International Nuclear Information System (INIS)

The composite of doped lanthanum gallate (La_0_._9Sr_0_._1Ga_0_._8Mg_0_._2O_2_._8_5, LSGM) and doped ceria (Ce_0_._8Sm_0_._2O_1_._9, CSO) was investigated as an electrolyte for solid oxide fuel cell (SOFC). The LSGM-CSO composite was examined by X-ray diffraction (XRD) and impedance spectroscopy. It was found that the sintered LSGM-CSO composite contains mainly fluorite CeO_2 phase and a minority impurity phase, Sm_3Ga_5O_1_2. The LSGM-CSO composite electrolyte shows a small grain boundary response in the impedance spectroscopy as compared to LSGM and CSO pellets. The composite electrolyte exhibits the highest conductivity in the temperature range of 250-600 "oC, compared to LSGM and CSO. The LSGM-CSO composite can be expected to be an attractive intermediate temperature electrolyte material for solid oxide fuel cells.

Science.gov (United States)

Commercial introduction of new polymer materials for use as the electrolyte in solid tantalum and solid aluminum electrolytic capacitors is underway. ...

Energy Technology Data Exchange (ETDEWEB)

This paper describes inorganic solid electrolytes from a viewpoint of electrolytes for lithium batteries. Lithium ion conductive inorganic solid electrolytes are largely divided into crystalline and amorphous substances. Crystalline substances are known as LiI and Li3N, and also oxygen acid salt. However, when considering application to a battery, its large grain boundary resistance and electrochemical instability would be a problem. Lithium ion conductive amorphous solid electrolytes are divided into an oxide system and a sulfide system. Since most of them do not contain transition metal elements, they are stable against electrochemical reduction, and ions move isotropically in electrolyte. Therefore, ion conduction paths across the grain boundaries may be connected more easily, forming an electrolyte with low grain boundary resistance. As a result of the ...

UK PubMed Central (United Kingdom)

The cancer preventive action of (−)-epigallocatechin gallate (EGCG), found in green tea, is strongly supported by epidemiology and laboratory research data. However, the mechanism by...Full Text Available

UK PubMed Central (United Kingdom)

BackgroundMany studies associated the main polyphenolic constituent of green tea, (-)-Epigallocatechin-3-gallate (EGCG), with inhibition of cancers, invasion and metastasis. To date,...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Research investigating applicability of lithium salts for solid electrolyte batteries was described. The studies included determinations of lithium ion conductivities in solid electrolyte systems based on Li4SiO4, LiTi2(PO4)3, and ceramic materials. Research on all solid state lithium cells utilizing TiS2 NiPS3 electrodes was also reported.

Energy Technology Data Exchange (ETDEWEB)

A research program has been initiated to screen and select electrolyte materials for use in steam electrolyzers in the 300-600/sup 0/C temperature range. Screening of a significant number of acid anhydrides, hydroxides, oxides, and phospates for their electrolytic conductivity properties is underway. Of the binary materials examined to date, only polymerized phosphoric acid, immobilized on an H/sup +/ substituted zeolite, shows promise. A substantial number of ternary compounds remain to be synthesized and evaluated.

Energy Technology Data Exchange (ETDEWEB)

The invention comprises an improved rechargeable zinc-air cell/battery having recirculating alkaline electrolyte and a zinc electrode comprising a porous foam support material which carries the active zinc electrode material. 5 figs.

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A gas diffusion semiconductor electrode and solar cell and a process for gaseous fixation, such as nitrogen photoreduction, CO/sub 2/ photoreduction and fuel gas photo-oxidation are described. The gas diffusion photosensitive electrode has a central electrolyte porous matrix with an activated semiconductor material on one side adapted to be in contact with an electrolyte and a hydrophobic gas diffusion region on the opposite side adapted to be in contact with a supply of molecular gas.

Energy Technology Data Exchange (ETDEWEB)

This article reports of the nickel-metal-hydride battery and its ability to compete with the lead-acid battery in electric-powered vehicles. The topics of the article include development of the battery, the impetus for development in California environmental law, battery performance, packaging for the battery's hazardous materials, and the solid electrolyte battery.

Energy Technology Data Exchange (ETDEWEB)

Lithium, with its strong reducing property and very low potential (-3.045 V/ENH), is one of the best material for electrodes. By combining lithium with an oxidizer, one can obtain an energy and electromotive force higher than with any other electrochemical couple. The density of lithium is low (0.534 g/cm{sup 3}) and thus, its specific capacity is higher than other classical anode materials. This article presents the technology of lithium batteries: 1 - presentation; 2 - negative electrodes: metallic lithium based, lithiated carbon based, transition metal compounds based negative electrodes; 3 - positive electrodes: 'low' voltage and 'high' voltage cathode materials; 4 - electrolytes: introduction, organic solvents and lithium salts-based electrolytes (case of the lithium anode battery, case of the lithium-ion battery), polymer ...

International Nuclear Information System (INIS)

The nature of the electrolyte strongly influences the electrode kinetics of the oxygen evolution reaction (OER) and electrochemical ozone production (EOP) mainly by affecting the degree of coverage by the intermediates of both processes. The anomalous behaviour of the Tafel coefficient, b, as a function of temperature was attributed to surface adsorption of the electrolyte species, and the competition between them, as well as gas bubble adherence. Comparison of the current efficiencies of the EOP, PHI_E_O_P, determined for different temperatures and supporting electrolyte compositions, showed the presence of fluorinated anions increases PHI_E_O_P. The influence of the anion nature on PHI_E_O_P, when analysed in the light of the proposed electrode mechanism, reveals introduction into the electrolyte of anions having a high electronegativity changes the double layer structure resulting in an increase of ...

Energy Technology Data Exchange (ETDEWEB)

We report synthesis, characterization and ion transport in polyether-based ionic melt electrolytes consisting of Li salts of low-basicity anions covalently attached to polyether oligomers. Purity of the materials was investigated by HPLC analysis and electrospray ionization mass spectrometry. The highest ionic conductivity of 7.1 x 10{sup -6} S/cm at 30 deg. C was obtained for the sample consisting of a lithium salt of an arylfluorosulfonimide anion attached to a polyether oligomer with an ethyleneoxide (EO) to lithium ratio of 12. The conductivity order of various ionic melts having different polyether chain lengths suggests that at higher EO:Li ratios the conductivity of the electrolytes at room temperature is determined in part by the amount of crystallization of the polyether portion of the ionic melt.

Science.gov (United States)

Several commercially available capacitors were evaluated at the liquid nitrogen temperature (77 K). Our primary interest was their performance under a bias voltage when used as DC link capacitors in cryogenic power electronics. In general, the performance of polymer capacitors and certain ceramic capacitors is almost independent of the temperature, DC bias, and frequency. On the other hand, ceramic capacitors based on high dielectric constant materials showed a strong dependence on the boundary conditions. Aluminum electrolytic capacitors showed a dramatic decrease of capacitance at 77 K, possibly due to the electrolyte being frozen and therefore losing its conductivity.

UK PubMed Central (United Kingdom)

BackgroundA combination of levodopa (L-DOPA) and carbidopa is the most commonly-used treatment for symptom management in Parkinson's disease. Studies have shown that concomitant...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Lithium metal-polymer electrolyte batteries with improved utilisation of the active material at a moderate-low temperature (65degC) were realised. Low molecular weight poly(ethylene glycol) (PEG, MW=2000) was used as the lithium-ion conductive matrix in the composite cathode. The cathode active material was crystalline V{sub 2}O{sub 5}. A blend of poly(ethylene oxide) (PEO, MW=4x10{sup 6}) and PEG was used as a solid polymer electrolyte (SPE). The transport properties of the SPE were evaluated at various temperatures. A specific conductivity as high as 1.0x10{sup -4} S cm{sup -1} was calculated at 45degC. The temperature dependence of the interfacial resistances between lithium/SPE and cathode material/PEG was evaluated. The lithium/SPE interfacial resistance decreases linearly with the temperature. The charge transfer resistance between cathode material and PEG ...

International Nuclear Information System (INIS)

Pitting corrosion is a kind of electrolytic corrosion by which the surface of a material is locally affected owing to inhomogeneities on the part of the material or medium. The paper deals briefly with questions relating to the importance, to parameters medium or materialwise, influence on production and construction, as well as the general conditions for pitting corrosion. In particular oxygen corrosion in unalloyed and low-alloy steel, and pitting corrosion in ferritic chromium-steel and austenitic chromium-nickel (molybdenum) steel is described. (DG).

Energy Technology Data Exchange (ETDEWEB)

The project has been developing Yttria Stabilized Zirconia (YSZ)-Alumina Composites as an electrolyte of a self-support type planar Solid Oxide Fuel Cell (SOFC) from the following points of view: a path of alumina particles with high thermal conductivity can be designed as an electrolyte sheet; there are some possibilities that the electrolyte can be enhanced in mechanical strength. As previously reported, these composite materials have higher mechanical strength and better thermal shock resistance than those of YSZ. These composites containing 0-30 wt% of Al[sub 2]O[sub 3] were measured by AC impedance method at temperatures of 250-1,000[degree]C. Electrical conductivities of 8YSZ without Al[sub 2]O[sub 3] and a composite consisting of 80 wt% YSZ and 20 wt%Al[sub 2]O[sub 3] as sintered samples were 1.2 x 10[sup -1]S/cm and 1.0 x 10[sup -1]S/cm respectively at 1,000[degree]C. The composite containing 20 ...

Energy Technology Data Exchange (ETDEWEB)

The confocal Raman micro-spectroscopy has been used for the study of a Lithium/polymer electrolyte-LiTFSI/V{sub 2}O{sub 5} type battery in which the polymer electrolyte thickness is of about 80 {mu}m. The analysis is performed on the side of the battery thanks to a specially designed cell which preserves all the characteristics of the real system. The analysis is performed on 20 points aligned between the anode and the cathode and with a depth of several tenth of {mu}m. The analysis of data obtained during charging/output cycles allows to evaluate the gradients of salt concentration inside the electrolyte, the pollutions of LiOH, Li{sub 2}CO{sub 3}, Li{sub 2}O and Li{sub 3}N -type at the lithium interface, but also the structural modifications of the cathode material. The in-situ study of concentration gradients inside the electrolyte is of prime importance for the understanding of ...

Science.gov (United States)

... Accession Number : ADD872506. Title : ALUMINUM ELECTROLYTIC CAPACITORS. Corporate Author : Personal Author ...

Science.gov (United States)

The Energy crisis happens to be one of the greatest challenges we are facing today. In this view, much effort has been made in developing new, cost effective, environmentally friendly energy conversion and storage devices. The performance of such devices is fundamentally related to material properties. Hence, innovative materials engineering is important in solving the energy crisis problem. One such innovation in materials engineering is porous materials for energy storage. Porous electrode materials for lithium-ion batteries (LIBs) offer a high degree of electrolyte-electrode wettability, thus enhancing the electrochemical activity within the material. Among the porous materials, mesoporous materials draw special attention, owing to shorter diffusion lengths for Li+ and electronic movement. ...

International Nuclear Information System (INIS)

An effective method of enhancing charge injection and electroluminescence efficiency of polymer-based light emitting diode is introduced. Spin-coated films of poly (N-vinylcarbazole) blended with electron-transport material (Bu-PBD), laser dye (Coumarin6), and the typical supporting electrolyte (tetraethylammonium perchlorate; TEAP) were examined and it was found that the injection current and luminance of the light emitting diode doped with TEAP were enhanced dramatically after heat-treatment at 80 deg. C and appropriate biasing in an external electric field of 1.5x10"8 V/m at this temperature. The thermally stimulated current (TSC) was also measured to investigate the relaxation process of ionic space charges in the films. The relaxation times of ionic polarization were found to be related to the cation size of the electrolyte. And the relaxation time becomes long enough by the use of TEAP doping.

British Library Electronic Table of Contents (United Kingdom)

ObjectivesTo assess the influence of epigallocatechin-3-gallate (EGCG) on the efficacy of ionizing radiation on prostate cancer cells because of the increased use of dietary interventions, especially by patients with prostate cancer. Radiotherapy is used to treat localized prostate cancer. Some people consume green tea (EGCG) as a chemopreventive agent against prostate cancer. Green tea can act as an antioxidant and induce superoxide dismutase enzymes, which could scavenge the free oxygen radicals generated by radiotherapy. MethodsProstate cancer cell line DU145 cells were treated with EGCG or radiotherapy, or both. Cell death was assessed using trypan blue cell counting, and apoptosis was confirmed by assessing poly (adenosine phosphate ribose) polymerase cleavage. The antioxidant potenti...

Energy Technology Data Exchange (ETDEWEB)

A rechargeable cell is disclosed which is characterized in the following manner. A positive electrode is formed from a manganese oxide electrode material. This manganese oxide electrode material contains a heavy metal selected from the group comprising lead, bismuth, and mixtures of lead and bismuth. The cell also contains a negative electrode of zinc. A separator is provided between the positive electrode and the negative electrode. An alkaline electrolyte consisting essentially of an alcohol and an alkaline hydroxide is also contained in the rechargeable cell in contact with both the positive electrode and the negative electrode.

