Energy Technology Data Exchange (ETDEWEB)

The ..beta.. decay half-lives of neutron-rich isotopes with Z=24-28 are calculated in the QRPA with a Gamow-Teller residual interaction. For odd-mass and odd-odd systems QRPA phonon correlations are introduced to quasiparticle transitions in first-order perturbation. The calculated half-lives agree very well with the experimental values. For later application of this model to nuclei far from stability, we have examined the dependence of the calculated half-lives on the model parameters.

International Nuclear Information System (INIS)

Spin-flip probabilities for "4"8Ca(p vector, n vector)"4"8Sc reveal that at 0"0 the apparent continuum under and adjacent to the Gamow-Teller giant resonance is also primarily 1"+ strength. A comparison of "4"0Ca(p vector,n vector)"4"8Sc shows no discernable signature of Gamow-Teller strength in the region -30 > Q(MeV) > -45. The spin-flip component of the dipole resonance for "4"0Ca is broader than the non-spin-flip component. (orig.).

International Nuclear Information System (INIS)

The electron structure of the A-15 compounds is studied by accounting for the Hubbard energy as the highest energy parameter. The conditions for the Cooper instability origination are obtained. The superconducting transition temperature dependence on the degree of filling the d- and p-shells of the transition and nontransition elements is determined. The relationship between the transition temperature and the energy jumpover along the chains, which allows comparison with the experiment, is established. Qualitative explanation of the Mattias empiric rules is presented

International Nuclear Information System (INIS)

... radioisotopes coincidence methods energy-level transitions gamma radiation

International Nuclear Information System (INIS)

Our studies on K#beta#/K#alpha# X-ray intensity ratios of some of the technologically important 3d-transition metal compounds have been reviewed. Comparison of the experimental results with single-configuration Dirac-Fock calculations provided important information on the valence states of the transition metals in various compounds, which can be helpful in understanding the nature of bonding in the compounds. (author)

Energy Technology Data Exchange (ETDEWEB)

The normal-incommensurate phase transition in K2ZnCl4 was studied by neutron scattering measurements. A well-defined soft phonon behavior was not observed above the normal-incommensurate transition temperature of Tsub(i)=288C. Diffuse scattering develops around(h,0,1 +- 0.3) as temperature approaches Tsub(i) from above, and the peak intensity obeys a Curie-Weiss law above Tsub(i). The results indicate that the normal-incommensurate phase transition in K2ZnCl4 can be interpreted as an order-disorder process.

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The two-phase flow regime transition in a large diameter (I.D.=200mm) vertical pipe was experimentally investigated using a dual-sensor optical probe. The flow transitions from bubbly to chum without an intermediate slug flow regime as the air flow rate is increased. The transition boundaries developed for bubbly to slug flow in small diameter pipes are compared to the bubbly to chum flow transition of the present experiment. The bubbly to chum transition occurs at a void fraction of about 0.15 compared to 0.25 for bubbly to slug transition in small diameter pipes. The radial distribution of bubble diameter, bubble frequency, bubble velocity and local void fraction were obtained using a dual-sensor optical probe at different flow conditions. The Probability Density Function (PDF) and Cumulative Distribution Function (CDF) of the bubble velocity and size are used ...

Energy Technology Data Exchange (ETDEWEB)

This work concerns the development of a methodology the objective of which is to characterize and diagnose two-phase flow regime transitions. The approach is based on the fundamental assumption that a transition flow is less stationary than a flow with an established regime. During the first time, the efforts focused on: (1) the design and construction of an experimental loop, allowing to reproduce the main horizontal two-phase flow patterns, in a stable and controlled way; (2) the design and construction of an electrical impedance probe, providing an imaged information of the spatial phase distribution in the pipe; and (3) the systematic study of the joint time-frequency and time-scale analysis methods, which permitted to define an adequate parameter quantifying the unstationarity degree. During the second time, in order to verify the fundamental assumption, a series of experiments were conducted, the objective of which ...

Energy Technology Data Exchange (ETDEWEB)

The gastrointestinal transit was studied in 20 patients with loop transverse colostomies and previously normal colons. This analysis was performed through radiological observation of progression of 20 radiopaque pellets and measurements of its transit time in the various segments of the digestive tract. An evaluation of other related clinical and radiological events was carried out sentimentality's. In order to better understand the influence of the surgical procedure, the study was performed under similar dietary and supportive care conditions and standard radiological studies before and after the re-establishment of transit, thus enabling a comparison with the same individual. (author)

British Library Electronic Table of Contents (United Kingdom)

The atomic mechanism of a glass-to-liquid transition in a monatomic Lennard-Jones (LJ) glass was studied using the molecular dynamics (MD) method. Glassy models were heated up from low temperature at two different heating rates and a glass-to-liquid transition found to occur at the higher heating rate. The temperature dependence of the potential energy, mean-squared-displacements (MSD) of the atoms and the self-intermediate scattering function indicate clearly that a glass transition occurs in the system. The atomic mechanism of the glass-to-liquid transition was investigated by analyzing the spatio-temporal arrangement of liquid-like atoms in the system upon heating. Liquid-like atoms were detected using the Lindemann-melting-like criterion. Upon heating, liquid-like atoms occur at temper...

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The mechanism of chemical poisoning of model heterogeneously catalyzed reactions on transition metal surfaces is studied. Clean Mo(001) surfaces were characterized; results suggest a first-layer contraction of 10% of the bulk interlayer spacing. Characterization of clean Co(0001) surfaces is underway. Decomposition of formic acid on Mo(001) surfaces is being studied. (DLC)

Science.gov (United States)

Page 1. TRANSITIONING DARPA TECHNOLOGY ... Transitioning DARPA Technology JAMESJ.RJCHARDSON DIANE L. LARRNA ...

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The compound GdPd{sub 2}Si, which is reported to order antiferromagnetically at 13 K, has been investigated by heat capacity and electrical resistivity measurement in the presence of external magnetic fields. In contrast to an earlier report, the zero-field heat capacity and resistivity data indicate two magnetic transitions at 13 and 17 K. The external magnetic field substantially influences the resistivity and heat capacity of the compound around the magnetic ordering temperature. The magnetocaloric effect, which is calculated from in-field heat capacity data, is quite large around the magnetic transition temperature. The magnetoresistance is also large near the magnetic ordering temperature. The metamagnetic transition is observed for 10 kOe magnetic field both in magnetocaloric and in magnetoresistance data. The metamagnetic transition strongly influences the magnetocaloric effect and ...

International Nuclear Information System (INIS)

A diode-laser fluorescence experiment was performed in order to study fine-structure transitions between 5"2P states of rubidium atoms colliding with ground-state potassium or caesium atoms. The Rb(5"2P_3_/_2) state was optically excited and the intensity ratio of sensitized to direct fluorescence was measured. (author).

International Nuclear Information System (INIS)

We study the possibility of utilizing the superfluid to Mott-insulator quantum phase transition in an array of quantum well exciton-polariton traps to generate indistinguishable single photons in a massive parallel fashion. By means of analytical and numerical methods, the device operations and system properties are examined using realistic experimental parameters. Such a deterministic, massive parallel generation may find new applications in photonic quantum information processing.

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We report on solid solution CePd[sub 2-x]Mn[sub x]Si[sub 2] which shows an interesting transition of the Ce-ion from magnetism in a Kondo regime to an intermediate valence state coupled with a strongly magnetic 3d sublattice. ((orig.))

UK PubMed Central (United Kingdom)

Conformational transitions of poly(dA-dC).poly(dG-dT), poly(dA-dT).poly(dA-dT), and other alternating purine-pyrimidine DNAs were studied in aqueous ethanol solutions containing molar concentrations...Full Text Available

CERN Document Server

In studying the dynamics of large N_c SU(N_c) gauge theory with fundamental quark flavours in the quenched approximation, we observe a novel phase transition at finite temperature. A quark condensate forms at finite quark mass, and the value of the condensate varies smoothly with the quark mass for generic region in parameter space. At a particular value of the quark mass, there is a finite discontinuity in the condensate's vacuum expectation value, corresponding to a first order phase transition. We study this using holography, the string dual being the geometry of N_c D3--branes at finite temperature, AdS_5-Schwarzschild times S^5, probed by a D7-brane. The D7-brane has topology R^4 times S^3 times S^1, and allowed solutions correspond to either the S^3 or the S^1 shrinking away in the interior of the geometry. The phase transition represents a jump between branches of solutions ...

CERN Document Server

Experimental studies of charmless semileptonic B decays can be broadly categorized into inclusive and exclusive measurements depending on how the final states are treated. The inclusive method measures the decay rate $\\Gamma(B \\to X_u \\ell \

Energy Technology Data Exchange (ETDEWEB)

The federating theme of superconductivity has given rise to a number of experimental studies of point defects in solids as different as transition metals (V, Nb, ...), A-15 compounds (V{sub 3}Si, Nb{sub 3}Ge, ...), or perovskite-like copper oxides. Some of these experiments are presented here. (orig.).

Energy Technology Data Exchange (ETDEWEB)

The L edge absorption of Pd, Ag, Sn, In, and CsI was measured in order to study the density of states and the unoccupied d states. 4 figures. (DLC)

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The relationship between the QRS transition zone of the standard 12-lead ECG and interventricular septum was studied. The position and the angle to the horizontal line of the interventricular septum were evaluated with computed tomography (CT) and compared to the QRS transition zone. The subjects were 36 patients with no cardiovascular diseases. The patients were divided into 3 groups according to the position of QRS transition zone: V{sub 1}-V{sub 2} (8 cases), V{sub 3}-V{sub 4} (21 cases), and V{sub 5}-V{sub 6} (7 cases). The interventricular septum on CT was directed to the anterior chest wall between V{sub 3} and V{sub 4} in all 3 groups. The mean value of the interventricular septal angle did not differ from group to group, 52.1deg for V{sub 1}-V{sub 2} group, 49.8deg for V{sub 3}-V{sub 4} group, and 48.2deg for V{sub 5}-V{sub 6}. It was concluded that the direction of the interventricular septum ...

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This paper describes the results obtained from two large experimental facilities built at Sandia National Laboratories in Albuquerque, NM. FLAME (Flame Acceleration Measurements and Experiments) is a large horizontal rectangular channel designed to study flame acceleration, transition to detonation, simulation of combustion in containment geometries, component heating, and other problems in hydrogen combustion relevant to reactor safety. The Heated Detonation Tube has been designed to study detonations in hydrogen-air-steam mixtures. Both facilities have been in operation for just over a year. 12 figures.

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We decided to investigate first the interaction of hydrogen with the 4d transition-metal series, with the first element being hcp Y. Because of the recent development of soft pseudopotentials, we chose to use the plane wave basis set to carry out the calculation. Since problems had been associated with the slow convergence in transition metals, we first tested the computational methods by studying the structural properties of Y; results were encouraging. We started the calculation of YH{sub x} with hydrogen occupying different interstitial sites.

International Nuclear Information System (INIS)

A study of the #pi#1g/sub 9/2/ orbit size in "8"8Sr, "9"0Zr, and "9"2Mo is presented. The rms radius for the point-proton density is extracted by studying transitions to 8"+ states in these nuclei. The radii are consistently larger than a value determined in a magnetic electron scattering experiment on "9"3Nb. A qualitative discussion of the ground state occupation of the #pi#1g/sub 9/2/ orbit based on the transition amplitudes to the 8"+ states is given.

Energy Technology Data Exchange (ETDEWEB)

The first overtone spectrum of solid parahydrogen with various low ortho impurity levels has been studied in detail using a White-type external multireflection system. For the Q{sub 2{l_arrow}0}(0) transition the authors have observed the fully resolved threefold splitting due to the crystal field effect. Furthermore, the authors have obtained a rich satellite spectrum associated with the transitions Q{sub 2{l_arrow}0}(0) and Q{sub 2{l_arrow}0}(1) at different ortho-H{sub 2} contents revealing information about the ortho-H{sub 2} pair interaction in the second vibrationally excited state of the hydrogen molecule. A preliminary analysis and assignment of these satellite transitions will be presented. Another point of study was the spectral region around 8300 cm{sup -1}, where the double transitions of the type Q{sub 1{l_arrow}0}(n) + Q{sub 1{l_arrow}0}(n{prime}) ...

International Nuclear Information System (INIS)

The evolution of metallic substance atomic structure is studied on temperature variation including crystal heating up to melting points, a crystal- liquid phase transition and initiation of a high-density liquid specific structure. It is marked that heat induced changes of simple metal structure can be described as changes around a natural elementary cell which is common for both a crystal and a liquid and consists of a central atom and Z_1 atoms of the first coordination sphere. On this basis the vacancy model of melting is verified. Concentrations of melting vacancies are determined by coordination numbers in the form of Z_1/(1+Z_1)"2 which are the same for both a crystal and a natural elementary cell. The size of natural elementary cells is in an agreement with that of the coordination sphere featured in the liquid and phase transition statistical theory. Calculated data are given for a number of metals, Cs, Eu, Ni, V ...

