The aim of this study was to investigate the photodegradation of the antiemetic drug metoclopramide. Metoclopramide aqueous solutions were photoirradiated at 254nm under argon atmosphere. Irradiated metoclopramide solutions were analyzed by high performance liquid chromatography-iontrap mass spectrometry in order to characterize photolysis products. Rapid decrease in metoclopramide purity, following first-order kinetic, was observed following irradiation. The structures of 18 photolysis products were tentatively identified based on their mass spectra and fragmentation. The main degradation mechanism was scission of the chlorine which could be followed by polymerization of the resulting products since dimeric and trimeric products were observed.
The objective of this report is to review the different technologies for trapping the gaseous wastes containing Cs, Ru, Tc, {sup 14}C, Kr, Xe, I and {sup 3}H from a voloxidation process. Based on literature reviews and KAERI's experimental results on the gaseous fission products trapping, appropriate trapping method for each fission product has been selected considering process reliability, simplicity, decontamination factor, availability, and disposal. Specifically, the most promising trapping method for each fission product has been proposed for the development of the INL off-gastrapping system. A fly ash filter is proposed as a trapping media for a cesium trapping unit. In addition, a calcium filter is proposed as a trapping media for ruthenium, technetium, and {sup 14}C ...
Questions are examined of prospecting for nonanticlinical traps within North Sakhalin, their spatial distribution and evaluation of the outlook for oil and gas content. Traps of tapering and facial substitution on wings and periclines of local elevations, accumulative bar and erosion-accumulative channel are isolated. THe hypothesis is made that it is possible to form stratigraphic traps above the discrepancy and below it. It is noted that formation of zones of lithological tapering and facial substitution are associated with areas of the exchange of the sedimentation situation. The primary role of the shore and coastal zones in the formation of the examined types of nonanticlinal traps is established. The Okhino-Ekhabinskiy region in North Sakhalin is isolated as the primary object for prospecting for nonanticlinal traps.
From the alkalised crude extract of Symphytum cordatum (L.) W.K. roots, pyrrolizidine alkaloids (PAs) were extracted as free tertiary bases and polar N-oxides in a merely one-step liquid-liquid partitioning (LLP) in separation funnel and subsequently pre-fractionated by preparative multiple-development (MD) thin-layer chromatography (TLC) on silica gel plates. In this way three alkaloid fractions of different polarities and retention on silica gel plates were obtained as: the most polar N-oxides of the highest retention, the tertiary bases of medium retention, and diesterified N-oxides of the lowest retention. The former fraction was reduced into free bases by sodium hydrosulfite and purified by LLP on Extrelut-NT3 cartridge. It was further analysed together with the two other fractions by high-performance liquid chromatography (HPLC)-ion-trap mass spectrometry with atmospheric pressure chemical ionization (APCI) interface on XTerra C{sub 18} column using a ...
A water trap system based on a thermoelectric cooling device is employed to remove a major fraction of the water from air samples, prior to analysis of these samples for chemical composition, by a variety of analytical techniques where water vapor interferes with the measurement process. These analytical techniques include infrared spectroscopy, mass spectrometry, ion mobility spectrometry and gas chromatography. The thermoelectric system for trapping water present in air samples can substantially improve detection sensitivity in these analytical techniques when it is necessary to measure trace analytes with concentrations in the ppm (parts per million) or ppb (parts per billion) partial pressure range. The thermoelectric trap design is compact and amenable to use in a portable gas monitoring instrumentation.
Artificial neural network analysis is found to be far superior to multiple regression when applied to the evaluation of trap quality in the Northern Kuqa Depression, a gas-rich depression of Tarim Basin in western China. This is because this technique can correlate the complex and non-linear relationship between trap quality and related geological factors, whereas multiple regression can only describe a linear relationship. However, multiple regression can work as an auxiliary tool, as it is suited to high-speed calculations and can indicate the degree of dependence between the trap quality and its related geological factors which artificial neural network analysis cannot. For illustration, we have investigated 30 traps in the Northern Kuqa Depression. For each of the traps, the values of 14 selected geological factors were all known. While geologists were also ...
Decontamination and decommission activities related to the Molten Salt Reactor Experiment (MSRE) involve the trapping and recovery of radiolitically generated uranium hexafluoride and fluorine. Although fission product radiolysis was known to generate F{sub 2}, the formation of UF{sub 6} and its transport from the fuel salt was unexpected. Some of these gaseous radiolysis products have been moving through the gas piping to a charcoal bed since the reactor was shut down in 1969. Current and planned remediation and clean-up activities involve the trapping of the gaseous products, deactivation and treatment of the activated charcoal bed, stabilization and reconditioning of the fuel salt, and recovery of the uranium. The chemical aspects of these processes, including radiolytic generation mechanisms, reactions between uranium hexafluoride and fluorine and trapping materials such as activated charcoal, ...
The Fast Flux Test Facility (FFTF) is a 400-MWt, sodium-cooled reactor located on the Hanford Site near Richland, Washington, USA. The FFTF is owned by the U.S. Department of Energy and is operated by the Westinghouse Hanford Company. The FFTF was designed to test fuels and materials for use in liquid metal reactors. Since initial operation in 1982, anticipated breaches of experimental fuel pins have released fission products, including cesium, into the primary sodium. Because of its high volatility, cesium vaporizes into the cover gas space, where it condenses on components and equipment and is transported into the cover gas outlet. Because of the long half-life of "1"3"7Cs, these deposits result in long-term, local radiation levels that make contact maintenance difficult. Thus, a cesium trap was installed in FFTF to reduce the cesium level in the sodium. The trap could also permit a Run Beyond ...
A dispersion interferometer based on CO2 laser for measurements of plasma line density in the gas dynamic trap (GDT) experiment has been developed with sensitivity el>min ? 1.1013 cm-2, temporal resolution ?50 ns. The main advantages of the interferometer are compactness and low sensitivity to vibrations. The interferometer does not require specific vibration isolation structure and can be mounted directly on the working chamber of the plasma device. The above mentioned advantages have been successfully demonstrated in the Gas Dynamic Trap experiments.
The possibility of employing a number of adsorbents (polyphenylquinoxaline, Tenax GC, Carbopak C, graphitized thermal carbon black, silica gels modified with pyrocarbon or hexamethyldisilazane) for the trapping of organic traces from air has been investigated. Adsorption capacities of these adsorbents with respect to a number of volatiles released from certain plastics used as building material (polyvinylchloride, Relin, Acronal, etc.) have been measured. A number of the volatiles were identified by gas chromatography - mass-spectrometry after trapping on the adsorbents investigated. Chromatographic separation after trapping on the adsorbents was carried out on wall-coated open-tubular capillary columns as well as in capillary columns packed with graphitized thermal carbon black.
The Mississippi Office of Geology has conducted field trials using the surface exploration techniques of geomicrobial, radiometrics, and free soil gas. The objective of these trials is to determine if Mississippi oil and gas fields have surface hydrocarbon expression resulting from vertical microseepage migration. Six fields have been surveyed ranging in depth from 3,330 ft to 18,500 ft. The fields differ in trapping styles and hydrocarbon type. The results so far indicate that these fields do have a surface expression and that geomicrobial analysis as well as radiometrics and free soil gas can detect hydrocarbon microseepage from pressurized reservoirs. All three exploration techniques located the reservoirs independent of depth, hydrocarbon type, or trapping style.
The ground state of a three-dimensional (3D) rotating trapped superfluid Fermi gas in the BCS-BEC crossover is mapped to finite N v -body vortex states by a simple ansatz. The total vortex energy is measured from the ground-state energy of the system in the absence of the vortices. The vortex state is stable since the vortex potential and rotation energies are attractive while the vortex kinetic energy and interaction between vortices are repulsive. By combining the analytical and numerical works for the minimal vortex energy, the 2D configurations of N v vortices are studied by taking into account of the finite size effects both on xy-plane and on z-direction. The calculated vortex numbers as a function of the interaction strength are appropriate to the renew experimental results by Zwier...
We study the thermodynamics of a one-dimensional attractive Fermi gas (the Gaudin-Yang model) with spin imbalance. The exact solution has been known from the thermodynamic Bethe ansatz for decades, but it involves an infinite number of coupled nonlinear integral equations whose physics is difficult to extract. Here the solution is analytically reduced to a simple, powerful set of four algebraic equations. The simplified equations become universal and exact in the experimental regime of strong interaction and relatively low temperature. Using the new formulation, we discuss the qualitative features of finite-temperature crossover and make quantitative predictions on the density profiles in traps. We propose a practical two-stage scheme to achieve accurate thermometry for a trapped spin-imbalanced Fermi gas.
SiC has been considered as a primary candidate material for a first wall component in future fusion reactor because it has been claimed that SiC has excellent high-temperature properties, good chemical stability and low activation. However, the behavior of tritium on SiC has not been discussed yet. In this study, tritium trapping capacity on the surface of SiC was experimentally obtained at the temperature range of 25-800 deg. C in consideration of tritium trapping to the experimental system. The capacity, which was independent of the water vapor pressure in the gas phase and the temperature, was determined as about 10{sup 6} Bq/cm{sup 2}. The isotope exchange reaction rate between tritiated water in a gas phase and hydrogen on the surface was quantified at the temperature of 25, 500 and 700 deg. C in consideration of the behavior of tritium trapping at change of experimental ...
SiC has been considered as a primary candidate material for a first wall component in future fusion reactor because it has been claimed that SiC has excellent high-temperature properties, good chemical stability and low activation. However, the behavior of tritium on SiC has not been discussed yet. In this study, tritium trapping capacity on the surface of SiC was experimentally obtained at the temperature range of 25-800 deg. C in consideration of tritium trapping to the experimental system. The capacity, which was independent of the water vapor pressure in the gas phase and the temperature, was determined as about 10"6 Bq/cm"2. The isotope exchange reaction rate between tritiated water in a gas phase and hydrogen on the surface was quantified at the temperature of 25, 500 and 700 deg. C in consideration of the behavior of tritium trapping at change of experimental condition by the ...
The TRIGA-SPEC experiment has been installed recently at the research reactor TRIGA Mainz. Ground state properties like masses, charge radii, spins, and moments of short-lived nuclides can be determined with very-high precision using the Penning trap mass spectrometer TRIGA-TRAP, and the collinear laser spectroscopy setup TRIGA-LASER. Short-lived neutron-rich radionuclides in the mass range 80 < A < 140 are produced by thermal neutron induced fission of e.g. U-235, Pu-239 or Cf-249, respectively. For the extraction and ionization of the fission products a gas-jet system is coupled to a 2.45-GHz ECR ion source for the production of singly charged ions. The gas-jet has been tested on-line and fission products have been extracted. First off-line tests of the ion source have been performed successfully with argon gas. The results of the commissioning test of the ion source and the ...
In the food, chemical and safety industry there is a demand for gas detectors for process control applications, like quality control of food or leakage control in chemical plants. Gas sensor array systems have the potential to be used in this areas, with the advantage of being also affordable systems compared to other systems like gaschromatographs (GC) or infrared detectors (NIR, FTIR). One of the main drawbacks of the gas sensors is their response to non interesting ambient factors like temperature, pressure and humidity. Metal oxide sensors (MOS) have a low ambient temperature and pressure dependency. Some of them (SnO + dopands) have some sensitivity to humidity. In many cases the response of the sensors is often non-linear, which implies a concentration dependant pattern of the samples. (orig.)
The report reviews the activity during the fourth year of Gas Research Institute's Gas Appliance Technology Center program. Work on gas appliances involved a conceptual table-top multi-function oven, development of an indirect-fired conveyor oven, and performance comparisons of smooth cooktops. Performance-evaluation methods for commercial ovens were evaluated. Design improvements were made to a direct-fired conveyor oven and a pulse-combustion deep-fat fryer. Performance of common vents were studied, and a device was designed to allow incorporation of appliances with positive vent pressures into such systems. Standards-related work included draft-hood capacities, flexible corrugated-connector corrosion, and sediment trap efficiencies. Heating-related work comprised conceptual design of a vented baseboard heater and a centralized heat-transfer fluid system.
Measurements of the expansion rate of pure-electron plasmas have been performed on the Electron Diffusion Gauge (EDG) device at background helium gas pressures in the 5 x 10(superscript -8) Torr to 1 x 10(superscript -5) Torr range, where plasma expansion due to electron-neutral collisions dominates over plasma expansion due to trap asymmetries. It is found that the expansion rate, defined as the time rate of change of the particles' mean-square radius, scales approximately linearly with pressure and inversely as the square of the magnetic field strength in this regime, in agreement with classical predictions.
We duscuss a resonant microwave trap for neutral atoms. Because of the long spontaneous radiation time this trap is remarkably different from the optical trap. It also has advantages over static magnetic traps that trap the excited spin state of the lowest electronic level, in that atoms predominantly in the spin ground state can be trapped. We analyze the relaxation-ejection lifetime of atoms in such a trap using the formalism of dressed atomic states. Results are appliedi to atomic hydrogen and the possibility of Bose-Einstein condensation is considered.
A cryogenic separation method of chloromethane (CH{sub 3}Cl) from methyl iodide (CH{sub 3}I) for {delta}{sup 37}Cl measurement with isotope ratio mass spectrometer is described. A cold trap with sealed 2,2,4-trimethylpentane (TMP) as the cryogen is used in this method. CH{sub 3}Cl can be separated from CH{sub 3}I at the TMP melting point (-107 deg. C) based on the difference in the vapor pressure between CH{sub 3}Cl (322.6 Pa) and CH{sub 3}I (lower than 1.3 Pa) at -107 deg. C. After two-step separation processes, the yields of CH{sub 3}Cl purified from CH{sub 3}Cl-CH{sub 3}I mixture are 96-101%, and the difference between the {delta}{sup 37}Cl{sub original} and {delta}{sup 37}Cl{sub Afterseparation} is from -0.06 to +0.06 per mille (0.01 {+-} 0.04 per mille ). These results suggest that CH{sub 3}Cl is completely separated from CH{sub 3}I with no change of {delta}{sup 37}Cl value. This method using the cold trap with sealed TMP is very safe and ...
Methods for the synthesis and quantitation of the novel choline analogues, telluronium choline and acetyltelluronium choline, are described. An assay procedure utilizing pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) with cold trapping was developed with [2H4]telluronium choline and [2H4]acetyltelluronium choline as internal standards. The telluronium compounds were ion-pair extracted from tissue with dipicrylamine, washed with 2-butanone, and pyrolyzed prior to GC-MS analysis. The compounds were monitored using selected ion monitoring at m/z 232 and m/z 190 for acetyltelluronium and telluronium choline, respectively, and at m/z 236 and m/z 194 for the analogous deuterated internal standards. The assay was linear over a range of 20 pmol-20 nmol of compound taken through the assay. PMID:8130881
A mathematical model has been constructed to describe the creation and filling of thermoluminescence traps during irradiation. Processes considered include trap filling, recombinations both between free charges and between free and trapped charges and thermal de-trapping. Also a simple trap creation term, linear with dose, has been included. A computer program has been written in order to solve the system of differential equations describing the various charge carrier flows during irradiation. The model and the program are described and the results of the application of the model to some simple energy-level schemes are discussed. Thermal de-trapping and band-to-band recombinations can introduce a dose rate dependence into the accumulation of trapped charge, whilst trap creation leads to the supralinear growth of charge ...
Most of the petroleum fields in the Norwegian sector of the North Sea are sandstone reservoirs; the oil and gas are trapped in different species of sandstone. But the Ekofisk Field is a chalk reservoir, which really challenges the operator companies. When oil is produced from chalk reservoirs, water usually gets in and the reservoir subsides. The subsidence may be expensive for the oil companies or be used to advantage by increasing the recovery rate. Since 60 per cent of the world's petroleum reserves are located in carbonate reservoirs, it is important to understand what happens as oil and gas are pumped out. Comprehensive studies at the Department of Petroleum Technology and Applied Geophysics at Stavanger University College in Norway show that the mechanical properties of chalk are considerably altered when the pores in the rock become saturated with oil/gas or water under different stress ...
Hot gastrapped in a dark matter halo will produce a decrement in the surface brightness of the microwave background, the Sunyaev-Zel'dovich (SZ) effect. While massive clusters produce the strongest central SZ decrements, we point out that a local galaxy halo, specifically the halo of M31, may be one of the brightest integrated SZ sources in the sky. For various realistic gas distributions consistent with current X-ray limits, we show that the integrated SZ decrement from M31 will be comparable to decrements already detected in more distant sources, provided its halo contains an appreciable quantity of hot gas. A measurement of this decrement would provide direct information on the mass, spatial distribution and thermodynamic state of hot gas in a low-mass halo, and could place important constraints on current models of galaxy formation. Detecting such an extended (~ 10 degree), ...
The Jurua gas field is the first important hydrocarbon accumulation found in the jungle-covered Solimoes basin. The tectonic framework in this area is characterized by a right-lateral transpressional zone (Jurua structural trend). Hydrocarbon traps are anticlines developed along the upthrown block of a reverse fault. The prospective 2,200-m-thick Paleozoic section is unconformably covered by a 2,800-m-thick pile of Mesozoic and Cenozoic continental sediments. Anomalous concentrations of hydrocarbons (C{sub 2}-C{sub 4}) in soil samples are concordantly aligned with the trace of the reverse fault crossing the gas field, indicating that this feature acted as a conduit for hydrocarbon microseepage. Gas-producing wells are located over a tabular watershed which coincides with the northeast-southwest Jurua structural trend. An unsupervised classification of Landsat MSS data over the gas ...
The Ordos Basin is a typical lapped basin, including three sequences of strata: early Paleozoic, late Paleozoic and Mesozoic, with a total thickness of 4000-6000m. Impermeable sealing beds are well developed at the top and base of the upper Paleozoic sequence, separating it from the Mesozoic and the lower Paleozoic strata to form an independent petroleum system. In this petroleum system, the source rocks are widely distributed coals and dark mudstones occurring in the Carboniferous-lower Permian coal measures, with a thickness of 10-15 and 40-60m, respectively. The reservoirs are mainly early Permian tight sandstones, mostly with a porosity of 4-8% and a permeability of 0.1-1.0x10{sup -3}{mu}m{sup 2}. The regional cap rock is a 100-150m thick mudstone in the upper Permian strata. The structural framework of the basin is a huge asymmetric syncline, dipping gently toward the east and north, and steeply toward the south and west. Well data show that gas-saturated, ...
A summary of the off-gas behavior in the HARVEST pot vitrification process is presented. Experimental runs were carried out on 3 representative wastes (MAGNOX - thermal reactor, metal fuel, THORP - thermal oxide fuel and PFR - fast reactor oxide fuel) using 2 methods of feeding the glass-formers (slurry and crizzle). Materials were carried over from the vitrification vessel into the off-gas system by entrainment supplemented by volatilization. The main volatile elements were Ru, B, Cs. Some volatility was also shown by Na and Li. The overall behavior of the off-gas was consistent with the presence in it of 5 separate aerosols of particulate matter. Sources of entrainment gave rise to 3 aerosols, and a further 2 aerosols were formed as a result of chemical reaction (Ru) and condensation (Cs) proceses involving the volatile species. Entrainment was enhanced when the feed contained free alkali nitrate. The Ru volatility ...
A sensitive and rapid automated method has been developed for the selective analysis of acid extractable sulfide in environmental samples by combining gas dialysis separation techniques with methylene blue detection procedures. Acid extractable sulfide is separated from the sample matrix by the gas dialysis membrane and subsequently trapped in a dilute sodium hydroxide receiving stream. This stream is reacted with N,N-dimethyl-p-phenylenediamine and ferric chloride to produce methylene blue which is then quantitated colorimetrically at 660 nm. For standards and nonturbid environmental samples, there is good agreement between the results obtained by this procedure and the standard methylene blue method. The effect of interferences on the accurate determination of sulfide by both methods was also examined and it was found that cupric ions significantly interfered with sulfide estimation. To obtain adequate sulfide recoveries ...
Since 1999, several studies on nuclear fuels were realised in C11/C12 Atalante Hot Cell. This paper presents firstly an overview of the apparatus used for fuel dissolution and characterisation like reactor design, gastrapping flask and solid/liquid separation. Then, the general methodology is described as a function of fuel, temperature, reagents, showing for each step, the reachable experimental data: Dissolution rate, chemical and radiochemical fuel composition including volatile LLRN, insoluble mass, composition, morphology, cladding chemical, radiochemical and physical characterisation using SIMS (made in Cadarache/LECA facilities), MEB. To conclude, some of the obtained results on 129I and 14C composition of oxide fuels, rate of dissolution and first results on dissolution studies of RERTR UMo fuel will be detailed. (Author)
The n3 and n4 vibrational transitions of CH3 and CD3 isolated in solid parahydrogen were studied by high-resolution infrared spectroscopy. The radicals were produced by in situ UV photolysis of methyl iodides trapped in solid parahydrogen. The observed spectra showed clear rotational fine structures, which were subjected to further splitting due to the electrostatic field of solid parahydrogen. The molecular constants and crystal field parameters of the radicals in solid parahydrogen were determined by analyzing the spectral structures of the n3 and n4 transitions of CD3 by the crystal field theory. The rotational constants of the CD3 radical were found to be only a few percent smaller than those in the gas phase. The determined crystal field parameters indicated significant quantum effect...
... Abstract : Small metallic fragments can be trapped in combustible cartridge cases during manufacture and released into the interior-ballistic flow ...
Reserve appreciation, also called reserve growth, is the increase in the estimated ultimate recovery (the sum of year end reserves and cumulative production) from fields subsequent to discovery from extensions, infield drilling, improved recovery of in-place resources, new pools, and intrapool completions. In recent years, reserve appreciation has become a major component of total U.S. annual natural gas reserve additions. Over the past 15 years, reserve appreciation has accounted for more than 80 percent of all annual natural gas reserve additions in the U.S. lower 48 states (Figure 1). The rise of natural gas reserve appreciation basically came with the judgment that reservoirs were much more geologically complex than generally thought, and they hold substantial quantities of natural gas in conventionally movable states that are not recovered by typical well spacing and vertical completion practices. ...
An embodiment of a mercury-free fluorescent lamp combines a low pressure rare gas discharges with a phosphor having a quantum efficiency grater than one. The choice of the rare gas depends on a number of factors, one of which is the resonance transition energy. Less demand is placed the quantum efficiency of the phosphor for a lower energy resonance photon. Xenon has the lowest energy resonance transition of the stable rare gases at 8.5 eV (147 nm) and thus is a good candidate to study. The usefulness of a xenon-based discharge depends on the radiant emittance of the discharge at the resonance wavelength of 147 nm. The radiant emittance from a low pressure xenon positive column discharge is measured using two independent techniques. The first relies on the measurement of the resonance level density using absorption techniques. The effective decay rate of the resonance level is calculated using radiation trapping theory. The ...
Nanocrystalline cemented tungsten carbide has attracted considerable interests for use in cutting tool because of its superior mechanical properties. In this study, nano-sized powders of mixed WC and Co were prepared from attrition-milled oxides by a gas reduction-carburization process. The effects of compacting pressure, heating schedule, additional ball-milling, and the presence of a grain growth inhibitor on the sintering properties of the nano-sized WC-Co powders were examined. The grain size and phases in WC-Co alloy were clearly affected by compacting pressure. Because of the trapped gases and the lower melting point of the cobalt binder, when a compact of nano-sized WC-Co powder was sintered through a heating schedule with holding steps, the sintered alloy maintained the small size of WC grains without any {eta} phase. In addition, the additional ball-milling improved the microstructure and mechanical properties of the nano-sized WC-Co ...
Nanocrystalline cemented tungsten carbide has attracted considerable interests for use in cutting tool because of its superior mechanical properties. In this study, nano-sized powders of mixed WC and Co were prepared from attrition-milled oxides by a gas reduction-carburization process. The effects of compacting pressure, heating schedule, additional ball-milling, and the presence of a grain growth inhibitor on the sintering properties of the nano-sized WC-Co powders were examined. The grain size and phases in WC-Co alloy were clearly affected by compacting pressure. Because of the trapped gases and the lower melting point of the cobalt binder, when a compact of nano-sized WC-Co powder was sintered through a heating schedule with holding steps, the sintered alloy maintained the small size of WC grains without any #eta# phase. In addition, the additional ball-milling improved the microstructure and mechanical properties of the nano-sized WC-Co ...
An atlas series about the offshore northern Gulf of Mexico will group gas and oil reservoirs into subregional plays and will display reservoir data on a computerized geographical information system. The atlas series will provide critically compiled reservoir engineering data to help the private sector explore and develop hydrocarbons and to help the public sector analyze the hydrocarbon endowment in this basin. In this report, we cover aspects of the play-analysis procedure and provide specific examples of lower Miocene plays from the upper Texas coast and Federal Outer Continental Shelf (OCS). Play analysis emphasizes using broad classes of structural style, depositional style and environments, and defining attributes to group reservoirs into plays. To date, we have identified 4 Oligocene and 25 Miocene plays in Texas State offshore waters and 115 plays in the Federal OCS. Texas State offshore plays are gas prone (cumulative production 3.7 ...
In 1977 and 1978, workers at Idaho National Engineering Laboratory (INEL) developed and tested a process for the regeneration and reuse of silver mordenite, AgZ, used to trap iodine from the dissolver off-gas stream of a nuclear fuel reprocessing plant. We were requested by the Airborne Waste Management Program Office of the Department of Energy to perform a confirmatory recycle study using repeated loadings at about 150/sup 0/C with elemental iodine, each followed by a drying step at 300/sup 0/C, then by iodine removal using elemental hydrogen at 500/sup 0/C. The results of our study show that AgZ can be recycled. There was considerable difficulty in stripping the iodine at 500/sup 0/C.; however, this step went reasonably well at 550/sup 0/C or slightly higher, with no apparent loss in the iodine-loading capacity of the AgZ. Large releases of elemental iodine occurred during the drying stage and the early part of the stripping stage. Lead ...
The LPCTrap setup is a transparent Paul trap dedicated to the measurement of the ??? correlation coefficient a ?? in the ? decay of trapped radioactive nuclides. In a first experiment, the system has been used to record ?105 coincidences between the ? particles and recoiling ions emitted from the decay of 6He?+? ions. The analysis of the collected data has already shown that the size of the 6He?+? ion cloud confined in the Paul trap is a critical parameter, potentially limiting the accuracy on the a ?? measurement. We report here the precise determination of the trapped ion cloud temperature and size. This was performed by extracting the trapped ions toward a position sensitive micro channel plate detector at different phases of the RF driving field. We find a temperature T exp ?= 0.107(7)...
Charge transport in disordered organic semiconductors is generally described as thermally activated hopping in a gaussian distribution of localized states. The presence of charge traps is critical to the performance of organic electronic devices, since trapped charge carriers do no longer contribute to the current flow. The trap distribution in the polymer poly(3-hexylthiophene) (P3HT) is investigated by applying the fractional thermally stimulated current technique. Thereby, a low temperatur double-peak distribution has been revealed. One of the peaks is believed to belong to the tail of the intrinsic density of states, whereas the other trap is strongly affected by exposure to oxygen. We discuss the influence of oxygen exposure time on the trap distribution.
The DITE (Divertor Injection Tokamak Experiment) program has been undertaken to demonstrate the feasibility of impurity control by the use of a diverter in an injection-heated toroidal plasma configuration. Rather than behaving in accordance with neoclassical toroidal containment theory, the plasma is subject to various instabilities, particularly the resistive fluid MHD types, follows the empirical scaling of energy confinement time with plasma parameters observed in other plasma devices. DITE experiments have, however, extended the range of current and density. Impurities arising from plasma interactions with the vacuum vessel surface are controlled by the bundle divertor, which diverts a portion of plasma and power in the plasma scrape-off layer into a separate target chamber where impurities can be removed. Auxiliary plasma heating is provided by the injection of powerful beams of neutral hydrogen atoms produced by multi-aperture ion sources and hydrogen gas ...
A brief comparative review of possible mercury free fluorescent lighting technologies is presented, including rare-gas positive column discharges, molecular discharges, and dielectric barrier discharges. Detailed experimental results on xenon positive column discharges will then be considered. In order to judge whether xenon-based discharges are a viable UV source it is necessary to measure the radiant emittance (power per unit area) for the vacuum ultraviolet (VUV) resonance xenon emission at 147 nm. Two techniques to determine the VUV radiant emittance have been developed and applied to xenon discharges. One method combines the measured resonance level density using absorption spectroscopy and a calculation of the trapped decay rate for the resonance radiation to arrive at the radiant emittance at 147 nm. A second method utilizes a direct measurement of the radiance (power per unit area per unit solid angle) at 147 nm using a calibrated VUV ...
Volatile compounds produced in flexible food packaging materials (LDPE, EVAc, PET/PE/EVOH/PE) during electron beam irradiation were isolated by purge and trap technique and identified by combined gas chromatography-mass spectrometry (GC/MS), after thermal desorption and concentration. For comparison purposes non-irradiated films were also studied. Film samples were irradiated at low (5 kGy, corresponding to cold pasteurization), intermediate (20 kGy, corresponding to cold sterilization) and high (100 kGy) doses. It was observed that a number of volatile compounds are produced after irradiation in all cases. Furthermore the amounts of all volatile compounds increase with increasing irradiation dose. Both primary (methyl-derivatives etc.) as well as secondary i.e. oxidation products (ketones, aldehydes, alcohols, carboxylic acids etc.) are produced upon irradiation. These products may affect organoleptic properties and thus shelf-life of ...
