Energy Technology Data Exchange (ETDEWEB)

Describes progress made with the new economic system in the USSR coal industry since full self-financing was introduced on 1 January 1989, pointing out that mining is now being carried out at greater depths than before (515 m in 1988, 457 m in 1981 on the average) and that an increasing proportion of coal is being produced by mines liable to coal and gas bursts (62.3% in 1988, 59.6% in 1981). More difficult conditions means that mining costs are increasing. Explains system of agreements between teams of workers and mine management regarding output and extraction costs. Reveals that on 1 January 1990 a new list of coal prices will include 90% price rises on average, as a result of need for mines to finance themselves. There are to be 2 variants of this price list: one containing standard nationwide prices, the other based on mining areas, taking into account different geological and other conditions. Concludes by emphasizing ...

Energy Technology Data Exchange (ETDEWEB)

The performance of the new combustor was tested. Experiments showed that this combustor has superior insulating quality than the previous one. Measured radial concentrations indicated uniform distribution of the primary fuel (coal) inside the fire tube resulting in reasonably flat concentration profiles. However, measured radial concentrations after the addition of the reburn fuel showed uneven distribution of the fuel resulting in parabolic concentration profiles, an indication of insufficient mixing in the reburn zone. In order to study mechanisms of nitrogenous species destruction in the reburn zone, it is necessary to achieve adequate mixing if the assumption of one dimensional plug flow behavior is to be valid. Thus, it became necessary to modify the injector design and the injection mode of the reburn fuel to achieve an adequate level of mixing which is the focus of this report. The results show that a minimum reburn fuel jet velocity of 15 m/s (standard ...

Energy Technology Data Exchange (ETDEWEB)

This program is concerned with the development of an advanced method for the separation of hydrogen sulfides from coal gas. The process utilizes an electrochemical membrane which removes hydrogen sulfide without cooling the gas and with negligible pressure loss through the separator.

Energy Technology Data Exchange (ETDEWEB)

The information reported is for the period October I to December 31, 1993. During this quarter, activities were undertaken in Task 2. Oxygen concentrations were measured in the post-flame region of the entrained flow reactor. The sampling probe was used for the hot gas tests to sample the gas stream. Samples were injected into a gas chromatograph to determine the oxygen concentration. Results agreed with thermoequilibrium calculations that yield equilibrium compositions based on the stoichiometry of the feed gases. The axial temperature distribution along the reactor centerline was measured using a silica-coated platinum-rhodium thermocouple. Two coating techniques were tested and it was found that flame-plating silica to the thermocouple wires produced a thinner coating than a ceramic adhesive technique and therefore a smaller radiation correction. Other activities this quarter ...

Energy Technology Data Exchange (ETDEWEB)

The objective of this project is to develop a pellet formulation which is capable of achieving low sulfur partial pressures and a high capacity for sulfur, loaded from a hot fuel gas and which is readily regenerable. Furthermore the pellet must be strong for potential use in a fluidized bed and regenerable over many cycles of loading and regeneration. Regeneration should be in air or oxygen-depleted air to produce a high-concentration sulfur dioxide. Fixed-bed tests were conducted with several formulations of manganese sesquioxide and titania, and alumina They were subject to a simplified fuel gas of the oxygen-blown Shell type spiked with a 30,000ppmv concentration of H{sub 2}S. Pellet crush strengths for 4 and 2mm diameter pellets was typically 12 lbs per pellet and 4 lbs per pellet, respectively. For the most favorable of the formulations tested and under the criteria of break-through at less than 100ppmv H2S and loading temperatures of ...

International Nuclear Information System (INIS)

Natural gas is essential to the world economy. Gas now accounts for almost a quarter of OECD primary energy requirements and is expected to become the second most important fuel in the world in the next decade. Industrial and residential consumers increasingly rely on natural gas to keep their houses warm, their lights on and their factories running. Meanwhile the gas industry itself has entered a new phase. Where gas used to be restricted to regional markets, it is now increasingly traded on a global scale. While gas production and transport requires long-term investment, now it is optimised on a short-term basis. Demand continues to grow, but local gas production has become much more expensive. How should we react? How will demand be satisfied? What changes are required to promote flexibility and trade? What are the ...

Science.gov (United States)

Programs in coal research by the Pittsburgh Energy Technology Center are discussed. Topics include: Coal Science and Chemistry, Coal Liquefaction, Alternative Fuels, Coal Preparation, Combustion, MHD Program, Flue Gas Cleanup, Environmental Coordination, and Technology Transfer. (CBS)

Energy Technology Data Exchange (ETDEWEB)

Work on this coke oven gas cleaning demonstration project (CCT-II) this quarter has been focused on Phase IIB tasks, and include engineering, procurement, construction, and training. Additionally, plans for changes in the operating schedule of the coke plant that affect the demonstration project are described. Engineering efforts are nearly complete. Remaining to be finalized is an assessment of electrical heat tracing/insulation needs for pipe lines, assessment of fire protection requirements, and instrument modifications. Procurement of all major equipment items is complete, except for possible additions to fire fighting capabilities. Major focus is on expediting pipe and structural steel to the project site. Civil construction is complete except for minor pads and bases as required for pipe supports, etc. Erection of the hydrogen sulfide and ammonia scrubber vessels is complete. Installation of scrubber vessel internals is underway. A ...

Energy Technology Data Exchange (ETDEWEB)

North Slope of Alaska has huge oil deposits in heavy oil reservoirs such as Ugnu, West Sak and Shrader Bluff etc. The viscosity of the last two reservoir oils vary from {approx}30 cp to {approx}3000 cp and the amount in the range of 10-20 billion barrels. High oil viscosity and low formation strength impose problems to high recovery and well productivity. Water-alternate-gas injection processes can be effective for the lower viscosity end of these deposits in West Sak and Shrader Bluff. Several gas streams are available in the North Slope containing NGL and CO{sub 2} (a greenhouse gas). The goal of this research is to develop tools to find optimum solvent, injection schedule and well-architecture for a WAG process in North Slope shallow sand viscous oil reservoirs. In the last quarter, we have developed streamline generation and convection subroutines for miscible gas injection. The ...

Energy Technology Data Exchange (ETDEWEB)

The three tasks were completed during this reporting period. During this quarter, work focused on a local structural analysis of the Table Rock field, greater Green River basin (GGRB) in southwestern Wyoming. The ultimate objective of the local analysis is to apply the techniques developed and demonstrated during earlier phases of the project in the Rulison Field area of the Piceance basin for sweet-spot delineation. The primary goal of this work is to focus in on the Table Rock field area in the northern Washakie basin of the Greater Green River basin in support of Union Pacific Resources and DOE planned horizontal drilling efforts. The work plan for the quarter of April 1, 1998--June 30, 1998 consisted of three tasks: (1) Acquire necessary seismic data and depth-convert, (2) Map major fault geometry and analyze displacement vectors, (3) Develop and initiate a natural fracture prediction study.

Energy Technology Data Exchange (ETDEWEB)

A High Performance Power System (HIPPS) is being developed. This system is a coal-fired, combined cycle plant with indirect heating of gas turbine air. Foster Wheeler Development Corporation and a team consisting of Foster Wheeler Energy Corporation, Bechtel Corporation, University of Tennessee Space Institute and Westinghouse Electric Corporation are developing this system. In Phase 1 of the project, a conceptual design of a commercial plant was developed. Technical and economic analyses indicated that the plant would meet the goals of the project which include a 47 percent efficiency (HHV) and a 10 percent lower cost of electricity than an equivalent size PC plant. The concept uses a pyrolysis process to convert coal into fuel gas and char. The char is fired in a High Temperature Advanced Furnace (HITAF). The HITAF is a pulverized fuel-fired boiler/air heater where steam is generated and gas turbine air is indirectly ...

Science.gov (United States)

Research is being carried out in this project in two areas which are of interest to ongoing investigations at the Pittsburgh Energy Technology Center (PETC). They are: (a) thermal behavior of slurry reactors used for indirect coal liquefaction; and (b) coal liquefaction under supercritical conditions. The current status of each of these tasks is summarized in this report. 76 refs., 23 figs., 6 tabs.

British Library Electronic Table of Contents (United Kingdom)

The influence of geometry and operating conditions of the centrifugal compressor stage on the radial gas force is determined on the basis of the theoretical method and calculation program using experimental boundary conditions.

Energy Technology Data Exchange (ETDEWEB)

This report presents the work performed at the Institute of Gas Technology (IGT) during the second program quarter from October 1, 1993 to December 31, 1993, under Department of Energy (DOE) Contract No. DE-AC22-93PC92114. This program has co-ordinated funding for Task 1 from IGT`s Sustaining Membership Program (SMP), while DOE is funding Tasks 2--8. Progress in all tasks are reported. The overall objective of this research project is to develop a catalytic process to convert natural gas to liquid transportation fuels. The process consists of two steps that each utilize catalysts and sulfur containing intermediates: (1) to convert natural gas to CS{sub 2} and (2) to convert CS{sub 2} to gasoline range liquids. Experimental data will be generated to demonstrate the potential of catalysts and the overall process. During this quarter, progress in the following areas has been made. An ...

Energy Technology Data Exchange (ETDEWEB)

In the third quarterly report adsorption of heavy metals ions such as Cu(II) and Cr(VI) onto soils drawn from the laboratory-type wetland was shown to be weak. Secondly, it was shown that modified-clays did adsorb Cr(VI) ions strongly at pH 4.5. Further, studies on the pH dependence of the adsorption of {beta}-naphthoic acid, (NA), a well-documented contaminant in many oil and gas well waste waters onto modified-clays were undertaken and it was shown that uptake of NA by modified-clays was of the high affinity type at pH 4.5 and 7.0, but weak at pH 9.0. Adsorption of heavy metal ions, Cu{sup 2+}, and Cr(VI) onto algae, a proposed wetland amendment, was carried out and the results were presented and discussed in the fourth quarterly report. Uptake of NA by the soil component of the laboratory-type wetland was monitored as a function of pH. This quarterly report presents results from studies on the uptake ...

Science.gov (United States)

No Abstract Available

Energy Technology Data Exchange (ETDEWEB)

Coal may be used to generate electrical energy by any of several processes, most of which involve combustion or gasification. Combustion in a coal-fired boiler and power generation using a steam-cycle is the conventional conversion method; however total energy conversion efficiencies for this type of process are only slightly over 30%. Integration of a gas-cycle in the process (combined cycle) may increase the total conversion efficiency to 40%. Conversion processes based on gasification offer efficiencies above 50%. H{sub 2}S is the predominant gaseous contaminant in raw coal gas. This process is concerned with the removal of H{sub 2} from coal gas through an electrochemical membrane technology.

Energy Technology Data Exchange (ETDEWEB)

In this first quarterly technical report for DOE Contract No. DE-AC22-87PC79654, a description of the background, technology, and application is provided. The design and fabrication of advanced combustion chambers were completed during this period. Initial testing on both the bare metal and refractory lined advanced chambers were initiated. The units were tested initially with gas but primarily with coal. A Pittsburgh No. 8 pulverized coal was used for these test activities. Both advanced chambers pulsed well.

Science.gov (United States)

The H-Coal ebullated bed reactor contains at least four discrete components: gas, liquid, catalyst, and unconverted coal and ash. Because of the complexity created by these four components, it is desirable to understand the fluid dynamics of the system. The objective of this program is to establish the dependence of the ebullated bed fluid dynamics on process parameters. This will permit improved control of the ebullated bed reactor. Progress has been made in the study undertaken for defining the hydrodynamic properties of gas/liquid/solid systems as related to the H-Coal process. The literature search was completed, and a report will be issued shortly. Design and construction of the fluid dynamics unit proceeded as planned. Unit completion is scheduled for May 1, 1978.

Energy Technology Data Exchange (ETDEWEB)

The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of ...

Energy Technology Data Exchange (ETDEWEB)

Short-term radon measurements were used to make a comparison between weekly screening tests and seasonal concentration. The screening measurements were made in an indoor environment over a period of one quarter during early summer and the results are compared with the measured average radon level over that period. In these experiments, the envelope-type and plastic bag monitors were used for screening and long term radon concentration measurements, respectively. The results show that one cannot achieve predicting the seasonal mean radon concentration based on weekly measurements better than 50% under the conditions reported. (author).

Energy Technology Data Exchange (ETDEWEB)

A High Performance Power System (HIPPS) is being developed. This system is a coal-fired, combined cycle plant with indirect heating of gas turbine air. Foster Wheeler Development Corporation and a team consisting of Foster Wheeler Energy Corporation, Bechtel Corporation, University of Tennessee Space Institute and Westinghouse Electric Corporation are developing this system. In Phase 1 of the project, a conceptual design of a commercial plant was developed. Technical and economic analyses indicated that the plant would meet the goals of the project which include a 47 percent efficiency (HHV) and a 10 percent lower cost of electricity than an equivalent size PC plant. The concept uses a pyrolyzation process to convert coal into fuel gas and char. The char is fired in a High Temperature Advanced Furnace (HITAF). The HITAF is a pulverized fuel-fired boiler/air heater where steam is generated and gas turbine air is indirectly ...

Energy Technology Data Exchange (ETDEWEB)

The corrosion behavior of 304 stainless steel was characterized with cyclic voltammetry in a eutectic Li/K and Li/Na carbonate melt under anode and cathode gas of the molten-carbonate fuel cell (MCFC). The corrosion rate of 304 steel was determined in four different environments of the MCFC with electrochemical methods and from cross-sectional analysis of corrosion layers. These four environments were open-circuit and MCFC-load conditions both under anode and cathode gas. At open-circuit conditions corrosion was more severe under the oxidizing cathode gas then under the reducing anode gas. On the contrary, at load conditions corrosion was more severe under anode than under cathode gas. The anodic polarization under anode gas enhances corrosion, whereas the high anodic polarization under cathode ...

Energy Technology Data Exchange (ETDEWEB)

Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is crucial in meeting the needs of ...