Energy Technology Data Exchange (ETDEWEB)

{gamma}-Butyrolactone-based electrolytes have been used as the operating electrolytes for aluminum electrolytic capacitors. The chemical stability of these electrolytes at elevated temperatures has been examined by monitoring the decrease in their electrolytic conductivities. The deteriorated electrolytes were analyzed by gas and liquid chromatography and the conductivity decrease was directly correlated with the loss of acid components. In quaternary ammonium hydrogen maleate/{gamma}-butyrolactone electrolytes, the maleate anion decomposed by decarboxylation resulting in a complex polymer containing polyester and polyacrylate structures. Quaternary ammonium benzoate/{gamma}-butyrolactone electrolytes decomposed by SN2 reactions giving alkyl benzoates and trialkylamines. The deterioration of the carboxylate ...

Science.gov (United States)

... Accession Number : ADD872708. Title : ALUMINUM ELECTROLYTIC CAPACITORS FOR HIGH FREQUENCY APPLICATIONS. Corporate Author : ...

UK PubMed Central (United Kingdom)

IntroductionThe major risk factor for osteoarthritis (OA) is aging, but the mechanisms underlying this risk are only partly understood. Age-related accumulation of advanced glycation...Full Text Available

UK PubMed Central (United Kingdom)

The ζ chain-associated 70-kDa protein (ZAP-70) of tyrosine kinase plays a critical role in T cell receptor-mediated signal transduction and the immune response. A high level of ZAP-70 expression...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

This paper deals with the preparation and characterization of polyaniline/TiO{sub 2} composite by XRD, UV-VIS spectra, TGA/DTA and FTIR. The composite is used as a cathode material for rechargeable battery comprising of zinc container as the anode, cellulose acetate as the separator and polyvinyl sulfate and carboxy methyl cellulose as the solid polymer electrolytes (SPE). By using the PAn/TiO{sub 2} composite as the cathode material, the cylindrical AA type rechargeable battery was fabricated and the following output was observed. The open circuit voltage (OCV) is 1.4 V and current is 250 mA to 1.0 A, 50 recharge cycles, power density is 350 A h/kg and power efficiency is 70%.

British Library Electronic Table of Contents (United Kingdom)

Porous SnO2 nanotubes were prepared via electrospinning followed by calcination in air. As anode materials for lithium ion batteries, the porous nanotubes delivered a high discharge capacity of 807mAhg^-^1 after 50cycles. Even after cycled at high rates, the electrode still retained a high fraction of its theoretical capacity. Such excellent performances of porous SnO2 nanotubes could be attributed to the porous and hollow structure which facilitated liquid electrolyte diffusion into the bulk materials and buffered large volume changes during lithium ions insertion/extraction. Furthermore, the nanoparticles of nanotubes provided the shorter diffusion length for lithium ions insertion which benefited in retaining the structural stability and good rate performance. Our results demonstrated t...

British Library Electronic Table of Contents (United Kingdom)

Sm"1"."8Ce"0"."2CuO"4-xCe"0"."9Gd"0"."1O"1"."9"5 (SCC-xCGO, x=0-12vol.%) composite cathodes supported on Ce"0"."9Gd"0"."1O"1"."9"5 (CGO) electrolyte are studied for applications in IT-SOFCs. Results show that Sm"1"."8Ce"0"."2CuO"4 material is chemically compatible with Ce"0"."9Gd"0"."1O"1"."9"5 at 1000^oC. The composite electrode exhibits optimum microstructure and forms good contact with the electrolyte after sintering at 1000^oC for 4h. The polarization resistance (R"p) reduces to the minimum value of 0.17@Wcm^2 at 750^oC in air for SCC-CGO06 composite cathode. The relationship between R"p and oxygen partial pressure indicates that the reaction rate-limiting step is the surface diffusion of the dissociative adsorbed oxygen on the composite cathode.

Science.gov (United States)

Measurements of PEM fuel cell device performance were made with different gas inlet temperatures and relative humidity using a newly-designed test fixture. Significant improvement in device performance was observed when the fuel inlet temperature was increased above the operating temperature of the cell. These measurements were then correlated to a model to describe energy and mass transport processes. Proton exchange membrane (PEM), fuel cells--the focus of this study--use an ion conducting polymer, especially polyperfluorosulfonic acid materials. These polymer materials, when imbibed with water, exhibit solution-like properties, but because the anions are chemically bound to the polymeric structure, the electrolyte is contained. Importantly, product water removal is simplified, as electrolyte dilution is not a concern. However, the proton transport rate is a function of the polymer geometry, which is ...

International Nuclear Information System (INIS)

Oxide ionic conductivities of (CeO_2)_x(Sc_2O_3)_(_0_._1_1_-_x_)(ZrO_2)_0_._8_9 (x = 0.01-0.10) electrolytes were optimized for the application in intermediate-temperature solid oxide fuel cell (IT-SOFC). Powders with different contents of CeO_2 and Sc_2O_3 were prepared via a co-precipitation method. The obtained powders and pellets were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and impedance spectroscopy. Among all the compositions, (CeO_2)_0_._0_4(Sc_2O_3)_0_._0_7(ZrO_2)_0_._8_9(4Ce7ScZr) gives the highest ionic conductivity of 0.065 S cm"-"1 at 800 "oC. The effects on densification and electrical properties of different sintering additives, such as SiO_2, MgO, Co_3O_4, MoO_3 and Bi_2O_3, were studied and different conducting behavior with these additives were observed. The densification temperatures of CeO_2 and Sc_2O_3 co-doped electrolytes can be reduced by around ...

Science.gov (United States)

The possibility of using lead and lead-bismuth mixed oxides as positive active materials in organic electrolyte lithium cells with a working voltage similar to those of silver zinc cells has been considered. Button cells of SR 44 size have been developed as a test vehicle and studied under various conditions of discharge rate and storage. This paper describes the performance characteristics obtained under these conditions and suggests in conclusion the possible replacement of silver zinc cells by such systems for a large range of low-rate applications on the basis of cost effectiveness.

Science.gov (United States)

Intermetallic compounds are regarded as highly promising for applications as high temperature structural materials. However, recent studies have demonstrated that a number of ordered alloys exhibit environmental embrittlement when tested in various environments at ambient temperature. When exposed to hydrogen gas or electrolytically charged with hydrogen, a significant ductility loss has been reported. The reaction of water vapor with reactive elements in the crack tip results in the generation of atomic hydrogen which diffuses from the surface to the interior and causes embrittlement. In this paper, the authors try to analyze the sensitivity of hydrogen embrittlement of ordered alloys based upon energetical considerations.

Energy Technology Data Exchange (ETDEWEB)

The following method is proposed as a supplement to main patent 2419107, which deals with the filling of tubular plates surrounding the lead cores: the flat materials which are used to produce the jacket tubes are prepared before forming into jacket tubes by a film producing aqueous carboxy-methyl cellulose solution closing the pores. The preparation can be done by coating the flat material with a soluble foil. After pressing the paste in, the tubular plates are dried and after cooling are dipped into sulphuric acid with a specific gravity of 1.24 g/cm/sup 3/. The carboxy-methyl cellulose is dissolved and the permeability of the tube walls for electrolyte is restored after only 15 minutes.

Energy Technology Data Exchange (ETDEWEB)

The electrochemical metal dissolution of 100Cr6 steel in sodium chloride solution, applying high electrolyte flow rates and high current densities, has been studied with a view to the influence of material heterogeneities such as carbide segregation lines in the steel matrix. It was shown that the presence of such segregations is responsible for the formation of troughs on the specimen surface during electrochemical dissolution. A mechanism for trough formation was proposed. A dedicated heat treatment applied to the 100Cr6 steel eliminated the carbide segregation lines and established a soft annealed, fine-grained microstructure containing globular carbides. Subsequent electrochemical dissolution did not show any development of surface irregularities as troughs. (orig.)

Energy Technology Data Exchange (ETDEWEB)

The paper describes a lithium battery researched on under the Moonlight Project which is a long life secondary battery with high energy density and high power density. Using as a base a Li4SiO4 system which exhibits stable and high Li[sup +] conductivity as solid electrolyte material, partial Si[sup 4+] is replaced with divalent ions such as B[sup 3+] and Al[sup 3+] or divalent ions such as Ni[sup 2+] and Co[sup 2+], by which Li[sup +] for electric charge compensation can be increased and conductivity is enhanced. As to a LiTi2P3O12 system, Ti[sup 4+] is replaced with Sc[sup 3+] and Y[sup 3+]. In both systems, by replaCing Si[sup 4+] or Ti[sup 4+] with trivalent metal ions and increasing mobile Li[sup +], those with ion conductivity exceeding that at 300[degree]C, 10[sup -3]Scm[sup -1], can be developed. TiS2 and NiPS3 are prepared as cathode material and miniature cells are trially fabricated. Various polarization ...

British Library Electronic Table of Contents (United Kingdom)

In this research, new thin freestanding films of poly(methyl methacrylate) (PMMA)/50% epoxidised natural rubber (ENR 50) were doped with lithium triflate, LiCF3SO3 salt was prepared by a solvent casting method. The incorporation of ENR 50 is found to increase the conductivity of PMMA/LiCF3SO3 by two orders of magnitude at room temperature. The highest conductivity achieved was 5.09x10-5Scm-1 at room temperature when 60% of LiCF3SO3 salt was introduced into the PMMA blend containing 10% ENR 50. The formation of excessive hydrogen bonds and interchain crosslinking limit the performance of the blend at higher concentrations of ENR 50. The ionic conduction mechanisms in PMMA/ENR 50/LiCF3SO3 electrolytes obey the Arrhenius rule in which the ion transport in these materials is thermally assisted...

Energy Technology Data Exchange (ETDEWEB)

A great amount of naturally produced manganese dioxide has been widely used as cell active material since 1880's, but nowadays synthetic manganese dioxides such as electrolytic manganese dioxides (EMD) and chemically prepared manganese dioxides (CMD), etc. are used therefor and cell performances have considerably been improved. The synthetic manganese dioxides which are being used widely as the above cell active materials are active materials designed and reformed as manganese-oxygen-proton based active materials. In this study, electrochemical behaviors of synthetic manganese dioxides (layered manganese dioxides and spinel-related manganese dioxides) were examined in a 1MLiClO4 propylene carbonate/tetrahydrofuran (1:1) solution. A discharge curve shown by the layered manganese dioxide presented a distorted S-shape and that of the spinel-related manganese dioxide showed the ...

Science.gov (United States)

aluminum electrolytic capacitors with Freon, trichloroethylene, carbon tetrachloride, or other chlorine or fluorine solvents. Aluminum electrolytic ...

Energy Technology Data Exchange (ETDEWEB)

During past two decades, the importance of rechargeable lithium cells has been emphasized and a large variety of materials has been discovered and evaluated for use as reversible cathodes and electrolytes. Materials that undergo intercalation or topochemical reactions with lithium have been investigated as candidates for cathodes in nonaqueous secondary lithium cells (1). Recent interest in researching cathode active materials has mainly focussed on crystalline transition metal chalcogenides. On the other hand, electrochemical behaviors of several amorphous materials have been reported, for example MoS/sub 2/,MoS/sub 3/,V/sub 2/S/sub 5/ (2) and LiV/sub 3/O/sub 8/ (3). However, no successful cycling behavior has been obtained except for MoS/sub 2/ in the amorphous state. This paper reports electrochemical data on rechargeable vanadate glasses in the system V/sub 2/O/sub 5/-P/sub ...

Energy Technology Data Exchange (ETDEWEB)

Secondary energy can be described as a surplus of electrical energy in a hydropower because the lower demand of energy in some period of the day and the excess of water in the reservoir during the rainy periods. This study proposes the using of the excess of energy at Itaipu Bi nacional for electrolytically hydrogen production and ammonia for nitrogenous fertilizers. Ammonia is a raw material for nitrogenous fertilizers synthesis and produced using hydrogen and nitrogen from the atmosphere. This paper determines the minimal cost of hydrogen production and the capacity of hydrogen production, with this data and according the ammonia market for nitrogenous fertilizers in the Centre/South region was estimated the better capacity of ammonia production for one plant near Itaipu. The process of ammonia production using energy excess is the most environmental acceptable. (author)

British Library Electronic Table of Contents (United Kingdom)

In this paper we demonstrate the electrodeposition of nickel, a common ferromagnetic material, in various magnetically desirable shapes including nanowires, nanoparticles and highly faceted shells. In order to obtain three dimensional mesostructures, the electrochemical deposition of nickel was performed on highly oriented pyrolytic graphite (HOPG) under different electrolyte composition and deposition potential conditions. Under potentiostatic deposition at one distinct potential negative with respect to the reversible potential of nickel, three stages of nucleation and growth take place leading to a complex morphology of deposits. However, dual-pulse potential deposition and electrodeposition in low pH solutions causing hydrogen evolution, lead to nickel deposits in the form of nanowires...