International Nuclear Information System (INIS)

The influence of 3d-transition metal impurities on the superconducting properties of the A-15 compounds V_3Si and V_3Ga have been investigated. In the case of V_3Si, the Fe impurities replacing V were found to have a local moment. A compensation effect was found in this case, resulting in a 20KOe increase in the upper critical field at dilute concentrations of Fe. It was demonstrated that long range order V_3Ga possessed higher transition temperature and upper critical field than found hitherto. Investigations on Nb_3Ge/sub 1-x/Ga/sub x/ films obtained by chemical vapor deposition has clearly shown the relation between the transition temperature and structural characteristics. The influence of generalized defects on the superconducting properties in A-15 type Nb_3X compounds has been discussed.

British Library Electronic Table of Contents (United Kingdom)

The n3 and n4 vibrational transitions of CH3 and CD3 isolated in solid parahydrogen were studied by high-resolution infrared spectroscopy. The radicals were produced by in situ UV photolysis of methyl iodides trapped in solid parahydrogen. The observed spectra showed clear rotational fine structures, which were subjected to further splitting due to the electrostatic field of solid parahydrogen. The molecular constants and crystal field parameters of the radicals in solid parahydrogen were determined by analyzing the spectral structures of the n3 and n4 transitions of CD3 by the crystal field theory. The rotational constants of the CD3 radical were found to be only a few percent smaller than those in the gas phase. The determined crystal field parameters indicated significant quantum effect...

International Nuclear Information System (INIS)

Electronic circular dichroism (ECD) of the n-#pi# and #pi# -#pi# transitions of the amide groups in the ultraviolet has become an indispensable tool for qualitative characterization of proteins in solution. Since the existence of such a spectrum (that is, of natural optical activity) comes from the three dimensional interaction of the chromophores in the molecule, CD is exquisitely sensitive to molecular conformation. However, in proteins, the amide transitions available in the near UV are limited in number and are broads and overlapping. Interactions among them yield information about the polymeric backbone, but since such amide electronic excitation are relatively delocalized, the resulting

International Nuclear Information System (INIS)

Phase transformations in TiD_#approx#_0_._7_5 subjected to high-pressure treatment were investigated by simultaneous real-time measurements of neutron diffraction and small-angle neutron scattering. The neutron spectra were taken on heating the samples in temperature ranges 100 to 300 K and 300 to 870 K. A sequence of structural transitions was observed, which involves 7 different phases and intermediate states with hcp, fcc, fco or bcc metal sublattices and hydrogen atoms. 30 refs., 9 figs., 1 tab.

Energy Technology Data Exchange (ETDEWEB)

We discuss the algebraic structure of the generator coordinate method for triaxial quadrupole collective motion. The collective solutions are classified according to the representations of the permutation group of the intrinsic axes. Our method amounts to an approximate angular-momentum projection. We apply it to a study of the spherical-to-deformed-shape transition in light even strontium isotopes {sup 78-88}Sr. We find that triaxial configurations play a significant role in explaining the structure of the transitional isotopes {sup 80-82}Sr. (orig.).

CERN Document Server

We complete the study of smooth $Z_3$-quotients of complete intersection Calabi-Yau threefolds by discussing the six new manifolds that admit free $Z_3$ actions that were discovered discovered recently by Braun. These manifolds were missed in an earlier work and complete the web of smooth $Z_3$-quotients in a nice way. We discuss the transitions between these manifolds and include also the other manifolds of the web. This leads to the conclusion that the web of $Z_3$-free quotients of complete intersection Calabi-Yau threefolds is connected by conifold transitions.

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A simplified relativistic configuration interaction method is used to study the dielectronic satellite transition processes. In this method, the infinite resonant doubly excited states can be calculated, and furthermore, the whole high-n dielectronic satellite transition processes can be treated conveniently by interpolation (rather than extrapolation) in the frame of quantum defect theory. As an example, we calculate the contributions from high-n dielectronic satellites to the K{alpha} resonance line in helium-like iron, and the results are in good agreement with the experimental measurements. (orig.) 39 refs.

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The proposed short wavelength coherent light source driven by the SLAC 3 km linac might be used to induce transitions between nuclear isomeric states. If an isotope were found with energetically adjacent isomeric states, one short-lived and one long-lived, and it were possible to separate and concentrate the long-lived species, and other nuclear and solid-state parameters were favorable, it might be possible to convert sufficient population to the short-lived state to realize [gamma]-ray lasing. Even if the x-ray intensity were insufficient, study of such driven transitions would be quite valuable.

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The properties of the triplet of low-lying states in {sup 101}Mo have been studied through spectroscopy of the {gamma} radation following thermal neutron capture in {sup 100}Mo and {beta}-decay of {sup 101}Nb and through a measurement of the proton angular distributions in the {sup 100}Mo(d, p) reaction with 14 MeV deuteron energy. The half-lives of the 13.5 keV state and the 57.0 keV 5/2{sup +} state have been measured as 226(7) and 133(7) ns, respectively. These values and the quadrupole/dipole mixing ratios of the 13.5 keV and 43.5 keV transitions yield spin and parity 3/2{sup +} for the 13.5 keV level. The E2 components in the 13.5 (3/2{sup +}->1/2{sup +}) and 43.5 keV (5/2{sup +}->3/2{sup +}) transitions are {le} 8x10{sup -4} and 54(9)%, respectively. The possibility of an additional state near to the 57.0 keV level is discussed. IBFM/PTQM calculations, taking into consideration the ...

Energy Technology Data Exchange (ETDEWEB)

In a recent publication [I. Galanakis, K. Ozdog-tilde an, E. Sasiog-tilde lu, B. Aktas, Phys. Rev. B 74 (2006) 140408(R)] we have shown that in the case of CrAs and related transition-metal chalcogenides and pnictides, crystallizing in the zinc-blende structure, the excess of the transition-metal atoms leads to half-metallic ferrimagnetism. The latter property is crucial for spintronic applications with respect to ferromagnets due to the lower stray fields created by these materials. We extend this study to cover the case where the transition-metal atoms sitting at antisites are not identical to the ones in the perfect sites. In Cr-based compounds, the creation of Mn antisites keeps the half-metallic ferrimagnetic character produced also by the Cr antisites. In the case of VAs, Cr and Mn antisites keep the half-metallic character of VAs (contrary to V antisites) due to the larger exchange splitting ...

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Beam-foil spectroscopy techniques have been used to study intercombination transitions in Be-like Fe{sup 22+} and B-like Fe{sup 21+}. The method of time delayed spectroscopy was used to identify the Be-like 2s{sup 2} {sup 1}S{sub 0}-2s2p {sup 3}P{sub 1} and B-like 2s{sup 2}2p {sup 2}P{sub 3/2}-2s2p{sup 2} {sup 4}P{sub 5/2} transitions. Intensity decay curves for these transitions were recorded and level lifetimes were obtained. The latter were found to be 17.5 {+-} 1.5 ns for the Be-like 2s2p {sup 3}P{sub 1} level and 14.8 {+-} 1.0 ns for the B-like 2s2p{sup 2} {sup 4}P{sub 5/2} level. (orig.).

CERN Document Server

This thesis is divided up into five chapters as outlined below. Chapter 1 gives the background to the techniques used in this thesis including X-ray structure determination and ab initio methods. An overview of some recent studies using ab initio methods to study transition metal complexes is also given. Chapter 2 investigates structural trans influence in a number of transition metal and p-block complexes. The database and ab initio studies showed that the classical trans influence model based on Pt(II) chemistry does not always hold. For some systems (eg. d sup 1 sup 0 s sup 0 for Sb sup V and Sn sup I sup V) the cis influence is of similar magnitude to the trans influence. For other systems (d sup 0), the trans influence is not as powerful as usually assumed. Chapter 3 is an investigation into the bridging chloride unit. A database study was performed on ...

International Nuclear Information System (INIS)

The energy level schemes of "1"9"2Os and "1"9"2Pt have been established on the basis of #gamma#-#gamma# coincidence studies using a dual parameter data collection system. Ge(Li) detectors were employed to study the gamma spectra produced in the E.C. and #beta#"- decays of "1"9"2Ir to "1"9"2Os and "1"9"2Pt, respectively. Thirteen new transitions and three new levels at 1,146.95, 1,237.35 and 1,913.76 keV are suggested. Relative intensities from singles measurements, branching ratios, #alpha#(K) and log ft values were calculated and multipolarities, spins and parities deduced. Comparisons are made with predictions of the Interacting Boson Model calculated on the basis of an O(6) to SU(3) transition. (orig.).

CERN Document Server

The confining effect of a spherical substrate inducing anchoring (normal to the surface) of rod-like liquid crystal molecules contained in a thin film spread over it has been investigated with regard to possible changes in the nature of the isotropic-to-nematic phase transition as the sample is cooled. The focus of these Monte Carlo simulations is to study the competing effects of the homeotropic anchoring due to the surface inducing orientational ordering in the radial direction and the inherent uniaxial order promoted by the intermolecular interactions. By adopting entropic sampling procedure, we could investigate this transition with a high temperature precision, and we studied the effect of the surface anchoring strength on the phase diagram for a specifically chosen geometry. We find that there is a threshold anchoring strength of the surface below which uniaxial nematic phase results, and above ...

Energy Technology Data Exchange (ETDEWEB)

A visual study of film boiling using photographic and high speed motion-picture methods was carried out to determine the flow regime transition criteria in the post-CHF region. An idealized inverted annular flow was obtained by introducing a liquid jet of Freon 113 through a nozzle, precisely centered with respect to the internal diameter of the test section, with an annular gas flow. The respective ranges for liquid and gas exit velocities were 0.05 to 0.5 and 0.03 to 7.9 m/s. Nitrogen and helium were used in the study. For the present configuration, there are four basic flow regimes. Beginning from the nozzle exit, there is a smooth, inverted annular flow section with liquid in the core and gas in the annulus; followed by the rough wavy section with an intact liquid core, the agitated and the dispersed flow regimes. For a given liquid jet velocity, the axial extent of each flow regime decreases with increasing gas ...

Energy Technology Data Exchange (ETDEWEB)

This thesis deals with the special electronic properties of the transition-metal aluminides. Following quasicrystals and their approximants it is shown that even materials with small elementary cells exhibit the same surprising effects. So among the transition-metal aluminides also semi-metallic and semiconducting compounds exist, although if they consist of classic-metallic components like Fe, Al, or Cr. These properties are furthermore coupled with a deep pseusogap respectively gap in the density of states and strongly covalent bonds. Bonds are described in this thesis by two eseential properties. First by the bond charge and second by the energetic effect of the bond. It results that in the caes of semiconducting transition-metal aluminides both a saturation of certain bonds and a bond-antibond alteration in the Fermi level is present. By the analysis of the near-order in form of the so-calles coordination polyeders it ...

International Nuclear Information System (INIS)

The isostructural #gamma#-#alpha# phase transition of Ce which occurs at 8 kbar has been studied by means of fully self-consistent (non-muffin-tin potential) linearized-augmented-plane-wave energy band calculations carried out for five different values of the lattice constant. In contradiction to the 4f electron promotional model of the transition, the results yield essentially one 4f electron to be occupied in each phase but with the 4f wave function somewhat less localized, and therefore more bandlike, in the ''collapsed'' #alpha# phase. A singly occupied 4f state is shown to be consistent with the available experimental data. These results strongly support the picture of a 4f localized bold-arrow-left-right itinerant transition at the #gamma#-#alpha# transition and conflict with the promotional model in which some fraction of 4f electrons are transferred to the sd conduction ...

International Nuclear Information System (INIS)

A visual study of film boiling is carried out to determine the flow regime transition in the post-CHF region. An idealized inverted annular flow is obtained by introducing a liquid jet of Freon 113 through a nozzle, precisely centered with respect to the internal diameter of the test section, with an annular gas flow. The respective ranges for liquid and gas velocities are 0.05-0.5 and 0.03-8.2 m s"-"1. Nitrogen and helium are used in the study. For the present configuration, there are four flow regimes; namely, the smooth inverted annular flow-section, the rough wavy, agitated and dispersed flow regimes. (author).

Energy Technology Data Exchange (ETDEWEB)

The pressure dependence of the photoluminescence (PL) transition associated with the fundamental band gap of ZnO nanowires has been studied at pressures up to 15 GPa. ZnO nanowires are found to have a higher structural phase transition pressure around 12 GPa as compared to 9.0 GPa for bulk ZnO. The pressure-induced energy shift of the near band-edge luminescence emission yields a linear pressure coefficient of 29.6 meV/GPa with a small sublinear term of -0.43 meV/GPa{sup 2}. An effective hydrostatic deformation potential -3.97 eV for the direct band gap of the ZnO nanowires is derived from the result.

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A study of the ..pi..1g/sub 9/2/ orbit size in /sup 88/Sr, /sup 90/Zr, and /sup 92/Mo is presented. The rms radius for the point-proton density is extracted by studying transitions to 8/sup +/ states in these nuclei. The radii are consistently larger than a value determined in a magnetic electron scattering experiment on /sup 93/Nb. A qualitative discussion of the ground state occupation of the ..pi..1g/sub 9/2/ orbit based on the transition amplitudes to the 8/sup +/ states is given.

