Energy Technology Data Exchange (ETDEWEB)

A water trap system based on a thermoelectric cooling device is employed to remove a major fraction of the water from air samples, prior to analysis of these samples for chemical composition, by a variety of analytical techniques where water vapor interferes with the measurement process. These analytical techniques include infrared spectroscopy, mass spectrometry, ion mobility spectrometry and gas chromatography. The thermoelectric system for trapping water present in air samples can substantially improve detection sensitivity in these analytical techniques when it is necessary to measure trace analytes with concentrations in the ppm (parts per million) or ppb (parts per billion) partial pressure range. The thermoelectric trap design is compact and amenable to use in a portable gas monitoring instrumentation.

Science.gov (United States)

The analysis of complex fluids such as crude oils, fuels, vegetable oils and mixed waste streams poses significant challenges arising primarily from the multiplicity of components, the different properties of the components (polarity, polarizability, etc.) and matrix properties. We have recently introduced an analytical strategy that simplifies many of these analyses, and provides the added potential of linking compositional information with physical property information. This aspect can be used to facilitate equation of state development for the complex fluids. In addition to chemical characterization, the approach provides the ability to calculate thermodynamic properties for such complex heterogeneous streams. The technique is based on the advanced distillation curve (ADC) metrology, which separates a complex fluid by distillation into fractions that are sampled, and for which thermodynamically consistent temperatures are measured at atmospheric pressure. The ...

Science.gov (United States)

No abstract available.

Energy Technology Data Exchange (ETDEWEB)

The automotive paints could be generally differentiated by color, layer sequence and chemistry of the paint layers comprising each of the topcoat and the primer system. The successful identification of hit-and-run a and traffic accidental vehicles from evidential paint fragments is greatly facilitated with a comprehensive laboratory collection of reference paint samples and the technique for direct analysis without sample preparation. The Pyrolysis-Gas Chromatography(PGC) is a precise and reliable method for performing both quantitative and qualitative analysis of polymeric materials and forensic samples. Our Forensic Laboratory is conducting the examination and identification of 73 reference paint samples; 4 colors of each domestic automotive make that is poplar in Korea, by Curie Point Pyrolyzer(JHP-3) and GC with capillary column(ultra alloy-5). This method can be used not only to compare paint traces with their ...

International Nuclear Information System (INIS)

This paper presents the analytical results of alcohols, esters and organic acids in sweet potato wine irradiated by #gamma#-rays. (author).

Energy Technology Data Exchange (ETDEWEB)

This report describes the sampling and chemical analyses of smoke gas components for combustion performed in the SP Industry Calorimeter, where continuous measurements of oxygen, carbon dioxide and carbon monoxide are an integrated part of the Calorimeter system. On-line measurements of nitrogen oxides and total amounts of unburnt hydrocarbons were performed. Hydrogen cyanide, hydrogen chloride and ammonia in the smoke were sampled and absorbed in impinger bottles and subsequently analyzed using wet chemical techniques. An adsorbent sampling system was designed to allow the identification and quantitative analysis of individual organic compounds in the smoke. Gas chromatography was utilized with a mass spectrometric detector for the identification and a FID for quantification of the total amounts as well as individual components. A procedure for cleaning the smoke gas duct in ...

Energy Technology Data Exchange (ETDEWEB)

Polyethylene pipes and connections are being widely used in treated water distribution services. Migration of low molecular weight compounds from the polyethylene into the water can change its final quality. This paper is about the concentrations and identification of the migration compounds found in treated water after staying in contact with low and high-density polyethylene. Identification and quantification were carried out using CLSA (Closed Loop Stripping Analysis) extraction technique and gas chromatography coupled to mass spectrometry (HRGC/HRMS). (Author) 12 refs.

International Nuclear Information System (INIS)

Research and development activities are reported on absorption spectroscopy, calorimetry, electrolysis, emission spectroscopy, fluorimetry gas chromatography, infrared spectroscopy, liquid chromatography, liquid scintillation counting, mass spectroscopy, microscopy, radiometric analysis, and thermal analysis. A group of miscellaneous projects are also described.

British Library Electronic Table of Contents (United Kingdom)

18a(H)-, 18b(H)-oleanane and lupane are angiosperm-derived biomarkers that are used as age indicators for the Late Cretaceous onwards when the first proliferation of angiosperms occurred. In addition, the 18a(H)-/18b(H)-oleanane ratio is employed as a thermal maturity parameter of crude oil. However, evidence has shown that accurate quantification of these compounds has been impeded by inadequate chromatographic separation by traditional one-dimensional gas chromatography. In this study, we present the separation of 18a(H)-, 18b(H)-oleanane and lupane with comprehensive two-dimensional gas chromatography (GCxGC). Furthermore, it was observed that 18b(H)-oleanane elutes earlier than 18a(H)-oleanane in second dimension (polarity) which we attribute to steric hindrance effects. Two GC conditi...

International Nuclear Information System (INIS)

The fission gas xenon bonded in bubbles, in pore, and in the lattice of mixed carbide fuels is measured by electron-probe microanalysis. Radial xenon distribution and release curves are determined and are calibrated by gas chromatography of the bonded fission gas and by burnup analysis in the respective pin sections of the irradiation experiments FR2 6A and 6C, Mol 11/K 2, and DFR 330/1. The results are correlated to the microstructure of the fuel, bonding medium, temperature, and burnup. (Auth.).

UK PubMed Central (United Kingdom)

Fatty acid biomarker analysis coupled with gas chromatography-isotope ratio mass spectrometry was used to confirm the presence of methanotrophic and thiotrophic bacterial endosymbionts in the tissues...Full Text Available

UK PubMed Central (United Kingdom)

A Legionella-like organism (strain 1087-AZ-H) was isolated from a pleural-fluid specimen from a renal transplant patient undergoing immunosuppressive therapy. Growth characteristics and gas-liquid chromatography...Full Text Available

UK PubMed Central (United Kingdom)

BackgroundLiquid chromatography-mass spectrometry (LC-MS) is one of the major techniques for the quantification of metabolites in complex biological samples. Peak modeling is one...Full Text Available

International Nuclear Information System (INIS)

Volatile compounds produced in flexible food packaging materials (LDPE, EVAc, PET/PE/EVOH/PE) during electron beam irradiation were isolated by purge and trap technique and identified by combined gas chromatography-mass spectrometry (GC/MS), after thermal desorption and concentration. For comparison purposes non-irradiated films were also studied. Film samples were irradiated at low (5 kGy, corresponding to cold pasteurization), intermediate (20 kGy, corresponding to cold sterilization) and high (100 kGy) doses. It was observed that a number of volatile compounds are produced after irradiation in all cases. Furthermore the amounts of all volatile compounds increase with increasing irradiation dose. Both primary (methyl-derivatives etc.) as well as secondary i.e. oxidation products (ketones, aldehydes, alcohols, carboxylic acids etc.) are produced upon irradiation. These products may affect organoleptic properties and thus ...

British Library Electronic Table of Contents (United Kingdom)

Purpose To study the chemical modifications induced upon irradiation of solid human insulin at radiosterilization doses and investigate the influence of the absorbed dose on radiolysis. Materials and Methods Volatile radiolytic products were monitored by gas chromatography coupled with mass spectrometry (GC-MS) and non-volatile products by two different high performance liquid chromatography (HPLC) methods: the formation of higher molecular weight proteins was assessed by size exclusion liquid chromatography whereas assays for related compounds and chemical potency tests were carried out using reverse-phase HPLC-UV. Conformational changes were investigated by measurements of circular dichroism. Results After gamma irradiation at 10?kGy, the recovery of insulin was 96.8%; higher molecular w...

British Library Electronic Table of Contents (United Kingdom)

Dimethyl methylphosphonate (DMMP), a chemical simulant of the nerve gas GB, was decontaminated with a nonthermal atmospheric pressure plasma. The decontamination efficiency was measured qualitatively by means of Fourier transform spectroscopy and quantitatively by means of gas chromatography. With helium gas only, 10g/m2 of DMMP on an aluminum surface was 99.9% decontaminated in 2min, furthermore, with the addition of 5% of oxygen gas, it was 99.99% decontaminated in 10min. Given the low input power (<100W) and temperature (<75degreeC), this plasma is eligible for nondestructive decontamination of almost all material surfaces.

Science.gov (United States)

The thermodynamic characteristics of sorption of the isomeric tricyclo[5.2.1.02.6]decane (tetrahydrodicyclopentadiene, TDCPD) molecules were for the first time determined experimentally and by molecular statistical methods under the conditions of gas-adsorption chromatography on graphitized thermal carbon black and gas-liquid chromatography on stationary liquid phases of different polarities (Apiezon L and Carbowax 20M). The effects of the chemical nature of sorbents on the retention of the TDCPD isomers are considered. A procedure for calculating the thermodynamic characteristics of adsorption of molecules with a complex structure is suggested within the framework of the atom-atom approximation of the semiempirical molecular statistical theory of adsorption for the example of isostructural norbornane molecules. The procedure involves simultaneous variation of geometric parameters and refinement of the ...

Science.gov (United States)

Methods for the synthesis and quantitation of the novel choline analogues, telluronium choline and acetyltelluronium choline, are described. An assay procedure utilizing pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) with cold trapping was developed with [2H4]telluronium choline and [2H4]acetyltelluronium choline as internal standards. The telluronium compounds were ion-pair extracted from tissue with dipicrylamine, washed with 2-butanone, and pyrolyzed prior to GC-MS analysis. The compounds were monitored using selected ion monitoring at m/z 232 and m/z 190 for acetyltelluronium and telluronium choline, respectively, and at m/z 236 and m/z 194 for the analogous deuterated internal standards. The assay was linear over a range of 20 pmol-20 nmol of compound taken through the assay. PMID:8130881

Energy Technology Data Exchange (ETDEWEB)

The possibility of employing a number of adsorbents (polyphenylquinoxaline, Tenax GC, Carbopak C, graphitized thermal carbon black, silica gels modified with pyrocarbon or hexamethyldisilazane) for the trapping of organic traces from air has been investigated. Adsorption capacities of these adsorbents with respect to a number of volatiles released from certain plastics used as building material (polyvinylchloride, Relin, Acronal, etc.) have been measured. A number of the volatiles were identified by gas chromatography - mass-spectrometry after trapping on the adsorbents investigated. Chromatographic separation after trapping on the adsorbents was carried out on wall-coated open-tubular capillary columns as well as in capillary columns packed with graphitized thermal carbon black.

British Library Electronic Table of Contents (United Kingdom)

In this study, a novel graphene nanosheets (GNSs) coated solid phase microextraction (SPME) fiber was prepared by immobilizing microwave synthesized GNSs on a stainless steel wire. Microwave synthesized GNSs were verified by X-ray diffraction, field emission-scanning electron microscopy (FE-SEM) and transmission electron microscope (TEM). GNS-SPME fiber was characterized using FE-SEM and the results showed the GNS coating was homogeneous, porous, and highly adherent to the surface of the stainless steel fiber. The performance and feasibility of the GNS-SPME fiber was evaluated under one-step microwave assisted (MA) headspace (HS) SPME followed by gas chromatography with electron capture detection for five organochlorine pesticides (OCPs) in aqueous samples. Parameters influencing the extra...

International Nuclear Information System (INIS)

Since antioxidants have been shown to play a major role in preventing some of the effects of aging and photoaging in skin, it is important to study this phenomenon in a controlled manner. This was accomplished by developing a simple and reliable in vitro technique to assay antioxidant efficacy. Inhibition of peroxidation by antioxidants was used as a measure of relative antioxidant potential. Liposomes, high in polyunsaturated fatty acids (PUFA), were dispersed in buffer and irradiated with ultraviolet (UV) light. Irradiated liposomes exhibited a significantly higher amount of hydroperoxides than liposomes containing antioxidants in a dose- and concentration-dependent manner. Lipid peroxidation was determined spectrophotometrically by an increase in thiobarbituric acid reacting substances. To further substantiate the production of lipid peroxides, gas chromatography was used to measure a decrease in PUFA substrate. In order ...

International Nuclear Information System (INIS)

Brief summaries are given of research carried out in the following areas: absorption spectroscopy of titanium, niobium, and molybdenum in uranium alloys; atomic absorption spectroscopy of selenium in stainless steel, computer program improvements for spectrophotometer control, and detection of beryllium in stack gases; electrolysis for inactivation of bacteria in cooling-tower water; improved solvent analysis by gas chromatography; sequential radionuclide separation for various sample matrices; progress on an electron microprobe analyzer; and miscellaneous projects.

Energy Technology Data Exchange (ETDEWEB)

The retention indices of cycloalkenes and cycloalkadienes with C/sub 6/-C/sub 13/ rings are determined by gas-liquid chromatography (GLC) on glass capillary columns coated with OV-1 and Ucon LB 550X and by gas-solid chromatrography (GSC) on a microcolumn packed with uncoated graphitized thermal carbon black (GTCB). Structure-retention correlations are derived on using index differences such as H/sup OV/, H/sup GTCB/ and ..delta..I values, considering the differences in the stereochemistry of these compounds. It is shown that the combined application of index increments obtained in GLC and GSC provides more detaled structure informations. The value of the retention index units agree with the most stable conformations of the alicyclic compounds. The high value for the energy equivalent to an index unit (..delta..G/sub I.U./ = 4.18 kJ/mol) confirms that graphitized thermal carbon black causes much stronger dispersive ...

British Library Electronic Table of Contents (United Kingdom)

Fourier-transform infrared (FTIR) spectroscopy was used to monitor amino acids, organic acids, and changes during ripening. Twelve Cheddar cheese samples were ripened for 73 days and samples were drawn periodically. Water-soluble fractions of samples were analyzed by gas chromatography (20 amino acids), liquid chromatography (three organic acids), and FTIR spectroscopy (4000-700 cm-1). Spectra were correlated with chromatographic data and ripening events and analyzed by multivariate statistics to develop prediction and classification models. Most models showed a good fit (correlation coefficient > or =0.89) and could predict the levels of amino acids and organic acids and age of the cheese in less than 20 min. Lactic acid, leucine, glutamic acid, asparagine, phenylalanine, and valine were ...

Energy Technology Data Exchange (ETDEWEB)

The determination of the banned anabolic substance zeranol and the metabolites taleranol and zearalanone in bovine urine is complicated by the occurrence of the structurally-related mycotoxin zearalenone and the corresponding {alpha}- and {beta}-zearalenol metabolites which possess similar estrogenic properties. A liquid chromatography-negative ion electrospray tandem mass spectrometric method is presented for the confirmatory analysis of all six resorcylic acid lactones ('zeranols') in urine samples using deuterium-labelled internal standards. The method was validated as a confirmatory method for bovine urine samples according to new draft EU guidelines and showed good precision and linearity, and CC{alpha} and CC{beta} values of 0.02-0.30 and <1.0 ng ml{sup -1}, respectively. The applicability was demonstrated by comparing the results of an incurred sample with previous results on the same sample obtained by gas ...