Energy Technology Data Exchange (ETDEWEB)

In recent years, interest in the development of a polymer electrolyte fuel cell (PEFC) has considerably increased due to its advantages (e.g., high power density) compared with other fuel cell systems, and its potentials to become the power plant for the next generation, nonpolluting automobile engine. For large scale application of fuel cells, low platinum loading electrode structures are necessary. An electrode based on a highly porous carbonized polyacrylonitrile foam material with very low platinum loading ({approximately} 13 {micro}g/cm{sup 2}) was prepared. The performance of this electrode for oxygen reduction was evaluated and compared with bulk platinum and glassy carbon electrodes.

International Nuclear Information System (INIS)

Alloy 690 and Alloy600 are used as a material for the steam generator tubing in the pressurized water reactor(PWR) of nuclear power plants due to its high corrosion resistance. Although those are a highly corrosion resistance material, their stress corrosion cracking(SCC) have been found on occasion, which are deeply related to a surface oxide film on a base material which have occurred on the primary side as well as the secondary side of a tubing. And The SCC is accelerated in the existing Pb which is the impurity of secondary steam generator components. The Oxide on a steel surface in an aqueous solution above 100 .deg. C is composed of a duplex film structure. The inner layer of the oxide is dense and less porous, which is formed by a growth of the oxide layer on the metal surface. The outer layer of the oxide is less adhesive, which is formed by a dissolution and precipitation mechanism. Growth processes of the inner ...

International Nuclear Information System (INIS)

Laser glazing, using a KrF excimer laser (> = 248 nm, >a = 22 ns), has been used to improve the corrosion resistance properties of crystallized Fe_4_0Ni_3_8Mo_4B_1_8 (Metglas 2826 MB) and the permanent magnet material Nd_1_5Fe_7_7B_8. The formation of an amorphous layer was confirmed by conversion-electron Mossbauer Spectroscopy (CEMS), and the thickness of the amorphous layer was determined from the attenuation of the x-rays diffracted from the underlying crystalline material. The variation with laser fluence of the amorphous layer thickness on the Metglas were measured. The corrosion properties of the original, crystalline and laser glazed Metglas were measured potentiodynamically in acid electrolyte. Similar voltametric characteristics were obtained for the laser glazed surface and original Metglas, both showing a lower current in the passive region than the crystalline material. Laser glazing ...

Energy Technology Data Exchange (ETDEWEB)

A solid electrolytic capacitor having a solid electrolyte comprising manganese dioxide dispersed in an aromatic polyamide capable of further cure to form polyimide linkages, the solid electrolyte being disposed between a first electrode made of valve metal covered by an anodic oxide film and a second electrode opposite the first electrode. The electrolyte autogenously produces water, oxygen, and hydroxyl groups which act as healing substances and is not itself produced pyrolytically. Reduction of the manganese dioxide and the water molecules released by formation of imide linkages result in substantially improved self-healing of anodic dielectric layer defects.

Energy Technology Data Exchange (ETDEWEB)

Ionic conductive materials are of much interest as an electrolyte for solid-state lithium batteries. Poly(alkylene oxide) and lithium salt complex exhibits high ionic conductivity in terms of its high solubility for lithium salts. However, the temperature dependency of its ionic conductivity is quite large and non-linear, the ionic conductivity drops down at low temperature, especially below glass transition temperature of the polymer. Because its ionic conductive mechanism is derived from its segmental motion of polymer main chain. A novel ionic conductive material, poly[2,6-dimethoxy-N-(4-vinylphenyl)benzamide] is synthesized and confirm ionic conductivity even below glass transition temperature. Ionic conductivity of the polymer with lithium ditrifluoromethylsulfonate imide complex shows 10{sup -5}Scm{sup -1} from 0 to 60{sup o}C. Its temperature dependency is linear, namely Arrehnius type dependency. Evaluating from ...

International Nuclear Information System (INIS)

The aim of this work was to compare the electrochemical behaviors and safety performance of graphite and the lithium titanate spinel Li1.33Ti1.67O4 with half-cells versus Li metal. Their electrochemical properties in 1 M LiPF6/EC + DEC (1:1 w/w) or 1 M LiPF6/PC + DEC (1:1 w/w) at room and elevated temperatures (30 and 60 deg C) have been studied using galvanostatic cycling. At 30 deg C graphite has higher reversible capacity than Li1.33Ti1.67O4 when using the LiPF6/EC + DEC as electrolyte. At 60 deg C graphite declines in cell capacity yet Li1.33Ti1.67O4 remains almost unchanged. In a propylene carbonate (PC) containing electrolyte, graphite electrode exfoliates and loses its mechanical integrity while Li1.33Ti1.67O4 electrode is very stable. An accelerating rate calorimeter (ARC) and microcalorimeter have been used to compare the thermal stability of lithiated lithium titanate spinel and graphite. Results show that Li1.33Ti1.67O4 may be used ...

Energy Technology Data Exchange (ETDEWEB)

It is well known that a protective film is formed on the graphite negative electrode in ethylene carbonate (EC) electrolyte solution. This film is lithium-ion conductive and protects the decomposition of the electrolyte solution. In the present paper, the electrode/electrolyte interfaces in lithium-ion rechargeable batteries were characterized by three-dimensional complex impedance plots, whose axes are real, imaginary parts and time. The film resistance R {sub sei} and charge transfer resistance R {sub ct} were determined for negative electrodes in EC/ethyl methyl carbonate (EMC) electrolyte solution, and the formation mechanisms of the interfacial film were discussed. Furthermore, the contributions of vinylene carbonate and ethylene sulfite, which are added into the electrolyte solution for the film formation, were investigated.

Energy Technology Data Exchange (ETDEWEB)

ABO{sub 3} perovskite-type oxides having vacancies in the A-sites of their structure are interesting candidates for solid electrolytes when their A-sites are occupied by Li{sup +} ions having a high mobility. This is the case with the [Li{sub 3x}La{sub 2/3-x}]TiO{sub 3} solid solution compound which has a 10{sup -3} S cm{sup -1} ionic conductivity at ambient temperature. Electrochemical intercalation in this material is possible thanks to the presence of Ti{sup 4+} but the small amount of vacancies (0.33 maximum) leads to a low intercalation rate. In order to solve this problem, the LiLaNb{sub 2}O{sub 7} material which has a greater amount of vacancies has been studied and the results relative to the electrochemical intercalation of lithium in this perovskite are presented. The thermodynamical and kinetics properties of the lithium intercalation reaction have been studied by intermittent galvano-static discharges and ...

Energy Technology Data Exchange (ETDEWEB)

Triethanolamine (TEA) has been evaluated as an additive to a commercial electrolyte to enhance the properties of aluminum electrolytic capacitors. The results showed 1-3wt.% TEA additive can prevent the pH and conductivity of the electrolytes from decreasing for 5000h at 60{sup o}C. The anodic restoration ability of an anode aluminum film in the electrolyte with TEA additive showed more efficient than the electrolyte without TEA additive. Low temperature electric characteristics of capacitors showed that TEA additive can prevent the electrolyte inside capacitors from freezing and losing electric characteristics even at -40{sup o}C. Load life test of capacitors impregnated with electrolytes with or without TEA additive showed remarkable differences. The TEA additive promoted 105{sup o}C load life time from 3019h up to 5624h and form 2144h up ...

Science.gov (United States)

... This pinhole process may be similar to the formation of an oxide layer in aluminum electrolytic capacitors immersed in a borax solution. ...

Science.gov (United States)

Aluminum electrolytic capacitors are presently not allowed on NASA missions because they outgas water and organic vapors, as well as H2. As a consequence, much larger and heavier packages of tantalum capacitors are used. A hermetically sealed aluminum capacitor has been developed under NASA-MSFC SBIR contracts. This capacitor contains a nongassing electrolyte that was developed for this application so internal pressure would remain low. Capacitors rated at 250 to 540 V have been operated under full load for thousands of hours at 85 and 105 C with good electrical performance and low internal pressure. Electrolyte chemistry and seal engineering concepts will be discussed.

Science.gov (United States)

... Aluminum electrolytic capacitors have improved through the years. They are smaller, and equivalent series resistance (ESR) is improved. ...

Science.gov (United States)

Aluminum electrolytic capacitors have a long history of reliable operation in unattended field sites. However, their use in the expected space applications ...

International Nuclear Information System (INIS)

BaZr_0_._1Ce_0_._7Y_0_._2O_3_-_#delta# (BZCY7) exhibits adequate proton conductivity as well as sufficient chemical and thermal stability over a wide range of SOFC operating conditions, while layered GdBa_0_._5Sr_0_._5Co_2O_5_+_#delta# (GBSC) perovskite deposited on a doped ceria electrolyte demonstrates advanced electrochemical properties. This research fully takes advantage of these advanced properties and develops novel protonic ceramic membrane fuel cells (PCMFCs) of Ni-BZCY7|BZCY7|GBSC. The results show that the open-circuit potential of 1.003 V, maximum power density of 430 mW cm"-"2, and a low polarization resistance of the electrodes of 0.08 #OMEGA# cm"2 are achieved at 700 "oC. With temperature increases, the total cell resistance decreases, among which electrolyte resistance becomes increasingly dominant over polarization resistance. The results also indicate that GBSC perovskite cathode is a good candidate for intermediate ...

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MnO powder materials are investigated as anode active materials for Li-ion batteries. Lithium is stored reversibly in MnO through conversion reaction and interfacial charging mechanism, according to the results of ex situ XRD, TEM and galvanostatic intermittent titration technique. A layer of the solid electrolyte interphase with a thickness of 20-60 nm is covered on MnO particles after full insertion. MnO powder materials show reversible capacity of 650 mAh g{sup -1} with average charging voltage of 1.2 V. It can deliver 400 mAh g{sup -1} at a rate of 400 mA g{sup -1}. The cyclic performance of MnO is improved significantly after decreasing particle size and coating with a layer of carbon. Among observed transition metal oxides, MnO shows relatively lower voltage hysteresis (<0.7 V) between the discharging and the charging curves at 0.05 C. In addition to its environmental benign feature and ...

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A zinc-air battery in a case is described including a zinc particle bed supported adjacent the current feeder and diaphragm on a porous support plate which holds the particles but passes electrolyte solution. Electrolyte is recycled through a conduit between the support plate and top of the bed by convective forces created by a density of differential caused by a higher concentration of high density discharge products in the interstices of the bed than in the electrolyte recycle conduit. 7 figures.

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This document reports the progress and accomplishments of a 16 month program to develop a rechargeable zinc-air battery for electric vehicle propulsion, from October 1988 through January 1990. The program was the first stage in the transition of alkaline zinc electrode technology, invented at Lawrence Berkeley Laboratory, to private industry. The LBL invention teaches the use of a copper metal foam substrate for the zinc electrode, in combination with forced convection of electrolyte through the foam during battery operation. Research at LBL showed promise that this approach would avoid shape change (densification and dendrite growth), the primary failure mode of this electrode. The program comprised five tasks; (1) cell design, (2) capacity maximization, (3) cycle testing, (4) materials qualification, and (5) a cost/design study. The cell design contemplates a plate and frame stack, with alternating zinc and oxygen electrode frame assemblies ...

British Library Electronic Table of Contents (United Kingdom)

Abstract The present work, regarding the determination of ultratrace Os(VIII), Ru(III) and Ir(III) in superficial waters is an interesting example of the possibility to simultaneously, or better sequentially determine each single element in real samples by voltammetry. The method is based on the catalytic current of the Os(VIII)- and Ru(III)-bromate systems by square wave voltammetry and on the Ir(III) determination by square wave catalytic adsorptive stripping voltammetry. 0.5-mol-L-1 acetate buffer pH-4.9+7.710-2-mol-L-1 NaBrO3 and 0.5-mol-L-1 acetate buffer pH-4.9+7.710-2-mol-L-1 NaBrO3+2.310-5-mol-L-1 cetyltrimethylammonium bromide (CTAB) +0.2-mol-L-1 KCl were employed as the supporting electrolytes. The analytical procedure was verified by the analysis of the standard reference materi...

International Nuclear Information System (INIS)

Sulfonated poly(ether ether ketone) (SPEEK) membranes with various degrees of sulfonation (DS) have been prepared as a potential membrane material for proton exchange membrane by sulfonation process using mixtures of (15-30% concentration) fuming sulfuric acid and (95-98%) concentrated sulfuric acid as the sulfonating agent. The sulfonation process was conducted at room temperature by varying the acid ratio and reaction time. The produced membranes were then characterized by evaluating the ion exchange capacity (IEC), water uptake, thermal stability, proton conductivity and methanol permeability as a function of degree of sulfonation. The proton conductivity of the sulfonated PEEK membranes with various DS was within the magnitude of 10"-"3 and 10"-"2 S cm"-"1 at room temperature and the methanol permeability was in the range of 3.45 x 10"-"7 to 2.73 x 10"-"6 cm"2 s"-"1. The overall membrane performance of the SPEEK membrane with 80% DS was six times higher than ...

British Library Electronic Table of Contents (United Kingdom)

An extremely sensitive stripping voltammetric procedure for ultra-trace determination of iridium(III) is reported. The method is based on the interfacial accumulation of the iridium(III)-CTAB complex onto the glassy carbon electrode, followed by the catalytic reduction of the adsorbed complex in the presence of bromate. 0.3molL^-^1 acetate buffer pH 4.7+6.9x10^-^2molL^-^1 NaBrO3+2.7x10^-^5molL^-^1 cetyltrimethylammonium bromide (CTAB)+0.2molL^-^1 KCl was employed as the supporting electrolyte. The analytical procedure was verified by the analysis of the standard reference materials: Sea Water BCR-CRM 403 and Fresh Water NIST-SRM 1643d. The accuracy, expressed as relative error e%, was satisfactory, being lower than 6%, while precision as repeatability, expressed as relative standard deviat...