CERN Document Server

We present several recent results from the BaBar collaboration in the areas of initial state radiation physics and transition form factors. An updated study of the processes e+e- -> K+K-pi+pi- and e+e- -> K+K-pi0pi0 provides an improved understanding of the Y(2175) meson. A very precise study of the process e+e- -> pi+pi- improves the precision on the calculated anomalous magnetic moment of the muon and provides by far the best information on excited rho states. Our previous measurements of the timelike transition form factors (TFF) of the eta and eta' mesons at Q^2=112 GeV^2, combined with new measurements of the their spacelike TFFs and those of the pi0 and eta_c mesons, provide powerful tests of QCD and models of the distribution amplitudes of quarks inside these mesons. The eta_c TFF shows the expected behavior over the Q^2 range 1-50 GeV^2, and we are sensitive to next-to-leading-order QCD ...

International Nuclear Information System (INIS)

Axial offset anomaly (AOA) is caused by the deposition of crud on the fuel cladding of a PWR. When significant levels of crud build up on the cladding, boron can accumulate in the pores of the crud as a concentrated solution or solid phase, and cause the flux depression. Numerous studies have been conducted on the primary water chemistry to reduce the amount of crud in the primary circuit to avoid radioactivity buildup and unexpected power transition in the plant. However, experiments on the crud are restricted in the laboratory because the crud is a highly radioactive material. The objective of this study is to develop a test method for simulating the deposition of crud in a nuclear power plant

International Nuclear Information System (INIS)

The nuclear shapes of transitional Mo isotopes are calculated by means of a model based on the cranking approximation and the Strutinksy method. The recent experimental results of the high-spin spectroscopy and lifetime measurement of "8"7Mo are studied in detail and explained by the evolution of the #gamma#-deformation with the quasiparticle configurations. The shape calculations with the modified-harmonic-oscillator potential give a critical neutron number N #>=# 47 for the spherical shape of the Mo isotopes. (orig.).

International Nuclear Information System (INIS)

The 142Nd and 143Nd nucleus excited states have been studied using the "1"4"2","1"4"3Nd(p,p') and "1"4"0Ce(#alpha#,n)"1"4"3Nd reactions. The energy level schemes were determined as well as spectroscopic information about spin, parity and multipolarity of electromagnetic transitions. 54 refs, 25 figs, 9 tabs.

International Nuclear Information System (INIS)

The alloy of Ti-Al-Mo-V-Cr system is studied for its structure in a strained state and specific features of #beta#-#alpha# transformation in a #beta#-matrix and deformation twins on ageing. It is determined that preliminary deformation initiates the decomposition of solid solution on aging. In a metastable #beta#-titanium alloy the substructure of deformation twins is shown to vary essentially with aluminium and chromium partial substitution for molybdenum and vanadium

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To simulate the effects of the breakup channel on rearrangement amplitudes, the conventional coupled-reaction-channel (CRC) expansion is augmented by pseudoreaction channels. The construction of the projector for the extended CRC space is discussed, and transition-operator equations on this space are given. By solving the full and post-approximation forms of the CRC equations for a model three-particle problem, the crucial role played by the nonorthogonality terms is demonstrated.

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Metastable nuclear isomers are central to the study of nuclear structure and their energy storage capability has suggested a variety of applications. The feasibility of applications depends sensitively on the efficiency of any process that can deplete an isomer upon demand. This work surveys how State-of-the-art in nuclear level and transition data impacts the search for induced energy release from isomers using recent advances in experimental techniques.

Energy Technology Data Exchange (ETDEWEB)

Distribution of Lipiodol within hepatic tumor was evaluated using serial computed tomography. Imagistic Lipiodol transition into the tumor via hepatic artery was slower than that of water soluble contrast medium, spreading to central part first and turn to peripheral part of the tumor. This method was thought to be useful to clarify Lipiodol distribution in hepatic tumor and to decide the method or necessity of additional trans-arterial therapy. (author).

Energy Technology Data Exchange (ETDEWEB)

The method of double microwave--radio-frequency resonance has been used to obtain spectra of the 2/sub 11/reverse arrow2/sub 12/ and 3/sub 21/reverse arrow3/sub 22/ transitions in HCOOD, DCOOH, and HCOOH molecules. The constants of the quadrupole bond of the deuterons have been determined, magnetic interactions being taken into acocunt. A comparison with results of previous studies is given.

Energy Technology Data Exchange (ETDEWEB)

Properties of highly correlated electrons, such as heavy fermion compounds, metal-insulator transitions, one-dimensional conductors and systems of restricted dimensionality are studied theoretically. The main focus is on Kondo insulators and impurity bands due to Kondo holes, the low-temperature magnetoresistivity of heavy fermion alloys, the n-channel Kondo problem, mesoscopic systems and one-dimensional conductors.

Energy Technology Data Exchange (ETDEWEB)

3d occupation numbers of the transition elements corresponding to various types of atomic configurations are calculated by means of the linear muffin-tin orbital (LMTO) method. This data is used with the multiconfiguration Dirac-Fock (MCDF) X-ray intensity ratios to estimate the electron populations of the 3d metals in alloys.

International Nuclear Information System (INIS)

Autoionizing and Auger transitions in atomic manganese and samarium have been experimentally investigated by observation of the ejected electrons in the energy region 0 to 40 eV following electron impact excitation with incident beams in the energy range 15-500 eV. Seventy-four spectral features are tabulated for manganese and a number of new assignments have been made based on pseudo-relativistic Hartree-Fock calculations and quantum defect analysis. A similar study of samarium reveals only a number of broad features in the ejected-electron energy range 8-10 eV. Three features have been observed consistently in the ejected-electron spectrum of samarium and assigned by comparison with previous work. (author).

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Over 100 candidates were examined, including commercial materials and many that were synthesized in house. The mixed oxides were based on Ti, V, Nb, Cr, Mo, W, Mn, Fe, Co, Ni, and Cu doped with other transition metals. A number of individual (single-metal) oxides were included for comparison. The candidates were tested in single cells with Li(Si) anodes and separators based on LiCl-KCl eutectic. Screening was done under constant-current conditions at current densities of 125 me/cm{sup 2} and, to a lesser extent, 50 me/cm{sup 2} at 500 C. Relative performance and limitations of the oxide cathodes are discussed.

CERN Document Server

A recurrent idea in the study of complex systems is that optimal information processing is to be found near bifurcation points or phase transitions. However, this heuristic hypothesis has few (if any) concrete realizations where a standard and biologically relevant quantity is optimized at criticality. Here we give a clear example of such a phenomenon: a network of excitable elements has its sensitivity and dynamic range maximized at the critical point of a non-equilibrium phase transition. Our results are compatible with the essential role of gap junctions in olfactory glomeruli and retinal ganglionar cell output. Synchronization and global oscillations also appear in the network dynamics. We propose that the main functional role of electrical coupling is to provide an enhancement of dynamic range, therefore allowing the coding of information spanning several orders of magnitude. The mechanism could provide a microscopic ...

British Library Electronic Table of Contents (United Kingdom)

A study of elliptical flow is carried out for different mass asymmetries of colliding nuclei using the reactions of Formula Not Shown ( Formula Not Shown ), Formula Not Shown ( Formula Not Shown ) and Formula Not Shown ( Formula Not Shown ). The present reactions are simulated at incident energies between 50 and 250 MeV/nucleon within the framework of isospin-dependent quantum molecular dynamics model. For the present analysis, total mass of colliding pairs is kept fixed and mass asymmetry is varied between 0.3 and 0.7. The elliptical flow shows a transition from in-plane to out-of-plane in the mid rapidity region with incident energy. The transition energy is found to increase with the mass asymmetry for light charged particles. A good agreement is obtained with experimental measurements.

British Library Electronic Table of Contents (United Kingdom)

The crystal structure of Ca2RuD6 has been determined by neutron powder diffraction: space group Fm3m, K2PtCl6 structure, as found for other hexahydride salts of group 8 metals with alkaline earth or lanthanide counter ions. No structural phase transition was observed between 340K and 50K. The deuterium nuclear quadrupole coupling constant, 54.7kHz, leads to an ionic character of the Ru-D bond of 76%. The known trends in the behaviour of A2MH6 salts are interpreted in terms of the ionization energies of the cation and the central metal atom.

International Nuclear Information System (INIS)

The activities "1"0"1Mo and "1"0"1Tc produced from neutron capture by natural Mo were chemically separated and studied using Ge(Li) #gamma#-ray detectors. Out of 185 transitions observed in the decay of "1"0"1Mo, 170 were assigned to 44 excited levels in "1"0"1Tc. For the decay of "1"0"1Tc, 26 of 27 transitions were placed among 10 excited levels in "1"0"1Ru. The interpretation of the "1"0"1Tc level scheme using the shell-model approach is not satisfactory even for a five-particle calculation. Systematics of odd-A level structures in the region of A=101 indicate that the level structure of "1"0"1Tc could be due partly to the onset of collective effects.

CERN Document Server

We present a single solid-state laser system to cool, coherently manipulate and detect $^{25}$Mg$^+$ ions. Coherent manipulation is accomplished by coupling two hyperfine ground state levels using a pair of far-detuned Raman laser beams. Resonant light for Doppler cooling and detection is derived from the same laser source by means of an electro-optic modulator, generating a sideband which is resonant with the atomic transition. We demonstrate ground-state cooling of one of the vibrational modes of the ion in the trap using resolved-sideband cooling. The cooling performance is studied and discussed by observing the temporal evolution of Raman-stimulated sideband transitions. The setup is a major simplification over existing state-of-the-art systems, typically involving up to three separate laser sources.

KoreaScience (Korea)

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We argue that closed string tachyons drive two spacetime topology changing transitions--loss of genus in a Riemann surface and separation of a Riemann surface into two components. The tachyons of interest are localized versions of Scherk-Schwarz winding string tachyons arising on Riemann surfaces in regions of moduli space where string-scale tubes develop. Spacetime and world-sheet renormalization group analyses provide strong evidence that the decay of these tachyons removes a portion of the spacetime, splitting the tube into two pieces. We address the fate of the gauge fields and charges lost in the process, generalize it to situations with weak flux backgrounds, and use this process to study the type 0 tachyon, providing further evidence that its decay drives the theory sub-critical. Finally, we discuss the time-dependent dynamics of this topology-changing transition and find that it can occur more efficiently than ...

International Nuclear Information System (INIS)

The #gamma#-ray spectrum emitted after thermal neutron capture in "8"7Sr was studied at the ILL high flux reactor with pair- and intrinsic Ge-spectrometers. 661 transitions were assigned to the reaction "8"7Sr(n,#gamma#)"8"8Sr and 205 of them were placed into a "8"8Sr level scheme of 47 levels. This represents 88% of the observed intensity. The level energies were determined with a precision of better than 22 ppm; the neutron binding energy was determined as 11 112.69 (22) keV. To aid the analysis high resolution particle spectra of the reaction "8"7Sr(d,p)"8"8Sr were measured at 20 MeV deuteron energy with the Munich Q3D spectrometer. 85 states were observed with this reaction. The data helped to establish newly found levels and to differentiate between primary and secondary transitions in the (n,#gamma#) data. The observed level densities and primary transition strengths are compared with statistical ...

CERN Document Server

One of the most active areas of physics in the last decades has been that of critical phenomena, and Monte Carlo simulations have played an important role as a guide for the validation and prediction of system properties close to the critical points. The kind of phase transitions occurring for the Betts lattice (lattice constructed removing 1/7 of the sites from the triangular lattice) have been studied before with the Potts model for the values q=3, ferromagnetic and antiferromagnetic regime. Here, we add up to this research line the ferromagnetic case for q=4 and 5. In the first case, the critical exponents are estimated for the second order transition, whereas for the latter case the histogram method is applied for the occurring first order transition. Additionally, Domany's Monte Carlo based clustering technique mainly used to group genes similar in their expression levels is reviewed. Finally, a ...

CERN Document Server

We consider the role of quantum effects in the transfer of hyrogen-like species in enzyme-catalysed reactions. This study is stimulated by claims that the observed magnitude and temperature dependence of kinetic isotope effects imply that quantum tunneling below the energy barrier associated with the transition state significantly enhances the reaction rate in many enzymes. We use a path integral approach which provides a general framework to understand tunneling in a quantum system which interacts with an environment at non-zero temperature. Here the quantum system is the active site of the enzyme and the environment is the surrounding protein and water. Tunneling well below the barrier only occurs for temperatures less than a temperature $T_0$ which is determined by the curvature of potential energy surface near the top of the barrier. We argue that for most enzymes this temperature is less than room temperature. For physically reasonable ...

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The polarization of extracted SATURNE II proton beam as a function of different ion source configurations was studied. Two distinct experiments were necessary for this purpose. In the first one, the left-right instrumental asymmetry of the beam polarimeter was determined using an unpolarized beam. In the second one this correction factor was applied to asymmetries measured with the beam from the polarized ion source in all polarization states. The measurements were carried out at the proton beam kinetic energy 0.80 GeV, where the pp-elastic scattering analyzing power is near its maximum. The results confirmed that the two so-called ``unpolarized states`` of the source were polarized to several percent, whereas the absolute values of the beam polarizations in the so-called ``polarized states`` were equal and opposite. It was observed that the hexapole lens of the ion source produced beam polarization in the absence of any transition. The beam ...

