WorldWideScience

Sample records for exhaust gas temperature

  1. Effect of EGR on the exhaust gas temperature and exhaust opacity in compression ignition engines

    Avinash Kumar Agrawal; Shrawan Kumar Singh; Shailendra Sinha; Mritunjay Kumar Shukla

    2004-06-01

    In diesel engines, NOx formation is a highly temperature-dependent phenomenon and takes place when the temperature in the combustion chamber exceeds 2000 K. Therefore, in order to reduce NOx emissions in the exhaust, it is necessary to keep peak combustion temperatures under control. One simple way of reducing the NOx emission of a diesel engine is by late injection of fuel into the combustion chamber. This technique is effective but increases fuel consumption by 10–15%, which necessitates the use of more effective NOx reduction techniques like exhaust gas recirculation (EGR). Re-circulating part of the exhaust gas helps in reducing NOx, but appreciable particulate emissions are observed at high loads, hence there is a trade-off between NOx and smoke emission. To get maximum benefit from this trade-off, a particulate trap may be used to reduce the amount of unburnt particulates in EGR, which in turn reduce the particulate emission also. An experimental investigation was conducted to observe the effect of exhaust gas re-circulation on the exhaust gas temperatures and exhaust opacity. The experimental setup for the proposed experiments was developed on a two-cylinder, direct injection, air-cooled, compression ignition engine. A matrix of experiments was conducted for observing the effect of different quantities of EGR on exhaust gas temperatures and opacity.

  2. Exhaust Gas Temperature Measurements in Diagnostics of Turbocharged Marine Internal Combustion Engines Part I Standard Measurements

    Korczewski Zbigniew

    2015-01-01

    Full Text Available The article discusses the problem of diagnostic informativeness of exhaust gas temperature measurements in turbocharged marine internal combustion engines. Theoretical principles of the process of exhaust gas flow in turbocharger inlet channels are analysed in its dynamic and energetic aspects. Diagnostic parameters are defined which enable to formulate general evaluation of technical condition of the engine based on standard online measurements of the exhaust gas temperature. A proposal is made to extend the parametric methods of diagnosing workspaces in turbocharged marine engines by analysing time-histories of enthalpy changes of the exhaust gas flowing to the turbocompressor turbine. Such a time-history can be worked out based on dynamic measurements of the exhaust gas temperature, performed using a specially designed sheathed thermocouple.

  3. Exhaust Gas Temperature Measurements in Diagnostics of Turbocharged Marine Internal Combustion Engines Part II Dynamic Measurements

    Korczewski Zbigniew

    2016-01-01

    Full Text Available The second part of the article describes the technology of marine engine diagnostics making use of dynamic measurements of the exhaust gas temperature. Little-known achievements of Prof. S. Rutkowski of the Naval College in Gdynia (now: Polish Naval Academy in this area are presented. A novel approach is proposed which consists in the use of the measured exhaust gas temperature dynamics for qualitative and quantitative assessment of the enthalpy flux of successive pressure pulses of the exhaust gas supplying the marine engine turbocompressor. General design assumptions are presented for the measuring and diagnostic system which makes use of a sheathed thermocouple installed in the engine exhaust gas manifold. The corrected thermal inertia of the thermocouple enables to reproduce a real time-history of exhaust gas temperature changes.

  4. Thermodynamic control-oriented modeling of cycle-to-cycle exhaust gas temperature in an HCCI engine

    Highlights: • First thermodynamic model in the literature to predict exhaust temperature in HCCI engines. • The model can be used for integrated control of HCCI combustion and exhaust temperature. • The model is experimentally validated at over 300 steady state and transient conditions. • Results show a good agreement between predicted and measured exhaust temperatures. • Sensitivity of exhaust gas temperature to variation of engine variables is shown. - Abstract: Model-based control of Homogenous Charge Compression Ignition (HCCI) engine exhaust temperature is a viable solution to optimize efficiency of both engine and the exhaust aftertreatment system. Low exhaust temperature in HCCI engines can limit the abatement of hydrocarbon (HC) and carbon monoxide (CO) emissions in an exhaust aftertreatment system. A physical–empirical model is described for control of exhaust temperature in HCCI engines. This model captures cycle-to-cycle dynamics affecting exhaust temperature and is based on thermodynamic relations and semi-empirical correlations. It incorporates intake and exhaust gas flow dynamics, residual gas mixing, and fuel burn rate and is validated with experimental data from a single cylinder engine at over 300 steady state and transient conditions. The validation results indicate a good agreement between predicted and measured exhaust gas temperature

  5. Processing of exhaust gas

    Silicon carbide is an important component in exhaust gas filters for diesel engines. Norway produces and refines SiC, which is used in fireproof and ceramic industry and as an abrasive. It is also increasingly used in electronic industry. The emission from diesel engines consists of small spherical soot particles with an appendage of fuel, lubricating oil, water and sulphur compounds. These particles are intercepted by silicon carbide filters. There is a world-wide demand for environmentally friendly diesel engines and a growing demand for silicon carbide. From 2002, the EU permits a maximum emission of 0.025 grams per km of driving

  6. Gas turbine exhaust system silencing design

    Gas turbines are the preferred prime mover in many applications because of their high efficiency, fuel flexibility, and low environmental impact. A typical mid-size machine might have a power rating of 80 MW, a flow of about 1000 kg/hr, and an exhaust temperature of over 500C. The most powerful single source of noise is generally the exhaust, which may generate over a kilowatt of acoustic energy. This paper reports that there are two important ways in which exhaust systems can radiate noise. The first is through the discharge of the exhaust duct, with the exhaust gas. Because of the large quantity of hot gas, the duct exit is always oriented vertically; it may be fairly high in the air in order to promote dispersion of the exhaust plume. This source is almost always attenuated by means of a silencer located somewhere in the ductwork. The second source of noise is often called breakout; it is the radiation of exhaust noise through the walls of the ducting. Breakout is most important for those sections of the exhaust duct which lie upstream of the silencer, where sound levels inside the ducting are highest. Both exhaust duct exit noise and breakout noise can be calculated from the sound power level of the gas turbine exhaust and the sound transmission loss (TL) of the silencer and ducting

  7. Effect of Ambient Temperature on Total Organic Gas Speciation Profiles from Light-Duty Gasoline Vehicle Exhaust.

    Roy, Anirban; Sonntag, Darrell; Cook, Richard; Yanca, Catherine; Schenk, Charles; Choi, Yunsoo

    2016-06-21

    Total organic gases (TOG) emissions from motor vehicles include air toxic compounds and contribute to formation of ground-level ozone and secondary organic aerosol (SOA). These emissions are known to be affected by temperature; however previous studies have typically focused only on the temperature dependence of total emission factors and select toxic compounds. This study builds on the previous research by performing an evaluation of a comprehensive set of gas-phase organic compounds present in gasoline motor vehicle exhaust. A fleet of five vehicles using port fuel injection engine technology and running on E10 fuel was tested. Overall, three temperatures (0, 20, and 75 °F; or -18, -7, and 24 °C), two driving conditions (urban-FTP75 and aggressive driving-US06) and 161 compounds were evaluated; the emissions distributions were used to construct speciation profiles for each driving cycle and temperature. Overall, the speciation results indicated a significant increase in alkane and methane content, and decrease in alcohol, aldehyde and ketone content with decreasing temperature. These were verified using a statistical significance test. The fraction and composition of Mobile Source Air Toxics (MSATs) were significantly affected by temperature for both driving cycles. The ozone forming potentials of these profiles were evaluated using the maximum incremental reactivity (MIR) scale. Aromatic content was predicted to be a major driver behind the ozone forming potentials. Additionally, the decreasing ozone potential could be attributed to increased methane fractions with increasing temperature. PMID:27203618

  8. Elevated exhaust temperature, zoned, electrically-heated particulate matter filter

    Gonze, Eugene V [Pinckney, MI; Bhatia, Garima [Bangalore, IN

    2012-04-17

    A system includes an electrical heater and a particulate matter (PM) filter that is arranged one of adjacent to and in contact with the electrical heater. A control module selectively increases an exhaust gas temperature of an engine to a first temperature and that initiates regeneration of the PM filter using the electrical heater while the exhaust gas temperature is above the first temperature. The first temperature is greater than a maximum exhaust gas temperature at the PM filter during non-regeneration operation and is less than an oxidation temperature of the PM.

  9. Thermodynamic optimization of several (heat recovery steam generator) HRSG configurations for a range of exhaust gas temperatures

    Design optimization of a (heat recovery steam generator) HRSG is essential due to its direct impact on large power generation combined cycles. This study is aimed at giving a thermodynamic comparison between the optimums of three configurations of HRSG operating at exhaust gas temperature (TOT) from 350 °C to 650 °C. The optimization results, using PSO (Particle Swarm Optimization) method, show that adding another pressure level allows achieving a higher pressure at the inlet of high pressure turbine, producing more steam quantities, destroying less exergy and finally producing more specific work independently of TOT. For a given value of 600 °C representative of TOT of recent gas turbines, an addition of a pressure level is shown to increase the specific work of about 17 kJ/kg, representing a benefit of about 10% for the steam cycle, whereas a third pressure level results in 8 kJ/kg increase in the specific work, corresponding to 4% in the steam cycle. - Highlights: • Three types of HRSG are optimized and compared between them for several TOT values. • Adding a pressure level leads to thermodynamic performance enhancement whatever TOT. • Adding a pressure level permits reaching higher optimal pressures whatever TOT value. • Adding a pressure level permits producing more steam quantities. • Superheater effectiveness tends to its highest possible value except for high TOTs

  10. High temperature sensors for exhaust diagnosis

    Svenningstorp, Henrik

    2000-07-01

    One of the largest problems that we will have to deal with on this planet this millennium is to stop the pollution of our environment. In many of the ongoing works to reduce toxic emissions, gas sensors capable of enduring rough environments and high temperatures, would be a great tool. The different applications where sensors like this would be useful vary between everything from online measurement in the paper industry and food industry to measurement in the exhaust pipe of a car. In my project we have tested Schottky diodes and MlSiCFET sensor as gas sensors operating at high temperatures. The measurement condition in the exhaust pipe of a car is extremely tough, not only is the temperature high and the different gases quite harmful, there are also a lot of particles that can affect the sensors in an undesirable way. In my project we have been testing Schottky diodes and MlSiCFET sensors based on SiC as high temperature sensors, both in the laboratory with simulated exhaust and after a real engine. In this thesis we conclude that these sensors can work in the hostile environment of an engines exhaust. It is shown that when measuring in a gas mixture with a fixed I below one, where the I-value is controlled by the O{sub 2} concentration, a sensor with a catalytic gate metal as sensitive material respond more to the increased O{sub 2} concentration than the increased HC concentration when varying the two correspondingly. A number of different sensors have been tested in simulated exhaust towards NO{sub x}. It was shown that resistivity changes in the thin gate metal influenced the gas response. Tests have been performed where sensors were a part of a SCR system with promising results concerning NH{sub 3} sensitivity. With a working temperature of 300 deg C there is no contamination of the metal surface.

  11. A Fault Diagnosis Approach for Gas Turbine Exhaust Gas Temperature Based on Fuzzy C-Means Clustering and Support Vector Machine

    Zhi-tao Wang

    2015-01-01

    Full Text Available As an important gas path performance parameter of gas turbine, exhaust gas temperature (EGT can represent the thermal health condition of gas turbine. In order to monitor and diagnose the EGT effectively, a fusion approach based on fuzzy C-means (FCM clustering algorithm and support vector machine (SVM classification model is proposed in this paper. Considering the distribution characteristics of gas turbine EGT, FCM clustering algorithm is used to realize clustering analysis and obtain the state pattern, on the basis of which the preclassification of EGT is completed. Then, SVM multiclassification model is designed to carry out the state pattern recognition and fault diagnosis. As an example, the historical monitoring data of EGT from an industrial gas turbine is analyzed and used to verify the performance of the fusion fault diagnosis approach presented in this paper. The results show that this approach can make full use of the unsupervised feature extraction ability of FCM clustering algorithm and the sample classification generalization properties of SVM multiclassification model, which offers an effective way to realize the online condition recognition and fault diagnosis of gas turbine EGT.

  12. Short review on heat recovery from exhaust gas

    Jaber, Hassan; Khaled, Mahmoud; Lemenand, Thierry; Ramadan, Mohamad

    2016-07-01

    The increasing growth of energy demand leads to issues associated with energy demand reduction and propose new energy efficient solutions. Heat recovery consists the most promising solution especially in regions where renewable energy resources are not available. That is why the domain of heat recovery has shown a tremendous improvement during the recent years. On the other hand, few works have been dedicated to heat recovery from exhaust gas. This paper presents a review on heat recovery from exhaust gas. The authors propose to classify exhaust gas heat recovery systems within three different classifications that are exhaust gas temperature, utilized equipment and recovery purposes.

  13. Development of high temperature SiC based field effect sensors for internal combustion engine exhaust gas monitoring

    Wingbrant, Helena

    2003-01-01

    While the car fleet becomes increasingly larger it is important to lower the amounts of pollutants from each individual diesel or gasoline engine to almost zero levels. The pollutants from these engines predominantly originate from high NOx emissions and particulates, in the case when diesel is utilized, and emissions at cold start from gasoline engines. One way of treating the high NOx levels is to introduce ammonia in the diesel exhausts and let it react with the NOx to form nitrogen gas an...

  14. Effects of exhaust temperature on helicopter infrared signature

    The effects of exhaust temperature on infrared signature (in 3–5 μm band) for a helicopter equipped with integrative infrared suppressor were numerically investigated. The internal flow of exhaust gas and the external downwash flow, as well as the mixing between exhaust gas and downwash were simulated by CFD software to determine the temperature distributions on the helicopter skin and in the exhaust plume. Based on the skin and plume temperature distributions, a forward–backward ray-tracing method was used to calculate the infrared radiation intensity from the helicopter with a narrow-band model. The results show that for a helicopter with its integrative infrared suppressor embedded inside its rear airframe, the exhaust temperature has significant influence on the plume radiation characteristics, while the helicopter skin radiation intensity has little impact. When the exhaust temperature is raised from 900 K to 1200 K, the plume radiation intensity in 3–5 μm band is increased by about 100%, while the skin radiation intensity is increased by only about 5%. In general, the effects of exhaust temperature on helicopter infrared radiation intensity are mainly concentrated on plume, especially obvious for a lower skin emissivity case. -- Highlights: ► The effect of exhaust temperature on infrared signature for a helicopter is numerically investigated. ► The impact of exhaust temperature on helicopter skin temperature is revealed. ► The impact of exhaust temperature on plume radiation characteristics is revealed. ► The impact of exhaust temperature on helicopter skin radiation is revealed. ► The impact of exhaust temperature on helicopter's total infrared radiation intensity is revealed

  15. Exhaust gas recirculation system for an internal combustion engine

    Wu, Ko-Jen

    2013-05-21

    An exhaust gas recirculation system for an internal combustion engine comprises an exhaust driven turbocharger having a low pressure turbine outlet in fluid communication with an exhaust gas conduit. The turbocharger also includes a low pressure compressor intake and a high pressure compressor outlet in communication with an intake air conduit. An exhaust gas recirculation conduit fluidly communicates with the exhaust gas conduit to divert a portion of exhaust gas to a low pressure exhaust gas recirculation branch extending between the exhaust gas recirculation conduit and an engine intake system for delivery of exhaust gas thereto. A high pressure exhaust gas recirculation branch extends between the exhaust gas recirculation conduit and the compressor intake and delivers exhaust gas to the compressor for mixing with a compressed intake charge for delivery to the intake system.

  16. Exhaust gas assisted reforming of rapeseed methyl ester for reduced exhaust emissions of CI engines

    The nitrogen oxides (NOx) emissions of compression ignition (CI) engines fueled with biodiesel are generally higher compared to conventional diesel fuelling. Previous research work in CI engines has shown that the partial replacement of hydrocarbon fuels by hydrogen combined with exhaust gas recirculation (EGR) can reduce NOx and smoke emissions without significant changes to the engine efficiency. In the present study, the production of hydrogen-rich gas by catalytic exhaust gas assisted fuel reforming of rapeseed methyl ester (RME) has been investigated experimentally as a way to provide the required hydrogen for the reduction of biodiesel emissions. For comparison, tests with ultra low sulphur diesel (ULSD) were also performed. The reforming experiments were carried out in a mini reactor supplied with exhaust gas from a single cylinder CI engine. In all cases, the reactor inlet temperature was kept at 290-bar C which was chosen as a typical low exhaust gas temperature of diesel engines operating at part load. The engine operating condition (speed, load) was the same in all the tests and the reactor product gas was examined as a function of the reactor fuel flow rate and the composition of fuel and engine exhaust gas. Up to 17% hydrogen content of the reformer product was achieved and the results indicated that the main reactions in the reformer were the exothermic complete oxidation of part of the fuel and the endothermic steam reforming reaction. Reforming of RME produced more hydrogen with higher fuel conversion efficiency compared to ULSD reforming

  17. Method of controlling temperature of a thermoelectric generator in an exhaust system

    Prior, Gregory P; Reynolds, Michael G; Cowgill, Joshua D

    2013-05-21

    A method of controlling the temperature of a thermoelectric generator (TEG) in an exhaust system of an engine is provided. The method includes determining the temperature of the heated side of the TEG, determining exhaust gas flow rate through the TEG, and determining the exhaust gas temperature through the TEG. A rate of change in temperature of the heated side of the TEG is predicted based on the determined temperature, the determined exhaust gas flow rate, and the determined exhaust gas temperature through the TEG. Using the predicted rate of change of temperature of the heated side, exhaust gas flow rate through the TEG is calculated that will result in a maximum temperature of the heated side of the TEG less than a predetermined critical temperature given the predicted rate of change in temperature of the heated side of the TEG. A corresponding apparatus is provided.

  18. Investigation of exhaust gas temperature distribution within a furnace of a stoker fired boiler as a function of its operating parameters

    Krawczyk, Piotr; Badyda, Krzysztof; Szczygieł, Jacek; Młynarz, Szczepan

    2015-09-01

    Distribution of the exhaust gas temperature within the furnace of a grate boiler greatly depends on its operating parameters such as output. It has a considerably different character than temperature distributions in other types of boilers (with pulverised or fluidised bed), as it varies considerably across the chamber. Results presented in this paper have been obtained through research of a grate-fired hot water boiler with a nominal rating of some 30 MW. Measurements have been taken by introducing temperature sensors into prearranged openings placed in the boiler side walls. Investigation has been carried out for different output levels. Tests involved thermocouples in ceramic coating and aspirated thermocouples. The latter were used to eliminate influence of radiative heat transfer on measured results. Values obtained with both methods have been cross-checked.

  19. Coke-free dry reforming of model diesel fuel by a pulsed spark plasma at low temperatures using an exhaust gas recirculation (EGR) system

    Sekine, Yasushi; Furukawa, Naotsugu; Matsukata, Masahiko; Kikuchi, Eiichi, E-mail: ysekine@waseda.jp [Department of Applied Chemistry, Waseda University, 65-301, Okubo, Shinjuku, Tokyo 169-8555 (Japan)

    2011-07-13

    Dry reforming of diesel fuel, an endothermic reaction, is an attractive process for on-board hydrogen/syngas production to increase energy efficiency. For operating this dry reforming process in a vehicle, we can use the exhaust gas from an exhaust gas recirculation (EGR) system as a source of carbon dioxide. Catalytic dry reforming of heavy hydrocarbon is a very difficult reaction due to the high accumulation of carbon on the catalyst. Therefore, we attempted to use a non-equilibrium pulsed plasma for the dry reforming of model diesel fuel without a catalyst. We investigated dry reforming of model diesel fuel (n-dodecane) with a low-energy pulsed spark plasma, which is a kind of non-equilibrium plasma at a low temperature of 523 K. Through the reaction, we were able to obtain syngas (hydrogen and carbon monoxide) and a small amount of C{sub 2} hydrocarbon without coke formation at a ratio of CO{sub 2}/C{sub fuel} = 1.5 or higher. The reaction can be conducted at very low temperatures such as 523 K. Therefore, it is anticipated as a novel and effective process for on-board syngas production from diesel fuel using an EGR system.

  20. Coke-free dry reforming of model diesel fuel by a pulsed spark plasma at low temperatures using an exhaust gas recirculation (EGR) system

    Sekine, Yasushi; Furukawa, Naotsugu; Matsukata, Masahiko; Kikuchi, Eiichi

    2011-07-01

    Dry reforming of diesel fuel, an endothermic reaction, is an attractive process for on-board hydrogen/syngas production to increase energy efficiency. For operating this dry reforming process in a vehicle, we can use the exhaust gas from an exhaust gas recirculation (EGR) system as a source of carbon dioxide. Catalytic dry reforming of heavy hydrocarbon is a very difficult reaction due to the high accumulation of carbon on the catalyst. Therefore, we attempted to use a non-equilibrium pulsed plasma for the dry reforming of model diesel fuel without a catalyst. We investigated dry reforming of model diesel fuel (n-dodecane) with a low-energy pulsed spark plasma, which is a kind of non-equilibrium plasma at a low temperature of 523 K. Through the reaction, we were able to obtain syngas (hydrogen and carbon monoxide) and a small amount of C2 hydrocarbon without coke formation at a ratio of CO2/Cfuel = 1.5 or higher. The reaction can be conducted at very low temperatures such as 523 K. Therefore, it is anticipated as a novel and effective process for on-board syngas production from diesel fuel using an EGR system.

  1. 1025t/h锅炉排烟温度高改造%Treatment of high exhaust gas temperature for 1025t / h boiler

    刘勋川; 周胜利

    2011-01-01

    This paper briefly introduces the structure of 1025t/h boiler and its operation in Guizhou Qianbei Power Plant, aiming at its existing problems, such as high exhaust gas temperature and high desuperheating water flow, etc. By analyzing the boiler operation pa- rameters, this article presents some proposals to reduce exhaust gas temperature and boiler desuperheating water flow, and to improve the efficiency of the heating boiler. After the transformation, while receiving obvious effects, compared with the design value, it still has bigger difference. The author also puts forward views and opinions.%简要介绍了贵州西电黔北发电总厂1025t/h锅炉的结构及运行情况,针对锅炉排烟温度高、减温水流量大等问题。通过对锅炉运行参数的分析,提出了旨在降低锅炉排烟温度和减温水流量,提高了锅炉效率的受热面改造的建议。

  2. Coke-free dry reforming of model diesel fuel by a pulsed spark plasma at low temperatures using an exhaust gas recirculation (EGR) system

    Dry reforming of diesel fuel, an endothermic reaction, is an attractive process for on-board hydrogen/syngas production to increase energy efficiency. For operating this dry reforming process in a vehicle, we can use the exhaust gas from an exhaust gas recirculation (EGR) system as a source of carbon dioxide. Catalytic dry reforming of heavy hydrocarbon is a very difficult reaction due to the high accumulation of carbon on the catalyst. Therefore, we attempted to use a non-equilibrium pulsed plasma for the dry reforming of model diesel fuel without a catalyst. We investigated dry reforming of model diesel fuel (n-dodecane) with a low-energy pulsed spark plasma, which is a kind of non-equilibrium plasma at a low temperature of 523 K. Through the reaction, we were able to obtain syngas (hydrogen and carbon monoxide) and a small amount of C2 hydrocarbon without coke formation at a ratio of CO2/Cfuel = 1.5 or higher. The reaction can be conducted at very low temperatures such as 523 K. Therefore, it is anticipated as a novel and effective process for on-board syngas production from diesel fuel using an EGR system.

  3. Low exhaust temperature electrically heated particulate matter filter system

    Gonze, Eugene V.; Paratore, Jr., Michael J.; Bhatia, Garima

    2012-02-14

    A system includes a particulate matter (PM) filter, a sensor, a heating element, and a control module. The PM filter includes with an upstream end that receives exhaust gas, a downstream end and multiple zones. The sensor detects a temperature of the exhaust gas. The control module controls current to the heating element to convection heat one of the zones and initiate a regeneration process. The control module selectively increases current to the heating element relative to a reference regeneration current level when the temperature is less than a predetermined temperature.

  4. Exhaust gas treatment by electron beam irradiation

    Among global environmental problems, atmospheric pollution has been discussed since relatively old days, and various countermeasures have been taken, but recently in connection with acid rain, the efficient and economical treatment technology is demanded. As the denitration and desulfurization technology for the exhaust gas from the combustion of fossil fuel, the incineration of city trash and internal combustion engines, three is the treatment method by electron beam irradiation. By irradiating electron beam to exhaust gas, nitrogen oxides and sulfur oxides are oxidized to nitric acid and sulfuric acid, and by promoting the neutralization of these acids with injected alkali, harmless salts are recovered. This method has the merit that nitrogen oxides and surfur oxides can be removed efficiently with a single system. In this report, as for the exhaust gas treatment by electron beam irradiation, its principle, features, and the present status of research and development are described, and in particular, the research on the recent exhaust gas treatment in city trash incineration is introduced. This treatment method is a dry process, accordingly, waste water disposal is unnecessary. The reaction products are utilized as fertilizer, and waste is not produced. (K.I.)

  5. 40 CFR 86.111-90 - Exhaust gas analytical system.

    2010-07-01

    ... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Exhaust gas analytical system. 86.111... Complete Heavy-Duty Vehicles; Test Procedures § 86.111-90 Exhaust gas analytical system. (a) Schematic drawings. Figure B90-7 is a schematic drawing of the exhaust gas analytical system for analysis...

  6. 40 CFR 89.416 - Raw exhaust gas flow.

    2010-07-01

    ... 40 Protection of Environment 20 2010-07-01 2010-07-01 false Raw exhaust gas flow. 89.416 Section... Procedures § 89.416 Raw exhaust gas flow. The exhaust gas flow shall be determined by one of the methods...) Measurement of the air flow and the fuel flow by suitable metering systems (for details see SAE J244....

  7. Low temperature operation and exhaust emission

    Laurikko, J.

    1987-01-01

    Ambient temperature has the greatest effect on the exhaust emissions of internal combustion engines during the initial cold star and before the engine is fully warmed-up. Fuel evaporation is poor in a cold engine and the fuel-air mixture must be made richer to ensure that the engine weill start and be driveable. However, the combustion of a rich fuel-air mixture is incomplete because of the lack of oxygen, and the exhaust gases will contain an excessive amount of carbon monoxide (CO). The formation of nitrogen oxides (NO/sub x/) in a combustion engine is tied to high temperatures and oxygen concentrations. The conditions in a non-warmed engine using a rich fuel-air mixture are unfavourable for the formation of NO/sub x/ and the emission of NO/sub x/ may even diminish with falling ambient temperature. When the engine has reached its normal operating temperature the exhaust emissions are usually independent of the ambient temperature if the engine is equipped with intake air preheating that is sufficiently powerful. The reduction efficiency of a catalytic converter mainly depends on its operation temperature. Continuous operation at low temperatures may cause rapid poisoning of the converter. At low temperatures, carbon and other particles that do not burn collect on the active surface of the converter reducing its effectiveness.

  8. Integrated exhaust gas recirculation and charge cooling system

    Wu, Ko-Jen

    2013-12-10

    An intake system for an internal combustion engine comprises an exhaust driven turbocharger configured to deliver compressed intake charge, comprising exhaust gas from the exhaust system and ambient air, through an intake charge conduit and to cylinders of the internal combustion engine. An intake charge cooler is in fluid communication with the intake charge conduit. A cooling system, independent of the cooling system for the internal combustion engine, is in fluid communication with the intake charge cooler through a cooling system conduit. A coolant pump delivers a low temperature cooling medium from the cooling system to and through the intake charge cooler for the transfer of heat from the compressed intake charge thereto. A low temperature cooler receives the heated cooling medium through the cooling system conduit for the transfer or heat therefrom.

  9. Second law analysis of a low temperature combustion diesel engine: Effect of injection timing and exhaust gas recirculation

    For diesel engines, low temperature combustion (LTC) with a high level of EGR and late injection becomes attractive because of its potential of simultaneous reduction of nitrogen oxides (NOx) and particulate matter (PM) emissions. However, detailed thermodynamic evaluations including second law analysis of the LTC are few. The current work employed an engine cycle simulation incorporating the second law of thermodynamics to evaluate the energy and exergy distribution of various processes in a low temperature combustion diesel engine. After validation with experimental data at eight operating conditions including four different EGR levels and two different injection timings, the model was used to evaluate the effect of EGR level and injection timing on the first and second law parameters. As EGR was increased, intake temperature and equivalence ratio increased. Results showed that for the case at 0% EGR level with conventional injection timing, about 30% of the fuel exergy was destructed during combustion processes, and as EGR level increased to 45% (intake temperature and equivalence ratio also increased), the combustion destructed exergy decreased to 20% of the fuel exergy. This was largely due to the related combustion temperature increase. For both conventional (−6.5° aTDC) and late (1.5° aTDC) injection timings, the percentage of exergy transfer through flows increases as EGR increases, which is attributed to the retarded ignition by increasing EGR. Other parameters such as energy and exergy transfer due to heat transfer, blow-by, and unburned fuel also were determined as a function of EGR level and injection timing. -- Highlights: ► Exergy destruction during combustion decreased as intake temperature increased. ► Both conventional and late injection timings (LTC cases) were examined. ► For conventional injection timings, the combustion efficiency remains constant as EGR increases. ► For late injections and high EGR, combustion was incomplete.

  10. Design of a high temperature chemical vapor deposition reactor in which the effect of the condensation of exhaust gas in the outlet is minimized using computational modeling

    Yoon, Ji-Young; Geun Kim, Byeong; Nam, Deok-Hui; Yoo, Chang-Hyoung; Lee, Myung-Hyun; Seo, Won-Seon; Shul, Yong-Gun; Lee, Won-Jae; Jeong, Seong-Min

    2016-02-01

    Tetramethylsilane (TMS) was recently proposed as a safe precursor for SiC single crystal growth through high temperature chemical vapor deposition (HTCVD). Because the C content of TMS is much higher than Si, the exhaust gas from the TMS-based HTCVD contains large amounts of C which is condensed in the outlet. Because the condensed C close to the crystal growth front will influence on the thermodynamic equilibrium in the crystal growth, an optimal reactor design was highly required to exclude the effect of the condensed carbon. In this study, we report on a mass/heat transfer analysis using the finite element method (FEM) in an attempt to design an effective reactor that will minimize the effect of carbon condensation in the outlet. By applying the proposed reactor design to actual growth experiments, single 6H-SiC crystals with diameters of 50 mm were successfully grown from a 6H-SiC seed. This result confirms that the proposed reactor design can be used to effectively grow 6H-SiC crystals using TMS-based HTCVD.

  11. Boosting devices with integral features for recirculating exhaust gas

    Wu, Ko-Jen

    2015-12-22

    According to one embodiment of the invention, a turbine housing includes a turbine inlet in fluid communication with a turbine volute configured to house a turbine wheel, the turbine inlet configured to direct an exhaust gas flow from an engine to the turbine wheel. The turbine housing also includes a turbine outlet in fluid communication with the turbine volute, the turbine outlet configured to direct the exhaust gas flow to an exhaust gas conduit and a first exhaust gas recirculation supply port located on and in fluid communication with the turbine outlet, the first exhaust gas recirculation supply port being configured to direct a portion of the exhaust gas flow to an exhaust gas recirculation supply conduit.

  12. Exhaust gas recirculation in a homogeneous charge compression ignition engine

    Duffy, Kevin P.; Kieser, Andrew J.; Rodman, Anthony; Liechty, Michael P.; Hergart, Carl-Anders; Hardy, William L.

    2008-05-27

    A homogeneous charge compression ignition engine operates by injecting liquid fuel directly in a combustion chamber, and mixing the fuel with recirculated exhaust and fresh air through an auto ignition condition of the fuel. The engine includes at least one turbocharger for extracting energy from the engine exhaust and using that energy to boost intake pressure of recirculated exhaust gas and fresh air. Elevated proportions of exhaust gas recirculated to the engine are attained by throttling the fresh air inlet supply. These elevated exhaust gas recirculation rates allow the HCCI engine to be operated at higher speeds and loads rendering the HCCI engine a more viable alternative to a conventional diesel engine.

  13. Investigation of Diesel Exhaust Gas Toxicity on Transient Modes

    Ivashchenko Nikolay Antonovich

    2014-12-01

    Full Text Available Currently, the generation of heat engines and their control systems are based on ecological indices such as the toxicity of the fulfilled gases. When designing motors, software packages are widely used. These software packages provide the ability to calculate the workflow of engine at steady-state conditions. The definition of indicators emissions is a difficult task. The distribution statistics of the modes shows that the engines of the transport units work on unsteady modes most of the time. The calculation of toxicity indicators is even less developed. In this article experimental and numeric study of the diesel engine with turbocharger exhaust toxicity was considered. As a result of the experimental study, which was conducted with single-cylinder diesel engine compartment simulated work on the transient state, working process characteristics of a diesel engine were obtained, including carbon and nitrogen oxides concentrations. Functional dependencies of concentrations of toxic exhaust components, such as carbon and nitrogen oxides, on excess air ratio and exhaust temperature were obtained. Diesel engine transient processes were simulated using developed mathematical dynamic model of combined engine in locomotive power plant with a change in control signal (position of locomotive driver’s controller and external influence signal (resistance moment. The analysis of exhaust gas toxicity was conducted.

  14. 40 CFR 1065.127 - Exhaust gas recirculation.

    2010-07-01

    ... 40 Protection of Environment 32 2010-07-01 2010-07-01 false Exhaust gas recirculation. 1065.127 Section 1065.127 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Equipment Specifications § 1065.127 Exhaust gas recirculation. Use...

  15. 30 CFR 7.102 - Exhaust gas cooling efficiency test.

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Exhaust gas cooling efficiency test. 7.102 Section 7.102 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR TESTING....102 Exhaust gas cooling efficiency test. (a) Test procedures. (1) Follow the procedures specified...

  16. 40 CFR 86.211-94 - Exhaust gas analytical system.

    2010-07-01

    ... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Exhaust gas analytical system. 86.211... analytical system. The provisions of § 86.111-94 apply to this subpart, except that the NOX analyzer is optional. The exhaust gas analytical system must contain components necessary to determine...

  17. 30 CFR 36.26 - Composition of exhaust gas.

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Composition of exhaust gas. 36.26 Section 36.26... EQUIPMENT Construction and Design Requirements § 36.26 Composition of exhaust gas. (a) Preliminary engine... immediately at full load and speed. The preliminary liquid-fuel-injection rate shall be such that the...

  18. On the thermodynamics of waste heat recovery from internal combustion engine exhaust gas

    Meisner, G. P.

    2013-03-01

    The ideal internal combustion (IC) engine (Otto Cycle) efficiency ηIC = 1-(1/r)(γ - 1) is only a function of engine compression ratio r =Vmax/Vmin and exhaust gas specific heat ratio γ = cP/cV. Typically r = 8, γ = 1.4, and ηIC = 56%. Unlike the Carnot Cycle where ηCarnot = 1-(TC/TH) for a heat engine operating between hot and cold heat reservoirs at TH and TC, respectively, ηIC is not a function of the exhaust gas temperature. Instead, the exhaust gas temperature depends only on the intake gas temperature (ambient), r, γ, cV, and the combustion energy. The ejected exhaust gas heat is thermally decoupled from the IC engine and conveyed via the exhaust system (manifold, pipe, muffler, etc.) to ambient, and the exhaust system is simply a heat engine that does no useful work. The maximum fraction of fuel energy that can be extracted from the exhaust gas stream as useful work is (1-ηIC) × ηCarnot = 32% for TH = 850 K (exhaust) and TC = 370 K (coolant). This waste heat can be recovered using a heat engine such as a thermoelectric generator (TEG) with ηTEG> 0 in the exhaust system. A combined IC engine and TEG system can generate net useful work from the exhaust gas waste heat with efficiency ηWH = (1-ηIC) × ηCarnot ×ηTEG , and this will increase the overall fuel efficiency of the total system. Recent improvements in TEGs yield ηTEG values approaching 15% giving a potential total waste heat conversion efficiency of ηWH = 4.6%, which translates into a fuel economy improvement approaching 5%. This work is supported by the US DOE under DE-EE0005432.

  19. New catalysts for exhaust gas cleaning

    Haerkoenen, M. [Kemira Metalkat Oy, Oulu (Finland)

    1996-12-31

    Major challenge for future catalyst systems was to develop thermally more stable washcoats for close coupled operating conditions and for engines operating under high speed and load conditions. To design these future emission systems extensive research and development was undertaken to develop methods to disperse and stabilize the key catalytic materials for operation at much higher temperatures. Second priority was to design catalysts that are more effective under low temperature exhaust conditions and have improved oxygen storage properties in the washcoats. Incorporating new materials and modified preparation technology a new generation of metallic catalyst formulations emerged, those being trimetallic K6 (Pt:Pd:Rh and bimetallic K7) (Pd+Pd:Rh). The target was to combine the best property of Pt:Rh (good NO{sub x} reduction) with that of the good HC oxidation activity of Pd and to ensure that precious metal/support interactions were positively maintained. Both K6 and K7 concepts contain special catalyst structures with optimized washcoat performance which can be brick converter configuration. Improvement in light-off, thermal stability and transient performance with these new catalyst formulations have clearly been shown in both laboratory and vehicle testing. (author) (20 refs.)

  20. Exhaust gas recirculation for advanced diesel combustion cycles

    Highlights: • Analysis of the incremental (cycle-by-cycle) build-up of EGR. • Proposed one-step equations for transient/steady-state gas concentration estimation. • Defined an in-cylinder excess-air ratio to account for the recycled oxygen with EGR. • Demonstrated the use of intake oxygen as a reliable measure of EGR effectiveness. • Demonstrated the impact of engine load and intake pressure on EGR effectiveness. - Abstract: Modern diesel engines tend to utilize significantly large quantities of exhaust gas recirculation (EGR) and high intake pressures across the engine load range to meet NOx targets. At such high EGR rates, the combustion process and exhaust emissions tend to exhibit a marked sensitivity to small changes in the EGR quantity, resulting in unintended deviations from the desired engine performance characteristics (energy efficiency, emissions, stability). An accurate estimation of EGR and its effect on the intake dilution are, therefore, necessary to enable its application during transient engine operation or unstable combustion regimes. In this research, a detailed analysis that includes estimation of the transient (cycle-by-cycle) build-up of EGR and the time (engine cycles) required to reach the steady-state EGR operation has been carried out. One-step global equations to calculate the transient and steady-state gas concentrations in the intake and exhaust are proposed. The effects of engine load and intake pressure on EGR have been examined and explained in terms of intake charge dilution and in-cylinder excess-air ratio. The EGR analysis is validated against a wide range of empirical data that include low temperature combustion cycles, intake pressure and load sweeps. This research intends to not only formulate a clear understanding of EGR application for advanced diesel combustion but also to set forth guidelines for transient analysis of EGR

  1. Automotive exhaust gas flow control for an ammonia–water absorption refrigeration system

    A considerable part of the energy generated by an automotive internal combustion engine is wasted as heat in the exhaust system. This wasted heat could be recovered and applied to power auxiliary systems in a vehicle, contributing to its overall energy efficiency. In the present work, the experimental analysis of an absorption refrigeration system was performed. The exhaust system of an automotive internal combustion engine was connected to the generator element of an absorption refrigeration system. The performance of the absorption refrigerator was evaluated as a function of the supplied heat. The use of a control strategy for the engine exhaust gas mass flow rate was implemented to optimize the system. Exhaust gas flow was controlled by step-motor actuated valves commanded by a microcontroller in which a proportional-integral control scheme was implemented. Information such as engine torque, speed, key temperatures in the absorption cycle, as well as internal temperatures of the refrigerator was measured in a transient regime. The results indicated that the refrigeration system exhibited better performance when the amount of input heat is controlled based on the temperature of the absorption cycle generator. It was possible to conclude that, by dynamically controlling the amount of input heat, the utilisation range of the absorption refrigeration system powered by exhaust gas heat could be expanded in order to incorporate high engine speed operating conditions. - Highlights: •An absorption refrigerator was driven by automotive exhaust gas heat. •A system for controlling the refrigeration system heat input was developed. •Excessive exhaust gas heat leads to ineffective operation of the refrigerator. •Control of refrigerator's generator temperature led to better performance. •The use of exhaust gas was possible for high engine speeds

  2. IC ENGINE SUPERCHARGING AND EXHAUST GAS RECIRCULATION USING JET COMPRESSOR

    Adhimoulame Kalaisselvane; Natarajan Alagumurthy; Krishnaraj Palaniradja; G Selvaraj Gunasegarane

    2010-01-01

    Supercharging is a process which is used to improve the performance of an engine by increasing the specific power output whereas exhaust gas recirculation reduces the NOx produced by engine because of supercharging. In a conventional engine, supercharger functions as a compressor for the forced induction of the charge taking mechanical power from the engine crankshaft. In this study, supercharging is achieved using a jet compressor. In the jet compressor, the exhaust gas is used as the motive...

  3. Methane oxidation over noble metal catalysts as related to controlling natural gas vehicle exhaust emissions

    Natural gas has considerable potential as an alternative automotive fuel. This paper reports on methane, the principal hydrocarbon species in natural-gas engine exhaust, which has extremely low photochemical reactivity but is a powerful greenhouse gas. Therefore, exhaust emissions of unburned methane from natural-gas vehicles are of particular concern. This laboratory reactor study evaluates noble metal catalysts for their potential in the catalytic removal of methane from natural-gas vehicle exhaust. Temperature run-up experiments show that the methane oxidation activity decreases in the order Pd/Al2O3 > Rh/Al2O3 > Pt/Al2O3. Also, for all the noble metal catalysts studied, methane conversion can be maximized by controlling the O2 concentration of the feedstream at a point somewhat rich (reducing) of stoichiometry

  4. Experimental study on exhaust gas after treatment using limestone

    Sakhrieh Ahmad

    2013-01-01

    In this study a simple low-cost exhaust gas after-treatment filter using limestone was developed and tested on a four cylinder DI diesel engine coupled with dynamometer under variable engine running conditions. Limestone was placed in cast iron housing through which exhaust gases passes. The concentration of both carbon dioxide and nitrogen oxides were measured with and without the filter in place. It was found that both pollutants were decreased significantly when the filter is in plac...

  5. Low-pressure-ratio regenerative exhaust-heated gas turbine

    Tampe, L.A.; Frenkel, R.G.; Kowalick, D.J.; Nahatis, H.M.; Silverstein, S.M.; Wilson, D.G.

    1991-01-01

    A design study of coal-burning gas-turbine engines using the exhaust-heated cycle and state-of-the-art components has been completed. In addition, some initial experiments on a type of rotary ceramic-matrix regenerator that would be used to transfer heat from the products of coal combustion in the hot turbine exhaust to the cool compressed air have been conducted. Highly favorable results have been obtained on all aspects on which definite conclusions could be drawn.

  6. 40 CFR 86.511-90 - Exhaust gas analytical system.

    2010-07-01

    ... system for HC, CO and CO2, Figure F90-3, consists of a flame ionization detector (FID) (heated (235°±15... analytical system for methanol consists of a gas chromatograph (GC) equipped with a flame ionization detector...-dinitrophenylhydrazine (DNPH) derivatives using ultraviolet (UV) detection. The exhaust gas analytical system...

  7. Exhaust gas energy recovery system of pneumatic driving automotive engine

    Han Yongqiang; Sun Wenxu; Li Qinghua; Zhong Ming; Hao Wei; Du Wenchang

    2011-01-01

    Almost the same quantity to net output work of energy has been carried out and wasted by exhaust gas in typical automotive engine. Recovering the energy from exhaust gas and converting to mechanical energy will dramatically increase the heat efficiency and decrease the fuel consumption. With the increasing demand of fuel conservation, exhaust gas energy recovery technologies have been a hot topic. At present, many researches have been focused on heating or cooling the cab, mechanical energy using and thermo-electronic converting. Unfortunately, the complicated transmission of mechanical energy using and the depressed efficiency of thermo-electronic converting restrict their widely applying. In this paper, a kind of exhaust gas energy recovery system of pneumatic driving automotive engine, in which highly compressed air acts as energy storing and converting carrier, has been established. Pneumatic driving motor can produce moderate speed and high torque output, which is compatible for engine using. The feasibility has been certificated by GT-Power simulation and laboratory testes. The technologies about increasing recovery efficiency have been discussed in detail. The results demonstrated that the in parallel exhaust gas energy recovery system, which is similar to the compound turbo-charger structure can recovery 8 to 10 percent of rated power output. At last, a comprehensive system,which includes Rankine cycle based power wheel cycle unit etc. , has been introduced.

  8. Simulation of exhaust gas heat recovery from a spray dryer

    This study explored various alternatives in improving the energy utilization of spray drying process through the exhaust gas heat recovery. Extensible and user-friendly simulation code was written in Visual Basic for Applications within Microsoft Excel for this purpose. The effects of process parameters were analyzed on the energy efficiency and energy saving in the industrial-scale spray drying system with exhaust gas heat recovery in an air-to-air heat exchanger and in the system with partial recirculation of exhaust air. The spray dryer is equipped with an indirect heater for heating the drying air. The maximum gains of 16% in energy efficiency and 50% in energy saving were obtained for spray drying system equipped with heat exchanger for exhaust air heat recovery. In addition, 34% in energy efficiency and 61% in energy saving for system with recirculation of exhaust air in the present range of process parameters. The high energy efficiency was obtained during drying of large amount of dilute slurry. The energy saving was increased using the large amount of hot drying air. - Highlights: • We model industrial-scale spray drying process with the exhaust gas heat recovery. • We develop an Excel VBA computer program to simulate spray dryer with heat recovery. • We examine effects of process parameters on energy efficiency and energy saving. • High energy efficiency is obtained during drying of large amount of dilute slurry. • Energy saving is increased using the large amount of hot drying air

  9. Organic Rankine cycle for power recovery of exhaust flue gas

    To study the effects of different working fluids on the performance of organic Rankine cycle (ORC), three working fluids, a mixture that matches with heat source, a mixture that matches with heat sink and a pure working fluid, are selected in this paper. Thermodynamic models were built in Matlab together with REFPROP, with which, the physical properties of the selected working fluids can be acquired. Heat source of the ORC system is the exhaust flue gas of boiler in a 240 MW pulverized coal-fired power plant. Some indicators such as thermal efficiency, inlet temperature of expander, superheat degree, mass flow, volumetric flow, and exergy destruction distribution, as well as the influence of recuperator are studied. The analytical results show that the mixture that matches with heat sink has the greatest efficiency and the mixture that matches with heat source has the lowest superheat degree. The rate of heat exchanged in recuperator to that in evaporator has a maximum value with evaporating pressure. There exists no optimal working fluid for all indicators (thermal efficiency, heat exchanger area, mass flow and volumetric flow etc.). An appropriate working fluid should be chosen by taking both investment cost and power generating benefits into account. The cost-benefit ratio of the proposed ORC plant was evaluated either. - Highlights: • Three types of working fluids are selected for ORC using exhaust flue gas. • The mixture that matches with heat sink has the greatest efficiency. • The mixture that matches with heat source has the lowest superheat degree. • There does not exist a working fluid that satisfies all the indicators

  10. Novel catalytic converter for natural gas powered diesel engines to meet stringent exhaust emission regulations

    Zheng, M.; Mirosh, E.A. [Alternative Fuel Systems Inc. (Canada); Matros, Yu.S.; Bunimovich, G.A.; Strots, V.O. [Matros Technologies Inc. (United States); Sallamie, N.; Checkel, M.D. [Alberta Univ. (Canada); Windawi, H. [Johnson Matthey (United States)

    1998-12-31

    The implementation of stringent exhaust emission regulations has led to the development of natural gas powered dual fuel systems with electronic multiport injection. The high compression ratio of the baseline diesel engine was maintained to keep the high thermal efficiency of diesel cycles. The dual fuel system is mainly powered by natural gas and ignited by a diesel pilot. Extensive experimental results indicate that the diesel dual fuel system provides simultaneous reductions in NO{sub x} and particulate emissions. The system also has low exhaust THC and CO under heavy-duty operations. With the combined use of exhaust gas recirculation and catalytic converter, low emission operation has been extended to a larger range, from medium to full loads for all testing speeds. However, conventional converters exhibit poor conversion efficiency at low engine loads due to the low exhaust temperature levels. This leads to increased exhaust emissions during low load operations, especially for the non-reactive hydrocarbons, specifically, methane. To solve this problem, a novel automotive exhaust gas aftertreatment system - the reversing flow catalytic converter - has been developed. The prototype Reversing Flow Converter (RFC) consists of a diversion flow valve and a catalytic monolith converter. The diversion valve periodically re-directs the engine exhaust flow through the catalyst in alternative directions. The duration of flow in each direction is determined by engine operating conditions to obtain an ideal temperature profile along the axis of the monolith. The catalytic converter was designed to have high methane conversion efficiency. Associated techniques, such as retarding fuel injection, exhaust gas recirculation, and the variation of diesel pilot to natural gas ratio, can be used to raise exhaust temperature and bring the catalytic converter to light-off temperatures quicker. Engine dynamometer tests showed that CO conversion rate was above 95% and CH{sub 4

  11. A method for removal of CO from exhaust gas using pulsed corona discharge.

    Li, X; Yang, L; Lei, Y; Wang, J; Lu, Y

    2000-10-01

    An experimental study of the oxidation of CO in exhaust gas from a motorcycle has been carried out using plasma chemical reactions in a pulsed corona discharge. In the process, some main parameters, such as the initial CO concentration, amplitude and frequency of pulses, residence time, reactor volume, and relative humidity (RH), as well as their effects on CO removal characteristics, were investigated. O3, which is beneficial to reducing CO, was produced during CO removal. When the exhaust gas was at ambient temperature, more than 80% CO removal efficiency was realized at an initial concentration of 288 ppm in a suitable range of the parameters. PMID:11288300

  12. An approach for exhaust gas energy recovery of internal combustion engine: Steam-assisted turbocharging

    Highlights: • The calculation method for SAT engine was developed and introduced. • SAT can effectively promote the low-speed performances of IC engine. • At 1500 r/min, intake pressure reaches target value and torque is increased by 25%. • The thermal efficiency of SAT engine only has a slight increase. - Abstract: An approach for IC engine exhaust gas energy recovery, named as steam-assisted turbocharging (SAT), is developed to assist the exhaust turbocharger. A steam generating plant is coupled to the exhaust turbocharged engine’s exhaust pipe, which uses the high-temperature exhaust gas to generate steam. The steam is injected into turbine inlet and used as the supplementary working medium for turbine. By this means, turbine output power and then boosting pressure can be promoted due to the increase of turbine working medium. To reveal the advantages and energy saving potentials of SAT, this concept was applied to an exhaust turbocharging engine, and a parameter analysis was carried out. Research results show that, SAT can effectively promote the low-speed performances of IC engine, and make the peak torque shift to low-speed area. At 1500 r/min, the intake gas pressure can reach the desired value and the torque can be increased by 25.0% over the exhaust turbocharging engine, while the pumping mean effective pressure (PMEP) and thermal efficiency only have a slight increase. At 1000 r/min, the improvement of IC engine performances is very limited due to the low exhaust gas energy

  13. 40 CFR 86.111-94 - Exhaust gas analytical system.

    2010-07-01

    ...(a) and 1 CFR part 51. (B) Copies may be inspected at U.S. EPA, OAR, 401 M St., SW., Washington, DC... 40 CFR 1065.275 for the determination of N2O (required for 2015 and later model year vehicles). A... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Exhaust gas analytical system....

  14. IC ENGINE SUPERCHARGING AND EXHAUST GAS RECIRCULATION USING JET COMPRESSOR

    Adhimoulame Kalaisselvane

    2010-01-01

    Full Text Available Supercharging is a process which is used to improve the performance of an engine by increasing the specific power output whereas exhaust gas recirculation reduces the NOx produced by engine because of supercharging. In a conventional engine, supercharger functions as a compressor for the forced induction of the charge taking mechanical power from the engine crankshaft. In this study, supercharging is achieved using a jet compressor. In the jet compressor, the exhaust gas is used as the motive stream and the atmospheric air as the propelled stream. When high pressure motive stream from the engine exhaust is expanded in the nozzle, a low pressure is created at the nozzle exit. Due to this low pressure, atmospheric air is sucked into the expansion chamber of the compressor, where it is mixed and pressurized with the motive stream. The pressure of the mixed stream is further increased in the diverging section of the jet compressor. A percentage volume of the pressurized air mixture is then inducted back into the engine as supercharged air and the balance is let out as exhaust. This process not only saves the mechanical power required for supercharging but also dilutes the constituents of the engine exhaust gas thereby reducing the emission and the noise level generated from the engine exhaust. The geometrical design parameters of the jet compressor were obtained by solving the governing equations using the method of constant rate of momentum change. Using the theoretical design parameters of the jet compressor, a computational fluid dinamics analysis using FLUENT software was made to evaluate the performance of the jet compressor for the application of supercharging an IC engine. This evaluation turned out to be an efficient diagnostic tool for determining performance optimization and design of the jet compressor. A jet compressor was also fabricated for the application of supercharging and its performance was studied.

  15. Estimating IC engine exhaust gas lambda and oxygen from the response of a universal exhaust gas oxygen sensor

    Universal exhaust gas oxygen sensors (UEGOs) are in widespread use in internal combustion engines where they are used to measure lambda (the non-dimensional air–fuel ratio) and oxygen concentration (XO2). The sensors are used on production engines and for research and development. In a previous paper, a model of the UEGO sensor was presented, based on a solution of the Stefan–Maxwell equations for an axisymmetric geometry, and it was shown that for a known gas composition, predictions of the sensor response agreed well with experiment. In the present paper, the more ‘practical’ problem is addressed: how well can such a model predict λ and XO2 based on the sensor response? For IC engine applications, a chemistry model is required in order to predict λ, and such a model is also desirable for an accurate prediction of XO2. A fast (matrix exponential) method of solving the Stefan–Maxwell equations is also introduced, which offers the possibility of a near real-time computation of λ and XO2, with application, for example, to bench instruments. Extensive results are presented showing how the interpretation of the UEGO response may be compromised by uncertainties. These uncertainties may relate not only to the sensor itself, such as temperature, pressure and mean pore diameter, but also the chemistry model. (paper)

  16. Experimental study on exhaust gas after treatment using limestone

    Sakhrieh Ahmad

    2013-01-01

    Full Text Available In this study a simple low-cost exhaust gas after-treatment filter using limestone was developed and tested on a four cylinder DI diesel engine coupled with dynamometer under variable engine running conditions. Limestone was placed in cast iron housing through which exhaust gases passes. The concentration of both carbon dioxide and nitrogen oxides were measured with and without the filter in place. It was found that both pollutants were decreased significantly when the filter is in place, with no increase in the fuel consumption rate.

  17. Test Program for High Efficiency Gas Turbine Exhaust Diffuser

    Norris, Thomas R.

    2009-12-31

    This research relates to improving the efficiency of flow in a turbine exhaust, and thus, that of the turbine and power plant. The Phase I SBIR project demonstrated the technical viability of “strutlets” to control stalls on a model diffuser strut. Strutlets are a novel flow-improving vane concept intended to improve the efficiency of flow in turbine exhausts. Strutlets can help reduce turbine back pressure, and incrementally improve turbine efficiency, increase power, and reduce greenhouse gas emmission. The long-term goal is a 0.5 percent improvement of each item, averaged over the US gas turbine fleet. The strutlets were tested in a physical scale model of a gas turbine exhaust diffuser. The test flow passage is a straight, annular diffuser with three sets of struts. At the end of Phase 1, the ability of strutlets to keep flow attached to struts was demonstrated, but the strutlet drag was too high for a net efficiency advantage. An independently sponsored followup project did develop a highly-modified low-drag strutlet. In combination with other flow improving vanes, complicance to the stated goals was demonstrated for for simple cycle power plants, and to most of the goals for combined cycle power plants using this particular exhaust geometry. Importantly, low frequency diffuser noise was reduced by 5 dB or more, compared to the baseline. Appolicability to other diffuser geometries is yet to be demonstrated.

  18. Electron beam treatment of exhaust gas with high NOx concentration

    Simulated exhaust gases with a high NOx concentration, ranging from 200 to 1700 ppmv, were irradiated by an electron beam from an accelerator. In the first part of this study, only exhaust gases were treated. Low NOx removal efficiencies were obtained for high NOx concentrations, even with high irradiation doses applied. In the second part of study, gaseous ammonia or/and vapor ethanol were added to the exhaust gas before its inlet to the plasma reactor. These additions significantly enhanced the NOx removal efficiency. The synergistic effect of high SO2 concentration on NOx removal was observed. The combination of electron beam treatment with the introduction of the above additions and with the performance of irradiation under optimal parameters ensured high NOx removal efficiency without the application of a solid-state catalyst. (paper)

  19. Power plant including an exhaust gas recirculation system for injecting recirculated exhaust gases in the fuel and compressed air of a gas turbine engine

    Anand, Ashok Kumar; Nagarjuna Reddy, Thirumala Reddy; Shaffer, Jason Brian; York, William David

    2014-05-13

    A power plant is provided and includes a gas turbine engine having a combustor in which compressed gas and fuel are mixed and combusted, first and second supply lines respectively coupled to the combustor and respectively configured to supply the compressed gas and the fuel to the combustor and an exhaust gas recirculation (EGR) system to re-circulate exhaust gas produced by the gas turbine engine toward the combustor. The EGR system is coupled to the first and second supply lines and configured to combine first and second portions of the re-circulated exhaust gas with the compressed gas and the fuel at the first and second supply lines, respectively.

  20. NOx Monitoring in Humid Exhaust Gas Using Non-Dispersive Infrared Spectroscopy

    Stolberg-Rohr, Thomine Kirstine

    This PhD thesis is concerned with the measurement of NOX in moist exhaust gas onboard ships using non-dispersive infrared (NDIR) spectroscopy. In such a measurement one of the major challenges is spectral interference from water vapour which is present in high concentrations in the exhaust. The Ph...... suggesting that it is possible but challenging to measure NOX in moist exhaust gas using NDIR. The characteristics of optical filters tend to change with temperature, and since this compromises the water signal balancing, much of the work presented in the thesis is devoted to the design of optical bandpass...... for the first time. Information about CO2 absorption and emission in combustion conditions is highly demanded for accurate modelling of heat transfer processes during combustion in large ship engines which in turn is crucial for understanding the formation of emission gasses, in particular NOx....

  1. 75 FR 82040 - Notice of Public Meeting on the International Maritime Organization Guidelines for Exhaust Gas...

    2010-12-29

    ... Exhaust Gas Cleaning Systems for Marine Engines To Comply with Annex VI to MARPOL 73/78 AGENCY: Coast... meeting on the International Maritime Organization guidelines for exhaust gas cleaning systems for marine...-543 policy letter 09-01 that provide guidance for exhaust gas cleaning systems under MARPOL Annex...

  2. High Temperature Resistant Exhaust Valve Spindle

    Bihlet, Uffe Ditlev

    O5 and Na2SO4 condense on the spindle, causing hot corrosion. Current industry standards can withstand service temperatures of up to 500°C for the spindle seat and 700°C for the spindle bottom. This project was tasked with increasing these temperatures 50°C each. Literature review as well as an in......-situ corrosion test revealed that the most resistant alloy in such an environment is Alloy 657 (Ni-based, 49 wt% Cr, 1.5 wt% Nb). This alloy is suitable for the spindle bottom, but not for the spindle seat, as it is too weak. Thermodynamic calculations suggested that it was possible to modify the chemistry of...... the current valve seat alloy, Alloy 718 (Ni-based, 19 wt% Cr, 18 wt% Fe, 5.1 wt% Nb, 3 wt% Mo, 1 wt% Ti and 0.6 wt% Al), and thereby to obtain a more hot corrosion resistant alloy. To validate these calculations, 16 Ni-based alloys, containing 40 wt% Cr and Nb, Ta and Ti in varying levels, were...

  3. High exhaust temperature, zoned, electrically-heated particulate matter filter

    Gonze, Eugene V.; Paratore, Jr., Michael J.; Bhatia, Garima

    2015-09-22

    A system includes a particulate matter (PM) filter, an electric heater, and a control circuit. The electric heater includes multiple zones, which each correspond to longitudinal zones along a length of the PM filter. A first zone includes multiple discontinuous sub-zones. The control circuit determines whether regeneration is needed based on an estimated level of loading of the PM filter and an exhaust flow rate. In response to a determination that regeneration is needed, the control circuit: controls an operating parameter of an engine to increase an exhaust temperature to a first temperature during a first period; after the first period, activates the first zone; deactivates the first zone in response to a minimum filter face temperature being reached; subsequent to deactivating the first zone, activates a second zone; and deactivates the second zone in response to the minimum filter face temperature being reached.

