Fatty acid biomarker analysis coupled with gaschromatography-isotope ratio mass spectrometry was used to confirm the presence of methanotrophic and thiotrophic bacterial endosymbionts in the tissues...Full Text Available
Experimental investigation of the length of single burning jets of methane and hydrogen previously diluted with an inert gas (nitrogen or helium) was carried out. Efflux of fuel gases into the atmosphere occurred through cylindrical extension pieces 4 and 8 mm in diameter. The Reynolds numbers at the cut of a piece varied in the range from 400 to 12,000. A clearly defined dependence of the jet length on the quality of the added inert gas is obtained. The correlation of experimental data made it possible to recommend formulas for engineering calculations of free laminar and turbulent jets.
Appendices to this summary consist of twelve individual status reports that will be available through the National Technical Information Service (NTIS) in the United States and of course limited copies will be available through NATO. The twelve report titles which are appendices to the summary are: (A) Status Report on the Limestone/Sludge Flue Gas Desulfurization Process; (B) Status Report on the Lime/Sludge Flue Gas Desulfurization Process; (C) Status Report on the Double Alkali/Sludge Flue Gas Desulfurization Process; (D) Status Report on the Sea Water Scrubbing Flue Gas Desulfurization Process; (E) Status Report on the Limestone/Gypsum Flue Gas Desulfurization Process; (F) Status Report on the Lime/Gypsum Flue Gas Desulfurization Process; (G) Status Report on the Double Alkali/Gypsum Flue Gas Desulfurization Process; (H) Status Report on ...
The high pressure discharges (pulsed or D C corona, barrier, gliding and the others), have been studied both experimentally and theoretically as sources of low temperature plasma for pollution control technologies. The potential of electrical discharge methods has been demonstrated for the decomposition of many types of VOC. The air or oxygen are used as a feed gas in which pollutant is diluted. The ozone production in air or oxygen in such discharges is also discussed
The solubility of Sn(IV) oxide was determined in a dilute NaClO{sub 4} solution with pH 2 through 12 at ambient temperature. Both oversaturation and undersaturation experiments were carried out in an inert gas glovebox where the concentration of the oxygen and carbon dioxide were less than 1 ppm. The solubility of Sn(IV) oxide was 3 {times} 10{sup {minus}8} mol/l at neutral pH, and increased at pH > 7.5. Equilibrium constants of soluble reactions were calculated from the experimental data, using curve fitting method. The study suggests that the solubility of Sn(IV) oxide would be higher than that provisionally used in current safety assessments of HLW disposal sites.
The solubility of Sn(IV) oxide was determined in a dilute NaClO_4 solution with pH 2 through 12 at ambient temperature. Both oversaturation and undersaturation experiments were carried out in an inert gas glovebox where the concentration of the oxygen and carbon dioxide were less than 1 ppm. The solubility of Sn(IV) oxide was 3 x 10"-"8 mol/l at neutral pH, and increased at pH > 7.5. Equilibrium constants of soluble reactions were calculated from the experimental data, using curve fitting method. The study suggests that the solubility of Sn(IV) oxide would be higher than that provisionally used in current safety assessments of HLW disposal sites.
Investigations were conducted on the range of emission rates of NO, NO[sub 2], CO and hydrocarbons, and the thermal efficiencies produced by each burner on three production cookers, supplied by different Australian manufacturers. It was found that the emissions and efficiencies were markedly affected by (1) the thermal input, both with and without a load on the burner, and (2) the load-height to flame-length ratio, with a load on the burner. The effect of hydrocarbon leakage into the secondary/dilution air was investigated, to explain the observed correlation of hydrocarbon emission rate with dilution air flow. The hydrocarbons were found to arise from two sources: -leakage from the stabilisation ports at the base of the burner, which was found to be significant at the higher thermal input; -incomplete combustion of the fuel in the premix, which was the dominant source of hydrocarbons emissions at the lower thermal input. (author)
We have demonstrated that, with simple pH adjustment, volatile drugs such as methamphetamine, amphetamine, 3,4-methylenedioxymethamphetamine (MDMA), ketamine, and valproic acid could be analyzed rapidly from raw biofluid samples (e.g. urine and serum) without dilution, or extraction, using atmospheric pressure ionization. The ion source was a variant type of atmospheric pressure chemical ionization (APCI) that used a dielectric barrier discharge (DBD) to generate the metastable helium gas and reagent ions. The sample solution was loaded in a disposable glass pipette, and the volatile compounds were purged by nitrogen gas to be reacted with the metastable helium gas. The electrodes of the DBD were arranged in such a way that the generated glow discharge was confined within the discharge tub...
A hydrogen combustion and exhaust emissions in a supercharged gas engine ignited with micro pilot diesel fuel was discussed in this presentation. A schematic diagram of the experimental study was first presented. The single cylinder, water-cooled, supercharged test engine was illustrated. Results were presented for the following: fuel energy and energy share (hydrogen and diesel fuel); pressure history and rate of heat release; engine performance and exhaust emissions; effect of nitrogen dilution on heat value per cycle; effect of N_2 dilution on pressure history and rate of heat release; and engine performance and exhaust emissions. This presentation demonstrated that smooth and knock-free engine operation results from the use of hydrogen in a supercharged dual-fuel engine for leaner fuel-air equivalence ratios maintaining high thermal efficiency. It was possible to attain mor3 than 90 per cent hydrogen-energy substitution ...
In order to investigate the effect of humidity on laminar burning velocity(S), the effect of humidity on the combustion reaction and radiation intensity was studied, taking account of dilution gases such as CO/sub 2/ and Ar which has the approximately identical characteristics to exhaust gas circulation(EGR) gas used to prevent NOx discharge from engines. According to the heat reaction theory, mean specific heat(C) of mixture, mean molecular weight(M) and adiabatic flame temperature(T) etc. were said to affect S but from experimental results, the effect of M and C could be ignored, compared with the effect of T. The relationship between S and H/sub 2/O, Ar of CO/sub 2/% in mixture of diluted gases was clarified. The effect of H/sub 2/O on S was mainly caused by changes of T. The effect of radical C/sub 2/, CH and OH on radiation intensity was similar to that of H/sub 2/O and Ar and the effect of H/sub ...
Neon 19, a 17-second positron-emitting radioelement, is produced continously by 23 MeV alpha particle bombardment of oxygen. For a 12 ..mu..A particle current the method of preparation described delivers 14 mCi of neon 19 per min to the functional exploration room. The radiochemically pure radioactive gas is diluted in air and breathed continously by the patient lying under a positron tomographic camera. The regional lung ventilation distribution is obtained on 2 cm thick sections of organ with a transverse resolution of 17 mm. Quantification of the ventilation output per unit lung volume is contemplated.
This study investigated the engine performance and emissions of a supercharged engine fueled by hydrogen and ignited by a pilot amount of diesel fuel in dual-fuel mode. The engine was tested for use as a cogeneration engine, so power output while maintaining a reasonable thermal efficiency was important. Experiments were carried out at a constant pilot injection pressure and pilot quantity for different fuel-air equivalence ratios and at various injection timings without and with charge dilution. The experimental strategy was to optimize the injection timing to maximize engine power at different fuel-air equivalence ratios without knocking and within the limit of the maximum cylinder pressure. The engine was tested first with hydrogen-operation condition up to the maximum possible fuel-air equivalence ratio of 0.3. A maximum IMEP of 908 kPa and a thermal efficiency of about 42% were obtained. Equivalence ratio could not be further increased due to knocking of the ...
Hydrogenation of high-volatile bituminous coal under high temperatures and pressures produced low-sulfur fuel oils. At a coal conversion of 80 percent, the ratio of oil to gas yields was approximately 3 : 1 and 23 percent of the coal sulfur was contained in the oil. Sulfur content of the oil, however, remained the same at different coal-conversion levels. The data obtained in the semicontinuous dilute-phase hydrogenation system showed that the whole oil can be directly used as a fuel oil where 1 percent sulfur is tolerated. Fuel oils containing 0.5 percent and 0.25 percent sulfur were produced by desulfurization of the whole oil.
BACKGROUND: The correlation between pesticide residue levels and formulation of an active substance is often not considered, even if it is reasonable to expect some differences arising from behaviour during dilution and spraying, from adhesion to plant and from degradation. An experimental study to investigate the magnitude of tebuconazole residues as a function of different tebuconazole formulated products was carried out in Italy. The fungicide was applied as wettable powder (WP) and water-dispersible granule (WG) formulations to peach, plum, apricot and nectarine orchards, on four different sites. The fruit samples gained from the field trials were quantitatively analysed by gas chromatography with a nitrogen phosphorus detector (GC/NPD) for tebuconazole residues. RESULTS: Tebuconazole ...
Laboratory experiments were conducted to simulate the transfer of acidic THOREX waste from Tank 8D-4 into the alkaline PUREX waste in Tank 8D-2 at West Valley. The purpose of the experiments was to explore means of minimizing the production of nitric oxide (NO) gas during mixing of the two wastes and to assess the potential for the gas to further react in the vapor space possibly leading to enhanced corrosion of the tank walls. Forty one THOREX/PUREX mixing tests were conducted to explore the effects of stirring rate, pH, THOREX addition rate, THOREX or PUREX dilution, and temperature. The two most important criteria for minimizing NO production were to maintain some degree of agitation and the keep the pH in the PUREX high, preferably >12. Steel corrosion tests were performed in the presence of low partial pressures of NO{sub 2} and liquid water or water vapor. The NO{sub 2} (from oxidation of NO in the vapor space) ...
A sensitive and rapid automated method has been developed for the selective analysis of acid extractable sulfide in environmental samples by combining gas dialysis separation techniques with methylene blue detection procedures. Acid extractable sulfide is separated from the sample matrix by the gas dialysis membrane and subsequently trapped in a dilute sodium hydroxide receiving stream. This stream is reacted with N,N-dimethyl-p-phenylenediamine and ferric chloride to produce methylene blue which is then quantitated colorimetrically at 660 nm. For standards and nonturbid environmental samples, there is good agreement between the results obtained by this procedure and the standard methylene blue method. The effect of interferences on the accurate determination of sulfide by both methods was also examined and it was found that cupric ions significantly interfered with sulfide estimation. To obtain adequate sulfide recoveries ...
The chemostat theory on two species competition has shown that the dilution rate where transition of dominance occurs - transition-dilution rate - is independent of limiting-nutrient concentration. However, we obtained the experimental data indicating that the transition-dilution rate changed with variations in limiting-ammonium concentrations, using the chemostat mixed-culture of the cyanobacterium Microcystis novacekii and the green alga Scenedesmus quadricauda. The transition-dilution rate was dependent on the concentration of limiting ammonium in the influx culture medium. We tried to simulate the experimental results. Though the dilution rate has been considered independent of nutrient concentration, we introduce the effective dilution rate that depends on nutrient concentration (ammo...
Described herein are the results of the FY1994 research program for analysis and evaluation for thin film solar cells. The study on quantitative analysis of hydrogen atoms in a plasma determines quantity of hydrogen atoms in the plasma of monosilane diluted with hydrogen. It is found, contrary to expectation, that quantity of hydrogen atoms in the plasma decreases as it is more diluted with hydrogen. The study on light-induced degradation of the thin chlorine-base amorphous silicon films confirms that the plasma CVD method with 20% of dichlorosilane gas added to monosilane gas produces the thin amorphous silicon film 3 times faster than the conventional method. The thin film has essentially the same defect density as the one prepared by the conventional method, showing good photoelectric characteristics. The thin film of chlorinated amorphous silicon has a 1 digit lower defect density than the ...
Headspace solid-phase microextraction (HS-SPME) coupled to comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GCxGC-TOFMS) was applied for equilibrium headspace analysis of Malaysian soursop (Annona muricata) volatile flavor compounds. A two-level fractional factorial design (25-1) was used to determine the effect of SPME variables, namely, SPME fibers, adsorption temperature, extraction time, amount of salt, sample amount and sample concentration on the extraction efficiency of volatile flavor compounds. A total of 37 volatile compounds were identified, comprising 21 esters, 6 alcohols, 3 terpenes, 2 acids, 2 ketones, 2 aldehydes and an aromatic with different hydrophobicities (log P) ranging between -0.14 and 4.83. Extraction using 10g of diluted (5% w/w) ...
Formation of particles from heavy duty diesel and CNG vehicles was studied in laboratory conditions. PM, nano and soot mode particle emissions formed from buses of Euro 2-5 -emission levels were studied in relation to age and type approval characteristics of the vehicle. Characteristic particle emission factors from city driving were obtained by driving the buses on VTT's heavy duty chassis dynamometer applying the transient Braunschweig city cycle. The vehicles were a representative set of Euro 2 to 3 emission categories, supplemented with Euro 4-5 (EEV) -targeted CRT, CNG and DPF cars. Particle number emissions from Euro 4 to 5 buses were 1/100-1/1000 and mass emissions 1/10-1/100 of those of the current fleet. Particle emission from natural gas buses and after an advanced CRT trap contained almost entirely liquid < 60 nm nano particles, which will make filter mass based PM control very challenging in the near future. One result was that ...
The chemical composition and evolution of formation waters associated with gas production in the Palm Valley field, Northern Territory, has important implications for reservoir management, saline water disposal, and gas reserve calculations. Historically, the occurrence of saline formation water in gas fields has been the subject of considerable debate. A better understanding of the origin, chemical evolution and movement of the formation water at Palm Valley has important implications for future reservoir management, disposal of highly saline water and accurate gas reserves estimation. Major and trace element abundance data suggest that a significant component of the highly saline water from Palm Valley has characteristics that may have been derived from a modified evaporated seawater source such as an evaporite horizon. The most dilute waters probably represent condensate and the ...
A vessel phantom suitable for evaluation of spatial and contrast resolution of FCRDSA (Fuji Computed Radiography, digital subtraction angiography) has been developed and used for determining resolution. The effects of iodine concentration, low dose exposure, and acryl thickness on the resolution were evaluated in FCRDSA, and FCRDSA images were compared with film substraction with use of this phantom. It has been proven that limitation of resolution of FCRDSA was 5 % 1 mm and about 1/4 dose exposure compared with conventional film exposure was clinically acceptable. Dye dilution method was useful to determine a program of IVDSA with imaging plate. It has been proven that time to appearance and time to peak of time-concentration curve of dye dilution method closely correlate to time to appropriate image of DSA in the neck, the chest, and the abdomen. 106 cases of IVDSA and 130 cases of IADSA using FCR in Tohoku University Hospital from January ...
BackgroundObtaining single parasite clones is required for many techniques in malaria research. Cloning by limiting dilution using microscopy-based assessment for parasite growth...Full Text Available
This article introduces a predictive capability for Hg retention in any Ca-based wet flue gas desulfurization (FGD) scrubber, given mercury (Hg) speciation at the FGD inlet, the flue gas composition, and the sulphur dioxide (SO2) capture efficiency. A preliminary statistical analysis of data from 17 full-scale wet FGDs connects flue gas compositions, the extents of Hg oxidation at FGD inlets, and Hg retention efficiencies. These connections clearly signal that solution chemistry within the FGD determines Hg retention. A more thorough analysis based on thermochemical equilibrium yields highly accurate predictions for total Hg retention with no parameter adjustments. For the most reliable data, the predictions were within measurement uncertainties for both limestone and Mg/lime systems operating in both forced and natural oxidation mode. With the U.S. Environmental Protection Agency's (EPA) Information Collection Request ...
The pitting corrosion properties have been investigated in welded and unwelded condition by polarization tests in sodium chloride solutions. The two steels were TIG welded without adding welding material and as shielding on the bottom side argon gas containing 2, 26 or 99 ppm oxygen was used. In some tests low breakthrough potentials were received, without discovering any pitting corrosion in the specimen surfaces. The unwelded SS 2352 steel had a critical (lowest) pitting temperature (CPT) of 5 degrees C in the more concentrated solution. For the same steel with weld pitting corrosion was obtained at 5 degrees C, which was the lowest temperature for the tests. Thus the CPT value was lower than 5 degrees C, but by looking at the pitting corrosion potentials the following conclusion could be drawn: Welding with higher oxygen content in the shielding gas implied lower pitting corrosion resistance. For the SS 2353 steel the CPT values were 25 and ...
Potential exposure of workers to phosphide was examined during an in-depth industrial hygiene survey at the Bunge Corporation, in Kansas City, Kansas, where the gas was used as a grain fumigant. During the study, 14 men were employed at the facility. Tablets of aluminum phosphide were added to the grain mass for fumigation. General dilution ventilation resulted from outside air entering the work areas through ventilation louvers; there was also a local-exhaust ventilation system. Air samples revealed that, when the fumigant dispensers were being filled, workers in the area had significant exposure. At the time of the survey the relative humidity in the facility was high, permitting the reaction to phosphide to occur more readily. The levels of phosphide and respirable dust were reasonably low in the elevators, suggesting that the ventilation system was adequate. The author recommends that workers filling the dispenser with the aluminum ...
Measurements of PEM fuel cell device performance were made with different gas inlet temperatures and relative humidity using a newly-designed test fixture. Significant improvement in device performance was observed when the fuel inlet temperature was increased above the operating temperature of the cell. These measurements were then correlated to a model to describe energy and mass transport processes. Proton exchange membrane (PEM), fuel cells--the focus of this study--use an ion conducting polymer, especially polyperfluorosulfonic acid materials. These polymer materials, when imbibed with water, exhibit solution-like properties, but because the anions are chemically bound to the polymeric structure, the electrolyte is contained. Importantly, product water removal is simplified, as electrolyte dilution is not a concern. However, the proton transport rate is a function of the polymer geometry, which is set, in part, by the polymer water ...
PETROBRAS/TRANSPETRO Pipelines and Terminals have 500 regular employees and 5.064 out sourced workers in its Southeast Division. The out sourced employees work under 125 contracts involving a wide range of activities such as maintenance, pipeline operation, pipeline launching, engineering, administrative and auxiliary services. Among these workers, 1.200 peoples are subjected to occupational exposure, which may be present in the industrial process or in the products transported in our pipelines, e.g. industrial noise, sulfidric gas, toluene, xylene and benzene (recognized as a carcinogen according to ACGIH and Brazilian Ministry of Labour). Our PPRA (acronym in Portuguese for Occupational Exposure Prevention Program) involves the workforce and fosters health by anticipation, recognition, evaluation and control of the situations that may result in injuries. Further actions include the procurement of equipment for detection of these agents not only in the air but ...
Field studies were conducted May 28-June 1, 1979, to determine the chemical composition and physical behavior of discharges from an offshore gas drilling rig in the central basin of Lake Erie. The drilling operation was observed for four days, from rig jackup to the circulation of mud through the borehole after drilling had been completed. Resuspension studies using nephelometry, supplemented with chemical analyses, indicated little resuspension of lake bottom materials or release of metals to the water column during rig jack-up. Portions of the turbidity plumes generated during drilling were buoyant. Three surface turbidity plumes were mapped with nephelometry to a point at which particulate concentrations reached background levels in the Lake. Detectable plumes were approx. 400 to 1500 m in length and had maximum widths < 230 m. A chemical survey conducted in the plume during early gas shows indicated that discharged inorganic chemical ...
The purpose of this investigation is to show that resource to anisotropic compression along a magnetic field is not a necessary condition for star formation within large collapsing interstellar gas clouds. Although such a scenario would certainly eliminate the magnetic field and angular momentum problems associated with isotropically collapsing clouds, it is believed there is sufficient observational theoretical evidence to warrant the present study of magnetically braked, isotropically collapsing gas clouds. It is not attempted to disprove the hypothesis of anisotropic compression, but to offer instead, a reasonable alternative. Angular momentum transfer from magnetically braked, cool interstellar gas clouds of 10"2, 10"3 and 10"4 times the mass of the sun is examined. Magnetic torques acting on a contracting, rotating cloud, permeated by a frozen-in magnetic field coupling the cloud to the galactic field of the ...
It is planned to use the tritium dose model, DCART (Doses from Chronic Atmospheric Releases of Tritium), to reconstruct dose to the hypothetical maximally exposed individual from annual routine releases of tritiated water (HTO) and tritiated hydrogen gas (HT) from all Lawrence Livermore National Laboratory (LLNL) facilities and from the Sandia National (SNL) Laboratory's Tritium Research Laboratory over the last fifty years. DCART has been described in Part 1 of ''Historical Doses From Tritiated Water And Tritiated Hydrogen Gas Released To The Atmosphere from Lawrence Livermore National Laboratory (LLNL)'' (UCRL-TR-205083). This report (Part 2) summarizes information about annual routine releases of tritium from LLNL (and SNL) since 1953. Historical records were used to derive facility-specific annual data (e.g., source terms, dilution factors, ambient air concentrations, ...
During the last years one focus of German PWR safety analysis was boron dilution events with the potential of reactivity transients. Coolant with a low boron concentration could be collected in localized areas of the reactor coolant system e.g. by separation of borated reactor coolant into highly concentrated and diluted fractions (inherent dilution) which can occur during reflux- condenser heat transfer after a small break loss of coolant accident with a limited availability of the emergency core cooling systems. The TUeV NORD SysTec was charged by German supervisory authorities with the assessment of the safety analyses of boron dilution events presented by the utilities. These analyses are based on the simulation of boron dilution and transport processes in conjunction with a number of dedicated experiments. The analyses shall demonstrate that boron dilution ...
During the last years one focus of German PWR safety analysis was boron dilution events with the potential of reactivity transients. Coolant with a low boron concentration could be collected in localized areas of the reactor coolant system e.g. by separation of borated reactor coolant into highly concentrated and diluted fractions (inherent dilution) which can occur during reflux- condenser heat transfer after a small break loss of coolant accident with a limited availability of the emergency core cooling systems. The TUeV NORD SysTec was charged by German supervisory authorities with the assessment of the safety analyses of boron dilution events presented by the utilities. These analyses are based on the simulation of boron dilution and transport processes in conjunction with a number of dedicated experiments. The analyses shall demonstrate that boron dilution ...
During the last years, boron dilution events with the potential of reactivity transients were an important issue of German PWR safety analyses. A coolant with a low-boron concentration could be collected in localized areas of the reactor coolant system, e.g., by separation of a borated reactor coolant into highly concentrated and diluted fractions (inherent dilution) which can occur during reflux-condenser heat transfer after a small break loss of coolant accident with a limited availability of the emergency core cooling systems. During the course of follower core assessments, TUV NORD SysTec appraises safety analyses of boron dilution events presented by the utilities. These analyses are based on the simulation of boron dilution and transport processes in conjunction with a number of dedicated experiments. The analyses demonstrate that boron dilution events ...
The in vitro susceptibility of Actinobacillus actinomycetemcomitans to azithromycin, a new macrolide antibiotic of a new class known as azalides, was compared with that of erythromycin by the agar dilution...Full Text Available
The antibacterial activities of different nitroheterocyclic compounds were assessed by an agar dilution method against aerobic, microaerophilic, and anaerobic bacteria. Nitronaphthofurans inhibited...Full Text Available
... Abstract : The electric resistance in weak (diluted) solid solutions of the Pd-Ag and Fe-W systems, as wellAS THE Hall effect in a Pd-Ag system ...
This study was aimed to test and select hydrophobic activated charcoal, manufactured in Romania, used as adsorbents of solvents which partly compose diluters employed in car industry. With regard to the diluters, three of the seven types of activated charcoal studied (Sorbent 1, R - Cafs and AD3) showed the greatest capacity of adsorption, when determined under dynamic and static conditions. (authors) 8 refs.
A procedure for the determination of lead in soil samples by "2"0"3Pb radioisotope dilution substoichiometric method is described. Japan NIES No.2 river clay standard sample and 83-40 Tibet soil standard sample were determined. The obtained values were in good agreement with reference values. The standard deviation of the method was less then 5%. Detection limit was about 0.1 #mu#g Pb.
A procedure for the determination of lead in various biological and environmental samples by "2"0"3Pb radioisotope dilution substoichiometric method is presented. The accuracy of the method by comparison with the literature values of reference materials appears to be good. The standard deviation of the method is less than 10%, and detection limit is about 0.1 #mu#g of lead. (author) 5 refs.
Measurements of temperature and NO concentration in laminar, partially premixed methane-air flames stabilized on a ceramic burner in coflow are reported. The NO concentration and temperature were determined by laser-induced fluorescence (LIF) and coherent anti-Stokes Raman scattering (CARS), respectively. Upstream heat loss to the burner was varied by changing the exit velocity of the fuel-air mixture at a constant equivalence ratio of 1,3; this alters the structure of the flame from an axisymmetric Bunsen-type to a strongly stabilized flat flame. To facilitate analysis of the results, a method is derived for separating the effects of dilution from those of chemical reaction based on the relation between the measured temperature and the local mixture fraction, including the effects of upstream heat loss. Using this method, the amount of NO formed during burnout of the hot, fuel-rich combustion products can be ascertained. In the Bunsen-type flame, it is seen that ...
The objective of this paper is to present a theoretical evaluation of soil and house related factors that may affect the transport of radon from the soil into houses. A two-dimensional mathematical model was used to simulate the diffusive and convective transport of radon into the house through idealized openings in the understructure. With the help of model predictions we tried to find out whether diffusion or convection predominates and under which circumstances. Radon transport through cracks in the house understructure is influenced mainly by the soil permeability, radon concentration at the soil-crack interface, the total area of cracks and the pressure difference across cracks. Because of its large range of variability, the soil permeability appears to have the greatest effect on the radon transport through cracks. At permeabilities below 1x10"-"1"2 m"2 diffusive transport predominates and is almost invariable with the soil permeability. For permeabilities between 1x10"-"1"2 m"2 ...
Large scale experiments were performed to determine the effectiveness of thermal glow plug igniters to burn hydrogen in a condensing steam environment due to the presence of water sprays. The experiments were designed to determine if a detonation or accelerated flame could occur in a hydrogen-air-steam mixture which was initially nonflammable due to steam dilution but was rendered flammable by rapid steam condensation due to water sprays. Eleven Hydrogen Igniter Tests were conducted in the test vessel. The vessel was instrumented with pressure transducers, thermocouple rakes, gas grab sample bottles, hydrogen microsensors, and cameras. The vessel contained two prototypic engineered systems: (1) a deliberate hydrogen ignition system and (2) a water spray system. Experiments were conducted under conditions scaled to be nearly prototypic of those expected in Advanced Light Water Reactors (such as the Combustion Engineering (CE) System 80+), with ...
Against the background of more severe limitation of particle emission in all application areas of Diesel engines, it is necessary to monitor the particle emission, but also the chemical composition of the particles. The basis of assessing particle emission is formed by gravimetric determination of the particle concentration from exhaust gasdiluted with particle-free ambient air, with a maximum temperature of 52 degrees C at the sampling position. While it is already possible, using the part flow dilution system, to take samples locally, previously the subsequent particle determination and characterisation could only be done in a chemical laboratory. For this reason, the C/S particle measurement process was developed as an alternative to gravimetry, which can be used locally, eg: on ships and which makes it possible to determine the particle mass and composition. This process is based on a thermographic carbon and sulphate ...
1 - Description of program or function: This library for fusion neutronics calculations, to be used in conjunction with the TRANSX code, is the MATXS format version of ZZ-GEFF-2-GENDF from which it has been derived by means of the MATXSR NJOY module. It has a 175 neutron, 42 photon VITAMIN-J group structure with the standard weighting function: Maxwellian (at the temperature to which the material is referenced) + 1/E + fission spectrum + 1/E + fusion peak + 1/E. It includes 93 materials from 1-H-1 to Bi-209 - almost all from EFF-2 basic data; but Ag-107, Ag-109, natural Cd, the 6 Hf isotopes and the 4 W isotopes have been taken from JEF-2.2 - at 3 temperatures and 6 dilution cross section values; 10 thermal groups are provided below 3 eV. Neutron cross sections and diffusion matrices, photon and gas production, kerma and DPA are given. The library includes H in H2O, metallic Be and Graphite for which an accurate treatment with S(alpha, beta) ...
Full text of publication follows: The TUV NORD e.V. is an independent Technical Support Organisation (TSO) performing safety assessments in almost every field of technology. In nuclear safety the TUV can look back on more than 40 years of experience. In the last years in Germany PWR safety analyses were focussed on boron dilution events with the potential of reactivity transients. The possibility of coolant with a low boron concentration collected in localized areas of the reactor coolant system (RCS) can be caused by injection of coolant with less boron content from interfacing systems (external dilution) as well as separation of borated reactor coolant into highly concentrated and diluted fractions (inherent dilution). Inherent dilution can e.g. occur after reflux-condenser heat transfer after a small break loss of coolant accident (SBLOCA) with a limited operability of the ...
Objective To investigate value of magnetic resonance cholangiopancreatography (MRCP) using oral diluted gadolinium (Gd)-diethylenetriamine penta-acetic acid (DTPA) as negative contrast materials in diagnosis of juxtapapillary duodenal diverticulum with atypical imaging features. Methods Nineteen patients with juxtapapillary duodenal diverticula of which imaging findings were atypical underwent MRCP using oral diluted Gd-DTPA as negative contrast materials after conventional MRCP without any oral contrast materials. Results Twenty diverticula were revealed in the 19 patients. At conventional MRCP, the diverticula appeared as rounded lesion with high signal intensity. After oral administration of diluted Gd-DTPA, they disappeared at MRCP. These entities were diagnosed as duodenal diverticula...
We provide a brief review of our recent results from optically detected magnetic resonance studies of grown-in non-radiative defects in two most important dilute nitride systems-Ga(In)NAs grown on GaAs substrates and Ga(Al,In)NP grown on Si and GaP substrates. These results have led to the identification of defect complexes in the alloys, involving intrinsic defects such as As_G_a antisites and Ga_i self-interstitials. They have also shed light on formation mechanisms of the defects and on their role in non-radiative carrier recombination that is harmful to the performance of potential optoelectronic and photonic devices based on these dilute nitrides.