DNA transposons are efficient tools in transgenesis and have therefore become popular in the analysis of the regulatory genome in vertebrates via enhancer trap screens. Here, I discuss recent progress...Full Text Available
Small metallic fragments can be trapped in combustible cartridge cases during manufacture and released into the interior-ballistic flow upon combustion of the case. Such particles may survive the interior-ballistic cycle and pose an ignition threat to the...
Electronic trap densities at the indium tin oxide (ITO)/hole transport layer (HTL) interface in operating organic light-emitting diodes (OLEDs) are characterized in situ using impedance spectroscopy. For OLEDs with a high density of active trap states, negative values of the frequency derivative of resistance are clearly observable for frequencies on the order of 10 kHz, whereas positive values are observed when the trap density is low With this technique, it is revealed that the trap density is minimized via the introduction of a TPD-Si{sub 2} (4,4'-bis[(p-trichlorosilylpropylphenyl) phenylamino]-biphenyl) passivation layer at the ITO/HTL interface or by the application of large electric fields during device operation. Furthermore, impedance spectroscopy illustrates that the ITO/HTL interface is not a simple series resistance when traps are present since they are shown not ...
A serological trapping technique for detecting rotaviruses is described which involves coating electron microscope grids with protein A and specific rotavirus antiserum. The presence of a layer of antibodies...Full Text Available
A new analysis is developed for long secondary photocurrent transients which gives the distribution of trapped holes in valence band tail states. Thermally assisted tunneling to dangling bonds is implicated as the rate limiting step in hole-recombination. Light-soaking causes the energetically deeper hole traps with the longer residence times to be lost first and in the same number as would be expected for the increase in dangling bonds; This result supports a model which has hole trapping in valence tail states as a precursor to light induced dangling bonds.
A catalytic trap oxidizer based on a radial flow metal mesh filter was developed for use as an after treatment device on light-duty diesel vehicles. A complete system for assisted regeneration was devised to enable this unit to operate without blocking during all normal driving modes. The integration of the catalyzed trap and regeneration system with the vehicle to provide a practical system for the reduction of diesel particulate emissions is discussed. To date, many prototype catalytic trap and regeneration system installations have been completed on various test vehicles, both naturally aspirated and turbocharged. The operational conditions and test results from a selection of these studies are presented.
Trapped ions are a near ideal system to study quantum information processing due to the high degree of control over the ion's external confinement and internal degrees of freedom. We demonstrate the key steps necessary for trapped ion quantum computing and focus on phonon-mediated entangling gates. We highlight several key algorithms implemented over the last decade with these gates and give a detailed description of Grover's quantum database search implemented with two trapped ion qubits.
... Brewarrina Aboriginal Fish Traps (Baiame's Ngunnhu) - National Heritage - New South Wales http://www.environment.gov.au/heritage/places/...national/brewarrina/index.html Brewarrina Aboriginal Fish Traps (Baiame's Ngunnhu) - National Heritage - New South Wales Change text size Skip to ...Search You are here: Environment home »Heritage »Heritage places »National heritage places Brewarrina Aboriginal Fish Traps (Baiame's Ngunnhu), New South Wales ... The Brewarrina fish traps continue to be visible in the Darling River today and were included in the National Heritage List on 3 ...
Two geochemical surveys were conducted in 1992 and 2000 respectively in the Yimeng Uplift of the Ordos Basin, China. The earlier survey grid had 1 x 5km spacing and the later survey grid had 0.5 x 0.5km spacing. The acid-extractable hydrocarbons of both surveys show similar geochemical trends. However, the anomalies obtained with traditional statistical methods do not correlate with existing oil/gas fields. This study reveals two problems in the data and their processing. The first one is interference caused by the variation of soil composition. We applied a wavelet-analysis-based method to eliminate this interference in the data of the later survey. The second is that micro-seepage anomalies did not identify existing oil/gas fields and seepage anomalies related with faults had not been previously recognized. We modified the logic multiplication cluster analysis and applied a multi-fractal model and a back propagation artificial neural network ...
We propose two schemes for the implementation of quantum discrete Fourier transform in the ion trap system. In each scheme we design a tunable two-qubit phase gate as the main ingredient. The experimental implementation of the schemes would be an important step toward complex quantum computation in the ion trap system.
The permeation of hydrogen through steam generator tubes at high temperatures ({approx} 300 degrees C) has been studied using an electrochemical technique. With this technique, hydrogen is generated on one side of the tube and monitored on the other side. The time for the hydrogen to reach the other side is used to determine the diffusion coefficient of hydrogen in the tube. Boundary conditions at the entry and exit sides have been investigated separately. Preliminary studies were performed on Stainless Steel 316 and Nickel Alloy 800 to better understand the influence of the solution chemistry on the electrochemical evolution of hydrogen. The surface phenomena effect and the trapping effect are discussed to account for differences observed in the permeation response. The hydrogen permeation through oxides at the exit side has been studied. Two nickel alloys (Alloy 800 and Alloy 600), materials widely used for steam generator tubes, have been investigated. The tubes ...
The theoretical and experimental investigation of the mechanism of SO2 and H2S removal by CaCO3 -based sorbents (limestones and dolomites) in pressurized uidized-bed coal combustors (PFBC) and high pressure gasiers, respectively, is the main objective of this study. It is planned to carry out reactivity evolution experiments under simulated high pressure conditions or in high pressure thermogravimetric and, if needed, uidized- bed reactor (high pressure) arrangements. The pore structure of fresh, heat-treated, and half-calcined solids (dolomites) will be analyzed using a variety of methods. Our work will focus on limestones and dolomites whose reaction with SO2 or H2S under atmospheric conditions has been studied by us or other research groups in past studies. Several theoret- ical tools will be employed to analyze the obtained experimental data including a variable diusivity shrinking-core model and models for diusion, reaction, and structure evolution in chemically reacting porous ...
The Cambro-Ordovician platform was formed along the margin of the old super-continent of Laurentia approximately 470 million years ago, and is a prolific producer of hydrocarbons. This presentation provided a geological review of the region as well as estimates of the amounts of oil in place. A simplified geological cross-section of the formation was presented, as well as a chart of the Anticosti Basin of western Newfoundland. Details of exploration wells targeting the Cambro-Ordovician carbonate platform and current west coast land holdings were provided. An outline of the area's petroleum system included details of source rock, reservoirs, traps and seals and migration and timing. Offshore prospects for the platform were estimated to be in the region of 100 to 200 million barrels. Onshore prospects were estimated to be in the region of 30 million to 150 million barrels. It was noted that limited coverage by onshore seismic data may mean that larger ...
Formaldehyde, a well-identified indoor pollutant, was recently classified as carcinogenic. New regulations for the air quality are expected and therefore there is a need for low-cost sensors, sensitive and selective with a fast response time for the detection of formaldehyde at ppb level. In the present work, we had developed a chemical sensor based on nano-porous matrices doped with Fluoral-P and optical methods of detection. The nano-porous matrices, elaborated via the Sol-Gel process, display nano-pores whose cavity is tailored for the trapping of the targeted pollutant. They provide a first selectivity with the discrimination of the pollutants by their size. A second selectivity is obtained with a molecular probe, Fluoral-P, which reacts specifically with formaldehyde leading to the 3,5- di-acetyl-1,4-dihydro-lutidine (DDL). The kinetics of formation of DDL was studied as function of many parameters such as the concentration of Fluoral-P in the matrix, the ...
Optically stimulated luminescence (OSL) and thermoluminescence are observed in polycrystalline RbMgF3:Eu2+ after x-ray, ?-ray, or ? irradiation. The main electron traps are F-centers but there are other unidentified traps. The main hole traps at room temperature are probably Eu3+ and thermal or optical stimulation leads to electron-hole recombination at the Eu3+ site and Eu2+ emissions arising from 6PJ to 8S7/2 and 4f5d(Eg) to 8S7/2 transitions. We find that some of the electron traps can be emptied by infrared stimulation and all of the electron traps can be emptied by white light stimulation. The OSL dark decay is long and exceeds 5 days for traps that are emptied by white light stimulation after initial infrared bleaching. Our results show that this compound can be used as a radiation dosimeter for intermediate dose levels where the 87Rb self-dose does not ...
We analyze the impact of trap states in the oxide layer of a superconducting tunnel junctions, on the fluctuation of the Josephson critical current, thus on coherence in superconducting qubits. Two mechanisms are usually considered: the current blockage due to repulsion at the occupied trap states, and the noise from electrons hopping across a trap. We extend previous studies of noninteracting traps to the case where the traps have on-site electron repulsion inside one ballistic channel. The repulsion not only allows the appropriate temperature dependence of 1/f noise, but also is a control to the coupling between the computational qubit and the spurious two-level systems inside the oxide dielectric. We use second order perturbation theory which allows to obtain analytical formulae for the interacting bound states and spectral weights, limited to small and intermediate repulsions. ...
A detailed study of adsorption of automobile exhaust hydrocarbons in Ag{sup +}-exchanged zeolites under cold-start conditions (room temperature and in the presence of water) was carried out with FT-IR spectroscopy, using toluene and propylene as probes. The results show that exchanged Ag{sup +} in zeolites is unique for trapping olefin and aromatic hydrocarbons due to its resistance to water adsorption. In contrast, exchanged Cu{sup 2+} in zeolites, which has good hydrocarbon trapping properties under dry conditions, does not trap hydrocarbons under wet conditions. Here, solvation of Cu{sup 2+} screens the interactions of the cation with adsorbed hydrocarbons. The results also show that, in addition to the nature of the cation, the structure of the zeolite also plays a role in hydrocarbon trapping. Aging at high temperatures, with water vapor (=10%) and SO{sub 2} (=15ppm), leads to a decrease of the ...
Spectroscopy of antihydrogen has the potential to yield high-precision tests of the CPT theorem and shed light on the matter-antimatter imbalance in the Universe. The ALPHA antihydrogen trap at CERN's Antiproton Decelerator aims to prepare a sample of antihydrogen atoms confined in an octupole-based Ioffe trap and to measure the frequency of several atomic transitions. We describe our techniques to directly measure the antiproton temperature and a new technique to cool them to below 10 K. We also show how our unique position-sensitive annihilation detector provides us with a highly sensitive method of identifying antiproton annihilations and effectively rejecting the cosmic-ray background.
With a computerized curve fitting method the trapping parameters of TLD-100 chips were calculated after #alpha#-, #beta#- and #gamma#-irradiation. The absorption of radiation produces an additional glow peak at 250 deg C, and the dominant one arises at 280 deg C. After the analysis of the glow curves only a little LET-dependence of the trap depths and that of the half widths was detected. The charge densities after irradiation before heating of the taps responsible for the high temperature glow peaks (T>240 deg C) show a LET-dependence. (author).
Nov 8, 2010 ... Ihring Mission 11, the radiation dosimetry measurement system functioned normally and provided data on the Earth's trapped radiation belts ...
Removal Sampling is an easy-to-use Windows program which calculates population statistics from removal trapping experiment data. Using maximum likelihood methods it ... ...
A relocatable storage magazine apparatus for storing and retrieving explosives and ordnance and for partially containing and attenuating the blast, conflagration and flying debris from an accidental explosion is described comprising: (a) a container having an access hole; (b) a debris trap attached to the container, the debris trap communicating with said container via the access hole, said debris trap having vent holes for venting the pressure of an explosion from said debris trap to the atmosphere; (c) means for covering said access hole; (d) means for suspending explosives and ordnance from the covering means; (e) means for entering the storage magazine to store and retrieve explosives and ordnance; (f) means for retaining said covering means in a position above the access hole wherein said explosives and ordnance are accessible from the entering means.
... Zinn, J., Hoerlin, H., and Petschek, AG, "The Motion of Bomb Debris Follow- ing the Starfish Test," Radiation Trapped in the Earth's Magnetic Field ...
Calculations relating to two experiments that demonstrate coherent control of preformed rubidium-85 molecules in a magneto-optical trap using ultrafast laser pulses are presented. In the first experiment, it is shown that pre-associated molecules in an incoherent mixture of states can be made to oscillate coherently using a single ultrafast pulse. A novel mechanism that can transfer molecular population to more deeply bound vibrational levels is used in the second. Optimal parameters of the control pulse are presented for the application of the mechanism to molecules in a magneto-optical trap. The calculations make use of an experimental determination of the initial state of molecules photoassociated by the trapping lasers in the magneto-optical trap and use shaped pulses consistent with a standard ultrafast laser system.
SummaryCongenital lobar emphysema (CLE) characterized by over distension and air-trapping in the affected lobe is one of the causes of infantile respiratory distress requiring...Full Text Available
We have developed a low-temperature particle detector that uses a novel quasiparticle trapping mechanism to funnel athermal phonon energy from an 80 mg Ge absorber into a 1.6 mg doped Ge thermistor via a superconducting Al film. We report on pulse height spectra obtained at 320 mK by scanning a {sup 241}Am alpha source along the device, and show that up to 20% of the energy deposited in the Ge absorber by a 5.5 MeV alpha particle interaction can be collected into a thermistor via quasiparticle trapping. We show that this device is sensitive to the position of an alpha particle interaction in the Ge absorber for interaction distances of up to 5 mm from a quasiparticle trap.
Four general topics are covered in respect to the natural space radiation environment: (1) particles trapped by the earth`s magnetic field, (2) cosmic rays, (3) radiation environment inside a spacecraft, (4) laboratory radiation sources. The interaction of radiation with materials is described by ionization effects and displacement effects. Total-dose effects on MOS devices is discussed with respect to: measurement techniques, electron-hole yield, hole transport, oxide traps, interface traps, border traps, device properties, case studies and special concerns for commercial devices. Other device types considered for total-dose effects are SOI devices and nitrided oxide devices. Lastly, single event phenomena are discussed with respect to charge collection mechanisms and hard errors. (GHH)
Zinn, John;. Hoerlin,. Herman; and Petschek,. Albert. G.: The Motion of Bomb. Debris. Following the Starfish. Test. Radiation. Trapped in the Earth's ...
A new principle of particle trapping in the simple spherical cavity using both electric and magnetic components of radiofrequency electromagnetic field is proposed. The electric component of H {sub 12} oscillating mode drives the fast particle oscillations, while the magnetic component synchronously bends the trajectories to the cavity center. A specially developed theory of particle stability predicts dense and energetic electron cluster in the trap. Numerical simulations of particle dynamics in the complete electromagnetic field taking into account both space charge and particle-induced magnetic field are in good agreement with the analytic results, giving a density of 2.6*10{sup 1} electrons/cm{sup 3} and an average kinetic energy of around 30 keV at an operating frequency of 3 GHz. Being used at lower frequency, spherical cavity can trap protons and heavier ions too, but with lower density and kinetic energy.
Motional heating of ions in micro-fabricated traps is a challenge hindering experimental realization of large-scale quantum processing devices. Recently a series of measurements of the heating rates in surface-electrode ion traps characterized their frequency, distance, and temperature dependencies, but our understanding of the microscopic origin of this noise is still vague. In this work we develop a theoretical model for the electric field noise which is associated with a random distribution of adsorbed atoms on the trap electrode surface. By using first principle calculations of the fluctuating dipole moments of the adsorbed atoms we evaluate the distance, frequency and temperature dependence of the resulting electric field fluctuation spectrum.Our theory calculates the noise spectrum beyond the standard scenario of two-level fluctuators, by incorporating all the relevant vibrational states. The $1/f$ noise is shown to ...
This talk will summarize key features of three conceptual fusion neutron test facilities designed in the early 1980s: TASKA,^1 TDF,^2 and TASKA-M.^3 Motivated by the accessibility and maintainability of cylindrical geometry, these magnetic-mirror designs possess a simple central cell, as in a fusion neutron test facility based on the gas dynamic trap (GDT).^4 The TASKA-M design, like today's GDT designs, included the injection of neutral beams into the central cell to create a sloshing-ion distribution that gives density peaks near the materials test modules. In TASKA and TDF, the minimum-B end-cell designs contained thermal barriers, regions of low electrostatic potential to reduce electron flow between central cell and end cells. Thermal barriers improve performance but require more complicated input power systems, and their physics basis is less well established than that of simple mirrors. For TASKA-M, a more conservative design, minimum-B ...
The Rebi Block is currently in the early stages of hydrocarbon exploration. The subsurface geology of this area is only known from seismic reflection data. By applying seismic stratigraphy techniques, unconformities and condensed sections were recognized. These discontinuities were dated using paleontological information from the Kulka-1 well, Northwest Shelf of Australia. With these age constraints, seven unconformities and three condensed sections were dated and correlated to the Exxon global sea level curve. The chronostratigraphic charts for the Rebi Block and the Northwest Shelf of Australia have clarified the Mesozoic stratigraphy of the study area. The Exxon global sea level curve has refined the ages determined by conventional paleontological dating. The chart has also helped in predicting source, reservoir and seal potential within a time framework. Prospective stratigraphic traps were those related to the incised valleys at the southeastern part of the ...
The mechanism for afterglow suppression in codoped CsI:Tl,Eu reported in the preceding paper was investigated by combined radioluminescence and thermoluminescence experiments. Model rate equations informed by these experiments were employed to simulate afterglow. It was found that codoping with europium introduces deep electron traps, with room-temperature glow peaks, that effectively scavenge the electrons from shallow traps associated with thallium, thus suppressing afterglow in the time domain of tens of milliseconds.
Quantum computers hold the promise of solving certain computational tasks much more efficiently than classical computers. We review recent experimental advances towards a quantum computer with trapped ions. In particular, various implementations of qubits, quantum gates and some key experiments are discussed. Furthermore, we review some implementations of quantum algorithms such as a deterministic teleportation of quantum information and an error correction scheme.
A computerised curve-fitting method was developed to calculate the trapping parameters in LiF TLD-100 and LiF:Mg, Ti. After irradiation in a "6"0Co field and with X rays emitted at different voltages the TL process is best described by first-order kinetics. A dependence of the trapping parameters on both the concentration of Mg and Ti and photon energy was detected. (author).
Delta-doped boron marker layers in silicon have been used to test further the relationship between B transient enhanced diffusion (TED) and the flux of silicon interstitials released during the annealing stage following self implantation. The authors present new data which address a number of questions raised by the present models. They show that in the experiments bulk trapping of interstitials is significant only for low implant fluences ({approximately}10{sup 12} cm{sup {minus}2}). The origin of the observed diffusion-like profiles for the interstitial flux is instead found to lie in local trapping within the {delta}-doped layers themselves. Boron trapped in immobile clusters may be associated with Si interstitials in approximately a 1:1 ratio; nevertheless this trapping contribution alone may not entirely account for the observed gradient. They suggest that some part of the observed TED response ...
Delta-doped boron marker layers in silicon have been used to test further the relationship between B transient enhanced diffusion (TED) and the flux of silicon interstitials released during the annealing stage following self implantation. The authors present new data which address a number of questions raised by the present models. They show that in the experiments bulk trapping of interstitials is significant only for low implant fluences (#approx#10"1"2 cm"-"2). The origin of the observed diffusion-like profiles for the interstitial flux is instead found to lie in local trapping within the #delta#-doped layers themselves. Boron trapped in immobile clusters may be associated with Si interstitials in approximately a 1:1 ratio; nevertheless this trapping contribution alone may not entirely account for the observed gradient. They suggest that some part of the observed TED response with depth is ...
Specimen strips of pure alpha titanium and beta titanium alloy were exposed to a range of up to 46 deuterium plasma discharges in the Princeton Large Torus Tokamak (PLT) under simulated first wall conditions, and the amount of trapped deuterium in these specimens was measured, using carbon as a calibration standard for trapping. The Deuterium Nuclear Microprobe was used to study the total trapped deuterium and the deuterium depth distribution in the exposed materials before and after annealing at 373 and 423"0K. The Scanning Auger Microprobe was used to identify the effects of surface impurities on the deuterium distribution. Results indicate that about 20 to 40% of the incident deuterium was trapped by the surface and about 90% of the trapped deuterium remained in a 20A carbonaceous film deposited during plasma exposure. Annealing resulted in a gradual loss from the film. These ...
Geologic sequestration is currently being practiced and scientifically evaluated as a critical component in a broad strategy, comprising new practices and technologies, for mitigating global climate change due to anthropogenic emissions of CO2. Demonstrating that geologic sequestration of CO2 is safe and effective, and gaining public acceptance of sequestration technologies are critically important in meeting these global climate change challenges. Monitored field-scale demonstrations of geologic sequestration of carbon dioxide will contribute greatly toward growing trust and confidence in the technology; however, pilot demonstrations ultimately will not be the norm for new geological sequestration deployments. Instead, scientists, engineers, regulators, and ultimately the public will rely on numerical simulations to predict the performance of geologic repositories for carbon dioxide sequestration. The U.S. Department of Energy (DOE), through the National Environmental Technology ...
The laser cooling and trapping of ultracold neutral dysprosium has been recently demonstrated using the broad, open 421-nm cycling transition. Narrow-line magneto-optical trapping of Dy on longer wavelength transitions would enable the preparation of ultracold Dy samples suitable for loading optical dipole traps and subsequent evaporative cooling. We have identified the closed 741-nm cycling transition as a candidate for the narrow-line cooling of Dy. We present experimental data on the isotope shifts, the hyperfine constants A and B, and the decay rate of the 741-nm transition. In addition, we report a measurement of the 421-nm transition's linewidth, which agrees with previous measurements. We summarize the laser cooling characteristics of these transitions as well as other narrow cycling transitions that may prove useful for cooling Dy.
Cu(II)-ATSM continues to be investigated, both in the laboratory and in the clinic, as a tumor hypoxia imaging agent. However, meaningful interpretation of these images requires a more complete understanding of the mechanism by which the tracer is trapped within the cell. Cu(II)-ATSM is a simple molecule and its biochemical interaction with cells is similarly simple, mainly based upon redox chemistry. Here we suggest that the trapping mechanism is biphasic. The first phase is a reduction/oxidation cycle involving thiols and molecular oxygen. This can be followed by interaction with proteins in the mitochondria leading to more permanent retention of the tracer. The uptake mechanism is complicated by this second step because of the changes in the cell resulting from hypoxia, such as an incre...
There have been several reports of transient-enhanced diffusion during furnace or rapid thermal annealing of ion-implanted silicon and some reports of no enhancement. In this contribution, the authors show that many of the observed effects can be accounted for by an interstitial trapping mechanism, in which large numbers of Si atoms are trapped by group V dopant atoms in the amorphous material during implantation. These trapped atoms are retained during solid-phase-epitaxial (SPE) growth, but can be released later during thermal processing to give the transient-enhanced diffusion. The authors present a model which can predict the transient effects (or lack of them) for any concentration of Sb, Bi, or As dopants sufficient to amorphize the silicon and any thermal processing technology which relies on SPE growth (furnace, cw laser, or rapid thermal annealing).
During the recrystallization by solid-phase-epitaxial (SPE) growth of supersaturated silicon alloys, a high concentration of interstitials is trapped. These are released by subsequent heating causing a transient (greatly enhanced) diffusion of the substitutional dopant by an interstitialcy mechanism. The enhancement may be as much as five orders of magnitude over tracer values, and shows an activation energy of only 1.8 +- 0.2 eV. Following the transient, the interstitials condense into loops, allowing an independent estimate to be made of their concentration. From these observations, we propose that during ion implantation, a fraction of the implanted dopants can acquire their natural valency, and retain it as the crystallization interface passes. For group V dopants this creates the trapped interstitials, giving transient enhanced diffusion when they are released by subsequent annealing.
During the recrystallization by solid-phase-expitaxial (SPE) growth of supersaturated silicon alloys, a high concentration of interstitials is trapped. These are released by subsequent heating causing a transient (greatly enhanced) diffusion of the substitutional dopant by an interstitialcy mechanism. The enhancement may be as much as five orders of magnitude over tracer values, and shows an activation energy of only 1.8 +/- 0.2 eV. Following the transient, the interstitials condense into loops, allowing an independent estimate to be made of their concentration. From these observations, it is proposed that during ion implantation, a fraction of the implanted dopants can acquire their natural valency, and retain it as the crystallization interface passes. For group V dopants this creates the trapped interstitials, giving transient enhanced diffusion when they are released by subsequent annealing. 12 references, 6 figures.
The antioxidant properties of magnolol and honokiol were evaluated in the experimental systems of reducing ONOO^- and ^1O"2, bleaching @b-carotene in linoleic acid (LH) emulsion, and trapping 2,2'-azinobis(3-ethylbenzothiazoline-6-sulfonate) cationic radical (ABTS^+?) and 2,2'-diphenyl-1-picrylhydrazyl radical (DPPH), and then were applied to inhibit the oxidation of DNA induced by Cu^2^+/glutathione (GSH) and 2,2'-azobis(2-amidinopropane hydrochloride) (AAPH). Magnolol and honokiol were active to reduce ONOO^- and ^1O"2. Honokiol showed a little higher activity to protect LH and to inhibit Cu^2^+/GSH-induced oxidation of DNA than magnolol. In addition, honokiol exhibited higher activities to trap ABTS^+? and DPPH than magnolol. In particular, honokiol trapped 2.5 radicals while magnolol o...
Deep level effects in GaAs MOSFET have been characterised in the ohmic channel using DLTS, low frequency excess noise and dispersion technique. An isothermal multi exponential curve fitting method has been devised and implanted into the DLTS system. Multi exponential curve fitting method used to decompose a multi exponential transient into its constituents so that the peak signature can be better characterised for the case whereas several peaks are closely spaced. Low frequency excess noise and dispersion techniques also confirm the trap in signature of the same traps observed in the DLTS measurements. (author)
Hydrogen (H) plasma treatment, oxygen (O) plasma treatment and water (H_2O)-vapor heat treatment for polycrystalline-silicon (poly-Si) thin-film transistors (TFTs) have been analyzed by separately extracting trap density at a front silicon-oxide interface (D_F) and trap density at a back interface (D_B). It is found that the H plasma treatment is apt to generate D_F and D_B. The O plasma treatment reduces D_F, while the H_2O-vapor heat treatment reduces both D_F and D_B. Improvement of transistor characteristics of poly-Si TFTs depends on understanding these results.
The invention relates to a method for purifying a gas mixture containing at least one undesirable gas compound utilizing certain sulfonamide or sulfamide solvents.
of satellite, aircraft and ground-based observations. In ..... swarm traps by Utah Department of Food and Agriculture (DAF) personnel. Preliminary Results ..... the 150th anniversary of the book's publication and the 200th anniversary of Darwin's birth. ...... cold war submarine missions to find that Arctic Ocean ...
The astonishingly efficient location and excision of damaged DNA bases by DNA repair glycosylases is an especially intriguing problem in biology. One example is the enzyme uracil DNA glycosylase (UNG),...Full Text Available
Peptide toxins with high affinity, divergent pharmacological functions, and isoform-specific selectivity are powerful tools for investigating the structure-function relationships of voltage-gated...Full Text Available
A new type of radiation which occurs when particles are accelerated in the field of a longitudinal wave and in a transverse magnetic field is studied. The characteristics of such spontaneous radiation are obtained, and the influence of collective effects on the radiation is analyzed. The application of the findings to the theory of free electron lasers is discussed. 8 references.
It is shown analytically and experimentally that thermally stimulated current (TSC) measurements at negative bias incompletely describe oxide-trap charge in SIMOX and bipolar base oxides irradiated at 0 V. Positive-bias TSC is also required.
Total-dose irradiation seriously damages MOS devices and their circuit performance. Threshold voltage shifts, transconductance degradation and increase in off-state leakage current are generally observed for irradiated devices. These instabilities are essentially due to positive and/or negative charge trapping in SiO_2 and interface trap generation at the SiO_2/Si interface. Radiation hardening of CMOS VLSIs is to eliminate these trapping effects, and for this purpose, special considerations for fabrication processes and layout design are necessary. In this paper, basic mechanisms for radiation-induced charge trapping and related effects on MOS devices are reviewed. Also discussed are radiation-hardening technologies from both fabrication-process and layout-design viewpoints. Using these technologies, 1 #mu#m radiation-hard CMOS gate arrays have been successfully developed. Experimental data taken for ...
The kinetics of electrical breakdown of thin (15-70 ?m) layers of polymers and ceramics in a constant-sign field at 77-480 K has been investigated. The temperature dependences of the longevity (breakdown waiting time) of both dielectrics have been found to be similar to each other. At elevated temperatures, the longevity of the dielectrics varies exponentially with increasing temperature, and at reduced temperatures, it is temperature-independent (there is an athermal plateau). The mechanisms of elementary events controlling the process of preparation of the dielectrics for breakdown at elevated and reduced temperatures are the thermal-fluctuation over-barrier electron transition from trap to trap and the tunneling (under-barrier) transition, respectively. The hopping electron transport in the field direction gives rise to critical space charges causing breakdown of the dielectrics. The transition barrier heights (trap ...