  4. Temperature optimisation of a diesel engine using exhaust gas heat recovery and thermal energy storage (Diesel engine with thermal energy storage)

    Kauranen, Pertti; Elonen, Tuomo; Wikström, Lisa; Heikkinen, Jorma; Laurikko, Juhani

    2009-01-01

    Abstract Modern automotive diesel engines are so energy efficient that they are heating up slowly and tend to run rather cold at subzero temperatures. The problem is especially severe in mail delivery operations where the average speed is low and the drive cycle includes plenty of idling. The problem is typically solved by adding a diesel fuelled additional engine heater which is used for the preheating of the engine during cold start and additional heating of the engine if the coo...

  5. Process and device for cleaning furnace exhaust gas in a vitrification plant

    The furnace exhaust gas produced during vitrification is cleaned of carried over dust particles in an exhaust gas cleaning stage using a washing liquid. In order to achieve a simplified process for dosing and exhaust gas cleaning, radioactive fission product solution is taken from the feed container as the washing liquid and is transported to the head of the exhaust gas cleaning stage. The fission product solution noting as washing liquid is returned to the feed container after passing through the exhaust gas cleaning stage. The furnace exhaust gas of the vitrification plant is taken through the exhaust gas cleaning stage in counterflow. The invention also concerns a device to carry out this process. (orig./HP)

  6. Exhaust gas bypass valve control for thermoelectric generator

    Reynolds, Michael G; Yang, Jihui; Meisner, Greogry P.; Stabler, Francis R.; De Bock, Hendrik Pieter Jacobus; Anderson, Todd Alan

    2012-09-04

    A method of controlling engine exhaust flow through at least one of an exhaust bypass and a thermoelectric device via a bypass valve is provided. The method includes: determining a mass flow of exhaust exiting an engine; determining a desired exhaust pressure based on the mass flow of exhaust; comparing the desired exhaust pressure to a determined exhaust pressure; and determining a bypass valve control value based on the comparing, wherein the bypass valve control value is used to control the bypass valve.

  7. Effect of exhaust gas recirculation on diesel engine nitrogen oxide reduction operating with jojoba methyl ester

    Saleh, H.E. [Mechanical Power Department, Faculty of Engineering, Mattaria, Helwan University, 9 k Eltaaweniat, Nasr Road, P.O. Box 11718, Cairo (Egypt)

    2009-10-15

    Jojoba methyl ester (JME) has been used as a renewable fuel in numerous studies evaluating its potential use in diesel engines. These studies showed that this fuel is good gas oil substitute but an increase in the nitrogenous oxides emissions was observed at all operating conditions. The aim of this study mainly was to quantify the efficiency of exhaust gas recirculation (EGR) when using JME fuel in a fully instrumented, two-cylinder, naturally aspirated, four-stroke direct injection diesel engine. The tests were carried out in three sections. Firstly, the measured performance and exhaust emissions of the diesel engine operating with diesel fuel and JME at various speeds under full load are determined and compared. Secondly, tests were performed at constant speed with two loads to investigate the EGR effect on engine performance and exhaust emissions including nitrogenous oxides (NO{sub x}), carbon monoxide (CO), unburned hydrocarbons (HC) and exhaust gas temperatures. Thirdly, the effect of cooled EGR with high ratio at full load on engine performance and emissions was examined. The results showed that EGR is an effective technique for reducing NO{sub x} emissions with JME fuel especially in light-duty diesel engines. With the application of the EGR method, the CO and HC concentration in the engine-out emissions increased. For all operating conditions, a better trade-off between HC, CO and NO{sub x} emissions can be attained within a limited EGR rate of 5-15% with very little economy penalty. (author)

  8. Parasitic load control system for exhaust temperature control

    Strauser, Aaron D.; Coleman, Gerald N.; Coldren, Dana R.

    2009-04-28

    A parasitic load control system is provided. The system may include an exhaust producing engine and a fuel pumping mechanism configured to pressurize fuel in a pressure chamber. The system may also include an injection valve configured to cause fuel pressure to build within the pressure chamber when in a first position and allow injection of fuel from the pressure chamber into one or more combustion chambers of the engine when in a second position. The system may further include a controller configured to independently regulate the pressure in the pressure chamber and the injection of fuel into the one or more combustion chambers, to increase a load on the fuel pumping mechanism, increasing parasitic load on the engine, thereby increasing a temperature of the exhaust produced by the engine.

  9. Evaluation of the necessity of exhaust gas recirculation employment for a methanol/diesel reactivity controlled compression ignition engine operated at medium loads

    Highlights: • Methanol fraction considerably affected the engine performance. • Exhaust gases had little effect on fuel efficiency at a fixed ignition timing. • Good performance was obtained without exhaust gases at low initial temperature. • The introduction of exhaust gases was essential when initial temperature is high. - Abstract: Three-dimensional computational fluid dynamics simulation was conducted to investigate the improvement of engine performance by managing exhaust gas recirculation rate and methanol fraction in a methanol/diesel reactivity controlled compression ignition engine. By defining fuel efficiency and ringing intensity as the restricted boundaries, the operating ranges of exhaust gas recirculation rate and methanol fraction under various initial temperatures were determined to simultaneously achieve high fuel economy and avoid engine knock. The results indicated that the fuel efficiency and ringing intensity were dominantly affected by the combustion phasing, and they was nearly insensitive to the variations of exhaust gas recirculation rate and initial temperature at a constant combustion phasing. The necessity of exhaust gas recirculation employment at medium loads was dependent on the level of initial temperature. When initial temperature was less than the critical value (380 K in this study), optimal engine performance could be achieved by only adopting high methanol fraction without introducing exhaust gas recirculation. Once initial temperature was beyond the critical value, exhaust gas recirculation was imperative to avoid excessive ringing intensity. Through simultaneously optimizing methanol fraction and exhaust gas recirculation rate, the combined strategy exhibited more advantages in fuel efficiency, nitrogen oxides, and ringing intensity under a wide range of initial temperature

  10. Exhaust Gas Recirculation in Gas Turbines for Reduction of CO2 Emissions; Combustion Testing with Focus on Stability and Emissions

    Røkke, Petter E.; Hustad, Johan E.

    2005-01-01

    Exhaust gas recirculation can be applied with the intention of reducing CO2 emissions. When a fraction of the exhaust gas is injected in the entry of a gas turbine, the amount of CO2 in the exhaust gas not being recirculated will be higher and less complicated to capture. However, with this change in combustion air composition, especially the reduced concentration of oxygen, the combustion process will be affected. The lower oxygen concentration decreases the stability and the increased amoun...

  11. Measurement of Gas-phase Acids in Diesel Exhaust

    Wentzell, J. J.; Liggio, J.; Li, S.; Vlasenko, A. L.; Staebler, R. M.; Brook, J.; Lu, G.; Poitras, M.; Chan, T.

    2012-12-01

    Gas-phase acids were measured using chemical ionization mass spectrometry (CIMS) as part of the Diesel Engine Emission Research Experiment (DEERE). The CIMS technique, utilizing acetate ion (CH3COO-) as a reagent ion, proved to be a rapid (measurements on the order of seconds) and sensitive (several counts/pptv) method of quantifying the acid emissions. Diluted diesel exhaust measurements were made from a Constant Volume Sampling dilution tunnel using a light duty (1.9L turbocharged Volkswagen Jetta TDI) diesel engine equipped with an OEM diesel oxidation catalyst and exhaust gas recirculation, mounted on an engine dynamometer. Acids measured included isocyanic, nitrous, nitric, propionic and sum of lactic and oxalic, as well as other unidentified compounds. Complimentary measurements of CO, CO2, Total Hydrocarbon (THC), and NOx, were also performed. Several engine modes (different engine rpm and torque outputs) at steady state were examined to determine their effect on acid emissions. Emission rates with respect to NOx and fuel based emission factors were determined. Measurements of HONO fuel emission factors agree well with real-world measurements within a traffic tunnel.1 The first estimate of isocyanic acid emission factors from a diesel engine is reported, and suggests that the emission of this highly toxic compound in diesel exhaust should not be ignored. 1. Kurtenbach, R., Becker, K. H., Gomes, J. A. G., Kleffmann, J.,Lorzer, J. C., Spittler, M., Wiesen, P., Ackermann, R., Geyer, A.,and Platt, U.: Investigations of emissions and heterogeneous formation of HONO in a road traffic tunnel, Atmos. Environ., 35, 3385-3394, doi:10.1016/S1352-2310(01)00138-8, 2001.

  12. Exhaust Gas Recirculation in Gas Turbines for Reduction of CO2 Emissions; Combustion Testing with Focus on Stability and Emissions

    Johan E. Hustad

    2005-12-01

    Full Text Available Exhaust gas recirculation can be applied with the intention of reducing CO2 emissions. When a fraction of the exhaust gas is injected in the entry of a gas turbine, the amount of CO2 in the exhaust gas not being recirculated will be higher and less complicated to capture. However, with this change in combustion air composition, especially the reduced concentration of oxygen, the combustion process will be affected. The lower oxygen concentration decreases the stability and the increased amount of CO2, H2O and N2 will decrease the combustion temperature and thus, the NOx emissions. Testing has been performed on a 65 kW gas turbine combustor, to investigate the effect of adding N2, CO2 and O2 in the combustion process, with focus on stability and emissions of NOx. Results show that adding N2 and CO2 decreases the NOx emissions, whereas O2 addition increases the NOx emissions. The tests have been performed both in a diffusion flame (pilot burner and a premixed flame (main burner, and for additives being injected with the fuel or with the air stream. Addition into the fuel stream is proven to affect the NOx emissions the most. The stability limits of the flames are indicated with respect to mass-based additive-to-fuel ratios.

  13. Cytotoxicity of the exhaust gas from a thermal reactor of MSWI baghouse ash.

    Huang, Wu-Jang; Shue, Meei-Fang

    2007-10-01

    Baghouse ash from municipal solid waste incineration (MSWI) plant was heated from 25 degrees C to 800 degrees C under nitrogen in a fixed-bed reactor. The exhaust gas was passed sequentially through water, acetone and cyclohexane. The cytotoxicity testing of the three adsorbates was done with the MRC-5 cell line and the percentage cell survival was determined by 3-(4,5-dimethylthiazol-2-yl)-5(3-carboxymethoxyphenol)-2-(4-sulfophenyl)-2H-tetrazolium (MTS) analysis. The highest level of toxicity of the exhaust gas was observed at 500 degrees C. The total cytotoxicity of the three adsorbates at any treatment temperature was found to be a function of the sum of organic carbon (TOC), inorganic carbon (IC) and molecular chlorine (Cl(2)), of which, molecular chlorine was quantitatively the greatest. PMID:17585993

  14. An experimental study on the effects of the thermal barrier plating over engine fuel consumption exhaust temperature and emissions

    Gürbüz, Hüseyin; Gökkaya, Hasan

    2014-01-01

    The aim of this study, the combustion chamber elements of a one-cylinder diesel engine which is air-cooled, single-cylinder, direct injection, 4-stroke and starter motor were plated with thermal barrier plating and tested with diesel fuel between the speeds of 1600 1/min to 3200 1/min and determined the effects of the thermal barrier plating on the engine exhaust gas temperature, emissions and fuel consumption. Increase in the temperature of the exhaust gas, decrease in HC and CO emissions th...

  15. An experimental study on the effects of the thermal barrier plating over engine fuel consumption exhaust temperature and emissions

    Hüseyin Gürbüz

    2014-01-01

    Full Text Available The aim of this study, the combustion chamber elements of a one-cylinder diesel engine which is air-cooled, single-cylinder, direct injection, 4-stroke and starter motor were plated with thermal barrier plating and tested with diesel fuel between the speeds of 1600 1/min to 3200 1/min and determined the effects of the thermal barrier plating on the engine exhaust gas temperature, emissions and fuel consumption. Increase in the temperature of the exhaust gas, decrease in HC and CO emissions that are harmful to the environment and living things and improvement in fuel consumption were observed.

  16. Steady-state modelling of the universal exhaust gas oxygen (UEGO) sensor

    The universal exhaust gas oxygen (UEGO) sensor is a well-established device which was developed for the measurement of relative air fuel ratio in internal combustion engines. There is, however, little information available which allows for the prediction of the UEGO's behaviour when exposed to arbitrary gas mixtures, pressures and temperatures. Here we present a steady-state model for the sensor, based on a solution of the Stefan–Maxwell equation, and which includes a momentum balance. The response of the sensor is dominated by a diffusion barrier, which controls the rate of diffusion of gas species between the exhaust and a cavity. Determination of the diffusion barrier characteristics, especially the mean pore size, porosity and tortuosity, is essential for the purposes of modelling, and a measurement technique based on identification of the sensor pressure giving zero temperature sensitivity is shown to be a convenient method of achieving this. The model, suitably calibrated, is shown to make good predictions of sensor behaviour for large variations of pressure, temperature and gas composition. (paper)

  17. An experimental study on the effects of exhaust gas on spruce (Picea abies L. Karst.)

    Hautala, E.L.; Holopainen, J.; Kaerenlampi, L. [Kuopio Univ. (Finland). Dept. of Ecology and Environmental Science; Surakka, J.; Ruuskanen, J. [Kuopio Univ. (Finland). Dept. of Environmental Sciences

    1995-12-31

    Motor vehicle exhausts are significant contributors to air pollution. Besides fine particles and inorganic gases, like CO, SO{sub 2} and NO{sub x}, exhaust gas contains a large group of aromatic hydrocarbon compounds, many of which are phytotoxic. In field studies, exhausts are found to have both direct and indirect harmful effects on roadside plants. However, only few experimental studies have been made about the effects of exhaust gas emissions on coniferous trees. The aim of this study was to survey the effects of exhausts on spruce (Picea abies L. Karst.) in standardized conditions. The concentrations of major exhaust gas components in the chamber atmosphere were detected simultaneously. The effects of exhaust on epistomatal waxes of first-year spruce needles are described. (author)

  18. Effect of Fuel-Air Ratio, Inlet Temperature, and Exhaust Pressure on Detonation

    Taylor, E S; Leary, W A; Diver, J R

    1940-01-01

    An accurate determination of the end-gas condition was attempted by applying a refined method of analysis to experimental results. The results are compared with those obtained in Technical Report no. 655. The experimental technique employed afforded excellent control over the engine variables and unusual cyclic reproducibility. This, in conjunction with the new analysis, made possible the determination of the state of the end-gas at any instant to a fair degree of precision. Results showed that for any given maximum pressure the maximum permissible end-gas temperature increased as the fuel-air ratio was increased. The tendency to detonate was slightly reduced by an increase in residual gas content resulting from an increase in exhaust backpressure with inlet pressure constant.

  19. Removal of methane from compressed natural gas fueled vehicle exhaust

    The objective of this paper is to investigate the modes of methane (CH4) removal from simulated compressed natural gas (CNG) fueled vehicle exhaust under net oxidizing, net reducing, and stoichiometric conditions. Model reaction studies were conducted. The results suggest that the oxidation of methane with oxygen contributes to the removal of methane under net oxidizing conditions. In contrast, the oxidation of methane with oxygen as well as nitric oxide contributes to its removal under net reducing conditions. The steam reforming reaction does not significantly contribute to the removal of methane. The methane conversions under net reducing conditions are higher than those observed under net oxidizing conditions. The study shows that the presence of carbon monoxide in the feed gas leads to a gradual decrease in the methane conversion with increasing redox ratio, under net oxidizing conditions. a minimum in methane conversion is observed at a redox ratio of 0. 8. The higher activity for the methane-oxygen reaction resulting from a lowering in the overall oxidation state of palladium and the contribution of the methane-nitric oxide reaction toward the removal of CH4 appear to account for the higher CH4 conversions observed under net reducing conditions

  20. Neuralfussy multivariable control applied to the control of velocity, power, and exhaust gas temperature of a turbo gas unit; Control neurodifuso multivariable aplicado al control de velocidad, potencia y temperatura de gases de escape de una unidad turbogas

    Segura Ozuna, Victor Octavio

    2004-11-15

    The electric power demand in Mexico has forced to the electric sector to be in a constant search of methods and systems that, among other objectives, improve the operation of the generating power stations of electric power continually. As part of their mission, the Electrical Research Institute (IIE) has promoted and leaning the applied research and the technological development to improve the indexes of security, readiness, dependability, efficiency and durability of central generating by means of the development and the installation of big digital systems of information and control. At the present time, inside the scheme of electric power generation, the gas turbine (UTG) represent 7% of the generation of the national electric sector [1]. These units have become the dominant way of the new electric generation in the U.S, either in simple cycle or combined. The above-mentioned, is attributable at less installation cost for generated kilowatt, to the shortest construction programs, at first floor levels of emission of pollutants and competitive operation costs. The control system of the gas turbine is based on conventional control algorithms of the type PI [2]. This control scheme is dedicated for regulation tasks and rejection to interferences, and it doesn't stop pursuit of reference points. The controllers act all on a control valve, that which represents a strong interaction among the same ones, for example an adjustment in the parameters of the algorithm of the digital PI of temperature, it can improve their acting but it can also affect the acting of the speed control or that of power. The gas turbine presents a non lineal behavior and variant in the time, mainly in the starting stage where several important disturbances are presented. At the moment, the controllers used in the scheme of control of the turbines are lineal, which are syntonized for a specific operation point and they are conserved this way by indefinite time. In this thesis the

  1. Exhaust bypass flow control for exhaust heat recovery

    Reynolds, Michael G.

    2015-09-22

    An exhaust system for an engine comprises an exhaust heat recovery apparatus configured to receive exhaust gas from the engine and comprises a first flow passage in fluid communication with the exhaust gas and a second flow passage in fluid communication with the exhaust gas. A heat exchanger/energy recovery unit is disposed in the second flow passage and has a working fluid circulating therethrough for exchange of heat from the exhaust gas to the working fluid. A control valve is disposed downstream of the first and the second flow passages in a low temperature region of the exhaust heat recovery apparatus to direct exhaust gas through the first flow passage or the second flow passage.

  2. Temperature monitoring of vehicle engine exhaust gases under vibration condition using optical fibre temperature sensor systems

    Two optical approaches, comprising and contracting both the fluorescence decay lifetime and the fibre Bragg grating (FBG) methods, were developed and evaluated for temperature monitoring of exhaust gases for use on a vehicle engine. The FBGs used in the system were written into specially designed Bi-Ge co-doped photosensitive fibres, to enable them to sustain high temperatures to over 8000C, which is far beyond that of FBGs written into most commercial photosensitive fibres. The sensors were subjected to a range of vibration tests, as a part of an optical exhaust monitoring network under development, and results from the test carried out are reported

  3. Analysis of the reusability of the energy of the exhaust gas from the calciner for the production of carbon

    A calciner is used to produce carbon from anthracite coal. In its working process, a significant amount of energy is lost through its exhaust gas. How much energy can be recovered from the exhaust gas becomes important. To answer this question a method to determine the mass flow rate and the composition of the exhaust gas from a calciner is developed, and a combustion model based on well-stirred reactor is used to obtain the suitable combustor parameters and the amount of the chemical energy which can be released in combustion. As an example to verify the method and the model, the energy utilization ratio of a calciner with power of 1250 kW is investigated. The results show that the method can determine the mass flow rate and the composition of the exhaust gas, and the combustion model is suitable for obtaining reasonable results in determining the volume and the heat duty of the combustor, the air–fuel ratio, and the amount of the chemical energy released. For a calciner with power of 1250 kW, when the temperature of the tail gas after combustion reaches to 135 °C, the energy utilization ratio of the calciner is calculated to be around 77%. - Highlights: • A method obtaining the mass balance of exhaust gas from calciner is reported. • A combustion model obtaining combustion behavior of the exhaust gas is reported. • Determining the energy utilization ratio of a typical calciner is demonstrated. • The energy utilization ratio of a typical calciner is about 77%

  4. Platform for a Hydrocarbon Exhaust Gas Sensor Utilizing a Pumping Cell and a Conductometric Sensor

    Ralf Moos; Kerstin Wiesner; Diana Biskupski; Andrea Geupel; Maximilian Fleischer

    2009-01-01

    Very often, high-temperature operated gas sensors are cross-sensitive to oxygen and/or they cannot be operated in oxygen-deficient (rich) atmospheres. For instance, some metal oxides like Ga2O3 or doped SrTiO3 are excellent materials for conductometric hydrocarbon detection in the rough atmosphere of automotive exhausts, but have to be operated preferably at a constant oxygen concentration. We propose a modular sensor platform that combines a conductometric two-sensor-setup with an electroche...

  5. Dual-purpose power plants, experiences with exhaust gas purification plants

    From 1984 to 1988, the research and development project ''pollutant reduction for exhaust gases from heat production systems'' sponsored by the Federal Ministry of Research and Technology (BMFT) has been carried out by TUeV in Bavaria. This project was to show the state of exhaust gas technology for small and medium-sized plants (boilers and motoric heat generators). When publishing the final report, no positive balance could be given. Based on the results, the succession project ''Exhaust gas purification plants in field test'' (ARIF) has been started. This project has the following objectives: -Measuring technical investigation of the exhaust gas purification of motoric driven heat generator systems in field test. - Suitability of hand measuring devices for emissions for a discontinuous control of the exhaust gas purification plat by the operator. - Control of new methods regarding pollutant reduction for motoric and conventional heat generators. (orig.)

  6. NOVEL GAS SENSORS FOR HIGH-TEMPERATURE FOSSIL FUEL APPLICATIONS

    Palitha Jayaweera

    2004-05-01

    SRI is developing ceramic-based microsensors for detection of exhaust gases such as NO, NO{sub 2}, and CO in advanced combustion and gasification systems. The sensors detect the electrochemical activity of the exhaust gas species on catalytic electrodes and are designed to operate at high temperatures, elevated pressures, and corrosive environments typical of large power generation exhausts. Under this research project we are developing sensors for multiple gas detection in a single package along with data acquisition and control software and hardware. The sensor package can be easily integrated into online monitoring systems for active emission control. This report details the research activities performed from October 2003 to April 2004.

  7. Laboratory Scale of Liquid Coal Fuel Combustion Process and Exhaust Gas Formation

    Kartika K. Hendratna

    2010-01-01

    Full Text Available Problem statement: Much research of coal has been already undertaken to ascertain the possibilities of coal being used as substitute for heavy fuel oil in the transportation sector. The effects of using coal as transportation fuel to the environment must also be considered. This study will review several aspects of the coal oil combustion process including combustion behavior, flame stability, some emissions from exhaust gas; CO, NOx and the particulate matter in a well insulated laboratory scale furnace for more stable of combustion. Approach: New way for preparation for liquid coal oil steady combustion on a 2.75 m horizontal boiler with four annular segment tubes, a water jacket system and a system for measurement of water temperature inside was archived. Data was gained by applying liquid coal in the experiment. Detailed preparation and setting for steady combustion of coal oil and formation of the exhaust gas were discussed based on data sampling from four sample points in each centre of the angular tube segments. Results: Preparation for coal oil combustion is an important point in the successful of combustion. Heating coal fuel to than 100°C, heating the fuel line to the same temperature and providing enough air pressure for atomization of coal oil until 0.1 MPa allows coal fuel smoothly atomized in the semi gas phase. There was enough of air combustion via a blower with 4500 L min-1 of flow rate and a 24 L min-1 of water flow rate in the water jacket transforms the energy of the fuel to the heat. Uncolored of the exhaust gas and the physical inspection describes the completion of combustion. This result close-relates with the pollutants formation in the exhaust gas. Conclusion: By conducting a deep research process, there is a chance for the substitute of heavy fuel oil with liquid coal fuel with no special treatment needed in combustion process without ignoring the contribution of the combustion results as an environmental problem.

  8. Test procedures for measuring exhaust emissions from natural gas transmission engines

    This paper reports on the measurement of exhaust components from large natural gas transmission engines involves collection of the exhaust sample, transfer of the sample to the analytical instrumentation, measurement of individual component concentrations, and calculations of emission results in terms of mass, fuel specific, and brake specific rates. The major exhaust components measured include nitrogen oxides (NOx), total hydrocarbons (THC), carbon dioxide (CO2), carbon monoxide (CO), and oxygen (O2). Collection of the exhaust sample requires proper probe design and placement in the exhaust system. Transfer of the sample to the analytical instruments must maintain sample integrity from the point where the sample is removed from the exhaust stream to the point at which the sample enters the instrument for analysis. Various analytical techniques are used to measure the exhaust emission concentrations

  9. Real-time exhaust gas modular flowmeter and emissions reporting system for mobile apparatus

    Breton, Leo Alphonse Gerard (Inventor)

    2002-01-01

    A real-time emissions reporting system includes an instrument module adapted to be detachably connected to the exhaust pipe of a combustion engine to provide for flow of exhaust gas therethrough. The instrument module includes a differential pressure probe which allows for determination of flow rate of the exhaust gas and a gas sampling tube for continuously feeding a sample of the exhaust gas to a gas analyzer or a mounting location for a non-sampling gas analyzer. In addition to the module, the emissions reporting system also includes an elastomeric boot for detachably connecting the module to the exhaust pipe of the combustion engine, a gas analyzer for receiving and analyzing gases sampled within the module and a computer for calculating pollutant mass flow rates based on concentrations detected by the gas analyzer and the detected flowrate of the exhaust gas. The system may also include a particulate matter detector with a second gas sampling tube feeding same mounted within the instrument module.

  10. Development of exhaust gas treatment technologies for environment protection

    Full text: The emission of carbon dioxide (CO2) and other pollutants which result from burning fossil fuels has been identified as the major contributor to global warming and climate change. However, for the immediate term over the next 10 - 20 years at least, the world will continue to rely on fossil fuels as the source of primary energy. The challenge for the fossil fuel industry is to find cost-effective solutions that will reduce the release of CO2 and other pollutants into the atmosphere. The focus of this paper is on the ability to treat the exhaust gas from fossil fuel power plants in order to capture and store the CO2 and remove other pollutants such as SOx and NOx which are released in the atmosphere. In summary, capture/separation costs represent the largest financial impediment for this types of plants. Hence, efficient, cost-effective capture/separation technologies will need to be developed in order to allow their large-scale use. (authors)

  11. Field-effect gas sensors and their application in exhaust treatment systems; Feldeffekt-Gassensoren und ihre Anwendung in Abgasnachbehandlungssystemen

    Schalwig, Jan

    2002-07-01

    Tightening environmental constraints on exhaust gas emissions of gasoline and Diesel engines led to a growing interest in new and highly sophisticated gas sensors. Such sensors will be required in future exhaust gas aftertreatment systems for the selective real time detection of pollutants such as nitric oxides, hydrocarbons and carbon monoxide. Restrictions on cost and device dimensions imposed by the automobile industry make semiconductor gas sensors promising candidates for the realization of cheap and small-size sensor devices. This work deals with semiconductor field effect devices with catalytically active platinum (Pt) electrodes and potential applications of such devices in automotive exhaust gas aftertreatment systems. To allow for continuous operation at high temperatures, silicon carbide (SiC) and group III-nitrides such as GaN and AlGaN were used as semiconductor materials. Different devices have been realized with such materials: SiC based MOS capacitors (MOSiC), GaN Schottky diodes and GaN/AlGaN high electron mobility transistors (HEMT). The principle feasibility of SiC and GaN based field effect gas sensors for automotive applications was tested under laboratory conditions using synthetic gas mixtures. Exhaust gas components such as carbon monoxide (CO), nitric oxides (NO and NO{sub 2}), various saturated and unsaturated hydro-carbons as well as water vapor, oxygen (O{sub 2}) and hydrogen (H{sub 2}) were used as test gases in appropriate concentrations with the sensor devices being operated in a range of temperatures extending from room temperature up to 600{sup o}C. (orig.)

  12. Implementation of Exhaust Gas Recirculation for Double Stage Waste Heat Recovery System on Large Container Vessel

    Andreasen, Morten; Marissal, Matthieu; Sørensen, Kim;

    2014-01-01

    Concerned to push ships to have a lower impact on the environment, the International Maritime Organization are implementing stricter regulation of NOx and SOx emissions, called Tier III, within emission control areas (ECAs). Waste Heat Recovery Systems (WHRS) on container ships consist of...... recovering some of the waste heat from the exhaust gas. This heat is converted into electrical energy used on-board instead of using auxiliary engines. Exhaust Gas Recirculation (EGR) systems, are recirculating a part of the exhaust gas through the engine combustion chamber to reduce emissions. WHRS combined...

  13. Evaluating tractor performance and exhaust gas emissions using biodiesel from cotton seed oil

    Alternative fuels for diesel engines, such as biodiesel, have attracted much attention recently due to increasing fuel prices and the imperative to reduce emissions. The exhaust gas emissions from tractors and other agricultural machinery make a significant contribution to these emissions. The use of biodiesel in internal combustion engines (ICE) has been reported to give comparable performance to conventional diesel (CD), but with generally lower emissions. There is however, contradictory evidence of NO emissions being both higher and lower from the use of biodiesel. In this work, agriculture tractor engine performance and its emission using both CD and biodiesel from cotton seed oil (CSO-B20) mixed at a 20% blend ration has been evaluated and compared. The PTO test results showed comparable exhaust emissions between CD and CSO-B20. However, the use of CSO-B20 led to reductions in the thermal efficiency and exhaust temperature and an increase in the brake specific fuel consumption (BSFC), when compared to CD.

  14. 40 CFR 91.420 - CVS concept of exhaust gas sampling system.

    2010-07-01

    ... 40 Protection of Environment 20 2010-07-01 2010-07-01 false CVS concept of exhaust gas sampling system. 91.420 Section 91.420 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... mixing tunnel into which the engine exhaust and dilutant (background) air are dumped; a dilute...

  15. 40 CFR 90.420 - CVS concept of exhaust gas sampling system.

    2010-07-01

    ... 40 Protection of Environment 20 2010-07-01 2010-07-01 false CVS concept of exhaust gas sampling system. 90.420 Section 90.420 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR... consist of: a mixing tunnel into which the engine exhaust and dilutant (background) air are dumped;...

  16. Evaluation of SI engine exhaust gas emissions upstream and downstream of the catalytic converter

    Silva, C.M.; Costa, M.; Farias, T.L. [Mechanical Engineering Department, Instituto Superior Tecnico, Technical University of Lisbon, Avenida Rovisco Pais, 1049-001 Lisbon (Portugal); Santos, H. [Escola Superior de Tecnologia e Gestao, Instituto Politecnico de Leiria, Leiria (Portugal)

    2006-11-15

    The conversion efficiency of a catalytic converter, mounted on a vehicle equipped with a 2.8l spark ignition engine, was evaluated under steady state operating conditions. The inlet and outlet chemical species concentration, temperature and air fuel ratio (A/F) were measured as a function of the brake mean effective pressure (BMEP) and engine speed (rpm). Oil temperature, coolant temperature, brake power and spark advance were also monitored. In parallel, a mathematical model for the catalytic converter has been developed. The main inputs of the model are the temperature, flow rate, chemical species mass flow and local A/F ratio as measured at the catalyst inlet section. The main conclusions are: (i) the exhaust gas and substrate wall temperatures at the catalyst outlet increase with BMEP and rpm; (ii) the HC conversion efficiency increases with the value of BMEP up to a maximum beyond which it decreases; (iii) the CO conversion efficiencies typically increase with BMEP; (iv) the NO{sub x} conversion efficiency remains nearly constant regardless of BMEP and rpm; (v) except for idle, the NO{sub x} conversion efficiency is typically the highest, followed in turn by the CO and HC conversion efficiencies; (vi) conversion efficiencies are lower for idle conditions, which can be a problem under traffic conditions where idle is a common situation; (vii) regardless of rpm and load, for the same flow rate the conversion efficiency is about the same; (viii) the model predictions slightly over estimate the exhaust gas temperature data at the catalyst outlet section with the observed differences decreasing with BMEP and engine speed; (ix) in general, the model predictions of the conversion efficiencies are satisfactory. (author)

  17. Simulation and evaluation of a CCHP system with exhaust gas deep-recovery and thermoelectric generator

    Highlights: • Exhaust gas deep-recovery and thermoelectric generator are applied in CCHP system. • Electric output of TEG changes from 0.231 kW to 1.18 kW. • Total recoverable waste heat increases by 13–16%. • ESR, CSR and PEE are improved to 0.304, 0.417, and 0.944, respectively. • The total investment increment of system is about 11%. - Abstract: Combined cooling, heating and power (CCHP) systems are thought to be highly efficient in energy utilization. But there are still potentials to further improve system performance. This work proposed a CCHP system based on internal combustion engine (ICE) for power generation, refrigeration and domestic hot water production. Thermoelectric generator (TEG) and condensing heat exchanger are applied to efficiently recover the exhaust gas waste heat of ICE. All the energy flows are designed based on energy cascading utilization principle. Basing on the test results of a 16 kW ICE, CCHP system characteristics are investigated by simulation from idling condition to full load condition. Especially, the part load performance of TEG and absorption chiller are simulated and discussed. The feasible operating zone of ICE and feed water flow rate are figured out to keep the domestic hot water temperature within a certain range. Results show that the primary energy efficiency of system can reach 0.944, thanks to the condensing heat recovery from exhaust gas. The primary energy saving ratio and cost saving ratio can reach 0.304 and 0.417, respectively. Considering some more equipment is incorporated, the total investment increment is about 11.1%

  18. Portable Gas Analyzer Based on Fourier Transform Infrared Spectrometer for Patrolling and Examining Gas Exhaust

    Yuntao Liang; Xiaojun Tang; Xuliang Zhang; Fuchao Tian; Yong Sun; Haozhe Dong

    2015-01-01

    Aimed at monitoring emission of organic gases such as CH4, C2H6, C3H8, iso-C4H10, n-C4H10, C2H4, C3H6, C2H2, CO, and CO2, from coal mines, petroleum refineries, and other plants, a Fourier Transform Infrared (FT-IR) spectrometer was used to develop a portable gas analyzer for patrolling and examining gas exhaust. Firstly, structure of the instrument was introduced. Then, a spectral analysis approach was presented. Finally, instrument was tested with standard gases and with actual gases emitte...

  19. Fusion plasma exhaust: the interaction of hot plasma with cold gas and solid surfaces

    The power fluxes along magnetic field lines in the exhaust of a fusion device based on the tokamak are very high and are made worse by instabilities of the plasma edge region. They would result in the rapid erosion of solid target surfaces by sputtering and evaporation. The use of a gas target to absorb the heat load is potentially an attractive solution to this problem. The interaction zone is an example of a system in steady state but far from thermodynamic equilibrium and has many generic properties in common with sources of low temperature plasma used in industrial applications. Recent work to elucidate the interaction of a hot plasma stream with a cold gas will be described and the problems associated with modelling such processes will be outlined

  20. Mutagenicity of diesel exhaust particle extracts: influence of driving cycle and environmental temperature.

    Clark, C R; Dutcher, J S; Brooks, A L; McClellan, R O; Marshall, W F; Naman, T M

    1982-01-01

    General Motors and Volkswagen diesel passenger cars (1980 and 1981 model year) were operated on a climate controlled chassis dynomometer and the particulate portion of the exhaust was collected on high volume filters. Dichloromethane extracts of the exhaust particles (soot) collected while the cars were operated under simulated highway, urban and congested urban driving cycles were assayed for mutagenicity in Salmonella strains TA-98 and TA-100. Driving pattern did not significantly influence the mutagenic potency of the exhaust particle extracts or estimates of the amount of mutagenicity emitted from the exhaust despite large differences in particle emission rates and extractable fraction of the particles. Mutagenicity of extracts of exhaust particles collected while the vehicles were operated at test chamber temperatures of 25, 50, 75 and 100 degrees F were also very similar. The results suggest that driving pattern and environmental temperature do not significantly alter the emission of genotoxic combustion products from the exhaust. PMID:6193022

  1. Selection оf Parameters for System of Diesel Engine Exhaust Gas Recirculation

    G. M. Kukharionok

    2014-01-01

    Full Text Available The paper presents research results of various methods for recirculation of diesel engine exhaust gases. An influence of recirculation parameters on economic and ecological diesel engine characteristics has been evaluated in the paper. The paper considers an influence of turbocharger configuration on the intensity of gas recirculation. Specific features of the recirculation system operation in dynamic modes have been shown in the paper. The paper provides recommendations for selection of a diesel engine exhaust gas recirculation system.

  2. In optics humidity compensation in NDIR exhaust gas measurements of NO2

    Stolberg-Rohr, Thomine Kirstine; Buchner, Rainer; Clausen, Sønnik;

    2015-01-01

    NDIR is proposed for monitoring of air pollutants emitted by ship engines. Careful optical filtering overcomes the challenge of optical detection of NO2 in humid exhaust gas, despite spectroscopic overlap with the water vapour band. © 2014 OSA.......NDIR is proposed for monitoring of air pollutants emitted by ship engines. Careful optical filtering overcomes the challenge of optical detection of NO2 in humid exhaust gas, despite spectroscopic overlap with the water vapour band. © 2014 OSA....

  3. Design review report for the RMCS exhauster modifications for flammable gas tanks

    Corbett, J.E., Westinghouse Hanford

    1996-08-27

    This report documents the completion of the formal design review for the Rotary Mode Core Sampling (RMCS) Exhauster modifications for flammable gas tanks. The RMCS Exhauster modifications are intended to support core sampling operations in waste tanks requiring flammable gas controls. The objective of this review was to approve Engineering Change Orders and new drawings, at the 100% design completion state. The conclusion reached by the review committee was that the design was acceptable and efforts should continue toward fabrication and delivery.

  4. Nonlinear Adaptive Control of Exhaust Gas Recirculation for Large Diesel Engines

    Nielsen, Kræn V.; Blanke, Mogens; Vejlgaard-Laursen, Morten

    2015-01-01

    A nonlinear adaptive controller is proposed for the exhaust gas recirculation system on large two-stroke diesel engines. The control design is based on a control oriented model of the nonlinear dynamics at hand that incorporates fuel flow and turbocharger speed changes as known disturbances to the exhaust gas recirculation. The paper provides proof of exponential stability for closed loop control of the model given. Difficulties in the system include that certain disturbance levels will make ...

  5. Gas separation process using membranes with permeate sweep to remove CO.sub.2 from gaseous fuel combustion exhaust

    Wijmans Johannes G.; Merkel, Timothy C.; Baker, Richard W.

    2012-05-15

    A gas separation process for treating exhaust gases from the combustion of gaseous fuels, and gaseous fuel combustion processes including such gas separation. The invention involves routing a first portion of the exhaust stream to a carbon dioxide capture step, while simultaneously flowing a second portion of the exhaust gas stream across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas back to the combustor.

  6. Portable Gas Analyzer Based on Fourier Transform Infrared Spectrometer for Patrolling and Examining Gas Exhaust

    Yuntao Liang

    2015-01-01

    Full Text Available Aimed at monitoring emission of organic gases such as CH4, C2H6, C3H8, iso-C4H10, n-C4H10, C2H4, C3H6, C2H2, CO, and CO2, from coal mines, petroleum refineries, and other plants, a Fourier Transform Infrared (FT-IR spectrometer was used to develop a portable gas analyzer for patrolling and examining gas exhaust. Firstly, structure of the instrument was introduced. Then, a spectral analysis approach was presented. Finally, instrument was tested with standard gases and with actual gases emitted from a petroleum refinery. For the latter test, a gas chromatograph (GC was used as a reference instrument. The test results showed that the detection limit of every component of analyte was less than 10 × 10−6. The maximum test error of every analyte was less than 15 × 10−6 when its practical concentration was no more than 500 × 10−6. A final comparison showed that the result curves of analytes obtained with FT-IR spectrometer almost overlapped with those obtained with GC, and their resulting noise was less than 6.4% when the practical gas concentration was above 100 × 10−6. As a result, our instrument was suitable to be used as a portable instrument for monitoring exhaust gases.

  7. THERMODYNAMIC MODEL OF THE CYCLE OF SPARK IGNITION ENGINE WITH EXHAUST GAS RECIRCULATION

    Öğüçlü, Özer

    2015-01-01

    A thermodynamic model has been developed and applied to predict the emission levels and performance of a spark ignition engine with using Exhaust Gas Recirculation (EGR) gas. The model simulates the full thermodynamic cycle of the engine and includes heat transfer, combustion, gas exchange process, thermal dissociation of water and carbon dioxide, and chemical equilibrium. 

  8. Exhaust gas recirculation – Zero dimensional modelling and characterization for transient diesel combustion control

    Highlights: • Zero-dimensional EGR model for transient diesel combustion control. • Detailed analysis of EGR effects on intake, cylinder charge and exhaust properties. • Intake oxygen validated as an operating condition-independent measure of EGR. • Quantified EGR effectiveness in terms of NOx emission reduction. • Twin lambda sensor technique for estimation of EGR/in-cylinder parameters. - Abstract: The application of exhaust gas recirculation (EGR) during transient engine operation is a challenging task since small fluctuations in EGR may cause larger than acceptable spikes in NOx/soot emissions or deterioration in the combustion efficiency. Moreover, the intake charge dilution at any EGR ratio is a function of engine load and intake pressure, and typically changes during transient events. Therefore, the management of EGR during transient engine operation or advanced combustion cycles (that are inherently less stable) requires a fundamental understanding of the transient EGR behaviour and its impact on the intake charge development. In this work, a zero-dimensional EGR model is described to estimate the transient (cycle-by-cycle) progression of EGR and the time (engine cycles) required for its stabilization. The model response is tuned to a multi-cylinder engine by using an overall engine system time-constant and shown to effectively track the transient EGR changes. The impact of EGR on the actual air–fuel ratio of the cylinder charge is quantified by defining an in-cylinder excess-air ratio that accounts for the oxygen in the recycled exhaust gas. Furthermore, a twin lambda sensor (TLS) technique is implemented for tracking the intake dilution and in-cylinder excess-air ratio in real-time. The modelling and analysis results are validated against a wide range of engine operations, including transient and steady-state low temperature combustion tests

  9. [Research on diagnosis of gas-liquid detonation exhaust based on double optical path absortion spectroscopy technique].

    Lü, Xiao-Jing; Li, Ning; Weng, Chun-Sheng

    2014-03-01

    The effect detection of detonation exhaust can provide measurement data for exploring the formation mechanism of detonation, the promotion of detonation efficiency and the reduction of fuel waste. Based on tunable diode laser absorption spectroscopy technique combined with double optical path cross-correlation algorithm, the article raises the diagnosis method to realize the on-line testing of detonation exhaust velocity, temperature and H2O gas concentration. The double optical path testing system is designed and set up for the valveless pulse detonation engine with the diameter of 80 mm. By scanning H2O absorption lines of 1343nm with a high frequency of 50 kHz, the on-line detection of gas-liquid pulse detonation exhaust is realized. The results show that the optical testing system based on tunable diode laser absorption spectroscopy technique can capture the detailed characteristics of pulse detonation exhaust in the transient process of detonation. The duration of single detonation is 85 ms under laboratory conditions, among which supersonic injection time is 5.7 ms and subsonic injection time is 19.3 ms. The valveless pulse detonation engine used can work under frequency of 11 Hz. The velocity of detonation overflowing the detonation tube is 1,172 m x s(-1), the maximum temperature of detonation exhaust near the nozzle is 2 412 K. There is a transitory platform in the velocity curve as well as the temperature curve. H2O gas concentration changes between 0-7% during detonation under experimental conditions. The research can provide measurement data for the detonation process diagnosis and analysis, which is of significance to advance the detonation mechanism research and promote the research of pulse detonation engine control technology. PMID:25208369

  10. Turbine exhaust diffuser with region of reduced flow area and outer boundary gas flow

    Orosa, John

    2014-03-11

    An exhaust diffuser system and method for a turbine engine. The outer boundary may include a region in which the outer boundary extends radially inwardly toward the hub structure and may direct at least a portion of an exhaust flow in the diffuser toward the hub structure. At least one gas jet is provided including a jet exit located on the outer boundary. The jet exit may discharge a flow of gas downstream substantially parallel to an inner surface of the outer boundary to direct a portion of the exhaust flow in the diffuser toward the outer boundary to effect a radially outward flow of at least a portion of the exhaust gas flow toward the outer boundary to balance an aerodynamic load between the outer and inner boundaries.

  11. Exhaust gas concentration of CNG fuelled direct injection engine at MBT timing

    Full text: This paper presents an experimental result of exhaust gas concentration of high compression engine fuelled with compressed natural gas (CNG) at maximum brake torque (MBT). The engine uses central direct injection (DI) technique to inject the CNG into the cylinder. The engine geometry bases on gasoline engine with 14:1 compression ratio and called CNGDI engine. The injectors are positioned within a certain degrees of spark plug location. The objective of the experiment is to study the influence and significant of MBT timing in CNGDI engine towards exhaust gases. The experimental tests were carried out using computer-controlled eddy-current dynamometer, which measures the CNGDI engine performance. At MBT region, exhaust gas concentration as such CO, HC, NOx, O2 and CO2, were recorded and analyzed during the test using the Horiba analyzer. A closed loop wide band lambda sensor has been mounted at the exhaust manifold to indicate the oxygen level during the exercise. (author)

  12. An analysis of the thermodynamic efficiency for exhaust gas recirculation-condensed water recirculation-waste heat recovery condensing boilers (EGR-CWR-WHR CB)

    This study presents fundamental research on the development of a new boiler that is expected to have a higher efficiency and lower emissions than existing boilers. The thermodynamic efficiency of exhaust gas recirculation-condensed water recirculation-waste heat recovery condensing boilers (EGR-CWR-WHR CB) was calculated using thermodynamic analysis and was compared with other boilers. The results show the possibility of obtaining a high efficiency when the temperature of the exhaust gas is controlled within 50–60 °C because water in the exhaust gas is condensed within this temperature range. In addition, the enthalpy emitted by the exhaust gas for the new boiler is smaller because the amount of condensed water is increased by the high dew-point temperature and the low exhaust gas temperature. Thus, the new boiler can obtain a higher efficiency than can older boilers. The efficiency of the EGR-CWR-WHR CB proposed in this study is 93.91%, which is 7.04% higher than that of existing CB that is currently used frequently. - Highlights: • The study presents the development of a new boiler expected to have a high efficiency. • Thermodynamic efficiency of EGR-CWR-WHR condensing boiler was calculated. • Efficiency of EGR-CWR-WHR CB is 93.91%, which is 7.04% higher than existing CB

  13. Analysis of benefits of using internal exhaust gas recirculation in biogas-fueled HCCI engines

    Highlights: • The influence of EGR on combustion of biogas fueled HCCI was investigated. • The aim was to reduce intake temperature requirement by internal EGR. • Combustion products caused the delay of combustion in similar conditions. • Internal EGR enabled by negative valve overlap increased cylinder temperature. • This increase was not enough to significantly reduce the intake temperature. - Abstract: This paper describes a numerical study that analyzed the influence of combustion products (CP) concentration on the combustion characteristics (combustion timing and combustion duration) of a biogas fueled homogeneous charge compression ignition (HCCI) engine and the possibility of reducing the high intake temperature requirement necessary for igniting biogas in a HCCI engine by using internal exhaust gas recirculation (EGR) enabled by negative valve overlap (NVO). An engine model created in AVL Boost, and validated against experimental engine data, was used in this study. The results show, somewhat counter-intuitively, that when CP concentrations are increased the required intake temperature for maintaining the same combustion timing must be increased. When greater NVO is used to increase the in-cylinder CP concentration, the in-cylinder temperature does increase, but the chemical dilution influence of CP almost entirely counteracts this thermal effect. Additionally, it has been observed that with larger fractions of CP some instability of combustion in the calculation was obtained which indicates that the increase of internal EGR might produce some combustion instability

  14. 40 CFR 86.1511 - Exhaust gas analysis system.

    2010-07-01

    ... Regulations for Otto-Cycle Heavy-Duty Engines, New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Heavy-Duty Engines, New Otto-Cycle Light-Duty Trucks, and New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Light-Duty Trucks; Idle...

  15. 40 CFR 86.1509 - Exhaust gas sampling system.

    2010-07-01

    ... Regulations for Otto-Cycle Heavy-Duty Engines, New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Heavy-Duty Engines, New Otto-Cycle Light-Duty Trucks, and New Methanol-Fueled Natural Gas-Fueled, and Liquefied Petroleum Gas-Fueled Diesel-Cycle Light-Duty Trucks; Idle...

  16. Current Techniques of Growing Algae Using Flue Gas from Exhaust Gas Industry: a Review.

    Huang, Guanhua; Chen, Feng; Kuang, Yali; He, Huan; Qin, An

    2016-03-01

    The soaring increase of flue gas emission had caused global warming, environmental pollution as well as climate change. Widespread concern on reduction of flue gas released from industrial plants had considered the microalgae as excellent biological materials for recycling the carbon dioxide directly emitted from exhaust industries. Microalgae also have the potential to be the valuable feedback for renewable energy production due to their high growth rate and abilities to sequester inorganic carbon through photosynthetic process. In this review article, we will illustrate important relative mechanisms in the metabolic processes of biofixation by microalgae and their recent experimental researches and advances of sequestration of carbon dioxide by microalgae on actual industrial and stimulate flue gases, novel photobioreactor cultivation systems as well as the perspectives and limitations of microalgal cultivation in further development. PMID:26695777

  17. Study on the combustion characteristics of a premixed combustion system with exhaust gas recirculation

    The boiler of a premixed combustion system with EGR (exhaust gas recirculation) is investigated to explore the potential for increasing thermal efficiency and lowering pollutant emissions. To achieve this purpose, a thermodynamic analysis is performed to predict the effect of EGR on the thermodynamic efficiency for various equivalence ratios. Experiments of a preheated air condensing boiler with EGR were conducted to measure the changes in the thermal efficiency and the characteristics of the pollutant emission. Finally, a 1-D premixed code was calculated to understand the effect of the EGR method on the NO reduction mechanism. The results of the thermodynamic analysis show that the thermodynamic efficiency is not changed because the temperature and the amount of the exhaust gas are unchanged, even though the EGR method is implemented in the system. However, when the EGR method is used with an equivalence ratio near 1.00, it is experimentally verified that the thermal efficiency increases and the NOx concentration decreases. Based on the results from numerical calculations, it is shown that the NO production rates of N + O2 ↔ NO + O and N + OH ↔ NO + H are remarkably changed due to the decrease in the flame temperature and the NO mole fraction is decreased. - Highlights: • Premixed combustion system with EGR is studied for a high efficiency and low NOx. • All research is performed with various EGR and equivalence ratios. • It verified that efficiency increases and the NOx emission decreases with EGR method. • NO production rates are remarkably changed by N + O2 ↔ NO + O and N + OH ↔ NO + H with EGR

  18. Turbocharger efficiencies in pulsating exhaust gas flow; Turboladerwirkungsgrade in pulsierender Abgasstroemung

    Aymanns, Richard; Scharf, Johannes; Uhlmann, Tolga [FEV GmbH, Aachen (Germany). Business Unit Gasoline Engines; Pischinger, Stefan [RWTH Aachen (Germany). Lehrstuhl fuer Verbrennungskraftmaschinen

    2012-07-15

    The exhaust pressure pulse amplitudes in downsizing engines challenge the quasi steady modelling of turbocharger turbines in engine process simulation. An early selection of a well matching turbocharger is the key to time efficiency in the concept development phase of engines with ambitious performance and fuel economy targets. This article from FEV and RWTH Aachen assesses the turbocharger efficiencies in pulsating exhaust gas flow and gives a handling recommendation to minimise matching errors. (orig.)

  19. Low-pressure-ratio regenerative exhaust-heated gas turbine. Final report

    Tampe, L.A.; Frenkel, R.G.; Kowalick, D.J.; Nahatis, H.M.; Silverstein, S.M.; Wilson, D.G.

    1991-01-01

    A design study of coal-burning gas-turbine engines using the exhaust-heated cycle and state-of-the-art components has been completed. In addition, some initial experiments on a type of rotary ceramic-matrix regenerator that would be used to transfer heat from the products of coal combustion in the hot turbine exhaust to the cool compressed air have been conducted. Highly favorable results have been obtained on all aspects on which definite conclusions could be drawn.

  20. Workshop on an Assessment of Gas-Side Fouling in Fossil Fuel Exhaust Environments

    Marner, W. J. (Editor); Webb, R. L. (Editor)

    1982-01-01

    The state of the art of gas side fouling in fossil fuel exhaust environments was assessed. Heat recovery applications were emphasized. The deleterious effects of gas side fouling including increased energy consumption, increased material losses, and loss of production were identified.

  1. Tracer Gas Technique Versus a Control Box Method for Estimating Direct Capture Efficiency of Exhaust Systems

    Madsen, U.; Aubertin, G.; Breum, N. O.; Fontaine, J. R.; Nielsen, Peter V.

    Numerical modelling of direct capture efficiency of a local exhaust is used to compare the tracer gas technique of a proposed CEN standard against a more consistent approach based on an imaginary control box. It is concluded that the tracer gas technique is useful for field applications....

  2. Application of the water gas shift reaction to fusion fuel exhaust streams

    In a Fusion Fuel Clean Up (FCU) system, impurities will be removed from the fusion reactor exhaust and neutral beam line streams. Tritium in this impurity stream will be recovered and recycled to the fuel stream. In one flowsheet configuration of the Tritium Systems Test Assembly (TSTA), tritium is recovered from a simulated impurity stream via uranium hot metal beds and recycled to an isotope separation system. This study has shown, however, that the catalyzed water gas shift reaction, by which (H,D,T)2O and CO are converted to (H,D,T)2 and CO2 is a better method of (H,D,T)2O reduction than the hot metal beds. Catalytic reactors were designed, built and tested to provide data for the design of a prototype reactor to replace the hot metal beds in the FCU system. The prototype reactor contains only 10 g of catalyst and is expected to last at least 5 years. The reactor is small (1.3 cm OD x 13 cm long), operates at low temperatures (approximately 490 K) and will convert water to hydrogen, at a CO/H2O ratio of 1.5, with an efficiency of greater than 98 percent. Results show that the catalytic reactor is very stable even during upset conditions. Wide ranges of flow and a CO/H2O ratio variance from 1.3 upward have little effect on the conversion efficiency. Short term high temperature excursions do not affect the catalyst and lower temperatures will simply decrease the reaction rate resulting in lower conversions. The reactor appears to be unaffected by NO2, CO2, O2 and N2 in the feed stream at concentration levels expected in a fusion reactor exhaust stream

  3. Experimental study on engine gas-path component fault monitoring using exhaust gas electrostatic signal

    Sun, Jianzhong; Zuo, Hongfu; Liu, Pengpeng; Wen, Zhenhua

    2013-12-01

    This paper presents the recent development in engine gas-path components health monitoring using electrostatic sensors in combination with signal-processing techniques. Two ground-based engine electrostatic monitoring experiments are reported and the exhaust gas electrostatic monitoring signal-based fault-detection method is proposed. It is found that the water washing, oil leakage and combustor linear cracking result in an increase in the activity level of the electrostatic monitoring signal, which can be detected by the electrostatic monitoring system. For on-line health monitoring of the gas-path components, a baseline model-based fault-detection method is proposed and the multivariate state estimation technique is used to establish the baseline model for the electrostatic monitoring signal. The method is applied to a data set from a turbo-shaft engine electrostatic monitoring experiment. The results of the case study show that the system with the developed method is capable of detecting the gas-path component fault in an on-line fashion.

  4. Experimental study on engine gas-path component fault monitoring using exhaust gas electrostatic signal

    This paper presents the recent development in engine gas-path components health monitoring using electrostatic sensors in combination with signal-processing techniques. Two ground-based engine electrostatic monitoring experiments are reported and the exhaust gas electrostatic monitoring signal-based fault-detection method is proposed. It is found that the water washing, oil leakage and combustor linear cracking result in an increase in the activity level of the electrostatic monitoring signal, which can be detected by the electrostatic monitoring system. For on-line health monitoring of the gas-path components, a baseline model-based fault-detection method is proposed and the multivariate state estimation technique is used to establish the baseline model for the electrostatic monitoring signal. The method is applied to a data set from a turbo-shaft engine electrostatic monitoring experiment. The results of the case study show that the system with the developed method is capable of detecting the gas-path component fault in an on-line fashion. (paper)

  5. Dynamic exhaust gas measurement with diode-lasers. Dynamische Abgasmessung mit Diodenlasern

    Nitzschke, E.; Wolf, H.

    The future development of internal combustion engines requires an exact knowledge of dynamic processes. Information on the time resolved concentration of single exhaust gas components is of special importance. Measurement techniques should have a time resolution of one combustion cycle. The reported instrument fulfills this requirement and has a response time of 3 ms. The exhaust gas analysis is performed by using a spectroscopic technique with infrared diode lasers. First applications of the system have shown it to be important for the analysis and optimization of modern engines. With gas sampling close to the exhaust valve the combustion process can precisely be analyzed. Strong variations were observed between single combustion cycles. Sampling behind the catalyst high system speed revealed dynamic properties of the catalyst and motor management system. (orig./HW).

  6. Removal of Carbon Dioxide Gas From the Exhaust Gases Generated at the Takoradi Thermal Power Station

    M. Charles

    2010-10-01

    Full Text Available Takoradi Thermal Power Station (TTPS generates electricity by burning fossil-fuel and hence it also generates greenhouse gases especially carbon dioxide, which is vented into the atmosphere. These greenhouse gases are pollutants known to cause global warming. A method for the removal of carbon dioxide gas from the exhaust gases generated at TTPS is proposed in this research. It aims at reducing the plant’s carbon dioxide emission into the atmosphere and hence reducing the plant’s rate of pollution into the atmosphere. The method employed is a modification of a method known as the Fluor Daniel ECONAMINE FG process. This method removes carbon dioxide from exhaust gas by using an amine solution which comes into “contact” with the exhaust gas in a counter-current manner. This method has been applied by 23 companies which produce CO2 on a large scale. However, before TTPS apply this method a cost feasibility study is recommended.

  7. Damage of natural stone tablets exposed to exhaust gas under laboratory conditions

    Farkas, Orsolya; Szabados, György; Török, Ákos

    2016-04-01

    Natural stone tablets were exposed to exhaust gas under laboratory conditions to assess urban stone damage. Cylindrical test specimens (3 cm in diameter) were made from travertine, non-porous limestone, porous limestone, rhyolite tuff, sandstone, andesite, granite and marble. The samples were exposed to exhaust gas that was generated from diesel engine combustion (engine type: RÁBA D10 UTSLL 160, EURO II). The operating condition of the internal combustion engine was: 1300 r/m (app 50%). The exhaust gas was diverted into a pipe system where the samples were placed perpendicular to main flow for 1, 2, 4, 8 and 10 hours, respectively. The exhaust emission was measured by using AVL particulate measurement technology; filter paper method (AVL 415). The stone samples were documented and selective parameters were measured prior to and after exhaust gas exposure. Density, volume, ultrasonic pulse velocity, mineral composition and penetration depth of emission related particulate matter were recorded. The first results indicate that after 10 hours of exposure significant amount of particulate matter deposited on the stone surface independently from the surface properties and porosity. The black soot particles uniformly covered all types of stones, making hard to differentiate the specimens.

  8. Exhaust Gas Emissions from a Rotating Detonation-wave Engine

    Kailasanath, Kazhikathra; Schwer, Douglas

    2015-11-01

    Rotating detonation-wave engines (RDE) are a form of continuous detonation-wave engines. They potentially provide further gains in performance than an intermittent or pulsed detonation-wave engine (PDE). The overall flow field in an idealized RDE, primarily consisting of two concentric cylinders, has been discussed in previous meetings. Because of the high pressures involved and the lack of adequate reaction mechanisms for this regime, previous simulations have typically used simplified chemistry models. However, understanding the exhaust species concentrations in propulsion devices is important for both performance considerations as well as estimating pollutant emissions. Progress towards addressing this need will be discussed in this talk. In this approach, an induction parameter model is used for simulating the detonation but a more detailed finite-chemistry model including NOx chemistry is used in the expansion flow region, where the pressures are lower and the uncertainties in the chemistry model are greatly reduced. Results show that overall radical concentrations in the exhaust flow are substantially lower than from earlier predictions with simplified models. The performance of a baseline hydrogen/air RDE increased from 4940 s to 5000 s with the expansion flow chemistry, due to recombination of radicals and more production of H2O, resulting in additional heat release. Work sponsored by the Office of Naval Research.

