Percutaneous osseointegrated prostheses for amputees: Limb compensation in a 12-month ovine model.
Percutaneous osseointegrated prostheses are being investigated as an alternative strategy to attach prosthetic limbs to patients. Although the use of these implants has shown to be promising in clinical trials, the ability to maintain a skin seal around an osseointegrated implant interface is a major challenge to prevent superficial and deep periprosthetic infections. The specific aim of this study was to establish a translational load-bearing ovine model to assess postoperative limb compensation and gait symmetry following a percutaneous osseointegrated implant. We tested the following hypotheses: (1) the animals would return to pre-amputation limb loads within 12-months; (2) the animals would return to a symmetrical gait pattern (stride length and time in stance) within 12-months. The results demonstrated that one month following surgery, the sheep loaded their amputated limb to a mean value of nearly 80% of their pre-amputation loading ...
2011-09-13
The Non-linear Relationship between Gait Speed and Falls: The MOBILIZE Boston Study
UK PubMed Central (United Kingdom)
OBJECTIVESAlthough several studies suggest that slow gait speed is a predictor of falls, it may also be a protective mechanism to prevent falls. Further, fast walking...Full Text Available
2011-06-01
Amputee Independent Prosthesis Properties-A new model for description and measurement.
A model is presented for describing the Amputee Independent Prosthesis Properties (AIPP) of complete assemblies of trans-tibial prosthetic components distal to the socket. This new AIPP model includes features of both lumped parameter and roll-over models and describes prosthesis properties that are of importance in stance phase, including prosthetic foot geometry, normal stiffness, shear stiffness, and damping (energy dissipation). Methods are described for measuring the parameters of the AIPP model using a custom test-rig, commercial load-cell, and a motion capture system. Example data are presented for five pylon angles reflecting the shank angles seen in normal gait. Through the inclusion of measured AIPP in future in-vivo studies comparing different prostheses more generic information, as opposed to product specific claims, will become more widely available to inform future designs, prescription, and alignment procedures. PMID:21831379
2011-08-09
Environmental Research Database
DescriptionLameness, commonly referred to as the leg health, in the modern broiler chicken is an emotive issue and the debate surrounding this subject is not helped by the lack of agreement as to how leg health should be assessed. A commonly used tool for scoring leg health is the Bristol Gait Score, a technique used in the recently reported Defra project AW0230 (`Leg Health and Welfare in Commercial Broiler Production`). The authors of the final report for AW0230 noted that for the chickens gait scored [continued...
2011-01-31
Rhythmic Dynamics and Synchronization via Dimensionality Reduction: Application to Human Gait
UK PubMed Central (United Kingdom)
Reliable characterization of locomotor dynamics of human walking is vital to understanding the neuromuscular control of human locomotion and disease diagnosis. However, the inherent oscillation and...Full Text Available
2010-12-01
Natural Gaits of the Non-Pathological Flat Foot and High-Arched Foot
UK PubMed Central (United Kingdom)
There has been a controversy as to whether or not the non-pathological flat foot and high-arched foot have an effect on human walking activities. The 3D foot scanning system was employed to obtain static...Full Text Available
Can treadmill walking be used to assess propulsion generation?
UK PubMed Central (United Kingdom)
Instrumented treadmills offer significant advantages for analysis of human locomotion, including recording consecutive steady-state gait cycles, precisely controlling walking speed, and avoiding...Full Text Available
2008-01-01
Phase composition of the VT22-alloy and its cyclic strength
International Nuclear Information System (INIS)
In connection with the different cyclical strengths of the two-phase (#alpha# + #beta#) titanium alloy in the case of the acicular and rounded formations of the #alpha#-phase, we have studied, employing the X-ray diffraction method, the phase composition of the alloy and the influence of heat treatment upon it. Using the method of electronic fractography, we examined the fractures in samples destroyed by the asymmetric twisting, in order to find out why the durability of the alloy is dependent upon the #alpha# - phase structure. It has been found that in the BT22 alloy, the decay the #beta#-phase may proceed in two ways; either with the formation of the martensite #alpha#'-phase of the acicular shape or with the separation of the non-martensite round-shaped #alpha#-phase. The character of the phase ...
UK PubMed Central (United Kingdom)
Cyclin-Dependent Kinase 1 (CDK1) is the major M-phase kinase known also as the M-phase Promoting Factor or MPF. Studies performed during the last decade have shown many details of how CDK1 is regulated...Full Text Available
UK PubMed Central (United Kingdom)
The effect of growth phase on expression of virulence-associated factors was studied by Northern hybridization in an M1T1 clinical isolate of Streptococcus pyogenes. Expression of M...Full Text Available
1999-10-01
The Bidimensional Stefan Problem with Convection: The Time-Dependent Case.
This paper considers the time dependent Stefan problem with convection in the fluid phase governed by the Stokes equation, and with adherence of the fluid on the lateral boundaries. The existence of a weak solution is obtained via the introduction of a te...
1982-01-01
Direct measurement of the alpha-epsilon transition stress and kinetics for shocked iron
Energy Technology Data Exchange (ETDEWEB)
Iron undergoes a polymorphic phase transformation from alpha phase (bcc) to the epsilon phase (hcp) when compressed to stresses exceeding 13 CPa. Bccause the epsilon phase is denser than the alpha phase, a single shock wave is unstable and breaks up into an elastic wave, a plastic wave, and a phase transition wave. Examination of this structured wave coupled with various phase transformation models has been used to indirectly examine the transition kinetics. Recently, multimillion atom simulations (molecular dynamics) have been used to examine the shock-induced transition in single crystal iron illustrating an orientation dependence of the transition stress, mechanisms, and kinetics. The objective of the current work was to perform plate impact experiments to examine the shock-response of polycrystalline and single ...
2009-01-01
Simulation of DNA electrophoresis through microstructures
British Library Electronic Table of Contents (United Kingdom)
The dependence of the mobility of DNA molecules through an hexagonal array of micropillars on their length and the applied electric field was investigated and it was found that mobility is a nonmonotonic function of their length. Results also revealed that the size dependence of the DNA mobility depends on the applied electric field and there is a crossover around E 25 V/cm for the mobility of l-DNA and T4-DNA. These observations are explained in terms of the diffusion process inside the structure affected by the solvent and are modeled using the Langevin and its corresponding Fokker-Planck equations. The phenomenon is generalized under three regimes in a phase diagram relating the electric field and the DNA lengths. The model and the associated phase diagram described here provide an expl...
2007-01-01
International Nuclear Information System (INIS)
An important application of metal hydrides is as a moderator material in nuclear reactors. The fundamental properties of hydrides are illustrated and an impression given of the current research into hydrogen in transition metals. Phase diagrams, magnetic properties, temperature dependence of the diffusion coefficient, energy level schemes and superconductivity are considered. (C.F.).
Drift compression and final focus of intense heavy ion beams
Energy Technology Data Exchange (ETDEWEB)
The longitudinal and transverse dynamics of a heavy ion fusion beam during the drift compression and final focus phase is studied. A lattice design with four time-dependent magnets is described that focuses the entire beam pulse onto a single focal point with the same spot size.
2003-05-01
UK PubMed Central (United Kingdom)
DNA damage is a threat to genomic integrity in all living organisms. Plants and green algae are particularly susceptible to DNA damage especially that caused by UV light, due to their light dependency...Full Text Available
Cloning and Analysis of a Candida albicans Gene That Affects Cell Surface Hydrophobicity
UK PubMed Central (United Kingdom)
The opportunistic pathogenic yeast Candida albicans exhibits growth phase-dependent changes in cell surface hydrophobicity, which has been correlated with adhesion to host tissues....Full Text Available
2001-06-01
Interaction of antimicrobial peptides with lipid membranes
International Nuclear Information System (INIS)
This study aims to investigate the difference in the interaction of antimicrobial peptides with two classes of zwitterionic peptides, phosphatidylethanolamines (PE) and phosphatidylcholines (PC). Further experiments were performed on model membranes prepared from specific bacterial lipids, lipopolysaccharides (LPS) isolated from Salmonella minnesota. The structure of the lipid-peptide aqueous dispersions was studied by small-and wide-angle X-ray diffraction during heating and cooling from 5 to 85 C. The lipids and peptides were mixed at lipid-to-peptide ratios 10-10000 (POPE and POPC) or 2-50 (LPS). All experiments were performed at synchrotron soft condensed matter beamline A2 in Hasylab at Desy in Hamburg, Germany. The phases were identified and the lattice parameters were calculated. Alamethicin and melittin interact in similar ways with the lipids. Pure POPC forms only lamellar phases. POPE forms lamellar phases at low ...
Nanosized copper ferrite materials: Mechanochemical synthesis and characterization
International Nuclear Information System (INIS)
Nanodimensional powders of cubic copper ferrite are synthesized by two-steps procedure of co-precipitation of copper and iron hydroxide carbonates, followed by mechanochemical treatment. X-ray powder diffraction, Moessbauer spectroscopy and temperature-programmed reduction are used for the characterization of the obtained materials. Their catalytic behavior is tested in methanol decomposition to hydrogen and CO and total oxidation of toluene. Formation of nanosized ferrite material is registered even after one hour of milling time. It is established that the prolonging of treatment procedure decreases the dispersion of the obtained product with the appearance of Fe2O3. It is demonstrated that the catalytic behavior of the samples depends not only on their initial phase composition, but on the concomitant ferrite phase transformations by the influence of the reaction medium. -- Graphical abstract: It is demonstrated that the ...
2011-05-01
International Nuclear Information System (INIS)
The thermal transformation of Al-base icosahedral phases was studied in-situ by real time neutron powder diffraction. Different compositions have been selected in order to vary the initial phase morphology and change the neutron scattering contrast between species. Alloys with low silicon and large aluminium contents produce first the orthorhombic O-Al_6Mn modification. In alloys with larger silicon content, the #alpha#-AlMnSi cubic phase appears soon after the beginning of the transformation but is still preceeded by O-Al_6Mn. Depending on compositions, the crystallization of the icosahedral phase is controlled either by the diffusion of Al through its interface with the residual fcc aluminium or that of Si within the bulk. The results are discussed in the light of current structural models. (author) 40 refs., 14 figs., 3 tabs.
1987-01-01
New High-Pressure Excitations in Parahydrogen
Energy Technology Data Exchange (ETDEWEB)
Raman and infrared spectroscopy of para-H{sub 2} to pressures in excess of 200GPa and to 8K using new ultrapure synthetic diamond anvils reveals numerous new vibrational excitations in the three high-pressure phases. Highly resolved Raman-active librons indicate differences in orientational ordering between phasesII and III, including evidence for changes within phaseII. The librons in phaseIII are strongly pressure dependent and reflect a substantial increase in ordering with pressure. Multiple vibrons in all three phases (I, II, and III) are observed. The results place new bounds on predicted crystal structures and dynamics of the dense molecular solid. {copyright} {ital 1997} {ital The American Physical Society}
1998-01-01
Analysis of the dynamics of the cavity radiation of a coherently pumped correlated emission laser is presented. The phase fluctuation and dephasing are found to affect the time evolution of the two-mode squeezing and intensity of the cavity radiation significantly. The intensity and degree of the two-mode squeezing increase at early stages of the process with time, but this trend changes rapidly afterwards. It is also shown that they increase with phase fluctuation and dephasing in the strong driving limit, however the situation appears to be opposite in the weak driving limit. This essentially suggests that the phase fluctuation and dephasing weaken the coherence induced by a strong driving mechanism so that the spontaneous emission gets a chance. The other important aspect of the phase fluctuation, in this regard, is the relaxation of the time at which the maximum squeezing is manifested as well as ...
2010-01-01
A-15 compounds as solid solutions of elements
Energy Technology Data Exchange (ETDEWEB)
Experimental data on A-15 binary phases (the lattice parameter dependence on composition, phase diagrams, etc.) have been considered and the so-called ''compounds with A-15 structure'' are shown to be solid solutions of element substitution in the structure of A-15 type. Values of lattice parameter and atomic volume of A-15 modifications for 21 elements have been obtained (for Zr, W, Nb, Mo, V in particular). There has been shown the possibility of calculation of atomic volumes and lattice parameters of A-15 binary phases at the lack of direct experimental data. The essential role of atomic volume relations of different phases has been observed for the estimation of stability conditions of A-15 phase.
1984-09-01
A-15 compounds as solid solutions of elements
International Nuclear Information System (INIS)
Experimental data on A-15 binary phases (the lattice parameter dependence on composition, phase diagrams, etc.) have been considered and the so-called ''compounds with A-15 structure'' are shown to be solid solutions of element substitution in the structure of A-15 type. Values of lattice parameter and atomic volume of A-15 modifications for 21 elements have been obtained (for Zr, W, Nb, Mo, V in particular). There has been shown the possibility of calculation of atomic volumes and lattice parameters of A-15 binary phases at the lack of direct experimental data. The essential role of atomic volume relations of different phases has been observed for the estimation of stability conditions of A-15 phase.
Energy Technology Data Exchange (ETDEWEB)
The amorphization of a quenched sample of the GaSb-II high-pressure phase was studied at ambient pressure by real-time neutron diffraction in the course of the sample heating from 100 K to room temperature at a rate of 0.4 K min{sup -1}. The transformation to the amorphous state begins at 140 K and is completed near room temperature. The {beta}-Sn type structure was shown to represent only the mean lattice of the high-pressure GaSb-II phase. The superstructure of this phase widely varied with temperature and is caused by the ordered displacement of atoms. The temperature range of the metastable crystalline phase relaxation is divided into three intervals according to the temperature dependence of the tetragonality ratio (c/a). At the boundaries of these temperature intervals, i.e. temperatures T = 170 and 230 K, two second-order phase transitions are observed. ...
2009-01-28
International Nuclear Information System (INIS)
The amorphization of a quenched sample of the GaSb-II high-pressure phase was studied at ambient pressure by real-time neutron diffraction in the course of the sample heating from 100 K to room temperature at a rate of 0.4 K min-1. The transformation to the amorphous state begins at 140 K and is completed near room temperature. The ?-Sn type structure was shown to represent only the mean lattice of the high-pressure GaSb-II phase. The superstructure of this phase widely varied with temperature and is caused by the ordered displacement of atoms. The temperature range of the metastable crystalline phase relaxation is divided into three intervals according to the temperature dependence of the tetragonality ratio (c/a). At the boundaries of these temperature intervals, i.e. temperatures T = 170 and 230 K, two second-order phase transitions are observed. Anomalous ...
2009-01-28
Solvent extraction of well defined astatine species
International Nuclear Information System (INIS)
During solvent extraction of At"-, [At(H_2O)_2]"+, AtCl, AtCl_2"- as well as of astatine compounds with higher oxidation states like AtO_n"-, the astatine species are changed into astatine of the oxidation state zero at the phase boundary independent on the organic solvent used. At(O) probably reacts with components of the organic phase or with decomposition products formed by chemical reactions or by radiolysis. The extraction coefficients of the astatine species depend on the experimental conditions applied, the redox potential, and on complex forming reactions or associations, resp., occuring in the aqueous phase. (author).
The thermochromic properties of La{sub 1-x}Sr{sub x}MnO{sub 3} compounds
Energy Technology Data Exchange (ETDEWEB)
La{sub 1-x}Sr{sub x}MnO{sub 3} (LSMO) compounds (0.175{<=}x{<=}0.30) were prepared by conventional solid-state reaction method. Temperature dependence of the total hemispherical emittance ({epsilon}{sub H}) of the compounds from 173 to 373 K was measured on a calorimetric emissometer (CE) which was constructed based on the steady-state calorimetric method. The compounds show thermochromic properties and {epsilon}{sub H}'s have low value at low temperature and have high value at high temperature, because the compounds are dominated by metallic phase and insulator phase, respectively. We use the phase separation model to interpret the temperature dependence of {epsilon}{sub H}. (author)
2008-10-15
International Nuclear Information System (INIS)
The temperature dependences of the Grueneisen parameter, heat capacity, bulk modulus and linear thermal expansion coefficient of sixteen III-V zincblende compounds are studied by first-principles response-function calculations. The fundamental relationships among these physical parameters are explored. Negative thermal expansions at lower temperature are found in most of these III-V phases except for the nitrides and boron compounds. By analyzing the cell-volume dependences of the phonon spectrum, it is found that the phases with a negative thermal expansion show a significant acoustic phonon weakening at the X-point in their phonon dispersion, while slight weakening is only seen around the L-point for those boron phases. There is no sign of phonon weakening in the nitrides. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)
2009-07-01
British Library Electronic Table of Contents (United Kingdom)
Deltombe T, Gustin T. Selective tibial neurotomy in the treatment of spastic equinovarus foot in hemiplegic patients: a 2-year longitudinal follow-up of 30 cases. Objective To assess the long-term efficacy of selective tibial neurotomy in the treatment of spastic equinovarus foot in hemiplegic patients. Design Intervention study (before-after trial) with an observational design and 2-year follow-up. Setting Spasticity group in a university hospital. Participants Hemiplegic patients (N=30) with spastic equinovarus foot. Intervention A selective neurotomy was performed at the level of the motor nerve branches of the tibial nerve. Main Outcome Measures Spasticity (Ashworth scale), muscle strength (Medical Research Council scale), passive ankle dorsiflexion, gait parameters (6 min walking test...
2010-01-01
British Library Electronic Table of Contents (United Kingdom)
To document the range of activity and patterns of normal surface kinesiological electromyography in normal children, 87 children ranging from age 3 to 18 years who were developing normally were evaluated at free walking speed. Analysis was performed on 6307 gait cycles from 11 different muscles with custom software. We devised an algorithm to do a computer-based KEMG curve pattern analysis to sort out curves that did not match the physiologic muscle activity pattern, We also devised a combined preset amplitude and statistics-based criteria to satisfactorily determine the onset/cessation of KEMG activity. The measurements of timing and duration of activity, body height and weight, body mass index, cadence, stride length, and age were obtained for statistical analysis. From the pattern recog...
2007-01-01
Fixation Techniques for Split Anterior Tibialis Transfer in Spastic Equinovarus Feet
British Library Electronic Table of Contents (United Kingdom)
Equinovarus of the foot is the most common lower extremity deformity following traumatic brain injury. We evaluated outcomes of the split anterior tibialis tendon transfer (SPLATT) for correction of equinovarus in 47 patients with hemiplegic traumatic brain injury and specifically studied differences in outcomes with two tendon fixation techniques. Seventeen patients constituting Group I underwent fixation with one technique and 30 constituting Group II had another technique. Patients in both groups had appropriate procedures based on dynamic electromyography and gait analyses. Both groups were demographically comparable. All 47 feet were corrected to plantigrade position. Thirty-six of 47 patients became brace-free at final followup. There was a notable decrease in the use of ambulatory a...
2008-01-01
Microwave axial free-electron laser with enhanced phase stability
International Nuclear Information System (INIS)
Free-electron laser (FEL) amplifiers have demonstrated high efficiencies and high output power at microwave wavelengths. However, measurements and simulations have indicated that the present level of phase stability for these devices is not sufficient for driving linear accelerators. Fluctuations in the diode voltage, which is needed to accelerate the electron beam, are the largest cause of the shifts in the phase of the output power. Pulse-power technology cannot keep the voltage fluctuations less than 1/4%. However, we have found a scheme that will make the output phase much less sensitive to these fluctuations by exploiting the traveling wave nature of the FEL interaction. In this paper we study the phase stability issue by analyzing the dispersion relation for an axial FEL, in which the rf field is transversely wiggled and the electron trajectories are purely longitudinal. The advantage of using the ...
1995-08-21
Energy Technology Data Exchange (ETDEWEB)
The distribution of the alkaline earth elements strontium and barium between the solid phases of phosphates of transition elements of group 4 and chloride melts was studied. The distribution coefficients of strontium and barium were found at T = 700-800/sup 0/C. Phosphates of the type NaM/sub 2//sup (IV)/(PO/sub 4/)/sub 3/, where M/sub (IV)/ represents titanium, zirconium, and hafnium, were used as the solid phases. It was established that there is an enrichment of the precipitates with the distributed components. The distribution coefficient depends on the nature of the solid phase and the temperature. It was suggested that M/sup (II)/ x M/sub 4//sup (IV)/(PO/sub 4/)/sub 6/ is formed in processes of distribution, where M/sup (II)/ represents Sr, Ba.
1987-07-01
Phase stability, electronic and elastic properties of ScN
International Nuclear Information System (INIS)
The structural stability, electronic and elastic properties of ScN under high pressure were investigated by using full-potential linearized augmented plane-wave (FP-LAPW) method. Our calculations indicate that there exists a pressure-induced structural phase transformation from the ambient rock-salt (B1) phase to CsCl-type (B2) phase above 335 GPa. The origin of moderate high bulk modulus, mechanical and high melting point was analyzed by electronic properties. The variations of elastic constants (C_i_j) with volume and pressure have been investigated. Moreover, the volume dependencies of Debye temperature, the longitudinal and transverse elastic wave velocities have been presented.
2010-06-01
A review of heat exchanger tube bundle vibrations in two-phase cross-flow
International Nuclear Information System (INIS)
Flow-induced vibration is an important concern to the designers of heat exchangers subjected to high flows of gases or liquids. Two-phase cross-flow occurs in industrial heat exchangers, such as nuclear steam generators, condensers, and boilers, etc. Under certain flow regimes and fluid velocities, the fluid forces result in tube vibration and damage due to fretting and fatigue. Prediction of these forces requires an understanding of the flow regimes found in heat exchanger tube bundles. Excessive vibrations under normal operating conditions can lead to tube failure. Relatively little information exists on two-phase vibration. This is not surprising as single-phase flow induced vibration; a simpler topic is not yet fully understood. Vibration in two-phase is much more complex because it depends upon two-phase flow regime, i.e. characteristics of ...
2004-05-01
Multidimensional two-phase flow regime distribution in a PWR downcomer during an LBLOCA refill phase
Energy Technology Data Exchange (ETDEWEB)
The multidimensional countercurrent two-phase flow regimes that occur in a pressurized-water reactor (PWR) vessel downcomer during the refill phase of a large-break loss-of-coolant accident are studied using a transparent 1/10 scale model of a PWR vessel. The various flow regimes and their distribution in the downcomer have been identified and mapped for a range of air-water flooding experiments. The two-phase flow patterns that are identified in the downcomer included various types of film flows, droplet flows, countercurrent churn flows and cocurrent flows depending on the flooding condition. Through observation of the two-phase flow dynamics it was deduced that the physical mechanisms associated with the flooding processes could be separated into a liquid entrainment process and a film flow reversal process. In addition to the above exercise, the effect of non-uniform injection ...
1994-09-01
Multidimensional two-phase flow regime distribution in a PWR downcomer during an LBLOCA refill phase
International Nuclear Information System (INIS)
The multidimensional countercurrent two-phase flow regimes that occur in a pressurized-water reactor (PWR) vessel downcomer during the refill phase of a large-break loss-of-coolant accident are studied using a transparent 1/10 scale model of a PWR vessel. The various flow regimes and their distribution in the downcomer have been identified and mapped for a range of air-water flooding experiments. The two-phase flow patterns that are identified in the downcomer included various types of film flows, droplet flows, countercurrent churn flows and cocurrent flows depending on the flooding condition. Through observation of the two-phase flow dynamics it was deduced that the physical mechanisms associated with the flooding processes could be separated into a liquid entrainment process and a film flow reversal process. In addition to the above exercise, the effect of non-uniform injection ...
1993-10-01
Energy Technology Data Exchange (ETDEWEB)
Nickel-titanium alloys may coexist in more than one crystalline structure. There is a high temperature phase, austenite, and a low temperature phase, martensite. The metallurgical basis for the superelasticity and the shape memory effect relies in the ability of these alloys to transform easily from one phase to another. There are three essential factors for the orthodontist to understand nickel-titanium alloys behaviour: stress; deflection; and temperature. These three factors are related to each other by the stress-deflection, stress-temperature and deflection-temperature diagrams. This work was undertaken with the objective to analyse commercial nickel-titanium alloys for orthodontics application, using the dynamical mechanical analyser - DMA. Four NiTi 0,017 X 0,025'' archwires were studied. The archwires were Copper NiTi 35 deg C (Ormco), Neo Sentalloy F200 (GAC), Nitinol Superelastic (Unitek) and ...
2002-07-01
True and measured outgassing rates of a vacuum chamber with a reversibly adsorbed phase
Energy Technology Data Exchange (ETDEWEB)
A pump down model for a vacuum chamber with a reversibly adsorbed phase is presented. The outgassing equation which predicts the variation of coverage at the wall surface of a vacuum chamber with time is derived. Then the measured and the true outgassing rates are defined. The theoretical measured outgassing rate shows only a very weak dependence for pumping speed. This prediction is opposite to the experimental result that the measured outgassing rate depends significantly on pumping speed. It is discussed that the experimental measured outgassing rate must be described as the product of the effective pumping speed and the measured pressure in the pumped chamber, in which the measured pressure is equivalent to the equilibrium pressure of the wall surface described by the equilibrium adsorption isotherm as a function of the shifted surface coverage {theta}-{delta}{theta} by a small coverage {delta}{theta} from the coverage ...
2000-03-01
Radius of thawing around an injection well and time of complete freezeback
An approximate method of calculating the radius of thawing around an injection well is presented. The method is based on the assumption that for a cylindrical system the position of the phase interface in the Stefan problem can be approximated through two functions: one function determines the position of the melting-temperature isotherm in the problem without phase transitions and the second function does not depend on time. The adjusted heating time concept was used to describe the first function. The second function is a known analytical relationship and is expressed in terms of ice content, thermal properties of thawed/frozen formations, formation temperature and the temperature of the injected fluid. Simple approximate formulae are suggested to estimate the duration of the freezeback period. To verify the proposed formulae, the results of numerical solutions were used. An example which shows that the duration of the ...
2006-06-01
Particulate composites in the TiC-TiYTZP system
International Nuclear Information System (INIS)
Twelve powders of TiO_2-Y_2O_3-ZrO_2 solid solution of the methodically changed composition were prepared by a coprecipitation-calcination technique. After mixing with phenol-formaldehyde resin, the powders were calcinated for 2 hours at 1200"oC in vacuum. The resultant composite powders contained TiC and non-reacted carbon. Green compacts were sintered in vacuum at 1500"oC for 2 hours. A temperature increase was stopped at 1200"oC to react remains of carbon. There were two carbides in the composites TiC and ZrC. TiC non-stoichiometry depended on carbon content in the system. Phase composition of the depended on of titania and yttria in zirconia solid solution. The majority of the samples showed two tetragonal zirconia phases differing in lattice parameter and tetragonality. (author)
2004-09-12
Nuclear magnetic resonance study of La_3X compounds and related phases
International Nuclear Information System (INIS)
Normal state nuclear magnetic resonance studies of the La_3In, La_3Tl compounds have been made in order to investigate the origin of the large temperature-dependent magnetic susceptibility. It is possible to analyse the different contributions to the susceptibility using Knight-shift and relaxation time T_1 measurements of In"1"1"5 and Tl"2"0"5 nuclei. The exchange enhancement of the spin-susceptibility chisub(pd) is of the same order as that found in A-15 compounds and the strong temperature-dependence of chi(T) is attributed to the presence of a peak in the electronic density of states near the Fermi level. The variation of the Knight-shift in the ternary alloys La_3Xsub(1-y)Xsub(y)sup(') is analogous to that observed in the corresponding La_3X phases, on the other hand the Knight-shift in the carbides La_3XC is temperature independent. (author).
Turbulent characteristics of a statified two-phase flow in a horisontal plane channel
International Nuclear Information System (INIS)
Experimental investigations of the turbulence characteristics of the air flow above the wave surface of the film in the horizontal rectangular channel in the 5-20 m/s velosity range of the air rate change (Reynolds number for the air 120O0-48000, 100-1000 for the film) are carried out. It is shown that intensities of turbulent pulsations of the rate increase with the growth of liquid flow rate in the film especially in the region of large squall waves. The experimental results on the pulsations are presented in the dimensionless form by a universal dependence. Distributions of tangentials of turbulent stresses above the film are obtained, turbulent stresses are compared with friction losses at the phase interface.
1982-02-01
Spontaneous and stimulated Raman studies of vibrational dephasing in condensed phases
Energy Technology Data Exchange (ETDEWEB)
Vibrational dephasing in condensed phases is studied from both a theoretical and experimental standpoint. A theory is presented which describes the dynamics of motional or exchange processes in weakly perturbed systems. This general formalism, which has been previously used to describe motional narrowing in magnetic resonance, is applied to vibrational spectroscopy. The model treats the case of a high frequency vibration anharmonically coupled to a low-frequency vibration. Intermolecular exchange of low frequency vibrational quanta results in a temperature dependent broadening and frequency shift of the high frequency vibration. Analysis of experimental data by this model yields both the exchange rates and the anharmonic couplings.
1980-05-01
Properties of s-p and s-d type A-15 superconductors: a comparison
International Nuclear Information System (INIS)
In general there are actually two different types of A-15 compounds (A_3B) whose superconducting properties depend on whether the B atoms are transition elements (s-d type) or nontransition elements (s-p type). The properties in which the s-d type superconductors show marked differences in behavior from the s-p type include: (1) stoichiometry and range of composition, (2) the strong influence of N(O) on the stability and T/sub c/ of the phase, and (3), the effect of composition and atomic ordering on the T/sub c/ of the phase. These differences are discussed and a conclusion presented.
Phase diagram and effective shape of semi-flexible colloidal rods and biopolymers
We study suspensions of semi-flexible colloidal rods and biopolymers using an Onsager-type second-virial functional for a segmented-chain model. For suspensions of thin and thick fd virus particles we calculate phase diagrams in quantitative agreement with experimental observations, and we find their effective state-point dependent shape to be much shorter and thicker than the actual shape. We also calculate the stretching of worm-like micelles in a host fd virus solution, again finding agreement with experiments. For both systems, our results show that the fd virus stiffness can play a key role in system behavior.
2011-01-01
Influence of the massicot Pb O in PLZT ceramics
International Nuclear Information System (INIS)
(Pb_1_-_x La_x) (Zr_0_._6_5 Ti_0_._3_5) ceramics, with x = 0.09 (PLZT 9/65/35) were prepared using lead monoxide (Pb O) with different amount of litharge (tetragonal) and massicot (orthorhombic) phases. Results, based on x-ray diffraction patterns, remanent polarization and dielectric measurements, show that the Pb O polymorphic phase does not change the final structure of the PLZT but causes changes on the remanent polarization and dielectric permittivity temperature dependence. (author). 11 refs, 2 figs, 2 tabs.
1994-06-18
Gas-liquid phase equilibrium in the system carbon dioxide-hexametapol (hexamethylphosphoramide)
Energy Technology Data Exchange (ETDEWEB)
The authors investigated phase equilibria in the system carbon dioxide-hexametapol. Vacuum-distilled solvent of ''pure'' grade was used. The solubility of CO/sub 2/ in hexametapol under pressures at various temperatures and the temperature dependence of the Henry's law coefficient is show. It is concluded that the solubility of carbon dioxide in hexametapol in the temperature and pressure ranges corresponding to the operating conditions of industrial equipment for removing CO/sub 2/ from gases conforms to the Krichevskii-II'inskaya equation. The experimental data can be used for equipment design.
1985-09-01
International Nuclear Information System (INIS)
In a program to develop a metastable beta alloy with improved fracture toughness, it was found that the tensile ductility of the alloy Ti-8 Mo-4.5 Cr-2.5 Al was strongly dependent on both processing history and annealing temperature. Evaluation of the microfracture mode of tensile samples by scanning electron microscope and metallographic techniques showed that the presence of a continuous grain boundary alpha is the most significant parameter controlling the ductility and is highly detrimental. It is concluded that, for optimum processing, the material must be worked prior to aging to avoid this grain boundary phase.
Bidimensional instability in antiferroelectric liquid crystals
Scientific Electronic Library Online (English)
Abstract in english In the last decade it has been experimentally found a periodic domain pattern arising in smectic C* liquid crystals in surface stabilized bookshelf geometry. Such a periodic texture appears after switching-off an external electric field, even in strong anchoring conditions. It has a static character and can be bidimensional, being dependent on both directions normal to the smectic planes and normal to the cell plates. In the present work an explanation to this phenomenon (more) is proposed. According to our model in the antiferroelectric phase the biperiodic texture is a threshold phenomenon, appearing for values of the spontaneous polarization greater than a critical value, whereas in the ferroelectric phase this type of bidimensional instability is hindered.
2002-06-01
Two-phase flow regime characterization in a PWR hot leg with candy cane geometry
International Nuclear Information System (INIS)
This paper describes a series of tests investigating two-phase flow regimes in a transparent model of a PWR hot leg. Test conditions were selected to cover a wide range of gas and liquid superficial velocities (.01 m/s 2 m/s) were also performed for comparison with semi-analytical predictions. Results include average void fractions, flow rates, and visual characterizations of the two-phase flow phenomena. Results show generally good agreement with Taitel and Duckler flow regime map and Zuber-Findlay correlation for average void fraction in vertical pipes. Results also indicate that flow regimes and collapsed liquid level (void fraction) are more strongly dependent on air flow rate (air superficial velocity) than water flow rate (water superficial velocity).
1984-10-01
International Nuclear Information System (INIS)
In recent years, there has been increased emphasis on techniques to enhance two-phase flow heat transfer. The resulting increase in the use of heat transfer augmentation and the engineering importance of the subject presents this investigation in order to study the effect of different heater surface configurations on two-phase flow instabilities. The authors present the results of an experimental and theoretical study, summarized as: instabilities are not affected by small changes in heat transfer; nucleate boiling increases system unstability; amplitude of the oscillations increases as the axial temperature gradient over the heater increases; for the same type heater surfaces system stability increases with decreasing equivalent diameter; period of the oscillations depend on the heater surfaces; and linearized analysis and steady-state data can be used to determine the oscillation thresholds.
1985-10-01
British Library Electronic Table of Contents (United Kingdom)
Abstract Phase-separation dynamics are investigated by SALS in aqueous MC solutions in the presence of 5% NaCl, promoted by a quench temperature. The observed scattering peak indicates that the phase separation occurs by the SD mechanism, leading to a bicontinuous structure. A semilog plot of I(q) against time in the early stage of SD gives a straight line, but the position of qmax varies; also, a Cahn-Hilliard plot indicates that diffusive processes dominate and the data can be described by linear CHC theory. Dapp shows a kinetic dependency on the quench temperature. The spinodal temperature of the sample is 41-C. In the late stages, S(q,t) collapses into a universally time-independent curve.
2011-01-01
Phase transition in a simple plasma model
A phase transition of gas-liquid type with an upper critical point is examined which arises in a model of charges of one sign on compensating background (OCP). The phase transition parameters are dependent on the detailed assumptions about the compressibility of the background, but the occurrence of this transition is independent on the background equation of state. In the electron-gas model ('jellium'), this transition appears to rule out Wigner crystallization. A variational principle in statistical mechanics is used to derive so-called Double-OCP model for a superposition of two one-component plasma models for charges of opposite sign. The free energy of this model sets an upper bound to that of a real plasma. Situations are discussed where this transition should manifest itself in anomalies in the approximate description of a non-ideal plasma.
2009-01-01
Microgravity two-phase flow regime modeling
Energy Technology Data Exchange (ETDEWEB)
A flow pattern or flow regime is the characteristics spatial distribution of the phases of fluid in a duct. Since heat transfer and pressure drop are dependent on the characteristic distribution of the phases, it is necessary to describe flow patterns in an appropriate manner so that a hydrodynamic or heat transfer theory applicable to that pattern can be chosen. The objective of the present analysis is to create a flow regime map based on physical modeling of vapor/liquid interaction phenomena in a microgravity environment. In the present work, four basic flow patterns are defined: dispersed flow, stratified flow, slug flow, and annular flow. Fluid properties, liquid and vapor flow rates, and pipe size were chosen as the principal parameters. It is assumed that a transition from one flow pattern to another will occur when there is a change in the dominant force which controls that flow pattern. The forces considered in ...
1987-01-01
International Nuclear Information System (INIS)
In the paper results of the investigation on the effect of microstructure on room temperature tensile properties and fracture toughness of two-phase #alpha#+#beta# titanium alloy Ti-6Al-2Mo-2Cr have been presented. Microstructure has been varied by changes in the cooling rate from the solution treatment temperature and aging time and temperature. Mechanical properties examined show dependence on the treatment conditions, especially aging conditions. It has been attributed mainly to the amount and morphology of #alpha# phase obtained after heat treatment. The higher volume fraction of lamellar #alpha# structure, the higher fracture toughness. (author)
1998-05-17
British Library Electronic Table of Contents (United Kingdom)
The dependence of melting temperature T m on the size and shape of an n -dimensional nanocrystal of elementary single-component substance is studied. The nanocrystal has the form of an n-dimensional parallelepiped with a square base. The ratio of the length of side rib to the length of base rib (which is equal to f) defines the form of the system. It is demonstrated that, if the surface pressure is ignored, the value of T m decreases with isomorphic (f = const) decrease in the size of nanocrystal. In so doing, the more the value of form parameter f deviates from unity, the more appreciable the size dependence of T m will be. However, if the surface pressure (?Laplace pressure??) is taken into account in the case of decrease in size, the value of T m may vary significantly. In so doing, if ...
2009-01-01
British Library Electronic Table of Contents (United Kingdom)
An Environmental Impact Assessment (EIA) study for any project is a time- consuming process because it has a large number of dependent and independent variables that must be taken into account. Although EIAs are dependent on geo-spatial information in order to make an assessment, there are no standard rules for conducting an environmental assessment. In addition, each assessment objective is case-dependent, based on what information is available. This paper presents a new framework for the analysis phase of the Environmental Impact Assessment (EIA) for projects, based on the integration between remote sensing technology, geographic information systems, and spatial modeling. The framework comprehensively analyzes the environmental vulnerability around the project areas and its impact on the...
2010-01-01
Dynamic and static error analyses of neutron radiography testing
Energy Technology Data Exchange (ETDEWEB)
Neutron radiography systems are being used for real-time visualization of the dynamic behavior as well as time-averaged measurements of spatial vapor fraction distributions for two phase fluids. The data in the form of video images are typically recorded on videotape at 30 frames per second. Image analysis of he video pictures is used to extract time-dependent or time-averaged data. The determination of the average vapor fraction requires averaging of the logarithm of time-dependent intensity measurements of the neutron beam (gray scale distribution of the image) that passes through the fluid. This could be significantly different than averaging the intensity of the transmitted beam and then taking the logarithm of that term. This difference is termed the dynamic error (error in the time-averaged vapor fractions due to the inherent time-dependence of the measured data) and is separate from the static ...
1999-03-01
Immobilization of stationary phases onto chromatographic supports by gamma radiation
International Nuclear Information System (INIS)
Cobalt-60 gamma radiation has been found to be an effective means of immobilizing stationary phases onto gas and liquid chromatographic supports. The ability of a phase to crosslink was determined to be highly dependent on its chemical structure. Gamma radiation was employed to immobilize Se-30, a methylsilicone, and 216 PS onto Chromosorb WHP for packed column chromatography. The resultant columns exhibited increased thermal stability and a high degree of efficiency. Several blended phases containing varying ratios of Se-30:216 PS were also immobilized onto chromatographic packings. This work was further extended to the immobilization of Se-30 and 216 PS onto fused silica capillaries via gamma radiation. Columns exhibited excellent efficiency and improved thermal stability. An investigation into the role of immobilization of polymeric phases for HPLC was undertaken. Results ...
Growth of single-crystal metastable semiconducting (GaSb)_1/sub -//sub x/Ge/sub x/ films
International Nuclear Information System (INIS)
Epitaxial metastable (GaSb)/sub 1-x/Ge/sub x/ alloys with compostions across the pseudobinary phase diagram have been grown on (100) GaAs substrates by multitarget rf sputtering. An essential feature allowing the growth of these metastable materials was low-energy ion bombardment of the growing film during deposition to enhance surface diffusion, promote mixing, and preferentially sputter incipient second-phase precipitates. Annealing experiments indicated that the metastable films exhibit good high-temperature stability and that they transform through a continuous series of GaSb-rich and Ge-rich phases in which the solute concentrations decrease until the equilibrium two-phase alloy is obtained. While the calculated free-energy difference between the single-phase metastable and equilibrium states is approx.18 meV, the measured activation barrier for the transformation is approx.3 ...
6180-01-01
Design and Development of a Test Facility to Study Two-Phase Steam/Water Flow in Porous Media
Energy Technology Data Exchange (ETDEWEB)
The concept of relative permeability is the key concept in extending Darcy's law for single phase flow through porous media to the two-phase flow regime. Relative permeability functions are needed for simulation studies of two-phase geothermal reservoirs. These are poorly known inspite of considerable theoretical and experimental investigations during the last decade. Since no conclusive results exist, many investigators use ad hoc parametrization, or adopt results obtined from flow of oil and gas (Corey, 1954). It has been shown by Reda and Eaton (1980) that this can lead to serious deficiencies. Sensitivity of the relative permeability curves for prediction of mass flow rate and flowing enthalpy into geothermal wells has been studied by many investigators (e.g. Eaton and Reda (1980), Bodvarsson et al (1980), Sun and Ershagi (1979) etc.). It can be concluded from these studies that the beehavior of a ...
1983-12-15
Sorption of heteropoly acids by polyurethane foam
International Nuclear Information System (INIS)
Sorption of oxidized and reduced forms of molybdosilicic, molybdophosphoric and molybdovanadophosphoric acids by polyurethane foam based on ethers and esters is studied. On the basis of sorption dependence on solution pH, polyurethane foam type and spectral characteristics of sorbates the suggestion has been made that in the polyurethane foam phase there are two main types of sorbent-sorbate interaction: electrostatic (ion-ion) and with hydrogen bond formation: and it is impossible to determine the contribution of every interaction
1997-12-01
International Nuclear Information System (INIS)
Paper estimates the corrosion resistance and studies the character of dissolving of silicon-bearing austenite stainless steels in strongly oxidizing media containing phosphate and fluoride admixtures. Corrosion behaviour of the studied steels is determined to depend essentially on the content of admixture or alloying silicon, as well as, on their phase composition in many respects determined by the thermal treatment condition. Refs. 22, figs. 1, tabs. 2.
Rotational modes of oscillation of rodlike dust grains in a plasma
Three dimensional rotatory modes of oscillations in a one-dimensional chain of rodlike charged particles or dust grains in a plasma are investigated. The dispersion characteristics of the modes are analyzed. The stability of different equilibrium orientations of the rods, phase transitions between the different equilibria, and a critical dependence on the relative strength of the confining potential are analyzed. The relations of these processes with liquid crystals, nanotubing, and plasma coating are discussed.