Science.gov (United States)

DOE's program for the conversion of coal to liquid fuels was begun by two of DOE's predecessor agencies: Office of Coal Research (OCR) in 1962, and Bureau of Mines, US Department of the Interior, in the 1930's. Current work is aimed at improved process configurations for both catalytic and non-catalytic processes to provide more attractive processing economics and lower capital investment. The advantage of coal liquefaction is that the entire range of liquid products, especially boiler fuel, distillate fuel oil, and gasoline, can be produced from coal by varying the type of process and operating conditions used in the process. Furthermore, coal-derived liquids have the potential for use as chemical feedstocks. To provide efficient and practical means of utilizing coal resources, DOE is supporting the development of several conversion processes that are currently in the pilot plant stage. DOE, together with the Electric Power Research ...

Energy Technology Data Exchange (ETDEWEB)

Effects of combustion conditions on the critical calorific value of flame blowout were reported for low calorific gas on the assumption of using coal derived gaseous fuel. Further, calculations of adiabatic flame temperature by using chemical equilibrium calculation were conducted in order to get a possibility of increasing exit gas temperature of gas turbine combustor to 1,300 C for low calorific value gas fuel. As a result, effects of (1) fuel composition, (2) preheating fuel temperature, (3) calorific value, and (4) combustion air velocity and fuel nozzle diameter, on the critical calorific values of flame blowout were clarified. In increasing exit gas temperature of gas turbine combustor to 1,300 C when using low calorific value gas fuel, it is essential to get an advanced cooling technology for the ...

Energy Technology Data Exchange (ETDEWEB)

This report provides a brief summary of the milestone for Quarter 1 of 2006 of the NATional CARBon Sequestration Database and Geographic Information System (NATCARB) This milestone assigns consistent symbology to the ''National CO{sub 2} Facilities'' GIS layer on the NATCARB website. As a default, CO{sub 2} sources provided by the Regional Carbon Sequestration Partnerships and the National Group are now all one symbol type. In addition for sinks such as oil and gas fields where data is drawn from multiple partnerships, the symbology is given a single color. All these modifications are accomplished as the layer is passed through the national portal (www.natcarb.org). This documentation is sent to National Energy Technology Laboratory (NETL) as a Topical Report and will be included in the next Annual Report.

Energy Technology Data Exchange (ETDEWEB)

Gas turbine component protection remains essential but environmental regulations emphasize the gas-turbine efficiency. Heating and cooling are features often integrated into the GI air intake packages to provide the optimum operating conditions. This paper describes modern inlet air treatment systems and discusses their effectiveness. (author)

Science.gov (United States)

The report describes a computer model developed by TVA to simulate the performance and determine the economics of coal cleaning, or coal cleaning combined with flue gas desulfurization (FGD), for power plant emission control processes over a wide range of user-specified condition...

Energy Technology Data Exchange (ETDEWEB)

The European gas market is continuing to expand due to increased industrial, domestic and power generation demand. As a result of this demand, and the trend toward liberalization of the market, the need for storage of gas is also increasing. One key segment of the large scale storage of gas is underground storage, either in partially depleted gas or oil fields, naturally occurring caverns, aquifers and salt cavities. In most cases the gas produced after storage requires conditioning to meet the water of hydrocarbon dew point specification of the gas transmission system. For that reason export gas from storage will require gas conditioning in order to meet pipeline specifications. Adsorption as a feasible and reliable process will be presented in detail and especially in regards ...

International Science & Technology Center (ISTC)

Hard Nano-Strutural Coatings Resistant to the Extreme Conditions of Chemical, Abrasive and High Energy Media for Thermonuclear Power, Oil and Gas and Chemical Industries

Energy Technology Data Exchange (ETDEWEB)

Gas hydrates are crystalline substances composed of water and gas, in which a solid-water-lattice accommodates gas molecules in a cage-like structure. Gas hydrates are globally widespread in permafrost regions and beneath the sea in sediment of outer continental margins. While methane, propane, and other gases can be included in the clathrate structure, methane hydrates appear to be the most common in nature. The amount of methane sequestered in gas hydrates is probably enormous, but estimates are speculative and range over three orders of magnitude from about 100,000 to 270,000,000 trillion cubic feet. The amount of gas in the hydrate reservoirs of the world greedy exceeds the volume of known conventional gas reserves. Gas hydrates also represent a significant drilling and production hazard. A fundamental question ...

International Nuclear Information System (INIS)

The performance of the gas-jet transport system coupled to the RIKEN gas-filled recoil ion separator GARIS was investigated using 255No produced in the 238U(22Ne, 5n)255No reaction. Alpha particles of 255No separated with GARIS and transported by the gas-jet system were measured with a rotating wheel apparatus for ? spectrometry under low background condition. The high gas-jet efficiencies of about 75% were independent of the recoil ranges of 255No in the gas-jet chamber. The present results suggest that the GARIS/gas-jet system is a promising tool for the next-generation superheavy element chemistry: (1) the background radioactivities of unwanted reaction products are strongly suppressed, (2) the intense beam is absent in the gas-jet chamber and hence the high gas-jet efficiency is achieved, and (3) ...

Energy Technology Data Exchange (ETDEWEB)

A combination of erosion and corrosion at the Victoria Junction coal preparation plant in Sydney, Nova Scotia was causing serious problems. Schedule 80 mild steel pipes were starting to fail as well as some quarter-inch steel plates in the lauders and chutes. Some corrosion tests were carried out and the high chloride level in the process water was felt to be the single most important contribution to the corrosion problem. Cast basalt was selected as a solution to the pipe wear problem. Three different types of abrasion/corrosion-resistant tiling - basalt tiles, kalceram tiles and ceramic tiles were well suited to the chloride conditions at this plant.

Energy Technology Data Exchange (ETDEWEB)

The six-axes industrial robot MANUTEC r15 UW was modified to work underwater and successfully tested down to the simulated water depth of 1100 m. Next step in the program was to use this robot as a handling tool for inspection tasks at the welding seam of an underwater structure conducted with CCD-cameras and distance sensors. This was also to demonstrate the possibility to assist and later on to replace divers from this work. Additional research was focussed on the stiffness and rigidity of the robot during the precise guiding of tools and workpieces under current water conditions up to a flow velocity of 1.1 m/s. Present work is concentrated on the application of this subsea robot on a maintenance task at the Brazilian underwater template OCTOS-1000. For this experiments the robot is integrated in a large mock-up which simulates a quarter section of this template. (orig.)

Science.gov (United States)

The first quarter 1982 report summarizes the operating and test data obtained at the six ton per day Advanced Coal Liquefaction Research and Development Facility in Wilsonville, Alabama. The Wilsonville R and D Facility was in operation 52% of the period with scheduled shutdowns accounting for 33% of the downtime. Illinois 6 coal from the Burning Star No. 2 mine was processed during Run 236. The three process units of the Wilsonville facility were operated in a non-integrated mode to evaluate process parameters and to test equipment and operating modifications. Data were obtained in the following areas: In the SRC Unit: operation at low severity reaction conditions for single stage liquefaction with a high LSRC recycle rate using Illinois 6 coal; process solvent activity control; and preliminary feeding tests with hydrotreated SRC as a replacement for LSRC in the process solvent. In the CSD Unit: operation with T102 Vacuum Column bottoms ...

Energy Technology Data Exchange (ETDEWEB)

Accomplishments for the quarter are presented for the following areas of research: oil shale, tar sand, coal, advanced exploratory process technology, and jointly sponsored research. Oil shale research includes; oil shale process studies, environmental base studies for oil shale, and miscellaneous basic concept studies. Tar sand research covers process development. Coal research includes; underground coal gasification, coal combustion, integrated coal processing concepts, and solid waste management. Advanced exploratory process technology includes; advanced process concepts, advanced mitigation concepts, and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO[sub 2] HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis ...

Science.gov (United States)

The goal of GRI's Gas Appliance Technology Center is to encourage the introduction of highly efficient, cost-effective, convenient gas appliances for residential and commercial gas users. The report covers activity at Battelle from February 1989 to April 1990 in broad support tasks, residential and commercial appliances, and residential space conditioning. Broad support tasks included the G/A/S Newsletter; the GATC InfoBase; and technology transfer, workshops, and GATC coordination. Residential appliance tasks included burner technology research, gas appliance venting, gas lighting, and plastics durability. Commercial appliance tasks included development of a commercial cooktop fuel/air mixing valve. Residential space conditioning tasks included a corrosion test method for gas appliances and ...

Energy Technology Data Exchange (ETDEWEB)

Kawasaki Heavy Industries, Ltd. has developed a gas turbine combined cycle and cogeneration plant computer aided engineering (CAE) system, which creates cycle heat balance automatically on given configurations of gas turbines, heat recovery boilers, steam turbines and auxiliaries. The system can predict the performance of the plant as a function of control set points, loads, process steam requirements and ambient conditions, which enables accurate and fast design of gas turbine combined cycle and cogeneration plants. (author)

British Library Electronic Table of Contents (United Kingdom)

Natural gas is a promising alternative fuel to meet strict engine emission regulations in many countries. Natural gas engines can operate at lean burn and stoichiometric conditions with different combustion and emission characteristics. In this paper, the operating envelope, fuel economy, emissions, cycle-to-cycle variations in indicated mean effective pressure and strategies to achieve stable combustion of lean burn natural gas engines are highlighted. Stoichiometric natural gas engines are briefly reviewed. To keep the output power and torque of natural gas engines comparable to those of their gasoline or Diesel counterparts, high boost pressure should be used. High activity catalyst for methane oxidation and lean deNOx system or three way catalyst with precise air-fuel ratio control str...

Energy Technology Data Exchange (ETDEWEB)

The goal of this project is to develop a bench-scale procedure to produce clean, desulfurized, premium-quality chars from the Illinois basin coals. This goal is achieved by utilizing the effective capabilty of smectites in combination with methane to manipulate the char yields. The major objectives are: to determine the optimum water- ground particle size for the maximum reduction of pyrite and minerals by the selective-bitumen agglomeration process; to evaluate the type of smectite and its interlamellar cation which enhances the premium-quality char yields; to find the mode of dispersion of smectites in clean coal which retards the agglomeration of char during mild gasification; to probe the conditions that maximize the desulfurized clean-char yields under a combination of methane+oxygen or helium+oxygen; to characterize and accomplish a material balance of chars, liquids, and gases produced during mild gasification; to identify the conditions ...

Energy Technology Data Exchange (ETDEWEB)

A natural gas and diesel dual-fuel turbocharged compression ignition (CI) engine is developed to reduce emissions of a heavy-duty diesel engine. The compressed natural gas (CNG) pressure regulator is specially designed to feed back the boost pressure to simplify the fuel metering system. The natural gas bypass improves the engine response to acceleration. The modes of diesel injection are set according to the engine operating conditions. The application of honeycomb mixers changes the flowrate shape of natural gas and reduces hydrocarbon (HC) emission under low-load and lowspeed conditions. The cylinder pressures of a CI engine fuelled with diesel and dual fuel are analysed. The introduction of natural gas makes the ignition delay change with engine load. Under the same operating conditions, the emissions of smoke and ...

CERN Multimedia

The experiment NA59: The "Quarter Wave Plate" is a "110" silicon crystal of 5 cm diameter and 10 cm long

CERN Document Server

We have used the SINFONI integral field spectrograph to map the near-infrared K-band emission lines of molecular and ionised hydrogen in the central regions of two cool core galaxy clusters, Abell 2597 and Sersic 159-03. Gas is detected out to 20 kpc from the nuclei of the brightest cluster galaxies and found to be distributed in clumps and filaments around it. The ionised and molecular gas phases trace each other closely in extent and dynamical state. Both gas phases show signs of interaction with the active nucleus. Within the nuclear regions the kinetic luminosity of this gas is found to be somewhat smaller than the current radio luminosity. Outside the nuclear region the gas has a low velocity dispersion and shows smooth velocity gradients. There is no strong correlation between the intensity of the molecular and ionised gas emission and either the radio or ...

International Nuclear Information System (INIS)

This study develops a statistical model of industrial US natural gas consumption based upon historical data for the 1958-2003 period. The model specifically addresses interfuel substitution possibilities and changes in the industrial economic base. Using a relatively simple approach, the framework can be simulated repeatedly with little effort over a range of different conditions. It may also provide a valuable input into larger modeling exercises where an organization wants to determine long-run natural gas prices based upon supply and demand conditions. Projections based upon this demand framework indicate that industrial natural gas consumption may grow more slowly over the next 20 yr than being projected by the U.S. Energy Information Administration (EIA). This conclusion is based upon the assumption that natural gas prices will follow oil prices, as they ...

Energy Technology Data Exchange (ETDEWEB)

This fourteenth quarterly technical progress report of the MHD Integrated Topping Cycle Project presents the accomplishments during the period November 1, 1990 to January 31, 1991. Testing of the High Pressure Cooling Subsystem electrical isolator was completed. The PEEK material successfully passed the high temperature, high pressure duration tests (50 hours). The Combustion Subsystem drawings were CADAM released. The procurement process is in progress. An equipment specification and RFP were prepared for the new Low Pressure Cooling System (LPCS) and released for quotation. Work has been conducted on confirmation tests leading to final gas-side designs and studies to assist in channel fabrication.The final cathode gas-side design and the proposed gas-side designs of the anode and sidewall are presented. Anode confirmation tests and related analyses of anode wear mechanisms used in the selection of the ...

Energy Technology Data Exchange (ETDEWEB)

New furnaces were built based on fused silica with NiChrome heating elements custom-wound on alumina ceramic to self-compensate for induced magnetic fields during operation. During tests these furnaces failed due to thermal stresses caused by the high temperature cement used to hold the alumina ceramic in place. As a third solution pieces of boron nitride have been procured from which new furnace bodies will be machined during the third quarter. In order to increase the in-house capacity for machining ceramic parts a small lathe was ordered. The implementation of the LabView data acquisition software from National Instruments, Inc. took more time than anticipated and is still not completed. Major difficulties had to be overcome during the integration of the separate positive and negative high voltage supplies ({plus_minus}1000V). It became apparent that a custom-designed switch had to be installed to safeguard the data acquisition modules and the Apple Macintosh ...

Energy Technology Data Exchange (ETDEWEB)

The mining and energy industry is under assault today for reasons that have less to do with alleged technical failures and much more to do with ethical complaints about a rate of growth in population that industrial products from mining resources have made possible. The political agendas of Western industrialized nations have been driven during the past quarter century by those whose social philosophy advocates a new ethic of biocentric equality, whereby humans must be forced to being `living as if Nature mattered`. A Green ethic requires that `a violent, plundering humankind` must abandon its alleged rape of the earth and derive its ethical norms from pre-existing ecosystemic harmonies to preserve a fragile and precarious balance existing in Nature. From the perspective of history, there is nothing new about such complaints, current complaints about the use of fossil fuels and pollution from mining, echo similar complaints in past periods. Current Green thinking ...