Inherent boron dilution can occur in case of a Small Break LOCA when low borated water is mainly accumulated in the U-legs due to reflux boiling in the Steam Generator tubes after the loss of natural circulation. The restart of the natural circulation may lead to criticality because of the injection of these low borated slugs towards the core. To evaluate this potential risk, the boron concentration at the core inlet has to be known which makes necessary to estimate the mixing phenomena in the cold leg, in the downcomer and in the lower plenum: CFD calculations are required. First of all the validation of CFX5 CFD code on the relevant phenomena of inherent boron dilution has been established (UPTF TRAM C3 test). Then, an application to the 900 MW French Pressurized Water Reactor series has been performed. (authors)
The nuclear complex in Tarapur, Maharashtra is a multi facility nuclear site comprising of power reactors and research facilities. Each facility has independent liquid effluent discharge line to Arabian Sea. Experimental studies were conducted to evaluate dilution factors in the aquatic environment using liquid effluent releases as tracer from one of the facilities. 3H and 137Cs radioisotopes present in the routine releases were used as simulated tracer nuclides. The dilution factors(D.F) observed for tritium were in the range of 20-20000 in a distance range of 10 m to 1500 m respectively and for 137Cs the D.F. were in the range of 50 to 900 over a distance range of 10-200 m. The paper describes the analytical methodology and sampling scenarios and the results of dilution factors obtained for Tarapur aquatic environment. (author)
High-temperature LiCl-KCl molten salt medium provides an efficient way to produce the paramagnetic Eu(II) ion to be magnetically diluted into a diamagnetic host medium. Eu(II) was formed by a dissolution and an auto-reduction processes in a high-temperature LiCl-KCl eutectic melt at 723 K by using Eu{sub 2}O{sub 3} as a starting material. By using EPR and luminescence spectroscopic method, we studied the nature of the magnetically isolated paramagnetic Eu(II) ion diluted in a LiCl-KCl medium. With the aid of these spectroscopic tools, it was found that stable Eu(II) species was formed spontaneously at 723 K under anaerobic conditions. EPR and luminescence spectroscopy provided detailed information regarding the nature of the europium ion in a molten salt.
High-temperature LiCl-KCl molten salt medium provides an efficient way to produce the paramagnetic Eu(II) ion to be magnetically diluted into a diamagnetic host medium. Eu(II) was formed by a dissolution and an auto-reduction processes in a high-temperature LiCl-KCl eutectic melt at 723 K by using Eu_2O_3 as a starting material. By using EPR and luminescence spectroscopic method, we studied the nature of the magnetically isolated paramagnetic Eu(II) ion diluted in a LiCl-KCl medium. With the aid of these spectroscopic tools, it was found that stable Eu(II) species was formed spontaneously at 723 K under anaerobic conditions. EPR and luminescence spectroscopy provided detailed information regarding the nature of the europium ion in a molten salt.
High-temperature LiCl-KCl molten salt medium provides an efficient way to produce the paramagnetic Eu(II) ion to be magnetically diluted into a diamagnetic host medium. Eu(II) was formed by a dissolution and an auto-reduction processes in a high-temperature LiCl-KCl eutectic melt at 723K by using Eu2O3 as a starting material. By using EPR and luminescence spectroscopic method, we studied the nature of the magnetically isolated paramagnetic Eu(II) ion diluted in a LiCl-KCl medium. With the aid of these spectroscopic tools, it was found that stable Eu(II) species was formed spontaneously at 723K under anaerobic conditions. EPR and luminescence spectroscopy provided detailed information regarding the nature of the europium ion in a molten salt.
Inherent boron dilution can occur in case of a small Break LOCA when low borated water is accumulated in the U-legs due to reflux boiling in the Steam Generator tubes after the loss of natural circulation. The restart of the natural circulation may lead to criticality because of the injection of these low borated slugs towards the core. To evaluate this potential risk, the boron concentration at the core inlet has to be known which makes necessary to estimate the mixing phenomena in the cold leg, in the downcomer and in the lower plenum: CFD calculations are required. First of all the validation of CFX5 CFD code on the relevant phenomena of inherent boron dilution has been established (UPTF TRAM C3 test). Then, an application to the 900 MW French Pressurized Water Reactor series has been performed. (authors)
An apparatus for measuring the overall decontamination factors of first and second filters located in a plenum. The first filter separates the plenum's upstream and intermediate chambers. The second filter separates the plenum's intermediate and downstream chambers. The apparatus comprises an aerosol generator that generates a challenge aerosol. An upstream collector collects unfiltered aerosol which is piped to first and second dilution stages and then to a laser aerosol spectrometer. An intermediate collector collects challenge aerosol that penetrates the first filter. The filtered aerosol is piped to the first dilution stage, diluted, and then piped to the laser aerosol spectrometer which detects single particles. A downstream collector collects challenge aerosol that penetrates both filters. The twice-filtered aerosol is piped to the aerosol spectrometer. A pump and several valves control the movement ...
Results of hot cracking on welds with compositions between alloy 800 and AWS ER NiCr 3. Investigation of the influence of Si, Mn, Ti and Al on the hot cracking suscpetibility of the alloy 800. (orig.).
Solid molecular orthohydrogen exhibits orientational order at low temperatures. The orthohydrogen molecules, which are quadrupoles, order in the Pa3 structure. We have simulated this ordering, and explored the behaviour under dilution by spherical parahydrogen molecules.
Randomly amplified polymorphic DNA (RAPD) analysis and the PCR assay were used in combination with dilution plating on a semiselective medium to detect and enumerate propagules of Trichoderma...Full Text Available
In this study we use the multiple indicator dilution technique to outline the kinetic mechanisms underlying the uptake of rubidium, a cation which, in the steady state, is concentrated by hepatic parenchymal...Full Text Available
... dilutions greater than 10 -5 for an end-point. ... Polyvinyl polypyrrolidone (PVPP) (Sigma, P-6755); NET buffer ... The adsorbent celite should prevent filter clogging. ...
Maintenance energy expenditures were mesured for five rumen bacteria, Selenomonas ruminantium, Butyrivibrio fibrisolvens, Bacteroides ruminicola, Megasphaera elsdenii, and Streptococcus bovis, by using a complex medium with glucose as the carbon source. Large differences (as high as 8.5-fold) in maintenance energy expenditures were seen among these bacteria. The suggestion is made that maintenance requirements could be a significant determinant of bacterial competition in the rumen. Theoretical maximum growth yields, calculated from double reciprocal plots of yield versus dilution rate, were compared to theoretical Y(ATP) values in order to estimate minimum molar adenosine 5'-triphosphate yields from glucose for each bacterium. Results showed that relative yield among the bacteria was growth rate dependent. At high dilution rates, both S. ruminantium and S. bovis produced lactate as their principal fermentation product. At lower ...
The in vitro activity of chephaloridine, cephalexin, cefatrizine (BL-S640), and cephapirin (BL-P-1322) was evaluated by the serial dilution method against pathogenic gram-positive and gram-negative...Full Text Available
In the context of the shock-initiation problem, we study analytically the first effects of chemistry, treating a small chemical heat release as a perturbation on an inert flow. Specifically, we study the initial transient in plane-shock initiation in a dilute explosive, where the chemical energy is small relative to the mechanical-thermal energy. The vehicle for the study is the mathematical analog for reactive flow. The solution resembles a double refraction: to first order, the pressure or density is a superposition of two forward-going waves, both originating at the rear boundary, and carrying the same function, but running at different velocities. Surprisingly, this first-order solution is independent of the sensitivity of the reaction rate to the state, which appears only at second order.
CT is the most accurate method to detect pulmonary emphysema in vivo. They compared prospectively two different methods for emphysema quantitation in 5 normal volunteers and 20 consecutive patients with chronic obstructive pulmonary disease (COPD). All subjects were submitted to function tests and HRCT; three scans were acquired at preselected levels during inspiration. The type and extent of pulmonary emphysema were defined by two independent observers under blind conditions. Disagreements were subsequently settled by consent. All subjects were also examined with expiratory spiral CT using a density mask program, at two different cut-off levels (-850,-900 HU). Visual score and expiratory spiral density mask values (-850 HU) were significantly correlated (r = 0.86), but the visual extent of emphysema was always higher than shown by expiratory spiral CT. The emphysema extent assessed with both CT methods correlated with the function result of expiratory airflow obstruction and ...
CT is the most accurate method to detect pulmonary emphysema in vivo. They compared prospectively two different methods for emphysema quantitation in 5 normal volunteers and 20 consecutive patients with chronic obstructive pulmonary disease (COPD). All subjects were submitted to function tests and HRCT; three scans were acquired at preselected levels during inspiration. The type and extent of pulmonary emphysema were defined by two independent observers under blind conditions. Disagreements were subsequently settled by consent. All subjects were also examined with expiratory spiral CT using a density mask program, at two different cut-off levels (-850,-900 HU). Visual score and expiratory spiral density mask values (-850 HU) were significantly correlated (r = 0.86), but the visual extent of emphysema was always higher than shown by expiratory spiral CT. The emphysema extent assessed with both CT methods correlated with the function result of expiratory airflow obstruction and ...
For evaporation crystallization of extremely corrosive FGD scrubber solutions which - depending on the process - can lead all the way to a product suitable for depositing, an economic equipment concept based on metallic construction materials was to be investigated. In a parameter study, electrochemical test methods were used to determine the influence of the pH value, the Fe{sup 3+}, F and So{sub 2} contents in a solution containing 200 g/l CaCl{sub 2}+30 g/l NaCl at 80deg C on the resistance to pitting corrosion of stainless steels and NiCrMo alloys. In addition, electrochemical and wet corrosion tests (e.g. crevice corrosion) were conducted using original FGD scrubber solutions with 43-50% dry substance from the power plants Reuter-West, Oberhavel and Rudow of the BEWAG, Berlin. The results were compared to those of standardized and non-standardized short-term tests for determining the critical pitting corrosion and crevice corrosion temperatures for the various materials. Of the ...
Carbon capture and storage have been receiving increasing interest lately, mainly as an option to reduce CO{sub 2} emissions from the power sector. The concept could be adapted for production of H{sub 2} as well, which would provide a carbon free energy carrier that could be used for example as transportation fuel. In this doctoral thesis, the option to use chemical-looping technologies to produce H{sub 2} from fossil fuels with CO{sub 2} capture is explored. In chemical-looping combustion, direct contact between fuel and combustion air is avoided. Instead, a solid oxygen carrier performs the task of bringing oxygen from the air to the fuel. Thus, the resulting CO{sub 2} and H{sub 2}O are not diluted with N{sub 2}, and pure CO{sub 2} can easily be recovered by cooling and condensation. The heat of reaction is the same as for ordinary combustion. Chemical-looping reforming uses the same basic principles as chemical-looping combustion, but operates at under ...
The twin-cities of El Paso and Juarez share the water resources of the Hueco Bolson aquifer and overlying Rio Grande aquifer. Both aquifers span the international border between Mexico and the United States. Salinity in the Rio Grande aquifer varies widely, some parts of the shallow aquifer containing less than 1,000 mg/L total dissolved solids (TDS), other parts of the aquifer exceeding 5,000 mg/L TDS. One sizable part of the "Lower Valley" area, approximately 45 km below El Paso contains very dilute water near the outer edge of the floodplain. Historically it had been thought that the dilute waters in this location were derived from recharge from arroyos that drained proximal parts of the Hueco Bolson. Instead, our hydrogen and oxygen isotope data and carbon-14 data indicate that these dilute waters were derived from pre-dam infiltration of the Rio Grande. Relatively light and slightly evaporated pre-dam waters (-11.5 ...
We have measured the Raman isotropic profiles of the ?(C?N) band at 2235 cm(-1) for five solutions of ME6N (4-cyanophenyl-4'-hexylbenzoate) liquid crystal dissolved in CCl(4) in the range from x = 0.12 to 0.007 (x, mole fraction of ME6N) and then obtained the corresponding vibrational correlation functions, C(v)(t), by time Fourier transformation. The increase with dilution of the dephasing times ?(v) complies with the behavior of the nonmonotonic concentration dependence predicted by the fluctuation concentration model for this concentration range (x Rothschild, which, being based on the assumption that the environmental modulation is described by a stretched exponential decay e(-(t/?(0))(?)), is more appropriate for the interpretation of the vibrational correlation function arising from a distribution of relaxation processes caused, as in the present case, by the persistence of pseudonematic domains. With dilution the dispersion parameter ? ...
The invention relates to a method for purifying a gas mixture containing at least one undesirable gas compound utilizing certain sulfonamide or sulfamide solvents.
Macronutrient self-selection and responses to dietary protein dilution were investigated in Senegalese sole, a flatfish species of interest for Mediterranean aquaculture. Eight groups of six sole were distributed among 75-l tanks and allowed to feed on three experimental diets composed of pure macronutrients: PC (75% crude protein and 25% carbohydrate), PF (75% crude protein and 25% crude fat) and PFC (10% crude protein, 45% crude fat and 45% carbohydrate). Choosing from the above diets, the sole selected a diet containing 68.0% crude protein, 15.7% crude fat and 16.3% carbohydrate. When the PF diet was diluted 50% with cellulose, the fish increased their feed intake to sustain the energy intake (5.0?kJ/kg BW/day). Their selection of fat remained unchanged, while carbohydrate selection sig...
This project evaluated the feasibility of using a low-concentration (approx. 0.5 wt %) chemical cleaning process to remove corrosion product deposits from steam generator surfaces and magnetite from tube-to-support plate crevices of PWR steam generators. The primary objective was to develop a dilute process that could be safely applied at scheduled intervals, such as during normal refueling outages, to maintain a clean operating condition in the steam generator. The dilute chemical cleaning process developed in this project was demonstrated successfully on two model generators which were operated on faulted chemistry by DOE/CRC at Commonwealth's State Line Facility. Unit 5 was cleaned after 48 days of operation with 1% seawater fouling, and Unit 6 was cleaned after 112 days of operations with Lake Michigan water. This report describes work leading to the model generator cleaning demonstrations and provides details of the cleaning ...
This project evaluated the feasibility of using a low-concentration (approx. 0.5 wt %) chemical cleaning process to remove corrosion product deposits from steam generator surfaces and magnetite from tube-to-support plate crevices of PWR steam generators. The primary objective was to develop a dilute process that could be safely applied at scheduled intervals, such as during normal refueling outages, to maintain a clean operating condition in the steam generator. The dilute chemical cleaning process developed in this project was demonstrated successfully on two model generators which were operated on faulted chemistry by DOE/CRC at Commonwealth's State Line Facility. Unit 5 was cleaned after 48 days of operation with 1% seawater fouling, and Unit 6 was cleaned after 112 days of operations with Lake Michigan water. This report describes work leading to the model generator cleaning demonstrations and provides details of the cleaning operation for ...
The first automated method for the determination of mexiletine hydrochloride - an antiarrhythmic agent - is reported. The method is based on the reaction of the analyte with o-phthalaldehyde (OPA) in the presence of sulfite in basic medium using a sequential injection (SI) manifold. The reaction product was monitored spectrofluorimetrically (lex=350nm/lem=446nm). A simple and effective on-line dilution approach was adopted in order to expand the linearity and apply the method to assay, dosage uniformity and dissolution tests with minimum sample preparation. Chemical (pH, amount concentrations of OPA and sulfite) and instrumental variables (temperature, flow rate, injection volumes, etc.) that affected the determination were studied. The developed assay was validated in terms of linearity, ...
Dilute caustic high-level radioactive waste slurries can induce pitting corrosion in carbon steel. Cyclic potentiodynamic polarization tests were conducted in simulated and actual waste solutions to determine minimum concentrations of sodium nitrate which inhibit pitting in ASTM A537 class 1 steel exposed to these solutions. Susceptibility to pitting was assessed through microscopic inspection of specimens and inspection of polarization scans. Long-term coupon immersion tests were conducted to verify the nitrite concentrations established by the cyclic potentiodynamic polarization tests. The minimum effective nitrite concentration is expressed as a function of the waste nitrate concentration and temperature.
The effect of four extracts from neem seeds (Azadirachta indica) containing 2000, 5000, 9000 and 10,000ppm of azadirachtin A (AZA), quantified by high-performance liquid chromatography (HPLC) and diluted to 1.25%; 2.5%; 5.0%; 10.0% and 12.8% was verified by in vitro tests with engorged females and larvae of the cattle tick Rhipicephalus microplus. The results from the bioassays with the engorged females showed that the main toxic effect of the extracts was reduction of the reproductive parameters, with a sharp drop in the number of eggs laid and the hatching rate, mainly when the extracts were diluted to 10.0% and 12.8%. The product effectiveness (PE) calculations for all the solutions tested showed that the AZA solution at 10,000ppm (N10) was the most effective. However, statistical analy...
Objective: To develop a method for RIA of transferrin without dilution of the serum sample. Methods: The measurable range was broadened through: Lowering of the specific radioactivity of the labelled antigen, increasing the concentration of the anti-serum and improve the curve fitting method. Results: The antiserum affinity was 3.82 x 10"-"1"0 mol/L, the specific radioactivity of the labelled antigen was 15.3 mg/mic, inter-assay error CV 5.38%, intra-assay error CV = 3.5% and the shape of the curve was good. For 30 normal control specimens, the mean TF content was 2.81 +- 0.972 mg/ml. Conclusion: Development of a method for RIA of TF without previous dilution of the test serum was of clinical value
Microcrystalline silicon carbide ({mu}c-SiC) was prepared at low substrate temperatures using Hot Wire chemical vapor deposition (HWCVD). High crystalline volume fractions were achieved at high hydrogen dilution and high deposition pressure. Without intentional doping, such material shows high dark conductivity and high optical absorption below the band gap. The material prepared at low deposition pressure or low hydrogen dilution, on the other hand, shows much lower conductivity and sub-gap absorption, but high spin densities up to 5 x 10{sup 19} cm{sup -3}. This high absorption can be attributed to free carriers, different to {mu}c-Si:H where a correlation between the sub-gap absorption and the spin density is observed.
In this study, the effect of intake charge dilution with carbon dioxide on the combustion and emission characteristics of a 4-cylinder direct-injection diesel engine fueled with biodiesel, ethanol-biodiesel and methanol-biodiesel were investigated. With increase of intake CO"2 concentration, CO, HC, particulate mass concentration, particle number concentration and geometric diameter (GMD) of all fuels increased while NO"x decreased obviously. After addition of methanol and ethanol in biodiesel, the NO"x, particulate mass concentration and particle number concentration decreased at each intake CO"2 concentration, compared with biodiesel. Moreover, as the intake CO"2 concentration increased from 2% to 5.6%, particulate mass concentration of the alcohol-biodiesel blends remained almost unchan...
This paper describes the benchmark analysis results of Rapid Boron Dilution (RBD) transient tests. The RBD transient tests were carried out at University of Maryland. The data were obtained as a part of the International Standard Problem No. 43, ISP-43, for code assessment. Nuclear Power Engineering Corporation (NUPEC) participated the benchmark analysis of ISP443 with the PLASHY code. The PLASHY code is a general purpose single-phase fluid analysis code, developed by NUPEC. The code has two types of module, Cartesian/Cylindrical coordinate system module and BFC module. In order to reduce the computing time, the Cartesian/Cylindrical coordinate system module was employed. All calculations were done on a parallel computer, IBM SP2, by using the 12 of 76 CPU units. (author)
Experiments based on a 23 central composite full factorial design were carried out in 200-ml stainless-steel containers to study the pretreatment, with dilute sulfuric acid, of a sugarcane bagasse sample obtained from a local sugar?alcohol mill. The independent variables selected for study were temperature, varied from 112.5?C to 157.5?C, residence time, varied from 5.0 to 35.0 min, and sulfuric acid concentration, varied from 0.0% to 3.0% (w/v). Bagasse loading of 15% (w/w) was used in all experiments. Statistical analysis of the experimental results showed that all three independent variables significantly influenced the response variables, namely the bagasse solubilization, efficiency of xylose recovery in the hemicellulosic hydrolysate, efficiency of cellulose enzymatic saccharificatio...
A publication on Norwegian gas and gas export. The content is wide spread from use of gas in daily life via sub sea pipeline repair systems to an overview over tomorrows gas fields. (AG)
Inorganic acids are commonly used for surface cleaning and finishing of metals. The acids become unuseable due to contamination with metals or diluted and weakened. Diffusion dialysis has become a way to recover the useable acid and allow separation of the metals for recovery and sale to refineries. This technique is made possible by the use of membranes that are strong enough to withstand low ph and have long service life.
Samples of geothermal scale formed from Magmamax No. 1 and Woolsey No. 1 wells in the Imperial Valley, Calif., were exposed to concentrated and dilute solutions of common laboratory reagents. The time of exposure and temperature of the reagent were also varied. Several reagents easily dissolved significant amounts of the scale. An in situ test was performed with marginal success.
In Ce(Ru{sub 1-x}Pd{sub x}){sub 2}Si{sub 2} the dilution of the transition metal leads to strong electronic effects resulting in the disappearance and the appearance of long-range magnetic order in CePd{sub 2}Si{sub 2} and CeRu{sub 2}Si{sub 2}, respectively. ((orig.)).
In Ce(Ru_1_-_xPd_x)_2Si_2 the dilution of the transition metal leads to strong electronic effects resulting in the disappearance and the appearance of long-range magnetic order in CePd_2Si_2 and CeRu_2Si_2, respectively. ((orig.)).
The author is exploring the efficiency of pulsed plasma processing in the removal of nitrogen dioxide, nitrogen oxide, and other pollutants. This process uses an electrical discharge to create chemical radicals from air molecules. These radicals can react with pollutants and form harmless compounds. Additives such as hydrocarbons are also used to improve the efficiency of the removal. The efficient removal of nitrogen dioxide has required the presence of dilute aqueous solution of ammonia.
Using spectral hole-burning-based ultraslow group velocity in a dilute solid medium, we report enhanced photon echo efficiency three orders of magnitude higher than that in a nonslow light regime. The enhancement is due to exponentially increased absorption of an optical data pulse owing to the enhanced photon-atom interaction in an ultraslow light regime, whereas echo reabsorption is negligibly small due to group-velocity dependent population depletion.
Neutron activation of nitrogen and hydrogen in the body, the isotope dilution technique and the measurement of naturally radioactive potassium in the body are among the new nuclear methods, now under collaborative development by the Australian Nuclear Scientific and Technology Organization and medical specialists from several Sydney hospitals. These methods allow medical specialists to monitor the patient's response to various diets and dietary treatments in cases of cystic fibrosis, anorexia nervosa, long-term surgical trauma, renal diseases and AIDS. ills.
This study evaluates the frequency and functions of immunocompetent T cells at the clonal level in solid human lung tissue versus peripheral blood. Enzymatic digestion of slices of histologically normal...Full Text Available
Free-electron-laser (FEL) oscillators require a train of high-brightness bunches. Conventional subharmonic bunchers are currently used with rf linacs to generate pulse trains, but the resulting dilution of the transverse phase space and lower beam brightness are unacceptable for high-performance FELs. Recent developments suggest that photoemitters of high quantum efficiency combined with rapid acceleration can produce pulse trains of higher brightness than has been achieved before.
A gas diffusion semiconductor electrode and solar cell and a process for gaseous fixation, such as nitrogen photoreduction, CO/sub 2/ photoreduction and fuel gas photo-oxidation are described. The gas diffusion photosensitive electrode has a central electrolyte porous matrix with an activated semiconductor material on one side adapted to be in contact with an electrolyte and a hydrophobic gas diffusion region on the opposite side adapted to be in contact with a supply of molecular gas.
In the groundwater flow modelling part of this work the effective dilution volume in the well scenario was estimated by means of transient simulations of groundwater flow and transport, which are coupled due to the varying salinity. Both deep, drilled wells and shallow surface wells in the vicinity of the repository were considered. The simulations covered the time period from the present to 1000 years after the present. Conceptually the fractured bedrock consists of planar fracture zones (with a high fracture density and a greater ability to conduct water) and the intact rock (in which the fracture density and the hydraulic conductivity are low). For them the equivalent-continuum model was applied separately. Thus, the fractured bedrock was considered as piecewise homogeneous (except for the depth dependence) and isotropic continuum with representative average characteristics. A generic simulation model for groundwater flow and solute transport was developed on ...
The book tries about the International and national aspects, natural gas situation, production, consumption, prices, demand projection, energetic plans, norms and laws of the natural gas in Colombia
This document provides information on the supply and disposition of natural gas to a wide audience. The 1996 data are presented in a sequence that follows natural gas from it`s production to it`s end use.
The origin of natural gas in the Japanese oil and gas fields are geochemically studied. Samples are taken from structural natural gas, surface gas seepage, water-dissolved natural gas and coal-field gas of the Japan Sea coast area. The origins of primary hydrocarbons are classified into bacteria gas and thermogenic gas, the latter being subclassified into gas in oil production zone with the per million deviation of the carbon isotope (/sup 13/C/sup 1/) of methane less than -35 and those gases with maturity higher than this. Surface gas seepage is subjected to migration and bacterial oxidation. Coal gas is similar to oil gas. The CO/sub 2/ concentration is 0 - 2% and /sup 13/CO/sub 2/ deviations from -30 - +30. The origin can be barely ...
Many older homes are equipped with mercury-containing gas regulators that reduce the pressure of natural gas in the mains to the low pressure used in home gas piping. Removal of these regulators can...Full Text Available
Sewage gas or biogas as a product of anaerobic digestion contains methane and carbon dioxide as its main components. Biogas is scrubbed off carbon dioxide in absorption columns and purified to natural-gas quality. The purified gas then is piped to the gas pressure control station and fed into the public network. Description of process and plant is given.
We report the performance of a micro gas turbine on biomass producer gas and mixtures of biomass producer gas with natural gas. The micro gas turbine delivers full power on gas mixtures with a heating value of at least 15 MJ/Nm{sup 3}. For gas of lower heating value, the maximum fuel gas flow limits the attainable power. The lower limit for stable operation is about 8 MJ/Nm{sup 3}. The gross efficiency of the micro gas turbine depends on output power but not on the gas heating value, within our measurement accuracy. Above 70% of full power, emissions of CO and NO are 40 and 10 times lower than those of a gas engine of similar size. At part load below 70% of full power, the micro gas turbine burner switches to a different operating mode ...
A dilute tungsten heavy alloy consisting of 50W-35Ni-15Fe (wt pct) was liquid phase sintered at 1,500 C for times ranging from 30 to 960 minutes. This alloy corresponds to a nominal solid content of 20 vol pct at the sintering temperature. Because of the excess liquid, the alloy densified easily and exhibited extensive liquid-solid separation due to the density difference between the phases. The solid content at the compact bottom ranged from 45 to 70 vol pct over position and time. The microstructure of the settled region was quantified for volume fraction of tungsten, grain size, connectivity, and settled solid angle of repose. These results provide a basis for extending the microstructural parameters to possible microgravity conditions. The grain growth rate constant varies with the inverse 2/3 power of the volume fraction of liquid, possibly reflecting combined coalescence and solution-reprecipitation processes. This volume-fraction effect on the ...
A dilute tungsten heavy alloy consisting of 50W-35Ni-15Fe (wt pct) was liquid phase sintered at 1,500 C for times ranging from 30 to 960 minutes. This alloy corresponds to a nominal solid content of 20 vol pct at the sintering temperature. Because of the excess liquid, the alloy densified easily and exhibited extensive liquid-solid separation due to the density difference between the phases. The solid content at the compact bottom ranged from 45 to 70 vol pct over position and time. The microstructure of the settled region was quantified for volume fraction of tungsten, grain size, connectivity, and settled solid angle of repose. These results provide a basis for extending the microstructural parameters to possible microgravity conditions. The grain growth rate constant varies with the inverse 2/3 power of the volume fraction of liquid, possibly reflecting combined coalescence and solution-reprecipitation processes. This volume-fraction effect on the ...
This procedure describes the formulation and make-up of Simulated Dilute Water (SOW), a low-ionic-content water to be used for Activity E-20-50, Long-Term Corrosion Studies. This water has an ionic content which is nominally a factor of ten higher than that of representative waters at or near Yucca Mountain. Representative waters were chosen as J-13 well water [Harrar, 1990] and perched water at Yucca Mountain [Glassley, 1996]. J-13 well water is obtained from ground water that is in contact with the Topopah Spring tuff, which is the repository horizon rock. The perched water is located in the Topopah Spring tuff, but below the repository horizon and above the water table. A nominal times ten higher ionic content was chosen to simulate the effect of ionic concentrating due to elevated temperature water flowing through fractures where salts and minerals have been deposited due to evaporation and boiling.
Liquid-liquid extractive separation of lithium isotopes was carried out in order to investigate the fluctuation of separation factors (a) as a function of salt concentrations in an aqueous phase. Two equations for separation factor (a_o_b_s) as a function of the concentration were introduced; one for the diluted region, and another for the concentrated region. In the former solution where hydrated lithium ions are predominant, 1n a_o_b_s = Ac + B, and in the latter where ion-pairs with anions are predominant, 1n a_o_b_s = Dc + E(c - F)"1"/"3 + G. Some guidelines are derived from the salt-specific constants A, B, D, E, F and G. The heavier isotopes are inclined to be in the more hydrated state in the diluted solution, while the lighter isotopes tend to be in a less hydrated state. In the concentrated solution, heavier isotopes are more likely to be in ion-pair form. Ionic association occurs from the lower concentration in the order of LiI < ...
We show the existence of global-in-time weak solutions to a general class of coupled FENE-type bead-spring chain models that arise from the kinetic theory of dilute solutions of polymeric liquids with noninteracting polymer chains. The class of models involves the unsteady incompressible Navier-Stokes equations in a bounded domain in two or three space dimensions for the velocity and the pressure of the fluid, with an elastic extra-stress tensor appearing on the right-hand side in the momentum equation. The extra-stress tensor stems from the random movement of the polymer chains and is defined by the Kramers expression through the associated probability density function that satisfies a Fokker-Planck-type parabolic equation, a crucial feature of which is the presence of a center-of-mass diffusion term. We require no structural assumptions on the drag term in the Fokker-Planck equation; in particular, the drag term need not be corotational. With a square-integrable ...
An Allis-Chalmers, Model 2900, turbocharged diesel engine was converted to a dual-fuel engine in which ethyl alcohol was fumigated between the turbocharger and the intake manifold, and the diesel fuel was injected normally at a reduced rate. Tests were performed to determine if crankcase oil dilution that had occurred was caused by the following independent parameters: proof of the ethyl alcohol, crankcase oil temperature, engine load at maximum torque speed, and percentage of total energy in the form of ethyl alcohol. Engine tests were steady state for six hours, after which the crankcase oil was sampled for American Society for Testing and Materials (ASTM) laboratory tests for determination of flash points and fire points, water by centrifuge, water by distillation, and viscosity at room temperature. Results indicate a decrease in thermal efficiency and an increase in exhaust carbon monoxide as the percentage of total energy as alcohol is increased. Additional ...
Biomimetic vesicle media which can selectivity extract and concentrate heavy metals (e.g., Pb{sup 2+}) from dilute solutions of 5 ppm and less have been prepared. At a concentration of only 1% 2/v, these non-covalently assembled, unilamellar, surfactant vesicles provide approximately 1,000m{sup 2} of exposed membrane surface area per liter of suspension which gives rise to very rapid rates of metal ion extraction. To facilitate the selective transport of heavy metal ions through the ion impermeable vesicle wall, the vesicles are doped with lipophilic ionophores, both natural and synthetic. In addition, the metal chelating agent, nitrolotriacetate, is encapsulated in the aqueous vesicle core to provide the driving force for metal ion uptake and concentration. Concentration factors in excess of 1000 fold have been observed. Metal-sorbing surfactant vesicles measuring approximately 100 nm in diameter are stable and have been tested in a bench-scale metal ion ...
