WorldWideScience
1

Modeling Blast and High-Velocity Impact of Composite Sandwich Panels  

Science.gov (United States)

Analytical models for predicting the deformation and failure of composite sandwich panels subjected to blast and projectile impact loading are presented in this paper. The analytical predictions of the transient deformations and damage initiation in the composite sandwich panels were compared with finite element solutions using ABAQUS Explicit. For the blast model, the predicted transient deformation of the sandwich panel was within 7%of FEA results, while the predicted damage initiation using Hashin's composite failure criteria was about 15%higher than FEA results in most cases. For the high velocity impact model, the predicted transient deformations were within 20%of FEA results.

2009-01-01

2

Computation and analysis of single well responses for gas condensate systems  

Energy Technology Data Exchange (ETDEWEB)

A fully implicit compositional simulator was written to predict the drawdown and buildup responses for a single well in a gas condensate reservoir. The model uses the Redlich-Kwong equation of state to compute fluid properties and to determine phase equilibrium. The accuracy of the model predictions in the two-phase flow regime is tested using the results of a steady-state theory developed here. Two new correlating functions for transient flow - the reservoir integral and the sandface integral - are presented. The reservoir integral is shown to be a good liquid analogue during transient flow (drawdown). The sandface integral correlates with the liquid solution only in the slope. These two theoretical functions are shown to reduce to a computable pseudopressure function by using the results of the steady-state theory. The usefulness of this pseudopressure function for computing the permeability-thickness ...

1985-01-01

3

Transient behaviour of solar heated radiation receivers for small gas turbine power plants  

Energy Technology Data Exchange (ETDEWEB)

Solar heating of gas turbine plants steps back more and more into the focus of current research. The mainly instationary operation of solar turbine power plants can only be predicted with sufficient accuracy if the transient behaviour of the receiver for the solar radiation is known. Therefore the transient behaviour of cavity receivers of different design is investigated. The mathematical model used for the simulation of the heat transfer and energy storage processes is illustrated. Computed results for receivers with various inner lining are compared and evaluated concerning their use in practice.

1987-03-01

4

Transient behavior of solar heated radiation receivers for small gas turbine power plants  

Energy Technology Data Exchange (ETDEWEB)

Solar heating of gas turbine plants is moving back to the focus of current research. The mainly unsteady operation of solar turbine power plants can only be predicted with sufficient accuracy if the transient behavior of the solar radiation receiver is known. Therefore the transient behavior of cavity receivers of different designs is investigated. The mathematical model used to simulate heat transfer and energy storage is illustrated. Computed results for two receivers with different inner lining are compared and evaluated concerning their use in practice.

1987-01-01

5

Depth of origin of the gas content in thermal waters  

Energy Technology Data Exchange (ETDEWEB)

The gas composition of recent thermal waters is in perfect conformity with their geologic-tectonic positions. The composition of gas-liquid inclusions in the basic-hyperbasic xenoliths of basaltoid lavas depends on the depth from which xenoliths are supplied. (The depth is determined by using the methods of geological thermobarometers). By comparing available data the conclusion was drawn that the gas compositions of thermal waters reflect the depth of generation of deep fluid which heats them and depends on the penetration depth of the fluid-conducting fissure zones.

1980-01-01

6

Modeling Transient Discharge into a Tunnel Drilled in a Heterogeneous Formation  

British Library Electronic Table of Contents (United Kingdom)

Abstract An analytical model is developed to predict transient discharge flow into a tunnel drilled at various speeds through a heterogeneous formation. This model relies on simplifying assumptions commonly enforced in hydrogeologic engineering, and combines the convolution and superposition principles to account for composite sections with arbitrary parametric contrasts. An application to the data monitored during the exploratory drilling of an Alpine tunnel confirms the validity of the approach.

2007-01-01

7

Seal Monitoring System for an Explosive Containment Vessel  

Energy Technology Data Exchange (ETDEWEB)

Researchers at Lawrence Livermore National Laboratory are developing high-performance explosive firing vessels to contain (one time) explosive detonations that contain toxic metals and hazardous gases. The filament-wound polymer composite vessels are designed to contain up to 80 lb (TNT equivalent) explosive in a 2-meter sphere without leakage. So far, two half-scale (1-meter diameter) vessels have been tested; one up to 150% of the design explosive limit. Peak dynamic pressures in excess of 280 MPa (40 Ksi) in the vessel were calculated and measured. Results indicated that there was a small amount of gas and particle leakage past the first two of the seven o-ring seals. However, the remaining five seals prevented any transient leakage of the toxic gases and particulates out of the vessel. These results were later confirmed by visual inspection and particulate analysis of swipes taken from the sealing surfaces.

2004-06-28

8

Mountain scale modeling of transient, coupled gas flow, heat transfer and carbon-14 migration  

International Nuclear Information System (INIS)

We simulate mountain-scale coupled heat transfer and gas flow at Yucca Mountain. A coupled rock-gas flow and heat transfer model, TGIF2, is used to simulate mountain-scale two-dimensional transient heat transfer and gas flow. The model is first verified against an analytical solution for the problem of an infinite horizontal layer of fluid heated from below. Our numerical results match very well with the analytical solution. Then, we obtain transient temperature and gas flow distributions inside the mountain. These distributions are used by a transient semianalytical particle tracker to obtain carbon-14 travel times for particles starting at different locations within the repository. Assuming that the repository is filled with 30-year-old waste at an initial areal power density of 57 kw/acre, we find that repository temperatures remain above ...

1993-09-26

9

Steady-state isotopic transient kinetic analysis investigation of CO-O_2 and CO-NO reactions over a commercial automotive catalyst  

International Nuclear Information System (INIS)

In this paper, steady-state isotopic transient kinetic analysis (SSITKA) is used to study two model reactions, CO oxidation and CO-NO reactions, on a typical formulation of a three-way auto-catalyst. Under steady-state conditions, abrupt switches in the isotopic composition of CO ("1"2C"1"6O/"1"3C"1"8O) were carried out to produce isotopic transients in both labeled reactants and products. Along with the determination of the average surface lifetimes and concentrations of reaction intermediates, an analysis of the transient responses along the carbon reaction pathway indicated that the distribution of active sites for the formation of CO_2 was bimodal for both reactions. Furthermore, relatively few surface sites contributed to the overall reaction rate.

1991-08-25

10

Mathematic modeling of the coke gas combustion process  

Energy Technology Data Exchange (ETDEWEB)

Analysis of the coke gas combustion porcess is presented. Standard kinetic relationships were utilized. Calculations were performed for coke gas with high and low content of H/sub 2/ and for blasting air 20 and 100/sup 0/C. Temperature relationships, composition of gas combustion products and release of nitrogen oxides were determined. Results are analyzed which will make it possible to control the composition of combustion products.

1983-01-01

11

Geochemical study on origin of natural gases in Japanese oil and gas fields  

Energy Technology Data Exchange (ETDEWEB)

The origin of natural gas in the Japanese oil and gas fields are geochemically studied. Samples are taken from structural natural gas, surface gas seepage, water-dissolved natural gas and coal-field gas of the Japan Sea coast area. The origins of primary hydrocarbons are classified into bacteria gas and thermogenic gas, the latter being subclassified into gas in oil production zone with the per million deviation of the carbon isotope (/sup 13/C/sup 1/) of methane less than -35 and those gases with maturity higher than this. Surface gas seepage is subjected to migration and bacterial oxidation. Coal gas is similar to oil gas. The CO/sub 2/ concentration is 0 - 2% and /sup 13/CO/sub 2/ deviations from -30 - +30. The origin can be barely ...

1988-05-01

12

Dense and diffuse gas in dynamically active clouds  

CERN Document Server

We investigate the chemical and observational implications of repetitive transient dense core formation in molecular clouds. We allow a transient density fluctuation to form and disperse over a period of 1 Myr, tracing its chemical evolution. We then allow the same gas immediately to undergo further such formation and dispersion cycles. The chemistry of the dense gas in subsequent cycles is similar to that of the first, and a limit cycle is reached quickly (2 - 3 cycles). Enhancement of hydrocarbon abundances during a specific period of evolution is the strongest indicator of previous dynamical history. The molecular content of the diffuse background gas in the molecular cloud is expected to be strongly enhanced by the core formation and dispersion process. Such enhancement may remain for as long as 0.5 Myr. The frequency of repetitive core formation should strongly determine the ...

2006-01-01

13

NGNP Composites R&D Technical Issues Study  

Energy Technology Data Exchange (ETDEWEB)

This study identifies potential applications and design requirements for ceramic materials (CMs) and ceramic composite materials (CCMs) in the NGNP hightemperature gas-cooled reactor (HTGR) primary circuit. Components anticipated for fabrication from non-graphite CMs and CCMs are identified along with recommended normal and off-normal operating conditions. The evaluation defines required dimensions and material properties of the candidate materials for normal operating conditions (NOC), anticipated transients, abnormal events, and design basis events. The report also identifies additional activities required for codifying the selected materials. The activities include ASTM Standard and ASME Code development and other work to support NRC licensing of the plant. Evaluation of the NGNP baseline design indicates components requiring either CMs or CCMs depend upon the reactor operating temperatures. For a reactor outlet ...

2008-09-01

14

Powder composites for gas-plasma ceramic coatings  

Energy Technology Data Exchange (ETDEWEB)

The method of production of xAl{sub 2}O{sub 3}-yTiO{sub 2} compositions provides for the depth distribution of coating components and specifies its mechanical properties. In case of the composition obtained by cladding, titanium is mainly concentrated at the substrate. In case of mechanical mixture or composition obtained by sintering the oxides, the depth distribution of coating components is random.

1995-12-31

15

TS-1 and TS-2 transient overpower tests on FFTF fuel  

International Nuclear Information System (INIS)

The TS-1 and TS-2 TREAT transient experiments subjected a low burnup (2 MWd/kg) and a medium burnup (58 MWd/kg), respectively, FFTF irradiated fuel pin to unprotected 5 cents/s overpower transient conditions. The fuel pin failure response was similar in the two tests, which demonstrated a large margin to failure (P/P_0 > 3) and a favorable upper level failure location. Thus, for these transient conditions, burnup effects on transient performance appeared to be minimal in the range tested. Pin disruption in the medium burnup TS-2 test was more severe due to the higher fission gas pressurization, but failure occurred at only a 5% lower power level than for the low burnup TS-1 fuel pin. Both tests exhibited axial extrusion of molten fuel to the region above the fuel column several seconds before pin failure, demonstrating a potentially beneficial inherent safety mechanism to delay ...

1985-11-10

16

Engine use of producer gas, experiences and requirements  

Energy Technology Data Exchange (ETDEWEB)

The most effective way to generate electricity out of biomass is the gasification and the use of the gas in a gas engine. The conversion of the organic carbon with the gasification of biomass is higher than 95 %. Depending on the gasification concept, the efficiency of gasifiers is found between 70 and 90 %. If the pyrolysis gas is used in a gas engine, an electric efficiency of about 26 % referring to the primary amount of energy can be obtained. With efficient gas cleaning (cleaning for tar and dust), pyrolysis gas is well qualified for engine combustion. Through modern state of engine controlling there are ways to have complete control of the fluctuations in the gas composition. Furthermore, the minor calorific value of offered wood gas poses no problem for turbo charged lean-burn ...

1999-07-01

17

Limestone Dissolution in Flue Gas Desulfurization Processes.  

Science.gov (United States)

The report gives results of the measurement of dissolution rates of reagent CaCO3 and commercial limestones (9 types/19 grinds) at constant pH and solution composition by batch titration with HC1. Conditions were selected to simulate flue gas desulfurizat...

1983-01-01

18

Study on low calorific gas combustion. Part 1  

Energy Technology Data Exchange (ETDEWEB)

Effects of combustion conditions on the critical calorific value of flame blowout were reported for low calorific gas on the assumption of using coal derived gaseous fuel. Further, calculations of adiabatic flame temperature by using chemical equilibrium calculation were conducted in order to get a possibility of increasing exit gas temperature of gas turbine combustor to 1,300 C for low calorific value gas fuel. As a result, effects of (1) fuel composition, (2) preheating fuel temperature, (3) calorific value, and (4) combustion air velocity and fuel nozzle diameter, on the critical calorific values of flame blowout were clarified. In increasing exit gas temperature of gas turbine combustor to 1,300 C when using low calorific value gas fuel, it is essential to get an advanced cooling technology for the ...

1986-01-01

19

Method of removing entrained particles from flue gas and composition of matter  

Energy Technology Data Exchange (ETDEWEB)

A composition of matter to treat particles entrained in flue gas, is described comprising: a caustic liquid used to adjust resistivity of the entrained particles; and inert particulate matter supporting the caustic liquid for inhibiting chemical action of the caustic liquid until used to adjust the resistivity of the entrained particles, the inert particulate matter supporting sufficient caustic liquid to adjust the resistivity of the entrained particles.

1988-04-19

20

The origin of natural gas and the hydrocarbon charging history of the Yulin gas field in the Ordos Basin, China  

Energy Technology Data Exchange (ETDEWEB)

The genetic type, source and charging history of natural gas in the Yulin gas field in the Ordos Basin have been studied by combining the carbon isotopic composition of natural gas and geochemical characteristics of light hydrocarbons with carbon isotope fractionation model results and fluid inclusion analysis. The carbon isotopic composition of methane and ethane in the Yulin gas field is relatively enriched in {sup 13}C with {delta}{sup 13}C{sub 1} values ranging from - 35.3 permille to - 29.8 permille (average value = - 32.4 permille) and {delta}{sup 13}C{sub 2} ranging from - 26.3 permille to - 23.5 permille (average value = - 24.8 permille). The C{sub 7} light hydrocarbons are predominated by methylcyclohexane, accounting for 65.8% to 80.9% (average value = 71.6%), which is characteristic of coal-derived gas. Furthermore, the ...

2010-04-01

21

Composition of insoluble kerogen-like organic polymer in the carbonate rocks of Orenburg gas-condensate deposit  

British Library Electronic Table of Contents (United Kingdom)

The concentrates of scattered organic matter???kerogen-like polymer, which is insoluble in acids and organic solvents???were isolated from rock samples taken at different depths from various stratigraphic units at the productive deposits of the Orenburg oil-gas condensate field using chemical methods. The chemical composition of the kerogen-like polymer and the concentrations of trace elements in it were studied. The regularities of evolutionary changes in the composition of the organic matter and the concentrations of trace elements in it in the order of the kerogen-like polymer and the following its consecutive derivatives were established: asphaltenes, ethanol-benzene tars, benzene tars, oils, and paraffins

2011-01-01

22

The evaporation pan technique revisited: Old theory and a new application for time-weighted synoptic tracing of the isotopic composition of atmospheric vapour  

International Nuclear Information System (INIS)

Reliable and consistent characterization of the stable isotope composition of atmospheric water vapour and its temporal variability are important prerequisites to the wider application of isotope mass balance methods in atmospheric and water balance studies. A new approach is proposed which utilizes standard class-A evaporation pans, which have sufficient volume to buffer short-term transient variations in atmospheric conditions, justifying the assumption of constant kinetic isotopic fractionation effects in concert with precisely measured temperature and relative humidity to derive vapour isotopic composition. The results of the studies suggest that isotopic sampling of existing, conventionally operated class-A evaporation pans could offer a straightforward and cost-effective solution to the problem of documenting the shifting isotopic distribution in atmospheric moisture

1999-12-01

23

Consolidation behavior of Cu- and Ni-based bulk metallic glass composites  

Energy Technology Data Exchange (ETDEWEB)

The Cu- and Ni-based bulk metallic glass matrix composites were fabricated by spark plasma sintering of a mixture of gas-atomized metallic glass powders and ductile brass powders. The brass powders added for the enhancement of plasticity are well distributed in the matrix after consolidation. The matrix of the composite materials remains as a fully amorphous phase after consolidation process. With increasing the brass content, the level of plasticity strain increased, although the level of strength decreased. The successful consolidation of metallic glass matrix composite with high density was attributed to viscous flow in the supercooled liquid state during spark plasma sintering.

2007-05-31

24

Model-based control strategy for direct injection diesel engine; Model enzan ni motozuku chokufun diesel engine no seigyo saitekika  

Energy Technology Data Exchange (ETDEWEB)

For a direct injection diesel engine to exhibit its inherent low-emission characteristics, it is essential to improve control accuracy, in particular under transient operating conditions during which emissions are more noted. A model-based control system is established for exhaust gas recirculation (EGR) and air/fuel ratio, using a diesel-engine/vehicle model established on the CAD control system. Described herein are the results of simulation for optimizing control of transient conditions, and the emission-controlling effects confirmed by the field tests. The tests for verification of the established model have confirmed that there are good agreements between the simulated and observed results in terms of air/fuel ratio changing with EGR ratio, exhaust and intake gas and pressure levels, and vehicle speed. The model will be applicable to assessment of emission characteristics under varying conditions. ...

1997-05-01

25

Characterization of the combustion of biomass producer gas in a constant volume combustion bomb  

British Library Electronic Table of Contents (United Kingdom)

In this article a methodology is presented for studying the influence of the biomass moisture content and the biomass/air ratio on the producer gas composition and on the chemiluminescent emissions during the combustion process. Firstly, a mathematical model based on the thermo-chemical processes inside the gasifier is used to predict the composition of the producer gas as a mixture of CO, CO2, H2, N2, CH4 and H2O gases. Secondly, the predicted composition is introduced into a constant volume combustion bomb (CVCB), which simulates the typical conditions inside the combustion chamber of an internal combustion engine, in order to characterize its combustion under gasoline-type conditions through the instantaneous pressure and the detection of the spontaneous luminous radiation (chemilumines...

2010-01-01

26

The origin of natural gas and the hydrocarbon charging history of the Yulin gas field in the Ordos Basin, China  

British Library Electronic Table of Contents (United Kingdom)

The genetic type, source and charging history of natural gas in the Yulin gas field in the Ordos Basin have been studied by combining the carbon isotopic composition of natural gas and geochemical characteristics of light hydrocarbons with carbon isotope fractionation model results and fluid inclusion analysis. The carbon isotopic composition of methane and ethane in the Yulin gas field is relatively enriched in ^1^3C with d^1^3C1 values ranging from -35.3%% to -29.8%% (average value=-32.4%%) and d^1^3C2 ranging from -26.3%% to -23.5%% (average value=-24.8%%). The C7 light hydrocarbons are predominated by methylcyclohexane, accounting for 65.8% to 80.9% (average value=71.6%), which is characteristic of coal-derived gas. Furthermore, the gas geochemistry indicates that, although marine lime...

2010-01-01

27

Transient simulation of a catalytic converter for a dual fuel engine  

Energy Technology Data Exchange (ETDEWEB)

A catalytic converter of a ceramic monolith honeycomb substrate, coated with a washcoat of catalyst and attached to a natural gas/diesel dual fuel engine was simulated and studied experimentally. The paper describes the application of one-dimensional finite element model for the transient and steady state operation. Laminar flow was approximated using a dispersed plug flow model, and chemical kinetics were simulated using LHHW (Langmuir/ Hinshelwood/ Hougan/ Watson) type expressions. Simulation results were compared with experimental results for heating and cooling cycles which resulted from speed and load changes on the engine. The comparison showed a maximum difference between the two sets of emission levels of about 10 per cent, showing that the one-dimensional model is acceptable model for this dual fuel engine converter combination. 50 refs., 3 tabs., 13 figs.

2000-06-01

28

Ppercase(femaxi-iv): a computer code for the analysis of thermal and mechanical behavior of light water reactor fuel rods  

International Nuclear Information System (INIS)

Ppercase(femaxi-iv) is a computer code for the analysis of thermal and mechanical behavior of light water reactor fuel rods during steady-state and transient conditions. The main purpose of ppercase(femaxi-iv) is to calculate the stress and strain distributions in the fuel and cladding due to the pellet-cladding mechanical interaction, and the fission gas release rate during operations, especially power transients. The capability of ppercase(femaxi-iv) was extensively tested with a number of experimental results obtained in some international fuel irradiation programs. This paper provides a general description of the various models involved in ppercase(femaxi-iv) and some results of applications on the experimental data. ((orig.)).

1994-01-01

29

Femaxi-iv: a computer code for the analysis of thermal and mechanical behavior of light water reactor fuel rods  

Energy Technology Data Exchange (ETDEWEB)

Femaxi-iv is a computer code for the analysis of thermal and mechanical behavior of light water reactor fuel rods during steady-state and transient conditions. The main purpose of femaxi-iv is to calculate the stress and strain distributions in the fuel and cladding due to the pellet-cladding mechanical interaction, and the fission gas release rate during operations, especially power transients. The capability of femaxi-iv was extensively tested with a number of experimental results obtained in some international fuel irradiation programs. This paper provides a general description of the various models involved in femaxi-iv and some results of applications on the experimental data. ((orig.))

1994-06-01

30

Stable-Carbon-Isotope Composition of Fatty Acids in Hydrothermal Vent Mussels Containing Methanotrophic and Thiotrophic Bacterial Endosymbionts  

UK PubMed Central (United Kingdom)

Fatty acid biomarker analysis coupled with gas chromatography-isotope ratio mass spectrometry was used to confirm the presence of methanotrophic and thiotrophic bacterial endosymbionts in the tissues...Full Text Available

1998-01-01

31

Revision number 2 to test design description Volume IB, Part 2 (WHC-SP-0214) FSP-1R FFTF test assembly (HF191A)  

Energy Technology Data Exchange (ETDEWEB)

Based on changes to the fuel pin gas gap composition, pin location and assembly location, revisions to the TDD-IB, Part 2 are provided.

1989-07-14

33

Control of Phosphorus Transient Enhanced Diffusion using Co-implantation  

CERN Document Server

Control of Phosphorus Transient Enhanced Diffusion using Co-implantation

2006-01-01

34

Densification behavior and properties of Y_2O_3-containing #alpha#-SiAlON-based composites  

International Nuclear Information System (INIS)

Different SiAlON composites based on #alpha#'-SiAlON are investigated, with respect to the phase relationships, densification behavior, and mechanical properties. The compositions are located on a phase-diagram line parallel to the Si_3N_4-Y_2O_3#centre dot#9AlN compound in the Si_3N_4-SiO_2-AlN-Al_2O_3-Y_2O_3-YN system. Analysis of the reaction sequences shows that the formation of the composites is associated with the transient appearance of Y_4Al_2O_9 (YAM), yttrium-aluminum-garnet (YAG), melilite, and a nitrogen-rich liquid phase. The small shift of compositions on the Si_3N_4-Y_2O_3#centre dot#9AlN compound phase-diagram line toward the Al_2O_3-rich side offers the advantage of a higher sinterability and the removal of the melilite phase from a wide range of compositions containing #alpha#'-SiAlON and polytypes. The #alpha#'/#beta#'-SiAlON ...

35

A model for the calculation of vent clearing transients in pressure suppression systems  

International Nuclear Information System (INIS)

For the layout of a pressure suppression system of a light water cooled reactor (boiling water reactor) it is important to know the time dependent behavior of the vent clearing transient after a loss-of-coolant accident for two main reasons: time of the end of the vent clearing transient influences strongly the pressure and temperature maxima in the drywell and wetwell. Time-dependent behavior of the vent clearing transient influences pressure loads in the condensation pool of the wetwell and therefore pressure induced stresses to the structure. The time-dependent behavior of the water masses in the vent pipes and wetwell are described by the basic equations for a nonstationary incompressible friction flow: momentum equation, continuity equation and a correlation for the variation of the state of the gas volume in the wetwell above the water level. After many algebraic operations and integrations along ...

1975-09-01

36

Influence of SiC addition on tribological properties of SiAlON  

British Library Electronic Table of Contents (United Kingdom)

The tribological properties of gas pressure sintered SiAlON and its composite with 18wt% silicon carbide (SiC) against two different mating materials, i.e., alumina and SiAlON are evaluated. SiAlON and SiAlON-18%SiC composite ceramics were prepared by pressure less sintering and gas pressure sintering. Fretting wear tests were carried out under dry unlubricated ambient conditions (room temperature 23-25^oC; relative humidity 50-55%) with a load of 8N for 45,000 cycles. Friction and wear properties of SiAlON-SiC proved better than the monolithic SiAlON. The formation of silica roll like structure on the composite worn surface was observed.

2011-01-01

37

Helium-cooling in fusion power plants  

Energy Technology Data Exchange (ETDEWEB)

This paper reviews different helium-cooled first wall and blanket designs; and compares the selection of structural materials. The authors found that the solid breeder, SiC-composite material option generates the lowest amount of induced radioactivity and afterheat and has the highest temperature capability. When combined with the direct cycle gas turbine system, it has the potential to be the most economical fusion system and can compete with advanced fission reactors. When compared to martensitic steel and V-alloy, SiC-composite is the least developed of these three structural materials, a focused development effort will be needed. Fundamental research has begun in addressing the issues of optimized composite materials, irradiation effects, leak tightness and low activation braze materials. Development of helium-cooled high heat flux components and further development of the direct cycle ...

1994-11-01

38

Experimental study on simultaneous desulfurization and denitrification from flue gas with composite absorbent  

British Library Electronic Table of Contents (United Kingdom)

Abstract The characteristics of desulfurization and denitrification with composite absorbent were researched through aqueous absorption experiments. The removal efficiencies of SO2 and NO were up to 100 and 95%, respectively. The composite absorbent included NaClO2 and component M. Existence of component M in the solution could reduce the absorbent cost compared with using sodium chlorite alone. Chlorine dioxide, as main reaction intermediate product, participated in oxidation reaction. The optimal experimental conditions involved NaClO2 concentration of1.13 mmol/L, solution pH of 5.5, molar ratio (M/NaClO2) of 4.1, reaction temperature of 323 K. The optimal solution pH and reaction temperature were both in the required ranges of limestone-gypsum wet flue gas desulfurization (FGD) process....

2011-01-01

39

New injection equipment for high-speed Diesel engines  

Energy Technology Data Exchange (ETDEWEB)

A high-speed light-Diesel engine with direct injection has been developed by the Institute of Combustion Engines, Graz. Thanks to light construction throughout, exhaust gas supercharger and noise-reduced composition a Diesel engine could be built that is comparable to Otto-cycle engines as regards performance, weight, aggregate size and noise production but far superior to these with respect to fuel consumption and exhaust gas emission.

1982-09-01

40

Desulphurization of hot reducing gases in the entrained bed reactor  

Energy Technology Data Exchange (ETDEWEB)

Using an experimental pilot plant, designed and built for the tests, the influence of the following parameters was determined: desulphurization of the test gas, temperature, residence time in the reactor tube, concentration of the hydrogen sulphide and desulphurization agent, size of the particles which comprise the agent and composition of the gas. Allowance was made for the effect of calcination and carbonisation. Desulphurization was carried out with limestone on a gaseous mixture of CO and H/sub 2/. A mathematical description of the test findings and yield is presented. 8 refs.

1986-08-01

41

Fluid pressure arrival time tomography: Estimation and assessment in the presence of inequality constraints, with an application to a producing gas field at Krechba, Algeria  

Energy Technology Data Exchange (ETDEWEB)

Deformation in the overburden proves useful in deducing spatial and temporal changes in the volume of a producing reservoir. Based upon these changes we estimate diffusive travel times associated with the transient flow due to production, and then, as the solution of a linear inverse problem, the effective permeability of the reservoir. An advantage an approach based upon travel times, as opposed to one based upon the amplitude of surface deformation, is that it is much less sensitive to the exact geomechanical properties of the reservoir and overburden. Inequalities constrain the inversion, under the assumption that the fluid production only results in pore volume decreases within the reservoir. We apply the formulation to satellite-based estimates of deformation in the material overlying a thin gas production zone at the Krechba field in Algeria. The peak displacement after three years of gas production is approximately ...

2010-04-01

42

The effect of oxygen enriched air obtained by gas separation membranes from the emission gas of diesel engines  

British Library Electronic Table of Contents (United Kingdom)

Gas separation membranes with polydimethylsiloxane(PDMS)/polystyrene(PS) were prepared by using the sequential interpenetrating polymer network (IPN) method with various PS contents (10?70wt%). These gas separation membranes can be applied to reduce the smoke density in the emission gas of diesel engines. PS content has a pronounced effect on the membrane performance. It was found that the optimized PS contents in the final membrane were 50wt%. The emission capacities of diesel engines used in this study were 632 cc and 11,149 cc. When the oxygen separation membrane was used in the diesel engines, the smoke density of both diesel engines was remarkably reduced (35?73%). The oxygen concentration in the inlet air affects the composition of the emission gases. Especially, hydrocarbon (HC) dec...

2006-01-01

43

Modeling of lean premixed combustion in stationary gas turbines  

Energy Technology Data Exchange (ETDEWEB)

Lean premixed combustion (LPC) of natural gas is of considerable interest in land-based gas turbines for power generation. However, modeling such combustors and adequately addressing the concerns of LPC, which include emissions of nitrogen oxides, carbon monoxide and unburned hydrocarbons, remains a significant challenge. In this paper, characteristics of published simulations of gas turbine combustion are summarised and methods of modeling turbulent combustion are reviewed. The velocity-composition PDF method is selected for implementation in a new comprehensive model that uses an unstructured-grid flow solver. Reduced mechanisms for methane combustion are evaluated in a partially stirred reactor model. Comprehensive model predictions of swirl-stabilised LPC of natural gas are compared with detailed measurements obtained in a laboratory-scale combustor. The model is also applied to ...

1999-07-01

44

Effects of various gas mixtures on plasma nitriding behavior of AISI 5140 steel  

International Nuclear Information System (INIS)

AISI 5140 steel was plasma nitrided at various gas mixtures of nitrogen, hydrogen, and argon to investigate the actions of hydrogen and argon on plasma nitriding. The structural and mechanical properties of ion-nitrided AISI 5140 steel have been assessed by evaluating composition of phases, surface hardness, compound layer thickness, and case depth by using X-ray diffraction (XRD), microhardness tests, and scanning electron microscopy (SEM). It was found that the growth of compound layer can be controlled and the diffusion improved when the gas mixture includes H_2 gas. Additionally, it was determined that the amount of Ar in dual gas mixture must be at 20% minimum to obtain distinctive surface hardness and compound layer thickness.

2002-10-01

45

Coenzyme Q10 nanoparticles prepared by a supercritical fluid-based method  

British Library Electronic Table of Contents (United Kingdom)

A supercritical fluid-based method is proposed to produce coenzyme Q10 (CoQ10) nanoparticles. First, CoQ10/polyethylene glycol 6000 composite particles are prepared by a modified PGSS (particles from gas-saturated solutions) process with controlling the flow rate of the gas-saturated solution. Then, CoQ10 nanoparticles are obtained by dissolving the composite particles into water. The effect of experimental variables of the modified PGSS process, including pressure, temperature, flow rate of the gas-saturated solution, and mass fraction of CoQ10, on the CoQ10 particle size and particle size distribution was investigated. Results show that CoQ10 slurry product with a median diameter of 190nm and yield of 89.8% can be prepared at an optimum condition (operating pressure of 25MPa, operating t...

2011-01-01

46

Testing of the 1-MWth bench-model cavity-receiver steam generator  

Science.gov (United States)

A schematic of the Bench cavity receiver system is given, and the primary objectives, schedule and research plan for each of four tests are discussed. The tests are: (1) cold flow testing to functionally check all valves and their response using high pressure nitrogen gas; (2) a hot checkout to simulate both steady state and transient flux inputs to the receiver which are expected at the French facility; (3) basic performance using solar energy at the French facility; and (4) ir radiant heat testing. (LEW)

47

Microcantilever detector for explosives  

Energy Technology Data Exchange (ETDEWEB)

Methods and apparatus for detecting the presence of explosives by analyzing a vapor sample from the suspect vicinity utilize at least one microcantilever. Explosive gas molecules which have been adsorbed onto the microcantilever are subsequently heated to cause combustion. Heat, along with momentum transfer from combustion, causes bending and a transient resonance response of the microcantilever which may be detected by a laser diode which is focused on the microcantilever and a photodetector which detects deflection of the reflected laser beam caused by heat-induced deflection and resonance response of the microcantilever. 2 figs.

1999-06-29

48

Origin of salinity in produced waters from the Palm Valley gas field, Northern Territory, Australia  

Energy Technology Data Exchange (ETDEWEB)

The chemical composition and evolution of produced waters associated with gas production in the Palm Valley gas field, Northern Territory, has important implications for issues such as gas reserve calculations, reservoir management and saline water disposal. The occurrence of saline formation water in the Palm Valley field has been the subject of considerable debate. There were no occurrences of mobile water early in the development of the field and only after gas production had reduced the reservoir pressure, was saline formation water produced. Initially this was in small quantities but has increased dramatically with time, particularly after the initiation of compression in November 1996. The produced waters range from highly saline (up to 300,000 mg/L TDS), with unusual enrichments in Ca, Ba and Sr, to low salinity fluids that may represent condensate waters. The Sr isotopic ...

2005-04-01

49

Origin of salinity in produced waters from the Palm Valley gas field, Northern Territory, Australia  

International Nuclear Information System (INIS)

The chemical composition and evolution of produced waters associated with gas production in the Palm Valley gas field, Northern Territory, has important implications for issues such as gas reserve calculations, reservoir management and saline water disposal. The occurrence of saline formation water in the Palm Valley field has been the subject of considerable debate. There were no occurrences of mobile water early in the development of the field and only after gas production had reduced the reservoir pressure, was saline formation water produced. Initially this was in small quantities but has increased dramatically with time, particularly after the initiation of compression in November 1996. The produced waters range from highly saline (up to 300,000 mg/L TDS), with unusual enrichments in Ca, Ba and Sr, to low salinity fluids that may represent condensate waters. The Sr isotopic ...

2005-04-01

50

Investigation of the steady state and transient operating behaviour of a 20 kW pressure electrolyser  

Energy Technology Data Exchange (ETDEWEB)

The present paper describes the investigation of the static and dynamic behaviour of an 20 kW pressure electrolyser. The suitability for a coupled operating regime with a wind power plant has been investigated. At first the static behaviour has been analysed. The share of oxygen in hydrogen gas is lower than 0.5 Vol%. But reaching the temperature limit of 80 deg C leads to a switch off of the electrolyser, accompanied by an increase of the oxygen share in hydrogen gas up to 1.3 Vol%. Therefore, an improvement of the cooling system is necessary. Secondly, the electrolyser was excited by different step signals for load changing and finally, the electrolyser has been controlled by the power output signal of the windmill. The investigation shows that the development of a direct coupled wind-hydrogen system will be only a small step. 3 refs.

1998-07-01

51

Experimental investigation of spray induced gas stratification break-up and mixing in two interconnected vessels  

British Library Electronic Table of Contents (United Kingdom)

To analyze the effect of containment spray on gas mixing and depressurization, two experiments (ST3_1 and ST3_2) were performed with two interconnected vessels. These experiments were conducted in the frame of the OECD/SETH-2 project using the PANDA facility. The vessels were preconditioned such that a helium-rich layer is formed in the upper section of the first vessel, henceforth referred to as Vessel-1. In the case of the first experiment (ST3_1), the remaining volume of Vessel-1 and the entirety of the second vessel, Vessel-2, were filled with pure steam. For ST3_2, the second experiment presented here, pure steam was replaced with a steam-air mixture instead. Water was injected from the top of Vessel-1 with a spray nozzle projecting downwards. Transient behavior of system pressure, as...

2011-01-01

52

Active catalytic sites in the ammoxidation of propane and propene over V-Sb-O catalysts  

Energy Technology Data Exchange (ETDEWEB)

The ammoxidation of propane over VSb{sub y}O{sub x} catalysts (y=1, 2, 5) was investigated with respect to the role of different oxygen species in the selective and non selective reaction steps using transient experiments in the Temporal Analysis of Products (TAP) reactor. Only lattice oxygen is involved in the oxidation reactions. Using isotopic labelled oxygen it is shown that two different active sites exist on the surface. On site A, which can be reoxidized faster by gas phase oxygen compared to site B, mainly CO is formed. On site B CO{sub 2} and acrolein as well as NO and N{sub 2}O in the presence of ammonia in the feed gas are formed and reoxidation mainly occurs with bulk lattice oxygen. (orig.)

1998-12-31

53

Development of tough #alpha#-SiAlON  

International Nuclear Information System (INIS)

The development of tough #alpha#-SiAlON with elongated grains in the last five years is summarized. This progress has been guided by the improved understanding of phase relations and nucleation/growth kinetics in SiAlON ceramics. Although most #alpha#-SiAlON compositions can be processed to contain some elongated grains, their microstructure, fracture toughness and R-curve behavior vary greatly. Such variability is due to the different phase stability of #alpha#-SiAlONs and the varying physical chemistry of the competing phases, including the transient/residual liquid. For this reason, microstructure control of #alpha#-SiAlON must pay close attention to the composition, starting powder and heating schedule. Seeding with single crystals of an appropriate #alpha#-SiAlON composition provides an attractive alternative that simplifies the task of microstructure control, since such seeds are thermodynamically ...

54

Development of a cupola furnace process model. Final technical report  

Science.gov (United States)

A strategic partnership was formed among the American Foundrymen`s Society and the Federal government to develop and transfer the technology needed by the US foundry industry to: increase energy efficiency of cupola melting; improve recovery of carbon, silicon, and manganese through reduced oxidation losses; and improve productivity due to more uniform and predictable iron compositions. An effective mathematical model of the cupola offers a solution to the complex and interactive chemical and heat transfer processes to melt cast iron. The transient changes in charge size, charge composition, blast rate, and coke rate are used to optimize operation to improve melting rates, minimize oxidation losses of valuable alloying elements (C, Si, and Mn), and maintain iron composition. Despite these challenges, the cupola produces iron at a lower cost, and have better environmental controls than other melting ...

1995-07-01

55

Visualization and measurement of pressurized multiphase flow using neutron radiography of JRR-3M system  

Energy Technology Data Exchange (ETDEWEB)

Concerning the transient phenomenon of solid-gas two-phase flow, an attempt was made to visualize and measure a flow phenomenon in which three-dimensional bubbles occurred, grew and collapsed in the vicinity of a gas injection nozzle while solid particles were circulating. Such a phenomenon could not or hardly be visualized and measured by conventional methods. Such two-phase flow was visualized using neutron radiography, its characteristics measured and the usefulness of the visualization by neutron radiography confirmed. For this purpose, three-dimensional fluidized bed vessels, rectangular or cylindrical-shaped, made of steel or aluminum sheet, were prepared. Polyethylene or glass beads were used as solid particles and activated carbon particles as the tracer. In the experiment, nitrogen gas was blown into the vessel from one nozzle and distributors provided at the bottom of the vessel and exhausted ...