An RNA secondary structure is locally optimal if there is no lower energy structure that can be obtained by the addition or removal of a single base pair, where energy is defined according...Full Text Available
A bedload trap in the riverbed provided direct quantitative measurement of debris-transport rate in the East Fork River, Wyoming, a basin of 466 km2 drainage area. Traction load moves only...Full Text Available
In the cyanobacterium Anabaena sp. strain PCC 7120, open reading frames (ORFs) alr3026, alr3027, and all3028 encode a tripartite ATP-independent...Full Text Available
Formation of particles from heavy duty diesel and CNG vehicles was studied in laboratory conditions. PM, nano and soot mode particle emissions formed from buses of Euro 2-5 -emission levels were studied in relation to age and type approval characteristics of the vehicle. Characteristic particle emission factors from city driving were obtained by driving the buses on VTT's heavy duty chassis dynamometer applying the transient Braunschweig city cycle. The vehicles were a representative set of Euro 2 to 3 emission categories, supplemented with Euro 4-5 (EEV) -targeted CRT, CNG and DPF cars. Particle number emissions from Euro 4 to 5 buses were 1/100-1/1000 and mass emissions 1/10-1/100 of those of the current fleet. Particle emission from natural gas buses and after an advanced CRT trap contained almost entirely liquid < 60 nm nano particles, which will make filter mass based PM control very challenging in the near future. One ...
The inner part of a fusion reactor will have to operate at very high neutron loads. In steady-state reactors the minimum fluence before the scheduled replacement of the reactor core should be at least l0-15 Mw.yr/m2. A more frequent replacement of the core is hardly compatible with economic constraints. A most recent summary of the discussions of these issues is presented in Ref. [l]. If and when times come to build a commercial fusion reactor, the availability of information on the behavior of materials and components at such fluences will become mandatory for making a final decision. This makes it necessary an early development and construction of a neutron source for fusion material and component testing. In this paper, we present information on one very attractive concept of such a source: a source based on a so called Gas Dynamic Trap. This neutron source was proposed in the mid 1980s (Ref. [2]; see also a survey [3] ...
The aim of this paper is to investigate the total ionizing dose (TID) radiation effects on MOS capacitor with nitride/oxide stack gate. The stack gate MOS capacitors are fabricated with 20 nm oxide, 40 nm nitride or 110 nm nitride respectively. Through the analysis of CV curve of the irradiation capacitors, it is found that the degradation of the CV curve is due to a significant increase of interface traps and somewhat smaller oxide charge. It is also shown that the thicker of the nitride, more interface traps and oxide charge will be occurred. (authors)
Gallium liquid-metal ion sources that have been introduced in the late 1970s have allowed the development of a new class of micro- and nanofabrication tools collectively denominated as focused ion beam (FIB) machines. To investigate the potential of a helium beam in such a FIB instrument the authors have tested a room-temperature electron beam ion trap coupled with a high resolution FIB machine. In this letter they present their first results in target imaging using a helium beam with a resolution that allows to account for a beam diameter in the submicrometer range.
The deuterium inventory at JET after 2001-2004 operational campaign has been determined using nuclear reaction analysis (NRA) and secondary ion mass spectrometry (SIMS). A full poloidal set of divertor tiles and a set of outer poloidal limiter (OPL) tiles were analysed providing an estimation for the total deuterium retention of about 66 g. Deuterium is trapped mainly at the inner divertor on horizontal target tile and at the inner divertor louvre area where ?60% of the trapped D is found. The long-term D retention is ?4% of the total D input.
The lifetime of the circulating electron beam in the Naval Research Laboratory modified betatron has been increased by more than 2 orders of magnitude with the addition of strong focusing windings to the device. The injected beam consistently spirals from the injector to the minor axis and is trapped. The #approx#0.5-kA trapped electron ring has been accelerated above 10 MeV from the injection energy of 0.5 to 0.6 MeV. The beam acceleration has been confirmed not only by the x-ray attenuation technique but also with the detection of photoneutrons.
The mono- and intramolecular cation-radicals (CR) reactions of diethylmercury in the CFCl_3, CFCl_2CF_2Cl matrices and CF_2BrCF_2Br and CFCl_3 freons vitrified mixture (1:1) were studied through the EPR method. Formation of radical products of transformations of the initial CR diethylmercury (X-ray radiation dose - 100-200 Gy at the temperature of 293 K) was studied through the spin trap of 2.4.6 - tri-tret-butylnitrosebenzene.
Significantly improved immunity to hot-hole damage of the SiO[sub 2]/Si structure is achieved by a shallow fluorine implantation into the poly-Si gate of MOS capacitors followed by a drive-in process. Compared to the nonfluorinated control, the fluorinated samples exhibit a dramatic reduction of both hole trapping probability and interface-trap generation under avalanche hole injection conditions. The degree of such an improvement increases monotonically as a function of the F implantation dose (up to 10[sup 16]/cm[sup 2]). Significant decrease of the hole detrapping rate is also observed in fluorinated samples. Possible mechanisms are discussed.
The behavior of afterglow (AG), thermoluminescence (TL), infrared stimulated luminescence (IRSL) and phototransferred TL (PTTL) under thermal and/or infrared (IR) stimulation in blue (470 nm) light illuminated at room temperature (RT) SrAl2O4:Eu2+, Dy3+ is presented. The TL glow curve consists of four peaks with maxima at about 340, 430, 560 and 680 K. The 340 and 440 K peaks are described well by second order kinetics with activation energies of 0.83 and 1.05 eV, respectively. The AG decay is fitted by the Becquerel's law with exponent 1.5 and correlates well with the thermal emptying of the traps responsible for the 340 K peak. The 340 and 430 K TL peak traps are destroyed under IR (830 nm) stimulation creating IRSL. IR stimulation after illumination with blue light and preliminary heating restore partially the 340 and 430 K TL peaks by phototransfer from deeper traps. The shape of the IRSL decay curves depends strongly ...
Rotary screw traps, located at four sites in the Grande Ronde River basin, were used to characterize aspects of early life history exhibited by juvenile Onchorhychus mykiss during migration years 1995-99. The Lostine, Catherine Creek and upper Grande Ronde traps captured fish as they migrated out of spawning areas into valley rearing habitats. The Grande Ronde Valley trap captured fish as they left valley habitats downstream of Catherine Creek and upper Grande Ronde River rearing habitats. Dispersal downstream of spawning areas was most evident in fall and spring, but movement occurred during all seasons that the traps were fished. Seaward migration occurred primarily in spring when O. mykiss smolts left overwintering area located in both spawning area and valley habitats. Migration patterns exhibited by O. mykiss suggest that Grande Ronde Valley habitats are used for overwintering and should be ...
A publication on Norwegian gas and gas export. The content is wide spread from use of gas in daily life via sub sea pipeline repair systems to an overview over tomorrows gas fields. (AG)
A gas diffusion semiconductor electrode and solar cell and a process for gaseous fixation, such as nitrogen photoreduction, CO/sub 2/ photoreduction and fuel gas photo-oxidation are described. The gas diffusion photosensitive electrode has a central electrolyte porous matrix with an activated semiconductor material on one side adapted to be in contact with an electrolyte and a hydrophobic gas diffusion region on the opposite side adapted to be in contact with a supply of molecular gas.
Sulfur poisoning from engine fuel and lube is one of the most recognizable degradation mechanisms of a NOx adsorber catalyst system for diesel emission reduction. Even with the availability of 15 ppm sulfur diesel fuel, NOx adsorber will be deactivated without an effective sulfur management. Two general pathways are currently being explored for sulfur management: (1) the use of a disposable SOx trap that can be replaced or rejuvenated offline periodically, and (2) the use of diesel fuel injection in the exhaust and high temperature de-sulfation approach to remove the sulfur poisons to recover the NOx trapping efficiency. The major concern of the de-sulfation process is the many prolonged high temperature rich cycles that catalyst will encounter during its useful life. It is shown that NOx adsorber catalyst suffers some loss of its trapping capacity upon high temperature lean-rich exposure. With the use of a disposable SOx ...
Optically stimulated luminescence (OSL) of synthetic stishovite was investigated for a future dating technique of meteor impact craters. Luminescence around 330 nm was measured on the #gamma#-ray irradiated stishovite under two stimulating light sources of infrared laser (830 nm) and blue light emitting diode set (470 nm). Thermoluminescence (TL) studies before and after the OSL measurements showed the intensities around 100-200 deg. C and 220-350 deg. C to increase and those around 350-450 deg. C to decrease. This indicates that a part of deep-trapped charges excited during the OSL measurements were retrapped by shallower traps. The infrared stimulated luminescence (IRSL) after the TL measurement up to 450 deg. C could not be detected, while the blue light stimulated luminescence (BLSL) after TL had about one-tenth of the intensity before TL. This indicates that a part of the charges in shallower traps were detrapped ...
The central topic of this work is the study of the properties and the implementation of a Paul trap used for the measurement of the beta-neutrino angular correlation parameter in the decay of {sup 6}He. This coefficient provides a signature of the nature of the interactions involved in the weak interaction. The value of this coefficient can be deduced from the kinematical distribution of the decay events. An electromagnetic trap is used for the trapping of {sup 6}He{sup +} ions in a small volume. This trap has an open geometry that enables the detection in coincidence of the electron and the recoil ion emitted in the beta decay. A dedicated detection set up is used for the measurement of the electron energy, the ion time of flight and the position of the two particles for each event. A general description of the LPCTrap facility and of its performances is presented and shows that this set up is able to ...
Results of an augmented-plane-wave calculation of the positron lifetime and the angular-correlation curves for aluminum, both in the vacancy-free crystal and in the crystal with a vacancy, are presented. The environment of the vacancy was simulated by a face-centered-cubic supercell with a volume 27 times that of the standard primitive unit cell of the Al lattice. The calculated positron-vacancy binding energy is 3.36 eV at room temperature. The temperature dependences of the trapping potential, the positron-vacancy binding energy, and the positron lifetime both in the Bloch state and in the vacancy-trapped state, associated only with the static thermal expansion of the lattice, have been calculated. It is found that the fractional increase in positron lifetime in the Bloch state is only approx.80% of the fractional increase in the volume of the lattice. The lifetime in the vacancy-trapped state is also found to vary with ...
The book tries about the International and national aspects, natural gas situation, production, consumption, prices, demand projection, energetic plans, norms and laws of the natural gas in Colombia
This document provides information on the supply and disposition of natural gas to a wide audience. The 1996 data are presented in a sequence that follows natural gas from it`s production to it`s end use.
The origin of natural gas in the Japanese oil and gas fields are geochemically studied. Samples are taken from structural natural gas, surface gas seepage, water-dissolved natural gas and coal-field gas of the Japan Sea coast area. The origins of primary hydrocarbons are classified into bacteria gas and thermogenic gas, the latter being subclassified into gas in oil production zone with the per million deviation of the carbon isotope (/sup 13/C/sup 1/) of methane less than -35 and those gases with maturity higher than this. Surface gas seepage is subjected to migration and bacterial oxidation. Coal gas is similar to oil gas. The CO/sub 2/ concentration is 0 - 2% and /sup 13/CO/sub 2/ deviations from -30 - +30. The origin can be barely ...
Polycrystalline ZnS semiconducting films have been prepared in sandwich configuration by spray pyrolysis technique using ZnO-coated glass substrates and mixed aqueous solutions of ZnCl{sub 2} and thiourea. The sandwich structures have been produced successfully by means of ZnO-coated glass substrates. The produced ZnS films have been crystallized in a wurtzite structure and had a direct band gap energy of 3.62 eV. The electrical properties of the sample have been studied by an analysis based on the thermally stimulated current spectra in the temperature range of 40-300 K with various heating rates. A set of curves of I (T) for varying initial density of filled traps at a heating rate of {beta} {sub 2}=0.06 K s{sup -1} indicate that the observed peaks in the TSC curve of polycrystalline ZnS films have first-order features. In order to evaluate the trap parameters of ZnS films, we have used curve-fitting method. The values of the frequency factor ...
The results presented here demonstrate that the Paul Trap Simulator Experiment (PTSX) simulates the propagation of intense charged particle beams over distances of many kilometers through magnetic alternating-gradient (AG) transport systems by making use of the similarity between the transverse dynamics of particles in the two systems. Plasmas have been trapped that correspond to normalized intensity parameters s = wp2 (0)/2wq2 * 0.8, where wp(r) is the plasmas frequency and wq is the average transverse focusing frequency in the smooth-focusing approximation. The measured root-mean-squared (RMS) radius of the beam is consistent with a model, equally applicable to both PTSX and AG systems that balances the average inward confining force against the outward pressure-gradient and space-charge forces. The PTSX device confines one-component cesium ion plasmas for hundreds of milliseconds, which is equivalent to over 10 km of beam propagation.
The diffusion of ion beam injected self-interstitials (I) and their interaction with impurities in crystalline Si has been investigated and modeled. In particular, the I-substitutional carbon (C) interactions have been studied, using a molecular-beam-epitaxy grown Si{sub 1-y}C{sub y} layer interposed between the shallow I-source and a deeper B-spike (marker for I-concentration). Substitutional C atoms are shown to trap I's, to be removed from their substitutional sites, and to form stable precipitates into the C-rich region. The I-trapping mechanism was quantitatively studied by a simulation code. The reactions causing trapping and deactivation are described. In addition, the boron markers approach was extended to the two dimensional (2D) diffusion. High resolution scanning capacitance microscopy was used for quantitative measurements of the 2D boron transient enhanced diffusion induced on a boron delta array by ...
The diffusion of ion beam injected self-interstitials (I) and their interaction with impurities in crystalline Si has been investigated and modeled. In particular, the I-substitutional carbon (C) interactions have been studied, using a molecular-beam-epitaxy grown Si_1_-_yC_y layer interposed between the shallow I-source and a deeper B-spike (marker for I-concentration). Substitutional C atoms are shown to trap I's, to be removed from their substitutional sites, and to form stable precipitates into the C-rich region. The I-trapping mechanism was quantitatively studied by a simulation code. The reactions causing trapping and deactivation are described. In addition, the boron markers approach was extended to the two dimensional (2D) diffusion. High resolution scanning capacitance microscopy was used for quantitative measurements of the 2D boron transient enhanced diffusion induced on a boron delta array by the I's ion beam ...
We calculate the structure of accretion disks around Kerr black holes for accretion rates 0.001 - 10 M_sun/s. Such disks are plausible candidates for the central engine of gamma-ray bursts. Our disk model is fully relativistic and treats accurately microphysics of the accreting matter: neutrino emissivity, opacity, electron degeneracy, and nuclear composition. The neutrino-cooled disk forms above a critical accretion rate that depends on the black hole spin. The disk has the ``ignition'' radius r_ign where neutrino flux rises dramatically, cooling becomes efficient, and the proton-to-nucleon ratio Y_e drops. Other characteristic radii are r_alpha where most of alpha-particles are disintegrated, r_nu where the disk becomes neutrino-opaque, and r_trap where neutrinos get trapped and advected into the black hole. We find r_alpha, r_ign, r_nu, r_trap and show their dependence on the accretion rate. We discuss the qualitative ...
We consider a Bose-Einstein condensate (BEC) of N atoms of repulsive interaction #approx# U_0, in an elliptical trap, axially pierced by a Gaussian-intensity laser beam, forming an effective (quasi-2D) toroidal trap with minimum at radial distance #rho# = #rho#_p. The macroscopic angular momentum states #PSI#_l(#rho#,#theta#) #approx# #sq root#N#PHI#_l(#rho#)e"i"l"#theta# for integer l spread up to #rho# > #rho#_p. The spreading lowers rotational energies, so estimated low metastability barriers can support large l < or approx. l_m_a_x #approx# (NU_0)"1"/"4, < or approx. 10 for typical parameters. The l-dependent density profile module #PHI#_l(#rho#)"2 -#PHI#_0(#rho#)"2 is a signature of BEC rotation. Results are insensitive to off-axis laser displacements #rho#_0, for #rho#_0 #rho#_m_a_x << 1. (author).
This report describes the cost, performance, and other key characteristics of an innovative technology for determining the presence or absence, and measuring the concentration, of volatile organic compounds (VOCs) and semi-volatile organic compounds (SVOCs) in groundwater and soil, and in gaseous remediation process streams at hazardous waste sites. This new technology is Direct Sampling Ion Trap Mass Spectrometry (DSITMS). DSITMS introduces sample materials directly into an ion trap mass spectrometer by means of a very simple interface, such as a capillary restrictor or a polymer membrane. There is typically very little, if any, sample preparation and no chromatographic separation of the sample constituents. This means that the response of the instrument to the analytes or contaminants in a sample is nearly instantaneous, and that analytical methods based on DSITMS are fast. Analyses are typically completed in less than five minutes, and the ...
Bacteriophage M13 mp10 DNA were irradiated with near-UV light in the presence of tetracycline derivatives and primed with synthetic oligonucleotide to be used for DNA synthesis using Escherichia coli DNA polymerase. Chain terminations were observed by denaturing polyacrylamide gel electrophoresis and mapped precisely. All the synthesis stops occurred before or at the level of guanine residues, showing that the photoreaction mediated by tetracycline derivatives led to a preferential alteration of guanine residues. These lesions were demonstrated to be induced in DNA through a pathway involving singlet oxygen. Tetracycline derivatives also photoinduced the breakage of the DNA sugar-phosphate backbone monitored by the conversion of supercoiled phi X174 DNA to a relaxed form. This lesion was shown to be initiated by hydroxyl radicals. The production of this free radical has been confirmed by electron paramagnetic resonance (EPR) spin trapping experiments using ...
Biological control agents can be more effective if their populations are genetically diverse, particularly when the target invasive plant comprises a range of genotypes with different susceptibilities and occurs across various microclimates. We report on the use of an efficient approach to find, in the native range, diverse isolates of a rust fungus for biological control. An outdoor trap garden containing various clones of invasive European blackberry (Rubus fruticosus agg.) collected in Australia, each with a different DNA phenotype, was established in France. Within 4?weeks of establishment, the leaf-rust fungus Phragmidium violaceum was recovered from all clones in the garden. Molecular analyses of eight recovered and purified isolates of the fungus from the garden revealed that they w...
PAMELA is a satellite borne experiment designed to study with great accuracy cosmic rays of galactic, solar, and trapped nature in a wide energy range (protons: 80 MeV-700 GeV, electrons 50 MeV-400 GeV). Main objective is the study of the antimatter component: antiprotons (80 MeV-190 GeV), positrons (50 MeV-270 GeV) and search for antinuclei with a precision of the order of $10^{-8}$). The experiment, housed on board the Russian Resurs-DK1 satellite, was launched on June, $15^{th}$ 2006 in a $350\\times 600 km$ orbit with an inclination of 70 degrees. In this work we describe the scientific objectives and the performance of PAMELA in its first two years of operation. Data on protons of trapped, secondary and galactic nature - as well as measurements of the December $13^{th}$ 2006 Solar Particle Event - are also provided.
A transient-enhanced diffusion has been observed during the furnace or rapid thermal annealing of ion-implanted silicon. We have studied this transient in detail and show that, for doses of Group V dopants sufficient to amorphize the silicon, it arises from the trapping of interstitials by dopant atoms during implantation. These are retained during solidphase-epitaxial (SPE) growth, but can be released by additional thermal processing to cause the observed transient and the formation of a band of extended defects. We have measured the enhanced diffusion coefficients and the duration of the transient for Sb-implanted Si by careful furnace annealing experiments. We obtain general expressions which predict the effects of the transient during any thermal processing based on SPE growth (furnace, CW laser, or rapid thermal annealing). We show that there is no analogous mechanism of vacancy trapping by Group III elements.
A transient-enhanced diffusion has been observed during the furnace or rapid thermal annealing of ion-implanted silicon. We have studied this transient in detail and show that, for doses of Group V dopants sufficient to amorphize the silicon, it arises from the trapping of interstitials by dopant atoms during implantation. These are retained during solidphase-epitaxial (SPE) growth, but can be released by additional thermal processing to cause the observed transient and the formation of a band of extended defects. We have measured the enhanced diffusion coefficients and the duration of the transient for Sb-implanted Si by careful furnace annealing experiments. We obtain general expressions which predict the effects of the transient during any thermal processing based on SPE growth (furnace, CW laser, or rapid thermal annealing). We show that there is no analogous mechanism of vacancy trapping by Group III elements.
Lead is known to enter substitutionally in divalent state when doped in alkali halides. When irradiated at room temperature these lead centers (Pb"+"+) act as traps for electrons knocked off from the halogen ions and become Pb"+ and Pb"0 (for large doses of irradiation). These changes could be followed in the optical absorption studies. These lead-doped crystals after X-ray irradiation yield a thermoluminescence output smaller than that observed in 'pure' crystals. However, two new glow peaks are observed in additions to those due to F-centers. In KCl : Pb and Kbr : Pb crystals part of the F-center glow preceds the new glow peaks. The new peaks are attributed to the Pb"+ and Pb"0 centers. The glow peak temperatures and trap depths for these peaks an obtained by total-curve fitting method are reported. (author).
The effects of the heating rate from 0.6 up to 50{sup o}C.s{sup -1} on the thermoluminescence of {alpha}-Al{sub 2}O{sub 3}:C are very intensive. The material rapidly loses its high sensitivity as the heating rate increases. The peak shape characteristics, peak maximum and full width at half maximum agree only qualitatively with those theoretically predicted. The trapping parameters calculated by the curve fitting method, the peak shape method, the variable heating rate method and the initial rise method, were found to decrease as the heating rate increases. The validity of the results are discussed in the framework of the kinetic models. (author).
The effects of the heating rate from 0.6 up to 50"oC.s"-"1 on the thermoluminescence of #alpha#-Al_2O_3:C are very intensive. The material rapidly loses its high sensitivity as the heating rate increases. The peak shape characteristics, peak maximum and full width at half maximum agree only qualitatively with those theoretically predicted. The trapping parameters calculated by the curve fitting method, the peak shape method, the variable heating rate method and the initial rise method, were found to decrease as the heating rate increases. The validity of the results are discussed in the framework of the kinetic models. (author).
The possibility of controlling the radial electric field of toroidal plasmas by injecting high energy electrons along the reversible loss cone orbit of the helical magnetic traps is investigated. It is well known that the radial electric field plays an important role in the confinement improvement scenario especially in the low collisional regime under the physics picture of neoclassical theory. For this purpose, it is made clear that the most suitable particles are transit particles, which show a transition from helically trapped orbits to blocked ones. It is also found that a parallel AC electric field launched from outside assists this transition and makes it possible for particles to penetrate deeply into the plasma. In addition we clarify that the viscosity of the plasma coupled with the helical field configuration provide a bifurcation of plasma states and its stable solution results in confinement improvement. (author)
In this paper a novel method is presented, based on the use of plasma processing, to suppress the transient enhanced diffusion of boron implanted in silicon. We found for silicon samples processed with plasma and subsequently boron implanted that the anomalous diffusion of the dopant atoms at the beginning of the annealing process is almost completely suppressed. This phenomenon is interpreted in terms of capture of the ion beam generated interstitials by the dislocations induced by the plasma processing. At room temperature the dislocations are observed to grow in size after the boron implant, attesting their efficiency as trapping centres for interstitials. Moreover, varying the plasma process conditions we can establish a general relation between the presence of the trapping centres induced by the plasma processing and the suppression of the transient diffusion.
In a series of recent papers, Corben recovered various properties of many hadronic resonances by considering them as compounds of a bradyon and of one (or more) tachyons. In this note it is explained why that success follows from considering the tachyon four-momenta orthogonal to the bradyon one, and why, in such a case, the bradyon and tachyons can be formally dealt with as non-interacting even when they keep participating in the ''self-trapping''. Finally an attempt is made to understand (on the basis of the model by Caldirola, Pavsic and Recami where hadrons are considered as ''strong black-holes'') why in general those compound hadrons decay and why in this decay the trapped tachyons are, quantum-mechanically, emitted in the corresponding bradyonic form.
The dynamic response of cylindrical and ring-shaped YBaCuO bulk parts to pulsed magnetic fields is calculated by using small sets of finite elements. Some comparisons with experimental results are provided, and they give confidence in the modelling of the superconducting properties. Transient magnetizations as a function of time and space as well as shapes and absolute values of trapped magnetic flux profiles are presented. The influence of the sample geometry is investigated for different millisecond pulsed magnetization processes. Results are reported for different radial thicknesses and heights, different pulse durations, peak magnetic fields and pulse sequences with and without stepwise cooling. Comparisons concerning the achievable trapped magnetic field and flux are made, and implications for the use of high-temperature superconductor bulk parts as cryo-permanent magnets in potential applications like electric machinery are discussed.
The effects of irradiation from a focused ion beam (FIB) system on MOS transistors are reported systematically for the first time. Three MOS transistor technologies, with 0.5, 1, and 3 {mu}m minimum feature sizes and with gate oxide thicknesses ranging from 11 to 50 nm, were analyzed. Significant shifts in transistor parameters (such as threshold voltage, transconductance, and mobility) were observed following irradiation with a 30 keV Ga{sup +} focused ion beam with ion doses varying by over 5 orders of magnitude. The apparent damage mechanism (which involved the creation of interface traps, oxide trapped charge, or both) and extent of damage were different for each of the three technologies investigated.
The multi-faceted research effort of the EBIT (Electron Beam Ion Trap) program in N-Division of the Physics and Space Technology Department at Lawrence Livermore National Laboratory (LLNL) continues to contribute significant results to the physical sciences from studies with low energy very highly charged heavy ions. The EBIT program attracts a number of collaborators from the US and abroad for the different projects. The collaborations are partly carried out through participating graduate students demonstrating the excellent educational capabilities at the LLNL EBIT facilities. Moreover, participants from Historically Black Colleges and Universities are engaged in the EBIT project. This report describes EBIT work for 1995 in atomic structure measurements and radiative transition probabilities, spectral diagnostics for laboratory and astrophysical plasmas, ion/surface interaction studies, electron-ion interactions studies, retrap and ion collisions, and ...
It has previously been shown that ensembles of terminated protograph-based low-density parity-check (LDPC) convolutional codes have a typical minimum distance that grows linearly with block length and that they are capable of achieving capacity approaching iterative decoding thresholds on the binary erasure channel (BEC). In this paper, we review a recent result that the dramatic threshold improvement obtained by terminating LDPC convolutional codes extends to the additive white Gaussian noise (AWGN) channel. Also, using a (3,6)-regular protograph-based LDPC convolutional code ensemble as an example, we perform an asymptotic trapping set analysis of terminated LDPC convolutional code ensembles. In addition to capacity approaching iterative decoding thresholds and linearly growing minimum distance, we find that the smallest non-empty trapping set of a terminated ensemble grows linearly with block length.
Many older homes are equipped with mercury-containing gas regulators that reduce the pressure of natural gas in the mains to the low pressure used in home gas piping. Removal of these regulators can...Full Text Available
Sewage gas or biogas as a product of anaerobic digestion contains methane and carbon dioxide as its main components. Biogas is scrubbed off carbon dioxide in absorption columns and purified to natural-gas quality. The purified gas then is piped to the gas pressure control station and fed into the public network. Description of process and plant is given.
We report the performance of a micro gas turbine on biomass producer gas and mixtures of biomass producer gas with natural gas. The micro gas turbine delivers full power on gas mixtures with a heating value of at least 15 MJ/Nm{sup 3}. For gas of lower heating value, the maximum fuel gas flow limits the attainable power. The lower limit for stable operation is about 8 MJ/Nm{sup 3}. The gross efficiency of the micro gas turbine depends on output power but not on the gas heating value, within our measurement accuracy. Above 70% of full power, emissions of CO and NO are 40 and 10 times lower than those of a gas engine of similar size. At part load below 70% of full power, the micro gas turbine burner switches to a different operating mode ...
The most effective way to generate electricity out of biomass is the gasification and the use of the gas in a gas engine. The conversion of the organic carbon with the gasification of biomass is higher than 95 %. Depending on the gasification concept, the efficiency of gasifiers is found between 70 and 90 %. If the pyrolysis gas is used in a gas engine, an electric efficiency of about 26 % referring to the primary amount of energy can be obtained. With efficient gas cleaning (cleaning for tar and dust), pyrolysis gas is well qualified for engine combustion. Through modern state of engine controlling there are ways to have complete control of the fluctuations in the gas composition. Furthermore, the minor calorific value of offered wood gas poses no problem for turbo charged lean-burn gas engines. ...
This patent describes an electrodeless lamp. It comprises: a microwave cavity; a source of microwaves in communication with the cavity; a lamp envelope containing a plasma-forming medium mounted within the microwave cavity; a gas manifold for feeding gas to at least one gas passageway for directing a stream of gas to the outer surface of the envelope; a gas leak passageway leading from the gas manifold; a conductive mesh assembly for retaining microwaves within the cavity and permitting light to be emitted from the cavity. The assembly including gas flow blocking means for preventing the flow of gas through the gas leak passageway when the screen is in place in the lamp; and means for shutting off the source of microwaves when the gas pressure in the manifold drops below a ...