Anaerobic treatment of olive oil mill wastewaters (COD up to 220 kg/cubic m) is feasible, and the most promising results were obtained on UASB reactors, both at laboratory and pilot scale (tank capacity 15 litres and 5 cubic m), fed on diluted waste (COD = 13-18 kg/cubic m). Volumetric loading rates ranging from 16-21.5 kg COD/cubic m/day and 70% removal efficiencies were obtained with these digesters. Start-up of UASB reactors fed on olive oil mill waste is a delicate step which still has to be fully controlled and optimized. The best results were obtained by starting with very diluted waste (COD = 5 kg/cubic m). Granulation of the sludge, as achieved in Dutch UASB digesters fed on sugar beet wastewaters, was not obtained, but, even so, the settleability of the sludge was very good. 22 references.
The most effective way to generate electricity out of biomass is the gasification and the use of the gas in a gas engine. The conversion of the organic carbon with the gasification of biomass is higher than 95 %. Depending on the gasification concept, the efficiency of gasifiers is found between 70 and 90 %. If the pyrolysis gas is used in a gas engine, an electric efficiency of about 26 % referring to the primary amount of energy can be obtained. With efficient gas cleaning (cleaning for tar and dust), pyrolysis gas is well qualified for engine combustion. Through modern state of engine controlling there are ways to have complete control of the fluctuations in the gas composition. Furthermore, the minor calorific value of offered wood gas poses no problem for turbo charged lean-burn gas engines. ...
This patent describes an electrodeless lamp. It comprises: a microwave cavity; a source of microwaves in communication with the cavity; a lamp envelope containing a plasma-forming medium mounted within the microwave cavity; a gas manifold for feeding gas to at least one gas passageway for directing a stream of gas to the outer surface of the envelope; a gas leak passageway leading from the gas manifold; a conductive mesh assembly for retaining microwaves within the cavity and permitting light to be emitted from the cavity. The assembly including gas flow blocking means for preventing the flow of gas through the gas leak passageway when the screen is in place in the lamp; and means for shutting off the source of microwaves when the gas pressure in the manifold drops below a ...
Solution and dilution enthalpies of aqueous solutions of potassium diclofenac salt (K_DC) were measured by an isoperibolic calorimeter at 298.15 and 318.5?K. Heat capacities of the solutions with concentrations 0.002?0.09?mol?kg?1 were obtained at the temperature interval of 288.15?318.15?K using a scanning adiabatic microcalorimeter. The virial coefficients were derived from Pitzer?s model, and the excess thermodynamic functions of both the solvent and the solute of the solution were calculated. The concentration and temperature dependencies of thermodynamic characteristics of the solution were analyzed and discussed.
Nitrite is to be used to inhibit pitting corrosion during Extended Sludge Processing (ESP) at the Savannah River Plant. The required nitrite concentrations are expressed as a function of the slurries' nitrate ion concentration and temperature. In the most dilute slurries, the nitrite inhibitor requirement is independent of the nitrate ion concentration and depends only on the temperature of the waste. The nitrate-independent concentration ensures that there is sufficient inhibitor, in sludge slurries whose nitrate has been depleted by radiolysis, to prevent pitting corrosion induced by other corrosive anions (e.g., sulfate and chloride). The threshold nitrate concentration at which the nitrite level is expressed as a function only of temperature is 0.02 M.
Nitrite is to be used to inhibit pitting corrosion during Extended Sludge Processing (ESP) at the Savannah River Plant. The required nitrite concentrations are expressed as a function of the slurries` nitrate ion concentration and temperature. In the most dilute slurries, the nitrite inhibitor requirement is independent of the nitrate ion concentration and depends only on the temperature of the waste. The nitrate-independent concentration ensures that there is sufficient inhibitor, in sludge slurries whose nitrate has been depleted by radiolysis, to prevent pitting corrosion induced by other corrosive anions (e.g., sulfate and chloride). The threshold nitrate concentration at which the nitrite level is expressed as a function only of temperature is 0.02 M.
The study of randomness in low-dimensional quantum antiferromagnets is at the forefront of research in the field of strongly correlated electron systems, yet there have been relatively few experimental model systems. Complementary neutron scattering and numerical experiments demonstrate that the spin-diluted Heisenberg antiferromagnet La2Cu(1-z)(Zn,Mg)zO4 is an excellent model material for square-lattice site percolation in the extreme quantum limit of spin one-half. Measurements of the ordered moment and spin correlations provide important quantitative information for tests of theories for this complex quantum-impurity problem.
We discuss how magnetic phenomena affect superconductivity in simple metals, transition metals and alloys thereof, and dilute Rare-Earth alloys. It is shown both qualitatively and quantitatively that superconductors are sensitive probes for studying itinerant spin excitations, local spin excitations associated with nearly magnetic impurities, the effect of the atomic environment on the stability of local magnetic moments, and the nature of the spin order in Rare-Earth alloys. Also, we discuss how magnetic impurities can be used to study the electronic configuration which is responsible for superconductivity in Laves-phase crystals like A-15 compounds and ..beta..-W crystals, for example.
This paper discusses the mass spectrometric system that has been developed at the ICPP (Idaho Chemical Processing Plant) to meet the multiple constraints of U accountability, high sample load, and plant process control. The measurement system must produce high-quality accountability results while maintaining high sample throughput and reasonable turnaround time. The mass spectrometric system that has evolved to meet these demands includes extensive operator training, routine quality control checks, and continuing review of performance. 7 refs.
XVTa and XXTa nuclei were oriented at low temperature as dilute impurities in Fe. The magnetic hyperfine splitting frequencies = B sub(HF)/Ih of the XVTa and XXTa ground states have been measured to be 320.45(11) and 317.552(55) MHz by using the technique of NMR-ON. Taking the known hyperfine field of Y Ta in Fe, the magnetic moments have been deduced: ( XVTa, 7/2 ) =2.270(45) and ( XXTa, 7/2 ) =2.250(45) sub(N). These values of the magnetic moments are discussed in the framework of the rotational model.
"1"7"5Ta and "1"7"7Ta nuclei as dilute impurities in Fe were oriented at low temperatures. Using the technique of NMR/ON the magnetic moments have been measured: "+#mu#("1"7"5Ta, 7/2"+,"+=2.270(45) #mu# sub(N) and "+#mu#("1"7"5Ta, 7/2"+)"+=2.250(45) #mu# sub(N). These values are discussed in the framework of the rotational model. (author).
A report is given on an improved filler-binder mixing method in the manufacture of artificial graphite, the so-called coat-mix process. The individual graphite-filler grains are coated completely with uniform binder coatings (phenol formaldehyde resin) in a continuous process. Methanol is used as solvent for the resin. In a modified further development of the process, the use of organic solvents can be disregarded by dissolving the binder resin in caustic soda and injecting the slurry into water diluted acid. The manufacture of casting molds from coat-mix powders, their properties and industrial application are given. Finally, the advantages of using carbon bodies of coal-mix material for conversion to silicon carbide are indicated. (IHOE).
A method to achieve NMR of dilute samples in the earth's magnetic field by applying para-hydrogen induced polarization is presented. Maximum achievable polarization enhancements were calculated by numerically simulating the experiment and compared to the experimental results and to the thermal equilibrium in the earth's magnetic field. Simultaneous 19F and 1H NMR detection on a sub-milliliter sample of a fluorinated alkyne at millimolar concentration (1018 nuclear spins) was realized with just one single scan. A highly resolved spectrum with a signal/noise ratio higher than 50:1 was obtained without using an auxiliary magnet or any form of radio frequency shielding.
Scientists of the Institute of Wood Chemistry of the Latvian Academy of Sciences have developed two highly efficient processes for producing furfural, a feedstock for varnishes, synthetic resins and plastics. It is made of production wastes, including branches and small-dimension timber. By one process, the raw material is chipped, treated first with diluted sulphuric acid and then with steam heated to 250 degrees C. The other uses concentrated sulphuric acid as a catalyst. Besides furfural, this process also yields sugar solutions used in alcohol and nutrient yeast production.
LUCIFER (Low-background Underground Cryogenic Installation For Elusive Rates) is a new project for the study of neutrinoless Double Beta Decay, based on the technology of scintillating bolometers. These devices promise a very efficient rejection of the alpha background, opening the way to a virtual background-free experiment if candidates with a transition energy higher than 2615 keV are investigated. The baseline candidate for LUCIFER is 82Se. This isotope will be embedded in ZnSe crystals grown with enriched selenium and operated as scintillating bolometers in a low-radioactivity underground dilution refrigerator. In this paper, the LUCIFER concept will be introduced. The sensitivity and the very promising prospects related to this project will be discussed.
The discovery of nearly sixty molecules, often unstable or complexes, in the interstellar space has been one of the greatest surprises of contemporary astronomy. We may, indeed, be surprised that molecules having up to 13 atoms might be synthetized in an extremely diluted space and at a very low temperature. That these molecules are, most of all, organic molecules is another astonishing subject, at least for the non-specialist. The interstellar molecule formation is indeed well understood nowadays, at least for the simplest ones. This article takes stock of interstellar chemistry which is essentially an ionic chemistry very different from laboratory chemistry.
FLOWER, a computer code recommended by USNRC for assessing the environmental impact in tidal regions, was adapted and improved so as to be suitable to deal with the influence of drift stream along seashore to the dilution of contaminants and heat in the bay mouth. And the code outputs were presented with more mid-results such as average concentrations and temperature values for all tides considered. Finally, the modified code is applied to the dispersion calculation of heat and liquid effluents from Daya Bay Nuclear Power Plant, and the impacts from routine operation of the plant on Daya Bay sea waters were given.
This work is the first active crossflow filter testing of the new strontium-permanganate process for Envelope C at the Savannah River Technology Center. Extreme filtration difficulties with the ferric hydroxide precipitation led to investigations of other chemistries with simulants. The current process includes the isotopic dilution by precipitation from inactive strontium nitrate addition. A permanganate strike to replace ferric reagents was found to provide practical filterability and good lanthanide or transuranic decontamination. That work had been supported with simulant and active beaker testing.
The kinetics of HO{sub 2} radicals in UV-irradiated frozen dilute solutions of H{sub 2}O{sub 2} were followed by the ESR technique. Radical disproportionations at the irradiation temperature were found to be adequately described in terms of dispersive kinetics by a second-order equal-concentration kinetic equation with rate parameters changing non-monotonically in the temperature range 100-200 K. These changes are thought to occur due to well separated structural relaxation regions of polycrystalline ice in the above temperature range. (author).
Eighty-seven subtraction images of FCR were compared with subtraction images of conventional angiography. Although FCR images with reduced exposure dose (25 % of regular dose) and with diluted contrast material (150 mgI/ml, 50 % of usual concentration) were slightly inferior to the images of conventional angiography, most clinically important vessels were adequately visualized. As FCR has wider dynamic range and higher contrast resolution than conventional angiography, FCR may take over conventional angiography. (author).
A process is provided for conducting organic compound conversion over a catalyst composition comprising a specially treated crystalline zeolite having a high initial silica-to-alumina mole ratio, said zeolite having been synthesized from a reaction mixture comprising a diamine as a cation source. The treatment of the zeolite material comprises the sequential steps of reacting the zeolite with a dilute hydrogen fluoride solution, contacting the hydrogen fluoride solution reacted material with aluminum chloride vapor, and then treating the aluminum chloride contacted material to convert it to hydrogen form.
Exhaust fine and ultra fine particle numbers, particle sizes, mass, shape, structure and density were studied from Euro II - EEV emission level heavy-duty vehicles. For total particle emission factors city buses were run on dynamic conditions simulating city bus driving. The new heavy-duty chassis dynamometer of VTT was used. Vehicles were a comprehensive sample of current city bus fleet, the type approved emission level of which was Euro II - Euro III. Also cleaner engines of Euro IV to EEV targeted emission level were included: CRT, CNG, DPF. Particle emissions of these buses were extremely low; numbers 1/100 - 1/1000 and masses 1/10 - 1/100 of those of the predominating techniques. Morphological properties of fine particle populations that represent majority of particle size distribution (Da < 500 nm) are being analyzed by image processing (Matlab) from electron microscopical images (SEM, ESEM and TEM) as a function of particle size. Particles from different formation ...
This document is the combined Remedial Investigation and Feasibility Study Report for the Lower Watts Bar Reservoir (LWBR) Operable Unit (OU). The LWBR is located in Roane, Rhea, and Meigs counties, Tennessee, and consists of Watts Bar Reservoir downstream of the Clinch River. This area has received hazardous substances released over a period of 50 years from the U.S. Department of Energy`s Oak Ridge Reservation (ORR), a National Priority List site established under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). As required by this law, the ORR and all off-site areas that have received containments, including LWBR, must be investigated to determine the risk to human health and the environment resulting from these releases, the need for any remedial action to reduce these risks, and the remedial actions that are most feasible for implementation in this OU. Contaminants from the ORR are primarily transported to the LWBR via the Clinch River. ...
The thesis explains the development of a mass spectrometerical isotope dilution analysis (MS/DA) for determining trace amounts of Tc. The Tc-97 isotope has been prepared by in-core irradiation of Ru of natural isotopic composition, and used as the indicator isotope. For separation of Tc-97 from the Ru matrix, a method has been developed to quantitatively separate Tc-97 from a high Ru surplus. For determining the isotope ratio for the MS/DA, a mass spectrometrical measuring technique has been found which allows reproducible measurement of the Tc-99/Tc-97 isotope ratio. Positive and, for the first time, also negative thermoionisation has been used as a method of selective ionisation of Tc. The applicability of the MS/DA for Tc trace analysis has been verified using two Al foils doped with Tc-99 or Mo-98, respectively. These have been irradiated in a nuclear reactor, the irradiation of Tc-99 yielding Ru-100, and irradiation of Mo-98 Tc-99. The determination of the ...
Biomass and nutrient dynamics of black spruce seedlings during the hardening phase of the greenhouse rotation were examined after four pre-hardening fertilization regimes - conventional, constant-rate loading, exponential loading, and high exponential loading (delivering respectively 15, 40, 40 and 60 mg N seedling{sup -1}) - in order to assess nutrient dilution and steady-state nutrition. Although height growth of seedlings had virtually ceased during hardening, shoot biomass increased 99-142% and root biomass increased five- to tenfold depending on treatment. The biomass increase compromised steady-state nutrient status by diluting internal nutrient pools as nutrient supply was unable to keep up with growth. Soil nutrient levels were rapidly depleted during this period because of plant uptake and lack of fertilizer supplementation. Pre-hardening nutrient loading partly countered and delayed dilution effects, especially ...
Gas hydrates have impacted the oil and gas industry since 1934, when they were first found to plug pipelines. Today we know that in deep oceans and in permafrost, very substantial gas reserves are present in hydrated form. Concerns are being raised about in situ dissociation for both energy and greenhouse implications upon methane release. In Japan work is underway to consider the storage of carbon dioxide, concentrated in clathrates. This talk will deal with some basic questions. Why should we be interested in gas hydrates? What are gas hydrates? How do gas hydrates form? How might hydrates impact on the energy/environmental picture?
This book discusses the progress and problems of current interest in gaseous dielectrics and their use, with special emphasis on insulation in high-voltage transmission lines and substations. Topics covered include: basic physics of gaseous dielectrics; basic mechanisms; gas decomposition, reactions and toxicity; diagnostics and field probes; gases and mixtures for GIS transformers and circuit breakers; gaseous media for discharge chemistry and etching/corona; gas engineering for pulsed power and switching; gas breakdown under steep-fronted voltages; new developments in gas-insulated equipment and gas handling; gas/insulator interface/flashover; and quality control in testing gas-insulated equipment. Contains approximately 85 papers.
Gas hydrates are crystalline substances composed of water and gas, in which a solid-water-lattice accommodates gas molecules in a cage-like structure. Gas hydrates are globally widespread in permafrost regions and beneath the sea in sediment of outer continental margins. While methane, propane, and other gases can be included in the clathrate structure, methane hydrates appear to be the most common in nature. The amount of methane sequestered in gas hydrates is probably enormous, but estimates are speculative and range over three orders of magnitude from about 100,000 to 270,000,000 trillion cubic feet. The amount of gas in the hydrate reservoirs of the world greedy exceeds the volume of known conventional gas reserves. Gas hydrates also represent a significant drilling and production hazard. A fundamental question ...
Gas hydrates are crystalline substances composed of water and gas, in which a solid-water-lattice accommodates gas molecules in a cage-like structure. Gas hydrates are globally widespread in permafrost regions and beneath the sea in sediment of outer continental margins. While methane, propane, and other gases can be included in the clathrate structure, methane hydrates appear to be the most common in nature. The amount of methane sequestered in gas hydrates is probably enormous, but estimates are speculative and range over three orders of magnitude from about 100,000 to 270,000,000 trillion cubic feet. The amount of gas in the hydrate reservoirs of the world greedy exceeds the volume of known conventional gas reserves. Gas hydrates also represent a significant drilling and production hazard. A fundamental question ...
We report the performance of a commercial recuperated micro gas turbine on biomass producer gas and mixtures of biomass producer gas with natural gas. The biomass producer gas, obtained by gasification at 850{sup o}C with air at atmospheric pressure, contains about 7% H2, 17% CO, 15% CO2, 4% CH4, 2% other hydrocarbons, 2% H2O, and a balance of N2 and Ar from air. It has a net heating value of about 6 MJ/(Nm{sup 3}). The micro gas turbine delivers full power (30 kW{sub e}) on gas mixtures with a net heating value of at least 15 MJ/(Nm{sup 3}). For gas of lower heating value, the maximum fuel gas flow allowed by the fuel control unit limits the attainable power. At reduced power, the lower limit for stable operation is a net heating value of about 8 MJ/(Nm{sup 3}). The gross efficiency of the micro ...
The situation of natural gas in the Federal Republic of Germany is described, with particular emphasis on the advantages and consequences of natural gas supply. The brochure discusses the role of natural gas on the energy market, the reliability of natural gas supply, the environmental impacts, the energy-saving effect of natural gas, natural gas prices, the competitive strength of the German gas industry, and the long-term reliability of natural gas supply. (orig.) [German] Die Situation des Erdgases in der Bundesrepublik Deutschland wird beschrieben, wobei die wichtigsten Vorteile und Auswirkungen der Erdgasversorgung besonders hervorgehoben werden. Es geht um die Stellung des Erdgases im Energiemarkt, die Sicherheit der Energieversorgung, Umweltschutz, Energieeinsparung durch Erdgaseinsatz, Erdgaspreise, ...
Effects of combustion conditions on the critical calorific value of flame blowout were reported for low calorific gas on the assumption of using coal derived gaseous fuel. Further, calculations of adiabatic flame temperature by using chemical equilibrium calculation were conducted in order to get a possibility of increasing exit gas temperature of gas turbine combustor to 1,300 C for low calorific value gas fuel. As a result, effects of (1) fuel composition, (2) preheating fuel temperature, (3) calorific value, and (4) combustion air velocity and fuel nozzle diameter, on the critical calorific values of flame blowout were clarified. In increasing exit gas temperature of gas turbine combustor to 1,300 C when using low calorific value gas fuel, it is essential to get an advanced cooling technology for the gas turbine ...
The genetic type, source and charging history of natural gas in the Yulin gas field in the Ordos Basin have been studied by combining the carbon isotopic composition of natural gas and geochemical characteristics of light hydrocarbons with carbon isotope fractionation model results and fluid inclusion analysis. The carbon isotopic composition of methane and ethane in the Yulin gas field is relatively enriched in {sup 13}C with {delta}{sup 13}C{sub 1} values ranging from - 35.3 permille to - 29.8 permille (average value = - 32.4 permille) and {delta}{sup 13}C{sub 2} ranging from - 26.3 permille to - 23.5 permille (average value = - 24.8 permille). The C{sub 7} light hydrocarbons are predominated by methylcyclohexane, accounting for 65.8% to 80.9% (average value = 71.6%), which is characteristic of coal-derived gas. Furthermore, the gas geochemistry indicates ...
The production, principal applications, characteristics and properties, advantages of the gas natural is showed. A sectorial overview of the ceramic industry and the utilization of the natural gas in the ceramic industry is presented. The expectations are systematized and the impact of the natural gas utilization in the ceramic industry is evaluated. Some conclusions are withdrawn and recommendations suggested.
A combined gas/steam turbine process includes a high-pressure furnace and a high pressure gasification unit with a mounted upstream of a combustion chamber there is a gas turbine with a waste heat system. Combustion heat which is not needed to heat the flue gas to combustion temperature is released from the furnace and transferred to ths combustion air going into the combustion chamber.
Nomographs have been developed to simplify site performance estimates for various types of gas turbine engines used for industrial applications. The nomographs can provide valuable data for engineers to use for an initial appraisal of projects where gas turbines are to be considered. General guidelines for the selection of gas turbines are also discussed. In particular, site conditions that influence the performance of gas turbines are described.
The budding natural gas markets in East Europe attract a great deal of interest from natural gas industries in the Western countries. Dutch companies, institutions and the government, too, are active in this market. So far the results have not been spectacular. An analysis is made of the present situation and the Dutch approach
This article puts the case for coal fired combined cycle gas turbine (CCGT) power plants. The need to gasify the coal for the CCGT, use of fluidised bed combustors or gasification systems, the difference in prices of coal and natural gas, and coal and natural gas reserves are discussed. (UK)
Natural gas is essential to the world economy. Gas now accounts for almost a quarter of OECD primary energy requirements and is expected to become the second most important fuel in the world in the next decade. Industrial and residential consumers increasingly rely on natural gas to keep their houses warm, their lights on and their factories running. Meanwhile the gas industry itself has entered a new phase. Where gas used to be restricted to regional markets, it is now increasingly traded on a global scale. While gas production and transport requires long-term investment, now it is optimised on a short-term basis. Demand continues to grow, but local gas production has become much more expensive. How should we react? How will demand be satisfied? What changes are required to promote flexibility and trade? What are the implications for ...
Mist eliminators for flue gas desulphurisation units remove liquid droplets entrained in the flue gas leaving the SO/sub 2/-absorber vessels. The commercial designs currently available are described.
The purpose of this project was to build a long-range, parallel hybrid gas/electric vehicle capable of driving beyond the communter capabilities of series hybrid vehicles. It was envisioned that since the gas engine would be able to independently propel t...
Radon-222 has been measured in natural gas produced from experimental geopressured-geothermal test wells. Comparison with published data suggests that while radon activity of this unconventional natural gas resource is higher than conventional gas produced in the gulf coast, it is within the range found for conventional gas produced throughout the US. A method of predicting the likely radon activity of this unconventional gas is described on the basis of the data presented, methane solubility, and known or assumed reservoir conditions of temperature, fluid pressure, and formation water salinity.
BackgroundEmphysematous cholecystitis is a variant of acute cholecystitis which is generally caused by gas-forming organisms. Emphysematous cholecystitis may cause gas spreading...Full Text Available
... Accession Number : ADD135818. Title : Performance of Titanium in Flue Gas Desulfurization Scrubber Systems,. Descriptive Note : Journal Article,. ...
The properties of the ideal gas of classical (nonquantum) tachyons are considered. Starting from the definition of thermodynamic functions for this system, it may be found that tachyons and bradyons gases are similar. (AA).
A new surveillance system for Oil-Filled cable, which can provide continuous monitoring, using a newly developed optical gas sensor that can detect the concentration of the gas dissolved in the oil with extremely high sensitivity has been developed. It was proved that the degree of deterioration of the insulating oil can be detected by measuring C{sub 2}H{sub 2} and CH{sub 4} by investigating the relation between the degree of deterioration and amount of combustible gas generated. In order to detect extremely small amounts of gas, a new gas detecting method using absorption line of the gas using a frequency modulated technique has been developed. The gas detection ability was also confirmed by examination using a 66 kV of cable and the possibility of detection at an early stage is expected.
Rapid technology improvements, resulting in high efficiency, emissions reduction and low generation cost, are making gas turbines the generation technology of choice despite some recent reliability problems. The basic reason for the dominance is high efficiency. The rapid pace of gas-turbine technology improvement in the 1990s drove combined-cycle thermal efficiency to nearly 60 percent with natural gas as the fuel. It will probably go even higher after the year 2000. In addition, the gas-fired combined cycle is a bargain. With natural gas prices where they are right now, it is the least-cost generation operation for power producers with access to gas. Many will replace older, high-cost power plants with new gas-fired combined cycle power plants.
The oxygen production of a photosynthetic gas exchanger containing Chlorella pyrenoidosa (1% packed cell volume) was measured when various concentrations of carbon dioxide were present...Full Text Available
The purpose of this publication is to provide a better understanding of flue gas desulfurization. It provides brief answers to questions concerning its applicability, cost, effectiveness, and operation.
This bibliography contains 3920 references including abstracts, to information on the technology of flue gas desulfurization and denitrification. These references and others are included in the Department of Energy's Energy Data Base (EDB) through Decembe...
Tests to measure the maximum horsepower of commercial vehicles converted for use with natural gas fuel indicate a reduction of approximately 20% in horsepower compared with gasoline-driven vehicles. This reduction in horsepower resulting from the use of gas is due basically to the lower thermal efficiency of the cycle of natural gas compared with that of gasoline and to its lower volumetric efficiency, since natural gas is injected into the combustion chamber in gaseous form, unlike gasoline, in which part of the fuel entering the cylinder is in the liquid phase. Natural gas used as a fuel generates lower quantities of air pollutants, particularly unburned hydrocarbons (HCs) and carbon monoxide (CO). Despite the downside of reduced horsepower, the use of natural gas as a fuel for automotive vehicles equipped with Otto-cycle engines is economically viable owing ...
The natural gas industry has proposed an increase in the DOE gas R&D budget from about $100 million to about $250 million per year for each of the next 10 years. The proposal includes four programs: natural gas supplies, fuel cells, natural gas vehicles and stationary combustion systems. This paper is a qualitative assessment of the gas industry proposal and recommends a natural gas R&D strategy for the DOE. The methodology is a conceptual framework based on an analysis of market failures and the energy policy objectives of the DOE`s (1991) National Energy Strategy. This framework would assist the DOE in constructing an R&D portfolio that achieves energy policy objectives. The natural gas supply program is recommended to the extent that it contributes to energy price stability. Stationary combustion programs are supported on ...
Prepared to make housing project managers, maintenance engineering staff, and designers and architects of HUD - assisted and HUD - insured housing projects and mobile home parks aware of their responsibilities under the Natural Gas Pipeline Safety Act, this handbook provides technical guidance for the reduction of gas leaks and the handling of gas leak incidents in residential areas. The hazards of natural gas, concern over gas safety in residential areas, applicable codes and standards, and sources of information and help are reviewed, along with maintenance and engineering considerations relating to gas pipe failures, the detection of gas leaks, appliance servicing, and pipe installation, repair, and replacement. Housing management considerations are also examined, with attention to recordkeeping and reporting, emergency contingency ...
Gas Supplies of Interstate Natural Gas Pipeline Companies 1987 was prepared by the Reserves and Natural Gas Division, Office of Oil and Gas, Energy Information Administration (EIA). The publication provides information on the total reserves, production, and deliverability capabilities of the 87 interstate pipeline companies required to file the Federal Energy Regulatory Commission (FERC) Form 15, ''Interstate Pipeline's Annual Report of Gas Supply.'' This publication is the 25th in a series of annual reports on the total gas supplies of interstate pipeline companies since the inception of individual company reports to the Federal Power Commission (FPC) in 1964 for report year 1963. This publication provides information on the interstate pipeline companies' supply of natural gas during ...
The corrosion behavior of 304 stainless steel was characterized with cyclic voltammetry in a eutectic Li/K and Li/Na carbonate melt under anode and cathode gas of the molten-carbonate fuel cell (MCFC). The corrosion rate of 304 steel was determined in four different environments of the MCFC with electrochemical methods and from cross-sectional analysis of corrosion layers. These four environments were open-circuit and MCFC-load conditions both under anode and cathode gas. At open-circuit conditions corrosion was more severe under the oxidizing cathode gas then under the reducing anode gas. On the contrary, at load conditions corrosion was more severe under anode than under cathode gas. The anodic polarization under anode gas enhances corrosion, whereas the high anodic polarization under cathode gas leads to anodic protection. Corrosion ...
Polymeric coated ferromagnetic carriers with an absorbed layer of octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) diluted by tributyl phosphate (TBP) are being evaluated for application in the separation and the recovery of low concentrations of americium, plutonium, and uranium from nuclear waste solutions. Due to their chemical nature, these extractants selectively complex americium and plutonium contaminants onto the particles and the complexed particles can be recovered from the solution using a magnet. Physical and chemical characterization of the extractant-absorbed particles were performed by gamma and liquid scintillation counting, scanning electron microscopic (SEM) micrograph, and other physical measurements. Plutonium, americium, and uranium separations have been performed at various HNO{sub 3} and HCl concentrations. Parameters were studied to determine the limitations and capacity of the process. The status of the chemistry and ...
Heat capacities and densities of aqueous MgCl/sub 2/, CaCl/sub 2/, and SrCl/sub 2/ from the accompanying paper are combined with literature data up to 473 K to yield temperature-dependent equations by using the ion-interaction model of Pitzer. These heat capacity equations have been integrated to yield the enthalpy and the Gibbs energy. The enthalpy parameters for 298 K are evaluated in separate calculations using published high-temperature osmotic data as well as heats of dilution, while the Gibbs energy parameters for 298 K are taken from the literature. The range of validity of the final equations is described.
The circulating cooling water flowrate of GNPS and LNPS is totally about 190 m"3/s. Both stations are located on the western coast of semi-closed Daya Bay. A lot of studies concerning thermal impact of GNPS and LNPS have been carried out since 1987, including mathematical model, physical model, on-site survey and satellite remote sensing, etc. This paper describes the hydrological features of Daya Bay and discharge characteristics of circulating water of GNPS and LNPS, estimates the actual thermal impact of GNPS and LNPS, and indicates that it is advantageous for the dilution of circulating water while the two discharge channels of GNPS and LNPS are combined together towards east
In order to produce a quality grout from LLW using hydraulic cements, proper conditioning of the waste is essential for complete cement curing. Several technologies were investigated as options for conditions. Since the LLW is dilute, removal of all, or most, of the water will significantly reduce the final waste volume. Neutralization of the LLW is also desirable since acidic liquids to not allow cement to cure properly. The nitrate compounds are very soluble and easily leached from solid waste forms; therefore, denitration is desirable. Thermal and chemical denitration technologies have the advantages of water removal, neutralization, and denitration. The inclusion of additives during thermal treatment were investigated as a method of forming insoluable waste conditions.
