WorldWideScience
 
 
1

Jump in the air gasification rate of potassium-doped cellulosic chars  

Energy Technology Data Exchange (ETDEWEB)

Chars prepared from potassium-exchanged carboxy methyl cellulose at several heat treatment temperatures (HTTs) were gasified in air isothermally at selected gasification temperatures (GTs) in the range 633-893 K to investigate the catalytic effectiveness of potassium species. The chars displayed a noticeable jump in gasification rate at a particular gasification temperature (called jump temperature, T{sub j}). The magnitude of jump was much less than that reported for copper and nickel catalysis, but comparable with that for calcium catalysis. Increase in HTT caused a decrease in the jump temperature of chars in contrast with the increase observed in copper, nickel and calcium catalysis; also the magnitude of jump did not decrease, but remained unaltered, on increasing HTT. The different behavior of potassium catalysis is correlated to a change in the chemical state of potassium at higher HTT. The results reveal the ...

2010-12-15

2

Microstructure and mechanical properties of quasi-carbon fibers and their polyacrylonitrile matrix composites  

Energy Technology Data Exchange (ETDEWEB)

Quasi-carbon fibers (QCFs) were prepared from Polyacrylonitrile (PAN) precursor by pyrolysis in the temperature range from 400{degrees}C to 950{degrees}C. The QCF-reinforced composites were fabricated by impregnating the QCFs with the PAN resin. The microstructural changes of both QCFs and their composites were characterized by the X-ray diffraction method. The stacking size and the crystallinity of the QCFs increased with the increasing heat treatment temperature (HTT). The crystallinity of the PAN matrix in a composite was also affected by various QCFs. DSC data indicated that thermal reaction mechanism of the composite could be altered due to the interaction between the fiber and the matrix. DMTA studies showed that good adhesion existed at the interface of the QCF-reinforced composites containing lower HTT fibers. The modulus magnitudes of QCFs and their composites increased with the QCF pyrolysis temperature. Although the QCFs exhibited a ...

1994-12-31

3

Research on pitting corrosion of steam generator heat transfer tubes based on acoustic emission  

International Nuclear Information System (INIS)

Corrosion of steam generator heat transfer tubes (SGHTT) is one of the important problems which affect safety operation of nuclear power plants (NPP), and the hazard of pitting corrosion of heat transfer tubes is the most serious. With an acoustic emission device, the signals during a corrosion test on SGHTT were collected and analyzed, and the corrosion points in the tubes were located accurately. The results show that pitting corrosion of heat transfer tubes has passed through three periods in its development: expansion phase, stationary phase and rapid developing phase. The corrosion damage of HTT can be found earlier with acoustic emission than any other non-destructive testing methods. Acoustic emission can be used for on-line and real-time monitoring of the safety and operation of the steam generator and has therefore a great significance. (orig.)

2010-09-01