2003-01-01
Energy Technology Data Exchange (ETDEWEB)
This paper presents the experimental measurements of the transmittivity of commercial grade stearic acid. The effects of temperature and thickness on transmittance have been studied. The study indicates that the effect of temperature on the transmittance of stearic acid in the liquid phase is not significant. However, it is highly dependent on temperature during the solidification process. Because of its low thermal conductivity and high transmittivity, it can be used as a transparent insulating material. (Author)
1999-12-01
Magnetoresistance of Two-Dimensional Tight-Binding Electrons in a Weak Magnetic Field
International Nuclear Information System (INIS)
We study the Anderson model on a two-dimensional square lattice with an applied weak magnetic field B which causes the hopping matrix elements to have Peierls phase factors. The recursion method is applied and B dependent conductivity ?(B) is calculated from the Kubo formula for different system sizes and degree of disorder W . For large W there is no systematic change of ?(B) with B, it shows a fluctuating behavior.
2008-08-25
Kinetics of achieving equilibrity at the sorption of radionuclides
International Nuclear Information System (INIS)
Radionuclide (R) sorption from a solution (vapor) by freshly formed crystals with production of substitution solid solutions under different types of self-disordering is studied. Changes of self-defectiveness and macrodefectiveness with time and effect of radiation defects in the presence of P macroquantities are taken into account. An analysis for monodispersed sorbents is performed. It is shown that the achievement of equilibrium within a reasonable time in impurity-solid phase system depends on defectiveness which ensures a required level of the coefficient of impurity diffusion in sorbent crystals.
Energy Technology Data Exchange (ETDEWEB)
This paper describes the implementations of a fuzzy logic based self-tuned controller to improve the stability of electric power systems. The stabilizing signal is computed using the standard fuzzy membership function depending on the speed/acceleration state of the generator in the phase plane. The performance of the proposed stabilizer is demonstrated by practical implementation using a digital signal processor mounted on a PC-AT. Results of the experimental tests on a physical model of a power system are presented.
1993-06-01
Kinetics of the stress induced phase transition in quartz by real-time neutron scattering
International Nuclear Information System (INIS)
Complete text of publication follows. The stability regime of the incommensurate phase of quartz is influenced by uniaxial stress. Hence, the phase transition can be induced under isothermal conditions by the application of external mechanical forces. Using real-time neutron scattering the time evolution of structural changes is investigated id detail during stress variations. The time dependent behaviour of the satellite reflection is compared with that one of the fundamental Bragg reflection which - via primary extinction - gives information about the perfection of the crystal. On increasing stress the perfection of the lattice is destroyed immediately while the modulated structure is built up with a delay of about 1 s. Decreasing the stress leads to a reverse behaviour. Moreover, there is evidence that under periodical load residual non-relaxed strain fields survive leading to a different temperature ...
1999-09-01
British Library Electronic Table of Contents (United Kingdom)
Abstract Purpose: To describe the pattern of expression of the cyclin-dependent kinase inhibitors (CDKIs) p16, p21 and p27, and the cell cycle in SRA 01/04 cells relative to contact inhibition. Methods: SRA 01/04 cells were grown to overconfluence under normal conditions. At various phases of the cell growth, cells were assayed by flow cytometry and Western blotting for the expression of CDKIs. Results: Expression of p16 was detected from early logarithmic growth to stationary phases, during which the number of cells in G0/G1 increased from 46 to 69%. Expression of p21 was detected only during the overgrowth phase, when 60% of the cells were in G0/G1. Expression of p27 was not observed in SRA 01/04 cells. Conclusions: p16 expression was likely mediated by G0/G1 arrest to induce contact inh...
2011-01-01
International Nuclear Information System (INIS)
The dependence of the photoluminescent properties of In_0_._4_8(Al_yGa_1_-_y)_0_._5_2P alloys (0#<=#y#<=#0.5) on growth temperature and substrate misorientation off GaAs(100) has been studied. Samples were grown using low-pressure metalorganic vapor phase epitaxy. By studying the dependence of ordering behavior in InGaP as a function of substrate misorientation and growth temperature simultaneously, a very large range in low-temperature photoluminescence emission energy---135 meV---has been obtained. The photoluminescence linewidth exhibits a strong, continuous dependence on the extent of atomic ordering (the emission energy) in the alloys. The results indicate that inhomogeneity in the microstructure of the material (i.e., between ''ordered'' domains and the ''disordered'' matrix) is the dominant photoluminescence broadening mechanism. This investigation has allowed a significant optimization of ...
Energy Technology Data Exchange (ETDEWEB)
A one-way coupling system between the plant simulator TRAC/BF1-ENTREE and the subchannel code with the improved cross flow model, NASCA, has been developed. Based on a scenario of turbine trip tests in the Peach Bottom Unit 2, the wide and rapid reactivity insertion transient induced by the system pressure rise was calculated. The pin power distribution in hot bundles was re-constructed considering heterogeneity of the fuel bundle. When the neighboring control blade is withdrawn, NASCA predicted that the steady-state bundle exit void distribution was nearly flat with regardless of the pin power distribution. However, void distributions in the middle and lower bundle regions became complicated depending on the pin power and the two-phase flow regime in each subchannel. The pin power distribution rapidly changed according to traveling of control blades. However, influence in the void distribution was delayed and damped due to the fuel heat ...
2002-11-01
International Nuclear Information System (INIS)
In order to practice design-by-analysis of thermohydraulics design of BWR fuel rod bundles, the subchannel analysis would play a major role. There, one of the immediate concerns is improvement in its predictive capability of boiling transition phenomena on the fuel rod surface. This capability strongly depends on the modeling of thermohydraulics phenomena of interests: 1) vapor-liquid redistribution by inter-subchannel exchanges due to the diversion cross flow, turbulent mixing and void drift, 2) liquid film behaviors, 3) transition of two-phase flow regimes, 4) droplet entrainment and deposition and 5) spacer-droplet interactions. These are considered to be five key factors in understanding the BT in BWR fuel rod bundles. This paper describes a progress and current status in the second year of the three year project on developing generalized boiling transition models with the above five key factors being focused on. A combined approach of ...
2004-10-04
Expression of Na(+)-H+ exchange and ATP-dependent proton extrusion in growing rat IMCD cells
Energy Technology Data Exchange (ETDEWEB)
As the last step of urinary acidification, the inner medullary collecting duct (IMCD) is thought to secrete protons into the tubular lumens by means of a H(+)-translocating adenosinetriphosphatase (H(+)-ATPase). However, recent studies have also shown the existence of Na(+)-H+ exchange activity in IMCD cells. Although the physiological function of the antiporter in IMCD cells is unknown, activation of Na(+)-H+ exchange in other cell-culture systems has been suggested to be closely associated with the process of cell growth. Thus presence of Na(+)-H+ exchange may relate to the growth phase of these cells. To examine intracellular pH (pHi) regulation in growing IMCD cells, we studied proton transport by Na(+)-dependent and Na(+)-independent mechanisms by microfluorimetry using the pHi-sensitive dye 2',7'-bis(carboxyethyl)-5,6-carboxyfluorescein acetoxymethyl ester (BCECF/AM). Actively growing cells, defined by (3H)thymidine ...
1990-03-01
Energy Technology Data Exchange (ETDEWEB)
Inverted annular flow can be visualized as a liquid jet-like core surrounded by a vapor annulus. While many analytical and experimental studies of heat transfer in this regime have been performed, there is very little understanding of the basic hydrodynamics of the post-CHF flow field. However, a recent experimental study was done that was able to successfully investigate the effects of various steady-state inlet flow parameters on the post-CHF hydrodynamics of the film boiling of a single phase liquid jet. This study was carried out by means of a visual photographic analysis of an idealized single phase core inverted annular flow initial geometry (single phase liquid jet core surrounded by a coaxial annulus of gas). In order to extend this study, a subsequent flow visualization of an idealized two-phase core inverted annular flow geometry (two-phase central jet core, surrounded by ...
1988-01-01
Fixation Techniques for Split Anterior Tibialis Transfer in Spastic Equinovarus Feet
Equinovarus of the foot is the most common lower extremity deformity following traumatic brain injury. We evaluated outcomes of the split anterior tibialis tendon transfer (SPLATT) for correction of equinovarus in 47 patients with hemiplegic traumatic brain injury and specifically studied differences in outcomes with two tendon fixation techniques. Seventeen patients constituting Group I underwent fixation with one technique and 30 constituting Group II had another technique. Patients in both groups had appropriate procedures based on dynamic electromyography and gait analyses. Both groups were demographically comparable. All 47 feet were corrected to plantigrade position. Thirty-six of 47 patients became brace-free at final followup. There was a notable decrease in the use of ambulatory aids and ambulatory status improved in both groups. There were three fixation-related complications in Group I and none in Group II. Surgical correction of the spastic equinovarus ...
2008-01-01
Bilateral femoral neck fractures following pelvic irradiation
International Nuclear Information System (INIS)
Over 300 cases of femoral neck fractures following radiotherapy for intrapelvic malignant tumor have been reported in various countries since Baensch reported this disease in 1927. In Japan, 40 cases or so have been reported, and cases of bilateral femoral neck fractures have not reached to ten cases. The authors experienced a case of 75 year-old female who received radiotherapy for cancer of the uterus, and suffered from right femoral neck fracture 3 months after and left femoral neck fracture one year and half after. As clinical symptoms, she had not previous history of trauma in bilateral femurs, but she complained of a pain in a hip joint and of gait disturbance. The pain in left femoral neck continued for about one month before fracture was recognized with roentgenogram. As histopathological findings, increase of fat marrow, decrease of bone trabeculae, and its marked degeneration were recognized. Proliferation of some blood vessels was found out, but ...
The effects of applied magnetic fields on the {alpha}/{gamma} phase boundary in the Fe-Si system
Energy Technology Data Exchange (ETDEWEB)
The CALPHAD (calculations of phase diagrams) method is used to examine the effects of applied magnetic fields on the {alpha}/{gamma} phase boundary in the Fe-Si system in the paramagnetic state. The reported susceptibility data for pure Fe is first re-evaluated. The contributions to the total Gibbs energy of the ferrite ({alpha}) and austenite ({gamma}) from the external fields are calculated based on the Curie-Weiss law and the re-evaluated susceptibility data. The Fe-Si phase diagram on the Fe-rich side as a function of applied field is calculated using the Thermo-Calc(TM) package. With increasing field strength, the {gamma} loop shrinks monotonically; that is, the {alpha}/{gamma}-Fe transition temperature increases while that for {gamma}/{delta}-Fe transition decreases, albeit more slowly. Finally, in conformance with the existing CALPHAD databank, Redlich-Kister polynomials are proposed to account for the compositional ...
2006-07-21
Energy Technology Data Exchange (ETDEWEB)
Cryogenic distillation is the main industrial method for separating hydrogen's isotopes, because it presents the advantage of high separating factors and also the possibility of processing great quantities of gases. In the case of multicomponent mixtures the determination of transport for molecular species between the two phases is very difficult owing to the particularities of physical characteristics of each component from the mixture. The transport of molecular species is also strongly influenced by the hydrodynamics of two phases, in strong connection with the dimension of the interface between the vapor and liquid phase. The characteristics of the interface depend on the type and geometry of the separation area: plates or package. The traditional methods of analysis for exchange processes use the concept 'theoretic plate', a physical entity for which the values of ...
1998-07-01
Elastic properties of potential superhard phases of RuO_2
International Nuclear Information System (INIS)
First-principles plane-wave pseudopotential and full-potential linearized-augmented plane-wave methods have been used to study the elastic and electronic properties of several potential superhard RuO_2 phases. The structures, relative stabilities, and the elastic constants and bulk moduli of these phases have been calculated within local-density approximation (LDA) and generalized gradient approximation (GGA). In RuO_2, the LDA and GGA approximations yield smaller and larger lattice constants, respectively, for the Pa3-bar-RuO_2 structure. The internal structural parameter for oxygen atoms in the Pa3-bar structure has a volume dependence that differs from the experimental result and therefore implies a significantly different compression mechanism. The calculated bulk moduli are very similar for the fluorite and Pa3-bar structures and therefore apparently independent of the internal structural parameter. The structure and ...
2000-04-15
PVT-apparatus for measurements on gas/oil solutions up to 2000 bar and 440 K
Energy Technology Data Exchange (ETDEWEB)
A high pressure piezometer is described with which pVT-measurements on solutions of gases in liquids like oils can be performed at pressures and temperatures up to 2000 bar and 440 K, respectively. The present investigations deal mainly with the system squalaneCO/sub 2/ at different mole fractions, but also with squalaneN/sub 2/. The high accuracy of the measurements reveals a pronounced structure of the pV-curves in dependence on temperature and mole fraction. At larger mole fractions is the unequivocal assignment of the phases ambiguous, and the representation of the experimental data in terms of an equation of state not possible for the whole pressure and temperature range. However, for solutions with lower mole fractions could be determined the saturation pressures and the isothermal compressibility in the unsaturated region. Furthermore, the molar excess volumes of the mixture have been calculated and the phase ...
1982-11-01
Modelling of two-phase natural circulation in a WWER-plant: PMK experimental results
International Nuclear Information System (INIS)
Experiments have been performed with the PMK integral-type facility, a model of WWER-440 type PWRs, to investigate two-phase natural circulation behaviour. The phenomena to be expected in this reactor type are different from those in PWRs with vertical steam generators mainly due to the loop seal in the hot leg and the horizontal layout of the steam generator heat transfer tubes. The experiments showed that the system is repressurized when the water level drops to the hot leg elevation due to the effect of the loop seal. Opening of the loop seal can be smooth, but may lead to oscillations depending on the power and the mass inventory. Natural circulation recovers after the hot leg loop seal is opened, but then decreases with further mass inventory decrease. (orig.).
Measuring perceptual centers using the phase correction response
British Library Electronic Table of Contents (United Kingdom)
The perceptual center (P-center) is fundamental to the timing of heterogeneous event sequences, including music and speech. Unfortunately, there is currently no comprehensive and reliable model of P-centers in acoustic events, so P-centers must instead be measured empirically. This study reviews existing measurement methods and evaluates two methods in detail?the rhythm adjustment method and a new method based on the phase correction response (PCR) in a synchronous tapping task. The two methods yielded consistent P-center estimates and showed no evidence of P-center context dependence. The PCR method appears promising because it is accurate and efficient and does not require explicit perceptual judgments. As a secondary result, the magnitude of the PCR is shown to vary systematically with ...
2011-01-01
British Library Electronic Table of Contents (United Kingdom)
PP2B is a Ca2+/calmodulin-dependent protein phosphatase that is ubiquitously expressed in mammals. Among other actions, it is an effector mechanism in NMDA-mediated glutamate neurotransmission as well as a regulator of GSK3? and MAPK signaling cascades. Because all of these mechanisms have demonstrable roles in the control of circadian rhythyms, we hypothesized that PP2B would be a key regulator of rhythm generation and entrainment, and that through inhibition of its phosphatase activity, the circadian system would be affected by immunosuppressant drug therapy. We report here that immunosuppressant drugs (cyclosporin A, FK506) (1) block the circadian responses to light that underlie photic entrainment; (2) produce circadian phase shifts with a characteristic nonphotic profile; and (3) disr...
2008-01-01
Extraction of rare earths by carbonic acids melts
Energy Technology Data Exchange (ETDEWEB)
Extraction of rare earths (La, Ce, Pr, Eu, Gd, Er, Yb) from nitrate solutions by melts of carboxylic acids of the C/sub 17/-C/sub 20/ fraction and stearic acid with paraffin, depending on the temperature (60-90 deg), phase contact time and their volume ratio (O:B from 1:5 up to 1:100), pH of the aqueous phase (2-6), rare earth concentration (10/sup -6/-10/sup -3/ m) is studied. It is shown that in the whole concentration range investigated rare earths are extracted quantitatively into the carboxylic acid melt of C/sub 17/-C/sub 20/ fraction at the equilibrium value of pH>=3.8, while into the melt of 0.1 M stearic acid in paraffin at pH>=4.5.
1980-10-01
Effect of globular structure op mechanical properties of VT3-1 alloy
International Nuclear Information System (INIS)
Effect of globular structure parameters - size of primary #alpha#-phase particles (bsub(I)), thickness and amount of plates of secondary #alpha#-phase (bsub(II), #gamma#sub(II#alpha# )) - on a complex of mechanical properties (#sigma#sub(#beta#), S, phi, asub(H), asub(T), Ksub(Q), #sigma#sub(-1), #sigma#_1_0_0"4"5"0, #sigma#sub(0.2/100)) of VT3-1 (#alpha#+#beta#)-titanium alloy is studied. The dependences obtained allow one to determine globular structure parameters, providing necessary mechanical properties. In combination with data on the effect of thermal treatment conditions on structure parameters, results obtained in the paper may be used for structure control to increase a level of required characteristics.
Computer simulation of the initial rafting process of a nickel-base single-crystal superalloy
Energy Technology Data Exchange (ETDEWEB)
Rafting of the {gamma}/{gamma}{prime} morphology of nickel-base superalloys is a well-known phenomenon during high-temperature deformation. The initial stages of this type of directional coarsening were modeled two-dimensionally by the method of finite elements (FEs) using an energy-perturbation approach. In addition to the elastic energy density, the effect of the local difference of the hydrostatic stresses in {gamma} and {gamma}{prime} in combination with the different lattice parameters of the two phases was considered in the calculations as a further driving force. From the results of modeling, the deformation-induced internal stresses and strains were determined and used to evaluate the direction-dependent lattice parameters and lattice misfits of the two phases. The results agree well with experimentally determined values.
2000-03-01
International Nuclear Information System (INIS)
Austenitic stainless steel AISI 304 has been nitrided by radio frequency (rf) plasma containing various nitrogen-hydrogen gas mixtures, in order to study the effect of hydrogen on structure and magnetic properties of the formed compound layer. The thermal temperature has been measured at the vicinity of the samples. The compound layer thus produced has been characterized using, X-ray diffractometer and vibration sample magnetometer. Providing the total pressure of nitrogen and hydrogen is held constant, the addition of hydrogen up to 50% gives new structural phases. The magnetization values of the plasma treated samples are strongly dependent on the percentage of H_2 in the gas phase. An excessive amount of hydrogen (#approx#75%) on the other hand, retards the nitriding process. The surface temperature of the sample and plasma condition is crucial factors for nitriding process.
2006-04-15
British Library Electronic Table of Contents (United Kingdom)
Irradiation of EP-823 (16Cr12MoWsiVNbB) ferritic-martensitic steel with 7-MeV Ni++ ions and with 30- and 70-keV He+ ions at a temperature of 500?C was followed by an increase in the microhardness, which was due to both radiation point defects and changes in the phase composition and the dislocation structure of the steel. It was found that the dependence of the largest relative increase in the microhardness on the concentration of radiation-induced point defects in the near-surface region of the steel under irradiation with different ions correlated with an analogous dependence of the surface segregation of silicon and chromium.
2011-01-01
Resistivity, Hall effect, and magnetic susceptibility of UPd_2Si_2
International Nuclear Information System (INIS)
The electrical resistivity, Hall effect, and magnetic susceptibility of single-crystal UPd_2Si_2 have been studied between 4.2 and 300 K. A large anisotropy was observed in both the magnetic and transport properties. There is a quadratic temperature dependence of the resistivity for a range of temperatures between 4.2 and 80 K. At higher temperatures, the resistivity indicates a Kondo-type behavior. The behavior of these quantities is accounted for by the magnetic phase transitions at 108 and 136 K reported from neutron-scattering studies. At high temperatures, the magnetic susceptibility of UPd_2Si_2 is Curie-Wiess-like along the c axis. The temperature dependence of the Hall coefficient above 108 K is accounted for by a theoretical model invoking skew scattering of conduction electrons by localized magnetic moments.
Resistivity, Hall effect, and magnetic susceptibility of UPd[sub 2]Si[sub 2
Energy Technology Data Exchange (ETDEWEB)
The electrical resistivity, Hall effect, and magnetic susceptibility of single-crystal UPd[sub 2]Si[sub 2] have been studied between 4.2 and 300 K. A large anisotropy was observed in both the magnetic and transport properties. There is a quadratic temperature dependence of the resistivity for a range of temperatures between 4.2 and 80 K. At higher temperatures, the resistivity indicates a Kondo-type behavior. The behavior of these quantities is accounted for by the magnetic phase transitions at 108 and 136 K reported from neutron-scattering studies. At high temperatures, the magnetic susceptibility of UPd[sub 2]Si[sub 2] is Curie-Wiess-like along the [ital c] axis. The temperature dependence of the Hall coefficient above 108 K is accounted for by a theoretical model invoking skew scattering of conduction electrons by localized magnetic moments.
1993-12-15
Pressure-dependent photoluminescence study of ZnO nanowires
Energy Technology Data Exchange (ETDEWEB)
The pressure dependence of the photoluminescence (PL) transition associated with the fundamental band gap of ZnO nanowires has been studied at pressures up to 15 GPa. ZnO nanowires are found to have a higher structural phase transition pressure around 12 GPa as compared to 9.0 GPa for bulk ZnO. The pressure-induced energy shift of the near band-edge luminescence emission yields a linear pressure coefficient of 29.6 meV/GPa with a small sublinear term of -0.43 meV/GPa{sup 2}. An effective hydrostatic deformation potential -3.97 eV for the direct band gap of the ZnO nanowires is derived from the result.
2004-09-13
Energy Technology Data Exchange (ETDEWEB)
The magnetic susceptibility and electrical resistivity in cerium and neodymium titanate bronzes in Ln/sub 2/3+x/TiO/sub 3+y/ of the perovskite structure were investigated in the temperature range 77-450/sup 0/K. The deviation of the 1/x = f(T) dependence from the Curie-Weiss law, found for a majority of the compositions, was interpreted from the crystal-field effect based on the state of the Ce/sup 3 +/ and Nd/sup 3 +/ cations. For a number of the phases, a transition from metallic conductivity at high temperatures to semiconducting conductivity was detected at temperatures below 200-250/sup 0/K, which agrees well with the conclusion about the temperature dependence of x, related to the subsystem of Ti/sup 3 +/ cations.
1987-01-01
A fundamental Doppler-like but asymmetric wave effect that shifts received signals in frequency in proportion to their respective source distances, was recently described as means for a whole new generation of communication technology using angle and distance, potentially replacing TDM, FDM or CDMA, for multiplexing. It is equivalent to wave packet compression by scaling of time at the receiver, converting path-dependent phase into distance-dependent shifts, and can multiply the capacity of physical channels. The effect was hitherto unsuspected in physics, appears to be responsible for both the cosmological acceleration and the Pioneer 10/11 anomaly, and is exhibited in audio data. This paper discusses how it may be exploited for instant, passive ranging of signal sources, for verification, rescue and navigation; incoherent aperture synthesis for smaller, yet more accurate radars; universal immunity to jamming or ...
2008-01-01
Small angle neutron scattering (SANS) on the unilamellar vesicle populations (diameter 500 and 1000 angstrom) was used to characterize lipid vesicles from dimyristoylphosphatidylcholine (DMPC) at three phases (gel, ripple, and liquid). Parameters of vesicle populations and internal structure of the DMPC bilayer were characterized on the basis of the Separated Form Factor (SFF) model. Parameters of the internal bilayer structure (thickness of the membrane and the hydrophobic core, hydration, and surface area of lipid molecule) were determined on the basis of the Hydrophobic-Hydrophilic (HH) approximation of neutron scattering length density across the bilayer r(x) and of the Step Function (SF) approximation of r(x). It was demonstrated in frame of HH approximation that DMPC membrane thickness in liquid phase (T=30 degrees) depends on the membrane curvature. The dependence of the DMPC membrane thickness ...
2005-01-01
The influence of amino acids on the biomineralization of hydroxyapatite in gelatin.
The effects of pH on the calcium phosphate phase, of Tris and of amino acids, such as aspartic acid, glutamic acid, and serine on hydroxyapatite formation and morphology, were studied in double diffusion experiments. In this system, hydroxyapatite was only formed when the pH was around 7.4 or higher for the duration of the reaction. A decrease in pH resulted in the transformation of hydroxyapatite to octacalcium phosphate. Amino acids and Tris or the buffering capacity of Tris have an effect on the morphology of the synthetic hydroxyapatite. The presence of the additive results in spheres consisting of needles, blades or plates depending on the reaction system. PMID:12175941
2002-08-30
Structural Phase Transition in AuZn Alloys
Energy Technology Data Exchange (ETDEWEB)
AuxZn1-x alloys undergo a shape memory martensitic transformation whose temperature and nature (continuous or discontinuous) is strongly composition dependent. Neutron diffraction experiments were performed on single crystals of x=50 and 52 to explore the structural changes occurring at the transition temperature. A transverse modulation with wavevector q0=(1/3,1/3,0) develops below the transition temperature, with no observable change in lattice parameter. However, the Bragg peak width shows a broadening suggesting an unresolved rhombohedral distortion similar to what has been observed in NiTi-Fe alloys.
2009-05-03
Striped instability of a holographic Fermi-like liquid
We consider a holographic description of a system of strongly-coupled fermions in 2+1 dimensions based on a D7-brane probe in the background of D3-branes. The black hole embedding represents a Fermi-like liquid. We study the excitations of the Fermi liquid system. Above a critical density which depends on the temperature, the system becomes unstable towards an inhomogeneous modulated phase which is similar to a charge density and spin wave state. The essence of this instability can be effectively described by a Maxwell-axion theory with a background electric field. We also consider the fate of zero sound at non-zero temperature.
2011-01-01
Solution of vector Stefan problems with cross-diffusion
A general model for the dissolution of particles in multi-component alloys is proposed and analyzed. The model is based on diffusion equations with cross-terms for the several species, combined with a Stefan condition as the equation of motion of the interface between the particle and diffusive phase. Several numerical schemes for the solution of the Stefan problem are proposed and compared. It turns out that diagonalization is useful for numerical purposes. However, for the case of position-dependent diffusion coefficients one has to use a different scheme. Here, we analyze stability and workload of several time integration methods.
2005-04-01
Energy Technology Data Exchange (ETDEWEB)
We investigate the formation of nanostructures in 2D strained alloys on face centered cubic (111) surfaces by means of equilibrium Monte Carlo simulations. In the framework of an off-lattice model, we consider one monolayer of two bulk-immiscible adsorbates A and B with negative and positive misfit relative to the substrate, respectively. Simulations show that the adsorbates partly self-organize into island or stripe-like patterns. We show how these structures depend on the relative misfits, interaction, and concentration of components. The morphology is quite different for phase separation and intermixing regimes.
2008-07-02
Signal simulator for the calibration of eddy current probes
Energy Technology Data Exchange (ETDEWEB)
This paper describes a signal simulator which is designed to calibrate eddy current probes. By using simultaneously an excitation coil and an electrically conducting plane, the simulator can emulate signals which correspond to spot welds with different flaws. The presence of a conducting plane allows a wide variation of the amplitude and phase of the excitation coil voltage during the calibration of a probe. A mathematical model for the simulator is derived and used to study the variation of the impedance change upon the parameters of the probe. Numerical computation shows that the impedance change depends in an important way on the frequency of the excitation coil current.
1994-01-01
Preparation of NiZn-ferrite nanofibers by electrospinning for DNA separation
Energy Technology Data Exchange (ETDEWEB)
We present the synthesis, magnetic and UV spectrometry of NiZn-ferrite nanofiber. The single phase of spinel ferrite was obtained at 600 {sup o}C. The NiZn-ferrite fibers fabricated by an electrospinning process were formed as a polygonal grain growth with firing temperature in fiber matrix. It appeared that the saturation magnetization (M{sub S}) of NiZn-ferrite nanofiber was dependent on Ni/Zn molar ratio which is similar to that of the inverse spinel ferrites. The NiZn-ferrite fibers showed good DNA adsorption efficiency that can be modified and utilized for DNA separation with magnetic nanofiber as a novel material in clinical applications.
2009-05-15
Plasma nitriding of low alloy steels at floating and cathodic potentials
International Nuclear Information System (INIS)
The low alloy steels were nitrided in the plasma atmosphere generated by using hollow cathode discharge. For comparison, specimens of 40 Cr steel were in two different potential states. One kind is isolated from cathode and anode between them the discharge was created. The other kind is placed on the plate which is connected to the cathode. The nitriding was carried out at different temperatures. The surface morphology, phase of compound layers and microhardness profiles were analyzed. The optical microscopy observation and X-ray diffraction showed that the compound layers were formed in all experiments. The results of the nitriding treatment are weakly dependent on the potentials applied on the specimens.
2008-08-15
Optimal oscillation-center transformations
Energy Technology Data Exchange (ETDEWEB)
A variational principle is proposed for defining that canonical transformation, continuously connected with the identity transformation, which minimizes the residual, coordinate-dependent part of the new Hamiltonian. The principle is based on minimization of the mean-square generalized force. The transformation reduces to the action-angle transformation in that part of the phase space of an integrable system where the orbit topology is that of the unperturbed system, or on primary KAM surfaces. General arguments in favor of this definition are given, based on Galilean invariance, decay of the Fourier spectrum, and its ability to include external fields or inhomogeneous systems. The optimal oscillation-center transformation for the physical pendulum, or particle in a sinusoidal potential, is constructed.
1984-08-01
On the mechanism of the nonmonotonic relaxation processes in the metallic melts
International Nuclear Information System (INIS)
The numerical analysis of the experimental data on viscosity change by time in the period after fast heating and crystal-liquid phase transition for the copper nonequilibrium melts and the Fe_7_0Cr_1_0P_1_3C_7 glass-forming melt near their melting temperatures is accomplished through the method of correlation functions and the Rytov-Dimentberg criterion. The observed dependences have nonmonotonic oscillating character but they do not relate to auto-oscillations. The proposed theoretical model of the properties oscillations origination by relaxation in the nonequilibrium liquids explains them as manifestation of noise-induced transitions in the metastable area near the critical temperatures (melting, structural transitions)
2000-01-01
Lithium-lead/water reaction experiments and analysis
Energy Technology Data Exchange (ETDEWEB)
An experiment has been performed to investigate the chemical reaction between the liquid phases of the eutectic lithium-lead (Li/sub 17/Pb/sub 83/) and water. The reactants and products were constrained within a closed reaction vessel, allowing the extent of reaction to be determined from the partial pressure of the hydrogen reaction product. The data from the tests showed that the extent of reaction did not depend upon the water temperature. The data also indicated that the extent of reaction passed through a maximum as the initial liquid metal temperature was varied from 350 to 500 C, and a model was developed to explain this behavior. 11 refs., 3 figs.
1988-01-01
EXAFS Study of Semimetal-Semiconductor Transition of Bismuth Clusters
International Nuclear Information System (INIS)
Extended X-ray absorption fine structure (EXAFS) measurements of bismuth clusters in the temperature range of 23 -300 K have been performed using synchrotron radiation in order to investigate the size dependent phase transition. The inter-atomic distances around 3.0 A and 3.6 A are attributed to the nearest neighbors within the layer and between layers, respectively. EXAFS functions were analysed by the curve fitting method within a symmetric distribution approximation. The nearest neighbor distance of the 0.5 nm thick films is shorter than that of the 300 nm thick films at all the temperatures, which is related to the reduction of the inter-layer correlation.
2007-02-02
British Library Electronic Table of Contents (United Kingdom)
The computational analysis of the model system consisting of the processes of CO2 assimilation and photorespiration shows the appearance of sustained oscillations in the system which might reflect their presence in photosynthesizing cells. Concentrations of CO2 and O2 oscillate in opposite phases causing Rubisco switching continuously between the carboxylase (CO2 assimilation) and the oxygenase (photorespiration) reactions. The results of modeling are consistent with carbon isotopic and other observed data. They show that the oscillation period varies from about 1 s to 3 s depending on the values of parameters taken. Too high concentrations of O2 suppress the oscillations.
2011-01-01
Rare-earth doped (#alpha#'/#beta#')-sialon ceramics
International Nuclear Information System (INIS)
The objectives of this research were to investigate the possibility of controlling the #alpha#'/#beta#' phase ratio and morphology in Sialon ceramics. These objectives have been sought by the control of the starting composition, and by post sintering heat treatment. The main emphasis has been on the production of a series of #alpha#' and (#alpha#'+#beta#') Sialon ceramics with a minimum amount of the glass phase by the pressureless sintering technique and using ytterbium (Yb) as an #alpha#' stabilising element. The Yb additions were made via the oxide or the alumino- silicate presynthesised glass; the latter was found to improve the density. The XRD analysis of the as sintered materials revealed #alpha#' to be the dominant phase with minor contributions from #beta#' sialon and/ or 12H A1N polytype. Additions of SiO_2 or #beta#-Si_3N_4 were made to various materials to assess potential mechanisms for obtaining control over ...
Stress-induced amorphization at moving crack tips in NiTi.
Energy Technology Data Exchange (ETDEWEB)
In situ fracture studies on thin-film NiTi intermetallic compounds have been carried out in the high-voltage electron microscope at Argonne National Laboratory. Local stress-induced amorphization of regions directly in front of moving crack tips has been observed under tensile loading conditions. The stress-induced amorphization at crack tips exhibits a temperature dependence similar to that of ion-induced amorphization of NiTi. The upper limiting temperature for stress-induced amorphization is the same as that for ion-induced amorphization of crystalline NiTi and for amorphous phase formation during ion-beam mixing of Ni and Ti multilayer specimens. This upper limiting temperature of 600K is also the lowest temperature at which stress-induced amorphous phase crystallizes during isothermal annealing. This isothermal crystallization temperature is nearly 200K less than the kinetic crystallization temperature during heating ...
1998-01-29
Properties and challenges of nanolayer coatings
Energy Technology Data Exchange (ETDEWEB)
A systematic study was made on MoSi{sub 2}-based nanolayer coatings. Alternating layers with thickness 1-20 nm were prepared by sputtering. Nitrided MoSi{sub 2} has a very high crystallization temperature, >1000 C, and MoSi{sub 2}Nx (x=3-4) can be used as a stable second phase reinforcement or diffusion barrier coatings. Mechanical properties depend strongly on phase and morphology of the layers: hardness and modulus is significantly increased in the crystallization. The nanolayers have much higher hardness but lower modulus (which project higher toughness in the nanolayers). Wear resistance is improved with decreasing layer thickness. Single phase MoSi{sub 2}Nx (x=0-4.2) has a wide range of hardness and modulus with varying N content and annealing, suggesting the possibility of engineering MoSi{sub 2}Nx to produce different material properties for different mechanical applications. Most of this ...
1995-12-01
Dielectric properties of fluxed barium titanate ceramics with zirconia additions
Energy Technology Data Exchange (ETDEWEB)
BaTiO{sub 3} compacts, when fluxed with {lt} 2 vol% of a complex borate glass phase, were sintered to near theoretical density at temperatures {lt} 1175{degrees}C in 2 h. Microstructural analysis showed a uniform grain size {lt} 1.0 {mu}m with 0.75 wt% ZrO{sub 2} added to the flux phase as a grain growth inhibitor. TEM analysis revealed a microcrystalline grain-boundary phase with the ZrO{sub 2} resident along the grain boundaries. These samples displayed an essentially flat dielectric profile, low dissipation factors ({lt} 2%) over the range 25{degrees} to 125{degrees}C, a near linear dependence ({approx} {+-} 15%) between 25{degrees} and {minus} 55{degrees}C, and significantly increased voltage stability. X-ray diffraction analysis of these small-grained materials indicates a suppression of the tetragonal structure toward a more cubic modification.
1990-03-01
Dielectric properties of fluxed barium titanate ceramics with zirconia additions
International Nuclear Information System (INIS)
BaTiO_3 compacts, when fluxed with < 2 vol% of a complex borate glass phase, were sintered to near theoretical density at temperatures < 1175 degrees C in 2 h. Microstructural analysis showed a uniform grain size < 1.0 #mu#m with 0.75 wt% ZrO_2 added to the flux phase as a grain growth inhibitor. TEM analysis revealed a microcrystalline grain-boundary phase with the ZrO_2 resident along the grain boundaries. These samples displayed an essentially flat dielectric profile, low dissipation factors (< 2%) over the range 25 degrees to 125 degrees C, a near linear dependence (#approx# #+-# 15%) between 25 degrees and - 55 degrees C, and significantly increased voltage stability. X-ray diffraction analysis of these small-grained materials indicates a suppression of the tetragonal structure toward a more cubic modification.
Effects of interstitial clustering on transient enhanced diffusion of boron in silicon
Energy Technology Data Exchange (ETDEWEB)
A simulation model for boron diffusion which takes into account the aggregation of the excess interstitials in clusters, and subsequently, the dissolution of these defects, is proposed. The interstitial supersaturation and generation rate are determined according to the classical theory of nucleation and growth of particles, in analogy with the precipitation of a new phase in heavily doped silicon. The clusters are considered as precipitates formed by interstitial Si atoms. The B diffusion is modelled on the basis of the dopant-interstitial pair diffusion mechanism. The clusters dissolution during annealing maintains nearly constant, for a long period, the interstitial supersaturation and the related enhancement of the boron diffusion. This gives a good account of the diffusion results over a large range of experimental conditions. Furthermore, this approach describes most of the behavior of the transient enhanced diffusion (TED), like the temperature ...
1997-11-01
STOMP, Subsurface Transport Over Multiple Phases, theory guide
Energy Technology Data Exchange (ETDEWEB)
This guide describes the simulator`s governing equations, constitutive functions and numerical solution algorithms of the STOMP (Subsurface Transport Over Multiple Phases) simulator, a scientific tool for analyzing multiple phase subsurface flow and transport. The STOMP simulator`s fundamental purpose is to produce numerical predictions of thermal and hydrologic flow and transport phenomena in variably saturated subsurface environments, which are contaminated with volatile or nonvolatile organic compounds. Auxiliary applications include numerical predictions of solute transport processes including radioactive chain decay processes. In writing these guides for the STOMP simulator, the authors have assumed that the reader comprehends concepts and theories associated with multiple-phase hydrology, heat transfer, thermodynamics, radioactive chain decay, and nonhysteretic relative permeability, saturation-capillary pressure ...
1996-10-01
Multiphase treatment of ODTX in HMX spheres
Energy Technology Data Exchange (ETDEWEB)
What will be discussed in this report represents a framework upon which multiphase and other real physical effects can be built. Chemical models of increasing complexity are envisioned and this methodology can provide a tool for evaluating new ideas against known experimental data. The recent work to be reported here addresses the multiphase issue of temperature deviation between phases undergoing chemical and heat transport processes. Modeling of the LLNL ODTX experiment will be performed with FLUENT, a commercially available computational fluid dynamics (CFD) code. FLUENT solves flows in 2D or 3D in Cartesian, cylindrical, or general curvilinear coordinates, with steady-state of fully time-dependent analysis. Multiphase flows in which two or more continuous phases are present can be solved with arbitrary volumetric sources of heat, mass, momentum, and chemical species applied through user-defined FORTRAN subroutines. ...
1997-12-22
Energy Technology Data Exchange (ETDEWEB)
In order to practice a design-by-analysis of thermohydraulics design of BWR fuel rod bundles, the subchannel analysis would play a major role. There, the immediate concern is improvement in its predictive capability of CHF due in particular to the film dryout (boiling transition phenomena: BT) on the fuel rod surface. Constitutive equations in the subchannel analysis formulation are responsible for the quality of calculated results. The constitutive equations are a result of integration of the local and instantaneous description of two-phase flows over the subchannel control volume. In general, they are expressed in terms of subchannel-control-volume- as well as area-averaged two-phase flow state variables. In principle the information on local and instantaneous physical phenomena taking place inside subchannels must be counted for in the algebraic form of the equations on the basis of a more mechanistic modeling approach. They should include ...
2006-07-01
Two-phase flow modeling in the rod bundle subchannel analysis
Energy Technology Data Exchange (ETDEWEB)
Full text of publication follows:In order to practice a design-by-analysis of thermohydraulics design of BWR fuel rod bundles, the subchannel analysis would play a major role. There, the immediate concern is improvement in its predictive capability of CHF due in particular to the film dryout (boiling transition phenomena: BT) on the fuel rod surface. Constitutive equations in the subchannel analysis formulation are responsible for the quality of calculated results. The constitutive equations are a result of integration of the local and instantaneous description of two-phase flows over the subchannel control volume. In general, they are expressed in terms of subchannel-control-volume- as well as area-averaged two-phase flow state variables. In principle the information on local and instantaneous physical phenomena taking place inside subchannels must be counted for in the algebraic form of the equations on the basis of a more mechanistic ...
2004-07-01
Two-phase flow modeling in the rod bundle subchannel analysis
International Nuclear Information System (INIS)
In order to practice a design-by-analysis of thermohydraulics design of BWR fuel rod bundles, the subchannel analysis would play a major role. There, the immediate concern is improvement in its predictive capability of CHF due in particular to the film dryout (boiling transition phenomena: BT) on the fuel rod surface. Constitutive equations in the subchannel analysis formulation are responsible for the quality of calculated results. The constitutive equations are a result of integration of the local and instantaneous description of two-phase flows over the subchannel control volume. In general, they are expressed in terms of subchannel-control-volume- as well as area-averaged two-phase flow state variables. In principle the information on local and instantaneous physical phenomena taking place inside subchannels must be counted for in the algebraic form of the equations on the basis of a more mechanistic modeling approach. They should include ...
2006-01-01
Metastability and dynamics of the shock-induced phase transition in iron
Energy Technology Data Exchange (ETDEWEB)
The shock-induced {alpha}(bcc){r_arrow}{var_epsilon}(hcp) transition in iron begins at 13 GPa on the Hugoniot. In the two-phase region above 13 GPa, the Hugoniot lies well above the equilibrium surface defined by G{sub {alpha}}=G{sub {var_epsilon}}, with G the Gibbs free energy. Also, the phase transition relaxation time {tau} is uncertain, with estimates ranging from {lt}50 ns to {approx}180 ns. Here we present an extensive study of these important aspects, metastability and dynamics, of the {alpha}-{var_epsilon} transition in iron. Our primary theoretical tools are (a) accurate theoretically based free energies for {alpha} and {var_epsilon} phases of iron and (b) accurate calculations of the wave evolution following planar impacts. We define metastable surfaces for forward and reverse transitions by the condition that the thermodynamic driving force G{sub {alpha}}{minus}G{sub {var_epsilon}} is just balanced by an opposing ...
1997-02-01
The accurate magnetic structure of CeAl{sub 2} at various temperatures in the ordered state
Energy Technology Data Exchange (ETDEWEB)
The magnetic structure of the cubic compound CeAl{sub 2} is incommensurate and double-k. The moments on the two Ce sites describe two elliptical helices of opposed chiralities and lie in the (11-bar0) plane, with their Fourier components m{sup k} close to the [111] direction. Recent symmetry considerations, including for the first time the inversion center of the crystal, have reduced the number of parameters of this structure and have underlined the existence of a phase difference between the projections m{sub x}{sup k}, m{sub y}{sup k} and m{sub z}{sup k} of m{sup k}. Up to now, although many neutron investigations have been carried out on CeAl{sub 2} single crystals, no set of magnetic intensities was available which was large and good enough to check whether this phase difference exists or not. We have measured such a set of data, taking great care of the instrumental resolution in order to avoid unwanted contributions to the intensities ...