Science.gov (United States)

PMID:7075772

British Library Electronic Table of Contents (United Kingdom)

Headspace solid-phase microextraction (HS-SPME) coupled to comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GCxGC-TOFMS) was applied for equilibrium headspace analysis of Malaysian soursop (Annona muricata) volatile flavor compounds. A two-level fractional factorial design (25-1) was used to determine the effect of SPME variables, namely, SPME fibers, adsorption temperature, extraction time, amount of salt, sample amount and sample concentration on the extraction efficiency of volatile flavor compounds. A total of 37 volatile compounds were identified, comprising 21 esters, 6 alcohols, 3 terpenes, 2 acids, 2 ketones, 2 aldehydes and an aromatic with different hydrophobicities (log P) ranging between -0.14 and 4.83. Extraction using 10g of diluted (5% w/w) ...

International Nuclear Information System (INIS)

The work presented here demonstrates the ability of proton-transfer-reaction mass spectrometry (PTR-MS) to perform fast-response measurements of volatile organic compounds (VOCs) (including methanol, acetonitrile, acetaldehyde, acetone, PAN-type compounds, alpha- and beta-pinene, nopinone and pinonaldehyde) at the pptv level and its versatile applicability in the field of environmental trace gas analysis. Laboratory and field experiments including various calibration techniques and intercomparisons with other measurement techniques such as gas chromatography, atmospheric pressure chemical ionization and Fourier transformation infrared spectroscopy were performed providing a first characterization of the PTR-MS instrument performance (sensitivity, detection limit, precision, accuracy). Typically a detection limit (S/N=2) of 50 pptv for a 10 s signal integration time, a precision of 5 ...

British Library Electronic Table of Contents (United Kingdom)

Successful electron capture dissociation (ECD) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) applications to peptide and protein structural analysis have been enabled by constant progress in implementation of improved electron injection techniques. The rate of ECD product ion formation has been increased to match the liquid chromatography and capillary electrophoresis timescales, and ECD has been combined with infrared multiphoton dissociation in a single experimental configuration to provide simultaneous irradiation, fast switching between the two techniques, and good spatial overlap between ion, photon, and electron beams. Here we begin by describing advantages and disadvantages of the various existing electron injection techniques for ECD in FT-ICR MS. We next ...

International Nuclear Information System (INIS)

Poly(lactic acid) (PLA) is attractive as a substitute for classical polymer packaging material due to its biodegradability and sufficient mechanical and barrier properties. Presented research was focused on the changes of basic mechanical parameters after ionizing irradiation performed with doses in the range of 2.5-25 kGy, commonly used in radiation sterilization and preservation of foods. Two commercial available PLA packaging films were tested. The influence of radiation dose on the mechanical properties - tensile strength and elongation were determined using standardized methods. Radiation resistance of PLA is sufficient for packaging applications. The investigations of gas products of radiolysis of PLA have been made by gas chromatography after electron beam (EB) irradiations. (authors)

Energy Technology Data Exchange (ETDEWEB)

Trichlorfon is an organophosphorus insecticide, which is extensively being used for protection of fruit crops. Trichlorfon is a thermal labile compound, which cannot be easily determined by gas chromatography (GC) and has no suitable group for sensitive detection by high performance liquid chromatography (HPLC). In this study, a {sup 31}P nuclear magnetic resonance ({sup 31}P NMR) has been described for monitoring of trichlorfon without any separation step. The quantitative works of {sup 31}P NMR spectroscopy has been performed in the presence of an internal standard (hexamethylphosphoramide). Limit of detection (LOD) for this method has been found to be 55 mg L{sup -1}, without any sample preparation, and the linear working range was 150-5500 mg L{sup -1}. Relative standard deviation (R.S.D.%) of the method for three replicates within and between days was obtained {<=}9%. The average recovery efficiency was ...

Science.gov (United States)

The technology for flue gas desulfurization (FGD) with seawater is widely adopted by coal-fired power plants in coastal areas. SO2 in the flue gas is absorbed by alkaline seawater and transfered in aqueous phase as sulfite (SO3(2-)), and most SO3(2-) is transformed to sulfate (SO4(2-)) after an aeration process. The remaining SO3(2-) in the seawater discharged to sea area may be harmful to marine organism because of its biological toxicity, thus it is necessary to determine the concentration of SO3(2-) in the seawater for desulfurization. In this study, the method of determination of SO3(2-) in the seawater by ion chromatography was investigated. The separation was achieved on an IonPac AS14A column with 14 mmol/L NaOH-12 mmol/L Na2 CO3 solution as the mobile phase at a flow rate of 1.2 mL/min, and the detection was performed by a pulsed amperometric detector. Formaldehyde was added as a protective agent when sampling ...

International Nuclear Information System (INIS)

Cisplatin (cis-diaminedichloroplatinum [II] is a coordination compound, used in the treatment of several solid tumors. Cisplatin and its hydrolysis products exhibit a great pharmacological effect but are very toxic and probably carcinogenic. The present review summarizes the most important advances in the last years in the techniques employed for the detection and quantification of cisplatin and its hydrolysis products and in the different matrixes studied. The new emerging techniques and their modifications recently developed, fundamentally the combined use of detection and separation techniques for the analysis of platinum species and their impact on the speed, sensitivity and specificity of the analytical determination, with regard to the techniques used in the last century are discussed. High-Performance Liquid Chromatography and Capillary Electrophoresis, coupled with detection ...

Energy Technology Data Exchange (ETDEWEB)

A fluidized bed combustor of 0.146 m diameter and 1 m length was fabricated from stainless steel to burn olive cake. Initially, and in order to obtain fluidization, the system was operated under cold conditions using a sand with particle size in the range of 500 to 710 microns. The continuous combustion experiments were carried out under controlled conditions, such that the effects of bed temperature, olive cake feed rate, fluidization velocity, and particle size on combustion efficiency and flue gas composition were investigated. It was found that the combustion efficiency decreases with the bed temperature, fluidization velocity, and the feed rate, while it increases with the particle size used. Further, the gas products analysis carried out using a gas chromatography analyzer have shown a nonmeasured amount of SO2, and small amounts of CO. Finally, the temperature distribution along the bed indicated ...

British Library Electronic Table of Contents (United Kingdom)

Solid-phase extraction and gas chromatography with electron-capture detection has been used for sensitive, simple, and reliable analysis of carfentrazone-ethyl residues in water. Carfentrazone-ethyl was enriched by use of multiwalled carbon nanotubes (MWCNT), a new adsorptive material. Several conditions affecting recovery of the analyte, for example polarity and volume of eluents, pH of water samples, and sample volume, were studied. Recovery from fortified samples, linear range, and limit of detection were evaluated. The results showed that MWCNT are an efficient SPE adsorbent for preconcentration of carfentrazone-ethyl in water. Under the optimized SPE conditions, recovery of carfentrazone-ethyl from fortified water was 81.49?91.08%, with RSD from 1.66 to 8.21%. The limits of detection ...

British Library Electronic Table of Contents (United Kingdom)

The thermodynamic characteristics of adsorption (TCA) on the basal face of graphite have been calculated in terms of the semiempirical molecular statistical theory of adsorption for molecules of O-, S-, and Se-containing heteroadamantanes of different structure and isostructural cyclohexane derivatives. The influence of the nature, number, and position of heteroatoms in the adamantane framework on the TCA values was studied in detail, which made it possible to predict the retention of the compounds considered on the surface of graphitized thermal carbon black under the conditions of equilibrium gas adsorption chromatography. The introduction of each subsequent heteroatom into a polyheteroadamantane molecule makes a non-additive contribution to the TCA values. The contributions of various f...

British Library Electronic Table of Contents (United Kingdom)

The flame retardancy of polybutylene terephthalate (PBT) was studied focusing on the effect of various oxides. Thermo-gravimetric analysis, pyrolysis/gas chromatography/mass spectrometry, and elemental analysis (EA) were used to analyze the flame retardancy, which were observed through the UL-test and a cone calorimeter. Many oxides influenced the flame retardancy and some of them could suppress the flammability of PBT. In particular, the blended-PBTs with ZnO and V2O5 accelerated the degradation and the edges of oxygen consumption were shorter than neat-PBT although the flammability became poorer. The quantitative analysis of the scission products and the results of EA showed that hydrolysis, successive dehydration, and other various reactions changed the scission route to generate less f...

British Library Electronic Table of Contents (United Kingdom)

Breath analysis could offer a non-invasive means of intravenous drug monitoring if robust correlations between drug concentrations in breath and blood can be established. In this study, propofol blood and breath concentrations were determined in an animal model under varying physiological conditions. Propofol concentrations in breath were determined by means of two independently calibrated analytical methods: continuous, real-time proton transfer reaction mass spectrometry (PTR-MS) and discontinuous solid-phase micro-extraction coupled with gas chromatography mass spectrometry (SPME-GC-MS). Blood concentrations were determined by means of SPME-GC-MS. Effects of changes in pulmonary blood flow resulting in a decreased cardiac output (CO) and effects of dobutamine administration resulting in...

Energy Technology Data Exchange (ETDEWEB)

We developed a surrogate mixture model to represent the physical properties of a coal-derived liquid fuel using only information obtained from a gas chromatography-mass spectrometry analysis of the fuel and a recently developed 'advanced distillation curve'. We then predicted the density, speed of sound, and viscosity of the fuel and compared them to limited experimental data. The surrogate contains five components (n-propylcyclohexane, trans-decalin, {alpha}-methyldecalin, bicyclohexane, and n-hexadecane), yet comparisons to limited experimental data demonstrate that the model is able to represent the density, sound speed, and viscosity to within 1, 4, and 5%, respectively. 102 refs., 2 figs., 5 tabs.

Energy Technology Data Exchange (ETDEWEB)

The kinetics of biosorption and desorption of lindane by live activated sludge and the fungus R. arrhizus was studies. The results from the use of live activated sludge suggest that besides biosorption, other lindane removal mechanisms acted in parallel. Most probably, biodegradation. A relationship between biodegradation and bisorption-desorption was established. Mass spectroscopy and gas chromatography studies suggested the presence of lindane biodegradation by products. Lindane accumulated by the live activated sludge could be desorbed while being biodegraded at the same time. Values for lindane biokinetic constants were estimated. Biosorption of lindane by live R. arrhizus is a rapid and reversible process with no indication of biodegradation. Values for the lindane biotransformation kinetic coefficients were estimated. (orig.).

International Nuclear Information System (INIS)

Homidium bromide and isometamidium chloride are used extensively in the treatment of bovine trypanosomiasis in Africa, but no specific and sensitive method to detect the drug in plasma has been published yet. Comparing the methods of other investigators it was found that they could not overcome the protein binding of these drugs which reduced the available and determined drug to 10% of the real concentrations. These techniques overcome the protein binding by enzyme digestion and an alteration of the pH before adding the sample directly on clean-up columns. Drug recover rates above 80% were obtained. For the detection, the HPLC was employed using a C18 reversed phase analytical column and UV detection, determining both drugs as intact molecules. (author).

Energy Technology Data Exchange (ETDEWEB)

The reference method used to analyse polychlorodibenzo-p-dioxins (PCDDs), polychlorodibenzofurans (PCDFs) and dioxin-like polychlorinated biphenyls (dl-PCBs) is chromatography with high resolution mass spectrometry (GC-HRMS). It is interesting to check the suitability of screening methods that are faster and less expensive. Different matrices (milk, fish oil, chicken compound feed, pork tissue, chicken tissue, sepiolitic clay, whole egg and herring tissue) were analysed in the frame of the European project DIFFERENCE1. One of the aims of this project is to optimise screening methods. The CALUX bio-assay was one of the screening techniques used. This paper presents the extraction and purification methods used for the analyses. The CALUX results for dioxins and for dl-PCBs were compared to the corresponding GC-HRMS results.

Energy Technology Data Exchange (ETDEWEB)

New technological advances make it possible to perform on site gas-in-oil analysis quickly and efficiently. Gas-in-oil analysis is crucial in assessing the status of oil-filled electrical equipment. The new technique is used for extracting and measuring gases dissolved in electrical insulating oil. On-site sampling requires the use of a specially designed 100 ml capacity syringe. Extraction of the dissolved gases is made with a precise ratio of oil to air. A comparison was made between the analysis of the on-site and the laboratory techniques. Results showed that the detection limits of the on-site technique were comparable to those obtained by laboratory methods.

International Nuclear Information System (INIS)

Thromboxane A2, the predominant product of arachidonic acid metabolism in the blood platelet, is a potent vasoconstrictor and platelet agonist. During its biosynthesis from cyclic endoperoxide, 12(S)-hydroxy-5Z,8E,10E-heptadecatrienoic acid (HHT) is formed in equal amounts. The further metabolism of HHT, catalyzed by 15-hydroxyprostaglandin dehydrogenase, leads to 12-oxo-5Z,8E,10E-heptadecatrienoic acid (Oxo-HT). Sample workup procedures are described which allow for the sensitive and reproducible determination of these two arachidonic acid metabolites in human plasma by gas chromatography-mass spectrometry in the presence of deuterated analogues as internal standards. HHT is derivatized to the pentafluorobenzyl ester tert-butyldimethylsilyl ether. In order to enable quantification of low concentrations of about 10 pg/ml in nonstimulated human plasma, the samples have to be purified by HPLC. Oxo-HT is derivatized to the pentafluorobenzyl ester, ...

Energy Technology Data Exchange (ETDEWEB)

We have recently introduced several important improvements in the measurement of distillation curves for complex fluids. This new method is a significant improvement over current approaches, with features including a composition-explicit data channel for each distillate fraction (for both qualitative and quantitative analysis), trace chemical analysis of each distillate fraction, and a corrosivity assessment of each distillate fraction. In the present contribution, we present the application of the advanced distillation curve method to a bio-derived crude oil prepared from swine manure. One motivation behind the work was to precisely measure the distillation curve of the oil derived from swine manure with our advanced distillation apparatus and compare the bio-derived oil to traditional petroleum crude oils. Then, the information content of the bio-derived oil distillation was extended further with the composition-explicit data channel: gas ...

Energy Technology Data Exchange (ETDEWEB)

Advanced techniques for focused-ion-beam (FIB) device modification have been developed for complex, multistep modifications to circuitry on planar chip technology. Applying gas-assisted etching (GAE) techniques for high-aspect-ratio milling and the selective milling of both conductive and insulating films enhances process latitude. Localized ion-beam-induced deposition of an insulating film provides reconstructive capability in previously modified areas. The application of both techniques for complex device modification on VSLI devices fabricated with CMOS process technology is reviewed. (UK).