1998-01-01

56

Evaluation of spark ignition of a gas cooktop flame  

Science.gov (United States)

One of the energy-saving devices used on gas cooking appliances to eliminate the standing pilot is a spark ignition system. For safety, an ignition system must start promptly and be active whenever flowing gas is not ignited. To minimize noise and nuisance shock hazard, ignition must occur quickly and the sparking must be stopped as soon as ignition occurs and remain off as long as the flame is present. To accomplish both of these requirements, ignition systems have been devised which use the electrical current rectification property of a flame to sense it. These systems spark whenever the gas valve is on and a flame is not present. The factors affecting the performance of a spark ignition system are numerous, complex, and transient. All of these properties make quantification of performance difficult. A system is described which can evaluate the overall performance of ignition systems over significant ...

1996-01-01

59

Cardiac Rehabilitation for TIA Patients  

Science.gov (United States)

TIA (Transient Ischemic Attack)

2010-12-13

61

Stress corrosion cracking: 1965-1990  

Energy Technology Data Exchange (ETDEWEB)

Advances in the theory and practice of stress corrosion cracking (SCC) are reviewed for the period 1965-1990. The proceedings of two landmark conferences are used as a basis for discussion: Ohio State University (1967) and Kohler, WI (1988). The discussion is developed around the following topics: metal-environment combinations, testing, fractography, metallurgical aspects, electrochemical aspects and crack chemistry, mechanisms, and prediction and mitigation. It is concluded that the main developments since 1967 are the recognition of the lack of specificity of SCC environments, the use of slow strain rate and fracture mechanics testing, quantitative SEM fractography, studies of grain boundary structure and compositions, transient electrochemistry of bare metal surfaces, measurement and modelling of crack chemistry, elaboration of several SCC models, including slip-dissolution and film induced cleavage, and mitigation by alloy development or ...

1990-01-01

62

Recycling and ?re-hydration? of degassed magma inducing transient dissolution/crystallization events at Stromboli (Italy)  

British Library Electronic Table of Contents (United Kingdom)

Intrusive degassing and recycling of degassed and dense magma at depth have been proposed for a long time at Stromboli. The brief explosive event that occurred at the summit craters on 9 January 2005 threw out bombs and lapilli that could be good candidates to illustrate recycling of shallow degassed magma at depth. We present an extensive data set on both the textures and the mineral, bulk rock and glassy matrix chemistry of the ?9 Jan? products. The latter have the common shoshonitic?basaltic bulk composition of lavas and scoriae issued from typical strombolian activity. In contrast they differ by the heterogeneous chemistry of their matrix glasses and their crystal textures that testify to crystal dissolution event(s) just prior magma crystallization upon ascent and eruption. Comparison...

2008-01-01

63

Nomographs for the optimum solar pond driven LiBr/ZnBr sub 2 /CH sub 3 OH absorption-refrigeration system  

Energy Technology Data Exchange (ETDEWEB)

The paper presents a procedure for the calculation of an absorption-refrigeration plant that uses an LiBr/ZnBr{sub 2}/CH{sub 3}OH solution and is driven throughout the year by heat received from a solar pond. The calculations for the solar pond are based on a finite-difference solution of the transient heat conduction differential equation during the year, and the operation of the refrigeration unit is simulated by the use of functions describing the thermodynamic behaviour of the working medium. On the basis of the procedure devised, correlations and nomographs are developed that describe the seasonally optimum operation of the proposed composite system. The nomographs may be employed for a first estimation in the design of such systems. (Author).

1992-07-01

64

Multi-Dimensional Analysis for Sodium Hot Pool using MARS-LMR in Steady State  

International Nuclear Information System (INIS)

DBEs (Design Basis Event) of KALIMER-600 (Korea Advanced Liquid Metal Reactor) were analyzed in one dimension by KAERI (Korea Atomic Energy Research Institute). KALIMER-600 is the pool type SFR (Sodium cooled Fast Reactor), thereby the sodium of primary system is prohibited movement to out of a reactor vessel. There are many contacting and including compositions in the sodium hot pool, such as IHX (Intermediate Heat eXchanger), DHX (Decay Heat eXchanger), Pump, UIS (Upper Internal Structure), and core. Moreover, the complex phenomena are occurred in sodium hot pool during steady and transient states. Therefore, the one dimensional analysis is modified to the multi-dimensional analysis through modification of sodium hot pool from one to three dimensions

2010-10-01

65

Formation conditions, chloride content, and stability of passive films on an iron-chromium alloy  

Energy Technology Data Exchange (ETDEWEB)

Passive films were formed on a high purity Fe-23 Cr alloy in acid sulfate solutions in the presence and absence of chloride ion. The resulting film composition was investigated by Auger depth profiling. The passivated samples were exposed to a 1M NaCl solution at a constant potential slightly above the critical pitting potential, and the current-time transient was measured in order to compare the relative stability of the different films. The results obtained suggest that the formation conditions influence the chloride content of the passive film and the breakdown behavior. Passive films formed in the presence of chloride contain and are slightly less stable towards breakdown. No chloride was found in films formed in sulfate and subsequently exposed to chloride well below the pitting potential.

1993-07-01

66

Giant gas field of northern West Siberia  

Energy Technology Data Exchange (ETDEWEB)

The 66 fields discovered since the 1960s in the northern West Siberian basin contain at least 22 trillion m/sup 3/ (777 tcf) of proved gas, almost one-third of the world's reserves. Half of these fields are giants (> 85 billion m/sup 3/ or 3000 bcf of reserves). These include the largest and second-largest gas fields in the world-Urengoy (8.099 trillion m/sup 3/ or 286 tcf of gas) and Yamburg (4.81 trillion m/sup 3/ or 170 tcf of gas)-as well as most of the other ten largest gas fields in the world. The West Siberian basin occupies a 3.4-million km/sup 2/ (1.31-million mi/sup 2/) arctic lowland immediately east of the Ural Mountains, extending north under the Kara Sea. It is a composite basin, with Mesozoic-Cenozoic basin fill on top of a Paleozoic basin that overlies a crystalline Archean-Proterozoic framework. The productive zones in the northern ...

1986-06-01

67

Investigation on boron transient enhanced diffusion induced by the advanced P{sup +}/N ultra-shallow junction fabrication processes  

Energy Technology Data Exchange (ETDEWEB)

In this paper, we propose to characterize boron transient enhanced diffusion (TED) for processes currently used for P{sup +}/N ultra-shallow junctions (USJ) fabrication. Indeed, the fundamental understanding of boron diffusion for low energy boron implantation is mandatory to evaluate the scalability of such processes for the coming complementary metal-oxide-semiconductor (CMOS) transistor generations. In these experiments, we characterize the boron anomalous diffusion, thanks to boron buried marker-layers obtained by epitaxial growth. B{sup +} and BF{sub 2}{sup +} ultra-low energy (ULE) implantations and plasma doping (PLAD) using BF{sub 3} as precursor gas are carried out to compare the two techniques used for advanced USJ fabrication. Boron diffusion behaviors are analyzed via secondary ion mass spectrometry for annealing at 700 deg. C for 5 min and 15 min. Finally this paper brings some physical insights explaining the technological benefit ...

2005-08-01

68

Investigation on boron transient enhanced diffusion induced by the advanced P"+/N ultra-shallow junction fabrication processes  

International Nuclear Information System (INIS)

In this paper, we propose to characterize boron transient enhanced diffusion (TED) for processes currently used for P"+/N ultra-shallow junctions (USJ) fabrication. Indeed, the fundamental understanding of boron diffusion for low energy boron implantation is mandatory to evaluate the scalability of such processes for the coming complementary metal-oxide-semiconductor (CMOS) transistor generations. In these experiments, we characterize the boron anomalous diffusion, thanks to boron buried marker-layers obtained by epitaxial growth. B"+ and BF_2"+ ultra-low energy (ULE) implantations and plasma doping (PLAD) using BF_3 as precursor gas are carried out to compare the two techniques used for advanced USJ fabrication. Boron diffusion behaviors are analyzed via secondary ion mass spectrometry for annealing at 700 deg. C for 5 min and 15 min. Finally this paper brings some physical insights explaining the technological benefit coming from PLAD ...

2005-08-01

69

A Remarkable Low-Mass X-ray Binary within 0.1 pc of the Galactic Center  

CERN Document Server

Recent X-ray and radio observations have identified a transient low-mass X-ray binary (LMXB) located only 0.1 pc in projection from the Galactic center, CXOGC J174540.0-290031. In this paper, we report the detailed analysis of X-ray and infrared observations of the transient and its surroundings. Chandra bservations detect the source at a flux of F_X = 2e-12 erg cm^-2 s^-1 (2-8 keV). After accounting for absorption both in the interstellar medium and in material local to the source, the implied luminosity of the source is only L_X = 4e34 erg/s (2-8 keV; D=8 kpc). However, the diffuse X-ray emission near the source also brightened by a factor of 2. The enhanced diffuse X-ray emission lies on top of a known ridge of dust and ionized gas that is visible infrared images. We interpret the X-ray emission as scattered flux from the outburst, and determine that the peak luminosity of CXOGC J174540.0-290031 was >2e36 erg/s. We ...

2005-01-01

70

Scope and dissolution studies and characterization of irradiated nuclear fuel in Atalante Hot Cell Facilities (abstract and presentation slides)  

Energy Technology Data Exchange (ETDEWEB)

Since 1999, several studies on nuclear fuels were realised in C11/C12 Atalante Hot Cell. This paper presents firstly an overview of the apparatus used for fuel dissolution and characterisation like reactor design, gas trapping flask and solid/liquid separation. Then, the general methodology is described as a function of fuel, temperature, reagents, showing for each step, the reachable experimental data: Dissolution rate, chemical and radiochemical fuel composition including volatile LLRN, insoluble mass, composition, morphology, cladding chemical, radiochemical and physical characterisation using SIMS (made in Cadarache/LECA facilities), MEB. To conclude, some of the obtained results on 129I and 14C composition of oxide fuels, rate of dissolution and first results on dissolution studies of RERTR UMo fuel will be detailed. (Author)

2005-01-01

71

Resistance of the alloy steel used in the fuel gas desulphurization installations  

International Nuclear Information System (INIS)

The results have been presented of DC polarization and exposure investigations of alloy steels used as construction materials in flue gas desulphurization installations. on the base of analysis of composition of investigated steels and results of polarization studies, conditions have been discussed in which the pitting resistance equivalent (PRE) should be used. Among tested steels the significantly highest resistance to pitting corrosion is exhibited by 654SMO steel, classified as the super austenitic grade. (author). 14 refs, 3 figs, 2 tabs.

72

Fundamental study on CO{sub 2} removal from the flue gas of thermal power plant by hollow-fiber gas-liquid contactor  

Energy Technology Data Exchange (ETDEWEB)

Microporous membranes are suitable for the CO{sub 2}-MEA (monoethanolamine) system because the overall mass transfer coefficient K of the membrane is approximately 10 times larger than that of composite membranes consisting of microporous membranes and homogeneous membranes. The overall volumetric mass transfer coefficient K{center_dot} of the hollow-fiber contact is more than 5 times larger than that of a conventional packed bed, which suggests that adorption using the present method has the advantage of making the absorption more compact. 8 refs., 7 figs., 4 tabs.

1994-12-31

73

Generation of ozone by pulsed corona discharge over water surface in hybrid gas-liquid electrical discharge reactor  

International Nuclear Information System (INIS)

Ozone formation by a pulse positive corona discharge generated in the gas phase between a planar high voltage electrode made from reticulated vitreous carbon and a water surface with an immersed ground stainless steel plate electrode was investigated under various operating conditions. The effects of gas flow rate (0.5-3 litre min"-"1), discharge gap spacing (2.5-10 mm), applied input power (2-45 W) and gas composition (oxygen containing argon or nitrogen) on ozone production were determined. Ozone concentration increased with increasing power input and with increasing discharge gap. The production of ozone was significantly affected by the presence of water vapour formed through vaporization of water at the gas-liquid interface by the action of the gas phase discharge. The highest energy efficiency for ozone production was obtained using high voltage pulses of ...

2005-02-07

74

Behavior of inert gas contamination in high Ni alloy powder and consolidation powder material; Ko Ni gokin funmatsu funmatsu seikeitai ni okeru fukassei gas seibun no kyodo  

Energy Technology Data Exchange (ETDEWEB)

Inert gas contamination, structure and mechanical properties of consolidated high-Ni alloy powder material were studied to improve its characteristics. In experiment, the chemical composition and fraction of porosity in cross sections of Alloy 625 powder were examined which was produced by Ar gas atomization method impinging supplemental gas jet onto accumulated alloy powder in the bottom of a tank for rapid cooling. The structure and mechanical properties of the alloy rod were also examined which was produced by hot hydrostatic pressing or hot extrusion of the powder filled into a capsule. As a result, although Ar content included in the powder produced by Ar gas atomization method decreased with reduction in grain size, the fine powder less than 22{mu}m still included Ar of nearly 0.5mass-ppm. Obvious correlation was found between the fraction of porosity in powder cross sections ...

1996-07-01

75

Design of experiment approach applied to reducing and oxidizing tolerance of anode supported solid oxide fuel cell. Part II: Electrical, electrochemical and microstructural characterization of tape-cast cells  

British Library Electronic Table of Contents (United Kingdom)

One of the major limitations of the nickel (Ni) - yttria-stabilized zirconia (YSZ) anode support for solid oxide fuel cells (SOFC) is its low capability to withstand transients between reducing and oxidizing atmospheres (''RedOx'' cycle), owing to the Ni-to-NiO volume expansion. This work presents results on different anode supports fabricated by tape casting. Three compositions are prepared, as the outcome of a preceding design of experiment approach. The NiO proportion is 40, 50 and 60wt% of the anode composite. The anode support characteristics like shrinkage during sintering, in-situ conductivity at high temperature, electrochemical performance and tolerance against RedOx cycles have been measured. Performance up to 0.72Wcm^-^2 (0.62V, 800^oC) is recorded for the 60wt% NiO sample on sm...

2011-01-01

76

Stable carbon isotope compositions and source rock geochemistry of the giant gas accumulations in the Ordos Basin, China  

Energy Technology Data Exchange (ETDEWEB)

Ordos Basin, the second largest sedimentary basin in China, contains enormous natural gas resources. Each of the four giant gas fields discovered so far in this basin (i.e., Sulige, Yulin, Wushenqi and Jingbian) has over 100 billion cubic meters (bcm) or 3.53 trillion cubic feet (tcf) of proven gas reserves. This study examines the stable carbon isotope data of 125 gas samples collected from the four giant gas fields in the Ordos Basin. Source rocks in the Upper Paleozoic coal measures are suggested by the generally high {delta}{sup 13}C values of C{sub 2}-C{sub 4} gaseous hydrocarbons in the gases from the Sulige, Yulin and Wushenqi gas fields. The {delta}{sup 13}C values of methane, benzene and toluene in gases from the Lower Paleozoic reservoirs of the Jingbian field indicate a significant contribution from humic source rocks, as they are similar to those in ...

2005-07-01

77

Review of combustion processes in the dual fuel engine: the gas diesel engine  

Energy Technology Data Exchange (ETDEWEB)

This review examines the characteristics of the compression-ignition type of dual-fuel engine and the combustion phenomena that affect these characteristics. The specific areas covered involve normal combustion processes, the nature and origin of engine knock, operation with LNG, and the effect of intake temperature on combustion efficiency and exhaust composition.

1980-01-01

78

Preparation of oxygen-containing organic products from bed-oxidized brown coal by ozonation  

Energy Technology Data Exchange (ETDEWEB)

The possibility of modifying the functional composition of humic acids by gas-phase ozonation of bed-oxidized brown coal was examined. About 90% of the organic matter of brown coal was converted to low-molecular weight soluble oxygen-containing products by stepwise liquid-phase ozonation (in chloroform and acetic acid).

2009-01-15

79

Offshore and arctic operations symposium - 1987  

Energy Technology Data Exchange (ETDEWEB)

This book presents the papers given at a conference on offshore platforms. Topics considered in this book include risk assessment, crack propagation, fracture control, stress corrosion, the reliability of pile foundations, the thermal conductivity of offshore pipeline coating material, economic analysis, hydrodynamics, simulation, Arctic structure design, composite materials, buoys, deep water drilling, corrosion protection, pollution control equipment, and subsea exhaust gas compressors.

1987-01-01

80

Coal geology and its application to coal-bed methane reservoirs  

Energy Technology Data Exchange (ETDEWEB)

A total of nine papers were presented at the course with the following titles: peat accumulation and coal basins; coal composition; coal quality; sedimentary environments of coal; generation, storage and migration of natural gas in coal bed reservoirs; geophysical log interpretation; the Ardley coal zone of central Alberta; stratigraphy and sedimentary environment of the Coalspur Formation; and the coal-bearing Luscar Group of western Alberta. All of these papers have been abstracted separately.

1990-01-01

81

CFCC radiant burner assessment. Final report, April 1, 1992--July 31, 1994  

Energy Technology Data Exchange (ETDEWEB)

The objective of this work was to identify methods of improving the performance of gas-fired radiant burners through the use of Continuous Fiber Ceramic Composites (CFCCs). Methods have been identified to improve the price and performance characteristics of the porous surface burner. Results are described.

1994-11-01

82

The formation and removal characteristics of aerosols in ammonia-based wet flue gas desulfurization  

British Library Electronic Table of Contents (United Kingdom)

The characteristics of aerosol generation were studied experimentally in an ammonia-based wet flue gas desulfurization process. Particle size distributions and concentrations, morphologies and compositions before and after desulfurization were measured using an electrical low pressure impactor and scanning electron microscopy, respectively. The results show that aerosols can be generated between ammonia and sulfur dioxide resulting in gas-phase reaction and the aerosol concentration at the outlet of scrubber is significantly higher than at the inlet. Before desulfurization the particles are primarily silica-alumina minerals including O, Al, Si and C, while after ammonia-based desulfurization aerosol particles have smooth surfaces with regular structures, such as cubic and prismatic crystal...

2011-01-01

83

FFTF criteria for run-to-cladding-breach experiments  

International Nuclear Information System (INIS)

The Fast Flux Test Facility (FFTF) is a liquid-metal-cooled fast reactor, which is designed to test a variety of different structural and fuel materials. A safety analysis is performed for each experiment that is irradiated in FFTF. The FFTF final safety analysis report (FSAR) assumed that all driver fuel assemblies would maintain cladding integrity during normal operations and all design transients. Maintenance of cladding integrity retains three barriers to any fission gas release to the public and also prevents any potential contact between the fuel and coolant. Experiments are, in general, expected to meet the same criterion. Selected experiments can, however, be classified as run-to-cladding-breach experiments (RTCB). The purpose of this paper is to describe alternative acceptance criteria for RTCB experiments that they feel provide protection equivalent to the maintenance of cladding integrity.

1986-06-15

84

Distribution of NADPH-diaphorase activity in the central nervous system of the young and adult land snail Megalobulimus abbreviatus  

British Library Electronic Table of Contents (United Kingdom)

Nitric oxide (NO) is a gas produced through the action of nitric oxide synthase that acts as a neurotransmitter in the central nervous system (CNS) of adult gastropod mollusks. There are no known reports of the presence of NOS-containing neurons and glial cells in young and adult Megalobulimus abbreviatus. Therefore, NADPH-d histochemistry was employed to map the nitrergic distribution in the CNS of young and adult snails in an attempt to identify any transient enzymatic activity in the developing CNS. Reaction was observed in neurons and fibers in all CNS ganglia of both age groups, but in the pedal and cerebral ganglia, positive neurons were more intense than in other ganglia, forming clusters symmetrically located in both paired ganglia. However, neuronal NADPH-d activity in the mesocer...

2010-01-01

85

The US Advanced Liquid Metal Reactor and the Fast Flux Test Facility Phase IIA passive safety tests  

International Nuclear Information System (INIS)

This report discusses the safety approach of the Advanced Liquid Metal reactor program, sponsored by the US Department of Energy, which relies upon passive reactor responses to off-normal condition to limit power and temperature excursions to levels that allow safety margins. Gas expansion modules (GEM) have included in the design to provide negative reactivity to enhance these margins in the extremely unlikely event that pumping power is lost and the highly reliable scram system fails to operate. The feasibility and beneficial features of these devices were first demonstrated in the core of the Fast Flux Test Facility (FFTF) in 1986. Preapplication safety evaluations by the US Nuclear Regulatory Commission have identified areas that must be addressed if these devices are to be relied on. One of these areas is the response of the reactor when it is critical and the pumps are turned on, resulting in positive reactivity being added to the core. Tests to examine such ...

1992-10-25

86

The U.S. Advanced Liquid Metal Reactor and the fast flux test facility phase IIA passive safety tests  

International Nuclear Information System (INIS)

The safety approach of the Advanced Liquid Metal Reactor program, sponsored by the U.S. Department of Energy, relies upon passive reactor responses to off-normal conditions to limit power and temperature excursions to levels that allow large safety margins. Gas expansion modules (GEM) have been included in the design to provide negative reactivity to enhance these margins in the extremely unlikely event that pumping power is lost and the highly reliable scram system fails to operate. The feasibility and beneficial features of these devices were first demonstrated in the core of the Fast Flux Test Facility (FFTF) in 1986. Pre-application safety evaluations by the U.S. Nuclear Regulatory Commission have identified areas that must be addressed if these devices are to be relied on. One of these areas is the response of the reactor when it is critical and the pumps are turned on, resulting in positive reactivity being added to the core. Tests to examine such ...

87

Theoretical study on composition of gas produced by coal gasification; Sekitan gas ka de seiseisuru gas no sosei ni kansuru kosatsu (HYCOL data no doteki kaiseki)  

Energy Technology Data Exchange (ETDEWEB)

In relation to considerations on composition of gas produced by coal gasification, the HYCOL hydrogen generation process data were analyzed. From the fact that CO concentration (Y) decreases linearly with CO2 concentration (X), element balance of gasification of reacted coal was used to introduce a reaction analysis equation. The equation includes a term of oxygen excess {Delta}(amount of oxygen consumed for combustion of CO and H2 in excess of the theoretical amount), derived by subtracting the stoichiometric oxygen amount used to gasify coal into CO and H2 from the consumed oxygen amount. The {Delta} can be used as a reference to oxygen utilization efficiency. An equation for the {Delta} was introduced. Also introduced was a term for steam decomposition amount derived by subtracting the generated steam from the supplied steam. These terms may be used as a clue to permeate into the gasifying reaction process. This suggestion was discussed by ...

1996-10-28

88

Catalytic oxidation of the unburnt fuel for the efficient production of electric energy  

Energy Technology Data Exchange (ETDEWEB)

Modern combined cycle power plants with natural gas as the only fuel reach efficiencies of up to 58% for electric power generation. Nevertheless the reserves of natural gas are more limited compared to the reserves of coal. Therefore possibilities should be investigated to use coal for such plants also. One concept, that combines the use of coal in a combined cycle application with high efficiencies is examined in this paper. According to this concept the exhaust gas of the gas turbine (vitiated air) is the combustion air for the pulverised coal combustion, that takes place in the bottoming steam generator. Due to the low oxygen content of the vitiated air the burnout of the coal may be incomplete. In order to avoid the incomplete combustion of the coal and the resulting decrease of the efficiency of the plant and possible emission problems, a catalyst, that converts carbon monoxide and unburnt carbon ...

1995-12-31

89

Application of SGFM technology to alternate feedstocks. Phase III  

Energy Technology Data Exchange (ETDEWEB)

The Synthesis Gas From Manure (SGFM) pilot plant was constructed at Texas Tech University to evaluate the gasification of cattle feedlot manure. A study of gas yield and composition as a function of operating conditions was performed. This report presents the results of a comparison of feedstocks other than manure in the pilot plant. Oak sawdust was the superior feedstock tested in terms of both gas yield and operability. Corn stover and mesquite were comparable and presented some handling problems. Cotton gin trash was unacceptable due to low-temperature ash fusion in the reactor. The gas yield from oak sawdust varied from 0.8 to 1.7 1/gm DAF feed at average temperatures of 650 to 770/sup 0/C. The gas contained approximately 15% hydrogen and 40% carbon monoxide by volume. It also contained 5 to 8% methane and 2 to 5% ethylene. All of these results were obtained ...

1980-01-01

90

Method for forming a bladder for fluid storage vessels  

Energy Technology Data Exchange (ETDEWEB)

A lightweight, low permeability liner for graphite epoxy composite compressed gas storage vessels. The liner is composed of polymers that may or may not be coated with a thin layer of a low permeability material, such as silver, gold, or aluminum, deposited on a thin polymeric layer or substrate which is formed into a closed bladder using torispherical or near torispherical end caps, with or without bosses therein, about which a high strength to weight material, such as graphite epoxy composite shell, is formed to withstand the storage pressure forces. The polymeric substrate may be laminated on one or both sides with additional layers of polymeric film. The liner may be formed to a desired configuration using a dissolvable mandrel or by inflation techniques and the edges of the film seamed by heat sealing. The liner may be utilized in most any type of gas storage system, and is particularly applicable ...

2000-01-01

91

Lightweight bladder lined pressure vessels  

Energy Technology Data Exchange (ETDEWEB)

A lightweight, low permeability liner for graphite epoxy composite compressed gas storage vessels. The liner is composed of polymers that may or may not be coated with a thin layer of a low permeability material, such as silver, gold, or aluminum, deposited on a thin polymeric layer or substrate which is formed into a closed bladder using torispherical or near torispherical end caps, with or without bosses therein, about which a high strength to weight material, such as graphite epoxy composite shell, is formed to withstand the storage pressure forces. The polymeric substrate may be laminated on one or both sides with additional layers of polymeric film. The liner may be formed to a desired configuration using a dissolvable mandrel or by inflation techniques and the edges of the film seamed by heat sealing. The liner may be utilized in most any type of gas storage system, and is particularly applicable ...

1998-01-01

92

Fabrication and characterization of Cu/YSZ cermet high temperature electrolysis cathode material prepared by high-energy ball-milling method  

Energy Technology Data Exchange (ETDEWEB)

Cu/YSZ cermet (40 and 60 vol.% Cu powder with balance YSZ) is a more economical cathode material than the conventional Ni/YSZ cermet for high temperature electrolysis (HTE) of water vapor and it was successfully fabricated by high-energy ball-milling of Cu and YSZ powders, pressing into pellets (o 13 mm x 2 mm) and subsequent sintering process at 700 deg. C under flowing 5%-H{sub 2}/Ar gas. The Cu/YSZ composite material thus fabricated was characterized using various analytical tools such as XRD, SEM, and laser diffraction and scattering method. Electrical conductivity of sintered Cu/YSZ cermet pellets thus fabricated was measured by using 4-probe technique for comparison with that of conventional Ni/YSZ cermets. The effect of composite composition on the electrical conductivity was investigated and a marked increase in electrical conductivity for copper contents greater than 40 vol.% in the ...

2009-01-07

93

Water management studies in PEM fuel cells, Part I: Fuel cell design and in situ water distributions  

Energy Technology Data Exchange (ETDEWEB)

A proton exchange membrane fuel cell (PEMFC) must maintain a balance between the hydration level required for efficient proton transfer and excess liquid water that can impede the flow of gases to the electrodes where the reactions take place. Therefore, it is critically important to understand the two-phase flow of liquid water combined with either the hydrogen (anode) or air (cathode) streams. In this paper, we describe the design of an in situ test apparatus that enables investigation of two-phase channel flow within PEMFCs, including the flow of water from the porous gas diffusion layer (GDL) into the channel gas flows; the flow of water within the bipolar plate channels themselves; and the dynamics of flow through multiple channels connected to common manifolds which maintain a uniform pressure differential across all possible flow paths. These two-phase flow effects have been studied at relatively low operating temperatures under ...

2009-05-15

94

The photophoretic sweeping of dust in transient protoplanetary disks  

CERN Document Server

Protoplanetary disks start their lives with a dust free inner region where the temperatures are higher than the sublimation temperature of solids. As the star illuminates the innermost particles, which are immersed in gas at the sublimation edge, these particles are subject to a photophoretic force. We examine the motion of dust particles at the inner edge of protoplanetary disks due to photophoretic drag. We find that, in a laminar disk, photophoretic drag increases the size of the inner hole after accretion onto the central body has become subdued. This region within the hole becomes an optically transparent zone containing gas and large dusty particles (>>10 cm), but devoid of, or strongly depleted in, smaller dust aggregates. Photophoresis can clear the inner disk of dust out to 10 AU in less than 1 Myr. At late times, the edge reaches a stable equilibrium between inward drift and photophoretic outward drift, at a distance of some ...

2006-01-01

95

Performance characteristics of a natural circulation cooling/latent heat storage system  

Energy Technology Data Exchange (ETDEWEB)

A cooling system was developed which could be used even in such areas where the maximum and minimum temperatures of a day might differ widely. The system features in that a latent heat storage unit is connected to the natural circulation cooling unit consisting of 2 heat exchangers where condensed gas (refrigerant) which performs gas-liquid change has been sealed, enabling to cool objects night and day without the requirement for any power source. Electronic equipment was installed in an insulated shelter. Lauric acid and refrigerant R-22 were used as the latent heat storage medium and the heat transport medium respectively. Natural convection heat transfer performance of the outside surfaces of the condenser and the evaporator and the transient behavior of the system during the melting and solidification periods of the latent heat storage medium were tested. As a result of a 48 hour simulation experiment with load ...

1987-09-25

96

Flow regime transition criteria for upward two-phase flow in vertical tubes  

Energy Technology Data Exchange (ETDEWEB)

Traditional two-phase flow-regime criteria based on the gas and liquid superficial velocities may not be suitable to the analyses of rapid transient or entrance flows by the two-fluid model. Under these conditions, it is postulated that direct geometrical parameters such as the void fraction are conceptually simpler and therefore more reliable parameters to be used in flow-regime criteria than the traditional parameters. From this point of view, new flow-regime criteria for upward gas-liquid flow in vertical tubes have been developed considering the mechanisms of flow-regime transitions. These new criteria can be compared to existing criteria and experimental data under steady-state and fully developed flow conditions by using relative velocity correlations. The criteria showed reasonable agreements with the existing data for atmospheric air-water flows. Further comparisons with data for steam-water in round tubes and a ...

1984-05-01

97

Flow regime transition criteria for upward two-phase flow in vertical tubes  

International Nuclear Information System (INIS)

Traditional two-phase flow-regime criteria based on the gas and liquid superficial velocities may not be suitable to the analyses of rapid transient or entrance flows by the two-fluid model. Under these conditions, it is postulated that direct geometrical parameters such as the void fraction are conceptually simpler and therefore more reliable parameters to be used in flow-regime criteria than the traditional parameters. From this point of view, new flow-regime criteria for upward gas-liquid flow in vertical tubes have been developed considering the mechanisms of flow-regime transitions. These new criteria can be compared to existing criteria and experimental data under steady-state and fully developed flow conditions by using relative velocity correlations. The criteria showed reasonable agreements with the existing data for atmospheric air-water flows. Further comparisons with data for steam-water in round tubes and a ...

1984-01-01

98

Feed-forward compensation for transient beam loading of the 805 MHz debuncher for the Fermilab linac upgrade  

CERN Document Server

Feed-forward compensation for transient beam loading of the 805 MHz debuncher for the Fermilab linac upgrade

1990-01-01

99

Simulation of carbon dioxide absorption by sodium hydroxide solution in a packed bed and studying the effect of operating parameters on absorption  

International Nuclear Information System (INIS)

Available in abstract form only. Full text of publication follows: In this study. simulation of carbon dioxide absorption by Sodium Hydroxide solution in a packed bed has been investigated. At first, mass and energy balances were applied around a differential height of the bed. So, the governing equations were obtained. Surface renewal theory by Danckwerts was used to represent the mass transfer operation Finally, by changing the operating parameters like solvent temperature, inlet gas composition pressure and height of the bed, the effect of these parameters on the absorption and the composition of carbon dioxide in exit stream have been investigated. (authors)

2007-09-02

100

Novel Processing of Unique Ceramic-Based Nuclear Materials and Fuels  

Energy Technology Data Exchange (ETDEWEB)

Advances in nuclear reactor technology and the use of gas-cooled fast reactors require the development of new materials that can operate at the higher temperatures expected in these systems. These include refractory alloys base on Nb, Zr, Ta, Mo, W, and Re; ceramics and composites such as those based on silicon carbide (SiCf-SiC); carbon-carbon composites; and advanced coatings. Besides the ability to handle higher expected temperatures, effective heat transfer between reactor componets is necessary for improved efficiency. Improving thermal conductivity of the materials used in nuclear fuels and other temperature critical components can lower the center-line fuel temperature and thereby enhance durability and reduce the risk of premature failure.

2008-11-30

101

Low temperature surface modifications of polyacrylonitrile ultrafiltration membranes: 1. Plasma treatment effects  

Energy Technology Data Exchange (ETDEWEB)

Excitation of low temperature helium or helium/water plasma and subsequent exposure to air of polyacrylonitrile (PAN) ultrafiltration membranes was used to hydrophilize the surface of these materials. We analyzed the effectiveness of this approach as a function of plasma operating variables including gas phase composition, plasma power, treatment time and system pressure. Following the changes in physical and chemical composition of the PAN surface resulting from these modifications was a major aspect of this work. Techniques such as the captive bubble contact angle method, ellipsometry, ESCA, and FTIR-ATR were all used. In addition, the formation and life-time of peroxides during these processes were determined. At low powers (<25W) and short treatment periods ({<=}30 sec), the main chemical conversion of PAN surfaces was simultaneous hydrophilization and stabilization via PAN cyclization. Relatively small water ...

1995-12-01

102

Kinetic behavior of solid particle in chemical-looping combustion: suppressing carbon deposition in reduction  

Energy Technology Data Exchange (ETDEWEB)

In order to apply chemical-looping combustion to a practical power plant, carbon deposition on the solid particle is one of the key problems to be overcome. Six kinds of solid particles were examined to clarify the kinetic behavior of carbon deposition. The effects of the solid composition, feed gas composition, and reaction temperature on carbon deposition were investigated by thermogravimetrical reactor on the basis of NiO/YSZ particle. From the viewpoints of both reactivity and resistance against carbon deposition, the particle of NiO mixed with YSZ (i.e., yttria-stabilized zirconia) was found to be a good candidate for chemical-looping combustion. It has been observed that carbon deposition could be completely avoided with very low concentration of water vapor. By means of a proposed model, the condition that carbon deposition would be avoided was identified. 12 refs., 8 figs., 2 tabs.

1998-03-01

103

Electrochemical and gas phase parameters of cathodes for intermediate temperature solid oxide fuel cells  

International Nuclear Information System (INIS)

A series of cyclic voltammetry, chronoamperometry and electrochemical impedance experiments have been carried out in order to investigate the effect of cathode composition and porosity on the electrochemical characteristics of strontium-doped lanthanum, praseodymium and gadolinium cobaltite cathodes. The impedance responses at different electrode potentials of the half cell and symmetric single cell setups are compared and analyzed by the equivalent circuit modeling method. The deconvolution of impedance spectra for single cell cathode and anode reactions contributions based on the results of simultaneous analysis of half cells and symmetric single cells has been made by differential impedance real part vs. ac frequency plot analysis method. Noticeable influence of cathode chemical composition, meso-porosity and macro-porosity on the electrochemical activity of the oxygen electroreduction has been demonstrated. Seeming activation energy values ...

2010-11-01

104

Surface modification of PTFE sheet by synchrotron radiation in the soft X-ray region  

International Nuclear Information System (INIS)

Full text: The surface properties of poly (tetrafluoroethylene) (PTFE) are changed by the exposure to synchrotron radiation (SR). We succeeded in controlling the wettability of the PTFE surface from hydrophobic to hydrophilic by varying the substrate temperature during the SR irradiation and found that the wettability was ascribable to microstructure and chemical composition of surface.In these previous works, oxygen atoms were found to inhabit on the hydrophobic surface of PTFE. In this study, we investigated the surface modification of PTFE from the SR exposure experiment under the O_2 gas atmosphere. The SR exposure to the PTFE sheet was carried out at beamline 6 (BL6) of the New- SUBARU. The PTFE sheet was irradiated to the white beam, ranging 50-1000 eV at BL6 at room temperature. The gas cell was mounted at the irradiation chamber. The O_2 gas pressure in the gas cell can be ...

2004-07-19

105

The effect of H_2S on molten carbonate fuel cells  

International Nuclear Information System (INIS)

Although molten carbonate fuel cells (MCFC) have been under development since the late 1950s, the operating characteristics with gases derived from coal containing a wide range of elements other than C, H, and O were not studied until the Energy Conversion Alternative Study (ECAS) was completed in the late 1970s. Since then, the work of each contractor (United Technologies, Institute of Gas Technology, General Electric, and Energy Research Corporation) has included some contaminant studies (primarily of sulfur compounds). The majority of the reported work appears to have been conducted by UTC and IGT. The results indicate that the MCFC requires removal of sulfur to ppm levels. However, because of the strong dependence on temperature, pressure, gas composition, gas utilization, cell components, and system operation (i.e. recycle, venting, gas cleanup), the tolerance limits can vary ...

106

Reaction kinetics of fluidized bed gasification of Jordanian oil shales  

Energy Technology Data Exchange (ETDEWEB)

Trying to achieve the optimal utilization of oil shale resources, and the production of a more environmentally acceptable fuel, as well as a solid waste with a low a sulphur content, thereby reducing acidic leachates, has led to this investigation. In this article, the influences of the bed temperature and the choice of fluidizing gas on the quality and quantity of the produced fuel gas, using a continuous feed fluidized bed reactor, were investigated. The composition and calorific value of the generated gas were determined. There was a nearly linear increase in the amount of fuel gas produced as a function of temperature, reaching {approx}350 kg per 10{sup 3} kg of dry raw shale and the gross calorific value ranged from 15 to 23 MJ-kg{sup -1} with CO and H{sub 2} being the major constituents. Subsequent experiments were carried out, employing a thermogravimetric analyser under ...

2000-02-01

107

Gasification of lignocellulosic biomass in fluidized beds for renewable energy development: A review  

Energy Technology Data Exchange (ETDEWEB)

A literature review on gasification of lignocellulosic biomass in various types of fluidized bed gasifiers is presented. The effect of several process parameters such as catalytic bed material, bed temperature and gasifying agent on the performance of the gasifier and quality of the producer gas is discussed. Based on the priorities of researchers, the optimum values of various desired outputs in the gasification process including improved producer gas composition, enhanced LHV, less tar and char content, high gas yield and enhanced carbon conversion and cold gas efficiency have been reported. The characteristics and performance of different fluidized bed gasifiers were assessed and the obtained results from the literature have been extensively reviewed. Survey of literature revealed that several industrial biomass gasification plants using fluidized beds are currently conducting in ...