Energy Technology Data Exchange (ETDEWEB)

All of the project work since the previous report has been on Phase 2B tasks. Therefore, this quarterly progress report summarizes the period's activities in Engineering, Procurement and Civil Construction. Engineering is 95% complete, but revisions and changes are still being incorporated particularly in the Instrument and Electrical areas. Procurement has only valves 4 in. and above yet to order to complete all major items purchased. The scheduled material curve was based on the original estimate of the job. The projected curve reflects the previous month's estimate. Construction of civil work is proceeding according to schedule in the field. The initial bid packages for the Mechanical General Contractor portion of the work have been reviewed and evaluated. Order placement is scheduled for the end of July. The Electrical package is due back from the bidders on July 6. It requires additional evaluation by BSC and DSO and will not be placed until ...

Energy Technology Data Exchange (ETDEWEB)

This document describes research performed at the Morgantown Energy Technology Center in the areas of oil and gas, advanced systems application, environmental technologies, applied energy science and remediation. The following subtasks are described: CROW{sup TM} Process Modeling, Development of a Portable Data Acquisition System and Coalbed Methane Simulator, Tank Bottom Waste Processing using the TaBoRR{sup TM} Process, Process Support and Development, Eastern Shale Oil Residue as an Asphalt Additive, Solid Waste Management, Remediation of Contaminated Soils, The Syn-Ag{sup TM} Process: Coal Combustion Ash Management Option, the Maxi-Acid{sup TM} Process: In- sit Amelioration of Acid Mine Drainage, Spill Test Facility Database, Heavy Oil/Plastics Co-Processing, Fossil Fuel and Hydrocarbon Conversion Using Hydrogen-Rich Plasmas, and North Site Remediation.

Energy Technology Data Exchange (ETDEWEB)

The authors report the fabrication and characterization of a low temperature (200--400 C) thin film gas sensor constructed from a MOCVD-grown yttria-stabilized zirconia (YSZ) layer sandwiched between two platinum thin film electrodes. A reproducible gas-sensing response is produced by applying a cyclic voltage which generates voltammograms with gas-specific current peaks and shapes. Growth conditions are optimized for preparing YSZ films having dense microstructures, low leakage currents, and maximum ion conductivities. In particular, the effect of growth temperature on film morphology and texture is discussed and related to the electrical and gas-sensing properties of the thin film sensor device.

Science.gov (United States)

The Gas Research Institute established the Gas Appliance Technology Center (GATC) in 1982 to develop improved gas appliances. Between 1986 and 1992, the scope of GATC activities at Battelle included technology transfer and overall industry support, residential appliances, commercial appliances, and residential space conditioning. The following tasks are representative of the GATC activities described in the report; gas burner technology, appliance venting, emissions, water heating, range/oven technology, self-powered appliances, commercial cooktop burners, reconstituting ovens, appliance reliability improvement, combination space-heating/water-heating systems, condensing heat exchangers, corrosion testing, and space heating technology. The report includes references to available sources for further reading.

Energy Technology Data Exchange (ETDEWEB)

Uranium enrichment by gas centrifugation relies on the pressure diffusion of the isotopes when their gaseous mixture is submitted to the pressure diffusion in the strong radial pressure gradient due to the centrifugal force in a very rapidly rotating cylinder. To compute the isotope separation in a gas centrifuge, the viscous compressible Navier-Stokes equations are solved for the mixture, then the diffusion equations are solved for the isotopes. As far as the separation performance is concerned, the models deal with the steady state of the axi-symmetric gas motion in the rotating cylinder. The numerical tools are briefly presented: first, the MOLINA code which numerically solves the axi-symmetric gas motion in the specific conditions of rapid rotation by use of a change of variables suited to the high density gradient and by use of a Marker And Cell method; then, the diffusion ...

International Nuclear Information System (INIS)

The possibility of surface modification of high-speed steel cutting tool by means of vacuum-plasma treatment including ion nitriding in gas plasma followed by the deposition of wear resistant (Ti, Al)N coatings in metal-gas plasma of a vacuum arc discharge is studied. The regularities of nitrided layer formation and the structure of these layers under various operation conditions of cutting tool are investigated. Optimum conditions of vacuum-plasma treatment providing the best wear resistance of cutting are determined

International Nuclear Information System (INIS)

Thermodynamic consideration and process calculations at equilibrium conditions showed that processes for separating gas mixtures by partial condensation at low temperatures using turboexpanders have got less energy losses than processes with quasi isobar partial condensation. Compared to the low-pressure parts of condensing steam turbines in turboexpanders less erosion problems are to expected for such separating processes. Separation of liquid in the machine, however, is more difficult withouf additional measures. (orig.).

Science.gov (United States)

The developments of oil and gas fields in deep waters (5000 ft and more) will become more common in the future. It is inevitable that production systems will operate under multiphase flow conditions (simultaneous flow of gas-oiland water possibly along wi...

Energy Technology Data Exchange (ETDEWEB)

This is the second technical report, covering the period from April 1, 2003 through September 30, 2003. This project brings together three parts of the oil exploration, development, and permitting process to form the foundation for a more fully integrated information technology infrastructure for the State of Alaska. The geo-technical component is a shared effort between the State Department of Administration and the US Department of Energy. The Alaska Oil and Gas Conservation Commission is rapidly converting high volumes of paper documents and geo-technical information to formats suitable for search and retrieval over the Internet. The permitting component is under the lead of the DNR Office of Project Management and Permitting. A web-based system will enable the public and other review participants to track permit status, submit and view comments, and obtain important project information on-line. By automating several functions of the current manual process, ...

CERN Document Server

In this paper we will report on the operation and the performance of the ATLAS data-flow system during the 2010 physics run of the Large Hadron Collider (LHC) at 7 TeV. The data-flow system is responsible for reading out, formatting and conveying the event data, eventually saving the selected events into the mass storage. By the second quarter of 2010, for the first time, the system will be capable of the full event building capacity and improved data-logging throughput. We will in particular detail the tools put in place to predict and track the system working point, with the aim of optimizing the bandwidth and the computing resource sharing, and anticipate possible limits. Naturally, the LHC duty cycle, the trigger performance, and the detector configuration influence the system working point. Therefore, numerical studies of the data-flow system capabilities have been performed considering different scenarios. This is crucial for the first phase of the LHC ...

Science.gov (United States)

All first-stage experimental tests were completed for Task 4 (and the Contract). The first-stage one-liter autoclave tests that were made were duplicates of Run 41-LA. The conditions used were chosen last quarter to reduce the cost of the first-stage of the process from those used at the conclusion of Task 3. Filtration and second-stage tests were made using the products of the first-stage tests. Post-second-stage filtration, tested as an alternative to interstage (pre-second- stage) filtration, resulted in low filtration rates. Different catalyst loadings and type and residence time for second-stage hydrotreating were explored. Longer residence times did not result in significantly more resid conversion. Higher catalyst loadings were more effective in converting the resid at the same residence time. The material and elemental balances for the first-stage were completed. The material and elemental balances for the second-stage were initiated.

International Nuclear Information System (INIS)

Electricity generation from natural gas in gas turbine units can be made substantially more efficient by preliminary methane conversion to a synthesis gas containing hydrogen and carbon monoxide and/or by the use of some of the synthesis gas produced in industry. An alternative improvement involves the introduction of solid oxide fuel cells (SOFCs) and the use of the synthesis gas in them. In this study, a modified scheme of gas turbine cycle that includes an SOFC, a membrane reactor (instead of a traditional combustion chamber), and a catalytic reactor to perform methane conversion to produce hydrogen (synthesis gas) is proposed. Variations of the energy and exergy efficiencies of the integrated system with operating conditions are provided, showing, for example, that SOFC efficiency is enhanced if the fuel cell active ...

Energy Technology Data Exchange (ETDEWEB)

The shrinking core model is examined for gas-solid noncatalytic reactions with a self-inhibited rate form and it is shown that multiple reaction pathways are possible for solid particles reacted under identical conditions. The observed reaction rate can have up to two discontinuities (jumps) during reaction for particles of spherical and cylindrical shape. The geometric instability analysis reveals that the reaction interface is stable under a very limited set of conditions only for solid particles of slab geometry. For a sphere or cylinder at large Biot numbers the reaction interface is always potentially unstable. This model provides a plausible explanation for gas-solid reactions which exhibit erratic shrinking core behavior.

British Library Electronic Table of Contents (United Kingdom)

In this article a methodology is presented for studying the influence of the biomass moisture content and the biomass/air ratio on the producer gas composition and on the chemiluminescent emissions during the combustion process. Firstly, a mathematical model based on the thermo-chemical processes inside the gasifier is used to predict the composition of the producer gas as a mixture of CO, CO2, H2, N2, CH4 and H2O gases. Secondly, the predicted composition is introduced into a constant volume combustion bomb (CVCB), which simulates the typical conditions inside the combustion chamber of an internal combustion engine, in order to characterize its combustion under gasoline-type conditions through the instantaneous pressure and the detection of the spontaneous luminous radiation (chemilumines...

Energy Technology Data Exchange (ETDEWEB)

General conclusions, principles and order of substantiating the extractable reserves and coefficients of oil extraction from oil and oil and gas fields are presented. Recommendations are made for solving questions of constructing calculation models for heterogeneous beds, schematization of the working conditions, selection of mathematical models for oil extraction for different geological-field conditions and different stages of ''life'' of the field.

Energy Technology Data Exchange (ETDEWEB)

This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid vapor condensed in both the high temperature ...

Energy Technology Data Exchange (ETDEWEB)

The technical and economic feasibility of using a typical, elemental, phosphorus byproduct gas stream in methanol production is assessed. The purpose of the study is to explore the potential of a substitute for natural gas. The first part of the study establishes economic tradeoffs between several alternative methods of supplying the hydrogen which is needed in the methanol synthesis process to react with CO from the off gas. The preferred alternative is the Battelle Process, which uses natural gas in combination with the off gas in an economically sized methanol plant. The second part of the study presents a preliminary basic design of a plant to (1) clean and compress the off gas, (2) return recovered phosphorus to the phosphorus plant, and (3) produce methanol by the Battelle Process. Use of elemental phosphorus byproduct gas in methanol ...

Energy Technology Data Exchange (ETDEWEB)

LEDF (Large Equipment Dismantling Facility) will be constructed for the purpose of decontaminating the high level {alpha} solid waste generated in oarai engineering center of JNC. And, main processing process of LEDF is incineration and melting system. LEDF will be intended to reduce the secondary waste that occurs along with the operation of the off gas processing equipment of incineration and melting system. It assumed that we are able to eliminate the adsorption tower using silica gel, if the decontamination factor to volatile ruthenium is able to expect in the packed scrubber that is established to remove harmful gas. Thereupon, we carried out this tests that eliminates the adsorption tower and reduces the secondary waste. The decontamination factor (DF) to the volatile ruthenium by the water scrubber is confirmed in the established institution which is in Tokai Works. However, decontamination factor differs and depends on the ruthenium ...

Energy Technology Data Exchange (ETDEWEB)

This paper focuses on the application and features of a unified multi-machine train condition monitoring and diagnostic system as applied to a 340 MW repowered combined cycle power plant. Modifications during repowering of the plant required the addition of gas turbines, and design changes to the boiler and steam turbine. Operational procedure during startup also had to be developed. In order to improve the economics of operation, enhancement of both plant operational efficiency and availability were required. Thus it was decided to implement an on-line plant-wide multi-machine Condition Monitoring System. In this paper, the details of the condition monitoring system and some of the design details of the power plant are presented. Requirements of a condition monitoring system applicable to a combined cycle plant are also covered. Salient system design features are explained. The ...

Energy Technology Data Exchange (ETDEWEB)

Gas and plasma nitriding processes were executed in the magnesium with modification by titanium in search for an effective surface treatment method for magnesium alloys. Magnesium-nitrogen system has completely no solid solution or solubility, so that nitride should be only formed by eutectic reaction in the liquid phase. Hence, magnesium is difficult or nearly impossible to have its surface modified by nitriding. Addition of nitride forming element into magnesium enables us to lower the onset temperature of nitriding. Magnesium-titanium alloys with 1 to 5 wt% are yielded by the bulk mechanical alloying and, subjected to gas nitriding for various process conditions. Successful co-formation of Mg{sub 3}N{sub 2} as well as TiN becomes a proof to demonstrate the possibility of gas/plasma nitriding in the solid-state magnesium with aid of nitride former. (orig.)

International Nuclear Information System (INIS)

The production of atmospheric pollutants in combustion processes depends on plant characteristic, combustion conditions and fuel quality. The influence of fuel quality on the emission of sulphur oxides, nitrogen oxides, carbon monoxide, dust and carbon dioxide and on the emission of some toxic pollutants, such as heavy metals and polycyclic aromatic hydrocarbons, is analysed. The comparison between the emission limits, fixed by the Italian legislation, and the uncontrolled pollutant emissions, produced by fossil fuel combustion in power plants and industrial use, shows that, in order to comply with the limits, a reduction of pollutant emissions is required through the use of abatement systems and cleaner fuels where natural gas has a primary role. The use of cleaner fuels is particularly required in heating plants and appliances for the residential sector, where the development of new gas technologies further increases the ...

Energy Technology Data Exchange (ETDEWEB)

In nuclear fuel, in approximately one quarter of the fissions, one of the two formed fission products is gaseous. These are mainly the noble gases xenon and krypton with isotopes of xenon contributing up to 90% of the product gases. These noble fission gases do not combine with other species, and have a low solubility in the normally used uranium oxide matrix. They can be dissolved in the fuel matrix or precipitate in nanometer-sized bubbles within the fuel grain, in micrometer-sized bubbles at the grain boundaries, and a fraction also precipitates in fuel pores, coming from fuel fabrication. A fraction of the gas can also be released into the plenum of the fuel rod. With increasing fission, and therefore burn-up, the ceramic fuel material experiences a transformation of its structure in the 'cooler' rim region of the fuel. A subdivision occurs of the original fuel grains of few microns size into thousands of small grains of ...