"2"0"3Pb, an ideal radionuclide for toxicological studies, can be artificially produced by bombardment of a thallium target but due to the extreme toxicity of thallium the lead has to be separated completely from the thallium. A single step method is here described consisting of removing the thallium from a dilute acid chloride solution using a continuous ethyl ether extraction. Essentially all of the thallium and almost none of the lead is removed in a 3-hr extraction. Because the ether is recycled, only about 30 ml are needed. If other contaminants are introduced from the bombardment and its subsequent manipulations, an additional step is used in which the lead is extracted from an iodide solution with methyl isopropyl keton. (U.K.).
The oxidation of n-butylbenzene was studied in a jet-stirred reactor (JSR) at 10atm in dilute conditions providing new experimental results over the low- and high-temperature range 550-1180K, and variable equivalence ratio (0.25ϕ1.5). They consisted of concentration profiles of the reactants, stable intermediates and final products, measured as a function of temperature, at a constant residence time of 1s, by sonic probe sampling followed by on-line GC-MS and off-line GC-TCD-FID and GC-MS analyses. The oxidation of n-butylbenzene in these conditions was modeled using a detailed chemical kinetic reaction mechanism (404 species and 2210 reactions, most of them reversible) deriving from a previous scheme proposed for the ignition, oxidation, and combustion of simple aromatics (benzene,...
A method, based on anion exchange chromatography, is presented for the isolation of "1"3"9Ce after production by a proton-induced nuclear reaction on a thick praseodymium target. After bombardment the target is dissolved in nitric acid and "1"3"9Ce oxidised to the Ce(IV) oxidation state with bromic acid. "1"3"9Ce is then separated form the praseodymium by anion exchange chromatography on a Ag MP-1 resin column in a nitric acid - bromic acid mixture. "1"3"9Ce is sorbed onto the resin column and praseodymium eluted with the acid mixture. The bromic acid is washed out of the column with nitric acid and "1"3"9Ce finally eluted with dilute nitric acid containing sulphur dioxide.
Abstract:- The demand for Lithium-ion batteries as a major power source in portable electronic devices and vehicles is rapidly increasing. I use cumulative data of vehicle, mobile phone, laptop, and digital camera production to show that demand will overshoot the available global Lithium resources before 2025. Even if 100% of all Lithium-ion batteries were recycled today, recycling could not prevent this resource depletion in time. As the increasing Lithium scarcity will increase the price, it will be feasible to mine diluted resources with a strong environmental impact. I highlight these impacts in Lithium-rich Bolivia, the potential new -Saudi Arabia of Lithium.- Lithium extraction is likely to cause substantial water pollution, and-through impacts on native diversity-facilitate human he...
The influence of 3d-transition metal impurities on the superconducting properties of the A-15 compounds V_3Si and V_3Ga have been investigated. In the case of V_3Si, the Fe impurities replacing V were found to have a local moment. A compensation effect was found in this case, resulting in a 20KOe increase in the upper critical field at dilute concentrations of Fe. It was demonstrated that long range order V_3Ga possessed higher transition temperature and upper critical field than found hitherto. Investigations on Nb_3Ge/sub 1-x/Ga/sub x/ films obtained by chemical vapor deposition has clearly shown the relation between the transition temperature and structural characteristics. The influence of generalized defects on the superconducting properties in A-15 type Nb_3X compounds has been discussed.
We have used polarised neutrons to measure the integrated magnetic cross-section of a dilute alloy of Ce in Y a Kondo system, T{sub K}{approx}40 K. Previous polarised neutron measurements of the field-induced magnetic form factor found no anomalies that could be attributed to the formation of a spin compensation cloud around the Ce ion. The present measurements, focused on the diffuse low-Q range, represent information over a very wide length scale in real space. Again, they show no changes in the Q-dependence of the form-factor at low temperatures that could be attributed to the formation of a spin compensation cloud. An alternative interpretation of the phenomenon based on the dynamical magnetic susceptibility of Y-Ce is proposed.
We have used polarised neutrons to measure the integrated magnetic cross-section of a dilute alloy of Ce in Y a Kondo system, T_K#approx#40 K. Previous polarised neutron measurements of the field-induced magnetic form factor found no anomalies that could be attributed to the formation of a spin compensation cloud around the Ce ion. The present measurements, focused on the diffuse low-Q range, represent information over a very wide length scale in real space. Again, they show no changes in the Q-dependence of the form-factor at low temperatures that could be attributed to the formation of a spin compensation cloud. An alternative interpretation of the phenomenon based on the dynamical magnetic susceptibility of Y-Ce is proposed.
Carbon steel is frequently used to construct concentrated sulphuric acid storage tanks. This paper discussed the corrosion performance of carbon steel tanks and outlined the underlying mechanisms responsible for major corrosion modes. Analyses of hydrogen grooving and dilute acid corrosion failure mechanisms were presented. Recent corrosion-induced leak failures were also discussed. The use of anodic protection and organic coatings as a corrosion control measure was also evaluated. The results of laboratory studies that were conducted to understand corrosion-induced failures showed that carbon steel electrodes exhibited transpassive corrosion at relatively high anodic potentials, while stainless steel electrodes exhibited transpassive corrosion at anodic potentials less than 1 V. It was concluded that corrosion-induced leaks can be prevented by using anodic protection and baked phenolic coating technologies. 23 refs., 9 figs.
Summary: The surface coverage of amorphous silica gels used in the synthesis of silica polyamine composites has been investigated by 29Si NMR. By diluting the polyamine anchor silane, chloropropyl trichlorosilane, with methyl trichlorosilane it was found that surface coverage could be markedly improved for a range of amine polymers after grafting to the silica surface. The commensurate decrease in the number of anchor points and increase in the number of free amines results in an increase in metal capacity and/or an improvement in capture kinetics. Solid state CPMAS-13C NMR has been employed to investigate the structure and metal ion binding of a series of these composite materials. It is reported that the highly branched polymer, poly(ethyleneimine) (PEI) exhibits much broader 13C NMR res...
This paper describes an experiment which has been performed with a somewhat different philosophy in its approach as compared to previous work. (a) The trigger threshold energy was increased by more than a factor of ten on previous experiments reducing the dilution effect of many lower energy showers known not to produce tachyons. 1673 shower were recorded. (b) The exposure time was made longer than previous experiments in order to obtain a reasonably large statistical sample at the higher threshold. Observations were made between February 1979 and June 1980, the total live time being 9768 hours. (c) Records of the detector output amplitude for the 480#mu#s lead time were integrated point by point as is sometimes done in radio astronomy, this gives the integrated energy deposition within the detector.
The random walk function is a mathematical function derived from studies of the mass transport and flow of diffusible materials through tubes. Approximations to the function were first used some time ago in the field of cardiac tracer dilution curves, but in the absence of rapid and reproducible curve fitting the method never became commonplace. The current study uses the latest curve-fitting techniques and shows how the method may be used with precision in the analysis of time-activity curves from dynamic oesophageal and blood flow studies. The physiological basis of the method is given and parameters obtained which relate to both the rate of flow and the local dispersion of the bolus.
The characteristic rich shifting of the maximum adiabatic flame temperature from the stoichiometric value for mixtures of hydrocarbon and air is demonstrated to be caused by product dissociation and hence reduced amount of heat release. Since the extent of dissociation is greater on the lean side as a result of the stoichiometry of dissociated products, the peaking occurs on the rich side. The specific heat per unit mass of the mixture is shown to increase monotonically with increasing fuel concentration, and as such tends to shift the peak toward the lean side. It is further shown that this is the cause for the lean shifting of the adiabatic flame temperature of oxidizer-enriched mixtures of N{sub m}H{sub n} and F{sub 2} and of NH{sub 3} and O{sub 2}, with various amounts of inert dilution, even though their maximum heat release still peaks on the rich side. (author)
"1"7"5Ta and "1"7"7Ta nuclei were oriented at low temperature as dilute impurities in Fe. The magnetic hyperfine splitting frequencies #nu#="+#mu#B sub(HF)/Ih"+ of the "1"7"5Ta and "1"7"7Ta ground states have been measured to be 320.45(11) and 317.552(55) MHz by using the technique of NMR-ON. Taking the known hyperfine field of "1"8"1Ta in Fe, the magneticmoments have been deduced: "+#mu#("1"7"5Ta, 7/2"+)"+=2.270(45) and "+#mu#("1"7"7Ta, 7/2"+)"+=2.250(45)#mu# sub(N). These values of the magnetic moments are discussed in the framework of the rotational model. (author).
The in-depth distribution of phases in c-BN films deposited by Ion Beam Assisted Deposition (IBAD) at two different ion energy values (300 and 600 eV) was investigated using the quantitative IR transmission measurements and the HREM technique. Whatever the value of the studied ion energies, the characteristic layered morphology of c-BN film is observed including the interfacial sp"2 zone between the substrate and the c-BN volume. In the case of 600 eV ion energy, this interfacial zone is less well-defined in comparison with 300 eV ion energy and the corresponding thickness is more important. Furthermore, the h-BN phase is more diluted within the c-BN film volume showing that the purest phase concentration of c-BN is found for the lowest ion energy, i.e., 300 eV.
The magnetic properties of diluted spinels Zn{sub 1-x}M{sub x}Fe{sub 2}O{sub 4} (M = Mg, Ni) systems have been studied by mean field theory, probability law and high-temperature series expansions method in the range 0 {<=} x {<=} 1. The exchange interactions are calculated by the first and second theory, respectively. The magnetic phase diagrams of Zn{sub 1-x}M{sub x}Fe{sub 2}O{sub 4} (M = Mg, Ni) are calculated by the high-temperature series expansions, combined with the Pade approximants method. The critical exponent associated with the magnetic susceptibility ({gamma}) is deduced.
We present the results of the low-temperature specific heat of Kondo compound Ce{sub 3-x}La{sub x}Pd{sub 20}Si{sub 6} (x=0, 1, 2 and 2.7) and its magnetic-field dependence for x=0. The magnetic part of specific heat divided by temperature, C{sub m}/T, for x=0 makes a peak as high as 9 J/mol Ce K{sup 2} at 0.2 K. On the other hand, C{sub m}/T for the other x`s keeps increasing monotonically below 0.2 K and the Fermi-liquid ground state is not realized even in diluted samples. It was found that the magnetic field strongly depresses C{sub m}/T at low temperatures. (orig.).
We present the results of the low-temperature specific heat of Kondo compound Ce_3_-_xLa_xPd_2_0Si_6 (x=0, 1, 2 and 2.7) and its magnetic-field dependence for x=0. The magnetic part of specific heat divided by temperature, C_m/T, for x=0 makes a peak as high as 9 J/mol Ce K"2 at 0.2 K. On the other hand, C_m/T for the other x's keeps increasing monotonically below 0.2 K and the Fermi-liquid ground state is not realized even in diluted samples. It was found that the magnetic field strongly depresses C_m/T at low temperatures. (orig.).
Numerical simulations are used to test the kinetic theory constitutive relations of inertial granular shear flow. These predictions are shown to be accurate in the dilute regime, where only binary collisions are relevant, but underestimate the measured value in the dense regime, where force networks of size $\\xi$ are present. The discrepancy in the dense regime is due to non-collisional forces that we measure directly in our simulations and arise from elastic deformations of the force networks. We model the non-collisional stress by summing over all paths that elastic waves travel through force networks. This results in an analytical theory that successfully predicts the stress tensor over the entire inertial regime without any adjustable parameters.
The determination of Li and proton-capture element abundances in globular cluster (GC) giants allows us to constrain several key questions on the multiple population scenarios in GCs, from formation and early evolution to pollution and dilution mechanisms. In this Letter, we present our results on Li abundances for a large sample of giants in the intermediate-metallicity GC NGC 6121 (M4), for which Na and O have been already determined by Marino et al. The stars analyzed are both below and above the red giant branch bump luminosity. We found that the first and second generation stars share the same Li content, suggesting that a Li production must have occurred. This provides strong observational evidence supporting the scenario in which asymptotic giant branch stars are GC polluters.
Extraction of hemicellulose from hardwood chips prior to pulping is a possible method for producing ethanol and acetic acid in an integrated forest bio-refinery, adding value to wood components normally relegated to boiler fuel. Hemicellulose was extracted from hardwood chips using green liquor, a pulping liquor intermediate consisting of aqueous NaOH, Na2CO3, and Na2S, at 160degreeC, held for 110min in a 20L rocking digester. The extracted liquor contained 3.7% solids and had a pH of 5.6. The organic content of the extracts was mainly xylo-oligosaccharides and acetic acid. Because it was dilute, the hemicellulose extract was concentrated by evaporation in a thin film evaporator. Concentrates from the evaporator reached levels of up to 10% solids. Inhibitors such as acetic acid and sodium ...
Some N-containing or S-containing organic substances and some acetylenic alcohols were tested as inhibitors of the corrosive attack suffered by Fe-based metallic glasses in deaerated 0.1 N sulfuric acid (H{sub 2}SO{sub 4}) solution at 25 C. It was verified that the specific action these compounds exerted on the corrosion process of the amorphous alloys was similar to the one these compounds exerted on polycrystalline iron. The most efficient substances were those containing a sulfur atom with available lone pairs, which chiefly inhibited the anodic reaction of both metal specimens. Owing to the chemical and physical homogeneity of the amorphous alloy, the chemisorbed inhibitor film that formed on the glassy surface was more stable and protective than that formed on the polycrystalline iron.
Hydrogen cyanide (HCN) production by Pseudomonas aeruginosa in a synthetic medium is stimulated by the presence of glycine. Methionine enhances this stimulation but will not substitute for glycine as a stimulator of cyanogenesis. Threonine and phenylalanine are effective substitutes for glycine in the stimulation of HCN production. Glycine, threonine, and serine are good radioisotope precursors of HCN, but methionine and phenylalanine are not. Cell extracts of P. aeruginosa convert (/sup 14/C)threonine to (/sup 14/C)glycine. H14CN is produced with low dilution of label from either (1-/sup 14/C)glycine or (2-/sup 14/C)glycine, indicating a randomization of label either in the primary or secondary metabolism of glycine. When whole cells were fed (1,2-/sup 14/C)glycine, cyanide and bicarbonate were the only radioactive extracellular products observed.
It is hypothesized that the good performance of Alloy 800 in steam generator service is due to its relative immunity to two distinct mechanisms of stress corrosion cracking; the argument also applies to intergranular corrosion. One mechanism operates in the high-nickel region (Alloy 600 and nearby model alloys) and is due to internal intergranular oxidation. The other operates in the low-nickel (stainless steel) region and is due to de-alloying of Fe and/or Cr. This latter mechanism may, under special conditions, operate in high-Ni, high-Cr alloys such as 690. Some essential features of the de-alloying mechanism are demonstrated using strong caustic solutions, and the prospect of extending this approach to dilute high-temperature environments is discussed. (author)
Roux-en-Y gastric bypass surgery (RYGB) remains to be the most effective long-term treatment for obesity and its associated comorbidities, but the specific mechanisms involved remain elusive. Because RYGB patients appear to no longer be preoccupied with thoughts about food and are satisfied with much smaller meals and calorically dilute foods, brain reward mechanisms could be involved. Just as obesity can produce maladaptive alterations in reward functions, reversal of obesity by RYGB could normalize these changes or even further reset the food reward system through changes in gut hormone secretion, aversive conditioning and/or secondary effects of weight loss. Future studies with longitudinal assessments of reward behaviors and their underlying neural circuits before and after surgery wil...
Contents The study aimed at testing the effectiveness of dimethylformamide, alone or combined with glycerol, as cryoprotectant for freezing ram semen. Ejaculates from nine rams were cryopreserved in Tris-based extenders, containing 5% of glycerol, association of dimethylformamide with glycerol, in four proportions achieving 5% of cryoprotectors in the media and pure dimethylformamide (2, 3, 4 and 5%) in replacement to glycerol. The samples were diluted to 100--106 sptz/ml and stored in 0.25-ml straws in liquid nitrogen. After thawing (37C for 30-s), motility was preserved better by the extender containing 5% of glycerol (p-<-0.05). The extenders containing pure dimethylformamide, or more than 2% in combination with glycerol, provided sperm motilities close to zero. Plasma and acrosomal mem...
Differential Scanning Calorimetry (DSC) is employed to study the changes in enthalpy of natural rubber latex samples when heated under a controlled temperature program. It is found that the mass normalized areas of the DSC curves between room temperature and 170??C for different latex samples are inversely proportional to the dry rubber content (DRC) of the samples, measured following the weighing and drying method. The changes in total enthalpy of the samples in this temperature range are interpreted as due to the variations in the quantity of water present in the samples. The measurements have been repeated by diluting selected samples with known quantities of water, and it is found that the normalized areas of the DSC curves are directly proportional to the amount of water added to the ...
This environmental assessment quantifies the water quality-related benefits for Transportation Equipment Cleaning (TEC) facilities based on site-specific analyses of current conditions and the conditions that would be achieved by process changes under proposed BAT (Best Available Technology) and PSES (Pretreatment Standards for Existing Sources) controls. The US Environmental Protection Agency (EPA) estimated instream pollutant concentrations for 157 priority and nonconventional pollutants from three subcategories (barge-chemical and petroleum, rail-chemical, and truck-chemical) of direct and indirect discharges using stream dilution modeling. The potential impacts and benefits to aquatic life are projected by comparing the modeled instream pollutant concentrations to published EPA aquatic life criteria guidance or to toxic effect levels.
A new technique has been developed for the measurement of steam mass flowrate, water mass flowrate and total enthalpy of two-phase fluids produced from geothermal wells. The method involves precisely metered injection of liquid and vapor phase tracers into the two-phase production pipeline and concurrent sampling of each phase downstream of the injection point. Subsequent chemical analysis of the steam and water samples for tracer content enables the calculation of mass flowrate for each phase given the known mass injection rates of tracer. This technique has now been used extensively at the Coso geothermal project, owned and operated by California Energy Company. Initial validation of the method was performed at the Roosevelt Hot Springs geothermal project on wells producing to individual production separators equipped with orificeplate flowmeters for each phase.
By ab-initio calculation we show that the (Ga,Fe)N ground state may be changed from anti-ferromagnetic to ferromagnetic by acceptor defect like Ga vacancies. The electronic structures are calculated by using the Korringa-Kohn-Rostoker (KKR) method combined with coherent potential approximation (CPA). We show that we can increase the magnetic moment of Fe in p-type GaN by oxygen co-doping. Mechanism of exchange interactions between magnetic ions in p-type (Ga,Fe)N is also studied. The effect of external magnetic field on the electronic structure of (Ga, Fe)N and p-type (Ga, Fe)N is investigated.
Phenytoin (PHT), phenobarbital (PHB), lamotrigine (LTG), and topiramate (TPM) are some of the most widely used antiepileptic drugs (AEDs). Monitoring of their concentrations in serum is important for the treatment of epilepsy. A reference measurement procedure (RMP) for certification of PHT, PHB, LTG, and TPM in serum has been developed and critically evaluated. Isotopically labeled compounds of PHT, PHB, LTG, and TPM are used as internal standards for the four AEDs. The four drugs and their respective labeled internal standards are simultaneously extracted from serum using solid-phase extraction prior to reversed-phase liquid chromatography?tandem mass spectrometry (LC-MS/MS). Chromatographic separation was performed using a C18 column. Electrospray ionization (ESI) in the positive ion mo...
The experimental densities, {rho} for binary mixtures of (N-acetylmorpholine + benzene, +toluene, +ethylbenzene, and +mesitylene) have been measured at temperatures from (293.15 to 343.15) K and atmospheric pressure over the whole mole fraction range. From these results, excess molar volumes V{sup E} have been calculated and fitted to the Redlich-Kister polynomial equation. The V{sup E} values are negative over the whole mole fraction range and at all temperatures. Thermal expansion coefficients {alpha}{sub i}, apparent molar volumes V{phi}{sub i}, and partial molar volumes at infinite dilution V{sub i}{sup {infinity}} have been calculated. The variation of these properties with composition and temperature of the binary mixtures are discussed in terms of molecular interactions.
Using indigenously developed computer program, coupled neutron gamma multi-group libraries have been generated from MA TXS-NJOY files. The MATXS format contains all the details for each reaction. Temperature and dilution factor dependent cross-sections have been generated and used in discrete ordinates method for benchmark studies of fast critical experiments. We have analyzed criticality benchmarks, which includes CSEWG fast critical benchmarks, "2"3"3U and Pu spheres and enriched uranium spheres using 30-group neutron cross-sections. Neutron and gamma spectra for spheres with point neutron source at the center, are also calculated with 42-group coupled neutron gamma cross-sections. (author)
Under operational conditions in nuclear power plants, the carbon steel components of the primary and secondary circuits react with high temperature cooling agent forming several iron oxides and oxyhydroxides. These deposits can result in tubes' constrictions, pitting and intergranular corrosion and finally to heat transfer reducing and increasing of radiation fields around the circuits, as well. The descaling process involves the chemical dissolution of the corrosion deposits by means of diluted organic acidic solutions containing usually a carboxylic acid, a reductant and one or more corrosion inhibitors. To evaluate the removing rates of these superficial films two types of methods were used, the gravimetric and potentiodynamic techniques. By correlating the experimental results, we established the chemical composition of descaling solution and two models of mechanisms applicable to our specific conditions. (authors)
An oxidative method for enriching the content of humic acids in a mined lignite from Umbria (central Italy) is described. A mild oxidation using H{sub 2}O{sub 2} in an alkaline medium was successful in increasing the percentage of lignite-derived humidifed carbon from 5.77% to 33.67%. The newly formed humic acids showed a higher number of oxygen-bearing functional groups, a lower carbon/oxygen ratio and a higher absorbance ratio at 465 and 665 nm (E{sub 4}/E{sub 6}) in diluted solution compared to the native lignite-derived humic acids. A high E{sub 4}/E{sub 6} ratio indicated less condensation of the aromatic nucleus and a lower molecular weight in comparison to the lignite-derived native humic acids.
Oxidative degradation of methylene blue (MB) by Co^2^+-HCO3^- system with H2O2 in aqueous solution was studied. Nearly complete decolorization of the dye was obtained in less than 50min in diluted NaHCO3 solution (25mM) in the presence of only 20mM Co^2^+ ions. Meanwhile, the conjugated structure and phenyl rings of the MB molecule were destroyed or even broken down into small organic acids and inorganic ions, as indicated by FT-IR spectra and ion-chromatography. Photoluminescence probing and radical scavenging technologies suggested that the reaction of MB degradation in this system mainly involved the generation and participation of hydroxyl radicals. Furthermore, by cyclovoltammetric measurements, the in situ formed different complexes between Co^2^+ and HCO3^- were observed at differen...
There have been a number of studies considering the possibility of removing and recovering heavy metals from diluted solutions. These are due, principally, because of the commercial value of some metals as well as in the environmental impact caused by them. The traditional methods for removing have several disadvantages when metals are present in concentrations lower than 100 mg/l. Biosorption, which uses biological materials as adsorbents, has been considered as an alternative method. In this work, variables like pH and biomass chemical pretreatment have been studied for its effect on the capacity for zinc biosorption by Thiobacillus ferrooxidans. Also, studies to determinate the time for zinc adsorption were carried out. Results indicate that a capacity as high as 82.61 mg of Zn(II)/g of dry biomass can be obtained at a temperature of 25 C and that the biosorption process occurs in a time of 30 min. (orig.)
The potential of the yeast Candida tropicalis and Candida guillermondii was evaluated and an isolated partnership of microorganisms of waters of the Medellin River, conformed by two bacteria and one leavening, to degrade the content of organic matter present in wine produced by the factory of Licores and Alcoholes de Antioquia (FLA) in aerobic process with biomass production. For each one of the microorganisms in study this capacity of removal in units of chemical demand of oxygen was quantified (CDO); in addition, parameters were analyzed such as yield of the biomass in relation to the removed CDO and to total reducing sugars (TRS) consumed, time of fermentation and speed of growth different dilutions from wine. Also the possible inhibition was analyzed that the present phenolic compounds in this wine can cause in the biological process of degradation.
Forty-seven subtraction images of FCR were compared with subtraction images of conventional angiography of the head. Quality of the FCR images were equal or superior to that of conventional angiography. Antero-posterior projection of external carotid arteriography by FCR was most useful because of its wide dynamic range. As contrast resolution of FCR is superior to that of conventional angiography, only half diluted contrast media was needed. As for spacial resolution, FCR is slightly inferior to conventional angiography. However, most vessels which are clinically important were adequately demonstrated. A weak point of FCR which should be improved is relatively long time to process the images after radiation exposure. (author).
The power?time curves of mice splenic lymphocytes growth at 37??C affected by ginsenoside Rh2 were determined by microcalorimetry using a 3114/3236 TAM air bioactivity monitor with ampoule mode. Then, the minimal inhibitory concentration (MIC) of Rh2 on splenic lymphocytes growth was determined by serial dilution method. From factor analysis (FA) on six quantitative thermokinetic parameters from the power?time curves, the activity of Rh2 on splenic lymphocytes could be quickly evaluated by analyzing the changes in the two main parameters: growth rate constant k, and maximum heat-output power, P m. The results showed that Rh2 had strong inhibitory activity on splenic lymphocytes growth, and this inhibitory activity was strengthened with increasing concentration of Rh2 in the concentration r...
Disodium phenyldibenzimidazole tetrasulfonate (PDT) is a new organic UV filter with hydrophilic properties used in modern sunscreen spray formulations. The aim of this work was to develop and validate an analytical method that can be used to study skin absorption of PDT from sunscreens. Results obtained in vitro for human skin showed a low level of absorption. The proposed in vitro method employs a diffusion cell. Sunscreen lotion was applied onto pretreated human skin, which was then placed in the cell. PDT was collected in a receptor liquid, the surface of which was in contact with the skin. The solutions obtained were diluted appropriately and analyzed by liquid chromatography without any interference. The analytical features of chromatographic determination with fluorimetic detection w...
In the CLIC main linac it is very important to minimise the trajectory excursion and consequently the emittance dilution in order to obtain the required luminosity. Several algorithms have been proposed and lately the ballistic method has proved to be very effective. The trajectory method described in this Note retains the main advantages of the latter while adding some interesting features. It is based on the separation of the unknown variables like the quadrupole misalignments, the offset and slope of the injection straight line and the misalignments of the beam position monitors (BPM). This is achieved by referring the trajectory relatively to the injection line and not to the average pre-alignment line and by using two trajectories each corresponding to slightly different quadrupole strengths. A reference straight line is then derived onto which the beam is bent by a kick obtained by moving the first quadrupole. The other quadrupoles are then aligned on that ...
Full text: Chemical-technology approaches allowing to intensification the prevention processes of gas hydrates formation at motion of gas-liquid stream of natural gas in system natural gas well - gas wire have been worked up. Technological regimes of treatment of gas stream have been determined. Linear correlation dependences inhibitor electrolytes contained hydrated ions with different ion radii and charges of subgroups of alkali elements with one - type electron configuration were obtained. Important physico-chemical parameters of electrolytes have been determined: activity; coefficients of activity, viscosity, diffusion; density; heat capacity; heat conductivity; surface tension and freezing-point. The features of continuous influence of inhibitory factors on process of gas flow at low temperatures and relatively high pressure differences ...
The passive continental margin in the northern South China Sea is a weakly active area. It has been found to be favorable for large gas field development and also to be profitable for gas hydrate. The active faults, diapir structure, slump deposits, faults break of slopes, gas chimneys and sandstone of submarine fan, control the concentration of gas hydrate. Gas chimneys are widely distributed in the northern South China Sea. They supply the pathway for migration of deeper gas to gas hydrate stability zones especially in the basin of tectonic inactive zone. This paper discussed the geological structures of gas hydrate occurrence in gas fields and presented a detailed analysis of gas chimneys within the northern slope of the South China Sea. The paper described the geological ...
The paper deals with a model in which the motion of a gas in plasma accerators and high-curent discharges in the present of a skin effect is treated as expulsion by a 'magnetic piston' under the action of surface current flow. Specifically examined is the situation where the initial gas pressure is negligible in comparison with the magnetic pressure, and the motion of the gas may be treated as a self-simulating one. A system of hydrodynamic equations of the problem is derived and integrated by Adam's method. Results are plotted and discussed.
Gas contaminated with at least one noxious component, such as SO/sub 2/, HF or NOx, is scrubbed with a clear, calcium-containing, initially-basic washing liquid which also comprises the anion of a strong inorganic acid, that of a polybasic carboxylic acid and, optionally, that of a monobasic carboxylic acid. Apparatus is provided for scrubbing the gas, oxidizing produced calcium bisulfite to calcium sulfate, separating out and removing solids, and recirculating clarified liquid for scrubbing contaminated gas.
The Rayleigh scattering length has been calculated for rare-gas liquids in the ultraviolet for the frequencies at which they luminesce. The calculations are based on the measured dielectric constants in the gas phase, except in the case of xenon for which measurements are available in the liquid. The scattering length mayplace constraints on the design of some large-scale detectors, using uv luminescence, being proposed to observe solar neutrinos and dark matter. Rayleigh scattering in mixtures of rare-gas mixtures is also discussed.
The fission gas xenon bonded in bubbles, in pore, and in the lattice of mixed carbide fuels is measured by electron-probe microanalysis. Radial xenon distribution and release curves are determined and are calibrated by gas chromatography of the bonded fission gas and by burnup analysis in the respective pin sections of the irradiation experiments FR2 6A and 6C, Mol 11/K 2, and DFR 330/1. The results are correlated to the microstructure of the fuel, bonding medium, temperature, and burnup. (Auth.).
Analysis of the coke gas combustion porcess is presented. Standard kinetic relationships were utilized. Calculations were performed for coke gas with high and low content of H/sub 2/ and for blasting air 20 and 100/sup 0/C. Temperature relationships, composition of gas combustion products and release of nitrogen oxides were determined. Results are analyzed which will make it possible to control the composition of combustion products.
This thesis dealt with the metal-organic gas phase epitaxy with nitrogen as carrier gas. For this first by means of three-dimensional modelings of the epitaxy process the influence of the carrier gas on the processes was explained. The optimization of the growth parameter for the whole light-emitting-diode structure in double-hetero arrangement resulted that an a temperature of 770 C and a V/ III-ratio of 150 layers with a high crystal quality could be reached.