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Eu 4f electronic structures of a temperature-induced valence transition system EuPd{sub 2}Si{sub 2} have been investigated by bulk-sensitive high-resolution photoemission spectroscopy at temperatures from 20 to 300 K. The bulk Eu{sup 2+} 4f component is definitely distinguished from two surface Eu{sup 2+} 4f components. The changes in the spectral intensity of the bulk Eu{sup 2+} and Eu{sup 3+} 4f configurations and in the energy separation between these states are observed in the temperature dependent photoemission spectra. These temperature dependences are related to the valence transition of EuPd{sub 2}Si{sub 2}. The Eu mean valence is evaluated to be 2.75{+-}0.03 at 20 K and 2.30{+-}0.05 at 300 K. These values are in good agreement with those evaluated from Moessbauer and Eu L{sub III}-edge X-ray absorption measurements.

International Nuclear Information System (INIS)

... electron reactions electrons excitation inelastic scattering m1-transitions proton

Science.gov (United States)

We discuss how magnetic phenomena affect superconductivity in simple metals, transition metals and alloys thereof, and dilute Rare-Earth alloys. It is shown both qualitatively and quantitatively that superconductors are sensitive probes for studying itinerant spin excitations, local spin excitations associated with nearly magnetic impurities, the effect of the atomic environment on the stability of local magnetic moments, and the nature of the spin order in Rare-Earth alloys. Also, we discuss how magnetic impurities can be used to study the electronic configuration which is responsible for superconductivity in Laves-phase crystals like A-15 compounds and ..beta..-W crystals, for example.

CERN Document Server

We study the energetics of island formation in Stranski-Krastanow growth within a parameter-free approach. It is shown that an optimum island size exists for a given coverage and island density if changes in the wetting layer morphology after the 3D transition are properly taken into account. Our approach reproduces well the experimental island size dependence on coverage, and indicates that the critical layer thickness depends on growth conditions. The present study provides a new explanation for the (frequently found) rather narrow size distribution of self-assembled coherent islands.

International Nuclear Information System (INIS)

The results of the study of dimensionally dependent fluorescence of boron difluoride ?-diketonates of general formula (R1COCHCOR2)BF2 are presented. The fact that for most of the compounds studied a noticeable hypsochrome shift of the luminescence band maximum is characteristic during transition from bulk crystals to microcrystals was detected. However, for boron difluoride dibenzoylmethanate having a unique supramolecular structure, a bathochromic shift of luminescence due to the crustal size reduction is observed. The dimensionally dependent luminescence properties of the complexes have been analyzed within the exciton mechanism

Science.gov (United States)

Critical power at boiling transition is an important factor in a boiling water reactor (BWR) fuel bundle design. Boiling transition under high quality accounts for dryout as the result of the complete disappearance of film flow on a fuel rod. This liquid film vanishing process can be calculated by the liquid film model, which takes into account the evaporation due to heat from the rod surface, liquid film entrainment by steam flow, and liquid droplet deposition. It is known that spacers affect liquid film entrainment and liquid droplet deposition, so the detailed study of spacer effects on hydrodynamic characteristics is necessary for critical power prediction based on the film flow model. Many studies have been conducted to examine spacer effects on liquid film flow. However, most of them are restricted to simple test sections such as a rectangular conduit. There are a few reports on fuel bundle ...

International Nuclear Information System (INIS)

High-spin states (I < or approx. 50(#Planck constant#/2#pi#)) of the odd-odd nucleus "1"7"0Ta have been investigated with the "1"2"4Sn("5"1V,5n) reaction. The resolving power of Gammasphere has allowed for the observation of eleven rotational bands (eight of which are new) and over 430 transitions (#approx#350 of which are new) in this nucleus. Many interband transitions have been observed such that the relative spins and excitation energies of the 11 bands have been established. This is an unusual circumstance in an odd-odd study. Configurations have been assigned to most of these bands based upon features such as alignment properties, band crossings, B(M1)/B(E2) ratios, and the additivity of Routhians. A systematic study of the frequency at which normal signature ordering occurs in the #pi#h_9_/_2#nu#i_1_3_/_2 band has been performed and it is found that its trend is opposite to that observed in ...

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A crucial step in human breast cancer progression is the acquisition of invasiveness. There is a distinct lack of human cell culture models to study the transition from pre-invasive to invasive phenotype as it may occur 'spontaneously' in vivo. To delineate molecular alterations important for this transition, we isolated human breast epithelial cell lines that showed partial loss of tissue polarity in three-dimensional reconstituted-basement membrane cultures. These cells remained non-invasive; however, unlike their non-malignant counterparts, they exhibited a high propensity to acquire invasiveness through basement membrane in culture. The genomic aberrations and gene expression profiles of the cells in this model showed a high degree of similarity to primary breast tumor profiles. The xenograft tumors formed by the cell lines in three different microenvironments in nude mice displayed metaplastic ...

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LiNiO{sub 2} is one of the most promising material for positive electrodes of lithium-ion batteries. However, its behaviour during cycling and the existence of several phase transitions induced by the lithium ions de-intercalation process has not been explained so far. A transition electron microscopy study of various Li{sub x}NiO{sub 2} (0.25study is in agreement with the potential levels of the electrochemical cycle and with the polarization phenomena during cycling. Abstract only. (J.S.)

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The deexcitation of quasi-projectiles (QP) released in binary Au on Au collisions as been studied from 60 to 100 MeV/u. Bimodality between two different decay patterns has been observed for intermediate violence collisions. The main experimental result is that the system jumps from one mode to the other on a narrow range of energy deposit and/or impact parameter. The sorting of the events (according to the violence of the collision) has been provided by the perpendicular energy of the light charged particles emitted on the quasi-target side. Such a sorting prevents spurious autocorrelation effects between the sorting variable and the observed mechanism. The two modes of the QP decay correspond on the one side to residue or fission fragments production, and on the other side to the multifragmentation channel. A detailed study has been performed in order to try to establish the origin of the observed bimodality in disentangling dynamical or ...

British Library Electronic Table of Contents (United Kingdom)

Transverse glow discharges in supersonic air and methane flows are studied both experimentally and theoretically. The experiments show that a diffuse volume discharge filling the whole cross section of the flow can easily be initiated in air, whereas a diffuse discharge in a methane flow shows a tendency to transition into a constricted mode. The electron transport coefficients (mobility and drift velocity) and the kinetic coefficients (such as collisional excitation rates of the vibrational levels of a methane molecule, as well as dissociation and ionization rates) are calculated by numerically solving the Boltzmann equation for the electron energy distribution function. The calculated coefficients are used to estimate the parameters of the plasma and the electric field in the positive co...

British Library Electronic Table of Contents (United Kingdom)

Abstract Although neonatology, the study of the newborn, is well established in medical science, psychological research on the newborn is relatively scarce. Can we justify this period as a distinct stage of human development in Psychology? This introductory article considers the unique characteristics of the neonatal period, the impact of the transition to extrauterine life, including the impact of birth itself, and the stages of brain development that characterize this period. It presents evidence of an intentional, intersubjective neonate, and uses behavioural and neuroscientific evidence to argue that the neonate's early social preferences and responses indicate a unique, sensitive, experience-expectant stage of development. The authors of this issue agree in proposing that the newborn ...

International Nuclear Information System (INIS)

A study of stress corrosion cracking susceptibility of Zircaloy-4 in chloride-containing aqueous methanolic media is presented. The influence of water content is investigated in the 5-100 vol. % water range. The dependence of stress corrosion cracking on potential is evidenced. A close correlation is established with pitting susceptibility determined by a statistical analysis of induction times. A correlation with the repassivation potential is observed in the water-rich solutions. In the low water content solutions, two repassivation curves are determined according to the experimental technique. Pit morphology and fractography show a transition from aqueous to organic media. (author).

International Nuclear Information System (INIS)

Photoluminescence spectra for solutions containing Sm"3"+ isotope ions in heavy and normal water were studied in the wave length #lambda# = 500-700 nm and for absorption spectra and photoluminescence excitation spectra within the range of #lambda# = 260-600 nm. Differences in molar extinction coefficients for "1"4"4Sm"3"+ and "1"5"4Sm"3"+ were established both in the solutions with D_2O and by transition from the solutions with D_2O to the solutions with H_2O. New possible causes of the identified effects are discussed

CERN Document Server

We study the production of gravitational waves from cosmic domain walls created during phase transition in the early universe. We investigate the process of formation and evolution of domain walls by running three dimensional lattice simulations. If we introduce an approximate discrete symmetry, walls become metastable and finally disappear. We calculate the spectrum of gravitational waves produced by collapsing metastable domain walls. Extrapolating the numerical results, we find the signal of gravitational waves produced by domain walls whose energy scale is around 10^10-10^12GeV will be observable in the next generation gravitational wave interferometers.

British Library Electronic Table of Contents (United Kingdom)

This paper deals with dynamical behavior of a nonlinear suspension system. We examine chaotic motion in a vehicle suspension system with hysteretic nonlinearity excited by a road profile. A one degree of freedom quarter-car model with nonsymmetric potential is investigated. The Melnikov criterion is used to study the intersection of stable and unstable manifolds and transition to chaos for the system. The condition for chaotic vibration is found using a Melnikov function. Chaotic motion also is indicated by a bifurcation diagram and Lyapunov exponents.

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Neutron deficient nuclei with mass numbers A {approx} 90 and 40 {<=} Z {<=} 44 have been studied making use of the Osiris and Nordball spectrometers. The high spin states of these nuclei and their electromagnetic decay properties are compared to shell model calculations based on the core {sup 88}Sr and using different parametrizations of the residual interaction. The dependence of the mean square deviations of experimental and theoretical level energies, branching ratios, and transition probabilities on the neutron numbers N = 46-50 and the validity of seniority as a good quantum number are discussed. (orig.).

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Chemical effects of L X-ray intensity ratios in niobium and molybdenum compounds were studied by electron and proton bombardments. L{sub {gamma}1} X-rays which involve transition of 4d electrons of the valence shell were found to be sensitive to the chemical environment. The L{sub {gamma}1}/L{sub {beta}1} X-ray intensity ratio increased with an increase of the 4d electron occupation of niobium or molybdenum in niobium or molybdenum compounds, showing that the chemical effects can be ascribed to the 4d electron behavior of the metallic atom in its compounds. (orig.).

International Nuclear Information System (INIS)

The effect of yttrium substitution at the lanthanum site on the superconducting properties of La_1_-_xY_xO_0_._9F_0_._1FeAs ('x' = 0, 0.10, 0.20, 0.30, 0.50 and 0.60) oxypnictides has been studied. Powder X-ray diffraction studies confirm single phases till x = 0.1 beyond which minor amount of Y_2O_3 is observed. The temperature dependence of resistivity measurements confirm the superconducting transition temperature (T_c) of 34.8 (#+-#0.05) K and corresponding Meissner transition at 34.3 K in the 'x' = 0.3 composition which is higher than that reported for the parent phase (LaO_0_._9F_0_._1FeAs (T_c = 28 K)). Further increase in the concentration of yttrium leads to broadening and suppression of the superconducting transition. The value of H_c_2 at zero temperature is estimated to be about 60.5 T. The Seebeck coefficient (S) shows a negative sign indicating that the major ...

International Nuclear Information System (INIS)

The extraction-spectrophotometric method has been used to study lanthanoid ion complexing (Pr, Nd, Ho and Er) with antipyrine (Ant) and salicylic acid (Sal). The component relationship in different-ligand compounds Ln:Aut:Sal=2:3:6 and solvate number equal to 5 are determined; molar extinction coefficients of binary and different-ligand compounds are calculated. Oscillator strengths of absorption bands corresponding to supersensitive transitions of neodymium, holmium, erbium and some most intensive praseodymium bands are calculated. The study of IR spectra of investigated compounds allows to conclude on formation of coordination bonds of the central atom with the antipyrine molecule through the oxygen of the carbonyl group as well as on carboxyl group hydrogen substitution for metal and formation of coordination bond with OH group in salicylic acid molecules.

British Library Electronic Table of Contents (United Kingdom)

The present investigation focuses on the study of design parameters for a generic fan-in-wing configuration. The objective is to evaluate the performance of a fan-in-wing concept in a Short-Take-Off and Landing situation. The results presented are also of interest for transition between hover and a wing-sustained flight for a Vertical Take Off and Landing concept. Steady Reynolds Averaged Navier-Stokes computations using an actuator disk technique are performed. The results show a good agreement with experimental data and simulation results obtained in previous investigations for a generic wind tunnel model. A parametric study is conducted for a more realistic wing planform. For a single fan installed in the wing, the streamwise and spanwise influence on the wing aerodynamics is studied. I...

International Nuclear Information System (INIS)

The dynamics of a cluster-type system formed by constant total number of molecules, M, is studied when clusters change their sizes by nearest-size transitions (the Szilard model) with time-dependent boundary conditions and non-zero initial cluster size distribution. We compare these results to those reported previously, when non-stationary cluster size distribution was considered under the condition that only monomers are present in the system at the initial moment t=0, and describe the effect of arbitrary pre-existing clusters on the time evolution of the interacting clusters with different sizes, n. The average group size problem is also solved, and the process of relaxation in the system is studied. authors)

UK PubMed Central (United Kingdom)

In the American educational system, school transitions are frequent and predictable, but they can disrupt student functioning across developmental domains. How students experience school transitions...Full Text Available

CERN Document Server

The phase transition is a performance measure of the sparsity-undersampling tradeoff in compressed sensing (CS). This letter reports, for the first time, the existence of an exact phase transition for the $\\ell_1$ minimization approach to the complex valued CS problem. This discovery is not only a complementary result to the known phase transition of the real valued CS but also shows considerable superiority of the phase transition of complex valued CS over that of the real valued CS. The results are obtained by extending the recently developed ONE-L1 algorithms to complex valued CS and applying their optimal and iterative solutions to empirically evaluate the phase transition.