Energy Technology Data Exchange (ETDEWEB)

Limited demand and high cost has prevented the construction of hard rock caverns in this country for a number of years. The storage of natural gas in mined caverns may prove technically feasible if the geology of the targeted market area is suitable; and economically feasible if the cost and convenience of service is competitive with alternative available storage methods for peak supply requirements. It is believed that mined cavern storage can provide the advantages of high delivery rates and multiple fill-withdrawal cycles in areas where salt cavern storage is not possible. In this research project, PB-KBB merged advanced mining technologies and gas refrigeration techniques to develop conceptual designs and cost estimates to demonstrate the commercialization potential of the storage of refrigerated natural gas in hard rock caverns. Five regions of the U.S.A. were studied for underground storage development and PB-KBB ...

Energy Technology Data Exchange (ETDEWEB)

The productivity characteristics of perforated gas well are investigated for the first time under real conditions considering drilling damage, perforation compacted zone and anisotropy in this paper. A non-linear finite element model for non-Darcy flow in perforated gas reservoir is built to consider the effects of twelve factors on productivity ratio (PR) of perforated gas well. The nomographs for two cases are presented in this paper. Compared with previous works, the following results are found: (1) the effects of drilling damage and perforation diameter on PR of gas well are more remarkable than that in oil well; (2) any perforation phase may be the best or the worst as to perforating gas well, which depends on anisotropy, drawdown and that whether or not perforations are beyond drilling damage zone; (3) the increase in perforation length hardly improve PR ...

Energy Technology Data Exchange (ETDEWEB)

This is the third quarterly progress report for Year 3 of the ACTS Project. It includes a review of progress made in: (1) Flow Loop construction and development and (2) research tasks during the period of time between Jan. 1, 2002 and Mar. 31, 2002. This report presents a review of progress on the following specific tasks: (a) Design and development of an Advanced Cuttings Transport Facility (Task 3: Addition of a Cuttings Injection/Separation System), (b) Research project (Task 6): ''Study of Cuttings Transport with Foam Under LPAT Conditions (Joint Project with TUDRP)'', (c) Research project (Task 9b): ''Study of Foam Flow Behavior Under EPET Conditions'', (d) Research project (Task 10): ''Study of Cuttings Transport with Aerated Mud Under Elevated Pressure and Temperature Conditions'', (e) ...

Science.gov (United States)

... Airframe System Technoloqies Laser fabricated flooring Composite sandwich panels for noise control Spray formed HS aluminum alloys Protective ...

Science.gov (United States)

cellulose casing material made by Food Products Division,. Union Carbide Corporation. tion of the anode from oxygen generated at the charging electrode. ...

Science.gov (United States)

LASERASSISTED SOLAR CELL METALLIZATION PROCESSING DOE/JPL/956615--84/3. S. Dutta and P. G. McMullin. Quarterly Report for the period March 13 ...

Science.gov (United States)

Magnetic coil pressure wave generation for magnetic forming

Science.gov (United States)

A developed flue gas desulfurization and dust removal process with a cross-flow moving bed filled with activated coke (AC) was tested on a pilot scale with the gas treatment capacity of 1000 mg x h(-t). The results show that a easy-operating and stable-running pilot-scale testing equipment can be reached, and under the conditions of testing space velocity, the feed gas temperature of 120 degrees C, SO2 concentrations of 3232-6006 mg x m(-3) and dust concentration of 89.3-1599.7 mg x m(-3), the high efficiency of flue gas desulfurization and dust removal is reached with the purity of dust less than 50 mg x m(-3). In the technology, the spent AC was regenerated by heating, and the SO2 concentration in the desorption gas is about 40.1%, which can be efficiently recovered as a sulfur resource. Favorable economy benefit can be reached by using the process. ...

British Library Electronic Table of Contents (United Kingdom)

A laboratory-scale multi-layer system was developed for the adsorption of PCDD/Fs from gas streams at various operating conditions, including gas flow rate, operating temperature and water vapor content. Excellent PCDD/F removal efficiency (>99.99%) was achieved with the multi-layer design with bead-shaped activated carbons (BACs). The PCDD/F removal efficiency achieved with the first layer adsorption bed decreased as the gas flow rate was increased due to the decrease of the gas retention time. The PCDD/F concentrations measured at the outlet of the third layer adsorption bed were all lower than 0.1ng I-TEQNm-3. The PCDD/Fs desorbed from BAC were mainly lowly chlorinated congeners and the PCDD/F outlet concentrations increased as the operating temperature was increased. In addition, the r...

International Nuclear Information System (INIS)

The major driver to enhance the efficiency of the simple gas turbine cycle has been the increase in process conditions through advancements in materials and cooling methods. Thermodynamic cycle developments or cycle integration are among the possible ways to further enhance performance. The current paper presents the possibilities and advantages from the LOTHECO natural gas-fired combined cycle concept. In the LOTHECO cycle, low-temperature waste heat or solar heat is used for the evaporation of injected water droplets in the compressed air entering the gas turbine's combustion chamber. Following a description of this innovative cycle, its advantages are demonstrated by comparison between different gas turbine power generation systems for small and large-scale applications, including thermodynamic and economic analysis. A commercial gas turbine (ALSTOM GT10C) ...

International Nuclear Information System (INIS)

It has been reported by the present authors that behavior of tritium release from solid breeder grain is consisted of diffusion in grain, tritium transfer at surface layer and surface reactions on grain surface such as adsorption or isotope exchange reactions. Tritium release curves estimated using the tritium release model gave good agreement with observed tritium release curves from Li_4SiO_4, Li_2ZrO_3 or LiAlO_2. Tritium release behavior from Li_2TiO_3 under humid purge gas, dry purge gas and dry purge gas with hydrogen conditions is discussed in this study, tritium release curves using the release model that we proposed previously give a good agreements with experimental tritium release curves. Tritium effective diffusivity in the crystal grain of Li_2TiO_3 is also estimated in this study using a curve-fitting method applied to the release curves obtained under the humid purge ...

International Nuclear Information System (INIS)

During unit wise conditioning of unit 8, the vacuum started deteriorating inside the tube after a spark. The RGA reading was taken and it was found out that residual gas inside tube was sulphur hexafluoride. A leak was detected in second tube of unit number eight in between electrode 6 to 8. Leak was sealed with the sealant. Again leak check was done and no leak was found. The tank was closed and conditioning was started again. During the same unit number eight conditioning, leak developed again followed by a spark. So the damaged tube was replaced with a new accelerator tube. During the installation time the alignment of the machine was taken care. Again leak checking was done and the tube was baked properly. The tank was closed again and this particular unit was conditioned for about four days. The maximum voltage it has attained was 1.1 MV. (author)

Energy Technology Data Exchange (ETDEWEB)

During the last 15 years cycles with CO{sub 2} capture have been in focus, due to the growing concern over our climate. Often, a natural gas fired combined cycle with a chemical absorption plant for CO{sub 2} capture from the flue gases have been used as a reference in comparisons between cycles. Neither the integration of the steam production for regeneration of amines in the combined cycle nor the off-design behaviour of such a plant has been extensively studied before. In this paper, the integration of steam production for regeneration of the amines is modelled at design load and studied in off-design conditions for a combined cycle. Different ambient conditions and part-load strategies and their influence on the cycle performance are also examined. Of particular interest is a novel strategy with the possibility of longer life of gas turbine blading, with marginal loss in efficiency. The off-design ...

Energy Technology Data Exchange (ETDEWEB)

Heat fusion is the most common joining method for polyethylene gas distribution piping. Butt fusion was studied with the intent of relating the quality of the joint to the joining conditions. A semi-empirical approach was used. The thermofluid consequences of joining conditions such as heater temperature, heating time and joining parameter were calculated using a computer model. The model was validated by instrumented tests. The strength of the joints was gauged by destructive mechanical testing. Tensile and tensile impact tests were used. Over 150 joints were fabricated using four different polyethylene resins. Most of the data are given in GRI Report No. 88/0276.2 -- Volume 2: Technical Reference on Butt Heat Fusion Joining of Polyethylene Gas Pipes. A parameter, termed the Joining Parameter, was found to characterize the joining conditions. Of the mechanical tests parameters, the ...

Energy Technology Data Exchange (ETDEWEB)

The effect of combustion conditions on conversion of char nitrogen to N2 was studied in the combustion experiment of char obtained by pyrolysis of coal. Char specimen was prepared by holding ZN coal of Chinese lignite in Ar atmosphere at 1123K for one hour. A batch scale quartz-made fluidized bed reactor was used for combustion experiment. After the specimen was fluidized in reaction gas, it was rapidly heated to start combustion reaction. CO, CO2 and N2 in produced gases were online measured by gas chromatography (GC). As the experimental result, under the incomplete combustion condition where a large amount of CO was produced by consuming almost all of O2, no NOx and N2O produced from char were found, and almost all of N-containing gas was N2. At the final stage of combustion, pyridinic-N disappeared completely, and pyrrolic-N decreased, while O-containing nitrogen complexes ...

Environmental Research Database

ObjectivesNot EnteredDescriptionMethane hydrate in an ice-like substance consisting of molecules of methane gas combined chemically with water. It is stable at high pressures and low temperatures. Since the ocean floor is normally cold, but temperatures increase with depth inside the Earth, such conditions normally prevail for a few hundred meters below the seafloor where the ocean depth is more than a few hundred metres. Methane beneath the ocean floor is formed by the decomposition of organic material. At the edges of the co [continued...

International Nuclear Information System (INIS)

The interaction of free electrons in the energy range from 0 to 10 eV with molecules at different stages of aggregation is investigated. The mechanism in the gas phase under single collision conditions is described. Fullerenes C_6_0 and C_7_0 are used as targets. Electron impact on condensed molecules can lead to temporary negative ions. The formation of Cl"- from gas phase CCl_4 and the desorption of Cl"- from 6 monolayer CCl_4 film on an Au substrate is determined experimentally. (Suda).

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the Groundwater Monitoring Program conducted by SRS during third quarter 1998. It includes the analytical data, field data, data review, quality control, and other documentation for this program; provides a record of the program's activities; and serves as an official record of the analytical results.

Energy Technology Data Exchange (ETDEWEB)

Research continued on low severity coal liquefaction. Research using high temperature infrared of cyclic olefins progressed well during this quarter. Several fluorinated solvents were found that provide a high temperature medium for isotetralin and its aromatic and aliphatic analogues.

Energy Technology Data Exchange (ETDEWEB)

This report summarizes activities of the Amarillo National Resource Center for Plutonium during the quarter. The report describes the Electronic Resource Library; DOE support activities; current and future environmental health and safety programs; pollution prevention and pollution avoidance; communication, education, training, and community involvement programs; and nuclear and other material studies, including plutonium storage and disposition studies.

Wastenet

... Hale, Markku Kulmala, 373.43 EUR; 225.00 USD; 276.00 GBP... More Journals » MAGAZINES & JOURNALS Journal of Water Supply: Research &Technology -... Journal of Water Supply: Research and Technolog... Environmental Quarterly - 2009 Fall Trinity`s Environmental Quarterly (EQ) magazine co... ...

Wastenet

... Hale, Markku Kulmala, 373.43 EUR; 225.00 USD; 276.00 GBP... More Journals » MAGAZINES & JOURNALS Environmental Quarterly - 2009 Fall Trinity`s Environmental Quarterly (EQ) magazine co... Industrial Wastewater Responsible for managing your company`s wastes?... ...

Energy Technology Data Exchange (ETDEWEB)

Concepts involving combined gas-turbine/steam-turbine power-generation plants, in which the fuel gas for the gas turbine is produced via the gasification of coal, are now extremely advanced. This technology already permits efficiencies of around 50% current development targets view 65% as achievable. In conventional technology, efficiencies are tied to conditions, such as air and cooling-water temperatures, at the particular location. In combined-cycle power plants, the properties of the fuel coal also play an important part. There are, in face, coals which can be more advantageously used in a combined-cycle power plant than in a conventional one. These differences, combined with advantageous concepts for coal-fired combined-cycle power-generating plants, are presented and analyzed. Particular attention is devoted to individual losses occurring at coal conversion, thermodynamic cycles, integration of ...

Energy Technology Data Exchange (ETDEWEB)

We demonstrate that the nanoparticle formation during laser ablation of metals by short (of a few tens of ps) laser pulses strongly depends on the concentration of surrounding gas. While, at vacuum conditions, nanoparticle formation shows very ''sharp'' atomic force microscope images of aggregated clusters, following with clear appearance of plasmon resonance on the absorption spectra of deposited films, an addition of gas particles starts to decrease the probability of cluster formation. This process shows a threshold for both helium (33 torr) and xenon (12 torr) above which no surface plasmon resonance and correspondingly no observable nanoparticles on the deposited surfaces were detected. The destruction of nanoparticle formation was attributed to the negative influence of surrounding gas particles on ablated particles aggregation. (orig.)

British Library Electronic Table of Contents (United Kingdom)

Indoor and soil gas Radon (222Rn) concentration measurements were accomplished in two stages in Sivas, a central eastern city in Turkey. In the first stage, CR-39 passive nuclear track detectors supplied by the Turkish Atomic Energy Authority (TAEA) were placed in the selected houses throughout Sivas centrum in two seasons; summer and winter. Before the setup of detectors, a detailed questionnaire form was distributed to the inhabitants of selected houses to investigate construction parameters and properties of the houses, and living conditions of inhabitants. Detectors were collected back two months later and analysed at TAEA laboratories to obtain indoor 222Rn gas concentration values. In the second stage, soil gas 222Rn measurements were performed using an alphameter near the selected h...

Energy Technology Data Exchange (ETDEWEB)

The purpose of the Energy Incentives and Agricultural Financial Resources Act of 1986 is to provide fair incentives for the domestic production of oil and gas, and to give flexibility to financial institutions with regard to energy and agricultural loans. The legislation reflects the current drop in activity and investment as a result of economic conditions and tax laws. It amends the Federal Deposit Insurance Act to assist troubled banks in providing capital and restructuring loans for energy development and agricultural pursuits. Title II repeals certain restrictions on the use of natural gas and petroleum imposed under the Fuel Use Act to open up markets and eliminate pricing requirements.