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For the development of high ionic conductive solid electrolyte, LiTi2(PO4)3 (LTP), one of the promising inorganic solid electrolyte, was synthesized to investigate an effect of additional lithium salt on the ion conductivity. Lithium salt added LTP composite electrolyte sintered at 900{degree}C exhibited highest conductivity, which was two order magnitude higher than pure LTP. Effects of lithium salt addition are as follows. Conductivity of the composite electrolyte provided larger sintering temperature dependence than the pure LTP. From X-ray diffraction analysis, structures and compositions were resemble between two composite electrolytes. Byproducts except LTP provided rather low conductivity. It was suggested that melted constitution in the composite can affect the sintering improvement by the additional lithium salt at temperatures over 800 {degree}C. From the observation of ...

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A family of mixed LiCo{sub y}Ni{sub (1-y)}VO{sub 4} (y=0.2, 0.5 and 0.8) compounds of potential use as high voltage cathode materials in lithium batteries, has been synthesized and characterized. The X-ray diffraction analysis showed that these compounds adopt an inverse spinel structure where in average 85% of the Ni{sup 2+} and Co{sup 2+} ions occupy octahedral sites and the other 15% occupy tetrahedral sites with the V{sup 5+} ions, although this occupation share is somewhat influenced by the preparation temperature. The annealing temperature plays also a key role in determining the particle size, as demonstrated by scanning electron microscope analysis. Cycling voltammetry tests showed that the lithium insertion-deinsertion process in the LiCo{sub y}Ni{sub (1-y)}VO{sub 4} electrode materials occurs reversibly around 4.3-4.4 V vs. Li, as also confirmed by cycling tests. The cycling capacity is somewhat modest; however, the trend of the ...

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The possibilities to electrodeposit thick coatings composed of nanoparticles of Sb and Sb{sub 2}O{sub 3} for use as high-capacity anode materials in Li-ion batteries have been investigated. It is demonstrated that the stability of the coatings depends on their Sb{sub 2}O{sub 3} concentrations as well as microstructure. The electrodeposition reactions in electrolytes with different pH and buffer capacities were studied using chronopotentiometry and electrochemical quartz crystal microbalance measurements. The obtained deposits, which were characterised with XRD and SEM, were also tested as anode materials in Li-ion batteries. The influence of the pH and buffer capacity of the deposition solution on the composition and particle size of the deposits were studied and it is concluded that depositions from a poorly buffered solution of antimony-tartrate give rise to good anode materials due to the inclusion ...

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Polysaccharides like cellulose and chitosan are known for their filmic properties. This paper concerns the synthesis and the study of chitosan-based polymer electrolytes. A preliminary work concerns the study of glucosamine reactivity. The poly-condensation of chitosan ethers (obtained by reaction with ethylene oxide or propylene oxide) with bifunctional and monofunctional oligo-ethers leads to the formation of thin lattices (10 {mu}m) having excellent mechanical properties. The presence of grafted polyether chains along the polysaccharide skeleton allows to modify the vitreous transition temperature and the molecular disorder of the system. Two type of polymer electrolytes have been synthesized: electrolytes carrying a dissolved alkaline metal salt and ionomers. The analysis of their thermal, dynamical mechanical, nuclear magnetic relaxation, electrical, and electrochemical properties shows that this new class of polymer ...

International Nuclear Information System (INIS)

A helium-3 proportional detector was equipped with the experiment of Liaw-type electrolytic cell contained eutectic LiCl-KCl molten salt saturated by LiD electrolytic to collect the informations of the rate and the energy distribution of possible neutron produced during the electrolysis processes. For long time monitoring, the significant reproducible neutron bursts appeared at several runs of cells during electrolytic processing. The neutron counting rate increased about a factor of two above the level of the background measurement. The pulse height signals were verified of neutron energy ranging from thermal up to 350 keV. (author).

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The electrolyte was brought into contact with air and potassium carbonate was measured with various contact time in order to check the defect of carbon dioxide in the air on zinc-air cell. The relationship between potassium carbonate concentration in electrolyte and battery capacity was also studied. The potassium carbonate concentration in the electrolyte. The rate of carbon dioxide absorption was mainly affected by the pore size of hydrophobic membrane. Our study showed that adapting the pore of hydrophobic membrane decreased the loss of cell discharge performance due to the presence of carbon dioxide or water vapor in the atmosphere. 7 refs., 12 figs., 1 tab.

Science.gov (United States)

Systems MEMS sensors C11-20 Lifetime Distributions of Aluminum Electrolytic Capacitors C11-22 Adhesion Strength of Advanced Polymer Films for Flexible and Rigid...

Science.gov (United States)

... The LVS bulk capacitance can be implemented using high temperature aluminum electrolytic capacitors with relatively low component volume. ...

International Nuclear Information System (INIS)

A kind of polymer-metal complex gel electrolyte is successfully prepared and is used in dye-sensitized solar cells. Raman and X-ray photoelectron spectroscopy confirm the structure of this complex and is found that the metal ion reacts with nitrogen in the polymer. This novel electrolyte shows apparent diffusion coefficient of iodide of 8.37 x 10-7 cm2 s-1 and the energy conversion efficiency of 6.10% when the amount of ZnI2 is 0.04 M. By studying the dissociation active energy of the inorganic salt in electrolytes, we find that the metal salts can dissociate more easily after reacting with polymer and as a result can provide extra free iodide ion. The cell maintains ca. 93% of its initial efficiency after 20 d without further sealing, which shows good long-time stability.

Science.gov (United States)

... o Application - Aluminum electrolytic capacitors provide the tallest voluse, mass and cost per microfarad except for tan- , talum capacitors. ...

Energy Technology Data Exchange (ETDEWEB)

The deterioration of AA2024, AA6061 and AA7475 anodised in an environmentally-compliant tartaric acid/sulphuric acid electrolyte has been examined as a function of the immersion time in the electrolyte after termination of anodising. By transmission electron microscopy and scanning electron microscopy, degradation of the porous oxide film was qualitatively observed on AA2024. Electrochemical impedance spectroscopy revealed that AA2024 and AA7075 were more sensitive to prolonged immersion in the anodising electrolyte compared with AA6061, due to increased barrier layer thinning rates and increased susceptibility to localized corrosion. Salt spray tests confirmed the previous, indicating decay of anticorrosion performance for AA2024 and AA7075.

International Nuclear Information System (INIS)

Solid oxide fuel cell (SOFC) is a promising source of power generation in terms of conversion efficiency which is higher than the conventional one, as it is not limited by the Carnot efficiency. Theoretically, the SOFC have an efficiency of the order of 60-80 % but it is limited by the number of active side available for the reaction i.e. TPB (triple phase boundary) at the electrode-electrolyte interface which depends on the particle size of the materials employed during the fabrication of SOFC components (i.e. the method employed during the synthesis). Literally, there are several methods used in the syntheses of oxide materials such as conventional solid-state reaction, co-precipitation, hydrothermal rout, sol-gel and Glycine nitrate process (GNP) but among these GNP found to be effective over the other because of homogeneity, phase purity and smaller particle size of final product. In this work, the Nano-crystalline ...

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Advanced lithium batteries presently under development operate either at the high temperatures associated with the LiCl-KCl molten salt (350-450/degree/C), or at ambient temperatures employing organic solvent based electrolytes. An intermediate temperature lithium battery is proposed as an alternative if it reduces corrosion problems present at high temperatures and improved kinetic performance with respect to ambient temperature cells. 17 refs.

International Nuclear Information System (INIS)

Analytical expression of the dependence of freezing temperature of electrolyte (CdCl_2, CdSO_4, BeSO_4) aqueous solutions on their composition was found. Three different methods were suggested were suggested for calculation of water activity in multicomponent solution. It was established that sublinear extrapolation of freezing temperature of salt aqueous solutions was possible not up to -5 deg C, but up to -15 deg C, independently of their composition. 6 refs.; 2 figs.

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Hydrogen uptake and embrittlement of tantalum by electrolytically produced hydrogen is investigated on samples of varying composition and type of pretreatment. Of decisive influence on the uptake of hydrogen are the oxide layers present on the tantalum surface. By contact with platinum group metals as alloying constituents, surface coatings or anodic protection, a protection of tantalum can be obtained depending on the experimental conditions.

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Water transport in the ionomeric membrane, typically Nafion{reg_sign}, has profound influence on the performance of the polymer electrolyte fuel cell, in terms of internal resistance and overall water balance. In this work, high resolution neutron imaging of the Nafion{reg_sign} membrane is presented in order to measure water content and through-plane gradients in situ under disparate temperature and humidification conditions.

International Nuclear Information System (INIS)

The stability constants of [AtX_2]"- with X = Cl, Br and I in ethanol and methanol as well as their ion mobilities at a temperature of 298 K and an ionic strength of 0.05 were determined by horizontal zone electromigration in homogeneous electrolyte solution. The results are compared with existing data from aqueous electrolyte systems. (author).

Energy Technology Data Exchange (ETDEWEB)

Basic properties and battery performances of the novel high temperature stable lithium salt (Li{sub 2}B{sub 12}F{sub 12}, Dilithium Dodecafluorododecaborate; Li{sub 2}DFB) were studied using a Mn-based cathode and anode composed of a hard carbon and graphite mixture. The effect of co-solvents (mainly linear carbonate in electrolyte formulation of PC/EC/co-solvent (5/30/65 vol% mixture)) on conductivity, viscosity, charge-discharge capacities, rate performance, temperature performance, cycle life and storage life at 60 C was investigated. Conductivity of Li{sub 2}DFB electrolyte increased with reducing its viscosity by changing co-solvent and increasing the volume of the higher dielectric solvent. Li{sub 2}DFB electrolytes showed comparable discharge capacity and columbic efficiency against LiPF{sub 6} electrolyte. Li{sub 2}DFB electrolytes improved the storage life and cycle life of ...

International Nuclear Information System (INIS)

Preparation of a uranous nitrate solution from the reduction process of a uranyl nitrate solution by using electrodialysis technique with a cation exchange membrane has been studied. Uranyl ions were reduced into uranous ions in a nitric acid solution stabilized by hydrazine sulfate in a two-compartment electrolytic cell made from flexiglass. Platinum and carbon or stainless steel were used as anode and cathode, respectively. The electrodialysis process was carried out at room temperature. A piece of cation exchange membrane was inserted between the two compartments and the distance between electrode and membrane was 1.5 cm and this was kept constant throughout the experiment. A 100 ml of a nitric acid 1.4 M solution was in the anode chamber as analyte, whilst a 100 ml of a uranyl nitrate solution with the uranium concentration of 23.97 g/l was in the cathode chamber containing hydrazine sulfate. The parameters tasted were reduction voltage, the amount of hydrazine ...

Science.gov (United States)

INTRODUCTION. We searched for a pathophysiologically based feature of major water electrolytes, which may define water quality better than the water hardness, respecting urinary calculus formation. MATERIALS AND METHODS. Utilizing a multistage stratified sampling, 2310 patients were diagnosed in the imaging centers of the provincial capitals in Iran between 2007 and 2008. These were composed of 1755 patients who were settled residents of 24 provincial capitals. Data on the regional drinking water composition, obtained from an accredited registry, and their relationships with the region's incidence of urinary calculi were evaluated by metaregression models. The stone risk index (defined as the ratio of calcium to magnesium-bicarbonate product in drinking water) was used to assess the risk of calculus formation. RESULTS. No correlation was found between the urinary calculus incidence and the amount of calcium, bicarbonate, or the total hardness ...

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This paper presents results of a laboratory and field study of naphthenic acid corrosion and the development of an effective chemical inhibitor for this type of corrosive attack. In the laboratory corrosion test, which involved 20 hour weight loss measurements in high flash solvent with a total acid number (TAN) of 16 mg KOH/gm at a temperature of 600 F (316 C), blank corrosion rates averaged 140 to 150 mpy (3.56 to 3.81 mm/y). Inhibited rates averaged about 10 to 12 mpy (0.254 to 0.305 mm/y). The field test was carried out on a heavy vacuum gas oil (HVGO) stream at 550 F (288 C) . Blanks varied from a high of 425 mpy (10.79 mm/y) for a 24 hour test to a low of about 100 mpy (2.54 mm/y) for a 150 hour test. Both electrical resistance (ER) probes and weight loss coupons showed corrosion rates below 5 mpy (0.127 mm/y) as long as they were adequately passivated. Passivation consisted of exposing the coupons to a high inhibitor dosage for a relatively short time to establish a protective ...