Energy Technology Data Exchange (ETDEWEB)

The densities and refractive indices of two binary systems (water + MEA and water + MDEA) and three ternary systems (water + MEA + CO{sub 2}, water + MDEA + CO{sub 2}, and water + MEA + MDEA) used for carbon dioxide (CO{sub 2}) capture were measured over the range of compositions of the aqueous alkanolamine(s) used for CO{sub 2} absorption at temperatures from 295 to 338 K. Experimental densities were modeled empirically, while the experimental refractive indices were modeled using well-established models from the known values of their pure-component densities and refractive indices. The density and Gladstone-Dale refractive index models were then used to obtain the compositions of unknown samples of the binary and ternary systems by simultaneous solution of the density and refractive index equations. The results from this technique have been compared with HPLC (high-performance liquid chromatography) results, while a third independent ...

Energy Technology Data Exchange (ETDEWEB)

This paper summarizes the investigation of horizontal direction drilling and the subsequent experimental installation of a natural gas network in a suburb of Paris, France. Three aspects of drilling were studied prior to implementation: (1) reliability of the technique and quality of pipelaying to ensure long-term supply main operation; (2) ability to assess the successfulness of the work by assessing preliminary conditions; and (3) economonic viability. Measurement of tensile stress on polyethylene pipe during pulling and comparative accelerated aging tests on scratched pipe were performed. In the implementation phase, 300 meters of pipe were laid daily, by using three machines simultaneously, at a cost comparable to that of conventional techniques.

Energy Technology Data Exchange (ETDEWEB)

A gas tracer technique based on carbon monoxide and a commercial automotive exhaust gas analyser has been applied to wind tunnel models of waterjet propulsion systems intakes. The post-processing and interpretation of the carbon monoxide concentration signals has yielded high resolution measurements of the bounding ingestion stream-tubes. (orig.) With 3 figs., 1 tab., 8 refs.

Energy Technology Data Exchange (ETDEWEB)

Lithium isotope separation by displacement chromatography is studied using fundamental principles; the equations are derived assuming theoretical stages in lithium adsorption bands. The concentration profiles in the band are calculated numerically under unsteady state.

UK PubMed Central (United Kingdom)

A liquid chromatography/tandem mass spectrometric (LC/MS/MS) assay was developed for the quantitative determination of salirasib (S-trans, trans-farnesylthiosalicylic acid,...Full Text Available

UK PubMed Central (United Kingdom)

A pigment-dispersing hormone (PDH) from eyestalks of the fiddler crab Uca pugilator has been purified by gel filtration, ion-exchange chromatography, partition chromatography, and reversed-phase...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The Lawrence Livermore National Laboratory has developed a mobile field laboratory for remote measurement of atmospheric processes and observables that are important in global climate change, dispersal of hazardous materials, and atmospheric pollution. Specific observables of interest are water vapor, trace gases, aerosol size and density, wind, and temperature. The goal is to study atmospheric processes continuously for extended periods in remote field locations. This laboratory has just reached field ready status with sensors for aerosol and trace gas measurement based on established techniques. A development program is underway to enhance the sensor suite with several new techniques and instruments that are expected to significantly extend the state of the art in remote trace gas analysis. The new sensors will be incorporated into the lab during the next two years.

Energy Technology Data Exchange (ETDEWEB)

Worker exposures to N-nitroso compounds were evaluated at B.F. Goodrich Company, Woodburn, Indiana on December 12, 1979. Personal and area air samples were collected and analyzed by gas-chromatography and thermal-energy-analysis methods. All of the samples contained N-nitrosomorpholine (NMOR) and five samples also contained N-nitrosodimethylamine (NDMA). The amount of NMOR ranged from 0.85 to 3.7 micrograms per cubic meter (micrograms/cu m) for area air samples and 0.63 to 1.8 micrograms/cu m for personal samples. NDMA concentrations ranged from undetectable to 1.8 microgram/cu m for area samples and undetectable to 0.09 micrograms/cu m for personal samples. The authors note that no exposure standards exist for NDMA or NMOR but both are listed as potential human carcinogens. They suggest that the B.F. Goodrich Company characterize nitrosamine exposures at this facility.

Energy Technology Data Exchange (ETDEWEB)

The use of ionising radiation for the preservation of food has been under investigation for many years but has yet to receive worldwide acceptance. Although irradiation can be carefully controlled, it is generally accepted that the development of a test or tests for the detection of irradiated food would enhance consumer confidence and might help to enforce labelling regulations. The 2-alkylcyclobutanones are reported to be the only cyclic compounds formed as the products of the radiolysis of saturated and unsaturated triglycerides. The synthesis of 2-dodecylcyclobutanone (DCB) and 2-tetradecylcyclobutanone (TCB), which are formed from palmitic and stearic acid respectively following irradiation, has been carried out and using irradiated chicken meat as the model for a high-lipid containing food, both cyclobutanones have been extracted with hexane and then identified using gas chromatography/mass spectrometry (GC/MS). DCB and TCB have been ...

Energy Technology Data Exchange (ETDEWEB)

In this 150-day study, chicken manure, kenaf, and white rot fungus were added to soil microcosms in an attempt to enhance the degradation of polychlorinated biphenyls. The soil was contaminated with commercial PCB mixtures. Dishes were ammended with 5% dry weight chicken manure, 1% dry weight kenaf, and 1% dry weight kenaf plus Phanerochaete chrysosporium inoculant. PCB concentrations were determined at 30 day intervals by soxhlet extraction and gas chromatography analyses. Preliminary results of microbial populations and PCB degradation are presented. At 90 days, the microcosms amended with chicken manure had significantly higher populations of bacteria, fungi, and actinomycetes. However, at 120 days, these soils underwent great reductions in actinomycete and bacterial populations. Through 60 days, the concentration of the PCBs Aroclor 1242 and 1248 had its greatest reduction in the kenaf amended soils. The concentration of Aroclor 1260 either ...

Energy Technology Data Exchange (ETDEWEB)

The values of -{delta}G{sub A}{sup O} of n-alkanes on calcite are lower on the stearic acid treated calcite than on the untreated calcite. The value of -{delta}G{sub A}{sup O} of n-alkanes on calcite increase with increasing carbon numbers of n-alkanes. The values of -{delta}G{sub A}{sup O} measured on the treated calcite are significantly lower than those measured on the untreated calcite. The -{delta}G{sub A}{sup O} of n-alkanes on the treated calcite are close to the heat of liquefaction of n-alkanes. All the experimental values of -{delta}G{sub A}{sup O} of n-alkanes on calcite are larger than theoretical entropy decrease particularly for the higher molecular mass n-alkanes. Thus the important entropy decrease observed upon adsorption can not only be attributed to the loss of one degree of freedom of the adsorbed molecules. The values of {gamma}{sub S}{sup D} of the treated and untreated calcite decrease with increasing temperature. {gamma}{sub S}{sup D} for the treated calcite is ...

Energy Technology Data Exchange (ETDEWEB)

The ruptured offshore oil well 80 miles from Mexican town of Ciudad del Carmen, which poured 8000 barrels of light oil a day into the Gulf of Mexico, provided marine scientists with the opportunity to monitor the spill and see what happens to petroleum hydrocarbons in sea water. Scientists followed changes in viscosity, surface tension, and buoyancy of individual oil globs as they moved through the water and interacted with the surface slick. Using gas chromatography and mass spectroscopy, chemists are gaining an understanding of the unique characteristics of the oil. Computer-generated models projected the slick's movement in the Gulf in response to wind and wave pressures, but the sophisticated system did not give an accurate daily prediction. Immediate damage to fish, turtles, and sea birds was documented by tagging. Long-term effects will take longer to ascertain since 25 years is generally required to flush oil out of sediments. ...

British Library Electronic Table of Contents (United Kingdom)

This paper presents a comprehensive study of pesticide levels and bio-accumulation characteristics in human adipose tissues among residents of Southeast China. A large number of adipose samples (n=633) were selected for 58 pesticides and were analyzed by high sensitive Gas Chromatography-Tandem Mass Spectrometry (GC-MS/MS). The results showed that POPs pesticides were frequently detected, including 2,4prime-DDD, 2,4prime-DDE, 2,4prime-DDT, 4,4prime-DDD, 4,4prime-DDE, 4,4prime-DDT, a-HCH, b-HCH, g-HCH, d-HCH, hexachlorobenzene (HCB), and mirex. Other detected pesticide species were dicofol, methamidophos and chlordimeform, which have rarely been reported. Comparing to different countries, the concentrations of total DDT and HCH in these three Chinese southeastern sites were in the middle ra...

Energy Technology Data Exchange (ETDEWEB)

There is an urgent need to monitor the condition of fluid-filled taped (FFT) cables. The Dissolved-Gas Analysis (DGA) technique that has been successfully applied to power transformers holds great potential for the preventive maintenance of FFT cables. However, before this emerging technique can be properly applied to cables, a suitable fluid sampling and subsequent gas analysis method had to be developed, including the generation of both laboratory and field data to aid in data interpretation. Data on gas saturation levels in various cable fluids have been presented. This paper describes a novel method developed specifically for FFT cables and discusses field results so obtained. The type, distribution and concentration of gases from fluid alone and paper alone under electrical stress has been presented, including the differences between normal and not-so-normal cable systems as ...

Energy Technology Data Exchange (ETDEWEB)

The influence of membrane pH gradients on the transbilayer distribution of some common phospholipids has been investigated. The authors demonstrate that the transbilayer equilibrium of the acidic phospholipids egg phosphatidylglycerol (EPG) and egg phosphatidic acid (EPA) can be manipulated by membrane proton gradients, whereas phosphatidylethanolamine, a zwitterionic phospholipid, remains equally distributed between the inner and outer monolayers of large unilamellar vesicles (LUVs). Asymmetry of EPG is examined in detail and demonstrated by employing three independent techniques: ion-exchange chromatography, {sup 13}C NMR, and periodic acid oxidation of the (exterior) EPG headgroup. In the absence of a transmembrane pH gradient ({Delta}pH) EPG is equally distributed between the outer and inner monolayers of LuVs. When vesicles composed of either egg phosphatidylcholine (EPC) or DOPC together with 5 mol % EPG are prepared with a transmembrane ...

Energy Technology Data Exchange (ETDEWEB)

An in situ synthesis of ZnS and CdS quantum dots (QDs) in an aqueous solution of sodium hyaluronate (Hyal) produced foils emitting light on excitation with a UV light. The wavelength of emission was only slightly QDs size and more QDs concentration dependent and reached up to {approx}320 nm in the case of ZnS and {approx}400-450 nm in the case of CdS. Nanoparticles remained as non-agglomerated 10-20 nm nanoclusters. CdS/Hyal and ZnS/Hyal-QDs biocomposites were characterized using photoluminescence (PL), IR spectrometric techniques, and Transmission Electron Microscopy (TEM). The absolute molecular weights, radii of gyration, R{sub g}, and thermodynamic properties of the obtained foils are given. Electric resistivity studies performed for the hyaluronic foil in the 100-1000 V range have revealed that the hyaluronate foil has very weak conducting properties and QDs only insignificantly affect those properties as QDs practically did not interact with the foil. Size ...

Energy Technology Data Exchange (ETDEWEB)

A process is described for converting organic waste into a combustible gas for use in a heavy duty thermal engine. The engines best suited for this operation are of the dual-fuel type whose output power results from the simultaneous work of 2 combustibles. The gas flow rate is controlled by the desired power output, while diesel fuel injection remains constant regardless of engine load. The low BTU gas produced by the gasification of dry wastes is a mixture of CO, H/sub 2/ CH/sub 4/, CO/sub 2/ and N/sub 2/. Diesel fuel savings under usual operating conditions is no less than 80% of the consumption of conventional diesel engines of identical power. Characteristics of the low Btu gas engines are described as are the characteristics of the gasifying equipment. Applications for this process are suggested. (DMC)

Energy Technology Data Exchange (ETDEWEB)

In the food, chemical and safety industry there is a demand for gas detectors for process control applications, like quality control of food or leakage control in chemical plants. Gas sensor array systems have the potential to be used in this areas, with the advantage of being also affordable systems compared to other systems like gaschromatographs (GC) or infrared detectors (NIR, FTIR). One of the main drawbacks of the gas sensors is their response to non interesting ambient factors like temperature, pressure and humidity. Metal oxide sensors (MOS) have a low ambient temperature and pressure dependency. Some of them (SnO + dopands) have some sensitivity to humidity. In many cases the response of the sensors is often non-linear, which implies a concentration dependant pattern of the samples. (orig.)

Energy Technology Data Exchange (ETDEWEB)

Precondition for the low-NO operation of gas turbine burners is the generation of as homogeneous as possible a gaseous fuel/air mixture. Such a burner behavior can be achieved by selective adaptation of the flow and injection. A computing model is introduced that calculates the dynamically balanced GASs/droplet flow through numerical solution of the transport equations in a curved orthogonal coordinate system. The feedback reaction of the fuel droplets to the gas phase is considered by source terms and/or sink terms. Test computations were carried out for comparison with analytical solutions from the flow mechanics and validated by comparison with measurement results. Droplet motion and evaporation were checked by means of published experimental results on single droplets. For the validation of the developed computing technique, model tests were carried out with water in place of fuel. It is pointed out that the choice of ...

Energy Technology Data Exchange (ETDEWEB)

There is very little quantitative documentation of actual improvements resulting from the installation of new general ventilation systems in industrial settings. Therefore the performance of the common mixing design principle was compared to the displacement design principle by means of an intervention study in a workshop (V = 12,000 m[sup 3]), where thermoplastics were moulded. An experimental signal-response tracer gas technique was used. In terms of supplying fresh air to the zone of occupancy the displacement system was better than the mixing system by a factor of 2. In terms of the exposure level to a simulated contaminant (tracer gas) the displacement system was better by a factor 1.5-18. (author)

Energy Technology Data Exchange (ETDEWEB)

Many energies companies rely heavily on the financial markets to fund expansion plans due to the capital intensive nature of this industry. The dramatic and rapid changes in the financial markets over the last few years create both challenges and opportunities for oil and gas companies trying to survive a volatile era and to position themselves for recovery. These market volatilies have bred new financial techniques and opportunities in both the domestic and global capital markets. This paper discusses specific applications, benefits and advantages of these new techniques and financial products to energy companies.

Energy Technology Data Exchange (ETDEWEB)

Indoor air exposures to gaseous contaminants originating in soil can cause large human health risks. To predict and control these exposures, the mechanisms that affect vapor transport in near-surface soils need to be understood. In particular, radon exposure is a concern since average indoor radon concentrations lead to much higher risks than are generally accepted for exposure to other environmental contaminants. This dissertation examines an important component of the indoor radon problem: the impacts of wind on soil-gas and radon transport and entry into buildings. The research includes experimental and modeling studies of wind`s interactions with a building`s superstructure and the resulting soil-gas and radon flows in the surrounding soil. In addition to exploring the effects of steady winds, a novel modeling technique is developed to examine the impacts of fluctuating winds on soil-gas and radon ...