We present the results of a comprehensive study of the temperature dependences of the quantum efficiency for ultraviolet detectors based on GaAs, GaP and 4H--SiC Schottky structures, and on Si, GaAs p-n structures. For ultraviolet detectors based on Schottky structures, the quantum efficiency increases with increasing temperature for all photon energies, even including the semiconductor intrinsic absorption region. On the other hand, for ultraviolet detectors based on p-n structures, the quantum efficiency is practically temperature independent in the semiconductor intrinsic absorption region. The change in the quantum efficiency for the GaAs and Si detectors is less than 0.01% per degree. To explain the measurements, a variable trap occupancy model is presented. Subsurface imperfections of the semiconductor cause fluctuations in the profile of the conduction band and the valence band edges. In the presence of an electric field in the space-charge region, these ...
We present the results of a comprehensive study of the temperature dependences of the quantum efficiency for ultraviolet detectors based on GaAs, GaP and 4H--SiC Schottky structures, and on Si, GaAs p-n structures. For ultraviolet detectors based on Schottky structures, the quantum efficiency increases with increasing temperature for all photon energies, even including the semiconductor intrinsic absorption region. On the other hand, for ultraviolet detectors based on p-n structures, the quantum efficiency is practically temperature independent in the semiconductor intrinsic absorption region. The change in the quantum efficiency for the GaAs and Si detectors is less than 0.01% per degree. To explain the measurements, a variable trap occupancy model is presented. Subsurface imperfections of the semiconductor cause fluctuations in the profile of the conduction band and the valence band edges. In the presence of an electric field in the space-charge region, these ...
Data of thermally stimulated luminescence (TSL) of single (Cu), double (Cu, Mn) and triple (Cu, Mn, Gd) activated SrS phosphors, which throws light on the nature and distribution of deeper traps have been presented. The samples are prepared by Bhawalkar's method and excited by UV 365 nm and #gamma#-rays to study the phenomenon. (author). 8 refs., 2 figs., 1 tab.
Stable strange quark matter produced in the QCD phase transition in the early universe will trap neutrons and repel protons, thus reducing primordial helium production, Ysub(p). For reasonable values of Ysub(p), the radius of strange droplets must exceed 10/sup -6/ cm if strange matter shall solve the dark-matter problem without spoiling Big Bang helium synthesis. (orig.).
Stable strange quark matter produced in the QCD phase transition in the early universe will trap neutrons and repel protons, thus reducing primordial helium production, Ysub(p). For reasonable values of Ysub(p), the radius of strange droplets must exceed 10/sup 6/ cm if strange matter shall solve the dark-matter problem without spoiling Big Bang helium synthesis. (orig.).
In this work the diffusion of ion-beam-injected self-interstitials (Is) and their interaction with impurities in crystalline Si are presented. In particular, the I penetration into a molecular beam epitaxy grown Si structure was studied by means of diffusion effects induced on B spikes, analyzed by a developed simulation code. Trapping effects at sample-surface and bulk are evidenced and modeled. The B marker approach was extended to the two-dimensional (2D) I-diffusion occurring as a consequence of ion implantation through a sub-micron dimension patterned oxide mask. I-source size effects on the I penetration have been found and modeled, quantitatively describing the 2D I-diffusion. The I-substitutional carbon interactions have been also studied, showing the C ability to effectively retain Is. The I-trapping mechanism was quantitatively studied by the simulation code, showing that one I is able to deactivate about two C ...
Recent results of experimental and theoretical investigations, carried out in the Institute of plasma Physics of the NSC KIPT, are presented in the report. The main problems of discussion are as follows: plasma confinement and heating in stellarators and electromagnetic traps; powerful quasi-steady-state plasma accelerators (QSPA); experiments relevant for ITER; fusion Plasma theory; methods of high temperature plasma diagnostics; plasma technology. The main prospects on the IPP investigators are discussed also.
Ethyl azidoformate reacts, on thermolysis with acenaphthylene, to give a 1:2 adduct involving sequential aziridine formation, ring-opening to a 1,3-dipolar pyridinium-2,6-betaine, and trapping of the dipole with acenaphthylene. The structure of the adduct was confirmed by X-ray crystallography.
We will examine modeling data for various orbits using modeling software and compare this with actual satellite flight result. In particular, we will discuss the contributions of trapped protons to total dose and the effectiveness of shielding.
We propose a scheme for the generation of the cluster states for many atoms in cavity QED. In our scheme, the atoms are sent through nonresonant cavity fields in the vacuum states. The cavity fields are only virtually excited and no quantum information will be transferred from the atoms to the cavity fields. The advantage is that the cavities are suppressed during the procedure. The scheme can also be generalized to the ion trap system.
Penning trap mass spectrometry is presented as a complementary tool to nuclear spectroscopy experiments for the study of nuclear structure in the vicinity of N=40, Z=28. High-precision mass measurements of the "6"3"-"6"6Fe and "6"4"-"6"7Co isotopes have been carried out with the Low Energy Beam and Ion Trap (LEBIT) Penning trap mass spectrometer. The newly obtained mass values for "6"6Fe and "6"7Co are presented, together with the previously reported LEBIT mass measurements in this region. In the case of "6"5Fe the existence of a new isomer is reported, and an isomer recently discovered by decay spectroscopy in "6"7Co is confirmed. Relative mass uncertainties as low as 4x10"-"8 are obtained. All mass values are found to be in good agreement with previous experimental results with the exception of "6"4Co, where a 5#sigma# deviation is observed. Using these data the two neutron separation energies S_2_n are calculated. ...
The lowest excited level in Ni-like ions, 3d{sup 9}4s {sup 3}D{sub 3}, decays only via a magnetic octupole (M3) decay. They present calculated values of transition wavelengths and rates for ions with 30 {le} Z {le} 100. They have observed this line in Xe{sup 26+}, using the Livermore EBIT-I electron beam ion trap and a microcalorimeter, as well as a high-resolution flat-field grating spectrometer.
We study the possibility of utilizing the superfluid to Mott-insulator quantum phase transition in an array of quantum well exciton-polariton traps to generate indistinguishable single photons in a massive parallel fashion. By means of analytical and numerical methods, the device operations and system properties are examined using realistic experimental parameters. Such a deterministic, massive parallel generation may find new applications in photonic quantum information processing.
HIPDM is an "1"2"3I-labeled agent with a distribution in brain reflecting regional perfusion. This compound is neutral and lipid soluble at blood pH and freely crosses the blood-brain barrier. At the lower pH in brain, it picks up a hydrogen ion and becomes positively charged. In this form the molecule is not lipid soluble and it is trapped in brain.
The influence of MeV electrons irradiation on the gate oxide layers of hydrogenated polysilicon thin film transistors (TFTs) was investigated by measuring gate leakage currents and threshold voltages. The experimental data revealed a decrease of oxide trap density and increase of positive oxide charge. Improvement in the interface roughness and in the oxide quality near the bottom interface was observed.
The influence of MeV electrons irradiation on the gate oxide layers of hydrogenated polysilicon thin film transistors (TFTs) was investigated by measuring gate leakage currents and threshold voltages. The experimental data revealed a decrease of oxide trap density and increase of positive oxide charge. Improvement in the interface roughness and in the oxide quality near the bottom interface was observed.
We have performed precision measurements in a magneto-optical trap of the 7P1/2 hyperfine structure of the isotopes 209-210Fr. The ratio of these hyperfine constants to the previously measured 7S1/2 ground state values reveals a significant hyperfine anomaly. This anomaly results from the different radial dependence of the electron density in the two atomic levels. The measurements are sensitive to changes in the radial distribution of the neutron magnetism.
Fe, Mn, Ni, V, Ti and Mo were determined in aerosols from manual arc welding. Samples of welding aerosols were trapped on a Synpor 4 filter. The amount of determined elements in aerosols was detected using the method of radionuclide X-ray fluorescence analysis. A /sup 241/Am annular source was used as the source of excitation radiation and radiation was processed using a Si(Li) spectrometer.
Fe, Mn, Ni, V, Ti and Mo were determined in aerosols from manual arc welding. Samples of welding aerosols were trapped on a Synpor 4 filter. The amount of determined elements in aerosols was detected using the method of radionuclide X-ray fluorescence analysis. A "2"4"1Am annular source was used as the source of excitation radiation and radiation was processed using a Si(Li) spectrometer. (E.S.).
Since the integrity of the containment penetrations was confirmed under accident management (AM) conditions in the former test, failure criteria tests and aerosol trapping tests were carried out using low-voltage modules and flange gaskets of an actual plant under severe accident (SA) conditions, without AM. The safety margin for failure temperature of the penetrations and the credit for fission product (FP) aerosol trapping effect along the leakage paths of the degraded penetrations were evaluated in the present tests. Failure temperature of the penetrations ranged from 270 to 300degC for low-voltage modules and 300 to 350degC for flange gaskets under 0.4 to 1.0 MPa conditions. Pressure dependency on failure temperature was small. This means that the safety margin of failure temperature under AM condition is more than 70degC. By introducing a equivalent leak area for the damaged test pieces, total leak area was estimated which was smaller than ...
The influence of RTA (Rapid Thermal Anneal) treatment on MOS radiation hardness is demonstrated and compared with classical furnace treatment. In the case of the RTA, the oxide trapped charge is found to depend on: (i) the anneal temperature as expected, data are in good agreement with a recently developed model of oxygen out-diffusion; (ii) the location across the wafer with a radial dependence, results could be related to stress induced by thermal gradient.
Results from scanning electron microscopy, Fourier transform infrared spectroscopy and the measurement of thermally stimulated current show that a high density of the physical defects and the chemical defects are introduced into the surface of the silicone rubber plates after they are treated by corona discharge plasma. These defects behave electrically as shallow electron traps, leading to the formation of a uniform discharge in air at higher pressure when the corona-modified silicone rubber is used in dielectric barrier discharge.
A continuous-flow filter/concentrator for separating and/or concentrating particles in a fluid is disclosed. The filter is a three-port device an inlet port, an filter port and a concentrate port. The filter separates particles into two streams by the ratio of their dielectrophoretic mobility to their electrokinetic, advective, or diffusive mobility if the dominant transport mechanism is electrokinesis, advection, or diffusion, respectively.Also disclosed is a device for separating and/or concentrating particles by dielectrophoretic trapping of the particles.
A new technique is described in this paper for a general active radio frequency (RF) filter trap that can be used for suppressing noise or interference on high voltage (HV) transmission lines. The technique exploits the Miller effect of an RF amplifier in conjunction with a special sensing circuit, and is potentially far more economical to implement than conventional techniques that use passive HV filter components.
A description is given of an automatic liquid nitrogen pumping system. Pamping of liquid nitrogen iato cooling traps up to a predetermined level is achieved by an automatically controlled compressed air system. An impontant feature of the equipment is the ability to switch automatically from an empty liquid nitrogen reservoir to a full one. This allows for a much more flexible operation than in conventional systems where the reservoir has to be replaced manually when empty. (auth)
Appendices to this summary consist of twelve individual status reports that will be available through the National Technical Information Service (NTIS) in the United States and of course limited copies will be available through NATO. The twelve report titles which are appendices to the summary are: (A) Status Report on the Limestone/Sludge Flue Gas Desulfurization Process; (B) Status Report on the Lime/Sludge Flue Gas Desulfurization Process; (C) Status Report on the Double Alkali/Sludge Flue Gas Desulfurization Process; (D) Status Report on the Sea Water Scrubbing Flue Gas Desulfurization Process; (E) Status Report on the Limestone/Gypsum Flue Gas Desulfurization Process; (F) Status Report on the Lime/Gypsum Flue Gas Desulfurization Process; (G) Status Report on the Double Alkali/Gypsum Flue Gas Desulfurization Process; (H) Status Report on ...
Gas hydrates have impacted the oil and gas industry since 1934, when they were first found to plug pipelines. Today we know that in deep oceans and in permafrost, very substantial gas reserves are present in hydrated form. Concerns are being raised about in situ dissociation for both energy and greenhouse implications upon methane release. In Japan work is underway to consider the storage of carbon dioxide, concentrated in clathrates. This talk will deal with some basic questions. Why should we be interested in gas hydrates? What are gas hydrates? How do gas hydrates form? How might hydrates impact on the energy/environmental picture?
This book discusses the progress and problems of current interest in gaseous dielectrics and their use, with special emphasis on insulation in high-voltage transmission lines and substations. Topics covered include: basic physics of gaseous dielectrics; basic mechanisms; gas decomposition, reactions and toxicity; diagnostics and field probes; gases and mixtures for GIS transformers and circuit breakers; gaseous media for discharge chemistry and etching/corona; gas engineering for pulsed power and switching; gas breakdown under steep-fronted voltages; new developments in gas-insulated equipment and gas handling; gas/insulator interface/flashover; and quality control in testing gas-insulated equipment. Contains approximately 85 papers.
Gas hydrates are crystalline substances composed of water and gas, in which a solid-water-lattice accommodates gas molecules in a cage-like structure. Gas hydrates are globally widespread in permafrost regions and beneath the sea in sediment of outer continental margins. While methane, propane, and other gases can be included in the clathrate structure, methane hydrates appear to be the most common in nature. The amount of methane sequestered in gas hydrates is probably enormous, but estimates are speculative and range over three orders of magnitude from about 100,000 to 270,000,000 trillion cubic feet. The amount of gas in the hydrate reservoirs of the world greedy exceeds the volume of known conventional gas reserves. Gas hydrates also represent a significant drilling and production hazard. A fundamental question ...
Gas hydrates are crystalline substances composed of water and gas, in which a solid-water-lattice accommodates gas molecules in a cage-like structure. Gas hydrates are globally widespread in permafrost regions and beneath the sea in sediment of outer continental margins. While methane, propane, and other gases can be included in the clathrate structure, methane hydrates appear to be the most common in nature. The amount of methane sequestered in gas hydrates is probably enormous, but estimates are speculative and range over three orders of magnitude from about 100,000 to 270,000,000 trillion cubic feet. The amount of gas in the hydrate reservoirs of the world greedy exceeds the volume of known conventional gas reserves. Gas hydrates also represent a significant drilling and production hazard. A fundamental question ...
We report the performance of a commercial recuperated micro gas turbine on biomass producer gas and mixtures of biomass producer gas with natural gas. The biomass producer gas, obtained by gasification at 850{sup o}C with air at atmospheric pressure, contains about 7% H2, 17% CO, 15% CO2, 4% CH4, 2% other hydrocarbons, 2% H2O, and a balance of N2 and Ar from air. It has a net heating value of about 6 MJ/(Nm{sup 3}). The micro gas turbine delivers full power (30 kW{sub e}) on gas mixtures with a net heating value of at least 15 MJ/(Nm{sup 3}). For gas of lower heating value, the maximum fuel gas flow allowed by the fuel control unit limits the attainable power. At reduced power, the lower limit for stable operation is a net heating value of about 8 MJ/(Nm{sup 3}). The gross efficiency of the micro ...
The situation of natural gas in the Federal Republic of Germany is described, with particular emphasis on the advantages and consequences of natural gas supply. The brochure discusses the role of natural gas on the energy market, the reliability of natural gas supply, the environmental impacts, the energy-saving effect of natural gas, natural gas prices, the competitive strength of the German gas industry, and the long-term reliability of natural gas supply. (orig.) [German] Die Situation des Erdgases in der Bundesrepublik Deutschland wird beschrieben, wobei die wichtigsten Vorteile und Auswirkungen der Erdgasversorgung besonders hervorgehoben werden. Es geht um die Stellung des Erdgases im Energiemarkt, die Sicherheit der Energieversorgung, Umweltschutz, Energieeinsparung durch Erdgaseinsatz, Erdgaspreise, ...
Effects of combustion conditions on the critical calorific value of flame blowout were reported for low calorific gas on the assumption of using coal derived gaseous fuel. Further, calculations of adiabatic flame temperature by using chemical equilibrium calculation were conducted in order to get a possibility of increasing exit gas temperature of gas turbine combustor to 1,300 C for low calorific value gas fuel. As a result, effects of (1) fuel composition, (2) preheating fuel temperature, (3) calorific value, and (4) combustion air velocity and fuel nozzle diameter, on the critical calorific values of flame blowout were clarified. In increasing exit gas temperature of gas turbine combustor to 1,300 C when using low calorific value gas fuel, it is essential to get an advanced cooling technology for the gas turbine ...
The genetic type, source and charging history of natural gas in the Yulin gas field in the Ordos Basin have been studied by combining the carbon isotopic composition of natural gas and geochemical characteristics of light hydrocarbons with carbon isotope fractionation model results and fluid inclusion analysis. The carbon isotopic composition of methane and ethane in the Yulin gas field is relatively enriched in {sup 13}C with {delta}{sup 13}C{sub 1} values ranging from - 35.3 permille to - 29.8 permille (average value = - 32.4 permille) and {delta}{sup 13}C{sub 2} ranging from - 26.3 permille to - 23.5 permille (average value = - 24.8 permille). The C{sub 7} light hydrocarbons are predominated by methylcyclohexane, accounting for 65.8% to 80.9% (average value = 71.6%), which is characteristic of coal-derived gas. Furthermore, the gas geochemistry indicates ...
The production, principal applications, characteristics and properties, advantages of the gas natural is showed. A sectorial overview of the ceramic industry and the utilization of the natural gas in the ceramic industry is presented. The expectations are systematized and the impact of the natural gas utilization in the ceramic industry is evaluated. Some conclusions are withdrawn and recommendations suggested.
A combined gas/steam turbine process includes a high-pressure furnace and a high pressure gasification unit with a mounted upstream of a combustion chamber there is a gas turbine with a waste heat system. Combustion heat which is not needed to heat the flue gas to combustion temperature is released from the furnace and transferred to ths combustion air going into the combustion chamber.
Nomographs have been developed to simplify site performance estimates for various types of gas turbine engines used for industrial applications. The nomographs can provide valuable data for engineers to use for an initial appraisal of projects where gas turbines are to be considered. General guidelines for the selection of gas turbines are also discussed. In particular, site conditions that influence the performance of gas turbines are described.
The budding natural gas markets in East Europe attract a great deal of interest from natural gas industries in the Western countries. Dutch companies, institutions and the government, too, are active in this market. So far the results have not been spectacular. An analysis is made of the present situation and the Dutch approach
This article puts the case for coal fired combined cycle gas turbine (CCGT) power plants. The need to gasify the coal for the CCGT, use of fluidised bed combustors or gasification systems, the difference in prices of coal and natural gas, and coal and natural gas reserves are discussed. (UK)
Natural gas is essential to the world economy. Gas now accounts for almost a quarter of OECD primary energy requirements and is expected to become the second most important fuel in the world in the next decade. Industrial and residential consumers increasingly rely on natural gas to keep their houses warm, their lights on and their factories running. Meanwhile the gas industry itself has entered a new phase. Where gas used to be restricted to regional markets, it is now increasingly traded on a global scale. While gas production and transport requires long-term investment, now it is optimised on a short-term basis. Demand continues to grow, but local gas production has become much more expensive. How should we react? How will demand be satisfied? What changes are required to promote flexibility and trade? What are the implications for ...
Mist eliminators for flue gas desulphurisation units remove liquid droplets entrained in the flue gas leaving the SO/sub 2/-absorber vessels. The commercial designs currently available are described.
The purpose of this project was to build a long-range, parallel hybrid gas/electric vehicle capable of driving beyond the communter capabilities of series hybrid vehicles. It was envisioned that since the gas engine would be able to independently propel t...
Radon-222 has been measured in natural gas produced from experimental geopressured-geothermal test wells. Comparison with published data suggests that while radon activity of this unconventional natural gas resource is higher than conventional gas produced in the gulf coast, it is within the range found for conventional gas produced throughout the US. A method of predicting the likely radon activity of this unconventional gas is described on the basis of the data presented, methane solubility, and known or assumed reservoir conditions of temperature, fluid pressure, and formation water salinity.
BackgroundEmphysematous cholecystitis is a variant of acute cholecystitis which is generally caused by gas-forming organisms. Emphysematous cholecystitis may cause gas spreading...Full Text Available
... Accession Number : ADD135818. Title : Performance of Titanium in Flue Gas Desulfurization Scrubber Systems,. Descriptive Note : Journal Article,. ...
The properties of the ideal gas of classical (nonquantum) tachyons are considered. Starting from the definition of thermodynamic functions for this system, it may be found that tachyons and bradyons gases are similar. (AA).
A new surveillance system for Oil-Filled cable, which can provide continuous monitoring, using a newly developed optical gas sensor that can detect the concentration of the gas dissolved in the oil with extremely high sensitivity has been developed. It was proved that the degree of deterioration of the insulating oil can be detected by measuring C{sub 2}H{sub 2} and CH{sub 4} by investigating the relation between the degree of deterioration and amount of combustible gas generated. In order to detect extremely small amounts of gas, a new gas detecting method using absorption line of the gas using a frequency modulated technique has been developed. The gas detection ability was also confirmed by examination using a 66 kV of cable and the possibility of detection at an early stage is expected.
Rapid technology improvements, resulting in high efficiency, emissions reduction and low generation cost, are making gas turbines the generation technology of choice despite some recent reliability problems. The basic reason for the dominance is high efficiency. The rapid pace of gas-turbine technology improvement in the 1990s drove combined-cycle thermal efficiency to nearly 60 percent with natural gas as the fuel. It will probably go even higher after the year 2000. In addition, the gas-fired combined cycle is a bargain. With natural gas prices where they are right now, it is the least-cost generation operation for power producers with access to gas. Many will replace older, high-cost power plants with new gas-fired combined cycle power plants.
The oxygen production of a photosynthetic gas exchanger containing Chlorella pyrenoidosa (1% packed cell volume) was measured when various concentrations of carbon dioxide were present...Full Text Available
The purpose of this publication is to provide a better understanding of flue gas desulfurization. It provides brief answers to questions concerning its applicability, cost, effectiveness, and operation.
This bibliography contains 3920 references including abstracts, to information on the technology of flue gas desulfurization and denitrification. These references and others are included in the Department of Energy's Energy Data Base (EDB) through Decembe...
Tests to measure the maximum horsepower of commercial vehicles converted for use with natural gas fuel indicate a reduction of approximately 20% in horsepower compared with gasoline-driven vehicles. This reduction in horsepower resulting from the use of gas is due basically to the lower thermal efficiency of the cycle of natural gas compared with that of gasoline and to its lower volumetric efficiency, since natural gas is injected into the combustion chamber in gaseous form, unlike gasoline, in which part of the fuel entering the cylinder is in the liquid phase. Natural gas used as a fuel generates lower quantities of air pollutants, particularly unburned hydrocarbons (HCs) and carbon monoxide (CO). Despite the downside of reduced horsepower, the use of natural gas as a fuel for automotive vehicles equipped with Otto-cycle engines is economically viable owing ...
K"#pi#=20"- and 49/2"- yrast isomers have been discovered in "1"7"6Ta and "1"7"7Ta, with meanlives of 1.4 ms and 0.19 ms, respectively. The long meanlives arise from substantial K-hindrance in the "1"7"6Ta case but from spin-trapping in the "1"7"7Ta case. Quasiparticle calculations, which treat the Fermi and pairing energies self-consistently, reproduce the excitation energies of these isomers and the other multi-quasiparticle high-K states observed. Due to blocking, pairing is significantly reduced in the 3-quasiparticle states, the extent depending on the specific configurations. It is completely quenched for both protons and neutrons in the highest seniority states. Yrast traps of even higher spin are predicted to exist in "1"7"6Ta and "1"7"7Ta. ((orig.)).
Implanted B and P dopants in Si exhibit transient enhanced diffusion (TED) during initial annealing which arises from the excess interstitials generated by the implant. In order to study the mechanisms of TED, the authors have used B doping marker layers in Si to probe the injection of interstitials from near-surface, non-amorphizing Si implants during annealing. The in-diffusion of interstitials is limited by trapping at impurities and has an activation energy of {approximately}3.5 eV. Substitutional C is the dominant trapping center with a binding energy of 2--2.5 eV. The high interstitial supersaturation adjacent to the implant damage drives substitutional B into metastable clusters at concentrations below the B solid solubility limit. Transmission electron microscopy shows that the interstitials driving TED are emitted from {l_brace}311{r_brace} defect clusters in the damage region at a rate which also exhibits an activation energy of 3.6 ...
Implanted B and P dopants in Si exhibit transient enhanced diffusion (TED) during initial annealing which arises from the excess interstitials generated by the implant. In order to study the mechanisms of TED, the authors have used B doping marker layers in Si to probe the injection of interstitials from near-surface, non-amorphizing Si implants during annealing. The in-diffusion of interstitials is limited by trapping at impurities and has an activation energy of #approx#3.5 eV. Substitutional C is the dominant trapping center with a binding energy of 2--2.5 eV. The high interstitial supersaturation adjacent to the implant damage drives substitutional B into metastable clusters at concentrations below the B solid solubility limit. Transmission electron microscopy shows that the interstitials driving TED are emitted from #left brace#311#right brace# defect clusters in the damage region at a rate which also exhibits an activation energy of 3.6 ...
A strong dependence of thermal activation energy (TAE) on infrared (IR) stimulation time for the infrared stimulated luminescence (IRSL) signal was observed for K-feldspar grains extracted from several sediments and granites from China. A TAE value as low as {approx}0.1 eV was observed at the beginning of IR stimulation and increased to {approx}0.45 eV after 90 s. For a trap depth of {approx}2 eV below the conduction band for the IRSL traps, the TAE value of {approx}0.45 eV is consistent with the energy gap between the excited states ({approx}0.5 eV below the conduction band) and conduction band. This phenomenon is explained as the result of the coexistence of thermally assisted recombination via conduction band or band-tail states hopping and athermal tunnelling recombination of electrons from the excited states under IR stimulation, leading to the observation of a higher anomalous fading rate in the initial part of the IRSL decay curve.
The deep water parts of the Moere and Southern Voering Basins are large frontier areas, which are considered to contain significant undiscovered hydrocarbon resources, within Cretaceous and Paleogene reservoirs. PGS Reservoir AS have evaluated the Cretaceous and Paleogene successions of the shallow and deep water areas offshore Mid-Norway using high-resolution sequence stratigraphic techniques. The successions have been subdivided into about 20 stratigraphic sequences. The results are: (1) A more acurate and higher resolution stratigraphy, (2) Greater constraints on basin palaeoenvironmental and palaeogeographic reconstructions, (4) Fully integrated sandstone fairway models, with increased ability to reservoir and seal quality and continuity, (5) In addition to several obvious giant domal traps, subtler yet significant structural and stratigraphic leads and prospects can be identified, (6) The timing, volume and phase of hydrocarbon generation may be estimated more ...
Thallium-201 diethyldithiocarbamate (DDC) behaves like a chemical microsphere and is trapped by spontaneous decomposition in the brain in proportion to regional perfusion. They have shown that the technetium-99m analog, Tc-99m DDC (1), is unsuitable for cerebral perfusion imaging because it does not decompose rapidly enough to be trapped in the brain. With the goal of turning this greater stability of 1 into an advantage, a series of dithiocarbamates with lipophilic or amine groups designed to enhance cerebral uptake and retention was prepared from the following amines by reaction with carbon disulfide and sodium hydroxide: pyrrolidine (2), piperazine (3), 4-benzylpiperazine (4), and 4-(1-piperidino)piperidine (5). These ligands (5 mg) were labelled with Tc-99m in > 95% efficiency (ITLC-SG, saline) by reduction of pertechnetate at room temperature with formamidine sulfinic acid at alkaline pH. In preliminary studies, 4 and 5 show a trend of ...
The spectral dependences of absorption photoinduced in a pure bismuth titanium oxide crystal by 532-nm laser pulses are studied. It is shown that optical absorption in the crystal in the range from 492 to 840 nm increases with increasing exposure. The photoinduced absorption relaxes in the dark for more than 60 hours. A model of photoinduced absorption is proposed which assumes the population of two trap centres with the normal energy distribution law for the concentrations of electrons photoexcited from donors to the conduction band. This model well describes the spectral dependences of photoinduced absorption by using the average ionisation energies of the traps E{sub 1} = 1.60 eV and E{sub 2} = 2.57 eV. The model is used to estimate the increase in the photorefractive sensitivity of a bismuth titanium oxide crystal in the near IR region, which was earlier observed after exposing the crystal to visible radiation. It is predicted that the ...
An attempt to determine lysozyme hydration by employing a proton nuclear magnetic resonance (NMR) spin-echo technique and to correlated such measurements with the 20 "0C sorption equilibrium data is made. Determinations of specific site hydration for lysozyme, as well as proton NMR transverse relaxation rates for five different types of water populations in the lysozyme-water system, are presented over the whole range of lysozyme concentrations. The proton spin-echo NMR results are consistent with a three-component analysis of the sorption isotherm up to 70% water content, above which two additional water populations are identified by 360-MHz proton NMR spin-echoes. On the basis of the proton NMR results, a major component (III) of the lysozyme sorption isotherm is assigned to the water trapped between lysozyem molecules, whose relaxation rate is increased by diffusion barriers. The trapped water population dominates the relationship between ...