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In order to get the separation of natural isotopes of lithium by electrolytic amalgamation, an electrolytic cell with a confined mercury cathode was used to obtain data for the design of a separation stage. The initial work was followed by the design of a moving mercury cathode electrolytic cell and three experiments with six batches stages were performed for the determination of the elementary separation factor. The value obtained, 1.053, was ill agreement: with the specialized literature. It was verified in all experiments that the lithium - 6 isotope concentrated in the amalgam phase and that the lithium - 7 isotope concentrated in the aqueous phase. A stainless-steel cathode for the decomposition of the lithium amalgam and the selective desamalgamation were also studied. In view of the results obtained, a five stages continuous scheme was proposed. (author)

Science.gov (United States)

A sulfonated fluoroalkyl graft polymer (FGP) membrane was prepared as a polymer electrolyte. First, the FGP membrane was grafted with styrene under UV irradiation. The grafted FGP was then sulfonated to functionalize it for proton conductivity. The grafting degree of the membrane increased with increasing grafting time during UV irradiation. The proton conductivity of the membrane increased with increasing grafting degree. The swelling ratio was independent of the grafting time, however, the water uptake increased with increasing grafting degree. Based on these results, it was found that the UV-initiated styrene grafting occurred along the membrane thickness direction. Moreover, the membrane was embedded within the glass fibers of the composite. This composite electrolytic membrane had 1.15 times the proton conductivity of a Nafion 117 membrane.

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A body-centered cubic (bcc) Mg-12Li-9Al-1Zn (wt.%) alloy was fabricated in air by electrolysis from LiCl-KCl molten salt at 500 deg. C. Electrolytic deposition of Li atoms on cathode (Mg-Al-Zn alloy) and diffusion of the Li atoms formed the bcc Mg-Li-Al-Zn alloy with 12 wt.% Li and only 0.264 wt.% K. Low K concentration in the bcc Mg alloy strip after the electrolysis process resulted from 47% atomic size misfit between K and Mg atoms and low solubility of K in Mg matrix.

Science.gov (United States)

Feasibility of depositing continuous films of nano-porous alumino-silicates, primarily zeolites and MCM-41, on metallic and non-metallic substrates was examined with an aim to develop membranes for separation of gaseous mixtures and also for application as hydrogen storage material. Mesoporous silica was deposited in-side the pores of these nano-porous disks with an aim to develop membranes for selective separations. Our study involves supported zeolite film growth on substrates using in-situ hydrothermal synthesis. Faujasite, Silicalite and Mesoporous silica have been grown on various metallic and non-metallic supports. Metallic substrates used for film growth included anodized titanium, sodium hydroxide treated Titanium, Anodized aluminum, and sintered copper. A non-metallic substrate used was nano-porous aluminum oxide. Zeolite film growth was characterized using Scanning Electron Microscope (AMRAY 1820) and High Resolution Transmission electron microscope. ...

International Nuclear Information System (INIS)

Analysis of results of an investigation into the structure of lithium salt aqueous solutions is presented. An anomaly in lithium ion behaviour in solutions at the structural level is noted. 40 refs., 3 tabs.

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This paper describes zinc-air battery for electric vehicle (EV). This battery is composed of air electrode, zinc electrode, and alkali electrolyte. During the discharge, oxygen taken from the air is reduced at the air electrode, and zinc is dissolved at the zinc electrode. The whole reaction is formation of zinc oxide from oxygen and zinc. This is taken out to use as a secondary battery through exchange and regeneration, which is called mechanical charge. For Electric Fuel, discharged products in the zinc electrode from a spent EV are extracted by a vibrating crusher, and are dissolved in KOH to prepare zinc ion electrolyte. Thus, zinc is obtained through the electrolytic refining. Since the regenerated zinc is separated from the electrolytic electrode as a form of dendritic powder, it is recovered, treated by press molding, regenerated, and used as a zinc electrode. The battery developed by Electric ...

Science.gov (United States)

twenty 350 V, 2.5 mF aluminum electrolytic capacitors with 10.8 mH inductors made of multi-strand wire. The PFN discharge was controlled using an silicon ...

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An electrolyte for high voltage lithium metal anode cells must simultaneously satisfy at least the following requirements; (i) high cycling efficiency on the lithium metal anode; (ii) higher oxidation potential than the charging voltage, and (iii) high specific conductivity. We have examined various electrolytes for lithium metal anode cells using a high voltage cathode, LiMn{sub 1.9}Co{sub 0.1}O{sub 4}. Of the electrolytes resistant to high voltage that we used, a system containing 60 to 90 vol.% of dimethyl carbonate (DMC) mixed with ethylene carbonate (EC) and 1.0 M lithium hexafluorophosphate (LiPF{sub 6}) provided the best cycling efficiency on a lithium metal anode, as well as a high specific conductivity around 10 mS cm{sup -1} at 20 C. (orig.)

International Nuclear Information System (INIS)

A study has been performed of the initial corrosion of support structure alloys in crevices of various geometries, when galvanically coupled to alloy 600. Corrosion rates were monitored continuously by measuring the galvanic current flowing in each couple, transduced by a zero impedance ammeter. Experiments were performed in a single-pass flowing electrolyte system, with AVT water pumped through alloy 600 tubing past the orifice of each crevice. Fourteen crevices were studied simultaneously in two parallel flow arms containing seven specimens each. The steady state AVT water pH/hydrazine/oxygen concentrations were controlled by microcomputer, allowing the effect of secondary water chemistry on the corrosion rate to be studied easily. Control of the crevice electrolyte composition was achieved by separately pumping electrolyte, at a low rate, directly into the crevices of the seven specimens in the lower flow arm. In ...

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The deformation characteristics of pellets of electrolyte-binder (EB) mixes based on MgO were measured under simulated, thermal-battery conditions. Measurements (using a statistically designed experimental strategy) were made as a function of applied pressure, temperature, and percentage of theoretical density for four molten-salt electrolytes at two levels of MgO. The EB mixes are used as separators in Li-alloy thermal batteries. The electrolytes included LiCl-KCI eutectic, LiCl-LiBr-KBr eutectic, LiBr-KBr-LiF eutectic, and a LiCl-LiBr-LiF electrolyte with a minimum-melting composition. The melting points ranged from 313 C to 436 C. The experimental data were used to develop statistical models that approximate the deformation behavior of pellets of the various EB mixes over the range of experimental conditions we examined. This report, discusses the importance of the deformation response surfaces to ...

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The agglomerate for the element is made from activated charcoal powder, an electrically conducting additive and a neutral electrolyte. The activated charcoal makes up 30 to 50 percent of the weight of the agglomerate. It is a mixture of hydrophobized and unhydrophobized powder in a ratio of 85 to 70 to 15 to 30. The element has high discharge characteristics.

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The pH of the solution is shown to significantly effect the reflection anisotropy spectroscopy (RAS) profiles of adenine adsorbed at Au(110)/electrolyte interfaces. At pH 12.8 the net adsorption is very weak due the formation of negative adenine ions in solution. The sensitivity of the RAS profiles to the pH of the solution is probably due to a change in the geometry of the adsorbed molecules caused by a disruption of the base stacking configuration that is adopted when adenine is adsorbed from solutions at pH 7.1. (Abstract Copyright [2010], Wiley Periodicals, Inc.)

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This invention pertains to passivation-free solid-state rechargeable batteries composed of Li.sub.4 Ti.sub.5 O.sub.12 anode, a solid polymer electrolyte and a high voltage cathode. The solid polymer electrolyte comprises a polymer host, such as polyacrylonitrile, poly(vinyl chloride), poly(vinyl sulfone), and poly(vinylidene fluoride), plasticized by a solution of a Li salt in an organic solvent. The high voltage cathode includes LiMn.sub.2 O.sub.4, LiCoO.sub.2, LiNiO.sub.2 and LiV.sub.2 O.sub.5 and their derivatives.

International Nuclear Information System (INIS)

Equivalent circuit and electrical parameters for H-doped NH_4UO_2PO_4.3H_2O self supported membranes have been determined by impedance spectroscopy. The measurements were carried out with a dry membrane, at different temperatures, and a wet membrane in contact with different electrolyte solutions. Resistance values for the dry membrane decrease with temperature increase, which agrees with the weak protonic character of the H-doped ammonium uranylphosphate. On the other hand, differences in the electrical parameters, depending on the electrolyte considered were also obtained and are attributed to different conduction mechanisms. (Author).

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A solid electrolyte for lithium batteries requires several properties: a good ionic conductivity of about 10{sup -3} S/cm at 298 deg. K, a high cationic transport number (greater than 0.5), a redox stability window higher than 4.5 V, a good stability of the interface with the lithium electrode, and a sufficient mechanical stability. The family of gelled or hybrid electrolytes seems to meet all these requirements. Thus, a systematic study of the gelling of an ethylene carbonate and lithium bistrifluorosulfonimide (LiTFSI) based electrolyte has been carried out. The polymers used for gel or pseudo-gel synthesis are POE, PMMA and PAN which represent 3 different cases of interaction with the electrolyte. All the properties mentioned above have been studied according to the nature of the polymer and to the concentration of lithium salt, showing the advantages and drawbacks of each polymer. The possibility of ...

CERN Document Server

Materials science and technology

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Developing safe, reliable, cost-effective, and efficient hydrogen-electricity co-generation systems is an important step in the quest for national energy security and minimized reliance on foreign oil. This project aimed to, through materials research, develop a cost-effective advanced technology cogenerating hydrogen and electricity directly from distributed natural gas and/or coal-derived fuels. This advanced technology was built upon a novel hybrid module composed of solid-oxide fuel-assisted electrolysis cells (SOFECs) and solid-oxide fuel cells (SOFCs), both of which were in planar, anode-supported designs. A SOFEC is an electrochemical device, in which an oxidizable fuel and steam are fed to the anode and cathode, respectively. Steam on the cathode is split into oxygen ions that are transported through an oxygen ion-conducting electrolyte (i.e. YSZ) to oxidize the anode fuel. The dissociated hydrogen and residual steam are exhausted from ...

Science.gov (United States)

... Materials (PREM) Synopsis of Program: The objective of PREM is to enhance diversity in materials ... careers in materials research.The Partnerships for Research and Education in Materials (PREM ...

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... Materials Research - Major Instrumentation Project (IMR-MIP) program in the Division of Materials ... for materials preparation and characterization essential for researchers studying materials in a ...

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... Materials Development Program TECHNOLOGY EDUCATION INSTRUCTIONAL MATERIALS Elementary - High School ... of technology education materials through its Instructional Materials Development (IMD) program. The ...

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... materials science and engineering, condensed-matter or materials physics, solid-state or materials ... include materials theory, condensed-matter and materials physics, solid-state and materials ...

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This report summarizes the results of research conducted during the sixteen month continuation of a program to develop rechargeable zinc-air batteries for electric vehicles. The zinc-air technology under development incorporates a metal foam substrate for the zinc electrode, with flow of electrolyte through the foam during battery operation. In this soluble'' zinc electrode the zincate discharge product dissolves completely in the electrolyte stream. Cycle testing at Lawrence Berkeley Laboratory, where the electrode was invented, and at MATSI showed that this approach avoids the zinc electrode shape change phenomenon. Further, electrolyte flow has been shown to be necessary to achieve significant cycle life (> 25 cycles) in this open system. Without it, water loss through the oxygen electrode results in high-resistance failure of the cell. The Phase I program, which focused entirely on the zinc ...

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The single-electrode capacitance of a nano-porous carbon electrode used as an electric double layer capacitor was measured. The charged state of the electrolyte ion was discussed from the results. Single-electrode capacitance was not proportional to the specific surface area of the electrode. This implies that the whole surface of the electrode is not effective for the formation of an electric double layer. It is considered that edge orientation of the carbon structure would give a dominant contribution to capacitance. For measurements with aqueous solutions of various electrolytes, capacitance was about the same value for each salt compound. For aqueous acid solution, on the other hand, capacitance was twice to three times as large as that for salt compounds. This difference, however, became negligibly small if the concentration of electrolyte solution was lowered. Taking account of the hydrated ionic radius of each ion, ...

International Nuclear Information System (INIS)

Spent oxide fuels are reduced in a molten salt of CaCl_2-CaF_2 to convert them into metals, then melted in an Fe-U bath disposed in an electrolytic refining vessel and brought into contact with molten Mg, to extract transuranium elements and rare earth elements contained in the Fe-U bath as metals in the molten Mg. Then molten Mg is removed and the residue is brought into contact with KCl-LiCl molten salt and electrolyzed using the Fe-U as an anode. Then, uranium is recovered by deposition on an iron cathode disposed in chloride electrolytes of the electrolytic refining vessel. Uranium and transuranium elements can be thus separated and, for example, depleted uranium for use in blanket fuels can be recovered easily. This can greatly reduce the temporary storage amount of depleted uranium, to eliminate requirement for a large-scaled facility used exclusively for storing uranium and long time management for uranium. (T.M.).

Energy Technology Data Exchange (ETDEWEB)

This project will determine whether electrolytic dialysis has promise in the separation of charged particles in an aqueous solution. The ability to selectively move ions from one aqueous solution to another through a semipermeable membrane will be studied as a function of emf, amperage, and particle electrical charge. The ions selected for the study are Cl{sup -} and SO{sub 4}{sup 2-}. These ions are of particular interest because of their electrical conduction properties in aqueous solution resulting with their association with the corrosive action of metals. The studies will be performed with commercial membranes on solutions prepared in the laboratory from reagent salts. pH adjustments will be made with dilute reagent acid and base. Specific objectives of the project include testing a selected membrane currently available for electrolytic dialysis, membrane resistance to extreme pH conditions, the effectiveness of separating a mixture of two ...