2010-12-15

108

Effect of parameters on performance of LNG-FPSO offloading system in offshore associated gas fields  

Energy Technology Data Exchange (ETDEWEB)

Due to the advantages of the flexibility and economics in exploration and production of offshore liquefied natural gas (LNG), the floating production storage and offloading unit for liquefied natural gas (LNG-FPSO) has attracted wide attentions in recent years. The offloading system for LNG transportation from LNG-FPSO to LNG carrier is one of the most important parts in LNG-FPSO. The influences of the main parameters such as the mass flow rate and the height difference of the pipeline. on the performance of LNG offloading in offshore associated gas fields were investigated. A model based on a typical offshore LNG offloading system was first established and simulations were conducted. The governing equations were then used to evaluate the effects of parameters together with the simulation results. It was found that there was an economic mass flow rate for practical design on balance of the cost in pump head and BOG. The ...

2010-11-15

109

Lithofacial characteristics and geological structure of the Mesozoic to Cenozoic sediments of the Zapadno Rakushechniy Sea site  

Energy Technology Data Exchange (ETDEWEB)

Seismic exploration is used to identify the Zapadno Rakushechniy Sea uplift. It is promising with respect to prospecting for oil and gas deposits as a result of its proximity to the Severo Rakushechniy deposit with commercial oil and gas presence in the Triassic sediments. Structural prospecting wells are drilled at the Zapadno Rakushechnyy Sea site which open sediment from the Neogene to the upper Triassic. The Triassic sediments are represented by a thick terrigeneous to carbonate series washed out to a varying degree and covered by Jurassic sediments. A comparison of the lithofacial composition of the Triassic sediments shows that the thickness and lithological composition o the Triassic rocks varies by site, while the sediments of the upper Triassic are sharply reduced in thickness to the southsouthwest. The older are the sediments of the Indskiy stage of the lower Triassic. The isolated stages of ...

1984-01-01

110

Chemical evolution of formation waters in the Palm Valley gas field, Northern Territory  

International Nuclear Information System (INIS)

The chemical composition and evolution of formation waters associated with gas production in the Palm Valley field, Northern Territory, has important implications for reservoir management, saline water disposal, and gas reserve calculations. Historically, the occurrence of saline formation water in gas fields has been the subject of considerable debate. A better understanding of the origin, chemical evolution and movement of the formation water at Palm Valley has important implications for future reservoir management, disposal of highly saline water and accurate gas reserves estimation. Major and trace element abundance data suggest that a significant component of the highly saline water from Palm Valley has characteristics that may have been derived from a modified evaporated seawater source such as an evaporite horizon. The most dilute waters probably represent condensate and the ...

111

Thermoelectrically cooled water trap  

Energy Technology Data Exchange (ETDEWEB)

A water trap system based on a thermoelectric cooling device is employed to remove a major fraction of the water from air samples, prior to analysis of these samples for chemical composition, by a variety of analytical techniques where water vapor interferes with the measurement process. These analytical techniques include infrared spectroscopy, mass spectrometry, ion mobility spectrometry and gas chromatography. The thermoelectric system for trapping water present in air samples can substantially improve detection sensitivity in these analytical techniques when it is necessary to measure trace analytes with concentrations in the ppm (parts per million) or ppb (parts per billion) partial pressure range. The thermoelectric trap design is compact and amenable to use in a portable gas monitoring instrumentation.

2006-02-21

112

The compatibility of alloy 800 in HTR atmospheres  

International Nuclear Information System (INIS)

A thermodynamic analysis of the behaviour of Alloy 800 in helium based atmospheres relevant to the High Temperature Gas Cooled Reactor indicates that, depending upon the precise gas composition, oxidation and carburisation, or carburisation alone may be expected. The prime influence appears to be the moisture level. The morphology and structure of the reaction products are discussed. It is shown that the 'reactive' elements chromium, manganese, titanium and silicon are concentrated in the oxide scale which is normally duplex in structure. Aluminium oxide is formed at grain boundaries and in an internal oxidation zone together with titanium and sometimes silicon. In carburising conditions, mixed titanium-chromium carbides are formed. When this occurs, intergranular penetration is maximised. Weight gain data are assessed and briefly described and a tentative model for the mechanism of corrosion of Alloy 800 in HTR helium is ...

113

Oil-oil and oil-source rock correlations in the Alpine Foreland Basin of Austria: Insights from biomarker and stable carbon isotope studies  

British Library Electronic Table of Contents (United Kingdom)

The Alpine Foreland Basin is a minor oil and moderate gas province in central Europe. In the Austrian part of the Alpine Foreland Basin, oil and minor thermal gas are thought to be predominantly sourced from Lower Oligocene horizons (Schoneck and Eggerding formations). The source rocks are immature where the oil fields are located and enter the oil window at ca. 4 km depth beneath the Alpine nappes indicating long-distance lateral migration. Most important reservoirs are Upper Cretaceous and Eocene basal sandstones.Stable carbon isotope and biomarker ratios of oils from different reservoirs indicate compositional trends in W-E direction which reflect differences in source, depositional environment (facies), and maturity of potential source rocks. Thermal maturity parameters from oils of di...

2011-01-01

114

Insights gained from studies of gas pipeline rights-of-way of varying ages through wetlands  

Energy Technology Data Exchange (ETDEWEB)

Impacts of gas pipeline rights-of-way (ROWs) through wetlands depend on types of habitat, construction techniques, final elevations, ROW maintenance practices, soil composition, and local climate. In some instances factors unrelated to the presence of the pipeline may have greater impacts on wetland modification than does the pipeline itself. At one site, the required seeding program inhibited natural reestablishment of wetland plants; at another, downstream construction resulted in a major disruption to the adjacent wetland habitat. This paper discusses observation from 13 study sites, each zero to 30 years old, that are located in seven Eastern States.

1993-10-01

115

Degradation of gas turbine coatings and life assessment  

Energy Technology Data Exchange (ETDEWEB)

MCrAlY coatings are widely used on hot section components of gas turbines to provide hot corrosion and/or oxidation protection by formation of an oxide layer on the surface. As the protective oxide scale exfoliates during service, aluminum from the coating diffuses outward for reformation of the protective scale. Aluminum may also diffuse inward due to the differences in composition between the coating and the substrate. Thus, the coatings degrade due to oxidation, oxide scale spallation, and inward and outward diffusion of aluminum. Service life of these coatings is controlled by the aluminum content in the coating, operating temperature and start- shutdown cycles. In-service degradation of CoCrAlY and CoNiCrAlY coatings is presented. A procedure to predict the remaining service life of coatings under oxidizing conditions is discussed. (orig.) 12 refs.

1998-12-31

116

A method for determining the origin of bitumoids  

Energy Technology Data Exchange (ETDEWEB)

The invention is associated with organic geochemistry and may be used in conducting geological exploration operations for oil and gas. The purpose of the invention is to increase the precision of the method for determining the genesis of bitumoids. This is achieved through determining the isotopic composition of nickel or vanadium and from the anomalously high values of the isotopic ratio of Ni-58 to Ni-62 or from the anomalously low values of the isotopic ratio of vanadium, a conclusion is drawn about the epigenetic nature of the bitumoids. The proposed method is characterized by greater resolution due to the fact that the values of the isotopic ratios for oil bearing and water bearing structures are essentially not superimposed. The proposed method exceeds the resolution of metal metering studies in conducting geological exploration for oil and gas by 2 to 3 times.

1983-01-01

117

MRI of normal fetal brain development  

International Nuclear Information System (INIS)

Normal fetal brain maturation can be studied by in vivo magnetic resonance imaging (MRI) from the 18th gestational week (GW) to term, and relies primarily on T2-weighted and diffusion-weighted (DW) sequences. These maturational changes must be interpreted with a knowledge of the histological background and the temporal course of the respective developmental steps. In addition, MR presentation of developing and transient structures must be considered. Signal changes associated with maturational processes can mainly be ascribed to the following changes in tissue composition and organization, which occur at the histological level: (1) a decrease in water content and increasing cell-density can be recognized as a shortening of T1- and T2-relaxation times, leading to increased T1-weighted and decreased T2-weighted intensity, respectively; (2) the arrangement of microanatomical structures to create a symmetrical or asymmetrical environment, leading ...

2006-02-01

118

Emission characterization of an alcohol/diesel-pilot fueled compression-ignition engine and its heavy-duty diesel counterpart. Final report, August 1980-August 1981  

Energy Technology Data Exchange (ETDEWEB)

This report describes results from emissions testing of a prototype diesel engine, developed by Volvo Truck Corporation of Sweden, which uses pilot injection of diesel fuel for compression ignition of alcohol fuel injection for main combustion. In addition to this dual-fuel engine, emission testing was also conducted on a heavy-duty diesel engine of similar design. Both engines were tested over the 1979 13-mode FTP, or shorter versions of this modal test, and over the 1984 Transient FTP as well as an experimental bus cycle. The dual-fuel engine was characterized with methanol, ethanol and ethanol with 30 percent water (wt %). An oxidation catalyst was also used with methanol and ethanol. Emission characterization included regulated emissions (HC, CO, and NOX) along with total particulate, unburned alcohols, individual hydrocarbons, aldehydes, phenols, and odor. The particulate matter was characterized in terms of particle size distribution, sulfate content, C, H, ...

1981-08-01

119

Synthesis of nanoporous carbon as a gas adsorbent by reverse replication process of silica template  

Energy Technology Data Exchange (ETDEWEB)

Porous carbon with high surface area and pore volume was prepared by a reverse replication process and its toluene equilibrium adsorption behavior was investigated. The preparation process of the porous carbon was composed of following sub-processes in series: synthesis and template preparation of silica gel, impregnation and polymerization of DVB monomer in silica template, carbonization of DVB polymer in a silica-polymer composite, and HF-assisted selective etching of silica in carbon-silica composite, The prepared porous carbon was nano porous and had ultrahigh specific surface area (2007 m{sup 2}/g) and large pore volume (3.07cm{sup 3}/g). The nanoporous carbon showed rapid toluene adsorption rate and good toluene adsorption capacity, compared with a commercial Y-type zeolite, In the present study, a reverse replication process to prepare nanoporous carbons will be introduced and its application potential as a gas ...

2003-06-01

120

3-D CFD MODEL OF A MULTI-CELL HIGH TEMPERATURE ELECTROLYSIS STACK  

Energy Technology Data Exchange (ETDEWEB)

A three-dimensional computational fluid dynamics (CFD) electrochemical model has been created to model high-temperature electrolysis stack performance and steam electrolysis in the Idaho National Laboratory (INL) Integrated Lab Scale (ILS) experiment. The model is made of 60 planar cells stacked on top of each other operated as Solid Oxide Electrolysis Cells (SOEC). Details of the model geometry are specific to a stack that was fabricated by Ceramatec, Inc. and tested at INL. Inlet and outlet plenum flow and distribution are considered. Mass, momentum, energy, and species conservation and transport are provided via the core features of the commercial CFD code FLUENT. A solid-oxide fuel cell (SOFC) model adds the electrochemical reactions and loss mechanisms and computation of the electric field throughout the cell. The FLUENT SOFC user defined subroutine was modified for this work to allow for operation in the SOEC mode. Model results provide detailed profiles of temperature, Nernst ...

2009-05-01

121

Thermodynamic Model of Aluminum Combustion in SDF Explosions  

Energy Technology Data Exchange (ETDEWEB)

Thermodynamic states encountered during combustion of Aluminum powder in Shock-Dispersed-Fuel (SDF) explosions were analyzed with the Cheetah code. Results are displayed in the Le Chatelier diagram: the locus of states of specific internal energy versus temperature. Accuracy of the results was confirmed by comparing the fuel and products curves with the heats of detonation and combustion, and species composition as measured in bomb calorimeter experiments. Results were fit with analytic functions u = f(T) suitable for specifying the thermodynamic properties required for gas-dynamic models of combustion in explosions.

2006-06-19

122

Test coking of charges containing coal from the Western Donbass and the Karaganda coalfield  

Science.gov (United States)

In recent years the feedstock base of the coking plants in the South has been significantly degraded: the charges contain an increased quantity of gas coal and coal from coalfields in the East are being included. Certain plants in the Ukraine receive coal from the Kuznetsk, Pechora and Karaganda coalfields. Addition of these coal types in the charges of plants in the South is expected to continue in the future. Their efficient utilization requires careful investigation of the new charges in order to determine the optimal composition and to produce blast furnace coke meeting modern specifications.

1981-01-01

123

Hydrocarbon and mineral resources of the Uinta Basin, Utah and Colorado  

Energy Technology Data Exchange (ETDEWEB)

The Uinta Basin is an important hydrocarbon producing area, with extensive resources of hydrocarbon, bitumen, and fossil fuels. Gilsonite, tar sands, oil shale and coal are found in abundance with the cretaceous and Tertiary sedimentary rocks. The 25 papers include discussion on: leasing; thermal maturity of rocks and hydrocarbon deposits; influence of source rock type, thermal maturity and migration on composition and distribution of the natural gas; drilling; geology; structural evolution of gilsonite dykes; reclamation of coal mines; oil shale resources; and uranium mining.

1992-01-01

124

Coal slurry pH studies  

Energy Technology Data Exchange (ETDEWEB)

Coal slurry pH values can be used to characterize coals. pH values depend on the coal, time since slurry preparation, contact with gas atmosphere, particle size, and stirring. Measured values reflect a sequence of reactions including: carbon dioxide absorption by water from the air, wetting of the coal (pH may be affected by the elemental composition of the mineral matter), and further equilibration with species in the water. The pH initially drops as carbon dioxide is absorbed, then rapidly increases as the coal is wetted, and then slowly decreases as some reactions with species in the water take place.

1995-12-01

125

Hot-pressed MoSi_2-particulate-reinforced #alpha#-SiAlON composites  

International Nuclear Information System (INIS)

MoSi_2-particulate-reinforced #alpha#-SiAlON ceramic composites 10, 20, 25, and 30 vol% were prepared by at 1,750--1,800C. The #alpha#-SiAlON matrix was of the composition (Y_0_._4_8Si_1_0_._0_0Al_2_._3_0O_1_._1_7N_1_5_._2_9). The hardness for the fully dense samples changed from HV10 = 22.5 to 15.3 GPa and the toughness from 3.2 to around 5.2 MPa#centre dot#m"1"/"2 when up to 30 vol% MoSi_2 was present. Two interesting microstructural features have been found. First, with an increasing amount of MoSi_2 a pronounced coalescence of MoSi_2 particles formed a ''dual phase'' material. The second effect was the growth of elongated #alpha#-SiAlON grains in the matrix with 10 vol% MoSi_2 added. The oxidation resistance has been determined, to be unaffected by the addition of 20 vol% MoSi_2 at 1,250 C in oxygen gas of 1 atm pressure.

126

Flux pinning and critical currents in A-15 superconductors  

Science.gov (United States)

The relationship between processing, microstructure, and properties was studied for A-15 compounds in multifilamentary composites produced by solid-state diffusion and in thin-film samples produced by vapor deposition. Grain sizes of A-15 superconducting compounds were measured by transmission electron microscopy of multifilamentary composites reacted at various temperatures. Critical current densities at 4.2 K and fields up to 6 T were found to be similar for niobium-tin, vanadium-gallium, and vanadium-silicon of the same grain size. Study of the Cu-V-Si phase diagram led to the production of improved multifilamentary vanadium-silicon conductors. The effects of various alloying elements on A-15 layers produced by solid-state diffusion were studied. The most promising new observation was that tantalum can be incorporated into niobium-tin reaction layers, leading to an enhancement of critical currents at high fields. The critical temperature of ...

1978-02-01

127

Effect of chemical composition of SiOx films on rapid formation of Si nanocrystals induced by thermal plasma jet irradiation  

British Library Electronic Table of Contents (United Kingdom)

Si nanocrystal floating gate MOS capacitors were formed on p-Si (100) wafers by thermal plasma jet (TPJ) annealing of SiO2/SiOx /SiO2/Si(100) stacked structure. The chemical composition of SiOx layer was controlled by changing the SiH4, He, and O2 gas flow ratio during plasma enhanced chemical vapour deposition. The MOS capacitors showed clear hysteresis in capacitance-voltage (CV) characteristics after TPJ annealing. The hysteresis width shows maximum value when initial composition x =1.7, which shows the maximum photoluminescence (PL) intensity. The maximum hysteresis width of 6.8 V was observed with gate voltage swept between 20 and -20 V in x = 1.7 sample. The result means 7.4 x 1012 cm-2 carriers are injected to or emitted from Si nanocrystals. The duration of 1 V shift in flatband vo...

2010-01-01

128

Transient burnout in flow reduction condition  

International Nuclear Information System (INIS)

A transient flow reduction burnout experiment was conducted with water in a uniformly heated, vertically oriented tube. Test pressures ranged from 0.5 to 3.9 MPa. An analytical method was developed to obtain transient burnout conditions at the exit. A simple correlation to predict the deviation of the transient burnout mass velocity at the tube exit from the steady state mass velocity obtained as a function of steam-water density ratio and flow reduction rate. The correlation was also compared with the other data. (author).

130

Aphasia  

Science.gov (United States)

... is temporarily interrupted but quickly restored, called a transient ischemic attack. In these circumstances, language abilities may return in ...

131

Advanced distillation curve measurements for corrosive fluids: Application to two crude oils  

Energy Technology Data Exchange (ETDEWEB)

We have recently introduced several important improvements in the measurement of distillation curves for complex fluids. The modifications include a composition-explicit data channel for each distillate fraction (for both qualitative and quantitative analysis) and corrosivity assessment of each distillate fraction. The composition-explicit information is achieved with a new sampling approach that allows precise qualitative as well as quantitative analyses of each fraction, on the fly. We have applied the new method to a variety of fluids, including simple n-alkanes, rocket propellant, gasoline, jet fuels, and a hydrocarbon fluid made corrosive with dissolved hydrogen sulfide. In the current contribution, we present the application of the advanced distillation curve method to two samples of crude oil. A primary motivation behind the work is to precisely measure the distillation curves of these oils using our advanced distillation apparatus; ...

2008-10-15

132

The transient performance during acceleration in a passenger car diesel engine at the lower temperature operation  

Energy Technology Data Exchange (ETDEWEB)

Diesel passenger car is superior to gasoline engine car in the fuel economy, but it has some defects to improve: noise, startability, particulate and transient performance, etc. Among these problems, this paper presents particularly transient performance in a diesel engine and clarifies the causes of its decline at lower temperature operation. As the results, it is found that the transient torque at the early stage of acceleration is only 50% at -20/sup 0/C, and that when coolant temperature went up to 20/sup 0/C, the transient torque approaches to that of the warmed up engine. The transient response become worse with retarding the injection timing and with decreasing the engine speed. On the other hand, since the normal response is not obtained despite using high cetane number fuel, main cause of the inferior transient torque is not the poor combustion, but the ...

1985-01-01

133

Development of a method for xenon determination in the microstructure of high burn-up nuclear fuel[Dissertation 17527  

Energy Technology Data Exchange (ETDEWEB)

In nuclear fuel, in approximately one quarter of the fissions, one of the two formed fission products is gaseous. These are mainly the noble gases xenon and krypton with isotopes of xenon contributing up to 90% of the product gases. These noble fission gases do not combine with other species, and have a low solubility in the normally used uranium oxide matrix. They can be dissolved in the fuel matrix or precipitate in nanometer-sized bubbles within the fuel grain, in micrometer-sized bubbles at the grain boundaries, and a fraction also precipitates in fuel pores, coming from fuel fabrication. A fraction of the gas can also be released into the plenum of the fuel rod. With increasing fission, and therefore burn-up, the ceramic fuel material experiences a transformation of its structure in the 'cooler' rim region of the fuel. A subdivision occurs of the original fuel grains of few microns size into thousands of small grains of sub-micron sizes. ...

2008-07-01

134

The impact of wet flue gas desulfurization scrubbing on mercury emissions from coal-fired power stations.  

Science.gov (United States)

This article introduces a predictive capability for Hg retention in any Ca-based wet flue gas desulfurization (FGD) scrubber, given mercury (Hg) speciation at the FGD inlet, the flue gas composition, and the sulphur dioxide (SO2) capture efficiency. A preliminary statistical analysis of data from 17 full-scale wet FGDs connects flue gas compositions, the extents of Hg oxidation at FGD inlets, and Hg retention efficiencies. These connections clearly signal that solution chemistry within the FGD determines Hg retention. A more thorough analysis based on thermochemical equilibrium yields highly accurate predictions for total Hg retention with no parameter adjustments. For the most reliable data, the predictions were within measurement uncertainties for both limestone and Mg/lime systems operating in both forced and natural oxidation mode. With the U.S. Environmental Protection Agency's ...

2005-07-01

135

Preparation, characterization and electrical properties of SnO{sub 2} based liquid petroleum gas sensor  

Energy Technology Data Exchange (ETDEWEB)

The present investigation deals with the fabrication of liquid petroleum gas (LPG) sensor based on semiconducting oxide SnO{sub 2}. The gas sensor elements have been prepared by conventional solid state route. Addition of noble metal sensitizer, palladium and grain growth inhibitor, aluminum silicate to the base material SnO{sub 2}, not only improved the sensitivity towards LPG but also the selectivity in the presence of CO and CH{sub 4} gases. Out of various sensor compositions, SnO{sub 2}:Al{sub 2}Si{sub 2}O{sub 7} (35 wt.%):Pd (1.5 wt.%) sintered at 800 C for 5 h has shown high sensitivity (0.97) towards LPG at an operating temperature of 350 C. Different characterization techniques have been employed, such as differential thermal analysis (DTA), surface area analyzer, X-ray diffraction (XRD), to study the formation of SnO{sub 2}, surface area and crystallite size, respectively. The results suggested the possibility of ...

1999-03-25

136

Oxygen carriers for chemical looping combustion of solid fuels  

Energy Technology Data Exchange (ETDEWEB)

A thermal analyzer-differential scanning calorimeter-mass spectrometer (TG-DSC-MS) was used to study oxygen carriers (OC) for their potential use for the application of chemical looping combustion (CLC) to solid fuels. Reaction rates, changes in reaction rates with repeated oxidation-reductions, exothermic heats during oxidation, and the effect of changing reduction gas compositions were studied. Oxidation rates were greater than reduction rates and reaction rates were reproducible through multiple oxidation-reduction cycles except where agglomeration occurred with powders. Iron oxide (Fe{sub 2}O{sub 3} powder) and iron-based catalysts were found suitable for CLC of solid fuels having rapid reduction rates which increased with higher reducing gas concentrations. Fe{sub 2}O{sub 3} powder was used to oxidize a high carbon coal char in an inert gas removing 88% of the carbon from the char. Other properties ...

2009-05-15

137

GAS EVOLUTION FROM INSULATING MATERIALS FOR SUPERCONDUCTING COIL OF ITER BY GAMMA RAY IRRADIATION AT LIQUID NITROGEN TEMPERATURE  

International Nuclear Information System (INIS)

A laminated material composed of glass cloth/polyimide film/epoxy resin will be used as an insulating material for superconducting coil of International Thermonuclear Experimental Reactor (ITER). In order to keep safe and stable operation of the superconducting coil system, it is indispensable to evaluate radiation resistance of the material, because the material is exposed to severe environments such as high radiation field and low temperature of 4 K. Especially, it is important to estimate the amount of gases evolved from the insulating material by irradiation, because the gases affect on the purifying system of liquid helium in the superconducting coil system. In this work, the gas evolution from the laminated material by gamma ray irradiation at liquid nitrogen temperature (77 K) was investigated, and the difference of gas evolution behavior due to difference of composition in the epoxy resin was discussed. It was found ...

2008-03-03

138

Direct combustion of olive cake using fluidized bed combustor  

Energy Technology Data Exchange (ETDEWEB)

A fluidized bed combustor of 0.146 m diameter and 1 m length was fabricated from stainless steel to burn olive cake. Initially, and in order to obtain fluidization, the system was operated under cold conditions using a sand with particle size in the range of 500 to 710 microns. The continuous combustion experiments were carried out under controlled conditions, such that the effects of bed temperature, olive cake feed rate, fluidization velocity, and particle size on combustion efficiency and flue gas composition were investigated. It was found that the combustion efficiency decreases with the bed temperature, fluidization velocity, and the feed rate, while it increases with the particle size used. Further, the gas products analysis carried out using a gas chromatography analyzer have shown a nonmeasured amount of SO2, and small amounts of CO. Finally, the temperature distribution along the bed indicated ...

1999-04-15

139

Char particle fragmentation and its effect on unburned carbon during pulverized coal combustion. Quarterly report, October 1, 1993--December 31, 1993  

Energy Technology Data Exchange (ETDEWEB)

The information reported is for the period October I to December 31, 1993. During this quarter, activities were undertaken in Task 2. Oxygen concentrations were measured in the post-flame region of the entrained flow reactor. The sampling probe was used for the hot gas tests to sample the gas stream. Samples were injected into a gas chromatograph to determine the oxygen concentration. Results agreed with thermoequilibrium calculations that yield equilibrium compositions based on the stoichiometry of the feed gases. The axial temperature distribution along the reactor centerline was measured using a silica-coated platinum-rhodium thermocouple. Two coating techniques were tested and it was found that flame-plating silica to the thermocouple wires produced a thinner coating than a ceramic adhesive technique and therefore a smaller radiation correction. Other activities this quarter included the fabrication ...

1994-02-01

140

NATURAL GAS VARIABILITY IN CALIFORNIA: ENVIRONMENTAL IMPACTS AND DEVICE PERFORMANCE EXPERIMENTAL EVALUATION OF POLLUTANT EMISSIONS FROM RESIDENTIAL APPLIANCES  

Science.gov (United States)

The effect of liquefied natural gas on pollutant emissions was evaluated experimentally with used and new appliances in the laboratory and with appliances installed in residences, targeting information gaps from previous studies. Burner selection targeted available technologies that are projected to comprise the majority of installed appliances over the next decade. Experiments were conducted on 13 cooktop sets, 12 ovens, 5 broiler burners, 5 storage water heaters, 4 forced air furnaces, 1 wall furnace, and 6 tankless water heaters. Air-free concentrations and fuel-based emission factors were determined for carbon monoxide, nitrogen oxides, nitrogen dioxide, and the number of (predominantly ultrafine) particles over complete burns?including transient effects (device warm-up and intermittent firing of burners) following ignition--and during more stable end-of-burn conditions. Formaldehyde was measured over multi-burn cycles. The baseline fuel ...

2009-12-01

141

Analysis of enclosed sodium pool fire scenario in sodium fire experimental facility  

International Nuclear Information System (INIS)

Liquid sodium is used as coolant in Fast Breeder Reactors (FBR). There is a likelyhood of sodium spillage in ambient air in the Steam Generator Building (SGB) of the FBR plant. Due to high chemical reactivity with oxygen, especially at temperatures greater than 573 K, it catches fire very easily. In order to carryout safety related experimental studies for different modes of sodium fires and to develop suitable mathematical models for the assessment of their consequences, an experimental facility (SFEF, Sodium Fire Experimental Facility) is being setup a IGCAR, Kalpakkam. The SFEF is having a 540 m"3 volume experimental hall. Stainless steel linear will be provided on the inside surfaces of experimental hall walls, ceiling and floor. Analysis has been carried out for enclosed sodium pool fire scenarios in SFEF by using sodium pool fire code SOFIRE II, which estimates the thermal transients like pressure rise, gas temperature rise, cell wall ...

2007-04-22

142

Phenol by direct hydroxylation of benzene with nitrous oxide - role of surface oxygen species in the reaction pathways  

Energy Technology Data Exchange (ETDEWEB)

Transient experiments in a Temporal Analysis of Products (TAP) Reactor were performed to elucidate the role of surface oyxgen species in the oxidation of benzene to phenol on ZSM-5 type zeolites with nitrous oxide as a selective oxidant. It was shown by puls experiments with nitrous oxide that the mean lifetime of the generated surface oxygen species is between 0.2s at 500 C and about 4.2 s at 400 C. Afterwards the surface oxygen species desorb as molecular oxygen into the gas phase where total oxidation will take place if hydrocarbons are present. Dual puls experiments consisting of a nitrous oxide puls followed by a benzene puls allowed studying the reactivity of the surface oxygen species formed during the first puls. The observation of the phenol formation was impeded due to the strong sorption of phenol. Multipulse experiments were necessary to reach a pseudo steady state phenol yield. (orig.)

1998-12-31

143

PANDA passive decay heat removal transient test results  

International Nuclear Information System (INIS)

PANDA is a large scale facility for investigating the long-term decay heat removal from the containment of a next generation of 'passive' Advanced Light Water Reactors (ALWR). PANDA was used to examine the long-term LOCA response of the Passive Containment Cooling System (PCCS) for the General Electric (GE) Simplified Boiling Water Reactor (SBWR). The first PANDA test series had the dual objectives of demonstrating the performance of the SBWR PCCS and extending the data base available for containment analysis code qualification. The test objectives also include the study of the effects of mixing and stratification of steam and noncondensible gases in the drywell (DW) and in the suppression chamber or wetwell (WW). Ten tests were conducted in the course of the PANDA SBWR Program. The tests demonstrated a favorable and robust overall PCCS performance under different conditions. The present paper focuses on the main phenomena observed during the tests with respect to PCCS operation and DW ...

144

Natural circulation cooling in US Pressurized Water Reactors  

International Nuclear Information System (INIS)

This document is a synthesis of data and analysis concerning natural circulation cooling in US Pressurized Water Reactors during off-normal operation and accident transients. Its objective is the integration of important research findings concerning PWR natural circulation phenomena into a single reference document. Sources of information include the Nuclear Regulatory Commission, reactor vendors, utility sponsored research groups, utilities, national laboratories, research reports, meeting papers, archival literature, and foreign sources. Three modes of natural circulation are discussed: single-phase, two-phase, and reflux/boiling condensation. General characteristics, analytical expressions, noncondensible gas effects, secondary effects, and nonuniform flow are described with regard to each of the natural circulation modes. Plant operational data, tests in scaled experimental facilities, and analysis with thermal hydraulic system codes have ...

145

High frequency individual cylinder estimation for control of diesel engines; Observateur cylindre a cylindre haute frequence pour le controle des moteurs diesel  

Energy Technology Data Exchange (ETDEWEB)

Increasingly stringent pollution regulations have spurred a broad interest in the reduction of engine emissions. Two strategies can be considered: after-treatment or engine emissions reduction. For Diesel engines, after-treatment has a high cost induced by the required technology and implementation issues. In this context, the Highly Premixed Combustion combustion mode (HP C) has emerged as a topic of major interest in recent years. It represents one of the most promising ways for new generation of CI engines using high Exhaust Gas Recirculation (EGR) rates. Experimentation on the test bench brought the proof of significant emission reduction. However, actual vehicle implementation implies frequent transient which fall far beyond steady state experimentation on the test bench. Several key challenges have to be addressed. With this combustion technology; accurate torque balancing at all engine modes is a requirement. Even slight unbalance ...

2006-07-01

146

0--30 keV low-energy focused ion beam system  

Energy Technology Data Exchange (ETDEWEB)

Low-energy focused ion beam (FIB) is a useful tool for shallow doping, gas-assisted etching, and other uses to minimize substrate damage in semiconductor device fabrication. The possibility to form a finely FIB of low energy under 1 keV was suggested in the investigations on the retarding mode in electron optical systems. The abilities of the simplest type of retarding mode FIB column are examined here. The optical properties are calculated for the corresponding model and some images are observed with Ga/sup +/ ion beams <0.3 ..mu..m in diameter for beam energies, 10, 5, and 1 keV, using a retarding mode one-lens FIB system. 1-keV and 100-eV Ga/sup +/ FIB was implanted to Ga/As substrate, and the defects are analyzed by deep-level transient spectroscopy. The defect concentration for 100 eV was < (1)/(5) that for 1000 keV.

1988-05-01

147

0--30 keV low-energy focused ion beam system  

International Nuclear Information System (INIS)

Low-energy focused ion beam (FIB) is a useful tool for shallow doping, gas-assisted etching, and other uses to minimize substrate damage in semiconductor device fabrication. The possibility to form a finely FIB of low energy under 1 keV was suggested in the investigations on the retarding mode in electron optical systems. The abilities of the simplest type of retarding mode FIB column are examined here. The optical properties are calculated for the corresponding model and some images are observed with Ga"+ ion beams <0.3 #mu#m in diameter for beam energies, 10, 5, and 1 keV, using a retarding mode one-lens FIB system. 1-keV and 100-eV Ga"+ FIB was implanted to Ga/As substrate, and the defects are analyzed by deep-level transient spectroscopy. The defect concentration for 100 eV was < (1)/(5) that for 1000 keV.

148

Use of coal as fuel for chemical-looping combustion with Ni-based oxygen carrier  

Energy Technology Data Exchange (ETDEWEB)

Chemical-looping combustion is an indirect combustion technology with inherent separation of the greenhouse gas CO{sub 2}. The feasibility of using NiO as an oxygen carrier during chemical-looping combustion of coal has been investigated experimentally at 800-960{degree}C in the present work. The experiments were carried out in a fluidized bed, where the steam acted as the gasification-fluidization medium. Coal gasification and the reaction of oxygen carrier with the water gas take place simultaneously in the reactor. The oxygen carrier particles exhibit high reactivity above 900{degree}C, and the dry basis concentration of CO{sub 2} in the exit gas of the reactor is nearly 95%. The flue gas composition as a function of the reactor temperature and cyclic reduction number is discussed. At 800-960{degree}C, the dry basis concentration of CO{sub 2} in the flue gas ...

2008-12-15

149

Study of the Effects of Ambient Conditions Upon the Performance of Fan Powered, Infrared, Natural Gas Burners  

Energy Technology Data Exchange (ETDEWEB)

Fourier transform infrared spectroscopy is a simple, fast, reliable and nondestructive analytical method. By using the method developed in Clark Atlanta University, consistent and reliable infrared spectral results can be obtained. An accurate radiant energy can be calculated from these infrared spectra by using a blackbody as the calibration standards. By means of the specially-designed-and-lab-made sampling inlet and the Horiba gas analyzers, the compositions of CO{sub 2}, CO, UCH, NOx and O{sub 2} etc. from the combustion exhaust gases have been on-line accurately analyzed. The commercial natural gas IR burner performed differently in the different conditions. For the methane-air combustion, at the equivalence ratio {Phi} = 1, the IR burner produced its maximum radiation efficiency, {approximately}31.4%, and the concentration of CO{sub 2} reached its maximum value, {approximately}10.7%. In the fuel-lean region, the O{sub ...

1997-03-31

150

Study of radionuclide contributing to dose rates in 540 MWe plant environment  

International Nuclear Information System (INIS)

Tarapur Atomic Power Station Unit-4 is first 540 MWe pressurized heavy water reactor in India. It achieved criticality on 06th March 2005 and then operated at full power i.e 500 MWe. Radiation workers during the normal operation and reactor shutdown are exposed to radiation field. The control of dose rates and the collective dose of the radiation workers is most important for the best performance of the reactor. Experience gained during the operation of the 220 MWe reactors has shown that the Moderator system, primary heat transport system, annulus gas system and moderator cover gas system are the main systems contributing to the dose rate and collective dose. In order to identify the radio nuclides contributing to the radiation field, study was undertaken at TAPS Unit-4. Various samples from the Moderator, primary heat transport system, annulus gas system and moderator cover gas system were collected ...

2005-11-23

152

Transient-enhanced diffusion during furnace and rapid thermal annealing of ion-implanted silicon  

Energy Technology Data Exchange (ETDEWEB)

A transient-enhanced diffusion has been observed during the furnace or rapid thermal annealing of ion-implanted silicon. We have studied this transient in detail and show that, for doses of Group V dopants sufficient to amorphize the silicon, it arises from the trapping of interstitials by dopant atoms during implantation. These are retained during solidphase-epitaxial (SPE) growth, but can be released by additional thermal processing to cause the observed transient and the formation of a band of extended defects. We have measured the enhanced diffusion coefficients and the duration of the transient for Sb-implanted Si by careful furnace annealing experiments. We obtain general expressions which predict the effects of the transient during any thermal processing based on SPE growth (furnace, CW laser, or rapid thermal annealing). We show that there is no analogous mechanism of ...

1985-08-01

153

Transient-enhanced diffusion during furnace and rapid thermal annealing of ion-implanted silicon  

International Nuclear Information System (INIS)

A transient-enhanced diffusion has been observed during the furnace or rapid thermal annealing of ion-implanted silicon. We have studied this transient in detail and show that, for doses of Group V dopants sufficient to amorphize the silicon, it arises from the trapping of interstitials by dopant atoms during implantation. These are retained during solidphase-epitaxial (SPE) growth, but can be released by additional thermal processing to cause the observed transient and the formation of a band of extended defects. We have measured the enhanced diffusion coefficients and the duration of the transient for Sb-implanted Si by careful furnace annealing experiments. We obtain general expressions which predict the effects of the transient during any thermal processing based on SPE growth (furnace, CW laser, or rapid thermal annealing). We show that there is no analogous mechanism of ...

154

Carbon Bed Mercury Emissions Control For Mixed Waste Treatment  

International Nuclear Information System (INIS)

Mercury has had various uses in nuclear fuel reprocessing and other nuclear processes, and so is often present in radioactive and mixed (both radioactive and hazardous according to the Resource Conservation and Recovery Act) wastes. Depending on regulatory requirements, the mercury in the off-gas must be controlled with sometimes very high efficiencies. Compliance to the Hazardous Waste Combustor (HWC) Maximum Achievable Control Technology (MACT) standards can require off-gas mercury removal efficiencies up to 99.999% for thermally treating some mixed waste streams. Several test programs have demonstrated this level of off-gas mercury control using fixed beds of granular sulfur-impregnated activated carbon. Other results of these tests include: (a) The depth of the mercury control mass transfer zone was less than 15-30 cm for the operating conditions of these tests, (b) MERSORB(reg_sign) carbon can sorb Hg up to 19 wt% of ...

2010-11-01

155

Exergy-based method for analyzing the composition of the electricity cost generated in gas-fired combined cycle plants  

International Nuclear Information System (INIS)

The proposed method to analyze the composition of the cost of electricity is based on the energy conversion processes and the destruction of the exergy through the several thermodynamic processes that comprise a combined cycle power plant. The method uses thermoeconomics to evaluate and allocate the cost of exergy throughout the processes, considering costs related to inputs and investment in equipment. Although the concept may be applied to any combined cycle or cogeneration plant, this work develops only the mathematical modeling for three-pressure heat recovery steam generator (HRSG) configurations and total condensation of the produced steam. It is possible to study any nx1 plant configuration (n sets of gas turbine and HRSGs associated to one steam turbine generator and condenser) with the developed model, assuming that every train operates identically and in steady state. The presented model was conceived from a complex configuration of a ...