Sediment trap fluxes of solids, organic carbon, polycyclic aromatic hydrocarbons (PAHs), and polychlorinated biphenyls (PCBs) were measured in Lake Superior in 1984 and 1985. Mass fluxes from surface waters ranged from 0.14 to 1.1 g/m{sup 2}{center dot}day and increased near the lake floor due to resuspension of surficial sediment and horizontal transport in the benthic nepheloid layer. Organic matter fluxes from surface water ranged from 60 to 90 mg of C/m{sup 2}{center dot}day, with {approximately}5% of organic carbon settling from surface waters accumulating in bottom sediments. Concentrations of PCBs and PAHs are enriched 10-100 times on settling particles relative to those on suspended particles. Resultant settling fluxes are 10-100 times greater for several PCB and PAH compounds than net accumulation rates in bottom sediments, indicating the effective and rapid recycling in the benthic region. Biological packaging of organic pollutants into rapidly settling ...
The recent development of matrix-assisted UV laser desorption (LD) mass spectrometry has made possible the ionization and detection of extremely large molecules (with molecular weights exceeding 100,000 Daltons). This technique has generated enormous interest in the biological community for the direct examination of large peptides and oligonucleotides. Although this matrix-assisted ionization method has been developed and used almost exclusively with time-of-flight (TOF) mass spectrometers, research is currently in progress to demonstrate this technique with trapped ion mass spectrometers, such as Fourier transform ion cyclotron resonance mass spectrometry (FTMS). The potential capabilities of FTMS for wide mass range, high resolution measurement, and ion trapping experiments suggest that this instrumental technique should be useful for the detailed structural characterization of large ions generated by the matrix-assisted technique. We have ...
We used the recuperation effect (see also 'Recuperation of infrared stimulated luminescence of feldspars' in this issue) for investigating the connection between infrared- and greenlight-stimulated luminescence (IRSL and GLSL) of feldspars by performing a 'double-bleach recuperation' experiment. A diode system was used for infrared (IR) stimulation, and a filtered-light unit for greenlight (GL) stimulation. Powdered feldspar samples (2 mg each) of known chemical characterisation from a mineral collection were used. After beta-irradiation with 180 Gy and storage in the dark for several weeks feldspar aliquots were bleached down to a residual level of {approx}1% of the initial level, first with IR and subsequently with GL. For both stimulations, detection of the stimulated luminescence was carried out in the near ultraviolet region (around 260-360 nm, peaked at 340 nm). Other aliquots were bleached in reverse order (1st GL, 2nd IR). These bleaching ...
We used the recuperation effect (see also 'Recuperation of infrared stimulated luminescence of feldspars' in this issue) for investigating the connection between infrared- and greenlight-stimulated luminescence (IRSL and GLSL) of feldspars by performing a 'double-bleach recuperation' experiment. A diode system was used for infrared (IR) stimulation, and a filtered-light unit for greenlight (GL) stimulation. Powdered feldspar samples (2 mg each) of known chemical characterisation from a mineral collection were used. After beta-irradiation with 180 Gy and storage in the dark for several weeks feldspar aliquots were bleached down to a residual level of #approx#1% of the initial level, first with IR and subsequently with GL. For both stimulations, detection of the stimulated luminescence was carried out in the near ultraviolet region (around 260-360 nm, peaked at 340 nm). Other aliquots were bleached in reverse order (1st GL, 2nd IR). These bleaching sequences were also applied to ...
Objective: To study the effects of minocycline hydrochloride (MINO) on the formation of tartrate-resistant acid phosphatase (TRAP) staining-positive multinucleated osteoclast-like cells in mouse bone marrow cells (BMCs) treated with 1@a,25(OH)"2D"3 or soluble receptor activator of nuclear factor-@kB ligand (s-RANKL). Materials and methods: Mouse BMCs were cultured in alpha-modified minimum essential medium containing foetal calf serum (10%) and tetracyclines (2.5, 5 and 10@mM), such as MINO, tetracycline hydrochloride (TC), oxytetracycline hydrochloride (OXT) or doxycycline (DOXY) in the presence of 1@a,25(OH)"2D"3 (10nM) or s-RANKL (20ng/ml) for 7 days, and the number of TRAP staining-positive osteoclast-like cells was counted. In RNA isolated from BMCs treated with 1@a,25(OH)"2D"3 or s-R...
The authors investigated the harmful effect of compound grease on premium connections. The pressure buildup of compound grease trapped between threads was measured during and after makeup of the connection. The resulting hoop stress in the coupling and the reduction in the seal interference were also measured. Mathematical models were developed to calculate coupling stress and grease pressure. Results indicate that for the conventional API buttress-thread profile, the pressure of trapped compound grease remains permanently high after the connection is made up because of the small thread-clearance area. This high pressure results in a high coupling stress and a large reduction in seal interference diameter, thereby degrading the integrity of the connection. To solve this problem, the thread profile was redesigned with a thread-clearance area larger than that of conventional buttress thread. The connection with the new thread design showed a ...
We describe a method for the analysis of multi-site phosphorylation in serine/threonine (Ser/Thr)-rich protein sequences. Site-specific mutagenesis was used to introduce tryptic cleavage sites in the serine glutamine/threonine glutamine cluster domain (SCD) of the human checkpoint protein kinase (Chk2). The mutant proteins were shown to autophosphorylate on residues that are inducibly phosphorylated when mammalian cells are exposed to ionizing radiation (serine 33/35, serine 516, threonine 68 and threonine 432). Five Ser/Thr clusters within the SCD were flanked by arginine or lysine residues to produce tryptic peptides for nanospray liquid chromatography (nanoLC)/linear quadrupole ion trap Fourier transform ion cyclotron resonance mass spectrometry. Phosphorylation sites were assigned usin...
The transport properties of a 'thin' polycrystalline diamond film are analyzed after the sample exposure to 8.06-keV x-ray radiation. Structure and morphology of the as-grown film have been evaluated by Raman, x-ray diffraction, and scanning electron microscopy techniques. The transport properties have been investigated by measuring dark current-voltage characteristics in the temperature range of 60 to 360 K. Ohmic transport has been evidenced on the as-grown film up to 1.16x10"5 V/cm. After irradiation, nonlinear contributions to the dark current have been evidenced and related to field-assisted thermal ionization of traps. Below 200 K, hopping mechanisms have been observed. Correlations have been found among x-ray irradiation, density of traps involved in the transport processes, and the nonhomogeneous nature of the sample. A simple model of the grain boundary structure is proposed to explain the observations.
A good knowledge of medfly population dynamics is necessary to control it. Population dynamics are being studied by means of the Jackson trap with trimedlure attractant (male, sex-pheromone). Weekly sampling of wild medfly populations was started in June at Aabde and in August at Sour and Jbeil. Trap surveys of medfly density will be carried for at least one year before sterile males releases are started against a long-established infestation. Since populations can vary with season and in different parts of an infested area. Knowledge of this variation is needede to determine when releases should start, because they should begin, just after or during a population decline. Field evaluation will include, ecological data on medfly population distribution number, host preference, and medfly overwintering. Surveys of medfly adults and larvae, host species, and phenology, temperature and medfly history, all will be used to guide the control program, ...
Electron trapping in crossed electric and magnetic fields is an important mechanism by which electrical discharges can develop in low pressure gases. The authors report observations of discharges produced by this mechanism around a spherical anode in two space simulation chambers, namely the Space Plasma Interaction Experiment (SPIE) at the University of Maryland, and the NASA-Lewis B-2 chamber. They have identified two types of discharges in these experiments. In the B-2 chamber, the breakdown takes the form of a runaway dischage with spherical topology, limited only by the ability of the power supply to provide the current. In the SPIE chamber this type of discharge also occurs, in addition to a low current toroidal discharge which is observed at higher magnetic fields. They present measurements of both types of discharge and show how the trapping effect of the magnetic field together with secondary electron emission by high energy ion ...
The magnetic separation technology using sub-microsized ferromagnetic particle is indispensable in many areas of medical biosciences. For example, ferromagnetic particles (200-500 nm) are widely used for cell sorting in stem cell research with the use of cell surface-specific antigens. Nanosized ferromagnetic particles (10-20 nm) have been suggested as more suitable in drug delivery studies given their efficiency of tissue penetration, however, the magnetic separation method for them has not been established. One of the major reasons is that magnetic force acting on the object particles decreases drastically as a particle diameter becomes small. In this study, magnetic force acting on the targets was enhanced by the combination of superconducting magnet and the filter consisting of ferromagnetic particle. By doing so, we confirmed that Fe{sub 3}O{sub 4} of 20 nm in diameter was trapped in the magnetic filter under an external magnetic field of 0.5 T. Fe{sub 3}O{sub ...
The atomic masses of the alkali-metal isotopes "6Li,"2"3Na,"3"9","4"1K,"8"5","8"7Rb, and "1"3"3Cs have been obtained from measurements of cyclotron frequency ratios of pairs of ions simultaneously trapped in a Penning trap. The results, with one standard deviation uncertainty, are: M("6Li)=6.015 122 887 4(16)u,M("2"3Na)=22.989769 282 8(26)u,M("3"9K)=38.963 706 485 6(52)u,M("4"1K)=40.961 825 257 4(48)u,M("8"5Rb)=84.911 789739(9)u,M("8"7Rb)=86.909 180 535(10)u, and M("1"3"3Cs)=132.905 451 963(13)u. Our mass of "6Li yields an improved neutron separation energy for "7Li of 7251.1014(45) keV.
A comprehensive and highly selective method for detecting in bacterial supernatants a modified sulfur nucleoside, S-adenosyl-L-methionine (SAM), and its metabolites, i.e., S-adenosylhomocysteine (SAH), adenosine (Ado), 5prime-deoxy-5prime-methylthioadenosine (MTA), adenine (Ade), S-adenosyl-methioninamine (dcSAM), homocysteine (Hcy) and methionine (Met), was developed. The method is based on reversed-phase liquid chromatography with positive electrospray ionization (ESI+) coupled to a hybrid linear quadrupole ion trap (LTQ) and 7-T Fourier transform ion cyclotron resonance mass spectrometry (FTICRMS). A gradient elution was employed with a binary solvent of 0.05 M ammonium formate at pH 4 and acetonitrile. The assay involves a simultaneous cleanup of cell-free bacterial broths by solid-pha...
The natural gas industry has proposed an increase in the DOE gas R&D budget from about $100 million to about $250 million per year for each of the next 10 years. The proposal includes four programs: natural gas supplies, fuel cells, natural gas vehicles and stationary combustion systems. This paper is a qualitative assessment of the gas industry proposal and recommends a natural gas R&D strategy for the DOE. The methodology is a conceptual framework based on an analysis of market failures and the energy policy objectives of the DOE`s (1991) National Energy Strategy. This framework would assist the DOE in constructing an R&D portfolio that achieves energy policy objectives. The natural gas supply program is recommended to the extent that it contributes to energy price stability. Stationary combustion programs are supported on ...
Prepared to make housing project managers, maintenance engineering staff, and designers and architects of HUD - assisted and HUD - insured housing projects and mobile home parks aware of their responsibilities under the Natural Gas Pipeline Safety Act, this handbook provides technical guidance for the reduction of gas leaks and the handling of gas leak incidents in residential areas. The hazards of natural gas, concern over gas safety in residential areas, applicable codes and standards, and sources of information and help are reviewed, along with maintenance and engineering considerations relating to gas pipe failures, the detection of gas leaks, appliance servicing, and pipe installation, repair, and replacement. Housing management considerations are also examined, with attention to recordkeeping and reporting, emergency contingency ...
Gas Supplies of Interstate Natural Gas Pipeline Companies 1987 was prepared by the Reserves and Natural Gas Division, Office of Oil and Gas, Energy Information Administration (EIA). The publication provides information on the total reserves, production, and deliverability capabilities of the 87 interstate pipeline companies required to file the Federal Energy Regulatory Commission (FERC) Form 15, ''Interstate Pipeline's Annual Report of Gas Supply.'' This publication is the 25th in a series of annual reports on the total gas supplies of interstate pipeline companies since the inception of individual company reports to the Federal Power Commission (FPC) in 1964 for report year 1963. This publication provides information on the interstate pipeline companies' supply of natural gas during ...
The corrosion behavior of 304 stainless steel was characterized with cyclic voltammetry in a eutectic Li/K and Li/Na carbonate melt under anode and cathode gas of the molten-carbonate fuel cell (MCFC). The corrosion rate of 304 steel was determined in four different environments of the MCFC with electrochemical methods and from cross-sectional analysis of corrosion layers. These four environments were open-circuit and MCFC-load conditions both under anode and cathode gas. At open-circuit conditions corrosion was more severe under the oxidizing cathode gas then under the reducing anode gas. On the contrary, at load conditions corrosion was more severe under anode than under cathode gas. The anodic polarization under anode gas enhances corrosion, whereas the high anodic polarization under cathode gas leads to anodic protection. Corrosion ...
In order to study the effects of microwaves on chemical reactions equipment was designed to acquire in-situ vibrational spectra of sol-gel components as they are irradiated with microwaves. Fourier Transform Infrared (FTIR) and Raman spectroscopy were used. A low temperature (10K) FTIR cell was used to trap samples in an argon matrix at 10{sup -7} Torr. For the liquid samples no differences were seen in spectra of irradiated and nonirradiated samples, but the argon matrix isolation technique showed dramatic differences.
The previously unknown property of the optical speckle pattern reported. The interference of a speckle with the counterpropagating phase-conjugated (PC) speckle wave produces a randomly distributed ensemble of a twisted entities (ropes) surrounding optical vortex lines. These entities appear in a wide range of a randomly chosen speckle parameters inside the phase-conjugating mirrors regardless to an internal physical mechanism of the wave-front reversal. These numerically generated interference patterns are relevant to the Brillouin PC mirrors and to a four-wave mixing PC mirrors based upon laser trapped ultracold atomic cloud.
Summary DNA topoisomerases are the key enzymes involved in carrying out high precision DNA transactions inside the cells. However, they are detrimental to the cell when a wide variety of topoisomerase-targeted drugs generate cytotoxic lesions by trapping the enzymes in covalent complexes on the DNA. The discovery of unusual heterodimeric topoisomerase I in kinetoplastid family added a new twist in topoisomerase research related to evolution, functional conservation and their preferential sensitivity to Camptothecin. On the other hand, structural and mechanistic studies on kinetoplastid topoisomerase II delineate some distinguishing features that differentiate the parasitic enzyme from its prokaryotic and eukaryotic counterparts. This review summarizes the recent advances in research in kin...
The deferred luminescence (isothermal luminescence -ITL- and thermoluminescence - RTL) emitted by Chlorella cells after #gamma# irradiation at 77 K has been investigated. The decay kinetics of ITL as well as the effect of illumination of both ITL and RTL show that trapped electrons take part in the recombination reactions which give rise to both emissions, and that ITL can be attributed to electron tunnelling. Most strains of Chlorella studied present similar RTL glow curves, the only exceptions found being Chlorella vulgaris (green and bleached strains).
Recent results of the experiments at GOL-3 facility are presented. Plasma with a density of 1014...1016 cm-3 is confined in a 12-meter-long solenoid, which comprises 55 corrugation cells with mirror ratio Bmax/B min=4.8/3.2 T. The plasma is heated up to 2...4 keV temperature by a high power relativistic electron beam (?1 MeV, ? 330 kA, ?8?s, ?120 kJ) injected through one of the ends. Mechanism of experimentally observed fast ion heating, issued of plasma stability and confinement are discussed.
This paper described the application of an AC surface probe, similar to presently used eddy current probes, to the measurement of DC transport critical currents and critical state dissipation in high {Tc} superconductors. It has been shown that the probe can provide quantitative measurement of the full field penetration in superconducting samples by measuring the response of AC induced screening currents for superconducting materials in the form of tapes with overlayers of silver. In this manner, the AC probe can be used to replace the contact DC probe for determining critical currents in a noncontacting and local manner suitable for scanning over or along the sample.
This paper described the application of an AC surface probe, similar to presently used eddy current probes, to the measurement of DC transport critical currents and critical state dissipation in high T_c superconductors. It has been shown that the probe can provide quantitative measurement of the full field penetration in superconducting samples by measuring the response of AC induced screening currents for superconducting materials in the form of tapes with overlayers of silver. In this manner, the AC probe can be used to replace the contact DC probe for determining critical currents in a noncontacting and local manner suitable for scanning over or along the sample.
This paper described the application of an AC surface probe, similar to presently used eddy current probes, to the measurement of DC transport critical currents and critical state dissipation in high [Tc] superconductors. It has been shown that the probe can provide quantitative measurement of the full field penetration in superconducting samples by measuring the response of AC induced screening currents for superconducting materials in the form of tapes with overlayers of silver. In this manner, the AC probe can be used to replace the contact DC probe for determining critical currents in a noncontacting and local manner suitable for scanning over or along the sample.
Stream invertebrates that feed on leaf litter are intimately tied to the nature and timing of the litter input. These invertebrates are called shredders; they consume streamside, riparian litter that has become trapped in the stream channel. This plant litter accumulates at the leading edge of obstructions in the current and settles out in pools, alcoves, and other depositional zones. Given the extensive literature that has accumulated over the last 20 years, researchers can now develop a general, testable model that relates riparian plant communities to the stream shredders, which depend upon litter derived from those communities.
The refractive index of novel organosilica (nano/micro)material is determined using two methods. The first method is based on analysis of optical extinction efficiency of organosilica beads versus wavelength, which is obtained by a standard laboratory spectrometer. The second method relies on the measurable trapping potential of these beads in the focused light beam (laser tweezers). Polystyrene beads were used to test these methods, and the determined dispersion curves of refractive index values have been found accurate. The refractive index of organosilica beads has been determined to range from 1.60-1.51 over the wavelength range of 300-1100 nm.
Transient, greatly enhanced diffusion has been observed on annealing solid-phase-epitaxial (SPE) grown Si-Sb alloys. This is shown to be due to a high concentration of interstitials being trapped during SPE regrowth. The migration enthalpy, for diffusion of Sb by an interstitialcy mechanism was measured as 1.8 +/- 0.2 eV. The interstitials eventually condensed into loops, marking the end of the transient. In a SPE grown Si-Bi alloy a similar transient enhanced diffusion was observed, with an activation energy of 2.0 +/- 0.2 eV, but no loops formed. 8 figures, 7 references.
Transient, greatly enhanced diffusion has been observed on annealing solid-phase-epitaxial (SPE) grown Si-Sb alloys. This is shown to be due to a high concentration of interstitials being trapped during SPE regrowth. The migration enthalpy, for diffusion of Sb by an interstitialcy mechanism was measured as 1.8 +/- 0.2 eV. The interstitials eventually condensed into loops, marking the end of the transient. In a SPE grown Si-Bi alloy a similar transient enhanced diffusion was observed, with an activation energy of 2.0 +/- 0.2 eV, but no loops formed. 8 figures, 7 references.
The present paper investigates the peristaltic transport of a couple stress fluid in an asymmetric channel with the effect of the induced magnetic field. The exact solutions of momentum and the magnetic field equations have been calculated under the assumptions of long wave length and low but finite Reynolds number. The expression for pressure rise has been computed numerically using mathematics software Mathematica. The graphical results have been presented to discuss the physical behavior of various physical parameters of interest. Finally, the trapping phenomena have been discussed for various physical parameters. (orig.)
The present paper investigates the peristaltic transport of a couple stress fluid in an asymmetric channel with the effect of the induced magnetic field. The exact solutions of momentum and the magnetic field equations have been calculated under the assumptions of long wave length and low but finite Reynolds number. The expression for pressure rise has been computed numerically using mathematics software Mathematica. The graphical results have been presented to discuss the physical behavior of various physical parameters of interest. Finally, the trapping phenomena have been discussed for various physical parameters.
This paper discusses the influence of an endoscope on the peristaltic flow of a couple stress fluid in an annulus under a zero Reynolds number and long wavelength approximation. The inner tube is uniform, rigid, while the outer tube has a sinusoidal wave traveling down its wall. Analytical expressions for the axial velocity, stream function and axial pressure gradient are established. The flow is investigated in a wave frame of reference moving with the velocity of the wave. Numerical calculations are carried out for the pressure rise, frictional forces and trapping. The features of the flow characteristics are analyzed by plotting graphs and discussed in detail.
The temperature and pressure dependence of the mobilities of negative charges injected into liquid hydrogen and deuterium have been measured. The authors propose the existence of two types of charge carriers in liquid parahydrogen. One is a bubble with an electron inside while the other has higher mobility. Relaxation of the current through liquid hydrogen was observed. It is suggested that in liquid and solid hydrogen under {beta}-irradiation neutral complexes are created which can trap the negative charges and have a lifetime of about 10 hours. 6 refs., 5 figs.
The results of studies of the time-resolved luminescence of self-trapped excitons (STE) with different multiplicity as well as the X-ray emission in oriented BeO crystals under excitation in the vicinity of the 1 s Be photoabsorption edge are presented. The branching of the electronic excitations relaxation depends strongly on the crystal orientation after the inner-shell excitation. The common features between the processes of the STE luminescence and resonantly excited X-ray fluorescence have been discussed.
Infrared (IR, 880 nm) stimulated luminescence (IRSL) signal was observed from quartz at room temperature. The characteristics of the signal such as its response to {gamma}-ray irradiation, thermal stability and thermal assistance energy show that the signal originates from different traps than those responsible for the luminescence signal stimulated by green light (GL, 514 nm). The IRSL signal's short lifetime (18 days at 15 deg. C) may have been the reason why it was not detected in previous experiments. The decay of the IR signal after GL illumination was observed. The thermoluminescence at 76 deg. C was enhanced after IR illumination.
As part of a project to complete a comprehensive catalogue of astrophysically relevant emission lines in support of new-generation X-ray observatories using the Lawrence Livermore electron beam ion traps EBIT-I and EBIT-II, we studied emission lines of argon and sulfur in the soft X-ray and extreme ultraviolet region. Here we present observations of Ar IX through Ar XVI and S VII through S XIV between 20 and 75 {angstrom} to illustrate our work.
The magnetoresistance in an FeNi submicron-structure comprising two wires of 80 and 200 nm in width connected in series was measured at 77 K. When the external magnetic field was applied parallel to the wire axis, two switching fields corresponding to the distinct coercive force of the two wires were observed. When the external magnetic field was applied at an angle of {theta}>30 deg. to the wire axis one switching field was observed, indicating simultaneous magnetization reversal in both wires. This indicates that the domain-wall trapping around the joint can be controlled systematically in terms of the direction of the external magnetic field.
Individual laser cooled atoms are delivered on demand from a single atom magneto-optic trap to a high-finesse optical cavity using an atom conveyor. Strong coupling of the atom with the cavity field allows simultaneous cooling and detection of individual atoms for time scales exceeding 15 s. The single atom scatter rate is studied as a function of probe-cavity detuning and probe Rabi frequency, and the experimental results are in good agreement with theoretical predictions. We demonstrate the ability to manipulate the position of a single atom relative to the cavity mode with excellent control and reproducibility.
In this study the authors examine the convective cooling provided by fluid trapped in the cavity between two consecutive rollers in a roller bearing. In order to calculate the steady-state temperature of the roller, the designer must know nor only the rolling-contact heat input received by the roller but also the convection cooling effect of the surrounding fluid. Until recently, this lateral convection cooling effect was modeled by assuming a certain (constant) heat transfer coefficient h at the roller surface, and then calculating the steady-state temperature distribution around the roller.
The 8 papers in the report deal with the following areas: Introduction to diesel particulate emissions, alternative fuels, and the transit industry; Technical problems and policy issues associated with the 1991 bus emissions standards; Reducing transit bus emissions: comparative costs and benefits of methanol, particulate traps, and fuel modification; Effects of applying emissions averaging, trading, and banking to transit buses; Strategic review of heavy-duty engine emission regulations and alternate fuels; Meeting bus emissions standards--a perspective; Economic evaluation of bus maintenance contracting; Objectives for a transit-bus-fleet management data, information, and knowledge exchange.
Ninety-five nests of Centris (Heterocentris) terminata Smith were collected in trap nests, during November/2001 and January/2003, at two fragments (PZGV e CFO-UFBA) of secondary Atlantic Forest, in Salvador, Bahia State (13 deg 01' W and 38 deg 30' S). The highest nest frequencies occurred from December to February (summer), with no nests foundations from August to October (winter - early spring). Two-hundred eight adults emerged from 347 brood cells, being 164 males and 116 females (1: 0.42). During the study period sex ratio was male biased ({chi}{sup 2} = 9.342; gl = 10; P < 0.05). C. terminata nested in holes with diameters 6, 8, 10 mm, but 84,2% were constructed in 8 and 10 mm. nests had one to seven cells arranged in a linear series with the cell's partitions built with a mixture of sand and resin or oil. Male is significantly smaller than female, which emerges from the first cells constructed. Immature mortality occurred in ...
In this paper we discuss the results of thermoluminescence (TL) studies carried out on freshly quenched crystals of KBr doped with {approx} 50 ppm of Eu{sup 2+} ions which were X-irradiated at room temperature. The TL glow curve of this phosphor material consists of three glow peaks at 355, 376 and 398 K whose intensities increased as a function of X-irradiation time. The TL glow peaks were analyzed by the total curve-fitting method in order to obtain the characteristic parameters; activation energy, pre-exponential factor and kinetic order. The spectral character of the emission recorded during thermoluminescence was found to be the same for all glow peaks and consists of a broad band centered at {approx} 420 nm. It is proposed that the model of the TL process most consistent with our experimental results is one in which the Eu{sup 2+} impurity acts as an electron trap during the irradiation process and that the radiation induced center (partner of an center) and ...
In this paper we discuss the results of thermoluminescence (TL) studies carried out on freshly quenched crystals of KBr doped with #approx# 50 ppm of Eu"2"+ ions which were X-irradiated at room temperature. The TL glow curve of this phosphor material consists of three glow peaks at 355, 376 and 398 K whose intensities increased as a function of X-irradiation time. The TL glow peaks were analyzed by the total curve-fitting method in order to obtain the characteristic parameters; activation energy, pre-exponential factor and kinetic order. The spectral character of the emission recorded during thermoluminescence was found to be the same for all glow peaks and consists of a broad band centered at #approx# 420 nm. It is proposed that the model of the TL process most consistent with our experimental results is one in which the Eu"2"+ impurity acts as an electron trap during the irradiation process and that the radiation induced center (partner of an center) and the V_k ...
Receptor interacting protein 140 (RIP140) is a coregulator for numerous nuclear receptors and transcription factors and primarily exerts gene-repressive activities on various target genes. We previously identified a spectrum of posttranslational modifications on RIP140 that augment its property and biological activity. In T(3)-triggered biphasic regulation of cellular retinoic acid binding protein 1 (Crabp1) gene along the course of fibroblast-adipocyte differentiation, we found TRAP220(MED1) critical for T(3)-activated chromatin remodeling whereas RIP140 essential for T(3)-repressive chromatin remodeling of this gene promoter. In this current study, we aim to examine whether and how RIP140 replaces TRAP220(MED1) on the CrabpI promoter in differentiating adipocyte cultures. We find increasing recruitment of RIP140 to this promoter, with corresponding reduction in TRAP220(MED1) recruitment during the T(3)-repressive phase. ...
The construction of networks consisting of optically interconnected processing units is a promising way to scale up quantum information processing systems. To store quantum information, single trapped atoms are among the most proven candidates. By placing them in high finesse optical resonators, a bidirectional information exchange between the atoms and photons becomes possible with, in principle, unit efficiency. Such an interface between stationary and ying qubits constitutes a possible node of a future quantum network. The results presented in this thesis demonstrate the prospects of a quantum interface consisting of a single atom trapped within the mode of a high-finesse optical cavity. In a two-step process, we distribute entanglement between the stored atom and two subsequently emitted single photons. The long atom trapping times achieved in the system together with the high photon collection efficiency of the cavity ...
We investigate the possibility of kaon condensation in the dense interior of neutron stars through the s-wave interaction of kaons with nucleons. We include nucleon-nucleon interactions by using simple parametrizations of realistic forces, and include electrons and muons in #beta#-equilibrium. The equation of state above the condensate threshold is derived in the mean field approximation. The conditions under which kaon condensed cores undergo a transition to quark matter containing strange quarks are also established.The critical density for kaon condensation lies in the range (2.3-5.0)#rho#_0, where #rho#_0=0.16 fm"-"3 is the equilibrium density of nuclear matter. The critical density depends largely on the value of the strangeness content of the proton, the size of which is controversial. For too large a value of the strangeness content, matter with a kaon condensate is not sufficiently stiff to support the lower limit of 1.44 M_o_e_d_o_t for a neutron star. Kaon condensation ...
Full text: Chemical-technology approaches allowing to intensification the prevention processes of gas hydrates formation at motion of gas-liquid stream of natural gas in system natural gas well - gas wire have been worked up. Technological regimes of treatment of gas stream have been determined. Linear correlation dependences inhibitor electrolytes contained hydrated ions with different ion radii and charges of subgroups of alkali elements with one - type electron configuration were obtained. Important physico-chemical parameters of electrolytes have been determined: activity; coefficients of activity, viscosity, diffusion; density; heat capacity; heat conductivity; surface tension and freezing-point. The features of continuous influence of inhibitory factors on process of gas flow at low temperatures and relatively high pressure differences ...