2008-04-02
The accurate magnetic structure of CeAl_2 at various temperatures in the ordered state
International Nuclear Information System (INIS)
The magnetic structure of the cubic compound CeAl_2 is incommensurate and double-k. The moments on the two Ce sites describe two elliptical helices of opposed chiralities and lie in the (11-bar0) plane, with their Fourier components m"k close to the [111] direction. Recent symmetry considerations, including for the first time the inversion center of the crystal, have reduced the number of parameters of this structure and have underlined the existence of a phase difference between the projections m_x"k, m_y"k and m_z"k of m"k. Up to now, although many neutron investigations have been carried out on CeAl_2 single crystals, no set of magnetic intensities was available which was large and good enough to check whether this phase difference exists or not. We have measured such a set of data, taking great care of the instrumental resolution in order to avoid unwanted contributions to the intensities from other domains. As the magnetic form factor of ...
2008-04-02
Studies of weak hcp "3He-"4He solution decomposition and magnetic properties of decomposed samples
International Nuclear Information System (INIS)
The information is reported on the kinetics of decomposition of weak hcp "3He-"4He solutions with the starting "3He concentration 0.5#+-#0.1% and 1.20#+-#0.2% under the sample pressure 3.5 to 3.8 MPa before the decomposition. The NMR technique of the prompt control of the phase separation process is developed. To accelerate the metastable phase decomposition, the samples were thermally cycled at temperatures below 100 mK. Using the pulse NMR method, the magnetic susceptibility of "3He nuclei and the spin-lattice T_1 and spin-spin T_2 relaxation times were measured on three samples of the decomposed solid solutions with the starting "3He concentration 0.5% at the pressures 3.53, 3.71 and 3.78 MPa. Above 10 mK the Curie-Weiss constant was two to three times higher than the values typical of bulk bcc "3He of the corresponding density. Below 10 mK the magnetic susceptibility was observed to deviate from the Curie-Weiss law. One of the samples ...
The dependence of the photoluminescent properties of In{sub 0.48}(Al{sub {ital y}}Ga{sub 1{minus}{ital y}}){sub 0.52}P alloys (0{le}{ital y}{le}0.5) on growth temperature and substrate misorientation off GaAs(100) has been studied. Samples were grown using low-pressure metalorganic vapor phase epitaxy. By studying the dependence of ordering behavior in InGaP as a function of substrate misorientation and growth temperature simultaneously, a very large range in low-temperature photoluminescence emission energy---135 meV---has been obtained. The photoluminescence linewidth exhibits a strong, continuous dependence on the extent of atomic ordering (the emission energy) in the alloys. The results indicate that inhomogeneity in the microstructure of the material (i.e., between ordered'' domains and the disordered'' matrix) is the dominant photoluminescence broadening ...
1992-12-01
Energy Technology Data Exchange (ETDEWEB)
The dependence of the photoluminescent properties of In{sub 0.48}(Al{sub {ital y}}Ga{sub 1{minus}{ital y}}){sub 0.52}P alloys (0{le}{ital y}{le}0.5) on growth temperature and substrate misorientation off GaAs(100) has been studied. Samples were grown using low-pressure metalorganic vapor phase epitaxy. By studying the dependence of ordering behavior in InGaP as a function of substrate misorientation and growth temperature simultaneously, a very large range in low-temperature photoluminescence emission energy---135 meV---has been obtained. The photoluminescence linewidth exhibits a strong, continuous dependence on the extent of atomic ordering (the emission energy) in the alloys. The results indicate that inhomogeneity in the microstructure of the material (i.e., between ordered'' domains and the disordered'' matrix) is the dominant photoluminescence broadening ...
1992-12-01
Combined chemotherapy and radiotherapy: from biology to bed-side
International Nuclear Information System (INIS)
Combination of radiotherapy and chemotherapy (CRC) is actually one important way of research in oncology. Theoretical advantages are: (1) Spatial cooperation; (2) Additivity, which is only obtained if the toxicity of each modality are different; (3) Supra-additivity, which needs a rigorous in vitro definition; the only way to prove it is to make an isobologram analysis. This model has however, some limitations: qualitative variable could not be used, results could be different, depending on the cell line and isoeffect chosen...In fact, a supra-additivity was only demonstrated for cis platinum and etoposide. Interactions mechanisms were: (1) at the molecular level, creation of new lesions or inhibition of radiation lesions repair; (2) At the cellular level, either cytokinetic cooperation with S-phase dependent drugs, or synchronization for the drugs which blocked the cells in M-phase; (3) At the tissular ...
AlGaInP double heterostructure laser diodes with a GaInP active layer constitute a basic laser structure for visible-light lasers using an AlGaInP alloy system. This paper gives a detailed description of (Al/sub x/Ga/sub 1 - x/)/sub 0.5/In/sub 0.5/P metalorganic vapor phase epitaxial growth, laser-fabrication processes, and basic device-characteristics for these lasers. The obtained pulsed-threshold-current was about 3.8 kA/cm/sup 2/(3.2 kA/cm/sup 2/ minimum) for laser diodes with an 8-10 /n//m wide and 150-300 ..mu..m long injection stripe. High characteristic-temperature T/sub o/ for the temperature dependence of pulsed threshold current was obtained and was found to be dependent on band-gap-energy differences between active layers and cladding layers. The maximum value for T/sub o/ was 222 K. The lasing wavelength of an AlGaInP double heterostructure laser diode with a GaInP active layer was found to ...
1987-06-01
Energy Technology Data Exchange (ETDEWEB)
Jittery (ji) is a recessive mouse mutation on Chromosome 10 characterized by progressive ataxic gait, dystonic movements, spontaneus seizures, and death by dehydration/starvation before fertility. Recently, a viable neurological recessive mutation, hesitant, was discovered. It is characterized by hesitant, uncoordinated movements, exaggerated stepping of the hind limbs, and reduced fertility in males. In a complementation test and by genetic mapping we have shown here that hesitant and jittery are allelic. Using several large intersubspecific backcrosses and intercrosses we have genetically mapped ji near the marker Amh and microsatellite markers D10Mit7, D10Mit21, and D10Mit23. The linked region of mouse Chromosome 10 is homologous to human 19p13.3, to which several human ataxia loci have recently been mapped. By excluding genes that map to human 21q22.3 (Pfkl) and 12q23 (Nfyb), we conclude that jittery is not likely to be a genetic mouse model for human ...
1996-08-01
The phase shifts leading to the broadening and shift of spectral lines
International Nuclear Information System (INIS)
The classical theory of collisional broadening and shift parameters (?, ?) of an isolated spectral line was used to obtain simple analytical formulas for calculating both ? and ?. These formulas were obtained on the assumption that the short range interaction is effective only in the broadening while the long range is effective in the shift of the spectral line. These parameters ? and ? depend on the limiting phase shifts responsible for broadening ?b and shift ??. It was found that the values of ?b and ?? are not equal to each other as was proposed by Weisskopf ?b=??=1. The maximum and average values of ?b (?bmax, ?bav) and ?? (??max, ??av) were obtained by numerical evaluation, using different inverse power potentials. By introducing these parameters into the approximated formulas for ? and ? using Van der Waals and Lennard-Jones potential, it was found that the results of calculations for (? and ?) with different atomic transitions perturbed ...
2009-02-01
Synthesis and characterization of #beta#-SiAlON with a rare earth concentrate as sintering aid
International Nuclear Information System (INIS)
Silicon nitride-based ceramics behavior is strongly influenced by microstructural parameters, which, in turn are determined by chosen densification method. Highly covalent Si-N bond hind are the silicon nitride densification. Therefore, metal oxides are used in order to get high density. However, such oxides must be carefully selected, because they affect the general macroscopic properties of sintered bodies. In the present work, the viability of rare earth concentrate use to produce #beta#--Si_6_-_xAl_xO_xN_8_-_x and its effect on mechanical properties of the sintering ceramics are studied. Additive composition, heating rate, soaking time and sintering temperature were took as variables. Hardness, fracture toughness, Young's modulus and flexural strength were investigated. Lattice parameter compositional dependence and secondary phases crystallized after past-sintering heat treatment were also determined. The results show that rare earth ...
Subwavelength atom localization via amplitude and phase control of the absorption spectrum. II
International Nuclear Information System (INIS)
Interaction of the internal states of an atom with spatially dependent standing-wave cavity field can impart position information of the atom passing through it leading to subwavelength atom localization. We recently demonstrated a different regime of atom localization [Phys. Rev. A 72, 013820 (2005)], namely sub-half-wavelength localization through phase control of electromagnetically induced transparency. This regime corresponds to extreme localization of atoms within a chosen half-wavelength region of the standing-wave cavity field. Here we present further investigation of the simplified model considered earlier and show interesting features of the proposal. We show how the model can be used to simulate a variety of energy-level schemes. Furthermore, the dressed-state analysis is employed to explain the emergence and suppression of the localization peaks, and the peak positions and widths. The range of parameters for obtaining clean ...
2006-02-01
International Nuclear Information System (INIS)
When liquids are confined in nano-scopic dimensions, their properties differ from the corresponding bulk liquid, due to their reduced dimensionality and surface effects. Phase transition temperatures and pressures are often shifted from the bulk values and new phases can appear due to the strong interactions of the molecules with the confining walls. We have studied the structural and dynamical properties of aromatic liquids such as benzene, toluene, and ortho-terphenyl confined in nano-porous materials, MCM-41 and SBA-15, synthesized and characterized in our laboratory. A non-trivial dependence of the glass transition temperature, Tg, on the pore size and surface treatment of nano-porous materials is confirmed and interpreted as resulting from a competition between the fluid-wall and fluid-fluid intermolecular interactions. An increase of Tg is observed for small pore sizes and attractive surface while Tg decreases for non ...
2006-01-01
Some numerical problems in atomic physics
International Nuclear Information System (INIS)
The numerical calculation of oscillatory wavefunctions occurring in the theory of electron scattering from positive ions is considered, the aim being to develop methods for evaluating the oscillatory solutions using a logarithmic grid. Thus, the permitted step-size for the solution depends only upon the potential, enabling calculations at different energies to be performed using the same discretisation. Two similar generalisations of the W.K.B. transformation for second order ordinary differential equations are made and applied to the radial Dirac equations. Iterative schemes for the solution of the resulting non-linear amplitude equations are discussed, one for use in the asymptotic region and the other a Newton scheme for continuing the solution closer to the origin. Using these techniques a reliable and efficient program for calculating relativistic scattering phase shifts from ionic potentials has been written. Relativistic Optical Model ...
1981-01-01
Piezoelectric Properties of (1-x)(Na0.5K0.5)NbO3-xAgSbO3 Lead-Free Ceramics
British Library Electronic Table of Contents (United Kingdom)
(1-x)(Na0.5K0.5)NbO3-xAgSbO3 lead-free piezoelectric ceramics were prepared by normal sintering. The effects of the AgSbO3 on the phase structure and piezoelectric properties of the ceramics were systematically studied. These results show that the AgSbO3-modified (K0.50Na0.50)NbO3 lead-free piezoelectric ceramics form stable solution with orthorhombic structure, and the Curie temperature and the polymorphic phase transition of the ceramics decreased with increasing AgSbO3. The result shows that the piezoelectric properties of the ceramics strongly depend on the AgSbO3. The ceramics with x=0.05 possess optimum properties (d33=192 pC/N, kp=43%, Tc=348degreeC, To-t=145degreeC, ?r632, and tan d3.5%). These results indicate that the ceramic is a promising candidate material for lead-free piezoe...
2009-01-01
Magnetic microstructure of candidates for epitaxial dual Heusler magnetic tunnel junctions
Energy Technology Data Exchange (ETDEWEB)
Heusler alloys are considered as interesting ferromagnetic electrode materials for magnetic tunnel junctions, because of their high spin polarization. We, therefore, investigated the micromagnetic properties in a prototypical thin film system comprising two different Heusler phases Co{sub 2}MnSi (CMS) and Co{sub 2}FeSi (CFS) separated by a MgO barrier. The magnetic microstructure was investigated by X-ray photoemission electron microscopy (XPEEM). We find a strong influence of the Heusler phase formation process on the magnetic domain patterns. SiO{sub 2}/V/CMS/MgO/CFS and SiO{sub 2}/V/CFS/MgO/CMS trilayer structures exhibit a strikingly different magnetic behavior, which is due to pinhole coupling through the MgO barrier and a strong thickness dependence of the magnetic ordering in Co{sub 2}MnSi.
2009-05-15
Limitations of traveling wave relaying for overhead EHV transmission lines
Energy Technology Data Exchange (ETDEWEB)
Limitations of traveling wave relaying schemes for protection of overhead extra-high voltage transmission lines are investigated. A method of analysis of traveling wave phenomena for three phase transmission lines is developed in which the interdependent phase voltages and currents are decoupled into their modal counterparts, which are approximately independent. A time domain digital simulation program is used to solve the modal transmission line equations to obtain the fault induced traveling waves detected at the relay location. The frequency dependence of the aerial modes is ignored but their losses are included. A lumped element analysis method, originally developed for transient analysis of lossy coaxial cables, is adapted here to obtain approximate solution for the fault induced traveling waves of the ground mode. Excellent agreement is found between the results obtained by this method and frequency domain methods. ...
1986-01-01
Iron Aluminide Hot Gas Filters
Energy Technology Data Exchange (ETDEWEB)
Currently, high temperature filter systems are in the demonstration phase with the first commercial scale hot filter systems being installed on integrated gasification combined cycle (IGCC) and pressurized fluid bed combustion cycle (PBFC) systems (70 MW). They are dependent on the development of durable and economic high temperature filter systems. These filters are mostly ceramic tubes or candles. Ceramic filter durability has not been high. Failure is usually attributed to mechanical or thermal shock: they can also undergo significant changes due to service conditions. The overall objective of this project is to commercialize weldable, crack resistant filters which will provide several years service in advanced power processes. The specific objectives of this project are to develop corrosion resistant alloys and manufacturing processes to make Iron Aluminide filter media, and to use a ``short term`` exposure apparatus supported by other ...
1996-12-31
Hydrodynamic and thermal modeling of solid particles in a multi-phase, multi-component flow. [LMFBR
Energy Technology Data Exchange (ETDEWEB)
This paper presents the new thermal hydraulic models describing the hydrodynamics of the solid fuel/steel chunks during an LMFBR hypothetical core-disruptive accident. These models, which account for two-way coupling between the solid and fluid phases, describe the mass, momentum, and energy exchanges which occur when the chunks are present at any axial location. They have been incorporated in LEVITATE, a code for the analysis of fuel and cladding dynamics under Loss-of-Flow (LOF) conditions. Their influence on fuel motion is presented in the context of the L6 TREAT experiment analysis. It is shown that the overall hydrodynamic behavior of the molten fuel and solid-fuel chunks is dependent on both the size of the chunks and the power level. At low and intermediate power levels the fuel motion is more dispersive when small chunks, rather than large ones, are present. At high power levels the situation is reversed. These effects are explained in ...
1983-01-01
Energy Technology Data Exchange (ETDEWEB)
A series of plasma nitriding experiments has been conducted on AISI 304L austenitic stainless steel at temperatures ranging from 375 to 475 C using pulsed-DC plasma with different pulse duty cycles, N{sub 2}-H{sub 2} gas mixtures and treatment times. It is shown that a wide range of treatment parameters exist that allow the formation of the S-phase. The formation and growth of this surface layer depend strongly on the treatment parameters, such as nitrogen partial pressure and duty cycle. Within the parameter range investigated, the layer growth appears to be diffusion controlled with an activation energy about 107 kJ/mol. The formation of CrN precipitates during plasma nitriding is not accompanied by the formation of bcc iron, which might be expected due to the loss of free chromium. However, the S-phase transforms into CrN and bcc iron following a heat treatment at 450 C or higher for 25 h. The wear rate after plasma ...
1999-09-01
Formation of ZnTe compounds by using the electrochemical ion exchange reaction in molten chloride
Energy Technology Data Exchange (ETDEWEB)
The formation of ZnTe films was investigated on zinc substrates at 640 K by using the following ion exchange and chemical reaction processes,2Zn{sub (substrate)}+Te{sup 4+}{sub (inmoltensalts)}->2Zn{sup 2+}+Te{sub (onsubstrate)}Zn{sub (substrate)}+Te= {sub (onsubstrate)}-> ZnTe{sub (onsubstrate)}The Te{sup 4+} species was supplied to the substrate via the gas phase, vaporized from the eutectic LiCl-KCl molten salt containing TeCl{sub 4} (0.05-0.9 mol%). The phase of the films obtained depended on the reaction time and the TeCl{sub 4} content in the molten chloride. At low TeCl{sub 4} concentrations, ZnTe alloy was not formed over the entire surface even after 3.6 ks. On the other hand, at high TeCl{sub 4} concentrations, tellurium was detected in addition to the ZnTe compound during the first 0.3 ks of the reaction. By selecting appropriate TeCl{sub 4} concentrations and reaction times, a ZnTe film with a ...
2005-05-01
Formation kinetics and work function tuning of Pd_2Si fully silicided metal gate
International Nuclear Information System (INIS)
The formation kinetics of Pd_2Si for fully silicided (FUSI) gate formation and the work function tuning of a Pd_2Si FUSI gate by impurity predoping were investigated. It has been found that the morphology and phase of a formed FUSI layer depend not only on the silicidation annealing temperature but also on the heating ramp-up rate and the presence of impurities. Fast ramp-up annealing was necessary to avoid defect formation, such as voids in the silicide film at the oxide interface, and to obtain a homogeneous silicide film containing only Pd_2Si phase. The most severe effect on the silicidation reaction, that is the increase in defect formation, was brought about by As predoping. The work function of the Pd_2Si FUSI gate was modulated by impurity pileup at the Pd_2Si/SiO_2 interface, as in the case of the NiSi FUSI gate. However, the work function shifted in the opposite direction to that of the NiSi FUSI gate for As, P, ...
2007-04-01
International Nuclear Information System (INIS)
The phase transition behaviour of polyethylene-b-poly(ethylene oxide) (PE-b-PEO) diblock copolymer with relatively short chain lengths has been studied on the basis of temperature dependent infrared and Raman spectral measurements and synchrotron WAXD/SAXS simultaneous measurements, from which the concrete structural changes were deduced successfully from the various levels of molecular chain conformation, chain packing mode and higher-order structure. The higher-order structure has been found to transform between lamella, perforated lamella, gyroid, cylinder and sphere structures. The inner structural changes occurring in the polyethylene and poly(ethylene oxide) parts have been related with these morphological changes. The morphological transition from lamella to gyroid occurs with keeping the crystalline state of polyethylene parts. This apparently curious transition can be interpreted reasonably by assuming the thermally-activated chain ...
2009-08-01
Eulerian approach for multiphase flow simulation in a glass melter
Energy Technology Data Exchange (ETDEWEB)
A glass furnace, consisting of a combustion space and a glass melter, uses combustion heat to melt sand and cullet into liquid glass to make products. Glass quality is mainly dependent on the temperature, glass composition, and the level of impurities in a glass melter, which include solid batch/cullet particles, liquid glass, and gas bubbles. A comprehensive computational model using an Eulerian approach has been developed to simulate multiphase flows in a glass melter. It includes all the phases, divides solid particles or gas bubbles into various size groups, and treats each group as a continuum. The derived mass, momentum, and energy conservation equations of the flow are solved for local properties for each phase. The simulation considers the heating and melting of the batch (mainly from the radiative heat from combustion and from the convective heat from the molten glass), the formation and transport of bubbles, and ...
2005-12-01
Eulerian approach for multiphase flow simulation in a glass melter
International Nuclear Information System (INIS)
A glass furnace, consisting of a combustion space and a glass melter, uses combustion heat to melt sand and cullet into liquid glass to make products. Glass quality is mainly dependent on the temperature, glass composition, and the level of impurities in a glass melter, which include solid batch/cullet particles, liquid glass, and gas bubbles. A comprehensive computational model using an Eulerian approach has been developed to simulate multiphase flows in a glass melter. It includes all the phases, divides solid particles or gas bubbles into various size groups, and treats each group as a continuum. The derived mass, momentum, and energy conservation equations of the flow are solved for local properties for each phase. The simulation considers the heating and melting of the batch (mainly from the radiative heat from combustion and from the convective heat from the molten glass), the formation and transport of bubbles, and ...
2005-12-01
Estimation of vapour pressure over MOX fuel
International Nuclear Information System (INIS)
Use of high plutonia MOX as fuel is contemplated from the point of view of rapid disposition of plutonium and economic power generation. The fuel pellets are subjected to steep thermal gradients #approx# 1700 K drop across a radius of #approx# 2.5mm. This leads to evaporation-condensation of the fuel constituents to cooler regions. Vaporization depends on fuel compositions such as Pu fraction, Oxygen-to-Metal (O/M) ratio and local temperature. Knowledge of vapour chemistry is essential in understanding the fuel behavior. The vaporization behaviour of MOX was analyzed in this work using thermochemical methods. The vapour phase consisted of nine species; O, O_2, Pu, PuO, PuO_2, U, UO, UO_2 and UO_3. Oxygen formed part of the vapour phase along with other species and oxygen potential was not controlled independently. The vapour pressures were estimated at 2000 K as a function of (O/M) for several Pu-fraction. Results for ...
2010-12-01
Elastic Properties of Nematic Liquid Crystals Formed by Living and Migrating Cells
In culture migrating and interacting amoeboid cells can form nematic liquid crystal phases. A polar nematic liquid crystal is formed if the interaction has a polar symmetry. One type of white blood cells (granulocytes) form clusters where the cells are oriented towards the center. The core of such an orientational defect (disclination) is either a granulocyte forced to be in an isotropic state or another cell type like a monocyte. An apolar nematic liquid crystal is formed if the interaction has an apolar symmetry. Different cell types like human melanocytes (=pigment cells of the skin), human fibroblasts (=connective tissue cells), human osteoblasts (=bone cells), human adipocytes (= fat cells) etc., form an apolar nematic liquid crystal. The orientational elastic energy is derived and the orientational defects (disclination) of nematic liquid crystals are investigated. The existence of half-numbered disclinations show that the nematic phase ...
1998-01-01
Energy Technology Data Exchange (ETDEWEB)
Described herein are effects of nitrogen dissolved in steel on passivity and pitting corrosion, as one of the major corrosion phenomena observed in stainless steel. Mechanisms involved in controlling pitting corrosion by nitrogen are also discussed. Nitrogen contained in austenic stainless steel is concentrated in the surface area, in particular in the vicinity of the interface between the passive film and metal matrix. Nitrogen tends to decrease critical current density in an acid, when it is added to steel of high critical current density (approximately 1mA/cm{sup 2} or higher). This phenomenon is considered to result from accumulation of nitrogen preferentially in the surface area to prevent dissolution of steel. Nitrogen dissolved in the austenic phase improves resistance of the steel to pitting corrosion. This phenomenon is considered to result from controlled decrease in pH level during the initial stage of pitting corrosion, characterized by evolution of ...
1998-09-15
Energy Technology Data Exchange (ETDEWEB)
Hydrolysis of olive oil by Chromobacterium viscosum lipase was studied in a reverse micellar system of a anionic surfactant Aerosol OT (AOT) and isooctane. Different methods of solubilization of the micellar system afford specific dependence of enzymatic activity of the lipase on the water content in the micelles. In an injection method, water content is controlled by the amount of injected water, which determines the micelle size and hydrophobicity of the micelle without salt addition and changes reversibly the conformation of lipase corresponding to the change of lipase activity. The activity reaches the maximum at a water content (water/AOT)of 7. In a phase transfer method, water content is determined by salt concentration in the aqueous phase in contact with micelles and the water content corresponding to the maximum activity is 12 to 13, below which the activity decrese drastically. Addition of taurodeoxycholic acid to ...
1992-01-10
Effect of low copper content and heat treatment on intergranular corrosion of model AlMgSi alloys
International Nuclear Information System (INIS)
Certain 6000-series extrusions may develop susceptibility to intergranular corrosion (IGC) by improper heat treatment, especially if copper is present as an alloying element. Although occurrence of IGC in such cases is documented, the underlying mechanisms are not adequately explained. We present corrosion data for two model alloys, having different Cu content and Mg:Si ratio, showing that the susceptibility to IGC depended primarily on the Cu content and secondly on thermal processing. Low Cu samples (0.0005 wt.% Cu) were essentially resistant to IGC. High Cu samples (0.12 wt.% Cu), which were air cooled after extrusion, exhibited significant IGC. However, IGC susceptibility was reduced significantly as a result of artificial aging to peak strength. Water quenched high Cu samples were essentially resistant to IGC. However, slight IGC susceptibility was introduced after aging. Electron optical characterisation revealed Al_4Mg_8Si_7Cu_2 ...
2006-01-01
Energy Technology Data Exchange (ETDEWEB)
To improve organic electronic applications, knowledge about microscopic mechanisms determining the charge carrier mobilities is pivotal. 9,10-Diphenylanthracene (DPA) has been identified as model system to study those correlations due to its high electron and hole mobilities at room temperature and its complex structural phase behaviour. We demonstrate our temperature dependent Time-Of-Flight data on single crystals grown by vapor phase transport (VPT) and by Bridgman growth technique. Both preparation techniques revealed crystals of different morphologies resulting in significant variations of the related bipolar mobilities. As a key result, the charge carrier mobility of {proportional_to}1 cm{sup 2}/Vs at room temperature along the (111)-direction of Bridgman crystals exceeds that along the (001)-direction of VPT grown crystals by about one order of magnitude. The observed differences in the mobility data are discussed in ...
2010-07-01
CFD Approaches for Modelling Bubble Entrainment by an Impinging Jet
International Nuclear Information System (INIS)
This contribution presents different approaches for the modeling of gas entrainment under water by a plunging jet. Since the generation of bubbles happens on a scale which is smaller than the bubbles, this process cannot be resolved in meso-scale simulations, which include the full length of the jet and its environment. This is why the gas entrainment has to be modeled in meso-scale simulations. In the frame of a Euler-Euler simulation, the local morphology of the phases has to be considered in the drag model. For example, the gas is a continuous phase above the water level but bubbly below the water level. Various drag models are tested and their influence on the gas void fraction below the water level is discussed. The algebraic interface area density (AIAD) model applies a drag coefficient for bubbles and a different drag coefficient for the free surface. If the AIAD model is used for the simulation of impinging jets, the gas entrainment ...
5101-01-01
ADIABATIC MASS LOSS AND THE OUTCOME OF THE COMMON ENVELOPE PHASE OF BINARY EVOLUTION
International Nuclear Information System (INIS)
We have developed a new method for calculating common envelope (CE) events based on explicit consideration of the donor star's structural response to adiabatic mass loss. In contrast to existing CE prescriptions, which specify a priori the donor's remnant mass, we determine this quantity self-consistently and find that it depends on binary and CE parameters. This aspect of our model is particularly important to realistic modeling for upper main-sequence star donors without strongly degenerate cores (and hence without a clear core/envelope boundary). We illustrate the central features of our method by considering CE events involving 10 M_s_u_n donors on or before their red giant branch. For such donors, the remnant core mass can be as much as 30% larger than the star's He-core mass. Applied across a population of such binaries, our methodology results in a significantly broader remnant mass and final orbital separation distribution and a 20% increase in CE survival ...
2010-08-10
Van Der Pol model of a Cerenkov maser
Energy Technology Data Exchange (ETDEWEB)
A non-linear analysis of a Cerenkov maser is presented. The system consists of a ring configuration of a cylindrical waveguide filled with a dielectric material. A single transverse-magnetic mode is assumed to propagate in the system. A low-density pencil electron beam travels in part of the ring, confined by a strong axial magnetic field. Using the single-particle description for the beam and the wave equation for the field, we obtain a set of two coupled non-linear differential equations describing the slowly varying amplitude and phase of the electromagnetic mode. The gain per path is assumed to be small and the spatial growth of the field is neglected. The resulting time dependent amplitude includes the exponential gain of the linear stage and the saturation to its maximum value. The time dependent frequency is also calculated. The two equations are combined to a single Van Der Pol equation with a non-linear restoring ...
1995-12-31
Energy Technology Data Exchange (ETDEWEB)
Expressions for the spatial moments and macrodispersion tensor for sorbing solutes in heterogeneous formations were presented using a probabilistic model of a fluid residence time coupled with the particle position analysis. The fluid residence time was defined as a fraction of the actual time during which the particle stayed in the mobile fluid phase of the aquifer. The fluid residence time is a random variable whose variability comes as a result of the non-equilibrium sorption properties. The sorbing solute was assumed to be governed with first-order linear kinetics. The closed-form expressions were based on the stationarity in the kinetic process and on the first-order approximation in the hydraulic conductivity field and in the fluid residence time. The non-equilibrium effects were presented as a function of the spatial variability in hydraulic conductivity and temporal variability in the fluid residence time. The importance of the non-equilibrium processes in ...
1993-06-01
Three-dimensional power system stabilizer
Energy Technology Data Exchange (ETDEWEB)
Power system stabilizers (PSSs) are used to enhance damping of power system oscillations through excitation control of synchronous generator. The objective of the PSS is to generate a stabilizing signal, which produces a damping torque component on the generator shaft. Conventional PSSs are designed with the phase compensation technique in the frequency domain and include the lead-lag blocks whose parameters are determined according to a linearized power system model. The performance of conventional PSSs (CPSSs) depends upon the generator operating point and the system parameters, but a reasonable level of robustness can be achieved depending on the tuning method. This paper presents a new three-dimensional PSS (3D PSS), which uses rotor speed deviation, rotor acceleration and load angle deviation as input signals. The 3D PSS attempts to return the generator to the state-space origin, based on the generator's ...
2010-07-15
Structural, electronic and magnetic properties of splat-quenched FeCsub(x) alloys (x<0.05)
International Nuclear Information System (INIS)
The results of a combined investigation of splat-quenched Fe-Csub(x) (x<0.05) alloys by resistivity, X-ray diffraction and Moessbauer spectroscopy are presented. The residual resistivity increases linearly with the carbon content (#DELTA#rho=5#mu##OMEGA#cm/at.%) with a slope identical to that observed in the dilute ferritic phase. X-ray diffraction reveals the presence of a martensite structure in addition to a small fraction of residual austenite; the dependence of the a and c lattice parameters on xsub(c) agrees with earlier measurements. A detailed investigation of the relative reflexion intensities shows that the as-quenched martensites consist of a mixing of massive martensite and tetragonal martensite for low carbon content and of tetragonal martensite only for xsub(c) approximately 0.05. The Moessbauer spectra reveal 3 or 4 magnetically non equivalent iron sites. From a detailed analysis of the intensity ...
2006-01-01
Spectral dependence of ultrasonic attenuation for hydrided Zr-2.5%Nb Alloy
International Nuclear Information System (INIS)
The cold-worked Zr-2.5%Nb alloy is used as material for the pressure tubes in CANDU nuclear reactors. During the service life in reactor, diffusion of hydrogen and/or deuterium in the pressure tubes wall occur. Below a certain temperature, a stable hydride of zirconium is formed, as a brittle phase which can lead to catastrophic failures. For this reason, it is very important to be able to investigate the hydrogen effect on the micro structural properties of zirconium alloys. In the present paper a non-destructive testing technique is used, known as ultrasonic spectral analysis. When an ultrasonic signal traverses a medium, the frequency components associated with the input signal are altered. By frequency analysing the reflected signals, it is possible to study and compare the material properties. The two major parameters measured in ultrasonic spectroscopy are the attenuation and the velocity of the waves. Attenuation is determined by the energy losses in ...
2009-10-12
We present computer modeling along with experimental data on the formation of sharp conical tips on silicon-based three-layer structures that consist of a single-crystal Si layer on a 1 {mu}m layer of silica on a bulk Si substrate. The upper Si layers with thicknesses in the range of 0.8-4.1 {mu}m were irradiated by single pulses from a KrF excimer laser focused onto a spot several micrometers in diameter. The computer simulation includes two-dimensional time-dependent heat transfer and phase transformations in Si films that result from the laser irradiation (the Stefan problem). After the laser pulse, the molten material self-cools and resolidifies, forming a sharp conical structure, the height of which can exceed 1 {mu}m depending on the irradiation conditions. We also performed computer simulations for experiments involving single-pulse irradiation of bulk silicon, reported by other groups. We discuss conditions under ...
2008-05-01
Research on Dynamic Neutron Radiography in HANARO
Energy Technology Data Exchange (ETDEWEB)
Neutron radiography is a non-destructive test method to examine a material by using the dependency of neutron attenuation on the nuclear characteristics of the atoms composing the object material. There are two categories of neutron radiography; static neutron radiography and dynamic neutron radiography. The static neutron radiography is a technique to observe a standing object by using a camera or a film cassette. The dynamic neutron radiography(DNR) is a technique to observe a moving object usually by using a camera. Depending on the camera frame rate, the dynamic neutron radiography is categorized into the real time neutron radiography(RTNR) and the high speed neutron radiography(HSNR). The frame rate for RTNR is 30 frames/s and that for HSNR is usually more that 500 frames/sec. Thus, RTNR is good for observing time-averaged phenomena and HSNR is good for observing instantaneous phenomena. DNR is a powerful tool for fluid visualization as ...
2005-07-01
Research on Dynamic Neutron Radiography in HANARO
International Nuclear Information System (INIS)
Neutron radiography is a non-destructive test method to examine a material by using the dependency of neutron attenuation on the nuclear characteristics of the atoms composing the object material. There are two categories of neutron radiography; static neutron radiography and dynamic neutron radiography. The static neutron radiography is a technique to observe a standing object by using a camera or a film cassette. The dynamic neutron radiography(DNR) is a technique to observe a moving object usually by using a camera. Depending on the camera frame rate, the dynamic neutron radiography is categorized into the real time neutron radiography(RTNR) and the high speed neutron radiography(HSNR). The frame rate for RTNR is 30 frames/s and that for HSNR is usually more that 500 frames/sec. Thus, RTNR is good for observing time-averaged phenomena and HSNR is good for observing instantaneous phenomena. DNR is a powerful tool for fluid visualization as ...
2005-10-27
International Nuclear Information System (INIS)
In this work we report a study of the induced changes in structure and corrosion behavior of martensitic stainless steels nitrided by plasma immersion ion implantation (PI"3) at different previous heat treatments. The samples were characterized by x-ray diffraction and glancing angle x-ray diffraction, scanning electron microscopy, energy dispersive x-ray spectroscopy, and potentiodynamic measurements. Depending on the proportion of retained austenite in the unimplanted material, different phase transformations are obtained at lower and intermediate temperatures of nitrogen implantation. At higher temperatures, the great mobility of the chromium yields CrN segregations like spots in random distribution, and the #alpha#"'-martensite is degraded to#alpha#-Fe (ferrite). The nitrided layer thickness follows a fairly linear relationship with the temperature and a parabolic law with the process time. The corrosion resistance ...
2006-09-01
Neutron scattering studies of mixed-valence semiconductors
Energy Technology Data Exchange (ETDEWEB)
Neutron scattering experiments on the mixed-valence (MV) compounds SmB{sub 6} are reported. The inelastic magnetic response of SmB{sub 6} at T = 2 K, measured on a double-isotope single crystal,displays a strongly damped peak at 35 meV corresponding to the inter multiplet transition of Sm{sup 2+}. At lower energies ( h.{omega} {approx_equal} 14 meV), a narrow magnetic excitation is observed, with remarkable scattering-vector and temperature dependences of its intensity. This novel feature is discussed in terms of recent theoretical works describing the formation of an anisotropic local bound state in semiconducting MV materials. If the average samarium valence is decreased by substituting La for Sm, a peak is found to appear at high energies. The elastic magnetic form factor of SmB{sub 6} was determined using polarised neutrons and no significant difference is observed in its Q-dependence with respect to that of pure divalent samarium. This ...
1994-12-31
Enthalpy relaxation properties of the ethylene glycol (EG) aqueous solutions confined within silica-gel void spaces of 1.1 nm in the average void thickness and 6, 12 and 52 nm in their average diameters were examined by an adiabatic calorimetry to understand the glass transition behavior of the solutions and the rearrangement processes of the molecules. The glass transition temperature Tg of EG was found to decrease with adding the water molecules which are mobile under the condition lacking in the full hydrogen-bond network. Meanwhile, the Tg in the water-rich region showed a rise towards pure water; after a phase separation in a 25 mol% (x = 0.25) EG solution, the Tg was 160 K which was higher than that derived by extrapolating the composition dependence to pure water. The Tg = 160 K is the same as observed in the pure water confined within 1.1 nm voids; this indicates the validity of the interpretation that the glass transition at 160 K of ...
2008-02-01
Formation of the Neutron Donor C13 in AGB Stars by Overshoot and Rotation
(abridged) Observations clearly show that low-mass AGB stars can provide a nucleosynthesis site of the s-process. Recent stellar evolution models indicate that radiative burning of C13 between thermal pulses in low-mass AGB stars may indeed provide the needed neutrons. Some mixing between the proton-rich envelope and the carbon-rich core may lead to the production of C13. However, the responsible physical mechanism is not yet unambiguously identified. We present stellar model calculations with overshoot and rotation. Overshoot, with a time-dependent and exponentially decaying efficiency, leads to a partial mixture of protons and C12 during the third dredge-up. According to the depth-dependent ratio of protons and C12, a small C13-pocket forms underneath a N14-rich layer. Overshoot does not allow for any mixing during the interpulse phase. Rotation introduces mixing driven by large angular velocity gradients which form at ...
2000-01-01
Excitonic transitions in InGaP/InAlGaP strained quantum wells
International Nuclear Information System (INIS)
Excitonic transitions in metalorganic vapor phase epitaxially grown In_xGa_1_-_xP/In_0_._4_8(Al_0_._7Ga_0_._3)_0_._5_2P strained single quantum-well structures are characterized using low-temperature photoluminescence and photoluminescence excitation (PLE) spectroscopies. The structures consist of several uncoupled quantum wells with thicknesses between 1.2 and 11.3 nm, and compositions x of 0.48 (nominally lattice matched) and 0.56 (#approx#0.6% biaxial compressive strain). The photoluminescence spectra exhibit intense peaks over the wavelength range 550--650 nm, with linewidths between 7 and 23 meV depending on the well thickness. The PLE spectra reveal strong heavy-hole and light-hole transitions, as well as higher-order (n=2) transitions in the thicker wells. The heavy-hole/light-hole splitting shows little dependence on well thickness in the strained structures, indicating a relatively large conduction band offset of ...
Culture-area relation in Axelrod's model for culture dissemination
A salient facet of Axelrod's model for culture dissemination or social influence is the existence of many multicultural absorbing states. The dependence of the number $C$ of different, coexisting cultures on the size $A$ of the territory or, equivalently, on the number of agents -- the culture-area relation -- is investigated through extensive simulations. This relation exhibits a strong qualitative dependence on the two parameters of the model, namely, the number $F$ of culture features and the number $q$ of values that each feature can take on. We find that a non-monotonous culture-area relation, for which the number of cultures decreases when the area grows beyond a certain size, occurs for $q$ smaller than a threshold value $q_c = q_c (F)$ provided that $F \\geq 3$. In the limit of infinite area, this threshold value signals the onset of a discontinuous phase transition between a homogeneous regime for which C=1, and a ...
2009-01-01
Energy Technology Data Exchange (ETDEWEB)
Cold deformation of YBa{sub 2}Cu{sub 3}O{sub 7-x}(phase 123, T{sub c} = 88.5-92 K) powders and strips causes partial decomposition of the 123 phase, a reduction in the degree of orthorhombicity of the structure up to almost complete degradation, and a decrease in T{sub c}. When they are deformed, yttrium high temperature superconductors acquire basal (001) (110) texture with high pole density (13-15 arbitrary units), low scattering angle ({+-} 6deg--7deg from the normal direction), and a weak preference for a, b or a + b in the rolling direction; traces of (139) orientations may also be found. This texture is known to be favourable for increasing j{sub k}. The combined effect of cold deformation and a carbon-containing binder leads, however, to a complete loss of superconductivity at 77 K or above. Depending on the regime of subsequent annealing, the following effects may be observed: degradation of the orthorhombic ...
1991-09-20
Stress and stability of sputter deposited A-15 and bcc crystal structure tungsten thin films
International Nuclear Information System (INIS)
Magnetron sputter deposition was used to fabricate body centered cubic (bcc) and A-15 crystal structure W thin films. Previous work demonstrated that the as-deposited crystal structure of the films was dependent on the deposition parameters and that the formation of a metastable A-15 structure was favored over the thermodynamically stable bcc phase when the films contained a few atomic percent oxygen. However, the A-15 phase was shown to irreversibly transform into the bcc phase between 500 C and 650 C and that a significant decrease in the resistivity of the metallic films was measured after the transformation. The current investigation of 150 nm thick, sputter deposited A-15 and bcc tungsten thin films on silicon wafers consisted of a series of experiments in which the stress, resistivity and crystal structure of the films was measured as a function of temperatures cycles in a Flexus 2900 thin film ...
2900-01-01
Plasma nitriding of pure iron at several temperatures
Energy Technology Data Exchange (ETDEWEB)
The present work discusses the effect of the plasma nitriding temperature on the physical and chemical properties of the compound layer formed on pure iron samples. The samples were plasma nitrided in a mixture of H{sub 2}-20% N{sub 2} under a pressure of 6 mbar by using dc glow discharges. The treatment temperature T{sub N} was selected in the interval 400-600 C in steps of 50 C. X-ray diffraction and Moessbauer spectroscopy techniques were used as analytical tools to study the composition of the near-surface compound layer. Our results indicate that the effective thickness of the compound layer is smaller than 0.2 {mu}m for T{sub N} {<=}450 C and greater than this value for T{sub N} {>=}500 C. Also, we found that the compound layer is formed by a mixture of the phases {epsilon}-Fe{sub x}N(3.2{>=} x {>=}2) and {gamma}'-Fe{sub 4}N. In this case, the relative fractions of each phase ...
2002-06-01
Energy Technology Data Exchange (ETDEWEB)
Both the sign and magnitude of residual stress can vary with the thickness of sputter deposited films. The origins of this behavior are not well understood. In this work, the authors consider the correlation between the residual stress behavior and the depth dependence of impurities in thin (2.5 nm--150 nm) sputtered Mo and Ta films. They also consider the effects of phase transformations and microstructural changes on the stress behavior. Films were deposited onto Si substrates with native oxide. The residual stress observed in the Mo films varied from highly compressive at 2.5 nm film thickness to {approximately}0 at 10 nm thickness. Ta films also exhibited a high compressive stress, which relaxed from highly compressive to tensile between 10 nm and 50 nm film thickness. Impurities in the films may originate from the sputtering targets, the background gases, and the substrate surfaces. Auger Electron Spectroscopy (AES) results showed the ...
1997-05-01
Energy Technology Data Exchange (ETDEWEB)
Nitriding leads to improved tribological and corrosive properties of iron alloy components. In order to study the effect of plasma nitriding parameters on the structure of compound layer and diffusion zone, a systematic variation of process parameters, temperature and process gas atmosphere has been carried out. Metallographic inspection, X-ray diffraction and glow discharge optical spectroscopy analysis (GDOES) were used in this investigation. The results clarified that depending on the amount of nitrogen in the gas atmosphere nitrided layers with and without compound layer can be generated in the surface of M2 tool steel for temperatures from 350 C to 500 C. For plasma nitriding in 5 vol.% Nitrogen and 95 vol.% Hydrogen no compact compound layer was formed. The gas mixture of 76 vol.% Nitrogen resulted in compound layer formation for all temperatures from 350 C to 500 C. X-ray phase analysis indicated an almost 100% {epsilon}-(carbo)nitride ...