Plasma with a gas temperature below room temperature is not yet fully understood although it is expected to be an attractive tool for applications to material processing. In the present work, gas-temperature-dependent generation of a cryoplasma jet was studied. So far, we have generated a helium cryoplasma jet (296-5 K) under atmospheric pressure. At gas temperatures below 20 K, the helium excimer, He2, was observed clearly from by optical emission spectroscopy.
The gas composition of recent thermal waters is in perfect conformity with their geologic-tectonic positions. The composition of gas-liquid inclusions in the basic-hyperbasic xenoliths of basaltoid lavas depends on the depth from which xenoliths are supplied. (The depth is determined by using the methods of geological thermobarometers). By comparing available data the conclusion was drawn that the gas compositions of thermal waters reflect the depth of generation of deep fluid which heats them and depends on the penetration depth of the fluid-conducting fissure zones.
Spark ignition internal combustion engines perform satisfactorily when the fueled with biomass producer gas from a fluidized bed gasifier. Although power output is reduced compared to natural gas levels, full power recovery can be achieved with a relatively low level of supercharging. Important considerations are an adequate fuel delivery system and adquate gas cleaning. ref.
... harassment, incidental to construction and operation of an offshore liquefied natural gas (LNG) facility. Under the Marine Mammal Protection ... ...
The primary objective of this study is to assess the oil and gas potential of the West Siberian Basin of Russia. The study does not analyze the costs or technology necessary to achieve the estimates of the ultimate recoverable oil and gas. This study uses reservoir data to estimate recoverable oil and gas quantities which were aggregated to the field level. Field totals were summed to a basin total for discovered fields. An estimate of undiscovered oil and gas, from work of the US Geological Survey (USGS), was added to give a total basin resource volume. Recent production decline points out Russia`s need to continue development of its discovered recoverable oil and gas. Continued exploration is required to discover additional oil and gas that remains undiscovered in the basin.
Details of a 1 day conference designed to create more efficient interactions between the gas supply and electricity systems in Ontario and new models for gas supply and the electricity system were presented. Market efficiency, generators' perspectives on critical gas issues, an overview of the North American gas and an outline of issues concerning Ontario were discussed. A natural gas industry forecast and issues concerning marketers and producers were presented. The terms on which gas is bought and sold were discussed. Regulatory tools, cost allocation and issues relating to unbundling were also presented. Infrastructure needs were reviewed, as well as basic market structures. It was suggested that appropriate commercial service options need to be developed and approved, including cross-utility services.
The Department of Energy has proposed a rulemaking process to set minimum standards for the efficiency of gas ranges under the National Appliance Energy Conservation Act (NAECA). The Gas Research Institute is compiling information on annual household range gas usage in order to prepare a response to the proposed rulemaking. The data base from the Northern Illinois Gas residential load study provides recent information (data taken from 1990 through 1992) over a comprehensive study of household types and appliance and user characteristics (150 variables noted for each household). The stated Objective is to study the Northern Illinois Gas residential load study data base and to evaluate its effectiveness in predicting annual household gas usage.
Research was performed to assess the feasibility of barrier membrane substances, for use within mining or associated high risk environments, in restricting the diffusion transport of radon gas quantities. Specific tests were conducted to determine permeability parameters of a variety of membrane materials with reference to radon flow capabilities. Tests were conducted both within laboratory and in-situ emanation environments where concentrations and diffusion flows of radon gas were known to exist. Equilibrium radon gas concentrations were monitored in initially radon-free chambers adjacent to gas sources, but separated by specified membrane substances. Membrane barrier effectiveness was demonstrated to result in reduced emanation concentrations of radon gas within the sampling chamber atmosphere. Minimum gas concentrations were evidenced where the barrier ...
The light gain due to S/sub 2/ molecules in a supersonically cooled gas mixture is calculated. The S/sub 2/ molecules formed due to the recombination of the sulfur atoms, and the combustion gas mixture was preheated in a precombustion chamber. Optimal gas flow and nozzle parameters are found which correspond to the highest possible light gain using Cs/sub 2/-Ar and S/sub 2/-Ar gas mixtures. The steady state gas flow in the nozzle was calculated, taking into account the chemical reactions in the one-dimensional approximation. It is shown that the maximum gain values vary in the 0.0001-0.002 range for gas pressures in the precombustion chamber in the range 10-100 atm. The optimal initial relative concentration of Cs/sub 2/ molecules and S/sub 2/ molecules are given. 32 references.
The use of natural gas in China is still relatively immature, as gas production only supplies a low percentage of the domestic energy system. In contrast, Chinese economy mainly relies on coal with a 67% share of the total primary energy supply. The environmental impact from this high coal dependence is significant and planners have sought for cleaner energy sources. Natural gas is both cleaner and generally more efficient than coal and gas consumption is rising quickly due to these facts. The growth tendency indicates that natural gas will become an important substitution for coal in some parts of the Chinese primary energy consumption. To quantify this tendency, this paper uses a system dynamics model to create a possible outlook. The results show that the gas consumption in China will c...
Biomass gasification provides the potential to efficiently and economically produce a renewable source of a clean gaseous fuel suitable for power generation or synthesis gas (syngas) applications. An important side benefit of the use of biomass is the effective minimization of the primary greenhouse gas, carbon dioxide (CO{sub 2}), by providing a means to close-loop the CO{sub 2} cycle. However, high molecular weight hydrocarbon constituents (tar) in the product gas from gasification can complicate the downstream uses of the gas. This paper discusses both the development of a low cost, disposable catalyst system that can eliminate these heavy hydrocarbons from the gas and the use of the catalyst in conjunction with the Battelle high-throughput gasification process for power generation and synthesis applications. (author)
The presence of an extraneous light gas must be taken into account in consideration of centrifugal separation of uranium isotopes, when there is inevitable leakage of such a gas through the gas sealant and/or leaking in from the atmosphere. Consideration is first given to the influence of the presence of the light gas on the maximum separative power. Then the basic equation for isotope separation containing a light gas is derived from Hirschfelder's diffusion equations. This equation is solved and the separative performance is expressed in terms of the shape factor and reflux parameter. The formulas for expressing the flow configurations of the gases are obtained for a simple model in which inflow and outflow prevail throughout the centrifuge. The corresponding equation for a model in which the gases flow in two concentric thin streams is also derived. It is concluded that the ...
A patent is claimed for a process by which a low-hydrogen gas containing at least 90 percent by volume of methane which is suited for natural gas substitution is produced by transformation of vaporizable hydrocarbons with the aid of steam in the presence of a catalyst containing nickel, at temperatures of 350 to 600/sup 0/C and at increased pressure. Hydrocarbons and steam are supplied to the reaction in mixed form with recycle product gas. Per kilogramme of hydrocarbons to be converted in the high btu gas reactor, less than 1 kilogramme of fresh steam is needed. High btu gas is fed back from the high btu gas reactor to the input end of the same via a gas cycle comprising a cooler, a carbon dioxide absorption device, and a saturator. Between the carbon dioxide absorption device and the saturator a product gas is branched ...
The performance of the gas-jet transport system coupled to the RIKEN gas-filled recoil ion separator GARIS was investigated using 255No produced in the 238U(22Ne, 5n)255No reaction. Alpha particles of 255No separated with GARIS and transported by the gas-jet system were measured with a rotating wheel apparatus for ? spectrometry under low background condition. The high gas-jet efficiencies of about 75% were independent of the recoil ranges of 255No in the gas-jet chamber. The present results suggest that the GARIS/gas-jet system is a promising tool for the next-generation superheavy element chemistry: (1) the background radioactivities of unwanted reaction products are strongly suppressed, (2) the intense beam is absent in the gas-jet chamber and hence the high gas-jet efficiency is achieved, and (3) the beam-free ...
The purpose of this study is to identify the radiative heat transfer augmentation by a coaxial cylinder introduced in the infinite cylindrical pipe enclosing a participating gas. The gas is either a mixture of water vapor and carbon dioxide or gray. The gas is assumed to be homogeneous at a constant temperature, and has a refractive index of unity. All of the surfaces are opaque and gray, diffusely emitting and reflecting at a constant temperature. The effect of system diameter, diameter ratio, wall emittances, gas and surface temperatures, mixture component on heat transfer augmentation are studied by using the zone method with participating gas radiative properties evaluated from the weighted sum of gray gases model. From the radiative equilibrium condition, the installed wall temperature is formulated and calculated by the iteration method. If the medium is a gray ...
Visible smoke of exhaust gas from iron ore sintering plants spoil the scenery around the works. In this paper, the mechanism of formation of visible smoke is discussed by detailed analysis of the exhaust gas components and dust in the Oita No. 1 sintering plant. The main substance of visible smoke was mist condensing in the air during the cooling of exhaust gas that contained 0.1 ppm of sulfuric acid. Sulfuric acid is considered to raise the dew point and so facilitate mist condensation, and to lower the vaporization of visible mist containing sulfuric acid solution. Dust in the exhaust gas is also considered to act as nucleation sites for mist condensation. This proposed mechanism was confirmed by the test remixing SOx-rich gas with desulfurization gas in the Nagoya No. 3 sintering plant. Long trails of visible smoke were observed by remixing SOx-rich ...
Pressurized fluidized bed combustion (PFBC) is an emerging coal-fired, combined-cycle power generation technology nearing commercial status through several operating and planned demonstration plants throughout the world. Current-generation PFBC plants use ``ruggedized`` gas turbines that can tolerate dust loading common with conventional cyclone gas cleaning. The next generation of PFBC will apply advanced hot gas cleaning systems that will reuse the dust loading to low levels acceptable to high performance, industrial gas turbines. These advances should result in performance and cost advantages. This article examines the demonstration of PFBC technology at Tidd power station.
Sigma 1) examines ways to reduce the number of breakdowns of pressure-regulating stations and to minimize the energy consumed in warming the gas, 2) determines the optimal gas temperatures upstream from the pressure reduction, and 3) shows the dependence of energy consumption upon the water dewpoint. The method of calculating the optimal input temperature relies on Mollier's diagram. Tables and nomographs for natural gas and water dewpoint at 19/sup 0/F and 580 psi (-7/sup 0/C and 4 MPa) are useful in achieving the desired gas temperatures. Heating the regulators' control valves is important.
A study was conducted to examine the energy consumption in existing and new hog farming facilities and to analyse the potential for increased natural gas use in the Saskatchewan hog industry. Existing heating/cooling, ventilation and feed mill equipment choices offer possibilities for running on electricity, natural gas or propane. Energy costs are lowest when natural gas is used. To put the study in context, an overview of the Saskatchewan hog industry was provided. The potential increase in natural gas use in hog production by year 2005 was estimated. 10 refs., 6 tabs., 8 figs.
Increased use of natural gas has positive effects for the environment and the climate, because it primarily replaces petroleum products. Moreover, the natural gas does not pose a threat to bio fuel in Norway. But introducing CO2 taxes on natural gas will significantly increase the emission of greenhouse gases, concludes a report conducted by Norsk Energi (Norwegian Energy) on behalf of Norsk Naturgassforening (Norwegian Natural Gas Association) and Norsk Gassforum (Norwegian Gasforum). A brief presentation of the main conclusions in the report (ml)
National Power is building its first gas turbine combined cycle power station at Killingholme, situated to the south of the River Humber in the East of England. NEI ABB Gas Turbines Limited was awarded the turnkey contract in July 1990 to build a nominal 650 MW combined cycle power station based around three Asea Brown Boveri GT13E gas turbines. The project is outlined in this article. The plant is due for completion in July 1993. (author)
This article outlines the use of gasifiers during World War II and how, with soaring fuel prices, producer gas may provide an alternate energy path for agribusiness and farms today. In the last few years, the University of California has become a focus of producer gas research in the US. Biomass fuels used include crushed walnut shells, fruit pits, cereal straw and corn cobs. Particle size, moisture content and slagging create problems and the right kind of gas producer must be used to obtain reliable conversion to producer gas.
The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through February 1999.
The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through September 1999.
The waste tail gas fuel emitted from refinery plant in Taiwan e.g. catalytic reforming unit, catalytic cracking unit and residue desulfurization unit, was recovered and reused as a replacement fuel. In this study, it was slowly added to the fuel stream of a heater furnace to replace natural gas for powering a full-scale distillation process. The waste tail gas fuel contained on average 60 mol% of hydrogen. On-site experimental results show that both the flame length and orange-yellowish brightness decrease with increasing proportion of waste gas fuel in the original natural gas fuel. Moreover, the adiabatic flame temperature increases as the content of waste gas fuel is increased in the fuel mixture since waste gas fuel has a higher adiabatic flame temperature than that of natural gas. The complete replacement of natural ...
This paper provided an outline of the Canadian natural gas commodity market and a forecast for Canadian natural gas supply and prices for the 2007 winter heating season. Since 2001, steady demand growth and slow supply growth have contributed to higher North American natural gas commodity prices. The loss of natural gas supply due to hurricanes pushed North American natural gas commodity prices to record levels in 2005. Canadian natural gas production levels currently exceed domestic gas consumption. In 2005, Canada produced 16.5 billion cubic feet per day of marketable natural gas. Approximately 45 per cent was consumed domestically, and the remainder was exported to the United States. Despite high levels of drilling activity, production of natural gas from western Canada has flattened out since ...
Relative densities and relative massic heat capacities have been measured for aqueous solutions of Y(ClO_4)_3, Yb(ClO_4)_3, Dy(ClO_4)_3, and Sm(ClO_4)_3 at T=(288.15,298.15,313.15, and 328.15) K and p=0.1 MPa. These measurements were made in the concentration range 0.01624#<=#m/(mol#centre dot#kg"-"1)#<=#0.41822 using a Sodev 02D Vibrating Tube Densimeter and a Picker Microflow Calorimeter, respectively. To counter the potential effects of hydrolysis, aqueous solutions of the investigated salts were acidified with perchloric acid. After correcting for the presence of the acid, the measured properties were used to calculate apparent molar volumes and apparent molar heat capacities for solutions of the perchlorate salts in water. The calculated apparent molar properties were modeled at each investigated temperature using Pitzer ion interaction equations to produce estimates of apparent molar volumes and heat capacities at infinite dilution. In addition, the ...
The extraction and recovery of cesium from simulated Purex waste solutions was successfully demonstrated in the pilot plant pulse column. Stable volumetric capacities as high as 670 gph/ft/sup 2/ (sum of both phases) were obtained for alkaline supernate-type waste; however, for efficient operation (transfer unit height - HTU -of two feet or less), the maximum throughput rate was limited to about 500 gph/ft/sup 2/. This rate could be achieved with feeds diluted to densities within 0.08 g/cc of the solvent density. Stable feed was prepared from simulated current, denitrated waste by addition of citric acid to complex the iron before neutralization to the desired operating pH of 7 to 8. Capacities of 500 gph/ft/sup 2/ were readily achieved with this feed, together with HTU's of 1.0 to 1.3 feet. Sodium extracted with the cesium was satisfactorily scrubbed from the solvent with a dilute citric acid solution. ...
A systematic study for the materials design of III-V and II-VI compound-based ferromagnetic diluted magnetic semiconductors is given based on ab initio calculations within the local spin density approximation. The electronic structures of 3d-transition-metal-atom-doped GaN and Mn-doped InN, InP, InAs, InSb, GaN, GaP, GaAs, GaSb, AlN, AlP, AlAs and AlSb were calculated by the Korringa-Kohn-Rostoker method combined with the coherent potential approximation. It is found that the ferromagnetic ground states are readily achievable in V-, Cr- or Mn-doped GaN without any additional carrier doping treatments, and that InN is the most promising candidate for high-T_C ferromagnet. A simple explanation of the systematic behavior of the magnetic states in III-V and II-VI compound-based diluted magnetic semiconductors is also given. It is also shown that V or Cr-doped ZnS, ZnSe, and ZnTe are ferromagnetic without p- or n-type doping treatment. However, Mn-, ...
The distribution of carrier free lead-203 between plasma and cells of canine blood in vitro was measured. Activity in the plasma decreased to less than 5% of the initial blood activity during the first 15 min and then exponentially with a half time of 160 min. Incubation in cell free plasma before addition to whole blood transformed the isotope, decreasing the amount subsequently associated with cells. In animal studies, activity was measured in plasma, blood cells, urine, and feces after exposure to lead-203. In one group, the animals were exposed by intravenous injection of dilute citric acid solutions of isotope. In a second group, carrier free isotope which had been transformed by incubation in plasma was injected intravenously. The kinetics of the distribution of the isotope differed between the two experimental groups. After injection of the transformed lead, the lead-203 content of the blood cell fraction rose from 10% of the dose at 5 min to 21% to 43% at ...
The molar heat capacities of chloroform, dichloromethane, methanol, acetonitrile, acetone, dimethyl sulfoxide, benzene, dimethylformamide, toluene, and cyclohexane, as well as their deuterated isotopologues, were measured using a multi-channel heat conduction TAM (Thermal Activity Monitor) III microcalorimeter. In addition, the apparent molar heat capacities of some of the associated dilute aqueous solutions (0.0039 i < 0.0210) were also measured. A temperature drop method from (298.15 to 297.15) K at 0.1 MPa was employed. The corresponding heat capacities were determined from the integration of the measured heat flow. The heat capacity results are shown to be in good to very good agreement with the available literature values. In addition, good correlations were obtained for the effect of isotopic substitution on both molar heat capacity and apparent molar heat capacity in aqueous solutions. These correlations should be useful in the prediction of the molar ...
This study aimed to correlate the efficiency of enzymatic hydrolysis of the cellulose contained in a sugarcane bagasse sample pretreated with dilute H(2)SO(4) with the levels of independent variables such as initial content of solids and loadings of enzymes and surfactant (Tween 20), for two cellulolytic commercial preparations. The preparations, designated cellulase I and cellulase II, were characterized regarding the activities of total cellulases, endoglucanase, cellobiohydrolase, cellobiase, ?-glucosidase, xylanase, and phenoloxidases (laccase, manganese and lignin peroxidases), as well as protein contents. Both extracts showed complete cellulolytic complexes and considerable activities of xylanases, without activities of phenoloxidases. For the enzymatic hydrolyses, two 2(3) central composite full factorial designs were employed to evaluate the effects caused by the initial content of solids (1.19-4.81%, w/w) and loadings of enzymes (1.9-38.1 FPU/g bagasse) ...
CT of the gastrointestinal tract is commonly performed after administration of a high-density diluted iodinated oral contrast material. However, because if inadequate mixing of the contrast material with the gastrointestinal contents, pseudotumor and poor mucosal visualization are frequently shown on abdominal CT. To overcome these problem, 10% corn oil emulsion (COE) is tested as an alternative oral contrast agent in 40 patients. We analyse patients tolerance, gastric mucosal visualization and discrimination of pancreas from the duodenal C-loop to 10% COE in 40 patients compared with those obtained from 35 patients, who was received high-density diluted iodinated oral contrast agent (gastrografin). The results are as follows : 1. Patients' tolerance to 10% COE is similar to that to conventional oral contrast agent. 2. Image of the gastric mucosa from patients receiving 10% COE is superior to that receiving oral contrast agent. 3. The ...
CT of the gastrointestinal tract is commonly performed after administration of a high-density diluted iodinated oral contrast material. However, because if inadequate mixing of the contrast material with the gastrointestinal contents, pseudotumor and poor mucosal visualization are frequently shown on abdominal CT. To overcome these problem, 10% corn oil emulsion (COE) is tested as an alternative oral contrast agent in 40 patients. We analyse patients tolerance, gastric mucosal visualization and discrimination of pancreas from the duodenal C-loop to 10% COE in 40 patients compared with those obtained from 35 patients, who was received high-density diluted iodinated oral contrast agent (gastrografin). The results are as follows : 1. Patients' tolerance to 10% COE is similar to that to conventional oral contrast agent. 2. Image of the gastric mucosa from patients receiving 10% COE is superior to that receiving oral contrast agent. 3. The ...
The State of the Espirito Santo will become until the end of 2008, one of the main producers and natural gas exporters of Brazil, where, according to PETROBRAS, the State will produce about 20 million /day m{sup 3}, what it will go to contribute significantly for reduction of the dependence of the Bolivian gas, and still to give support to the natural gas sector in Brazil. The Intention of this work, is to identify proposals so that it has left of the gas produced in the State of the Espirito Santo, has a differentiated price. It does not make sensible the State to pay for the gas that is removed in its proper territory the same price that paid Sao Paulo for the gas that consumes imported of national Bolivia. With the markdown of the gas the State will be able to attract investments of great transport, to generate job and income and to ...
We have used the SINFONI integral field spectrograph to map the near-infrared K-band emission lines of molecular and ionised hydrogen in the central regions of two cool core galaxy clusters, Abell 2597 and Sersic 159-03. Gas is detected out to 20 kpc from the nuclei of the brightest cluster galaxies and found to be distributed in clumps and filaments around it. The ionised and molecular gas phases trace each other closely in extent and dynamical state. Both gas phases show signs of interaction with the active nucleus. Within the nuclear regions the kinetic luminosity of this gas is found to be somewhat smaller than the current radio luminosity. Outside the nuclear region the gas has a low velocity dispersion and shows smooth velocity gradients. There is no strong correlation between the intensity of the molecular and ionised gas emission and either the radio or ...
Nova Corporation and its related businesses are involved in natural gas production, gas pipelines, consulting services, and upgrading of natural gas into chemicals and plastics. Nova owns Alberta Gas Transmission Division, the primary gas transportation system in Alberta, with 11,400 miles of pipeline and total deliveries in 1992 of 3.4 trillion ft"3. Nova also owns 50% of Foothills Pipe Lines Ltd., one of Canada's largest carriers of exported gas, and 50% of TQM Pipeline Partnership, which transports natural gas in Quebec. Nova conducts its chemicals business through Novacor Chemicals Ltd., which has plants in Alberta, Ontario, Quebec, and the USA. Novacor's major petrochemicals are methanol, ethylene, propylene, and styrene and its major plastics are polystyrene, polypropylene, and polyethylene. Nova's gas-producing ...
Gas transmission pipelines are susceptible to both internal (gas side) and external (soil side) corrosion attack. Internal corrosion is caused by the presence of salt laden moisture, CO{sub 2}, H{sub 2}S, and perhaps O{sub 2} in the natural gas. Internal corrosion usually manifests itself as general corrosion. However, the presence of chlorides in entrained water also can lead to pitting corrosion damage. The electrochemical noise technique can differentiate general from localized corrosion and provide estimates of corrosion rates without external perturbation of the corroding system. It is increasingly being applied to field and industrial installations for in situ corrosion monitoring. It has been used here to determine its suitability for monitoring internal and external corrosion damage on gas transmission pipelines. Corrosion measurements were made in three types of environments: (1) aqueous ...
Short-lived fission gas release from fuel pellets during irradiation was investigated based on the experimental results of the gas-flow rigs irradiated in the Halden Heavy Water Reactor (HBWR). The release-to-birth (R/B) rates of short-lived fission gas were measured by means of gas-flow measurement during the irradiation experiments. Surface-to-volume (S/V) ratios of fuel pellets and diffusion coefficients of short-lived fission gas release were evaluated from the obtained (R/B) values. The increase of (S/V) ratio agreed well with the point where the fuel temperature exceeded the threshold of 1% fission gas release. This indicates that the interlinkage of fission gas bubbles occurred there. The evaluated diffusion coefficients scattered in the range between 10"-"2"3 and 10"-"1"7 m"2/s, and the effects of fuel type (UO_2 or MOX) were not ...
The European gas market is continuing to expand due to increased industrial, domestic and power generation demand. As a result of this demand, and the trend toward liberalization of the market, the need for storage of gas is also increasing. One key segment of the large scale storage of gas is underground storage, either in partially depleted gas or oil fields, naturally occurring caverns, aquifers and salt cavities. In most cases the gas produced after storage requires conditioning to meet the water of hydrocarbon dew point specification of the gas transmission system. For that reason export gas from storage will require gas conditioning in order to meet pipeline specifications. Adsorption as a feasible and reliable process will be presented in detail and especially in regards to hydrocarbon dew-pointing compared with ...
Geologically estimated natural gas resources are 500 Tcm. With the advance in geological science increase of estimated resources is expected. Natural gas reserves in 2000 have been proved to be around 165 Tcm. As it is known the reserves are subject to two constraints, namely: capital invested in the exploration and drilling technologies used to discover new reserves. The natural gas scarcity factor, i.e. ratio between available reserves and natural gas consumption, is around 300 years for the last 50 years. The new discovery of natural gas reserves has given rise to a new energy strategy based on natural gas. Natural gas utilization is constantly increasing in the last 50 years. With new technologies for deep drilling, we have come to know that there are enormous gas resources available at relatively low price. These ...
Geologically estimated natural gas resources are 500 Tcm. With the advance in geological science increase of estimated resources is expected. Natural gas reserves in 2000 have been proved to be around 165 Tcm. As it is known the reserves are subject to two constraints, namely: capital invested in the exploration and drilling technologies used to discover new reserves. The natural gas scarcity factor, i.e. ratio between available reserves and natural gas consumption, is around 300 years for the last 50 years. The new discovery of natural gas reserves has given rise to a new energy strategy based on natural gas. Natural gas utilization is constantly increasing in the last 50 years. With new technologies for deep drilling, we have come to know that there are enormous gas resources available at relatively low price. These ...
Two-phase flow in horizontal parallel channels has been experimentally investigated under fuel cell related operating conditions. Pronounced hysteresis is observed in the pressure drop versus flow characteristic curve when starting from either flooded or dry conditions. When gas is introduced into channels initially filled with water (flooded initial condition), both gas and liquid tend to flow predominantly in one channel at low gas or liquid flow velocities. As the gas flow velocity increases, even distribution of gas and liquid flow in both channels is observed, accompanied with a sudden decrease in the pressure drop. On the other hand, even gas and liquid flow distribution between both channels is found at comparatively lower gas flow velocities when starting with dry-gas flow conditions with liquid introduced into ...
A report is given of a meeting of the Netherlands Association for Energy Legislation (NEVER), which was held in Amsterdam, Netherlands, April 2006. After the meeting a presentation was made about the report 'Government involvement in liberalised gas markets. A welfare-economic analysis of the Dutch gas-depletion policy' of the Netherlands Bureau for Economic Policy Analysis (CPB). This report analyses the welfare effects of two major components of the Dutch gas-depletion policy: the offtake guarantee for small-fields gas and the cap on production from the Groningen field. After the presentation a reaction was given to the report. Both presentations give an overview of the governmental policy and insight in the effects.
A high-density gas jet supersonic nozzle is reported in this paper. The jitter and actuation time of the nozzle is determined by the pin discharge and laser spark radiation respectively. The jitter time of the nozzle is within 10 ?s with the backing pressure as high as 25 bar. With a nanosecond laser pulse focused on the gas jet about 1 mm below the nozzle, the actuation time is calculated to be about 15 ms by detecting the laser produced spark radiation, which reveals the existence of the gas jet and the relative gas density evolving with time. Consequently the gas density is estimated to be well above 1019 cm-3, compared with theoretical simulations from the nozzle parameters.
Some aspects of the PSO scheme for natural gas are examined critically. Two central arguments used for justifying the PSO subsidy scheme of natural gas and its distribution are reviewed; these include the 'smallholder argument' and the 'environmental argument'. The 'smallholder argument' claims that since Norway has the natural gas resources, it should also make use of the natural gas in the country, and not simply send the raw material to other countries. The 'environmental argument' states that natural gas compared to other fossil fuels such as coal and fuel oil, is a far cleaner alternative, thus an environmental-friendly alternative entitled to financial support. The arguments are critically examined by the author (ml)
We report on the discovery of kinematic shock signatures associated with a localized radio jet interaction in the merging Seyfert galaxy NGC 5929. We explore the velocity-dependent ionization structure of the gas and find that low-ionization gas at the interaction site is significantly more disturbed than high-ionization gas, which we attribute to a local enhancement of shock ionization due to the influence of the jet. The characteristic width of the broad low-ionization emission is consistent with shock velocities predicted from the ionization conditions of the gas. We interpret the relative prominence of shocks to the high density of gas in the nuclear environment of the galaxy and place some constraints of their importance as feedback mechanisms in Seyferts.
Natural gas is a promising alternative fuel to meet strict engine emission regulations in many countries. Natural gas engines can operate at lean burn and stoichiometric conditions with different combustion and emission characteristics. In this paper, the operating envelope, fuel economy, emissions, cycle-to-cycle variations in indicated mean effective pressure and strategies to achieve stable combustion of lean burn natural gas engines are highlighted. Stoichiometric natural gas engines are briefly reviewed. To keep the output power and torque of natural gas engines comparable to those of their gasoline or Diesel counterparts, high boost pressure should be used. High activity catalyst for methane oxidation and lean deNOx system or three way catalyst with precise air-fuel ratio control str...
During the 1990's, natural gas was the energy source with the fastest rate of growth in the world energy balance. Nevertheless, recent evolutions of the energy context, in particular in terms of prices, have had a rather strong impact on the progress of the different energy sources penalizing gas a little. Beyond this competition between energies, which may increase, the medium-term perspectives of natural gas development is in keeping with an environment full of uncertainties. This article presents: the world supply and demand prospects for 2010-2015 (impact of high gas prices on other energy sources, occurrence of production constraints, political decisions of producing countries and world gas industry balance), trends on main markets (North America, Europe, Asia-Oceania), and international trade. (J.S.)
An increasing share of natural gas supplies distributed to residential appliances in the U.S. may come from liquefied natural gas (LNG) imports. The imported gas will be of a higher Wobbe number than domestic gas, and there is concern that it could produce more pollutant emissions at the point of use. This report will review recently undertaken studies, some of which have observed substantial effects on various appliances when operated on different mixtures of imported LNG. While we will summarize findings of major studies, we will not try to characterize broad effects of LNG, but describe how different components of the appliance itself will be affected by imported LNG. This paper considers how the operation of each major component of the gas appliances may be impacted by a switch to LNG, and how this local impact may affect overall safety, performance and pollutant emissions.
The 575-mile Statpipe gas transportation system entails 191 miles of wet-gas line running from the Statfjord field across the Norwegian trench to the Karsto, Norway, conditioning plant and 384 miles of dry-gas line from Karsto, again across the trench, to the Heindal and Sleipner fields for final connection at Ekofisk with the Norpipe system for transport to Emden, West Germany. Special construction considerations include the 1000-ft-deep trench crossings, the rocky shore approach and departure, and the subsea tie-ins required at depths of up to 500 ft. The system has an initial annual design capacity of 186 billion CF of wet gas and 260 billion CF through the dry-gas line to Emden.