UK PubMed Central (United Kingdom)

This paper examines theoretically the effects that restraints on the tertiary structure of a superhelical DNA domain exert on the energetics of linking and the onset of conformational transitions. The...Full Text Available

International Nuclear Information System (INIS)

Apart from conventional phase transitions driven by the thermal effects, quantum phase transitions generated by quantum fluctuations have their own mechanisms that are reflected in critical phenomena. Quantum phase transitions have an origin from spontaneous symmetry breaking commonly to thermal phase transitions. Even in this case, inherent quantum fluctuations substantially modify and yield new aspects. Quantum phase transitions have, however, another mechanism caused by topology changes, which gives completely new characters. Recently, a mechanism which connects these two has been found. Proimities from first-order transitions and phase separatins as well as from multiphase coexistence also generate characteristic and unconventional quantum criticalities. Understanding novel quantum criticalities offers a firm basis of recent active researches on fields such ...

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This report describes the evaluation results for new Orion VII buses at NYCT with CNG propulsion and new hybrid propulsion.

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This document is the annual update of the FFTF and Advanced Reactors Transition Program Resource Loaded Schedule for FY 2002 using current project direction and authorized funding levels

Wastenet

Pages 184-197: Understanding Personal Change in a Women’s Faith-Based Transitional Center/title link ...titleUnderstanding Personal Change in a Women’s Faith-Based Transitional Center/dc:title

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Mixed-convection phenomena can occur within liquid-dominated geothermal reservoirs due to interactions of injected flows, or ground-water flows, with the buoyancy-induced fluid motion. This problem was studied experimentally and numerically for the case of opposing flows about a vertical heat source in a liquid-saturated porous medium. The ratio of the Rayleigh number (Ra) to the Peclet number (Pe) was identified as the nondimensional parameter which characterizes the relative influence of buoyancy-driven to pressure-gradient-driven fluid motion. The transition from mixed to forced convection was numerically determined to be (Ra/Pe) approx. = -0.5, where the minus sign denotes superimposed downflow. Agreement between measured and predicted thermal-field results showed that the finite-element code of Gartling and Hickox (1982 a,b) can be used to model low-temperature (single-phase) geothermal reservoirs throughout the natural, mixed, and forced ...

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Mixed-conducting Sr-Fe-Co oxides have potential applications in dense ceramic membranes for high-purity oxygen separation and/or methane conversion to produce syngas (CO + H{sub 2}), because of their combined high electronic/ionic conductivity and significant oxygen permeability. We studied the crystal structure and microstructure of the system in X-ray diffraction experiments and by using scanning electron microscopy, respectively. Thermogravimetric analysis was conducted on the SrFeCo{sub 0.5}O{sub x} sample in environments of various oxygen partial pressures (pO{sub 2}). Conductivity increased while weight decreased with increasing temperature. Activation energy decreased while conductivity increased with increasing pO{sub 2}. The pO{sub 2}-dependent conducting behavior of the SrFeCo{sub 0.5}O{sub x} system can be understood by considering the trivalent-to-divalent transition of transition-metal ions.

British Library Electronic Table of Contents (United Kingdom)

Abstract Toughening amplification of the neat poly(vinyl chloride) (PVC) and its reinforced version containing 25 phr of the cellulose acetate (CA)-compatibilized starch using methyl methacrylate-butadiene-styrene (MBS) core-shell particles was studied. The room temperature measured impact strength of the PVC showed mild increase up to 10 wt % with the addition of MBS particles. Then, the toughness enhanced discontinuously to super-tough plateau regime. The room temperature measured impact strength of PVC containing 20 phr of MBS particles, however, was reduced by as much as 95% when it was filled with 25 phr of the CA-compatibilized starch. In addition, the brittle-ductile transition (BDT) of the toughened PVC increased from 0 to 60 C because of its reinforcement, even though the matrix n...

International Nuclear Information System (INIS)

We report the results of a linearized augmented-plane-wave calculation of the electronic structure of fcc La at three lattice constants corresponding to ambient pressure, 50, and 120 kbars. The Kohn-Sham-Gaspar approximation for exchange and correlation is used and the potential is allowed a fully non-muffin-tin form. The f bands lie approx.2--2.5 eV above the Fermi level and are approx.1 eV wide, resulting in a very small (0.05 electrons) localized f occupation. Under pressure the f bands rise and broaden appreciably, resulting in only a slight increase in f occupation. The rigid-muffin-tin approximation for the electron-phonon interaction lambda overestimates the superconducting transition temperature T/sub c/ by 40%, but we find that the drastic increase in T/sub c/ under pressure can be attributed primarily to changes in the electronic stiffness eta. Structural transitions which occur at 25 and 53 kbars may be related to changes in ...

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Composites based on pure gypsum and polyester-styrene resin have been prepared using various doses of gamma radiation. Some physical properties of the prepared composites and the influence of irradiation dose on it have been studied as: compression strength, hardness, thermal decomposition temperature in nitrogen or oxygen, and the change in weight in aqueous solutions with different pH values. The glass transition temperature of the pure polymer and the composites increases with increasing the irradiation dose up to a plateau, and the glass transition temperature of the pure polymer is lower than that of the composites. The irradiation dose does not seem to affect the decomposition temperature of the pure polymer or the composites significantly and the decomposition temperature in presence of nitrogen is higher than that in presence of oxygen. Increasing the irradiation dose leads to an enhancement of the compression ...

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The ultrafine fibers based on the composites of polyethylene terephthalate (PET) and a series of fatty acids, lauric acid (LA), myristic acid (MA), palmitic acid (PA), and stearic acid (SA), were prepared successfully via electrospinning as form-stable phase change materials (PCMs). The morphology and thermal properties of the composite fibers were studied by field emission scanning electron microscopy (FE-SEM) and differential scanning calorimetry (DSC), respectively. It was found that the average fiber diameter increased generally with the content of fatty acid (LA) in the LA/PET composite fibers. The fibers with the low mass ratio maintained cylindrical shape with smooth surface while the quality became worse when the mass ratio is too high (more than 100/100). Moreover, the latent heat of the composite fibers increased with the increase of LA content and the phase transition temperature of the fibers have no obvious variations compared with ...

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We report the results of neutron-diffraction experiments on CeM/sub 2/Si/sub 2/ (M = Ag,Au,Pd,Rh) which were performed to explore the role of valence fluctuations and 4f hybridization in the magnetic ordering of cerium compounds. All four order antiferromagnetically, the first three exhibiting structures consisting of ferromagnetic layers with moments perpendicular to the layers, which are believed to be characteristic of 4f-4f interactions mediated through hybridization with conduction electrons. CePd/sub 2/Si/sub 2/ has an anomalously small moment (0.62..mu../sub B/) in the ordered state. CeAg/sub 2/Si/sub 2/ exhibits an incommensurate longitudinal, static magnetization wave with moment and propagation direction along the a axis. The fourth compound, CeRh/sub 2/Si/sub 2/, has the highest known transition temperature (39 K) reported for cerium ordering; it exhibits another second-order transition at 27 K to a complex commensurate structure ...

International Nuclear Information System (INIS)

A method that employs simultaneous neutron and #gamma#-ray diffraction techniques is proposed for accurate measurements of strains with or without an applied electric field (0-100 kV m"-"1). Instead of an absolute determination of the position of the neutron Bragg peak, a relative measurement of the neutron and #gamma# peak positions is used and allows a determination of the lattice-parameter changes with an accuracy of within 2 x 10"-"6. This technique avoids systematic errors originating in sample rotations by taking advantage of a reference directly related to the crystal lattice. The method appears to be particularly important for crystals that exhibit structural phase transitions, as demonstrated by the measurement of the strain U_x_x in KH_2PO_4 crystals as a function of temperature and applied electric field. In this case the errors would amount to #+-#20%. The results demonstrate the need to re-examine the theory previously proposed by Uesu, Tanaka and ...

International Nuclear Information System (INIS)

In this paper, an improved soft switched two cell interleaved boost AC/DC converter with high power factor is proposed and investigated. A new auxiliary circuit is designed and added to two cell interleaved boost converter to reduce the switching losses. The proposed auxiliary circuit is implemented using only one auxiliary switch and a minimum number of passive components without an important increase in the cost and complexity of the converter. The main advantage of this auxiliary circuit is that it not only provides zero-voltage-transition (ZVT) for the main switches but also provides soft switching for the auxiliary switch and diodes. Though all semiconductor devices operate under soft switching, they do not have any additional voltage and current stresses. The proposed converter operates successfully in soft switching operation mode for a wide range of input voltage level and the load. In addition, it has advantages such as fewer structure complications, lower ...

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Iron undergoes a polymorphic phase transformation from alpha phase (bcc) to the epsilon phase (hcp) when compressed to stresses exceeding 13 CPa. Bccause the epsilon phase is denser than the alpha phase, a single shock wave is unstable and breaks up into an elastic wave, a plastic wave, and a phase transition wave. Examination of this structured wave coupled with various phase transformation models has been used to indirectly examine the transition kinetics. Recently, multimillion atom simulations (molecular dynamics) have been used to examine the shock-induced transition in single crystal iron illustrating an orientation dependence of the transition stress, mechanisms, and kinetics. The objective of the current work was to perform plate impact experiments to examine the shock-response of polycrystalline and single crystal iron with nanosecond resolution for impact stresses spanning the {alpha} - ...

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Experiments have been carried out in water at 355 C to study transport of oxygen and hydrogen (as deuterium) in growing corrosion films. Composition of the films was also examined in 2.9 Mev and 3.9 Mev /alpha/-particle backscattering experiments. Corrosion occurs predominantly by oxygen diffusion through the film via grain boundary or similar short circuit diffusion paths, to form fresh oxide at the oxide metal interface. Increasing grain size within thick pre-breakaway films contributes to a decrease in diffusivity. The rate transition results from the generation of new diffusion pathways in previously protective oxide. Unexpectedly high concentrations of deuterium were observed. 26 refs.

International Nuclear Information System (INIS)

The electrical resistivity, Hall effect, and magnetic susceptibility of single-crystal UPd_2Si_2 have been studied between 4.2 and 300 K. A large anisotropy was observed in both the magnetic and transport properties. There is a quadratic temperature dependence of the resistivity for a range of temperatures between 4.2 and 80 K. At higher temperatures, the resistivity indicates a Kondo-type behavior. The behavior of these quantities is accounted for by the magnetic phase transitions at 108 and 136 K reported from neutron-scattering studies. At high temperatures, the magnetic susceptibility of UPd_2Si_2 is Curie-Wiess-like along the c axis. The temperature dependence of the Hall coefficient above 108 K is accounted for by a theoretical model invoking skew scattering of conduction electrons by localized magnetic moments.

British Library Electronic Table of Contents (United Kingdom)

High molecular weight samples of the novel biodegradable polyester poly(ethylene sebacate) (PESeb) were synthesized. Miscible poly(ethylene sebacate)/poly(4-vinyl phenol) semicrystalline/amorphous blends were prepared by applying the solvent casting method. Miscibility was proved by the single composition dependent glass transition temperature over the entire composition range observed in DSC traces of the quenched blend samples and also by the melting point depression. The Flory-Huggins interaction parameter was found to be x12 = -1.3. Also, FTIR spectra supported the hypothesis of intermolecular interactions due to hydrogen bonding. The crystallization of PESeb in blends was studied. As expected, isothermal crystallization rates decreased in the blends with increasing the PVPh content. T...

Science.gov (United States)

Since the elucidation of the structure of double helical DNA, the construction of small molecules that recognize and react at specific DNA sites has been an area of considerable interest. In particular, the study of transition metal complexes that bind DNA with specificity has been a burgeoning field. This growth has been due in large part to the useful properties of metal complexes, which possess a wide array of photophysical properties and allow for the modular assembly of an ensemble of recognition elements. Here we review recent experiments in our laboratory aimed at the design and study of octahedral metal complexes that bind DNA non-covalently and target reactions to specific sites. Emphasis is placed both on the variety of methods employed to confer site-specificity and upon the many applications for these complexes. Particular attention is given to the family of complexes recently designed that target single base ...

Energy Technology Data Exchange (ETDEWEB)

Kinetics of postradiation polymerization of triethylene glycol ..cap alpha.., ..omega..-dimethacrylate has been studied by calorimetric method. The low-temperature radiolysis has been studied by ESR method. The radiation-chemical yield of radicals on ..gamma..-irradiation by /sup 60/Co is determined being equal to 6+-1 1/100 ev. Transformation of the radicals spectrum into the spectrum of propagating macroradicals proceeds at 140 K. After the transition from glassy to liquid state (Tsub(g)=193 K) the intensive postpolymerization begins. During the polymerization the disappearance of radicals is observed. For the low-temperature region the effective activation energy of polymerization is determined beina equal to 50.7+-0.8 kJ/mol.