2001-09-01
Flow regime transfer conditions for two-phase flow in a fracture
Energy Technology Data Exchange (ETDEWEB)
Between 25 and 30 percent of total known petroleum reserves are contained within oil-laden fractured reservoirs where the dominant flow path is through the fractures. Economic oil recoveries from fractured reservoirs depend on a better understanding of the flow in fractures and networks of fractures. However, the flow of heavy oil and water, and particularly the flow regime map for two-phase immiscible flow has received less attention in contrast with gas-liquid flow in fractures. This paper discussed the use of flow pattern observations in a Hele-Shaw cell to generate two-phase flow regime maps. The paper investigated the effect of fracture gap and fluid viscosities on flow regimes. A correlation based on different flow and fracture properties was developed to define flow transition conditions between flow regimes. The paper presented the experiments, with particular reference to the experimental apparatus and the ...
2010-07-01
Burning of droplets and particles of explosives
Energy Technology Data Exchange (ETDEWEB)
Small droplets of organic diazides investigated by C.K. Law and coworkers burn in hot gas at 1 atm with rates inversely proportional to the droplet diameter presumably owing to leading chemical reaction proceeds in gas phase. These burning rates are obviously much lower than those obtained by extrapolation of the results measured for the some substances in glass tubes (at pressure of about 10{sup -2}-10{sup -1} atm, and temperature 0-100 deg C) on the burning conditions of the droplets. Kinetic constants estimated using Zel`dovich equation for the burning rate in gas phase and Semenov relation for delay time of the droplets micro-explosion in liquid phase are about the same: E {approx_equal} 0.17 MJ/mol, log{sub 10}k{sub o} {approx_equal} 15(S{sup -1}). In both of the cases the leading chemical reaction is supposed to be of the first order. Landau instability is assumed to be reflected in distortion of the droplets at ...
1996-12-31
np{yields}d{gamma} for big-bang nucleosynthesis
Energy Technology Data Exchange (ETDEWEB)
The cross section for np{yields}d{gamma} is calculated at energies relevant to big-bang nucleosynthesis using the recently developed effective field theory that describes the two-nucleon sector. The E1 amplitude is computed up to N{sup 3}LO and depends only upon nucleon-nucleon phase shift data. In contrast, the M1 contribution is computed up to next-to-leading order, and the four-nucleon-one-magnetic-photon counterterm that enters is determined by the cross section for cold neutron capture. The uncertainty in the calculation for nucleon energies up to E{approx}1 MeV is estimated to be (less-or-similar sign)4%. (c) 1999 The American Physical Society.
1999-12-01
X-ray studies of solid n-H/sub 2/
Energy Technology Data Exchange (ETDEWEB)
Results of X-ray investigations of solid normal hydrogen are presented. Temperature dependences of the lattice parameteps, molar volumes, linear and volume expansion coefficients in the 2K-Tsub(melt) temperature range are obtaiped. An essential n-H/sub 2/ expansion anisotropy in the premelting temperature region is pointed out. It is shown that the hexagonal lattice parameter ratios over the whole investigated temperature range is considerably higher than for solid parahydrogen. A considerable difference in thermal expansion of normal hydrogen and parahydrogen in the low temperature region is revealed. It is caused by contribuation of a rotational subsystem, increasing with the temperature decrease to crystal expansion. A detailed analysis of solid n-H/sub 2/ thermodynamic properties is conducted. The data testifying to the presence of isomorphous phase transformation in the solid n-H/sub 2/ in the premelting temperature region are discussed.
1983-08-01
Transient enhanced diffusion in B/sup +/ and P/sup +/ implanted silicon
International Nuclear Information System (INIS)
The authors report the transient enhanced diffusion of supersaturated phosphorous in ion-implanted SPE grown Si. Precipitation proceeds rapidly to a metastable SiP phase, which can be converted to an orthorhombic form or re-dissolved by subsequent heat treatment. The effects are strongly temperature dependent, and consistent with the trapped interstitial model. The behavior of different dopants follow their relative interstitialcy diffusion coefficients. The results suggest that ion implantation induced point defects dominate over thermally activated point defects during low temperature and certain rapid thermal processing, controlling dopant deactiviation and diffusion in crystalline or amorphous silicon, and can also affect the SPE growth rate.
Time-resolved triple-axis spectroscopy - a new method for real-time neutron scattering
International Nuclear Information System (INIS)
A new method for kinetic experiments with neutrons is described. This method combines the conventional triple-axis neutron spectroscopy with relaxation-type experiments. Whereas the former method yields information about the microscopic dynamics of solids, the latter provides macroscopic relaxation times. The combination of both methods allows to determine the microscopic mechanism of relaxation processes. The time-resolved triple-axis spectroscopy is limited to reversible processes and to time scales from 10"-"3 to 10"4 s. Typical applications are the kinetics of phase transformations (structural and dynamical changes), kinetics of domain distributions, kinetics of (spinodal) decomposition, reversible solid state reactions, time-dependent occupation of phonon states or phonon lifetimes. (orig.).
1990-04-01
International Nuclear Information System (INIS)
Hydrostatic weighing was used to measure the pre-melt density of crystalline eutectic mixtures of alkaline metal chlorides of the compositions (mole fractions): 0.605 LiCl + 0.395 CsCl, 0.585 LiCl + 0.415 KCl, 0.297 NaCl + 0.246 KCl + 0.457 CsCl, and 0.348 NaCl + 0.652 CsCl with melting points 598, 628, 753, 763 K, respectively, as a function of temperature. In the same temperature ranges, the compressibility and molar volume of eutectics as well as their sudden change upon melting were estimated. Unusual variations of these properties were revealed near the crystal/liquid phase transition, which were related to local disordering of particle configuration
TEM analyses of heterogeneous nucleation of internally oxidised multi-component Ag-Zn-based alloys
Energy Technology Data Exchange (ETDEWEB)
The aim of our research was to identify structures and chemical compositions of phases formed during internal oxidation of multi-component Ag-Zn-Mg-based alloys. Since the ability of inoculation mostly depends on large free energy of formation of oxides of microalloying elements and their crystallographic similarity, Mg in quantities of 0.001-0.5 mass% was selected as a micro-alloying element. These correspond to the quantities of 0.005-2.5 vol.% of MgO in the selected Ag-Zn-based alloys. Ag-based metal matrix, heterogeneous nuclei of MgO and oxide (ZnO) of the main alloying element were analysed by transmission electron microscopy (TEM). Structural inter-connections among them were also investigated and analysed. In situ phenomenon of heterogeneous nucleation of MgO and ZnO was proved. (orig.)
2001-11-01
Superconductivity on the threshold of magnetism in CePd{sub 2}Si{sub 2} and CeIn{sub 3}
Energy Technology Data Exchange (ETDEWEB)
The magnetic ordering temperature of some rare-earth-based heavy-fermion compounds is strongly pressure dependent and can be completely suppressed at a critical pressure, p{sub c}, making way for novel correlated electron states close to this quantum critical point. We have studied the clean heavy-fermion antiferromagnets CePd{sub 2}Si{sub 2} and CeIn{sub 3} in a series of resistivity measurements at high pressures up to 3.2 GPa and down to temperatures in the mK region. In both materials, superconductivity appears in a small window of a few tenths of a GPa on either side of p{sub c}. We present detailed measurements of the superconducting and magnetic temperature-pressure phase diagram, which indicate that superconductivity in these materials is enhanced, rather than suppressed, by the closeness to magnetic order. (author)
2001-03-26
Superconductivity on the threshold of magnetism in CePd_2Si_2 and CeIn_3
International Nuclear Information System (INIS)
The magnetic ordering temperature of some rare-earth-based heavy-fermion compounds is strongly pressure dependent and can be completely suppressed at a critical pressure, p_c, making way for novel correlated electron states close to this quantum critical point. We have studied the clean heavy-fermion antiferromagnets CePd_2Si_2 and CeIn_3 in a series of resistivity measurements at high pressures up to 3.2 GPa and down to temperatures in the mK region. In both materials, superconductivity appears in a small window of a few tenths of a GPa on either side of p_c. We present detailed measurements of the superconducting and magnetic temperature-pressure phase diagram, which indicate that superconductivity in these materials is enhanced, rather than suppressed, by the closeness to magnetic order. (author)
2001-03-26
Structure and properties of Li2Zn2(MoO4)3 crystals activated with copper and chromium ions
British Library Electronic Table of Contents (United Kingdom)
Based on the corrected phase diagrams proper growth conditions for Li2Zn2(MoO4)3 crystals are selected. Large crystals (up to 100 mm), both impurity-free and activated by transition metal ions (Cu, Cr), are grown by the low-gradient Czochralski method. By the EPR method the charge state and structural position of copper and chromium ions are determined. The performed studies of luminescent properties show that for impurity-free crystals luminescence with ? = 388 nm with a two-exponential luminescence decay with ?1 = 2 ns and ?2 = 6 ns is observed at room temperature. At 77 K for both impurity-free crystals and those activated with transition metal ions luminescence with ? = 560 nm and the luminescence lifetime ? = 100 ns is observed, the intensity of luminescence with ? = 560 nm depending ...
2011-01-01
Role of temperature in the spontaneous precipitation of calcium sulfate dihydrate
Energy Technology Data Exchange (ETDEWEB)
The spontaneous precipitation of calcium sulfate in supersaturated solutions over the temperature range between 25.0 and 80.0 C was investigated by monitoring the solution specific conductivity during desupersaturation. From measurements of the induction times preceding the onset of precipitation the surface energy of the forming solid, identified as gypsum, was found between ca. 12 and 25 mJ/m{sup 2} for the temperature range between 80.0 and 25.0 C, respectively. Kinetics analysis showed that over 50 C it is possible that anhydrous calcium sulfate is forming as a transient phase converting into the more stable calcium sulfate dihydrate. The linear dependence of the rates of precipitation on the relative solution supersaturation suggested a mechanism according to which the growth units are integrated into the active sites of the supercritical nuclei by surface diffusion. According to the morphological examination of the crystals it is possible ...
1999-02-16
British Library Electronic Table of Contents (United Kingdom)
In this study, the use of the weakly basic anion exchange resins of phenol-formaldehyde (Amberlyst A 23), polyacrylate (Amberlite IRA 67) and polystyrene (Lewatit MonoPlus MP 62) matrices for removal of the reactive dye Remazol Black B (RBB) from aqueous solution and wastewater were investigated. RBB sorption on the anion exchangers was a time dependent process. Color reduction percentiles of 75.2, 33.9 and 25.1% in wastewater treatment were found after 216 h of phase contact time with Lewatit MonoPlus MP 62, Amberlyst A 23 and Amberlite IRA 67, respectively. Inorganic salts and anionic surfactant action influenced RBB uptake by the anion exchangers. The amounts of dye retained by the anion exchangers increased with a rise in temperature. The maximum sorption capacities calculated from the...
2011-01-01
British Library Electronic Table of Contents (United Kingdom)
Abstract A method to grow the halophilic archaeon Haloferax volcanii in microtiter plates has been optimized and now allows the parallel generation of very reproducible growth curves. The doubling time in a synthetic medium with glucose is around 6-h. The method was used to optimize glucose and casamino acid concentrations, to clarify carbon source usage and to analyze vitamin dependence. The characterization of osmotolerance revealed that after a lag phase of 24-h, H. volcanii is able to grow at salt concentrations as low as 0.7-M NaCl, much lower than the 1.4-M NaCl described as the lowest concentration until now. The application of oxidative stresses showed that H. volcanii exhibits a reaction to paraquat that is delayed by about 10-h. Surprisingly, only one of two amino acid auxotrophi...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
This Final Report documents the research accomplishments achieved in the first phase of operations of a new Advanced Photon Source beam line (7-ID MHATT-CAT) dedicated to real-time x-ray studies. The period covered by this report covers the establishment of a world-class facility for time-dependent x-ray studies of materials. During this period many new and innovative research programs were initiated at Sector 7 with support of this grant, most notably using a combination of ultrafast lasers and pulsed synchrotron radiation. This work initiated a new frontier of materials research: namely, the study of the dynamics of materials under extreme conditions of high intensity impulsive laser irradiation.
2003-09-10
Non-Markovian dephasing in solid-state single photon sources
Solid-state single-photon sources have many desirable features that make them attractive for applications in quantum information processing. However, the phase coherence of such devices can be severely compromised by coupling to the solid-state environment. Here, we study the effects of realistic dephasing environments on a pair of solid-state single photon sources in the context of quantum interference effects such as the Hong-Ou-Mandel dip. By means of exact solutions for the non-Markovian dynamics of the sources, we show that the resulting loss of visibility depends crucially on the timing of photon detection events. Our results demonstrate that the effective visibility can be improved via temporal post-selection, and also that time-resolved interference can be a useful probe of the interaction between the emitter and its host environment.
2008-01-01
British Library Electronic Table of Contents (United Kingdom)
By choosing appropriate microemulsion systems, hexagonal cobalt (Co) and cobalt-nickel (1:1) alloy nanoparticles have been obtained with cetyltrimethylammonium bromide as a cationic surfactant at 500degreeC. This method thus stabilizes the hcp cobalt even at sizes (<10nm) at which normally fcc cobalt is predicted to be stable. On annealing the hcp cobalt nanoparticles in H2 at 700degreeC we could transform them to fcc cobalt nanoparticles. Microscopy studies show the formation of spherical nanoparticles of hexagonal and cubic forms of cobalt and Co-Ni (1:1) alloy nanoparticles with the average size of 4, 8 and 20nm, respectively. Electrochemical studies show that the catalytic property towards oxygen evolution is dependent on the applied voltage. At low voltage (less than 0.65V) the Co (he...
2009-01-01
British Library Electronic Table of Contents (United Kingdom)
Laser welding of AISI 904 L super austenitic stainless steel using a diffusion cooled slab 3.5kW CO2 laser and employing two different shielding gases, namely argon and helium, was carried out. The laser weld bead profile depends on various parameters such as beam power (BP), travel speed (TS) and focal position (FP) of the laser spot. These parameters have to be selected suitably to obtain the desirable output. The cross sectioned area of the bead profiles measured using an optical microscope to determine the bead width and depth of penetration. X-ray diffraction used for phase identification confirmed that the weld structure was fully austenitic and dendritic. Hardness was observed to increase in the weld bead with respect to the parent metal and it was related to the microstructural ref...
2010-01-01
Energy Technology Data Exchange (ETDEWEB)
A noninvasive method is described for estimating local cerebral blood flow (LCBF) and local partition coefficients by means of computed tomographic scanning during inhalation of 30% stable xenon gas in oxygen. Time-dependent xenon concentrations in arterial blood and brain tissue during the wash-in and washout phases are used to calculate partition coefficients and LCBF values by means of a least-squares curve-fitting analysis. Control values for partition coefficient and LCBF obtained from control subjects with minor head trauma in the chronic stage were compatible with those in several past reports, and reproducibility was satisfactory. The theoretic grounds underlying this new method of curve-fitting analysis are discussed.
1988-07-01
International Nuclear Information System (INIS)
A noninvasive method is described for estimating local cerebral blood flow (LCBF) and local partition coefficients by means of computed tomographic scanning during inhalation of 30% stable xenon gas in oxygen. Time-dependent xenon concentrations in arterial blood and brain tissue during the wash-in and washout phases are used to calculate partition coefficients and LCBF values by means of a least-squares curve-fitting analysis. Control values for partition coefficient and LCBF obtained from control subjects with minor head trauma in the chronic stage were compatible with those in several past reports, and reproducibility was satisfactory. The theoretic grounds underlying this new method of curve-fitting analysis are discussed.
Energy Technology Data Exchange (ETDEWEB)
Many modern military systems used for communications, command and control, navigation, and surveillance depend on reliable and relatively noise-free transmission of radiowave signals through the earth's ionosphere. Small-scale irregularities in the ionospheric density can cause severe distortion, known as radiowave scintillation, of both the amplitude and phase of these signals. The WBMOD computer program can be used to estimate these effects on a wide range of systems. The objective of this study is to investigate improvements to the WBMOD model based on extensive data sets covering both the equatorial and high-latitude regimes. This report summarizes the work completed during the second year, which include completion of the new models for the equatorial region and initial development of models for the high latitude (auroral and polar cap) region.
1993-11-01
Intermediate Strain-Rate Loading Experiments - Technique and Applications to Ceramics
Energy Technology Data Exchange (ETDEWEB)
A new test methodology is described which allows access to loading rates that lie between split Hopkinson bar and shock-loading techniques. Gas gun experiments combined with velocity interferometry techniques have been used to experimentally determine the intermediate strain-rate loading behavior of Coors AD995 alumina and Cercom silicon-carbide rods. Graded-density materials have been used as impactors; thereby eliminating the tension states generated by the radial stress components during the loading phase. Results of these experiments demonstrate that the time-dependent stress pulse generated during impact allows an efficient transition from the initial uniaxial strain loading to a uniaxial stress state as the stress pulse propagates through the rod. This allows access to intermediate loading rates over 5 x 10{sup 3}/s to a few times 10{sup 4}/s.
1999-08-16
Interfacial area transport: data and models
International Nuclear Information System (INIS)
The objective of this research is to replace the current flow regime dependent interfacial area correlations in the thermal-hydraulic system analysis codes with an interfacial area transport equation, which dynamically models two-phase flow regime transitions. The interfacial area transport equation applicable to bubbly flows has been developed based on mechanistic modeling of bubble interaction. Detailed experiments have been performed for bubbly conditions in 2.54, 5.08 and 10.16-cm ID pipes to benchmark the model. This new approach predicts the continuous changes of the interfacial area and will eliminate artificial bifurcations stemming from the use of the static flow regime transition criteria. This paper presents the preliminary results of incorporating the one-group transport equation into the USNRC consolidated code, currently under development. The framework for the two-group transport equation and the necessary constitutive relations ...
2001-05-23
Interfacial area transport equation: model development and benchmark experiments
Energy Technology Data Exchange (ETDEWEB)
The interfacial area transport equation dynamically models two-phase flow regime transitions and predicts continuous changes of the interfacial area concentration along the flow field. It replaces the flow regime-dependent correlations for the interfacial area concentration in thermal-hydraulic system analysis. In the present study, detailed formulation of the interfacial area transport equation is presented along with its evaluation results based on the detailed benchmark experiments. In view of model evaluation, the equation is simplified into one-dimensional steady state one-group interfacial area transport equation. The prediction made by model agrees well with the experimental data obtained in round pipes of various diameters. The framework for the two-group transport equation and the necessary constitutive relations are also presented in view of bubble transport of various sizes and shapes. (author)
2002-07-01
Instanton fermionic zero mode at finite temperature and chemical potential
In QCD the spontaneous breaking of chiral symmetry and the U(1) axial anomaly can be understood considering instantons as the gauge configurations mediating quark-quark interaction. The existence of an exact zero mode solution of the Dirac equation in the field of a single instanton is the fundamental ingredient of this analysis. Explicit expressions for psi_0 are available for T different from 0 and mu=0, and mu different from 0 and T=0. In this paper we derive the solution for the most general case T different from 0 and mu different from 0. This new result opens the possibility of investigating the QCD dynamics associated with instantons in the full phase diagram. As a first step in this direction we will study the dependence of the instanton density from the thermodynamic coordinates.
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
Many modern military systems used for communications, command and control, navigation, and surveillance depend on reliable and relatively noise-free transmission of radiowave signals through the earth`s ionosphere. Small-scale irregularities in the ionospheric density can cause severe distortion, known as radiowave scintillation, of both the amplitude and phase of these signals. The WBMOD computer program can he used to estimate these effects on a wide range of systems. The objective of this study is to investigate improvements to the WBMOD model based on extensive data sets covering both the equatorial and high-latitude regimes. This report summarizes the work completed during the third year of this project, which includes completion of the new model for the high-latitude (auroral and polar cap) region of the WBMOD model.
1994-08-31
Hydrogen effect on cold rolling texture of stable #beta#-titanium alloy
International Nuclear Information System (INIS)
A study was made into microstructure and texture of cold rolled titanium alloy VT-35 with various hydrogen content aimed to reveal hydrogen influence on the mechanism of cold plastic deformation by rolling. Experiments were carried out using sheets 1.2 mm thick hydrogenated up to hydrogen concentrations from 0.06 to 0.554 mass. %. All specimens constituted a single-phase FCC #beta#-solid solution. It is shown that small hydrogen additions have a plasticizing effect on #beta#-titanium alloys in their cold rolling. The character of texture is dependent on hydrogen concentration and determined by deformation mechanism. 6 refs.; 5 figs.
Hydrogen absorption behavior of Zr-2.5Nb pressure tubes in Wolsung Unit 1
Energy Technology Data Exchange (ETDEWEB)
The deuterium uptake behavior of Zr-2.5Nb pressure tubes in Wolsung Unit 1 was analyzed in terms of longitudinal location, operation time, and coolant temperature. The results were compared with those obtained from Canadian CANDU reactors. The amount of deuterium uptake was higher at the outlet part than at the inlet part and was also higher when subjected to a longer operation time and a higher coolant temperature. The hydrogen uptake of Zr-2.5Nb in a hydrogen gas atmosphere was dependent on the microstructure of the alloy. The aged Zr-2.5Nb consisting of {alpha}-Zr and {beta}-Zr phases. The hydrogen in the alloy decreased the rate of oxidation. This could be explained in terms of the cathodic controlled reaction of Zr-2.5Nb oxidation. (author)
1998-08-01
British Library Electronic Table of Contents (United Kingdom)
The behavior of proton transfer facilitated by a novel thiazole derivative, N-methyl-4-(4-phenoxyphenyl)thiazol-2-amine (MPPT), across the water/1,2-dichloroethane (1,2-DCE) interface was investigated electrochemically. The ionic partition diagram for MPPT was obtained from interpretation of the cyclic voltammograms. The apparent partition coefficient of MPPT was evaluated by the shaking-flask method under experimental conditions, while that for the protonated form of MPPT was calculated from its transfer potential obtained from the ionic partition diagram. It was suggested that the mechanism for transfer of MPPT across the water/1,2-DCE) interface depends on the pH of the aqueous phase. The parameters of the facilitated proton transfer across the water/1,2-DCE interface were evaluated as ...
2011-01-01
FG Sge at the stage of dust shell ejection
British Library Electronic Table of Contents (United Kingdom)
New photometric observations of the variable star FG Sge, a rapidly evolving planetary nebula nucleus, were performed in 2003?2008. On 230 nights, we obtained 86 UBV and 155 BV RI (or R c , I c ) magnitude estimates. The maximum amplitude of the V-band light variations was >8 m . Six deep minima and four high maxima were observed. Analysis of the light curve has shown that the pulsation period of the star remained constant since 1991 and was P = 115 days. We have studied the wavelength dependence of the extinction at various phases of the light curve. The blueing of the B-V color at deep minima is interpreted as the result of light scattering in the circumstellar dust shell of the star formed by preceding dust ejections since 1992. Our spectroscopic observations performed on nine nights in...
2009-01-01
Electrical installations in locations with explosion hazards
Energy Technology Data Exchange (ETDEWEB)
The optimization of the safety characteristics of electrical installations in industrial plants with explosion or fire hazards can be obtained only through a careful interdisciplinary study and analysis carried out at the onset of the plant project design phase. The least complex and costly and safest solutions are those which are born from plant designs which take into account the typology of the industrial process or technology, or which incorporate pollution abatement measures and adequate safety measures for the electrical installations. This paper provides examples to illustrate how the global plant economy is fundamentally dependant upon a multi-disciplinary initial effort in design analyses. Comments are made relevant to the adequacy of the safety requirements established by existing and planned Italian norms in dealing with safety and fire protection for high-tech industrial plant electrical installations.
1987-11-01
British Library Electronic Table of Contents (United Kingdom)
BACKGROUND AND PURPOSE In spite of its widespread clinical application, there is little information on the cellular cardiac effects of the antidiabetic drug rosiglitazone in larger experimental animals. In the present study therefore concentration-dependent effects of rosiglitazone on action potential morphology and the underlying ion currents were studied in dog hearts. EXPERIMENTAL APPROACH Standard microelectrode techniques, conventional whole cell patch clamp and action potential voltage clamp techniques were applied in enzymatically dispersed ventricular cells from dog hearts. KEY RESULTS At concentrations -10-M rosiglitazone decreased the amplitude of phase-1 repolarization, reduced the maximum velocity of depolarization and caused depression of the plateau potential. These effects d...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
The present work focuses on investigations of a highly selective ligand for Am(III)/Ln(III) separation: bis-triazinyl-pyridine (BTP). By means of nano-electro-spray mass spectrometry, complex formation of BTP with selected elements of the lanthanide series is investigated. We show that the diluent drastically influences complex speciation. Measurements obtained in the extraction-relevant diluent 1-octanol show the occurrence of Ln(BTP){sub i} (i 1-3) species in different relative abundances, depending on the lanthanide used. Here, the relative abundances of the Ln(BTP){sub 3} complexes correlate with the distribution ratios for extraction to the organic phase of the respective lanthanide. (authors)
2009-12-15
British Library Electronic Table of Contents (United Kingdom)
We report a solution-phase synthetic route to copper nanoparticles with controllable size and shape. The synthesis of the nanoparticles is achieved by the reduction of copper(II) salt in aqueous solution with hydrazine under air atmosphere in the presence of poly(acrylic acid) (PAA) as capping agent. The results suggest that the pH plays a key role for the formation of pure copper nanoparticles, whereas the concentration of PAA is important for controlling the size and geometric shape of the nanoparticles. The average size of the copper nanoparticles can be varied from 30 to 80 nm, depending on the concentration of PAA. With a moderate amount of PAA, faceted crystalline copper nanoparticles are obtained. The as-synthesized copper nanoparticles appear red in color and are stable for weeks, ...
2010-01-01
Boron diffusion in amorphous silicon
Energy Technology Data Exchange (ETDEWEB)
We have investigated B diffusion in pre-amorphized silicon. In our experiments, the crystalline surface layer of silicon-on-insulator (SOI) substrates was completely amorphized by Ge ion implantation. Using SOI substrates in this fashion suppressed solid-phase-epitaxy regrowth, making it possible to investigate B diffusion in pre-amorphous silicon over a wider range of temperatures (500-650 deg. C) and times (5-1000 s) than has previously been reported. Diffusivities were determined with the aid of computational processes modeling. The results from this work demonstrate the B diffusion in a-Si is concentration dependent, exhibits a transient enhanced diffusion, and possesses an Arhennius behavior with activation energy of {approx}2.1 eV.
2005-12-05
Boron diffusion in amorphous silicon
International Nuclear Information System (INIS)
We have investigated B diffusion in pre-amorphized silicon. In our experiments, the crystalline surface layer of silicon-on-insulator (SOI) substrates was completely amorphized by Ge ion implantation. Using SOI substrates in this fashion suppressed solid-phase-epitaxy regrowth, making it possible to investigate B diffusion in pre-amorphous silicon over a wider range of temperatures (500-650 deg. C) and times (5-1000 s) than has previously been reported. Diffusivities were determined with the aid of computational processes modeling. The results from this work demonstrate the B diffusion in a-Si is concentration dependent, exhibits a transient enhanced diffusion, and possesses an Arhennius behavior with activation energy of #approx#2.1 eV.
2005-12-05
Are ecologists blind to small things? The missed stories on non-tropical seed predation on feces
British Library Electronic Table of Contents (United Kingdom)
Seed dispersal involves several complex stages that can be affected by multiple peripheral processes. Thus, a major dispersal event can be followed by secondary dispersal, which can reduce density-dependent mortality and consolidate the dispersal phase. But predation events can also follow, and predation of seeds in feces is particularly interesting because it can heavily alter the fate of seeds dispersed through vertebrate guts. Our review of 20 cases involving this kind of interaction found that research has chiefly been in tropical and subtropical areas (85% of cases), suggesting that it is a minor phenomenon at higher latitudes. However, the small size of both the seeds and predators involved may have caused this process to go unnoticed outside the tropics. We tested the presence of pr...
2010-01-01
Approximate solutions to the Stefan problem with internal heat generation
Energy Technology Data Exchange (ETDEWEB)
Using a quasi-static approach valid for Stefan numbers less than one, we derive approximate equations governing the movement of a phase change front for materials which generate internal heat. These models are applied for both constant surface temperature and constant surface heat flux boundary conditions, in cylindrical, spherical, plane wall and semi-infinite geometries. Exact solutions with the constant surface temperature condition are obtained for the steady-state solidification thickness using the cylinder, sphere, and plane wall geometries which show that the thickness depends on the inverse square root of the internal heat generation. Under constant surface heat flux conditions, closed form equations can be obtained for the three geometries. In the case of the semi-infinite wall, we show that for constant temperature and constant heat flux out of the wall conditions, the solidification layer grows then remelts. (orig.)
2008-05-15
Antiferromagnetic Kondo lattice: CePdSi_2
International Nuclear Information System (INIS)
The compounds CePdSi_2, CeIrSi_2 and CeRhSn_2 have been synthesized and studied by X-ray diffraction, electrical resistivity and magnetic susceptibility. The magnetic susceptibility of CePdSi_2 exhibits two peaks at 6.8 K and 2.5 K, respectively, indicating two antiferromagnetic phase transitions, while that of CeIrSi_2 shows a broad maximum at 150 K, characteristic of valence fluctuating Ce-compounds. CeRhSn_2 remains paramagnetic down to 5 K. The resistivity of CeIrSi_2 exhibits a T"2 dependence at low temperatures, indicating a Fermi-liquid ground state, while those of CePdSi_2 and CeRhSn_2 shows the presence of Kondo and crystal field effects. (orig.).
1996-08-19
Energy Technology Data Exchange (ETDEWEB)
A core-wide in-phase neutron flux oscillation, which took place, for example, at LaSalle-2 in the USA in 1988, is one of the nuclear-coupled thermal hydraulic instabilities in boiling water reactors (BWRs). In this study, an analysis has been performed focusing on the excitation of this type of instability in BWRs due to seismically induced resonance, within the scope of a point kinetics model. For this purpose, the TRAC-BF1 code has been modified to take into account the external acceleration in addition to gravity. As a result of this analysis, it is shown that reactivity insertion can occur accompanied by in-surge of the coolant into the core resulting from excitation. It is also shown that the amount of reactivity inserted largely depends on the degree of stability of the initial state and the amplitude of the seismic wave, whose frequency is the same as the characteristic frequency of the instability. (orig.).
1996-04-01
International Nuclear Information System (INIS)
A core-wide in-phase neutron flux oscillation, which took place, for example, at LaSalle-2 in the USA in 1988, is one of the nuclear-coupled thermal hydraulic instabilities in boiling water reactors (BWRs). In this study, an analysis has been performed focusing on the excitation of this type of instability in BWRs due to seismically induced resonance, within the scope of a point kinetics model. For this purpose, the TRAC-BF1 code has been modified to take into account the external acceleration in addition to gravity. As a result of this analysis, it is shown that reactivity insertion can occur accompanied by in-surge of the coolant into the core resulting from excitation. It is also shown that the amount of reactivity inserted largely depends on the degree of stability of the initial state and the amplitude of the seismic wave, whose frequency is the same as the characteristic frequency of the instability. (orig.).
1996-01-01
Alignment of nematic liquid crystals on mixed Langmuir-Blodgett mono-layers
Mono-layers of stearic and behenic acids and mixtures of them in different proportions, deposited with the Langmuir-Blodgett technique, were used to study the alignment and the alignment dynamics in nematic liquid crystal cells. A relaxation process from a splay-bend flow induced metastable orientation to the homeotropic one occurs. The lifetime of the metastable state was found to depend on the mono-layer composition. The transition between the homeotropic and the conical anchoring was found to be irreversible in the case of the mixed aligning mono-layers: on cooling from the isotropic phase a quasi-planar nematic state (schlieren texture) appears. It is stable in a range of a few degrees below the clearing point and, on decreasing the temperature, relaxes to the homeotropic state in form of expanding domains.
1998-01-01
Alignment and alignment dynamics of nematic liquid crystals on Langmuir-Blodgett mono-layers
Mono-layers of stearic and behenic acids deposited with the Langmuir-Blodgett technique, were used as aligning films in nematic liquid crystal cells. During the filling process the liquid crystal adopts a deformed quasi-planar alignment with splay-bend deformation and preferred orientation along the filling direction. This state is metastable and transforms with time into homeotropic once the flow has ceased. The transition is accompanied by formation of disclination lines which nucleate at the edges of the cell. The lifetime of the metastable splay-bend state was found to depend on the cell thickness. On heating, anchoring transition from quasi-homeotropic to degenerate tilted alignment in form of circular domains takes place near the transition to the isotropic phase. The anchoring transition is reversible with a small hysteresis.
1998-01-01
International Nuclear Information System (INIS)
Activation energy values for high temperature deformation of a beta -titanium alloy Ti-10V were determined from the flow stress strain rate data taken from the second increasing strain rate cycles, in order to find the rate controlling mechanism. Although the data obtained from first increasing strain rate cycles are considered most appropriated by the author in a previous study due to obvious reasons, the values obtained in present work are again indicative of lattice self diffusion in beta -phase as the rate controlling mechanism for this alloy and nevertheless suggest that two different activation energy values for a deformation process could be possible in a given temperature range, depending upon the data. (author)
2007-12-01
A review of the structural characteristics of alloy 800
International Nuclear Information System (INIS)
The published literature is reviewed and supplemented by current information from the author's laboratory, to show the influence of various compositional, heat treatment and thermomechanical factors on the structural characteristics of Alloy 800. The features discussed include carbon, aluminium, titanium and boron, solution treatment, ageing treatments with and without applied strain, and cold working. Examples of the aspects reviewed include the effect of heat treatment and service or testing temperature on the austenite grain size, and the relative importance of M_2_3C_6 and TiC, the influence of carbon level on gamma prime, the effect of residual or steady stress combined with time at temperature on changes in carbide or gamma prime morphology, and on the appearance of sigma or other intermetallic phases. The questions posed by these features are discussed generally, in terms of their effect on the mechanical properties at ambient and elevated temperatures and ...
A new method of determining the inclination angle in interacting binaries
We describe a method of determining the system parameters in non-eclipsing interacting binaries. We find that the extent to which an observer sees the shape of the Roche-lobe of the secondary star governs the amount of distortion of the absorption line profiles. The width and degree of asymmetry of the phase-resolved absorption line profiles show a characteristic shape, which depends primarily on the binary inclination and gravity darkening exponent. We show that, in principle, by obtaining high spectral and time resolution spectra of quiescent cataclysmic variables or low mass X-ray binaries in which the mass-losing star is visible, fitting the shape of absorption line profiles will allow one to determine not only the mass function of the binary, but also the binary inclination and hence the mass of the binary components.
1998-01-01
Thermomechanical fatigue of ODS superalloys; Thermomechanische Ermuedung von ODS-Superlegierungen
Energy Technology Data Exchange (ETDEWEB)
The ODS superalloys MA 6000 and MA 760 were investigated with regard to their behaviour under non-isothermal fatigue stress. For this purpose, strain-controlled thermomechanical and bithermal experiments with different phase relationships between strain and temperature were carried out on the one hand; on the other hand, the deformation behaviour under thermomechanical stress was modelled on the basis of isothermal cyclic creep data. The fatigue experiments show that a diamond-shaped cycle derived from the stress pattern of a turbine blade is clearly less critical than in-phase and out-of-phase cycles. The life of the diamond-shaped cycle is determined by oxidation-induced crack initiation and propagation and can be predicted easily with a suitable damage model. Important damage parameters required by the model can be obtained by the less complicated bithermal fatigue tests. Modelling of the TMF hystereses suggests that ...
1995-07-01
Multi-Phase Fracture-Matrix Interactions Under Stress Changes
Energy Technology Data Exchange (ETDEWEB)
The main objectives of this project are to quantify the changes in fracture porosity and multi-phase transport properties as a function of confining stress. These changes will be integrated into conceptual and numerical models that will improve our ability to predict and optimize fluid transport in fractured system. This report details our progress on: (a) developing the direct experimental measurements of fracture aperture and topology and fluid occupancy using high-resolution x-ray micro-tomography, (b) counter-current fluid transport between the matrix and the fracture, (c) studying the effect of confining stress on the distribution of fracture aperture and two-phase flow, and (d) characterization of shear fractures and their impact on multi-phase flow. The three-dimensional surface that describes the large-scale structure of the fracture in the porous medium can be determined using x-ray micro-tomography with ...
2005-12-07
Energy Technology Data Exchange (ETDEWEB)
In this study, liquid flame spray (LFS) was used to produce titania, silver and silver-titania deposits of nanoparticles. Titanium(IV)ethoxide (TEOT) and silver nitrate in ethanol solutions were used as precursors and sprayed into turbulent hydrogen-oxygen flame. Production rates of 1.5-40 mg/min of titania were used with silver additions of 1, 2, 4, and 8 wt% compared to titania. Nanoparticle deposits were collected by thermophoretic sampling at six different axial distances from the flame torch head: 3, 5, 10, 12, 15, and 20 cm, of which the all but the last one occurred inside the flame. The deposit samples were analysed by TEM and SAED analysis. The powder samples of the particles were also collected by electric precipitator to XPS and specific surface area analysis. Particle size and effective density after the flame in the aerosol were analysed with SMPS and ELPI. The results from the previous studies i.e. controlling the particle size by setting the production rates of the ...
2007-08-15
Energy Technology Data Exchange (ETDEWEB)
This is the first time that the adsorption of binary mixtures of polycyclic aromatic hydrocarbons (PAHs) has been studied. This study was carried out at laboratory scale in an experimental apparatus specially designed for this aim: with gas-phase fluorescence, a new detection procedure was used. Experimental conditions, mainly in terms of temperature (150C) and contaminant concentration (approximately 1 ppmv), close to the ones observed in energy generation systems, were applied. The PAH adsorption process interpretation was carried out by recording the experimentally obtained breakthrough curves. After the detection parameter optimization, the influence of adsorbate characteristics in the hot gas cleaning of PAH was studied. In this system, the adsorption of 10 binary mixtures of five PAH (naphthalene (Np), fluorene (Fu), phenanthrene (Phe), fluoranthene (Fl), and pyrene (Py)) on an activated carbon was investigated. It was found that the adsorbent efficiency is ...
2003-06-01
Enzyme-induced growth of silver nanoparticles studied on single particle level
Energy Technology Data Exchange (ETDEWEB)
Based on their interesting properties, metal nanoparticles show the potential as an analytical tool in electronic (Burmeister et al. 2004), optical (Yguerabide and Yguerabide 1998), and catalytic applications (Liu 2006). Their characteristics depend on the composition, shape, and size of the single particles. These various properties are utilized in many different approaches such as optics, magnetics (Lang et al. 2007), and laser technology (Csaki et al. 2007). We investigated an alternative method for the synthesis of nanoparticles. In this case, an enzyme, horseradish peroxidase, induces a silver deposition and replaces a metal nanoparticle as the reaction seed. Depending on the reaction time, we could obtain particles in a range of few nanometers up to more than 250 nm. For a better understanding of the enzymatic silver deposition process, the silver particles produced by this process were analyzed by SEM, TEM, and atomic force microscopy ...
2009-05-15
Anisotropic Nd{endash}Fe{endash}B bonded magnets made from HDDR powders (invited)
Energy Technology Data Exchange (ETDEWEB)
Anisotropic Nd{endash}Fe{endash}B magnet powders can be produced by the hydrogenationdecomposition-desorption-recombination (HDDR) process from Nd{endash}Fe@ xnB{endash}Co{endash}M ({ital M}=Ga, Zr, Nb, Hf, and Ta) alloys. The present status of those HDDR powders and the bonded magnets made from them are reviewed with regards to the powder particle size dependence of their magnetic properties, their magnetic thermal stability, and their magnetization behavior. The results of a mechanistic study on the recombination step are also presented. The magnetic properties of the anisotropic HDDR powder depend relatively little on the powder particle size. Bonded magnets with a density of {approximately}6.20 g/cm{sup 3} and a BH{sub max} of 18.5{endash}20.5 MGOe can be produced from anisotropic HDDR powders with particle sizes of below 300 {mu}m diam. The temperature coefficient of the intrinsic coercive force {sub {ital iH}}{sub {ital c}}, of the bonded ...
1996-04-01
Energy Technology Data Exchange (ETDEWEB)
A new generation of quasimonochromatic high-flux X-ray sources, based on the X-ray radiation produced through Compton scattering between an electron beam and a laser beam, is under development. One of the possible applications of this source is inline phase contrast mammography, based on the observation of the edge-enhancement effect that can be observed at the border of structures inside the breast in images produced using a partially or totally coherent X-ray beam. In this work we present the results of a set of simulations of inline phase contrast mammography using typical inverse Compton scattering sources parameters. The simulated sample was a tumour-like mass having spherical shape, diameter between 200 {mu}m and 5 mm, placed inside a breast-like matrix, 4 cm thick, and a standard composition of 50% glandular tissue and 50% adipose tissue. We discuss the minimum requirements for mammography using inverse Compton scattering sources and we ...
2009-09-01
Thermal stability of nanocomposite CrC/a-C:H thin films
International Nuclear Information System (INIS)
The thermal stability of low-friction Me-C/a-C:H coatings is important for their potential applications in the tool and automotive industry. Recently we showed that CrC _x/a-C:H coatings prepared by unbalanced magnetron sputtering of a Cr target in Ar + CH_4 glow discharges exhibit a nanocomposite structure where metastable fcc CrC nanocrystals are encapsulated by an a-C:H phase. Here, we present the structural evolution of these nanocomposite CrC/a-C:H coatings during annealing. High-temperature X-ray diffraction in vacuum and differential scanning calorimetry (DSC) combined with thermo-gravimetric analysis in Ar atmosphere indicate decomposition of the formed metastable fcc CrC phase and subsequent formation of Cr_3C_2 and Cr_7C_3 and structural transformation of the a-C:H matrix phase towards higher sp"2 bonding contents at temperatures above 450 deg. C. Combined DSC and mass spectrometer analysis as well as elemental ...
2007-05-07
THE BURST MODE OF ACCRETION AND DISK FRAGMENTATION IN THE EARLY EMBEDDED STAGES OF STAR FORMATION
International Nuclear Information System (INIS)
We revisit our original papers on the burst mode of accretion by incorporating a detailed energy balance equation into a thin-disk model for the formation and evolution of circumstellar disks around low-mass protostars. Our model includes the effect of radiative cooling, viscous and shock heating, and heating due to stellar and background irradiation. Following the collapse from the prestellar phase allows us to model the early embedded phase of disk formation and evolution. During this time, the disk is susceptible to fragmentation, depending upon the properties of the initial prestellar core. Globally, we find that higher initial core angular momentum and mass content favors more fragmentation, but higher levels of background radiation can moderate the tendency to fragment. A higher rate of mass infall onto the disk than that onto the star is a necessary but not a sufficient condition for disk fragmentation. More locally, ...