The Sulige gas field and the Yulin gas field are located in the north of the Ordos Basin. Reservoir pressure in the Sulige area is subnormal, whereas reservoirs in the Yulin area have normal hydrostatic pressure. This paper provides an explanation of this difference. The characteristics of reservoir sediment and formation water chemistry in the gas reservoirs of these two areas were analyzed. The results showed that both reservoirs have good sealing ability. Data of numerical simulation showed that tectonic uplift resulted in a great reduction in formation pressure in the northern Ordos Basin during the late Cretaceous period, and the decrease was greater in the Yulin gas field than in the Sulige gas field. However, because the total hydrocarbon-generating intensity of the Sulige area (<24...
The Granger instantaneous-causality test is applied to explore the potential causal relationships between wholesale electricity and natural-gas prices in California. The test shows these relationships to be bi-directional, and reveals California's electricity and natural-gas markets to be as inextricably intertwined as casual observation and theoretical considerations would suggest they ought to be. This meshing of markets exacerbated the effects of California's natural-gas crisis on the contemporaneous electricity crisis, while concurrently the electricity crisis may have contributed to the dysfunction in the national-gas market and helped to precipitate the natural-gas crisis. The finding supports an integrated approach, as opposed to a piecemeal approach, for formulating energy policy recommendations, not just in California but in the world at large. (author)
The Granger instantaneous-causality test is applied to explore the potential causal relationships between wholesale electricity and natural-gas prices in California. The test shows these relationships to be bi-directional, and reveals California's electricity and natural-gas markets to be as inextricably intertwined as casual observation and theoretical considerations would suggest they ought to be. This meshing of markets exacerbated the effects of California's natural-gas crisis on the contemporaneous electricity crisis, while concurrently the electricity crisis may have contributed to the dysfunction in the national-gas market and helped to precipitate the natural-gas crisis. The finding supports an integrated approach, as opposed to a piecemeal approach, for formulating energy policy recommendations, not just in California but in the world at large.
In this study the technical and economical possibilities of burning carbon monoxide (CO) of the flue gas and utilizing of the released heat in hot air cupola furnace used for melting have been studied. As basis for examining was burning of cleaned furnace...
The paper is an overview of utility flue gas desulfurization (FGD) technology and costs. The two commercially offered throwaway and salable product systems that are considered to be the most important for near-term (through 1990) SO2 control are: throwawa...
This patent describes a method of improving the S0{sub 2} scrubbing efficiency of flue gas desulfurization scrubbers. It comprises conducting the scrubbing operation in such scrubbers in the presence of an oil-soluble surfactant.
Gas turbine component protection remains essential but environmental regulations emphasize the gas-turbine efficiency. Heating and cooling are features often integrated into the GI air intake packages to provide the optimum operating conditions. This paper describes modern inlet air treatment systems and discusses their effectiveness. (author)
The structure of the skin in the epauletted fruit bat (Epomophorus wahlbergi) wing and body trunk was studied with a view to understanding possible adaptations for gas metabolism and...Full Text Available
The genetic type, source and charging history of natural gas in the Yulin gas field in the Ordos Basin have been studied by combining the carbon isotopic composition of natural gas and geochemical characteristics of light hydrocarbons with carbon isotope fractionation model results and fluid inclusion analysis. The carbon isotopic composition of methane and ethane in the Yulin gas field is relatively enriched in ^1^3C with d^1^3C1 values ranging from -35.3%% to -29.8%% (average value=-32.4%%) and d^1^3C2 ranging from -26.3%% to -23.5%% (average value=-24.8%%). The C7 light hydrocarbons are predominated by methylcyclohexane, accounting for 65.8% to 80.9% (average value=71.6%), which is characteristic of coal-derived gas. Furthermore, the gas geochemistry indicates that, although marine lime...
The Bureau of Mines performed chemical research to elaborate details of sulfur chemistry pertaining to the citrate flue gas desulfurization process in which sulfur dioxide (SO2), absorbed (as bisulfite ion) in a buffered sodium citrate solution, is reduce...
This report gives the results of a survey of operational flue gas desulfurization (FGD) systems on coal-fired utility boilers in the United States. The FGD systems installed on Units 1 and 2 at the Bruce Mansfield Station of the Pennsylvania Power Company...
A catalytic process for the oxidation of sulfur-containing gases , E.G., sulfur dioxide and simultaneous production of sulfuric acid wherein a sulfur-containing gas is reacted with an oxygencontaining gas in the presence of a catalyst comprising an iron group metal on a solid support comprising a zeolite in a silicaalumina matrix.
Gas exchange between the plant and the environment is severely hampered when plants are submerged, leading to oxygen and energy deficits. A straightforward way to reduce these shortages of oxygen and...Full Text Available
TSS (thermal swing sublimation) method was studied which uses vaporization heat and sensible heat of LNG for solidification and separation of CO2 gas in waste gases of LNG-fired combined cycle power generation system. In experiment, the mixed gas composed of CO2, H2O and N2 was used for simulating waste gas of LNG-fired combined cycle power generation systems, and the growth behavior of ice and dry ice was studied for developing dry ice making technology under low-temperature condition. As the experimental result, the following were clarified: various crystal structures depending on cooling temperature, the effect of gas flow rate on peeling of surface precipitated solids, and solidification characteristics of H2O/CO2 mixed gas. The growth rate of precipitated solid film thickness decreased with an increase in gas flow rate, while increased with CO2 ...
Limestone slurry needs to move efficiently through a complex process, meaning that selecting the right pumps and valves is critical. The article discusses factors to consider in selecting pumps and values for flue gas desulfurization process in coal-fired power plants. 2 photos.
The possibility has been explored of using a laser scattering technique to detect the imminent onset of rock activity associated with gas outbursts. The instrument described in this paper provides a sensitive, remote and rapid means of passively monitoring micro-seismic activity at the exposed face.
Petroleum is the unchallenged energy market leader in West Germany,having a share of 42%; natural gas accounts for 16-17%. West Germany imports 29% of its natural gas from the Soviet Union, 28% from the Netherlands, 14% from Norway, and 1% from Denmark. In West Germany many-branched natural gas distribution system is operated, equipped with a.o. 21 installations for underground storage which results in a great flexibility of the system. Because of the preferential treatment given to the use of coal as fuel for power plants the share of natural gas has decreased to the present 6% in the last ten years. In the indutrial sector the share is 18%. Strict air pollution abatement measures ('TA-Luft') favour the use of natural gas. However, duty has been levied on the use of natural gas per January 1st, 1989. For space heating of houses and commercial ...
The Monthly Energy Review provides an overview of the production, distribution, and consumption of energy derived from petroleum natural gas, coal, electricity, and nuclear energy. It also discusses oil and gas resource development, energy prices, and issues relevant to international energy markets.
This report presented some quick facts about oil and gas pipelines in Turkey and presented opportunities for trade. The key players and customers in the oil and gas sector were described along with an export check list. Turkey is looking into becoming an energy bridge between oil and gas producing countries in the Middle East, Central Asia and Europe. The oil and gas sectors are dominated by the Turkish Petroleum Corporation, a public enterprise dealing with exploration and production, and the State Pipeline Corporation which deals with energy transmission. They are also the key buyers of oil and gas equipment in Turkey. There are several pipelines connecting countries bordering the Caspian Sea. Opportunities exist in the areas of engineering consulting as well as contracting services for oil and gas pipeline transmission and distribution. Other opportunities ...
The report gives results of the measurement of dissolution rates of reagent CaCO3 and commercial limestones (9 types/19 grinds) at constant pH and solution composition by batch titration with HC1. Conditions were selected to simulate flue gas desulfurizat...
The influence of geometry and operating conditions of the centrifugal compressor stage on the radial gas force is determined on the basis of the theoretical method and calculation program using experimental boundary conditions.
... Radon gas concentrations are measured using instruments with calibrations traceable to the UK National Physical Laboratory and PTB, Germany. The primary facility is a 43 m3 walk-in chamber accessed by an airlock. Radon gas is maintained at a level in this chamber that is ...
The various steps of gas treatment in the Sasol II coal liquefaction plant are discussed: CO/sub 2/ removal, separation of the hydrocarbon fractions and the recirculated hydrogen by low-temperature decomposition, production of pure hydrogen by alternating pressure absorption.
Jeltes, R., Burghardt, E., and Breman, J. (1971). Brit. J. industr. Med., 28, 96-99. Gas chromatographic determination of phosgene and dichloroacetylene in air. Phosgene and dichloroacetylene...Full Text Available
An experimental investigation of heat transfer characteristics for various configurations of air jets impinging on the leading edge inner surface of a gas turbine blade wall is presented. Three configurations were investigated, namely a slot jet, a round ...
The goal of GRI's Gas Appliance Technology Center is to encourage the introduction of highly efficient, cost-effective, convenient gas appliances for residential and commercial gas users. The report covers activity at Battelle from February 1989 to April 1990 in broad support tasks, residential and commercial appliances, and residential space conditioning. Broad support tasks included the G/A/S Newsletter; the GATC InfoBase; and technology transfer, workshops, and GATC coordination. Residential appliance tasks included burner technology research, gas appliance venting, gas lighting, and plastics durability. Commercial appliance tasks included development of a commercial cooktop fuel/air mixing valve. Residential space conditioning tasks included a corrosion test method for gas appliances and vents, generic technology for condensing ...
This paper summarizes the current scientific and technological knowledge about greenhouse gas emissions from various agricultural practices and the manufacturing of food. The study also provides estimates that compare agriculture-related alternatives for reducing greenhouse gas emissions.
Legal aspects of using natural gas as boiler fuel for electric utilities are reviewed through one utility's challenges to the Power Plant and Industrial Fuel Use implementation. ASARCO vs. FPC, 1973, and City of Willcox vs. FPC are discussed. (PSB)
The report, generated by a computerized data base system, presents a survey of operational and planned domestic utility flue gas desulfurization (FGD) systems, operational domestic particle scrubbers, and Japanese coal-fired utility FGD installations. It ...
The report presents detailed technical information concerning application of flue gas desulfurization (FGD) systems to industrial boilers. The information was obtained by a survey of plant personnel, control system vendors, regulatory agencies, and consulting engineering firms. T...
The report discusses the capabilities of equipment vendors to supply and install the quantity of flue gas desulfurization systems required to meet alternative standards for coal-fired steam generators. It analyzes limiting factors affecting supply capabilities (such as the availa...
The effects of freeze-thaw cycling on the strength and durability of samples of compacted, stabilized, wet flue gas desulfurization (FGD) by-products are reported. The results of laboratory tests show a clear relationship between higher water contents and...
NO[sub x] emission legislation requirements for large-bore internal combustion engines have required engine manufacturers to continue to develop and improve techniques for exhaust emission reduction. This paper describes the development of the Cooper-Bessemer Clean Burn gas-diesel (dual-fuel) engine that results in NO[sub x] reductions of up to 92 percent as compared with an uncontrolled gas-diesel engine. Historically, the gas-diesel and diesel engine combustion systems have not responded to similar techniques of NO[sub x] reduction that have been successful on straight spark-ignited natural gas burning engines. NO[sub x] levels of a nominal 1.0 g/BHP-h, equal to the spark-ignited natural gas fueled engine, have been achieved for the gas-diesel and are described. In addition, the higher opacity exhaust plume characteristic of gas-diesel ...
Concentration of an amine solution for removal of hydrogen sulfides and carbon dioxide from natural gas, is tested by carbon dioxide absorption measurement in an apparatus allowing complete reaction to give reliable results.
The increasing price differential between natural gas and coal will create a demand for technology that can allow the displacement of natural gas with coal in power plants. Coal gasification is the standard approach suggested to allow coal to displace natural gas. However, the relatively high capital investment required for coal gasification will require fuel cost differentials higher than those anticipated in the near term before coal gasification replaces natural gas. One way of achieving shorter term displacement of natural gas by coal would be to develop technology that would allow coal to be used as the heat source for the endothermic reforming of natural gas. In a natural gas-fired combined cycle power plant, the endothermic heat of reforming, which would be provided by coal combustion, is recovered in the combined-cycle. Therefore, ...
At the St. Joe Minerals Corp.'s zinc smelter powerplant, an SO2 emission control program evolved into a cooperative program with the Bureau of Mines for installation and initial operation of a citrate process flue gas desulfurization demonstration plant. ...
The report describes a computer model developed by TVA to simulate the performance and determine the economics of coal cleaning, or coal cleaning combined with flue gas desulfurization (FGD), for power plant emission control processes over a wide range of user-specified condition...
The manual describes a combined coal-cleaning and flue gas desulfurization (FGD) computerized design and cost-estimate model and gives detailed procedures for using it. All inputs and outputs are described, as well as the various options available. Design and economic premises ar...
This project addresses the problem of flue gas desulfurization (FGD) sludge disposal to land. Specifically, the chemical species of FGD sludge constituents are thermodynamically modeled using the equilibrium constant approach, in an attempt to predict the constituent concentratio...
The report gives an initial assessment of the feasibility of disposing of flue gas desulfurization wastes in mines and in the ocean. The purpose of the assessment was to evaluate environmental, technical, regulatory, and economic aspects of the use of such disposal sites. Availab...
Crockford, G. W., Crowder, M., and Prestidge, S. P. (1972).Brit. J. industr. Med.,29, 378-386. A trace gas technique for measuring clothing microclimate...Full Text Available
In this paper we have proposed a novel gas turbine cycle with hydrogen-fueled chemical-looping combustion, and the system study on two hydrogen-fueled power plants, the new gas turbine cycle and an advanced gas turbine cycle with H{sub 2}/O{sub 2} combustion, has been investigated with the aid of exergy principle (EUD methodology). The hydrogen fueled chemical-looping combustion in the new gas turbine cycle consists of two successive reactions: hydrogen fuel is reacted with metal oxide (reduction of metal oxide), and then instead of air or pure oxygen, the reduced metal is successively oxidized by the saturated air. As a result, the new hydrogen-fueled gas turbine cycle has a breakthrough performance, with at least about 12 percentage-point higher efficiency compared to the gas turbine cycle with H{sub 2}/O{sub 2} combustion, and will be environmentally superior ...
Gas-fired combined cycle plant may be the norm when it comes to new plant but it comes in a variety of shapes and sizes. Samarinda uses aero-derivatives with the famous Rolls-Royce RB211 gas generator. (author)
The feasibility of producing a pocket-sized air contaminant monitor based upon a miniature gas chromatograph and an integrated microcomputer has been demonstrated and a practical design for the instrument is presented. This pocket-sized instrument is intended to be used as a pers...
Apparatus and method for selective measurement of tritium oxide in an environment which may include other radioactive components and gamma radiation, the measurement including the selective separation of tritium oxide from a sample gas through a membrane into a counting gas, the generation of electrical pulses individually representative by rise times of tritium oxide and other radioactivity in the counting gas, separation of the pulses by rise times, and counting of those pulses representative of tritium oxide. The invention further includes the separate measurement of any tritium in the sample gas by oxidizing the tritium to tritium oxide and carrying out a second separation and analysis procedure as described above.
A high-voltage cathode initiates an electron emission, resulting in a reduction in the carbon dioxide concentration in exhaust gas from the burning of hydrocarbon fuel. Assuming that the observed carbon dioxide reduction is originated from the molecular decomposition, the energy needed for the endothermic reaction of this carbon dioxide reduction may stem primarily from the internal energy reduction in the exhaust gas in accordance of the first law of the thermodynamics. An oxygen increase due to the reduction in carbon dioxide in a discharge gas was observed in real time.
This report consists of three sections. The first section is a brief general overview of all the issues that impact the competition between natural gas and electricity in industrial applications. The second section of this report focus on the all the marketing issues and provides detail analysis of the status of these issues in Europe, Japan and United States. The third section of this report is a detail review of the current status of the competition between gas technologies and electro-technologies, it also make recommendation for developing new gas technologies. The fourth section is a contribution from M. Pettersson and S. Stenstroem, Sweden, on infrared dryers. (authors)
Makeup water is distilled internally in an amine gas treating unit by adding it to the reclaimer used to process a slipstream of lean amine from the stripper.
Experimental data on the gas holdup and the mean bubble size in a bubble column with a single nozzle was obtained for gas-molten salt systems of a eutectic mixture of LiCl (58 mol %)-KCl (42 mol %) and molten NaNO/sub 3/. The liquid-phase mass transfer coefficient K /SUB L/ was evaluated from the specific surface area a and the volumetric coefficient K /SUB L/ a data for oxygen and carbon dioxide absorption into molten NaNO/sub 3/. The dimensionless correlations of the performance of bubble columns for aqueous solutions can be extended to the gas-molten salt systems.
This dissertation deals with membrane gas absorption in the application of CO{sub 2} removal by aqueous alkanolamines, using microporous PTFE hollow fiber membranes. A new lab-scale apparatus was constructed and an extensive experimental study executed to determine the performance of the membrane gas absorber, with aqueous solutions of monoethanolamine (MEA) and methyldiethanolamine (MDEA) as absorbents. The important operation parameters CO{sub 2} partial pressure, gas velocity, liquid velocity, temperature and liquid CO{sub 2} loading were systematically varied within the range typically experienced in a process for exhaust gas CO{sub 2}-removal
This thesis dealt with the metal-organic gas phase epitaxy with nitrogen as carrier gas. For this first by means of three-dimensional modelings of the epitaxy process the influence of the carrier gas on the processes was explained. The optimization of the growth parameter for the whole light-emitting-diode structure in double-hetero arrangement resulted that an a temperature of 770 C and a V/ III-ratio of 150 layers with a high crystal quality could be reached.
Access for independents to retail gas markets was a central concern in European policy reform efforts in the 1990s. Upstream oil and gas companies reacted with strategic intentions of forward integration. By late 2004, forward integration was still weak, however. An important explanation of the gap between announced strategic re-orientation and actual strategy implementation lies in the political failure of EU member states to dismantle market barriers to entry for independents. Variations between companies in downstream strategy implementation are explained by variations in business opportunities and internal company factors.
Kawasaki Heavy Industries, Ltd. has developed a gas turbine combined cycle and cogeneration plant computer aided engineering (CAE) system, which creates cycle heat balance automatically on given configurations of gas turbines, heat recovery boilers, steam turbines and auxiliaries. The system can predict the performance of the plant as a function of control set points, loads, process steam requirements and ambient conditions, which enables accurate and fast design of gas turbine combined cycle and cogeneration plants. (author)
Dimethyl methylphosphonate (DMMP), a chemical simulant of the nerve gas GB, was decontaminated with a nonthermal atmospheric pressure plasma. The decontamination efficiency was measured qualitatively by means of Fourier transform spectroscopy and quantitatively by means of gas chromatography. With helium gas only, 10g/m2 of DMMP on an aluminum surface was 99.9% decontaminated in 2min, furthermore, with the addition of 5% of oxygen gas, it was 99.99% decontaminated in 10min. Given the low input power (<100W) and temperature (<75degreeC), this plasma is eligible for nondestructive decontamination of almost all material surfaces.
The purpose of this work was to develop and evaluate a method of locating breached fuel within the Fast Flux Test Facility (FFTF) reactor based on the relative response of the delayed neutron monitors (DNM) located on each of the three primary sodium cooling loops. The primary method of location is the use of tag gas containing unique ratios of the noble gases xenon and krypton. Although the tag gas system works quite well, it is relatively expensive because of the costs of preparing and loading the gas into each fuel pin. Triangulation of DNM signals could potentially decrease tag gas costs while maintaining overall location reliability.
Biogas supply to the public gas grid is a new option discussed in the most recent publication of Fachagentur Nachwachsende Rohstoffe (FNR) e.V. The biogas is purified, upgraded to natural gas quality and fed into an existing gas grid. Once there, it can be transported across long distances and also used for electric power generation at the consumer side. The study investigates inhowfar and in what instances this method is feasible and promising. It discusses the technical background and the regional potential of biogas. Seven model biogas systems are presented as examples. (orig.)
This paper is a quarterly report describing the use of a new soil gas collection device which allows the collection of soil gas in the field for later analysis in the laboratory. It describes the installation of this sampling device and the procedure for setting the probe, extraction of soil gas beneath the surface, and sealing of the soil gas for transport. The sites used for initial testing was the top of Yucca Mountain and Crystal Spring in Ash Meadows National Wildlife Refuge. The results from this initial test showed no volatile matter present in the soil at these locations.
The multicell proportional chambers at the backing calorimeter of the ZEUS experiment at the storage ring HERA are supplied with a gas mixture of Ar/CO[sub 2] by an open gas system. Flow proportional counters with the build-up [sup 55]Fe sources are used as gas system monitoring detectors. The ZEUS experiment is planned to collect data for about 10 years. Therefore, the lifetime of the Ar/CO[sub 2] mixture should be known. In this paper, the results of laboratory tests and preliminary measurements of the aging effects for monitoring counters are presented. ((orig.))
The risk perception of the public consists of two components: the objectively factual component and the subjectively irrational component. The two strategies adopted by the German gas supply industry are the internal and the external communication strategy. Concepts and measures of accident precaution, registration and analysis of accident data (installation and operating errors, defects on flue systems, pipelines and valves, subsequent installation of gas appliances) are discussed. (R.P.)
The energy price volatility model suggests that some of the proposed natural gas programs can contribute to energy price stability. The sector most vulnerable to fuel price variations is, of course, the transportation sector. The most effective strategy to achieve energy pace stability is to reduce petroleum consumption in this sector. The natural gas vehicle program is therefore recommended as potentially important and worthy of further consideration. At this point, distinguishing the merits of various subprograms is not feasible. This result farther supports the conclusion that the DOE`s energy R&D portfolio is not efficiently balanced and an increase in oil and gas research should be a high priority. The DOE has responded favorably and has significantly increased its proposed research with the explicit objective of displacing oil in the transportation sector. The enhanced research and development program for energy ...
This paper gives a Coulomb gas representation for level kN = 1 supersymmetric SU(2) Kac-Moody algebra in terms of three free scalar superfields. It is clarified how this representation reduces to a Coulomb gas representation for the corresponding bosonic SU(2) Kac-Moody algebra and the free fermionic algebra. The primary superfields and the correlation functions, which satisfy the supersymmetric Knizhnik-Zamolodchikov equation, are also discussed.
The US$360 million project to increase gas supplies to Eastern and Southern Thailand is discussed, and the use of international competitive bidding to purchase the line pipe and other facilities is reported. The government approved proposal for a gas fired combined-cycle power station and gas separation plant are discussed. (UK).
The need is substantiated for using remote control of technological processes on blowout dangerous beds. A method is proposed for this control based on recording with the help of AGZ apparatus for gas release into the roadway. Distinguishing features are indicated for the change in methane concentration in the roadway with normal occurrence of the process and in the case of blowout of coal and gas.
Smart electricity and gas supply grids are a prerequiste for full-scale utilization of the potential of modern energy-saving appliances and equipment. Direct exchange of information between the supplier and the consumer is indispensable for reducing costly and energy-intensive peak loads. (orig.)
This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid vapor condensed in both the high temperature and low temperature ...
This invention pertains to a Fischer Tropsch process for converting synthesis gas to an oxygenated hydrocarbon with particular emphasis on dimethyl ether. Synthesis gas comprising carbon monoxide and hydrogen are converted to dimethyl ether by carrying out the reaction in the presence of an alkali metal-manganese-iron carbonyl cluster incorporated onto a zirconia-alumina support.
To suppress space charge blowup in an ion beam passing through a photoneutralizer, it is necessary to introduce some background gas. An analysis is presented of the neutralization of a high-energy, >200-keV negative deuterium ion beam, exposed to photodetachment while in the presence of deuterium. With a gas thickness of <0.01 Torr.cm, the neutral fraction in the output beam is found to be about the same as that gotten from the photoneutralizer operating in vacuum. Neutral atom beam injection for plasma heating is discussed.
This paper describes a practical knowledge on gas engine performance and combustion characteristics which are required by experimental studies for two types of developed gas burning engines, i. e. a spark ignited gas engine and a dual fuel engine, and also introduces their practical use and application. As for dual fuel engine performance, a manifold air pressure of about 27% was decreased, a scavenging ratio of 23% reduced and an exhaust temperature at the turbine inlet on 14% was increased at the gas engine operation under the mean effective cylinder pressure of 1.22 MPa in comparison with the diesel operation. Furthemore, empirical data on the effect of excess air ration on the engine performance and combustion characteristics, a risk of knocking during changing over on the dual fuel engine operation, and the rated output in case of using alternate fuel gas were reported. Two ...
Triassic sedimentary rocks are widespread in the Pechora sineclise and Pre-Uralian edge trough territory. They are up to 920 and 400 m thick respectively. Commercial flows of oil and gas have been obtained from these deposits in the last few years. The geology of the area is described and its is concluded that the main oil and gas potential should be connected with the northern areas of the Pechora sineclise.
I propose that an interpretation of the interaction of noble gas atoms with metal surfaces as predominantly physisorbing provides the best explanation for the systematics of their binding energies and surface dipoles, as well as for the tendency of noble gas atoms to bind in low coordinated sites. In the present context physisorption is defined as a process driven by the overlap of the electrostatic atomic potentials of the interacting species. (orig.)
The technical and economic feasibility of using a typical, elemental, phosphorus byproduct gas stream in methanol production is assessed. The purpose of the study is to explore the potential of a substitute for natural gas. The first part of the study establishes economic tradeoffs between several alternative methods of supplying the hydrogen which is needed in the methanol synthesis process to react with CO from the off gas. The preferred alternative is the Battelle Process, which uses natural gas in combination with the off gas in an economically sized methanol plant. The second part of the study presents a preliminary basic design of a plant to (1) clean and compress the off gas, (2) return recovered phosphorus to the phosphorus plant, and (3) produce methanol by the Battelle Process. Use of elemental phosphorus byproduct gas in methanol ...
This paper reports that Sen. Bennett Johnston (D-La.) has vowed if Congress enacts an omnibus energy bill in the fall, it will not include a restriction on states' rights to proration natural gas production. Johnston, Senate energy committee chairman, will lead Senate conferees in their negotiations with members of the House of Representatives. The House energy bill has an antiproration amendment. The Senate's bill does not. Oklahoma's and Texas' recent actions to proration gas production prompted the federal legislation.
The 66 fields discovered since the 1960s in the northern West Siberian basin contain at least 22 trillion m/sup 3/ (777 tcf) of proved gas, almost one-third of the world's reserves. Half of these fields are giants (> 85 billion m/sup 3/ or 3000 bcf of reserves). These include the largest and second-largest gas fields in the world-Urengoy (8.099 trillion m/sup 3/ or 286 tcf of gas) and Yamburg (4.81 trillion m/sup 3/ or 170 tcf of gas)-as well as most of the other ten largest gas fields in the world. The West Siberian basin occupies a 3.4-million km/sup 2/ (1.31-million mi/sup 2/) arctic lowland immediately east of the Ural Mountains, extending north under the Kara Sea. It is a composite basin, with Mesozoic-Cenozoic basin fill on top of a Paleozoic basin that overlies a crystalline Archean-Proterozoic framework. The productive zones in the northern basin are principally ...
Cattle or chicken manure is pelletized, and a bed of the pellets is combusted at the bottom to create a temperature gradient and to generate a fuel gas. Thus, an approximately 25 cm-high bed of approximately 5 mm-diameter chicken manure pellets was combusted to produce a fuel gas of 1622 kcal/kg manure.
There are several concerns which bring to consider natural gas as a viable alternative to liquid fuels in transport. First, natural gas allows the curbing of global pollution in this steadily growing industry. Indeed, decoupling greenhouse gas emissions from transport growth has become a major issue in tackling climate change. Second, a more extensive use of natural gas would relieve city air quality, which is presently at levels harmful of human health. Nonetheless, this is just one side of the coin. The other side entails building a refuelling station network, and this carries financial requirements. The financing fraction holds a pivotal role in deciding whether natural gas for automotive purposes is an efficient solution. The final aim of this work is, therefore, to compare the natural gas advantages, stemming from avoided global and local emission, with the ...
In order to facilitate observations of low energy nuclear reactions, a new type recoil mass-separator together with a new gas-jet target system is being developed at the tandem accelerator facility in Kyushu University. The expected mass-resolving power of the separator is 220 for a solid angle of 10 msr and the practical thickness of the gas-jet target will exceed 0.1 atm#centre dot#cm for the light elements of H and He. (author).
The EPA proposed effluent limitations guidelines and standards for the offshore segment of the oil and gas industry on August 26, 1985. On November 26, 1990, and March 13, 1991, the Agency reproposed effluent limitations guidelines and standards for both drilling and production wastes. The report is primarily concerned with the total annualized cost incurred by the offshore oil and gas industry in complying with the regulations.
In a suicide committed using aluminium phosphide (AlP) the liberated toxic phosphine gas was detected in post-mortem specimens using a headspace gas chromatographic procedure with a nitrogen-phosphorous detector (HS-GC/NPD). At autopsy a direct sampling into airtight headspace vials for a later analysis is recommended. AlP has to be considered a potent pesticide and its use and availability should be restricted as much as possible.
The densities for binary mixtures of dichloromethane with aniline, or nitrobenzene, respectively, including those of pure liquids, were measured over the entire composition range at T = (288.15, 293.15, 298.15, and 303.15) K and atmospheric pressure using a vibrating-tube densimeter. From the experimental results, the excess molar volumes, V{sub m}{sup E}, partial molar volumes, V{sub i}-bar, the apparent molar volume, V{sub {phi}}{sub i}, and the partial molar excess volumes at infinite dilution, (V{sub i}{sup E}-bar){sup {infinity}}, were calculated over whole composition range. Negative values of V{sub m}{sup E} for (dichloromethane + aniline) attributed to the formation of the charge transfer complex, while for (dichloromethane + nitrobenzene) system, the free volume effect played a dominant role. The extent of negative deviations in V{sub m}{sup E} values follows the order: nitrobenzene > aniline. The Prigogine-Flory-Patterson (PFP) theory and its ...
Underground injection, compared to other waste disposal methods, is considered to have the advantages of isolating wastes in a confined brine aquifer well below the horizon of human activity and underground sources of drinking water (USDWs). While most of injected wastes move laterally in the injection zone, posing a long-term concern to the human health and environment, a small amount can migrate upward to the upper aquifers, causing a greater threat to the quality of USDWs. Both the dual porosity and the single porosity models were used to investigate the migration of injected wastes through these hydrologic conduits. The results indicate that regional upward migration through an extensive confining formation is a slow process. Nevertheless, injected wastes can move upward rapidly through microannuli and channels in the cement sheath and spread over a distance in the upper aquifer. The wastes can also migrate fast through fractures in the disturbed zone. The study further suggests ...