British Library Electronic Table of Contents (United Kingdom)

The effect of water shortage on growth and gas exchange of maize grown on sandy soil (SS) and clay soil was studied. The lower soil water content in the SS during vegetative growth stages did not affect plant height, above-ground biomass, and leaf area index (LAI). LAI reduction was observed on the SS during the reproductive stage due to early leaf senescence. Canopy and leaf gas exchanges, measured by eddy correlation technique and by a portable photosynthetic system, respectively, were affected by water stress and a greater reduction in net photosynthetic rate (A N) and stomatal conductance (g s) was observed on SS. Chlorophyll and carotenoids content was not affected by water shortage in either condition. Results support two main conclusions: (1) leaf photosynthetic capacity was unaffec...

Energy Technology Data Exchange (ETDEWEB)

Limited demand and high cost has prevented the construction of hard rock caverns in this country for a number of years. The storage of natural gas in mined caverns may prove technically feasible if the geology of the targeted market area is suitable; and economically feasible if the cost and convenience of service is competitive with alternative available storage methods for peak supply requirements. It is believed that mined cavern storage can provide the advantages of high delivery rates and multiple fill-withdrawal cycles in areas where salt cavern storage is not possible. In this research project, PB-KBB merged advanced mining technologies and gas refrigeration techniques to develop conceptual designs and cost estimates to demonstrate the commercialization potential of the storage of refrigerated natural gas in hard rock caverns. Five regions of the U.S.A. were studied for underground storage ...

International Nuclear Information System (INIS)

Tank calibration experiments have been carried out using a mock-up input accountancy tank with the object of developing a high accuracy solution volume measurement technique for Rokkasho Reprocessing Plant (RRP). The experimental parameters such as temperature, solution density, off gas pressure and so on have been fluctuated in the calibration experiments in order to evaluate the influence on the solution volume measurement. As a result, it was confirmed that the solution volume measurement error of the mock-up tank was within #+-#0.04% (at full volume) using careful data correction technique for measured data. For the high accuracy volume measurement at RRP, it is important to correct data properly taking account of the actual conditions such as uncontrollable ambient temperature that are different from the experiment. (author)

Energy Technology Data Exchange (ETDEWEB)

The nature and relationship of methane to coal mines is discussed and sources of information are outlined. Methods of gas analysis in general and methods for the detection of methane in use in coal mines are described. Methods of remote detection of gases and those that have application for use in underground coal mining operations are discussed. The report represents recommendations on remote methane detection systems that may find application in underground coal mines. (20 refs.)

CERN Document Server

By using a laser and maser in tandem, it is possible to obtain laser action in the hot exhaust gases involved in heat engine operation. Such a "quantum afterburner" involves the internal quantum states of working gas atoms or molecules as well as the techniques of cavity quantum electrodynamics and is therefore in the domain of quantum thermodynamics. As an example, it is shown that Otto cycle engine performance can be improved beyond that of the "ideal" Otto heat engine.

Energy Technology Data Exchange (ETDEWEB)

Time resolved light scattering from laser-induced electrostrictive gratings was used for the determination of flow velocities in air at room temperature. By measuring the velocity profile across the width of a slit nozzle we demonstrated the high spatial resolution (about 200 mm) of this novel technique. (author) 3 figs., 1 ref.

Wastenet

...to facilities using - Petrol and diesel industrial engines - Petrol and diesel light vehicles, commercial vehicles and trucks on the facility - Large stationary diesel and dual-fuel engines - Heavy-duty natural gas fired pipeline compressor engines and turbines First published in February 1999 Revised - August 2000 Version 2.3 - ...

Energy Technology Data Exchange (ETDEWEB)

In order to judge the potential fluorescent lamp applications of various low-pressure positive column discharges it is necessary to measure the absolute power emitted in the ultraviolet region of the spectrum. For rare-gas discharges the principle emission occurs in the vacuum ultraviolet so that it is difficult to measure the radiant emittance (power per unit area) of the resonance radiation by standard methods. Two independent techniques are discussed for measuring the radiant emittance of positive column discharges in the vacuum ultraviolet. These techniques are used to study xenon positive column discharges at the resonance wavelength of 147 nm. The first method relies on the measurement of the resonance level density by absorption techniques. The effective decay rate of the resonance level is then determined by the simulation of resonance radiation transport. These two quantities are combined to ...

International Nuclear Information System (INIS)

A Real-Time Neutron Radiography (RTNR) system and a high speed X-ray Computed Tomography (X-CT) system are used to determine the flow regime, the instantaneous cross-sectional averaged void fraction, and the time averaged void fraction in a vertical annulus flow channel. A standard optical video system is also used to observe the flow regime. The annulus flow channel is operated as a bubble column and measurements are obtained for gas flow rates form 0.0 to 30.0 l/min. The flow regimes observed by all three measurement systems via image analysis shows that the results agree well with each other. Both the RTNR and the X-CT systems show that the time averaged and cross-sectional averaged void fraction increases with increasing superficial gas velocity. Time and cross-sectional averaged void fractions determined by the RTNR system agree within 4% with those determined by the high speed X-ray CT technique. (orig.).

Energy Technology Data Exchange (ETDEWEB)

The information reported is for the period October I to December 31, 1993. During this quarter, activities were undertaken in Task 2. Oxygen concentrations were measured in the post-flame region of the entrained flow reactor. The sampling probe was used for the hot gas tests to sample the gas stream. Samples were injected into a gas chromatograph to determine the oxygen concentration. Results agreed with thermoequilibrium calculations that yield equilibrium compositions based on the stoichiometry of the feed gases. The axial temperature distribution along the reactor centerline was measured using a silica-coated platinum-rhodium thermocouple. Two coating techniques were tested and it was found that flame-plating silica to the thermocouple wires produced a thinner coating than a ceramic adhesive technique and therefore a smaller radiation correction. Other activities this quarter ...

Energy Technology Data Exchange (ETDEWEB)

In this paper we study different effects of excited molecules on swarm parameters, electron energy distribution functions and gas discharge modeling. First we discuss a possible experiment in parahydrogen to resolve the discrepancy in hydrogen vibrational excitation cross section data. Negative differential conductivity (NDC) is a kinetic phenomenon which manifests itself in a particular dependence of the drift velocity on E=N and it is affected by superelastic collisions with excited states. A complete kinetic scheme for argon required to model excited state densities in gas discharges is also described. These results are used to explain experiments in capacitively and inductively coupled RF plasmas used for processing. The paper illustrates the application of atomic and molecular collision data, swarm data and the theoretical techniques in modeling of gas discharges with large abundances of excited ...

Energy Technology Data Exchange (ETDEWEB)

One such agent is the widely used anesthetic, halothane. To study the toxicity of u.v. decomposed halothane, mice were exposed to anesthetic concentrations (1.3%) of non- and u.v.-irradiated halothane in oxygen for 90 min. Halothane sleeping times increased from 14.3 min to 72.5 min. Microsomal mixed function oxidase activity decreased, as shown by prolonged pentobarbital sleeping times 1 day after exposure to halothane and irradiated halothane (54.6 min and 149.1 min, respectively, as compared to a 34.6-min control). Quantitative and qualitative differences were found in the amount of (/sup 14/C)-pentobarbital metabolites excreted by u.v. irradiated halothane-exposed mice compared to either oxygen or non-irradiated halothane-exposed groups. In addition, serum glutamic-oxalacetic transaminase (SGOT) of irradiated halothane-exposed mice increased to 233% of the control values, and serum glutamic-pyruvic transaminase (SGPT) were 377% of control values. No significant changes in SGOT or ...

Energy Technology Data Exchange (ETDEWEB)

The overall goal of the DOE fine particulate program is to ensure that the best science and technology is available for any regulatory decision-making related to the health and environmental impacts of ambient fine particulate matter and regional haze. Interest primarily lies in the particulate fraction having aerodynamic diameters of 2.5 microns and less (PM2.5). Particulates of this size are the focus of the newly established National Ambient Air Quality Standards. As such, the Federal Energy Technology Center (FETC) is establishing a fine particulate sampling station at the Center's Pittsburgh site located in South Park Township, PA. This sampling station is one of a group of stations scattered throughout Pennsylvania, West Virginia, and Ohio that constitute the Upper Ohio River Valley Project. The station is equipped with a full complement of fine particulate and gaseous monitors including the following: (1) R and P Sequential FRM sampler, (2) Grimm PM2.5 continuous ...

Energy Technology Data Exchange (ETDEWEB)

While tritium exposure to the site-workers in Wolsung NPP is up to about 40% of the total personnel exposure, Ministry of Science and Technology has asked tritium removal facility for requirement of post heavy-water reactor construction. For the purpose of essential removal of tritium from the Wolsung heavy-water reactor system, a preliminary study on the cryogenic Ar-N{sub 2} and H{sub 2}-D{sub 2} distillation process for development of liquid-phase catalytic exchange cryogenic hydrogen distillation process technology. The Ar-N{sub 2} distillation column showed good performance with approximately 97% of final Ar concentration, and a computer simulation code was modified using these data. A simulation code developed for cryogenic hydrogen isotopes (H{sub 2}, HD, D{sub 2}, HT, DT, T{sub 2}) distillation column showed good performance after comparison with the result of a JAERI code, and a H{sub 2}-D{sub 2} distillation column was made. Gas ...

Energy Technology Data Exchange (ETDEWEB)

The affinity label 8-((4-bromo-2,3-dioxobutyl)thio)adenosine 5{prime}-triphosphate (8-BDB-TA-5{prime}-TP) reacts covalently with rabbit muscle pyruvate kinase, incorporating 2 mol of reagent/mol of enzyme subunit upon complete inactivation. Protection against inactivation is provided by phosphoenolpyruvate, K{sup +}, and Mn{sup 2+} and only 1 mol of reagent/mol of subunit is incorporated. The authors have now identified the resultant modified residues. After reaction with 8-BDB-TA-5{prime}-TP at pH 7.0, modified enzyme was incubated with ({sup 3}H)NaBH{sub 4} to reduce the carbonyl groups of enzyme-bound 8-BDB-TA-5{prime}-TP and to introduce a radioactive tracer into the modified residues. Following carboxymethylation and digestion with trypsin, the radioactive peptides were separated on a phenylboronate agarose column followed by reverse-phase high-performance liquid chromatography in 0.1% trifluoroacetic acid with an acetonitrile gradient. ...

Energy Technology Data Exchange (ETDEWEB)

N/C and S/C ratios show only minor differences between asphaltenes and coal on this basis, the asphaltenes continue to appear to be good surrogates for the characterization of organic acid rain precursors in coal. Alkylmethoxythiophene carboxylic acids (ATCA) are detected in all dichromate oxidation products analyzed to date. Relative concentrations of ATCA compounds are directly proportional to the sample`s bulk organic sulfur contents. Concentrations of ATCA compounds in oxidation products decrease upon repeated oxidation. This may indicate that the thiophenic groups tend to be located in external positions on the coal macromolecular structure and a high proportion of them can be stripped away with only one mild oxidation step. If true, this may make industrial-scale removal of organic sulfur easier than expected. Using analytical micropyrolysis-gas chromatography with a sulfur-selective flame photometric detector, it is possible to easily ...

Energy Technology Data Exchange (ETDEWEB)

The newly developed techniques by the Hot Laboratory (JMTR HL) have provided for us the key information on behavior of specimens due to mechanical / physical / chemical / synergistic effects of radiation, stress and water for fission and fusion reactor environment. These techniques are focused on several topics as follows; (1) miniaturized specimen test for the development of fusion reactor materials, (2) slow strain rate tensile testing (SSRT) and crack propagation measuring tests for the study of Irradiation Assisted Stress Corrosion Cracking (IASCC) of core internals of LWR, (3) handling technique on specimens including tritium for the research and development of tritium breeders and neutron multiplier as fusion blanket materials, (4) joining method using the Tungsten Inert Gas (TIG) welding technique for re-assembling of capsule and re-fabrication of specimen and (5) ...

Energy Technology Data Exchange (ETDEWEB)

A portion of the active site of rabbit skeletal myosin near the ribose ring of ATP can be labeled by the photoaffinity analogue 3{prime}(2{prime})-O-(4-benzoylbenzoyl)adenosine triphosphate (Bz{sub 2}ATP). The specificity of the photolabeling was assured by first trapping ({sup 14}C)Bz{sub 2}ATP at the active site by use of thiol cross-linking agents. Five radioactive peptides were isolated by high-performance liquid chromatography after extensive trypsin and subtilisin digestion of photolabeled myosin subfragment 1. Four of these peptides were sequenced by Edman techniques, and all originated from a region with the sequence Gly-Glu-Ile-Thr-Val-Pro-Ser-Ile-Asp-Asp-Gln, which corresponds to rabbit myosin heavy chain residues 312-328. The fifth labeled peptide had an amino acid composition appropriate for residues 312-328. Amino acid composition, radiochemical analysis, and sequence data indicate that Ser-324 is the major amino acid residue ...

Energy Technology Data Exchange (ETDEWEB)

This short survey focuses on the main radiation-induced base lesions that have been identified within cellular DNA. For this purpose, sensitive assays that are aimed at measuring a few modifications per 10{sup 7} normal bases were set-up. In that respect high performance liquid chromatography - tandem mass spectrometry (CLHP-MS/MS) was found to be able to single out the formation of 9 oxidized nucleosides and two modified nucleo-bases out of the 70 oxidative base lesions that have been identified in model systems. As a striking result, it was found that in the DNA of {gamma}-irradiated human monocytes, the formamide-pyrimidine derivative of guanine is produced in a higher yield than the ubiquitous 8-oxo-7,8-dihydro-guanine damage, both arising from the same radical precursor. However, relatively high doses of ionizing radiation (> 20 Gy) have to be applied in order to detect an increase in the level of the damage. This is due to the low efficiency for both ...

Energy Technology Data Exchange (ETDEWEB)

Ternary diagrams or pseudo ternary diagrams are commonly used to provide a graphical representation of equilibrium fluid phase behavior for systems as diverse as distillation columns and miscible gas floods of oil reservoirs. The phase envelope and the position of the critical point on it are important to enhanced oil recovery engineers who are involved with miscible gas flood design. In the past, phase equilibrium data were laboriously plotted on the pseudo ternary diagram and special graphical techniques were utilized to locate the critical point on the phase envelope. Presented in this article is a computerized curve fitting method to, firstly, generate the phase envelope from a given set of phase equilibrium data and then use the 'tie-line slopes' to position the critical point. Experimental data are included and show excellent agreement with this new method.