  9. High temperature gas reactor

    The present invention provides a reflector block structure of a high temperature gas reactor in which graphite blocks are not failed even a containing cylinder loaded to a fuel exchanger collides against to secured reflectors upon loading and withdrawing fuel constitutional elements. Namely, a protection plate made of a metal material such as stainless steel is covered on the secured reflector blocks disposed to the upper most step among secured graphite reflector blocks constituting the reactor core. In addition, positioning guide grooves are formed on the protection plate for guiding the containing cylinder loaded to the fuel exchanger to the column of the reactor core constitutional elements. With such a constitution, even if the containing cylinder of fuel exchanger is hoisted down and collided against the inner circumferential edge of the secured reflector blocks due to deviation of the position and the direction upon exchange of fuels, the reflector blocks are not failed since the above-mentioned portion is covered with the metal protection plate. In addition, the positioning guide grooves lead the fuel exchanger to a predetermined column correctly. (I.S.)

  10. A Framework for Modular Modeling of the Diesel Engine Exhaust Gas Cleaning System

    Åberg, Andreas; Hansen, Thomas Klint; Linde, Kasper;

    2015-01-01

    Pollutants from diesel engines have a negative effect on urban air quality. Because of this and new legislation restricting the emission level, it is necessary to develop exhaust gas treatment systems for diesel engines that can reduce the amount of pollutants. A modular model capable of simulating...... modular model. Four different models in the automotive diesel exhaust gas cleaning system are presented briefly. Based on the presented methodology, it is discussed which changes are needed to the models to create a modular model of the whole catalytic system....

  11. Exhaust Gas Recirculation Control for Large Diesel Engines - Achievable Performance with SISO Design

    Hansen, Jakob Mahler; Blanke, Mogens; Niemann, Hans Henrik; Vejlgaard-Laursen, Morten

    analysis of the highly non-linear dynamics. Control architectures are investigated and performance in terms of disturbance rejection and reference tracking are investigated under model uncertainty. Classical feed-forward and feedback controller designs are investigated using classical and Quantitative......This paper investigates control possibilities for Exhaust Gas Recirculation (EGR) on large diesel engines. The goal is to reduce the amount of NOx in the exhaust gas by reducing the oxygen concentration available for combustion. Control limitations imposed by the system are assessed using linear...... Feedback Theory (QFT) designs. Validation of the controller is made on the model with focus on disturbance reduction ability....

  12. Feeding a Gas Turbine with Aluminum Plant Exhaust for Increased CO2 Concentration in Capture Plant

    Jordal, Kristin; Anantharaman, Rahul; Genrup, Magnus; Aarhaug, Thor Anders; Bakken, Jørn; Lilliestråle, Astrid; Mejdell, Thor; Holt, Nancy J.

    2015-01-01

    Aluminum production contributes to global CO2 emissions both due to the production process itself and due to the generation of electric power required for aluminum production. A concept is presented for increasing the CO2 concentration in the aluminum exhaust from ∼1% to ∼5% through the feeding of aluminum plant exhaust gas to a natural gas combined cycle (NGCC). The specific energy demand for CO2 capture is therewith reduced for both the aluminum plant and the NGCC. An evaluation was made of...

  13. ANALYSIS OF EXHAUST GAS EMISSION IN THE MARINE TWO-STROKE SLOW-SPEED DIESEL ENGINE

    Branko Lalić

    2016-07-01

    Full Text Available This paper explores the problem of exhaust emissions of the marine two-stroke slow-speed diesel engines. After establishing marine diesel engine regulations and defining the parameters influencing exhaust emissions, the simulation model of the marine two-stroke slow-speed diesel engine has been developed. Furthermore, the comparison of numerical and experimentally obtained data has been performed, resulting in achieving the model validity at 100% load, which represents a requirement for further exhaust gas analysis. Deviations obtained at the real engine and the model range from 2% to 7%. An analysis of the influential parameters such as compression ratio, exhaust valve timing and fuel injection timing has been performed. The obtained results have been compared and conclusions have been drawn.

  14. HEAT TRANSFER IN EXHAUST SYSTEM OF A COLD START ENGINE AT LOW ENVIRONMENTAL TEMPERATURE

    Snežana D Petković

    2010-01-01

    Full Text Available During the engine cold start, there is a significantly increased emission of harmful engine exhaust gases, particularly at very low environmental temperatures. Therefore, reducing of emission during that period is of great importance for the reduction of entire engine emission. This study was conducted to test the activating speed of the catalyst at low environmental temperatures. The research was conducted by use of mathematical model and developed computer programme for calculation of non-stationary heat transfer in engine exhaust system. During the research, some of constructional parameters of exhaust system were adopted and optimized at environmental temperature of 22 C. The combination of design parameters giving best results at low environmental temperatures was observed. The results showed that the temperature in the environment did not have any significant influence on pre-catalyst light-off time.

  15. Process for reducing harmful substances in exhaust gas/exhaust air by means of photosynthesising algae and device to carry out the process. Verfahren zur Minderung von Abgas-/Abluft-Schadstoffen mittels photosynthetisierender Algen und Vorrichtung zur Durchfuehrung des Verfahrens

    Schimmelpfeng, L.; Thormaelen, C.

    1986-09-25

    The process reported here uses the photosynthesis properties of micro-organisms which can stand extremes of harmful substances (micro-algae: cyanidium caldarium), using light energy to fix carbon dioxide, SO/sub 2/ and NO/sub x/ in biological compounds. Metal ions can be accumulated simultaneously. The process provides for the uncomplicated direct introduction of exhaust gas/exhaust air (temperature range: 40-80/sup 0/C) into the lighted culture. If sunlight is used, the process has a very favourable energy balance, as the harmful substances are converted biologically into compounds rich in energy, which can be reused (e.g. biogas).

  16. Re-entrainment and dispersion of exhausts from indoor radon reduction systems. Analysis of tracer gas data

    Tracer gas studies were conducted around four model houses in a wind tunnel, and around one house in the field, to quantify re-entrainment and dispersion of exhaust gases released from residential indoor radon reduction systems. Re-entrainment tests in the field suggest that active soil depressurization systems exhausting at grade level can contribute indoor radon concentrations 3 to 9 times greater than systems exhausting at the eave. With a high exhaust concentration of 37,000 Bq/m3, the indoor contribution from eave exhaust re-entrainment may be only 20% to 70% of the national average ambient level in the U.S. (about 14 Bq/m3), while grade-level exhaust may contribute 1.8 times the ambient average. The grade-level contribution would drop to only 0.18 times ambient if the exhaust were 3,700 Bq/m3. Wind tunnel tests of exhaust dispersion outdoors suggest that grade-level exhaust can contribute mean concentrations beside houses averaging 7 times greater than exhaust at the eave, and 25 to 50 times greater than exhaust midway up the roof slope. With 37,000 Bq/m3 in the exhaust, the highest mean concentrations beside the house could be less than or equal to the ambient background level with eave and mid-roof exhausts, and 2 to 7 times greater than ambient with grade exhausts. (au) 9 refs

  17. 46 CFR 63.25-7 - Exhaust gas boilers.

    2010-10-01

    ... results in inadequate heat transfer, a high temperature alarm or low flow alarm must be activated. An audible alarm must automatically sound, and a visual indicator must indicate when the fluid temperature exceeds the maximum operating temperature or when the fluid/steam flowing through the heat exchanger...

  18. A method for a numeric prediction of gas turbine exhaust ducts out door noise

    Guivarch, M.

    1995-10-01

    When Electricite de France (EDF) ordered a 216 MWe gas turbine in 1986, the preliminary evaluation of the noise radiated by the exhaust duct had been a difficult problem. Therefore, EDF has developed an acoustic model of the exhaust duct of the turbine in order to compare the solutions proposed by different builders and to test the influence of the exhaust duct geometry modification on the environmental sound level. This model is based on bidimensional modelling of the exhaust duct and is developed in three main steps: a computation of the flow in the exhaust duct using a k - {epsilon} code. This computation provides the basic data needed for modeling the noise generated downstream the silencers and the convected field for the computation of sound propagation; a computation of the noise generated by the flow turbulence downstream the silencers. It is based on the Ribner modelling of noise radiated by turbulent subsonic free jets and uses the results of the flow computation. In this way, we compute the turbulent noise levels and assume that the total noise levels throughout the duct exit is the sum of the turbulent noise and of the turbine noise; a computation of sound propagation in the exhaust duct. This computation takes into account the flow and the attenuation of sound due to the silencers. In a first stage, it is validated by measurements taken when the machine is out of operating condition. The second stage provides the turbine noise levels throughout the tack exit. (author) 8 refs.

  19. NOVEL GAS SENSORS FOR HIGH-TEMPERATURE FOSSIL FUEL APPLICATIONS

    Palitha Jayaweera

    2004-05-01

    SRI is developing ceramic-based microsensors for detection of exhaust gases such as NO, NO{sub 2}, and CO in advanced combustion and gasification systems. The sensors detect the electrochemical activity of the exhaust gas species on catalytic electrodes and are designed to operate at high temperatures, elevated pressures, and corrosive environments typical of large power generation exhausts. Under this research project we are developing sensors for multiple gas detection in a single package along with data acquisition and control software and hardware. The sensor package can be easily integrated into online monitoring systems for active emission control. This report details the research activities performed from May 2004 to October 2004 including testing of catalytic materials, sensor design and fabrication, and software development.

  20. 40 CFR 86.110-90 - Exhaust gas sampling system; diesel vehicles.

    2010-07-01

    ... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Exhaust gas sampling system; diesel vehicles. 86.110-90 Section 86.110-90 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED... connected to a dilution tunnel. Figure B90-5 is a schematic drawing of the PDP system. Figure B90-6 is...

  1. 40 CFR 92.114 - Exhaust gas and particulate sampling and analytical system.

    2010-07-01

    ... and analysis shall comply with the requirements of 40 CFR part 1065, with the following exceptions and... and analytical system. 92.114 Section 92.114 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Procedures § 92.114 Exhaust gas and particulate sampling and analytical system. (a) General. (1)...

  2. Modelling for Control of Exhaust Gas Recirculation on Large Diesel Engines

    Hansen, Jakob Mahler; Zander, Claes-Göran; Pedersen, Nicolai; Blanke, Mogens; Vejlgaard-Laursen, Morten

    models. While literature is rich on four-stroke automotive engines, this paper considers two-stroke engines and develops a non-linear dynamic model of the exhaust gas system. Parameters are determined by system identication. The paper uses black-box nonlinear model identication and modelling from rst...

  3. An overview of exhaust emissions regulatory requirements and control technology for stationary natural gas engines

    In this paper a practical overview of stationary natural gas engine exhaust emissions control technology and trends in emissions regulatory requirements is presented. Selective and non-selective catalytic reduction and lean burn technologies are compared. Particular emphasis is focussed on implications of the Clean Air Act of 1990. Recent emissions reduction conversion kit developments and a practical approach to continuous monitoring are discussed

  4. Implementation of an experimental pilot reproducing the fouling of the exhaust gas recirculation system in diesel engines

    Gaborieau, Cécile; Sommier, Alain; Toutain, Jean; Anguy, Yannick; Crepeau, Gérald; Gobin, Benoît

    2012-04-01

    The European emission standards EURO 5 and EURO 6 define more stringent acceptable limits for exhaust emissions of new vehicles. The Exhaust Gas Recirculation (EGR) system is a partial but essential solution for lowering the emission of nitrogen oxides and soot particulates. Yet, due to a more intensive use than in the past, the fouling of the EGR system is increased. Ensuring the reliability of the EGR system becomes a main challenge. In partnership with PSA Peugeot Citroën, we designed an experimental setup that mimics an operating EGR system. Its distinctive features are (1) its ability to reproduce precisely the operating conditions and (2) its ability to measure the temperature field on the heat exchanger surface with an Infra Red camera for detecting in real time the evolution of the fooling deposit based on its thermal resistance. Numerical codes are used in conjunction with this experimental setup to determine the evolution of the fouling thickness from its thermal resistance.

  5. HPLC analysis of aldehydes in automobile exhaust gas: Comparison of exhaust odor and irritation in different types of gasoline and diesel engines

    This study investigated high performance liquid chromatography (HPLC) to identify and measure aldehydes from automobile exhaust gas. Four aldehydes: formaldehyde (HCHO), acetaldehyde (CH3CHO), acrolein (H2C=CHCHO) and propionaldehyde (CH3CH2CHO) and one ketone, acetone (CH3)2CO are separated. The other higher aldehydes in exhaust gas are very small and cannot be separated. A new method of gas sampling, hereafter called bag sampling in HPLC is introduced instead of the trapping gas sampling method. The superiority of the bag sampling method is its transient gas checking capability. In the second part of this study, HPLC results are applied to compare exhaust odor and irritation of exhaust gases in different types of gasoline and diesel engines. Exhaust odor, irritation and aldehydes are found worst in direct injection (DI) diesel engines and best in some good multi-point injection (MPI) gasoline and direct injection gasoline (DIG) engines. Indirect injection (IDI) diesel engines showed odor, irritation and aldehydes in between the levels of MPI gasoline, DIG and DI diesel engines

  6. Exhaust gas recirculation study on dual-fuel methane combustion

    Murillo Hernández, Alberto

    2015-01-01

    Currently, interest in different alternative transport fuels is growing. There are two main reasons for this motivation: the universal environmental concern, caused by the noticeable impact of petroleum fuels on the human health and environment, and the necessity of replacement due to the declining availability of petroleum. Dual-fuel engines could mean a partial solution of these worries, since the primary fuel of this type of engines is natural gas, mostly formed by methane, which can d...

  7. Measurement of gas-phase polycyclic aromatic hydrocarbons (PAH) in gasoline vehicle exhaust

    Polycyclic aromatic hydrocarbons (PAH) are emitted at low levels from most combustion sources including motor vehicles. Extensive studies have been carried out in the past on the identification and quantitation of PAH in particular matter, primarily from diesel vehicles; however, only limited data are available on gas phase emissions from motor vehicles. Gas phase emissions are important from both a health perspective and because of their higher chemical reactivity during atmospheric transport. A method was sought to allow the authors to measure gas phase PAH in diluted vehicle exhaust over the relatively short collection times permitted during the U. S. Environmental Protection Agency (EPA) Urban Dynamometer Driving Schedule (UDDS) or Federal Test Procedure (FTP). In this paper, the authors describe their results on the development of a method using adsorption/thermal desorption with Tenax solid absorbent for the analysis of PAH and PAH derivatives in dilute vehicle exhaust

  8. Turbine exhaust diffuser with a gas jet producing a coanda effect flow control

    Orosa, John; Montgomery, Matthew

    2014-02-11

    An exhaust diffuser system and method for a turbine engine includes an inner boundary and an outer boundary with a flow path defined therebetween. The inner boundary is defined at least in part by a hub structure that has an upstream end and a downstream end. The outer boundary may include a region in which the outer boundary extends radially inward toward the hub structure and may direct at least a portion of an exhaust flow in the diffuser toward the hub structure. The hub structure includes at least one jet exit located on the hub structure adjacent to the upstream end of the tail cone. The jet exit discharges a flow of gas substantially tangential to an outer surface of the tail cone to produce a Coanda effect and direct a portion of the exhaust flow in the diffuser toward the inner boundary.

  9. Hydrogen combustion and exhaust emissions in a supercharged gas engine ignited with micro pilot diesel fuel

    A hydrogen combustion and exhaust emissions in a supercharged gas engine ignited with micro pilot diesel fuel was discussed in this presentation. A schematic diagram of the experimental study was first presented. The single cylinder, water-cooled, supercharged test engine was illustrated. Results were presented for the following: fuel energy and energy share (hydrogen and diesel fuel); pressure history and rate of heat release; engine performance and exhaust emissions; effect of nitrogen dilution on heat value per cycle; effect of N2 dilution on pressure history and rate of heat release; and engine performance and exhaust emissions. This presentation demonstrated that smooth and knock-free engine operation results from the use of hydrogen in a supercharged dual-fuel engine for leaner fuel-air equivalence ratios maintaining high thermal efficiency. It was possible to attain mor3 than 90 per cent hydrogen-energy substitution to the diesel fuel with zero smoke emissions. figs.

  10. Reduction of NOx and PM in marine diesel engine exhaust gas using microwave plasma

    Balachandran, W.; FInst, P.; Manivannan, N.; Beleca, R.; Abbod, M.

    2015-10-01

    Abatement of NOx and particulate matters (PM) of marine diesel exhaust gas using microwave (MW) non-thermal plasma is presented in this paper. NOx mainly consist of NO and less concentration of NO2 in a typical two stoke marine diesel engine and microwave plasma generation can completely remove NO. MW was generated using two 2kW microwave sources and a saw tooth passive electrode. Passive electrode was used to generate high electric field region within microwave environment where high energetic electrons (1-3eV) are produced for the generation of non-thermal plasma (NTP). 2kW gen-set diesel exhaust gas was used to test our pilot-scale MW plasma reactor. The experimental results show that almost 100% removal of NO is possible for the exhaust gas flow rate of 60l/s. It was also shown that MW can significantly remove soot particles (PM, 10nm to 365nm) entrained in the exhaust gas of 200kW marine diesel engine with 40% engine load and gas flow rate of 130l/s. MW without generating plasma showed reduction up to 50% reduction of PM and with the plasma up to 90% reduction. The major challenge in these experiments was that igniting the desired plasma and sustaining it with passive electrodes for longer period (10s of minutes) as it required fine tuning of electrode position, which was influenced by many factors such as gas flow rate, geometry of reactor and MW power.

  11. Trigeneration scheme for energy efficiency enhancement in a natural gas processing plant through turbine exhaust gas waste heat utilization

    Highlights: ► Efficiency enhancement of Natural Gas (NG) processing plants in hot/humid climates. ► Gas turbine waste heat powered trigeneration scheme using absorption refrigeration. ► Annual NG savings of 1879 MSCM and operating cost savings of US$ 20.9 million realized. ► Trigeneration scheme payback period estimated at approximately 1 year. ► Significant economical and environmental benefits for NG processing plants. - Abstract: The performance of Natural Gas Processing Plants (NGPPs) can be enhanced with the integration of Combined Cooling, Heating and Power (CCHP) generation schemes. This paper analyzes the integration of a trigeneration scheme within a NGPP, that utilizes waste heat from gas turbine exhaust gases to generate process steam in a Waste Heat Recovery Steam Generator (WHRSG). Part of the steam generated is used to power double-effect water–lithium bromide (H2O–LiBr) absorption chillers that provide gas turbine compressor inlet air-cooling. Another portion of the steam is utilized to meet part furnace heating load, and supplement plant electrical power in a combined regenerative Rankine cycle. A detailed techno-economic analysis of scheme performance is presented based on thermodynamic predictions obtained using Engineering Equation Solver (EES). The results indicate that the trigeneration system could recover 79.7 MW of gas turbine waste heat, 37.1 MW of which could be utilized by three steam-fired H2O–LiBr absorption chillers to provide 45 MW of cooling at 5 °C. This could save approximately 9 MW of electric energy required by a typical compression chiller, while providing the same amount of cooling. In addition, the combined cycle generates 22.6 MW of additional electrical energy for the plant, while process heating reduces furnace oil consumption by 0.23 MSCM per annum. Overall, the trigeneration scheme would result in annual natural gas fuel savings of approximately 1879 MSCM, and annual operating cost savings of

  12. Study of modeling theory of multiphase gas distribution in exhaust process of automobile

    臧杰

    2004-01-01

    According to experiments and the phenomena that tailpipes often have dirty particulate matter, this paper takes dynamic theory analysis as its study aim, beginning with the description method of multiphase gas distribution differential equation. According to the characteristics that exhaust gas will flow with high velocity in a tailpipe, it is supposed that gas mass that differ largely will layer when flowing with high velocity in a tailpipe.This means the exhaust gas is mixed with particulate matter, gas with large mass (CO2 ,HC,NOx ) and gas with small mass (CO,H2O,N2 ,O2). The interface of two phase fluid will be become clearer as it flows in the pipe for a long distance. The fluid continuous equation between gas phase and solid phase and the mathematical relationship between the geometry parameter and the flowing are established by a multiphase gas flowing theory. Analyzing the interface and state of layers will provide a basic theory for developing a catalytic converter with high efficiency.

  13. The effect of piston bowl temperature on diesel exhaust emissions

    Ladommatos, N; Xiao, Z.; Zhao, H.

    2005-01-01

    In modern, high-speed, direct injection diesel engines for passenger vehicles, there is extensive impingement of the fuel sprays on to the piston bowl walls. Recent trends towards smaller engine sizes, equipped with high-pressure common-rail fuel injection systems, have tended to increase the spray/piston wall interaction. This paper describes tests carried out in a high-speed direct injection automotive diesel engine, during which the temperature of the piston was increased in a controlled m...

  14. Development of a metal hydride refrigeration system as an exhaust gas-driven automobile air conditioner

    Qin, Feng; Chen, Jiangping; Chen, Zhijiu [Institute of Refrigeration and Cryogenics Engineering, Shanghai Jiaotong University, Shanghai 200030 (China); Lu, Manqi; Yang, Ke [Engineering Center, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, Liaoning Province 110016 (China); Zhou, Yimin [Research Center, Zhejiang Yinlun Machinery Co. Ltd., Tiantai County, Zhejiang Province 317200 (China)

    2007-10-15

    Aiming at developing exhaust gas-driven automobile air conditioners, two types of systems varying in heat carriers were preliminarily designed. A new hydride pair LaNi{sub 4.61}Mn{sub 0.26}Al{sub 0.13}/La{sub 0.6}Y{sub 0.4}Ni{sub 4.8}Mn{sub 0.2} was developed working at 120-200 C/20-50 C/-10-0 C. P-C isotherms and reaction kinetics were tested. Reaction enthalpy, entropy and theoretical cycling coefficient of performance (COP) were deducted from Van't-Hoff diagram. Test results showed that the hydride pair has flat plateau slopes, fast reaction dynamics and small hystereses; the reaction enthalpy of the refrigeration hydride is -27.1 kJ/mol H{sub 2} and system theoretical COP is 0.711. Mean particle sizes during cycles were verified to be an intrinsic property affected by constitution, heat treatment and cycle numbers rather than initial grain sizes. Based on this work pair, cylindrical reactors were designed and a function proving metal hydride intermittent refrigeration system was constructed with heat conducting oil as heat source and water as heat sink. The reactor equivalent thermal conductivity is merely 1.3 W/(m K), which still has not meet practical requirement. Intermittent refrigeration cycles were achieved and the average cooling power is 84.6 W at 150 C/30 C/0 C with COP being 0.26. The regulations of cycling performance and minimum refrigeration temperature (MRT) were determined by altering heat source temperature. Results showed that cooling power and system COP increase while MRT decreases with the growth of heat source temperature. This study develops a new hydride pair and confirms its application in automobile refrigeration systems, while their heat transfer properties still need to be improved for better performance. (author)

  15. Analysis of Exhaust Gas Waste Heat Recovery and Pollution Processing for Z12V190 Diesel Engine

    Hou Xuejun; Gao Deli

    2012-01-01

    With the increasingly prominent problem regarding rapid economy development and the gradually serious environmental pollution, the waste heat recovery and waste gas pollution processing have received significant attention. Z12V190 diesel engine has high fuel consumption and low thermal efficiency and releases large amounts of exhaust gas and waste heat into the atmosphere, causing serious problems of energy waste and environmental pollution. In this work, the diesel engine exhaust gas compone...

  16. Experimental research on exhaust gas purifying facilities in incinerating treatment of radioactive wastes

    Among the research on the incinerating treatment of combustible low level wastes, three items, that is, combustible low level radioactive wastes and incinerating treatment method, wet type exhaust gas purifying facilities and ceramic filter type dry exhaust gas purifying facilities, were selected, and experimental research was carried out on the main theme of exhaust gas purification in the incineration of low level radioactive wastes. The definition of combustible low level radioactive wastes was decided, and the wastes conforming to this criteria were investigated and classified. The combustible low level wastes generated in the Tokai Research Establishment were classified and weighed, and the results reflected well the state of activities. The change of radioactive wastes to radioactive aerosol, radioactive gas and residue by incineration was investigated. The effect of volume reduction by incineration was studied. The decontamination performance of wet purifying system, the release of tritium steam, the cooling capacity of scrubbers and their corrosion, the construction of the test incinerator using ceramic filters, and the various tests on ceramic filters are reported. (K.I.)

  17. Study on using acetylene in dual fuel mode with exhaust gas recirculation

    Interest in employing gaseous fuels to internal combustion (IC) engines whether for stationary or mobile automotive applications has gained importance because of the economical, sustainable and environmental technical features associated with their usage. However, the incidence of preignition and knock remains a significant barrier in achieving their optimum performance potential. With the advent of latest technologies, the above barriers are eliminated. One such technique is timed manifold injection (TMI) of the gaseous fuel, which is controlled electronically to precisely monitor the induction of fuel to overcome the preignition problem in the intake. In the present investigation, acetylene was injected in the intake manifold in a single cylinder diesel engine, with a gas flow rate of 240 g/h, start of injection time is 10o aTDC and 90o CA (9.9 ms) duration, operated in dual fuel mode. In order to decrease the NOx emissions from acetylene-diesel engine, cooled EGR was employed. The cylinder pressure, brake thermal efficiency and emissions such as NOx, smoke, CO, HC, CO2 and exhaust gas temperature were studied. Dual fuel operation with acetylene induction coupled with cooled EGR results in lowered NOx emissions and improved part load performance. -- Highlights: → Acetylene was tried in SI engines, but due to backfire further research was hindered as an alternative fuel. → But it is not tried in CI engine. Timed manifold injection was tried in diesel engine in the present work to combat backfire. → Author was successful in running the diesel engine in dual fuel mode. → 21% maximum diesel replacement was achieved. Author is confident that acetylene will be commercialised as a fuel for diesel engine in future.

  18. Experimental investigation of an improved exhaust recovery system for liquid petroleum gas fueled spark ignition engine

    Gürbüz Habib; Akçay Hüsameddin

    2015-01-01

    In this study, we have investigated the recovery of energy lost as waste heat from exhaust gas and engine coolant, using an improved thermoelectric generator (TEG) in a LPG fueled SI engine. For this purpose, we have designed and manufactured a 5-layer heat exchanger from aluminum sheet. Electrical energy generated by the TEG was then used to produce hydrogen in a PEM water electrolyzer. The experiment was conducted at a stoichiometric mixture ratio, 1/2 th...

  19. Investigation of Materials for Use in Exhaust Gas Condensate Environment with Focus on EGR systems

    Olofsson, Andreas

    2012-01-01

    EGR (Exhaust Gas Recirculation) ar en teknik som anvands for dieselmotorer, for att mota de hart satta utslappskraven for kvaveoxider. EGR fungerar genom att en del av avgaserna aterfors till cylindrarna. Avgaserna gor sa att den maximala forbranningstemperaturen sanks, vilket kraftigt reducerar bildandet av kvaveoxider. Dieselavgaser inneh aller framst CO2, NOx, SO2 och H2O och innan avgasernaaterfors till cylindrarna kyls de ner. Detta leder till att det bildas ett korrosivt kondensat, eft...

  20. Evaluation of Exhaust Gas Condensing Economizer Installation at Riga CHP Plants

    Zigurs, Aris; Kunickis, Maris; Balodis, Maris; Linkevics, Olegs; Stuklis, Ilmars; Ivanova, Polina

    2015-01-01

    In this study, passive exhaust gas condensing economizer installation is evaluated at Riga CHP plants No. 1 and No. 2 to increase efficiency of heat only boilers (HOBs). Five options are investigated: two options for Riga CHP plant No. 1 and three options for Riga CHP plant No. 2. The study provides the analysis of HOBs operation statistics, determination of HOBs operation trends, development of production programmes, as well as economic and sensitivity analysis of the considered options. Bas...

  1. Laboratory Scale of Liquid Coal Fuel Combustion Process and Exhaust Gas Formation

    Kartika K. Hendratna; Osami Nishida; Hirotsugu Fujita; Wataru Harano

    2010-01-01

    Problem statement: Much research of coal has been already undertaken to ascertain the possibilities of coal being used as substitute for heavy fuel oil in the transportation sector. The effects of using coal as transportation fuel to the environment must also be considered. This study will review several aspects of the coal oil combustion process including combustion behavior, flame stability, some emissions from exhaust gas; CO, NOx and the particulate matter in a well insulated laboratory s...

  2. 5th international exhaust gas and particulate emissions forum. Proceedings; 5. Internationales Forum Abgas- und Partikelemissionen. Beitraege

    NONE

    2008-12-11

    The Proceedings of the 5th International Exhaust Gas and Particulate Emissions Forum contains 22 printed contributions as well as a CD-ROM. The titles of them are: (1) Diesel Emissions Control in the United States - 2010 and Beyond; (2) The MBE90 commercial vehicle engine for EPA '07 emissions regulations; (3) Concepts for engines and exhaust-gas cleaning systems for heavy duty trucks of the future; (4) HD Engine Technology for Near-Zero Emissions and Lowest Cost of Ownership; (5) (Partially-) Homogeneous Diesel Combustion; (6) Exhaust gas sensors for NOx storage catalysts and ammonia-SCR systems; (7) Sensors for modern exhaust gas after-treatment systems; (8) New reducing agents for low NOx-SCR Techno-logy; (9) Exhaust gas Aftertreatment on Lean Burn Gasoline Direct Injection Engines: The System of TWC and NOx-Storage Catalyst; (10) New Platinum/Palladium based catalyzed filter technologies for future passenger car applications; (11) Development of a Roadway Hydrocarbon Sorption Model and Characterization of a Novel PM Generator; (12) Requirements for current and future particulate measurement instrumentation from the point of view of the Physikalisch-Technische Bundesanstalt; (13) Standardized dilution conditions for gravimetric PM sampling - measures to assure results that correlate; (14) Particle Counting according PMP; (15) Future high-confidence measurement of diesel particulate emissions for approval and development; (16) New developments in optical instrumentation for exhaust gas; (17) Simultaneous Detection of Gaseous and Particulate Exhaust Components by Photoacoustic Spectroscopy; (18) Boundaries of modern exhaust gas instrumentation; (19) Raising quality and reducing application effort through efficient data input to the particulate filter load model for a EURO5 diesel car; (20) Stop-start operation of diesel engines - modified require-ment for exhaust gas after-treatment?; (21) Particulates emission with Biodiesel B30 impact on CSF management; (22

  3. 40 CFR 86.1309-90 - Exhaust gas sampling system; Otto-cycle and non-petroleum-fueled engines.

    2010-07-01

    ... 40 Protection of Environment 19 2010-07-01 2010-07-01 false Exhaust gas sampling system; Otto-cycle and non-petroleum-fueled engines. 86.1309-90 Section 86.1309-90 Protection of Environment... gases in the exhaust duct connected to the dilution tunnel (for the purposes of this paragraph,...

  4. Electron beam treatment technology for exhaust gas for preventing acid rain

    Recently, accompanying the increase of the use of fossil fuel, the damage due to acid rain such as withering of trees and extinction of fishes and shells has occurred worldwide, and it has become a serious problem. The sulfur oxides and nitrogen oxides contained in exhaust gas are oxidized by the action of sunbeam to become sulfuric acid and nitric acid mists, which fall in the form of rain. Acid rain is closely related to the use of the coal containing high sulfur, and it hinders the use of coal which is rich energy source. In order to simplify the processing system for boiler exhaust gas and to reduce waste water and wastes, Ebara Corp. developed the dry simultaneous desulfurizing and denitrating technology utilizing electron beam in cooperation with Japan Atomic Energy Research Institute. The flow chart of the system applied to the exhaust gas treatment in a coal-fired thermal power station is shown. The mechanism of desulfurization and denitration, and the features of this system are described. The demonstration plant was constructed in a coal-fired thermal power station in Indianapolis, Indiana, USA, and the trial operation was completed in July, 1987. The test results are reported. (K.I.)

  5. Three-dimensional reconstruction method on the PDE exhaust plume flow flame temperature field

    Zhang, Zhimin; Wan, Xiong; Luo, Ningning; Li, Shujing

    2010-10-01

    Pulse detonation engine (referred to as PDE) has many advantage about simple structure, high efficiency thermal [1] cycling etc. In the future, it can be widely used in unmanned aircraft, target drone, luring the plane, the imaginary target, target missiles, long-range missiles and other military targets. However, because the exhaust flame of PDE is complicated [2], non-uniform temperature distribution and mutation in real time, its 3-D temperature distribution is difficult to be measured by normal way. As a result, PDE is used in the military project need to face many difficulties and challenges. In order to analyze and improve the working performance of PDE, deep research on the detonation combustion process is necessary. However, its performance characteristic which is in non-steady-state, as well as high temperature, high pressure, transient combustion characteristics put forward high demands about the flow field parameters measurement. In this paper, the PDE exhaust flames temperature field is reconstructed based on the theory of radiation thermometry [3] and Emission Spectral Tomography (referred to as EST) [4~6] which is one branch of Optical CT. It can monitor the detonation wave temperature distribution out of the exhaust flames at different moments, it also provides authentication for the numerical simulation which directs towards PDE work performance, and then it provides the basis for improving the structure of PDE.

  6. 40 CFR 86.210-08 - Exhaust gas sampling system; Diesel-cycle vehicles not requiring particulate emissions measurements.

    2010-07-01

    ... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Exhaust gas sampling system; Diesel... of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) CONTROL OF... the outside surface of the CVS duct or dilution tunnel....

  7. Effects of injection pressure and injection timing to exhaust gas opacity for a conventional indirect diesel engine

    Budiman, Agus; Majid, Akmal Irfan; Pambayun, Nirmala Adhi Yoga; Yuswono, Lilik Chaerul; Sukoco

    2016-06-01

    In relation to pollution control and environmental friendliness, the quality of exhaust gas from diesel engine needs to be considered. The influences of injection pressure and timing to exhaust gas opacity were investigated. A series of experiments were conducted in a one-cylinder conventional diesel engine with a naturally aspirated system and indirect injection. The default specification of injection pressure was 120 kg/cm2. To investigate the injection pressure, the engine speed was retained on 1000 rpm with pressure variations from 80 to 215 kg/cm2. On the other hand, the various injection timing (8, 10, 12, 16 degrees before TDC point and exact 18 degrees before TDC point) were used to determine their effects to exhaust gas opacity. In this case, the engine speed was varied from 1000 to 2400 rpm. The injector tester was used to measure injection pressure whereas the exhaust gas opacity was determined by the smoke meter. Those data were also statistically analyzed by product moment correlation. As the results, the injection pressure of diesel engine had a non-significant positive correlation to the exhaust gas opacity with r = 0.113 and p > 5 %. Injection pressure should be adjusted to the specification listed on the diesel engine as if it was too high or too low will lead to the higher opacity. Moreover, there was a significant positive correlation between injection timing and the exhaust gas opacity in all engine speeds.

  8. Responses of spruce seedlings (Picea abies) to exhaust gas under laboratory conditions. 1. plant-insect interactions

    Viskari, E.-L.; Koessi, S. [Kuopio Univ. (Finland). Dept. of Ecology and Environmental Science; Surakka, J.; Pasanen, P.; Ruuskanen, J. [Kuopio Univ. (Finland). Dept. of Environmental Sciences; Mirme, A. [Tartu Univ. (Estonia). Int. of Environmental Physics; Holopainen, J.K. [Kuopio Univ. (Finland). Dept. of Ecology and Environmental Science; Agricultural Research Centre, Plant Production research, Jokioinen (Finland)

    2000-07-01

    The effects of motor vehicle exhaust gas on Norway spruce seedlings (Picea abies (L) Karst) and plant-insect interaction of spruce shoot aphid (Cinara pilicornis Hartig) was studied. The exhaust gas concentrations in the fumigation chambers were monitored and controlled by measuring the concentration of nitrogen oxides (NO{sub x}) with a computer aided feedback system. The concentrations of major exhaust gas components (black carbon (BC), fine particles, VOCs and carbonyl compounds) in the chamber air were also measured. Responses of Norway spruce seedlings to a 2 and 3 week exhaust gas exposure and subsequent performance of spruce shoot aphid were studied using realistic exposure regimes; 50, 100 and 200 ppb NO{sub x}. The feedback control system based on NO{sub x} concentrations proved an adequate and practical means for controlling the concentration of exhaust gases and studying plant responses in controlled environment chambers. The exhaust exposure resulted in increased concentrations of proline, glutamine, threonine, aspartic acid, glycine and phenylalanine and decreased concentration of arginine, serine, alanine and glycine in young needles. No changes in soluble N concentrations were observed. The results are interpreted as a stress response rather than use of NO{sub x} as a nitrogen source. No changes in total phenolics and only transient changes in some individual terpene concentrations were detected. The exhaust gas exposure stressed the exposed seedlings, but had no significant effect on N metabolism or the production of defence chemicals. Aphid performance was not significantly affected. Soluble N, secondary metabolism and aphid performance were not sensitive to exhaust gas exposure during shoot elongation in Norway spruce. (author)

  9. Variable-geometry turbocharger with asymmetric divided volute for engine exhaust gas pulse optimization

    Serres, Nicolas

    2010-11-09

    A turbine assembly for a variable-geometry turbocharger includes a turbine housing defining a divided volute having first and second scrolls, wherein the first scroll has a substantially smaller volume than the second scroll. The first scroll feeds exhaust gas to a first portion of a turbine wheel upstream of the throat of the wheel, while the second scroll feeds gas to a second portion of the wheel at least part of which is downstream of the throat. Flow from the second scroll is regulated by a sliding piston. The first scroll can be optimized for low-flow conditions such that the turbocharger can operate effectively like a small fixed-geometry turbocharger when the piston is closed. The turbine housing defines an inlet that is divided by a dividing wall into two portions respectively feeding gas to the two scrolls, a leading edge of the dividing wall being downstream of the inlet mouth.

  10. Multiple Exhaust Nozzle Effects on J-2X Gas Generator Outlet Impedance

    Kenny, R. Jeremy; Muss, Jeffrey; Hulka, James R.; Casiano, Matthew

    2010-01-01

    The current test setup of the J-2X gas generator system uses a multiple nozzle configuration to exhaust hot gases to drive the propellant supply turbines. Combustion stability assessment of this gas generator design requires knowledge of the impedance effects the multiple nozzle configuration creates on the combustion chamber acoustic modes. Parallel work between NASA and Sierra Engineering is presented, showing two methods used to calculate the effective end impedance resulting from multiple nozzle configurations. The NASA method is a simple estimate of the effective impedance using the long wavelength approximation. Sierra Engineering has developed a more robust numerical integration method implemented in ROCCID to accommodate for multiple nozzles. Analysis using both methods are compared to J-2X gas generator test data collected over the past year.

  11. Ion beam analyses of particulate matter in exhaust gas of a ship diesel engine

    There is an urgent need to reduce emission of the particulate matter (PM) in the exhaust gas from ship diesel engines causing various health hazards and serious environmental pollution. Usually the heavy fuel oil (HFO) for ships is of low quality, and contains various kinds of impurities. Therefore, the emission of PM along with exhaust gas from ship diesel engines is one of the most serious environmental issues. However, the PM fundamental properties are not well known. Therefore, it is important to perform elemental analysis of the PM. The HFO contains sulfur with a relatively high concentration of a few percent. It is important to make quantitative measurements of sulfur in the PM, because this element is poisonous for the human body. In the present work, PM samples were collected from exhaust gas of a test engine, and RBS and PIXE analyses were applied successfully to quantitative analysis of the PM samples. The RBS analysis enabled quantitative analysis of sulfur and carbon in the collected PM, while heavier elements such as vanadium and iron were analyzed quantitatively with the PIXE analysis. It has been found that the concentration ratio of sulfur to carbon was between 0.007 and 0.012, and did not strongly depend on the output power of the engine. The S/C ratio is approximately equal to the original composition of the HFO used in the present work, 0.01. From the known conversion ratio 0.015 of sulfur in the HFO to sulfates, the conversion ratio of carbon in the HFO to the PM is found to be 0.01–0.02 by the RBS measurements. On the other hand, the PIXE analysis revealed a vanadium enrichment of one order of magnitude in the PM.

  12. Evaluation of an exhaust gas evacuation system during propane-fueled lift truck maintenance

    Exposure to carbon monoxide (CO) gas in the workplace can cause health problem. CO gas is colourless and odourless, and exposure to it can cause intoxication, particularly for mechanics working on internal combustion engines fed by propane-fueled lift trucks. Regular procedures for evacuating the gases emitted during routine mechanical repairs involve the use of rigid evacuating pipes attached to the building and hooked to a flexible pipe at the end of the exhaust pipe. With lift trucks, this procedure is limited because of the configuration of these vehicles, and also because this type of work is often done in places without access to permanent mechanical ventilation. The object of this study was to propose a new evacuation method for CO gas fumes that would lower the exposures of fumes for mechanics and for workstations. It identified the criteria that should be considered, such as the configuration of the existing exhaust system of lift trucks, and feasibility of using this system at a variety of on-site locations. The design of the device was described and evaluated. 7 refs., 6 tabs., 8 figs., 3 appendices

  13. Remote gas analysis of aircraft exhausts using FTIR-emission-spectroscopy

    Heland, J.; Schaefer, K. [Fraunhofer Inst. for Atmospheric Environmental Research, Garmisch-Partenkirchen (Germany)

    1997-12-31

    FITR emission spectroscopy as a remote sensing multi-component analyzing technique was investigated to determine the composition of aircraft exhausts at ground level. A multi-layer radiative transfer interpretation software based on a line-by-line computer algorithm using the HITRAN data base was developed. Measurements were carried out with different engine types to determine the traceable gas species and their detection limits. Finally validation measurements were made to compare the results of the system to those of conventional equipment. (author) 8 refs.

  14. Implementation of an experimental pilot reproducing the fouling of the exhaust gas recirculation system in diesel engines

    Crepeau Gérald

    2012-04-01

    Full Text Available The European emission standards EURO 5 and EURO 6 define more stringent acceptable limits for exhaust emissions of new vehicles. The Exhaust Gas Recirculation (EGR system is a partial but essential solution for lowering the emission of nitrogen oxides and soot particulates. Yet, due to a more intensive use than in the past, the fouling of the EGR system is increased. Ensuring the reliability of the EGR system becomes a main challenge. In partnership with PSA Peugeot Citroën, we designed an experimental setup that mimics an operating EGR system. Its distinctive features are (1 its ability to reproduce precisely the operating conditions and (2 its ability to measure the temperature field on the heat exchanger surface with an Infra Red camera for detecting in real time the evolution of the fooling deposit based on its thermal resistance. Numerical codes are used in conjunction with this experimental setup to determine the evolution of the fouling thickness from its thermal resistance.

  15. KATsim. A tool for numerically simulating exhaust-gas catalysts; KATsim. Ein Werkzeug zur numerischen Simulation von Abgaskatalysatoren

    Dusemund, Sandra; Schneider, Hellfried; Langeheinecke, Kay [IAV GmbH, Gifhorn (Germany). Geschaeftsbereich Powertrain Mechatronik; Bank, Robert [Rostock Univ. (Germany). Lehrstuhl fuer Technische Thermodynamik

    2009-11-15

    The demands placed on numerically simulating exhaust-gas aftertreatment components are manifold. In addition to laying out the process engineering of exhaust-emission systems, the focus also rests on concept studies for their configuration as well as on 3-D simulations. Increasingly, simulations are also being used for developing and calibrating algorithms for engine control units. To meet these different requirements, IAV is developing the KATsim modular numeric simulation system. (orig.)

  16. Study of SI engine fueled with methanol vapor and dissociation gas based on exhaust heat dissociating methanol

    Highlights: • The full load power decreases successively from gasoline engine, methanol vapor engine to dissociated methanol engine. • Both power and thermal efficiency of dissociated methanol engine can be improved by boosting pressure. • The conversion efficiency of recovered exhaust gas energy is largely influenced by the BMEP. • At the same BMEP, dissociated methanol engine has higher thermal efficiency than methanol vapor engine and gasoline engine. - Abstract: To improve the fuel efficiency of internal combustion (IC) engine and also achieve the goal of direct usage of methanol fuel on IC engine, an approach of exhaust heat dissociating methanol was investigated, which is a kind of method for IC engine exhaust heat recovery (EHR). A bottom cycle system is coupled with the IC engine exhaust system, which uses the exhaust heat to evaporate and dissociate methanol in its catalytic cracker. The methanol dissociation gas (including methanol vapor) is used as the fuel for IC engine. This approach was applied to both naturally aspirated (NA) engine and turbocharged engine, and the engine performance parameters were predicted by the software GT-power under various kinds of operating conditions. The improvement to IC engine performance and the conversion efficiency of recovered exhaust gas energy can be evaluated by comparing the performances of IC engine fueled with various kinds of fuels (or their compositions). Results show that, from gasoline engine, methanol vapor engine to dissociated methanol engine, the full load power decreases successively in the entire speed area due to the declining of volumetric efficiency, while it is contrary in the thermal efficiency at the same brake mean effective pressure (BMEP) level because of the improving of fuel heating value. With the increase of BMEP, the conversion efficiency of recovered exhaust gas energy is promoted. All those results indicate that the approach of exhaust heat dissociating methanol has large

  17. 对废气中氮化物的测量%Measurement of nitrogen compounds in exhaust gas

    2005-01-01

    Environmental standards and technological advances continue to cut emission levels. The lowering of pollutant concentrations in exhaust gas is increasing demands on measurement technology. Measurement of pollutants is required for monitoring and adjusting pollutant reduction systems. Such measurement equipment must be reliable and low maintenance. Continuous gas analyzers from ABB show how innovative approaches permit industrial metrology to achieve higher sensitivity.

  18. DOE 6430.1a compliance checklist for the rotary mode core sampling exhauster flammable gas interlock

    This document examines the Safety Class I criteria in DOE 6430.1a and determines applicability to the rotary mode core sampling exhauster flammable gas interlock. Purpose of the interlock is to prevent the design basis accident of deflagration in single shell flammable gas watchlist tank

  19. Application of Ceria and Lanthana in Catalyst for Cleansing Exhaust Gas of Car

    Yang Chunsheng; Chen Jianhua; Dai Shaojun

    2004-01-01

    The importanCe of rare earths being applied in the catalyst for cleansing the exhaust gas out of car was introduced. The acting mechanism of ceria and lanthana in catalyst and its influencing factors were discussed, and its prospect was forecasted. Pt-Rh precious metals three-way catalyst is widely used for decontaminating the exhaust gas of car now. Ceria and lanthana, which can decrease the content of Pt-Rh and increase the content of Pd in the catalyst, are used as additive in the decontaminating catalyst in order to solve the problem of the supply and demand of Pt and Rh.It is reported that increasing the activity of the coat on catalyst, regulating automatically the ratio of air and fuel, acting as catalyst-accelerator, and improving its properties such as thermal stability and strength may primarily amount for the catalyzing, mechanism of ceria and lanthana. The factors, such as their interaction, additive methods, and effects of cocatalyst ZrO2, CuO, AgO, etc. , will remarkably influence the catalyzing function of ceria and lanthana.

  20. Oxidation and exhaust gas corrosion resistance of the cobalt base clad layers

    H. Smolenska

    2008-12-01

    Full Text Available Purpose: Purpose of this work is describing the behaviour of the cobalt base cladding layers after treatment in hot air (750°C, 200 hours and exhaust gases (700°C, two month.Design/methodology/approach: The layers were produced by two cladding, laser and PTA, cladding technique. Cladding was conducted with a high power diode laser HDPL ROFIN SINAR DL 020 and Plasma Transformed Arc method. The layers consisted of three multitracking sublayers. The cobalt base layers were evaluated by microstructure investigations (optical and scanning electron microscope SEM, chemical analysis and micro hardness measurements.Findings: The microstructure of the investigated layers did not change much, neither on the top part nor in the clad/steel interface after treatment in both environments. On the outer surfaces the oxide layers were observed which consisted generally of chromium and iron oxides. The compositions of this scales were reviled by the EDS analyze. The changes in chemical compositions before and after oxidation and after corrosion in exhaust gases in the dendritic regions and micro regions were confirmed by the semi-quantitative chemical analysis (EDS. Neither the oxidation nor exposition for two month in exhaust gases did not influence on the morphology of the clad layers in any region however changes in chemical composition were observed. For both sort of clads the oxide layers were observed on the surface. The proposed layers are resistant for the hot exhausted gases.Research limitations/implications: The future researches should be done on microstructural and kinetic analyze of high temperature corrosion for higher temperature and times of the process.Practical implications: The clad layers, of this composition, were designed as a method to prolong service time for the ship engine exhausted valve and after this investigation the first valve heads with laser clad layer were installed in working ship engine.Originality/value: The chemical

  1. Analysis of a Temperature-Controlled Exhaust Thermoelectric Generator During a Driving Cycle

    Brito, F. P.; Alves, A.; Pires, J. M.; Martins, L. B.; Martins, J.; Oliveira, J.; Teixeira, J.; Goncalves, L. M.; Hall, M. J.

    2016-03-01

    Thermoelectric generators can be used in automotive exhaust energy recovery. As car engines operate under wide variable loads, it is a challenge to design a system for operating efficiently under these variable conditions. This means being able to avoid excessive thermal dilution under low engine loads and being able to operate under high load, high temperature events without the need to deflect the exhaust gases with bypass systems. The authors have previously proposed a thermoelectric generator (TEG) concept with temperature control based on the operating principle of the variable conductance heat pipe/thermosiphon. This strategy allows the TEG modules’ hot face to work under constant, optimized temperature. The variable engine load will only affect the number of modules exposed to the heat source, not the heat transfer temperature. This prevents module overheating under high engine loads and avoids thermal dilution under low engine loads. The present work assesses the merit of the aforementioned approach by analysing the generator output during driving cycles simulated with an energy model of a light vehicle. For the baseline evaporator and condenser configuration, the driving cycle averaged electrical power outputs were approximately 320 W and 550 W for the type-approval Worldwide harmonized light vehicles test procedure Class 3 driving cycle and for a real-world highway driving cycle, respectively.

  2. Exhaust circulation into dry gas desulfurization process to prevent carbon deposition in an Oxy-fuel IGCC power generation

    Highlights: • Power plant with semi-closed gas turbine and O2–CO2 coal gasifier was studied. • We adopt dry gas sulfur removal process to establish the system. • The exhaust gas circulation remarkably prevented carbon deposition. • Efficiency loss for exhaust gas circulation is quite small. • Appropriate operating condition of sulfur removal process is revealed. - Abstract: Semi-closed cycle operation of gas turbine fueled by oxygen–CO2 blown coal gasification provides efficient power generation with CO2 separation feature by excluding pre-combustion type CO2 capture that usually brings large efficiency loss. The plant efficiency at transmission end is estimated as 44% at lower heating value (LHV) providing compressed CO2 with concentration of 93 vol%. This power generation system will solve the contradiction between economical resource utilization and reduction of CO2 emission from coal-fired power plant. The system requires appropriate sulfur reduction process to protect gas turbine from corrosion and environment from sulfur emission. We adopt dry gas sulfur removal process to establish the system where apprehension about the detrimental carbon deposition from coal gas. The effect of circulation of a portion of exhaust gas to the process on the retardation of carbon deposition was examined at various gas compositions. The circulation remarkably prevented carbon deposition in the sulfur removal sorbent. The impact of the circulation on the thermal efficiency is smaller than the other auxiliary power consumption. Thus, the circulation is appropriate operation for the power generation

  3. Combustion and exhaust emission characteristics of a dual fuel compression ignition engine operated with pilot Diesel fuel and natural gas

    Towards the effort of reducing pollutant emissions, especially soot and nitrogen oxides, from direct injection Diesel engines, engineers have proposed various solutions, one of which is the use of a gaseous fuel as a partial supplement for liquid Diesel fuel. These engines are known as dual fuel combustion engines, i.e. they use conventional Diesel fuel and a gaseous fuel as well. This technology is currently reintroduced, associated with efforts to overcome various difficulties of HCCI engines, using various fuels. The use of natural gas as an alternative fuel is a promising solution. The potential benefits of using natural gas in Diesel engines are both economical and environmental. The high autoignition temperature of natural gas is a serious advantage since the compression ratio of conventional Diesel engines can be maintained. The present contribution describes an experimental investigation conducted on a single cylinder DI Diesel engine, which has been properly modified to operate under dual fuel conditions. The primary amount of fuel is the gaseous one, which is ignited by a pilot Diesel liquid injection. Comparative results are given for various engine speeds and loads for conventional Diesel and dual fuel operation, revealing the effect of dual fuel combustion on engine performance and exhaust emissions

  4. Novel Gas Sensors for High-Temperature Fossil Fuel Applications

    Palitha Jayaweera; Francis Tanzella

    2005-03-01

    SRI International (SRI) is developing ceramic-based microsensors to detect exhaust gases such as NO, NO{sub 2}, and CO in advanced combustion and gasification systems under this DOE NETL-sponsored research project. The sensors detect the electrochemical activity of the exhaust gas species on catalytic electrodes attached to a solid state electrolyte and are designed to operate at the high temperatures, elevated pressures, and corrosive environments typical of large power generation exhausts. The sensors can be easily integrated into online monitoring systems for active emission control. The ultimate objective is to develop sensors for multiple gas detection in a single package, along with data acquisition and control software and hardware, so that the information can be used for closed-loop control in novel advanced power generation systems. This report details the Phase I Proof-of-Concept, research activities performed from October 2003 to March 2005. SRI's research work includes synthesis of catalytic materials, sensor design and fabrication, software development, and demonstration of pulse voltammetric analysis of NO, NO{sub 2}, and CO gases on catalytic electrodes.

  5. Effect of the Sequence of the Thermoelectric Generator and the Three-Way Catalytic Converter on Exhaust Gas Conversion Efficiency

    Su, Chuqi; Tong, Naiqiang; Xu, Yuman; Chen, Shan; Liu, Xun

    2013-07-01

    The potential for thermoelectric exhaust heat recovery in vehicles has increased with recent improvements in the efficiency of thermoelectric generators (TEGs). The problem with using thermoelectric generators for vehicle applications is whether the device is compatible with the original vehicle exhaust system, which determines the quality of the exhaust gas treatment and the realization of energy conservation and emission reduction. Based on ANSYS CFX simulation analysis of the impact of two positional relationships between the TEG and three-way catalytic converter in the exhaust system on the working efficiency of both elements, it is concluded that the layout with the front three-way catalytic converter has an advantage over the other layout mode under current conditions. New ideas for an improvement program are proposed to provide the basis for further research.

  6. Exhaust gas emissions and mutagenic effects of modern diesel fuels, GTL, biodiesel and biodiesel blends

    Munack, Axel; Ruschel, Yvonne; Schroeder, Olaf [Federal Research Institute for Rural Areas, Forestry and Fisheries, Braunschweig (Germany)], E-mail: axel.munack@vti.bund.de; Krahl, Juergen [Coburg Univ. of Applied Sciences (Germany); Buenger, Juergen [University of Bochum (Germany)

    2008-07-01

    Biodiesel can be used alone (B100) or blended with petroleum diesel in any proportion. The most popular biodiesel blend in the U.S.A. is B20 (20% biodiesel, 80% diesel fuel), which can be used for Energy Policy Act of 1992 (EPAct) compliance. In the European Union, the use of biofuel blends is recommended and was introduced by federal regulations in several countries. In Germany, biodiesel is currently blended as B5 (5% biodiesel) to common diesel fuel. In 2008, B7 plus three percent hydrotreated vegetable oil (HVO) as well is intended to become mandatory in Germany. To investigate the influence of blends on the emissions and possible health effects, we performed a series of studies with several engines (Euro 0, III and IV) measuring regulated and non-regulated exhaust compounds and determining their mutagenic effects. Emissions of blends showed an approximate linear dependence on the blend composition, in particular when regulated emissions are considered. However, a negative effect of blends was observed with respect to mutagenicity of the exhaust gas emissions. In detail, a maximum of the mutagenic potency was found in the range of B20. From this point of view, B20 must be considered as a critical blend, in case diesel fuel and biodiesel are used as binary mixtures. (author)

  7. A study on exhaust gas emissions from ships in Turkish Straits

    The Turkish Straits, i.e. Istanbul (Bosphorus) and Canakkale (Dardanellen), which connect Black Sea and Aegean Sea, have a continuously increasing maritime traffic. Especially, the maritime traffic on Bosphorus (Istanbul Strait) that connects the continents of Europe and Asia is too complex due to geographical conditions. The maritime traffic in the Turkish Straits includes the ships, which are in use in domestic transport, the transit passing ships with various aims and fishing, sport or strolling ships. In this paper, fuel consumption and exhaust gas emissions NOx, CO, CO2, VOC, PM exhausted from ships such as transit vessels, which are passing both Bosphorus and Dardanellen, and passenger ships used in domestic transport on the Bosphorus are calculated. In order to do this the general characteristics, the main engine systems, the fuel types, cruising times and speeds of all vessels are taken into consideration. The calculated NOx emissions on the Bosphorus are 2720t from domestic passenger ships and 4357t from transit ships. In this case it is clear that the transit ships cause more than half of the total amount of emissions from ships on the Bosphorus. The amount of nitrogen oxide emissions from domestic passenger ships used for public transport in Istanbul Strait is equal to approx. 4% of nitrogen oxide emissions from motor vehicles in Istanbul. Finally, the future emissions from ships in Turkish Straits are discussed. (Author)

  8. Control of gaseous pollutants emission with EGR (exhaust gas recirculation) and catalytic converter

    Porto, Fernando Silva de Araujo [Faculdade de Engenharia Quimica de Lorena (FAENQUIL), SP (Brazil); Mann, Jens; Ueberschaer, Dietmar [Fachhochschule Darmstadt (Germany). Fachbereich Maschinenbau; Balestieri, Jose Antonio Perrella; Nascimento, Nazem [UNESP, Guaratingueta, SP (Brazil). Faculdade de Engenharia]. E-mail: ftilor@eu.ansp.br; perrella@feg.unesp.br; nazem@feg.unesp.br

    1997-07-01

    Study of gaseous pollutant emission from engine tests simulating real work conditions, using spark point manually controlled and exhaust gas recirculation in diverse proportion levels. The objective of this present work is to re-examine the potential of the EGR conception, a well-known method of combustion control, employed together electronic fuel injection and three-way catalytic converter closed-loop control at a spark ignition engine, verifying the performance characteristics and technical availability of this conception to improve pollution control and fuel economy. The pollutant emissions under operational conditions were analyzed and compared with the expected by concerning theory and real tests performed by EGR equipped engines by factory. (author)

  9. Application of Irradiation. Application to polymer processing, exhaust gas treatment, sterilization of medical instruments and food

    Many fields such as industry, agriculture, medical treatment and environment use radiation. This report explained some examples of irradiation applications. Radiation source is 60Co γ-ray. Polymer industry use radiation for radiation curing (thermally stable polymer), tire, expanded polymer, radiation induced graft copolymerization and electron beam curing. On environmental conservation, radiation is used for elimination of NOx and SOx in exhaust combustion gas. In the medical treatment, radiation is applied to sterilization of medical instruments, that occupied about 50% volume, and blood for transfusion, which is only one method to prevent GVHD after transfusion. On agriculture, irradiation to spice, dry vegetable, frozen kitchen, potato and garlic are carried out in 30 countries. However, potato is only a kind food in Japan. Radiation breeding and pest control are put in practice. (S.Y.)

  10. Dual-catalyst aftertreatment of lean-burn natural gas engine exhaust

    A dual-catalyst system for the reduction of NO with CH4 under lean conditions was investigated. The system is comprised of a mixed bed containing a Co/ZrO2 catalyst, active for the oxidation of NO to NO2, and a Pd/sulfated zirconia (SZ) catalyst that is active for the reduction of NO2 with CH4. Such a system is capable of taking advantage of higher reduction rates for NO2, as compared to NO, that have been previously observed. When simulated exhaust streams from lean-burn natural gas engines are used as feed, the dual-catalyst system is simultaneously active for the reduction of NOx and the oxidation of unburned hydrocarbons and CO. (author)

  11. Effects of exhaust gas recirculation on the thermal efficiency and combustion characteristics for premixed combustion system

    In this research, a boiler in a premixed combustion system used to achieve exhaust gas recirculation was investigated as a way to achieve high thermal efficiencies and low pollutant emissions. The effects of various exhaust gas recirculation (EGR) ratios, equivalence ratios and boiler capacities on thermal efficiency, NOx and CO emissions and the flame behavior on the burner surface were examined both experimentally and numerically. The results of the experiments showed that when EGR was used, the NOx and CO concentrations decreased and the thermal efficiency increased. In the case of a 15% EGR ratio at an equivalence ratio of 0.90, NOx concentrations were found to be smaller than for the current operating condition of the boiler, and the thermal efficiency was approximately 4.7% higher. However, unlike NOx concentrations, although the EGR ratio was increased to 20% at an equivalence ratio of 0.90, the CO concentration was higher than in the current operating condition of the boiler. From the viewpoint of burner safety, the red glow on the burner surface was noticeably reduced when EGR was used. These results confirmed that the EGR method is advantageous from the standpoint of reducing emission concentrations and ensuring burner safety. -- Highlights: ► The premixed boiler system applied EGR was investigated to achieve high thermal efficiencies and low pollutant emissions. ► Thermal efficiency and emission characteristics were examined with EGR ratios, equivalence ratios and boiler capacities. ► EGR method is advantageous from the standpoint of reducing emission concentrations and ensuring burner safety.