The US Nuclear Regulatory Commission is currently considering revision of rule 10 CFR Part 20, which covers disposal of solid wastes containing minimal radioactivity. In support of these revised rules, we have evaluated the consequences of disposing of four waste streams at four types of disposal areas located in three different geographic regions. Consequences are expressed in terms of human exposures and associated health effects. Each geographic region has its own climate and geology. Example waste streams, waste disposal methods, and geographic regions chosen for this study are clearly specified. Monetary consequences of minimal activity waste disposal are briefly discussed. The PRESTO methodology was used to evaluate radionuclide transport and health effects. This methodology was developed to assess radiological impacts to a static local population for a 1000-year period following disposal. Pathways and processes of transit from the trench to exposed populations included the ...
Most livestock farmers in the United States do not take advantage of anaerobic digester technology because of the high cost and large scale. These limitations therefore reduce the production of renewable energy from farmlands. In order to expand anaerobic digestion methods and improve environmental quality, affordable and smaller-scale digesters should be developed to enable most livestock farmers to convert manure to methane. Doing so would improve their economic efficiency and environmental sustainability. This paper provided an analogy to the development of the Model T to better explain the need and potential for this technology. A modified fixed-dome digester was installed on the Ohio State University dairy in Columbus, Ohio. The digester was unheated, buried, had a volume of 1 m{sup 3} and received diluted dairy manure as feedstock. Biogas was produced at digester temperatures as low 10 degrees C during colder ambient temperatures. Water quality also improved. ...
Isotherms have been measured for H(D){sub 2}(g) solution in crystalline Pd{sub 9}Si{sub 2} in the temperature range from 235 to 373 K. The solubilities are significant, e.g., at 1.0 MPa (298 K), (H/Pd) = 0.052 or Pd{sub 9}Si{sub 2}H{sub 0.47}, however, there is no indication of hydride phase formation even down to 235 K at 1.0 MPa. The thermodynamic values for hydrogen solutions at infinite dilution of hydrogen are {Delta}H{degrees}{sub H}= -11.9 kJ/mole {1/2}H{sub 2} and {Delta}S{degrees}{sub H} = -50 J/K mole {1/2}H{sub 2}. The former is more negative than for Pd-H{sub 2} and the latter is somewhat more positive; but generally the values are not that different from Pd-H{sub 2}. The isotope effect is similar to that found for Pd-H(D){sub 2}.
Full text. Here we present a status report of the Schenberg antenna, which started commissioning runs in September 2006 under the full support of FAPESP. In its first commissioning runs we tested three preliminary parametric transducer systems, which did not achieve a high enough performance for placing the antenna sensitivity in the range of the calibrator capacitor. Instead of improving the calibrator, making it capable of introducing a larger input force, we decided to go to a radical upgrading operation: replacing the three transducers for a complete set of six transducers, with better sensitivity and arranged according to the truncated icosahedron configuration, plus two extra ones; starting to install the dilution refrigerator; installing wires, cables, and amplifiers for the complete set of transducer circuits; and a new suspension and vibration isolation system for the cabling and microstrip antennas. We also have been developing a new set of transducers, ...
We demonstrate that a massive asymptotic giant branch (AGB) star is a good candidate as the main source of short-lived radionuclides in the early solar system. Recent identification of massive (4-8 solar masses) AGB stars in the Galaxy, which are both lithium- and rubidium-rich, demonstrates that these stars experience proton captures at the base of the convective envelope (hot bottom burning), together with high-neutron density nucleosynthesis with 22Ne as a neutron source in the He shell and efficient dredge-up of the processed material. A model of a 6.5 solar masses star of solar metallicity can simultaneously match the abundances of 26Al, 41Ca, 60Fe, and 107Pd inferred to have been present in the solar nebula by using a dilution factor of 1 part of AGB material per 300 parts of original solar nebula material, and taking into account a time interval between injection of the short-lived nuclides and consolidation of the first meteorites equal to 0.53 Myr. Such a ...
The excess molar volumes V_m"E for binary liquid mixtures containing dipropylene glycol monomethyl ether or dipropylene glycol monobutyl ether and methanol, 1-propanol, 1-pentanol and 1-heptanol have been measured as a function of composition using a continuous dilution dilatometer at T=(288.15, 298.15, and 308.15) K and atmospheric pressure over the whole concentration range. The excess volume results allowed the following mixing quantities to be reported in all range of concentrations or at equimolar concentrations: #alpha#, volume expansivity; (#partial deriv#V_m"E/#partial deriv#T)_p; (#partial deriv#H"E/#partial deriv#P)_T at T=298.15 K. The obtained results have been compared at T=298.15 K with the calculated values by using the Flory theory of liquid mixtures. The theory predicts the #alpha#, and #alpha#"E values rather well, while the calculated values of (#partial deriv#V_m"E/#partial deriv#T)_p and (#partial deriv#H"E/#partial deriv#P)_T show general ...
The distribution of Cu, Ni, Co and Mn between an aqueous solution of constant ionic strength and Versatic Acid 911 diluted with benzene was investigated. Only one extracted species of Cu was revealed to have a dimeric structure of the composition (CuR_2.RH)_2, while both monomer and dimer were found in the extraction of Ni, Co and Mn. The curve-fitting method was employed to determine these species, from which the composition of the extracted species was found to be NiR_2.4RH and (NiR_2.2RH)_2, CoR_2.4RH and (CoR_2.2RH)_2, and MnR_2.4RH and (MnR_2.2RH)_2, respectively. The apparent equilibrium constants of the above species and those between monomer and dimer were also determined. The curve-fitting method was proved to be a precise method for determining the equilibrium constants and extracted species. (author).
Here we present evidence that in water/acetonitrile solvent detailed structural and dynamic information can be obtained for important proteins that are naturally present as oligomers under native conditions. An NMR-derived human insulin monomer structure in H{sub 2}O/CD{sub 3}CN, 65/35 vol%, pH 3.6 is presented and compared with the available X-ray structure of a monomer that forms part of a hexamer (Acta Crystallogr. 2003 Sec. D59, 474) and with NMR structures in water and organic cosolvent. Detailed analysis using PFGSE NMR, temperature-dependent NMR, dilution experiments and CSI proves that the structure is monomeric in the concentration and temperature ranges 0.1-3 mM and 10-30 deg. C, respectively. The presence of long-range interstrand NOEs, as found in the crystal structure of the monomer, provides the evidence for conservation of the tertiary structure. Starting from structures calculated by the program CYANA, two different molecular dynamics simulated ...
In this work the authors study the stabilization point of a lifted, reacting jet of nitrogen diluted methane in co-flowing air. The jet flow is acoustically forced so as to organize the large scale vortical structures. The validation of the numerical results is possible through a concurrent experimental investigation of a similar planar jet. The use of an acoustically forced planar jet allows for significant savings by the restriction of the computation to two dimensions; the model is otherwise applicable in three dimensions. The authors based their study on the following parameters, which are derived from the experimental setup: a jet width of 1.16 cm, a mean jet velocity of 0.8 m/s, and a coflow velocity of 0.1 m/s. The acoustical forcing is studied at frequencies of 7.5 MHz and 90 MHz, which have been established experimentally as being characteristic of two broad behavioral modes. The authors restrict themselves to five species and the single step, ...
The results of a combined investigation of splat-quenched Fe-Csub(x) (x<0.05) alloys by resistivity, X-ray diffraction and Moessbauer spectroscopy are presented. The residual resistivity increases linearly with the carbon content (#DELTA#rho=5#mu##OMEGA#cm/at.%) with a slope identical to that observed in the dilute ferritic phase. X-ray diffraction reveals the presence of a martensite structure in addition to a small fraction of residual austenite; the dependence of the a and c lattice parameters on xsub(c) agrees with earlier measurements. A detailed investigation of the relative reflexion intensities shows that the as-quenched martensites consist of a mixing of massive martensite and tetragonal martensite for low carbon content and of tetragonal martensite only for xsub(c) approximately 0.05. The Moessbauer spectra reveal 3 or 4 magnetically non equivalent iron sites. From a detailed analysis of the intensity dependence of the subspectra on carbon content the ...
Vertical U-tube steam generators in Pressurized Water Reactors (PWRs) operating an All Volatile Treatment (AVT) secondary chemistry have experienced corrosion problems, particularly denting and sludges. The studies reported evaluate the feasibility of using a low-concentration (0.5 wt%) chemical cleaning process to remove corrosion product deposits from steam generator surfaces and magnetite from tube-to-support plate crevices of PWR steam generators. The process potentially may be applied at schedule intervals, such as during normal refueling outages, to maintain a steam generator in clean operating condition. This report describes the results of testing to evaluate the effectiveness of several chelant acids for dissolving steam generator sludges and crevice magnetite. Corrosion of carbon steel by the chelant acids and the effects of various inhibitors are evaluated. The effectiveness of ion-exchange regeneration of several chelant-based solvents is also addressed. 10 figures, 12 ...
Investigations were made on the biodegradability and bacterial toxicity of chemicals. The intention was to obtain data necessary for estimating and judging the behaviour of these chemicals during aerobic biological waste water treatment. The course of biodegradation and toxicity with time and concentration could be measured, quantified and described. As test procedure, the respirometric dilution method was used. This method is based on a die away test with continuous measuring of the oxygen used for biochemical oxidation processes. The course of the oxygen demand with time and concentration shows the biodegradation and toxicity patterns of the tested chemical. A variety of household and industrial chemicals were investigated. One group of substances were microbiocides, some of which showed toxic effects at concentrations less than 20 mg/l while others were biodegradable even at concentrations of 200 mg/l. Another group of test chemicals were anionic and nonionic ...
The surface coverage of amorphous silica gels used in the synthesis of silica polyamine composites has been investigated by 29Si NMR. By diluting the polyamine anchor silane, chloropropyl trichlorosilane, with methyl trichlorosilane it was found that surface coverage could be markedly improved for a range of amine polymers after grafting to the silica surface. The commensurate decrease in the number of anchor points and increase in the number of free amines results in an increase in metal capacity and/or an improvement in capture kinetics. Solid state CPMAS-13C NMR has been employed to investigate the structure and metal ion binding of a series of these composite materials. It is reported that the highly branched polymer, poly(ethyleneimine) (PEI) exhibits much broader 13C NMR resonances than the linear polymers poly(allylamine) (PAA) and poly(vinylamine) (PVA). These results are understood in terms of the low energy conformations calculated from molecular modeling ...
This study presents a rapid and selective method for the recovery of lanthanides and yttrium, existing in economically interesting concentrations, from red mud, the byproduct of the alumina production. The leaching process is based on the extraction of these elements with diluted nitric acid from red mud under moderate conditions and without using any preliminary treatment. Several parameters such as leaching agents, contact time, temperature, pressure and solid to liquid ratio were investigated in order to achieve an optimum recovery. The process followed here was selected taking into account its efficiency for the selective recovery of yttrium and lanthanides, but also its suitability for the subsequent liquid-liquid extraction of the leaching solution for the separation of the individual lanthanides. The achieved recovery percentages were for Y about 90%, for the investigated heavy lanthanides (Dy, Er, Yb) up to 70%, for the middle ones (Nd, Sm, Eu, Gd) up to ...
This study presents a rapid and selective method for the recovery of lanthanides and yttrium, existing in economically interesting concentrations, from red mud, the byproduct of the alumina production. The leaching process is based on the extraction of these elements with diluted nitric acid from red mud under moderate conditions and without using any preliminary treatment. Several parameters such as leaching agents, contact time, temperature, pressure and solid to liquid ratio were investigated in order to achieve an optimum recovery. The process followed here was selected taking into account its efficiency for the selective recovery of yttrium and lanthanides, but also its suitability for the subsequent liquid-liquid extraction of the leaching solution for the separation of the individual lanthanides. The achieved recovery percentages were for Y about 90%, for the investigated heavy lanthanides (Dy, Er, Yb) up to 70%, for the middle ones (Nd, Sm, Eu, Gd) up to ...
This study deals with the adsorption and desorption of lead (c <= 10/sup -8/ - 10/sup -3/ M), labelled with /sup 212/Pb or /sup 210/Pb, on glass in relation to pH and composition of the solution, concentration of lead and time. The prevailing mechanism of the adsorption in the pH range from 3 to 8 is the ion exchange of Pb/sup 2 +/ and PbOH/sup +/ ions in electric double layer on the surface of glass. At the higher pH values lead (c <= 10/sup -8/ - 10/sup -6/ M) is adsorbed mainly by physical adsorption or chemisorption of its hydrolyzed forms. A rather high adsorption capacity of glass, exceeding 3.10/sup -9/ M/cm/sup 2/, has been found in neutral solutions for the cationic forms of lead. The adsorbed lead can be easily desorbed with the solution of 1 M nitric acid.
Pitting corrosion of Inconel 600 was examined in chloride and sulfate solutions through usage of potentiodynamic polarization techniques. The effects of chloride and sulfate concentration were investigated in the range of 0.0001 to 0.1 M. Increasing chloride concentrations resulted in active shifts of the pit nucleation potential. Immunity to pitting corrosion was evident at a chloride level below 0.005 M. Increasing sulfate concentrations resulted in improved pitting resistance of Inconel 600 in chloride solutions. Detrimental effects associated with pitting were evident with low-level sulfate being added to dilute chloride media. The density of pits increased with increasing chloride concentrations or temperature between room temperature and 70 C. Systematic trends for the depth of pits were not evident. The observations of pitting corrosion in open immersion were consistent with those in polarization methods. Corrosion products contained in the pits were ...
In this dissertation, a two-phase, air-droplets, dilute, turbulent, and steady state flow in a horizontal rectangular channel, is modeled and numerically simulated using a modified KIVA-3V code. The deposition of different sizes of droplets on the walls of the channel is also studied. In this model, the interaction effects between the phases (two-way coupling) are considered by source terms in the momentum and energy equations for the continuous phase and by the instantaneous local velocity of the air in the droplet equation of motion, which includes the aerodynamic and gravitational forces. The turbulence is modeled by a k-? model. The interaction effects between the turbulence and the dispersed droplets are also taken into account. The effects of the turbulence on the droplets are modeled by a fluctuating component added to the local air velocity in the droplet equation of motion. The effects of the droplets on the turbulence are modeled by two extra terms in the ...
Neutron powder diffraction and magnetometric studies of the HoRh_2_-_xPd_xSi_2 series of solid solutions (x=0, 0.5, 0.75, 1.0, 1.5, 1.8) are reported. The intermetallics investigated crystallize in the body-centred-tetragonal ThCr_2Si_2-type structure (space group I4/mmm). All the samples order antiferromagnetically at low temperatures. For low values of the dilution parameter x a simple collinear antiferromagnetic structure of the AFI type is stable. Below T_N the magnetic moments are parallel to the c-axis and then, below T_t, deflect forming an angle #psi# with the c-axis. Further replacement of Rh by Pd results in the development of a sine-wave-modulated magnetic structure with one two-component propagation vector and magnetic moments in the basal plane. For x=1.8 a sine-wave-modulated structure similar to that reported for HoPd_2Si_2 (i.e. with a two-component propagation vector and magnetic moments parallel to the b-axis) was found. (author)
Five cycles of loading, elution, and regeneration were performed to remove technetium from a Hanford waste sample retrieved from Tank 241-AW-101 using SuperLig 639 resin. The waste sample was diluted to 4.95 M Na plus and then was processed to remove 137Cs through dual ion exchange columns each containing 15 mL of SuperLig 644. To remove 99Tc, the cesium decontaminated solution was processed downwards through two ion exchange columns, each containing 12 mL of SuperLig 639 resin. The columns, designated as lead and lag, each had an inside diameter of 1.45 cm and a height of 30 cm. The columns were loaded in series, but were eluted and then regenerated separately. The average technetium loading for the cycles was 250 BV at 10 percent breakthrough. There was no significant difference in the loading performances among the five cycles. The percent removal of 99Tc was greater than 99.94 percent and the average decontamination factor (DF) was approximately 1.7 x 103. ...
Micronutrient deficiencies in flooded rice have been recognized with increasing frequency in recent years. Zinc deficiency is the most widespread disorder, followed by Fe, Mn, and Cu deficiencies. Boron and Mo deficiencies have not been reported in field culture. The peculiar characteristics of a flooded soil are: 1) a layer of standing water; 2) absence of oxygen; 3) a soil profile largely in a reduced chemical state; 4) the presence of large biological carbon dioxide excesses; 5) the presence of high concentrations of soluble Fe"+"+ and Mn"+"+; 6) alteration of soil pH; 7) the presence of toxic substances; 8) increased soluble Na"+, K"+, Ca"+"+, Mg"+"+, NH_4"+, HCO_3"-, H_2PO_4"-, and Si(OH)_4 in the soil solution. Micronutrient availability in flooded soils is affected by: 1) increased solubility of relatively insoluble minerals due to dilution effects; 2) pH changes in relation to solubility and plant availability; 3) changes in oxidation-reduction equilibria; ...
To systematically analyze the dynamical implications of the matter content in cosmology, we generalize earlier dynamical systems approaches so that perfect fluids with a general barotropic equation of state can be treated. We focus on locally rotationally symmetric Bianchi type IX and Kantowski-Sachs orthogonal perfect fluid models, since such models exhibit a particularly rich dynamical structure and also illustrate typical features of more general cases. For these models, we recast Einstein's field equations into a regular system on a compact state space, which is the basis for our analysis. We prove that models expand from a singularity and recollapse to a singularity when the perfect fluid satisfies the strong energy condition. When the matter source admits Einstein's static model, we present a comprehensive dynamical description, which includes the qualitative asymptotic behavior, of models in the neighborhood of the Einstein model; the results refute earlier claims about ...
The AC susceptibility of La_xNd_1_-_xF_3 single crystals, for 0#<=#x#<=#0.1, has been measured from 1.5 up to 40 K and their DC susceptibility for 0#<=#x#<=#1 has been measured from 3 up to 300 K in magnetic fields up to 0.2 T. In both susceptibilities the magnetic fields were applied parallel to the crystallographic a-axis (perpendicular to the c-axis). The effective Bohr magneton number p_e_f_f and paramagnetic Curie temperature #theta#_p have been obtained, using the Curie-Weiss law in the temperature range 100-300 K. Also the g-values corresponding to the five Kramers doublets in the "4I_9_/_2 ground multiplet of Nd"3"+ ion in La_xNd_1_-_xF_3 have been determined in the direction perpendicular to the c-axis, using the Van Vleck theory of paramagnetic susceptibility. The effect of the dilution of the paramagnetic Nd"3"+ ions with diamagnetic La"3"+ ions is also discussed. (orig.).
Motivated by recent experiments on KIF1A, a representative member of single-headed kinesin motor proteins family, we develop a theoretical model of intra-cellular transport by mutually interacting molecular motors. The model explicitly accounts not only for the hydrolysis of ATP, but also for the ratchet mechanism which is believed to drive each individual KIF1A motor. We study the model by a combination of analytical and numerical techniques. A remarkable feature of this model is that all the parameters in it can be completely evaluated from experimental data. Our results in the dilute limit are in excellent quantitative agreement with the empirical data from single molecule experiments. In the high density regime the predictions of the model also agree qualitatively with the corresponding experimental observations. We derive a phase diagram that shows the influence of hydrolysis and Langmuir kinetics on the collective spatio-temporal organization of the motors. ...
Micron scale silicon nitride (SiNx) microdisk optical resonators fabricated on a silicon wafer are demonstrated with Q = 3.6 x 10^6 (finesse = 5 x 10^4) and an effective mode volume of 15 (\\lambda / n)^3 at wavelengths \\lambda ~ 852 nm resonant with the D2 transition manifold of cesium. A dilute hydrofluoric wet etch is shown to provide sensitive tuning of the microdisk optical resonances, and robust mounting of a fiber taper provides efficient fiber optic coupling to the SiNx microdisk cavities while allowing unfettered optical access for laser cooling and trapping of atoms. Initial measurement of a hybrid atom-cavity chip indicates that cesium adsorption on the surface of the SiNx microdisks results in significant red-detuning of the disk resonances. A technique for parallel integration of multiple (10) microdisks with a single optical fiber taper is also demonstrated.
Using a syngeneic p53-null mouse mammary gland tumor model that closely mimics human breast cancer, we have identified, by limiting dilution transplantation and in vitro mammosphere assay, a Lin(-)CD29(H)CD24(H) subpopulation of tumor-initiating cells. Upon subsequent transplantation, this subpopulation generated heterogeneous tumors that displayed properties similar to the primary tumor. Analysis of biomarkers suggests the Lin(-)CD29(H)CD24(H) subpopulation may have arisen from a bipotent mammary progenitor. Differentially expressed genes in the Lin(-)CD29(H)CD24(H) mouse mammary gland tumor-initiating cell population include those involved in DNA damage response and repair, as well as genes involved in epigenetic regulation previously shown to be critical for stem cell self-renewal. These studies provide in vitro and in vivo data that support the cancer stem cell (CSC) hypothesis. Furthermore, this p53-null mouse mammary tumor model may allow us to identify new ...
Natural sunlight induces a genotoxic response in cultured CHO cells pre-treated with shale oil retort process water. Near ultraviolet light (NUV) component of the solar spectrum is the apparent radiation responsible for photoactivation. Cultured human skin fibroblasts are acutely sensitive to the genotoxic effects of photoactivated process water. The mutagenic potential of photoactivated process water in human cells is the same as that witnessed for an equivalent killing dose of the potent skin carcinogen FUV. DNA repair processes are involved in modulating genotoxic effects of this photo-induced process. The exact magnitude of the potential health-related and environmental risks resulting from photoactivation of retort process waters and other oil shale by-products is unassessed at this time. Our demonstration that a significant rate of mutation occurs in cultured human cells exposed to high dilutions of process waters and fluences of NUV comparable to that ...
A fully quantized many-particle theory of the standard free-electron laser in the small-signal, cold-beam regime is presented. The approach is based on an evaluation of the time-evolution operator in the interaction picture to first order in the quantum-mechanical recoil. For algebraic convenience we use the moving (Bambini-Renieri) frame, in which resonance occurs for zero electron momentum. Though we neglect space-charge effects, genuine many-particle contributions still show up, because the radiation emitted by one electron can be amplified by another electron. Our main results are gross features of the amplification, such as gain and spread, are virtually without many-particle effects. These effects are mainly important in the case of spontaneous emission. For a sufficiently high current, the buildup of the laser field from vacuum is enhanced by amplified spontaneous emission. Incoherence of the spontaneous radiation from several electrons induces deviations from Poisson statistics ...
Forty samples of medicinal plants (Peumus boldus, Camellia sinensis, Maytenus ilicifolia and Cassia angustifolia), purchased from pharmacies and street market in the five cities of Sao Paulo State, were irradiated using a "6"0Co gamma ray source (Gammacell) with a dose of 10.0 kGy, delivered at dose rate of 3.0 kGy/h. Nonirradiated samples were used as controls of fungal isolates. For fungal counts and identification in medicinal plants a serial dilutions from 10"-"1 to 10"-"6 of the samples were seeded in duplicates and plated using the method in Dichloran 18% Glycerol Agar (DG 18) and were counted after five days at 25 deg C. Mycological analysis of control samples revealed the presence of genera Aspergillus and Penicillium, which are known as toxigenic fungi. The process of gamma radiation was effective in reducing the number of colony forming units (cfu/g) in all irradiated samples of medicinal plants after 30 days, using the dose of 10.0 kGy and kept of veiled ...
Inductively coupled fluorocarbon (CF4/Ar and C4F8/Ar) plasmas were used to etch HfO2, which is a promising high-dielectric-constant material for the gate of complementary metal-oxide-semiconductor devices. The etch rates of HfO2 in CF4/Ar plasmas exceeded those in C4F8/Ar plasmas. The tendency for etch rates to become higher in fluorine-rich (high F/C ratio) conditions indicates that HfO2 can be chemically etched by fluorine-containing species. In C4F8/Ar plasmas with a high Ar dilution ratio, the etch rate of HfO2 increased with increasing bias power. The etch rate of Si, however, decreasd with bias power, suggesting that the deposition of carbon-containing species increased with increasing the power and inhibited the etching of Si. The HfO2/Si selectivity monotonically increased with increasing power, then became more than 5 at the highest tested bias power. The carbon-containing species to inhibit etching of Si play an important role in enhancing the HfO2/Si ...
The distribution of environmental tritium and the correlation coefficients between tritium concentrations in several environmental samples and the emissions of tritiated water vapor from Wolsong NPP 1 were studied. The annual mean concentrations of atmospheric HTO were in the range 1#centre dot#31-29#centre dot#2 Bq m"-"3 and the long-term atmospheric dilution factors were in the range 10"-"7-10"-"6 s m"-"3. Annual mean concentrations of tritium in ground water were in the range 19#centre dot#2-27#centre dot#9 Bq l"-"1 at N-1 and 64#centre dot#1-189 Bq l"-"1 at S-2, and were generally less than 0#centre dot#2% of MPC_w (222 kBq l"-"1). The concentrations of tritium in precipitation decreased exponentially with distance from Wolsong NPP 1, falling to current global levels at about 25 km off-site. The highest concentration of tritium in soil moisture was observed in May and June, when the relative humidity was high. The concentrations of tritium in soil moisture were ...
An experimental investigation was conducted to evaluate the effect of three different oxygenated compounds, diglyme, diethyl maleate and dibutyl maleate, on emissions from a Volkswagen 1.9 litre, turbocharged, direct injection diesel engine. Sampling was performed using a mini-dilution tunnel technique to obtain particulate matter and a Fourier transform infrared (FTIR) spectrometer for gaseous emissions. The particulate samples were analysed using thermal analysis and Soxhlet extraction to determine the fraction of volatile and soluble organic material respectively. All three oxygenated compounds were found to be effective at reducing particulate emissions, with the maleate compounds being more effective overall than the diglyme. Analysis of the relative contributions of changes in the soot and soluble organic fraction (SOF) to the reduction of particulate matter indicated that, for diethyl maleate and diglyme, reductions in soot were the dominant effect. No ...
This project will determine whether electrolytic dialysis has promise in the separation of charged particles in an aqueous solution. The ability to selectively move ions from one aqueous solution to another through a semipermeable membrane will be studied as a function of emf, amperage, and particle electrical charge. The ions selected for the study are Cl{sup -} and SO{sub 4}{sup 2-}. These ions are of particular interest because of their electrical conduction properties in aqueous solution resulting with their association with the corrosive action of metals. The studies will be performed with commercial membranes on solutions prepared in the laboratory from reagent salts. pH adjustments will be made with dilute reagent acid and base. Specific objectives of the project include testing a selected membrane currently available for electrolytic dialysis, membrane resistance to extreme pH conditions, the effectiveness of separating a mixture of two ions selected on the ...
The uptake and incorporation of (/sup 3/H)adenine as a measure of total microbial (bacteria and unicellular algae) nucleic acid synthesis depends on the validity of several assumptions. A unique characteristic of the (/sup 3/H)adenine method is the ability to measure the specific radioactivity (nCi pmol/sup -1/) of the immediate precursor pool of the adenine incorporated into nucleic acids. This measurement permits correction for isotope dilution when the added radiotracer mixes with exogenous pools of structurally related compounds before uptake and with endogenous pools after transport into the cells. The immediate precursors to (/sup 3/H)adenine incorporation into cellular RNA and DNA are ATP and dATP. Since the intracellular dATP pool is in isotopic equilibrium with the ATP pool, one can determine the specific radioactivity of both precursor pools by measuring that of the intracellular ATP pool. If the specific activity of the precursor pool is not measured, ...
Impurities (Ca, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Ti, Y, Zn and Zr) in sialon powder were determined by the following procedure: A sample (0.5 g) was heated with a mixture of hydrofluoric acid (3 ml) and nitric acid (1 ml) in a Teflon pressure vessel at 170degC for 16 h. The contents of the vessel were transferred into a platinum crucible containing phosphoric acid (4 ml) and heated on a hot plate until the opaque appearance of the content changed to a clear-syrupy fluid. The fluid was diluted to 100 ml with water and used for ICP-AES analysis of all impurity elements except K, which was determined by AAS. It was necessary to match closely the matrix concentrations (H_3PO_4, Al and/or Y) of the standard solutions with those of sialon sample solutions for the determination of impurities because of interferences of the matrix components. This method was successfully applied to the determination of impurities in commercial sialon samples. (author).
Determination of americium (Am) is one of the requirements of chemical quality assurance of plutonium (Pu) bearing fuel materials. Though many methods are published for determining Am at picogram to femtogram levels in environmental and biological matrices, yet a few of them are used routinely for Pu based nuclear fuel samples. This paper gives a brief summary of the different analytical methods available and presents results of our experiments on the determination of Am in Pu bearing fuels using gamma spectroscopy. The methods utilizing gamma emissions from "2"4"1Am and Pu isotopes are fast as they do not involve chemical separation of Pu and Am, do not require an accurate knowledge of the efficiency values of the detector systems and are not dependent on the availability of a radiometric standard for "2"4"1Am. In addition, for aged Pu samples containing large amounts of "2"4"1Am, there is no need for dilution and this reduces the volume of analytical radioactive ...
Careful sample preparation and secondary ion mass spectroscopy have been used to characterize arsenic dose loss to the silicon-oxide interface. Using high resolution x-ray photoelectron spectroscopy for microprofiling, we have directly observed the pileup of arsenic at the silicon dioxide-silicon interface. At least half of the pileup is shown to be on the silicon side of the interface in the first monolayer of silicon. Monolayer chemical oxidation and etching are successfully used to profile this pileup in silicon. This pileup contains most of the arsenic dose loss that occurs during transient enhanced diffusion. This result is crucial to correctly model the dose loss and provides physical justification for using a trap/detrap model at the interface, which is necessary to account for the fact that the arsenic surface concentration remains constant during an anneal and the fact that the dose loss is partially reversible. Finally, we have found that normal etching of the oxide in ...
Careful sample preparation and secondary ion mass spectroscopy have been used to characterize arsenic dose loss to the silicon-oxide interface. Using high resolution x-ray photoelectron spectroscopy for microprofiling, we have directly observed the pileup of arsenic at the silicon dioxide-silicon interface. At least half of the pileup is shown to be on the silicon side of the interface in the first monolayer of silicon. Monolayer chemical oxidation and etching are successfully used to profile this pileup in silicon. This pileup contains most of the arsenic dose loss that occurs during transient enhanced diffusion. This result is crucial to correctly model the dose loss and provides physical justification for using a trap/detrap model at the interface, which is necessary to account for the fact that the arsenic surface concentration remains constant during an anneal and the fact that the dose loss is partially reversible. Finally, we have found that normal etching of the oxide in ...