Energy Technology Data Exchange (ETDEWEB)

The spontaneous ionic polymerization of 4-vinyl-pyridine in presence of mono-tosylated or bromated short chains of poly(ethylene oxide)-(PEO) is used to prepare amorphous comb-like poly-cations with low Tg. The polymer electrolyte properties of these new structures have been studied without any addition of salts. The ionic conductivity of these fixed cation poly-electrolytes depends on the length of the grafted PEO and varies from 10{sup -7} to 10{sup -4} S/cm between 25 and 80 deg. C. It is only weakly dependent on the nature of the cation but it is controlled by the movements of the pyridinium cation which are facilitated by the plastifying effect of the POE chains which do not directly participate to the ionic transport. (J.S.) 17 refs.

Energy Technology Data Exchange (ETDEWEB)

A series of modifications which increased the capacity of Canadian Electrolytic Zinc's Valleyfield plant from 220,000 MT/year to 260,000 MT/year during the last decade is discussed, combined with an an overview of the plant's operations. The modifications included modernisation of the waste disposal methods and facilities, such as a new high-density sludge wastewater treatment process, a new process to remove selenium from weak acid solutions and the jarofix process. Roasting capacity also has been improved by recent investments in new cooling coils, rebricking, oxygen enrichment and process automation. In addition to increases in refining capacity, the improvements also enabled the company to minimize its impact on the environment and the community.

British Library Electronic Table of Contents (United Kingdom)

A numerical model is developed to study electrolyte dependent kinetics in fuel cells. The model is based on the Poisson-Nernst-Planck (PNP) and generalized-Frumkin-Butler-Volmer (gFBV) equations, and is used to understand how the diffuse layer and ionic transport play a role in the performance difference between acidic and alkaline systems. The laminar flow fuel cell (LFFC) is used as the model fuel cell architecture to allow for the appropriate comparison of equivalent acidic and alkaline systems. We study the overall cell performance and individual electrode polarizations of acidic and alkaline fuel cells for both balanced and unbalanced electrode kinetics as well as in the presence of transport limitations. The results predict cell behavior based on electrolyte composition that strongly...

Energy Technology Data Exchange (ETDEWEB)

This document reproduces the final project of David San Fabian Ayuso, presented on May 26, 2005, for the obtention of the engineer degree of the Carlos III University of Madrid. A single-phase, isothermal model, including both electron and proton transport, is introduced for the simulation of polymer electrolyte fuel cells (PEM). The model is implemented in the commercial code Fluent 6.0, through the use of UDFs (User Defined Functions). In order to validate the model, a single canal of a PEM monocell is simulated in three dimensions. The obtained result are qualitatively satisfactory. It is observed that it is not essential to solve the current collectors when a monocell is considered (and not a stack). in the present study, the number of nodes is the computational grid appears to be too low in the membrane zone in order to make a complete validation of the model. (Author) 20 refs.

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The measurement of local heat transfer coefficients is necessary to record the basic phenomena of heat transfer in thin-film apparatuses. For this reason the so-called electrochemical analogy method was developed and used for this application. The electrochemical method implies a specifically composed electrolyte which substitutes the fluid to be evaporated in the thin-film apparatus. Using the redox electrolyte (0,025 kmol/m/sup 3/ K/sub 4/Fe(CN)/sub 6/ resp. k/sub 4/Fe(CN)/sub 6/ and 2nNaOH) the viscosity was, for the first time, thickened until 0.4 Pa s by the help of hydroxyethyl-cellulose.

British Library Electronic Table of Contents (United Kingdom)

In situ composite coating of hydroxyapatite (HA)/TiO2 were produced on titanium (Ti) substrate by micro-arc oxidation coupled with electrophoretic deposition (MAO&EPD) technique with different concentrations of HA particles in the 0.2M NaOH electrolyte solution. The surface morphology and chemical composition of the hybrid coating were effected by HA concentration. The amount of HA particles incorporated into coating layer increased with increasing HA concentration used in the electrolyte solution. The corrosion behavior of the coating layer in simulated body fluids (SBF) was evaluated using a potentiodynamic polarization test. The corrosion resistance of the coated sample was increased compared to the untreated Ti sample. The in vitro bioactivity assessment showed that the MAO&EPD treated...

Energy Technology Data Exchange (ETDEWEB)

Brookhaven National Laboratory is involved in a conceptual design study of a commercial nuclear power system which utilizes high-temperature electrolysis to produce synthetic fuels. The system is called HYFIRE. It includes a tokamak fusion power reactor supplying electrical and thermal energy to an array of electrolytes. The electrolytes produce hydrogen which can be used either directly as a fuel or in the production of hydrocarbons. The purpose of the study is to provide a mechanism for DOE to further assess the commercial potential of fusion using a tokamak reactor to produce synthetic fuel. The HYFIRE design is based on the tokamak commercial power reactor, STARFIRE. STARFIRE uses the deuterium/tritium/lithium fuel cycle. The HYFIRE study assumes the plasma shape and characteristics of STARFIRE study but uses a different blanket design. This study is particularly interested in the possibility of using the STARFIRE tokamak in the production ...

Energy Technology Data Exchange (ETDEWEB)

Hydrogen has the potential to serve as both an energy storage means and an energy carrier in renewable energy systems. When renewable energy sources such as solar or wind power are used to produce electrical power, the output can vary depending on weather conditions. By using renewable sources to produce hydrogen, a fuel which can be stored and transported, a reliable and continuously available energy supply with a predictable long-term average output is created. Electrolysis is one method of converting renewable energy into hydrogen fuel. In this experiment we examine the use of an electrolyzer based on polymer-electrolyte membrane technology to separate water into hydrogen and oxygen. The oxygen is vented to the atmosphere and the hydrogen is stored in a small pressure vessel.

Energy Technology Data Exchange (ETDEWEB)

For the development of a rechargeable zinc/air battery, La[sub 0.6]Ca[sub 0.4]CoO[sub 3]-catalyzed (perovskite) bifunctional oxygen electrodes and pasted zinc electrodes were prepared and tested in monopolar zinc/air cells. In addition, a bipolar Zn/air stack was tested using reticulated copper foam as substrate for the zinc deposit. The cells were cycled in moderately alkaline ZnO-saturated electrolyte with KF as an electrolyte additive. The maximum power as well as the cycle life of the cells was investigated. The differences in porosity of the zinc electrode before and after the long-term test were analyzed using mercury porosimetry. (author) 8 figs., 13 refs.

British Library Electronic Table of Contents (United Kingdom)

A Brownian dynamics simulation has been used to investigate the aggregation kinetics of bimodal colloidal mixtures with similar surface chemistries but different sizes, driven by the DLVO interaction potential. The time evolution of structural formation is examined by the mean number of neighbors under fast and slow aggregation regions. It was found that the electrolyte ionic strength affects the kinetic pattern of colloidal aggregation. Under the high electrolyte ionic strength conditions (fast aggregation), the selective aggregation of the least stable single component can take place in the early stage, while the other component is enriched in this least stable component in the later stage. With the ionic strength decreasing (towards the slow aggregation), the hybrid aggregation (selecti...

Science.gov (United States)

Materials World Network: Cooperative Activity in Materials Research between US Investigators and ... Program Title: Materials World Network: Cooperative Activity in Materials Research between US ...

Energy Technology Data Exchange (ETDEWEB)

This definitive reference is organized in an easy-to-follow format based on materials properties. It features new and existing data verified through major professional societies in the materials fields, such as ASM International and the American Ceramic Society. The third edition has been significantly expanded, most notably by the addition of new tabular material for a wide range of nonferrous alloys and various materials. The contents include: Structure of materials; Composition of materials; Phase diagram sources; Thermodynamic and kinetic data; Thermal properties of materials; Mechanical properties of materials; Electrical properties of materials; Optical properties of materials; Chemical properties of materials.

Energy Technology Data Exchange (ETDEWEB)

A hydrous oxide film for the application as dielectric film is synthesized by immersion of pure aluminum in hot water. From a Rutherford backscattering analysis, the ratio of aluminum to oxygen atoms was found to be 3:2 in the anodized aluminum oxide film, and 2:1 in the hydrous oxide layer. Anodization of the hydrous oxide layer was more effective for the transition of amorphous anodic oxides to the crystalline aluminum oxides.

Energy Technology Data Exchange (ETDEWEB)

The study presented in this thesis is a contribution about the analysis of failures modes of electrolytic capacitors and thyristors. The studied components are main elements of the protection system of the superconductive magnets of the LHC. The study of the ageing of the electrolytic capacitors has shown that their reliability is strongly related to their technological characteristic. Evolution of their principal indicator of ageing (ESR) can be modeled according to different laws chosen according to their running mode. It appears that the prediction of failure of these components other than that due to wear can be only statistical taking into account the many causes of failure involving various modes of failure. In order to be able to evaluate influence of the ageing of the electrolytic capacitors on a system, simple models taking into account this parameters as well as the effective temperature of the component are ...

Energy Technology Data Exchange (ETDEWEB)

The objective of this research is to gain a better understanding of the corrosion of the aluminized type 316 stainless steel employed in the seal areas of the molten carbonate fuel cell. The seals are formed between the aluminized Type 316 SS surface and the electrolyte (generally a mixture of molten alkali carbonates and lithium aluminate).

Energy Technology Data Exchange (ETDEWEB)

Several Mg-Y binary ribbons with Y content up to {approx}17.9 at.% were fabricated by melt-spinning. X-ray diffraction (XRD) revealed that the phase structure changes with increasing Y content from extended solid solution to partially amorphous, and then fully intermetallic Mg{sub 24}Y{sub 5}. Anodic potentiodynamic polarization performed in 0.01 M NaCl electrolyte (pH=12) revealed improved anodic passivity behavior compared to pure Mg for all the Mg-Y alloys. X-ray photoelectron spectroscopy (XPS) revealed that the improved passivity of Mg-Y was more related to the elemental oxidation state rather than the concentration of the surface components. To study the effect of Cl{sup -} ion on the passivity behavior, anodic potentiodynamic and potentiostatic polarization were performed on Mg-17.9 at.% Y in alkaline (pH=12) NaCl electrolytes containing Cl{sup -} ion in the concentration range from 0.00 to 0.50 M. The passive films formed in 0.01 M NaCl ...

Energy Technology Data Exchange (ETDEWEB)

A flexible battery is printed on paper by screen-printing a zinc/carbon/polymer composite anode on one side of the sheet, polymerising a poly(3,4-ethylenedioxythiophene) (PEDOT) cathode on the other side of the sheet, and applying a lithium chloride electrolyte between the two electrodes. The PEDOT cathode is prepared by inkjet printing a pattern of iron(III)p-toluenesulfonate as a solution in butan-1-ol onto paper, followed by vapour phase polymerisation of the monomer. The electrolyte is prepared as a solution of lithium chloride and lithium hydroxide and also applied by inkjet printing on to paper, where it is absorbed into the sheet cross-section. Measurements on a zinc/carbon-PEDOT/air battery in a similar configuration on a polyethylene naphthalate substrate shows a discharge capacity of up to 1.4 mAh cm{sup -2} for an initial load of 2.5 mg zinc, equivalent to almost 70% of the zinc content of the anode, which generates 0.8 V at a ...

Energy Technology Data Exchange (ETDEWEB)

Interpenetrated lattices (IPL) are combinations of reticulated polymers linked together by permanent crisscross. This structure is well-adapted to combined highly incompatible pairs of polymers. The in-situ sequential method has been applied successfully to the synthesis of ethylene poly-oxides / poly-siloxanes IPLs. The results concerning the preparation of such lattices and their behaviour as solid polymer electrolytes are presented in this paper. (J.S.) 24 refs.

International Nuclear Information System (INIS)

Sodium-ion-conducting glasses are considered a promising alternative to the ceramic electrolytes. The glass upon which the most development work has been done is a sodium borate glass, which has an ionic resistivity of about 2 x 10/sup 4/ #OMEGA#-cm at 300"0C. Because of its high resistivity, cells using this borate glass require thousands of hollow glass fibers, each about 80 micrometers outer diameter (15 micrometer wall). In spite of its greater complexity, the cell with the glass electrolyte is of interest because of its potential for lower cost and higher power than the cell with ceramic electrolyte. Recently, silicate glasses of lower resistivity have been proposed for this application. These include: a soda-alumina-silica glass (900 #OMEGA#-cm at 300"0C), a soda-zirconia-magnesia-silica glass (700 #OMEGA#-cm at 300"0C), and a soda-zirconia-silica glass (600 #OMEGA#-cm at 300"0C). These lower resistivity glasses would ...

Energy Technology Data Exchange (ETDEWEB)

According to the invention, a zinc foil is arranged between the negative electrode of a zinc/air battery (round cell) and the expansion space compensating for the reactive increase in volume of the zinc powder. This zinc foil functioning as a stop diaphragm particularly ensures, from the very onset, that the zinc filling has a density and compactness necessary for good electronic conductance.