2008-02-01

156

Advanced distillation curve measurement: Application to a bio-derived crude oil prepared from swine manure  

Energy Technology Data Exchange (ETDEWEB)

We have recently introduced several important improvements in the measurement of distillation curves for complex fluids. This new method is a significant improvement over current approaches, with features including a composition-explicit data channel for each distillate fraction (for both qualitative and quantitative analysis), trace chemical analysis of each distillate fraction, and a corrosivity assessment of each distillate fraction. In the present contribution, we present the application of the advanced distillation curve method to a bio-derived crude oil prepared from swine manure. One motivation behind the work was to precisely measure the distillation curve of the oil derived from swine manure with our advanced distillation apparatus and compare the bio-derived oil to traditional petroleum crude oils. Then, the information content of the bio-derived oil distillation was extended further with the composition-explicit data channel: ...

2008-11-15

157

Thermal release of volatile fission products from irradiated nuclear fuel  

International Nuclear Information System (INIS)

An effective procedure for removing _3H, Xe and Kr from irradiated fuels was demonstrated using Shippingport UO"2 fuel. The release characteristics of _3H, Kr, Xe, and I from irradiated nuclear fuel have been determined as a function of temperature and gaseous environment. Vacuum outgassing and a flowing gas stream have been used to vary the gaseous environment. Vacuum outgassing released about 99% of the _3H and 20% of both Kr and Xe within a 3 h at 1500_0C. Similar results were obtained using a carrier gas of He containing 6% H"2. However, a carrier gas containing only He resulted in the release of approximately 80% of the _3H and 99% of both Kr and Xe. These results indicate that the release of these volatile fission products from irradiated nuclear fuel is a function of the chemical composition of the gaseous environment. The rate of tritium release increased with increasing temperature (1100 to ...

158

Release and sorption of alkali metals in coal fired combined cycle power systems; Freisetzung und Einbindung von Alkalimetallverbindungen in kohlebefeuerten Kombikraftwerken  

Energy Technology Data Exchange (ETDEWEB)

Coal fired combined cycle power systems will be a sufficient way to increase the efficiency of coal combustion. However, combined cycle power systems require a reliable hot gas cleanup. Especially alkali metals, such as sodium and potassium, can lead to hot corrosion of the gas turbine blading if they condensate as sulphates. The actual work deals with the release and sorption of alkali metals in coal fired combined cycle power systems. The influence of coal composition, temperature and pressure on the release of alkali species in coal combustion was investigated and the relevant release mechanisms identified. Alumosilicate sorbents have been found that reduce the alkali concentration in the hot flue gas of the Circulating Pressurized Fluidized Bed Combustion 2{sup nd} Generation (CPFBC 2{sup nd} Gen.) at 750 C to values sufficient for use in a gas turbine. Accordingly, ...

2009-07-01

159

Oxydehydrogenation of propane to propylene with metal molybdates  

Energy Technology Data Exchange (ETDEWEB)

Single and binary metal molybdates of the formula AMoO{sub 4}, where A=Ni, Co, Mg,Mn and/or Zn, were investigated for the oxydehydrogenation of propane to propylene, as well as some ternary molybdates of the formula NiO{sub 0.45}Co{sub 0.45}X{sub 0.066}MoO{sub 4} where X=P, Bi, Fe, Cr, V and Ce. All catalysts were supported on SiO{sub 2} with an active phase/support ratio of 80/20 (wt%). The reaction is catalytic and not a gas phase initiated reaction. It is first order in propane, consistent with the abstraction of the methylene hydrogen being the rate limiting step. Propane conversions and propylene yields vary greatly depending on the metal of the molybdate and surface area of the catalyst. Highest propylene yields (16% at 26.6% propane conversion) are obtained with NiMoO{sub 4}/SiO{sub 2}. Conversion and yield are significantly influenced by the molybdenum content of the compositions. The effect is biggest in the nickel molybdate system. ...

1996-10-01

160

Radiation technology of wood-plastic composite materials  

International Nuclear Information System (INIS)

... radiation effects RADIATIONS. WOOD-PLASTIC COMPOSITES.

1981-10-02

161

Nano-Materials in Metal-Matrix Composites  

International Science & Technology Center (ISTC)

Metal Matrix Composites on the Basis of Nano-Materials

162

Multifunctional Composite Coating  

International Science & Technology Center (ISTC)

New Composite Multifunctional Coatings Produced Using SHS-Electrodes

163

Electrodepositing Nanostructured Composite Coatings  

International Science & Technology Center (ISTC)

Development of the Method of Electrodepositing Nanostructured Composite Coatings with Improved Engineering Properties

164

Ceramic Composite Materials  

International Science & Technology Center (ISTC)

Development of Ceramic Composite Materials and Structural Elements for High-Temperature Nuclear Reactors

165

Transient Ischemic Attack Before Nonlacunar Ischemic Stroke in the Elderly  

UK PubMed Central (United Kingdom)

Background:Several studies suggest transient ischemic attack (TIA) may be neuroprotective against ischemic stroke analogous to preinfarction angina's protection against...Full Text Available

2008-09-01

166

Thirty-five cases of transient hyperthyroidism.  

UK PubMed Central (United Kingdom)

Over a 7-year period transient hyperthyroidism was diagnosed in 35 patients seen in a consulting practice in a community hospital. The patients were followed up for an average of 15 months. Initially...Full Text Available

1984-05-01

167

Imaging of calcium transients in skeletal muscle fibers.  

UK PubMed Central (United Kingdom)

Epifluorescence images of Ca2+ transients elicited by electrical stimulation of single skeletal muscle fibers were studied with fast imaging techniques that take advantage of the large fluorescence...Full Text Available

1991-01-01

168

Synthesis and electrochemistry properties of Sn-Sb ultrafine particles as anode of lithium-ion batteries  

International Nuclear Information System (INIS)

Ultrafine particles of Sn-Sb alloys with different chemical composition have been prepared by hydrogen plasma-metal reaction. Structure, morphology, size and chemical composition of the Sn-Sb ultrafine particles were investigated by transmission electron microscopy, X-ray diffraction, BET gas adsorption, and induction-coupled plasma spectroscopy. It was found that all the particles have spherical shapes, with average particle size in the range of 100-300 nm. The electrochemistry properties as an alternative anode material for lithium-ion batteries have been characterized by constant current cycling and cyclic voltammetry. Electrochemical measurements showed that the alloys with Sn-46.5 at.% Sb have best reversible capacity and capacity retention. It exhibited a high reversible lithium-ion storage capacity of 701 mAh g"-"1 in the initial cycle, which has remained at 81% (i.e., 566 mAh g"-"1) of its original capacity after 20 ...

2007-07-31

169

Rutherford backscattering study of the oxidation of palladium silicide on amorphous silicon substrates  

International Nuclear Information System (INIS)

Marker experiments for studying the mass transport through a palladium silicide layer on a crystalline substrate during thermal oxidation at 700 to 850 deg C have been reported recently. In this work argon gas embedded in amorphous silicon during sputtering was implemented as the inert marker and the oxidation of PdSi was processed above 900 deg C. At this high-temperature oxidation silicon-rich silicide PdSisub(y), with y exceeding 5, may be obtained. This can be anticipated by considering the Pd-Si phase diagram which shows the liquid phase may appear at an annealing temperature above 892 deg C. As a result, a non-stoichiometric and non-uniform silicide layer may develop at the sample surface. Marker analysis showed that both palladium and silicon dissociated at the Pdsub(x)Si/ SiO_2 interface and moved to the substrate with the silicon being the dominant diffuser. The Rutherford backscattering spectra (RBS) showing the oxide film and ...

170

Modeling key cupola reactions: Behavior of carbon, silicon and manganese  

Energy Technology Data Exchange (ETDEWEB)

In the present study, models of key chemical processes governing the compositions of the tapped metal from the cupola on the basis of physico-chemical fundamentals have been developed. As evident from the literature survey, the investigations conducted in the past have focused their attention on one phenomenon at a time; for example, a particular chemical reaction, measurement of gas composition or the temperature distribution inside a cupola. Notwithstanding the importance of these studies and their contribution toward the understanding of cupola operation, mathematical models of key chemical processes and their interdependence must be investigated to obtain a complete insight into the various interlinked phenomena occurring inside a cupola. For example, the oxidation of the metallic charge leads to the formation of iron oxide which influences the final content of elements such as silicon, manganese and carbon. The ...

1991-01-01

171

Effect of iron catalyst on the composition of oil from coal liquefaction  

Energy Technology Data Exchange (ETDEWEB)

The effect of two iron catalysts, red mud and CGS S-G, as well as Co-Mo/Al/sub 2/O/sub 3/ and Ni-Mo/Al/sub 2/O/sub 3/ commercial catalysts on the composition of oil derived from the liquefaction of Japanese subbituminous coal have been investigated comparatively by conventional autoclave experiments at 440 and 450C under initial hydrogen pressure of 85kg/cm/sup 2/ . G with tetralin to coal weight ratio of 3. From the results obtained at 450C, total conversion and the yield of gas revealed almost same level with four catalysts, but the oil product from molybdenum catalysts showed higher yield than that from iron catalysts. CGS S-G catalyst also showed higher yield of oil product than red mud catalyst. Reaction behavior of two iron catalysts were also tested by solvent recycle mode experiments.

1987-01-01

172

Antioxidant properties of natural substances in irradiated fresh poultry  

Energy Technology Data Exchange (ETDEWEB)

This study was undertaken to determine if a combined treatment (marinating in natural plant extracts or vacuum) with irradiation could have a synergistic effect, in order to prevent the lipid oxidation resulting in the development of undesirable flavours. The fresh chicken legs were irradiated at 0,3 and 5 kGy. The fatty acids composition of lipids was identified using gas liquid chromatography. The effect of irradiation treatment combined with a pre-treatment on the fatty acids composition was followed. The day after irradiation, ten panallists were asked to evaluate, using the instruction scaling, the overall appearance, the odor, the flavor and the overall acceptability of the samples. The major fatty acids identified in lipids were oleic acid, palmitic acid, palmitoleic acid and stearic acid. Pre-treatments have a significant effect on linoleic acid (C18:2) and higher fatty acids. The unsaturated fatty acids derived ...

1998-06-01

173
174

TS-1 and TS-2 transient overpower tests on FFTF fuel  

International Nuclear Information System (INIS)

The TS-1 and TS-2 Transient Reactor Test Facility (TREAT) experiments were conducted on irradiated Fast Flux Test Facility (FFTF) fuel pins to characterize their failure behavior when subjected to hypothetical 5%/s transient overpower conditions. The TS-1 test employed a near-fresh (2 MWd/kg) fuel pin, while the TS-2 test used a medium-burnup (58 MWd/kg) fuel pin. Transient conditions were closely matched between the two experiments to provide a direct comparison of burnup effects on the failure response.

1985-11-10

175

Simulation of the transient eddy current measurement for the characterization of depth and conductivity of a plate  

International Nuclear Information System (INIS)

A transient eddy current measurement method is presented to determine the thickness and conductivity of a conductive plate. The conductive plate is induced by an air-cored coil, the magnetic flux density along the axial is measured and the various signals corresponding to plates with different thickness and conductivity are calculated using a 3D transient eddy current simulator. Characteristic features are obtained from the transient response. A similarity-based modeling method is utilized in this study to estimate the thickness and conductivity of the conductive plate. (author)

2008-07-01

176

NASTRAN nonlinear dynamic transient accident analysis for FFTF reactor component  

International Nuclear Information System (INIS)

... computer calculations fftf reactor nonlinear problems reactor accidents reactor

1976-11-14

177

NASA TECH BRIEF  

Science.gov (United States)

Magnetic Forming Studies. The use of transient high magnetic-field devices has made possible the generation of very large accurately ...

178

Geometry changes transient transport in plasmas  

Energy Technology Data Exchange (ETDEWEB)

Role of ballooning effect in toroidal plasmas on the transient transport problems is investigated. Due to the mode localization along the magnetic field line, a meso scale appears in a radial correlation length of fluctuating fields. This scale length introduces the interference of the gradient and flux in different radial locations. For the fluctuation which gives the gyro-Bohm-like diffusion in a stationary state, this long radial correlation of the fluctuating field causes a fast propagation of response against a rapid transient perturbation. Upper bound of transient thermal diffusivity is derived. (author)

2001-06-01

179

Determination of charge carrier mobility in poly(3hexylthiophene) with different current transient measurement techniques  

Energy Technology Data Exchange (ETDEWEB)

The carrier mobility in organic disordered materials, such as conjugated polymers, plays an important role in understanding the behaviour of organic electronic devices. We investigated the mobility of charge carriers in poly(3-hexylthiophene) (P3HT) using different current transient measurement methods. Besides the conventional transient photoconductivity experiment, time-of-flight (TOF), we used extraction current transient techniques, such as charge carrier extraction by linearly increasing voltage (CELIV), probing equilibrium carriers instead. The field and temperature dependence of the mobility are discussed in view of hopping transport in a Gaussian density of states distribution.

2007-07-01

180

Carotid Artery Stenting Outcomes in the Standard Risk Population for Carotid Endarterectomy  

Science.gov (United States)

Carotid Artery Disease; Stroke; Amaurosis Fugax; Transient Ischemic Attack (TIA)

2011-10-03

181

Study on bubbly flow behavior in natural circulation reactor by thermal-hydraulic simulation tests with SF6-Gas and ethanol liquid  

Science.gov (United States)

An advanced experimental technique has been developed to simulate two-phase flow behavior in a light water reactor (LWR). The technique applies three kinds of methods; (1) use of sulfur-hexafluoride (SF6) gas and ethanol (C2H5OH) liquid at atmospheric temperature and a pressure less than 1.0MPa, where the fluid properties are similar to steam-water ones in the LWR, (2) generation of bubble with a sintering tube, which simulates bubble generation on heated surface in the LWR, (3) measurement of detailed bubble distribution data with a bi-optical probe (BOP), (4) and measurement of liquid velocities with the tracer liquid. This experimental technique provides easy visualization of flows by using a large scale experimental apparatus, which gives three-dimensional flows, and measurement of detailed spatial distributions of two-phase flow. With this technique, we have carried out experiments simulating two-phase flow behavior in a single-channel geometry, a ...

2009-02-01

182

Rn3D: A finite element code for simulating gas flow and radon transport in variably saturated, nonisothermal porous media. User`s manual, Version 1.0  

Energy Technology Data Exchange (ETDEWEB)

This document is a user`s manual for the Rn3D finite element code. Rn3D was developed to simulate gas flow and radon transport in variably saturated, nonisothermal porous media. The Rn3D model is applicable to a wide range of problems involving radon transport in soil because it can simulate either steady-state or transient flow and transport in one-, two- or three-dimensions (including radially symmetric two-dimensional problems). The porous materials may be heterogeneous and anisotropic. This manual describes all pertinent mathematics related to the governing, boundary, and constitutive equations of the model, as well as the development of the finite element equations used in the code. Instructions are given for constructing Rn3D input files and executing the code, as well as a description of all output files generated by the code. Five verification problems are given that test various aspects of code operation, complete with example input ...

1994-01-01

183

Future gasoline engine concepts based on direct injection technology; Die Direkteinspritzung als Basis zukuenftiger Ottomotorkonzepte  

Energy Technology Data Exchange (ETDEWEB)

For the transformation of gasoline direct injection concepts into production solutions not only fuel economy and emission potential but also system stability and durability is important as well as the optimized interaction with exhaust gas aftertreatment and engine management. By application of optical diagnostic methods on research engines and especially in real multicylinder engines, a DI gasoline combustion system could be developed meeting all these requirements. Its fuel economy in the lower part load range is found within the scatterband of DI-Diesel engines. Special emphasis has been concentrated on the optimum adaptation of the combustion system to the limited exhaust gas temperature range of the NOx storage catalyst technology. A combination of this DI gasoline concept with turbocharging reveals a high potential especially regarding transient response. (orig.) [Deutsch] Bei der Ueberfuehrung von ...

1998-08-01

184

ELM resolved energy distribution studies in the JET MKII Gas-Box divertor using infra-red thermography  

International Nuclear Information System (INIS)

Using infra-red (IR) thermography, power loads onto the MKII Gas-Box divertor targets have been investigated in Type-I ELMy H-Mode plasmas at JET in medium current discharges (Ip = 2.6 MA and BT = 2.7 T). Heat fluxes are calculated from the measured divertor target tile surface temperatures taking into account the influence of co-deposited surface layers on tile surfaces. This is particularly important when estimating the energy deposition during transient events such as ELMs. Detailed energy balance analysis is used, both from IR and tile embedded thermocouples, to demonstrate an approximately constant ELM-averaged in/out divertor target asymmetry of ?0.55 and to show that the ELM in/out energy deposition ratio ranges from 1 : 1 to 2 : 1. The inter-ELM in/out ratio is close to the ELM-averaged value at low pedestal collisionalities and decreases down to values close to zero when the inner target plasma detaches at the highest pedestal ...

2007-05-01

185

Application of neutron radiography systems in JRR-3M to nuclear engineering  

Energy Technology Data Exchange (ETDEWEB)

Initial major applications of neutron radiography (NR) to nuclear engineering were nondestructive inspections of nuclear fuel, control rods, reactor materials and some other components. Increase in the available neutron flux over 10{sup 8} n/cm{sup 2}s at the JRR-3M thermal neutron radiography facility (TNRF) in 1991 has expanded the application field to the dynamic but clear imaging of moving objects and fluid phenomena. The JRR-3M TNRF is facilitated with three major imaging systems, being characterized by spatial and/or temporal resolutions: 1. Static neutron radiography (SNR), 2. real-time neutron radiography (RNR) with an imaging rate of 30 frames/s and 3. High-frame-rate neutron radiography (HFRNR). SNR has been used for three-dimensional visualization of air-water two-phase flows in a simulated rod bundle. Three-dimensional computed tomography clearly illustrated average void fraction distributions around tie spacers. RNR has been used for visualization and quantitative ...

1999-07-01

186

Transient enhanced diffusion and deactivation of ion-implanted As in strained Si  

International Nuclear Information System (INIS)

First results on the effects of strain on transient enhanced diffusion and deactivation of As-implanted ultrashallow junctions are presented. A significant effect of strain on the magnitude and timescale of transient enhanced diffusion is observed, which is consistent with the stabilization of interstitial-type defects by tensile strain. Our results show no significant impact of strain on As electrical activity during the deactivation timescale accessed in this study.

2005-08-01

187

Study of transient enhanced dopant diffusion in silicon and proposed limiting methods  

International Nuclear Information System (INIS)

The transient enhanced diffusion in crystalline silicon implanted with dopants ad followed by high temperature annealing to activate the dopants is introduced. The physical mechanisms of transient enhanced dopant diffusion are then reviewed together with a short introduction to the proposed suppressing methods. Finally, the perspectives with using high energy heavy ions in this field are briefly discussed

2001-09-01

188

Numerical calculation of the transient response of transmission systems using the natural spline functions, with applications on high-voltage transmission lines  

Energy Technology Data Exchange (ETDEWEB)

To determine the transient response of linear and time-invariant transmission systems which are only described for discret frequencies, it is possible to find a good functional approximation by means of the generalized impulse method, combined with the most important natural spline-interpolation functions of the first and the third degree. This procedure has been applied to calculate the step response of the transient behaviour of the zero-sequence impedance system of the high voltage transmission line.

1981-10-01

189

Improved control of fuel crushing in coal-fired power stations  

Energy Technology Data Exchange (ETDEWEB)

With the frequent load changes to which a hard coal power station is subjected in the middle and peak load range, great demands are linked with the transient behaviour of the steam generator. Due to the serial connection of the crusher and boiler, the strongly delaying transient behaviour of the crusher compounds entirely with the transient behaviour of the steam generator. Therefore, a suggestion is to be made here as to the improvement of the dynamics of the crusher.

1988-01-01

190

Estimates of Amplitudes of Transient Regimes in Quasi-Controllable Discrete Systems  

CERN Document Server

Families of regimes for discrete control systems are studied possessing a special quasi-controllability property that is similar to the Kalman controllability property. A new approach is proposed to estimate the amplitudes of transient regimes in quasi-controllable systems. Its essence is in obtaining of constructive a priori bounds for degree of overshooting in terms of the quasi-controllability measure. The results are applicable for analysis of transients, classical absolute stability problem and, especially, for stability problem for desynchronized (asynchronous, switching) systems.

2009-01-01

191

3-D numerical simulation of the transient electromagnetic pulse coupling to double cylinder object  

International Nuclear Information System (INIS)

In this paper, finite-difference time-domain method is used to research the transient electromagnetic pulse (EMP) coupling to the cylinder object which is shielded in another shielding cavity with a hole numerically. The different coupling effectiveness of three transient EMP is simulated. The distribution of the electric field in the shielding cavity and the current on the cavity are researched. The shielding effectiveness is evaluated. (authors)

2006-10-21

192

Powertrain and apparatus using a continuously variable ratio transmission to improve fuel economy  

Energy Technology Data Exchange (ETDEWEB)

An automotive powertrain includes a conventional piston engine, a continuously variable ratio transmission, an engine speed sensor and a feedback control system. The control system adjusts both the transmission ratio and the throttle valve in the engine carburetor or fuel metering system in response to the position of the accelerator pedal and in response to the crankshaft speed as measured by the engine sensor. The transmission provides extreme overdrive gear ratios which allow the engine to be operated at wide open throttle even during moderate cruising, and, in addition, the engine carburetor or fuel metering system is calibrated to deliver to the engine a stoichiometric air-fuel mixture which is combined, before combustion, with a special proportion of recirculated exhaust gas. As a result of extensive wide open throttle engine operation with the above mentioned intake charge composition, combustion variables are optimized to produce ...

1981-07-28

193

Plasma nitriding of AISI 304 steel  

International Nuclear Information System (INIS)

In the present investigation, the properties of plasma nitrided AISI 304 steel were studied by changing the presence of nitrogen in the gas mixture. The plasma nitriding was performed at temperature -560 deg C, pressure -4 mbar and duration 24 hours. The nitrided samples were characterized by evaluating the phase composition, micro hardness, and diffusion layer thickness. The phase analysis indicates the mixed phases of CrN and Fe_3N, Fe_3N and Fe_4N which has the highest intensity. The results show the glow discharge plasma nitriding in presence of N_2 (80 vol. %) and H_2 (rest) produced higher hardness as well as higher case depth. (author)

2004-09-01

194

Inferring temperature uniformity from gas composition measurements in a hydrogen combustion-heated hypersonic flow stream  

Energy Technology Data Exchange (ETDEWEB)

The application of a method for determining the temperature of an oxygen-replenished air stream heated to 2600 K by a hydrogen burner is reviewed and discussed. The purpose of the measurements is to determine the spatial uniformity of the temperature in the core flow of a ramjet test facility. The technique involves sampling the product gases at the exit of the test section nozzle to infer the makeup of the reactant gases entering the burner. Knowing also the temperature of the inlet gases and assuming the flow is at chemical equilibrium, the adiabatic flame temperature is determined using an industry accepted chemical equilibrium computer code. Local temperature depressions are estimated from heat loss calculations. A description of the method, hardware and procedures is presented, along with local heat loss estimates and uncertainty assessments. The uncertainty of the method is estimated at {+-}31 K, and the spatial uniformity was measured within {+-}35 K.

1995-08-01

195

High temperature structural silicides  

Energy Technology Data Exchange (ETDEWEB)

Structural silicides have important high temperature applications in oxidizing and aggressive environments. Most prominent are MoSi{sub 2}-based materials, which are borderline ceramic-intermetallic compounds. MoSi{sub 2} single crystals exhibit macroscopic compressive ductility at temperatures below room temperature in some orientations. Polycrystalline MoSi{sub 2} possesses elevated temperature creep behavior which is highly sensitive to grain size. MoSi{sub 2}-Si{sub 3}N{sub 4} composites show an important combination of oxidation resistance, creep resistance, and low temperature fracture toughness. Current potential applications of MoSi{sub 2}-based materials include furnace heating elements, molten metal lances, industrial gas burners, aerospace turbine engine components, diesel engine glow plugs, and materials for glass processing.

1997-03-01

196

Gasification of waste from furniture industries for generation of sustainable energy  

Energy Technology Data Exchange (ETDEWEB)

The global interest in renewable energy is attributed to the decline in fossil fuel sources and the need for technical, economic, social and environmental sustainability. This study focused on the new techniques that have been developed for the use of biomass for energy from wood wastes from the forest-based industry. As an energy source, wood waste contributes positively to the environment by reducing environmental problems related to contamination of soil, air and water through improper disposal of waste. Biomass gasification has the advantage of converting biomass into a combustible gas that can be used for heat generation, electricity and synthesis of chemicals. Syngas produced from gasification of eucalyptus residues has significant potential, with an average High Heating Value of 6.60 MJ/m{sup 3}, and regular composition during the process, with predominance of carbon monoxide, followed by hydrogen, carbon dioxide and methane.

2010-07-01

197

Fragranced consumer products: Chemicals emitted, ingredients unlisted  

British Library Electronic Table of Contents (United Kingdom)

Fragranced consumer products are pervasive in society. Relatively little is known about the composition of these products, due to lack of prior study, complexity of formulations, and limitations and protections on ingredient disclosure in the U.S. We investigated volatile organic compounds (VOCs) emitted from 25 common fragranced consumer products-laundry products, personal care products, cleaning supplies, and air fresheners-using headspace analysis with gas chromatography/mass spectrometry (GC/MS). Our analysis found 133 different VOCs emitted from the 25 products, with an average of 17 VOCs per product. Of these 133 VOCs, 24 are classified as toxic or hazardous under U.S. federal laws, and each product emitted at least one of these compounds. For ''green'' products, emissions of these c...

2011-01-01

198

Electrochemical behaviour of multicomponent Zr-Ti-V-Mn-Cr-Ni alloys in alkaline solution  

Energy Technology Data Exchange (ETDEWEB)

The effect of the composition of multicomponent Zr-Ti-V-Mn-Cr-Ni alloys on their hydrogen-storage capacity and on the rate of electrosorption/desorption hydrogen was investigated under potentiodynamics as well as single-pulse and long-term galvanostatic conditions. The main characteristics of alloys and alloy electrodes were determined by their structural analysis by means of X-ray diffraction and scanning electron microscope, by specific surface area test and by determination of the hydrogen absorption/desorption isotherms in the gas/solid phase system. It was found that only the alloys with a manganese content below a threshold could be used as electrode materials for Ni-MH batteries, whereas the modification of the electrode material by micro-encapsulation of alloy particles should limit the dissolution of manganese from the electrode material in a strong alkaline solution. (orig.)

1996-01-01

199

Tritium Release Behavior from Li_4SiO_4  

International Nuclear Information System (INIS)

This paper proposes a model to explain tritium release behavior of an irradiated Li_4SiO_4 sample made by Forschungszentrum Karlsruhe. The release curves were obtained in a series of experiments carried out using out-pile temperature programmed desorption techniques in the Kyoto University Reactor (KUR). Tritium release curves obtained for different purge gas compositions (N_2, N_2 + H_2, N_2 + H_2O) were compared for selection of suitable conditions to determine the apparent diffusivity of tritium in a crystal grain of Li_4SiO_4.In the model formation, some mass transfer steps in the bulk of the crystal grain and those on the surface of the grain were taken into account, which were diffusion of tritium in the grain, adsorption and desorption of water on the surface of the grain, two types of isotope exchange reactions, and water formation reaction by the addition of hydrogen to the purge gas.Diffusivities of tritium in the ...

2004-12-01

200

Solid-gas equilibria in CaSO/sub 3/-H/sub 2/O/sub (g)/ system and Lewis-acid-base alloys  

Energy Technology Data Exchange (ETDEWEB)

The role played by calcium sulfite in the flue gas desulfurization of lime/limestone scrubbers makes it desirable to work out its thermodynamic properties. A thermogravimetric apparatus was used to study the equilibria between calcium sulfite hemihydrate and calcium sulfite anhydrite under different conditions. Efforts were made to analyze the difficulties encountered in the dynamic approach to equilibration after calcium sulfate dihydrate failed in calibration of the apparatus. Finally, the kinetics and thermodynamics for the dissociation of calcium sulfite hemihydrate were examined. The confirmation of Engel-Brewer's correlation between the electronic configuration and crystal structure in metallic systems has long been pursued in this group by studying the Lewis-acid-base interactions. Tantalum-iridium alloys of different compositions were brought into equilibrium with various steam/hydrogen mixtures in the same thermogravimetric ...

1981-10-01

201

Sensitivity of dual fuel engine combustion and knocking limits to gaseous fuel composition  

International Nuclear Information System (INIS)

Combustion noise, knock and ignition limits data are measured and presented for a dual fuel engine running on dual fuels of Diesel and three gaseous fuels separately. The gaseous fuels used are liquefied petroleum gas, pure methane and compressed natural gas mixture. The maximum pressure rise rate during combustion is presented as a measure of combustion noise, and the knocking and ignition limits are presented as torque output at the onset of knocking and ignition failure. Experimental investigation on the dual fuel engine revealed the noise generated from combustion, knocking and ignition limits for all gases at different design and operating conditions. A Ricardo E6 Diesel version engine is converted to run on dual fuel of Diesel and the tested gaseous fuel and is used throughout the work. The engine is fully computerized, and the cylinder pressure data, crank angle data and engine operating variables are stored in a PC for off line ...

2004-02-01

202

Potentials of biofuels  

Energy Technology Data Exchange (ETDEWEB)

This paper discussed the potential of biofuels with particular reference to the situation in Germany and Europe. Emphasis was on technical potential, such as biofuel production, utilization and environmental aspects. The Institute of Agricultural Technology and Biosystems Engineering ran vTI emission tests on diesel engines to evaluate the environmental impacts of biofuels. This testing facility is able to drive heavy-duty diesel engines in both stationary and dynamic test cycles, such as the European ESC and ETC. Additional analyses were conducted to determine the fine and ultra-fine particles, polycyclic aromatic hydrocarbons (PAH), aldehydes, ketones, and the usual regulated exhaust gas compounds. Ames tests were conducted to assess the mutagenic potential of tailpipe emissions. Previous study results showed that neat vegetable oils can render the exhaust high in mutagenic potency. Some of the non-regulated exhaust gas compounds were found ...

2010-07-01

203

Potential biogas scrubbing using a high rate pond  

Energy Technology Data Exchange (ETDEWEB)

The potential to scrub biogas in a high rate pond (HRP) was evaluated using apparatus designed to maximize gas-liquid contact. Experiments compared the removal of carbon dioxide from synthetic biogas by an 'in-pond angled gutter' to that by a simulated 'counter-current pit'. Results showed that the counter current pit has potential for use in biogas scrubbing, with synthetic biogas carbon dioxide composition consistently reduced from 40% to<5%. The in-pond angled gutter was less effective due to bubble coalescence which reduced the total bubble surface surface area available for gas transfer. Measurement of oxygen levels in the scrubbed biogas showed that despite supersaturation of oxygen in the HRP water, there was little transfer to the biogas, so that explosive methane/oxygen mixtures would not be formed. Theoretical calculations indicated that the amount of biogas likely to be ...

2005-07-01

204

Mechanisms controlling the leaching kinetics of fixated flue gas desulfurization (FGD) material under neutral and acidic conditions.  

Science.gov (United States)

A number of agricultural and engineering uses for fixated flue gas desulfurization (FGD) material exist; however, the potential for leaching of hazardous elements has limited widespread application and the processes controlling the leaching of this material are poorly understood. In this study, a flow-through rotating-disk system was applied to elucidate the relative importance of bulk diffusion, pore diffusion, and surface chemical reaction in controlling the leaching of fixated FGD material under pH conditions ranging from 2.2 to 6.8. Changing the hydrodynamics in the rotating disk system did not affect the leaching kinetics at both pH 2.2 and 6.8, indicating that bulk diffusion was not the kinetic-limiting step. Application of the shrinking core model (SCM) to the data suggested a surface reaction-controlled mechanism, rather than a pore diffusion mechanism. The leaching of fixated FGD material increased with decreasing pH, suggesting it can be described by a ...

2007-05-07

205

Laboratory differential simulation design method of pressure absorbers for carbonization of phenolate solution by carbon dioxide in coal-tar processing  

Energy Technology Data Exchange (ETDEWEB)

A laboratory differential simulation method is used for the design of carbonization columns at coal-tar processing in which phenols are regenerated from phenolate solution by carbon dioxide absorption. The design method is based on integration of local absorption rates of carbon dioxide along the column. The local absorption rates into industrial phenolate mixture are measured in a laboratory model contactor for various compositions of the gas and liquid phases under the conditions that ensure the absorption rates in the laboratory absorber simulate the local rates in the industrial column. On the bases of the calculations, two-step carbonization columns were designed for 30000 t/year of the phenolate solution treatment by carbon dioxide. The absorption proceeds at higher pressure of 500 kPa and temperatures from 50 to 65 C, pure carbon dioxide is used and toluene is added. These conditions have the following favourable effects: (I) significant ...

2009-01-15

206

Hydrogen production from coal using coal direct chemical looping and syngas chemical looping combustion systems: Assessment of system operation and resource requirements  

Energy Technology Data Exchange (ETDEWEB)

Coal direct chemical looping (CDCL) substitutes the gasification process in syngas chemical looping (SCL), thus eliminating the need for higher oxygen consumption. In this study, operating conditions are assessed for CDCL and SCL, directed towards hydrogen production from coal. The main objective is to increase the overall H{sub 2}/CO{sub 2} ratio for a given amount of coal, based on the various conditions. The operating variables considered as part of a resource optimization analysis include: (i) inlet conditions to the primary reactors, (ii) minimum resource requirements (air, steam and iron oxide), (iii) hydrogen-to-component ratios, and (iv) effect of coal carrier gas. The results suggest that CDCL has a higher hydrogen-to-CO{sub 2} ratio than SCL along with advantages such as low overall resource requirements (steam and air) and fewer intermediate processes. The coal carrier gas affects the hydrogen production only in the SCL system by ...

2009-03-15

207

Eulerian approach for multiphase flow simulation in a glass melter  

Energy Technology Data Exchange (ETDEWEB)

A glass furnace, consisting of a combustion space and a glass melter, uses combustion heat to melt sand and cullet into liquid glass to make products. Glass quality is mainly dependent on the temperature, glass composition, and the level of impurities in a glass melter, which include solid batch/cullet particles, liquid glass, and gas bubbles. A comprehensive computational model using an Eulerian approach has been developed to simulate multiphase flows in a glass melter. It includes all the phases, divides solid particles or gas bubbles into various size groups, and treats each group as a continuum. The derived mass, momentum, and energy conservation equations of the flow are solved for local properties for each phase. The simulation considers the heating and melting of the batch (mainly from the radiative heat from combustion and from the convective heat from the molten glass), the formation and transport of bubbles, and ...

2005-12-01

208

Eulerian approach for multiphase flow simulation in a glass melter  

International Nuclear Information System (INIS)

A glass furnace, consisting of a combustion space and a glass melter, uses combustion heat to melt sand and cullet into liquid glass to make products. Glass quality is mainly dependent on the temperature, glass composition, and the level of impurities in a glass melter, which include solid batch/cullet particles, liquid glass, and gas bubbles. A comprehensive computational model using an Eulerian approach has been developed to simulate multiphase flows in a glass melter. It includes all the phases, divides solid particles or gas bubbles into various size groups, and treats each group as a continuum. The derived mass, momentum, and energy conservation equations of the flow are solved for local properties for each phase. The simulation considers the heating and melting of the batch (mainly from the radiative heat from combustion and from the convective heat from the molten glass), the formation and transport of bubbles, and ...

2005-12-01

209

Catalyst and reactor development for a liquid-phase Fischer-Tropsch process. Quarterly technical progress report, 1 April 1981-30 June 1981  

Science.gov (United States)

In October 1980, Air Products and Chemicals, Inc. began a three year contract with the DOE: Catalyst and Reactor Development for a Liquid Phase Fischer-Tropsch Process. The program contains four major tasks: (1) Project Work Plan, (2) Slurry Catalyst Development, (3) Slurry Reactor Design Studies, and (4) Pilot Facility Design. This report describes work on Tasks 2 and 3 carried out in the third quarter of the contract. In Task 2, the computerized search of the Fischer-Tropsch literature was continued, and improvements were made in data processing programs. Shakedown tests were completed on the first 300 ml slurry reactor, and construction of the second and third reactors began. Five modified conventional slurry catalysts were prepared, and two batches were tested in the gas phase giving information on selectivity as a function of composition and activation. Four supported cluster catalyst were synthesized, and seven were tested in the ...

1981-07-01

210

Model to simulate the interaction between boron carbide and steam or air at high temperature  

Energy Technology Data Exchange (ETDEWEB)

The oxidation of boron carbide in steam or air was recently extensively studied especially in Forschungszentrum Karlsruhe, Institut fuer Materialforschung. An important data set is available for the interaction modelling. An oxygen diffusion model through the superficial liquid boron oxide formed on the boron carbide external surface associated to a superficial reaction between the liquid boron oxide and steam is proposed to simulate the experimental kinetics from BOX rig and thermogravimetric tests on the interaction between steam and boron carbide at a temperature range 800 C to 1400 C. The oxygen diffusion model will be also useful to simulate interaction between boron carbide and Ar+O2 (air simulation) atmosphere when the steam pressure becomes zero. From the analysis of BOX rig experimental kinetics of non-condensable (H2, CO2, CO and CH4) gases we propose an oxygen diffusion model through the liquid boron oxide and a ''steam/liquid boron ...

2005-03-01

211

Phenomenological studies on structure and elemental composition of nanosecond and femtosecond laser-generated aerosols with implications on laser ablation inductively coupled plasma mass spectrometry  

International Nuclear Information System (INIS)

In laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS), the properties of laser-generated aerosols, such as size and composition, are crucial for matrix-independent quantification. In this study, the aerosol particle morphology and elemental composition generated by two state-of-the-art laser systems (ArF excimer nanosecond-UV laser and Ti:sapphire femtosecond-IR laser) were investigated by electron microscopic techniques. Electrostatic sampling of the aerosols directly onto transmission electron microscopy (TEM) grids allowed us to study the morphology and elemental composition of the aerosols using TEM and TEM-EDX (energy dispersive X-ray spectroscopy) analyses, respectively. The results of the electron microscopic studies were finally compared to the LA-ICPMS signals of the main matrix components. The investigations were carried out for non-conducting materials (glass and zircon), metallic samples ...