British Library Electronic Table of Contents (United Kingdom)

In this study, we thoroughly analyzed abrupt behaviors, trends, and periodicity properties of water vapor flux and moisture budget entering and exiting the four edges of the Pearl River basin based on the NCAR/NCEP reanalysis dataset by using the continuous wavelet transform and the simple two-phase linear regression technique. Possible implications for hydrological cycle and water resource management of these changes are also discussed. The results indicate that: (1) the water vapor propagating through the four edges of the Pearl River basin is decreasing, and it is particularly true for the changes of the water vapor flux exiting from the north edge of the study river basin. The transition point from increase to decrease occurs in the early 1960s; (2) The wavelet transform spectra indica...

Energy Technology Data Exchange (ETDEWEB)

The thermal performance and phase change stability of stearic acid as a latent heat energy storage material has been studied experimentally. The thermal performance and heat transfer characteristics of the stearic acid were tested and compared with other studies given in the literature. In the present study, parameters such as transition times, temperature range and propagation of the solid-liquid interface as well as the effect of heat flow rate on the phase change stability of stearic acid as a phase change material (PCM) were studied. The experimental results showed that the melting stability of the PCM is better in the radial direction than in the axial direction. The variation in the melting and solidification parameters of the PCM with the change of inlet water temperature is also studied. We observed that while the heat exchanger tube is in the horizontal ...

International Nuclear Information System (INIS)

... energy levels intermediate mass nuclei isotopes nuclei odd-even nuclei

CERN Document Server

We combine a limited number of accurately measured transition frequencies in hydrogen and deuterium, recent quantum electrodynamics (QED) calculations, and, as an essential additional ingredient, a generalized least-squares analysis, to obtain precise and optimal predictions for hydrogen and deuterium transition frequencies. Some of the predicted transition frequencies have relative uncertainties more than an order of magnitude smaller than that of the g-factor of the electron, which was previously the most accurate prediction of QED.

CERN Document Server

We develop a theory of Smectic A - Smectic C phase transition with anomalously weak smectic layer contraction. We construct a phenomenological description of this transition by generalizing the Chen-Lubensky model. Using a mean-field molecular model, we demonstrate that a relatively simple interaction potential suffices to describe the transition. The theoretical results are in excellent agreement with experimental data.

KoreaScience (Korea)

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Energy Technology Data Exchange (ETDEWEB)

This project has been concerned with the understanding of certain key physical and physical chemical properties of polymeric systems which are related to their use as working substances in mechanochemical systems. Since the crystal-liquid phase transition is involved in the process of interest, attention has been focused on this transition and on the properties of semi-crystalline polymers. Two kinds of behavior and properties have been studied in this program. One of these is concerned with melting-crystallization under an applied external force. Here the primary matters of concern are the equilibrium melting temperature-stress relations and the associated problem of crystallization kinetics under an applied external stress. The other area of study involves mechanical properties, with particular emphasis on the influence of the morphological and structural variables which describe the semi-crystalline ...

Energy Technology Data Exchange (ETDEWEB)

A numerical study has been performed to investigate the hydrodynamic aspects of the pool boiling on horizontal-, vertical- and downward-facing surfaces. The FlowLab code, which is based on a Lattice-Boltzmann (LB) model of two-phase flows, is employed. Macroscopic properties, such as surface tension ({sigma}) and contact angle ({beta}), are implemented through the fluid-fluid (G{sub {sigma}}) and fluid-solid (G{sub t}) interaction potentials. The model is found to express a linear relation between the macroscopic properties ({sigma}, {beta}) and microscopic parameters (G{sub {sigma}}, G{sub t}). The simulation results on bubble departure diameter appear to have the same parametric dependence as the empirical correlation. Hydrodynamic aspects of two-phase flow regime transition mechanism are investigated for different surface-coolant configurations. Results of the LB simulation clearly demonstrate that not only the bubble nucleation site density ...

Energy Technology Data Exchange (ETDEWEB)

The sharp, temperature induced, continuous valence transition in EuPd/sub 2/Si/sub 2/ is drastically changed by doping with Sn at the Si site up to 5 at.%. Only a first order valence transition occurs for a 3% Sn doped sample and the 2/sup +/ component which survives the valence transition orders magnetically at 4.2 K. No valence transition at all occurs for a 5% Sn doped sample right up to 1.9 K and magnetic ordering sets in around 30 K.

Energy Technology Data Exchange (ETDEWEB)

Electron scattering data have been used to obtain transition charge densities for the low-lying E2 transitions in /sup 88/Sr, /sup 89/Y, and /sup 90/Zr. These charge densities show a characteristic shape indicative of their microscopic constituency, modified by core-polarization effects. A good description of transitions in the even-even nuclei is obtained by using the measured single-particle transitions in /sup 89/Y as effective densities. .ID LV2086 .PG 19 22

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The effects of dilute impurity doping on charge-density wave (CDW) structures and gaps in NbSe{sub 3} 1T-TaS{sub 2} and 2H-NbSe{sub 2} have been studied by using a scanning tunneling microscope (STM) operating at 4.2 K. In Fe doped samples of NbSe{sub 3} the STM spectroscopy measurements indicate that the added impurities can significantly shift the CDW energy gaps. In NbSe{sub 3}, Fe reduces both CDW gaps by 25-30%, and produces changes in the conductance structure relative to the pure material. The images of Fe{sub 0.01}NbSe{sub 3} show that all three surface chains in the unit cell still carry a strong CDW modulation with no evident disorder. However, a change in the relative amplitudes of the high and low temperature CDWs is detected. The effects of Co and Ni impurities on the gaps in NbSe{sub 3} have also been studied. While Co increases both by 25-30%, Ni increases only the high temperature gap with the low temperature gap remaining ...

Energy Technology Data Exchange (ETDEWEB)

NMR and CD studies indicate that Mg/sup 2 +/ and Ca/sup 2 +/ are able to change the conformation of tetracycline in DMSO solution. This may affect the in vivo effect of tetracycline. Using /sup 23/Na NMR, the formation constant of NaLAS (LAS represents the anion of lasalocid A) was found to be 80 M/sup -1/ which is much smaller than that in less polar solvents. Spin-lattice relaxation measurements were made to study the binding sites of Gd/sup 3 +/ on Las in ChCl/sub 3/-DMF mixed solvent system. No intermediate conformation (between cyclic and open-chain) was found. LAS was found to be a good second-sphere ligand to inert transition-metal amines. NMR studies suggest that LAS is in cyclic conformation when bound to these metal amines. A new method for the synthesis of spin-labeled anticancer Pt(II) complexes was developed. It is very simple and gives high yield of pure spin-labeled Pt(II) complexes.

CERN Document Server

We present a theoretical framework for formal study of systematic effects in Supernovae Type Ia (SN Ia) that utilizes 2-d simulations to implement a form of the deflagration-detonation transition (DDT) explosion scenario. The framework is developed from a randomized initial condition that leads to a sample of simulated SN Ia whose Ni56 masses have a similar average and range to those observed, and have many other modestly realistic features such as the velocity extent of intermediate mass elements. The intended purpose is to enable statistically well-defined studies of both physical and theoretical parameters of the SN Ia explosion simulation. We present here a thorough description of the outcome of the SN Ia explosions produced by our current simulations. A first application of this framework is utilized to study the dependence of the SN Ia on the Ne22 content, which is known to be directly influenced ...

Energy Technology Data Exchange (ETDEWEB)

This report is an examination and analysis of the zinc-air system as the motive power source for electric vehicle propulsion. Various versions of the zinc-air system and operating schemes along with their advantages and disadvantages are discussed. Baseline cost calculations are also presented in order to compare the cost effectiveness of each of the systems. The treatise is conceptual in nature and is not based on new experimental work. The information is based on published literature and investigations carried out at ERC in the past. The study also includes recommendations and suggestions in areas that require further research and development work to achieve a smooth transition from the conceptual stage to a practical, viable, and cost effective system.

British Library Electronic Table of Contents (United Kingdom)

This article presents numerical study of 3-D thermosolutale mixed convection (TSMC) in horizontal rectangular channels. The contribution of this work is to characterize the travelling wave's appearance and to generalize the behavior of Poiseuille-Rayleigh-Benard (PRB) systems for a broad range of dimensionless parameters, which control the double diffusive mixed convection. The numerical results consist of analyzing the flow regimes of the steady longitudinal thermoconvectives rolls for the case of purely thermal mixed convection (TMC) and for both thermal and mass transfer (TSMC). The transition from opposed volume forces to cooperating ones at fixed Rayleigh (Ra), Reynolds (Re), and Lewis (Le) numbers, considerably affects the birth and the development of the longitudinal rolls (noted R/...

British Library Electronic Table of Contents (United Kingdom)

The dependence of melting temperature T m on the size and shape of an n -dimensional nanocrystal of elementary single-component substance is studied. The nanocrystal has the form of an n-dimensional parallelepiped with a square base. The ratio of the length of side rib to the length of base rib (which is equal to f) defines the form of the system. It is demonstrated that, if the surface pressure is ignored, the value of T m decreases with isomorphic (f = const) decrease in the size of nanocrystal. In so doing, the more the value of form parameter f deviates from unity, the more appreciable the size dependence of T m will be. However, if the surface pressure (?Laplace pressure??) is taken into account in the case of decrease in size, the value of T m may vary significantly. In so doing, if ...

CERN Document Server

Hidden Markov models (HMMs) are probabilistic functions of finite Markov chains, or, put in other words, state space models with finite state space. In this paper we examine subspace estimation methods for HMMs whose output lies a finite set as well. In particular we study the geometric structure arising from the non-minimality of the linear state space representation of HMMs, and consistency of a subspace algorithm arising from a certain factorisation of the singular value decomposition of the estimated linear prediction matrix. For this algorithm we show that the estimates of the transition and emission probability matrices are consistent up to a similarity transformation, and that the m-step linear predictor computed from the estimated system matrices is consistent, i.e. converges to the true optimal linear m-step predictor.

International Nuclear Information System (INIS)

We have studied energy levels in "6"3Fe populated in the #beta#-decay of "6"3Mn. A new (preliminary) level scheme of "6"3Fe includes 10 excited states connected by 21 #gamma#-rays. The first excited states at 357 and 451 keV have the level half-lives of 110 ps and 780 ps, respectively. Three states, at 357, 451 and 1132 keV, are strongly #beta#-fed with log ft #approx# 5, while there is only a very week #beta#-feeding, if any at all, to the ground state. The new results imply that "6"3Fe departs from a simple shell model structure observed for heavier N = 37 isotones of "6"5Ni and "6"7Zn. (author)

International Nuclear Information System (INIS)

After the publication of the 2nd progress report of geological disposal of TRU waste in Japan, policy and general scheme of future study for the waste disposal in Japan was published by ANRE and JAEA. This annual report summarized aim and progress of individual problem, which was assigned into JAEA in the published policy and general scheme. The problems are as follows; characteristics of TRU waste and its geologic disposal, treatment and waste production, quality control and inspection methodology for waste, mechanical analysis of near-field, data acquisition and preparation on radionuclides migration, cementitious material transition, bentonite and rock alteration in alkaline solution, nitrate effect, performance assessment of the disposal system and decomposition of nitrate as an alternative technology. (author)

International Nuclear Information System (INIS)

Progress in experimental investigations of high spin excitations in spherical and transitional nuclei in the A = 180 to 204 mass range is described. Most of the experiments were performed by in-beam #gamma#-ray spectroscopy using beams of "3He, "4He, and "1"2C ions from the Michigan State University cyclotron. The main results of studies of the nuclei "1"9"5 "1"9"7 "1"9"9 "2"0"1 "2"0"2 "2"0"3Pb, "1"9"6 "1"9"7 "1"9"9 "2"0"0Hg and "1"8"6 "1"8"7 "1"8"8 "1"8"9Pt are summarized.

Energy Technology Data Exchange (ETDEWEB)

This renewal request for DOE grant DE-FG02-86ER45238, is dedicated to providing a complete thermodynamic profile of solids fluids, and fluid mixtures, over a wide range of temperatures and pressures. We are partially motivated by technological interest in detonation, combustion, superhard high pressure materials, and high temperature superconductors, which are important components of interest of various DOE laboratories. Our work on fluids and solids, composed of simple molecules, involves the determination of structures, phase transitions, pressure-volume relations, phonon, vibron, and libron modes of excitation, sound velocities, specific heats, thermal expansion, virial coefficients, sublimation energies, and orientational translational, and magnetic correlations. We hope that the study of these systems under extreme thermodynamic conditions will lead to exotic new materials of value, as well as enhanced fundamental understanding.

Energy Technology Data Exchange (ETDEWEB)

We present a synchrotron x-ray diffraction study of melting in stacks of two-dimensional crystalline arrays of the membrane protein bacteriorhodopsin. Two distinct regimes have been found as a function of the intermembrane distance d . In the {open_quotes}coupled{close_quotes} regime for d{lt}250 {Angstrom} the temperature (T{sub m}) of the melting transition decreases with increasing d , demonstrating the effect of the repulsive membrane interactions on the intramembrane protein ordering. For d{gt}250 {Angstrom} a {open_quotes}decoupled{close_quotes} regime is found with higher T{sup *}{sub m} independent of d . Below T{sup *}{sub m} a solid-liquid-solid reentrant behavior is observed as d is increased. {copyright} {ital 1999} {ital The American Physical Society}

International Nuclear Information System (INIS)

Silica glasses containing Pr"3"+ with and without CdS nanoparticles were prepared by sol-gel technique. The influence of CdS nanoparticles on Pr"3"+ doped glass was studied by absorption, photoluminescence and up-conversion. From the measured intensities of various absorption bands of these glasses, the Judd-Ofelt parameters ?_2, ?_4 and ?_6 have been evaluated. The radiative transition probability (A), radiative lifetime (?_R), branching ratio (?_R) and integrated emission cross-section (?_P) were calculated from excited states of "3P_1 and "3P_0 levels. The up-conversion emissions were found in the green, orange and red regions under 800 nm excitation with peaks 559, 612 and 688 nm respectively. On excitation with 370 nm also leads to similar green, orange and red regions.