  12. Low-temperature gas from marine shales

    Jarvie Daniel M

    2009-02-01

    Full Text Available Abstract Thermal cracking of kerogens and bitumens is widely accepted as the major source of natural gas (thermal gas. Decomposition is believed to occur at high temperatures, between 100 and 200°C in the subsurface and generally above 300°C in the laboratory. Although there are examples of gas deposits possibly generated at lower temperatures, and reports of gas generation over long periods of time at 100°C, robust gas generation below 100°C under ordinary laboratory conditions is unprecedented. Here we report gas generation under anoxic helium flow at temperatures 300° below thermal cracking temperatures. Gas is generated discontinuously, in distinct aperiodic episodes of near equal intensity. In one three-hour episode at 50°C, six percent of the hydrocarbons (kerogen & bitumen in a Mississippian marine shale decomposed to gas (C1–C5. The same shale generated 72% less gas with helium flow containing 10 ppm O2 and the two gases were compositionally distinct. In sequential isothermal heating cycles (~1 hour, nearly five times more gas was generated at 50°C (57.4 μg C1–C5/g rock than at 350°C by thermal cracking (12 μg C1–C5/g rock. The position that natural gas forms only at high temperatures over geologic time is based largely on pyrolysis experiments under oxic conditions and temperatures where low-temperature gas generation could be suppressed. Our results indicate two paths to gas, a high-temperature thermal path, and a low-temperature catalytic path proceeding 300° below the thermal path. It redefines the time-temperature dimensions of gas habitats and opens the possibility of gas generation at subsurface temperatures previously thought impossible.

  13. Improved design of a tangential entry cyclone separator for separation of particles from exhaust gas of diesel engine.

    Mukhopadhyay, N

    2011-01-01

    An effective design of cyclone separator with tangential inlet is developed applying an equation derived from the correlation of collection efficiency with maximum pressure drop components of the cyclone, which can efficiently remove the particles around 1microm of the exhaust gas of diesel engine. PMID:22324145

  14. RE-ENTRAINMENT AND DISPERSION OF EXHAUSTS FROM INDOOR RADON REDUCTION SYSTEMS: ANALYSIS OF TRACER GAS DATA

    Tracer gas studies were conducted around four model houses in a wind tunnel, and around one house in the field, to quantify re-entrainment and dispersion of exhaust gases released from residential indoor radon reduction systems. Re-entrainment tests in the field suggest that acti...

  15. The Effect of Ambient Temperature and Exercise to the Level of Exhaustion on

    Somaye Kasharafifard

    2014-06-01

    Full Text Available Background: The increase in the amount of heat shock protein and C-reactive protein occurring as a result of stress was done with the aims of returning cell homeostasis, successful restoration of cell injury and protection of cell against more injuries. Materials and Methods: Fifteen climber and 15 non athlete subjects were chosen. A selected aerobic test was done by the subjects using Monark bicycle under two different conditions. Before starting the test, the subjects were exposed to a normal condition with the temperature of 24±2°C for an hour and a blood sample was taken from all the subjects. Then immediately, the subjects took the selected aerobic test to the level of exhaustion and blood sample was taken again. A week later, these subjects were exposed to a heated environment with the temperature of 38±2°C, followed by blood sample taking. Finally, the test was done by the subjects to the level of exhaustion and the last blood sample was taken. Then, the amount of heat shock protein (HSP and C - reactive protein (CRP in blood samples was measured. Results: A meaningful difference was observed in the changes of heat shock proteins (p=0.012 and C-reactive protein (p=0.02 between athlete and non athlete subjects. There was no meaningful difference in CRP and HSP in normal and hot condition for non athlete subjects before and after the test. But the result of the study demonstrates that There was a meaningful difference for athletes in both conditions before and after the test (p=0.002. Conclusion: Based on the study, it is claimed that while an athlete is exposed to several stressful conditions (e.g. high temperature and physical exercise, compared to a non athlete, the reaction of his body cells is more significant in order to prevent the injury.

  16. On Developing a Spectroscopic System for Fast Gas Temperature Measurements in Combustion Environments

    Evseev, Vadim; Clausen, Sønnik

    2009-01-01

    Fourier Transform Infra Red (FTIR) spectroscopy techniques are known to provide reliable results for gas temperature measurements and can be comparatively easily performed on an industrial scale such as a boiler on a power plant or an exhaust of a ship engine cylinder. However temporal resolution...

  17. NO{sub x} reduction from a heavy-duty diesel engine with direct injection of natural gas and cooled exhaust gas recirculation

    McTaggart-Cowan, G.; Bushe, W.K.; Hill, P.G. [British Columbia Univ., Dept. of Mechanical Engineering, Vancouver, BC (Canada); Munshi, S.R. [Westport Innovations Inc., Vancouver, BC (Canada)

    2004-06-01

    A heavy-duty ISX diesel engine has been commissioned for single-cylinder operation fuelled with pilot diesel ignited natural gas injected directly into the cylinder. The stock ISX engine was modified by replacing the diesel fuelling system with a high-pressure natural gas system, replacing the turbocharger with an independently controlled supercharger and installing a variable-flow exhaust gas recirculation (EGR) system. A study of the impact of cooled EGR on engine performance and gaseous emissions was carried out. Various engine speeds, loads and injection timings were tested over a range of EGR fractions. A preliminary study of the effect of EGR 'type' - supplemental or replacement - was also carried out. The results indicate that the NO{sub x} emissions varied linearly with the intake oxygen mass fraction (representative of the EGR fraction) until NO{sub x} emissions reached 20 per cent of their non-EGR levels. Further NO{sub x} reductions were achieved with higher EGR fractions, but the rate of reduction was significantly reduced. The NO{sub x} reductions were found to be independent of engine speed and load. An overall activation energy for NO{sub x} formation was determined by correlating the NO{sub x} reductions with a representative flame temperature. The emissions of combustion by-products, including carbon monoxide (CO)and unburned total hydrocarbons (THC) increased significantly at higher EGR fractions. The engine performance and efficiency were not significantly affected except at very high EGR fractions. (Author)

  18. Numerical model of a thermoelectric generator with compact plate-fin heat exchanger for high temperature PEM fuel cell exhaust heat recovery

    Xin, Gao; Andreasen, Søren Juhl; Chen, Min;

    2012-01-01

    plate-fin heat exchangers is adopted. Then the model is validated against experimental data and the main variables are identified by means of a sensitivity analysis. Finally, the system configuration is optimized for recovering heat from the exhaust gas. The results exhibit the crucial importance of the......This paper presents a numerical model of an exhaust heat recovery system for a high temperature polymer electrolyte membrane fuel cell (HTPEMFC) stack. The system is designed as thermoelectric generators (TEGs) sandwiched in the walls of a compact plate-fin heat exchanger. Its model is based on a...... model accuracy and the optimization on system configuration. Future studies will concentrate on heat exchanger structures....

  19. Numerical Simulation of Exhaust Gas Cooling in Channels with Periodic Elbows for Application in Compact Heat Recovery Systems

    Miniature and Micro devices represent the new frontier for advanced heat and mass transfer technology. Due to the small length scales, the use of CFD is very useful for designing and optimizing microfluidic devices since experimentation and visualization at these scales can be difficult. In this work a high temperature air microfluidic cooling strategy for applications such as compact waste heat recovery, exhaust gas recirculation and fuel cell thermal management is proposed. Initially, the application of a simple straight microchannel is considered. In an effort to partially compensate for the poor thermal properties of air, right-angle bends are introduced in order to induce Dean vortices which periodically restart the thermal boundary layer development, thus improving the heat transfer and fluid mixing. Numerical simulations in the range of 100 ≤ ReDh ≤ 1000 have been carried out for channels of square cross-section. Channel wall lengths of 1.0 mm are investigated for elbow spacings of 5 mm, 10 mm and 15 mm. High temperature air (300°C) at atmospheric inlet pressure is the working fluid. The results indicate that the elbows substantially improve the local and average heat transfer in the channels while increasing the pressure drop. Design considerations are discussed which take into account the heat transfer and pressure drop characteristics of the channels.

  20. PERFORMANCE AND EXHAUST GAS EMISSIONS ANALYSIS OF DIRECT INJECTION CNG-DIESEL DUAL FUEL ENGINE

    RANBIR SINGH

    2012-03-01

    Full Text Available Existing diesel engines are under stringent emission regulation particularly of smoke and particulate matter in their exhaust. Compressed Natural Gas and Diesel dual fuel operation is regarded as one of the best ways to control emissions from diesel engines and simultaneously saving petroleum based diesel fuel. Dual fuel engineis a conventional diesel engine which burn either gaseous fuel or diesel or both at the same time. In the present paper an experimental research was carried out on a laboratory single cylinder, four-stroke variable compression ratio, direct injection diesel engine converted to CNG-Diesel dual fuel mode to analyze the performance and emission characteristics of pure diesel first and then CNG-Diesel dual fuel mode. The measurements were recorded for the compression ratio of 15 and 17.5 at CNG substitution rates of 30% and 60% and varying theload from idle to rated load of 3.5kW in steps of 1 up to 3kW and then to 3.5kW. The results reveal that brake thermal efficiency of dual fuel engine is in the range of 30%-40% at the rated load of 3.5 kW which is 11%-13% higher than pure diesel engine for 30% and 60% CNG substitution rates. This trend is observed irrespective of the compression ratio of the engine. Brake specific fuel consumption of dual fuel engine is found better than pure diesel engine at all engine loads and for both CNG substitution rates. It is found that there is drastic reduction in CO, CO2, HC, NOx and smoke emissions in the exhaust of dual fuel engine at all loads and for 30% and 60% CNG substitution rates by employing some optimum operating conditions set forth for experimental investigations in this study.

  1. Optimization of a thermoelectric generator subsystem for high temperature PEM fuel cell exhaust heat recovery

    Gao, Xin; Andreasen, Søren Juhl; Kær, Søren Knudsen;

    2014-01-01

    In previous work, a thermoelectric (TE) exhaust heat recovery subsystem for a high temperature polymer electrolyte membrane (HT-PEM) fuel cell stack was developed and modeled. Numerical simulations were conducted and have identified an optimized subsystem configuration and 4 types of compact heat...... exchangers with superior performance for further analysis. In this work, the on-design performances of the 4 heat exchangers are more thoroughly assessed on their corresponding optimized subsystem configurations. Afterward, their off-design performances are compared on the whole working range of the fuel...... cell stack. All through this study, different electrical connection styles of all the thermoelectric generator (TEG) modules in the subsystem and their influences are also discussed. In the end, the subsystem configuration is further optimized and a higher subsystem power output is achieved. All TEG...

  2. Pd catalysts supported on modified Zr0.5Al0.5O1.75 used for lean-burn natural gas vehicles exhaust purification

    Hongyan Shang; Yun Wang; Maochu Gong; Yaoqiang Chen

    2012-01-01

    Composite supports Zr0.5Al0.5O1.75 modified by metal oxides,such as La2O3,ZnO,Y2O3 or BaO,were prepared by co-precipitation method,and palladium catalysts supported on the modified composite supports were prepared by impregnation method.Their properties were characterized by X-ray diffraction (XRD),NH3 temperature-programmed desorption (NH3-TPD),H2 temperature-programmed reduction (H2-TPR),N2 adsorption/desorption,and CO-chemisorption.The catalytic activity and the resistance to water poisoning of the prepared Pd catalysts were tested in a simulated exhaust gas from lean-burn natural gas vehicles with and without water vapor.The results demonstrated that the modified supports had an apparent effect on the performance of Pd catalysts,compared with the Pd catalyst supported on the unmodified ZrAl.The addition of ZnO or Y2O3 promoted the conversion of CH4.In the absence of water vapor,Pd/ZnZrAl exhibited the best activity for CH4 conversion with the light-off temperature (T50) of 275 ℃ and the complete conversion temperature (T90) of 314 ℃,respectively.However,in the presence of water vapor,Pd/YZrAl was the best one over which the light-off temperature (T50) of methane was 339 ℃ and the complete conversion temperature (T90) was 371 ℃.These results indicated that Pd catalyst supported on the modified composite ZrAl support showed excellent catalytic activity at low temperature and high resistance to H2O poisoning for the exhaust purification of lean-burn natural gas vehicles.

  3. The performance of a monolithic catalytic converter of automobile exhaust gas with oscillatory feeding of CO, NO, and O{sub 2}. A modelling study

    Nievergeld, A.J.L.; Hoebink, J.H.B.J.; Marin, G.B. [Lab. voor Chemische Technologie, Eindhoven Univ. of Technology, Eindhoven (Netherlands)

    1995-12-31

    An isothermal monolithic catalytic converter of automobile exhaust gas was modelled in order to assess the effects of oscillatory feeding of CO, O{sub 2} and NO on the performance of the reactor. The influence of the temperature, frequency, and amplitude on the time average conversions was investigated. An improvement relative to the steady state conversion of 8% for CO and 30% for NO can be obtained. An explanation is given in terms of strongly changing surface coverage during cycling of the feed concentrations. 9 figs., 5 tabs., 16 refs.

  4. Study of an exhaust gas recirculation equipped micro gas turbine supplied with bio-fuels

    The authors discuss in this paper some aspects related to the employment of liquid and gaseous bio-fuels in a micro-gas turbine. Besides the purpose of checking the effectiveness of methods for supplying the micro-turbine with fuels from renewable sources, the attention is focused on the need of controlling the pollutant emission. To this aim, several solutions are experienced and numerically tested. For the liquid fuel supply, a new shape and location of the main fuel injector is combined with a modified position of the pilot injector. In the case of the biogas fuelling, an external EGR option is considered as activated. Both methods aim at the reduction of the thermal and prompt NO formation by approaching the flameless combustion concept. -- Highlights: • External and internal EGR concepts applied to NOx control from micro gas turbines. • For gaseous fuels: internal EGR is obtained by a proper location of the pilot injector. • For liquid fuels: replacing the original radial injectors with a pressure swirl atomizer. • We apply a CFD based method, after validation with experimental data. • Blends of bio-fuels with fossil fuels promise noticeable benefits

  5. On exhaust emissions from petrol-fuelled passenger cars at low ambient temperatures

    Laurikko, J. [VTT Energy, Espoo (Finland). Energy Use

    1998-11-01

    The study at hand deals with regulated and unregulated exhaust emissions from petrol-fuelled cars at low ambient temperatures with present-day or near-future exhaust after treatment systems. The subject has been investigated at VTT over a decade and this report compiles data from various sub-studies carried out between the years 1993 - 1997. Each one of them viewed different aspects of the phenomenon, like determining the low-temperature response of today`s new cars employing three-way catalytic converters or assessing the long-term durability and the influence of vehicle mileage upon the low-temperature emissions performance. Within these studies, together more than 120 cars of model years from 1990 to 1997 have been tested. Most of them were normal, in-service vehicles with total mileages differing between only a few thousand kilometres for new cars up to 80,000 km or even more for the in-use vehicles. Both the US FTP75 and the European test cycle have been employed, and the ambient temperatures ranged from the baseline (+22 deg C) down to +- O deg C, -7 deg C and in some cases even to -20 deg C. The studies attested that new cars having today`s advanced emissions control systems produced fairly low levels of emissions when tested in conditions designated in the regulations that are the basis of the current new-vehicle certification. However, this performance was not necessarily attained at ambient temperatures that were below the normative range. Fairly widespread response was recorded, and cars having almost equal emissions output at baseline could produce largely deviating outcomes in low-temperature conditions. On average, CO and HC emissions increased by a factor of five to 10, depending on the ambient temperature and vehicle type. However, emissions of NO{sub x} were largely unaffected. Apart from these regulated emissions, many unregulated species were also determined, either by using traditional sampling and chromatography methods or on-line, employing

  6. Low-temperature gas from marine shales

    Jarvie Daniel M; Mango Frank D

    2009-01-01

    Abstract Thermal cracking of kerogens and bitumens is widely accepted as the major source of natural gas (thermal gas). Decomposition is believed to occur at high temperatures, between 100 and 200°C in the subsurface and generally above 300°C in the laboratory. Although there are examples of gas deposits possibly generated at lower temperatures, and reports of gas generation over long periods of time at 100°C, robust gas generation below 100°C under ordinary laboratory conditions is unprecede...

  7. Combustion and exhaust emission characteristics of a compression ignition engine using liquefied petroleum gas-Diesel blended fuel

    Towards the effort of reducing pollutant emissions, especially smoke and nitrogen oxides, from direct injection (DI) Diesel engines, engineers have proposed various solutions, one of which is the use of a gaseous fuel as a partial supplement for liquid Diesel fuel. The use of liquefied petroleum gas (LPG) as an alternative fuel is a promising solution. The potential benefits of using LPG in Diesel engines are both economical and environmental. The high auto-ignition temperature of LPG is a serious advantage since the compression ratio of conventional Diesel engines can be maintained. The present contribution describes an experimental investigation conducted on a single cylinder DI Diesel engine, which has been properly modified to operate under LPG-Diesel blended fuel conditions, using LPG-Diesel blended fuels with various blended rates (0%, 10%, 20%, 30%, 40%). Comparative results are given for various engine speeds and loads for conventional Diesel and blended fuels, revealing the effect of blended fuel combustion on engine performance and exhaust emissions

  8. Establishing isokinetic flow for a plasma torch exhaust gas diagnostic for a plasma hearth furnace

    Pollack, B.R.

    1996-05-01

    Real time monitoring of toxic metallic effluents in confined gas streams can be accomplished through use of Microwave Induced Plasmas to perform atomic emission spectroscopy, For this diagnostic to be viable it is necessary that it sample from the flowstream of interest in an isokinetic manner. A method of isokinetic sampling was established for this device for use in the exhaust system of a plasma hearth vitrification furnace. The flow and entrained particulate environment were simulated in the laboratory setting using a variable flow duct of the same dimensions (8-inch diameter, schedule 40) as that in the field and was loaded with similar particulate (less than 10 {mu}m in diameter) of lake bed soil typically used in the vitrification process. The flow from the furnace was assumed to be straight flow. To reproduce this effect a flow straightener was installed in the device. An isokinetic sampling train was designed to include the plasma torch, with microwave power input operating at 2.45 GHz, to match local freestream velocities between 800 and 2400 ft/sec. The isokinetic sampling system worked as planned and the plasma torch had no difficulty operating at the required flowrates. Simulation of the particulate suspension was also successful. Steady particle feeds were maintained over long periods of time and the plasma diagnostic responded as expected.

  9. Reducing the CO2 emissions from fossil fuel power plans by exhaust gas treatment

    The emission of carbon dioxide (CO2) and other pollutants which result from burning fossil fuels has been identified as the major contributor to global warming and climate change. However, for the short term, at least for the next 10-20 years, the world will continue to rely on fossil fuels as the source of primary energy. The challenge for the fossil the fuel industry is to find cost-effective solutions that will reduce the release of CO2 and other pollutants into the atmosphere. The focus of this paper is on the ability to treat the exhaust gas from fossil fuel power plants in order to capture and store the CO2 and remove the other pollutants such as SOx and NOx which are released into the atmosphere. In summary, capture/separation costs represent the largest financial impediment for this type of plants. Hence, efficient, cost-effective capture/separation technologies need to be developed to allow their large-scale use. (author)

  10. On Developing a Spectroscopic System for Fast Gas Temperature Measurements in Combustion Environments

    Evseev, Vadim; Clausen, Sønnik

    2009-01-01

    Fourier Transform Infra Red (FTIR) spectroscopy techniques are known to provide reliable results for gas temperature measurements and can be comparatively easily performed on an industrial scale such as a boiler on a power plant or an exhaust of a ship engine cylinder. However temporal resolution is not high enough to trace fast temperature variations which are of great importance for complete combustion diagnostics. To eliminate the above mentioned shortcoming, a new IR spectroscopic-imaging...

  11. Reduction of the exhaust gas emissions during warm up by improving the mixture preparation of spark-ignition engines

    During warm-up the engine emits the highest concentration of exhaust gas emissions. An improvement of the atomization behaviour of the injected fuel should lead to a good mixture preparation in the manifold and combustion chamber and further to lower exhaust gas emissions during warm up. During these investigations it was found out that the build-up of fuel film in the manifold of cold spark-ignition engines can not be prevented. But by injecting the fuel at the open inlet valve it is possible to reduce the fuel film. The injection of extremely finely atomized fuel at the open inlet valve leads to a better mixture preparation with smaller fuel dropplets in the manifold and combustion chamber. This again leads, during warm-up of the spark ignition engine, to a reduction of the HC emissions of 30% and the CO emissions of 50%. (author)

  12. Pyrometric Gas and Surface Temperature Measurements

    Fralick, Gustave; Ng, Daniel

    1999-01-01

    A multiwavelength pyrometer possessing advantages over the one- and two-wavelength designs is described. Results of its application to surface temperature measurements of ceramics is presented. Also described is a probe suitable for gas temperature measurements to temperatures > 2600 K. The design of the probe includes a multiwavelength pyrometer with fiber optic input.

  13. Analysis of the state and size of silver on alumina in effective removal of NOx from oxygen rich exhaust gas

    Arve, K.; Klingstedt, F.; Eränen, K.; Murzin, D. Yu.; Čapek, Libor; Dědeček, Jiří; Sobalík, Zdeněk; Wichterlová, Blanka; Svennerberg, K.; Wallenberg, L. R.; Bovin, J.-O.

    2006-01-01

    Roč. 6, č. 4 (2006), s. 1076-1083. ISSN 1533-4880 R&D Projects: GA AV ČR 1ET400400413 Grant ostatní: European Union(XE) GR5D-CT 2001-00595 Institutional research plan: CEZ:AV0Z40400503 Keywords : silver * exhaust gas * removal of NOx Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 2.194, year: 2006

  14. Robust control of speed and temperature in a power plant gas turbine.

    Najimi, Ebrahim; Ramezani, Mohammad Hossein

    2012-03-01

    In this paper, an H(∞) robust controller has been designed for an identified model of MONTAZER GHAEM power plant gas turbine (GE9001E). In design phase, a linear model (ARX model) which is obtained using real data has been applied. Since the turbine has been used in a combined cycle power plant, its speed and also the exhaust gas temperature should be adjusted simultaneously by controlling fuel signals and compressor inlet guide vane (IGV) position. Considering the limitations on the system inputs, the aim of the control is to maintain the turbine speed and the exhaust gas temperature within desired interval under uncertainties and load demand disturbances. Simulation results of applying the proposed robust controller on the nonlinear model of the system (NARX model), fairly fulfilled the predefined aims. Simulations also show the improvement in the performance compared to MPC and PID controllers for the same conditions. PMID:22062324

  15. Thermodynamic and economic performances optimization of an organic Rankine cycle system utilizing exhaust gas of a large marine diesel engine

    Highlights: • A new parameter is proposed for optimizing economic performance of the ORC system. • Maximal thermodynamic and economic performances of an ORC system are presented. • The corresponding operating pressures in turbine of optimum thermodynamic and economic performances are investigated. • An optimal effectiveness of pre-heater is obtained for the ORC system. - Abstract: The aim of this study is to investigate the thermodynamic and economic performances optimization for an ORC system recovering the waste heat of exhaust gas from a large marine diesel engine of the merchant ship. Parameters of net power output index and thermal efficiency are used to represent the economic and thermodynamic performances, respectively. The maximum net power output index and thermal efficiency are obtained and the corresponding turbine inlet pressure, turbine outlet pressure, and effectiveness of pre-heater of the ORC system are also evaluated using R1234ze, R245fa, R600, and R600a. Furthermore, the analyses of the effects of turbine inlet temperature and cooling water temperature on the optimal economic and thermodynamic performances of the ORC system are carried out. The results show that R245fa performs the most satisfactorily followed by R600, R600a, and R1234ze under optimal economic performance. However, in the optimal thermodynamic performance evaluations, R1234ze has the largest thermal efficiency followed by R600a, R245fa, and R600. The payback periods will decrease from 0.5 year for R245fa to 0.65 year for R1234ze respectively as the system is equipped with a pre-heater. In addition, compared with conventional diesel oil feeding, the proposed ORC system can reduce 76% CO2 emission per kilowatt-hour

  16. Temperature Modulation of a Catalytic Gas Sensor

    Eike Brauns; Eva Morsbach; Sebastian Kunz; Marcus Baeumer; Walter Lang

    2014-01-01

    The use of catalytic gas sensors usually offers low selectivity, only based on their different sensitivities for various gases due to their different heats of reaction. Furthermore, the identification of the gas present is not possible, which leads to possible misinterpretation of the sensor signals. The use of micro-machined catalytic gas sensors offers great advantages regarding the response time, which allows advanced analysis of the sensor response. By using temperature modulation, additi...

  17. Temperature Controlled Filamentation in Argon Gas

    CAO Shi-Ying; KONG Wei-Peng; SONG Zhen-Ming; QIN Yu; LI Ru-Xin; WANG Qing-Yue; ZHANG Zhi-Gang

    2008-01-01

    Temperature controlled filamentation is experimentally demonstrated in a temperature gradient gas-filled tube.The proper position of the tube is heated by a furnace and two ends of the tube are cooled by air. The experimental results show that multiple filaments are shrunken into a single fila.ment or no filament only by increasing the temperature at the beginning of the filament. This technique offers another degree of freedom of controlling the filamentation and opens a new way for intense monocycle pulse generation through gradient temperature in a noble gas.

  18. Investigation of the Performance of HEMT-Based NO, NO2 and NH3 Exhaust Gas Sensors for Automotive Antipollution Systems

    Halfaya, Yacine; Bishop, Chris; Soltani, Ali; Sundaram, Suresh; Aubry, Vincent; Voss, Paul L.; Salvestrini, Jean-Paul; Ougazzaden, Abdallah

    2016-01-01

    We report improved sensitivity to NO, NO2 and NH3 gas with specially-designed AlGaN/GaN high electron mobility transistors (HEMT) that are suitable for operation in the harsh environment of diesel exhaust systems. The gate of the HEMT device is functionalized using a Pt catalyst for gas detection. We found that the performance of the sensors is enhanced at a temperature of 600 °C, and the measured sensitivity to 900 ppm-NO, 900 ppm-NO2 and 15 ppm-NH3 is 24%, 38.5% and 33%, respectively, at 600 °C. We also report dynamic response times as fast as 1 s for these three gases. Together, these results indicate that HEMT sensors could be used in a harsh environment with the ability to control an anti-pollution system in real time. PMID:26907298

  19. ANALYSIS OF EXHAUST GAS EMISSION IN THE MARINE TWO-STROKE SLOW-SPEED DIESEL ENGINE

    Branko Lalić; Gojmir Radica; Nikola Račić

    2016-01-01

    This paper explores the problem of exhaust emissions of the marine two-stroke slow-speed diesel engines. After establishing marine diesel engine regulations and defining the parameters influencing exhaust emissions, the simulation model of the marine two-stroke slow-speed diesel engine has been developed. Furthermore, the comparison of numerical and experimentally obtained data has been performed, resulting in achieving the model validity at 100% load, which represents a requirement for furth...

  20. Investigation of ambient temperature on the performance of GE-F5 gas turbine

    The role of ambient temperature in determining the performance of GE-F5 gas turbine is analysed by investigating the Shirvan gas turbine power plant 10MW, 15MW and 20MW power output. These parameters have been brought as a function of ambient temperature. The results show when ambient temperature increases 1 deg C, The compressor pressure decreases about 20kPa, compressor outlet temperature increases about 1.13 deg C and exhaust temperature increases about 2.5 deg C. It is revealed that variations are due to decreasing the efficiency of compressor and less due to mass flow rate of air reduction as ambient temperature increases at constant power output. The results shows cycle efficiency reduces 3% with increasing 50 of ambient temperature, also the m increases as ambient temperature increase for constant turbine work. These are also because of reducing the compressor efficiency as ambient temperature increases

  1. The Heat Exchanger Performance of Shell and Multi Tube Helical Coil as a Heater through the Utilization of a Diesel Machine’s Exhaust Gas

    . Zainuddin

    2016-04-01

    Full Text Available A review on reutilization of heat waste from a diesel machine is absolutely important. This is because the exhaust gas potential of a Diesel machine keeps increasing and not much has been utilized by the industry. One of the techniques of reutilizing the heat waste in industry is by using a heat exchanger. The technique is also very useful for the environment because it can reduce air pollution caused by the exhaust gas of the diesel machine. The main purpose of the research is to find out the capability of shell and multi-tube helical coil HE as an air heater by utilizing the exhaust gas of the Diesel machine. The heat exchanger of shell and multi-tube helical coil  utilizes the exhaust thermal gas of the Diesel machine as the air heater already made. The apparatus has the following dimension: the shell length of 1.05 m, diameter 0.1524 m, tube length of 3.25 m with 20 coils, tube diameter of 0.011 m, coil diameter of 0.0508 m with 4 helical coils. The type of Diesel machine to use in the testing is 4FB1 Isuzu Diesel engine. The machine has the maximum machine power and rotation of 54 kW and 3,600 rpm. The performance testing of heat exchanger has been conducted in some variations of Diesel machine rotations of 1,500 rpm, 1,750 rpm, 2,000 rpm, 2,250 rpm and 2,500 rpm. The testing result shows a maximum effectiveness to happen at the machine rotation of 1,500 rpm. The maximum effectiveness to get is 67.8% and then it goes down drastically in accordance with the increase of air mass flow rate. The hot air temperature created is from 47.1°C to 52.3°C so that it can be used for the purpose of drying up the unhulled rice.

  2. Effects of Gas Velocity and Temperature on Nitric Oxide Conversion in Simulated Catalytic Converter

    Sathaporn Chuepeng

    2012-01-01

    Full Text Available Problem statement: Gaseous emissions from gasoline engine such as carbon monoxide, unburned hydrocarbon and nitrogen oxides were usually reduced in three-way catalytic converter simultaneously around theoretical fuel and air combustion. Engine speed and load and other parameters were varied over a wide range of operating conditions, resulting in different exhaust gas composition and condition intake into catalytic converter. This work was studied the conversion of Nitric Oxide (NO in exhaust gas catalytic converter affected by gas velocity and inlet temperature using numerical modeling. Approach: The simulation was based on a one-dimensional time-dependent model within a single monolith channel of the converter. Upon certain assumptions, the study was considered heterogeneous combustion reaction between gas and solid phases based on lumped kinetic reactions. In this study, constants and variables used for mass and heat transfers were dependent on gas or solid phase temperature and mole fraction. Finite difference scheme incorporated with the generated computer code was established for solving species and energy balances within gas and solid phases. Results: The NO conversion was increased with transient period in initial and reached steady state at different values. The lower inlet gas temperature was resulted in lesser NO conversion at the same inlet NO concentration and gas velocity. The light-off temperatures were up to 520 K and a sudden rise in NO conversion was from 550-605 K and decreasing onwards, generating working temperature window. NO conversion increased throughout the catalyst bed from the inlet and the conversion decreased as the gas velocity increased. Conclusion/Recommendations: Gas space velocity and gas temperature intake to the converter affected the NO conversion over the time and the axial distance from the catalyst bed inlet. The numerical results have summarily demonstrated a good approximation compared to experimental

  3. Effect of Exhaust Gas Recirculation and Combustible Oxygen Mass Fraction on Emission Index of NOx for Counterflow Methane/Air Diffusion Flames

    Sane, Mugdha S

    2013-01-01

    Exhaust gas recirculation has been proven to be an effective method of reducing emissions of oxides of nitrogen (NOx) from internal combustion engines. The present study validates this effect through flame simulations using detailed chemistry. Counterflow methane/air diffusion flames were simulated in one dimension in physical space using GRI-Mech 3.0 detailed chemistry mechanism, thermal, and transport data. The influence of Exhaust Gas Recirculation (EGR) on the flame structure and NOx emis...

  4. Thermally grown oxide films and corrosion performance of ferritic stainless steels under simulated exhaust gas condensate conditions

    Highlights: • Five ferritic stainless steels with dissimilar composition included. • Thermal oxide films and performance under exhaust gas condensate conditions studied. • Oxide films grown at 300 and 600 °C show differences in structure and properties. • Performance of alloys with >11.5 wt.% Cr is related to elements Ti, Si, Nb and Mo. • Compositional optimization requires knowledge on several linked processes. - Abstract: Five ferritic stainless steels are characterized in terms of thermally grown oxide films and corrosion performance under simulated exhaust gas condensate conditions. Oxide films developed at 300 °C show only little variation in microstructure and properties between the alloys, whereas those evolved at 600 °C exhibit clear differences. Especially in alloys with >11.5 wt.% chromium, the presence and distribution of such alloying elements as titanium, silicon, niobium and molybdenum are crucial for the film properties and the overall corrosion performance. The results may be exploited in the compositional optimization of the alloys for the cold-end components of automotive exhaust system

  5. Estimation of exhaust gas aerodynamic force on the variable geometry turbocharger actuator: 1D flow model approach

    Highlights: • Estimation of aerodynamic force on variable turbine geometry vanes and actuator. • Method based on exhaust gas flow modeling. • Simulation tool for integration of aerodynamic force in automotive simulation software. - Abstract: This paper provides a reliable tool for simulating the effects of exhaust gas flow through the variable turbine geometry section of a variable geometry turbocharger (VGT), on flow control mechanism. The main objective is to estimate the resistive aerodynamic force exerted by the flow upon the variable geometry vanes and the controlling actuator, in order to improve the control of vane angles. To achieve this, a 1D model of the exhaust flow is developed using Navier–Stokes equations. As the flow characteristics depend upon the volute geometry, impeller blade force and the existing viscous friction, the related source terms (losses) are also included in the model. In order to guarantee stability, an implicit numerical solver has been developed for the resolution of the Navier–Stokes problem. The resulting simulation tool has been validated through comparison with experimentally obtained values of turbine inlet pressure and the aerodynamic force as measured at the actuator shaft. The simulator shows good compliance with experimental results

  6. Effect of ejector dilutors on measurements of automotive exhaust gas aerosol size distributions

    Ejector dilutors have long been used for automotive exhaust particle sampling, as they can offer a low-cost option for stable dilution. In an ejector dilutor, pressurized air expanding in the periphery of a nozzle draws in and mixes with an exhaust sample which is then led to analytical equipment. The combination of processes involved may lead to particle losses which can affect the measurement. This study examines the losses of diesel exhaust particles of different characteristics (nucleation mode, non-volatile accumulation mode, internally and externally mixed accumulation mode) when these are sampled through an ejector dilutor. A scanning mobility particle sizer (SMPS), an electrical low-pressure impactor and a diffusion charger were used as analytical equipment to characterize losses with different instruments. Particle losses were found negligible for all practical applications of diesel exhaust aerosol sampling. Also, the sampling outlet and the operating pressure of the ejector dilutor were found to have a non-measurable effect on the distribution shape. Some variation of the labile nucleation mode particles was attributed to evaporation within the SMPS rather than an ejector effect, and this was confirmed by sampling solid NaCl particles in the same size range. The study further confirms the usability of ejector dilutors for exhaust particle sampling and dilution

  7. Oxidation and corrosion fatigue aspects of cast exhaust manifolds

    Ekström, Madeleine

    2015-01-01

    Emission regulations for heavy-duty diesel engines are becoming increasingly restrictive to limit the environmental impacts of exhaust gases and particles. Increasing the specific power output of diesel engines would improve fuel efficiency and greatly reduce emissions, but these changes could lead to increased exhaust gas temperature, increasing demands on the exhaust manifold material. This is currently the ferritic ductile cast iron alloy SiMo51, containing about 4 wt% Si and ~1 wt% Mo, wh...

  8. Effect of ambient temperature on the performance of micro gas turbine with cogeneration system in cold region

    A small-scale prime mover especially micro gas turbine is a key factor in order to widespread the utilization of biogas. It is well known that a performance of large-scale gas turbine is greatly affected by its inlet air temperature. However, the effect of the inlet air temperature on the performance of small-scale gas turbine (micro gas turbine) is not widely reported. The purpose of the present study is to investigate the effect of the inlet air temperature on the performance of a micro gas turbine (MGT) with cogeneration system (CGS) arrangement. An analysis model of the MGT-CGS was set up on the basis of experimental results obtained in a previous study and a manufacturer standard data, and it was analysed under a various ambient temperature condition in a cold region. The results show that when ambient temperature increased, electrical efficiency ηele of the MGT decreased but exhaust heat recovery ηehr increased. It was also found that when ambient temperature increased, exhaust heat to mass flow rate Qexe/me and exhaust heat recovery to mass flow rate Qehr/me increased, with maximum ratios of 259 kJ/kg and 200 kJ/kg, respectively were found in summer peak. Furthermore, it was also found that the exhaust heat to power ratio Qexe/Pe had a similar characteristic with exhaust heat recovery to power ratio Qehr/Pe. Qexe/Pe and Qehr/Pe increased with the increase of ambient temperature. Moreover, although different values of total energy efficiency, fuel energy saving and CO2 reduction for every temperature condition were found comparing with a two conventional system that were considered, the MGT-CGS could annually reduce 30,000-80,000 m3/y of fuel consumption and 35-94 t-CO2/y of CO2 emissions. - Research highlights: → Micro gas turbine cogeneration system (MGT-CGS) has higher electrical efficiency and lower exhaust heat recovery efficiency under cold condition. → MGT-CGS has lower exhaust heat and exhaust heat recovery to power ratio under cold condition.

  9. Gas conduction in a high temperature reactor

    The hot gas is distributed and mixed by polygonal blocks in the reactor floor. Radial and an annular channel are used for this purpose. This annular channel also carried circular ducts distributed evenly over the circumference, which lead to a heat exchanger. Temperature differences across the crossection of the reactor floor are evened out by multiple deflection, combination and renewed splitting of the gas flows. (DG)

  10. High temperature gas-cooled reactor technology

    The high temperature gas-cooled reactor (HTGR) with a direct cycle helium system has drawn attention as the next generation nuclear power plant that is closest to commercialization. Fuji Electric participated in the design, manufacture and construction of JAPCO's Tokai-1 plant, a 'Colder Hall' type reactor, which was the first commercial nuclear power plant in Japan, and JAERI's high temperature engineering test reactor (HTTR), which was the first high temperature gas-cooled reactor in Japan. Fuji Electric, a pioneer of gas-cooled reactors, worked on the design, construction and development of these reactors. This paper provides brief descriptions of the air-cooled spent fuel storage system of the HTTR, material test facilities for the HTTR, and the development of an inherently safe and highly efficient commercial HTGR power plant as examples of Fuji Electric's recent activities in the HTGR field. (author)

  11. Micro- and Nanostructural Characteristics of Particles Before and After an Exhaust Gas Recirculation System Scrubber

    Lieke, Kirsten Inga; Rosenørn, Thomas; Pedersen, Jannik;

    2013-01-01

    atomic scale such as layer distance, lamella length, and tortuosity were not observed to be influenced by the scrub-ber. We also found that particles in the size range between 30 and 50 nm, which were abundant in the exhaust before and after scrubber, were not graphitic soot. Furthermore, we found...

  12. Fast spatially resolved exhaust gas recirculation (EGR) distribution measurements in an internal combustion engine using absorption spectroscopy.

    Yoo, Jihyung; Prikhodko, Vitaly; Parks, James E; Perfetto, Anthony; Geckler, Sam; Partridge, William P

    2015-09-01

    Exhaust gas recirculation (EGR) in internal combustion engines is an effective method of reducing NOx emissions while improving efficiency. However, insufficient mixing between fresh air and exhaust gas can lead to cycle-to-cycle and cylinder-to-cylinder non-uniform charge gas mixtures of a multi-cylinder engine, which can in turn reduce engine performance and efficiency. A sensor packaged into a compact probe was designed, built and applied to measure spatiotemporal EGR distributions in the intake manifold of an operating engine. The probe promotes the development of more efficient and higher-performance engines by resolving high-speed in situ CO2 concentration at various locations in the intake manifold. The study employed mid-infrared light sources tuned to an absorption band of CO2 near 4.3 μm, an industry standard species for determining EGR fraction. The calibrated probe was used to map spatial EGR distributions in an intake manifold with high accuracy and monitor cycle-resolved cylinder-specific EGR fluctuations at a rate of up to 1 kHz. PMID:26253286

  13. The impact of using biodiesel/marine gas oil blends on exhaust emissions from a stationary diesel engine.

    Karavalakis, G; Tzirakis, E; Mattheou, L; Stournas, S; Zannikos, F; Karonis, D

    2008-12-01

    The purpose of this work was to investigate the impact of marine gas oil (MGO)/biodiesel blends on the exhaust emissions and fuel consumption in a single cylinder, stationary, diesel engine. Three different origins of biodiesel were used as the blending feedstock with the reference MGO, at proportions of 5 and 10% by volume. Methyl esters were examined according to the automotive FAME standard EN 14214. The baseline MGO and biodiesel blends were examined according to ISO 8217:2005 specifications for the DMA category. Independently of the biodiesel used, a decrease of PM, HC, CO and CO(2) emissions was observed. Emissions of NO(x) were also lower with respect to MGO. This reduction in NO(x) may be attributed to some physicochemical properties of the fuels applied, such as the higher cetane number and the lower volatility of methyl esters. Reductions in PM for biodiesel blends were lower in the exhaust than those of the reference fuel which was attributed to the oxygen content and the near absence of sulphur and aromatics compounds in biodiesel. However, a slight increase in fuel consumption was observed for the biodiesel blends that may be tolerated due to the exhaust emissions benefits. Brake thermal efficiency was also determined. Unregulated emissions were characterized by determining the soluble organic fraction content of the particulate matter. PMID:18988104

  14. Kinetic plots for programmed temperature gas chromatography.

    Jespers, Sander; Roeleveld, Kevin; Lynen, Frederic; Broeckhoven, Ken; Desmet, Gert

    2016-06-10

    The applicability of the kinetic plot theory to temperature-programmed gas chromatography (GC) has been confirmed experimentally by measuring the efficiency of a temperature gradient separation of a simple test mixture on 15, 30, 60 and 120m long (coupled) columns. It has been shown that the temperature-dependent data needed for the kinetic plot calculation can be obtained from isothermal experiments at the significant temperature, a temperature that characterizes the entire gradient run. Furthermore, optimal flow rates have been calculated for various combinations of column length, diameter, and operating temperature (or significant temperature). The tabulated outcome of these calculations provide good starting points for the optimization of any GC separation. PMID:27179678

  15. Iodine retention from process gas and exhaust air in dissolving aluminium-clad fuel elements in nitric acid

    In the 99Mo Production Facility Rossendorf (AMOR) aluminium-clad fuel elements irradiated for about 200 h in the Rossendorf Research Reactor are chemically reprocessed after a cooling time of 48 h. The iodine isotopes produced together with a number of the other fission products have to be separated from the solution gas because of their radiotoxicity, volatility, and amount. Although iodine is retained in the facility, the existing exhaust air system was completed by a specific filter system in order to prevent any iodine releases

  16. Helium turbine power generation in high temperature gas reactor

    This paper presents studies on the helium turbine power generator and important components in the indirect cycle of high temperature helium cooled reactor with multi-purpose use of exhaust thermal energy from the turbine. The features of this paper are, firstly the reliable estimation of adiabatic efficiencies of turbine and compressor, secondly the introduction of heat transfer enhancement by use of the surface radiative heat flux from the thin metal plates installed in the hot helium and between the heat transfer coil rows of IHX and RHX, thirdly the use of turbine exhaust heat to produce fresh water from seawater for domestic, agricultural and marine fields, forthly a proposal of plutonium oxide fuel without a slight possibility of diversion of plutonium for nuclear weapon production and finally the investigation of GT-HTGR of large output such as 500 MWe. The study of performance of GT-HTGR reduces the result that for the reactor of 450 MWt the optimum thermal efficiency is about 43% when the turbine expansion ratio is 3.9 for the turbine efficiency of 0.92 and compressor efficiency of 0.88 and the helium temperature at the compressor inlet is 45degC. The produced amount of fresh water is about 8640 ton/day. It is made clear that about 90% of the reactor thermal output is totally used for the electric power generation in the turbine and for the multi-puposed utilization of the heat from the turbine exhaust gas and compressed helium cooling seawater. The GT-Large HTGR is realized by the separation of the pressure and temperature boundaries of the pressure vessel, the increase of burning density of the fuel by 1.4 times, the extention of the nuclear core diameter and length by 1.2 times, respectively, and the enhancement of the heat flux along the nuclear fuel compact surface by 1.5 times by providing riblets with the peak in the flow direction. (J.P.N.)

  17. Influence of steam injection through exhaust heat recovery on the design performance of solid oxide fuel cell . gas turbine hybrid systems

    This study analyzed the influence of steam injection on the performance of hybrid systems combining a solid oxide fuel cell and a gas turbine. Two different configurations (pressurized system and ambient pressure system) were examined and the effects of injecting steam, generated by recovering heat from the exhaust gas, on system performances were compared. Performance variations according to the design of different turbine inlet temperatures were examined. Two representative gas turbine pressure ratios were used. Without steam injection, the pressurized system generally exhibits higher system efficiency than the ambient pressure system. The steam injection augments gas turbine power, thus increasing the power capacity of the hybrid system. The power boost effect due to the steam injection is generally greater in the relatively higher pressure ratio design in both the pressurized and ambient pressure systems. The effect of the steam injection on system efficiency varies depending on system configurations and design conditions. The pressurized system hardly takes advantage of the steam injection in terms of system efficiency. On the other hand, the steam injection contributes to the efficiency improvement of the ambient pressure system in some design conditions. In particular, a higher pressure ratio provides a better chance of efficiency increase due to the steam injection

  18. Low-temperature gas from marine shales: wet gas to dry gas over experimental time

    Jarvie Daniel M; Mango Frank D

    2009-01-01

    Abstract Marine shales exhibit unusual behavior at low temperatures under anoxic gas flow. They generate catalytic gas 300° below thermal cracking temperatures, discontinuously in aperiodic episodes, and lose these properties on exposure to trace amounts of oxygen. Here we report a surprising reversal in hydrocarbon generation. Heavy hydrocarbons are formed before light hydrocarbons resulting in wet gas at the onset of generation grading to dryer gas over time. The effect is moderate under ga...

  19. Polymer spiral film gas-liquid heat exchanger for waste heat recovery in exhaust gases

    Breton, Antoine

    2012-01-01

    In this master thesis report the development of an innovative spiral heat exchanger based on polymer materials is described. Building prototypes, erection of a test bench and firsts tests of the heat exchanger are presented. The heat exchanger prototype survived all tests especially several days in contact with aggressive gases. A facility integrating a Diesel exhaust gases production has been developed to test this heat exchanger design. Performance results obtained during the tes...

  20. Improving engine efficiency by extracting laser energy from hot exhaust gas

    We show that it is possible to improve the efficiency of a classical Otto-cycle heat engine by adding a high-Q microwave cavity and a laser system that can extract coherent laser energy from thermally excited 'exhaust' atoms. This improvement does not violate the second law of thermodynamics, i.e., we show that a combined high-Q microwave cavity and a laser system does not improve the efficiency of a classical Carnot-cycle heat engine

  1. 40 CFR 86.1710-99 - Fleet average non-methane organic gas exhaust emission standards for light-duty vehicles and...

    2010-07-01

    ... 40 Protection of Environment 19 2010-07-01 2010-07-01 false Fleet average non-methane organic gas....1710-99 Fleet average non-methane organic gas exhaust emission standards for light-duty vehicles and light light-duty trucks. (a) Fleet average NMOG standards and compliance. (1) Each manufacturer...

  2. Prediction of emissions and exhaust temperature for direct injection diesel engine with emulsified fuel using ANN

    KÖKKÜLÜNK, Görkem; Akdoğan, Erhan; AYHAN, Vezir

    2012-01-01

    Exhaust gases have many effects on human beings and the environment. Therefore, they must be kept under control. The International Convention for the Prevention of Pollution from Ships (MARPOL), which is concerned with the prevention of marine pollution, limits the emissions according to the regulations. In Emission Control Area (ECA) regions, which are determined by MARPOL as ECAs, the emission rates should be controlled. Direct injection (DI) diesel engines are commonly used as a prop...

  3. Emission characteristics of iso-propanol/gasoline blends in a spark-ignition engine combined with exhaust gas re-circulation

    Gong Jing

    2014-01-01

    Full Text Available Experiments were carried out in a spark-ignition engine fueled with iso-propanol/gasoline blends. Emission characteristics of this engine were investigated experimentally, including gaseous emissions (HC, CO, NOx and particulate matter emission in term of number and size distributions. The effects of different iso-propanol percentages, loads and exhaust gas recirculation rates on emissions were analyzed. Results show that the introduction of exhaust gas recirculation reduces the NOx emission and NOx emission gives the highest value at full load condition. HC and CO emissions present inconspicuous variations at all the loads except the load of 10%. Additionally, HC emission shows a sharp increase for pure propanol when the exhaust gas recirculation rate is up to 5%, while little variation is observed at lager exhaust gas recirculation rates. Moreover, the particulate matter number concentration increases monotonically with the increase of load and the decrease of exhaust gas recirculation rate. There exists a critical spark timing that produces the highest particulate matter number concentration at all the blending ratios.

  4. Principle Findings from Development of a Recirculated Exhaust Gas Intake Sensor (REGIS) Enabling Cost-Effective Fuel Efficiency Improvement

    Schnabel, Claus [Robert Bosch LLC, Farmington Hills, MI (United States)

    2016-03-30

    : publication of two new technical papers by Clemson detailing the control strategies used for the EGR system control. The two papers was published in the 2016 SAE World Congress in April 2016. The titles of each paper are, “Physics-Based Exhaust Pressure and Temperature Estimation for Low Pressure EGR Control in Turbocharged Gasoline Engines,” by K. Siokos, and “A Control Algorithm for Low Pressure – EGR Systems using a Smith Predictor with Intake Oxygen Sensor Feedback”, by R. Koli. All phase III work packages have been completed. The primary work packages in phase III were the following: completion of long-term sensor durability testing, final demonstration of benefits of EGR control w/o sensing, final decision of the second generation sensor development path.

  5. The pilot plant experiment of electron beam irradiation process for removal of NOx and SOx from sinter plant exhaust gas in the iron and steel industry

    Air pollution problem has become more important in the progress of industry. Nitrogen oxides (NOx, mostly NO) and sulfur oxides (SOx, mostly SO2) which are contained in a sinter plant exhaust gas, are known as serious air pollutants. In such circumstances, an attempt has been made to simultaneously remove NOx and SOx from the sinter plant exhaust gas by means of a new electron beam irradiation process. The process consists of adding a small amount of NH3 to the exhaust gas, irradiating the gas by electron beam, forming ammonium salts by reactions of NOx and SOx with the NH3 and collecting ammonium salts by dry electrostatic precipitator (E.P.). Basic research on the present process had been performed using heavy oil combustion gas. Based on the results research was launched to study the applicability of the process to the treatment of sinter plant exhaust gas. A pilot plant, capable of treating a gas flow of 3000 Nm3/H was set up, and experiments were performed from July 1977 to June 1978. The plant is described and the results are presented. (author)

  6. Operating limitations due to low gas temperature

    Bruschi, R.; Ghiselli, W.; Spinazze, M.

    1995-12-31

    A number of projects concerning continental links for the transport of treated natural gas over long distance, both on and offshore, have been implemented during the last few years or are currently being implemented. The long trunklines in North America and subsea trunklines planned or already in operation in the North Sea, are outstanding examples of such long distance transmission of gas in large diameter pipelines operated at high pressure. The development of such network has paid special attention to the effects that low temperature resulting from the transportation process may imply in terms of pipe structural integrity and environmental impact. Scope of this paper is to discuss operating limitations due to low gas temperature. New project scenarios are presented in a brief introduction. The fluido-thermo-dynamic background for the development of low temperatures are outlined. Finally some topics relevant to structural integrity are discussed in particular such as the pipe steel behaviour at low temperature, the prediction techniques of the ice bulb growth around the pipe, the interactions of the cold line with the soil and the consequences due to the differential compliancy of the pipeline towards points of fixity (in-line valves/tees or fixed plants). 30 refs., 22 figs., 1 tab.

  7. Quantification of diesel exhaust gas phase organics by a thermal desorption proton transfer reaction mass spectrometer

    M. H. Erickson

    2012-02-01

    Full Text Available A new approach was developed to measure the total abundance of long chain alkanes (C12 and above in urban air using thermal desorption with a proton transfer reaction mass spectrometer (PTR-MS. These species are emitted in diesel exhaust and may be important precursors to secondary organic aerosol production in urban areas. Long chain alkanes undergo dissociative proton transfer reactions forming a series of fragment ions with formula CnH2n+1. The yield of the fragment ions is a function of drift conditions. At a drift field strength of 80 Townsends, the most abundant ion fragments from C10 to C16 n-alkanes were m/z 57, 71 and 85. The PTR-MS is insensitive to n-alkanes less than C8 but displays an increasing sensitivity for larger alkanes. Higher drift field strengths yield greater normalized sensitivity implying that the proton affinity of the long chain n-alkanes is less than H2O. Analysis of diesel fuel shows the mass spectrum was dominated by alkanes (CnH2n+1, monocyclic aromatics, and an ion group with formula CnH2n−1 (m/z 97, 111, 125, 139. The PTR-MS was deployed in Sacramento, CA during the Carbonaceous Aerosols and Radiative Effects Study field experiment in June 2010. The ratio of the m/z 97 to 85 ion intensities in ambient air matched that found in diesel fuel. Total diesel exhaust alkane concentrations calculated from the measured abundance of m/z 85 ranged from the method detection limit of ~1 μg m−3 to 100 μg m−3 in several air pollution episodes. The total diesel exhaust alkane concentration determined by this method was on average a factor of 10 greater than the sum of alkylbenzenes associated with spark ignition vehicle exhaust.

  8. Amperometric NOx-sensor for Combustion Exhaust Gas Control. Studies on transport properties and catalytic activity of oxygen permeable ceramic membranes

    The aim of the research described in this thesis is the development of a mixed conducting oxide layer, which can be used as an oxygen permselective membrane in an amperometric NOx sensor. The sensor will be used in exhaust gas systems. The exhaust gas-producing engine will run in the lean mix mode. The preparation of this sensor is carried out using screen-printing technology, in which the different layers of the sensor are applied successively. Hereafter, a co-firing step is applied in which all layers are sintered together. This co-firing step imposes several demands on the selection of materials. The design specifications of the sensor further include requirements concerning the operating temperature, measurement range and overall stability. The operating temperature of the sensor varies between 700 and 850C, enabling measurement of NOx concentrations between 50 and 1200 ppm with a measurement accuracy of 10 ppm. Concerning the stability of the sensor, it must withstand the exhaust gas atmosphere containing, amongst others, smoke, acids, abrasive particles and sulphur. Because of the chosen lean-mix engine concept, in which the fuel/air mixture switches continuously between lean (excess oxygen) and fat (excess fuel) mixtures, the sensor must withstand alternately oxidising and reducing atmospheres. Besides, it should be resistant to thermal shock and show no cross-sensitivity of NOx with other exhaust gas constituents like oxygen and hydrocarbons. The response time should be short, typically less than 500 ms. Because of the application in combustion engines of cars, the operational lifetime should be longer than 10 years. Demands on the mixed conducting oxide layer include the following ones. The layer should show minimal catalytic activity towards NOx-reduction. The oxygen permeability must be larger than 6.22 10-8 mol/cm2s at a layer thickness between 3-50 μm. Since the mixed conducting oxide layer is coated on the YSZ electrolyte embodiment, the two

  9. Impact of intake CO 2 addition and exhaust gas recirculation on NO x emissions and soot reactivity in a common rail diesel engine

    Al-Qurashi, Khalid

    2012-10-18

    The impact of intake CO 2 addition and exhaust gas recirculation (EGR) on engine combustion characteristics, NO x emissions, and soot oxidative reactivity was studied in a common rail diesel engine equipped with a cooled EGR system. The engine test results and the heat release analysis show that the reduced flame temperature, induced by the reduction of the oxygen concentration (dilution effect) is the dominant mechanism via which CO 2 and EGR lower NO x emissions in diesel engines. On the other hand, the collected soot from the engine tests was examined for its oxidative reactivity using a thermogravimetric analyzer (TGA). Results show that EGR has a significant effect on soot reactivity and results in higher initial active sites compared to the CO 2 case. We conclude that the reduced flame temperature (thermal effect) which is a consequence of the dilution effect is responsible for the observed increase in soot reactivity. These results confirm observations from our past work on flame soot, which showed that the peak adiabatic flame temperature is the governing factor affecting soot reactivity. These findings imply that driving the combustion concepts toward low temperature is favorable to effectively control engine pollutants, including soot reactivity. © 2012 American Chemical Society.

  10. IAEA high temperature gas cooled reactor activities

    IAEA activities on high temperature gas cooled reactors are conducted with the review and support of Member States, primarily through the International Working Group on Gas Cooled Reactors (IWGGCR). This paper summarises the results of the IAEA gas cooled reactor project activities in recent years along with ongoing current activities through a review of Co-ordinated Research Projects (CRPs), meetings and other international efforts. A series of three recently completed CRPs have addressed the key areas of reactor physics for LEU fuel, retention of fission products, and removal of post shutdown decay heat through passive heat transport mechanisms. These activities along with other completed and ongoing supporting CRPs and meetings are summarised with reference to detailed documentation of the results. (author)

  11. Ejection of toxic and carcinogenic substances along with the exhaust gasses of gas turbine engines and ways of reducing them

    Varshavskiy, I.L.; Kanilo, P.M.; Khesina, A.Y.; Ryabeka, V.P.; Smirnov, G.A.

    1981-01-01

    Studies of the amount of carcinogenic substances in exhaust gasses of piston aviation engines showed that the concentration of Benzene (A) tyrene in exhaust gasses is found at a level of 0.5-5 micrograms/m/sup 3/. It increases with an increase of a load, rotation frequency and angle of advance of fuel injection. The maximum concentration of Benzene(A)tyrene is observed in transitional states related to acceleration of the airplane. Measures to reduce the ejection of NO (injection of water into the combustion chamber, the use of water and fuel emulsions, recirculation of the treated gasses into the combustion chamber) relates to an increase of Benzene(a)tyrene ejections. Tests were carried out on an experimental test bed using the gas turbine aviation engine type AI-9 to determine the amount of waste gasses that are carcinogenic and toxic. The Benzene(a)tyrene concentration in waste gasses of piston engines (0.8 micrograms/m/sup 3/) with an increase of the total coefficient of excess air in a combustion chamber increases by a factor of 2 to 4. Enriching the fuel-air mixture with hydrogen in a combustion chamber of a gas turbine engine by adding hydrogen to the primary zone of the combustion chamber simultaneously reduces the concentration of waste gasses, Benzene(a)tyrene and CO. For the AI-25 gas turbine engine the addition of hydrogen in the amount of 5% mass of fuel reduces the ejection of CO by a factor of 2, and that of Benzene(a)tyrene by a factor of 7.

  12. Exhaust Gas Analysis and Parametric Study of Ethanol Blended Gasoline Fuel in Spark Ignition Engine

    Jitendra kumar

    2013-07-01

    Full Text Available It is well known that the future availability of energy resources, as well as the need for reducing CO2 emissions from the fuels used has increased the need for the utilization of regenerative fuels. This research is done taking commercial gasoline as reference which is originally blended with 5% ethanol. Hence 5%, 10%, 15%, 20% ethanol blended with Gasoline initially was tested in SI engines. Physical properties relevant to the fuel were determined for the four blends of gasoline. A four cylinder, four stroke, varying rpm, Petrol (MPFI engine was tested on blends containing 5%,10%,15%,20% ethanol and performance characteristics, and exhaust emissions were evaluated. Even though higher blends can replace gasoline in a SI engine, results showed that there is a reduction in exhaust gases, such as HC, O2, CO, CO2 and increase in Brake Thermal Efficiency on blending. Hence we can conclude from the result that using 10% ethanol blend is most effective and we can utilize it for further use in SI engines with little constraint on material used to sustain little increase in pressure.