212

Transient testing of FFTF fuel pins in TREAT  

International Nuclear Information System (INIS)

A series of six transient tests was performed on FFTF irradiated fuel pins to demonstrate their transient performance capability. The tests were performed in the TREAT reactor using sodium loops and instrumented test trains. The TEMECH computer code was used to design overpower transients which would simulate FFTF fuel pin thermal conditions during slow and fast unprotected transients. Some tests were run to substantial overpower levels but terminated prior to fuel pin failure, while other tests were intentionally extended to fuel failure to establish failure thresholds and characteristics. Post-test examination data provided significant cladding strain and fuel melting information used for performance code calibration and validation. These data showed that cladding damage caused by fuel melting is related to the steady state condition of the fuel.

1986-09-07

213

Ammonia recycling and destruction in a CFB gasifier  

Energy Technology Data Exchange (ETDEWEB)

Biomass contains nitrogen that is converted to NOx on combustion. Conversion of biomass into producer gas by thermal gasification offers an opportunity to reduce NOx-emissions by NH3 removal from the producer gas with water. Waste water will have to be treated before it can be drained. Recovered NH3 may have value as base chemical, but usually will have to be disposed off as waste. Recycling within the gasification process is an option to dispose off NH3 waste, provided NH3 is broken down under gasification conditions. We present experimental data on NH3 destruction in a CFB gasifier at temperatures from 780C to 860C, when NH3 is injected into the gasification air. Within that temperature range, the fraction of NH3 that is broken down increases from less than 50% to nearly 100%. Clearly, the presence of O2 at the injection point leads to a much higher rate of NH3 destruction than observed for purely thermal cracking. Although measurement of the ...

2004-05-01

214

Transient-diffusion measurements of radon. Practical interpretation of measured data  

International Nuclear Information System (INIS)

The mathematical calculation to obtain a radon diffusion coefficient from measured radon transient-diffusion data is usually done by fitting a difference equation to the data. The difference equation is obtained through transformation of the time-dependent diffusion equation based on Fick's law. But, actual measured transient-diffusion data often have much scatter. Therefore just fitting over the whole range of the measured data through the method of least squares may not always be valid, because the method offers mathematical interpretation rather than a physical one. Instead, the actual radon diffusion coefficients must be otherwise obtainable from measured radon transient data. Taking this viewpoint, the present paper claims that about a 90% leveling-off time is often easily discernible regardless of the shape of the radon transient curve obtained from the measured data and it can be a decisive ...

2007-07-01

215

Assessment of soil-gas, soil, and water contamination at the former 19th Street landfill, Fort Gordon, Georgia, 2009-2010  

Science.gov (United States)

Soil gas, soil, and water were assessed for organic and inorganic constituents at the former 19th Street landfill at Fort Gordon, Georgia, from February to September 2010. Passive soil-gas samplers were analyzed to evaluate organic constituents in the hyporheic zone and flood plain of a creek and soil gas within the estimated boundaries of the former landfill. Soil and water samples were analyzed to evaluate inorganic constituents in soil samples, and organic and inorganic constituents in the surface water of a creek adjacent to the landfill, respectively. This assessment was conducted to provide environmental constituent data to Fort Gordon pursuant to requirements of the Resource Conservation and Recovery Act Part B Hazardous Waste Permit process. The passive soil-gas samplers deployed in the water-saturated hyporheic zone and flood plain of the creek adjacent to the former landfill indicated the ...

2011-01-01

216

Comparison of thermochemically calculated and measured dioxin contents in the off-gas of a sinter plant  

Energy Technology Data Exchange (ETDEWEB)

Polychlorinated dibenzo-p-dioxins and dibenzo-furans form a family of more than 200 compounds which are relatively stable in the biosphere and tend to accumulate in the human body. The tetra- to hexa-chlorinated dioxins and furans are considered highly toxic. To facilitate the assessment of the total toxicity of dioxin and furan mixtures, the estimated toxic effects of the individual compounds relative to the 2,3,7,8-tetrachloro-dibenzo-p-dioxin (TCDD) were introduced as Toxic Equivalent Factors which yield, when multiplied with the respective concentrations, the Toxic Equivalent (TE) of the mixture. Toxic dioxins and furans are unintentionally formed in a number of industrial combustion processes such as waste incineration and iron ore sintering, in the chemical industry and in household heating. To keep the emissions as low as possible, off-gas clearing systems for the collection of dioxins and furans are increasingly prescribed by the authorities. In addition, ...

1997-12-31

217

Simulations of Groundwater Flow and Radionuclide Transport in the Vadose and Saturated Zones beneath Area G, Los Alamos National Laboratory  

Energy Technology Data Exchange (ETDEWEB)

Numerical simulations are used to predict the migration of radionuclides from the disposal units at Material Disposal Area G through the vadose zone and into the main aquifer in support of a radiological performance assessment and composite analysis for the site. The calculations are performed with the finite element code, FEHM. The transport of nuclides through the vadose zone is computed using a three-dimensional model that describes the complex mesa top geology of the site. The model incorporates the positions and inventories of thirty-four disposal pits and four shaft fields located at Area G as well as those of proposed future pits and shafts. Only three nuclides, C-14, Tc-99, and I-129, proved to be of concern for the groundwater pathway over a 10,000-year period. The spatial and temporal flux of these three nuclides from the vadose zone is applied as a source term for the three-dimensional saturated zone model of the main aquifer that underlies the site. The ...

1999-07-01

218

Light Weight Composite Mirrors for Science Instruments  

Science.gov (United States)

Light Weight Composite Mirrors for Science Instruments. Composite Optics, Inc. San Diego, CA. INNOVATION. Light weight, large aperture reflectors of graphite ...

219

The composition-explicit distillation curve technique: Relating chemical analysis and physical properties of complex fluids.  

Science.gov (United States)

The analysis of complex fluids such as crude oils, fuels, vegetable oils and mixed waste streams poses significant challenges arising primarily from the multiplicity of components, the different properties of the components (polarity, polarizability, etc.) and matrix properties. We have recently introduced an analytical strategy that simplifies many of these analyses, and provides the added potential of linking compositional information with physical property information. This aspect can be used to facilitate equation of state development for the complex fluids. In addition to chemical characterization, the approach provides the ability to calculate thermodynamic properties for such complex heterogeneous streams. The technique is based on the advanced distillation curve (ADC) metrology, which separates a complex fluid by distillation into fractions that are sampled, and for which thermodynamically consistent temperatures are measured at atmospheric pressure. The ...

2009-11-17

220

Reactive magnetron sputtering of hard Si-B-C-N films with a high-temperature oxidation resistance  

International Nuclear Information System (INIS)

Based on the results obtained for C-N and Si-C-N films, a systematic investigation of reactive magnetron sputtering of hard quaternary Si-B-C-N materials has been carried out. The Si-B-C-N films were deposited on p-type Si(100) substrates by dc magnetron co-sputtering using a single C-Si-B target (at a fixed 20% boron fraction in the target erosion area) in nitrogen-argon gas mixtures. Elemental compositions of the films, their surface bonding structure and mechanical properties, together with their oxidation resistance in air, were controlled by the Si fraction (5-75%) in the magnetron target erosion area, the Ar fraction (0-75%) in the gas mixture, the rf induced negative substrate bias voltage (from a floating potential to -500 V) and the substrate temperature (180-350 deg. C). The total pressure and the discharge current on the magnetron target were held constant at 0.5 Pa and 1 A, respectively. The energy and flux of ...

2005-11-01

221

Preparation of ZnO-Al2O3 Particles in a Premixed Flame  

DEFF Research Database (Denmark)

Zinc oxide (ZnO) and alumina (Al2O3) particles are synthesized by the combustion of their volatilized acetylacetonate precursors in a premixed air-methane flame reactor. The particles are characterized by XRD, transmission electron microscopy, scanning mobility particle sizing and by measurement of the BET specific surface area. Pure (?-)alumina particles appear as dendritic aggregates with average mobile diameter 43-93 nm consisting of partly sintered, crystalline primary particles with diameter 7.1-8.8 nm and specific surface area 184-229 m2/g. Pure zinc oxide yields compact, crystalline particles with diameter 25-40 nm and specific surface area 27-43 m2/g. The crystallite size for both oxides, estimated from the XRD line broadening, is comparable to or slightly smaller than the primary particle diameter. The specific surface area increases and the primary particle size decreases with a decreasing flame temperature and a decreasing precursor vapour pressure. The combustion of ...

2000-01-01

222

Effect of chemical composition of SiO{sub x} films on rapid formation of Si nanocrystals induced by thermal plasma jet irradiation  

Energy Technology Data Exchange (ETDEWEB)

Si nanocrystal floating gate MOS capacitors were formed on p-Si (100) wafers by thermal plasma jet (TPJ) annealing of SiO{sub 2}/SiO{sub x} /SiO{sub 2}/Si(100) stacked structure. The chemical composition of SiO{sub x} layer was controlled by changing the SiH{sub 4}, He, and O{sub 2} gas flow ratio during plasma enhanced chemical vapour deposition. The MOS capacitors showed clear hysteresis in capacitance-voltage (CV) characteristics after TPJ annealing. The hysteresis width shows maximum value when initial composition x =1.7, which shows the maximum photoluminescence (PL) intensity. The maximum hysteresis width of 6.8 V was observed with gate voltage swept between 20 and -20 V in x = 1.7 sample. The result means 7.4 x 10{sup 12} cm{sup -2} carriers are injected to or emitted from Si nanocrystals. The duration of 1 V shift in flatband voltage was {proportional_to}0.1 ms with 20 V pulse, and charged carriers were stably ...

2010-04-15

223

Transient Critical Heat Flux tests on a rod bundle simulating Pressurized Water Reactors  

International Nuclear Information System (INIS)

Transients induced in nuclear power plants from many sources result in one or more fluid conditions changing with time. Fluid conditions of pressure, inlet temperature, inlet flow, or even system power many change separately or in conjunction with each other. The result of the condition change may be one which induces departure from nucleate boiling. An experimental investigation of transient which were intended to achieve Critical Heat Flux was performed at the Heat Transfer Research Facility of Columbia University for Siemens Nuclear Power Corporation. The transients were set up to include broad ranges of flow and pressure conditions near the operating range of pressurized water reactors. Transient events were dominated by varying single conditions and measuring the response of the system and of the rod thermocouples. Because of coupling effects within the test loop, secondary conditions would also ...

233

Method of purifying a gas mixture containing undesirable gas compounds  

Energy Technology Data Exchange (ETDEWEB)

The invention relates to a method for purifying a gas mixture containing at least one undesirable gas compound utilizing certain sulfonamide or sulfamide solvents.

1985-03-12

235

Thermodynamic Stable Metal Compositions  

International Science & Technology Center (ISTC)

Thermodynamic Stable Metal Compositions for Improvement of an Operational Safety of Constructional Materials under Conditions of Multifactor Loadings of an Aggressive Environment

236

Shock and Impact Response of Naval Composite Structures  

Science.gov (United States)

... at the end of this report. A. Low-Velocity Impact of Composite Sandwich Panels In 2007, the PI developed analytical solutions ...

2010-08-09

237

Nondestructive Testing of Polymeric Composite Sandwich ...  

Science.gov (United States)

... Accession Number : ADD345858. Title : Nondestructive Testing of Polymeric Composite Sandwich Panels Via the Thermographic Halo,. ...

238

MINEQL-PC. Chemical Equilibrium Composition of Aqueous Systems  

Energy Technology Data Exchange (ETDEWEB)

MINEQL is a subroutine package to calculate equilibrium composition of an aqueous system, accounting for mass transfer.

1986-11-21

239

Liquid hydrocarbon fuel composition  

Energy Technology Data Exchange (ETDEWEB)

A fuel composition comprising a liquid hydrocarbon fuel and a detergent amount of the product of reaction between a polyamine and a stearic acid is described.

1983-07-19

240

Damage and Repair of the APS Graphite/Epoxy Composite ...  

Science.gov (United States)

... Abstract : High temperature testing of graphite/epoxy laminates and composite sandwich panels was performed while the Shuttle was on orbit to ...

1982-10-12

241

DARPA Program Composition for Embedded Systems (PCES) ...  

Science.gov (United States)

... Title : DARPA Program Composition for Embedded Systems (PCES) Program Capstone Demonstration Video (Postprint) (CD-ROM). ...

2005-09-01

242

Computational Simulation - NASA Technical Report Server (NTRS)  

Science.gov (United States)

the progressive simplification of composite sandwich panels. The equations ... The thermal and structural behavior of composite sandwich panels with a ...

243

Carbon Fiber Reinforced Glass Matrix Composites for Satellite ...  

Science.gov (United States)

... The ultimate compressive strength (UCS) for the HMU/BSG composite is essentially equivalent to the tensile strength exhibited by this system. ...

1992-06-01

244

Advances and challenges of wood polymer composites  

Science.gov (United States)

... polypropylene, polylactic acid and polyvinyl chloride to form wood plastic composites (WPC). WPCs have seen a large growth in ... ...

245

Advanced Composites for Aerospace Require Waterjet ...  

Science.gov (United States)

... Accession Number : ADD808679. Title : Advanced Composites for Aerospace Require Waterjet Technology. Descriptive Note : Journal article. ...

1992-09-01

246

Transient performance of FFTF [Fast Flux Test Facility] reference fuel  

International Nuclear Information System (INIS)

Fourteen irradiated Fast Flux Test Facility (FFTF) fuel pins were subjected to representative overpower transients in six flowing sodium loop experiments conducted in the TREAT reactor. The transient tests were extended to substantial overpower levels well beyond protected levels, with some tests intentionally run to failure to identify failure thresholds and characteristics. Test variables included transient ramp rate (5, 50, and 100 cents/s) and burnup (2 to 58 MWd/kg). Performance limits and failure characteristics were identified, and cladding strain and fuel melting data were obtained for development and verification of transient analysis codes. The test results demonstrated that FFTF Reference fuel pins are capable of surviving overpower levels well beyond the FFTF secondary Plant Protection System (PPS) trip limit of 1.25 times normal rated power. Based on analytical evaluations to interpolate ...

1986-09-07

247

Study of heat rejection mechanism of a direct-injection diesel engine. 1st Report. Characteristics of local heat flux; Study of heat reinjection mechanism of a direct-injection diesel engine. 1. Characteristics of local heat flux  

Energy Technology Data Exchange (ETDEWEB)

Experimental investigations are being conducted on a single-cylinder direct-injection diesel engine to examine the transient heat transfer characteristics. Transient temperature data from stationary locations in the piston and cylinder head were used as the basis for determining the transient heat flux rates. Transient surface temperature was measured using the thin film thermocouples. At first, the transient heat flux rates calculated from the analysis method used in this paper were compared with the results from FEM. The results showed good agreement. Using this analysis method, the transient heat flux rates were calculated. The tests were performed at 1200 rpm with constant air flow. The parameters that were varied included the fuel rate and injection timing. Based on these results, the present paper discusses the mechanism of heat rejection in a ...

1997-09-25

248

Single-Electrode Transient Behavior for Electric Double Layer Capacitor Composed of Nano-Porous Carbon Electrode; Kasseitan denki 2jyuso kyapasita no tankyoku jyuhoden katei ni taisuru sokudoronteki kento  

Energy Technology Data Exchange (ETDEWEB)

Single-electrode transient behavior was measured mainly during the discharging process for a model cell of electric double layer capacitor with nano-porous carbon electrodes and reference electrode. Apparent conductivity in the cell, which we call `effective conductivity,` is determined with approximation of current in transient behavior to a one-dimensional electrophoretic model. A comparison of effective conductivity with conductivity of bulk solution suggests an interesting mechanism of transfer of electrolyte ions. The difference in transient behavior between various electrolyte ions was not conspicuous in spite of distinctive differences in conductivity of each bulk solution. The large pore diameter of the carbon electrode results in rapid transient behavior and such an electrode should be suitable for rapid charge and discharge. The effect of origin of carbon electrode is found to be significant ...

1997-07-10

249

Restudy of acid-extractable hydrocarbon data from surface geochemical survey in the Yimeng Uplift of the Ordos Basin, China: Improvement of geochemical prospecting for hydrocarbons  

Energy Technology Data Exchange (ETDEWEB)

Two geochemical surveys were conducted in 1992 and 2000 respectively in the Yimeng Uplift of the Ordos Basin, China. The earlier survey grid had 1 x 5km spacing and the later survey grid had 0.5 x 0.5km spacing. The acid-extractable hydrocarbons of both surveys show similar geochemical trends. However, the anomalies obtained with traditional statistical methods do not correlate with existing oil/gas fields. This study reveals two problems in the data and their processing. The first one is interference caused by the variation of soil composition. We applied a wavelet-analysis-based method to eliminate this interference in the data of the later survey. The second is that micro-seepage anomalies did not identify existing oil/gas fields and seepage anomalies related with faults had not been previously recognized. We modified the logic multiplication cluster analysis and applied a multi-fractal model and a back propagation ...

2006-06-15

250

Natural gas in Lake Erie: a reconnaissance survey of discharges from an offshore drilling rig  

Energy Technology Data Exchange (ETDEWEB)

Field studies were conducted May 28-June 1, 1979, to determine the chemical composition and physical behavior of discharges from an offshore gas drilling rig in the central basin of Lake Erie. The drilling operation was observed for four days, from rig jackup to the circulation of mud through the borehole after drilling had been completed. Resuspension studies using nephelometry, supplemented with chemical analyses, indicated little resuspension of lake bottom materials or release of metals to the water column during rig jack-up. Portions of the turbidity plumes generated during drilling were buoyant. Three surface turbidity plumes were mapped with nephelometry to a point at which particulate concentrations reached background levels in the Lake. Detectable plumes were approx. 400 to 1500 m in length and had maximum widths < 230 m. A chemical survey conducted in the plume during early gas shows indicated that discharged ...

1980-10-01

251

Microstructural analysis of a plasmanitrided tool steel by means of metallography and X-ray diffraction; Mikrostrukturelle und roentgenographische Analysen an einem plasmanitrierten Schnellarbeitsstahl  

Energy Technology Data Exchange (ETDEWEB)

Nitriding leads to improved tribological and corrosive properties of iron alloy components. In order to study the effect of plasma nitriding parameters on the structure of compound layer and diffusion zone, a systematic variation of process parameters, temperature and process gas atmosphere has been carried out. Metallographic inspection, X-ray diffraction and glow discharge optical spectroscopy analysis (GDOES) were used in this investigation. The results clarified that depending on the amount of nitrogen in the gas atmosphere nitrided layers with and without compound layer can be generated in the surface of M2 tool steel for temperatures from 350 C to 500 C. For plasma nitriding in 5 vol.% Nitrogen and 95 vol.% Hydrogen no compact compound layer was formed. The gas mixture of 76 vol.% Nitrogen resulted in compound layer formation for all temperatures from 350 C to 500 C. X-ray phase analysis indicated an almost 100% ...

2001-09-01

252

Experimental studies of selective acid gas removal: Absorption of hydrogen sulfide and carbon dioxide into aqueous methyldiethanolamine using packed columns  

Energy Technology Data Exchange (ETDEWEB)

The use of aqueous methyldiethanolamine (MDEA) for selective removal of hydrogen sulfide from acid gas streams has been studied in a 2 inch column packed with 1/4 inch ceramic Intalox saddles. The column was operated in a counter-current, steady state fashion. The feed gas composition varied between 1 and 5 mole % hydrogen sulfide and between 0 and 50 mole % carbon dioxide. In order to assist the development of packed column absorption models, the rate at which pure carbon dioxide absorbs into 2 M MDEA was measured as a function of pressure, liquid flow rate and packed bed length. The importance of end effects was carefully evaluated. In addition, draining and tracer methods were used to estimate the amount of static holdup present in the column. Using classical draining methods, as much as 50 % of the total holdup was found to be static. However, according to the step decrease in tracer method, less than 5 % of the total ...

1988-01-01

253

Modeling and analysis of heat transfer from the MHTGR core through a steel reactor vessel to the reactor cavity cooling system  

International Nuclear Information System (INIS)

The commercial Modular High Temperature Gas-Cooled Reactor (MHTGR) achieves improved reactor safety performance and reliability by utilizing an integrated sequence of completely passive thermal storage and heat transfer mechanisms to reject decay heat in the event that all its active cooling systems fail to operate. During such events, the initial heatup transient in the core is followed by a quasi-steady state cooldown process which, if uninterrupted, can continue for several days. A buoyancy-driven natural convection cooling system called the RCCS facilitates the continuous heat removal by circulating ambient air through the reactor cavity, where it is heated and then exhausted to the outside environment. The peak thermal load on the RCCS occurs approximately at the time that the vessel reaches its highest temperature. To confirm the adequacy of the RCCS design, detailed analytical models were developed to simulate the decay heat removal ...

1994-08-01

254

Activities performed within the program of Nuclear Safety Research on structural and cladding materials for innovative reactor systems able to transmute nuclear waste  

International Nuclear Information System (INIS)

Full text: The transmutation of nuclear waste to reduce the burden on a geological repository is a relevant topic within the Program of Nuclear Safety Research of the Research Centre Karlsruhe. Several studies have confirmed that a high efficiency of transmutation of actinides is reached in fast neutron spectrum reactor system. Therefore, an important effort is dedicated to the study of transmutation strategies with different fast reactors and their associated technologies. Moreover, in international contexts as Generation IV International Forum (GIF) and Sustainable Nuclear Energy Technology Platform (SNETP), fast reactors are considered in the frame of sustainable development of nuclear energy and reduction of waste. The systems that are currently under investigation, in the frame of the different fuel cycle scenarios, are liquid metal cooled and gas cooled fast reactors as well as Accelerator Driven Sub-critical Transmutation devices (ADS). These innovative ...

2009-10-05

255

Point defect supersaturation and enhanced diffusion in SPE regrown silicon  

Energy Technology Data Exchange (ETDEWEB)

Transient, greatly enhanced diffusion has been observed on annealing solid-phase-epitaxial (SPE) grown Si-Sb alloys. This is shown to be due to a high concentration of interstitials being trapped during SPE regrowth. The migration enthalpy, for diffusion of Sb by an interstitialcy mechanism was measured as 1.8 +/- 0.2 eV. The interstitials eventually condensed into loops, marking the end of the transient. In a SPE grown Si-Bi alloy a similar transient enhanced diffusion was observed, with an activation energy of 2.0 +/- 0.2 eV, but no loops formed. 8 figures, 7 references.

1984-01-01

256

Point defect supersaturation and enhanced diffusion in SPE regrown silicon  

International Nuclear Information System (INIS)

Transient, greatly enhanced diffusion has been observed on annealing solid-phase-epitaxial (SPE) grown Si-Sb alloys. This is shown to be due to a high concentration of interstitials being trapped during SPE regrowth. The migration enthalpy, for diffusion of Sb by an interstitialcy mechanism was measured as 1.8 +/- 0.2 eV. The interstitials eventually condensed into loops, marking the end of the transient. In a SPE grown Si-Bi alloy a similar transient enhanced diffusion was observed, with an activation energy of 2.0 +/- 0.2 eV, but no loops formed. 8 figures, 7 references.

257

Unmasking Stem/Progenitor Cell Properties in Differentiated ...  

Science.gov (United States)

... In addition to changes in BrdU, we also observed transient changes in p63 gene expression in the myoepithelial/stem cell layer. ...

2007-08-01

258

Transient suppression of MLH1 allows effective single-nucleotide substitution by single-stranded DNA oligonucleotides  

British Library Electronic Table of Contents (United Kingdom)

Short synthetic single-stranded oligodeoxyribonucleotides (ssODNs) can be used to introduce subtle modifications into the genome of mouse embryonic stem cells (ESCs). We have previously shown that effective application of ssODN-mediated gene targeting in ESC requires (transient) suppression of DNA mismatch repair (MMR). However, whereas transient down-regulation of the mismatch recognition protein MSH2 allowed substitution of 3 or 4 nucleotides, 1 or 2 nucleotide substitutions were still suppressed. We now demonstrate that single- or dinucleotide substitution can effectively be achieved by transient down-regulation of the downstream MMR protein MLH1. By exploiting highly specific real-time PCR, we demonstrate the feasibility of substituting a single basepair in a non-selectable gene. Howev...

2011-01-01

259

Transient stability enhancement of electric power generating systems by 120-degree phase rotation  

Energy Technology Data Exchange (ETDEWEB)

A method and system for enhancing the transient stability of an intertied three-phase electric power generating system. A set of power exporting generators (10) is connected to a set of power importing generators (20). When a transient cannot be controlled by conventional stability controls, and imminent loss of synchronism is detected (such as when the equivalent rotor angle difference between the two generator sets exceeds a predetermined value, such as 150 degrees), the intertie is disconnected by circuit breakers. Then a switch (30) having a 120-degree phase rotation, or a circuit breaker having a 120-degree phase rotation is placed in the intertie. The intertie is then reconnected. This results in a 120-degree reduction in the equivalent rotor angle difference between the two generator sets, making the system more stable and allowing more time for the conventional controls to stabilize the transient.

1982-01-01

260

Transient overpower test E8 on FFTF-type low-power irradiated fuel  

International Nuclear Information System (INIS)

... excursions fftf reactor fuel elements lmfbr type reactors reactivity insertions

1975-06-08

261

Transient / Structural Analysis of a Combustor under Explosive Loads  

Science.gov (United States)

Ultimate Compressive Strength = 3000.0 psi. 3.0 Failure Criteria. The structural criteria used to evaluate the combustor components was chosen ...

263

Prediction of transient-enhanced diffusion during rapid thermal annealing of ion-implanted silicon  

International Nuclear Information System (INIS)

There have been several reports of transient-enhanced diffusion during furnace or rapid thermal annealing of ion-implanted silicon and some reports of no enhancement. In this contribution, the authors show that many of the observed effects can be accounted for by an interstitial trapping mechanism, in which large numbers of Si atoms are trapped by group V dopant atoms in the amorphous material during implantation. These trapped atoms are retained during solid-phase-epitaxial (SPE) growth, but can be released later during thermal processing to give the transient-enhanced diffusion. The authors present a model which can predict the transient effects (or lack of them) for any concentration of Sb, Bi, or As dopants sufficient to amorphize the silicon and any thermal processing technology which relies on SPE growth (furnace, cw laser, or rapid thermal annealing).

1985-03-01

264

Long-term storage of solar heat  

Energy Technology Data Exchange (ETDEWEB)

Stochastic models for the simulation of global radiation are discussed. Thermal transients in the ground are analyzed. The performance of buried-pipe storage and a space heating system with long-term storage is described.

1981-06-01

265

Influence of inflammation on the efficacy of antibiotic treatment of experimental pyelonephritis.  

UK PubMed Central (United Kingdom)

An acute exudative Escherichia coli pyelonephritis rat model was used to study the influence of progressive pyelonephritis on the efficacy of antibiotic treatment. In this model, transient ureteral...Full Text Available

1986-05-01

266

Cooperative Effects on Transient Spectral Hole Burning  

Science.gov (United States)

... of Dist SpeA tI/ __LLL5' Page 5. 3 the coherent effects on the spontaneous radiation, we calculate the pump- field-induced ...

1992-06-01

267

Computer Controlled MHD Power Consolidation and Pulse ...  

Science.gov (United States)

... is a standard in the utility industry which is used to study switching transients on power distribution networks and high-voltage transmission lines. ...

1990-08-01

268

Hybrid Composites Made from Oil Palm Empty Fruit Bunches/Jute Fibres: Water Absorption, Thickness Swelling and Density Behaviours  

British Library Electronic Table of Contents (United Kingdom)

In this research, hybrid composite materials were prepared from combination of oil palm Empty fruit bunches (EFB) fibre and jute fibre as reinforcement, epoxy as polymer matrix. This study intended to investigate the effect of jute fiber hybridization and different layering pattern on the physical properties of oil palm EFB-Epoxy composites. Water absorption and thickness swelling test reveal that hybrid composite shows a moderate water absorption which is 11.20% for hybrid EFB/Jute/EFB composite and 6.08% for hybrid Jute/EFB/Jute composite. The thickness swelling and water absorption of the hybrid composites slightly increased as the layering pattern of hybrid composites changed. Hybrid composites are more water resistance and dimensional stable compare to the pure EFB composites. This is...

2011-01-01

269

Radiation protection and the management of radioactive waste in the oil and gas industry  

CERN Document Server

Radiation protection and the management of radioactive waste in the oil and gas industry

2003-01-01

270

Ideal gas of tachyons  

Energy Technology Data Exchange (ETDEWEB)

In this paper we consider properties of the ideal gas of classical (nonquantum) tachyons.

1983-10-15

271

CONVERTING WASTE  

Wastenet

condenser, gas refiner, oil (gas) storage tank and dual fuel engine

273

Gasmap 2006. Bringing Norwegian gas to Europe; En publikasjon om norsk gass og gasseksport  

Energy Technology Data Exchange (ETDEWEB)

A publication on Norwegian gas and gas export. The content is wide spread from use of gas in daily life via sub sea pipeline repair systems to an overview over tomorrows gas fields. (AG)

2006-06-15

274

The viscoelastic composite with interface debonding  

British Library Electronic Table of Contents (United Kingdom)

The effect of particle/matrix interface debonding on composites consisting of elastic particles and viscoelastic matrix is studied. The interface debonding is represented by a nonlinear cohesive law for the high explosive PBX 9501. The Mori-Tanaka method gives the constitutive relation of the composite in terms of the properties of elastic particles, viscoelastic matrix, and nonlinear cohesive law for interfaces. For the example of a composite with spherical particles subject to hydrostatic tension, simple analytical expressions of the composite stress-strain relation are obtained. The strain rate and temperature have strong effects on the composite behavior. High strain rate and low temperature give high strength of the composite. However, the rate and temperature effects decrease as the ...

2008-01-01

275

Wax and hydrate control with electrical power  

Energy Technology Data Exchange (ETDEWEB)

Electrical heating of subsea flowlines is an effective way to prevent wax and hydrate information, especially for long transportation distances and in low-temperature deep water. Systems are available for use in conjunction with bundles, pipe-in-pipe, and wet-thermal-insulation systems. These systems provide environmentally friendly fluid-temperature control without chemicals or flaring for pipeline depressurizing. Enhanced production is achieved because no time is lost by unnecessary depressurizing, pigging, heating-medium circulation, or removal of hydrate and wax blockages. The seabed temperature at 100-m and greater water depths may range from 7 to {minus}1.5 C, causing a rapid cooling of the hot well streams being transported in subsea flowlines. Under these supercooling conditions, vulnerable crude oils and multiphase compositions will deposit wax and asphalts; also the gas/water phase may freeze solid with hydrate particles. The paper ...

1997-08-01

276

Tokamak and laboratory modeling of hydrocarbon film deposition on metallic mirrors  

International Nuclear Information System (INIS)

In this work, amorphous hydrocarbon (a-C:H) film deposition on metallic mirrors was studied during working shots in tokamak T-10 and at exposure in Ar/CHD3/D2 dc magnetron discharge in a special laboratory high vacuum setup. Analysis of film composition (including hydrogen content) was carried out using nuclear physical methods. Thickness and optical parameters (refractive and extinction coefficients) of the films were estimated by ellipsometry. Laboratory films can be characterized as soft a-C:H films in comparison with hard tokamak films (? = 1.2 and 1.8 g/cm3, respectively). For the first one, a linear dependence of deposition rate on mirror temperature was observed in a wide temperature range. The addition of methane into initial Ar/D2 magnetron gas mixture leads to an increase of deposition rate. The data obtained should be taken into account to prevent hydrocarbon film formation on the surface of first mirrors in ITER.

2009-06-15

277

The use of low sulphide tailings as the moisture retaining layer in engineered cover systems to prevent AMD  

Energy Technology Data Exchange (ETDEWEB)

One of the main problems facing the mining sector is the production of acid mine drainage (AMD), which is caused by the oxidation of sulphide minerals in the presence of water. AMD can have a detrimental effect on the environment. One solution is to use soil covering over the materials that cause acid to limit the gas flux by diffusion. A capillary barrier effect is generated by using various layers of different types of soil. In the composite system till and clay normally form the basis of the fine material layer. The use of low sulphide tailings to replace the use of fine grained soil was studied to evaluate its effectiveness. Following both in situ and laboratory experiments spread over an eight-year period, the results indicated that an effective method to limit the oxygen flux and generation of AMD is the use of non-acid generating tailings as the moisture retaining layer. The main concepts that form the basis of the study, analysis and ...

2000-07-01

278

The influence of active screen plasma nitriding parameters on corrosion behavior of a low-alloy steel  

Energy Technology Data Exchange (ETDEWEB)

This work presents a comparative study of low-alloy steel nitriding for different possible techniques. Active screen plasma nitriding (ASPN) is a successful surface modification method that has many advantages over the conventional DC plasma nitriding (CPN). The corrosion behavior of 30CrNiMo8 low-alloy steel has been examined using anodic polarization tests in 3.5% NaCl solution under varying conditions of ASPN and CPN processes. The process variables included active screen setup parameters, treatment temperature (550 and 580 deg. C), gas mixture (25/75 and 75/25 of N{sub 2}/H{sub 2}) and treatment time (5 and 10 h) in 500 Pa pressure. The structure and phases composition of the compound layer was studied by X-ray diffraction (XRD), microhardness tests, optical microscopy and scanning electron microscopy (SEM). It was observed that ASPN treated samples surface enhanced corrosion resistance while the temperature and/or hole size of screen setup ...

2009-09-18

279

The influence of active screen plasma nitriding parameters on corrosion behavior of a low-alloy steel  

International Nuclear Information System (INIS)

This work presents a comparative study of low-alloy steel nitriding for different possible techniques. Active screen plasma nitriding (ASPN) is a successful surface modification method that has many advantages over the conventional DC plasma nitriding (CPN). The corrosion behavior of 30CrNiMo8 low-alloy steel has been examined using anodic polarization tests in 3.5% NaCl solution under varying conditions of ASPN and CPN processes. The process variables included active screen setup parameters, treatment temperature (550 and 580 deg. C), gas mixture (25/75 and 75/25 of N_2/H_2) and treatment time (5 and 10 h) in 500 Pa pressure. The structure and phases composition of the compound layer was studied by X-ray diffraction (XRD), microhardness tests, optical microscopy and scanning electron microscopy (SEM). It was observed that ASPN treated samples surface enhanced corrosion resistance while the temperature and/or hole size of screen setup ...

2009-09-18

280

The fate of trace elements at coal-fired power plants  

International Nuclear Information System (INIS)

Within the framework of a Dutch research program on the environmental effects of coal combustion 15 measuring campaigns were carried out in the eighties. All the relevant ingoing and outgoing flows of electric power plants were sampled and the heavy metals composition was determined. An overview is given of these fifteen measuring campaigns. It is concluded that between 99.7% and 99.9% of the fly ash can be separated by electrofilters. The removal of solid elements is higher than 99%, except for those elements, which are enriched in the fly ash, f.e. Cd and Se (>90% removal is possible). Additional separation of the emissions of fly ash and elements in the fly ash takes place in a flue gas desulfurization (FGD) installation. Some elements are emitted as gaseous wastes. After the electrofilter Cl, F and I can be found for almost 100%, Br and Hg for 50% on average, and only small amounts of As and Se in the gaseous phase. In a wet FGD unit ...

281

The effect of frequency and temperature on the formation of nitrided layers and surface characteristics in the plasma nitrided stainless steel  

Energy Technology Data Exchange (ETDEWEB)

This work was initiated to examine the effect of frequency and treatment temperature on the formation of nitrided layers and surface characteristics during plasma nitriding. Plasma nitriding experiments were performed with 316L austenitic stainless steel at the temperatures 400 .deg. C and 500 deg. C using a pulsed d.c. plasma with various frequencies in an atmosphere of N{sub 2}-H{sub 2} gas mixture. The microstructure and thickness of the nitrided layer and morphology of the nitrided surface were investigated using OM, SEM, XRD, EDS and AFM. XRD patterns revealed that the surface layer formed at 400 deg. C consisted of S phase only and CrN+Fe{sub 4}N nitrides at 500 .deg. C and no change of phase composition with frequency was observed. The compound layer thickened slightly with increased frequency. Also, the surface roughness increased as the frequency of the pulsed plasma increased from 50 to 5,000Hz.

1999-04-01

282

Terrestrial Planet Formation in Extra-Solar Planetary Systems  

CERN Document Server

Terrestrial planets form in a series of dynamical steps from the solid component of circumstellar disks. First, km-sized planetesimals form likely via a combination of sticky collisions, turbulent concentration of solids, and gravitational collapse from micron-sized dust grains in the thin disk midplane. Second, planetesimals coalesce to form Moon- to Mars-sized protoplanets, also called "planetary embryos". Finally, full-sized terrestrial planets accrete from protoplanets and planetesimals. This final stage of accretion lasts about 10-100 Myr and is strongly affected by gravitational perturbations from any gas giant planets, which are constrained to form more quickly, during the 1-10 Myr lifetime of the gaseous component of the disk. It is during this final stage that the bulk compositions and volatile (e.g., water) contents of terrestrial planets are set, depending on their feeding zones and the amount of radial mixing that occurs. The main ...

2008-01-01

283

Techno-economic assessment of anaerobic digestion systems for agri-food wastes  

Energy Technology Data Exchange (ETDEWEB)

Activities in British Columbia's Fraser Valley generate an estimated 3 million tones of agriculture and food wastes annually, of which 85 per cent are readily available for anaerobic digestion. The potential for energy generation from biogas through anaerobic digestion is approximately 30 MW. On-farm manure-based systems represent the most likely scenario for the development of anaerobic digestion in British Columbia in the near future. Off-farm food processing wastes may be an alternative option to large centralized industrial complexes. Odour control, pathogen reduction, improved water quality, reduced greenhouse gas emissions and reduced landfill usage are among the environmental benefits of anaerobic digestion. The economical benefits include power and heat generation, biogas upgrading, and further processing of the residues to produce compost or animal bedding. This paper described a newly developed anaerobic digestion (AD) calculator that helps users ...

2010-07-01

284

Preparation and properties of #alpha#"' and #alpha#"'+ #beta#"' sialon ceramics  

International Nuclear Information System (INIS)

The densification of #alpha#"1-and #alpha#"+#beta#"1-sialon ceramics has been studied by means of in situ dilatometry. It is seen that the densification is greatly affected by the reaction sequences and the grain growth. The formation and densification of sialons start simultaneously as the dissolution of nitrides into the oxide eutectic liquid phase occurs. The formation of sialons is complete at 1800 deg C., while full densification can only be obtained by using gas pressure sintering. The typical microstructure of both #alpha#"'-and mixed #alpha#'+#beta#'-sialon ceramics consists of a crystalline phase of sialons and a small fraction of amorphous phase at grain boundaries. Vickers hardness (HV0.5) was measured by using the indentation technique, and the biaxial bending strength (#sigma#_b_i) was determined with the 'ball-on-ring' test. Fracture toughness was determined by using both the indentation and single-edged notched beam techniques. It is concluded that ...