2010-08-20
Spin freezing in the re-entrant spin glass FeNiMn close to the frustration limit
Energy Technology Data Exchange (ETDEWEB)
In the invar alloy (Fe{sub 0.65}Ni{sub 0.35}){sub 1-} {sub x} Mn {sub x} we measured the magnetic form factor s(Q) and the intermediate scattering function s(Q,t) for a sample close to the critical Mn concentration (x {sub c}=0.139), at which the sample turns to a re-entrant spin glass phase. The aim was to check whether the magnetic behaviour would approach the Q-independent relaxation behaviour of a classical spin glass when x=x {sub c}. The experiment showed a quite similar spin freezing as for a more ferromagnetic sample with x=0.113. The intermediate scattering function and the form factor were determined by paramagnetic NSE. The normalized scattering function S(Q,t)=s(Q,t)/s(Q)=exp[(-{gamma}t) {sup n}] was fitted by stretched exponential decay. As a function of temperature T<200 K the inverse time constant {gamma} showed the change of more than four orders of magnitude from frozen spin glass (T=60 K to T=100 K), where the ferromagnetic ...
2007-07-15
Energy Technology Data Exchange (ETDEWEB)
The current specifications of the LLNL fusion-fission hybrid proposal, namely LIFE, impose severe constraints on materials, and in particular on the nuclear fissile or fertile nuclear fuel and its immediate environment. This constitutes the focus of the present report with special emphasis on phase formation and phase transformations of the transmutation fuel and their consequences on particle and pebble thermal, chemical and mechanical integrities. We first review the work that has been done in recent years to improve materials properties under the Gen-IV project, and with in particular applications to HTGR and MSR, and also under GNEP and AFCI in the USA. Our goal is to assess the nuclear fuel options that currently exist together with their issues. Among the options, it is worth mentioning TRISO, IMF, and molten salts. The later option will not be discussed in details since an entire report is dedicated to it. Then, in a second part, with ...
2008-11-10
Numerical investigation of boiling regime transition mechanism by a Lattice-Boltzmann model
Energy Technology Data Exchange (ETDEWEB)
A numerical study has been performed to investigate the hydrodynamic aspects of the pool boiling on horizontal-, vertical- and downward-facing surfaces. The FlowLab code, which is based on a Lattice-Boltzmann (LB) model of two-phase flows, is employed. Macroscopic properties, such as surface tension ({sigma}) and contact angle ({beta}), are implemented through the fluid-fluid (G{sub {sigma}}) and fluid-solid (G{sub t}) interaction potentials. The model is found to express a linear relation between the macroscopic properties ({sigma}, {beta}) and microscopic parameters (G{sub {sigma}}, G{sub t}). The simulation results on bubble departure diameter appear to have the same parametric dependence as the empirical correlation. Hydrodynamic aspects of two-phase flow regime transition mechanism are investigated for different surface-coolant configurations. Results of the LB simulation clearly demonstrate that not only the bubble ...
2001-02-01
Energy Technology Data Exchange (ETDEWEB)
The current specifications of the LLNL fusion-fission hybrid proposal, namely LIFE, impose severe constraints on materials, and in particular on the nuclear fissile or fertile nuclear fuel and its immediate environment. This constitutes the focus of the present report with special emphasis on phase formation and phase transformations of the transmutation fuel and their consequences on particle and pebble thermal, chemical, and mechanical integrities. We first review the work that has been done in recent years to improve materials properties under the Gen-IV project, and with in particular applications to HTGR and MSR, and also under GNEP and AFCI in the USA. Our goal is to assess the nuclear fuel options that currently exist together with their issues. Among the options, it is worth mentioning TRISO, IMF, and molten salts. The later option will not be discussed in details since an entire report (Volume 8 - Molten-salt Fuels) is dedicated to it. ...
2008-12-19
EVOLUTION OF WHITE DWARF STARS WITH HIGH-METALLICITY PROGENITORS: THE ROLE OF "2"2Ne DIFFUSION
International Nuclear Information System (INIS)
Motivated by the strong discrepancy between the main-sequence turnoff age and the white dwarf cooling age in the metal-rich open cluster NGC 6791, we compute a grid of white dwarf evolutionary sequences that incorporates for the first time the energy released by the processes of "2"2Ne sedimentation and of carbon/oxygen phase separation upon crystallization. The grid covers the mass range from 0.52 to 1.0 M _s_u_n, and is appropriate for the study of white dwarfs in metal-rich clusters. The evolutionary calculations are based on a detailed and self-consistent treatment of the energy released from these two processes, as well as on the employment of realistic carbon/oxygen profiles, of relevance for an accurate evaluation of the energy released by carbon/oxygen phase separation. We find that "2"2Ne sedimentation strongly delays the cooling rate of white dwarfs stemming from progenitors with high metallicities at moderate luminosities, while ...
2010-08-10
International Nuclear Information System (INIS)
In the present study, the relationship between the crystallographic orientations and growth directions of grain boundary-allotriomorphic-#alpha# (GB #alpha#) and secondary Widmanstaetten #alpha# laths growing from the GB #alpha# at grain boundaries separating #beta# grains with specific misorientations has been examined. These relationships have been determined using a variety of characterization techniques, including scanning electron microscopy, orientation imaging microscopy, transmission electron microscopy (TEM) and a dual-beam focused ion beam instrument to provide site-selected TEM foils. Two very interesting cases, one in which the two adjacent #beta# grains are rotated mutually by approximately 10.5"o about a common direction and the other in which the two #beta# grains are in a twin relationship, i.e. a 60"o rotation about a common direction, have been studied. It was discovered that the #alpha# laths growing into two adjacent #beta# grains from the common grain boundary ...
2007-12-01
Corrosion product role on the inhibition of Zn alloy electrodeposit corrosion
Energy Technology Data Exchange (ETDEWEB)
Electrodeposited Zn alloys with Fe group metals are known to be more resistant than pure Zn. However, the role of the corrosion products on the corrosion inhibition is not considered up to date. The aim of the present work was to examine the composition of corrosion products, which form on the Zn and Zn alloy surfaces under atmospheric corrosion conditions up to 3 year of exposure, trying to correlate it with the differences in their corrosion resistance. Zn corrosion products have been characterized by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Corrosion film composition was determined to depend on the sample exposure she, as well on the coating type. During the initial exposure stages oxide film was found to be the principal reaction product (XPS data), which in marine station consists from hydroxide phase exceptionally, while in urban one, contain up to 6-12 % of oxide. Succeeding corrosion products (XRD data) in ...
1998-12-31
Energy Technology Data Exchange (ETDEWEB)
Customized reference tubes reduced sensitivity discrepancies able to be observed from one probe to the other, due to the gain setting adjustment required for a pre-definite level in amplitude response of the artificial notch. The use of a reference circuit in place of a reference part, makes characterization of the probe matched to its generator more accurate: - the material dependence is cancelled during the compensation process, - the reference signal can be adjusted more accurately in amplitude and phase response, - the manufacturing cost is reduced compared to the one necessary for machining the reference part, - the amplitude and phase response of the reference circuit can be simply modelled by using the transformer relations, such as one can appreciate the variations of the probe definition parameters and its connexion to the generator, and makes them optimal for use. The method proposed by ALSTOM for the ...
2001-07-01
We present results from the first studies of electric-field effects on optical transitions in visible-band-gap InGaP/InAlGaP multiple-quantum-well (MQW) structures. These structures, grown at 775 [degree]C by metalorganic vapor phase epitaxy on (100) GaAs substrates misoriented 6[degree] towards P(111)[r angle][l angle]111[r angle]A, consist of nominally undoped MQWs surrounded by doped In[sub 0.49]Al[sub 0.51]P cladding layers to form [ital p]-[ital i]-[ital n] diodes. The Stark shifts of various allowed and forbidden quantum-well transitions were observed in bias-dependent electroreflectance spectra of In[sub 0.49]Ga[sub 0.51]P/In[sub 0.49](Al[sub 0.5]Ga[sub 0.5])[sub 0.51]P MQW samples with 10-nm-thick layers. We find the magnitude of these shifts to depend on the details of the Mg doping profile, confirming the importance of Mg diffusion and unintentional background doping in these materials. Our results show that ...
1994-04-04
International Nuclear Information System (INIS)
We present results from the first studies of electric-field effects on optical transitions in visible-band-gap InGaP/InAlGaP multiple-quantum-well (MQW) structures. These structures, grown at 775 degree C by metalorganic vapor phase epitaxy on (100) GaAs substrates misoriented 6 degree towards P(111)right-angle left-angle 111 right-angle A, consist of nominally undoped MQWs surrounded by doped In_0_._4_9Al_0_._5_1P cladding layers to form p-i-n diodes. The Stark shifts of various allowed and forbidden quantum-well transitions were observed in bias-dependent electroreflectance spectra of In_0_._4_9Ga_0_._5_1P/In_0_._4_9(Al_0_._5Ga_0_._5)_0_._5_1P MQW samples with 10-nm-thick layers. We find the magnitude of these shifts to depend on the details of the Mg doping profile, confirming the importance of Mg diffusion and unintentional background doping in these materials. Our results show that (InAlGa)P materials are promising for ...
The authors present electric-field dependent electroreflectance and photocurrent spectra of visible-bandgap In{sub x}(Al{sub y}Ga{sub 1{minus}y}){sub 1{minus}x}P/In{sub x{prime}}(Al{sub y{prime}}Ga{sub 1{minus}y{prime}}){sub 1{minus}x{prime}}P multiple-quantum-well (MQW) structures. These structures, grown by metal-organic vapor phase epitaxy on 6{degrees}-misoriented (100) GaAs substrates, have undoped MQWs sandwiched between doped In{sub 0.5}Al{sub 0.5}P layers, forming p-i-n diodes. Quantum-well compositions in the range 0.46{le}x{le}0.52 and 0{le}y{le}0.4, corresponding to bandgaps in the red to yellow-green range, were used. The Stark shifts in these various samples were measured and found to depend on the details of the Mg p-type doping profile, confirming important diffusion effects, in agreement with secondary ion mass spectrometry and capacitance-voltage data. The results show that these new materials are promising ...
1993-12-31
Energy Technology Data Exchange (ETDEWEB)
The objective of this project is to increase oil recovery from fractured reservoirs through improved fundamental understanding of the process of spontaneous imbibition by which oil is displaced from the rock matrix into the fractures. Spontaneous imbibition is fundamentally dependent on the reservoir surface free energy but this has never been investigated for rocks. In this project, the surface free energy of rocks will be determined by using liquids that can be solidified within the rock pore space at selected saturations. Thin sections of the rock then provide a two-dimensional view of the rock minerals and the occupant phases. Saturations and oil/rock, water/rock, and oil/water surface areas will be determined by advanced petrographic analysis and the surface free energy which drives spontaneous imbibition will be determined as a function of increase in wetting phase saturation. The inherent loss in surface free energy ...
2006-12-08
Energy Technology Data Exchange (ETDEWEB)
Sulfate attack of cement-based materials remains an important problem for the durability assessment of containers and disposal engineering barriers dedicated to the long-term storage of radioactive wastes since underground water which may reach these elements contains small quantities of sulfates (7-31 mmol/1). This work contributes to the study of sulfate-induced damage mechanisms, to their understanding and modelling. The experimental phases of this study aimed at the understanding of the different physico-chemical phenomena involved during an external sulfate attack at following their evolution and their impact on the transport and mechanical properties of the material. Leaching experiments in pure water and in a solution of sodium sulfate (with a sulfate content of 15 mmol/1), have been performed simultaneously on OPC paste (w/c 0,4)in order to allow a comparison of test results. The frequent analysis of the leachant has shown a consumption of sulfate ions by ...
2002-06-01
Flue gas desulfurization pilot study: summary of phase I and phase II reports
The initial phase of this study consisted of a survey of existing FGD systems used on larger combustion processes in the NATO countries and Japan.
1980-04-01
CP Violation in Top Physics at the NLC
Top quark is extremely sensitive to non-standard CP violating phases. General strategies for exposing different types of phases at the NLC are outlined. SUSY phase(s) cause PRA in $t\\to Wb$. The transverse polarization of the $\\tau$ in the reaction $t\\to b\\tau\
1996-01-01
Energy Technology Data Exchange (ETDEWEB)
Full text of publication follows: Different to the very simple class of homogeneous non-equilibrium models (HEM) an one dimensional thermal-hydraulic theoretical drift-flux based and thus non-homogeneous coolant channel model and, as a result, an in itself complete thermal-hydraulic coolant channel module CCM have been established allowing to simulate in a very general way the steady state and transient behaviour of the most important parameters of a single- or two-phase fluid flowing within any type of heated or non-heated coolant channel (with an eventually varying cross flow area). To avoid mathematical discontinuities at the transition from single- to two-phase flow the coolant channel will, in its general form, be split into different regions, i.e. be looked as a basic channel (BC) which can consist of a number of different flow regimes and can, accordingly, be subdivided into a number of sub-channels (SC-s). All of them belong, obviously, ...
2005-07-01
Water uptake and exchange kinetics of polyelectrolyte films: a neutron reflectometry study
Energy Technology Data Exchange (ETDEWEB)
The sequential layer-by-layer adsorption of polyanions and polycations to build polyelectrolyte multilayers has triggered enormous interest in their potential uses in a wide range of fields, from photonic to pharmaceutical applications. We show that the conformation of the solvent swollen films - prior to drying - is determined by the initial adsorption conditions, but can be altered ex-situ by exposure to a liquid phase of very high ionic strength. Recently it has been observed that the swelling depends on the charge of the outermost layer. In the PAH/PSS system we saw that assemblies with PSS as the outermost layer swell more than those with PAH outside. A neutron reflectivity study of this effect in addition indicated the existence of two kinds of water, bound with different strength within the films. Beside an unexpected two-step kinetics of swelling, the reflectivity curves of the layers against vacuum before and after re-hydration in ...
2007-07-01
Energy Technology Data Exchange (ETDEWEB)
The oxidative dehydrogenation (ODH) of light alkanes is an alternative way for the production of olefins. A wide variety of catalytic systems has been investigated. Vanadium oxide based catalysts were described in the literature as effective catalysts for the ODH of propane. The catalytic activity and selectivity depend on the kind of support material, the kind of dopants and the formation of complex metal oxide phases. In recent papers it was claimed that both orthovanadate and/or pyrovanadate species are selective for the ODH of propane. Niobia based materials were investigated as catalysts for acidic and selective oxidation type reactions. In the ODH of propane niobia exhibited a high selectivity to propene but the conversion of propane was low. V{sub 2}O{sub 5}-Nb{sub 2}O{sub 5} catalysts proved to be catalytically active and selective and showed no formation of oxygenates. In the present study the influence of the niobia dopant of the ...
1998-12-31
Treatment of produced water using hydrocyclones; Tratamento de agua produzida usando hidrociclone
Energy Technology Data Exchange (ETDEWEB)
Beyond a great number of applications in mineral process, the hydrocyclone separation has been used recently in an increasing number of fields, such as: environmental engineering, petrochemical engineering, food engineering, electrochemical engineering, pulp bioengineering, processes and paper industries, among others. Nowadays, the produced water is treated and then reinjected in the surface and also in return to the formation. In the offshore platforms, the produced water can be directly discarded in the ocean, since the dispersed phase concentration (oil) is according to Brazilian regulating agency limits. The basic principle used in hydrocyclone separation is the centrifugal sedimentation machine: the suspended particles are submitted to centrifugal acceleration, which separates them from the fluid. The basic geometry of a hydrocyclone consists of four parts: a cylindrical section for feeding, a conical section for swirling, an overflow and an under flow. The ...
2008-07-01
The use of foam to improve liquid lifting from low-pressure gas wells
Energy Technology Data Exchange (ETDEWEB)
Gas well load up is the loss of available reservoir energy due to the accumulation of liquids in the wellbore over time, and these liquids arise from liquids (hydrocarbons and water) condensed from the gas. Accumulation of these liquids near the wellbore can cause severe reduction to complete loss of available transport energy. A systematic experimental approach was undertaken to evaluate the performance of foam in removing liquids from the bottom of wells. The objectives of the research were: (1) to determine the efficiency of liquid lifting with foam; and (2) to compare the effects of surfactant type and concentration on liquid lifting. A flowloop successfully simulated the effects of completions with and without packer for low-pressure gas well with liquid production. In the base-case runs (air and water flow), the two phase flow regime was mostly annular. Liquid lifting is improved in general when a surfactant is used. For data analysis, two new parameters, ...
1999-07-01
The frequency map for billiards inside ellipsoids
The billiard motion inside an ellipsoid $Q \\subset \\Rset^{n+1}$ is completely integrable. Its phase space is a symplectic manifold of dimension $2n$, which is mostly foliated with Liouville tori of dimension $n$. The motion on each Liouville torus becomes just a parallel translation with some frequency $\\omega$ that varies with the torus. Besides, any billiard trajectory inside $Q$ is tangent to $n$ caustics $Q_{\\lambda_1},...,Q_{\\lambda_n}$, so the caustic parameters $\\lambda=(\\lambda_1,...,\\lambda_n)$ are integrals of the billiard map. The frequency map $\\lambda \\mapsto \\omega$ is a key tool to understand the structure of periodic billiard trajectories. In principle, it is well-defined only for nonsingular values of the caustic parameters. We present four conjectures, fully supported by numerical experiments. The last one gives rise to some lower bounds on the periods. These bounds only depend on the type of the caustics. We ...
2010-01-01
Energy Technology Data Exchange (ETDEWEB)
This paper describes an investigation of electrodeposited Zn-14% Ni and aluminium-based SermeTel 1140/962 coatings as possible replacements for cadmium. Slow strain rate tests were performed to measure the extent of direct hydrogen embrittlement of a high strength steel substrate as a result of the coating process and of hydrogen re-embrittlement caused by coating corrosion. The level of re-embrittlement was shown to depend on both the electrochemical potential of the coating and its barrier properties. Zn-14% Ni coatings caused the most re-embrittlement as they had the most active potential and contained through-thickness defects which left the steel exposed to hydrogen uptake. The microstructure of the high strength steel was also shown to be an important factor affecting the extent of embrittlement. AerMet 100 steel was more resistant than 300M steel and this was attributed to the presence of reverted austenite surrounding the martensite laths in AerMet 100, ...
2008-04-15
The NIR Upgrade to the SALT Robert Stobie Spectrograph
The near infrared (NIR) upgrade to the Robert Stobie Spectrograph (RSS) on the Southern African Large Telescope (SALT), RSS/NIR, extends the spectral coverage of all modes of the visible arm. The RSS/NIR is a low to medium resolution spectrograph with broadband imaging, spectropolarimetric, and Fabry-Perot imaging capabilities. The visible and NIR arms can be used simultaneously to extend spectral coverage from approximately 3200 A to 1.6 um. Both arms utilize high efficiency volume phase holographic gratings via articulating gratings and cameras. The NIR camera is designed around a 2048x2048 HAWAII-2RG detector housed in a cryogenic dewar. The Epps optical design of the camera consists of 6 spherical elements, providing sub-pixel rms image sizes of 7.5 +/- 1.0 um over all wavelengths and field angles. The exact long wavelength cutoff is yet to be determined in a detailed thermal analysis and will depend on the semi-warm instrument cooling ...
2006-01-01
Energy Technology Data Exchange (ETDEWEB)
The objective of this paper is first to provide empirical evidence of what can be seen as a rather remarkable change in EU's position on the use of greenhouse gas (GHG) emissions trading (ET) in climate policy, from the role of a sceptic in the run-up to Kyoto towards more of a frontrunner. The paper argues that there is a synergistic and multilevel mix of explanatory factors for this 'U-turn', including developments at the international, EU, Member State, sub-national, and even down to the personal level. Second, the paper explores and discusses the philosophy behind the Commission's proposal for a directive on GHG ET. Third, the paper examines the prospects for 'success' of a scheme for EU-wide ET using a multifaceted set of metrics. In brief, we argue that output success - the chances for having a directive adopted - hinges on the resolution of two key issues. First, whether the preliminary phase is to be ...
2003-07-01
International Nuclear Information System (INIS)
Electrodeposition of semiconducting iron oxide (Fe_2O_3) thin film was carried out from an alkaline sulphate bath. A 0.1 M ferrous sulphate (FeSO_4#centre dot#7H_2O) was complexed with 0.1 M citric acid. By addition of 1 N NaOH, pH of the solution was made alkaline (pH=9) and deposition of iron oxide (Fe_2O_3) thin films was carried out potentiostatically at room temperature (300 K). From cyclic voltametry (CV), electrochemical studies were carried out for deposition of iron oxide thin films. The XRD studies reveal that Fe_2O_3 with epsilon (#epsilon#) phase having monoclinic crystal structure is formed. By observing scanning electron microscope (SEM), it is seen that iron oxide films were homogeneous, uniform and well covered to surface of the substrate. Grain size was found to be in nanometers range from XRD analysis. The optical band gap of Fe_2O_3 thin film was estimated to be 1.90 eV. Electrical resistivity was order of 10"4 #OMEGA# cm. Dielectric constant and ...
2003-09-28
Spectrophotometric determination of vanadium(V) with 2-carbethoxy-5-hydroxy-1-(4-tolyl)-4-pyridone
International Nuclear Information System (INIS)
Vanadium(V) in aqueous HCl, HNO_3 or H_2SO_4 solutions is extracted with 2-carbethoxy-5-hydroxy-1-(4-tolyl)-4-pyridone (HA) dissolved in CHCl_3 and determined spectrophotometrically, Depending on the composition of the aqueous phase, two complexes are formed. At pH 1 (HCl, HNO_3, H_2SO_4) VO_2A(HA)_2 is formed with maximal absorption at 478 nm. However, from 4-5 M HCl, VO_2Cl(HA)_3 is extracted, and has maximal absorption at 615 nm. The same complex is extracted from 2-3 M HNO_3 or 3-4 M H_2SO_4 if enough chloride is added. Solutions of both complexes follow Beer's law and the molar extinction coefficients are 4.15x10"3 1.mole"-"1cm"-"1 at 478 nm and 5.10x10"3 at 615 nm. The determination of vanadium at both wavelengths is very simple, fast and selective. The composition of the complexes was established by the usual methods as well as by characterization of the isolated crystalline compounds by elemental analysis and infrared spectroscopy. ...
1975-01-01
Recent trends in heavy-fermion physics
Energy Technology Data Exchange (ETDEWEB)
We discuss recent results obtained for the heavy-fermion metals UPd{sub 2}Al{sub 3} and YbRh{sub 2}Si{sub 2}. UPd{sub 2}Al{sub 3} is the first among all superconductors for which tunneling and inelastic neutron-scattering data highlight a non-phononic, i.e., magnetic-exciton mediated, pair state. YbRh{sub 2}Si{sub 2} represents a model system exhibiting pronounced non-Fermi liquid effects above a weak antiferromagnetic phase transition at T{sub N}=70 mK. Upon approaching the quantum critical point (T{sub N}{yields}0), by low doping with Ge, one observes for T<0.3 K disparate behavior in the temperature dependences of both the electrical resistivity and the electronic specific heat as well as a Curie-Weiss law in the uniform magnetic susceptibility, implying uncompensated large 4f moments. These observations indicate a break up of the composite quasiparticles into their local f-spin and itinerant conduction-electron parts.
2003-05-01
Piezoelectric properties and thermal stability of (Na0.53K0.47-xAgx)Nb1-xSbxO3 ceramics
British Library Electronic Table of Contents (United Kingdom)
Abstract Many (K1-xNax)NbO3 (KNN)-based ceramics with high piezoelectric performance exhibit undesirable strong temperature dependence due to the orthorhombic-tetragonal polymorphic phase transition near room temperature. In order to improve the temperature stability of the ceramics, many additives have been added into the KNN-based ceramics to shift TO-T down to below room temperature. Contrary to the previous approach (Na0.53K0.47-xAgx)Nb1-xSbxO3 (NKANS) ceramics with TO-T well above room temperature have been prepared by a conventional solid-state reaction method. The density and the electrical properties are effectively improved by the addition of AgSbO3, and optimum piezoelectric properties are found in the ceramics with 0.05---x---0.07, with maximum kp---0.46 for NKANS5 and maximum d...
2011-01-01
On the Potential for Vacancy Annihilation as a Mechanism for Conditioning in Pu-1.9 at.% Ga
Energy Technology Data Exchange (ETDEWEB)
The {delta} {yields} {alpha}{prime} martensitic transformation in Pu-1.9 at.% Ga occurs when the alloy is cooled below about -100 C. This transformation exhibits anomalous behavior, where the isothermal transformation proceeds atypically with double-C kinetics. Recent work has revealed that an ambient temperature isothermal hold (referred to as conditioning) prior to the transformation has different effects depending on whether transformation proceeds in the upper- or lower-C of the double-C: the amount of transformation is increased with conditioning in the upper-C, while the transformation in the lower-C seems to be engendered by conditioning. The mechanism by which conditioning affects the low-temperature {delta} {yields} {alpha}{prime} transformation is thus of great importance to understanding the transformation itself as well as the general circumstances that can affect a martensitic phase transformation. Using differential scanning ...
2009-03-09
A systematic study of the Bragg nuclear resonant reflectivity from periodic multilayers in the energy and time domains is presented. Using the kinematical approach of the general reflectivity theory we describe the basic features of the time evolution of the reflected wave after a pulsed excitation of resonant multilayers by synchrotron radiation. Effects of the collective excitation have been examined such as the shift of quantum beat phases, the interplay between electronic and nuclear subsystem excitations depending on their relative position in a multilayer, the energy and time evolution of standing waves inside a resonant multilayer, and their influence on the reflectivity spectra. The exact expression for the reflectivity by a thin resonant layer placed inside a multilayer structure has been derived. The observed shift of the delayed reflectivity Bragg peak relative to the prompt peak is explained by the developed formalism. Experimental ...
2005-09-15
Noise bias in the refinement of structures derived from single particles
Energy Technology Data Exchange (ETDEWEB)
One of the main goals in the determination of three-dimensional macromolecular structures from electron microscope images of individual molecules and complexes (single particles) is a sufficiently high spatial resolution, about 4 A, at which the interpretation with an atomic model becomes possible. To reach high resolution, an iterative refinement procedure using an expectation maximization algorithm is often used that leads to a more accurate alignment of the positional and orientational parameters for each particle. We show here the results of refinement algorithms that use a phase residual, a linear correlation coefficient, or a weighted correlation coefficient to align individual particles. The algorithms were applied to computer-generated data sets that contained projections from model structures, as well as noise. The algorithms show different degrees of over-fitting, especially at high resolution where the signal is weak. We demonstrate that the degree of ...
2004-12-15
British Library Electronic Table of Contents (United Kingdom)
The interfacial tension g of the hexane solution of 1H,1H,10H,10H-perfluorodecane-1,10-diol (FC10diol) and 1H,1H,2H,2H-perfluorododecanol (TFC12OH) mixture against water was measured as a function of the total molality m and composition of TFC12OH in the mixture X2 at 298.15K under atmospheric pressure. The interfacial pressure p vs. mean area per adsorbed molecule A curves and the phase diagram of adsorption (PDA) were constructed in order to shed light on the effect of the molecular orientation on the state of and the miscibility of FC10diol and TFC12OH in the adsorbed film. The p vs. A curves demonstrated that the mixed system exhibits three kinds of film states, parallel-condensed, normal-condensed, and multilayer states, depending on m and X2. The PDA indicated that film composition X...
2010-01-01
Magnetic properties of a SmNiSn single crystal
Energy Technology Data Exchange (ETDEWEB)
The magnetic properties of a single crystal of SmNiSn with the orthorhombic {epsilon}-TiNiSi-type crystal structure have been investigated by magnetic susceptibility, magnetization and electrical resistivity measurements from 1.5 K to room temperature. Two anomalies have been found in the magnetic susceptibility, indicating an antiferromagnetic phase transition at T{sub N}=9.4 K and a second transition at 4.4 K. A large magnetic anisotropy has been found at low temperatures in the temperature and field dependencies of magnetic susceptibility and magnetization. Below 80 K, the easy axis of the magnetization is the c-axis. At T=2.0 K, the c-axis magnetization curve exhibits metamagnetic-like behavior at H{sub c}=42 kOe and reaches 0.54 emu/g at H=55 kOe, whereas for the a- and b-axis the magnetization is linear and smaller. The paramagnetic susceptibilities do not follow the Curie-Weiss law suggesting a large van Vleck contribution of the Sm ...
2003-04-01
Magnetic properties of Y_2Cu_2O_5, Y_2BaCuO_5, and Y_2Ba_2O_5 compounds
International Nuclear Information System (INIS)
The magnetic susceptibility of Y_2Cu_2O_5, Y_2BaCuO_5, and Y_2Ba_2O_5 single-phase compounds in weak magnetic fields (H_0=0.1--20 Oe) and moderate magnetic fields (H_0#=#0.2 Oe it converts into a paramagnetic maximum #chi#(T) which corresponds to an antiferromagnetic transition. In a moderate magnetic field H=500 Oe a normal Curie-Weiss law, #chi##approx##mu#"2_e_f_f (T-#theta#) is observed. At temperatures T=150--300 K, #theta#=38 K and #mu#_e_f_f#approx#2.2 #mu#_B/at. Cu. At T<150 k the temperature dependence of #chi# is described by a simple Curie law with #theta##approx#0. Although the paramagnetic signal is extremely weak, in the Y_2Ba_2O_5 compound the curve of #chi#(T, H_0=100 Oe) for a Y_2ba_2O_5 sample exhibits a slightly smeared maximum at a temperature T#approx#13 K.
1989-01-01
Energy Technology Data Exchange (ETDEWEB)
Antitumor platinum(II) complexes derived from N-alkyl-propanediamine differing in the length of their carbon chain (C8, C10, C12 and C14) were incorporated in liposomes and the cytotoxic activity of these formulations was evaluated against tumor (A{sub 549}, MDA-MB-231, B16-F1 and B16-F10) and non-tumor (BHK-21 and CHO) cell lines. Stable and monodisperse liposome suspensions incorporating the platinum complexes were obtained from the lipid composition consisting of distearoyl-sn-glycero-3-phosphocholine, cholesterol and 1,2-distearoyl-sn-glycero- 3-phosphoethanolamine-N-(methoxy(polyethylene glycol)-2000) at 5:3:0.3 molar ratio. The entrapment efficiency (EE%) of the platinum complexes in liposomes increased with the carbon chain length. EE% was higher than 80% in C12- and C14-derivatives. The effect of liposome encapsulation on the cytotoxic activity of the complexes was found to depend on the carbon chain length. These data indicate that the highest drug ...
2010-07-01
Lasing efficiency and tuning range of a dynamic distributed-feedback laser
Energy Technology Data Exchange (ETDEWEB)
The effects of the contrast of the pump field interference pattern, that is, the effectiveness of the dynamic amplitude-phase grid, and various optical arrangements on the lasing efficiency and tuning range of a dynamic distributed-feedback dye laser are investigated. It is shown that the proper choice of prism apex angle, prism material and dye solvent in a laser in the range 400-1000 microns pumped by two beams of different intensity directed through the congruent sides of an isosceles prism in contact with the active medium solution on its third side can lead to optical losses of less than 2% from the boundaries of the prism. Measurements of polymethine dye laser efficiency and tuning range as a function of the relative intensity of the two ruby-laser pump beams reveals that as the contrast of the pump beam interference pattern decreases, the tuning range remains practically constant and the efficiency increases in the nonlinear (saturation) region of the ...
1980-08-01
Interaction of energetic beams with metals and semiconductors - a computational approach
International Nuclear Information System (INIS)
In a vacuum insulator, the narrow electron beam emitted from the cathode impinges on the anode and raises its temperature and also may produce high thermal stress. This high thermal stress, in conjuction with the surface electrostatic pressure may rupture the surface and detach particles from it. In this thesis, the interaction of high energy electron and laser beams with metals and semiconductors is investigated. The differential equations governing the physical processes involved in the interaction are solved by the finite element method. Effects of beam penetration into the material, variable beam reflectance at the surface, finite beam size and dependence of material properties on temperature are accounted for. The two-phase moving boundary problem, also known as the Stefan problem, is solved by an enthalpy formulation of the heat equation. Material deformation by thermal stresses caused by high temperature gradients and electrostatic ...
1984-01-01
Integration of turbo-generator modules in digital transient network analyzer
The behavior of a small power system consisting of two interconnected generators is simulated in real-time by a prototype Digital Transient Network Analyzer (TNA). The prototype Digital TNA consists of two Computational Modules and one I/O Module. The Modules communicate with each other through ribbon cables. Each Computational Module simulates one Turbo-Generator, its Transformer, its Governor, Exciter, and Power System Stabilizer Systems. The numerical integration is shared by two TMS320C30 DSPs at a step-size of 100 microseconds in real-time. The I/O module post-processes the state variables and presents selected information for analog display. The paper presents oscillograms from a test program which includes symmetry checks and behavioral checks against well known waveforms of hunting oscillations, synchronization out-of-phase torques, and subsynchronous resonance phenomena. The success of the Digital TNA depends on: (a) the theoretical ...
1994-05-01
Influence of the Alfven wave spectrum on the scrape-off layer of the TCA tokamak
International Nuclear Information System (INIS)
The study of the scrape-off layer (SOL) during Alfven wave heating may lead to a better understanding of the antenna-plasma interaction. The scrape-off layer of the TCA tokamak has been widely investigated by means of Langmuir probes. The aim of this work is to present measurements on the influence of the Alfven wave spectrum on the scrape-off layer. These experiments have shown that the plasma boundary layer is strongly affected by the wave field, in particular the ion saturation current and the floating potential. In TCA, as the spectrum evolves due to a density rise, the passage of the Alfven continua and their associated eigenmodes, the Discrete Alfven Wave (DAW) induces a strong depletion in the edge density of up to 70% during the continuum part and a density increase during the crossing of an eigenmode. The floating potential becomes negative during the continua and even more negative crossing the eigenmodes. In case of MHD mode activity, this behaviour changes for power ...
1988-05-01
Energy Technology Data Exchange (ETDEWEB)
Silicon nitride based ceramics have attracted considerable attention as good candidates for structural applications due to their excellent mechanical properties including strength, hardness, fracture toughness, and high temperature strength. These properties are strongly influenced by grain size and morphology, and by the degree of crystallinity and chemistry of grain boundary phases. In this work, the microstructure of Si{sub 3}N{sub 4} densified with Nd{sub 2}O{sub 3}, Y{sub 2}O{sub 3} and Al{sub 2}O{sub 3} sintering additives was studied. Sintered samples were polished and plasma etched for microstructural analysis using scanning electron microscope. Quantitative evaluation of materials microstructure was accomplished using Quantikov software. Fracture toughness was measured by Vickers indentation method. The observed microstructure is typical of silicon nitride based materials and is characterized by high aspect ratio.-Si{sub 3}N{sub 4} grains embedded into a ...
2003-07-01
Hydrogen transport behavior of Timetal-21S alloy
International Nuclear Information System (INIS)
Ti-15Mo-2.7Nb-3Al-0.2Si (Timetal-21S), a metastable #beta#-titanium alloy, is a candidate material for titanium matrix composite structures in hydrogen-fueled hypersonic planes because of its excellent formability and adequate mechanical properties in the 500--800 C temperature range. The alloy is strengthened through the precipitation of fine #alpha# particles in the #beta# matrix. The mechanical properties and microstructures are controlled by a solutionizing/aging heat treatment. A major concern in using titanium alloys in hydrogen service is the embrittlement caused by the precipitation of hydrides. It is believed that the large solubility of hydrogen in the #beta#-phase would preclude the precipitation of hydrides in Beta titanium alloys, especially at low hydrogen pressures. However, depending on the hydrogen content, a shift in the ductile/brittle transition temperatures to levels much higher than room temperature has been reported for ...
Hydrogen behavior in the iron surface layer modified by plasma nitriding and ion boronising
Energy Technology Data Exchange (ETDEWEB)
The effects of the plasma nitriding with the formation of compound nitride and diffusion zones and of the boronising with the different ion doses on hydrogen distribution and hydrogen induced deterioration of a surface layer were examined in the case of Armco iron. Electrochemical studies of hydrogen permeation rate, hydrogen vacuum extraction measurements, optical and scanning microscopy, X-ray diffraction and elastic recoil detection analysis (ERDA) were used. Accumulation of entering hydrogen within the various constituent zones of the modified layer inhibits the hydrogen transport into the metal and thus, decreases the mean hydrogen content in the deeper zones and in the core. Hydrogen accumulation within the compact nitride zone causes the expansion of the nitride lattice, nitride phase transformation and deterioration. The ion boronising enhances the hydrogen effects in the plasma nitrided layers. Therefore, modification of the surface layer by plasma ...
2000-12-01
High Magnetic Field NMR Studies of LiVGe$_2$O$_6$, a quasi 1-D Spin $S = 1$ System
We report $^{7}$Li pulsed NMR measurements in polycrystalline and single crystal samples of the quasi one-dimensional S=1 antiferromagnet LiVGe$_2$O$_6$, whose AF transition temperature is $T_{\\text{N}}\\simeq 24.5$ K. The field ($B_0$) and temperature ($T$) ranges covered were 9-44.5 T and 1.7-300 K respectively. The measurements included NMR spectra, the spin-lattice relaxation rate ($T_1^{-1}$), and the spin-phase relaxation rate ($T_2^{-1}$), often as a function of the orientation of the field relative to the crystal axes. The spectra indicate an AF magnetic structure consistent with that obtained from neutron diffraction measurements, but with the moments aligned parallel to the c-axis. The spectra also provide the $T$-dependence of the AF order parameter and show that the transition is either second order or weakly first order. Both the spectra and the $T_1^{-1}$ data show that $B_0$ has at most a small effect on the alignment of the AF ...
2001-01-01
Gauge invariant perturbation theory in spatially homogeneous cosmology
International Nuclear Information System (INIS)
The perturbations of the L.R.S. class A spatially homogeneous spacetimes are treated using Hamiltonian methods in conjunction with techniques from the theory of Lie group harmonic analysis. These latter techniques lead to a simple way of handling any set of tensor equations on these background spacetimes which has the same symmetry group as the space-time metric. Once this approach is developed, the Hamiltonian formulation is used to recover in a clean way the Bonanos equations for the perturbations of the perfect fluid models of the class of spacetimes under consideration. The conserved quantities associated with the four-dimensional symmetry group are evaluated and their role in the linearized Hamiltonian dynamics is discussed. The time-dependent linear canonical transformation of the linearized vacuum gravitational phase space adapted to Moncrief's gauge invariant decomposition is described in general for these models and evaluated ...
International Nuclear Information System (INIS)
In this paper, we present the results of Plasma-Enhanced Chemical Vapor Deposition gate-oxide (SiO_2) integrity on ELC (excimer-laser-crystallized), MILC (metal-induced lateral-crystallized) and SPC (solid-phase-crystallized) polysilicon films. We observed that gate oxide strength of poly-Si TFT strongly depends on the crystallization method for the active silicon layer. In the case of ELC films, asperities on the silicon surface reduce the SiO_2 breakdown field significantly. The metallic contaminants in MILC films are responsible for a deleterious impact on gate oxide integrity. Among the three cases, the SiO_2 breakdown field was the highest for the SPC silicon films. The breakdown fields at the 50 % failure points in Weibull plots for the ELC, MILC and SPC cases were 5.1 MV/cm, 6.2 MV/cm, and 8.1 MV/cm, respectively. We conclude that the roughness and metallic contamination of the poly-Si films are the main factors that cause enhanced ...
2006-01-01
Energy Technology Data Exchange (ETDEWEB)
We report here a study of the mechanisms leading to loss of growth control in chicken embryo fibroblasts transformed by Rous sarcoma virus (RSV). We have been particularly concerned with the role of the src gene in this process, and have used RSV mutants temperature sensitive (ts) for transformation to investigate the nature of the growth regulatory lesion. The two principal findings were (1) the stationary phase of the cell cycle (G{sub 1}) in chick embryo fibroblasts seems to have two distinct regulatory compartments (using the terminology of Brooks et al. we refer to these as 'Q' and 'A' states). When rendered stationary at 41.5 C by serum deprivation, normal cells enter a Q state, but cells infected with the ts-mutant occupy an A state. (2) Whereas normal cells can occupy either state depending on culture conditions, the ts-infected cells, at 41.5 C, do not seem to enter Q even though a known src gene ...
1980-07-01
Energy Technology Data Exchange (ETDEWEB)
In order to establish coal NOx preventive measures, discussions were given on formation of N2 in the fixed-bed pyrolysis of low rank coals and the mechanisms thereof. Chinese ZN coal and German RB coal were used for the discussions. Both coals do not produce N2 at 600{degree}C, and the main product is volatile nitrogen. Conversion into N2 does not depend on heating rates, but increases linearly with increasing temperature, and reaches 65% to 70% at 1200{degree}C. In contrast, char nitrogen decreases linearly with the temperature. More specifically, these phenomena suggest that the char nitrogen or its precursor is the major supply source of N2. When mineral substances are removed by using hydrochloric acid, their catalytic action is lost, and conversion into N2 decreases remarkably. Iron existing in ion-exchanged condition in low-rank coal is reduced and finely diffused into metallic iron particles. The particles react with heterocyclic nitrogen compounds and turn ...
1996-10-28
First detection of polarized scattered light from an exoplanetary atmosphere
We report the first direct detection of an exoplanet in polarized scattered light. The transiting planet HD189733b is one of the very hot Jupiters with shortest periods and, thus, smallest orbits, which makes them ideal candidates for polarimetric detections. We obtained polarimetric measurements of HD189733 in the $B$ band well distributed over the orbital period and detected two polarization maxima near planetary elongations with the peak amplitude of $\\sim2\\cdot10^{-4}$. Assuming Rayleigh scattering, we estimated the effective size of the scattering atmosphere (Lambert sphere) to be 1.5$\\pm$0.2 $R_{\\rm J}$, which is 30% larger than the radius of the opaque body previously inferred from transits. If the scattering matter fills the planetary Roche lobe, the lower limit of the geometrical albedo can be estimated as 0.14. The phase dependence of polarization indicates that the planetary orbit is oriented almost in the north-south direction ...
2007-01-01
Energy Technology Data Exchange (ETDEWEB)
This report concerns investigations in the title conducted by 8 groups of National Institute of Radiological Sciences (NIRS) during the period of 1998-2000. The groups are for investigation of: Effects of p53 tumor suppressor gene in radiation-induced leukemia, Role of atm-gene in dose rate effect of ionizing radiation, Function of DNA-dependent protein kinase catalytic subunit (DNA-PK{sub cs}), Functional complementation of radiation-sensitive mutant M10 cell line by human XRCC4 cDNA expression, Role of radiation-induced apoptosis in digital defects in embryonic mice, Functional analysis of S-phase specific novel nuclear protein NP95 by gene targeting, Role of chemokine in T cell development and lymphomagenesis, and establishment of production techniques of gene-modified mice using embryonic stem cells for genetic analysis of radiation-sensitive genes. The groups describe summaries of their studies and published original articles are also ...