British Library Electronic Table of Contents (United Kingdom)

A supercritical fluid-based method is proposed to produce coenzyme Q10 (CoQ10) nanoparticles. First, CoQ10/polyethylene glycol 6000 composite particles are prepared by a modified PGSS (particles from gas-saturated solutions) process with controlling the flow rate of the gas-saturated solution. Then, CoQ10 nanoparticles are obtained by dissolving the composite particles into water. The effect of experimental variables of the modified PGSS process, including pressure, temperature, flow rate of the gas-saturated solution, and mass fraction of CoQ10, on the CoQ10 particle size and particle size distribution was investigated. Results show that CoQ10 slurry product with a median diameter of 190nm and yield of 89.8% can be prepared at an optimum condition (operating pressure of 25MPa, operating t...

Energy Technology Data Exchange (ETDEWEB)

The analysis for the WITCH/LINER experiments was performed to investigate the heat transfer characteristics between the gas-agitated steel melt and the vertical surface. The applicability of heat transfer correlations for a gas-agitated fluid system was examined through the numerical analysis of the one-dimensional heat conduction taking into account the crust formation due to the solidification of the steel melt. The heat transfer correlation developed by Konsetov was modified for the application to fluids with low Prandtl number. The constant in the modified correlation was empirically found mainly through the comparison between the analysis and the experiments under conditions that a churn-turbulent two-phase flow regime was anticipated to form. The modified Konsetov correlation could predict the heat transfer characteristics observed through the experiments in an acceptable level. (author)

Energy Technology Data Exchange (ETDEWEB)

Metallic components within or immediately adjacent to gasifiers, such as gas distributors, thermowells, transfer lines, and cyclones, are subjected to severe of temperature, pressure, and hostile multicomponent gas environments. Metallic heat exchangers/waste-heat boilers resistant to sulfidation, corrosion. and erosion in low- and medium-Btu gas environments are essential components in large-scale gasification schemes, in both dry ash and slogging type gasifiers. Components, in general. must be resistant to corrosion, erosion, and high-temperature creep. A substantial data base is needed on the mechanical properties of materials exposed to complex gas environments to provide a more viable basis for establishing long-term reliability of components. This work examines high-temperature creep of Alloy 800, a high-chromium alloy widely used in coal conversion systems, after exposure to oxygen and ...

International Nuclear Information System (INIS)

In the present paper it is assumed that above a limiting value of fission fluency (burn-up) a more intensive process of irradiation introduced chemical interaction occurs. A significant part of fission gas product is thus expected to be chemically bounded in the matrix of UO_2 fuel. The fission gas atoms substituting, for example, uranium atoms in the crystallographic lattice can form weak facets. At a certain saturation condition, division of the grains can occur at the weak facets and the increase in fission-gas products release may be expected. The fact that the process of grain division for high burn-ups (70-80 MWd/kgU) forms an extremely fine structure up to the temperature as high as 1100 "oC and simultaneously the observed decreases in fission gas concentration in the fuel supports this concept. The analysis of fission gas concentration change due to the ...

Energy Technology Data Exchange (ETDEWEB)

For a direct injection diesel engine to exhibit its inherent low-emission characteristics, it is essential to improve control accuracy, in particular under transient operating conditions during which emissions are more noted. A model-based control system is established for exhaust gas recirculation (EGR) and air/fuel ratio, using a diesel-engine/vehicle model established on the CAD control system. Described herein are the results of simulation for optimizing control of transient conditions, and the emission-controlling effects confirmed by the field tests. The tests for verification of the established model have confirmed that there are good agreements between the simulated and observed results in terms of air/fuel ratio changing with EGR ratio, exhaust and intake gas and pressure levels, and vehicle speed. The model will be applicable to assessment of emission characteristics under varying ...

Energy Technology Data Exchange (ETDEWEB)

A study has been performed for the development and assessment of a subchannel analysis code which is purposed to be used for the analysis of advanced reactor conditions with various configurations of reactor core and several kinds of reactor coolant fluids. The subchannel analysis code was developed on the basis of MATRA code which is being developed at KAERI. A GUI (Graphic User Interface) system was adopted in order to reduce input error and to enhance user convenience. The subchannel code was complemented in the property calculation modules by including various fluids such as heavy liquid metal, gas, refrigerant,and supercritical water. The subchannel code was applied to calculate the local thermal hydraulic conditions inside the non-square test bundles which was employed for the analysis of CHF. The applicability of the subchannel code was evaluated for a high temperature gas cooled reactor ...

British Library Electronic Table of Contents (United Kingdom)

Doped ultrafine silicon dioxide powder with a narrow particle size distribution was obtained by RF discharge-stimulated dichlorosilane (SiH2C) oxidation at a low pressure using isobutylene as the combustion inhibitor and chromium hexacarbonyl (Cr(CO)6) as the dopant. The formation and morphology of the ultrafine particles are governed by the parameters of the RF discharge and by the chemical mechanism of the combustion reaction yielding the aerosol. Submicron-sized filamentous carbon structures can be obtained by isobutylene decomposition under spark discharge conditions in the presence of a molybdenum metal catalyst.

Energy Technology Data Exchange (ETDEWEB)

The ''Enabling & Information Technology To Increase RAM for Advanced Powerplants'' program, by DOE request, was re-directed, de-scoped to two tasks, shortened to a 2-year period of performance, and refocused to develop, validate and accelerate the commercial use of enabling materials technologies and sensors for coal/IGCC powerplants. The new program was re-titled ''Enabling Technology for Monitoring & Predicting Gas Turbine Health & Performance in IGCC Powerplants''. This final report summarizes the work accomplished from March 1, 2003 to March 31, 2004 on the four original tasks, and the work accomplished from April 1, 2004 to July 30, 2005 on the two re-directed tasks. The program Tasks are summarized below: Task 1--IGCC Environmental Impact on high Temperature Materials: The first task was refocused to address IGCC environmental impacts on high temperature materials used in ...

Energy Technology Data Exchange (ETDEWEB)

Conversion of coal gas into liquid products is a multistep process which involves numerous unit processes. Compared with similar processes using natural gas as feedstock, there are challenges, particularly with the gas purification. There are, however, also advantages when using a carbon-monoxide-rich gas which ultimately may result in a greatly simplified process. This paper discusses the challenges when converting a gas from an entrained coal gasifier into a liquid product and the paper presents the various options available. The following issues will be touched upon: sour gas shift and adjustment of the H{sub 2}/CO ratio; acid Gas Removal (AGR) - when and how; syngas purification; methanol and combined methanol/DME synthesis; gasoline synthesis; future integrated processes. Here, various options are available depending on the gasifier; ...

Energy Technology Data Exchange (ETDEWEB)

The investigations of lignite hydroliquefaction were aimed at improving reaction control in order to minimize residue and gas portion and hence increase the oil yield. To reach this goal, the process parameters were optimized and various catalysts tested for use in sump phase hydrogenation. Detailed investigations were also carried out on the problem of calcium carbonate agglomeration and the maceral decomposition behaviour of different lignite samples under hydrogenation conditions.

Energy Technology Data Exchange (ETDEWEB)

The conductivity of the membrane is a limiting factor for the efficiency and power density of PEFCs. Because this conductivity is strongly dependent on the membrane hydration, water management is an important aspect of PEFC optimisation. Single cell model experiments were made in order to determine the in-plane hydration of a Nafion{sup R} membrane under fuel cell conditions as function of the gas humidities. (author) 4 fig., 3 refs.

Energy Technology Data Exchange (ETDEWEB)

The phenomenon of runaway electrons (REs) at high values of the ratio field intensity/gas number density {ital E}/{ital N} and {ital N} up to the Loshmidt number {ital N}{sub {ital L}}{approx_equal}2.7{times}10{sup 19} cm{sup {minus}3} is described. REs are shown to govern the breakdown and discharges at such condition. {copyright} {ital 1996 American Institute of Physics.}

Energy Technology Data Exchange (ETDEWEB)

During thirty years the techniques used for sensing the environment have changed dramatically. This paper describes the latest generation of sensors available. This new generation of sensors includes those two most critical gas sensors for methane and carbon monoxide and new sensors for airflow and air temperature. When these sensors are combined with the new sensors for machine condition monitoring it forms the heart of the Sentex system. 2 figs.

CERN Document Server

We present experimental studies on the photoionization and photodissociation processes (photodestruction) of gaseous amino acids and nucleobases in interstellar and interplanetary radiation conditions analogs. The measurements have been undertaken at the Brazilian Synchrotron Light Laboratory (LNLS), employing vacuum ultraviolet (VUV) and soft X-ray photons. The experimental set up basically consists of a time-of-flight mass spectrometer kept under high vacuum conditions. Mass spectra were obtained using photoelectron photoion coincidence technique. We have shown that the amino acids are effectively more destroyed (up to 70-80%) by the stellar radiation than the nucleobases, mainly in the VUV. Since polycyclic aromatic hydrocarbons have the same survival capability and seem to be ubiquitous in the ISM, it is not unreasonable to predict that nucleobases could survive in the interstellar medium and/or in comets, even as a stable cation.

Energy Technology Data Exchange (ETDEWEB)

The Oxycoal burner for pulverised coal combustion previously developed by the authors has been scaled up to typical power plant dimensions and a CFD study of pulverised coal combustion in a 1200 MWth oxy-firing furnace has been performed. The study revealed the importance of modelling the flue gas radiation behaviour for flue gas temperatures and wall heat transfer. This was done using a non-grey implementation of the Exponential Wide Band Model (EWBM). Typically, comparisons between air and oxy-fired furnaces point out that to obtain similar flame behaviour, the oxygen content in oxy-firing conditions should be increased until the same adiabatic flame temperature is reached. However, it was found that for these conditions, significantly increased wall heat fluxes can be the result. Furthermore, at gas temperatures comparable to air combustion, particle burnout is accelerated in ...

Energy Technology Data Exchange (ETDEWEB)

Chemical-looping combustion is a promising technology for the combustion of gas or solid fuel with efficient use of energy and inherent separation of CO{sub 2}. Chemical-looping combustion of methane with calcium sulfate as a novel oxygen carrier was conducted in a laboratory scale fixed bed reactor. The effects of reaction temperature, gas flow rate, sample mass, and particle size on reduction reactions were investigated and an optimum operating condition was determined. The results show that this novel oxygen carrier has a high reduction reactivity and stability in a long-time reduction/oxidation test. The conversions of CH{sub 4} increased with a higher temperature, smaller gas flow rate, larger sample mass and smaller particle size. The suitable reaction temperature seems to be around 950 deg. C. Low temperatures lead to a low CH{sub 4} conversion, but a significant SO{sub 2} formation was observed ...

Energy Technology Data Exchange (ETDEWEB)

Fourier transform infrared spectroscopy is a simple, fast, reliable and nondestructive analytical method. By using the method developed in Clark Atlanta University, consistent and reliable infrared spectral results can be obtained. An accurate radiant energy can be calculated from these infrared spectra by using a blackbody as the calibration standards. By means of the specially-designed-and-lab-made sampling inlet and the Horiba gas analyzers, the compositions of CO{sub 2}, CO, UCH, NOx and O{sub 2} etc. from the combustion exhaust gases have been on-line accurately analyzed. The commercial natural gas IR burner performed differently in the different conditions. For the methane-air combustion, at the equivalence ratio {Phi} = 1, the IR burner produced its maximum radiation efficiency, {approximately}31.4%, and the concentration of CO{sub 2} reached its maximum value, {approximately}10.7%. In the fuel-lean region, the O{sub ...

Energy Technology Data Exchange (ETDEWEB)

Radioiodinated 15-(p-iodophenyl)-3,3-dimethylpentadecanoic acid (DMIPP) has been prepared as a new terminal iodophenyl-substituted fatty acid containing dimethyl-branching at the beta-position. Iodine-125-labeled DMIPP showed rapid, high myocardial uptake (min, mean % injected dose/g) in fasted rats (5, 4.67; 30, 5.06; 60, 4.79; 120, 4.37), and also exhibited high heart:blood ratios (min, ratio) 5, 3:1; 30, 12:1; 60, 12:1; 120, 13:1. These data demonstrate an unanticipated much longer myocardial residence time with DMIPP (+/sub 1/2/ 7-8 h) than observed with either the 3-monomethyl (BMIPP) analogue (+/sub 1/2/ 30-45 min) or the rapidly metabolized straight-chain (IPP) analogue (+/sub 1/2/ 10-15 min). The (/sup 123/I)DMIPP is thus an excellent candidate for clinical evaluation of regional fatty acid metabolism under conditions where the uptake of energy substrates can be assessed independent of regional blood delivery. Studies with the new activated carbon-based ...

International Nuclear Information System (INIS)

The nuclear activity was conducted for many years in Romania under Traditional Safeguards (TS) and has developed in good conditions the specific nuclear safeguards. Now there is a good opportunity to improve the performance and quality of the safeguards activity and at the same time to increase the accountancy and control of nuclear materials by passing to Integrated Safeguards (IS) implementation. The legal framework is the Law 100/2000 for ratification of the Protocol between Romania and International Atomic Energy Agency (IAEA), additional completion to the Agreement between the Socialist Republic of Romania Government and IAEA relating to safeguards. It is part of the Treaty on the non-proliferation of nuclear weapons published in the Official Gazette no. 3/31 January 1970, and the Additional Protocol published in the Official Gazette no. 295/ 29.06.2000. The first discussion about Integrated Safeguards (IS) between the Nuclear Fuel Plant (FCN) representatives ...

Science.gov (United States)

This quarterly report covers activities of the Two-Stage, Close- Coupled Catalytic Liquefaction of Coal program during the period January 1,--March 31,1992, at Hydrocarbon Research, Inc. in Lawrenceville and Princeton, New Jersey. This DOE contract period is from October 1, 1988 to September 30, 1992. The overall purpose of the program is to achieve higher yields of better quality transportation and turbine fuels and to lower the capital and production costs in order to make the products from direct coal liquefaction competitive with other fossil fuel products. The quarterly report covers work on Laboratory Testing, PDU Activities and Administration.