285

Preparation and characterization of CdS nanoparticles and CdS/polyacrylonitrile nanocomposites by {gamma}-irradiation  

Energy Technology Data Exchange (ETDEWEB)

There has been considerable interest in producing and studying nanoparticle materials because of the effect of size on their structure, physical and chemical structure. Most studied nanoparticle semiconductors belong to the II-VI group, as they are relatively easy to synthesize and are generally prepared as particulates or in thin film form. Among II-VI compounds, CdS is one of the most studied materials. There are different ways to synthesize CdS nanoparticles such as colloidal particles, chemical decomposition, sol-gel, gas evaporation, magnetron sputtering, electrostatic deposition, and etc. {gamma}-irradiation is one of the effective methods for synthesis of nanomaterials. These nonomaterials have been extensively used in the preparation of nanocrystalline metals, metal oxides, and metal-polymer composites. However, The preparation of CdS nanoparticle and CdS/ polyacrylonitrile nanocomposite by {gamma}-irradiation method at room temperature ...

2001-11-15

286

Position sensitive and Bragg curve spectroscopy detector system for heavy ion reaction studies  

International Nuclear Information System (INIS)

A complete heavy ion identification system in heavy ion reaction studies consists, in general, of: 1) a position sensitive avalanche counter, and 2) ionization chamber to obtain total energy as well as a heavy ion identifier signal (such as the E#DELTA#E signal from a E-#DELTA#E type detector or the height of the Bragg peak that scales as Z of the heavy ion in a Bragg curve ionization chamber). In addition, a time-of-flight information may be needed to resolve the masses of the ions. With this motivation in mind, a composite detector system consisting of a Bragg curve spectroscopy ionization chamber (BCS-IC) and a one dimensional position sensitive parallel grid avalanche counter (XPS-PGAC) has been developed and used successfully at the BARC-TIFR pelletron accelerator facility. The design and performance of this gas detector system are reported. (author). 4 refs., 2 figs.

287

OXYGEN-ENRICHED COAL COMBUSTION WITH CARBON DIOXIDE RECYCLE AND RECOVERY: SIMULATION AND EXPERIMENTAL STUDY  

Energy Technology Data Exchange (ETDEWEB)

Two computational problems were worked on for this study. The first chapter examines the option of coal combustion using oxygen feed with carbon dioxide recycle to control the adiabatic flame temperature. Computer simulations using an existing state-of-the-art 3-dimensional computer code for turbulent reacting flows with reacting particles were employed to study the effects of increased carbon dioxide mole fraction on the char burnout, radiant heat transfer, metal partitioning, and NOx formation. The second chapter compares assumptions for the CO/CO{sub 2} ratio at the surface of mineral inclusions made in previous studies to predictions obtained from a pseudo-steady state kinetic model (SKIPPY) for a single porous particle. The detailed kinetic simulations from SKIPPY for varying particle sizes and bulk gas compositions were used to develop algebraic expressions for the CO/CO{sub 2} ratio that can be incorporated into metal vaporization ...

2002-02-28

288

Novel reduced pressure-balance syringe for chromatographic analysis.  

Science.gov (United States)

When withdrawing a fluid sample (for additional chromatographic analyses) from an apparatus operated at a reduced pressure, a typical syringe proves to be ineffective (even if it is equipped with a gas tight plunger). It simply does not create enough pressure differential to remove a fluid sample from a reduced pressure environment. We encountered such a situation as part of efforts to extend the operation of the advanced distillation curve protocol to reduced pressures. The problem was solved by the development of a pressure balance syringe that allows reliable and precise sampling from an apparatus operating at sub-ambient pressures. This new device uses an external vacuum source to evacuate a syringe barrel, allowing a user to withdraw fluid samples from environments with pressures as low as 0.5kPa. To demonstrate the operation of the newly developed device, distillate analyses were performed on two fluids at low pressure: a predefined validation mixture, and a ...

2010-09-19

289

Microstructural evaluation of as-solidified and heat-treated [gamma]-TiAl based powders  

Energy Technology Data Exchange (ETDEWEB)

Powders with nominal compositions (in atomic percent) Ti-48Al and Ti-48Al-2Nb-2Cr were prepared by the plasma rotating electrode process (PREP) and gas atomization (GA) techniques. As-solidified and heat-treated (1000degC per 3 h) powder samples were examined by metallography, scanning electron microscopy, X-ray diffraction and transmission electron microscopy. The microstructures of the powders were characterized as a function of atomization technique, alloy content, powder particle size (solidification rate) and thermal history. All of the as-solidified powders were comprised of disordered [alpha], and ordered [alpha][sub 2]-Ti[sub 3]Al and [gamma]-TiAl. For both alloys, a larger volume fraction of [alpha] and [alpha][sub 2] was observed in the PREP powders relative to GA powders of comparable size. Additionally, for both alloys and both atomization techniques, the volume fraction of [alpha][sub 2] was observed to increase with decreasing ...

1992-05-15

290

Magnetic field amplification and generation in hypervelocity meteoroid impacts with application to lunar paleomagnetism  

International Nuclear Information System (INIS)

A one-dimensional numerical model for the expansion of impact-produced vapor clouds is used to investigate magnetic field generation mechanisms in events such as meteor collisions with the moon. The resulting cloud properties, such as ionization fraction, electrical conductivity, radial expansion velocity, mass density, and energy density are estimated. The model is initiated with the peak shock states and pressure thresholds for incipient and complete vaporization of anorthosite lunar surface materials by iron and GA composition meteorites. The expansion of the spherical gas cloud into a vacuum was traced with a one-dimensional explicit lagrangian hydrodynamic code. The hypervelocity impact plasmas produced are found to be significant in the amplitudes and orientations of the magnetic fields generated. An ambient magnetic field could have been provided by the core dynamo, which would have interacted with the expanding plasmas and formed ...

1984-03-12

291

Low-energy ion-induced electron emission from gas-covered surfaces  

International Nuclear Information System (INIS)

Measurements of ion-induced electron emission have been performed with helium and argon ions with energies between 300 and 900 eV on W, W with 10% Ti, Al, Al with 1% Cu, Al with 1% Si, Si, and Be. This article describes many of the important surface characteristics that influence the ion-induced electron emission. For low-energy ions, the substrate material was found to be less important as the velocity of the incident ion decreased. In the case of incident Ar"+ the substrate material had a negligible effect on the emission for this energy range. The presence of an adsorbed layer enhanced emission in all cases. Heating the substrates resulted in oxidation of the surfaces and a subsequent increase in emission. The electron emission from aluminum samples with smaller grain sizes was higher than samples of identical composition with larger grains. This effect is due to the greater number of adsorption sites resulting from the higher grain boundary area.

292

Interfacial reactions between PbO-rich glasses and aluminium composites  

CERN Document Server

565 deg C occurs when dissolution rate exceeds oxidation rate, exposing the fresh Al anode to the glass melt. Under inert atmosphere (at 583 deg C), air oxidation is not possible and galvanic cell redox reactions generate an excessive copper interlayer as the system attempts to sustain the oxide layer at the anode. Similar behaviour is observed in those coatings formed on the alloy using glass C (containing Al sub 2 O sub 3 and Na sub 2 O). In this case, the interfacial reactions involve the PbO of the glass and Pb-rich spherical precipitates are formed in the interfacial region, along side sodium aluminosilicate phases, precipitated from the PbO-depleted glass. The behaviour in both systems indicates that oxygen diffuses through the edge of the glass drop, from the atmosphere, to the substrate/glass interface. Coatings formed on the MMCs in air exhibited a porosity of approx 10%, attributed to the production of CO sub 2 gas through the oxidation of SiC at the ...

2000-01-01

293

Influence of the substrate coating temperature on the vacuum properties of Ti-Zr-V non-evaporable getter films  

CERN Document Server

Non-evaporable thin film getters of various compositions have been produced by sputtering. Among about 20 materials which have been studied, the lowest activation temperature (about 180 degree C) has been displayed by a Ti-Zr-V coating obtained from a cathode made of intertwisted elemental wires. In order to optimize the vacuum properties of this film various production parameters, including the substrate temperature during coating, have been varied. The films have been characterized by pumping speed measurement, secondary electron microscopy, and X-ray diffraction. It has been found that the substrate coating temperature affects significantly the activation temperature, the pumping speed and the gas surface capacity. The highest pumping speed values, obtained for substrate coating temperatures of 250 degree C and 300 degree C, are clearly correlated with the increased surface roughness and porosity of the Ti-Zr-V film.

2003-01-01

294

Hydrogen synthesis via combustion of fuel-rich natural gas/air mixtures at elevated pressure  

Energy Technology Data Exchange (ETDEWEB)

Combustion of extremely fuel-rich ({phi}=4) methane/air mixtures at elevated pressures is investigated as a potential means to generate molecular hydrogen by non-catalytic partial oxidation. This system is investigated both computationally and experimentally. The computations use a perfectly-stirred reactor model and an explicit methane cool-flame mechanism to investigate the effects of reactor parameters on reaction time and product composition. Under adiabatic conditions, such mixtures are predicted to autoignite at low temperatures {approx}700 K for pressures exceeding 8.5 atm. Above 15 atm, conversion to products is complete in roughly 1 s. The dependence of reaction time and hydrogen yield is investigated as a function of inlet temperature, system pressure, and flame equivalence ratio. Actual product yields are measured in a tube reactor facility, and many of the predictions of the model, including long relaxation times to chemical equilibrium and temperatures ...

2005-07-01

295

High pressure thermogravimetric analysis of the direct sulfation of Spanish calcium-based sorbents  

Energy Technology Data Exchange (ETDEWEB)

Under typical conditions found in Pressurized Fluidized Bed Combustion (PFBC), the calcination reaction of limestones is thermodynamically inhibited, and the sorbent reacts with SO{sub 2} by a direct mechanism. Direct sulfation reactivity of different Spanish sorbents was studied by high-pressure thermogravimetric analysis. It was found that the physical structure of the surface of the particles influence the sulfation behaviour of the sorbents. Total pore volume and pore surface area correlated well with the reactivity of the sorbents. Temperatures between 800 and 925{degree}C, and pressure between 12 and 25 bar, promoted an increase in reactivity, while the gas composition had no effect when changed from 15% CO{sub 2}, 3% O{sub 2}, 0.5% SO{sub 2}, balance N{sub 2} to 12% CO{sub 2}, 7% O{sub 2}, 0.5% SO{sub 2}, balance N{sub 2}. It was found that the unreacted shrinking core model could not satisfactorily describe the sulfation reaction under ...

1999-02-01

296

Heat capacity measurements of atoms and molecules adsorbed on evaporated metal films  

Energy Technology Data Exchange (ETDEWEB)

Investigations of the properties of absorbed monolayers have received great experimental and theoretical attention recently, both because of the importance of surface processes in practical applications such as catalysis, and the importance of such systems to the understanding of the fundamentals of thermodynamics in two dimensions. We have adapted the composite bolometer technology to the construction of microcalorimeters. For these calorimeters, the adsorption substrate is an evaporated film deposited on one surface of an optically polished sapphire wafer. This approach has allowed us to make the first measurements of the heat capacity of submonolayer films of /sup 4/He adsorbed on metallic films. In contrast to measurements of /sup 4/He adsorbed on all other insulating substrates, we have shown that /sup 4/He on silver films occupies a two-dimensional gas phase over a broad range of coverages and temperatures. Our apparatus has been used to ...

1989-05-01

297

Electrochemical ozone production: influence of the supporting electrolyte on kinetics and current efficiency  

International Nuclear Information System (INIS)

The nature of the electrolyte strongly influences the electrode kinetics of the oxygen evolution reaction (OER) and electrochemical ozone production (EOP) mainly by affecting the degree of coverage by the intermediates of both processes. The anomalous behaviour of the Tafel coefficient, b, as a function of temperature was attributed to surface adsorption of the electrolyte species, and the competition between them, as well as gas bubble adherence. Comparison of the current efficiencies of the EOP, PHI_E_O_P, determined for different temperatures and supporting electrolyte compositions, showed the presence of fluorinated anions increases PHI_E_O_P. The influence of the anion nature on PHI_E_O_P, when analysed in the light of the proposed electrode mechanism, reveals introduction into the electrolyte of anions having a high electronegativity changes the double layer structure resulting in an increase of surface concentration of the active centres ...

2003-02-05

298

Conceptual fusion power monitor based on the "1"6O(n,p)"1"6N reaction  

International Nuclear Information System (INIS)

The feasibility of developing a fusion power monitor based on a fluid activation detector is considered here. The activation fluid may be either a liquid or a gas and its composition can be selected from a number of candidate materials to provide desired activation and decay characterisitcs. Performance calculations indicate that ordinary water would be a nearly ideal activation fluid. The "1"6O(n,p)"1"6N reaction has a threshold at about 10 MeV and a cross section energy dependence giving it a predominant response for unmoderated D-T fusion neutrons. Adequate activation can be obtained at moderate flow rates for remote counting away from the high radiation area of the reactor. The 7.16 sec half-life of "1"6N is ideal for remote counting with subsequent decay in a small hold-up tank to eliminate activity build-up in the recycled water.

1981-07-01

299

Analysis of the relationship between the coal properties and their liquefaction characteristics by using the coal data base; Tanshu data base ni yoru tanshitsu to ekika tokusei no kaiseki  

Energy Technology Data Exchange (ETDEWEB)

The relationship between coal properties and liquefaction or gasification characteristics was analyzed by using the analysis and test results and liquefaction characteristics in the coal data base. On liquefaction reaction, the close relation between an oil yield and coal constituent composition or a coal rank is well-known. Various multivariable regression analyses were conducted by using 6 factors as variables such as calorific value, volatile component, O/C and H/C atomic ratios, exinite+vitrinite content and vitrinite reflectance, and liquefaction characteristics as variate. On liquefaction characteristics, the oil yield of dehydrated and deashed coals, asphaltene yield, hydrogen consumption, produced water and gas quantities, and oil+asphaltene yield were predicted. The theoretical gasification efficiency of each specimen was calculated to evaluate the liquefaction reaction obtained. As a result, the oil yield increased with H/C atomic ...

1996-10-28

300

A low temperature synthesized NbC as grain growth inhibitor for WC-Co composites  

Energy Technology Data Exchange (ETDEWEB)

Niobium carbide can be used to inhibit WC grain growth in hardmetal. The performance of a NbC powder produced at low temperature by solid-gas reaction (an experimental powder) as WC grain growth inhibitor is compared with that of a commercial NbC powder. It is verified that NbC effectively inhibits heterogeneous WC coarsening. This results in an increase in hardness. The commercial and experimental NbC powders exhibit a comparable performance in inhibiting the WC grain coarsening, in spite of a significant difference in particle size and shape. The commercial NbC powder is very fine while the experimental one is coarse and porous, but its crystallites are finer than those of the commercial product. The milling procedure used to prepare the alloys is able to reduce the particle size of the experimental NbC, and thus guarantee a dispersion of the particles with a quality level comparable to that found for the alloy prepared with the commercial NbC. (orig.)

2000-11-30

301

A biomass-supported Na2CO3 sorbent for flue gas desulfurization.  

Science.gov (United States)

A novel sorbent for SO2 removal has been investigated. The sorbent is obtained by conventional incipient wetness impregnation of abandoned biomaterials (straw or dried leaves) with an aqueous solution of Na2CO3. A material with the composition 80 wt % Na2CO3/straw shows a desulfurization activity which is both higher and faster than that of the reference sample Na2CO3/gamma-Al2O3. The breakthrough and stoichiometric SO2 adsorption efficiencies for 80 wt % Na2CO3/straw reach 48.9% and 80.6%, respectively, at a temperature of 80 degrees C. The adsorption efficiencies are almost constant in the temperature range 70 to 300 degrees C. According to IR and XPS analysis the main products observed on the spent sorbent are sulfite below 150 degrees C and sulfate at 300 degrees C. The Na2CO3 in 80 wt % Na2CO3/straw can potentially be recycled by the oxidation of the straw with concomitant reduction of the sulfite species to elemental sulfur, making the proposed process CO2 ...

2003-06-01

302

Transient sheath overvoltages in armored power cables  

Energy Technology Data Exchange (ETDEWEB)

This paper is concerned with methods of limiting the build-up of transient voltages between sheath and armor in long armored power cables. Calculations by a frequency dependent cable model demonstrate that this voltage can be efficiently limited to an acceptable level by introducing sheath-armor bondings at regular intervals, or by using a semiconductive sheath-armor interlayer. The paper investigates the required minimum length between bondings, as well as the required conductivity of the sheath-armor interlayer if the use of bondings is to be avoided.

1996-07-01

303

Transient enhanced diffusion of oxygen in Fe mediated by large electronic excitation  

International Nuclear Information System (INIS)

Contrary to the electronic excitation induced phenomena of desorption and sputtering, we observed incorporation of oxygen in a thin Fe film during its irradiation with swift heavy ions. It is observed that the adsorbed oxygen diffuses in to the Fe film. The incorporation of oxygen and its diffusion in the bulk of the film is a manifestation of extremely large electronic energy deposition by the incident ions. It is shown that the experimentally observed high diffusivity of oxygen in Fe during irradiation is due to the existence of transient melt phase of Fe.

2003-10-15

304

Searches for Fast Radio Transients  

CERN Document Server

We discuss optimal detection of fast radio transients from astrophysical objects while taking into account the effects of propagation through intervening ionized media, including dispersion, scattering and scintillation.Our analysis applies to the giant-pulse phenomenon exhibited by some pulsars, for which we show examples, and to radio pulses from other astrophysical sources, such as prompt radio emission from gamma-ray burst sources and modulated signals from extra-terrestrial civilizations.

2003-01-01

305

Prevent Diabetes Problems: Keep Your Heart and Blood Vessels Healthy  

Science.gov (United States)

... mini-stroke," also called a TIA or a transient ischemic attack . If you have any of these warning signs, ... ur-uhl) (ar-TEE-ree-uhl) (dih-ZEEZ) transient ischemic attack (TRANZ-see-uhnt) (iss-KEE-mik) (uh-TAK) [ ...

306

On the theory of transient enhanced diffusion in boron-implanted silicon  

Energy Technology Data Exchange (ETDEWEB)

Transient enhanced diffusion in boron-implanted silicon is interpreted as being due to the fact that during rapid thermal annealing a relaxation process takes place, associated with quasi-chemical reactions including defects. A simple analytical model makes it possible to describe the annealing mechanism on a microscopic scale in terms of reaction-diffusion processes. The measured dependences of the boron diffusion coefficient of the enhanced diffusion on time, temperature and implantation energy are satisfactorily explained. (author).

1991-01-01

307

On the theory of transient enhanced diffusion in boron-implanted silicon  

International Nuclear Information System (INIS)

Transient enhanced diffusion in boron-implanted silicon is interpreted as being due to the fact that during rapid thermal annealing a relaxation process takes place, associated with quasi-chemical reactions including defects. A simple analytical model makes it possible to describe the annealing mechanism on a microscopic scale in terms of reaction-diffusion processes. The measured dependences of the boron diffusion coefficient of the enhanced diffusion on time, temperature and implantation energy are satisfactorily explained. (author).

308

Fast reactor fuel pin performance requirements for off-normal events  

International Nuclear Information System (INIS)

HEDL is conducting an experimental transient testing program to evaluate the performance of prototypic Fast Flux Test Facility (FFTF) fuel pins up to the cladding integrity limit. The relationship is described of the HEDL/TREAT transient overpower test program to the confirmation of FFTF fuel pin design bases via the FFTF fuel pin design procedure.

309

Evaluation of transient dose in conveyor type low dose irradiator  

International Nuclear Information System (INIS)

In conveyor type irradiators, the movement of conveyor and the product boxes is not there until the source is fully in the irradiation position. In case the conveyor system fails the source must automatically be returned to its shielded storage vault. The dose received by the product during the movement of the source from or to the shield becomes significant if the total dose to be received by the product is small. A study has been carried out for evaluating the transient dose received by onions in the POTON irradiator. The results of the study are discussed in this paper. (author)

2003-03-05

310

Interface engineering in chalcopyrite thin film solar devices  

Energy Technology Data Exchange (ETDEWEB)

Successful interface engineering requires compositional and electronic material characterization as a prerequisite for understanding and intentionally generating interfaces in photovoltaic devices. The paper gives an overview with several examples, all referring to Cu(In,Ga)(S,Se){sub 2} ('CIGSSe')-based solar cells, with an emphasis on characterization using highly specialized methods, such as elastic recoil detection analysis, X-ray emission spectroscopy and photoelectron spectroscopy using synchrotron and ultraviolet light for excitation, inverse photoemission spectroscopy and Kelvin probe force microscopy. First, the determination of the depth profile of the band gap energy E{sub g} in the absorber layer is demonstrated. The modification of E{sub g} towards both interfaces is discussed in terms of beneficial electronic effects. Next, the interface between absorber and buffer layers with alternative and promising non-toxic materials is ...

2006-06-15

311

Influence of phosphorus vapor ambient for InGaAsP growth on GaAs substrate  

Science.gov (United States)

For visible-light-emitting laser diodes, InGaAsP double heterostructures have been grown on GaAs substrates using liquid-phase epitaxy. As the growth temperature is as high as about 780 /sup 0/C, a large amount of phosphorus evaporates from the solutions for the cladding layers during the growth process. The phosphorus vapor disturbs the solution composition for the active layer, so that very thin and uniform active layers cannot be obtained. By using In-P-Sn solution and supplying the phosphorus partial pressure around the graphite boat, the influence of phosphorus vapor ambient for InGaAsP (lambda/sub P//sub L/ = 805 nm) growth is confirmed. When the phosphorus partial pressure increases, the surface of epitaxial layer becomes rough and the substrate is partly etched back. From x-ray diffraction and photoluminescence spectral measurements, the composition of the grown layer is also found to be changed. As a result of increasing the flow rate ...

1986-12-01

312

Fiscal 1997 report on the results of the R and D of industrial scientific technology. R and D of synergistic ceramics (R and D of corrosion prevention technology for the petroleum production system); 1997 nendo sangyo kagaku gijutsu kenkyu kaihatsu seika hokokusho. Synergy ceramics no kenkyu kaihatsu (sekiyu seisan system fushoku boshi gijutsu kenkyu kaihatsu)  

Energy Technology Data Exchange (ETDEWEB)

To heighten durability and safety of materials/parts for undersea oil drilling, the development of ceramic base materials was made by developing function harmony type process technology which harmonizes on a high grade contrary characteristics and various functions. The paper summed up the fiscal 1997 results. In the design of system formation, computational simulation technology was developed to the composite process and the diploid system. The development of multifunction simultaneous manifestation materials was trially made by the higher nano structure process. A study was made of control of microstructures of porous materials and matrix filling by the gas phase precipitation control. Proposed were selective control of grain growth from species crystals and the columnar particle orientation laminated structure of simultaneous manifestation of strength and toughness. By composite precipitation reaction control, studied ...

1998-03-01

313

Crack healing behavior and high-temperature strength properties in Si3N4/SiC composite ceramics. Si3N4/SiC fukugo ceramics no kiretsu chiyu kyodo to koon kyodo tokusei  

Energy Technology Data Exchange (ETDEWEB)

Two kinds of Si3N4/SiC composite ceramics having different sintering auxiliaries were fabricated to investigate reproduction of crack healing phenomenon, effects of sintering auxiliaries on crack healing behavior, optimal crack healing conditions, and high-temperature strength characteristics of crack healed portions. The experiment used sinters added with SiC powder at 20% by volume, and hot-pressed under conditions of a sintering temperature of 1850 degC, time for two hours, and a pressure of 35 MPa. The sintering auxiliaries used are Y2O3 and Al2O3. In the experiment, pre-cracks were introduced into test specimens, and heat treatments were given in atmosphere and in argon gas atmosphere at 1300 degC for one hour. A four-point bending test was conducted in atmosphere as a strength test. The result of the experiment revealed that the materials which were heat-treated in atmosphere have greater crack healing effect, that the optimum heat ...

1998-05-21

314

Hydrothermal synthesis of tobermorite/hydroxyapatite composites  

British Library Electronic Table of Contents (United Kingdom)

A tobermorite/hydroxyapatite composite was prepared by hydrothermal treatment using diatomaceous earth, ?-tricalcium phosphate and slaked lime starting materials. The XRD patterns of the composite confirmed that tobermorite and hydroxyapatite were formed after the hydrothermal process. The bending strength of the composite reached a level higher than 9?MPa after the hydrothermal process. The development of the bending strength was due to the formation of tobermorite and hydroxyapatite during the hydrothermal process. The composite had a high specific surface area due to these newly formed crystals.

2008-01-01

315

Electrochemical stability of silicon/carbon composite anode for lithium ion batteries  

International Nuclear Information System (INIS)

Silicon/carbon composite anode materials were prepared by pyrolyzing the phenol-formaldehyde resin (PFR) mixed with silicon and graphite powders. Scanning electron microscopic (SEM) observation showed that the morphology stability of the composite electrodes can be retained during cycling. A structure evolution mechanism is proposed to illuminate the enhancement of cycleability of the composite electrode. The composite used as anode material for lithium ion batteries possesses a reversible capacity of over 700 mAh/g.

2007-04-20

316

Catalysis over activated zeolites  

Science.gov (United States)

A process is provided for conducting organic compound conversion over a catalyst composition comprising a supported crystalline zeolite having a high initial silica-to-alumina mole ratio, said supported zeolite being prepared by compositing said crystalline zeolite with alumina, reacting the composite with a particular hydrogen fluoride solution in a specified way, drying the hydrogen fluoride reacted composite, treating the dried composite by hydrolysis, ammonolysis and/or by contact with an ammonium salt solution, and calcining the resulting material.

1985-02-19

317

Transient radon diffusion through radon-proof membranes: A new technique for more precise determination of the radon diffusion coefficient  

Energy Technology Data Exchange (ETDEWEB)

The following paper is focused on the numerical modelling of the transient radon diffusion through radon-proof membranes during the measurement of their radon diffusion coefficient. The major aim of such numerical modelling is to increase the accuracy of radon diffusion coefficients derived from the measured data sets. The developed complex ''transient'' numerical model is able to calculate the radon diffusion coefficient with sufficient accuracy from almost any data set - even from a short-time measurement with a non-linear course of results. This numerical model can also be used for various analyses of transient radon transfer processes (e.g. for the calculation of radon distribution curves within the membrane). The following paper presents governing equations for the simulation model, together with a brief description of algorithms incorporated in the newly developed software package, ...

2009-06-15

318

Study of heat reinjection mechanism of a direct-injection diesel engine. 2nd Report. Effects of combustion control item on heat flux; Chokufun diesel kikan no nensho shitsunai netsu sonshitsu no mechanism ni kansuru kenkyu. 2. Nenshokei parameter no netsu nagare eno eikyo  

Energy Technology Data Exchange (ETDEWEB)

Experimental investigations are being conducted on a single-cylinder direct-injection diesel engine to examine the effects of combustion chamber specifications and swirl ratios on the heat release and transient heat transfer characteristics. Heat rejection was examined on the basis of heat release calculations using cylinder pressure time histories. Transient surface temperature data obtained from stationary locations in the piston and cylinder head were used as the basis for determining the transient heat flux rates. The results showed good agreement with the heat rejection calculated from cylinder pressure data and that transient heat flux in a piston cavity was reduced with the larger cavity diameter and a higher swirl ratio. On the other hand, a transient heat flux in a piston head was not changed by the cavity diameter and swirl ratio. 5 refs., 19 figs.

1997-09-25

319

Gas fixation solar cell using gas diffusion semiconductor electrode  

Energy Technology Data Exchange (ETDEWEB)

A gas diffusion semiconductor electrode and solar cell and a process for gaseous fixation, such as nitrogen photoreduction, CO/sub 2/ photoreduction and fuel gas photo-oxidation are described. The gas diffusion photosensitive electrode has a central electrolyte porous matrix with an activated semiconductor material on one side adapted to be in contact with an electrolyte and a hydrophobic gas diffusion region on the opposite side adapted to be in contact with a supply of molecular gas.

1980-12-23

320

The effect of hydrogen peroxide solution on SO2 removal in the semidry flue gas desulfurization process.  

Science.gov (United States)

The present study attempts to use hydrogen peroxide solution to humidify Ca(OH)(2) particles to enhance the absorption of SO(2) to achieve higher removal efficiency and to solve the valuable reuse of the reaction product in the semidry flue gas desulfurization (FGD) process. Experiments were carried out to examine the effect of various operating parameters including hydrogen peroxide solution concentration, Ca/S molar ratio and approach to adiabatic saturation temperature on SO(2) removal efficiency in a laboratory scale spray reactor. The product samples were analyzed to obtain semi-quantitative measures of mineralogical composition by X-ray diffraction (XRD) with reference intensity ratio (RIR) method and the morphology of the samples was examined by scanning electron microscope (SEM). Compared with spraying water to humidify Ca(OH)(2), SO(2) removal efficiency was improved significantly by spraying hydrogen peroxide solution of 1-3 wt.% to ...

2009-04-24

321

The Influence of CH_4 Gas Addition in the Nitriding of Low Temperature Plasma Carburized AISI304L Stainless Steel  

International Nuclear Information System (INIS)

The effects of CH_4 content at nitriding step in the low temperature two-step plasma treatment (carburizing+nitriding) on the surface characteristics of AISI304L stainless steel were investigated. The low temperature plasma carburizing was carried out at 550 .deg. C for 5h in a gas mixture of H_2 Ar and CH_4. The thickness of a carburized layer increased up to about 30 #mu#m and corrosion resistance of the layer decreased due to the precipitation formed at the grain boundary. After carburizing, a low temperature plasma nitriding was subsequently performed in the same chamber at 400 .deg. C for 15h to improve corrosion resistance and to further increase the surface hardness. The surface hardness of a N-enriched layer after nitriding reached up to 1,200HV_0_._1, which is much higher than that of as-carburized layer(750 HV_0_._1). The post nitriding process had a beneficial effect on reducing the precipitates in the C-enriched layer. The thickness of the N-enriched ...

2007-10-01

322

Simulation of char combustion according to shrinking particle and shrinking core model in circulating fluidized bed boilers; Simulation des Koksabbrandes nach dem Shrinking Particle- und Shrinking Core Modell in zirkulierenden Wirbelschichtfeuerungen  

Energy Technology Data Exchange (ETDEWEB)

The presented paper describes the formulation of the fractional mass balances which are used to calculate the concentration and size distribution of char in the balance cells of a circulating fluidized bed boiler. In case of using the shrinking core model additionally the distribution of conversion of the char particles is calculated. Basically two reaction models (a shrinking particle and a shrinking core model) are available to describe the combustion process. The model considers all essential physico/chemical phenomena (primary fragmentation, attrition, mass transfer to gas phase) which have to be taken into account for the description of the combustion process. The model is part of an overall simulation program for circulating fluidized bed boilers. This engineering simulator has been developed to return the main performance parameters of such systems like temperature along the furnace height, size distribution of balanced solid components, heat flows at the ...

1998-12-31

323

Preliminary experience with the new Harwell inactive vitrification pilot plant  

International Nuclear Information System (INIS)

The decision of the United Kingdom to adopt a policy of solidification of high level waste had led to renewed interest in vitrification. The HARVEST process chosen is an adaptation of the FINGAL concept developed at Harwell 15 years ago. Because of certain changes in engineering design and differences in the composition of the waste, additional chemical engineering data are required for HARVEST. The new inactive pilot plant has been built to provide this information. Its size is virtually full-scale and batches of glass up to 1 tonne can be manufactured in vessels of diameter up to 750mm. Five glass-making runs have been carried out. Attention has concentrated on the performance of the off-gas system which employs wet methods. Carry-over of solids occurs, primarily as a result of physical entrainment. The carry-over of synthetic fission products is improved from 2.5 to 0.1% by directing the feed down the vessel walls. Most of the entrained ...

324

Experimental study and modeling of CH{sub 4}/O{sub 2}/Ar and C{sub 2}H{sub 6}/O{sub 2}/Ar pre-mixing laminar flames; Etude experimentale et modelisation de flammes laminaires de premelange CH{sub 4}/O{sub 2}/Ar et C{sub 2}H{sub 6}/O{sub 2}/Ar  

Energy Technology Data Exchange (ETDEWEB)

New studies are always needed to better determine the physico-chemical processes involved in the combustion of natural gas. The understanding of the reaction mechanisms that lead to the formation of nitrogen oxides or volatile organic compounds requires to identify the inner mechanisms which take place during combustion and in particular the mechanisms of formation of intermediate products. The aim of this study is to analyze the thermal degradation of methane and ethane in low pressure pre-mixed stabilized laminar flames condition, because both of these compounds represent the major part of natural gas composition. The main chemical reaction ways identified in the studied flames and responsible for combustion have been identified after a comparison between experimental results and the computerized simulation performed using an a-priori postulated chemical mechanism. This study stresses on the transfer reaction schemes ...

1996-12-31

325

CERAMIC MEMBRANES FOR HYDROGEN PRODUCTION FROM COAL  

Energy Technology Data Exchange (ETDEWEB)

The preparation and performance of membranes for application to hydrogen separation from coal-derived gas is described. The membrane material investigated was dense amorphous silica deposited on a suitable support by chemical vapor deposition (CVD). Two types of support materials were pursued. One type consisted of a two-layer composite, zeolite silicalite/{alpha}-Al{sub 2}O{sub 3}, in the form of tubes approximately 0.7 cm in diameter. The other type was porous glass tubes of diameter below 0.2 cm. The first type of support was prepared starting from {alpha}-Al{sub 2}O{sub 3} tubes of 1{micro}m mean pore diameter and growing by hydrothermal reaction a zeolite silicalite layer inside the pores of the alumina at the OD side. After calcination to remove the organic template used in the hydrothermal reaction, CVD was carried out to deposit the final silica layer. CVD was carried out by alternating exposure of the surface with silicon tetrachloride ...

2004-04-01

326

Study of wood plastic composite in the presence of nitrogen containing additives  

Energy Technology Data Exchange (ETDEWEB)

Effect of nitrogen-containing additives in the study of wood plastic composites of MMA with simul and mango wood of Bangladesh has been investigated. Nine different additives were used and the additives containing carboamide group induce the highest tensile strength to the composite. (author).

1994-10-01

327

Study of wood plastic composite in the presence of nitrogen containing additives  

International Nuclear Information System (INIS)

Effect of nitrogen-containing additives in the study of wood plastic composites of MMA with simul and mango wood of Bangladesh has been investigated. Nine different additives were used and the additives containing carboamide group induce the highest tensile strength to the composite. (author).

1994-01-01

328

Study of wood plastic composite in the presence of nitrogen containing additives  

Science.gov (United States)

Effect of nitrogen-containing additives in the study of wood plastic composites of MMA with simul and mango wood of Bangladesh has been investigated. Nine different additives were used and the additives containing carboamide group induce the highest tensile strength to the composite.

1994-10-01

329

Potentials for composites from agro-based fibers  

Energy Technology Data Exchange (ETDEWEB)

A composite is any combination of two or more resources held together by some type of mastic or matrix. This report will describe several different types of composites with regard to thermoplasticization, improved mechanical properties, and stiffness.

1995-12-01

330

Physical Morphology and Quantitative Characterization of Chemical Changes of Weathered PVC/Pine Composites.  

Science.gov (United States)

This study investigated weathering effects on polyvinyl chloride (PVC) based wood plastic composites (WPC), with a focus on the color and structure that is attributed to the material composition. It is directed towards quantifying the main chemical modifi...

2009-01-01

331

Osteoblast response to dimethacrylate composites varying in composition, conversion and roughness using a combinatorial approach  

UK PubMed Central (United Kingdom)

Dimethacrylate polymers and composites are seeing increased usage in orthopedics. As these applications require the material to integrate with the surrounding tissues, direct contact cytotoxicity...Full Text Available

2009-09-01

332

The chain of the natural gas in Colombia  

International Nuclear Information System (INIS)

The book tries about the International and national aspects, natural gas situation, production, consumption, prices, demand projection, energetic plans, norms and laws of the natural gas in Colombia

2007-01-01

333

Overview of estimations of natural gas in small fields  

International Nuclear Information System (INIS)

An overview is given the expected amount of natural gas that can be produced from small gas fields in the Netherlands in the next 20 years.

2005-01-01

334

Natural gas annual 1996  

Energy Technology Data Exchange (ETDEWEB)

This document provides information on the supply and disposition of natural gas to a wide audience. The 1996 data are presented in a sequence that follows natural gas from it`s production to it`s end use.

1997-09-01

335

Size and morphology of heavy-duty vehicle particle emissions; Raskaan ajoneuvokannan hiukkaspaeaestoen koko ja morfologia - HD-PM  

Energy Technology Data Exchange (ETDEWEB)

Formation of particles from heavy duty diesel and CNG vehicles was studied in laboratory conditions. PM, nano and soot mode particle emissions formed from buses of Euro 2-5 -emission levels were studied in relation to age and type approval characteristics of the vehicle. Characteristic particle emission factors from city driving were obtained by driving the buses on VTT's heavy duty chassis dynamometer applying the transient Braunschweig city cycle. The vehicles were a representative set of Euro 2 to 3 emission categories, supplemented with Euro 4-5 (EEV) -targeted CRT, CNG and DPF cars. Particle number emissions from Euro 4 to 5 buses were 1/100-1/1000 and mass emissions 1/10-1/100 of those of the current fleet. Particle emission from natural gas buses and after an advanced CRT trap contained almost entirely liquid < 60 nm nano particles, which will make filter mass based PM control very challenging in the near future. One ...

2006-10-15

336

Wear resistant composite structure of vitreous carbon containing convoluted fibers. Quarterly report No. 4  

Energy Technology Data Exchange (ETDEWEB)

This report presents a brief description of the fabrication and advantages of a composite, carbon-metal fiber material which does not require lubrication.

1995-05-01

337

Relationship of source and sink in determining kernel composition of maize  

UK PubMed Central (United Kingdom)

The relative role of the maternal source and the filial sink in controlling the composition of maize (Zea mays L.) kernels is unclear and may be influenced by the genotype and the N...Full Text Available

2010-01-01

338

Preparation of covalently modified organic-inorganic composite nanoparticles and their interfacial electron transfer researches  

CERN Document Server

Preparation of covalently modified organic-inorganic composite nanoparticles and their interfacial electron transfer researches

1998-01-01

339

Predictions of Thermal Buckling Strengths of Hypersonic ... - NASA  

Science.gov (United States)

Composite Sandwich Panels under Different Thermal Environments, Composite Structures, Vol. 25,. July 1993, pp. 227239. 11. Ko, William L., Mechanical and ...