Science.gov (United States)

The dynamic dielectric susceptibility and the elastic compliance of the relaxor ferroelectric lanthanum lead zirconate titanate (PLZT) 9/65/35 have been measured under different cooling and heating protocols in order to study aging and memory. The memory of multiple aging stages at different temperatures has been found (several dips in the susceptibility curves on heating), as in spin glass systems below the glass transition. Remarkably, in PLZT the memory of several aging stages is retained also above the freezing temperature deduced from the dynamic susceptibilities. The results are discussed in light of the existing models of aging and memory in spin and dipolar glasses. PMID:15447139

International Nuclear Information System (INIS)

The energy level schemes of "1"5"2Gd and "1"5"2Sm have been established on the basis of single #gamma#-spectra, and #gamma#-#gamma# coincidence measurements. Ge(Li) detectors were used to study the gamma spectra produced in the EC/#beta#"+ and #beta#"- decays of "1"5"2Eu to "1"5"2Sm and "1"5"2Gd, respectively. Thirteen new transitions are reported and data from eleven coincidence gates enabled five new levels to be suggested. Relative intensities and log ft values were calculated and spin/parities deduced. Comparisons are made with new predictions of the Interacting Boson Model. (orig.).

Energy Technology Data Exchange (ETDEWEB)

The kinetics of the reaction of 2,4-dinitrohalogenobenzenes (chlorine, bromine, and iodine derivatives) with tetraethylammonium azide in acetonitrile and in a mixed acetonitrile-dioxane solvent (80 vol. % dioxane) were studied. It was established that there is a marked increase (by more than three orders of magnitude) in the azidization rate constant in the transition from protic solvents to aprotic media, due to the decrease in the activation energy barrier of the reaction. The nucleophilicity parameters N/sup +/ for the azide ion in the investigated solvents were determined in terms of Ritchie's relationship. It was established that the effect of the nature of the leaving group on the rate constant of the reactions is complex in character, and it was shown that treatment of the relative reactivity series for the investigated substrates must be based on an analysis of the activation parameters and not restricted to data obtained at ...

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The interfacial area transport equation dynamically models two-phase flow regime transitions and predicts continuous changes of the interfacial area concentration along the flow field. It replaces the flow regime-dependent correlations for the interfacial area concentration in thermal-hydraulic system analysis. In the present study, detailed formulation of the interfacial area transport equation is presented along with its evaluation results based on the detailed benchmark experiments. In view of model evaluation, the equation is simplified into one-dimensional steady state one-group interfacial area transport equation. The prediction made by model agrees well with the experimental data obtained in round pipes of various diameters. The framework for the two-group transport equation and the necessary constitutive relations are also presented in view of bubble transport of various sizes and shapes. (author)

Energy Technology Data Exchange (ETDEWEB)

To make the Dutch energy system more sustainable as formulated in the objectives of the recently constituted Task Force Energietransitie (Energy Transition), additional investments by the government in sustainable energy are needed. One of the ideas is to start a public-private risk bearing fund that invests in Netherlands based innovation projects in the area of sustainable energy. The ingoing assumption is that there is a shortage of capital supply for innovation projects that are in between the Research and Development phase and the market introduction phase, and that the government can attract further commercial private capital by co-investing itself. The Ministry of Economic Affairs has asked Bain and Company to perform a due diligence on the validity of the in-going assumptions for raising such a Venture Capital fund. This report contains the key conclusions of the study performed in June and the first half of July of 2006.

International Nuclear Information System (INIS)

The resonant scattering of bremsstrahlung #gamma#-rays by a SrCO_3 target has been studied for #gamma#-ray energies of 5-11 MeV. Six #gamma#-transitions of energies between 6-8 MeV, which indicate six resonant states in "8"8Sr, were observed. The relative intensities of the resonantly scattered #gamma#-rays at 125 and 150"0 were found to be compatible only with the assignment of spin 1 to the six states. Radiative widths of the resonant states were deduced. The possibility that these states are components of the giant M1 resonance in "8"8Sr is discussed. (orig.).

International Nuclear Information System (INIS)

The experimental study of the proton-rich nuclei close to the N=Z line is a constant challenge for nuclear spectroscopy, mainly due to the difficulty to produce them with the currently available beam/target combinations. Significant advances on this direction were obtained from experiments performed with the GASP array during the last two years: the yrast line of "8"4Mo was extended up to 10"+, "8"8Ru observed for the first time, and the N=Z+1 line was mapped from "8"1Zr to "9"5Ag. These new results allow us to have a more complete image of the transition from the well-deformed shell closure at N,Z=40 to the spherical-shell closure at N,Z=50, and highlights some particular effects that can be observed only in the vicinity of the N=Z line. (orig.)

Science.gov (United States)

This article describes a methodology that implements a Markov decision process (MDP) optimization technique in a real time fed-batch experiment. Biological systems can be better modeled under the stochastic framework and MDP is shown to be a suitable technique for their optimization. A nonlinear input/output model is used to calculate the probability transitions. All elements of the MDP are identified according to physical parameters. Finally, this study compares the results obtained when optimizing ethanol production using the infinite horizon problem, with total expected discount policy, to previous experimental results aimed at optimizing ethanol production using a recombinant Escherichia coli fed-batch cultivation. (c) 1997 John Wiley & Sons, Inc. Biotechnol Bioeng 55: 317-327, 1997. PMID:18636490

International Nuclear Information System (INIS)

The self-consistent-pseudopotential method is applied to the A-15 compounds Nb_3Ge and Nb_3Al. The Fermi energy is found to lie in a region of very flat bands having a bonding character along the Nb chains. Comparison with the band structures of the (nonexistent) A-15 materials Nb_3Nb and Nb_3/sup asterisk/ (chains only) suggest that the p states on the Ge and Al atoms are instrumental in determining the position of the Fermi level. There is little evidence for rigid-band behavior in the Nb_3Al/sub x/Ge/sub 1-x/ system. Studies of the effects of chain dimerization in Nb_3Ge suggest that states at R and M are more likely candidates to participate in structural transitions than states at GAMMA or X.

International Nuclear Information System (INIS)

The effects of intradot electron-electron interaction on the photon-assisted Andreev tunneling of a superconductor/carbon-nanotube/superconductor system are studied by using nonequilibrium Green's function technique. The inverse supercurrent reflecting the #pi#-junction transition emerges in the spin-split energy-levels regime polarized by the Coulomb interaction. For the positive tunneling case, the supercurrent reaches its maximum when the spin-degenerate energy-levels are nearest to the Fermi surface. Conversely, for the negative tunneling case, the supercurrent reaches its maximum when two split energy-levels are symmetric with respect of the Fermi surface. The sign and the amplitude of the Andreev tunneling depend distinctly on the energy-level spacing tuned by photon-assisted tunneling. In order to fully understand the transport characteristics, the current-carrying density of states are investigated, which clearly shows the enhancement, ...

Energy Technology Data Exchange (ETDEWEB)

The authors present results of grazing incidence X-ray diffraction studies concerning the effect of pH (and thus, of headgroup dissociation) on Langmuir monolayers of fatty acids, in the absence of any divalent cations in the aqueous subphase. An increase in pH transforms the distorted-hexagonal S phase first to the partially disordered Rotator-I phase with less distortion, and then to the completely disordered Rotator-II phase with an undistorted hexagonal structure. The S-Rotator-I and Rotator-I-Rotator-II transitions are pushed to lower temperatures with increase in pH. The fact that the effects of pH increase are almost identical to the effects of increasing temperature indicates the important role of headgroup-headgroup interactions in these monolayer phases.

British Library Electronic Table of Contents (United Kingdom)

Sols of silver nanoparticles in toluene were studied by broadband dielectric spectroscopy (10?3?105 Hz). The frequency dependences of the specific alternating current (ac) conductivity and the complex electric modulus were used to estimate the temperature/frequency intervals of long- and short-range charge transfer occurs, respectively. A considerable increase (by more than 30 ?C) in the Vogel temperature T 0 and the glass transition temperature T g in sols compared with the pure solvent was found. It can be hypothesized that these cooperative effects reflect the initial stage of the superlattice formation. Although the dielectric characteristics of sols are generally controlled by the conductivity relaxation, the dielectric response was observed in the high-frequency range (1?103 Hz) at l...

International Nuclear Information System (INIS)

The #gamma# rays following the #beta# decays of "8"8Kr and "8"8Rb have been studied, using both large volume Ge(Li) detectors for singles and coincidence measurements and anti-Compton spectrometry for singles measurements. Level schemes for "8"8Rb and "8"8Sr were constructed from the data and 74 of 81 #gamma# rays observed in the decay of "8"8Kr were placed in the "8"8Rb level scheme with 23 excited states. For the decay of "8"8Rb, all of the observed 27 #gamma# rays have been placed in the (well known) level structure of "8"8Sr. Spin and parity assignments have been deduced from #beta#-decay logft values and #gamma#-ray transition patterns. Possible shell model interpretations are presented for the level schemes.

CERN Document Server

We study the ground state of an ideal coupled two-component gas of ultracold atoms in a one dimensional optical lattice, either bosons or fermions. Due to the internal two-level structure of the atoms, the Brillouin zone is twice as large as imposed by the periodicity of the lattice potential. This is reflected in the Bloch dispersion curves, where the energy bands regularly possess several local minima. As a consequence, when the system parameters are tuned across a resonance condition, a non-zero temperature topological first order phase transition occurs which arises from an interplay between initernal and kinetic atomic energies. It is shown that these phenomena are also captured for two and three dimensional optical lattices.

British Library Electronic Table of Contents (United Kingdom)

Using institutional and resource dependence theories as the conceptual framework, this study identifies three forms of conformity?political, economic, and social?that can affect the level of private entrepreneurs? formal political participation in a transition economy. Data from a 2004 national-wide survey of 3,012 private firms in China show that political conformity (indicated by membership in the ruling party), economic conformity (amount of taxes paid), and social conformity (amount of charity donated) are each antecedents to private entrepreneurs? formal political participation. Moreover, political conformity negatively moderates the relationship between social conformity and private entrepreneurs? formal political participation?for party members, a lesser amount of charity is associa...

Energy Technology Data Exchange (ETDEWEB)

We have studied the structure of both propanol isomers in their glassy and crystalline states by neutron diffraction. The glass-transition temperatures of 1- and 2-propanol are about 98 and 115 K, respectively and, surprisingly, even larger differences are observed for the melting temperatures of the stable crystals, which are 148 and 185 K, respectively. Their supercooled liquid phases show rather different relaxation spectra, 1-propanol manifesting strong deviations from Debye behavior, whereas 2-propanol shows a far weaker effect. We discuss the spectra obtained for the static structure factor and the static pair correlation function D(r). There is a noticeable difference in the position of the first sharp diffraction peak, which clearly indicates a density change, well correlated with the period of the intermolecular oscillations shown by D(r). (orig.)

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Regularities in the radiation cross-linking of low-density polyethylene under various conditions of ..gamma..-irradiation were studied. It is shown that at the 0.5 GPa pressure and 450 K the gel formation is initiated at doses of about 1 kGy, i.e. at doses 10 times as low as compared to normal conditions. Abnormally high rate of radiation cross-linking at high temperature and high pressure is an evidence of changes in the mechanism of polyethylene, radiation cross-linking, i.e. of the process transition from nonchain to chain conditions. Decrease in the potential barriers of macroradical reactions with macromolecules is the most probable reason of change in the polymer cross-linking nature.

CERN Document Server

Mono-layers of stearic and behenic acids and mixtures of them in different proportions, deposited with the Langmuir-Blodgett technique, were used to study the alignment and the alignment dynamics in nematic liquid crystal cells. A relaxation process from a splay-bend flow induced metastable orientation to the homeotropic one occurs. The lifetime of the metastable state was found to depend on the mono-layer composition. The transition between the homeotropic and the conical anchoring was found to be irreversible in the case of the mixed aligning mono-layers: on cooling from the isotropic phase a quasi-planar nematic state (schlieren texture) appears. It is stable in a range of a few degrees below the clearing point and, on decreasing the temperature, relaxes to the homeotropic state in form of expanding domains.

British Library Electronic Table of Contents (United Kingdom)

The influence of trace level Ni additions on the eutectic solidification mode of Sn?0.7Cu has been studied using continuous torque experiments during solidification. The solid fraction at which resistance to paddle rotation at the thermal centre of the sample occurs is related to the spatial distribution of solid during solidification. The results indicate that a transition in solidification mode occurs in the range 0?300ppm Ni. Growth occurs antiparallel to heat flow from near the mould walls in the Ni-free alloy, while equiaxed growth from distributed centres dominates in alloys containing at least 300ppm Ni.