  13. Lightweight Exhaust Manifold and Exhaust Pipe Ducting for Internal Combustion Engines

    Northam, G. Burton (Inventor); Ransone, Philip O. (Inventor); Rivers, H. Kevin (Inventor)

    1999-01-01

    An improved exhaust system for an internal combustion gasoline-and/or diesel-fueled engine includes an engine exhaust manifold which has been fabricated from carbon- carbon composite materials in operative association with an exhaust pipe ducting which has been fabricated from carbon-carbon composite materials. When compared to conventional steel. cast iron. or ceramic-lined iron paris. the use of carbon-carbon composite exhaust-gas manifolds and exhaust pipe ducting reduces the overall weight of the engine. which allows for improved acceleration and fuel efficiency: permits operation at higher temperatures without a loss of strength: reduces the "through-the wall" heat loss, which increases engine cycle and turbocharger efficiency and ensures faster "light-off" of catalytic converters: and, with an optional thermal reactor, reduces emission of major pollutants, i.e. hydrocarbons and carbon monoxide.

  14. The Evolution of High Temperature Gas Sensors.

    Garzon, F. H. (Fernando H.); Brosha, E. L. (Eric L.); Mukundan, R. (Rangachary)

    2001-01-01

    Gas sensor technology based on high temperature solid electrolytes is maturing rapidly. Recent advances in metal oxide catalysis and thin film materials science has enabled the design of new electrochemical sensors. We have demonstrated prototype amperometric oxygen sensors, nernstian potentiometric oxygen sensors that operate in high sulfur environments, and hydrocarbon and carbon monoxide sensing mixed potentials sensors. Many of these devices exhibit part per million sensitivities, response times on the order of seconds and excellent long-term stability.

  15. Bicycle Painting Exhaust Gas Treatment Technology Comparison%自行车涂装废气治理技术的对比

    杜万义; 张晓燕

    2015-01-01

    The exhaust gas of bicycle spraying mainly contains two parts. The first part is the mist particles which appear during spraying process. The second part is VOC which appear during the process of spraying and drying. This paper describes the main treatment method of the exhaust gas during bicycle spraying.%自行车涂装废气主要有两部分,一是喷涂过程中产生的漆雾颗粒物,二是喷涂和烘干过程中产生的VOC。本文阐述了涂装废气的治理主要方法。

  16. Low-temperature gas from marine shales: wet gas to dry gas over experimental time

    Jarvie Daniel M

    2009-11-01

    Full Text Available Abstract Marine shales exhibit unusual behavior at low temperatures under anoxic gas flow. They generate catalytic gas 300° below thermal cracking temperatures, discontinuously in aperiodic episodes, and lose these properties on exposure to trace amounts of oxygen. Here we report a surprising reversal in hydrocarbon generation. Heavy hydrocarbons are formed before light hydrocarbons resulting in wet gas at the onset of generation grading to dryer gas over time. The effect is moderate under gas flow and substantial in closed reactions. In sequential closed reactions at 100°C, gas from a Cretaceous Mowry shale progresses from predominately heavy hydrocarbons (66% C5, 2% C1 to predominantly light hydrocarbons (56% C1, 8% C5, the opposite of that expected from desorption of preexisting hydrocarbons. Differences in catalyst substrate composition explain these dynamics. Gas flow should carry heavier hydrocarbons to catalytic sites, in contrast to static conditions where catalytic sites are limited to in-place hydrocarbons. In-place hydrocarbons and their products should become lighter with conversion thus generating lighter hydrocarbon over time, consistent with our experimental results. We recognize the similarities between low-temperature gas generation reported here and the natural progression of wet gas to dry gas over geologic time. There is now substantial evidence for natural catalytic activity in source rocks. Natural gas at thermodynamic equilibrium and the results reported here add to that evidence. Natural catalysis provides a plausible and unique explanation for the origin and evolution of gas in sedimentary basins.

  17. Gas turbine high temperature reactor, GTHTR-300

    The high temperature gas reactor (HTGR) has some characters without previously set reactors such as capability of taking out heat with high temperature, high specific safety, and so on. The gas turbine high temperature reactor (GTHTR) activating such characters has some advantages such as high power generation efficiency, feasibility on simplification of safety apparatus, and so on, and that has excellent economical efficiency. Recently, this GTHTR system is positively promoted on its investigation in South Africa, U.S.A., Russia, Holland, China, France, and so on. In JAERI, on a base of the feasibility study on GTHTR carried out fiscal year 1996 to 2000 as an entrusted research by the Science and Technology Agency, a design investigation on an actual use GTHTR (GTHTR-300) with excellent safety economical efficiency and operation feature and about 300 MW in electric output by using Japanese own technology has been progressed. The GTHTR-300 is an excellent system adopted Japanese initiative also for GTHTR as well as activated some reactor related technologies accumulated on HTGR R and D in Japan at a center of HTTR (high temperature engineering test reactor). Here were described on developing target, design concept, and a route to actual use of GTHTR. (G.K.)

  18. The study of heat transfer for nanofluid with carbon nano particle in an exhaust gas recirculation (EGR) cooler

    Kim, Seongsoo; Chung, Hanshik; Jeong, Hyomin; Lee, Byungho; Ochirkhuyag, Bayanjargal; Lee, Jehyun; Choi, Heekyu

    2013-07-01

    A carbon nanofluid was adapted to examine the characteristics of its cooling performance in an exhaust gas recirculation (EGR) cooler, compared with that of the usual working fluid water. After steady state, the heat transfer rate of water became nearly constant; however, that of the nanofluid showed a slight increase, suggesting that something happened to the nanofluid. The result shows that the cooling performance of the carbon nanofluid was a little better than that of water; however, its performance data improved with time while those of water were stable. It shows that assembly of the carbon nanoparticles changed with its circulation through the EGR cooler and the shape of the particle assembly depended on the dispersion method employed.

  19. High temperature gas-cooled reactor: gas turbine application study

    The high-temperature capability of the High-Temperature Gas-Cooled Reactor (HTGR) is a distinguishing characteristic which has long been recognized as significant both within the US and within foreign nuclear energy programs. This high-temperature capability of the HTGR concept leads to increased efficiency in conventional applications and, in addition, makes possible a number of unique applications in both electrical generation and industrial process heat. In particular, coupling the HTGR nuclear heat source to the Brayton (gas turbine) Cycle offers significant potential benefits to operating utilities. This HTGR-GT Application Study documents the effort to evaluate the appropriateness of the HTGR-GT as an HTGR Lead Project. The scope of this effort included evaluation of the HTGR-GT technology, evaluation of potential HTGR-GT markets, assessment of the economics of commercial HTGR-GT plants, and evaluation of the program and expenditures necessary to establish HTGR-GT technology through the completion of the Lead Project

  20. High temperature gas-cooled reactor: gas turbine application study

    1980-12-01

    The high-temperature capability of the High-Temperature Gas-Cooled Reactor (HTGR) is a distinguishing characteristic which has long been recognized as significant both within the US and within foreign nuclear energy programs. This high-temperature capability of the HTGR concept leads to increased efficiency in conventional applications and, in addition, makes possible a number of unique applications in both electrical generation and industrial process heat. In particular, coupling the HTGR nuclear heat source to the Brayton (gas turbine) Cycle offers significant potential benefits to operating utilities. This HTGR-GT Application Study documents the effort to evaluate the appropriateness of the HTGR-GT as an HTGR Lead Project. The scope of this effort included evaluation of the HTGR-GT technology, evaluation of potential HTGR-GT markets, assessment of the economics of commercial HTGR-GT plants, and evaluation of the program and expenditures necessary to establish HTGR-GT technology through the completion of the Lead Project.

  1. Estimation of current density distribution of PAFC by analysis of cell exhaust gas

    Kato, S.; Seya, A. [Fuji Electric Co., Ltd., Ichihara-shi (Japan); Asano, A. [Fuji Electric Corporate, Ltd., Yokosuka-shi (Japan)

    1996-12-31

    To estimate distributions of Current densities, voltages, gas concentrations, etc., in phosphoric acid fuel cell (PAFC) stacks, is very important for getting fuel cells with higher quality. In this work, we leave developed a numerical simulation tool to map out the distribution in a PAFC stack. And especially to Study Current density distribution in the reaction area of the cell, we analyzed gas composition in several positions inside a gas outlet manifold of the PAFC stack. Comparing these measured data with calculated data, the current density distribution in a cell plane calculated by the simulation, was certified.

  2. Device for the removal of sulfur dioxide from exhaust gas by pulsed energization of free electrons

    The performance of a new device using pulsed streamer corona for the removal of sulfur dioxide from humid air has been evaluated. The pulsed streamer corona produced free electrons which enhance gas-phase chemical reactions, and convert SO2 to sulfuric acid mist. The SO2 removal efficiency was compared with that of the electron-beam flue-gas treatment process. The comparison demonstrates the advantage of the novel device

  3. Near-explicit Gas-phase Chemistry Coupled with Extensive Aqueous Mechanism: Looking at Ethanol (E85) Exhaust in a Fog

    Ginnebaugh, D. L.; Jacobson, M. Z.

    2011-12-01

    We combine a near-explicit gas-phase chemical mechanism with an extensive aqueous mechanism in a chemical solver to examine the effects of ethanol (E85) versus gasoline on the fate of pollutants in the presence of a fog. We use the Master Chemical Mechanism (MCM, version 3.1, Leeds University) and the Chemical Aqueous Phase Radical Mechanism, CAPRAM 3.0, with the SMVGEAR II chemical ordinary differential solver to provide the speed necessary to simulate complex chemistry. The MCM has over 13, 500 organic reactions and 4,600 species, while CAPRAM treats aqueous chemistry among 390 species and 829 reactions (including 51 gas-to-aqueous phase reactions). We validate a simplified version of the model against results from a comprehensive intercomparison by Barth et al (2003). In previous work on ethanol (E85), we analyzed the temperature-dependence of ethanol and gasoline exhaust chemistry and its impact on urban air pollution considering only gas-phase chemistry. In addition to the air pollution findings, we verified that using the MCM with SMVGEAR is practical in a 3-D model. Here, we extend our study to include aqueous chemistry in the presence of a fog. We investigate the impact aqueous reactions have on unburned ethanol and acetaldehyde mixing ratios in the atmosphere in particular because acetaldehyde is an ozone precursor and carcinogen, and aqueous oxidation has potential to speed the conversion of unburned ethanol to acetaldehyde. Acetaldehyde also forms acetic acid in aqueous solution. Acetic acid vapor is an eye, nose, and lung irritant, so both species contribute negatively to human health. We look at the impact of fog liquid water content and temperature on the degradation of emitted aromatic and other species as well, from both gasoline and E85.

  4. Control of PCDDs/PCDFs, PCBs and PAHs emissions in exhaust of landfill gas fed engines

    Idczak, F.; Dengis, P.; Duchateau, P.; Petitjean, S. [ISSeP, Liege (Belgium)

    2004-09-15

    Wallonia in Belgium, like many countries around the world, planned to reduce amounts of waste generated by human activity and stored in landfills. Since they experienced a couple of crisis situations in the past, both with former and presently used landfill sites, authorities launched a demanding landfill monitoring program which covers now 9 out of the 10 major sites. Biogas produced in these landfills are collected and eliminated in two different ways. Either simply burned in a flare, or, when the methane grade and flow are high enough, the biogas can be burned in electricity producing engines. This later use represents an energy recovery from the waste. In the context of difficulty for landfill sites to be accepted by the public (the well-known NIMBY phenomenon), the question has been raised whether combustion of the biogas did not entail production of dioxins and other polyaromatic compounds. For the exhaust gases of engines operated with biogas, a check on the presence of dioxins and associated organic pollutants, composed of three different runs or days of sampling for each of 5 landfill sites was performed upon demand of responsible authorities.

  5. 40 CFR 86.110-94 - Exhaust gas sampling system; diesel-cycle vehicles, and Otto-cycle vehicles requiring particulate...

    2010-07-01

    ... 40 Protection of Environment 18 2010-07-01 2010-07-01 false Exhaust gas sampling system; diesel... 86.110-94 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS... CFV-EFC-CVS), sample system with heat exchanger connected to a dilution tunnel. The heat exchanger...

  6. 14 CFR 29.1123 - Exhaust piping.

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Exhaust piping. 29.1123 Section 29.1123... STANDARDS: TRANSPORT CATEGORY ROTORCRAFT Powerplant Exhaust System § 29.1123 Exhaust piping. (a) Exhaust... by operating temperatures. (b) Exhaust piping must be supported to withstand any vibration...

  7. 14 CFR 27.1123 - Exhaust piping.

    2010-01-01

    ... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Exhaust piping. 27.1123 Section 27.1123... STANDARDS: NORMAL CATEGORY ROTORCRAFT Powerplant Exhaust System § 27.1123 Exhaust piping. (a) Exhaust piping... operating temperatures. (b) Exhaust piping must be supported to withstand any vibration and inertia loads...

  8. Inhalation of diesel engine exhaust affects spermatogenesis in growing male rats; Diesel enigne hai gas bakuro ni yoru seicho yusei rat no seishi keisei eno eiky

    Kawai, A. [Japan Automobile Research Institute Inc., Tsukuba (Japan)

    2000-04-01

    The paper investigated effects of the exposure of diesel engine exhaust on internal secretion function of genital organs of rats being in growth. Exposure tests were divided into a group of exposing rats to total exhaust gas (TG), a group of exposing rats to particulate-free exhaust gas (PFG), and a group of exposing rats to clean air (comparison group). The tests were carried out for 6 hours/day, for 5 days/week, and for 3 months from the birth. As to the weight at the time of finishing tests, there were no significant differences in weights of testicle and epididymis in each group. About the concentration of male/female sex hormones in serum, the values were significantly higher in TG and PFG groups than the comparison group. The follide stimulating hormone significantly decreased in both exposure groups as compared with the comparison group. The luteinizing hormone significantly decreased in TG group as compared with the comparison group and PFG group. Further, the sperm productivity and testicle hyaluronidase activity significantly decreased in both exhaust exposure groups as compared with the comparison group. It is indicated that the diesel engine exhaust stimulates the secretion of adrenal cortical hormone, reduces emission of gonadotropic hormone, and controls the spermatogenesis of rats. (NEDO)

  9. METHANE EMISSIONS FROM THE NATURAL GAS INDUSTRY VOLUME 11: COMPRESSOR DRIVER EXHAUST

    The 15-volume report summarizes the results of a comprehensive program to quantify methane (CH4) emissions from the U.S. natural gas industry for the base year. The objective was to determine CH4 emissions from the wellhead and ending downstream at the customer's meter. The accur...

  10. 30 CFR 36.47 - Tests of exhaust-gas cooling system.

    2010-07-01

    ... water consumption, high-water level when the system sprays excess water, and low-water level when the... allowable liquid fuel rate and governed speed with 0.5 ±0.1 percent, by volume, of natural gas in the intake... cooling water shall be filled with the quantity of water recommended by the applicant. No cooling...

  11. 78 FR 63015 - Exhaust Emissions Standards for New Aircraft Gas Turbine Engines and Identification Plate for...

    2013-10-23

    ... kilonewtons (kN) (76 FR 45012). The EPA also proposed adopting the gas turbine engine test procedures of the... 18, 2012 (77 FR 36342), and was effective July 18, 2012. On December 31, 2012, the FAA published a final rule with a request for comments (77 FR 76842) adopting the EPA's new emissions standards in...

  12. Development of High Temperature Gas Sensor Technology

    Hunter, Gary W.; Chen, Liang-Yu; Neudeck, Philip G.; Knight, Dak; Liu, Chung-Chiun; Wu, Quing-Hai; Zhou, Huan-Jun

    1997-01-01

    The measurement of engine emissions is important for their monitoring and control. However, the ability to measure these emissions in-situ is limited. We are developing a family of high temperature gas sensors which are intended to operate in harsh environments such as those in an engine. The development of these sensors is based on progress in two types of technology: (1) The development of SiC-based semiconductor technology; and (2) Improvements in micromachining and microfabrication technology. These technologies are being used to develop point-contact sensors to measure gases which are important in emission control especially hydrogen, hydrocarbons, nitrogen oxides, and oxygen. The purpose of this paper is to discuss the development of this point-contact sensor technology. The detection of each type of gas involves its own challenges in the fields of materials science and fabrication technology. Of particular importance is sensor sensitivity, selectivity, and stability in long-term, high temperature operation. An overview is presented of each sensor type with an evaluation of its stage of development. It is concluded that this technology has significant potential for use in engine applications but further development is necessary.

  13. 废气涡轮增压器故障诊断浅谈%Fault Diagnosis of Exhaust Gas Turbochargers

    谷伟

    2014-01-01

    废气涡轮增压器被广泛应用于采油平台发电机组中。描述了废气涡轮增压器的构造、原理及作用,提出采用正确的使用和保养方法。针对影响增压器使用寿命因素加以诊断分析,并说明使用中的注意事项,意在减少增压器故障,延长其使用寿命,降低维护费用。%Exhaust gas turbochargers are widely applied in the generator sets of oil platforms. In the paper,the struc-ture,principle and functions of gas turbochargers were described and proper usage and maintenance methods were proposed. Moreover,factors affecting the service life of the turbochargers were diagnosed and analyzed and precau-tions were explained,aiming to reduce turbocharger failures,prolong their service life and reduce maintenance costs.

  14. A New Ductility Exhaustion Model for High Temperature Low Cycle Fatigue Life Prediction of Turbine Disk Alloys

    Zhu, Shun-Peng; Huang, Hong-Zhong; Li, Haiqing; Sun, Rui; Zuo, Ming J.

    2011-06-01

    Based on ductility exhaustion theory and the generalized energy-based damage parameter, a new viscosity-based life prediction model is introduced to account for the mean strain/stress effects in the low cycle fatigue regime. The loading waveform parameters and cyclic hardening effects are also incorporated within this model. It is assumed that damage accrues by means of viscous flow and ductility consumption is only related to plastic strain and creep strain under high temperature low cycle fatigue conditions. In the developed model, dynamic viscosity is used to describe the flow behavior. This model provides a better prediction of Superalloy GH4133's fatigue behavior when compared to Goswami's ductility model and the generalized damage parameter. Under non-zero mean strain conditions, moreover, the proposed model provides more accurate predictions of Superalloy GH4133's fatigue behavior than that with zero mean strains.

  15. Effects of Gas Temperature Fluctuation on the Soot Formation Reactions

    CHEN Ying; ZHANG Jian

    2013-01-01

    The effects of gas temperature fluctuations on soot formation and oxidation reactions are investigated numerically in a reacting flow.The instantaneous variations of soot mass fraction with time are obtained under the time-averaged gas temperature of 1500 1700 K.The simulation results show that the gas temperature fluctuation has obvious influence on the instantaneous processes of soot formation and oxidation.Within the present range of gas temperature,the gas temperature fluctuation results in generally lower soot mass fraction comparing to that without gas temperature fluctuation.The increase in the fluctuation amplitude of gas temperature leads to decrease in time-averaged soot mass fraction and increase in time-averaged soot particle number density.

  16. Gas Turbine Engine Having Fan Rotor Driven by Turbine Exhaust and with a Bypass

    Suciu, Gabriel L. (Inventor); Chandler, Jesse M. (Inventor)

    2016-01-01

    A gas turbine engine has a core engine incorporating a core engine turbine. A fan rotor is driven by a fan rotor turbine. The fan rotor turbine is in the path of gases downstream from the core engine turbine. A bypass door is moveable from a closed position at which the gases from the core engine turbine pass over the fan rotor turbine, and moveable to a bypass position at which the gases are directed away from the fan rotor turbine. An aircraft is also disclosed.

  17. Electrochemical high-temperature gas sensors

    Saruhan, B.; Stranzenbach, M.; Yüce, A.; Gönüllü, Y.

    2012-06-01

    Combustion produced common air pollutant, NOx associates with greenhouse effects. Its high temperature detection is essential for protection of nature. Component-integration capable high-temperature sensors enable the control of combustion products. The requirements are quantitative detection of total NOx and high selectivity at temperatures above 500°C. This study reports various approaches to detect NO and NO2 selectively under lean and humid conditions at temperatures from 300°C to 800°C. All tested electrochemical sensors were fabricated in planar design to enable componentintegration. We suggest first an impedance-metric gas sensor for total NOx-detection consisting of NiO- or NiCr2O4-SE and PYSZ-electrolyte. The electrolyte-layer is about 200μm thickness and constructed of quasi-single crystalline columns. The sensing-electrode (SE) is magnetron sputtered thin-layers of NiO or NiCr2O4. Sensor sensitivity for detection of total NOx has been measured by applying impedance analysis. The cross-sensitivity to other emission gases such as CO, CO2, CH4 and oxygen (5 vol.%) has been determined under 0-1000ppm NO. Sensor maintains its high sensitivity at temperatures up to 550°C and 600°C, depending on the sensing-electrode. NiO-SE yields better selectivity to NO in the presence of oxygen and have shorter response times comparing to NiCr2O4-SE. For higher temperature NO2-sensing capability, a resistive DC-sensor having Al-doped TiO2-sensing layers has been employed. Sensor-sensitivity towards NO2 and cross-sensitivity to CO has been determined in the presence of H2O at temperatures 600°C and 800°C. NO2 concentrations varying from 25 to 100ppm and CO concentrations from 25 to 75ppm can be detected. By nano-tubular structuring of TiO2, NO2 sensitivity of the sensor was increased.

  18. The Study of Automotive Exhaust Gas Turbine Power Generation Technology%汽车废气涡轮发电技术的研究

    张勇斌

    2015-01-01

    汽车废气涡轮发电是利用汽车尾气能量推动涡轮转动并带动发电机发电的一项技术。基于汽车节能的思想,以东风EQ6100型内燃机为例设计了汽车废气回收利用装置,并从内燃机进气流量入手配合实际循环状态和排气状况,对热量的回收效益和涡轮机功率进行了计算,并对涡轮机结构进行了初步设计,发电机进行了选型匹配。计算得出了汽车废气涡轮发电涡轮机的功率和排气能量大小,证实了利用汽车废气驱动涡轮发电的可行性。%Automotive exhaust gas turbine power generation is a technology to use the car exhaust energy to rotate and drive a turbine generator to generate electricity. Based on the idea of energy-saving cars, taking Dongfeng EQ6100-type internal combustion engine as an example, a vehicle exhaust recycling system was designed. Combining the engine intake air flow rate and the actual cycling situation as well as the exhaust situation, the heat recovery efficiency and turbine power were calculated, turbine structure was preliminarily designed, and the selection of matching generators was carried out. Calculation of the automobile exhaust turbine generator turbine power and exhaust energy confirmed the feasibility of the use of motor vehicle exhaust to drive a turbine to generate electricity.

  19. Experimental Investigation of a Temperature-Controlled Car Seat Powered by an Exhaust Thermoelectric Generator

    Du, H.; Wang, Y. P.; Yuan, X. H.; Deng, Y. D.; Su, C. Q.

    2016-03-01

    To improve the riding comfort and rational utilization of the electrical energy captured by an automotive thermoelectric generator (ATEG), a temperature-controlled car seat was constructed to adjust the temperature of the car seat surface. Powered by the ATEG and the battery, the seat-embedded air conditioner can improve the riding comfort using a thermoelectric device to adjust the surface temperature of the seat, with an air duct to regulate the cold side and hot side of the thermoelectric device. The performance of the thermoelectric cooler (TEC) and theoretical analysis on the optimum state of the TEC device are put forward. To verify the rationality of the air duct design and to ensure sufficient air supply, the velocity field of the air duct system was obtained by means of the finite element method. To validate the reliability of the numerical simulation, the air velocity around the thermoelectric device was measured by a wind speed transmitter. The performance of the temperature-controlled car seat has been validated and is in good agreement with bench tests and real vehicle tests.

  20. An Approach to the Prototyping of an Optimized Limited Stroke Actuator to Drive a Low Pressure Exhaust Gas Recirculation Valve.

    Gutfrind, Christophe; Dufour, Laurent; Liebart, Vincent; Vannier, Jean-Claude; Vidal, Pierre

    2016-01-01

    The purpose of this article is to describe the design of a limited stroke actuator and the corresponding prototype to drive a Low Pressure (LP) Exhaust Gas Recirculation (EGR) valve for use in Internal Combustion Engines (ICEs). The direct drive actuator topology is an axial flux machine with two air gaps in order to minimize the rotor inertia and a bipolar surface-mounted permanent magnet in order to respect an 80° angular stroke. Firstly, the actuator will be described and optimized under constraints of a 150 ms time response, a 0.363 N·m minimal torque on an angular range from 0° to 80° and prototyping constraints. Secondly, the finite element method (FEM) using the FLUX-3D(®) software (CEDRAT, Meylan, France) will be used to check the actuator performances with consideration of the nonlinear effect of the iron material. Thirdly, a prototype will be made and characterized to compare its measurement results with the analytical model and the FEM model results. With these electromechanical behavior measurements, a numerical model is created with Simulink(®) in order to simulate an EGR system with this direct drive actuator under all operating conditions. Last but not least, the energy consumption of this machine will be estimated to evaluate the efficiency of the proposed EGR electromechanical system. PMID:27213398

  1. Purex canyon exhaust fan bearing temperature monitoring system doric 245 datalogger programming

    A micro-processor based datalogger is used to monitor, display, and log seventeen RTD temperature channels. Five bearings are monitored for each of the three electric motor-fan assemblies and two bearings are monitored on the steam turbine unit. Several alarms per data channel (a High alarm at 236 degrees and a High High alarm at 246 degrees F) will alert the operation's staff to increasing abnormal bearing temperatures. This procedure is cross-referenced to the manufacturers manual. All programming steps will have the following footnote: Mpg x-xx. The Mpg refers to the Manual page, with x as the section number and xx as the page number in that section. When more information is needed, such as pictures or details, then the manual section and page number is provided

  2. Toward gas exhaustion in the W51 high-mass protoclusters

    Ginsburg, Adam; Goddi, Ciriaco; Galván-Madrid, Roberto; Dale, James E; Bally, John; Battersby, Cara D; Youngblood, Allison; Sankrit, Ravi; Smith, Rowan; Darling, Jeremy; Kruijssen, J M Diederik; Liu, Hauyu Baobab

    2016-01-01

    We present new JVLA observations of the high-mass cluster-forming region W51A from 2 to 16 GHz with resolution ${\\theta}_{fwhm} \\approx$ 0.3 - 0.5". The data reveal a wealth of observational results: (1) Currently-forming, very massive (proto-O) stars are traced by o-H2CO $2_{1,1}-2_{1,2}$ emission, suggesting that this line can be used efficiently as a massive protostar tracer. (2) There is a spatially distributed population of $\\sim$mJy continuum sources, including hypercompact H ii regions and candidate colliding wind binaries, in and around the W51 proto-clusters. (3) There are two clearly detected protoclusters, W51e and W51 IRS2, that are gas-rich but may have most of their mass in stars within their inner $\\sim$ 0.05 pc. The majority of the bolometric luminosity in W51 most likely comes from a third population of OB stars between these clusters. The presence of a substantial population of exposed O-stars coincident with a population of still-forming massive stars, along with a direct measurement of the...

  3. Gas formation. Formation temperatures of thermogenic and biogenic methane.

    Stolper, D A; Lawson, M; Davis, C L; Ferreira, A A; Santos Neto, E V; Ellis, G S; Lewan, M D; Martini, A M; Tang, Y; Schoell, M; Sessions, A L; Eiler, J M

    2014-06-27

    Methane is an important greenhouse gas and energy resource generated dominantly by methanogens at low temperatures and through the breakdown of organic molecules at high temperatures. However, methane-formation temperatures in nature are often poorly constrained. We measured formation temperatures of thermogenic and biogenic methane using a "clumped isotope" technique. Thermogenic gases yield formation temperatures between 157° and 221°C, within the nominal gas window, and biogenic gases yield formation temperatures consistent with their comparatively lower-temperature formational environments (<50°C). In systems where gases have migrated and other proxies for gas-generation temperature yield ambiguous results, methane clumped-isotope temperatures distinguish among and allow for independent tests of possible gas-formation models. PMID:24970083

  4. Ultra Efficient CHHP Using a High Temperature Fuel Cell to Provide On-Site Process Reducing Gas, Clean Power, and Heat

    Jahnke, Fred C. [Fuelcell Energy, Inc., Danbury, CT (United States)

    2015-06-30

    FuelCell Energy and ACuPowder investigated and demonstrated the use of waste anode exhaust gas from a high temperature fuel cell for replacing the reducing gas in a metal processing furnace. Currently companies purchase high pressure or liquefied gases for the reducing gas which requires substantial energy in production, compression/liquefaction, and transportation, all of which is eliminated by on-site use of anode exhaust gas as reducing gas. We performed research on the impact of the gas composition on product quality and then demonstrated at FuelCell Energy’s manufacturing facility in Torrington, Connecticut. This demonstration project continues to operate even though the research program is completed as it provides substantial benefits to the manufacturing facility by supplying power, heat, and hydrogen.

  5. Effect of nozzle hole size coupling with exhaust gas re-circulation on the engine emission perfomance based on KH-ACT spray model

    Zhang Liang; He Zhixia; Wang Qian; Guo Genmiao

    2015-01-01

    To research an effective measure of reducing the Soot and NOx in engine at the same time, different nozzle hole diameters coupled with exhaust gas recirculation (EGR) were adopted in this study based on KH-ACT spray breakup model, which takes the aerodynamic-induced ,cavitation-induced and turbulence-induced breakup into account. The SAGE detailed chemistry combustion and the new atomization model used in the simulation have been verified with the experimen...

  6. Modelling of an SCR catalytic converter for diesel exhaust after treatment: Dynamic effects at low temperature

    Tronconi, Enrico; Nova, Isabella; Ciardelli, Cristian [Dipartimento di Chimica, Materiali e Ingegneria Chimica ' G. Natta' , Politecnico di Milano, P.zza L. Da Vinci 32, 20133 Milano (Italy); Chatterjee, Daniel; Bandl-Konrad, Brigitte; Burkhardt, Thomas [DaimlerChrysler AG Abteilung RBP/C, HPC: 096-E220, D-70546 Stuttgart (Germany)

    2005-08-15

    As part of a fundamental and applied work on the development of an unsteady mathematical model of the NH{sub 3}-selective catalytic reduction (SCR) process for design and control of integrated after-treatment systems of heavy-duty engines, we present herein a transient kinetic analysis of the standard SCR NO+NH{sub 3} system which provides new insight in the catalytic kinetics and mechanism prevailing at low temperatures. Based on kinetic runs performed over a commercial powdered V{sub 2}O{sub 5}-WO{sub 3}-TiO{sub 2} catalyst in the 175-450{sup o}C T-range feeding NH{sub 3} and NO (1000ppm) in the presence of H{sub 2}O (1-10%, v/v) and O{sub 2} (2-6%, v/v), an original dual-site modified redox rate law is derived which effectively accounts for NH{sub 3} inhibition effects observed during transient reactive experiments at T<250{sup o}C. We also demonstrate that implementation of the novel modified redox kinetics into a fully predictive 1D+1D model of SCR monolith reactors can significantly improve simulations of SCR transient runs at different scales, including engine test bench experiments over full-scale SCR honeycomb catalysts.

  7. Development of high temperature metallic melting processes related to detritiation of exhausted control rods

    A rather critical problem to be faced in developing a safe strategy for the management of tritiated solid wastes is dealing with the outgassing property of tritium. Releases of tritium under elemental or oxide form may occur from waste items at different temperatures and rates depending upon the nature of tritium bonds into the waste matrix as well as on its 'contamination history'. Apart from the commercial value of tritium, its release from waste packages anyhow represents a risk of tritium exposure that cannot be accepted by skippers, by store and disposal site operators as well as by the general public. Consequently it is mandatory to carry out the detritiation of such wastes before their packaging and storage or disposal. In the boron carbide control rods from the Lingen BWR after about three years of operation, tritium generated by neutron reaction was essentially retained in the B4C matrix. The objectives of the study are to demonstrate the feasibility of two processes aimed at reducing to the maximum practicable extent the level of tritium contamination in such waste management are facilitated

  8. Neutral gas temperature measurements within transformer coupled toroidal argon plasmas

    Spatially resolved neutral gas temperature of Ar plasmas within a new type of transformer-coupled toroidal plasma source was measured by fitting unresolved rovibrational bands of trace gas N2 (C 3Πu→B 3Πg). With power density as high as 4.8 W/cm3, the maximum neutral gas temperature inside Ar plasmas was found to be 2000 K. The position with maximum neutral gas temperature was off the center of the cross section and close to the ferrite core, where higher electric field contributes to higher heating power. The dependence of neutral gas temperature on pressure was measured and can be empirically fitted by proportionality between gas temperature and logarithm of the pressure, as found by other researchers. A simple physical model gives the dependence of pressure as the sixth order of neutral gas temperature, which fits the experimental data as well. It was also found that added N2 gas perturbed Ar plasmas obviously, and therefore we recommend adding less than 1% N2 as trace gas. There is no dependence of fitted neutral gas temperature on the optical resolution of monochromator, as would be expected

  9. 废气涡轮增压器的优缺点分析%Analysis of the advantages and disadvantages for exhaust gas turbocharger

    富刚

    2013-01-01

    The exhaust gas turbocharger is a new technology for engine and a good solution for poor condition of nat-urally aspirated engine. Therefore, the exhaust gas turbocharger has been widely applied in a variety of models, particularly in sedan; Of course, the exhaust gas turbocharger also has its own drawbacks, so people use many effective ways to im-prove and compensate its shortcomings.%  废气涡轮增压器作为发动机的一项新技术,很好解决了自然吸气发动机动力性不佳的问题。因此,废气涡轮增压器在各种车型特别是轿车上得到了广泛的应用;当然,废气涡轮增压器也有其自身的缺点,因此针对其缺点人们采取了许多的有效的改善方法来弥补其缺陷。

  10. Hydrogen production from biomass pyrolysis gas via high temperature steam reforming process

    Full text: The aim of this work has been undertaken as part of the design of continuous hydrogen production using the high temperature steam reforming process. The steady-state test condition was carried out using syngas from biomass pyrolysis, whilst operating at high temperatures between 600 and 1200 degree Celsius. The main reformer operating parameters (e.g. temperature, resident time and steam to biomass ratio (S/B)) have been examined in order to optimize the performance of the reformer. The operating temperature is a key factor in determining the extent to which hydrogen production is increased at higher temperatures (900 -1200 degree Celsius) whilst maintaining the same as resident time and S/B ratio. The effects of exhaust gas composition on heating value were also investigated. The steam reforming process produced methane (CH4) and ethylene (C2H4) between 600 to 800 degree Celsius and enhanced production ethane (C2H6) at 700 degree Celsius. However carbon monoxide (CO) emission was slightly increased for higher temperatures all conditions. The results show that the use of biomass pyrolysis gas can produce higher hydrogen production from high temperature steam reforming. In addition the increasing reformer efficiency needs to be optimized for different operating conditions. (author)

  11. Determination of benzene in exhaust gas from biofuels. Final report; Bestimmung von Benzol im Abgas von Biokraftstoffen. Abschlussbericht

    Dutz, M.; Buenger, J.; Gnuschke, H.; Halboth, H.; Gruedl, P.; Krahl, J.

    2001-10-01

    With the advance of environmental legislation and practices oriented towards sustainability renewable energy resources are becoming increasingly important. Use of replenishable raw materials helps preserve fossil resources. In the fuel sector the most widely used replenishable materials are rape methyl ester (RME) and ethyl tertiary butyl ether (ETBE). The purpose of the present project on the ''Determination of benzene in exhaust gas from biofuels'' was to generate orienting data on the potential health relevance of mixtures of fossil and renewable fuel intended for use in spark ignition and diesel engines. This included a determination of benzene emissions and the mutagenicity of particles. Beyond the applied-for scope of research measurements were also performed on the test engine's toluene, ethyl benzene and xylene emissions as well as on the smoke spot number and nitrogen oxide (NO{sub x}) and hydrocarbon (HC) emissions of the diesel engine. [German] Regenerative Energien gewinnen durch die Umweltgesetzgebungen und das Streben nach einer nachhaltigen Entwicklung zunehmend an Bedeutung. Durch die Verwendung nachwachsender Rohstoffe koennen die fossilen Ressourcen geschont werden. Im Kraftstoffsektor sind hier hauptsaechlich Rapsoelmethylester (RME) und optional Ethyltertiaerbutylether (ETBE) zu nennen. Um fuer Diesel- und Ottomotoren insbesondere mit Blick auf Kraftstoffgemische aus fossilen und regenerativen Komponenten orientierende Daten ueber eine potenzielle Gesundheitsrelevanz zu generieren, wurde das Projekt 'Bestimmung von Benzol im Abgas von Biokraftstoffen' durchgefuehrt. Neben der Benzolemission wurde die Mutagenitaet der Partikeln ermittelt. Ueber den beantragten Untersuchungsrahmen hinaus wurden die Tuluol-, Ethylbenzol-, und Xylolemissionen der eingesetzten Motoren, sowie die Russzahl (RZ) und die Stickoxid- (NO{sub x}) und Kohlenwasserstoffemissionen (HC) des Dieselmotors bestimmt. (orig.)

  12. Tokamak fusion reactor exhaust

    This report presents a compilation of papers dealing with reactor exhaust which were produced as part of the TIGER Tokamak Installation for Generating Electricity study at Culham. The papers are entitled: (1) Exhaust impurity control and refuelling. (2) Consideration of the physical problems of a self-consistent exhaust and divertor system for a long burn Tokamak. (3) Possible bundle divertors for INTOR and TIGER. (4) Consideration of various magnetic divertor configurations for INTOR and TIGER. (5) A appraisal of divertor experiments. (6) Hybrid divertors on INTOR. (7) Refuelling and the scrape-off layer of INTOR. (8) Simple modelling of the scrape-off layer. (9) Power flow in the scrape-off layer. (10) A model of particle transport within the scrape-off plasma and divertor. (11) Controlled recirculation of exhaust gas from the divertor into the scrape-off plasma. (U.K.)

  13. Deactivation of Pd Catalysts by Water during Low Temperature Methane Oxidation Relevant to Natural Gas Vehicle Converters

    Rahman Gholami

    2015-03-01

    Full Text Available Effects of H2O on the activity and deactivation of Pd catalysts used for the oxidation of unburned CH4 present in the exhaust gas of natural-gas vehicles (NGVs are reviewed. CH4 oxidation in a catalytic converter is limited by low exhaust gas temperatures (500–550 °C and low concentrations of CH4 (400–1500 ppmv that must be reacted in the presence of large quantities of H2O (10–15% and CO2 (15%, under transient exhaust gas flows, temperatures, and compositions. Although Pd catalysts have the highest known activity for CH4 oxidation, water-induced sintering and reaction inhibition by H2O deactivate these catalysts. Recent studies have shown the reversible inhibition by H2O adsorption causes a significant drop in catalyst activity at lower reaction temperatures (below 450 °C, but its effect decreases (water adsorption becomes more reversible with increasing reaction temperature. Thus above 500 °C H2O inhibition is negligible, while Pd sintering and occlusion by support species become more important. H2O inhibition is postulated to occur by either formation of relatively stable Pd(OH2 and/or partial blocking by OH groups of the O exchange between the support and Pd active sites thereby suppressing catalytic activity. Evidence from FTIR and isotopic labeling favors the latter route. Pd catalyst design, including incorporation of a second noble metal (Rh or Pt and supports high O mobility (e.g., CeO2 are known to improve catalyst activity and stability. Kinetic studies of CH4 oxidation at conditions relevant to natural gas vehicles have quantified the thermodynamics and kinetics of competitive H2O adsorption and Pd(OH2 formation, but none have addressed effects of H2O on O mobility.

  14. The effect of ambient temperature and humidity on the carbon monoxide emissions of an idling gas turbine

    Kauffman, C. W.; Subramaniam, A. K.

    1977-01-01

    Changes in ambient temperature and humidity affect the exhaust emissions of a gas turbine engine. The results of a test program employing a JT8D combustor are presented which quantize the effect of these changes on carbon monoxide emissions at simulated idle operating conditions. Analytical results generated by a kinetic model of the combustion process and reflecting changing ambient conditions are given. It is shown that for a complete range of possible ambient variations, significant changes do occur in the amount of carbon monoxide emitted by a gas turbine engine.

  15. Experimental study on scale prevention method using exhausted gases from geothermal power station. Chinetsu hatsudensho no haishutsu gas wo mochiita scale fuchaku boshiho no kenkyu

    Hirowatari, K. (Kyushu Electric Power Co. Ltd., Fukuoka (Japan))

    1990-10-25

    This paper reports on a method of suppressing the scale deposition, which is considered to be promising in view of both economical efficiency of power generation and prevention of environmental pollution. A brief summary is first given of the well known fact that the silica scaling can be suppressed by keeping geothermal water in acidic conditions. There is next a description of an experiment, which was performed at the Hatchobaru geothermal power station, on the control of pH condition of geothermal water using a technique of bringing it in contact with exhaust gas discharged from the plant, which contains 70% of CO {sub 2} gas and about 2% of H {sub 2} S gas in volume. It is shown by this experiment that pH of the geothermal water was lowered to a value less than about 5.5 and thereby the rate of scale deposition could be reduced to about one twentieth of that observed in the case of original thermal water. Furthermore, it is noted that H {sub 2} S gas causes the deposition of much slime containing various kinds of metal elements on the filler of vessels used for pH adjustment of the geothermal water, but it can be efficiently removed from the exhaust gas by means of the pressure swing adsorption process. 8 refs., 15 figs., 4 tabs.

  16. In situ gas temperature measurements by UV-absorption spectroscopy

    Fateev, Alexander; Clausen, Sønnik

    2009-01-01

    range from 23 degrees C to 1,500 degrees C. The gas temperature was evaluated (1) from the analysis of the structure of selected NO high-resolution gamma-absorption bands and (2) from the analysis of vibrational distribution in the NO gamma-absorption system in the (211-238) nm spectral range. The......The absorption spectrum of the NO A(2)Sigma(+) <- X(2)Pi gamma-system can be used for in situ evaluation of gas temperature. Experiments were performed with a newly developed atmospheric-pressure high-temperature flow gas cell at highly uniform and stable gas temperatures over a 0.533 m path in the...... accuracy of both methods is discussed. Validation of the classical Lambert-Beer law has been demonstrated at NO concentrations up to 500 ppm and gas temperatures up to 1,500 degrees C over an optical absorption path length of 0.533 m....

  17. High-Speed Multiplexed Spatiotemporally Resolved Measurements of Exhaust Gas Recirculation Dynamics in a Multi-Cylinder Engine Using Laser Absorption Spectroscopy.

    Yoo, Jihyung; Prikhodko, Vitaly; Parks, James E; Perfetto, Anthony; Geckler, Sam; Partridge, William P

    2016-04-01

    The need for more environmentally friendly and efficient energy conversion is of paramount importance in developing and designing next-generation internal combustion (IC) engines for transportation applications. One effective solution to reducing emissions of mono-nitrogen oxides (NOx) is exhaust gas recirculation (EGR), which has been widely implemented in modern vehicles. However, cylinder-to-cylinder and cycle-to-cycle variations in the charge-gas uniformity can be a major barrier to optimum EGR implementation on multi-cylinder engines, and can limit performance, stability, and efficiency. Precise knowledge and fine control over the EGR system is therefore crucial, particularly for optimizing advanced engine concepts such as reactivity controlled compression ignition (RCCI). An absorption-based laser diagnostic was developed to study spatiotemporal charge-gas distributions in an IC engine intake manifold in real-time. The laser was tuned to an absorption band of carbon dioxide (CO2), a standard exhaust-gas marker, near 2.7 µm. The sensor was capable of probing four separate measurement locations simultaneously, and independently analyzing EGR fraction at speeds of 5 kHz (1.2 crank-angle degree (CAD) at 1 k RPM) or faster with high accuracy. The probes were used to study spatiotemporal EGR non-uniformities in the intake manifold and ultimately promote the development of more efficient and higher performance engines. PMID:27091946

  18. Photochemical transformation of aircraft exhausts at their transition from the plume to the large scale dispersion in the Northern temperature belt

    Karol, I.L.; Kiselev, A.A. [Main Geophysical Observatory, St.Petersburg (Russian Federation)

    1997-12-31

    The 2-D diurnally varying photochemical model of the Northern temperate zonal tropospheric belt with fixed (off line) temperature and air transport is used for the description of the formation of aircraft exhaust concentration distribution in the North Atlantic commercial flight corridor, based on actual flights in summer and winter. A strong diurnal and seasonal variation of emitted NO{sub x} oxidation rate is revealed and evaluated. (author) 11 refs.

  19. Black carbon from ships: a review of the effects of ship speed, fuel quality and exhaust gas scrubbing

    D. A. Lack

    2012-01-01

    Full Text Available The International Maritime Organization (IMO has moved to address the health and climate impact of the emissions from the combustion of low-quality residual fuels within the commercial shipping industry. Fuel sulfur content (FS limits and an efficiency design index for future ships are examples of such IMO actions. The impacts of black carbon (BC emissions from shipping are now under review by the IMO, with a particular focus on the potential impacts of future Arctic shipping.

    Recognizing that associating impacts with BC emissions requires both ambient and onboard observations, we provide recommendations for the measurement of BC. We also evaluate current insights regarding the effect of ship speed (engine load, fuel quality and exhaust gas scrubbing on BC emissions from ships. Observations demonstrate that BC emission factors (EFBC increases 3 to 6 times at very low engine loads (<25% compared to EFBC at 85–100% load; absolute BC emissions (per nautical mile of travel also increase up to 100% depending on engine load, even with reduced load fuel savings. If fleets were required to operate at lower maximum engine loads, presumably associated with reduced speeds, then engines could be re-tuned, which would reduce BC emissions.

    Ships operating in the Arctic are likely running at highly variable engine loads (25–100% depending on ice conditions and ice breaking requirements. The ships operating at low load may be emitting up to 50% more BC than they would at their rated load. Such variable load conditions make it difficult to assess the likely emissions rate of BC.

    Current fuel sulfur regulations have the effect of reducing EFBC by an average of 30% and potentially up to 80% regardless of engine load; a removal rate similar to that of scrubbers.

    Uncertainties among current observations demonstrate there is a need for more information on (a the impact of fuel

  20. Black carbon from ships: a review of the effects of ship speed, fuel quality and exhaust gas scrubbing

    D. A. Lack

    2012-05-01

    Full Text Available The International Maritime Organization (IMO has moved to address the health and climate impact of the emissions from the combustion of low-quality residual fuels within the commercial shipping industry. Fuel sulfur content (FS limits and an efficiency design index for future ships are examples of such IMO actions. The impacts of black carbon (BC emissions from shipping are now under review by the IMO, with a particular focus on the potential impacts of future Arctic shipping.

    Recognizing that associating impacts with BC emissions requires both ambient and onboard observations, we provide recommendations for the measurement of BC. We also evaluate current insights regarding the effect of ship speed (engine load, fuel quality and exhaust gas scrubbing on BC emissions from ships. Observations demonstrate that BC emission factors (EFBC increases 3 to 6 times at very low engine loads (<25% compared to EFBC at 85–100% load; absolute BC emissions (per nautical mile of travel also increase up to 100% depending on engine load, even with reduced load fuel savings. If fleets were required to operate at lower maximum engine loads, presumably associated with reduced speeds, then engines could be re-tuned, which would reduce BC emissions.

    Ships operating in the Arctic are likely running at highly variable engine loads (25–100% depending on ice conditions and ice breaking requirements. The ships operating at low load may be emitting up to 50% more BC than they would at their rated load. Such variable load conditions make it difficult to assess the likely emissions rate of BC.

    Current fuel sulfur regulations have the effect of reducing EFBC by an average of 30% and potentially up to 80% regardless of engine load; a removal rate similar to that of scrubbers.

    Uncertainties among current observations demonstrate there is a need for more information on a the impact of fuel quality

  1. Novel silica membranes for high temperature gas separations

    Bighane, Neha

    2011-04-01

    This article describes fabrication of novel silica membranes derived via controlled oxidative thermolysis of polydimethylsiloxane and their gas separation performance. The optimized protocol for fabrication of the silica membranes is described and pure gas separation performance in the temperature range 35-80°C is presented. It is observed that the membranes exhibit activated transport for small gas penetrants such as He, H 2 and CO 2. The membranes can withstand temperatures up to 350°C in air and may ultimately find use in H 2/CO 2 separations to improve efficiency in the water-gas shift reactor process. © 2011 Elsevier B.V.

  2. Temperature detection in a gas turbine

    Lacy, Benjamin; Kraemer, Gilbert; Stevenson, Christian

    2012-12-18

    A temperature detector includes a first metal and a second metal different from the first metal. The first metal includes a plurality of wires and the second metal includes a wire. The plurality of wires of the first metal are connected to the wire of the second metal in parallel junctions. Another temperature detector includes a plurality of resistance temperature detectors. The plurality of resistance temperature detectors are connected at a plurality of junctions. A method of detecting a temperature change of a component of a turbine includes providing a temperature detector include ing a first metal and a second metal different from the first metal connected to each other at a plurality of junctions in contact with the component; and detecting any voltage change at any junction.

  3. Swirl and blade wakes in the interaction between gas turbines and exhaust diffusers investigated by endoscopic particle image velocimetry

    Opilat, Victor

    2011-10-21

    Exhaust diffusers studied in this thesis are installed behind the last turbine stage of gas turbines, including those used in combined cycle power plants. Extensive research made in recent years proved that effects caused by an upstream turbine need to be taken into account when designing efficient diffusers. Under certain conditions these effects can stabilize the boundary layer in diffusers and prevent separation. In this research the impact of multiple parameters, such as tip leakage flow, swirl, and rotating blade wakes, on the performance of a diffuser is studied. Experiments were conducted using a diffuser test rig with a rotating bladed wheel as a turbine effect generator and with an additional tip leakage flow insert. The major advantages of this test rig are modularity and easy variation of the main parameters. To capture the complexity and understand the physics of diffuser flow, and to clarify the phenomenon of the flow stabilisation, the 2D endoscopic laser optical measurement technique Partide Image Velocimetry (PIV) was adopted to the closed ''rotating'' diffuser test rig. Intensity and distribution of vortices in the blade tip area are decisive for diffuser performance. Large vortices in the annular diffuser inlet behind the blade tips interact with the boundary layer in diffusers. At design point these vortices are very early suppressed by the main flow. For the operating point with a low value of the flow coefficient (negative swirl), vortices are ab out two tim es stronger than for design point and the boundary layer is destabilized. V mtices develop in the direction contrary to swirl in the main flow and just cause flow destabilization. Coherent back flow zones are induced and reduction of diffuser performance occurs. For the operating point with positive swirl (for a high flow coefficient value), these vortices are also strong but do not counteract the main flow because they develop in the same direction with the swirl in the

  4. Temperature effect on gas phase alkylbenzene dealkylation

    Dealkylation of ethylbenzene, propylbenzene, and isopropylbenzene by radiolytically formed 2H3+ ions has been studied in the gaseous phase as a function of the irradiation temperature. The extent of the reaction, which increases with the temperature follows the order ethylbenzene -1 between the activation energies for dealkylation of ethylbenzene and isopropylbenzene, and of ethylbenzene and propylbenzene, respectively. (author)

  5. Investigation and evaluation of potential exhaust braking strategiesusing model predictive control

    Hallqvist, Erik

    2015-01-01

    The eciency of today's aftertreatment system relies on the exhaust gas temperature.The Selective Catalytic Reduction system, which is a part of theaftertreatment system has an operating temperature window which starts atapproximately 200C in order to work as eciently as possible. Rolling downhillwithout burning fuel could cause the exhaust aftertreatment system to cooldown below this window, which gives higher emissions when burning fuel again.This thesis focuses on investigating the potentia...

  6. Reflection error correction of gas turbine blade temperature

    Kipngetich, Ketui Daniel; Feng, Chi; Gao, Shan

    2016-03-01

    Accurate measurement of gas turbine blades' temperature is one of the greatest challenges encountered in gas turbine temperature measurements. Within an enclosed gas turbine environment with surfaces of varying temperature and low emissivities, a new challenge is introduced into the use of radiation thermometers due to the problem of reflection error. A method for correcting this error has been proposed and demonstrated in this work through computer simulation and experiment. The method assumed that emissivities of all surfaces exchanging thermal radiation are known. Simulations were carried out considering targets with low and high emissivities of 0.3 and 0.8 respectively while experimental measurements were carried out on blades with emissivity of 0.76. Simulated results showed possibility of achieving error less than 1% while experimental result corrected the error to 1.1%. It was thus concluded that the method is appropriate for correcting reflection error commonly encountered in temperature measurement of gas turbine blades.

  7. Seismic stability of VGM type high temperature gas cooled reactors

    The main principles of the design provision of high temperature gas cooled VGM reactors seismic stability and the results of calculations, performed by linear-spectral method are presented. (author). 1 ref., 10 figs

  8. Isolating Gas Sensor From Pressure And Temperature Effects

    Sprinkle, Danny R.; Chen, Tony T. D.; Chaturvedi, Sushi K.

    1994-01-01

    Two-stage flow system enables oxygen sensor in system to measure oxygen content of low-pressure, possibly-high-temperature atmosphere in test environment while protecting sensor against possibly high temperature and fluctuations in pressure of atmosphere. Sensor for which flow system designed is zirconium oxide oxygen sensor sampling atmospheres in high-temperature wind tunnels. Also adapted to other gas-analysis instruments that must be isolated from pressure and temperature effects of test environments.

  9. Biomass Gasification and High Temperature Gas Cleaning

    Hejdová, Petra; Solich, M.; Vosecký, Martin; Malecha, J.; Koutský, B.; Punčochář, Miroslav; Skoblia, Sergej

    -: -, 2005, s. 221-224. ISBN 80-8073-382-1. [New Trends in Technology Systems Operation'05. Prešov (SK), 20.11.2005-21.11.2005] R&D Projects: GA ČR(CZ) GA104/04/0829 Institutional research plan: CEZ:AV0Z40720504 Keywords : biomass and waste * gasification * hot gas cleaning Subject RIV: CI - Industrial Chemistry, Chemical Engineering

  10. The Influence of Mixing in High Temperature Gas Phase Reactions

    Østberg, Martin

    1996-01-01

    of the mixing in the SNR process using injection of NH3 with carrier gas into the flue gas in crossflow by a quartz nozzle.Experiments were made with variation in NH3 flow, carrier gas flow, carrier gas composition (O2 concentration) and reactor temperature. Natural gas has been used as an addition...... concentrations in the injected gas between 0 - 20 vol%.Using a nozzle with a diameter of 1.9 mm the reduction of NO is dependent on the carrier gas flow for temperatures above 1200 K (1100 K when natural gas is added).It is shown that this effect can not be described by macromixing using a simple reactor model...... between the injected jet and the flue gas in crossflow both for the 1.0 mm and 1.9 mm nozzle, indicating that for momentum ratios above 30 there is no further improvement of the mixing. For decreasing momentum ratios below 30 the NO outlet concentration is increasing for temperatures above 1200 K...

  11. Development history of the gas turbine modular high temperature reactor

    The development of the high temperature gas cooled reactor (HTGR) as an environmentally agreeable and efficient power source to support the generation of electricity and achieve a broad range of high temperature industrial applications has been an evolutionary process spanning over four decades. This process has included ongoing major development in both the HTGR as a nuclear energy source and associated power conversion systems from the steam cycle to the gas turbine. This paper follows the development process progressively through individual plant designs from early research of the 1950s to the present focus on the gas turbine modular HTGR. (author)

  12. GC/MS Gas Separator Operates At Lower Temperatures

    Sinha, Mahadeva P.; Gutnikov, George

    1991-01-01

    Experiments show palladium/silver tube used to separate hydrogen carrier gas from gases being analyzed in gas-chromatography/mass-spectrometry (GC/MS) system functions satisfactorily at temperatures as low as 70 to 100 degrees C. Less power consumed, and catalytic hydrogenation of compounds being analyzed diminished. Because separation efficiency high even at lower temperatures, gas load on vacuum pump of mass spectrometer kept low, permitting use of smaller pump. These features facilitate development of relatively small, lightweight, portable GC/MS system for such uses as measuring concentrations of pollutants in field.

  13. Effect of Exhaust Gas Recirculation on the Dual Fuel Combustion of Gasoline and CNG by Compression Ignition

    A. Rashid A. Aziz; Raja Shahzad; Noraz Al-Khairi; P. Naveenchandran

    2011-01-01

    Homogeneous Charge Compression Ignition (HCCI) is a combustion process that promises the combination of diesel like efficiencies and very low NOx emissions. The major issues with HCCI are high heat release rates, lack of combustion control and high CO and HC emissions. Operating HCCI with two fuels of different properties and recirculation of exhaust gases are effective strategies of promoting and controlling autoignition. This study discusses the effects of EGR on the combustion characterist...

  14. Measured gas and particle temperatures in VTT's entrained flow reactor

    Clausen, Sønnik; Sørensen, L.H.

    2006-01-01

    Particle and gas temperature measurements were carried out in experiments on VTTs entrained flow reactor with 5% and 10% oxygen using Fourier transform infrared emission spectroscopy (FTIR). Particle temperature measurements were performed on polish coal,bark, wood, straw particles, and bark and...

  15. Control rod drive for high temperature gas cooled reactor

    DengJun-Xian; XuJi-Ming; 等

    1998-01-01

    This control rod drive is developed for HTR-10 high temperature gas cooled test reactor.The stepmotor is prefered to improve positioning of the control rod and the scram behavior.The preliminary test in 1600170 ambient temperature shows that the selected stepmotor and transmission system can meet the main operation function requirements of HTR-10.

  16. Simultaneous conversion of nitrogen oxides and soot into nitrogen and carbon dioxide over iron containing oxide catalysts in diesel exhaust gas

    This paper deals with the simultaneous catalytic conversion of NOx and soot into N2 and CO2 in diesel exhaust gas. Several iron containing oxide catalysts were partially modified by the alkali metal potassium and were used for NOx-soot reaction in a model exhaust gas. Fe1.9K0.1O3 has shown highest catalytic performance for N2 formation in the so far investigated catalysts. Further studies have shown that Fe1.9K0.1O3 was deactivated in a substantial way after about 20 TPR experiments due to the agglomeration of the promoter potassium. Experiments carried out over the aged Fe1.9K0.1O3 catalyst have shown that NOx-soot reaction was suppressed at higher O2 concentration, since O2-soot conversion was kinetically favored. In contrast to that, the catalytic activity was increased in presence of NO2 and H2O. Mechanistic examinations suggest that (CO) intermediates, formed at the soot surface, are the reactive sites in the NOx-soot reaction. Higher catalytic performance in presence of NO2 could be explained by the enhanced formation of these (CO) species. Moreover, nitrate species formed at the catalyst surface might also play an important role in NOx-soot conversion

  17. Effects of Gas Velocity and Temperature on Nitric Oxide Conversion in Simulated Catalytic Converter

    Sathaporn Chuepeng

    2012-01-01

    Problem statement: Gaseous emissions from gasoline engine such as carbon monoxide, unburned hydrocarbon and nitrogen oxides were usually reduced in three-way catalytic converter simultaneously around theoretical fuel and air combustion. Engine speed and load and other parameters were varied over a wide range of operating conditions, resulting in different exhaust gas composition and condition intake into catalytic converter. This work was studied the conversion of Nitric Oxide (NO) in exhaust...

  18. Effect of cooling the recirculated exhaust gases on diesel engine emissions

    Although combustion is essential in most energy generation processes, it is one of the major causes of air pollution. Spiral fin exhaust pipes were designed to study the effect of cooling the recirculated exhaust gases (EGR) of Diesel engines on the chemical composition of the exhaust gases and the reduction in the percentages of pollutant emissions. The gases examined in this study were oxides of nitrogen (NOx), carbon dioxide (CO2) and carbon monoxide (CO). In addition, O2 concentration in the exhaust was measured. The two designs adopted in this study were exhaust pipes with solid and hollow fins around them. The first type uses air flow around the fins to cool the exhaust gases. The second type consists of hollow fins around the exhaust pipe to allow cooling water to flow in the hollow passage. Different combinations and arrangements of the solid and hollow fins exhaust pipes were used. It was found that decreasing the temperature of the EGR resulted in reductions in the oxides of nitrogen (NOx) and carbon dioxide (CO2) but increased the carbon monoxide (CO) in the exhaust gases. In addition, the oxygen (O2) concentration in the exhaust was decreased. As a general trend, the percentages of reduction in the NOx gas concentrations were lower than the percentages of increase in the CO emissions as a result of cooling the EGR of a Diesel engine by a heat exchanger. Using water as a cooling medium decreased the exhaust gases temperature and the amount of pollutants more than did air as a cooling medium. In a separate series of tests, increasing the cooled EGR ratios decreased the exhaust NOx but increased the particulate matter concentrations in the exhaust gases

  19. Modern gas-based temperature and pressure measurements

    Pavese, Franco

    2013-01-01

    This 2nd edition volume of Modern Gas-Based Temperature and Pressure Measurements follows the first publication in 1992. It collects a much larger set of information, reference data, and bibliography in temperature and pressure metrology of gaseous substances, including the physical-chemical issues related to gaseous substances. The book provides solutions to practical applications where gases are used in different thermodynamic conditions. Modern Gas-Based Temperature and Pressure Measurements, 2nd edition is the only comprehensive survey of methods for pressure measurement in gaseous media used in the medium-to-low pressure range closely connected with thermometry. It assembles current information on thermometry and manometry that involve the use of gaseous substances which are likely to be valid methods for the future. As such, it is an important resource for the researcher. This edition is updated through the very latest scientific and technical developments of gas-based temperature and pressure measurem...