International Nuclear Information System (INIS)

One of several methods to build YSZ electrolyte of SOFC is plasma spraying. This system heats particle to a melting point and then pushing them into target and forming a deposition. This paper presents heating studies of YSZ particle in plasma jet. By simple model it is shown that the required time such those YSZ particle with grain size of 50 ?m to be melt is around 12 x 10-4 second. (author)

Science.gov (United States)

NSF-NIST Interaction in Chemistry, Materials Research, Molecular Biosciences, Bioengineering, and ... Laboratory (CSTL). Materials research is centralized in the Materials Science and Engineering ...

International Nuclear Information System (INIS)

A method is described for immobilizing or solidifying waste material, which includes blending the waste material with powdered metal and subjecting the mixture of waste material and powdered metal to high pressure. (author).

Science.gov (United States)

... of this material is, however, outside the currently approved earth fill materials collection area ... fill material suitable for its intended use. The currently approved site contains material that is ...

Energy Technology Data Exchange (ETDEWEB)

This book describes the uses, coatings, and fabrication of laser materials. Topics considered include: optical waveguide materials; optical storage materials; holographic recording materials; phase conjunction materials; holographic recording materials; phase conjunction materials; laser crystals; laser glasses; quantum counter materials; thin films and coatings; multilayer dielectric coatings; graded-index surfaces and films; optical materials fabrication; fabrication techniques; fabrication procedures for specific materials.

International Science & Technology Center (ISTC)

Metal Matrix Composites on the Basis of Nano-Materials

International Nuclear Information System (INIS)

... FUEL CYCLE AND FUEL MATERIALS MATERIALS SCIENCE chromium-nickel

International Science & Technology Center (ISTC)

Development of Ceramic Composite Materials and Structural Elements for High-Temperature Nuclear Reactors

International Nuclear Information System (INIS)

A survey is given on the results in hand on the natural radioactivity of building materials. It is shown that only a small percentage of building materials has an increased content of radioactive materials. The results are compared with approximate values given in a Russian publication. (orig./AK).

Science.gov (United States)

... materials science and education beyond what is expected from any one Center. "Advanced materials are ... for DMR's Division of Materials Research. "Fundamental research on materials is essential to the ...

Energy Technology Data Exchange (ETDEWEB)

The purpose of this work was to establish a new binary data base by compiling the activity coefficients of plutonium and uranium at oxidation state +IV to better account for media effects in the liquid-liquid extraction operations implemented to reprocess spent nuclear fuel. Chapter 1: first reviews the basic thermodynamic concepts before describing the issues involved in acquiring binary data for the tetravalent actinides. The difficulties arise from two characteristics of this type of electrolyte: its radioactive properties (high specific activity requiring nuclearization of the experimental instrumentation) and its physicochemical properties (strong hydrolysis). After defining the notion of fictive binary data, an approach based on the thermodynamic concept of simple solutions is described in which the activity coefficient of an aqueous phase constituent is dependent on two parameters: the water activity of the system and the total concentration of dissolved ...

Energy Technology Data Exchange (ETDEWEB)

The crystallization of calcium sulfate from aqueous solutions with NaCl is both geological and industrial interest because NaCl is the dominant solute in natural brines and many industrial fluids. Induction periods for the nucleation of calcium sulfate dihydrate were experimentally determined as a function of supersaturation in NaCl solutions from 0 to 6 m at 25 C and in 3.0-m NaCl solutions at temperatures from 25 to 90 C. Using classic nucleation theory, the interfacial tension between gypsum and 3.0-m NaCl solution was estimated to be about 39 mJ/m[sup 2] at 25 C and increases with increasing temperature (to 63 mJ/m[sup 2] at 90 C). It was observed that the induction period decreases with increasing NaCl concentrations up to 3 m and then starts to increase slightly at a given temperature and saturation state. The electrolyte effect on nucleation was proportional to the enhanced solubility of calcium sulfate dihydrate in NaCl solutions. This phenomenon may result ...

International Nuclear Information System (INIS)

A commercial CFD code, Fluent, has been used to analyse the design of a filter-press reactor operating with characteristic linear flow velocities between 0.024 and 0.192 m s-1. Electrolyte flow through the reactor channel was numerically calculated using a finite volume approach to solve the Navier-Stokes equations. The length of the channel was divided into 7 sections corresponding to distances of 0, 0.01, 0.04, 0.08, 0.12, 0.14 and 0.15 m from the electrode edge nearest to the inlet. The depth of the channel was divided into three planes parallel to the channel bottom. For each channel section, a velocity profile was obtained at each depth together with the average velocity in each plane. The flow predictions show that the flow development, as the electrolyte passes through the cell, is strongly affected by the manifold causing strong vortex structures at the entrance and exit of the channel. Although the flow disturbances are a function of ...

British Library Electronic Table of Contents (United Kingdom)

The effects of gas diffusion layer's (GDL's) anisotropic bending stiffness on the degradation behavior of polymer electrolyte membrane fuel cells have been investigated under freezing conditions. We have prepared GDL sheet samples such that the higher stiffness direction of GDL roll is aligned with the major flow field direction of a metallic bipolar plate at angles of 0^o (parallel: '0^o GDL') and 90^o (perpendicular: '90^o GDL'). The I-V performances before and after 1000 temperature cycles between -10 and 1 ^oC of 90^o GDL stack are higher than those of 0^o GDL stack, and the voltages of 90^o GDL stack are decreased slower than those of 0^o GDL stack, indicating a higher durability of 90^o GDL stack. Furthermore, the values and increasing rates of high-frequency resistance of 90^o GDL s...

Energy Technology Data Exchange (ETDEWEB)

Apparatus and methods are described for generating heat and electricity from the consumption of a variety of aluminum products. The method consists of (A) a reaction chamber containing an aqueous electrolyte solution and adapted for introduction therein of aluminum pieces of various shapes and sizes up to a certain maximum predetermined size and for effecting a chemical reaction between said aqueous electrolyte and said aluminum pieces yielding aluminum hydroxide and an intermediate reactant; (B) means for feeding said aluminum pieces into said reaction chamber in small quantities upon demand; (C) means for removing the heat generated in said chamber as a result of said reaction; (D) means for removing said aluminum hydroxide reaction product; and (E) means for oxidizing said intermediate reactant in an electrochemical cell, thereby generating electrical energy. The intermediate reactant is preferably hydrogen or zinc. The latter may be used in ...

DEFF Research Database (Denmark)

Polyacrylonitrile (PAN)-based polymer electrolytes have obtained considerable attention due to their fascinating characteristics such as appreciable ionic conductivity at ambient temperatures and mechanical stability. This study is based on the system PAN-ethylene carbonate (EC)-propylene carbonate (PC)-lithium trifluoromethanesulfonate (LiCF3SO3). The composition 15 mol% PAN-42 mol% EC-36 mol% PC-7 mol% LiCF3SO3 has shown a maximum room temperature conductivity of 1.2 x 10(-3) stop S cm(-1) stop. Also, it was possible to make a thin, transparent film out of that composition. Cells of the form, Li/PAN-EC-PC-LiCF3SO3/polypyrrole (PPy)-alkylsulfonate (AS) were investigated using cyclic voltammetry and continuous charge-discharge tests. When cycled at low scan rates, a higher capacity could be obtained and well-defined peaks were present. The appearance of peaks elucidates the fact that redox reactions occur completely. This well proves the reason for higher capacity. ...

Energy Technology Data Exchange (ETDEWEB)

We report tests of a refuelable zinc/air battery of modular, bipolar-cell design, intended for fleet electric busses and vans. The stack consists of twelve 250-cm{sup 2} cells built of two units: (1) a copper-clad glass-reinforced epoxy board supporting anode and cathode current collectors, and (2) polymer frame providing for air- and electrolyte distribution and zinc fuel storage. The stack was refueled in 4 min. by a hydraulic transfer of zinc particles entrained in solution flow.

International Nuclear Information System (INIS)

The ion mobilities of |"2"1"1At|At(I) in dependence on thiourea (tu) concentration, iodide concentration and a mixture of both ligands were measured by the electromigration method in free electrolytes. An equilibrium model was developed for the characterization of electromigration curves which permitted the calculation of stability constants and ion mobilities of the complexes |AtI|, |AtI_2|"-, |Attu|"+, |Attu_2|"+ and |AtItu| existing in these solutions. Ethanol and water served as solvents. The temperature was 298 K and the ionic strength was about 0.05 mol/dm"3. (author) 16 refs.; 2 figs.

Energy Technology Data Exchange (ETDEWEB)

The authors report a novel configuration for a zinc-particle, packed-bed anode in which an open structure of high hydraulic permeability is maintained indefinitely in a cell with closely spaced walls by the formation of particle bridges and associated gaps. The configuration minimizes electrolyte pumping costs, allows rapid refueling and partial recharge, and provides for 100% zinc consumption. This approach benefits zinc/air fuel batteries by allowing nearly continuous operation and fuel recycle without commercial infrastructure; it benefits Zn/[Fe(CN){sub 6}]{sup {minus}3} batteries by eliminating shape-change and polarization problems found with planar anodes.

International Nuclear Information System (INIS)

Crystallization points of aqueous solution of the systems M(ClO_4)_2-H_2O (M"2 = Mg"2"+, Ca"2"+, Sr"2"+, Ba"2"+), depending on the salt concentration, were identified by visual-polythermal method. Relying on model notions on the structure of the electrolyte solutions, specific features of strontium perchlorate solubility polytherm and concentration dependence of the relative dynamic viscosity of the salt aqueous solutions are discussed

International Nuclear Information System (INIS)

The effects of #alpha# particle irradiation on a passive film formed on a 304 type stainless steel are studied in situ. The experimental arrangement minimizes the radiolysis effects due to the electrolyte. Under irradiation, a modification of the electronic structure of the oxide layers is revealed by photo-electrochemistry and impedance measurements. The influence of irradiation on the corrosion resistance of the passive film is investigated. Comparing the rest potential and the breakdown potential respectively under and without irradiation, a drop in the passivity range under irradiation is shown. this is interpreted as a decrease in the corrosion resistance. (author).

Energy Technology Data Exchange (ETDEWEB)

Cement-based composites are widely used in applications which demand long-term service life. One important example is in immobilization matrices for low-level radioactive and other hazardous wastes, which demands long-term retention and durability. The authors describe conductivity measurements of grouts flooded with water and in contact with a sink that consists of pure water. The conductivity measurements were designed and carried out in parallel with present quality verification methods and standard leach tests of the nuclear waste management industry. For the first time, the authors show that the method of replacing intrusive chemical analysis with conductivity measurements of the leaching samples yields equivalent results.

Energy Technology Data Exchange (ETDEWEB)

For the development of a rechargeable zinc/air battery, La{sub 0.6}Ca{sub 0.4}CoO{sub 3}-catalyzed (perovskite) bifunctional oxygen electrodes and pasted zinc electrodes were prepared and tested in monopolar zinc/air cells. The cells were cycled in moderately alkaline electrolyte. The maximum power as well as the cycle life of the cells were investigated. Up to 450 cycles could be reached, and attractive specific energies and powers were obtained. (author) 3 figs., 4 refs.

Energy Technology Data Exchange (ETDEWEB)

Objective of the project is characterization of electrode reactions in molten salt by using metal oxides and silica-based electrode. The scope of project are characterization of metal oxide properties in molten salt and miniaturization of 3-electrode electrochemical test cell. Electrochemical micro-cell for actinide-LiCl-KCl molten salt was newly designed. Electroless and electrochemical deposition technique was applied to Mo coating on quartz tube. From the design of electrode and 3-electrode electrochemical cell suitable for the tests in molten salt electrolyte, so it is anticipated to get the information on the electrochemical behavior of metallic electrode in molten salt and to secure the information on oxidation/reduction behavior of actinide

Energy Technology Data Exchange (ETDEWEB)

The aim of this work is to develop an industrial process for the synthesis of an extrusible electrolyte polymer for lithium batteries. From literature data and precise specifications the high molar mass EO/OP copolymers synthesis by coordinative catalysis has been studied in order to reach a high productivity and to minimize the treatment steps. Two catalytic systems have been studied: the aluminium alkoxide-based Vandenberg-type catalysis and the calcium alcoholate amides catalysis. The first catalysis performed in solution gives excellent results. Its adaptation to silicon supported catalysis leads to a directly usable polymer in suspension but the productivity falls down and remains to be optimized. The calcium amide catalysis in heptane suspension generates acceptable productivities but also a too high proportion of low molar masses. Various approaches have been studied to minimize this proportion due to the presence of secondary sites that generate a cationic ...

International Nuclear Information System (INIS)

The anodic reaction kinetics and interfacial mass transport of a direct polymer electrolyte membrane formic acid fuel cell have been investigated in an all solid-state electrochemical cell using a highly active nanostructured palladium-gold alloy microelectrode as an in situ probe. Well-defined 'S-shaped' steady-state cyclic voltammograms exhibiting current-rising region at lower overpotentials and limiting current region at higher overpotentials have been first obtained for the electrochemical oxidation of formic acid at varying temperature. The 'S-shaped' steady state polarization curves and chronoamperometric curves enable convenient measurements of the anodic reaction kinetics and interfacial mass transport of formic acid under real polymer electrolyte membrane conditions. It is encouragingly found that formic acid can be directly oxidized to CO2 with the first electron transfer being the likely rate-determining step and the formation of ...