Science.gov (United States)

Products of a power plant flue gas desulfurization scrubber are discharged into a pond as sludge consisting of calcite (initial delta13C 3.2-3.8 per thousand), gypsum (initial delta34S 7.6-8.6 per thousand), and aqueous solution. Reducing conditions exist below a boundary that appears to move vertically as a function of changes in pond water level. Under reducing conditions, bacteria partially reduce aqueous sulfate to low-delta34S sulfide, consuming organic carbon and generating low-delta13C bicarbonate. Under oxidizing conditions, sulfide is converted to sulfate, leading to calcite dissolution, gypsum precipitation, and isotopic re-equilibration of remaining calcite with dissolved bicarbonate near the pond surface. The gypsum has delta34S near 6 per thousand, and calcite has delta13C as low as -1.7 per thousand; the changes from initial values correspond to predictions based on isotopic balance and ...

Energy Technology Data Exchange (ETDEWEB)

Field corrosion tests were conducted on eight single tube materials and two welded overlay materials in three typical Japanese waste incineration plants in an effort to develop new corrosion-resistant superheater tubes capable of functioning efficiently under temperature and pressure conditions of 500 C and 100 kgf/cm{sup 2}-g in high-efficiency waste-to-energy (WTE) plants. Austenitic alloys containing higher concentrations of chromium, nickel, and molybdenum [Cr + Ni + Mo] showed excellent corrosion-resistant properties, and the new alloys JHN24 and HR30M showed good corrosion resistance. Different corrosion rates found in each of the three plants were explained by differences in operating conditions, such as gas temperature, concentration of molten salts resulting from chlorine (Cl) content of deposits, heavy metal (zinc oxide [ZnO] + lead oxide [PbO]) content, etc. It was confirmed that the corrosion rate of materials ...

International Nuclear Information System (INIS)

Most of the petroleum fields in the Norwegian sector of the North Sea are sandstone reservoirs; the oil and gas are trapped in different species of sandstone. But the Ekofisk Field is a chalk reservoir, which really challenges the operator companies. When oil is produced from chalk reservoirs, water usually gets in and the reservoir subsides. The subsidence may be expensive for the oil companies or be used to advantage by increasing the recovery rate. Since 60 per cent of the world's petroleum reserves are located in carbonate reservoirs, it is important to understand what happens as oil and gas are pumped out. Comprehensive studies at the Department of Petroleum Technology and Applied Geophysics at Stavanger University College in Norway show that the mechanical properties of chalk are considerably altered when the pores in the rock become saturated with oil/gas or water under different stress ...

Energy Technology Data Exchange (ETDEWEB)

Trying to achieve the optimal utilization of oil shale resources, and the production of a more environmentally acceptable fuel, as well as a solid waste with a low a sulphur content, thereby reducing acidic leachates, has led to this investigation. In this article, the influences of the bed temperature and the choice of fluidizing gas on the quality and quantity of the produced fuel gas, using a continuous feed fluidized bed reactor, were investigated. The composition and calorific value of the generated gas were determined. There was a nearly linear increase in the amount of fuel gas produced as a function of temperature, reaching {approx}350 kg per 10{sup 3} kg of dry raw shale and the gross calorific value ranged from 15 to 23 MJ-kg{sup -1} with CO and H{sub 2} being the major constituents. Subsequent experiments were carried out, employing a thermogravimetric analyser under similar ...

Energy Technology Data Exchange (ETDEWEB)

Indoor and soil gas Radon ({sup 222}Rn) concentration measurements were accomplished in two stages in Sivas, a central eastern city in Turkey. In the first stage, CR-39 passive nuclear track detectors supplied by the Turkish Atomic Energy Authority (TAEA) were placed in the selected houses throughout Sivas centrum in two seasons; summer and winter. Before the setup of detectors, a detailed questionnaire form was distributed to the inhabitants of selected houses to investigate construction parameters and properties of the houses, and living conditions of inhabitants. Detectors were collected back two months later and analysed at TAEA laboratories to obtain indoor {sup 222}Rn gas concentration values. In the second stage, soil gas {sup 222}Rn measurements were performed using an alphameter near the selected houses for the indoor measurements. Although {sup 222}Rn concentrations in Sivas were quite low in ...

Science.gov (United States)

One of the energy-saving devices used on gas cooking appliances to eliminate the standing pilot is a spark ignition system. For safety, an ignition system must start promptly and be active whenever flowing gas is not ignited. To minimize noise and nuisance shock hazard, ignition must occur quickly and the sparking must be stopped as soon as ignition occurs and remain off as long as the flame is present. To accomplish both of these requirements, ignition systems have been devised which use the electrical current rectification property of a flame to sense it. These systems spark whenever the gas valve is on and a flame is not present. The factors affecting the performance of a spark ignition system are numerous, complex, and transient. All of these properties make quantification of performance difficult. A system is described which can evaluate the overall performance of ignition systems over significant periods of time and ...

International Nuclear Information System (INIS)

Various kinds of decontaminations are carried out in atomic power plant. Here current decontamination technologies such as chemical decontamination with chemical solution or blast decontamination have a problem of reduction of secondary radioactive waste generated in the decontamination process. On the other hand, a low pressure arc plasma can remove metal oxide film on the metal substrate without heavy damage on the metal substrate when the object to be treated was set as a cathode. Dry surface decontamination technology with using low-pressure arc plasma can decrease secondary radioactive waste because low-pressure arc plasma does not need any chemical solution. In addition, the time required for treatment can be shorter, so it is possible for the low-pressure arc plasma decontamination technology to interpolate the current decontamination technologies such as spot decontamination technology etc. Therefore we have been investigating the dependence of removal of metal oxide film on ...

Energy Technology Data Exchange (ETDEWEB)

Progress is reported on: radon barrier systems for uranium mill tailings; liner evaluation for uranium mill tailings; revegetation/rock cover for stabilization of inactive U-tailings sites; and application of long-term chemical biobarriers for uranium tailings.

Wastenet

UNEP will provide in the first CPR quarterly report of 2011 the financial statements for 2010. ...for assessing and rating programme performance UNEP to work with the CPR to identify better ways of streamlining reporting requirements ...in 2011 to achieve the ratios requested by the CPR dependent on receipt of contributions originally planned for the

Energy Technology Data Exchange (ETDEWEB)

Laser-assisted processing techniques for producing high-quality solar cell metallization patterns are being investigated, developed, and characterized. The tasks comprising these investigations are outlined.

Science.gov (United States)

DOE is supporting the development of several conversion processes that are currently in the pilot plant stage. Each of these processes is described briefly and information given as to contractor, contract, funding, site and current progress. Several support projects are treated similarly. (LTN)

Energy Technology Data Exchange (ETDEWEB)

This study investigated the effect of hydrogen content in producer gas on the performance and exhaust emissions of a supercharged producer gas-diesel dual-fuel engine. Two types of producer gases were used in this study, one with low hydrogen content (H{sub 2} = 13.7%) and the other with high hydrogen content (H{sub 2} = 20%). The engine was tested for use as a co-generation engine, so power output while maintaining a reasonable thermal efficiency was important. Experiments were carried out at a constant injection pressure and injection quantity for different fuel-air equivalence ratios and at various injection timings. The experimental strategy was to optimize the injection timing to maximize engine power at different fuel-air equivalence ratios without knocking and within the limit of the maximum cylinder pressure. Two-stage combustion was obtained; this is an indicator of maximum power output conditions and a precursor ...

Energy Technology Data Exchange (ETDEWEB)

Studies were conducted to quantitate the evolution of nitrogen oxides (NO/sub (x)/) from soybean (Glycine max (L.) Merr.) leaves during in vivo nitrate reductase (NR) assays with aerobic and anaerobic gas purging. Anaerobic gas purging (N/sub 2/ and argon) consistently resulted in greater NO/sub (x)/ evolution than did aerobic gas purging (air and O/sub 2/). The evolution of NO/sub (x)/ was dependent on gas flow rate and on NO/sub 2//sup -/ formation in the assay medium; although a threshold level of NO/sub 2//sup -/ appeared to exist beyond which the rate of NO/sub (x)/ evolution did not increase further. The loss of NO/sub (x)/ from in vivo NR assays under gas purging explains partially, but not stoichiometrically, the decrease of NO/sub 2//sup -/ accumulation in in vivo NR assay medium with young soybean leaves. The lack of stoichiometry between NO/sub (x)/ evolution and apparent ...

Energy Technology Data Exchange (ETDEWEB)

British Columbia is rich in resources of coal but is deficient in resources of liquid petroleum. The overall objective of the B.C. Research Coal Liquefaction Program is to provide sufficient technical data to identify and evaluate coal conversion opportunities in the province. In this first quarterly report, liquefaction test systems are discussed and results from the testing of equipment, procedures and analytical methods using coal samples from Sukunka (N.E. coal) and Hat Creek (central interior) are presented. The proposed program to be undertaken over the next four years is outlined.

International Nuclear Information System (INIS)

A thermodynamic analysis of the behaviour of Alloy 800 in helium based atmospheres relevant to the High Temperature Gas Cooled Reactor indicates that, depending upon the precise gas composition, oxidation and carburisation, or carburisation alone may be expected. The prime influence appears to be the moisture level. The morphology and structure of the reaction products are discussed. It is shown that the 'reactive' elements chromium, manganese, titanium and silicon are concentrated in the oxide scale which is normally duplex in structure. Aluminium oxide is formed at grain boundaries and in an internal oxidation zone together with titanium and sometimes silicon. In carburising conditions, mixed titanium-chromium carbides are formed. When this occurs, intergranular penetration is maximised. Weight gain data are assessed and briefly described and a tentative model for the mechanism of corrosion of Alloy 800 in HTR helium is ...

British Library Electronic Table of Contents (United Kingdom)

To test the hypothesis that leaf level photosynthetic related traits might confer late successionals a competitive advantage over early successionals in low light growth conditions, steady photosynthetic assimilation and dynamic photosynthetic induction related traits were examined in low light grown seedlings with contrasting successional status. Compared with the early successionals, late successionals as a group significantly exhibited lower leaf gas exchange rates. While late successionals required a longer time to respond to simulated sunflecks, they had lower rates of induction losses after sunflecks. Such photosynthetic induction traits allowed late successionals to more effectively utilize subsequent sunflecks. It was observed that plants with lower gas exchange rates responded mor...

International Nuclear Information System (INIS)

Chromium nitride thin films were deposited on SA-304 stainless steel substrates by using direct-current reactive magnetron sputtering. The influence of process conditions such as nitrogen content in the fed gas, substrate temperature, and different sputtering gases on microstructural characteristics of the films was investigated. The films showed (200) preferred orientation at low nitrogen content (< 30%) in the fed gas. The formation of Cr_2N and CrN phases was observed when 30% and 40% N_2 were used, with a balance of Ar, respectively. Field emission scanning electron microscopy and atomic force microscopy were used to characterize the morphology and surface topography of the thin films, respectively. Microhardness tests showed a maximum hardness of 16.95 GPa for the 30% nitrogen content.

International Nuclear Information System (INIS)

To evaluate safety of horizontal steam generator used in passive safety system, it is needed to make clear flooding characteristics in U bend pipe. In this study, two-phase flow experiment in a horizontal U bend pipe was carried out to make clear the influence of the length of horizontal pipe and the radius of U bend. Flooding in the U bend pipe was observed in the condition of lower gas or liquid volumetric flux than that in the horizontal pipe or the vertical pipe. Flooding and carry-up in the U bend pipe is hardly change with increasing the length between the water inlet and the U bend, but greatly related with the length from the water inlet to the lower tank and the shape of the U bend inlet. (author).

British Library Electronic Table of Contents (United Kingdom)

Abstract The characteristics of desulfurization and denitrification with composite absorbent were researched through aqueous absorption experiments. The removal efficiencies of SO2 and NO were up to 100 and 95%, respectively. The composite absorbent included NaClO2 and component M. Existence of component M in the solution could reduce the absorbent cost compared with using sodium chlorite alone. Chlorine dioxide, as main reaction intermediate product, participated in oxidation reaction. The optimal experimental conditions involved NaClO2 concentration of1.13 mmol/L, solution pH of 5.5, molar ratio (M/NaClO2) of 4.1, reaction temperature of 323 K. The optimal solution pH and reaction temperature were both in the required ranges of limestone-gypsum wet flue gas desulfurization (FGD) process....

Energy Technology Data Exchange (ETDEWEB)

Process engineers can predict quickly and accurately the equilibrium behavior of simultaneous H/sub 2/S and CO/sub 2/ absorptions in monoethanolamine and diethanolamine systems by using the nomographs developed by H.K. Ferguson Co. Correlation lines for temperature and amine concentration provided with the loading curves make the nomographs useful for any combination of temperature, concentration, and liquid loadings. The accuracy of the nomographs is within the acceptable range for normal engineering applications when the operating parameters lie in the region of practical gas-treating conditions. Correction curves given for each nomograph to improve the accuracy are generally not needed except for cases where the gas loadings are higher than 0.5 mole/mole of amine.

CERN Document Server

We study the ground state of an ideal coupled two-component gas of ultracold atoms in a one dimensional optical lattice, either bosons or fermions. Due to the internal two-level structure of the atoms, the Brillouin zone is twice as large as imposed by the periodicity of the lattice potential. This is reflected in the Bloch dispersion curves, where the energy bands regularly possess several local minima. As a consequence, when the system parameters are tuned across a resonance condition, a non-zero temperature topological first order phase transition occurs which arises from an interplay between initernal and kinetic atomic energies. It is shown that these phenomena are also captured for two and three dimensional optical lattices.

Energy Technology Data Exchange (ETDEWEB)

An experimental investigation has been carried out to examine for the first time the performance and combustion noise of an indirect injection diesel engine running with new fuel derived from pure jojoba oil, jojoba methyl ester, and its blends with gas oil. A Ricardo E6 compression swirl diesel engine was fully instrumented for the measurement of combustion pressure and its rise rate and other operating parameters. Test parameters included the percentage of jojoba methyl ester in the blend, engine speed, load, injection timing and engine compression ratio. Results showed that the new fuel derived from jojoba is generally comparable and a good replacement to gas oil in diesel engine at most engine operating conditions, in terms of performance parameters and combustion noise produced. (author)

International Nuclear Information System (INIS)

Austenitic stainless steel AISI 304 has been nitrided by radio frequency (rf) plasma containing various nitrogen-hydrogen gas mixtures, in order to study the effect of hydrogen on structure and magnetic properties of the formed compound layer. The thermal temperature has been measured at the vicinity of the samples. The compound layer thus produced has been characterized using, X-ray diffractometer and vibration sample magnetometer. Providing the total pressure of nitrogen and hydrogen is held constant, the addition of hydrogen up to 50% gives new structural phases. The magnetization values of the plasma treated samples are strongly dependent on the percentage of H_2 in the gas phase. An excessive amount of hydrogen (#approx#75%) on the other hand, retards the nitriding process. The surface temperature of the sample and plasma condition is crucial factors for nitriding process.