  20. Study on Temperature Modulation Techniques for Micro Gas Sensors

    Guangfen Wei; Zhenan Tang; Hongquan Zhang; Yanbing Xue; Jun Yu

    2006-01-01

    The sensitivity and selectivity of gas sensors are related with not only sensing material, but also their operating temperatures. Applying this property, temperature modulation technique has been proposed to improve the selectivity of gas sensors. With a newly developed alumina based micro gas sensor, the sensitivity to CO and CH4 at different operating temperatures was investigated. By modulating the temperature of the sensor at pulse and sine wave modes with different frequencies and amplitudes, the dynamic responses of the sensor were measured and processed. Results show that the modulating waveshape plays an important role in the improvement of selectivity, while the influence of frequency is small at the suitable sampling frequency in the range of 25 mHz~200 mHz.

  1. Thermoelectric generators incorporating phase-change materials for waste heat recovery from engine exhaust

    Meisner, Gregory P; Yang, Jihui

    2014-02-11

    Thermoelectric devices, intended for placement in the exhaust of a hydrocarbon fuelled combustion device and particularly suited for use in the exhaust gas stream of an internal combustion engine propelling a vehicle, are described. Exhaust gas passing through the device is in thermal communication with one side of a thermoelectric module while the other side of the thermoelectric module is in thermal communication with a lower temperature environment. The heat extracted from the exhaust gasses is converted to electrical energy by the thermoelectric module. The performance of the generator is enhanced by thermally coupling the hot and cold junctions of the thermoelectric modules to phase-change materials which transform at a temperature compatible with the preferred operating temperatures of the thermoelectric modules. In a second embodiment, a plurality of thermoelectric modules, each with a preferred operating temperature and each with a uniquely-matched phase-change material may be used to compensate for the progressive lowering of the exhaust gas temperature as it traverses the length of the exhaust pipe.

  2. Design and development of gas turbine high temperature reactor 300

    JAERI (Japan Atomic Energy Research Institute) has been designing a Japan's original gas turbine high temperature reactor, GTHTR300 (Gas Turbine High Temperature Reactor 300). The greatly simplified design based on salient features of the HTGR (High Temperature Gas-cooled reactor) with a closed helium gas turbine enables the GTHTR300 a high efficient and economically competitive reactor to be deployed in early 2010s. Also, the GTHTR300 fully taking advantage of various experiences accumulated in design, construction and operation of the HTTR (High Temperature Engineering Test Reactor) and fossil gas turbine systems reduces technological development concerning a reactor system and electric generation system. Original features of this system are core design with two-year refueling interval, conventional steel material usage for a reactor pressure vessel, innovative plant flow scheme and horizontally installed gas turbine unit. Due to these salient features, the capital cost of the GTHTR300 is less than a target cost of 200 thousands Yen/kWe, and the electric generation cost is close to a target cost of 4 Yen/kWh. This paper describes the original design features focusing on reactor core design, fuel design, in-core structure design and reactor pressure vessel design except PCU design. Also, R and D for developing the power conversion unit is briefly described. The present study is entrusted from the Ministry of Education, Culture, Sports, Science and Technology of Japan. (author)

  3. Determination of gas temperature in the plasmatron channel according to the known distribution of electronic temperature

    Gerasimov Alexander V.

    2013-01-01

    Full Text Available An analytical method to calculate the temperature distribution of heavy particles in the channel of the plasma torch on the known distribution of the electronic temperature has been proposed. The results can be useful for a number of model calculations in determining the most effective conditions of gas blowing through the plasma torch with the purpose of heating the heavy component. This approach allows us to understand full details about the heating of cold gas, inpouring the plasma, and to estimate correctly the distribution of the gas temperature inside the channel.

  4. The exhausted horse syndrome.

    Foreman, J H

    1998-04-01

    Exhaustion occurs in most equestrian sports, but it is more frequent in events that require sustained endurance work such as endurance racing, three-day eventing, trial riding, and hunting. Exhaustion is also more likely when an unfit, unacclimatized, or unsound horse is exercised. Mechanisms that contribute to exhaustion include heat retention, fluid and electrolyte loss, acid-base imbalance, and intramuscular glycogen depletion. Clinical signs include elevated temperature, pulse, and respiratory rate; depression; anorexia; unwillingness to continue to exercise; dehydration; weakness; stiffness; hypovolemic shock; exertional myopathy; synchronous diaphragmatic flutter; atrial fibrillation; diarrhea; colic; and laminitis. Treatment includes stopping exercise; rapid cooling; rapid large volume intravenous or oral fluid administration; and nonsteroidal anti-inflammatory drug administration. PMID:9561696

  5. Laser mass spectrometry for high sensitive and multi-com- ponent analysis of exhaust gas from vehicles

    2001-01-01

    Laser mass spectrometry is a newly developed method for pollutantdetection. It combines resonance-en- hanced multiphoton ionization (REMPI) and time-of-flight mass spectro- metry (TOF-MS). It may detect pollutants with high sensitivity, high selectivity and in a multi-com- ponent way. In this note, laser mass spectrometry was used to detect the pollutants in exhaust gases from vehicles. With one-color REMPI (at 266 nm), several aromatic hydrocarbons, including benzene, toluene, xylene, C3-benzene, etc., were detected. These substances were selectively ionized by (1+1) REMPI and their mass resolution was detected by a TOF mass spectrometer. And a quantitative analysis was achieved.

  6. A laser-based sensor for measurement of off-gas composition and temperature in basic oxygen steelmaking

    We are developing an optical sensor for process control in basic oxygen steelmaking. The sensor measures gas temperature and relative CO/CO2 concentration ratios in the furnace off-gas by transmitting the laser probe beam directly above the furnace lip and below the exhaust hood during oxygen blowing. Dynamic off-gas information is being evaluated for optimizing variables such as lance height, oxygen flow, post-combustion control, and prediction of final melt-carbon content. The non-invasive nature of the optical sensor renders it robust and relatively maintenance-free. Additional potential applications of the method are process control for electric arc furnace and bottom-blown oxygen steelmaking processes. (author)

  7. Multi-spectral temperature measurement method for gas turbine blade

    Gao, Shan; Feng, Chi; Wang, Lixin; Li, Dong

    2016-02-01

    One of the basic methods to improve both the thermal efficiency and power output of a gas turbine is to increase the firing temperature. However, gas turbine blades are easily damaged in harsh high-temperature and high-pressure environments. Therefore, ensuring that the blade temperature remains within the design limits is very important. There are unsolved problems in blade temperature measurement, relating to the emissivity of the blade surface, influences of the combustion gases, and reflections of radiant energy from the surroundings. In this study, the emissivity of blade surfaces has been measured, with errors reduced by a fitting method, influences of the combustion gases have been calculated for different operational conditions, and a reflection model has been built. An iterative computing method is proposed for calculating blade temperatures, and the experimental results show that this method has high precision.

  8. High temperature gas dynamics an introduction for physicists and engineers

    Bose, Tarit K

    2014-01-01

    High Temperature Gas Dynamics is a primer for scientists, engineers, and students who would like to have a basic understanding of the physics and the behavior of high-temperature gases. It is a valuable tool for astrophysicists as well. The first chapters treat the basic principles of quantum and statistical mechanics and how to derive thermophysical properties from them. Special topics are included that are rarely found in other textbooks, such as the thermophysical and transport properties of multi-temperature gases and a novel method to compute radiative transfer. Furthermore, collision processes between different particles are discussed. Separate chapters deal with the production of high-temperature gases and with electrical emission in plasmas, as well as related diagnostic techniques.This new edition adds over 100 pages and includes the following updates: several sections on radiative properties of high temperature gases and various radiation models, a section on shocks in magneto-gas-dynamics, a sectio...

  9. Gravitational collapse of a magnetized fermion gas with finite temperature

    We examine the dynamics of a self-gravitating magnetized fermion gas at finite temperature near the collapsing singularity of a Bianchi-I spacetime. Considering a general set of appropriate and physically motivated initial conditions, we transform Einstein-Maxwell field equations into a complete and self-consistent dynamical system amenable for numerical work. The resulting numerical solutions reveal the gas collapsing into both, isotropic (''point-like'') and anisotropic (''cigar-like''), singularities, depending on the initial intensity of the magnetic field. We provide a thorough study of the near collapse behavior and interplay of all relevant state and kinematic variables: temperature, expansion scalar, shear scalar, magnetic field, magnetization, and energy density. A significant qualitative difference in the behavior of the gas emerges in the temperature range T/mf ∝ 10-6 and T/mf ∝ 10-3. (orig.)

  10. Gravitational collapse of a magnetized fermion gas with finite temperature

    Gaspar, I Delgado; Sussman, Roberto A; Rey, A Ulacia

    2013-01-01

    We examine the dynamics of a self--gravitating magnetized electron gas at finite temperature near the collapsing singularity of a Bianchi-I spacetime. Considering a general and appropriate and physically motivated initial conditions, we transform Einstein--Maxwell field equations into a complete and self--consistent dynamical system amenable for numerical work. The resulting numerical solutions reveal the gas collapsing into both, isotropic ("point-like") and anisotropic ("cigar-like") singularities, depending on the initial intensity of the magnetic field. We provide a thorough study of the near collapse behavior and interplay of all relevant state and kinematic variables: temperature, expansion scalar, shear scalar, magnetic field, magnetization and energy density. A significant qualitative difference in the behavior of the gas emerges in the temperature range $\\hbox{T} sim10^{4}\\hbox{K}$ and $\\hbox{T}\\sim 10^{7}\\hbox{K}$.

  11. Estimated times to exhaustion and power outputs at the gas exchange threshold, physical working capacity at the rating of perceived exertion threshold, and respiratory compensation point.

    Bergstrom, Haley C; Housh, Terry J; Zuniga, Jorge M; Camic, Clayton L; Traylor, Daniel A; Schmidt, Richard J; Johnson, Glen O

    2012-10-01

    The purposes of this study were to compare the power outputs and estimated times to exhaustion (T(lim)) at the gas exchange threshold (GET), physical working capacity at the rating of perceived exertion threshold (PWC(RPE)), and respiratory compensation point (RCP). Three male and 5 female subjects (mean ± SD: age, 22.4 ± 2.8 years) performed an incremental test to exhaustion on an electronically braked cycle ergometer to determine peak oxygen consumption rate, GET, and RCP. The PWC(RPE) was determined from ratings of perceived exertion data recorded during 3 continuous workbouts to exhaustion. The estimated T(lim) values for each subject at GET, PWC(RPE), and RCP were determined from power curve analyses (T(lim) = ax(b)). The results indicated that the PWC(RPE) (176 ± 55 W) was not significantly different from RCP (181 ± 54 W); however, GET (155 ± 42 W) was significantly less than PWC(RPE) and RCP. The estimated T(lim) for the GET (26.1 ± 9.8 min) was significantly greater than PWC(RPE) (14.6 ± 5.6 min) and RCP (11.2 ± 3.1 min). The PWC(RPE) occurred at a mean power output that was 13.5% greater than the GET and, therefore, it is likely that the perception of effort is not driven by the same mechanism that underlies the GET (i.e., lactate buffering). Furthermore, the PWC(RPE) and RCP were not significantly different and, therefore, these thresholds may be associated with the same mechanisms of fatigue, such as increased levels of interstitial and (or) arterial [K⁺]. PMID:22716291

  12. High-temperature oxidation of graphite rods with temperature control by combustion gas recycle

    The combustion of graphite (fuel blocks) is of fundamental importance in the fuel reprocessing scheme for the High-Temperature Gas-Cooled Reactor (HTGR). A study was made to evaluate a chunk-type burner for possible application in this reprocessing step. The combustion gases were recycled to allow operation at higher burn rates without an increase in graphite temperature. Graphite rods of two diameters were oxidized with makeup oxygen and recycled stack gases at various gas flow rates in an insulated reactor. Results of this study indicate a strong dependence of oxygen transfer on gas flow rate with little effect resulting from changes in graphite temperature. High carbon monoxide concentrations in the exit gas were not a problem except at oxygen concentrations below approx. 5%. Stable operation of a recycle controlled burner was achieved, avoiding the temperature excursions common in previous graphite burners

  13. Gas temperature effects in micrometre-scale dielectric barrier discharges

    Sitaraman, H; Raja, L L, E-mail: lraja@mail.utexas.edu [Department of Aerospace Engineering and Engineering Mechanics, University of Texas at Austin, TX 78712 (United States)

    2011-07-06

    A numerical modelling study of micrometre-length-scale (gap distances of {approx}50-100 {mu}m) dielectric barrier discharges (micro-DBDs) is reported. A comparison of micro-DBDs with classical large-scale DBDs (gap distances of {approx} mm) reveals the principal effect of downscaling DBD gap dimensions on the gas heating in these discharges. A one-dimensional, self-consistent, multi-species, multi-temperature continuum model is used in the simulations. For a constant pd (pressure x discharge gap distance) and applied voltage waveform (500 V, 10 MHz), a larger cycle-averaged gas temperature rise is seen in the micro-DBDs {approx}hundreds of kelvin compared with much smaller rise {approx}tens of kelvin in the classic DBDs. The gas temperature increase in micro-DBDs is mainly due to the rapid increase in the power densities as the gap dimensions are decreased compared with the increase in the wall loss with decreasing gap distances. For conditions studied in this work, the power densities in micro-DBDs are about four orders of magnitude larger than classic DBDs. Operation at higher frequencies, with other conditions remaining constant, is observed to favour larger gas temperatures in micro-DBDs. Micro-DBDs are therefore excellent device candidates to provide controllable gas heating in a variety of micro-electro mechanical systems; small spacecraft electrothermal micropropulsion devices being an example.

  14. Gas temperature effects in micrometre-scale dielectric barrier discharges

    A numerical modelling study of micrometre-length-scale (gap distances of ∼50-100 μm) dielectric barrier discharges (micro-DBDs) is reported. A comparison of micro-DBDs with classical large-scale DBDs (gap distances of ∼ mm) reveals the principal effect of downscaling DBD gap dimensions on the gas heating in these discharges. A one-dimensional, self-consistent, multi-species, multi-temperature continuum model is used in the simulations. For a constant pd (pressure x discharge gap distance) and applied voltage waveform (500 V, 10 MHz), a larger cycle-averaged gas temperature rise is seen in the micro-DBDs ∼hundreds of kelvin compared with much smaller rise ∼tens of kelvin in the classic DBDs. The gas temperature increase in micro-DBDs is mainly due to the rapid increase in the power densities as the gap dimensions are decreased compared with the increase in the wall loss with decreasing gap distances. For conditions studied in this work, the power densities in micro-DBDs are about four orders of magnitude larger than classic DBDs. Operation at higher frequencies, with other conditions remaining constant, is observed to favour larger gas temperatures in micro-DBDs. Micro-DBDs are therefore excellent device candidates to provide controllable gas heating in a variety of micro-electro mechanical systems; small spacecraft electrothermal micropropulsion devices being an example.

  15. Effect of cooled EGR on performance and exhaust gas emissions in EFI spark ignition engine fueled by gasoline and wet methanol blends

    Rohadi, Heru; Syaiful, Bae, Myung-Whan

    2016-06-01

    Fuel needs, especially the transport sector is still dominated by fossil fuels which are non-renewable. However, oil reserves are very limited. Furthermore, the hazardous components produced by internal combustion engine forces many researchers to consider with alternative fuel which is environmental friendly and renewable sources. Therefore, this study intends to investigate the impact of cooled EGR on the performance and exhaust gas emissions in the gasoline engine fueled by gasoline and wet methanol blends. The percentage of wet methanol blended with gasoline is in the range of 5 to 15% in a volume base. The experiment was performed at the variation of engine speeds from 2500 to 4000 rpm with 500 intervals. The re-circulated exhaust gasses into combustion chamber was 5%. The experiment was performed at the constant engine speed. The results show that the use of cooled EGR with wet methanol of 10% increases the brake torque up to 21.3%. The brake thermal efficiency increases approximately 39.6% using cooled EGR in the case of the engine fueled by 15% wet methanol. Brake specific fuel consumption for the engine using EGR fueled by 10% wet methanol decreases up to 23% at the engine speed of 2500 rpm. The reduction of CO, O2 and HC emissions was found, while CO2 increases.

  16. Exhaust gas emissions and environmental effects by use of rape seed oil based fuels in agricultural tractors; Schadstoffemissionen und Umweltwirkungen bei Verwendung von Rapsoelkraftstoffen in der Landwirtschaft

    Krahl, J.; Vellguth, G.; Munack, A.; Stalder, K.; Bahadir, M.

    1996-01-01

    The use of biofuels can only be supported, if their effects on environment and human health are well known. So the exhaust gases of seven different Diesel engines fueled with rape seed oil or RME were analyzed and compared to those from Diesel fuel (DF). As motor test procedure the 5-mode cycle was chosen, which simulates the typical load of agricultural tractors. Besides the determination of the regulated and nonregulated exhaust gas compounds, some engines were examined with regard to the cytotoxic and mutagenic potentials of their particulates as well. The result of all investigations shows that RME has definite advantages when it is used in rural areas. (orig.) [Deutsch] Oekologische Aspekte, die Endlichkeit fossiler Ressourcen und das Bestreben, die landwirtschaftlichen Strukturen zu erhalten, motivieren die Verwendung nachwachsender Rohstoffe. In der Bundesforschungsanstalt fuer Landwirtschaft (FAL) wird seit den 70er Jahren die technische Nutzung von Rapsoel als Alternativkraftstoff untersucht. Schon sehr frueh zeigte sich, dass reines Rapsoel nicht langfristig in konventionellen Dieselmotoren einsetzbar ist, da schwere Motorschaeden die Folge sind. Um Rapsoel dennoch als Kraftstoff nutzen zu koennen, muss entweder der Motor oder der Kraftstoff veraendert werden. Durch motorische Sonderkonstruktionen auf der einen oder die Umesterung des Rapsoels - meist zu Rapsoelmethylester (RME) - auf der anderen Seite gelingt es, Rapsoel als fluessigen Energietraeger zu verwenden. Mit RME, der in seinen physikalischen Eigenschaften dem Dieselkraftstoff (DK) sehr aehnelt, wird seit 1982 in der Versuchsstation der FAL ein Traktor erfolgreich betrieben, Bild 1. Analog dazu muessen auch modifizierte Motoren ihre Tauglichkeit im Langzeitversuch unter Beweis stellen. (orig.)

  17. A comparative study of the elemental composition of the exhaust emissions of cars powered by liquefied petroleum gas and unleaded petrol

    Lim, McKenzie C. H.; Ayoko, Godwin A.; Morawska, Lidia; Ristovski, Zoran D.; Jayaratne, E. Rohan; Kokot, Serge

    Elements emitted from the exhausts of new Ford Falcon Forte cars powered by unleaded petrol (ULP) and liquefied petroleum gas (LPG) were measured on a chassis dynamometer. The measurements were carried out in February, June and August 2001, and at two steady state driving conditions (60 and 80 km h -1). Thirty seven elements were quantified in the exhaust samples by inductively coupled plasma mass spectrometry (ICPMS). The total emission factors of the elements from the exhausts of ULP cars were higher than those of LPG cars at both engine speeds even though high variability in the exhaust emissions from different cars was noted. The effect of the operating conditions such as mileage of the cars, engine speed, fuel and lubricating oil compositions on the emissions was studied. To investigate the effects of these conditions, multivariate data analysis methods were employed including exploratory principal component analysis (PCA), and the multi-criteria decision making methods (MCDM), preference ranking organization method for enrichment evaluation (PROMETHEE) and geometrical analysis for interactive aid (GAIA), for ranking the cars on the basis of the emission factors of the elements. PCA biplot of the complete data matrix showed a clear discrimination of the February, June and August emission test results. In addition, (i) platinum group elements (PGE) emissions were separated from each other in the three different clusters viz. Pt with February, Pd with June and Rh with August; (ii) the motor oil related elements, Zn and P, were particularly associated with the June and August tests (these vectors were also grouped with V, Al and Cu); and (iii) highest emissions of most major elements were associated with the August test after the cars have recorded their highest mileage. Extensive analysis with the aid of the MCDM ranking methods demonstrated clearly that cars powered by LPG outperform those powered by ULP. In general, cars tested in June perform better than

  18. Utilisation of CO2, fixation of nitrogen and exhaust gas cleaning in electric discharge with electrode catalysis

    The method reported here provides a contribution to CO2 utilisation, nitrogen fixation and combustion exhaust cleaning using synergetic effect of electric discharge with heterogeneous catalysis on electrodes. The efficiency of CO2 removal is about 40-65%. The process of CO2 removal is always accompanied by NOx, VOC, SX and other component removal and is connected with O2 formation. The final product of process is powder with fractal microstructure, low specific weight, water insoluble suitable for use as nitrogen containing fertilizer. The main component (95%) of solid product is amorphous condensate of amino acids with about 5% of metal organic compound with catalytic properties. The condensate has character of statistical proteinoid. Its creation seems to play important role during formation of life in pre-biotic Earth

  19. Recovery of Exhaust Waste Heat for ICE Using the Beta Type Stirling Engine

    Wail Aladayleh; Ali Alahmer

    2015-01-01

    This paper investigates the potential of utilizing the exhaust waste heat using an integrated mechanical device with internal combustion engine for the automobiles to increase the fuel economy, the useful power, and the environment safety. One of the ways of utilizing waste heat is to use a Stirling engine. A Stirling engine requires only an external heat source as wasted heat for its operation. Because the exhaust gas temperature may reach 200 to 700°C, Stirling engine will work effectively....

  20. 46 CFR 119.430 - Engine exhaust pipe installation.

    2010-10-01

    ... 46 Shipping 4 2010-10-01 2010-10-01 false Engine exhaust pipe installation. 119.430 Section 119... INSTALLATION Specific Machinery Requirements § 119.430 Engine exhaust pipe installation. (a) The design of all... an exhaust pipe. (b) Exhaust gas must not leak from the piping or any connections. The piping must...

  1. NOx abatement in the exhaust of lean-burn natural gas engines over Ag-supported γ-Al2O3 catalysts

    Azizi, Y.; Kambolis, A.; Boréave, A.; Giroir-Fendler, A.; Retailleau-Mevel, L.; Guiot, B.; Marchand, O.; Walter, M.; Desse, M.-L.; Marchin, L.; Vernoux, P.

    2016-04-01

    A series of Ag catalysts supported on γ-Al2O3, including two different γ-Al2O3 supports and various Ag loadings (2-8 wt.%), was prepared, characterized (SEM, TEM, BET, physisorption, TPR, NH3-TPD) and tested for the selective catalytic reduction of NOx by CH4 for lean-burn natural gas engines exhausts. The catalysts containing 2 wt.% Ag supported on γ-Al2O3 were found to be most efficient for the NOx reduction into N2 with a maximal conversion of 23% at 650 °C. This activity was clearly linked with the ability of the catalyst to concomitantly produce CO, via the methane steam reforming, and NO2. The presence of small AgOx nanoparticles seems to be crucial for the methane activation and NOx reduction.

  2. Temperatures of dust and gas in S~140

    Koumpia, E; Ossenkopf, V; van der Tak, F F S; Mookerjea, B; Fuente, A; Kramer, C

    2015-01-01

    In dense parts of interstellar clouds (> 10^5 cm^-3), dust & gas are expected to be in thermal equilibrium, being coupled via collisions. However, previous studies have shown that the temperatures of the dust & gas may remain decoupled even at higher densities. We study in detail the temperatures of dust & gas in the photon-dominated region S 140, especially around the deeply embedded infrared sources IRS 1-3 and at the ionization front. We derive the dust temperature and column density by combining Herschel PACS continuum observations with SOFIA observations at 37 $\\mu$m and SCUBA at 450 $\\mu$m. We model these observations using greybody fits and the DUSTY radiative transfer code. For the gas part we use RADEX to model the CO 1-0, CO 2-1, 13CO 1-0 and C18O 1-0 emission lines mapped with the IRAM-30m over a 4' field. Around IRS 1-3, we use HIFI observations of single-points and cuts in CO 9-8, 13CO 10-9 and C18O 9-8 to constrain the amount of warm gas, using the best fitting dust model derived wit...

  3. Pengaruh Variasi Temperatur Sintesa, Temperatur Operasi dan Konsentrasi gas CO terhadap sensitivitas Sensor Gas Co dari Material ZnO

    Endah Lutfiana

    2014-03-01

    Full Text Available Karbon monoksida ( CO merupakan gas yang tidak berwarna dan tidak berbau yang dihasilkan dari proses pembakaran yang tidak sempurna. Gas ini sangat beracun bagi tubuh manusia karena sifat biologinya yang mampu berikatan dengan hemoglobin yang mana bertugas membawa oksigen dalam darah, sehingga kadar oksigen dapat menurun drastis dan menyebabkan keracunan bahkan kematian. Sehingga dibutuhkan suatu alat pendeteksi atau sensor untuk mendeteksi adanya gas tersebut.Oksida metal seringkali digunakan untuk material sensor. ZnO merupakan suatu material semikonduktor yang telah digunakan untuk aplikasi sensor. Dalam penelitian ini pembuatan sensor ZnO dilakukan dengan mengoksidasi serbuk Zn pada variasi temperatur 800, 850, 900 oC selama 40 menit. Selanjutnya dibuat pelet sensor dengan mengkompaksi serbuk ZnO hasil Oksidasi dengan tekanan 200 Bar. Pelet kemudian disinter dengan temperatur 500oC. Setelah itu dilakukan pengujian SEM, XRD, dan uji Sensitivitas dengan variasi temperatur operasi 30, 50, 100 oC dan variasi konsentrasi 10 ppm, 50 ppm, 100 ppm, 250 ppm, 500 ppm. Dari hasil pengujian didapatkan nilai sensitivitas tertinggi pada temperatur sintesa 800oC dengan konsentrasi gas CO 500 ppm pada temperatur operasi sensor 100oC yaitu sebesar 0,52.

  4. Quantification of benzene, toluene, ethylbenzene and o-xylene in internal combustion engine exhaust with time-weighted average solid phase microextraction and gas chromatography mass spectrometry.

    Baimatova, Nassiba; Koziel, Jacek A; Kenessov, Bulat

    2015-05-11

    A new and simple method for benzene, toluene, ethylbenzene and o-xylene (BTEX) quantification in vehicle exhaust was developed based on diffusion-controlled extraction onto a retracted solid-phase microextraction (SPME) fiber coating. The rationale was to develop a method based on existing and proven SPME technology that is feasible for field adaptation in developing countries. Passive sampling with SPME fiber retracted into the needle extracted nearly two orders of magnitude less mass (n) compared with exposed fiber (outside of needle) and sampling was in a time weighted-averaging (TWA) mode. Both the sampling time (t) and fiber retraction depth (Z) were adjusted to quantify a wider range of Cgas. Extraction and quantification is conducted in a non-equilibrium mode. Effects of Cgas, t, Z and T were tested. In addition, contribution of n extracted by metallic surfaces of needle assembly without SPME coating was studied. Effects of sample storage time on n loss was studied. Retracted TWA-SPME extractions followed the theoretical model. Extracted n of BTEX was proportional to Cgas, t, Dg, T and inversely proportional to Z. Method detection limits were 1.8, 2.7, 2.1 and 5.2 mg m(-3) (0.51, 0.83, 0.66 and 1.62 ppm) for BTEX, respectively. The contribution of extraction onto metallic surfaces was reproducible and influenced by Cgas and t and less so by T and by the Z. The new method was applied to measure BTEX in the exhaust gas of a Ford Crown Victoria 1995 and compared with a whole gas and direct injection method. PMID:25911428

  5. Microstructural Characterization of Low Temperature Gas Nitrided Martensitic Stainless Steel

    Fernandes, Frederico Augusto Pires; Christiansen, Thomas Lundin; Somers, Marcel A. J.

    The present work presents microstructural investigations of the surface zone of low temperature gas nitrided precipitation hardening martensitic stainless steel AISI 630. Grazing incidence X-ray diffraction was applied to investigate the present phases after successive removal of very thin sections...

  6. Reactor core design of Gas Turbine High Temperature Reactor 300

    Japan Atomic Energy Research Institute (JAERI) has been designing Japan's original gas turbine high temperature reactor, Gas Turbine High Temperature Reactor 300 (GTHTR300). The greatly simplified design based on salient features of the High Temperature Gas-cooled Reactor (HTGR) with a closed helium gas turbine enables the GTHTR300 a highly efficient and economically competitive reactor to be deployed in early 2010s. Also, the GTHTR300 fully taking advantage of various experiences accumulated in design, construction and operation of the High Temperature Engineering Test Reactor (HTTR) and existing fossil fired gas turbine systems reduces technological development concerning a reactor system and electric generation system. Original design features of this system are the reactor core design based on a newly proposed refueling scheme named sandwich shuffling, conventional steel material usage for a reactor pressure vessel (RPV), an innovative coolant flow scheme and a horizontally installed gas turbine unit. The GTHTR300 can be continuously operated without the refueling for 2 years. Due to these salient features, the capital cost of the GTHTR300 is less than a target cost of 200,000 yen (1667 US$)/kW e, and the electric generation cost is close to a target cost of 4 yen (3.3 US cents)/kW h. This paper describes the original design features focusing on the reactor core design and the in-core structure design, including the innovative coolant flow scheme for cooling the RPV. The present study is entrusted from the Ministry of Education, Culture, Sports, Science and Technology of Japan

  7. Role of average speed in N₂O exhaust emissions as greenhouse gas in a huge urban zone (MVMZ): would we need a cold sun?

    Castillo, S; Mac-Beath, I; Mejia, I; Camposeco, R; Bazan, G; Morán-Pineda, M; Carrera, R; Gómez, R

    2012-05-15

    Nowadays, the drastic pollution problems, some of them related with greenhouse gas emissions, have promoted important attempts to face and diminish the global warming effects on the Mexico Valley Metropolitan Zone (MVMZ) as well as on the huge urban zones around the world. To reduce the exhaust gas emissions, many efforts have been carried out to reformulate fuels and design new catalytic converters; however, it is well known that other variables such as socio-economic and transport structure factors also play an important role around this problem. The present study analyzes the roles played by several commonly-used three-way catalytic converters (TWC) and the average traffic speed in the emission of N(2)O as greenhouse gas. According to this study, by increasing the average traffic flow and avoiding constant decelerations (frequent stops) during common trips, remarkable environmental and economic benefits could be obtained due to the diminution of N(2)O and other contaminant emissions such as ammonia (NH(3)) and even CO(2) with the concomitant reduced fossil fuel consumption. The actions mentioned above could be highly viable to diminish, in general, the global warming effects and contamination problems. PMID:22245865

  8. Low temperature catalytic combustion of natural gas - hydrogen - air mixtures

    Newson, E.; Roth, F. von; Hottinger, P.; Truong, T.B. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1999-08-01

    The low temperature catalytic combustion of natural gas - air mixtures would allow the development of no-NO{sub x} burners for heating and power applications. Using commercially available catalysts, the room temperature ignition of methane-propane-air mixtures has been shown in laboratory reactors with combustion efficiencies over 95% and maximum temperatures less than 700{sup o}C. After a 500 hour stability test, severe deactivation of both methane and propane oxidation functions was observed. In cooperation with industrial partners, scaleup to 3 kW is being investigated together with startup dynamics and catalyst stability. (author) 3 figs., 3 refs.

  9. 汽车燃料和排放物的快速气相色谱分析%HIGH-SPEED GAS CHROMATOGRAPHY ANALYSIS OF AUTOMOTIVE FUELS AND EXHAUST SPECIES

    AKIYAMAK

    2003-01-01

    The chemical analysis of organic compounds in the automotive fuels and exhaust species is an extremely important and complex procedure. For these compounds analysis, gas chromatography is the most widely method used because of its excellent selectivity, and wide dynamic concentration range. Although, analysis time of automotive fuels and exhausts are very long because these are complex mixtures, and target compounds in these samples are very low concentration. Concentrations of some species for example 13-butadiene are change after collection. Long analysis turnaround time make cost increase. The high-speed gas chromatography analysis techniques of automotive fuels and exhaust species are developed, because to decrease turnaround of analysis time is very important for cutback the cost of experiments and ensure of reliability.

  10. Simulation of fission gas release during temperature transients

    Paper discusses the release of fission gases Xe and Kr as a diffusion process. It takes into account gas generation due to fission, gas precipitation in bubbles within the grains, diffusion of gas towards the grain boundaries, formation of grain boundary bubbles, its saturation and subsequent gas release, resolution of the gas contained into both types of bubbles and grain growth. Temperature profile calculations have allowed to evaluate the gas distribution in fuel pellet and in each grain. Analytical and numerical methods are used. Several experiments are simulated with the code and a good agreement between the measured Paper discusses the release of fission gases Xe and Kr as a diffusion process. It takes into and calculated results has been obtained. The influence of the initial grain size and density on fission gas release has been evaluated. It has been found that larger grain size and lower density both yield lower release, but density variation has a minor effect on the release. (author). 10 refs, 4 figs

  11. Temperatures of dust and gas in S 140

    Koumpia, E.; Harvey, P. M.; Ossenkopf, V.; van der Tak, F. F. S.; Mookerjea, B.; Fuente, A.; Kramer, C.

    2015-08-01

    Context. In dense parts of interstellar clouds (≥105 cm-3), dust and gas are expected to be in thermal equilibrium, being coupled via collisions. However, previous studies have shown that in the presence of intense radiation fields, the temperatures of the dust and gas may remain decoupled even at higher densities. Aims: The objective of this work is to study in detail the temperatures of dust and gas in the photon-dominated region S 140, especially around the deeply embedded infrared sources IRS 1-3 and at the ionization front. Methods: We derive the dust temperature and column density by combining Herschel-PACS continuum observations with SOFIA observations at 37 μm and SCUBA data at 450 μm. We model these observations using simple greybody fits and the DUSTY radiative transfer code. For the gas analysis we use RADEX to model the CO 1-0, CO 2-1, 13CO 1-0 and C18O 1-0 emission lines mapped with the IRAM-30 m telescope over a 4' field. Around IRS 1-3, we use HIFI observations of single-points and cuts in CO 9-8, 13CO 10-9 and C18O 9-8 to constrain the amount of warm gas, using the best fitting dust model derived with DUSTY as input to the non-local radiative transfer model RATRAN. The velocity information in the lines allows us to separate the quiescent component from outflows when deriving the gas temperature and column density. Results: We find that the gas temperature around the infrared sources varies between ~35 and ~55 K. In contrast to expectation, the gas is systematically warmer than the dust by ~5-15 K despite the high gas density. In addition we observe an increase of the gas temperature from 30-35 K in the surrounding up to 40-45 K towards the ionization front, most likely due to the UV radiation from the external star. Furthermore, detailed models of the temperature structure close to IRS 1 which take the known density gradient into account show that the gas is warmer and/or denser than what we model. Finally, modelling of the dust emission from

  12. Numerical simulation of wall temperature on gas pipeline due to radiation of natural gas during combustion

    Ilić Marko N.

    2012-01-01

    Full Text Available This paper presents one of the possible hazardous situations during transportation of gas through the international pipeline. It describes the case when at high-pressure gas pipeline, due to mechanical or chemical effect, cracks and a gas leakage appears and the gas is somehow triggered to burn. As a consequence of heat impingement on the pipe surface, change of material properties (decreasing of strength at high temperatures will occur. In order to avoid greater rapture a reasonable pressure relief rate needs to be applied. Standards in this particular domain of depressurizing procedure are not so exact (DIN EN ISO 23251; API 521. This paper was a part of the project to make initial contribution in defining the appropriate procedure of gas operator behaving during the rare gas leakage and burning situations on pipeline network. The main part of the work consists of two calculations. The first is the numerical simulation of heat radiation of combustible gas, which affects the pipeline, done in the FLUENT software. The second is the implementation of obtained results as a boundary condition in an additional calculation of time resolved wall temperature of the pipe under consideration this temperature depending on the incident flux as well as a number of other heat flow rates, using the Matlab. Simulations were done with the help of the “E.ON Ruhrgas AG” in Essen.

  13. Denuder for measuring emissions of gaseous organic exhaust gas constituents; Denuder zur Emissionsmessung von gasfoermigen organischen Abgasinhaltsstoffen

    Gerchel, B.; Jockel, W.; Kallinger, G.; Niessner, R.

    1997-05-01

    Industrial plants which emit carcinogenic or other noxious substances should be given top priority in any policy to ward off harmful environmental effects. This also applies to many volatile and semi-volatile air constituents such as volatile aliphatic carbonyls or amines. To date there are no satisfactory methods for determining trace organic components of exhaust gases. It is true that aldehydes are considered in the VDI Guideline 3862, but the measuring methods given there are based on absorption in liquids and are accordingly difficult to use and show a high cross-sensitivity for other substances. No VDI Guideline exists to date on amine emissions. In view of the complexity of exhaust gases a selective enrichment of certain families of substances would appear indicated. Sampling trouble could be reduced if it was possible only to accumulate the gaseous phase, or even just one family of gaseous constituents. A particularly suitable air sampling method is that of diffusion separation. These diffusion separators (denuders) are well known as a powerful measuring system which is able to accumulate trace pollutants in the outside air. The purpose of the present study was to find out whether the concept of diffusion separation is also applicable to emission monitoring, and in particular whether it is suitable for detecting volatile aliphatic aldehydes and amines (primary and secondary) at extremely low concentrations (<10 ppb). (orig./SR) [Deutsch] Fuer Anlagen mit Emissionen von krebserzeugenden und gesundheitsgefaehrdenden Stoffen ergibt sich ein besonderer Handlungsbedarf zum Schutz vor schaedlichen Umwelteinwirkungen. Zu diesen Stoffen gehoeren auch viele leicht- und mittelfluechtigen Luftinhaltsstoffe, wie z.B. die leichtfluechtigen aliphatischen Carbonyle oder Amine. Fuer organische Komponenten, die nur in geringen Konzentrationen im Abgas vorkommen, existieren bisher keine zufriedenstellenden Messverfahren. Fuer die Aldehyde liegt zwar die VDI-Richtlinie 3862

  14. Exhaust gas emissions from diesel-engines driven by rape seed oil methyl ester, rape seed oil and diesel fuel - an evaluation of laboratory and vehicle fleet test results

    Kern, C.; Widmann, B. [Technische Univ. Muenchen (Germany)

    1999-11-01

    Diesel fuels from rape seed oil can contribute to a reduction of CO{sub 2}-emissions and save mineral fuel resources. But at the same time other emission components, which have an environmental or health impact, must be compared with the exhaust gas emissions from presently used mineral diesel fuels. This study compares various results from vehicle emission tests, concentrating on personnel vehicles and rape seed oil methyl ester (RME), to show a tendency if there is a similar, lower or even higher output of critical exhaust gas components. The results vary in a wide range: for motors with a generally high emission level there is a tendency for lower emissions with RME, but for motors with a sophisticated technology (e.g. injection technique and exhaust gas cleaning) the differences between the fuels become more and more insignificant, so that general statements about advantages cannot be made. The influence of modern motor and exhaust gas cleaning technology seems more important here than the fuel properties. Even through the differences between the fuels in emission components are not significant in general it can be stated that the advantages concerning the reduction of CO{sub 2}-emission and biodegradability remain. (orig.)

  15. Exhaust gas emissions from diesel-engines driven by rape seed oil methyl ester, rape seed oil and diesel fuel - an evaluation of laboratory and vehicle fleet test results

    Kern, C.; Widmann, B. (Technische Univ. Muenchen (Germany))

    1999-01-01

    Diesel fuels from rape seed oil can contribute to a reduction of CO[sub 2]-emissions and save mineral fuel resources. But at the same time other emission components, which have an environmental or health impact, must be compared with the exhaust gas emissions from presently used mineral diesel fuels. This study compares various results from vehicle emission tests, concentrating on personnel vehicles and rape seed oil methyl ester (RME), to show a tendency if there is a similar, lower or even higher output of critical exhaust gas components. The results vary in a wide range: for motors with a generally high emission level there is a tendency for lower emissions with RME, but for motors with a sophisticated technology (e.g. injection technique and exhaust gas cleaning) the differences between the fuels become more and more insignificant, so that general statements about advantages cannot be made. The influence of modern motor and exhaust gas cleaning technology seems more important here than the fuel properties. Even through the differences between the fuels in emission components are not significant in general it can be stated that the advantages concerning the reduction of CO[sub 2]-emission and biodegradability remain. (orig.)

  16. Nanostructured Materials for Room-Temperature Gas Sensors.

    Zhang, Jun; Liu, Xianghong; Neri, Giovanni; Pinna, Nicola

    2016-02-01

    Sensor technology has an important effect on many aspects in our society, and has gained much progress, propelled by the development of nanoscience and nanotechnology. Current research efforts are directed toward developing high-performance gas sensors with low operating temperature at low fabrication costs. A gas sensor working at room temperature is very appealing as it provides very low power consumption and does not require a heater for high-temperature operation, and hence simplifies the fabrication of sensor devices and reduces the operating cost. Nanostructured materials are at the core of the development of any room-temperature sensing platform. The most important advances with regard to fundamental research, sensing mechanisms, and application of nanostructured materials for room-temperature conductometric sensor devices are reviewed here. Particular emphasis is given to the relation between the nanostructure and sensor properties in an attempt to address structure-property correlations. Finally, some future research perspectives and new challenges that the field of room-temperature sensors will have to address are also discussed. PMID:26662346

  17. Optimized Feature Extraction for Temperature-Modulated Gas Sensors

    Alexander Vergara

    2009-01-01

    Full Text Available One of the most serious limitations to the practical utilization of solid-state gas sensors is the drift of their signal. Even if drift is rooted in the chemical and physical processes occurring in the sensor, improved signal processing is generally considered as a methodology to increase sensors stability. Several studies evidenced the augmented stability of time variable signals elicited by the modulation of either the gas concentration or the operating temperature. Furthermore, when time-variable signals are used, the extraction of features can be accomplished in shorter time with respect to the time necessary to calculate the usual features defined in steady-state conditions. In this paper, we discuss the stability properties of distinct dynamic features using an array of metal oxide semiconductors gas sensors whose working temperature is modulated with optimized multisinusoidal signals. Experiments were aimed at measuring the dispersion of sensors features in repeated sequences of a limited number of experimental conditions. Results evidenced that the features extracted during the temperature modulation reduce the multidimensional data dispersion among repeated measurements. In particular, the Energy Signal Vector provided an almost constant classification rate along the time with respect to the temperature modulation.

  18. 40 CFR 86.109-94 - Exhaust gas sampling system; Otto-cycle vehicles not requiring particulate emission measurements.

    2010-07-01

    ... be limited to ±10 °F (±5.6 °C) during the entire test. The temperature measuring system shall have an... substantiates the need for this closer tolerance.) (2) The temperature measuring system shall have an accuracy... change (as measured in hot silicone oil). (3) The pressure measuring system shall have an accuracy...

  19. Technical assessment of gas turbine cycle for high temperature gas-cooled reactor

    The gas turbine cycle appears to be the best near-term power conversion method for the high temperature gas-cooled reactor (HTGR). The author extensively investigates the gas turbine cycle including direct cycle, open indirect cycle and closed indirect cycle with medium of helium, nitrogen and air. Each cycle is analyzed and optimized from the thermodynamic standpoint and its turbo-machine is aerodynamically designed. As a result, the direct cycle with helium is an ideal option for the HTGR gas turbine cycle; however it is not easy to be realized based on current technology. The closed indirect cycle with helium or nitrogen is a practical one at present time, which can get the gas turbine cycle and lay technical bases for the future direct cycle

  20. 论多晶硅生产废气回收的必要性%On the Necessity for Recycling of Exhaust Gas in Polysilicon Production

    陆大军

    2011-01-01

    介绍了某企业多晶硅生产过程中废气的来源和组成,对废气回收的必要性进行了论述。%In a 3,000 t/a polysilicon project with modified Siemens process,the low-boiling-point compositions which are produced in production systems are not recycled for some design and production reasons.As a result,the severe exceeding standard of low-boiling-point compositions in the production systems makes the systems always excess pressure,which makes it is not easy for the safety operation for the system.Besides,the recycling systems do not classify the discharge,then the off gas scrubber system do not work properly and the treatment cost is increased.This makes a lot of material waste and increases the production cost.In order to save production costs and reduce the treatment costs,it is urgent to recycle the exhaust gas.

  1. Generating usable and safe CO{sub 2} for enrichment of greenhouses from the exhaust gas of a biomass heating system

    Dion, L.M.; Lefsrud, M. [McGill Univ., Macdonald Campus, Ste-Anne-deBellevue, PQ (Canada). Dept. of Bioresource Engineering

    2010-07-01

    This study demonstrated the use of biomass as a renewable fuel to enrich a greenhouse with carbon dioxide (CO{sub 2}). CO{sub 2} enrichment of greenhouses has been shown to improve crop production whether it occurs from liquid CO{sub 2} or combustion of fossil fuels. Biomass, in the form of wood chips or pellets, has received much interest as a sustainable and economically viable alternative to heat greenhouses. As such, the opportunity exists to convert exhaust gases from a greenhouse wood heating system into a useful resource. CO{sub 2} can be extracted from flue gas via membrane separation instead of electrostatic precipitators. This technique has shown potential for large industries trying to reduce and isolate CO{sub 2} emissions for sequestration and may be applicable to the greenhouse industry. Some research has also been done with wet scrubbers using catalysts to obtain plant fertilizers. Sulphur dioxide (SO{sub 2}) and nitrogen (NO) emissions can be stripped from flue gas to form ammonium sulphate as a valuable byproduct for fertilizer markets. This study will review the potential of these techniques in the summer of 2010 when experiments will be conducted at the Macdonald Campus of McGill University.

  2. High temperature gas cleaning for pressurized gasification. Final report

    Alden, H.; Hagstroem, P.; Hallgren, A.; Waldheim, L. [TPS Termiska Processer AB, Nykoeping (Sweden)

    2000-04-01

    The purpose of the project was to build an apparatus to study pressurized, high temperature gas cleaning of raw gasification gas generated from biomass. A flexible and easy to operate pressurized apparatus was designed and installed for the investigations in high temperature gas cleaning by means of thermal, catalytic or chemical procedures. A semi continuos fuel feeding concept, at a maximum rate of 700 g/h, allowed a very constant formation of a gas product at 700 deg C. The gas product was subsequently introduced into a fixed bed secondary reactor where the actual gas cleanup or reformation was fulfilled. The installation work was divided into four work periods and apart from a few delays the work was carried out according to the time plan. During the first work period (January - June 1994) the technical design, drawings etc. of the reactor and additional parts were completed. All material for the construction was ordered and the installation work was started. The second work period (July - December 1994) was dedicated to the construction and the installation of the different components. Initial tests with the electrical heating elements, control system and gas supply were assigned to the third work period (January - June 1995). After the commissioning and the resulting modifications, initial pyrolysis and tar decomposition experiments were performed. During the fourth and final work period, (June - December 1995) encouraging results from first tests allowed the experimental part of the project work to commence, however in a slightly reduced program. The experimental part of the project work comparatively studied tar decomposition as a function of the process conditions as well as of the choice of catalyst. Two different catalysts, dolomite and a commercial Ni-based catalyst, were evaluated in the unit. Their tar cracking ability in the pressure interval 1 - 20 bar and at cracker bed temperatures between 800 - 900 deg C was compared. Long term tests to study

  3. Lithographically fabricated silicon microreactor for operando QEXAFS studies in exhaust gas catalysis during simulation of a standard driving cycle

    Doronkin, D. E.; Baier, S.; Sheppard, T.; Benzi, F.; Grunwaldt, J.-D.

    2016-05-01

    Selective catalytic reduction of NOx by ammonia over Cu-ZSM-5 was monitored by operando QEXAFS during simulation of the New European Driving Cycle. The required fast temperature transients were realized using a novel silicon microreactor, enabling simultaneous spectroscopic and kinetic analysis by X-ray absorption spectroscopy (XAS) and mass spectrometry (MS). Periods of high temperature were correlated to an increase in both N2 production and change of coordination of Cu sites. This operando approach using Si microreactors can be applied to other heterogeneous catalytic systems involving fast temperature transients.

  4. Gas diffusion and temperature dependence of bubble nucleation during irradiation

    Foreman, A. J. E.; Singh, Bachu Narain

    The continuous production of gases at relatively high rates under fusion irradiation conditions may enhance the nucleation of cavities. This can cause dimensional changes and could induce embrittlement arising from gas accumulation on grain boundaries. Computer calculations have been made of the...... diatomic nucleation of helium bubbles, assuming helium to diffuse substitutionally, with radiation-enhanced diffusion at lower temperatures. The calculated temperature dependence of the bubble density shows excellent agreement with that observed in 600 MeV proton irradiations, including a reduction in...... activation energy below Tm/2. The coalescence of diatomic nuclei due to Brownian motion markedly improves the agreement and also provides a well-defined terminal density. Bubble nucleation by this mechanism is sufficiently fast to inhibit any appreciable initial loss of gas to grain boundaries during the...

  5. Gas temperature measurement in combustors by use of suction pyrometry

    The purpose of this paper is to introduce new measurement techniques and configurations in gas suction pyrometry. A detailed description of three types of mini-pyrometers for the study of burning and heat transfer processes is presented. A suction pyrometer whose inner cavity is insulated by ceramic wool was developed for use in high velocity and high temperature jets of combustion products. A second type of pyrometer was developed for measuring oscillating gas temperatures, based on a micron-size sensitive head located in a spherical piece of fibrous material, through which the hot gases are aspirated. A third pyrometer was developed with an electrically-heated thermocouple and pulsed suction for use in low velocity 'dirty' gaseous media

  6. Chemical relaxation times in a hadron gas at finite temperature

    Goity, J L

    1993-01-01

    The relaxation times of particle numbers in hot hadronic matter with vanishing baryon number are estimated using the ideal gas approximation and taking into account resonance decays and annihilation processes as the only sources of particle number fluctuations. Near the QCD critical temperature the longest relaxation times turn out to be of the order of 10 fm and grow roughly exponentially to become of the order of $10^{3}$ fm at temperatures around 100 MeV. As a consequence of such long relaxation times, a clear departure from chemical equilibrium must be observed in the momentum distribution of secondary particles produced in high energy nuclear collisions.

  7. Physical processes in low-temperature gas-dynamic lasers

    Konyukhov, V.K. (ed.)

    1990-01-01

    The book focuses on the coupled mode CO[sub 2] gasdynamic laser (16-22 [mu]m) and the feasibility of an H[sub 2]O or D[sub 2]O gasdynamic laser (in the submilimeter region) that could operate at exceptionally low stagnation temperatures. The text contains two major parts with eight chapters. In the first part, this text covers an overview of gas dynamic lasers in terms of vibrationally nonequilibrium processes for a homogeneous gas system and also for a gas-aerosol system with heterogeneous water condensation. The latter part is an excellent resource of a spectroscopic data base, which is useful in predicting performance characteristics of gasdynamic lasers. The last five chapters contain a detailed theoretical analysis and experimental results on rotationally nonequilibrium processes of both H[sub 2]O and D[sub 2]O in biphase (vapor liquid) supersonic flow. The role of rotational nonequilibrium has not received attention in gas dynamic lasers in the case of water-free condensation. The experimental measurements using high resolution spectroscopic studies in this text, however, indicate that a theoretical analysis of gasdynamic laser should take account the presence of effects of rotational non-equilibrium, particularly in rarefied supersonic jet streams with high water vapor concentration at low temperature. Similar rotational nonequilibrium effects were previously treated for HF or DF molecules when studying high energy chemical lasers.

  8. High-Temperature Gas-Cooled Test Reactor Point Design

    Sterbentz, James William [Idaho National Laboratory; Bayless, Paul David [Idaho National Laboratory; Nelson, Lee Orville [Idaho National Laboratory; Gougar, Hans David [Idaho National Laboratory; Kinsey, James Carl [Idaho National Laboratory; Strydom, Gerhard [Idaho National Laboratory; Kumar, Akansha [Idaho National Laboratory

    2016-04-01

    A point design has been developed for a 200 MW high-temperature gas-cooled test reactor. The point design concept uses standard prismatic blocks and 15.5% enriched UCO fuel. Reactor physics and thermal-hydraulics simulations have been performed to characterize the capabilities of the design. In addition to the technical data, overviews are provided on the technological readiness level, licensing approach and costs.

  9. Optimum Reactor Outlet Temperatures for High Temperature Gas-Cooled Reactors Integrated with Industrial Processes

    This report summarizes the results of a temperature sensitivity study conducted to identify the optimum reactor operating temperatures for producing the heat and hydrogen required for industrial processes associated with the proposed new high temperature gas-cooled reactor. This study assumed that primary steam outputs of the reactor were delivered at 17 MPa and 540 C and the helium coolant was delivered at 7 MPa at 625-925 C. The secondary outputs of were electricity and hydrogen. For the power generation analysis, it was assumed that the power cycle efficiency was 66% of the maximum theoretical efficiency of the Carnot thermodynamic cycle. Hydrogen was generated via the high temperature steam electrolysis or the steam methane reforming process. The study indicates that optimum or a range of reactor outlet temperatures could be identified to further refine the process evaluations that were developed for high temperature gas-cooled reactor-integrated production of synthetic transportation fuels, ammonia, and ammonia derivatives, oil from unconventional sources, and substitute natural gas from coal.

  10. Estimation of Wasted Thermal Energy from Gas Turbine Units in Mosul Power Station

    Dr. A. R. Al-Habbo; A.Youns Fathi

    2012-01-01

    The present study involve a thermal analysis of a gas turbine unit like those which are used in Mosul gas turbine power station in order to estimate the amount of thermal energy is wasted in the exhaust gases. A computer program is developed to investigate the effect of ambient temperature on the performance of the gas turbine unit including the mass flow of air, power output, thermal efficiency, specific fuel consumption, exhaust gas temperature and the amount of wasted thermal energy (Qexh)...

  11. Hybrid high temperature gas-cooled reactor, thermonuclear fusion

    The project of a multi-purpose high temperature gas-cooled reactor started in 1969. The Atomic Energy Commission, Japan, approved in 1980 the budget for the design study of the experimental reactor. The conceptual design is in progress. The manufacturing of coated fuel pellets and the test method have been developed. The study of graphite structure is carried out. Corrosion and creep tests are made to obtain the knowledge concerning the metals in high temperature helium gas. The engineering study of various machines and structures operating at high temperature is performed. International cooperative works are considered. The experimental reactor will be critical in 1987. A critical plasma test facility, JT-60, has been constructed at the Japan Atomic Energy Research Institute. As the theoretical work on plasma confinement, the evaluation of the critical beta value of JT-60 was made. By high temperature neutral beam injection, the slowing down and heating processes of high energy particles are studied. The development of a non-circular cross-section tokamak is in progress. The construction of JT-60 will be completed in 1984. Study concerning superconducting magnets is considered. Japan is one of the members of INTOR project. (Kato, T.)

  12. Corrosion of Alloy 617 in high-temperature gas environments

    High-temperature gas-cooled reactors (HTGRs) with helium gas as the primary coolant have been considered as one type of the Generation IV nuclear power reactor systems. Several nickel-based superalloys, including Alloy 617, are potential structural materials to serve as pressure boundary components, such as the intermediate heat exchanger (IHX) in an HTGR. Impurities in a helium coolant, such as H2O and O2, can interact with structural materials at working temperatures of >900 °C, leading to serious degradation on these materials. In addition, defects in IHX surface coatings would allow these species to reach and interact with the external surfaces of these components, leading to similar or even more serious degradation. In this study we investigated the oxidation behavior of Alloy 617 in high-temperature, gaseous environments with various levels of O2 and H2O. A series of general corrosion tests were conducted at test temperatures of 650 °C, 750 °C, 850 °C and 950 °C under various coolant compositions of dry air, 1% O2, 10% relative humidity (RH), and 50% RH. Preliminary results showed that the surface morphologies of the Alloy 617 samples exhibited distinct evidence of intergranular corrosion. Compact chromium oxide layers were observed on the sample surfaces. The oxidation mechanisms of this alloy in the designated environments are discussed

  13. High-Temperature Gas Sensor Array (Electronic Nose) Demonstrated

    Hunter, Gary W.

    2002-01-01

    The ability to measure emissions from aeronautic engines and in commercial applications such as automotive emission control and chemical process monitoring is a necessary first step if one is going to actively control those emissions. One single sensor will not give all the information necessary to determine the chemical composition of a high-temperature, harsh environment. Rather, an array of gas sensor arrays--in effect, a high-temperature electronic "nose"--is necessary to characterize the chemical constituents of a diverse, high-temperature environment, such as an emissions stream. The signals produced by this nose could be analyzed to determine the constituents of the emission stream. Although commercial electronic noses for near-room temperature applications exist, they often depend significantly on lower temperature materials or only one sensor type. A separate development effort necessary for a high-temperature electronic nose is being undertaken by the NASA Glenn Research Center, Case Western Reserve University, Ohio State University, and Makel Engineering, Inc. The sensors are specially designed for hightemperature environments. A first-generation high-temperature electronic nose has been demonstrated on a modified automotive engine. This nose sensor array was composed of sensors designed for hightemperature environments fabricated using microelectromechanical-systems- (MEMS-) based technology. The array included a tin-oxide-based sensor doped for nitrogen oxide (NOx) sensitivity, a SiC-based hydrocarbon (CxHy) sensor, and an oxygen sensor (O2). These sensors operate on different principles--resistor, diode, and electrochemical cell, respectively--and each sensor has very different responses to the individual gases in the environment. A picture showing the sensor head for the array is shown in the photograph on the left and the sensors installed in the engine are shown in the photograph on the right. Electronics are interfaced with the sensors for

  14. Gas hydrate dissociation in sediments: Pressure-temperature evolution

    Kwon, Tae-Hyuk; Cho, Gye-Chun; Santamarina, J. Carlos

    2008-03-01

    Hydrate-bearing sediments may destabilize spontaneously as part of geological processes, unavoidably during petroleum drilling/production operations or intentionally as part of gas extraction from the hydrate itself. In all cases, high pore fluid pressure generation is anticipated during hydrate dissociation. A comprehensive formulation is derived for the prediction of fluid pressure evolution in hydrate-bearing sediments subjected to thermal stimulation without mass transfer. The formulation considers pressure- and temperature-dependent volume changes in all phases, effective stress-controlled sediment compressibility, capillarity, and the relative solubilities of fluids. Salient implications are explored through parametric studies. The model properly reproduces experimental data, including the PT evolution along the phase boundary during dissociation and the effect of capillarity. Pore fluid pressure generation is proportional to the initial hydrate fraction and the sediment bulk stiffness; is inversely proportional to the initial gas fraction and gas solubility; and is limited by changes in effective stress that cause the failure of the sediment. When the sediment stiffness is high, the generated pore pressure reflects thermal and pressure changes in water, hydrate, and mineral densities. Comparative analyses for CO2 and CH4 highlight the role of gas solubility in excess pore fluid pressure generation. Dissociation in small pores experiences melting point depression due to changes in water activity, and lower pore fluid pressure generation due to the higher gas pressure in small gas bubbles. Capillarity effects may be disregarded in silts and sands, when hydrates are present in nodules and lenses and when the sediment experiences hydraulic fracture.