Science.gov (United States)

... Astronomy & Space Biology Chemistry & Materials Computing Earth & Environment Education ... Materials Research Center at the University of Chicago, one of nearly 30 NSF-supported Materials ...

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... of Award Costs (Schedule A), are free of material misstatement. An audit includes examining, on a ... support costs, materials and supplies, and the indirect costs. We found two material internal ...

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... s guides and "how-to" videos and other materials, and 7. Receive continuing support from GLOBE's ... and educational materials that result from international proposals in its materials and support ...

UK PubMed Central (United Kingdom)

As adulterated and substituted Chinese medicinal materials are common in the market, therapeutic effectiveness of such materials cannot be guaranteed. Identification at species-, strain- and locality-levels,...Full Text Available

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PMID:4317460

J-STORE (Japan)

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... of new construction materials; and the behavior of infrastructure materials and structural ... polymers, reinforcing materials, wood and biodegradable structural materials; scale effects from ...

KoreaScience (Korea)

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Science.gov (United States)

... The Effect of the Temperature to Which the Material is Heated on the Process of Formation of Intermetallic Compounds in Magnetic Pulse Welding,. ...

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... and Security..........................13 Materials Science ... hybrid system theory, Internet analysis, materials science, mixing, physiology, iterative control ...

International Science & Technology Center (ISTC)

Nanostructured Materials from Impulse Plasma in Liquid: Studying of Physical-Chemical Properties, Optimization of Conditions of Obtaining

Science.gov (United States)

... Accession Number : ADD318302. Title : ELECTROMAGNETIC MATERIALS TESTING USING RL AND RC-MULTIVIBRATORS. Corporate Author : ...

International Nuclear Information System (INIS)

... aluminium 28 building materials cockcroft-walton accelerators copper copper

Energy Technology Data Exchange (ETDEWEB)

A method using a focused ion beam (FIB) to prepare a silicon amorphous material is presented. The method involves the redeposition of sputtered material generated during the interaction of the Ga{sup +} ion beam with a silicon substrate material. The shape and dimensions of this amorphous material are self-organized and reproducible. The stability of this amorphous material under electron irradiation was investigated in the transmission electron microscopy (TEM). Electron irradiation can induce recrystallization of the amorphous material, resulting in the lateral and vertical growth, starting at an amorphous-crystalline interface, of polysilicon containing defects.

Science.gov (United States)

A computer was built for use with the NRU reactor to solve the problem of Xe/sup 135/ concentrations. The effect of any changes in reactor on Xe/sup 135/ concentration can be predicted and steps taken to avoid poisoning out. An electromechanical system was used for the computer to avoid the inherent disadvantages that electronic analog computers present for problems of very long solution times. The electromechanical analog computer has a high order of reliability and contains no vaccum tubes, commutators, slip rings, relays, or aluminum electrolytic capacitors. It is insensitive to transient disturbarce. In the event of failure of components or interruption of line voltage, it will retain existing information. The computer was designed for ~ 1% accuracy in Xe/ sup 135/ concentration readings. (W.D.M.)

Energy Technology Data Exchange (ETDEWEB)

The new generation of performing rechargeable lithium-ion batteries (``rocking-chair``-type) are penalized by important self-output phenomena linked with the use of highly oxidizing positive electrodes. In order to limit this problem in LiMn{sub 2}O{sub 4}/C batteries, two different passivation techniques were used in order to limit the surface contact between the positive electrode and the electrolyte. Thanks to these treatments, a significant reduction of the percentage of irreversible capacity losses is effectively observed. (J.S.) 3 refs.

CERN Document Server

The development of a replacement to the conventional film based X-ray imaging technique is required for many reasons. One possible route for this is the use of a large area film of a suitable semiconductor overlaid on an amorphous silicon readout array. A suitable semiconductor exists in cadmium telluride and its tertiary alloy cadmium zinc telluride. In this thesis the spectroscopic characteristics of commercially available CZT X- and gamma-radiation detectors are established. The electronic, optical, electro-optic, structural and compositional properties of these detectors are then investigated. The attained data is used to infer a greater understanding for the carrier transport in a CZT radiation detector following the interaction of a high energy photon. Following this a method used to fabricate large area films of CdTe on a commercial scale is described. This is cathodic electrodeposition from an aqueous electrolyte. The theory and experimental arrangement for ...

Energy Technology Data Exchange (ETDEWEB)

Passive films formed on stainless steels in a borate buffer solution (pH 9.2) have been investigated by capacitance measurements and photoelectrochemistry. The study was carried out on films formed on AISI type 304 and 316 stainless steels and high purity alloys with differing chromium, nickel, and molybdenum contents. Complementary research by Auger analysis shows that the passive films are composed essentially of an inner chromium region in contact with the metallic substrate and an outer iron oxide region developed at the film/electrolyte interface. The semiconducting properties of the passive films are determined by those of the constituent chromium and iron oxides which are of p-type and n-type, respectively. Thus the influence of the alloying elements on the semiconducting properties of the passive films is explained by changes in the electronic structure of each of these two oxide regions.

Energy Technology Data Exchange (ETDEWEB)

At-pseudohalogen compounds with SCN/sup -/ and CN/sup -/ were synthesized at the first time using At(THETA)/sup +/, At/sup 0/ and At/sup -/. Investigations of the electromigration behaviour of these compounds in free electrolytes in dependence on the SCN/sup -/ and CN/sup -/ concentrations and on pH permit deductions about compound formation and hydrolysis behaviour. The formation constant for At(SCN)/sub 2//sup -/ is 4x10/sup 2/ lxmol/sup -1/ at an ion strength of 0.05/sup 2/ molxl/sup -1/. Between pH 7 and 9 hydrolysis takes place resulting in At/sup -/. The same result has been found in the case of the hydrolysis of AtCl/sub 2//sup -/ and AtBr/sub 2//sup -/.

Science.gov (United States)

A new process engineering flowsheet reflecting an improved design of the LASL Bismuth Sulfate thermochemical cycle is presented. The design is based on laboratory data that indicate a lowered endothermic heat load for a partial decomposition of the solid bismuth sulfate. A small electrical energy demand should result from operation of the sulfur dioxide electrolytic step at lower acid concentration, in principle. The results of the flowsheeting analysis yield a thermal efficiency of 50% for the cycle when coupled to a conceptual fusion energy heat source at 1500/sup 0/K. A parametric analysis shows a slight drop in efficiency as the temperature of the heat source is decreased. The LASL Bismuth Sulfate thermochemical cycle appears to have potential as a means of producing hydrogen from high-temperature heat sources such as fusion, fission, and solar energy; it also appears to be competitive with alternative thermochemical cycles as well as with water electrolysis ...

International Nuclear Information System (INIS)

The efficiency of electric power generation by dye-sensitized mesoscopic photovoltaic cells has been progressing steadily over the last years reaching now 11% in full sunlight. An important question for practical applications concerns the stability of these devices under prolonged exposure to light or heat. Strikingly stable operation can be obtained by judicious selection of the sensitizer, electrolyte and sealant rendering feasible a service life of at least 20 years under normal outdoor conditions. The sensitizer playing a central role in the light energy conversion process, we analyze the kinetic requirements for it to sustain the required one hundred million turnovers. We also review recent results on the use of self-assembled monolayers of amphiphilic sensitizers and co-adsorbents to enhance the thermal robustness of the device. (author)

Energy Technology Data Exchange (ETDEWEB)

Aluminium AA5182 coupons covered by a polyaniline film in the emeraldine base (EB) form showed increasing corrosion potential and decreasing corrosion current as a function of the thickness of the polymer layer. The cathodic reaction was proved not limited by diffusion of species inside the electrolyte solution and oxygen had no effect on the electrochemical behaviour of the coated samples. An EB coating on indium tin oxide conducting layer appeared slightly electroactive in neutral media. The IR spectra of aluminium coated samples, before and after heating in argon atmosphere, confirmed a redox reaction between the polymer film and the metal. This galvanic coupling can explain the good protective behaviour of emeraldine base against corrosion of aluminium.

International Nuclear Information System (INIS)

Formation of the complex of the univalent astatine cation with nitrilotriacetic acid (AtL)"2"- and its stability constant (lgK_1=8.97(4), 25degC, #mu#=0.1) have been found experimentally for the first time. The complex is stable in perchlorate solutions in presence of 5 . 10"-"3 mol . l"-"1 of the oxidizer Na_2S_2O_8 in the interval 4#<=#pH#<=#8.5. The complex is supposed to be destroyed in weak alkaline solutions by reduction of astatine to astatide. The deprotonation constant of hypoastatic acid pK_d_p=5.23(9) was found to be lower than determined previously. The investigation was carried out by the method of ion electrophoresis in free electrolyte solutions. (orig.).

Energy Technology Data Exchange (ETDEWEB)

The present volume on modeling of batteries and fuel cells discusses the significance of the effectiveness factor for flooded porous electrodes, active pore distribution spectroscopy for characterizing porous battery electrodes, the agglomerate model for porous electrodes, and dynamic-performance measurements of battery cells for electric vehicles and other applications. Attention is given to mathematical modeling of a primary zinc/air battery, mathematical modeling of Grace Li-TiS2 cells, modeling of electrocrystallization processes in battery systems, and rotating disk electrode studies in molten Li/K carbonate eutectic. Topics addressed include the variability of nickel oxide cathode dissolution in molten carbonate fuel cells, water transport properties of fuel cell ionomers, modeling water content effects in polymer electrolyte fuel cells, and computer algebra applied in electrochemistry and fuel cell modeling.

International Nuclear Information System (INIS)

Intergranular corrosion (IGC) resistance of types 304LN and 316LN stainless steels (SS) thermally aged at 823, 873, and 923 K for various durations was assessed by ASTM A262 practice A test (electrolytic etch test) and electrochemical potentiodynamic reactivation (EPR) test. The results indicated that the type 316LN SS has significantly improved IGC resistance compared to 304LN SS. Based on the results of these tests, time-temperature-sensitization (TTS) diagrams were developed for both alloys. The secondary precipitates formed during thermal aging treatments were electrochemically extracted and analyzed by X-ray diffraction (XRD) to determine the types of precipitates formed during the aging treatments. The results indicated that the precipitates were mostly of M_2_3C_6 carbides.

British Library Electronic Table of Contents (United Kingdom)

Durability is a major limitation of current proton exchange membrane fuel cells. Mechanical stress due to hygro-thermal cycling is one failure mechanism of the polymer electrolyte membrane. In previous work the cyclic rate, temperature, and hydration dependent elastic-viscoplastic mechanical behavior of Nafion has been extensively investigated in uniaxial and biaxial tension, serving as a data basis and means of validation for a three-dimensional constitutive model. Here, the important effect of loading via constrained swelling is studied. Specifically, two types of loading are investigated: partially constrained swelling via a bimaterial swelling test and hygro-thermal cycling within a fuel cell. The bimaterial swelling conditions are examined via experiments in conjunction with modeling....

Energy Technology Data Exchange (ETDEWEB)

Investigates polarographically determined capacitative curves of Soviet anthracite (Removsk seam) in solutions of KCl, HCl, phenol, propyl, butyl, amyl and hexyl alcohols. The curves were found to be asymmetric and to raise quickly in their cathode range. Their dependence on electrolyte concentration and displacements of their zero charge points were observed. Displacement values of zero charge potential were tabulated for organic compounds. It was possible to calculate displacements taking the non-uniformity of coal structure into account. It was further possible to assess surface interactions between coal and adsorbed molecules from the viewpoint of molecular energy. Orientation of phenol and alcohol molecules on the coal surface is also pointed out. 10 refs.

International Nuclear Information System (INIS)

The effect of surface treatment on the characteristics of the passive film on a super duplex stainless steel is addressed. Auger Electron Spectroscopy (AES) has been used to provide in-depth chemical profile analyses of the passivation film. This study showed that the constitution of the film is largely dependent on the electrolytic conditions under which it is produced or to which it is submitted. The passive films formed by polarisation in an alkaline solution (boric-borate solution) consist of two regions, an inner region rich in chromium and an outer region rich in iron, whilst the films produced in acid solution only present the chromium - rich region. The film thickness is also greatly affected by the polarisation conditions. It can vary from ca. 8 monolayers to about 20 monolayers for cathodically and anodically polarised specimens respectively. The microstructure of weldmetal is also discussed. (author)

Energy Technology Data Exchange (ETDEWEB)

A UPS based on a line-interactive system for CATV (Cable TV) networks has been newly developed. An inverter of the UPS featuring a pure sine wave output and equipped with an uninterrupptible transfer switch made it possible to raise its reliability high and to reduce the uninterruptible transfer time from 50 {approx} 100 ms to only 3 ms. The expected life of 15 years and maintenance-free of the UPS were realized by monitoring and optimizing the operational conditions of lead-acid batteries, aluminum electrolytic capacitors and cooling fans. The use of rust- and weather- resistant painting methods for an outer box of the UPS also contributed to extend the life of the system. (author)