The passive continental margin in the northern South China Sea is a weakly active area. It has been found to be favorable for large gas field development and also to be profitable for gas hydrate. The active faults, diapir structure, slump deposits, faults break of slopes, gas chimneys and sandstone of submarine fan, control the concentration of gas hydrate. Gas chimneys are widely distributed in the northern South China Sea. They supply the pathway for migration of deeper gas to gas hydrate stability zones especially in the basin of tectonic inactive zone. This paper discussed the geological structures of gas hydrate occurrence in gas fields and presented a detailed analysis of gas chimneys within the northern slope of the South China Sea. The paper described the geological ...
The paper deals with a model in which the motion of a gas in plasma accerators and high-curent discharges in the present of a skin effect is treated as expulsion by a 'magnetic piston' under the action of surface current flow. Specifically examined is the situation where the initial gas pressure is negligible in comparison with the magnetic pressure, and the motion of the gas may be treated as a self-simulating one. A system of hydrodynamic equations of the problem is derived and integrated by Adam's method. Results are plotted and discussed.
Gas contaminated with at least one noxious component, such as SO/sub 2/, HF or NOx, is scrubbed with a clear, calcium-containing, initially-basic washing liquid which also comprises the anion of a strong inorganic acid, that of a polybasic carboxylic acid and, optionally, that of a monobasic carboxylic acid. Apparatus is provided for scrubbing the gas, oxidizing produced calcium bisulfite to calcium sulfate, separating out and removing solids, and recirculating clarified liquid for scrubbing contaminated gas.
The Rayleigh scattering length has been calculated for rare-gas liquids in the ultraviolet for the frequencies at which they luminesce. The calculations are based on the measured dielectric constants in the gas phase, except in the case of xenon for which measurements are available in the liquid. The scattering length mayplace constraints on the design of some large-scale detectors, using uv luminescence, being proposed to observe solar neutrinos and dark matter. Rayleigh scattering in mixtures of rare-gas mixtures is also discussed.
The fission gas xenon bonded in bubbles, in pore, and in the lattice of mixed carbide fuels is measured by electron-probe microanalysis. Radial xenon distribution and release curves are determined and are calibrated by gas chromatography of the bonded fission gas and by burnup analysis in the respective pin sections of the irradiation experiments FR2 6A and 6C, Mol 11/K 2, and DFR 330/1. The results are correlated to the microstructure of the fuel, bonding medium, temperature, and burnup. (Auth.).
Analysis of the coke gas combustion porcess is presented. Standard kinetic relationships were utilized. Calculations were performed for coke gas with high and low content of H/sub 2/ and for blasting air 20 and 100/sup 0/C. Temperature relationships, composition of gas combustion products and release of nitrogen oxides were determined. Results are analyzed which will make it possible to control the composition of combustion products.
This thesis dealt with the metal-organic gas phase epitaxy with nitrogen as carrier gas. For this first by means of three-dimensional modelings of the epitaxy process the influence of the carrier gas on the processes was explained. The optimization of the growth parameter for the whole light-emitting-diode structure in double-hetero arrangement resulted that an a temperature of 770 C and a V/ III-ratio of 150 layers with a high crystal quality could be reached.
Plasma with a gas temperature below room temperature is not yet fully understood although it is expected to be an attractive tool for applications to material processing. In the present work, gas-temperature-dependent generation of a cryoplasma jet was studied. So far, we have generated a helium cryoplasma jet (296-5 K) under atmospheric pressure. At gas temperatures below 20 K, the helium excimer, He2, was observed clearly from by optical emission spectroscopy.
The gas composition of recent thermal waters is in perfect conformity with their geologic-tectonic positions. The composition of gas-liquid inclusions in the basic-hyperbasic xenoliths of basaltoid lavas depends on the depth from which xenoliths are supplied. (The depth is determined by using the methods of geological thermobarometers). By comparing available data the conclusion was drawn that the gas compositions of thermal waters reflect the depth of generation of deep fluid which heats them and depends on the penetration depth of the fluid-conducting fissure zones.
Spark ignition internal combustion engines perform satisfactorily when the fueled with biomass producer gas from a fluidized bed gasifier. Although power output is reduced compared to natural gas levels, full power recovery can be achieved with a relatively low level of supercharging. Important considerations are an adequate fuel delivery system and adquate gas cleaning. ref.
... harassment, incidental to construction and operation of an offshore liquefied natural gas (LNG) facility. Under the Marine Mammal Protection ... ...
The primary objective of this study is to assess the oil and gas potential of the West Siberian Basin of Russia. The study does not analyze the costs or technology necessary to achieve the estimates of the ultimate recoverable oil and gas. This study uses reservoir data to estimate recoverable oil and gas quantities which were aggregated to the field level. Field totals were summed to a basin total for discovered fields. An estimate of undiscovered oil and gas, from work of the US Geological Survey (USGS), was added to give a total basin resource volume. Recent production decline points out Russia`s need to continue development of its discovered recoverable oil and gas. Continued exploration is required to discover additional oil and gas that remains undiscovered in the basin.
Details of a 1 day conference designed to create more efficient interactions between the gas supply and electricity systems in Ontario and new models for gas supply and the electricity system were presented. Market efficiency, generators' perspectives on critical gas issues, an overview of the North American gas and an outline of issues concerning Ontario were discussed. A natural gas industry forecast and issues concerning marketers and producers were presented. The terms on which gas is bought and sold were discussed. Regulatory tools, cost allocation and issues relating to unbundling were also presented. Infrastructure needs were reviewed, as well as basic market structures. It was suggested that appropriate commercial service options need to be developed and approved, including cross-utility services.
The Department of Energy has proposed a rulemaking process to set minimum standards for the efficiency of gas ranges under the National Appliance Energy Conservation Act (NAECA). The Gas Research Institute is compiling information on annual household range gas usage in order to prepare a response to the proposed rulemaking. The data base from the Northern Illinois Gas residential load study provides recent information (data taken from 1990 through 1992) over a comprehensive study of household types and appliance and user characteristics (150 variables noted for each household). The stated Objective is to study the Northern Illinois Gas residential load study data base and to evaluate its effectiveness in predicting annual household gas usage.
Research was performed to assess the feasibility of barrier membrane substances, for use within mining or associated high risk environments, in restricting the diffusion transport of radon gas quantities. Specific tests were conducted to determine permeability parameters of a variety of membrane materials with reference to radon flow capabilities. Tests were conducted both within laboratory and in-situ emanation environments where concentrations and diffusion flows of radon gas were known to exist. Equilibrium radon gas concentrations were monitored in initially radon-free chambers adjacent to gas sources, but separated by specified membrane substances. Membrane barrier effectiveness was demonstrated to result in reduced emanation concentrations of radon gas within the sampling chamber atmosphere. Minimum gas concentrations were evidenced where the barrier ...
The light gain due to S/sub 2/ molecules in a supersonically cooled gas mixture is calculated. The S/sub 2/ molecules formed due to the recombination of the sulfur atoms, and the combustion gas mixture was preheated in a precombustion chamber. Optimal gas flow and nozzle parameters are found which correspond to the highest possible light gain using Cs/sub 2/-Ar and S/sub 2/-Ar gas mixtures. The steady state gas flow in the nozzle was calculated, taking into account the chemical reactions in the one-dimensional approximation. It is shown that the maximum gain values vary in the 0.0001-0.002 range for gas pressures in the precombustion chamber in the range 10-100 atm. The optimal initial relative concentration of Cs/sub 2/ molecules and S/sub 2/ molecules are given. 32 references.
The use of natural gas in China is still relatively immature, as gas production only supplies a low percentage of the domestic energy system. In contrast, Chinese economy mainly relies on coal with a 67% share of the total primary energy supply. The environmental impact from this high coal dependence is significant and planners have sought for cleaner energy sources. Natural gas is both cleaner and generally more efficient than coal and gas consumption is rising quickly due to these facts. The growth tendency indicates that natural gas will become an important substitution for coal in some parts of the Chinese primary energy consumption. To quantify this tendency, this paper uses a system dynamics model to create a possible outlook. The results show that the gas consumption in China will c...
Biomass gasification provides the potential to efficiently and economically produce a renewable source of a clean gaseous fuel suitable for power generation or synthesis gas (syngas) applications. An important side benefit of the use of biomass is the effective minimization of the primary greenhouse gas, carbon dioxide (CO{sub 2}), by providing a means to close-loop the CO{sub 2} cycle. However, high molecular weight hydrocarbon constituents (tar) in the product gas from gasification can complicate the downstream uses of the gas. This paper discusses both the development of a low cost, disposable catalyst system that can eliminate these heavy hydrocarbons from the gas and the use of the catalyst in conjunction with the Battelle high-throughput gasification process for power generation and synthesis applications. (author)
The presence of an extraneous light gas must be taken into account in consideration of centrifugal separation of uranium isotopes, when there is inevitable leakage of such a gas through the gas sealant and/or leaking in from the atmosphere. Consideration is first given to the influence of the presence of the light gas on the maximum separative power. Then the basic equation for isotope separation containing a light gas is derived from Hirschfelder's diffusion equations. This equation is solved and the separative performance is expressed in terms of the shape factor and reflux parameter. The formulas for expressing the flow configurations of the gases are obtained for a simple model in which inflow and outflow prevail throughout the centrifuge. The corresponding equation for a model in which the gases flow in two concentric thin streams is also derived. It is concluded that the ...
A patent is claimed for a process by which a low-hydrogen gas containing at least 90 percent by volume of methane which is suited for natural gas substitution is produced by transformation of vaporizable hydrocarbons with the aid of steam in the presence of a catalyst containing nickel, at temperatures of 350 to 600/sup 0/C and at increased pressure. Hydrocarbons and steam are supplied to the reaction in mixed form with recycle product gas. Per kilogramme of hydrocarbons to be converted in the high btu gas reactor, less than 1 kilogramme of fresh steam is needed. High btu gas is fed back from the high btu gas reactor to the input end of the same via a gas cycle comprising a cooler, a carbon dioxide absorption device, and a saturator. Between the carbon dioxide absorption device and the saturator a product gas is branched ...
The performance of the gas-jet transport system coupled to the RIKEN gas-filled recoil ion separator GARIS was investigated using 255No produced in the 238U(22Ne, 5n)255No reaction. Alpha particles of 255No separated with GARIS and transported by the gas-jet system were measured with a rotating wheel apparatus for ? spectrometry under low background condition. The high gas-jet efficiencies of about 75% were independent of the recoil ranges of 255No in the gas-jet chamber. The present results suggest that the GARIS/gas-jet system is a promising tool for the next-generation superheavy element chemistry: (1) the background radioactivities of unwanted reaction products are strongly suppressed, (2) the intense beam is absent in the gas-jet chamber and hence the high gas-jet efficiency is achieved, and (3) the beam-free ...
The purpose of this study is to identify the radiative heat transfer augmentation by a coaxial cylinder introduced in the infinite cylindrical pipe enclosing a participating gas. The gas is either a mixture of water vapor and carbon dioxide or gray. The gas is assumed to be homogeneous at a constant temperature, and has a refractive index of unity. All of the surfaces are opaque and gray, diffusely emitting and reflecting at a constant temperature. The effect of system diameter, diameter ratio, wall emittances, gas and surface temperatures, mixture component on heat transfer augmentation are studied by using the zone method with participating gas radiative properties evaluated from the weighted sum of gray gases model. From the radiative equilibrium condition, the installed wall temperature is formulated and calculated by the iteration method. If the medium is a gray ...
Visible smoke of exhaust gas from iron ore sintering plants spoil the scenery around the works. In this paper, the mechanism of formation of visible smoke is discussed by detailed analysis of the exhaust gas components and dust in the Oita No. 1 sintering plant. The main substance of visible smoke was mist condensing in the air during the cooling of exhaust gas that contained 0.1 ppm of sulfuric acid. Sulfuric acid is considered to raise the dew point and so facilitate mist condensation, and to lower the vaporization of visible mist containing sulfuric acid solution. Dust in the exhaust gas is also considered to act as nucleation sites for mist condensation. This proposed mechanism was confirmed by the test remixing SOx-rich gas with desulfurization gas in the Nagoya No. 3 sintering plant. Long trails of visible smoke were observed by remixing SOx-rich ...
Pressurized fluidized bed combustion (PFBC) is an emerging coal-fired, combined-cycle power generation technology nearing commercial status through several operating and planned demonstration plants throughout the world. Current-generation PFBC plants use ``ruggedized`` gas turbines that can tolerate dust loading common with conventional cyclone gas cleaning. The next generation of PFBC will apply advanced hot gas cleaning systems that will reuse the dust loading to low levels acceptable to high performance, industrial gas turbines. These advances should result in performance and cost advantages. This article examines the demonstration of PFBC technology at Tidd power station.
Sigma 1) examines ways to reduce the number of breakdowns of pressure-regulating stations and to minimize the energy consumed in warming the gas, 2) determines the optimal gas temperatures upstream from the pressure reduction, and 3) shows the dependence of energy consumption upon the water dewpoint. The method of calculating the optimal input temperature relies on Mollier's diagram. Tables and nomographs for natural gas and water dewpoint at 19/sup 0/F and 580 psi (-7/sup 0/C and 4 MPa) are useful in achieving the desired gas temperatures. Heating the regulators' control valves is important.
A study was conducted to examine the energy consumption in existing and new hog farming facilities and to analyse the potential for increased natural gas use in the Saskatchewan hog industry. Existing heating/cooling, ventilation and feed mill equipment choices offer possibilities for running on electricity, natural gas or propane. Energy costs are lowest when natural gas is used. To put the study in context, an overview of the Saskatchewan hog industry was provided. The potential increase in natural gas use in hog production by year 2005 was estimated. 10 refs., 6 tabs., 8 figs.
Increased use of natural gas has positive effects for the environment and the climate, because it primarily replaces petroleum products. Moreover, the natural gas does not pose a threat to bio fuel in Norway. But introducing CO2 taxes on natural gas will significantly increase the emission of greenhouse gases, concludes a report conducted by Norsk Energi (Norwegian Energy) on behalf of Norsk Naturgassforening (Norwegian Natural Gas Association) and Norsk Gassforum (Norwegian Gasforum). A brief presentation of the main conclusions in the report (ml)
National Power is building its first gas turbine combined cycle power station at Killingholme, situated to the south of the River Humber in the East of England. NEI ABB Gas Turbines Limited was awarded the turnkey contract in July 1990 to build a nominal 650 MW combined cycle power station based around three Asea Brown Boveri GT13E gas turbines. The project is outlined in this article. The plant is due for completion in July 1993. (author)
This article outlines the use of gasifiers during World War II and how, with soaring fuel prices, producer gas may provide an alternate energy path for agribusiness and farms today. In the last few years, the University of California has become a focus of producer gas research in the US. Biomass fuels used include crushed walnut shells, fruit pits, cereal straw and corn cobs. Particle size, moisture content and slagging create problems and the right kind of gas producer must be used to obtain reliable conversion to producer gas.
The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through February 1999.
The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through September 1999.
The waste tail gas fuel emitted from refinery plant in Taiwan e.g. catalytic reforming unit, catalytic cracking unit and residue desulfurization unit, was recovered and reused as a replacement fuel. In this study, it was slowly added to the fuel stream of a heater furnace to replace natural gas for powering a full-scale distillation process. The waste tail gas fuel contained on average 60 mol% of hydrogen. On-site experimental results show that both the flame length and orange-yellowish brightness decrease with increasing proportion of waste gas fuel in the original natural gas fuel. Moreover, the adiabatic flame temperature increases as the content of waste gas fuel is increased in the fuel mixture since waste gas fuel has a higher adiabatic flame temperature than that of natural gas. The complete replacement of natural ...
This paper provided an outline of the Canadian natural gas commodity market and a forecast for Canadian natural gas supply and prices for the 2007 winter heating season. Since 2001, steady demand growth and slow supply growth have contributed to higher North American natural gas commodity prices. The loss of natural gas supply due to hurricanes pushed North American natural gas commodity prices to record levels in 2005. Canadian natural gas production levels currently exceed domestic gas consumption. In 2005, Canada produced 16.5 billion cubic feet per day of marketable natural gas. Approximately 45 per cent was consumed domestically, and the remainder was exported to the United States. Despite high levels of drilling activity, production of natural gas from western Canada has flattened out since ...
The State of the Espirito Santo will become until the end of 2008, one of the main producers and natural gas exporters of Brazil, where, according to PETROBRAS, the State will produce about 20 million /day m{sup 3}, what it will go to contribute significantly for reduction of the dependence of the Bolivian gas, and still to give support to the natural gas sector in Brazil. The Intention of this work, is to identify proposals so that it has left of the gas produced in the State of the Espirito Santo, has a differentiated price. It does not make sensible the State to pay for the gas that is removed in its proper territory the same price that paid Sao Paulo for the gas that consumes imported of national Bolivia. With the markdown of the gas the State will be able to attract investments of great transport, to generate job and income and to ...
We have used the SINFONI integral field spectrograph to map the near-infrared K-band emission lines of molecular and ionised hydrogen in the central regions of two cool core galaxy clusters, Abell 2597 and Sersic 159-03. Gas is detected out to 20 kpc from the nuclei of the brightest cluster galaxies and found to be distributed in clumps and filaments around it. The ionised and molecular gas phases trace each other closely in extent and dynamical state. Both gas phases show signs of interaction with the active nucleus. Within the nuclear regions the kinetic luminosity of this gas is found to be somewhat smaller than the current radio luminosity. Outside the nuclear region the gas has a low velocity dispersion and shows smooth velocity gradients. There is no strong correlation between the intensity of the molecular and ionised gas emission and either the radio or ...
Nova Corporation and its related businesses are involved in natural gas production, gas pipelines, consulting services, and upgrading of natural gas into chemicals and plastics. Nova owns Alberta Gas Transmission Division, the primary gas transportation system in Alberta, with 11,400 miles of pipeline and total deliveries in 1992 of 3.4 trillion ft"3. Nova also owns 50% of Foothills Pipe Lines Ltd., one of Canada's largest carriers of exported gas, and 50% of TQM Pipeline Partnership, which transports natural gas in Quebec. Nova conducts its chemicals business through Novacor Chemicals Ltd., which has plants in Alberta, Ontario, Quebec, and the USA. Novacor's major petrochemicals are methanol, ethylene, propylene, and styrene and its major plastics are polystyrene, polypropylene, and polyethylene. Nova's gas-producing ...
Gas transmission pipelines are susceptible to both internal (gas side) and external (soil side) corrosion attack. Internal corrosion is caused by the presence of salt laden moisture, CO{sub 2}, H{sub 2}S, and perhaps O{sub 2} in the natural gas. Internal corrosion usually manifests itself as general corrosion. However, the presence of chlorides in entrained water also can lead to pitting corrosion damage. The electrochemical noise technique can differentiate general from localized corrosion and provide estimates of corrosion rates without external perturbation of the corroding system. It is increasingly being applied to field and industrial installations for in situ corrosion monitoring. It has been used here to determine its suitability for monitoring internal and external corrosion damage on gas transmission pipelines. Corrosion measurements were made in three types of environments: (1) aqueous ...
Short-lived fission gas release from fuel pellets during irradiation was investigated based on the experimental results of the gas-flow rigs irradiated in the Halden Heavy Water Reactor (HBWR). The release-to-birth (R/B) rates of short-lived fission gas were measured by means of gas-flow measurement during the irradiation experiments. Surface-to-volume (S/V) ratios of fuel pellets and diffusion coefficients of short-lived fission gas release were evaluated from the obtained (R/B) values. The increase of (S/V) ratio agreed well with the point where the fuel temperature exceeded the threshold of 1% fission gas release. This indicates that the interlinkage of fission gas bubbles occurred there. The evaluated diffusion coefficients scattered in the range between 10"-"2"3 and 10"-"1"7 m"2/s, and the effects of fuel type (UO_2 or MOX) were not ...
The European gas market is continuing to expand due to increased industrial, domestic and power generation demand. As a result of this demand, and the trend toward liberalization of the market, the need for storage of gas is also increasing. One key segment of the large scale storage of gas is underground storage, either in partially depleted gas or oil fields, naturally occurring caverns, aquifers and salt cavities. In most cases the gas produced after storage requires conditioning to meet the water of hydrocarbon dew point specification of the gas transmission system. For that reason export gas from storage will require gas conditioning in order to meet pipeline specifications. Adsorption as a feasible and reliable process will be presented in detail and especially in regards to hydrocarbon dew-pointing compared with ...
Geologically estimated natural gas resources are 500 Tcm. With the advance in geological science increase of estimated resources is expected. Natural gas reserves in 2000 have been proved to be around 165 Tcm. As it is known the reserves are subject to two constraints, namely: capital invested in the exploration and drilling technologies used to discover new reserves. The natural gas scarcity factor, i.e. ratio between available reserves and natural gas consumption, is around 300 years for the last 50 years. The new discovery of natural gas reserves has given rise to a new energy strategy based on natural gas. Natural gas utilization is constantly increasing in the last 50 years. With new technologies for deep drilling, we have come to know that there are enormous gas resources available at relatively low price. These ...
Geologically estimated natural gas resources are 500 Tcm. With the advance in geological science increase of estimated resources is expected. Natural gas reserves in 2000 have been proved to be around 165 Tcm. As it is known the reserves are subject to two constraints, namely: capital invested in the exploration and drilling technologies used to discover new reserves. The natural gas scarcity factor, i.e. ratio between available reserves and natural gas consumption, is around 300 years for the last 50 years. The new discovery of natural gas reserves has given rise to a new energy strategy based on natural gas. Natural gas utilization is constantly increasing in the last 50 years. With new technologies for deep drilling, we have come to know that there are enormous gas resources available at relatively low price. These ...
Two-phase flow in horizontal parallel channels has been experimentally investigated under fuel cell related operating conditions. Pronounced hysteresis is observed in the pressure drop versus flow characteristic curve when starting from either flooded or dry conditions. When gas is introduced into channels initially filled with water (flooded initial condition), both gas and liquid tend to flow predominantly in one channel at low gas or liquid flow velocities. As the gas flow velocity increases, even distribution of gas and liquid flow in both channels is observed, accompanied with a sudden decrease in the pressure drop. On the other hand, even gas and liquid flow distribution between both channels is found at comparatively lower gas flow velocities when starting with dry-gas flow conditions with liquid introduced into ...
A report is given of a meeting of the Netherlands Association for Energy Legislation (NEVER), which was held in Amsterdam, Netherlands, April 2006. After the meeting a presentation was made about the report 'Government involvement in liberalised gas markets. A welfare-economic analysis of the Dutch gas-depletion policy' of the Netherlands Bureau for Economic Policy Analysis (CPB). This report analyses the welfare effects of two major components of the Dutch gas-depletion policy: the offtake guarantee for small-fields gas and the cap on production from the Groningen field. After the presentation a reaction was given to the report. Both presentations give an overview of the governmental policy and insight in the effects.
A high-density gas jet supersonic nozzle is reported in this paper. The jitter and actuation time of the nozzle is determined by the pin discharge and laser spark radiation respectively. The jitter time of the nozzle is within 10 ?s with the backing pressure as high as 25 bar. With a nanosecond laser pulse focused on the gas jet about 1 mm below the nozzle, the actuation time is calculated to be about 15 ms by detecting the laser produced spark radiation, which reveals the existence of the gas jet and the relative gas density evolving with time. Consequently the gas density is estimated to be well above 1019 cm-3, compared with theoretical simulations from the nozzle parameters.
Some aspects of the PSO scheme for natural gas are examined critically. Two central arguments used for justifying the PSO subsidy scheme of natural gas and its distribution are reviewed; these include the 'smallholder argument' and the 'environmental argument'. The 'smallholder argument' claims that since Norway has the natural gas resources, it should also make use of the natural gas in the country, and not simply send the raw material to other countries. The 'environmental argument' states that natural gas compared to other fossil fuels such as coal and fuel oil, is a far cleaner alternative, thus an environmental-friendly alternative entitled to financial support. The arguments are critically examined by the author (ml)
We report on the discovery of kinematic shock signatures associated with a localized radio jet interaction in the merging Seyfert galaxy NGC 5929. We explore the velocity-dependent ionization structure of the gas and find that low-ionization gas at the interaction site is significantly more disturbed than high-ionization gas, which we attribute to a local enhancement of shock ionization due to the influence of the jet. The characteristic width of the broad low-ionization emission is consistent with shock velocities predicted from the ionization conditions of the gas. We interpret the relative prominence of shocks to the high density of gas in the nuclear environment of the galaxy and place some constraints of their importance as feedback mechanisms in Seyferts.
Natural gas is a promising alternative fuel to meet strict engine emission regulations in many countries. Natural gas engines can operate at lean burn and stoichiometric conditions with different combustion and emission characteristics. In this paper, the operating envelope, fuel economy, emissions, cycle-to-cycle variations in indicated mean effective pressure and strategies to achieve stable combustion of lean burn natural gas engines are highlighted. Stoichiometric natural gas engines are briefly reviewed. To keep the output power and torque of natural gas engines comparable to those of their gasoline or Diesel counterparts, high boost pressure should be used. High activity catalyst for methane oxidation and lean deNOx system or three way catalyst with precise air-fuel ratio control str...
During the 1990's, natural gas was the energy source with the fastest rate of growth in the world energy balance. Nevertheless, recent evolutions of the energy context, in particular in terms of prices, have had a rather strong impact on the progress of the different energy sources penalizing gas a little. Beyond this competition between energies, which may increase, the medium-term perspectives of natural gas development is in keeping with an environment full of uncertainties. This article presents: the world supply and demand prospects for 2010-2015 (impact of high gas prices on other energy sources, occurrence of production constraints, political decisions of producing countries and world gas industry balance), trends on main markets (North America, Europe, Asia-Oceania), and international trade. (J.S.)
An increasing share of natural gas supplies distributed to residential appliances in the U.S. may come from liquefied natural gas (LNG) imports. The imported gas will be of a higher Wobbe number than domestic gas, and there is concern that it could produce more pollutant emissions at the point of use. This report will review recently undertaken studies, some of which have observed substantial effects on various appliances when operated on different mixtures of imported LNG. While we will summarize findings of major studies, we will not try to characterize broad effects of LNG, but describe how different components of the appliance itself will be affected by imported LNG. This paper considers how the operation of each major component of the gas appliances may be impacted by a switch to LNG, and how this local impact may affect overall safety, performance and pollutant emissions.
The 575-mile Statpipe gas transportation system entails 191 miles of wet-gas line running from the Statfjord field across the Norwegian trench to the Karsto, Norway, conditioning plant and 384 miles of dry-gas line from Karsto, again across the trench, to the Heindal and Sleipner fields for final connection at Ekofisk with the Norpipe system for transport to Emden, West Germany. Special construction considerations include the 1000-ft-deep trench crossings, the rocky shore approach and departure, and the subsea tie-ins required at depths of up to 500 ft. The system has an initial annual design capacity of 186 billion CF of wet gas and 260 billion CF through the dry-gas line to Emden.
The Sulige gas field and the Yulin gas field are located in the north of the Ordos Basin. Reservoir pressure in the Sulige area is subnormal, whereas reservoirs in the Yulin area have normal hydrostatic pressure. This paper provides an explanation of this difference. The characteristics of reservoir sediment and formation water chemistry in the gas reservoirs of these two areas were analyzed. The results showed that both reservoirs have good sealing ability. Data of numerical simulation showed that tectonic uplift resulted in a great reduction in formation pressure in the northern Ordos Basin during the late Cretaceous period, and the decrease was greater in the Yulin gas field than in the Sulige gas field. However, because the total hydrocarbon-generating intensity of the Sulige area (<24...
The Granger instantaneous-causality test is applied to explore the potential causal relationships between wholesale electricity and natural-gas prices in California. The test shows these relationships to be bi-directional, and reveals California's electricity and natural-gas markets to be as inextricably intertwined as casual observation and theoretical considerations would suggest they ought to be. This meshing of markets exacerbated the effects of California's natural-gas crisis on the contemporaneous electricity crisis, while concurrently the electricity crisis may have contributed to the dysfunction in the national-gas market and helped to precipitate the natural-gas crisis. The finding supports an integrated approach, as opposed to a piecemeal approach, for formulating energy policy recommendations, not just in California but in the world at large. (author)
The Granger instantaneous-causality test is applied to explore the potential causal relationships between wholesale electricity and natural-gas prices in California. The test shows these relationships to be bi-directional, and reveals California's electricity and natural-gas markets to be as inextricably intertwined as casual observation and theoretical considerations would suggest they ought to be. This meshing of markets exacerbated the effects of California's natural-gas crisis on the contemporaneous electricity crisis, while concurrently the electricity crisis may have contributed to the dysfunction in the national-gas market and helped to precipitate the natural-gas crisis. The finding supports an integrated approach, as opposed to a piecemeal approach, for formulating energy policy recommendations, not just in California but in the world at large.
Classical semiconductor physics has been continuously improving electronic components such as diodes, light-emitting diodes, solar cells and transistors based on highly purified inorganic crystals over the past decades. Organic semiconductors, notably polymeric, are a comparatively young field of research, the first light-emitting diode based on conjugated polymers having been demonstrated in 1990. Polymeric semiconductors are of tremendous interest for high-volume, low-cost manufacturing (''printed electronics''). Due to their rather simple device structure mostly comprising only one or two functional layers, polymeric diodes are much more difficult to optimize compared to small-molecular organic devices. Usually, functions such as charge injection and transport are handled by the same material which thus needs to be highly optimized. The present work contributes to expanding the knowledge on the physical mechanisms determining device performance by ...