The aim of this study was to search for a sorbent that could act as an extraction phase and as a support for solid-matrix time-resolved luminescence (SMTRL). Four potential sorbents were investigated for this purpose using tetracycline (TC) as a model analyte. Sorbents prepared from C18 silica gel or calcium cross-linked pectin gel were able to extract TC from dilute solutions. Europium(III)-TC complex adsorbed on the surface of C18 generated the most intense TRL signal when measured at {lambda}{sub ex} = 388 nm and {lambda}{sub em} = 615 nm. This method achieved a 1 ng/ml limit of detection (LOD) with a 100 {mu}l sample solution in a repeated spotting mode. Hyphenation of sorbent extraction and SMTRL was demonstrated using C18. This method is suitable for screening of TC in foods or aqueous solutions and can be extended to other luminescent lanthanide-chelating analytes in physiological or environmental samples.
A process model was used to better understand the controls on the chemical evolution of drainage in a historic mining district. At the Pecos Mine Operable Unit, New Mexico, drainage near the waste rock pile is acidic (pH varies from 3.0--5.0) and carries high concentrations of Zn, Al, Cu and Pb. As drainage flows toward the Pecos River, pH increases to greater than 7 and heavy metal content decreases. A process model of natural attenuation in this drainage shows the main controls on pH are reaction with a local bedrock that contains limestone, and concurrent mixing with tributary streams. Models that account for both calcite dissolution and mixing reproduce the observed decrease in aqueous metal concentrations with increasing pH. Contaminant concentrations attenuate primarily via two distinct pathways: Al, Cu, Fe and Pb precipitate directly from solution, whereas Zn, Mg, Mn and SO{sub 4} concentrations decrease primarily through dilution. Additionally, Pb adsorbs ...
With "1"5"1Eu-Moessbauer spectroscopy and other methods the complex magnetic properties of Eu_2PdSi_3, arising from the two crystallographically different lattice sites of the Eu"2"+ ions, have been already studied. Here we study the impact of magnetic dilution of the magnetic Eu"2"+ sites by non-magnetic Y"3"+ ions. A previous specific heat study has found reduced magnetic ordering temperatures with strong indication of disorder effects like in magnetic spin glasses. Here we provide from "1"5"1Eu-Moessbauer spectroscopy detailed information of the impact of Y"3"+ substitution on the magnetic properties of the two lattice sites, well distinguishable in the "1"5"1Eu-spectra. Since the substitution of the larger Eu"2"+ ions by the smaller Y"3"+ ions is connected with a lattice contraction, we also applied high pressure to the Eu_2PdSi_3 sample and observed drastic changes in the magnetic properties originating from a valence transition towards Eu"3"+ for one of the ...
Turkey's natural gas (NG) production is very small and is almost all imported. Turkish natural gas production in 2000, 23 billion cubic feet (Bcf), met around 4% of domestic natural gas consumption requirements. NG consumption is estimated at around 700 Bcf in year 2002, accounting for around 17% of Turkey's total energy consumption. Turkish natural gas demand had been projected to increase extremely rapidly in coming years. Country oil production is 50,674 barrels per day (bbl/d) of which 46,674 bbl/d was crude oil in 2002. In 2002, oil consumption was 635,000 bbl/d and net oil imports was 584,326 bbl/d in Turkey. Oil provides around 43% of Turkey's total energy requirements. (Author)
This article describes how a natural gas-fired combined cycle with increased firing temperature, reduced cooling air usage, improved component efficiencies, and cycle enhancements could achieve a lower heating value plant efficiency of greater than 60%. Today's gas turbine systems feature high fuel-to-electricity efficiencies. Efficiencies, on a lower-heating-value (LHV) basis, for large natural gas-fired combined-cycle systems for the utility market have been demonstrated at 54%. Even though manufacturers will make improvements in the 1990s, efficiency levels will reach a plateau. Cycle innovations and gas turbine design changes will achieve LHV efficiencies in the 60% range for natural gas-fired utility machines.
A new process for the removal of tar from biosyngas, OLGA (Oil and Gas Washer), is presented. This gas cleaning technology is based on physical principles and is designed to eliminate tar problems that relate to fouling and er pollution. The applied principles are confirmed by experimental validation. OLGA can be operated without suffering from harmful effects on important gasification characteristics as cold gas efficiency, gasifier simplicity, and feedstock flexibility. Some fundamental considerations in the development of OLGA are discussed. Amongst these is a different approach to the tar problem. This approach does not consider the total tar content as decisive in the evaluation of gas cleaning equipment. Instead, evaluation is focussed on whether tar properties as condensation behaviour and water solubility can still occur. A biosyngas free of tar should therefore be synonymous to a biosyngas that ...
Gas separation membranes with polydimethylsiloxane(PDMS)/polystyrene(PS) were prepared by using the sequential interpenetrating polymer network (IPN) method with various PS contents (10?70wt%). These gas separation membranes can be applied to reduce the smoke density in the emission gas of diesel engines. PS content has a pronounced effect on the membrane performance. It was found that the optimized PS contents in the final membrane were 50wt%. The emission capacities of diesel engines used in this study were 632 cc and 11,149 cc. When the oxygen separation membrane was used in the diesel engines, the smoke density of both diesel engines was remarkably reduced (35?73%). The oxygen concentration in the inlet air affects the composition of the emission gases. Especially, hydrocarbon (HC) dec...
Thailand's demand for gas will outstrip supplies in the late 1990s as rapid economic growth continues. Gas will be a cornerstone for Thai energy policy throughout the growth, although sources in neighboring countries need development. Thai gas production will rise 25% from 1992 to average 1 bcfd by 1995. Including production from new discoveries, production could rise to 1.5 bcfd by 2000, up almost 90% from the 1992 level. Increased gas flow output in the mid-1990s will be due largely to development of Gulf of Thailand fields. By 1998, production from Gulf of Thailand fields will not be enough to offset the decline in today's fields. Thailand will need to import more than 1 bcfd by 2005 in the absence of future discoveries in the country. The paper discusses new pipelines and imports.
The ElectroStatic Precipitator (ESP) removes dust and tar droplets very efficiently from biomass product gas. Dust was removed for more than 99%. The tar dewpoint was reduced from 130C to 21C, which is sufficient for the application of the product gas in a gas engine. Tar removal is not sensitive to the voltage or fluctuations in the gas residence time . The voltage was varied between 28 to 37 kV{sub arith} and the gas residence time between 4 and 11s. Fouling of the ESP collector plates was negligible, which was concluded from visual inspection after 200 hours of operation. A reduction in the residence time reduces the size of the ESP and has a significant impact on the investment costs of the ESP. Keywords: electrostatic filter, tar removal, circulating fluidised bed (CFB)
The authors report the fabrication and characterization of a low temperature (200--400 C) thin film gas sensor constructed from a MOCVD-grown yttria-stabilized zirconia (YSZ) layer sandwiched between two platinum thin film electrodes. A reproducible gas-sensing response is produced by applying a cyclic voltage which generates voltammograms with gas-specific current peaks and shapes. Growth conditions are optimized for preparing YSZ films having dense microstructures, low leakage currents, and maximum ion conductivities. In particular, the effect of growth temperature on film morphology and texture is discussed and related to the electrical and gas-sensing properties of the thin film sensor device.
A survey was undertaken of literature on the conversion of coke-fired cupola furnaces so that they can be fuelled, either wholly or partially, with natural gas. The aim was to determine the most suitable method for a specific furnace. Substitution with natural gas can result in speedier adjustment and control of the smelting process and in addition operational costs are reduced as natural gas is a cheaper fuel. The payback period would be one year. Pollutive emissions would be reduced. It was concluded that the most satisfactory solution would be that 3-4 gas burners should be placed immediately above the smelting zone in the furnace. Each burner should be placed in a separate combustion box in which the complete combustion process could take place. The burners should be placed symmetrically about the furnace, pointing at a small degree downwards. In this way the combustion chamber will not be filled ...
In this paper, the authors investigate the technical and economical aspects of the natural gas injection in non-integrated pig-iron plants using charcoal in the blast furnace. The effects of the natural gas injection concerning the blast furnace flame temperature, charcoal consumption, productively and permeability are analyzed. It was found that the injection is beneficial in many ways, such as in the improvement of the productivity and quality, if the flame temperature is kept within an appropriate range. In the financial-economic project`s evaluation, the cash flow for the natural gas injection was analysed considering two blast conditions: through the drying and oxygen enrichment of the air. A sensibility analysis is presented in which the internal rate of return of the investment varies according to the prices of charcoal and oxygen. 3 refs., 3 figs., 3 tabs
The majority of Brazilian big cities served by conventional railroad systems with routes starting in the center of the URBIS, destinate them the long distances transport of passengers and cargo. Actually, these systems are being transformed to become commuter trains which join a great capacity of transportation to a much lower costs of implantation than subway ones. The most important characteristic of this train, when talking about energy consumption, is the possibility of using different kinds of explosion engines from three cycles: Diesel, mixed (Diesel + Natural Gas), and Otto moved by natural gas, besides the traditional electric traction. The use of natural gas in Otto cycle engines shows itself competitive from the point of view of investments, operational costs and environmental preservation. (author). 10 refs., 1 fig
Lean premixed combustion (LPC) of natural gas is of considerable interest in land-based gas turbines for power generation. However, modeling such combustors and adequately addressing the concerns of LPC, which include emissions of nitrogen oxides, carbon monoxide and unburned hydrocarbons, remains a significant challenge. In this paper, characteristics of published simulations of gas turbine combustion are summarised and methods of modeling turbulent combustion are reviewed. The velocity-composition PDF method is selected for implementation in a new comprehensive model that uses an unstructured-grid flow solver. Reduced mechanisms for methane combustion are evaluated in a partially stirred reactor model. Comprehensive model predictions of swirl-stabilised LPC of natural gas are compared with detailed measurements obtained in a laboratory-scale combustor. The model is also applied to industrial combustor ...
Remote, offshore gas reserves have long been a challenging deepwater petroleum resource to tap. Natural gas in many offshore regions is plentiful, but lacks access to the market because of the logistical challenges and costs. Most large offshore gas discoveries are capped, and gas associated with oil production is re-injected into the reservoir or is flared. A more attractive option is to convert the gas into a liquid product on a floating production, storage, and offloading (FPSO) vessel. However, some conventional process technologies are not well suited for operation on floating vessels that are highly space and weight constrained and may challenge vessel stability during inclement weather. Microchannel process technology units under development offer intensified processes that are suit...
In this paper it will be discussed how to most effectively give room to competitive forces in natural gas markets, given the traditional merchant pipeline as point of departure. Alternative models of organizing the market will be reviewed: we first consider decreasing barriers to entry and then analyse advantages and drawbacks of a third party access system. In this context different forms of implementing a competitive market for transportation capacity and coordinating it with gas trade are discussed, among them a simultaneous auction of gas and transmission capacity. Finally a hub system of point markets will be suggested to improve the currently implemented third party access system and to allow for competitive markets for gas and transportation service. 33 refs., 6 figs.
The Gas Research Institute established the Gas Appliance Technology Center (GATC) in 1982 to develop improved gas appliances. Between 1986 and 1992, the scope of GATC activities at Battelle included technology transfer and overall industry support, residential appliances, commercial appliances, and residential space conditioning. The following tasks are representative of the GATC activities described in the report; gas burner technology, appliance venting, emissions, water heating, range/oven technology, self-powered appliances, commercial cooktop burners, reconstituting ovens, appliance reliability improvement, combination space-heating/water-heating systems, condensing heat exchangers, corrosion testing, and space heating technology. The report includes references to available sources for further reading.
One of the unsolved problems of the natural gas dual fuel engine is that there is too much exhaust of Total Hydrogen Carbon(THC) at a low equivalent mixture ratio. To fix it, a natural gas mixed with hydrogen was applied to engine test. The results showed that the higher the mixture ratio of hydrogen to natural gas, the higher the combustion efficiency. And when the amount of the intake air is reached to 90% of WOT, the combustion efficiency was promoted. But, like a case making the injection timing earlier, the equivalent mixture ratio for the nocking limit decreases and the produce of NOx increases. 5 refs., 9 figs., 1 tab.
AISI 5140 steel was plasma nitrided at various gas mixtures of nitrogen, hydrogen, and argon to investigate the actions of hydrogen and argon on plasma nitriding. The structural and mechanical properties of ion-nitrided AISI 5140 steel have been assessed by evaluating composition of phases, surface hardness, compound layer thickness, and case depth by using X-ray diffraction (XRD), microhardness tests, and scanning electron microscopy (SEM). It was found that the growth of compound layer can be controlled and the diffusion improved when the gas mixture includes H_2 gas. Additionally, it was determined that the amount of Ar in dual gas mixture must be at 20% minimum to obtain distinctive surface hardness and compound layer thickness.
Laboratory tests have been done to assess the feasibility of using microwaves to manufacture refractory liner boards as used in the steel industry. Results show that microwaves cured and dried the product about ten times faster than the conventional gas-oven process. The quality of boards dried with microwaves appears to be as good or better than of those dried with gas. The potential for fast, energy-optimized drying in a small space has been demonstrated. Economically, the energy-cost of using microwaves is comparable to using gas when drying the last 30% moisture content, that is, for about the last 50% of the present gas-drying time. For higher moisture contents, such as encountered in the early stages of drying, the energy can be supplied at a lower cost by gas. 8 figs.
In energy industries, it is always of difficulty to produce high heat value(HHV) gas continuously using pulverized coal. In this paper, a new type furnace for partitioned alternative gasification using pulverized coal is developed, in which the oxidation and reduction reaction occur alternatively with the dropping of pulverized coal and finally HHV gas could be continuously obtained at the reduction zone exit and low heat value(LHV) gas at the oxidation zone exit. Furthermore, the gasification characteristics and their factors in furnace are numerically simulated under two dimensional model with a self-coded program, based on heat, mass and energy transfer as well as reaction principles. It is found that the producing rate of HHV gas is 1.10Nm3/kg with heat value of 11.72MJ/Nm3, however, t...
Various theories and examples of modelling, forecasting and optimization designing in the different parts of the petroleum and gas industries are presented, stochastic programming for long term planning in the refining industry, stochastic model for gasoline blending, feedstock optimization, location and sizing for offshore platforms, hydrocarbon exploration simulation rapid method, valuation of oil field development leases, economic models for petroleum allocation, models for oil supply market, trade embargo game theory, stochastic programming of gas contract portfolio management, scheduling transportation of oil and gas, strategic planning in an oil pipeline company, simulation of offshore oil terminal systems, hierarchical selection of oil and gas distribution systems.
The method is related to hydrodynamic methods for studying wells and may be used in the prospecting and mapping of gas and gas condensate deposits and formations. The method consits of drilling exploratory wells and measurement of the physical parameters of the stratum liquid. The piezometric levels are periodically determined simultaneously in all the observation wells during a change in the atmospheric pressure, and the presence of a remoteness of the gas deposit from the well is judged from the size of the increments in the piezometric levels intime. The determinations of the piezometric levels in the wells are conducted during an abrupt change in atmospheric pressure, for instance, during the replacement of a cyclone by an anticyclone or the reverse. The atmospheric pressure is measured by a barograph, while the piezometric levels are measured by high precision level meters or pressure gauges of low pressure. The method ...
The purpose of this project was to build a long-range, parallel hybrid gas/electric vehicle capable of driving beyond the communter capabilities of series hybrid vehicles. It was envisioned that since the gas engine would be able to independently propel the car when needed and that the electric motor would be capable of doing the same, then you have a very desirable situation where this car can operate much more cheaply on electricity for the short distance runs under approximately 60 miles and also be able to propel the vehicle via the gas engine on the long-distance trips. During the time the car would be operating in the gas engine mode, it would be also recharging the 16 deep cycle batteries via the electric motor now being used as a generator. Then, even on long-distance trips, the electric motor could be used, after having been fully or partially recharged, to even further reduce cost per mile.
Ordos Basin, the second largest sedimentary basin in China, contains enormous natural gas resources. Each of the four giant gas fields discovered so far in this basin (i.e., Sulige, Yulin, Wushenqi and Jingbian) has over 100 billion cubic meters (bcm) or 3.53 trillion cubic feet (tcf) of proven gas reserves. This study examines the stable carbon isotope data of 125 gas samples collected from the four giant gas fields in the Ordos Basin. Source rocks in the Upper Paleozoic coal measures are suggested by the generally high {delta}{sup 13}C values of C{sub 2}-C{sub 4} gaseous hydrocarbons in the gases from the Sulige, Yulin and Wushenqi gas fields. The {delta}{sup 13}C values of methane, benzene and toluene in gases from the Lower Paleozoic reservoirs of the Jingbian field indicate a significant contribution from humic source rocks, as they are similar to those in ...
The productivity characteristics of perforated gas well are investigated for the first time under real conditions considering drilling damage, perforation compacted zone and anisotropy in this paper. A non-linear finite element model for non-Darcy flow in perforated gas reservoir is built to consider the effects of twelve factors on productivity ratio (PR) of perforated gas well. The nomographs for two cases are presented in this paper. Compared with previous works, the following results are found: (1) the effects of drilling damage and perforation diameter on PR of gas well are more remarkable than that in oil well; (2) any perforation phase may be the best or the worst as to perforating gas well, which depends on anisotropy, drawdown and that whether or not perforations are beyond drilling damage zone; (3) the increase in perforation length hardly improve PR of ...
Puffer gas circuit breaker used widely in interrupters with from middle capacity to large capacity does not keep away from reacting force of the puffer with high functions in principle and there is a limit in low operation. In this study, aiming at low operation of the interrupters, in order to clarify the basic motions of hybrid circuit interrupter that is the combination of thermal puffer gas circuit breaker and vacuum circuit breaker, the interrupting ability of simple thermal puffer gas breaker and the voltage sharing characteristics in the cases of series connection with the vacuum circuit breaker are studied. The results of the study are as follows. In comparing terminal short circuit accident interrupting ability of single flow typed thermal puffer gas breaker with that of double flow typed thermal puffer gas breaker, the interrupting ability of the double flow typed thermal ...
Electricity generation from natural gas in gas turbine units can be made substantially more efficient by preliminary methane conversion to a synthesis gas containing hydrogen and carbon monoxide and/or by the use of some of the synthesis gas produced in industry. An alternative improvement involves the introduction of solid oxide fuel cells (SOFCs) and the use of the synthesis gas in them. In this study, a modified scheme of gas turbine cycle that includes an SOFC, a membrane reactor (instead of a traditional combustion chamber), and a catalytic reactor to perform methane conversion to produce hydrogen (synthesis gas) is proposed. Variations of the energy and exergy efficiencies of the integrated system with operating conditions are provided, showing, for example, that SOFC efficiency is enhanced if the fuel cell active area is augmented. ...
A gas injection diesel engine was developed as an approaching measure to the diversification of fuel. Contrary to the usual low pressure gas application engine, this engine applies a so-called diffuse combustion method, in which high pressure (24.7Mpa) gas fuel is injected directly in the cylinder and is ignited and combusted by a little pilot fuel injected almost at the same time. The engine have following features. As a principle, it can attain the same heat efficiency and output rate as a diesel engine in any load range. It is excellent in responsibility to load fluctuation. There is no internal leakage of gas fuel to the scavenging chamber (the crank chamber) in the compression stroke. Not only a wide range of mixed combustion of gas fuel and heavy oil fuel, but also single combustion of heavy oil is possible. It is, therefore, drawing attention as an engine for an LNG ship and ...
The following industrial-scale power station processes are compared with natural gas/light fuel oil heating: Conventional steam generation, steam generation with gas turbine upstream, gas turbine process with low-pressure-waste heat boiler and cogeneration. Industrial gas turbines between 10 and 25 MW are compared with one another; typical boilers and industrial turbines are described. CO{sub 2} and NO{sub x} emissions are indicated. The steam turbines used are the efficient and robust turbines used in industry, wherever possible they are built as single-line plant with the gas turbine. (orig.) [Deutsch] Es werden folgende Industriekraftwerksprozesse mit Erdgas-Leichtoelfeuerung verglichen: Konventioneller Dampfprozess, Dampfprozess mit Vorschaltgasturbine, Gasturbinenprozess mit ND-Abhitzekessel und Kombianlage. Die Industriegasturbinen zwischen 10 und 25 MW werden ...
This conference was attended by decision makers throughout the supply chain in the natural gas industry who face the continuing challenges of changes in market mechanisms, pricing options, and transmission alternatives. It provided an opportunity to review issues affecting producers, shippers, marketers, and end-users in an environment of tight energy markets and high, inelastic demand. The constraints on adequate energy supplies are influenced by economic factors, current and future resources, materials, equipment, skilled labour, technology and financial capital. The 8 sessions of the conference dealt with the tight North American gas supply; the slow development of new supplies; resource access issues, including politics and supply security; the geopolitics of natural gas; impacts of high prices on the North American economy; energy industry impacts of high natural gas prices; domestic politics and ...
In order to establish the optimum fueling in a natural gas fueled dual fuel engine, tests were made for some operational parameters and their combination on the engine performances and the exhaust emissions. The results show that the gas oil quantity should be increased and gas oil injection timing should be advanced to suppress unburned hydrocarbon emission at middle and low output range, while the quantity should be reduced and the timing should be retarded to avoid onset of knock at high loads. The unburned hydrocarbon emission and the thermal efficiency are improved at the same load avoiding too lean natural gas premixture by restriction of intake charge air. However the improvement is limited because the ignition and initial combustion of pilot diesel fuel is deteriorated when the cylinder pressure is excessively lowered by throttling. The increase in pilot gas oil amount is ...
This dissertation concerns a study of the utilization of sorghum biomass as the fuel for a methane production system. The objective of this research is to determine an optimal sorghum-methane production system based on anaerobic batch digestion technology. The system is described as the interaction of three components: estimation of available biomass, storage of biomass, and the gas production. Levelized costs are obtained for each component. The biomass supply is assumed to decay exponentially in quality with storage time. The gas production process is a batch type of digestion with an exponential production rate. Gas production is formulated for a fixed planning horizon (one year) as a function of the number of batches and the batch residence times. The cost equation is then described as a function of these gas production equations and their levelized costs. The structure of this resulting equation is ...
The energy recovery scheme at Mucking Marshes landfill site, operated by Cory Environmental Limited, has been in operation since October 1991. Using landfill gas abstracted from the site, a gas turbine generates up to 3.2 MW net electric power for export. Operation and performance of the scheme has been monitored over the period January 1995 to August 1996. Overall performance since the first use of the turbine has also been studied, and has shown reliable and profitable operation. The capital cost of the gas turbine and gas compressor plant was approximately 1.8 million. Actual gas collection wells, pipework, pumping and monitoring facilities, while essential to the scheme, are considered part of the gas control equipment needed for the landfill site. Based on a notional electricity selling price of 4p/kWh, the current annual income from exported power is ...
In response to the Clean Coal II solicitation, Bethlehem Steel Corporation (BSC) submitted a proposal to the DOE in May 1988. The proposal submitted by BSC describes a Unique integration of commercial technologies developed by Davy/Still Otto to clean coke oven gas being produced at its Sparrows Point, Maryland steel plant. This innovative coke oven gas cleaning system combines secondary gas cooling with hydrogen sulfide and ammonia removal, hydrogen sulfide and ammonia recovery, ammonia destruction and sulfur recovery to produce a cleaner fuel gas for plant use. The primary environmental benefit associated with employing this innovative coke oven gas cleaning system is realized when the fuel gas is burned within the steel plant. Emissions of sulfur dioxide are reduced by more than 60 percent. The removal, recovery and destruction of ammonia eliminates the ...
This study develops a statistical model of industrial US natural gas consumption based upon historical data for the 1958-2003 period. The model specifically addresses interfuel substitution possibilities and changes in the industrial economic base. Using a relatively simple approach, the framework can be simulated repeatedly with little effort over a range of different conditions. It may also provide a valuable input into larger modeling exercises where an organization wants to determine long-run natural gas prices based upon supply and demand conditions. Projections based upon this demand framework indicate that industrial natural gas consumption may grow more slowly over the next 20 yr than being projected by the U.S. Energy Information Administration (EIA). This conclusion is based upon the assumption that natural gas prices will follow oil prices, as they have done over recent decades. If natural ...
As its indigenous gas supplies decline, the UK will need to import more gas. In November 2006, the Department of Trade and Industry issued a consultation on revising the consent regime for offshore gas storage and offshore liquefied natural gas unloading. A total of 27 responses had been received by the closing date of 16 February 2007 from a variety of interest parties including developers and their representative organisations, consultants, environmental organisations, maritime organisations, heritage organisations and other public bodies. This report presents the Government's response to the views expressed by these respondents. The majority of respondents supported the Government's proposals to put in place new legislation to permit offshore gas storage activities. Many believed new legislation was necessary to provide the legal certainty necessary ro encourage ...
The usually low wear resistance of titanium materials can be increased by the thermochemical surface treatment nitriding. In result of comparative investigations of gas and plasma nitriding it will be shown that it is possible to obtain a specific variation of the properties in the highly stressed case by means of these both technologies on example of the ({alpha}+{beta}) alloy Ti-6Al-4V. Gas and plasma nitriding was carried out in the temperature range from 650 to 800 C over 4 to 48 h in different gas atmospheres, i.e. 100% NH{sub 3} (gas), 100% N{sub 2} (gas and plasma), 20% H{sub 2} + 80% N{sub 2} and 20% Ar + 20% H{sub 2} (plasma). The temperature range was fixed in the middle of ({alpha}+{beta}) region, because the core properties are influenced negative in the field of {beta}-transustemperature. The relations between the applied nitriding technologies, the layer structure ...
In our previous work, we demonstrated that biomass-generated producer gas can be converted to ethanol and acetic acid using a microbial catalyst Clostridium carboxidivorans P7{sup T}. Results showed that the producer gas (1) induced cell dormancy, (2) inhibited H{sub 2} consumption, and (3) affected the acetic acid/ethanol product distribution. Results of this work showed that tars were the likely cause of cell dormancy and product redistribution and that the addition of a 0.025{mu}m filter in the gas cleanup negated the effects of tars. C. carboxidivorans P7{sup T} can adapt to the tars (i.e. grow) only after prolonged exposure. Nitric oxide, present in the producer gas at 150ppm, is an inhibitor of the hydrogenase enzyme involved in H{sub 2} consumption. We conclude that significant conditioning of the producer gas will be required for the successful coupling of biomass-generated ...
Gas Distribution Companies have long paid great attention to improving the quality of gas supply service to the consumer. This has involved them in an on-going attempt to successfully define and establish a clear computer assisted replacement programme which, when drawn up on a reliability basis, may also prove cost effective. The reasons which drive any gas line replacement programme are mainly related to the necessity: to improve the gas network asset so as to face a striking expected growth in gas demand; to refurbish old distribution systems with the purpose not only to increase the reliability and continuity of gas supply but also to reduce the rate of maintenance costs due to frequent repair works; to prevent the possibility of massive replacement works for a progressing ageing of the network. This paper will present the computer assisted procedure being ...
High and volatile natural gas prices have increasingly led to calls for investments in renewable energy. One line of argument is that deployment of these resources may lead to reductions in the demand for and price of natural gas. Many recent US-based modeling studies have demonstrated that this effect could provide significant consumer savings. In this article we evaluate these studies, and benchmark their findings against economic theory, other modeling results, and a limited empirical literature. We find that many uncertainties remain regarding the absolute magnitude of this effect, and that the reduction in natural gas prices may not represent an increase in aggregate economic wealth. Nonetheless, we conclude that many of the studies of the impact of renewable energy on natural gas prices appear to have represented this effect within reason, given current knowledge. These studies specifically ...
High and volatile natural gas prices have increasingly led to calls for investments in renewable energy. One line of argument is that deployment of these resources may lead to reductions in the demand for and price of natural gas. Many recent US-based modeling studies have demonstrated that this effect could provide significant consumer savings. In this article we evaluate these studies, and benchmark their findings against economic theory, other modeling results, and a limited empirical literature. We find that many uncertainties remain regarding the absolute magnitude of this effect, and that the reduction in natural gas prices may not represent an increase in aggregate economic wealth. Nonetheless, we conclude that many of the studies of the impact of renewable energy on natural gas prices appear to have represented this effect within reason, given current knowledge. These studies specifically ...
This contribution presents different approaches for the modeling of gas entrainment under water by a plunging jet. Since the generation of bubbles happens on a scale which is smaller than the bubbles, this process cannot be resolved in meso-scale simulations, which include the full length of the jet and its environment. This is why the gas entrainment has to be modeled in meso-scale simulations. In the frame of a Euler-Euler simulation, the local morphology of the phases has to be considered in the drag model. For example, the gas is a continuous phase above the water level but bubbly below the water level. Various drag models are tested and their influence on the gas void fraction below the water level is discussed. The algebraic interface area density (AIAD) model applies a drag coefficient for bubbles and a different drag coefficient for the free surface. If the AIAD model is used for the simulation ...
The overall goal of the Gas-to-Liquids Program at the U.S. Department of Energy`s Pittsburgh Energy Technology Center (PETC) is to develop technologies for the production of hydrocarbon fuels and premium chemicals from light alkane gases. PETC`s current Gas-to-Liquids Program comprises the development of four primary advanced conversion technologies, namely, partial oxidation, oxidative coupling, oxyhydrochlorination, and novel conversion processes. Based on the current state of development, it can be concluded that, in the near future, one or more of these technologies will reach proof-of-concept demonstration. Oxyhydrochlorination is the most advanced direct conversion technology, and the synthesis of lower cost methyl chloride from natural gas would impact several commercial technologies that utilize methyl chloride as an intermediate to high value products. Technology development for the partial oxidation of methane to ...
Calgary-based TAG Oil is an exploration company that manages 4.1 million acres of major producing oil and gas fields in New Zealand. The enormous Maui field, with 4 tcf of natural gas in place, has dominated the gas market in New Zealand by meeting nearly 90 per cent of the country's energy demand at costs much lower than world prices. However, the maturing field is in decline and will cease production by 2008. New gas field discoveries will only meet 60 per cent of the country's energy requirements for 5 additional years. Unless new large reserves of gas are discovered, the supply and demand situation will get worse. Lead time to place new production on-stream requires 5 to 10 years, which creates a large supply gap over the next decade. Public resistance to coal-fired power plants, new hydroelectric dams and nuclear power has left the country with no viable alternative to natural ...
A case study of a hypothetical offshore production fixed leg platform facility is presented. The purpose of the case study is to demonstrate the advantages offered by modern, fuel efficient large gas turbines in central power generation service for offshore production. The case study was presented using the Rolls- Royce RB211 large gas turbine with facility production of approximately 240,000 BPD of oil and 540 MMSCFD of associated gas. The gas was subjected to three stages of separation for removal of hydrocarbon liquids and water. The liquids, natural gas, and crude oil were exported from the production platform to an onshore receiving terminal. Gas compression is the service that requires the greatest amount of power for any given production facility. For this case study, gas compression represented approximately 70 per cent of the power ...