2002-03-01
Extension of QMD to the relativistic region and the calculation of proton induced reactions
Energy Technology Data Exchange (ETDEWEB)
When quantum molecular dynamics (QMD) is applied to the nuclear reactions in theory of relativity region, a number of problems arise, and in order to solve them, the prescription of the extension of ordinary nonrelativistic QMD is introduced, and the analysis of proton incidence reaction by using it is shown. By introducing the interaction corresponding to Lorentz transformation, the problems were solved. QMD is the semiclassical simulation that treats the motion of nucleons represented by Gauss wave packet. The motion of wave packet center is expressed by Newton equations and two-nucleon collision. The introduction of the interaction corresponding to Lorentz transformation is explained. As the result of the introduction, through the relative distance of two particles, the interaction becomes to depend on momentum. The phase distribution function of one body corresponding to Lorentz transformation is used for calculating the final state Pauli ...
1995-06-01
The aim of present study was to evaluate antioxidant property of Glycyrrhiza glabra root extracts using in vitro models. The dose-dependent aqueous and ethanolic extracts demonstrated the scavenging activity against nitric oxide (concentration that caused 50% inhibition of nitric oxide radicals [IC(50)]=72 and 62.1 microg/ml, respectively), superoxide (IC(50)=64.2 and 38.4 microg/ml, respectively), hydroxyl (IC(50)=81.9 and 63 microg/ml, respectively), DPPH (IC(50)=43.6 and 28.3 microg/ml, respectively) and ABTS(*+) (IC(50)=77.3 and 57.2 microg/ml, respectively) radicals. Further, both extracts showed strong reducing power and iron-chelating capacities. In the Fe(2+)/ascorbate system, both extracts were found to inhibit mitochondrial fraction lipid peroxidation. In copper-catalyzed human serum and low-density lipoprotein oxidation models, both extracts significantly (P<0.05) lengthened the lag phase along with a decline in the oxidation ...
2009-04-22
Energy Technology Data Exchange (ETDEWEB)
The leakage current behaviors of PLZT capacitors with top electrodes of Pt, Ir, and IrO{sub 2} are investigated before and after hydrogen forming gas anneal. The P-E hysteresis and fatigue properties of Pt/PLZT/Pt capacitors are almost recovered after recovery anneal in O{sub 2} ambient. The leakage current mechanisms of PLZT capacitors with Pt and IrO{sub 2} top electrodes are consistent with space-charge influenced injection model showing the strong time dependence irrespective of annealing conditions. On the other hand, the leakage current behavior of Ir/PLZT/Pt capacitor shows steady state independent of time because IrPb, conducting phase, formed at interface between Ir top and PLZT is a high conduction path. Teh leakage current mechanism of Ir/PLZT/Pt capacitor is consistent with Schottky barrier model. (author). 15 refs., 6 figs.
2001-02-01
EVOLUTION OF MASSIVE STARS WITH PULSATION-DRIVEN SUPERWINDS DURING THE RED SUPERGIANT PHASE
International Nuclear Information System (INIS)
Pulsations driven by partial ionization of hydrogen in the envelope are often considered important for driving winds from red supergiants (RSGs). In particular, it has been suggested by some authors that the pulsation growth rate in an RSG can be high enough to trigger an unusually strong wind (or a superwind), when the luminosity-to-mass ratio becomes sufficiently large. Using both hydrostatic and hydrodynamic stellar evolution models with initial masses ranging from 15 to 40 M_s_u_n, we investigate (1) how the pulsation growth rate depends on the global parameters of supergiant stars and (2) what would be the consequences of a pulsation-driven superwind, if it occurred, for the late stages of massive star evolution. We suggest that such a superwind history would be marked by a runaway increase, followed by a sudden decrease, of the wind's mass-loss rate. The impact on the late evolution of massive stars would be substantial, with stars losing a huge fraction of ...
2010-07-01
Diagnosis for the cancer extension of cholangiocarcinoma. The current status
International Nuclear Information System (INIS)
Described is the diagnosis for the cancer extension of cholangiocarcinoma by various imaging techniques and processes to support the current surgical procedure based on preoperative biliary drainage. The cancer tends to locally extend horizontally and/or vertically and its diagnosis is important for surgical indication. For the indication, multi-detector raw CT (MDCT) and MR cholangio-pancreatography (MRCP) are useful and particularly, the former can give multi-phase (arterial, portal and delayed) images to reconstruct multiplanar (MPR) and CT angiographic 3D images, which have made the previous invasive examinations like angiography and percutaneous transportal contrasting unnecessary. MDCT and MRCP can almost complete the diagnosis of the extension. The operative procedure is decided dependently on the site of the lesion, and of which diagnosis, whether it is hepatic hilar/on upper bile duct or middle/lower ductal, is different. MDCT-MPR and ...
2010-07-01
Energy Technology Data Exchange (ETDEWEB)
Radiographic images generated by the real-time neutron radiography system (RTNR) are analyzed by customized image processing software of the determination of instantaneous void fraction distribution. The cross-sectional averaged axial void fraction profiles and the two-dimensional void fraction profiles are determined simultaneously for each image. Various flow regimes are generated to determine if the RTNR system can accurately predict the void distribution in the radial, axial, and temporal coordinates. The results show the RTNR system correctly determines the void fraction distribution for each flow regime; however, accuracy decreases with decreasing void fraction. For net water thicknesses > 1.0 cm, the accuracy decreases with increasing water thickness due to the extreme sensitivity of thermal neutron interactions with light water. Heavy water is a more suitable fluid than light water for void fraction measurements in large-diameter flow systems.
1995-01-01
Composites in the TiC-TiYTZP system
International Nuclear Information System (INIS)
Ceramic matrix composites in the TiC-Ti, Y-TZP system can be synthesized by the reaction between carbon and the TiO_2-Y_2O_3-ZrO_2 solid solution nanopowder. This method results in the more homogeneous powders than those prepared by the physical mixing of TiC and zirconia s.s. powders. Twelve TiO_2-Y_2O_3-ZrO_2 solid solution nanopowders differing in the proportions of the constituent oxides were prepared by the coprecipitation- calcination route. They were reacted with the pyrolytic carbon evenly distributed within the system. Carbon was introduced by the thermal decomposition of the phenol-formaldehyde resin dissolved in ethyl alcohol and mixed with the zirconia s.s. nanopowder. Reaction was performed in vacuum. Compacts of the composite powders sintered in vacuum give dense materials of evenly distributed TiC inclusions of sizes not surpassing 400 nm. Hardness of such materials was dependent on their chemical and phase composition but was ...
2003-09-25
International Nuclear Information System (INIS)
In this work we investigate an iron oxide thin film grown with atomic layer deposition for a gas sensor application. The objective is to characterize the structural, chemical, and electrical properties of the film, and to demonstrate its gas-sensitivity. The obtained scanning electron microscopy and atomic force microscopy results indicate that the film has a granular structure and that it has grown mainly on the glass substrate leaving the platinum electrodes uncovered. X-ray diffraction results show that iron oxide is in the #alpha#-Fe_2O_3 (hematite) phase. X-ray photoelectron spectra recorded at elevated temperature imply that the surface iron is mainly in the Fe"3"+ state and that oxygen has two chemical states: one corresponding to the lattice oxygen and the other to adsorbed oxygen species. Electric conductivity has an activation energy of 0.3-0.5 eV and almost Ohmic current-voltage dependency. When exposed to O_2 and CO, a typical ...
2008-07-31
Bar strengths in spiral galaxies estimated from 2MASS images
Non-axisymmetric forces are presented for 107 spiral galaxies using the 2 Micron All Sky Survey (2MASS) images. We apply both Cartesian integration and a polar grid integration utilizing a limited number of azimuthal Fourier components of density. We found that bar strength is independent of the method used to evaluate the gravitational potential. However, the polar method is more suitable for weak and noisy images. Bar strength was found to be sensitive to the Hubble-type dependent scale height of the disk, which has been ignored in the previous studies. On the other hand, the method is rather insensitive to the vertical model of the disk, as long as a same vertical dispersion is assumed, or to the boxy/peanut shaped structure, studied in terms of non-constant vertical scale height along the disk. In the near-IR most galaxies in our sample show non-axisymmetric forces in some level, and 40 percent of them have bars in a sense that they have regions with a constant ...
2002-01-01
Antiferromagnetic Kondo lattice: CePdSi{sub 2}
Energy Technology Data Exchange (ETDEWEB)
The compounds CePdSi{sub 2}, CeIrSi{sub 2} and CeRhSn{sub 2} have been synthesized and studied by X-ray diffraction, electrical resistivity and magnetic susceptibility. The magnetic susceptibility of CePdSi{sub 2} exhibits two peaks at 6.8 K and 2.5 K, respectively, indicating two antiferromagnetic phase transitions, while that of CeIrSi{sub 2} shows a broad maximum at 150 K, characteristic of valence fluctuating Ce-compounds. CeRhSn{sub 2} remains paramagnetic down to 5 K. The resistivity of CeIrSi{sub 2} exhibits a T{sup 2} dependence at low temperatures, indicating a Fermi-liquid ground state, while those of CePdSi{sub 2} and CeRhSn{sub 2} shows the presence of Kondo and crystal field effects. (orig.). 5 refs.
1997-02-01
Energy Technology Data Exchange (ETDEWEB)
The computer programme COMMIX-2 describes steady state and transient multidimensional single- and two-phase fluid flows with heat transfer in nuclear reactor components and multicomponent systems. Originally from the Argonne National Laboratory, the code has been further developed at the Kernforschungszentrum Karlsruhe. The original Point-SOR iterative method for the solution of a Poisson-like equation describing the pressure distribution in the fluid as well as the transport of enthalpy and turbulent quantities has been complemented with iterative and direct line- and block-methods. None of the newly implemented methods is original in itself but their implementation into the computer code, which can describe the most general shapes of definition domains, gave a code speed-up by a factor of 2-5, depending on the problem treated. The code capabilities are assessd by the calculation of a benchmark problem involving the numerical simulation of ...
1987-03-01
International Nuclear Information System (INIS)
The computer programme COMMIX-2 describes steady state and transient multidimensional single- and two-phase fluid flows with heat transfer in nuclear reactor components and multicomponent systems. Originally from the Argonne National Laboratory, the code has been further developed at the Kernforschungszentrum Karlsruhe. The original Point-SOR iterative method for the solution of a Poisson-like equation describing the pressure distribution in the fluid as well as the transport of enthalpy and turbulent quantities has been complemented with iterative and direct line- and block-methods. None of the newly implemented methods is original in itself but their implementation into the computer code, which can describe the most general shapes of definition domains, gave a code speed-up by a factor of 2-5, depending on the problem treated. The code capabilities are assessd by the calculation of a benchmark problem involving the numerical simulation of ...
1987-01-01
Relation of the One-Phase Stefan Problem to the Seepage of ...
... Accession Number : ADA079641. Title : Relation of the One-Phase Stefan Problem to the Seepage of Liquids and Electrochemical Machining,. ...
1979-12-01
DARPA DTN Phase 3 Core Engineering Support
This report covers the initial DARPA DTN Phase 3 activities as JPL provided Core Engineering Support
2010-01-01
Enhancement of Heat and Mass Transfer in Mechanically Contstrained Ultra Thin Films
Energy Technology Data Exchange (ETDEWEB)
Oregon State University (OSU) and the Pacific Northwest National Laboratory (PNNL) were funded by the U.S. Department of Energy to conduct research focused on resolving the key technical issues that limited the deployment of efficient and extremely compact microtechnology based heat actuated absorption heat pumps and gas absorbers. Success in demonstrating these technologies will reduce the main barriers to the deployment of a technology that can significantly reduce energy consumption in the building, automotive and industrial sectors while providing a technology that can improve our ability to sequester CO{sub 2}. The proposed research cost $939,477. $539,477 of the proposed amount funded research conducted at OSU while the balance ($400,000) was used at PNNL. The project lasted 42 months and started in April 2001. Recent developments at the Pacific Northwest National Laboratory and Oregon State University suggest that the performance of absorption and desorption systems can be ...
2005-01-01
Critical Currents in A-15 Superconductors
The critical currents of A-15 phase Nb(,3)Sn, V(,3)Si, Nb(,3)Ge, V(,3)Ga, and Nb-Sn with a few at.% Ga and Al(,2)O(,3) have been measured at temperatures up to T(,c) and in magnetic fields up to 8T to study fundamental flux pinning interactions as a function of defect size and density. The samples are electron beam evaporated films typically 2 (mu)m thick. Their particular usefulness for this study is that they span the clean to dirty limits and their normal state resistivity and grain size can be controlled by deposition parameters. The grain boundaries are the defects most responsible for flux pinning. The electron scattering mechanism is based on the local change in the coherence length due to increased conduction electron scattering and is chosen from among several possible mechanisms to calculate the elementary pinning force at a grain boundary. A direct summation of the elementary pinning force of each boundary is compared with the experimental results. ...
1982-01-01
Phase I Report: DARPA Exoskeleton Program
The Defense Advanced Research Projects Agency (DARPA) inaugurated a program addressing research and development for an Exoskeleton for Human Performance Augmentation in FY!2001. A team consisting of Oak Ridge National Laboratory, the prime contractor, AeroVironment, Inc., the Army Research Laboratory, the University of Minnesota, and the Virginia Polytechnic Institute has recently completed an 18-month Phase I effort in support of this DARPA program. The Phase I effort focused on the development and proof-of-concept demonstrations for key enabling technologies, laying the foundation for subsequently building and demonstrating a prototype exoskeleton. The overall approach was driven by the need to optimize energy efficiency while providing a system that augmented the operator in as transparent manner as possible (non-impeding). These needs led to the evolution of two key distinguishing features of this team's approach. The first is the ...
2004-01-21
Yttrium doped La_1_-_xY_xO_0_._9F_0_._1FeAs superconductors: Hall and thermopower studies
International Nuclear Information System (INIS)
The effect of yttrium substitution at the lanthanum site on the superconducting properties of La_1_-_xY_xO_0_._9F_0_._1FeAs ('x' = 0, 0.10, 0.20, 0.30, 0.50 and 0.60) oxypnictides has been studied. Powder X-ray diffraction studies confirm single phases till x = 0.1 beyond which minor amount of Y_2O_3 is observed. The temperature dependence of resistivity measurements confirm the superconducting transition temperature (T_c) of 34.8 (#+-#0.05) K and corresponding Meissner transition at 34.3 K in the 'x' = 0.3 composition which is higher than that reported for the parent phase (LaO_0_._9F_0_._1FeAs (T_c = 28 K)). Further increase in the concentration of yttrium leads to broadening and suppression of the superconducting transition. The value of H_c_2 at zero temperature is estimated to be about 60.5 T. The Seebeck coefficient (S) shows a negative sign indicating that the major contribution to the conductivity is by electrons. ...
2010-06-01
Tomography and Methods of Travel-Time Calculation for Regional Seismic Location
Energy Technology Data Exchange (ETDEWEB)
We are developing a laterally variable velocity model of the crust and upper mantle across Eurasia and North Africa to reduce event location error by improving regional travel-time prediction accuracy. The model includes both P and S velocities and we describe methods to compute travel-times for Pn, Sn, Pg, and Lg phases. For crustal phases Pg and Lg we assume that the waves travel laterally at mid-crustal depths, with added ray segments from the event and station to the mid crustal layer. Our work on Pn and Sn travel-times extends the methods described by Zhao and Xie (1993). With consideration for a continent scale model and application to seismic location, we extend the model parameterization of Zhao and Xie (1993) by allowing the upper-mantle velocity gradient to vary laterally. This extension is needed to accommodate the large variation in gradient that is known to exist across Eurasia and North African. Further, we extend the linear ...
2007-07-02
The role of oxygen diffusion in the release of technetium from reducing cementitious waste forms
Energy Technology Data Exchange (ETDEWEB)
Cementitious materials provide an ideal geochemical environment (e.g., high pH pore fluids and large surface areas for sorption) for immobilizing nuclear waste. The inclusion of reducing agents, such as blast furnace slag (BFS) can immobilize radionuclides by forming of solid sulfide phases. Thermodynamic calculations using the MINTEQ geochemical computer code indicate the elemental sulfur present in BPS reacts with the highly mobile pertechnetate anion (TcO{sub 4}{sup -}) anion to form an insoluble technetium sulfide phase (Tc{sub 2}S{sub 7(s)}). Initially, the waste form very effectively immobilizes technetium. However, as oxygen diffuses into the waste form, an outer zone of oxidized concrete and a shrinking core of reduced intact concrete develops. Oxidation of sulfur in the outer zone results in increased technetium concentrations in the pore fluid because Tc{sub 2}S{sub 7(a)} oxidizes to the mobile TcO{sub 4}{sup -} anion. The TcO{sub ...
1993-12-31
International Nuclear Information System (INIS)
Solid oxide fuel cell (SOFC) is a promising source of power generation in terms of conversion efficiency which is higher than the conventional one, as it is not limited by the Carnot efficiency. Theoretically, the SOFC have an efficiency of the order of 60-80 % but it is limited by the number of active side available for the reaction i.e. TPB (triple phase boundary) at the electrode-electrolyte interface which depends on the particle size of the materials employed during the fabrication of SOFC components (i.e. the method employed during the synthesis). Literally, there are several methods used in the syntheses of oxide materials such as conventional solid-state reaction, co-precipitation, hydrothermal rout, sol-gel and Glycine nitrate process (GNP) but among these GNP found to be effective over the other because of homogeneity, phase purity and smaller particle size of final product. In this work, the Nano-crystalline ...
2010-12-01
Synopsis of moisture monitoring by neutron probe in the unsaturated zone at Area G
Energy Technology Data Exchange (ETDEWEB)
Moisture profiles from neutron probe data provide valuable information in site characterization and to supplement ground water monitoring efforts. The neutron probe precision error (reproducibility) is found to be about 0.2 vol% under in situ field conditions where the slope in moisture content with depth is varying slowly. This error is about 2 times larger near moisture spikes (e.g., at the vapor phase notch), due to the sensitivity of the probe response to vertical position errors on the order of 0.5 inches. Calibrations were performed to correct the downhole probe response to the volumetric moisture content determined on core samples. Calibration is sensitive to borehole diameter and casing type, requiring 3 separate calibration relations for the boreholes surveyed here. Power law fits were used for calibration in this study to assure moisture content results greater than zero. Findings in the boreholes reported here confirm the broad features seen previously ...
1997-12-31
Energy Technology Data Exchange (ETDEWEB)
When liquids are confined in nano-scopic dimensions, their properties differ from the corresponding bulk liquid, due to their reduced dimensionality and surface effects. Phase transition temperatures and pressures are often shifted from the bulk values and new phases can appear due to the strong interactions of the molecules with the confining walls. We have studied the structural and dynamical properties of aromatic liquids such as benzene, toluene, and ortho-terphenyl confined in nano-porous materials, MCM-41 and SBA-15, synthesized and characterized in our laboratory. A non-trivial dependence of the glass transition temperature, T{sub g}, on the pore size and surface treatment of nano-porous materials is confirmed and interpreted as resulting from a competition between the fluid-wall and fluid-fluid intermolecular interactions. An increase of T{sub g} is observed for small pore sizes and attractive surface while T{sub g} ...
2006-11-15
International Nuclear Information System (INIS)
Full text: It was recently-established for hexagonal barium ferrite-industrially important magnetically hard material that refinement of the crystallite dimensions into the nanoscale regime, typically #<=# 10 nm, leads after heat treatment at temperatures 800-1000 deg C to significant coercivity increase of up to 6.5 kOe (#approx#3-4 times) with saturation magnetisation values of 50-55 emu/g (#approx#95% of bulk at room temperature). High-energy mechanochemical processing has been applied to prepare nanostructural (nanocrystalline-amorphous) composites. High resolution electron microscopy studies reveal that the enhancement of the final magnetic properties was due to formation of magnetically noninteracting #approx#l,#mu#m Ba-ferrite particles with 5-10 nm amorphous surface layer - depending on annealing parameters. Similar situation was established also for ball milled strontium ferrite (SrFe_1_2O_1_9) powders where short annealing 4 h at 1000 deg C produced ...
Revisit to the helicity and the generalized self-organization theory
Energy Technology Data Exchange (ETDEWEB)
It is clarified that the so-caned 'helicity conservation law' is never the conservation equation of the helicity K itself', but is merely 'the time change rate equation of K', which is passively and resultantly determined by the mutually independent volume and surface integral terms. It is shown that since the total helicity K can never be conserved in the real experimental systems, the conjecture of the total helicity invariance is not physically available to real magnetized plasmas in an exact sense. The well-known relaxation theory by Dr. J. B. Taylor is clarified to be neither the variational principle nor the energy principle, but be merely a mathematical calculation, using the variational calculus in order to find the minimum magnetic energy solution from the set of solutions having the same value of K. With the use of auto-correlations for physical quantities, it is presented that a novel basic formulation of an extended generalized ...
2000-09-01
Preparation of Mg-#alpha# SiAlON powder by carbothermal reduction-nitridation of talc and halloysite
International Nuclear Information System (INIS)
Carbothermal reduction-nitridation (CRN) of talc (Mg_3(Si_2O_5)_2(OH)_2) and halloysite (Al_2Si_2O_5(OH)_4) clay provides a useful route for preparing low-cost Mg-#alpha# sialon powder. In this study, the chosen molecular ratios of talc to halloysite were 0.1:1, 0.2:1, 1.5:1.0 and 2.0:1. The CRN reaction was conducted at 1450 to 1520 deg C and 2 to 6h holding time using carbon black as a reducing agent in flowing N_2 (gas). The results showed the synthesized powder was composed of #alpha#-sialon, #beta#-sialon and small amounts of SiC, 15R and AlN phases that greatly depended on the ratio of talc to halloysite, the reaction temperature and holding time. The highest content of Mg-#alpha# sialon, as much as 90wt%, was achieved at 1480 deg C for a holding time of 4h at a talc to halloysite ratio of 1.5:1.0. SiC was considered as an intermediate compound. We also discuss the evaporation loss of Mg caused by talc decomposing into MgSiN_2 ...
International Nuclear Information System (INIS)
Novel CdS hollow microspheres have been successfully synthesized via a facile template-free solution-phase reaction from cadmium nitrate and thioacetamide precursors. The morphology of CdS hollow microspheres depends strongly on the ratio between the precursors, cadmium nitrate to thioacetamide ratio. The physical properties of the hollow microspheres have systematically been studied by different characterization methods. The stoichiometry of the hollow microspheres studied by the energy dispersive X-ray diffraction spectroscopy confirmed that the synthesized CdS hollow microspheres are nearly stoichiometric bulk like CdS. The morphology of the hollow microspheres studied by high resolution scanning electron microscopy and transmission electron microscopy observations showed that the CdS hollow microspheres of the size of 2.5 ?m have hollow structure and are constructed by several nanoparticles of the size between 30 and 40 nm. The UV-visible ...
2010-12-15
Oxydehydrogenation of propane to propylene with metal molybdates
Energy Technology Data Exchange (ETDEWEB)
Single and binary metal molybdates of the formula AMoO{sub 4}, where A=Ni, Co, Mg,Mn and/or Zn, were investigated for the oxydehydrogenation of propane to propylene, as well as some ternary molybdates of the formula NiO{sub 0.45}Co{sub 0.45}X{sub 0.066}MoO{sub 4} where X=P, Bi, Fe, Cr, V and Ce. All catalysts were supported on SiO{sub 2} with an active phase/support ratio of 80/20 (wt%). The reaction is catalytic and not a gas phase initiated reaction. It is first order in propane, consistent with the abstraction of the methylene hydrogen being the rate limiting step. Propane conversions and propylene yields vary greatly depending on the metal of the molybdate and surface area of the catalyst. Highest propylene yields (16% at 26.6% propane conversion) are obtained with NiMoO{sub 4}/SiO{sub 2}. Conversion and yield are significantly influenced by the molybdenum content of the compositions. The effect is biggest in the nickel ...
1996-10-01
Magnetic and thermal properties of cubic single-crystal PrCu_4Ag
International Nuclear Information System (INIS)
We succeeded in synthesizing a new cubic intermetallic compound PrCu_4Ag in a fcc structure. Measurements of X-ray diffraction, magnetic susceptibility, magnetization, specific heat, electrical resistivity, thermal expansion, and elastic constants have been performed on single crystals of PrCu_4Ag. A maximum value of #chi#(T) with a corresponding peak in C(T) suggests that an antiferromagnetic phase transition occurs at T_N=2.4 K, where a sudden decrease in #rho#_4_f(T) and a sharp peak in the thermal expansion coefficient #alpha#(T) were observed. Characteristic Curie-type softening was observed in the temperature dependence of the transverse mode for (C_1_1 - C_1_2)/2 and C_4_4 from 70 K down to T_N, which implies that the crystalline electric field (CEF) ground state is the magnetic triplet #GAMMA#_5. The anisotropic properties in M(T,H) and C(T,H) are studied when the external magnetic field is applied in the <100>, <110>, and ...
2010-11-01
Floating zone crystal growth of selected R2PdSi3 ternary silicides
Energy Technology Data Exchange (ETDEWEB)
Substitution of various rare earths R within the class of R2PdSi3 single crystals with hexagonal AlB2-type crystallographic structure reveals the systematic dependence of anisotropic magnetic properties governed by the interplay of crystal-electric field effects and magnetic two-ion interactions. Here we compare the floating zone (FZ) crystal growth with radiation heating of compounds with R = Tb, Tm, Pr, and Gd. The congruent melting behavior enabled moderate growth velocities of 3 to 5 mmh-1. The preferred growth directions are close to the basal plane of the hexagonal unit cell. The composition of the crystals, except of Tb2PdSi3, is slightly Pd-depleted with respect to the nominal composition 16.7 at.% Pd. Thin precipitates of RSi secondary phases were detected in the crystal matrix. Their phase fraction can be diminished by growth from Pd-rich melt compositions and annealing treatments. The compounds exhibit ...
2011-06-01
International Nuclear Information System (INIS)
For the intermetallic system CaCdsub(1-x)Tlsub(x), 0 <= x <= 1, the Knight shift Ksub(s) of the Cd-NMR and the Tl-NMR were calculated as a function of x, Ksub(s) = Ksub(s)(x). The theoretical investigations were performed on the basis of relativistic augmented-plane-wave (RAPW) band-structure calculations for the boundary phases CaCd and CaTl respectively, and by using the rigid band model for the ternary phases. The density of states and the matrix elements of the relativistic hyperfine operator for electron states at the Fermi surface were calculated in detail. The obtained values were compared with nonrelativistic calculations. The effect of using different exchange potentials was studied for Ksub(s)(Tl). For the Cd-NMR the relativistic effects enhance the nonrelativistic results by a factor of about 1.4. The theoretical value for the Knight shift is smaller than the experimental one by a factor of 1.13. The band structure for CaTl ...
International Nuclear Information System (INIS)
Metal waste generated from domestic nuclear operation for defense and commercial application has led to a growing stockpile of radioactively contaminated scrap metal, much of which is stainless steel. A significant fraction of this material cannot be efficiently surface decontaminated. The burial of this material would be wasteful and expensive, since long term monitoring would be necessary in order to minimize environmental risk. Much of this waste consists of bulky equipment. In many case, this equipment contains valuable material that may be recycled. The piece of equipment considered frequently also has complex geometries, making extremely difficult, time-consuming and expensive to determine the exact location and level of radioactivity on the internal surfaces. After melting, however, the radioactivity may be precisely determined from samples of each ingot. Moreover, an ingot may be released for restricted or unrestricted reuse, or stored for decay to appropriated limits. Melting ...
2007-05-10
Additives to lower and stabilize the viscosity of pyrolysis oils during storage
Energy Technology Data Exchange (ETDEWEB)
The initial development of additives to stabilize the viscosity of biocrude during long-term storage has produced dramatic results. The additives investigated were ethyl acetate, methyl isobuyl ketone and methanol, acetone, methanol, acetone and methanol, and ethanol. These additives represent three chemical families, which all demonstrated the ability to drastically reduce the aging rate of biocrude, as defined by the increase in viscosity with time. Accelerated aging tests were run at 90{degree}C to screen the additives. The additives not only lowered the initial viscosity at 40{degree}C by half but also reduced the aging rate of a hot gas filtered pyrolysis oil made from hybrid poplar (NREL run 175) by factors of 1-18 compared to the original pure oil. With the best additive, methanol, at a 10 wt% level in the pyrolysis oil, the modified biocrude was still a single-phase liquid and still met the ASTM no. 4 diesel fuel specification for viscosity even after 96 h ...
1997-09-01
Two branches of research are conducted in this thesis. The first deals with nonlinear combustion response as a mechanism for triggering combustion instabilities in solid rocket motors. A nonlinear wave equation is developed to study a wide class of combustion response functions to second-order in fluctuation amplitude. Conditions for triggering are derived from analysis of limit cycles, and regions of triggering are found in parametric space. Introduction of linear cross-coupling and quadratic self-coupling among the acoustic modes appears to be how the nonlinear combustion response produces triggering to a stable limit cycle. Regions of initial conditions corresponding to stable pulses were found, suggesting that stability depends on initial phase angle and harmonic content, as well as the composite amplitude, of the pulse. Also, dependence of nonlinear stability upon system parameters is considered. The second part of ...
1999-01-01
International Nuclear Information System (INIS)
The p75 neurotrophin receptor (p75"N"T"R) is a death receptor which belongs to the tumor necrosis factor receptor super-family of membrane proteins. This study shows that p75"N"T"R retarded cell cycle progression by induced accumulation of cells in G0/G1 and a reduction in the S phase of the cell cycle. The rescue of tumor cells from cell cycle progression by a death domain deleted (#DELTA#DD) dominant-negative antagonist of p75"N"T"R showed that the death domain transduced anti-proliferative activity in a ligand-independent manner. Conversely, addition of NGF ligand rescued retardation of cell cycle progression with commensurate changes in components of the cyclin/cdk holoenzyme complex. In the absence of ligand, p75"N"T"R-dependent cell cycle arrest facilitated an increase in apoptotic nuclear fragmentation of the prostate cancer cells. Apoptosis of p75"N"T"R expressing cells occurred via the intrinsic mitochondrial pathway leading to a ...
2006-03-24
Energy Technology Data Exchange (ETDEWEB)
Using discrete air sampling, values of {delta}{sup 13}C and {delta}{sup 18}O in atmospheric CO{sub 2}, as well as its concentration, were measured in a forest in the central part of the main island of Japan during the period from June 1994 to June 1996 to examine the biospheric contribution to their temporal variations. {delta}{sup 13}C shows a prominent diurnal variation with high values in the daytime and low values in the nighttime, especially during the warm season. {delta}{sup 13}C also vary seasonally, showing a maximum in summer and a minimum in spring. The diurnal and seasonal variations of {delta}{sup 13}C are opposite in phase with those of the CO{sub 2} concentration. The rate of change in {delta}{sup 13}C with respect to the CO{sub 2} concentration is found to be approximately -0.005 per mille/ppmv. This suggests that the diurnal and seasonal variations of the CO{sub 2} concentration are produced primarily by diurnally- and ...
1997-09-01
Energy Technology Data Exchange (ETDEWEB)
In the hypothetical event of a severe accident in a Light Water Reactor, scenarios in which the reactor pressure vessel (RPV) fails and the core melt mixture (called corium) relocates into the reactor cavity, cannot be excluded. The viscosity (in fact, corium rheological behaviour) plays a major role in many phenomena such as core melt down, discharge from reactor pressure vessel, interaction with structural materials (concrete,...) and spreading in a core-catcher. For these reasons, it is important to be able to predict the rheological behaviour of corium melts of different compositions (essentially based on UO{sub 2}, ZrO{sub 2}, Fe{sub x}O{sub y} and Fe for in-vessel scenarios, plus SiO{sub 2} and CaO for ex-vessel scenarios) at temperatures above solidus temperature. In the case of corium-concrete mixtures, the increase of viscosity depends not only on the increase of particles in the melts but also on the increase of the residual liquid ...
1999-09-24
Simulation of dopant diffusion and activation during flash lamp annealing
International Nuclear Information System (INIS)
A set of advanced models implemented into the simulator Sentaurus Process was applied to simulate ultra shallow junction formation by flash lamp annealing (FLA). The full path transient enhanced diffusion model includes equations for small interstitial clusters (I_2, I_3, I_4), #left brace#3 1 1#right brace# defects and dislocation loops. A dopant-point defect clustering model is used for dopant activation simulation. Several cluster types are considered: B_2, B_2I, B_2I_2, B_3I, B_3I_2, B_3I_3 for boron and As_2, As_2V, As_3, As_3V, As_4, As_4V for arsenic. Different point defect and dopant-point defect pair charge states are taken into account to obtain accurate results in the high doping level region. The flux expressions in the three-phase segregation model include a dependence on the doping level and point defect supersaturation. The FLA process was performed at various peak temperatures in a Mattson Millios"T"M fRTP"T"M system. The ...
2008-12-05
Optimal design of perforating completion for gas well
Energy Technology Data Exchange (ETDEWEB)
The productivity characteristics of perforated gas well are investigated for the first time under real conditions considering drilling damage, perforation compacted zone and anisotropy in this paper. A non-linear finite element model for non-Darcy flow in perforated gas reservoir is built to consider the effects of twelve factors on productivity ratio (PR) of perforated gas well. The nomographs for two cases are presented in this paper. Compared with previous works, the following results are found: (1) the effects of drilling damage and perforation diameter on PR of gas well are more remarkable than that in oil well; (2) any perforation phase may be the best or the worst as to perforating gas well, which depends on anisotropy, drawdown and that whether or not perforations are beyond drilling damage zone; (3) the increase in perforation length hardly improve PR of gas well when perforations have been beyond drilling damage zone. The new method ...
1995-10-01
Energy Technology Data Exchange (ETDEWEB)
In cooperation with NRPB, the specifications of the mainframe COSYMA version 95/1 and the PC COSYMA version 2.0 were prepared and the corresponding modifications implemented. Important improvements are dose-rate dependent models for deterministic health effects, the time dependent efficiency of stable iodine tablets, the extension of data bases for the inclusion of activation products, and supplementary evaluation programs. PC COSYMA has been completed by an economics module, further options in the ingestion pathways, and a graphics package for presenting assessment results. COSYMA has been applied for probabilistic dose assessments within paramter studies and special investigations of EPR concepts. RODOS, the real-time on-line decision support system for nuclear emergency management, has been further developed with the aim of the first pilot version 2.0 for pre-operational application in the second half of 1995. At present, some 20 institutes ...
1995-08-01
This study investigated whether estradiol influenced the survival of new granule neurons, independent of altering cell proliferation, in the adult rodent dentate gyrus and whether estradiol-induced changes in new neuron number relate to any observed changes in hippocampus-dependent behavior. To test whether estradiol specifically promotes the survival of new neurons we injected castrated adult male meadow voles with the cell synthesis marker bromodeoxyuridine (BrdU; 50 mg/kg) twice on day 0 and then injected either estradiol (10 microg) or vehicle for 5 consecutive days either over days 1-5, days 6-10 or days 11-15 and perfused them on day 16. Estradiol doubled the number of hippocampal BrdU-labeled neurons but only when administered during a discrete period (days 6-10; P< or =0.01) when most new neurons extend their axons [J Comp Neurol 413 (1999) 146]. To test whether the estradiol-induced increase in new neuron number was related to ...
2004-01-01
Energy Technology Data Exchange (ETDEWEB)
In addition to dependable starting - even at extreme sub-zero temperatures - the starting behaviour of modern commercial vehicle diesel engines is increasingly being evaluated on the basis of HC emissions in the starting and warm-up phases. To improve their performance in this respect, most small and medium-sized diesel engines (with a capacity of 3 to 12 litres) are therefore equipped with intake air heating systems. As an alternative to high-performance, fuel-burning flame start systems, the automotive industry supplier Beru has now developed a new type of self-regulating electric heating element which not only ensures dependable starting with short heating times but also allows drastic reductions in HC emissions. (orig.) [Deutsch] Das Startverhalten moderner Nutzfahrzeug-Dieselmotoren wird, ergaenzend zum Hauptmerkmal des sicheren Starts auch bei extremen Minustemperaturen, zunehmend anhand der HC-Emission in der Start- ...
1997-04-01
Energy Technology Data Exchange (ETDEWEB)
Measurements were completed on the solubility of cupric and cuprous oxides in liquid water and steam at controlled pH conditions from 25 to 400 C (77 to 752 F). The results of this study have been combined with those reported from this laboratory in two previous EPRI reports to provide a complete description of the solubility of these oxides and the speciation of copper dissolved in liquid water and steam as a function of oxidation state, temperature, pH, and in the case of steam, pressure. These constitute the first set of reliable data for cuprous oxide solubility over this range of conditions. For the more intensively studied CuO case, agreement was found between our results and those of previous studies of its solubility in steam, whereas only partial agreement was evident for its solubility in liquid water. For both oxides this disagreement often amounted to orders of magnitude. The solubility of cuprous oxide is somewhat lower than that of CuO at ambient conditions, except as ...
2004-05-01
International Nuclear Information System (INIS)
Doping of manganese (Mn3+/Mn4+) into the Aurivillius phase Pb1-xBi4+xTi4-xMnxO15 was carried out using the molten salt technique for various Mn concentrations (x=0, 0.2, 0.4, 0.6, 0.8, and 1). Single phase samples could be obtained in the composition range with x up to 0.6 as confirmed by X-ray and neutron diffraction analysis. Dielectric measurements show a peak at 801, 803, 813 and 850 K for samples with x=0, 0.2, 0.4, and 0.6, respectively, related to the ferroelectric transition temperature (Tc). The main contribution of the in-plane polarization for x?0.2 which was calculated from the atomic positions obtained by the structure analysis is the dipole moment in the Ti(1)O6 layer; however, for x?0.4 the polarization originates from the dipole moment in the Ti(2)O6 layer. Mn doping in the Pb1-xBi4+xTi4-xMnxO15 does not show any long range magnetic ordering. -- Graphical abstract: The dipole moment of TiO6 dependence of x ...
2011-05-01
Ecological problems of natural gas cleansing
International Nuclear Information System (INIS)
Full text: Chemical-technology approaches allowing to intensification the prevention processes of gas hydrates formation at motion of gas-liquid stream of natural gas in system natural gas well - gas wire have been worked up. Technological regimes of treatment of gas stream have been determined. Linear correlation dependences inhibitor electrolytes contained hydrated ions with different ion radii and charges of subgroups of alkali elements with one - type electron configuration were obtained. Important physico-chemical parameters of electrolytes have been determined: activity; coefficients of activity, viscosity, diffusion; density; heat capacity; heat conductivity; surface tension and freezing-point. The features of continuous influence of inhibitory factors on process of gas flow at low temperatures and relatively high pressure differences ?P have been studied by using of technological installation modulating the system natural gas well - gas wire. The ...
2007-06-01
Scale-up of two-phase flow in heterogeneous chalk. Matrix properties
Energy Technology Data Exchange (ETDEWEB)
This investigation presents scale-up of a detailed heterogeneous geostatistical model to a full field reservoir simulation model, considering both single and two-phase flow properties. The model represents a typical low permeability Danish North Sea chalk reservoir and includes capillary pressure and saturation end-point variations. Two new up-scaling methods has been investigated, all based on fine scale simulation on a cross section of the geomodel. The first methods assumes piston style behaviour and a coupled viscosity is introduced into the basic Darcy`s equations. The second method is a modification of the JBN method traditionally applied in analysing results from core flooding experiments, which emerged as the most successful and therefore also the recommended method. 1. In addition to the up scaling work we review the Equivalent Radius Method for capillary pressure normalisation with explicit derivation of type functions for Maastrichtian and Danian chalk ...
1998-02-01
Metastability of Molecular Phases of Nitrogen: Implications to the Phase Diagram
Energy Technology Data Exchange (ETDEWEB)
Despite their simplicity, diatomic molecules of first row elements can exhibit very complex phase diagrams. Determination of the phase diagrams can be further complicated by the existence of hysteretic molecular phases that can be observed over large regions of coexistence. Here we present evidence for a previously unreported molecular phase of nitrogen existing at room temperature at least over the range of 33-74 GPa. Our measurements show that sample history may have a significant impact on the thermodynamic states accessed by the molecular nitrogen solid and, by extension, also on the established phase diagram.
2001-09-12
Phase Information and the Evolution of Cosmological Density Perturbations
The Fourier transform of cosmological density perturbations can be represented in terms of amplitudes and phases for each Fourier mode. We investigate the phase evolution of these modes using a mixture of analytical and numerical techniques. Using a toy model of one-dimensional perturbations evolving under the Zel'dovich approximation as an initial motivation, we develop a statistic that quantifies the information content of the distribution of phases. Using numerical simulations beginning with more realistic Gaussian random-phase initial conditions, we show that the information content of the phases grows from zero in the initial conditions, first slowly and then rapidly when structures become non-linear. This growth of phase information can be expressed in terms of an effective entropy: Gaussian initial conditions are a maximum entropy realisation of the ...
2000-01-01
International Nuclear Information System (INIS)
The phase space of quantized systems that contain tachyons has been investigated. Interpretation difficulties and unexpected divergences are found when it is considered the volume of Lorentz-invariant phase space. These problems can be overcome, however, at the expense of Lorentz invariance.
Energy Technology Data Exchange (ETDEWEB)
The phase space of quantized systems that contain tachyons has been investigated. Interpretation difficulties and unexpected divergences are found when we consider the volume of Lorentz-invariant phase space. These problems can be overcome, however, at the expense of Lorentz invariance.
1983-12-21
UK PubMed Central (United Kingdom)
cdc18+ of Schizosaccharomyces pombe is a periodically expressed gene that is required for entry into S phase and for the coordination of S phase with mitosis. cdc18+ is related to the Saccharomyces...Full Text Available
1995-12-19
International Nuclear Information System (INIS)
French English ... Orig. Title Imagerie IRM des lesions focales hepatiques avec les antennes de surface en reseau phase (phased array): apnee ou imagerie haute resolution?.
1995-10-26
Phase 2 of the four phase NASA/DoD Aerospace Knowledge Diffusion Research Project was undertaken to study the transfer of scientific and technical information (STI) from government to the aerospace industry and the role of librarians and technical informa...
1991-01-01
Chaotic system of two-phase flow in a small, horizontal, rectangular channel.
Various measurement tools that are used in chaos theory were applied to analyze two-phase pressure signals with the objective of identifying and interpreting flow pattern transitions for two-phase flows in a small, horizontal rectangular channel. These me...