Energy Technology Data Exchange (ETDEWEB)

The development of solid state chemical sensors, and more specifically of gas sensors, is carried out with great strength in the present time since the environmental pollution and the security in work and domestic ambient are problems of great interest and social impact. The main fields of application, are: automobile, domestic sensors, control of industrial process, bio medicine, environment. These chemical sensors are experimenting a great advance because of the advantages they offer, as low cost, simple operation, possibility of measure continuous and ''In situ'' and small size, in contrast with analytical techniques that need complex instrumentation and large size equipments. In the present work, a sensor for CO detecting concentrations as low as 50 p.p.m., is studied showing great interest since this gas is highly toxic even to such a low concentration. (Author)

Energy Technology Data Exchange (ETDEWEB)

The biological treatment process was selected by Gaz de France (GDF), the French national gas utility, for the de-pollution of an old gas works where the main pollutants are coal tars containing polycyclic aromatic hydrocarbons. Microorganism-based biological treatment techniques may involve bio-reactors, static ground knolls (where oxygen is brought through drains) and dynamic knolls (where oxygenation is carried out by turning up the soil). Issues on sampling, sorting, process testing, site preparation, process control, etc. are reviewed

Energy Technology Data Exchange (ETDEWEB)

A new technique for ion implantation into concave surface of insulating materials is proposed and experimentally studied. The principle is roughly described by referring to modifying inner surface of a PET (polyethylene terephthalate) bottle. An electrode that is supplied with positive high-voltage pulses is inserted into the bottle. Both plasma formation and ion implantation are simultaneously realized by the same high-voltage pulses. Ion sheath with a certain thickness that depends on plasma parameters is formed just on the inner surface of the bottle. Since the plasma potential is very close to that of the electrode, ions from the plasma are accelerated in the sheath and implanted perpendicularly into the bottle's inner surface. Laser Raman spectroscopy shows that the inner surface of an ion-implanted PET bottle is modified into DLC (diamond-like carbon). Gas permeation measurement shows that gas-barrier ...

British Library Electronic Table of Contents (United Kingdom)

Flue gas desulfurization systems (FGDs) are operated in severely corrosive environments that cause sulfuric acid dew-point corrosion. The corrosion behavior of low-alloy steels was tested using electrochemical techniques (electrochemical impedance spectroscopy, potentiodynamic tests, potentiostatic tests), and the corrosion products were analyzed by scanning electron microscopy and X-ray photoelectron spectroscopy. The electrochemical results showed that alloying W with small amounts of Sb, Cu, and Co improves the corrosion resistance of steels. The results of surface analyses showed that the surface of the steels alloyed with W consisted of W oxides and higher amounts of Sb and Cu oxides. This suggests that the addition of W promotes the formation of a protective WO3 film, in addition to ...

International Nuclear Information System (INIS)

Nuclear forensic science has become increasingly important for global nuclear security. However, many current laboratory analysis techniques are based on methods developed without the imperative for timely analysis that underlies the post-detonation forensics mission requirements. Current analysis of actinides, fission products, and fuel-specific materials requires time-consuming chemical separation coupled with nuclear counting or mass spectrometry. High-temperature gas-phase separations have been used in the past for the rapid separation of newly created elements/isotopes and as a basis for chemical classification of that element. We are assessing the utility of this method for rapid separation in the gas-phase to accelerate the separations of radioisotopes germane to post-detonation nuclear forensic investigations. The existing state of the art for thermo chromatographic separations, and its applicability to nuclear ...

Energy Technology Data Exchange (ETDEWEB)

A systematic study of the effects of environmental factors on nylon 66 and Kevlar 29 strength degradation in parachute components is being conducted at Sandia National Laboratories. It includes: (1) accelerated aging studies in air, inert environments, humidity, ozone, and smog; (2) a 25-year surveillance program of parachutes in a variety of natural climatic environments; (3) moisture absorption as a function of humidity; (4) effects of surface coatings normally applied to parachutes; and (5) development of nondestructive evaluation techniques which can be used to map mechanical properties over the entire parachute surface. The accelerated aging and moisture absorption studies show that air, humidity, and smog contribute to degradation. Chemiluminescence, gas chromatographic pyrograms, and uv spectroscopy show promise as nondestructive evaluation techniques.

Energy Technology Data Exchange (ETDEWEB)

Three holes the size of deposition holes (depth 7.5 m and diameter 1.5 m) were bored in the Research Tunnel at Olkiluoto, Finland. A novel full-face boring technique was used based on rotary crushing of rock and removal of crushed rock by vacuum flushing through the drill string. The purpose of the work was to demonstrate the feasibility of the technique. During the boring test procedures were carried out in order to determine the effect of changes in operating parameters on the performance of the boring machine and the quality of the hole. The boring method was found to be technically feasible and efficient. Evaluation of the quality of the hole included studies of the geometry of the hole, measurements of the surface roughness using a laser profilometer and study of excavation disturbances in the zone adjacent to the surface of the holes using two novel methods, He-gas diffusion and the {sup 14}C-polymethylmethacrylate ...

Energy Technology Data Exchange (ETDEWEB)

Petroleum resources are finite and, therefore, search for their alternative non-petroleum fuels for internal combustion engines is continuing all over the world. Moreover gases emitted by petroleum fuel driven vehicles have an adverse effect on the environment and human health. There is universal acceptance of the need to reduce such emissions. Towards this, scientists have proposed various solutions for diesel engines, one of which is the use of gaseous fuels as a supplement for liquid diesel fuel. These engines, which use conventional diesel fuel and gaseous fuel, are referred to as 'dual-fuel engines'. Natural gas and bio-derived gas appear more attractive alternative fuels for dual-fuel engines in view of their friendly environmental nature. In the gas-fumigated dual-fuel engine, the primary fuel is mixed outside the cylinder before it is inducted into the cylinder. A pilot quantity of liquid fuel is ...

International Nuclear Information System (INIS)

A simple method is presented for the separation of lead-203 from copper-backed thallium cyclotron targets. The procedure involves cation-exchange chromatography in hydrochloric acid and hydrochloric acid-acetone mixtures. Further purification involves anion-exchange chromatography in nitric acid-hydrobromic acid mixtures. A cation-exchange column containing 3.0 g of resin can handle as much as 15 g of thallium and 160 mg of copper. An anion-exchange column containing 3.0 g of resin can separate lead from up to 200 mg of thallium and 10 mg of copper. Separations are extremely sharp and less than 0.1 #mu#g of thallium and less than 0.1 #mu#g of copper remain in the lead-203 fraction. (author).

British Library Electronic Table of Contents (United Kingdom)

Phycocyanin - a major phycobiliprotein constitutively produced by many cyanobacteria hold several promising applications in diagnostics, biomedical research, and therapeutics. This paper discusses a novel rapid method for the purification of cyanobacterial phycocyanin (C-PC) from Phormidium fragile using hydrophobic interaction chromatography. The protein was extracted and concentrated by grinding under liquid nitrogen and ammonium sulfate fractionation. C-PC was purified by single step hydrophobic interaction chromatography. Purified phycocyanin showed absorbance maximum (lmax) at 624nm. The criterion of purity (R) achieved was 4.52. Phycocyanin to phycoerythrin and phycocyanin to allophycocyanin purity ratio were 3.85 and 7.49, respectively. The purified protein showed a pI of 5.2 and ha...

Energy Technology Data Exchange (ETDEWEB)

We have developed a novel technique for measurements of low energy (p,alpha) reactions using heavy ion beams and a differentially-pumped windowless gas target. We applied this new approach to study the 183 keV resonance in the 17O(p,alpha)14}N reaction. We report a resonance energy (center-of-mass) of 183.5{+0.1}{-0.4} keV, a resonance strength of 1.70 +/- 0.15 meV, and set an upper limit (95\\% confidence) on the total width of the state of < 0.1 keV. This resonance is important for the 17O(p,alpha)14}N reaction rate, and we find that 18F production is significantly decreased in low mass ONeMg novae but less affected in more energetic novae. We also report the first determination of the stopping power for oxygen ions in hydrogen gas near the peak of the Bragg curve (E=193 keV/u) to be (63+/-1)e-15 eV-cm2.

Energy Technology Data Exchange (ETDEWEB)

Wet limestone scrubbing is once again becoming a popular technology for removal of sulfur dioxide (SO{sub 2}) from power plant emissions. Critical to the operation of wet limestone flue gas desulfurization (FGD) systems is accurate chemical analysis of scrubber solids. The analytical technique of thermogravimetry is ideal for this application, as the instrument can give precise readings of the principal scrubber solids components, calcium sulfite/sulfate hemihydrate, calcium sulfate dihydrate (gypsum), and unused calcium carbonate. The data provides plant chemists, engineers, and operators with information needed to fine-tune scrubber operation and detect process upsets. (orig.)

International Nuclear Information System (INIS)

The study of the dynamics of lubricants and mechanical components encased in metal enclosures is important to many industries. Of particular importance is the flow characteristics of oils or similar lubricants within the metal enclosure during operation of the device. The purpose of this summary is to report on the design and successful application of a real-time neutron radiography system to study the lubrication and design of the piston and seal of a gas spring. In addition, the application of this technique to a wider range of similar problems using the pulse capability of the TRIGA reactor is described.

Energy Technology Data Exchange (ETDEWEB)

Research activity during the 1991--1992 funding period has been concerned with the following topics relevant to carbon monoxide activation. (1) Exploratory studies of water gas shift catalysts heterogenized on polystyrene based polymers. (2) Mechanistic investigation of the nucleophilic activation of CO in metal carbonyl clusters. (3) Application of fast reaction techniques to prepare and to investigate reactive organometallic intermediates relevant to the activation of hydrocarbons toward carbonylation and to the formation of carbon-carbon bonds via the migratory insertion of CO into metal alkyl bonds.

Energy Technology Data Exchange (ETDEWEB)

The procedure followed by the Laboratorio de Metrologia Nuclear in Sao Paulo, Brazil, for the standardization of {sup 242g} Am is described. The calibration system was composed of a 4 {pi} gas-flow proportional counter coupled to a pair of NaI(Tl) crystals operating in coincidence. The samples were produced by irradiating dried aliquots of {sup 241} Am with thermal and epithermal neutrons at the IEA-R1 research reactor. The efficiency tracer technique has been applied using {sup 60} Co as tracer. The beta detection efficiency was changed by external absorbers and extrapolated to unity by linear least square fitting applying covariance methodology. (author)

International Nuclear Information System (INIS)

Meteorological and radon concentration data referring to a measurement campaign carried out in Urbino, Central Italy, are reported and discussed. This study presents a method allowing monitoring of the vertical atmospheric stability using continuous measurements of radon gas near ground. In particular radon evidences the presence of temperature inversion such as the formation of the nocturnal stable layer and gives information on the vertical turbulence and the motion of air masses. This technique is very useful in describing the temporal evolution of the pollutants in the atmosphere. (author)

International Nuclear Information System (INIS)

The current status of research and development in the realm of physics and technology of collective ion acceleration in systems with a virtual cathode (VC) is reviewed. Three major acceleration methods and devices developed on their basis are considered: reflex triodes and their modifications, gas-filled vircators, and vacuum vircators with a Luce diode. Experimental data are outlined and the principal physical models interpreting these data are described. New ion acceleration techniques whose realization involves the production and disappearance of the VC are also discussed. All methods of collective ion acceleration are compared and the possible ways for the further development of this promising scientific field are highlighted. (reviews of topical problems)

Energy Technology Data Exchange (ETDEWEB)

In a breeder-type nuclear power plant, liquid metal is used as a coolant due to the high heat capacity factor. Also, some proposals for fusion reactor blanket design include liquid metal as a possible coolant. In both cases the understanding of natural circulation of liquid-metal flow behavior is an integral part of the thermal hydraulic analysis, especially under two-phase flow conditions. Experimental investigations have been conducted to study a liquid metal two-phase natural circulation flow system. A lead-bismuth (PbBi) eutectic mixture is used as a working fluid in a heated metal walled natural circulation loop. Gas injection induces natural circulation through the gas-lift mechanism. A real-time neutron radiography system is used to visualize the two-phase mixture, specifically the interface and the flow regime. Measurements of void fraction, void fluctuation and bubble propagation are performed.

Energy Technology Data Exchange (ETDEWEB)

The cooperative project was a joint development program between Ceradyne and Oak Ridge National Laboratory through Lockheed Martin Energy Research (LMER). Cooperative work was of benefit to both parties. ORNL was able to assess the effect of the microwave nitridation process coupled with gas-pressure sintering for fabrication of parts for advanced diesel engines. Ceradyne gained access to gelcasting expertise and microwave facilities and experience for the nitridation of SRBSN materials. The broad objective of the CRADA between Ceradyne and OIWL was to (1) examine the applicability of the gelcasting technology to fabricate parts from SRBSN, and (2) to assess the effect of the microwave nitridation of silicon process coupled with gas-pressure sintering for fabrication of parts for advanced diesel engines. The following conclusions can be made from the work performed under the CRADA: (1) Gelcasting is a viable method to fabricate SRBSN parts ...

Energy Technology Data Exchange (ETDEWEB)

The present investigation deals with the fabrication of liquid petroleum gas (LPG) sensor based on semiconducting oxide SnO{sub 2}. The gas sensor elements have been prepared by conventional solid state route. Addition of noble metal sensitizer, palladium and grain growth inhibitor, aluminum silicate to the base material SnO{sub 2}, not only improved the sensitivity towards LPG but also the selectivity in the presence of CO and CH{sub 4} gases. Out of various sensor compositions, SnO{sub 2}:Al{sub 2}Si{sub 2}O{sub 7} (35 wt.%):Pd (1.5 wt.%) sintered at 800 C for 5 h has shown high sensitivity (0.97) towards LPG at an operating temperature of 350 C. Different characterization techniques have been employed, such as differential thermal analysis (DTA), surface area analyzer, X-ray diffraction (XRD), to study the formation of SnO{sub 2}, surface area and crystallite size, respectively. The results suggested the possibility of ...

Energy Technology Data Exchange (ETDEWEB)

A lightweight, low permeability liner for graphite epoxy composite compressed gas storage vessels. The liner is composed of polymers that may or may not be coated with a thin layer of a low permeability material, such as silver, gold, or aluminum, deposited on a thin polymeric layer or substrate which is formed into a closed bladder using torispherical or near torispherical end caps, with or without bosses therein, about which a high strength to weight material, such as graphite epoxy composite shell, is formed to withstand the storage pressure forces. The polymeric substrate may be laminated on one or both sides with additional layers of polymeric film. The liner may be formed to a desired configuration using a dissolvable mandrel or by inflation techniques and the edges of the film seamed by heat sealing. The liner may be utilized in most any type of gas storage system, and is particularly applicable for hydrogen, ...