  15. Design study on gas turbine high temperature reactor (GTHTR300)

    Japan Atomic Energy Research Institute (JAERI) has been conducting the design study of an original design concept of gas turbine high temperature reactor, the GTHTR300 (Gas Turbine High Temperature Reactor 300). The GTHTR300 is a greatly simplified HTGR-GT plant that leads to substantially reduced technical and cost requirements for earlier technology deployment. Also, it is expected to be an efficient and economically competitive reactor in 2010s due to newly proposed design features such as core design with two-year refueling interval, conventional steel material usage for a reactor pressure vessel, innovative plant flow scheme and horizontally installed gas turbine unit. This paper describes the original design features focusing on reactor core design, fuel design, in-core structure design and reactor pressure vessel design. In addition, a preliminary cost evaluation proved that the capital cost of the GTHTR300 is less than a target cost of 200 thousands Yen/kWe. The present study is entrusted from the Ministry of Education, Culture, Sports, Science and Technology of Japan. (author)

  16. Optimum Reactor Outlet Temperatures for High Temperature Gas-Cooled Reactors Integrated with Industrial Processes

    Lee O. Nelson

    2011-04-01

    This report summarizes the results of a temperature sensitivity study conducted to identify the optimum reactor operating temperatures for producing the heat and hydrogen required for industrial processes associated with the proposed new high temperature gas-cooled reactor. This study assumed that primary steam outputs of the reactor were delivered at 17 MPa and 540°C and the helium coolant was delivered at 7 MPa at 625–925°C. The secondary outputs of were electricity and hydrogen. For the power generation analysis, it was assumed that the power cycle efficiency was 66% of the maximum theoretical efficiency of the Carnot thermodynamic cycle. Hydrogen was generated via the hightemperature steam electrolysis or the steam methane reforming process. The study indicates that optimum or a range of reactor outlet temperatures could be identified to further refine the process evaluations that were developed for high temperature gas-cooled reactor-integrated production of synthetic transportation fuels, ammonia, and ammonia derivatives, oil from unconventional sources, and substitute natural gas from coal.

  17. High-temperature gas effects on aerodynamic characteristics of waverider

    Liu Jun

    2015-02-01

    Full Text Available This paper focuses on the analysis of high-temperature effect on a conical waverider and it is a typical configuration of near space vehicles. Two different gas models are used in the numerical simulations, namely the thermochemical non-equilibrium and perfect gas models. The non-equilibrium flow simulations are conducted with the usage of the parallel non-equilibrium program developed by the authors while the perfect gas flow simulations are carried out with the commercial software Fluent. The non-equilibrium code is validated with experimental results and grid sensitivity analysis is performed as well. Then, numerical simulations of the flow around the conical waverider with the two gas models are conducted. In the results, differences in the flow structures as well as aerodynamic performances of the conical waverider are compared. It is found that the thermochemical non-equilibrium effect is significant mainly near the windward boundary layer at the tail of the waverider, and the non-equilibrium influence makes the pressure center move forward to about 0.57% of the whole craft’s length at the altitude of 60 km.

  18. High-temperature gas effects on aerodynamic characteristics of waverider

    Liu Jun; Li Kai; Liu Weiqiang

    2015-01-01

    This paper focuses on the analysis of high-temperature effect on a conical waverider and it is a typical configuration of near space vehicles. Two different gas models are used in the numerical simulations, namely the thermochemical non-equilibrium and perfect gas models. The non-equilibrium flow simulations are conducted with the usage of the parallel non-equilibrium pro-gram developed by the authors while the perfect gas flow simulations are carried out with the com-mercial software Fluent. The non-equilibrium code is validated with experimental results and grid sensitivity analysis is performed as well. Then, numerical simulations of the flow around the conical waverider with the two gas models are conducted. In the results, differences in the flow structures as well as aerodynamic performances of the conical waverider are compared. It is found that the thermochemical non-equilibrium effect is significant mainly near the windward boundary layer at the tail of the waverider, and the non-equilibrium influence makes the pressure center move forward to about 0.57%of the whole craft’s length at the altitude of 60 km.

  19. CO{sub 2}-fertilization via exhaust gas treatment of reciprocating gas engines: developments and experiences; Fertilisation au CO{sub 2} par traitement des gaz provenant de moteurs a gaz alternatifs: developpement et experience

    Bekker, M.; Hoving, K.; Klimstra, J.; Top, H. [N.V. Nederlandse Gasunie (Netherlands)

    2000-07-01

    The Dutch climate is such that greenhouses are used to produce vegetables, flowers and other plants. To heat the greenhouse, boilers and combined heat and power systems (CHP) are used. CHP has a better fuel utilisation than a boiler because of the simultaneously production of heat and power. In a greenhouse, CO{sub 2} has to be added to compensate the CO{sub 2} consumed by the plants to grow. Higher CO{sub 2} concentration than ambient are being used to increase plant growth and yield. The use of 'clean' flue gas from boilers was common practice but nowadays flue gas of engines can be used after cleaning. Exhaust gas cleaning systems (EGC) based on a Selective Reduction Catalyst and an Oxidation Catalyst make this possible. This paper describes the principle of these EGCs, gives insight into the important parameters which determine the required cleanliness and discusses the research results of Gasunie Research on this topic. It is found that different catalyst makes have their own specific behaviour depending on the monolith and active material and the how the catalyst is manufactured, mechanical mixed or impregnated. The use of CHP gives a high fuel utilisation and, in combination with EGC, increased crop yields. This results in an even more efficient use of the primary fuel, natural gas. (authors)

  20. Low temperature dynamic characteristics of a three-way catalytic converter

    Balenovic, M.; Backx, A.C.P.M. [Technische Univ. Eindhoven (Netherlands). Dept. of Electrical Engineering; Harmsen, J.M.A.; Hoebink, J.H.B.J. [Technische Univ. Eindhoven (Netherlands). Lab. of Chemical Reactor Engineering

    2001-07-01

    A mathematical model of a three-way catalytic converter based on a detailed chemical kinetic model has been created mainly to analyze the converter's dynamic behavior at low temperatures. The light-off process of the converter is analyzed in detail. Competition of species for empty noble metal surface determines the light-off characteristic, as inhibition processes increase light-off temperatures of some exhaust gas components in the complete exhaust mixture. Perturbations of the exhaust gas mixture around stoichiometry can in certain conditions decrease the effect of inhibition and lower the light-off temperature for some exhaust components. (orig.)

  1. Low temperature dynamic characteristics of a three-way catalytic converter

    Balenovic, M.; Backx, A.C.P.M. [Eindhoven University of Technology (Netherlands). Dept. of Electrical Engineering; Harmsen, J.M.A.; Hoebink, J.H.B.J. [Eindhoven University of Technology (Netherlands). Laboratory of Chemical Reactor Engineering

    2001-07-01

    A mathematical model of a three-way catalytic converter based on a detailed chemical kinetic model has been created mainly to analyze the converter's dynamic behavior at low temperatures. The light-off process of the converter is analyzed in detail. Competition of species for empty noble metal surface determines the light-off characteristic, as inhibition processes increase light-off temperatures of some exhaust gas components in the complete exhaust mixture. Perturbations of the exhaust gas mixture around stoichiometry can in certain conditions decrease the effect of inhibition and lower the light-off temperature for some exhaust components. (author)

  2. Startup analysis for a high temperature gas loaded heat pipe

    Sockol, P. M.

    1973-01-01

    A model for the rapid startup of a high-temperature gas-loaded heat pipe is presented. A two-dimensional diffusion analysis is used to determine the rate of energy transport by the vapor between the hot and cold zones of the pipe. The vapor transport rate is then incorporated in a simple thermal model of the startup of a radiation-cooled heat pipe. Numerical results for an argon-lithium system show that radial diffusion to the cold wall can produce large vapor flow rates during a rapid startup. The results also show that startup is not initiated until the vapor pressure p sub v in the hot zone reaches a precise value proportional to the initial gas pressure p sub i. Through proper choice of p sub i, startup can be delayed until p sub v is large enough to support a heat-transfer rate sufficient to overcome a thermal load on the heat pipe.

  3. La catalyse d'épuration des gaz d'échappement automobiles. Situation actuelle et nouvelles orientations Catalytic Automotive Exhaust Gas Depollution. Present Status and New Trends

    Prigent M.

    2006-11-01

    Full Text Available Cet article passe en revue les différents systèmes catalytiques de post-traitement utilisés actuellement sur la plupart des automobiles pour limiter leurs rejets de polluants. Les systèmes sont différenciés par leur mode de fonctionnement, le type de moteur à dépolluer (deux-temps, quatre-temps, diesel ou essence ou par leur mode de réalisation. Les nouvelles orientations, prévues pour respecter les futures réglementations antipollution, sont également décrites. On montre que certains véhicules prototypes, équipés de moteurs à combustion interne, sont capables d'avoir des émissions très proches de zéro tout comme les véhicules électriques. A review is made of the various types of exhaust gas aftertreatment systems presently used on most vehicles to reduce pollutant emissions. The systems are differentiated by their mode of action, according to the engine type to be depolluted (two-stroke, four-stroke, diesel or spark-ignition, and by their type of make-up. The major developments foreseen in the future, in view of compliance with the new legislations, are described. It is shown that some prototype vehicles with internal combustion engines are able to emit pollutant quantities really close to zero, such as electric cars.

  4. Effect of nozzle hole size coupling with exhaust gas re-circulation on the engine emission perfomance based on KH-ACT spray model

    Zhang Liang

    2015-01-01

    Full Text Available To research an effective measure of reducing the Soot and NOx in engine at the same time, different nozzle hole diameters coupled with exhaust gas recirculation (EGR were adopted in this study based on KH-ACT spray breakup model, which takes the aerodynamic-induced ,cavitation-induced and turbulence-induced breakup into account. The SAGE detailed chemistry combustion and the new atomization model used in the simulation have been verified with the experiment data from a YN4100QBZL engine. Different diesel nozzles was adopted in the study combined with different EGR rates ranging from 0% to 40%. The simulation results show that the NOx emission could be reduced effectively for both small(0.1mm and large(0.15mm diesel nozzle when increasing EGR ratio. The soot emission increases for the small nozzle hole size as the EGR increasing. However, when it comes to the large diesel nozzle, the emission increases slightly first and decrease quickly when the EGR rate above 20%.

  5. The effect of high temperatures on tropical forest gas exchange.

    Doughty, C. E.; Goulden, M.; Miller, S.; Da Rocha, H.

    2006-12-01

    Further research is required to understand the sensitivity of tropical forest to climate warming. Previous research has shown that tropical forest photosynthesis decreases and respiration increases at high leaf temperatures and that tree growth is reduced in years with higher average air temperatures (Clark et al 2003). Models indicate that the climate related destruction of the Amazon forest will amplify global warming by 1.5¢ª C, resulting in a mean temperature increase of 5.5¢ª C, as compared with 4¢ª C without this carbon cycle feedback (Cox et al 2000). These studies demonstrate the importance of temperature on tropical forest gas exchange. At the LBA Tapajos km 83 site we determined what controls tropical leaf temperature and how temperature affects photosynthesis and respiration. Sunlit leaves were substantially warmer than air temperatures and this had a negative effect on photosynthesis and stomatal conductance. We used eddy flux data to compare intervals of 10 minute cloudy periods followed by 20 minute sunny periods to see if similar trends could be seen at both the leaf and canopy level. The longer the sunny interval the warmer the canopy became and canopy conductance and CO2 exchange declined correspondingly. As the canopy warmed u* increased which increased turbulence and kept the canopy temperature from rising more. Long light intervals can cause heat stress in tropical forests but due to the very cloudy nature of the tropics such intervals are rare. However, if the tropics become both warmer and less cloudy such heat stress will increase.

  6. Exhaust gas emissions from various automotive fuels for light-duty vehicles. Effects on health, environment and energy utilization

    The main aim of the investigation has been to assess the effects on health and environment from various alternative fuels for light-duty vehicles. Effects that can be identified and quantified, such as acidification, ozone formation, cancer risk and climate change, have been of primary interest but other effects, such as respiratory diseases, have also been investigated. Data have been collected through literature surveys for subsequent calculation of the mentioned effects in different time-frames. Corrections have been used to take into consideration the influence of climate, ageing and driving pattern. Emissions generated in fuel production have also been accounted for. The most significant and important differences between the fuels have been found for effects as ozone formation cancer risk and particulate emissions. Alternative fuels, such as methanol and methane (natural gas and biogas), significantly decrease the ozone formation in comparison to petrol, while ethanol, methanol and methane are advantageous concerning cancer risk. The particulate emissions are considerably higher for diesel engines fuelled by diesel oil and RME in comparison to the other fuels. In the future, the importance of acid emissions in the fuel production will increase since the NOx and SOx emissions will decrease from the vehicles. The emissions of climate gases could be significantly reduced by using non-fossil fuels but the efficiency of the drive train is also of importance. The technical development potential for further emission reductions is considerable for all fuels but the advantage for the best fuel options will remain in the future

  7. Automobile Exhaust Pollution and Purification Methods

    Tang, Dawei

    2014-01-01

    As we all know, the automobile gas exhaust pollution has become more and more severe at recent years. It influences both to the human beings health and to quality of environment. The purpose of this thesis is to find out what are the main components of the exhaust gases, and give a basic and effective way to solve the problem. In this thesis, first the danger of exhaust pollution and its components will be presented. Then the writer will give the general mechanism of automobile exhaust ...

  8. Thorium fueled high temperature gas cooled reactors. An assessment

    The use of thorium as a fertile fuel for the High Temperature Gas Cooled Reactor (HTR) instead of uranium has been reviewed. It has been concluded that the use of thorium might be beneficial to reduce the actinide waste production. To achieve a real advancement, the uranium of the spent fuel has to be recycled and the requested make-up fissile material for the fresh fuel has to be used in the form of highly-enriched uranium. A self-sustaining fuel cycle may be possible in the HTR of large core size, but this could reduce the inherent safety features of the design. (orig.)

  9. Combustion Noise and Pollutants Prediction for Injection Pattern and Exhaust Gas Recirculation Tuning in an Automotive Common-Rail Diesel Engine

    Arsie Ivan

    2015-01-01

    Full Text Available In the last years, emissions standards for internal combustion engines are becoming more and more restrictive, particularly for NOx and soot emissions from Diesel engines. In order to comply with these requirements, OEMs have to face with innovative combustion concepts and/or sophisticate after-treatment devices. In both cases, the role of the Engine Management System (EMS is increasingly essential, following the large number of actuators and sensors introduced and the need to meet customer expectations on performance and comfort. On the other hand, the large number of control variables to be tuned imposes a massive recourse to the experimental testing which is poorly sustainable in terms of time and money. In order to reduce the experimental effort and the time to market, the application of simulation models for EMS calibration has become fundamental. Predictive models, validated against a limited amount of experimental data, allow performing detailed analysis on the influence of engine control variables on pollutants, comfort and performance. In this paper, a simulation analysis on the impact of injection pattern and Exhaust Gas Recirculation (EGR rate on fuel consumption, combustion noise, NO and soot emissions is presented for an automotive Common-Rail Diesel engine. Simulations are accomplished by means of a quasi-dimensional multi-zone model of in-cylinder processes. Furthermore a methodology for in-cylinder pressure processing is presented to estimate combustion noise contribution to radiated noise. Model validation is carried out by comparing simulated in-cylinder pressure traces and exhaust emissions with experimental data measured at the test bench in steady-state conditions. Effects of control variables on engine performance, noise and pollutants are analyzed by imposing significant deviation of EGR rate and injection pattern (i.e. rail pressure, start-of-injection, number of injections. The results evidence that quasi-dimensional in

  10. HT-PEM Fuel Cell System with Integrated Thermoelectric Exhaust Heat Recovery

    Gao, Xin

    This thesis presents two case studies on improving the efficiency and the loadfollowing capability of a high temperature polymer electrolyte membrane (HTPEM) fuel cell system by the application of thermoelectric (TE) devices. TE generators (TEGs) are harnessed to recover the system exhaust gas...

  11. Fort St. Vrain high temperature gas-cooled reactor

    The construction, testing, and preliminary operating experience of the Fort St. Vrain Nuclear Generating Station are described. This station utilizes the advanced high-temperature gas-cooled reactor (HTGR) concept and is the first nuclear reactor system in the United States to use a prestressed concrete reactor vessel (PCRV). Helium is used as the primary coolant, and a nitrogen system provides refrigeration for the low temperature equipment of the helium purification system and for the moisture monitors in the primary coolant system. Design, construction and testing to date at this station have made a significant contribution to the HTGR concept for central station electric generating plants to supply the increasing demands for electrical energy. (U.S.)

  12. Fission gas release from uranium dioxide in high temperature transients

    The experiments described in this thesis investigate the kinetics and mechanisms for release of inert fission gases from irradiated fuel (uranium dioxide) during temperature transients, occuring in AGR type and PWR type reactors. A description is given of the fundamental physical properties of uranium dioxide with particular emphasis placed on the effects of irradiation damage and the build-up of fission product concentrations. A brief review is given of the principle mechanisms by which gases are thought to be released, covering both thermal and irradiation induced processes. The main design features of the Civil Advanced Gas Cooled Reactor (CAGR) and Pressurised Water Reactor (PWR) systems, concentrating on the specifications and normal operating conditions of the uranium dioxide fuel. This is followed by a brief description of the conditions anticipated during postulated reactor malfunctions. Two classes of fault are considered, in which the fuel temperature increases through loss of coolant efficiency or a rise in heat generation rate. (author)

  13. High temperature phase equilibria in a solar-composition gas

    Using recent additions to thermochemical data on minerals and information on their solid solution behavior, new equilibrium phase diagrams have been computed in a system of solar gas composition (Si, Al, Mg, Ca, Fe, Ni, Ti, Na, K, C, H, O, S, N) in the pressure and temperature ranges of 1 to 10-6 bar and 1153 to 1773 K respectively. These calculations show that Fe-Ni alloy condenses before all silicates included here (except melilite) down to a pressure of 2 x 10-4 bar below which plagioclase and clinopyroxene condense first. Orthopyroxene condenses next followed by ilmenite. Pressure-temperature variation of the chemical composition of melilite, clinopyroxene, orthopyroxene, metal alloy and plagioclase may be used for cosmothermometry and cosmobarometry for equilibrium assemblages. The major transition from the refractory oxides and melilite (the meteorite 'inclusion assemblage') to an assemblage of Fe-Ni alloy, olivine, plagioclase and pyroxenes ('planet-forming') takes place within a narrow interval of pressure and temperature. Small fluctuations of either pressure or temperature across this narrow region result in drastic changes in types and modes of minerals, which may explain the wide mineralogical varieties of meteorites. (author)

  14. Exfoliated black phosphorus gas sensing properties at room temperature

    Donarelli, M.; Ottaviano, L.; Giancaterini, L.; Fioravanti, G.; Perrozzi, F.; Cantalini, C.

    2016-06-01

    Room temperature gas sensing properties of chemically exfoliated black phosphorus (BP) to oxidizing (NO2, CO2) and reducing (NH3, H2, CO) gases in a dry air carrier have been reported. To study the gas sensing properties of BP, chemically exfoliated BP flakes have been drop casted on Si3N4 substrates provided with Pt comb-type interdigitated electrodes in N2 atmosphere. Scanning electron microscopy and x-ray photoelectron spectroscopy characterizations show respectively the occurrence of a mixed structure, composed of BP coarse aggregates dispersed on BP exfoliated few layer flakes bridging the electrodes, and a clear 2p doublet belonging to BP, which excludes the occurrence of surface oxidation. Room temperature electrical tests in dry air show a p-type response of multilayer BP with measured detection limits of 20 ppb and 10 ppm to NO2 and NH3 respectively. No response to CO and CO2 has been detected, while a slight but steady sensitivity to H2 has been recorded. The reported results confirm, on an experimental basis, what was previously theoretically predicted, demonstrating the promising sensing properties of exfoliated BP.

  15. Radioactivity evaluation code system for high temperature gas cooled reactors

    A code system for the evaluation of the behavior of radioactive fission products (FP) in high temperature gas-cooled reactors (HTGR) is described. The first half of this report is devoted to the description of the conceivable behavior of FPs in the experimental very high temperature gas-cooled reactor being designed at JAERI. The transfer of FPs from the fuel to the primary coolant is considered in three steps; the release of FPs from the coated fuel particles; the diffusion of FPs within graphite sleeves; and the transfer of FPs from the sleeve surface to the coolant. As for the FP behavior within the primary coolant system, the deposition of FPs on various walls of the system is considered. As for the secondary and the thermal utilization systems, the transfer of tritium is specially considered. The calculation model for the transfer and deposition of fission products within the whole plant system is presented by a chart. The second half of this report describes the evaluation code system. The physical and mathematical models treated in each component code are presented and discussed. (Aoki, K.)

  16. Temperature profile and producer gas composition of high temperature air gasification of oil palm fronds

    Environmental pollution and scarcity of reliable energy source are the current pressing global problems which need a sustainable solution. Conversion of biomass to a producer gas through gasification process is one option to alleviate the aforementioned problems. In the current research the temperature profile and composition of the producer gas obtained from the gasification of oil palm fronds by using high temperature air were investigated and compared with unheated air. By preheating the gasifying air at 500°C the process temperature were improved and as a result the concentration of combustible gases and performance of the process were improved. The volumetric percentage of CO, CH4 and H2 were improved from 22.49, 1.98, and 9.67% to 24.98, to 2.48% and 13.58%, respectively. In addition, HHV, carbon conversion efficiency and cold gas efficiency were improver from 4.88 MJ/Nm3, 83.8% and 56.1% to 5.90 MJ/Nm3, 87.3% and 62.4%, respectively.

  17. The Status of Marine Engine Exhaust Gas Scrubbing and Desulfurizing Technology and its Development Trend%船舶废气洗涤脱硫技术现状及发展趋势

    周松; 李琤; 沈飞翔

    2014-01-01

    As marine engine exhaust gas emission limitation is becoming more and more stringent, the research state of marine engine exhaust gas scrubber is introduced in detail, and the tendency, economy and prospect of the application of marine scrubbers are analyzed. The research shows that the exhaust gas scrubber is a valid measure to meet IMO 2015 regulation of fuel sulphur content. Although the initial in-vestment of scrubber is large, the capital can be recovered in 1~4 years, and is expected to have wide application in marine auxiliary products market.%针对船舶排放控制日趋严格,介绍了国内外船舶动力装置废气洗涤脱硫技术的研究现状,并分析了其发展趋势、经济性和应用前景。研究表明,船舶废气洗涤技术是应对2015年IMO燃油含硫量限制的有效方法。洗涤系统虽然初投资较大,但成本可在1~4年内收回,具有广阔的市场前景。

  18. A highly efficient six-stroke internal combustion engine cycle with water injection for in-cylinder exhaust heat recovery

    A concept adding two strokes to the Otto or Diesel engine cycle to increase fuel efficiency is presented here. It can be thought of as a four-stroke Otto or Diesel cycle followed by a two-stroke heat recovery steam cycle. A partial exhaust event coupled with water injection adds an additional power stroke. Waste heat from two sources is effectively converted into usable work: engine coolant and exhaust gas. An ideal thermodynamics model of the exhaust gas compression, water injection and expansion was used to investigate this modification. By changing the exhaust valve closing timing during the exhaust stroke, the optimum amount of exhaust can be recompressed, maximizing the net mean effective pressure of the steam expansion stroke (MEPsteam). The valve closing timing for maximum MEPsteam is limited by either 1 bar or the dew point temperature of the expansion gas/moisture mixture when the exhaust valve opens. The range of MEPsteam calculated for the geometry of a conventional gasoline engine and is from 0.75 to 2.5 bars. Typical combustion mean effective pressures (MEPcombustion) of naturally aspirated gasoline engines are up to 10 bar, thus this concept has the potential to significantly increase the engine efficiency and fuel economy.

  19. Roles of catalytic oxidation in control of vehicle exhaust emissions

    Catalytic oxidation was initially associated with the early development of catalysis and it subsequently became a part of many industrial processes, so it is not surprising it was used to remove hydrocarbons and CO when it became necessary to control these emissions from cars. Later NOx was reduced in a process involving reduction over a Pt/Rh catalyst followed by air injection in front of a Pt-based oxidation catalyst. If over-reduction of NO to NH3 took place, or if H2S was produced, it was important these undesirable species were converted to NOx and SOx in the catalytic oxidation stage. When exhaust gas composition could be kept stoichiometric hydrocarbons, CO and NOx were simultaneously converted over a single Pt/Rh three-way catalyst (TWC). With modern TWCs car tailpipe emissions can be exceptionally low. NO is not catalytically dissociated to O2 and N2 in the presence of O2, it can only be reduced to N2. Its control from lean-burn gasoline engines involves catalytic oxidation to NO2 and thence nitrate that is stored and periodically reduced to N2 by exhaust gas enrichment. This method is being modified for diesel engines. These engines produce soot, and filtration is being introduced to remove it. The exhaust temperature of heavy-duty diesels is sufficient (250-400oC) for NO to be catalytically oxidised to NO2 over an upstream platinum catalyst that smoothly oxidises soot in the filter. The exhaust gas temperature of passenger car diesels is too low for this to take place all of the time, so trapped soot is periodically burnt in O2 above 550oC. Catalytic oxidation of higher than normal amounts of hydrocarbon and CO over an upstream catalyst is used to give sufficient temperature for soot combustion with O2 to take place. (author)

  20. Time-dependent temperature field under conditions of filtration of gas-liquid mixture

    One solved the problem of temperature fields at filtration of gas containing liquid with regard to phase transitions and imperfection of a gas phase. One determined regularities of formation of time-dependent temperature fields at filtration of those mixtures. At rather long times and at not very high values of coefficient of gas solubility the temperature effect of filtrating liquid with dissolved gas changes the sign

  1. Metaphysics methods development for high temperature gas cooled reactor analysis

    Gas cooled reactors have been characterized as one of the most promising nuclear reactor concepts in the Generation-IV technology road map. Considerable research has been performed on the design and safety analysis of these reactors. However, the calculational tools being used to perform these analyses are not state-of-the-art and are not capable of performing detailed three-dimensional analyses. This paper presents the results of an effort to develop an improved thermal-hydraulic solver for the pebble bed type high temperature gas cooled reactors. The solution method is based on the porous medium approach and the momentum equation including the modified Ergun's resistance model for pebble bed is solved in three-dimensional geometry. The heat transfer in the pebble bed is modeled considering the local thermal non-equilibrium between the solid and gas, which results in two separate energy equations for each medium. The effective thermal conductivity of the pebble-bed can be calculated both from Zehner-Schluender and Robold correlations. Both the fluid flow and the heat transfer are modeled in three dimensional cylindrical coordinates and can be solved in steady-state and time dependent. The spatial discretization is performed using the finite volume method and the theta-method is used in the temporal discretization. A preliminary verification was performed by comparing the results with the experiments conducted at the SANA test facility. This facility is located at the Institute for Safety Research and Reactor Technology (ISR), Julich, Germany. Various experimental cases are modeled and good agreement in the gas and solid temperatures is observed. An on-going effort is to model the control rod ejection scenarios as described in the OECD/NEA/NSC PBMR-400 benchmark problem. In order to perform these analyses PARCS reactor simulator code will be coupled with the new thermal-hydraulic solver. Furthermore, some of the other anticipated accident scenarios in the benchmark

  2. Commercial-vehicle engines and exhaust-gas aftertreatment in the conflict between customer benefits and emission legislation; Nutzfahrzeugmotoren und Abgasnachbehandlung im Zielkonflikt zwischen Kundennutzen und Emissionsgesetzgebung

    Laemmermann, R.; Held, W. [MAN Nutzfahrzeuge Gruppe, Geschaeftseinheit Motoren, Nuernberg (Germany)

    2006-07-01

    From October 2006 onwards all commercial vehicles > 7.5 t newly registered in Europe must comply with the Euro 4 emission limits. At the same time vehicles > 12 t which already comply with the next emission step (Euro 5) can in Germany expect to qualify for a discount of 2 ct/km on the motorway toll. These incentives can also be expected to apply at the introduction of the next emission limit step in 2009, provided that premature compliance with the Euro 6 limits is guaranteed. Both the Euro 6 emission limits themselves and the testing procedures have, however, not yet been agreed in Europe. In USA the EPA has decided on very low limits for 2007, and these will, with regard to NOx emissions, be made even stricter in 2010. Despite the reduction in NO{sub x} emissions it will be very important to ensure minimum fuel consumption. Higher consumption, which is normally a consequence of any reduction in NOx emissions, results in higher CO{sub 2} emission, but also means higher costs for hauliers. In future, therefore, everything possible must be done to keep the level of CO{sub 2} emission, which is not subject to limitation, as low as possible. The commercial-vehicle industry is currently making great efforts to develop suitable technical solutions in the shortest possible time. The following paper describes the changes in emission limits and emission cycles currently under discussion. It also explains the very elaborate technical measures necessary for complying with the future statutory regulations on emissions from commercial vehicles. Only with a clever combination of internal modifications to the engine which reduce the emissions and suitable but expensive exhaust-gas aftertreatment systems will it be possible to provide environmentally compatible and economical commercial vehicles for the still rising volume of road goods transport. (orig.)

  3. Extraction of Mg(OH)2 from Mg silicate minerals with NaOH assisted with H2O: implications for CO2 capture from exhaust flue gas.

    Madeddu, Silvia; Priestnall, Michael; Godoy, Erik; Kumar, R Vasant; Raymahasay, Sugat; Evans, Michael; Wang, Ruofan; Manenye, Seabelo; Kinoshita, Hajime

    2015-01-01

    The utilisation of Mg(OH)2 to capture exhaust CO2 has been hindered by the limited availability of brucite, the Mg(OH)2 mineral in natural deposits. Our previous study demonstrated that Mg(OH)2 can be obtained from dunite, an ultramafic rock composed of Mg silicate minerals, in highly concentrated NaOH aqueous systems. However, the large quantity of NaOH consumed was considered an obstacle for the implementation of the technology. In the present study, Mg(OH)2 was extracted from dunite reacted in solid systems with NaOH assisted with H2O. The consumption of NaOH was reduced by 97% with respect to the NaOH aqueous systems, maintaining a comparable yield of Mg(OH)2 extraction, i.e. 64.8-66%. The capture of CO2 from a CO2-N2 gas mixture was tested at ambient conditions using a Mg(OH)2 aqueous slurry. Mg(OH)2 almost fully dissolved and reacted with dissolved CO2 by forming Mg(HCO3)2 which remained in equilibrium storing the CO2 in the aqueous solution. The CO2 balance of the process was assessed from the emissions derived from the power consumption for NaOH production and Mg(OH)2 extraction together with the CO2 captured by Mg(OH)2 derived from dunite. The process resulted as carbon neutral when dunite is reacted at 250 °C for durations of 1 and 3 hours and CO2 is captured as Mg(HCO3)2. PMID:26391815

  4. The determination of regulated and some unregulated exhaust gas components from ethanol blended diesel fuels in comparison with neat diesel and ethanol fuel

    Investigations that have been carried out at Luleaa University of Technology (LTU) show how exhaust gas emissions and engine performance are affected by the composition of the fuels. The fuels that have been tested and compared are two different ethanol blended diesel fuels, 'neat' diesel fuels and neat ethanol fuels. Two different, heavy-duty engines were used for the investigations; one for the neat ethanol fuels and the other for the ethanol blended diesel fuels and neat diesel fuels. The investigation also includes some tests with two oxidizing catalysts. Results from the investigation show that none of the fuels produce emissions exceeding the values of the 13-mode test (ECE R-49, 1997). Lowest HC-emission levels were found for the two 'neat' ethanol fuels although the difference between the HC-emissions can be considered negligible for the studied fuels. An effective reduction in the hydrocarbon emissions was achieved by using a catalyst. The investigation also shows that the NOx emissions were much lower for the neat ethanol fuels than for the other fuels. Even if the CO emissions from the two ethanol fuels were approximately three times higher than for the other investigated fuels the use of a catalyst equalize the CO emissions from the studied fuels. The formaldehyde and acetaldehyde emissions were clearly higher for the neat ethanol fuels than for the other investigated fuels. However, by using a catalyst the formaldehyde emission from the ethanol fuels could be decreased. Unfortunately, the use of a catalyst also resulted in an increase in the emission of acetaldehyde from the ethanol fuelled engine 10 refs, 11 figs, 5 tabs, 6 appendixes

  5. Reduced graphene oxide for room-temperature gas sensors

    We demonstrated high-performance gas sensors based on graphene oxide (GO) sheets partially reduced via low-temperature thermal treatments. Hydrophilic graphene oxide sheets uniformly suspended in water were first dispersed onto gold interdigitated electrodes. The partial reduction of the GO sheets was then achieved through low-temperature, multi-step annealing (100, 200, and 300 0C) or one-step heating (200 0C) of the device in argon flow at atmospheric pressure. The electrical conductance of GO was measured after each heating cycle to interpret the level of reduction. The thermally-reduced GO showed p-type semiconducting behavior in ambient conditions and was responsive to low-concentration NO2 and NH3 gases diluted in air at room temperature. The sensitivity can be attributed mainly to the electron transfer between the reduced GO and adsorbed gaseous molecules (NO2/NH3). Additionally, the contact between GO and the Au electrode is likely to contribute to the overall sensing response because of the adsorbates-induced Schottky barrier variation. A simplified model is used to explain the experimental observations.

  6. New deployment of high temperature gas-cooled reactor

    The high temperature gas-cooled reactor (HTGR) is now under a condition difficult to know it well, because of considering not only power generation, but also diverse applications of its nuclear heat, of having extremely different safe principle from that of conventional reactors, of having two types of pebble-bed and block which are extremely different types, of promoting its construction plan in South Africa, of including its application to disposition of Russian surplus weapons plutonium of less reporting HTTR in Japan in spite of its full operation, and so on. However, HTGR is expected for an extremely important nuclear reactor aiming at the next coming one of LWR. HTGR which is late started and developed under complete private leading, is strongly conscious at environmental problem since its beginning. Before 30 years when large scale HTGR was expected to operate, it advertised a merit to reduce wasted heat because of its high temperature. As ratio occupied by electricity expands among application of energies, ratio occupied by the other energies are larger. When considering applications except electric power, high temperature thermal energy from HTGR can be thought wider applications than that from LWR and so on. (G.K.)

  7. Catalytic removal of methane and NO{sub x} in lean-burn natural-gas engine exhaust; Elimination par catalyse du methane et des NO{sub x} dans les echappements de moteur au gaz naturel a basse combustion

    Yamamoto, H.; Satokawa, S.; Yahagi, M.; Yamaseki, K.; Hoshi, F.; Uchida, H.; Yokota, H. [Tokyo Gas Co., Ltd. (Japan)

    2000-07-01

    We have developed a new catalytic system to reduce the emissions of hydrocarbons, carbon monoxide (CO), and nitrogen oxides (NO{sub x}) contained in the exhaust gases from a lean-burn natural-gas engine. Catalytic oxidation of unburned hydrocarbons and CO in the exhaust has been studied for noble metals supported on alumina. (1) A low-loading catalyst comprising platinum supported on alumina (Pt/alumina) was efficient for the oxidation of CO and hydrocarbons without methane. The CO conversions were maintained at more than 98 % for 20,000 hours over the Pt/alumina. (2) A catalyst comprising platinum and palladium supported on alumina (Pt-Pd/alumina) exhibited higher levels of oxidation of hydrocarbons (including methane) than a catalyst comprising only palladium supported on alumina (Pd/alumina). Its oxidation also lasted longer. The combined effects of the platinum and palladium metals achieved high sulfur dioxide resistance. Increasing the palladium content in the Pt-Pd/alumina catalyst increased the level of oxidation and extended the lifetime of the catalyst. (3) A catalyst comprising silver supported on alumina (Ag/alumina) was effective at reducing the amount of NO{sub X} by using the unburned hydrocarbons in the exhaust gas. The NO{sub x} conversions over Ag/alumina were maintained at more than 30 % for 3,500 hours. We describe a total clean-up system consisting of a Ag/alumina catalyst and a Pt-Pd/alumina catalyst in series on the exhaust gas stream. (authors)

  8. Seismic study on high temperature gas-cooled reactor core

    The resistance against earthquakes of a high temperature gas-cooled reactor (HTGR) core with block-type fuel is not yet fully ascertained. Seismic studies must be made if such a reactor plant is to be installed in the areas with frequent earthquakes. The experimental and analytical studies for the seismic response of the HTGR core were carried out. First, the fundamental behavior, such as the softening characteristic of a single stacked column (which is piled up with blocks) and the hardening characteristic with the block impact were clarified from the seismic experiments. Second, the displacement and the impact characteristics of the two-dimensional vertical core and the two-dimensional horizontal core were studied from the seismic experiments. Finally, analytical methods and computer programs for the seismic response of HTGR cores were developed. (author) 57 refs

  9. Medium-size high-temperature gas-cooled reactor

    This report summarizes high-temperature gas-cooled reactor (HTGR) experience for the 40-MW(e) Peach Bottom Nuclear Generating Station of Philadelphia Electric Company and the 330-MW(e) Fort St. Vrain Nuclear Generating Station of the Public Service Company of Colorado. Both reactors are graphite moderated and helium cooled, operating at approx. 7600C (14000F) and using the uranium/thorium fuel cycle. The plants have demonstrated the inherent safety characteristics, the low activation of components, and the high efficiency associated with the HTGR concept. This experience has been translated into the conceptual design of a medium-sized 1170-MW(t) HTGR for generation of 450 MW of electric power. The concept incorporates inherent HTGR safety characteristics [a multiply redundant prestressed concrete reactor vessel (PCRV), a graphite core, and an inert single-phase coolant] and engineered safety features

  10. Hybrid simulation of high temperature gas cooled reactor

    A hybrid simulator was made to calculate the dynamics of high temperature gas cooled reactor(VHTR). The continuous space-discrete time (CSDT) method is applied to solve the partial differential equations of the heat transfer in the hybrid computation. By this method the error of the heat balance is decreased to less than one percent in the steady state. Though the mini computer is used for this simulator, it operates about five times faster than real time. The dynamics of VHTR are characterized by the large heat capacity of the reactor core and the long time constant. The values of these parameters are reported as the results of this calculation. The control system of the reactivity and the coolant flow rate is required to operate the reactor. The nonlinearity of VHTR which occurs in the change of flow rate are also understood quantitatively by this simulator. (author)

  11. Advances in High Temperature Gas Cooled Reactor Fuel Technology

    This publication reports on the results of a coordinated research project on advances in high temperature gas cooled reactor (HTGR) fuel technology and describes the findings of research activities on coated particle developments. These comprise two specific benchmark exercises with the application of HTGR fuel performance and fission product release codes, which helped compare the quality and validity of the computer models against experimental data. The project participants also examined techniques for fuel characterization and advanced quality assessment/quality control. The key exercise included a round-robin experimental study on the measurements of fuel kernel and particle coating properties of recent Korean, South African and US coated particle productions applying the respective qualification measures of each participating Member State. The summary report documents the results and conclusions achieved by the project and underlines the added value to contemporary knowledge on HTGR fuel.

  12. Performance improvement of a 330MWe power plant by flue gas heat recovery system

    Xu Changchun; Xu Min; Zhao Ming; Liang Junyu; Sai Juncong; Qiu Yalin; Xiang Wenguo

    2016-01-01

    In a utility boiler, the most heat loss is from the exhaust flue gas. In order to reduce the exhaust flue gas temperature and further boost the plant efficiency, an improved indirect flue gas heat recovery system and an additional economizer system are proposed. The waste heat of flue gas is used for high-pressure condensate regeneration heating. This reduces high pressure steam extraction from steam turbine and more power is generated. The waste heat recov...

  13. Heat Exhaustion, First Aid

    ... rashes clinical tools newsletter | contact Share | Heat Exhaustion, First Aid A A A Heat exhaustion signs and symptoms ... specific to the other stages of heat illness. First Aid Guide Use a combination of the following measures ...

  14. Thermal Hydraulics of the Very High Temperature Gas Cooled Reactor

    The U.S Department of Energy (DOE) is conducting research on the Very High Temperature Reactor (VHTR) design concept for the Next Generation Nuclear Plant (NGNP) Project. The reactor design will be a graphite moderated, thermal neutron spectrum reactor that will produce electricity and hydrogen in a highly efficient manner. The NGNP reactor core will be either a prismatic graphite block type core or a pebble bed core. The NGNP will use very high-burnup, low-enriched uranium, TRISO-coated fuel, and have a projected plant design service life of 60 years. The VHTR concept is considered to be the nearest-term reactor design that has the capability to efficiently produce hydrogen. The plant size, reactor thermal power, and core configuration will ensure passive decay heat removal without fuel damage or radioactive material releases during reactor core-accidents. The objectives of the NGNP Project are to: Demonstrate a full-scale prototype VHTR that is commercially licensed by the U.S. Nuclear Regulatory Commission, and Demonstrate safe and economical nuclear-assisted production of hydrogen and electricity. The DOE laboratories, led by the INL, perform research and development (R and D) that will be critical to the success of the NGNP, primarily in the areas of: (1) High temperature gas reactor fuels behavior; (2) High temperature materials qualification; (3) Design methods development and validation; (4) Hydrogen production technologies; and (5) Energy conversion. This paper presents current R and D work that addresses fundamental thermal hydraulics issues that are relevant to a variety of possible NGNP designs

  15. Thermal hydraulics of the very high temperature gas cooled reactor

    The Idaho National Laboratory (INL), under the auspices of the U.S. Department of Energy, is conducting research on the Very High Temperature Reactor (VHTR) design concept for the Next Generation Nuclear Plant (NGNP) Project. The reactor design will be a graphite moderated, thermal neutron spectrum reactor that will produce electricity and hydrogen in a highly efficient manner. The NGNP reactor core will be either a prismatic graphite block type core or a pebble bed core. The NGNP will use very high-burnup, low-enriched uranium, TRISO-coated fuel, and have a projected plant design service life of 60 years. The VHTR concept is considered to be the nearest-term reactor design that has the capability to efficiently produce hydrogen. The plant size, reactor thermal power, and core configuration will ensure passive decay heat removal without fuel damage or radioactive material releases during reactor core-accidents. The objectives of the NGNP Project are to: Demonstrate a full-scale prototype VHTR that is commercially licensed by the U.S. Nuclear Regulatory Commission, and Demonstrate safe and economical nuclear-assisted production of hydrogen and electricity. The DOE laboratories, led by the INL, perform research and development (R and D) that will be critical to the success of the NGNP, primarily in the areas of: · High temperature gas reactor fuels behavior · High temperature materials qualification · Design methods development and validation · Hydrogen production technologies · Energy conversion. This paper presents current R and D work that addresses fundamental thermal hydraulics issues that are relevant to a variety of possible NGNP designs. (author)

  16. Thermal Hydraulics of the Very High Temperature Gas Cooled Reactor

    Chang Oh; Eung Kim; Richard Schultz; Mike Patterson; Davie Petti

    2009-10-01

    The U.S Department of Energy (DOE) is conducting research on the Very High Temperature Reactor (VHTR) design concept for the Next Generation Nuclear Plant (NGNP) Project. The reactor design will be a graphite moderated, thermal neutron spectrum reactor that will produce electricity and hydrogen in a highly efficient manner. The NGNP reactor core will be either a prismatic graphite block type core or a pebble bed core. The NGNP will use very high-burnup, low-enriched uranium, TRISO-coated fuel, and have a projected plant design service life of 60 years. The VHTR concept is considered to be the nearest-term reactor design that has the capability to efficiently produce hydrogen. The plant size, reactor thermal power, and core configuration will ensure passive decay heat removal without fuel damage or radioactive material releases during reactor core-accidents. The objectives of the NGNP Project are to: Demonstrate a full-scale prototype VHTR that is commercially licensed by the U.S. Nuclear Regulatory Commission, and Demonstrate safe and economical nuclear-assisted production of hydrogen and electricity. The DOE laboratories, led by the INL, perform research and development (R&D) that will be critical to the success of the NGNP, primarily in the areas of: • High temperature gas reactor fuels behavior • High temperature materials qualification • Design methods development and validation • Hydrogen production technologies • Energy conversion. This paper presents current R&D work that addresses fundamental thermal hydraulics issues that are relevant to a variety of possible NGNP designs.

  17. Exhaust emission control and diagnostics

    Mazur, Christopher John; Upadhyay, Devesh

    2006-11-14

    A diesel engine emission control system uses an upstream oxidation catalyst and a downstream SCR catalyst to reduce NOx in a lean exhaust gas environment. The engine and upstream oxidation catalyst are configured to provide approximately a 1:1 ratio of NO to NO2 entering the downstream catalyst. In this way, the downstream catalyst is insensitive to sulfur contamination, and also has improved overall catalyst NOx conversion efficiency. Degradation of the system is determined when the ratio provided is no longer near the desired 1:1 ratio. This condition is detected using measurements of engine operating conditions such as from a NOx sensor located downstream of the catalysts. Finally, control action to adjust an injected amount of reductant in the exhaust gas based on the actual NO to NO2 ratio upstream of the SCR catalyst and downstream of the oxidation catalyst.

  18. Estimating the temperature of a catalytic converter

    Ma, T.T.-H.

    1994-11-02

    A method of estimating the temperature of a catalytic converter used in the exhaust system of an internal combustion engine is described. Heated exhaust gas oxygen (HEGO) sensors are placed upstream and downstream of the catalytic converter. The temperature of the catalytic converter shortly after start-up is measured by monitoring the resistance of the HEGO sensor's heating element. The downstream sensor is used for mixture control and to double check results of the upstream sensor. (UK)

  19. Integration of a molten carbonate fuel cell with a direct exhaust absorption chiller

    Margalef, Pere; Samuelsen, Scott [National Fuel Cell Research Center (NFCRC), University of California, Irvine, CA 92697-3550 (United States)

    2010-09-01

    A high market value exists for an integrated high-temperature fuel cell-absorption chiller product throughout the world. While high-temperature, molten carbonate fuel cells are being commercially deployed with combined heat and power (CHP) and absorption chillers are being commercially deployed with heat engines, the energy efficiency and environmental attributes of an integrated high-temperature fuel cell-absorption chiller product are singularly attractive for the emerging distributed generation (DG) combined cooling, heating, and power (CCHP) market. This study addresses the potential of cooling production by recovering and porting the thermal energy from the exhaust gas of a high-temperature fuel cell (HTFC) to a thermally activated absorption chiller. To assess the practical opportunity of serving an early DG-CCHP market, a commercially available direct fired double-effect absorption chiller is selected that closely matches the exhaust flow and temperature of a commercially available HTFC. Both components are individually modeled, and the models are then coupled to evaluate the potential of a DG-CCHP system. Simulation results show that a commercial molten carbonate fuel cell generating 300 kW of electricity can be effectively coupled with a commercial 40 refrigeration ton (RT) absorption chiller. While the match between the two ''off the shelf'' units is close and the simulation results are encouraging, the match is not ideal. In particular, the fuel cell exhaust gas temperature is higher than the inlet temperature specified for the chiller and the exhaust flow rate is not sufficient to achieve the potential heat recovery within the chiller heat exchanger. To address these challenges, the study evaluates two strategies: (1) blending the fuel cell exhaust gas with ambient air, and (2) mixing the fuel cell exhaust gases with a fraction of the chiller exhaust gas. Both cases are shown to be viable and result in a temperature drop and flow

  20. Temperature Control of Gas Chromatograph Based on Switched Delayed System Techniques

    Xiao-Liang Wang; Ming-Xu Zhang; Kun-Zhi Liu; Xi-Ming Sun

    2014-01-01

    We address the temperature control problem of the gas chromatograph. We model the temperature control system of the gas chromatograph into a switched delayed system and analyze the stability by common Lyapunov functional technique. The PI controller parameters can be given based on the proposed linear matrix inequalities (LMIs) condition and the designed controller can make the temperature of gas chromatograph track the reference signal asymptotically. An experiment is given to illustrate the...

  1. Temperature Control of Gas Chromatograph Based on Switched Delayed System Techniques

    Xiao-Liang Wang

    2014-01-01

    Full Text Available We address the temperature control problem of the gas chromatograph. We model the temperature control system of the gas chromatograph into a switched delayed system and analyze the stability by common Lyapunov functional technique. The PI controller parameters can be given based on the proposed linear matrix inequalities (LMIs condition and the designed controller can make the temperature of gas chromatograph track the reference signal asymptotically. An experiment is given to illustrate the effectiveness of the stability criterion.

  2. Numerical Modeling of Exhaust Smoke Dispersion for a Generic Frigate and Comparisons with Experiments

    Selma Ergin; Erin Dobrucal

    2014-01-01

    The exhaust smoke dispersion for a generic frigate is investigated numerically through the numerical solution of the governing fluid flow, energy, species and turbulence equations. The main objective of this work is to obtain the effects of the yaw angle, velocity ratio and buoyancy on the dispersion of the exhaust smoke. The numerical method is based on the fully conserved control-volume representation of the fully elliptic Navier-Stokes equations. Turbulence is modeled using a two-equation (k-ε) model. The flow visualization tests using a 1/100 scale model of the frigate in the wind tunnel were also carried out to determine the exhaust plume path and to validate the computational results. The results show that down wash phenomena occurs for the yaw angles between ψ=10° and 20°. The results with different exhaust gas temperatures show that the buoyancy effect increases with the increasing of the exhaust gas temperature. However, its effect on the plume rise is less significant in comparison with its momentum. A good agreement between the predictions and experiment results is obtained.

  3. Numerical modeling of exhaust smoke dispersion for a generic frigate and comparisons with experiments

    Ergin, Selma; Dobrucalı, Erinç

    2014-06-01

    The exhaust smoke dispersion for a generic frigate is investigated numerically through the numerical solution of the governing fluid flow, energy, species and turbulence equations. The main objective of this work is to obtain the effects of the yaw angle, velocity ratio and buoyancy on the dispersion of the exhaust smoke. The numerical method is based on the fully conserved control-volume representation of the fully elliptic Navier-Stokes equations. Turbulence is modeled using a two-equation ( k- ɛ) model. The flow visualization tests using a 1/100 scale model of the frigate in the wind tunnel were also carried out to determine the exhaust plume path and to validate the computational results. The results show that down wash phenomena occurs for the yaw angles between ψ =10° and 20°. The results with different exhaust gas temperatures show that the buoyancy effect increases with the increasing of the exhaust gas temperature. However, its effect on the plume rise is less significant in comparison with its momentum. A good agreement between the predictions and experiment results is obtained.

  4. Multiphysics methods development for high temperature gas reactor analysis

    Seker, Volkan

    Multiphysics computational methods were developed to perform design and safety analysis of the next generation Pebble Bed High Temperature Gas Cooled Reactors. A suite of code modules was developed to solve the coupled thermal-hydraulics and neutronics field equations. The thermal-hydraulics module is based on the three dimensional solution of the mass, momentum and energy equations in cylindrical coordinates within the framework of the porous media method. The neutronics module is a part of the PARCS (Purdue Advanced Reactor Core Simulator) code and provides a fine mesh finite difference solution of the neutron diffusion equation in three dimensional cylindrical coordinates. Coupling of the two modules was performed by mapping the solution variables from one module to the other. Mapping is performed automatically in the code system by the use of a common material mesh in both modules. The standalone validation of the thermal-hydraulics module was performed with several cases of the SANA experiment and the standalone thermal-hydraulics exercise of the PBMR-400 benchmark problem. The standalone neutronics module was validated by performing the relevant exercises of the PBMR-268 and PBMR-400 benchmark problems. Additionally, the validation of the coupled code system was performed by analyzing several steady state and transient cases of the OECD/NEA PBMR-400 benchmark problem.

  5. Effect of Temperature on Gas Hold—up in Aerated Stirred Tanks

    高正明; 施力田

    2003-01-01

    Gas holdups in ambient gassed and hot sparged systems with multiple modern impellers and the effect of temperature on gas holdup are reported,The operating temperature has a great impact on gas holdup though the gas dispersion regime in the hot sparged system is similar to the ambient gassed condition,The gas holdup under the elevated temperature and the ambient gassed operation is successfully correlated.With the sarme total gas flow rate and power input,the gas holdup in the hot sparged system(say near the boiling point)is only about half of that in the ambient system ,The results imply that almost all existing hot sparged reactors have been designed on the basis of incorrect estimates of the gas holdup during operation.

  6. The gas corrosion of the cobalt base clad layer at elevated temperature

    H. Smolenska

    2006-08-01

    Full Text Available Purpose: Purpose of this paper is to evaluate the microstructural and mechanical properties evolution of thelaser and PTA clad layers made of the powder containing cobalt after oxidation in air (750°C, 200 hours andcorrosion in exhaust gases (700°C, two month.Design/methodology/approach: The layers were made by cladding technique. Cladding was conducted witha high power diode laser HDPL ROFIN SINAR DL 020 and Plasma Transformed Arc method. The subsequenttracks were overlapped by 30÷40%. The performance of the hardfaced materials were evaluated by microstructure(optical and scanning electron microscope SEM, chemical analysis and micro hardness measurements.Findings: After heat treatment the microstructure of the clad layers did not change much, neither on the top partnor in the clad/steel interface. However the oxide layer on the surface is observed. The EDS analyze revile thecomposition of this scale which consisted generally of chromium and iron oxides. The semi-quantitative chemicalanalysis (EDS of the dendritic regions and micro regions confirms changes in chemical contents before and afteroxidation and after corrosion in exhaust gases. The oxidation at temperature 750°C for 200 hours in air and fortwo month in exhaust gases did not influence on the morphology of the clad layers neither on the top part nor inthe clad/steel interface. However changes in chemical composition were observed. On the surface of both sort ofclads the oxide layers were observed. These sorts of layers are resistant for the hot exhausted gases.Research limitations/implications: During the future research kinetic analyze of high temperature corrosionshould be done also for different temperature and times of the process.Practical implications: The layers were designed as a method to prolong service time for the ship engineexhausted valve.Originality/value: The chemical composition of the powder was new one. Also using the laser claddingtechnique for ship engine parts

  7. Gas-Liquid Mass Transfer Characteristics in a Gas-Liquid-Solid Bubble Column under Elevated Pressure and Temperature

    Haibo Jin; Suohe Yang; Guangxiang He; Delin Liu; Zemin Tong; Jianhua Zhu

    2014-01-01

    abstract The volumetric mass transfer coefficient kLa of gases (H2, CO, CO2) and mass transfer coefficient kL on liquid par-affin side were studied using the dynamic absorption method in slurry bubble column reactors under elevated temperature and elevated pressure. Meanwhile, gas-holdup and gas-liquid interfacial area a were obtained. The effects of temperature, pressure, superficial gas velocity and solid concentration on the mass transfer coeffi-cient were discussed. Experimental results show that the gas-liquid volumetric mass transfer coefficient kLa and interfacial area a increased with the increase of pressure, temperature, and superficial gas velocity, and decreased with the slurry concentration. The mass transfer coefficient kL increased with increasing superficial gas velocity and temperature and decreased with higher slurry concentration, while it changed slightly with pressure. Ac-cording to analysis of experimental data, an empirical correlation is obtained to calculate the values of kLa for H2 (CO, CO2) in the gas-paraffin-quartz system in a bubble column under elevated temperature and elevated pressure.

  8. An Annular Mechanical Temperature Compensation Structure for Gas-Sealed Capacitive Pressure Sensor

    Kohei Higuchi; Yonggang Jiang; Kazusuke Maenaka; Hidekuni Takao; Xiuchun Hao

    2012-01-01

    A novel gas-sealed capacitive pressure sensor with a temperature compensation structure is reported. The pressure sensor is sealed by Au-Au diffusion bonding under a nitrogen ambient with a pressure of 100 kPa and integrated with a platinum resistor-based temperature sensor for human activity monitoring applications. The capacitance-pressure and capacitance-temperature characteristics of the gas-sealed capacitive pressure sensor without temperature compensation structure are calculated. It is...

  9. Low-Temperature Photochemically Activated Amorphous Indium-Gallium-Zinc Oxide for Highly Stable Room-Temperature Gas Sensors.

    Jaisutti, Rawat; Kim, Jaeyoung; Park, Sung Kyu; Kim, Yong-Hoon

    2016-08-10

    We report on highly stable amorphous indium-gallium-zinc oxide (IGZO) gas sensors for ultraviolet (UV)-activated room-temperature detection of volatile organic compounds (VOCs). The IGZO sensors fabricated by a low-temperature photochemical activation process and exhibiting two orders higher photocurrent compared to conventional zinc oxide sensors, allowed high gas sensitivity against various VOCs even at room temperature. From a systematic analysis, it was found that by increasing the UV intensity, the gas sensitivity, response time, and recovery behavior of an IGZO sensor were strongly enhanced. In particular, under an UV intensity of 30 mW cm(-2), the IGZO sensor exhibited gas sensitivity, response time and recovery time of 37%, 37 and 53 s, respectively, against 750 ppm concentration of acetone gas. Moreover, the IGZO gas sensor had an excellent long-term stability showing around 6% variation in gas sensitivity over 70 days. These results strongly support a conclusion that a low-temperature solution-processed amorphous IGZO film can serve as a good candidate for room-temperature VOCs sensors for emerging wearable electronics. PMID:27430635

  10. Determination of an instability temperature for alloys in the cooling gas of a high temperature reactor

    High temperature alloys designed to be used for components in the primary circuit of a helium cooled high temperature nuclear reactor show massive CO production above a certain temperature, called the instability temperature T/sub i/, which increases with increasing partial pressure of CO in the cooling gas. At p/sub CO/ = 15 microbar, T/sub i/ lies between 900 and 950 degrees C for the four alloys under investigation: T/sub i/ is lowest for the iron base alloy Incoloy 800 H and increases for the nickel base alloys in the order Inconel 617, HDA 230 and Nimonic 86. Measurements of T/sub i/ made at 3 different laboratories were compared and shown to agree for p/sub CO/25 microbar, compatible with CO production by a reaction of Cr2O3 with carbides. Some measurements of T/sub i/ on HDA 230 and Nimonic 86 were performed in the course of simulated reactor disturbances. They showed that the oxide layer looses its protective properties above T/sub i/. A highlight of the examinations was the detection of eta-carbides (M6C) with unusual properties. M6C is the only type of carbide occuring in HDA 230. An eta-carbide with a lattice constant of 1088.8 pm had developed at the surface of Nimonic 86 during pre-oxidation before the disturbance simulation. Its composition is estimated at Ni3SiMo2C. Eta-carbides containing Si and especially eta-carbides with lattice constants as low as 1088.8 pm have been described only rarely until now. (author)

  11. Coated particle fuel for high temperature gas cooled reactors

    for process heat/hydrogen generation applications with 950 .deg. C outlet temperatures. There is a clear set of standards for modern high quality fuel in terms of low levels of heavy metal contamination, manufacture-induced particle defects during fuel body and fuel element making, irradiation/accident induced particle failures and limits on fission product release from intact particles. While gas-cooled reactor design is still open-ended with blocks for the prismatic and spherical fuel elements for the pebble-bed design, there is near worldwide agreement on high quality fuel: a 500 μm diameter UO2 kernel of 10% enrichment is surrounded by a 100 μm thick sacrificial buffer layer to be followed by a dense inner pyrocarbon layer, a high quality silicon carbide layer of 35 μm thickness and theoretical density and another outer pyrocarbon layer. Good performance has been demonstrated both under operational and under accident conditions, i.e. to 10% FIMA and maximum 1600 .deg. C afterwards. And it is the wide-ranging demonstration experience that makes this particle superior. Recommendations are made for further work: 1. Generation of data for presently manufactured materials, e.g. SiC strength and strength distribution, PyC creep and shrinkage and many more material data sets. 2. Renewed start of irradiation and accident testing of modern coated particle fuel. 3. Analysis of existing and newly created data with a view to demonstrate satisfactory performance at burnups beyond 10% FIMA and complete fission product retention even in accidents that go beyond 1600 .deg. C for a short period of time. This work should proceed at both national and international level

  12. Research on Diagnosis of Gas-Liquid Detonation Exhaust Based on Double Optical Path Absortion Spectroscopy Technique%基于双光路吸收光谱技术的气液两相爆轰燃气诊断技术研究

    吕晓静; 李宁; 翁春生

    2014-01-01

    The effect detection of detonation exhaust can provide measurement data for exploring the formation mechanism of detonation ,the promotion of detonation efficiency and the reduction of fuel waste .Based on tunable diode laser absorption spec-troscopy technique combined with double optical path cross-correlation algorithm ,the article raises the diagnosis method to real-ize the on-line testing of detonation exhaust velocity ,temperature and H2 O gas concentration .The double optical path testing system is designed and set up for the valveless pulse detonation engine with the diameter of 80 mm .By scanning H2 O absorption lines of 1343nm with a high frequency of 50 kHz ,the on-line detection of gas-liquid pulse detonation exhaust is realized .The re-sults show that the optical testing system based on tunable diode laser absorption spectroscopy technique can capture the detailed characteristics of pulse detonation exhaust in the transient process of detonation .The duration of single detonation is 85 ms un-der laboratory conditions ,among which supersonic injection time is 5.7 ms and subsonic injection time is 19.3 ms .The valveless pulse detonation engine used can work under frequency of 11 Hz .The velocity of detonation overflowing the detonation tube is 1 172 m · s-1 ,the maximum temperature of detonation exhaust near the nozzle is 2 412 K .There is a transitory platform in the velocity curve as well as the temperature curve .H2 O gas concentration changes between 0~7% during detonation under experi-mental conditions .The research can provide measurement data for the detonation process diagnosis and analysis ,which is of sig-nificance to advance the detonation mechanism research and promote the research of pulse detonation engine control technology .%对爆轰燃气准确有效地检测可以为探索爆轰形成机理以及提升爆轰发动机工作效率提供数据支撑。提出了基于可调谐半导体激光吸收光谱技术结合双光路互相关算法

  13. Heat exchanger performance in main cooling system on high temperature test operation at high temperature gas-cooled reactor 'HTTR'

    High Temperature Engineering Test Reactor (HTTR) of high temperature gas-cooled reactor at Japan Atomic Energy Research Institute achieved the reactor outlet coolant temperature of 950degC for the first time in the world at Apr.19, 2004. To remove generated heat at reactor core and to hold reactor inlet coolant temperature as specified temperature, heat exchangers in HTTR main cooling system should have designed heat exchange performance. In this report, heat exchanger performance is evaluated based on measurement data in high temperature test operation. And it is confirmed the adequacy of heat exchanger designing method by comparison of evaluated value with designed value. (author)

  14. Proliferation resistance assessment of high temperature gas reactors

    Chikamatsu N, M. A. [Instituto Tecnologico y de Estudios Superiores de Monterrey, Campus Santa Fe, Av. Carlos Lazo No. 100, Santa Fe, 01389 Mexico D. F. (Mexico); Puente E, F., E-mail: midori.chika@gmail.com [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico)

    2014-10-15

    The Generation IV International Forum has established different objectives for the new generation of reactors to accomplish. These objectives are focused on sustain ability, safety, economics and proliferation resistance. This paper is focused on how the proliferation resistance of the High Temperature Gas Reactors (HTGR) is assessed and the advantages that these reactors present currently. In this paper, the focus will be on explaining why such reactors, HTGR, can achieve the goals established by the GIF and can present a viable option in terms of proliferation resistance, which is an issue of great importance in the field of nuclear energy generation. The reason why the HTGR are being targeted in this writing is that these reactors are versatile, and present different options from modular reactors to reactors with the same size as the ones that are being operated today. Besides their versatility, the HTGR has designed features that might improve on the overall sustain ability of the nuclear reactors. This is because the type of safety features and materials that are used open up options for industrial processes to be carried out; cogeneration for instance. There is a small section that mentions how HTGR s are being developed in the international sector in order to present the current world view in this type of technology and the further developments that are being sought. For the proliferation resistance section, the focus is on both the intrinsic and the extrinsic features of the nuclear systems. The paper presents a comparison between the features of Light Water Reactors (LWR) and the HTGR in order to be able to properly compare the most used technology today and one that is gaining international interest. (Author)

  15. Gas Temperature and Radiative Heat Transfer in Oxy-fuel Flames

    Bäckström, Daniel; Johansson, Robert; Andersson, Klas;

    lower temperature than the suction pyrometer in the low velocity regions of the furnace, a difference which is likely to be an effect of the purge gas added in the optical probe. The measured temperature fluctuations were evaluated by modeling of the gas radiation. The influence from the measured...