1995-01-01
Amorphous to crystalline phase transformation in Metglas reg-sign studied by Moessbauer spectroscopy
International Nuclear Information System (INIS)
The authors present differential scanning calorimetry (DSC) and in situ Moessbauer spectroscopy results for Metglas ribbons, to which different heat treatments were made. The Curie temperature of the amorphous phase is determined and the evolution of the magnetic field of this phase is studied as a function of temperature
1997-12-01
A comparison of iterative algorithms and a mixed approach for in-line x-ray phase retrieval
UK PubMed Central (United Kingdom)
Previous studies have shown that iterative in-line x-ray phase retrieval algorithms may have higher precision than direct retrieval algorithms. This communication compares three iterative phase...Full Text Available
2009-08-15
Energy Technology Data Exchange (ETDEWEB)
Effects associated with the temperature dependence of the level density parameter, a(T), are investigated in connection with neutron evaporation processes. Different approximations, for this temperature dependence, are compared for the case of neutron emission from the compound nucleus /sup 209/Pb.
1987-07-01
UK PubMed Central (United Kingdom)
IntroductionThe objective of this study was to examine age-, hormone-, and sex-dependent differences to the behavioral effects of nicotine using place-conditioning...Full Text Available
2009-10-01
International Nuclear Information System (INIS)
The heating history of a droplet during its flight can be divided into two phases: (a) the initial phase when evaporation, although it occurs, does not change the heat balance of the droplet much (the case considered in our previous paper and (b) the final phase when the cooling due to evaporation balances the heat flux from the plasma. The later phase is considered in Chen's comment. In our reply, a very straightforward consideration demonstrates that even in the final phase of the droplet flight, the 'rocket' effect can be significant. (reply)
2007-07-07
On Phase Transition of Compressed Sensing in the Complex Domain
The phase transition is a performance measure of the sparsity-undersampling tradeoff in compressed sensing (CS). This letter reports, for the first time, the existence of an exact phase transition for the $\\ell_1$ minimization approach to the complex valued CS problem. This discovery is not only a complementary result to the known phase transition of the real valued CS but also shows considerable superiority of the phase transition of complex valued CS over that of the real valued CS. The results are obtained by extending the recently developed ONE-L1 algorithms to complex valued CS and applying their optimal and iterative solutions to empirically evaluate the phase transition.
2011-01-01
The early phase change Gene in Maize
UK PubMed Central (United Kingdom)
Recessive mutations of the early phase change (epc) gene in maize affect several aspects of plant development. These mutations were identified initially because of...Full Text Available
2002-01-01
British Library Electronic Table of Contents (United Kingdom)
We investigated phase transition of ilmenite-type AgSbO3 to pyrochlore by post-heat treatment and the synergy effect of the mixed phases of AgSbO3 on the photocatalytic activities to enhance the activities. The AgSbO3 with an ilmenite structure was prepared by a cation-exchange method. Phase transition from the ilmenite to pyrochlore occurred by proper control of post-heat treatment. The sample that was obtained by post-heat treatment of ilmenite-type AgSbO3 at 660^oC for 3h consisted of both of the ilmenite and pyrochlore phases, and the sample at 685^oC for 4h mainly consisted of the pyrochlore phase. Together with an increase in the ratio of the pyrochlore phase, the optical absorption spectra blue-shifted. The band gaps of single phases of the ilmenite and the pyrochlore were 2.4 and 2...
2010-01-01
STUDY OF METEOR WIND MEASUREMENT TECHNIQUES. ...
... of a secondary standard (VCO) locally available. ... phase of the local secondary standards to the 10-min average of the phase of ... I3a - - \\.-e-~--. ...
1970-02-01
Quantitative Spectroscopy of Photospheric-Phase Type II SN
... and high-quality photospheric-phase Type II SN spectra to constrain core- collapse SN explosions, massive star evolution, and distances in the Universe ...
Energy Technology Data Exchange (ETDEWEB)
The aim of this paper is to present the phase-space properties of the systems that contain bradyons, luxons and tachyons. It is shown that particularly at low energy, these properties are quite different from the well-known properties of bradyons.
1983-03-12
Phase formation sequence in the Pd-GaAs system
Energy Technology Data Exchange (ETDEWEB)
The morphological aspects of ternary phase formation during the Pd-GaAs reaction have been studied by application of transmission electron microscopy (TEM) and Rutherford backscattering (RBS) techniques. The TEM images show that the first product phase, ''phase I'', forms during deposition of Pd onto (100) GaAs and exhibits the preferred orientation (0001)/sub I/ approx. // (01 anti 1)/sub GaAs/. In the presence of unreacted Pd, the second phase, ''phase II'', nucleates at large-angle grain boundaries in the phase I film as the annealing temperature increases above approx.250C. Energy dispersive analysis of x-rays and RBS suggest the nominal compositions Pd3GaAs and Pd4GaAs for phases I and II, respectively.
1985-12-01
George C. - NASA Technical Reports Server
Indicated inertial navigation error and required update frequency. phasing, and times). Docking Phase. Range; range rate. Clock angle; clock angle rate ...
Flood Plain Information. Kenai River, Phase I. Kenai ...
... Accession Number : ADA067692. Title : Flood Plain Information. Kenai River, Phase I. Kenai Peninsula Borough, Alaska. ...
1973-06-01
International Nuclear Information System (INIS)
... structure crystal-phase transformations fluorescence fluorescence spectroscopy
2011-02-22
International Nuclear Information System (INIS)
... 5. Formation of the annular two-phase flow regime, with a wavy film on the
1974-01-01
Anesthetic stimulation of insect water receptors.
UK PubMed Central (United Kingdom)
Halothane, chloroform, and carbon tetrachloride, in the vapor and liquid phases, stimulate the water receptor of the blowfly Phormia regina. There are three successive phases of response to long-lasting...Full Text Available
1976-09-01
On the A-dependence of the nuclear structure functions
International Nuclear Information System (INIS)
The A-dependence of the nuclear structure functions is described rather well within the framework of the quark-parton-flucton model of nucleus. 16 refs. (author).
Kinetic energy dependence of the reactions of N"+ ions with NO, CO, CO_2, N_2O and SO_2
International Nuclear Information System (INIS)
... kinetics chemical reactions energy dependence ion-molecule collisions milli
1977-07-01
Children of men with alcohol dependence: Psychopathology, neurodevelopment and family environment
UK PubMed Central (United Kingdom)
Background:Children of people with alcohol dependence (COAs) are at high risk for behavioral and cognitive problems.Aim:Aim of...Full Text Available
2010-10-01
Management of fire and industrial safety - challenges during commissioning of a NPP
International Nuclear Information System (INIS)
Construction and commissioning period of NPP are reduced world over drastically by stringent schedule for financial and economic reasons. For meeting the schedule, commissioning of components and systems are started immediate after installation, while construction activities are continued in parallel at the same place. Parallel activities' and 'Time Constraint' have brought new challenges to 'Management of Fire and Industrial Safely' during commissioning. An innovative approach was used during such phase of commissioning of TAPP-3 and 4. This paper outlines challenges encountered during this phase and special approach and measures used to meet those challenges. This paper also outlines problems encountered during implementation of these measures and subsequent change in approach to ensure smooth and safe execution of activities. Primarily, challenges were conflicting requirements by various agencies to carryout commissioning in parallel with ...
2006-11-13
Energy Technology Data Exchange (ETDEWEB)
We present the first 3.8 {micro}m image of the dusty ring surrounding the young binary system GG Tau, obtained with the W. M. Keck II 10m telescope's adaptive optics system. THis is the longest wavelength at which the ring has been detected in scattered light so far, allowing a multi-wavelength analysis of the scattering proiperties of the dust grains present in this protoplanetary disk in combination with previous, shorter wavelengths, HST images. We find that the scattering phase function of the dust grains in the disk is only weakly dependent on the wavelength. This is inconsistent with dust models inferred from observations of the interstellar medium or dense molecular clouds. In particular, the strongly forward-throwing scattering phase function observed at 3.8 {micro}m implies a significant increase in the population of large ({approx}> 1 {micro}m) grains, which provides direct evidence for grain ...
2004-02-04
Energy Technology Data Exchange (ETDEWEB)
1. Cyanide degradation: Of the cyanide- and thiocyanate-degrading bacteria, Burkholderia cepacia and Pseudomonas spec. were the most effective. 2. Biosorption: Of the isolates suited for biosorption of heavy metals, 597-A (non-identifiable) and 597-A2 (Aspergillus fumigatis) had the biggest potential. The sorption capacity of the fungi for metals varied with the C source used for their growth: apple juice > molasses > glucose. The fungi are not cyanide-sensitive and can even degrade cyanide. Living biomass had better metal sorption efficiencies than dead mycelium. The biosorption rates in waste water were usually higher than in broth. Depending on the metal composition and concentrations and on the exposure time and volume of the mycelia, up to 85 % of the initial concentration was removed from the liquid phase. The capacity of different biomasses for the sorption of metal mixtures was between 65 and 80 mg/g of dry matter ...
1999-12-01
Basic research on cermet nuclear fuel
Energy Technology Data Exchange (ETDEWEB)
Production of cermet nuclear fuel having fine uranium dioxide (UO{sub 2}) particles dispersed in matrix metal requires basic property data on the compatibility of matrix metal with fission product compounds. It is thermodynamically suggested that, as burnup increases, cesium in oxide fuel reacts with the fuel, other fission products or cladding pipe and produces cesium uranates, cesium molybdate, or cesium chromate in stainless steel cladding pipe. Attempt was made to measure the thermal expansion coefficient and thermal conductivity of cesium uranates (Cs{sub 2}UO{sub 4} and Cs{sub 2}U{sub 2}O{sub 7}), cesium molybdate (Cs{sub 2}MoO{sub 4}) and cesium chromate (Cs{sub 2}CrO{sub 4}). Thermal expansion was measured by X-ray diffraction and determined by Cohen`s method. Thermal conductivity was obtained by measuring thermal diffusion by laser flash method. The thermal expansion of Cs{sub 2}UO{sub 4} and Cs{sub 2}U{sub 2}O{sub 7} is as low as 1.2% for the former and 1.0% for the latter, ...
1998-01-01
Energy Technology Data Exchange (ETDEWEB)
The quantitative measurement of carbon concentration-distance curves serves as fundamental prerequisite for the evaluation of rim zone properties connected with decarburisation processes in material science. This was shown in part 1 of the present work with two samples from through-hardenable rolling bearing steel 100Cr6 (SAE 52100) austenitised in different oxidising atmospheres by position dependent determination of hardness, residual stresses, and X-ray line broadening ({l_brace}211{r_brace} {alpha}'-Fe diffraction line). In practice, it is important to predict carbon concentration-distance curves under prevailing heat treatment conditions or to conclude conversely from profile measurements. Based on a refined kinetics model of a diffusion-controlled process, part 2 therefore presents a simulation tool developed by means of the finite element method (FEM). Apart from the concentration dependence of the diffusion coefficient, it also ...
2003-08-01
Breaking the Biological barriers to Cellulosic Ethanol: A Joint Research Agenda
Energy Technology Data Exchange (ETDEWEB)
A robust fusion of the agricultural, industrial biotechnology, and energy industries can create a new strategic national capability for energy independence and climate protection. In his State of the Union Address (Bush 2006), President George W. Bush outlined the Advanced Energy Initiative, which seeks to reduce our national dependence on imported oil by accelerating the development of domestic, renewable alternatives to gasoline and diesel fuels. The president has set a national goal of developing cleaner, cheaper, and more reliable alternative energy sources to substantially replace oil imports in the coming years. Fuels derived from cellulosic biomass - the fibrous, woody, and generally inedible portions of plant matter - offer one such alternative to conventional energy sources that can dramatically impact national economic growth, national energy security, and environmental goals. Cellulosic biomass is an attractive energy feedstock because it is an abundant, ...
2006-06-01
Visualization of liquid metal two-phase flow by a real time neutron radiography system
Energy Technology Data Exchange (ETDEWEB)
In order to understand the detail transient two-phase flow structure, more advanced two-phase flow instrumentation is required. One advanced technique for flow visualization is real-time neutron radiography. Reconstruction method of visualized radiographic image of liquid metal two-phase flow generated by the real-time neutron radiography system is proposed in this paper. Image processing techniques for noise reduction and image enhancement are discussed in detail. (author).
1995-11-01
Visualization of liquid metal two-phase flow by a real time neutron radiography system
International Nuclear Information System (INIS)
In order to understand the detail transient two-phase flow structure, more advanced two-phase flow instrumentation is required. One advanced technique for flow visualization is real-time neutron radiography. Reconstruction method of visualized radiographic image of liquid metal two-phase flow generated by the real-time neutron radiography system is proposed in this paper. Image processing techniques for noise reduction and image enhancement are discussed in detail. (author).
1995-01-01
Through Weld Inspection of Wrought Stainless Steel Piping Using Phased Arrays
Energy Technology Data Exchange (ETDEWEB)
Outline: Discuss far-side weld problem and phased array techniques applied. Describe laboratory work on flawed piping specimens using L- and S-wave arrays and provide synopsis of results. Discuss conclusions ofr capability of phased array as applied to austenitic welds. Research Approach: Evaluate phased arrays on unifornly-welded piping specimens. Apply best methods to non-uniform welds. Correlate acoustic responses as function of weld microstructures.
2004-12-31
The electrical measurement of AC losses in a three-phase tri-axial superconducting cable
International Nuclear Information System (INIS)
In a three-phase tri-axial cable, the magnetic interaction between the phases makes the loss measurement by an electromagnetic method very complex. We developed the theoretical background showing that three-phase AC loss measurements by the electromagnetic method are, in principle, possible. We then implemented this theory in practical measurements on a 3 m long, tri-axial cable fabricated from RABiTS (rolling-assisted biaxially textured substrate) coated conductor. Initially, the proposed measurement technique was implemented in the simpler cases when the three cable phases are 180"0 out of phase, i.e. (0"0, 180"0, 360"0) or (0"0, 360"0, 180"0) rather than (0"0, 120"0, 240"0) as in a traditional three-phase system. For these cases, the currents in the phases are either in phase (360"0 phase ...
2010-09-01
Magnetic phase transition in UPd_2Si_2
International Nuclear Information System (INIS)
... fields magnetic moments neel temperature neutron diffraction order-disorder
Discrete phase retrieval in musical structures
British Library Electronic Table of Contents (United Kingdom)
This paper describes phase-retrieval approaches in music by focusing on the particular case of the cyclic groups (beltway problem). After presenting some old and new results on phase retrieval, we introduce the extended phase retrieval for a generalized musical Z-relation. This concept is accompanied by mathematical definitions and motivations from computer-aided composition. We assume from the reader basic knowledge of groups, topological groups, group algebras, group actions, Lebesgue integration, convolution products, and Fourier transform.
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
In the third quarterly report adsorption of heavy metals ions such as Cu(II) and Cr(VI) onto soils drawn from the laboratory-type wetland was shown to be weak. Secondly, it was shown that modified-clays did adsorb Cr(VI) ions strongly at pH 4.5. Further, studies on the pH dependence of the adsorption of {beta}-naphthoic acid, (NA), a well-documented contaminant in many oil and gas well waste waters onto modified-clays were undertaken and it was shown that uptake of NA by modified-clays was of the high affinity type at pH 4.5 and 7.0, but weak at pH 9.0. Adsorption of heavy metal ions, Cu{sup 2+}, and Cr(VI) onto algae, a proposed wetland amendment, was carried out and the results were presented and discussed in the fourth quarterly report. Uptake of NA by the soil component of the laboratory-type wetland was monitored as a function of pH. This quarterly report presents results from studies on the uptake of phenol and {beta}-naphthoic acid by laboratory-type ...
1993-10-04
Energy Technology Data Exchange (ETDEWEB)
The integrity of a pipeline system is determined by its weakest links which may be the joints. Heat fusion is the most common method for joining gas distribution polyethylene (PE) piping. There are procedural, thermal, and mechanical aspects of making fusion joints. Acceptable procedural aspects, such as heater calibration and cleanliness, can be assured by rigorous training and certification of the operators. Thermal and mechanical aspects consist of specifying joining conditions such as the heater temperature, heating time, and joining pressure. In the absence of procedural errors, the strength of a fusion joint should depend on the pipe material, pipe dimensions, and the thermal and mechanical joining conditions. Socket heat fusion was studied both experimentally and analytically to determine how the strength of the joint varied with the conditions under which it was made. The standard tensile impact test was modified to test socket fusion joint samples in ...
1991-03-01
Theoretical analysis of strain-induced shape changes in cubic precipitates during coarsening
Energy Technology Data Exchange (ETDEWEB)
The work reported here concerns the evolution of the shape of a coherent, cubic precipitate as it grows by coarsening. The work was motivated by the need to explain recent experimental observations that show that cuboidal ..gamma.. Ni/sub 3/Al precipitates in Ni-Al alloys resist coarsening and decompose into doublets of parallel rectangular plates and octets of small cubes. The theoretical model assumes a precipitate of cubic phase with negative elastic anisotropy, and neglects any difference between the elastic constants of the precipitate and the matrix. The elastic energy of the precipitate is then calculated as a function of its morphology, including the possibility of decomposition into doublets or octets of discrete particles. The results show that a cuboidal precipitate with (100) faces and edge length, 2a, is metastable with respect to transition to a doublet of discrete plates, with dimensions a x 2a x 2a, that are separated by the distance ..mu.. - a, ...
1988-06-01
The importance of sodium plume behaviour in the natural convection cooling of fast reactors
International Nuclear Information System (INIS)
This paper relates to a simple approach to the analysis of the behaviour of pool type LMFBR primary circuits in natural convection and to experimental work to support this approach. The primary application is the prediction of plant behaviour in decay heat removal conditions when depending on natural convection effects to cool the core. In formulating a mathematical model of the plant for this application, the main difficulty is the modelling of the large plena between the core and IHX and the IHX and the pump inlet. In a previous paper discussing CDFR behaviour after a reactor scram with total loss of power to the primary pumps, the first author described attempts to model the CDFR hot pool in a way which would be limiting in a pessimistic sense. The shortcomings of these attempts were reviewed and mention was made of an improved method then under development. Essentially, the improved model allowed for migration of hot sodium from the core to the top of the hot ...
The free electron laser klystron amplifier concept
International Nuclear Information System (INIS)
The simplest high gain free electron laser (FEL) amplifier concept is proposed. A klystron amplifier has the useful property that the various electronic processes take place in separate portions of the amplifier, rather than overlapping as in FEL amplifier with an uniform undulator. The klystron consists of two fundamental parts: succession of 2-3 cascades (modulator), and an output undulator (radiator) in which the modulated electron beam coherently radiates. Each cascade consists of uniform undulator and dispersion section. Unlike distributed optical klystrons, we have a high gain per cascade pass. This has a few consequences. First, klystron gain does not depend on the bunch compression in the injector linac, i.e. maximum gain per cascade pass at high peak beam current is the same at low peak beam current, without compression. Conventional, short-wavelength FEL amplifier and distributed optical klystron require electron beam peak current of a few kA. Second, ...
Energy Technology Data Exchange (ETDEWEB)
Small unilamellar vesicles which form when gel-state long-chain phosphatidylcholines are mixed with micellar short-chain lecithins undergo an increase in size as the long-chain species melts to its liquid-crystalline form. Analysis of the vesicle population with quasi-elastic light scattering shows that the particle size increases from 90-A radius to greater than 5000-A radius. Resonance energy transfer experiments show total mixing of lipid probes with unlabeled vesicles only when the Tm of the long-chain phosphatidylcholine is exceeded. This implies that the large size change represents a fusion process. Aqueous compartments are also mixed during this transition. 31P NMR analysis of the vesicle mixtures above the phase transition shows a great degree of heterogeneity with large unilamellar particles coexisting with oligo- and multilamellar structures. Upon cooling the vesicles below the Tm, the original size distribution (e.g., small unilamellar vesicles) is ...
1989-10-03
Energy Technology Data Exchange (ETDEWEB)
The integrity of a pipeline system is determined by its weakest links which may be the joints. Heat fusion is the most common method for joining gas distribution polyethylene (PE) piping. There are procedural, thermal, and mechanical aspects of making fusion joints. Acceptable procedural aspects, such as heater calibration and cleanliness, can be assured by rigorous training and certification of the operators. Thermal and mechanical aspects consist of specifying joining conditions such as the heater temperature, heating time, and joining pressure. In the absence of procedural errors, the strength of a fusion joint should depend on the pipe material, pipe dimensions, and the thermal and mechanical joining conditions. Socket heat fusion was studied both experimentally and analytically to determine how the strength of the joint varied with the conditions under which it was made. The standard tensile impact test was modified to test socket fusion joint samples in ...
1991-03-01
As a result of the large limestone deposits available in Poland, the low cost of reagent acquisition for the largescale technological use and relatively well-documented processes of flue gas desulfurization (FGD) technologies based on limestone sorbent slurry, wet scrubbing desulfurization is a method of choice in Poland for flue gas treatment in energy production facilities, including power plants and industrial systems. The efficiency of FGD using the above method depends on several technological and kinetic parameters, particularly on the pH value of the sorbent (i.e., ground limestone suspended in water). Consequently, many studies in Poland and abroad address the impact of various parameters on the pH value of the sorbent suspension, such as the average diameter of sorbent particles (related to the limestone pulverization degree), sorbent quality (in terms of pure calcium carbonate [CaCO3] content of the sorbent material), stoichiometric surfeit of CaCO3 in ...
2010-08-01
International Nuclear Information System (INIS)
Rats or mice acutely exposed to high concentrations of ozone show an immediate and significant weight loss, even when allowed free access to food and water. The mechanisms underlying this systemic response to ozone have not been previously elucidated. We have applied the technique of global gene expression analysis to the livers of C57BL mice acutely exposed to ozone. Mice lost up to 14% of their original body weight, with a 42% decrease in total food consumption. We previously had found significant up-regulation of genes encoding proliferative enzymes, proteins related to acute phase reactions and cytoskeletal functions, and other biomarkers of a cachexia-like inflammatory state in lungs of mice exposed to ozone. These results are consistent with a general up-regulation of different gene families responsive to NF-#kappa#B in the lungs of the exposed mice. In the present study, we observed significant down-regulation of different families of mRNAs in the livers of ...
2005-10-15
Structure and property relationship in the mixed-conducting Sr-Fe-Co-O system.
Energy Technology Data Exchange (ETDEWEB)
Mixed-conducting ceramic oxides have potential uses in high-temperature electrochemical applications such as solid oxide fuel cells, advanced batteries, sensors, and oxygen-permeable membranes. The Sr-Fe-Co-O system combines high electronic/ionic conductivity with appreciable oxygen permeability at elevated temperatures. Dense ceramic membranes made of this material can be used to separate high-purity oxygen from air without the need for external electrical circuitry, or to partially oxidize methane to produce syngas. Samples of Sr{sub 2}Fe{sub 3{minus}x}Co{sub x}O{sub y} (with x = 0, 0.6, 1.0, and 1.4) were prepared by solid-state reaction in atmospheres with various oxygen partial pressures (pO{sub 2}) and were characterized by X-ray diffraction, scanning electron microscopy, and electrical conductivity measurements. Phase components of the samples are dependent on cobalt concentration and synthesis pO{sub 2}. Total conductivity increases ...
1998-05-18
International Nuclear Information System (INIS)
Structure and magnetic properties of UNi_1_0_-_xFe_xSi_2 intermetallics and "2"9Si nuclear magnetic resonance (NMR) in UNi_1_0Si_2 are investigated in a wide temperature range. Solid solutions in the exactly single-phase tetragonal form, ThMn_1_2 type, exist for x<2. The Ni and Fe atoms occupy the 8(f), 8(i) and 8(j) positions statistically, whereas the U atoms occupy the 2(a) and the Si atoms the 8(j) sites. The lattice parameters roughly follow Vegard's law. The magnetic susceptibility does not exhibit Curie-Weiss behaviour and, at about 630 K, an anomaly in the temperature dependence is observed. At low temperature, other anomalies are observed at 32 K and 45 K, for x=0.5 and 1.0 respectively. These low temperature anomalies are probably connected with magnetic ordering of a ferromagnetic character, whereas that at 630 K might result from the superparamagnetic state of Ni. Two "2"9Si NMR lines in UNi"1"0Si"2 were observed with the Knight ...
1993-09-01
Energy Technology Data Exchange (ETDEWEB)
The follow-up system for wastes (JAeSTI), developed at the end of the 1990s, forms a basis for today's followup activities in Finland. JAeSTI relies on an environmental protection database, the compliance monitoring system VAHTI operated by the environmental authorities. Waste followup and waste statistics depend very much on the annual waste quantities recorded in the VAHTI system. In the KYJ-project the coverage and reliability of the data in the VAHTI system was evaluated as for the streams of solid municipal waste. The project also included the compiling of national statistics on municipal waste for the year 2000. The project used other information sources, too, such as statistics compiled when the National Waste Plan and regional waste plans were revised in 2002. In addition, the extent and quantity of in-situ (household) composting and incineration were assessed on the basis of a separate study (Annex 2, In Finnish). In connection with the data ...
2004-07-01
International Nuclear Information System (INIS)
The electronic structure and properties of the cubic Laves phase (C15) compounds ZrZn_2 and ZrV_2 have been determined using our all-electron full-potential linearized-augmented-plane-wave (FLAPW) method for bulk solids. The computations were performed in two stages: (i) self-consistent warped muffin tin and (ii) self-consistent full potential. Spin-orbit coupling was included after either stage. The effects of the inclusion of the nonspherical terms inside the muffin tins on the eigenvalues is found to be small (of order 1 mRy). However, due to the fact that some of the bands near the Fermi level are flat, this effect leads to a much higher value of the density of states at E/sub F/ in ZnZr_2. The most important difference between the materials ZrZn_2 and ZrV_2 is the position of the d bands derived from the Zr and V atoms. Consequently, these materials have completely different Fermi surfaces. We have investigated the magnetic properties of these compounds by ...
Energy Technology Data Exchange (ETDEWEB)
The electronic structure and properties of the cubic Laves phase (C15) compounds ZrZn/sub 2/ and ZrV/sub 2/ have been determined using our all-electron full-potential linearized-augmented-plane-wave (FLAPW) method for bulk solids. The computations were performed in two stages: (i) self-consistent warped muffin tin and (ii) self-consistent full potential. Spin-orbit coupling was included after either stage. The effects of the inclusion of the nonspherical terms inside the muffin tins on the eigenvalues is found to be small (of order 1 mRy). However, due to the fact that some of the bands near the Fermi level are flat, this effect leads to a much higher value of the density of states at E/sub F/ in ZnZr/sub 2/. The most important difference between the materials ZrZn/sub 2/ and ZrV/sub 2/ is the position of the d bands derived from the Zr and V atoms. Consequently, these materials have completely different Fermi surfaces. We have investigated the magnetic properties ...
1988-03-01
We have measured the Raman isotropic profiles of the ?(C?N) band at 2235 cm(-1) for five solutions of ME6N (4-cyanophenyl-4'-hexylbenzoate) liquid crystal dissolved in CCl(4) in the range from x = 0.12 to 0.007 (x, mole fraction of ME6N) and then obtained the corresponding vibrational correlation functions, C(v)(t), by time Fourier transformation. The increase with dilution of the dephasing times ?(v) complies with the behavior of the nonmonotonic concentration dependence predicted by the fluctuation concentration model for this concentration range (x Rothschild, which, being based on the assumption that the environmental modulation is described by a stretched exponential decay e(-(t/?(0))(?)), is more appropriate for the interpretation of the vibrational correlation function arising from a distribution of relaxation processes caused, as in the present case, by the persistence of pseudonematic domains. With dilution the dispersion parameter ? and the average ...
2010-11-11
Energy Technology Data Exchange (ETDEWEB)
The recent rapid progress in surface treatment techniques dictates that the titanium alloys should have an improved resistance to frictional wear without any loss of their high corrosion resistance. These requirements can be satisfied by producing surface layers of specified microstructure and phase composition. The present paper describes a modification of the plasma discharge nitriding treatment of titanium alloys, i.e. the glow discharge-assisted oxycarbonitriding, which by introducing oxygen, nitrogen and carbon into the surface zone of the layer [a Ti(NCO) type layer] improves its useful properties, primarily the resistance to frictional wear and the resistance to corrosion [T. Wierzchon, J. Sobiecki, Vacuum, 44 (1993) 975; T. Wierzchon et al., in: G. Hecht, F. Richter, J. Hahn (Eds.), Thin Films, DGM Informationgesellschaft, Germany, 1994, p. 195] [1:2]. This is because titanium shows a good affinity to oxygen, carbon and nitrogen, whereas the chemical ...
1997-11-25
Products of the Benzene + O(3P) Reaction
The gas-phase reaction of benzene with O(3P) is of considerable interest for modeling of aromatic oxidation, and also because there exist fundamental questions concerning the prominence of intersystem crossing in the reaction. While its overall rate constant has been studied extensively, there are still significant uncertainties in the product distribution. The reaction proceeds mainly through the addition of the O atom to benzene, forming an initial triplet diradical adduct, which can either dissociate to form the phenoxy radical and H atom, or undergo intersystem crossing onto a singlet surface, followed by a multiplicity of internal isomerizations, leading to several possible reaction products. In this work, we examined the product branching ratios of the reaction between benzene and O(3P) over the temperature range of 300 to 1000 K and pressure range of 1 to 10 Torr. The reactions were initiated by pulsed-laser photolysis of NO2 in the presence of benzene and ...
2009-12-21
High quality La/sub 1.8/Sr/sub 0.2/CuO/sub 4/ and YBa/sub 2/Cu/sub 3/O/sub 7/ superconducting thin films, with zero resistance at 88 K, have been made by dual-ion-beam sputtering of metal and oxide targets at elevated temperatures. The films are about 1.0 ..mu..m thick and are single phase after annealing. The substrates investigated are Nd-YAP, MgO, SrF/sub 2/, Si, CaF/sub 2/, ZrO/sub 2/-9% Y/sub 2/O/sub 3/, BaF/sub 2/, Al/sub 2/O/sub 3/, and SrTiO/sub 3/. Characterization of the films was carried out using Rutherford backscattering spectroscopy, resistivity measurements, transmission electron microscopy, x-ray diffraction, and secondary ion mass spectroscopy. Substrate/film interaction was observed in every case. This generally involves diffusion of the substrate into the film, which is accompanied by, for example, the replacement of Ba by Sr in the YBa/sub 2/Cu/sub 2/O/sub 7/ structure, in the case of SrTiO/sub 3/ substrate. The best substrates were those that ...
1988-03-15
ON THE POSSIBILITY OF ENRICHMENT AND DIFFERENTIATION IN GAS GIANTS DURING BIRTH BY DISK INSTABILITY
International Nuclear Information System (INIS)
We investigate the coupling between rock-size solids and gas during the formation of gas giant planets by disk fragmentation in the outer regions of massive disks. In this study, we use three-dimensional radiative hydrodynamic simulations and model solids as a spatial distribution of particles. We assume that half of the total solid fraction is in small grains and half in large solids. The former are perfectly entrained with the gas and set the opacity in the disk, while the latter are allowed to respond to gas drag forces, with the back reaction on the gas taken into account. To explore the maximum effects of gas-solid interactions, we first consider 10 cm size particles. We then compare these results to a simulation with 1 km size particles, which explores the low-drag regime. We show that (1) disk instability planets have the potential to form large cores due to aerodynamic capturing of rock-size solids in spiral arms before fragmentation; (2) temporary clumps can concentrate tens ...
2010-11-20
Energy Technology Data Exchange (ETDEWEB)
Biomass and nutrient dynamics of black spruce seedlings during the hardening phase of the greenhouse rotation were examined after four pre-hardening fertilization regimes - conventional, constant-rate loading, exponential loading, and high exponential loading (delivering respectively 15, 40, 40 and 60 mg N seedling{sup -1}) - in order to assess nutrient dilution and steady-state nutrition. Although height growth of seedlings had virtually ceased during hardening, shoot biomass increased 99-142% and root biomass increased five- to tenfold depending on treatment. The biomass increase compromised steady-state nutrient status by diluting internal nutrient pools as nutrient supply was unable to keep up with growth. Soil nutrient levels were rapidly depleted during this period because of plant uptake and lack of fertilizer supplementation. Pre-hardening nutrient loading partly countered and delayed dilution effects, especially when applied ...
1997-07-01
Nuclear radiation detectors on II-VI compounds
International Nuclear Information System (INIS)
Nuclear radiation detectors in integral execution were produced by successive epitaxial growth from vapor phase of Zn Te and Cd Se thin layers onto scintillating Zn Se (Te) crystals. The irradiation of combined Zn Se (Te) - Zn Te - Cd Se detectors by Cu_K_a X-rays leads to the appearance of photoreceiver e.m.f., which tends to saturation with the increase of X-ray radiation dose reaching the value of 0.34-0.40 V at 200 R/min. The short circuit current dependence of irradiation dose power is linear. The matching factor for detectors with Zn Te-Cd Se photoreceivers with different doping levels is 0.68-0.92. The absolute monochromatic sensitivity is 0.32-0.35 m A/m W at a quantum efficiency 0.58-0.61 and a time constant 2 x 10"-"4 s. The calculated dose sensitivity for Zn Se(Te)-Zn Te-Cd Se combined detectors at the irradiation with X-rays having effective energy 8.86 keV gives the value 3.9 x 10"-"7 A/cm"2 (R/min); the experimental value of dose ...
1993-10-13
Energy Technology Data Exchange (ETDEWEB)
Neutron reflectometry (NR) was used to measure the concentration profile of a symmetric PEP/dPEP polymer blend with nanometer-scale resolution in the one-phase region. The shape of the profile near the surface was found to differ significantly from mean-field theory predictions for all bulk concentrations and temperatures surveyed. The profile shape is flattened at the surface over a distance about half the bulk correlation length, a length scale far greater than that of the dispersive forces that are the dominant microscopic interaction in such blends. We introduce a new method for extracting the surface energy difference that drives segregation based on the Gibbs adsorption equation (GAE) and compare it to a previous method based on mean-field theory. While both methods produce qualitatively similar results (the surface energy of pure dPEP is {approx}0.21 mJ/m{sup 2} smaller than pure PEP), the GAE method is much less model dependent, ...
1995-12-04
Modelling and simulation of rate-based mechanistic model for CO{sub 2} capture
Energy Technology Data Exchange (ETDEWEB)
The electric power industry can use the carbon dioxide absorption process to capture carbon from high-volume flue gas. However, the current cost of the process is too high due to the approximation method used in process design. The absorption column is typically designed with parameters that are assumed to be constant over the whole length of the column, resulting in an oversized unit. This approximation method is no longer valid given new environmental and economic concerns. In order to develop an accurate column design for high-efficiency carbon dioxide (CO{sub 2}) capture, it is necessary to understand the phenomena taking place in the system. A mechanistic model is presented for a robust absorber design that takes into account mass-transfer and hydrodynamic behaviour within the CO{sub 2} absorption columns. The capture performance of a packed column under a wide range of design and operating conditions was determined using a model based on the kinetics and thermodynamics of a ...
2003-07-01
Magnetic properties of laminated perovskite-like ferroelectromagnetics
International Nuclear Information System (INIS)
Magnetic properties of layer ferromagnets against the thickness are investigated. Two new compounds served for studies: Bisub(6)Tisub(2)Nbsub(0,5)Fesub(2,5)Osub(18) and Bi_7Ti_3Fe_3O_2_1. The Moessbauer effect and the magnetic susceptibility measurements were applied in the experiment. The Faraday method was used in magnetic measurements in fields from 1 to 9,5 kOe. The results of Moessbauer measurements show that temperature dependence of the spectra is typical for compounds with superparamagnetic properties. The magnetic fields Hsub(n) on Fe"5"7 nuclei in Bisub(6)Tisub(2)Nbsub(0,5)Fesub(2,5)Osub(18) and Bi_7Ti_3Fe_3O_2_1 are similar and equal to 520+-10 kOe. Therefore it may be concluded that relaxation times of nuclear spins in these compounds are equal or close to each other. The lines of quadrupole splitting appear in spectra together at 20 K. The results of magnetic measurements show that the Curie-Weiss law is satisfied in the range of high temperatures for ...
1975-01-01
Magnetic excitations in R_2PdSi_3 studied by inelastic neutron scattering
International Nuclear Information System (INIS)
R_2PdSi_3 compounds have been found to exhibit rich magnetic phenomena arising from the interplay between RKKY interaction, crystal electric field effects and geometric frustration due to the derived hexagonal AlB_2 structure. The observed crystallographic superstructure further complicates the CEF level scheme. Inelastic neutron scattering measurements on single crystals of Tm_2PdSi_3 and Er_2PdSi_3 have been performed at the cold triple axis spectrometer PANDA in FRM-II. Both compounds order antiferromagnetically at T_N=7 K and 2.1 K respectively; Er_2PdSi_3 undergoes a second phase transition at T_2=2 K. Several low lying CEF excitations (below 10 meV) were observed. The intensity of the lowest excitation show strong directional dependence (in HK0 plane for Er_2PdSi_3 and in HHL plane for Tm_2PdSi_3), from which the details of the transitional matrix could be deduced. Measurements in magnetic fields up to 13 T show Zeeman splitting of the ...
2009-03-22
Hydrogen embrittlement, revisited by in situ electrochemical nanoindentation
Energy Technology Data Exchange (ETDEWEB)
The fine scale mechanical probing capability of NI-AFM was used to examine hydrogen interaction with plasticity. To realize this, an electrochemical three electrode setup was incorporated into the NI-AFM. The developed ECNI-AFM is capable of performing nanoindentation as well as imaging surfaces inside electrolytes. The developed ECNI-AFM setup was used to examine the effect of cathodically charged hydrogen on dislocation nucleation in pure metals and alloys. It was shown that hydrogen reduces the pop-in load in all of the tested materials except Cu. The reduced pop-in load can be interpreted as the HELP mechanism. Classical dislocation theory was used to model the homogeneous dislocation nucleation and it was shown that H reduces the activation energy for dislocation nucleation in H sensitive metals which are not undergoing a phase transformation. The activation energy for dislocation nucleation is related to the material specific parameters; shear modulus {mu}, ...
2007-07-01
Pulsed operation of an AlGaInP graded-index separate confinement heterostructure laser grown by organometallic vapor phase epitaxy is reported. The laser active region consists of a single 100 A Ga/sub 0.5/In/sub 0.5/P quantum well and 1600 A graded index regions on both sides of the well. The graded index regions were produced by lattice-matched graded composition (Al/sub y/Ga/sub 1-//sub y/)/sub 0.5/In/sub 0.5/P quaternary alloys. This structure reduces the broad-area threshold current compared to a double heterostructure laser, with pulsed thresholds as low as 1050 A/cm/sup 2/. Total pulsed power of 1.4 W at 658 nm is available from an 80 ..mu..m x 300 ..mu..m mesa-stripe laser. A differential quantum efficiency of approx.56% is measured. By examining the cavity length dependence of the threshold current density and quantum efficiency, it is apparent that the quantum well gain has not saturated in these structures. This suggests that devices ...
1987-11-23
Heat transfer characteristics of horizontal steam generators under natural circulation conditions
Energy Technology Data Exchange (ETDEWEB)
This paper deals with the heat transfer characteristics of horizontal steam generators, particularly under natural circulation (decay heat removal) conditions on the primary side. Special emphasis is on the inherent features of horizontal steam generator behaviour. A mathematical model of the horizontal steam generator primary side is developed and qualitative results are obtained analytically. A computer code, called HSG, is developed to solve the model numerically, and its predictions are compared with experimental data. The code is employed to obtain for VVER 440 steam generators quantitative results concerning the dependence of primary-to-secondary heat transfer efficiency on the primary side flow rate, temperature and secondary level. It turns out that the depletion of the secondary inventory leads to an inherent limitation of the decay energy removal in VVER steam generators. The limitation arises as a consequence of the steam generator tube bundle geometry. ...
1996-10-01
Gene Repressive Activity of RIP140 Through Direct Interaction with CDK8.
Receptor interacting protein 140 (RIP140) is a coregulator for numerous nuclear receptors and transcription factors and primarily exerts gene-repressive activities on various target genes. We previously identified a spectrum of posttranslational modifications on RIP140 that augment its property and biological activity. In T(3)-triggered biphasic regulation of cellular retinoic acid binding protein 1 (Crabp1) gene along the course of fibroblast-adipocyte differentiation, we found TRAP220(MED1) critical for T(3)-activated chromatin remodeling whereas RIP140 essential for T(3)-repressive chromatin remodeling of this gene promoter. In this current study, we aim to examine whether and how RIP140 replaces TRAP220(MED1) on the CrabpI promoter in differentiating adipocyte cultures. We find increasing recruitment of RIP140 to this promoter, with corresponding reduction in TRAP220(MED1) recruitment during the T(3)-repressive phase. We also uncover direct interaction of ...
2011-08-25
Functions of mammalian Cdc7 kinase in initiation/monitoring of DNA replication and development
Energy Technology Data Exchange (ETDEWEB)
Cdc7 kinase plays an essential role in firing of replication origins by phosphorylating components of the replication complexes. Cdc7 kinase has also been implicated in S phase checkpoint signaling downstream of the ATR and Chk1 kinases. Inactivation of Cdc7 in yeast results in arrest of cell growth with 1C DNA content after completion of the ongoing DNA replication. In contrast, conditional inactivation of Cdc7 in undifferentiated mouse embryonic stem (ES) cells leads to growth arrest with rapid cessation of DNA synthesis, suggesting requirement of Cdc7 functions for continuation of ongoing DNA synthesis. Furthermore, loss of Cdc7 function induces recombinational repair (nuclear Rad51 foci) and G2/M checkpoint responses (inhibition of Cdc2 kinase). Eventually, p53 becomes highly activated and the cells undergo massive p53-dependent apoptosis. Thus, defective origin activation in mammalian cells can generate DNA replication checkpoint signals. ...
2003-11-27
International Nuclear Information System (INIS)
The Phebus FP project in an international reactor safety project. Its main objective is to study the release, transport and retention of fission products in a severe accident of a Light Water Reactor (LWR). The FPT4 test was performed with a fuel debris bed geometry, to look at late phase core degradation and the releases of low volatile fission products and actinides. Post Test Analyses results indicate that releases of noble gases (Xe, Kr) and high-volatile fission products (Cs, I) were nearly complete and comparable to those obtained during Phebus tests performed with a fuel bundle geometry (FPT1, FPT2). Volatile fission products such as Mo, Te, Rb, Sb were released significantly as in previous tests. Ba integral release was greater than that observed during FPT1. Release of Ru was comparable to that observed during FPT1 and FPT2. As in other Phebus tests, the Ru distribution suggests Ru volatilization followed by fast redeposition in the fuelled section. The ...
2006-03-01
Equatorial scintillation model. Technical report, 1 February 1983-30 April 1985
Energy Technology Data Exchange (ETDEWEB)
Radiowave scintillation in the presence of natural and/or high-altitude nuclear disturbances has the potential to disrupt numerous transionospheric radio and radar systems. This report develops a model characterizing the plasma-density irregularities that produce scintillation in the naturally disturbed equatorial F layer. The model is incorporated into Program WBMOD along with subroutines for computing both link geometry and scintillation indices, the latter by means of phase screen diffraction theory. The model is based on similarly extensive analysis of wideband data from two equatorial stations. It describes irregularities at an effective height of 350 km that are isotropic across the geomagnetic field and elongated by a factor of 50 along the field and whose one-dimensional spatial power spectrum obeys a single-regime power law with a (negative) spectral index of 1.5. The height-integrated spectral strength of the irregularities is modeled as a function of ...