Energy Technology Data Exchange (ETDEWEB)

Polychlorinated dibenzo-p-dioxins and dibenzo-furans form a family of more than 200 compounds which are relatively stable in the biosphere and tend to accumulate in the human body. The tetra- to hexa-chlorinated dioxins and furans are considered highly toxic. To facilitate the assessment of the total toxicity of dioxin and furan mixtures, the estimated toxic effects of the individual compounds relative to the 2,3,7,8-tetrachloro-dibenzo-p-dioxin (TCDD) were introduced as Toxic Equivalent Factors which yield, when multiplied with the respective concentrations, the Toxic Equivalent (TE) of the mixture. Toxic dioxins and furans are unintentionally formed in a number of industrial combustion processes such as waste incineration and iron ore sintering, in the chemical industry and in household heating. To keep the emissions as low as possible, off-gas clearing systems for the collection of dioxins and furans are increasingly prescribed by the authorities. In addition, ...

Energy Technology Data Exchange (ETDEWEB)

The present article describes the specialities in various chemical process equipment fabricated by Hitachi. It introduces the thin-film evaporator which heats, vaporizes and concentrates high viscosity fluid and slurry under thin-film conditions, the centrifugal extractor which uses a high speed rotating rotor to separate two kinds of immiscible liquids effectively in counter current contact conditions under a gravitational force ranging from 2,000G to 4,500G, the process gas boiler and heat pipe equipment which recovers exhausted heat effectively from various plants, the furnace and quench systems which are applied to olefin plants, EDC cracking and steam reforming, and the equipment which has been supplied to chemical plants operated under severe conditions, such as high temperature, high pressure and corrosive atmosphere. It was demonstrated that these technologies and know-hows accumulated from ...

Energy Technology Data Exchange (ETDEWEB)

Over the past 40 years, cavern storage of LPG's, petrochemicals, such as ethylene and propylene, and other petroleum products has increased dramatically. In 1991, the Gas Processors Association (GPA) lists the total U.S. underground storage capacity for LPG's and related products of approximately 519 million barrels (82.5 million cubic meters) in 1,122 separate caverns. Of this total, 70 are hard rock caverns and the remaining 1,052 are caverns in salt deposits. However, along the eastern seaboard of the U.S. and the Pacific northwest, salt deposits are not available and therefore, storage in hard rocks is required. Limited demand and high cost has prevented the construction of hard rock caverns in this country for a number of years. The storage of natural gas in mined caverns may prove technically feasible if the geology of the targeted market area is suitable; and economically feasible if the cost and convenience of service ...

Energy Technology Data Exchange (ETDEWEB)

The integrity of a pipeline system is determined by its weakest links which may be the joints. Heat fusion is the most common method for joining gas distribution polyethylene (PE) piping. There are procedural, thermal, and mechanical aspects of making fusion joints. Acceptable procedural aspects, such as heater calibration and cleanliness, can be assured by rigorous training and certification of the operators. Thermal and mechanical aspects consist of specifying joining conditions such as the heater temperature, heating time, and joining pressure. In the absence of procedural errors, the strength of a fusion joint should depend on the pipe material, pipe dimensions, and the thermal and mechanical joining conditions. Socket heat fusion was studied both experimentally and analytically to determine how the strength of the joint varied with the conditions under which it was made. The standard tensile impact ...

Energy Technology Data Exchange (ETDEWEB)

Within the framework of efforts to optimize state-of-the-art waste disposal methods, this research project makes a theoretical analysis of the propagation behaviour of pollutants from landfills and waste incineration plants into the immediate vicinity of such plants. In order to judge the propagation of pollutants near the above-mentioned waste disposal facilities, a calculation program was developed within the framework of this research project which permits simulation of the propagation of such emissions in a three-dimensional space by application of an Eulerian grid model. It is capable of realistically representing fluid flow conditions and pollutant concentrations for certain points of times within the complex building patterns of such plants, for randomly chosen atmospheric conditions. (orig.)

International Nuclear Information System (INIS)

Exposure tests of candidate materials were carried out up to 1000 hr in the sulfuric acid environments of thermochemical hydrogen production IS process, focusing on the corrosion of welded portion and of crevice area. In the gas phase sulfuric acid decomposition condition at 850degC, welded samples of Alloy 800 and of Alloy 600 showed the same good corrosion resistance as the base materials. In the boiling condition of 95 wt% sulfuric acid solution, test sample of SiC showed the same good corrosion resistance. Also negligible corrosion was observed in crevice corrosion. (author)

International Nuclear Information System (INIS)

Very High Temperature gas cooled nuclear Reactor (VHTR), which was coupled with Sulfur-Iodine (SI) thermo-chemical cycle, has been selected for the Nuclear Hydrogen Development and Demonstration (NHDD) project in Korea Atomic Energy Research Institute. Among the various hydrogen production methods, Sulfur-Iodine (SI) thermo-chemical cycle is a good method as a massive hydrogen production without CO2 emission. In SI cycle, the sulfuric acid decomposition is one issue for the material corrosion on high temperature and pressure condition. For the simulation of the sulfuric acid decomposition, we designed a sulfuric acid loop with a small-scale gas loop which is simulated for the integrity and feasibility tests on a H2SO4 decomposition process. The primary objective of the loop is to validate the corrosion and the mechanical performances of a key component of the NHDD, Process Heat Exchanger (PHE). In this paper, we discussed ...

Science.gov (United States)

A number of agricultural and engineering uses for fixated flue gas desulfurization (FGD) material exist; however, the potential for leaching of hazardous elements has limited widespread application and the processes controlling the leaching of this material are poorly understood. In this study, a flow-through rotating-disk system was applied to elucidate the relative importance of bulk diffusion, pore diffusion, and surface chemical reaction in controlling the leaching of fixated FGD material under pH conditions ranging from 2.2 to 6.8. Changing the hydrodynamics in the rotating disk system did not affect the leaching kinetics at both pH 2.2 and 6.8, indicating that bulk diffusion was not the kinetic-limiting step. Application of the shrinking core model (SCM) to the data suggested a surface reaction-controlled mechanism, rather than a pore diffusion mechanism. The leaching of fixated FGD material increased with decreasing pH, suggesting it can ...

Energy Technology Data Exchange (ETDEWEB)

A laboratory differential simulation method is used for the design of carbonization columns at coal-tar processing in which phenols are regenerated from phenolate solution by carbon dioxide absorption. The design method is based on integration of local absorption rates of carbon dioxide along the column. The local absorption rates into industrial phenolate mixture are measured in a laboratory model contactor for various compositions of the gas and liquid phases under the conditions that ensure the absorption rates in the laboratory absorber simulate the local rates in the industrial column. On the bases of the calculations, two-step carbonization columns were designed for 30000 t/year of the phenolate solution treatment by carbon dioxide. The absorption proceeds at higher pressure of 500 kPa and temperatures from 50 to 65 C, pure carbon dioxide is used and toluene is added. These conditions have the following favourable ...

Energy Technology Data Exchange (ETDEWEB)

Two important greenhouse gases, CO{sub 2} and CH{sub 4}, are closely connected to the carbon cycling of wetlands. Although virgin wetlands are mostly carbon accumulating ecosystems, major proportion of the CO{sub 2} bound annually in photosynthesis is released back to the atmosphere. Main portion of the carbon cycling in wetlands is quite fast while a small proportion of carbon diffusing from soil is released from organic matter, which may be ten thousand years old. Methane is formed in the anaerobic layers of wetlands, from where it is released gradually to the atmosphere. The decomposition in anaerobic conditions is very slow, which means that usually only a few percent of the annual carbon cycling takes place as methane. Research on CO{sub 2} fluxes of different virgin and managed peatlands was the main topic of this project during the first phase of SILMU. The measurements were made during two seasons in varying conditions in c. 30 study ...

International Nuclear Information System (INIS)

Traditional two-phase flow-regime criteria based on the gas and liquid superficial velocities may not be suitable to the analyses of rapid transient or entrance flows by the two-fluid model. Under these conditions, it is postulated that direct geometrical parameters such as the void fraction are conceptually simpler and therefore more reliable parameters to be used in flow-regime criteria than the traditional parameters. From this point of view, new flow-regime criteria for upward gas-liquid flow in vertical tubes have been developed considering the mechanisms of flow-regime transitions. These new criteria can be compared to existing criteria and experimental data under steady-state and fully developed flow conditions by using relative velocity correlations. The criteria showed reasonable agreements with the existing data for atmospheric air-water flows. Further comparisons with data for steam-water in ...

Energy Technology Data Exchange (ETDEWEB)

Oregon State University (OSU) and the Pacific Northwest National Laboratory (PNNL) were funded by the U.S. Department of Energy to conduct research focused on resolving the key technical issues that limited the deployment of efficient and extremely compact microtechnology based heat actuated absorption heat pumps and gas absorbers. Success in demonstrating these technologies will reduce the main barriers to the deployment of a technology that can significantly reduce energy consumption in the building, automotive and industrial sectors while providing a technology that can improve our ability to sequester CO{sub 2}. The proposed research cost $939,477. $539,477 of the proposed amount funded research conducted at OSU while the balance ($400,000) was used at PNNL. The project lasted 42 months and started in April 2001. Recent developments at the Pacific Northwest National Laboratory and Oregon State University suggest that the performance of absorption and desorption ...

International Nuclear Information System (INIS)

Mercury has had various uses in nuclear fuel reprocessing and other nuclear processes, and so is often present in radioactive and mixed (both radioactive and hazardous according to the Resource Conservation and Recovery Act) wastes. Depending on regulatory requirements, the mercury in the off-gas must be controlled with sometimes very high efficiencies. Compliance to the Hazardous Waste Combustor (HWC) Maximum Achievable Control Technology (MACT) standards can require off-gas mercury removal efficiencies up to 99.999% for thermally treating some mixed waste streams. Several test programs have demonstrated this level of off-gas mercury control using fixed beds of granular sulfur-impregnated activated carbon. Other results of these tests include: (a) The depth of the mercury control mass transfer zone was less than 15-30 cm for the operating conditions of these tests, (b) MERSORB(reg_sign) carbon can sorb ...

Energy Technology Data Exchange (ETDEWEB)

In a breeder-type nuclear power plant, liquid metal is used as a coolant due to the high heat capacity factor. Also, some proposals for fusion reactor blanket design include liquid metal as a possible coolant. In both cases the understanding of natural circulation of liquid-metal flow behavior is an integral part of the thermal hydraulic analysis, especially under two-phase flow conditions. Experimental investigations have been conducted to study a liquid metal two-phase natural circulation flow system. A lead-bismuth (PbBi) eutectic mixture is used as a working fluid in a heated metal walled natural circulation loop. Gas injection induces natural circulation through the gas-lift mechanism. A real-time neutron radiography system is used to visualize the two-phase mixture, specifically the interface and the flow regime. Measurements of void fraction, void fluctuation and bubble propagation are performed.

Energy Technology Data Exchange (ETDEWEB)

A new type of passive cooling system has been invented (Forsberg 1993): the Temperature-Initiated Passive Cooling System (TIPACS). The characteristics of the TIPACS potentially match requirements for an improved reactor-cavity-cooling system (RCCS) for the modular high-temperature gas-cooled reactor (MHTGR). This report is an initial evaluation of the TIPACS for the MHTGR with a Rankines (steam) power conversion cycle. Limited evaluations were made of applying the TIPACS to MHTGRs with reactor pressure vessel temperatures up to 450 C. These temperatures may occur in designs of Brayton cycle (gas turbine) and process heat MHTGRs. The report is structured as follows. Section 2 describes the containment cooling issues associated with the MHTGR and the requirements for such a cooling system. Section 3 describes TIPACS in nonmathematical terms. Section 4 describes TIPACS`s heat-removal capabilities. Section 5 analyzes the operation of the ...

Energy Technology Data Exchange (ETDEWEB)

This paper describes potentials on fuel economy and NO{sub x} exhaust emissions of a series hybrid urban bus system equipped with a ceramic gas turbine engine (CGT). The simulating program developed in-house was used to analyze influences of several parameters of each main components of the hybrid vehicle system on the performance of the bus running on the modified bus driving cycle. The basic data used in this analysis for a CGT was derived from the results of 'the Automotive 100kW CGT Project' of Japan. A dynamic response of a CGT-Generator rotating system was very much improved by introducing of 'Assisting system' in which the generator was used as an acceleration-deceleration assisting device when much acceleration or deceleration was needed. This system would make a CGT operate along the optimum operating line (fuel minimum line) even under the unsteady driving conditions. This analysis showed that the ...

Energy Technology Data Exchange (ETDEWEB)

The aim was to investigate conditions relating to the substitution of natural gas for part of the amount of cinders previously used as fuel in an existing cupola furnace used in an iron foundry. The process of retrofitting is described. The principle solution is that four gas burners are placed symmetrically around the furnace immediately above the melting zone. They are mounted in separate fire boxes in such a way that they point downwards in order to prevent the fire box being filled with materials from the furnace, which would cause damage to the burners. The burners are continuously controlled to produce an output of 720 - 2620 kW and with 0.5 - 1.5 excess air. This solution was successful although it was found necessary (in order to achieve a satisfactory quality of resulting molten material) to add extra cinders to the furnace resulting in a reduction of only 9% of total cinders used, instead of the hoped-for 15%. The ...