The authors report the transient enhanced diffusion of supersaturated phosphorous in ion-implanted SPE grown Si. Precipitation proceeds rapidly to a metastable SiP phase, which can be converted to an orthorhombic form or re-dissolved by subsequent heat treatment. The effects are strongly temperature dependent, and consistent with the trapped interstitial model. The behavior of different dopants follow their relative interstitialcy diffusion coefficients. The results suggest that ion implantation induced point defects dominate over thermally activated point defects during low temperature and certain rapid thermal processing, controlling dopant deactiviation and diffusion in crystalline or amorphous silicon, and can also affect the SPE growth rate.
We have studied in detail the transient enhanced diffusion observed during furnace or rapid-thermal-annealing of ion-implanted Si. We show that the effect originates in the trapping of Si atoms by dopant atoms during implantation, which are retained during solid-phase-epitaxial (SPE) growth but released by subsequent annealing to cause a transient dopant precipitation or profile broadening. The interstitials condense to form a band of dislocation loops located at the peak of the dopant profile, which may be distinct from the band formed at the original amorphous/crystalline interface. The band can develop into a network and effectively getter the dopant. We discuss the conditions under which the various effects may or may not be observed, and discuss conflicting observations on As"+ implanted Si.
The authors have studied in detail the transient enhanced diffusion observed during furnace or rapid-thermal-annealing of ion-implanted Si. The authors show that the effect originates in the trapping of Si atoms by dopant atoms during implantation, which are retained during solid-phase epitaxial (SPE) growth but released by subsequent annealing to cause a transient dopant precipitation or profile broadening. The interstitials condense to form a band of dislocation loops located at the peak of the dopant profile, which may be distinct from the band formed at the original amorphous/crystalline interface. The band can develop into a network and effectively getter the dopant. They discuss the conditions under which the various effects may or may not be observed, and discuss preliminary observations on As/sup +/ implanted Si. 12 references, 12 figures.
We have studied in detail the transient enhanced diffusion observed during furnace or rapid-thermal-annealing of ion-implanted Si. We show that the effect originates in the trapping of Si atoms by dopant atoms during implantation, which are retained during solid-phase-epitaxial (SPE) growth but released by subsequent annealing to cause a transient dopant precipitation or profile broadening. The interstitials condense to form a band of dislocation loops located at the peak of the dopant profile, which may be distinct from the band formed at the original amorphous/crystalline interface. The band can develop into a network and effectively getter the dopant. We discuss the conditions under which the various effects may or may not be observed, and discuss conflicting observations on As/sup +/ implanted Si.
The authors have studied in detail the transient enhanced diffusion observed during furnace or rapid-thermal-annealing of ion-implanted Si. The authors show that the effect originates in the trapping of Si atoms by dopant atoms during implantation, which are retained during solid-phase epitaxial (SPE) growth but released by subsequent annealing to cause a transient dopant precipitation or profile broadening. The interstitials condense to form a band of dislocation loops located at the peak of the dopant profile, which may be distinct from the band formed at the original amorphous/crystalline interface. The band can develop into a network and effectively getter the dopant. They discuss the conditions under which the various effects may or may not be observed, and discuss preliminary observations on As"+ implanted Si. 12 references, 12 figures.
In this work, we describe the fabrication and operating characteristics of GaAs/AlGaAs thin film solar cells processed by the epitaxial liftoff (ELO) technique. This technique allows the transfer of these cells onto glass substrates. The performance of the lifted-off solar cell is demonstrated by means of electrical measurements under both dark and illuminated conditions. We have also optimized the light trapping conditions in this direct-gap material. The results show that good solar absorption is possible in active layers as thin as 0.32 {mu}m. In such a thin solar cell, the open circuit voltage would be enhanced. We believe that the combination of an epitaxial liftoff thin GaAs film, and nano-texturing can lead to record breaking performance. {copyright} {ital 1997 American Institute of Physics.}
The complex thermally stimulated luminescence (TSL) pattern of NaAlSi_3O_8 has been analyzed on transparent and opaque varieties of natural crystals and synthetic pure powder. The existence of seven additional peaks in the range 20 to 450 "0C following X-irradiation at room temperature (RT) is reported, also evaluated by the curve fitting method. The validity of the analysis is discussed in the light of detailed trap analysis of KAlSi_3O_8. An attempt has been made to probe the excistence of high temperature peaks beyond 450 "0C using UV stimulation at RT. All the TSL peaks analyzed follow a second-order kinetic process.
This report reviews Soviet R and D of (1) high-intensity negative ion sources and (2) transport and focusing of negative ion beams, using Soviet open literature of the past ten years, and correlates this data with data on Soviet institutes responsible for negative ion beam development. The Soviets are developing intense negative ion beams as the basis for creating neutral beams for injection into mirror traps and tokamaks, for inertial confinement fusion, and possibly for exoatmospheric beam weapon applications. The report focuses specifically on surface-plasma-type ion sources, which were first developed in the USSR and which show great promise for creating beams of high intensity, high brightness, and low emittance. Mechanisms for optimum negative ion beam transport are also discussed.
We study spontaneously generated entanglement (SGE) between two identical multilevel atoms in free space via vacuum-induced radiative coupling. We show that the SGE in two-atom systems may initially increase with time but eventually vanishes in the time scale determined by the excited state lifetime and radiative coupling strength between the two atoms. We demonstrate that a steady-state SGE can be established by incoherently pumping the excited states of the two-atom system. We have shown that an appropriate rate of incoherent pump can help producing optimal SGE. The multilevel systems offer us more chanel to establish entanglement. The system under consideration could be realized in a tight trap or atoms/ions doped in a solid substrate.
Abstract Intrasexual selection can occur through direct aggressive interactions between males for access to females. We tested the relationship between social dominance and male reproductive success among meadow voles, Microtus pennsylvanicus. Dominance ranks of wild-caught males were determined using neutral arena trials, with the winner of two of three trials considered dominant. These males were then released into field enclosures and allowed to visit females housed in nestboxes for 8 wk, and males' home range sizes were determined using weekly grid trapping. Male reproductive success was determined using molecular paternity analysis (six microsatellite primers) for all pups born during the field experiment. Males with higher dominance ranks had larger home ranges. However, male dominan...
Reactions of reducing species from acetonitrile media with silver iodide particles (#approx#25-angstrom diameter) have been investigated by pulse radiolysis techniques. Injection of electrons into these ultrasmall particles leads to transient bleaching of the adsorption of AgI at wavelengths close to the onset of absorption (#approx#400 nm) with the concomitant reduction of AgI to metallic silver. The reduction of Ag"+ ions and formation of silver atoms and/or dimeric Ag_2 molecules on three different size AgI particles (#approx#100, 35, and #approx#25 angstrom) have also been examined by picosecond laser spectroscopy.
Seasonal and habitat calliphorid abundance and distribution were examined weekly for two years (2001-2003) in Santa Clara County, California, using sentinel traps baited with bovine liver. Of the 34,389 flies examined in three defined habitats (rural, urban, and riparian), 38% of the total catch represented Compsomyiops callipes (Bigot) and 23% represented Phormia regina (Meigen). Other flies collected in this survey included Calliphora vomitoria (Linnaeus), Calliphora latifrons (Hough), Lucilia sericata (Meigen), Lucilia cuprina (Wiedemann), and Lucilia mexicana (Macquart), which is a new record for the area. Multivariate MANOVA and ANOVA (P 0.05) analysis indicate significant seasonal habitat preference for all fly species examined. This information may be used to identify potentially fo...
We study the effects of quantum production of open strings on the relativistic scattering of D-branes. We find strong corrections to the brane trajectory from copious production of highly-excited open strings, whose typical oscillator level is proportional to the square of the rapidity. In the corrected trajectory, the branes rapidly coincide and remain trapped in a configuration with enhanced symmetry. This is a purely stringy effect which makes relativistic brane collisions exceptionally inelastic. We trace this effect to velocity-dependent corrections to the open string mass, which render open strings between relativistic D-branes surprisingly light. We observe that pair-creation of open strings could play an important role in cosmological scenarios in which branes approach each other at very high speeds. (author)
During the last two years, the performance of the Penning trap mass spectrometer ISOLTRAP at ISOLDE/CERN (Geneva) has been considerably enhanced. Many technical improvements have been completed (i) to access nuclides that are produced in minute quantities of only 100 ions s/sup -1/, (ii) to increase the relative mass accuracy to
A compilation of technical papers, from the 23rd annual Precise Time and Time Interval (PTTI) Applications and Planning Meeting, is presented. Papers were given in the following categories: (1) developments in rubidium, cesium, and hydrogen-based frequency standards, and in cryogenic and trapped-ion technology; (2) international and transnational applications of PTTI technology with emphasis on satellite laser tracking networks, GLONASS timing, comparison of national time scales and international communications; (3) applications of PTTI technology to the telecommunications, power distribution, platform positioning, and geophysical survey industries; (4) applications of PTTI technology to evolving military communications and navigation systems; and (5) dissemination of precise time and frequency by means of GPS, GLONASS, MILSTAR, Loran, and synchronous communications satellites.
This paper describes new strategies for the brain-specific delivery of radionuclides that can be used to evaluate regional cerebral perfusion by single photon imaging techniques. A description of several examples of interesting new strategies that have recently been reported is presented. A new approach at this institution for the brain-specific delivery of radioiodinated iodophenylalkyl-substituted dihyronicotinamide systems is described which shows good brain uptake and retention in preliminary studies in rats. Following transport into the brain these agents appear to undergo facile intracerebral oxidation to the quaternized analogues which do not recross the intact blood-brain barrier and so are effectively trapped in the brain. 49 refs., 9 figs., 1 tab.
The goals of this paper are to describe new strategies being pursued at several institutions for the brain-specific delivery of radionuclides that can be used to evaluate regional cerebral perfusion by single photon imaging techniques. A comprehensive review of the literature is beyond the scope of these proceedings and our goal is to, therefore, present a description of several examples of interesting new strategies that have recently been reported. In addition, the authors also describe a new approach being pursued at their institution for the brain-specific delivery of radioiodinated iodophenylaklyl-substituted dihydronicotiamide systems which shows good brain uptake and retention in preliminary studies in rats. Following transport into the brain these agents appear to undergo facile intracerebral oxidation to the quaternized analogues which do not cross the intact blood-brain-barrier and are effectively trapped in the brain.
After irradiation at 254nm of aqueous solutions of the antipsychotic drug flupentixol, the structures of the photodegradation products were determined by ultra high performance liquid-chromatography linked to mass spectrometry. Fragmentation patterns of the parent ions were established on a hybrid linear ion trap-orbitrap mass spectrometer allowing accurate mass measurements of both parent and daughter ions. This allowed to propose plausible structures for the main photolysis products of flupentixol. A total of nine photoproducts were detected after irradiation of the drug. The main photoproduct is generated following the addition of a hydroxyl group on the double bond adjacent to the thioxanthene ring. Secondary photoproducts were also observed.
The irradiation behavior of Li{sub 2}TiO{sub 3} under a fusion reactor environment was simulated by simultaneous irradiation of Li{sub 2}TiO{sub 3} by the triple ion beams and the respective single ion beams of O{sup 2+}, He{sup +} and H{sup +}. The microstructural changes in Li{sub 2}TiO{sub 3} caused by the irradiation were measured by Raman spectroscopy and FT-IR photoacoustic spectroscopy. The results suggest that the formation of TiO{sub 2} due to displacements by irradiation occurs, and the irradiation defects generated by irradiation trap hydrogen and increase the amount of hydroxyl near the surface. Such phenomena are believed to significantly affect the chemical form of the released tritium and the tritium inventory in the breeding materials of a fusion reactor.
The irradiation behavior of Li_2TiO_3 under a fusion reactor environment was simulated by simultaneous irradiation of Li_2TiO_3 by the triple ion beams and the respective single ion beams of O"2"+, He"+ and H"+. The microstructural changes in Li_2TiO_3 caused by the irradiation were measured by Raman spectroscopy and FT-IR photoacoustic spectroscopy. The results suggest that the formation of TiO_2 due to displacements by irradiation occurs, and the irradiation defects generated by irradiation trap hydrogen and increase the amount of hydroxyl near the surface. Such phenomena are believed to significantly affect the chemical form of the released tritium and the tritium inventory in the breeding materials of a fusion reactor.
The development of new efficient afterglow phosphors is currently hampered by a limited understanding of the persistent luminescence mechanism. Radioluminescence (RL) and x-ray absorption measurements on the persistent phosphor SrAl2O4:Eu,Dy were combined to reveal possible valence state changes for the rare earth (co)dopants. Traps in the phosphor material are quickly filled when exposing thermally emptied SrAl2O4:Eu,Dy powder to x rays. On the same time scale a partial oxidation of Eu2+ to Eu3+ is observed by x-ray absorption near-edge spectroscopy (XANES), while for the trivalent dysprosium the valence state remains unchanged. The impact of these observations on the recently proposed models for persistent luminescence is discussed.
Samples of vitamin D fortified orange juice obtained from retail food stores were analyzed for vitamin D3 content using a method developed by combining the best features of two AOAC methods. Detection by ultraviolet absorption at 265nm was compared to detection by selected ion monitoring (SIM) using atmospheric pressure chemical ionization (APCI) mass spectrometry (MS). Furthermore, an ion trap (IT) mass spectrometer was employed in a 'dual parallel MS' arrangement to simultaneously obtain qualitative APCI-ITMS data. The method was applied to 33 samples of 3 national American orange juice brands and 7 samples of 5 other American brands collected using a statistically designed sampling plan as part of the National Food and Nutrient Analysis Program to provide values for the USDA National Nu...
We have developed a process for chemical purification of carbon nanotubes for solution-processable thin-film transistors (TFTs) having high mobility. Films of the purified carbon nanotubes fabricated by simple drop coating showed carrier mobilities as high as 164 cm2V?1s?1, normalized transconductances of 0.78 Sm?1, and on/off current ratios of 106. Such high performance requires the preparation of a suspension of micrometer-long and highly purified semiconducting single-walled carbon nanotubes (SWCNTs). Our purification process includes length and electronic-type selective trapping of SWCNTs using recycling gel filtration with a mixture of surfactants. The results provide an important milestone toward printed high-speed and large-area electronics with roll-to-roll and ink-jet device fabri...
An effect of laser-cooling of water was observed for the first time with a temperature decrease dT = -2.2 K after irradiation of liquid water surface by a powerful Ar-Xe pulse laser with a pulse energy of about 1 J and wavelength L = 1.73, 2.63 and 2.65 um. The discovered effect can apparently be ascribed to the optical excitation of vibrational states of H2O molecules followed by an endothermic consolidation of chemically active excited molecules into a quasi-stable cluster-like structure. The measured time dependences of the cooling effect show that a typical life time of the new state of water amounts to hours. It has also been shown that the life time of the excited vibrational molecular states due to a radiation trapping effect can be estimated to at least hundreds of seconds.
Laboratory studies have been carried out to determine the toxicity of methiocarb pellets to wild trapped wood mice in order to provide some background data prior to any further evaluation of hazard in the field. In this study, wood mice were exposed to dry and to dampened methiocarb pellets in order to reproduce field trial application conditions. Field observations of methiocarb pellets indicate that the physical character changes under dry and wet weather conditions. This may affect their relative attractiveness and potential toxicity to wood mice. The laboratory assessment of exposed wood mice included measurement of brain esterase activities, methiocarb residues in selected mouse tissue, carcasses, and histological evaluation of kidney, liver and lungs.
We report the use of ion beam induced charge imaging to characterise the charge signal uniformity of epitaxial gallium nitride radiation detectors. The detectors were fabricated from 2 {mu}m thick semi-insulating gallium nitride, grown by MOCVD on a sapphire substrate. A carrier concentration of 1.4x10{sup 15} cm{sup -3} was measured using capacitance-voltage measurements. Ion beam induced charge imaging was carried out with a 2 MeV alpha particle beam focussed to a 3 {mu}m diameter and raster scanned across the device. The resulting ion beam images show excellent charge signal uniformity in this material with no evidence of material defects or polycrystalline structure on the micrometer length scale. No evidence of charge signal trapping was observed in these devices.
Efficient, low-temperature conversion of infrared light into visible light (red, orange, green) is reported at single heterojunctions and undoped quantum wells of GaAs and ordered Al_xGa_1_-_xInP_2; an increase in photon energy of 700 meV is obtained. The signal originates from the high-band-gap layers and disappears only if the excitation energy is tuned below the GaAs band gap. The intensity of the up-converted photoluminescence (PL) is found to decrease significantly slower with increasing temperature than that of the regular PL and it remains observable up to 200 K. Interface-induced cold Auger processes along with the presence of trapped states for both electrons and holes in these ordered alloys account for this nonlinear mechanism. A colinear double-beam experiment confirms this. copyright 1996 The American Physical Society.
The proposed active sites on the catalyst surface in heterogeneous propylene ammoxidation have been successfully modelled by structurally characterized pinacolato W(VI) tert-butylimido complexes. These compounds exist as an equilibrating mixture of amine-bis(imido) and imido-bis(amido) complexes, the position of this equilibrium is dependent on the electronic nature of the glycolate ligand. Both of the C-N bond-forming reactions proposed in recent studies by Grasselli et al. (1) have been reproduced using discrete Group VI d{sup 0} organoimido complexes under mild conditions suitable for detailed mechanistic studies. These reactions are: (1) oxidative trapping of radicals at molybdenum imido sites, and (2) migration of the allyl group from oxygen to an imido nitrogen atom.
Summary Indigenous people demonstrably lived along rivers and around lakes and wetlands of Australia's Murray-Darling Basin in pre-European times. Waterways were, and continue to be, of major significance to the society and culture of Aboriginal peoples throughout Australia. Historically, they exploited most of the fauna - from mussels and crayfish, to fish and birds - and either ate, or used for other purposes, many species of aquatic plants. Such practices placed them in the role of environmental modifiers, a role played by all human groups from both past and present. They built sophisticated fish traps, cut gaps in river banks to allow fish to move on to floodplains, and there is evidence that they practised a form of fish culture by creating small impoundments in which small fish could...
The Hanford Waste Vitrification Plant Project has been established to convert the high-level radioactive waste associated with nuclear defense production at the Hanford Site into a waste form suitable for disposal in a deep geologic repository. The Hanford Waste Vitrification Plant will mix processed radioactive waste with borosilicate material, then heat the mixture to its melting point (vitrification) to forin a glass-like substance that traps the radionuclides in the glass matrix upon cooling. The Hanford Waste Vitrification Plant Quality Assurance Program has been established to support the mission of the Hanford Waste Vitrification Plant. This Quality Assurance Program Description has been written to document the Hanford Waste Vitrification Plant Quality Assurance Program.
Abstract Gaseous microemboli (GME) remain a challenge for cardiopulmonary bypass (CPB) because there is a positive correlation between microemboli exposure during CPB and postoperative neurological injury. Thus, minimizing the number of GME delivered to pediatric patients undergoing CPB procedures would lead to better clinical outcomes. In this study, we used a simulated CPB model to evaluate the effectiveness of capturing GME and the degree of membrane pressure drop for a new membrane oxygenator, Capiox Baby FX05 (Terumo Corporation, Tokyo, Japan), which has an integrated arterial filter with open and closed purge line. We used identical components in this study as our clinical CPB circuit. Three emboli detection and classification quantifier transducers were placed at prepump, preoxygena...
AbstractBackground In recent years nano-metaloxides which easily penetrate into the cells with special interest due to their higher chemical reactivity as compared to that of similar materials in the bulk form. Of particular interest are nano-TiO2 and ZnO, which have been widely used for their bactericidal and anticancerous properties. Purpose The aim of the present study was to examine the bactericidal properties of nano-TiO2 and ZnO combined with visible light on S. aureus and S. epidermitis, known for their high prevalence in infected wounds. Study Using the technique of electron-spin resonance (ESR) coupled with spin trapping, we examined the ability of TiO2 and ZnO nanoparticle suspensions in water to produce reactive oxygen species (ROS) with and without visible light irradiation. Th...
A brief summary of the theory and experiments on electron- cyclotron heating and current drive is presented. The general relativistic formulation of wave propagation and linear absorption is considered in some detail. The O-mode and the X-mode for normal and oblique propagation are investigated and illustrated by several examples. The experimental verification of the theory in T-10 and D- III-D is briefly discussed. Quasilinear evolution of the momentum distribution and related applications as, for instance, non linear wave, damping and current drive, are also considered for special cases of wave frequencies, polarization and propagation. In the concluding section we present the general formulation of the wave damping and current drive in the absence of electron trapping for arbitrary values of the wave frequency. (Author) 13 refs.
The primary charge separation in photosynthetic bacteria generates a dimeric bacteriochlorophyll (BChl) cation and a bacteriopheophytin (BPheo) anion which lie within close proximity of each other (approx. 10 A). The two radicals also lie within van der Waals contact on opposite sides of a lone BChl bridging molecule. Spectral changes in the red (Q/sub y/) band of the bridge BChls have been observed on picosecond time scales following excitation of the reaction center (RC) and have been variously attributed to the formation of a BChl anion, to a charge-transfer state, or to electrochromic effects. They present calculations here which suggest that electrochromic effects caused by the photogenerated cation and/or anion can rationalize the optical changes observed in the flash photolyses as well as in trapping experiments.
We have analyzed the MHD flow of a conducting couple stress fluid in a slit channel with rhythmically contracting walls. In this analysis we are taking into account the induced magnetic field. Analytical expressions for the stream function, the magnetic force function, the axial pressure gradient, the axial induced magnetic field and the distribution of the current density across the channel are obtained using long wavelength approximation. The results for the pressure rise, the frictional force per wave length, the axial induced magnetic field and distribution of the current density across the channel have been computed numerically and the results were studied for various values of the physical parameters of interest, such as the couple stress parameter ?, the Hartmann number M, the magnetic Reynolds number R and the time averaged mean flow rate ?. Contour plots for the stream and magnetic force functions are obtained and the trapping phenomena for the flow field ...
Thinning and burning forests established on revegetated mine pits in jarrah (Eucalyptus marginata) forests of south-west Australia is being considered as a management option to accelerate succession in sites with excessive tree densities. To assess the impact of thinning and burning on reptiles and small mammals, we installed trapping grids in eight thinned and burned sites, each paired with untreated controls. Of the eight pairs, four were in rehabilitated sites (planted with nonlocal species) and four were in restored sites (seeded with local species). Thinning and burning had no significant impact on the small mammal community, although Cercatetus concinnus was more abundant in rehabilitated sites. In contrast, thinning and burning significantly increased reptile abundance and species r...
To study the defect creation induced by electronic processes in refractory oxides, MgO single crystals were irradiated with high energy tin, uranium and lead ions. Optical absorption measurements showed that F-type centers (oxygen vacancies with trapped electrons) were created during irradiation. The total number of centers per unit area of bombarded sample increases linearly with irradiating fluence. The main part of the point defects was found to arise from electronic processes. The concentration of F-type centers induced by ionization increases with the electronic energy losses. Assuming a saturation of point defect concentration at high fluences, F-type center creation cross sections could be estimated. The influence of irradiation temperature and of the velocity of the bombarding ions are discussed.
A review of the deep-level defects observed in both electron- and proton-irradiated GaAs solar cells is presented. Studies of the effects of periodic and continuous thermal annealing on the radiation-induced electron and hole traps and the recombination parameters in GaAs solar cells were made for a wide range of electron and proton energies, fluence, annealing temperature and annealing time. A refined model for numerical simulations of the displacement damage was developed for computing the defect density and the cell parameters in the electron- and proton-irradiated GaAs solar cells. Excellent agreement was obtained between the calculated values and the experimental data for the proton-irradiated GaAs solar cells. (orig.).
A research was started aiming at evaluating the possible use of natural zeolites as exchange conditioners to improve and make durable the soil resilience against the adverse effects of the use of anomalous waters for irrigation purposes. This paper deals with a preliminary investigation on the comparative resilience of an Entisol with poor exchange properties and of a Neapolitan yellow tuff (NYT) sample against the adverse features of a dirty municipal sewage (DSW). Results showed that NYT treatment largely and significantly improved the poor soil exchange activity. In particular. NYT exchange sites selectively took up ammonium from DSW. As a consequence, ammonium was trapped, then protected against losses in the environment and, concurrently, exchangeable cations, such as K and Ca, were made free as plant nutrients. The results highlight the possible positive role of zeolitized tuff in restoring and sustaining soil resilience.
We review our recent work on an atomistic approach to the development of predictive process simulation tools. First principles methods, molecular dynamics simulations, and experimental results are used to construct a database of defect and dopant energetics in Si. This is used as input for kinetic Monte Carlo simulations. C and B trapping of the Si self- interstitial is shown to help explain the enormous disparity in its measured diffusivity. Excellent agreement is found between experiments and simulations of transient enhanced diffusion following 20-80 keV B implants into Si, and with those of 50 keV Si implants into complex B-doped structures. Our simulations predict novel behavior of the time evolution of the electrically active B fraction during annealing.
In this work, we investigated self-heating related instability in polysilicon thin film transistors (poly-Si TFTs) fabricated on polyimide (PI) substrates. Indeed, when Joule heating becomes relevant, the temperature of the active layer can substantially rise, since the devices are fabricated on thermally insulating substrates. As a result, electrical instability is triggered and attributed to the generation of interface states, due to the Si-H bond breaking, and charge trapping into the gate insulator. In addition, by using 3-dimensional numerical simulations, coupling the thermodynamic and transport models, we analyzed the temperature distribution of the device under operating conditions and found that self-heating is more severe for devices fabricated on plastic substrates.
The optically stimulated luminescent (OSL) radiation dosimeter technically surveys a wide dynamic measurement range and a high sensitivity. Optical fiber dosimeters provide capability for remote monitoring of the radiation in the locations which are difficult-to-access and hazardous. In addition, optical fiber dosimeters are immune to electrical and radio-frequency interference. In this paper, a novel remote optical fiber radiation dosimeter is described. The optical fiber dosimeter takes advantage of the charge trapping materials CaS:Ce, Sm that exhibit OSL. The measuring range of the dosimeter is from 0.1 to 100 Gy. The equipment is relatively simple and small in size, and has low power consumption. This device is suitable for measuring the space radiation dose and also can be used in high radiation dose condition and other dangerous radiation occasions. (authors)
We present a single solid-state laser system to cool, coherently manipulate and detect $^{25}$Mg$^+$ ions. Coherent manipulation is accomplished by coupling two hyperfine ground state levels using a pair of far-detuned Raman laser beams. Resonant light for Doppler cooling and detection is derived from the same laser source by means of an electro-optic modulator, generating a sideband which is resonant with the atomic transition. We demonstrate ground-state cooling of one of the vibrational modes of the ion in the trap using resolved-sideband cooling. The cooling performance is studied and discussed by observing the temporal evolution of Raman-stimulated sideband transitions. The setup is a major simplification over existing state-of-the-art systems, typically involving up to three separate laser sources.
In this study the technical and economical possibilities of burning carbon monoxide (CO) of the flue gas and utilizing of the released heat in hot air cupola furnace used for melting have been studied. As basis for examining was burning of cleaned furnace...
The paper is an overview of utility flue gas desulfurization (FGD) technology and costs. The two commercially offered throwaway and salable product systems that are considered to be the most important for near-term (through 1990) SO2 control are: throwawa...
This patent describes a method of improving the S0{sub 2} scrubbing efficiency of flue gas desulfurization scrubbers. It comprises conducting the scrubbing operation in such scrubbers in the presence of an oil-soluble surfactant.
Gas turbine component protection remains essential but environmental regulations emphasize the gas-turbine efficiency. Heating and cooling are features often integrated into the GI air intake packages to provide the optimum operating conditions. This paper describes modern inlet air treatment systems and discusses their effectiveness. (author)
The structure of the skin in the epauletted fruit bat (Epomophorus wahlbergi) wing and body trunk was studied with a view to understanding possible adaptations for gas metabolism and...Full Text Available
The genetic type, source and charging history of natural gas in the Yulin gas field in the Ordos Basin have been studied by combining the carbon isotopic composition of natural gas and geochemical characteristics of light hydrocarbons with carbon isotope fractionation model results and fluid inclusion analysis. The carbon isotopic composition of methane and ethane in the Yulin gas field is relatively enriched in ^1^3C with d^1^3C1 values ranging from -35.3%% to -29.8%% (average value=-32.4%%) and d^1^3C2 ranging from -26.3%% to -23.5%% (average value=-24.8%%). The C7 light hydrocarbons are predominated by methylcyclohexane, accounting for 65.8% to 80.9% (average value=71.6%), which is characteristic of coal-derived gas. Furthermore, the gas geochemistry indicates that, although marine lime...
The Bureau of Mines performed chemical research to elaborate details of sulfur chemistry pertaining to the citrate flue gas desulfurization process in which sulfur dioxide (SO2), absorbed (as bisulfite ion) in a buffered sodium citrate solution, is reduce...