341

Metal phthalocyanine catalysts  

Energy Technology Data Exchange (ETDEWEB)

As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

1994-01-01

342

Measurements of the concentration and composition of nuclei for cirrus formation  

UK PubMed Central (United Kingdom)

This article addresses the need for new data on indirect effects of natural and anthropogenic aerosol particles on atmospheric ice clouds. Simultaneous measurements of the concentration and composition...Full Text Available

2003-12-09

343

Instrumeted Impact Testing of Composite Sandwich Panels,  

Science.gov (United States)

... Accession Number : ADD442819. Title : Instrumeted Impact Testing of Composite Sandwich Panels,. Corporate Author : AUBURN UNIV AL. ...

1989-05-01

344

Indirect resin composites  

UK PubMed Central (United Kingdom)

Aesthetic dentistry continues to evolve through innovations in bonding agents, restorative materials, and conservative preparation techniques. The use of direct composite restoration in posterior teeth...Full Text Available

2010-10-01

345

Fiber Reinforced Superalloys - NASA Technical Reports Server  

Science.gov (United States)

hlgh fiber content composites met the minlmum requirements. (1400 O F ) , the hlgher fiber content as-fabricated composites have impact strengths distinctly ...

346

Energy Finite Element Analysis ... - NASA Technical Reports Server  

Science.gov (United States)

structures made out of composite laminates and/or composite sandwich panels. A Spectral Finite Element Method (SFEM) [19, 20] is used for evaluating the ...

347

Design of Damage-Tolerant Composite Sandwich Panels with Tear Straps  

Science.gov (United States)

The objectives of the Phase-I research address the development of mechanics- based structural integrity analysis methodologies for composite sandwich panels ...

348

Composition of the Scientific Policy Committee Appointment of Two New Members by the Chairman of the Committee (J. Specht, A. Wroblewski)  

CERN Document Server

Composition of the Scientific Policy Committee Appointment of Two New Members by the Chairman of the Committee (J. Specht, A. Wroblewski)

1993-01-01

349

Composite vector leptoquarks in [ital e][sup +][ital e[minus  

Energy Technology Data Exchange (ETDEWEB)

We study the signals for composite vector leptoquarks in [ital e][sup +][ital e[minus

1993-02-01

350

A Composite Architecture for Network Security at JPL Robert B ...  

Science.gov (United States)

A Composite Architecture for Network Security at JPL. Robert B. Mead, Tom G. Dearmond, and Joseph S. Sherif. JPL, California Institute of Technology ...

351

A Composite Architecture for Network Security at JPL  

Science.gov (United States)

We advance a tentative composite model for computer security at JPL, together with inter and intra networking with other NASA centers and overseas clients.

1998-01-01

354

Residential Mercury Spills from Gas Regulators  

UK PubMed Central (United Kingdom)

Many older homes are equipped with mercury-containing gas regulators that reduce the pressure of natural gas in the mains to the low pressure used in home gas piping. Removal of these regulators can...Full Text Available

2006-06-01

358

Transient heat transfer in a directly-irradiated solar chemical reactor for the thermal dissociation of ZnO  

International Nuclear Information System (INIS)

A numerical and experimental investigation is carried out in a solar thermochemical reactor for the thermal dissociation of ZnO at 2000 K using concentrated solar energy. The reactor consists of a cavity-receiver lined with ZnO particles and directly exposed to high-flux irradiation. A transient heat transfer model is formulated to link the rate of radiation, convection, and conduction heat transfer to the reaction kinetics. The radiosity and Monte Carlo methods are applied to obtain the distribution of net radiative fluxes at the internal surfaces of the reactor cavity and at the surface of the ZnO bed. Validation is accomplished in terms of the calculated and measured transient temperature profiles and chemical reaction rates.

2008-04-01

359

Transient enhanced diffusion and gettering of dopants in ion implanted silicon  

International Nuclear Information System (INIS)

We have studied in detail the transient enhanced diffusion observed during furnace or rapid-thermal-annealing of ion-implanted Si. We show that the effect originates in the trapping of Si atoms by dopant atoms during implantation, which are retained during solid-phase-epitaxial (SPE) growth but released by subsequent annealing to cause a transient dopant precipitation or profile broadening. The interstitials condense to form a band of dislocation loops located at the peak of the dopant profile, which may be distinct from the band formed at the original amorphous/crystalline interface. The band can develop into a network and effectively getter the dopant. We discuss the conditions under which the various effects may or may not be observed, and discuss conflicting observations on As"+ implanted Si.

1984-11-26

360

Transient enhanced diffusion and gettering of dopants in ion implanted silicon  

Energy Technology Data Exchange (ETDEWEB)

The authors have studied in detail the transient enhanced diffusion observed during furnace or rapid-thermal-annealing of ion-implanted Si. The authors show that the effect originates in the trapping of Si atoms by dopant atoms during implantation, which are retained during solid-phase epitaxial (SPE) growth but released by subsequent annealing to cause a transient dopant precipitation or profile broadening. The interstitials condense to form a band of dislocation loops located at the peak of the dopant profile, which may be distinct from the band formed at the original amorphous/crystalline interface. The band can develop into a network and effectively getter the dopant. They discuss the conditions under which the various effects may or may not be observed, and discuss preliminary observations on As/sup +/ implanted Si. 12 references, 12 figures.

1986-01-01

361

Transient enhanced diffusion and gettering of dopants in ion implanted silicon  

Energy Technology Data Exchange (ETDEWEB)

We have studied in detail the transient enhanced diffusion observed during furnace or rapid-thermal-annealing of ion-implanted Si. We show that the effect originates in the trapping of Si atoms by dopant atoms during implantation, which are retained during solid-phase-epitaxial (SPE) growth but released by subsequent annealing to cause a transient dopant precipitation or profile broadening. The interstitials condense to form a band of dislocation loops located at the peak of the dopant profile, which may be distinct from the band formed at the original amorphous/crystalline interface. The band can develop into a network and effectively getter the dopant. We discuss the conditions under which the various effects may or may not be observed, and discuss conflicting observations on As/sup +/ implanted Si.

1984-01-01

362

Transient enhanced diffusion and gettering of dopants in ion implanted silicon  

International Nuclear Information System (INIS)

The authors have studied in detail the transient enhanced diffusion observed during furnace or rapid-thermal-annealing of ion-implanted Si. The authors show that the effect originates in the trapping of Si atoms by dopant atoms during implantation, which are retained during solid-phase epitaxial (SPE) growth but released by subsequent annealing to cause a transient dopant precipitation or profile broadening. The interstitials condense to form a band of dislocation loops located at the peak of the dopant profile, which may be distinct from the band formed at the original amorphous/crystalline interface. The band can develop into a network and effectively getter the dopant. They discuss the conditions under which the various effects may or may not be observed, and discuss preliminary observations on As"+ implanted Si. 12 references, 12 figures.

363

Suppression of transient enhanced diffusion following {ital in} {ital situ} photoexcitation during boron ion implantation  

Energy Technology Data Exchange (ETDEWEB)

The effect of {ital in} {ital situ} photoexcitation during boron ion implantation on subsequent transient enhanced B diffusion in Si has been investigated. Photoexcitation using a mercury arc lamp was performed during B{sup +} implantation at 35 keV for a dose of 5{times}10{sup 14} cm{sup {minus}2} at 177 K. A reduction in the electrical activation dip, i.e., reverse annealing effect, in the temperature range 550--700 {degree}C was observed. Also, the transient enhanced diffusion of B, measured using SIMS following 800 {degree}C, 30 min annealing, was suppressed. Both effects demonstrate that the creation of self-interstitials during the implantation process is significantly reduced. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}.

1995-10-09

364

Suppression of transient enhanced diffusion following in situ photoexcitation during boron ion implantation  

International Nuclear Information System (INIS)

The effect of in situ photoexcitation during boron ion implantation on subsequent transient enhanced B diffusion in Si has been investigated. Photoexcitation using a mercury arc lamp was performed during B"+ implantation at 35 keV for a dose of 5x10"1"4 cm"-"2 at 177 K. A reduction in the electrical activation dip, i.e., reverse annealing effect, in the temperature range 550--700 degree C was observed. Also, the transient enhanced diffusion of B, measured using SIMS following 800 degree C, 30 min annealing, was suppressed. Both effects demonstrate that the creation of self-interstitials during the implantation process is significantly reduced. copyright 1995 American Institute of Physics.

365

Plasma processing: a novel method to reduce the transient enhanced diffusion of boron implanted in silicon  

International Nuclear Information System (INIS)

In this paper a novel method is presented, based on the use of plasma processing, to suppress the transient enhanced diffusion of boron implanted in silicon. We found for silicon samples processed with plasma and subsequently boron implanted that the anomalous diffusion of the dopant atoms at the beginning of the annealing process is almost completely suppressed. This phenomenon is interpreted in terms of capture of the ion beam generated interstitials by the dislocations induced by the plasma processing. At room temperature the dislocations are observed to grow in size after the boron implant, attesting their efficiency as trapping centres for interstitials. Moreover, varying the plasma process conditions we can establish a general relation between the presence of the trapping centres induced by the plasma processing and the suppression of the transient diffusion.

1999-01-01

366

Enhanced diffusion from interstitial trapping during solid-phase-epitaxial growth of silicon alloys. Draft  

Energy Technology Data Exchange (ETDEWEB)

During the recrystallization by solid-phase-epitaxial (SPE) growth of supersaturated silicon alloys, a high concentration of interstitials is trapped. These are released by subsequent heating causing a transient (greatly enhanced) diffusion of the substitutional dopant by an interstitialcy mechanism. The enhancement may be as much as five orders of magnitude over tracer values, and shows an activation energy of only 1.8 +- 0.2 eV. Following the transient, the interstitials condense into loops, allowing an independent estimate to be made of their concentration. From these observations, we propose that during ion implantation, a fraction of the implanted dopants can acquire their natural valency, and retain it as the crystallization interface passes. For group V dopants this creates the trapped interstitials, giving transient enhanced diffusion when they are released by subsequent annealing.

1984-08-01

367

Enhanced diffusion from interstitial trapping during solid-phase-epitaxial growth of silicon alloys  

Energy Technology Data Exchange (ETDEWEB)

During the recrystallization by solid-phase-expitaxial (SPE) growth of supersaturated silicon alloys, a high concentration of interstitials is trapped. These are released by subsequent heating causing a transient (greatly enhanced) diffusion of the substitutional dopant by an interstitialcy mechanism. The enhancement may be as much as five orders of magnitude over tracer values, and shows an activation energy of only 1.8 +/- 0.2 eV. Following the transient, the interstitials condense into loops, allowing an independent estimate to be made of their concentration. From these observations, it is proposed that during ion implantation, a fraction of the implanted dopants can acquire their natural valency, and retain it as the crystallization interface passes. For group V dopants this creates the trapped interstitials, giving transient enhanced diffusion when they are released by subsequent annealing. 12 references, 6 figures.

1984-01-01

368

Effect of structure and thermal properties of the electrically heated rod on transient thermal-hydraulic experiment  

International Nuclear Information System (INIS)

The electrically heated rod is usually used as a substitute for fuel rod in thermal-hydraulic experiment. However, the different structure and thermal properties between nuclear fuel rod and electrically heated rod result in different steady-state distribution of temperature and stored energy and different response to thermal-hydraulic in simulation transient experiment. This paper analyses the effect of structure and thermal properties differences between nuclear fuel rod and electrically heated rod on experiment, and then introduce a feasible method, i.e. electric power is controlled by a program, to reduce the differences between the transient responses of nuclear fuel rod and electrically heated rod. At the same time, this paper points out the limits of the method. (authors)

2004-09-01

369

Benchmark analysis of rapid boron dilution transient by the PLASHY impact code  

International Nuclear Information System (INIS)

This paper describes the benchmark analysis results of Rapid Boron Dilution (RBD) transient tests. The RBD transient tests were carried out at University of Maryland. The data were obtained as a part of the International Standard Problem No. 43, ISP-43, for code assessment. Nuclear Power Engineering Corporation (NUPEC) participated the benchmark analysis of ISP443 with the PLASHY code. The PLASHY code is a general purpose single-phase fluid analysis code, developed by NUPEC. The code has two types of module, Cartesian/Cylindrical coordinate system module and BFC module. In order to reduce the computing time, the Cartesian/Cylindrical coordinate system module was employed. All calculations were done on a parallel computer, IBM SP2, by using the 12 of 76 CPU units. (author)

2000-10-01

370

ON-LINE MONITORING OF FLUE GAS DESULFURIZATION ...  

Science.gov (United States)

... Title : ON-LINE MONITORING OF FLUE GAS DESULFURIZATION SCRUBBER CORROSION WITH ELECTROCHEMICAL TECHNIQUES. ...

1986-11-01

371

Flue Gas Desulfurization and Low Btu Gasification - A ...  

Science.gov (United States)

... Accession Number : ADD419503. Title : Flue Gas Desulfurization and Low Btu Gasification - A Comparison Appendix G. ...

1975-05-01

372

Flue Gas Desulfurization and Its Alternatives: The State of the ...  

Science.gov (United States)

... Accession Number : ADD419981. Title : Flue Gas Desulfurization and Its Alternatives: The State of the Art,. Corporate Author ...

1974-11-01

374

Plant for processing sewage gas to natural-gas quality  

Energy Technology Data Exchange (ETDEWEB)

Sewage gas or biogas as a product of anaerobic digestion contains methane and carbon dioxide as its main components. Biogas is scrubbed off carbon dioxide in absorption columns and purified to natural-gas quality. The purified gas then is piped to the gas pressure control station and fed into the public network. Description of process and plant is given.

1983-09-01

375

Micro gas turbine operation with biomass producer gas  

Energy Technology Data Exchange (ETDEWEB)

We report the performance of a micro gas turbine on biomass producer gas and mixtures of biomass producer gas with natural gas. The micro gas turbine delivers full power on gas mixtures with a heating value of at least 15 MJ/Nm{sup 3}. For gas of lower heating value, the maximum fuel gas flow limits the attainable power. The lower limit for stable operation is about 8 MJ/Nm{sup 3}. The gross efficiency of the micro gas turbine depends on output power but not on the gas heating value, within our measurement accuracy. Above 70% of full power, emissions of CO and NO are 40 and 10 times lower than those of a gas engine of similar size. At part load below 70% of full power, the micro gas turbine burner switches to a different operating mode ...

2007-08-15

376

Wear resistant of Al{sub 2}O{sub 3}/heat-resistant steel at high temperature  

Energy Technology Data Exchange (ETDEWEB)

The high temperature abrasive wear resistant of the composites with different Al{sub 2}O{sub 3} volume fractions, particle coating and size were investigated and the failure action of composites under different conditions at high temperature was analyzed. The results showed that the high temperature abrasive wear resistant of composite with Ni coating and wide size and 39% volume fraction of particle is the best among all composites examined. (orig.)

2005-07-01

377

THE EFFECT OF FIBRE MISALIGNMENT ON THE ...  

Science.gov (United States)

... and testing of unidirectional composites, there are serious doubts about the possibility of obtaining a true ultimate compressive strength for this kind ...

388

MICROMECHANICS - COMPRESSIVE PROPERTIES OF ...  

Science.gov (United States)

... slenderness ratio. Equations which determine the ultimate compressive strength of a composite were established. Several ...

1965-05-01

391

Kevlar and carbon composites compared  

Energy Technology Data Exchange (ETDEWEB)

Characteristics of advanced composites are investigated. The fibers considered are Kevlar and carbon. The greatest advantage of composites over metals is emphasized, and lies in their permitting designers to obtain properties in exactly the locations desired. Kevlar replaced S-glass on the Trident 2 missile, saving 800 lbs. and adding 800 miles to its range. Military aircraft builders find that advanced carbon composites more often than not win out over Kevlar.

1985-02-01

402

Development and Fabrication of Compositions for 155-mm ...  

Science.gov (United States)

... Descriptors : *PROPELLING CHARGES, *NITROCELLULOSE, *COMBUSTIBLE CARTRIDGE CASES, DENSITY, FIBERS, MANUFACTURING ...

1982-10-01

408

An R&D Exploratory Investigation of Resin Binders for the ...  

Science.gov (United States)

... Descriptors : *POLYMERS, *BINDERS, *HOWITZERS, *COMBUSTIBLE CARTRIDGE CASES, CHEMICAL COMPOSITION, PROPELLING ...

1980-10-01

409

1993 - NASA  

Science.gov (United States)

... BUCKLING ANALYSIS OF METAL MATRIX COMPOSITE SANDWICH PANELS UNDER DIFFERENT THERMAL ENVIRONMENTS , Technical Memorandum ...

410

Zebrafish TRPA1 Channels are Required for Chemosensation but not for Thermosensation or Mechanosensory Hair Cell Function  

UK PubMed Central (United Kingdom)

Transient receptor potential (TRP) ion channels have been implicated in detecting chemical, thermal and mechanical stimuli in organisms ranging from mammals to Caenorhabditis elegans....Full Text Available

2008-10-01

411

Transient increase in glucose 1,6-bisphosphate in human skeletal muscle during isometric contraction.  

UK PubMed Central (United Kingdom)

Changes in glucose 1,6-bisphosphate and regulators of glucose-1,6-bisphosphate synthase and phosphatase during isometric contraction have been determined. Biopsies were obtained from the quadriceps...Full Text Available

1989-03-15

412

Transient enhanced diffusion of Sb and B due to MeV silicon implants  

Energy Technology Data Exchange (ETDEWEB)

We measure the transient enhanced diffusion of shallow molecular-beam-epitaxy grown marker layers of Sb and B due to deep MeV Si{sup +} ion implants at very high doses ({approx}10{sup 16}cm{sup {minus}2}). We expect the near-surface region of these implants to be vacancy rich, and we observe transient enhanced diffusion of Sb (the classic vacancy diffuser). The large enhancements imply a significant vacancy supersaturation ({approx}700 at 740{degree}C). Double implantation of the high-dose MeV Si followed by a shallow (40 keV) Si implant and annealing produces a greatly reduced number of {l_brace}311{r_brace} defects compared to a 40 keV implant into virgin Si, again consistent with a vacancy-rich region in the near-surface region of an MeV implant. However, the shallow B marker layers also show transient enhanced diffusion for the same MeV implant under similar annealing conditions, implying that an interstitial ...

1997-06-01

413

Transient enhanced diffusion of Sb and B due to MeV silicon implants  

International Nuclear Information System (INIS)

We measure the transient enhanced diffusion of shallow molecular-beam-epitaxy grown marker layers of Sb and B due to deep MeV Si"+ ion implants at very high doses (#approx#10"1"6cm"-"2). We expect the near-surface region of these implants to be vacancy rich, and we observe transient enhanced diffusion of Sb (the classic vacancy diffuser). The large enhancements imply a significant vacancy supersaturation (#approx#700 at 740 degree C). Double implantation of the high-dose MeV Si followed by a shallow (40 keV) Si implant and annealing produces a greatly reduced number of #left brace#311#right brace# defects compared to a 40 keV implant into virgin Si, again consistent with a vacancy-rich region in the near-surface region of an MeV implant. However, the shallow B marker layers also show transient enhanced diffusion for the same MeV implant under similar annealing conditions, implying that an interstitial supersaturation is ...

414

Transient enhanced diffusion in ion-implanted silicon  

Energy Technology Data Exchange (ETDEWEB)

We discuss the transient-enhanced diffusion of Sb, As, P, In, Ga, and B in ion-implanted Si, where the near-surface region has been amorphized by the dopant or by a self-implantation process. With Sb, a large transient diffusion enhancement is observed proportional to dopant concentration. For Sb, As, P, and In, the enhancement follows the relative interstitialcy diffusion coefficient. We believe this behavior is caused by stable implantation-induced point defects present in the amorphous surface layer, which decay during thermal processing to release high concentrations of self-interstitials. This process occurs in competition with the solid phase epitaxial (SPE) growth process, and for high dopant concentrations can occur in the amorphous phase ahead of the crystallization front. We believe this may be the origin of the dopant redistribution which can occur during SPE growth, which sets the upper limit to the dopant concentration which can be ...

1987-03-01

415

Transient and Persistent Hypercalcaemia in Patients Treated by Maintenance Haemodialysis  

UK PubMed Central (United Kingdom)

In a group of 32 patients with terminal renal failure the initial hypocalcaemia was corrected after two months' adequate maintenance haemodialysis. In seven patients hypercalcaemia occurred with a...Full Text Available

1968-10-19

416

Transient Hoogsteen Base Pairs in Canonical Duplex DNA  

UK PubMed Central (United Kingdom)

Sequence-directed variations in the canonical DNA double helix structure that retain Watson-Crick base-pairing play important roles in DNA recognition, topology, and nucleosome positioning....Full Text Available

2011-02-24

417

Transcatheter Arterial Embolization in Patients with Kidney Diseases: an Overview of the Technical Aspects and Clinical Indications  

UK PubMed Central (United Kingdom)

Therapeutic embolization is defined as the voluntary occlusion of one or several vessels, and this is achieved by inserting material into the lumen to obtain transient or permanent thrombosis in the...Full Text Available

2010-05-01

418

Temperature-induced opening of TRPV1 ion channel is stabilized by the pore domain  

UK PubMed Central (United Kingdom)

SummaryTRPV1 is the founding and best-studied member of the family of temperature-activated transient receptor potential ion channels (thermoTRPs). Voltage, chemicals, and heat...Full Text Available

2010-06-01

419

Study on the transient piping vibration of power plant. Secondary piping system of Wolsung 1 unit.  

Science.gov (United States)

In order to maintain a safe operation and availability of generating facilities, qualitative and quantitative assessment of piping vibration was performed vibration sources and damages of piping support was identified on the second piping system of Wolsun...

1996-01-01

420

Spatiotemporal intracellular calcium dynamics during cardiac alternans  

UK PubMed Central (United Kingdom)

Cellular calcium transient alternans are beat-to-beat alternations in the peak cytosolic calcium concentration exhibited by cardiac cells during rapid electrical stimulation or under pathological conditions....Full Text Available

2009-09-01

421

Solution structure of two molecular motor domains: nonclaret disjunctional and kinesin.  

UK PubMed Central (United Kingdom)

The effects of selected ligands on the structure of the truncated heavy-chain chemomechanical motor domains of Drosophila ncd and human kinesin were compared using the technique of transient electric...Full Text Available

1995-04-01

422

SCDAP/RELAP5/MOD 3.1 code manual: Interface theory. Volume 1  

Energy Technology Data Exchange (ETDEWEB)

The SCDAP/RELAP5 code has been developed for best estimate transient simulation of light water reactor coolant systems during a severe accident. The code models the coupled behavior of the reactor coolant system, core, fission product released during a severe accident transient as well as large and small break loss of coolant accidents, operational transients such as anticipated transient without SCRAM, loss of off-site power, loss of feedwater, and loss of flow. A generic modeling approach is used that permits as much of a particular system to be modeled as necessary. Control system and secondary system components are included to permit modeling of plant controls, turbines, condensers, and secondary feedwater conditioning systems. This volume describes the organization and manner of the interface between severe accident models which are resident in the SCDAP portion of the code and hydrodynamic models ...

1995-06-01

423

Ring opening reaction dynamics of a photochromic diarylethene derivative dye  

International Nuclear Information System (INIS)

Ring opening dynamics of diarylethene derivative (BTF6) in n-hexane are studied by femtosecond transient absorption and time resolved spontaneous fluorescence techniques. Cyclo-reversion time constant is obtained.

2001-11-01

424

Proteomic approach with LCMS-IT-TOF identified an increase of Rab33B after transient focal cerebral ischemia in mice  

UK PubMed Central (United Kingdom)

BackgroundSeveral proteins are known to be markedly expressed in the brain during cerebral ischemia; however, the changes in protein profiles within the ischemic brain after an ischemic...Full Text Available

425

On the spontaneous stochastic dynamics of a single gene: complexity of the molecular interplay at the promoter  

UK PubMed Central (United Kingdom)

BackgroundGene promoters can be in various epigenetic states and undergo interactions with many molecules in a highly transient, probabilistic and combinatorial way, resulting in...Full Text Available

426

Numerical Simulation and Analyses of the Loss of Feedwater Transient at the Unit 4 of Kola NPP  

Science.gov (United States)

A three-dimensional numerical simulation of the loss-of-feed water transient at the horizontal steam generator of the Kola nuclear power plant is performed. Presented numerical results show transient change of integral steam generator parameters, such as steam generation rate, water mass inventory, outlet reactor coolant temperature, as well as detailed distribution of shell side thermal-hydraulic parameters: swell and collapsed levels, void fraction distributions, mass flux vectors, etc. Numerical results are compared with measurements at the Kola NPP. The agreement is satisfactory, while differences are close to or below the measurement uncertainties. Obtained numerical results are the first ones that give complete insight into the three-dimensional and transient horizontal steam generator thermal-hydraulics. Also, the presented results serve as benchmark tests for the assessment and further improvement of one-dimensional ...

2002-07-01

427

Novel Human Erythrovirus Associated with Transient Aplastic Anemia  

UK PubMed Central (United Kingdom)

Erythrovirus (formerly parvovirus) B19 causes a wide range of diseases in humans, including anemia due to aplastic crisis. Diagnosis of B19 infection relies on serology and the detection of viral DNA...Full Text Available

1999-08-01

428

Mechanism for transient-enhanced diffusion in ion-implanted silicon  

International Nuclear Information System (INIS)

High-dose ion implantation followed by solid-phase-epitaxial (SPE) growth is now a well-established technique for the production of supersaturated silicon alloys. However, these alloys also contain a high supersaturation of silicon interstitials, which give rise to transient, greatly enhanced dopant diffusion with subsequent heating. In this contribution, the authors present a study of a series of Si-Sb alloys of various concentrations which were made by Sb implantation under various conditions to deduce the origin of the observed transient diffusion. A multiple implant scheme was employed to produce samples with an approximately uniform dopant concentration from 40 to 150 nm in depth, but with the amorphous layer extending to a depth of 380 nm. By scaling the implant doses, alloys with different concentrations in the uniform region were produced, allowing an accurate measure of diffusion coefficients as a function of concentration. Diffusion ...

1985-03-01

429

MFR, a Putative Receptor Mediating the Fusion of Macrophages  

UK PubMed Central (United Kingdom)

We had previously identified a macrophage surface protein whose expression is highly induced, transient, and specific, as it is restricted to actively fusing macrophages in vitro and in vivo. This protein...Full Text Available

1998-11-01

430

MEG demonstrates a supra-additive response to facial and vocal emotion in the right superior temporal sulcus  

UK PubMed Central (United Kingdom)

An influential neural model of face perception suggests that the posterior superior temporal sulcus (STS) is sensitive to those aspects of faces that produce transient visual changes, including facial...Full Text Available

2009-11-24

431

Long-Lasting Inhibitory Effects of Fetal Liver Mesenchymal Stem Cells on T-Lymphocyte Proliferation  

UK PubMed Central (United Kingdom)

Human bone marrow mesenchymal stem cells (BM-MSC) are multipotent progenitor cells that have transient immunomodulatory properties on Natural Killer (NK) cells, Dendritic Cells (DC), and T cells. This...Full Text Available

432

Life Span Extension in Mice by Food Restriction Depends on an Energy Imbalance12  

UK PubMed Central (United Kingdom)

In this study, our main objective was to determine whether energy restriction (ER) affects the rate of oxygen consumption of mice transiently or lastingly and whether metabolic rate plays a role in...Full Text Available

2009-03-01

433

Iron Metabolism in the Anaemia of Chronic Renal Failure. Effects of Dialysis and of Pareuteral Iron  

UK PubMed Central (United Kingdom)

Serial studies of iron transport in patients on maintenance dialysis showed normal or raised values in almost all subjects and a transient increase soon after the start of dialysis in three. These...Full Text Available

1969-07-26

434

In vitro selection of RNA molecules that displace cocaine from the membrane-bound nicotinic acetylcholine receptor  

UK PubMed Central (United Kingdom)

The nicotinic acetylcholine receptor (AChR) controls signal transmission between cells in the nervous system. Abused drugs such as cocaine inhibit this receptor. Transient kinetic investigations indicate...Full Text Available

1998-11-24

435

IGENPRO knowledge-based digital system for process transient diagnostics and management  

Energy Technology Data Exchange (ETDEWEB)

Verification and validation issues have been perceived as important factors in the large scale deployment of knowledge-based digital systems for plant transient diagnostics and management. Research and development (R&D) is being performed on the IGENPRO package to resolve knowledge base issues. The IGENPRO approach is to structure the knowledge bases on generic thermal-hydraulic (T-H) first principles and not use the conventional event-basis structure. This allows for generic comprehensive knowledge, relatively small knowledge bases and above all the possibility of T-H system/plant independence. To demonstrate concept feasibility the knowledge structure has been implemented in the diagnostic module PRODIAG. Promising laboratory testing results have been obtained using data from the full scope Braidwood PWR operator training simulator. This knowledge structure is now being implemented in the transient management module PROMANA to treat ...

1997-12-31

436

GCN/Fermi GRB and Transient Notices - GCN - NASA  

Science.gov (United States)

The GBM location uncertainties range from 5-15deg (radius, 1 sigma, stat+sys). ... The site's dis/enabling on Notice types and their other filter criteria .... Fermi Pointing Direction Notice gives the current pointing direction of the ...

437

Ethylene Regulates Monomeric GTP-Binding Protein Gene Expression and Activity in Arabidopsis1  

UK PubMed Central (United Kingdom)

Ethylene rapidly and transiently up-regulates the activity of several monomeric GTP-binding proteins (monomeric G proteins) in leaves of Arabidopsis as determined by two-dimensional gel electrophoresis...Full Text Available

2003-04-01

438

Energetic constraints on the creation of cell membrane pores by magnetic particles.  

UK PubMed Central (United Kingdom)

Naturally occurring and contaminant ferromagnetic and ferrimagnetic particles have been found within or near cells, and might allow pulsed magnetic fields to create transient cell membrane opening ("pores")....Full Text Available

1996-08-01

439

Ectopic Expression of Constitutively Activated RACB in Barley Enhances Susceptibility to Powdery Mildew and Abiotic Stress1  

UK PubMed Central (United Kingdom)

Small RAC/ROP-family G proteins regulate development and stress responses in plants. Transient overexpression and RNA interference experiments suggested that the barley (Hordeum vulgare)...Full Text Available

2005-09-01

440

Data report of BWR post-CHF tests. Transient core thermal-hydraulic test program. Contract research  

Energy Technology Data Exchange (ETDEWEB)

JAERI has been performing transient core thermal-hydraulic test program. In the program, authors performed BWR/ABWR DBE simulation tests with a test facility, which can simulate BWR/ABWR transients. The test facility has a 4 x 4 bundle core simulator with 15-rod heaters and one non-heated rod. Through the tests, authors quantified the thermal safety margin for core cooling. In order to quantify the thermal safety margin, authors collected experimental data on post-CHF. The data are essential for the evaluation of clad temperature transient when core heat-up occurs during DBEs. In comparison with previous post-CHF tests, present experiments were performed in much wider experimental condition, covering high clad temperature, low to high pressure and low to high mass flux. Further, data at wider elevation (lower to higher elevation of core) were obtained in the present experiments, which make possible to discuss the effect of ...

2001-03-01

441

Basic processes in internal combustion engines. 1989  

Energy Technology Data Exchange (ETDEWEB)

This book contains 8 papers including the topics of: Spray and Flame Structure in Diesel Combustion; Experimental and Theoretical Investigations of Diesel Injection Transients; Lead-Fuel Governor System - Dual-Fuel Engine; Fuel Spray Modeling in Swirling Flows.

1989-01-01

442

Auxins Induce Tryptophan Decarboxylase Activity in Radicles of Catharanthus Seedlings 1  

UK PubMed Central (United Kingdom)

Germinating seedlings of Catharanthus roseus produce monoterpenoid indole alkaloids as a result of a transient increase of tryptophan decarboxylase (TDC) activity. The influence of...Full Text Available

1992-10-01

443

Association of Thyroid Hormone Concentrations with Levels of Organochlorine Compounds in Cord Blood of Neonates  

UK PubMed Central (United Kingdom)

BackgroundThyroid hormones are important regulators of brain development. During critical periods of development, even transient disorders in thyroid hormone availability may lead...Full Text Available

2007-12-01

444

Assessment of RELAP5/MOD3/CANDU"+ to Wolsung-1 D_2O leakage event  

International Nuclear Information System (INIS)

In order to evaluate the integrated performance of RELAP5/MOD3/CANDU"+ for CANDU operational transient analysis, we assesed the code to the D_2O leakage event occurred at Wolsung-I, 600 MW(e) CANDU reactor, on Oct. 20, '94. D_2O leakage event was initiated by stuck opening of liquid relief valve No.4 in primary coolant pressure and level control system. Assessment calculation was performed for the plant transients up to 1000 seconds after the initiating event. Calculation results are compared with those measured in primary heat transport system, pressure and inventory control system and boiler secondary system. Comparison with the plant trip log shows that the RELAP5/CANDU"+ is able to simulate the plant transients properly, from which we can conclude that the RELAP5/CANDU"+ is validated for application to CANDU operational transient analysis. CANDU specific models used in the assessment are fuel bundle ...

2001-10-01

445

ADP-Glucose Pyrophosphorylase, a Regulatory Enzyme for Bacterial Glycogen Synthesis  

UK PubMed Central (United Kingdom)

The accumulation of α-1,4-polyglucans is an important strategy to cope with transient starvation conditions in the environment. In bacteria and plants, the synthesis of glycogen and starch occurs...Full Text Available

2003-06-01

446

A Hot New Twist to Hair Biology  

UK PubMed Central (United Kingdom)

The vanilloid receptor-1 (VR1, or transient receptor potential vanilloid-1 receptor, TRPV1) is activated by capsaicin, the key ingredient of hot peppers. TRPV1 was originally described on sensory neurons...Full Text Available

2005-04-01

447

Role of additives in wood plastic composite of water soluble monomer  

International Nuclear Information System (INIS)

Wood plastic composites are prepared under radiation of "6"0Co gamma source with simul, a low grade wood of Bangladesh using a water soluble monomer acrylamide (AM) mixed with a swelling solvent methanol, water or methanol/water (1:1) at different compositions in the presence of a number of additives and co-additives such as NVP (N-vinylpyrrolidone), TPGDA (tripropylene glycol diacrylate), TMPTA (trimethylol propane triacrylate), sulfuric acid, urea and copper sulfate. Polymer loading (PL) and tensile strength (TS) of the composites are measured. The role of these additives on the composites is also discussed. It is observed that nitrogen-atom containing-materials like urea, NVP and AM produce composites with the highest mechanical strength, and incorporation of copper into this system provides additional property of protection and preservation of the composites ...

1994-01-01

448

Glass Furnace Combustion and Melting Research Facility.  

Energy Technology Data Exchange (ETDEWEB)

The need for a Combustion and Melting Research Facility focused on the solution of glass manufacturing problems common to all segments of the glass industry was given high priority in the earliest version of the Glass Industry Technology Roadmap (Eisenhauer et al., 1997). Visteon Glass Systems and, later, PPG Industries proposed to meet this requirement, in partnership with the DOE/OIT Glass Program and Sandia National Laboratories, by designing and building a research furnace equipped with state-of-the-art diagnostics in the DOE Combustion Research Facility located at the Sandia site in Livermore, CA. Input on the configuration and objectives of the facility was sought from the entire industry by a variety of routes: (1) through a survey distributed to industry leaders by GMIC, (2) by conducting an open workshop following the OIT Glass Industry Project Review in September 1999, (3) from discussions with numerous glass engineers, scientists, and executives, and (4) during visits to ...

2004-08-01

449

Spectroscopy of color centers in yttrium-aluminium perovskite crystals  

International Nuclear Information System (INIS)

The color centers, which are generated in yttrium-aluminium perovskite (YAP):Nd(1 at.%) and YAP:Er(50 at.%) crystals under the influence of ultraviolet and #gamma#-irradiation, have been studied by absorption spectroscopy. The generated color centers are both stable and transient at room temperature. It is shown that the transient color centers are mainly responsible for the decrease of laser generation efficiency of Nd:YAP and YAP:Er irradiated crystals, although physical mechanisms leading to efficiency decrease are different in these materials. (orig.)

1998-07-24

450

Safe hole trapping, light soaking and secondary photocurrent transients in amorphous silicon  

International Nuclear Information System (INIS)

A new analysis is developed for long secondary photocurrent transients which gives the distribution of trapped holes in valence band tail states. Thermally assisted tunneling to dangling bonds is implicated as the rate limiting step in hole-recombination. Light-soaking causes the energetically deeper hole traps with the longer residence times to be lost first and in the same number as would be expected for the increase in dangling bonds; This result supports a model which has hole trapping in valence tail states as a precursor to light induced dangling bonds.

1988-09-26

451

SM-2--HORIZONTAL STEAM GENERATOR ANALYSIS  

Science.gov (United States)

ABS>A horizontal steam generator design for the SM-2 was lysis to determine the per formance of such a steam generator under steady state operating conditions and during load transients, The configuration for this design is a two- drum unit consisting of a heat exchanger unit and separator drum interconnected by integral riser and downcomer. An analog computer was used to analyze the steam generator behavior Wring load transients. The effect of various design changes on the response of the steam generator to step chages in load was determined. The horizontal steam generator design was compared to the existing vertical steam generator design for weight, size, price, and performance. (auth)

1959-11-01

452

Out-of-pile simulation of mild TOPs; development of pin failure, material movement and relocation in bundle geometry  

International Nuclear Information System (INIS)

An experimental technique is described which allows for parametric investigations of transient behavior of mobile core materials in a fuel bundle geometry. For the out-of-pile simulation of energy releases resulting from mild TOP- or LOF-accidents the exothermic reaction of an aluminium-oxide-thermite is used. Transient material relocation inside the test section is recorded by X-ray-cinematography. Results of some experiments recently performed close to conditions expected to be achieved during mild TOP-accidents are described in detail.