Energy Technology Data Exchange (ETDEWEB)

Laboratory experiments were conducted to simulate the transfer of acidic THOREX waste from Tank 8D-4 into the alkaline PUREX waste in Tank 8D-2 at West Valley. The purpose of the experiments was to explore means of minimizing the production of nitric oxide (NO) gas during mixing of the two wastes and to assess the potential for the gas to further react in the vapor space possibly leading to enhanced corrosion of the tank walls. Forty one THOREX/PUREX mixing tests were conducted to explore the effects of stirring rate, pH, THOREX addition rate, THOREX or PUREX dilution, and temperature. The two most important criteria for minimizing NO production were to maintain some degree of agitation and the keep the pH in the PUREX high, preferably >12. Steel corrosion tests were performed in the presence of low partial pressures of NO{sub 2} and liquid water or water vapor. The NO{sub 2} (from oxidation of NO in the vapor space) concentrations were ...

Energy Technology Data Exchange (ETDEWEB)

This report describes the design of a well test to determine two-phase hydraulic properties of a low permeability, low porosity formation. Estimation of gas-related parameters in such formations is difficult using standard pumping tests mainly because of the strong fluctuations in the pressure and flow rate data which are a consequence of gas bubbles evolving in the test interval. Even more important is the fact that the data do not allow distinguishing among alternative conceptual models. The estimated parameters are therefore uncertain, highly correlated, and ambiguous. In this study we examine a test sequence that could be appended to a standard hydraulic testing program. It is shown that performing a series of water and gas injection tests significantly reduces parameter correlations, thus decreasing the estimation error. Moreover, the extended test sequence makes possible the identification of the model that describes ...

Energy Technology Data Exchange (ETDEWEB)

Due to the general market conditions, the construction of steam turbines was greatly reduced in 1987. As in 1986, it came to a downward movement. This situation will heighten in the coming years. The exploitation of devices, which are available by way of the development of EDP in computation, construction, production and operation, leads to considerable improvements. These improvements can only be employed gradually, due to the reduction in production. However, technological progress can be used economically in part in the restoration of old installations. Here turbine construction, the thermodynamical interpretation of gas and steam turbines, developments in the field of conduction technology, piping and materials are described. Also improvements in operation security and operation supervision of the installations is treated, as well as service and maintenance of the plants. (BR) With 131 refs.

Energy Technology Data Exchange (ETDEWEB)

Knock limitations are investigated using natural gas, with diesel pilot ignition, as a fuel for the 3406 DI-TA Caterpillar diesel engine. Thermodynamic properties at TDC are generated by computer and compared with experimental results. Exhaust emissions are analyzed. A comparison is made of dual-fuel operation relative to diesel. Observations are made to determine the onset of knock. The onset of knock is characterized as a function of engine speed, load, inlet manifold temperature, and air-fuel ratio (A/F). The conditions at the inset of knock are determined using cylinder pressure data. The most efficient operating range is determined with knock avoidance as a prime parameter.

Energy Technology Data Exchange (ETDEWEB)

The authors investigated phase equilibria in the system carbon dioxide-hexametapol. Vacuum-distilled solvent of ''pure'' grade was used. The solubility of CO/sub 2/ in hexametapol under pressures at various temperatures and the temperature dependence of the Henry's law coefficient is show. It is concluded that the solubility of carbon dioxide in hexametapol in the temperature and pressure ranges corresponding to the operating conditions of industrial equipment for removing CO/sub 2/ from gases conforms to the Krichevskii-II'inskaya equation. The experimental data can be used for equipment design.

Energy Technology Data Exchange (ETDEWEB)

A 20-cell PEFC stack was designed and built. Resin impregnated graphite was used as bipolar plate material. The air cooling of the stack was optimized by introducing high surface structures into the open space of the cooling plates. At {eta} (H{sub 2} LHV) = 0.5 a power of 880 W was obtained under conditions of low gas-pressures of 1.15 bar{sub a}. The auxiliary power for process air supply and cooling at 880 W power is less than 7% of the power output, indicating that the described system may be operated at a high efficiency. (author) 5 figs., 2 refs.

International Nuclear Information System (INIS)

Retention kinetics and tissue partition coefficients for "8"5Kr were determined in rats exposed to known concentrations of "8"5Kr gas. The tissue partition coefficients were used to calculate the relative tissue radiation dose, assuming exposure conditions equivalent to the maximum permissible concentration in air (MPC)a. The estimated radiation dose was highest in adrenals and body fat, about twice the dose estimated for the next highest tissue, ovaries. Saturation and desaturation curves show that the contents of the large intestines have a prolonged desaturation time compared to other samples analyzed.

Science.gov (United States)

According to the LeChatelier-Braun principle, when a closed quiescent system initially in an equilibrium or unstressed steady state is subjected to an externally imposed ``stress'' it responds in a manner tending to alleviate that stress. Use of this entropically based qualitative rule, in combination with the notion of Maxwell thermal stresses existing in nonisothermal gases and liquids, enables one to (i) derive Maxwell's thermal-creep boundary condition prevailing at the boundary between a solid and a fluid (either gas or liquid) and (ii) rationalize the phenomenon of thermophoresis in liquids, for which, in contrast with the case of gases, an elementary explanation is currently lacking. These two objectives are achieved by quantitatively interpreting the heretofore qualitative LeChatelier-Braun notion of stress in the present context as being the fluid's stress tensor, the latter including Maxwell's thermal stress. In effect, thermophoretic ...

International Nuclear Information System (INIS)

Lappeenranta University of Technology (LTKK) and VTT Energy carried out a series of preliminary tests in 1999 to study the behavior of noncondensable (NC) gases in VVER geometry. The tests aimed at studying the effect of NC gases on system thermal-hydraulics and on heat transfer in a horizontal steam generator (HSG). The system behavior can be affected by hydrogen produced in the core in case of a severe accident, by nitrogen from hydro-accumulators released into the primary circuit in case of a loss-of-coolant accident (LOCA) and more generally by any NC gas in all cases where cooling is ensured by natural circulation. A secondary objective of the tests - the first series of tests ever performed with NC gas with PACTEL - was to find out, if the instrumentation of PACTEL was adequate for this type of tests and if it was functioning properly. This paper presents the measured and calculated (CATHARE code version V15a mod 2.1) results of the test ...

Energy Technology Data Exchange (ETDEWEB)

Oestfold Research has trough the project 'Climate accounts for disposal' for Waste Norway developed a model for calculation of net greenhouse gas emissions at the disposal of various waste types. The model is based on life cycle methodology according to the standard IS014044. This model has been used for plastic packaging in the project by adapting the basic values of specific conditions in the municipality of Fredrikstad. Oestfold Research has made an assessment of greenhouse gas emissions for the recycling and material recovery of plastic packaging from households in the district on assignment from Fredrikstad municipality and compared with the current solution where plastic packaging together with residual waste is used for energy utilisation. Based on the population in Fredrikstad and estimated amount of plastic packaging waste arising per household per year the difference in climate impact was ...

International Nuclear Information System (INIS)

The trifluoroacetate metal-organic decomposition route to YBa_2Cu_3O_7 film growth was investigated in order to bring new insights in the growth mechanism and its dependence on processing conditions and critical current density. Precursor films were processed on LaAlO_3 substrates at different total pressure, oxygen partial pressure, water vapor partial pressure, and volume gas flow rate keeping the growth temperature at 740 "0C. The influence of these various experimental parameters on the film growth rate, which was evaluated by in situ electrical resistance measurements, was studied thoroughly. It was found that the growth rate is nearly independent of the oxygen pressure and proportional to the square root of the water pressure. Additionally, the growth rate increases with a decrease of the total pressure or an increase of the gas flow rate. An empirical multi-exponential model simulates the experimental data, however, ...

International Nuclear Information System (INIS)

Treatment chemicals are used in all facets of the natural gas industry (NGI) from well development through transmission and storage of natural gas. The multitude of chemicals used, combined with the dozens of chemical manufacturers and/or suppliers has lead to the availability of hundreds of possible chemical products. Because of the widespread use of chemical products and their numerous sources, the NGI needs access to consistent data regarding their effectiveness and potential environmental impacts. The objective of this work was to evaluate the effectiveness and potential environmental impacts of, chemical products used in the NGI. This assessment was initially focused on biocides and corrosion inhibitors and their use in the gas production, storage and transmission facilities, The overall approach was obtain the necessary data on chemical use and effectiveness directly from the oil and gas industry, ...

International Nuclear Information System (INIS)

A cross-flow atmospheric plasma jet with distilled water or analyte solution nebulization has been investigated. The plasma gas flows perpendicularly to the RF powered electrode (11.21 MHz) and a grounded electrode was added for plasma stabilization. The working parameters of the plasma generator can be controlled in order to maximize either the plasma power (75 W) or the voltage on the RF powered electrode (plasma power, 40 W). The plasma gas, pure argon (0.4 l min-1) or a mixture of argon (0.3-0.4 l min-1) and helium (0-0.2 l min-1), was also used for liquid nebulization. Optical emission of the plasma, collected in the normal viewing mode, was used for plasma diagnostics and for evaluating its excitation capabilities. The influence of helium content in the mixed-gas plasma on the plasma characteristics and on the emission axial profiles of the plasma gas constituents and of the analytes originate ...

Energy Technology Data Exchange (ETDEWEB)

Soil contamination by liquid organic pollutants represents a serious threat to phreatic ground water. These organic liquids get into the ground and migrate through the porous medium until they finally reach the aquifer. After a critical study of the literature, we listed various existing multiple displacements under three-phase conditions of a disconnected polluting phase that may or not spread over water. The aim of this thesis is to model (at pore scale level) and integrate in the pore network model the various flows that occur when three phases (gas, pollutant and air) are present in a porous medium. The porous medium is supposed completely water-wet. The polluting phase may be connected or not, and the spreading coefficient of the pollutant over water may either be positive or negative. The goal of our study is to obtain macroscopic parameters such as relative permeabilities and capillary pressure. These parameters can be then incorporated ...

Energy Technology Data Exchange (ETDEWEB)

The invention relates to a method for purifying a gas mixture containing at least one undesirable gas compound utilizing certain sulfonamide or sulfamide solvents.

International Nuclear Information System (INIS)

The aim of the project is to study the conditions and processes occurring in permanently frozen crystalline bedrock, with special reference to deep (i.e., several hundreds of meters) bedrock conditions. The target of the study is the Lupin mine in Nunavut Territory, Northern Canada. The results may be utilized in assessing the long-term performance of deep underground constructions (e.g., nuclear waste repositories) in cooling climatic conditions. In Phase I of the project versatile background information was collected from the site e.g., on climate, geology and on hydrogeological and hydrogeochemical conditions. During Phase II a broad range of research was conducted including (i) electromagnetic soundings to investigate the distribution of permafrost in the surroundings of the mine; (ii) drilling of three research boreholes at the base of the permafrost for groundwater research; (iii) application of ...

Energy Technology Data Exchange (ETDEWEB)

During second quarter 1992, tritium, trichloroethylene, tetrachloroethylene, chloroethene, antimony, 1,1-dichloroethylene, lead, nonvolatile beta, radium-228, thorium-228, or total alpha-emitting radium (radium-226 and radium-228) exceeded the US Environmental Protection Agency Primary Drinking Water Standards (PDWS) in groundwater samples from monitoring wells at the Mixed Waste Management Facility (MWMF) and adjacent facilities. Tritium and trichloroethylene were the most widespread constituents; 55 (48%) of the 115 monitored wells contained elevated tritium activities, and 23 (20%) wells exhibited elevated trichloroethylene concentrations. Sixty-three downgradient wells screened in Aquifer Zone IIB2 (Water Table), Aquifer Zone IIB[sub 2] (Barnwell/McBean), and Aquifer Unit IIA (Congaree) contained concentrations of tritium, trichloroethylene, tetrachloroethylene, chloroethene, antimony, 1,1-dichloroethylene, lead, nonvolatile beta, radium-228, thorium-228, or ...

Energy Technology Data Exchange (ETDEWEB)

A phase 2 study was initiated to investigate surfactant-assisted coal liquefaction, with the objective of quantifying the enhancement in liquid yields and product quality. This publication covers the first quarter of work. The major accomplishments were: the refurbishment of the high-pressure, high-temperature reactor autoclave, the completion of four coal liquefaction runs with Pittsburgh No. 8 coal, two each with and without sodium lignosulfonate surfactant, and the development of an analysis scheme for the product liquid filtrate and filter cake. Initial results at low reactor temperatures show that the addition of the surfactant produces an improvement in conversion yields and an increase in lighter boiling point fractions for the filtrate.

Energy Technology Data Exchange (ETDEWEB)

The OSP (Operating Safety Procedure) required for performance of electrical arc testing of CFC replacement fluids was renewed. Electrical breakdown tests at one atmosphere pressure have been performed for R-22, R-134a, and R-125/R-143a (50:50 blend; R-507), and breakdown products identified. No differences in HCFC breakdown products are seen in the presence or absence of lubricant oils. The design of the high pressure-high temperature test stand has been finalized, and construction initiated during this quarter. Three motor stators and rotors were received from Tecumseh Products Company for use in motor burnout tests. A test plan for the motor breakdown tests is in preparation.

CERN Document Server

Two constructions due to Dr\\'apal produce a group by modifying exactly one quarter of the Cayley table of another group. We present these constructions in a compact way, and generalize them to Moufang loops, using loop extensions. Both constructions preserve associators, the associator subloop, and the nucleus. We conjecture that two Moufang 2-loops of finite order $n$ with equivalent associator can be connected by a series of constructions similar to ours, and offer empirical evidence that this is so for $n=16$, 24, 32; the only interesting cases with $n\\le 32$. We further investigate the way the constructions affect code loops and loops of type $M(G, 2)$. The paper closes with several conjectures and research questions concerning the distance of Moufang loops, classification of small Moufang loops, and generalizations of the two constructions.

Energy Technology Data Exchange (ETDEWEB)

This report is to present the progress made on the project ''Establishment of an Environmental Control Technology Laboratory (ECTL) with a Circulating Fluidized-Bed Combustion (CFBC) System'' during the period July 1, 2004 through September 30, 2004. The following tasks have been completed. First, renovation of the new Combustion Laboratory and the construction of the Circulating Fluidized-Bed (CFB) Combustor Building have started. Second, the design if the component parts of the CFBC system have been reviewed and finalized so that the drawings may be released to the manufacturers during the next quarter. Third, the experiments for solid waste (chicken litter) incineration have been conducted using a Thermogravimetric Analyzer (TGA). This is in preparation for testing in the simulated fluidized-bed combustor. The experimental results from this study are presented in this report. Finally, the proposed work for the next ...