1985-09-30
Composition, structure and evolution of neutron stars with kaon condensates
International Nuclear Information System (INIS)
We investigate the possibility of kaon condensation in the dense interior of neutron stars through the s-wave interaction of kaons with nucleons. We include nucleon-nucleon interactions by using simple parametrizations of realistic forces, and include electrons and muons in #beta#-equilibrium. The equation of state above the condensate threshold is derived in the mean field approximation. The conditions under which kaon condensed cores undergo a transition to quark matter containing strange quarks are also established.The critical density for kaon condensation lies in the range (2.3-5.0)#rho#_0, where #rho#_0=0.16 fm"-"3 is the equilibrium density of nuclear matter. The critical density depends largely on the value of the strangeness content of the proton, the size of which is controversial. For too large a value of the strangeness content, matter with a kaon condensate is not sufficiently stiff to support the lower limit of 1.44 M_o_e_d_o_t for a neutron star. ...
International Nuclear Information System (INIS)
Current trends in nuclear power generation (and particularly in pressurized water reactors) are toward plant life extension and extended fuel burnup. A higher heat generation rate can induce local boiling regimes at the fuel rod surface in the hottest channels of the core, which can strongly modify the chemical environment of the cladding and influence the oxidation rate of zirconium alloys. Tests performed in out-of-pile loops under severe chemical and thermal-hydraulic conditions (nucleate boiling, higher lithium contents compared to PWRs) reveal two important phenomena: an increase of the oxidation rate of Zircaloy-4 cladding materials in 'high' lithiated environments; an enrichment of the chemical additives in the primary water (boron, lithium) at the surface of the cladding under nucleate boiling conditions. The latter phenomenon, also called 'hideout effect', is mainly controlled by some thermal hydraulic parameters such as bubble diameters and nucleation site density. These ...
1999-12-01
International Nuclear Information System (INIS)
The extracellular matrix (ECM) of the distal tissues in a newt limb stump is completely reorganized in the 2-3-week period following amputation. In view of numerous in vitro studies showing that extracellular material influences cellular migration and proliferation, it is likely that the changes in the limb's ECM are important activities in the process leading to regeneration of such limbs. Using biochemical, autoradiographic, and histochemical techniques we studied temporal and spatial differences in the synthesis of glycosaminoglycans (GAGs) during the early, nerve-dependent phase of limb regeneration. Hyaluronic acid synthesis began with the onset of tissue dedifferentiation, became maximal within 1 weeks, and continued throughout the period of active cell proliferation. Chondroitin sulfate synthesis began somewhat later, increased steadily, and reached very high levels during chondrogenesis. During the first 10 days after amputation, ...
1986-01-01
A factor produced by the plerocercoid stage of S. mansonoides mimics some, but not all, of the actions reported for hGH. The biological actions of plerocercoid growth factor (PGF) suggest structural similarity to human GH (hGH). Plerocercoid membranes were solubilized, and PGF was purified more than 1000-fold by hGH receptor affinity chromatography. The ability of purified PGF to displace [125I]hGH from monoclonal antibodies specific for four distinct nonoverlapping antigenic determinants of hGH and from an anti-hGH polyclonal antibody was tested in liquid phase RIA. All of the hGH antibodies cross-reacted with PGF, with potencies ranging from more than 60% to less than 1% that of the hGH standard. Of the four major epitopes of hGH defined by the monoclonal antibodies used in this study, only one is not represented to a significant extent in PGF. The epitope of hGH that is only marginally present in PGF is highly conformationally dependent, and ...
1987-11-01
Analysis of Selected Two-Phase Flow Phenomena in VVER Reactors with Horizontal Steam Generators
International Nuclear Information System (INIS)
Since 1984 the thermal-hydraulic code ATHLET has been also applied for the analyses of LOCA and transients in VVER plants. The specific design of these plants especially of the steam generator design requires a specific modelling of the phenomena which may occur under LOCA and transient conditions in these plants. Differences in design compared to the design of western reactors have been briefly listed. Specific phenomena occurring under small leak accidents are shortly described. The consideration of the simulation of the boiler-condenser mode illustrates the modelling requirements for a code which may be applied to the prediction of such a thermal-hydraulic behaviour. Facing the lack of experimental data, the reliability of the simulation has been discussed by means of plausibility studies based on the momentum balance for steam and water. In summary: The VVER reactors differ in design compared to reactors of western design. The VVER design, especially the design of the horizontal ...
1992-04-06
A study of Pd-Ta on Si(100) using AES, RBS and variable energy positron annihilation
The applicability of Pd/sub x/Ta/sub 1-x/ as a diffusion barrier on Si has been investigated. For this purpose Pd/sub x/Ta/sub 1-x/ films of 200 nm thickness (x ranges from 0 to 1) were deposited on Si(100), and the reaction between over-layer and substrate was studied as a function of temperature. Interaction was found to occur at temperatures increasing with the Ta content. The as-deposited Pd/sub x/Ta/sub 1-x/ films with 0.2 less than or equal to x less than or equal to 0.6 were found to be amorphous. The amorphous phase had a higher reaction temperature than the crystalline one, causing a discontinuous step in the reaction temperature. RBS spectra revealed that for the Pd-rich compositions first a stoichiometric Pd2Si layer formed underneath a pure Ta layer. At higher temperatures TaSi2 formed at the surface. For Ta-rich compositions Pd2Si formed first as well, however, the reaction temperature was so high that Pd2Si grains formed in a Si matrix. The defect ...
1988-01-01
Water Concentration Dependent Photochemistry of Ketoprofen in Neutral Aqueous Solutions
International Nuclear Information System (INIS)
... v. 1267(1) RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR
2010-08-06
A Stress-Dependent Hysteresis Model for Ferroelectric ...
... Attributes and limitations of the charac- terization framework are illustrated through comparison with experimental PLZT data. ...
2011-05-13
Energy Technology Data Exchange (ETDEWEB)
The results of real-time neutron diffraction measurements during the superconducting phase formation process in the Bi(Pb)-Sr-Ca-Cu-O system are reported. A Sr-Ca-Cu-O type precursor, with the same stoichiometry as the 2223 phase, was used as starting material, and the temperature range favorable to the formation of the 2223 phase was investigated. The diffraction patterns were processed by a multiphase Rietveld refinement. The formation and decomposition of the 2201 and 2212 phases were directly observed. Experimental evidence on the existence of a partially melted phase in the range 855-860[degrees]C, involved in the formation of the 2223 phase, is discussed. 14 refs., 9 figs., 1 tab.
1993-08-01
International Nuclear Information System (INIS)
The results of real-time neutron diffraction measurements during the superconducting phase formation process in the Bi(Pb)-Sr-Ca-Cu-O system are reported. A Sr-Ca-Cu-O type precursor, with the same stoichiometry as the 2223 phase, was used as starting material, and the temperature range favorable to the formation of the 2223 phase was investigated. The diffraction patterns were processed by a multiphase Rietveld refinement. The formation and decomposition of the 2201 and 2212 phases were directly observed. Experimental evidence on the existence of a partially melted phase in the range 855-860 degrees C, involved in the formation of the 2223 phase, is discussed. 14 refs., 9 figs., 1 tab.
Science of quantum phase transitions and quantum criticalities
International Nuclear Information System (INIS)
Apart from conventional phase transitions driven by the thermal effects, quantum phase transitions generated by quantum fluctuations have their own mechanisms that are reflected in critical phenomena. Quantum phase transitions have an origin from spontaneous symmetry breaking commonly to thermal phase transitions. Even in this case, inherent quantum fluctuations substantially modify and yield new aspects. Quantum phase transitions have, however, another mechanism caused by topology changes, which gives completely new characters. Recently, a mechanism which connects these two has been found. Proimities from first-order transitions and phase separatins as well as from multiphase coexistence also generate characteristic and unconventional quantum criticalities. Understanding novel quantum criticalities offers a firm basis of recent active researches on fields such ...
2011-02-01
International Nuclear Information System (INIS)
Here we reported a two-step procedure for preparing a novel polymeric based solid-solid phase change heat storage material. Firstly, a copolymer monomer containing a polyethylene glycol monomethyl ether (MPEG) phase change unit and a vinyl unit was synthesized via the modification of hydrogen group of MPEG. Secondly, by copolymerization of the copolymer monomer and phenyl ethylene, a novel polymeric based solid-solid phase change heat storage material was prepared. The composition, structure and properties of the novel polymeric based solid-solid phase change material were characterized by IR, "1H NMR, DSC, WAXD, and POM, respectively. The results show that the novel polymeric based solid-solid phase change material possesses of excellent crystal properties and high phase change enthalpy.
2009-06-01
Energy Technology Data Exchange (ETDEWEB)
A new technique has been developed for the measurement of steam mass flowrate, water mass flowrate and total enthalpy of two-phase fluids produced from geothermal wells. The method involves precisely metered injection of liquid and vapor phase tracers into the two-phase production pipeline and concurrent sampling of each phase downstream of the injection point. Subsequent chemical analysis of the steam and water samples for tracer content enables the calculation of mass flowrate for each phase given the known mass injection rates of tracer. This technique has now been used extensively at the Coso geothermal project, owned and operated by California Energy Company. Initial validation of the method was performed at the Roosevelt Hot Springs geothermal project on wells producing to individual production separators equipped with orificeplate flowmeters for each ...
1993-01-28
Effects of velocity-dependent force on the magnetic form factors of odd-Z
International Nuclear Information System (INIS)
We investigate the effects of the velocity-dependent force on the magnetic form factors and magnetic moments of odd-Z nuclei. The form factors are calculated with the harmonic-oscillator wavefunctions. It is found that the contributions of the velocity-dependent force manifest themselves in the very large momentum transfer region (q?4 fm-1). In the low and medium q region the contributions of the velocity-dependent force are very small compared with those without this force. However, in the high-q region the contributions of the velocity-dependent force are larger than the normal form factors. The diffraction structures beyond the existing experimental data are found after the contributions of the velocity-dependent force are included. The formula of the correction to the single particle magnetic moment due to the velocity-dependent force is reproduced exactly ...
2008-03-01
Proton spin lattice relaxation studies in lithium ammonium sulfate LiNH_4SO_4
International Nuclear Information System (INIS)
Lithium ammonium sulfate (LAS) undergoes a phase transition at Tsub(c1) = 459.5deg K from a paraelectric phase (phase 1) to a ferroelectric phase (phase II) and again at Tsub(c2) = 283deg K to a polar ferroelastic phase (phase III). Proton spin lattice relaxation investigations in the temperature range 480-77deg K at 10 MHz show discontinuous changes in Tsub(1) at the transition temperatures, indicating first order phase transitions. The absence of the slow motion region (#omega#sub(not)tausub(not)>>1) shows that the ammonium ions are reorienting fast enough to keep the resonance absorption line narrow down to liquid nitrogen temperatures. The possibility of a second minimum and a low activation energy, Esub(a) = 2.659 kcal/mole, in phase III suggest the possibility of tunnelling of the protons ...
1978-12-31
Structural transformations of metastable #alpha#''-phase during cold deformation
International Nuclear Information System (INIS)
Phase transformations occuring during cold deformation in hardened #alpha#+#beta# titanium alloy of the Ti-Al-Mo-Zr-Sn-Si system with 10% summary content of alloying elements are studied by X-ray diffraction analysis. Two stages of trapsformation of metastable #alpha#''-phase are found. A conclusiop is made that ability of the alloy containing #alpha#''-phase to cold deformation is determined by the presence of favourable texture, by high degree of metastability and by volume portion of #alpha#''-phase in the alloy structure.
International Nuclear Information System (INIS)
In FY 1984 three specific tasks which are all related to not-well-understood two-phase phenomena of importance to LWR accidents have been identified under the program. These three tasks are: (1) inverted annular flow experiments and modeling; (2) hot leg U-bend two-phase flow simulation study; and (3) development and evaluation of two-phase flow scaling criteria. Some of the important results obtained under Tasks (1) and (2) are reported in this paper.
1984-10-23
Energy Technology Data Exchange (ETDEWEB)
The author shows in this paper an interesting relation between elementary and topological excitations in the antiferromagnetic and d-wave superconducting phases of the t-J model at two dimensions. The topological spin and charge excitations in one phase have the same dynamics as elementary excitations in the other phase, except the appearance of energy gaps. Moreover, the transition from one phase to another can be described as a quantum disordering transition associated with the topological excitations. Based on the above picture, a plausible phase diagram of t-J model is constructed.
2000-02-10
Crystal structure of telluric acid ammonium phosphate (TAAP) in the paraelectric phase
Energy Technology Data Exchange (ETDEWEB)
Crystal structure of monoclinic telluric acid ammonium phosphate (TAAP) has been studied by an X-ray diffraction method in the paraelectric phase at 333 K and in the ferroelectric phase at room temperature. It is confirmed that the space group in the paraelectric phase is P2/n. Comparison of the results between the two temperatures suggests that the plane which is made by the PO{sub 4} tetrahedron linked by hydrogen bonds has an important role for the ferroelectric phase transition. This plane is almost parallel to the direction of spontaneous polarization.
2005-01-15
CIRNAT - a code for one and two-phase natural circulation
Energy Technology Data Exchange (ETDEWEB)
CIRNAT, a one-dimensional code for natural circulation analysis, was described. The homogeneous approach was adopted for the two-phase flow regime and different heat transfer regimes were considered. The code was exhaustively tested for one-phase flow systems. For two phase flows a boiling/condensing system was simulated. The results are qualitatively correct but the oscillations observed at the system were not captured by the model. Other two-phase flow tests must be done to show the limits of the homogeneous approach before the introduction of a more complex model. (author)
1996-07-01
CIRNAT - a code for one and two-phase natural circulation
International Nuclear Information System (INIS)
CIRNAT, a one-dimensional code for natural circulation analysis, was described. The homogeneous approach was adopted for the two-phase flow regime and different heat transfer regimes were considered. The code was exhaustively tested for one-phase flow systems. For two phase flows a boiling/condensing system was simulated. The results are qualitatively correct but the oscillations observed at the system were not captured by the model. Other two-phase flow tests must be done to show the limits of the homogeneous approach before the introduction of a more complex model. (author)
1996-11-11
International Nuclear Information System (INIS)
The Utility PhotoVoltaic Group (UPVG), supported by member dues and a grant from the US Department of Energy, has as its mission the acceleration of the use of cost-effective small-scale and emerging large-scale applications of photovoltaics for the benefit of electric utilities and their customers. Formed in October, 1992, with the support of the American Public Power Association, Edison Electric Institute, and the National Rural Electric Cooperative Association, the UPVG currently has 90 members from all sectors of the electric utility industry. The UPVG's efforts as conceived were divided into four phases: Phase 0--program plan; Phase 1--organization and strategy development; Phase 2--creating market assurance; and Phase 3--higher volume purchases. The Phase 0 effort developed the program plan and was completed early in 1993. The Phase 1 ...
2006-11-24
Energy Technology Data Exchange (ETDEWEB)
The two-phase flow program is directed at understanding the hydrodynamics of two-phase flows. The two-phase flow regime is characterized by a series of flow patterns that are designated as bubble, slug, churn, and annular flow. Churn flow has received very little scientific attention. This lack of attention cannot be justified because calculations predict that the churn flow pattern will exist over a substantial portion of the two-phase flow zone in producing geothermal wells. The University of Houston is experimentally investigating the dynamics of churn flow and is measuring the holdup over the full range of flow space for which churn flow exists. These experiments are being conducted in an air/water vertical two-phase flow loop. Brown University has constructed and is operating a unique two-phase flow research facility specifically designed to address flow ...
1983-12-01
Some highlights of phase-C commissioning of Tarapur-4 the first to be synchronized 540 MWe PHWR
International Nuclear Information System (INIS)
Commissioning of a Pressurized heavy water reactor (PHWR) plant of NPCIL involves three phases viz phase-A which consist of pre-criticality activities such as hydro test, air hold test, no load test of motors etc., phase-B consist of criticality and post criticality physics experiments. The phase-C, which is considered the major phase, consist of initial power raise to about 10 % , TG rolling, synchronization, going to significant power in steps and performance tests such as load rejection tests from various power levels. In order to have smooth commissioning for the Phase-C, an integrated team consisting of engineers from various design and analysis groups of NPCIL headquarters was formed to participate along with site O and M engineers, closely observe and coordinate phase-C commissioning activities. During this commissioning some major ...
2006-11-13
Results of two-phase natural circulation in hot-leg U-bend simulation experiments
Energy Technology Data Exchange (ETDEWEB)
In order to study the two-phase natural circulation and flow termination during a small break loss of coolant accident in LWR, simulation experiments have been performed using two different thermal-hydraulic loops. The main focus of the experiment was the two-phase flow behavior in the hot-leg U-bend typical of BandW LWR systems. The first group of experiments was carried out in the nitrogen gas-water adiabatic simulation loop and the second in the Freon 113 boiling and condensation loop. Both of the loops have been designed as a flow visualization facility and built according to the two-phase flow scaling criteria developed under this program. The nitrogen gas-water system has been used to isolate key hydrodynamic phenomena such as the phase distribution, relative velocity between phases, two-phase flow regimes and flow termination mechanisms, whereas the Freon ...
1987-01-01
Phases of a two dimensional large N gauge theory on a torus
We consider two-dimensional large N gauge theory with D adjoint scalars on a torus, which is obtained from a D+2 dimensional pure Yang-Mills theory on T^{D+2} with D small radii. The two dimensional model has various phases characterized by the holonomy of the gauge field around non-contractible cycles of the 2-torus. We determine the phase boundaries and derive the order of the phase transitions using a method developed in an earlier work (hep-th/0910.4526), which is nonperturbative in the 'tHooft coupling and uses a 1/D expansion. We embed our phase diagram in the more extensive phase structure of the D+2 dimensional Yang-Mills theory and match with the picture of a cascade of phase transitions found earlier in lattice calculations (hep-lat/0710.0098). We also propose a dual gravity system based on a Scherk-Schwarz compactification of a D2 brane wrapped on a ...
2011-01-01
Development of a dual-detector X-ray imaging system for phase retrieval study
International Nuclear Information System (INIS)
Based on a recently introduced phase X-ray imaging approach, a dual-detector prototype was developed for in-line X-ray phase imaging and phase retrieval utilizing a micro-focus X-ray source and two computed radiography (CR) cassette detectors. The system was built on a horizontal optical rail to facilitate manual adjustment of the positions of the X-ray source, the sample and the detectors. The novel design of the detector-1 is essential, it detects a portion of radiation to form an attenuation image; allows the rest of radiation to reach the detector-2 to form a phase contrast image, and the two images are used to retrieve a phase map. The two detectors are balanced for optimal phase-retrieval with reasonable radiation dose to the object to be imaged. The system was examined in terms of the linearity, the fractions of the X-ray photons detected by the two ...
2007-01-01
X-ray Phase Imaging Microscopy using a Fresnel Zone Plate and a Transmission Grating
International Nuclear Information System (INIS)
We report on a hard X-ray phase imaging microscopy (a phase-difference microscopy) that consists of an objective and a transmission grating. The simple optical system provides a quantitative phase image, and does not need a wave field mostly coherent on the objective. Our method has a spatial resolution almost same as that of the absorption contrast microscope image obtained by removing the grating. We demonstrate how our approach provides a phase image from experimentally obtained images. Our approach is attractive for easily appending a quantitative phase-sensitive mode to normal X-ray microscopes, and has potentially broad applications in biology and material sciences.
2010-06-23
Two-phase application of multi-objective genetic algorithms in green building design
Energy Technology Data Exchange (ETDEWEB)
The application of multi-objective genetic algorithms for green building design in two phases were presented in order to better help designers in the decision-making process. The purpose is to minimize two conflicting criteria: the life-cycle cost and the life-cycle environmental impact. Environmental impact criteria examined include energy and non-energy natural resources, global warming, and acidification. Variables focus on building envelope-related parameters. The application of multi-objective genetic algorithms is divided into two phases. The first phase intends to help designers in understanding the trade-off relationship between the two conflicting criteria. The second phase intends to refine the performance region that is of the designer's interest. The results after the two-phase application of the multi objective genetic algorithm were then presented. 13 refs., 4 ...
2005-07-01
Thermal stability of mixed-cation #alpha#-sialon ceramics
International Nuclear Information System (INIS)
A series of #alpha#-sialon (#alpha#') compositions containing mixed stabilising cations were prepared, by introducing additional CaO to a basic Sm #alpha#-sialon compositions. The thermal stability of these Sm-Ca-containing #alpha#-sialon phases was investigated using XRD, SEM and EDXS techniques. It was found that the addition of calcium into the Sm #alpha#-sialon systems greatly improved the stability of the #alpha#-sialon phases. Calcium was found to be incorporated into the #alpha#-sialon structure, coexistent with the samarium, and partitioning of the calcium and samarium was observed between the #alpha#' phase and grain boundary phases. This indicates a technique which may be used to improve the thermal stability of the #alpha#' phase while maintaining good refractory phases at the sialon grain boundaries.
2003-01-02
Thermal energy storage system with stearic acid as phase change material
Energy Technology Data Exchange (ETDEWEB)
A simple tube-in-tube heat exchanger system for thermal energy storage employing stearic acid as PCM has been investigated. The performance and heat transfer characteristics of such a system were studied. Phase transition temperature range and times were measured and the speed of the phase transition front was computed. The melting front was found to move in the radial direction inward as well as in the axial direction from the top toward the bottom of the phase change material PCM tube. The speed of the melting front is enhanced by a convection heat transfer mechanism in the melted PCM. The heat transfer rate and, consequently, phase transition time can be altered by changing the water inlet temperature to the heat exchanger. In addition, a faster phase transition is realized by placing the heat exchanger in a horizontal position rather than a vertical one. (Author)
1994-10-01
Theoretical considerations for X-ray phase contrast mammography by Thomson source
Energy Technology Data Exchange (ETDEWEB)
The advent, in the near future, of compact X-ray sources like Thomson Back-Scattering (TBS) will allow the clinical application of advanced X-ray imaging techniques, such as phase contrast, with higher sensitivity and lower impact in terms of dose delivery. In this work, we theoretically investigated the possibility of using such sources for phase contrast imaging of micro-calcifications included in a breast tissue. In our study we analyzed the phase and amplitude distribution of the TBS source and we showed that this source can be used for phase contrast imaging since the source coherence at the sample position is sufficiently high for achieving good contrast and micrometer spatial resolution. Indeed the spatial coherence of a TBS source is closer to that of a synchrotron radiation source, and much better than that of a laboratory source. Moreover, we showed the advantages of phase ...
2009-09-01
Ternary diagram plotting software design using the tie-line slope method
Energy Technology Data Exchange (ETDEWEB)
Ternary diagrams are commonly used to provide a graphic representation of equilibrium fluid phase behavior for systems as diverse as distillation columns and miscible gas floods of oil reservoirs. The phase envelope, and the position of the critical point on it, are important to enhanced oil recovery engineers who are involved with miscible gas flood design. In the past, phase equilibrium data were laboriously plotted on the ternary diagram and special graphic techniques were utilized to locate the critical point on the phase envelope. This work presents a computerized curve fitting method to generate the phase envelope from a given set of phase equilibrium data and then use the tie-line slopes to position the critical point. Experimental data are included and show excellent agreement with this new method.
1982-01-01
Ternary diagram plotting software design using the ''tie-line slope'' method
Energy Technology Data Exchange (ETDEWEB)
Ternary diagrams or pseudo ternary diagrams are commonly used to provide a graphical representation of equilibrium fluid phase behavior for systems as diverse as distillation columns and miscible gas floods of oil reservoirs. The phase envelope and the position of the critical point on it are important to enhanced oil recovery engineers who are involved with miscible gas flood design. In the past, phase equilibrium data were laboriously plotted on the pseudo ternary diagram and special graphical techniques were utilized to locate the critical point on the phase envelope. Presented in this article is a computerized curve fitting method to, firstly, generate the phase envelope from a given set of phase equilibrium data and then use the 'tie-line slopes' to position the critical point. Experimental data are included and show excellent agreement ...
1983-01-01
Production of tetrazolium salts under conditions of phase-transfer catalysis
Energy Technology Data Exchange (ETDEWEB)
Recently the authors showed that tetrazolium salts can be obtained during the oxidation of substituted 1,3,5-triarylformazans with potassium permanganate in a two-phase organic solvent-water system. The role of phase-transfer catalyst in this reaction is played by the tetrazolium salt, which is formed in a small amount as the result of oxidation of the formazan at the phase boundary. The method is distinguished by its extreme simplicity. However, the yield of the tetrazolium salts fluctuates within wide limits and does not exceed 62%. This is due to the fact that as the reaction proceeds the pH of the aqueous phase increases from 6 to 12. At the same time it is known that tetrazolium salts are unstable in aqueous alkaline solutions. They found that if the aqueous phase is replaced by aqueous hydrochloric acid (5 wt. %) the yields of the tetrazolium salts (Ia-g) are increased to ...
1988-06-20
Energy Technology Data Exchange (ETDEWEB)
The magnitude of electric and magnetic fields around a high voltage three-phase transmission line was studied. A three-phase transmission circuit with parallel conductors produces rotating elliptic electric and magnetic fields. This study investigated the optimum arrangement of the phase conductors to minimize the maximum value of the magnetic flux density and to minimize the intensity of the resultant electric field. Two different types of high voltage double circuit transmission lines of 400 kV were considered. The optimum arrangement of the phase conductors was determined. It was concluded that the optimum arrangement can be easily applied to already constructed high voltage transmission lines by properly interchanging the phase conductors at the substations. 10 refs., 1 tab., 4 figs.
1997-12-31
International Nuclear Information System (INIS)
The magnitude of electric and magnetic fields around a high voltage three-phase transmission line was studied. A three-phase transmission circuit with parallel conductors produces rotating elliptic electric and magnetic fields. This study investigated the optimum arrangement of the phase conductors to minimize the maximum value of the magnetic flux density and to minimize the intensity of the resultant electric field. Two different types of high voltage double circuit transmission lines of 400 kV were considered. The optimum arrangement of the phase conductors was determined. It was concluded that the optimum arrangement can be easily applied to already constructed high voltage transmission lines by properly interchanging the phase conductors at the substations. 10 refs., 1 tab., 4 figs.
1997-08-24
On the criterion of the crystal-liquid phase transition
British Library Electronic Table of Contents (United Kingdom)
A localization criterion for the crystal-liquid phase transition (PT) is suggested, according to which the PT starts when the ratio E d/k B T reaches a boundary value E d(s)/k B T m, above which a solid phase, and below which, a liquid phase is located in the phase diagram. Here, E d is the energy of the delocalization of an atom, k B is the Boltzmann constant, T is the temperature, and E d(s) is the energy of delocalization for the solid phase at the melting point T m. It is shown that this criterion extends the Lindemann criterion of melting to the case of crystallization, and the L?ven criterion of crystallization to the case of melting. It is shown that the localization criterion suggested is applicable both for the normally melting substances and for the substances melting with a decr...
2008-01-01
On the criterion of the crystal-liquid phase transition
British Library Electronic Table of Contents (United Kingdom)
A localization criterion is proposed for the crystal-liquid phase transition (PT). According to this criterion, the PT begins when the E d/k b T ratio reaches a boundary value E d(s)/k b T m such that a solid phase is present above it and a liquid phase is present below it in a phase diagram. Here, E d is the energy of atom delocalization, k b is the Boltzmann constant, T is the temperature, and E d(s) is the delocalization energy for a solid phase at melting point T m. This criterion is shown to generalize the Lindemann criterion of melting to the case of crystallization and the L?ven criterion of crystallization to the case of melting. This localization criterion is found to be applicable for both normally melting substances and substances that melt with a decrease in the specific volume...
2008-01-01
Linac automated beam phase control system.
Energy Technology Data Exchange (ETDEWEB)
Adjustment of the rf phase in a linear accelerator is crucial for maintaining optimal performance. If phasing is incorrect, the beam will in general have an energy error and increased energy spread. While an energy error can be readily detected and corrected using position readings from beam position monitors at dispersion locations, this is not helpful for correcting energy spread in a system with many possible phase errors. Uncorrected energy spread results in poor capture efficiency in downstream accelerators, such as the Advanced Photon Source's (APS's) particle accumulator ring (PAR) or booster synchrotron. To address this issue, APS has implemented beam-to-rf phase detectors in the linac, along with software for automatic correction of phase errors. We discuss the design, implementation, and performance of these detectors and how they improved APS top-up ...
2006-01-01
Feasibility study of the iterative x-ray phase retrieval algorithm
International Nuclear Information System (INIS)
An iterative phase retrieval algorithm was previously investigated for in-line x-ray phase imaging. Through detailed theoretical analysis and computer simulations, we now discuss the limitations, robustness, and efficiency of the algorithm. The iterative algorithm was proved robust against imaging noise but sensitive to the variations of several system parameters. It is also efficient in terms of calculation time. It was shown that the algorithm can be applied to phase retrieval based on one phase-contrast image and one attenuation image, or two phase-contrast images; in both cases, the two images can be obtained either by one detector in two exposures, or by two detectors in only one exposure as in the dual-detector scheme.
2009-01-01
Disordered bcc γ-phase to δ-phase transformation in Zr-rich U-Zr alloy
British Library Electronic Table of Contents (United Kingdom)
The transformation mechanism of hexagonal delta phase from the disordered bcc gamma phase has not been reported before in the Zr-rich U-Zr alloy system. With the help of X-ray diffraction, transmission electron microscopy (TEM) and high-resolution TEM analyses it was shown that the gamma to delta conversion takes place by the lattice collapse mechanism of omega transformation. It was also ascertained that a higher aging temperature or time promotes the growth of all four variants of the delta phase within a parent gamma grain. In addition, ab initio electronic structure calculations showed that the bcc to hexagonal transformation, involving partial ordering of the parent bcc phase followed by (111) plane collapse, is energetically favorable.
2011-01-01
Crystallisation of grain boundary phases in silicon nitride and sialon ceramics
International Nuclear Information System (INIS)
A survey is presented of the principles and practice of tailoring sintering liquid composition and processing cycle to enable crystallisation of intergranular phases in silicon nitride and sialon ceramics. Critical features in sialon ceramics are the O/N balance in residual glasses and post-sintering heat-treatment temperatures to enable nucleation of either intermediate phases at constant composition or oxide phases with re-partitioning of non stoichiometric components in #beta#' or #alpha#' solid solutions. Crystallisation of disilicate phases in non-sialon compositions exemplifies a problem in control of polymorphs with differing atomic volumes. Crystallisation of intergranular phases has an influence mainly on high-temperature mechanical and environmental behaviour of these ceramics. (orig.).
1993-10-04
Energy Technology Data Exchange (ETDEWEB)
Various measurement tools that are used in chaos theory were applied to analyze two-phase pressure signals with the objective of identifying and interpreting flow pattern transitions for two-phase flows in a small, horizontal rectangular channel. These measurement tools included power spectral density function, autocorrelation function, pseudo-phase-plane trajectory, Lyapunov exponent,s and fractal dimensions. It was demonstrated that the randomlike pressure fluctuations characteristic of two-phase flow in small rectangular channels are chaotic, and governed by a high-order deterministic system. The correlation dimension is potentially a new approach for identifying certain two-phase flow patterns and transitions.
1996-06-01
TRITEX. A ferritic steel loop with Pb-15.8Li. Facility and operation
Energy Technology Data Exchange (ETDEWEB)
TRITEX was a pumped loop with Pb-15.8Li, fabricated from steel 1.4922. In contact with the molten eutectic were also molybdenum, vanadium and armco-iron. The loop was originally designed to investigate tritium extraction using solid getter metals. Over the years the goal changed to the study of metals, corrosion products and purification of the eutectic mixture. Therefore many modifications were done. The first part of this report describes TRITEX. All parts were enclosed in thermoboxes for a homogeneous temperature. One test section was in an argon glove box and could be opened during operation. Other special equipment`s were: permeation membranes and liquid-metal-covergas-interfaces to study the transport of H{sub 2}, D{sub 2} and {sup 3}H, different purification devices, a quartz observation window to see the liquid metal surface, 4 different kinds of flow measurements, level indicators, freeze valves. The second part describes loop operation. Between 1989 and 1996, the eutectic ...
1999-05-01
A study of flow boiling phenomena using real time neutron radiography
International Nuclear Information System (INIS)
The operation and safety of both fossil-fuel and nuclear power stations depend on adequate cooling of the thermal source involved. This is usually accomplished using liquid coolants that are forced through the high temperature regions by a pumping system; this fluid then transports the thermal energy to another section of the power station. However, fluids that undergo boiling during this process create vapor that can be detrimental, and influence safe operation of other system components. The behavior of this vapor, or void, as it is generated and transported through the system is critical in predicting the operational and safety performance. This study uses two advanced penetrating radiation techniques, Real Time Neutron Radiography (RTNR), and High Speed X-Ray Tomography (HS-XCT), to examine void generation and transport behavior in a flow boiling system. The geometries studied were tube side flow boiling in a cylindrical configuration, and a similar flow ...
1346-01-01
International Nuclear Information System (INIS)
Phase contrast X-ray imaging has been studied intensively using X-rays from synchrotron radiation and micro-focus X-ray tubes. However, these studies have revealed the difficulty of this technique's application to practical medical imaging. We have created a phase contrast imaging technique using a molybdenum X-ray tube with a small focal spot size for mammography. We identified the radiographic conditions in phase contrast magnification mammography with a screen-film system, where edge effect due to phase contrast overcomes geometrical unsharpness caused by the 0.1 mm-focal spot of a molybdenum X-ray tube. The edge enhancement due to phase imaging was observed in an image of a plastic tube, and then geometrical configuration of the X-ray tube, the object and the screen-film system was determined for phase imaging of mammography. In order to investigate a ...
2002-03-01
X-Ray Phase Imaging for Breast Cancer Detection
... Accession Number : ADA535309. Title : X-Ray Phase Imaging for Breast Cancer Detection. Descriptive Note : Annual rept. 1 Sep 2009-31 Aug 2010 ...
2010-09-01
Two-phase flow regime modeling
International Nuclear Information System (INIS)
This paper describes a long term course of research into the fundamentals of two phase flow regime dynamics that had lead to a differential description of regime properties. The development has included experiment, microscale simulation, and mathematical averaging to produce a dynamic equation for interfacial area.
1981-03-01
UK PubMed Central (United Kingdom)
Staphylococcus aureus preferentially catabolizes glucose, generating pyruvate, which is subsequently oxidized to acetate under aerobic growth conditions. Catabolite repression of the...Full Text Available
2002-11-01
Relation of the One-Phase Stefan Problem to the Seepage of Liquids and Electrochemical Machining.
The flow of water through a dam of fairly arbitrary shape is examined in the limit of large frictional drag on the flow. The relation of the problem to the one-phase Stefan problem and a problem of anodic smoothing is explored. Monotonicity and uniqueness...
1979-01-01
UK PubMed Central (United Kingdom)
Phosphoramidite reagents can phosphitylate guanine bases at the O6-position during solid phase synthesis and serious chain cleavage occurs if the base phosphitylation is not eliminated before the iodine/water...Full Text Available
1986-08-26
On the possibilities of a phase transition of superconducting type in the gross-Neveu model
Energy Technology Data Exchange (ETDEWEB)
It is shown that calculation of the anomalous expectation values for the massless Gross-Neveu model in the Hartree-Fock approximation indicates the presence of an ordinary chiral phase transition if the coupling constant has the normal sign (g > 0) and of a different transition of the superconductivity type if g < 0.
1995-11-01
UK PubMed Central (United Kingdom)
A detailed comparative assessment was made of the use of solid-phase-coupled antibodies in radioimmunoassay, by using an assay for human placental lactogen as a model system. The major advantages of...Full Text Available
1974-03-01
Energy Technology Data Exchange (ETDEWEB)
Anatomical specimens and normal persons were studied by gradient echo MR imaging to determine the influence of different echo times (TE) on bone marrow contrast. First of all, six normal persons were studied to determine specific echo times for in-phase and opposed-phase states. Using different sequences bone marrow contrast in isolated femoral bones was determined and compared to results of pathological exams. Red bone marrow had no signal on opposed-phase images; contrast between red and yellow marrow was higher on opposed-phase than on in-phase images. Bone marrow lesions can be expected to be visualised with high signal on opposed-phase images; this technique should be especially suited for MR imaging of bone marrow. (orig.).
1991-06-01
UK PubMed Central (United Kingdom)
[Leu]- and [Met]enkephalin from thoracic ganglia of the shore crab Carcinus maenas have been purified to homogeneity by a reversed-phase HPLC procedure. Automated gas-phase sequencing revealed a primary...Full Text Available
1991-10-01
Investigation of natural circulation two-phase flow behaviour in header manifold using CFD code
Energy Technology Data Exchange (ETDEWEB)
The three-dimensional (3-D), multiphase, computational fluid dynamic (CFD) code FLUENT is used to simulated two-phase flow behaviour in a CANDU header manifold under low (natural circulation) flow conditions. This behaviour was previously inferred from experimental data. The CFD simulations reported here are being used to support these inferences and to obtain a better understanding of phase distribution in the header manifold. The simulations seem to show that the vapor-water mixture models in the FLUENT code do not capture properly phase separation in the header and proper phase branching at the header-feeder connections that have been observed in experiments at low flows. The simulations using discrete-phase model in FLUENT, which tracks the pathlines of the individual vapor bubbles in the water continuum phase, show interesting, complicated and, in some ...
2006-07-01
High Efficiency Solar Cell on Low Cost Metal Foil Substrate
During Phase II multi-junction solar cell will be grown on the large grain thin film produced during Phase I on flexible/low cost metal foil substrate. ...
This cost-effectiveness analysis supports the proposed effluent limitations guidelines and standards for the Metal Products and Machinery Industry (MP and M) Phase I Industry. The report assesses the cost-effectiveness of five regulatory options for indir...
1995-01-01
Energy Technology Data Exchange (ETDEWEB)
To attain reproducible and stable contacts to compound semiconductor devices, it is necessary to achieve thermodynamically stable phases after the reaction of metals with the compound semiconductor. In this study, the final phases produced by the reactions between GaAs and thin metal films of Co, Rh, Ir, Ni, Pd, and Pt have been investigated. They are identified as MGa for M = Co, Rh, Ni, Pd, and Pt, monoarsenides of Co and Ni, diarsenides of Rh, Ir, Pd, and Pt, and Ir/sub 3/Ga/sub 5/. These phases, if deposited directly onto GaAs, will produce thermally stable contacts. In addition to the identification of these stable phases, analyses of the products of thin-film M/GaAs reactions by transmission electron microscopy, x-ray diffraction, and Rutherford backscattering spectrometry reveal the distribution, grain size, and crystallographic texture of these end phases. Trends in these ...
1987-09-01
UK PubMed Central (United Kingdom)
A solid-phase radioimmunoassay employing 125I-labeled enterotoxins and polystyrene tubes coated with specific antibody has been developed for assaying the relative concentrations of antibodies...Full Text Available
1975-06-01
UK PubMed Central (United Kingdom)
The polymorphic phase behavior of a homologous series of n-saturated 1,2-diacyl phosphatidylethanolamines was investigated by differential scanning calorimetry, 31P-nuclear magnetic resonance, and Fourier...Full Text Available
1993-04-01
Application of ?- and ?-Isomerism of Octahedral Metal Complexes for Inducing Chiral Nematic Phases
UK PubMed Central (United Kingdom)
The Δ- and Λ-isomerism of octahedral metal complexes is employed as a source of chirality for inducing chiral nematic phases. By applying a wide range of chiral metal complexes as a...Full Text Available
Antimicrobial Wound Dressing. Phase 1.
The main objective of Phase I of this SBIR project was to demonstrate the feasibility for successful development of an antimicrobial wound dressing based on a hydrogel sustained release matrix. This goal has been achieved. In vitro studies of drug diffusi...
1987-01-01
Structure functions of nuclei in fluctonic model with rescaling
International Nuclear Information System (INIS)
It is shown that the available data on x, Q"2, and A dependence of nuclear structure functions and for their ratios (EMS effect) can be described in terms of the flucton model with rescaling of parton distributions in nuclei. The x, Q"2 and A dependence of nuclear structure functions in the cumulative range (x >1) is predicted.
UK PubMed Central (United Kingdom)
The introduction of prenatal screening requires rapid high-throughput diagnosis of common aneuploidies. Multiplex ligation-dependent probe amplification (MLPA) allows for quick, easily automated multiplex...Full Text Available
2009-01-01
Mechanism of Na(+)-dependent citrate transport in Klebsiella pneumoniae.
UK PubMed Central (United Kingdom)
Citrate transport via CitS of Klebsiella pneumoniae has been shown to depend on the presence of Na+. This transport system has been expressed in Escherichia coli, and uptake of citrate in E. coli membrane...Full Text Available
1992-08-01
Hydrodynamics of primordial black hole formation: dependence on the equation of state
Energy Technology Data Exchange (ETDEWEB)
An analysis is made of the manner in which the process of primordial black-hole formation and the subsequent accretion of gas depend on the equation of state. On the assumption that the process is spherically symmetric, the problem is solved numerically.
1980-03-01
UK PubMed Central (United Kingdom)
Place fields of hippocampal pyramidal cells expand asymmetrically when adult rats repeatedly follow the same route. This behaviorally-induced expression of neuronal plasticity utilizes an NMDAR-dependent,...Full Text Available
2008-06-01
Dynamin-dependent NMDAR endocytosis during LTD and its dependence on synaptic state
UK PubMed Central (United Kingdom)
BackgroundThe N-methyl-D-aspartate (NMDA)-type glutamate receptor expressed at excitatory glutamatergic synapses is required for learning and memory and is critical for normal brain...Full Text Available
Coping with crowds: Density-dependent disease resistance in desert locusts
UK PubMed Central (United Kingdom)
Parasite transmission generally exhibits some form of positive density dependence. Thus, as population density increases, so too does the per capita risk of becoming infected. Under...Full Text Available
2002-04-16
Cell-density-dependent Changes in the Metabolism of Chloronema Cell Cultures
UK PubMed Central (United Kingdom)
In the growing chloronema cell suspension cultures of the moss Funaria hygrometrica Hedw., activities of several enzymes have been found to be cell-density-dependent. Cyclic nucleotide...Full Text Available
1979-07-01
Caveolin-1 as a Novel Indicator of Wound-Healing Capacity in Aged Human Corneal Epithelium
UK PubMed Central (United Kingdom)
Excess caveolin-1 has been reported to play a role in age-dependent hyporesponsiveness to growth factors in vitro. Therefore, we hypothesized that caveolin-1–dependent hyporesponsiveness...Full Text Available
2010-11-01
A structural determinant required for RNA editing
UK PubMed Central (United Kingdom)
RNA editing by adenosine deaminases acting on RNAs (ADARs) can be both specific and non-specific, depending on the substrate. Specific editing of particular adenosines may depend on the overall sequence...Full Text Available
2011-07-01
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