International Nuclear Information System (INIS)

A single plasma process involving three consecutive steps has been developed for producing high gas flow catalytic nanostructures on the electrodes of proton exchange membrane (PEM) fuel cells (FC). Using a high density helicon radio frequency (13.56 MHz) plasma, nickel is sputtered onto a porous carbon support. Changing the background gas from argon to methane/hydrogen allowed 2 ?m long, 37 nm diameter carbon nanofibres (CNFs) to be grown by diffusion through the nickel clusters in a 'tip growth' mechanism at the relatively low temperature of 400 deg. C. The third step involves plasma sputtering of platinum onto the CNFs, resulting in nanoclusters (3-8 nm) being formed on the periphery of the CNFs. Four FC cathodes were synthesized on carbon paper and PTFE/carbon loaded cloth (known as gas diffusion layer, GDL), both with and without CNFs, with the Pt/CNFs nanostructures grown on PTFE/carbon loaded cloth having the best FC ...

International Nuclear Information System (INIS)

To increase further the accuracy of flow regime and considering the non-stationary characteristics of differential pressure fluctuation signals of gas-liquid two-phase flow, the flow regime identification method based on recurrence quantification analysis (RQA) and multi-sensor data fusion techniques is put forward. First of all, the recurrence quantification analysis method is used to extract the nonlinear feature parameters of the differential pressure fluctuation signals of gas-liquid two-phase flow, and data fusion of feature layer is conducted by QRA feature parameters of differential pressure signals of three pressure measure intervals, and composes the fusion feature vectors. The fused characteristic vector are input into the support vector machine for identify flow regime. The identification results for four typical flow regimes of air-water two-phase flow in horizontal pipe has shown that the reliability of the ...

Energy Technology Data Exchange (ETDEWEB)

The high insulating strength of certain gases, such as sulfur hexafluoride, when used at high pressure, suggests that there may be advantages to compressed gases as the insulating fluid in power transformers. However, simply exchanging the oil for compressed gas in an otherwise conventional transformer design will not yield a significant overall advantage. Compressed gases present the engineer with properties which are quite different from mineral oil. If gases are to be used as the major insulating fluid in power transformers, then virtually all aspects of the insulation and cooling of the apparatus must be reconsidered, affording an opportunity to introduce new design concepts, new materials, and new construction techniques. In this program, the feasibility of using the following principal design concepts has been explored: sheet conductors for the windings; a system of sealed, self-contained, annular cooling ducts containing circulating ...

Energy Technology Data Exchange (ETDEWEB)

This dissertation describes a measurement of the rate ofnuclear muon capture by the proton, performed by the MuCap Collaborationusing a new technique based on a time projection chamber operating inultraclean, deuterium-depleted hydrogen gas at room temperature and 1 MPapressure. The hydrogen target's low gas density of 1 percent compared toliquid hydrogen is key to avoiding uncertainties that arise from theformation of muonic molecules. The capture rate was obtained from thedifference between the mu- disappearance rate in hydrogen--as determinedfrom data collected in the experiment's first physics run in fall2004--and the world averagefor the mu+ decay rate. After combining theresults of my analysis with the results from another independent analysisof the 2004 data, the muon capture rate from the hyperfine singlet groundstate of the mu-p atom is found to be Lambda_S = 725.0 +- 17.4 1/s, fromwhich the ...

Energy Technology Data Exchange (ETDEWEB)

The design of the first structural wall (FSW) in an inertial confinement fusion (ICF) reactor requires some knowledge of the expected wall loading produced by x-ray and neutron deposition; specifically in the High Yield Lithium Injection Fusion Energy (HYLIFE) reactor, wall loading results from two sources -- gas shock and liquid impact. Gas shock is derived from x-ray deposition in the thin layers of exposed blanket material, producing ionized vapor, which will generate gas shock on the FSW. Liquid impact, on the other hand, results from the acceleration of liquid blanket material by two possible forces -- the drag from vapor expansion through the blanket material and the neutron-induced isochoric disassembly process. Both impacts, however, are coupled by the interaction of hot gas expanding through the liquid blanket. This paper discusses scaling methods for estimating pressure and impulse on the ...

UK PubMed Central (United Kingdom)

A cholinesterase was partially purified from bush bean (Phaseolus vulgaris L.) roots by using acridinium-based ligand affinity chromatography. The procedure gave a 78-fold increase in specific activity,...Full Text Available

UK PubMed Central (United Kingdom)

Mycobacterium tuberculosis is the etiologic agent of tuberculosis and can be accurately detected by laboratories using commercial genetic tests. Nontuberculosis mycobacteria (NTM) causing other mycobacterioses...Full Text Available

UK PubMed Central (United Kingdom)

Ion filtration chromatography on diethylaminoethyl-Sephadex A-25 has been used to separate two isozymes each of triose phosphate isomerase, glyceraldehyde 3-phosphate dehydrogenase, glycerate 3-phosphate...Full Text Available

UK PubMed Central (United Kingdom)

A Sepharose-coupled 19S human thyroglobulin has been used as an immunoadsorbent to isolate anti-thyroglobulin autoantibodies and to evaluate the antigen-antibody interactions. With the system proposed...Full Text Available

UK PubMed Central (United Kingdom)

Phenylalanine hydroxylase was purified from crude extracts of human livers which show enzyme activity by usine two different methods: (a) affinity chromatography and (b) immunoprecipitation with an...Full Text Available

UK PubMed Central (United Kingdom)

Attention has shifted from the treatment of colorectal cancer (CRC) to chemoprevention using aspirin and folic acid as agents capable of preventing the onset of colon cancer. However, no sensitive...Full Text Available

UK PubMed Central (United Kingdom)

The aim of the present study was to describe the physicochemical characteristics of streptococcal T antigen. T protein isolated from Streptococcus pyogenes type 12 (R53/1077, Colindale) and purified...Full Text Available

Science.gov (United States)

The report gives results of an examination, including mutagenic screening, of the chemical composition of residual fuel oils and their column chromatography pre-fractions. A degree of correlation between composition and mutagenicity has been achieved. Radionuclide data has been o...

UK PubMed Central (United Kingdom)

Amino acids labelled with dimethylaminoazobenzenesulphonyl chloride can be separated by reversed-phase high-pressure liquid chromatography and detected in the visible region (436 nm). All 19 naturally...Full Text Available

Science.gov (United States)

An advanced experimental technique has been developed to simulate two-phase flow behavior in a light water reactor (LWR). The technique applies three kinds of methods; (1) use of sulfur-hexafluoride (SF6) gas and ethanol (C2H5OH) liquid at atmospheric temperature and a pressure less than 1.0MPa, where the fluid properties are similar to steam-water ones in the LWR, (2) generation of bubble with a sintering tube, which simulates bubble generation on heated surface in the LWR, (3) measurement of detailed bubble distribution data with a bi-optical probe (BOP), (4) and measurement of liquid velocities with the tracer liquid. This experimental technique provides easy visualization of flows by using a large scale experimental apparatus, which gives three-dimensional flows, and measurement of detailed spatial distributions of two-phase flow. With this technique, we have carried out ...

Energy Technology Data Exchange (ETDEWEB)

This article discussed a project formed to develop innovative seismic imaging technologies. The Kaleidoscope project aims to accelerate the processing of seismic sound waves by several orders of magnitude using advanced computer-based techniques to reveal oil and gas deposits buried deep in the earth in a manner that is both cost-effective and efficient. It is expected that the technology will be used in deep water applications with massive untapped reserves. The seismic technology will be used to locate hydrocarbons and oil reserves buried 20,000 feet beneath the seabed. It is estimated that the Gulf of Mexico contains 56 billion barrels of oil equivalent worth nearly $6 trillion. However, the reserves are difficult to locate due to the interbedded salt bodies in the subsurface. The project is simultaneously working on both hardware and software applications, and are currently writing the first petascale set of seismic imaging applications. ...

Energy Technology Data Exchange (ETDEWEB)

Powders with nominal compositions (in atomic percent) Ti-48Al and Ti-48Al-2Nb-2Cr were prepared by the plasma rotating electrode process (PREP) and gas atomization (GA) techniques. As-solidified and heat-treated (1000degC per 3 h) powder samples were examined by metallography, scanning electron microscopy, X-ray diffraction and transmission electron microscopy. The microstructures of the powders were characterized as a function of atomization technique, alloy content, powder particle size (solidification rate) and thermal history. All of the as-solidified powders were comprised of disordered [alpha], and ordered [alpha][sub 2]-Ti[sub 3]Al and [gamma]-TiAl. For both alloys, a larger volume fraction of [alpha] and [alpha][sub 2] was observed in the PREP powders relative to GA powders of comparable size. Additionally, for both alloys and both atomization techniques, the volume fraction of [alpha][sub 2] ...

Energy Technology Data Exchange (ETDEWEB)

The aim of this contract is to investigate, develop, and characterize laser-assisted processing techniques utilized to produce the fine-line, thin-metal grid structures that are required to fabricate high-efficiency solar cells. During the first quarter of this contract, a comprehensive literature search was carried out in the various state-of-the-art laser-assisted techniques for metal deposition, including laser chemical vapor deposition and laser photolysis of organometallics, as well as laser-enhanced electroplating. A compact system for the experiments involving laser-assisted photolysis of gas-phase compounds was designed and constructed. The work performed in the second quarter is detailed in this report. Metal deposition experiments have been carried out utilizing laser-assisted pyrolysis of a variety of metal-bearing polymer films and metallo-organic inks spun onto silicon substrates. Laser decomposition of spun-on ...

Energy Technology Data Exchange (ETDEWEB)

The effects of temperature and the use of macroreticular resins were studied in lithium isotope separation by an ion-exchange method. The isotope separation factors obtained decreased by increasing the temperature, and the factors for macroreticular resins were identical with those for the usual gel-type resins. However, the performance of isotope separation per unit band length in displacement chromatography was found to be improved by increasing the temperature and using macroreticular resins, because accelerating the interphase mass transfer caused the reduction of HETP (Height Equivalent to a Theoretical Plate).

Energy Technology Data Exchange (ETDEWEB)

The availability of polysilicon feedstock has become a major issue for the photovoltaic (PV) industry in recent years. Most of the current polysilicon feedstock is derived from rejected material from the semiconductor industry. However, the reject material can become scarce and more expensive during periods of expansion in the integrated-circuit industry. Continued rapid expansion of the PV crystalline-silicon industry will eventually require a dedicated supply of polysilicon feedstock to produce solar cells at lower costs. The photovoltaic industry can accept a lower purity polysilicon feedstock (solar-grade) compared to the semiconductor industry. The purity requirements and potential production techniques for solar-grade polysilicon have been reviewed. One interesting process from previous research involves reactive gas blowing of the molten silicon charge. As an example, Dosaj et all reported a reduction of metal and boron impurities from ...

Energy Technology Data Exchange (ETDEWEB)

Chemical composition of fine aerosol particles over the northern Chilean coastal waters was determined onboard the U.S. DOE G-1 aircraft during the VOCALS (VAMOS Ocean-Cloud-Atmosphere-Land Study) field campaign between October 16 and November 15, 2008. SO42-, NO3-, NH4+, and total organics (Org) were determined using an Aerodyne Aerosol Mass Spectrometer, and SO42-, NO3-, NH4+, Na+, Cl-, CH3SO3-, Mg2+, Ca2+, and K+ were determined using a particle-into-liquid sampler-ion chromatography technique. The results show the marine boundary layer (MBL) aerosol mass was dominated by non- sea-salt SO42- followed by Na+, Cl-, Org, NO3-, and NH4+, in decreasing importance; CH3SO3-, Ca2+, and K+ rarely exceeded their respective limits of detection. The SO42- aerosols were strongly acidic as the equivalent NH4+ to SO42- ratio was only ~0.25 on average. NaCl particles, presumably of sea-salt origin, showed chloride deficits but retained Cl- typically more ...

Energy Technology Data Exchange (ETDEWEB)

An embodiment of a mercury-free fluorescent lamp combines a low pressure rare gas discharges with a phosphor having a quantum efficiency grater than one. The choice of the rare gas depends on a number of factors, one of which is the resonance transition energy. Less demand is placed the quantum efficiency of the phosphor for a lower energy resonance photon. Xenon has the lowest energy resonance transition of the stable rare gases at 8.5 eV (147 nm) and thus is a good candidate to study. The usefulness of a xenon-based discharge depends on the radiant emittance of the discharge at the resonance wavelength of 147 nm. The radiant emittance from a low pressure xenon positive column discharge is measured using two independent techniques. The first relies on the measurement of the resonance level density using absorption techniques. The effective decay rate of the resonance level is calculated using radiation ...

Energy Technology Data Exchange (ETDEWEB)

The invention relates to a method for purifying a gas mixture containing at least one undesirable gas compound utilizing certain sulfonamide or sulfamide solvents.

Science.gov (United States)

The largest solar heating and cooling system undertaken to date is now operating at the George A. Towns Elementary School in Atlanta, Georgia. It is expected to provide more than 60 percent of the building's heating and cooling requirements, using commercially available components and techniques. The Towns project is a United States Energy Research and Development Administration-sponsored experiment. The principal components of the solar heating and cooling system designed for the school--the solar collector array, the existing gas-fired boiler, the absorption chiller, and hot and cold water underground tanks to provide thermal storage--are described. To derive maximum benefit from the experiment, the system is fully instrumented for accurate measurement of performance. Environmental data, including insolation and ambient temperture, humidity, and wind conditions will be recorded. The inlet temperatures, outlet temperatures, and the ...

Energy Technology Data Exchange (ETDEWEB)

A generalized approach to the analysis of the effects of transmission line faults on natural gas transmission pipelines has been developed and is presented in this report. A state of the art user-friendly computational tool has been developed and verified for the analysis of interference between electrical power lines and nearby buried or above-ground pipelines. This computer program, ECCAPP, is distinguished by its ability to model and analyze accurately complex, realistic interactions between pipelines and power lines, using easily obtained input data. The final report consists of three volumes. An independent fourth volume was also developed to simplify the installation of the ECCAPP software. This report, volume 1, contains the theory upon which the ECCAPP computer program is based. A parametric analysis and graphical charts have been formulated using ECCAPP to permit estimates to be made in the field or during preliminary analyses for situations that are not ...

Energy Technology Data Exchange (ETDEWEB)

Permian coal and Triassic mudstone from the Ordos Basin were pyrolyzed in a closed system using a gold tube technique. Carbon and hydrogen isotopes of the gases generated from pyrolysis were compared to Mesozoic gases in the basin to interpret the origin, maturity and any mixing of gases. Maturation trends for thermogenic methane from both coal and lacustrine kerogens in our experiment were found to be independent of heating rate, allowing their use for determination of gas provenance. Gases from a tectonically stable area like the Shanbei slope are derived mainly from Yanchang lacustrine kerogen, and gases in tectonically active areas consist of mixtures of coal-derived gases and oil-associated methane from deeply buried formations, as well as oil-associated gases and biogenic gases from shallow depth. The thermal maturity of the C{sub 2} and C{sub 3} gases is estimated to cover an equivalent vitrinite reflectance range from 0.7% to 1.2% R{sub ...