1979-08-23

453

Nastran nonlinear dynamic transient accident analysis for FFTF reactor component  

International Nuclear Information System (INIS)

A nonlinear dynamic transient analysis merging hand calculations and the NASTRAN structural analysis computer code was conducted for a Fast Flux Test Facility in-reactor test assembly during an extremely unlikely design basis accidental event which is considered a Hypothetical Core Disruptive Accident (HCDA). The finite element modeling of the problem took advantage of NASTRAN's versatility to create loads and nonlinear elements not previously found in NASTRAN's library. The structural criteria for the test assembly to withstand an HCDA stipulates that the test assembly and its spoolpiece shall remain integral with the reactor head such that missiles are not generated.

1976-11-15

454

Monte Carlo simulations and experimental validations of #alpha# eigenvalues - 091  

International Nuclear Information System (INIS)

A Monte Carlo method called transient curve fitting method was developed to calculate a eigenvalues by first simulating the existing neutrons and precursors in the system, then calculating the Eigen-distribution of neutron flux and calculating the a eigenvalues using the transient results based on the Eigen-distribution by the code TMCC. The results of this method are tested by calculating Godiva Benchmark problems and they agree well with the benchmark results. Then the reasonable results of Subcritical Facility in Tsinghua University are given by TMCC, and the results are compared with the experimental results measured by Rossi-a method. Even in the deep subcritical cases, the method can give results consistent with experimental results. (authors)

2010-05-09

455

Modeling of dislocation loop growth and transient enhanced diffusion in silicon for amorphizing implants  

Energy Technology Data Exchange (ETDEWEB)

It has been observed that dislocation loops form and grow during annealing of silicon wafers implanted at doses above the amorphization threshold. Dislocation loops can act to store interstitials for prolonged periods of anneals, sustaining an interstitial super-saturation and thus causing substantial transient enhanced diffusion (TED). The authors have developed a comprehensive model which, in combination with a model and parameters for {l_brace}311{r_brace} defects from previous work, accounts for the formation and evolution of dislocation loops during ion implant annealing, as well as giving the correct TED behavior.

1997-11-01

456

Modeling of dislocation loop growth and transient enhanced diffusion in silicon for amorphizing implants  

International Nuclear Information System (INIS)

It has been observed that dislocation loops form and grow during annealing of silicon wafers implanted at doses above the amorphization threshold. Dislocation loops can act to store interstitials for prolonged periods of anneals, sustaining an interstitial super-saturation and thus causing substantial transient enhanced diffusion (TED). The authors have developed a comprehensive model which, in combination with a model and parameters for #left brace#311#right brace# defects from previous work, accounts for the formation and evolution of dislocation loops during ion implant annealing, as well as giving the correct TED behavior.

1996-12-02

457

Initiation transient in dilute explosives  

Energy Technology Data Exchange (ETDEWEB)

In the context of the shock-initiation problem, we study analytically the first effects of chemistry, treating a small chemical heat release as a perturbation on an inert flow. Specifically, we study the initial transient in plane-shock initiation in a dilute explosive, where the chemical energy is small relative to the mechanical-thermal energy. The vehicle for the study is the mathematical analog for reactive flow. The solution resembles a double refraction: to first order, the pressure or density is a superposition of two forward-going waves, both originating at the rear boundary, and carrying the same function, but running at different velocities. Surprisingly, this first-order solution is independent of the sensitivity of the reaction rate to the state, which appears only at second order.

1981-01-01

458

Fast starting cold shield cooling circuit for superconducting generators  

Energy Technology Data Exchange (ETDEWEB)

An apparatus is provided for rapidly restarting the flow of coolant through the cold electromagnetic shield of a superconducting rotor following a thermal transient episode. A vortex diode inhibits coolant flow in the undesirable reverse direction and encourages the reestablishment of a normal thermosyphon cooling loop flow quickly following the termination of a thermal transient such as that caused by transmission line faults. The present invention requires no moving parts and may therefore be permanently sealed in the superconducting rotor without risk of costly repair efforts caused by components failure.

1982-12-21

459

Damping of capacitance voltage substations ferroresonance using a suitable RLC filter  

Energy Technology Data Exchange (ETDEWEB)

The underlying theory and model of capacitive voltage substations and its associated problems are described. This system is intended to supply electricity to rural communities directly from high-voltage transmission lines. This technique leads to important cost reductions when compared with conventional alternatives. However, in several transient cases, some problems such as ferroresonance and overvoltages could occur in these substations. Using a developed capacitive substation model these transient cases are simulated. A suitable filter is designed to damp overvoltages clue to ferroresonance. Analytical aspects of filter design are presented and some computer simulation tests are provided to highlight the usefulness of the proposed filter. (author)

2004-11-01

460

Application of self-adaptive procedure to the thermal problems analysis under steady-state and transient regimens; Aplicacao de procedimento auto-adaptativo na analise de problemas termicos no regime permanente e transiente  

Energy Technology Data Exchange (ETDEWEB)

This work describes a procedure for the adaptive time dependent Finite Element Method using an automatic mesh refinement (H-Version) that efficiently reduces estimated errors ( a posteriori) below pre-assigned limits. Classical model problem for steady-state heat transfer are investigated, and the results are compared with the analytical solution. Then some typical time-dependent problem are qualitatively analysed. (author) 10 refs., 7 figs.

1990-12-31

461

Acceptance test of full scope simulator of Daya Bay NPP  

International Nuclear Information System (INIS)

The author describes the purpose, classification and main process of acceptance test of full scope simulator of Daya Bay Nuclear Power Plant, including the correction of non-conformance items which are discovered during the performance of acceptance tests. The results of the acceptance tests show that the model accepted by the full scope simulator of Daya Bay Nuclear Power Plant is fully able to cope with the simulation of normal transients and incidental transients and the performance of the simulator indeed compiled with the technical specifications which are defined n the relevant contracts.

462

Electrodeless lamp energized by microwave energy  

Energy Technology Data Exchange (ETDEWEB)

This patent describes an electrodeless lamp. It comprises: a microwave cavity; a source of microwaves in communication with the cavity; a lamp envelope containing a plasma-forming medium mounted within the microwave cavity; a gas manifold for feeding gas to at least one gas passageway for directing a stream of gas to the outer surface of the envelope; a gas leak passageway leading from the gas manifold; a conductive mesh assembly for retaining microwaves within the cavity and permitting light to be emitted from the cavity. The assembly including gas flow blocking means for preventing the flow of gas through the gas leak passageway when the screen is in place in the lamp; and means for shutting off the source of microwaves when the gas pressure in the manifold drops below a ...

1990-01-16

463

Thermal characterization of rubberwood-polymer composites  

International Nuclear Information System (INIS)

The thermal properties of five types of radiation-induced wood-polymer composites based on a tropical hardwood, rubberwood (Hevea braziliensis), was studied by oxygen index measurement, differential thermal analysis (DTA) and thermogravimetry (TG). The DTA and TG curves of composites were different from those of rubberwood, which can be attributed to the presence of the incorporated polymers. Of the five composites, the one impregnated with bis(2-chloroethyl)vinyl phosphonate reduced the initial temperature of decomposition, increased the peak temperatures of exothermic reactions, and increased the char yield. Comparison with physical blends of rubberwood and the corresponding polymer provided some evidence of chemical interaction of wood and polymer in some of the composites. (author).

1989-01-01

464

Radiation induced polymerization of vinyl monomers and their application for preparation of wood-polymer composites  

International Nuclear Information System (INIS)

Polymerizing effects of high energy radiation has been found suitable for preparation of wood-polymer composites. In the present work after evaluating polymer products that have been obtained by irradiation method, wood-polymer composites have been prepared by in situ polymerization of vinyl acetate, acrylic acid and acrylic acid/styrene mixture using two samples of Iranian hardwoods, Beech and Hornbeam. These woods and their composites have been tested for their physical and mechanical properties. The results have shown that chemical bonding between polymer and the cell wall component lead to better strength properties in the composites. (author).

1992-09-01

465

Flue gas desulfurization pilot study. phase i. survey of major installations. report no. 95. summary of survey reports on flue gas desulfurization processes  

Science.gov (United States)

Appendices to this summary consist of twelve individual status reports that will be available through the National Technical Information Service (NTIS) in the United States and of course limited copies will be available through NATO. The twelve report titles which are appendices to the summary are: (A) Status Report on the Limestone/Sludge Flue Gas Desulfurization Process; (B) Status Report on the Lime/Sludge Flue Gas Desulfurization Process; (C) Status Report on the Double Alkali/Sludge Flue Gas Desulfurization Process; (D) Status Report on the Sea Water Scrubbing Flue Gas Desulfurization Process; (E) Status Report on the Limestone/Gypsum Flue Gas Desulfurization Process; (F) Status Report on the Lime/Gypsum Flue Gas Desulfurization Process; (G) Status Report on the Double Alkali/Gypsum Flue Gas Desulfurization Process; (H) Status Report on ...

1979-01-01

466

Surface states and wear behavior of drills of ground, sandblasted and plasmanitrided samples and drills made of AISI M2 high speed steel; Einfluss unterschiedlicher Oberflaechenzustaende vor dem Plasmanitrieren auf Eigenschaften und Zerspanungsverhalten des Schnellarbeitsstahls S 6-5-2  

Energy Technology Data Exchange (ETDEWEB)

In the present work the effect of different surface conditions on plasma nitriding response of AISI M2 high speed steel was investigated. The plasma nitriding of ground and sandblasted samples and drills was performed at temperatures of 400 C and 500 C for two gas mixtures: 5 vol.% N{sub 2} and 76 vol.% N{sub 2} in hydrogen. Surface layers were characterized before and after plasma nitriding concerning the microstructure, roughness, microhardness, chemical composition, phase composition and residual stress states. Machining tests were carried out with drills during which drilling forces and flank wear have been measured. A significant effect of the surface state prior to nitriding on residual stress states and the properties of the nitrided layer and untreated core has been observed. Thinner nitrided layers on ground and sandblasted samples were attributed to high compressive residual stress states and a stress affected ...

2003-01-01

467

The nature of gas hydrates  

Energy Technology Data Exchange (ETDEWEB)

Gas hydrates have impacted the oil and gas industry since 1934, when they were first found to plug pipelines. Today we know that in deep oceans and in permafrost, very substantial gas reserves are present in hydrated form. Concerns are being raised about in situ dissociation for both energy and greenhouse implications upon methane release. In Japan work is underway to consider the storage of carbon dioxide, concentrated in clathrates. This talk will deal with some basic questions. Why should we be interested in gas hydrates? What are gas hydrates? How do gas hydrates form? How might hydrates impact on the energy/environmental picture?

1995-12-31

468

Gaseous dielectrics V  

Energy Technology Data Exchange (ETDEWEB)

This book discusses the progress and problems of current interest in gaseous dielectrics and their use, with special emphasis on insulation in high-voltage transmission lines and substations. Topics covered include: basic physics of gaseous dielectrics; basic mechanisms; gas decomposition, reactions and toxicity; diagnostics and field probes; gases and mixtures for GIS transformers and circuit breakers; gaseous media for discharge chemistry and etching/corona; gas engineering for pulsed power and switching; gas breakdown under steep-fronted voltages; new developments in gas-insulated equipment and gas handling; gas/insulator interface/flashover; and quality control in testing gas-insulated equipment. Contains approximately 85 papers.

1987-01-01

469

Catalytic hydrothermal gasification of biomass for the production of synthetic natural gas[Dissertation 17100  

Energy Technology Data Exchange (ETDEWEB)

Energy from biomass is a CO{sub 2} neutral, sustainable form of energy. Anaerobic digestion is an established technology for converting biomass to biogas, which contains around 60% methane, besides CO{sub 2} and various contaminants. Most types of biomass contain material that cannot be digested; in woody biomass, this portion is particularly high. Therefore, conventional anaerobic digestion is not suited for the production of biogas from woody biomass. While wood is already being converted to energy by conventional thermal methods (gasification with subsequent methanation), dung, manure, and sewage sludge represent types of biomass whose energy potential remains largely untapped (present energetic use of manure in Switzerland: 0.4%). Conventional gas phase processes suffer from a low efficiency due to the high water content of the feed (enthalpy of vaporization). An alternative technology is the hydrothermal gasification: the water contained within the biomass ...

2007-07-01

470

Development of a thermographic measurement process as an alternative to gravimetry in determining Diesel engine particle emission. Final report; Entwicklung eines thermographischen Messverfahrens als Alternative zur Gravimetrie bei der Ermittlung von Dieselpartikel-Emissionen. Abschlussbericht  

Energy Technology Data Exchange (ETDEWEB)

Against the background of more severe limitation of particle emission in all application areas of Diesel engines, it is necessary to monitor the particle emission, but also the chemical composition of the particles. The basis of assessing particle emission is formed by gravimetric determination of the particle concentration from exhaust gas diluted with particle-free ambient air, with a maximum temperature of 52 degrees C at the sampling position. While it is already possible, using the part flow dilution system, to take samples locally, previously the subsequent particle determination and characterisation could only be done in a chemical laboratory. For this reason, the C/S particle measurement process was developed as an alternative to gravimetry, which can be used locally, eg: on ships and which makes it possible to determine the particle mass and composition. This process is based on a thermographic carbon and sulphate ...

1994-12-31

471

Well log evaluation of natural gas hydrates  

Energy Technology Data Exchange (ETDEWEB)

Gas hydrates are crystalline substances composed of water and gas, in which a solid-water-lattice accommodates gas molecules in a cage-like structure. Gas hydrates are globally widespread in permafrost regions and beneath the sea in sediment of outer continental margins. While methane, propane, and other gases can be included in the clathrate structure, methane hydrates appear to be the most common in nature. The amount of methane sequestered in gas hydrates is probably enormous, but estimates are speculative and range over three orders of magnitude from about 100,000 to 270,000,000 trillion cubic feet. The amount of gas in the hydrate reservoirs of the world greedy exceeds the volume of known conventional gas reserves. Gas hydrates also represent a significant drilling and production hazard. A fundamental question ...

1992-10-01

472

Well log evaluation of natural gas hydrates  

Energy Technology Data Exchange (ETDEWEB)

Gas hydrates are crystalline substances composed of water and gas, in which a solid-water-lattice accommodates gas molecules in a cage-like structure. Gas hydrates are globally widespread in permafrost regions and beneath the sea in sediment of outer continental margins. While methane, propane, and other gases can be included in the clathrate structure, methane hydrates appear to be the most common in nature. The amount of methane sequestered in gas hydrates is probably enormous, but estimates are speculative and range over three orders of magnitude from about 100,000 to 270,000,000 trillion cubic feet. The amount of gas in the hydrate reservoirs of the world greedy exceeds the volume of known conventional gas reserves. Gas hydrates also represent a significant drilling and production hazard. A fundamental question ...

1992-10-01

473

Micro Gas Turbine Operation with Biomass Producer Gas and Mixtures of Biomass Producer Gas and Natural Gas  

Energy Technology Data Exchange (ETDEWEB)

We report the performance of a commercial recuperated micro gas turbine on biomass producer gas and mixtures of biomass producer gas with natural gas. The biomass producer gas, obtained by gasification at 850{sup o}C with air at atmospheric pressure, contains about 7% H2, 17% CO, 15% CO2, 4% CH4, 2% other hydrocarbons, 2% H2O, and a balance of N2 and Ar from air. It has a net heating value of about 6 MJ/(Nm{sup 3}). The micro gas turbine delivers full power (30 kW{sub e}) on gas mixtures with a net heating value of at least 15 MJ/(Nm{sup 3}). For gas of lower heating value, the maximum fuel gas flow allowed by the fuel control unit limits the attainable power. At reduced power, the lower limit for stable operation is a net heating value of about 8 MJ/(Nm{sup 3}). The gross efficiency of the micro ...

2007-08-15

474

Preparation of polyester/gypsum/composite using gamma radiation, and its radiation stability  

Energy Technology Data Exchange (ETDEWEB)

Composites based on pure gypsum and polyester-styrene resin have been prepared using various doses of gamma radiation. Some physical properties of the prepared composites and the influence of irradiation dose on it have been studied as: compression strength, hardness, thermal decomposition temperature in nitrogen or oxygen, and the change in weight in aqueous solutions with different pH values. The glass transition temperature of the pure polymer and the composites increases with increasing the irradiation dose up to a plateau, and the glass transition temperature of the pure polymer is lower than that of the composites. The irradiation dose does not seem to affect the decomposition temperature of the pure polymer or the composites significantly and the decomposition temperature in presence of nitrogen is higher than that in presence of oxygen. Increasing the irradiation dose leads ...

2005-06-01

475

Preliminary study on the development of EFB Fibre-sago starch composites: impact and flexural properties  

International Nuclear Information System (INIS)

There is growing interest in the use of natural fibres as the reinforcements for polymer composites in the automotive industry and as matrix for composites in building products application to replace synthetic fibres. In this respect the aim of this study is to develop an environmental friendly composites for furniture industry based on EFB fibres and sago starch. In this preliminary study, a basic composition and processing of EFB fibres-sago starch composites were established and the properties of the composites were determined. EFB fibre content was varied between 50-80% by weight. The amount of sago starch in liquid form was also varied and final weight percentage of sago starch added into the EFB fibres was adjusted accordingly. The mixtures of EFB fibres and sago starch were blended using Haake Rheomixer. The preliminary results indicate that the impact ...

2004-07-12

476

Microstructure and mechanical properties of quasi-carbon fibers and their polyacrylonitrile matrix composites  

Energy Technology Data Exchange (ETDEWEB)

Quasi-carbon fibers (QCFs) were prepared from Polyacrylonitrile (PAN) precursor by pyrolysis in the temperature range from 400{degrees}C to 950{degrees}C. The QCF-reinforced composites were fabricated by impregnating the QCFs with the PAN resin. The microstructural changes of both QCFs and their composites were characterized by the X-ray diffraction method. The stacking size and the crystallinity of the QCFs increased with the increasing heat treatment temperature (HTT). The crystallinity of the PAN matrix in a composite was also affected by various QCFs. DSC data indicated that thermal reaction mechanism of the composite could be altered due to the interaction between the fiber and the matrix. DMTA studies showed that good adhesion existed at the interface of the QCF-reinforced composites containing lower HTT fibers. The modulus magnitudes of QCFs and their ...

1994-12-31

477

The natural gas industry - a survey; Erdgaswirtschaft - Eine Branche im Ueberblick  

Energy Technology Data Exchange (ETDEWEB)

The situation of natural gas in the Federal Republic of Germany is described, with particular emphasis on the advantages and consequences of natural gas supply. The brochure discusses the role of natural gas on the energy market, the reliability of natural gas supply, the environmental impacts, the energy-saving effect of natural gas, natural gas prices, the competitive strength of the German gas industry, and the long-term reliability of natural gas supply. (orig.) [German] Die Situation des Erdgases in der Bundesrepublik Deutschland wird beschrieben, wobei die wichtigsten Vorteile und Auswirkungen der Erdgasversorgung besonders hervorgehoben werden. Es geht um die Stellung des Erdgases im Energiemarkt, die Sicherheit der Energieversorgung, Umweltschutz, Energieeinsparung durch Erdgaseinsatz, Erdgaspreise, ...

2000-09-01

478

Study on the natural gas utilization in the ceramic industry; Estudo sobre a utilizacao do gas natural na industria ceramica  

Energy Technology Data Exchange (ETDEWEB)

The production, principal applications, characteristics and properties, advantages of the gas natural is showed. A sectorial overview of the ceramic industry and the utilization of the natural gas in the ceramic industry is presented. The expectations are systematized and the impact of the natural gas utilization in the ceramic industry is evaluated. Some conclusions are withdrawn and recommendations suggested.

1998-07-01

479

Combined gas/steam turbine process. Kombinierter Gas/Dampfturbinen-Prozess  

Energy Technology Data Exchange (ETDEWEB)

A combined gas/steam turbine process includes a high-pressure furnace and a high pressure gasification unit with a mounted upstream of a combustion chamber there is a gas turbine with a waste heat system. Combustion heat which is not needed to heat the flue gas to combustion temperature is released from the furnace and transferred to ths combustion air going into the combustion chamber.

1991-01-31

480

Charts estimate gas-turbine site performance  

Energy Technology Data Exchange (ETDEWEB)

Nomographs have been developed to simplify site performance estimates for various types of gas turbine engines used for industrial applications. The nomographs can provide valuable data for engineers to use for an initial appraisal of projects where gas turbines are to be considered. General guidelines for the selection of gas turbines are also discussed. In particular, site conditions that influence the performance of gas turbines are described.

1988-05-09

481

Bring money and natural gas; Part 5: The activities of Dutch companies in the East European natural gas market. Geld en gas meebrengen; Deel 5: Nederlandse bedrijven actief op de Oosteuropese gasmarkt  

Energy Technology Data Exchange (ETDEWEB)

The budding natural gas markets in East Europe attract a great deal of interest from natural gas industries in the Western countries. Dutch companies, institutions and the government, too, are active in this market. So far the results have not been spectacular. An analysis is made of the present situation and the Dutch approach

1993-09-01

482

Study on the electrochemical properties of MgNi-CuO hydrogen storage composite materials  

Energy Technology Data Exchange (ETDEWEB)

To study the effect of CuO on the electrochemical properties of MgNi alloy, the MgNi-xCuO (x = 3, 5 and 10 wt%) composites were prepared by ball-milling method. The X-ray diffraction (XRD) analysis showed that the structures of the composites were amorphous. The cycle stability of the composites was improved compared to pure MgNi alloy due to the enhancement of the anti-corrosion property in the alkaline electrolyte, and the composite with 5 wt% CuO ball-milled for 15 h exhibited the best performance. Electrochemical impedance spectroscopy (EIS) and potential-step measurements indicated that the electrochemical kinetics of the composites was improved.

2009-07-29

483

Chemical resistance, void content and tensile properties of oil palm/jute fibre reinforced polymer hybrid composites  

British Library Electronic Table of Contents (United Kingdom)

Tri layer hybrid composites of oil palm empty fruit bunches (EFB) and jute fibres was prepared by keeping oil palm EFB as skin material and jute as the core material and vice versa. The chemical resistance, void content and tensile properties of oil palm EFB/Jute composites was investigated with reference to the relative weight of oil palm EFB/Jute, i.e. 4:1, the fibre loading was optimized and different layering pattern were investigated. It is found from the chemical resistance test that all the composites are resistant to various chemicals. It was observed that marked reduction in void content of hybrid composites in different layering pattern. From the different layering pattern, the tensile properties were slightly higher for the composite having jute as skin and oil palm EFB as core ...

2011-01-01

484

Tritium contamination and decontamination study on materials for ITER remote handling equipment  

Energy Technology Data Exchange (ETDEWEB)

Several materials, lenses, dry bearings and cables were exposed to a tritiated moisture environment to study the behavior of tritium contamination on candidate materials for ITER remote handling equipment. To optimize the tritium removal procedure, decontamination experiments using a gas purge with three different moisture concentrations were also performed. The surface tritium concentrations of CeO{sub 2} containing alkaline barium glass (NB), CeO{sub 2} containing lead glass (LX) and synthetic quartz (Quartz) after the exposure experiments were 7.80, 10.94 and 0.67 Bq/cm{sup 2}, respectively. It was found that the tritium concentration was influenced by the compositions of the materials. The concentrations of tritium on type 831 (solid lubrication material: graphite) and type 237 (solid lubrication material: tungsten disulfate) dry bearings after the exposure experiments were 89.80 and 31.78 Bq/cm{sup 2}, respectively. The tritium ...

2001-09-01

485

Tritium contamination and decontamination study on materials for ITER remote handling equipment  

International Nuclear Information System (INIS)

Several materials, lenses, dry bearings and cables were exposed to a tritiated moisture environment to study the behavior of tritium contamination on candidate materials for ITER remote handling equipment. To optimize the tritium removal procedure, decontamination experiments using a gas purge with three different moisture concentrations were also performed. The surface tritium concentrations of CeO_2 containing alkaline barium glass (NB), CeO_2 containing lead glass (LX) and synthetic quartz (Quartz) after the exposure experiments were 7.80, 10.94 and 0.67 Bq/cm"2, respectively. It was found that the tritium concentration was influenced by the compositions of the materials. The concentrations of tritium on type 831 (solid lubrication material: graphite) and type 237 (solid lubrication material: tungsten disulfate) dry bearings after the exposure experiments were 89.80 and 31.78 Bq/cm"2, respectively. The tritium concentration in an electric ...

2001-09-01

486

Triggered instabilities in rocket motors and active combustion control for an incinerator afterburner  

Science.gov (United States)

Two branches of research are conducted in this thesis. The first deals with nonlinear combustion response as a mechanism for triggering combustion instabilities in solid rocket motors. A nonlinear wave equation is developed to study a wide class of combustion response functions to second-order in fluctuation amplitude. Conditions for triggering are derived from analysis of limit cycles, and regions of triggering are found in parametric space. Introduction of linear cross-coupling and quadratic self-coupling among the acoustic modes appears to be how the nonlinear combustion response produces triggering to a stable limit cycle. Regions of initial conditions corresponding to stable pulses were found, suggesting that stability depends on initial phase angle and harmonic content, as well as the composite amplitude, of the pulse. Also, dependence of nonlinear stability upon system parameters is considered. The second part of this thesis presents research for a ...

1999-01-01

487

Surface modification of 30CrNiMo8 low-alloy steel by active screen setup and conventional plasma nitriding methods  

Energy Technology Data Exchange (ETDEWEB)

In this paper, we report on a comparative study of active screen plasma nitriding (ASPN) and conventional dc plasma nitriding (CPN) behavior of 30CrNiMo8 low-alloy steel that has been examined under various process conditions. The process variables included active screen setup parameters (screen and iron plate top lids placed on the screen setup with 8 mm of hole size), treatment temperature (550 and 580 deg. C), gas mixture (75/25 and 25/75 of N{sub 2}/H{sub 2}) and treatment time (5 and 10 h) in 500 Pa pressure. The structure and phases composition of the diffusion zone and compound layer were studied by X-ray diffraction (XRD), microhardness tests, light optical microscopy and scanning electron microscopy (SEM). It was observed that treated sample surfaces in both CPN and ASPN methods consist of {gamma}' and {epsilon} phases, and while the nitriding time and/or temperature increases, the intensity of {epsilon} phase in the compound ...

2007-12-30

488

Surface modification of 30CrNiMo8 low-alloy steel by active screen setup and conventional plasma nitriding methods  

International Nuclear Information System (INIS)

In this paper, we report on a comparative study of active screen plasma nitriding (ASPN) and conventional dc plasma nitriding (CPN) behavior of 30CrNiMo8 low-alloy steel that has been examined under various process conditions. The process variables included active screen setup parameters (screen and iron plate top lids placed on the screen setup with 8 mm of hole size), treatment temperature (550 and 580 deg. C), gas mixture (75/25 and 25/75 of N_2/H_2) and treatment time (5 and 10 h) in 500 Pa pressure. The structure and phases composition of the diffusion zone and compound layer were studied by X-ray diffraction (XRD), microhardness tests, light optical microscopy and scanning electron microscopy (SEM). It was observed that treated sample surfaces in both CPN and ASPN methods consist of #gamma#' and #epsilon# phases, and while the nitriding time and/or temperature increases, the intensity of #epsilon# phase in the compound layer will increase ...

2007-12-30

489

Structure and magnetic properties of nanostructural strontium ferrite prepared by mechanochemical treatment  

International Nuclear Information System (INIS)

Full text: It was recently-established for hexagonal barium ferrite-industrially important magnetically hard material that refinement of the crystallite dimensions into the nanoscale regime, typically #<=# 10 nm, leads after heat treatment at temperatures 800-1000 deg C to significant coercivity increase of up to 6.5 kOe (#approx#3-4 times) with saturation magnetisation values of 50-55 emu/g (#approx#95% of bulk at room temperature). High-energy mechanochemical processing has been applied to prepare nanostructural (nanocrystalline-amorphous) composites. High resolution electron microscopy studies reveal that the enhancement of the final magnetic properties was due to formation of magnetically noninteracting #approx#l,#mu#m Ba-ferrite particles with 5-10 nm amorphous surface layer - depending on annealing parameters. Similar situation was established also for ball milled strontium ferrite (SrFe_1_2O_1_9) powders where short annealing 4 h at 1000 deg C produced ...

490

Proceedings of the workshop on high resolution computed microtomography (CMT)  

Energy Technology Data Exchange (ETDEWEB)

The purpose of the workshop was to determine the status of the field, to define instrumental and computational requirements, and to establish minimum specifications required by possible users. The most important message sent by implementers was the remainder that CMT is a tool. It solves a wide spectrum of scientific problems and is complementary to other microscopy techniques, with certain important advantages that the other methods do not have. High-resolution CMT can be used non-invasively and non-destructively to study a variety of hierarchical three-dimensional microstructures, which in turn control body function. X-ray computed microtomography can also be used at the frontiers of physics, in the study of granular systems, for example. With high-resolution CMT, for example, three-dimensional pore geometries and topologies of soils and rocks can be obtained readily and implemented directly in transport models. In turn, these geometries can be used to calculate fundamental physical ...

1997-02-01

491

Pre-Oxidized and Nitrided Stainless Steel Foil for Proton Exchange Membrane Fuel Cell Bipolar Plates: Part 1 Corrosion, Interfacial Contact Resistance, and Surface Structure  

Energy Technology Data Exchange (ETDEWEB)

Thermal (gas) nitridation of stainless steels can yield low interfacial contact resistance (ICR), electrically-conductive and corrosion-resistant nitride containing surfaces (Cr2N, CrN, TiN, V2N, VN, etc) of interest for fuel cells, batteries, and sensors. This paper presents the results of scale up studies to determine the feasibility of extending the nitridation approach to thin 0.1 mm stainless steel alloy foils for proton exchange membrane fuel cell (PEMFC) bipolar plates. A major emphasis was placed on selection of alloy foil composition and nitidation conditions potentially capable of meeting the stringent cost goals for automotive PEMFC applications. Developmental Fe-20Cr-4V alloy and type 2205 stainless steel foils were treated by pre-oxidation and nitridation to form low-ICR, corrosion-resistant surfaces. Promising behavior was observed under simulated aggressive anode- and cathode- side bipolar plate conditions for both materials. ...

2010-09-01

492

Nanocomposite electrodes based on pre-synthesized organically capped platinum nanoparticles and carbon nanotubes. Part I: Tuneable low platinum loadings, specific H upd feature and evidence for oxygen reduction  

Energy Technology Data Exchange (ETDEWEB)

A bottom-up approach is used here to combine carbon nanotubes synthesized by CVD and organically capped platinum nanoparticles electrocatalyst exhibiting a direct electrochemical activity towards oxygen reduction. Both nano-objects are handled in liquid suspension and are associated together in a controlled way. The nanocomposite liquid dispersions can be precisely controlled in terms of platinum nanoparticles to carbon nanotubes weight ratios (NP/NT) which correspond to different coverages of nanotubes by nanoparticles. Electrodes with low to ultra-low platinum loadings can then be prepared on porous fuel cell carbon supports by filtration. The direct electrochemical activity towards aqueous oxygen reduction reaction (ORR) of electrodes with platinum loadings ranging from about 1 to 60 {mu}g/cm{sup 2} is reported without any activation step in order to keep the features of the nanoparticles intact. Before that, we studied the responses obtained when impregnating our hydrophobic ...

2009-09-30

493

Formation of SiO2 protective coating on SUS 304 stainless steel by chemical vapor deposition using TEOS-O3 gas system. TEOS-O3 kei CVD ni yoru SUS 304 stainless kojo eno SiO2 boshoku hifuku no keisei  

Energy Technology Data Exchange (ETDEWEB)

The passive films formed in stainless steels are thin and fine oxide films, a high corrosion resistance can be provided by these films. This study formed SiO2 protective coating on the substrate of SUS 304 stainless steels by chemical vapor deposition using TEOS-O3 system. Firstly, relations of substrate temperature and deposition rate of films, chemical composition, refractive index of films were investigated. Then, the corrosion resistance of SUS 304 stainless steels coated SiO2 films was examined by activation time and an anodic polarization curve in 1 kmol[center dot]m[sup -3] HCl solution. The results were obtained as follows. Thickness of SiO2 films linearly increases with time at the deposition temperature of 473 to 673 K. Si-OH bonds would disappear above the deposition temperature of 573 K, almost perfect SiO2 films were obtained. The activation time in 1 kmol[center dot]m[sup -3] HCl solution increased with increase of thickness of SiO2 films. 21 refs., ...

1993-05-15

494

Fission product and actinide release from the debris bed test Phebus FPT4: synthesis of the post test analyses and of the revaporisation testing of the plenum samples  

International Nuclear Information System (INIS)

The Phebus FP project in an international reactor safety project. Its main objective is to study the release, transport and retention of fission products in a severe accident of a Light Water Reactor (LWR). The FPT4 test was performed with a fuel debris bed geometry, to look at late phase core degradation and the releases of low volatile fission products and actinides. Post Test Analyses results indicate that releases of noble gases (Xe, Kr) and high-volatile fission products (Cs, I) were nearly complete and comparable to those obtained during Phebus tests performed with a fuel bundle geometry (FPT1, FPT2). Volatile fission products such as Mo, Te, Rb, Sb were released significantly as in previous tests. Ba integral release was greater than that observed during FPT1. Release of Ru was comparable to that observed during FPT1 and FPT2. As in other Phebus tests, the Ru distribution suggests Ru volatilization followed by fast redeposition in the fuelled section. The similar release ...

2006-03-01

495

Effects of ion-induced electron emission on magnetron plasma instabilities  

International Nuclear Information System (INIS)

Some magnetron sputtering systems experience rapid oscillations in the current and voltage of the plasma discharge after several hours when equipped with certain targets. These oscillations often lead to the plasma becoming extinguished, a condition known as ''flame-out.'' This article details the study of two 90% W--10% Ti magnetron targets which differed in density. The higher density targets sometimes experienced flame-out after approximately 3 h of sputtering. The less dense material could be sputtered for the entire 15 h life of the target. Scanning electron microscopy pictures and atomic composition depth profiles were obtained using Auger electron spectroscopy. In addition, a Colutron-based ion source with a high vacuum system was used to measure ion-induced secondary electron emission coefficients as a function of energy, ion specie, and gas coverage. Analysis of the sample from the group that suffers flame-out showed large regions of ...

496

Development of a stable cobalt-ruthenium Fischer-Tropsch catalyst. Technical progress report No. 12, July 1, 1992--September 30, 1992  

Energy Technology Data Exchange (ETDEWEB)

The fixed bed pilot plant, the catalyst testing procedure, and the calculations for conversion and selectivities were previously described in the technical progress report covering the period of 3/16/88 to 6/16/88 for Contract DE-AC22-87PC79812. Conversions and hydrocarbon selectivities were calculated using data from an on-line gas chromatography (GC) analyzer. Alcohol selectivities were calculated using data from an on-line boiling point GC analyzer which analyzed the liquid product. The catalysts were prepared via the steps of impregnation, calcination, and reduction on a special Y-zeolite-derived support. The impregnation step consisted of evaporation of metal salts on to the support from an aqueous solution. For one catalyst (No. 6531-188) the metal salts were evaporated on to the support from a reverse micelle solution containing the metal salts. All the catalysts were calcined for four hours at 450{degree}C. The calcined catalysts were loaded in the reactor ...

1992-12-31

497

Crystallographic data for new phases in the CaSO/sub 3/-H/sub 2/O system  

Energy Technology Data Exchange (ETDEWEB)

Among the three modifications of calcium sulfite hemihydrate, two of them, hexagonal ..beta..-CaSO/sub 3/.1/2H/sub 2/O with a rhombohedral lattice and ..gamma..-CaSO/sub 3/.1/2H/sub 2/O with a simple triangular hexagonal lattice, were found in the authors' recent work. By heating ..cap alpha..- and/or ..gamma..-hemihydrate at 330-360/sup 0/C in a nitrogen atmosphere, the orthorhombic anhydrate ..cap alpha..-CaSO/sub 3/ was formed, with lattice constants of 6.472, 15.93, and 23.44 angstrom for a, b, and c respectively, while the body-centered tetragonal anhydrate ..beta..-CaSO/sub 3/, with lattice constants of 15.68 and 19.44 angstrom for a and c respectively, was formed by heating the ..beta..-hemihydrate. The dehydration of three hemihydrates and the hydration of two anhydrates were discussed. Calcium sulfite hemihydrate (CaSO/sub 3/.1/2H/sub 2/O) is useful as an architectural material since it has a high thermal stability and a low water solubility in comparison with calcium ...

1982-03-01

498

Application of new corrosion-resistance superheater tubings for a 500 C, 100 Kgf/cm{sup 2}{center_dot}g high-efficiency waste-to-energy plant  

Energy Technology Data Exchange (ETDEWEB)

A two-year demonstration run of a 500 C/100kgf/cm{sup 2}{center_dot}g high-efficiency waste-to-energy pilot plant has been started from February 1998; this plant represents as the final stage of the NEDO project of development of a high-efficiency waste-to-energy plant. Alloy 625 (SB444) and 310 HCbN tubings were selected for the 3rd and 2nd superheater of the pilot plant, respectively, and ten kinds of conventional and new solid-wall tubings, weld overlayed tubings, composite tubings, and cermet spray coated tubings were tested. By means of 6000-hour field corrosion test in three typical domestic plants, material life and corrosion environment for superheater tubings installed in the pilot plant were evaluated. Also, the effect of alloying elements Cr, Ni, Mo, corrosion rate law, etc. were investigated in detail. Furthermore, the design conception and basic performance of the pilot plant regarding pollution control and corrosion prevention were determined, based ...

1999-11-01

499

A SURVEY OF MOLECULAR LINES TOWARD MASSIVE CLUMPS IN EARLY EVOLUTIONARY STAGES OF HIGH-MASS STAR FORMATION  

International Nuclear Information System (INIS)

We have observed the CH_3OH J = 2-1, SiO J = 2-1, C"3"4S J = 2-1, H"1"3CO"+ J = 1-0, HN"1"3C J = 1-0, CCH N = 1-0, OCS J = 8-7, and SO J_N = 2_2-1_1 lines toward 20 massive clumps, including Midcourse Space Experiment (MSX) 8 #mu#m dark sources (infrared dark clouds) and MSX 8 #mu#m sources, by using the Nobeyama Radio Observatory 45 m telescope. We have found that the velocity widths of the CH_3OH and C"3"4S lines are broader than those of the H"1"3CO"+ line in the MSX dark sources. On the other hand, they are comparable to the velocity width of the H"1"3CO"+ line in the MSX sources. In addition, the [SiO]/[H"1"3CO"+] abundance ratio is found to be enhanced in the MSX dark sources in comparison with the MSX sources. These results suggest that shocks caused by interaction between an outflow and an ambient dense gas would have substantial impact on the chemical composition of the MSX dark sources. The velocity widths of the CH_3OH and C"3"4S ...

2010-05-10