Energy Technology Data Exchange (ETDEWEB)

The work in the past year has primarily involved four areas of magnetic thin films: amorphous rare earth-transition metal alloys, epitaxial CoPt{sub 3} and Ni-Pt alloy thin films, amorphous rare earth doped Si (a new class of dilute magnetic semiconductor with large negative magnetoresistance which the authors have discovered), and exchange-coupled antiferromagnetic insulators. In the amorphous alloys, they made a systematic study of the effects of local anisotropy, macroscopic (perpendicular) anisotropy, and exchange constant on the fundamental (and practical) properties of these magnetic alloys, as originally described in the grant proposal. The work on the epitaxial Co-Pt (and more recently Ni-Pt) alloys was originally undertaken as a comparison study to the amorphous alloys. Crystalline Co-Pt alloys have many striking similarities to the amorphous rare earth-transition metal alloys: perpendicular ...

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The fuel economy of different types of trucks was simulated. Preliminary vehicle simulation activity took place in order to determine a feasible range of vehicle fuel efficiency improvements that could be obtained. Another objective was to provide a start to the Systems Analysis road mapping process in order to identify significant improvements for future studies at minimal costs. Technology improvements to all types of trucks were categorized in relation to engine improvements, the incorporation of continuously variable transmissions, hybrid drivetrain technology and improvements in aerodynamic drag, rolling resistance and weight reduction. The trucks which had the largest national impact were identified from data on vehicles, miles driven, fuel consumption and exhaust gases. The study involved Class 2B utility trucks, Class 6 enclosed delivery trucks, Class 8 transit buses and Class 8 tractor trailer trucks because they ...

CERN Document Server

A phase transition of gas-liquid type with an upper critical point is examined which arises in a model of charges of one sign on compensating background (OCP). The phase transition parameters are dependent on the detailed assumptions about the compressibility of the background, but the occurrence of this transition is independent on the background equation of state. In the electron-gas model ('jellium'), this transition appears to rule out Wigner crystallization. A variational principle in statistical mechanics is used to derive so-called Double-OCP model for a superposition of two one-component plasma models for charges of opposite sign. The free energy of this model sets an upper bound to that of a real plasma. Situations are discussed where this transition should manifest itself in anomalies in the approximate description of a non-ideal plasma.

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Full text of publication follows:In the current thermal-hydraulic system analysis codes using the two-fluid model, the empirical correlations that are based on the two-phase flow regimes and regime transition criteria are being employed as closure relations for the interfacial transfer terms. Due to its inherent shortcomings, however, such static correlations are inaccurate and present serious problems in the numerical analysis. In view of this, a new dynamic approach employing the interfacial area transport equation has been studied. The interfacial area transport equation dynamically models the two-phase flow regime transitions and predicts continuous change of the interfacial area concentration along the flow field. Hence, when employed in the thermal-hydraulic system analysis codes, it eliminates artificial bifurcations stemming from the use of the static flow regime transition criteria. Therefore, ...

Science.gov (United States)

Photorefractives, in general, are among the most promising materials solutions to real time optical correlation. Applications include military target recognition and civilian robotic vision. Crystals of sillenite structure photorefractives, Bi12XO20, where X equals Si, Ge, or Ti, have been grown by melt techniques and in the case of bismuth silicon oxide (BSO) and bismuth titanium oxide (BTO) by the hydrothermal method of high-temperature/high-pressure solution growth. The two growth methods are discussed and crystals grown by the two methods are compared in this paper. Optical absorption and TSC studies show that hydrothermal BSO is essentially free of the native antisite Bi defect which usually acts as a donor. These studies also show that the trap density is greatly reduced in hydrothermal material. Preliminary experiments show that hydrothermal BTO crystals have improved properties over melt grown samples. Al and P act as donors and ...

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A multi-faceted research program has been performed to investigate in detail several aspects of free and forced convective cooling of underground electric cable systems. There were two main areas of investigation. The first one reported in this volume dealt with the fluid dynamic and thermal aspects of various components of the cable system. In particular, friction factors for laminar flow in the cable pipes with various configurations were determined using a finite element technique; the temperature distributions and heat transfer in splices were examined using a combined analytical numerical technique; the pressure drop and heat transfer characteristics of cable pipes in the transitional and turbulent flow regime were determined experimentally in a model study; and full-scale model experimental work was carried out to determine the fluid dynamic and thermal characteristics of entrance and exit chambers for the cooling oil. The second major ...

International Nuclear Information System (INIS)

Electron paramagnetic resonance (EPR), optical, infrared and Raman spectral studies have been carried out on vanadyl ions doped in polyvinylalcohol (PVA) films. The spin-Hamiltonian parameters (g and A) and the molecular orbital coefficients (#beta#_2"*"2 and k) have been evaluated. The values of spin-Hamiltonian parameters confirm that the vanadyl ions are present in PVA films as VO"2"+ molecular ions in an octahedral site with a tetragonal compression (C_4_v). The temperature variation EPR studies reveal that the variation of number of spins with temperature is in accordance with Boltzmann law. It is interesting to observe that the variation of susceptibility with temperature obeys Curie-Weiss law. The FT-IR and FT-Raman spectrum exhibits few bands, which are attributed to O-H, C-H, C-C and C-O groups of stretching and bending vibrations. The optical absorption spectrum exhibits two bands, which are assigned to "2B_2_g->"2B_1_g and ...

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When liquids are confined in nano-scopic dimensions, their properties differ from the corresponding bulk liquid, due to their reduced dimensionality and surface effects. Phase transition temperatures and pressures are often shifted from the bulk values and new phases can appear due to the strong interactions of the molecules with the confining walls. We have studied the structural and dynamical properties of aromatic liquids such as benzene, toluene, and ortho-terphenyl confined in nano-porous materials, MCM-41 and SBA-15, synthesized and characterized in our laboratory. A non-trivial dependence of the glass transition temperature, T{sub g}, on the pore size and surface treatment of nano-porous materials is confirmed and interpreted as resulting from a competition between the fluid-wall and fluid-fluid intermolecular interactions. An increase of T{sub g} is observed for small pore sizes and attractive surface while T{sub g} ...

International Nuclear Information System (INIS)

Higgs mediated flavor violating electromagnetic interactions, induced at the one-loop level by a nondiagonal Hf_if_j vertex, with f_i and f_j charged leptons or quarks, are studied within the context of a completely general effective Yukawa sector that comprises SU_L(2)xU_Y(1)-invariant operators of up to dimension-six. Exact formulae for the one-loop #gamma#f_if_j and #gamma##gamma#f_if_j couplings are presented and their related processes used to study the phenomena of Higgs mediated lepton flavor violation. The experimental limit on the #mu##->#e#gamma# decay is used to derive a bound on the branching ratio of the #mu##->#e#gamma##gamma# transition, which is 6 orders of magnitude stronger than the current experimental limit. Previous results on the #tau##->##mu##gamma# and #tau##->##mu##gamma##gamma# decays are reproduced. The possibility of detecting signals of lepton flavor violation at #gamma##gamma# ...

International Nuclear Information System (INIS)

The puborectalis syndrome is a defecation disorder supported by the nonrelaxation of puborectalis sling with consequent dyschezia. They report on a series of 98 patients submitted to clinical examination, defecography, anorectal manometry, electromyography and intestinal transit time studies. The main symptoms of puborectalis syndrome in their patients were incomplete defecation (89 %) and intermittent evacuation (63 %); 28 % of patients turned to finger defecation. In all patients, defecography showed an abnormal increase in puborectalis impression on the posterior anorectal wall, reduced anorectal angle opening under straining (mean value: 113 deg) and prolonged expulsion time with barium pooling in the ampulla (mean evacuation time: 38 seconds). Such anorectal abnormalities as rectal mucosal prolapse (47 cases) and anterior rectocele (36 cases) were also associated. In 33 of 98 patients (34 % of cases), sling assessment by bidigital ...

International Nuclear Information System (INIS)

The crystal structure of borophosphates ABPO_5 (A = alkaline earth or Pb) was resolved on a polycrystalline sample using the Rietveld method. The x-ray diffraction patterns data show that ABPO_5 crystallize in a centrosymmetric space group P3_121 and their structure is related to the borogermanates REBGeO_5 with a stillwellite-type structure. Pr"3"+ ion was used as a local structural probe to corroborate the structural resolution results. Absorption and fluorescence spectra of A_1_-_xPr_xBP_1_-_xGe_xO_5 (A alkaline earth or Pb; x = 0.05) have been investigated at different temperatures. At 9 K the 3"H_4#->#"3P_0 transition of trivalent praseodymium ion (4f"2 configuration) is observed as a single line. This indicates a unique crystallographic site for the rare earth ion in these compounds replacing the divalent cation. Energy level schemes were deduced from the low-temperature spectroscopic measurements. Comparing the electronic level splittings of ...

UK PubMed Central (United Kingdom)

An explicit proposal for experiments leading to abrupt transitions in spatially extended bacterial populations in a Petri dish is presented on the basis of an exact formula obtained through an analytic...Full Text Available

UK PubMed Central (United Kingdom)

Epithelial-mesenchymal transition (EMT), a switch of polarized epithelial cells to a migratory, fibroblastoid phenotype, is considered a key process driving tumor cell invasiveness and metastasis....Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The authors report experimental results of heat transfer in the region of transition to turbulence. The augmentation was induced through deployment of periodically placed cylindrical eddy promoters in parallel plane channel flows. Eight different configurations were used. The presence of eddy promoters displaced the point of transition from Reynolds number values of 1500 for the plane channel to around 400 for the least stable case. The value of Nusselt number at the transition for eddy promoters cases was up to 2.5 times higher than the one for the plane channel at the transition. Furthermore, the lower the transition Reynolds number, the higher the Nusselt number at the transition. For the cases where the diameter of the promoters was small and/or the pitch large, the heat transfer results in the transition region were consistent with ...

UK PubMed Central (United Kingdom)

Transitions at 28-32°C in membranes of many kinds of seeds influence their germination and subsequent growth. Changes at 28-32°C in the rates of loss of endogenous amino acids from imbibed...Full Text Available

International Nuclear Information System (INIS)

... transitions lutetium 175 target mev range 10-100 multipolarity neutrons parity

KoreaScience (Korea)

Full Text Available

International Nuclear Information System (INIS)

... deformed nuclei eigenvalues even-odd nuclei gold 195 hamiltonians iridium

Science.gov (United States)

... transition to couple the emitted spontaneous radiation with the ammonia molecules and thus provide more amplification [2]. ...

International Nuclear Information System (INIS)

... beta decay energy levels energy-level transitions internal conversion

Energy Technology Data Exchange (ETDEWEB)

We present results from ab-initio electronic-structure calculations of mechanical properties of the rhombohedral phase of vanadium reported in recent experiments (R Ia), and other predicted high-pressure phases (R Ib and bcc), focusing on properties relevant to dynamic experiments. We find that of the three transitions the largest volume collapse (1.3%) is for the R Ia to R Ib transition. Calculations of the single crystal and polycrystal elastic constants reveal a remarkably small discontinuity across the phase transitions even at zero temperature where the transitions are first order.

International Nuclear Information System (INIS)

... beta decay coincidence spectrometry energy levels energy-level transitions

International Nuclear Information System (INIS)

... correlation beta-minus decay coincidence spectrometry experimental data

Energy Technology Data Exchange (ETDEWEB)

High-precision laser spectroscopy on lithium isotopes is of fundamental interest, experimentally as well as theoretically. The lithium atom has long served as a test system for the calculation of various atomic properties in few-electron atoms and significant advances have been made in the last decade[1-3]. Recently, calculations of transition energies for the 22S1/2 -> 32S1/2 and the 22S1/2 -> 22P1/2, 3/2 transitions and of the mass-dependant isotope shift (IS) in these transitions have been reported with a relative accuracy of better than 1 X 10-7 and 5 x 10-6, respectively[4, 5]. These calculations are the foundation for experimental efforts, currently underway at GSI Darmstadt, Germany, to determine the root-mean-square (rms) charge radius of the unstable lithium isotopes[6, 7]. The basic principle is that if all mass-dependent contributions to the IS can be calculated with sufficient accuracy, the ...

Energy Technology Data Exchange (ETDEWEB)

A Bianchi type-IX cosmological model has been found as a solution of Einstien's vacuum field equations with a cosmological constant. The solution represents a rotating generalziation fo the de Sitter universe. This universe shows a transition to exponential expansion and the vorticity begins to decay exponentially at the grand-unified-theory time. The point of time for this transition is independent of the magnitude of the vorticity. During the Guth inflationary era the vorticity decays by a factor of the order 10 US.

Science.gov (United States)

We introduce a discrete multiplicative process as a generic model of competition. Players with different abilities successively join the game and compete for finite resources. Emergence of dominant players and evolutionary development occur as a phase transition. The competitive dynamics underlying this transition is understood from a formal analogy to statistical mechanics. The theory is applicable to bacterial competition, predicting novel population dynamics near criticality.

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The National Renewable Energy Laboratory (NREL) evaluated the performance of diesel, compressed natural gas (CNG), and hybrid electric (equipped with BAE Systems? HybriDrive propulsion system) transit buses at New York City Transit (NYCT). CNG, Gen I and Gen II hybrid electric propulsion systems were compared on fuel economy, maintenance and operating costs per mile, and reliability.