Energy Technology Data Exchange (ETDEWEB)

This paper deals with an industrial application of the foam decontamination process applied to large volume components. The work presented below was achieved within the context of a CEC contract. The objective of this 4-year programme was to study, develop and demonstrate an effective in-situ decontamination process using foams containing suitable chemical reagents. Laboratory tests were first performed to optimize the chemical formulation of the foams. Pilot tests were then conducted to study the hydrodynamic features of the fluids and to adapt a technique of permanent foam circulation. With these tests completed, it was essential to validate the foam process on an industrial scale and on a representative nuclear component. The objective was successfully achieved. The process was effectively validated during the decontamination of a graphite-gas cooler representing a developed area of 1000 m{sup 2}. Results were quite convincing since the ...

British Library Electronic Table of Contents (United Kingdom)

Background When assessing the function of the cardiovascular system, cardiac output (CO) is a substantial parameter. For its determination, numerous non-invasive techniques have been proposed in the recent years including inert gas rebreathing (IGR) and impedance cardiography (ICG). The aim of our study was to evaluate whether a novel ICG algorithm (electrical velocimetry) and IGR can be used interchangeably in the clinical setting. Methods A total of 120 consecutive stable patients were included resulting in two pairs of repeated non-invasive cardiac output measurements. Results The mean CO was 5.0???1.2?l/min (range 2.6?8.6?l/min) using IGR and 4.4???1.1?l/min (1.7?7.4?l/min) using ICG, respectively. Bland?Altman analysis revealed an acceptable agreement with a mean bias of 0.6???1.2?l/m...

Science.gov (United States)

The growth of an oxide interfacial layer was recently found to increase the open-circuit voltage (OCV) and efficiency by up to 60 per cent in GaAs metal-semiconductor solar cells. Details of oxidation techniques to provide the necessary oxide thickness and chemical structure and using ozone, water-vapor-saturated oxygen, or oxygen gas discharges are described, as well as apparent crystallographic orientation effects. Preliminary results of the oxide chemistry obtained from X-ray, photoelectron spectroscopy are given. Ratios of arsenic oxide to gallium oxide of unity or less seem to be preferable. Samples with the highest OVC predominantly have As(+3) in the arsenic oxide rather than As(+5). A major difficulty at this time is a reduction in OCV by 100-200 mV when the antireflection coating is vacuum deposited.

Energy Technology Data Exchange (ETDEWEB)

Supercritical CO2 is used as a new solvent for immersion deposition, a galvanic displacement process traditionally carried out in aqueous HF solutions containing metal ions, to selectively develop metal films on featured or non-featured silicon substrates. Components of supercritical fluid immersion deposition (SFID) solutions for fabricating Cu and Pd films on silicon substrates are described along with the corresponding experimental setup and procedure. Only silicon substrates exposed and reactive to SFID solutions can be coated. The highly pressurized and gas-like supercritical CO2, combined with the galvanic displacement property of immersion deposition, enables the SFID technique to selectively deposit metal films in small features. SFID may also provide a new method to fabricate palladium silicide in small features or to metallize porous silicon.

British Library Electronic Table of Contents (United Kingdom)

A study was conducted to determine the fitting soil moisture for the normal growth of two-year-old W. sinensis (Sims) Sweets by using gas exchange technique. Remarkable threshold values of net photosynthetic rate (Pn), transpiration rate (Tr) and water use efficiency (WUE) were observed in the W. sinensis leaves treated by various soil moisture and photosynthetic available radiation (PAR). The fitting soil moisture for maintaining a high level of Pn and WUE was in range of 15.3%?26.5% of volumetric water content (VWC), of which the optimal VWC was 23.3%. Under the condition of fitting soil moisture, the light saturation point of leaves occurred at above 800?mol?m?2?s?1, whereas under the condition of water deficiency (VWC, 11.9% and 8.2%) or oversaturation (VWC, 26.5%), the light saturatio...

British Library Electronic Table of Contents (United Kingdom)

Earth degassing specifically of carbon dioxide CO2 is of increasing interest with respect to the global carbon budget, related climate effects, earthquake and volcano eruption mechanisms, as well as plant physiological reactions in gas-rich environments. Investigations in all of these disciplines require the detection of surface CO2 degassing structures and quantification of their emissions. We introduce minimal thermal change detection based on infrared imaging as a new remote sensing tool for the detection of earth surface thermal anomalies suiting among others to discover earth degassing locations of any origin. The method allows for seamless areal search and monitoring of degassing structures in any terrain. As proof of concept infrared imaging measurements were performed at the Bossol...

Energy Technology Data Exchange (ETDEWEB)

New results for two types of nano-size silicon, prepared via thermal vapour deposition either with or without a graphite substrate are presented. Their superior reversible charge capacity and cycle life as negative electrode material for lithium-ion batteries have already been shown in previous work. Here the lithiation reaction of the materials is investigated more closely via different electrochemical in situ techniques: Raman spectroscopy, dilatometry and differential electrochemical mass spectrometry (DEMS). The Si/graphite compound material shows relatively high kinetics upon discharge. The moderate relative volume change and low gas evolution of the nano silicon based electrode, both being important points for a possible future use in real batteries, are discussed with respect to a standard graphite electrode. (author)

Energy Technology Data Exchange (ETDEWEB)

Excitation of low temperature helium or helium/water plasma and subsequent exposure to air of polyacrylonitrile (PAN) ultrafiltration membranes was used to hydrophilize the surface of these materials. We analyzed the effectiveness of this approach as a function of plasma operating variables including gas phase composition, plasma power, treatment time and system pressure. Following the changes in physical and chemical composition of the PAN surface resulting from these modifications was a major aspect of this work. Techniques such as the captive bubble contact angle method, ellipsometry, ESCA, and FTIR-ATR were all used. In addition, the formation and life-time of peroxides during these processes were determined. At low powers (<25W) and short treatment periods ({<=}30 sec), the main chemical conversion of PAN surfaces was simultaneous hydrophilization and stabilization via PAN cyclization. Relatively small water permeability changes were ...

International Nuclear Information System (INIS)

This work describes the ability of ion beam analysis techniques IBA to simultaneously determine the concentration and the possible depth profile of some light elements, such as carbon, oxygen and nitrogen, in matrices of high atomic number Z, such as stainless steel materials. In fact, the nitriding process of some materials has the potential to improve their tribological and mechanical properties and to offer various advantages as compared with other methods used in the modification of surfaces. Gas and Plasma nitriding were applied to certain types of steel, such as AISI-304 and H-13 which are commonly used in the industry, in order to improve their hardness and their surface corrosion resistance. The improvement was correlated with the depth profile of N and the consequent structure variations. More specifically, non-Rutherford elastic backscattering (alpha, alpha) at 5 MeV was performed on different samples, before and after nitriding, in ...

Energy Technology Data Exchange (ETDEWEB)

The application of a method for determining the temperature of an oxygen-replenished air stream heated to 2600 K by a hydrogen burner is reviewed and discussed. The purpose of the measurements is to determine the spatial uniformity of the temperature in the core flow of a ramjet test facility. The technique involves sampling the product gases at the exit of the test section nozzle to infer the makeup of the reactant gases entering the burner. Knowing also the temperature of the inlet gases and assuming the flow is at chemical equilibrium, the adiabatic flame temperature is determined using an industry accepted chemical equilibrium computer code. Local temperature depressions are estimated from heat loss calculations. A description of the method, hardware and procedures is presented, along with local heat loss estimates and uncertainty assessments. The uncertainty of the method is estimated at {+-}31 K, and the spatial uniformity was measured within {+-}35 K.

International Nuclear Information System (INIS)

Since high resolution sequence stratigraphy was introduced into China by DENG Hong-wen in 1995, it has been experienced two development stages in China which are the beginning stage of theory research and development of theory research and application, and the stage of theoretical maturity and widely application that is going into. It is proved by practices that high resolution sequence stratigraphy plays more and more important roles in the exploration and development of oil and gas in Chinese continental oil-bearing basin and the research field spreads to the exploration of coal mine, uranium mine and other strata deposits. However, the theory of high resolution sequence stratigraphy still has some shortages, it should be improved in many aspects. The authors point out that high resolution sequence stratigraphy should be characterized quantitatively and modelized by computer techniques. (authors)

Energy Technology Data Exchange (ETDEWEB)

The global interest in renewable energy is attributed to the decline in fossil fuel sources and the need for technical, economic, social and environmental sustainability. This study focused on the new techniques that have been developed for the use of biomass for energy from wood wastes from the forest-based industry. As an energy source, wood waste contributes positively to the environment by reducing environmental problems related to contamination of soil, air and water through improper disposal of waste. Biomass gasification has the advantage of converting biomass into a combustible gas that can be used for heat generation, electricity and synthesis of chemicals. Syngas produced from gasification of eucalyptus residues has significant potential, with an average High Heating Value of 6.60 MJ/m{sup 3}, and regular composition during the process, with predominance of carbon monoxide, followed by hydrogen, carbon dioxide and methane.

Energy Technology Data Exchange (ETDEWEB)

The North Dakota Energy & Environmental Research Center (EERC) approach to removing NO{sub x} from flue gas emitted by coal-fired utility boilers or for the control of NO{sub x} formation by advanced combustion techniques involves the development of a catalytic fabric filter (CFF) for simultaneous NO{sub x} and particulate control. The NO{sub x}is removed by catalytic reduction with ammonia to form nitrogen and water. Bench-scale experimental results have shown that over 90% NO{sub x} removal can be achieved. This report details the strengths and areas for for development in this project.

International Nuclear Information System (INIS)

The alloy type 'alloy 800' with its different variants is used for numerous components in high-temperature reactor (HTR) plants, e.g. for hot-gas conductors, the high-pressure part of steam generators, superheaters, steam collecting vessels and live steam conductors. This study deals with the evaluation of creep rupture tests on 28 welded joints of alloy 800 with an accumulated test duration of 410 years, with the objective to obtain quantitative information on a possible loss of strength in comparison with the unwelded material. The longest test period of an individual test amounted to 98,000 h and the analyzed test temperature range lay between 550"0 and 1000"0C. (orig./MM).

Energy Technology Data Exchange (ETDEWEB)

The bulk removal of CO/sub 2/ from industrial gases is a frequently applied process in the field of gas-treating. Usually chemical solvents are used in order to increase both the solvent-loading capacity and the absorption rate. These solvents often are aqueous solutions of alkanolamines. The loaded-liquid is regenerated at high temperatures with the aid steam. In the present study absorption rates are experimentally determined in various mixtures of amines over a wide range of concentrations. Simultaneously, a model was developed for the description of mass transfer accompanied by parallel reversible chemical reactions. The equations of this mass transfer model could not be solved analytically and therefore numerical techniques were used to obtain an exact description of this process. This model also includes the asymptotic situations of homogeneous catalysts and shuttle mechanism for which in the literature several approximate solutions have ...

International Nuclear Information System (INIS)

The densification of #alpha#"1-and #alpha#"+#beta#"1-sialon ceramics has been studied by means of in situ dilatometry. It is seen that the densification is greatly affected by the reaction sequences and the grain growth. The formation and densification of sialons start simultaneously as the dissolution of nitrides into the oxide eutectic liquid phase occurs. The formation of sialons is complete at 1800 deg C., while full densification can only be obtained by using gas pressure sintering. The typical microstructure of both #alpha#"'-and mixed #alpha#'+#beta#'-sialon ceramics consists of a crystalline phase of sialons and a small fraction of amorphous phase at grain boundaries. Vickers hardness (HV0.5) was measured by using the indentation technique, and the biaxial bending strength (#sigma#_b_i) was determined with the 'ball-on-ring' test. Fracture toughness was determined by using both the indentation and single-edged notched beam ...

International Nuclear Information System (INIS)

Focused ion beam (FIB) milling techniques are presented aiming at the manipulation of both tin dioxide (SnO_2) inverted opals and polystyrene (PS) direct opals. Different SnO_2 opals are considered in order to estimate the regularity of their bulk after the production. A SnO_2 mesoporous monolith is FIB micromachined to make it suitable for optical applications. PS direct opals are structured by FIB milling at different scales. Ordered arrays of PS opals are modified by selectively removing a single sphere. In performing this task, we discuss the effects on the FIB milling due to the gas-assisted enhanced etching and to the binding of the nearest neighbours. Techniques to achieve imaging of PS opals in absence of a conductive coating are also brought up. Furthermore, isolated PS spheres are drilled with or without enhanced etching in order to produce controlled defects on them. The FIB-assisted manipulations we show may ...

International Nuclear Information System (INIS)

In this paper, we propose to characterize boron transient enhanced diffusion (TED) for processes currently used for P"+/N ultra-shallow junctions (USJ) fabrication. Indeed, the fundamental understanding of boron diffusion for low energy boron implantation is mandatory to evaluate the scalability of such processes for the coming complementary metal-oxide-semiconductor (CMOS) transistor generations. In these experiments, we characterize the boron anomalous diffusion, thanks to boron buried marker-layers obtained by epitaxial growth. B"+ and BF_2"+ ultra-low energy (ULE) implantations and plasma doping (PLAD) using BF_3 as precursor gas are carried out to compare the two techniques used for advanced USJ fabrication. Boron diffusion behaviors are analyzed via secondary ion mass spectrometry for annealing at 700 deg. C for 5 min and 15 min. Finally this paper brings some physical insights explaining the technological benefit coming from PLAD ...

Energy Technology Data Exchange (ETDEWEB)

A real-time neutron radiography (RTNR) system is used to determine two-phase flow parameters for a horizontal co-current two-phase flow channel with a cylindrical 37 rod bundle. Image processing techniques are applied to visualize the two-phase flow, and to determine flow regime, cross-sectional averaged void fraction, time averaged void fraction, and void distribution. The experimentally determined flow regime map disagrees with existing flow regime models developed for the cylindrical rod bundles. A new flow regime is observed and designated large amplitude stratified wavy (LASW) flow. The results show that the LASW flow regime may be due to a combination of undeveloped flow phenomena, boundary conditions, and circumferential cross flow occuring in the bundle. The rods in the bundle may act as a dampener to the vertical flow component and hinders the development of the wave into plug or slug flow by changing the momentum of the fluid in the circumferential ...