This report gives the results of a survey of operational flue gas desulfurization (FGD) systems on coal-fired utility boilers in the United States. The FGD systems installed on Units 1 and 2 at the Bruce Mansfield Station of the Pennsylvania Power Company...
A catalytic process for the oxidation of sulfur-containing gases , E.G., sulfur dioxide and simultaneous production of sulfuric acid wherein a sulfur-containing gas is reacted with an oxygencontaining gas in the presence of a catalyst comprising an iron group metal on a solid support comprising a zeolite in a silicaalumina matrix.
Gas exchange between the plant and the environment is severely hampered when plants are submerged, leading to oxygen and energy deficits. A straightforward way to reduce these shortages of oxygen and...Full Text Available
TSS (thermal swing sublimation) method was studied which uses vaporization heat and sensible heat of LNG for solidification and separation of CO2 gas in waste gases of LNG-fired combined cycle power generation system. In experiment, the mixed gas composed of CO2, H2O and N2 was used for simulating waste gas of LNG-fired combined cycle power generation systems, and the growth behavior of ice and dry ice was studied for developing dry ice making technology under low-temperature condition. As the experimental result, the following were clarified: various crystal structures depending on cooling temperature, the effect of gas flow rate on peeling of surface precipitated solids, and solidification characteristics of H2O/CO2 mixed gas. The growth rate of precipitated solid film thickness decreased with an increase in gas flow rate, while increased with CO2 ...
Limestone slurry needs to move efficiently through a complex process, meaning that selecting the right pumps and valves is critical. The article discusses factors to consider in selecting pumps and values for flue gas desulfurization process in coal-fired power plants. 2 photos.
The possibility has been explored of using a laser scattering technique to detect the imminent onset of rock activity associated with gas outbursts. The instrument described in this paper provides a sensitive, remote and rapid means of passively monitoring micro-seismic activity at the exposed face.
Petroleum is the unchallenged energy market leader in West Germany,having a share of 42%; natural gas accounts for 16-17%. West Germany imports 29% of its natural gas from the Soviet Union, 28% from the Netherlands, 14% from Norway, and 1% from Denmark. In West Germany many-branched natural gas distribution system is operated, equipped with a.o. 21 installations for underground storage which results in a great flexibility of the system. Because of the preferential treatment given to the use of coal as fuel for power plants the share of natural gas has decreased to the present 6% in the last ten years. In the indutrial sector the share is 18%. Strict air pollution abatement measures ('TA-Luft') favour the use of natural gas. However, duty has been levied on the use of natural gas per January 1st, 1989. For space heating of houses and commercial ...
The Monthly Energy Review provides an overview of the production, distribution, and consumption of energy derived from petroleum natural gas, coal, electricity, and nuclear energy. It also discusses oil and gas resource development, energy prices, and issues relevant to international energy markets.
This report presented some quick facts about oil and gas pipelines in Turkey and presented opportunities for trade. The key players and customers in the oil and gas sector were described along with an export check list. Turkey is looking into becoming an energy bridge between oil and gas producing countries in the Middle East, Central Asia and Europe. The oil and gas sectors are dominated by the Turkish Petroleum Corporation, a public enterprise dealing with exploration and production, and the State Pipeline Corporation which deals with energy transmission. They are also the key buyers of oil and gas equipment in Turkey. There are several pipelines connecting countries bordering the Caspian Sea. Opportunities exist in the areas of engineering consulting as well as contracting services for oil and gas pipeline transmission and distribution. Other opportunities ...
The report gives results of the measurement of dissolution rates of reagent CaCO3 and commercial limestones (9 types/19 grinds) at constant pH and solution composition by batch titration with HC1. Conditions were selected to simulate flue gas desulfurizat...
The influence of geometry and operating conditions of the centrifugal compressor stage on the radial gas force is determined on the basis of the theoretical method and calculation program using experimental boundary conditions.
... Radon gas concentrations are measured using instruments with calibrations traceable to the UK National Physical Laboratory and PTB, Germany. The primary facility is a 43 m3 walk-in chamber accessed by an airlock. Radon gas is maintained at a level in this chamber that is ...
The various steps of gas treatment in the Sasol II coal liquefaction plant are discussed: CO/sub 2/ removal, separation of the hydrocarbon fractions and the recirculated hydrogen by low-temperature decomposition, production of pure hydrogen by alternating pressure absorption.
Jeltes, R., Burghardt, E., and Breman, J. (1971). Brit. J. industr. Med., 28, 96-99. Gas chromatographic determination of phosgene and dichloroacetylene in air. Phosgene and dichloroacetylene...Full Text Available
An experimental investigation of heat transfer characteristics for various configurations of air jets impinging on the leading edge inner surface of a gas turbine blade wall is presented. Three configurations were investigated, namely a slot jet, a round ...
The goal of GRI's Gas Appliance Technology Center is to encourage the introduction of highly efficient, cost-effective, convenient gas appliances for residential and commercial gas users. The report covers activity at Battelle from February 1989 to April 1990 in broad support tasks, residential and commercial appliances, and residential space conditioning. Broad support tasks included the G/A/S Newsletter; the GATC InfoBase; and technology transfer, workshops, and GATC coordination. Residential appliance tasks included burner technology research, gas appliance venting, gas lighting, and plastics durability. Commercial appliance tasks included development of a commercial cooktop fuel/air mixing valve. Residential space conditioning tasks included a corrosion test method for gas appliances and vents, generic technology for condensing ...
This paper summarizes the current scientific and technological knowledge about greenhouse gas emissions from various agricultural practices and the manufacturing of food. The study also provides estimates that compare agriculture-related alternatives for reducing greenhouse gas emissions.
Legal aspects of using natural gas as boiler fuel for electric utilities are reviewed through one utility's challenges to the Power Plant and Industrial Fuel Use implementation. ASARCO vs. FPC, 1973, and City of Willcox vs. FPC are discussed. (PSB)
The report, generated by a computerized data base system, presents a survey of operational and planned domestic utility flue gas desulfurization (FGD) systems, operational domestic particle scrubbers, and Japanese coal-fired utility FGD installations. It ...
The report presents detailed technical information concerning application of flue gas desulfurization (FGD) systems to industrial boilers. The information was obtained by a survey of plant personnel, control system vendors, regulatory agencies, and consulting engineering firms. T...
The report discusses the capabilities of equipment vendors to supply and install the quantity of flue gas desulfurization systems required to meet alternative standards for coal-fired steam generators. It analyzes limiting factors affecting supply capabilities (such as the availa...
The effects of freeze-thaw cycling on the strength and durability of samples of compacted, stabilized, wet flue gas desulfurization (FGD) by-products are reported. The results of laboratory tests show a clear relationship between higher water contents and...
NO[sub x] emission legislation requirements for large-bore internal combustion engines have required engine manufacturers to continue to develop and improve techniques for exhaust emission reduction. This paper describes the development of the Cooper-Bessemer Clean Burn gas-diesel (dual-fuel) engine that results in NO[sub x] reductions of up to 92 percent as compared with an uncontrolled gas-diesel engine. Historically, the gas-diesel and diesel engine combustion systems have not responded to similar techniques of NO[sub x] reduction that have been successful on straight spark-ignited natural gas burning engines. NO[sub x] levels of a nominal 1.0 g/BHP-h, equal to the spark-ignited natural gas fueled engine, have been achieved for the gas-diesel and are described. In addition, the higher opacity exhaust plume characteristic of gas-diesel ...
Concentration of an amine solution for removal of hydrogen sulfides and carbon dioxide from natural gas, is tested by carbon dioxide absorption measurement in an apparatus allowing complete reaction to give reliable results.
The increasing price differential between natural gas and coal will create a demand for technology that can allow the displacement of natural gas with coal in power plants. Coal gasification is the standard approach suggested to allow coal to displace natural gas. However, the relatively high capital investment required for coal gasification will require fuel cost differentials higher than those anticipated in the near term before coal gasification replaces natural gas. One way of achieving shorter term displacement of natural gas by coal would be to develop technology that would allow coal to be used as the heat source for the endothermic reforming of natural gas. In a natural gas-fired combined cycle power plant, the endothermic heat of reforming, which would be provided by coal combustion, is recovered in the combined-cycle. Therefore, ...
At the St. Joe Minerals Corp.'s zinc smelter powerplant, an SO2 emission control program evolved into a cooperative program with the Bureau of Mines for installation and initial operation of a citrate process flue gas desulfurization demonstration plant. ...
The report describes a computer model developed by TVA to simulate the performance and determine the economics of coal cleaning, or coal cleaning combined with flue gas desulfurization (FGD), for power plant emission control processes over a wide range of user-specified condition...
The manual describes a combined coal-cleaning and flue gas desulfurization (FGD) computerized design and cost-estimate model and gives detailed procedures for using it. All inputs and outputs are described, as well as the various options available. Design and economic premises ar...
This project addresses the problem of flue gas desulfurization (FGD) sludge disposal to land. Specifically, the chemical species of FGD sludge constituents are thermodynamically modeled using the equilibrium constant approach, in an attempt to predict the constituent concentratio...
The report gives an initial assessment of the feasibility of disposing of flue gas desulfurization wastes in mines and in the ocean. The purpose of the assessment was to evaluate environmental, technical, regulatory, and economic aspects of the use of such disposal sites. Availab...
Crockford, G. W., Crowder, M., and Prestidge, S. P. (1972).Brit. J. industr. Med.,29, 378-386. A trace gas technique for measuring clothing microclimate...Full Text Available
In this paper we have proposed a novel gas turbine cycle with hydrogen-fueled chemical-looping combustion, and the system study on two hydrogen-fueled power plants, the new gas turbine cycle and an advanced gas turbine cycle with H{sub 2}/O{sub 2} combustion, has been investigated with the aid of exergy principle (EUD methodology). The hydrogen fueled chemical-looping combustion in the new gas turbine cycle consists of two successive reactions: hydrogen fuel is reacted with metal oxide (reduction of metal oxide), and then instead of air or pure oxygen, the reduced metal is successively oxidized by the saturated air. As a result, the new hydrogen-fueled gas turbine cycle has a breakthrough performance, with at least about 12 percentage-point higher efficiency compared to the gas turbine cycle with H{sub 2}/O{sub 2} combustion, and will be environmentally superior ...
Gas-fired combined cycle plant may be the norm when it comes to new plant but it comes in a variety of shapes and sizes. Samarinda uses aero-derivatives with the famous Rolls-Royce RB211 gas generator. (author)
The feasibility of producing a pocket-sized air contaminant monitor based upon a miniature gas chromatograph and an integrated microcomputer has been demonstrated and a practical design for the instrument is presented. This pocket-sized instrument is intended to be used as a pers...
Apparatus and method for selective measurement of tritium oxide in an environment which may include other radioactive components and gamma radiation, the measurement including the selective separation of tritium oxide from a sample gas through a membrane into a counting gas, the generation of electrical pulses individually representative by rise times of tritium oxide and other radioactivity in the counting gas, separation of the pulses by rise times, and counting of those pulses representative of tritium oxide. The invention further includes the separate measurement of any tritium in the sample gas by oxidizing the tritium to tritium oxide and carrying out a second separation and analysis procedure as described above.
A high-voltage cathode initiates an electron emission, resulting in a reduction in the carbon dioxide concentration in exhaust gas from the burning of hydrocarbon fuel. Assuming that the observed carbon dioxide reduction is originated from the molecular decomposition, the energy needed for the endothermic reaction of this carbon dioxide reduction may stem primarily from the internal energy reduction in the exhaust gas in accordance of the first law of the thermodynamics. An oxygen increase due to the reduction in carbon dioxide in a discharge gas was observed in real time.
This report consists of three sections. The first section is a brief general overview of all the issues that impact the competition between natural gas and electricity in industrial applications. The second section of this report focus on the all the marketing issues and provides detail analysis of the status of these issues in Europe, Japan and United States. The third section of this report is a detail review of the current status of the competition between gas technologies and electro-technologies, it also make recommendation for developing new gas technologies. The fourth section is a contribution from M. Pettersson and S. Stenstroem, Sweden, on infrared dryers. (authors)
Makeup water is distilled internally in an amine gas treating unit by adding it to the reclaimer used to process a slipstream of lean amine from the stripper.
Experimental data on the gas holdup and the mean bubble size in a bubble column with a single nozzle was obtained for gas-molten salt systems of a eutectic mixture of LiCl (58 mol %)-KCl (42 mol %) and molten NaNO/sub 3/. The liquid-phase mass transfer coefficient K /SUB L/ was evaluated from the specific surface area a and the volumetric coefficient K /SUB L/ a data for oxygen and carbon dioxide absorption into molten NaNO/sub 3/. The dimensionless correlations of the performance of bubble columns for aqueous solutions can be extended to the gas-molten salt systems.
This dissertation deals with membrane gas absorption in the application of CO{sub 2} removal by aqueous alkanolamines, using microporous PTFE hollow fiber membranes. A new lab-scale apparatus was constructed and an extensive experimental study executed to determine the performance of the membrane gas absorber, with aqueous solutions of monoethanolamine (MEA) and methyldiethanolamine (MDEA) as absorbents. The important operation parameters CO{sub 2} partial pressure, gas velocity, liquid velocity, temperature and liquid CO{sub 2} loading were systematically varied within the range typically experienced in a process for exhaust gas CO{sub 2}-removal
This thesis dealt with the metal-organic gas phase epitaxy with nitrogen as carrier gas. For this first by means of three-dimensional modelings of the epitaxy process the influence of the carrier gas on the processes was explained. The optimization of the growth parameter for the whole light-emitting-diode structure in double-hetero arrangement resulted that an a temperature of 770 C and a V/ III-ratio of 150 layers with a high crystal quality could be reached.
Access for independents to retail gas markets was a central concern in European policy reform efforts in the 1990s. Upstream oil and gas companies reacted with strategic intentions of forward integration. By late 2004, forward integration was still weak, however. An important explanation of the gap between announced strategic re-orientation and actual strategy implementation lies in the political failure of EU member states to dismantle market barriers to entry for independents. Variations between companies in downstream strategy implementation are explained by variations in business opportunities and internal company factors.
Kawasaki Heavy Industries, Ltd. has developed a gas turbine combined cycle and cogeneration plant computer aided engineering (CAE) system, which creates cycle heat balance automatically on given configurations of gas turbines, heat recovery boilers, steam turbines and auxiliaries. The system can predict the performance of the plant as a function of control set points, loads, process steam requirements and ambient conditions, which enables accurate and fast design of gas turbine combined cycle and cogeneration plants. (author)
Dimethyl methylphosphonate (DMMP), a chemical simulant of the nerve gas GB, was decontaminated with a nonthermal atmospheric pressure plasma. The decontamination efficiency was measured qualitatively by means of Fourier transform spectroscopy and quantitatively by means of gas chromatography. With helium gas only, 10g/m2 of DMMP on an aluminum surface was 99.9% decontaminated in 2min, furthermore, with the addition of 5% of oxygen gas, it was 99.99% decontaminated in 10min. Given the low input power (<100W) and temperature (<75degreeC), this plasma is eligible for nondestructive decontamination of almost all material surfaces.
The purpose of this work was to develop and evaluate a method of locating breached fuel within the Fast Flux Test Facility (FFTF) reactor based on the relative response of the delayed neutron monitors (DNM) located on each of the three primary sodium cooling loops. The primary method of location is the use of tag gas containing unique ratios of the noble gases xenon and krypton. Although the tag gas system works quite well, it is relatively expensive because of the costs of preparing and loading the gas into each fuel pin. Triangulation of DNM signals could potentially decrease tag gas costs while maintaining overall location reliability.
Biogas supply to the public gas grid is a new option discussed in the most recent publication of Fachagentur Nachwachsende Rohstoffe (FNR) e.V. The biogas is purified, upgraded to natural gas quality and fed into an existing gas grid. Once there, it can be transported across long distances and also used for electric power generation at the consumer side. The study investigates inhowfar and in what instances this method is feasible and promising. It discusses the technical background and the regional potential of biogas. Seven model biogas systems are presented as examples. (orig.)
This paper is a quarterly report describing the use of a new soil gas collection device which allows the collection of soil gas in the field for later analysis in the laboratory. It describes the installation of this sampling device and the procedure for setting the probe, extraction of soil gas beneath the surface, and sealing of the soil gas for transport. The sites used for initial testing was the top of Yucca Mountain and Crystal Spring in Ash Meadows National Wildlife Refuge. The results from this initial test showed no volatile matter present in the soil at these locations.
The multicell proportional chambers at the backing calorimeter of the ZEUS experiment at the storage ring HERA are supplied with a gas mixture of Ar/CO[sub 2] by an open gas system. Flow proportional counters with the build-up [sup 55]Fe sources are used as gas system monitoring detectors. The ZEUS experiment is planned to collect data for about 10 years. Therefore, the lifetime of the Ar/CO[sub 2] mixture should be known. In this paper, the results of laboratory tests and preliminary measurements of the aging effects for monitoring counters are presented. ((orig.))
The risk perception of the public consists of two components: the objectively factual component and the subjectively irrational component. The two strategies adopted by the German gas supply industry are the internal and the external communication strategy. Concepts and measures of accident precaution, registration and analysis of accident data (installation and operating errors, defects on flue systems, pipelines and valves, subsequent installation of gas appliances) are discussed. (R.P.)
The energy price volatility model suggests that some of the proposed natural gas programs can contribute to energy price stability. The sector most vulnerable to fuel price variations is, of course, the transportation sector. The most effective strategy to achieve energy pace stability is to reduce petroleum consumption in this sector. The natural gas vehicle program is therefore recommended as potentially important and worthy of further consideration. At this point, distinguishing the merits of various subprograms is not feasible. This result farther supports the conclusion that the DOE`s energy R&D portfolio is not efficiently balanced and an increase in oil and gas research should be a high priority. The DOE has responded favorably and has significantly increased its proposed research with the explicit objective of displacing oil in the transportation sector. The enhanced research and development program for energy ...
This paper gives a Coulomb gas representation for level kN = 1 supersymmetric SU(2) Kac-Moody algebra in terms of three free scalar superfields. It is clarified how this representation reduces to a Coulomb gas representation for the corresponding bosonic SU(2) Kac-Moody algebra and the free fermionic algebra. The primary superfields and the correlation functions, which satisfy the supersymmetric Knizhnik-Zamolodchikov equation, are also discussed.
The US$360 million project to increase gas supplies to Eastern and Southern Thailand is discussed, and the use of international competitive bidding to purchase the line pipe and other facilities is reported. The government approved proposal for a gas fired combined-cycle power station and gas separation plant are discussed. (UK).
The need is substantiated for using remote control of technological processes on blowout dangerous beds. A method is proposed for this control based on recording with the help of AGZ apparatus for gas release into the roadway. Distinguishing features are indicated for the change in methane concentration in the roadway with normal occurrence of the process and in the case of blowout of coal and gas.
Smart electricity and gas supply grids are a prerequiste for full-scale utilization of the potential of modern energy-saving appliances and equipment. Direct exchange of information between the supplier and the consumer is indispensable for reducing costly and energy-intensive peak loads. (orig.)
This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid vapor condensed in both the high temperature and low temperature ...
This invention pertains to a Fischer Tropsch process for converting synthesis gas to an oxygenated hydrocarbon with particular emphasis on dimethyl ether. Synthesis gas comprising carbon monoxide and hydrogen are converted to dimethyl ether by carrying out the reaction in the presence of an alkali metal-manganese-iron carbonyl cluster incorporated onto a zirconia-alumina support.
To suppress space charge blowup in an ion beam passing through a photoneutralizer, it is necessary to introduce some background gas. An analysis is presented of the neutralization of a high-energy, >200-keV negative deuterium ion beam, exposed to photodetachment while in the presence of deuterium. With a gas thickness of <0.01 Torr.cm, the neutral fraction in the output beam is found to be about the same as that gotten from the photoneutralizer operating in vacuum. Neutral atom beam injection for plasma heating is discussed.
This paper describes a practical knowledge on gas engine performance and combustion characteristics which are required by experimental studies for two types of developed gas burning engines, i. e. a spark ignited gas engine and a dual fuel engine, and also introduces their practical use and application. As for dual fuel engine performance, a manifold air pressure of about 27% was decreased, a scavenging ratio of 23% reduced and an exhaust temperature at the turbine inlet on 14% was increased at the gas engine operation under the mean effective cylinder pressure of 1.22 MPa in comparison with the diesel operation. Furthemore, empirical data on the effect of excess air ration on the engine performance and combustion characteristics, a risk of knocking during changing over on the dual fuel engine operation, and the rated output in case of using alternate fuel gas were reported. Two ...
Triassic sedimentary rocks are widespread in the Pechora sineclise and Pre-Uralian edge trough territory. They are up to 920 and 400 m thick respectively. Commercial flows of oil and gas have been obtained from these deposits in the last few years. The geology of the area is described and its is concluded that the main oil and gas potential should be connected with the northern areas of the Pechora sineclise.
I propose that an interpretation of the interaction of noble gas atoms with metal surfaces as predominantly physisorbing provides the best explanation for the systematics of their binding energies and surface dipoles, as well as for the tendency of noble gas atoms to bind in low coordinated sites. In the present context physisorption is defined as a process driven by the overlap of the electrostatic atomic potentials of the interacting species. (orig.)
The technical and economic feasibility of using a typical, elemental, phosphorus byproduct gas stream in methanol production is assessed. The purpose of the study is to explore the potential of a substitute for natural gas. The first part of the study establishes economic tradeoffs between several alternative methods of supplying the hydrogen which is needed in the methanol synthesis process to react with CO from the off gas. The preferred alternative is the Battelle Process, which uses natural gas in combination with the off gas in an economically sized methanol plant. The second part of the study presents a preliminary basic design of a plant to (1) clean and compress the off gas, (2) return recovered phosphorus to the phosphorus plant, and (3) produce methanol by the Battelle Process. Use of elemental phosphorus byproduct gas in methanol ...
This paper reports that Sen. Bennett Johnston (D-La.) has vowed if Congress enacts an omnibus energy bill in the fall, it will not include a restriction on states' rights to proration natural gas production. Johnston, Senate energy committee chairman, will lead Senate conferees in their negotiations with members of the House of Representatives. The House energy bill has an antiproration amendment. The Senate's bill does not. Oklahoma's and Texas' recent actions to proration gas production prompted the federal legislation.
The 66 fields discovered since the 1960s in the northern West Siberian basin contain at least 22 trillion m/sup 3/ (777 tcf) of proved gas, almost one-third of the world's reserves. Half of these fields are giants (> 85 billion m/sup 3/ or 3000 bcf of reserves). These include the largest and second-largest gas fields in the world-Urengoy (8.099 trillion m/sup 3/ or 286 tcf of gas) and Yamburg (4.81 trillion m/sup 3/ or 170 tcf of gas)-as well as most of the other ten largest gas fields in the world. The West Siberian basin occupies a 3.4-million km/sup 2/ (1.31-million mi/sup 2/) arctic lowland immediately east of the Ural Mountains, extending north under the Kara Sea. It is a composite basin, with Mesozoic-Cenozoic basin fill on top of a Paleozoic basin that overlies a crystalline Archean-Proterozoic framework. The productive zones in the northern basin are principally ...
Cattle or chicken manure is pelletized, and a bed of the pellets is combusted at the bottom to create a temperature gradient and to generate a fuel gas. Thus, an approximately 25 cm-high bed of approximately 5 mm-diameter chicken manure pellets was combusted to produce a fuel gas of 1622 kcal/kg manure.
There are several concerns which bring to consider natural gas as a viable alternative to liquid fuels in transport. First, natural gas allows the curbing of global pollution in this steadily growing industry. Indeed, decoupling greenhouse gas emissions from transport growth has become a major issue in tackling climate change. Second, a more extensive use of natural gas would relieve city air quality, which is presently at levels harmful of human health. Nonetheless, this is just one side of the coin. The other side entails building a refuelling station network, and this carries financial requirements. The financing fraction holds a pivotal role in deciding whether natural gas for automotive purposes is an efficient solution. The final aim of this work is, therefore, to compare the natural gas advantages, stemming from avoided global and local emission, with the ...
In order to facilitate observations of low energy nuclear reactions, a new type recoil mass-separator together with a new gas-jet target system is being developed at the tandem accelerator facility in Kyushu University. The expected mass-resolving power of the separator is 220 for a solid angle of 10 msr and the practical thickness of the gas-jet target will exceed 0.1 atm#centre dot#cm for the light elements of H and He. (author).
The EPA proposed effluent limitations guidelines and standards for the offshore segment of the oil and gas industry on August 26, 1985. On November 26, 1990, and March 13, 1991, the Agency reproposed effluent limitations guidelines and standards for both drilling and production wastes. The report is primarily concerned with the total annualized cost incurred by the offshore oil and gas industry in complying with the regulations.
In a suicide committed using aluminium phosphide (AlP) the liberated toxic phosphine gas was detected in post-mortem specimens using a headspace gas chromatographic procedure with a nitrogen-phosphorous detector (HS-GC/NPD). At autopsy a direct sampling into airtight headspace vials for a later analysis is recommended. AlP has to be considered a potent pesticide and its use and availability should be restricted as much as possible.
A new process for the removal of tar from biosyngas, OLGA (Oil and Gas Washer), is presented. This gas cleaning technology is based on physical principles and is designed to eliminate tar problems that relate to fouling and er pollution. The applied principles are confirmed by experimental validation. OLGA can be operated without suffering from harmful effects on important gasification characteristics as cold gas efficiency, gasifier simplicity, and feedstock flexibility. Some fundamental considerations in the development of OLGA are discussed. Amongst these is a different approach to the tar problem. This approach does not consider the total tar content as decisive in the evaluation of gas cleaning equipment. Instead, evaluation is focussed on whether tar properties as condensation behaviour and water solubility can still occur. A biosyngas free of tar should therefore be synonymous to a biosyngas that ...
Gas separation membranes with polydimethylsiloxane(PDMS)/polystyrene(PS) were prepared by using the sequential interpenetrating polymer network (IPN) method with various PS contents (10?70wt%). These gas separation membranes can be applied to reduce the smoke density in the emission gas of diesel engines. PS content has a pronounced effect on the membrane performance. It was found that the optimized PS contents in the final membrane were 50wt%. The emission capacities of diesel engines used in this study were 632 cc and 11,149 cc. When the oxygen separation membrane was used in the diesel engines, the smoke density of both diesel engines was remarkably reduced (35?73%). The oxygen concentration in the inlet air affects the composition of the emission gases. Especially, hydrocarbon (HC) dec...
Thailand's demand for gas will outstrip supplies in the late 1990s as rapid economic growth continues. Gas will be a cornerstone for Thai energy policy throughout the growth, although sources in neighboring countries need development. Thai gas production will rise 25% from 1992 to average 1 bcfd by 1995. Including production from new discoveries, production could rise to 1.5 bcfd by 2000, up almost 90% from the 1992 level. Increased gas flow output in the mid-1990s will be due largely to development of Gulf of Thailand fields. By 1998, production from Gulf of Thailand fields will not be enough to offset the decline in today's fields. Thailand will need to import more than 1 bcfd by 2005 in the absence of future discoveries in the country. The paper discusses new pipelines and imports.
The ElectroStatic Precipitator (ESP) removes dust and tar droplets very efficiently from biomass product gas. Dust was removed for more than 99%. The tar dewpoint was reduced from 130C to 21C, which is sufficient for the application of the product gas in a gas engine. Tar removal is not sensitive to the voltage or fluctuations in the gas residence time . The voltage was varied between 28 to 37 kV{sub arith} and the gas residence time between 4 and 11s. Fouling of the ESP collector plates was negligible, which was concluded from visual inspection after 200 hours of operation. A reduction in the residence time reduces the size of the ESP and has a significant impact on the investment costs of the ESP. Keywords: electrostatic filter, tar removal, circulating fluidised bed (CFB)
The Gas Research Institute established the Gas Appliance Technology Center (GATC) in 1982 to develop improved gas appliances. Between 1986 and 1992, the scope of GATC activities at Battelle included technology transfer and overall industry support, residential appliances, commercial appliances, and residential space conditioning. The following tasks are representative of the GATC activities described in the report; gas burner technology, appliance venting, emissions, water heating, range/oven technology, self-powered appliances, commercial cooktop burners, reconstituting ovens, appliance reliability improvement, combination space-heating/water-heating systems, condensing heat exchangers, corrosion testing, and space heating technology. The report includes references to available sources for further reading.
The method is related to hydrodynamic methods for studying wells and may be used in the prospecting and mapping of gas and gas condensate deposits and formations. The method consits of drilling exploratory wells and measurement of the physical parameters of the stratum liquid. The piezometric levels are periodically determined simultaneously in all the observation wells during a change in the atmospheric pressure, and the presence of a remoteness of the gas deposit from the well is judged from the size of the increments in the piezometric levels intime. The determinations of the piezometric levels in the wells are conducted during an abrupt change in atmospheric pressure, for instance, during the replacement of a cyclone by an anticyclone or the reverse. The atmospheric pressure is measured by a barograph, while the piezometric levels are measured by high precision level meters or pressure gauges of low pressure. The method ...