  16. Effect of Air Temperature and Relative Humidity at Various Fuel-Air Ratios on Exhaust Emissions on a Per-Mode Basis of an AVCO Lycoming 0-320 Diad Light Aircraft Engine: Volume 1: Results and Plotted Data

    Skorobatckyi, M.; Cosgrove, D. V.; Meng, P. R.; Kempe, E. E., Jr.

    1978-01-01

    A carbureted four cylinder air cooled 0-320 DIAD Lycoming aircraft engine was tested to establish the effects of air temperature and humidity at various fuel-air ratios on the exhaust emissions on a per-mode basis. The test conditions include carburetor lean out at air temperatures of 50, 59, 80, and 100 F at relative humidities of 0, 30, 60, and 80 percent. Temperature humidity effects at the higher values of air temperature and relative humidity tested indicated that the HC and CO emissions increased significantly, while the NOx emissions decreased. Even at a fixed fuel air ratio, the HC emissions increase and the NOx emissions decrease at the higher values of air temperature and humidity.

  17. Effect of air temperature and relative humidity at various fuel-air ratios on exhaust emissions on a per-mode basis of an Avco Lycoming 0-320 DIAD light aircraft engine. Volume 2: Individual data points

    Skorobatckyi, M.; Cosgrove, D. V.; Meng, P. R.; Kempke, E. R.

    1976-01-01

    A carbureted four cylinder air cooled 0-320 DIAD Lycoming aircraft engine was tested to establish the effects of air temperature and humidity at various fuel-air ratios on the exhaust emissions on a per-mode basis. The test conditions included carburetor lean-out at air temperatures of 50, 59, 80, and 100 F at relative humidities of 0, 30, 60, and 80 percent. Temperature-humidity effects at the higher values of air temperature and relative humidity tested indicated that the HC and CO emissions increased significantly, while the NOx emissions decreased. Even at a fixed fuel-air ratio, the HC emissions increase and the NOx emissions decrease at the higher values of air temperature and humidity. Volume II contains the data taken at each of the individual test points.

  18. Organic acids emissions from natural-gas-fed engines

    Zervas, Efthimios; Tazerout, Mohand

    A natural-gas-fed spark-ignition engine, operating under lean conditions, is used for the study of the organic acids exhaust emissions. These pollutants are collected by passing a sample of exhaust gas into deionised water. The final solution is directly analysed by HPLC/UV at 204 nm. Only formic acid is emitted in detectable concentration under the experimental conditions used. Its concentration decreases with the three engine operating parameters studied: spark advance, volumetric efficiency and fuel/air equivalence ratio. Exhaust formic acid concentration is also linked with exhaust oxygen concentration and exhaust temperature. A comparison with other engines (SI engines fed with gasoline and compression ignition engines) from bibliographic data proves that natural-gas-fed engines emit less organic acids than the other two types of engines.

  19. Electron temperature and density measurement of tungsten inert gas arcs with Ar-He shielding gas mixture

    The diagnostics of atmospheric welding plasma is a well-established technology. In most cases the measurements are limited to processes using pure shielding gas. However in many applications shielding gas is a mixture of various components including metal vapor in gas metal arc welding (GMAW). Shielding gas mixtures are intentionally used for tungsten inert gas (TIG) welding in order to improve the welding performance. For example adding Helium to Argon shielding gas allows the weld geometry and porosity to be influenced. Yet thermal plasmas produced with gas mixtures or metal vapor still require further experimental investigation. In this work coherent Thomson scattering is used to measure electron temperature and density in these plasmas, since this technique allows independent measurements of electron and ion temperature. Here thermal plasmas generated by a TIG process with 50% Argon and 50% Helium shielding gas mixture have been investigated. Electron temperature and density measured by coherent Thomson scattering have been compared to the results of spectroscopic measurements of the plasma density using Stark broadening of the 696.5 nm Argon spectral line. Further investigations of MIG processes using Thomson scattering technique are planned

  20. THE INTEGRATION OF PROCESS HEAT APPLICATIONS TO HIGH TEMPERATURE GAS REACTORS

    Michael G. McKellar

    2011-11-01

    A high temperature gas reactor, HTGR, can produce industrial process steam, high-temperature heat-transfer gases, and/or electricity. In conventional industrial processes, these products are generated by the combustion of fossil fuels such as coal and natural gas, resulting in significant emissions of greenhouse gases such as carbon dioxide. Heat or electricity produced in an HTGR could be used to supply process heat or electricity to conventional processes without generating any greenhouse gases. Process heat from a reactor needs to be transported by a gas to the industrial process. Two such gases were considered in this study: helium and steam. For this analysis, it was assumed that steam was delivered at 17 MPa and 540 C and helium was delivered at 7 MPa and at a variety of temperatures. The temperature of the gas returning from the industrial process and going to the HTGR must be within certain temperature ranges to maintain the correct reactor inlet temperature for a particular reactor outlet temperature. The returning gas may be below the reactor inlet temperature, ROT, but not above. The optimal return temperature produces the maximum process heat gas flow rate. For steam, the delivered pressure sets an optimal reactor outlet temperature based on the condensation temperature of the steam. ROTs greater than 769.7 C produce no additional advantage for the production of steam.

  1. Functional Integral Approach to the Transition Temperature of Attractive Interacting Bose Gas in Traps

    HU Guang-Xi; DAI Xian-Xi

    2004-01-01

    The functional integral approach (FIA) is introduced to study the transition temperature of an imperfect Bose gas in traps.An interacting model in quantum statistical mechanics is presented.With the model we study a Bose gas with attractive interaction trapped in an external potential.We obtain the result that the transition temperature of a trapped Bose gas will slightly shift upwards owing to the attractive interacting force.Successful application of the FIA to Bose systems is demonstrated.

  2. Modeling of Aerobrake Ballute Stagnation Point Temperature and Heat Transfer to Inflation Gas

    Bahrami, Parviz A.

    2012-01-01

    A trailing Ballute drag device concept for spacecraft aerocapture is considered. A thermal model for calculation of the Ballute membrane temperature and the inflation gas temperature is developed. An algorithm capturing the most salient features of the concept is implemented. In conjunction with the thermal model, trajectory calculations for two candidate missions, Titan Explorer and Neptune Orbiter missions, are used to estimate the stagnation point temperature and the inflation gas temperature. Radiation from both sides of the membrane at the stagnation point and conduction to the inflating gas is included. The results showed that the radiation from the membrane and to a much lesser extent conduction to the inflating gas, are likely to be the controlling heat transfer mechanisms and that the increase in gas temperature due to aerodynamic heating is of secondary importance.

  3. Exhaustion from prolonged gambling

    Fatimah Lateef

    2013-01-01

    Complaints of fatigue and physical exhaustion are frequently seen in the acute medical setting, especially amongst athletes, army recruits and persons involved in strenuous and exertional physical activities.Stress-induced exhaustion, on the other hand, is less often seen, but can present with very similar symptoms to physical exhaustion.Recently, three patients were seen at theDepartment ofEmergencyMedicine, presenting with exhaustion from prolonged involvement in gambling activities.The cases serve to highlight some of the physical consequences of prolonged gambling.

  4. Scaling Studies for High Temperature Test Facility and Modular High Temperature Gas-Cooled Reactor

    Richard R. Schult; Paul D. Bayless; Richard W. Johnson; James R. Wolf; Brian Woods

    2012-02-01

    The Oregon State University (OSU) High Temperature Test Facility (HTTF) is an integral experimental facility that will be constructed on the OSU campus in Corvallis, Oregon. The HTTF project was initiated, by the U.S. Nuclear Regulatory Commission (NRC), on September 5, 2008 as Task 4 of the 5-year High Temperature Gas Reactor Cooperative Agreement via NRC Contract 04-08-138. Until August, 2010, when a DOE contract was initiated to fund additional capabilities for the HTTF project, all of the funding support for the HTTF was provided by the NRC via their cooperative agreement. The U.S. Department of Energy (DOE) began their involvement with the HTTF project in late 2009 via the Next Generation Nuclear Plant (NGNP) project. Because the NRC's interests in HTTF experiments were only centered on the depressurized conduction cooldown (DCC) scenario, NGNP involvement focused on expanding the experimental envelope of the HTTF to include steady-state operations and also the pressurized conduction cooldown (PCC).

  5. Effects of fuel properties and oxidation catalyst on diesel exhaust emissions; Keiyu seijo oyobi sanka shokubai no diesel haishutsu gas eno eikyo

    Aihara, S.; Morihisa, H.; Tamanouchi, M.; Araki, H.; Yamada, S. [Petroleum Energy Center, Advanced Technology and Research Institute, Tokyo (Japan)

    1997-10-01

    Effects of fuel properties (T90 and Poly-Aromatic Hydrocarbons: PAH) and oxidation catalyst on diesel exhaust emissions were studied using three DI diesel engines and two diesel passenger cars. (IDI engine) PM emissions were found to increase as T90 and PAH increased and could be decreased considerably for each fuel if an oxidation catalyst was installed. 5 refs., 9 figs., 3 tabs.

  6. Effects of gasoline properties on exhaust emission and photochemical reactivity; Gasoline seijo ga haiki gas sosei, kokagaku hannosei ni oyobosu eikyo

    Kumagai, R.; Usui, K.; Moriya, A.; Sato, M.; Nomura, T.; Sue, H. [Petroleum Energy Center, Advanced Technology and Research Institute, Tokyo (Japan)

    1997-10-01

    In order to investigate the effects of fuel properties on emissions, four passenger cars were tested under Japanese 11 and 10-15 modes using two series gasoline fuels. The test results suggest that the distillation property (T90) affects A/F ratio which in turn influences exhaust emissions. The results of regression analysis show that both ozone forming potential and air toxics are highly corrected with the composition of aromatic hydrocarbons in gasoline. 3 refs., 10 figs., 6 tabs.

  7. Effect of hydrogen-diesel fuel co-combustion on exhaust emissions with verification using an in-cylinder gas sampling technique

    Talibi, M.; P. Hellier; Balachandran, R; Ladommatos, N.

    2014-01-01

    The paper presents an experimental investigation of hydrogen-diesel fuel co-combustion carried out on a naturally aspirated, direct injection diesel engine. The engine was supplied with a range of hydrogen-diesel fuel mixture proportions to study the effect of hydrogen addition (aspirated with the intake air) on combustion and exhaust emissions. The tests were performed at fixed diesel injection periods, with hydrogen added to vary the engine load between 0 and 6 bar IMEP. In addition, a nove...

  8. The effect of metal salts on quantification of elemental and organic carbon in diesel exhaust particles using thermal-optical evolved gas analysis

    Y. Wang

    2010-07-01

    Full Text Available Thermal-optical evolved gas analysis (TOEGA is a conventional method for classifying carbonaceous aerosols as organic carbon (OC and elemental carbon (EC. Its main source of uncertainty arises from accounting for pyrolyzed OC (char, which has similar behavior to the EC originally present on the filter. Sample composition can also cause error, at least partly by complicating the charred carbon correction. In this study, lab generated metal salt particles, including alkali (NaCl, KCl, Na2SO4, alkaline-earth (MgCl2, CaCl2 and transition metal salts (CuCl2, FeCl2, FeCl3, CuCl, ZnCl2, MnCl2, CuSO4, Fe2(SO43, were deposited on a layer of diesel particles to investigate their effect on EC and OC quantification with TOEGA. Measurements show that metals reduce the oxidation temperature of EC and enhance the charring of OC. The split point used to determine classification of EC vs. OC is more dependent on changes in EC oxidation temperature than it was on charring. The resulting EC/OC ratio is reduced by 0–80% in the presence of most of the salts, although some metal salts increased reported EC/OC at low metal to carbon ratios. In general, transition metals are more active than alkali and alkaline-earth metals; copper is the most active. Copper and iron chlorides are more active than sulfates. The melting point of metal salts is strongly correlated with the increase of OC charring, but not with the reduction of EC oxidation temperature. Other chemistry, such as redox reactions, may affect the EC oxidation. A brief discussion of possible catalytic mechanisms for the metals is provided.

  9. Catalytic converter heating by reversible chemical reaction of CaO/Ca(OH)2. Simulation study of exhaust emission reduction with prototype heater; CaO/Ca(OH)2 kagyaku hannonetsu ni yoru sangen shokubai kanetsu hoshiki no kento. Prototype sochi no haishutsu gas joka seino simulation

    Katashiba, H.; Kimura, H. [Mitsubishi Electric Corp., Tokyo (Japan); Morita, S. [Osaka City University, Osaka (Japan). Faculty of Engineering

    1998-07-25

    Rapid activation of three-way catalyst is very effective to reduce harmful substances in exhaust gas. For heating the catalyst of a car, feasibility study of CaO/Ca(OH)2 reversible exothermic reaction has been done. In this paper, experimental results of prototype heater with exothermic hydration and dehydration reaction are described. Furthermore, the performance of exhaust emission reduction with the prototype heater and Ca(OH)2 dehydration are estimated by simulation study. It is predicted that the prototype heater reduces unburned exhaust emission by 37% in LA-4 test cycle simulation. 6 refs., 5 figs.

  10. Control Technology of Exhaust Gas Emission from Marine Diesel Engine%船用柴油机有害物排放控制技术

    庞海龙; 邓成林; 姚广涛; 资新运; 卜建国; 陈超

    2011-01-01

    This paper introduced the actual situation of atmospheric pollution caused by exhaust emission from marine diesel engines and expounded the regulations made by IMO for controlling exhaust emissions. And then, it summarized current methods to reduce SOx, NOx and PM in the exhaust gases. Finally, it pointed that the combination application of various technologies is the main development tendency of the emission reduction for marine diesel engine in the future.%介绍船舶柴油机排气对大气污染的现状及国际海事组织对船舶柴油机排放的控制法规;归纳总结了目前降低船舶柴油机氮氧化物、硫氧化物和颗粒物排放的主要技术措施,提出了多种技术综合运用是今后船舶柴油机减排发展必然趋势.

  11. TRISO-Coated Fuel Processing to Support High Temperature Gas-Cooled Reactors

    Del Cul, G.D.

    2002-10-01

    The initial objective of the work described herein was to identify potential methods and technologies needed to disassemble and dissolve graphite-encapsulated, ceramic-coated gas-cooled-reactor spent fuels so that the oxide fuel components can be separated by means of chemical processing. The purpose of this processing is to recover (1) unburned fuel for recycle, (2) long-lived actinides and fission products for transmutation, and (3) other fission products for disposal in acceptable waste forms. Follow-on objectives were to identify and select the most promising candidate flow sheets for experimental evaluation and demonstration and to address the needs to reduce technical risks of the selected technologies. High-temperature gas-cooled reactors (HTGRs) may be deployed in the next -20 years to (1) enable the use of highly efficient gas turbines for producing electricity and (2) provide high-temperature process heat for use in chemical processes, such as the production of hydrogen for use as clean-burning transportation fuel. Also, HTGR fuels are capable of significantly higher burn-up than light-water-reactor (LWR) fuels or fast-reactor (FR) fuels; thus, the HTGR fuels can be used efficiently for transmutation of fissile materials and long-lived actinides and fission products, thereby reducing the inventory of such hazardous and proliferation-prone materials. The ''deep-burn'' concept, described in this report, is an example of this capability. Processing of spent graphite-encapsulated, ceramic-coated fuels presents challenges different from those of processing spent LWR fuels. LWR fuels are processed commercially in Europe and Japan; however, similar infrastructure is not available for processing of the HTGR fuels. Laboratory studies on the processing of HTGR fuels were performed in the United States in the 1960s and 1970s, but no engineering-scale processes were demonstrated. Currently, new regulations concerning emissions will impact the

  12. Condensation Dripping Water Detection and Its Control Method from Exhaust Pipe of Gasohol Vehicle under Low Environmental Temperature Conditions: A Case Study in Harbin, China

    Guangdong Tian; Tiangang Qiang; Jiangwei Chu; Guangming Qiao

    2012-01-01

    Gasohol is one of renewable clean alternative energies, which is widely used around the world. Gasohol had been raised to be used in 9 provinces of China since 2001. However, its closed use was merely promoted in Heilongjiang province since November 1, 2004. Moreover, this issue aroused extensive discussions and controversies. One of them is the condensation dripping water issue from exhaust pipe in cold winter. Does the ethanol cause the road freezing in cold winter? To deal with this issue,...

  13. Capture efficiency measurement of pollutants over a workbench with the reinforced slot exhaust system

    Pavelek M.

    2013-04-01

    Full Text Available The paper deals with the measurement of the capture efficiency of pollutants by the slot reinforced exhaust system situated in two positions over the workbench. The slot reinforced exhaust system, which is known as REEXS, is the traditional slot exhaust hood equipped with an air supply inlet that intensifies exhausting along the axis of the exhaust hood. It can operate in traditional or reinforced exhaust modes. Measurements were made for the same air velocity in the suction slot and with the different momentum flux ratio of supplied and exhausted air flow. The tracer gas method was used for the capture efficiency measurement of the system. As the tracer gas the carbon dioxide was chosen. The knowledge of the shape and range of the effective exhaust area for various configurations in front of the exhaust hood is important for the exhaust hood setting according to a source of pollutants.

  14. Performance Analysis of a Reciprocating Piston Expander and a Plate Type Exhaust Gas Recirculation Boiler in a Water-Based Rankine Cycle for Heat Recovery from a Heavy Duty Diesel Engine

    Gunnar Latz

    2016-06-01

    Full Text Available The exhaust gas in an internal combustion engine provides favorable conditions for a waste-heat recovery (WHR system. The highest potential is achieved by the Rankine cycle as a heat recovery technology. There are only few experimental studies that investigate full-scale systems using water-based working fluids and their effects on the performance and operation of a Rankine cycle heat recovery system. This paper discusses experimental results and practical challenges with a WHR system when utilizing heat from the exhaust gas recirculation system of a truck engine. The results showed that the boiler’s pinch point necessitated trade-offs between maintaining adequate boiling pressure while achieving acceptable cooling of the EGR and superheating of the water. The expander used in the system had a geometric compression ratio of 21 together with a steam outlet timing that caused high re-compression. Inlet pressures of up to 30 bar were therefore required for a stable expander power output. Such high pressures increased the pump power, and reduced the EGR cooling in the boiler because of pinch-point effects. Simulations indicated that reducing the expander’s compression ratio from 21 to 13 would allow 30% lower steam supply pressures without adversely affecting the expander’s power output.

  15. Exhaust Structure Influence on Gas Flow Distribution in PSC-1O0 Guide Vane Cyclone Tube%排气结构对PSC-100型导叶式旋风管内流场分布的影响

    王建军; 许文文; 金有海

    2011-01-01

    采用五孔球探针测量了不同排气结构参数(导流锥下口直径d1、开缝面积比a和开缝位置)的改变对PSC-100型导叶式旋风管内总压降和流场的影响.试验结果表明:带有导流锥的排气结构对分离有利;导流锥下口直径增大,气流旋转强度减小,颗粒分离所需离心力场减弱;导流锥开缝面积越大,分离空间内气旋强度越低;导流锥上侧缝开缝部位对旋风管内流场分布亦有影响.%By means of the intelligent five-hole pitot tube, the exhaust structure influence from the lower port d1 , the slotted area ratio a and the slotted position on the flow field distribution were investigated. Experimental results show that, an exhaust structure with diversion cone benefits centrifugal separation; with the enlargement of lower port d1 , the gas rotation intensity slows down and the centrifugal force to particle separation decreases; the gas rotation intensity slows down with the reduce of slotted area. The slotted position also influences flow field distribution.

  16. High Temperature Gas Cooled Reactor Fuels and Materials

    At the third annual meeting of the technical working group on Nuclear Fuel Cycle Options and Spent Fuel Management (TWG-NFCO), held in Vienna, in 2004, it was suggested 'to develop manuals/handbooks and best practice documents for use in training and education in coated particle fuel technology' in the IAEA's Programme for the year 2006-2007. In the context of supporting interested Member States, the activity to develop a handbook for use in the 'education and training' of a new generation of scientists and engineers on coated particle fuel technology was undertaken. To make aware of the role of nuclear science education and training in all Member States to enhance their capacity to develop innovative technologies for sustainable nuclear energy is of paramount importance to the IAEA Significant efforts are underway in several Member States to develop high temperature gas cooled reactors (HTGR) based on either pebble bed or prismatic designs. All these reactors are primarily fuelled by TRISO (tri iso-structural) coated particles. The aim however is to build future nuclear fuel cycles in concert with the aim of the Generation IV International Forum and includes nuclear reactor applications for process heat, hydrogen production and electricity generation. Moreover, developmental work is ongoing and focuses on the burning of weapon-grade plutonium including civil plutonium and other transuranic elements using the 'deep-burn concept' or 'inert matrix fuels', especially in HTGR systems in the form of coated particle fuels. The document will serve as the primary resource materials for 'education and training' in the area of advanced fuels forming the building blocks for future development in the interested Member States. This document broadly covers several aspects of coated particle fuel technology, namely: manufacture of coated particles, compacts and elements; design-basis; quality assurance/quality control and characterization techniques; fuel irradiations; fuel

  17. Developments in advanced high temperature disc and blade materials for aero-engine gas turbine applications

    Everitt, S

    2012-01-01

    The research carried out as part of this EngD is aimed at understanding the high temperature materials used in modern gas turbine applications and providing QinetiQ with the information required to assess component performance in new propulsion systems. Performance gains are achieved through increased turbine gas temperatures which lead to hotter turbine disc rims and blades. The work has focussed on two key areas: (1) Disc Alloy Assessment of High Temperature Properties; and (2) Thermal Barr...

  18. A novel nuclear combined power and cooling system integrating high temperature gas-cooled reactor with ammonia–water cycle

    Highlights: • We propose a novel nuclear ammonia–water power and cooling cogeneration system. • The high temperature reactor is inherently safe, with exhaust heat fully recovered. • The thermal performances are improved compared with nuclear combined cycle. • The base case attains an energy efficiency of 69.9% and exergy efficiency of 72.5%. • Energy conservation and emission reduction are achieved in this cogeneration way. - Abstract: A nuclear ammonia–water power and refrigeration cogeneration system (NAPR) has been proposed and analyzed in this paper. It consists of a closed high temperature gas-cooled reactor (HTGR) topping Brayton cycle and a modified ammonia water power/refrigeration combined bottoming cycle (APR). The HTGR is an inherently safe reactor, and thus could be stable, flexible and suitable for various energy supply situation, and its exhaust heat is fully recovered by the mixture of ammonia and water in the bottoming cycle. To reduce exergy losses and enhance outputs, the ammonia concentrations of the bottoming cycle working fluid are optimized in both power and refrigeration processes. With the HTGR of 200 MW thermal capacity and 900 °C/70 bar reactor-core-outlet helium, the system achieves 88.8 MW net electrical output and 9.27 MW refrigeration capacity, and also attains an energy efficiency of 69.9% and exergy efficiency of 72.5%, which are higher by 5.3%-points and 2.6%-points as compared with the nuclear combined cycle (NCC, like a conventional gas/steam power-only combined cycle while the topping cycle is a closed HTGR Brayton cycle) with the same nuclear energy input. Compared with conventional separate power and refrigeration generation systems, the fossil fuel saving (based on CH4) and CO2 emission reduction of base-case NAPR could reach ∼9.66 × 104 t/y and ∼26.6 × 104 t/y, respectively. The system integration accomplishes the safe and high-efficiency utilization of nuclear energy by power and refrigeration

  19. Immune Exhaustion and Transplantation.

    Sanchez-Fueyo, A; Markmann, J F

    2016-07-01

    Exhaustion of lymphocyte function through chronic exposure to a high load of foreign antigen is well established for chronic viral infection and antitumor immunity and has been found to be associated with a distinct molecular program and characteristic cell surface phenotype. Although exhaustion has most commonly been studied in the context of CD8 viral responses, recent studies indicate that chronic antigen exposure may affect B cells, NK cells and CD4 T cells in a parallel manner. Limited information is available regarding the extent of lymphocyte exhaustion development in the transplant setting and its impact on anti-graft alloreactivity. By analogy to the persistence of a foreign virus, the large mass of alloantigen presented by an allograft in chronic residence could provide an ideal setting for exhausting donor-reactive T cells. The extent of T cell exhaustion occurring with various allografts, the kinetics of its development, whether exhaustion is influenced positively or negatively by different immunosuppressants, and the impact of exhaustion on graft survival and tolerance development remains a fertile area for investigation. Harnessing or encouraging the natural processes of exhaustion may provide a novel means to promote graft survival and transplantation tolerance. PMID:26729653

  20. Duplex tab exhaust nozzle

    Gutmark, Ephraim Jeff (Inventor); Martens, Steven (nmn) (Inventor)

    2012-01-01

    An exhaust nozzle includes a conical duct terminating in an annular outlet. A row of vortex generating duplex tabs are mounted in the outlet. The tabs have compound radial and circumferential aft inclination inside the outlet for generating streamwise vortices for attenuating exhaust noise while reducing performance loss.

  1. Local Exhaust Ventilation

    Madsen, Ulla; Breum, N. O.; Nielsen, Peter V.

    Capture efficiency of a local exhaust system, e.g. a kitchen hood, should include only contaminants being direct captured. In this study basic concepts of local exhaust capture efficiency are given, based on the idea of a control box. A validated numerical model is used for estimation of the...

  2. Heat Recovery From Tail Gas Incineration To Generate Power

    Tawfik, Tarek

    2010-09-15

    Many industrial processes result in tail gas wastes that must be flared or incinerated to abide with environmental guidelines. Tail gas incineration occurs in several chemical processes resulting in high-temperature exhaust gas that simply go to the stack, thus wasting all that valuable heat! This paper discusses useful heat recovery and electric power generation utilizing available heat in exhaust gas from tail gas incinerators. This heat will be recovered in a waste-heat recovery boiler that will produce superheated steam to expand in a steam turbine to generate power. A detailed cost estimate is presented.

  3. Analysis Of A High Temperature Gas-Cooled Reactor Powered High Temperature Electrolysis Hydrogen Plant

    An updated reference design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production has been developed. The HTE plant is powered by a high-temperature gas-cooled reactor (HTGR) whose configuration and operating conditions are based on the latest design parameters planned for the Next Generation Nuclear Plant (NGNP). The current HTGR reference design specifies a reactor power of 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 322 C and 750 C, respectively. The reactor heat is used to produce heat and electric power to the HTE plant. A Rankine steam cycle with a power conversion efficiency of 44.4% was used to provide the electric power. The electrolysis unit used to produce hydrogen includes 1.1 million cells with a per-cell active area of 225 cm2. The reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes a steam-sweep system to remove the excess oxygen that is evolved on the anode (oxygen) side of the electrolyzer. The overall system thermal-to-hydrogen production efficiency (based on the higher heating value of the produced hydrogen) is 42.8% at a hydrogen production rate of 1.85 kg/s (66 million SCFD) and an oxygen production rate of 14.6 kg/s (33 million SCFD). An economic analysis of this plant was performed with realistic financial and cost estimating The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a competitive cost. A cost of $3.03/kg of hydrogen was calculated assuming an internal rate of return of 10% and a debt to equity ratio of 80%/20% for a reactor cost of $2000/kWt and $2.41/kg of hydrogen for a reactor cost of $1400/kWt.

  4. Temperature induced decay of persistent currents in superfluid ultracold gas

    Kumar, Avinash; Jendrzejewski, Fred; Campbell, Gretchen K

    2016-01-01

    We study how temperature affects the lifetime of a quantized, persistent current state in a toroidal Bose-Einstein condensate (BEC). When the temperature is increased, we find a decrease in the persistent current lifetime. Comparing our measured decay rates to simple models of thermal activation and quantum tunneling, we do not find agreement. The measured critical velocity is also found to depend strongly on temperature, approaching the zero temperature mean-field solution as the temperature is decreased. This indicates that an appropriate definition of critical velocity must incorporate the role of thermal fluctuations, something not explicitly contained in traditional theories.

  5. Analysis of passive residual heat removal system of modular high temperature gas-cooled reactor

    The passive residual heat removal system plays an important role for the inherent safety of high temperature gas-cooled reactor (HTGR). The thermal hydraulic calculation method for the residual heat removal system of HTGR was introduced. The operating temperatures of the residual heat removal system at different residual heat powers and different environmental temperatures were calculated. The containment concrete temperature was numerically simulated. The results show that the highest concrete temperature is acceptable. (authors)

  6. Influence of the Gas Mixture Ratio on the Correlations Between the Excimer XeCl* Emission and the Sealed Gas Temperature in Dielectric Barrier Discharge Lamps

    徐金洲; 梁荣庆; 任兆杏

    2002-01-01

    For dielectric barrier discharge lamps filled with various gas mixture ratios, the correlations between the excimer XeCl* emission and the sealed gas temperature have been founded, and a qualitative explication is presented. For gas mixture with chlorine larger than 3%, the emission intensity increases with the sealed gas temperature, while with chlorine about 2%, the emission intensity decreases with the increase in the gas temperature, and could be improved by cooling water. However, if chlorine is less than 1.5%, the discharge appears to be a mixture mode with filaments distributed in a diffused glow-like discharge, and the UV emission is independent on the gas temperature.

  7. Influence of the gas mixture radio on the correlations between the excimer XeCl emission and the sealed gas temperature in dielectric barrier discharge lamps

    Xu Jin Zhou; Ren Zhao Xing

    2002-01-01

    For dielectric barrier discharge lamps filled with various gas mixture ratios, the correlations between the excimer XeCl emission and the sealed gas temperature have been founded, and a qualitative explication is presented. For gas mixture with chlorine larger than 3%, the emission intensity increases with the sealed gas temperature, while with chlorine about 2%, the emission intensity decreases with the increasing in the gas temperature, and could be improved by cooling water. However, if chlorine is less than 1.5%, the discharge appears to be a mixture mode with filaments distributed in a diffused glow-like discharge, and the UV emission is independent on the gas temperature

  8. Numerical study of particle deposition and scaling in dust exhaust of cyclone separator

    Xu, W. W.; Li, Q.; Zhao, Y. L.; Wang, J. J.; Jin, Y. H.

    2016-05-01

    The solid particles accumulation in the dust exhaust cone area of the cyclone separator can cause the wall wear. This undoubtedly prevents the flue gas turbine from long period and safe operation. So it is important to study the mechanism how the particles deposited and scale on dust exhaust cone area of the cyclone separator. Numerical simulations of gas-solid flow field have been carried out in a single tube in the third cyclone separator. The three-dimensionally coupled computational fluid dynamic (CFD) technology and the modified Discrete Phase Model (DPM) are adopted to model the gas-solid two-phase flow. The results show that with the increase of the operating temperature and processing capacity, the particle sticking possibility near the cone area will rise. The sticking rates will decrease when the particle diameter becomes bigger.

  9. Recovery of Exhaust Waste Heat for ICE Using the Beta Type Stirling Engine

    Wail Aladayleh

    2015-01-01

    Full Text Available This paper investigates the potential of utilizing the exhaust waste heat using an integrated mechanical device with internal combustion engine for the automobiles to increase the fuel economy, the useful power, and the environment safety. One of the ways of utilizing waste heat is to use a Stirling engine. A Stirling engine requires only an external heat source as wasted heat for its operation. Because the exhaust gas temperature may reach 200 to 700°C, Stirling engine will work effectively. The indication work, real shaft power and specific fuel consumption for Stirling engine, and the exhaust power losses for IC engine are calculated. The study shows the availability and possibility of recovery of the waste heat from internal combustion engine using Stirling engine.

  10. Analysis of characteristics of different working fluids for gas turbine cycle with high temperature gas-cooled reactor

    Gas turbine cycle with high temperature gas-cooled reactor is the main direction of nuclear energy generation, which is with the advantages in terms of the safety and economy. The thermal and physical properties of helium, nitrogen, carbon dioxide and the mixtures were compared and analyzed in this paper. Further more, the heat transfer coefficient, pressure loss and the stage number of turbo-machines have been also compared. Results indicate that taking the mixture of helium and carbon dioxide as the working fluid of gas turbine cycle with high temperature gas-cooled reactor can not only improve the heat transfer coefficient and decrease the stage number of turbo-machinery, but also can limit the pressure loss to a certain level. (authors)

  11. The Fort St. Vrain high temperature gas-cooled reactor. Pt. 10

    In October 1977, during the rise to power test program, the Fort St. Vrain high temperature gas-cooled reactor experienced the first of 37 fluctuation events involving primary coolant outlet temperature, nuclear detector signals, steam generator module gas inlet temperature and steam generator module main and reheat steam temperatures. In a 3 year investigation it was determined that the apparent cause of the fluctuations was movements of core components accompanied by periodic changes in bypass flows and crossflows of primary coolant helium. Installation of region constraint devices has eliminated fluctuations, but a single small primary coolant helium core outlet temperature redistribution is experienced routinely during rise to power. (orig.)

  12. Gas-cooled high temperature reactor with a coolant gas circuit subdivided into several loops

    In the annulus between liner and side reflector horizontal penetrations open up in which the hot-gas pipes run coaxially. For isolating these loops inflatable sealing bellows, and inflatable sealing balloons are introduced through construction openings, each sealing bellows isolating the gap between penetration and hot-gas pipe and the sealing balloon isolating the hot-gas pipe itself. (RW)

  13. Prediction of auto-ignition temperatures and delays for gas turbine applications

    Bounaceur, Roda; Glaude, Pierre-Alexandre; Sirjean, Baptiste; Fournet, René; Montagne, Pierre; Vierling, Matthieu; Moliere, Michel

    2015-01-01

    Gas turbines burn a large variety of gaseous fuels under elevated pressure and temperature conditions. During transient operations, variable gas/air mixtures are involved in the gas piping system. In order to predict the risk of auto-ignition events and ensure a safe operation of gas turbines, it is of the essence to know the lowest temperature at which spontaneous ignition of fuels may happen. Experimental auto-ignition data of hydrocarbon-air mixtures at elevated pressures are scarce and of...

  14. Development of data logger for atmospheric pressure, temperature and relative humidity for gas-filled detector

    At IoP-NISER an initiative has been taken to build and test micro-pattern gas detector such as Gas Electron Multiplier (GEM) for several upcoming High-Energy Physics (HEP) experiment projects. Temperature (t), atmospheric pressure (p) and relative humidity (RH) monitor and recording is very important for gas filled detector development. A data logger to monitor and record the ambient parameters such as temperature, relative humidity and pressure has been developed. With this data logger continuous recording of t, p, RH and time stamp can be done with a programmable sampling interval. This data is necessary to correct the gain of a gas filled detector

  15. Transient fission gas release from UO2 fuel for high temperature and high burnup

    In the present paper it is assumed that the fission gas release kinetics from an irradiated UO2 fuel for high temperature is determined by the kinetics of grain growth. A well founded assumption that Vitanza curve describes the change of uranium dioxide re-crystallization temperature and the experimental results referring to the limiting grain size presented in the literature are used to modify the grain growth model. Algorithms of fission gas release due to re-crystallization of uranium dioxide grains are worked out. The defect trap model of fission gas behaviour described in the earlier papers is supplemented with the algorithms. Calculations of fission gas release in function of time, temperature, burn-up and initial grain sizes are obtained. Computation of transient fission gas release in the paper is limited to the case where steady state of irradiation to accumulate a desired burn-up is performed below the temperature of re-crystallization then the subsequent step temperature increase follows. There are considered two kinds of step temperature increase for different burn-up: the final temperature of the step increase is below and above the re-crystallization temperature. Calculations show that bursts of fission gas are predicted in both kinds. The release rate of gas liberated for the final temperature above the re-crystallization temperature is much higher than for final temperature below the re-crystallization temperature. The time required for the burst to subside is longer due to grain growth than due to diffusion of bubbles and knock-out release. The theoretical results explain qualitatively the experimental data but some of them need to be verified since this sort of experimental data are not found in the available literature. (author)

  16. SiC based MOSFET transistors for high temperature industrial gas sensing applications

    Lloyd Spetz, Anita

    2000-03-01

    Field effect sensors based on silicon carbide have been demonstrated for industrial applications at high temperatures and in rough environments. Metal insulator silicon carbide, MISiC, Schottky diode devices as well as FET transistor devices that can be operated up to 700°C are presented. For high operation temperatures the sensors respond within milliseconds to a change between an oxidizing and reducing atmosphere, and cylinder specific monitoring of a combustion engine has been demonstrated. Changing the temperature and the type of gate metal gives sensors with diverse response patterns to different components in e.g. exhaust gases and flue gases. Sensor devices operating around 300°C with some selectivity to nitric oxide in synthetic diesel exhaust gases are presented. At a higher temperature, about 500°C, some selectivity to HC is found in synthetic petrol exhausts. Boilers of the size 0.5 - 5 MW constitute a potential market for combustion monitoring sensors. We have demonstrated MISiC devices with high selectivity to carbon monoxide in flue gases. References: Fast responding air/fuel sensor for individual cylinder control, A. Baranzahi, P. Tobias, A. Lloyd Spetz, I Lundström, P. Mårtensson, M. Glavmo, A. Göras, J. Nytomt, P. Salomonsson, and H. Larsson, SAE Technical Paper Series 972940, Combustion and Emisson Formation in SI Engines, (SP-1300) (1997) 231-240. MISiC Schottky Diodes as NOx sensors in simulated exhausts, H. Svenningstorp, P. Tobias, C. Wijk, I. Lundström, P. Salomonsson, L.-G. Ekedahl, and A. Lloyd Spetz, proc. Eurosensors XIII, The Hague, The Netherlands, September 12-15, pp. 501-504, 1999. Measurements with MISiC and MOS sensors in flue gases, L. Unéus, P. Ljung, M. Mattsson, P. Mårtenssson, R. Wigren, P. Tobias, I. Lundström, L-G. Ekedahl and A. Lloyd Spetz, proc. Eurosensors XIII, The Hague, The Netherlands, September 12-15, pp. 521-524, 1999.

  17. Hydrostatic gas distributions: global estimates of temperature and abundance

    Ciotti, L.; Pellegrini, S

    2008-01-01

    Estimating the temperature and metal abundance of the intracluster and the intragroup media is crucial to determine their global metal content and to determine fundamental cosmological parameters. When a spatially resolved temperature or abundance profile cannot be recovered from observations (e.g., for distant objects), or deprojection is difficult (e.g., due to a significant non-spherical shape), only global average temperature and abundance are derived. After introducing a general techniqu...

  18. High Temperature Gas-cooled Reactor Projected Markets and Scoping Economics

    Larry Demick

    2010-08-01

    The NGNP Project has the objective of developing the high temperature gas-cooled reactor (HTGR) technology to supply high temperature process heat to industrial processes as a substitute for burning of fossil fuels, such as natural gas. Applications of the HTGR technology that have been evaluated by the NGNP Project for supply of process heat include supply of electricity, steam and high-temperature gas to a wide range of industrial processes, and production of hydrogen and oxygen for use in petrochemical, refining, coal to liquid fuels, chemical, and fertilizer plants.

  19. Coupled model of deformation and gas flow process with temperature and slippage effect

    Chunhui ZHANG

    2015-06-01

    Full Text Available The effects of temperature, slippage effect and effective stress of coal on the coupled mechanism of deformation and gas glow are key issues to control coal and gas outburst and design the methane recovery engineering. Firstly, intact coal from Huaxing mine in Jilin Province is crushed and coal briquette specimen are made. Then the tri-axial coupled test setup of the deformation, gas flow and temperature developed by ourselves is adopted to investigate the effects of pore pressure, effective stress and temperature on the permeability of coal briquette specimen. The results show that: 1 Under the condition of low pore pressure, the permeability first reduces with pore pressure increasing, then at a threshold of pore pressure it rises with pore pressure increasing, which is called “slippage effect”. 2 The effective confining stress significantly influences the permeability. With increasing effective confining stress, the space of pores and cracks are compressed and the permeability reduces. 3 The temperature significantly influences the permeability and the permeability decreases with temperature increasing. The main reason is that the space of pores and cracks is compressed due to the temperature stress. Because of the constraint around, temperature compressive stress appears in internal coal samples. Coal pore and fracture space is compressed, and the sample permeability decreases. Besides, the viscosity of gas increases with temperature increasing. It decreases the trend of coal permeability . The temperature influence on coal permeability approximates to linear relationship. 4 The empirical permeability evolution equation with varying temperature, effective stress and slippage effects is presented. The coal is viewed as elastic medium, combined with effective stress principle and the empirical permeability equation, the coupled model of deformation and gas flow with varying temperature and slippage effects is built. Furthermore, the code

  20. Impact of compression on gas transport in non-woven gas diffusion layers of high temperature polymer electrolyte fuel cells

    Froning, Dieter; Yu, Junliang; Gaiselmann, Gerd; Reimer, Uwe; Manke, Ingo; Schmidt, Volker; Lehnert, Werner

    2016-06-01

    Gas transport in non-woven gas diffusion layers of a high-temperature polymer electrolyte fuel cell was calculated with the Lattice Boltzmann method. The underlying micro structure was taken from two sources. A real micro structure was analyzed in the synchrotron under the impact of a compression mask mimicking the channel/rib structure of a flow field. Furthermore a stochastic geometry model based on synchrotron X-ray tomography studies was applied. The effect of compression is included in the stochastic model. Gas transport in these micro structures was simulated and the impact of compression was analyzed. Fiber bundles overlaying the micro structure were identified which affect the homogeneity of the gas flow. There are significant deviations between the impact of compression on effective material properties for this type of gas diffusion layers and the Kozeny-Carman equation.

  1. Gas diffusion and temperature dependence of bubble nucleation during irradiation

    Foreman, A. J. E.; Singh, Bachu Narain

    1986-01-01

    The continuous production of gases at relatively high rates under fusion irradiation conditions may enhance the nucleation of cavities. This can cause dimensional changes and could induce embrittlement arising from gas accumulation on grain boundaries. Computer calculations have been made of the...... activation energy below Tm/2. The coalescence of diatomic nuclei due to Brownian motion markedly improves the agreement and also provides a well-defined terminal density. Bubble nucleation by this mechanism is sufficiently fast to inhibit any appreciable initial loss of gas to grain boundaries during the...... nucleation period, provided that incubation effects do not occur....

  2. HT-PEM Fuel Cell System with Integrated Thermoelectric Exhaust Heat Recovery

    Gao, Xin

    2014-01-01

    This thesis presents two case studies on improving the efficiency and the loadfollowing capability of a high temperature polymer electrolyte membrane (HTPEM) fuel cell system by the application of thermoelectric (TE) devices.TE generators (TEGs) are harnessed to recover the system exhaust gas for electricity. For this aim, a heat exchanger based TEG heat recovery subsystem is designed. Instead of optimizing an ordinary rectangular heat exchanger, high efficient and commercialized compact plat...

  3. Energy and exergy analyses of a bottoming Rankine cycle for engine exhaust heat recovery

    In this paper, a theoretical study on the thermodynamic processes of a bottoming Rankine cycle for engine waste heat recovery is conducted from the viewpoints of energy balance and exergy balance. A theoretical formula and an exergy distribution map for qualitative analyses of the main operating parameters are presented under simplified conditions when exhaust gas is selected as the only heat source. Five typical working fluids, which are always selected by manufacturers for different types of engines, are compared under various operating conditions in Matlab software. The results show that working fluid properties, evaporating pressure and superheating temperature are the main factors influencing the system design and performances. The global recovery efficiency does not exceed 0.14 under typical operating conditions. Ethanol and R113 show better thermodynamic performances in the whole exhaust gas temperature range. In addition, the optimal evaporating pressure usually does not exist in engine exhaust heat recovery, and the distributions of exergy destruction are varied with working fluid categories and system design constraints. - Highlights: • A theoretical formula for qualitative analyses of the Rankine cycle is proposed. • System exergy destruction is investigated with an exergy distribution map. • Design constraints of the bottoming Rankine cycle for ICEs are summarized. • The optimal evaporating pressure does not occur under typical exhaust conditions. • The exergy destruction depends on working fluid categories and system constraints

  4. Large-scale time-resolved digital particle image velocimetry (TR-DPIV) for measurement of high subsonic hot coaxial jet exhaust of a gas turbine engine

    The development of a highly configurable triple digital particle image velocimetry (DPIV) system is described, which is capable of acquiring both continuous, statistically independent measurements at up to 14 Hz and time-resolved PIV data at MHz rates. The system was used at QinetiQ's Noise Test Facility (NTF) as part of the EU-funded CoJeN programme to obtain measurements from high subsonic (Mach ≤ 0.9), hot (∼500 °C), large (1/10th) scale coaxial jet flows at a standoff distance of ∼1 m. High-resolution time-averaged velocity and turbulence data were obtained for complete coaxial engine exhaust plumes down to 4 m (20 jet diameters) from the nozzle exit in less than 1 h. In addition, the system allowed volumetric data to be obtained, enabling fast assessment of spatial alignment of nozzle configurations. Furthermore, novel six-frame time-series data-capture is demonstrated up to 330 kHz, used to calculate time–space correlations within the exhaust, allowing for study of spatio-temporal developments in the jet, associated with jet-noise production. The highly automated system provides synchronization triggers for simultaneous acquisition from different measurement systems (e.g. LDA) and is shown to be versatile, rugged, reliable and portable, operating remotely in a hostile environment. Data are presented for three operating conditions and two nozzle geometries, providing a database to be used to validate CFD models of coaxial jet flow

  5. High Temperature Gas-Cooled Test Reactor Options Status Report

    Sterbentz, James William [Idaho National Lab. (INL), Idaho Falls, ID (United States); Bayless, Paul David [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-08-01

    Preliminary scoping calculations are being performed for a 100 MWt gas-cooled test reactor. The initial design uses standard prismatic blocks and 15.5% enriched UCO fuel. Reactor physics and thermal-hydraulics simulations have been performed to identify some reactor design features to investigate further. Current status of the effort is described.

  6. Gas sensing properties of nanocrystalline diamond at room temperature

    Davydova, Marina; Kulha, P.; Laposa, A.; Hruška, Karel; Demo, Pavel; Kromka, Alexander

    2014-01-01

    Roč. 5, Dec (2014), s. 2339-2345. ISSN 2190-4286 R&D Projects: GA ČR(CZ) GP14-06054P Institutional support: RVO:68378271 Keywords : gas sensor * integrator * interdigitated electrodes * nanocrystalline diamond * response Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.670, year: 2014

  7. Noble-gas hydrides: new chemistry at low temperatures.

    Khriachtchev, Leonid; Räsänen, Markku; Gerber, R Benny

    2009-01-20

    Noble-gas chemistry has been undergoing a renaissance in recent years, due in large part to noble-gas hydrides, HNgY, where Ng = noble-gas atom and Y = electronegative fragment. These molecules are exceptional because of their relatively weak bonding and large dipole moments, which lead to strongly enhanced effects of the environment, complexation, and reactions. In this Account, we discuss the matrix-isolation synthesis of noble-gas hydrides, their spectroscopic and structural properties, and their stabilities.This family of species was discovered in 1995 and now has 23 members that are prepared in noble-gas matrices (HXeBr, HKrCl, HXeH, HXeOH, HXeO, etc.). The preparations of the first neutral argon molecule, HArF, and halogen-free organic noble-gas molecules (HXeCCH, HXeCC, HKrCCH, etc.) are important highlights of the field. These molecules are formed by the neutral H + Ng + Y channel. The first addition reaction involving HNgY molecules was HXeCC + Xe + H --> HXeCCXeH, and this led to the first hydride with two noble-gas atoms (recently extended by HXeOXeH). The experimental synthesis of HNgY molecules starts with production of H and Y fragments in solid noble gas via the UV photolysis of suitable precursors. The HNgY molecules mainly form upon thermal mobilization of the fragments.One of the unusual properties of these molecules is the hindered rotation of some HNgY molecules in solid matrices; this has been theoretically modeled. HNgY molecules also have unusual solvation effects, and the H-Xe stretching mode shifts to higher frequencies (up to about 150 cm-1) upon interaction with other species.The noble hydrides have a new bonding motif: HNgY molecules can be represented in the form (H-Ng)+Y-, where (H-Ng)+ is mainly covalent, whereas the interaction between (HNg)+ and Y- is predominantly ionic. The HNgY molecules are highly metastable species representing high-energy materials. The decomposition process HNgY --> Ng + HY is always strongly exoergic

  8. Preliminary operating experiences with the AVR at an average hot-gas temperature of 9500C

    The two-loop system with a high temperature reactor, which is operated by the Arbeitsgemeinschaft Versuchsreaktor (AVR) GmbH and which was built by the BBC/Krupp consortium (today HRB), has been in operation for more than seven years. In that time more than 635 x 106kWhr have been produced and more that 6.5 x 105 spherical fuel elements have been circulated under operation. The fully integrated design, and above all the ceramic gas duct, permit very high gas temperatures although no high alloyed, heat resistant steels were used in the reactor. In February 1974 the average hot-gas temperature at the outlet of the core could thus be increased from its original design value of 8500C to 9500C. Peak temperatures of above 500C are thereby confined to a small region between the middle of the core and the beginning of the steam generator. Carbon protects the steel structures against high temperatures. Unplanned interruptions and reductions of operation due to the increase of the hot-gas temperature have not occurred so far. Some thermocouples in the hot-gas region failed. All other components functioned satisfactorily and, one year after the increase in the hot-gas temperature, there are no misgivings as to their future functioning. These satisfactory but short operating experiences at 9500C will have to be supplemented in the next few years by experiences over a longer period. (Auth.)

  9. Effect of Temperature Wave on the Gas Transport in Liquid-Saturated Porous Media

    Goldobin, Denis S

    2013-01-01

    We study the effect of surface temperature oscillations on gas mass transport through liquid-saturated porous media. Temperature wave induced by these oscillations and decaying deep in the massif creates the gas solubility wave along with the corresponding solute diffusion flux wave. When bubbles are immobilized by the surface tension force the only remaining mechanisms of gas mass transport are related to solute flux through liquid in pores. We evaluate analytically the generated time-average mass flux for the case of medium everywhere littered with gas bubbles and reveal the significant effect of the temperature wave on the gas release from the massif and bubble mass redistribution within the massif. Analytical theory is validated with numerical calculations.

  10. A flow calorimeter for determining combustion efficiency from residual enthalpy of exhaust gases

    Evans, Albert; Hibbard, Robert R

    1954-01-01

    A flow calorimeter for determining the combustion efficiency of turbojet and ram-jet combustors from measurement of the residual enthalpy of combustion of the exhaust gas is described. Briefly, the calorimeter catalytically oxidizes the combustible constituents of exhaust-gas samples, and the resultant temperature rise is measured. This temperature rise is related to the residual enthalpy of combustion of the sample by previous calibration of the calorimeter. Combustion efficiency can be calculated from a knowledge of the residual enthalpy of the exhaust gas and the combustor input enthalpy. An accuracy of +-0.2 Btu per cubic foot was obtained with prepared fuel-air mixtures, and the combustion efficiencies of single turbojet combustors measured by both the flow-calorimeter and heat-balance methods compared within 3 percentage units. Flow calorimetry appears to be a suitable method for determining combustion efficiencies at high combustor temperatures where ordinary thermocouples cannot be used. The method is fundamentally more accurate than heat-balance methods at high combustion efficiencies and can be used to verify near-100-percent efficiency data.

  11. Microwave and Conventional Pyrolysis of Coffee Hulls at Different Temperatures for a Hydrogen Rich Gas

    Menendez, Angel; Fernandez, Yolanda; Dominguez, Antonio; Pis, Juan; Valente Nabais, Joao; Carrott, Peter; Carrott, Manuela

    2006-01-01

    Microwave and Conventional Pyrolysis of Coffee Hulls at Different Temperatures for a Hydrogen Rich Gas. The paper reports the comparison of using a microwave and a conventional furnace to do the pysolysis of the coffee hulls.

  12. The choice of the optimal temperature and time parameters of gas nitriding of steel

    Dhafer, Wadee Al-Rekaby; Kostyk, Viktoriia; Kostyk, Kateryna; Glotka, Alexandr; Chechel, Mykola

    2016-01-01

    Mathematical modeling of the gas nitriding process allows solving the problems of control of process parameters, prediction of outcomes and development of various treatment conditions, which is quite an urgent issue today. The research was aimed at selecting the optimum temperature and time parameters of gas nitriding of 38Сr2MoAl steel. Optical and electron microscopy showed that the diffusion layer after gas nitriding in the ammonia environment is the nitrided case and the region of interna...

  13. Optical methods to study the gas exchange processes in large diesel engines

    Gros, S.; Hattar, C. [Wartsila Diesel International Oy, Vaasa (Finland); Hernberg, R.; Vattulainen, J. [Tampere Univ. of Technology, Tampere (Finland). Plasma Technology Lab.

    1996-12-01

    To be able to study the gas exchange processes in realistic conditions for a single cylinder of a large production-line-type diesel engine, a fast optical absorption spectroscopic method was developed. With this method line-of-sight UV-absorption of SO{sub 2} contained in the exhaust gas was measured as a function of time in the exhaust port area in a continuously fired medium speed diesel engine type Waertsilae 6L20. SO{sub 2} formed during the combustion from the fuel contained sulphur was used as a tracer to study the gas exchange as a function of time in the exhaust channel. In this case of a 4-stroke diesel engine by assuming a known concentration of SO{sub 2} in the exhaust gas after exhaust valve opening and before inlet and exhaust valve overlap period, the measured optical absorption was used to determine the gas density and further the instantaneous exhaust gas temperature during the exhaust cycle. (author)

  14. Study of temperature and gas composition effects in rt relations of ATLAS MDT BIL Chambers

    Baroncelli, Antonio; Tagliaventi, Stefano; Bagnaia, Paolo; Solfaroli, Elena

    2004-01-01

    Large samples of cosmic rays taken at the Roma Tre test stand using precisely calibrated gas bottles have been used to study temperature and gas composition effects in spectra and rt relations of MDT BIL chambers of the Atlas experiment. Results are presented in this note. A comparison with Garfield expectations is also shown.

  15. MAPPING OF TEMPERATURE AND VELOCITY FIELD IN HOT GAS FREE JET

    Gregor, Jan; Jakubová, I.; Mendl, T.; Šenk, J.

    Brno, 2005, s. 81-83. ISBN 80-214-2931-3. [Symposium on Physics of Switching Arc /16th./. Nové Město na Moravě (CZ), 05.09.2005-09.09.2005] Institutional research plan: CEZ:AV0Z20430508 Keywords : hot gas mixture * temperature * velocity Subject RIV: BL - Plasma and Gas Discharge Physics

  16. High-temperature gas-cooled reactors (HTGRs) and their potential for non-electric application

    This paper presents High Temperature Gas cooled Reactors (HTGR). It also enumerates the potentials for non electrical applications such as delivering hot water, generating steam, producing hydrogen and carbon monoxide via conversion of natural gas. Then the author presents the contribution of HTGRs to reduce carbon dioxide emissions. (TEC). 4 figs., 1 ref

  17. Effect of Ambient Temperature on the Performance of Gas Turbines Power Plant

    Naeim Farouk Mohammed; Liu Sheng; Qaisar Hayat

    2013-01-01

    Efficiency and electric-power output of gas turbines vary according to the ambient conditions. The amount of these variations greatly affects electricity production, fuel consumption and plant incomes. The purpose of the present study is to investigate the effect of the ambient temperature on the performance of gas turbines. We observed that the power decreases due to reduction in air mass flow rate (the density of the air declines as temperature increases) and the efficiency decreases becaus...

  18. Sorption Enhanced High Temperature Water Gas Shift Reaction: Materials and Catalysis

    Noor, Tayyaba

    2013-01-01

    The work presented in this thesis focus on the hydrogen production by high temperature water gas shift reaction in conjunction to reforming process, as a significant industrial method for hydrogen generation. This thesis is a summary of three scientific papers. The work is directed towards synthesis of catalyst, evaluation for kinetic parameters and reaction mechanism, and sorption enhanced study to produce fuel cell grade hydrogen focusing high temperature water gas shift reaction. The main ...

  19. 30 CFR 7.101 - Surface temperature tests.

    2010-07-01

    ... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Surface temperature tests. 7.101 Section 7.101... temperature tests. The test for determination of exhaust gas cooling efficiency described in § 7.102 may be... the rated horsepower specified in § 7.97(a)(2). (ii) Install sufficient temperature measuring...

  20. Effect of Gas/Steam Turbine Inlet Temperatures on Combined Cycle Having Air Transpiration Cooled Gas Turbine

    Kumar, S.; Singh, O.

    2012-10-01

    Worldwide efforts are being made for further improving the gas/steam combined cycle performance by having better blade cooling technology in topping cycle and enhanced heat recovery in bottoming cycle. The scope of improvement is possible through turbines having higher turbine inlet temperatures (TITs) of both gas turbine and steam turbine. Literature review shows that a combined cycle with transpiration cooled gas turbine has not been analyzed with varying gas/steam TITs. In view of above the present study has been undertaken for thermodynamic study of gas/steam combined cycle with respect to variation in TIT in both topping and bottoming cycles, for air transpiration cooled gas turbine. The performance of combined cycle with dual pressure heat recovery steam generator has been evaluated for different cycle pressure ratios (CPRs) varying from 11 to 23 and the selection diagrams presented for TIT varying from 1,600 to 1,900 K. Both the cycle efficiency and specific work increase with TIT for each pressure ratio. For each TIT there exists an optimum pressure ratio for cycle efficiency and specific work. For the CPR of 23 the best cycle performance is seen at a TIT of 1,900 K for maximum steam temperature of 570 °C, which gives the cycle efficiency of 60.9 % with net specific work of 909 kJ/kg.