International Nuclear Information System (INIS)

As for No.2 plant in Sendai Nuclear Power Station, which is the fourth nuclear power generation facilities in Kyushu Electric Power Co., Inc., all works have been completed, and at present, the final trial operation is under way. In No.2 plant, many new techniques for raising the reliability and safety, improving the maintainability and reducing radiation exposure were introduced on the basis of the operation experience of PWRs obtained so far, similarly to No.1 plant. In this paper, the main items of the new techniques related to the design and construction of the plant are reported. No. 2 plant is a first improved and standardized plant having the thermal output of 2660 MW for standard three-loop PWRs, and the rated power output was set at 890 MW. As for the turbine, TC6F-40 in was adopted. As the improved design, a large reactor containment vessel, 17 x 17 type 9-grid fuel, improved steam generators, a reactor vessel cover of one-body type, ...

Science.gov (United States)

Citizens Gas and Coke Utility operates three coke oven batteries, producing both foundry coke and blast furnace coke, under the trade name Indianapolis Coke. Active participation in the regulation negotiation process by the Vice President of Indianapolis Coke allowed the company to accurately anticipate the environmental regulations, long before they were set in law. Several improvements were put into motion that helps them meet the new environmental regulations. Better trained operators with new job positions dedicated solely to environmental compliance, an extensive environmental training program, and two innovations, a portable oven door milling and cleaning machine and three new computer applications are the result of team efforts. The focus of this paper is development of the computer applications designed to enhance three areas of environmental compliance. The three areas addressed by the applications are documentation and information deployment, problem ...

Energy Technology Data Exchange (ETDEWEB)

In rare instances, carbon monoxide (CO) levels in houses can reach dangerously high concentrations, causing adverse health effects ranging from mild headaches to, under extreme conditions, death. Hundreds of fatal accidental carbon monoxide poisonings occur each year primarily due to the indoor operation of motor vehicles, the indoor use of charcoal for cooking, the operation of malfunctioning vented and unvented combustion appliances, and the misuse combustion appliances. Because there is a lack of simple, inexpensive, and accurate field sampling instrumentation, it is difficult for gas utilities and researchers to conduct field research studies designed to quantify the concentrations of CO in residences. Determining the concentration of CO in residences is the first step towards identifying the high risk appliances and high-CO environments which pose health risks. Thus, there exists an urgent need to develop and field-validate a CO-quantifying ...

Energy Technology Data Exchange (ETDEWEB)

Full text of publication follows: Energy and environment are two major concerns in our modern society due to the coming shortage in fossil energy sources and the growing of greenhouse gas emissions. The challenge for the coming years is to discover new energy resources and to develop devices that are compatible with a sustainable development and generate few (or zero) emission. One of these devices is the fuel cell feed by hydrogen, whose application fields are very large. In particular, the proton exchange membrane fuel cell (PEMFC) is the most realistic device for automotive application. However, hydrogen storage remains one of the most important challenges regarding its development. Although different techniques are available for storing hydrogen, no ideal solution has been found yet. Compression needs elaborated tanks in shape for supporting high pressures, liquefaction requires an expensive hydrogen cooling and adapted tanks. Chemical ...

Energy Technology Data Exchange (ETDEWEB)

In this paper we consider properties of the ideal gas of classical (nonquantum) tachyons.

KoreaScience (Korea)

Full Text Available

International Nuclear Information System (INIS)

A method, based on anion exchange chromatography, is presented for the isolation of "1"3"9Ce after production by a proton-induced nuclear reaction on a thick praseodymium target. After bombardment the target is dissolved in nitric acid and "1"3"9Ce oxidised to the Ce(IV) oxidation state with bromic acid. "1"3"9Ce is then separated form the praseodymium by anion exchange chromatography on a Ag MP-1 resin column in a nitric acid - bromic acid mixture. "1"3"9Ce is sorbed onto the resin column and praseodymium eluted with the acid mixture. The bromic acid is washed out of the column with nitric acid and "1"3"9Ce finally eluted with dilute nitric acid containing sulphur dioxide.

British Library Electronic Table of Contents (United Kingdom)

A simple, sensitive and rapid method for analysis of granisetron in human plasma, utilizing liquid chromatography tandem mass spectrometry (LC-MS/MS), has been developed and validated to satisfy FDA guidelines for bioanalytical methods. The analyte and internal standard (IS) were isolated from 100ml plasma samples by liquid-liquid extraction (LLE). A Varian 1200l tandem mass spectrometer equipped with an electrospray ionization source was operated in selected reaction monitoring (SRM) mode with the precursor-to-product ion transitions m/z 313.4/138 for granisetron and m/z 270/201 for the IS used for quantitation. The assay exhibited a linear dynamic range of 0.02-20ng/ml for granisetron in human plasma. The lower limit of quantification (LLOQ) was 0.02ng/ml with a relative standard deviati...

International Nuclear Information System (INIS)

Fractionation of isotopes of the alkali metals and the alkaline earth metals in ion exchange chromatography of their chlorides was studied. The heavier isotopes of potassium and rubidium were found to be preferentially fractionated into the ion exchanger phase while the lighter isotopes of lithium, magnesium, calcium and strontium were enriched in the exchanger phase. This can be interpreted as a resultant of the relative significance of isotope effect upon dehydration and isotope effect accompanying the phase change of the hydrated metal ion. Found was no evidence of anomalous isotope effect attributable to the odd-even difference in mass number of isotopes. Based on the spectroscopic and solution chemical data (experimental and theoretical), the isotopic reduced partition function ratios of the hydrated alkaline metal ions and stretching force constants of metal ion-hydrating water bonds were estimated. (author).

Energy Technology Data Exchange (ETDEWEB)

Conditions of the separation and detection of organic and inorganic anions by gradient ion chromatography and suppressed conductivity detection were studied, and the procedure of gradient elution was optimized. A detection limit of 1 x 10{sup -3} {mu}g x L{sup -1} was obtained using the pre-concentrated column and most relative standard deviations obtained in the determination of seven organic and inorganic anions were below 5%. This method was proved to be simple, rapid and accurate for the separation and determination of low-molecular-weight organic acids and inorganic anions and could be applied in the analysis of the samples from water and steam systems of thermal power plants with satisfactory results. (orig.)

International Nuclear Information System (INIS)

The study reports the identification of different organic acids that are formed during the pyrohydrolysis of mixed carbide of uranium and plutonium using ion chromatography (IC). The identification of organic acids present in the pyrohydrolysis distillate is required to carry out interference free analysis of Cl and F. The study describes three stage isocratic separations with NaOH eluents having concentrations 2 mM, 10 mM and 50 mM respectively in order to separate and identify both aliphatic and aromatic acids. The present investigation identified formic, acetic, propionic, butyric, tartaric and oxalic acids in the distillate, however, aromatic acids could not be identified. (author)

Energy Technology Data Exchange (ETDEWEB)

Part 2 of this manual provides the electric utility engineer with detailed technical information on some of the major mechanical equipment used in the FGD system. The objectives of Part 2 are the following: to provide the electric utility engineer with information on equipment that may be unfamiliar to him, including ball mills, vacuum filters, and mist eliminators; and to identify the unique technique considerations imposed by an FGD system on more familiar electric utility equipment such as fans, gas dampers, piping, valves, and pumps. Part 3 provides an overview of the recommended procedures for evaluating proposals received from FGD system vendors. The objectives are to provide procedures for evaluating the technical aspects of proposals, and to provide procedures for determining the total costs of proposals considering both initial capital costs and annual operating and maintenance costs. The primary objective of Part 4 of this manual is ...

Science.gov (United States)

We present a new approach for growing Si nanowires directly from a silicon substrate, without the use of a metal catalyst, silicon vapor or CVD gasses. The growth can be performed in a furnace type configuration at moderate temperatures or in localized regions by resistive heating. Since the silicon wires grow directly from the silicon substrate, they do not need to be manipulated nor aligned for subsequent applications. Wires in the 20-50 nm diameter range with lengths over 80 ?m can be grown by this technique. We have studied the effects of various growth parameters, including temperature, substrate orientation, initial sample cleaning and carrier gasses. Results indicate that most important parameters in the growth of the nanowires are the surface cleaning, the temperature and the type of carrier gas used. A model is proposed, which involves an oxide catalyst for the process, with the growth of the nanowires enabled by a significantly ...

Energy Technology Data Exchange (ETDEWEB)

Alter both oil crisis, of 1973 and 1979, a bad effect of the elevated costs and continuously increment of the oil prices was noted, for this reason, the interest for renewable energies sources widely available in developing countries was increased. All over the world, governments have formulated main objectives for energies savings and search for friendly technologies, taking into account the effects related with the environment. The imminent scarcity of fossil fuels has made humanity the rational use of primary energies, as a result of these; new plants with improved technology have been conceived taking into account energy savings and efficiency improvement. In this context, biomass gasification technologies are important, since they consist in techniques of parallel production of electricity and heat from just one fuel. This work consists in the development of a gasifier down draft of 100 kW for an internal combustion engine, which includes its sizing process ...

Energy Technology Data Exchange (ETDEWEB)

A gas diffusion semiconductor electrode and solar cell and a process for gaseous fixation, such as nitrogen photoreduction, CO/sub 2/ photoreduction and fuel gas photo-oxidation are described. The gas diffusion photosensitive electrode has a central electrolyte porous matrix with an activated semiconductor material on one side adapted to be in contact with an electrolyte and a hydrophobic gas diffusion region on the opposite side adapted to be in contact with a supply of molecular gas.

UK PubMed Central (United Kingdom)

The polysaccharide components from cultured cells of Rhizobium fredii USDA205 and Rhizobium meliloti AK631 were extracted with hot phenol-water and separated by repetitive gel filtration chromatography....Full Text Available

UK PubMed Central (United Kingdom)

Maleic hydrazide (MH) is taken up by corn and pea seedling roots and bound to some material which is insoluble in 80% ethanol or 5% trichloroacetic acid. ¹⁴C-MH is stable metabolically; chromatography...Full Text Available

International Nuclear Information System (INIS)

Dianionic tridentate, O, N, S Schiff bases derived from salicylaldehyde and 2-mercapto-amines react with Tc(V) gluconate to form radiochemically pure neutral Tc chelates. The existence of lipophilic Tc complexes could be proved by high voltage electrophoresis, thin layer chromatography and octanol/water partition coefficients. (author).

International Nuclear Information System (INIS)

Carbaryl is one of the insecticides used in large quantities in Indonesia. It is effective against soybean and peanut plant insects. The residues in the plants are determined by Colorimetry at the residues level up to 5 ppm and by thin layer chromatography at level up to 0,1 ppm. Both methods use coupling reaction between hydrolysis product of Carbaryl and diazo reagent to produce colour. (author).

Energy Technology Data Exchange (ETDEWEB)

A hyaluronic acid binding fraction was purified from the supernatant media of both 3T3 and murine sarcoma virus (MSV) transformed 3T3 cultures by hyaluronate and immunoaffinity chromatography. Sodium dodecyl sulfate-polyacrylamide gel electrophoresis resolved the hyaluronate affinity-purified fraction into three major protein bands of estimated molecular weight (M/sub r,e/) 70K, 66K, and 56K which contained hyaluronate binding activity and which were termed hyaluronate binding proteins (HABP). Hyaluronate affinity chromatography combined with immunoaffinity chromatography, using antibody directed against the larger HABP, allowed a 20-fold purification of HABP. Fractions isolated from 3T3 supernatant medium also contained additional binding molecules in the molecular weight range of 20K. This material was present in vanishingly small amounts and was not detected with a silver stain or with (/sup 35/S)methionine label. The ...

CERN Document Server

Lithography Production Techniques for next Generations of Microelectronics

International Nuclear Information System (INIS)

An overview is given the expected amount of natural gas that can be produced from small gas fields in the Netherlands in the next 20 years.

Energy Technology Data Exchange (ETDEWEB)

The origin of natural gas in the Japanese oil and gas fields are geochemically studied. Samples are taken from structural natural gas, surface gas seepage, water-dissolved natural gas and coal-field gas of the Japan Sea coast area. The origins of primary hydrocarbons are classified into bacteria gas and thermogenic gas, the latter being subclassified into gas in oil production zone with the per million deviation of the carbon isotope (/sup 13/C/sup 1/) of methane less than -35 and those gases with maturity higher than this. Surface gas seepage is subjected to migration and bacterial oxidation. Coal gas is similar to oil gas. The CO/sub 2/ concentration is 0 - 2% and /sup 13/CO/sub 2/ deviations from -30 - +30. The origin can be barely ...

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

UK PubMed Central (United Kingdom)

Many older homes are equipped with mercury-containing gas regulators that reduce the pressure of natural gas in the mains to the low pressure used in home gas piping. Removal of these regulators can...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

Science.gov (United States)

... Accession Number : ADD419503. Title : Flue Gas Desulfurization and Low Btu Gasification - A Comparison Appendix G. ...

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

Energy Technology Data Exchange (ETDEWEB)

Sewage gas or biogas as a product of anaerobic digestion contains methane and carbon dioxide as its main components. Biogas is scrubbed off carbon dioxide in absorption columns and purified to natural-gas quality. The purified gas then is piped to the gas pressure control station and fed into the public network. Description of process and plant is given.

Energy Technology Data Exchange (ETDEWEB)

We report the performance of a micro gas turbine on biomass producer gas and mixtures of biomass producer gas with natural gas. The micro gas turbine delivers full power on gas mixtures with a heating value of at least 15 MJ/Nm{sup 3}. For gas of lower heating value, the maximum fuel gas flow limits the attainable power. The lower limit for stable operation is about 8 MJ/Nm{sup 3}. The gross efficiency of the micro gas turbine depends on output power but not on the gas heating value, within our measurement accuracy. Above 70% of full power, emissions of CO and NO are 40 and 10 times lower than those of a gas engine of similar size. At part load below 70% of full power, the micro gas turbine burner switches to a different operating mode ...

International Nuclear Information System (INIS)

An overview of different Ion Beam Analysis (IBA) techniques is given. Examples of applications of the PIXE techniques to various types of samples are presented. (author)

Energy Technology Data Exchange (ETDEWEB)

This work presents a comparative study of low-alloy steel nitriding for different possible techniques. Active screen plasma nitriding (ASPN) is a successful surface modification method that has many advantages over the conventional DC plasma nitriding (CPN). The corrosion behavior of 30CrNiMo8 low-alloy steel has been examined using anodic polarization tests in 3.5% NaCl solution under varying conditions of ASPN and CPN processes. The process variables included active screen setup parameters, treatment temperature (550 and 580 deg. C), gas mixture (25/75 and 75/25 of N{sub 2}/H{sub 2}) and treatment time (5 and 10 h) in 500 Pa pressure. The structure and phases composition of the compound layer was studied by X-ray diffraction (XRD), microhardness tests, optical microscopy and scanning electron microscopy (SEM). It was observed that ASPN treated samples surface enhanced corrosion resistance while the temperature and/or hole size of screen setup ...